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Home My WebLink AboutDSHW-2025-000237Anderson Geneva, LLC United States Steel Corporation Page 1 of 2 January 10, 2025 Mr. Doug Hansen, Director Division of Waste Management and Radiation Control Utah Department of Environmental Quality P.O. Box 144880 Salt Lake City, UT 84114-4880 RE: Semi-Annual Groundwater Sampling Report, Fall 2024 – Former Closed Hazardous Waste Impoundments Area (SWMU GW-4.14) – Former Geneva Steel Facility, Vineyard, Utah Dear Mr. Hansen: United States Steel Corporation (USS) and Anderson Geneva, LLC (Geneva) are pleased to provide this Semi-Annual Site Management Plan (SMP) Groundwater Sampling Report, Fall 2024 for the former Closed Hazardous Waste Impoundments (CHWIs), Solid Waste Management Unit (SWMU) GW-4.14 at the former Geneva Steel Facility in Vineyard, Utah (Site). Groundwater sampling and laboratory testing were conducted in accordance with paragraph 11.b of the Site Management Plan (SMP) for the CHWIs (USS and Anderson Geneva, 2021). The SMP was approved by the Utah Department of Environmental Quality (UDEQ) on March 24, 2022 (UDEQ, 2022a) and the environmental covenant (EC) was approved by UDEQ on June 15, 2022 (UDEQ, 2022b). This sampling replaces the previous sampling performed at the CHWIs area when waste was in-place, which was conducted in accordance with the Permit (UTD009086133). The Permit-directed sampling will no longer be performed at the CHWIs, as the waste has been relocated to the CAMU and the Permit is in the process of being modified to account for the CAMU and other Site changes. Field Activities Groundwater samples were collected on October 9, 2024 at the former CHWIs area from monitoring wells MW-03, MW-05, and MW-16. Field activities were conducted in accordance with applicable standard operating procedures (SOPs) contained in the Verification Investigation Work Plan (VIWP) (USS et al., 2017). Groundwater sampling forms are included in Attachment A. Analytical Testing Groundwater and quality assurance/quality control (QA/QC) samples were sent to Eurofins TestAmerica, Denver, a Utah-certified laboratory, for analysis under chain-of-custody procedures. The analytical results were validated by an AECOM chemist in accordance with the revised Data Collection and Quality Assurance Plan (URS, 2004). The data validation report is included in Attachment B. All data were considered usable, as qualified. Groundwater samples were analyzed for the volatile organic compounds (VOCs) benzene, toluene, ethylbenzene, xylenes (total), and naphthalene (BTEXN) using U.S. Environmental Protection Agency (EPA) Test Method 8260B. Page 2 of 2 Results and Discussion All results are below or within the allowable management range, as presented in the SMP. The locations of the SMP monitoring wells (MW-03, MW-05, and MW-16) are shown in Figure 1 and laboratory analytical results are summarized in Table 1. The laboratory report is included in electronic format in Attachment C. References UDEQ, 2022a. UDEQ approval of Site Management Plan Former Closed Hazardous Waste Impoundments Area. March 24, 2022. UDEQ, 2022b. Environmental Covenant for the Former Closed Hazardous Waste Impoundment. June 15, 2022. URS, 2004. Final RCRA Facility Investigation Work Plan. Task II, Part Two: Data Collection and Quality Assurance Plan, Former Geneva Steel Facility, Vineyard, Utah. EPA/UTD009086133. 2004. USS, Geneva Steel LLC, and AECOM, 2017. Revised Final RCRA Facility Investigation Task III, Part 4: Verification Investigation Work Plan, Former Geneva Steel Facility, Vineyard, Utah. EPA/UTD009086133. December 2017. USS and Anderson Geneva, 2021. Site Management Plan for Former Closed Hazardous Waste Impoundments Area, Former Geneva Steel Facility, Vineyard, Utah. EPA/UTD009086133. November 16, 2021. Tables:Table 1 – Fall 2024 Groundwater Sampling Results, Former Geneva Steel Facility, Former Closed Hazardous Waste Impoundments Site Management Plan. Figures:Figure 1 –Former Closed Hazardous Waste Impoundments (CHWIs SWMU GW- 4.14)Groundwater Sampling Locations Attachments:Attachment A – Groundwater Sampling Forms Attachment B – Data Validation Report Attachment C – Analytical Report with Chain-of-Custody Record Please contact us at your convenience if you have any questions on this matter. cc: B. Mustoe, AECOM T. Messersmith, AECOM File: AG, USS Tables Table 1 Fall 2024 Groundwater Sampling Results Former Geneva Steel Facility Closed Hazardous Waste Impoundments Area Site Management Plan Location ID Field Sample ID Date Sample Code Analyte MDL RL Indoor Residential 1E-06 CAL Indoor Industrial / Commercial Worker 1E-06 CAL Units MW-05 10/9/2024 N BENZENE 0.001 0.00014 0.001 0.011 0.070 mg/L MW-05 10/9/2024 N ETHYLBENZENE ND 0.00014 0.001 0.7 0.7 mg/L MW-05 10/9/2024 N NAPHTHALENE ND 0.00099 0.003 0.022 0.157 mg/L MW-05 10/9/2024 N TOLUENE ND 0.00032 0.001 131 526 mg/LMW-05 10/9/2024 N XYLENES (TOTAL)ND 0.00011 0.001 10 17.35 mg/L MW-905 10/9/2024 FD BENZENE 0.00089 J 0.00014 0.001 0.011 0.070 mg/L MW-905 10/9/2024 FD ETHYLBENZENE ND 0.00014 0.001 0.7 0.7 mg/L MW-905 10/9/2024 FD NAPHTHALENE ND 0.00099 0.003 0.022 0.157 mg/L MW-905 10/9/2024 FD TOLUENE ND 0.00032 0.001 131 526 mg/L MW-905 10/9/2024 FD XYLENES (TOTAL)ND 0.00011 0.001 10 17.35 mg/L MW-16 10/9/2024 N BENZENE 0.00061 J 0.00014 0.001 0.011 0.070 mg/L MW-16 10/9/2024 N ETHYLBENZENE ND 0.00014 0.001 0.7 0.7 mg/L MW-16 10/9/2024 N NAPHTHALENE ND 0.00099 0.003 0.022 0.157 mg/L MW-16 10/9/2024 N TOLUENE ND 0.00032 0.001 131 526 mg/L MW-16 10/9/2024 N XYLENES (TOTAL)ND 0.00011 0.001 10 17.35 mg/L MW-03 10/9/2024 N BENZENE 0.16 0.00072 0.005 0.011*0.070*mg/L MW-03 10/9/2024 N ETHYLBENZENE ND 0.00072 0.005 0.7 0.7 mg/L MW-03 10/9/2024 N NAPHTHALENE ND 0.005 0.015 0.022 0.157 mg/L MW-03 10/9/2024 N TOLUENE 0.0017 J 0.0016 0.005 131 526 mg/L MW-03 10/9/2024 N XYLENES (TOTAL)ND 0.00057 0.005 10 17.35 mg/L Notes CAL - Corrective Action Level RL - Reporting limit FD - Field duplicate (S) - Solubility Limit J - Estimated quantity UJ - Not detected, the associated value is an estimate MDL - Method detection limit U- analyte was analyzed for, but not detected above the level of the adjusted detection limit mg/L - milligrams per liter Bolded results indicate a 1E-06 CAL exceedance. N - Normal * - 1E-04 Benzene CALs: Indoor Residential = 0.88 mg/L, Indoor Industrial/Commercial = 5.83 mg/L ND - Non-detect Result MW-16 MW-03 MW-05 Page 1 of 1 Figures !< !< !< MW-05 MW-16MW-03 50 0 50 100Feet Former Geneva Steel FacilityVineyard, Utah Detail Area UtahLake §¨¦15 µFigure 1Closed Hazardous Waste Impoundments(CHWIs SWMU 4.14)Groundwater Sampling Locations Aerial Source: NearMap 2024Path: \\na.aecomnet.com\lfs\AMER\SaltLakeCity-USSLC2\DCS\Projects\USS_Geneva RCRA CA\Groundwater\Groundwater SWMUs\SWMU GW 4.14 CHWIs\SMP Reports\Fall 2023\Figures\Fig1_CHWIs_SMP_sampling_locations.mxd SMP Monitoring Well!< Site Management Area(Site Management Plan, CHWIs, 2022) Attachment A Groundwater Sampling Forms Attachment B Data Validation Report TABLE OF CONTENTS i Section 1 Introduction ..................................................................................................................... 1-1 Section 2 Data Validation Process ................................................................................................. 2-1 2.1 Laboratory Performance Data Evaluation Criteria .................................. 2-1 2.1.1 Initial Calibration ......................................................................... 2-1 2.1.2 Initial and/or Continuing Calibration Verification ...................... 2-1 2.1.3 Internal Standard Data ................................................................. 2-1 2.1.4 Laboratory Control Sample (LCS) Analysis................................ 2-2 2.1.5 Dual Column Confirmation Results ............................................. 2-3 2.1.6 ICP Interference Check Sample (ICS) for Metals ....................... 2-3 2.2 Sample-Specific Data Evaluation Criteria ............................................... 2-4 2.2.1 Case Narrative Comments, Chain of Custody (COC) and Sample Receipt ............................................................................ 2-4 2.2.2 Holding Times ............................................................................. 2-4 2.2.3 Blanks .......................................................................................... 2-5 2.2.4 Matrix Spike Analysis.................................................................. 2-5 2.2.5 Duplicate Sample Analysis .......................................................... 2-6 2.2.6 Internal Standard Data (Metals only) ........................................... 2-6 2.2.7 Post-Digestion Spike Recovery (Metals Only) ............................ 2-6 2.2.8 Serial Dilution (Metals only) ....................................................... 2-7 2.2.9 Surrogate Recoveries ................................................................... 2-7 2.2.10 Field Duplicate Results ................................................................ 2-8 2.2.11 Anion/Cation Balance .................................................................. 2-8 2.2.12 Balance of Total to Partial Analyses ............................................ 2-8 2.2.13 Reporting of Isomer Totals (VOCs Only) ................................... 2-9 Section 3 Data Validation Narrative ............................................................................................... 3-1 3.1 Data Validation Narrative for Data Package 280-197896-1 .................... 3-1 3.2 Overall Assessment .................................................................................. 3-1 3.3 Notes from Case Narrative ....................................................................... 3-1 3.4 Chain of Custody (COC) and Sample Receipt ........................................ 3-1 3.5 Holding Times ......................................................................................... 3-2 3.6 Blanks ...................................................................................................... 3-2 3.7 Laboratory Control Sample (LCS)/Laboratory Control Sample Duplicate (LCSD) .................................................................................... 3-2 3.8 Surrogate Recoveries ............................................................................... 3-2 Section 4 Site-Specific Quality Control Assessment ................................................................... 4-1 4.1 Matrix Spike/Matrix Spike Duplicate Analyses ...................................... 4-1 4.2 Field Duplicate Analyses ......................................................................... 4-2 4.3 Field Blank Analyses ............................................................................... 4-2 4.4 Equipment Blank Analyses ...................................................................... 4-2 TABLE OF CONTENTS ii Section 5 Overall Assessment of Analytical Data ........................................................................ 5-1 5.1 Precision ................................................................................................... 5-1 5.2 Accuracy .................................................................................................. 5-1 5.3 Representativeness ................................................................................... 5-1 5.4 Completeness ........................................................................................... 5-2 5.5 Comparability .......................................................................................... 5-2 5.6 Sensitivity ................................................................................................ 5-2 List of Tables Table 1-1 Parameters Analyzed and Analytical Methods Used for Geneva Steel Groundwater Samples Table 1-2 Data Validation Qualifier Definitions Table 1-3 Data Validation Qualifier Codes and Bias Direction Codes Attachments Attachment 1 – Matrix Spike and Matrix Spike Duplicate Assessment Attachment 2 – Summary of Qualified Data SECTIONONE Introduction 1-1 1. Section 1 ONE Introduction The Fall groundwater monitoring event for 2024 was conducted by AECOM at the former Geneva Steel facility (on behalf of United States Steel Corporation). The purpose of the monitoring program is to collect data of sufficient quality and quantity to characterize the groundwater chemistry and to meet the requirements of the “Post-Closure Permit for Post- Closure Care of Three Closed Hazardous Waste Surface Impoundments and Facility Wide Corrective Action,” issued to US Steel Corporation and Geneva Steel LLC (EPA ID No. UTD 009 086 133) on May 14, 2004. The samples were analyzed for the analyses requested on the chain of custody forms (COCs), for the parameters listed in Table 1-1 below, and in accordance with the methods listed in the Table 1-1. Eurofins Environment Testing in Denver, Colorado (EET-Denver) conducted the analyses. The results were reported in one data package. This data validation report presents the results of the data validation conducted on the laboratory analytical data packages received. Table 1-1 PARAMETERS ANALYZED AND ANALYTICAL METHODS USED FOR GENEVA STEEL GROUNDWATER SAMPLES Analyte/Group Preparation Method Analytical Method Volatile Organic Compounds (VOCs) SW846 5030C SW846 8260D SW846 = USEPA Office of Solid Waste, Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods The review consisted of evaluation of laboratory performance criteria and sample-specific criteria as described in the Resource Conservation and Recovery Act (RCRA) Facility Investigation, Remedial Facility Investigation (RFI) Work Plan Data Collection Quality Assurance Plan (DCQAP) (August 2004). United States Environmental Protection Agency (USEPA) National Functional Guidelines (NFG) for Superfund Organic Methods Data Review Functional Guidelines for Superfund Organic Data Review (November 2020) and USEPA NFG for Superfund Inorganic Data Review (November 2020), as appropriate to the analytical method, and Quality Control (QC) limits specified in the DCQAP were utilized as guidance during data validation. Section 8.0 of the DCQAP provides details as to how Functional Guidelines guidance was implemented. The laboratory performance parameters included the following as appropriate for the methods performed: initial calibration procedures and results, continuing calibration procedures and results, laboratory control sample (LCS) results, Inductively Coupled Plasma (ICP) interference check samples (ICSs), compound identification, and internal standard recovery. In accordance with the DCQAP, the laboratory is required to identify any quality assurance/quality control (QA/QC) issues relative to the laboratory performance criteria in the case narrative. These QA/QC issues identified in the case narrative were evaluated to verify that the laboratory analyses are in compliance with the method. Section 2.1 summarizes the QC requirements for the laboratory performance criteria that were used in the data validation process and how data were qualified. The sample-specific criteria evaluated included the following as appropriate for the methods performed: COC and sample receipt documentation, holding times, blank results, matrix spike/matrix spike duplicate (MS/MSD) sample analysis, surrogate spike compound recovery, field duplicate results agreement, Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) internal standard recovery, post-digestion spike recoveries (PDS), and serial dilution results. The sample-specific criteria were evaluated for all of the data received. Section 2.2 summarizes the SECTIONONE Introduction 1-2 sample-specific criteria that were used in the data validation process and how data were qualified. Section 3 presents the data validation narrative for the QA/QC issues relative to the laboratory performance criteria identified in the laboratory case narrative and the sample-specific criteria. Data validation narrative results are presented in Section 3 for each data package. Section 4 provides a discussion of the matrix spike/matrix spike duplicate results, field duplicate results, and the field blank results. This report is concluded with an overall assessment of the complete data set, presented in Section 5. During the data validation process, the data reviewer copied qualifiers into the access database and generated a summary form, Attachment 2 of any data validation qualifiers assigned (“U,” “J,” “UJ,” “N”, “NJ”, and “R”) and associated qualifier and bias codes as listed in Tables 1-2 and 1-3. The purpose of the qualifier codes is to provide information with regard to the data quality condition(s) that resulted in the assigned qualifiers. The bias code provides an indication of the bias direction of the results qualified as estimated based on data quality condition(s) that resulted in the data qualification and the results of the other associated quality control analyses. The data qualifier codes are followed by a hyphen and the applicable bias code. For example, a result qualified as estimated due to a holding time exceedance, which resulted in a potential low bias in the result, has the following qualifier code and bias direction annotated, “HT-L.” In the case of multiple data quality conditions resulting in qualification, each qualifier code is listed and separated by a comma. For example, a result qualified as estimated due to low matrix spike recovery and poor method duplicate precision would have the following codes annotated, “MS, SD–I, with the I indicating that the direction of bias is indeterminate. Table 1-2 DATA VALIDATION QUALIFIER DEFINITIONS Qualifier Definitions1 U The analyte was analyzed for, but was not detected above the level of the adjusted detection limit or quantitation limit, as appropriate. J The result is an estimated quantity. The associated numerical value is the approximate concentration of the analyte in the sample. UJ The analyte was analyzed for, but was not detected. The reported quantitation limit is approximate and may be inaccurate or imprecise. R The data are unusable. The sample results are rejected due to serious deficiencies in meeting QC criteria. The analyte may or may not be present in the sample. NJ The analysis indicates the presence of an analyte that has been tentatively identified and the associated numerical value represents its approximate concentration. 1Definitions cited from the USEPA Contract Laboratory Program National Functional Guidelines for Organic Data Review, November 2020. Table 1-3 SECTIONONE Introduction 1-3 DATA VALIDATION QUALIFIER CODES AND BIAS DIRECTION CODES Qualifier Code* Data Quality Conditions Resulting in Assigned Qualification General Use P Preservation requirement (e.g., temperature or pH) was not met HT Holding time requirement was not met MB Method blank or preparation blank contamination LCS Laboratory control sample evaluation criteria not met FB Field blank contamination SQL The analysis meets all qualitative identification criteria, but the measured concentration is less than the reporting limit. EB Equipment blank contamination FD Field duplicate evaluation criteria not met TB Trip Blank Contamination RL Reporting limit exceeds decision criteria (for non-detects) PJ Professional Judgment Inorganic Methods ICV Initial calibration verification evaluation criteria not met CCV Continuing calibration verification evaluation criteria not met CCB Continuing calibration blank contamination PB Preparation blank contamination ICS Interference check sample evaluation criteria not met D Laboratory duplicate precision or MS/MSD precision evaluation criteria not met MS Matrix spike recovery outside acceptance range PDS Post-digestion spike recovery outside acceptance range MSA Method of standard additions correction coefficient ≤0.995 DL Serial dilution results did not meet evaluation criteria Organic Methods TUNE Instrument performance (tuning) criteria not met ICAL Initial calibration evaluation criteria not met CCAL Continuing calibration evaluation criteria not met SUR Surrogate recovery outside acceptance range MS/SD Matrix spike/matrix spike duplicate precision criteria not met IS Internal standard evaluation criteria not met MS Matrix spike recovery outside acceptance range ID Target compound identification criteria not met Bias Codes H Bias in sample result likely to be high L Bias in sample result likely to be low I Bias in sample result is indeterminate *In the case of multiple qualifier codes, all codes would be listed and separated by a comma SECTIONTWO Data Validation Process 2-1 2. Section 2 TWO Data Validation Process The analytical data were generated and reviewed in accordance with the protocols summarized in the following subsections, as applicable to the reported methods. The data validation effort was performed to evaluate the usability of the sample data for meeting the project objectives. 2.1 LABORATORY PERFORMANCE DATA EVALUATION CRITERIA The laboratory performance parameters evaluated were only the parameters identified by the laboratory in the case narrative not meeting method acceptance criteria. The subsections below discuss how each of the laboratory performance parameters reported by the laboratory in the case narrative as not meeting acceptance criteria were evaluated. If the case narrative describes a laboratory performance criterion not covered by the subsections below, the data review person evaluated the associated data against method requirements to determine the need for data qualification. The laboratory performance criteria evaluated included initial and continuing calibration, laboratory control sample results, and other checks as pertinent to the analytical technique (i.e., gas chromatography-mass spectrometry (GC-MS) instrument check (tuning) and internal standard performance). Section 2.1 summarizes the review of laboratory performance criteria. The results of any QA/QC issues identified in the case narrative are presented in Section 3. 2.1.1 Initial Calibration The analytical method was used to determine the QC acceptance criteria for initial calibration. If the case narrative or data validation process indicated that the initial calibration for any analyte did not meet the acceptance criteria, then all results for that given analyte associated with the initial calibration were qualified as estimated (“J/UJ”) with a qualifier code of “ICAL” and a bias code of “I” for indeterminate direction of bias. 2.1.2 Initial and/or Continuing Calibration Verification The analytical method was used to determine the QC acceptance criteria for initial and continuing calibration verification. If the case narrative or data validation process indicated that the initial or continuing calibration verification for any analyte did not meet the acceptance criteria, then all results for that given analyte associated with the initial or continuing calibration verification were qualified as estimated (“J/UJ”) with a qualifier code of “ICV” or “CCV” for inorganics and “CCAL” for organics. If the data reviewer could discern a probable magnitude and/or direction of bias to the associated sample results based on the information provided, then appropriate qualifier bias codes were assigned. Because the Methods 8260B and 8270C do not provide the criterion for the percent drift (%D) for non-calibration check compounds (CCCs), the reviewer used guidance from Functional Guidelines and used 25% for the criterion for the %D for all other target compounds. 2.1.3 Internal Standard Data The analytical method was used to determine the QC acceptance criteria for internal standard area counts for GC/MS organic analysis and for internal standard quantitation. Internal standard area counts are not a direct measure of the accuracy of the analysis. Low internal standard area counts for sample analysis relative to those observed in the associated continuing calibration SECTIONTWO Data Validation Process 2-2 analysis may be indicative of low extraction or purging efficiency which decreases the analysis sensitivity (raises the detection limit). High internal standard area counts may be indicative of coeluting interferences at the retention time of the internal standard in the sample, may be caused by a drift in detector sensitivity, or may be caused by injection of a different amount of sample extract. Coeluting interferences to the internal standard may result in a low bias in reported results quantified by the given internal standard. Injection of a larger volume of extract would result in increased sensitivity of the analysis (lowered detection limit). • If data validation indicated that internal standard area counts were below the lower acceptance limit, then results reported as not-detected were qualified as estimated (“UJ”) and results reported as detected did not require qualification since the calculation corrects for reduced extraction efficiency. • If data validation indicated that internal standard area counts were above the upper acceptance limit, then results reported as detected or as not-detected were qualified as estimated (“J/UJ”). A qualifier code of “IS” was assigned to all results qualified on the basis of internal standard area counts. 2.1.4 Laboratory Control Sample (LCS) Analysis The analyte recoveries obtained for LCS analyses were compared to analytical method requirements and to the acceptance range contained in Table 3-1 of the DCQAP. All analytes specified in the analytical method were spiked into the LCS (see Section 5.2 for effect on data usability). Data associated with LCS recoveries outside the acceptance range were qualified as follows: • If the LCS recovery for an analyte was greater than the upper acceptance limit, suggesting a potential high bias in reported results, all positive results for that analyte in all associated samples were qualified as estimated (“J”) whereas nondetect results were considered to be acceptable for use without qualification because the high bias did not affect nondetect results. • If the LCS recovery for an analyte was less than the lower acceptance limit but >30%, suggesting a potential low bias in reported results, positive and nondetect results for that analyte in all associated samples were qualified as estimated (“J” or “UJ”). • If the LCS recovery for an analyte was less than the lower acceptance limit and <30%, positive sample results were qualified as estimated (“J”) whereas nondetect results were qualified as unusable (“R”) for all associated sample results. • If the LCS recovery for an analyte was greater than the lower acceptance limit but <30% and >10%, positive and nondetect results for that analyte in all associated samples were qualified as estimated (“J” or “UJ”). • If the LCS recovery for an analyte was less than 10%, positive sample results were qualified as estimated (“J”) whereas nondetect results were qualified as unusable (“R”) for all associated sample results. SECTIONTWO Data Validation Process 2-3 A qualifier code of “LCS” was assigned to all results qualified or rejected on the basis of LCS recoveries. Because a summary form was provided for this laboratory performance parameter in the data packages for each of the requested methods, this parameter was evaluated and discussed in each of the review narrative sections presented in Section 3. 2.1.5 Dual Column Confirmation Results A second, dissimilar column confirmation was required by some of the GC analysis methods. If the analytical method or laboratory contract specifies quantitative evaluation of second column result agreement, the following qualifications were considered: • If the relative percent difference (RPD) between primary and secondary column positive detect results was greater than 40%, and the difference between the values reported for the two columns was likely due to co-eluting interference, the data reviewer qualified the reported sample results as presumptive evidence of compound presence, but at an estimated quantity (“NJ”). If the result reported by the laboratory was the higher of the two results, and if there was evidence that the higher value was caused by co-eluting interference, then the data reviewer may cross out the reported result and replace it with the lower of the two results, and • If the samples analyzed were not considered as previously well-characterized for the constituents present and second column confirmation was not performed for a GC analysis, the reported sample results was qualified as presumptive evidence of presence at an estimated quantity (“NJ”). • If the RPD between primary and secondary column positive detect results was greater than 40%, and there was no evidence of co-eluting interferences, the data reviewer qualified the sample result as estimated (“J”). 2.1.6 ICP Interference Check Sample (ICS) for Metals The analytical method specifies the QC acceptance criteria for ICS analysis for metals analysis methods covered under the DCQAP. • If the percent recovery (%R) for analytes present in the ICS sample was above the upper acceptance criterion, then results reported as detected for that analyte in associated samples for which the potentially interfering elements were present at concentrations equivalent to or greater than those present in the ICS sample were qualified as estimated (“J”) with a potential high bias; nondetectable results did not require qualification. • If the %R for analytes present in the ICS sample was less than the lower acceptance criterion, then both detected and nondetected results for that analyte in associated samples for which the potentially interfering elements were present at concentrations equivalent to or greater than those present in the ICS sample were qualified as estimated (“J/UJ”) with a potential low bias. • If the analytes not actually present in the ICS sample were reported at concentrations for which the absolute value of the concentration was greater than the sample quantitation limit for the analyte, then the potential effect and magnitude of the bias was evaluated for SECTIONTWO Data Validation Process 2-4 all associated samples for which the potentially interfering elements were present at concentrations equivalent to or greater than those present in the ICS sample. If the concentration was reported as a positive value and the magnitude of the ICS sample result represents more than 25% of an associated sample result reported as detected, then the associated sample result was qualified as estimated (“J”) with a potential high bias. In this case, nondetectable results did not require qualification. If the concentration was reported as a negative value and the absolute value of the magnitude of the ICS sample result represents more than 25% of an associated sample result (or sample quantitation limit for nondetects), then the associated sample result was qualified as estimated (“J/UJ”) with a potential low bias. A qualifier code of “ICS” was assigned to all results qualified on the basis of ICS results. Because a summary form was provided for this laboratory performance parameter in the data packages for each of the metals, this parameter was evaluated and discussed in each of the review narrative sections presented in Section 3. 2.2 SAMPLE-SPECIFIC DATA EVALUATION CRITERIA The data validation process also included a review of sample-specific criteria for all of the data packages for those parameters that are sample-related. All of the data were reviewed for the sample-specific criteria described in this section. No recalculation of results from the raw data or transcription error checking was performed during the review of the sample-specific criteria. In addition to the review criteria summarized in this section, the validator reviewed the laboratory case narrative to determine if the information provided by the laboratory accurately reflects all issues and noteworthy items encountered during the sample analysis. If notations identified in the case narrative were not covered by this section and were found to indicate a potential effect on data quality, the data reviewer evaluated the problem. If the DCQAP, analytical method, or Functional Guidelines did not specify requirements related to the criterion under evaluation, the data reviewer utilized professional judgment to evaluate the effect of the reported item or condition on the associated analytical data. All uses of professional judgment were described in the data validation review narrative. The results of the sample-specific criteria evaluation are presented in Section 3. 2.2.1 Case Narrative Comments, Chain of Custody (COC) and Sample Receipt The data validation process began with an examination of the laboratory case narrative, COC documentation, and sample receipt and log-in information. Any analytical issues noted in the laboratory case narrative were noted in the data validation narrative along with a summary of the effect on the data and its usability. The analytical results received were compared against those requested on the COC form. Any COC issues or discrepancies were noted in the data validation report. Any issues noted by the laboratory with regard to sample condition upon receipt were also noted. 2.2.2 Holding Times The holding times were compared to the holding time requirements contained in Tables 4-1 and 4-2 of the DCQAP. Results for analyses not performed within holding time limits were qualified SECTIONTWO Data Validation Process 2-5 as estimated (”J/UJ”). If the holding time was grossly exceeded (more than two times the holding time limit), the data reviewer utilized professional judgment to evaluate the need to reject nondetectable results. A qualifier code of “HT” was assigned to all results qualified or rejected on the basis of holding times. 2.2.3 Blanks The results for rinsate blanks, preparation blanks, calibration blanks, and other blanks reported in the data package were reviewed. If the associated sample matrix was a solid; positive rinsate, calibration, and other associated aqueous blank results were converted to equivalent concentrations in the solid samples by assuming that all contamination found in the aqueous blank aliquot analyzed was potentially present at up to five times that amount in the solid sample aliquot analyzed. Sample results for analytes detected in an associated blank at concentrations less than five times the equivalent blank concentration were qualified as nondetect (“U”) at the reported concentration. Negative blank concentrations were evaluated for potential effects (low bias) on sample data when the absolute value of the negative concentration was greater than the method detection limit (MDL). If the negative concentration in a blank may potentially have produced more than a 25% effect on a reported sample result or sample quantitation limit, the associated sample result was qualified as estimated (“J/UJ”). For example, if the blank result was -2 milligrams per liter (mg/L); the MDL was 1 mg/L and the associated sample result was 5 mg/L; the sample result was qualified since a potential low bias of 2 mg/L represents 40% of the reported concentration and the absolute value of the blank concentration was greater than the MDL. Preparation blanks are associated with all samples prepared with that sample (preparation batch). Continuing calibration blank samples are considered to be associated with all samples in a given analytical run. The highest continuing calibration blank samples concentration was used for data qualification. A qualifier code of “MB”, “CCB”, “TB”, “FB” or “RB” was assigned to all results qualified on the basis of method blank, continuing calibration blank, trip blank, field blank, or rinsate blank results, respectively. 2.2.4 Matrix Spike Analysis The MS recoveries were compared to the criteria contained in Table 3-1 of the DCQAP. For organic and inorganic analyses, data associated with MS or MSD recoveries outside the acceptance range were qualified as follows, using guidance from Functional Guidelines: • If the recovery of a MS analyte exceeded the upper limit of the acceptance range, suggesting a potential high bias in sample results, positive results for that target analyte in the sample used for the MS were qualified as estimated (“J”); whereas, nondetect results for that analyte in the sample were considered acceptable for use without qualification. • If the recovery of a MS analyte was less than the lower limit of the acceptance range but ≥10% for organic analyses and ≥30% for inorganic analyses, suggesting a potential low bias in sample results, positive and nondetect results for that analyte in the sample used for the MS were qualified as estimated (“J/UJ”). SECTIONTWO Data Validation Process 2-6 • If the recovery of a MS analyte was less than the lower limit of the acceptance range and <10% for organic analyses and <30% for inorganic analyses, positive results were qualified as estimated (“J”) and nondetect results were qualified as unusable (“R”) for that analyte in the sample used for the MS. • The MS amount for each target analyte was compared to concentrations found for that analyte in the native (unspiked) sample to ensure the appropriate spike level was used, per Functional Guidelines guidance. If the spike level for an analyte was <25% of the concentration for that analyte found in the native sample, the MS percent recovery was considered not to be an appropriate measure of accuracy and, therefore, sample results were not qualified based on those MS results. Qualification of results for associated samples in the batch or data package was not performed based on MS recoveries alone. The data reviewer used professional judgment and considered the results of other QC measures such as surrogate recoveries and LCS recoveries in conjunction with MS/MSD results to determine the need for qualification of associated sample results. 2.2.5 Duplicate Sample Analysis Results for the duplicate sample (laboratory duplicate or MSD) were compared to the criteria in Table 3-1 of the DCQAP. If the duplicate results for an analyte did not satisfy the applicable evaluation criterion, results for that analyte in the sample that the duplicate was performed on were qualified as estimated (“J/UJ”). Professional judgment was used to determine if all results for that analyte in all associated samples would need to be qualified. A qualifier code of “D” was assigned to all results qualified on the basis of laboratory duplicate results. A qualifier code of “MS/SD” was assigned to all results qualified on the basis of MS/MSD precision. 2.2.6 Internal Standard Data (Metals only) Internal standards are used routinely in the analysis for metals by ICP-MS; however, internal standards may be used in the analysis of metals by ICP-AES. Internal standard recoveries for every sample and standard (as the requested level of reporting permits evaluation) will be compared to an acceptance range of 30-120%. Results associated with internal standard recoveries outside the acceptance range where the sample was not diluted and reanalyzed will be qualified as estimated (J/UJ). If upon reanalysis the internal standard recoveries are still outside the acceptance range, the results will be qualified as estimated (J/UJ). A qualifier code of “IS” was assigned to all results qualified on the basis of internal standard recoveries. 2.2.7 Post-Digestion Spike Recovery (Metals Only) The analyte recoveries obtained for post-digestion spike analyses were compared to the acceptance range for accuracy in the analytical method. Under some circumstances, laboratories will quantify results by the method of standard additions to compensate for low post-digestion spike recovery. As such, the low spike recovery would not indicate poor accuracy. However, if the result for the sample on which the post-digestion spike analysis was performed was not obtained by the method of standard additions and the post-digestion spike recovery was outside SECTIONTWO Data Validation Process 2-7 of the acceptance limits, the result for the sample on which the post-digestion spike was run were qualified based on the following guidance: • If the recovery was above the upper acceptance limit, detectable results were qualified as estimated (“J”). No action was taken for nondetects. • If the recovery was below the lower acceptance limit but ≥30%, detectable and nondetectable results were qualified as estimated (“J/UJ”). • If the recovery was <30%, detectable results were qualified as estimated (“J”) and nondetectable results were qualified as unusable (“R”). The data reviewer used professional judgment in conjunction with other QC sample results, such as MS recoveries, to determine the need for qualification of results for other samples (if any) associated with the post-digestion spike analysis. A qualifier code of “PDS” was assigned to all results qualified or rejected on the basis of post-digestion spike recoveries. 2.2.8 Serial Dilution (Metals only) ICP serial dilutions were run to help evaluate whether or not significant physical or chemical interferences exist due to sample matrix. When analyte concentrations were sufficiently high (the concentration in the original sample is minimally a factor of 50 above the IDL) the results obtained for a five-fold-dilution of the original sample were compared to the original results by means of a percent difference (%D). The %D was compared to a precision acceptance limit of ±15%. If the absolute value of the percent difference between the diluted and original result was greater than 15%, all results for that analyte in that sample delivery group (SDG) were qualified as estimated (“J/UJ”). Generally, the diluted result can be considered to be the more accurate result, as long as the diluted concentration was well above the detection limit. Therefore, the data reviewer can generally discern a potential bias direction from a comparison of the diluted and undiluted results. A qualifier code of “DL” was assigned to all results qualified on the basis of serial dilution results. 2.2.9 Surrogate Recoveries The surrogate recoveries obtained for each sample analysis for which surrogates were analyzed were compared to the laboratory historical limits. Results for analytes in the sample associated with surrogate recoveries outside the acceptance range were qualified as follows: • If the surrogate recovery was greater than the upper acceptance limit for any surrogate (for semivolatile organics by GC/MS, two or more surrogates in either fraction must be high), suggesting a potential high bias in reported results, all positive results for associated analytes in that sample were qualified as estimated (“J”), whereas nondetect results were considered to be acceptable for use without qualification. • If the surrogate recovery was less than the lower acceptance limit but >10% (for semivolatile organics by GC/MS, two or more surrogates in either fraction were out with at least one of them being less than the lower limit but >10%), suggesting a potential low bias in reported results, positive and nondetect results for associated analytes in that sample were qualified as estimated (“J” or “UJ”). SECTIONTWO Data Validation Process 2-8 • If any surrogate recovery was <10%, positive results for associated analytes in that sample were qualified as estimated (“J”) whereas associated nondetect results were qualified as unusable (“R”). A qualifier code of “SUR” was assigned to all results qualified as estimated or unusable on the basis of surrogate recoveries. 2.2.10 Field Duplicate Results Criteria for evaluating field duplicate results were not provided in the EPA Functional Guidelines. Therefore, the criteria in Table 3-1 of the DCQAP were used for validation of homogenized or collocated field duplicate results for all analyses. If the criteria were not met for an analyte, all associated sample data for that analyte were qualified as estimated (“J/UJ”). A qualifier code of “FD” was assigned to all results qualified on the basis of field duplicate results. 