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HomeMy WebLinkAboutDRC-2012-001822 - 0901a06880304888D:<C- 2012-00 1822 EnErgy FUEIS REsaurcES IU5FI) Inc. August 29, 2012 Sent VIA OVERNIGHT DELIVERY Mr Rusty Lundberg Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West PO Box 144850 Salt Lake City, UT 84114-4820 Re: Transmittal of 2nd Quarter 2012 Nitrate Monitoring Report UDEQ Docket No. UGVy^-09-03 White Mesa Uranium Mill Dear Mr Lundberg Enclosed are two copies of the White Mesa Uranium Mill Nitrate Monitonng Report for the 2nd Quarter of 2012 as required by the January 2009 Stipulated Consent Agreement, UDEQ Docket No UGW-09-03, as well as two CDs each containing a word searchable electronic copy of the report Ifyou should have any questions regarding this report please contact me Yours very truly, ENERGY FUELS RESOURCES (USA) INC Jo Ann Tischler Director, Compliance CC David C Frydenlund Harold R Roberts David E Turk Katharine A Weinel Central Files Energy Fuels Resources (USA) Inc 225 Union Boulevard, Suite 600 Lakewood, CO 80228 Phone 303-974-2140 August 29, 2012 Sent VIA OVERNIGHT DELIVERY Mr. Rusty Lundberg Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144850 Salt Lake City, UT 84114-4820 Re: Transmittal of 2nd Quarter 2012 Nitrate Monitoring Report UDEQ Docket No. UGW-09-03 White Mesa Uranium Mill Dear Mr. Lundberg: Enclosed are two copies of the White Mesa Uranium Mill Nitrate Monitoring Report for the 2nd Quarter of 2012 as required by the January 2009 Stipulated Consent Agreement, UDEQ Docket No. UGW-09-03, as well as two CDs each containing a word searchable electronic copy of the report. If you should have any questions regarding this report please contact me. Yours. very truly, J ' .. ' ., ~~ ENERGY FUELS RESOURCES (USA) INC. Jo Ann Tischler Director, Compliance cc: David C. Frydenlund Harold R. Roberts David E. Turk Katherine A. Weinel Central Files Energy Fuels Resources (USA) Inc. Lakewood, CO 80228 225 Union Boulevard, Suite 600 Phone: 303-974-2140 White Mesa Uranium Mill Nitrate Monitoring Report State of Utah Stipulated Consent Agreement, January 2009 Docket No. UGW09-03 2nd Quarter (April through June) 2012 Prepared by: Energy Fuels Resources (USA) Inc. (formerly Denison Mines (USA) Corp.) 225 Union Boulevard, Suite 600 Lakewood, CO 80228 August 29, 2012 TABLE OF CONTENTS 1.0 INTRODUCTION ................................................................................................. 4 1.1 Quality Assurance Plan Modifications during the Quarter .................................. 4 2.0 GROUNDWATER NITRATE MONITORING ................................................ 5 2.1 Samples and Measurements Taken During the Quarter ..................................... 5 2.1.1 Nitrate Monitoring ...................................................................................... 5 2.1.2 Parameters Analyzed .................................................................................. 6 2.1.3 Groundwater Head and Level Monitoring .................................................. 6 2.2 Sampling Methodology and Equipment and Decontamination Procedures ....... 6 2.2.1 Well Purging and Depth to Groundwater ................................................... 6 2.2.2 Sample Collection ....................................................................................... 7 2.3 Field Data ............................................................................................................ 8 2.4 Depth to Groundwater Data and Water Table Contour Map .............................. 9 2.5 Laboratory Results .............................................................................................. 9 2.5.1 Copy of Laboratory Results ........................................................................ 9 2.5.2 Regulatory Framework ............................................................................... 9 3.0 QUALITY ASSURANCE AND DATA VALIDATION ................................. 10 3.1 Field QC Samples ............................................................................................. 10 3.2 Adherence to Mill Sampling SOPs ................................................................... 11 3.3 Analyte Completeness Review ......................................................................... 11 3.4 Data Validation ................................................................................................. 11 3.4.1 Field Data QAlQC Evaluation .................................................................. 11 3.4.2 Holding Time Evaluation .......................................................................... 12 3.4.3 Receipt Temperature Evaluation ............................................................... 12 3.4.4 Analytical Method Checklist .................................................................... 12 3.4.5 Reporting Limit Evaluation ...................................................................... 12 3.4.6 QAlQC Evaluation for Sample Duplicates ............................................... 13 3.4.7 Rinsate Check ........................................................................................... 13 3.4.8 Other Laboratory QAlQC ......................................................................... 14 4.0 INTERPRETATION OF DATA ....................................................................... 15 4.1 Interpretation of Groundwater Levels, Gradients and Flow Directions ........... 15 4.1.1 Current Site Groundwater Contour Map ................................................... 15 4.1.2 Comparison of Current Groundwater Contour Map to Groundwater Contour Map for Previous Quarter ........................................................... 15 4.1.3 Hydrographs .............................................................................................. 15 4.1.4 Depth to Groundwater Measured and Groundwater Elevation ................. 16 4.2 Review of Analytical Results ............................................................................ 16 4.2.1 Current Nitrate and Chloride Isoconcentration Maps ............................... 16 4.2.2 Nitrate and Chloride Concentration Trend Data and Graphs .................... 16 4.2.3 Interpretation of Analytical Data .............................................................. 16 5.0 CORRECTIVE ACTION REPORT ................................................................. 17 5.1 Identification and Definition of the Problem ......................................................... 17 5.2 Assignment of Responsibility for Investigation of the Problem ....................... 17 5.3 Investigation and Determination of Cause of the Problem ............................... 17 5.4 Determination of a Corrective Action to Eliminate the Problem ..................... 18 1 N:\Required Reports\Nitrate Quarterly Monitoring Report\201Z QZ\201Z QZ Nitrate Report text.docx 5.5 5.6 5.7 5.8 6.0 7.0 8.0 Assigning and Accepting Responsibility for Implementing the Corrective Action ............................................................................................................... 18 Implementing the Corrective Action and Evaluating Effectiveness ................. 18 Verifying That the Corrective Action Has Eliminated the Problem ................. 18 Assessment of Previous Quarter's Corrective Actions ..................................... 18 CONCLUSIONS AND RECOMMENDATIONS ............................................ 19 ELECTRONIC DATA FILES AND FORMAT .............................................. 19 SIGNATURE AND CERTIFICATION ........................................................... 20 2 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx LIST OF TABLES Table 1 Summary of Well Sampling and Constituents for the Period Table 2 Nitrate Percent Difference Table 3 Chloride Percent Difference INDEX OF TABS Tab A Site Plan and Perched Well Locations White Mesa Site Tab B Order of Sampling and Field Data Worksheets Tab C Kriged Current Quarter Groundwater Contour Map and Depth to Water Data Tab D Kriged Previous Quarter Groundwater Contour Map Tab E Hydrographs of Groundwater Elevations Over Time for Nitrate Monitoring Wells Tab F Depths to Groundwater and Elevations Over Time for Nitrate Monitoring Wells Tab G Laboratory Analytical Reports Tab H Quality Assurance and Data Validation Tables H-l Field Data QAIQC Evaluation H-2 Holding Time Evaluation H-3 Analytical Method Check H-4 Reporting Limit Evaluation H-5 QAlQC Evaluation for Sample Duplicates H -6 QC Control limits for Analysis and Blanks H-7 Receipt Temperature Evaluation H-8 Rinsate Evaluation Tab I Kriged Current Quarter Nitrate and Chloride Isoconcentration Maps Tab J Analyte Concentration Data Over Time Tab K Nitrate and Chloride Concentration Trend Graphs Tab L CSV Transmittal Letter 3 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 1.0 INTRODUCTION The Utah Department of Environmental Quality ("UDEQ") Division of Radiation Control ("DRC") noted in a Request dated September 30, 2008 (the "Request"), for a Voluntary Plan and Schedule to Investigate and Remediate Nitrate Contamination at the White Mesa Uranium Mill (the "Mill") (the "Plan"), that nitrate levels have exceeded the State water quality standard of 10 mg/L in certain monitoring wells. As a result of the Request, Energy Fuels Resources (USA) Inc. ("EFR") (formerly Denison Mines (USA) Corp.) entered into a Stipulated Consent Agreement (the "Consent Agreement") with the Utah Water Quality Board in January 2009 which directed the preparation of a Nitrate Contamination Investigation Report ("CIR") and Quarterly Nitrate Monitoring Reports. A subsequent letter dated December 1,2009, among other things, recommended that EFR also address elevated chloride concentration in the Nitrate Monitoring Reports. The Consent Agreement ("CA") was amended in August 2011. Under the amended Consent Agreement, EFR submitted a Corrective Action Plan ("CAP"), pursuant to the requirements of the Utah Groundwater Quality Protection Rules [UAC R317-6-6.15(C- E)] on November 29, 2011 and revised versions of the CAP on February 27, 2012 and May 7, 2012. This is the Quarterly Nitrate Monitoring Report, as required under the Consent Agreement, State ofUDEQ Docket No. UGW-09-03 for the second quarter of2012. 1.1 Quality Assurance Plan Modifications during the Quarter During the first and second quarter of 2012, Revision 6 of the approved Quality Assurance Plan ("QAP"), dated March 22, 2010, was revised on March 26, 2012 (Revision 7.0), May 25, 2012 (Revision 7.1) and June 6, 2012 (Revision 7.2). Revision 7.0, dated March 26, 2012, incorporated changes requested by Division of Radiation Control ("DRC") in correspondence dated February 7, 2012. The changes were requested to address field sampling procedures for low yield wells consistent with U.S. Environmental Protection Agency ("EP A") guidance documents. EFR submitted Revision 7.0 of the QAP on March 26, 2012. Revision 7.1 was submitted on May 25, 2012 to address minor changes to Revision 7.0 noted by DRC. Revision 7.1 was approved by DRC in correspondence dated May 30, 2012. EFR noted on June 6, 2012 that there were typographical errors in Revision 7.1 that interfered with field operations and submitted Revision 7.2 on June 6, 2012 to correct these typographical errors. DRC · approved Revision 7.2 on June 7, 2012. Samples were collected during the second quarter 2012 from April 18, 2012 through April 20, 2012 using the procedures contained in the approved QAP, Revision 6.0. Samples collected in the third quarter of 2012 will be purged and sampled in accordance with Revision 7.2 of the QAP. 4 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 2.0 GROUNDWATER NITRATE MONITORING 2.1 Samples and Measurements Taken During the Quarter A map showing the location of all groundwater monitoring wells, piezometers, existing wells, temporary chloroform contaminant investigation wells and temporary nitrate investigation wells is attached under Tab A. Nitrate samples and measurements taken during this reporting period (April through June 2012), are discussed in the remainder of this section. 2.1.1 Nitrate Monitoring Quarterly sampling for nitrate monitoring parameters was performed in the following wells: TWN-1 TWN-8 TWN-15 Piezometer 3 TWN-2 TWN-9 TWN-16 TWN-3 TWN-10 TWN-17 TWN-4 TWN-11 TWN-18 TWN-5 TWN-12 TWN-19 TWN-6 TWN-13 Piezometer 1 TWN-7 TWN-14 Piezometer 2 Table 1 provides an overview of all locations sampled during the current period, along with the date samples were collected from each location, and the date( s) upon which analytical data were received from the contract laboratory. Table 1 also identifies rinsate samples collected, as well as sample numbers associated with any required duplicates. As indicated in Table 1, nitrate monitoring was performed in all of the nitrate monitoring wells, and Piezometers 1, 2, and 3. Analytical data for all of the nitrate wells, and the piezometers are included in Tab G. Pursuant to EFR's agreements with DRC during the December 2011 conference calls regarding the pH investigation, EFR immediately stopped filling the Upper Wildlife Pond ("UWLP") at the Mill. In the past, EFR has sampled the UWLP during the quarterly nitrate sampling program. As a result of not filling the UWLP, there was insufficient water in the pond to allow collection of a representative sample. Additionally, the cows that graze in the area wallowed in and defecated in the remaining water. These two factors would most likely have caused some analytical difficulties and erroneous data. Due to current conditions at the time of the nitrate sampling program, that is, the minimal volume of water and the likelihood that the water is contaminated, EFR ceased sampling of the UWLP. EFR notified DRC of this sampling change via e-mail on April 18,2012 and received a written e-mail response and agreement from DRC on that same day. Nitrate and chloride are also monitored in all of the Mill's groundwater monitoring wells and chloroform investigation wells. Data from those wells for this quarter are 5 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx incorporated in certain maps and figures in this report but are discussed in their respective programmatic reports. 2.1.2 Parameters Analyzed Locations sampled during this reporting period were analyzed for the following constituents: • Inorganic Chloride • Nitrate plus Nitrite as Nitrogen (referred to herein as nitrate) Use of analytical methods consistent with the requirements found in Revision 6 of the QAP was confirmed for all analytes, as discussed later in this report. 2.1.3 Groundwater Head and Level Monitoring Depth to groundwater was measured in the following wells andlor piezometers, pursuant to Part I.E.3 of the Groundwater Discharge Permit (the "GWDP") (dated July 14,2011): • The quarterly groundwater compliance monitoring wells. • Existing well MW -4 and all of the temporary chloroform investigation wells. • Piezometers -P-1, P-2, P-3, P-4 and P-S. • MW-20, MW-22, and MW-34. • The DR piezometers which were installed during the Southwest Hydrogeologic Investigation. • Nitrate monitoring wells. • In addition to the above, depth to water measurements are routinely observed in conjunction with sampling events for all wells sampled during quarterly and accelerated efforts, regardless of the sampling purpose. All well levels used for groundwater contour mapping were measured and recorded within S calendar days of each other as indicated by the measurement dates in the summary sheet under Tab C. 2.2 Sampling Methodology and Equipment and Decontamination Procedures The QAP provides a detailed presentation of procedures utilized for groundwater sampling activities under the GWDP (July 14,2011). The sampling methodology, equipment and decontamination procedures that were performed for the nitrate contaminant investigation, as summarized below, are consistent with the QAP. 2.2.1 Well Purging and Depth to Groundwater A list of the wells in order of increasing nitrate contamination is generated quarterly. The order for purging is thus established. The list is included with the Field Data Worksheets 6 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx under Tab B. Mill personnel start purging with all of the non-detect wells and then move to the more contaminated wells in order of nitrate contamination, starting with the wells having the lowest nitrate contamination. Before leaving the Mill office, the pump and hose are decontaminated using the cleaning agents described in Section 6.2.5 of the QAP. A rinsate blank is collected after the first pump decontamination of each day as described below. Mill personnel then proceed to the first well which is the well with the lowest concentration (i.e. non-dectect) of nitrate based on the previous quarter's sampling results. Well depth measurements are taken and the two casing volumes are calculated (measurements are made using the same instrument used for the monitoring wells under the Mill's GWDP). The Grundfos pump (a 6 to 10 gallon per minute [gpm] pump) is then lowered to the bottom of the well and purging is begun. At the first well, the purge rate is measured for the purging event by using a calibrated 5 gallon bucket. After the evacuation of the well has been completed, the well is sampled when possible, and the pump is removed from the well and the process is repeated at each well location moving from the least contaminated to most contaminated well. If sample collection is not possible due to the well being purged dry a sample is collected after recovery as described below. All wells are capped and secured prior to leaving the sampling location. Decontamination of non-dedicated equipment, using the reagents in Section 6.2.5 of the QAP, is performed between each sample location, and at the beginning of each sampling day, in addition to the pre-event decontamination described above. 2.2.2 Sample Collection Wells Following the purging of a nitrate investigation well, the sampling takes place once stabilization has been achieved in accordance with Section 6.2.7 of the QAP. Prior to leaving the Mill office for sampling, Mill Personnel prepare a cooler with ice. A trip blank is not required as the sampling event does not include analyses for Volatile Organic Compounds ("VOCs"). Once Mill Personnel arrive at the well sites, labels are filled out for the various samples to be collected. All personnel involved with the collection of water and samples are then outfitted with rubber gloves to avoid sample contamination. Each sample collection event begins at the locations which are non-detect for nitrate (based on the previous quarter's data) and proceeds by concentration to the location with the highest concentration (based on the previous quarter's data). The dedicated portable pump is appropriately decontaminated prior to each sampling event, each sampling day, and between well samples. It is important to note that the rinsate blank sample frequency was modified during the fourth quarter 2010 as recommended by UDEQ personnel present on site for split sampling during the chloroform sampling program. Previously, a rinsate blank sample was collected after each decontamination of the nondedicated pump and prior to the next use of the pump. Per an e-mail from Mr. Phil Goble, dated November 15,2010, the decreased rinsate blank frequency implemented during the chloroform sampling program was acceptable for 7 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx implementation on the nitrate sampling program. Based on the revised procedure, rinsate blank samples are only required at the beginning of the sampling event and at the beginning of each day of purging. The frequency change was implemented during fourth quarter 2010. The rinsate blank sample frequency will be modified again during the third quarter 2012 sampling event pursuant to UDEQ approval of the Groundwater QAP, Revision 7.2 on June 7, 2012. The frequency for rinsate blank samples will be one rinsate blank sample for every 20 field samples. Samples are taken from the portable pump after stabilization has been achieved, unless the well is pumped dry. If the well is pumped dry, Mill personnel use a disposable bailer to sample the well after it has recovered in accordance with Section 6.2.7 of the QAP. The bailer is attached to a reel of approximately 150 feet of nylon rope and then lowered into the well. After coming into contact with the water, the bailer is allowed to sink into the water in order to fill. Once full, the bailer is reeled up out of the well:' Sample bottles are filled as follows: • First, a 250 ml sample is collected for nitrate/nitrite. This sample is not filtered, but is preserved with H2S04. • Second, a 500 ml sample is collected for chloride. This sample is not filtered and is not chemically preserved. After the samples have been collected for a particular well, the samples are placed into the cooler that contains ice. The well is then recapped and Mill personnel proceed to the next well. If a bailer has been used it is disposed of. Piezometers Samples are collected from Piezometers 1, 2 and 3, if possible. Samples are collected from piezometers using a disposable bailer following the procedures described for wells that have been pumped dry, above. However, due to the difficulty in obtaining samples from the piezometers, the purging protocols set out in the QAP are not followed. After samples are collected, the bailer is disposed-of and samples are placed into a cooler containing ice for sample preservation and transit to the Mill's contract analytical laboratory, EL. 2.3 Field Data Attached under Tab B are copies of all Field Data Worksheets that were completed during the quarter for the nitrate contaminant investigation monitoring wells, and piezometers identified in Section 2.1.1 above, and Table 1. It is important to note that the field data sheet appearance was changed in the fourth quarter 2010 as a result of the implementation of an electronic data capture system. The field data sheets contain the same information as the approved field . data sheet attached to the approved QAP in approximately the same location. The new data sheets allow the electronic capture of 8 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report textdocx data while still maintaining the real-time recording of information manually in ink as required by UDEQ. The changes were made to accommodate the data recording and validation system. Revised field forms will be used during the third quarter 2012 sampling event. The revised field forms are based on the changes approved in the Groundwater QAP, Revision 7.2. Approval of the QAP, Revision 7.2 was received June 7, 2012. 2.4 Depth to Groundwater Data and Water Table Contour Map Depth-to-groundwater measurements which were utilized for groundwater contours are included on the Quarterly Depth to Water Sheet at Tab C of this Report along with the kriged groundwater contour map for the current quarter generated from this data. All well levels used for groundwater contour mapping were measured and recorded within 5 calendar days of each as indicated by the measurement dates in the summary sheet under Tab C. A copy of the kriged groundwater contour map generated from the previous quarter's data is provided under Tab D. 2.5 Laboratory Results 2.5.1 Copy of Laboratory Results All analytical results were provided by EL. Table 1 lists the dates when analytical results were reported to the Quality Assurance ("QA") Manager for each well or other sample. Results from analysis of samples collected for this quarter's nitrate investigation are provided under Tab G of this Report. Also included under Tab G are the results of analyses for duplicate samples and rinsate samples for this sampling effort, as identified in Table 1. See the Groundwater Monitoring Report and Chloroform Monitoring Report for this quarter for nitrate and chloroform analytical results for the groundwater monitoring wells and chloroform investigation wells not listed in Table 1. 