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HomeMy WebLinkAboutDWQ-2025-004873 Methylmercury Criterion for the Protection of Human Health: Criterion Support Document Matt Smiley set the catch and release record for lake trout in 2019. The fish was caught at Flaming Gorge and was 48 inches long. Photo credit: Matt Smiley. June 12, 2025 UTAH DIVISION OF WATER QUALITY Executive Summary In 2001, the U.S. Environmental Protection Agency (EPA) issued a new recommended water quality criterion for methylmercury to protect human health. The recommended methylmercury criterion is based on fish and shellfish tissue because over 99% of the mercury exposures to the U.S. population are from eating fish and shellfish. The main form of mercury in fish and shellfish is methylmercury. Methylmercury is made when bacteria methylate mercury in the aquatic environment. The recommended criterion is 0.3 mg/kg wet weight methylmercury in fish and shellfish tissues. Utah currently monitors mercury concentrations in fish and issues waterbody consumption advisories when concentrations exceed 0.3 mg/kg. The Utah Division of Water Quality recommends adoption of the 0.3 mg/kg wet weight methylmercury criterion to Utah’s list of water quality criteria for human health in R317-2 Table 2.14.6. Adoption of the methylmercury criterion may result in new impairment determinations for waters with existing fish consumption advisories. The adoption of the methylmercury criterion is not expected to substantially impact the UDPES permitting program because most waters affected by a consumption advisory are not impacted by permitted discharges. In addition, mercury discharges in UPDES permits are already required to comply with a stringent mercury water quality criterion of 0.000012 mg/l. UTAH DIVISION OF WATER QUALITY Contents 1.0 Introduction 1 1.1 Scope 1 1.2 Mercury in Utah Fish 1 1.3 Sources of Mercury in Utah. 2 1.4 EPA (2001) Methylmercury Criterion 2 2.0 Recommendations for Utah 4 2.1 Methylmercury Criterion 4 2.2 Implementation for Assessments and TMDLs 5 2.3 Implementation for UPDES Permits 5 2.4 Translators 6 2.5 Consumption Advisories 7 2.6 Recommended Rule Changes 7 3.0 References 8 UTAH DIVISION OF WATER QUALITY 1.0 Introduction 1.1 Scope This criterion support document reviews the EPA (2001) recommended methylmercury criterion for protection of human health and includes recommendations for adding a new statewide methylmercury criterion for Utah. This criterion, if adopted, may be further modified based on site-specific conditions (R317-2-7.1.c). Only the Utah Water Quality Board has the authority to change Utah’s water quality standards by following Utah’s administrative rulemaking process. The rulemaking process includes publication in the Utah Bulletin and opportunities for public participation. Excess mercury exposures can lead to adverse health effects in humans. ATSDR (1999) provides the following information regarding mercury: Mercury is a naturally occurring metal which has several forms. The metallic mercury is a shiny, silver-white, odorless liquid. If heated, it is a colorless, odorless gas. Mercury combines with other elements, such as chlorine, sulfur, or oxygen, to form inorganic mercury compounds or “salts,” which are usually white powders or crystals. Mercury also combines with carbon to make organic mercury compounds. The most common one, methylmercury, is produced mainly by microscopic organisms in the water and soil The nervous system is very sensitive to all forms of mercury. Methylmercury and metallic mercury vapors are more harmful than other forms, because more mercury in these forms reaches the brain. Very young children are more sensitive to mercury than adults. Mercury in the mother’s body passes to the fetus and may accumulate there, possibly causing damage to the developing nervous system. Nearly all methylmercury exposures in the United States occur through eating fish and shellfish (EPA, 2010; 2021). To protect human health, EPA (2001) recommends a criterion that is based on methylmercury concentrations in fish tissue. This document discusses the EPA (2001) methylmercury criterion, the available data on mercury in Utah fish, recommended criteria for Utah, discussions of implementation of the proposed criterion, and proposed rule language. 