2.2.11 Anion/Cation Balance Since water is generally electrically neutral, the sum of the dissolved cation concentrations (expressed in milli-equivalents per liter) should equal the sum of the dissolved anion concentrations. For projects in which the major cations and anions were analyzed, the data reviewer should evaluate whether there was an acceptable balance between anion concentrations and cation concentrations. It should be noted that major cations and anions must both be analyzed to complete the anion/cation balance. In accordance with Standard Methods #1030F, the equation used to calculate anion-cation balances is: Percent difference = 100 x (Concentrations of cations - Concentrations of anions) / (Concentrations of cations + Concentrations of anions) Laboratory accuracy control limits for most analytes for this project are ±30%. This level of accuracy is considered to be fully acceptable in meeting the end use objectives of ground water monitoring. A 30% bias in the metals analysis corresponds to an anion-cation balance percent difference of approximately 13%. Therefore, since a 30% bias is considered not to adversely affect the usability of the data, an evaluation criterion of a percent difference less than ± 13% was utilized for anion-cation balance evaluation. If the anion/cation balance was greater than ±13%, the data reviewer used professional judgment to discern likely causes of the imbalance and need for qualification of data. 2.2.12 Balance of Total to Partial Analyses Results for the total analysis of a particular analyte should be greater than the results for a partial analysis of that analyte. For example, the results for total metals should be greater than or equal to the results for dissolved metals, and Ammonia as N concentrations should not be greater than Total Kjeldahl Nitrogen concentrations. Because all results were limited by the accuracy of the analysis, the criteria for accuracy of the analysis were used as the basis for criteria to evaluate the agreement between the results for the partial analysis and the total portion. Where both of the results were greater than five times the higher reporting limit (RL), the criterion utilized was that SECTIONTWO Data Validation Process 2-9 the two values should agree within ±30%. For example, the partial analysis result should not be more than 30% higher than the total analysis result. Where either of the results was less than five times the RL, an evaluation criterion of plus or minus two-times the higher RL was compared against the difference between the partial and total results. If the results for the partial versus total analyses did not satisfy the appropriate evaluation criterion, results for the partial and total analyses were qualified as estimated ("J/UJ"). 2.2.13 Reporting of Isomer Totals (VOCs Only) Total xylenes and 1,2-DCE results were calculated and reported by the laboratory as described in the SWMU South of 400 North Data Validation Report dated November 2007. SECTIONTHREE Data Validation Narrative 3-1 3. Section 3 THREE Data Validation Narrative The results for the October 2024 (Fall) Closed Hazardous Waste Impoundment groundwater samples collected at the former Geneva Steel facility were reported by EET-Denver in one data package. The subsections below present the results of the data validation for the method results reported in each of the data packages. Validation results based on MS/MSD, field duplicates, field blank, and equipment blank results are presented in Section 4. 3.1 DATA VALIDATION NARRATIVE FOR DATA PACKAGE 280-197896-1 Data package 280-197896-1 contained the analytical results for three groundwater samples, one field duplicate sample, one field blank, and one trip blank sample. The table below lists the sample included in this data package, the corresponding laboratory identifications (IDs), the analyses performed, and any QC sample designations. Field Identification Laboratory Identification Analyses QC Designations TB-100924 280-197896-1 VOCs Trip Blank FB-100924 280-197896-2 Field Blank MW-05 280-197896-3 MW-905 280-197896-4 Field Duplicate of MW-05 MW-03 280-197896-5 MS/MSD MW-16 280-197896-6 MS/MSD – Matrix Spike/Matrix Spike Duplicate QC – Quality Control VOCs – Volatile Organic Compounds Analyses: VOCs (8260B) – Benzene, Ethylbenzene, Naphthalene, Toluene, Xylene (total) 3.2 OVERALL ASSESSMENT The data reported in this data package are considered usable as qualified, for meeting project objectives. The qualifiers are presented in Attachment 2. 3.3 NOTES FROM CASE NARRATIVE The laboratory noted several analytical issues in the case narrative. Provided below are the items listed in the laboratory case narrative that are not described in the review below and a summary of the effect on data and its usability. • Several samples were analyzed at a dilution due to foaming at the time of purging. 3.4 CHAIN OF CUSTODY (COC) AND SAMPLE RECEIPT The samples were shipped to EET-Denver under COC. The cooler temperatures upon receipt was 0.3 degrees Celsius (°C), within the recommended ≤6°C temperature criterion. Ice was present in the cooler. The samples were received intact and were consistent with the accompanying COC. Therefore, data qualification was not necessary on the basis of sample receipt and COC. SECTIONFOUR Data Validation Narrative 3-2 3.5 HOLDING TIMES The holding time criterion was met for the analyses. Therefore, data qualification was not necessary. 3.6 BLANKS Method Blanks No target analytes were detected in the method blanks. Therefore, data qualification was not necessary. Trip Blanks Results for one trip blank sample (TB-100924) were reported in this data package. No target analytes were detected in the trip blank. Therefore, data qualification was not necessary. Field Blank Results for one field blank (FB-100924) were reported in this data package. No target analytes were detected in the field blank. Therefore, data qualification was not necessary. 3.7 LABORATORY CONTROL SAMPLE (LCS)/LABORATORY CONTROL SAMPLE DUPLICATE (LCSD) The LCS/ LCSD recoveries were within the DCQAP specified acceptance ranges. Therefore, data qualification was not necessary. The RPDs between LCS and LCSD results for chemistry target analytes contained in the spiking solutions used by the laboratory were within acceptance limits indicating acceptable method precision. 3.8 SURROGATE RECOVERIES The recoveries for the surrogate compounds in field samples were within laboratory-determined acceptance limits. Therefore, data qualification was not necessary. SECTIONFOUR Site-Specific Quality Control Assessment 4-1 4. Section 4 FOUR Site-Specific Quality Control Assessment The following four subsections present a discussion on the MS/MSD analyses, field duplicate analyses, and field blank analyses associated with the samples collected during the October 2024 (Fall) Closed Hazardous Waste Impoundment sampling event. 4.1 MATRIX SPIKE/MATRIX SPIKE DUPLICATE ANALYSES The site-specific MS results were assessed collectively to evaluate potentially systematic matrix effects and to determine the need for qualification of sample results of similar matrix. The table below lists the site-samples that were used to prepare matrix spike samples. As a minimum of one MS set was requested for each analytical method performed for this sampling event, the DCQAP frequency for matrix QC samples (5% per analysis method) was satisfied. Sample Identification Data Package Analyses MW-03 280-197896-1 VOCs VOCs – Volatile Organic Compounds (Benzene, Ethylbenzene, Naphthalene, Toluene, Total Xylene) In accordance with SW-846, the laboratory calculated control limits based on historical recoveries. These control limits were used to assess the accuracy of the site-specific sample matrix for the analyses listed in the table above as specified in the DCQAP. For the sample results that were greater than four times the spike amount, the MS and MSD results were not appropriate for assessing accuracy and precision. For the MS/MSD results that were diluted due to high analyte concentrations or matrix interference, the MS and MSD results were not appropriate for assessing accuracy and precision. In general, if less than 35% of the valid spike recoveries for a given analyte were outside of the acceptance range, only the parent sample results were qualified as estimated. Data qualification was not assigned if the potential biases were high, and the results were non-detect. In general, if more than 35% of the valid spike recoveries for a given analyte were outside of the acceptance range, the results for that analyte in the samples of the same matrix were considered for data qualification. However, qualification of associated sample results in the batch, data package, or sampling event was not performed on the basis of matrix spike recoveries alone. The data reviewer used professional judgment and considered the results of other QC measures such as LCS and surrogate recoveries in conjunction with MS/MSD results for other batches to determine the need for qualification of associated samples. The MS/MSD recoveries and RPDs for the site-specific samples collected in association with this sampling event are presented in Attachment 1. The table below presents a summary of only those results that did not meet the acceptance criterion described above, as well as any resultant data qualification. Attachment 1 presents the statistics and details that resulted in data qualification. The following data qualifications were issued: • If the MS/MSD recoveries were below the acceptance limits, results were qualified as estimated (J/UJ) to reflect the potential low bias. • If the MS/MSD recoveries were above the acceptance limits, detectable results were qualified as estimated (J) to reflect the potential high bias. Data qualification was not issued to non-detect results. SECTIONFOUR Site-Specific Quality Control Assessment 4-2 • If the MS/MSD recoveries were below 10% for organic compounds or below 30% for inorganic compounds, non-detect results were qualified as unusable (R) and detect results were qualified as estimated (J) to reflect the potential low bias. • If the RPD between the MS/MSD results exceeded the acceptance limit, results were qualified as estimated (J/UJ) with an indeterminate bias. The MS and MSD recoveries for target analytes contained in the spiking solutions used by the laboratory were within acceptance limits indicating acceptable method accuracy and sample matrix accuracy. Therefore, data qualification was not necessary. The RPDs between MS and MSD results for chemistry target analytes contained in the spiking solutions used by the laboratory were within acceptance limits indicating acceptable method precision and sample matrix precision. Therefore, data qualification was not necessary. 4.2 FIELD DUPLICATE ANALYSES One field duplicate sample was collected during this sampling event (MW-05/MW-905), per the DCQAP frequency for field duplicate samples (10% per analysis method) was satisfied. The field duplicate results satisfied the applicable evaluation criteria listed in Section 2. Therefore, data qualification was not necessary. 4.3 FIELD BLANK ANALYSES One field blank (FB-101124) was collected in association with this sampling event and analyzed for VOCs. As one field blank was collected for this sampling event, the DCQAP frequency for field blank sample (5% per analysis method) was satisfied. No target analytes were reported in the field blank. Therefore, data qualification was not necessary. 4.4 EQUIPMENT BLANK ANALYSES As dedicated equipment was used to collect the samples, an equipment blank was not collected in association with this sampling event. No further action was necessary. SECTIONFIVE Overall Assessment of Analytical Data 5-1 5. Section 5 FIVE Overall Assessment of Analytical Data The October 2024 (Fall) Geneva Steel Closed Hazardous Waste Impoundment groundwater data are considered usable, as qualified. A general overall assessment of data quality assurance objectives is provided below. 5.1 PRECISION Precision is a measure of mutual agreement among replicates (or between duplicate) or co-located sample measurements of the same analyte. The closer the numerical values of the measurements are to each other, the more precise the measurement. Precision for a single analyte was expressed as a RPD or absolute difference between results of field duplicate results, LCS/LCSD results, and MS/MSD results. The LCS/LCSD, MS/MSD, and method duplicate results for VOCs analyses satisfied the precision evaluation criteria. As such, the overall level of precision demonstrated by the analyses and with respect to the site-specific sample matrix is considered acceptable. Precision of sampling and analyses was evaluated by the comparison of field duplicate results. One field duplicate sample (Section 4.2) was collected during this sampling event. The field duplicate results satisfied the precision evaluation criteria. As such, the field duplicate sample results are indicative of satisfactory sampling and analysis precision and satisfactory representativeness of the samples to the medium sampled. 5.2 ACCURACY Accuracy is a measure of bias in a measurement system. The closer the value of the measurement agrees with the true value, the more accurate the measurement. This was expressed as the percent recovery of surrogates and of target analytes in LCS/LCSDs and MS/MSDs. The surrogate recoveries associated with field samples were within laboratory-determined acceptance limits. The LCS recoveries were within the DCQAP specified acceptance ranges. The MS/MSD results satisfied the accuracy evaluation criteria. No data were qualified as unusable on the basis of surrogate, LCS/LCSD or MS/MSD recoveries. As such, the overall level of accuracy demonstrated by the analyses and with respect to the site-specific sample matrix is considered acceptable. 5.3 REPRESENTATIVENESS Representativeness is the degree to which data accurately and precisely represent a characteristic of a population, parameter variations at a sampling point, or an environmental condition. The design of, and rationale for, the sampling program (in terms of the purpose for sampling, selecting the sampling locations, the number of samples to be collected, the ambient conditions for sample collection, the frequencies and timing for sampling, and the sampling techniques) assures that the environmental condition has been sufficiently represented. Representativeness was maintained during the sampling effort by completing all sampling using similar sampling procedures and in accordance with approved work plans. SECTIONFIVE Overall Assessment of Analytical Data 5-2 5.4 COMPLETENESS Completeness is defined as the ratio of the number of valid analytical results (valid analytical results include values qualified as estimated) to the total number of analytical results requested on samples submitted for analysis. The results were considered usable for meeting project objectives. As such, the overall analytical completeness is 100%, satisfying the overall completeness goal for investigative activities of 80% for each sampling event. 5.5 COMPARABILITY Comparability expresses the confidence with which one data set can be compared to another. Comparability can be related to accuracy and precision because these quantities are measures of data reliability. Data are comparable if collection techniques, measurement procedures, method and reporting are equivalent for the samples within a sample set. To maximize comparability, all samples covered by this report were collected and analyzed in accordance with prescribed quality assurance and quality control measures. As acceptable levels of overall accuracy and precision were attained, the data reported within these data packages are considered comparable to one another. 5.6 SENSITIVITY RLs are established by the analytical laboratory based on the MDLs, historical data, and comparison to EPA limits for the respective methods. The laboratory reported positive results between the MDL and the RL. To reflect the higher degree of uncertainty associated with values reported between the MDL and RL, these results were qualified as estimated (“J”). A qualifier code of SQL, denoting sample quantitation limit, was assigned to results qualified for this reason. The laboratory RLs met or were lower than (higher sensitivity) the maximum laboratory RLs specified in the DCQAP with the exceptions noted below. Sample MW-03 was analyzed at a dilution for VOCs analysis due to foaming during the analysis. This resulted in elevated reporting limits; however, ethylbenzene, naphthalene, toluene, and/or xylenes total were reported as non-detect at an elevated reporting limit. Therefore, the non-detect results for ethylbenzene, naphthalene, toluene, and xylenes total will need to be evaluated by the end user of the data with respect to project objectives. Attachment 1 Matrix Spike and Matrix Spike Duplicate Assessment Attachment 1 Matrix Spike and Matrix Spike Duplicate Assessment Attachment 2 Summary of Qualified Data Attachment 2 Summary of Qualified Data Attachment 1 MS/MSD Collective Assessment for the October 2024 (Fall) Closed Hazardous Waste Impoundments (CHWI) Groundwater Sampling Event - Geneva Steel Sample ID Analyte %R Criteria Range RPD Control Limit MS MSD RPD Total number of %Rs below the lower Limit Total number of %Rs above the upper limit Total number of applicable MS/MSD Results Percent of MS/MSD %Rs outside acceptance range Average MS/MSD %Rs Benzene 80-120 20 103 101 0.7 0 0 2 0% 102 Ethylbenzene 80-120 20 97 97 0 0 0 2 0% 97 Naphthalene 60-124 21 104 103 0.77 0 0 2 0% 104 Toluene 80-120 20 97 96 0.82 0 0 2 0% 97 Xylenes (Total)80-120 20 100 99 0.4 0 0 2 0% 100 Potentially applicable footnote: * = Overall average of recoveries was within control limits; qualification of data was limited to parent sample(s) %R = Percent Recovery ID = Identification MS = Matrix Spike MSD = Matrix Spike Duplicate NA = Not Applicable because parent sample result was greater than four times the spike amount added NC = Not Calculated due to dilution RPD = Relative Percent Difference Below the lower limit of the acceptance range Above the upper limit of the acceptance range RPD between the MS and MSD results exceeded the criterion More than 35% of the applicable MS/MSD recoveries were outside the acceptance range Recovery is less than 10% for organic and 30% for inorganics Method 8260D MW-05 Attachment 2 Summary of Qualified Data for the October 2024 (Fall) Closed Hazardous Waste Impoundments (CHWI) Groundwater Sampling Event - Geneva Steel Sample Code Laboratory Sample ID Field Sample ID Dilution Analytical Method Analyte Result MDL RL Units Flag Reason Code FD 280‐197896‐4MW‐905 1 SW846 8260D BENZENE 0.89 0.14 1 UG/L J SQL‐I N 280‐197896‐5MW‐03 5 SW846 8260D TOLUENE 1.7 1.6 5 UG/L J SQL‐I N 280‐197896‐6MW‐16 1 SW846 8260D BENZENE 0.61 0.14 1 UG/L J SQL‐I UG/L Micrograms per Liter ID Identification FD Field Duplicate Sample MDL Method Detection Limit N Normal Sample ND Non‐Detect RL Reporting Limit Qualifier J The result is an estimated quantity. The associated numerical value is the approximate concentration of the analyte in the sample Reason Code SQL The analysis meets all qualitative identification criteria, but the measured concentration is less than the reporting limit Bias Code I Bias in sample result is indeterminate. Attachment C Laboratory Analytical Report with Chain-of-Custody Record ANALYTICAL REPORT PREPARED FOR Attn: Tammi Messersmith AECOM 756 Winchester Street Suite 400 Salt Lake City UT 84107 Generated 10/22/2024 9:29 AM JOB DESCRIPTION CHWI Fall 2024 JOB NUMBER 280-197896-1 See page two for job notes and contact information. Arvada CO 80002 4955 Yarrow Street Eurofins Denver Page 1 of 426 Eurofins Denver Eurofins Denver is a laboratory within TestAmerica Laboratories, Inc., a company within Eurofins Environment Testing Group of Companies Job Notes This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager. Authorization Generated 10/22/2024 9:29 AM Authorized for release by Shelby R McCabe, Project Manager I Shelby.McCabe@et.eurofinsus.com 303 736-0165 Page 2 of 426 Table of Contents Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8 Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21 Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22 Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24 COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .36 Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .111 8260D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .111 8260D QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .112 8260D Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .121 Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .168 8260D ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .168 8260D CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .362 Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .376 8260D Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .376 8260D Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .384 Page 3 of 426 Table of Contents 8260D LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .391 8260D MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .403 8260D Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417 8260D Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .419 Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 424 Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .425 Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426 Page 4 of 426 Definitions/Glossary Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Qualifiers GC/MS VOA Qualifier Description J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Qualifier U Indicates the analyte was analyzed for but not detected. Glossary These commonly used abbreviations may or may not be present in this report. ☼Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level" MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Eurofins Denver Page 5 of 426 Job Narrative 280-197896-1 Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification Summary Page unless otherwise noted under the individual analysis. Data qualifiers and/or narrative comments are included to explain any exceptions, if applicable. Matrix QC may not be reported if insufficient sample is provided or site-specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD may be performed, unless otherwise specified in the method. Surrogate and/or isotope dilution analyte recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in the narrative. Regulated compliance samples (e.g. SDWA, NPDES) must comply with the associated agency requirements/permits. Receipt The samples were received on 10/10/2024 9:20 AM. Unless otherwise noted below, the samples arrived in good condition, and, where required, properly preserved and on ice. The temperature of the cooler at receipt time was 0.3°C. Method 8260D - Volatile Organic Compounds by GC/MSSamples TB-100924 (280-197896-1), FB-100924 (280-197896-2), MW-05 (280-197896-3), MW-905 (280-197896-4),MW-03 (280-197896-5), MW-03 (280-197896-5MS), MW-03 (280-197896-5MSD) and MW-16 (280-197896-6) were analyzed for Volatile Organic Compounds by GC/MS. The samples were analyzed on 10/20/2024 and 10/21/2024. Samples MW-03 (280-197896-5)[5x], MW-03 (280-197896-5MS)[5x] and MW-03 (280-197896-5MSD)[5x] required dilution prior to analysis. The reporting limits have been adjusted accordingly. The following volatiles samples in batch 280-671719 were diluted due to foaming at the time of purging during the original sample analysis: MW-03 (280-197896-5), MW-03 (280-197896-5[MS]) and MW-03 (280-197896-5[MSD]). Elevated reporting limits (RLs) are provided. Page 6 of 426 Detection Summary Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Client Sample ID: TB-100924 Lab Sample ID: 280-197896-1 No Detections. Client Sample ID: FB-100924 Lab Sample ID: 280-197896-2 No Detections. Client Sample ID: MW-05 Lab Sample ID: 280-197896-3 Benzene RL 1.0 ug/L MDL 0.14 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA11.0 8260D Client Sample ID: MW-905 Lab Sample ID: 280-197896-4 Benzene RL 1.0 ug/L MDL 0.14 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA1J0.89 8260D Client Sample ID: MW-03 Lab Sample ID: 280-197896-5 Benzene RL 5.0 ug/L MDL 0.72 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA51608260D Toluene 5.0 ug/L1.6 Total/NA51.7 J 8260D Client Sample ID: MW-16 Lab Sample ID: 280-197896-6 Benzene RL 1.0 ug/L MDL 0.14 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Total/NA1J0.61 8260D Eurofins Denver This Detection Summary does not include radiochemical test results. Page 7 of 426 Client Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Lab Sample ID: 280-197896-1Client Sample ID: TB-100924 Matrix: WaterDate Collected: 10/09/24 08:00 Date Received: 10/10/24 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL 0.14 U 1.0 0.14 ug/L 10/20/24 23:53 1 Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier Benzene 1.0 0.14 ug/L 10/20/24 23:53 10.14 UEthylbenzene 3.0 0.99 ug/L 10/20/24 23:53 10.99 UNaphthalene 1.0 0.32 ug/L 10/20/24 23:53 10.32 UToluene 1.0 0.11 ug/L 10/20/24 23:53 10.11 UXylenes, Total 1,2-Dichloroethane-d4 (Surr)101 70 -127 10/20/24 23:53 1 Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery 4-Bromofluorobenzene (Surr)104 10/20/24 23:53 178-120 Toluene-d8 (Surr)102 10/20/24 23:53 180-125 Dibromofluoromethane (Surr)97 10/20/24 23:53 177-120 Eurofins Denver Page 8 of 426 Client Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Lab Sample ID: 280-197896-2Client Sample ID: FB-100924 Matrix: WaterDate Collected: 10/09/24 08:00 Date Received: 10/10/24 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL 0.14 U 1.0 0.14 ug/L 10/21/24 00:15 1 Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier Benzene 1.0 0.14 ug/L 10/21/24 00:15 10.14 UEthylbenzene 3.0 0.99 ug/L 10/21/24 00:15 10.99 UNaphthalene 1.0 0.32 ug/L 10/21/24 00:15 10.32 UToluene 1.0 0.11 ug/L 10/21/24 00:15 10.11 UXylenes, Total 1,2-Dichloroethane-d4 (Surr)98 70 -127 10/21/24 00:15 1 Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery 4-Bromofluorobenzene (Surr)105 10/21/24 00:15 178-120 Toluene-d8 (Surr)103 10/21/24 00:15 180-125 Dibromofluoromethane (Surr)97 10/21/24 00:15 177-120 Eurofins Denver Page 9 of 426 Client Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Lab Sample ID: 280-197896-3Client Sample ID: MW-05 Matrix: WaterDate Collected: 10/09/24 10:35 Date Received: 10/10/24 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL 1.0 1.0 0.14 ug/L 10/21/24 02:02 1 Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier Benzene 1.0 0.14 ug/L 10/21/24 02:02 10.14 UEthylbenzene 3.0 0.99 ug/L 10/21/24 02:02 10.99 UNaphthalene 1.0 0.32 ug/L 10/21/24 02:02 10.32 UToluene 1.0 0.11 ug/L 10/21/24 02:02 10.11 UXylenes, Total 1,2-Dichloroethane-d4 (Surr)101 70 -127 10/21/24 02:02 1 Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery 4-Bromofluorobenzene (Surr)103 10/21/24 02:02 178-120 Toluene-d8 (Surr)102 10/21/24 02:02 180-125 Dibromofluoromethane (Surr)96 10/21/24 02:02 177-120 Eurofins Denver Page 10 of 426 Client Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Lab Sample ID: 280-197896-4Client Sample ID: MW-905 Matrix: WaterDate Collected: 10/09/24 10:45 Date Received: 10/10/24 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL 0.89 J 1.0 0.14 ug/L 10/21/24 02:23 1 Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier Benzene 1.0 0.14 ug/L 10/21/24 02:23 10.14 UEthylbenzene 3.0 0.99 ug/L 10/21/24 02:23 10.99 UNaphthalene 1.0 0.32 ug/L 10/21/24 02:23 10.32 UToluene 1.0 0.11 ug/L 10/21/24 02:23 10.11 UXylenes, Total 1,2-Dichloroethane-d4 (Surr)98 70 -127 10/21/24 02:23 1 Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery 4-Bromofluorobenzene (Surr)104 10/21/24 02:23 178-120 Toluene-d8 (Surr)102 10/21/24 02:23 180-125 Dibromofluoromethane (Surr)95 10/21/24 02:23 177-120 Eurofins Denver Page 11 of 426 Client Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Lab Sample ID: 280-197896-5Client Sample ID: MW-03 Matrix: WaterDate Collected: 10/09/24 12:30 Date Received: 10/10/24 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL 160 5.0 0.72 ug/L 10/21/24 00:36 5 Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier Benzene 5.0 0.72 ug/L 10/21/24 00:36 50.72 UEthylbenzene 15 5.0 ug/L 10/21/24 00:36 55.0 UNaphthalene 5.0 1.6 ug/L 10/21/24 00:36 51.7 JToluene 5.0 0.57 ug/L 10/21/24 00:36 50.57 UXylenes, Total 1,2-Dichloroethane-d4 (Surr)99 70 -127 10/21/24 00:36 5 Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery 4-Bromofluorobenzene (Surr)101 10/21/24 00:36 578-120 Toluene-d8 (Surr)104 10/21/24 00:36 580-125 Dibromofluoromethane (Surr)93 10/21/24 00:36 577-120 Eurofins Denver Page 12 of 426 Client Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Lab Sample ID: 280-197896-6Client Sample ID: MW-16 Matrix: WaterDate Collected: 10/09/24 13:00 Date Received: 10/10/24 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS RL MDL 0.61 J 1.0 0.14 ug/L 10/21/24 02:45 1 Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier Benzene 1.0 0.14 ug/L 10/21/24 02:45 10.14 UEthylbenzene 3.0 0.99 ug/L 10/21/24 02:45 10.99 UNaphthalene 1.0 0.32 ug/L 10/21/24 02:45 10.32 UToluene 1.0 0.11 ug/L 10/21/24 02:45 10.11 UXylenes, Total 1,2-Dichloroethane-d4 (Surr)101 70 -127 10/21/24 02:45 1 Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery 4-Bromofluorobenzene (Surr)101 10/21/24 02:45 178-120 Toluene-d8 (Surr)102 10/21/24 02:45 180-125 Dibromofluoromethane (Surr)96 10/21/24 02:45 177-120 Eurofins Denver Page 13 of 426 Surrogate Summary Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Method: 8260D - Volatile Organic Compounds by GC/MS Prep Type: Total/NAMatrix: Water Lab Sample ID Client Sample ID (70-127) (78-120) (80-125) (77-120) DCA BFB TOL DBFM 101 104 102 97280-197896-1 Percent Surrogate Recovery (Acceptance Limits) TB-100924 98 105 103 97280-197896-2 FB-100924 101 103 102 96280-197896-3 MW-05 98 104 102 95280-197896-4 MW-905 99 101 104 93280-197896-5 MW-03 101 101 103 99280-197896-5 MS MW-03 99 101 102 98280-197896-5 MSD MW-03 101 101 102 96280-197896-6 MW-16 98 103 104 99LCS 280-671719/4 Lab Control Sample 99 102 103 100LCSD 280-671719/6 Lab Control Sample Dup 99 102 104 96MB 280-671719/9 Method Blank Surrogate Legend DCA = 1,2-Dichloroethane-d4 (Surr) BFB = 4-Bromofluorobenzene (Surr) TOL = Toluene-d8 (Surr) DBFM = Dibromofluoromethane (Surr) Eurofins Denver Page 14 of 426 QC Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Method: 8260D - Volatile Organic Compounds by GC/MS Client Sample ID: Method BlankLab Sample ID: MB 280-671719/9 Matrix: Water Prep Type: Total/NA Analysis Batch: 671719 RL MDL Benzene 0.14 U 1.0 0.14 ug/L 10/20/24 23:26 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier 0.14 U 0.141.0 ug/L 10/20/24 23:26 1Ethylbenzene 0.99 U 0.993.0 ug/L 10/20/24 23:26 1Naphthalene 0.32 U 0.321.0 ug/L 10/20/24 23:26 1Toluene 0.11 U 0.111.0 ug/L 10/20/24 23:26 1Xylenes, Total 1,2-Dichloroethane-d4 (Surr)99 70 -127 10/20/24 23:26 1 MB MB Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery 102 10/20/24 23:26 14-Bromofluorobenzene (Surr)78 -120 104 10/20/24 23:26 1Toluene-d8 (Surr)80 -125 96 10/20/24 23:26 1Dibromofluoromethane (Surr)77 -120 Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-671719/4 Matrix: Water Prep Type: Total/NA Analysis Batch: 671719 Benzene 50.0 47.0 ug/L 94 80 -120 Analyte LCS LCS DUnitResult Qualifier %Rec Spike Added %Rec Limits Ethylbenzene 50.0 47.1 ug/L 94 80 -120 Naphthalene 50.0 48.9 ug/L 98 60 -124 Toluene 50.0 46.2 ug/L 92 80 -120 Xylenes, Total 100 96.8 ug/L 97 80 -120 1,2-Dichloroethane-d4 (Surr)70 -127 Surrogate 98 LCS LCS Qualifier Limits%Recovery 1034-Bromofluorobenzene (Surr)78 -120 104Toluene-d8 (Surr)80 -125 99Dibromofluoromethane (Surr)77 -120 Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-671719/6 Matrix: Water Prep Type: Total/NA Analysis Batch: 671719 Benzene 50.0 47.8 ug/L 96 80 -120 2 20 Analyte LCSD LCSD DUnitResult Qualifier %Rec Spike Added %Rec Limits LimitRPD RPD Ethylbenzene 50.0 47.8 ug/L 96 80 -120 1 20 Naphthalene 50.0 50.3 ug/L 101 60 -124 3 21 Toluene 50.0 47.4 ug/L 95 80 -120 3 20 Xylenes, Total 100 98.6 ug/L 99 80 -120 2 20 1,2-Dichloroethane-d4 (Surr)70 -127 Surrogate 99 LCSD LCSD Qualifier Limits%Recovery 1024-Bromofluorobenzene (Surr)78 -120 103Toluene-d8 (Surr)80 -125 100Dibromofluoromethane (Surr)77 -120 Eurofins Denver Page 15 of 426 QC Sample Results Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Client Sample ID: MW-03Lab Sample ID: 280-197896-5 MS Matrix: Water Prep Type: Total/NA Analysis Batch: 671719 Benzene 160 125 285 ug/L 103 80 -120 Analyte MS MS DUnitResult Qualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits Ethylbenzene 0.72 U 125 121 ug/L 97 80 -120 Naphthalene 5.0 U 125 130 ug/L 104 60 -124 Toluene 1.7 J 125 123 ug/L 97 80 -120 Xylenes, Total 0.57 U 250 249 ug/L 100 80 -120 1,2-Dichloroethane-d4 (Surr)70 -127 Surrogate 101 MS MS Qualifier Limits%Recovery 1014-Bromofluorobenzene (Surr)78 -120 103Toluene-d8 (Surr)80 -125 99Dibromofluoromethane (Surr)77 -120 Client Sample ID: MW-03Lab Sample ID: 280-197896-5 MSD Matrix: Water Prep Type: Total/NA Analysis Batch: 671719 Benzene 160 125 283 ug/L 101 80 -120 1 20 Analyte MSD MSD DUnitResult Qualifier %Rec Spike Added Sample Result Sample Qualifier %Rec Limits LimitRPD RPD Ethylbenzene 0.72 U 125 121 ug/L 97 80 -120 0 20 Naphthalene 5.0 U 125 129 ug/L 103 60 -124 0 21 Toluene 1.7 J 125 122 ug/L 96 80 -120 1 20 Xylenes, Total 0.57 U 250 248 ug/L 99 80 -120 0 20 1,2-Dichloroethane-d4 (Surr)70 -127 Surrogate 99 MSD MSD Qualifier Limits%Recovery 1014-Bromofluorobenzene (Surr)78 -120 102Toluene-d8 (Surr)80 -125 98Dibromofluoromethane (Surr)77 -120 Eurofins Denver Page 16 of 426 QC Association Summary Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 GC/MS VOA Analysis Batch: 671719 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Water 8260D280-197896-1 TB-100924 Total/NA Water 8260D280-197896-2 FB-100924 Total/NA Water 8260D280-197896-3 MW-05 Total/NA Water 8260D280-197896-4 MW-905 Total/NA Water 8260D280-197896-5 MW-03 Total/NA Water 8260D280-197896-6 MW-16 Total/NA Water 8260DMB 280-671719/9 Method Blank Total/NA Water 8260DLCS 280-671719/4 Lab Control Sample Total/NA Water 8260DLCSD 280-671719/6 Lab Control Sample Dup Total/NA Water 8260D280-197896-5 MS MW-03 Total/NA Water 8260D280-197896-5 MSD MW-03 Total/NA Eurofins Denver Page 17 of 426 Lab Chronicle Client: AECOM Job ID: 280-197896-1 Project/Site: CHWI Fall 2024 Client Sample ID: TB-100924 Lab Sample ID: 280-197896-1 Matrix: WaterDate Collected: 10/09/24 08:00 Date Received: 10/10/24 09:20 Analysis 8260D MD10/20/24 23:531 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: FB-100924 Lab Sample ID: 280-197896-2 Matrix: WaterDate Collected: 10/09/24 08:00 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 00:151 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: MW-05 Lab Sample ID: 280-197896-3 Matrix: WaterDate Collected: 10/09/24 10:35 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 02:021 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: MW-905 Lab Sample ID: 280-197896-4 Matrix: WaterDate Collected: 10/09/24 10:45 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 02:231 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: MW-03 Lab Sample ID: 280-197896-5 Matrix: WaterDate Collected: 10/09/24 12:30 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 00:365 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: MW-16 Lab Sample ID: 280-197896-6 Matrix: WaterDate Collected: 10/09/24 13:00 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 02:451 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Eurofins Denver Page 18 of 426 Lab Chronicle Client: AECOM Job ID: 280-197896-1 Project/Site: CHWI Fall 2024 Client Sample ID: Method Blank Lab Sample ID: MB 280-671719/9 Matrix: WaterDate Collected: N/A Date Received: N/A Analysis 8260D MD10/20/24 23:261 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: Lab Control Sample Lab Sample ID: LCS 280-671719/4 Matrix: WaterDate Collected: N/A Date Received: N/A Analysis 8260D MD10/20/24 21:381 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 280-671719/6 Matrix: WaterDate Collected: N/A Date Received: N/A Analysis 8260D MD10/20/24 22:211 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: MW-03 Lab Sample ID: 280-197896-5 MS Matrix: WaterDate Collected: 10/09/24 12:30 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 03:495 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Client Sample ID: MW-03 Lab Sample ID: 280-197896-5 MSD Matrix: WaterDate Collected: 10/09/24 12:30 Date Received: 10/10/24 09:20 Analysis 8260D MD10/21/24 04:105 EET DEN671719 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 5 mL 5 mL Instrument ID: VMS_MS1 Laboratory References: EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL (303)736-0100 Eurofins Denver Page 19 of 426 Method Summary Job ID: 280-197896-1Client: AECOM Project/Site: CHWI Fall 2024 Method Method Description LaboratoryProtocol SW8468260DVolatile Organic Compounds by GC/MS EET DEN SW8465030BPurge and Trap EET DEN Protocol References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL (303)736-0100 Eurofins Denver Page 20 of 426 Sample Summary Client: AECOM Job ID: 280-197896-1 Project/Site: CHWI Fall 2024 Lab Sample ID Client Sample ID Matrix Collected Received 280-197896-1 TB-100924 Water 10/09/24 08:00 10/10/24 09:20 280-197896-2 FB-100924 Water 10/09/24 08:00 10/10/24 09:20 280-197896-3 MW-05 Water 10/09/24 10:35 10/10/24 09:20 280-197896-4 MW-905 Water 10/09/24 10:45 10/10/24 09:20 280-197896-5 MW-03 Water 10/09/24 12:30 10/10/24 09:20 280-197896-6 MW-16 Water 10/09/24 13:00 10/10/24 09:20 Eurofins DenverPage 21 of 426 Lab Name:Job No.: GC/MS VOA MANUAL INTEGRATION SUMMARY Eurofins Denver 280-197896-1 SDG No.: Instrument ID:Analysis Batch Number:VMS_MS1 671165 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/13 MS1_0297.D10/16/24 00:19 GC Column:DB-624 (60.25)ID:0.25(mm) Chloroethane Baseline AF7X 10/16/24 07:072.61 Tetrahydrofuran Baseline AF7X 10/16/24 07:075.25 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/40 MS1_0298.D10/16/24 00:40 GC Column:DB-624 (60.25)ID:0.25(mm) Isobutyl alcohol Assign Peak AF7X 10/16/24 07:095.65 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/41 MS1_0299.D10/16/24 01:02 GC Column:DB-624 (60.25)ID:0.25(mm) Isobutyl alcohol Assign Peak AF7X 10/16/24 07:105.65 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/42 MS1_0300.D10/16/24 01:23 GC Column:DB-624 (60.25)ID:0.25(mm) Isobutyl alcohol Assign Peak AF7X 10/16/24 07:115.65 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/43 MS1_0301.D10/16/24 01:45 GC Column:DB-624 (60.25)ID:0.25(mm) Isobutyl alcohol Assign Peak AF7X 10/16/24 07:125.65 8260D Page 22 of 426 Lab Name:Job No.: GC/MS VOA MANUAL INTEGRATION SUMMARY Eurofins Denver 280-197896-1 SDG No.: Instrument ID:Analysis Batch Number:VMS_MS1 671165 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/53 MS1_0313.D10/16/24 06:02 GC Column:DB-624 (60.25)ID:0.25(mm) cis-1,4-Dichloro-2-butene Wrong peak AF7X 10/16/24 07:389.77 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/54 MS1_0314.D10/16/24 06:23 GC Column:DB-624 (60.25)ID:0.25(mm) cis-1,4-Dichloro-2-butene Wrong peak AF7X 10/16/24 08:129.77 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/55 MS1_0315.D10/16/24 06:45 GC Column:DB-624 (60.25)ID:0.25(mm) cis-1,4-Dichloro-2-butene Wrong peak AF7X 10/16/24 08:129.77 Lab Sample ID:Client Sample ID: Date Analyzed:Lab File ID: COMPOUND NAME RETENTION TIME MANUAL INTEGRATION DATEANALYSTREASON IC 280-671165/56 MS1_0316.D10/16/24 07:06 GC Column:DB-624 (60.25)ID:0.25(mm) cis-1,4-Dichloro-2-butene Wrong peak AF7X 10/16/24 08:139.77 8260D Page 23 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte MV-Gas A_00200 Bromomethane 5 ug/mL500 uL 10 uL10/21/24 10/15/24Cal Dil Std_00422 P&T Methanol, Lot ED137-US Chloroethane 5 ug/mL Chloromethane 5 ug/mL Dichlorodifluoromethane 5 ug/mL Dichlorofluoromethane 5 ug/mL Trichlorofluoromethane 5 ug/mL Vinyl chloride 5 ug/mL 2-Chloroethyl vinyl ether 5 ug/mL Acrolein 49.375 ug/mLMV-MegaMainA_00116 25 uL 2-Butanone (MEK)20 ug/mL 2-Hexanone 20 ug/mL 4-Methyl-2-pentanone (MIBK)20 ug/mL Acetone 20 ug/mL Vinyl acetate 10 ug/mL Cyclohexanone 150 ug/mL 1,1,1,2-Tetrachloroethane 5 ug/mL 1,1,1-Trichloroethane 5 ug/mL 1,1,2,2-Tetrachloroethane 5 ug/mL 1,1,2-Trichloro-1,2,2-trifluoroethane 5 ug/mL 1,1,2-Trichloroethane 5 ug/mL 1,1-Dichloroethane 5 ug/mL 1,1-Dichloroethene 5 ug/mL 1,1-Dichloropropene 5 ug/mL 1,2,3-Trichlorobenzene 5 ug/mL 1,2,3-Trichloropropane 5 ug/mL 1,2,4-Trichlorobenzene 5 ug/mL 1,2,4-Trimethylbenzene 5 ug/mL 1,2-Dibromo-3-Chloropropane 5 ug/mL 1,2-Dichlorobenzene 5 ug/mL 1,2-Dichloroethane 5 ug/mL 1,2-Dichloropropane 5 ug/mL 1,3,5-Trimethylbenzene 5 ug/mL 1,3-Dichlorobenzene 5 ug/mL 1,3-Dichloropropane 5 ug/mL 1,4-Dichlorobenzene 5 ug/mL 1,4-Dioxane 100 ug/mL 2,2-Dichloropropane 5 ug/mL 2-Chlorotoluene 5 ug/mL 2-Methyl-2-propanol 50 ug/mL 3-Chloro-1-propene 5 ug/mL 4-Chlorotoluene 5 ug/mL 4-Isopropyltoluene 5 ug/mL Acrylonitrile 50 ug/mL Benzene 5 ug/mL Bromobenzene 5 ug/mL Page 24 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte Bromoform 5 ug/mL Carbon disulfide 5 ug/mL Carbon tetrachloride 5 ug/mL Chlorobenzene 5 ug/mL Chlorobromomethane 5 ug/mL Chlorodibromomethane 5 ug/mL Chloroform 5 ug/mL cis-1,2-Dichloroethene 5 ug/mL cis-1,3-Dichloropropene 5 ug/mL Cyclohexane 5 ug/mL Dibromomethane 5 ug/mL Dichlorobromomethane 5 ug/mL Ethyl ether 5 ug/mL Ethyl methacrylate 5 ug/mL Ethylbenzene 5 ug/mL Ethylene Dibromide 5 ug/mL Hexachlorobutadiene 5 ug/mL Hexane 5 ug/mL Iodomethane 5 ug/mL Isobutyl alcohol 125 ug/mL Isopropylbenzene 5 ug/mL m-Xylene & p-Xylene 5 ug/mL Methyl acetate 10 ug/mL Methyl tert-butyl ether 5 ug/mL Methylcyclohexane 5 ug/mL Methylene Chloride 5 ug/mL n-Butylbenzene 5 ug/mL n-Heptane 5 ug/mL N-Propylbenzene 5 ug/mL Naphthalene 5 ug/mL o-Xylene 5 ug/mL sec-Butylbenzene 5 ug/mL Styrene 5 ug/mL tert-Butylbenzene 5 ug/mL Tetrachloroethene 5 ug/mL Tetrahydrofuran 10 ug/mL Toluene 5 ug/mL trans-1,2-Dichloroethene 5 ug/mL trans-1,3-Dichloropropene 5 ug/mL trans-1,4-Dichloro-2-butene 5 ug/mL Trichloroethene 5 ug/mL 1-Chlorohexane 4 ug/mL 2-Pentanone 16 ug/mL sec-Butyl Alcohol 120 ug/mL MV-569722.sec_00019 Bromomethane 250 ug/mL12.5 mL 1250 uL11/12/24 10/12/24.MV-Gas A_00200 P&T Methanol, Lot 198123 Chloroethane 250 ug/mL Chloromethane 250 ug/mL Page 25 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte Dichlorodifluoromethane 250 ug/mL Dichlorofluoromethane 250 ug/mL Trichlorofluoromethane 250 ug/mL Vinyl chloride 250 ug/mL MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL 04/30/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0210106..MV-569722.sec_00019 Chloroethane 2500 ug/mL Chloromethane 2500 ug/mL Dichlorodifluoromethane 2500 ug/mL Dichlorofluoromethane 2500 ug/mL Trichlorofluoromethane 2500 ug/mL Vinyl chloride 2500 ug/mL 06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181..MV-569723_00019 MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL10/23/24 10/10/24.MV-MegaMainA_00116 P&T Methanol, Lot EG636-US 2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL 2-Hexanone 400 ug/mL 4-Methyl-2-pentanone (MIBK)400 ug/mL Acetone 400 ug/mL Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL 1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL 1,1,1-Trichloroethane 100 ug/mL 1,1,2,2-Tetrachloroethane 100 ug/mL 1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL 1,1,2-Trichloroethane 100 ug/mL 1,1-Dichloroethane 100 ug/mL 1,1-Dichloroethene 100 ug/mL 1,1-Dichloropropene 100 ug/mL 1,2,3-Trichlorobenzene 100 ug/mL 1,2,3-Trichloropropane 100 ug/mL 1,2,4-Trichlorobenzene 100 ug/mL 1,2,4-Trimethylbenzene 100 ug/mL 1,2-Dibromo-3-Chloropropane 100 ug/mL 1,2-Dichlorobenzene 100 ug/mL 1,2-Dichloroethane 100 ug/mL 1,2-Dichloropropane 100 ug/mL 1,3,5-Trimethylbenzene 100 ug/mL 1,3-Dichlorobenzene 100 ug/mL 1,3-Dichloropropane 100 ug/mL 1,4-Dichlorobenzene 100 ug/mL 1,4-Dioxane 2000 ug/mL 2,2-Dichloropropane 100 ug/mL 2-Chlorotoluene 100 ug/mL 2-Methyl-2-propanol 1000 ug/mL 3-Chloro-1-propene 100 ug/mL 4-Chlorotoluene 100 ug/mL Page 26 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte 4-Isopropyltoluene 100 ug/mL Acrylonitrile 1000 ug/mL Benzene 100 ug/mL Bromobenzene 100 ug/mL Bromoform 100 ug/mL Carbon disulfide 100 ug/mL Carbon tetrachloride 100 ug/mL Chlorobenzene 100 ug/mL Chlorobromomethane 100 ug/mL Chlorodibromomethane 100 ug/mL Chloroform 100 ug/mL cis-1,2-Dichloroethene 100 ug/mL cis-1,3-Dichloropropene 