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HomeMy WebLinkAboutDRC-2025-002415 299 South Main Street, Suite 1700 ▪ Salt Lake City, Utah 84111 (801) 649-2000 ▪ Fax: (801) 880-2879 ▪ www.energysolutions.com July 30, 2025 CD-2025-153 Mr. Doug Hansen, Director Division of Waste Management and Radiation Control P.O. Box 144880 Salt Lake City, UT 84114-4880 Subject: Groundwater Quality Discharge Permit No. UGW450005 – First Semi-Annual 2025 Accelerated Groundwater Monitoring Report Dear Mr. Hansen: In accordance with Part I.H.1.b of Groundwater Quality Discharge Permit Number UGW450005 (Permit), this report summarizes the groundwater analytical data collected from monitoring wells under accelerated monitoring from January 1 through June 30, 2025. The report includes a data summary table (Table 1) that lists sampling dates, analytes, analytical results, and the compliance status for each well monitored during the first half of 2025. Additionally, the report provides a detailed discussion of each analyte and corresponding well. P3-95 SWC Compliance monitoring well P3-95 SWC has been in out-of-compliance (OOC) status for total uranium, uranium-234 (U-234), and uranium-238 (U-238) since September 2013. The most recent exceedances of Groundwater Protection Levels (GWPLs) at this well occurred from February through May 2025 (Table 1). EnergySolutions attributes these exceedances to stormwater infiltration caused by precipitation events. During this period, the Clive Facility experienced 51% of the 31-year average precipitation, as reported in the 2024 annual meteorological summary (Trinity Consultants, 2024). On March 15, 2024, the Director of the Division of Waste Management and Radiation Control granted conditional approval (DRC-2024-004377) for EnergySolutions’ plan to restore well P3-95 SWC to compliant status (CD-2023-204; October 9, 2023). This plan included tracer dye testing to evaluate transport pathways. Details of the planned actions were outlined to the Division on February 20, 2025 (CD-2025-035). EnergySolutions submitted a variance request to extend the deadline to begin the tracer dye test from April 25, 2025 to April 25, 2026 (CD-2025-081) due to the lack of precipitation needed to begin the test. The variance request was approved by the Division on May 19, 2025 (DRC-2025-001463). Groundwater extraction has been a demonstrated effective method of maintaining below- GWPL uranium concentrations in P3-95 SWC groundwater. To address remediation of groundwater containing elevated uranium concentrations, submittal CD-2023-204 proposes to perform groundwater extraction at well P3-95 SWC. The schedule for groundwater extraction will be coordinated with the tracer dye test, to optimize test Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 2 of 9 results, i.e., groundwater extraction will not occur during the tracer dye testing to prevent possible dilution of the dye in well P3-95 SWC groundwater. To eliminate the potential source of surface water infiltration in the vicinity of well P3-95 SWC, EnergySolutions has managed storm water in the north-south, road-side ditch near the well as Priority 1 under a temporary variance from DWMRC. On September 22, 2023 (DRC-2023-071888), DWMRC approved an extension of the temporary variance until September 22, 2026. Additional information for well P3-95 SWC is available in status reports for the first quarter (May 14, 2025; CD-2025-102) and second quarter (July 17, 2025; CD-2025-150) of 2025. GW-23 In accordance with Part I.G.2 of the Permit, on August 9, 2023, EnergySolutions provided notice that well GW-23 entered probable out-of-compliance (POOC) status for total uranium (CD-2023-159). The total uranium concentration of the 2023 annual monitoring sample, collected in May 2023, exceeded the GWPL. EnergySolutions believes the total uranium exceedance at well GW-23 was caused by variability of the natural concentration of uranium, possibly related to infiltration and groundwater mounding occurring west of the well location. Depth-to-water measurements collected during the first half of 2023 indicated mounding had occurred west of well GW-23 in response to drainage of non-contact water from the offset on the south side of the Class A West embankment. Despite the concentration increase, the U-234 to U-238 isotopic ratio of