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HomeMy WebLinkAboutDRC-2012-001154 - 0901a068802b07fc0-2:12-001154 MINES Sent VIA Federal Express February 16 2012 Mr Rusty Lundberg Co Executive Secretary Utah Water Quality Board Utah Department of Environmental Quality 195 North 1950 West PO Box 144820 Salt Lake City UT 84114 4820 Dentson Mines (USA) Corp 105017th street Suite 950 Denver CO 80265 USA Tel 303 628 7798 Fax 303 389 4125 www denisonmines com Re Re Transmittal of 4th Quarter 2011 Nitrate Monitoring Report UDEQ Docket No UGW 09 03 White Mesa Uranium Mill Dear Mr Lundberg Enclosed are two copies of the White Mesa Uranium Mill Nitrate Monitoring Report for the 4th Quarter of 2011 as required by the January 2009 Stipulated Consent Agreement UDEQ Docket No UGW 09 03 as well as two CDs each containing a word searchable electronic copy of the report If you should have any questions regarding this report please contact me Yours very truly . DENISON MINES (USA) CORP Jo Ann Tischler Director Compliance and Permitting CC Ron F Hochstein David C Frydenlund Harold R Roberts David E Turk Kathy Weinel Central Files OENISONI)~~ MINES Sent VIA Federal Express February 16, 2012 Mr. Rusty Lundberg Co-Executive Secretary Utah Water Quality Board Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144820 Salt Lake City, UT 84114-4820 Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, CO 80265 USA Tel: 303628-7798 Fax: 303389-4125 www.denisonmines.com Re: Re: Transmittal of 4th Quarter 2011 Nitrate Monitoring Report UDEQ Docket No. UGW-09-03 White Mesa Uranium Mill Dear Mr. Lundberg: Enclosed are two copies of the White Mesa Uranium Mill Nitrate Monitoring Report for the 4th Quarter of 2011 as required by the January 2009 Stipulated Consent Agreement, UDEQ Docket No. UGW -09-03, as well as two CDs each containing a word searchable electronic copy of the report. If you should have any questions regarding this report please contact me. ~trul~ DENISON MINES (USA) CORP. JoAnn Tischler Director, Compliance and Permitting CC: Ron F. Hochstein David C. Frydenlund Harold R. Roberts David E. Turk Kathy Weinel Central Files White Mesa Uranium Mill Nitrate Monitoring Report State of Utah Stipulated Consent Agreement, January 2009 Docket No. UGW09-03 4th Quarter (October through December) 2011 Prepared by: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver CO 80265 February 16, 2012 TABLE OF CONTENTS 1.0 INTRODUCTION ................................................................................................. 3 2.0 GROUNDW ATERNITRATE MONITORING ................................................ 3 2.1 Samples and Measurements Taken During the Quarter ..................................... 3 2.1.1 Nitrate Monitoring ...................................................................................... 3 2.1.2 Parameters Analyzed .................................................................................. 4 2.1.3 Groundwater Head and Level Monitoring .................................................. 4 2.2 Sampling Methodology and Equipment and Decontamination Procedures ....... 4 2.2.1 Well Purging and Depth to Groundwater ................................................... 5 2.2.2 Sample' Collection ....................................................................................... 5 2.3 Field Data ............................................................................................................ 7 2.4 Depth to Groundwater Data and Water Table Contour Map .............................. 7 2.5 Laboratory Results .............................................................................................. 7 2.5.1 Copy of Laboratory Results ........................................................................ 7 2.5.2 Regulatory Framework ............................................................................... 7 3.0 QUALITY ASSURANCE AND DATA VALIDATION ................................... 8 3.1 Field QC Samples ............................................................................................... 8 3.2 Adherence to Mill Sampling SOPs ..................................................................... 9 3.3 Analyte Completeness Review ........................................................................... 9 3.4 Data Validation ................................................................................................... 9 3.4.1 Field Data QAlQC Evaluation .................................................................... 9 3.4.2 Holding Time Evaluation .......................................................................... 10 3.4.3 Receipt Temperature Evaluation ............................................................... 10 3.4.4 Analytical Method Checklist .................................................................... 10 3.4.5 Reporting Limit Evaluation ...................................................................... 10 3.4.6 QAlQC Evaluation for Sample Duplicates ............................................... 11 3.4.7 Rinsate Check ........................................................................................... 11 3.4.8 Other Laboratory QAlQC .................................................................•....... 12 4.0 INTERPRETATION OF DATA ....................................................................... 13 4.1 Interpretation of Groundwater Levels, Gradients and Flow Directions ........... 13 4.1.1 Current Site Groundwater Contour Map ................................................... 13 4.1.2 Comparison of Current Groundwater Contour Map to Groundwater Contour Map for Previous Quarter ........................................................... 13 4.1.3 Hydrographs .............................................................................................. 14 4.1.4 Depth to Groundwater Measured and Groundwater Elevation ................. 14 4.2 Review of Analytical Results ..................................... ; ...................................... 14 4.2.1 Current Nitrate and Chloride Isoconcentration Maps ............................... 14 4.2.2 Nitrate and Chloride Concentration Trend Data and Graphs .................... 14 4.2.3 Interpretation of Analytical Data .............................................................. 14 5.0 CORRECTIVE ACTION REPORT ................................................................. 15 5.1 Rinsate Blank Sample Chloride Levels .................................................................. 15 5.2 Assessment of Previous Quarter's Corrective Actions ..................................... 16 6.0 CONCLUSIONS AND RECOMMENDATIONS ............................................ 17 7.0 ELECTRONIC DATA FILES AND FORMAT .............................................. 17 8.0 SIGNATURE AND CERTIFICATION ........................................................... 18 1 N:\Required Reports\Nitrate QUaI1erly Monitoring Repolt\2011 Q4\2011 Q4 Nitrate Repolt text.docx LIST OF TABLES Table 1 Summary of Well Sampling and Constituents for the Period Table 2 Nitrate Percent Difference Table 3 Chloride Percent Difference INDEX OF TABS Tab A Site Plan and Perched Well Locations White Mesa Site Tab B Order of Sampling and Field Data Worksheets Tab C Kriged Current Quarter Groundwater Contour Map and Depth to Water Data Tab D Kriged Previous Quarter Groundwater Contour Map Tab E Hydrographs of Groundwater Elevations Over Time for Nitrate Monitoring Wells Tab F Depths to Groundwater and Elevations Over Time for Nitrate Monitoring Wells Tab G Laboratory Analytical Reports Tab H Quality Assurance and Data Validation Tables H -1 Field Data QAJQC Evaluation H-2 Holding Time Evaluation H -3 Anal ytical Method Check H -4 Reporting Limit Evaluation H-5 QAJQC Evaluation for Sample Duplicates H-6 QC Control limits for Analysis and Blanks H -7 Receipt Temperature Evaluation H -8 Rinsate Evaluation Tab I Kriged Current Quarter Nitrate and Chloride Isoconcentration Maps Tab J Analyte Concentration Data Over Time Tab K Nitrate and Chloride Concentration Trend Graphs Tab L CSV Transmittal Letter 2 N:\Required Reports\Nitrate Quarterly Monitoring Report\201l Q4\201l Q4 Nitrate Report text.docx 1.0 INTRODUCTION The Utah Department of Environmental Quality ("UDEQ") Division of Radiation Control ("DRC") noted in a Request dated September 30, 2008 (the "Request") , for a Voluntary Plan and Schedule to Investigate and Remediate Nitrate Contamination at the White Mesa Uranium Mill (the "Mill") (the "Plan"), that nitrate levels have exceeded the State water quality standard of 10 mg/L in certain monitoring wells. As a result of the Request, Denison Mines (USA) Corp. ("DUSA") entered into a Stipulated Consent Agreement (the "Consent Agreement") with the Utah Water Quality Board in January 2009 which directed the preparation of a Nitrate Contamination Investigation Report ("CIR") and Quarterly Nitrate Monitoring Reports. A subsequent letter dated December 1, 2009, among other things, recommended that DUSA also address elevated chloride concentration in the Nitrate Monitoring Reports. The Consent Agreement ("CA") was amended in August 2011. Under the amended Consent Agreement, DUSA submitted a Corrective Action Plan ("CAP"), pursuant to the requirements of the Utah Groundwater Quality Protection Rules [UAC R317-6-6.15(C -E)] on November 29, 2011. This is the Quarterly Nitrate Monitoring Report, as required under the Consent Agreement, State of UDEQ Docket No. UGW-09-03 for the fourth quarter of 2011. 2.0 GROUNDWATER NITRATE MONITORING 2.1 Samples and Measurements Taken During the Quarter A map showing the location of all groundwater monitoring wells, piezometers, existing wells, temporary chloroform contaminant investigation wells and temporary nitrate investigation wells is attached under Tab A. Nitrate samples and measurements taken during this reporting period (October through December 2011), are discussed in the remainder of this section. 2.1.1 Nitrate Monitoring Quarterly sampling for nitrate monitoring parameters was performed in the following wells: TWN-1 TWN-8 TWN-15 Piezometer 2 TWN-2 TWN-9 TWN-16 Piezometer 3 TWN-3 TWN-10 TWN-17 TWN-4 TWN-11 TWN-18 TWN-5 TWN-12 TWN-19 TWN-6 TWN-13 Upper Wildlife Pond ("UWLP") TWN-7 TWN-14 Piezometer 1 Table 1 provides an overview of all locations sampled during the current period, along with the date samples were collected from each location, and the date(s) upon which analytical data were received from the contract laboratory. Table 1 also identifies rinsate samples collected, as well as sample numbers associated with any required duplicates. 3 N:\Required Reports\Nitrate Quarterly Monitoring Report\201 I Q4\201 I Q4 Nitrate Report text.docx As indicated in Table 1, nitrate monitoring was performed in all of the nitrate monitoring wells, the UWLP, and Piezometers 1, 2, and 3. Analytical data for all of the nitrate wells, piezometers and the UWLP are included in Tab G. Nitrate and chloride are also monitored in all of the Mill's groundwater monitoring wells and chloroform investigation wells. Data from those wells for this quarter are incorporated in certain maps and figures in this report but are discussed in their respective programmatic reports. 2.1.2 Parameters Analyzed Locations sampled during this reporting period were analyzed for the following constituents: • Inorganic Chloride • Nitrate plus Nitrite as Nitrogen (referred to herein as nitrate) Use of analytical methods consistent with the requirements of the White Mesa Uranium Mill Groundwater Quality Assurance Plan, Revision 6, March 22,2010 (the "QAP") was confirmed for all analytes, as discussed later in this report. 2.1.3 Groundwater Head and Level Monitoring Depth to groundwater was measured in the following wells and/or piezometers, pursuant to Part I.E.3 of the Groundwater Discharge Permits (the "GWDP") (February IS, 2011 and July 18, 2011): • The quarterly groundwater compliance monitoring wells. • Existing well MW -4 and all of the temporary chloroform investigation wells. • Piezometers -P-1, P-2, P-3, P-4 and P-S. • MW-20, MW-22, and MW-34. • The DR piezometers which were installed during the Southwest Hydrogeologic Investigation. • Nitrate monitoring wells. • In addition to the above, depth to water measurements are routinely observed in conjunction with sampling events for all wells sampled during quarterly and accelerated efforts, regardless of the sampling purpose. All well levels used for groundwater contour mapping were measured and recorded within S calendar days of each other as indicated by the measurement dates in the summary sheet under Tab C. 2.2 Sampling Methodology and Equipment and Decontamination Procedures The QAP provides a detailed presentation of procedures utilized for groundwater sampling activities under the GWDP (July 14, 2011). 4 N:\Required Reports\Nitrate Quarterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Repol1 texLdocx The sampling methodology, equipment and decontamination procedures that were performed for the nitrate contaminant investigation, as summarized below, are consistent with the QAP. 2.2.1 Well Purging and Depth to Groundwater A list of the wells in order of increasing nitrate contamination is generated quarterly. The order for purging is thus established. The list is included with the Field Data Worksheets under Tab B. Mill personnel start purging with all of the non-detect wells and then move to the more contaminated wells in order of nitrate contamination, starting with the wells having the lowest nitrate contamination. Before leaving the Mill office, the pump and hose are decontaminated using the cleaning agents described in Section 6.2.5 of the QAP. A rinsate blank is collected after the first pump decontamination of each day as described below. Mill personnel then proceed to the first well which is the well with the lowest concentration of nitrate based on the previous quarter's sampling results. Well depth measurements are taken and the two casing volumes are calculated (measurements are made using the same instrument used for the monitoring wells under the Mill's GWDP). The Grundfos pump (a 6 to 10 gallon per minute [gpmJ pump) is then lowered to the bottom of the well and purging is begun. At the first well, the purge rate is measured for the purging event by using a calibrated 5 gallon bucket. After the evacuation of the well has been completed, the well is sampled when possible, and the pump is removed from the well and the process is repeated at each well location moving from the least contaminated to most contaminated well. If sample collection is not possible due to the well being purged dry a sample is collected after recovery as described below. All wells are capped and secured prior to leaving the sampling location. Decontamination of non-dedicated equipment, using the reagents in Section 6.2.5 of the QAP, is performed between each sample location, and at the beginning of each sampling day, in addition to the pre-event decontamination described above. 2.2.2 Sample Collection Wells Following the purging of a nitrate investigation well, the sampling takes place once stabilization has been achieved in accordance with Section 6.2.7 of the QAP. Prior to leaving the Mill office for sampling, Mill Personnel prepare a cooler with ice. A trip blank is not required as the sampling event does not include analyses for Volatile Organic Compounds ("VOCs"). Once Mill Personnel arrive at the well sites, labels are filled out for the various samples to be collected. All personnel involved with the collection of water and samples are then outfitted with rubber gloves to avoid sample contamination. Each sample collection event begins at the location least affected by nitrate (based on the previous quarter's sampling event) and proceeds by affected concentration to the most affected location. The dedicated portable pump is appropriately decontaminated prior to 5 N:\Required Reports\Nitrate Qual1erly Monitoring Report\20 II Q4\2011 Q4 Nitrate RepOl1 text.docx each sampling event, each sampling day, and between well samples. It is important to note that the rinsate blank sample frequency was modified during the fourth quarter 2010 as recommended by UDEQ personnel present on site for split sampling during the chloroform sampling program. Previously, a rinsate blank sample was collected after each decontamination of the nondedicated pump and prior to the next use of the pump. Per an e-mail from Mr. Phil Goble, dated, November 15, 2010, the decreased rinsate blank frequency implemented during the chloroform sampling program was acceptable for implementation on the nitrate sampling program. Based on the revised procedure, rinsate blank samples are only required at the beginning of the sampling event and at the beginning of each day of sampling. The frequency change was implemented during fourth quarter 2010. Samples are taken from the portable pump after stabilization has been achieved, unless the well is pumped dry. If the well is pumped dry, Mill personnel use a disposable bailer to sample the well after it has recovered in accordance with Section 6.2.7 of the QAP. The bailer is attached to a reel of approximately 150 feet of nylon rope and then lowered into the well. After coming into contact with the water, the bailer is allowed to sink into the water in order to fill. Once full, the bailer is reeled up out of the well. Sample bottles are filled as follows: • First, a 250 ml sample is collected for nitrate/nitrite. This sample is not filtered, but is preserved with H2S04. • Second, a 500 ml sample is collected for chloride. This sample is not filtered and is not chemically preserved. After the samples have been collected for a particular well, the samples are placed into the cooler that contains ice. The well is then recapped and Mill personnel proceed to the next well. If a bailer has been used it is disposed of. Ponds Grab samples are taken from the UWLP using a disposable bailer. Sample bottles are filled in the same manner as for wells, as stated above. After the samples are collected, the bailer is disposed of and samples are placed into a cooler containing ice for sample preservation and transit to the Mill's contract analytical laboratory, Energy Laboratories ("EL"). Piezometers Samples are collected from Piezometers 1, 2 and 3, if possible. Samples are collected from piezometers using a disposable bailer following the procedures described for wells thathave been pumped dry, above. However, due to the difficulty in obtaining samples from the piezometers, the purging protocols set out in the QAP are not followed. 6 N:\Required Reports\Nitrate Qualterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Report texLdocx After samples are collected, the bailer is disposed of and samples are placed into a cooler containing ice for sample preservation and transit to the Mill's contract analytical laboratory, EL. 2.3 Field Data Attached under Tab B are copies of all Field Data Worksheets that were completed during the quarter for the nitrate contaminant investigation monitoring wells, piezometers, and UWLP identified in Section 2.1.1 above, and Table 1. It is important to note that the field data sheet appearance was changed in the fourth quarter 2010 as a result of the implementation of an electronic data capture system. The field data sheets contain the same information as the approved field data sheet attached to the approved QAP in approximately the same location. The new data sheets allow the electronic capture of data while still maintaining the real-time recording of information manually in ink as required by UDEQ. The changes were made to accommodate the data recording and validation system. 2.4 Depth to Groundwater Data and Water Table Contour Map Depth-to-groundwater measurements which were utilized for groundwater contours are included on the Quarterly Depth to Water Sheet at Tab C of this Report along with the kriged groundwater contour map for the current quarter generated from this data. All well levels used for groundwater contour mapping were measured and recorded within 5 calendar days of each as indicated by the measurement dates in the summary sheet under Tab C. A copy of the kriged groundwater contour map generated from the previous quarter's data is provided under Tab D. 2.5 Laboratory Results 2.5.1 Copy of Laboratory Results All analytical results were provided by EL. Table 1 lists the dates when analytical results were reported to the Quality Assurance ("QA") Manager for each well or other sample. Results from analysis of samples collected for this quarter's nitrate investigation are provided under Tab G of this Report. Also included under Tab G are the results of analyses for duplicate samples and rinsate samples for this sampling effort, as identified in Table 1. See the Groundwater Monitoring Report and Chloroform Monitoring Report for this quarter for nitrate and chloroform analytical results for the groundwater monitoring wells and chloroform investigation wells not listed in Table 1. 2.5.2 Regulatory Framework As discussed in Section 1.0 above, the Request, Plan, and Consent Agreement each triggered a series of actions on DUSA's part. Potential surficial sources of nitrate and chloride have been described in the December 30, 2009 CIR and additional investigations into potential sources were completed. Pursuant to the Consent Agreement, a CAP was 7 N:\Required Reports\Nitrate Quarterly Monitoring Report\20ll Q4\201l Q4 Nitrate Report text.docx submitted to the Co-Executive Secretary on November 29, 2011. The CAP will describe future activities associated with the nitrate in groundwater. This quarterly report documents the continued monitoring consistent with the program described in the initial Nitrate Contamination Investigation Report submitted in 2009. The monitoring program . and reporting requirements set forth in the 2009 Contamination Investigation report will remain in effect until further notice and completion of the CAP. 3.0 QUALITY ASSURANCE AND DATA VALIDATION The Mill QA Manager performed a QAlQC review to confirm compliance of the monitoring program with requirements of the QAP. As required in the QAP, data QA includes preparation and analysis of QC samples in the field, review of field procedures, an anal yte completeness review, and QC review of laboratory data methods and data. Identification of field QC samples collected and analyzed is provided in Section 3.1. Discussion of adherence to Mill sampling Standard Operating Procedures ("SOPs") is provided in Section 3.2. Analytical completeness review results are provided in Section 3.3. The steps and tests applied to check field data QAlQC, holding times, receipt temperature and laboratory data QAlQC are discussed in Sections 3.4.1 through 3.4.7 below. The analytical laboratory has provided summary reports of the analytical QAlQC measurements necessary to maintain conformance with National Environmental Laboratory Accreditation Conference ("NELAC") certification and reporting protocol. The Analytical Laboratory QAlQC Summary Reports, including copies of the Mill's Chain of Custody and Analytical Request Record forms for each set of Analytical Results, follow the analytical results under Tab G. Results of review of the laboratory QAlQC information are provided under Tab H and discussed in Section 3.4, below. 3.1 Field QC Samples The following QC samples were generated by Mill personnel and submitted to the analytical laboratory in order to assess the quality of data resulting from the field sampling program. Field QC samples for the nitrate investigation program consist of one field duplicate sample for each 20 samples, one DI Field Blank ("DIFB") and equipment rinsate samples. During the quarter, two duplicate samples were collected as indicated in Table 1. The duplicates were sent blind to the analytical laboratory and analyzed for the same parameters as the nitrate wells. Rinsate samples were also collected at the beginning of the sampling period and at the beginning of each day of sampling from the decontaminated pump used for purging and sampling. Rinsate samples were labeled with the name of the subsequently sampled well with a terminal letter "R" added (e.g. TWN-7R). The results of these analyses are included with the routine analyses under Tab G. 8 N:\Required Reports\Nitrate Quarterly Monitoring Report\20ll Q4\2011 Q4 Nitrate Repolt text.docx 3.2 Adherence to Mill Sampling SOPs On a review of adherence by Mill personnel to the existing sampling SOPs, the QA Manager observed that QAlQC requirements established in the QAP were being adhered to and that the SOPs were implemented, except as noted below. 3.3 Analyte Completeness Review All analyses required by the GWDP for nitrate monitoring for the period were performed. 