100 ug/mL Cyclohexane 100 ug/mL Dibromomethane 100 ug/mL Dichlorobromomethane 100 ug/mL Ethyl ether 100 ug/mL Ethyl methacrylate 100 ug/mL Ethylbenzene 100 ug/mL Ethylene Dibromide 100 ug/mL Hexachlorobutadiene 100 ug/mL Hexane 100 ug/mL Iodomethane 100 ug/mL Isobutyl alcohol 2500 ug/mL Isopropylbenzene 100 ug/mL m-Xylene & p-Xylene 100 ug/mL Methyl acetate 200 ug/mL Methyl tert-butyl ether 100 ug/mL Methylcyclohexane 100 ug/mL Methylene Chloride 100 ug/mL n-Butylbenzene 100 ug/mL n-Heptane 100 ug/mL N-Propylbenzene 100 ug/mL Naphthalene 100 ug/mL o-Xylene 100 ug/mL sec-Butylbenzene 100 ug/mL Styrene 100 ug/mL tert-Butylbenzene 100 ug/mL Tetrachloroethene 100 ug/mL Tetrahydrofuran 200 ug/mL Toluene 100 ug/mL trans-1,2-Dichloroethene 100 ug/mL trans-1,3-Dichloropropene 100 ug/mL trans-1,4-Dichloro-2-butene 100 ug/mL Trichloroethene 100 ug/mL 1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL 2-Pentanone 320 ug/mL Page 27 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte sec-Butyl Alcohol 2400 ug/mL 09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476..MV-568720_00049 04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935..MV-569721_00016 2-Hexanone 12500 ug/mL 4-Methyl-2-pentanone (MIBK) 12500 ug/mL Acetone 12500 ug/mL 09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567..MV-569724_00038 03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630..MV-569727_00025 04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458..MV-571992_00017 1,1,1-Trichloroethane 2500 ug/mL 1,1,2,2-Tetrachloroethane 2500 ug/mL 1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL 1,1,2-Trichloroethane 2500 ug/mL 1,1-Dichloroethane 2500 ug/mL 1,1-Dichloroethene 2500 ug/mL 1,1-Dichloropropene 2500 ug/mL 1,2,3-Trichlorobenzene 2500 ug/mL 1,2,3-Trichloropropane 2500 ug/mL 1,2,4-Trichlorobenzene 2500 ug/mL 1,2,4-Trimethylbenzene 2500 ug/mL 1,2-Dibromo-3-Chloropropane 2500 ug/mL 1,2-Dichlorobenzene 2500 ug/mL 1,2-Dichloroethane 2500 ug/mL 1,2-Dichloropropane 2500 ug/mL 1,3,5-Trimethylbenzene 2500 ug/mL 1,3-Dichlorobenzene 2500 ug/mL 1,3-Dichloropropane 2500 ug/mL 1,4-Dichlorobenzene 2500 ug/mL 1,4-Dioxane 50000 ug/mL 2,2-Dichloropropane 2500 ug/mL 2-Chlorotoluene 2500 ug/mL 2-Methyl-2-propanol 25000 ug/mL 3-Chloro-1-propene 2500 ug/mL 4-Chlorotoluene 2500 ug/mL 4-Isopropyltoluene 2500 ug/mL Acrylonitrile 25000 ug/mL Benzene 2500 ug/mL Bromobenzene 2500 ug/mL Bromoform 2500 ug/mL Carbon disulfide 2500 ug/mL Carbon tetrachloride 2500 ug/mL Chlorobenzene 2500 ug/mL Chlorobromomethane 2500 ug/mL Chlorodibromomethane 2500 ug/mL Chloroform 2500 ug/mL cis-1,2-Dichloroethene 2500 ug/mL cis-1,3-Dichloropropene 2500 ug/mL Page 28 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte Cyclohexane 2500 ug/mL Dibromomethane 2500 ug/mL Dichlorobromomethane 2500 ug/mL Ethyl ether 2500 ug/mL Ethyl methacrylate 2500 ug/mL Ethylbenzene 2500 ug/mL Ethylene Dibromide 2500 ug/mL Hexachlorobutadiene 2500 ug/mL Hexane 2500 ug/mL Iodomethane 2500 ug/mL Isobutyl alcohol 62500 ug/mL Isopropylbenzene 2500 ug/mL m-Xylene & p-Xylene 2500 ug/mL Methyl acetate 5000 ug/mL Methyl tert-butyl ether 2500 ug/mL Methylcyclohexane 2500 ug/mL Methylene Chloride 2500 ug/mL n-Butylbenzene 2500 ug/mL n-Heptane 2500 ug/mL N-Propylbenzene 2500 ug/mL Naphthalene 2500 ug/mL o-Xylene 2500 ug/mL sec-Butylbenzene 2500 ug/mL Styrene 2500 ug/mL tert-Butylbenzene 2500 ug/mL Tetrachloroethene 2500 ug/mL Tetrahydrofuran 5000 ug/mL Toluene 2500 ug/mL trans-1,2-Dichloroethene 2500 ug/mL trans-1,3-Dichloropropene 2500 ug/mL trans-1,4-Dichloro-2-butene 2500 ug/mL Trichloroethene 2500 ug/mL 08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538..MV-CUS17739_00017 2-Pentanone 4000 ug/mL sec-Butyl Alcohol 30000 ug/mL 1,2-Dichloroethene, Totalmv-Cent BFB_00007 1,3-Dichloropropene, Total Tentatively Identified Compound Total BTEX Trihalomethanes, Total Xylenes, Total mv-IS/SS Tune_00001 10 mL BFB 50 ug/mL 11/30/23 (Purchased Reagent)BFB 250 ug/mLRestek, Lot A0143593.mv-IS/SS Tune_00001 mv-30241_00014 1,4-Dichlorobenzene-d4 50 ug/mL5 mL 0.1 mL05/31/28 07/31/24mv-Cent IS_00009 P&T Methanol, Lot EG-636-US Chlorobenzene-d5 50 ug/mL Page 29 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte Fluorobenzene 50 ug/mL 05/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0198297.mv-30241_00014 Chlorobenzene-d5 2500 ug/mL Fluorobenzene 2500 ug/mL MV-569722.sec_00019 Bromomethane 250 ug/mL12.5 mL 1250 uL10/17/24 09/17/24MV-Gas A_00198 P&T Methanol, Lot 198123 Chloroethane 250 ug/mL Chloromethane 250 ug/mL Dichlorodifluoromethane 250 ug/mL Dichlorofluoromethane 250 ug/mL Trichlorofluoromethane 250 ug/mL Vinyl chloride 250 ug/mL MV-569723_00018 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL 04/30/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0210106.MV-569722.sec_00019 Chloroethane 2500 ug/mL Chloromethane 2500 ug/mL Dichlorodifluoromethane 2500 ug/mL Dichlorofluoromethane 2500 ug/mL Trichlorofluoromethane 2500 ug/mL Vinyl chloride 2500 ug/mL 01/31/26 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0193735.MV-569723_00018 mv-30241_00014 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL03/01/25 08/15/24mv-IS_SS_00086 P&T Methanol, Lot EG636-US Chlorobenzene-d5 50 ug/mL Fluorobenzene 50 ug/mL 1,2-Dichloroethane-d4 (Surr)50 ug/mLMV-567650_00030 1000 uL 4-Bromofluorobenzene (Surr)50 ug/mL Dibromofluoromethane (Surr)50 ug/mL Toluene-d8 (Surr)50 ug/mL 05/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0198297.mv-30241_00014 Chlorobenzene-d5 2500 ug/mL Fluorobenzene 2500 ug/mL 05/31/26 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr) 2500 ug/mLRestek, Lot A0172587.MV-567650_00030 4-Bromofluorobenzene (Surr) 2500 ug/mL Dibromofluoromethane (Surr) 2500 ug/mL Toluene-d8 (Surr)2500 ug/mL MV-571992.sec_00010 Benzene 100 ug/mL25 mL 1000 uL11/04/24 10/04/24MV-MegaMain B_00110 P&T Methanol, Lot EG-636-US Ethylbenzene 100 ug/mL Naphthalene 100 ug/mL Toluene 100 ug/mL Xylenes, Total 200 ug/mL 08/31/25 (Purchased Reagent)Benzene 2500 ug/mLRESTEK, Lot A0195252.MV-571992.sec_00010 Ethylbenzene 2500 ug/mL Naphthalene 2500 ug/mL Toluene 2500 ug/mL Xylenes, Total 5000 ug/mL Page 30 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL10/23/24 09/23/24MV-MegaMainA_00115 P&T Methanol, Lot EG636-US 2-Butanone (MEK)400 ug/mLMV-569721_00015 800 uL 2-Hexanone 400 ug/mL 4-Methyl-2-pentanone (MIBK)400 ug/mL Acetone 400 ug/mL Vinyl acetate 200 ug/mLMV-569724_00037 1000 uL Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL 1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL 1,1,1-Trichloroethane 100 ug/mL 1,1,2,2-Tetrachloroethane 100 ug/mL 1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL 1,1,2-Trichloroethane 100 ug/mL 1,1-Dichloroethane 100 ug/mL 1,1-Dichloroethene 100 ug/mL 1,1-Dichloropropene 100 ug/mL 1,2,3-Trichlorobenzene 100 ug/mL 1,2,3-Trichloropropane 100 ug/mL 1,2,4-Trichlorobenzene 100 ug/mL 1,2,4-Trimethylbenzene 100 ug/mL 1,2-Dibromo-3-Chloropropane 100 ug/mL 1,2-Dichlorobenzene 100 ug/mL 1,2-Dichloroethane 100 ug/mL 1,2-Dichloropropane 100 ug/mL 1,3,5-Trimethylbenzene 100 ug/mL 1,3-Dichlorobenzene 100 ug/mL 1,3-Dichloropropane 100 ug/mL 1,4-Dichlorobenzene 100 ug/mL 1,4-Dioxane 2000 ug/mL 2,2-Dichloropropane 100 ug/mL 2-Chlorotoluene 100 ug/mL 2-Methyl-2-propanol 1000 ug/mL 3-Chloro-1-propene 100 ug/mL 4-Chlorotoluene 100 ug/mL 4-Isopropyltoluene 100 ug/mL Acrylonitrile 1000 ug/mL Benzene 100 ug/mL Bromobenzene 100 ug/mL Bromoform 100 ug/mL Carbon disulfide 100 ug/mL Carbon tetrachloride 100 ug/mL Chlorobenzene 100 ug/mL Chlorobromomethane 100 ug/mL Chlorodibromomethane 100 ug/mL Chloroform 100 ug/mL cis-1,2-Dichloroethene 100 ug/mL Page 31 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte cis-1,3-Dichloropropene 100 ug/mL Cyclohexane 100 ug/mL Dibromomethane 100 ug/mL Dichlorobromomethane 100 ug/mL Ethyl ether 100 ug/mL Ethyl methacrylate 100 ug/mL Ethylbenzene 100 ug/mL Ethylene Dibromide 100 ug/mL Hexachlorobutadiene 100 ug/mL Hexane 100 ug/mL Iodomethane 100 ug/mL Isobutyl alcohol 2500 ug/mL Isopropylbenzene 100 ug/mL m-Xylene & p-Xylene 100 ug/mL Methyl acetate 200 ug/mL Methyl tert-butyl ether 100 ug/mL Methylcyclohexane 100 ug/mL Methylene Chloride 100 ug/mL n-Butylbenzene 100 ug/mL n-Heptane 100 ug/mL N-Propylbenzene 100 ug/mL Naphthalene 100 ug/mL o-Xylene 100 ug/mL sec-Butylbenzene 100 ug/mL Styrene 100 ug/mL tert-Butylbenzene 100 ug/mL Tetrachloroethene 100 ug/mL Tetrahydrofuran 200 ug/mL Toluene 100 ug/mL trans-1,2-Dichloroethene 100 ug/mL trans-1,3-Dichloropropene 100 ug/mL trans-1,4-Dichloro-2-butene 100 ug/mL Trichloroethene 100 ug/mL 1-Chlorohexane 80 ug/mLMV-CUS17739.s_00012 2000 uL 2-Pentanone 320 ug/mL sec-Butyl Alcohol 2400 ug/mL 09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476.MV-568720_00049 01/31/26 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0193494.MV-569721_00015 2-Hexanone 12500 ug/mL 4-Methyl-2-pentanone (MIBK) 12500 ug/mL Acetone 12500 ug/mL 01/31/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0200199.MV-569724_00037 03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630.MV-569727_00025 04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458.MV-571992_00017 1,1,1-Trichloroethane 2500 ug/mL 1,1,2,2-Tetrachloroethane 2500 ug/mL 1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL Page 32 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte 1,1,2-Trichloroethane 2500 ug/mL 1,1-Dichloroethane 2500 ug/mL 1,1-Dichloroethene 2500 ug/mL 1,1-Dichloropropene 2500 ug/mL 1,2,3-Trichlorobenzene 2500 ug/mL 1,2,3-Trichloropropane 2500 ug/mL 1,2,4-Trichlorobenzene 2500 ug/mL 1,2,4-Trimethylbenzene 2500 ug/mL 1,2-Dibromo-3-Chloropropane 2500 ug/mL 1,2-Dichlorobenzene 2500 ug/mL 1,2-Dichloroethane 2500 ug/mL 1,2-Dichloropropane 2500 ug/mL 1,3,5-Trimethylbenzene 2500 ug/mL 1,3-Dichlorobenzene 2500 ug/mL 1,3-Dichloropropane 2500 ug/mL 1,4-Dichlorobenzene 2500 ug/mL 1,4-Dioxane 50000 ug/mL 2,2-Dichloropropane 2500 ug/mL 2-Chlorotoluene 2500 ug/mL 2-Methyl-2-propanol 25000 ug/mL 3-Chloro-1-propene 2500 ug/mL 4-Chlorotoluene 2500 ug/mL 4-Isopropyltoluene 2500 ug/mL Acrylonitrile 25000 ug/mL Benzene 2500 ug/mL Bromobenzene 2500 ug/mL Bromoform 2500 ug/mL Carbon disulfide 2500 ug/mL Carbon tetrachloride 2500 ug/mL Chlorobenzene 2500 ug/mL Chlorobromomethane 2500 ug/mL Chlorodibromomethane 2500 ug/mL Chloroform 2500 ug/mL cis-1,2-Dichloroethene 2500 ug/mL cis-1,3-Dichloropropene 2500 ug/mL Cyclohexane 2500 ug/mL Dibromomethane 2500 ug/mL Dichlorobromomethane 2500 ug/mL Ethyl ether 2500 ug/mL Ethyl methacrylate 2500 ug/mL Ethylbenzene 2500 ug/mL Ethylene Dibromide 2500 ug/mL Hexachlorobutadiene 2500 ug/mL Hexane 2500 ug/mL Iodomethane 2500 ug/mL Isobutyl alcohol 62500 ug/mL Isopropylbenzene 2500 ug/mL Page 33 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte m-Xylene & p-Xylene 2500 ug/mL Methyl acetate 5000 ug/mL Methyl tert-butyl ether 2500 ug/mL Methylcyclohexane 2500 ug/mL Methylene Chloride 2500 ug/mL n-Butylbenzene 2500 ug/mL n-Heptane 2500 ug/mL N-Propylbenzene 2500 ug/mL Naphthalene 2500 ug/mL o-Xylene 2500 ug/mL sec-Butylbenzene 2500 ug/mL Styrene 2500 ug/mL tert-Butylbenzene 2500 ug/mL Tetrachloroethene 2500 ug/mL Tetrahydrofuran 5000 ug/mL Toluene 2500 ug/mL trans-1,2-Dichloroethene 2500 ug/mL trans-1,3-Dichloropropene 2500 ug/mL trans-1,4-Dichloro-2-butene 2500 ug/mL Trichloroethene 2500 ug/mL 11/30/25 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 0006765276.s.MV-CUS17739.s_00012 2-Pentanone 4000 ug/mL sec-Butyl Alcohol 30000 ug/mL 10/23/24 09/23/24 25 mL MV-571992_00017 1000 uL Xylenes, Total 200 ug/mLMV-MegaMainA_00115 P&T Methanol, Lot EG636-US 04/30/26 (Purchased Reagent)Xylenes, Total 5000 ug/mLRESTEK, Lot A0203458.MV-571992_00017 mv-570808_00017 1,2,3-Trimethylbenzene 50 ug/mL20 mL 400 uL11/29/24 09/30/24MV-Supp A_00097 P&T Methanol, Lot EG636-US 1,3,5-Trichlorobenzene 50 ug/mL 2-Chloro-1,3-butadiene 50 ug/mL 2-Nitropropane 100 ug/mL Isopropyl alcohol 500 ug/mL Methacrylonitrile 500 ug/mL n-Butanol 1250 ug/mL Ethyl acetate 100 ug/mLmv-570809_00014 400 uL Methyl methacrylate 100 ug/mL Acetonitrile 500 ug/mLmv-571993_00010 400 uL Isopropyl ether 50 ug/mL Propionitrile 500 ug/mL Tert-amyl methyl ether 50 ug/mL Tert-butyl ethyl ether 50 ug/mL Ethanol 3000 ug/mLmv-571994_00010 600 uL Z-020209-01_00004 2000 uL cis-1,4-Dichloro-2-butene 100 ug/mL 04/30/25 (Purchased Reagent)1,2,3-Trimethylbenzene 2500 ug/mLRestek, Lot A0203604.mv-570808_00017 1,3,5-Trichlorobenzene 2500 ug/mL 2-Chloro-1,3-butadiene 2500 ug/mL 2-Nitropropane 5000 ug/mL Page 34 of 426 REAGENT TRACEABILITY SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Reagent ID Exp Date Date Prep Dilutant Used Reagent Final Volume Parent Reagent Reagent ID Volume Added ConcentrationAnalyte Isopropyl alcohol 25000 ug/mL Methacrylonitrile 25000 ug/mL n-Butanol 62500 ug/mL 01/31/25 (Purchased Reagent)Ethyl acetate 5000 ug/mLRestek, Lot A0200274.mv-570809_00014 Methyl methacrylate 5000 ug/mL 02/28/25 (Purchased Reagent)Acetonitrile 25000 ug/mLRESTEK, Lot A0194786.mv-571993_00010 Isopropyl ether 2500 ug/mL Propionitrile 25000 ug/mL Tert-amyl methyl ether 2500 ug/mL Tert-butyl ethyl ether 2500 ug/mL 03/31/26 (Purchased Reagent)Ethanol 100000 ug/mLRESTEK, Lot A0195429.mv-571994_00010 08/15/25 (Purchased Reagent)cis-1,4-Dichloro-2-butene 1000 ug/mLCPI, Lot 507909.Z-020209-01_00004 Page 35 of 426 Reagent mv-30241_00014 Page 36 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :30241 Lot No.:A0198297 8260A Internal Standard MixDescription : 8260A Internal Standard Mix 2,500 µg/mL, P&T Methanol, 1mL/ampul Container Size : Expiration Date :Storage:0°C or colder 2 mL > 1 mLPkg Amt: May 31, 2028 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 2,504.7Fluorobenzene462-06-6 +/- 140.7155BCBZ5549 99% 2 µg/mL 2,513.3Chlorobenzene-d5 3114-55-4 +/- 141.2024PR-29571 99% 3 µg/mL 2,515.31,4-Dichlorobenzene-d4 3855-82-1 +/- 141.3148PR-30447 Solvent:P&T Methanol 99% 67-56-1CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 1 of 3 Page 37 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID 1128342314Balance Serial # 24-May-2023Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 22-May-2023Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 1µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 38 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 39 of 426 Reagent MV-567650_00030 Page 40 of 426 Page 41 of 426 Page 42 of 426 Reagent MV-568720_00049 Page 43 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :568720 Lot No.:A0209476 8260 List 1/Std #5 Acrolein HighDescription : 8260 List 1/Std #5 Acrolein High 19,750µg/mL, Water, 1mL/ampul Container Size : Expiration Date :Storage:-20°C or colder 2 mL > 1 mLPkg Amt: Handling:This product is photosensitive. September 30, 2025 Ship:On Ice Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 19,917.5Acrolein107-02-8 +/- 585.1357RP240118CTH Solvent:Water 99% 7732-18-5CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 1 of 3 Page 44 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID 1128360905Balance Serial # 01-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 26-Mar-2024Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 1µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 45 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 46 of 426 Reagent MV-569721_00015 Page 47 of 426 Page 48 of 426 Page 49 of 426 Reagent MV-569721_00016 Page 50 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :569721 Lot No.:A0210935 8260 List 1/ Std #2 Ketones (2015)Description : 8260 List 1/ Std #2 Ketones (2015) 12,500µg/mL, P&T Methanol/Water (90:10), 1mL/ampul Container Size : Expiration Date :Storage:0°C or colder 2 mL > 1 mLPkg Amt: April 30, 2027 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 12,591.3Acetone67-64-1 +/- 435.1857SHBQ8504 99% 2 µg/mL 12,561.02-Butanone (MEK)78-93-3 +/- 434.1373SHBQ4704 99% 3 µg/mL 12,580.04-Methyl-2-pentanone (MIBK)108-10-1 +/- 434.7940SHBP9200 99% 4 µg/mL 12,580.72-Hexanone 591-78-6 +/- 434.8170MKCV1997 Solvent:P&T Methanol/Water (90:10) 99% 67-56-1/7732-18-5CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 1 of 3 Page 51 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID B707717271Balance Serial # 02-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 30-Apr-2024Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 0.2µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 52 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 53 of 426 Reagent MV-569722.sec_00019 Page 54 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :569722.SEC Lot No.:A0210106 8260 List 1 / Std #3 Gases (2015)Description : 8260 List 1 / Std #3 Gases (2015) 2,500µg/mL, P&T Methanol, 1mL/ampul Container Size : Expiration Date :Storage:0°C or colder 2 mL > 1 mLPkg Amt: April 30, 2027 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 2,508.8Dichlorodifluoromethane (CFC-12)75-71-8.SEC +/- 141.969628888 99% 2 µg/mL 2,503.3Chloromethane (methyl chloride)74-87-3.SEC +/- 142.014400022694 99% 3 µg/mL 2,508.1Vinyl chloride 75-01-4 *+/- 141.591000015559 99% 4 µg/mL 2,509.71,3-Butadiene 106-99-0.SEC +/- 141.741728539 99% 5 µg/mL 2,506.6Bromomethane (methyl bromide)74-83-9 *+/- 141.420900017022 99% 6 µg/mL 2,510.1Chloroethane (ethyl chloride)75-00-3.SEC +/- 142.264200021903 90% 7 µg/mL 2,523.6Dichlorofluoromethane (CFC-21)75-43-4 *+/- 141.779214485600 99% 8 µg/mL 2,512.0Trichlorofluoromethane (CFC-11)75-69-4.SEC +/- 142.197600010739 Solvent:P&T Methanol 99% 67-56-1CAS # Purity * Restek is unable to identify a reliable and/or acceptable second source for this material - the same batch of neat material may have been used to produce both the primary and secondary standard. The primary and secondary standards were prepared using different equipment and personnel. * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 1 of 3 Page 55 of 426 Raw material may contain trace amounts of tert-Butanol. Tech Tips: Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 60m x 0.25mm x 1.4µm Rtx-502.2 (cat.#10916) Column: helium-constant pressure 30 psi 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C MSD 1127510105Balance Serial # 17-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 10-Apr-2024Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 25.0 ml/min. Inj. Vol 1µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 56 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 57 of 426 Reagent MV-569723_00018 Page 58 of 426 Page 59 of 426 Page 60 of 426 Reagent MV-569723_00019 Page 61 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :569723.SEC Lot No.:A0210862 8260 List 1 / Std #4 2-CEVE (2015)Description : 8260 List 1 / Std #4 2-CEVE (2015) 2,500µg/mL, P&T Methanol, 1mL/ampul Container Size : Expiration Date :Storage:0°C or colder 2 mL > 1 mLPkg Amt: April 30, 2027 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 2,512.02-Chloroethyl vinyl ether 110-75-8.SEC +/- 31.2623AMBTF Solvent:P&T Methanol 99% 67-56-1CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. Degradation of tetrachloroethylene to pentachloroethane may occur if solutions containing 2-chloroethyl vinyl ether are combined with solutions that contain tetrachloroethylene. Tech Tips: 01-Nov-2022 rev.Page 1 of 3 Page 62 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID 1128342314Balance Serial # 02-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 29-Apr-2024Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 0.2µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 63 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 64 of 426 Reagent MV-569724_00037 Page 65 of 426 Page 66 of 426 Page 67 of 426 Reagent MV-569724_00038 Page 68 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :569724 Lot No.:A0209567 8260 List 1 / Std #6 Vinyl Acetate (2015)Description : 8260 List 1 / Std #6 Vinyl Acetate (2015) 5,000µg/mL, P&T Methanol, 1mL/ampul Container Size : Expiration Date :Storage:-20°C or colder 2 mL > 1 mLPkg Amt: Handling:This product is photosensitive. September 30, 2025 Ship:On Ice Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 98% 1 µg/mL 5,034.8Vinyl acetate 108-05-4 +/- 173.9777RP231030CTH Solvent:P&T Methanol 99% 67-56-1CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. Vinyl acetate is a volatile organic ester included in the target lists of several US EPA and other methods. Under acidic conditions, esters react with alcohols to form new esters (transesterification). Methanol-based mixes containing halogenated compounds are slightly acidic, so it is important to minimize exposure of vinyl acetate to mixes of halogenated compounds in methanol. For this reason, we offer vinyl acetate in individual solution, and suggest that it be introduced into the working level calibration solution immediately before use. This will minimize problems and ensure more consistent results. Tech Tips: 01-Nov-2022 rev.Page 1 of 3 Page 69 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID B251644995Balance Serial # 29-Mar-2024Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 27-Mar-2024Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 0.2µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 70 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 71 of 426 Reagent MV-569727_00025 Page 72 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :569727 Lot No.:A0209630 8260 List 2/ Std #3 Cyclohexanone (2015)Description : 8260 List 2/ Std #3 Cyclohexanone (2015) 25,000µg/mL, Water, 1mL/ampul Container Size : Expiration Date :Storage:10°C or colder 2 mL > 1 mLPkg Amt: March 31, 2027 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 25,225.0Cyclohexanone108-94-1 +/- 871.8345MKCS0133 Solvent:Water 99% 7732-18-5CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 1 of 3 Page 73 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID 1128360905Balance Serial # 02-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 29-Mar-2024Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 1µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 74 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 75 of 426 Reagent mv-570808_00017 Page 76 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :570808 Lot No.:A0203604 8260 List 2 / Std #6Description : 8260 List 2 / Std #6 2,500-62,500µg/mL, P&T Methanol, 1mL/ampul Container Size : Expiration Date :Storage:0°C or colder 2 mL > 1 mLPkg Amt: April 30, 2025 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 25,118.52-Propanol (isopropanol)67-63-0 +/- 410.7356SHBQ4760 99% 2 µg/mL 2,517.5Chloroprene (2-chloro-1,3-butadiene)126-99-8 +/- 41.1780230928JLM 99% 3 µg/mL 25,073.0Methacrylonitrile126-98-7 +/- 409.99161012014 99% 4 µg/mL 2,521.52,2,4-Trimethylpentane ( isooctane )540-84-1 +/- 41.2434SHBP5702 99% 5 µg/mL 62,717.51-Butanol 71-36-3 +/- 1,025.5446101601K21K 97% 6 µg/mL 5,037.22-Nitropropane 79-46-9 +/- 82.3680BCCB9352 99% 7 µg/mL 2,509.51-Chlorohexane 544-10-5 +/- 41.0471BCBS3368V 98% 8 µg/mL 2,524.01,2,3-Trimethylbenzene 526-73-8 +/- 41.28418776.10-36 99% 9 µg/mL 2,511.5Benzyl chloride 100-44-7 +/- 41.0798SHBH2102V 99% 10 µg/mL 2,515.01,3,5-Trichlorobenzene 108-70-3 +/- 41.137111319AS Solvent:P&T Methanol 99% 67-56-1CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 1 of 3 Page 77 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 105m x 0.53mm x 3.0µm Rtx-502.2 (cat.#10910) Column: hydrogen-constant pressure 11.0 psi. 40°C (hold 2 min.) to 240°C @ 8°C/min. (hold 5 min.) 200°C 250°C FID B251644995Balance Serial # 27-Oct-2023Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 25-Oct-2023Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 40 ml/min Inj. Vol 1µl Split Vent: 01-Nov-2022 rev.Page 2 of 3 Page 78 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 3 of 3 Page 79 of 426 Reagent mv-570809_00014 Page 80 of 426 Page 81 of 426 Page 82 of 426 Reagent MV-571992.sec_00010 Page 83 of 426 Page 84 of 426 Page 85 of 426 Page 86 of 426 Page 87 of 426 Reagent MV-571992_00017 Page 88 of 426 110 Benner Circle Bellefonte, PA 16823-8812 Tel: 1-814-353-1300 Fax: 1-814-353-1309 www.restek.com FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. CERTIFIED REFERENCE MATERIAL chromatographic plus Certificate of Analysis Catalog No. :571992 Lot No.:A0203458 8260 List 1 / Std #1 MegaMix (2017)Description : 8260 List 1 / Std #1 MegaMix (2017) 1,250-62,500µg/mL, P&T Methanol, 1mL/ampul Container Size : Expiration Date :Storage:0°C or colder 2 mL > 1 mLPkg Amt: April 30, 2026 Ship:Ambient Elution Order Compound Grav. Conc. (weight/volume) Expanded Uncertainty * (95% C.L.; K=2) C E R T I F I E D V A L U E S CAS #Lot #Purity 99% 1 µg/mL 2,515.0Diethyl ether (ethyl ether)60-29-7 +/- 86.9068SHBQ1495 99% 2 µg/mL 2,518.81,1,2-Trichlorotrifluoroethane (CFC-113)76-13-1 +/- 87.036400016133 99% 3 µg/mL 2,516.31,1-dichloroethene 75-35-4 +/- 86.9500SHBG8609V 99% 4 µg/mL 25,095.0tert-Butanol (TBA)75-65-0 +/- 867.1659SHBQ8002 99% 5 µg/mL 5,016.4Methyl acetate 79-20-9 +/- 173.3427SHBP3100 99% 6 µg/mL 2,517.4Iodomethane (methyl iodide)74-88-4 +/- 86.9888MKCN8012 99% 7 µg/mL 2,515.9Allyl chloride ( 3-chloropropene )107-05-1 +/- 86.9370RD230914ECS 99% 8 µg/mL 2,513.8Methylene chloride (dichloromethane)75-09-2 +/- 86.8636SHBQ6376 99% 9 µg/mL 2,512.9Carbon disulfide 75-15-0 +/- 86.8333Q30J743 99% 10 µg/mL 25,031.9Acrylonitrile107-13-1 +/- 864.9846102466R02E 99% 11 µg/mL 2,513.8Methyl-tert-butyl ether ( MTBE )1634-04-4 +/- 86.8636SHBP0179 99% 12 µg/mL 2,514.0cis-1,2-Dichloroethene 156-59-2 +/- 86.8722MKCP7830 99% 13 µg/mL 2,520.3n-Hexane (C6)110-54-3 +/- 87.0882STBG6381 99% 14 µg/mL 2,514.01,1-Dichloroethane 75-34-3 +/- 86.8722852900 99% 15 µg/mL 2,521.32,2-Dichloropropane 594-20-7 +/- 87.1227RD230426 99% 16 µg/mL 2,514.9trans-1,2-Dichloroethene 156-60-5 +/- 86.9025MKCP9516 01-Nov-2022 rev.Page 1 of 5 Page 89 of 426 99% 17 µg/mL 62,561.0Isobutanol (2-Methyl-1-propanol)78-83-1 +/- 2,161.8157SHBP7066 99% 18 µg/mL 2,513.6chloroform67-66-3 +/- 86.8593SHBN8469 99% 19 µg/mL 2,513.5Bromochloromethane74-97-5 +/- 86.8549230810JLM 99% 20 µg/mL 5,020.9Tetrahydrofuran109-99-9 +/- 173.4982SHBQ8516 99% 21 µg/mL 2,513.51,1,1-trichloroethane 71-55-6 +/- 86.8549RD230728RSR 99% 22 µg/mL 2,513.5Cyclohexane110-82-7 +/- 86.8549MKCQ2001 99% 23 µg/mL 2,514.31,1-Dichloropropene 563-58-6 +/- 86.8809230825JLM 99% 24 µg/mL 2,513.0carbon tetrachloride 56-23-5 +/- 86.8377SHBP4875 99% 25 µg/mL 2,515.4n-Heptane (C7)142-82-5 +/- 86.9197044743T01D 99% 26 µg/mL 2,513.51,2-Dichloroethane 107-06-2 +/- 86.8549SHBQ0693 99% 27 µg/mL 2,513.4Benzene71-43-2 +/- 86.8506MKCS3357 99% 28 µg/mL 2,513.6Trichloroethene79-01-6 +/- 86.8593SHBN3720 99% 29 µg/mL 2,514.8Methylcyclohexane108-87-2 +/- 86.8981SHBN1699 99% 30 µg/mL 2,514.91,2-Dichloropropane 78-87-5 +/- 86.9025BCBR0882V 99% 31 µg/mL 50,131.41,4-Dioxane 123-91-1 +/- 1,732.3059SHBQ2407 99% 32 µg/mL 2,514.6Dibromomethane74-95-3 +/- 86.893810233302 99% 33 µg/mL 2,513.5cis-1,3-Dichloropropene 10061-01-5 +/- 86.8549RD230406RSR 99% 34 µg/mL 2,512.9Toluene108-88-3 +/- 86.8333MKCS9989 97% 35 µg/mL 2,508.3Ethyl methacrylate 97-63-2 +/- 86.6752MKCN6206 99% 36 µg/mL 2,512.9trans-1,3-Dichloropropene 10061-02-6 +/- 86.8333RD220816 99% 37 µg/mL 2,513.51,1,2-Trichloroethane 79-00-5 +/- 86.8549FGB01 99% 38 µg/mL 2,514.11,3-Dichloropropane 142-28-9 +/- 86.8765BCCH5357 99% 39 µg/mL 2,514.0Tetrachloroethene127-18-4 +/- 86.8722SHBQ0051 99% 40 µg/mL 2,512.9dibromochloromethane124-48-1 +/- 86.8333MKCQ4517 99% 41 µg/mL 2,515.01,2-Dibromoethane (EDB)106-93-4 +/- 86.9068BCCH7113 99% 42 µg/mL 2,515.0Chlorobenzene108-90-7 +/- 86.9068SHBN6640 99% 43 µg/mL 1,254.8m-Xylene 108-38-3 +/- 43.3584SHBN6673 99% 44 µg/mL 1,257.0p-Xylene 106-42-3 +/- 43.4361SHBP5191 99% 45 µg/mL 2,514.1Ethylbenzene100-41-4 +/- 86.8765094632L21G 99% 46 µg/mL 2,514.91,1,1,2-Tetrachloroethane 630-20-6 +/- 86.9025GC01 99% 47 µg/mL 2,514.0o-Xylene 95-47-6 +/- 86.872250069309 99% 48 µg/mL 2,514.0Styrene100-42-5 +/- 86.8722MKCQ3390 99% 49 µg/mL 2,514.1Isopropylbenzene (cumene)98-82-8 +/- 86.8765Z20D022 99% 50 µg/mL 2,515.3bromoform75-25-2 +/- 86.9154050494L04R 99% 51 µg/mL 2,512.5bromodichloromethane75-27-4 +/- 86.8204MKCF8470 99% 52 µg/mL 2,515.31,1,2,2-Tetrachloroethane 79-34-5 +/- 86.9154QQJ41 01-Nov-2022 rev.Page 2 of 5 Page 90 of 426 98% 53 µg/mL 2,513.51,2,3-Trichloropropane 96-18-4 +/- 86.8534Q91-34 94% 54 µg/mL 2,504.7trans-1,4-dichloro-2-butene 110-57-6 +/- 86.5525RD230720RSR 98% 55 µg/mL 2,511.4n-Propylbenzene 103-65-1 +/- 86.7814G08M 99% 56 µg/mL 2,514.8Bromobenzene108-86-1 +/- 86.8981MKCQ7174 99% 57 µg/mL 2,513.81,3,5-Trimethylbenzene 108-67-8 +/- 86.8636BCCF4166 99% 58 µg/mL 2,514.82-Chlorotoluene 95-49-8 +/- 86.8981235783M23T 99% 59 µg/mL 2,514.94-Chlorotoluene 106-43-4 +/- 86.9025BCCG9286 99% 60 µg/mL 2,514.0tert-Butylbenzene 98-06-6 +/- 86.8722STBJ1937 99% 61 µg/mL 2,515.91,2,4-Trimethylbenzene 95-63-6 +/- 86.9370MKCS3775 99% 62 µg/mL 2,515.3sec-Butylbenzene 135-98-8 +/- 86.9154MKCP2266 99% 63 µg/mL 2,514.9p-Isopropyltoluene (p-Cymene)99-87-6 +/- 86.9025MKCR6143 99% 64 µg/mL 2,515.31,3-Dichlorobenzene 541-73-1 +/- 86.9154BCCD5315 99% 65 µg/mL 2,514.91,4-Dichlorobenzene 106-46-7 +/- 86.9025MKBS7929V 99% 66 µg/mL 2,514.5n-Butylbenzene 104-51-8 +/- 86.889509418JJ 99% 67 µg/mL 2,514.31,2-Dichlorobenzene 95-50-1 +/- 86.8809SHBN3835 97% 68 µg/mL 2,510.41,2-Dibromo-3-chloropropane 96-12-8 +/- 86.7464HBMVB 99% 69 µg/mL 2,514.91,2,4-Trichlorobenzene 120-82-1 +/- 86.9025SHBP5900 98% 70 µg/mL 2,510.0Hexachlorobutadiene87-68-3 +/- 86.7349RP230823RSR 99% 71 µg/mL 2,514.3Naphthalene91-20-3 +/- 86.8809STBL1057 99% 72 µg/mL 2,514.11,2,3-Trichlorobenzene 87-61-6 +/- 86.8765MKBX7627V Solvent:P&T Methanol 99% 67-56-1CAS # Purity * Expanded Uncertainty displayed in same units as Grav. Conc. 01-Nov-2022 rev.Page 3 of 5 Page 91 of 426 Carrier Gas: Temp. Program: Inj. Temp: Det. Type: Det. Temp: 60m x 0.25mm x 1.4µm Rtx-502.2 (cat.#10916) Column: helium-constant pressure 30 psi 40°C (hold 6 min.) to 240°C @ 6°C/min. (hold 10 min.) 200°C 250°C MSD B707717271Balance Serial # 08-Dec-2023Date Passed:Manufactured under Restek's ISO 9001:2015 Registered Quality System Certificate #FM 80397 22-Oct-2023Date Mixed: This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Quality Confirmation Test 20.0 ml/min. Inj. Vol 0.2µl Split Vent: 01-Nov-2022 rev.Page 4 of 5 Page 92 of 426 General Certified Reference Material Notes Expiration Notes: ·Expiration date valid for unopened ampul stored in compliance with the recommended conditions. ·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: ·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. ·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. ·Purity of isomeric compounds is reported as the sum of the isomers. ·Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: ·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. ·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: ·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: ·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability information, with the knowledge/understanding that open product stability is subject to the specific handling and environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861, which includes complete instructions. ·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. 01-Nov-2022 rev.Page 5 of 5 Page 93 of 426 Reagent mv-571993_00010 Page 94 of 426 Page 95 of 426 Page 96 of 426 Reagent mv-571994_00010 Page 97 of 426 Page 98 of 426 Reagent MV-CUS17739.s_00012 Page 99 of 426 Page 100 of 426 Page 101 of 426 Reagent MV-CUS17739_00017 Page 102 of 426 ISO 17034 Reference Material Certificate Product Information Sheet Custom Standard CUS-17739 Product Name: Product Number: 31-Aug-2026Expiration Date:Store Frozen (-25° to -10°C).Storage Conditions: 31-Jul-2024Lot Issue Date: 0006808538Lot Number: Traceability: The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3, ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088. Homogeneity: This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample size required. Intended Use: This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing calibration verification. Instructions for Use: Sample aliquots for analysis should be withdrawn at 20ºC to 25ºC immediately after opening the container and should be processed without delay for the certified values to be valid within the stated uncertainties. Safety: Expiration of Certification: The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is damaged, contaminated, or otherwise modified. Matrix:methanol (purge & trap grade) Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material. This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined gravimetrically, is listed above. Description: Component Name CAS#Analyte LotConcentrationUncertainty 1-chlorohexane 000544-10-5 RM204861004 ± 5 µg/mL 2-pentanone 000107-87-9 RM134784017 ± 20 µg/mL sec-butanol 000078-92-2 RM1350630013 ± 150 µg/mL 1 of 2Page: CSD-QA-015.2 ISO 17025 Cert No. AT-1937 250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/qualityPage 103 of 426 Maintenance of Certification: If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser. Sample lot approver: ISO 17034 RM was produced in accordance with the TUV/SUD registered ISO 9001:2015 Quality Management System. Cert# 951215321 2 of 2Page: www.agilent.com/quality/ CSD-QA-015.2 ISO 17025 Cert No. AR-1936 Cert No. AT-1937 250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/qualityPage 104 of 426 Reagent mv-IS/SS Tune_00001 Page 105 of 426 Page 106 of 426 Page 107 of 426 Page 108 of 426 Reagent Z-020209-01_00004 Page 109 of 426 Page 110 of 426 8260D Volatile Organic Compounds by GC/MS Page 111 of 426 FORM II GC/MS VOA SURROGATE RECOVERY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Matrix:Water Level:Low GC Column (1):DB-624 (60.25)ID:0.25(mm) #Lab Sample IDClient Sample ID # # #DBFM DCA TOL BFB 280-197896-1TB-100924 97 101 102 104 280-197896-2FB-100924 97 98 103 105 280-197896-3MW-05 96 101 102 103 280-197896-4MW-905 95 98 102 104 280-197896-5MW-03 93 99 104 101 280-197896-6MW-16 96 101 102 101 MB 280-671719/9 96 99 104 102 LCS 280-671719/4 99 98 104 103 LCSD 280-671719/6 100 99 103 102 280-197896-5 MSMW-03 MS 99 101 103 101 280-197896-5 MSDMW-03 MSD 98 99 102 101 QC LIMITS DBFM = Dibromofluoromethane (Surr)77-120 DCA = 1,2-Dichloroethane-d4 (Surr)70-127 TOL = Toluene-d8 (Surr)80-125 BFB = 4-Bromofluorobenzene (Surr)78-120 FORM II 8260D # Column to be used to flag recovery values Page 112 of 426 GC/MS VOA LAB CONTROL SAMPLE RECOVERY FORM III Job No.:Lab Name:280-197896-1Eurofins Denver SDG No.: Level:Matrix:Low Lab File ID:MS1_0595A.DWater Lab ID:LCS 280-671719/4 Client ID: REC % REC QC LIMITSCONCENTRATION (ug/L) SPIKE ADDED (ug/L) # LCS LCS COMPOUND Benzene 50.0 47.0 80-12094 Ethylbenzene 50.0 47.1 80-12094 Naphthalene 50.0 48.9 60-12498 Toluene 50.0 46.2 80-12092 Xylenes, Total 100 96.8 80-12097 FORM III 8260D # Column to be used to flag recovery and RPD values Page 113 of 426 GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY FORM III Job No.:Lab Name:280-197896-1Eurofins Denver SDG No.: Level:Matrix:Low Lab File ID:MS1_0597.DWater Lab ID:LCSD 280-671719/6 Client ID: COMPOUND SPIKE ADDED CONCENTRATION % REC % QC LIMITS REC (ug/L) (ug/L) # LCSD LCSD RPD RPD 50.0 47.8 20 80-120Benzene296 50.0 47.8 20 80-120Ethylbenzene196 50.0 50.3 21 60-124Naphthalene3101 50.0 47.4 20 80-120Toluene395 100 98.6 20 80-120Xylenes, Total 299 FORM III 8260D # Column to be used to flag recovery and RPD values Page 114 of 426 GC/MS VOA MATRIX SPIKE RECOVERY FORM III Job No.:Lab Name:280-197896-1Eurofins Denver SDG No.: Level:Matrix:Low Lab File ID:MS1_0612.DWater Lab ID:280-197896-5 MS Client ID:MW-03 MS LIMITS COMPOUND CONCENTRATION % REC QC REC SAMPLE CONCENTRATION SPIKE ADDED (ug/L) (ug/L) (ug/L) # MS MS 125 285 80-120Benzene103160 125 121 80-120Ethylbenzene970.72 U 125 130 60-124Naphthalene1045.0 U 125 123 80-120Toluene971.7 J 250 249 80-120Xylenes, Total 1000.57 U FORM III 8260D # Column to be used to flag recovery and RPD values Page 115 of 426 GC/MS VOA MATRIX SPIKE DUPLICATE RECOVERY FORM III Job No.:Lab Name:280-197896-1Eurofins Denver SDG No.: Level:Matrix:Low Lab File ID:MS1_0613.DWater Lab ID:280-197896-5 MSD Client ID:MW-03 MSD COMPOUND SPIKE ADDED CONCENTRATION % REC % QC LIMITS REC (ug/L) (ug/L) # MSD MSD RPD RPD 125 283 20 80-120Benzene1101 125 121 20 80-120Ethylbenzene097 125 129 21 60-124Naphthalene0103 125 122 20 80-120Toluene196 250 248 20 80-120Xylenes, Total 099 FORM III 8260D # Column to be used to flag recovery and RPD values Page 116 of 426 FORM IV GC/MS VOA METHOD BLANK SUMMARY Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Date Analyzed: GC Column:ID: Instrument ID:10/20/2024 23:26 DB-624 (60.25) NHeated Purge:(Y/N) VMS_MS1 MS1_0600.DLab File ID:Lab Sample ID:MB 280-671719/9 WaterMatrix: 0.25(mm) THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES: LAB SAMPLE ID LAB FILE ID DATE ANALYZEDCLIENT SAMPLE ID 10/20/2024 21:38MS1_0595A.DLCS 280-671719/4 10/20/2024 22:21MS1_0597.DLCSD 280-671719/6 10/20/2024 23:53MS1_0601.D280-197896-1TB-100924 10/21/2024 00:15MS1_0602.D280-197896-2FB-100924 10/21/2024 00:36MS1_0603.D280-197896-5MW-03 10/21/2024 02:02MS1_0607.D280-197896-3MW-05 10/21/2024 02:23MS1_0608.D280-197896-4MW-905 10/21/2024 02:45MS1_0609.D280-197896-6MW-16 10/21/2024 03:49MS1_0612.D280-197896-5 MSMW-03 MS 10/21/2024 04:10MS1_0613.D280-197896-5 MSDMW-03 MSD FORM IV 8260D Page 117 of 426 FORM V BROMOFLUOROBENZENE (BFB) Lab Name:Job No.: GC/MS VOA INSTRUMENT PERFORMANCE CHECK Eurofins Denver 280-197896-1 Lab File ID: Instrument ID: MS1_0292.D VMS_MS1 10/15/2024 22:07 BFB Injection Date: BFB Injection Time: M/E ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE Analysis Batch No.:671165 50 15.0 - 40.0 % of mass 95 15.6 75 30.0 - 60.0 % of mass 95 45.4 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 6.9 173 Less than 2.0 % of mass 174 0.0 (0.0) 1 174 Greater than 50% of mass 95 77.3 175 5.0 - 9.0 % of mass 174 6.0 (7.8) 1 176 95.0 - 101.0 % of mass 174 73.7 (95.3) 1 177 5.0 - 9.0 % of mass 176 5.1 (6.9) 2 1-Value is % mass 174 2-Value is % mass 176 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS: SDG No.: CLIENT SAMPLE ID LAB FILE IDLAB SAMPLE ID DATE ANALYZED TIME ANALYZED IC 280-671165/13 MS1_0297.D 10/16/2024 0:19 IC 280-671165/40 MS1_0298.D 10/16/2024 0:40 IC 280-671165/41 MS1_0299.D 10/16/2024 1:02 IC 280-671165/42 MS1_0300.D 10/16/2024 1:23 IC 280-671165/43 MS1_0301.D 10/16/2024 1:45 ICIS 280-671165/44 MS1_0302.D 10/16/2024 2:06 IC 280-671165/45 MS1_0303.D 10/16/2024 2:28 IC 280-671165/46 MS1_0304.D 10/16/2024 2:49 IC 280-671165/47 MS1_0305.D 10/16/2024 3:11 ICV 280-671165/48 MS1_0307.D 10/16/2024 3:54 IC 280-671165/49 MS1_0309.D 10/16/2024 4:36 IC 280-671165/50 MS1_0310.D 10/16/2024 4:58 IC 280-671165/51 MS1_0311.D 10/16/2024 5:19 IC 280-671165/52 MS1_0312.D 10/16/2024 5:41 IC 280-671165/53 MS1_0313.D 10/16/2024 6:02 IC 280-671165/54 MS1_0314.D 10/16/2024 6:23 IC 280-671165/55 MS1_0315.D 10/16/2024 6:45 IC 280-671165/56 MS1_0316.D 10/16/2024 7:06 ICV 280-671165/57 MS1_0318.D 10/16/2024 7:49 FORM V 8260D Page 118 of 426 FORM V BROMOFLUOROBENZENE (BFB) Lab Name:Job No.: GC/MS VOA INSTRUMENT PERFORMANCE CHECK Eurofins Denver 280-197896-1 Lab File ID: Instrument ID: MS1_0594A.D VMS_MS1 10/20/2024 21:17 BFB Injection Date: BFB Injection Time: M/E ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE Analysis Batch No.:671719 50 15.0 - 40.0 % of mass 95 15.4 75 30.0 - 60.0 % of mass 95 41.8 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 6.9 173 Less than 2.0 % of mass 174 0.0 (0.0) 1 174 Greater than 50% of mass 95 75.3 175 5.0 - 9.0 % of mass 174 5.7 (7.6) 1 176 95.0 - 101.0 % of mass 174 73.0 (96.9) 1 177 5.0 - 9.0 % of mass 176 4.9 (6.7) 2 1-Value is % mass 174 2-Value is % mass 176 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS: SDG No.: CLIENT SAMPLE ID LAB FILE IDLAB SAMPLE ID DATE ANALYZED TIME ANALYZED CCV 280-671719/2 MS1_0595.D 10/20/2024 21:38 LCS 280-671719/4 MS1_0595A.D 10/20/2024 21:38 LCSD 280-671719/6 MS1_0597.D 10/20/2024 22:21 MB 280-671719/9 MS1_0600.D 10/20/2024 23:26 TB-100924 280-197896-1 MS1_0601.D 10/20/2024 23:53 FB-100924 280-197896-2 MS1_0602.D 10/21/2024 0:15 MW-03 280-197896-5 MS1_0603.D 10/21/2024 0:36 MW-05 280-197896-3 MS1_0607.D 10/21/2024 2:02 MW-905 280-197896-4 MS1_0608.D 10/21/2024 2:23 MW-16 280-197896-6 MS1_0609.D 10/21/2024 2:45 MW-03 MS 280-197896-5 MS MS1_0612.D 10/21/2024 3:49 MW-03 MSD 280-197896-5 MSD MS1_0613.D 10/21/2024 4:10 FORM V 8260D Page 119 of 426 GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY Lab Name:Job No.: FORM VIII Eurofins Denver 280-197896-1 SDG No.: Sample No.:ICIS 280-671165/44 Date Analyzed:10/16/2024 02:06 Lab File ID (Standard):MS1_0302.D Instrument ID:VMS_MS1 GC Column:DB-624 (60.25)ID:0.25(mm) Heated Purge: (Y/N)N Calibration ID:98209 # RT #RT ## RT ## FB CBNZd5 DCBd4 AREA AREA AREA UPPER LIMIT LOWER LIMIT 5886832 1471708 345847 1383386 544055 2176220 6.03 8.77 11.06INITIAL CALIBRATION MID-POINT 6.20 5.86 8.94 8.60 11.23 10.89 2943416 691693 1088110 LAB SAMPLE ID CLIENT SAMPLE ID ICV 280-671165/48 2995118 685344 1101212 6.03 8.77 11.05 280-197896-2 FB-100924 3465777 772165 1158362 6.03 8.77 11.06 FB = Fluorobenzene CBNZd5 = Chlorobenzene-d5 DCBd4 = 1,4-Dichlorobenzene-d4 Area Limit = 50%-200% of internal standard area RT Limit = ± 0.167 minutes of internal standard RT # Column used to flag values outside QC limits FORM VIII 8260D Page 120 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:TB-100924 Lab Sample ID:280-197896-1 Matrix:MS1_0601.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 08:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/20/2024 23:53 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.14U71-43-2 Benzene 0.14 1.0 0.14U100-41-4 Ethylbenzene 0.14 3.0 0.99U91-20-3 Naphthalene 0.99 1.0 0.32U108-88-3 Toluene 0.32 1.0 0.11U1330-20-7 Xylenes, Total 0.11 %RECCAS NO.LIMITSQSURROGATE 101 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 104 78-120460-00-4 4-Bromofluorobenzene (Surr) 102 80-1252037-26-5 Toluene-d8 (Surr) 97 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 121 of 426 Report Date: 21-Oct-2024 01:20:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0601.D Lims ID: 280-197896-B-1 Client ID: TB-100924 Sample Type: Client Inject. Date: 20-Oct-2024 23:53:30 ALS Bottle#: 1 Worklist Smp#: 13 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-B-1 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:17:53 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3429328 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 777394 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1178730 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 747439 48.7 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.751 0.001 0 848754 50.5 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3380774 50.9 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 85 1139365 52.1 $ 8 BFB 95 9.899 9.900 -0.001 82 1139365 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 ND 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 92 3911 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.056 3.070 -0.014 42 1684 2.39 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.321 3.307 0.014 55 1195 0.4842 22 1,1-Dichloroethene 96 3.405 ND 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 ND 7 24 Iodomethane 142 3.559 3.559 0.000 96 5933 0.3565 25 Isopropyl alcohol 45 3.587 ND 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 ND 7 28 Methyl acetate 43 3.740 ND 29 3-Chloro-1-propene 41 3.754 ND 7 30 Methylene Chloride 84 3.880 ND 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 94 3279 0.4173 32 Acrylonitrile 53 4.103 ND 7 Page 122 of 426 Report Date: 21-Oct-2024 01:20:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0601.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 7 39 1,1-Dichloroethane 63 4.536 ND 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 5.011 0.000 92 6811 0.3763 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 5.249 0.000 92 15290 1.35 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 ND 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND 61 Benzene 78 5.779 ND 7 62 1,2-Dichloroethane 62 5.821 ND 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND 7 65 n-Butanol 56 6.226 6.226 0.000 49 1453 0.6913 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 ND 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 ND 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND U 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 ND 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 123 of 426 Report Date: 21-Oct-2024 01:20:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0601.