2.5.2 Regulatory Framework As discussed in Section 1.0 above, the Request, Plan, and Consent Agreement each triggered a series of actions on EFR's part. Potential surficial sources of nitrate and chloride have been described in the December 30, 2009 CIR and additional investigations into potential sources were completed. Pursuant to the Consent Agreement, the most recent version of the CAP was submitted to the Director of the Division of Radiation Control on May 7, 2012. The CAP describes future activities associated with the nitrate in groundwater. The CAP is currently undergoing public review and comment prior to final approval by the Director. This quarterly report documents the continued monitoring consistent with the program described in the initial Nitrate Contamination Investigation Report submitted in 2009. The monitoring program and reporting requirements set forth in the 2009 Contamination Investigation report will remain in effect until further notice and completion of the CAP. 9 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 3.0 QUALITY ASSURANCE AND DATA VALIDATION The Mill QA Manager performed a QAlQC review to confirm compliance of the monitoring program with requirements of the QAP. As required in the QAP, data QA includes preparation and analysis of QC samples in the field, review of field procedures, an analyte completeness review, and QC review of laboratory data methods and data. Identification of field QC samples collected and analyzed is provided in Section 3.1. Discussion of adherence to Mill sampling Standard Operating Procedures ("SOPs") is provided in Section 3.2. Analytical completeness review results are ' provided in Section 3.3. The steps and tests applied to check field data QAlQC, holding times, receipt temperature and laboratory data QAlQC are discussed in Sections 3.4.1 through 3.4.7 below. The analytical laboratory has provided summary reports of the analytical QAlQC measurements necessary to maintain conformance with National Environmental Laboratory Accreditation Conference ("NELAC") certification and reporting protocol. The Analytical Laboratory QAlQC Summary Reports, including copies of the Mill's Chain of Custody and Analytical Request Record forms for each set of Analytical Results, follow the analytical results under Tab G. Results of review of the laboratory QAlQC information are provided under Tab H and discussed in Section 3.4, below. 3.1 Field QC Samples The following QC samples were generated by Mill personnel and submitted to the analytical laboratory in order to assess the quality of data resulting from the field sampling program. Field QC samples for the nitrate investigation program consist of one field duplicate sample for each 20 samples, one DI Field Blank ("DIFB") and equipment rinsate samples. During the quarter, two duplicate samples were collected as indicated in Table 1. The duplicates were sent blind to the analytical laboratory and analyzed for the same parameters as the nitrate wells. Rinsate samples were also collected at the beginning of the sampling period and at the beginning of each day of purging from the decontaminated pump used for purging and sampling. Rinsate samples were labeled with the name of the subsequently sampled well with a terminal letter "R" added (e.g. TWN-7R). During the quarter three rinsate samples were collected and were sent to the analytical laboratory and analyzed for the same parameters as the nitrate wells. The results of these analyses are included with the routine analyses under Tab G. 10 . N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 3.2 Adherence to Mill Sampling SOPs On a review of adherence by Mill personnel to the existing sampling SOPs, the QA Manager observed that QAlQC requirements established in the QAP were being adhered to and that the SOPs were implemented, except as noted below. 3.3 Analyte Completeness Review All analyses required by the GWDP for nitrate monitoring for the period were performed. 3.4 Data Validation The QAP and GWDP (July 14, 2011) identify the data validation steps and data QC checks required for the nitrate monitoring program. Consistent with these requirements, . the QA Manager performed the following evaluations: a field data QAlQC evaluation, a holding time evaluation, an analytical method check, a reporting limit evaluation, a QC evaluation of sample duplicates, a QC evaluation of control limits for analysis and blanks, a receipt temperature evaluation, and a rinsate evaluation. Because no VOCs are analyzed for the nitrate contamination investigation, no trip blanks are required in the sampling program. Each evaluation is discussed in the following sections. Data check tables indicating the results of each test are provided under Tab H. 3.4.1 Field Data QA/QC Evaluation The QA Manager performs a review of all field recorded parameters to assess their adherence with QAP requirements. The assessment involved review of two sources of information: the Field Data Sheets and the Quarterly Depth to Water summary sheet. Review of the Field Data Sheets addresses well purging volumes and stability of five parameters: conductance, pH, temperature, redox potential, and turbidity. Review of the Depth to Water data confirms that all depth measurements used for development of groundwater contour maps were conducted within a five-day period of each other. The results of this quarter's review are provided under Tab H. Based upon this review, all well locations conformed to the QAP (Revision 6) requirement to evacuate two well casing volumes before sampling except TWN-2, TWN- 3, TWN-7, TWN-9, TWN-14, TWN-15, and TWN-17. These seven wells were all pumped to dryness before two casing volumes were evacuated and more than one set of field parameters could be collected. In each case, representative samples of formation water were collected after the wells were allowed to recover. Piezometers 1, 2, and 3 were not pumped, and were sampled directly after measurement of one set of parameters. Two casing volumes were pumped from TWN -10 before it was purged to dryness; however, only one set of field parameters were collected prior to TWN-10 being pumped dry. During review of the field data sheets, it was observed that sampling personnel consistently recorded depth to water for the quarterly sampling programs to the nearest 11 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 0.01 foot. All field parameters for all wells were within the QAP required limits, as indicated below. The review of the field sheets for compliance with QAP requirements resulted in the observations noted below. The QAP requirements in Section 6.2.7 specifically state that field parameters must have stabilized to within 10% over at least 2 consecutive measurements. The QAP states that turbidity should be less than 5 Nephelometric Turbidity Units ("NTU") prior to sampling unless the well is characterized by water that has a higher turbidity. The QAP does not require that turbidity measurements must be less than 5 NTU prior to sampling. As such, the noted observations regarding turbidity measurements less than 5 NTU below are included for information purposes only. • Fifteen well measurements and the measurement from Piezometers 3 exceeded the QAP's 5 NTU turbidity goal as noted in Tab H. All turbidity RPD's met the QAP Requirement to stabilize within 10%. EFR's letter to DRC of March 26, 2010 discusses further why turbidity does not appear to be an appropriate parameter for assessing well stabilization. In response to DRC's subsequent correspondence dated June 1, 2010 and June 24, 2010, EFR has completed a monitoring well redevelopment program. The redevelopment report was submitted to DRC on September 30, 2011. Redevelopment results will be discussed with DRC in an effort to come to a consensus regarding turbidity considerations for the nitrate wells at the Mill site. 3.4.2 Holding Time Evaluation QAP Table 1 identifies the method holding times for each suite of parameters. Sample holding time checks are provided in Tab H. All samples were received and analyzed within the required holding time. 3.4.3 Receipt Temperature Evaluation Chain of Custody sheets were reviewed to confirm compliance with the QAP requirement in QAP Table 1 that samples be received at 6°C or lower. Sample temperatures checks are provided in Tab H. All samples were received within the required temperature limit. 3.4.4 Analytical Method Checklist All analytical methods reported by the laboratory were checked against the required methods enumerated in the QAP. Analytical method checks are provided in Tab H. All methods were consistent with the requirements of the QAP. 3.4.5 Reporting Limit Evaluation All analytical method reporting limits reported by the laboratory were checked against the reporting limits enumerated in the QAP. Reporting Limit Checks are provided in Tab 12 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx H. All analytes were measured and reported to the required reporting limits, with the exception of 7 samples that had increased reporting limits due to matrix interference or required dilution due to the sample concentration. However, in all of those cases the analytical results were greater than the reporting limit used. 3.4.6 QAJQC Evaluation for Sample Duplicates Section 9.1.4 a) of the QAP states that RPDs will be calculated for the comparison of duplicate and original field samples. The QAP acceptance limits for RPDs between the duplicate and original field sample is less than or equal to 20% unless the measured results (described as activities in the QAP) are less than 5 times the required detection limit. This standard is based on the EPA Contract Laboratory Program National Functional Guidelines for Inorganic Data Review, February 1994, 9240.1-05-01 as cited in the QAP. The RPDs are calculated for all duplicate pairs for all analytes regardless of whether or not the reported concentrations are greater than 5 times the required detection limits. However, data will be considered noncompliant only when the results are greater than 5 times the required detection limit and the RPD is greater than 20%. The additional duplicate information is provided for information purposes. All duplicate results were within a 20% RPD. Results of the RPD test are provided in Tab H. 3.4.7 Rinsate Check Rinsate checks are provided in Tab H. Chloride A review of the analytical· results reported for rinsate blank samples indicated that one of the rinsate blank samples contained chloride. A DIFB was analyzed and the results indicated that it also contained chloride. A comparison of the rinsate blank sample concentration levels to the QAP requirements -that rinsate sample concentrations be one order of magnitude lower than that of the actual well -indicated that the rinsate blank sample with a detection of chloride did not meet this criterion. This criterion however, is irrelevant and inappropriate for the rinsate blank sample data collected during the nitrate sampling because rinsate blank samples are collected from the decontaminated portable pump used for well purging, and the pump is not used for sample collection. As stated in Section 2.2.1, wells that do not have a dedicated pump are purged using a portable pump. In wells where the portable pump is used for purging, a disposable bailer is used to collect the samples the day following purging activities. Based on the investigation into the source of chloride, EFR believes that the potential source for the chloride present in the rinsate blanks has been identified. Chloride is frequently a byproduct of the chlorination process in potable water supplies. 13 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx EFR believes the chloride contamination in the DI water is most likely the result of chlorination of the intake water used for the DI system. The chloride is most likely the result of the chlorination of the potable water at the Mill which is subsequently fed to the DI system. The chlorine added reacts with the naturally occurring organic and inorganic materials in the water. Corrective actions for this issue are described in Section 5.1. 3.4.8 Other Laboratory QA/QC Section 9.2 of the QAP requires that the laboratory's QAlQC Manager check the following items in developing data reports: (l) sample preparation information is correct and complete, (2) analysis information is correct and complete, (3) appropriate Analytical Laboratory procedures are followed, (4) analytical results are correct and complete, (5) QC samples are within established control limits, (6) blanks are within QC limits, (7) special sample preparation and analytical requirements have been met, and (8) documentation is complete. In addition to other laboratory checks described above, EFR's QA Manager rechecks QC samples and blanks (items (5) and (6)) to confirm that the percent recovery for spikes and the relative percent difference for spike duplicates are within the method-specific required limits, or that the case narrative sufficiently explains any deviation from these limits. Results of this quantitative check are provided in Tab H. All lab QAlQC results met these specified acceptance limits except as noted below. The QAP Section 8.1.2 requires that an MS/MSD (referred to as Duplicate Spike [Matrix spike] in the QAP) pair be analyzed with each analytical batch. The QAP does not specify acceptance limits for the MS/MSD pair, and the QAP does not specify that the MS/MSD pair be prepared on EFR samples only. Acceptance limits for MS/MSDs are set by the laboratories. The review of the information provided by the laboratories in the data packages verified that the QAP requirement to analyze an MS/MSD pair with each analytical batch was met. While the QAP does not require it, the recoveries were reviewed for compliance with the laboratory established acceptance limits. The QAP does not require this level of review, and the results of this review are provided for information only. The information from the Laboratory QAlQC Summary Reports indicates that the MS/MSDs recoveries and the associated RPDs for all quarterly nitrate samples are within acceptable laboratory limits for all regulated compounds as indicated in Tab H. The QAP requirement to analyze a MS/MSD pair with each analytical batch was met and as such the data are compliant with the QAP. The information from the Laboratory QAlQC Summary Reports indicates that the LCS recovenes were acceptable which indicate that the analytical system was operating properly. The QAP Section 8.1.2 requires that each analytical batch shall be accompanied by a reagent blank. All analytical batches routinely contain a blank, which is a blank sample 14 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx made and carried through all analytical steps. For the Mill samples, a method blank is prepared for all analytical methods. The information from the Laboratory QAlQC Summary Reports indicates that the method blanks did not contain detections of any target analytes above the RL. 4.0 INTERPRETATION OF DATA 4.1 Interpretation of Groundwater Levels, Gradients and Flow Directions. 4.1.1 Current Site Groundwater Contour Map As stated above, a listing of groundwater level readings for the current quarter (shown as depth to groundwater in feet) is included under Tab C. The data from this tab has been interpreted (kriged) and plotted in a water table contour map, provided under the same tab. The contour map is based on the current quarter's data for all wells. 4.1.2 Comparison of Current Groundwater Contour Map to Groundwater Contour Map for Previous Quarter The groundwater contour maps for the Mill site for the previous quarter, as submitted with the Nitrate Monitoring Report for the previous quarter, are attached under Tab D. A comparison of the water table contour maps for the current (second) quarter of 2012 to the water table contour maps for the previous quarter (first quarter of 2012) indicates . similar patterns of drawdown related to pumping of MW -4, MW -26, TW 4-4, TW 4-19 and TW4-20. Water levels and water level contours for the site have not changed significantly since the last quarter, except for a few locations. As discussed in Section 4.1.1, pumping at TW 4-4, which began in the first quarter of 2010, has depressed the water table near TW4-4, but a well-defined cone of depression is not yet evident, likely due to variable permeability conditions near TW4-4 and the low water level at adjacent well TW4-14. A reported decrease in water level of approximately 4 feet occurred in well MW-20. The water level changes at other wells, including pumping wells MW-4, MW-26, TW4-4, TW4-19, and TW4-20 were less than 1 foot. Water level fluctuations at pumping wells MW-4, MW-26, TW4-4, TW4-19, and TW4- 20 typically occur in part because of fluctuations in pumping conditions just prior to and at the time the measurements are taken. Water levels reported at pumping wells this quarter were, however, within 1 foot of their reported water levels last quarter. 4.1.3 Hydrographs Attached under Tab E are hydro graphs showing groundwater elevation in each nitrate contaminant investigation monitor well over time. 15 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 4.1.4 Depth to Groundwater Measured and Groundwater Elevation Attached in Tab F are tables showing depth to groundwater measured and groundwater elevation over time for each of the wells listed in Section 2.1.1 above. 4.2 Review of Analytical Results 4.2.1 Current Nitrate and Chloride Isoconcentration Maps Included under Tab I of this Report are current nitrate and chloride iso-concentration maps for the Mill site. Nitrate iso-contours start at 5 mg/L and chloride iso-contours start at 100 mg/L because those values appear to separate the plumes from background. All nitrate and chloride data used to develop these iso-concentration maps are from the current quarter's sampling events. 4.2.2 Nitrate and Chloride Concentration Trend Data and Graphs Attached under Tab J is a table summarizing values for nitrate and chloride for each well over time. Some data (MW -18, MW -19 and the Frog Pond) were not sampled this period but the historical data are included for information purposes. Attached under Tab K are graphs showing nitrate and chloride concentration plots in each monitor well over time. 4.2.3 Interpretation of Analytical Data Generally, the shapes of the nitrate and chloride plumes appear to be stable and unchanged for the last eleven quarters. The nitrate and chloride plumes maintain their general geographic association and it is still possible to separate the plumes into a segment northeast of the wildlife ponds and a southwest segment at the mill site. The current quarter's data continue to support the conclusion in the Nitrate Contamination Investigation Report that the nitrate and chloride at the Mill site are co-extensive and appear to originally come from the same source. Nitrate and chloride concentrations in samples from the downgradient edge of the plumes (in the vicinity of tailings impoundment monitoring wells MW -30 and MW -31) have remained essentially unchanged (current concentration within one standard deviation of the average of the previous ten quarters and within laboratory variation) and the plume does not appear to be migrating in the downgradient direction. In general, nitrate concentrations in nitrate monitoring wells are similar to values from last quarter or have declined (Table 2). Notable exceptions include nitrate concentrations in samples from PIEZ-3, TWN-2, and TWN-5 where values exceed the values from last quarter by 50% or more but all are less than values that have been previously measured from those sampling locations. For example, the nitrate concentration measured in PIEZ- 3 of 0.2 mg/L is 100% higher than the 0.1 mg/L measured last quarter but lower than the 0.6 mg/L concentration that has previously been measured in samples from this 16 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx piezometer. Some chloride concentrations are up slightly from last quarter but, with two exceptions, are within the range of previously measured concentrations. The measured chloride concentration in TWN-16 of 50 mg/L is higher than the previous high of 39 mg/L (Table 3). However, the measured chloride concentration in PIEZ-3 of 53 mg/L is lower than the previous high of 116 mg/L. Note that samples from recently installed chloroform monitoring wells TW 4-26 and TW4-27 had measured nitrate concentrations that are higher than 10 mg/L. However, nitrate concentrations in these wells are clearly separated from the nitrate/chloride plume at the Mill site by many wells that are below 10 mg/L or are nondetect for nitrate, including but not limited to, TW4-23, MW-32 and TW4-16. Thus, nitrate in TW4-26 and TW4-27 appears to be isolated from the plume at the Mill site, in the same way that the relatively small nitrate plumes at TWN-09 and TWN-17 are isolated from the plume at the Mill site. 5.0 CORRECTIVE ACTION REPORT Necessary corrective actions identified during the current monitoring period are described below. 5.1 Identification and Definition of the Problem Rinsate and DIFB Chloride Levels Chloride is present in one rinsate blank and in the DIFB for this quarter. To address previous nitrate contamination in the nitrate and chloroform sampling programs, an additional rinse with 55-gallons of DI water has previously been added to the decontamination process. EFR believes that the source for the chloride present in the rinsate blanks this quarter appears to be related to the increasing volume ofDI water used in the rinsate process due to the second 55-gallon rinse of the portable pump with DI water. The chloride present in the rinsate blanks is present in the DI water and is not the result of inadequate decontamination of the purging pump. The contamination in the DI water is most likely the result of chlorination of the intake water (from the potable water supply source) used for the DI system. At high volume use rates, the DI system appears to be unable to remove all of the chloride introduced with the DI intake (supply) water. 5.2 Assignment of Responsibility for Investigation of the Problem The problem has been investigated by the QA Manager. 5.3 Investigation and Determination of Cause of the Problem Rinsate and DIFB Chloride Levels As discussed above, chloride is entering the rinsate blanks from the chlorination of the potable water supply used as a feed to the DI system. The DI system is showing signs of breakthrough at times of high usage. To address the issue, the QA manager is working 17 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx with Mill staff evaluating the best approach to implement upgrades to the DI system to ensure its ability to support the high volume ofDI water needed for the rinsate process 5.4 Determination of a Corrective Action to Eliminate the Problem Rinsate and DIFB Chloride Levels The contamination in the DI water is most likely the result of chlorination of the intake water used for the DI system. Based on low level detections this quarter, the additional of a second DI rinse in the process is "stressing" the system and causing chloroform contamination. By upgrading the system, it will be able to support the high volume of DI water being pumped through the system. 