3.4 Data Validation The QAP and GWDP (July 14, 2011) identify the data validation steps and data QC checks required for the nitrate monitoring program. Consistent with these requirements, the QA Manager performed the following evaluations: a field data QAlQC evaluation, a holding time evaluation, an analytical method check, a reporting limit evaluation, a QC evaluation of sample duplicates, a QC evaluation of control limits for analysis and blanks, a receipt temperature evaluation, and a rinsate evaluation. Because no VOCs are analyzed for the nitrate contamination investigation, no trip blanks are required in the sampling program. Each evaluation is discussed in the following sections. Data check tables indicating the results of each test are provided under Tab H. 3.4.1 Field Data QAlQC Evaluation The QA Manager performs a review of all field recorded parameters to assess their adherence with QAP requirements. The assessment involved review of two sources of information: the Field Data Sheets and the Quarterly Depth to Water summary sheet. Review of the Field Data Sheets addresses well purging volumes and stability of five parameters: conductance, pH, temperature, redox potential, and turbidity. Review of the Depth to Water data confirms that all depth measurements used for development of groundwater contour maps were conducted within a five-day period of each other. The results of this quarter's review are provided under Tab H. Based upon this review, all well locations conformed to the QAP requirement to evacuate two well casing volumes before sampling except TWN -2, TWN -3, TWN -7, TWN -9, TWN -14, TWN -15, and TWN -17. These seven wells were all pumped to dryness before two casing volumes were evacuated and more than one set of field parameters could be collected. In each case, representative samples of formation water were collected after the wells were allowed to recover. Piezometers 1,2, and 3 were not pumped, and were sampled directly after measurement of one set of parameters. Two casing volumes were pumped from TWN-10 before it was purged to dryness; however, only one set of field parameters were collected prior to TWN-10 being pumped dry. During review of the field data sheets, it was observed that sampling personnel consistently recorded depth to water for the quarterly sampling programs to the nearest 0.01 foot. 9 N:\Required Reports\Nitrate Quarterly Monitoring Report\2011 Q4\2011 Q4 Nitrate RepoIt text.docx All field parameters for all wells were within the QAP required limits, as indicated below. The review of the field sheets for compliance with QAP requirements resulted in the observations noted below. The QAP requirements in Section 6.2.7 specifically state that field parameters must have stabilized to within 10% over at least 2 consecutive measurements. The QAP states that turbidity should be less than 5 Nephelometric Turbidity Units ("NTU") prior to sampling unless the well is characterized by water that has a higher turbidity. The QAP does not require that turbidity measurements be less than 5 NTU prior to sampling. As such, the noted observations regarding turbidity measurements less than 5 NTU below are included for information purposes only. • Seventeen well measurements and the measurements from the Upper Wildlife Pond, and Piezometers 2 and 3 exceeded the QAP's 5 NTU turbidity goal as noted in Tab H. All turbidity RPD's met the QAP Requirement to stabilize within 10%. DUSA's letter to DRC of March 26, 2010 discusses further why turbidity does not appear to be an appropriate parameter for assessing well stabilization. In response to DRC's subsequent correspondence dated June 1, 2010 and June 24, 2010, DUSA has completed a monitoring well redevelopment program. The redevelopment report was submitted to DRC on September 30, 2011. Redevelopment results will be discussed with DRC in an effort to come to a consensus regarding turbidity considerations for the nitrate wells at the Mill site. 3.4.2 Holding Time Evaluation QAP Table 1 identifies the method holding times for each suite of parameters. Sample holding time checks are provided in Tab H. All samples were received and analyzed within the required holding time. 3.4.3 Receipt Temperature Evaluation Chain of Custody sheets were reviewed to confirm compliance with the QAP requirement in QAP Table 1 that samples be received at 6°C or lower. Sample temperatures checks are provided in Tab H. All samples were received within the required temperature limit. 3.4.4 Analytical Method Checklist All analytical methods reported by the laboratory were checked against the required methods enumerated in the QAP. Analytical method checks are provided in Tab H. All methods were consistent with the requirements of the QAP. 3.4.5 Reporting Limit Evaluation All analytical method reporting limits reported by the laboratory were checked against the reporting limits enumerated in the QAP. Reporting Limit Checks are provided in Tab 10 N:\Required Reports\Nitrate Quarterly Monitoring Report\20ll Q4\201l Q4 Nitrate Report text.docx H. All analytes were measured and reported to the required reporting limits, with the exception of 9 samples (8 samples and 1 duplicate) that had increased reporting limits due to matrix interference or required dilution due to the sample concentration. However, in all of those cases the analytical results were greater than the reporting limit used. 3.4.6 QAlQC Evaluation for Sample Duplicates Section 9.1.4 a) of the QAP states that RPDs will be calculated for the comparison of duplicate and original field samples. The QAP acceptance limits for RPDs between the duplicate and original field sample is less than or equal to 20% unless the measured results (described as activities in the QAP) are less than 5 times the required detection limit. This standard is based on the EP A Contract Laboratory Program National Functional Guidelines for Inorganic Data Review, February 1994, 9240.1-05-01 as cited in the QAP. The RPDs are calculated for all duplicate pairs for all analytes regardless of whether or not the reported concentrations are greater than 5 times the required detection limits. However, data will be considered noncompliant only when the results are greater than 5 times the required detection limit and the RPD is greater than 20%. The additional duplicate information is provided for information purposes. All duplicate results were within a 20% RPD. Results of the RPD test are provided in Tab H. 3.4.7 Rinsate Check Rinsate checks are provided in Tab H. Chloride A review of the analytical results reported for rinsate blank samples indicated that one of the rinsate blank samples contained chloride. A DIFB was analyzed and the results indicated that it also contained chloride. A comparison of the rinsate blank sample concentration levels to the QAP requirements -that rinsate sample concentrations be one order of magnitude lower than that of the actual well -indicated that the rinsate blank sample with a detection of chloride met this criterion. This criterion however, is irrelevant and inappropriate for the rinsate blank sample data collected during the nitrate sampling because rinsate blank samples are collected from the decontaminated portable pump used for well purging, and the pump is not used for sample collection. As stated in Section 2.2.1, wells that do not have a dedicated pump are purged using a portable pump. In wells where the portable pump is used for purging, a disposable bailer is used to collect the samples the day following purging activities. Based on the investigation into the source of chloride, DUSA believes that the potential source for the chloride present in the rinsate blanks has been identified. Chloride is frequently a byproduct of the chlorination process in potable water supplies. 11 N:\Required Reports\Nitrate Quarterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Report texLdocx DUSA believes the chloride contamination in the DI water is most likely the result of chlorination of the intake water used for the DI system. The chloride is most likely the result of the chlorination of the potable water at the Mill which is subsequently fed to the DI system. The chlorine added reacts with the naturally occurring organic and inorganic materials in the water. Corrective actions for this issue are described in Section 5.1. 3.4.8 Other Laboratory QAlQC Section 9.2 of the QAP requires that the laboratory's QAlQC Manager check the following items in developing data reports: (1) sample preparation information is correct and complete, (2) analysis information is correct and complete, (3) appropriate Analytical Laboratory procedures are followed, (4) analytical results are correct and complete, (5) QC samples are within established control limits, (6) blanks are within QC limits, (7) special sample preparation and analytical requirements have been met, and (8) documentation is complete. In addition to other laboratory checks described above, DUSA's QA Manager rechecks QC samples and blanks (items (5) and (6)) to confirm that the percent recovery for spikes and the relative percent difference for spike duplicates are within the method-specific required limits, or that the case narrative sufficiently explains any deviation from these limits. Results of this quantitative check are provided in Tab H. All lab QAlQC results met these specified acceptance limits except as noted below. The QAP Section 8.1.2 requires that an MS/MSD (referred to as Duplicate Spike [Matrix spike] in the QAP) pair be analyzed with each analytical batch. The QAP does not specify acceptance limits for the MS/MSD pair, and the QAP does not specify that the MS/MSD pair be prepared on DUSA samples only. Acceptance limits for MS/MSDs are set by the laboratories. The review of the information provided by the laboratories in the data packages verified that the QAP requirement to analyze an MS/MSD pair with each analytical batch was met. While the QAP does not require it, the recoveries were reviewed for compliance with the laboratory established acceptance limits. The QAP does not require this level of review, and the results of this review are provided for information only. The information from the Laboratory QAlQC Summary Reports indicates that the MS/MSDs recoveries and the associated RPDs for all quarterly nitrate samples are within acceptable laboratory limits for all regulated compounds as indicated in Tab H. The QAP requirement to analyze a MS/MSD pair with each analytical batch was met and as such the data are compliant with the QAP. The information from the Laboratory QAlQC Summary Reports indicates that the LCS recoveries were acceptable which indicate that the analytical system was operating properly. 12 N:\Required Reports\Nitrate Qualterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Report texLdocx The QAP Section 8.1.2 requires that each analytical batch shall be accompanied by a reagent blank. All analytical batches routinely contain a blank, which is a blank sample made and carried through all analytical steps. For the Mill samples, a method blank is prepared for all analytical methods. The information from the Laboratory QAlQC Summary Reports indicates that the method blanks did not contain detections of any target analytes above the RL. 4.0 INTERPRETATION OF DATA 4.1 Interpretation of Groundwater Levels, Gradients and Flow Directions. 4.1.1 Current Site Groundwater Contour Map As stated above, a listing of groundwater level readings for the current quarter (shown as depth to groundwater in feet) is included under Tab C. The data from this tab has been interpreted (kriged) and plotted in a water table contour map, provided under the same tab. The contour map is based on the December 21, 2011 data for all wells. 4.1.2 Comparison of Current Groundwater Contour Map to Groundwater Contour Map for Previous Quarter The groundwater contour maps for the Mill site for the previous quarter, as submitted with the Nitrate Monitoring Report for the previous quarter, are attached under Tab D. A comparison of the water table contour maps for the current (fourth) quarter of 2011 to the water table contour maps for the previous quarter (third quarter of 2011) indicates similar patterns of draw down related to pumping of MW-4, MW-26, TW4-4, TW4-19 and TW4-20. The water level contour map for the current quarter covers a larger area than the map for the previous quarter and incorporates water level elevations from new DR-series piezometers and the elevations of seeps and springs connected to the perched water system. Otherwise, water levels and water level contours for the site have not changed significantly since the last quarter, except for a few locations. Pumping at TW4- 4, which began in the first quarter of 2010, has depressed the water table near TW4-4, but a well-defined cone of depression is not yet evident, likely due to variable permeability conditions near TW4-4 and the low water level at adjacent well TW4-14. Reported decreases in water levels of approximately 7 feet occurred in recently installed well MW-37 and of approximately 3 feet occurred in well MW-23. Reported increases in water level of approximately 10 feet occurred in pumping well TW4-20 and of approximately 3 feet occurred in well TWN-9. The water level changes at pumping wells MW-4, MW-26, and TW4-19 were less than 5 feet. Water level fluctuations at pumping wells MW-4, MW-26, TW4-4, TW4-19, and TW4- 20 are due in part to fluctuations in pumping conditions just prior to and at the time the measurements are taken. The largest decrease (increase in drawdown) of approximately 2 feet occurred in well MW-26 and the largest increase (decrease in drawdown), of approximately 10 feet, occurred in well TW4-20. The reported water level at well MW- 13 N:\Required Reports\Nitrate Quarterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Report text.docx 37 during the current quarter is similar to the reported second quarter water level which suggests that the third quarter water level may have been in error. 4.1.3 Hydrographs Attached under Tab E are hydro graphs showing groundwater elevation in each nitrate contaminant investigation monitor well over time. 4.1.4 Depth to Groundwater Measured and Groundwater Elevation Attached in Tab F are tables showing depth to groundwater measured and groundwater elevation over time for each of the wells listed in Section 2.1.1 above. 4.2 Review of Analytical Results 4.2.1 Current Nitrate and Chloride Isoconcentration Maps Included under Tab I of this Report are current nitrate and chloride iso-concentration maps for the Mill site. Nitrate iso-contours start at 5 mg/L and chloride iso-contours start at 100 mg/L because those values appear to separate the plumes from background. All nitrate and chloride data used to develop these iso-concentration maps are from the current quarter's sampling events. 4.2.2 Nitrate and Chloride Concentration Trend Data and Graphs Attached under Tab J is a table summarizing values for nitrate and chloride for each well over time. Some data (MW -18, MW -19 and the Frog Pond) were not sampled this period but the historical data are included for information purposes. Attached under Tab K are graphs showing nitrate and chloride concentration trends in each monitor well over time. 4.2.3 Interpretation of Analytical Data Generally, the shapes of the nitrate and chloride plumes appear to be stable and unchanged for the last eight quarters. The nitrate and chloride plumes maintain their general geographic association and it is still possible to separate the plumes into a segment northeast of the wildlife ponds and a southwest segment near the mill site. Nitrate and chloride concentrations in samples from the downgradient edge of the plumes (in the vicinity of tailings impoundment monitoring wells MW-30 and MW-31) have remained essentially unchanged (current concentration within one standard deviation of the average of the previous seven quarters and within laboratory variation) and the plume does not appear to be migrating in the downgradient direction. In general, both nitrate and chloride concentrations in nitrate monitoring wells are similar to values from last quarter or have declined (Tables 2 and 3). Notable exceptions include nitrate concentrations in TWN-7 which rose from 0.7 mg/L to 2.2 mg/L, nitrate concentrations in TWN-10 which rose from 0.1 mg/L to 0.2 mg/L, 14 N:\Required Reports\Nitrate Quarterly Monitoring RepOlt\2011 Q4\2011 Q4 Nitrate Report text.docx nitrate concentrations in TWN-11 which rose from 0.1 mg/L to 1.6 mg/L, and nitrate concentrations in TWN-12 which rose from 0.6 mg/L to 1.2 mg/L (Tables 2 and 3). Note that while there was an increase in nitrate concentrations in each of these wells from last quarter, in each case, current concentrations are consistent with data from older sampling events (Table 2). The current quarter's data continue to support the conclusion in the Nitrate Contamination Investigation Report that the nitrate and chloride are co-extensive and appear to originally come from the same source. 5.0 CORRECTIVE ACTION REPORT Necessary corrective actions identified during the current monitoring period are described below. 5.1 Rinsate Blank Sample Chloride Levels Identification and Definition of the Problem Rinsate and DIFB Chloride Levels Chloride is present in the rinsate blanks and in the DIFB for this quarter. To address previous nitrate contamination in the nitrate and chloroform sampling programs, an additional rinse with 55-gallons of DI water has previously been added to the decontamination process. DUSA believes that the source for the chloride present in the rinsate blanks this quarter appears to be related to the increasing volume of DI water used in the rinsate process due to the second 55-gallon rinse of the portable pump with DI water. The chloride present in the rinsate blanks is present in the DI water and is not the result of inadequate decontamination of the purging pump. The chloride contamination in the DI water is most likely the result of chlorination of the intake water (from the potable water supply source) used for the DI system. At high volume use rates, the DI system appears to be unable to remove all of the chloride introduced with the DI intake (supply) water. Assignment of Responsibility for Investigation of the Problem The problem is currently under investigation by the QA Manager. Investigation and Determination of Cause of the Problem Rinsate and DIFB Chloride Levels As discussed above, chloride is entering the rinsate blanks from the chlorination of the potable water supply used as a feed to the DI system. The DI system is showing signs of breakthrough at times of high usage. To address the issue, the QA manager is working with mill staff evaluating the best approach to implement upgrades to the DI system to ensure its ability to support the high volume of DI water needed for the rinsate process. 15 N:\Required Reports\Nitrate Quarterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Report text.docx Determination of a Corrective Action to Eliminate the Problem Rinsate and DIFB Chloride Levels The chloride contamination in the DI water is most likely the result of chlorination of the intake water used for the DI system. Based on low level detections this quarter, the additional of a second DI rinse in the process is "stressing" the system and causing chloride contamination. By upgrading the system, it will be able to support the high volume of DI water being pumped through the system. Assigning and Accepting Responsibility for Implementing the Corrective Action Rinsate and DIFB Chloride Levels It will be the joint responsibility of the Director, Compliance and Permitting, and the Mill's sampling staff to implement the changes and to assess the data to determine if it has corrected the problems. Implementing the Corrective Action and Evaluating Effectiveness Rinsate and DIFB Chloride Levels It is expected that chloride sources will be eliminated from the DIFBs after the DI system is upgraded to support the high volume of DI water in the system during the rinsate process. Analysis of the DI system by DUSA is underway to determine the best design for the system upgrades. Data collected after the completion of the system upgrades will determine if any further action is necessary to eliminate rinsate contamination. Verifying That the Corrective Action Has Eliminated the Problem Verification that chloride contamination has been eliminated will occur upon completion of the system upgrades and receipt of at least the two quarters of data. If chloride contamination persists then additional sources will be researched and the investigation will continue. 5.2 Assessment of Previous Quarter's Corrective Actions There were no corrective actions resulting from third quarter 2011 nitrate sampling event. 16 N:\Required Reports\Nitrate Qualterly Monitoring Report\20 II Q4\2011 Q4 Nitrate Report text.docx 6.0 CONCLUSIONS AND RECOMMENDATIONS Generally, the shapes of the nitrate and chloride plumes appear to be stable and unchanged for the last eight quarters. The nitrate and chloride plumes maintain their general geographic association and it is still possible to separate the plumes into a segment northeast of the wildlife ponds and a southwest segment near the mill site. Nitrate and chloride concentrations in samples from the downgradient edge of the plumes (in the vicinity of tailings impoundment monitoring wells MW-30 and MW-31) have remained essentially unchanged (current concentration within one standard deviation of the average of the previous seven quarters and within laboratory variation) and the plume does not appear to be migrating in the down gradient direction. In general, both nitrate and chloride concentrations in nitrate monitoring wells are similar to values from last quarter or have declined (Tables 2 and 3). The current quarter's data continue to support the conclusion in the Nitrate Contamination Investigation Report that the nitrate and chloride are co-extensive and appear to originally come from the same source. 7.0 ELECTRONIC DATA FILES AND FORMAT DUSA has provided to the Co-Executive Secretary an electronic copy of all laboratory results for groundwater quality monitoring conducted under the nitrate contaminant investigation during the Quarter, in Comma Separated Values ("CSV") format. A copy of the transmittal e-mail is included under Tab L. 17 N:\Required Reports\Nitrate Quarterly Monitoring Repolt\20ll Q4\201l Q4 Nitrate Report texLdocx 8.0 SIGNATURE AND CERTIFICATION This document was prepared by Denison Mines (USA) Corp. on February 16,2012. DENISON MINES (USA) CORP. By: Da¥ C. Fry' enlund Vice President, Regulatory Affairs and Counsel 18 N :\Required Reports\Nitrate Quarterly Monitoring Report\20 II Q4\20 11 Q4 Nitrate Report text.docx Certification: I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and ent r knowing violations. Da . F ydenlund Vice Presi nt, Regulatory Affairs and Counsel Denison Mines (USA) Corp. 19 N:\Required Reports\Nitrate Quarterly Monitoring Report\2011 Q4\2011 Q4 Nitrate Report text.docx Tables Table 1 Summary of Well Sampling and Constituents for the Period '~~ ,-,,;~ ":",;ft-., ~ ~~;~r ,<f~fI'\:~"':':I~,::'{t:f~~ ,!,~;,'~W~lt ' :'~,;ri,;' {, ., _ " " , , ; ':t , ',~ . ,q' .l~\;~!;i~(* f:~;~ptR'~~~(Jlle~~i~~D . g~~~,.~f~1t~~ ~~pQ,rt;~~ Piezometer 1 10119/2011 111912011 Piezometer 2 10119/2011 111912011 Piezometer 3 10119/2011 1119/2011 TWN-1 10/17/2011 1119/2011 TWN-2 10120/2011 1119/2011 TWN-3 10/20/2011 1119/2011 TWN-4 10118/2011 111912011 TWN-5 10117/2011 111912011 TWN-6 10/18/2011 1119/2011 TWN-7 10/19/2011 1119/2011 TWN-7R 10118/2011 111912011 TWN-8 10117/2011 111912011 TWN-8R 10117/2011 111912011 TWN-9 10/20/2011 1119/2011 TWN-10 10/18/2011 1119/2011 TWN-11 10/17/2011 1119/2011 TWN-12 10/17/2011 1119/2011 TWN-13 10117/2011 111912011 TWN-14 10119/2011 111912011 TWN-15 10/19/2011 1119/2011 TWN-16 10/18/2011 1119/2011 TWN-17 10/20/2011 1119/2011 TWN-17R 10/19/2011 1119/2011 TWN-18 10118/2011 111912011 TWN-19 10118/2011 111912011 TWN-65 10/18/2011 1119/2011 TWN-60 10/19/2011 1119/2011 TWN-70 10/20/2011 1119/2011 UWLP 10119/2011 111912011 Note: All wells were sampled for Nitrate and Chloride TWN-60 is a DI Field Blank TWN-65 is a duplicate of TWN-4, and TWN-70 is a duplicate ofTWN-17. UWLP is a sample from the Upper Wildlife Pond ':~ocatiiljf:;1 ;1 ,;e .,.,;"" Il: " w ' .: '~'!.i'L' ''; ( 7': ~ -_ I~ . ~~~~,Q'~ . ~ . lsfQ 2ndJl " SrdQ ' , 20Ttl;;f ._--,I' -'~~ ~ ~ - .. ,', ... , ',,, .. ~' :,~ ... 2009,f~ '2010~~"i 2019 ! ' ,,~,! .. ,: ",', "co."'" _,:,!iil.!! ; -Y;~\l.' Piez 1 NA NA 7.2 6.8 Piez 2 NA NA 0.6 0.6 Piez 3 NA 1.7 1.6 1.8 TWN1 0.5 0.5 0.6 0.6 TWN2 20.8 62.1 69 69 TWN3 29 25.3 26 27 TWN4 004 0.9 1 0.9 TWN5 0.2 0.3 0.3 0.3 TWN6 104 1.5 104 104 TWN7 0.1 0.8 1.2 1.6 TWN8 0.1 <0.1 <0.1 <0.1 TWN9 12 7.6 7.7 10.7 TWN10 104 1.5 1 0.2 TWN 11 1.3 104 1.3 104 TWN12 0.5 0.7 0.8 0.7 TWN 13 0.5 0.1 0.1 0.2 TWN14 304 2.9 2.9 3.5 TWN 15 1.1 0.7 1 1 TWN16 1 1.2 1.3 2.6 TWN 17 6.7 lOA 11 8.9 TWN 18 1.3 1.6 1.8 1.8 TWN19 704 7.2 6.2 7.2 .•..... Red value indicates nondetect Table 2 Nitrate (mg/L) ,'~ ';t i;¥;;' ',,1'~", ,C~ ~ "4th Q ,; " 11'1\ Q , .;st" ,. 11>2010 ' , ' ~lOlt ' '" "";~ "" ,.;leo '.1":) ,i" 'I:. '",' 6.5 7 0.2 0.3 1.8 1.8 0.6 0.5 48 43 24 24 1.0 0.9 0.3 004 1.2 1.1 1.0 1.3 <0.1 <0.1 8 9.5 1.3 0.3 104 104 0.7 4.2 004 1.6 4.2 3.7 1.2 104 2 4.6 8 8.6 1.6 104 7 7 I~Z!' c;~: .'" 2ndQ I 'lO~lf ; I "$, " ""':"' " 6.8 0.3 1.7 0.5 40 26 0.9 0.3 1.5 1.7 <0.1 10 1.2 104 1 <0.1 3.5 1.6 1.6 9 1.8 6.9 ," ''I;''':",,~, :~",;j1 *"'~:"" <~!!" ~9:~ -;.;~ '~~V-':q§: 'S~ '~7'?';IN~~iti; " %iDlfferenc¢' 3td::: ·3'r(lQ .. ,: rf . iii; '._ !l]\. '.' '~", v: <M!,,,,o~~ . ',,":2011 · !.,~' ;4th,Q'20ll . Q, 201J':~ndAth~~Q~ il.'~'" 0 .*,' '~~,'; :'~~iQ~~~:. ' ~,~~i, , :;:F ~ .. ' '. '. _, ": ~,., ",."~,,.~;; 7 6.6 -6 0.1 0.1 0 1.8 1.7 -6 0.5 0.5 0 33 33 0 25 25 0 1.1 0.9 -22 0.3 0.3 0 1.1 104 21 0.7 2.2 68 <0.1 <0.1 0 11 10.9 -1 0.1 0.2 50 0.1 1.6 94 0.6 1.2 50 <0.1 <0.1 0 3.5 3.9 10 1.6 1.3 -23 204 2.6 8 8.5 8.1 -5 1.8 1.9 5 7.1 6.5 -9 ,'" ,~, ,~!:" "¢I I', Ir~;: "~~~, "" ,'*;~ "L ' --, "'" '¥~'~, "',il "'<;: ',~ '" " 1",4 ' '" ~~'~;j ~Cf.,' , " '~, I~ " ":: ~i " ,. 