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 7 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.224 ND 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 7 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 100 m-Xylene & p-Xylene 106 9.006 ND 101 o-Xylene 106 9.369 ND 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 9.830 0.000 84 3870 1.27 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 7 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 7 122 1,2,3-Trimethylbenzene 105 11.101 ND 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 ND 7 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 13.335 0.000 95 10432 0.1855 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 ND 7 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 124 of 426 Report Date: 21-Oct-2024 01:20:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0601.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0.000 ND 7 S 150 Xylenes, Total (URS) 1 0.000 ND 7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0.000 ND 7 T 155 Dichloroacetonitrile TIC 74 1.000 ND T 156 2,3-dichloro-1-propene TIC 75 1.000 ND T 157 Propene oxide TIC 58 5.334 ND T 159 4-Ethyltoluene TIC 1 10.249 ND T 164 Dicyclopentadiene TIC 1 10.947 ND T 160 Methyl cyclohexane TIC 1 0.000 ND T 163 2-Butoxyethanol TIC 1 0.000 ND T 162 Propene TIC 1 0.000 ND T 161 Cyclohexane TIC 1 0.000 ND T 158 1,3-Butadiene TIC 1 0.000 ND QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 125 of 426 Report Date: 21-Oct-2024 01:20:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0601.D Injection Date: 20-Oct-2024 23:53:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-B-1 Lab Sample ID: 280-197896-1 Worklist Smp#: 13 Client ID: TB-100924 Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 1 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 Y ( X10 0 0 0 0 ) MS1_0601[MS SCAN Chro]:Total E t h yle n e o xide( 2 . 2 6 0 ) E t h a n o l ( 3 . 0 5 6 ) Acr o l e i n ( 3 . 3 0 7 ) I o dom e t h a n e ( 3 . 5 5 9 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 ) 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 ) T e t r a h yd ro f u r a n ( 5 . 2 4 9 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 ) $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 2 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ $ T o l u e n e - d8 (Su r r )( 7 . 4 2 7 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 )+ Nap h t h a l e n e ( 1 3 . 3 3 5 ) Page 126 of 426 Report Date: 21-Oct-2024 01:20:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0601.D Lims ID: 280-197896-B-1 Client ID: TB-100924 Sample Type: Client Inject. Date: 20-Oct-2024 23:53:30 ALS Bottle#: 1 Worklist Smp#: 13 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-B-1 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:17:53 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 48.7 97.34 $5 1,2-Dichloroethane-d4 (Surr)50.0 50.5 101.09 $6 Toluene-d8 (Surr)50.0 50.9 101.81 $7 4-Bromofluorobenzene (Surr)50.0 52.1 104.11 Page 127 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:FB-100924 Lab Sample ID:280-197896-2 Matrix:MS1_0602.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 08:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 00:15 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.14U71-43-2 Benzene 0.14 1.0 0.14U100-41-4 Ethylbenzene 0.14 3.0 0.99U91-20-3 Naphthalene 0.99 1.0 0.32U108-88-3 Toluene 0.32 1.0 0.11U1330-20-7 Xylenes, Total 0.11 %RECCAS NO.LIMITSQSURROGATE 98 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 105 78-120460-00-4 4-Bromofluorobenzene (Surr) 103 80-1252037-26-5 Toluene-d8 (Surr) 97 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 128 of 426 Report Date: 21-Oct-2024 01:20:12 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0602.D Lims ID: 280-197896-B-2 Client ID: FB-100924 Sample Type: Client Inject. Date: 21-Oct-2024 00:15:30 ALS Bottle#: 2 Worklist Smp#: 14 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-B-2 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:18:36 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3465777 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 772165 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1158362 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 750179 48.3 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 834174 49.2 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3381253 51.3 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 86 1126336 52.4 $ 8 BFB 95 9.899 9.900 -0.001 83 1126336 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 ND 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 92 5130 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.070 ND U 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.307 ND U 22 1,1-Dichloroethene 96 3.405 ND 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 ND 7 24 Iodomethane 142 3.559 3.559 0.000 78 4958 0.2817 25 Isopropyl alcohol 45 3.573 3.587 -0.014 98 21033 4.75 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 ND 7 28 Methyl acetate 43 3.740 ND 29 3-Chloro-1-propene 41 3.754 ND 7 30 Methylene Chloride 84 3.880 ND 7 31 2-Methyl-2-propanol 59 3.964 ND U 32 Acrylonitrile 53 4.103 ND Page 129 of 426 Report Date: 21-Oct-2024 01:20:12 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0602.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 39 1,1-Dichloroethane 63 4.536 ND 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 5.011 0.000 87 3618 0.1978 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 7 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 ND 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 ND 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND 61 Benzene 78 5.779 ND 62 1,2-Dichloroethane 62 5.821 ND 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND U 65 n-Butanol 56 6.226 ND U 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 ND 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 6.631 0.000 83 6382 8.29 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 ND 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 130 of 426 Report Date: 21-Oct-2024 01:20:12 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0602.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.224 ND 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 100 m-Xylene & p-Xylene 106 9.006 ND 101 o-Xylene 106 9.369 ND 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 9.830 0.000 80 3821 1.26 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 122 1,2,3-Trimethylbenzene 105 11.101 ND 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 ND 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 ND 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 ND 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 131 of 426 Report Date: 21-Oct-2024 01:20:12 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0602.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0.000 ND 7 S 150 Xylenes, Total (URS) 1 0.000 ND 7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0.000 ND 7 T 155 Dichloroacetonitrile TIC 74 1.000 ND T 156 2,3-dichloro-1-propene TIC 75 1.000 ND T 157 Propene oxide TIC 58 5.334 ND T 159 4-Ethyltoluene TIC 1 10.249 ND T 164 Dicyclopentadiene TIC 1 10.947 ND T 160 Methyl cyclohexane TIC 1 0.000 ND T 163 2-Butoxyethanol TIC 1 0.000 ND T 162 Propene TIC 1 0.000 ND T 161 Cyclohexane TIC 1 0.000 ND T 158 1,3-Butadiene TIC 1 0.000 ND QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 132 of 426 Report Date: 21-Oct-2024 01:20:12 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0602.D Injection Date: 21-Oct-2024 00:15:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-B-2 Lab Sample ID: 280-197896-2 Worklist Smp#: 14 Client ID: FB-100924 Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 2 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) MS1_0602[MS SCAN Chro]:Total E t h yle n e o xide( 2 . 1 7 6 ) I o dom e t h a n e ( 3 . 5 7 3 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 ) $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) 1 ,4- D i o xan e ( 6 . 6 3 1 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) C ycl o h e xan o n e ( 9 . 8 1 6 ) $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 ) Page 133 of 426 Report Date: 21-Oct-2024 01:20:12 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0602.D Lims ID: 280-197896-B-2 Client ID: FB-100924 Sample Type: Client Inject. Date: 21-Oct-2024 00:15:30 ALS Bottle#: 2 Worklist Smp#: 14 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-B-2 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:18:36 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 48.3 96.67 $5 1,2-Dichloroethane-d4 (Surr)50.0 49.2 98.31 $6 Toluene-d8 (Surr)50.0 51.3 102.51 $7 4-Bromofluorobenzene (Surr)50.0 52.4 104.73 Page 134 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:MW-05 Lab Sample ID:280-197896-3 Matrix:MS1_0607.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 10:35 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 02:02 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.1471-43-2 Benzene 1.0 1.0 0.14U100-41-4 Ethylbenzene 0.14 3.0 0.99U91-20-3 Naphthalene 0.99 1.0 0.32U108-88-3 Toluene 0.32 1.0 0.11U1330-20-7 Xylenes, Total 0.11 %RECCAS NO.LIMITSQSURROGATE 101 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 103 78-120460-00-4 4-Bromofluorobenzene (Surr) 102 80-1252037-26-5 Toluene-d8 (Surr) 96 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 135 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Lims ID: 280-197896-A-3 Client ID: MW-05 Sample Type: Client Inject. Date: 21-Oct-2024 02:02:30 ALS Bottle#: 7 Worklist Smp#: 19 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-A-3 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 First Level Reviewer: AF7X Date:21-Oct-2024 07:11:48 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3411858 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 767635 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1164497 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 732234 47.9 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 840942 50.3 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3344425 51.0 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 87 1114127 51.5 $ 8 BFB 95 9.899 9.900 -0.001 84 1114127 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 ND 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 95 1358 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.070 ND 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.307 ND U 22 1,1-Dichloroethene 96 3.405 3.405 0.000 93 15074 1.26 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 ND 7 24 Iodomethane 142 3.559 ND 7 25 Isopropyl alcohol 45 3.587 ND U 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 ND 7 28 Methyl acetate 43 3.740 ND 29 3-Chloro-1-propene 41 3.754 ND 7 30 Methylene Chloride 84 3.880 ND 31 2-Methyl-2-propanol 59 3.964 ND U 32 Acrylonitrile 53 4.103 ND Page 136 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 7 39 1,1-Dichloroethane 63 4.536 4.536 0.000 96 32577 1.46 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 ND 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 7 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 5.249 0.000 85 57993 5.14 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 95 11772 0.7012 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND 61 Benzene 78 5.779 5.779 0.000 90 56702 1.01 62 1,2-Dichloroethane 62 5.821 ND 7 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND 7 65 n-Butanol 56 6.226 ND 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 ND 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 6.631 0.000 92 4497 5.93 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND U 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 ND 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 137 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.224 ND 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 100 m-Xylene & p-Xylene 106 9.006 ND 101 o-Xylene 106 9.369 ND 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 ND U 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 122 1,2,3-Trimethylbenzene 105 11.101 ND 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 ND 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 ND 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 ND 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 138 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0 1.01 S 150 Xylenes, Total (URS) 1 0.000 ND 7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0.000 ND 7 T 155 Dichloroacetonitrile TIC 74 1.000 ND T 156 2,3-dichloro-1-propene TIC 75 1.000 ND T 157 Propene oxide TIC 58 5.334 ND T 159 4-Ethyltoluene TIC 1 10.249 ND T 164 Dicyclopentadiene TIC 1 10.947 ND T 160 Methyl cyclohexane TIC 1 0.000 ND T 163 2-Butoxyethanol TIC 1 0.000 ND T 162 Propene TIC 1 0.000 ND T 161 Cyclohexane TIC 1 0.000 ND T 158 1,3-Butadiene TIC 1 0.000 ND QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 139 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Injection Date: 21-Oct-2024 02:02:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-A-3 Lab Sample ID: 280-197896-3 Worklist Smp#: 19 Client ID: MW-05 Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 7 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 Y ( X10 0 0 0 0 ) MS1_0607[MS SCAN Chro]:Total 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ 1 ,1- D i c h l o r o e t h a n e ( 4 . 5 3 6 )+ Tet r a h yd ro f u r a n ( 5 . 2 4 9 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ 1 ,4- D i o xan e ( 6 . 6 3 1 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 ) Page 140 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Lims ID: 280-197896-A-3 Client ID: MW-05 Sample Type: Client Inject. Date: 21-Oct-2024 02:02:30 ALS Bottle#: 7 Worklist Smp#: 19 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-A-3 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 First Level Reviewer: AF7X Date:21-Oct-2024 07:11:48 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 47.9 95.85 $5 1,2-Dichloroethane-d4 (Surr)50.0 50.3 100.67 $6 Toluene-d8 (Surr)50.0 51.0 102.00 $7 4-Bromofluorobenzene (Surr)50.0 51.5 103.05 Page 141 of 426 Report Date: 21-Oct-2024 07:14:10 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0607.D Injection Date: 21-Oct-2024 02:02:30 Instrument ID: VMS_MS1 Lims ID: 280-197896-A-3 Lab Sample ID: 280-197896-3 Client ID: MW-05 Operator ID: bustillose ALS Bottle#: 7 Worklist Smp#: 19 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 61 Benzene, CAS: 71-43-2 30 70 110 150 190 230 270 310 350 m/z 0 8 16 24 32 40 48 56 Y ( X10 0 0 ) Raw Spec:Scan 294(5.78) 65 67 51 102 104 50 30 70 110 150 190 230 270 310 350m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 294(5.78), Qvalue=90 Sig Qvalue=97 78 77 52 79 30 70 110 150 190 230 270 310 350 0 2 4 6 8 10 ( X10 0 ) Ref Spec: 61 Benzene (NIST98.L) 78 7751 7974 30 70 110 150 190 230 270 310 350 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.790 min.(Qvalue: 90) 64 5.2 5.5 5.8 6.1 Min RT 0 5 10 15 20 25 30 Y ( X10 0 0 ) m/z 78.0 5 . 7 7 9 5.2 5.5 5.8 6.1Min RT 0 3 6 9 12 15 18 Y ( X10 0 0 ) m/z 52.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min RT 0 3 6 9 12 Y ( X10 0 0 ) m/z 77.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min 0 5 10 15 20 25 30 Y ( X10 0 0 ) m/z 78.0 m/z 52.0 m/z 77.0 Page 142 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:MW-905 Lab Sample ID:280-197896-4 Matrix:MS1_0608.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 10:45 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 02:23 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.14J71-43-2 Benzene 0.89 1.0 0.14U100-41-4 Ethylbenzene 0.14 3.0 0.99U91-20-3 Naphthalene 0.99 1.0 0.32U108-88-3 Toluene 0.32 1.0 0.11U1330-20-7 Xylenes, Total 0.11 %RECCAS NO.LIMITSQSURROGATE 98 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 104 78-120460-00-4 4-Bromofluorobenzene (Surr) 102 80-1252037-26-5 Toluene-d8 (Surr) 95 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 143 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Lims ID: 280-197896-A-4 Client ID: MW-905 Sample Type: Client Inject. Date: 21-Oct-2024 02:23:30 ALS Bottle#: 8 Worklist Smp#: 20 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-A-4 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 First Level Reviewer: AF7X Date:21-Oct-2024 07:12:19 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3422522 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 759135 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1170938 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 726787 47.4 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 824946 49.2 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3320905 51.2 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 87 1126826 51.8 $ 8 BFB 95 9.899 9.900 -0.001 83 1126826 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 ND 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 92 4564 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.070 ND 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.307 ND 22 1,1-Dichloroethene 96 3.405 3.405 0.000 97 14170 1.18 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 ND 7 24 Iodomethane 142 3.559 ND 7 25 Isopropyl alcohol 45 3.573 3.587 -0.014 98 20306 4.64 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 ND 28 Methyl acetate 43 3.740 ND 29 3-Chloro-1-propene 41 3.754 ND 30 Methylene Chloride 84 3.880 ND 31 2-Methyl-2-propanol 59 3.964 ND U 32 Acrylonitrile 53 4.103 ND Page 144 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 7 39 1,1-Dichloroethane 63 4.536 4.536 0.000 95 31601 1.41 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 ND 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 7 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 5.249 0.000 88 61077 5.40 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 10702 0.6355 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND U 61 Benzene 78 5.779 5.779 0.000 91 50294 0.8893 62 1,2-Dichloroethane 62 5.821 ND 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND 65 n-Butanol 56 6.226 ND U 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 ND 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 6.631 0.000 88 4757 6.25 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 ND 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 145 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.224 ND 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 100 m-Xylene & p-Xylene 106 9.006 ND 101 o-Xylene 106 9.369 ND 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 ND U 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 122 1,2,3-Trimethylbenzene 105 11.101 ND 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 ND 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 ND 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 ND 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 146 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0 0.8893 S 150 Xylenes, Total (URS) 1 0.000 ND 7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0.000 ND 7 T 155 Dichloroacetonitrile TIC 74 1.000 ND T 156 2,3-dichloro-1-propene TIC 75 1.000 ND T 157 Propene oxide TIC 58 5.334 ND T 159 4-Ethyltoluene TIC 1 10.249 ND T 164 Dicyclopentadiene TIC 1 10.947 ND T 160 Methyl cyclohexane TIC 1 0.000 ND T 163 2-Butoxyethanol TIC 1 0.000 ND T 162 Propene TIC 1 0.000 ND T 161 Cyclohexane TIC 1 0.000 ND T 158 1,3-Butadiene TIC 1 0.000 ND QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 147 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Injection Date: 21-Oct-2024 02:23:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-A-4 Lab Sample ID: 280-197896-4 Worklist Smp#: 20 Client ID: MW-905 Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 8 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) MS1_0608[MS SCAN Chro]:Total 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ I s o p r o p yl a l c o h o l ( 3 . 5 7 3 )+ 1 ,1- D i c h l o r o e t h a n e ( 4 . 5 3 6 )+ Tet r a h yd ro f u r a n ( 5 . 2 4 9 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 ) 1 ,4- D i o xan e ( 6 . 6 3 1 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 ) Page 148 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Lims ID: 280-197896-A-4 Client ID: MW-905 Sample Type: Client Inject. Date: 21-Oct-2024 02:23:30 ALS Bottle#: 8 Worklist Smp#: 20 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-A-4 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 First Level Reviewer: AF7X Date:21-Oct-2024 07:12:19 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 47.4 94.84 $5 1,2-Dichloroethane-d4 (Surr)50.0 49.2 98.45 $6 Toluene-d8 (Surr)50.0 51.2 102.41 $7 4-Bromofluorobenzene (Surr)50.0 51.8 103.65 Page 149 of 426 Report Date: 21-Oct-2024 07:14:13 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0608.D Injection Date: 21-Oct-2024 02:23:30 Instrument ID: VMS_MS1 Lims ID: 280-197896-A-4 Lab Sample ID: 280-197896-4 Client ID: MW-905 Operator ID: bustillose ALS Bottle#: 8 Worklist Smp#: 20 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 61 Benzene, CAS: 71-43-2 30 70 110 150 190 230 270 310 350 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 294(5.78) 65 67 51 78 102 104 50 30 70 110 150 190 230 270 310 350m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 294(5.78), Qvalue=91 Sig Qvalue=97 78 77 50 52 79 30 70 110 150 190 230 270 310 350 0 2 4 6 8 10 ( X10 0 ) Ref Spec: 61 Benzene (NIST98.L) 78 7751 7974 30 70 110 150 190 230 270 310 350 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.790 min.(Qvalue: 91) 5.2 5.5 5.8 6.1 Min RT 0 4 8 12 16 20 24 Y ( X10 0 0 ) m/z 78.0 5 . 7 7 9 5.2 5.5 5.8 6.1Min RT 0 4 8 12 16 20 Y ( X10 0 0 ) m/z 52.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min RT 0 5 10 15 20 25 30 Y ( X10 0 0 ) m/z 77.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min 0 5 10 15 20 25 30 Y ( X10 0 0 ) m/z 78.0 m/z 52.0 m/z 77.0 Page 150 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:MW-03 Lab Sample ID:280-197896-5 Matrix:MS1_0603.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 12:30 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:5 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 00:36 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 5.0 0.7271-43-2 Benzene 160 5.0 0.72U100-41-4 Ethylbenzene 0.72 15 5.0U91-20-3 Naphthalene 5.0 5.0 1.6J108-88-3 Toluene 1.7 5.0 0.57U1330-20-7 Xylenes, Total 0.57 %RECCAS NO.LIMITSQSURROGATE 99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 101 78-120460-00-4 4-Bromofluorobenzene (Surr) 104 80-1252037-26-5 Toluene-d8 (Surr) 93 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 151 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Lims ID: 280-197896-A-5 Client ID: MW-03 Sample Type: Client Inject. Date: 21-Oct-2024 00:36:30 ALS Bottle#: 3 Worklist Smp#: 15 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Sample Info: 280-197896-A-5 5x Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:19:44 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3331864 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 742067 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1159366 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 693980 46.5 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 808621 49.6 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3298637 52.0 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 86 1092163 50.7 $ 8 BFB 95 9.899 9.900 -0.001 84 1092163 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 2.009 0.000 97 3649 0.2418 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 91 3625 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.070 ND U 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.307 ND U 22 1,1-Dichloroethene 96 3.405 ND 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 3.447 0.000 98 68097 2.97 24 Iodomethane 142 3.545 3.559 -0.014 97 13597 0.9437 25 Isopropyl alcohol 45 3.587 ND U 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 ND 7 28 Methyl acetate 43 3.740 3.740 0.000 93 5651 0.2938 29 3-Chloro-1-propene 41 3.754 ND 7 30 Methylene Chloride 84 3.880 ND 7 31 2-Methyl-2-propanol 59 3.964 ND U 32 Acrylonitrile 53 4.103 ND 7 Page 152 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 39 1,1-Dichloroethane 63 4.536 ND 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 142709 8.11 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND U 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 5.249 0.000 76 4167 0.3781 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 ND 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND U 61 Benzene 78 5.779 5.779 0.000 96 1723692 31.3 62 1,2-Dichloroethane 62 5.821 ND U 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND U 65 n-Butanol 56 6.226 ND 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 6.478 0.000 97 33224 1.35 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 6.631 0.000 86 8169 11.0 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND U 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 7.483 0.000 97 20343 0.3469 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 153 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 7 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.210 8.224 -0.014 85 2724 NC 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 7 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 4075 0.1738 101 o-Xylene 106 9.369 ND 7 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 7 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 9.830 0.000 61 2885 0.99 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 7 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 7 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 122 1,2,3-Trimethylbenzene 105 11.101 ND 7 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 ND 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 ND 7 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 ND 7 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 154 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 137 1-Chlorohexane TIC 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0 31.8 S 150 Xylenes, Total (URS) 1 0 0.1738 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0 0.1738 T 155 Dichloroacetonitrile TIC 74 1.000 ND T 156 2,3-dichloro-1-propene TIC 75 1.000 ND T 157 Propene oxide TIC 58 5.334 ND T 159 4-Ethyltoluene TIC 1 10.249 ND T 164 Dicyclopentadiene TIC 1 10.947 ND T 160 Methyl cyclohexane TIC 1 0.000 ND T 163 2-Butoxyethanol TIC 1 0.000 ND T 162 Propene TIC 1 0.000 ND T 161 Cyclohexane TIC 1 0.000 ND T 158 1,3-Butadiene TIC 1 0.000 ND QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 155 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Injection Date: 21-Oct-2024 00:36:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-A-5 Lab Sample ID: 280-197896-5 Worklist Smp#: 15 Client ID: MW-03 Purge Vol: 5.000 mL Dil. Factor: 5.0000 ALS Bottle#: 3 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 Y ( X10 0 0 0 0 ) MS1_0603[MS SCAN Chro]:Total E t h yle n e o xide( 2 . 1 9 0 ) A c e t o n e ( 3 . 4 4 7 )+ M e t h yl a c e t a t e ( 3 . 7 4 0 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 1 1 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 ) $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ Tet r a h yd ro t h i o p h e n e ( 8 . 2 2 4 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 )+ Page 156 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Lims ID: 280-197896-A-5 Client ID: MW-03 Sample Type: Client Inject. Date: 21-Oct-2024 00:36:30 ALS Bottle#: 3 Worklist Smp#: 15 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Sample Info: 280-197896-A-5 5x Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:19:44 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 46.5 93.02 $5 1,2-Dichloroethane-d4 (Surr)50.0 49.6 99.12 $6 Toluene-d8 (Surr)50.0 52.0 104.07 $7 4-Bromofluorobenzene (Surr)50.0 50.7 101.46 Page 157 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Injection Date: 21-Oct-2024 00:36:30 Instrument ID: VMS_MS1 Lims ID: 280-197896-A-5 Lab Sample ID: 280-197896-5 Client ID: MW-03 Operator ID: bustillose ALS Bottle#: 3 Worklist Smp#: 15 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 61 Benzene, CAS: 71-43-2 30 70 110 150 190 230 270 310 350 m/z 0 13 26 39 52 65 78 91 Y ( X10 0 0 0 ) Raw Spec:Scan 294(5.78) 78 77 51 79 30 70 110 150 190 230 270 310 350m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 294(5.78), Qvalue=96 Sig Qvalue=98 78 7751 79 30 70 110 150 190 230 270 310 350 0 2 4 6 8 10 ( X10 0 ) Ref Spec: 61 Benzene (NIST98.L) 78 7751 7974 30 70 110 150 190 230 270 310 350 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.770 min.(Qvalue: 96) 5.2 5.5 5.8 6.1 Min RT 0 16 32 48 64 80 96 Y ( X10 0 0 0 ) m/z 78.0 5 . 7 7 9 5.2 5.5 5.8 6.1Min RT 0 3 6 9 12 15 Y ( X10 0 0 0 ) m/z 52.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min RT 0 4 8 12 16 20 24 Y ( X10 0 0 0 ) m/z 77.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min 0 16 32 48 64 80 96 Y ( X10 0 0 0 ) m/z 78.0 m/z 52.0 m/z 77.0 Page 158 of 426 Report Date: 21-Oct-2024 01:20:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0603.D Injection Date: 21-Oct-2024 00:36:30 Instrument ID: VMS_MS1 Lims ID: 280-197896-A-5 Lab Sample ID: 280-197896-5 Client ID: MW-03 Operator ID: bustillose ALS Bottle#: 3 Worklist Smp#: 15 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 80 Toluene, CAS: 108-88-3 30 70 110 150 190 230 270 310 350 m/z 0 2 4 6 8 10 12 Y ( X10 0 0 ) Raw Spec:Scan 416(7.48) 91 92 98 65 89 30 70 110 150 190 230 270 310 350m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 416(7.48), Qvalue=97 Sig Qvalue=100 91 92 65 89 30 70 110 150 190 230 270 310 350 0 2 4 6 8 10 ( X10 0 ) Ref Spec: 80 Toluene (NIST98.L) 91 92 65 30 70 110 150 190 230 270 310 350 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 7.480 min.(Qvalue: 97) 89 63 6.9 7.2 7.5 7.8 Min RT 0 2 4 6 8 10 12 Y ( X10 0 0 ) m/z 91.0 7 . 4 8 3 6.9 7.2 7.5 7.8Min RT 0 11 22 33 44 55 66 Y ( X10 0 ) m/z 92.0 7 . 4 8 3 6.9 7.2 7.5 7.8 Min RT 0 5 10 15 20 25 30 Y ( X10 0 ) m/z 65.0 7 . 4 8 3 6.9 7.2 7.5 7.8 Min 0 2 4 6 8 10 12 Y ( X10 0 0 ) m/z 91.0 m/z 92.0 m/z 65.0 Page 159 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:MW-16 Lab Sample ID:280-197896-6 Matrix:MS1_0609.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 13:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 02:45 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.14J71-43-2 Benzene 0.61 1.0 0.14U100-41-4 Ethylbenzene 0.14 3.0 0.99U91-20-3 Naphthalene 0.99 1.0 0.32U108-88-3 Toluene 0.32 1.0 0.11U1330-20-7 Xylenes, Total 0.11 %RECCAS NO.LIMITSQSURROGATE 101 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 101 78-120460-00-4 4-Bromofluorobenzene (Surr) 102 80-1252037-26-5 Toluene-d8 (Surr) 96 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 160 of 426 Report Date: 21-Oct-2024 07:14:15 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Lims ID: 280-197896-A-6 Client ID: MW-16 Sample Type: Client Inject. Date: 21-Oct-2024 02:45:30 ALS Bottle#: 9 Worklist Smp#: 21 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-A-6 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 First Level Reviewer: AF7X Date:21-Oct-2024 07:12:53 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3480752 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 778832 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1219636 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 747173 47.9 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 858308 50.4 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3391622 51.0 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 86 1147944 50.7 $ 8 BFB 95 9.899 9.900 -0.001 83 1147944 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 ND 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 93 5032 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.070 ND 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.307 ND 22 1,1-Dichloroethene 96 3.405 3.405 0.000 98 31748 2.60 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 ND 7 24 Iodomethane 142 3.559 ND 7 25 Isopropyl alcohol 45 3.587 3.587 0.000 78 5610 1.26 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 ND 28 Methyl acetate 43 3.740 ND 29 3-Chloro-1-propene 41 3.754 ND 30 Methylene Chloride 84 3.880 ND 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 91 6510 0.8163 32 Acrylonitrile 53 4.103 ND Page 161 of 426 Report Date: 21-Oct-2024 07:14:15 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 39 1,1-Dichloroethane 63 4.536 4.536 0.000 96 44064 1.93 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 ND 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 7 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 5.249 0.000 87 30336 2.64 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 96 60998 3.56 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND U 61 Benzene 78 5.779 5.779 0.000 92 35100 0.6103 62 1,2-Dichloroethane 62 5.821 ND 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND 7 65 n-Butanol 56 6.226 ND 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 ND 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 6.631 0.000 94 8944 11.6 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 ND 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 162 of 426 Report Date: 21-Oct-2024 07:14:15 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.224 ND 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 100 m-Xylene & p-Xylene 106 9.006 ND 101 o-Xylene 106 9.369 ND 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 ND U 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 122 1,2,3-Trimethylbenzene 105 11.101 ND 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 ND 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 13.335 0.000 96 14415 0.2478 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 ND 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 163 of 426 Report Date: 21-Oct-2024 07:14:15 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0 0.6103 S 150 Xylenes, Total (URS) 1 0.000 ND 7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0.000 ND 7 T 155 Dichloroacetonitrile TIC 74 1.000 ND T 156 2,3-dichloro-1-propene TIC 75 1.000 ND T 157 Propene oxide TIC 58 5.334 ND T 159 4-Ethyltoluene TIC 1 10.249 ND T 164 Dicyclopentadiene TIC 1 10.947 ND T 160 Methyl cyclohexane TIC 1 0.000 ND T 163 2-Butoxyethanol TIC 1 0.000 ND T 162 Propene TIC 1 0.000 ND T 161 Cyclohexane TIC 1 0.000 ND T 158 1,3-Butadiene TIC 1 0.000 ND QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 164 of 426 Report Date: 21-Oct-2024 07:14:15 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Injection Date: 21-Oct-2024 02:45:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-A-6 Lab Sample ID: 280-197896-6 Worklist Smp#: 21 Client ID: MW-16 Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 9 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) MS1_0609[MS SCAN Chro]:Total 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ I s o p r o p yl a l c o h o l ( 3 . 5 7 3 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 ) 1 ,1- D i c h l o r o e t h a n e ( 4 . 5 3 6 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ 1 ,4- D i o xan e ( 6 . 6 3 1 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) Page 165 of 426 Report Date: 21-Oct-2024 07:14:15 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Lims ID: 280-197896-A-6 Client ID: MW-16 Sample Type: Client Inject. Date: 21-Oct-2024 02:45:30 ALS Bottle#: 9 Worklist Smp#: 21 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: 280-197896-A-6 Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 First Level Reviewer: AF7X Date:21-Oct-2024 07:12:53 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 47.9 95.87 $5 1,2-Dichloroethane-d4 (Surr)50.0 50.4 100.72 $6 Toluene-d8 (Surr)50.0 51.0 101.95 $7 4-Bromofluorobenzene (Surr)50.0 50.7 101.37 Page 166 of 426 Report Date: 21-Oct-2024 07:14:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0609.D Injection Date: 21-Oct-2024 02:45:30 Instrument ID: VMS_MS1 Lims ID: 280-197896-A-6 Lab Sample ID: 280-197896-6 Client ID: MW-16 Operator ID: bustillose ALS Bottle#: 9 Worklist Smp#: 21 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 61 Benzene, CAS: 71-43-2 30 70 110 150 190 230 270 310 350 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 294(5.78) 65 67 51 102 104 30 70 110 150 190 230 270 310 350m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 294(5.78), Qvalue=92 Sig Qvalue=98 78 7752 79 30 70 110 150 190 230 270 310 350 0 2 4 6 8 10 ( X10 0 ) Ref Spec: 61 Benzene (NIST98.L) 78 7751 7974 30 70 110 150 190 230 270 310 350 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.790 min.(Qvalue: 92) 64 5.2 5.5 5.8 6.1 Min RT 0 3 6 9 12 15 18 Y ( X10 0 0 ) m/z 78.0 5 . 7 7 9 5.2 5.5 5.8 6.1Min RT 0 4 8 12 16 20 Y ( X10 0 0 ) m/z 52.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min RT 0 15 30 45 60 75 90 Y ( X10 0 ) m/z 77.0 5 . 7 7 9 5.2 5.5 5.8 6.1 Min 0 5 10 15 20 25 30 Y ( X10 0 0 ) m/z 78.0 m/z 52.0 m/z 77.0 Page 167 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 0.25(mm)DB-624 (60.25)ID: Calibration Files LEVEL:LAB SAMPLE ID:LAB FILE ID:1Level IC 280-671165/13 MS1_0297.D 2Level IC 280-671165/40 MS1_0298.D 3Level IC 280-671165/41 MS1_0299.D 4Level IC 280-671165/42 MS1_0300.D 5Level IC 280-671165/43 MS1_0301.D 6Level ICIS 280-671165/44 MS1_0302.D 7Level IC 280-671165/45 MS1_0303.D 8Level IC 280-671165/46 MS1_0304.D 9Level IC 280-671165/47 MS1_0305.D ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 LVL 9 Dichlorodifluoromethane 0.2449 0.2332 0.2038 0.2410 0.1799 Ave 10.1 0.2267 +++++ 0.2060 0.2128 15.00.218 5Chloromethane0.2660 0.2509 0.2340 0.2234 0.1802 Ave 11.4 0.2291 +++++ 0.2115 0.2164 0.1000 15.00.226 4Vinyl chloride 0.2048 0.2080 0.2152 0.2279 0.1712 Ave 8.3 0.2221 +++++ 0.2015 0.2025 30.00.206 7Bromomethane0.2390 0.2217 0.1659 0.1394 0.1156 Lin1 0.9990 0.1258 +++++ 0.1245 +++++ 0.99000.070 2 0.123 3Chloroethane0.1453 0.1756 0.1410 0.1544 0.1071 Ave 13.7 0.1452 +++++ 0.1339 0.1340 15.00.142 0Dichlorofluoromethane0.3923 0.3721 0.3633 0.3753 0.2836 Ave 9.9 0.3557 +++++ 0.3299 0.3291 15.00.350 2Trichlorofluoromethane0.2635 0.3010 0.2687 0.2681 0.2063 Ave 10.7 0.2606 +++++ 0.2398 0.2448 15.00.256 6Ethyl ether 0.1840 0.1875 0.1794 0.1678 0.1571 Ave 8.7 0.1591 +++++ 0.1500 0.1541 15.00.167 4Acrolein0.0450 0.0357 0.0375 0.0354 0.0339 Ave 10.9 0.0344 +++++ 0.0328 0.0333 15.00.036 01,1-Dichloroethene 0.1975 0.1762 0.1734 0.1736 0.1730 Ave 5.7 0.1747 +++++ 0.1616 0.1723 30.00.175 3 1,1,2-Trichloro-1,2,2-trifluoroeth ane 0.1548 0.1390 0.1255 0.1307 0.1356 Ave 8.9 0.1266 +++++ 0.1168 0.1236 15.00.131 6 Acetone 0.4354 0.2974 0.2264 0.1819 0.1645 Lin2 0.9990 0.1542 +++++ 0.1467 0.1478 0.99000.576 0 0.150 3 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 168 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 0.25(mm)DB-624 (60.25)ID: ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 LVL 9 Iodomethane 0.3290 0.2182 0.1882 0.1648 0.1588 Lin1 0.9970 0.1954 +++++ 0.2008 0.2043 0.99000.015 1 0.200 2Carbon disulfide 0.5225 0.4887 0.4595 0.4490 0.4536 Ave 5.2 0.4828 +++++ 0.4636 0.4906 15.00.476 3Methyl acetate 0.2981 0.3069 0.3057 0.2842 0.2800 Ave 4.8 0.2883 +++++ 0.2696 0.2762 15.00.288 63-Chloro-1-propene 0.9449 0.5672 0.4001 0.2746 0.2475 Lin2 0.9970 0.2332 +++++ 0.2045 0.2008 0.99000.367 2 0.208 1Methylene Chloride 0.3488 0.2655 0.2269 0.2178 0.2011 Lin2 0.9980 0.2002 +++++ 0.1811 0.1908 0.99000.077 6 0.191 82-Methyl-2-propanol 0.1250 0.1130 0.1107 0.1149 0.1080 Ave 4.3 0.1159 +++++ 0.1140 0.1150 15.00.114 6Acrylonitrile0.1547 0.1581 0.1625 0.1537 0.1584 Ave 6.5 0.1536 +++++ 0.1428 0.1321 15.00.152 0Methyl tert-butyl ether 0.5795 0.6322 0.6319 0.5541 0.5788 Ave 5.2 0.5804 +++++ 0.5535 0.5784 15.00.586 1trans-1,2-Dichloroethene 0.2108 0.1761 0.1945 0.1960 0.1968 Ave 5.5 0.1954 +++++ 0.1807 0.1919 15.00.192 8Hexane1.2731 1.0529 0.9984 1.1522 1.0778 Ave 8.9 1.0678 +++++ 0.9802 1.0111 15.01.076 7Vinyl acetate 0.4705 0.3764 0.3730 0.3619 0.3648 Ave 11.4 0.3775 +++++ 0.3352 0.3338 15.00.374 11,1-Dichloroethane 0.3411 0.3545 0.3430 0.3317 0.3199 Ave 5.4 0.3221 +++++ 0.3011 0.3112 0.1000 15.00.328 12-Butanone (MEK)0.3457 0.2627 0.2696 0.2579 0.2500 Ave 13.3 0.2534 +++++ 0.2368 0.2353 15.00.263 92,2-Dichloropropane 0.1744 0.2119 0.2075 0.2078 0.2073 Ave 8.2 0.2235 +++++ 0.2176 0.2339 15.00.210 5cis-1,2-Dichloroethene 0.2061 0.2413 0.2422 0.2124 0.2097 Ave 7.2 0.2146 +++++ 0.2006 0.2135 15.00.217 5sec-Butyl Alcohol 0.0862 0.0716 0.0797 0.0833 0.0796 Ave 6.4 0.0855 +++++ 0.0832 0.0748 15.00.080 5Chlorobromomethane0.1250 0.1154 0.1002 0.0937 0.0932 Ave 14.0 0.0913 +++++ 0.0851 0.0892 15.00.099 1Tetrahydrofuran0.1616 0.1827 0.1706 0.1646 0.1626 Ave 4.9 0.1643 +++++ 0.1568 0.1598 15.00.165 4 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 169 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 0.25(mm)DB-624 (60.25)ID: ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 LVL 9 Chloroform 0.3570 0.3251 0.3120 0.3231 0.3016 Ave 5.8 0.3170 +++++ 0.2981 0.3109 30.00.318 11,1,1-Trichloroethane 0.2491 0.2456 0.2361 0.2422 0.2405 Ave 3.1 0.2541 +++++ 0.2420 0.2587 15.00.246 0Cyclohexane0.3438 0.3295 0.3197 0.3150 0.3218 Ave 4.8 0.3167 +++++ 0.2913 0.3077 15.00.318 21,1-Dichloropropene 0.2495 0.3078 0.2635 0.2733 0.2604 Ave 7.2 0.2637 +++++ 0.2452 0.2609 15.00.265 6Carbon tetrachloride 0.1722 0.1854 0.1676 0.1708 0.1707 Ave 7.2 0.1896 +++++ 0.1876 0.2055 15.00.181 2Isobutyl alcohol 0.0016 0.0235 0.0275 0.0305 0.0274 Lin2 0.9900 0.0317 +++++ 0.0309 0.0313 0.9900-0.34 4 0.032 2Benzene0.9004 0.8963 0.8918 0.7976 0.8084 Ave 7.5 0.8052 +++++ 0.7447 0.7651 15.00.826 21,2-Dichloroethane 0.3012 0.2552 0.2676 0.2458 0.2338 Ave 10.7 0.2328 +++++ 0.2202 0.2262 15.00.247 9n-Heptane 0.2238 0.2079 0.1916 0.1881 0.1893 Ave 6.6 0.1973 +++++ 0.1840 0.1969 15.00.197 4Trichloroethene0.8440 0.8656 0.9102 0.8620 0.8483 Ave 3.6 0.8433 +++++ 0.8055 0.8245 15.00.850 42-Pentanone 0.4092 0.3679 0.3779 0.3757 0.3631 Ave 5.4 0.3766 +++++ 0.3523 0.3421 15.00.370 6Methylcyclohexane0.3121 0.2442 0.2521 0.2353 0.2302 Ave 11.9 0.2361 +++++ 0.2163 0.2306 15.00.244 61,2-Dichloropropane 0.2066 0.1941 0.1959 0.1825 0.1875 Ave 4.5 0.1920 +++++ 0.1789 0.1920 30.00.191 21,4-Dioxane 0.0115 0.0114 0.0116 0.0114 0.0109 Ave 4.0 0.0110 +++++ 0.0105 0.0105 15.00.011 1Dibromomethane0.1405 0.1303 0.1185 0.1098 0.1160 Ave 8.3 0.1165 +++++ 0.1132 0.1191 15.00.120 5Dichlorobromomethane0.2083 0.1919 0.1980 0.1919 0.1957 Ave 5.6 0.2094 +++++ 0.2087 0.2250 15.00.203 62-Chloroethyl vinyl ether 0.0756 0.0679 0.0584 0.0600 0.0490 Ave 12.7 0.0650 +++++ 0.0658 0.0701 15.00.064 0cis-1,3-Dichloropropene 1.1011 1.0837 1.0997 1.0410 1.0967 Ave 6.1 1.1835 +++++ 1.2024 1.2391 15.01.130 9 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 170 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 0.25(mm)DB-624 (60.25)ID: ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 LVL 9 4-Methyl-2-pentanone (MIBK)0.3672 0.3396 0.3548 0.3607 0.3479 Ave 4.4 0.3582 +++++ 0.3357 0.3207 15.00.348 1Toluene1.0018 0.8885 0.8976 0.8888 0.8606 Ave 6.6 0.8652 +++++ 0.8043 0.8339 30.00.880 1trans-1,3-Dichloropropene 0.1883 0.1765 0.1991 0.2042 0.2135 Ave 14.5 0.2447 +++++ 0.2438 0.2672 15.00.217 2Ethyl methacrylate 1.4372 1.4108 1.3330 1.3172 1.2934 Ave 3.6 1.3473 +++++ 1.3261 1.3530 15.01.352 21,1,2-Trichloroethane 0.2183 0.1846 0.1847 0.1875 0.1869 Ave 6.5 0.1868 +++++ 0.1764 0.1863 15.00.188 9Tetrachloroethene0.7843 0.7165 0.6675 0.6560 0.6559 Ave 7.6 0.6543 +++++ 0.6293 0.6378 15.00.675 21,3-Dichloropropane 1.5865 1.4306 1.4485 1.3937 1.4258 Ave 6.8 1.3409 +++++ 1.2917 1.3006 15.01.402 32-Hexanone 1.3922 1.3582 1.3283 1.4197 1.3483 Ave 5.7 1.3144 +++++ 1.2722 1.1788 15.01.326 5Chlorodibromomethane0.4902 0.5325 0.6032 0.5435 0.5944 Ave 13.8 0.6645 +++++ 0.6918 0.7292 15.00.606 2Ethylene Dibromide 0.9243 0.7845 0.8516 0.7989 0.8351 Ave 5.0 0.8378 +++++ 0.8235 0.8341 15.00.836 21-Chlorohexane +++++ 1.3836 1.4002 1.2013 1.1483 Ave 10.8 1.1375 +++++ 1.0822 1.1062 15.01.208 5Chlorobenzene2.6110 2.4790 2.4613 2.3624 2.3349 Ave 6.4 2.2565 +++++ 2.1874 2.1807 0.3000 15.02.359 