5.5 Assigning and Accepting Responsibility for Implementing the Corrective Action Rinsate and DIFB Chloride Levels It will be the joint responsibility of the Director, Compliance and Permitting, and the Mill's sampling staff to implement the changes and to assess the data to determine if it has corrected the problems. 5.6 Implementing the Corrective Action and Evaluating Effectiveness Rinsate and DIFB Chloride Levels It is expected that chloride sources will be eliminated from the DIFBs after the DI system is upgraded to support the high volume of DI water in the system during the rinsate process. An appropriate DI system has been identified. Installation is scheduled to follow construction of other capital improvements in the Mill in late 2012 or early 2013. Data collected after the completion of the system upgrades will determine if any further action is necessary to eliminate rinsate contamination. 5.7 Verifying That the Corrective Action Has Eliminated the Problem Verification that chloride contamination has been eliminated will occur upon completion of the system upgrades and receipt of at least the two quarters of data. If chloride contamination persists then additional sources will be researched and the investigation will continue. . 5.8 Assessment of Previous Quarter's Corrective Actions Nitrate was present in the rinsate blanks during the first quarter 2012. To address previous nitrate contamination in the nitrate and chloroform sampling programs, an additional rinse with 55-gallons of DI water has been added to the decontamination process. The nitrate contamination has been eliminated from rinsate blanks, however, the addition of 55-gallons of DI water has resulted in chloride contamination in rinsates and DIFBs. EFR is currently working to upgrade the DI system. An appropriate DI system has been identified. Installation is scheduled to follow construction of other capital improvements in the Mill in late 2012 or early 2013. 18 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx Verification that rinsate and DIFB contamination has been eliminated will occur upon completion of the system upgrades and receipt of at least the two quarters of data. If chloride contamination persists then additional sources will be researched and the investigation will continue. 6.0 CONCLUSIONS AND RECOMMENDATIONS Generally, the shapes of the nitrate and chloride plumes appear to be stable and unchanged for the last eleven quarters. The nitrate and chloride plumes maintain their general geographic association and it is still possible to separate the plumes into a segment northeast of the wildlife ponds and a southwest segment at the mill site. The current quarter's data continue to support the conclusion in the Nitrate Contamination Investigation Report that the nitrate and chloride at the Mill site are co-extensive and appear to originally come from the same source. Nitrate and chloride concentrations in samples from the downgradient edge of the plumes (in the vicinity of tailings impoundment monitoring wells MW-30 and MW-31) have remained essentially unchanged (current concentration within one standard deviation of the average of the previous ten quarters and within laboratory variation) and the plume does not appear to be migrating in the downgradient direction. The current quarter's data continue to support the conclusion in the Nitrate Contamination Investigation Report that the nitrate and chloride at the Mill site are co- extensive and appear to originally come from the same source. 7.0 ELECTRONIC DATA FILES AND FORMAT EFR has provided to the Co-Executive Secretary an electronic copy of all laboratory results for groundwater quality monitoring conducted under the nitrate contaminant investigation during the Quarter, in Comma Separated Values ("CSV") format. A copy of the transmittal e-mail is included under Tab L. 19 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx 8.0 SIGNATURE AND CERTIFICATION This document was prepared by Energy Fuels Resources (USA) Inc. on August 29,2012. Energy Fuels Resources (USA) Inc. By: Senior Vice President, Regulatory Affairs and General Counsel 20 N:\Required Reports\Nitrate Quarterly Monitoring Report\201Z QZ\201Z QZ Nitrate Report text.docx Certification: I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for owing violations. Davi Fry enlund Senior Vice resident, Regulatory Affairs and General Counsel Energy Fuels Resources (USA) Inc. 21 N:\Required Reports\Nitrate Quarterly Monitoring Report\2012 Q2\2012 Q2 Nitrate Report text.docx Tables Table 1 Summary of Well Sampling and Constituents for the Period "~; ,~~i .. -",w,-'iF,C ,'l' F 'j pf, " Y i!l,:;_il'~ WeU". pm -, Sample Colle~tiqnDtt~~ pate 9~ Lab_.:g~po~~i Piezometer 01 4/20/2012 Piezometer 02 4120/2012 Piezometer 03 4/20/2012 TWN-01 4118/2012 TWN-02 4/20/2012 TWN-03 4/20/2012 TWN-04 4/18/2012 TWN-05 4118/2012 TWN-06 4118/2012 TWN-07 4120/2012 TWN-08 4118/2012 TWN-09 4/20/2012 TWN-10 4119/2012 TWN-11 4/19/2012 TWN-12 4118/2012 TWN-13 4118/2012 TWN-13R 4118/2012 TWN-14 4/20/2012 TWN-15 4/20/2012 TWN-15R 4119/2012 TWN-16 4/19/2012 TWN-17 4/20/2012 TWN-18 4119/2012 TWN-19 4119/2012 TWN-65 4/18/2012 TWN-60 4/20/2012 TWN-70 4/20/2012 Note: All wells were sampled for Nitrate and Chloride TWN-60 is a DI Field Blank TWN-65 is a duplicate of TWN-04, and TWN-70 is a duplicate ofTWN-15. 511/2012 5/1/2012 511/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 51112012 511/2012 5/1/2012 5/1/2012 51112012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 5/1/2012 f(:~ ~~B J~~~ '~i'fi~~ k~,~:': . ,"1:, ·'~~!!t~' I~'::;i~ ,~, iw' II ~f' ~~r~ Ir,,·tlsf~~:.y ~",~~ '~. i;'~riy}i; ,?",~I1\.'1 A"; !~~ I'i;i~ ~I', I:~~~~~ ~l~~~~K.f:~ J;:~~~~"~;' [it I',:);",.!;, . ~;·;til*h·' Piez 1 NA NA 7.2 Piez 2 NA NA 0.6 Piez 3 NA 1.7 1.6 TWN1 0.5 0.5 0.6 TWN2 20.8 62.1 69 TWN3 29 25.3 26 TWN4 004 0.9 1 TWN5 0.2 0.3 0.3 TWN6 104 1.5 104 TWN7 0.1 0.8 1.2 TWN8 0.1 <0.1 <0.1 TWN9 12 7.6 7.7 TWN10 104 1.5 1 TWN11 1.3 104 1.3 TWN12 0.5 0.7 0.8 TWN13 0.5 0.1 0.1 TWN14 304 2.9 2.9 TWN15 1.1 0.7 1 TWN16 1 1.2 1.3 TWN17 6.7 lOA 11 TWN18 1.3 1.6 1.8 TWN19 704 7.2 6.2 Red value indicates nondetect \' I~, .~;; .c·· ;'::;1f. I}{'~ ::~~" k~: ." ~~~, I.'''.,·N ,,~ \;~"'@ 6.8 \ 0.6 1.8 0.6 69 27 0.9 0.3 104 1.6 <0.1 10.7 0.2 104 0.7 0.2 3.5 1 2.6 8.9 1.8 7.2 Table 2 Nitrate (mg/L) ;~; ';< .. ',;,:" ;'. ),~.:: ' , ~~;:); :. ~i''!r~:~};. ¥ F~:'i~ ~,.n.:'r;'i'"');' ::1 ~.20 tn .'~ '1;: ~;~~.~.~~:i~~; . ,'iff' "',f},,'" ." 6.5 7 0.2 0.3 1.8 1.8 0.6 0.5 48 43 24 24 1.0 0.9 0.3 004 1.2 1.1 1.0 1.3 <0.1 <0.1 8 9.5 1.3 0.3 104 104 0.7 4.2 004 1.6 4.2 3.7 1.2 104 2 4.6 8 8.6 1.6 104 7 7 ;,;:~,:~');"~'/~~~'*'w .~~ ~~~~,~:~ '~, . :',,',' " '. ~'~~,;" ;f\~;'~f~'~~: 'i~: F.:: ,~:~:': .. , "':~ ~'\:;i :.;i!~~.~lf~~r:~~~~I:~~~ " . ~ ~/~ "ii::' -~': .;~' ~~ ~;' . 0 ~ '·'".2nd'\'Q·, '1~rQ}\:,#~91:~;: {~i~'S; 4t1l~Q,~1"O~:t !'2.nd ~'2012 '1 ,Q2'Ot!,:;and'2nd\!~;~, .;'~';&~'f'~,:;i;r :';\' .. ~ , ~ ..~,E'< :>.: " ;:~ ,.~~ ~,~~;.t.:.'. ~ ~~: :~f~~ :',~;,'~'lr,:29il:::;~~~;~~'i 6.8 7 6.6 7.1 6.6 -7 0.3 0.1 0.1 0.1 0.2 100 1.7 1.8 1.7 1.8 1.7 -6 0.5 0.5 0.5 0.6 0.6 0 40 33 33 31 48.0 55 26 25 25 25 24.0 -4 0.9 1.1 0.9 0.9 1.1 22 0.3 0.3 0.3 0.2 0.3 50 1.5 1.1 104 1.2 1.1 -8 1.7 0.7 2.2 2.3 1.2 -48 <0.1 <0.1 <0.1 <0.1 <0.1 0 10 11 10.9 12.2 10.6 -13 1.2 0.1 0.2 0.8 0.9 13 104 0.1 1.6 1.6 1.6 0 1 0.6 1.2 0.9 1.2 33 <0.1 <0.1 <0.1 <0.1 <0.1 0 3.5 3.5 3.9 3.5 304 -3 1.6 1.6 1.3 1.5 1.6 7 1.6 204 2.6 2.8 2.0 -29 9 8.5 8.1 8.7 9.1 5 1.8 1.8 1.9 1.9 2.1 11 6.9 7.1 6.5 7 6.8 -3 Table 3 INDEX OF TABS Tab A Site Plan and Perched Well Locations White Mesa Site Tab B Order of Sampling and Field Data Worksheets Tab C Kriged Current Quarter Groundwater Contour Map and Depth to Water Data Tab D Kriged Previous Quarter Groundwater Contour Map Tab E Hydrographs of Groundwater Elevations Over Time for Nitrate Monitoring Wells Tab F Depths to Groundwater and Elevations Over Time for Nitrate Monitoring Wells Tab G Laboratory Analytical Reports Tab H Quality Assurance and Data Validation Tables H -1 Field Data QAlQC Evaluation H-2 Holding Time Evaluation H-3 Receipt Temperature Check H-4 Analytical Method Check H-5 Reporting Limit Evaluation H -6 QAlQC Evaluation for Sample Duplicates H -7 Rinsate Check H -8 QC Control Limits for Analyses and Blanks Tab I Kriged Current Quarter Isoconcentration Maps Tab J Analyte Concentration Data Over Time Tab K Concentration Trend Graphs Tab L CSV Transmittal Letter Tab A Site Plan and Perched Well Locations White Mesa Site MW-5 • perched monitoring well TW4-12 o temporary perched monitoring well TWN-10 <> temporary perched nitrate monitoring well PIEZ-1 (Ii) TW4-27 ~ perched piezometer temporary perched monitoring well installed October, 2011 RUIN SPRING o seep or spring HYDRO GEO CHEM, INC. WHITE MESA SITE PLAN SHOWING LOCATIONS OF PERCHED WELLS AND PIEZOMETERS REFERENCE H:1718000/may12/Uwelloc12.srf FIGURE A-1 TabB Order of Sampling and Field Data Worksheets Name TWN-13 TWN-S TWN-1 TWN-lO TWN-4 TWN-12 lWN-6 TWN-15 TWN-ll TWN·18 TWN-7 TWN-16 TWN-14 TWN-19 TWN-l7 TWN-9 TWN-3 TWN-2 Piez 1 Piez 2 Piez3 ~ ·Tu.)~ ~ Twlv 7f:> TwJIJ 60 Nitrate Mg/l Previous Nitrate Samples Qrt. Date/Purge sample NO NO 0.2 0.6 0.8 0.9 0.9 1.2 1.5 1.6 1.9 2.3 2.8 3.5 7 8.1 12.2 25.0 31.0 7.1 0.1 1.8 NO ~"lg'I;l O,Ig 4-UZ ·I~ Ogo'l c.-l-l&-\:;). 0'1"\5" 1-\-1 ~ .... ~ \O~:::t 4~ III -1;Z f3~~ -i-i«" i:{ i~ 1.o\-tX-\:l '~~"i ""\A~-~ 1'1~\ ~'~:lO -12 0 (;2.'1 Lj -Itt-P· Ol'S"S t.\-\Q-12 O~l.\.'S ~\-A)-l" Ob'10 Lt "l'\-I':l, loot '-i -.2.D-y., O~SC !.o\ .-\a..\~ \~~ '-\-).0 .• t~ 0'=-54 Li-::to ~ 12-07D3 L.\-:lC-l:l ()jI5 '-i-J..c-\:l.. o72.r, ~-.2o-P, i'~f, ~ -)..(> -\'J-\:l.JS 4·-')j) ~ I)" 12.;;l) l..\/IB{ I~ l;2SS L.\ / .2. 0/12. 0 (;;),.1 t..t /20/ 12... ) 3")0 Nitrate Order 2nd Quarter 2012 Depth Total Depth 46-05 120 61.67 145.5 GA.~ 150 ~sj '70 112.5 ~i ex) 105 '"10.70 12S.7 "1.S(,t..l> 110 is..:l.5 130 Gj.;l.I" 155 bGjA~ 142 ":11 .70 145 'i".bO 105 l.-t7.f<0 100 b2.qs 135 s.:l.i.{h 110 3Li· ~~ 110 b'3.~ 97 -:>3.4,S 96 :2.! :7t 96 f>\ .'0> 2.;';t3c 1.\0 .\0 " \ Rinsate Samples Name Date Sample TWN-13R y .,g ~I~ (>6'-'10 TWN-8R TWN-SR TWN-IR TWN-10R TWN·4R TWN-12R TWN-6R lWN-15R Li/l~ I I:?. o<>:>!> TWN-llR TWN-l8R TWN·7R TWN-16R TWN-14R TWN·19R TWN-9R TWN·3R TWN-2R :3 i,.SJ.. Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r~:lsoJ)1~J ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL ,~~I:~, FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 1 :z.. t\Ji Q'""~r=t=c::'" AJ , fro..+< ;LO ,~ Location (well name)~L-_P_l_~_L._-_0_1 _______ ---' Sampler Name and initials: 14tAr'll"l:(" t}blh();;::~fT'}} Date and Time for Purgin~'-\ 12..01~1~ Well Purging Equip Used:[QJpump o@ bailer pH Buffer 7.0 7,0 Specific Conductanc~L-_4_q....:q ___ --I1 IlMHOS/ cm Depth to Water Before Purgin~ G:, \ • gs Conductance (avg) and Sampling (if different) .... 1 _;v._~_~ _______ ---, Well Pump (if other than Bennet) L-I "v._~_~~ _____ ---I Prevo Well Sampled in Sampling Event I Pi Gz.~ 0'3 pH Buffer 4.0 4,0 Well Depth(O.Olft): 1-1 D ____ --' Casing Volume (V) pH of Water (avg) 4" well:~O~_-fI(.653h) 3" Well:. l5 . (.367h) 8,50 Well Water Temp. (avg) 1 ) S.S""1 Redox Potential (Eh)L-1 :2.04_--'-_--1 TurbiditYI-I Y~''-'''O,---_--, Weather Condo l ___ c. __ --=:....-_____ ---' _ ~V\.f)n't Ext'l Amb. Temp. O( (prior sampling event)IL-_)_g_o_---I Time I l~03 Gal. Purged L-I _0 __ --1 Time Gal. Purged L-I ___ --' Conductance Conductance Temp.oC J5.,£7 Temp.oC Redox Potential Eh (m V) I ~ 0 ~ Redox Potential Eh (m V) L-I ___ --I Turbidity (NTU) Turbidity (NTU) Time Gal. Purged L-I ___ ---' Time Gal. Purged L-I ___ --I Conductance pH ..... I ___ --' Conductance pH L-I ___ ......I Temp.oC Temp.oC Redox Potential Eh (m V) IL--___ ..... Redox Potential Eh (mV) L-I ___ --' Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged .... 1 __ 1:) ____ ..... gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I 0 T=2V/Q= I 0 I Number of casing volumes evacuated (if other than two) ..... 1 0 ___ ----' If well evacuated to dryness, number of gallons evacuated 1-1 D ___ ---J N arne of Certified Analytical Laboratory if Other Than Energy La~ ..... #I_~A _______ --, Sample Taken Sample Vol Filtered Preservative Preservative Added Type of Sample (indicate if other y N than as specified y N Type y VOCs D D 3x40 ml D D HCL D Nutrients 'tJ D 100 ml D ~ H2SO4 tJ Heavy Metals D D 250ml D D HN03 D All Other Non Radiologics D D 250ml D D No Preserv. D Gross Alpha D D 1,000 ml D D HN03 D Other (specify) 'fJ D Sample volume D 19 D Ghlor~~(. If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction ~ ("r~..Je:~ on f> rTe. ~1 )')..5"1. ~n(\tl ~p\es b~jea OV'"IJ. GOll~d-d 0;} rAnd.. {jq"rr-:n r,.,e~e~:t--o c.ol1ed-..saM[> 1G.S. l~O:S.. w~+er w~ Gleo..r. Piez-01 04-20-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N D D D D D !9 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) \----------------, t OENISONI)~~1 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL 'j MINES ..-.-...J FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 1 2nD< Q"",o.14er Nffr~ ~112 Location (well name)~I....-P_le_~_-_O_;;;" ________ ---, Sampler Name and initials: ~(lf\er 'HDI L'a~/fH Date and Time for Purgin~ j 72.0/~012.. Well Purging Equip Used:[QJpump or(![] bailer pH Buffer 7.0 7 .0 Specific Conductanc~l.........;q....:..4 _"1 ___ --,1 ~MHOS/ cm Depth to Water Before Purgin~:?2;2:.'3C> Conductance (avg) £770.3 and Sampling (if different) 1 ...... /0_0_11-________ -' Well Pump (if other than Bennet) I ...... M_VA _______ ......I l-rvJJV-02 Prevo Well Sampled in Sampling Event L... _________ --I pH Buffer 4.0 4.0 Well Depth(O.Olft): ...... 1 _0 ___ ----' Casing Volume (V) pH of Water (avg) 4" W ell:~----"D"'--_-II (.653h) 3" Well:, 0 ,(.367h) Well Water Temp. (avg) 1 15,54 Redox Potential (Eh)1 '174 TurbiditylL.,.J1L-.' '~----I Weather cond'l I..... _S_v.._""_-l'_'-ff ________ ---' Ext'l Amb. Temp. O( (prior sampling event)1.....1 1.1-7_° __ -, Time 1 \~'3:5 Gal. Purged r...lb ___ ---I Time Gal. Purged .... 1 ___ ---' Conductance 1 b7 6.3 Conductance pH 1-1 __ ----' Temp.oC 115. SCi Temp.oC Redox Potential Eh (mV) , q lY Redox Potential Eh (m V) ,'---__ ---I Turbidity (NTU) 1 \. b Turbidity (NTU) Time Gal. Purged 1.....' ___ ---' Time Gal. Purged 11....-___ -' Conductance pH 1,,--___ ......1 Conductance pH ,'---__ ---I Temp.oC Temp.oC Redox Potential Eh (m V) r...1 ___ ---I Redox Potential Eh (mV) ..... 1 ___ --' Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (OAP) V olume of Water Purged 1-1 _D ____ ...... gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = 1 0 T=2V/Q= I 0 I Number of casing volumes evacuated (if other than two) 1-1 _0 ___ ...... If well evacuated to dryness, number of gallons evacuated 1-1 0 ___ --.1 N arne of Certified Analytical Laboratory if Other Than Energy La~I-_~_~_~ ______ ---I Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) VOCs D D 3x40 m! Nutrients ~ D 100 ml Heavy Metals D D 250m! All Other Non Radiologics D D 250m! Gross Alpha D D 1,000 ml Other (specify) "fJ D Sample volume Ghlo(';~< . Comment Y N D D D 1:1 D D D D D D D 1:1 Type y HCL D H2SO4 ~ HN03 D No Presel-v. D HN03 D D If preservati ve is used, specify Type and Quantity of Preservative: n See instruction 6r£~ A(('\\)<::~ on S~-t~ a;...f' \;t~. ~f\(\~( I"l\~ &0..(",1(1 'Pr6.sc r't"Y +0 LcH-e,d-SQYYJpJe,S_ :''''l'V]fl \cs. Were.. bo-:l-c~ 0..1-1~5 ~~(' wa.s. deo.,. L e..-fT s ~~ ",--t-l:::t"3g Piez-0204-20-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N D D D D D ~ 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r--------------!OENISONI).4~ ATTACHMENT 1 Attachment 1 WHITE MESA URANIUM MILL ~ See instruction MINI:S FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 1 2... n IJ. Q"'C\r"fcr-)\J \~frtA.te .:l-OI':2. Location (well name )fL-_?_,_e._1.._-_0_3 ________ ----' Sampler Name and initials: 1 =-j" Anne., Ho)] /j~7f)j Date and Time for Purging q/:J-.'C> 7 ~o lr.:L Well Purging Equip Used:11[] pump 000 bailer Sampling Event 1 Q"'A("fec-~ )\)l::t('o,.;h:. pH Buffer 7.0 7.6 Specific Conductanc~~4_q ...... 9 ___ __'1 ~MHOS/ cm Depth to Water Before Purgina 9 0 . 1 0 Conductance (avg) and Sampling (if different) ~/--1 L--_~ ______ ---' Well Pump (if other than Bennet) L-I ~_YA-______ ---, I P~e:z-02.. Prevo Well Sampled in Sampling Event L-_________ ......... pH Buffer 4.0 Y.O Well Depth(O.Olft): ,--I _0 ___ ----' Casing Volume (V) pH of Water (avg) 4" well:~_OO:--_---iI(.653h) 3" Well:. D J367h) J~.11 Well Water Temp. (avg) 1}5 I L}l Redox Potential (Eh)1 177 Turbidityla.....;5~.~ __ ----' Weather cond'l L-__ S_\.A._t'\_n_il _______ --' Time I ' ~ UI 8' I Gal. Purged IL--_O __ ----' Conductance Temp.oC Redox Potential Eh (m V) 1 177 Turbidity (NTU) Time Gal. Purged L-I ___ ---' Conductance pH 1'--___ --' Temp.oC Redox Potential Eh (m V) L-I ___ ---' Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. O( (prior sampling event}L-11_7_o __ ----' Time Gal. Purged 1-1 ___ ---' Conductance pH L..-1 __ ----' Temp.oC Redox Potential Eh (m V) IL..--__ ---' Turbidity (NTU) Time Gal. Purged L-I ___ ----' Conductance pH 10..-___ --' Temp.oC Redox Potential Eh (mV) L-I ___ ---' Turbidity (NTU) 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged 1'--_____ --' gallon{s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I 0 T=2V/Q= I D I Number of casing volumes evacuated (if other than two) 0 L..-.. ___ .....I If well evacuated to dryness, number of gallons evacuated 0 L..-.. ___ .....I N arne of Certified Analytical Laboratory if Other Than Energy LaijL._~_~ _______ ....J Sample Taken Sample Vol Filtered Preservative Preservative Added Type of Sample (indicate if other y N than as specified y N Type y N VOCs D D 3x40 ml D D HCL D D Nutrients 1:l D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) E D Sample volume D ~ D ~ C~\Dr~l( If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction A ff i ~eJ. on ~ tt~ .. ..1 \::l 41. -r;.r1Tler' o.r1d. 6-", fr ,." p re-!,.(1) J. 1-0 GO JI e.d-.5 P"M r le..s, .::, iN"'I\ f) eS GO' \ eel-~~ ()J'l a bOo. :1 e,k "'+ \~E.O , vJo-.-tc:r Wo..-> c..1 e.w'. L-e.-+t $'~C. "')-JAS J Piez-0304-20-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of2 Mill .. Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) .-... _----_ .. ------_._, i OENISONr;)~~1 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL J_~INES _~ FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I · N~rq....fe. 2"l5\ Q",o.("1--e(' '2P)::L Location (well name )~L....-_'T...;:....;;v.:l-.;...N_-_0_, _______ ---1 Sampler Name and initials: l==t"o..7'lner bt611,'JtA.t,)TH- Date and Time for Purgin~ '1IJ<£/~ol~ and Sampling (if different) ...... 1 ~_~_'fo _______ ----I Well Purging Equip Used:OOpump or@] bailer Well Pump (if other than Bennet) 1 Cr.,.v.Y" J:rD..s Sampling Event IQv.CAf+erl~ j\) :}(""+~ Prevo Well Sampled in Sampling Event l--(vJ"v-OS pH Buffer 7.0 7,0 pH Buffer 4.0 Lf.D Specific ConductanceL-1 _ti\~'f_q ___ -JI ~MHOS/ cm Well Depth(O.Olft): I 11:2..SD Depth to Water Before Purgina .s 1.70 Casing Volume (V) 4" well:1 ~~ .70 1(·653h) 3" Well: 6 (.367h) 1.....-___ ...... Conductance (avg) ~D3 pH of Water (avg) 7.Sf> Well Water Temp. (avg) 1 \5.0\ Redox Potential (Eh)r...;;;I..2-:.,:16 ___ --' TurbiditY~I.;2.:..-..:..7 __ .......I Weather Condo Time ...... 11_0 ~---£.~ _---I Gal. Purged ...... 1 _fP.. __ ---' Conductance 1 st 03 pHI 7.S S Temp.oC Redox Potential Eh (m V) I ;z;2.'2.. Turbidity (NTU) Time ;.-1 ....... '_0.....;;..3_1_---' Conductance I ~ 03 Gal. Purged 1L.....---'7:.....g __ ...... pH I 7,SC- Temp.oC I lS.o) Redox Potential Eh (mV) I ;;... 17 Turbidity (NTU) I ';L7.~ White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. O( (prior sampling event)L-1 ...... 10_b __ --' Time 1030 Gal. Purged ...... 1 ~~ __ .......I Conductance I ~OS Temp.oC I 1~,0D Redox Potential Eh (m V) 1 ...... ?)5.D ___ --' Turbidity (NTU) I :2lSP Time 1103 -:z.. Gal. Purged I ...... q...;..;}:.....-__ ...... Conductance ...... 1 ~=O_'-\"-_"",, pH 1,.51:, Temp.oC 1 is.DI Redox Potential Eh (m V) ...... 1 _~_I_L __ ...... Turbidity (NTU) 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged ...... 1 _"....:...:..1 ___ -' gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = I \3 Time to evacuate two casing volumes (2V) T = 2V/Q = I G. I D I Number of casing volumes evacuated (if other than two) () "-------' If well evacuated to dryness, number of gallons evacuated D 1...-_---' N arne of Certified Analytical Laboratory if Other Than Energy La~ ...... ~_i._~ ______ ----J Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N Type y N VOCs D D 3x40 ml D D HCL D D . Nutrients 151 D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) "tJ D Sample volume D ,B D ~ Ch \O('~~(. If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction TWN-0104-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r·-----·----------·-·---·-----I I OENISONI)~~ ATTACHMENT 1 WHITE MESA URANIUM MILL Attachment 1 ~ See instruction lL~]NI:S -.J FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I 2. n J\ QU(A,..-t'er AJ ,':fr",,1'" ~ 12-0 \:to Sampler Name Location (well name)iL...-nN_l __ N_-_C_":l. ________ ---1 and initials: l~f"I1)e'-lJo\\)Jt~7Ti1- Date and Time for PurginS L.lIl~/:;.ol~ Well Purging Equip Used:OO pump o@ bailer Sampling Event I Q~CAr+(/'e N i "h"o..-\-~ pH Buffer 7.0 Specific Conductancel'---_4 _1_Cj __ ---'1 ~MHOS/ cm Depth to Water Before PurginS ;;L) • ~6 Conductance (avg) :l)D~ '---------~ and Sampling (if different) I \.17:;"0/ ::2..D12... Well Pump (if other than Bennet) I Gr'\Arl$C)~ Prevo Well Sampled in Sampling Event II\IJJJ-03 pH Buffer 4.0 q.o Well Depth(O.Olft): I qb.c>O Casing Volume (V) 4" well:1 '-18.77 IC.653h) 3" Well:. 0 . (.367h) pH of Water (avg) ~,7g '--~~~-------~ Well Water Temp. (avg) 1'5, SJ Redox Potential (Eh)1 'i~'i Turbidityl ~1"L~ Weather Condo Ext'l Amb. Temp. O( (prior sampling event)L...1 _1_&_° __ .... Time L-11_9_47 __ ...... Gal. Purged 1L-7_~ __ .....I Time 1 I Gal. Purged I I Conductance 1306 CO pH 1 (0,78 Conductance I I pH I 1 Temp.oC I I'S.5 l Temp.oC I I Redox Potential Eh (mV) I qsy Redox Potential Eh (m V) I I Turbidity (NTU) I a:4.~ Turbidity (NTU) I I Time Gal. Purged L...I ___ ---' Time I I Gal. Purged I I Conductance pH ...... 1 ___ --I Conductance I I pH I I Temp.oC Temp.oC I I Redox Potential Eh (m V) 1'--___ ...... Redox Potential Eh (mV) I I Turbidity (NTU) Turbidity (NTU) I I White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged ..... 1 -.:..7_:2 ___ ---' gallon(s} Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I \~ T = 2V/Q = I g., ~ I Number of casing volumes evacuated (if other than two) I [.q 1 If well evacuated to dryness, number of gallons evacuated N arne of Certified Analytical Laboratory if Other Than Energy La~L.._N._~_~ ______ ---, Sample Taken Sample Vol Filtered Preservative Preservative Added Type of Sample (indicate if other y N than as specified y N Type y VOCs 0 0 3x40 ml 0 0 HCL 0 Nutrients ~ 0 100 ml 0 ~ H2SO4 rn Heavy Metals 0 0 250ml 0 0 HN03 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 Other (specify) ~ 0 Sample volume 0 ~ 0 c..,~1 or J' J-( If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction Aa;"ea. On ~;+'" ",i-''-'~/. '''MeA 6..t\J. G-"",{,'" pres..""q J.;,r p"'r~e . P"r~~ b~",., )L1l.\ \. ? \Ai":j-ec\ well .ror ().. -+o+tA.\ of' '=-""i(\v:1t·S. t\kr~e~ W~" a.(~'. ?v\'I"~e el1J.c:j, 41- \4\.\1_ \0fA.1-(r W6...5:. L'<.o..("". l~.A Site> o. . ..} )t..\Sb Af(,:\J~A. on ~;i-e 0...1-Ol;2..0,--Tl\nn-er t?J\~ CrIA(('1'1'I pr~~t)~ +0 L,olleG1-.s~Mp)t:,$.. Ot:P~ {v\".:l<A+-e.r W~~ .;7..1.JD. So\Mpl-Gs-1o(;\.~1-c:c1 t}..~ D7~5 .. Le.