1.2 Mercury in Utah Fish For over 10 years, Utah has monitored the concentrations of mercury in thousands of game fish. The concentrations of total mercury were measured and all of the mercury presumed to be methylmercury. Most mercury in fish tissues (80-100%) is present as methylmercury (EPA, 2001). When the average concentration of mercury in fish exceeds 0.3 mg/kg ww, the Utah Department of Environmental Quality, Utah Department of Health, and Utah Division of Wildlife Resources issue a joint consumption advisory. The public are notified of these advisories through press releases, signs at the affected water bodies, and by publication on DWQ’s webpage. As of May 2024, Utah has issued fish consumption advisories due to mercury for 37 waterbodies in Utah. 1.3 Sources of Mercury in Utah. In 2007, DEQ published the Mercury Strategic Plan that was prepared with the assistance of the now inactive Mercury Workgroup. The Plan describes DEQs efforts to identify and address the potential sources of mercury in air, water, and soil in Utah. A multi-media approach is necessary because atmospheric deposition and multimedia cycling of mercury are significant in many waterbodies (EPA, 2010). Mercury emissions are global and disperse widely in the atmosphere. Therefore, even waterbodies without obvious local mercury sources can have elevated mercury concentrations in water and biota. There are both natural and anthropogenic sources of mercury. Natural sources of mercury UTAH DIVISION OF WATER QUALITY 1 include geothermal emissions and geological sources. Anthropogenic sources can include combustion, mining, and manufacturing. In particular, coal-fired power plants are the leading source of atmospheric mercury emissions in the United States. Mercury enters the aquatic food web when divalent mercury in water and sediments is converted through microbial action to methylmercury. Methylmercury is retained in fish tissue and can biomagnify up the food web. Methylation rates are generally higher under low oxygen conditions and in the presence of organic matter. Mercury detected in fish in U.S. surface waters is from both U.S. and international sources (EPA, 2005). EPA estimates that approximately 83 percent of the atmospheric mercury deposited on land and water in the U.S. is from sources outside the United States and Canada, and from natural and re-emitted sources. This mercury can be converted to methylmercury in aquatic environments by microbial organisms. EPA’s air quality modeling indicates that domestic sources influence mercury deposition much more in the eastern United States, and international sources are a more significant contributor to mercury deposition in the western United States, where relatively few domestic sources exist. 1.4 EPA (2001) Methylmercury Criterion The EPA (2001) recommended methylmercury criterion is 0.3 mg/kg (wet weight) in edible fish and shellfish tissue. EPA (2010) determined that a fish tissue criterion was appropriate for methylmercury because: ● A criterion expressed as a fish tissue concentration is closely tied to the “fishable” designated use goal for all waterbodies in the United States. ● A fish tissue concentration value is expressed in the same form (fish tissue) through which humans are exposed to methylmercury. ● A fish tissue concentration value is more consistent with how fish advisories are issued. ● At environmentally relevant concentrations, methylmercury is currently easier to detect in fish tissue than in water samples. The recommended criterion considers methylmercury exposures to people from all sources including air, drinking water, and food. Fish and shellfish