21,1,1,2-Tetrachloroethane 0.5922 0.5058 0.6282 0.5744 0.6441 Ave 10.5 0.6666 +++++ 0.6746 0.7123 15.00.624 8Ethylbenzene1.5394 1.3837 1.4099 1.2821 1.3468 Ave 7.1 1.2982 +++++ 1.2409 1.2818 30.01.347 9m-Xylene & p-Xylene 1.4988 1.5914 1.6816 1.5991 1.6135 Ave 3.6 1.5796 +++++ 1.5327 1.5416 15.01.579 8o-Xylene 1.7370 1.6713 1.5720 1.5244 1.5300 Ave 6.0 1.5134 +++++ 1.4685 1.4853 15.01.562 7Styrene2.9710 2.4122 2.5702 2.4596 2.5367 Ave 7.0 2.5200 +++++ 2.4486 2.4602 15.02.547 3Bromoform+++++ 0.2647 0.3545 0.3098 0.3621 Lin1 0.9950 0.4289 +++++ 0.4548 0.5018 0.1000 0.9900-0.36 6 0.478 2 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 171 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 0.25(mm)DB-624 (60.25)ID: ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 LVL 9 Isopropylbenzene 2.5147 2.2885 2.2297 2.2683 2.3037 Ave 6.0 2.2481 +++++ 2.1043 2.0687 15.02.253 3Cyclohexanone0.2009 0.1949 0.2063 0.2092 0.2015 Ave 5.7 0.1942 +++++ 0.1898 0.1734 15.00.196 31,1,2,2-Tetrachloroethane 0.9517 0.7576 0.8935 0.8425 0.8422 Ave 7.5 0.8185 +++++ 0.7860 0.7955 0.3000 15.00.835 9Bromobenzene0.7209 0.5765 0.6567 0.5748 0.5792 Ave 9.6 0.5790 +++++ 0.5510 0.5693 15.00.600 9trans-1,4-Dichloro-2-butene +++++ 0.1287 0.1294 0.1366 0.1330 Lin1 0.9940 0.1673 +++++ 0.1752 0.1951 0.9900-0.12 6 0.185 31,2,3-Trichloropropane 0.4185 0.2703 0.3169 0.3026 0.3043 Lin1 0.9990 0.2801 +++++ 0.2699 0.2770 0.99000.061 1 0.275 6N-Propylbenzene 0.8174 0.7314 0.7640 0.6874 0.6887 Ave 8.6 0.6723 +++++ 0.6373 0.6509 15.00.706 22-Chlorotoluene 0.5715 0.6077 0.6219 0.5663 0.5782 Ave 5.1 0.5525 +++++ 0.5393 0.5469 15.00.573 01,3,5-Trimethylbenzene 2.1772 1.8802 2.0616 2.0539 1.9372 Ave 5.9 1.9547 +++++ 1.8699 1.8369 15.01.971 54-Chlorotoluene 0.7379 0.6693 0.6469 0.5701 0.6201 Ave 10.2 0.5806 +++++ 0.5544 0.5698 15.00.618 6tert-Butylbenzene 1.8486 1.8075 1.7811 1.7305 1.6739 Ave 5.8 1.6759 +++++ 1.5997 1.5681 15.01.710 71,2,4-Trimethylbenzene 2.3514 1.9691 2.1753 2.0506 2.0664 Ave 7.2 2.0222 +++++ 1.9382 1.8818 15.02.056 9sec-Butylbenzene 0.5684 0.4294 0.5573 0.4937 0.4725 Ave 9.4 0.4863 +++++ 0.4735 0.4728 15.00.494 21,3-Dichlorobenzene 1.3421 1.0800 1.2122 1.1027 1.1164 Ave 8.9 1.0845 +++++ 1.0391 1.0535 15.01.128 84-Isopropyltoluene 2.3268 2.0339 2.2302 2.1157 2.1039 Ave 5.8 2.1085 +++++ 1.9903 1.9605 15.02.108 71,4-Dichlorobenzene 1.3238 1.2256 1.2699 1.0757 1.1182 Ave 8.8 1.1072 +++++ 1.0589 1.0705 15.01.156 2n-Butylbenzene 2.0652 1.8862 1.9788 1.8211 1.8479 Ave 6.0 1.8386 +++++ 1.7460 1.7342 15.01.864 81,2-Dichlorobenzene 1.2407 1.0706 1.1658 1.0545 1.0593 Ave 7.7 1.0398 +++++ 0.9923 1.0095 15.01.079 1 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 172 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 0.25(mm)DB-624 (60.25)ID: ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 LVL 9 1,2-Dibromo-3-Chloropropane 0.2143 0.1925 0.2271 0.2167 0.2165 Ave 10.8 0.2414 +++++ 0.2509 0.2713 15.00.228 81,2,4-Trichlorobenzene 0.7599 0.6289 0.5671 0.5962 0.5785 Ave 10.6 0.5878 +++++ 0.5705 0.5760 15.00.608 1Hexachlorobutadiene0.1999 0.2047 0.2253 0.2163 0.2170 Ave 4.3 0.2167 +++++ 0.1999 0.2101 15.00.211 2Naphthalene2.6572 2.3107 2.5415 2.3516 2.3046 Ave 5.8 2.3461 +++++ 2.3070 2.2614 15.02.385 01,2,3-Trichlorobenzene 0.5432 0.5376 0.5878 0.5475 0.5231 Ave 3.7 0.5398 +++++ 0.5279 0.5326 15.00.542 4Dibromofluoromethane (Surr)0.2163 0.2228 0.2220 0.2233 0.2233 Ave 1.8 0.2272 +++++ 0.2271 0.2293 15.00.223 91,2-Dichloroethane-d4 (Surr)0.2421 0.2517 0.2417 0.2423 0.2389 Ave 1.8 0.2480 +++++ 0.2442 0.2497 15.00.244 8Toluene-d8 (Surr)4.3047 4.2248 4.3103 4.2888 4.3379 Ave 1.3 4.2001 +++++ 4.3086 4.1970 15.04.271 54-Bromofluorobenzene (Surr)0.9394 0.9206 0.9424 0.9356 0.9495 Ave 1.7 0.9191 +++++ 0.9198 0.9014 15.00.928 5 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 173 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 GC Column:DB-624 (60.25)ID:0.25(mm) Calibration Files: LEVEL: LAB SAMPLE ID:LAB FILE ID: Level 1 IC 280-671165/13 MS1_0297.D Level 2 IC 280-671165/40 MS1_0298.D Level 3 IC 280-671165/41 MS1_0299.D Level 4 IC 280-671165/42 MS1_0300.D Level 5 IC 280-671165/43 MS1_0301.D Level 6 ICIS 280-671165/44 MS1_0302.D Level 7 IC 280-671165/45 MS1_0303.D Level 8 IC 280-671165/46 MS1_0304.D Level 9 IC 280-671165/47 MS1_0305.D ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Dichlorodifluoromethane AveFB 6905 13272 22941 68579 102404 0.500 1.00 2.00 5.00 10.0 667292 200100+++++50.026803001275820+++++ Chloromethane AveFB 7498 14285 26332 63566 102569 0.500 1.00 2.00 5.00 10.0 674274 200100+++++50.027258481309890+++++ Vinyl chloride AveFB 5774 11843 24223 64852 97468 0.500 1.00 2.00 5.00 10.0 653707 200100+++++50.025509991247723+++++ Bromomethane Lin1FB 6738 12622 18673 39658 65822 0.500 1.00 2.00 5.00 10.0 370419 +++++100+++++50.0+++++771017+++++ Chloroethane AveFB 4095 9996 15866 43919 60975 0.500 1.00 2.00 5.00 10.0 427300 200100+++++50.01687617829028+++++ Dichlorofluoromethane AveFB 11058 21181 40893 106790 161417 0.500 1.00 2.00 5.00 10.0 1046904 200100+++++50.041448982042824+++++ Trichlorofluoromethane AveFB 7428 17135 30243 76287 117402 0.500 1.00 2.00 5.00 10.0 767195 200100+++++50.030828461484969+++++ Ethyl ether AveFB 5187 10674 20191 47751 89432 0.500 1.00 2.00 5.00 10.0 468264 200100+++++50.01940795928668+++++ Acrolein AveFB 12518 20061 41630 99411 190488 4.94 9.88 19.8 49.4 98.8 1000348 1975988+++++49441361162007111+++++ 1,1-Dichloroethene AveFB 5567 10030 19515 49381 98461 0.500 1.00 2.00 5.00 10.0 514322 200100+++++50.021697611000625+++++ 1,1,2-Trichloro-1,2,2-trifluoroetha ne AveFB 4365 7912 14128 37200 77163 0.500 1.00 2.00 5.00 10.0 372647 200100+++++50.01557070723314+++++ Acetone Lin2FB 49096 67721 101927 207043 374461 2.00 4.00 8.00 20.0 40.0 1815204 800400+++++20074448473634749+++++ Iodomethane Lin1FB 9274 12422 21179 46878 90366 0.500 1.00 2.00 5.00 10.0 575280 200100+++++50.025733211243483+++++ Carbon disulfide AveFB 14730 27821 51718 127757 258152 0.500 1.00 2.00 5.00 10.0 1421027 200100+++++50.061792892871275+++++ FORM VI 8260D Page 174 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 GC Column:DB-624 (60.25)ID:0.25(mm) ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Methyl acetate AveFB 16808 34937 68817 161716 318679 1.00 2.00 4.00 10.0 20.0 1697013 400200+++++10069576533339491+++++ 3-Chloro-1-propene Lin2FB 26637 32289 45038 78128 140845 0.500 1.00 2.00 5.00 10.0 686399 200100+++++50.025293261266649+++++ Methylene Chloride Lin2FB 9832 15115 25535 61975 114438 0.500 1.00 2.00 5.00 10.0 589274 200100+++++50.024026091121560+++++ 2-Methyl-2-propanol AveFB 35229 64306 124590 326901 614546 5.00 10.0 20.0 50.0 100 3410387 20001000+++++500144899757062258+++++ Acrylonitrile AveFB 43602 90015 182911 437289 901591 5.00 10.0 20.0 50.0 100 4521458 20001000+++++500166412508844394+++++ Methyl tert-butyl ether AveFB 16336 35985 71124 157635 329435 0.500 1.00 2.00 5.00 10.0 1708327 200100+++++50.072849333427653+++++ trans-1,2-Dichloroethene AveFB 5942 10023 21888 55755 112004 0.500 1.00 2.00 5.00 10.0 575215 200100+++++50.024167651118783+++++ Hexane AveCBNZd 5 8246 14062 25795 75261 139306 0.500 1.00 2.00 5.00 10.0 738594 200100+++++50.030561401399408+++++ Vinyl acetate AveFB 26530 42850 83960 205928 415210 1.00 2.00 4.00 10.0 20.0 2222342 400200+++++10084097904151527+++++ 1,1-Dichloroethane AveFB 9617 20178 38607 94382 182081 0.500 1.00 2.00 5.00 10.0 947998 200100+++++50.039196171864549+++++ 2-Butanone (MEK)AveFB 38979 59826 121362 293460 569181 2.00 4.00 8.00 20.0 40.0 2983807 800400+++++200118527945866424+++++ 2,2-Dichloropropane AveFB 4916 12065 23351 59133 117989 0.500 1.00 2.00 5.00 10.0 657811 200100+++++50.029464161347584+++++ cis-1,2-Dichloroethene AveFB 5810 13738 27262 60421 119348 0.500 1.00 2.00 5.00 10.0 631733 200100+++++50.026885011242382+++++ sec-Butyl Alcohol AveFB 58290 97786 215204 568654 1087796 12.0 24.0 48.0 120 240 6036891 48002400+++++12002262215412369367+++++ Chlorobromomethane AveFB 3524 6570 11273 26661 53071 0.500 1.00 2.00 5.00 10.0 268742 200100+++++50.01123822526882+++++ Tetrahydrofuran AveFB 9111 20802 38400 93636 185047 1.00 2.00 4.00 10.0 20.0 967214 400200+++++10040262181941819+++++ Chloroform AveFB 10063 18504 35121 91931 171654 0.500 1.00 2.00 5.00 10.0 933064 200100+++++50.039154231846233+++++ 1,1,1-Trichloroethane AveFB 7022 13979 26569 68903 136859 0.500 1.00 2.00 5.00 10.0 747850 200100+++++50.032583071498829+++++ Cyclohexane AveFB 9693 18757 35988 89610 183151 0.500 1.00 2.00 5.00 10.0 932242 200100+++++50.038752351803913+++++ 1,1-Dichloropropene AveFB 7034 17522 29662 77760 148203 0.500 1.00 2.00 5.00 10.0 776177 200100+++++50.032866211518679+++++ FORM VI 8260D Page 175 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 GC Column:DB-624 (60.25)ID:0.25(mm) ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Carbon tetrachloride AveFB 4855 10554 18869 48593 97133 0.500 1.00 2.00 5.00 10.0 558115 200100+++++50.025877741161580+++++ Isobutyl alcohol Lin2FB 1106 33508 77424 217042 390372 12.5 25.0 50.0 125 250 2332700 50002500+++++125098533824790431+++++ Benzene AveFB 25383 51023 100376 226940 460127 0.500 1.00 2.00 5.00 10.0 2370146 200100+++++50.096362394611739+++++ 1,2-Dichloroethane AveFB 8490 14528 30118 69929 133061 0.500 1.00 2.00 5.00 10.0 685334 200100+++++50.028495601363728+++++ n-Heptane AveFB 6308 11832 21568 53507 107729 0.500 1.00 2.00 5.00 10.0 580772 200100+++++50.024805911139688+++++ Trichloroethene AveCBNZd 5 5467 11561 23516 56307 109639 0.500 1.00 2.00 5.00 10.0 583331 200100+++++50.024920331150001+++++ 2-Pentanone AveFB 36913 67022 136102 342083 661297 1.60 3.20 6.40 16.0 32.0 3547526 640320+++++160137894996982722+++++ Methylcyclohexane AveFB 8799 13900 28377 66940 131038 0.500 1.00 2.00 5.00 10.0 694973 200100+++++50.029042401339752+++++ 1,2-Dichloropropane AveFB 5823 11050 22050 51933 106718 0.500 1.00 2.00 5.00 10.0 565257 200100+++++50.024182131107705+++++ 1,4-Dioxane AveFB 6503 13008 26214 64759 123608 10.0 20.0 40.0 100 200 647411 40002000+++++100026482161306507+++++ Dibromomethane AveFB 3960 7416 13335 31244 66039 0.500 1.00 2.00 5.00 10.0 342787 200100+++++50.01500342701274+++++ Dichlorobromomethane AveFB 5872 10924 22283 54597 111398 0.500 1.00 2.00 5.00 10.0 616336 200100+++++50.028341481292785+++++ 2-Chloroethyl vinyl ether AveFB 2131 3865 6573 17058 27864 0.500 1.00 2.00 5.00 10.0 191285 200100+++++50.0882965407212+++++ cis-1,3-Dichloropropene AveCBNZd 5 7132 14474 28414 67996 141753 0.500 1.00 2.00 5.00 10.0 818597 200100+++++50.037451921716607+++++ 4-Methyl-2-pentanone (MIBK)AveFB 41407 77316 159714 410478 792010 2.00 4.00 8.00 20.0 40.0 4217150 800400+++++200161582738315143+++++ Toluene AveFB 28241 50580 101031 252872 489813 0.500 1.00 2.00 5.00 10.0 2546571 200100+++++50.0105029984980885+++++ trans-1,3-Dichloropropene AveFB 5307 10046 22404 58104 121525 0.500 1.00 2.00 5.00 10.0 720277 200100+++++50.033654461509809+++++ Ethyl methacrylate AveCBNZd 5 9309 18842 34442 86037 167177 0.500 1.00 2.00 5.00 10.0 931899 200100+++++50.040896031893155+++++ 1,1,2-Trichloroethane AveFB 6153 10510 20787 53350 106399 0.500 1.00 2.00 5.00 10.0 549793 200100+++++50.023468491092570+++++ FORM VI 8260D Page 176 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 GC Column:DB-624 (60.25)ID:0.25(mm) ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Tetrachloroethene AveCBNZd 5 5080 9569 17246 42851 84782 0.500 1.00 2.00 5.00 10.0 452597 200100+++++50.01927840898427+++++ 1,3-Dichloropropane AveCBNZd 5 10276 19107 37426 91036 184288 0.500 1.00 2.00 5.00 10.0 927488 200100+++++50.039310261844109+++++ 2-Hexanone AveCBNZd5 36069 72561 137275 370944 697096 2.00 4.00 8.00 20.0 40.0 3636603 800400+++++200142522107264833+++++ Chlorodibromomethane AveCBNZd 5 3175 7112 15586 35503 76829 0.500 1.00 2.00 5.00 10.0 459599 200100+++++50.02204034987661+++++ Ethylene Dibromide AveCBNZd 5 5987 10478 22003 52186 107934 0.500 1.00 2.00 5.00 10.0 579533 200100+++++50.025211391175629+++++ 1-Chlorohexane AveCBNZd 5 +++++ 14783 28942 62777 118732 +++++ 0.800 1.60 4.00 8.00 629431 16080.0+++++40.026748491236008+++++ Chlorobenzene AveCBNZd 5 16912 33109 63593 154308 301788 0.500 1.00 2.00 5.00 10.0 1560831 200100+++++50.065913183122826+++++ 1,1,1,2-Tetrachloroethane AveCBNZd 5 3836 6756 16231 37520 83247 0.500 1.00 2.00 5.00 10.0 461098 200100+++++50.02153086963014+++++ Ethylbenzene AveCBNZd 5 9971 18480 36428 83747 174081 0.500 1.00 2.00 5.00 10.0 897939 200100+++++50.038744021771535+++++ m-Xylene & p-Xylene AveCBNZd5 9708 21254 43447 104454 208544 0.500 1.00 2.00 5.00 10.0 1092598 200100+++++50.046596532188163+++++ o-Xylene AveCBNZd 5 11251 22322 40615 99571 197751 0.500 1.00 2.00 5.00 10.0 1046821 200100+++++50.044893392096540+++++ Styrene AveCBNZd 5 19244 32217 66406 160657 327877 0.500 1.00 2.00 5.00 10.0 1743096 200100+++++50.074359473495681+++++ Bromoform Lin1CBNZd 5 +++++ 3535 9159 20236 46803 +++++ 1.00 2.00 5.00 10.0 296685 200100+++++50.01516749649299+++++ Isopropylbenzene AveDCBd4 25431 47731 90183 232684 468045 0.500 1.00 2.00 5.00 10.0 2446218 200100+++++50.098866314785338+++++ Cyclohexanone AveCBNZd 5 39031 78082 159917 409862 781509 15.0 30.0 60.0 150 300 FORM VI 8260D Page 177 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 GC Column:DB-624 (60.25)ID:0.25(mm) ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 4029647 60003000+++++1500157237548129722+++++ 1,1,2,2-Tetrachloroethane AveDCBd4 9624 15801 36137 86428 171114 0.500 1.00 2.00 5.00 10.0 890635 200100+++++50.038018661787481+++++ Bromobenzene AveDCBd4 7290 12025 26560 58967 117670 0.500 1.00 2.00 5.00 10.0 630051 200100+++++50.027207121252929+++++ trans-1,4-Dichloro-2-butene Lin1DCBd4 +++++ 2684 5234 14010 27028 +++++ 1.00 2.00 5.00 10.0 182061 200100+++++50.0932630398512+++++ 1,2,3-Trichloropropane Lin1DCBd4 4232 5638 12817 31039 61818 0.500 1.00 2.00 5.00 10.0 304728 200100+++++50.01323861613670+++++ N-Propylbenzene AveDCBd4 8266 15254 30901 70519 139926 0.500 1.00 2.00 5.00 10.0 731525 200100+++++50.031107251449197+++++ 2-Chlorotoluene AveDCBd4 5779 12675 25153 58089 117483 0.500 1.00 2.00 5.00 10.0 601213 200100+++++50.026137611226402+++++ 1,3,5-Trimethylbenzene AveDCBd4 22018 39214 83385 210696 393585 0.500 1.00 2.00 5.00 10.0 2126921 200100+++++50.087788834252206+++++ 4-Chlorotoluene AveDCBd4 7462 13959 26163 58483 125991 0.500 1.00 2.00 5.00 10.0 631775 200100+++++50.027229931260625+++++ tert-Butylbenzene AveDCBd4 18695 37698 72038 177516 340086 0.500 1.00 2.00 5.00 10.0 1823592 200100+++++50.074942293637719+++++ 1,2,4-Trimethylbenzene AveDCBd4 23779 41069 87981 210352 419840 0.500 1.00 2.00 5.00 10.0 2200373 200100+++++50.089934504407492+++++ sec-Butylbenzene AveDCBd4 5748 8956 22540 50642 96000 0.500 1.00 2.00 5.00 10.0 529144 200100+++++50.022597151076675+++++ 1,3-Dichlorobenzene AveDCBd4 13572 22525 49027 113112 226828 0.500 1.00 2.00 5.00 10.0 1180044 200100+++++50.050346502362874+++++ 4-Isopropyltoluene AveDCBd4 23531 42420 90201 217036 427464 0.500 1.00 2.00 5.00 10.0 2294227 200100+++++50.093694104526107+++++ 1,4-Dichlorobenzene AveDCBd4 13387 25562 51364 110350 227193 0.500 1.00 2.00 5.00 10.0 1204795 200100+++++50.051160312408028+++++ n-Butylbenzene AveDCBd4 20885 39341 80036 186814 375440 0.500 1.00 2.00 5.00 10.0 2000610 200100+++++50.082880213970595+++++ 1,2-Dichlorobenzene AveDCBd4 12547 22330 47150 108172 215226 0.500 1.00 2.00 5.00 10.0 1131447 200100+++++50.048244512256498+++++ 1,2-Dibromo-3-Chloropropane AveDCBd4 2167 4015 9185 22234 43980 0.500 1.00 2.00 5.00 10.0 262646 200100+++++50.01296669570634+++++ 1,2,4-Trichlorobenzene AveDCBd4 7685 13116 22936 61157 117545 0.500 1.00 2.00 5.00 10.0 639544 200100+++++50.027527011297322+++++ Hexachlorobutadiene AveDCBd4 2022 4269 9112 22190 44086 0.500 1.00 2.00 5.00 10.0 235764 200100+++++50.01004045454683+++++ Naphthalene AveDCBd4 26872 48194 102792 241232 468238 0.500 1.00 2.00 5.00 10.0 2552766 200100+++++50.0108075315246284+++++ FORM VI 8260D Page 178 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98209Calibration Start Date:Calibration End Date:10/16/2024 00:19 N 10/16/2024 03:11 GC Column:DB-624 (60.25)ID:0.25(mm) ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 1,2,3-Trichlorobenzene AveDCBd4 5493 11212 23775 56164 106271 0.500 1.00 2.00 5.00 10.0 587335 200100+++++50.025451911200497+++++ Dibromofluoromethane (Surr)AveFB 609632 634242 624583 635327 635408 50.0 50.0 50.0 50.0 50.0 668830 50.050.0+++++50.0722066703286+++++ 1,2-Dichloroethane-d4 (Surr)AveFB 682613 716422 680215 689234 679879 50.0 50.0 50.0 50.0 50.0 729997 50.050.0+++++50.0786414756124+++++ Toluene-d8 (Surr)AveCBNZd 5 2788266 2821292 2784118 2801437 2803410 50.0 50.0 50.0 50.0 50.0 2905213 50.050.0+++++50.031713753075542+++++ 4-Bromofluorobenzene (Surr)AveDCBd4 949953 960012 952853 959805 964518 50.0 50.0 50.0 50.0 50.0 1000057 50.050.0+++++50.010769881045855+++++ Curve Type Legend: Ave = Average ISTD Lin1 = Linear 1/conc ISTDLin2 = Linear 1/conc^2 ISTD FORM VI 8260D Page 179 of 426 Report Date: 16-Oct-2024 07:40:49 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0297.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 1 Inject. Date: 16-Oct-2024 00:19:30 ALS Bottle#: 2 Worklist Smp#: 13 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 1 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:40:48 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:09:06 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2819067 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 647719 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.045 11.059 -0.014 96 1011286 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 609632 50.0 48.3 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 682613 50.0 49.4 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 2788266 50.0 50.4 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 88 949953 50.0 50.6 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 6905 0.5000 0.5604 10 Chloromethane 50 2.008 2.009 -0.001 99 7498 0.5000 0.5873 11 Vinyl chloride 62 2.134 2.134 0.000 95 5774 0.5000 0.4955 13 Bromomethane 94 2.483 2.483 0.000 86 6738 0.5000 0.3998 14 Chloroethane 64 2.609 2.609 0.000 95 4095 0.5000 0.5113 M 15 Dichlorofluoromethane 67 2.846 2.847 -0.001 96 11058 0.5000 0.5601 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 94 7428 0.5000 0.5134 18 Ethyl ether 59 3.168 3.168 0.000 84 5187 0.5000 0.5497 20 Acrolein 56 3.307 3.307 0.000 96 12518 4.94 6.17 22 1,1-Dichloroethene 96 3.405 3.405 0.000 96 5567 0.5000 0.5633 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 67 4365 0.5000 0.5884 23 Acetone 43 3.447 3.447 0.000 99 49096 2.00 1.96 24 Iodomethane 142 3.559 3.559 0.000 96 9274 0.5000 0.7461 26 Carbon disulfide 76 3.629 3.629 0.000 95 14730 0.5000 0.5485 28 Methyl acetate 43 3.740 3.740 0.000 96 16808 1.00 1.03 29 3-Chloro-1-propene 41 3.726 3.754 -0.028 72 26637 0.5000 0.5057 30 Methylene Chloride 84 3.880 3.880 0.000 85 9832 0.5000 0.5046 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 99 35229 5.00 5.45 32 Acrylonitrile 53 4.103 4.104 -0.001 95 43602 5.00 5.09 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 80 16336 0.5000 0.4944 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 91 5942 0.5000 0.5468 36 Hexane 57 4.383 4.383 0.000 83 8246 0.5000 0.5912 38 Vinyl acetate 43 4.522 4.523 -0.001 96 26530 1.00 1.26 39 1,1-Dichloroethane 63 4.536 4.537 0.000 91 9617 0.5000 0.5199 Page 180 of 426 Report Date: 16-Oct-2024 07:40:49 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0297.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 38979 2.00 2.62 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 5810 0.5000 0.4737 46 2,2-Dichloropropane 77 5.039 5.039 0.000 61 4916 0.5000 0.4142 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 97 58290 12.0 12.8 52 Tetrahydrofuran 42 5.249 5.249 0.000 86 9111 1.00 0.9772 M 51 Chlorobromomethane 128 5.235 5.249 -0.014 88 3524 0.5000 0.6304 53 Chloroform 83 5.318 5.319 -0.001 90 10063 0.5000 0.5611 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 35 7022 0.5000 0.5062 57 Cyclohexane 56 5.542 5.542 0.000 89 9693 0.5000 0.5403 59 Carbon tetrachloride 117 5.612 5.612 0.000 79 4855 0.5000 0.4753 58 1,1-Dichloropropene 75 5.612 5.612 0.000 93 7034 0.5000 0.4698 60 Isobutyl alcohol 41 5.751 5.668 0.083 29 1106 12.5 11.3 61 Benzene 78 5.779 5.780 -0.001 90 25383 0.5000 0.5449 62 1,2-Dichloroethane 62 5.821 5.821 0.000 95 8490 0.5000 0.6075 64 n-Heptane 43 6.003 6.003 0.000 71 6308 0.5000 0.5669 66 Trichloroethene 95 6.338 6.338 0.000 93 5467 0.5000 0.4962 67 2-Pentanone 43 6.478 6.478 0.000 98 36913 1.60 1.77 68 Methylcyclohexane 55 6.561 6.548 0.013 91 8799 0.5000 0.6380 69 1,2-Dichloropropane 63 6.575 6.576 -0.001 88 5823 0.5000 0.5402 71 1,4-Dioxane 88 6.631 6.631 0.000 91 6503 10.0 10.4 72 Dibromomethane 93 6.645 6.645 0.000 86 3960 0.5000 0.5829 73 Dichlorobromomethane 83 6.799 6.799 0.000 92 5872 0.5000 0.5115 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 82 2131 0.5000 0.5910 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 96 7132 0.5000 0.4868 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 94 41407 2.00 2.11 80 Toluene 91 7.483 7.483 0.000 98 28241 0.5000 0.5691 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 83 5307 0.5000 0.4335 84 Ethyl methacrylate 69 7.707 7.707 0.000 90 9309 0.5000 0.5314 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 87 6153 0.5000 0.5776 89 Tetrachloroethene 164 7.958 7.958 0.000 92 5080 0.5000 0.5808 90 1,3-Dichloropropane 76 8.014 8.014 0.000 83 10276 0.5000 0.5657 91 2-Hexanone 43 8.042 8.042 0.000 93 36069 2.00 2.10 93 Chlorodibromomethane 129 8.223 8.224 -0.001 93 3175 0.5000 0.4043 95 Ethylene Dibromide 107 8.349 8.349 0.000 96 5987 0.5000 0.5527 96 1-Chlorohexane 91 8.754 8.754 0.000 33 18312 0.4000 1.17 97 Chlorobenzene 112 8.796 8.796 0.000 93 16912 0.5000 0.5534 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 3836 0.5000 0.4739 98 Ethylbenzene 106 8.880 8.880 0.000 97 9971 0.5000 0.5711 100 m-Xylene & p-Xylene 106 8.992 9.006 -0.014 0 9708 0.5000 0.4744 101 o-Xylene 106 9.369 9.369 0.000 94 11251 0.5000 0.5558 103 Styrene 104 9.383 9.383 0.000 94 19244 0.5000 0.5832 104 Bromoform 173 9.578 9.578 0.000 91 2062 0.5000 1.10 105 Isopropylbenzene 105 9.718 9.718 0.000 94 25431 0.5000 0.5580 107 Cyclohexanone 55 9.830 9.830 0.000 91 39031 15.0 15.4 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 96 9624 0.5000 0.5692 109 Bromobenzene 156 10.053 10.053 0.000 90 7290 0.5000 0.5998 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 41 1668 0.5000 1.13 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 4232 0.5000 0.5374 112 N-Propylbenzene 120 10.123 10.137 -0.014 98 8266 0.5000 0.5787 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 5779 0.5000 0.4986 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 93 22018 0.5000 0.5522 115 4-Chlorotoluene 126 10.360 10.346 0.014 96 7462 0.5000 0.5964 Page 181 of 426 Report Date: 16-Oct-2024 07:40:49 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0297.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 89 18695 0.5000 0.5403 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 23779 0.5000 0.5716 118 sec-Butylbenzene 134 10.849 10.849 0.000 94 5748 0.5000 0.5750 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 95 13572 0.5000 0.5945 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 23531 0.5000 0.5517 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 89 13387 0.5000 0.5724 124 n-Butylbenzene 91 11.394 11.408 -0.014 96 20885 0.5000 0.5537 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 97 12547 0.5000 0.5749 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 85 2167 0.5000 0.4682 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 90 7685 0.5000 0.6248 129 Hexachlorobutadiene 225 13.195 13.196 -0.001 83 2022 0.5000 0.4733 130 Naphthalene 128 13.335 13.335 0.000 96 26872 0.5000 0.5571 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 90 5493 0.5000 0.5007 S 147 1,2-Dichloroethene, Total (URS) 96 0 1.00 1.02 S 148 Xylenes, Total 106 0 1.00 1.03 S 150 Xylenes, Total (URS) 1 0 1.00 1.03 S 151 Total BTEX 1 0 2.72 S 152 Trihalomethanes, Total 1 0 2.00 2.57 S 153 1,2-Dichloroethene, Total 1 0 1.00 1.02 S 154 1,3-Dichloropropene, Total 1 0 1.00 0.9203 QC Flag Legend Processing Flags Review Flags M - Manually Integrated Reagents: Cal Dil Std_00422 Amount Added: 5.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 182 of 426 Report Date: 16-Oct-2024 07:40:49 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0297.D Injection Date: 16-Oct-2024 00:19:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 13 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 2 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0297[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 8 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 4 7 )+ C a r b o n dis u l f i de( 3 . 6 2 9 )+ 3 - C h l o r o - 1 - p r o p e n e ( 3 . 7 5 4 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 )+ A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 5 4 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) Tol u e n e ( 7 . 5 1 1 ) t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 3 5 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 1 6 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) 1 ,2,3- Tri c h l o r o p r o p a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Trim e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 5 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 183 of 426 Report Date: 16-Oct-2024 07:40:49 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0297.D Injection Date: 16-Oct-2024 00:19:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 2 Worklist Smp#: 13 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 14 Chloroethane, CAS: 75-00-3 Signal: 1 Processing Integration Results RT: 2.61 Area: 5613 Amount: 0.500000 Amount Units: ug/l 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Y ( X10 0 ) m/z 64.0 2 . 6 0 9 Manual Integration Results RT: 2.61 Area: 4095 Amount: 0.511326 Amount Units: ug/l 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 Min RT 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Y ( X10 0 ) m/z 64.0 2 . 6 0 9 Reviewer: AF7X, 16-Oct-2024 07:07:16 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Baseline Page 184 of 426 Report Date: 16-Oct-2024 07:40:49 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0297.D Injection Date: 16-Oct-2024 00:19:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 2 Worklist Smp#: 13 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 52 Tetrahydrofuran, CAS: 109-99-9 Signal: 1 Processing Integration Results RT: 5.25 Area: 11217 Amount: 1.000000 Amount Units: ug/l 4.9 5.1 5.3 5.5 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 Y ( X10 0 ) m/z 42.0 5 . 2 4 9 Manual Integration Results RT: 5.25 Area: 9111 Amount: 0.977210 Amount Units: ug/l 4.9 5.1 5.3 5.5 Min RT 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 Y ( X10 0 ) m/z 42.0 5 . 2 4 9 Reviewer: AF7X, 16-Oct-2024 07:07:37 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Baseline Page 185 of 426 Report Date: 16-Oct-2024 07:40:52 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0298.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 2 Inject. Date: 16-Oct-2024 00:40:30 ALS Bottle#: 3 Worklist Smp#: 40 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 2 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:40:51 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:10:05 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2846226 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 667791 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1042842 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 634242 50.0 49.8 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 716422 50.0 51.4 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 2821292 50.0 49.5 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 89 960012 50.0 49.6 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 98 13272 1.00 1.07 10 Chloromethane 50 2.008 2.009 -0.001 97 14285 1.00 1.11 11 Vinyl chloride 62 2.134 2.134 0.000 97 11843 1.00 1.01 13 Bromomethane 94 2.483 2.483 0.000 93 12622 1.00 1.23 14 Chloroethane 64 2.609 2.609 0.000 97 9996 1.00 1.24 15 Dichlorofluoromethane 67 2.846 2.847 -0.001 96 21181 1.00 1.06 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 97 17135 1.00 1.17 18 Ethyl ether 59 3.168 3.168 0.000 87 10674 1.00 1.12 20 Acrolein 56 3.307 3.307 0.000 97 20061 9.88 9.79 22 1,1-Dichloroethene 96 3.405 3.405 0.000 97 10030 1.00 1.01 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 88 7912 1.00 1.06 23 Acetone 43 3.447 3.447 0.000 99 67721 4.00 4.08 24 Iodomethane 142 3.559 3.559 0.000 95 12422 1.00 1.01 26 Carbon disulfide 76 3.615 3.629 -0.014 99 27821 1.00 1.03 28 Methyl acetate 43 3.740 3.740 0.000 96 34937 2.00 2.13 29 3-Chloro-1-propene 41 3.726 3.754 -0.028 62 32289 1.00 0.9612 30 Methylene Chloride 84 3.880 3.880 0.000 88 15115 1.00 0.9797 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 99 64306 10.0 9.86 32 Acrylonitrile 53 4.103 4.104 -0.001 98 90015 10.0 10.4 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 92 35985 1.00 1.08 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 98 10023 1.00 0.9135 36 Hexane 57 4.383 4.383 0.000 90 14062 1.00 0.9779 38 Vinyl acetate 43 4.522 4.523 -0.001 97 42850 2.00 2.01 39 1,1-Dichloroethane 63 4.536 4.537 0.000 95 20178 1.00 1.08 Page 186 of 426 Report Date: 16-Oct-2024 07:40:52 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0298.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 59826 4.00 3.98 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 76 13738 1.00 1.11 46 2,2-Dichloropropane 77 5.039 5.039 0.000 58 12065 1.00 1.01 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 97786 24.0 21.3 52 Tetrahydrofuran 42 5.249 5.249 0.000 85 20802 2.00 2.21 51 Chlorobromomethane 128 5.235 5.249 -0.014 91 6570 1.00 1.16 53 Chloroform 83 5.318 5.319 -0.001 93 18504 1.00 1.02 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 97 13979 1.00 1.00 57 Cyclohexane 56 5.542 5.542 0.000 89 18757 1.00 1.04 59 Carbon tetrachloride 117 5.612 5.612 0.000 70 10554 1.00 1.02 58 1,1-Dichloropropene 75 5.612 5.612 0.000 94 17522 1.00 1.16 60 Isobutyl alcohol 41 5.654 5.668 -0.014 94 33508 25.0 29.0 M 61 Benzene 78 5.779 5.780 -0.001 90 51023 1.00 1.08 62 1,2-Dichloroethane 62 5.821 5.821 0.000 98 14528 1.00 1.03 64 n-Heptane 43 6.003 6.003 0.000 77 11832 1.00 1.05 66 Trichloroethene 95 6.338 6.338 0.000 96 11561 1.00 1.02 67 2-Pentanone 43 6.478 6.478 0.000 97 67022 3.20 3.18 68 Methylcyclohexane 55 6.548 6.548 0.000 90 13900 1.00 1.00 69 1,2-Dichloropropane 63 6.575 6.576 -0.001 91 11050 1.00 1.02 71 1,4-Dioxane 88 6.631 6.631 0.000 86 13008 20.0 20.6 72 Dibromomethane 93 6.659 6.645 0.014 94 7416 1.00 1.08 73 Dichlorobromomethane 83 6.799 6.799 0.000 95 10924 1.00 0.9425 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 78 3865 1.00 1.06 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 94 14474 1.00 0.9583 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 94 77316 4.00 3.90 80 Toluene 91 7.483 7.483 0.000 99 50580 1.00 1.01 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 95 10046 1.00 0.8127 84 Ethyl methacrylate 69 7.707 7.707 0.000 86 18842 1.00 1.04 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 88 10510 1.00 0.9772 89 Tetrachloroethene 164 7.958 7.958 0.000 94 9569 1.00 1.06 90 1,3-Dichloropropane 76 8.014 8.014 0.000 86 19107 1.00 1.02 91 2-Hexanone 43 8.042 8.042 0.000 94 72561 4.00 4.10 93 Chlorodibromomethane 129 8.223 8.224 -0.001 85 7112 1.00 0.8785 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 10478 1.00 0.9382 96 1-Chlorohexane 91 8.754 8.754 0.000 71 14783 0.8000 0.9159 97 Chlorobenzene 112 8.796 8.796 0.000 98 33109 1.00 1.05 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 40 6756 1.00 0.8096 98 Ethylbenzene 106 8.880 8.880 0.000 97 18480 1.00 1.03 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 21254 1.00 1.01 101 o-Xylene 106 9.369 9.369 0.000 95 22322 1.00 1.07 103 Styrene 104 9.383 9.383 0.000 94 32217 1.00 0.9470 104 Bromoform 173 9.578 9.578 0.000 88 3535 1.00 1.32 105 Isopropylbenzene 105 9.718 9.718 0.000 95 47731 1.00 1.02 107 Cyclohexanone 55 9.830 9.830 0.000 90 78082 30.0 29.8 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 94 15801 1.00 0.9063 109 Bromobenzene 156 10.053 10.053 0.000 92 12025 1.00 0.9594 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 42 2684 1.00 1.38 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 82 5638 1.00 0.7590 112 N-Propylbenzene 120 10.123 10.137 -0.014 98 15254 1.00 1.04 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 12675 1.00 1.06 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 94 39214 1.00 0.9537 115 4-Chlorotoluene 126 10.346 10.346 0.000 95 13959 1.00 1.08 Page 187 of 426 Report Date: 16-Oct-2024 07:40:52 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0298.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 37698 1.00 1.06 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 41069 1.00 0.9573 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 8956 1.00 0.8688 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 95 22525 1.00 0.9568 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 42420 1.00 0.9645 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 90 25562 1.00 1.06 124 n-Butylbenzene 91 11.408 11.408 0.000 98 39341 1.00 1.01 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 95 22330 1.00 0.99 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 81 4015 1.00 0.8412 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 90 13116 1.00 1.03 129 Hexachlorobutadiene 225 13.195 13.196 -0.001 91 4269 1.00 0.9689 130 Naphthalene 128 13.321 13.335 -0.014 96 48194 1.00 0.9688 132 1,2,3-Trichlorobenzene 180 13.545 13.559 -0.014 95 11212 1.00 0.99 S 147 1,2-Dichloroethene, Total (URS) 96 0 2.00 2.02 S 148 Xylenes, Total 106 0 2.00 2.08 S 150 Xylenes, Total (URS) 1 0 2.00 2.08 S 151 Total BTEX 1 0 5.20 S 152 Trihalomethanes, Total 1 0 4.00 4.16 S 153 1,2-Dichloroethene, Total 1 0 2.00 2.02 S 154 1,3-Dichloropropene, Total 1 0 2.00 1.77 QC Flag Legend Processing Flags Review Flags M - Manually Integrated Reagents: Cal Dil Std_00422 Amount Added: 10.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 188 of 426 Report Date: 16-Oct-2024 07:40:52 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0298.D Injection Date: 16-Oct-2024 00:40:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 3 Worklist Smp#: 40 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 60 Isobutyl alcohol, CAS: 78-83-1 Signal: 1 Processing Integration Results Not Detected Expected RT: 5.67 5.3 5.5 5.7 5.9 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 41.0 Manual Integration Results RT: 5.65 Area: 33508 Amount: 29.000847 Amount Units: ug/l 5.3 5.5 5.7 5.9 Min RT 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 41.0 5 . 6 5 4 Reviewer: AF7X, 16-Oct-2024 07:09:37 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Assign Peak Page 189 of 426 Report Date: 16-Oct-2024 07:40:54 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0299.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 3 Inject. Date: 16-Oct-2024 01:02:30 ALS Bottle#: 4 Worklist Smp#: 41 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 3 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:40:54 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:10:51 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2813838 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 645929 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1011144 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 624583 50.0 49.6 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 680215 50.0 49.4 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 2784118 50.0 50.5 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 88 952853 50.0 50.7 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 98 22941 2.00 1.87 10 Chloromethane 50 2.008 2.009 -0.001 98 26332 2.00 2.07 11 Vinyl chloride 62 2.134 2.134 0.000 98 24223 2.00 2.08 13 Bromomethane 94 2.483 2.483 0.000 91 18673 2.00 2.12 14 Chloroethane 64 2.609 2.609 0.000 98 15866 2.00 1.98 15 Dichlorofluoromethane 67 2.846 2.847 -0.001 96 40893 2.00 2.08 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 96 30243 2.00 2.09 18 Ethyl ether 59 3.168 3.168 0.000 88 20191 2.00 2.14 20 Acrolein 56 3.307 3.307 0.000 98 41630 19.8 20.6 22 1,1-Dichloroethene 96 3.405 3.405 0.000 96 19515 2.00 1.98 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 82 14128 2.00 1.91 23 Acetone 43 3.447 3.447 0.000 99 101927 8.00 8.22 24 Iodomethane 142 3.559 3.559 0.000 98 21179 2.00 1.80 26 Carbon disulfide 76 3.629 3.629 0.000 100 51718 2.00 1.93 28 Methyl acetate 43 3.740 3.740 0.000 97 68817 4.00 4.24 29 3-Chloro-1-propene 41 3.754 3.754 0.000 90 45038 2.00 2.08 30 Methylene Chloride 84 3.880 3.880 0.000 86 25535 2.00 1.96 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 99 124590 20.0 19.3 32 Acrylonitrile 53 4.103 4.104 -0.001 98 182911 20.0 21.4 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 94 71124 2.00 2.16 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 98 21888 2.00 2.02 36 Hexane 57 4.383 4.383 0.000 92 25795 2.00 1.85 38 Vinyl acetate 43 4.522 4.523 -0.001 97 83960 4.00 3.99 39 1,1-Dichloroethane 63 4.536 4.537 0.000 96 38607 2.00 2.09 Page 190 of 426 Report Date: 16-Oct-2024 07:40:54 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0299.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 121362 8.00 8.17 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 78 27262 2.00 2.23 46 2,2-Dichloropropane 77 5.039 5.039 0.000 65 23351 2.00 1.97 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 97 215204 48.0 47.5 52 Tetrahydrofuran 42 5.249 5.249 0.000 85 38400 4.00 4.13 51 Chlorobromomethane 128 5.235 5.249 -0.014 91 11273 2.00 2.02 53 Chloroform 83 5.318 5.319 -0.001 89 35121 2.00 1.96 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 97 26569 2.00 1.92 57 Cyclohexane 56 5.542 5.542 0.000 86 35988 2.00 2.01 59 Carbon tetrachloride 117 5.612 5.612 0.000 70 18869 2.00 1.85 58 1,1-Dichloropropene 75 5.612 5.612 0.000 97 29662 2.00 1.98 60 Isobutyl alcohol 41 5.654 5.668 -0.014 91 77424 50.0 53.5 M 61 Benzene 78 5.779 5.780 -0.001 92 100376 2.00 2.16 62 1,2-Dichloroethane 62 5.821 5.821 0.000 98 30118 2.00 2.16 64 n-Heptane 43 6.003 6.003 0.000 89 21568 2.00 1.94 66 Trichloroethene 95 6.338 6.338 0.000 94 23516 2.00 2.14 67 2-Pentanone 43 6.478 6.478 0.000 98 136102 6.40 6.53 68 Methylcyclohexane 55 6.547 6.548 -0.001 91 28377 2.00 2.06 69 1,2-Dichloropropane 63 6.575 6.576 -0.001 94 22050 2.00 2.05 71 1,4-Dioxane 88 6.631 6.631 0.000 89 26214 40.0 41.9 72 Dibromomethane 93 6.659 6.645 0.014 94 13335 2.00 1.97 73 Dichlorobromomethane 83 6.799 6.799 0.000 98 22283 2.00 1.94 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 92 6573 2.00 1.83 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 96 28414 2.00 1.94 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 94 159714 8.00 8.15 80 Toluene 91 7.483 7.483 0.000 99 101031 2.00 2.04 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 22404 2.00 1.83 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 34442 2.00 1.97 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 88 20787 2.00 1.95 89 Tetrachloroethene 164 7.958 7.958 0.000 93 17246 2.00 1.98 90 1,3-Dichloropropane 76 8.014 8.014 0.000 88 37426 2.00 2.07 91 2-Hexanone 43 8.042 8.042 0.000 93 137275 8.00 8.01 93 Chlorodibromomethane 129 8.223 8.224 -0.001 88 15586 2.00 1.99 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 22003 2.00 2.04 96 1-Chlorohexane 91 8.754 8.754 0.000 92 28942 1.60 1.85 97 Chlorobenzene 112 8.796 8.796 0.000 98 63593 2.00 2.09 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 41 16231 2.00 2.01 98 Ethylbenzene 106 8.880 8.880 0.000 97 36428 2.00 2.09 100 m-Xylene & p-Xylene 106 8.992 9.006 -0.014 0 43447 2.00 2.13 101 o-Xylene 106 9.369 9.369 0.000 97 40615 2.00 2.01 103 Styrene 104 9.383 9.383 0.000 93 66406 2.00 2.02 104 Bromoform 173 9.578 9.578 0.000 95 9159 2.00 2.25 105 Isopropylbenzene 105 9.718 9.718 0.000 96 90183 2.00 1.98 107 Cyclohexanone 55 9.830 9.830 0.000 88 159917 60.0 63.1 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 94 36137 2.00 2.14 109 Bromobenzene 156 10.053 10.053 0.000 92 26560 2.00 2.19 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 58 5234 2.00 2.08 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 12817 2.00 2.08 112 N-Propylbenzene 120 10.137 10.137 0.000 98 30901 2.00 2.16 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 25153 2.00 2.17 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 94 83385 2.00 2.09 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 26163 2.00 2.09 Page 191 of 426 Report Date: 16-Oct-2024 07:40:54 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0299.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 72038 2.00 2.08 117 1,2,4-Trimethylbenzene 105 10.681 10.682 -0.001 96 87981 2.00 2.12 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 22540 2.00 2.26 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 97 49027 2.00 2.15 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 90201 2.00 2.12 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 92 51364 2.00 2.20 124 n-Butylbenzene 91 11.408 11.408 0.000 97 80036 2.00 2.12 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 47150 2.00 2.16 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 85 9185 2.00 1.98 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 22936 2.00 1.87 129 Hexachlorobutadiene 225 13.195 13.196 -0.001 95 9112 2.00 2.13 130 Naphthalene 128 13.335 13.335 0.000 96 102792 2.00 2.13 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 94 23775 2.00 2.17 S 147 1,2-Dichloroethene, Total (URS) 96 0 4.00 4.24 S 148 Xylenes, Total 106 0 4.00 4.14 S 150 Xylenes, Total (URS) 1 0 4.00 4.14 S 151 Total BTEX 1 0 10.4 S 152 Trihalomethanes, Total 1 0 8.00 8.14 S 153 1,2-Dichloroethene, Total 1 0 4.00 4.24 S 154 1,3-Dichloropropene, Total 1 0 4.00 3.78 QC Flag Legend Processing Flags Review Flags M - Manually Integrated Reagents: Cal Dil Std_00422 Amount Added: 20.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 192 of 426 Report Date: 16-Oct-2024 07:40:54 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0299.D Injection Date: 16-Oct-2024 01:02:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 41 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 4 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0299[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 8 ) V i n yl c h l o r i de( 2 . 1 7 6 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 4 7 )+ C a r b o n dis u l f i de( 3 . 6 2 9 )+ 3 - C h l o r o - 1 - p r o p e n e ( 3 . 7 5 4 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 )+ A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 5 4 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 )+ 1 ,2- D i c h l o r o e t h a n e ( 5 . 8 3 5 ) * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tric h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) Tol u e n e ( 7 . 5 1 1 ) t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 1 6 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) t r a n s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 )+ s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 1 8 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 2 1 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 193 of 426 Report Date: 16-Oct-2024 07:40:54 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0299.D Injection Date: 16-Oct-2024 01:02:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 4 Worklist Smp#: 41 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 60 Isobutyl alcohol, CAS: 78-83-1 Signal: 1 Processing Integration Results Not Detected Expected RT: 5.67 5.3 5.5 5.7 5.9 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 Y ( X10 0 0 ) m/z 41.0 Manual Integration Results RT: 5.65 Area: 77424 Amount: 53.474953 Amount Units: ug/l 5.3 5.5 5.7 5.9 Min RT 0 3 6 9 12 15 18 21 24 27 30 33 36 39 Y ( X10 0 0 ) m/z 41.0 5 . 6 5 4 Reviewer: AF7X, 16-Oct-2024 07:10:30 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Assign Peak Page 194 of 426 Report Date: 16-Oct-2024 07:40:56 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0300.