the 2023 annual sample remained consistent with the Clive Facility background ratio. Subsequent to the May 2023 exceedance, the total uranium concentrations of eight consecutive quarterly samples collected from well GW-23 have been less than the GWPL. This includes the samples collected during first and second quarters of 2025 (Table 1). Review of field parameters, radiological analytical data, U-234/U-238 ratios, and non-radiological analytical data provide no evidence of contamination in well GW- 23 groundwater. Based on data collected since the May 2023 exceedance, EnergySolutions submitted a request to return GW-23 to in-compliance status on June 24, 2025 (CD-2025-132) and the Division approved the request on July 23, 2025 (DRC- 2025-002209). GW-26 In accordance with Part I.G.2 of the Permit, on December 17, 2024, EnergySolutions provided notice that well GW-26 entered POOC status for total uranium (CD-2024-255). The total uranium concentration of the 2024 annual monitoring sample, collected in May 2024 (0.0377 milligrams per liter [mg/L]), exceeded the GWPL (0.037 mg/L). Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 3 of 9 EnergySolutions believes the total uranium exceedance at well GW-26 was caused by variability of the natural concentration of uranium, possibly related to infiltration and groundwater mounding occurring south of the well location. Depth-to-water measurements collected during the first half of 2024 indicated mounding had occurred in vicinity of well GW-26 in response to drainage of non-contact water from the offset on the south side of the Class A West embankment. Despite the concentration increase, the U-234/U-238 isotopic ratio of the 2024 annual sample remained consistent with the Clive Facility background ratio. Subsequent to the May 2024 exceedance, the total uranium concentrations of two consecutive quarterly samples collected from well GW-26 have been less than the GWPL. This includes the samples collected during first and second quarters of 2025 (Table 1). Review of field parameters, radiological analytical data, U-234/U-238 ratios, and non-radiological analytical data provide no evidence of contamination in well GW- 26 groundwater. GW-58 In accordance with Part I.G.2 of the Permit, on September 5, 2024, EnergySolutions provided notice that well GW-58 entered POOC status for total uranium (CD-2024-184). The total uranium concentration of the 2024 annual monitoring sample, collected in May 2024 (0.047 mg/L), exceeded the GWPL (0.046 mg/L). On January 22, 2025, EnergySolutions provided notice that well GW-58 entered POOC status for U-234 (CD- 2025-013). The U-234 concentration of the October 2024 4th quarter POOC sample (31.7 picoCuries per liter [pCi/L]) exceeded the GWPL (31.2 pCi/L). EnergySolutions believes the total uranium and U-234 exceedance at well GW-58 were caused by variability of the natural concentration of uranium, possibly related to infiltration and groundwater mounding occurring near the well location. Depth-to-water measurements collected during the first half of 2024 indicated mounding had occurred around GW-58 in response to drainage of non-contact water to the Southwest Corner Pond and infiltration from Pond spillway overflow. Despite the concentration increase, the U-234 to U-238 isotopic ratio of the 2024 annual sample and the 2024 4th quarter sample remained consistent with the Clive Facility background ratio. Subsequent to the May 2024 total uranium exceedance, samples from two consecutive quarters have been below the total uranium GWPL; however, the 2025 annual sample (0.048 mg/L) exceeded the GWPL (Table 1). Subsequent to the October 2024 exceedance for U-234, samples from two consecutive quarters have been below the U- 234 GWPL . This includes the samples collected during first and second quarters of 2025 (Table 1). Review of field parameters, radiological analytical data, U-234/U238 ratios, and non-radiological analytical data provide no evidence of contamination in well GW- 58 groundwater. Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 4 of 9 GW-77 In accordance with Part I.G.2 of the Permit, on November 20, 2019, EnergySolutions notified DWMRC that compliance monitoring well GW-77 entered POOC status for the sum of radiums (CD19-0234). The sum of radiums concentrations in the 2019 annual sample exceeded the background-based GWPL (5.46 pCi/L) established for this well. Radium-226 (Ra-226) and radium-228 (Ra-228) are naturally occurring radionuclides in Clive Facility groundwater. EnergySolutions believes the observed radium exceedance was caused by fluctuations in background concentrations that may be related to increased infiltration in the vicinity of the well due to above-average precipitation rates at the Clive Facility that occurred in the first half of 2019. Accelerated quarterly sampling of well GW-77 for Ra-226 and Ra-228 began in fourth quarter 2019. Sum of radiums with a GWPL equal to or near 5 pCi/L is a less than optimal metric for efficient groundwater compliance monitoring at the Clive Facility: • Background concentrations of the sum of radiums in Clive Facility groundwater commonly exceed the Permit universal GWPL of 5 pCi/L as documented by DRC/DWMRC approval of background-based GWPL exceptions for 20 compliance monitoring wells, including GW-77. • The universal GWPL of 5 pCi/L is a Maximum Contaminant Level (MCL) established for protection of drinking water due to the carcinogenic effects of radium (alpha/beta decay) when ingested. Clive Facility groundwater is naturally non-potable with high concentrations of dissolved solids due to its occurrence in saline lake-bed sediments. • Technical analytical factors, such as matrix interference, related to analysis of isotopic radium in saline groundwater may influence reported results. For the first half of 2025, the sum of radiums concentration in groundwater at well GW-77 did not exceed the GWPL (Table 1). Since the initial 2019 exceedance, well GW-77 has been sampled for 19 consecutive quarters. Only one subsequent exceedance of the sum of radiums GWPL has occurred during the 19-quarter period, the first quarter 2022 sample duplicate. Apparent concentration trends and seasonality patterns are not observed in the radium concentration data from the well. Linear regression of the entire well GW-77 sum of radiums data set, with duplicate results removed, provided a slope of 1.03-05 pCi/L per day. From the first sample collected on November 24, 1998, to the most recent sample, collected on May 16, 2024, regression estimates the sum of radiums concentration has increased by 0.10 pCi/L, which is less than the typical counting uncertainty reported for isotopic radium analyses. In addition, during the 19-month accelerated monitoring period, there have been no observed changes in the general chemistry, field parameter data, or U-234/U-238 ratio; and indication of contamination is not observed in the other radiological data from the annual samples collected from well GW-77. Any suggestion that contamination is causing a slow increase in the radium Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 5 of 9 concentration at well GW-77, or more broadly, slow increases in radium or uranium concentrations at other Clive Facility wells, with the exception of well P3-95 SWC, is not supported by groundwater chemistry data collected to date. Based on eight consecutive quarterly POOC samples with sum of radiums concentrations below the GWPL, on May 17, 2024 (CD-2024-110), EnergySolutions submitted a request to return well GW-77 to in-compliance status. EnergySolutions again requested a return to in-compliance status for GW-77 on February 5, 2025 (CD-2025-022). This request was approved by DWMRC on April 11, 2025 (DRC-2024-007488). GW-126 In accordance with Part I.G.2 of the Permit, on November 30, 2022, EnergySolutions notified DWMRC that compliance monitoring well GW-126 entered POOC status for the sum of radiums (CD-2023-198). The sum of radiums concentration of the 2022 annual monitoring sample exceeded the GWPL. The first quarterly sample was collected in December 2022. For the first half of 2025, the sum of radiums concentration of the annual sample collected in May 2025 (5.21 pCi/L) exceeded the GWPL (5 pCi/L) (Table 1). Since the initial 2022 exceedance, well GW-126 has been sampled for eleven consecutive quarters. Other subsequent GWPL exceedances occurred in the quarterly sample collected on August 17, 2023 and August 20, 2024. EnergySolutions believes the observed radium exceedances are caused by natural fluctuations in background concentrations possibly related to infiltration occurring in the vicinity of