~ ~)T<. a.T ()1d-.7 TWN-0204-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N 0 0 0 0 0 ~ 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) rOEN,s~~I)~.41 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL i MINES FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I ;1.f\tJ\ Qv..tM .. ter 6J1 /\.);:o}(""'-+< !L.Dl~ Location (well name )~,-_T'_w_N_ .... _O_3 ________ ---, Sampler Name and initials: --r;.",,-er OQ 0 l\ j J\~~/'T'H" Date and Time for Purgina Y/lq /;2.01a... and Sampling (if different) I '-17 ;1...0/':;"01 ~ Well Purging Equip Used:[f[] pump o@ bailer Well Pump (if other than Bennet) Prey. Well Sampled in Sampling Event I '-_'1i_W_W_-_D_q _____ ----' pH Buffer 7.0 7.D pH Buffer 4.0 Specific Conductanc~,-_~-,-q-,-,q,---__ ---,I !lMHOS/ cm Well Depth(O.Olft): I 'J ",DO Depth to Water Before Purgina ~. 8S 4" well:1 41.::Z::S 1(.653h) 3" Well: 0 (.367h) L..-___ ....J Casing Volume (V) Conductance (avg) pH of Water (avg) Well Water Temp. (avg) I . 'Y.gj Redox Potential (Eh)1 3QS Turbidity ..... 1 J...;;;.O...;;;.O __ ~ Weather cond'l ..... _&_lo_v-_J..;;...t _______ ---I Ext'l Amb. Temp. O( (prior sampling event) 1-1 '_S_l' __ -....J Time 1 lq 15 Gal. Purged 1,---5_1 __ ~ Time Gal. Purged 1'--___ ..... Conductance l:t ~ '>'1 Conductance Temp. °c 1 lq. $3 Temp.oC Redox Potential Eh (m V) I 5 q 5 Redox Potential Eh (m V) 1-1 ___ --I Turbidity (NTU) \00 Turbidity (NTU) I I Time Gal. Purged 1-1 ___ -....J Time Gal. Purged 1-1 ___ -....J Conductance pH ..... I ___ --' Conductance pH ..... I ___ --' Temp.oC Temp.oC Redox Potential Eh (m V) I'--___ ....J Redox Potential Eh (m V) 1'---__ ---' Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged 1-1 _5_7 ___ --' Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = IL...-.._):;l __ ~ gallon(s) Time to evacuate two casing volumes (2V) T=2V/Q= 1 b,g7 I Number of casing volumes evacuated (if other than two) 1 1.'3>3 If well evacuated to dryness, number of gallons evacuated N arne of Certified Analytical Laboratory if Other Than Energy La~I-_;v_0~ _____ ~ Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs D D 3x40 m1 D D HCL D D Nutrients ~ D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologies D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) ~ D Sample volume D ~ D a Ghlor)'dG If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction Af"r;v~~ 00('\ ~;-}'C dt.~ l"-leE, -r""Y'n~r-~t\J. G-",-r,.;"l ?f'esenf +or P""':je.. rv..i"<\e. b~~r1 ? v..("~e~ vV~n .rof" 0.. +o-t~\ or 11 fVliYlU\i-~ aI.(1~ L1 S 5e.C6vuls. P\Af"~d well J.f'~1. Pw'~-G e..(H~ec\ a...t \'1 \~. v..)~~1 'h0\~ (J-. L'rtl"G ~;~LD\O(". LeB-SItu ",T It.Jl! A-rr:\)~ on ~I'+~ 0.+ 0"710 I II).(\rJif tiVla (;-Q.. ('" '11'1'\ pr<:sen+ ~ to c.o l1evt 5.ti\Mple.s. l:)~pt\ to wIAter v1o..~ 3~# bS s.~f>l~~ \Nd<:., c.o\1ec.t<::d 0.1' 071S. L<.,.f}-SJt~ o.-} O,t1 TWN-0304-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) .-----------Jl oENlsoNI)~~ ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL MINI:S _ FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I ::z.. nO. Gv.-o..r"'-er}J /f r A=t<... 2-D l~ Sampler Name Location (well name )~,--__ -r_W_N_-_O_'-\ ______ --I and initials: I-r;nn-er H6111cJ~jln:F Date and Time for Purgin8 L\/, ~ / ~ J~ Well Purging Equip Used:[![] pump o@ bailer pH Buffer 7.0 7.0 Specific ConductanceL-1 _"I;....;.ti ...... , __ --II ~MHOS/ cm Depth to Water Before Purgina 4 Q,/'D Conductance (avg) 'D~ and Sampling (if different) ,--I N._71T ________ ...... Well Pump (if other than Bennet) I &-rlN"la:fo~ Prev. Well Sampled in Sampling Event 1L-"1\N __ JV_-_1b _____ -----' pH Buffer 4.0 y,O Well Depth(O.Olft): 1 1~S)·7D Casing Volume (V) pH of Water (avg) 4" well:1 $.:50 1(·653h) 3" Well: 0 (.367h) L...-__ ---I Well Water Temp. (avg) I 14. q2. Redox Potential (Eh)1 .:l. 3:::' TurbiditYL-1 _11...;;;8'---_--1 Weather Condo IL-._B_CA_~_' t-=--_G_' o_v..._~---.:i~ __ --I Ext'l Amb. Temp. O( (prior sampling event}L-11_7_D __ ...... Time ha..>L Gal. Purged 1....1 _1_0.....:,L1 _-----I Time I \~3 Gal. Purged L-I --Il\~7 __ ...... Conductance I 10 '!> ~ Conductance Temp.oC 1 ) L\. '11 Temp.oC Redox Potential Eh (mV) I A'SLO Redox Potential Eh (mV) I ~SCf Turbidity (NTU) Turbidity (NTU) I lOb Time I l~S'i Gal. Purged 1....1 .....;.l_~_O_-----I Time 1\2SS Gal. Purged ...... 1 l:.......Li~~ __ --I Conductance 1 lO,>Y pH I 7.;;Q Conductance (0"'5'-1 Temp. °C 1 14 .~li Temp.oC I ''1/13 Redox Potential Eh (mV) I .:2..33 Redox Potential Eh (mV) 1 ;t3:l: Turbidity (NTU) Turbidity (NTU) II *' White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged ,'----:.\ L.\-=3 __ ---' gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I 13 T=2V/Q= I ~.'S3 I Number of casing volumes evacuated (if other than two) 0 '-----_ ...... If well evacuated to dryness, number of gallons evacuated () '-----_ ...... N arne of Certified Analytical Laboratory if Other Than Energy La~,-.;...~_/._;A. ______ ---I Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y VOCs D D 3x40 ml D D HCL D Nutrients ~ D 100 ml D ~ H2SO4 ~ Heavy Metals D D 250ml D D HN03 D All Other Non Radiologics D D 250ml D D No Preserv. D Gross Alpha D D 1,000 ml D D HN03 D Other (specify) ~ D Sample volume D ~ D ~hlc(";j( If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction Am'''ej 0(1 .sIt", At 1.2YD. -r;,Mer ,..".1. &",r,:" p('e~ef'l} -R,r p"'r~" ... ".1 .s"""pJ,t! eueY!+ R .. r~c bc~"'n ",1" I:tLJ"i, ? ~e~ ~ell -For .... -h-\-",\ J; \\ ",,;nu.+CS. W,,-1-u-).,eJ. "'-SI~h-1 do: S£o)or +" ,-I. 'Pu.r~c €fI~e~ Mil. ~M?k.s c-D\la-h::d ttS US'S. L-e:&) Si+t= "'}-13M) TWN-0404-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N D D D D D ~ 2 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) [--------------------1 I OENlsoNI)J~1 ATTACHMENT 1 Attachment 1 ~~ See instruction WHITE MESA URANIUM MILL Iv MINI:S . =:J FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I 2..,,;j Q v..o.r=t=d ;.J ,'.:.\'r"j"e 2D \2. Sampler Name Location (well name)fI-T~W_tJ_-_O_S ________ ___I and initials: ::fAnner +iO)\l'J(k~IrH- Date and Time for Purgin~ Y / 1 ~ I $2..() J:L Well Purging Equip Used:OO pump o@ bailer pH Buffer 7.0 Specific Conductanc~l.__q_'_4.1...1~'___ __ ---I1 ~MHOS/ cm Depth to Water Before Purgin~ bi1 ,90 Conductance (avg) 3C>bJ and Sampling (if different) 1L-,v.~:1._;4 _______ ____1 Well Pump (if other than Bennet) Prevo Well Sampled in Sampling Event II._-._l _~_;-J_-_O_~ _____ __' pH Buffer 4.0 '-\.0 Well Depth(O.Olft): I } Sb,OO Casing Volume (V) pH of Water (avg) 4" well:1 ~. ~ IC.653h) 3" Well:. 1) .(.367h) /.0'1 Well Water Temp. (avg) I lLiA \ Redox Potential (Eh)1 7:J?';).... TurbiditYI._I 3_1 0 __ ---' WeatherCond. L-1 __ B_O'_Mi_~~_G_\_o~_'tJ __ ____' Time I D,\4~ Conductance I 3 0 bl Temp.oC Gal. Purged lL--l _E __ ---' pH !7,()4 Redox Potential Eh (m V) 1-1 _'3_3_1 __ --' Turbidity (NTU) Time 1 o1l4t..t Gal. Purged 1 L-...;..10---'-y_----' Conductance pH 1 7.0b Temp.oC Redox Potential Eh (m V) 1-1 _3_1.....:~:.....-_--1 Turbidity (NTU) 3,D White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. O( (prior sampling event)!L--~';""Z> __ --1 Time ! 0'\., 3 Gal. Purged 1'--....:.4 ___ 1 __ --' Conductance I :30b-;t pH I 7.005 Temp.oC 114.Q\ Redox Potential Eh (m V) 1-1 :s:t __ S __ __, Turbidity (NTU) 1 3.0 Time I O"YS Gal. Purged 1._1 ___ "_7 __ ---' Conductance 1 ~OG. 1 pH 1 "7,6$ Temp.oC Redox Potential Eh (m V) 1-1 '3_15 __ ---' Turbidity (NTU) '3.0 1 of 2 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged lL--l:.-l.....::1 ___ ....... Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = ,--I ----::;;\3"--_--' gallon(s) Time to evacuate two casing volumes (2V) T=2V/Q= I g,o~ I Number of casing volumes evacuated (if other than two) 0 '-----_.....I If well evacuated to dryness, number of gallons evacuated 1-1 _1> ___ .....1 N arne of Certified Analytical Laboratory if Other Than Energy La~L-_,/I/_I._I9-______ ----I Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y VOCs 0 0 3x40 ml 0 0 HCL 0 Nutrients rn 0 100ml 0 ~ H2SO4 rB Heavy Metals 0 0 250ml 0 0 HN03 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 Other (specify) III 0 Sample volume 0 ~ 0 C'n\o~J~ }<.. If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction An-; \led. 0", oS ,.te ~ 1-O'l3C> • -s;: fl ()er An). G-o. rf','" ?rdoG11 r ,£""r pv-rje ....... J. S", ""'f'l'J -e.--l (:",,1. ? \A~~ b~() ",t 6 "13 c.. P ",r ~d. j,Jc! \ ~.... '" .}cst-", 1 0+' q yv';".4-e..5. wc;,,\-e .... ~()b dew. P .... (~G Ghae~ 6<(l~ ~q,yllpl.:.> l.ollec1eJ ..... t C'14..S L~ ~\-t< d\-T Oq£o ' TWN-0504-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N 0 0 0 0 0 rEI 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) [------------------1 [OENISONi).4.4 ATTACHlVIENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL I MINE~_ ............... I FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I .2. n J\ Q,,",~r+e.(' j\.h t1"'-~e. A o,~ Sampler Name and initials: 1-rd>.1'\r\cr I"J 6 1]. JO\~IT J.1-Location (well name )~I-_~_~ W_N_-_O_k"---______ ----' Date and Time for Purgina L\/1 gl~l~ and Sampling (if different) 1-1 _#._:14 ________ ..... Well Purging Equip Used:[IDpump or@] bailer Well Pump (if other than Bennet) I G-Tw"\;;tf~.s Prevo Well Sampled in Sampling Event I I-_l'_v.l_IJV_-_1_Q. _____ --' pH Buffer 7.0 7.0 pH Buffer 4.0 Specific Conductance ...... 1 _dj_Cf ~-"--__ ----,I [lMHOS/ cm Well Depth(O.Olft): I ':3 O.co Depth to Water Before Purgina 15.~ Casing Volume (V) 4" well:1 3S,75 1(.653h) 3" Well: 0 (.367h) '--------' Conductance (avg) 1-1_'5:>_\..:_'0 _____ --' pH of Water (avg) Well Water Temp. (avg) 1 \ L\. q2, I Redox Potential (Eh)1 t).S2 Turbidity 1-.1 1.;...-6-:.../_1 _----' Weather Condo I 'PO\H-)('j clb",di Ext'l Amb. Temp. °C (prior sampling event)I,--]~_6 __ ....I Time I \ y,..g Gal. Purged I s;r: Time 11 '1420'1 Gal. Purged 11-.~ ___ --I Conductance I tf>'-1D Conductance 1533 pH 1 7 .1.5 Temp.oC Temp.oC 14 ~q I Redox Potential Eh (m V) 1 :::t.l;; I Redox Potential Eh (mV) 1 !l5Y Turbidity (NTU) 10 .. 3 Turbidity (NTU) 1 to.':[ Time I lq~D Gal. Purged 1-.1 _7...;;;g~_--I Time 119 51 Gal. Purged ...... 1 ..... 1+-1 __ ~ Conductance ...... 1 \_b_9_1_----' pHI 7.JLj Conductance 1 '593 pH I'.IL} Temp.oC Temp.oC I \9.Q4 Redox Potential Eh (m V) 1-.1 zt_'-i_Gj __ ....I Redox Potential Eh (mV) L...I ~_9....;;..g_----, Turbidity (NTU) Turbidity (NTU) \0-0 White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged ...... 1 _.....:.q ....... / ___ ....J gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I \~ T=2V/Q= I 5.50 I Number of casing volumes evacuated (if other than two) 0 L..-___ ....J If well evacuated to dryness, number of gallons evacuated b L..-___ ....J N arne of Certified Analytical Laboratory if Other Than Energy La~ ..... _M_/;..;...~ ______ ---, Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs 0 0 3x40 ml 0 0 HCL 0 0 Nutrients 129 0 100 ml 0 ~ H2SO4 J9 0 Heavy Metals 0 0 250ml 0 0 HN03 0 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 0 Other (specify) BJ 0 Sample volume 0 ID 0 19 6h\br~~C If preservati ve is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction A-rf;\le~ everr\-. ~-ter on .s,l\-e "'+ I~.?D. 'lMl'leI" MA G-... rr 1'1 Fl"eSG"+ +> plA(S~ GV7..i Sq",,?/) P W" ~ <:. b'Zj a." "" + 1'-12 Y , P \A.r~ ed well ~r 0... -io-fp,/ OP 7 /'V\ } ~ iT'-c.s, v.-XA.S cleo.f', PW'<!e Cf'\d.eJ "'t'\~ 5lW'IpJ.a Ll>\kcteJ Ikt-1'-131. Depth tl> ~<A.1-if u.)a,.s o3~51 ~~ .s,+c ~1-}z...J]£ TWN-0604-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r---··-·-------·----! !OENISON')~~1 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL .~~_......J FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: ! ;;2.T"IA Gv..o.r+er'" N ,-:trO\.-r(; :2-0\2.. Location (well name)~ ..... ~..;...W_N_-_O_l ________ ____' Sampler Name and initials: 1 10. (H1t..r ijo111d~~ /T'1f' Date and Time for PurginB L1! 14/.;LOI?. and Sampling (if different) 1 q/2...oj .2.o~i£ Well Purging Equip Used:[![] pump o@ bailer Well Pump (if other than Bennet) 1 G-rlAY'cAl~s Sampling Event !Q'--\(A\""fer 1.::\ ;V 'fro-+<:. Prevo Well Sampled in Sampling Event I TwN-\6' pH Buffer 7.0 pH Buffer 4.0 D.O Specific Conductance ..... 1 _q_~.....::'1~ __ ---,1 !!MHOS/ cm Well Depth(O.Olft): I iO~·OO Depth to Water Before PurginB g~.l~ 4" well:1 \ \,02: 1(·653h) 3" Well: 0 (.367h) '------~ Casing Volume (V) Conductance (avg) pH of Water (avg) Well Water Temp. (avg) 1 l'1 .. J~ Redox Potential (Eh)! 3 O~ Turbidity 1 g .0 Weather Condo 1 ___ ' _________ ---1 _ 60\Ad'/j Ext'l Amb. Temp. O( (prior sampling event)l ...... b_o __ ----I Time 1 04 J~ Gal. Purged ...... 1 _, ~ __ ----' Time Gal. Purged 1-1 ___ ---' Conductance I J 1 b3 Conductance pH 1...-1 __ ---' Temp.oC Temp.oC Redox Potential Eh (m V) I 301 Redox Potential Eh (m V) ..... 1 ___ ---' Turbidity (NTU) B.O Turbidity (NTU) Time Gal. Purged I'---___ ~ Time Gal. Purged 11.....-__ ----1 Conductance pH ...... I ___ ....I Conductance pH I-I ___ .....I Temp.oC Temp.oC Redox Potential Eh (m V) 1-1 ___ ----' Redox Potential Eh (m V) 1 ...... ___ --1 Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged II.--_'~"':"'-__ ----I gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I \2. T=2V/Q= I l.g3 I Number of casing volumes evacuated (if other than two) I L/'J.. If well evacuated to dryness, number of gallons evacuated N arne of Certified Analytical Laboratory if Other Than Energy La~L./'J._,/A _______ ---J Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as Type y N specified below) y N Y N VOCs 0 0 3x40 ml 0 0 HCL 0 0 Nutrients i:1 0 100ml 0 ~ H2SO4 l!1 0 Heavy Metals 0 0 250ml 0 0 HN03 0 0 All Other Non Radiologics 0 0 250ml 0 0 ' No Preserv. 0 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 0 Other (specify) ~ 0 Sample volume 0 111 0 1:1 Gh'O\""~aL If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction TWN-0704-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) [o:~~~ijjj i ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL I. MINtS .. FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: l ;l ,,6\ Qv..b..<+e(" .N\+rG-.1< ;J..O 102. Sampler Name and initials: I ""-~n(\er aon4iJ~~tnt Location (well name)~,-_--rvJ_N_-_O_g ________ ----.I Date and Time for PurginB u.J Ig/~D'~ and Sampling (if different) ,-I ~_/4. ________ --, Well Purging Equip Used:r![] pump o@ bailer Well Pump (if other than Bennet) ~v.f)~S Prevo Well Sampled in Sampling Event I '-_'T_W_N_-_l_~ _____ ---, pH Buffer 7.0 pH Buffer 4.0 Li.O Specific Conductanc~,---....;..1_q..;,..q ___ ....... 1 ~MHOS/ cm Well Depth(O.Olft): I \:::tD, 00 · 1 1<;5,.50 Depth to Water Before Purging b I. (;1 Casing Volume (V) 4" well:I S'-l.JI.} 1(.653h) 3" Well: 0 (.367h) '-------' Conductance (avg) ,-I _;2.:3 __ '_~ _____ --I pH of Water (avg) 1.b6 Well Water Temp. (avg) I 14 . £~ Redox Potential (Eh)lL..-L..ll,"",3~_.....I Turbidity ''-=:3...:..;:0=--_-.....1 WeatherCond. I ?D\,A"~ G10w).~ Exfl Amb. Temp. O( (prior sampling event),-I _7_0 __ -.....1 Time Gal. Purged' 7 ~ Time ID 80 7 Gal. Purged lL-q..L.l.-J __ --I Conductance I ::2.. ~ 4 ~ Conductance , ;2..35g Temp.oC Temp.oC I lq.5~ Redox Potential Eh (mV) ,-I ...;..1_19....:....-_---' Redox Potential Eh (m V) 11....:-11_° __ -.....1 Turbidity (NTU) Turbidity (NTU) Time 'O~og Gal. Purged ..... 1 ...:..10"-4-'--_--' Time I '-O_g_D_'1 __ --' Gal. Purged ..... 1 ..:...11;....:;7 __ --' Conductance 1 2.':) b Co( pH I 7,1:,0 Conductance LZ.37'-1 pH 17.5" Temp.oC I 14. S7 Temp. °C 1 I Lt.; 7 Redox Potential Eh (mV) ,-I ..;...\....;..1.,;..3 __ --' Redox Potential Eh (m V) ,-I _Jl_S __ --' Turbidity (NTU) Turbidity (NTU) 3.0 White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged 1,---...:...\ _11"""--__ ----' Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 1...-1 -...:.1;::_; __ ......1 gallon(s) Time to evacuate two casing volumes (2V) T = 2V /Q = 1 g. 4.2 I Number of casing volumes evacuated (if other than two) 1-1 _D ___ ....... If well evacuated to dryness, number of gallons evacuated b 1.--___ ......1 N arne of Certified Analytical Laboratory if Other Than Energy La~L-·_M_:l._f'} _______ --, Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y VOCs 0 0 3x40 ml 0 0 HCL 0 Nutrients ~ 0 100 ml 0 ~ H2SO4 ~ Heavy Metals 0 0 250ml 0 0 HN03 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 Other (specify) ~ 0 Sample volume 0 "'g] 0 Ghlo('~d( If preservative is used, specify Type and Quantity of Preservative: Comment ~ See instruction A,d-vea 00 ~*e q (Y1S'3 --rtJi.nY\ec O\"J &fJ\('r;" presef7t' -Gr furj€. AnJ ..s0\/Yl?]/~ 'evenT. fv.r~e be~OItl 0\-1 68l>o . ?v..r~t!!d ~e.1l ~r ~ +0+1).1 o-r '1 minv\+Gs . \..JO\.+~r wo..s cJ~a.r. Pv..,..~e. e:(\J.~~ (AnA SD\fV\p\e.;. wet"o(. (..on~J~J. 0..1 Ogoq, Le:~ sH-<. ~ 0813 TWN-0804-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N 0 0 0 0 0 --l9 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged L-I ---:l3"'-.b ___ ---I Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = ...... 1 --:,1_:z __ --I gallon(s) Time to evacuate two casing volumes (2V) T=2V/Q= 13.:11 I Number of casing volumes evacuated (if other than two) 11. '1 If well evacuated to dryness, number of gallons evacuated N arne of Certified Analytical Laboratory if Other Than Energy La~ ...... _M_Y:_I1 ______ ----, Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs D D 3x40 ml D D HCL D D Nutrients ~ D 100 ml D I!I H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) ~ D Sample volume D ~ D .eg [..h\Of'~e If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction AH' ;~e~ 0(\ s~tc:.. tA.+ 13~Y. \~n1'\c.r 6,."A &(l-T(;" p('e~ef\\-.foy ,?",(~E!.. ?v..rtc-b ej~)'\ P.. t )3:2.7 tJv.f"~-eJ. v.)e.1\ ~o("' (to,. 4-*~\ 6-\ 3 m~(\""t-e>. ?v..('~e~ we'\ ~-(~'. wo....+Gr "'-Jo.5. )N'I()~-t~ c.Jar. f",r~~ Ul~~~ ~ 133D. LeP-sl:h::. ",1-' 13~~ Arr:"e.J.. 01'\ &,'t-c. ~} ObSq. -(OI.nner Ana (;,CJ.rrJ'y\ p"..ac.n1-in c.oIlGV+ ..so.t1IJple!::o. D-c!~ 1-0 t.vq.-Jt.y" wo.s. b3, 05 S~Y"'\?1es lNere. bO\;lea o..-} 07 03. L~ ~~~ C\.-t' 07DS TWN-0904-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) jl o~~~.-~~~~ ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL ,_~INES FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I ;l n J Q v.. 0.. f"tc:.t' N'~ ro.. +'<:.. aJ) l ':L Sampler Name and initials: I ""-;nY'et'" t/~lI:J~/-n+ Location (well name)~L-_~_w_tJ_-_l_D ________ --, Date and Time for Purgin~ L..\ / I gl;)...O)~ and Sampling (if different) I LJ/lq 7a.o/~ Well Purging Equip Used:[]TIpump o@ bailer Well Pump (if other than Bennet) I Grv,ntI+b..s Sampling Event I Qv..lA..(OfGr}v., .N ~(J' <. Prevo Well Sampled in Sampling Event I ...... <'N_1 __ JJ_-_O_l _____ --' pH Buffer 7.0 7.D pH Buffer 4.0 4.0 Specific ConductancelL--_Dl;....:.qq..o.....-__ ...... 1 ~MHOS/ cm Well Depth(O.Olft): I 105,00 Depth to Water Before Purgin~ gO. g~ 1 Casing Volume (V) 4" well:I 1.5./~ i(·653h) 3" Well: b (.367h) L--___ ....J Conductance (avg) pH of Water (avg) ..... 1 _~_ .. b_:O _____ ----I Well Water Temp. (avg) I \S. ~(, Redox Potential (Eh)1 Ll q ~ Turbidityl i5.7 Weather Condo I ?o-.rd-I 'b C1o'-l.J. ~ Ext'l Amb. Temp. O( (prior sampling event) ..... 1 _1.5_· __ ........ Time 1 l.2D ~ Gal. Purged ..... 13_2: __ ---' Gal. Purged L-I ___ ---' Conductance I ~C.b9 pH I q, ()O Conductance Temp.oC 1 '\1;. be Temp.oC Redox Potential Eh (m V) 1 L\G\ '6 Redox Potential Eh (m V) 1 ,sg-~") I 1 Turbidity (NTU) l iS.7 Turbidity (NTU) Time Gal. Purged IL--___ ....J Time , 1 Gal. Purged IL--___ ....J Conductance pH 11.--__ ----1 Temp.oC Temp.oC Redox Potential Eh (m V) L-I ___ ---' Redox Potential Eh (m V) 1 C001 Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged 1-1 _~ ____ ---' Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = L-I _l~~ __ -----I gallon(s) Time to evacuate two casing volumes (2V) T = 2V/Q = 1 .?.\y~ 1 Number of casing volumes evacuated (if other than two) If well evacuated to dryness, number of gallons evacuated 1-1 3_:t. __ ----' N arne of Certified Analytical Laboratory if Other Than Energy La~L-_pJ_I_~ ______ ----I Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N Type Y N VOCs D D 3x40 ml D D HCL D D Nutrients 1:1 D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250 ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) E D Sample volume D ~ D ~ C.'h\o\~clc. If preservative is used, specify Type and Quantity of Preservati ve: See instruction Comment TWN-10 04-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) ,----------------IOENISOJ)j.4 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL MINES FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I ;l. ha Q"'CArtcr N 14ro-,=tc::. d..Ol~ Location (well name)~,--T_W_!V_-_l_l ________ --, Sampler Name and initials: -r0\(\ (lei H 0 Illj~ R~ Date and Time for Purging L1!1 q J ~6' q and Sampling (if different) Il-tv_IA ________ .....I Well Purging Equip Used:l~ Ipump o@ bailer Well Pump (if other than Bennet) Sampling Event I &v..~(fer-b .N ,+rCA.te Prevo Well Sampled in Sampling Event I I-_-r'_\JJ_N_-_lS ______ --I pH Buffer 7.0 pH Buffer 4.0 q.D Specific Conductanc~l-_q:""~"""' ___ --I1 IlMHOS/ cm Well Depth(O.Olft): 111..lX.OC Depth to Water Before Purging Gl1 1 93 4" well:147 .. 3g 1(.653h) 3" Well: 0 (.367h) '----_.....I Casing Volume (V) Conductance (avg) 1-1 _~_-::7_~_D _____ --I pH of Water (avg) Well Water Temp. (avg) I J 4.57 Redox Potential (Eh) I :3>1.)"3 TurbiditylL-::l-_, Cf=---_--I Weather Condo Time I {J 7 5=< Gal. Purged 1-1 _gY~_---I Conductance 1 Q..7gb Temp.oC 1 14.S9 Redox Potential Eh (m V) 1 3q7 Turbidity (NTU) Time 1 07l5t..J Conductance 1 :2.7g0 Gal. Purged 1 ..... _10.....;8'---_---' pH 1 7·64 Temp.oC IY.5b Redox Potential Eh (mV) 1 "3,43 Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. O( (prior sampling event)I-' _5_2$ __ ---, Time 075.,'3 Gal. Purged ,L.-Gf_"' __ ----' Conductance '27 gD pH I "1,0.5 Temp.oC 11Q·57 Redox Potential Eh (m V) 1-1 _~_q....;.q __ .....1 Turbidity (NTU) Time 1 07~ Gal. Purged L-11:..-:;.L) ___ .....I Conductance 1 2180 pH 1 7,D'-1 Temp.oC 1 1~.S7 Redox Potential Eh (m V) ..... 13;;;-.Y_O __ ---' Turbidity (NTU) 1 of 2 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged ..... 1 _12._0 ___ ---' Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 1..-1 ---.;1~:;2... __ ------, gallon(s} Time to evacuate two casing volumes (2V) T = 2V/Q = 17.~1 I Number of casing volumes evacuated (if other than two) 1 ..... _° ___ .....1 If well evacuated to dryness, number of gallons evacuated IL--D ___ .....I Name of Certified Analytical Laboratory if Other Than Energy La~L-M_fa-_______ -I Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N Type y VOCs D D 3x40 ml D D HCL D Nutrients "EI D 100ml D "E1 H2SO4 ~ Heavy Metals D D 250ml D D HN03 D All Other Non Radiologics D D 250ml D D No Preserv. D Gross Alpha D D 1,000 ml D D HN03 D Other (specify) ~ D Sample volume D !J D Gh'O\~a< If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction An'·;"\le6. 0/'\ ~n-e. 0\.1' D13~ -r~nner ~y\~ &t..\f,..;n f('~()-3-..f~r 'P~r~~ ~ .s.o.MF1:~ E\JeniJ fv.C~e.. b~o.n "';-0145" ?v..r~d w~.ll ,pot""" "'-1-01--",1 6~ 1D Y"l)·nv..+~. W~er l.No..s <:1<:4r. PUf"~~ efltAdt MJ s.o..fYlpl~ Gonede~ td--0755 . .De?t~ -h VJJer ~ "3,1../<::' Lt:-W ~~i-o ~tl-07 5~ TWN-1104-19-2013 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N D D D D D ltl 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) I-------------~ iOEN,SOJ)JJ I ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL ~ ___ ' ........ ft!'I!'!!!-FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 1 ;LYl ci G \A(},.rte.(" 2.D'~ /J l'fr~'f"< Location (well name)i ...... ~~-_W_!0_-_,_Q.. _______ ----' Sampler Name and initials: 1 ~}'l(JC:(" H 0 llJA~l1'lt Date and Time for Purgin8 '1/1 '6/ .').0)'2... and Sampling (if different) ,---~_/...;.A:::"-______ ----I Well Purging Equip Used:[!!] pump or@] bailer Well Pump (if other than Bennet) 1 (,-( u.('IClI~~.s Sampling Event I QJ:",(+<Yb ;V'T ( ... :r" Prev. Well Sampled in Sampling Event I -rV->N-D'-1 pH Buffer 7.0 -"D Specific Conductanc~ ...... ----,C1'--!.qq..£...-__ ---,1 ~MHOS/ cm Depth to Water Before Purgin8 a-.