consumption from recreational and commercial sources account for over 99% of the general population’s exposure to methylmercury. Of these exposures, the EPA (2001) estimated that 27% was from marine and estuarine species obtained from commercial sources.The methylmercury from these other exposures are deducted from the total allowable exposures from fish obtained recreationally and is called the relative source contribution. Drinking water is not a significant source of exposure to methylmercury. The methylmercury criterion is based on an assumed general population fish consumption intake of 17.5 g/day for fish (about 14 lbs/year). This intake is based on national surveys for recreationally-caught fish and reflects the 90th percentile of fish consumption rates from the general public. This rate underestimates consumption rates for certain subpopulations, such as subsistence fishers, who can consume significantly greater amounts of fish (EPA, 2016a). For the sensitive subpopulations of “Women of Childbearing Age” and “Children”, EPA (2001) provides higher consumption rates of 165 g/day and 156 g/day, respectively, that would result in a more stringent criterion than 0.3 mg/kg. UTAH DIVISION OF WATER QUALITY 2 In the recommended criterion, methylmercury toxicity is estimated from the EPA Integrated Risk Information System (IRIS) reference dose of 0.0001 mg/kg- day. The methylmercury reference dose is based on the outcomes of epidemiological studies. The representativeness of the studied populations for the overall U.S. population continues to be debated in scientific literature. However, IRIS toxicity values are derived for use in all EPA programs and undergo rigorous review. The Centers for Disease Control recommend a less stringent minimum risk level (analogous to a reference dose) of 0.0003 mg/kg-day (ATSDR, 1999a) but do not recommend this value for use in fish consumption advisories. Consistent with other EPA human health criteria, the EPA methylmercury criterion does not specify either an averaging time or exceedance frequency for the criterion. Although no exposure duration is recommended, the human health criteria are intended to be protective for chronic exposures (EPA 2000b). The EPA IRIS glossary defines chronic exposures as “Repeated exposure by the oral, dermal, or inhalation route for more than approximately 10% of the life span in humans.” The human lifespan recommended by the EPA (2014) Superfund program is 70 years and EPA (2011) recommends 78 years. Ten percent is 7 and 8 years, respectively. EPA typically evaluates exposures over 7 years as chronic and less than 7 years as subchronic. This information could support an averaging time of up to 7 years. EPA (2001) does not explicitly recommend that the methylmercury criterion be expressed as an average but averaging methods are described as possible implementation methods. For instance, EPA (2010) discusses calculating average methylmercury concentrations for species and trophic levels from individual fish samples within a waterbody and the use of composited fish samples. Average concentrations and composite sampling are representative for chronic exposures. Absent expressing the criterion as an average, the criterion would be interpreted as not-to-exceed concentration in individual fish. 2.0 Recommendations for Utah 2.1 Methylmercury Criterion DWQ recommends that Utah adopt the EPA (2001) water quality criterion of 0.3 mg/kg (ww) for fish and shellfish tissue. The EPA IRIS reference dose 0.0001 mg/kg-bw/day is the best available estimate of a “safe dose” for human consumption. No Utah-specific data are available for consumption rates of recreationally-caught fish or shellfish and therefore, the EPA (2001) national consumption rates are recommended. Likewise, no Utah-specific data are available for the consumption rates or mercury concentrations for fish and shellfish from commercial sources. The EPA (2001) relative source contribution is therefore presumed