the well due to precipitation events at the Clive Facility. Laboratory analytical factors may also contribute to the sum of radium exceedances observed at well GW-126. Refer to submittals CD-2022-198, CD-2023-047, CD-2024-036 for additional discussion of analytical factors. GW-141 In accordance with Part I.G.2 of the Permit, on September 6, 2024, EnergySolutions notified DWMRC that compliance monitoring well GW-141 entered POOC status for selenium (CD-2024-185). The selenium concentration of the 2024 annual monitoring sample exceeded the GWPL. The first quarterly sample was collected in October 2024. Subsequent to the August 2024 exceedance, the selenium concentrations of POOC samples have not exceeded the GWPL (Table 1). EnergySolutions believes the observed selenium exceedances are caused by natural fluctuations in background concentrations possibly related to infiltration occurring in the vicinity of the well due to precipitation events at the Clive Facility. Laboratory analytical factors may also be the reason for the selenium exceedances observed at well GW-141. Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 6 of 9 CONCLUSIONS During the first half of 2025: • Well P3-95 SWC remained in OOC status for total uranium, U-234, and U-238. • Wells GW-23, GW-26 and GW-58 remained in POOC status for total uranium. A request to return to well GW-23 to in-compliance status was submitted on June 24, 2025 (CD-2025-132) based on the collection of eight consecutive quarterly samples with total uranium concentrations below the GWPL. This request was approved by the Division on July 23, 2025 (DRC-2025-002209). • Wells GW-77 and GW-126 were in POOC status for sum of radiums. GW-77 was returned to in-compliance status on April 11, 2025 (DRC-2024-007488). • Well GW-141 remained in POOC status for selenium. All accelerated monitoring samples collected at well P3-95 SWC during the first half of 2025 were less than the GWPLs for U-234 and U-238. Total uranium concentrations exceeded the GWPL in March and May of 2025. Total uranium, U-234, and U-238 exceedances at well P3-95 SWC reflect shallow subsurface contamination in the vicinity of the well. Correlation of periods of precipitation and infiltration with GWPL exceedances, and rapid concentration declines in response to groundwater extraction indicate the contamination source is located in the vadose zone. In response to observed exceedances during the first half of 2023, on October 9, 2023, EnergySolutions submitted a plan to return well P3-95 SWC to in- compliance status. DWMRC provided conditional approval of the plan on March 15, 2024. Details of the planned actions were further outlined to the Division on February 20, 2025 (CD-2025-035) and April 25, 2026 (CD-2025-081). Monthly OOC sampling for isotopic uranium continues at the well. The total uranium exceedances at wells GW-23, GW-26 and GW-58 reflect variations in the natural concentration of uranium in groundwater related to mounding and/or infiltration in the vicinity of these wells. Mounding to the west of well GW-23 may have affected groundwater conditions at the well. Since only one exceedance was observed at well GW-23, it is also possible the exceedance is related to analytical factors. GW-23 returned to annual sampling on July 23, 2025 (DRC-2025-002209). Quarterly POOC sampling for isotopic uranium will continue at wells GW-26 and GW-58. All accelerated monitoring samples collected at wells GW-77 and GW-126 during the first half of 2025 and analyzed for Ra-226 and Ra-228 were less than respective GWPLs for the sum of radiums, with the exception of the annual GW-126 sample collected in May. Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 7 of 9 Radium concentrations at wells GW-77 and GW-126 reflect variation in natural levels of Ra-226 and Ra-228 in groundwater. On May 17, 2024, EnergySolutions submitted a request to return well GW-77 to in-compliance status and again on February 5, 2025 (CD-2025-022). This request was approved by DWMRC on April 11, 2025 (DRC-2024- 007488) and well GW-77 was returned to annual monitoring. Quarterly POOC sampling for Ra-226 and Ra-228 continues at well GW-126. Quarterly POOC sampling of well GW-141 groundwater for selenium also continues. Groundwater sampling sheets, data validation worksheets, and analytical laboratory reports