'A : 4flli'Q~': .,,~·ftd Q ' ' ,:{~,rd :Q"-"~~'L6cation ~:; "~;~~ ..... ~t , 20tG,~"i1'j) j "', ";~"20,jO : '. 2.0.10 '" ~~, '., "'Ii/rP, 'llo ",:," s:,l ----. ~ ;.~. ,',~' ",:~ .~ . ~; '. "" '3 '", ~III: ' .. "," ~<:; Piez 1 NA NA 52 52 Piez 2 NA NA 8 8 Piez 3 NA 116 36 35 TWN1 18 17 20 19 TWN2 55 85 97 104 TWN3 106 111 118 106 TWN4 11 22 22 19 TWN5 48 43 44 43 TWN6 21 19 22 73 TWN7 7 6 6 7 TWN8 12 11 11 11 TWN9 205 183 175 210 TWN10 26 54 30 21 TWN 11 74 73 72 76 TWN12 109 113 106 112 TWN 13 83 47 49 53 TWN14 32 24 30 26 TWN 15 78 43 39 36 TWN16 39 35 35 35 TWN17 152 78 87 66 TWN 18 57 42 63 64 TWN19 125 118 113 113 Table 3 Chloride (mg/L) g,"'''', ", <'t{ " I~~' '.' , ~~;, ;;c I:,'·'· 4thQ, :' :''" Q'" ' " IItY 2011 ' 11,,201.0 ' -. -. -, , . ii' i,. SI 60 60 6 9 25 40 14 17 93 93 117 138 21 21 45 47 21 18 4 6 9 13 172 217 28 40 72 84 103 87 57 103 28 24 38 43 30 34 65 90 59 61 107 114 r,' '''''"'''iltl' I'J'! '2 "d~Q' "'''-n '" Ii, 2()i'1~~"~' I ~ 1~ III .~'(' 58 8 35 19 85 128 21 44 22 6 10 192 28 76 109 49 30 49 39 81 67 120 !;";;';"'~ '!it':'. .", I~:i:;:~~~: ~~ ,'~~::",.': 9:'::,:~~i~~; i:I;:'!l'~. ' .. " ,~, :' % Dlfferenee."t ~,·,a;l:Q A' ~ ~ " ,~~-, ~';;s ~~~~,~ , '. :4thT'(J 2011 ~'3rd"Q~2.o11~.a:ftd'" 2.olf .' , _ ~~:;1 ~ ~,; . ,"" : ': . , .i!&,' ~' ~--:, ~"):~~ .ii~ , 4th,Q;2()11'~~~ ~ ':I .. . -~ ~ ~ ~ ~ ~-::~ ~~:~4,;_, I'~: :s " ,,,," "", ~ ~ :c 53 55 4 9 8 -13 61 12 -4.08 14 10 -4.0 74 76 3 134 129 -4 35 20 -75 44 45 2 17 21 19 5 6 17 18 10 -8.0 208 134 -55 28 33 15 76 76 .0 102 87 -17 49 48 -2 25 27 7 47 38 -24 31 34 9 74 71 -4 65 60 -8 113 108 -5 INDEX OF TABS Tab A Site Plan and Perched Well Locations White Mesa Site Tab B Order of Sampling and Field Data Worksheets Tab C Kriged Current Quarter Groundwater Contour Map and Depth to Water Data Tab D Kriged Previous Quarter Groundwater Contour Map Tab E Hydrographs of Groundwater Elevations Over Time for Nitrate Monitoring Wells Tab F Depths to Groundwater and Elevations Over Time for Nitrate Monitoring Wells Tab G Laboratory Analytical Reports Tab H Quality Assurance and Data Validation Tables H-l Field Data QAlQC Evaluation H-2 Holding Time Evaluation H-3 Receipt Temperature Check H -4 Analytical Method Check H-5 Reporting Limit Evaluation H-6 QAlQC Evaluation for Sample Duplicates H -7 Rinsate Check H -8 QC Control Limits for Analyses and Blanks Tab I Kriged Current Quarter Isoconcentration Maps Tab J Analyte Concentration Data Over Time Tab K Concentration Trend Graphs Tab L CSV Transmittal Letter Tab A Site Plan and Perched Well Locations White Mesa Site I\JlW-5 @ perched monitoring well TW4-12 o temporary perched monitoring well TWN-10 ~ temporary perched nitrate monitoring well PIEZ-1 e TW4-27 3::t perched piezometer temporary perched monitoring well installed October, 2011 RUIN SPRING o seep or spring HYDRO GEO CHEM, INC. APPROVED WH~T!E MESA S~TE PLAN SHOW~NG lOCAT~ONS Of [PERCHED WEllS AND [P~EZOM!El!ERS DATE REFERENCE H :/718000/feb 12/UTMwe lIoc.srf FIGURE A-1 TabB Order of Sampling and Field Data Worksheets 1 '., w ~) ~ J ~,) "J \j ".} Nitrate Mg/l Nitrate Order 4th Quarter 2011 Nitrate Samples Name Previous Qrt. Date/Purge sample Depth Total Depth TWN-8 TWN-13 TWN-lO TWN-11 TWN-5 TWN-l TWN-12 TWN-7 TWN-4 TWN-6 TWN-15 TWN-18 TWN-16 TWN-14 TWN-19 TWN-17 TWN-9 TWN-3 TWN-2 Piez 1 Piez 2 0.1 0.1 0.1 0.1 0.3 0.5 0.6 0.7 1.1 1.1 1.6 1.8 2.4 3.5 7.1 8.5 11.0 25.0 33.0 7 0.1 Piez 3 1.8 wildlife NO '\"WN '10 ta/l'1l.1 0 (>ft6"\ 145.5 r1 0 oct il". 120 iO!l~1l1 0 o {;:tRD 105 11 0 \~"4J 142 \1 0 1''\~c 150 1'1 0 \i-l :?5 112.5 \1 0 \S\:2 110 \O/let;..\\ 0 DbSb 105 [D/I~/i\ 0 o 150_i) 125.7 \()/I ~1 \,1 0 D3S:l 130 ,\o/i(,\/ll 0 bb.;i..~ 155 iDJI~lil o i\D~ 145 iO!I$Sv /I 0 ~Q.33 100 \O/\q/i! 0 O('3b 135 \oi}~:ill 0 1 Ll,)g: 110 \01 jl.O/H 0 o1Q5 110 lO/:f1.0/!.1 0 D0b~ 97 \O/Jl.D/l \ 0 o t L-\D 96 \0/j)..0/1I 0 Ob3 D 96 'Ib/i~/ll l~15 [0/ i4/il t:z..t..\S lO/IQ/1I 0 \')..~O 101J<,j/1I 13DO 6'S io/'31l\ otu,S (,0 \0/111/1 1 \ "Sd-S ~. \ o/J..O/ll 01 oS Rinsate Samples Name Date Sample TWN-8R ItJlrUn t>.,SO TWN-13R TWN-l0R TWN-11R TWN-5R . TWN-1R TWN-12R TWN-7R lc/~/ll OiOO TWN-4R TWN-6R TWN-15R TWN-18R TWN-16R TWN-14R TWN-19R TWN-17R ,\oJi~/ ;I 0'1 11 TWN-9R TWN-3R TWN-2R Samplers: 'Mill -Groundwater Discharge Permit ('""") Groundwater Monitoring Quality Assurance Plan iOAP)j Date: 03/22/2010 Rev. 6 Attachment 1 , ~ I ATTACHi\'1ENT 1 DENISO..-~ j \VHITE l\IESA URANIUM l\HLL l ~.~. ~ .. til See instruct ion ··t~:. .MINE~~~......,..J FIELD DATA \VORKSHEET FOR GROUI'lD \VATER Description of Sampling Event: 1'1 Th C~c\'("+-G(" N ~~rQ.+< ,2.0' t Location (well name ):1_.' -...:.!...:;·vV~JJ_-..a.i _--.;., ______ ---11 Sampler Name and initials: I ~ni)c!'(, »~n ;JA") 1111- Date and Ti me for Purgin~I_.\.:..;..O"'-I"-! .. ,~/..;;;.~~1 , ____ --1 WelJ Purging Equip Used:~pump o@ bailer pH Buffer 7.0 ..... 1 _,.:.-,_0 _______ -1. I Specific Conductnncc 1.-.1 ....:,'t..;.,q 1-,--~_---,1 J!Ml-IOS/ em Depth to Water Before PurginL§i5-:9 ~' 'J Conductance (avg) WeIlWaterTemp.(avg) j '\~:6\' Gal. .Purged r: _ ~ .. {c> .,n,' . Conductance I 80" -6 . :'1 pH 17:U;.···:· Temp.oC Redox Potential Eh (mV) L):'~7~.:f>-<1 Turbidity (NTU) .1 Time Ij~' Gal. Purged _I _i1;....o ____ ...... J Conductance I .~O(>.O pH 1,. ~4 .. I Temp.oC Redox Potential Eh (mV) I ~., q Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater and Sampling (ifdifferent) I~A!;..:...JA~ _____ -" \Vell Pump (if other than Bennet) l6-r",nJ::(O;S . Prevo Well Sampled in Sampling Event I J... -r_W_.N_·:_-_5 __ ...;.-._---' pH Buffer 4.0 Wen Dcpth(O.O I ft)~ I Hc'l. _50 Casing Volume (V) 4" well:~ .. 1 <'. (.653h) 31t Well:~(.367h) pH of Water (avg) I Turbidityt..2..5 . ~ '. '1 Ext'l Amb. Temp. "C (prior sampling event}1 1'14"· " ·~'I Time 1 1Y~1 .: .···1 GaL Purged c...;.!-":i';::..o_---...;..----'·I Conductance "".g03: ~ ::'. I pH 17;/'1 .' Temp.oC Redox Potential Eh (mV) [:~1f,.· =1 Turbidity (NTU) I.::tt~~l ·, I Time 11l.J::t3 , Gal. Purged .... 1 ..... H_·>O_~. __ J Conductance [~OI.O " pH L.-[ 7.&..: ...... /Y'---_-' Temp.oC I i"1·q~ I Redox Potential Eh (mV) 1L..:I¢~7.:..lg"'---_-JI Turbidity (NTU) l ~b.1 A 10f2 capturx" COMPATIBLE WJTH~",.,,::.n:.--FUNCTlONHITV Mill· Groundwater Discharge Permit 0 Groundwater Monitoring Quality Assurance Plan (OAP) Date: 03/22/Z010 Rev.£> ... .;: ~ VoJume ofWaLer Purged I __ .... (...;;::O=D~ __ _ gallon(s) Pumping Rate Calculation Flow RaLe (Q), in gpm. S/60 = L-I ~, 0:...-_---' Time to evacuate two casing volumes (2V) T=2V/Q= I '8.0:> I Number of casing volumes evacuated (if other than two) , I If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy LabfuN;.:..'" lu'A..:...· ;,....,.,. _: '..;..'. _' ....;...~~~--I Type of Sample S 1 T k Sample Vol (indicate amp e a en , f h 1 1 ot er t Ian as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Filtered y N Preservative Type Preservative Added Y N If preservative is used, specifY Type and Quantity of Preservative: ?-Comment bd1. See instruction . A;.,;" eA. 0(\ .s 't e "" 1'110, I"'~h~r M~ {;.. Q.H ; 1\ pfe.Sc:M-~~c P 1>.(~c:,',;v,tA SlIMp)i.1j e" e ~ 1-. . P ~~c.. b5M 0..1' It.! l~.f W"~~.I. """"-fur .... +cJ~l ;,.r,o 1"1 il\v.+e5. .. ~hr . u)Go.s","I;fj.I( J. '~colo t"~J.1 bv..+ 1"\0 ~~~ CIe!;.!'. P ~r~~ en~~a MIA .s~.., p le.l.<. .. w·" .:." II .. .::.J-",t! a 1-1'-/.:(3, DCl'lh +b t.:>c..+,,. tA..~C( rv.t".jt: \.J)a~ ·13.03r Le.fl-'$/+('. A.-+' P-l~~.' '--_______ ---IIDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Mill· Groundwater Discharge Permit ~) Groundwater Monitoring Quality Assurance ptan (QAP) , ~. Date; 03/22/2010 Rev. G ATTACHMENT I IOEN,soH'l · '1 WHITE l\'fESA URANIUl\'1 MILL Attachment I .~ ..... ~~!! .. .-.-~j FIELD DATA \VORKSHEET FOR GROUND 'VATER Description of Sampling Event: I l.\Th Q\AQ.,cfec N ,'t""OI.t <: .:lO U Location (well name):I-1 'T..:...:.;w;.;..N_-~~ ________ ~ Sampler Name and initials: l4Anner Ue>Ji,Jcv-jA1t Date and Time for Purging W/19 Ia..oi I and Sampling (if different) I jO/.2.DI:ZOI/ Wen Purging Equip Used:!IDpump or@] bailer Well Pump (if other than Bennet) I G-rtAt1dPo S Prevo WelJ Sampled in Sampling Event L..1_-r_W_,_N_...,._3 ____ ---l pH Buffer 7.0 "7 :0 pH Buffer 4.0 , '4 .D ,' Specific Conductancet-I ... q ...... g1-4--__ --..II~MHOSI em Well Dcpth(O.Olft): I th.DC> I I Depth to Water Before Purgin~ \~ .'1S Casing Volume (V) Conductance (avg) I .... , ..... ', :.t-:.,...{......;4 .=5_· _____ ---'I pH of Water (avg) b -b7 ,' Well Water Temp. (avg) [.~l ~ Ei:: -I Redox Potential (Eh)1 jSi : . ' Turbidity I :!4 ~b ' Weather Condo ~ . ," ~v..i-tv\.f'" . ".' Ext" Amb. Temp. °C (prior sampling event}1 1'5<0 -I .. , Gal. Purged L.;..1'·'=5=-· _'-___ I Time ,-1_' _-.-;.___i Gal. Purged &...1 _-",;",~''-I' I Conductance I :;tb=P; Conductance 1--"_ ,", ,..0.;;' ",_. _-,·1 pH L..I _~_...." Temp. "C Temp.oC Redox Potential Eh (mV) 1-1 ....c;3..;:.,c5~1 _---" Redox Potentia1 Eh (m V) L..I ___ --I Turbidity (NTU) '1 Turbidity (NTU) I '. . I Time Gal. Purged &...1 ___ ..... Time Gal. Purged L..I --.;.~_...." Conductance pHL-I ___ ..... Conductance pH"-I ___ ..... Temp.oC Temp.oC Redox Potential Eh (m V)I I-___ --' Redox Potential Eh (mV) 1-1 ___ -oJ Turbidity (NTU) Turbidity (NTU) White Mesa Mm Field Data Worksheet for Groundwater A lof2 ,capturx (OMPATIBLI; WITIi/"-WS,.,:ri;--FU'"'CTlON .. lITY Mill . Groundwater Discharge Permit (~) Groundwater Monitoring Quality Assurance Plan (QAP) '. ",' Volume of Water Purged .... 1_0 __ ""'-__ Pumping Rate Calculation Date: 03/22/2010 Rev. 6 gallon(s) Flow Rate (Q), in gpm. S/60 = I io Time to evacuate two casing volumes (2V) T = 2V IQ = tJQu: Q~. ~=n"._n .] Number of casing volumes evacuated (if other than two) t.--D _· ____ I }.33 Ifwell evacuated to dryness, number of gallons evacuated o Name of Certified Analytical Laboratory if Other Than Energy Lab~'-,L;.d...:.../.:..:..A_.:.--___ ..:...---, Type of Sample VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) ~ ~Comment Sample Vol (indicate Preservative Sample Taken Filtered Preservative Added if other than as Type Y N specified below) Y N Y N If preservative is used, specify Type and Quantity of Preservative: 1 7' . , I See instruction , ~ . . J\((\~(d ()I'\ 5i+c cj, \~Db ~(\ncr, &j).(~"~ .€J.AA. ,rjo..~ <A.H p.r~.se(\t +b r~("~<.TWtJ~~··?\.A.("e(: be.~~ , .u\,r!c>\O , P\A.r~.ea weH fc;r A.; +c)t~l .o{: '". M;(\~(.s ~f1c{ yo S~~C:f1ds , Pu.r.sed wdl J(jl. \.i)'lfa , W().~ Mo~tI~ ~IC(A~., F\.\rnc enJeJ ~+ "C>17", L"~ ?;+c ~t Il);to . . .', Ar~vej Ol-\ S~+~ ~+ b~3, -r.:\·~l'e(' t\l"rl ' &c:-rft(l' p.e.se'l't-~o c..cll~c.+ So.fVlp1e..s , Depth +0 W(Ater- w~ 19·1t.1. S"'rr1f)e~ VJ~r~ Gollec..+u\ h.j bo.'\~t' ~ Ob'3C. L-'~.ft ~itc "J-O~3~. t....-_______ ---'IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater A 2of2 capturx' C0I4PAT111L(; W ITH.,./1'.,,~ ... ·l'lr-rO~CTlON"'I 'rY. ~II. Groundwater Discharge Permit () Groundwater Monitormg Quality Assurance Plan (QAP) \,-. ~ Date: 03/22/2010 Rev. 6 I A TT ACHMENT I Attachment I ~"~~ St:c instruction \VHITE l\fESA URANIUM MILL FIELD DATA \VORKSHEET FOR GROUND 'VATER liT", 'c~;%r'+'( I\J :+r~+~ :;to I,t I Location (wel1 name):I ..... ;:;J~· ~N~~3;;;;;.....· ____ ;.,,-...-'"-__ ---' Sampler Name ... _ ... _. _ _ _._ . ___ and initials: [~n~~', »~j ,/J;/Pt " " ~' =J Date and Time for Purgin~ \O/\Q/:;t.OH : and Sampling (if different) Well Purging Equip Used: !'Eil .. , I pump o@ bailer Well Pump (if other than Bennet) I ,~ .~." .::, &ru..."clf~ Sampling Event Q v-"r\-c.t)j J\): \ ('" \,;: Prev. Well Sampled in Sampling Event I· :;~ ~ ~ "I pH Buffer 7.0 pH Buffer 4.0 Specific Conductance I "'Cf4 /,:".':' \,IJ.tMHOS/cm Well Depth(O.Olft): I,; 9(,:00 ':'; ",:,.,.,., Depth to Water Before Purgin~~2.. 15' :"1 Casing Volume (V) 4" well:l: Lji:'b3!L: I{ .65 3 h) 3" W II -', .. ' .'" ,;~':<, . ~ (367h) e .... 0 ., ,' .. Redox Potential (Eh)f;': 345 ~:-···I Temp_ °C Redox Potential Eh (mV) I -'3%,:',;.'/.,;1 ~ Turbidity (NTU) Time Gal. Purged ..... 1; ....... , ................... ', .... ' '...I' I Conductance '1....1 _____ .. _. '.',_1 pH ..... 1' _. ___ ' _., -,'J Temp.oC I . '. ',I Redox Potential Eh (mV) .... 1 ___ --' Turbidity (NTU) Ext'l Amb. Temp. °C (prior sampling event)1 ';l:a:~,==J G I P d 1"""''':'''"''''''':''':''1 a _ urge ,\, ,i:; ';", ,.,:: ':); Conductance I ~; .. : ,:' .:'.": "', ';;,:~,: I Temp.oC Redox Potential Eh (mV) 1->: -:" . ':~' :1 Turbidity (NTU) Time .... 1.'_,. _______ _ Gal. Purged" '-. _ __.. .......... '_ .. 1 Conductance .... l ·_ .. ____ ---. .. ...I' I pHi-I ___ · ..... ·, Temp.oC .... 1 ___ -" Redox Potential Eh (m V) 1-1 ___ --" Turbidity (NTU) White Mesa Mili Field Data Worksheet for Groundwater MiII-Groundwater Discharge Permit r~ Groundwater Monitoring Quality Assurance Plan (QAP) ". " Volume of Water Purged 1""-,..-..o_D ___ _ Pumping Rate Calculation gallon(s} Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60= I 10 T = 2V/Q:: I ~.3:2 I Number of casing volumes evacuated (if other than two) Il.lq . Ifwell evacuated to dryness, number of gallons evacuated ·1 Name of Certified Analytical Laboratory if Other TIlan Energy Labf&,;..,' .. ·'_~..;...;I A;...;..' ' ____ ~~..;.t:1 Type of Sample VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Sample Vol (indicate Sample Taken if other than as Filtered Y N specified below) Y N Preservative Type Date: 03/22/2010 Rev. 6 Preservative Added Y N If preservative is used. specity Type and Quantity of Preservative: ~ ~ See instruction i~Conunent ~z~:t~:lt~r1·$c~·.,~~i.;!~t:;r~~~~~e1:1~i~~a1Ji:~·,'.:\,~f~;t~,~{ .. ~,~.· f \A~~t:, .,.e~.~il ~~ oq l1,., Laft S I~ ~1-O<1~l .....,» .;. ' .• ' "" ~ ,','" :. ' " Ar(,viJ ~~ ,~1·+e. tX~,9b3~'·-r~I\I\,er~na .6-(}.rn'I'\' e:.;~.s~~f'::+t)~o,lf~C+.~0IY1r.jc.s ;;~(:F-H" +0 ' ~~T~y' .\N(}..~ ~.SO "?·~~f'(~b(J.31~tt"",+:o.bl\O . '1-e,~ :~1'+~ iA·t-.O~Y3 ... ' . a....-_______ ---.lIDo not touch this cell (SheetName) White Mesa Mil! Field Data Worksheet for Groundwater A 2 of2 capturx· COMPATIBLE WITH;""'-UI~'W-FUNCTlON;'l1lY Mi~ • Groundwater Discharge Permit () Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) 3 " ATTACHMENT J J f>ENISO.}) . . I! \VHITE 1\IESA URANIU1\·1 l\ULL {~._-~J!tL~,,~ FIELD DATA \\'ORKSHEET FOR GROUND WATER Description of Sampling Event: (. l..\1h Q~r .AJ ~+r0-t~~o; I Attachment 1 ~iiA Sec instruction Location (well name):\ .... ·_·T1 ... W_N--"-.... _4_· ________ -"'" Samp]cr Name and initials: I :r;noU" Ho I/"~~ /'1'1+' • Date and Time for Purgin~ . !r;!US/;tou ' and Sampling (if different) ] Well Purging Equip Used: []TIpump o@ bailer Well Pump (if other than Bennet) Prevo Well Sampled in Sampling Event I '--r_:o...;.y_JN_· _~_7_' ____ ..;...a I pH Buffer 7.0 Specific Conduc!unce .... I_'1.3..iQL...l'fI..;.,' .,;... .. ,_.,;.. ...... _. · ...... IJ.lMHOSI em Depth to Water Before Purgin~.'3§'~ 16 ,.:~ .1 pH Buffer 4.0 I .. <9:0' ',.' Wen Depth(O.Olft): I J~· .. "76 Casing Volwne (V) 4" well:1 6~:~YI(.653h) 3" Well: ; .,0,.':';;-.. : ... (.367h) Conductance (avg) 1:'··.,~·io'6~~··:.·.;··.;' '.:"::~ ',' :·' ... ·1 pH of Water (avg) P.':~~lJ , H'" :' .. "'.'.::',:.:.':, ...... , ,.( Well Water Temp. (avg) I J4 .~' .. 1 Redox Potential (Eh)Ld.'b5:'·· .. ,'1 Turbidity~J§J::K~:.J Temp_ ~C I. ll.o\.~":,·',1 Redox Potential Eh (mV) 1 .3~~' _ .1 Turbidity (NTU) I ' J5 b oll Time 1'c;zt;4 p. ;', Gal. Purged """,1}:...;.;.'30~_-", Conductance :~:',\O~9::i :~,'] .pH I "-:1 -15 ' ',' Temp, °C It :r~G~.~=J Redox Potential Eh (mV) I z, b~ Turbidity (NTU) 154 ,0 White Mesa Mill field Data Worksheet for Groundwater Ext'l Amb. Temp. "'c (prior sampling event)) ,'1~' .: J pH I .. · '.'1 '. 1,5'; :',!: .:. '.1 Temp.oC Redox Potential Eh (mV) I. '3b b .1 Turbidity (NTU) Time I Og05 Conductance Temp.oC Gal. Purged 11 Lf () . I joo;' .1 I l~.~'> I Redox Potential Eh (m V) Loot 2""b=.;' S=---_-.A T urbidlty (NTU) Mifi -Groundwater Discharge Permit () Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged 1"--)110-4:..;,;'0_, __ ---' gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Sl60 = 11.---..;...\0_" __ --' Time to evacuate two casing volumes (2V) T=2V/Q= 1I1.3D I Number of casing volumes evacuated (if other than two) -"I If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy LabfL..d~'i:..;..I;....A __________ ::--,-:1 Type of Sample VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Comment Sample Taken Y N Sample Vol (indicate if other than as specified below) L--___ ~ ___ ---'IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Filtered Y N Preservative Type Preservative Added Y N If preservative is used, specifY Type and Quantity of Preservative: LJ See instruction ~ 2 of2 capturx· C0h4~A11(jLE WIfH"/'-",.,,,,b-FUN(T10NALITY Mill -Groundwater Discharge Permit () Groundwater Monitoring Quality Assurance Plan (CAP) --" Date: 03/22/2010 Rev. 6 r . ___ l ATTACHMENT 1 Attachment 1 [OENISOn ' . ~ i 'VHITE IUESA URANIUM l\'lILL ~/,~ S~e instnlction "'~..1.t!.'.!...~J FIELD DATA 'VORKSHEET FOR GROUND 'VATER Description of Sampling Event: 1 1..\1'"~ Q",w fd N ;+;c.. r<=. ;2..0'11 Samp1er Name Location (well name):1 'T v,;"N -5 ' and initials: I""'-;'I\nl!r Holl:J"z} In; ., Date and Time for Purgin~ ·\O/I'1 /~OH ·1 and Sampling (if different) I .;.]/8 ." I Well Purging Equip Used: !IDpump o@ bailer Well Pump (if other than Bennet) I G:rv.na--£o~ .' I pH Buffer 7.0 I · 7 .,0 .···.· I Specific ConductancelL--' :l..L..'1.L..4L..-__ ·-I,1 J.lMHOSl cm Depth to Water Before Purgin~~b~.7g ::>. Conductance (avg) I Prevo Well Sampled in Sampling Event li.--';""': w_N_ .... _ . ..;,it ____ ...I pH Buffer 4.0 Well Deptb(O.OI ft): I ] 56: 60 ' . ,'" Casing Volume (V) pH of Water (avg) 4" well:l t,~}~:" IC.653h) 3" Well: .' ,:.:0 ',/' ... r·: (.367h) Well Water Temp. (avg) '·.1 y ;'~y>'. , I Redox Potential (Eh) I. ;:3,o.i ,'c' I Turbidityl ·.y.q;·· I.:!:' .1 Weather Condo Time 1 ·\5~1 ' ~: .'. "' .. } Temp.oC Redox Potential Eh (mV) 11,.,;.~· .... '3~11_·_----' Turbidity (NTU) Time '-1 ..... ~3~3..:;.j"""'---:.....-J Conductance I 3oj.b Temp. °C I 14 ,8'14 Gal. Purged , __ · .... ·jo ..... l> __ ' --";'_-' I I Redox Potential Eh (m V) ..... 1-:).c..;O-.7....o...-_ ...... Turbidity (NTU) I 4,9 White Mesa Mill Field Data Worksheet fot Groundwater Ext'l Amb. Temp. °C (prior sampling event)r·} bf)'" .·:1 Conductance k· "3077 'j',: -,:. -I Temp.oC Redox Potential Eh (m V) I · :30'1 " . I Turbidity (NTU) I Time I Cdo .. : I Gal. Purged _I 1 ..... J 0 ........ :_._---' Conductance 1'3()7'j ... I Temp. °c 1114.Ztt I Redox Potentia) Eh (mV) I 30b " Turbidity (NTU) A 1 0f 2 capturx' COMPU tlll£ WITH/,,-W,~·n:--:-fUNCTIONAlITY Mill • Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (OAP) ,i~ l J •••• __ .J Date: 03/22/2010 Rev. 6 Volume of Water Purged 1-[ _)u).lo.()4--__ --' gallon{s} Pumping Rale Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 = _L __ l~O ________ --I T = 2ViQ = " t6.Yj I Number of casing volumes evacuated (if other than two) If wen evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Lab~ ivt /F', ,:': " ,~~;,,~':"" ." -, ' :,- Type of Sample SComment Sample Taken Sample Vol (indicate if other than as specified below) '--_______ ....... ]00 not touch this cell (SheetName) White Mesa Mifl Field Data Worksheet for Groundwater Filtered Preservative Added If preservative is used, specify Type and Quantity of Preservative: ;-.A, See instruction 'rr"''''~ A 2of 2 capturx" COMPATIBLE WITtf/,-wu;ri:--FUNCTIONALITY ,""""'.~ r!1m-Groundwater Discharge Permit ( ) Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (CAP) 1 -._, ' ..... ' --':" ATTACHMENT I 1 ,/l 'j \VHITE l\IESA URANIUM MILL ~,~~3E~q~.~,~, '. FIELD DATA WORKSHEET FOR GROUND 'VATER Description of Sampling Event: I \,;.yr"".Q~~(,+Gr . .N\1-ro-..te.. :2.0 i, Attachment 1 :E~~ St!~ instruction I Location (well name): ..... 1 .....;l-.::w~}J_-..;;.~ ___ ---.;. ____ .......... ·1 Sampler Name and initials: l·-r: .. nn «r . Hclll,"J,l'1 /T'H ' ""I Date and Time for Purgin~ ',. 1 a/let /:;./.JH ". . I and Sampling (if different) I· pIA Well Purging Equip Used: [][]pump o@ bailer Well Pump (if other than Bennet) Prevo Well Sampled in Sampling Event I '-.;...~ .... ~~;::_N_'~_·'t.t_· '--';"";';""""; __ -11 pH Buffer 7.0 1< "'~i 0 ':>·: . ,~ .. ~.I pH Buffer 4.0 Specific Conductancel 'A~ ,~. ~'::'''.' .': hlMHOSl em Depth to Water Before purgini·i'1',lld ... ',', ':: I Casing Volume (V) Redox Potential (Eh) 1 ··F.$r~ ~':", . ~.').:I Temp. QC Redox Potential Eh (mV) I .... , .;;.",a:,3::;..:.tq""--_....£1 Turbidity (NTU) I:;' p..j' "::,'·1 Time Ibg5r ·, ,'.:, Gal. Purged I· "1D.'.,:· Conductance ( , ly ~ pH I ,., 'fH ' ' : '" Temp. 'G-C !l4z 5!.. Redox Potential Eh (m V) ..... 1 ...,;;;;"3;..:..l'fol...:.' __ '_' *-A' I Turbidity (NTU) I } I ' I I White Mesa Mill Field Data Worksheet for Groundwater Ext" Amb. Temp. °C (prior sampling event} I ;".qo.::';-~ , Temp.oC Redox Potential Eh (mV) I· :'3~i~r>" , Turbidity (NTU) Time 10·8:53.. GaL Purged t'.,'Sit?'·:." ,.1 Conductance I l"'i(;.i I pH f '.'t3 , .. , Temp.oC I 111 .5(, ,;,.-) Redox Potential Eh (m V) 1\00.03"..." ...... ~ __ ~ Turbidity (NTU) {J 1·::t ,Mill. Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) " Volume of Water Purged 11-_!6 .... D_· ___ -'" gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 10-1 --:.;:;.\0_' __ --' Time to evacuate two casing volumes (2V) T = 2V/Q == 1·'7 .;;t 1 I Number of casing volumes evacuated (if other than two) ·1 Ifwell evacuated to dryness~ number of gal10ns evacuated Name of Certified Analytical Laboratory if Other Than Energy Labfs...;.~N~V.:....l·A~::-~~;;;....;.,. __ ·...;;-~;,,1 Type of Sample c.h\or~ck Sample Taken Y N Sample Vol (indicate if other than as specified below) Filtered Y N Preservative Type Preservative Added Y N If preservative is used, specify Type and Quantity of Preservatiyc: ~Comment ~ See instruction . A rr; ~ eAo~ .~)"~-l: ob~ .;~M~C; "';'rir~i';;1\ f r~!.~~ ·.vOI" 'Y'~~e ~I' ~ S.-f\:~ .~\l ~~t. . ?W"~ e ., be~o." ,,-\ piSl1~ .fv. ... jeA. \,j~" ~ .. 0... +¢-t~J.o-f g .:,ypn~+~~to"-..\--c:( u'l,a.~ mos+l~ G leo.r .1hr6V.j1tl'u:t ."+h'~ fV.(-~f' ·fv.~~' enJe!' ~.J ' 5o.~r\e~ .-were.. c611cc.tcJ ~+. q~~.~ .. ! D(;p~~.1(\~(A+er "Ji-e( P~C:~v.1fA~ ~;!.1tt . Le.~·~·t·h: ~r D851 '.' . : ........ _______ ----J,IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Mill -Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) I 1ft ~~ ATTACHMENT 1 Ie r~ . B J \VHITE l\IESA URANIUM MILL Attachment I ;{'!f~~ So.!C instruction ·~~~~~L~;..l FIELD DATA \VORKSHEET FOR GROUND \VATER Description of Sampling Event: I '-\~ Qv..o..",,1er-N ,,+(~+.e.. ~o'll Location (well name ):~I _'-~I w:;.;:..;..JJ=----!.1_· __ ---" ____ --' Sampler Name and initials: I-:f!.nncr Hcll.'J s,1!TH: Date and Time for Purgin~.. '() / I i< /:l.b I , and Sampling (if different) I .ll? /1'i/p.OJI. I Well Purging Equip Used: [f[]pump o@ bailer Well Pump (if other than Bennet) f'~:~:r&,;::-=J Sampling Event I Qv..<V"fc.rb 1\J :1-ro..t:e., Prev. Well Sampled in Sampling Event 1:'-w ~ ~ 7R:, " I pH Buffer 7.0 ( -r .' 0 ':'" ~ . I pH Buffer 4.0 Specific Conductance I 491 .. ' "I~MHOSl em Wen Depth(O.Olft): I-10S .00"· Depth to Water Before Purgingr'25% >7(;/ '.:: I Casing Volwne (V) "~':"""':"""::'i 4 Well: "iO .... &_ ....... ,:·:.,.,)(.653h) 3" Wen· '. ).'.>', .:: ',.[ (367h) ......... '" .. '.' ,-'-_.:': I • Conductance (avg) pH of Water (avg) Well Water Temp. (avg) "1L1 :7'J....· :,1 Redox Potential (Eh)I .: . :}g~' '.1 Weather Condo Time 1:0, ,"1 -.. I GaL Purged l ·ft··:~r:·:r·~·'::':l Conductance [}llfL~:;:~.-] pH L .. 7.~ .. ·.·:~:,.:I Temp. 'i,'}C f:·Jg·1a':·' '.' ··~.I Redox Potential Eh (mV) I 3~~'" Turbidity (NTU) t ·,} }·:"I Time Gal. Purged f . . '1 Conductance pH I ., Temp.oC Redox Potential Eh (m V) .... 1 ___ --" Turbidity (NTU) White Mesa Mill field Data Worksheet for Groundwater Ext'l Amb. Temp. °C (prior sampling event)l.5c':;:·-.. ) GaL Purged '1.-..... _, ... :. _____ : ..... :> ..... :;; I Conductance ",~ " ",,:.' I Temp.oC Redox Potential Eh (mV) L-I ....;...: · __ ......... 1 Turbidity (NTU) I > ... J Time I " -: I Gal. Purged 1,-__ ...;...;.--.." Conductance pH 1,-' ___ ..... Temp.oC Redox Potential Eh (mV) ,'--__ ---' Turbidity (NTU) .A 1 of 2 capturx~ COMPATIBLE WI'TH/"-W&~·W-FUIH;TlONAliTY Mill· Groundwater Discharge Permit , -~) Groundwater Monitoring Quality Assurance Plan (CAP) Date: 03/22/2010 Rev. 6 Volume of Water Purged IL--...r.\':\--'-___ .... gallan(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = !.-I ---:;.I,¥...O __ ---' Time to evacuate two casing volumes (2V) T = 2V /Q = I ;l.. 'a I Number of easing volumes evacuated (ifolher than two) 11. \~ If wel1 evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Lab~L..._N...;,./_A. ______ ......t'1 Type of Sample VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) ~ ~Commcnt S 1 Tak Sample Vol (indicate amp e en if other than as Y N specified below) '--___________ 100 not touch this cell (SheetName) White Mesa Mil! Field Data Worksheet (or Groundwater Filtered Y N Preservative Type Preservative Added Y N "'; \;::;8.':'~'Tt,~{;~:,{", .' •• , ..... \ -·";"*N·~· '-_. If preservative is used, spedfy Type and Quantity of Presentative: !<~ See instruction ~ 2of2 capturx' COMI'ATI9L£ WITH/"" U"~'l'Zr--F UNCTION"lITV MitL· Groundwater Discharge Permit f ') Groundwater Monitoring Quality Assurance Plan (QAP) (), '. "'-.'" Date: 03/2212010 Rev. 6 . i l ---j 1 A TTACH~1ENT 1 Attachment 1 j DENiSOn . I \VHITE f\fESA URANIUM ~HLL :~t~ Sw instnlction t~~~~ ...... ..,.) FIELD DATA WORKSHEET FOR GROUND \VATER Description of Sampling Event: I t4"'f'1\ G\A~ter N ~t-(" "'+c.. ·~o I \ I 11\ Sampler Name E;;: . ~ .. <~!;;JI · ], Location (well name): . vJJJ -i K and initials: L·:r:;!1_n,·'_ ,L~nA~~~~1-f--_ Date and Time for Purgin~ . lolls' /~O}) 'J and Sampling (if different) I Wen Purging Equip Used: [IDpump o@ bailer pH Buffer 7.0 1 .1.0 " -. ,., _. f -: Specific Conductance_I _4 ... ·~~1~· _..;.;..._-..;,.a:.JJ.lMHOSI em Depth to Water Before Purgin~. 