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 4 Inject. Date: 16-Oct-2024 01:23:30 ALS Bottle#: 5 Worklist Smp#: 42 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 4 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:40:56 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:11:36 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2845130 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 653193 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1025819 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 635327 50.0 49.9 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 689234 50.0 49.5 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 2801437 50.0 50.2 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 88 959805 50.0 50.4 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 68579 5.00 5.51 10 Chloromethane 50 2.008 2.009 -0.001 99 63566 5.00 4.93 11 Vinyl chloride 62 2.134 2.134 0.000 97 64852 5.00 5.51 13 Bromomethane 94 2.483 2.483 0.000 90 39658 5.00 5.08 14 Chloroethane 64 2.609 2.609 0.000 99 43919 5.00 5.43 15 Dichlorofluoromethane 67 2.846 2.847 -0.001 97 106790 5.00 5.36 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 99 76287 5.00 5.22 18 Ethyl ether 59 3.168 3.168 0.000 89 47751 5.00 5.01 20 Acrolein 56 3.307 3.307 0.000 99 99411 49.4 48.6 22 1,1-Dichloroethene 96 3.405 3.405 0.000 98 49381 5.00 4.95 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 91 37200 5.00 4.97 23 Acetone 43 3.447 3.447 0.000 98 207043 20.0 20.4 24 Iodomethane 142 3.559 3.559 0.000 95 46878 5.00 4.04 26 Carbon disulfide 76 3.629 3.629 0.000 98 127757 5.00 4.71 28 Methyl acetate 43 3.740 3.740 0.000 97 161716 10.0 9.85 29 3-Chloro-1-propene 41 3.754 3.754 0.000 88 78128 5.00 4.83 30 Methylene Chloride 84 3.880 3.880 0.000 85 61975 5.00 5.27 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 99 326901 50.0 50.1 32 Acrylonitrile 53 4.103 4.104 -0.001 99 437289 50.0 50.6 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 95 157635 5.00 4.73 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 99 55755 5.00 5.08 36 Hexane 57 4.383 4.383 0.000 86 75261 5.00 5.35 38 Vinyl acetate 43 4.522 4.523 -0.001 97 205928 10.0 9.67 39 1,1-Dichloroethane 63 4.536 4.537 0.000 96 94382 5.00 5.06 Page 195 of 426 Report Date: 16-Oct-2024 07:40:56 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0300.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 293460 20.0 19.5 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 60421 5.00 4.88 46 2,2-Dichloropropane 77 5.039 5.039 0.000 89 59133 5.00 4.94 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 568654 120.0 124.2 52 Tetrahydrofuran 42 5.249 5.249 0.000 86 93636 10.0 9.95 51 Chlorobromomethane 128 5.249 5.249 0.000 91 26661 5.00 4.73 53 Chloroform 83 5.318 5.319 -0.001 93 91931 5.00 5.08 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 97 68903 5.00 4.92 57 Cyclohexane 56 5.542 5.542 0.000 87 89610 5.00 4.95 59 Carbon tetrachloride 117 5.612 5.612 0.000 72 48593 5.00 4.71 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 77760 5.00 5.15 60 Isobutyl alcohol 41 5.654 5.668 -0.014 95 217042 125.0 129.3 M 61 Benzene 78 5.779 5.780 -0.001 95 226940 5.00 4.83 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 69929 5.00 4.96 64 n-Heptane 43 6.003 6.003 0.000 84 53507 5.00 4.76 66 Trichloroethene 95 6.338 6.338 0.000 98 56307 5.00 5.07 67 2-Pentanone 43 6.478 6.478 0.000 98 342083 16.0 16.2 68 Methylcyclohexane 55 6.548 6.548 0.000 87 66940 5.00 4.81 69 1,2-Dichloropropane 63 6.575 6.576 -0.001 97 51933 5.00 4.77 71 1,4-Dioxane 88 6.631 6.631 0.000 91 64759 100.0 102.4 72 Dibromomethane 93 6.645 6.645 0.000 97 31244 5.00 4.56 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 54597 5.00 4.71 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 91 17058 5.00 4.69 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 67996 5.00 4.60 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 94 410478 20.0 20.7 80 Toluene 91 7.483 7.483 0.000 98 252872 5.00 5.05 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 58104 5.00 4.70 84 Ethyl methacrylate 69 7.707 7.707 0.000 88 86037 5.00 4.87 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 87 53350 5.00 4.96 89 Tetrachloroethene 164 7.958 7.958 0.000 97 42851 5.00 4.86 90 1,3-Dichloropropane 76 8.014 8.014 0.000 87 91036 5.00 4.97 91 2-Hexanone 43 8.042 8.042 0.000 94 370944 20.0 21.4 93 Chlorodibromomethane 129 8.223 8.224 -0.001 90 35503 5.00 4.48 95 Ethylene Dibromide 107 8.349 8.349 0.000 97 52186 5.00 4.78 96 1-Chlorohexane 91 8.754 8.754 0.000 92 62777 4.00 3.98 97 Chlorobenzene 112 8.796 8.796 0.000 96 154308 5.00 5.01 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 41 37520 5.00 4.60 98 Ethylbenzene 106 8.880 8.880 0.000 98 83747 5.00 4.76 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 104454 5.00 5.06 101 o-Xylene 106 9.369 9.369 0.000 95 99571 5.00 4.88 103 Styrene 104 9.383 9.383 0.000 94 160657 5.00 4.83 104 Bromoform 173 9.578 9.578 0.000 95 20236 5.00 4.00 105 Isopropylbenzene 105 9.718 9.718 0.000 95 232684 5.00 5.03 107 Cyclohexanone 55 9.830 9.830 0.000 89 409862 150.0 159.8 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 94 86428 5.00 5.04 109 Bromobenzene 156 10.053 10.053 0.000 94 58967 5.00 4.78 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 73 14010 5.00 4.37 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 31039 5.00 5.27 112 N-Propylbenzene 120 10.137 10.137 0.000 98 70519 5.00 4.87 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 58089 5.00 4.94 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 93 210696 5.00 5.21 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 58483 5.00 4.61 Page 196 of 426 Report Date: 16-Oct-2024 07:40:56 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0300.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 177516 5.00 5.06 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 210352 5.00 4.98 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 50642 5.00 4.99 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 97 113112 5.00 4.88 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 217036 5.00 5.02 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 110350 5.00 4.65 124 n-Butylbenzene 91 11.408 11.408 0.000 97 186814 5.00 4.88 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 108172 5.00 4.89 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 85 22234 5.00 4.74 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 61157 5.00 4.90 129 Hexachlorobutadiene 225 13.195 13.196 -0.001 96 22190 5.00 5.12 130 Naphthalene 128 13.335 13.335 0.000 97 241232 5.00 4.93 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 97 56164 5.00 5.05 S 147 1,2-Dichloroethene, Total (URS) 96 0 10.0 9.96 S 148 Xylenes, Total 106 0 10.0 9.94 S 150 Xylenes, Total (URS) 1 0 10.0 9.94 S 151 Total BTEX 1 0 24.6 S 152 Trihalomethanes, Total 1 0 20.0 18.3 S 153 1,2-Dichloroethene, Total 1 0 10.0 9.96 S 154 1,3-Dichloropropene, Total 1 0 10.0 9.30 QC Flag Legend Processing Flags Review Flags M - Manually Integrated Reagents: MV-MegaMainA_00115 Amount Added: 2.50 Units: uL MV-Gas A_00198 Amount Added: 1.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 197 of 426 Report Date: 16-Oct-2024 07:40:56 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0300.D Injection Date: 16-Oct-2024 01:23:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 42 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 5 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0300[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 8 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ C a r b o n dis u l f i de( 3 . 6 2 9 )+ 3 - C h l o r o - 1 - p r o p e n e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 8 6 6 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 ) A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 5 4 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 1 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tric h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) Tol u e n e ( 7 . 5 1 1 ) t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 1 6 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) 1 ,1,2,2- Tet r a c h l o r o e t h a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 5 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 2 1 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 198 of 426 Report Date: 16-Oct-2024 07:40:56 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0300.D Injection Date: 16-Oct-2024 01:23:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 5 Worklist Smp#: 42 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 60 Isobutyl alcohol, CAS: 78-83-1 Signal: 1 Processing Integration Results Not Detected Expected RT: 5.67 5.3 5.5 5.7 5.9 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 ) m/z 41.0 Manual Integration Results RT: 5.65 Area: 217042 Amount: 129.2945 Amount Units: ug/l 5.3 5.5 5.7 5.9 Min RT 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 ) m/z 41.0 5 . 6 5 4 Reviewer: AF7X, 16-Oct-2024 07:11:15 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Assign Peak Page 199 of 426 Report Date: 16-Oct-2024 07:40:58 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0301.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 5 Inject. Date: 16-Oct-2024 01:45:30 ALS Bottle#: 6 Worklist Smp#: 43 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 5 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:40:58 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:12:30 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2845836 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 646263 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1015867 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 635408 50.0 49.9 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.752 0.000 0 679879 50.0 48.8 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 93 2803410 50.0 50.8 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 88 964518 50.0 51.1 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 102404 10.0 8.23 10 Chloromethane 50 2.009 2.009 0.000 99 102569 10.0 7.96 11 Vinyl chloride 62 2.134 2.134 0.000 98 97468 10.0 8.29 13 Bromomethane 94 2.483 2.483 0.000 89 65822 10.0 8.81 14 Chloroethane 64 2.609 2.609 0.000 98 60975 10.0 7.54 15 Dichlorofluoromethane 67 2.847 2.847 0.000 96 161417 10.0 8.10 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 98 117402 10.0 8.04 18 Ethyl ether 59 3.168 3.168 0.000 88 89432 10.0 9.39 20 Acrolein 56 3.307 3.307 0.000 100 190488 98.8 93.0 22 1,1-Dichloroethene 96 3.405 3.405 0.000 97 98461 10.0 9.87 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 93 77163 10.0 10.3 23 Acetone 43 3.447 3.447 0.000 100 374461 40.0 40.0 24 Iodomethane 142 3.559 3.559 0.000 97 90366 10.0 7.86 26 Carbon disulfide 76 3.629 3.629 0.000 98 258152 10.0 9.52 28 Methyl acetate 43 3.740 3.740 0.000 96 318679 20.0 19.4 29 3-Chloro-1-propene 41 3.754 3.754 0.000 91 140845 10.0 10.1 30 Methylene Chloride 84 3.880 3.880 0.000 85 114438 10.0 10.1 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 99 614546 100.0 94.3 32 Acrylonitrile 53 4.103 4.104 -0.001 99 901591 100.0 104.2 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 94 329435 10.0 9.88 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 96 112004 10.0 10.2 36 Hexane 57 4.383 4.383 0.000 88 139306 10.0 10.0 38 Vinyl acetate 43 4.522 4.523 -0.001 97 415210 20.0 19.5 39 1,1-Dichloroethane 63 4.536 4.537 0.000 96 182081 10.0 9.75 Page 200 of 426 Report Date: 16-Oct-2024 07:40:58 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0301.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 569181 40.0 37.9 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 80 119348 10.0 9.64 46 2,2-Dichloropropane 77 5.039 5.039 0.000 87 117989 10.0 9.85 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 1087796 240.0 237.5 52 Tetrahydrofuran 42 5.249 5.249 0.000 83 185047 20.0 19.7 51 Chlorobromomethane 128 5.235 5.249 -0.014 95 53071 10.0 9.41 53 Chloroform 83 5.319 5.319 0.000 92 171654 10.0 9.48 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 136859 10.0 9.77 57 Cyclohexane 56 5.542 5.542 0.000 86 183151 10.0 10.1 59 Carbon tetrachloride 117 5.612 5.612 0.000 73 97133 10.0 9.42 58 1,1-Dichloropropene 75 5.612 5.612 0.000 95 148203 10.0 9.81 60 Isobutyl alcohol 41 5.654 5.668 -0.014 95 390372 250.0 224.0 M 61 Benzene 78 5.779 5.780 -0.001 96 460127 10.0 9.78 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 133061 10.0 9.43 64 n-Heptane 43 6.003 6.003 0.000 90 107729 10.0 9.59 66 Trichloroethene 95 6.338 6.338 0.000 99 109639 10.0 9.97 67 2-Pentanone 43 6.478 6.478 0.000 98 661297 32.0 31.3 68 Methylcyclohexane 55 6.548 6.548 0.000 90 131038 10.0 9.41 69 1,2-Dichloropropane 63 6.576 6.576 0.000 97 106718 10.0 9.81 71 1,4-Dioxane 88 6.631 6.631 0.000 91 123608 200.0 195.4 72 Dibromomethane 93 6.659 6.645 0.014 98 66039 10.0 9.63 73 Dichlorobromomethane 83 6.799 6.799 0.000 98 111398 10.0 9.61 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 92 27864 10.0 7.65 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 97 141753 10.0 9.70 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 93 792010 40.0 40.0 80 Toluene 91 7.483 7.483 0.000 98 489813 10.0 9.78 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 91 121525 10.0 9.83 84 Ethyl methacrylate 69 7.707 7.707 0.000 88 167177 10.0 9.56 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 106399 10.0 9.89 89 Tetrachloroethene 164 7.958 7.958 0.000 96 84782 10.0 9.71 90 1,3-Dichloropropane 76 8.014 8.014 0.000 88 184288 10.0 10.2 91 2-Hexanone 43 8.042 8.042 0.000 93 697096 40.0 40.7 93 Chlorodibromomethane 129 8.224 8.224 0.000 89 76829 10.0 9.81 95 Ethylene Dibromide 107 8.349 8.349 0.000 97 107934 10.0 9.99 96 1-Chlorohexane 91 8.754 8.754 0.000 95 118732 8.00 7.60 97 Chlorobenzene 112 8.796 8.796 0.000 96 301788 10.0 9.90 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 83247 10.0 10.3 98 Ethylbenzene 106 8.880 8.880 0.000 97 174081 10.0 10.0 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 208544 10.0 10.2 101 o-Xylene 106 9.369 9.369 0.000 96 197751 10.0 9.79 103 Styrene 104 9.383 9.383 0.000 95 327877 10.0 9.96 104 Bromoform 173 9.578 9.578 0.000 95 46803 10.0 8.34 105 Isopropylbenzene 105 9.718 9.718 0.000 95 468045 10.0 10.2 107 Cyclohexanone 55 9.830 9.830 0.000 89 781509 300.0 308.1 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 171114 10.0 10.1 109 Bromobenzene 156 10.053 10.053 0.000 94 117670 10.0 9.64 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 75 27028 10.0 7.86 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 84 61818 10.0 10.8 112 N-Propylbenzene 120 10.137 10.137 0.000 98 139926 10.0 9.75 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 117483 10.0 10.1 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 94 393585 10.0 9.83 115 4-Chlorotoluene 126 10.346 10.346 0.000 97 125991 10.0 10.0 Page 201 of 426 Report Date: 16-Oct-2024 07:40:58 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0301.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 340086 10.0 9.78 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 97 419840 10.0 10.0 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 96000 10.0 9.56 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 226828 10.0 9.89 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 427464 10.0 9.98 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 227193 10.0 9.67 124 n-Butylbenzene 91 11.408 11.408 0.000 97 375440 10.0 9.91 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 215226 10.0 9.82 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 86 43980 10.0 9.46 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 93 117545 10.0 9.51 129 Hexachlorobutadiene 225 13.196 13.196 0.000 96 44086 10.0 10.3 130 Naphthalene 128 13.335 13.335 0.000 96 468238 10.0 9.66 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 95 106271 10.0 9.64 S 147 1,2-Dichloroethene, Total (URS) 96 0 20.0 19.8 S 148 Xylenes, Total 106 0 20.0 20.0 S 150 Xylenes, Total (URS) 1 0 20.0 20.0 S 151 Total BTEX 1 0 49.6 S 152 Trihalomethanes, Total 1 0 40.0 37.2 S 153 1,2-Dichloroethene, Total 1 0 20.0 19.8 S 154 1,3-Dichloropropene, Total 1 0 20.0 19.5 QC Flag Legend Processing Flags Review Flags M - Manually Integrated Reagents: MV-MegaMainA_00115 Amount Added: 5.00 Units: uL MV-Gas A_00198 Amount Added: 2.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 202 of 426 Report Date: 16-Oct-2024 07:40:59 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0301.D Injection Date: 16-Oct-2024 01:45:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 43 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 6 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0301[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 7 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ C a r b o n dis u l f i de( 3 . 6 2 9 )+ 3 - C h l o r o - 1 - p r o p e n e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 8 6 6 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 ) A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 3 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 5 4 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 2 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 2 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) Tol u e n e ( 7 . 5 1 1 ) t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tric h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 4 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 1 6 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) 1 ,1,2,2- Tet r a c h l o r o e t h a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tric h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 203 of 426 Report Date: 16-Oct-2024 07:40:59 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0301.D Injection Date: 16-Oct-2024 01:45:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 6 Worklist Smp#: 43 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 60 Isobutyl alcohol, CAS: 78-83-1 Signal: 1 Processing Integration Results RT: 5.79 Area: 5709 Amount: 6.002968 Amount Units: ug/l 5.3 5.5 5.7 5.9 6.1 Min 5 8 11 14 17 20 23 26 29 32 35 38 41 44 Y ( X10 0 ) m/z 41.0 5 . 7 9 3 Manual Integration Results RT: 5.65 Area: 390372 Amount: 223.9526 Amount Units: ug/l 5.3 5.5 5.7 5.9 6.1 Min RT 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 0 ) m/z 41.0 5 . 6 5 4 Reviewer: AF7X, 16-Oct-2024 07:12:07 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Assign Peak Page 204 of 426 Report Date: 16-Oct-2024 07:41:01 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0302.D Lims ID: icis Client ID: Sample Type: ICIS Calib Level: 6 Inject. Date: 16-Oct-2024 02:06:30 ALS Bottle#: 7 Worklist Smp#: 44 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 6 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:41:00 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:13:15 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2943416 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 691693 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1088110 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 668830 50.0 50.7 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.752 0.000 0 729997 50.0 50.6 $ 6 Toluene-d8 (Surr) 98 7.428 7.428 0.000 92 2905213 50.0 49.2 $ 7 4-Bromofluorobenzene (Surr) 95 9.900 9.900 0.000 88 1000057 50.0 49.5 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 667292 50.0 51.9 10 Chloromethane 50 2.009 2.009 0.000 99 674274 50.0 50.6 11 Vinyl chloride 62 2.134 2.134 0.000 97 653707 50.0 53.7 13 Bromomethane 94 2.483 2.483 0.000 89 370419 50.0 50.5 14 Chloroethane 64 2.609 2.609 0.000 99 427300 50.0 51.1 15 Dichlorofluoromethane 67 2.847 2.847 0.000 96 1046904 50.0 50.8 16 Trichlorofluoromethane 101 2.875 2.875 0.000 99 767195 50.0 50.8 18 Ethyl ether 59 3.168 3.168 0.000 88 468264 50.0 47.5 20 Acrolein 56 3.307 3.307 0.000 99 1000348 493.8 472.2 22 1,1-Dichloroethene 96 3.405 3.405 0.000 96 514322 50.0 49.8 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 92 372647 50.0 48.1 23 Acetone 43 3.447 3.447 0.000 99 1815204 200.0 201.4 24 Iodomethane 142 3.559 3.559 0.000 97 575280 50.0 48.7 26 Carbon disulfide 76 3.629 3.629 0.000 98 1421027 50.0 50.7 28 Methyl acetate 43 3.740 3.740 0.000 97 1697013 100.0 99.9 29 3-Chloro-1-propene 41 3.754 3.754 0.000 91 686399 50.0 54.3 30 Methylene Chloride 84 3.880 3.880 0.000 85 589274 50.0 51.8 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 99 3410387 500.0 505.7 32 Acrylonitrile 53 4.104 4.104 0.000 99 4521458 500.0 505.3 33 Methyl tert-butyl ether 73 4.118 4.118 0.000 94 1708327 50.0 49.5 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 96 575215 50.0 50.7 36 Hexane 57 4.383 4.383 0.000 88 738594 50.0 49.6 38 Vinyl acetate 43 4.523 4.523 0.000 97 2222342 100.0 100.9 39 1,1-Dichloroethane 63 4.537 4.537 0.000 96 947998 50.0 49.1 Page 205 of 426 Report Date: 16-Oct-2024 07:41:01 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0302.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 2983807 200.0 192.1 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 631733 50.0 49.3 46 2,2-Dichloropropane 77 5.039 5.039 0.000 86 657811 50.0 53.1 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 6036891 1200.0 1274.2 52 Tetrahydrofuran 42 5.249 5.249 0.000 84 967214 100.0 99.4 51 Chlorobromomethane 128 5.249 5.249 0.000 91 268742 50.0 46.0 53 Chloroform 83 5.319 5.319 0.000 92 933064 50.0 49.8 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 97 747850 50.0 51.6 57 Cyclohexane 56 5.542 5.542 0.000 87 932242 50.0 49.8 59 Carbon tetrachloride 117 5.612 5.612 0.000 75 558115 50.0 52.3 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 776177 50.0 49.7 60 Isobutyl alcohol 41 5.668 5.668 0.000 95 2332700 1250.0 1242.8 61 Benzene 78 5.780 5.780 0.000 95 2370146 50.0 48.7 62 1,2-Dichloroethane 62 5.821 5.821 0.000 98 685334 50.0 47.0 64 n-Heptane 43 6.003 6.003 0.000 89 580772 50.0 50.0 66 Trichloroethene 95 6.338 6.338 0.000 98 583331 50.0 49.6 67 2-Pentanone 43 6.478 6.478 0.000 98 3547526 160.0 162.6 68 Methylcyclohexane 55 6.548 6.548 0.000 89 694973 50.0 48.3 69 1,2-Dichloropropane 63 6.576 6.576 0.000 97 565257 50.0 50.2 71 1,4-Dioxane 88 6.631 6.631 0.000 89 647411 1000.0 989.6 72 Dibromomethane 93 6.645 6.645 0.000 97 342787 50.0 48.3 73 Dichlorobromomethane 83 6.799 6.799 0.000 100 616336 50.0 51.4 75 2-Chloroethyl vinyl ether 63 7.023 7.023 0.000 92 191285 50.0 50.8 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 97 818597 50.0 52.3 79 4-Methyl-2-pentanone (MIBK) 43 7.288 7.288 0.000 95 4217150 200.0 205.8 80 Toluene 91 7.483 7.483 0.000 98 2546571 50.0 49.2 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 89 720277 50.0 56.3 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 931899 50.0 49.8 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 549793 50.0 49.4 89 Tetrachloroethene 164 7.958 7.958 0.000 97 452597 50.0 48.5 90 1,3-Dichloropropane 76 8.014 8.014 0.000 96 927488 50.0 47.8 91 2-Hexanone 43 8.042 8.042 0.000 93 3636603 200.0 198.2 93 Chlorodibromomethane 129 8.224 8.224 0.000 89 459599 50.0 54.8 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 579533 50.0 50.1 96 1-Chlorohexane 91 8.754 8.754 0.000 94 629431 40.0 37.7 97 Chlorobenzene 112 8.796 8.796 0.000 95 1560831 50.0 47.8 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 461098 50.0 53.3 98 Ethylbenzene 106 8.880 8.880 0.000 97 897939 50.0 48.2 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 1092598 50.0 50.0 101 o-Xylene 106 9.369 9.369 0.000 96 1046821 50.0 48.4 103 Styrene 104 9.383 9.383 0.000 94 1743096 50.0 49.5 104 Bromoform 173 9.578 9.578 0.000 96 296685 50.0 45.6 105 Isopropylbenzene 105 9.718 9.718 0.000 95 2446218 50.0 49.9 107 Cyclohexanone 55 9.830 9.830 0.000 89 4029647 1500.0 1484.1 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 890635 50.0 49.0 109 Bromobenzene 156 10.053 10.053 0.000 95 630051 50.0 48.2 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 82 182061 50.0 45.8 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 304728 50.0 50.6 112 N-Propylbenzene 120 10.137 10.137 0.000 98 731525 50.0 47.6 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 601213 50.0 48.2 114 1,3,5-Trimethylbenzene 105 10.305 10.305 0.000 94 2126921 50.0 49.6 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 631775 50.0 46.9 Page 206 of 426 Report Date: 16-Oct-2024 07:41:01 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0302.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 1823592 50.0 49.0 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 97 2200373 50.0 49.2 118 sec-Butylbenzene 134 10.849 10.849 0.000 94 529144 50.0 49.2 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 1180044 50.0 48.0 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 2294227 50.0 50.0 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 1204795 50.0 47.9 124 n-Butylbenzene 91 11.408 11.408 0.000 97 2000610 50.0 49.3 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 99 1131447 50.0 48.2 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 88 262646 50.0 52.7 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 639544 50.0 48.3 129 Hexachlorobutadiene 225 13.196 13.196 0.000 97 235764 50.0 51.3 130 Naphthalene 128 13.335 13.335 0.000 96 2552766 50.0 49.2 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 96 587335 50.0 49.8 S 147 1,2-Dichloroethene, Total (URS) 96 0 100.0 100.0 S 148 Xylenes, Total 106 0 100.0 98.4 S 150 Xylenes, Total (URS) 1 0 100.0 98.4 S 152 Trihalomethanes, Total 1 0 200.0 201.7 S 153 1,2-Dichloroethene, Total 1 0 100.0 100.0 S 154 1,3-Dichloropropene, Total 1 0 100.0 108.7 QC Flag Legend Processing Flags Reagents: MV-MegaMainA_00115 Amount Added: 25.00 Units: uL MV-Gas A_00198 Amount Added: 10.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 207 of 426 Report Date: 16-Oct-2024 07:41:01 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0302.D Injection Date: 16-Oct-2024 02:06:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: icis Worklist Smp#: 44 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 7 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 Y ( X10 0 0 0 0 ) MS1_0302[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 7 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ C a r b o n dis u l f i de( 3 . 6 2 9 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 8 6 6 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 ) A c r ylo n i t r i l e ( 4 . 1 0 4 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 3 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 3 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 7 2 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 8 0 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 2 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 3 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 8 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 4 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 3 0 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 9 0 0 ) 1 ,1,2,2- Tet r a c h l o r o e t h a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Trim e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 208 of 426 Report Date: 16-Oct-2024 07:41:03 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0303.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 7 Inject. Date: 16-Oct-2024 02:28:30 ALS Bottle#: 8 Worklist Smp#: 45 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 7 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:41:02 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:13:59 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2963788 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 677932 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.058 11.059 -0.001 93 1093523 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 671201 50.0 50.6 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 723855 50.0 49.9 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 2947588 50.0 50.9 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 88 1017040 50.0 50.1 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 649853 75.0 50.2 10 Chloromethane 50 2.008 2.009 -0.001 99 623226 75.0 46.4 11 Vinyl chloride 62 2.134 2.134 0.000 97 621318 75.0 50.7 13 Bromomethane 94 2.483 2.483 0.000 88 414197 75.0 56.1 14 Chloroethane 64 2.609 2.609 0.000 99 403881 75.0 48.0 15 Dichlorofluoromethane 67 2.846 2.847 -0.001 96 997863 75.0 48.1 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 98 742639 75.0 48.8 18 Ethyl ether 59 3.168 3.168 0.000 87 700591 75.0 70.6 20 Acrolein 56 3.307 3.307 0.000 99 1552604 740.6 727.9 22 1,1-Dichloroethene 96 3.405 3.405 0.000 97 730598 75.0 70.3 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 92 510278 75.0 65.4 23 Acetone 43 3.447 3.447 0.000 99 2826706 300.0 313.5 24 Iodomethane 142 3.559 3.559 0.000 97 781882 75.0 65.8 26 Carbon disulfide 76 3.614 3.629 -0.015 99 2086919 75.0 73.9 28 Methyl acetate 43 3.740 3.740 0.000 97 2549494 150.0 149.0 29 3-Chloro-1-propene 41 3.754 3.754 0.000 90 977147 75.0 77.5 30 Methylene Chloride 84 3.880 3.880 0.000 86 851062 75.0 74.4 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 100 5429191 750.0 799.5 32 Acrylonitrile 53 4.103 4.104 -0.001 99 6886610 750.0 764.4 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 94 2594354 75.0 74.7 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 97 845062 75.0 74.0 36 Hexane 57 4.383 4.383 0.000 88 1014584 75.0 69.5 38 Vinyl acetate 43 4.522 4.523 -0.001 97 3204769 150.0 144.5 39 1,1-Dichloroethane 63 4.536 4.537 0.000 96 1401794 75.0 72.1 Page 209 of 426 Report Date: 16-Oct-2024 07:41:03 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0303.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 4532626 300.0 289.7 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 80 933626 75.0 72.4 46 2,2-Dichloropropane 77 5.039 5.039 0.000 93 978817 75.0 78.4 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 9549425 1800.0 2001.8 52 Tetrahydrofuran 42 5.249 5.249 0.000 85 1495388 150.0 152.6 51 Chlorobromomethane 128 5.249 5.249 0.000 92 400092 75.0 68.1 53 Chloroform 83 5.318 5.319 -0.001 93 1397569 75.0 74.1 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 1098886 75.0 75.4 57 Cyclohexane 56 5.542 5.542 0.000 86 1284369 75.0 68.1 59 Carbon tetrachloride 117 5.612 5.612 0.000 78 834066 75.0 77.7 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 1123028 75.0 71.3 60 Isobutyl alcohol 41 5.668 5.668 0.000 95 3709798 1875.0 1956.6 61 Benzene 78 5.779 5.780 -0.001 95 3442244 75.0 70.3 62 1,2-Dichloroethane 62 5.821 5.821 0.000 98 1022131 75.0 69.6 64 n-Heptane 43 6.003 6.003 0.000 89 849125 75.0 72.6 66 Trichloroethene 95 6.338 6.338 0.000 98 860224 75.0 74.6 67 2-Pentanone 43 6.478 6.478 0.000 97 5370269 240.0 244.5 68 Methylcyclohexane 55 6.547 6.548 -0.001 89 965366 75.0 66.6 69 1,2-Dichloropropane 63 6.575 6.576 -0.001 97 836375 75.0 73.8 71 1,4-Dioxane 88 6.631 6.631 0.000 91 1012757 1500.0 1537.5 72 Dibromomethane 93 6.659 6.645 0.014 97 521252 75.0 73.0 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 953036 75.0 79.0 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 91 190144 75.0 50.2 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 97 1268546 75.0 82.7 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 93 6366909 300.0 308.6 80 Toluene 91 7.483 7.483 0.000 98 3774918 75.0 72.4 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 1101401 75.0 85.6 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 1418695 75.0 77.4 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 810927 75.0 72.4 89 Tetrachloroethene 164 7.958 7.958 0.000 98 663455 75.0 72.5 90 1,3-Dichloropropane 76 8.014 8.014 0.000 96 1394487 75.0 73.3 91 2-Hexanone 43 8.042 8.042 0.000 92 5583907 300.0 310.5 93 Chlorodibromomethane 129 8.223 8.224 -0.001 90 720780 75.0 87.7 95 Ethylene Dibromide 107 8.349 8.349 0.000 99 876674 75.0 77.3 96 1-Chlorohexane 91 8.754 8.754 0.000 94 907216 60.0 55.4 97 Chlorobenzene 112 8.796 8.796 0.000 95 2341593 75.0 73.2 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 725349 75.0 85.6 98 Ethylbenzene 106 8.880 8.880 0.000 97 1338889 75.0 73.3 100 m-Xylene & p-Xylene 106 9.005 9.006 -0.001 0 1609100 75.0 75.1 101 o-Xylene 106 9.369 9.369 0.000 96 1575706 75.0 74.4 103 Styrene 104 9.383 9.383 0.000 95 2626719 75.0 76.1 104 Bromoform 173 9.578 9.578 0.000 96 481663 75.0 75.0 105 Isopropylbenzene 105 9.718 9.718 0.000 95 3599846 75.0 73.0 107 Cyclohexanone 55 9.829 9.830 -0.001 88 6369305 2250.0 2393.4 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 94 1356849 75.0 74.2 109 Bromobenzene 156 10.053 10.053 0.000 94 931061 75.0 70.8 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 75 300265 75.0 74.8 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 462041 75.0 76.4 112 N-Propylbenzene 120 10.137 10.137 0.000 98 1090743 75.0 70.6 113 2-Chlorotoluene 126 10.234 10.235 -0.001 97 913976 75.0 72.9 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 94 3170393 75.0 73.5 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 956313 75.0 70.7 Page 210 of 426 Report Date: 16-Oct-2024 07:41:03 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0303.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 2718873 75.0 72.7 117 1,2,4-Trimethylbenzene 105 10.681 10.682 -0.001 97 3312891 75.0 73.6 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 806810 75.0 74.6 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 1780327 75.0 72.1 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 3411302 75.0 74.0 121 1,4-Dichlorobenzene 146 11.072 11.073 -0.001 96 1808058 75.0 71.5 124 n-Butylbenzene 91 11.408 11.408 0.000 97 2981973 75.0 73.1 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 1692523 75.0 71.7 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 89 419845 75.0 83.9 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 95 959595 75.0 72.2 129 Hexachlorobutadiene 225 13.195 13.196 -0.001 98 327009 75.0 70.8 130 Naphthalene 128 13.335 13.335 0.000 96 3971740 75.0 76.1 132 1,2,3-Trichlorobenzene 180 13.558 13.559 -0.001 95 896391 75.0 75.6 S 147 1,2-Dichloroethene, Total (URS) 96 0 150.0 146.4 S 148 Xylenes, Total 106 0 150.0 149.5 S 150 Xylenes, Total (URS) 1 0 150.0 149.5 S 151 Total BTEX 1 0 365.4 S 152 Trihalomethanes, Total 1 0 300.0 315.8 S 153 1,2-Dichloroethene, Total 1 0 150.0 146.4 S 154 1,3-Dichloropropene, Total 1 0 150.0 168.3 QC Flag Legend Processing Flags Reagents: MV-MegaMainA_00115 Amount Added: 37.50 Units: uL MV-Gas A_00198 Amount Added: 15.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 211 of 426 Report Date: 16-Oct-2024 07:41:03 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0303.D Injection Date: 16-Oct-2024 02:28:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 45 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 8 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Y ( X10 0 0 0 0 0 ) MS1_0303[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 8 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ I o dom e t h a n e ( 3 . 6 1 4 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 )+ A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) I s o b u t yl a l c o h o l ( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 8 3 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 1 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 2 9 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) 1 ,1,2,2- Tet r a c h l o r o e t h a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 4 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 5 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 7 2 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 2 1 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 4 ) Page 212 of 426 Report Date: 16-Oct-2024 07:41:05 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0304.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 8 Inject. Date: 16-Oct-2024 02:49:30 ALS Bottle#: 9 Worklist Smp#: 46 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 8 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:41:05 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:14:41 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3096526 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 713816 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 93 1137029 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 703286 50.0 50.7 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.752 0.000 0 756124 50.0 49.9 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 3075542 50.0 50.4 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 89 1045855 50.0 49.5 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 1275820 100.0 94.3 10 Chloromethane 50 2.009 2.009 0.000 99 1309890 100.0 93.4 11 Vinyl chloride 62 2.134 2.134 0.000 97 1247723 100.0 97.5 13 Bromomethane 94 2.469 2.483 -0.014 90 771017 100.0 100.4 14 Chloroethane 64 2.609 2.609 0.000 99 829028 100.0 94.2 15 Dichlorofluoromethane 67 2.847 2.847 0.000 96 2042824 100.0 94.2 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 98 1484969 100.0 93.4 18 Ethyl ether 59 3.168 3.168 0.000 87 928668 100.0 89.6 20 Acrolein 56 3.307 3.307 0.000 100 2007111 987.5 900.6 22 1,1-Dichloroethene 96 3.405 3.405 0.000 96 1000625 100.0 92.2 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 90 723314 100.0 88.8 23 Acetone 43 3.447 3.447 0.000 99 3634749 400.0 386.8 24 Iodomethane 142 3.559 3.559 0.000 97 1243483 100.0 100.2 26 Carbon disulfide 76 3.615 3.629 -0.014 99 2871275 100.0 97.3 28 Methyl acetate 43 3.740 3.740 0.000 97 3339491 200.0 186.8 29 3-Chloro-1-propene 41 3.754 3.754 0.000 91 1266649 100.0 96.5 30 Methylene Chloride 84 3.880 3.880 0.000 87 1121560 100.0 94.0 31 2-Methyl-2-propanol 59 3.978 3.964 0.014 100 7062258 1000.0 995.5 32 Acrylonitrile 53 4.104 4.104 0.000 99 8844394 1000.0 939.6 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 94 3427653 100.0 94.4 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 97 1118783 100.0 93.7 36 Hexane 57 4.383 4.383 0.000 88 1399408 100.0 91.0 38 Vinyl acetate 43 4.522 4.523 -0.001 97 4151527 200.0 179.2 39 1,1-Dichloroethane 63 4.536 4.537 0.000 95 1864549 100.0 91.8 Page 213 of 426 Report Date: 16-Oct-2024 07:41:05 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0304.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 5866424 400.0 358.9 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 80 1242382 100.0 92.2 46 2,2-Dichloropropane 77 5.039 5.039 0.000 89 1347584 100.0 103.4 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 12369367 2400.0 2481.8 52 Tetrahydrofuran 42 5.249 5.249 0.000 84 1941819 200.0 189.6 51 Chlorobromomethane 128 5.235 5.249 -0.014 93 526882 100.0 85.8 53 Chloroform 83 5.319 5.319 0.000 93 1846233 100.0 93.7 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 1498829 100.0 98.4 57 Cyclohexane 56 5.542 5.542 0.000 86 1803913 100.0 91.5 59 Carbon tetrachloride 117 5.612 5.612 0.000 79 1161580 100.0 103.5 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 1518679 100.0 92.3 60 Isobutyl alcohol 41 5.668 5.668 0.000 95 4790431 2500.0 2415.8 61 Benzene 78 5.779 5.780 -0.001 95 4611739 100.0 90.1 62 1,2-Dichloroethane 62 5.821 5.821 0.000 98 1363728 100.0 88.8 64 n-Heptane 43 6.003 6.003 0.000 89 1139688 100.0 93.2 66 Trichloroethene 95 6.338 6.338 0.000 99 1150001 100.0 94.7 67 2-Pentanone 43 6.478 6.478 0.000 97 6982722 320.0 304.2 68 Methylcyclohexane 55 6.548 6.548 0.000 89 1339752 100.0 88.4 69 1,2-Dichloropropane 63 6.576 6.576 0.000 97 1107705 100.0 93.6 71 1,4-Dioxane 88 6.631 6.631 0.000 90 1306507 2000.0 1898.4 72 Dibromomethane 93 6.659 6.645 0.014 97 701274 100.0 94.0 73 Dichlorobromomethane 83 6.799 6.799 0.000 100 1292785 100.0 102.5 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 91 407212 100.0 102.8 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 1716607 100.0 106.3 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 93 8315143 400.0 385.7 80 Toluene 91 7.483 7.483 0.000 99 4980885 100.0 91.4 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 1509809 100.0 112.3 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 1893155 100.0 98.1 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 1092570 100.0 93.4 89 Tetrachloroethene 164 7.958 7.958 0.000 97 898427 100.0 93.2 90 1,3-Dichloropropane 76 8.014 8.014 0.000 96 1844109 100.0 92.1 91 2-Hexanone 43 8.042 8.042 0.000 92 7264833 400.0 383.6 93 Chlorodibromomethane 129 8.224 8.224 0.000 89 987661 100.0 114.1 95 Ethylene Dibromide 107 8.349 8.349 0.000 99 1175629 100.0 98.5 96 1-Chlorohexane 91 8.754 8.754 0.000 94 1236008 80.0 71.6 97 Chlorobenzene 112 8.796 8.796 0.000 96 3122826 100.0 92.7 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 963014 100.0 108.0 98 Ethylbenzene 106 8.880 8.880 0.000 97 1771535 100.0 92.1 100 m-Xylene & p-Xylene 106 8.992 9.006 -0.014 0 2188163 100.0 97.0 101 o-Xylene 106 9.369 9.369 0.000 96 2096540 100.0 94.0 103 Styrene 104 9.383 9.383 0.000 95 3495681 100.0 96.1 104 Bromoform 173 9.578 9.578 0.000 96 649299 100.0 95.9 105 Isopropylbenzene 105 9.718 9.718 0.000 96 4785338 100.0 93.4 107 Cyclohexanone 55 9.830 9.830 0.000 88 8129722 3000.0 2901.4 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 94 1787481 100.0 94.0 109 Bromobenzene 156 10.053 10.053 0.000 94 1252929 100.0 91.7 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 84 398512 100.0 95.2 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 613670 100.0 97.7 112 N-Propylbenzene 120 10.137 10.137 0.000 98 1449197 100.0 90.2 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 1226402 100.0 94.1 114 1,3,5-Trimethylbenzene 105 10.305 10.305 0.000 94 4252206 100.0 94.8 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 1260625 100.0 89.6 Page 214 of 426 Report Date: 16-Oct-2024 07:41:05 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0304.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 3637719 100.0 93.5 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 4407492 100.0 94.2 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 1076675 100.0 95.8 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 2362874 100.0 92.1 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 4526107 100.0 94.4 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 2408028 100.0 91.6 124 n-Butylbenzene 91 11.408 11.408 0.000 97 3970595 100.0 93.6 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 2256498 100.0 92.0 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 89 570634 100.0 109.7 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 95 1297322 100.0 93.8 129 Hexachlorobutadiene 225 13.196 13.196 0.000 98 454683 100.0 94.7 130 Naphthalene 128 13.335 13.335 0.000 97 5246284 100.0 96.7 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 96 1200497 100.0 97.3 S 147 1,2-Dichloroethene, Total (URS) 96 0 200.0 185.9 S 148 Xylenes, Total 106 0 200.0 191.0 S 150 Xylenes, Total (URS) 1 0 200.0 191.0 S 151 Total BTEX 1 0 464.6 S 152 Trihalomethanes, Total 1 0 400.0 406.2 S 153 1,2-Dichloroethene, Total 1 0 200.0 185.9 S 154 1,3-Dichloropropene, Total 1 0 200.0 218.6 QC Flag Legend Processing Flags Reagents: MV-MegaMainA_00115 Amount Added: 50.00 Units: uL MV-Gas A_00198 Amount Added: 20.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 215 of 426 Report Date: 16-Oct-2024 07:41:05 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0304.D Injection Date: 16-Oct-2024 02:49:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 46 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 9 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Y ( X10 0 0 0 0 0 ) MS1_0304[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 6 9 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 7 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ C a r b o n dis u l f i de( 3 . 6 1 5 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 9 7 8 )+ A c r ylo n i t r i l e ( 4 . 1 0 4 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 3 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) 1 ,1- D i c h l o r o p r o p e n e ( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tric h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 2 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 8 3 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 4 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 9 6 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 3 0 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) 1 ,1,2,2- Tet r a c h l o r o e t h a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 7 3 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 216 of 426 Report Date: 16-Oct-2024 07:41:07 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0305.