~ ~ 56 Conductance (avg) pH Buffer 4.0 L\:O Well Depth(O.Olft): 1 \)0.00 Casing Volume (V) pH of Water (avg) 4" Well:~(.653h) 3" Well:~(.367h) Well Water Temp. (avg) I ) "1. %4 Redox Potential (Eh) ...... 1 ....:..ltf.:...;O'---_ ...... Turbidity ...... l l_5_7 __ .....1 Weather Condo Exfl Amb. Temp. O( (prior sampling event) ...... 1 _'1_t> __ ---' Time 1134 \ Gal. Purged ...... 1 .-.,;q ..;,...J __ .....I Time 1 \~'1;;>" Gal. Purged ...... 1 ..;....\_O'i-'--_.....I Conductance 1 2.. t.\ ~ ~ pH 17,3 , Conductance 1 2. L\ 15 Temp.oC Temp.oC Redox Potential Eh (m V) ...... 1 _~_B_Z_--, Redox Potential Eh (mV) 1 18~ Turbidity (NTU) 1 \50 Turbidity (NTU) I lCS5 Time 1 \'£\:\:5 Gal. Purged ...... 1 .....;1L.;.J...L,7_---I Time I \:)\4 9 Gal. Purged ...... 1 ...;..:13:;...;0:::..-_---' Conductance 1 ,;L.q (;5 pH 1 7.~ Conductance I ,;z. q IN pH 1 / . 3:Z Temp.oC I lQ. 'in Temp. °C ,,4. ~ 1 1 Redox Potential Eh (mV) 1L--1'1.....;1 __ .....1 Redox Potential Eh (mV) ...... 1 _J9_5 __ ---' Turbidity (NTU) Turbidity (NTU) 11b..5 White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged 1L....-\_3e ____ .....1 gallon(s} Pumping Rate Calculation \-:)0 Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60= I ~ T=2V/Q= I g~l~ I Number of casing volumes evacuated (if other than two) 0 '"-----_ ..... If well evacuated to dryness, number of gallons evacuated t). L....-___ ....... N arne of Certified Analytical Laboratory if Other Than Energy La~L.-;""~_~:"';'~ ______ --' Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N Type y VOCs D D 3x40 ml D D HCL D Nutrients ~ D 100ml D ~ H2SO4 :@ Heavy Metals D D 250ml D D HN03 D All Other Non Radiologics D D 250ml D D No Preserv. D Gross Alpha D D 1,000 ml D D HN03 D Other (specify) 11:] D Sample volume D 'K1 D 0h1o'~~c.. If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction A~(:>le.~ 01'\ ~1+<:..:1 l33D, ~,,~er tN\~ Vo.rr;" f<'"e.setd-.ror 'P"'~~<: Mel. .s"vVlfl~ event Pw~e Ioef}"'/\"'~ 1~34. ?v..c-~...I. \>Xli f'or f)... ·h-ro.\ of ll> ,...,,',,I>.-t'e.:;.. ",\'len ,?vJ~G .st",,..fc;4 ~o\.f(;(" v.)~ o('().o('\ttJ~ b",--1" s1ov.)b c..)-GCM"'G~ ~ro~h O\A..1-The ?v.r~c. f'~\~-e, enJea qt1~ Sd\M~\~s, Gol1 ~(,1-Ga CA.-1-l~YY. Lc.H >{t<: 11\.-1 1 ~y 8. o -Gp~ ~o ~ CA-1e.r W lA,~ 8 ~. q J TWN-1204-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N D D D D D [J 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) I OENISONI)~~ I-··--···-···--·-·--------·-~--ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL ; MINES _. FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I 2. n Ii Q""o.(01"e(" N t~r~tG :l..C> 1~ Sampler Name and initials: -J~flner }-}o}J,'Ja..~/TH-Location (well name)~ ..... -r_w_N_-_l.J ________ __I Date and Time for Purging Y I J g 7 ~o 1 ~ Well Purging Equip Used:OOpump o@ bailer Sampling Event I Q\J\lArt-cr8 /'oJ I"+r£i\t.-e pH Buffer 7.0 7.D Specific ConductanceL..1 _~_q_4.L..-__ ---I1 ~MHOS/ cm Depth to Water Before Purgina 4 b.Os. Conductance (avg) and Sampling (if different) ..-v/A ~--------~ Well Pump (if other than Bennet) Prevo Well Sampled in Sampling Event I~T_vJ_JJ_-_l_3_R _____ --I pH Buffer 4.0 Well Depth(O.Olft): '4S. Sl) Casing Volume (V) pH of Water (avg) 4" well:i bl\.tlQ iC.653h) 3" Well:L-. _o __ .....1.(.367h) g.oo Well Water Temp. (avg) I I L\ ."1~ Redox Potential (Eh)1 1 S3 Turbidity I 1 0.'5 Weather cond'l L-__ P_fA_r_}_)-=~_G_\_O\A._J..f~ _ ____I1 Time 0,1.£ Gal. Purged L..I _10_4 __ ---1 Conductance ~77.1 Temp.oC Redox Potential Eh (mV) L..I _1 C:;_(J __ ~ Turbidity (NTU) Time I ',\7 Conductance I ~ bO Temp.oC I Ib,2 Gal. Purged I \ 3 C> pHI g.OI Redox Potential Eh (mV) L..ll_5_1:....-_---I Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater / Ext'l Amb. Temp. O( (prior sampling event)L-1 .....;b;....6 __ ......1 Time L-I O_J;...:..l...;;.'_---' Gal. Purged 1L-..:....;11.....:;7 __ ......I Conductance 873.::<. Temp.oC Redox Potential Eh (m V) I ..... .;....} 5..;;..5=-_--' Turbidity (NTU) Time 1 ..... 0_/-.:' g'=----_ ...... Gal. Purged ..... 1 -=-1l{3-=-_---' Conductance I ~.sg .1 pH I g.OI Temp.oC 1 1q.~ Redox Potential Eh (m V) L..I \:......4_9 __ ---1 Turbidity (NTU) 1 of 2 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (OAP) V olume of Water Purged L-I .-.,;1~Y.;:;;3 ___ ----J Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 1.-1 ---=13=---_----1 gallon(s) Time to evacuate two casing volumes (2V) T = 2V/Q = 1 q ,qq I Number of casing volumes evacuated (if other than two) .... 1_0 ___ ..... If well evacuated to dryness, number of gallons evacuated 1-1 _'0 ___ --1 N arne of Certified Analytical Laboratory if Other Than Energy LaijL.._/\.I._'/..;.;A~ _____ ----J Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs D D 3x40 ml D D HCL D D Nutrients ~ D 100 ml D f:I H2SO4 I!l D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) ~ D Sample volume D ~ D CII Gh)or;A1" If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction TWN-1304-18-2013 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r---------·---------·, ATTACHMENT 1 I OENISONI)~~!1 WHITE MESA URANIUM MILL Attachment 1 ~ See instruction ! MINIES ! FIELD DATA WORKSHEET FOR GROUND WATER D;;cription of Sampli~~ Event: 1 ~Y\6\ G\).o.r1-e.r N,'trCA.1"G 201~ Sampler Name Location (well name)~I-T_vJ_N_-_).3--.:.R~ ______ ----I and initials: l-ro..nnt!r Holl/'J~/1H Date and Time for Purgina '4/,g/~o\~ Well Purging Equip Used:~pump o@ bailer Sampling Event 1 Qv.~r+c:,r~ N i'ff"O\te. pH Buffer 7.0 1'---,--'-,0 ___ --' Specific ConductanceI-I _q....;...j.L..4..1.--__ ---I1 ~MHOS/ cm Depth to Water Before PurginSL-_o ___ ....I Conductance (avg) 0.0... and Sampling (if different) A//A '-------------' Well Pump (if other than Bennet) 1L-G-_t"_I..A_",_Jf_o_.s ____ --' Pre v . Well Sampled in Sampling Event I,--/'J._~_'A _______ ---, pH Buffer 4.0 ,-\.0 Well Depth(O.Olft): Casing Volume (V) pH of Water (avg) 4" well:~_o __ --1I(.653h) 3" Well:_ 0 J367h) Well Water Temp. (avg) 1 \5.4.3 Redox Potential (Eh)1-1 4_~_I __ ---, Turbidity II-0 ___ ---' Weather Condo I 0 .\ . 1 o-<"-t'~ G \ ow) ~ Ext'l Amb. Temp. O( (prior sampling event)I ..... .5_() __ ---' Time 1 6~3g Gal. Purged '--Il:....;;;g;.....-O_----I Time Gal. Purged 1-1 ___ ---' Conductance ().~ Conductance pH ,--I __ ----I Temp.oC Temp.oC Redox Potential Eh (m V) II.-LJ_"_l _---' Redox Potential Eh (m V) 1-1 ___ ---' Turbidity (NTU) 1 0 Turbidity (NTU) Time Gal. Purged 1-1 ___ -....I Time Gal. Purged 1-1 ___ -....I Conductance pH ..... I ___ --' Conductance pHL-I ___ ...... Temp.oC Temp.oC Redox Potential Eh (m V) .... 1 ___ ---' Redox Potential Eh (m V) 1'--___ ....1 Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged .... 1 _:;..._0_0 ___ ...... Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = L..-1 -.;.1=-3 __ ----' gallon(s) Time to evacuate two casing volumes (2V) T=2V/Q= 1 0 1 Number of casing volumes evacuated (if other than two) 0 '----_ ...... If well evacuated to dryness, number of gallons evacuated 0 '-----_......I N arne of Certified Analytical Laboratory if Other Than Energy La~L-_M_'/._A _______ --, Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N VOCs -0 0 3x40 mI 0 0 Nutrients "E1 0 100mI 0 'El Heavy Metals 0 0 250ml 0 0 All Other Non Radiologics 0 0 250ml 0 0 Gross Alpha 0 0 1,000 ml 0 0 Other (specify) 1;] 0 Sample volume 0 19 L-h' ol~cle Comment Ar(,,~\le.d on ~\-+~ (";"'1-0'-\0. 'R"1\$~-t~ be~~" 0..1--06\5 . 'Pv.tVlpeJ. ~D &tI\\\o~ So",,? \Norrer ",.,a lO() 6-Al1bn~ of' t::>I' ~cA+~r. R ' n.s(1.+e. ~o.Mrles tNere, c.ol1ec+eJ 6..1-0640. Left ~ite. ~+ Ob'15. TWN-13R 04-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Type y HCL 0 H2SO4 l:l HN03 0 No Preserv. 0 HN03 0 0 If preservative is used, specify Type and Quantity of Preservative: ~ See instruction SD &0.\1 onoS nGJd. Wo.to- ended. o..l1~ N 0 0 0 0 0 ~ 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) i ---·--·-··----·----------1 I OENISONI)~~i ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL ~!!!~S I FIELD DATA WORKSHEET FOR GROUNDWATER Description of Sampling Event: 1 ;2..nA Q\N).r+-a-N\*(o-..+~ .::2-O1~ Sampler Name Location (well name )i ..... TW __ N_-...-l;....I1 _________ --' and initials: 1 ~)1t1~1 Eo1\;JA~Jii.} Date and Time for PurginB '-\/1~/:;..ol~ Well Purging Equip Used:[~pump o@ bailer pH Buffer 7.0 7.0 Specific Conductance ..... 1 ~-=-q_q ____ ..... 1 !!MHOS/ cm Depth to Water Before PurginB a:. SS I Conductance (avg) 10;1.1 and Sampling (if different) 1 q/20Aw1~ Well Pump (if other than Bennet) I&("v..t\~s Prevo Well Sampled in Sampling Event I I..-nJ __ N_ .... _14 ______ .....J pH Buffer 4.0 11,Q Well Depth(O.Olft): 1 \3>5. ()~ Casing Volume (V) pH of Water (avg) 4" well:1 '47.30 1(·653h) 3" Well: b (.367h) L...-___ .....J Well Water Temp. (avg) 1 \ S· \~ Redox Potential (Eh) 1..-1 _1_8g~_-I Turbidityl112. :3 Weather Condo IL....-_C_'_owl_~ _______ ---I Ext'l Amb. Temp. O( (prior sampling event) 1.-1 ~,,_b __ ...... Time 110q:[ Gal. Purged .... 1 .s~~ __ ...... Time Gal. Purged ..... 1 ___ --' Conductance \O~J Conductance pH ..... 1 __ ----' Temp. DC Temp. DC Redox Potential Eh (m V) 1.-1 _1 ~_g __ --J Redox Potential Eh (m V) 1-1 ___ -.....J Turbidity (NTU) 19;):/3 Turbidity (NTU) Time Gal. Purged 1..-1 ___ -.....J Time Gal. Purged 1-1 ___ -.....J Conductance pH 11.-___ .......1 Conductance pH I.-I ___ .......I Temp. DC Temp. DC Redox Potential Eh (m V) ..... 1 ___ -----' Redox Potential Eh (m V) I ..... ___ -.....J Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged 1-1 _S_1 ___ ----' gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = 1 \~ T=2V/Q= 17.8& I Number of casing volumes evacuated (if other than two) I '·~o If well evacuated to dryness, number of gallons evacuated N arne of Certified Analytical Laboratory if Other Than Energy La~L..:~-..:...!1/J,--______ ......J Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as Type y N specified below) y N Y N VOCs D D 3x40 ml D D HCL D D Nutrients 'ij:I D 100 ml D ~ H2SO4 111 D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) l!l D Sample volume D KI D ~ Gh\O\;Je: If preservative is used, specify Type and Quantity of Preservative: Comment ~ See instruction TWN-1404-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r--------------, i OENISON~~~ ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL 1 MI ~ __ ...=J FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 1 ~ nJ. Q\MJ\f+ex-NI'trO\.+e ~I~ Location (well name )~L-~_W_tJ_-_15 ________ ----, Sampler Name and initials: I ::r;nn~THol1I4~r Date and Time for PurginB '-1!JQ / .a.0l~ and Sampling (if different) 1 YjMli..o 1':<. Well Purging Equip Used:~pump or@] bailer Well Pump (if other than Bennet) 16-rlAnJtbs Prevo Well Sampled in Sampling Event L-II'N __ AJ_-_)_&_~ _____ ..... pH Buffer 7.0 7.0 pH Buffer 4.0 4.0 Specific ConductanceL-1 _'"1.;...,1'1...:..~ ___ ---II ~MHOS/ cm Well Depth(O.Olft): L-I _lS_!:> ___ ...J Depth to Water Before Purgina ~,60S 4" well:1 4D.11 1(.653h) 3" Well: 0 (.367h) I.-___ ....J Casing Volume (V) Conductance (avg) pH of Water (avg) Well Water Temp. (avg) I 1t! ,8:2.. Redox Potential (Eh)1 3 blJ Turbidity 1 ;;4';)....' Weather Condo L-1 __ cJ_o_V._J_i ______ ---' Ext'l Amb. Temp. O( (prior sampling event)IL-5_o __ ....J Time 1 0 bSGj Gal. Purged 1 "12 L--7=~"""---....J Time Gal. Purged L-I ___ ----I Conductance I \ Sbg pH I /f~7 Conductance pH 1...-1 __ ----' Temp.oC 1 \9.'5X Temp.oC Redox Potential Eh (mV) 1 3(;'" Redox Potential Eh (mV) L-I ___ ----I Turbidity (NTU) 1 p:t. C; Turbidity (NTU) Time Gal. Purged IL--___ -' Time Gal. Purged 11..... ___ ---' Conductance pH ...... I ___ --' Conductance pH 1L--__ --oJ Temp.oC Temp.oC Redox Potential Eh (mV) 1.....1 ___ -.....l Redox Potential Eh (m V) IL-___ ....J Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (OAP) Volume of Water Purged 1 .... _7_;}... ____ ..... gallon(s} Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I 12.. T = 2V/Q = I 4:,,7<6 I Number of casing volumes evacuated (if other than two) I 1,7.(, If well evacuated to dryness, number of gallons evacuated N arne of Certified Analytical Laboratory if Other Than Energy La~L-_Al_/4 _______ --I Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N Type y N VOCs D D 3x40 ml D D HCL D D Nutrients 1!J D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) "tJ D Sample volume D ~ D tJ Ghlor;J( If preservative is used, specify Type and Quantity of Preservative: Comment ~ See instruction Arri\leA 0\'\ 5)t-", ... --t 06'lt;, \""O\Ilnel" 0VlJ. &"'(T;t\ pre.sen+--fOr F~e, R.r~<::: ~"'n £lit b653 P \A'-~....). "",,11 for "--h + '" \ of' (. f'Vl i >'l ""T6So . P v.r~;e~ w~1\ o\r.:j ~ p ",,"~G <!"deJ '" t 0 bS~ \Nt\.+er V:>~ MO.5.~ G1~o..c: Le.-P+ ~l~ ~.j-070Y. ' Arr;\j~~ C)(\ ~;+G 6..-1' OG:2.3. T~"niftAncA &A.rr:/\ p'fv~d\+~ c.ol1e c1--SCVvJp}GS. D~p+h +0 w~-rr.~ IN~ O12..1b_ ;)l1\.Mplt:'~ were-lo~,\leJ. 0..+ Ob:2.7, LcF-SJ~+e ~~Ob30 TWN-1504-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r---------·---, iOENISOJ).4.41 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL L-.~~_---.J FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 12."'c) Q""o.rl"~r N \~ro.,te .;2..01:<, Sampler Name Location (well name )~I..-_l _w_AJ_-_1 S_R~ ______ -....J and initials: I"'-"'J'lner HoI1J'J"'~rrH Date and Time for Purgina l.\ll~ / :2.01~ Well Purging Equip Used:[1[] pump o@ bailer pH Buffer 7.0 7.0 Specific ConductanceI-I _~.;...q...:.' ___ --,I !lMHOS/ cm Depth to Water Before Purginal..-__ C> __ --' Conductance (avg) o·b and Sampling (if different) 1..-1 ~~/..;...;.A-_______ ---, Well Pump (if other than Bennet) I G;-V\nJ.fo.S Prevo Well Sampled in Sampling Event I I..-_'_W_N_-_O_.b _____ --' pH Buffer 4.0 Well Depth(O.Olft): o Casing Volume (V) pH of Water (avg) 4" well:~-O-----fI(.653h) 3" Well:. () . (.367h) Well Water Temp. (avg) Redox Potential (Eh)1-1 _3_""" __ ---' Turbidity ,-I -=::0:..-_---' Weather Condo l ____ -=' _________ -....J _ G\bV.~ Ext'l Amb. Temp. °C (prior sampling event) ..... 1 _5_1> __ ---' Time I O'3~ Gal. Purged lL-l:...;~;....O __ ~ Time Gal. Purged 1-1 ___ ---I Conductance 0.5 pH I ~\53 Conductance pH &.-1 __ ---' Temp.oC \1.54 Temp.oC Redox Potential Eh (mV) 1-13--..;;.b-={)'---_--' Redox Potential Eh (m V) 1'--___ ...... 1 Turbidity (NTU) 1 0 Turbidity (NTU) 1 1 Time Gal. Purged ..... 1 ___ ---' Time Gal. Purged ..... 1 ___ ---' Conductance pH ..... I ___ --' Conductance pH L-I ___ ~ Temp.oC Temp.oC Redox Potential Eh (mV) 11-___ ---1 Redox Potential Eh (m V) 1-1 ___ ---I Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (OAP) Volume of Water Purged 1 L-_~_()_D ___ -I Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = &..-1 _13 __ ---' gallon(s) Time to evacuate two casing volumes (2V) T=2V/Q= 1 0 I Number of casing volumes evacuated (if other than two) 1"-0 ___ ....... If well evacuated to dryness, number of gallons evacuated 1L--l) ___ .....1 N arne of Certified Analytical Laboratory if Other Than Energy LaijL-rl._'I_A _______ --' Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs 0 0 3x40 ml 0 0 HCL 0 0 Nutrients ~ 0 100 ml 0 ~ H2SO4 ffi 0 Heavy Metals 0 0 250ml 0 0 HN03 0 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 0 Other (specify) rl:I 0 Sample volume 0 ~ 0 ~ ~h\or~tk If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction .Afri~~d on ~:·h .. ..} Ob\~. R;I\Sli..·h b~M o...} ObIS. P-"""p"d. 50 G-... UOh,s at Ac:J W"'+~J 1:,0 &...1\on.l. s,oo.. t> \,:) ... .te. 0.(\ a 10 i) Cr ... Jl 0" s of' o.x. w..der. 1<.; I\.$IA..+-e. en Jed "'" a St.iM b (,0 )l!:c+e~ 0--.+ Ob35. Le.+l-~'-~h~ ... ~+ Ob37 'P TWN-15R 04-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) ~E-N~S~NI).4 ~l ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL L MIN~S_~ FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I ~n (J\ Q\J-.o,:rfct N a:clA,"t<. .2.01;2,. Location (well name)~L-~ __ tJ_""-.!.l"';"' ________ ---I Sampler Name and initials: UY1}')Gt Ro)JJI(1.~IrJd- Date and Time for Purgin~ 1171~ 7;2.01~ Well Purging Equip Used:OOpump o@ bailer pH Buffer 7.0 Specific ConductanceI-I _j...Lq"':"~.A--__ ---I1 IlMHOS/ cm Depth to Water Before Purging Q7. gD Conductance (avg) and Sampling (if different) JJ/A ~--------~ Well Pump (if other than Bennet) Prevo Well Sampled in Sampling Event I I--r_\)J_N_ ... _O_1 _____ ...... pH Buffer 4.0 Well Depth(O.Olft): I \OO.OD Casing Volume (V) pH of Water (avg) 4" well:1 '34.og 1<·653h) 3" Well:L-. _0 __ ----1. (.367h) Well Water Temp. (avg) l )1t .qb Redox Potential (Eh)l :soq Turbidity I ..... 2_, y __ --' Weathercond'l I-_G_'_o_\,}..._A_1 _______ ____ Time Gal. Purged 1 ..... _'1_g __ --' Conductance pH I 7.J....1 Temp.oC Redox Potential Eh (m V) 1 ~,g Turbidity (NTU) Time I~I t>_O_D __ -, Gal. Purged 1-1 7_~ ___ -, Conductance Temp.oC Redox Potential Eh (m V) 1-1 _~_A'f __ .---- Turbidity (NTU) 2.\5 White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. O( (prior sampling event) 1 ..... 7_) __ --' Time I O'fb1 Conductance I J ~5~ Temp.oC 1 lY.1 0 Gal. Purged L-I _b_O __ --' pH I 7,J..) Redox Potential Eh (mV) 1 '3D~ Turbidity (NTU) Time 1-11;.....0_0_' __ .....1 Conductance 1 ,898 Temp.oC Gal. Purged 1-1 _8_'"4 __ .---- pH 17,21 Redox Potential Eh (m V) 1-1.2._q"' __ ---I Turbidity (NTU) 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged IL.--";:;~""':Y ___ ......I gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = ,--I -....:.1.;t.. ___ ....... T=2V/Q= I s.bi I Number of casing volumes evacuated (if other than two) () '----_ ........ If well evacuated to dryness, number of gallons evacuated 0 1--___ .....1 N arne of Certified Analytical Laboratory if Other Than Energy La~L-/'J---..;.~_~ ______ ---, Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y VOCs 0 0 3x40 ml 0 0 HCL 0 Nutrients ttl 0 100 ml 0 ~ H2SO4 ~ Heavy Metals 0 0 250ml 0 0 HN03 0 All Other Non Radiologics 0 0 250m! 0 0 No Preserv. 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 Other (specify) ra 0 Sample volume 0 ~ 0 Ch)orJ'a"( If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction A(f"l\l~a 00 ~I~c:. q..-!, oqso -ro..rtlle(' fArI~ &~rr~'.n pr~~nt -tor r)\"tje q.(Jo\ S(/.f11f \~ e\Jen-1. P\l\'~e.. bv~O\('\ O'o~ O'1SLl. P",rfleA vJel1 +01'" "" -h:rt~\ o~ 7 M/~\A+~S, '" o..h( w <>.5. C 1 "'....... P 1.\.( ~'" "'''' J,~ (}..YI,). ~f"IpJ~ Co J) eG +d ,,:1-100 I. D "P~/' +(J Wa. fer WlA.S. Lil\,~L\. Le.,f} $,1-G ~t IDOL1. TWN-1604-l9-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N 0 0 0 0 0 JXI 2 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) !-------------···----I I ()EN,soNl)j~1 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL L ,MI"!.~____ FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I:;... YI a Q\A~A~r AJA'",,,,,fG :1.. Ol::l. Location (well name )il-_-r_vJ_tJ_ ... ..:....17=----_______ -----1 Sampler Name and initials: l~nt'lG{" HolLJD-j~ Date and Time for Purgin8 gI1~7.20'o... and Sampling (if different) 1-1 ~_1_1~_Q7_!J,._o_1-::t _____ -, Well Purging Equip Used:OOpump o@ bailer Well Pump (if other than Bennet) 1 &(,l.\.'f\JJ~s Sampling Event 1 Q""o..r:t~r b N it rod: ~ Prev. Well Sampled in Sampling Event L-1_-r_W_N_-_'_' _____ -' pH Buffer 7.0 pH Buffer 4.0 Specific ConductanceI-I _4-=-q_~=----__ --,1 ~MHOS/ cm Well Depth(O.Olft): 1 11 C> .00 Depth to Water Before Purgina ~ 3 . 'f D 4" well:1 LlGJ.G,'J 1(·653h) 3" Well: 0 (.367h) '------' Casing Volume (V) Conductance (avg) 11~S pH of Water (avg) 7.'1J Well Water Temp. (avg) 1 1 S.O'i Redox Potential (Eh)L-,1 "3_6_D __ ---I Turbidity I 77, I Weather Condo Ext'l Amb. Temp. °C (prior sampling event)lL...,;l_ll> __ ----' Time 112f:,LJ Gal. Purged L-I 7~g __ ...... Time Gal. Purged 1-1 ___ --' Conductance I \) 3:S pH 1 7.q7 Conductance pH 1..-1 __ -----I Temp.oC 1 )5.04 Temp.oC Redox Potential Eh (m V) 1 ~<OO Redox Potential Eh (m V) L-I ___ --' Turbidity (NTU) 1 77.1 Turbidity (NTU) Time Gal. Purged IL--___ ..... Time Gal. Purged IL--__ ---' Conductance pH IL--__ ---' Conductance pH 1-.1 ___ --' Temp.oC Temp.oC Redox Potential Eh (m V) 1-1 ___ ---I Redox Potential Eh (m V) 1-1 ___ ---I Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (OAP) V olume of Water Purged L-I __ ,.<...;g=-_----' Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = L-I _'_~ __ ----I gallon(s) Time to evacuate two casing volumes (2V) T = 2V/Q = I 2S .. ,'2.~ I Number of casing volumes evacuated (if other than two) 1 )_S~ If well evacuated to dryness, number of gallons evacuated 173 N arne of Certified Analytical Laboratory if Other Than Energy La~L...M_~_:Ar _______ -J Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs D D 3x40 m! D D HCL D D Nutrients ~ D 100 ml D ~ H2SO4 .. ~ D Heavy Metals D D 250m! D D HN03 D D All Other Non Radiologics D D 250m! D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) m D Sample volume D g D ~ Ch\o,\~J< If preservative is used, specify Type and Quantity of Preservative: Comment ~ See instruction Auive! 0>" $'+" (Ai-1:J.4'1 -r'Mn~r GV1~ G-""rj.., r-r<:l"Ylt -1=0 ... p"''Zr P"'(Ji" b,(!",n tifT 1;2.'-18, P",,.~{.<\. ""e.1I +Dr f1.-i-.. '\-..J ".f' " M;",j-~ d\t'\a 30 St::~YlJ.s. P\A.r~Gd ~I\ J.r.j 1 P ,,-r~ et\J. ... ). ... t' 1:2.l)L-l, ~ ~~ if h .. ).....s \ ~~ J. ',Sc.O\br . L ~ S ,te G.-\-1::1..S& Af'("i\Je).. 01\ ~,\t-~ 1\.1-OG>53\ -r;:Y\1'\U ~f\~ (ro-..Y'(l'r. p,es~Y\t +0 C611<..c..t .5iAM p/f!,5. O~pth +l> v.:>o..1-Gl" w~ "3'-1. &' S , ~~~f>les welG boq·1~ol 0\,+ OhS".. Left s.jtG o..-r 0 (;, 5~ TWN-1704-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) r----------------.. ·--I I OENISONr;,~~ ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL L-!t'~~S I FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: I :L 1"11\ Q '-\()., .... +er IV ;J"r;J~ :J-C> 1 ~ Sampler Name Location (well name)~ ..... -r...:.-W_N_-...;,.18=--________ --I and initials: I :::Y;ntl~r +b1J;dAj/T-H Date and Time for Purgina L)/ 1~/:;",ol:1 Well Purging Equip Used:OOpump or[QJ bailer Sampling Event I Qv.o..rterh A);t,«<. pH Buffer 7.0 7.D Specific ConductancelL..-..1Q....L.1..L,.Q ___ --II ~MHOS/ cm Depth to Water Before Purgina S -, #i25 Conductance (avg) ..... 1 .:;;;:2.=..:..I~b.3=--_____ --I and Sampling (if different) .... I .M_VA ________ ...... Well Pump (if other than Bennet) I ~\At'lJfb..s Prevo Well Sampled in Sampling Event .... 1_-rft.J __ /J_-_,_l _____ -"""'" pH Buffer 4.0 Well Depth(O.Olft): I 145.00 Casing Volume (V) pH of Water (avg) 4" well:1 51·00 1(·653h) 3" Well: 0 (.367h) '----_ ...... Well Water Temp. (avg) I 14.3'-1 Redox Potential (Eh) ..... I -s_:>_GJ_--, Turbidity ..... 1 q_tt.L--_--' Weather Condo ..... 1_0 __ 'o_u_d---'o:i'J-I---______ ---' Time Gal. Purged ..... 1 _q_~ __ ...... Conductance 1 ;2..1 ~ 4 Temp.oC Redox Potential Eh (m V) 1 .... '5_45=---_---' Turbidity (NTU) Time I o~YL.} Gal. Purged 1 ..... 1_2:_0 __ ...... Conductance I :l\ 65 pH I 7.1& Temp.oC 1 1u.'55 Redox Potential Eh (m V) 1 3=:5C; Turbidity (NTU) 1411. GO White Mesa Mill Field Data Worksheet for Groundwater Ext'J Amb. Temp. O( (prior sampling event)IL-.-'6_o __ ....I Time Gal. Purged ...... 1 _10_& __ ...... Conductance 12 \ b':i Temp.oC 114/"55 Redox Potential Eh (m V) 1 3 43 Turbidity (NTU) Time I Og\.}~ Conductance 1 2.1 "7 Temp.oC Gal. Purged I ...... J_3_:t __ ...... pHl 7.lg Redox Potential Eh (m V) 1 335 Turbidity (NTU) 1 of 2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged 1-1 ...... }-=~:;..O";-.;.... __ ----I gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = 1 ..... _':2... ___ --' T = 2V/Q = I ~. E>O I Number of casing volumes evacuated (if other than two) I e If well evacuated to dryness, number of gallons evacuated o N arne of Certified Analytical Laboratory if Other Than Energy La~,-_'/v'_~_~ ______ ---, Sample Taken Sample Vol Filtered Preservative Preservative Added Type of Sample (indiCate if other y N than as specified y N Type y N VOCs D D 3x40 ml D D HCL D D Nutrients r:J D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) ll5J D Sample volume D 'f:] D ~ Gh\o,~J"( If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction Arf':" ed. on s ,,+,,, "d-M,3D -r",nl'ler <O\J'ld 6-<..rr,''1 p ('«s.ent Ji,... Y"'[je~;J.A S Ql'>1p7(j e-Je-;1: f V.ZF .b~ ... '\ 171. j 0 lS ':>'-1, P IA"~-e.