0· ... ·· ·-~':.I Conductance (avg) Well Pump (if other than Bennet) Prevo Well Sampled in Sampling Event I · -r"vJlJ ~ 1~· 1 pH Buffer 4.0 I.' "" .. 0 . : ·,1 Well Depth(O.OI ft): &.;...;1'._·.:0......;,·:...;... ~_~.I Casing Volume (V) 4" weill ' ,0 •. ..• IC653h) 3" Well:_ '·.·".0 .. :; ... ' . (.367h) Well Water Temp. (avg) I ':,,:}tf. '3 5 ,. ·.:.1 Redox Potential (Eh)I,:: "3(,1 ':':::< I Turbidityl3~ J :;::; "; . ,: I Ext-I Amb. Temp. °C (prior sampling event)I·; .. ·~~" ':1 Time k.~;:.:,:: " ..... J GaL Purged 1",-_ . ..;..;.:', '-..'-.,;.,;.,'..,;.-. _" ....... 'I Conductance 10 <; "'~."'.;' :~.:-Conductance ,-I :.;..~ .-......_ .... ...;. ... :,.;;.;,:::_\ . .;...11:) pH 110.-"_: _,...;.. .. .;....I: ..... j Temp.oC "1'1./3 ~'.'.'-:: I Temp.oC :.". : I Redox Potential Eh (m V) r _3':1::: ,;] Redox Potential Eh (m V) I . _-:'.:." . . I Turbidity (NTU) I 'OJ" ," I Turbidity (NTU) Time Gal. Purged ''--.-......,;._--..1·1 Time 1-.,' ".-. Gal. Purged &...1· _____ "....lI1 Conductance pHI~ ____ ' ....... 1 pHIl-____ ·1 Temp. ,z,C Redox Potential Eh (mV) 1..-1 ___ --11.1 Turbidity (NTU) I White Mesa Mill Field Data Worksheet for Groundwater Mill. GrQundwater. Di~charge ~ermit (J Groundwater MOOitonng Quality Assurance Plan (QAP) ~'.~ Date: 03/22/2010 Rev. 6 Volume of Water Purged gallon(s) Pumping Rate Calculation Flow Rate (Q). in gpm. Time to evacuate two casing volumes (2V) " S/60 = I,',',' . )0 ': : I T = 2V/Q = I' ',ej':'_" . :' I Number of casing volumes evacuated (if other than two) I :r:~: ','. .··· .. 1 If well evacuated to dryness~ number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labf .... M.;;,;.\/...,.;.·:\:.,..· ... ·..;;.,.:,;:_·· .' ___ ~ ____ --I: I Type of Sample Sample Taken Y N VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Sample Vol (indicate if other than as specified below) Filtered Y N Preservati ve Type Preservative Added Y N If preservative is used, specify Type and Quantity of Presen'ativc: fComnlent ".:~ See instruction l.~ At'ri,v cd.,~ o~, ~ i-l:~ ;":\-() 1.3' g . ,-:r",;~,'c(~h~G',,;~ i~'~)~d~~rt+~';fo; r;'i1\4+< .R;'~~<i ~'bed"" qt •. ,'·' '6~ 9 L·:F ~ ~<:~,"'o G-t.11~~ ,~ii tll>l ~fd'" S O~111\Il5.s(J<tF't.)~~; I 00 6-4J~ns of' ... ~ .< \.\i.e( . r .... :·-:~;i1-~~c:: '~~~~J.. ~a ~J\MP lc.s _w~te:. c;.·~lI~((kJ , ctt ·-b?O(J~> '. ;;. ..'_ .Left ... ~.I·t~·~t 070li .. "'· .'" ..'. . ' 1-.-_______ ..... 100 not touch this cell (SheetName) White Mesa MHI Field Data Worksheet for Groundwater A ;1 of2 capturx' COMPATIBLE WITH/'-Ut~·li::--fUNCT/ONAtIT.,. Min. Groundwater Discharge Permit :r-) Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) " I . I ATTACHl\'IENT J Attachment I l OENtSO,})~. '.:1! WHITE ~IESA URANIUM I\nLL :,,,,~ See iustnlction 4~ ... ¥.I,tf\~~"",,~~ FIELD DATA 'VORKSHEET FOR GROUND 'VATER Description of Sampling Event: 1 14·r1'\'Q lAf"ctc.r tJ l'tr~h. ;4otl =] Sampler Name Location (well name):! 'jvJN-g and initials: I -r;:,J'I1'\ (f 1-1(' H:Jtd,!1 l in Date and Time for Purging) .... _' o...;../_11_1;....;;:)..;,....;();...;.\1~ ___ ....... Well Purging Equip Used:OOpump o@ bailer pH Buffer 7.0 I ... -'.0 :. , Specific Conductance ..... 1 -l4w'1.-;,.'1 --.;.,--..;..._.....1··1 J-lMlJOS,I em Depth to Water Before Purgin~ bl .bO . ·1 and Sampling (i f different) ..... 1 __ AJ,~~...,8i.-' _____ --.01 Well Pump (if other than Bennet) I &(\A.nafc> ' Prevo Well Sampled in Sampling Event 1·1\';".). ~ 1\ pH Buffer 4.0 '4.0 Well Depth(O.Olft): I \45. :5b Casing Volume (V) 4" well:l .5 4:1g ... i<-653h) 3'* Well: 0 :·, .. ;. (.367h) Conductance (avg) (.~ Y '3:3 : " I pH of Water (avg) I. -'.00 Well Water Temp. (avg) I· t.L.\ .:)g , ~,J Redox Potential (Eh)L.;I.)!....;b;;:;..b=--~-' Turbidityh-I 9..:..;;.: __ 1 _' _ ........... ·1 Weather Condo Exfl Amb. Temp. "c (prior sampling event) 1&...,'<1...:,.°_' ..:..-...I Gal. Purged a.;.;.L..;.\ o;;..:;;o~· _-..;..::, ",I. Time I08Dt':·." .. ,I GaL Purged (. 'Ill) 'I Conductance 1?.4 ~i pH I' '~:'i.O-:A " I Conductance I :t~·J,U'·: ,. :'1 pH I:·;i.o/ I Temp.oC 1\\..\.40 Temp.oC I 14 .lit>· I Redox Potential Eh (mV) 1.0-1 ~lb=-q.L..;· _~ Redox Potential Eh (mV) 1165 ·, ' I Turbidity (NTU) ': ",\ .. 1 .' Turbidity (NTU) I ,~,7 I Time f O~O~ Gal. Purged .... 1 ..... l~ __ () __ ...., Time [9i9E:,·· .) Gal. Purged I J3t) I Conductance [-i~ii ,.:,] pH ,--11~'O::;.;;C~----, Conductance 1~~3b I pH 17.a J Temp.e:C I lij .~~ Temp.oC I iii·1! ... -,] Redox Potential Eh (mV) I '-_'--.bl ___ ...... Redox Potential Eh (mV) I flC I Turbidity (NfU) Turbidity (NTU) 1~;9 I White Mesa Mill Field Data Worksheet for Groundwater A 1012 capturx' COMPATIBL£ WITH/"-~o,,,·n:>--rIlNCTl~NA~IH Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP} /"",\ " Volume of Water Purged 1-1 ..... 1_·:>60.4-___ ....1 Pumping Rate Calculation Date: 03/22/2010 Rev. 6 gallon(s) Flow Rate (Q), in gpm. S/60 = I (0,£:1.5 · Time to evacuate two casing volumes (2V) T=2V/Q= I tD ·'i5 I \D Number of casing volumes evacuated (if other than two) If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Lab~L.A:...;'f,:.:..A=--__ -.;.. ___ --I Type of Sample S I Tak Sample Vol (indicate amp e en if other than as Y N specified below) VOCs Nutrients Heavy Metals .... -. '~:":".' .i' .. '1':':"1 ';-", 2' 50 1 .. ;,.c.;:..".:;~:~ '\""~f'~':'; m An Other Non Radiologies .. ,'. Gross Alpha Other (speci fy) ·,;,.·.r,':,7ij] .. ;,··.~'.,·,,',:,~1.: ... ':,'; f~~qW'" Sainjll.: e. vo~~i1te ~ _. -:."< ~'-,-'~ • .'t,,-~. co ~Comment " ., . '--_______ ---.lIDo not touch this ceIl (SheetName) ~ .. White Mesa Mill FIeld Oata worksheet for Groundwater Filtered Preservative Y N Type Preservative Added Y N If preservative is used. specify Type and Quantity of Preservative: I~~ See instruction A 2of2 ,capturx-COMf.'ATIGU wlrH~w,,,,,,.zi;--tU"lCTION"tlTY ~iIt • Groundwater Discharge Permit l~) ~roundwater Monitoring Quality Assurance Ptan (CAP) ~, .• ,' () Date: 03/22/2010 Rev. 6 Attachment 1 l~'~~ See instnlction ! . -. "' ...... --.-'1. ATTACHI\'1ENT 1 jOENISOtl.) .', It WHITE ~IESA URANIU~ll\nLL ~il ..... ~l~ .. M~'~h~I~"","'~~.j FIELD DATA 'VORKSHEET FOR GROUND WATER Description of Sampling Event: 14Th . Qv.c....r+er A,):-{ rc-'\=e;' ;2.011 : ' Location (well name):It...-_l· ...... ~_N.;,;;.:~...lo"·~"'-R __ · ._:; _" --o..-~--.. __ ...-..-_. · .... :._'1 Sampler Name and initials: I-f'Mn~r.· ~6n ;J~'1;111 Date and Time for Purgin~.~16/l7/.q.(jll ," . ./,] and Sampling (if different) I .. fo'/A .:,' I Well Purging Equip Used:IT!Jpump or@] bailer Well Pump (if other than Bennet) ~ITNnd £t6::;·:·.'=·;~'~.:] Prevo Well Sampled in Sampling Event I, :':/A " .\" pH Buffer 7.0 pH Buffer 4.0 I"'. :','.'.4 ' .. ,""'" . ·:t _ v I.,':' '}).~. ... Specific Conductancel :~a.A·~·:-;:. ".' .. ':: 'Iv-MIIOSl em Wen Depth(O.O 1ft): r 0 ;,' '~ .. : .. ' .:- Casing Vohune (V) ::: ::::~I ~g ,;:i:;,l,'(;J~:~~;~~ Conductance (avg) t'ti"~;:f~Ir:;;~;,:.::.,;?\,:-/,:("" :».,.';.::,<"., , pH of Water (avg)' r:~ ~O::«: {'·;;:,:,\X':':;iC:',.;:<''\:': :'.,:-1 Well Water Temp. (avg) r .jq<() 0'.:::.' <:1 Redox Potential (Eh) 1;::;·'50,0·,:\:: ,' ... :.1 Turbidityl :·0.<.·:>'" :.:;, ::1 Weather Condo . Conductance Temp.o-C I ::~b'··:.9 .-; ;,";'::: .. :'; I 1··,l'LCO ~"·:':>< I Redox Potential Eh (mV) 1::506"" '1 Turbidity (NTU) I ' '0 '"" ·· .. ·1 . . ... ~ ",b;'·' Time I· . ,"'. ;.:: .' I Gal. Purged ' ..... ____ ,,_. _ ........ "'--s' Conductance '-1.· ___ ·: ..... ·, '_:I pH 1"",,;_: ___ ~_" " .... 1 Temp.oC (". "I Redox Potential Eh (m V) _1-....-_____ ..... Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Tune: I ~~~·,~:e{.' ':':~~~' ,:~ ;:::; i:;~"·1 Conductance r;,:·);;·::\>:,~·' ,: .:: ·1 Temp.oC Redox Potential Eh (mV) r. .:.,,, :1 Turbidity (NTU) Time 111-'_>""" .-......_.....1.] Gal. Purged It....· __ 'M-.' _ .. ....l., Conductance _r ____ ~·'1 pHI~~~~'1 Temp.oC I Redox Potential Eh (m V) I"--_____ -.t·) Turbidity (NTU) I M7u -Groundwater Discharge Permit Groundwater Monitoring Qualitv Assurance Plan (QAP) Volume of Water Purged ..... 1 .... ;;.,0.;;1,0_·._0 ___ ---1 Pwnping Rate Calculation Flow Rate (Q), in gpm. 5/60= ...... 1 ~'l O=-1 . __ --1 () Date: 03/22/2010 Rev. 6 gallon(s) Time to evacuate two casing volumes (2V) T = 2V/Q = I ()' . I Number of casing volumes evacuated (if other than two) Q '1 Ifwen evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labf~}.J...;..;' /,.:...;-\:...;.: ___ .;......;.......:.-~....;...;;.... . ...;...:. ";...;...J.t Type ofSampJc VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (speci fy) Sample Vol (indicate Preservative Sample Taken Filtered Preservative if other than as Added Y N specified be1ow) Y N Type Y N If preservative is used, specifY Type and Quantity of Preservative: ~Comment b~ See instruction ,. ~I' '--_______ -IIDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater ~ 2 of2 capturx' tOMPAn6LE WITH./'--",.~·W_f t.JNCTlONMlTY Mill • Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater MonItoring Quality Assurance Plan (OAP) 1 .. , ATTACHMENT I H)ENISO./)11 .! I \VHITE l\IESA URANIUM MILL Attachment I ~~ Sec instnlction ··~l~L~!~ ... -, .. ~~ ..... .J FIELD DATA 'VORKSHEET FOR GROUND 'VATER Description of Sampling Event: I l.l~· G)v..~~t~r N ;~r",1t!.. :;"01 , Location (well name):I_:r.a...x.:v...1oI..I1N;...;;......··_9 ____________ ...... Sampler Name and initials: I "]ifll'lcr ttoll,'k'j/T/t Date and Time for Purginf{·io!,1:2.i,eu .. '=:==-J and Sampling (ifdifferent) IO/2DI;ZOlJ . Well Purging Equip Used:~pump o@ bailer Well Pump (if other than Bennet) I C-c\.\ndt"6;· SampJing Event I Q~rtelb N ;1ffAte. =J Prevo Well Sampled in Sampling Event L..1_'Ti_~_;J_,_-_}7 ____ --' pH Buffer 7.0 I · :':1.0 ..... 1 pH Buffer 4.0 E:'4 ,:D'~ ·1 Specific Conductance .... 1" _: q.:....:q ..... q_~~--..al J,.lMHOSl cm Well Depth(O.Olft): I qi.l)Q Depth to Water Before Purgin~ '3.4.Q .. >: '".1 Casing Volume (V) Conductance (avg) .~.< ,I pH of Water (avg) . :.n'; I ,'';' ... >"'/':,,,,', Well Water Temp. (avg) I,\y :7~ .. :1 Redox Potential (Eh)L,13!?\ .. :·."1 Turbidity I .... ' =c;~;..:...'" __ '...:.t'.1 Conductance 1.:t~:J5 \} ·1 Temp. qc tlt{1.~' ,:.:.' 'I Redox Potential Eh (mV) ...... 13..1;5;;::.1:...· --.o..;...;· ... ;....al Turbidity (NTU) J Time ... ' _'_'_' __ -I GaL Purged _I ._. _ ................ -1'1 Conductance '---_____ ·_1 pH _I _,., ___ :_1 Temp.oC n I Redox Potential Eh (m V) .... 1 ___ _ Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Ext'J Amb. Temp. °C (prior sampUngevent)I '~O~~ . Time J:~'" '. " ~' " .. <: I Gal. Purged I:·"; .' .... ;,~.,:', ',I Conductance &....,;.,1:·,·_,. _--1>1 pHt,--""_' _"'--1,·1 Temp.oC L Redox Potential Eh (mV) [,.,1 Turbidity (NTU) r ..... .' 'I Time 1 ..... _ .. ______ --' GaL Purged _I ___ ..0..1.1 Conductance _____ ........ I pH ,,--I __ ---II Temp.oC I Redox Potential Eh (m V) 1.;..1-.-;. __ ....." I Turbidity (NTU) I Mill· Groundwater Discharge Permit 0 Groundwater Monitoring Quality Assurance Plan (QAP) , Date: 03/22/2010 Rev. 6 Volume of Water Purged I .... ...,.;;S;;...,O ___ ---a gallon(s) Pumping Rate Calculation Flow Rate (Q)~ in gpm. Time to evacuate two casing volumes (2V) S/60 = I \ () -' I T=2V/Q= (Y .'3g '. I Number of casing volumes evacuated (if other than two) 1..1.40 If well evacuated to dryness, number of gallons evacuated 130· .... · .. '1 Name of Certified Analytical Laboratory if Other Than Energy Labf .... ' _'M .... " / ... '{l; ..... ; ..... , ... ...,;.:,._ ........ _" '~' ...;...;...-.-;........;':;......t;1 Type of Sample Sample Taken Y N VOCs Nutrients Heavy Metals . All Other Non Radiologies Gross Alpha Other (specify) Sample Vol (indicate if other than as specified below) Filtered Y N Preservative Type Preservati~.,tC Added Y N I f preservative is used, specifY Type and Quantity of Preservative: t! ~ See instruction ~Comment tI;;\~~f()" ii1-~",l :6f5~~R;~~i;~~F(;r;,p,;<71~1!t~t\U~~~~~4" ',?16 ~.~~~" '.;.+ (o8f? '." f?~(~~J. .. ~.~l\ .. ~or ,,-~o+~.1 . :.~.~ .. 1l'\~!,lAJ~~.'· .. p~r6~d.:Vl~I.~;J.~1:·:.t.'~t~r., .~~~3~ostlj·, .t::;};~()._r~:. , .... R~~-c! ,e,l'ld~a-~1 :.O~30: .. :.~~f1 ~? ~c,';,C\t,:·8~:13,;"::: :.->' ';':"'" ~"::': :;':' .. : ..... , ':.': ,';',.' .. -, ' .. '," ~·c-. tm ~ ~~o''', !,ite.... 1-wi',: ,..;';",\ ~ r in ti : Go.;./,,; ~ j:)\"~r1+ "-t"LoU ed, ~ .. i') pld.,De p+h " to\}) ~ f~r ·vJ~· b3 ~~\ SG\l'V\p\:e~ ·\N~ .. ·L':·b~~\:.~,~ .. 9b.·~3 -. Le·f+ .$'+<' lI\t. 065h ·· ' . . 'I' .... 1·_,--.,;... ____ ...;..... _____ 100 not touch this cell (SheetName) White Mesa Mil! Field Data Worksheet for Groundwater ~ 2 of2 capturx· (O"4I'ArtIlLE YIlTH~W.~·.T--FUNCTtQNALIT'I • "1m • Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ,~-.'~, I ~1 .-' Date: 03/22/2010 Rev. 6 iOEN'SoJ)~.· ,i WHITE~~:~~~:::I~!I MILL ~~!!!t!! .. L ""'_;"mJ FIELD DATA ,VORKSHEET FOR GROUND 'VATER Attachment J '-~ s· . ;","~,,",""': ce IllstructlOn Description of Sampling Event: I Y""~ Q v..o.r·~t!r tV :+ (" ~t<. ,;2.0 I' . Location (well name):t-I ~)~W~N.;...-_I:...;;i)~ _______ ---, Sampler Name and initials: I j:(1Hl(.r Hoill'J'S.,;J jill- Dale and Time for Purging \D/11/~DI\ Well Purging Equip Used: 00 pump o@ bailer pH Buffer 7.0 1 ',,0:. '. Specific Conductance """L·_ .. 1 ...... 4..1..· '~_~---II fJ.MHOSi em Depth to Water Before Purgin~' 5S·1~1'> .. ~: ·1 , I and Sampling (if different) Well Pump (if other than Bennet) Prev. Well Sampled in Sampling Event I 'T'w /IJ-13 pH Buffer 4.0 Well Depth(O.Olft): I'lD5~'bb ' ' Casing Volume (V) 4" well:I ·Ii;. i'l. . 'IC.653h) 311 Well:.:o ; ,.(.367h) pH of Water (avg) L..I·_~:....::3=-b_'_' -.-;.:'_" "':";"';_~-":·".;..JI Conductance (avg) I.... ,:' ~ '4'1" . ' Well Water Temp. (avg) I ,'I.s~9 0 .' Redox Potential (Eh) I 4 ~2 " .' '1 Turbidityl y~-q .~ Time I· O'lSq , "" Gal. Purged 1":3&.: ~': .. '::.; I Conductance I 5b'i7j·.:.:·>:·".' pH Ig ~''3k'' .;1 Temp_ ~C I }~,:4b : Redox Potential Eh (mV) I' ~b S ;. =J Turbidity (NTU) Time .... 1 _. ___ ...... GaL Purged ..... 1 ___ '"-' Conductance pH ,--I __ ----' Temp.oC Redox Potential Eh (mV) .... 1 ___ --' Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater ExtJI Amb. Temp. c>c {prior sampling event) 1 .... 1.;..;1_0 __ Time Gal. Purged ,. . :.' .I Conductance Temp.oC Redox Potential Eh (mV) L-l ___ , '~.I Turbidity (NTU) I Time GaL Purged .... 1 ___ ---I Conductance ..... 1' ___ ..... pH .... I __ ~ ..... Temp.~C L. __ --' Redox Potential Eh (mV) 1...1 ___ --' Turbidity (NTU) • Mill· Groundwater Oischarge Permit Groundwater Monitoring Quality Assurance Plan (CAP) o Date: 03/22/2010 Rev. 6 Volume of Water Purged z...1_3""""""'8"'--__ _ gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) " 5160 = 10-1 .....,::l;.::;,.b ___ -"" T=2V/Q= 1'3.03 , .1 Number of easing volumes evacuated (ifother than two) j:.:',<:; .. ,' I If well evacuated to dryness, munber of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labf :::;;';i~':':-': ",' ,~',I Type ofSamp1c VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Sample Taken Y N Sample Vol (indicate if other than as specified below) Filtered Y N Preservative Type Preservative Added Y N If preservative is used? specify Type and Quantity of Preservative: ~Comment t~ See instruction A (T·:~!x ;n j ;t <c t001 .. 0'1,50 :~,,~/ ~"A.;(rN; ~~P'-~ s~nt . + "ft~;' -rw'~~I~: p ""§ h~":n "},v 'IS 5. P v.r~~A w..11 for ",C +~",\ ~r;'~ M ~I) ,,-\!S ' ~d ~t' ~.ec.6nd S :\.).:),1 f <l1Id.~,I. 'p"G'" ~"d ~ J .. t oQ5'1 .. V-?(,d-cr .. h~.'Vi~ IJH~ '. til?coL~( tc>. it ," ~,e+1 .5 :.fC '\j )C?O~ ,. . .' .' < Arri,Je~ ~n S~, C\+ Ob"'b. ,.~(\I\.e.r .~\na "G:'~~rr-\ 1\-pre.s.in·r :· to c..c'\\e.(.t ~'~tv\'p\e~ Q Gpt~. oro to(.\'h::r ~~ .,gl.P.>o S~rv\ p'~ IN.~I~ ba.:lt:.(,t '\r o~~o·:, Le.~T ~it~ '",1-'O'~3 L---_~ _____ --IIDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Mill -Groundwater Discharge Permit f) () Date: 0.3/22/2010 Rev. 6 Groundwater Monitoring Qua1ity Assurance Plan (QAP) "'",~,;J Attachment 1 ,. ' "', ATTACHMENT 1 ;OENISO.n j'tl \VHITE l\'fESA URANIUl\'1 MILL '"~~~~"j"~.J FIELD DATA \VORKSHEET FOR GROUND \VATER Description ~fSrunpling Event: 11.j1-h ~~+~r Nrlr~t~ ;20\'( ... · Sampler Name:1ii; ... ... ---,-, Location (well name):(' Tw,j ~l] .f". . '1 and initials: L;0~~~' HoJ,t.J,~i&·=<_~ Date and Time for Purgin~ ioi j1/~OI( '-' l., I Well Purging Equip Used: J. (SJ 'I pump or[QJ bailer Specific Conductancel :: q~~ : .... : .... <... : .. :·!..lMHOS/ cm Depth to Water Before Purgingi' ~/l1D \' :··1 and Sampling (if different) . JJ/ d e .. : ... < ·:.· .. 1 Well Pump (if other than Bennet) [z.;;:-:dJb.s'u:· . :,'.1 Prey. Well Sampled in Sampling Event 1-r0Ai-u) ... pH Buffer 4.0 Casing Volume (V) I 4" wellri7~f,:I(.653h) 3" Well: .. ';,.':i:)"::"~":":."",,., (.367h) I Conductance (avg) 1:",,;,;; 27':'~:,:,.~"'::·~:t::::'" ,'i:;:'; '.'.:'~'.,:,; I ' pH of Water (avg) , ... :. G~7~"":'.:;';;:':': ;,l~. ?::-:,::;';:,', I Well Water Temp. (avg) l:j q , ~7J ':,:,:: J Redox Potential (Eh) 1'36.5 .: .« I Turbidityl >I~?d '.' Temp.oC 1'·IY·.bg ·:·.\.1 Turbidity (NTU) Time I" tb'-\4 •. Gal. Purged I · )00.'. ; "'1 Conductance I ::<:7 t; 5 '-,' I pH I G.76 ' :I Redox Potential Eh (mV) I -;'05 Turbidity (NYU) I '::s.. 4 , I White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. DC (prior sampling event)IJb~ ?: I Time I )'-."t'?] '~":\):':::;d Gal. Purged Fflo :.\'.:,:::; .,::::,~'I Conductance fa. 7 '3 ·:!:·~·:;.I pH :L~~:!ii·;::·;.:~>I1 Temp.oC 1,19~_Q.~:·.-:'] Redox Potential Eh (mV) "'30(; :. Turbidity (NTU) Il.2 :.~,·· 'I Time Il;l.~5 '. . " .1 Gal. Purged I L..f, ).::..;1 0;.-' .~. ___ ...,;.:··.,...!I Conductance I ~7'R·'·· I Temp.oC I 1~·:"'7 ·1 Redox Potential Eh (m V) 1o-11..c..O;;...S",,-..;.-.-.~.1 Turbidity (NTU) I J~·lf I '1 MVI. Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Waler Purged .... 1 ___ I._to_,., ___ _ gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60 == Lowr ~10_" __ --..I T = 2V/Q = I :f{~y 4 ' .. -<-.1 Number of casing volumes evacuated (if other than two) If well evacuated to dryness, number of gallons evacuated 1···.·:·',1 1::1 .,.] Name of Certified Analytica1 Laboratory if Other Than Energy Labfl..:·;....".:;..:,<l,:.:.;~;;.....,:·_:, '_" ~. ';"".' _'''';"".' ___ ;--0'. I Type of Sample Sample Vol (indicate Sample Taken if other than as specified below) Filtered Preservative Added If preservative is used, specify Type and Quantity of Preservative: See instruction' ;Comnlent . (Do not touch this cell (SheetName) ~--------------~~ White Mesa Mill Fie!d Data Worksheet for Groundwater M.iII • Groundwater Discharge Permit (r',\ Groundwater Monitoring Quality Assurance Plan (QAP) \.,--.,,' (~) Date: 03/22/2010 Rev. 6 j' .. ,' j ATTACHMENT J 'f)EN'SO.1l.' . .j "'HITE l\JESA URANIUl\Il\ULL Attachment I : ~~ S' . ",.($.": et: llli;tructmn ".:~~-..;,;~ FIELD DATA \VORKSHEET FOR GROUND WATER Des~ription ofSa~pling Event: I \..1~· Q \ho.r1-Gr N ~~f"~t~ ~Ol\ Sampler Name Location (wel1 name):l -rwAJ-):;l,. . I and initials: Date and Time for Purgin~\o/J1 /;J.JJ1\ .1 and Sampling (if different) ., Well Purging Equip Used: [![]pump or@] bailer WeB Pump (if other than Bennet) .1 Sampling Event f Qv.o.rts;rlv, /\J )\t,.;,,~ Prevo Well Sampled in Sampling Event r...;.1:_-r.;..;.; ... ~;....' _:A)_' ...... :1_': __ ";"';"_...:.J! pH Buffer 7.0 1-1 -.;' ._.7_,o __ --',1 Specific Conductance,-l~q.;.-q"_·_--...;.._....aIJlMl-rOS/ em Depth to Water Before Purgin~ .. 30 .~o ," ,I Conductance (avg) ,-1<_'.2.;..;.8..l.,;" ~=~=,_ .. ___ ~: I pH Buffer 4.0 1.4.0 .. .", Well Depth(O.Olft): lilo .oD. ". '" Casing Volume (V) 4" well:1 51.~j "1(.653h) 3ft Well:. .,0 :' "',::.(.367h) pH of Water (avg) Well Water Temp. (avg) I ·}t..\·~ 1.' Redox Potential (Eh)L..;1 ~~lH..:..._---, Turbidityl . ;.37: ", ,·1 Weather Condo I ,.'.~~~~."""." ... .' '." . ,,1., . Exfl Amb. Temp. cC (prior sampling event)Fr7ll . ;,·1 Conductance 1'.·~1j:i·~·_~·~~J pH 16:'<1 g ':'; J Conductance I :~ 14 '1"' .. ~ ''-:;:'1 pH ( 7.:00'.' " " .. -, Temp. ~C 1 '.I '1 ·S7 . I Temp.oC 1 14-~i ::.; ..... ] Redox Potential Eh (m V) 0.....;1 i:o:..-;...::r?..,---~_ Redox Potential Eh (m V) ..,;;1' ::z..;.;..;.. \....;i.i'---_ ...... I Turbidity (NTU) Turbidity (NTU) Time t~\.5_l1 __ --, Gal. Purged 1_, t_IO_' --,,_'_ ., .. ' :---.".1 Gal. Purged a...;.1 j ........... 0 __ _____ Conductance I ;1... ',,Usc . ., :1 Conductance I ~4 ,1· . ··1 pH I ,. Q;.l. I P1.!>1 Temp.eC Redox Potential Eh (m V) Ia-~_l ..... 'i,---__ Redox Potentia) Eh (mY) IL....:~~).(. __ -' Turbidity (NTU) I ):yo ,0 . Turbidity (NTU) 11t.jO.O White Mesa Mill Field Data Worksheet for Groundwater l\1ill -Groundwater Discharge Permit ("J Groundwater Monitoring Quality Assurance Plan (QAP) . '" Date: 03/22/2010 Rev. 6 Volume of Water Purged """I..JolP:r:;..;.;;;.tD ___ ---a gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. SJ60 = . c.-( ............ )0 ...... ' __ ...... Time to evacuate two casing volumes (2V) T = 2V/Q = I 10-3" I Number of casing volumes evacuated (if olher than two) If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labfr...-.'~...;.I ...... A...;.' _____ -....1 Type ofSamp]e VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) ~Conllllent Sample Vol (indicate Sample Taken if other than as Y N specified below) Preservative Filtered Preservative Added Y N Type Y N If preservative is used, specify Type and Quantity 0 f Preservative: ~~~ See instruction . .. . ,..., ,,',', "'" " '. . Arf~\letl on .sl+~ ~tll.l-'5b. ~nri-!(' Ana fro-U ;"" rre~c:{"\t +'or r~~'rt\e ~tl ~'(A~ P~~-;;1 'e\Jt"~t P\'\;~e be~C\I"I, ~t l!:>DO . P~("~e~ \NeJ\ ~r 0\.' -tOo"hAl :~ \A M't/)v..tt.S. ~J-er tl..+ ~ ·~r of r~r~c ~~ ~. ().Ii'r~ o("o..(\~e.. .C.()\Of. S\o~~.-c..\eQ.re~ -t)'rO,;\hO\lt1-h£., f\l.~C, \J..)~4-tr ,n'~c:(': to~'~ 61cW~J.. ?"'r~<:<!l1tlt:A ttIIJ .sc.m p k..> ""er<:. co/lcJtd tAt 13/9... 1.51a .1J-e.rTh -Jc:, V)"tc!r o.:t1~(' rv..('~e. \A)~ 'tZ ."i3 l.e~ ti i'te. (A.} \5aD . S~r\~J,. ha.~~ A ~~ ~1','-k.1 (<:tl Po..r~;G\~~ ~b(;"~\~ . (A. (oU-r\A, . 1-_______ --IIDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater MilH· Groundwater Discharge Permit Date: 03/2212010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) t • i A IT ACH~'lENT 1 Attachment 1 ; OENaSOn .· .J "rHITE iMESA URANIUM MILL "~,*'j1:-~Y!'A~-1 FIELD DATA \VORKSHEET FOR GROUND 'VATER . ~ -'."d: ';c..'f~ Sec instruction Description of Sampling Event: I yl'h Q V-{.l("t~r ·..AJ i~+~~""e ;l.c II Sampler Name Location (well name):1 ::i:YJ N -l~ and initials: Date and Time for Purgin~ loir7/~o'\I , • Well Purging Equip Used: IT!] pump o@ bailer pH Buffer 7.0 r· 7.0 ' .. :,' .' :.1 Specific Conductnneel~' _' ...L4..&.q~...;..· ______ · ...... I~MIIOSl em Depth to Water Before Purgin~-Yk>,'?-'I : .... _ and Sampling (if different) , .N/b Wen Pump (if other than Bennet) Prey. Well Sampled in Sampling Event I · ~wi0-.t;5 pH Buffer 4_0 I Well Dcpth(O.Olft): I \:2.6:00 .' Casing Volume (V) 4't well:I .~~ .... JJ ..... ,.,,::, .·,(.653h.) 3" Wel1:_:: d ·'·:', , ... ' J.367h) Conductance (avg) L-, . .....l]uc;.B;..;;;..-~....c."''''-,. ...... '. ___ ·-..;.~_·"·'-,·I pH of Water (avg) 1 .... ··...;..1-=~!i;;;..;:&='-· ........ -.~ ___ .....;;-' ____ .. _~ .... Well Water Temp. (avg)I· ,q'" bol ·: .. :-. I Redox Potential (Eh)Ei[~~~:~-:'l Turbidityl::J.l ·,'·8'a . ' : I ] 1 Weather Condo Ext'l Amb. Temp~ CtC (prior sampling event)I .. '9~ ,,:.q Time IOCiOi . ".:': I Conductance Temp.oC [i~3;g' ,'._u:,,] f ]t.i [b!i :.'.'] Redox Potential Eh (m V) I ,:105 : Turbidity (NTU) pH I"-r '57':"·.:' I Time I OCiDS ' Ga1. Purged I 'joe ' I Conductance t :~:i:l.;;l.1·· ·1 pH I 7,5 ~ ',< . ", I Temp.oC Redox Potential Eh (mV) I ~1:) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Conductance I-.;·I:iiq··' .::·:·.::::l Temp.oC [JY:'·Z:-. :J Redox Potential Eh (mY) I. :100. Turbidity (NTU) I ~1 ,<'1 .,: . ,I Time IO~Jb ' Gal. Purged """,l"':.;..p..;;;...(j_' _...0....&' I Conductance Temp.oC I·)~. I 1 .. t:L_4'~:,:: __ ·"LJ Redox Potential Eh (m V) I :;l.r-j(;l.. Turbidity (NTU) ~ 1 of2 capturx' (OM ~AT'8l£ WITIi/,-w~'rr-ruHCT'OHAlITY Mill· Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged _I ~J:...;..IQ= ••. ___ -' gallon{s} Pumping Rate Calculation Flow Rate (Q), in gpm. Si60 = II-o-"lu...b""--__ ---' Time to evacuate two casing volumes (2V) T=2V/Q= I '1.b~. I Number of casing volumes evacuated (if other than two) 1a.....~ ____ ---iI If well evacuated to dryness, number of gallons evacuated Ia....· ___ .--..I Name of Certified Analytical Laboratory if Other Than Energy Lab~""""";V:~··~I.;;;J.A __ "':"-__ ~--I.1 Type of Samp1e VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) " ~Comment Sample Vol (indicate Sample Taken if other than as Filtered Y N specified below) Y N Preservative Type Preservative Added Y N If preservative is used, speedy Type and Quantity of Prescrvatiye: t-;'71 See instruction ~~ ......... _______ ..........a1no not touch this cell (Sheet Name) White Mesa Mill Field Data Worksheet for Groundwater A 20f2 capturx· COMPATIBLE WITH ... ..-"Ll' ... ""ti;--FlJNCtION ... I.ITY Mill • Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (O,AP) Attachment 1 ~. ft · f A TT ACHl\fENT I l OENISO.r.", .! \VHITE l\fESA URANIUM MILL ~~~r_~!~+'!~' .-=" .... ""..,.,..1 FIELD DATA "'ORKSHEET FOR GROUND \VA TER Description of Sump ling Event: I t...\,1h Qu.Ar+er N :1-r",+~ :lOU i<.'.(~! See instruction Location (wen name ): ..... 