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 9 Inject. Date: 16-Oct-2024 03:11:30 ALS Bottle#: 10 Worklist Smp#: 47 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 9 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:41:07 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:15:49 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3148814 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 755636 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 93 1194773 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 722066 50.0 51.2 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.752 0.000 0 786414 50.0 51.0 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 93 3171375 50.0 49.1 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 88 1076988 50.0 48.5 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 2680300 200.0 194.7 10 Chloromethane 50 2.009 2.009 0.000 99 2725848 200.0 191.2 11 Vinyl chloride 62 2.134 2.134 0.000 97 2550999 200.0 196.0 13 Bromomethane 94 2.469 2.483 -0.014 89 1175697 200.0 150.8 14 Chloroethane 64 2.595 2.609 -0.014 99 1687617 200.0 188.7 15 Dichlorofluoromethane 67 2.847 2.847 0.000 96 4144898 200.0 188.0 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 99 3082846 200.0 190.8 18 Ethyl ether 59 3.168 3.168 0.000 87 1940795 200.0 184.1 20 Acrolein 56 3.307 3.307 0.000 100 4136116 1975.0 1825.2 22 1,1-Dichloroethene 96 3.405 3.405 0.000 95 2169761 200.0 196.6 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.405 3.419 -0.014 76 1557070 200.0 187.9 23 Acetone 43 3.447 3.447 0.000 99 7444847 800.0 783.0 24 Iodomethane 142 3.559 3.559 0.000 97 2573321 200.0 204.1 26 Carbon disulfide 76 3.615 3.629 -0.014 99 6179289 200.0 206.0 28 Methyl acetate 43 3.740 3.740 0.000 96 6957653 400.0 382.8 29 3-Chloro-1-propene 41 3.754 3.754 0.000 91 2529326 200.0 191.3 30 Methylene Chloride 84 3.880 3.880 0.000 85 2402609 200.0 198.5 31 2-Methyl-2-propanol 59 3.978 3.964 0.014 100 14489975 2000.0 2008.5 32 Acrylonitrile 53 4.103 4.104 -0.001 96 16641250 2000.0 1738.5 e 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 94 7284933 200.0 197.4 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 95 2416765 200.0 199.1 36 Hexane 57 4.369 4.383 -0.014 90 3056140 200.0 187.8 38 Vinyl acetate 43 4.522 4.523 -0.001 97 8409790 400.0 356.9 39 1,1-Dichloroethane 63 4.536 4.537 0.000 95 3919617 200.0 189.7 Page 217 of 426 Report Date: 16-Oct-2024 07:41:07 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0305.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 97 11852794 800.0 713.1 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 2688501 200.0 196.2 46 2,2-Dichloropropane 77 5.039 5.039 0.000 86 2946416 200.0 222.3 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 96 22622154 4800.0 4463.5 e 52 Tetrahydrofuran 42 5.249 5.249 0.000 83 4026218 400.0 386.6 51 Chlorobromomethane 128 5.235 5.249 -0.014 94 1123822 200.0 180.0 53 Chloroform 83 5.319 5.319 0.000 92 3915423 200.0 195.5 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 3258307 200.0 210.3 57 Cyclohexane 56 5.528 5.542 -0.014 88 3875235 200.0 193.4 59 Carbon tetrachloride 117 5.612 5.612 0.000 80 2587774 200.0 226.8 58 1,1-Dichloropropene 75 5.612 5.612 0.000 97 3286621 200.0 196.5 60 Isobutyl alcohol 41 5.668 5.668 0.000 94 9853382 5000.0 4875.5 61 Benzene 78 5.779 5.780 -0.001 96 9636239 200.0 185.2 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 2849560 200.0 182.6 64 n-Heptane 43 6.003 6.003 0.000 95 2480591 200.0 199.6 66 Trichloroethene 95 6.338 6.338 0.000 98 2492033 200.0 193.9 67 2-Pentanone 43 6.478 6.478 0.000 96 13789499 640.0 590.8 68 Methylcyclohexane 55 6.548 6.548 0.000 89 2904240 200.0 188.5 69 1,2-Dichloropropane 63 6.576 6.576 0.000 97 2418213 200.0 200.8 71 1,4-Dioxane 88 6.631 6.631 0.000 95 2648216 4000.0 3784.0 72 Dibromomethane 93 6.659 6.645 0.014 97 1500342 200.0 197.7 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 2834148 200.0 221.0 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 91 882965 200.0 219.2 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 3745192 200.0 219.1 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.288 0.014 90 16158273 800.0 737.1 80 Toluene 91 7.483 7.483 0.000 99 10502998 200.0 189.5 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 89 3365446 200.0 246.1 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 4089603 200.0 200.1 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 2346849 200.0 197.2 89 Tetrachloroethene 164 7.958 7.958 0.000 97 1927840 200.0 188.9 90 1,3-Dichloropropane 76 8.014 8.014 0.000 97 3931026 200.0 185.5 91 2-Hexanone 43 8.042 8.042 0.000 90 14252210 800.0 710.9 93 Chlorodibromomethane 129 8.224 8.224 0.000 90 2204034 200.0 240.6 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 2521139 200.0 199.5 96 1-Chlorohexane 91 8.754 8.754 0.000 94 2674849 160.0 146.5 97 Chlorobenzene 112 8.796 8.796 0.000 95 6591318 200.0 184.9 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 43 2153086 200.0 228.0 98 Ethylbenzene 106 8.880 8.880 0.000 97 3874402 200.0 190.2 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 4659653 200.0 195.2 101 o-Xylene 106 9.369 9.369 0.000 95 4489339 200.0 190.1 103 Styrene 104 9.383 9.383 0.000 95 7435947 200.0 193.2 104 Bromoform 173 9.578 9.578 0.000 97 1516749 200.0 210.6 105 Isopropylbenzene 105 9.718 9.718 0.000 96 9886631 200.0 183.6 107 Cyclohexanone 55 9.830 9.830 0.000 89 15723754 6000.0 5301.0 e 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 3801866 200.0 190.3 109 Bromobenzene 156 10.053 10.053 0.000 94 2720712 200.0 189.5 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 82 932630 200.0 211.3 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 1323861 200.0 200.8 112 N-Propylbenzene 120 10.137 10.137 0.000 98 3110725 200.0 184.3 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 2613761 200.0 190.9 114 1,3,5-Trimethylbenzene 105 10.305 10.305 -0.001 94 8778883 200.0 186.4 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 2722993 200.0 184.2 Page 218 of 426 Report Date: 16-Oct-2024 07:41:07 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0305.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 7494229 200.0 183.3 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 8993450 200.0 183.0 118 sec-Butylbenzene 134 10.849 10.849 0.000 94 2259715 200.0 191.3 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 5034650 200.0 186.7 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 9369410 200.0 185.9 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 5116031 200.0 185.2 124 n-Butylbenzene 91 11.408 11.408 0.000 97 8288021 200.0 186.0 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 4824451 200.0 187.1 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 89 1296669 200.0 237.1 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 2752701 200.0 189.4 129 Hexachlorobutadiene 225 13.196 13.196 0.000 98 1004045 200.0 198.9 130 Naphthalene 128 13.335 13.335 0.000 97 10807531 200.0 189.6 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 96 2545191 200.0 196.4 S 147 1,2-Dichloroethene, Total (URS) 96 0 400.0 395.3 S 148 Xylenes, Total 106 0 400.0 385.3 S 150 Xylenes, Total (URS) 1 0 400.0 385.3 S 151 Total BTEX 1 0 950.2 S 152 Trihalomethanes, Total 1 0 800.0 867.7 S 153 1,2-Dichloroethene, Total 1 0 400.0 395.3 S 154 1,3-Dichloropropene, Total 1 0 400.0 465.2 QC Flag Legend Processing Flags e - Potential Peak Saturated Reagents: MV-MegaMainA_00115 Amount Added: 100.00 Units: uL MV-Gas A_00198 Amount Added: 40.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 219 of 426 Report Date: 16-Oct-2024 07:41:08 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0305.D Injection Date: 16-Oct-2024 03:11:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 47 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 10 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 Y ( X10 0 0 0 0 0 ) MS1_0305[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 6 9 ) C h l o r o e t h a n e ( 2 . 5 9 5 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 7 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ I o dom e t h a n e ( 3 . 6 1 5 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 8 8 0 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 7 8 ) A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 6 9 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 7 9 )+ C h l o r o f o r m ( 5 . 3 3 3 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C yclo h e xan e ( 5 . 5 2 8 ) C a r b o n t e t r a c h l o r i de( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 0 3 )+ Tric h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 2 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 8 3 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 4 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 9 6 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C yclo h e xan o n e ( 9 . 8 3 0 )+ N-P r o p ylb e n zen e ( 1 0 . 1 3 7 ) 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 7 3 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 220 of 426 Calibration / Dichlorodifluoromethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2185 Error Coefficients Relative Standard Deviation:10.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.12247 50.0 2819067.0 0.244939 Y 2 IC 280-671165/40 1.0 0.233151 50.0 2846226.0 0.233151 Y 3 IC 280-671165/41 2.0 0.407646 50.0 2813838.0 0.203823 Y 4 IC 280-671165/42 5.0 1.2052 50.0 2845130.0 0.24104 Y 5 IC 280-671165/43 10.0 1.79919 50.0 2845836.0 0.179919 Y 6 ICIS 280-671165/44 50.0 11.335333 50.0 2943416.0 0.226707 Y 7 IC 280-671165/45 75.0 10.963217 50.0 2963788.0 0.146176 N 8 IC 280-671165/46 100.0 20.600828 50.0 3096526.0 0.206008 Y 9 IC 280-671165/47 200.0 42.560469 50.0 3148814.0 0.212802 Y RelResp = [0.2185]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 221 of 426 Calibration / Chloromethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2264 Error Coefficients Relative Standard Deviation:11.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.132987 50.0 2819067.0 0.265975 Y 2 IC 280-671165/40 1.0 0.250946 50.0 2846226.0 0.250946 Y 3 IC 280-671165/41 2.0 0.467902 50.0 2813838.0 0.233951 Y 4 IC 280-671165/42 5.0 1.117102 50.0 2845130.0 0.22342 Y 5 IC 280-671165/43 10.0 1.802089 50.0 2845836.0 0.180209 Y 6 ICIS 280-671165/44 50.0 11.453937 50.0 2943416.0 0.229079 Y 7 IC 280-671165/45 75.0 10.514011 50.0 2963788.0 0.140187 N 8 IC 280-671165/46 100.0 21.150961 50.0 3096526.0 0.21151 Y 9 IC 280-671165/47 200.0 43.283725 50.0 3148814.0 0.216419 Y RelResp = [0.2264]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 222 of 426 Calibration / Vinyl chloride Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2067 Error Coefficients Relative Standard Deviation:8.3 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.10241 50.0 2819067.0 0.20482 Y 2 IC 280-671165/40 1.0 0.208047 50.0 2846226.0 0.208047 Y 3 IC 280-671165/41 2.0 0.430426 50.0 2813838.0 0.215213 Y 4 IC 280-671165/42 5.0 1.139702 50.0 2845130.0 0.22794 Y 5 IC 280-671165/43 10.0 1.712467 50.0 2845836.0 0.171247 Y 6 ICIS 280-671165/44 50.0 11.104564 50.0 2943416.0 0.222091 Y 7 IC 280-671165/45 75.0 10.481823 50.0 2963788.0 0.139758 N 8 IC 280-671165/46 100.0 20.147142 50.0 3096526.0 0.201471 Y 9 IC 280-671165/47 200.0 40.507299 50.0 3148814.0 0.202536 Y RelResp = [0.2067]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 223 of 426 Calibration / Bromomethane Curve Type:Linear Weighting:Conc Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.07021 Slope:0.1233 Error Coefficients Relative Standard Deviation:14.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.119508 50.0 2819067.0 0.239015 Y 2 IC 280-671165/40 1.0 0.221732 50.0 2846226.0 0.221732 Y 3 IC 280-671165/41 2.0 0.331807 50.0 2813838.0 0.165903 Y 4 IC 280-671165/42 5.0 0.696945 50.0 2845130.0 0.139389 Y 5 IC 280-671165/43 10.0 1.156462 50.0 2845836.0 0.115646 Y 6 ICIS 280-671165/44 50.0 6.292332 50.0 2943416.0 0.125847 Y 7 IC 280-671165/45 75.0 6.987629 50.0 2963788.0 0.093168 N 8 IC 280-671165/46 100.0 12.44971 50.0 3096526.0 0.124497 Y 9 IC 280-671165/47 200.0 18.668886 50.0 3148814.0 0.093344 N RelResp = [0.07021] + [0.1233]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 Intercept = -0.569 Page 224 of 426 Calibration / Chloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.142 Error Coefficients Relative Standard Deviation:13.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.07263 50.0 2819067.0 0.145261 Y 2 IC 280-671165/40 1.0 0.175601 50.0 2846226.0 0.175601 Y 3 IC 280-671165/41 2.0 0.281928 50.0 2813838.0 0.140964 Y 4 IC 280-671165/42 5.0 0.771828 50.0 2845130.0 0.154366 Y 5 IC 280-671165/43 10.0 1.071302 50.0 2845836.0 0.10713 Y 6 ICIS 280-671165/44 50.0 7.258573 50.0 2943416.0 0.145171 Y 7 IC 280-671165/45 75.0 6.813595 50.0 2963788.0 0.090848 N 8 IC 280-671165/46 100.0 13.386421 50.0 3096526.0 0.133864 Y 9 IC 280-671165/47 200.0 26.797661 50.0 3148814.0 0.133988 Y RelResp = [0.142]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 225 of 426 Calibration / Dichlorofluoromethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3502 Error Coefficients Relative Standard Deviation:9.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.196129 50.0 2819067.0 0.392257 Y 2 IC 280-671165/40 1.0 0.372089 50.0 2846226.0 0.372089 Y 3 IC 280-671165/41 2.0 0.726641 50.0 2813838.0 0.36332 Y 4 IC 280-671165/42 5.0 1.876716 50.0 2845130.0 0.375343 Y 5 IC 280-671165/43 10.0 2.836021 50.0 2845836.0 0.283602 Y 6 ICIS 280-671165/44 50.0 17.783827 50.0 2943416.0 0.355677 Y 7 IC 280-671165/45 75.0 16.834251 50.0 2963788.0 0.224457 N 8 IC 280-671165/46 100.0 32.98574 50.0 3096526.0 0.329857 Y 9 IC 280-671165/47 200.0 65.816812 50.0 3148814.0 0.329084 Y RelResp = [0.3502]x Concentration 0 100 200 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 226 of 426 Calibration / Trichlorofluoromethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2566 Error Coefficients Relative Standard Deviation:10.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.131746 50.0 2819067.0 0.263491 Y 2 IC 280-671165/40 1.0 0.301013 50.0 2846226.0 0.301013 Y 3 IC 280-671165/41 2.0 0.537398 50.0 2813838.0 0.268699 Y 4 IC 280-671165/42 5.0 1.340659 50.0 2845130.0 0.268132 Y 5 IC 280-671165/43 10.0 2.062698 50.0 2845836.0 0.20627 Y 6 ICIS 280-671165/44 50.0 13.032392 50.0 2943416.0 0.260648 Y 7 IC 280-671165/45 75.0 12.528545 50.0 2963788.0 0.167047 N 8 IC 280-671165/46 100.0 23.977984 50.0 3096526.0 0.23978 Y 9 IC 280-671165/47 200.0 48.952494 50.0 3148814.0 0.244762 Y RelResp = [0.2566]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 227 of 426 Calibration / Ethyl ether Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1674 Error Coefficients Relative Standard Deviation:8.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.091999 50.0 2819067.0 0.183997 Y 2 IC 280-671165/40 1.0 0.187511 50.0 2846226.0 0.187511 Y 3 IC 280-671165/41 2.0 0.35878 50.0 2813838.0 0.17939 Y 4 IC 280-671165/42 5.0 0.839171 50.0 2845130.0 0.167834 Y 5 IC 280-671165/43 10.0 1.571278 50.0 2845836.0 0.157128 Y 6 ICIS 280-671165/44 50.0 7.954431 50.0 2943416.0 0.159089 Y 7 IC 280-671165/45 75.0 11.819182 50.0 2963788.0 0.157589 N 8 IC 280-671165/46 100.0 14.995321 50.0 3096526.0 0.149953 Y 9 IC 280-671165/47 200.0 30.817873 50.0 3148814.0 0.154089 Y RelResp = [0.1674]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 228 of 426 Calibration / Acrolein Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.03598 Error Coefficients Relative Standard Deviation:10.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 4.9375 0.222024 50.0 2819067.0 0.044967 Y 2 IC 280-671165/40 9.875 0.352414 50.0 2846226.0 0.035687 Y 3 IC 280-671165/41 19.75 0.739737 50.0 2813838.0 0.037455 Y 4 IC 280-671165/42 49.375 1.747038 50.0 2845130.0 0.035383 Y 5 IC 280-671165/43 98.75 3.346785 50.0 2845836.0 0.033891 Y 6 ICIS 280-671165/44 493.75 16.992977 50.0 2943416.0 0.034416 Y 7 IC 280-671165/45 740.625 26.192899 50.0 2963788.0 0.035366 N 8 IC 280-671165/46 987.5 32.409077 50.0 3096526.0 0.032819 Y 9 IC 280-671165/47 1975.0 65.677363 50.0 3148814.0 0.033254 Y RelResp = [0.03598]x Concentration 0 1000 2000 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 229 of 426 Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1316 Error Coefficients Relative Standard Deviation:8.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.077419 50.0 2819067.0 0.154838 Y 2 IC 280-671165/40 1.0 0.138991 50.0 2846226.0 0.138991 Y 3 IC 280-671165/41 2.0 0.251045 50.0 2813838.0 0.125523 Y 4 IC 280-671165/42 5.0 0.653749 50.0 2845130.0 0.13075 Y 5 IC 280-671165/43 10.0 1.355718 50.0 2845836.0 0.135572 Y 6 ICIS 280-671165/44 50.0 6.330179 50.0 2943416.0 0.126604 Y 7 IC 280-671165/45 75.0 8.608544 50.0 2963788.0 0.114781 N 8 IC 280-671165/46 100.0 11.679443 50.0 3096526.0 0.116794 Y 9 IC 280-671165/47 200.0 24.724706 50.0 3148814.0 0.123624 Y RelResp = [0.1316]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 230 of 426 Calibration / 1,1-Dichloroethene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1753 Error Coefficients Relative Standard Deviation:5.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.098738 50.0 2819067.0 0.197477 Y 2 IC 280-671165/40 1.0 0.176198 50.0 2846226.0 0.176198 Y 3 IC 280-671165/41 2.0 0.346768 50.0 2813838.0 0.173384 Y 4 IC 280-671165/42 5.0 0.867816 50.0 2845130.0 0.173563 Y 5 IC 280-671165/43 10.0 1.729913 50.0 2845836.0 0.172991 Y 6 ICIS 280-671165/44 50.0 8.736821 50.0 2943416.0 0.174736 Y 7 IC 280-671165/45 75.0 12.325409 50.0 2963788.0 0.164339 N 8 IC 280-671165/46 100.0 16.157219 50.0 3096526.0 0.161572 Y 9 IC 280-671165/47 200.0 34.453623 50.0 3148814.0 0.172268 Y RelResp = [0.1753]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 231 of 426 Calibration / Acetone Curve Type:Linear Weighting:Conc_Sq Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.576 Slope:0.1503 Error Coefficients Relative Standard Deviation:2.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 2.0 0.870785 50.0 2819067.0 0.435392 Y 2 IC 280-671165/40 4.0 1.189663 50.0 2846226.0 0.297416 Y 3 IC 280-671165/41 8.0 1.811174 50.0 2813838.0 0.226397 Y 4 IC 280-671165/42 20.0 3.638551 50.0 2845130.0 0.181928 Y 5 IC 280-671165/43 40.0 6.579104 50.0 2845836.0 0.164478 Y 6 ICIS 280-671165/44 200.0 30.834989 50.0 2943416.0 0.154175 Y 7 IC 280-671165/45 300.0 47.687385 50.0 2963788.0 0.158958 N 8 IC 280-671165/46 400.0 58.690755 50.0 3096526.0 0.146727 Y 9 IC 280-671165/47 800.0 118.216684 50.0 3148814.0 0.147771 Y RelResp = [0.576] + [0.1503]x Concentration 0 100 200 300 400 500 600 700 800 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Intercept = -3.83 Page 232 of 426 Calibration / Iodomethane Curve Type:Linear Weighting:Conc Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.01515 Slope:0.2002 Error Coefficients Relative Standard Deviation:23.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.164487 50.0 2819067.0 0.328974 Y 2 IC 280-671165/40 1.0 0.218219 50.0 2846226.0 0.218219 Y 3 IC 280-671165/41 2.0 0.376337 50.0 2813838.0 0.188168 Y 4 IC 280-671165/42 5.0 0.823829 50.0 2845130.0 0.164766 Y 5 IC 280-671165/43 10.0 1.587688 50.0 2845836.0 0.158769 Y 6 ICIS 280-671165/44 50.0 9.772319 50.0 2943416.0 0.195446 Y 7 IC 280-671165/45 75.0 13.190586 50.0 2963788.0 0.175874 N 8 IC 280-671165/46 100.0 20.078678 50.0 3096526.0 0.200787 Y 9 IC 280-671165/47 200.0 40.86175 50.0 3148814.0 0.204309 Y RelResp = [0.01515] + [0.2002]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Intercept = -0.0757 Page 233 of 426 Calibration / Carbon disulfide Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.4763 Error Coefficients Relative Standard Deviation:5.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.261257 50.0 2819067.0 0.522513 Y 2 IC 280-671165/40 1.0 0.488735 50.0 2846226.0 0.488735 Y 3 IC 280-671165/41 2.0 0.918994 50.0 2813838.0 0.459497 Y 4 IC 280-671165/42 5.0 2.245187 50.0 2845130.0 0.449037 Y 5 IC 280-671165/43 10.0 4.535609 50.0 2845836.0 0.453561 Y 6 ICIS 280-671165/44 50.0 24.139079 50.0 2943416.0 0.482782 Y 7 IC 280-671165/45 75.0 35.206955 50.0 2963788.0 0.469426 N 8 IC 280-671165/46 100.0 46.362843 50.0 3096526.0 0.463628 Y 9 IC 280-671165/47 200.0 98.120896 50.0 3148814.0 0.490604 Y RelResp = [0.4763]x Concentration 0 100 200 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Page 234 of 426 Calibration / 3-Chloro-1-propene Curve Type:Linear Weighting:Conc_Sq Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.3672 Slope:0.2081 Error Coefficients Relative Standard Deviation:5.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.472444 50.0 2819067.0 0.944887 Y 2 IC 280-671165/40 1.0 0.567225 50.0 2846226.0 0.567225 Y 3 IC 280-671165/41 2.0 0.800295 50.0 2813838.0 0.400147 Y 4 IC 280-671165/42 5.0 1.373013 50.0 2845130.0 0.274603 Y 5 IC 280-671165/43 10.0 2.47458 50.0 2845836.0 0.247458 Y 6 ICIS 280-671165/44 50.0 11.659905 50.0 2943416.0 0.233198 Y 7 IC 280-671165/45 75.0 16.484765 50.0 2963788.0 0.219797 N 8 IC 280-671165/46 100.0 20.452743 50.0 3096526.0 0.204527 Y 9 IC 280-671165/47 200.0 40.163153 50.0 3148814.0 0.200816 Y RelResp = [0.3672] + [0.2081]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Intercept = -1.76 Page 235 of 426 Calibration / Methyl acetate Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2886 Error Coefficients Relative Standard Deviation:4.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 1.0 0.298113 50.0 2819067.0 0.298113 Y 2 IC 280-671165/40 2.0 0.613743 50.0 2846226.0 0.306871 Y 3 IC 280-671165/41 4.0 1.222832 50.0 2813838.0 0.305708 Y 4 IC 280-671165/42 10.0 2.841979 50.0 2845130.0 0.284198 Y 5 IC 280-671165/43 20.0 5.59904 50.0 2845836.0 0.279952 Y 6 ICIS 280-671165/44 100.0 28.827271 50.0 2943416.0 0.288273 Y 7 IC 280-671165/45 150.0 43.010735 50.0 2963788.0 0.286738 N 8 IC 280-671165/46 200.0 53.923187 50.0 3096526.0 0.269616 Y 9 IC 280-671165/47 400.0 110.480533 50.0 3148814.0 0.276201 Y RelResp = [0.2886]x Concentration 0 100 200 300 400 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 236 of 426 Calibration / Methylene Chloride Curve Type:Linear Weighting:Conc_Sq Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.0776 Slope:0.1918 Error Coefficients Relative Standard Deviation:3.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.174384 50.0 2819067.0 0.348768 Y 2 IC 280-671165/40 1.0 0.265527 50.0 2846226.0 0.265527 Y 3 IC 280-671165/41 2.0 0.45374 50.0 2813838.0 0.22687 Y 4 IC 280-671165/42 5.0 1.089142 50.0 2845130.0 0.217828 Y 5 IC 280-671165/43 10.0 2.010622 50.0 2845836.0 0.201062 Y 6 ICIS 280-671165/44 50.0 10.010036 50.0 2943416.0 0.200201 Y 7 IC 280-671165/45 75.0 14.357673 50.0 2963788.0 0.191436 N 8 IC 280-671165/46 100.0 18.109972 50.0 3096526.0 0.1811 Y 9 IC 280-671165/47 200.0 38.151015 50.0 3148814.0 0.190755 Y RelResp = [0.0776] + [0.1918]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Intercept = -0.405 Page 237 of 426 Calibration / 2-Methyl-2-propanol Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1146 Error Coefficients Relative Standard Deviation:4.3 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 5.0 0.624834 50.0 2819067.0 0.124967 Y 2 IC 280-671165/40 10.0 1.129671 50.0 2846226.0 0.112967 Y 3 IC 280-671165/41 20.0 2.21388 50.0 2813838.0 0.110694 Y 4 IC 280-671165/42 50.0 5.744922 50.0 2845130.0 0.114898 Y 5 IC 280-671165/43 100.0 10.797284 50.0 2845836.0 0.107973 Y 6 ICIS 280-671165/44 500.0 57.932467 50.0 2943416.0 0.115865 Y 7 IC 280-671165/45 750.0 91.592094 50.0 2963788.0 0.122123 N 8 IC 280-671165/46 1000.0 114.03518 50.0 3096526.0 0.114035 Y 9 IC 280-671165/47 2000.0 230.086232 50.0 3148814.0 0.115043 Y RelResp = [0.1146]x Concentration 0 1000 2000 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Page 238 of 426 Calibration / Acrylonitrile Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.152 Error Coefficients Relative Standard Deviation:6.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 5.0 0.773341 50.0 2819067.0 0.154668 Y 2 IC 280-671165/40 10.0 1.581305 50.0 2846226.0 0.15813 Y 3 IC 280-671165/41 20.0 3.250205 50.0 2813838.0 0.16251 Y 4 IC 280-671165/42 50.0 7.684869 50.0 2845130.0 0.153697 Y 5 IC 280-671165/43 100.0 15.84053 50.0 2845836.0 0.158405 Y 6 ICIS 280-671165/44 500.0 76.806303 50.0 2943416.0 0.153613 Y 7 IC 280-671165/45 750.0 116.179194 50.0 2963788.0 0.154906 N 8 IC 280-671165/46 1000.0 142.811557 50.0 3096526.0 0.142812 Y 9 IC 280-671165/47 2000.0 264.246316 50.0 3148814.0 0.132123 Y RelResp = [0.152]x Concentration 0 1000 2000 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 239 of 426 Calibration / Methyl tert-butyl ether Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.5861 Error Coefficients Relative Standard Deviation:5.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.289741 50.0 2819067.0 0.579483 Y 2 IC 280-671165/40 1.0 0.632153 50.0 2846226.0 0.632153 Y 3 IC 280-671165/41 2.0 1.263825 50.0 2813838.0 0.631913 Y 4 IC 280-671165/42 5.0 2.77026 50.0 2845130.0 0.554052 Y 5 IC 280-671165/43 10.0 5.788018 50.0 2845836.0 0.578802 Y 6 ICIS 280-671165/44 50.0 29.019462 50.0 2943416.0 0.580389 Y 7 IC 280-671165/45 75.0 43.767537 50.0 2963788.0 0.583567 N 8 IC 280-671165/46 100.0 55.34675 50.0 3096526.0 0.553467 Y 9 IC 280-671165/47 200.0 115.677411 50.0 3148814.0 0.578387 Y RelResp = [0.5861]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 240 of 426 Calibration / trans-1,2-Dichloroethene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1928 Error Coefficients Relative Standard Deviation:5.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.105389 50.0 2819067.0 0.210779 Y 2 IC 280-671165/40 1.0 0.176075 50.0 2846226.0 0.176075 Y 3 IC 280-671165/41 2.0 0.388935 50.0 2813838.0 0.194467 Y 4 IC 280-671165/42 5.0 0.979832 50.0 2845130.0 0.195966 Y 5 IC 280-671165/43 10.0 1.967858 50.0 2845836.0 0.196786 Y 6 ICIS 280-671165/44 50.0 9.771215 50.0 2943416.0 0.195424 Y 7 IC 280-671165/45 75.0 14.256452 50.0 2963788.0 0.190086 N 8 IC 280-671165/46 100.0 18.065132 50.0 3096526.0 0.180651 Y 9 IC 280-671165/47 200.0 38.375798 50.0 3148814.0 0.191879 Y RelResp = [0.1928]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 241 of 426 Calibration / Hexane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.077 Error Coefficients Relative Standard Deviation:8.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.636541 50.0 647719.0 1.273083 Y 2 IC 280-671165/40 1.0 1.052874 50.0 667791.0 1.052874 Y 3 IC 280-671165/41 2.0 1.996736 50.0 645929.0 0.998368 Y 4 IC 280-671165/42 5.0 5.761008 50.0 653193.0 1.152202 Y 5 IC 280-671165/43 10.0 10.77781 50.0 646263.0 1.077781 Y 6 ICIS 280-671165/44 50.0 53.390305 50.0 691693.0 1.067806 Y 7 IC 280-671165/45 75.0 74.829334 50.0 677932.0 0.997724 N 8 IC 280-671165/46 100.0 98.02302 50.0 713816.0 0.98023 Y 9 IC 280-671165/47 200.0 202.223028 50.0 755636.0 1.011115 Y RelResp = [1.077]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 242 of 426 Calibration / Vinyl acetate Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3741 Error Coefficients Relative Standard Deviation:11.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 1.0 0.470546 50.0 2819067.0 0.470546 Y 2 IC 280-671165/40 2.0 0.752751 50.0 2846226.0 0.376376 Y 3 IC 280-671165/41 4.0 1.491912 50.0 2813838.0 0.372978 Y 4 IC 280-671165/42 10.0 3.618956 50.0 2845130.0 0.361896 Y 5 IC 280-671165/43 20.0 7.295044 50.0 2845836.0 0.364752 Y 6 ICIS 280-671165/44 100.0 37.751069 50.0 2943416.0 0.377511 Y 7 IC 280-671165/45 150.0 54.065422 50.0 2963788.0 0.360436 N 8 IC 280-671165/46 200.0 67.035236 50.0 3096526.0 0.335176 Y 9 IC 280-671165/47 400.0 133.539009 50.0 3148814.0 0.333848 Y RelResp = [0.3741]x Concentration 0 100 200 300 400 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 243 of 426 Calibration / 1,1-Dichloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3281 Error Coefficients Relative Standard Deviation:5.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.170571 50.0 2819067.0 0.341141 Y 2 IC 280-671165/40 1.0 0.354469 50.0 2846226.0 0.354469 Y 3 IC 280-671165/41 2.0 0.68602 50.0 2813838.0 0.34301 Y 4 IC 280-671165/42 5.0 1.658659 50.0 2845130.0 0.331732 Y 5 IC 280-671165/43 10.0 3.199078 50.0 2845836.0 0.319908 Y 6 ICIS 280-671165/44 50.0 16.103704 50.0 2943416.0 0.322074 Y 7 IC 280-671165/45 75.0 23.648689 50.0 2963788.0 0.315316 N 8 IC 280-671165/46 100.0 30.10711 50.0 3096526.0 0.301071 Y 9 IC 280-671165/47 200.0 62.239577 50.0 3148814.0 0.311198 Y RelResp = [0.3281]x Concentration 0 100 200 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 244 of 426 Calibration / 2-Butanone (MEK) Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2639 Error Coefficients Relative Standard Deviation:13.3 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 2.0 0.691346 50.0 2819067.0 0.345673 Y 2 IC 280-671165/40 4.0 1.050971 50.0 2846226.0 0.262743 Y 3 IC 280-671165/41 8.0 2.156521 50.0 2813838.0 0.269565 Y 4 IC 280-671165/42 20.0 5.157234 50.0 2845130.0 0.257862 Y 5 IC 280-671165/43 40.0 10.000242 50.0 2845836.0 0.250006 Y 6 ICIS 280-671165/44 200.0 50.686125 50.0 2943416.0 0.253431 Y 7 IC 280-671165/45 300.0 76.466772 50.0 2963788.0 0.254889 N 8 IC 280-671165/46 400.0 94.725896 50.0 3096526.0 0.236815 Y 9 IC 280-671165/47 800.0 188.21045 50.0 3148814.0 0.235263 Y RelResp = [0.2639]x Concentration 0 100 200 300 400 500 600 700 800 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 245 of 426 Calibration / 2,2-Dichloropropane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2105 Error Coefficients Relative Standard Deviation:8.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.087192 50.0 2819067.0 0.174384 Y 2 IC 280-671165/40 1.0 0.211947 50.0 2846226.0 0.211947 Y 3 IC 280-671165/41 2.0 0.414931 50.0 2813838.0 0.207466 Y 4 IC 280-671165/42 5.0 1.039197 50.0 2845130.0 0.207839 Y 5 IC 280-671165/43 10.0 2.073011 50.0 2845836.0 0.207301 Y 6 ICIS 280-671165/44 50.0 11.174278 50.0 2943416.0 0.223486 Y 7 IC 280-671165/45 75.0 16.512939 50.0 2963788.0 0.220173 N 8 IC 280-671165/46 100.0 21.759611 50.0 3096526.0 0.217596 Y 9 IC 280-671165/47 200.0 46.786123 50.0 3148814.0 0.233931 Y RelResp = [0.2105]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 246 of 426 Calibration / cis-1,2-Dichloroethene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2175 Error Coefficients Relative Standard Deviation:7.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.103048 50.0 2819067.0 0.206097 Y 2 IC 280-671165/40 1.0 0.241337 50.0 2846226.0 0.241337 Y 3 IC 280-671165/41 2.0 0.484427 50.0 2813838.0 0.242214 Y 4 IC 280-671165/42 5.0 1.061832 50.0 2845130.0 0.212366 Y 5 IC 280-671165/43 10.0 2.096888 50.0 2845836.0 0.209689 Y 6 ICIS 280-671165/44 50.0 10.73129 50.0 2943416.0 0.214626 Y 7 IC 280-671165/45 75.0 15.750553 50.0 2963788.0 0.210007 N 8 IC 280-671165/46 100.0 20.060901 50.0 3096526.0 0.200609 Y 9 IC 280-671165/47 200.0 42.690692 50.0 3148814.0 0.213453 Y RelResp = [0.2175]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 247 of 426 Calibration / sec-Butyl Alcohol Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.08048 Error Coefficients Relative Standard Deviation:6.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 12.0 1.033853 50.0 2819067.0 0.086154 Y 2 IC 280-671165/40 24.0 1.717819 50.0 2846226.0 0.071576 Y 3 IC 280-671165/41 48.0 3.82403 50.0 2813838.0 0.079667 Y 4 IC 280-671165/42 120.0 9.993463 50.0 2845130.0 0.083279 Y 5 IC 280-671165/43 240.0 19.112064 50.0 2845836.0 0.079634 Y 6 ICIS 280-671165/44 1200.0 102.549062 50.0 2943416.0 0.085458 Y 7 IC 280-671165/45 1800.0 161.101688 50.0 2963788.0 0.089501 N 8 IC 280-671165/46 2400.0 199.729746 50.0 3096526.0 0.083221 Y 9 IC 280-671165/47 4800.0 359.217058 50.0 3148814.0 0.074837 Y RelResp = [0.08048]x Concentration 0 1000 2000 3000 4000 5000 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 Page 248 of 426 Calibration / Chlorobromomethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.09914 Error Coefficients Relative Standard Deviation:14.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.062503 50.0 2819067.0 0.125006 Y 2 IC 280-671165/40 1.0 0.115416 50.0 2846226.0 0.115416 Y 3 IC 280-671165/41 2.0 0.200314 50.0 2813838.0 0.100157 Y 4 IC 280-671165/42 5.0 0.468537 50.0 2845130.0 0.093707 Y 5 IC 280-671165/43 10.0 0.932433 50.0 2845836.0 0.093243 Y 6 ICIS 280-671165/44 50.0 4.565138 50.0 2943416.0 0.091303 Y 7 IC 280-671165/45 75.0 6.749673 50.0 2963788.0 0.089996 N 8 IC 280-671165/46 100.0 8.507631 50.0 3096526.0 0.085076 Y 9 IC 280-671165/47 200.0 17.845163 50.0 3148814.0 0.089226 Y RelResp = [0.09914]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 249 of 426 Calibration / Tetrahydrofuran Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1654 Error Coefficients Relative Standard Deviation:4.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 1.0 0.161596 50.0 2819067.0 0.161596 Y 2 IC 280-671165/40 2.0 0.365431 50.0 2846226.0 0.182716 Y 3 IC 280-671165/41 4.0 0.682342 50.0 2813838.0 0.170586 Y 4 IC 280-671165/42 10.0 1.645549 50.0 2845130.0 0.164555 Y 5 IC 280-671165/43 20.0 3.251189 50.0 2845836.0 0.162559 Y 6 ICIS 280-671165/44 100.0 16.430127 50.0 2943416.0 0.164301 Y 7 IC 280-671165/45 150.0 25.227648 50.0 2963788.0 0.168184 N 8 IC 280-671165/46 200.0 31.354799 50.0 3096526.0 0.156774 Y 9 IC 280-671165/47 400.0 63.932293 50.0 3148814.0 0.159831 Y RelResp = [0.1654]x Concentration 0 100 200 300 400 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 250 of 426 Calibration / Chloroform Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3181 Error Coefficients Relative Standard Deviation:5.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.178481 50.0 2819067.0 0.356962 Y 2 IC 280-671165/40 1.0 0.325062 50.0 2846226.0 0.325062 Y 3 IC 280-671165/41 2.0 0.624076 50.0 2813838.0 0.312038 Y 4 IC 280-671165/42 5.0 1.615585 50.0 2845130.0 0.323117 Y 5 IC 280-671165/43 10.0 3.01588 50.0 2845836.0 0.301588 Y 6 ICIS 280-671165/44 50.0 15.850019 50.0 2943416.0 0.317 Y 7 IC 280-671165/45 75.0 23.577412 50.0 2963788.0 0.314365 N 8 IC 280-671165/46 100.0 29.81136 50.0 3096526.0 0.298114 Y 9 IC 280-671165/47 200.0 62.17298 50.0 3148814.0 0.310865 Y RelResp = [0.3181]x Concentration 0 100 200 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 251 of 426 Calibration / Dibromofluoromethane (Surr) Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2239 Error Coefficients Relative Standard Deviation:1.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 50.0 10.812655 50.0 2819067.0 0.216253 Y 2 IC 280-671165/40 50.0 11.141807 50.0 2846226.0 0.222836 Y 3 IC 280-671165/41 50.0 11.098418 50.0 2813838.0 0.221968 Y 4 IC 280-671165/42 50.0 11.165166 50.0 2845130.0 0.223303 Y 5 IC 280-671165/43 50.0 11.16382 50.0 2845836.0 0.223276 Y 6 ICIS 280-671165/44 50.0 11.361459 50.0 2943416.0 0.227229 Y 7 IC 280-671165/45 50.0 11.323364 50.0 2963788.0 0.226467 N 8 IC 280-671165/46 50.0 11.356049 50.0 3096526.0 0.227121 Y 9 IC 280-671165/47 50.0 11.465682 50.0 3148814.0 0.229314 Y RelResp = [0.2239]x Concentration 0 10 20 30 40 50 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ICIS 280-671165/44IC 280-671165/45IC 280-671165/46IC 280-671165/47 Page 252 of 426 Calibration / 1,1,1-Trichloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.246 Error Coefficients Relative Standard Deviation:3.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.124545 50.0 2819067.0 0.24909 Y 2 IC 280-671165/40 1.0 0.245571 50.0 2846226.0 0.245571 Y 3 IC 280-671165/41 2.0 0.472113 50.0 2813838.0 0.236057 Y 4 IC 280-671165/42 5.0 1.210894 50.0 2845130.0 0.242179 Y 5 IC 280-671165/43 10.0 2.404548 50.0 2845836.0 0.240455 Y 6 ICIS 280-671165/44 50.0 12.703777 50.0 2943416.0 0.254076 Y 7 IC 280-671165/45 75.0 18.538539 50.0 2963788.0 0.247181 N 8 IC 280-671165/46 100.0 24.201783 50.0 3096526.0 0.242018 Y 9 IC 280-671165/47 200.0 51.738639 50.0 3148814.0 0.258693 Y RelResp = [0.246]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Page 253 of 426 Calibration / Cyclohexane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3182 Error Coefficients Relative Standard Deviation:4.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.171919 50.0 2819067.0 0.343837 Y 2 IC 280-671165/40 1.0 0.329507 50.0 2846226.0 0.329507 Y 3 IC 280-671165/41 2.0 0.639482 50.0 2813838.0 0.319741 Y 4 IC 280-671165/42 5.0 1.574796 50.0 2845130.0 0.314959 Y 5 IC 280-671165/43 10.0 3.217877 50.0 2845836.0 0.321788 Y 6 ICIS 280-671165/44 50.0 15.836056 50.0 2943416.0 0.316721 Y 7 IC 280-671165/45 75.0 21.667694 50.0 2963788.0 0.288903 N 8 IC 280-671165/46 100.0 29.128013 50.0 3096526.0 0.29128 Y 9 IC 280-671165/47 200.0 61.534835 50.0 3148814.0 0.307674 Y RelResp = [0.3182]x Concentration 0 100 200 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 254 of 426 Calibration / 1,1-Dichloropropene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2656 Error Coefficients Relative Standard Deviation:7.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.124758 50.0 2819067.0 0.249515 Y 2 IC 280-671165/40 1.0 0.307811 50.0 2846226.0 0.307811 Y 3 IC 280-671165/41 2.0 0.527074 50.0 2813838.0 0.263537 Y 4 IC 280-671165/42 5.0 1.366546 50.0 2845130.0 0.273309 Y 5 IC 280-671165/43 10.0 2.603857 50.0 2845836.0 0.260386 Y 6 ICIS 280-671165/44 50.0 13.184969 50.0 2943416.0 0.263699 Y 7 IC 280-671165/45 75.0 18.945822 50.0 2963788.0 0.252611 N 8 IC 280-671165/46 100.0 24.522303 50.0 3096526.0 0.245223 Y 9 IC 280-671165/47 200.0 52.188237 50.0 3148814.0 0.260941 Y RelResp = [0.2656]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 255 of 426 Calibration / Carbon tetrachloride Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1812 Error Coefficients Relative Standard Deviation:7.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.08611 50.0 2819067.0 0.17222 Y 2 IC 280-671165/40 1.0 0.185403 50.0 2846226.0 0.185403 Y 3 IC 280-671165/41 2.0 0.335289 50.0 2813838.0 0.167645 Y 4 IC 280-671165/42 5.0 0.853968 50.0 2845130.0 0.170794 Y 5 IC 280-671165/43 10.0 1.706581 50.0 2845836.0 0.170658 Y 6 ICIS 280-671165/44 50.0 9.480736 50.0 2943416.0 0.189615 Y 7 IC 280-671165/45 75.0 14.070946 50.0 2963788.0 0.187613 N 8 IC 280-671165/46 100.0 18.75618 50.0 3096526.0 0.187562 Y 9 IC 280-671165/47 200.0 41.091249 50.0 3148814.0 0.205456 Y RelResp = [0.1812]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 256 of 426 Calibration / Isobutyl alcohol Curve Type:Linear Weighting:Conc_Sq Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:-0.3441 Slope:0.03216 Error Coefficients Relative Standard Deviation:9.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 12.5 0.019616 50.0 2819067.0 0.001569 Y 2 IC 280-671165/40 25.0 0.588639 50.0 2846226.0 0.023546 Y 3 IC 280-671165/41 50.0 1.375772 50.0 2813838.0 0.027515 Y 4 IC 280-671165/42 125.0 3.814272 50.0 2845130.0 0.030514 Y 5 IC 280-671165/43 250.0 6.858652 50.0 2845836.0 0.027435 Y 6 ICIS 280-671165/44 1250.0 39.625727 50.0 2943416.0 0.031701 Y 7 IC 280-671165/45 1875.0 62.585414 50.0 2963788.0 0.033379 N 8 IC 280-671165/46 2500.0 77.3517 50.0 3096526.0 0.030941 Y 9 IC 280-671165/47 5000.0 156.461798 50.0 3148814.0 0.031292 Y RelResp = [-0.3441] + [0.03216]x Concentration 0 1000 2000 3000 4000 5000 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Intercept = 10.7 Page 257 of 426 Calibration / 1,2-Dichloroethane-d4 (Surr) Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2448 Error Coefficients Relative Standard Deviation:1.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 50.0 12.107073 50.0 2819067.0 0.242141 Y 2 IC 280-671165/40 50.0 12.585473 50.0 2846226.0 0.251709 Y 3 IC 280-671165/41 50.0 12.086961 50.0 2813838.0 0.241739 Y 4 IC 280-671165/42 50.0 12.112522 50.0 2845130.0 0.24225 Y 5 IC 280-671165/43 50.0 11.945154 50.0 2845836.0 0.238903 Y 6 ICIS 280-671165/44 50.0 12.400507 50.0 2943416.0 0.24801 Y 7 IC 280-671165/45 50.0 12.211653 50.0 2963788.0 0.244233 N 8 IC 280-671165/46 50.0 12.209231 50.0 3096526.0 0.244185 Y 9 IC 280-671165/47 50.0 12.487464 50.0 3148814.0 0.249749 Y RelResp = [0.2448]x Concentration 0 10 20 30 40 50 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e IC 280-671165/40ICIS 280-671165/44IC 280-671165/47 Page 258 of 426 Calibration / Benzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.8262 Error Coefficients Relative Standard Deviation:7.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.450202 50.0 2819067.0 0.900404 Y 2 IC 280-671165/40 1.0 0.896327 50.0 2846226.0 0.896327 Y 3 IC 280-671165/41 2.0 1.783614 50.0 2813838.0 0.891807 Y 4 IC 280-671165/42 5.0 3.988218 50.0 2845130.0 0.797644 Y 5 IC 280-671165/43 10.0 8.084215 50.0 2845836.0 0.808421 Y 6 ICIS 280-671165/44 50.0 40.261825 50.0 2943416.0 0.805237 Y 7 IC 280-671165/45 75.0 58.071697 50.0 2963788.0 0.774289 N 8 IC 280-671165/46 100.0 74.466337 50.0 3096526.0 0.744663 Y 9 IC 280-671165/47 200.0 153.013786 50.0 3148814.0 0.765069 Y RelResp = [0.8262]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 259 of 426 Calibration / 1,2-Dichloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2479 Error Coefficients Relative Standard Deviation:10.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.150582 50.0 2819067.0 0.301163 Y 2 IC 280-671165/40 1.0 0.255215 50.0 2846226.0 0.255215 Y 3 IC 280-671165/41 2.0 0.535177 50.0 2813838.0 0.267588 Y 4 IC 280-671165/42 5.0 1.228925 50.0 2845130.0 0.245785 Y 5 IC 280-671165/43 10.0 2.337819 50.0 2845836.0 0.233782 Y 6 ICIS 280-671165/44 50.0 11.641813 50.0 2943416.0 0.232836 Y 7 IC 280-671165/45 75.0 17.243659 50.0 2963788.0 0.229915 N 8 IC 280-671165/46 100.0 22.02029 50.0 3096526.0 0.220203 Y 9 IC 280-671165/47 200.0 45.248147 50.0 3148814.0 0.226241 Y RelResp = [0.2479]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 260 of 426 Calibration / n-Heptane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1974 Error Coefficients Relative Standard Deviation:6.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.111881 50.0 2819067.0 0.223762 Y 2 IC 280-671165/40 1.0 0.207854 50.0 2846226.0 0.207854 Y 3 IC 280-671165/41 2.0 0.383249 50.0 2813838.0 0.191624 Y 4 IC 280-671165/42 5.0 0.940326 50.0 2845130.0 0.188065 Y 5 IC 280-671165/43 10.0 1.892748 50.0 2845836.0 0.189275 Y 6 ICIS 280-671165/44 50.0 9.865612 50.0 2943416.0 0.197312 Y 7 IC 280-671165/45 75.0 14.324996 50.0 2963788.0 0.191 N 8 IC 280-671165/46 100.0 18.402687 50.0 3096526.0 0.184027 Y 9 IC 280-671165/47 200.0 39.389291 50.0 3148814.0 0.196946 Y RelResp = [0.1974]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 261 of 426 Calibration / Trichloroethene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.8504 Error Coefficients Relative Standard Deviation:3.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.422019 50.0 647719.0 0.844039 Y 2 IC 280-671165/40 1.0 0.865615 50.0 667791.0 0.865615 Y 3 IC 280-671165/41 2.0 1.820324 50.0 645929.0 0.910162 Y 4 IC 280-671165/42 5.0 4.310135 50.0 653193.0 0.862027 Y 5 IC 280-671165/43 10.0 8.482537 50.0 646263.0 0.848254 Y 6 ICIS 280-671165/44 50.0 42.166901 50.0 691693.0 0.843338 Y 7 IC 280-671165/45 75.0 63.444711 50.0 677932.0 0.845929 N 8 IC 280-671165/46 100.0 80.553042 50.0 713816.0 0.80553 Y 9 IC 280-671165/47 200.0 164.896392 50.0 755636.0 0.824482 Y RelResp = [0.8504]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 262 of 426 Calibration / 2-Pentanone Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3706 Error Coefficients Relative Standard Deviation:5.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 1.6 0.654702 50.0 2819067.0 0.409189 Y 2 IC 280-671165/40 3.2 1.177384 50.0 2846226.0 0.367932 Y 3 IC 280-671165/41 6.4 2.418441 50.0 2813838.0 0.377881 Y 4 IC 280-671165/42 16.0 6.011729 50.0 2845130.0 0.375733 Y 5 IC 280-671165/43 32.0 11.618677 50.0 2845836.0 0.363084 Y 6 ICIS 280-671165/44 160.0 60.262056 50.0 2943416.0 0.376638 Y 7 IC 280-671165/45 240.0 90.598062 50.0 2963788.0 0.377492 N 8 IC 280-671165/46 320.0 112.750902 50.0 3096526.0 0.352347 Y 9 IC 280-671165/47 640.0 218.963378 50.0 3148814.0 0.34213 Y RelResp = [0.3706]x Concentration 0 100 200 300 400 500 600 700 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 263 of 426 Calibration / Methylcyclohexane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2446 Error Coefficients Relative Standard Deviation:11.