<\ we 11 .f;,,.. ().. ht"l.l or II ,., i Ill.\.-re.s.. water wo.> }'V'\~'\:!j C-\eA(". ?v..,~e. 'eY"I(1ea tkl\a SaMples Go neet~ ~+ o<&,y 5. LeJ.} s/'1-e q +-C8LJ1 D~J1-h +0 w~1-eI ~o.S 5'11/3 TWN-1804-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) OENISONr;,~~ ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL ifI MINES FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: ,;t"a Qv.,o..rh:r A> ,:troJc ~Ol~ Sampler Name Location (well name)~ ..... -r_W.....;j\J_-....:.lq..l..-________ ---I and initials: '--r~l'1n~r Ro }})'J~ /TH Date and Time for Purgin~ Ll/IGl/.2.01';).. Well Purging Equip Used:OOpump or@] bailer Sampling Event , Quu.r·tc:rlj Nitrod"< pH Buffer 7.0 I.D Specific Conductance ...... ' _~....:...q.....;q~ __ ---II [!MHOS/ cm Depth to Water Before Purgina 52.. 4 ~ Conductance (avg) and Sampling (if different) ..... , _,lV.....;yA~ _______ -..I Well Pump (if other than Bennet) 1 &rv.napo,S Prevo Well Sampled in Sampling Event ..... 1_-r_W_0J_-_}t..j _____ ~ pH Buffer 4.0 Y,D Well Depth(O.Olft): ..... 1 _11_0_,0_0 __ ----' Casing Volume (V) pH of Water (avg) 4" Well:f3T.5Tl(.653h) 3" Well:~(.367h) Well Water Temp. (avg) 115,4.5 Redox Potential (Eh)....::;L2;...;;.l..;..&.] __ ..... Turbidity I .... .;....) o_. ~ __ ..... Weather Condo Ext'l Amb. Temp. °C (prior sampling event)lL-l.;...l_~ __ -..I Time Gal. Purged IL--y...;;.,g __ -..J Time Gal. Purged ..... 1 '" ____ 0 __ ---' Conductance Conductance I lq13 Temp.oC Temp.oC I 1~.3g Redox Potential Eh (m V) I '-\'2-Redox Potential Eh (m V) ..... 1 _2_1_1 __ ..... Turbidity (NTU) 1 \O.S Turbidity (NTU) I lO.' Time 1 \2.01 Gal. Purged ..... 1 _7~ ___ -..I Time 1 1.2D~ Gal. Purged ...... 18_Y ___ -..I Conductance I lq~O Conductance pH I 7·4D Temp.oC Temp.oC tS. bD Redox Potential Eh (m V) 1 2.12. Redox Potential Eh (m V) I .2,)~ Turbidity (NTU) Turbidity (NTU) 10.7 White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged L-I _~;;;;;"~"':"-___ ....I Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = L-I ---I.-1~~_-----I gallon(s} Time to evacuate two casing volumes (2V) T=2V/Q= I G.~' I Number of casing volumes evacuated (if other than two) ..... 1 _0 ___ ..... If well evacuated to dryness, number of gallons evacuated L-I 0 ___ ----' N arne of Certified Analytical Laboratory if Other Than Energy La~L._.N._'/_~ ______ ---I Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) y N Type y VOCs 0 0 3x40 ml 0 0 HCL 0 Nutrients rn 0 100 ml 0 ~ H2SO4 ~ Heavy Metals 0 0 250ml 0 0 HN03 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 Other (specify) Q1 0 Sample volume 0 ~ 0 GhlD'f:d{ If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction A((";v~~ 01) ~"t~ ~-r n SD ~nhcr GtY1&\ frArr//l pre.5en.r..for pV'(j~ AnJ ..,sq)l1p)'(j -evan-1:- r "'(6"" ~'" 1'\ Ii\. t 11 S S . p",..-~ ""ell -t,;,.. ... .}o.} ~I .,..r 7 ,., j " ,,"+-e~ W.rr", ""'-S M D s·H J (..\eo...('. fv."'~ e..t1a~~ IN'\~ ~p\e;. \,..>e,r< c.o\\~d~~ 0...-\ \2..~. Depth +6 v.)o..-t~( wo..S \O~'\7 Le.++ ~i-te. ~-1 }2°C,. TWN-1904-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater N 0 0 0 0 0 ~ 2 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (OAP) :----------------, iOENISONi)jjl ATTACHMENT 1 Attachment 1 WHITE MESA URANIUM MILL ~ See instruction L M1NI:S FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: , ;l n« Q",o.:r-h: .. -r Ah"+ro-.f4t. .2.0 1 ~ Sampler Name Location (well name)~,----n_w_/J_-_~_b _______ ----, and initials: '~}'\()~Y-Hal J J'J~;j/171- Date and Time for PurginB 11/2.0/;2.Dl~ Well Purging Equip Used:[gJpump o@ bailer Sampling Event 'QvVA('fer~ "./\'X·h-""t< pH Buffer 7.0 1-.'_7~.O ___ -..I Specific Conductance .... ' _tl_GJ....;.1 ___ --" ~MHOS/ cm Depth to Water Before PurginBI-_O ___ .....I Conductance (avg) O.~ and Sampling (if different) ,A// A ~~~-------------.....I Well Pump (if other than Bennet) .... , ~ __ ~....;I+:....-________ --, Prevo Well Sampled in Sampling Event 1-1 ,_"_\. ... _J _v ______________ .....1 pH Buffer 4.0 , Ll.D Well Depth(O.Olft): Casing Volume (V) pH of Water (avg) 4" well:~--:() __ --fI(.653h) 3" Well:, I::> ,(.367h) 'Pi ~-z.-0' Well Water Temp. (avg) 'I g.:L3 Redox Potential (Eh)',-~_'4_7 __ --, Turbidity ,'--0_"_'5 __ --' Weather Condo Ext'l Amb. Temp. O( (prior sampling event) .... ' _.2._0_° __ .....1 Time '\32'1 Gal. Purged .... , _0 ___ .....1 Time Gal. Purged ,'---__ --..I Conductance '0 I ~ pH ' 7.55 Conductance pH ,'--__ --' Temp.oC 11&/23 Temp.oC Redox Potential Eh (m V) 1-1 ~_9_7 __ .....I Redox Potential Eh (m V) 11--___ .....1 Turbidity (NTU) 10·5 Turbidity (NTU) Time Gal. Purged .... 1 ___ --' Time Gal. Purged .... 1 ___ --' Conductance pH 1-.1 ___ --' Conductance pH 1-.1 ___ --' Temp.oC Temp.oC Redox Potential Eh (m V) 11--___ .....1 Redox Potential Eh (m V) .... 1 ___ --' Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) V olume of Water Purged ..... 1 _0 ____ ...... Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = I 0 gallon(s) Time to evacuate two casing volumes (2V) T=2V/Q= I 0 I Number of casing volumes evacuated (if other than two) 0 '----_ ...... If well evacuated to dryness, number of gallons evacuated 0 '----_ ...... N arne of Certified Analytical Laboratory if Other Than Energy La~L-_/'J._Y:_'lt ______ ----, Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol Filtered Preservative Preservative Added Type of Sample (indicate if other y N than as specified y N Type y N VOCs 0 0 3x40 ml 0 0 HCL 0 0 Nutrients ~ 0 100 ml 0 ~ H2SO4 ~ 0 Heavy Metals 0 0 250ml 0 0 HN03 0 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 0 Other (specify) ~ 0 Sample volume 0 ~ 0 ~ c.-h \ or J'de If preservative is used, specify Type and Quantity of Preservative: See instruction Comment TWN-60 04-20-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) 1------·-·-----------, !j)ENISONr;)~~1 ATTACHMENT 1 Attachment 1 ~ See instruction WHITE MESA URANIUM MILL J _ M~!'I£S FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event: 1 ~ na QW>.r+e~ N(tro...tc .2.01~ Location (well name)i ..... -r_w_JO_-_Q; _________ --I Sampler Name and initials: 1"1' 1'-nne, }Jo 1I.JA.j /11J Date and Time for Purgina '1/) g/ :;LDJ":l-, Well Purging Equip Used:~pump o@ bailer pH Buffer 7.0 Specific Conductance ..... 1 _~..:..~.:....q':"'-__ ....II !!MHOS/ cm Depth to Water Before Purgin~ L\ 0 . 7 D Conductance (avg) \o1:{3 and Sampling (if different) ..... 1 ~_~A ________ ....I Well Pump (if other than Bennet) 1 &r""Y'\Ji~.s l -rvJN-/O Prevo Well Sampled in Sampling Event ..... _________ ....1 pH Buffer 4.0 Well Depth(O.Olft): I 1:2.5.70 Casing Volume (V) pH of Water (avg) 4" well:I 55.3 0 1(.653h) 3" Well: 6 (.367h) '---___ ....I Well Water Temp. (avg) I ll.\ .q.:t Redox Potential (Eh)1 ~32> TurbiditYI.-I ~11...:::.8 __ --, Weather Condo Ext'/ Amb. Temp. °C (prior sampling event)II.-_1_/7J __ --' Time Gal. Purged 1.-1 ___ --' Time Gal. Purged ..... 1 ___ ---' Conductance pH 1.0-1 __ ----' Conductance pH 1.0-1 __ ----' Temp.oC Temp.oC Redox Potential Eh (m V) .... 1 ___ ---' Redox Potential Eh (m V) ..... 1 ___ ---I Turbidity (NTU) Turbidity (NTU) Time Gal. Purged .... 1 ___ ---' Time Gal. Purged 1"--__ ---' Conductance pH ..... 1 ___ --' Conductance pH ..... 1 ___ --' Temp.oC Temp.oC Redox Potential Eh (m V) IL--___ -I Redox Potential Eh (m V) .... 1 ___ ---' Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (OAP) Volume of Water Purged I ..... __ l~ ___ ---, gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I \3 T=2V/Q= 1 g.53 I Number of casing volumes evacuated (if other than two) ..... 1 _0 ___ -, If well evacuated to dryness, number of gallons evacuated ..... 1 0 ___ ---' N arne of Certified Analytical Laboratory if Other Than Energy La~,-_/V.....;/;,-i9 _______ ---, Sample Taken Sample Vol (indicate Filtered Preservative Preservative Added Type of Sample if other than as y N specified below) Y N Type y N VOCs D D 3x40 ml D D HCL D D Nutrients "tI D 100 ml D ~ H2SO4 ~ D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiologics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) ~ D Sample volume D 1!9 D ~ Ch\O(;~~ If preservati ve is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction TWN-6504-18-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of2 Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) [~~~M"~N-~~s·.-i),~l, WHITEA~~~=~I~~ MILL L....-_,_ -=, ..-J FIELD DATA WORKSHEET FOR GROUND WATER Attachment 1 ~ See instruction Description of Sampling Event: ! ~ IAcA Q V c...f" t C,r .,AI, f'c~t Cd ~ Q I 2= Location (well name)i T W.AI .... 70 Date and Time for Purging Y I \ q / /);0 I ~ Well Purging Equip Used:OO pump o@ bailer Sampling Event ! Q UOJf"+P'r'V'I ./V'hi pH Buffer 7.0 7./ C5 Specific Conductanc~ q q CJ !flMHOS/ cm Depth to Water Before Purging Q2, 65 Conductance (avg) J56S? Sampler Name and initials: GCNrt'~V\.J (Jev\~vr and Sampling (if different) y / ~O I ~b 1 -;(. Well Pump (if other than Bennet) Pre v . Well Sampled in Sampling Event IT' \,J IV'..J I bR pH Buffer 4.0 Well Depth(O.Olft): Casing Volume (V) pH of Water (avg) 4" well:1 3" Well: 1.55 1..>/ 0.71IC.653h) 25 (.367h) Well Water Temp. (avg) I J Y l 6~ I Redox Potential (Eh)1 369 Turbidity I "2 ;2.6 I Weather Condo Ext'l Amb. Temp. O( (prior sampling event)! _'5 f) Time Gal. Purged 1...-1 ___ --' Time Gal. Purged I I...-___ ......I Conductance pH ....... 1 __ ----' Conductance pH L-I __ ----I Temp.oC Temp.oC Redox Potential Eh (m V) 1...-1 ___ --I Redox Potential Eh (m V) 1...-1 ___ --I Turbidity (NTU) Turbidity (NTU) Time Gal. Purged 1...-1 ___ --I Time Gal. Purged 1...-1 ___ ......I Conductance pH I...-I ___ ......I Conductance pH L-1 ___ .....I Temp.oC Temp.oC Redox Potential Eh (m V) 11...-.. __ --' Redox Potential Eh (mV) 1 I...-___ ......I Turbidity (NTU) , Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater 1 of 2 Mill-Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (OAP) Volume of Water Purged ..... 1 __ 7l..-sr.2::::!..-_---' gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = I 1 ~ T=2V/Q= I 6,,7~ I Number of casing volumes evacuated (if other than two) 1.,7 1z 1 72-I If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy La~ ..... _ ..... ./V~/ ..... A'--'"-____ --, Date: 03/22/2010 Rev. 6 Sample Taken Sample Vol Filtered Preservative Preservative Added Type of Sample (indicate if other y N than as specified y N Type y N VOCs 0 0 3x40 ml 0 0 HCL 0 0 Nutrients Il1 0 100 ml 0 S H2SO4 ~ 0 Heavy Metals 0 0 250ml 0 0 HN03 0 0 All Other Non Radiologics 0 0 250ml 0 0 No Preserv. 0 0 Gross Alpha 0 0 1,000 ml 0 0 HN03 0 0 Other (specify) ~ 0 Sample volume 0 S 0 %l 6 k \or-\ cA6 If preservative is used, specify Type and Quantity of Preservati ve: Comment ~ See instruction TW/\/-15 TWN-70 04-19-2012 IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 TabC Kriged Current Quarter Groundwater Contour Map and Depth to Water Summary TIME WELL 1019 MW-1 1024 MW-2 1359 MW-3 1400 MW-3A 1101 MW-5 1104 MW-11 1058 MW-12 1031 MW-14 1035 MW-15 1408 MW-17 915 MW-18 924 MW-19 1339 MW-20 1345 MW-22 1053 . MW-23 1050 MW-24 1048 MW-25 1035 MW-26 1040 MW-27 1050 MW-28 1036 MW-29 1038 MW-30 1036 MW-31 1042 MW-32 1104 MW-33 1044 MW-34 1055 MW-35 1047 MW-36 1039 MW-37 Static level 64.66 109.70 83.20 85.26 106.45 88.15 108.63 103.88 106.60 74.66 70.28 52.08 88.93 67.10 114.27 114.34 73.78 68.16 51.00 76.59 102.01 75.90 68.00 74.80 DRY 108.40 112.50 110.60 108.45 NAME: DATE: TIME WELL Static Level 757 MW-4 71.04 800 TW4-1 64.92 812 TW4-2 66.85 823 TW4-3 50.20 841 TW4-4 70.00 826 TW4-5 56.78 814 TW4-6 69.98 849 TW4-7 67.86 817 TW4-8 66.50 823 TW4-9 54.75 803 TW4-1O 56.34 839 TW4-11 57.80 814 TW4-12 47.18 852 TW4-13 47.17 820 TW4-14 86.80 831 TW4-15 68.07 844 TW4-16 60.12 805 TW4-17 74.92 851 TW4-18 56.61 808 TW4-19 59.00 853 TW4-20 61.76 847 TW4-21 54.09 819 TW4-22 53.38 809 TW4-23 64.76 821 TW4-24 54.81 850 TW4-25 47.50 827 TW4-26 63.45 830 TW4-27 83.01 Tanner Holliday, Garrin Palmer 6/28/2012 TIME WELL 1418 PIEZ-1 1409 PIEZ-2 1411 PIEZ-3 1416 PIEZ-4 1413 PIEZ-5 1430 TWN-1 1442 TWN-2 1433 TWN-3 1457 TWN-4 1444 TWN-5 1437 TWN-6 1450 TWN-7 1454 TWN-8 1500 TWN-9 1459 TWN-lO 1516 TWN-11 1515 TWN-12 1503 TWN-13 1514 TWN-14 1519 TWN-15 1504 TWN-16 1507 TWN-17 1512 TWN-18 1509 TWN-19 Static Level 61.52 21.28 40.29 47.80 42.80 51.57 21.02 32.83 41.03 69.55 74.62 88.39 61.64 62.90 80.82 69.41 28.50 46.02 62.43 92.00 47.85 33.87 58.40 52.50 We split up to complete depth checks so some times may be the same. TIME WELL Static Level NA DR-1 ABANDON NA DR-2 ABANDON 1234 DR-5 83.2 1241 DR-6 94.37 1425 DR-7 92.18 1249 DR-8 51.05 1246 DR-9 86.69 1244 DR-10 78.05 1353 DR-11 98.35 1356 DR-12 88.55 1405 DR-13 70 1302 DR-14 76.55 1332 DR-15 93.05 NA DR-16 ABANDON 1305 DR-17 64.9 NA DR-18 ABANDON 1309 DR-19 63.3 1319.00 DR-20 55.3 1326 DR-21 107.38 1329 DR-22 Dry 1323 DR-23 70.77 1313 DR-24 43.95 NA DR-25 ABANDON @ Estimated dry area M:-5 perched monitoring well showing 5503 elevation in feet amsl TW4-12 temporary perched monitoring well 0 5577 showing elevation in feet amsl TWN-10 ~5586 temporary perched nitrate monitoring well showing elevation in feet amsl PIEZ-1 perched piezometer showing ~ 5594 elevation in feet amsl TW4-27 temporary perched monitoring well ~ 5525 installed October, 2011 showing elevation in feet amsl RUIN SPRING b 5380 seep or spring showing elevation in feet amsl HYDRO GEO CHEM, INC. NOTE: MW-4, MW-26, TW4-4, TW4-19, and TW4-20 are pumping wells KRIGED 2nd QUARTER, 2012 WATER LEVELS WHITE MESA SITE APPROVED DATE REFERENCE FIGURE H:/718000/aug121UwI0612_rev.srf C-l TabD Kriged Previous Quarter Groundwater Contour Map ~ Estimated dry area M.W'5 perched monitoring well showing 5503 elevation in feet amsl TW4·12 . . O temporary perched momtorlng well 5577 showing elevation in feet amsl TWN·10 A,5586 temporary perched nitrate monitoring V well showing elevation in feet amsl PIEZ·1 perched piezometer showing ~ 5594 elevation in feet amsl TW4·27 temporary perched monitoring well *5525 installed October, 2011 showing elevation in feet amsl RUIN SPRING b 5380 seep or spring showing elevation in feet amsl HYDRO GEO CHEM, INC. NOTE: MW-4, MW-26, TW4-4, TW4-19, and TW4-20 are pumping wells KRIGED 1st QUARTER, 2012 WATER LEVELS WHITE MESA SITE APPROVED DATE REFERENCE FIGURE H:/718000/may12/UwI0312.srf D-l TabE Hydrographs of Groundwater Elevations Over Time for Nitrate Monitoring Wells (J1 '" a (J1 ....... a Depth Below Measuring Point (ft.) (J1 o a ~ <.0 a ~ 00 a ~ -..J a ~ 0) a ~ (J1 a 1-----+----1----+-----+----+-----+-----+1 06/01/08 12/18/08 07/06/09 01122/10 08/10/10 02/26/11 09/14/11 04/01/12 '--__ --L ___ ...l..-__ ---l.. ___ ....J-___ .J...-__ ---l.. ___ -I-10/18/12 ~ z • ~ ~ r+ CD .., r-CD < CD 0 < CD .., =f 3 CD .-;= C'" 3 "C --- '" 0'1 a '" o a Depth Below Measuring Point (ft.) 0'1 a o a 0'1 a o a I-------!--------!------I------+-------+-I 06/01/08 12/18/08 07/06/09 01/22/10 08/10/10 02/26/11 09/1 4/11 04/01/12 L--____ ...I...-____ .....I.-____ --l-_____ ---!. ____ ----'-10/18/12 ~ Z • N ~ r+ CD .., r-CD < CD 0 < CD .., ::t 3 CD .-;= C'" 3 "'C --- .-. C. 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CI) .... ~ 0) ~ I Z ~ Z ~/g ~/O ~ -,------.-----.-----,..----,-----..,.----,-------, Z~HOlvO ~ ~/v ~/60 ~ ~/9Z/ZO o ~/O ~/90 O~/ZZHO 60/90lLO +-----+---+----1-----+-----+----+-----1 o N lC) lC) N lC) o LO lC) TabF Depths to Groundwater and Elevations Over Time for Nitrate Monitoring Wells Water Levels and Data over Time White Mesa Mill-Well TWN-l Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,646.96 5,648.09 1.13 112.5 5,600.38 02/06/09 47.71 46.58 5,599.99 07/21109 48.10 46.97 5,600.26 09/21109 47.83 46.70 5,601.10 10/28/09 46.99 45.86 5,602.59 12114/09 45.50 44.37 5,600.55 03111110 47.54 46.41 5,600.66 05111110 47.43 46.30 5,599.18 09/29110 48.91 47.78 5,598.92 12121110 49.17 48.04 5,598.29 02128111 49.80 48.67 5,597.80 06/21111 50.29 49.16 5,597.32 09/20111 50.77 49.64 5,597.15 12121111 50.94 49.81 5,596.54 03127112 51.55 50.42 5,596.52 06/28112 51.57 50.44 Water Levels and Data over Time White Mesa Mill-Well TWN-2 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,625.75 5,626.69 0.94 95 5,611.37 02106109 15.32 14.38 5,610.63 07121109 16.06 15.12 5,609.73 09121109 16.96 16.02 5,607.08 11/02109 19.61 18.67 5,606.57 12114/09 20.12 19.18 5,612.45 03111110 14.24 13.30 5,612.78 05111110 13.91 12.97 5,611.37 09129110 15.32 14.38 5,610.24 12121110 16.45 15.51 5,610.64 02128111 16.05 15.11 5,609.78 06121111 16.91 15.97 5609.79 09120111 16.90 15.96 5609.72 12121111 16.97 16.03 5,605.69 03/27112 21.00 20.06 5,605.67 06128112 21.02 20.08 Water Levels and Data over Time White Mesa Mill-Well TWN-3 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,633.64 5,634.50 0.86 110 5,603.77 02/06/09 30.73 29.87 5,602.37 07/21109 32.13 31.27 5,602.34 09/21109 32.16 31.30 5,602.60 10/28/09 31.90 31.04 5,603.12 12/14/09 31.38 30.52 5,602.90 03/11110 31.60 30.74 5,603.23 05/11110 31.27 30.41 5,602.86 09/29/10 31.64 30.78 5,603.35 12/21110 31.15 30.29 5,602.89 02/28/11 31.61 30.75 5,602.75 06/21111 31.75 30.89 5,602.40 09/20/11 32.10 31.24 5,602.40 12/21/11 32.10 31.24 5,601.70 03/27/12 32.80 31.94 5,601.67 06/28/12 32.83 31.97 Water Levels and Data over Time White Mesa Mill-Well TWN-4 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,641.04 5,641.87 0.83 136 5,601.47 02/06/09 40.40 39.57 5,604.26 07/21109 37.61 36.78 5,605.02 09/21109 36.85 36.02 5,605.87 10/28/09 36.00 35.17 5,605.81 12114/09 36.06 35.23 5,605.31 03111110 36.56 35.73 5,605.36 05/11110 36.51 35.68 5,604.59 09/29110 37.28 36.45 5,604.42 12/21110 37.45 36.62 5,603.69 02/28111 38.18 37.35 5,603.36 06/21111 38.51 37.68 5,602.82 09/20111 39.05 38.22 5,602.79 12/21111 39.08 38.25 5,600.82 03/27112 41.05 40.22 5,600.84 06/28112 41.03 40.20 Water Levels and Data over Time White Mesa Mill-Well TWN-5 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,653.70 5,655.18 1.48 155 5,584.43 08 /25/09 70.75 69.27 5,584.51 09/21109 70.67 69.19 5,584.54 11110109 70.64 69.16 5,584.62 12114/09 70.56 69.08 5,584.97 03111110 70.21 68.73 5,585.38 05111110 69.80 68.32 5,585.35 09129110 69.83 68.35 5,585.42 12/21110 69.76 68.28 5,585.08 02/28111 70.10 68.62 5,585.38 06/21111 69.80 68.32 5,585.51 09/20111 69.67 68.19 5,585.76 12/21111 69.42 67.94 5,585.61 03/27112 69.57 68.09 5,585.63 06/28/12 69.55 68.07 Water Levels and Data over Time White Mesa Mill-Well TWN-6 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,663.03 5,664.94 1.91 135 5,589.52 08/25 /09 75.42 73.51 5,589.46 09/22/09 75.48 73.57 5,589.61 11103/09 75.33 73.42 5,589.92 12/14/09 75.02 73.11 5,590.24 03111110 74.70 72.79 5,590.40 05/11110 74.54 72.63 5,590.24 09/29110 74.70 72.79 5,590.49 12/21110 74.45 72.54 5,590.16 02/28/11 74.78 72.87 5,590.44 06/21111 74.50 72.59 5,590.35 09/20111 74.59 72.68 5,590.67 12/21111 74.27 72.36 5,590.34 03/27112 74.60 72.69 5,590.32 06/28112 74.62 72.71 Water Levels and Data over Time White Mesa Mill-Well TWN-7 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,647.39 5,649.26 1.87 120 5,552.56 08/25/09 96.70 94.83 5,558.34 09/21109 90.92 89.05 5,558.82 11110109 90.44 88 .57 5,558.96 12114/09 90.30 88.43 5,559.54 03111110 89.72 87.85 5,559.60 05111110 89.66 87.79 5,559.83 09/29/10 89.43 87.56 5,559.00 12/21110 90.26 88.39 5,559.68 02/28111 89.58 87.71 5,560.43 06/21111 88.83 86.96 5,560.46 09/2 0/11 88.80 86.93 5,560.78 12/21111 88.48 86.61 5,560.92 03 /27112 88.34 86.47 5,560.87 06/28112 88.39 86.52 Water Levels and Data over Time White Mesa Mill-Well TWN-8 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,649.35 5,651.48 2.13 160 5,589.01 08/25/09 62.47 60.34 5,589.10 09/21109 62.38 60.25 5,589.09 11103 /09 62.39 60.26 5,603.38 12114/09 48.10 45.97 5,589.68 03111110 61.80 59.67 5,589.95 05111110 61.53 59.40 5,589.74 09129 /10 61.74 59.61 5,589.97 12/21110 61.51 59.38 5,589.67 02/28111 61.81 59.68 5,589.96 06/21111 61.52 59.39 5,589.82 09/20111 61.66 59.53 5,590.18 12121111 61.30 59.17 5,589.85 03127112 61.63 59.50 5,589.84 06/28112 61.64 59.51 Water Levels and Data over Time White Mesa Mill-Well TWN-9 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,645.68 5,647.45 1.77 102.5 5,582.05 08/25/09 65.40 63.63 5,582.12 09/22/09 65.33 63.56 5,582.27 11110109 65.18 63.41 5,582.53 12114/09 64.92 63.15 5,582.92 03 /11110 64.53 62.76 5,583.06 05111110 64.39 62.62 5,583.25 09/29110 64.20 62.43 5,583.57 12/21110 63.88 62.11 5,583.54 02/28111 63.91 62.14 5,583.92 06/21111 63.53 61.76 5,584.04 09/20111 63.41 61.64 5,587.42 12/21111 60.03 58.26 5,584.56 03/27/12 62.89 61.12 5,584.55 06/28112 62.90 61.13 Water Levels and Data over Time White Mesa Mill-Well TWN-IO Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,664.63 5,666.98 2.35 107.5 5,584.18 08/25/09 82.80 80.45 5,584.40 09/22/09 82.58 80.23 5,584.61 11110109 82.37 80.02 5,584.90 12114/09 82.08 79.73 5,585.21 03111110 81.77 79.42 5,585.42 05111110 81.56 79.21 5,585.42 09/29110 81.56 79.21 5,585.68 12/21110 81.30 78.95 5,585.60 02/28111 81.38 79.03 5,585.95 06/21111 81.03 78.68 5,585.92 09/20111 81.06 78.71 5,586.22 12/21111 80.76 78.41 5,586.16 03/27112 80.82 78.47 5,586.16 06/28112 80.82 78.47 Water Levels and Data over Time White Mesa Mill -Well TWN-ll Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,683.16 5,684.53 1.37 147.5 5,613.00 11103/09 71.53 70.16 5,613.88 12114/09 70.65 69.28 5,614.65 03111110 69.88 68.51 5,615.16 05111110 69.37 68.00 5,614.93 09/29110 69.60 68.23 5,615.09 12/21110 69.44 68.07 5,614.96 02/28111 69.57 68.20 5,615.12 06/21111 69.41 68.04 5,614.96 09/20111 69.57 68.20 5,615.18 12/21111 69.35 67.98 5,615.11 03/27112 69.42 68.05 5,615.12 06/28112 69.41 68.04 Water Levels and Data over Time White Mesa Mill-Well TWN-12 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,667.03 5,668.24 1.21 115 5,628.33 11103/09 39.91 38.70 5,628.86 12114/09 39.38 38.17 5,630.27 03111110 37.97 36.76 5,631.64 05111110 36.60 35.39 5,633.73 09129110 34.51 33.30 5,633.43 12121110 34.81 33.60 5,634.35 02/28111 33.89 32.68 5,635.95 06/21111 32.29 31.08 5,636.44 09/20111 31.80 30.59 5,638.93 12/21111 29.31 28.10 5,639.69 03/27112 28.55 27.34 5,639.74 06/28112 28.50 27.29 Water Levels and Data over Time White Mesa Mill-Well TWN-13 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,633.04 5,634.32 1.28 120 5,586.95 11103/09 47.37 46.09 5,587.22 12114/09 47.10 45.82 5,587.45 03/11110 46.87 45.59 5,587.64 05111110 46.68 45.40 5,587.37 09/29110 46.95 45.67 5,587.77 12/21110 46.55 45.27 5,587.64 02/28111 46.68 45.40 5,587.89 06/21111 46.43 45.15 5,588.03 09120111 46.29 45.01 5,588.30 12/21111 46.02 44.74 5,588.32 03/27/12 46.00 44.72 5,588.30 06/28112 46.02 44.74 Water Levels and Data over Time White Mesa Mill-Well TWN-14 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,647.80 5,649.53 1.73 135 5,586.18 11104/09 63.35 61.62 5,586.51 12114/09 63.02 61.29 5,586.71 03111110 62.82 61.09 5,586.72 05111110 62.81 61.08 5,586.53 09/29110 63.00 61.27 5,586.80 12/21110 62.73 61.00 5,586.74 02/28/11 62.79 61.06 5,586.84 06121111 62.69 60.96 5,586.73 09120111 62.80 61.07 5,586.98 12/21111 62.55 60.82 5,587.07 03/27112 62.46 60.73 5,587.10 06/28/12 62.43 60.70 Water Levels and Data over Time White Mesa Mill-Well TWN-IS Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,675.01 5,676.49 1.48 155 5,594.12 11110109 82.37 80.89 5,584.03 12114/09 92.46 90.98 5,584.10 03/11110 92.39 90.91 5,584.16 05111110 92.33 90.85 5,584.26 09/29110 92.23 90.75 5,584.30 12121110 92.19 90.71 5,584.04 02/28111 92.45 90.97 5,584.30 06/21111 92.19 90.71 5,584.37 09/20111 92.12 90.64 5,584.49 12/21111 92.00 90.52 5,584.47 03/27/12 92.02 90.54 5,584.49 06/28/12 92.00 90.52 Water Levels and Data over Time White Mesa Mill-Well TWN-16 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,651.07 5,652.70 1.63 100 5,603.34 11104/09 49.36 47.73 5,603.56 12114/09 49.14 47.51 5,603.84 03111110 48.86 47.23 5,604.31 05/11110 48.39 46.76 5,604.28 09/29110 48.42 46.79 5,604.39 12121110 48.31 46.68 5,604.20 02/28111 48.50 46.87 5,604.55 06/21111 48.15 46.52 5,604.74 09/20111 47.96 46.33 5,604.94 12121111 47.76 46.13 5,604.84 03/27112 47.86 46.23 5,604.85 06/28112 47.85 46.22 Water Levels and Data over Time White Mesa Mill-Well TWN-17 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,639.73 5,641.55 1.82 100 5,605.96 11104/09 35.59 33.77 5,606.27 12114/09 35.28 33.46 5,606.25 03111110 35.30 33.48 5,606.55 05111110 35.00 33.18 5,606.77 09/29110 34.78 32.96 5,607.15 12/21110 34.40 32.58 5,606.96 02/28111 34.59 32.77 5,607.22 06/21111 34.33 32.51 5,607.40 09/20111 34.15 32.33 5,607.85 12121111 33.70 31.88 5,607.67 03 /27112 33.88 32.06 5,607.68 06/28112 33.87 32.05 Water Levels and Data over Time White Mesa Mill-Well TWN -18 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,643.95 5,645.45 1.50 100 5,586.85 11102/09 58.60 57.10 5,600.14 12114/09 45.31 43.81 5,587.36 03111110 58.09 56.59 5,587.71 05/11110 57.74 56.24 5,587.50 09/29110 57.95 56.45 5,607.66 12/21110 37.79 36.29 5,587.35 02/28111 58.10 56.60 5,587.71 06/21111 57.74 56.24 5,587.65 09/20111 57.80 56.30 5,587.95 12/21111 57.50 56.00 5,587.05 03/27112 58.40 56.90 5,587.05 06/28/12 58.40 56.90 Water Levels and Data over Time White Mesa Mill-Well TWN-19 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,659.59 5,661.36 1.77 110 5,606.17 11102/09 55.19 53.42 5,606.70 12114/09 54.66 52.89 5,607.22 03111110 54.14 52.37 5,607.89 05/11110 53.47 51.70 5,607.98 09/29110 53.38 51.61 5,608.41 12/21110 52.95 51.18 5,608.49 02/28/11 52.87 51.10 5,608.60 06/21111 52.76 50.99 5,609.17 09/20111 52.19 50.42 5,608.90 12/21111 52.46 50.69 5,608.87 03127/12 52.49 50.72 5,608.86 06128/12 52.50 50.73 TabG Laboratory Analytical Reports EN:RGY www.energylab.com Analylit:afExcsllent:B Sines 1952 . Helena, MT 877 .. 