1 -.:ji:..,.;:W:..;;..;...;;~;...-~Jl-q..t...--_______ -"" Sampler Name and initials: I -r:M1c..f Hoj\;d,4.jhH: Date and Time for Purgin~ \O/l~ 1.2P\ I and Sampling (if different) OQL]9L1Qll , '=L~ ~] Well Purging Equip Used: (][Jpump o@ bailer I I& .. n.l£,~ ~ Well Pump (if other than Bennet) >< Sampling Event Qv.p£+Cr14 N rt("~t~ Prey . We II Sampled in Sampling Event I, -r vJN-1 c; pH Buffer 7.0 ~.o pH Buffer 4.0 ·'-\'.0 Specific Conductance .... 1 -Iq .... 1-t~-·. ___ ;_IJ-lMHOSl em WelJ Depth(O.Olft): I )35~oo.. . . I Depth to Water Before Purgin~ .b:l. .'61 Casing Volume (V) 4" Wen:. 47; (.653h) ~ ......... ~ ......... """ 3" Wen:' ___ c~:.__ . (.367h) pH of Water (avg) 7 '·5k·."'. I Conductance (avg) I . '." 10'1 (. , Well Water Temp. (avg) I ·lS:.l~ Redox Potential (Eh) I ,;L70., ',I Turbidityl lib .~· . f I Weather Condo ~I __ S_'~_·':_J) ..... ~_:· .. _ •.••• _ ......... ,_._ . .;... .. _.' .. ___ ~ Ext'l Amb. Temp. O( (prior sampling event)1 }~!) '. I Time I )~~.f)=:=J Gal. Purged 1.55 " .... ',1 Time Gal. Purgedr '-___ -'.: I Conductance I.-1·....,;.i...;;.,o ...LCi..&-1 _----II Conductance pH &0....1 __ ----' Temp. (:'C Temp.oC 1 Redox Potential Eh (mV) I 276 .. ] Redox Potentia.1 ~h (mV) 1"-___ ·_1 Turbidity (NTU) Turbidity (NTU) L I Time Gal. Purged ,-I ___ -' Time GaL Purged 1 ____ ----1 Conductance pH,-I ___ --, Conductance 1-1 ___ _ pH 11-___ _ Temp.oC __ 1 ___ _ Redox Potential Eh (m V) 1"'-___ _ Redox Potential Eh (mY) 1 .... ___ _ Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater M~U -Groundwater Discharge Permit ' ~) Date: 03/22/2010 Rev. 6 Groundwater Monitoring Qualitv Assurance Plan (QAP) Volume of Water Purgedl L-_p_:'7'--' __ __ gallon(s) Pumping Rate Calculation Flow Rate (Q) .. in gpm. Time to evacuate two casing volumes (2V) .. S/60 = 1-01 _11o:0 _____ --..J T=2V/Q= 1'1 ,42. I N umber of casing volumes evacuated (if other than two) I LIL If weB evacuated to dryness, number of gallons evacuated 157 Name of Certified Analytical Laboratory jfOther Than Energy Lab~,-____ .M_'/. .... p, _____ -.I Type of Sample S I Tak Sample Vol (indicate amp e en if other than as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Sf,"iiJ.,.:.';V.; "'~:':'~;i' SamPle v()lume _ ._ -',0,,:' Filtered Y N , ~:':'; :6~'i' ::,: :;':'.:\fr~i :~:._;~,:~ ;.i _ .. ~;' .• t..,' ~,~/:\/, -' ..•. Preservat i ve Type Preservative Added Y N If preservative is used, specifY Type and Quantity of Prescrvati,'e: ~Comment :"4 See instruction , i"'t<tj~ Atri~d on $*c..:l-1335,'-':11118 ,,,,,lG.-rr," r.scA +~ F'-'~c: "n,'N-I'I, f",~", 1:.~"II ... t 1340 I'~eo. lI;)ell t.,..," -\-':>-\-0.1 . ~ !S rn ;l)lAt~a."d l-\::t SeLcnei5.. P~r,:r~ cue" dr~ I, W.,,:to' i h~~ ~ s \ ~"'} al~(.o~()r to tt. Pu.r~c end~ o...+)34b . Le1f Sire <itt 13YCJ. Itrrt\)e.! tin ~;+(. ~~ , Ob'3a, -r"-,,nc.r ~nGl 6-c!(l"I'f\ fr(.,~\!."+ -\-0 c.e.Uec.+ s"qmr'es.., Dc::.~i7\ to wC\fer u1C\$ b3.3D SO\)t}~\(s. ~e.fe. b'\~\e.~".:t Ob36. l~~\-..s\t~ ~t C~40 '---__________ fDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater " " , Mill ~ Groundwater Discharge Permit {~, , J --. ..,,-' () Date: 03(22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (O,AP) ~ ... . ft \ ATTACHMENT 1 J llENISOtr ~_ ~ \VHITE l''1ESA URANIUM MILL Attachment I '\~ Sec instru~tion ·'~~!....:~~......."l FIELD DATA WORKSHEET FOR GROUND 'VATER Description of Sampling Event: I \..\Tk Qv.."'-rter N ,'4-("0.+' ;2.0 1\ : I Location (well name) :1 ..... ""f~w;;..;..;.:}J:...-....:1.5=-_""'""-___ ..;...;.......;.;..... __ : --II Sampler Name ...... ... .. " and initials: j':~G~~~~:·)i;J.liJ~~:l1:lf.=~ -~ ~ Date and Time for Purgin~ . \OII$IJl.ol i ' .] and Sampling (if different) .. 1 Wen Purging Equip Used:~pump or@] bailer Well Pump (if other than Bennet) ] Sampling Event I Q\t.Mrtcrl:1 .1> .:.r-r~ +, Prevo Well Sampled in Sampling Event I .... ~_._w_:.·~_' _~~_. '_. _. __ ""';'-'---.11 pH Buffer 7.0 I '.i TO -." .... : I Specific Conductance!_q'fi..a..'· q ...... q"--_...o..-~. I JlMHOSl em Conductance (avg) _I _:_. ·. __ l;~-.·(:k __ ' ,;;..' _~,: ____ -,' I pH Buffer 4.0 Well Dcpth(O.Olft): ,. 15,5.0(} '. :·1 Casing Volume (V) 4" wellll.\ I ,CO •... 'IC.653h) 3rt Well:.' 0 ',' '-, -" .(.367h) pH of Water (avg) '-0.1 ....... _: ' __ "_~q_~_" . .0.--__ ._, ........ I Well Water Temp. (avg) [E'-~~'-,--=:J Redox Potential (Eh)r 3i.7 ' .. ::.:-" I Turbidityr .ti:, ., Weather Condo I ~;;,~cf';;,t ~~~)'~:' .. "".'\j Ext'l Amb. Temp. ·C (prior samplingeventll12t <1 Time I,) 661 \.1 Conductance (1'30" ., .. -I Temp. "'C Redox Potential Eh (m V) I. 52" . I Turbidity (NTU) Time Conductance Temp.oC .1 Gal. Purged 1-1 __ : ..--~___'.I pH &.....1 ' __ -oJ1 Redox Potential Eh (m V) l ___ -'" Turbidity (NTU) Gal. Purged _I ___ ,:::,_., ..... Conductance I &...,_...;,_,,; _":"_""-11 Temp.oC I Redox Potential Eh (m V) 1'-'...;;. ... : _' . ______ -1.1 Turbidity (N11J) I ·1 Time I ," ',,,1 Gal. Purged ..... 1 __ .....;... ....... ·1 Conductance I .... , ___ ---' pH Lo-I __ --..1 Temp. °c 1 ______ ..... Redox Potential Eh (m V) 1'-___ --..1 Turbidity (NTU) Whit~ Mesa Mill Field Data Worksheet for Groundwater ,A 10f2 , capturx' COMPATIBLE WI.TIi~w:.t:·rir-FIJN (T!ONAlITV , MiII-Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP~ '" Volume of Water Purged JL.....::;b;.;:::;~O:::;....-' ___ ...t gallon(s} Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/GO = ,-I _l:..;::;;D ___ -J T=2V/Q= I ~.~ I Number of casing volumes evacuated (if other than two) IfweH evacuated to dryness, number of gallons evacuated I '-,0 Name of Certified Analytical Laboratory if Other Than Energy Lab~ NIp. , Type of Sample SIT k SampJe Vol (indicate amp e a en if other than as Filtered Y N specified below) Y N VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) ~'~:'.'.~. '·':t{~::,:·,}; Sampl~ volume '-" ;':.\.~.,~'~;-:':;?' .' Preservative Type Preservative Added Y N '.:~ ':';:5 ,,',} >",., ~":~.;,": ~:. ,.,':; .;''-, . If preselvati"e is used, specify Type and Quantity of Prescrvu tive: SComnlcnt ;.J See instruction < A<6,,~A O~ &:-\-<. <>.t 0<1;0;;"1 '''''~<r, &wr;n I ~ .. o • .1\ f~!.c".\. +0 ?v.r~~ .,.W.-) -IS. < Ft .. r,5e. b<'j"" ... + i 061. fv.r~Gcl. ,-,,,II ~ 4.. }O+,,1 of " M;n.itt$, P"r~.J 10)<;11 cl.rjl ~,,+,r h.d.. sl;~~~di~cal.r -+4 it b"-t-,.,,a~.fIJ C l(.II\.I", P v."~( en4eJ. ~t IOD7. L~·n·. s ~.+< Gt1-\Ol~.' , A(f;~~a. On .s;+e A.+ Of,.~.~n"u ;"a ' (;..""('/'1\ prc!i.c?"+ "To (blle(J ·.s~mfJ("s." D e.p+J... ·oft;; ~Cc.+l",r tt.J~j , q~ .~:t ~6,.m pl~~ were. b'!\.\I~A a.. 1--0 b:;t8'. Le~ s;tt' tl\+ 06.:S0 L '--_______ -""IDo not touch this cel1 (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Mill • Groundwater Discharge Permit ,r ,..,-") Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan rOAP} A TT ACH1\IENT 1 IO,Nlso,}):A; '. i \VHITE J\lESA URANIU~" l\HLL Attachment 1 ,:~;{~ See im;tmctioll ·'it_¥..w~!.,.,,, .... __ ~l FIELD DATA WORKSHEET FOR GROUND \VATER Desc'ription ofSmnpIing Event: I L,..\T~ O"'{.I..r+er AJ ,~r,,+e.. ;tOll Location (well name): ..... 1 _-__ I w.;;.....;..Al __ -...;.tk~ _______ ----' Date and Time for Purgin~ \'o!l g/flC>iJ WeI) Purging Equip Used:lJ[)pump o@ bailer pH Buffer 7.0 /.D Specific Conductance 1~:lL...l1I-1oq_' ,_' ---.;. __ ---.11." MHOSl em Depth to Water Before Purgin~l..J .~ ~ to. " " Conductance (avg) _1....ll ..... 1-...14'""--_____ , _" _ . ..o.--~! I and Sampling (if different) ~I N_/ .... 4_·, _____ ---'" Well Pump (if other than Bennet) lk:v., .... t1 ..... d .... · f< ..... O....J....;.-.....-._--..J Prevo Well Sampled in Sampling Event I"----_I _~_AJ_'_-_I_O ____ .....;......I pH Buffer 4.0 . 4 ... u, , Well Dcpth(O.Olft): I' \'c>6"o~ =:J Casing Volume (V) 4" well:I ~3<~q . ·1<·653h) 3" Well:. ','0 ', ,. , '_ (.367h) pH of Water (avg) 1 ...... :..:..7 _.0_'3 ..... , ____ .0..-' ,-.... ·1 Well Water Temp. (avg) I' Ji(.'1Q." I Redox Potential (Eh) I ~c ,,' , Turbidity 1 ...... :...;;;.0 _" _ ......... -...' I Weather Condo ".",' Ext't Amb. Temp. "C (prior sampling event)I,: lb'!) ',I Time ~[jx __ 3_6 __ ,· _'_;" ....... :: I Gal. Purged [: 40 ' ',',·,1 Time ,,-,1"=:B:;;.!,l_-I· I Gal. Purged I 50',' 1 Conductance 'j pH f ·~1.6i ': " ':1 Conductance r UH;:: ":':1 pH [ 7,:'0 1.( . ' 'I Temp. gc Temp.oC I.IY -~ Redox Potential Eh (m V)I L. ..;;;.,:)_O....;7~_ ...... Redox Potential Eh (mV) I ::SOb " Turbidity eNTU) -'0 Turbidity (NTU) I 0 ' -. t Time 1 • .2.~ Gal. Purged 1...1 ;::::;b;..;;;O;.... __ .... Time 1);63:2 GaL Purged ,-17;;...;:O~_-.I Conductance 1 1T11 pH I 7 .0,3 .1 Conductance ..... 11A..;7..;;;bh;.,;;.' __ '-" pH 17 .01 ,I Temp.oC Temp.oC Redox Potential Eh (mV) I ~b Redox Potential Eh (mV) _I Jc.-.,..,;D.5::1:1111....-_ ..... Turbidity (NTU) o Turbidity (NTU) o White Mesa Mill field Data Worksheet for Groundwater A lof2 capturx' (OMPATlelE WITl~~# ... ""n:--fUNtTlON.AlI1'f Mit! • Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitonng Quality Assurance Plan {QAP) Volume of Water Purged '-1 ..... 7:...,..;0 ______ .... gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 1"---..,..;1 ..... 0 __ ----" Time to evacuate two casing volumes (2V) T=2V/Q= I &.'17 I Number of casing volumes evacuated (if other than two) If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labf __ ~tV_-/.;.,.A ______ ....... Type of Sample Sample Vol (indicate Sample Taken if other than as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Filtered y N ,:,;' .. ·.-.~·.:.;,.',D .... '.':~.·_~· .. (,'.>;~ ...... ~'~Z.~~ ..... :-_ ;r:~~·~'/:~:~:: ----.; .'''.-::.; :-.. :;~:" (:< ... Preservative Type Prcservati ve Added Y N Ifpreservative is used, specify Type and Quantity of Preservative: ~ ,::.,..p See instruction ~Comment '--_______ ----IIDo not touch this cell (SheetName) White Mesa Mill field Data Worksheet for Groundwater MifI.'Groundwater Discharge Permit C-) Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) ,,' I • -• • A TT ACH1\fENT 1 j OENISO,}),A J! WHITE MESA URANIUM MILL .~ ..... M}l'...!$ ... , ,·,~l FIELD DATA \VORKSHEET FOR GROUND \VATER Attachment I ~',i~ SI;.'e instrul!tion Description of Sampling Event: I l.{Th Q",'~ (1-Cf' N l1-r"t c. ~o I I Location {well name):I&-:!..!... ~Wt.;IJ-=--"' ..... 'l,--________ -.a: Sampler Name and initials: l -rA.tlt1~r HoiJ.'J":!1/1"'It · Date and Time for Purgin~ \ ollql ::to I} and Sampling (if different) Well Purging Equip Used:OOpump o@ bailer Well Pump (if other than Bennet) J I" -rvJN, ~l1 ~ ·1 Prevo Well Sampled in Sampling Event 1,;..' _____ --:..._~_---I, pH Buffer 7.0 ,-I _J-:. .. _O-:'-~---iI' I pH Buffer 4.0 I ' q , 0 ··1 Specific ConductaneeL..l· _' q..:...~.;....9_, ___ -,tJ.1MHOSI em Well Depth(O.Olft): I.,J lO,:O.P'. Depth to Water Before PurgingJ':3'-{'lD ' .. J .; I Casing Volwne (V) 4" well:1 '""'t5h ·I(·653h) 311 Well:;:.'O ;' ::~:'.\,.::. (.367h) Conductance (avg) [".:. :' ~)114~'': '". ":. ,. pH of Water (avg) Redox Potential (Eh) I 34~,' ·1 Weather Condo I'-'. ')'" :" '., ,,' :'. ',: .... '. "1 (;; e.CA.r· " . _ ,.' , .. " . : . . • • ...~ ~. .': 7 ~ • • '. ,-. ' _ '. ~ ''''' Conductance I. 1.1 ,.4 ·3 ·,u~:.·1 pH 1::1.50 '·' :J Redox Potential Eh (mV) a..;.1.3:;;::,,1.,.L;;'.3::........;...;......J Turbidity (NTU) 1 .(;0 .0"" Time Gal. Purged L..l,_· ___ -"',1 Conductance ,-I ;,..' ___ -t' J pH r-I _. ___ .",_1 Temp.oC I Redox Potential Eh (m V) L..I ___ --' Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. DC (prior sampling event)( . 5 c . ·1 Time L;.I.'-.:-~·~· ...:--...... , GaI.' Purged I Conductance I: -:' ,;,\'" :.~:. ·1 '.;.'. ,::1 pHL &,,;...:....;.... ~ •• ....;...' ....... : 'J Temp.oC Redox Potential Eh (mV)C L.....;... .. _. ~_'-I'I Turbidity (NTU) I Time .... I_..;...;.._--J Gal. Purged 1-1 _____ ....... I Conductance pH ,-I ~ __ -.! Temp.oC Redox Potential Eh (m V) 1...1 . __ -..;.......,J Turbidity (NTU) I ~ 10f2 capturx' COMPATI8U WITH/""U'~.:·~FUHCTlO"' ... LITY Mill -~Groundwater Discharge Permit 0 Groundwater Monitoring Quality Assurance Plan (QAP) -~ o Date: 03/22/2010 Rev. 6 .fl Volume of Water Purged 1i.-.¥6....;g~ __ ...., gallon(s) Pumping Rate Calculation Flow Rate (Q)~ in gpm~ S/60::: 1",-' ----.\ 0 ..... ·· . __ ---...I Time to evacuate two casing volumes (2V) T = 2V IQ = I q A ! I Number of casing volumes evacuated (if other than two) 1 1:31. If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labf,......;'N;,...· .;..,;ift;...,;· .••• ~~_---.;_...;...;--a Type of Sample Sample Vol (indicate Sample Taken ifother than as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (sped fy) Filtered Y N Preservative Type Preservative Added Y N If preservative is used. specify Type and Quantity of Preservative: t! ~ See il1struction ~Commcnt . Ari\\1c'don' Sft<:·. f\t .. Oijb _~~(l-tr' l.\na .·~·frlf\_ rr~.s~l\r +()'?\.A_("~<. TvJN-·~?_ ?\A'~~~. t)~i;i1 : ~r ·~./qg.. ... \ ~W'~~,~vJ.dl ·.fb ... ~.+D~1 *J·:~~.;,~ttes.· WjA lSD .. .s~onls Pu.t~etl _weU rA~t . ...v,,--h-r ~(A~'~"'~i'~~+, J;~~}~r h .i1.· P~f'~(! fr1J.el &\1 6! .. ~.q :.:l:~:~~~ ~t 07Q ............ . _'. . . . . Arr;\)¢A on ~;te.· ~+-qb5fS . ~tiV\-tr "~'A~ &,,-ri-'t'\ .?t'~~c.n+ +~ ,co\\e(t .~(AMples.~ Jc;pTh:+-O U)(At~/ \N~ 35,?J). >G\rt\p\e-.S :~e('ib~;\ca~ A,+ C70.1;~· \..~.V1-.s\-h: Rt 07(0 "-_______ ---'IDo not touch tJlis cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Mill • Groundwater Discharge Permit 0 Oate: 03/22/2010 Rev. 6 Groundwater Monitoring Qualitv Assurance Plan (QAP) ~ ft Ai j ~OENISO~"'. ;1 ,~;A MINES . J! ATTACHl\-IENT I \VHITE l\fESA URANIUM MILL FIELD DATA \VORKSHEET FOR GROUND \V A TER Attachment 1 ¥#4,...-~_.bOY;"'~",,~~' Description of Sampling Event: I ~"'h Q",,,,-(-tir iJ ;i-f'I\T<. bl..O II ., Sampler Name r-::::=: ' '. . .... . :-__ ~ Location (well name):I -rWN -11 B and initials: ~Y\~~ .. ijolFJ~LT1L--J Date and Ti me for Purgin~ 1 b Il~ I ()...o, I . and Sampling (if different) Well Purging Equip Used:OOpump o@ bailer Well Pump (if other than Bennet) .1 Prev. Well Sampled in Sampling Event 11W.v-I'l , . J pH Buffer 4.0 Specific Conductance[f\~4 " .' ,. IIlMHOSl em Wen Depth(O.Olft):t a...-_·D-.;.··. __ .....:..--..I.I Depth to Water Before Purginm ' " Ci-. ", I Casing Volume (V) 4" well:1 "0 ... . >1«·,6 36 53 7 h h )) 31t Wel1::0 ' _ ',." '1 Conductance (avg) k,~: :.:{.';rr Cj '.:;~:.:' ;,~: .. Well Water Temp, (avg) 1,Ib ,gq't-,_ .. :;,· Redox Potential (Eh)IS,g ':',~ .' .. , Turbidityi-I ~;o..;;.' :_,7_· ---..-.1 Weather Condo I '~\ec.i:.\-,?:,,\ Time r -O~i·I~·'-.-,>·1 Gal. Purged 1:\z ·O'::··.·;·<,,'I Conductance I·' 0 ;4 .:' :-' '-" pH r ',1~'~" ';:'1 Redox Potential Eh (mV) 13/F5 ,'.' Turbidity (NTU) I ~:7. Time ., GaL Purged 1""--_____ ---' Conductance pH ,-I ---:.. __ .... Temp.oC ,:J Redox Potential Eh (mV) .... 1 ___ _ Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater Ext'l Amb. Temp. °C (prior sampling event}I 'L'~ . Time I ." ..........',;1 Gal. Purged LC::": .. , Conductance f :, ":". i' ~ " .. :'1 pH ..... 1· .. ..;.,;-. .. ' .. _ .. _. '-..1"'1 Temp.oC 1\ , .,' . ·1 Redox Potential Eh (mV) ..... 1 .. _: .. _.:....---..-a Turbidity (NTU) Time .... 1._, ___ .... .1 Gal. Purged' ..... __ -'-';'--.1 Conductance pH 1,--____ --'·1 Temp,oC Redox Potential Eh (m V) ..... 1 ___ --' Turbidity (NTU) Mil' -Groundwater Discharge Permit i:· ... J;) Groundwater Monitoring Quafity Assurance Plan (QAP) ~ C) Date: 03/22/2010 Rev. 6 Volume of Water Purged .... 1_!l.._·_O_O ___ ..... gaUon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = II..-'--';"J. _0 __ --' Time to evacuate two casing volumes C2V) T =2V/Q= 1....0 I Number of casing volumes evacuated (if other than two) 'I If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy LabfL-·_.Al_1'_A ______ ---I1 Type of Sample VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) t: ~Comment Sample Vol (indicate Sample Taken if other than as Filtered Y N specified below) Y N Preservative Type Preservative Added Y N If preservative is used, specifY Type and Quantity of Preservative: ~tJ See instruction , ,'" ~ , ." ...... ,' ': .. A (rl\)·e!. 0"" ~~+C:' ~-t Ob5~ . ..,....C\~t\e(M~ (,..Go.((;~ 'p~,~icnt ~or r ~r\~~tc.;:· .. R;I\JG\:r~ bG~A" .. G\.t ",". 0700. rV.~?~ So G-OI.\\lm~ ftC!).. \..)6.~!rt $~ Cro.Ho~~ .So"f. '~:t«('l loo',' lrAllo't\:~ or '·p.+ 'Wq-tcl'.' . S"'M 'p\~: ~,cc<--.. GOPeaea 8\+' 0711 ':, L~+t' s~c.. o.....y ::·OI~~, f{~f'3o..t'" enal~ G\.t o1;i..6 '--_______ .... IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater ~\1i1l -Groundwater Discharge Permit "y' l \ '-, .,... Date: 03122/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 1 f .......... , .11 ATTACHMENT 1 ~ I \VHITE ~n;:SA URANIUM l\ULL [OENISO '\ ~,~t ... ~.!Jg~~!>!'I~~...J FIELD DATA WORKSHEET FOR GROUND 'VATER Dcscrlpti~n of Sampling Event: ), ~" Q~rt~r N :;+r~t~~brr .' Location (well name ):I .,.v.i,oJ ~ l~ ~~nf~~:~~rne [-1;11;;~ -H~jjfJ<~2j;{":J Date and Time for Purgin~ ..... "~'lO ..... j~H~:;.;.J.=~_o ... li_·· ___ '_"_'~---r Well Purging Equip Used: I fi): J pump o@ bailer SampJing Event I Q\Ao.c+cf"'1 V\ N 0,4('(,\.+c. pH Buffer 7.0 I' ,.: ,~l, 6 :,;', \'::1 Specific Conductancelr.....·_9..4.· ~.:..q;-.', _,,: _,·::·_·::_:._.>_ .... ,--'IJ-tMlIOS/ em Depth to Water Before Purgin~·.:.'·b1);t.5 '·,.~·~ I Weather Condo Conductance Temp.oC I ~ ~t ~~:;','.::-';:'.':,' I I .. f~:r,)H-,:.,', I Redox Potential Eh (mV) k.'3 b~ ".";,,: Turbidity (NTU) I· bO·t·:' ·;:,1 Time 1'"<' 1 tos .,: I ' GaL Purged 1~·l _IO_.'· : __ -' Conductance Temp.oC I "~\~"\:, ; 1 ·\4 ,~ '. Redox Potential Eh (mV) I :\~ . :.J Turbidity (NTU) I White Mesa Mill Field Data Worksheet for Groundwater and Sampling (if different) '.N/A Well Pump (if other than Bennet) Prev. WeB Sampled in Sampling Event I L.. _~r_w_';_~_.~_;;, _t_S_ ........ __ :_1 pH Buffer 4.0 If W 11~' .. ,'~','. (653h) 4 e: ;"" bG>r", . 3" Well: 'Jf?8:::·'r,>' ,~ (.367h) Casing Volume (V) pH of Water (avg) I ;.·,:·:b~':gD::'C-c'-:·}~;::?··,:: :"."(':~,.>':~; I Exfl Amb. Temp. °C (prior sampling 'eventlk\l;° ·,.'·1 Conductance I:::":i\a:f:'.··,~~:. I ' pH 1>:'":'81 ,:,,:':1 Temp.oC O~;'~~'.'::~:~~'~: I Redox Potential Eh (mV) I:,'},-~ '.,".:::'" Turbidity (NTU) Conductance I~);ltj ,: ", I Temp.oC O~::J Redox Potential Eh (mV) I ~4a Turbidity (NTU) I f.4·0 , Mill • Groundwater Discharge Permit Date~ 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (O,AP) Volume of Water Purged a...1-'\.....::Ao~ ___ ..... gallon(s} Pumping Rate Calculation Flow Rate (Q). in gpm. Time to evacuate two casing volumes (2V) S/60:;: I \0 T ;:; 2V/Q;;: I 11 ,3 b, I Number of casing volumes evacuated (if other than two) If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labl'-...;:..tJ,....;.;f.:t:,;:;"P. ______ ,...;...t.1 Sample Vol (indicate Sample Taken jf other than as Type of Sample Y . N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Comment Filtered y N Preservative Type Preservative Added Y N Ifpreservative is used, specifY Type and Quantity of Preservative: : :~ See instruction h~, , " '" , " , ,,' :.' ,', A ~f i .:lei). on !>;1-c ,,:1-. I04~. .,-"riM( M~ b-v.H i /I pre s~nt .\or \>U.'b-c' ;,;J,. SI.":' I'l;~ e~""t. p",r~<. b~o..t\ ~1 ,J05Y . P\A('~-G.\. wcll ,",oj It. --+0+4.\ 0+ \:l MlI'lV.+C::.s. ~(A.t~r hKd. (;. ~1.1~),+ 4'S'6~or t-() ,-r. PV.rer (,f'\o.eb.. ~"a. s.Ci.""?\<~ wtr<: LoHeLtet\ dJ HOb . T:kp~l, tt,'WlA+~' ~c..~ ;5g,4'1, Left S;+<.. ~r ,') l~ s-r" _______ -IIDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater ... " 1 r~ Mill • Groundwater Discharge Permit ~ .... ",) Date: 03/2.2/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) I . . i ATTACHMENT J I .1). I \VHITE J\IESA URANIUM lHILL Attachment 1 h,;ij Se~ instnlction ;J!~~~-""'I"Q~ j FIELD DATA 'VORKSHEET FOR GROUND \V A TER Description of Sampling Event: Iljlh Q\A(M'±er N~:tr(;\.te . ~Cil Location (well name):I .... -r...:-;;W __ IV_ .... ...;..I'i...;...-;.... _---___ ...... ,..,.,1 Sampler Name and initials: 11;!\I1~r-HolliJ;;J /rJt . Date and Time for Purgin~ .... · .;;..\ {) ....... /-..:l g;;...I.~3.tJ.---;,h _.....--. ___ --' Well Purging Equip Used:~pump o@ bailer pH Buffer 7.0 '7.0 Specific Conductance I -.. 999 .' . '::: :·.IJ.lMHOSl em Depth to Water Before Purgin~. ti·" Z-b' .' ' I and Sampling (if different) I tv/A .'. '1 Well Pump (if other than Bennet) r{t,£JI~~~a:~~ .:: :,:.h, -~ Prevo Well Sampled in Sampling Event I ~w-~ -Iii . pH Buffer 4.0 Well Depth(O.Olft): I J t O~DC ·.' ~J Casing Volume (V) 411 Well:. . '~':.~ ,·f·' (.653h) 3" Well: ',;;'. ·._~ . .' .. :.~.';i,:: (.367h) Well Water Temp. (avg) L.1S.l(Y:··'.: '~I Redox Potential (Eh) I' ~q~':~ .. ' ':1 Time Conductance Temp.oC GaL Purged tdiz::X'-':';. :'".:)1 ~D I '., t'\ll '" "1""'.1 pH ;". 7 ,.-4~"' .. :. ::"':.~ Redox Potential Eh (mV) I ,29t -'~ .• I Turbidity (NTU) Time I , iY51 . -I Gal. Purged ,-I-....:.1 ...... 0_· ..o.-.;.._.~: J Conductance I l j b(; I pH t 7 _?.(S .1 Temp. ""'c [:j'~-j6 ·1 Redox Potential Eh (m V)I .... -..;;;.·~..;...;.~_k_----,I Turbidity (NTU) <2. b . . I Ext'l Amb. Temp~ °C (prior sampling event) I ~;l'(,; ·~.:_I Temp.oC DS.lO.·,· .: .-1 Redox Potential Eh (mV) I. ,2q, .'. -',.:: I Turbidity (NTU) Time I lY3f$ . . ' .. I Gal. Purged I SCi: '-. I Conductance [.t:t,g:~ pH Ll?~A5:;'.-',.:·,::···1 Temp. ""C Redox Potential Eh (m V)I &,..; ~ ...... fi5...!:1011... __ ~ Turbidity (NTU) (, . .b, White Mesa Mill Fjeld Data Worksheet for Groundwater • Mill • Groundwater Discharge Permit Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (CAP) '" Volume of Water Purged 1 ..... ....;:sJ=-6::;..···· ___ --.I gaUon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 1"--"'l.¥.Q __ ----' Time to evacuate two casing volumes (2V) T =: 2V/Q= I, .. ~.b I Number of casing volumes evacuated (if other than two) IL.,.;'~ __ ---' If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Lab~ ........... iv."",",I A:....;..' _______ ] Type of Sample S I Tak Sample Vol (indicate ampe en . If other than as Y N specified below) VOCs Nutrients Heavy Metals AU Other Non Radiologies Gross Alpha Other (specify) Filtered Y N 'r:~~·p·,·::':':.?· ;;':::;7~:::-~;;~ '-.~. # •• ',. • • '.~.. :.; ... ~ Preservative Type Preservative Added Y N If preservative is used. specify Type and Quantity of Preservative: ~Comment • Atj See instruction L~7 Ars·;\)~a On ~ ,\1-l. CI\.+' Pi;2..b . ';'n()~r A.Oa &"((';'~ fl"'e.sc«t ~or ·fH.A~C o..n&\ Sct,..jpj~~ -t!.v(;n1 .. pl)...{'.jc!, b~Q..(\: 0..+ ll.\'3D. P\.\("-5e4. ~e.JI ..tor a.. -+u+C\l 0+ 8 M/'(lv-.t~..s. ux...tC( 1..)&\.5 C)ec..C" 1irth)~ho",t +ht. f\).r~c -P~r~<. (!n~1!'a ,~! ~tvVlFJt'S were ·l:.ollcc.t<!'~ 4+ IYJ8. Depth +0 ~+cr ~.f.tl'r pv-rjC wc.!:. 8'5. ''1 . Le.\=} S ;.)-c ,,} N43 '--_______ ~IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater .-........ Mill ·~Groundwater Discharge Permit ) Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QAP) i , ATTACHMENT 1 IOENISO ' , 'A: 'VHITE l\IESA URANIUM MILL Attachment I Sec instruction ,.t~L""..MJ!'''!! ....... __ ...... ...J FIELD DATA \VORKSHEET FOR GROUND 'VATER Description of Sampling Event: I Ljth Q """'r+~r IV i'+r~ +<. ;1.0 II Location (well name): .... 1 .....;,..;....W...;.· .;...N_-_b;;...O ________ __ Samp1er Name and initials: l-1-:.rll1er j.J~ JIJd"d/1"'+ Date and Time for Purgin~ lO/~q /~o II Well Purging Equip Used: [Q]pump o@ bailer Sampling Event I Q\Ab.('-tu J.;1 N 'fr,,-tc. pHBuffcr 7.0 ,,-I _/~.;..;;.O_· __ --, Specific Conductancct-I _'1~,:....:~ ___ ---'tJ.lMHOSl em Depth to Water Before PurgingJ .... _6~· __ -' Conductance (avg) and Sampling (if different) ,-1.N,_v._/.J...~ ______ --' Well Pump (if other than Bennel) t-I ~_Y'A.---____ -..II Prevo Well Sampled in Sampling Event .... r!_f>_I_· -t._z..._-'*_l ____ --' pH Buffer 4.0 4 .0 Well Dcpth(O.Olft): .... ( _0 ___ --'.1 Casing Volume (V) pH of Water (avg) 4" Well;~(.653h) 3" Well=~(,367h) Well Water Temp_ (avg) I \G\.-:>g Redox Potential (Eh)1 3 0 1 · '1 Turbidity .... 1 .... ;>.. .... i ____ ..... WeatherCOlld·1 .... _S_ ..... \A_"_t'\..;.1....;.· .. ...;.. __ ....;.... _____ ..... Ext'l Amb. Temp ... c (prior sampling event)l t9 () Time , I Gal. Purged .... L _-..:~,· .. II Time Gal. Purged L,--...;..· __ '....,,' I Conductance ..... 1 ...;'1_0 Ll...a...-_ ..... I Conductance ,-'._' ___ . -I' I pH ,"'-__ --' Temp. QC Tenlp.OC Redox Potential Eh (mV) ..... 1 3 ___ ,o~' __ J--, Redox Potential Eh (m V)[ '--_____ -'----' Turbidity (NTU) I :;I -I I Turbidity (NTU) I I Time I ..... · _:_. __ -"" Gal. Purged .... 1 ___ ....I Time _L __ ..,....,,::1 GaL Purged 1 ..... ___ ..... Conductance pH .... ' ___ ..... Conductance ..... L ___ ~·I pH1L... ___ ..... Temp.oC Temp.oC .... 1 ___ __ Redox Potential Eh (m V) 11..-1 ___ --' Redox Potential Eh (mV) r ____ ....... Turbidity (NTU) Turbidity (NTU) White Mesa Mill Field Data Worksheet for Groundwater A lof2 capturx' COMPATl9l£ WlTli,/"-W."'~FU"'(tlON ... lITY . . . Mill) Groundwater Discharge Permit ",r) Groundwater Monitoring Quality AsslJrance Plan (QAP} t Volume of Water Purged .... 1 __ (J_.' __ --"' Pumping Rate Calculation gallon{s) .' J , .. ) Date: 03/22/2010 Rev. 6 Flow Rate (Q)~ in gpm. S/60 = I'---_o __ ··~ __ -" Time to evacuate two casing volumes (2V) T == 2VlQ ~ I 0 I Number of casing volumes evacuated (if other than two) o If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if O~her Than Energy Labrl..._2~. !."-A ______ _ Iii' .. , Type of Sample VOCs Nutrients Heavy Metals AU Other Non Radiologies Gross Alpha Other (specify) ChioriJe } Comment Sample Vol (indicate Sample Taken if other than as Y N specified below) DI '--_______ ---'IDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater Filtered Y N Preservative Type Preservative Added Y N If preservative is used, speciiY Type and Quantity of Preservative: y. A See instruction L~ MHI-Groundwater Discharge Permit Oate: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QA?) 1·-. -r A TT ACHMENT I ~OENISO.