for accelerated groundwater samples collected during the first half of 2025 will be provided in the 2025 Annual Groundwater Monitoring Report, due on or before March 1, 2026. Should you have any questions regarding this submission please feel free to contact me at (801)649-2060. Sincerely, Mathew R. Schon Manager, Groundwater and Environmental Program I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 8 of 9 P3-95 SWC Total Uranium 1/14/2025 0.180 mg/l 0.141 mg/l Monthly OOC P3-95 SWC Dup. Total Uranium 1/14/2025 0.180 mg/l 0.149 mg/l Monthly OOC P3-95 SWC Total Uranium 2/11/2025 0.180 mg/l 0.134 mg/l Monthly OOC P3-95 SWC Dup. Total Uranium 2/11/2025 0.180 mg/l 0.127 mg/l Monthly OOC P3-95 SWC Total Uranium 3/11/2025 0.180 mg/l 0.187 mg/l Monthly OOC P3-95 SWC Dup. Total Uranium 3/11/2025 0.180 mg/l 0.167 mg/l Monthly OOC P3-95 SWC Total Uranium 4/24/2025 0.180 mg/l 0.163 mg/l Annual OOC P3-95 SWC Total Uranium 5/19/2025 0.180 mg/l 0.195 mg/l Monthly OOC P3-95 SWC Dup. Total Uranium 5/19/2025 0.180 mg/l 0.182 mg/l Monthly OOC P3-95 SWC Total Uranium 6/3/2025 0.180 mg/l 0.172 mg/l Monthly OOC P3-95 SWC Uranium-234 1/14/2025 48 pCi/l 26.0 ± 3.55 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-234 1/14/2025 48 pCi/l 28.6 ± 2.58 pCi/l Monthly OOC P3-95 SWC Uranium-234 2/11/2025 48 pCi/l 24.9 ± 2.94 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-234 2/11/2025 48 pCi/l 24.7 ± 1.95 pCi/l Monthly OOC P3-95 SWC Uranium-234 3/11/2025 48 pCi/l 24.5 ± 2.43 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-234 3/11/2025 48 pCi/l 30.7 ± 2.25 pCi/l Monthly OOC P3-95 SWC Uranium-234 4/24/2025 48 pCi/l 28.3 ± 2.59 pCi/l Annual OOC P3-95 SWC Uranium-234 5/19/2025 48 pCi/l 32.8 ± 2.27 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-234 5/19/2025 48 pCi/l 28.4 ± 2.14 pCi/l Monthly OOC P3-95 SWC Uranium-234 6/3/2025 48 pCi/l 29.8 ± 2.17 pCi/l Monthly OOC Table 1. Sampling Results for Wells in Accelerated Monitoring January through June 2025 Compliance StatusWell ID Analyte Sample Date GWPL Result Sampling Event Mr. Doug Hansen July 30, 2025 CD-2025-153 Page 9 of 9 P3-95 SWC Uranium-238 1/14/2025 79 pCi/l 46 ± 4.67 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-238 1/14/2025 79 pCi/l 49.0 ± 3.36 pCi/l Monthly OOC P3-95 SWC Uranium-238 2/11/2025 79 pCi/l 43.9 ± 2.57 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-238 2/11/2025 79 pCi/l 41.6 ± 2.52 pCi/l Monthly OOC P3-95 SWC Uranium-238 3/11/2025 79 pCi/l 61.4 ± 3.24 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-238 3/11/2025 79 pCi/l 55.0 ± 3.00 pCi/l Monthly OOC P3-95 SWC Uranium-238 4/24/2025 79 pCi/l 53.6 ± 3.55 pCi/l Annual OOC P3-95 SWC Uranium-238 5/19/2025 79 pCi/l 63.9 ± 3.16 pCi/l Monthly OOC P3-95 SWC Dup. Uranium-238 5/19/2025 79 pCi/l 59.8 ± 3.10 pCi/l Monthly OOC P3-95 SWC Uranium-238 6/3/2025 79 pCi/l 56.6 ± 2.99 pCi/l Monthly OOC GW-23 Total Uranium 2/6/2025 0.03 mg/l 0.015 mg/l Quarterly POOC GW-23 Total Uranium 5/15/2025 0.03 mg/l 0.015 mg/l Annual POOC GW-26 Total Uranium 2/6/2025 0.037 mg/l 0.035 mg/l Quarterly POOC GW-26 Total Uranium 5/8/2025 0.037 mg/l 0.034 mg/l Annual POOC GW-58 Total Uranium 2/11/2025 0.046 mg/l 0.044 mg/l Quarterly POOC GW-58 Total Uranium 4/17/2025 0.046 mg/l 0.048 mg/l Annual POOC GW-58 Uranium-234 2/11/2025 31.2 pCi/l 27.2 ± 1.89 pCi/l Quarterly POOC GW-58 Uranium-234 4/17/2025 31.2 pCi/l 27.9 ± 1.905 pCi/l Annual POOC GW-77 Ra-226+Ra-228 2/6/2025 5.46 pCi/l 4.12 pCi/l Quarterly POOC GW-77 Ra-226+Ra-228 5/6/2025 5.46 pCi/l 3.87 pCi/l Annual POOC GW-126 Ra-226+Ra-228 2/6/2025 5 pCi/l 4.33 pCi/l Quarterly POOC GW-126 Dup. Ra-226+Ra-228 2/6/2025 5 pCi/l 2.65 pCi/l Quarterly POOC GW-126 Ra-226+Ra-228 5/13/2025 5 pCi/l 5.21 pCi/l Annual POOC GW-141 Selenium 2/11/2025 0.0705 mg/L 0.0635 mg/l Quarterly POOC GW-141 Dup. Selenium 2/11/2025 0.0705 mg/L 0.0574 mg/l Quarterly POOC GW-141 Selenium 4/8/2025 0.0705 mg/L 0.0638 mg/l Annual POOC Note: Groundwater Protection Level (GWPL) exceedances are listed in bold. mg/l - milligrams per liter pCi/l - picoCuries per liter OOC - Out-of-Compliance status POOC - Probable Out-of-Compliance status J - validation qualifier. Result is estimated. Table 1. Sampling Results for Wells in Accelerated Monitoring January through June 2025 (continued) Well ID Analyte Sample Date GWPL Result Sampling Event Compliance Status