472 .. 071 t • Billings, MT 800 .. 735-4489 . Gasper, WY 888-235-0515 LABORATO RIES 'IDli~~~~wY8·&6 ... 86-j115 • Rapid City, SD 888-&72-1225 • College Station, TX 888 .. 690-2218 ANALYTICAL SUMMARY REPORT May 01,2012 Denison Mines USA Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C12041150 Quote 10: C3317 -Nitrate and Chloride Sampling Project Name: 2nd Quarter Nitrate 2012 Energy Laboratories, Inc. Casper WY received the following 28 samples for Denison Mines USA Corp on 4/24/2012 for analysis. Sample 10 Client Sample 10 Collect Date Receive Date Matrix Test C12041150-001 TWN-13_04182012 04/18/12 7:18 04/24/12 Aqueous Chloride Nitrogen, Nitrate + Nitrite C 12041150-002 TWN-13R_04182012 04/18/126:40 04/24/12 Aqueous Same As Above C 12041150-003 TWN-08_04182012 04/18/128:09 04/24/12 Aqueous Same As Above C 12041150-004 TWN-05_04182012 04/18/129:45 04/24/12 Aqueous Same As Above C 1 2041150-005 TWN-01 -04182012 04/18/12 10:32 04/24/12 Aqueous Same As Above C 12041150-006 TWN-10_04192012 04/19/12 13:38 04/24/12 Aqueous Same As Above C 12041150-007 TWN-04_04182012 04/18/12 12:55 04/24/12 Aqueous Same As Above C 12041150-008 TWN-12_04182012 04/18/12 13:44 04/24/12 Aqueous Same As Above C 12041150-009 TWN-06_04182012 04/18/12 14:31 04/24/12 Aqueous Same As Above C12041150-010 TWN-15_04202012 04/20/126:27 04/24/12 Aqueous Same As Above C12041150-011 TWN-11 -04192012 04/19/12 7:55 04/24/12 Aqueous Same As Above C12041150-012 TWN-18_04192012 04/19/12 8:45 04/24/12 Aqueous Same As Above C12041150-013 TWN-07 _04202012 04/20/12 6:40 04/24/12 Aqueous Same As Above C12041150-014 TWN-16_04192012 04/19/12 10:01 04/24/12 Aqueous Same As Above C12041150-015 TWN-14_04202012 04/20/12 6:50 04/24/12 Aqueous Same As Above C12041150-016 TWN-19_04192012 04/19/12 12:02 04/24/12 Aqueous Same As Above C12041150-017 TWN-17_04202012 04/20/12 6:56 04/24/12 Aqueous Same As Above C12041150-018 TWN-09_04202012 04/20/127:03 04/24/12 Aqueous Same As Above ------_._-----------------------_._------_._------_._----------... ----------------------------------.----------------------------"-----------_. __ ._-------_._-------_._--------- C12041150-019 TWN-03_04202012 04/20/127:15 04/24/12 Aqueous Same As Above -----_._--------------------------------------_._------------------------_._------------_._------------------------_._-----------------------------------------------------------------_._------------_._--------------------------------_._- C 12041150-020 TWN-02_04202012 04/20/127:25 04/24/12 Aqueous Same As Above -------------------------------------------------------------_._------_ .. _---------------------------------------------"'------------------------------------------------------------------------------------------------------"'---------"'-- C12041150-021 TWN-15R_04192012 04/19/12 6:35 04/24/12 Aqueous Same As Above C 12041150-022 TVVN-60_04202012 04/20/12 13:30 04/24/12 Aqueous Same As Above C 12041150-023 TWN-65_04182012 04/18/12 12:55 04/24/12 Aqueous Same As Above C 12041150-024 TVVN-70_04202012 04/20/12 6:27 04/24/12 Aqueous Same As Above C12041150-025 Piez-01_04202012 04/20/12 13:05 04/24/12 Aqueous Same As Above C12041150-026 Piez-02_04202012 04/20/12 12:35 04/24/12 Aqueous Same As Above C12041150-027 Piez-03_04202012 04/20/12 12:50 04/24/12 Aqueous Same As Above Page 1 of 16 EI\ERGY LAB ORATORIES www.energyJab.com " ,',' ,}elena,MT871"472 .. 0711 . Billings, MT 800-735-4489 • Casper, WY 888-235-0515 AnalyticJilExtsJIencsSim 7952 <k ~,;,.':"". ,h ~lJi~tte.;wY8'6~6~6 .. 717~ • Rapid CIty, SI} 888-672-1225 • College Station, TX 888-690-2218 ANALYTICAL SUMMARY REPORT C12041150-028 Temp Blank 04/24/12 Aqueous Temperature The analyses presented in this report were performed at Energy Laboratories, Inc., 2393 Salt Creek Hwy., Casper, WY 82601, unless otherwise noted. Radiochemistry analyses were performed at Energy Laboratories, Inc., 2325 Kerzell Lane, Casper, WY 82601, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. The results as reported relate only to the item(s) submitted for testing. Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. Data corrected for moisture content are typically noted as - dry on the report. For agricultural and mining soil parameters/characteristics, all samples are dried and ground prior to sample analysis. If you have any questions regarding these test results, please call. Report Approved By: c5¥~ £; uJ~'Y Reporting Supervisor Digitally signed by Stephanie Waldrop Date: 2012.05.01 16:14:58 -06:00 Page 2 of 16 ~~""7'""""'---'-------'---------------www.energyJab.com Analytical Excsllsncs Sines 1952 Helena,MT877 .. 472 .. 0111 • Billings, MT 800-135-4489 • Casper, WY 888-235-0515 ~Gilleti:!!',WY-e66-686-7175 • Rapid City, SD. 888-672-1225 • College Station, IX 888-690-2218 CLIENT: Denison Mines USA Corp Project : 2nd Quarter Nitrate 2012 Report Date: 05/01/12 Sample Delivery Group: C12041150 CASE NARRATIVE ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4"C (±2"C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIL/SOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by ELI reflects the results for seven individual Aroclors. When the results for all seven are ND (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SD eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL-DOH NELAC: E87641, Radiochemical E871 017; California: 02118CA; Oregon: WY200001, Radiochemical WY200002; Utah: WY00002; Virginia: 00057; Washington: C836 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting www.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page www.energylab.com. Page 3 of 16 EN:RGY LA80RAT ORIES www.energyJab.com Analytical ExCIIUtHlCB Sines 1952 Helena, MT 877-472-0711 • Billings, MT 800-735w4489 -Casper, WY 888-235-0515 ~ill~tte, WY 866 .. 686-7175 • Rapid City, SD 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 Lab ID: C12041150-001 Client Sample ID: TWN-13_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C 12041150-002 Client Sample ID: TWN-13R_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 12041150-003 Client Sample ID: TWN-08_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 120411 50-004 Client Sample ID: TWN-05_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Rl -Analyte reporting limit. Definitions: QCl -Quality control limit. Result Units 53 mg/L NO mg/L Result Units NO NO mg/l mg/l Result Units 15 NO mg/l mg/l Result Units 39 0.3 mg/l mg/l Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Report Date: 05/01/12 Collection Date: 04/18/12 07:18 DateReceived: 04/24/12 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 04/26/12 14:43 1 Ir E353.2 04/26/1214:151 de Collection Date: 04/18/1206:40 DateReceived: 04/24/12 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 04/26/12 14:441 Ir E353.2 04/26/12 14:221 de Collection Date: 04/18/12 08:09 DateReceived: 04/24/12 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By MCL! A4500-CI B 04/26/12 14:46 1 Ir E353.2 04/26/12 14:251 de Collection Date: 04/18/1209:45 DateReceived: 04/24/12 Matrix: Aqueous QCL Method Analysis Date 1 By A4500-CI B 04/26/12 14:481 Ir E353.2 04/26/12 14:27 1 de MCl -Maximum contaminant level .. NO -Not detected at the reporting limit. Page 4 of 16 EN:RGY LABORATORIES www.energylal>.com f::" · '.,. .. :Helena, .1It 817 -472-0711 • Billings, MT ao8-73H 41l9 • Casper, WY .88-235-0515 AnalyticalExcsllsncsSincs 1952 .£;£:,," ., '~lne.tte! WY 86~-686-7175 • Rapid City, SD 888-672-1225 • College Station, IX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 LablD: C 12041150-005 Client Sample ID: TWN-01_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C12041150-006 Client Sample ID: TWN-10_04192012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C12041150-007 Client Sample ID: TWN-04_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 120411 50-008 Client Sample ID: TWN-12_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 17 mg/L 0.6 mg/L Result Units 28 0.9 mg/L mg/L Result Units 24 1.1 mg/L mg/L Result Units 106 mg/L 1.2 mg/L Qualifiers Rl 0.1 Qualifiers Rl 0.1 Qualifiers Rl 0.1 Qualifiers Rl 0.1 Report Date: 05/01/12 Collection Date: 04/18/12 10:32 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 14:51 fir E353.2 04/26/12 14:30 1 de Collection Date: 04/19/12 13:38 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 14:52 1 Ir E353.2 04/26/12 14:321 de Collection Date: 04/18/12 12:55 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By MeL! A4500-CI B 04/26/12 14:541 Ir E353.2 04/26/12 14:351 de Collection Date: 04/18/12 13:44 Date Received : 04/24/12 Matrix: Aqueous Qel Method Analysis Date 1 By A4500-CI B 04/26/12 14:561 Ir E353.2 04/26/12 14:37 1 de MCL -Maximum contaminant level. NO -Not detected at the reporting limit. Page 5 of 16 EN:RGY LABORATORIES www.energylab.com Analytical ExcsIIIHlCB Sincs 1952 ,HeJena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 ~Gillette, W'f 866-&86-7175 • Rapid City, SD 888-&72-1225 • College Station, IX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 Lab 10: C 12041150-009 Client Sample 10: TWN-06_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C12041150-010 Client Sample 10: TWN-15_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C12041150-011 Client Sample 10: TWN-11_04192012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C12041150-012 Client Sample 10: TWN-18_04192012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 22 mg/L 1.1 mg/L Result Units 46 1.6 mg/L mg/L Result Units 71 1.6 mg/L mg/L Result Units 64 2.1 mg/L mg/L Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Report Date: 05/01/12 Collection Date: 04/18/12 14:31 DateReceived: 04/24/12 Matrix: Aqueous MCL! QCL Method Analysis Date / By A4500-CI B 04/26/12 14:581 Ir E353.2 04/26/12 14:401 dc Collection Date: 04/20/1206:27 DateReceived: 04/24/12 Matrix: Aqueous MCL! QCL Method Analysis Date / By A4500-CI B 04/26/12 15 :09 fir E353.2 04/26/12 14:421 dc Collection Date: 04/19/1207:55 DateReceived: 04/24/12 Matrix: Aqueous MCL! QCL Method Analysis Date / By MCL! A4500-CI B 04/26/1215:11 fir E353.2 04/26/1215:15/dc Collection Date: 04/19/12 08:45 DateReceived: 04/24/12 Matrix: Aqueous QCL Method Analysis Date / By A4500-CI B 04/26/12 15:171 Ir E353.2 04/26/12 15 :22 1 dc MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 6 of 16 EN:RGY LABORATORIES www.energyJab.com Analytical ExCIIlIsncB Sines 1952 .H.elena, MT 871-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 $lillette,WY 86&:-686-7175 • Rapid City, SD 888-672-1225 • College Station, IX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 LablD: C12041150-013 Client Sample ID: TWN-07 _04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C12041150-014 Client Sample ID: TWN-16_04192012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C12041150-015 Client Sample ID: TWN-14_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C12041150-016 Client Sample ID: TWN-19_04192012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 6 mg/l 1.2 mg/L Result Units 50 2.0 Result 27 3.4 mg/L mg/L Units mg/L mg/L Result Units 117 mg/L 6.8 mg/L D -RL increased due to sample matrix. Qualifiers Rl 1 0.1 Qualifiers Rl 0.1 Qualifiers Rl D 0.2 Qualifiers Rl D 0.2 Report Date: 05/01/12 Collection Date: 04/20/1206:40 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:191 Ir E353.2 04/26/12 15 :25 1 dc Collection Date: 04/19/12 10:01 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:221 Ir E353.2 04/26/12 15:27 1 dc Collection Date: 04/20/1206:50 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel MeL! Method Analysis Date 1 By A4500-CI B 04/26/12 15:251 Ir E353.2 04/26/12 15 :30 1 dc Collection Date: 04/19/12 12:02 DateReceived: 04/24/12 Matrix: Aqueous Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:26 1 Ir E353.2 04/26/12 15:32 1 dc MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 7 of 16 EN:RGY LABORAT ORIES www.energylab.comHelena.MT871~472-0711 .Billings.MT 800-735-4489 • Casper, WY 888-235-0515 AnalyticalExcsJlsncsSincs '952 . ;~iil'~tfe, w.Y86.~-686 .. 717~. Rapid City, S[} 888-672-1225 • College Station, 1X 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 LablD: C12041150-017 Client Sample ID: TWN-17_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C12041150-018 Client Sample ID: TWN-09_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C12041150-019 Client Sample ID: TWN-03_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 120411 50-020 Client Sample ID: TWN-02_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 80 mg/L 9.1 mg/L Result Units 209 mg/L 10.6 mg/L Result Units 152 mg/L 24 mg/L Result Units 103 mg/L 48 mg/L D -RL increased due to sample matrix. Qualifiers Rl D 0.5 Qualifiers Rl 1 D 0.5 Qualifiers Rl D Qualifiers Rl D Report Date: 05/01/12 Collection Date: 04/20/1206:56 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:28 1 Ir E353.2 04/26/12 15 :35 1 dc Collection Date: 04/20/12 07:03 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:42 1 Ir E353.2 04/26/12 15:37 1 dc Collection Date: 04/20/1207:15 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By MeL! A4500-CI B 04/26/12 15:441 Ir E353.2 04/26/12 15:401 dc Collection Date: 04/20/1207:25 DateReceived: 04/24/12 Matrix: Aqueous Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:521 Ir E353.2 04/26/12 15:421 dc MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 8 of 16 E~RGY L ABORATORIES www.energylab.com Analytical Exc8llsncB Sincs1952 Helena, MTB77-472-071t • Billings, MT 800-735-4489 . Casper, WY 888-235-0515 :~in~tt¢J VIY 8&6-6B6':7175 • Rapid City, SO 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 Lab 10: C12041150-021 Client Sample 10: TWN-15R_04192012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C 12041150-022 Client Sample 10: TWN-60_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C12041150-023 Client Sample 10: TWN-65_04182012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C12041150-024 Client Sample 10: TWN-70_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 1 mg/L NO mg/L Result Units 1 NO mg/L mg/L Result Units 24 1.1 mg/L mg/L Result Units 46 1.7 mg/L mg/L Qualifiers Rl 0.1 Qualifiers Rl 0.1 Qualifiers Rl 0.1 Qualifiers Rl 0.1 Report Date: 05/01/12 Collection Date: 04/19/12 06:35 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15 :53 1 Ir E353.2 04/26/12 15 :50 1 de Collection Date: 04/20/12 13:30 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15 :54 fir E353.2 04/26/12 15:57 1 de Collection Date: 04/18/12 12:55 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By MeL! A4500-CI B 04/26/12 15:561 Ir E353.2 04/26/12 16:001 de Collection Date: 04/20/1206:27 DateReceived: 04/24/12 Matrix: Aqueous Qel Method Analysis Date 1 By A4500-CI B 04/26/12 15:581 Ir E353.2 04/26/12 16:021 de MCL -Maximum contaminant level. NO -Not detected at the reporting limit. Page 9 of 16 EN:RGY LABORATORIES www.energylab.com Analytical Excsll8l1CB Sines 1952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489-Casper, WY 888-235-0515 !1111~he, WY 86&-686-7175 • Rapid City, SD 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 2nd Quarter Nitrate 2012 LablD: C 12041150-025 Client Sample ID: Piez-01_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C 120411 50-026 Client Sample ID: Piez-02_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 12041150-027 Client Sample ID: Piez-03_04202012 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C 12041150-028 Client Sample ID: Temp Blank Analyses PHYSICAL PROPERTIES Temperature Report Rl -Analyte reporting limit. Definitions: QCl -Quality control limit. Result Units 58 mg/l 6.6 mg/l Result Units 8 0.2 mg/l mg/l Result Units 53 1.7 mg/l mg/l Result Units 2.6 o -Rl increased due to sample matrix. Qualifiers 0 Qualifiers Qualifiers Qualifiers Rl 0.2 Rl 0.1 Rl 1 0.1 Rl Report Date: 05/01/12 Collection Date: 04/20/12 13:05 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date / By A4500-CI B 04/26/12 15 :59 1 Ir E353.2 04/26/12 16 :05 1 dc Collection Date: 04/20/12 12:35 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date / By A4500-CI B 04/26/12 16:00 1 Ir E353.2 04/26/12 16:07 1 dc Collection Date: 04/20/12 12:50 DateReceived: 04/24/12 Matrix: Aqueous MeL! Qel Method Analysis Date / By MeL! A4500-CI B 04/26/12 16:021 Ir E353.2 04/26/12 16:101 dc Collection Date: Not Provided DateReceived: 04/24/12 Matrix: Aqueous Qel Method Analysis Date 1 By E170.1 04/24/12 09:30 1 kbh MCl -Maximum contaminant level. NO -Not detected at the reporting limit. Page 10 of 16 EN:RGY www.energylab.com Helena, MT 871-472-0711 • Billings, MT 800-735-4489 . Casper, WY 888-235-0515 _'~m~~!}! wr 86~ .. 6B6-7175 • Rapid City, SD 888-672-1225 • College Station, lX 888-690-2218 LABORATORIES Analytical ExcsllSflcS Sines 7952 QA/QC Summary Report Prepared by Casper, WY Branch Client: Denison Mines USA Corp Project: 2nd Quarter Nitrate 2012 Analyte Count Result Units Method: A4500-CI B Sample 10: MBLK9-120426A Chloride Sample 10: C12041131-001AMS Chloride Sample 10: C12041131-001AMSO Chloride Sample 10: C12041150-009AMS Chloride Sample 10: C12041150-009AMSO Chloride Sample 10: LCS35-120426A Chloride Sample 10: C12041150-015AMS Chloride Sample 10: C12041150-015AMSO Chloride Sample 10: C12041150-027AMS Chloride Sample 10: C12041150-027AMSO Chloride Qualifiers: RL -Analyte reporting limit. Method Blank NO mg/L Sample Matrix Spike 36.2 mg/L Sample Matrix Spike Duplicate 36.5 mg/L Sample Matrix Spike 57.8 mg/L Sample Matrix Spike Duplicate 57.4 mg/L Laboratory Control Sample 3580 mg/L Sample Matrix Spike 115 mg/L Sample Matrix Spike Duplicate 116 mg/L Sample Matrix Spike 144 mg/L Sample Matrix Spike Duplicate 143 mg/L Report Date: 05/01/12 Work Order: C 12041150 RL %REC Low Limit High Limit RPO RPOLimit Qual 1.0 1.0 102 1.0 103 1.0 102 1.0 101 1.0 101 1.0 99 1.0 100 1.0 102 1.0 101 Batch: 120426A-CL-TTR-W Run: TITRATION_120426A 04/26/1213:22 Run: TITRATION_120426A 90 110 Run: TITRATION_120426A 90 110 Run: TITRATION 120426A - 90 110 Run: TITRATION_120426A 90 110 Run: TITRATION_120426A 90 110 Run: TITRATION 120426A - 90 110 Run: TITRATION_120426A 90 110 Run: TITRATION 120426A - 90 110 Run: TITRATION 120426A - 90 110 1.0 0.6 0.8 0.6 04/26/12 14:35 04/26/12 14:37 10 04/26/12 14:59 04/26/12 15:00 10 04/26/12 15:01 04/26/12 15:47 04/26/12 15:48 10 04/26/12 16:03 04/26/12 16:05 10 NO -Not detected at the reporting limit. Page 11 of 16 EI'.ERGY www.energylab.com Helena, MTB77-472-071 t • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 ~ ~m~fte, WY 8&6-686-7175 • Rapid Cfty, SO 888-672-1225 • College Station, IX 888-690-2218 LABORATORIES Analytical Excsl/sncli Sines 1152 QA/QC Summary Report Prepared by Casper, WY Branch Client: Denison Mines USA Corp Report Date: 05/01/12 Project: 2nd Quarter Nitrate 2012 Work Order: C12041150 Analyte Count Result Units RL %REC Low Limit High Limit RPO RPOLimit Qual Method: E353.2 Batch: R158954 Sample 10: MBLK-1 Method Blank Run: TECHNICON_120426A 04/26/12 12:42 Nitrogen, Nitrate+Nitrite as N NO mg/L 0.10 Sample 10: LCS-2 Laboratory Control Sample Run: TECHNICON_120426A 04/26/12 13:35 Nitrogen, Nitrate+Nitrite as N 2.39 mg/L 0.10 96 90 110 Sample 10: LFB-3 Laboratory Fortified Blank Run: TECHNICON_120426A 04/26/12 13:37 Nftrogen, Nitrate+Nftrite as N 1.87 mg/L 0.10 95 90 110 Sample 10: C12041150-001BMS Sample Matrix Spike Run: TECHNICON_120426A 04/26/12 14: 17 Nitrogen, Nitrate+Nitrite as N 1.85 mg/L 0.10 94 90 110 Sample 10: C12041150-001 BMSO Sample Matrix Spike Duplicate Run: TECHNICON_120426A 04/26/12 14:20 Nitrogen, Nitrate+Nitrite as N 1.89 mg/L 0.10 96 90 110 2.1 10 Sample 10: C12041150-011BMS Sample Matrix Spike Run : TECHNICON_120426A 04/26/1215:17 Nitrogen, Nitrate+Nitrite as N 3.36 mg/L 0.10 91 90 110 Sample 10: C12041150-011BMSO Sample Matrix Spike Duplicate Run: TECHNICON_120426A 04/26/12 15:20 Nitrogen, Nitrate+Nitrite as N 3.35 mg/L 0.10 91 90 110 0.3 10 Sample 10: C12041150-021BMS Sample Matrix Spike Run: TECHNICON_120426A 04/26/12 15:52 Nitrogen, Nitrate+Nitrite as N 1.84 mg/L 0.10 94 90 110 Sample 10: C12041150-021BMSO Sample Matrix Spike Duplicate Run: TECHNICON_120426A 04/26/12 15:55 Nitrogen, Nitrate+Nitrite as N 1.86 mg/L 0.10 95 90 110 1.1 10 Qualifiers: RL -Analyte reporting limit. NO -Not detected at the reporting limit. Page 12 of 16 EN:RGY LABORATORIES m '" www.energylab.com ~ &, AII8/ytica1 ExcsllBllCf SiIlCB 1952 Heiena, MT 877-472..;0711 • Billings, MT 800-735-4489 • Casper, WV 888-235-0515 .~ill~tt;¢, Wy 866:,~B6-7175 • Rapid City, SD 888-672-1225 • College Station, TX 888-690-2218 Workorder Receipt Checklist Denison Mines USA Corp 1111111111111 il~ 11111111111111 ~IIIIIII C12041150 Login completed by: Tracy Judge Reviewed by: BL2000\tedwards Reviewed Date: 4/25/2012 Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? (Exclude analyses that are considered field parameters such as pH, DO, Res CI, Sulfite, Ferrous Iron, etc.) Containerffemp Blank temperature: Water -VOA vials have zero headspace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Yes 0' Yes 0' Yes D Yes 0' Yes 0' Yes 0' Yes 0' Yes 0' Yes 0' Yes 0' 2.6'C On Ice Yes D Yes 0' Date Received: 4/24/2012 Received by: tj No D No D No D No D No D No D No D No D No D No D No D No D Carrier FedEx name: Not Present D Not Present D Not Present 0' No VOA vials submitted 0' Not Applicable D Page 13 of 16 "'0 Q) CO (1) ~ +::. o -~ 0) ............... ~...........--~ Ef\ER~ Chain of Custody and Analytical Request Record PLEASE PRINT (Provide_~s m~h ioformation .as possibl~) page_' _of~ 'M,_,u-unA' EPA/State Compliance: Yes g , No 0 comPDme:, e.n. ~Oi" Project Name, PWS, PermiCEtc. I Sample Origin .2y\~ Q\M...("+e.r N I+('""t~ ;to\!t. State: l).~ M;(\~ Contact Nam e: Phone/Fax: Report Mail Address: 'PO 'BC)( 8' O~ B \"(\a~,,q ~ 84511 Cro..rr,l(\ 'P ~\01e(" 4~ ,,8 ~~ \ -Invoice Contact & Phone: . . Address: '-. InvoIce .c,) ~e D t\ ~ ~ 6.. -lv-.r k L..