})~( \VHITE l\IESA URANIUM MILL ':~~~lr~MfS_l~t~j FIELD DATA 'VORKSHEET FOR GROUND 'VATER Dcs~ription of Sampling Event: Ilj1'1\' Q\A~r+c(" N 1~+rC\..tt:. .20 ~l Attachment 1 ~:(). Sc;:c il1slnl(;tion . I Location (well name):I ____ ·"_W_N_:.;.._'_O ________ --' Sampler Name and initials: L:riWn.e.LH-;;ll/J;~LIli __ Date and Time for Purgin~' \b 1 11 /;;i.D, 1" .; ·1 and Sampling (if different) Well Purging Equip Used:I:BI Ipump o@ bailer Well Pump (if other than Bennet) Prey. Well Sampled in Sampling Event I '-f~;';c\"fl\ ',] pH Buffer 7.0 1 ','77'~ 0 : .. :.:::. :.' ' I pH Bufi'er4.0 Specific ConductanceLqq.q ':.. '. :·'IJ.lMHOSf em Well Depth(O.OI ft): 1 :·\lO~oO. :.:: <I Depth to Water Before Purgin~ 0\ .. LlO·:.-:· Casing Volunle (V) 4:: wel!~I '~} ;ff "T653hl 3 Well. .... ":; o · I .:' . (.367h) Conductance (avg) pH of Water (avg) Well Water Temp. (avg) h·l~'·.3q :·' :.,:1 Redox Potential (Eh) .. ~,' 'ft ,:: ~~ ................... '"'" ExfJ Amb. Temp. °C (prior sampling event)1 "5~ •. I Time I ,.\~:~:~/\~5·~)·~:·>.,~~1 ., . Conductance . ~.'r:::f-~il'>'.L~~,~::~<:;-.. n:;.< I Conductance Temp. ~C Temp. ~C I::: co: ... . ····1 Redox Potential Eh (m V) I, ·.~~';;~1~· ,,':y' ~'i ' ,I Redox Potential Eh (m V) ..... 1· ___ "'--': 1 Turbidity eNTU) Turbidity (NTU) L> :, I Time Gal. Purged I,;,.,L-'-_.f, ................ '.--. ........ , Time I";,.,·""': '" .... I -':". Gal. Purged ..... 1 ·_·, __ ·_,··· ..... :1 Conductance , .. ; I pH I Conductance ,L... .. _. ___ ...... pH ..... ,. ___ ..... Temp.oC 1-, . ·1 Temp.oC 11-·· ___ ..-.1 Redox Potential Eh (mV) _I ___ _ Redox Potentia) Eh (mV) IL--__ --I: I Turbidity (NTU) Turbidity (NTU) [ White Mesa Mill Field Data Worksheet for Groundwater Mill -Groundwater Discharge Permit ~~'''') ,¢~, I ~ Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan (QA?) Volume of Water Purged I~h_~·g"""··' ___ ---a gallon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = 1--1 -..::.".=.-D __ ---' Time to evacuate two casing volumes (2V) T == 2VlQ ~ I q .9 ( I Number of casing volumes evacuated (if other than two) 1},31 If well evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labfa......:;..N ...... I...;..ii ...... · _______ 1 Type of Sample Sample Vol (indicate Sample Taken if other than as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) ,., ~Comnlent .' _________ ..."IDo not touch this cell (SheetNamc) Whrte Mesa Mill Field Data Worksneetfor Groundwater Filtered Y N Preservative Type Preservative Added Y N Ifpreservative is used, specifY Type and Quantity of Preservative: ~ See instruction ./f 2 of 2 . capt ur x' C:O",PATl8Lf WI .. J'H,./'-"W~&'W-F UN(TlONAllTY Mill. Groundwater Discharge Permit :~".~) Date: 03/22/2010 Rev. 6 Groundwater Monitoring Qualitv Assurance Plan (QAP} ~ j ATTACHMENT 1 Attachment 1 J~ OENISO!"",: , i \VHITEMESA URANIU:I\'1l\nLL ~.fi}1 Sec instruction "~~~!4~IO\$,~","....-J FIELD DATA \VORKSHEET FOR GROUND \VATER Description of Sampling Event: I I.-l-r~ Qv.o.r\cr .IV ;};~ t~..201 J 1 Sampler Name , ' '" " Location (well name):1 UJNL. P . and initials: [::I;,\J"t~~~; jil~}Cl~;Lm"""c~,: ~ ::] Date and Time for Purgin~a......:..;lD~/~f..:..'t ;...:.I;J.;.;;.b.....:l .. I ___ ..;.".-.;.......J Well Purging Equip Used: [gJpump 000 bailer Sampling Event I Qv..(Ar .. h~r k1 N;-tr(A.t c:. pH Buffer 7.0 1"';.0 . '. Specific Conductance .... 1 _.9 ..... q..:,.q.:-,·':· ________ ...... ' I flMHOSl em Depth to Water Before Purgin~'_·_', .... O __ . ______ ...... ] Conductance (avg) }-it .: .' '!'-: ,,'. '. ·····:;1 and Sampling (if different) &...1 ;M'--Vl}-.:....-· _~ ___ -' Well Pump (if other than BenneOI a..;. ~_~_~_.' ____ ..-J I f'~C'l:~:2 Prevo Well Sampled in Sampling Event L-...;...._....;;..;..~~ __ -' pH Buffer 4.0 .y.D '. Well Depth(O.Olft): r....l ~O_ .. ......;...._--'] Casing Volwne (V) 4" well:1 0 . I (.653h) 3" Well:.1-""!!' .• o ..... ·,-~, ,-t·(.367h) pH of Water (avg) 'Well Water Temp. (avg) I.' )~.'Io l Redox Potential (Eh)I.;~~g '.': I Turbidity-I : l:2 k. ' • Weather Cond. ,:,,' '~':': ' ... ~:',; , . . ' , .'," :', .1 " ~,~"~~.' ' .. :1:;. ' " ~'.:;': '.' '----~----~--~~~~~~ Ext'l Amb. Temp. °C (prior sampling event)l lK§ " "·1 Time I.l.?-S(:[ .. '~.' I GaL P'urged ...... 1.._., ____ ......... ,j Time _I' .... ' '.'_': _ ..... , .. _; ::'--,·1 Gal. Purged .... 1: . ...;..;,...-._ .... .......-..-~, I Conductance I 'f] l ', o.J pH L· fj'. 7'J !· . .' .j Conductance ,-I' ..;.....;0.._:., ,-:" ,._-__ ] pHI " '.' .' I Temp. :t.i'c 17,1 I) I Temp.oC Redox Potential Eh (m V) [ .. 2 .. 6S :':.:] Redox Potential Eh (rn V) II.,;..' _. ___ '--,1 Turbidity (NTU) Turbidity (NTU) I . , '. I Time .1 GaL Purged r....1" ___ ....I Time Gal. Purged I &... ___ ..... ] Conductance pH"",,,I __ ~'1 Conductance pHL-1. ___ ..... Temp .. oC ~I: __ ---, Temp.oC Redox Potential Eh (mV) IL-___ --J Redox Potential Eh (mV) ,-I ___ ~I Turbidity (NTU) Turbidity (NTU) ==:J White Mesa Mill field Data Worksheet for Groundwater < /~ Mill • Groundwater Discharge Permit ( ) Groundwater Monitoring Qualitv Assurance Plan (QAP) , •. ' Date: 03/2.2/2010 Rev. 6 Volume of Water Purged I '-_----=U"-" __ ___ gaJlon(s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes (2V) S/60= I 0 T = 2V/Q = I ' 0 I Number of casing volumes evacuated (if other than two) o I If weB evacuated to dryness, number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labf ... _· #_-_1._/.} _____ ----t"1 Type of Sample VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) ~ ~Comment Sample Vol (indicate SampJe Taken if other than as Filtered Y N speei fled below) Y N Preservati ve Type Preservative Added Y N If preservative is used, specify Type and Quantity of Preservative: ~"-",:~ See instruction i"d . Ar(i\led ".0(\ ~;fc::. cd-Ii.i;L_""f"A~ner o.n~~(~~" f(t'~(;'"nt ~ ·co'lJ~c+' SG(l'7rld,~~pJc~ ~~(c c..l>He,-teJ ~-+ )300. G-r~ "5~tnf}C5~~re '·f~u ... f,;'(~ej .. 'p\M:,~S o~. '}h~ fond. __________ .... IDo not touch this eel] (SheetName) WhIte Mesa Mill Field Data Worksheet for Groundwater Mill . Groundwater Discharge Permit C) Groundwater Monitoring Quality Assurance Ptan (CAP) (~) Date: 03/22/2010 Rev. 6 ATTACHMENT 1 \VHITE l\fESA URANIUM MILL Attachment 1 FIELD DATA 'VORKSHEET FOR GROUND 'VATER Date and Time for Purginm · iO/IGi /;loli Well Purging Equip Used: [gJpump o@ bailer Sampling Event I Qv..o..l'·tt-:rb 1'0 [1-... ",+,- pH Buffer 7.0 Specific Conductancel-l_q-1.q..:...'.!-"~ __ -,I!lMHOSl em Depth to Water Before Purgin~' bf:~D " .;' I and Sampling (if different) I t-: ~;"';;"':;"}J..j)ll:'--_____ -J Well Pump (if other than Bennet) J,.,J M_' .;...~:-.I\-____ ----J Prevo \V'eH Sampled in Sampling Event I a..._u._. t.U_'. _L._p __ -'-__ __ pH Buffer 4.0 14,0 Well Depth(O.Olft):1 I...·...:.....0 __ ._,_._...J Casing Vohune (V) 411 well:I ·/;> .'1(.653h) 3" Well:. C>' ... " _ (.367h) pH of Water (avg) 1'-"_'.'_7 .... ' .,.:::;;))..,;..7 ....... ,_. __ -.:.... _' '....I Well Water Temp. (avg) I \!2 .6~ '. ·1 Redox Potential (Eh)I:lO""7 " . -; I Turbidityl ·45 ' '- Weather Condo I: ...~(£.~~: ".'....:.:\ .... ' •.. ··:1 Conductance Ternp. ac Ci~9 ":-·:1 \5 LC~·q I Redox Potential Eh (mV) I ·:~CJ-'· Turbidity (NTU) Time Gal. Purged '-1 __ ----.. __ , I Conductance ·1 pH s....f ~_---,' I Temp. QC '---__ J Redox Potential Eh (m V)I a... ___ ..... Turbidity (NTU) White Mesa Mil! Field Data Worksheet for Groundwater ExtJI Amb. Temp. cC {prior sampling event>1 . }8t> . ' '1 Tilnc I :~: :.J . :"~,'.'::: I Ga1. Purged , . -: I Conductance I,· : ',I' '"I pH I '.'.:;' I ,. ; -,' Temp.oC I ·1 Redox Potential Eh (nlV) I I Turbidity (NTU) r.. : I Time I "I GaL Purged I . I Conductance I I pH I I Temp.oC I I Redox Potential Eh (mV) I I Turbidity (NTU) I I . .~ Mill· Groundwater Discharge Permit (.;: .... Groundwater Monitoring Quality Assurance Plan (OAP) o Date: 03/22/2010 Rev. 6 Volume of\Vater Purged I'-_-D ___ _ gallon{s) Pumping Rate Calculation Flow Rate (Q), in gpm. Time to evacuate two casing volumes {2V) S/60 = I '0 T =2VJQ= I .. f.) I Number of casing volumes evacuated (if other than two) . ·1 IfweU evacuated to dryness, number of gallons evacuated '0 Name of Certified Analytical Laboratory if Other Than Energy Lab~ ..... ..._JV._'l._Il ______ __ Type of Sample S IT k Sample Vol (indicate Filtered P . Preservative amp e a en if other than as rescrvat]ve Added Type Y N specified be1ow) Y N Y N Ifpreservativl! is used, specify Type and Quantity of Preservative: % !jJ See instruction SCamment .A(~i~4 0" 's;f~ ~t' '13C'S ~.~ ~n.r1·~?~~i .~~~r;Ai"p~~~t :f~«,:s~I~'P;;~ evert-r ... ~Att1pi~j ~<:r~" "~-;'('l .~~ 13}5 ~: ~~fCt~· .. ~(i:.~' (y\C~+~.:.Gk;r 1. h~a -~O}Vl(.:'· .. ~(J ;t:.}.t'~ . tV) ~~+~r "(e~':;>\C" ~+l3i~:' . .".' . L..-_______ --lJDo not touch this cell (SheetName) White Mesa Mill field Data Worksheet for Groundwater • .r""<) MiJl-Groundwater Discharge Permit \. "J . Date; 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan {QAP) ATTACHl\tENT 1 "'HITE 1\fESA URANIUM J\lIILL Attachment 1 l~A See instntction FIELD DATA \VORKSHEET FOR GROUND WATER Location (well name):11.-....:,P...,.;\:..=· -e:;;;..;z-.;....-.. _d.._. ________ --' Sampler Name and initials: I ~oflcr H ~/I,'j~/IH Date and Time for Purgin~ . \0/15/:;"'01\ . ., and Sampling (if different) Wen Purging Equip Used: [QJpump 000 bailer Specific ConductanceI'.. qq1. '. ',' '."." h.tMHOSl em Conductance (avg) Well Water Temp. (avg) [:J'~"~i·.·::':u I 'Veather Cond. Conductance 1:'1; '1.5 :H-'.',:?' 1 Temp.I()C Redox Potential Eh (mV) 1:2..0' .', . ] Turbidity (NTU) Time Conductance Temp. 'oC 1' .. 7 ,'3 ,;' .1 Gal. Purged I ..... · --.;~_-"l pH 1,----__ ' ..... ". ) Redox Potential Eh (m V) JL...I __ ...-;...----J Turbidity (NTU) w hite Mesa Milt Field Oata Worksheet for Groundwater Well Pump (if other than Bennet) Prev. Well Sampled in Sampling Event I' ;. Pic z. .3 pH Buffer 4.0 WeB Depth(O.Olft): ___ I "_',/:}_': __ ',,-;'_-' ·_._1 Casing Volume (V) pH of Water (avg) 4" wen:I 'o.,' -.IC.653h) 3" Well: >0 ·:;; ',' (.367h) '·,1 .'f" . ~.. . • Turbidityl· ,,'7.3 " '·1 Extl. Amb. Temp. °C (prior sampling event)1 '1 1~:" Time r-.<~"::'.':'::.:'~;.' :.::., Gal. Purged r :::'·.::,>:: :~;~r,'_ J Conductance [_7~_';!'_" _____ \ -.t'" I pH I :::,:-,: ... :'\. :. . ':"1 Temp.oC '1 Redox Potential Eh (mV) ...... 1_··_. __ _ Turbidity (NTU) Gal. Purged 1 .... .:--.. __ _ pH ,--I __ .. --......:J .1 t Mill· Groundwater Discharge Permit \. Groundwater Monitoring Quality Assurance Plan (OAP) Volume of Water Purged L...1 __ o ___ --' gallon(s) Pumping Rate Calculation Flow Rate (Q)~ ill gpm. S/60 = L....1 _.....;;0_-, __ --' Time to evacuate two casing volumes (2V) T=2V/Q= I 0 I Number of casing volumes evacuated (if other than two) 1 .... _·, 0.;;;,.' '_0.--" If well evacuated to dryness, number of gallons evacuated L 0 Name of Certified Analytical Laboratory if Other TIlan Enerbry Lab~ ...... IY;;-.'I.;..I' ______ ...-.-I·1 Type of Sample Filtered Preservat i ve Y N Type SIT k Sample Vol (indicate amp e a en if other than as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) Date: 03/22/2010 Rev. 6 Preservative Added Y N If preservative is used, specify Type and Quantity of Preservative: '!-------------' ? ~ ! ~ <> ~Commcnt ,". See instruction ~.~ . " , 1\ rr ; Il ~cl. on ' ~i t C"'} \)..'37. 1''''",1''''' M <l G-Ar~ ;/1 f're-sl-n t -h c. oll ed-So.", pie!.. . s" /VI pie:> ~(6 b>.~~A ,,-1-1245. t.Jc..+er ~'lY\o!>t.sC.leo.r . L::.rt .s ;te Q..-t 1;ZL/ 8 :,. "-________ .... 100 not touch this cell (SheetName) White Mesa Mill Fiefd Data Worksheet for Groundwater A 2 of2 ,capturx' COMPATIBLE WITH~H.~n:--FUNC:T'ONAUTY I Mill· Groundwater Discharge Permit ,,"-:"~) Groundwater Monitoring Quality Assurance Plan (QAP) Date: 03/22./2.010 Rev. 6 .:f ,. Attachment 1 r . ft, ' I i A TT ACH1\fENT I i ttl. 1 \VHITE 1\JESA URANIUl\1 MILL ... ~~ ".~ Sec;: instruction iJ.~E .. ~l~L~"" ... j FIELD DATA 'VORKSHEET FOR GROUND \VATER Description ofSampJing Event: I 'iT~' (;)v.f)..r+er' N : tr~t<: ;2,.01 t Location (well name): .... 1 ?.:.....L.:\ c:::;.;:t.=--__ 3"'--____ ~ ___ __' Sampler Name and initials: I ~N)~r l-1()H~J~,j/Te Date and Time for Purgin~,: ,oj I'I/;J,.o\). Well Purging Equip Used: [QJpump o@ bailer Sampling Event I Q~c.r 1-; N :t n,\. t(' pH Buffer 7.0 I, ,-,.C .o ':'. ·1 Specific Conductaneel ~qq ,., . I llMHOSl em Depth to Water Before Purgin~:40. 42-. ,'" I Conductance (avg) ;,:1 and Sampling (if different) tV/A ~------------~~ Well Pump (if other than Bennet) 1-1 _H;';~I1 _____ .....J Prevo Well Sampled in Sampling Event I L-_,-w.--:.~'/V_. _~ :l._'. ____ ....... pH Buffer 4.0 Wen Depth(O.Olft): I-I_o~-' _"'-----' Casing Volume (V) pH of Water (avg) 411 Well:~(.653h) 3" Well:~(.367h) ll.iJ Well Water Temp. (avg) L ·:·15 .. 0C .. Redox Potential (Eh) I '. J 1'$ , .' ·1 Weather Condo Ext'l Amb. Temp. °C (prior sampling event)I 'i7: Tune &;..1. --.;.." .....;....;~.;..,J.I Gal. Purged J.",.;I .. -..;...;.. __ · ....... 'I Conductance I "~\4:(.,' .; ::1 Conductance &...;L_· .. ....;.. .. --.;...;~......I pHI... '--_.' _.----1,:1 Temp. uC I l!). 0 (). " I Temp.oC Redox Potential Eh (m V)I L. ...:,1..-.'1 fS:...i-_--' Redox Potential Eh (m V) a.;.1· .;..;.;...._~ ..... Turbidity (NTU) Turbidity (NTU) 1 :'0.:' I Time I GaL Purged 1-1 ____ ~....I Time Gal. Purged I I Conductance I pH L.1 _""--_....I Conductance . I pH I, :·'71 Temp.oC L..;L~_~......I Temp.t:'C Redox Potential Eh (m V) 1-1 ___ ---" Redox Potential Eh (m V) 1..-1 ___ .....I Turbidity (NTU) Turbidity (NTU) White Mesa Mil! Fietd Oata Work.sheet for Groundwater 4 Mill· Groundwater Discharge Permit /") Date: 03/22/2010 Rev. 6 Groundwater Monitoring Quality Assurance Plan ,QAP) Volume of Water Purged [ """ _D.,;;;;.··. ___ ---t gaUon{s) Pumping Rate Calculation Flow Rate (Qt in gpm. Time to evacuate two casing volumes (2V) S/60= I 6 T=2V/Q= I 0 I Number of casing volumes evacuated (if other than two) """I" ._0 _______ .... ]fweH evacuated to dryness, number of gallons evacuated '1-,..;;;0 ___ .... Name of Certified Analytical Laboratory if Other Than Energy. Lab~_r.;;.N ..... 1 ,., _________ --.1 Type of Sample Sample Vol (indicate Sample Taken if other than as Y N specified below) VOCs Nutrients Heavy Metals All Other Non Radiologies Gross Alpha Other (specify) fComment Filtered Y N Preservative Type Preservative Added Y N If preservative IS used., specify Type and Quantity of Preservative: [~ See instruction A((;vca on s.;tc ~t I:llO. ""'~"I1U ",,,cl (,..().rr;(l r(t:$~,,-r t~· t-..~i.led-.~tA.r'P)p}~~, 5."''''p't".5 ~~\~ o.} t1.30 ~ U-)C\.+cr \}l~ cJ~o.r ~ ~th "-'h~h PH. Le~-t s ,'te oJ '~3.s '--_______ --IIDo not touch this cell (SheetName) White Mesa Mill Field Data Worksheet for Groundwater 2 of 2 c,apturx' COMPA11!)U w ITH.,..4"",ri:-rUNCTIONAliTY TabC Kriged Current Quarter Groundwater Contour Map and Depth to Water Summary TIME 1207 1323 1028 1027 1335 1332 1339 1349 1344 1022 1203 1054 830 822 1327 1311 1318 1243 1307 1315 1321 1318 1327 1321 1340 1341 1330 1333 1342 NAME: Tanner Holliday, Garrin Palmer DATE: 12/21/2011 WELL Static level TIME WELL Static Level TIME WELL Static Level TIME WELL Static Level MW-1 66.50 1257 MW-4 72.01 1057 PIEZ-1 61.27 DR-1 ABANDON MW-2 109.80 1255 TW4-1 64.01 1215 PIEZ-2 18.77 DR-2 ABANDON MW-3 83.50 1258 TW4-2 66.88 1246 PIEZ-3 40.08 MW-3A 85.26 1251 TW4-3 49.18 1315 PIEZ-4 47.60 MW-5 106.09 1302 TW4-4 69.13 1312 PIEZ-5 42.46 920 DR-5 82.96 MW-11 88.11 1247 TW4-5 55.66 923 DR-6 94.45 MW-12 108.21 1304 TW4-6 69.91 1257 TWN-1 50.94 1336 DR-7 92.14 MW-14 103.65 1257 TW4-7 67.29 1238 TWN-2 16.97 916 DR-8 51 MW-15 106.36 1253 TW4-8 66.39 1250 TWN-3 32.10 913 DR-9 86.35 MW-17 75.03 1249 TW4-9 53.68 1244 TWN-4 39.08 909 DR-10 78.11 MW-18 69.91 1245 TW4-10 55.50 1209 TWN-5 69.42 1032 DR-11 98.27 MW-19 51.67 1300 TW4-11 56.99 1202 TWN-6 74.27 1034 DR-12 87.78 MW-20 87.45 1015 TW4-12 40.01 1210 TWN-7 88.48 1036 DR-13 69.8 MW-22 66.87 1016 TW4-13 46.00 1200 TWN-8 61.30 903 DR-14 76.2 MW-23 117.30 1019 TW4-14 87.05 1059 TWN-9 60.03 927 DR-15 92.8 MW-24 114.40 1243 TW4-15 76.33 1051 TWN-10 80.76 DR-16 ABANDON MW-25 73.80 1324 TW4-16 61.07 1046 TWN-11 69.35 901 DR-17 64.6 MW-26 76.33 1321 TW4-17 75.18 1044 TWN-12 29.31 DR-18 ABANDON MW-27 50.94 1259 TW4-18 56.25 1101 TWN-13 46.02 847.00 DR-19 63.2 MW-28 76.65 1223 TW4-19 60.27 1102 TWN-14 62.55 845.00 DR-20 55.85 MW-29 102.19 1241 TW4-20 70.95 1049 TWN-15 92.00 836 DR-21 101.29 MW-30 76.08 1304 TW4-21 53.67 1107 TWN-16 47.76 852 DR-22 Dry MW-31 68.06 1239 TW4-22 53.31 1105 TWN-17 33.70 841 DR-23 70.49 MW-32 75.18 1307 TW4-23 64.79 1241 TWN-18 57.50 855 DR-24 43.5 MW-33 Dry 1237 TW4-24 54.81 817 TWN-19 52.46 DR-25 ABANDON MW-34 107.75 1255 TW4-25 46.68 MW-35 112.35 1309 TW4-26 63.52 MW-36 110.45 1020 ITW4-27 I 90.16 MW-37 115.80 Comments: TW4-27 was purged yesterday on 12/20/2011 for well development and the static has not recovered to normal static. TW4-27 also needs bumper posts, labeled, painted, and locked. Some well times may be the same because we split up to take depths. ~ Estimated dry area iIIl!-5 perched monitoring well showing 'I!!:' 5503 elevation in feet amsl TW4-12 temporary perched monitoring well 0 5584 showing elevation in feet amsl TWN-10 ~5586 temporary perched nitrate monitoring well showing elevation in feet amsl PIEZ-1 perched piezometer showing G 5594 elevation in feet amsl TW4-27 temporary perched monitoring well 3:::t 5518 installed October, 2011 showing elevation in feet amsl RUIN SPRING 0 5380 seep or spring showing elevation in feet amsl JE;IYDRO GrEO CHEM, lINe. NOTE: MW-4, MW-26 , TW4-4, TW4-19, and TW4-20 are pumping wells KRJGElD 4th QlUARIER~ 2011 WAlleR LEVELS WH~TlE MESA S~TE APPROVED DATE REFERENCE FIGURE H:/718000/feb12/UwI1211.srf C-l TabD Kriged Previous Quarter Groundwater Contour Map PROPERTY BOUNDARY =\ 'As \1 \\ t'" , ~.:::--~=~ ,-;;;~ h ~ ~,r III '\ II II -~I II /1 I' " II :i 32 ,I \1 II II I' ',I \' II ,I \ @ M~-21 \ \ l\I \ \ \ ~~ ~~ ~~ ~~ ~~ MW·02 e5S03 ~~60 MW·20 e5453 ~~ ~ --=.,.,--..;~ -=--=-,-~, h -J[ "c -2 o 3000 MW-22 .5450 TW4-1 0 5554 PIEZ-1 Q 5594 TWN-4 <> 5603 MW-34 -9-5492 MW-36 ~5493 SCALE IN FEET EXPLANATION perched monitoring well showing elevation in feet amsl temporary perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl perched monitoring well installed August/September, 2010 showing elevation in feet amsl perched monitoring well installed April, 2011 showing elevation in feet amsl HYDRO GEO CHEM, INC. .,; ~ MW·01 e5S83 MW·18 e5S87 ~S86 TWN·10 ~--/:liJ:------? ---- :/ _ 552 ~ ~" II // // // // // // // // // // 0, NOTE: MW-4, MW-26, TW4-4, TW4-19 and TW4-20 are pumping wells KRIGED 3rd QUARTER, 2011 WATER LEVELS WHITE MESA SITE APPROVED DATE REFERENCE FIGURE SJS H:/718000/nov11/wI0911 .srf D-l \ TabE Hydrographs of Groundwater Elevations Over Time for Nitrate Monitoring Wells -c. 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CD .., 08/10/10 r-CD < CD 0 < CD 11/18/10 .., =t 3 CD .-. ~ 02/26/11 C'" 3 "C --- 06/06/11 09/14/11 12/23/11 01 ~ 01 01 01 o Depth Below Measuring Point (ft.) 01 ~ 01 01 ~ o 01 v.> C:.n 01 v.> o 01 N 01 01 N o I------t-----I----+--------t----+----j-------t-i 07/06/09 10/14/09 01/22/10 -. 05/02/10 08/10/10 11/18/10 02/26/11 06/06/11 09/14/11 '--__ ---L-___ ....1-___ ----L ___ ......J.-___ ...L..-__ --'-___ -'-12/23/11 ~ Z I ....10 co ~ r+ CD .., r-CD < CD 0 < CD .., =t 3 CD .-;= C'" 3 "'C - TabF Depths to Groundwater and Elevations Over Time for Nitrate Monitoring Wells Water Levels and Data over Time White Mesa Mill-Well TWN-l Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,646.96 5,648.09 1.13 112.5 5,600.38 02/06/09 47.71 46.58 5,599.99 07/21109 48.10 46.97 5,600.26 09/21109 47.83 46.70 5,601.10 10/28/09 46.99 45.86 5,602.59 12/14/09 45.50 44.37 5,600.55 03111110 47.54 46.41 5,600.66 05/11110 47.43 46.30 5,599.18 09/29110 48.91 47.78 5,598.92 12/21110 49.17 48.04 5,598.29 02/28111 49.80 48.67 5,597.80 06/21111 50.29 49.16 5,597.32 09/20111 50.77 49.64 Water Levels and Data over Time White Mesa Mill-Well TWN-2 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,625.75 5,626.69 0.94 95 5,611.37 02/06/09 15.32 14.38 5,610.63 07/21109 16.06 15.12 5,609.73 09/21109 16.96 16.02 5,607.08 11102/09 19.61 18.67 5,606.57 12114/09 20.12 19.18 5,612.45 03111110 14.24 13.30 5,612.78 05111110 13.91 12.97 5,611.37 09/29110 15.32 14.38 5,610.24 12/21110 16.45 15.51 5,610.64 02/28111 16.05 15.11 5,609.78 06/21111 16.91 15.97 5609.79 09/20111 16.90 15.96 Water Levels and Data over Time White Mesa Mill-Well TWN-3 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,633.64 5,634.50 0.86 110 5,603.77 02/06/09 30.73 29.87 5,602.37 07121109 32.13 31.27 5,602.34 09121109 32.16 31.30 5,602.60 10/28/09 31.90 31.04 5,603.12 12114/09 31.38 30.52 5,602.90 03111110 31.60 30.74 5,603.23 05111110 31.27 30.41 5,602.86 09129110 31.64 30.78 5,603.35 12/21110 31.15 30.29 5,602.89 02/28111 31.61 30.75 5,602.75 06/21111 31.75 30.89 5,602.40 09120111 32.10 31.24 Water Levels and Data over Time White Mesa Mill-Well TWN-4 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,641.04 5,641.87 0.83 136 5,601.47 02/06/09 40.40 39.57 5,604.26 07/21109 37.61 36.78 5,605.02 09/21109 36.85 36.02 5,605.87 10/28/09 36.00 35.17 5,605.81 12114/09 36.06 35.23 5,605.31 03111110 36.56 35.73 5,605.36 05111110 36.51 35.68 5,604.59 09/29/10 37.28 36.45 5,604.42 12/21110 37.45 36.62 5,603.69 02/28/11 38.18 37.35 5,603.36 06/21111 38.51 37.68 5,602.82 09/20111 39.05 38.22 Water Levels and Data over-Time White Mesa Mill-Well TWN-5 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,653.70 5,655.18 1.48 155 5,584.43 08 /25/09 70.75 69.27 5,584.51 09121109 70.67 69.19 5,584.54 11110109 70.64 69.16 5,584.62 12114/09 70.56 69.08 5,584.97 03111110 70.21 68.73 5,585.38 05111110 69.80 68.32 5,585.35 09/29110 69.83 68.35 5,585.42 12/21110 69.76 68.28 5,585.08 02/28111 70.10 68.62 5,585.38 06121111 69.80 68.32 5,585.51 09/20111 69.67 68.19 Water Levels and Data over Time White Mesa Mill-Well TWN-6 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,663.03 5,664.94 1.91 135 5,589.52 08/25/09 75.42 73.51 5,589.46 09/22/09 75.48 73.57 5,589.61 11103/09 75.33 73.42 5,589.92 12114/09 75.02 73.11 5,590.24 03111110 74.70 72.79 5,590.40 05111110 74.54 72.63 5,590.24 09/29110 74.70 72.79 5,590.49 12/21110 74.45 72.54 5,590.16 02/28111 74.78 72.87 5,590.44 06/21111 74.50 72.59 5,590.35 09/20/11 74.59 72.68 Water Levels and Data over Time White Mesa Mill -Well TWN-7 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,647.39 5,649.26 1.87 120 5,552.56 08/25/09 96.70 94.83 5,558.34 09/21109 90.92 89.05 5,558.82 11110109 90.44 88.57 5,558.96 12114/09 90.30 88.43 5,559.54 03111110 89.72 87.85 5,559.60 05111110 89.66 87.79 5,559.83 09/29110 89.43 87.56 5,559.00 12121110 90.26 88.39 5,559.68 02/28111 89.58 87.71 5,560.43 06121111 88.83 86.96 5,560.46 09/20111 88.80 86.93 Water Levels and Data over Time White Mesa Mill-Well TWN-8 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,649.35 5,651.48 2.13 160 5,589.01 08/25/09 62.47 60.34 5,589.10 09/21109 62.38 60.25 5,589.09 11103/09 62.39 60.26 5,603.38 12114/09 48.10 45.97 5,589.68 03111110 61.80 59.67 5,589.95 05111110 61.53 59.40 5,589.74 09129110 61.74 59.61 5,589.97 12121110 61.51 59.38 5,589.67 02128111 61.81 59.68 5,589.96 06/21111 61.52 59.39 5,589.82 09120111 61.66 59.53 Water Levels and Data over Time White Mesa Mill-Well TWN-9 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,645.68 5,647.45 1.77 102.5 5,582.05 08/25/09 65.40 63.63 5,582.12 09122109 65.33 63.56 5,582.27 11110/09 65.18 63.41 5,582.53 12114/09 64.92 63.15 5,582.92 03111110 64.53 62.76 5,583.06 05111110 64.39 62.62 5,583.25 09129110 64.20 62.43 5,583.57 12121110 63.88 62.11 5,583.54 02128111 63.91 62.14 5,583.92 06/21111 63.53 61.76 5,584.04 09/20111 63.41 61.64 Water Levels and Data over Time White Mesa Mill-Well TWN-IO Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,664.63 5,666.98 2.35 107.5 5,584.18 08/25/09 82.80 80.45 5,584.40 09/22/09 82.58 80.23 5,584.61 11110109 82.37 80.02 5,584.90 12114/09 82.08 79.73 5,585.21 03/11110 81.77 79.42 5,585.42 05111110 81.56 79.21 5,585.42 09/29110 81.56 79.21 5,585.68 12/21110 81.30 78.95 5,585.60 02/28111 81.38 79.03 5,585.95 06/21111 81.03 78.68 5,585.92 09/20111 81.06 78.71 Water Levels and Data over Time White Mesa Mill-Well TWN-ll Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,683.16 5,684.53 1.37 147.5 5,613.00 11103/09 71.53 70.16 5,613.88 12114/09 70.65 69.28 5,614.65 03111110 69.88 68.51 5,615.16 05111110 69.37 68.00 5,614.93 09/29110 69.60 68.23 5,615.09 12/21110 69.44 68.07 5,614.96 02/28111 69.57 68.20 5,615.12 06/21111 69.41 68.04 5,614.96 09/20111 69.57 68.20 Water -Levels and Data over Time White Mesa Mill-Well TWN-12 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,667.03 5,668.24 1.21 115 5,628.33 11103/09 39.91 38.70 5,628.86 12114/09 39.38 38.17 5,630.27 03 /11110 37.97 36.76 5,631.64 05111110 36.60 35.39 5,633.73 09/29110 34.51 33.30 5,633.43 12121110 34.81 33.60 5,634.35 02128111 33.89 32.68 5,635.95 06/21111 32.29 31.08 5,636.44 09/20111 31.80 30.59 Water Levels and Data over Time White Mesa Mill-Well TWN-13 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,633.04 5,634.32 1.28 120 5,586.95 11103/09 47.37 46.09 5,587.22 12114/09 47.10 45.82 5,587.45 03111110 46.87 45.59 5,587.64 05111110 46.68 45.40 5,587.37 09/29110 46.95 45.67 5,587.77 12/21110 46.55 45.27 5,587.64 02/28111 46.68 45.40 5,587.89 06/21111 46.43 45.15 5,588.03 09/20111 46.29 45.01 Water Levels and Data over Time White Mesa