appropriate for Utah. No specific averaging time or exceedance frequency are recommended consistent with EPA (2001). In the absence of explicit designations, the averaging time will be instantaneous and the exceedance frequency is never. Mercury concentrations in fish are less variable than water concentrations (EPA, 2010). The fish tissue concentrations are a result of the fish exposures over time and inherently integrate the variable water concentrations. When fish tissue can be assumed to be in quasi-equilibrium with environmental concentrations, fish tissue concentrations are representative of longer-term water concentrations which intrinsically is an averaging time for the water. Similarly, no specific exceedance frequency is recommended because the fish tissue concentrations already represent relatively long-term water concentrations and any adverse human health effects are not acceptable. 2.2 Implementation for Advisories & Assessments The implementation of methylmercury advisories and assessments in Utah is currently focused on consumption of fish muscle tissue because that is presumed to be the primary route of consumption and exposure for the general public. However, other routes of exposure are UTAH DIVISION OF WATER QUALITY 3 possible. For example, some populations may also consume non-muscle fish tissue or catch and consume crayfish. DWQ has not identified any quantitative data regarding specific populations or waterbodies where this type of consumption may be more common or their consumption rates. DWQ should continue to seek data and information regarding situations where the application of methylmercury criteria to other types of tissue could be appropriate. Adoption of a methylmercury criterion in Utah’s water quality standards is not expected to affect the current process for issuing fish consumption advisories. Advisories are currently issued based on the recommended 0.3 mg/kg criterion. Utah’s fish consumption advisories are issued jointly by the Utah Department of Health, Utah Division of Wildlife Resources and the Utah Division of Water Quality. The advisory process uses similar methods to those used by EPA to derive the methylmercury criterion but the methods are not identical. Though advisories are based on the same magnitude of mercury concentrations as the recommended criterion, the current advisories were issued independent of a water quality criterion and the advisory process may deviate from implementation of a methylmercury criterion for water quality assessments, TMDLs or permits. Advisory methods and new consumption advisories are reviewed by the Utah Water Quality Health Advisory Panel. Thirty seven waterbodies in Utah currently have fish consumption advisories for mercury. Where adequate data are available, consumption advisories should consider fish size, age, and trophic classes as well as any unique characteristics of the target population of consumers for a waterbody such as rates of consumption, the types of tissue consumed, and sensitivity to methylmercury. Adoption of the new methylmercury criterion will require minor updates to assessment methods. In particular, an updated criterion will result in lowering the threshold for impairment used in assessments from 1 to 0.3 mg/kg. Current assessment methods rely on a t-test to determine if species mean methylmercury concentrations exceed the assessment threshold. This approach is consistent with recommendations in EPA (2010), and is appropriate to continue. Where analytical resources are limited, the assessment may also choose to consider evaluating composite samples (EPA 2010). EPA (2010) includes additional guidance regarding statistical methods, sample sizes, and processes for evaluating methylmercury concentrations from composite fish tissue samples. Currently there are two waterbodies in Utah listed as impaired for mercury in fish tissue, Brough Reservoir and Newcastle Reservoir. Lowering the threshold for impairment from 1 to 0.3 mg/kg