\~S '7€ ..222. \ Special Report/Formats: ~ ~&11 W~O@ OO§®01J~(g[Q) DDW DpOTWIWWTP o State: ----o Other: ---- D EDD/EDT(Electronic Data) Format: ___ _ D LEVEL IV o NELAC o ~ ~OCl)~ ~1ll:gOI (fi ._> (5 >-Ci) ~(/)~~~ 03:= co c> r-u<c~I.Q·S a ,-1ll1~ -'-Qj JH c: -;:: (") (I) c...('OI~ C (1\ ..c~ co' ; \ E Q) _= CD ~ ""I ~Q.<CI5rCl .... E >1 .". ~ ~ !----------~---,----_+_--__;_t) SAMPLE IDENTIFICATION Collection MATRIX ~ Name, Location,lnterval, etc. Date _JJ n-w~ )?ill~ \ ~2..0\~ "'\/lg/1~ 01,g 2-W )( ~fj_ iR_O~lK::LO\~ 1~/l1i''J.. Cb40 ;2"'W :i 3 "'vJ~ .. OLO\"\H'~~ ~/rxlJ2. :L-W "; OK 0:\ 4 '1:vJN-_O.5-u~ t K2..0i2 ~ I~I US I J:}' 10'\'"\.5 2.,-"'-.J 5 . ,vJ/V -Q' _ 0"\' ~\~ 1'-\"8/,~ I ~O~ :1-vv' '/. '1A~/l~ I )-:)38 6 1'NN .. \ 0_0 '" ''1.2.0 \;t t 2-W 7-rwN .. O~_04'Kd..Otl. 14/lg/t2.! I~ ~-vJ ')( 8IvJtJ-12_0~\~~J2. 1'1/1i(/1~ Ir~yY ~-w y 9 "T\NN -01>_O'1,g,()\~J~/lg!,~ I \'-\'11 2-vJ [)< 10~\,VtJ-l!;_Ot..t:l{)U)\~l1PDI1d. I DU, .::2..-W x Custody Record ~~~~~~~~~~ \too Received by (print): Receivedby (print): t=' o ~ lJ.l _ I "0 (J § « e J-m t-E « ~ W "E W en C/) ~ ro Ci5 Email: Sampler: (Please Print) ~Y\nc(' +I ollitlAt Purchase Order: Quote/Bottle Order: .. R u 5 H DatefTime: DatefTime: Contact ELI prior to RUSH sample submittal for charges and scheduling -See Instruction Page Comments: Clle~;f Receipt Temp r2,~ °C On lee: ~N Custody Seal On Bottle ~N On Cooler N Intact N Signature N Match I~ I~ ~ l~ I~ ~ ~ ~ ,~ ~ (6) 1~CJ.20~a ~ Signature: Signature: MUSTbe~------------------------------~~~~~ __ ~~~~~ __ ~~~ ____ ~ S· d l ' ~'inature: Igne Samj)le D~osal: Return t9 C~nt: Lab Disposal: ~I In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to compl~~h4al'~iS/requested. This serves as notice of this possibility. All SUb-contract data will be clearly notated on your analytical report. \ \J "\J' •• •• " • • ~ , .... • L_~_ ..... __ .~_" ,.al"·uunl""",.,,..hl,,, .f ____ k",.. .. I,o. fnrrnC!' ~nti link~ "U Q) co CD ~ (JI o -., ~ 0) .. -------------_ .. ~-----. .. _ ...... -------. --.... --_._.-., Company Name: Project Name, PWS, Permit, Etc. Sample Origin EPA/State Compliance: State: Yes 0 No 0 Report Mail Address: StlYVI-C Contact Name: ~ Phone/Fax: Email: Sampler: (Please Print) 1 I rA-S. \ (-A. c1 e.. Invoice Address: Invoice Contact & Phone: ~ Purchase Order: Quote/Bottle Order: Special Report/Formats: s: ~&11 )1@O® OO~@l1D~@LI~[Q) .. Contact EU prior to .ShiJ:~ 0 "-RUSH sample submittal ~o (/)~ ~ for charges and "COoler 10(s): ~m;gOICi3 r::: 0 < R scheduling -See Cf,:v,.,1-._> 0 >oro w t:, I nstruction Page D OW 0 EDO/EDT(Electronic Data) ~(/)~~3: ~ 03:= ~ C» I "C Receipt Temp o POTWNVWTP Format: (J c Comments: ~«~I.Q~ :J U o ~ml c: \J « 0 ,2{., °c D State: 0 LEVEL IV •• Q) c: .-I-m ... ~1Q 00 c: -o Other: D NELAC ~~I~I \\: ~ ... On Ice: 0:)N ::J :J~~I&3: l-S Z a.. (J.)O W "E Custody Seal ~ >1 l W ctI D""'" ~ N en "C On Cooler N en c: i9 H Intact N C/) SAMPLE IDENTIFICATION Collection Collection MATRI.~ Signature aN {Name, Location, Interval, etc.) Date Time Match 1 -rwJ\}"'"11_04l 'I2.D \-:t 41'0.1 t:l. 01'S~ ,2-W Va I~ 2 i4/J~fl~ 08'15 :2.-vJ I~ ""1WN-\)(. ,O~ \,\;2,.012-~ 3 '1/~/JA Db40 =Z-w 'I IQ) ~tJ ... 01_0~!l.P;tOl:l nnn 4 U./IQ/o. 2 ... W 'f ~ ",wN-I..b_04lq~O 12 tOOl ~ ~vJtJ-\'i O'i2D~}~ i1/:JJ:>I Ie?.. ob5() ;L .... ~ X '= ~ 6 "f¥JN· t <1_ 04 t q a..ot1. !'1h'\/I=l ~O2-~-\A-") Y. ~ 7 ~JJ-11_o\.\~D201.l.. Y/;10/t:t Db5~ .2.-W ~ lit::! I~ iW fJ-0'1 __ {)l1!lO~I~ y/~o/J':L Oio~ ..:l,-W y ~ -TvJN -O~_ O~~;tO~ l.{{ UJ/ L.2 OilS .:J..-w )if 1~2)~I~ Tw f\.J -O:t _ 0 '1 :1.,(.).2,0 (:2-i'1l !JJ}/I~ o·1:J,.~ ::l ... W y. leJ Custody r?,;~u;;ed N~(lt;lUj 4 /~/:i~ "oa ~~~ ~~:tu~lI~k Received by (print): DatelTime: Signature: Record Relinquished by (print): 0 DatelTlme: Signature: V' Received by (print): DatelTime: Signature: MUST be Signed Sample Disposal: Return to Client: Lab Disposal: Kecelv" 0: zL;:7i 9 .. _~e/nme\ 1Jh'JA ~ignature: ~ -. ""U Q) co co ~ 0) o ....... ~ 0) II/SJJ..~lIr~fftY Chain of Custody and Analytical Request Record PLEASE PRINT (Provide as much information as possible.) Page~of ~ Company Name: Project Name, PWS, Permit, Etc. I Sample Origin EPA/State Compliance: State: Yes D No 0 Report Mail Address: s (~yV\ d contact;:~ 15:~ ~ ) Email: Sampler: (Please Print) I nvoice Address: Invoice Contact & Phone: <::::s Purchase Order: Quote/Bottle Order: Special Report/Formats: 5: &r;:[]&11 'i1@50@ rru~®C!D[§@LJ@:[Q) o ..... ~O(/)~ ~m;gOI ~ ._> 0 ~10 a,,, en (0:::.. Cl w • ~I R ~ Contact ELI prior to RUSH sample submittal for charges and scheduling -See L5ni~edbY: . ~. Cooler lO(s): eL~ c: "'''U5 (/):> ....... 03:1S~C) ,~ ~ « cnl·Q ~ -:-;, o .... m1c ",,4 .... Q) 1B r:: 'i:: rtl ~~I~O L"I Er-> ro I '-I :::JJ!:!~I~5: oW za.. (1)0 ++ E >1 ~ ~ Ie Dow o POlWMlWTP o State: ----o Other: ___ _ D EDD/EDT(Electronic Data) Format: ____ _ D LEVEL IV o NELAC SAMPLE IDENTIFICATION Collection Name, Location, Interval, etc. Date ColI~tion I MATRIX Time ~ n, \"".01 Ob~ ..2-vJ ~- ~~ :l.-"-' ;x 3 l.f"~ 1;1. \25S ;2.-w b{ 4.:).O.:tO, ~ '1/:,lC/ I ~ OG:;l7 .2-\IoJ )( 5 l'1.D/l~ 1305 ~~\~ .:l-\J ti ~ .u>/l2. \;2..~:S ;L.-w i 7 /2D/l;2.. )2.50 ~-w ft~~O~I~ 1 8 al 9 f 'f -- 10 Signature:' v Custody I ~ljnqUiSheaby(pri!lV:\ DatelTime: ~lAJ\t1~r Ho\"d.~~ YJ.2?:,/.2..0I~ \l00 ~un:g~:eJ4t;~ Record Relinquished by (print): DatelTime: I "C I nstruction Page Comments: U c:: ~ ~ I U C\1 l-e: .... <t: :::J W ~ I 5 w ctI en "C c:: co en I H Received by (print): DateJTime: Received by {print): DatelTime: Receipt Temp i.G °c On Ice: _~N Custody Seal On Bottle ~ N On Cooler Y N Intact Y N Signature N Match ~ ~~ ~ I 1-.:;::1 ~ ~ l~ I~ (6) ~CJ.2cJ4/ /--sl> I~ Signafure: Signature: M~STbe~--------------------------------------------~~~~~~~----~~~--~--____ ~~,gn~a~ure~:--------~ S Ig ned Sample DispQSal: Return to Client: Lab Disposal: J .IM"~ J In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to compl~ a~SiS requested. This serves as notice of this possibility. All sub·contract data will be clearly notated on your analytical report. o::.y Visit our web site at www.ener~b.com for additional information, downloadl<lhJA fAp. ~('h.,.,-illl,Q fnrrnc> !:Ionrl lin!" .. TabH Quality Assurance and Data Validation Tables B-1 Field Data QAlQC Evaluation Volume .l '" Location . 2x Casing Volume Pumped Volume Check Cwiductivity RPD pH :" RPD Temp RPD Piezometer 1 --2195.0 NC 8.30 NC 15.57 NC Piezometer 2 --676.3 NC 6.89 NC 15.54 NC Piezometer 3 --3080.0 NC 12.19 NC 15.41 NC TWN-l 39.7 79.40 91.00 OK 803.0 804.0 0.12 7.56 7.56 0.00 15.01 15.01 0.00 TWN-2 48.77 97.54 72.00 Pumped Dry 3006.0 NC 6.78 NC 13.51 NC TWN-3 41.23 82.46 57.00 Pumped Dry 2434.0 NC 7.31 NC 14.83 NC TWN-4 55.5 111.00 143.00 OK 1034.0 1034.0 0.00 7.34 7.34 . 0.00 14.94 14.93 0.07 TWN-5 52.52 105.04 117.00 OK 3061.0 3061.0 0.00 7.05 7.05 0.00 14.91 14.91 0.00 TWN-6 35.75 71.50 91.00 OK 1541.0 1543 .0 0.13 7.14 7.14 0.00 14.93 14.94 0.07 TWN-7 11.02 22.04 19.00 Pumped Dry 1153.0 NC 7.73 NC 14.76 NC TWN-8 54.74 109.48 117.00 OK 2369.0 2374.0 0.21 7.60 7.56 0.53 14.57 14.57 0.00 TWN:"9 22.29 44.58 36.00 Pumped Dry 2562.0 NC 6.93 NC 15.33 .' NC TWN-lO 15.78 31.56 32.00 Pumped Dry 3609.0 NC 4.60 NC 15.66 NC TWN-ll 47.38 94.76 120.00 OK 2780.0 2780.0 0.00 7.04 7.04 0.00 14.56 14.57 0.07 TWN-12 53.21 106.42 130.00 OK 2465 .0 2464.0 0.04 7.32 7.32 0.00 14.90 14.91 0.07 TWN-13 64 .94 129.88 143.00 OK 860.0 858.1 0.22 8.01 8.01 0.00 14.96 14.95 0.07 TWN-14 47.3 94.60 57.00 Pumped Dry 1021.0 NC 7.91 NC 15.13 NC TWN-15 40.71 81.42 72.00 Pumped Dry 1568.0 NC 7.27 NC 14.52 NC TWN-16 34.08 68.16 84.00 OK 1853.0 1848.0 0.27 7.21 7.21 0.00 14.90 14.90 0.00 TWN-17 49.69 99.38 78.00 Pumped Dry 1135.0 NC 7.47 NC 15.09 . NC TWN-18 57 114.00 132.00 OK 2165.0 2167.0 0.09 7.18 7.18 0.00 14.35 14.35 0.00 TWN-19 37.57 75.14 84.00 OK 1980.0 1972.0 0.40 7.39 7.40 0.14 15.39 15.60 1.36 Piezometers 1, 2, and 3 were not pumped, only one set of parameters were taken. TWN-2, TWN-3, TWN-7, TWN-9, TWN-14, TWN-15, and TWN-17 were purged to dryness before 2 casing volumes were removed. TWN-1O was purged to dryness after 2 casing volumes were removed. RPD > than 10% ;,. I' :,. Redox Potential ): RPD Turbidity RPD 209 NC 4.0 NC 474 NC 1.6 NC 177 NC 5.2 .. NC 217 216 0.46 27.3 27.4 0.37 454 NC 24.3 NC 395 NC 100.0 NC 233 232 0.43 120.0 118.0 1.68 319 315 1.26 3.0 3.0 0.00 249 248 0.40 10.1 10.0 1.00 309 NC 8.0 NC 113 115 1.75 3.0 3.0 NC 296 NC 11.0 NC 498 NC 75.7 NC 343 340 0.88 2.9 2.9 0.00 191 195 2.07 161.0 165.0 2.45 151 149 1.33 lOA 10.4 0.00 188 NC 42.3 NC 369 NC 22.6 NC 299 296 1.01 2.5 2.5 0.00 360 NC 77.1 NC 336 335 0.30 44.6 44.7 0.22 212 212 0.00 10.6 10.7 0.94 The QAP states that turbidity should be less than 5 Nephelometric Turbidity Units ("NTU") prior to sampling unless the well is characterized by water that has a higher turbidity. The QAP does not reguire that turbidity measurements be less than 5 NTU prior to sarnp>ling. As such the noted observations regarding turbidi!y measurements less than 5 NTU below are included for information I>U!I'oses onl . . ~ H-2: Holding Time Evaluation H-3: Analytical Method Check Nitrate Chloride A4500-CI B A4500-CI B Both Nitrate and Chloride were analyzed with the correct analytical method. H-4: Reporting Limit Evaluation U = Analyte was not detected at the RL D = RL was increased due to sample matrix or required dilution due to the sample concentration. In all cases the analytical results were greater than the reporting limit used. H-7 Piezometer 1,Piezometer 2, Piezometer 3, TWN-l,TWN-2, TWN-3,TWN-4,TWN-5,TWN-6,TWN-7,TWN-8, TWN- C12041150 9,TWN-I0, TWN-ll,TWN-12,TWN-13,TWN-13R, TWN-2.6 °C 14,TWN-15,TWN-15R,TWN-16, TWN-17, TWN-18, TWN-19, TWN-60,TWN-65,TWN-70 H-8 Rinsate Evaluation Previous Rinsate Sample Parameter Rinsate Result Well Sample TWN-13R Nitrogen ND mglL N/A TWN-13R Chloride ND mglL N/A TWN-15R Nitrogen ND mglL TWN-06 TWN-15R Chloride 1 mglL TWN-06 TWN-60 Nitrogen ND mglL Piez-01 TWN-60 Chloride 1 mglL Piez-01 The Rmsate sample Identified m Column 1 was collected after the pump was used to purge the well identified as "Previous Well Sampled" in Column 4 D = Reporting limit raised due to dilution/sample matrix. Reporting Result for Well Qualifier Limit NA 0.1 mglL NA 1mgIL 1.1 mglL 0.1 mglL 22 mglL 1mgIL 6.6 mglL D 0.1 mglL 58 mglL 1mgIL Tab I Kriged Current Quarter Isoconcentration Maps NS = not sampled; ND = not detected '-10 till MW-4 .4.9 TW4-1 0 7.1 TWN-1 ~0.6 PIEZ-1 ~ 6.6 TW4-27 ~41 kriged nitrate isocon and label kriged nitrate isocon and label (extent uncertain) perched monitoring well showing concentration in mg/L temporary perched monitoring well showing concentration in mg/L temporary perched nitrate monitoring well showing concentration in mg/L perched piezometer showing concentration in mg/L temporary perched monitoring well installed October 2011 showing concentration in mg/L HYDRO GEO CHEM, INC. KRIGED 2nd QUARTER, 2012 NITRATE (mg/L) (NITRATE + NITRITE AS N) 'APPROVED ' "1 DATE WHITE MESA SITE . "REFERENCE H:/718000/aug12/nitrate/Unt0612.srf FIGURE I-I NS = not sampled; NO = not detected MW-4 .39 TW4-1 0 42 TWN-1 ~17 PIEZ-1 Q 58 TW4-27 *17 perched monitoring well showing concentration in mg/L temporary perched monitoring well showing concentration in mg/L temporary perched nitrate monitoring well showing concentration in mg/L perched piezometer showing concentration in mg/L temporary perched monitoring well installed October, 2011 showing concentration in mg/L HYDRO GEO CHEM, INC. KRIGED 2nd QUARTER, 2012 CHLORIDE (mg/L) WHITE MESA SITE APPROVED DATE FIGURE H:/718000/aug12/chloride/UcI0612.srf 1-2 TabJ Analyte Concentrations Over Time TWN-l Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 0.7 19 7/21/2009 0.4 17 9/21/2009 0.4 19 10/28/2009 0.5 18 3/17/2010 0.5 17 5/26/2010 0.6 20 9/27/2010 0.6 19 12/7/2010 0.6 14 1/26/2011 0.5 17 4/20/2011 0.5 19 7/26/2011 0.5 14 10/17/2011 0.5 10 1/9/2012 0.6 15 4/18/2012 0.6 17 TWN-2 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 25.4 29 7/21/2009 25 25 9/21/2009 22.6 17 11/2/2009 20.8 55 3/24/2010 62.1 85 6/2/2010 69 97 9/29/2010 69 104 12/9/2010 48 93 2/1/2011 43 93 4/28/2011 40 85 7/28/2011 33 74 10/20/2011 33 76 1/12/2012 31 86 4/20/2012 48 103 TWN-3 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 23.6 96 7/21/2009 25.3 96 9/21/2009 27.1 99 11/2/2009 29 106 3/25/2010 25.3 111 6/3/2010 26 118 7/15/2010 27 106 12/10/2010 24 117 2/1/2011 24 138 4/28/2011 26 128 7/29/2011 25 134 10/20/2011 25 129 1/12/2012 25 143 4/20/2012 24 152 , TWN-4 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 1 13 7/21/2009 0.05 12 9/21/2009 0.4 13 10/28/2009 0.4 11 3/16/2010 0.9 22 5/27/2010 1.0 22 9/27/2010 0.9 19 12/8/2010 1 21 1/25/2011 0.9 21 4/20/2011 0.9 21 7/26/2011 1.1 35 10/18/2011 0.9 20 1/9/2012 0.9 20 4/18/2012 1.1 24 TWN-5 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 0.22 42 9/21/2009 0.5 45 11/10/2009 0.2 48 3/16/2010 0.3 43 5/26/2010 0.3 44 7/12/2010 0.3 43 12/7/2010 0.3 45 1/25/2011 0.4 47 4/20/2011 0.3 44 7/26/2011 0.3 44 10/17/2011 0.3 45 1/9/2012 0.2 45 4/18/2012 0.3 39 TWN-6 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 3.2 32 9/22/2009 1.6 13 11/3/2009 1.4 21 3/23/2010 1.5 19 6/1/2010 1.4 22 7/13/2010 1.4 73 i2/8/2010 1.2 21 1/26/2011 1.1 18 4/20/2011 1.5 22 7/27/2011 1.1 17 10/18/2011 1.4 21 1/10/2012 1.2 20 4/18/2012 1.1 22 TWN-7 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 ND 11 9/21/2009 ND 7 11/10/2009 0.1 7 3/17/2010 0.8 6 5/28/2010 1.2 6 7/14/2010 1.6 7 12/10/2010 1 4 1/27/2011 1.3 6 4/21/2011 1.7 6 7/29/2011 0.7 5 10/19/2011 2.2 6 1/11/2012 2.3 5 4/20/2012 1.2 6 TWN-8 Date Nitrate (mg/I) Chloride (mg/I) Notes 8/25/2009 0 11 Nitrate is NO 9/21/2009 0 12 Nitrate is NO 11/10/2009 0 12 Nitrate is NO 3/16/2010 0 11 Nitrate is NO 5/26/2010 0 11 Nitrate is NO 7/12/2010 0 11 Nitrate is NO 12/6/2010 0 9 Nitrate is NO 1/25/2011 0 13 Nitrate is NO 4/18/2011 0 10 Nitrate is NO 7/26/2011 0 18 Nitrate is NO 10/17/2011 0 10 Nitrate is NO 1/9/2012 0 11 Nitrate is NO 4/18/2012 0 15 Nitrate is NO TWN-9 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 9.3 169 9/22/2009 8.9 201 11/10/2009 12 205 3/23/2010 7.6 183 6/1/2010 7.6 175 7/15/2010 10.7 210 12/9/2010 8 172 2/1/2011 9.5 217 4/28/2011 10 192 7/29/2011 11 208 10/20/2011 10.9 134 1/12/2012 12.2 202 4/20/2012 10.6 209 TWN-l0 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 1.1 19 9/22/2009 1.6 35 11/10/2009 1.4 26 3/23/2010 1.5 54 6/4/2010 1 30 7/14/2010 0.2 21 12/8/2010 1.3 28 1/27/2011 0.3 40 4/21/2011 1.2 28 7/27/2011 0.1 28 10/18/2011 0.2 33 1/10/2012 0.8 44 4/19/2012 0.9 28 TWN-ll Date Nitrate (mg/I) Chloride (mg/I) 11/3/2009 1.3 74 3/17/2010 1.4 73 6/4/2010 1.3 72 9/27/2010 1.4 76 12/8/2010 1.4 72 1/27/2011 1.4 84 4/26/2011 1.4 76 7/27/2011 0.1 76 10/17/2011 1.6 76 1/10/2012 1.6 69 4/19/2012 1.6 71 TWN-12 Date Nitrate (mg/I) Chloride (mg/I) 11/3/2009 0.5 109 3/17/2010 0.7 113 5/26/2010 0.8 106 7/12/2010 0.7 112 12/7/2010 0.7 103 1/26/2011 4.2 87 4/26/2011 1 109 7/26/2011 0.6 102 10/17/2011 1.2 87 1/10/2012 0.9 104 4/18/2012 1.2 106 TWN-13 Date Nitrate (mg/I) Chloride (mg/I) Notes 11/4/2009 0.5 83 3/17/2010 0 47 Nitrate ND 5/26/2010 0.1 49 9/27/2010 0.2 53 12/7/2010 0.4 57 1/25/2011 1.6 103 4/26/2011 0 49 Nitrate ND 7/26/2011 0.1 49 10/17/2011 0 48 Nitrate ND 1/9/2012 0 46 Nitrate ND 4/18/2012 0 53 Nitrate ND TWN-14 Date Nitrate (mg/I) Chloride (mg/I) 11/4/2009 3.4 32 3/24/2010 2.9 24 6/2/2010 2.9 30 7/15/2010 3.5 26 12/10/2010 4.2 28 1/28/2011 3.7 24 4/27/2011 3.5 30 7/29/2011 3.5 25 10/19/2011 3.9 27 1/11/2012 3.5 26 4/20/2012 3.4 27 TWN-15 Date Nitrate (mg/I) Chloride (mg/I) 11/10/2009 1.1 78 3/18/2010 0.7 43 5/28/2010 1.0 39 7/13/2010 1.0 36 12/9/2010 1.2 38 1/27/2011 1.4 43 4/27/2011 1.6 49 7/28/2011 1.6 47 10/19/2011 1.3 38 1/11/2012 1.5 38 4/20/2012 1.6 46 TWN-16 Date Nitrate (mg/I) Chloride (mg/I) 11/4/2009 1 39 3/17/2010 1.2 35 5/27/2010 0.2 35 9/27/2010 2.6 35 12/9/2010 2 30 1/27/2011 4.6 34 4/27/2011 1.6 39 7/27/2011 2.4 31 10/18/2011 2.6 34 1/10/2012 2.8 33 4/19/2012 2 50 TWN-17 Date Nitrate (mg/I) Chloride (mg/I) 11/4/2009 6.7 152 3/24/2010 10.4 78 6/3/2010 11 87 7/15/2010 8.9 66 12/10/2010 8 65 2/1/2011 8.6 90 4/28/2011 9 81 7/29/2011 8.5 74 10/20/2011 8.1 71 1/12/2012 8.7 79 4/20/2012 9.1 80 TWN-18 Date Nitrate (mg/I) Chloride (mg/I) 11/2/2009 1.3 57 3/17/2010 1.6 42 6/1/2010 1.8 63 9/27/2010 1.8 64 12/9/2010 1.6 59 1/27/2011 1.4 61 4/26/2011 1.8 67 7/28/2011 1.8 65 10/18/2011 1.9 60 1/10/2012 1.9 64 4/19/2012 2.1 64 TWN-19 Date Nitrate (mg/I) Chloride (mg/I) 11/2/2009 7.4 125 3/23/2010 7.2 118 6/1/2010 6.2 113 9/29/2010 7.2 113 12/9/2010 7 107 2/1/2011 7 114 4/28/2011 6.9 120 7/28/2011 7.1 113 10/18/2011 6.5 108 1/10/2012 7 114 4/19/2012 6.8 117 Piezometer 1 Date Nitrate (mg/I) Chloride (mg/I) 2/19/2009 6.8 NA 7/14/2009 6.8 60 9/22/2009 7.3 78 10/27/2009 7.4 61 6/2/2010 7.2 52 7/19/2010 6.8 52 12/10/2010 6.5 60 1/31/2011 7 60 4/25/2011 6.8 58 7/25/2011 7 53 10/19/2011 6.6 55 1/11/2012 7.1 78 4/20/2012 6.6 58 Piezometer 2 Date Nitrate (mg/I) Chloride (mg/I) 2/19/2009 0.5 NA 7/14/2009 0.5 7 9/22/2009 0.5 17 10/27/2009 0.6 7 6/2/2010 0.6 8 7/19/2010 0.6 8 12/10/2010 0.2 6 1/31/2011 0.3 9 4/25/2011 0.3 8 7/25/2011 0.1 9 10/19/2011 0.1 8 1/11/2012 0.1 9 4/20/2012 0.2 8 Piezometer 3 Date Nitrate (mg/I) Chloride (mg/I) 2/19/2009 0.7 NA 7/14/2009 0.8 12 9/22/2009 0.8 24 10/27/2009 1.2 19 3/24/2010 1.7 116 6/2/2010 1.6 36 7/19/2010 1.6 35 12/10/2010 1.8 25 1/31/2011 1.8 40 4/25/2011 1.7 35 7/25/2011 1.8 61 10/19/2011 1.7 12 1/11/2012 1.8 20 4/20/2012 1.7 53 Piezometer 4 Date 7/14/2009 Nitrate (mg/I) 1.8 Chloride (mg/I) 46 Piezometer 5 Date 7/14/2009 Nitrate (mg/I) 0.7 Chloride (mg/I) 18 MW-18 Date Nitrate (mg/I) Chloride (mg/I) 7/14/2009 ND 51 MW-19 Date Nitrate (mg/I) Chloride (mg/I) 7/14/2009 2.2 24 Upper Wildlife Pond Oate Nitrate (mg/I) Chloride (mg/I) Note 9/22/2009 0 5 Nitrate NO 10/27/2009 0 3 Nitrate NO 6/2/2010 0 0 Nitrate and Chloride NO 7/19/2010 0 0 Nitrate and Chloride NO 12/10/2010 0 1 Nitrate NO 1/31/2011 0.1 1 4/25/2011 0 0 Nitrate and Chloride NO 7/25/2011 0 0 Nitrate and Chloride NO 10/19/2011 0 0 Nitrate and Chloride NO 1/11/2012 0 2 Nitrate NO Frog Pond Date 10/14/09 Nitrate (mg/I) o Chloride (mg/I) o Notes Nitrate ND TabK Concentration Trend Graphs en c 0 ;; m ... .., c Cl) (,) c 0 0 Cl) .., m ... ~ Z ~ • Z ~ r-----r-----r-------r-----.,-------,----.,------,-----.-l ~-PO 0 l ~-JdV .~~ ~ ~-das H 0 ~ ~-qa.::l ./~ ~ ~ 0~-5nv .~~ o~-uer ~~~ V~ 60-lnr V .V 90-oaO ~----~----~---~------~---~------~----+-----+90-unr co 6 I!) 6 ('t") o N o 6 ,--'-T----i-----r------r------.-~~-PO ~ ~-das ~ ~-qa.::J f/) c: 0 ;; CO .... .... c: Q) (,) c: 0 o~-5nv (.) Q) " "i: 0 .c: (.) ~ • o~-uer Z ~ ~~--------40----------~+---------~--------~----------1 go-unr N N 0 o tJ) c 0 ;; ns ~ ~ c CD 0 c 0 0 CD ~ ns ~ ~ Z N I Z ~ ...------r------,.----r------r----r-----,------,--'--,-l ~-PO ~ ~-das ~ ~-qa.::l 0~-5nv o ~-uer 80-oao ~----~------~----~------~----~------~----~----__+80-unr o 00 o c.o o L() o C") o C\I o tJ) c 0 +i CO ... .., C (1) (.) c 0 U (1) "C .~ 0 J: U N I Z ~ ~ ~-das ~ ~-qa,:j o~-5nv o~-uer ~-------+--------~--------~-------4--------~--------+go-unr o N o o ~ o CO o CO o N o U) c: 0 ;; CO '-.., c: CI) () c: 0 (.) CI) .., CO '-~ Z ('I) I Z ~ r------.r------r----r--.----,------r----.....,-----r l ~-PO ~ ~-das ~ ~-qa.::l o ~-6nV' o~-uer 80-0aO ~------~------~------~------~------+-------~------+80-unr I.C) ("t') o ("t') I.C) N o N I.C) o r---~--~---~-----'----""------r----r----r l ~-PO ~ ~-das 60-lnr 90-oao ~----~------~----~-----~-----+------+------+-----+90-unr o CO o N o o o cx::> o CO o N o en c: 0 ; ns L. ... c: CI) CJ c: 0 (.) CI) ... ns L. ~ Z .qo I Z ~ '.,..------.,..-----,-l ~ -PO ~ ~-des ~ ~-qe,:j o~-5nv o~-uer ~-------4--------_+--------~--------4_--------+_------__+g0-unr cx::> o co o (1/6w) N o o tJ) c: 0 ~ CO ~ ..., c: (1) 0 c: 0 (J (1) "C "i: .9 .c (J ~ I Z ~ r-----r-----,----,....-----r-----,----,...---...,...----r l ~ -PO ~ ~-das ~ ~-qa=f o~-6nv o~-uer ~----_+------+_-----4------~------+_----_+------4_----__+g0-unr o C') lC) N o U) t: 0 ; CO '-..., t: CD 0 t: 0 U CD ..., CO '-~ Z Lt) I Z ~ r------.,.------r-------r-----r--------r----~ l ~-PO ~ ~-das ~ ~-qa:f o ~-5nV' o~-uer 1------+-----+------+-----+------+-----+ 60-lnr co o IJ") o N o o U) s::::: 0 ;:; CO .... .... s::::: Q) () s::::: 0 (.) Q) "C at: 0 J: (.) Lt') • Z ~ .--------.-----...---------,..----.....--------,.------r l ~-PO ~ ~-das ~ ~-qa:J o ~-5nV' o~-uer f-------i-----+-----+----+------+-----I-60-lnr o CO o IJ") o N o o en c 0 ;; CU ~ ~ C Cl) 0 C 0 U Cl) ~ CU ~ ~ Z (0 I Z ~ I- ----r------,------r-----;----.,-----r--------r-l ~-PO ~ ~-das ~ ~-qa~ o~-5nv o~-uer 1------1-----+-----+----+----+------+----t--60-lnr I..() N N I..() o o tn s::::: 0 ;; CO L.. ..., s::::: CI) 0 s::::: 0 U CI) 'tl .~ 0 .s:::: U CO • Z ~ ....------,.-------r---..,..-------r-------r------r----r-----r l ~ -PO ~ ~-das ~ ~-qa::l o~-6nv o ~-uer !------4----+---l-----4----+---l-----I-----+ 60-lnr o CO o LO o C") o N o fn t: 0 ;:; CO '-..., t: CI) 0 t: 0 U CI) ..., CO '-~ Z ...... I Z ~ ,-----...,.------,------r--------r-------r l ~-Inr ~ ~-das ~ ~-unr ~ ~-qa:J O~-AON o~-5nv o ~-AeLI'J o ~-uer 60-PO !--------i---------if--------t--------f------+ 60-lnr l!) N N o I .-----. ........,-----.,.------r------,---------,-----.,-l ~-PO ~ ~-das fn c 0 ~ CO .... ..., c CD 0 C 0 ~ ~-qa.::J (.) CD "C ";: 0 J: (.) r--. • Z ~ o ~-Bn'v' o~-uer \-------!----.............;.-----l-----+----+-------+ 60-lnr o 00 N o ~ 0.9 0.8 0.7 0.6 :::r -C) E 0.5 - 0.4 0.3 0.2 0.1 o Q) o I :; ...., .... .... .... .... .... .... o T""" I C ro ...., .... .... .... .... .... .... TWN-8 Nitrate Concentrations TWN-8 Nitrate Concentrations are all Non Detect o T""" I 0> :::J « .... .... .... ..... T""" I ..c Q) LL .... .... ..... .... T""" T""" I c.. Q) Cf) .... .... .... ..... N T""" ~ c.. « .... ..... N T""" I U o tJ) r:::::: 0 ;:; CO '-.., r:::::: CD (.) r:::::: 0 U CD "C ";:: 0 J: U CO I Z ~ ~ ~-des ~ ~-qe=l o ~-Bn'v' o~-uer f----+---I---+-----j---+----+---+------l---+--+ 60-lnr o N 00 co N o 00 co N o ...-----...,,....-----.,.------r-------r------.------,------.-l ~-PO ~ ~-das fJ) t: 0 ;; cu .... .., t: Cl) (,) t: ~ ~-qa:J 0 U Cl) .., cu .... ~ Z 0) • Z ~ o ~-6n\f o~-uer !------l------!------+----+----+------l-----+ 60-lnr N o co N o tJ) c: 0 ;:; ns ~ ... c: CD (.) c: 0 0 CD "C "i: 0 J: 0 en I Z ~ ..--------r-------.------~-----....._------.-z ~-PO ~ ~-das ~ ~-qa.::l o ~-5n'v' o~-uer 1-------+------1-------+--------1-----+ 60-lnr o L() C\I o o C\I o L() o o ~ o L() o (/) t: 0 ;:: ns ... ... t: G) 0 t: 0 (.) G) ... ns ... ~ Z 0 ~ • Z ~ ·--,----..,.-----r-l~-PO ~ ~-das ~ ~-qa~ o ~-5n'v' o~-uer 1----+----+----+---+---+---+----+----+----+ 60-lnr N o o t/) c: 0 +:. 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G) 0. 0. ::J o ~-Aell'J o~-uer 60-l60 I------!-----+-----+-----+-----+-----+ 60-lnr ('I') o (1/6w) 0> o ~ LO o (1/6w) ~~ o 60-I\ON 60-PO 60-deS 60-deS 60-5nv 60-lnr f/) c: o ... ns ... .., c: CD (.) c: o (J CD "C ".: .2 J: (J "C c: o a. C) e LL 00 o <.0 o N o ~. 60-AON 60-PO 60-deS 60-deS 60-BnV TabL CSV Transmittal Letter Kathy Weinel From: Sent: To: Cc: Subject: Attachments: Dear Mr. Lundberg, Kathy Weinel Tuesday, August 14, 2012 1 :09 PM 'rlundberg@utah.gov' 'Phillip Goble'; Thomas Rushing iii; David Frydenlund; Jo Ann Tischler; David Turk; Harold Roberts; Jaime Massey Transmittal of CSV Files White Mesa Mill 2012 Q2 Nitrate Monitoring C12041150.CSV Attached to this e-mail are electronic copies of laboratory results for nitrate monitoring conducted at the White Mesa Mill during the second quarter of 2012, in Comma Separated Value (CSV) format. Please contact me at 303-389-4134 if you have any questions on this transmittal. Yours Truly Kathy Weinel Energy Fuels Resources (USA) Inc. Quality Assurance Manager 1