Mill-Well TWN-14 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,647.80 5,649.53 1.73 135 5,586.18 11/04/09 63.35 61.62 5,586.51 12114/09 63.02 61.29 5,586.71 03111/10 62.82 61.09 5,586.72 05111110 62.81 61.08 5,586.53 09/29110 63.00 61.27 5,586.80 12/21/10 62.73 61.00 5,586.74 02/28111 62.79 61.06 5,586.84 06/21111 62.69 60.96 5,586.73 09/20/11 62.80 61.07 Water Levels and Data over Time White Mesa Mill-Well TWN-15 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,675.01 5,676.49 1.48 155 5,594.12 11110109 82.37 80.89 5,584.03 12/14/09 92.46 90.98 5,584.10 03/11/10 92.39 90.91 5,584.16 05/11110 92.33 90.85 5,584.26 09/29/10 92.23 90.75 5,584.30 12121/10 92.19 90.71 5,584.04 02/28/11 92.45 90.97 5,584.30 06/21/11 92.19 90.71 5,584.37 09/20/11 92.12 90.64 Water Levels and Data over Time White Mesa Mill-Well TWN-16 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,651.07 5,652.70 1.63 100 5,603.34 11104/09 49.36 47.73 5,603.56 12114/09 49.14 47.51 5,603.84 03111110 48.86 47.23 5,604.31 05111110 48.39 46.76 5,604.28 09/29110 48.42 46.79 5,604.39 12/21110 48.31 46.68 5,604.20 02/28111 48.50 46.87 5,604.55 06/21111 48.15 46.52 5,604.74 09/20111 47.96 46.33 Water Levels and Data over Time White Mesa Mill-Well TWN-17 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,639.73 5,641.55 1.82 100 5,605.96 11104/09 35.59 33.77 5,606.27 12114/09 35.28 33.46 5,606.25 03111110 35.30 33.48 5,606.55 05111110 35.00 33.18 5,606.77 09/29110 34.78 32.96 5,607.15 12/21110 34.40 32.58 5,606.96 02/28111 34.59 32.77 5,607.22 06/21111 34.33 32.51 5,607.40 09/20111 34.15 32.33 Water Levels and Data over Time White Mesa Mill -Well TWN -18 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,643.95 5,645.45 1.50 100 5,586.85 11102/09 58.60 57.10 5,600.14 12/14/09 45.31 43.81 5,587.36 03/11110 58.09 56.59 5,587.71 05/11/10 57.74 56.24 5,587.50 09/29/10 57.95 56.45 5,607.66 12/21110 37.79 36.29 5,587.35 02/28/11 58.10 56.60 5,587.71 06/21111 57.74 56.24 5,587.65 09/20/11 57.80 56.30 Water Levels and Data over Time White Mesa Mill-Well TWN-19 Total or Measuring Measured Total Water Land Point Depth to Depth to Total Elevation Surface Elevation Length Of Date Of Water Water Depth Of (WL) (LSD) (MP) Riser (L) Monitoring (blw.MP) (blw.LSD) Well 5,659.59 5,661.36 1.77 110 5,606.17 11102/09 55.19 53.42 5,606.70 12114/09 54.66 52.89 5,607.22 03111110 54.14 52.37 5,607.89 05111110 53.47 51.70 5,607.98 09129110 53 .38 51.61 5,608.41 12/21110 52.95 51.18 5,608.49 02/28111 52.87 51.10 5,608.60 06/21111 52.76 50.99 5,609.17 09/20111 52.19 50.42 TabG Laboratory Analytical Reports EN:RGY LABORAT ORIES www.energylab.com I Analytical Excel/encI Sines 1952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WV 888-235-0515 Gillette, WY 866-686-7175 • Rapid City, SD 888-672-1225 • College Station, IX 888-690-2218 ANAL VTICAL SUMMARY REPORT November 09, 2011 Denison Mines USA Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C11100844 Project Name: 4th Quarter Nitrate 2011 Quote 10: C3317 -Nitrate and Chloride Sampling Energy Laboratories, Inc. Casper WY received the following 29 samples for Denison Mines USA Corp on 10/21/2011 for analysis. Sample ID Client Sample ID Collect Date Receive Date Matrix Test C 111 00844-001 TWN-8R 10/17/117:30 10/21/11 Aqueous Chloride Nitrogen, Nitrate + Nitrite C 11100844-002 TWN-7R 10/18/11 7:00 10/21/11 Aqueous Same As Above C 11100844-003 TWN-17R 10/19/117:19 10/21/11 Aqueous Same As Above C 11100844-004 TWN-8 10/17/118:03 10/21/11 Aqueous Same As Above C 111 00844-005 TWN-13 10/17/119:10 10/21/11 Aqueous Same As Above C 11100844-006 TWN-10 10/18/11 6:20 10/21/11 Aqueous Same As Above C 11100844-007 TWN-11 10/17/1112:45 10/21/11 Aqueous Same As Above C 11100844-008 TWN-5 10/17/11 13:40 10/21/11 Aqueous Same As Above C 11100844-009 TWN-1 10/17/1114:23 10/21/11 Aqueous Same As Above C111 00844-01 0 TWN-12 10/17/1115:1210/21/11 Aqueous Same As Above C11100844-011 TWN-7 10/19/11 6:50 10/21/11 Aqueous Same As Above C11100844-012 TWN-4 10/18/11 8:05 10/21/11 Aqueous Same As Above C11100844-013 TWN-6 10/18/11 8:52 10/21/11 Aqueous Same As Above C11100844-014 TWN-15 10/19/11 6:28 10/21/11 Aqueous Same As Above C11100844-015 TWN-18 10/18/11 11 :06 10/21/11 Aqueous Same As Above C11100844-016 TWN-16 10/18/11 12:33 10/21/11 Aqueous Same As Above C11100844-017 TWN-14 10/19/11 6:36 10/21/11 Aqueous Same As Above C 111 00844-01 8 TWN-19 10/18/11 14:38 10/21/11 Aqueous Same As Above C11100844-019 TWN-17 10/20/11 7:05 10/21/11 Aqueous Same As Above C 11100844-020 TWN-9 10/20/11 6:53 10/21/11 Aqueous Same As Above C 11100844-021 TWN-3 10/20/11 6:40 10/21/11 Aqueous Same As Above C 11100844-022 TWN-2 10/20/11 6:30 10/21/11 Aqueous Same As Above C 11100844-023 Piez-1 10/19/1113:15 10/21/11 Aqueous Same As Above C 11100844-024 Piez-2 10/19/1112:45 10/21/11 Aqueous Same As Above C 11100844-025 Piez-3 10/19/11 12:30 10/21/11 Aqueous Same As Above C 111 00844-026 UWLP 10/19/11 13:00 10/21/11 Aqueous Same As Above C 11100844-027 TWN-65 10/18/11 8:05 10/21/11 Aqueous Same As Above Page 1 of 17 " www.energylab.com r-Helena.MT877-472-0711 .Billings.MT 800-735-4489 • Casper, WY 888-235-0515 Analytical fxcsllsncB Sines 1952 J." .. ' ~iII~tte, WY 866-686-7175 • Rapid City, SD 888-672-1225 • College Station, IX 888-690-2218 ANAL VTICAL SUMMARY REPORT C11100844-028 TWN-70 10/20/11 7:05 10/21/11 Aqueous Same As Above C11100844-029 TWN-60 10/19/11 13:25 10/21/11 Aqueous Same As Above The analyses presented in this report were performed at Energy Laboratories, Inc., 2393 Salt Creek Hwy., Casper, WY 82601, unless otherwise noted. Radiochemistry analyses were performed at Energy Laboratories, Inc., 2325 Kerzell Lane, Casper, WY 82601, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. The results as reported relate only to the item(s) submitted for testing. All samples are reported on an as received basis unless otherwise indicated. If you have any questions regarding these test results, please call. Report Approved By: c3¥~D tJ~'Y Reporting Supervisor Digitally signed by Stephanie Waldrop Date: 2011.11.0916:11:50 -07:00 Page 2 of 17 www.energylab.com Analytical Excsllsnce Since 1952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gillette, WY 866-686-1175 • Rapid City, SO 888-672-1225 • College Station, IX 888-&90-2218 CLIENT: Denison Mines USA Corp Project : 4th Quarter Nitrate 2011 Report Date: 11/09/11 Sample Delivery Group: C11100844 CASE NARRATIVE ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4"C (±2"C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIL/SOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by ELI reflects the results for seven individual Aroclors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SO eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL-DOH NELAC: E87641, Radiochemical E871 017; California: 02118CA; Oregon: WY200001 ; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Rep,ort relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting www.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page www.energylab.com. Page 3 of 17 EN:RGY LABORATORIES www.energylab.com Af181ytical ExcsllBIICII Sincs '952 Helena, MT 877~472-0711 • Billings, MT 800-135-4489 • Casper, 'NY 888-235-0515 Gillette, WY 866~686-7175 • Rapid City, SD 88B-672~ 1225 II College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab ID: C11100844-001 Client Sample ID: TWN-8R Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-002 Client Sample ID: TWN-7R Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-003 Client Sample ID: TWN-17R Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-004 Client Sample ID: TWN-8 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units NO mg/L NO mg/L Result Units 1 NO mg/L mg/L Result Units NO NO mg/L mg/L Result Units 10 NO mg/L mg/L Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Report Date: 11/09/11 Collection Date: 10/17/11 07:30 Date Received : 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 10/21/11 15:071 we E353.2 11/01/1116:00/de Collection Date: 10/18/11 07:00 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 10/21/1115:12/we E353.2 11/02/11 11 :47 1 de Collection Date: 10/19/11 07:19 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By MCL! A4500-CI B 10/21/11 15:161 we E353.2 11/01/11 16:051 de Collection Date: 10/17/11 08:03 DateReceived: 10/21/11 Matrix: Aqueous QCL Method Analysis Date 1 By A4500-CI B 10/21/11 15:191 wc E353.2 11/01/11 16:071 dc MCL -Maximum contaminant level. NO -Not detected at the reporting limit. Page 4 of 17 EI'ERGY LABORATORIES www.energylab.com Analytical ExCIIIIBflCe Since 1952 Helena, MT 871-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gillette, WY 866-686-7175 • Rapid City, SD 888-&72-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab ID: C11100844-005 Client Sample ID: TWN-13 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab I D: C 111 00844-006 Client Sample ID: TWN-10 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-007 Client Sample ID: TWN-11 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-008 Client Sample ID: TWN-5 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 48 mg/L NO mg/L Result Units 33 0.2 Result 76 1.6 mg/L mg/L Units mg/L mg/L Result Units 45 0.3 mg/L mg/L Qualifiers Qualifiers Qualifiers Qualifiers Rl 0.1 Rl 0.1 Rl 1 0.1 Rl 1 0.1 Report Date: 11/09/11 Collection Date: 10/17/11 09:10 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date I By A4500-CI B 10/21/1115:22/we E353.2 11/01/11 16: 1 0 1 de Collection Date: 10/18/11 06:20 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date I By A4500-CI B 10/21/11 16:001 wc E353.2 11/01/11 16:171 dc Collection Date: 10/17/11 12:45 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel MeL! Method Analysis Date I By A4500-CI B 10/21/1116:04/we E353.2 11/01/11 16:251 de Collection Date: 10/17/11 13:40 DateReceived: 10/21/11 Matrix: Aqueous Qel Method Analysis Date I By A4500-CI B 10/21/11 16:061 wc E353.2 11/01/1116:27/dc MCL -Maximum contaminant level. NO -Not detected at the reporting limit. Page 5 of 17 EN:RGY LABORAT ORIES www.energylab.com Analytical ExcsJIBflce Sines 7952 Heiena, MT 877-412-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gillette, WY 866-&86-7175 • Rapid City, SD 888-672-1225 • College Station, TX 888-&90-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab ID: C11100844-009 Client Sample ID: TWN-1 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C111 00844-01 0 Client Sample ID: TWN-12 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-011 Client Sample ID: TWN-7 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-012 Client Sample ID: TWN-4 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Rl -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 10 mg/l 0.5 mg/l Result Units 87 1.2 mg/l mg/l Result Units 6 2.2 mg/l mg/l Result Units 20 0.9 mg/l mg/l Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Report Date: 11/09/11 Collection Date: 10/17/11 14:23 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 10/21/11 16:401 we E353.2 11/01/11 16:301 de Collection Date: 10/17/11 15:12 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 10/21/1116:45/we E353.2 11/01/11 16:321 de Collection Date: 10/19/11 06:50 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By MCL! A4500-CI B 10/21/1116:46/wc E353.2 11/01/11 16:351 dc Collection Date: 10/18/11 08:05 DateReceived: 10/21/11 Matrix: Aqueous QCL Method Analysis Date 1 By A4500-CI B 10/21/11 16:471 wc E353.2 11/01/11 16:371 dc MCl -Maximum contaminant level. ND -Not detected at the reporting limit. Page 6 of 17 EI\ERGY L.ABORATORIES www.energylab.com Analytical ExcsllsncB Sines '952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gille~e, WY 866-686-7175 • Rapid City, SO 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab ID: C11100844-013 Client Sample ID: TWN-6 Analyses Result MAJOR IONS Chloride 21 Nitrogen, Nitrate+Nitrite as N 1.4 Lab ID: C11100844-014 Client Sample ID: TWN-15 Units mg/L mg/L Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-015 Client Sample ID: TWN-18 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-016 Client Sample ID: TWN-16 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. 38 1.3 mg/L mg/L Result Units 60 1.9 Result 34 2.6 mg/L mg/L Units mg/L mg/L D -RL increased due to sample matrix. Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL D 0.2 Report Date: 11/09/11 Collection Date: 10/18/11 08:52 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 10/21/11 16:481 we E353.2 11/01/1116:40/dc Collection Date: 10/19/11 06:28 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By MCL! A4500-CI B 10/24/11 11 :40 1 we E353.2 11/01/11 16:421 de Collection Date: 10/18/11 11 :06 Date Received: 1 0/21/11 Matrix: Aqueous QCL Method Analysis Date 1 By A4500-CI B 10/24/11 11 :48 1 we E353.2 11/01/11 16:451 de Collection Date: 10/18/11 12:33 DateReceived: 10/21/11 Matrix: Aqueous MCL! QCL Method Analysis Date 1 By A4500-CI B 10/24/11 11 :52 1 we E353.2 11/01/11 16:551 de MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 7 of 17 EN:RGY LABORATORIES www.energylab.com Analytical Exes/fillies Sines 1952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, W'f 888-235-0515 Gillette, WY 866-&86-7175 • Rapid City, SO 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab 10: C11100844-017 Client Sample 10: TWN-14 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C11100844-018 Client Sample 10: TWN-19 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C11100844-019 Client Sample 10: TWN-17 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C11100844-020 Client Sample 10: TWN-9 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. Result Units 27 mg/L 3.9 mg/L Result Units 108 6.5 Result 71 8.1 mg/L mg/L Units mg/L mg/L Result Units 134 mg/L 10.9 mg/L D -RL increased due to sample matrix. Qualifiers Rl D 0.2 Qualifiers Rl D 0.5 Qualifiers Rl 1 D 0.5 Qualifiers Rl D 0.5 Report Date: 11/09/11 Collection Date: 10/19/11 06:36 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 10/24/11 11 :55 1 wc E353.2 11/01/1117:02/dc Collection Date: 10/18/11 14:38 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 10/24/1112:01/wc E353.2 11/01/11 17:051 dc Collection Date: 10/20/11 07:,05 / DateReceived: 10/21/11 { Matrix: Aqueous MeL! Qel MeL! Method Analysis Date 1 By A4500-CI B 10/24/11 12:071 wc E353.2 11/01/1117:07/dc Collection Date: 10/20/11 06:53 DateReceived: 10/21/11 Matrix: Aqueous Qel Method AnalYSis Date 1 By A4500-CI B 10/24/1112:15/wc E353.2 11/01/1117:10/dc MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 8 of 17 www.energylab.com AflBlytical ExCSUINICB Sines 1!152 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gillette, WY 866-686-7175 • Rapid City, SD 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab ID: C11100844-021 Client Sample ID: TWN-3 Analyses Result MAJOR IONS Chloride 129 Nitrogen, Nitrate+Nitrite as N 25 Lab ID: C 11100844-022 Client Sample ID: TWN-2 Units mg/L mg/L Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 111 00844-023 Client Sample ID: Piez-1 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N LablD: C 111 00844-024 Client Sample ID: Piez-2 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. 76 33 Result 55 6.6 mg/L mg/L Units mg/L mg/L Result Units 8 0.1 mg/L mg/L D -RL increased due to sample matrix. Qualifiers Rl D Qualifiers Rl D Qualifiers Rl D 0.5 Qualifiers Rl 0.1 Report Date: 11/09/11 Collection Date: 10/20/11 06:40 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date / By A4500-CI B 10/24/11 12:21 1 wc E353.2 11/01/11 17:121 dc Collection Date: 10/20/11 06:30 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 10/24/11 12 :25 1 wc E353.2 11/01/1117:15/dc Collection Date: 10/19/11 13:15 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel MeL! Method Analysis Date 1 By A4500-CI B 10/24/1112:30/wc E353.2 11/01/11 17:171 dc Collection Date: 10/19/11 12:45 DateReceived: 10/21/11 Matrix: Aqueous Qel Method Analysis Date 1 By A4500-CI B 10/24/11 14:131 wc E353.2 11/01/1117:20/dc MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 9 of 17 EN:RGY LASORATORI ES www.energylab.com Analytical ExcsllBll&B Sincs .1952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gillette, Wy 866-~86-7175 • Rapid City, SD 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: LablD: Denison Mines USA Corp 4th Quarter Nitrate 2011 C 111 00844-025 Client Sample ID: Piez-3 Analyses Result MAJOR IONS Chloride 12 Nitrogen, Nitrate+Nitrite as N 1.7 Lab ID: C11100844-026 Client Sample ID: UWLP Units mg/L mg/L Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-027 Client Sample ID: TWN-65 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C11100844-028 Client Sample ID: TWN-70 Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality control limit. ND ND Result 18 0.9 Result 74 8.6 D -RL increased due to sample matrix. mg/L mg/L Units mg/L mg/L Units mg/L mg/L Qualifiers Rl 0.1 Qualifiers Rl 0.1 Qualifiers Rl 0.1 Qualifiers Rl D 0.5 Report Date: 11/09/11 Collection Date: 10/19/11 12:30 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 10/24/1114:13/wc E353.2 11/01/11 17:221 dc Collection Date: 10/19/11 13:00 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By MeL! Qel A4500-CI B 10/24/11 14:131 wc E353.2 11/02/11 11 :37 1 dc Collection Date: 10/18/11 08:05 DateReceived: 10/21/11 Matrix: Aqueous Method Analysis Date 1 By A4500-CI B 10/24/1114:15/wc E353.2 11/02/11 11 :40 1 dc Collection Date: 10/20/11 07:05 DateReceived: 10/21/11 Matrix: Aqueous MeL! Qel Method Analysis Date 1 By A4500-CI B 10/24/1114:18/wc E353.2 11/02/11 11 :50 1 dc MCL -Maximum contaminant level. ND -Not detected at the reporting limit. Page 10 of 17 Ef\ERGY LABORATORIES www.energylab.com Analytical ExcsllsnclI Sines 1952 Helena, MT 877 -472-0711 -Billings, MT 800-735-4489 -Casper, WY 888-235-0515 Gillette, WY 866-&86-7175 • Rapid City, SO 888-672-1225 • College Station, TX 888-690-2218 LABORATORY ANALYTICAL REPORT Prepared by Casper, WY Branch Client: Project: Denison Mines USA Corp 4th Quarter Nitrate 2011 Lab 10: C11100844-029 Client Sample 10: TWN-60 Analyses Result MAJOR IONS Chloride 6 Nitrogen, Nitrate+Nitrite as N NO Report Rl -Analyte reporting limit. Definitions: QCl -Quality control limit. Units mg/l mg/l MCL! Qualifiers RL QCL 0.1 Report Date: 11/09/11 Collection Date: 10/19/11 13:25 DateReceived: 10/21/11 Matrix: Aqueous Method Analysis Date 1 By A4500-CI B 10/24/11 14:20 1 wc E353.2 11/02111 11 :52 1 dc MCl -Maximum contaminant level. NO -Not detected at the reporting limit. Page 11 of 17 EN:RGY www.energylab.com Helena, MT 871-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 'Gillette, WV 866-686-7175 • Rapid City, SO 888-672-1225 • College Station, IX 888-&90-2218 L.ABORATORIES Ana~1 Excsllsnc6 Sines 7952 ------------------------------------~--~------------- Client: Denison Mines USA Corp Project: 4th Quarter Nitrate 2011 QA/QC Summary Report Prepared by Casper, WY Branch Report Date: 11/09/11 Work Order: C11100844 Analyte Count Result Units RL %REC Low Limit High Limit RPO RPOLimit Qual Method: A4500-CI B Sample 10: MBLK9-111021 Chloride Sample 10: C11100844-007A Chloride Sample 10: C11100844-007A Chloride Sample 10: LCS35-111021 Chloride Method: A4500-CI B Sample 10: MBLK9-111024 Chloride Sample 10: C11100844-023AMS Chloride Sample 10: C11100844-023AMSO Chloride Sample 10: C11100844-028AMS Chloride Sample 10: C11100844-028AMSO Chloride Sample 10: LCS35-111024 Chloride Qualifiers: RL -Analyte reporting limit. Method Blank ND mg/L Sample Matrix Spike 259 mg/L Sample Matrix Spike Duplicate 259 mg/L Laboratory Control Sample 3450 mg/L Method Blank ND mg/L Sample Matrix Spike 173 mg/L Sample Matrix Spike Duplicate 173 mg/L Sample Matrix Spike 193 mg/L Sample Matrix Spike Duplicate 191 mg/L Laboratory Control Sample 3520 mg/L Batch: 111021-CL-TTR-W Run: TITRATION_111021 B 10/21/11 14:21 1.0 Run: TITRATION_111 021 B 10/21/11 16:55 1.0 103 90 110 Run: TITRATION_111021 B 10/21/11 16:56 1.0 103 90 110 0.0 10 Run: TITRATION_111 021 B 10/21/11 16:57 1.0 97 90 110 Batch: 111 024-CL-TTR-W Run: TITRATION_111024A 10/24/11 11 :32 1.0 Run: TITRATION_111024A 10/24/11 12:38 1.0 99 90 110 Run: TITRATION 111024A 10/24/11 12:39 - 1.0 99 90 110 0.0 10 Run: TITRATION_111024A 10/24/11 15:38 1.0 101 90 110 Run: TITRATION_111024A 10/24/11 15:39 1.0 99 90 110 1.2 10 Run: TITRATION_111024A 10/24/11 15:41 1.0 99 90 110 ND -Not detected at the reporting limit. Page 12 of 17 EI\ERGY LABORATORIES www.energylab.com J Analytical Exes/laneB Sines '952 _ '" Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 Gillette, WY866-686-7175 • Rapid City, SD 888-672-1225 • College Station, IX 888-690-2218 QA/QC Summary Report Prepared by Casper, WY Branch Client: Denison Mines USA Corp Report Date: 11/09/11 Project: 4th Quarter Nitrate 2011 Work Order: C11100844 Analyte Count Result Units RL %REC Low Limit High Limit RPO RPOLimit Qual Method: E353.2 Batch: R152715 Sample 10: MBLK-1 Method Blank Run: TECHNICON_111101A 11/01/1112:57 Nitrogen, Nitrate+Nitrite as N ND mg/L 0.10 Sample 10: LCS-2 Laboratory Control Sample Run: TECHNICON_1111 01 A 11/01/1113:00 Nitrogen, Nitrate+Nitrite as N 2.51 mg/L 0.10 100 90 110 Sample 10: LFB-3 Laboratory Fortified Blank Run: TECHNICON_1111 01 A 11/01/11 13:02 Nitrogen, Nitrate+Nitrite as N 1.95 mg/L 0.10 99 90 110 Sample 10: C11100844-006BMS Sample Matrix Spike Run: TECHNICON_111101A 11/01/1116:20 Nitrogen, Nitrate+Nitrite as N 2.07 mg/L 0.10 97 90 110 Sample 10: C11100844-006BMSO Sample Matrix Spike Duplicate Run: TECHNICON_1111 01 A 11/01/1116:22 Nitrogen, Nitrate+Nitrite as N 2.03 mg/L 0.10 95 90 110 2.0 10 Sample 10: C11100844-016BMS Sample Matrix Spike Run: TECHNICON_111101A 11/01/11 16:57 Nitrogen, Nitrate+Nitrite as N 6.51 mg/L 0.20 101 90 110 Sample 10: C11100844-016BMSO Sample Matrix Spike Duplicate Run: TECHNICON_111101A 11/01/1117:00 Nitrogen, Nitrate+Nitrite as N 6.53 mg/L 0.20 101 90 110 0.3 10 Method: E353.2 Batch: R152771 Sample 10: MBLK-1 Method Blank Run: TECHNICON_1111 02A 11/02/11 11 :17 Nitrogen, Nitrate+Nitrite as N ND mg/L 0.10 Sample 10: LCS-2 Laboratory Control Sample Run: TECHNI CON_1111 02A 11/02/11 11 :20 Nitrogen, Nitrate+Nitrite as N 2.30 mg/L 0.10 92 90 110 Sample 10: LFB-3 Laboratory Fortified Blank Run: TECHNICON_1 11102A 11/02/11 11 :22 Nitrogen, Nitrate+Nitrite as N 1.87 mg/L 0.10 95 90 110 Sample 10: C11100856-001JMS Sample Matrix Spike Run: TECHNI CON_1111 02A 11/02/11 11 :42 Nitrogen, Nitrate+Nitrite as N 2.11 mg/L 0.10 108 90 110 Sample 10: C11100856-001JMSO Sample Matrix Spike Duplicate Run: TECHNICON_111102A 11/02/11 11 :45 Nitrogen, Nitrate+Nitrite as N 2.04 mg/L 0.10 104 90 110 3.4 10 Sample 10: C11100848-0050MS Sample Matrix Spike Run: TECHNICON_111102A 11/02/1112:00 Nitrogen, Nitrate+Nitrite as N 2.83 mg/L 0.10 105 90 110 Sample 10: C11100848-0050MSO Sample Matrix Spike Duplicate Run: TECHNICON_111102A 11/02/11 12:02 Nitrogen, Nitrate+Nitrite as N 2.89 mg/L 0.10 108 90 110 2.1 10 Qualifiers: RL -Analyte reporting limit. ND -Not detected at the reporting limit. Page 13 of 17 EN:RGY LABORATORIES www.energylab.com Analytical ExcslllHlCB Sincs 1952 Helena, MT 877-472-0711 • Billings, MT 800-735-4489 • Casper, WY 888-235-0515 ~illette, WY 866-686-7175 • Rapid City, SO 888-672-1225 • College Station, TX 888-690-2218 Workorder Receipt Checklist 111111111111111111111111111111111111111111111111111111I Denison Mines USA Corp Login completed by: Edith McPike Reviewed by: BL2000\kschroeder Reviewed Date: 10/24/2011 Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? (Exclude analyses that are considered field parameters such as pH, DO, Res CI, Sulfite, Ferrous Iron, etc.) Containerffemp Blank temperature: Water -VOA vials have zero headspace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Yes 0" Yes 0" Yes 0 Yes 0" Yes 0" Yes 0" Yes 0" Yes 0" Yes 0" Yes 0" 2.4 "C On Ice Yes 0 Yes 0" C11100844 Date Received: 10/21/2011 Received by: ca No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier FedEx name: Not Present 0 Not Present 0 Not Present 0" No VOA vials submitted 0" Not Applicable 0 Page 14 of 17 '"U .~ (1) ~ (Jt o -~ ....... Chain of Custody and Analytical Request Record page_l_of~ lR;(r{.,y •• m.»Zf7.»a. PLEASE PRINT IProvide as much information as possible.} Company Name: 1~,tne.S Project Name, PWS, Permit, Etc. Sample Origin EPNState Compliance: D~;.sol\ 4th Q vart-u-J\H+rCk+~ State: ~..,.. Yes ~ No D Report Mail Address: PO T3(»)( g'O,\ Contact Name: Phone/Fax: Email: Sampler: (Please Print) 'B llknJ; 1'\ (\ ~T ~4~H "R~M PoJmer L.\3S b7g ~\ ~nner Ho lL'd~* Invoice Addre~ Invoice Contact & Phone: Purchase Order: Quote/Bottle Order: S~MC. S~f'I\<' Special ReporUFormats: ~&lb W@D@ ~~@l1D[g@1rc~@) .. Contact ELI prior to -ShIpped by: :;5: ~ -(;;'I. 0 "-RUSH sample submittal ~O(/)~ for charges and Cooler 10(5): ~CD3201 Q) I=' R ._> '0 >.~ 0 « scheduling -See C,t'eAf-D DW 0 EDD/EDT(Electronic Data) ~CI)~ !& ~ r:: UJ C Instruction Page 03:= ~ 0> I "'0 Rece~1 o POnNM/WTP Format: ~ () c:: Comments: u «~l-Q oS ::J U ...... ,-CDI~ « a \ 0 1: &~ j o State: D LEVEL IV ~ Q)jg C:'~ f-ro ~ a.('QI~o c o Other: D NELAC \l I-Cct!N ~(O • « 3 On Ice: ~~~I~~ ~ }-5 UJ -e Custody Seal E >1 .# UJ tt1 On Bottle ~: ('Q (/) "D (J) c:: On Cooler J ro U5 H Intact SAMPLE IDENTIFICATION Collection Collection {Name, Location, Interval, etc.} Date Time MATRIX Signature Y N Match 1 -rvJIJ -gR \o/n/l\ O"1'2>Q ~ ... W ~ I~ 2 --rwAJ -7 R \o/Jg/H 0700 1-W ,'1-I~ 3 TWN-\1 K \0/1'\/11 07\'1 :l-W X 1\9 Innn 4 "TWN-g \0117/\\ Og{)~ '? -'fJ .'J.. I~ I~ 5 J\lJN -l~ \O/t7/I\ octlD '2-vJ '" It:::=I ~ 6 ,WI\) _ \0 \O/lK/U Ob20 ~-\J 'A l~ 7 ~N-ll to/11tH 1.245 2-\J 'A II§ I~ 8 TWN-S \0/11111 \3'4D ~-'vJ X I~ 0) 9 TWN-\ IlO/J7/U \'-I;t,!