is expected to result in additional impairment listings for mercury in fish tissue, including potential impairments for any of the waterbodies with current mercury fish tissue advisories. However, some advisories are based on data that are over 10 years old and their representativeness of current conditions should be evaluated when determining impairment status. Assessment category decisions should also consider whether alternative assessment categories may be appropriate depending on statistical uncertainty or where source investigations do not identify water mercury sources. For example, the insufficient data category may be used when there is uncertainty in comparing methylmercury concentrations to the water quality standard. The ‘impairment not caused by a pollutant’ (4C) category may also be appropriate where no water sources of mercury are identified. For states that have a comprehensive mercury reduction program, EPA has also recommended the use of a 5M category for waters impaired primarily by atmospheric mercury sources (EPA 2007). DWQ should continue to coordinate with and consult the Utah Department of Health and Human Services, the Utah Division of Wildlife Resources, and the Water Quality Health Advisory Panel when making decisions regarding the modification and application of methylmercury advisory and assessment methods. 2.3 Implementation for TMDLS & UPDES Permits UTAH DIVISION OF WATER QUALITY 4 Implementation of a tissue-based criterion in total maximum daily load assessments (TMDLs) and UPDES permits presents many challenges because TMDLs are typically based on water concentrations (EPA, 2010). Whereas advisories and assessments are based on methylmercury in tissues, reductions in mercury loads to waterbodies through TMDLS or permit limits would be focused on total mercury concentrations. The determination of total mercury source reductions necessary to meet methylmercury fish tissue criteria requires the development of site-specific translators between water and tissue mercury concentrations (see Section 2.4). Where air deposition is the primary source of mercury, variability in fish tissue concentrations within the same airshed is likely attributable to site-specific factors affecting mercury methylation rates. Where impairments are identified, preliminary investigations should focus on determining what portion of the mercury is attributable to atmospheric sources versus water sources. Atmospheric mercury is difficult to measure, so these investigations are anticipated to initially focus on characterizing mercury concentrations in water. Where no apparent water sources of mercury exist to an impaired waterbody, a low TMDL prioritization may be appropriate. Permitted discharges are not expected to be the primary source of mercury for waters with existing fish consumption advisories. Most of the Utah waters affected by fish consumption advisories have no or very few permitted discharges upstream. Although some of these waters may be impacted by historical mining activities, air deposition is expected to be a major contributor of mercury to Utah waters. The permitting impacts of adopting a methylmercury criterion are anticipated to be limited. Currently, reasonable potential determinations for mercury are based on the existing 0.000012 mg/l mercury criterion, the likelihood of mercury being present in the effluent, and the concentrations of mercury measured in the effluent. For publicly owned treatment works (POTWs), mercury sources are also addressed by the pretreatment program. Reasonable potential for mercury has only been identified in two Utah Pollution Elimination System (UPDES) permits and these have been assigned a water quality-based effluent limit for mercury based on the existing 0.000012 mg/l mercury criterion. More stringent mercury discharge limits are possible in the future where methylmercury impairments downstream from point sources are identified, but these would only occur after TMDL development which would include source determination and translator development. Utah’s current approach to regulating mercury discharges appears to be adequately protective for methylmercury based on the lack of correlation between potential point sources of mercury and fish observed consumption advisories. At locations where fish tissue concentrations indicate that the Utah’s water-based criterion is not sufficiently protective, translators may need to be derived. As discussed in Section 2.4, DWQ and EPA (2010) recommend that site-specific translators be developed when translators are needed. EPA (2010) provides detailed recommendations for evaluating and implementing reasonable potential analyses for methylmercury for discharge permits. 2.4 Translators Translators describe the relationship between methylmercury concentrations in fish tissues and concentrations of mercury in water. This type of translator is also called a bioaccumulation factor or biomagnification factor. With a translator, the concentration of mercury in water can be used to predict the methylmercury concentration in fish tissue, or vice versa. When fish tissues exceed the methylmercury criterion, a translator is used to determine how much the water concentrations need to be reduced to achieve the fish tissue criterion. Once the water concentration is established, a water quality-based effluent limit or TMDL can be derived. In these circumstances, follow up monitoring to confirm the continued accuracy of site-specific translators is essential. A translator is a simplified representation of complex and dynamic site-specific processes. As presented in detail in EPA (2001, 2010), mercury is usually released to the environment in inorganic forms. Once in the aquatic environment, mercury partitions between dissolved and UTAH DIVISION OF WATER QUALITY 5 undissolved forms and between the water column and sediments. Methylmercury concentrations are a result of methylation of mercury compounds by microbial organisms and demethylation by microbial organisms and sunlight. Methylation rates are a function of organic carbon, sulfur, and dissolved oxygen and anthropogenic perturbations of these constituents may also affect methylmercury concentrations in fish. Methylmercury concentrations also tend to increase with fish age and in higher trophic levels and therefore, species feeding characteristics and lifecycles and the number of trophic levels at a site can influence the methylmercury concentrations observed in fish. Site-specific translators are developed by measuring mercury concentrations in both water and fish tissue and calculating a relationship. For permitting applications, the total recoverable mercury concentrations in water are compared to the edible fish tissue concentrations (EPA, 2010). A highly sensitive analytical method for the water is usually required along with special sampling protocols to avoid sample contamination. However, even these methods may not be sufficiently sensitive to quantify mercury concentrations in water. For the translators to be valid, mercury concentrations in fish tissue should be at or near equilibrium with the water. Fish tissues should be collected from fish most likely to be consumed and to have the highest exposures (i.e., fish from upper trophic levels) and more than one species may need to be sampled. EPA (2001, 2010, 2016) provides details on conducting investigations to determine translators between water and tissue. If a permittee or other interested parties intends to collect data to support a translator, DWQ pre-approval is strongly recommended to ensure that the data will be appropriate to support the derivation. If site-specific translators can’t be derived for e.g., a new discharge, EPA (2001) does provide draft national translators (bioaccumulation factors). These translators are anticipated to be protective but may be more stringent than necessary. By default, all mercury detected in fish is assumed to be methylmercury (EPA, 2000a). In some situations, verification of this assumption may be warranted. These situations include when a small change to the assumption of 100 percent methylmercury would affect the regulatory outcome (e.g., impairment determination or reasonable potential). Most mercury in fish tissues is methylmercury but percentages as low as 80 percent have been observed (EPA, 2000a). 