> "l.-W IX ~ 1°TWtJ_ll.. 10/11/11 151~ l..-vJ 1-~ 'J!/ tJlJ X '-/Y Custody rr,:u;ed tt\\::L~ Datemme; Signal,;: irf Received by (print): DatelTime: Signature: Record ln/Q.l)/~OH Ht1D clt6i 6. -; Relinquished by (print): r DatefTlme: Signmtke: V Received by (print): DatelTime: Signature: MUST be /. Signed Kecelvea DY LabOratory: /u737e.,~ '?,~ rIe : M Sample Disposal: Return 10 Client: Lab Disposal: ~ ,..~ . In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule, forms, and links. Chain of Custody and Analytical Request Record Page ~ of2 "~If({fDY •• ',l.»Z".»I1.aW PLEASE PRINT (Provide as much information as possible.) Company Name: M Project Name, PWS, Permit, Etc. Sample Origin EPA/State Compliance: De..,\son ; n~~ 11Th Q~wtcr AJ;-t('(htc State: \.X\ Yes ~ No D Report Mail Address: 1'D BD~ goq Contact Name: Phone/Fax: Email: Sampler: (Please Print) 131M~~nC\ \X, fit.t511 R~M ?().\(Y1U y~ b78 ~t ~ntl<i Hoj)'4",/ Invoice AddreSS:-' Invoice Contact & Phone: Purchase Order: Quote/Bottle Order: s,,,,,,c.. S",.,,< Special ReporUFormats: &Iill&[b W®D® OOrn®M[g@l1rn® • Contact ELI prior to Shipped by: s: P.e-~~ 0 03 RUSH sample submittal U'lOtJ).c t=" for charges and Codler 10(8): ~aJ;g51 03 0 « R scheduling -See C(,€t'l t-._> 0 >om w C I nstruction Page o DW D EDD/EDT(Electronic Oata) .::sCl.)CI.)m~ c Cis tJ) t-:c o$:= ~ 0> "0 ReceiPtJiP , D POTWNVWTP Format: () c: Comments: ~«~I.Q~ ~ :::l U o State: D LEVEL IV ° .... COl c: « e i), °c,,~ Qj Q) c'-I-m ] C.:rol~ C5 c: D Other: D NELAC E~ro ' \} I-.... On Ice: @N « :::l :::l (1).= Q) s: l-S zo..«laro 1l W "E Custody Seal ~ >1 W m On Bottle ~ )!. (J) "0 CI.) c: On Coo1er ~ ]! H Intact SAMPLE IDENTIFICATION Collection Collection en (Name, Location, Interval, etc.) Date Time MATRIX '3 Signature y, N Match ",t=- 1 TvJN-'7 \O/I'l/II O~~ ;)...-\J 't I~ 2 TwN '*'-\ lO/lg/JI 080~ 2.-vJ "I-I~ 3 '-WN~ b \o/lg/)I 089-. :l.-W ~ 1\9) Illnn 4 TW.AJ-\5 ID/lq/ll Ob.;lg ;t~'tJ 'k I~ I~ 5 1VJ 1\)-\g \O/H~/l , )IOb 2-YJ k I~ ~ 6-rwN-\b \O/lt</H \;L3~ ~-W 'f.... ~ 7 TW!J-\~ 110/19/ II Ob3b 2-'vJ 1 ~ ~ 8 "TWN-t~ \Ollg/II )~3g ~-W 'j. I~ 01 9 1wN-17 \O/a.O/t \ 010S '-.-w I~ I~ I~ 1°-rwN-9 \O/~O/Il O~~ ~-W ~ 1~#/;;lifW Custody ~~~:~ed ~~Il~l,,~ \O/;lD/~~~e: H~o SignCl ~jf.L Received by (print): Date/Time: Signature: --r -... ,:j ....... 40 ~ Record "\ Relinquished by (print): -0 Date/Time: Signature: ...,J Received by (print): Date/Time: Signature: MUST be /1 Signed Kecelvea Dy L3lX1ratory: rorq~'r,ef q·~K rZa;:~~D Sample Disposal: Return to Client: Lab Disposal: In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab,com for additional information, downloadable fee schedule, forms, and links. Chain of Custody and Analytical Request Record Page~of~ ,.~.({."y m':l.tilti.uni, Com pany Name: 1 Den\~on M:r'\es Report Mail Address: PO B\:)}C. &>9 B \ u.nA;ncy lA, Z '1 E>\ I I nvoice Address: S"r'\c. Special ReporUFormats: DDW D EDD/EDT(Electronic Data) o POlWIWWTP D State: ----o Other: ---- SAMPLE IDENTIFICATION Format:. ____ _ D LEVEL IV o NELAC Collection Collection (Name, Location, Interval. etc.) Date Time 1 "'\WN-~ lbl;lL)/l1 0"40 2 TWN--~ )O/~()/l( Ob:;O 3 PlG"Z-") \O/l~/ J t \~lS : Pi c-z. -;t )o/Ifi/l! \2""\.5 5 P'CZ-3 \o/l~/lI }.23C 6 U~Lf lo/lC\/l1 r~oo 7 TvJN-bS loll'''' O~O~ 8 TvJN"10 lo/'-D/n 070~ 9 TW Aol-(J:) lo/l~/H \~!::> 10 PLEASE PRINT (Provide as much information as possible.) Project Name, PWS, Permit, Etc . .l._ I Sample Origin L\Th Q~tGr N ·(\-r~"1l.': State: \.(i EPA/State Compliance: Yes'gf No 0 Contact Name: Phone/Fax: Email: Sampler: (Please Print) R~",(\ p~p'er 4~5 "78 ,2;u.\ -':"ner ~o H;J~'f' Invoice Contact & Phone: Purchase Order: Quote/Bottle Order: SNl"C: s: ~&[S Y1@D® !lJ@:®(!D~llrn[Q) .1 Contact ELI prior to ::in I RUSH sample submittal o .... ~O(/)~ ~co;gOI <i; '-> 0 >-Cti ~U)~ m $: t'--0:::..-CI) -u:::" '0 ~ g> til o«~lml~ ~ .... as.!B c: .;:: ~~I~C \l E ~>CIl • .... -:::.. j (1).-Q):> ~ Z Ci. «I g'o .,... E >1 \1 tA k J MATRIX ')..-'vJ )( ;t-w ~ ~-W '/. l-\N i)( ~-w y. :l-vJ 'f... ;2-\\1 ~ ;J.-'vJ 'f. 2-\0 y. i=' R for charges and Q <{ scheduling -See W t:, I nstruction Page :r: "0 U c Comments: j U « e .... ro .... E « :J l-S W "E Custody Seal W ro o"~ttI. ~N en "0 011 Cooler N c: ell U5 H Intact Y N Signature Y N Match CustOdY~:~H:m~~ }o/;;';;\ II~ _}~n~ Received by (print): DateJTime: Received by (print): Dateliime: Signature: Record Relinquished by (print): 0 Date/Time: Signature: ~ MUSTbeL-----------------------------~==~=m~--~~~~~_r~~ Signed Sample Disposal: Return to Client: Lab Disposal: A ~T,j',Ti' q~35 {M~01~~ In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certifled laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Vi~it our web site at www.eneravlab.com for additional information, downloadable fee schedule, forms, and links. TabH Quality Assurance and Data Validation Tables H-1 Field Data QAlQC Evaluation Volume ,; '~-, i;~ , ',", :~ & ~" Location 2x Casing Volume Pumped Volume Check C5)nductivity ,RfP ,pH -' I.!' RPD:, Te~p " 'RPD S '" Piezometer 1 --2229.0 NC 7.87 NC 15.02 NC Piezometer 2 --595.4 NC 8.83 NC 16.24 NC Piezometer 3 --3146.0 NC 12.11 NC 15.00 NC TWN-l 40.17 80.34 100.00 OK 800.0 801.0 0.12 7.14 7.14 0.00 14.98 14.98 0.00 TWN-2 50.31 100.62 67.00 Pumped Dry 2645.0 NC 6.67 NC 15.14 NC TWN-3 41.69 83.38 50.00 Pumped Dry 2514.0 NC 7.06 NC 14.39 NC TWN-4 56.54 113.08 140.00 OK 1007.0 1007.0 0.00 7.15 7.15 0.00 14.22 14.23 0.07 TWN-5 52.38 104.76 110.00 OK 3076.0 3073.0 0.10 6.62 6.62 0.00 14.84 14.84 0.00 TWN-6 36.09 72.18 80.00 OK 1462.0 1467.0 0.34 6.94 6.93 0.14 14.56 14.56 0.00 TWN-7 10.64 21.28 14.00 Pumped Dry 1271.0 NC 7.26 NC 14.72 NC TWN-8 54.78 109.56 130.00 OK 2434.0 2436.0 0.08 7.00 7.00 0.00 14.39 14.38 0.07 TWN-9 21.92 43.84 30.00 Pumped Dry 2675.0 NC 6.76 NC 14.72 NC TWN-10 15.19 30.38 38.00 OK 3644.0 NC 4.36 NC 15.40 NC TWN-11 47.21 94.42 110.00 OK 2765.0 2762.0 0.11 6.70 6.67 0.45 14.67 14.67 0.00 TWN-12 51.84 103.68 120'.00 OK 2480.0 2477.0 0.12 7.00 7.02 0.29 14.57 14.57 0.00 TWN-13 48.13 96.26 110.00 OK 1227.0 1225.0 0.16 7.58 7.59 0.13 14.68 14.68 0.00 TWN-14 47.14 94.28 57.00 Pumped Dry 1091.0 NC 7.56 NC 15.19 NC TWN-15 41 82.00 60.00 Pumped Dry 1366.0 NC 6.92 NC 14.43 NC TWN-16 33.84 67.68 70.00 OK 1777.0 1766.0 0.62 7.03 7.01 0.28 14.42 14.42 0.00 TWN-17 49.56 99.12 68.00 Pumped Dry 1143.0 NC 7.50 NC 14.39 NC TWN-18 56.84 113.68 120.00 OK 2124.0 2124.0 0.00 6.80 6.81 0.15 14.23 14.24 0.07 TWN-19 37.31 74.62 80.00 OK 1966.0 1968.0 0.10 7.28 7.25 0.41 15.10 15.10 0.00 UWLP xc 171.0 NC 8.78 NC 17.10 NC '" -- Piezometers 1, 2, and 3 were not pumped, only one set of parameters were taken. TWN-2, TWN-3, TWN-7, TWN-9, TWN-14, TWN-15, and TWN-17 were purged to dryness before 2 casing volumes were removed. TWN-I0 was purged to dryness after 2 casing volumes were removed. UWLP is a pond grab sample, no pumRing was reguired and stabilization parameters are not a£plicable RPD > than 10% ',r '. " " " rn if, I , ' "; " .'~ ~edox Potential i RPD Turbidity .. '" RPD 307 NC 4.5 NC 206 NC 7.3 c NC 198 NC 1:4.2 NC 279 278 0.36 26.0 26.1 0.38 351 NC 24.6 NC 345 NC 59.0 NC 366 365 0.27 159.0 163.0 n 2.48 307 306 0.33 4.9 4.9 0.00 319 318 0.31 11.1 11.2 0.90 382 NC 11.1 NC 167 170 1.78 9.6 9.9 NC 351 NC 16.1 NC 465 NC 46.9 NC 305 305 0.00 12.4 12.4 0.00 214 216 0.93 138.0 140.0 1.44 295 292 1.02 22.0 22.3 1.35 270 NC 46.2 ~ NC 327 NC 18.9 NC 306 306 0.00 0.0 0.0 0.00 393 NC l1li 60.0 NC 362 362 0.00 63.0 ~ 64.0 1.57 296 295 0.34 6.6 6.6 0.00 268 NC 12.6 NC ------~----~--~--------------------------------------------------------------------------------------------------------------~------------------~----------~ The QAP states that turbidity should be less than 5 Nephelometric Turbidity Units ("NTU") prior to sampling unless the well is characterized by water that has a higher turbidity. The QAP does not require that turbidity measuremepts be less than 5 NTU prim to saIDp'ling. As such, the noted observations regarding turbidity-measurements less than 5 NTU below are included for information u~oses only. H-2: Holding Time Evaluation , Allowed Holding e . , bah Analysis Holding Time Location ConstitlJent Sample Collection Date Data , Holding Time . Time Check Piezometer 1 Chloride 10119111 10/24/11 5.00 days 28 days OK Piezometer 1 Nitrogen 10119111 1111111 13.00 days 28 days OK Piezometer 2 Chloride 10119111 10/24111 5.00 days 28 days OK Piezometer 2 Nitrogen 10/19111 1111111 13.00 days 28 days OK Piezometer 3 Chloride 10/19111 10/24111 5.00 days 28 days OK Piezometer 3 Nitrogen 10/19/11 1111111 13.00 days 28 days OK TWN-1 Chloride 10117111 10121111 4.00 days 28 days OK TWN-1 Nitrogen 10/17/11 1111111 15.00 days 28 days OK TWN-2 Chloride 10/20111 10/24111 4.00 days 28 days OK TWN-2 Nitrogen 10/20/11 1111111 12.00 days 28 days OK TWN-3 Chloride 10120111 10/24111 4.00 days 28 days OK TWN-3 Nitrogen 10120111 1111111 12.00 days 28 days OK TWN-4 Chloride 10118/11 10121111 3.00 days 28 days OK TWN-4 Nitrogen -10118/11 1111111 14.00 days 28 days OK TWN-5 Chloride 10117111 10/21111 4.00 days 28 days OK TWN-5 Nitrogen 10117111 1111111 15.00 days 28 days OK TWN-6 Chloride 10118/11 10/21111 3.00 days 28 days OK TWN-6 Nitrogen 10/18/11 1111111 14.00 days 28 days OK TWN-7 Chloride 10/19/11 10/21111 2.00 days 28 days OK TWN-7 Nitrogen 10119/11 1111111 13.00 days 28 days OK TWN-8 Chloride 10117/11 10/21111 4.00 days 28 days OK TWN-8 Nitrogen 10117/11 1111111 15.00 days 28 days OK TWN-9 Chloride 10/20/11 10/24/11 4.00 days 28 days OK TWN-9 Nitrogen 10120111 1111111 12.00 days 28 days OK TWN-10 Chloride 10/18/11 10/21111 3.00 days 28 days OK TWN-10 Nitrogen 10/18/11 1111111 14.00 days 28 days OK TWN-11 Chloride 10/17/11 10/21111 4.00 days 28 days OK TWN-11 Nitrogen 10117111 1111111 15.00 days 28 days OK TWN-12 Chloride 10/17/11 10/21111 4.00 days 28 days OK TWN-12 Nitrogen 10/17111 11/1111 15.00 days 28 days OK TWN-13 Chloride 10/17/11 10/21111 4.00 days 28 days OK TWN-13 Nitrogen 10/17/11 1111111 15.00 days 28 days OK TWN-14 Chloride 10119111 10/24/11 5.00 days 28 days OK TWN-14 Nitrogen 10119111 1111111 13.00 days 28 days OK TWN-15 Chloride 10/19111 10/24111 5.00 days 28 days OK TWN-15 Nitrogen 10/19111 1111111 13.00 days 28 days OK TWN-16 Chloride 10/18/11 10124111 6.00 days 28 days OK TWN-16 Nitrogen 10/18/11 1111111 14.00 days 28 days OK TWN-17 Chloride 10/20111 10/24/11 4.00 days 28 days OK TWN-17 Nitrogen 10120111 1111111 12.00 days 28 days OK TWN-18 Chloride 10/18111 10/24111 6.00 days 28 days OK TWN-18 Nitrogen 10118/11 1111111 14.00 days 28 days OK TWN-19 Chloride 10118/11 10/24111 6.00 days 28 days OK TWN-19 Nitrogen 10118/11 1111111 14.00 days 28 days OK TWN-65 Chloride 10/18/11 10/24111 6.00 days 28 days OK TWN-65 Nitrogen 10/18/11 1112/11 15.00 days 28 days OK UWLP Chloride 10119111 10124111 5.00 days 28 days OK UWLP Nitrogen 10/19/11 1112/11 14.00 days 28 days OK TWN-70 Chloride 10/20/11 10/24/11 4.00 days 28 days OK TWN-70 Nitrogen 10120111 1112/11 13.00 days 28 days OK H-3: Analytical Method Check Parameter Meth:od . >., Meth.od Used by Lab fi . Nitrate E353.2 E353.2 Chloride A4500-CI B A4500-CI B Both Nitrate and Chloride were analyzed with the correct analytical method. H-4: Reporting Limit Evaluation K ;" -,-, i-ab -Reporting . Rqd.' Reporting --Location Constituent ' Sampling Result Limit Lhnit _ Qualifier, Piezometer 1 Chloride 55 mg/L 1 mg/L 1 mg/L Piezometer 1 Nitrogen 6.6 mg/L 0.5 mg/L 0.1 mg/L D Piezometer 2 Chloride 8 mg/L 1 mg/L 1 mg/L Piezometer 2 Nitrogen 0.1 mg/L 0.1 mg/L 0.1 mg/L Piezometer 3 Chloride 12 mg/L 1 mg/L 1 mg/L Piezometer 3 Nitrogen 1.7 mg/L 0.1 mg/L 0.1 mg/L TWN-l Chloride 10 mg/L 1 mg/L 1 mg/L TWN-l Nitrogen 0.5 mg/L 0.1 mg/L 0.1 mg/L TWN-2 Chloride 76 mg/L 1 mg/L 1 mg/L TWN-2 Nitrogen 33 mg/L 1 mg/L 0.1 mg/L D TWN-3 Chloride 129 mg/L 1 mg/L 1 mg/L TWN-3 Nitrogen 25 mg/L 1 mg/L 0.1 mg/L D TWN-4 Chloride 20 mg/L 1 mg/L 1 mg/L TWN-4 Nitrogen 0.9 mg/L 0.1 mg/L 0.1 mg/L TWN-5 Chloride 45 mg/L 1 mg/L 1 mg/L TWN-5 Nitrogen 0.3 mg/L 0.1 mg/L 0.1 mg/L TWN-6 Chloride 21 mg/L 1 mg/L 1 mg/L TWN-6 Nitrogen 1.4 mg/L 0.1 mg/L 0.1 mg/L TWN-7 Chloride 6 mg/L 1 mg/L 1 mg/L TWN-7 Nitrogen 2.2 mg/L 0.1 mg/L 0.1 mg/L TWN-8 Chloride 10 mg/L 1 mg/L 1 mg/L TWN-8 Nitrogen o mg/L 0.1 mg/L 0.1 mg/L U TWN-9 Chloride 134 mg/L 1 mg/L 1 mg/L TWN-9 Nitrogen 10.9 mg/L 0.5 mg/L 0.1 mg/L D TWN-I0 Chloride 33 mg/L 1 mg/L 1 mg/L TWN-I0 Nitrogen 0.2 mg/L 0.1 mg/L 0.1 mg/L TWN-ll Chloride 76 mg/L 1 mg/L 1 mg/L TWN-ll Nitrogen 1.6 mg/L 0.1 mg/L 0.1 mg/L TWN-12 Chloride 87 mg/L 1 mg/L 1 mg/L TWN-12 Nitrogen 1.2 mg/L 0.1 mg/L 0.1 mg/L TWN-13 Chloride 48 mg/L 1 mg/L 1 mg/L TWN-13 Nitrogen o mg/L 0.1 mg/L 0.1 mg/L U TWN-14 Chloride 27 mg/L 1 mg/L 1 mg/L TWN-14 Nitrogen 3.9 mg/L 0.2 mg/L 0.1 mg/L D TWN-15 Chloride 38 mg/L 1 mg/L 1 mg/L TWN-15 Nitrogen 1.3 mg/L 0.1 mg/L 0.1 mg/L TWN-16 Chloride 34 mg/L 1 mg/L 1 mg/L TWN-16 Nitrogen 2.6 mg/L 0.2 mg/L 0.1 mg/L D TWN-17 Chloride 71 mg/L 1 mg/L 1 mg/L TWN-17 Nitrogen 8.1 mg/L 0.5 mg/L 0.1 mg/L D TWN-18 Chloride 60 mg/L 1 mg/L 1 mg/L TWN-18 Nitrogen 1.9 mg/L 0.1 mg/L 0.1 mg/L TWN-19 Chloride 108 mg/L 1 mg/L 1 mg/L TWN-19 Nitrogen 6.5 mg/L 0.5 mg/L 0.1 mg/L D TWN-65 Chloride 18 mg/L 1 mg/L 1 mg/L TWN-65 Nitrogen 0.9 mg/L 0.1 mg/L 0.1 mg/L UWLP Chloride o mg/L 1 mg/L 1 mg/L U UWLP Nitrogen o mg/L 0.1 mg/L 0.1 mg/L U TWN-70 Chloride 74 mg/L 1 mg/L 1 mg/L TWN-70 Nitrogen 8.6 mg/L 0.5 mg/L 0.1 mg/L D U = Analyte was not detected at the RL D = RL was increased due to sample matrix or required dilution due to the sample concentration. In all cases the analytical results were greater than the reporting limit used. -< - H-5 QAlQC Evaluation for Sample Duplicates .. Constituent . TWN-17 TWN-70 %RPD· Chloride 71 74 4.14 Nitrogen 8.1 8.6 5.99 Constituent TWN':4 TWN-65 %RPD Chloride 20 18 10.53 Nitrogen 0.9 0.9 0.00 H-6 QC Control Limits for Analysis and Blanks All QC control limits for the 4th quarter of201l were within acceptable limits. H-7 Receipt Temperature Evaluation Sample Batch . Wells in Batch Temperature. !. Piezometer I,Piezometer 2, Piezometer 3, TWN-I,TWN-2, TWN-3, TWN-4,TWN-5, TWN-6, TWN-7 ,TWN-7R, TWN- CIll00844 8,TWN-8R, TWN-9,TWN-IO, TWN-II,TWN-IIR,TWN-2.4°C I2,TWN-13, TWN-14,TWN-I5,TWN-I6, TWN-I7, TWN-I8, TWN-I9, TWN-60,TWN-65,TWN-70,UWLP H-8 Rinsate Evaluation Previous Rinsate Sample Parameter Rinsate Result Well Sample TWN-7R Nitrogen ND mg/L TWN-12 TWN-7R Chloride 1 mg/L TWN-12 TWN-8R Nitrogen ND mg/L N/A TWN-8R Chloride ND mg/L N/A TWN-17R Nitrogen ND mg/L TWN-19 TWN-17R Chloride ND mg/L TWN-19 TWN-60 Nitrogen ND mg/L NA TWN-60 Chloride 6 mg/L NA The Rmsate sample IdentIfied m Column 1 was collected after the pump was used to purge the well identified as "Previous Well Sampled" in Column 4 D = Reporting limit raised due to dilution/sample matrix. Reporting Result for Well Qualifier Limit 1.2 mg/L 0.1 mg/L 87 mg/L 1mg/L N/A 0.1 mg/L N/A 1mg/L 6.5 mg/L 0.1 mg/L 108 mg/L D 1mg/L NA 0.1 mg/L NA 1mg/L Tab I Kriged Current Quarter Isoconcentration Maps NS = not sampled; NO = not detected iII1W-4 ~5.1 TW4-1 0 6.6 TWN-1 <C/O.5 PIEZ-1 e 6.6 TW4-27 ~NS perched monitoring well showing concentration in mg/L temporary perched monitoring well showing concentration in mg/L temporary perched nitrate monitoring well showing concentration in mg/L perched piezometer showing concentration in mg/L temporary perched monitoring well installed October 2011 (not sampled) HYDRO GEO CHENl, INC. KR~GElD 4th QUARTERs 2011 N~TRA TE ~mg/l} «N~TRA Te + Nl~TR~TE AS N) WH~T!E MESA S~TE APPROVED DATE REFERENCE FIGURE H:/718000/feb12/Unt1211.srf I-I NS = not sampled; ND = not detected MW-4 @40 TW4-1 0 37 TWN-1 ~10 PIEZ-1 e 55 TW4-27 ~NS perched monitoring well showing concentration in mg/L temporary perched monitoring well showing concentration in mg/L temporary perched nitrate monitoring well showing concentration in mg/L perched piezometer showing concentration in mg/L temporary perched monitoring well installed October, 2011 (not sampled) HYDRO GEO CHJEM, INCo KR~GED 4th QUAR1fER~ ~011 CHlORJDE ~m9J/l~ WH~rE MESA SITE APPROVED DATE REFERENCE FIGURE H:J718000/feb12/Ucl1211.srf I-2 TabJ Analyte Concentrations Over Time TWN-l Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 0.7 19 7/21/2009 0.4 17 9/21/2009 0.4 19 10/28/2009 0.5 18 3/17/2010 0.5 17 5/26/2010 0.6 20 9/27/2010 0.6 19 12/7/2010 0.6 14 1/26/2011 0.5 17 4/20/2011 0.5 19 7/26/2011 0.5 14 10/17/2011 0.5 10 TWN-2 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 25.4 29 7/21/2009 25 25 9/21/2009 22.6 17 11/2/2009 20.8 55 3/24/2010 62.1 85 6/2/2010 69 97 9/29/2010 69 104 12/9/2010 48 93 2/1/2011 43 93 4/28/2011 40 85 7/28/2011 33 74 10/20/2011 33 76 TWN-3 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 23.6 96 7/21/2009 25.3 96 9/21/2009 27.1 99 11/2/2009 29 106 3/25/2010 25.3 111 6/3/2010 26 118 7/15/2010 27 106 12/10/2010 24 117 2/1/2011 24 138 4/28/2011 26 128 7/29/2011 25 134 10/20/2011 25 129 TWN-4 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 1 13 7/21/2009 0.05 12 9/21/2009 0.4 13 10/28/2009 0.4 11 3/16/2010 0.9 22 5/27/2010 1.0 22 9/27/2010 0.9 19 12/8/2010 1 21 1/25/2011 0.9 21 4/20/2011 0.9 21 7/26/2011 1.1 35 10/18/2011 0.9 20 TWN-5 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 0.22 42 9/21/2009 0.5 45 11/10/2009 0.2 48 3/16/2010 0.3 43 5/26/2010 0.3 44 7/12/2010 0.3 43 12/7/2010 0.3 45 1/25/2011 0.4 47 4/20/2011 0.3 44 7/26/2011 0.3 44 10/17/2011 0.3 45 TWN-6 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 3.2 32 9/22/2009 1.6 13 11/3/2009 1.4 21 3/23/2010 1.5 19 6/1/2010 1.4 22 7/13/2010 1.4 73 12/8/2010 1.2 21 1/26/2011 1.1 18 4/20/2011 1.5 22 7/27/2011 1.1 17 10/18/2011 1.4 21 TWN-7 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 ND 11 9/21/2009 ND 7 11/10/2009 0.1 7 3/17/2010 0.8 6 5/28/2010 1.2 6 7/14/2010 1.6 7 12/10/2010 1 4 1/27/2011 1.3 6 4/21/2011 1.7 6 7/29/2011 0.7 5 10/19/2011 2.2 6 TWN-8 Date Nitrate (mg/I) Chloride (mg/I) Notes 8/25/2009 0 11 Nitrate is N D 9/21/2009 0 12 Nitrate is ND 11/10/2009 0 12 Nitrate is ND 3/16/2010 0 11 Nitrate is ND 5/26/2010 0 11 Nitrate is ND 7/12/2010 0 11 Nitrate is ND 12/6/2010 0 9 Nitrate is ND 1/25/2011 0 13 Nitrate is ND 4/18/2011 0 10 Nitrate is ND 7/26/2011 0 18 Nitrate is ND 10/17/2011 0 10 Nitrate is ND TWN-9 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 9.3 169 9/22/2009 8.9 201 11/10/2009 12 205 3/23/2010 7.6 183 6/1/2010 7.6 175 7/15/2010 10.7 210 12/9/2010 8 172 2/1/2011 9.5 217 4/28/2011 10 192 7/29/2011 11 208 10/20/2011 10.9 134 TWN-l0 Date Nitrate (mg/I) Chloride (mg/I) 8/25/2009 1.1 19 9/22/2009 1.6 35 11/10/2009 1.4 26 3/23/2010 1.5 54 6/4/2010 1 30 7/14/2010 0.2 21 12/8/2010 1.3 28 1/27/2011 0.3 40 4/21/2011 1.2 28 7/27/2011 0.1 28 10/18/2011 0.2 33 TWN-11 Date Nitrate (mg/I) Chloride (mg/I) 11/3/2009 1.3 74 3/17/2010 1.4 73 6/4/2010 1.3 72 9/27/2010 1.4 76 12/8/2010 1.4 72 1/27/2011 1.4 84 4/26/2011 1.4 76 7/27/2011 0.1 76 10/17/2011 1.6 76 TWN-12 Date Nitrate (mg/I) Chloride (mg/I) 11/3/2009 0.5 109 3/17/2010 0.7 113 5/26/2010 0.8 106 7/12/2010 0.7 112 12/7/2010 0.7 103 1/26/2011 4.2 87 4/26/2011 1 109 7/26/2011 0.6 102 10/17/2011 1.2 87 TWN-13 Date Nitrate (mg/I) Chloride (mg/I) Notes 11/4/2009 0.5 83 3/17/2010 0 47 Nitrate ND 5/26/2010 0.1 49 9/27/2010 0.2 53 12/7/2010 0.4 57 1/25/2011 1.6 103 4/26/2011 0 49 Nitrate ND 7/26/2011 0.1 49 10/17/2011 0 48 Nitrate ND TWN-14 Date Nitrate (mg/I) Chloride (mg/I) 11/4/2009 3.4 32 3/24/2010 2.9 24 6/2/2010 2.9 30 7/15/2010 3.5 26 12/10/2010 4.2 28 1/28/2011 3.7 24 4/27/2011 3.5 30 7/29/2011 3.5 25 10/19/2011 3.9 27 TWN-15 Date Nitrate (mg/I) Chloride (mg/I) 11/10/2009 1.1 78 3/18/2010 0.7 43 5/28/2010 1.0 39 7/13/2010 1.0 36 12/9/2010 1.2 38 1/27/2011 1.4 43 4/27/2011 1.6 49 7/28/2011 1.6 47 10/19/2011 1.3 38 TWN-16 Date Nitrate (mg/I) Chloride (mg/I) 11/4/2009 1 39 3/17/2010 1.2 35 5/27/2010 0.2 35 9/27/2010 2.6 35 12/9/2010 2 30 1/27/2011 4.6 34 4/27/2011 1.6 39 7/27/2011 2.4 31 10/18/2011 2.6 34 TWN-17 Date Nitrate (mg/I) Chloride (mg/I) 11/4/2009 6.7 152 3/24/2010 10.4 78 6/3/2010 11 87 7/15/2010 8.9 66 12/10/2010 8 65 2/1/2011 8.6 90 4/28/2011 9 81 7/29/2011 8.5 74 10/20/2011 8.1 71 TWN-18 Date Nitrate (mg/I) Chloride (mg/I) 11/2/2009 1.3 57 3/17/2010 1.6 42 6/1/2010 1.8 63 9/27/2010 1.8 64 12/9/2010 1.6 59 1/27/2011 1.4 61 4/26/2011 1.8 67 7/28/2011 1.8 65 10/18/2011 1.9 60 TWN-19 Date Nitrate (mg/I) Chloride (mg/I) 11/2/2009 7.4 125 3/23/2010 7.2 118 6/1/2010 6.2 113 9/29/2010 7.2 113 12/9/2010 7 107 2/1/2011 7 114 4/28/2011 6.9 120 7/28/2011 7.1 113 10/18/2011 6.5 108 Piezometer 1 Date Nitrate (mg/I) Chloride (mg/I) 2/19/2009 6.8 NA 7/14/2009 6.8 60 9/22/2009 7.3 78 10/27/2009 7.4 61 6/2/2010 7.2 52 7/19/2010 6.8 52 12/10/2010 6.5 60 1/31/2011 7 60 4/25/2011 6.8 58 7/25/2011 7 53 10/19/2011 6.6 55 Piezometer 2 Date Nitrate (mg/I) Chloride (mg/I) 2/19/2009 0.5 NA 7/14/2009 0.5 7 9/22/2009 0.5 17 10/27/2009 0.6 7 6/2/2010 0.6 8 7/19/2010 0.6 8 12/10/2010 0.2 6 1/31/2011 0.3 9 4/25/2011 0.3 8 7/25/2011 0.1 9 10/19/2011 0.1 8 Piezometer 3 Date Nitrate (mg/I) Chloride (mg/I) 2/19/2009 0.7 NA 7/14/2009 0.8 12 9/22/2009 0.8 24 10/27/2009 1.2 19 3/24/2010 1.7 116 6/2/2010 1.6 36 7/19/2010 1.6 35 12/10/2010 1.8 25 1/31/2011 1.8 40 4/25/2011 1.7 35 7/25/2011 1.8 61 10/19/2011 1.7 12 Piezometer 4 Date 7/14/2009 Nitrate (mg/I) Chloride (mg/I) 1.8 46 Piezometer 5 Date 7/14/2009 Nitrate (mg/I) 0.7 Chloride (mg/I) 18 MW-18 Date Nitrate (mg/I) Chloride (mg/I) 7/14/2009 ND 51 MW-19 Date Nitrate (mg/I) Chloride (mg/I) 7/14/2009 2.2 24 Upper Wildlife Pond Date Nitrate (mg/I) Chloride (mg/I) Note 9/22/2009 0 5 Nitrate ND 10/27/2009 0 3 Nitrate ND 6/2/2010 0 0 Nitrate and Chloride ND 7/19/2010 0 0 Nitrate and Chloride ND 12/10/2010 0 1 Nitrate ND 1/31/2011 0.1 1 4/25/2011 0 0 Nitrate and Chloride ND 7/25/2011 0 0 Nitrate and Chloride ND 10/19/2011 0 0 Nitrate and Chloride ND Frog Pond Date 10/14/09 Nitrate (mg/I) o Chloride (mg/I) o Notes Nitrate ND TabK Concentration Trend Graphs tJ) t: 0 ;; m ~ .., t: CD (.) t: 0 (.) CD "C "£: .2 .t: (.) ~ I Z ~ ......------.,.------r--------r--------..,------.-G ~ -JdV ~ ~-das ~ ~-qa.::J o ~-5nv o~-uer ~-----+------+--------~-------~--------+go-~aa L() N o N (1/6w) o o tJ) c: 0 +:: C'a ... .., c: Q) (.) c: 0 U Q) .., C'a ... ~ Z N I Z ~ ~ ,-----r------,.---...,.-----..,...----r-----r----,...----....,.-l ~ -JdV ~ ~-das ~ ~-qa;j o~-6nv o~-uer ~----~------~----~------~-----+------+_-----+------+go-oaa o 00 o c.o o L{) o N o (/) c 0 ;: CO .... .... C Q) () C 0 (.) Q) "C "i: 0 .c (.) N • Z ~ ...------.------.,......-----r-----....,.-------,.------r--l ~-JdV ~ ~-das ~ ~-qa.::J o~-6nv o~-uer ~-------+--------~--------~-------4---------~--------+go-oao o N o o "('"'"" o ex:> o <0 o N o t/) c 0 ;; «S s-... C (1) CJ c 0 (J (1) ... «S s-:!: Z (II) I Z ~ ~---"'------r-----r"-----,------;-----r------r l ~-JdV ~ ~-das ~ ~-qa~ o~-5nv o~-uer ~------~------~------~------+-------+-------+-------+Bo-~aa o ('f) L(') N o N o f/) c 0 ;; CO s... .... C CD () c 0 (J CD "C "i: 0 ..c:: (J M I Z ~ ...-----,-------,.----,------r-----r------r----r------.-G ~ -JdV ~ ~-das ~ ~-qa=:J o~-6nv o~-uer r------+------+-----~------~------+_----_+------~----__+go-~aa o CD ~ o N ~ o o ~ o CO (1/6w) o CD o N o U) c 0 ;; CU ... ... c Cl) (.) c 0 (.) Cl) ... cu ... ~ Z ~ • Z ~ .,...-----.,.-----..,.------.,..-----r------,----..,.-l ~-JdV ~ ~-das ~ ~-qa::l o~-5nv o~-uer 60-lnr ~-------+--------~--------+_------~--------_r--------+go-oaa co o <.0 o (1/6w) N o o tJ) t: 0 +i ca ~ ..., t: Cl) U t: 0 (J Cl) "C ";:: 0 J: (J oq- I Z ~ r-----r-------,.---...,-------r---.,....------r----r-----,-l ~-Jd'V ~ ~-das ~ ~-qa::l o ~-5n'V o~-uer ~----~------~-----r------r_-----r------T_-----r------+go-oaa o ('I') LO N o N (1/6w) o o tn c: 0 +:; CO ~ .., c: (1) (.) c: 0 (.) (1) .., CO ~ :: z It) I Z ~ r-------~--------~--------~--------~--------~------~ ~~-~aa ~ ~-das ~ ~-unr ~ ~-qa~ o ~-l\oN o~-Bnv o ~-Aell\l o~-uer 60-PO 1-------+-------+-----+-----+----+-----+ 6o-lnr co o L!) o C') a (1/6w) N a o ~ ~-das ~ ~-unr ~ ~-qa~ tn t: 0 +:. cu ... O~-AON ... t: Cl) CJ t: 0 U Cl) "C o~-6nv ".: 0 .c: U It) I Z ~ o ~-l\eV\J o~-uer 60-PO f-----+-----+---+----+----+-----I--------1'----+ 60-lnr ~ ~-das ~ ~-unr ~ ~-qa.:l U) c 0 ; CO O~-AON L.. ... C CI) 0 C 0 U CI) ... o~-6nv CO L.. ~ Z (0 I Z ~ o ~-AeV'J o~-uer 60-PO !------i------f----+----+----+-----t-----t-60-lnr L!) N L!) o N a tn t: 0 ~ m s... .., t: Q) () t: 0 (.) Q) 'C "i: 0 J: (.) CO • Z ~ ~----~------~----~------~----~------~----~------~ ~~-oao ~ ~-das ~ ~-unr ~ ~-qa,:j o ~-J\oN o~-5nv o ~-l\eV\l o~-uer 60-PO 1-----1------+----+----+----1-----+----1-----1--60-lnr o ex:> o CO o LO o N o o t/) c 0 ;; ns L.. ... C CI) 0 c 0 (J CI) ... ns L.. ~ Z ,.... 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LL co o co o I C\I o ~~ o o 60-J\ON 60-100 60-deS 60-deS 60-BnV TabL CSV Transmittal Letter Kathy Weinel From: Sent: To: Cc: Subject: Attachments: Dear Mr. Lundberg, Kathy Weinel Wednesday, February 08, 2012 12:28 PM 'rlundberg @ utah.gov' 'Phillip Goble'; TRUSHING@utah.gov'; Ron Hochstein; Harold Roberts; David Frydenlund; Jo Ann Tischler; David Turk; Jaime Massey Transmittal of CSV Files White Mesa Mill 2011 Q4 Nitrate Monitoring C11100844.CSV Attached to this e-mail are electronic copies of laboratory results for nitrate monitoring conducted at the White Mesa Mill during,the fourth quarter of 2011, in Comma Separated Value (CSV) format. Please contact me at 303-389-4134 if you have any questions on this transmittal. Yours Truly Kathy Weinel Denison Mines (USA) Corp. Quality Assurance Manager 1