2.6 Recommended Rule Changes A markup of the recommended changes to the standards in UAC R317-2-14 is shown below. The proposed additions are underlined. The criterion is specified as a wet-weight concentration of methylmercury in mg/kg in edible fish tissue. TABLE 2.14.6 LIST OF HUMAN HEALTH CRITERIA (CONSUMPTION) Chemical Parameter Water and Organism Organism Only and CAS # (ug/L) (ug/L) Class 1C Class 3A,3B,3C,3D Antimony 7440-36-0 5.6 640 Arsenic 7440-38-2 A A Beryllium 7440-41-7 C C Chromium III 16065-83-1 C C Chromium VI 18540-29-9 C C UTAH DIVISION OF WATER QUALITY 6 Copper 7440-50-8 1,300 Mercury 7439-97-6 A A Methylmercury 22967-92-6 0.3 E 0.3 E Nickel 7440-02-0 610 4,600 Selenium 7782-49-2 170 4,200 Thallium 7440-28-0 0.24 0.47 Zinc 7440-66-6 7,400 26,000 Free Cyanide 57-12-5 4 400 Asbestos 1332-21-4 7 million Fibers/L 2,3,7,8-TCDD Dioxin 1746-01-6 5.0 E -9 B 5.1 E-9 B Acrolein 107-02-8 3 400 Acrylonitrile 107-13-1 0.061 7.0 Benzene 71-43-2 2.1 B 51 B Bromoform 75-25-2 7.0 B 120 B Carbon Tetrachloride 56-23-5 0.4 B 5 B Chlorobenzene 108-90-7 100 MCL 800 Chlorodibromomethane 124-48-1 0.80 B 21 B Chloroform 67-66-3 60 B 2,000 B Dichlorobromomethane 75-27-4 0.95 B 27 B 1,2-Dichloroethane 107-06-2 9.9 B 2,000 B 1,1-Dichloroethylene 75-35-4 300 MCL 20,000 1,2-Dichloropropane 78-87-5 0.90 B 31 B 1,3-Dichloropropene 542-75-6 0.27 12 Ethylbenzene 100-41-4 68 130 Methyl Bromide 74-83-9 100 10,000 Methylene Chloride 75-09-2 20 B 1,000 B 1,1,2,2-Tetrachloroethane 79-34-5 0.2 B 3 B Tetrachloroethylene 127-18-4 10 B 29 B Toluene 108-88-3 57 520 1,2 -Trans-Dichloroethylene 156-60-5 100 MCL 4,000 1,1,1-Trichloroethane 71-55-6 10,000 MCL 200,000 1,1,2-Trichloroethane 79-00-5 0.55 B 8.9 B Trichloroethylene 79-01-6 0.6 B 7 B Vinyl Chloride 75-01-4 0.022 1.6 2-Chlorophenol 95-57-8 30 800 2,4-Dichlorophenol 120-83-2 10 60 2,4-Dimethylphenol 105-67-9 100 3,000 2-Methyl-4,6-Dinitrophenol 534-52-1 2 30 2,4-Dinitrophenol 51-28-5 10 300 UTAH DIVISION OF WATER QUALITY 7 3-Methyl-4-Chlorophenol 59-50-7 500 2,000 Pentachlorophenol 87-86-5 0.03 B 0.04 B Phenol 108-95-2 4,000 300,000 2,4,5-Trichlorophenol 95-95-4 300 600 2,4,6-Trichlorophenol 88-06-2 1.5 B 2.8 B Acenaphthene 83-32-9 70 90 Anthracene 120-12-7 300 400 Benzidine 92-87-5 0.00014 B 0.011 B BenzoaAnthracene 56-55-3 0.0012 B 0.0013 B BenzoaPyrene 50-32-8 0.00012 B 0.00013 B BenzobFluoranthene 205-99-2 0.0012 B 0.0013 B BenzokFluoranthene 207-08-9 0.012 B 0.013 B Bis2-Chloro1methylether 542-88-1 0.00015 0.017 Bis2-Chloro1methylethylether 108-60-1 200 B 4000 Bis2-ChloroethylEther 111-44-4 0.030 B 2.2 B Bis2-Chloroisopropy1Ether 39638-32-9 1,400 65,000 Bis2-EthylhexylPhthalate 117-81-7 0.32 B 0.37 B Butylbenzyl Phthalate 85-68-7 0.10 0.10 2-Chloronaphthalene 91-58-7 800 1,000 Chrysene 218-01-9 0.12 B 0.13 B Dibenzoa,hAnthracene 53-70-3 0.00012 B 0.00013 B 1,2-Dichlorobenzene 95-50-1 1,000 3,000 1,3-Dichlorobenzene 541-73-1 7 10 1,4-Dichlorobenzene 106-46-7 300 900 3,3-Dichlorobenzidine 91-94-1 0.049 B 0.15 B Diethyl Phthalate 84-66-2 600 600 Dimethyl Phthalate 131-11-3 2,000 2,000 Di-n-Butyl Phthalate 84-74-2 20 30 2,4-Dinitrotoluene 121-14-2 0.049 B 1.7 B Dinitrophenols 25550-58-7 10 1,000 1,2-Diphenylhydrazine 122-66-7 0.03 B 0.2 B UTAH DIVISION OF WATER QUALITY 8 Fluoranthene 206-44-0 20 20 Fluorene 86-73-7 50 70 Hexachlorobenzene 118-74-1 0.000079 B 0.000079 B Hexachlorobutadiene 87-68-3 0.01 B 0.01 B Hexachloroethane 67-72-1 0.1 B 0.1 B Hexachlorocyclopentadiene 77-47-4 4 4 Ideno 1,2,3-cdPyrene 193-39-5 0.0012 B 0.0013 B Isophorone 78-59-1 34 B 1,800 B Nitrobenzene 98-95-3 10 600 N-Nitrosodiethylamine 55-18-5 0.0008 B 1.24 B N-Nitrosodimethylamine 62-75-9 0.00069 B 3.0 B N-Nitrosodi-n-Propylamine 621-64-7 0.0050 B 0.51 B N-Nitrosodiphenylamine 86-30-6 3.3 B 6.0 B N-Nitrosopyrrolidine 930-55-2 0.016 B 34 B Pentachlorobenzene 608-93-5 0.1 0.1 Pyrene 129-00-0 20 30 1,2,4-Trichlorobenzene 120-82-1 0.071 MCL 0.076 Aldrin 309-00-2 0.00000077 B 0.00000077 B alpha-BHC 319-84-6 0.00036 B 0.00039 B beta-BHC 319-85-7 0.0080 B 0.014 B gamma-BHC (Lindane) 58-89-9 4.2 MCL 4.4 Hexachlorocyclohexane (HCH) Technical 608-73-1 0.0066 0.010 Chlordane 57-74-9 0.00031 B 0.00032 B 4,4-DDT 50-29-3 0.000030 B 0.000030 B 4,4-DDE 72-55-9 0.000018 B 0.000018 B 4,4-DDD 72-54-8 0.00012 B 0.00012 B Dieldrin 60-57-1 0.0000012 B 0.0000012 B alpha-Endosulfan 959-98-8 20 30 beta-Endosulfan 33213-65-9 20 40 UTAH DIVISION OF WATER QUALITY 9 Endosulfan Sulfate 1031-07-8 20 40 Endrin 72-20-8 0.03 0.03 Endrin Aldehyde 7421-93-4 1 1 Heptachlor 76-44-8 0.0000059 B 0.0000059 B Heptachlor Epoxide 1024-57-3 0.000032 B 0.000032 B Methoxychlor 72-43-5 0.02 0.02 Polychlorinated Biphenyls (PCBs) 1336-36-3 0.000064 B,D 0.000064 B,D Toxaphene 8001-35-2 0.00070 B 0.00071 B FOOTNOTES: A. See Table 2.14.2 B. Based on carcinogenicity of 10-6 risk. C. EPA has not calculated a human criterion for this contaminant. However, permit authorities should address this contaminant in NPDES permit actions using the State's existing narrative criteria for toxics D. This standard applies to total PCBs. E. mg/kg wet weight in edible fish and shellfish tissue 3.0 References Agency for Toxic Substances and Disease Registry (ATDSR), 1999. Mercury Tox FAQs. https://www.atsdr.cdc.gov/toxfaqs/tfacts46.pdf Agency for Toxic Substances and Disease Registry (ATDSR), 1999a. Toxicological Profile for Mercury. Environmental Protection Agency (EPA) 2021. https://www.epa.gov/mercury/how-people-are-exposed-mercury. Accessed August, 2021 EPA (U.S. Environmental Protection Agency). 2000a. Guidance for Assessing Chemical Contaminant Data for Use in Fish Advisories. Volume 1: Fish Sampling and Analysis, 3rd ed. EPA/823/B-00/007. Washington, DC: U.S. Environmental Protection Agency, Office of Water. http://www.epa.gov/ost/fishadvice/volume1/ index.html EPA (U.S. Environmental Protection Agency). 2000b. Methodology for Deriving Ambient Water Quality Criteria for the Protection of Human Health (2000). EPA-822-B-00-004 EPA (U.S. Environmental Protection Agency). 2001. Water Quality Criterion for the Protection of Human Health: Methylmercury. Final. EPA-823-R-1-001 UTAH DIVISION OF WATER QUALITY 10 EPA (U.S. Environmental Protection Agency). 2005. Technical Support Document, Revision of December 2000 Regulatory Finding on the Emissions of Hazardous Air Pollutants From Electric Utility Steam Generating Units and the Removal of Coal- and Oil-Fired Electric Utility Steam EPA (U.S. Environmental Protection Agency). 2007. Memorandum: Listing Waters Impaired by Atmospheric Mercury Under Clean Water Act Section 303(d): Voluntary Subcategory 5m for States with Comprehensive Mercury Reduction Programs. https://www.epa.gov/tmdl/listing-waters-impaired-atmospheric-mercury-voluntary-subcategory -5m-states-comprehensive EPA (U.S. Environmental Protection Agency). 2010. Guidance for Implementing the 2001 Methylmercury Criterion. EPA-823-10-001. EPA (U.S. Environmental Protection Agency). 2011. Exposure Factors Handbook. EPA (U.S. Environmental Protection Agency). 2014. Memorandum: Human Health Evaluation Manual, Supplemental Guidance: Update of Standard Default Exposure Factors. OSWER Directive 9200.1-120. EPA (U.S. Environmental Protection Agency). 2016. Technical Support for Adopting and Implementing EPA’s 2016 Selenium Criterion in Water Quality Standards. Draft. EPA-820-F-010 EPA (U.S. Environmental Protection Agency). 2016a. Guidance for Conducting Fish Consumption Surveys. 823B16002 Utah Department of Health (UDOH). 2012. Utah Fish Advisories, Changes to Utah Fish Consumption Values. UTAH DIVISION OF WATER QUALITY 11