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.156062 50.0 2819067.0 0.312125 Y 2 IC 280-671165/40 1.0 0.244183 50.0 2846226.0 0.244183 Y 3 IC 280-671165/41 2.0 0.50424 50.0 2813838.0 0.25212 Y 4 IC 280-671165/42 5.0 1.176396 50.0 2845130.0 0.235279 Y 5 IC 280-671165/43 10.0 2.302276 50.0 2845836.0 0.230228 Y 6 ICIS 280-671165/44 50.0 11.805552 50.0 2943416.0 0.236111 Y 7 IC 280-671165/45 75.0 16.286016 50.0 2963788.0 0.217147 N 8 IC 280-671165/46 100.0 21.633146 50.0 3096526.0 0.216331 Y 9 IC 280-671165/47 200.0 46.116411 50.0 3148814.0 0.230582 Y RelResp = [0.2446]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 264 of 426 Calibration / 1,2-Dichloropropane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1912 Error Coefficients Relative Standard Deviation:4.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.103279 50.0 2819067.0 0.206558 Y 2 IC 280-671165/40 1.0 0.194117 50.0 2846226.0 0.194117 Y 3 IC 280-671165/41 2.0 0.391814 50.0 2813838.0 0.195907 Y 4 IC 280-671165/42 5.0 0.912665 50.0 2845130.0 0.182533 Y 5 IC 280-671165/43 10.0 1.874985 50.0 2845836.0 0.187499 Y 6 ICIS 280-671165/44 50.0 9.602058 50.0 2943416.0 0.192041 Y 7 IC 280-671165/45 75.0 14.109899 50.0 2963788.0 0.188132 N 8 IC 280-671165/46 100.0 17.886254 50.0 3096526.0 0.178863 Y 9 IC 280-671165/47 200.0 38.398791 50.0 3148814.0 0.191994 Y RelResp = [0.1912]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Page 265 of 426 Calibration / 1,4-Dioxane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.01111 Error Coefficients Relative Standard Deviation:4.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 10.0 0.11534 50.0 2819067.0 0.011534 Y 2 IC 280-671165/40 20.0 0.228513 50.0 2846226.0 0.011426 Y 3 IC 280-671165/41 40.0 0.465805 50.0 2813838.0 0.011645 Y 4 IC 280-671165/42 100.0 1.138068 50.0 2845130.0 0.011381 Y 5 IC 280-671165/43 200.0 2.171734 50.0 2845836.0 0.010859 Y 6 ICIS 280-671165/44 1000.0 10.997613 50.0 2943416.0 0.010998 Y 7 IC 280-671165/45 1500.0 17.085517 50.0 2963788.0 0.01139 N 8 IC 280-671165/46 2000.0 21.096335 50.0 3096526.0 0.010548 Y 9 IC 280-671165/47 4000.0 42.051007 50.0 3148814.0 0.010513 Y RelResp = [0.01111]x Concentration 0 1000 2000 3000 4000 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 266 of 426 Calibration / Dibromomethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1205 Error Coefficients Relative Standard Deviation:8.3 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.070236 50.0 2819067.0 0.140472 Y 2 IC 280-671165/40 1.0 0.130278 50.0 2846226.0 0.130278 Y 3 IC 280-671165/41 2.0 0.236954 50.0 2813838.0 0.118477 Y 4 IC 280-671165/42 5.0 0.549079 50.0 2845130.0 0.109816 Y 5 IC 280-671165/43 10.0 1.160274 50.0 2845836.0 0.116027 Y 6 ICIS 280-671165/44 50.0 5.822945 50.0 2943416.0 0.116459 Y 7 IC 280-671165/45 75.0 8.793679 50.0 2963788.0 0.117249 N 8 IC 280-671165/46 100.0 11.323561 50.0 3096526.0 0.113236 Y 9 IC 280-671165/47 200.0 23.823922 50.0 3148814.0 0.11912 Y RelResp = [0.1205]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 267 of 426 Calibration / Dichlorobromomethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2036 Error Coefficients Relative Standard Deviation:5.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.104148 50.0 2819067.0 0.208296 Y 2 IC 280-671165/40 1.0 0.191903 50.0 2846226.0 0.191903 Y 3 IC 280-671165/41 2.0 0.395954 50.0 2813838.0 0.197977 Y 4 IC 280-671165/42 5.0 0.959482 50.0 2845130.0 0.191896 Y 5 IC 280-671165/43 10.0 1.95721 50.0 2845836.0 0.195721 Y 6 ICIS 280-671165/44 50.0 10.46974 50.0 2943416.0 0.209395 Y 7 IC 280-671165/45 75.0 16.078006 50.0 2963788.0 0.214373 N 8 IC 280-671165/46 100.0 20.874764 50.0 3096526.0 0.208748 Y 9 IC 280-671165/47 200.0 45.00342 50.0 3148814.0 0.225017 Y RelResp = [0.2036]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 268 of 426 Calibration / 2-Chloroethyl vinyl ether Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.06396 Error Coefficients Relative Standard Deviation:12.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.037796 50.0 2819067.0 0.075592 Y 2 IC 280-671165/40 1.0 0.067897 50.0 2846226.0 0.067897 Y 3 IC 280-671165/41 2.0 0.116798 50.0 2813838.0 0.058399 Y 4 IC 280-671165/42 5.0 0.299775 50.0 2845130.0 0.059955 Y 5 IC 280-671165/43 10.0 0.489557 50.0 2845836.0 0.048956 Y 6 ICIS 280-671165/44 50.0 3.249371 50.0 2943416.0 0.064987 Y 7 IC 280-671165/45 75.0 3.207787 50.0 2963788.0 0.04277 N 8 IC 280-671165/46 100.0 6.575304 50.0 3096526.0 0.065753 Y 9 IC 280-671165/47 200.0 14.020596 50.0 3148814.0 0.070103 Y RelResp = [0.06396]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 269 of 426 Calibration / cis-1,3-Dichloropropene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.131 Error Coefficients Relative Standard Deviation:6.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.550547 50.0 647719.0 1.101095 Y 2 IC 280-671165/40 1.0 1.083722 50.0 667791.0 1.083722 Y 3 IC 280-671165/41 2.0 2.199468 50.0 645929.0 1.099734 Y 4 IC 280-671165/42 5.0 5.204894 50.0 653193.0 1.040979 Y 5 IC 280-671165/43 10.0 10.967129 50.0 646263.0 1.096713 Y 6 ICIS 280-671165/44 50.0 59.173434 50.0 691693.0 1.183469 Y 7 IC 280-671165/45 75.0 93.559974 50.0 677932.0 1.247466 N 8 IC 280-671165/46 100.0 120.241561 50.0 713816.0 1.202416 Y 9 IC 280-671165/47 200.0 247.817203 50.0 755636.0 1.239086 Y RelResp = [1.131]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 270 of 426 Calibration / 4-Methyl-2-pentanone (MIBK) Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3481 Error Coefficients Relative Standard Deviation:4.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 2.0 0.73441 50.0 2819067.0 0.367205 Y 2 IC 280-671165/40 4.0 1.35822 50.0 2846226.0 0.339555 Y 3 IC 280-671165/41 8.0 2.83801 50.0 2813838.0 0.354751 Y 4 IC 280-671165/42 20.0 7.213695 50.0 2845130.0 0.360685 Y 5 IC 280-671165/43 40.0 13.915243 50.0 2845836.0 0.347881 Y 6 ICIS 280-671165/44 200.0 71.637003 50.0 2943416.0 0.358185 Y 7 IC 280-671165/45 300.0 107.411681 50.0 2963788.0 0.358039 N 8 IC 280-671165/46 400.0 134.265674 50.0 3096526.0 0.335664 Y 9 IC 280-671165/47 800.0 256.577127 50.0 3148814.0 0.320721 Y RelResp = [0.3481]x Concentration 0 100 200 300 400 500 600 700 800 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 271 of 426 Calibration / Toluene-d8 (Surr) Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:4.272 Error Coefficients Relative Standard Deviation:1.3 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 50.0 215.237317 50.0 647719.0 4.304746 Y 2 IC 280-671165/40 50.0 211.240643 50.0 667791.0 4.224813 Y 3 IC 280-671165/41 50.0 215.512696 50.0 645929.0 4.310254 Y 4 IC 280-671165/42 50.0 214.44175 50.0 653193.0 4.288835 Y 5 IC 280-671165/43 50.0 216.893896 50.0 646263.0 4.337878 Y 6 ICIS 280-671165/44 50.0 210.007402 50.0 691693.0 4.200148 Y 7 IC 280-671165/45 50.0 217.39555 50.0 677932.0 4.347911 N 8 IC 280-671165/46 50.0 215.429607 50.0 713816.0 4.308592 Y 9 IC 280-671165/47 50.0 209.848062 50.0 755636.0 4.196961 Y RelResp = [4.272]x Concentration 0 10 20 30 40 50 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13IC 280-671165/41IC 280-671165/42IC 280-671165/43IC 280-671165/45IC 280-671165/46 Page 272 of 426 Calibration / Toluene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.8801 Error Coefficients Relative Standard Deviation:6.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.500893 50.0 2819067.0 1.001785 Y 2 IC 280-671165/40 1.0 0.888545 50.0 2846226.0 0.888545 Y 3 IC 280-671165/41 2.0 1.795253 50.0 2813838.0 0.897626 Y 4 IC 280-671165/42 5.0 4.443945 50.0 2845130.0 0.888789 Y 5 IC 280-671165/43 10.0 8.605784 50.0 2845836.0 0.860578 Y 6 ICIS 280-671165/44 50.0 43.258768 50.0 2943416.0 0.865175 Y 7 IC 280-671165/45 75.0 63.684008 50.0 2963788.0 0.84912 N 8 IC 280-671165/46 100.0 80.426985 50.0 3096526.0 0.80427 Y 9 IC 280-671165/47 200.0 166.777047 50.0 3148814.0 0.833885 Y RelResp = [0.8801]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 273 of 426 Calibration / trans-1,3-Dichloropropene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2172 Error Coefficients Relative Standard Deviation:14.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.094127 50.0 2819067.0 0.188254 Y 2 IC 280-671165/40 1.0 0.176479 50.0 2846226.0 0.176479 Y 3 IC 280-671165/41 2.0 0.398104 50.0 2813838.0 0.199052 Y 4 IC 280-671165/42 5.0 1.021113 50.0 2845130.0 0.204223 Y 5 IC 280-671165/43 10.0 2.135137 50.0 2845836.0 0.213514 Y 6 ICIS 280-671165/44 50.0 12.235392 50.0 2943416.0 0.244708 Y 7 IC 280-671165/45 75.0 18.580968 50.0 2963788.0 0.247746 N 8 IC 280-671165/46 100.0 24.379078 50.0 3096526.0 0.243791 Y 9 IC 280-671165/47 200.0 53.439898 50.0 3148814.0 0.267199 Y RelResp = [0.2172]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 274 of 426 Calibration / Ethyl methacrylate Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.352 Error Coefficients Relative Standard Deviation:3.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.718599 50.0 647719.0 1.437197 Y 2 IC 280-671165/40 1.0 1.410771 50.0 667791.0 1.410771 Y 3 IC 280-671165/41 2.0 2.666082 50.0 645929.0 1.333041 Y 4 IC 280-671165/42 5.0 6.585879 50.0 653193.0 1.317176 Y 5 IC 280-671165/43 10.0 12.934131 50.0 646263.0 1.293413 Y 6 ICIS 280-671165/44 50.0 67.363628 50.0 691693.0 1.347273 Y 7 IC 280-671165/45 75.0 104.634019 50.0 677932.0 1.39512 N 8 IC 280-671165/46 100.0 132.608053 50.0 713816.0 1.326081 Y 9 IC 280-671165/47 200.0 270.606681 50.0 755636.0 1.353033 Y RelResp = [1.352]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Page 275 of 426 Calibration / 1,1,2-Trichloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1889 Error Coefficients Relative Standard Deviation:6.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.109132 50.0 2819067.0 0.218264 Y 2 IC 280-671165/40 1.0 0.18463 50.0 2846226.0 0.18463 Y 3 IC 280-671165/41 2.0 0.369371 50.0 2813838.0 0.184685 Y 4 IC 280-671165/42 5.0 0.937567 50.0 2845130.0 0.187513 Y 5 IC 280-671165/43 10.0 1.86938 50.0 2845836.0 0.186938 Y 6 ICIS 280-671165/44 50.0 9.33937 50.0 2943416.0 0.186787 Y 7 IC 280-671165/45 75.0 13.680584 50.0 2963788.0 0.182408 N 8 IC 280-671165/46 100.0 17.641867 50.0 3096526.0 0.176419 Y 9 IC 280-671165/47 200.0 37.265602 50.0 3148814.0 0.186328 Y RelResp = [0.1889]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 276 of 426 Calibration / Tetrachloroethene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6752 Error Coefficients Relative Standard Deviation:7.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.392145 50.0 647719.0 0.784291 Y 2 IC 280-671165/40 1.0 0.716467 50.0 667791.0 0.716467 Y 3 IC 280-671165/41 2.0 1.334976 50.0 645929.0 0.667488 Y 4 IC 280-671165/42 5.0 3.280118 50.0 653193.0 0.656024 Y 5 IC 280-671165/43 10.0 6.559404 50.0 646263.0 0.65594 Y 6 ICIS 280-671165/44 50.0 32.71661 50.0 691693.0 0.654332 Y 7 IC 280-671165/45 75.0 48.932268 50.0 677932.0 0.65243 N 8 IC 280-671165/46 100.0 62.931274 50.0 713816.0 0.629313 Y 9 IC 280-671165/47 200.0 127.564065 50.0 755636.0 0.63782 Y RelResp = [0.6752]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 277 of 426 Calibration / 1,3-Dichloropropane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.402 Error Coefficients Relative Standard Deviation:6.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.793245 50.0 647719.0 1.58649 Y 2 IC 280-671165/40 1.0 1.430612 50.0 667791.0 1.430612 Y 3 IC 280-671165/41 2.0 2.897068 50.0 645929.0 1.448534 Y 4 IC 280-671165/42 5.0 6.968538 50.0 653193.0 1.393708 Y 5 IC 280-671165/43 10.0 14.257972 50.0 646263.0 1.425797 Y 6 ICIS 280-671165/44 50.0 67.044773 50.0 691693.0 1.340895 Y 7 IC 280-671165/45 75.0 102.84859 50.0 677932.0 1.371315 N 8 IC 280-671165/46 100.0 129.172574 50.0 713816.0 1.291726 Y 9 IC 280-671165/47 200.0 260.113732 50.0 755636.0 1.300569 Y RelResp = [1.402]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 278 of 426 Calibration / 2-Hexanone Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.327 Error Coefficients Relative Standard Deviation:5.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 2.0 2.784309 50.0 647719.0 1.392155 Y 2 IC 280-671165/40 4.0 5.432912 50.0 667791.0 1.358228 Y 3 IC 280-671165/41 8.0 10.626168 50.0 645929.0 1.328271 Y 4 IC 280-671165/42 20.0 28.39467 50.0 653193.0 1.419734 Y 5 IC 280-671165/43 40.0 53.932842 50.0 646263.0 1.348321 Y 6 ICIS 280-671165/44 200.0 262.876956 50.0 691693.0 1.314385 Y 7 IC 280-671165/45 300.0 411.833856 50.0 677932.0 1.37278 N 8 IC 280-671165/46 400.0 508.872945 50.0 713816.0 1.272182 Y 9 IC 280-671165/47 800.0 943.060548 50.0 755636.0 1.178826 Y RelResp = [1.327]x Concentration 0 100 200 300 400 500 600 700 800 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 279 of 426 Calibration / Chlorodibromomethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6062 Error Coefficients Relative Standard Deviation:13.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.245091 50.0 647719.0 0.490182 Y 2 IC 280-671165/40 1.0 0.532502 50.0 667791.0 0.532502 Y 3 IC 280-671165/41 2.0 1.206479 50.0 645929.0 0.60324 Y 4 IC 280-671165/42 5.0 2.71765 50.0 653193.0 0.54353 Y 5 IC 280-671165/43 10.0 5.944097 50.0 646263.0 0.59441 Y 6 ICIS 280-671165/44 50.0 33.222759 50.0 691693.0 0.664455 Y 7 IC 280-671165/45 75.0 53.160199 50.0 677932.0 0.708803 N 8 IC 280-671165/46 100.0 69.181764 50.0 713816.0 0.691818 Y 9 IC 280-671165/47 200.0 145.839664 50.0 755636.0 0.729198 Y RelResp = [0.6062]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 280 of 426 Calibration / Ethylene Dibromide Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.8362 Error Coefficients Relative Standard Deviation:5.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.46216 50.0 647719.0 0.924321 Y 2 IC 280-671165/40 1.0 0.784527 50.0 667791.0 0.784527 Y 3 IC 280-671165/41 2.0 1.703206 50.0 645929.0 0.851603 Y 4 IC 280-671165/42 5.0 3.994685 50.0 653193.0 0.798937 Y 5 IC 280-671165/43 10.0 8.350625 50.0 646263.0 0.835063 Y 6 ICIS 280-671165/44 50.0 41.892357 50.0 691693.0 0.837847 Y 7 IC 280-671165/45 75.0 64.65796 50.0 677932.0 0.862106 N 8 IC 280-671165/46 100.0 82.348182 50.0 713816.0 0.823482 Y 9 IC 280-671165/47 200.0 166.822319 50.0 755636.0 0.834112 Y RelResp = [0.8362]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 281 of 426 Calibration / 1-Chlorohexane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.208 Error Coefficients Relative Standard Deviation:10.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.4 1.413576 50.0 647719.0 3.53394 N 2 IC 280-671165/40 0.8 1.106858 50.0 667791.0 1.383573 Y 3 IC 280-671165/41 1.6 2.240339 50.0 645929.0 1.400212 Y 4 IC 280-671165/42 4.0 4.805394 50.0 653193.0 1.201349 Y 5 IC 280-671165/43 8.0 9.186043 50.0 646263.0 1.148255 Y 6 ICIS 280-671165/44 40.0 45.499304 50.0 691693.0 1.137483 Y 7 IC 280-671165/45 60.0 66.910546 50.0 677932.0 1.115176 N 8 IC 280-671165/46 80.0 86.577493 50.0 713816.0 1.082219 Y 9 IC 280-671165/47 160.0 176.993222 50.0 755636.0 1.106208 Y RelResp = [1.208]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 282 of 426 Calibration / Chlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.359 Error Coefficients Relative Standard Deviation:6.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.305504 50.0 647719.0 2.611009 Y 2 IC 280-671165/40 1.0 2.478994 50.0 667791.0 2.478994 Y 3 IC 280-671165/41 2.0 4.9226 50.0 645929.0 2.4613 Y 4 IC 280-671165/42 5.0 11.811823 50.0 653193.0 2.362365 Y 5 IC 280-671165/43 10.0 23.348699 50.0 646263.0 2.33487 Y 6 ICIS 280-671165/44 50.0 112.826861 50.0 691693.0 2.256537 Y 7 IC 280-671165/45 75.0 172.701171 50.0 677932.0 2.302682 N 8 IC 280-671165/46 100.0 218.741665 50.0 713816.0 2.187417 Y 9 IC 280-671165/47 200.0 436.143725 50.0 755636.0 2.180719 Y RelResp = [2.359]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 283 of 426 Calibration / 1,1,1,2-Tetrachloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6248 Error Coefficients Relative Standard Deviation:10.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.296116 50.0 647719.0 0.592232 Y 2 IC 280-671165/40 1.0 0.505847 50.0 667791.0 0.505847 Y 3 IC 280-671165/41 2.0 1.256407 50.0 645929.0 0.628204 Y 4 IC 280-671165/42 5.0 2.872045 50.0 653193.0 0.574409 Y 5 IC 280-671165/43 10.0 6.440644 50.0 646263.0 0.644064 Y 6 ICIS 280-671165/44 50.0 33.331117 50.0 691693.0 0.666622 Y 7 IC 280-671165/45 75.0 53.49718 50.0 677932.0 0.713296 N 8 IC 280-671165/46 100.0 67.455339 50.0 713816.0 0.674553 Y 9 IC 280-671165/47 200.0 142.468464 50.0 755636.0 0.712342 Y RelResp = [0.6248]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 284 of 426 Calibration / Ethylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.348 Error Coefficients Relative Standard Deviation:7.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.769701 50.0 647719.0 1.539402 Y 2 IC 280-671165/40 1.0 1.383666 50.0 667791.0 1.383666 Y 3 IC 280-671165/41 2.0 2.819815 50.0 645929.0 1.409907 Y 4 IC 280-671165/42 5.0 6.410586 50.0 653193.0 1.282117 Y 5 IC 280-671165/43 10.0 13.468278 50.0 646263.0 1.346828 Y 6 ICIS 280-671165/44 50.0 64.908782 50.0 691693.0 1.298176 Y 7 IC 280-671165/45 75.0 98.748031 50.0 677932.0 1.31664 N 8 IC 280-671165/46 100.0 124.089051 50.0 713816.0 1.240891 Y 9 IC 280-671165/47 200.0 256.366954 50.0 755636.0 1.281835 Y RelResp = [1.348]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 285 of 426 Calibration / m-Xylene & p-Xylene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.58 Error Coefficients Relative Standard Deviation:3.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.749399 50.0 647719.0 1.498798 Y 2 IC 280-671165/40 1.0 1.591366 50.0 667791.0 1.591366 Y 3 IC 280-671165/41 2.0 3.363141 50.0 645929.0 1.68157 Y 4 IC 280-671165/42 5.0 7.995646 50.0 653193.0 1.599129 Y 5 IC 280-671165/43 10.0 16.134608 50.0 646263.0 1.613461 Y 6 ICIS 280-671165/44 50.0 78.979981 50.0 691693.0 1.5796 Y 7 IC 280-671165/45 75.0 118.677094 50.0 677932.0 1.582361 N 8 IC 280-671165/46 100.0 153.272202 50.0 713816.0 1.532722 Y 9 IC 280-671165/47 200.0 308.326562 50.0 755636.0 1.541633 Y RelResp = [1.58]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 286 of 426 Calibration / o-Xylene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.563 Error Coefficients Relative Standard Deviation:6.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.868509 50.0 647719.0 1.737019 Y 2 IC 280-671165/40 1.0 1.671331 50.0 667791.0 1.671331 Y 3 IC 280-671165/41 2.0 3.143921 50.0 645929.0 1.571961 Y 4 IC 280-671165/42 5.0 7.621867 50.0 653193.0 1.524373 Y 5 IC 280-671165/43 10.0 15.299576 50.0 646263.0 1.529958 Y 6 ICIS 280-671165/44 50.0 75.670926 50.0 691693.0 1.513419 Y 7 IC 280-671165/45 75.0 116.214163 50.0 677932.0 1.549522 N 8 IC 280-671165/46 100.0 146.854371 50.0 713816.0 1.468544 Y 9 IC 280-671165/47 200.0 297.056982 50.0 755636.0 1.485285 Y RelResp = [1.563]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 287 of 426 Calibration / Styrene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.547 Error Coefficients Relative Standard Deviation:7.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.485521 50.0 647719.0 2.971041 Y 2 IC 280-671165/40 1.0 2.412207 50.0 667791.0 2.412207 Y 3 IC 280-671165/41 2.0 5.140348 50.0 645929.0 2.570174 Y 4 IC 280-671165/42 5.0 12.29782 50.0 653193.0 2.459564 Y 5 IC 280-671165/43 10.0 25.367149 50.0 646263.0 2.536715 Y 6 ICIS 280-671165/44 50.0 126.002143 50.0 691693.0 2.520043 Y 7 IC 280-671165/45 75.0 193.730271 50.0 677932.0 2.58307 N 8 IC 280-671165/46 100.0 244.858689 50.0 713816.0 2.448587 Y 9 IC 280-671165/47 200.0 492.032341 50.0 755636.0 2.460162 Y RelResp = [2.547]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 288 of 426 Calibration / Bromoform Curve Type:Linear Weighting:Conc Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:-0.3657 Slope:0.4782 Error Coefficients Relative Standard Deviation:19.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.159174 50.0 647719.0 0.318348 N 2 IC 280-671165/40 1.0 0.264679 50.0 667791.0 0.264679 Y 3 IC 280-671165/41 2.0 0.708979 50.0 645929.0 0.354489 Y 4 IC 280-671165/42 5.0 1.549006 50.0 653193.0 0.309801 Y 5 IC 280-671165/43 10.0 3.621049 50.0 646263.0 0.362105 Y 6 ICIS 280-671165/44 50.0 21.446292 50.0 691693.0 0.428926 Y 7 IC 280-671165/45 75.0 35.524433 50.0 677932.0 0.473659 N 8 IC 280-671165/46 100.0 45.480838 50.0 713816.0 0.454808 Y 9 IC 280-671165/47 200.0 100.36241 50.0 755636.0 0.501812 Y RelResp = [-0.3657] + [0.4782]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Intercept = 0.765 Page 289 of 426 Calibration / Isopropylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.253 Error Coefficients Relative Standard Deviation:6.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.257359 50.0 1011286.0 2.514719 Y 2 IC 280-671165/40 1.0 2.288506 50.0 1042842.0 2.288506 Y 3 IC 280-671165/41 2.0 4.459454 50.0 1011144.0 2.229727 Y 4 IC 280-671165/42 5.0 11.341377 50.0 1025819.0 2.268275 Y 5 IC 280-671165/43 10.0 23.036726 50.0 1015867.0 2.303673 Y 6 ICIS 280-671165/44 50.0 112.406742 50.0 1088110.0 2.248135 Y 7 IC 280-671165/45 75.0 164.59855 50.0 1093523.0 2.194647 N 8 IC 280-671165/46 100.0 210.43166 50.0 1137029.0 2.104317 Y 9 IC 280-671165/47 200.0 413.745163 50.0 1194773.0 2.068726 Y RelResp = [2.253]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 290 of 426 Calibration / Cyclohexanone Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1963 Error Coefficients Relative Standard Deviation:5.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 15.0 3.012958 50.0 647719.0 0.200864 Y 2 IC 280-671165/40 30.0 5.84629 50.0 667791.0 0.194876 Y 3 IC 280-671165/41 60.0 12.378837 50.0 645929.0 0.206314 Y 4 IC 280-671165/42 150.0 31.373729 50.0 653193.0 0.209158 Y 5 IC 280-671165/43 300.0 60.463697 50.0 646263.0 0.201546 Y 6 ICIS 280-671165/44 1500.0 291.288693 50.0 691693.0 0.194192 Y 7 IC 280-671165/45 2250.0 469.759873 50.0 677932.0 0.208782 N 8 IC 280-671165/46 3000.0 569.455014 50.0 713816.0 0.189818 Y 9 IC 280-671165/47 6000.0 1040.431769 50.0 755636.0 0.173405 Y RelResp = [0.1963]x Concentration 0 1000 2000 3000 4000 5000 6000 0.0 0.2 0.4 0.6 0.8 1.0 Re l a t i v e R e s p o n s e ( X 1 0 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 291 of 426 Calibration / 4-Bromofluorobenzene (Surr) Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.9285 Error Coefficients Relative Standard Deviation:1.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 50.0 46.967574 50.0 1011286.0 0.939351 Y 2 IC 280-671165/40 50.0 46.028641 50.0 1042842.0 0.920573 Y 3 IC 280-671165/41 50.0 47.117572 50.0 1011144.0 0.942351 Y 4 IC 280-671165/42 50.0 46.782376 50.0 1025819.0 0.935648 Y 5 IC 280-671165/43 50.0 47.472651 50.0 1015867.0 0.949453 Y 6 ICIS 280-671165/44 50.0 45.953856 50.0 1088110.0 0.919077 Y 7 IC 280-671165/45 50.0 46.502908 50.0 1093523.0 0.930058 N 8 IC 280-671165/46 50.0 45.990692 50.0 1137029.0 0.919814 Y 9 IC 280-671165/47 50.0 45.070821 50.0 1194773.0 0.901416 Y RelResp = [0.9285]x Concentration 0 10 20 30 40 50 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e IC 280-671165/13IC 280-671165/41IC 280-671165/42IC 280-671165/43IC 280-671165/45 Page 292 of 426 Calibration / 1,1,2,2-Tetrachloroethane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.8359 Error Coefficients Relative Standard Deviation:7.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.47583 50.0 1011286.0 0.95166 Y 2 IC 280-671165/40 1.0 0.757593 50.0 1042842.0 0.757593 Y 3 IC 280-671165/41 2.0 1.786936 50.0 1011144.0 0.893468 Y 4 IC 280-671165/42 5.0 4.212634 50.0 1025819.0 0.842527 Y 5 IC 280-671165/43 10.0 8.422067 50.0 1015867.0 0.842207 Y 6 ICIS 280-671165/44 50.0 40.92578 50.0 1088110.0 0.818516 Y 7 IC 280-671165/45 75.0 62.040259 50.0 1093523.0 0.827203 N 8 IC 280-671165/46 100.0 78.60314 50.0 1137029.0 0.786031 Y 9 IC 280-671165/47 200.0 159.104114 50.0 1194773.0 0.795521 Y RelResp = [0.8359]x Concentration 0 100 200 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 293 of 426 Calibration / Bromobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6009 Error Coefficients Relative Standard Deviation:9.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.360432 50.0 1011286.0 0.720864 Y 2 IC 280-671165/40 1.0 0.576549 50.0 1042842.0 0.576549 Y 3 IC 280-671165/41 2.0 1.313364 50.0 1011144.0 0.656682 Y 4 IC 280-671165/42 5.0 2.874143 50.0 1025819.0 0.574829 Y 5 IC 280-671165/43 10.0 5.791605 50.0 1015867.0 0.57916 Y 6 ICIS 280-671165/44 50.0 28.951623 50.0 1088110.0 0.579032 Y 7 IC 280-671165/45 75.0 42.571624 50.0 1093523.0 0.567622 N 8 IC 280-671165/46 100.0 55.096616 50.0 1137029.0 0.550966 Y 9 IC 280-671165/47 200.0 113.858951 50.0 1194773.0 0.569295 Y RelResp = [0.6009]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 294 of 426 Calibration / trans-1,4-Dichloro-2-butene Curve Type:Linear Weighting:Conc Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:-0.1264 Slope:0.1853 Error Coefficients Relative Standard Deviation:20.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.082469 50.0 1011286.0 0.164939 N 2 IC 280-671165/40 1.0 0.128687 50.0 1042842.0 0.128687 Y 3 IC 280-671165/41 2.0 0.258816 50.0 1011144.0 0.129408 Y 4 IC 280-671165/42 5.0 0.682869 50.0 1025819.0 0.136574 Y 5 IC 280-671165/43 10.0 1.330292 50.0 1015867.0 0.133029 Y 6 ICIS 280-671165/44 50.0 8.365928 50.0 1088110.0 0.167319 Y 7 IC 280-671165/45 75.0 13.729249 50.0 1093523.0 0.183057 N 8 IC 280-671165/46 100.0 17.524267 50.0 1137029.0 0.175243 Y 9 IC 280-671165/47 200.0 39.02959 50.0 1194773.0 0.195148 Y RelResp = [-0.1264] + [0.1853]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Intercept = 0.682 Page 295 of 426 Calibration / 1,2,3-Trichloropropane Curve Type:Linear Weighting:Conc Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.06112 Slope:0.2756 Error Coefficients Relative Standard Deviation:11.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.209239 50.0 1011286.0 0.418477 Y 2 IC 280-671165/40 1.0 0.270319 50.0 1042842.0 0.270319 Y 3 IC 280-671165/41 2.0 0.633787 50.0 1011144.0 0.316894 Y 4 IC 280-671165/42 5.0 1.512889 50.0 1025819.0 0.302578 Y 5 IC 280-671165/43 10.0 3.042623 50.0 1015867.0 0.304262 Y 6 ICIS 280-671165/44 50.0 14.002628 50.0 1088110.0 0.280053 Y 7 IC 280-671165/45 75.0 21.126259 50.0 1093523.0 0.281683 N 8 IC 280-671165/46 100.0 26.985679 50.0 1137029.0 0.269857 Y 9 IC 280-671165/47 200.0 55.402198 50.0 1194773.0 0.277011 Y RelResp = [0.06112] + [0.2756]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 IC 280-671165/47 Intercept = -0.222 Page 296 of 426 Calibration / N-Propylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.7062 Error Coefficients Relative Standard Deviation:8.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.408688 50.0 1011286.0 0.817375 Y 2 IC 280-671165/40 1.0 0.731367 50.0 1042842.0 0.731367 Y 3 IC 280-671165/41 2.0 1.528022 50.0 1011144.0 0.764011 Y 4 IC 280-671165/42 5.0 3.437205 50.0 1025819.0 0.687441 Y 5 IC 280-671165/43 10.0 6.887024 50.0 1015867.0 0.688702 Y 6 ICIS 280-671165/44 50.0 33.614478 50.0 1088110.0 0.67229 Y 7 IC 280-671165/45 75.0 49.872888 50.0 1093523.0 0.664972 N 8 IC 280-671165/46 100.0 63.727354 50.0 1137029.0 0.637274 Y 9 IC 280-671165/47 200.0 130.180587 50.0 1194773.0 0.650903 Y RelResp = [0.7062]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 297 of 426 Calibration / 2-Chlorotoluene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.573 Error Coefficients Relative Standard Deviation:5.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.285725 50.0 1011286.0 0.571451 Y 2 IC 280-671165/40 1.0 0.607714 50.0 1042842.0 0.607714 Y 3 IC 280-671165/41 2.0 1.243789 50.0 1011144.0 0.621895 Y 4 IC 280-671165/42 5.0 2.831347 50.0 1025819.0 0.566269 Y 5 IC 280-671165/43 10.0 5.782401 50.0 1015867.0 0.57824 Y 6 ICIS 280-671165/44 50.0 27.626481 50.0 1088110.0 0.55253 Y 7 IC 280-671165/45 75.0 41.790433 50.0 1093523.0 0.557206 N 8 IC 280-671165/46 100.0 53.930111 50.0 1137029.0 0.539301 Y 9 IC 280-671165/47 200.0 109.383163 50.0 1194773.0 0.546916 Y RelResp = [0.573]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 298 of 426 Calibration / 1,3,5-Trimethylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.971 Error Coefficients Relative Standard Deviation:5.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.088614 50.0 1011286.0 2.177228 Y 2 IC 280-671165/40 1.0 1.880151 50.0 1042842.0 1.880151 Y 3 IC 280-671165/41 2.0 4.1233 50.0 1011144.0 2.06165 Y 4 IC 280-671165/42 5.0 10.269648 50.0 1025819.0 2.05393 Y 5 IC 280-671165/43 10.0 19.371876 50.0 1015867.0 1.937188 Y 6 ICIS 280-671165/44 50.0 97.73465 50.0 1088110.0 1.954693 Y 7 IC 280-671165/45 75.0 144.962337 50.0 1093523.0 1.932831 N 8 IC 280-671165/46 100.0 186.987579 50.0 1137029.0 1.869876 Y 9 IC 280-671165/47 200.0 367.387069 50.0 1194773.0 1.836935 Y RelResp = [1.971]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 299 of 426 Calibration / 4-Chlorotoluene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6186 Error Coefficients Relative Standard Deviation:10.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.368936 50.0 1011286.0 0.737872 Y 2 IC 280-671165/40 1.0 0.669277 50.0 1042842.0 0.669277 Y 3 IC 280-671165/41 2.0 1.293733 50.0 1011144.0 0.646866 Y 4 IC 280-671165/42 5.0 2.850552 50.0 1025819.0 0.57011 Y 5 IC 280-671165/43 10.0 6.201156 50.0 1015867.0 0.620116 Y 6 ICIS 280-671165/44 50.0 29.030842 50.0 1088110.0 0.580617 Y 7 IC 280-671165/45 75.0 43.726241 50.0 1093523.0 0.583017 N 8 IC 280-671165/46 100.0 55.435042 50.0 1137029.0 0.55435 Y 9 IC 280-671165/47 200.0 113.954408 50.0 1194773.0 0.569772 Y RelResp = [0.6186]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 300 of 426 Calibration / tert-Butylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.711 Error Coefficients Relative Standard Deviation:5.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.924318 50.0 1011286.0 1.848636 Y 2 IC 280-671165/40 1.0 1.807465 50.0 1042842.0 1.807465 Y 3 IC 280-671165/41 2.0 3.562203 50.0 1011144.0 1.781101 Y 4 IC 280-671165/42 5.0 8.652404 50.0 1025819.0 1.730481 Y 5 IC 280-671165/43 10.0 16.738707 50.0 1015867.0 1.673871 Y 6 ICIS 280-671165/44 50.0 83.796307 50.0 1088110.0 1.675926 Y 7 IC 280-671165/45 75.0 124.317138 50.0 1093523.0 1.657562 N 8 IC 280-671165/46 100.0 159.965973 50.0 1137029.0 1.59966 Y 9 IC 280-671165/47 200.0 313.625643 50.0 1194773.0 1.568128 Y RelResp = [1.711]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 301 of 426 Calibration / 1,2,4-Trimethylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.057 Error Coefficients Relative Standard Deviation:7.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.175681 50.0 1011286.0 2.351363 Y 2 IC 280-671165/40 1.0 1.96909 50.0 1042842.0 1.96909 Y 3 IC 280-671165/41 2.0 4.350567 50.0 1011144.0 2.175284 Y 4 IC 280-671165/42 5.0 10.252881 50.0 1025819.0 2.050576 Y 5 IC 280-671165/43 10.0 20.664122 50.0 1015867.0 2.066412 Y 6 ICIS 280-671165/44 50.0 101.10986 50.0 1088110.0 2.022197 Y 7 IC 280-671165/45 75.0 151.477884 50.0 1093523.0 2.019705 N 8 IC 280-671165/46 100.0 193.816165 50.0 1137029.0 1.938162 Y 9 IC 280-671165/47 200.0 376.366473 50.0 1194773.0 1.881832 Y RelResp = [2.057]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 302 of 426 Calibration / sec-Butylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.4942 Error Coefficients Relative Standard Deviation:9.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.284193 50.0 1011286.0 0.568385 Y 2 IC 280-671165/40 1.0 0.429403 50.0 1042842.0 0.429403 Y 3 IC 280-671165/41 2.0 1.114579 50.0 1011144.0 0.55729 Y 4 IC 280-671165/42 5.0 2.468369 50.0 1025819.0 0.493674 Y 5 IC 280-671165/43 10.0 4.725028 50.0 1015867.0 0.472503 Y 6 ICIS 280-671165/44 50.0 24.314821 50.0 1088110.0 0.486296 Y 7 IC 280-671165/45 75.0 36.890399 50.0 1093523.0 0.491872 N 8 IC 280-671165/46 100.0 47.345978 50.0 1137029.0 0.47346 Y 9 IC 280-671165/47 200.0 94.566708 50.0 1194773.0 0.472834 Y RelResp = [0.4942]x Concentration 0 100 200 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 303 of 426 Calibration / 1,3-Dichlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.129 Error Coefficients Relative Standard Deviation:8.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.671027 50.0 1011286.0 1.342054 Y 2 IC 280-671165/40 1.0 1.079981 50.0 1042842.0 1.079981 Y 3 IC 280-671165/41 2.0 2.424333 50.0 1011144.0 1.212167 Y 4 IC 280-671165/42 5.0 5.513253 50.0 1025819.0 1.102651 Y 5 IC 280-671165/43 10.0 11.164257 50.0 1015867.0 1.116426 Y 6 ICIS 280-671165/44 50.0 54.224481 50.0 1088110.0 1.08449 Y 7 IC 280-671165/45 75.0 81.403272 50.0 1093523.0 1.085377 N 8 IC 280-671165/46 100.0 103.905617 50.0 1137029.0 1.039056 Y 9 IC 280-671165/47 200.0 210.694835 50.0 1194773.0 1.053474 Y RelResp = [1.129]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 304 of 426 Calibration / 4-Isopropyltoluene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.109 Error Coefficients Relative Standard Deviation:5.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.16342 50.0 1011286.0 2.326839 Y 2 IC 280-671165/40 1.0 2.033865 50.0 1042842.0 2.033865 Y 3 IC 280-671165/41 2.0 4.460344 50.0 1011144.0 2.230172 Y 4 IC 280-671165/42 5.0 10.578669 50.0 1025819.0 2.115734 Y 5 IC 280-671165/43 10.0 21.039368 50.0 1015867.0 2.103937 Y 6 ICIS 280-671165/44 50.0 105.422568 50.0 1088110.0 2.108451 Y 7 IC 280-671165/45 75.0 155.977606 50.0 1093523.0 2.079701 N 8 IC 280-671165/46 100.0 199.032171 50.0 1137029.0 1.990322 Y 9 IC 280-671165/47 200.0 392.100006 50.0 1194773.0 1.9605 Y RelResp = [2.109]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 305 of 426 Calibration / 1,4-Dichlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.156 Error Coefficients Relative Standard Deviation:8.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.66188 50.0 1011286.0 1.32376 Y 2 IC 280-671165/40 1.0 1.225593 50.0 1042842.0 1.225593 Y 3 IC 280-671165/41 2.0 2.539895 50.0 1011144.0 1.269948 Y 4 IC 280-671165/42 5.0 5.378629 50.0 1025819.0 1.075726 Y 5 IC 280-671165/43 10.0 11.182222 50.0 1015867.0 1.118222 Y 6 ICIS 280-671165/44 50.0 55.36182 50.0 1088110.0 1.107236 Y 7 IC 280-671165/45 75.0 82.671238 50.0 1093523.0 1.102283 N 8 IC 280-671165/46 100.0 105.891231 50.0 1137029.0 1.058912 Y 9 IC 280-671165/47 200.0 214.100545 50.0 1194773.0 1.070503 Y RelResp = [1.156]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 306 of 426 Calibration / n-Butylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.865 Error Coefficients Relative Standard Deviation:6.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.032596 50.0 1011286.0 2.065192 Y 2 IC 280-671165/40 1.0 1.88624 50.0 1042842.0 1.88624 Y 3 IC 280-671165/41 2.0 3.957695 50.0 1011144.0 1.978848 Y 4 IC 280-671165/42 5.0 9.105602 50.0 1025819.0 1.82112 Y 5 IC 280-671165/43 10.0 18.478797 50.0 1015867.0 1.84788 Y 6 ICIS 280-671165/44 50.0 91.930503 50.0 1088110.0 1.83861 Y 7 IC 280-671165/45 75.0 136.347064 50.0 1093523.0 1.817961 N 8 IC 280-671165/46 100.0 174.603946 50.0 1137029.0 1.746039 Y 9 IC 280-671165/47 200.0 346.845007 50.0 1194773.0 1.734225 Y RelResp = [1.865]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 307 of 426 Calibration / 1,2-Dichlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:1.079 Error Coefficients Relative Standard Deviation:7.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.620349 50.0 1011286.0 1.240697 Y 2 IC 280-671165/40 1.0 1.070632 50.0 1042842.0 1.070632 Y 3 IC 280-671165/41 2.0 2.331518 50.0 1011144.0 1.165759 Y 4 IC 280-671165/42 5.0 5.27247 50.0 1025819.0 1.054494 Y 5 IC 280-671165/43 10.0 10.593217 50.0 1015867.0 1.059322 Y 6 ICIS 280-671165/44 50.0 51.991389 50.0 1088110.0 1.039828 Y 7 IC 280-671165/45 75.0 77.388541 50.0 1093523.0 1.031847 N 8 IC 280-671165/46 100.0 99.227812 50.0 1137029.0 0.992278 Y 9 IC 280-671165/47 200.0 201.898227 50.0 1194773.0 1.009491 Y RelResp = [1.079]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 308 of 426 Calibration / 1,2-Dibromo-3-Chloropropane Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2288 Error Coefficients Relative Standard Deviation:10.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.107141 50.0 1011286.0 0.214282 Y 2 IC 280-671165/40 1.0 0.192503 50.0 1042842.0 0.192503 Y 3 IC 280-671165/41 2.0 0.454189 50.0 1011144.0 0.227094 Y 4 IC 280-671165/42 5.0 1.083719 50.0 1025819.0 0.216744 Y 5 IC 280-671165/43 10.0 2.164653 50.0 1015867.0 0.216465 Y 6 ICIS 280-671165/44 50.0 12.068908 50.0 1088110.0 0.241378 Y 7 IC 280-671165/45 75.0 19.196898 50.0 1093523.0 0.255959 N 8 IC 280-671165/46 100.0 25.093203 50.0 1137029.0 0.250932 Y 9 IC 280-671165/47 200.0 54.264241 50.0 1194773.0 0.271321 Y RelResp = [0.2288]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/47 Page 309 of 426 Calibration / 1,2,4-Trichlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6081 Error Coefficients Relative Standard Deviation:10.6 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.379962 50.0 1011286.0 0.759924 Y 2 IC 280-671165/40 1.0 0.628858 50.0 1042842.0 0.628858 Y 3 IC 280-671165/41 2.0 1.134161 50.0 1011144.0 0.56708 Y 4 IC 280-671165/42 5.0 2.980886 50.0 1025819.0 0.596177 Y 5 IC 280-671165/43 10.0 5.785452 50.0 1015867.0 0.578545 Y 6 ICIS 280-671165/44 50.0 29.387838 50.0 1088110.0 0.587757 Y 7 IC 280-671165/45 75.0 43.876306 50.0 1093523.0 0.585017 N 8 IC 280-671165/46 100.0 57.048765 50.0 1137029.0 0.570488 Y 9 IC 280-671165/47 200.0 115.197657 50.0 1194773.0 0.575988 Y RelResp = [0.6081]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 310 of 426 Calibration / Hexachlorobutadiene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2112 Error Coefficients Relative Standard Deviation:4.3 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.099972 50.0 1011286.0 0.199943 Y 2 IC 280-671165/40 1.0 0.204681 50.0 1042842.0 0.204681 Y 3 IC 280-671165/41 2.0 0.450579 50.0 1011144.0 0.225289 Y 4 IC 280-671165/42 5.0 1.081575 50.0 1025819.0 0.216315 Y 5 IC 280-671165/43 10.0 2.169871 50.0 1015867.0 0.216987 Y 6 ICIS 280-671165/44 50.0 10.833647 50.0 1088110.0 0.216673 Y 7 IC 280-671165/45 75.0 14.952086 50.0 1093523.0 0.199361 N 8 IC 280-671165/46 100.0 19.994345 50.0 1137029.0 0.199943 Y 9 IC 280-671165/47 200.0 42.018233 50.0 1194773.0 0.210091 Y RelResp = [0.2112]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 311 of 426 Calibration / Naphthalene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.385 Error Coefficients Relative Standard Deviation:5.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 1.328605 50.0 1011286.0 2.657211 Y 2 IC 280-671165/40 1.0 2.310705 50.0 1042842.0 2.310705 Y 3 IC 280-671165/41 2.0 5.082956 50.0 1011144.0 2.541478 Y 4 IC 280-671165/42 5.0 11.75802 50.0 1025819.0 2.351604 Y 5 IC 280-671165/43 10.0 23.046226 50.0 1015867.0 2.304623 Y 6 ICIS 280-671165/44 50.0 117.302754 50.0 1088110.0 2.346055 Y 7 IC 280-671165/45 75.0 181.602948 50.0 1093523.0 2.421373 N 8 IC 280-671165/46 100.0 230.701416 50.0 1137029.0 2.307014 Y 9 IC 280-671165/47 200.0 452.283865 50.0 1194773.0 2.261419 Y RelResp = [2.385]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 312 of 426 Calibration / 1,2,3-Trichlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.5424 Error Coefficients Relative Standard Deviation:3.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/13 0.5 0.271585 50.0 1011286.0 0.54317 Y 2 IC 280-671165/40 1.0 0.537569 50.0 1042842.0 0.537569 Y 3 IC 280-671165/41 2.0 1.175649 50.0 1011144.0 0.587824 Y 4 IC 280-671165/42 5.0 2.73752 50.0 1025819.0 0.547504 Y 5 IC 280-671165/43 10.0 5.230557 50.0 1015867.0 0.523056 Y 6 ICIS 280-671165/44 50.0 26.98877 50.0 1088110.0 0.539775 Y 7 IC 280-671165/45 75.0 40.986381 50.0 1093523.0 0.546485 N 8 IC 280-671165/46 100.0 52.790958 50.0 1137029.0 0.52791 Y 9 IC 280-671165/47 200.0 106.51358 50.0 1194773.0 0.532568 Y RelResp = [0.5424]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/13 IC 280-671165/40 IC 280-671165/41 IC 280-671165/42 IC 280-671165/43 ICIS 280-671165/44 IC 280-671165/45 IC 280-671165/46 Page 313 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98212Calibration Start Date:Calibration End Date:10/16/2024 04:36 N 10/16/2024 07:06 0.25(mm)DB-624 (60.25)ID: Calibration Files LEVEL:LAB SAMPLE ID:LAB FILE ID:1Level IC 280-671165/49 MS1_0309.D 2Level IC 280-671165/50 MS1_0310.D 3Level IC 280-671165/51 MS1_0311.D 4Level IC 280-671165/52 MS1_0312.D 5Level IC 280-671165/53 MS1_0313.D 6Level IC 280-671165/54 MS1_0314.D 7Level IC 280-671165/55 MS1_0315.D 8Level IC 280-671165/56 MS1_0316.D ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 Ethanol 0.0104 0.0101 0.0111 0.0100 0.0101 Ave 3.9 0.0100 0.0098 0.0106 15.00.010 3Isopropyl alcohol 0.0781 0.0653 0.0664 0.0601 0.0594 Ave 10.1 0.0593 0.0584 0.0639 15.00.063 9Acetonitrile0.0935 0.0758 0.0640 0.0673 0.0642 Lin2 0.9980 0.0627 0.0617 0.0655 0.99000.296 2 0.062 5Isopropyl ether 0.1665 0.1749 0.1562 0.1780 0.1759 Ave 4.7 0.1782 0.1755 0.1813 15.00.173 32-Chloro-1,3-butadiene 0.2771 0.2556 0.2259 0.2631 0.2722 Ave 6.1 0.2679 0.2596 0.2712 15.00.261 6Tert-butyl ethyl ether 0.5789 0.5320 0.5027 0.5473 0.5535 Ave 4.1 0.5480 0.5370 0.5576 15.00.544 7Ethyl acetate 0.4053 0.3452 0.3142 0.3458 0.3474 Ave 7.5 0.3435 0.3308 0.3461 15.00.347 3Propionitrile0.0841 0.0808 0.0782 0.0855 0.0831 Ave 3.2 0.0805 0.0785 0.0832 15.00.081 7Methacrylonitrile0.1921 0.1844 0.1711 0.1873 0.1829 Ave 7.8 0.1791 0.1698 0.1486 15.00.176 9Tert-amyl methyl ether 0.6001 0.5086 0.5158 0.5557 0.5588 Ave 5.4 0.5615 0.5371 0.5718 15.00.551 2n-Butanol 0.0272 0.0269 0.0339 0.0295 0.0309 Ave 8.8 0.0313 0.0312 0.0343 15.00.030 6Methyl methacrylate 0.0798 0.0829 0.0779 0.0847 0.0875 Ave 5.4 0.0884 0.0851 0.0920 15.00.084 82-Nitropropane +++++ 0.0442 0.0423 0.0434 0.0536 Qua 1.0000 0.0573 0.0608 0.0715 0.9900-0.09 5 0.049 9 0.0000547 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 314 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 CURVE EVALUATION SDG No.: Calibration ID: Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS1 98212Calibration Start Date:Calibration End Date:10/16/2024 04:36 N 10/16/2024 07:06 0.25(mm)DB-624 (60.25)ID: ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF /RSE /RSE LVL 6 LVL 7 LVL 8 cis-1,4-Dichloro-2-butene 0.0334 0.1205 0.1210 0.1182 0.1344 Lin1 0.9940 0.1386 0.1385 0.1604 0.9900-0.24 7 0.149 21,2,3-Trimethylbenzene 2.2232 2.0732 2.1221 2.1192 2.0911 Ave 2.7 2.1026 2.0276 2.0757 15.02.104 31,3,5-Trichlorobenzene 0.6776 0.5973 0.6595 0.6612 0.6527 Ave 4.4 0.6441 0.6386 0.6945 15.00.653 2 FORM VI 8260D Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types. Page 315 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98212Calibration Start Date:Calibration End Date:10/16/2024 04:36 N 10/16/2024 07:06 GC Column:DB-624 (60.25)ID:0.25(mm) Calibration Files: LEVEL: LAB SAMPLE ID:LAB FILE ID: Level 1 IC 280-671165/49 MS1_0309.D Level 2 IC 280-671165/50 MS1_0310.D Level 3 IC 280-671165/51 MS1_0311.D Level 4 IC 280-671165/52 MS1_0312.D Level 5 IC 280-671165/53 MS1_0313.D Level 6 IC 280-671165/54 MS1_0314.D Level 7 IC 280-671165/55 MS1_0315.D Level 8 IC 280-671165/56 MS1_0316.D ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8 Ethanol AveFB 36549 72974 199094 364623 1820113 60.0 120 300 600 3000 2774123 120006000450078802303715484 Isopropyl alcohol AveFB 45913 78394 199319 364741 1780701 10.0 20.0 50.0 100 500 2755180 2000100075079313393684982 Acetonitrile Lin2FB 55006 91021 192058 407924 1924711 10.0 20.0 50.0 100 500 2912149 2000100075081337043888286 Isopropyl ether AveFB 9795 20987 46886 107956 527516 1.00 2.00 5.00 10.0 50.0 827452 20010075.022499461106593 2-Chloro-1,3-butadiene AveFB 16296 30668 67816 159583 816252 1.00 2.00 5.00 10.0 50.0 1244077 20010075.033651141636825 Tert-butyl ethyl ether AveFB 34049 63847 150939 332003 1659465 1.00 2.00 5.00 10.0 50.0 2545190 20010075.069195133386018 Ethyl acetate AveFB 47675 82860 188659 419479 2083452 2.00 4.00 10.0 20.0 100 3190995 40020015085896274171342 Propionitrile AveFB 49466 96963 234749 518330 2490079 10.0 20.0 50.0 100 500 3737050 20001000750103299634947469 Methacrylonitrile AveFB 112997 221248 513598 1136186 5483202 10.0 20.0 50.0 100 500 8318020 200010007501843486210709000 Tert-amyl methyl ether AveFB 35296 61028 154859 337075 1675315 1.00 2.00 5.00 10.0 50.0 2607694 20010075.070952693386631 n-Butanol AveFB 40051 80730 254196 446941 2315216 25.0 50.0 125 250 1250 3634586 500025001875106307214920486 Methyl methacrylate AveFB 9384 19903 46763 102779 524573 2.00 4.00 10.0 20.0 100 821025 40020015022843411072980 2-Nitropropane QuaFB +++++ 10601 25402 52624 321132 +++++ 4.00 10.0 20.0 100 532478 4002001501774023766331 cis-1,4-Dichloro-2-butene Lin1DCBd4 1397 10472 26476 51980 293281 2.00 4.00 10.0 20.0 100 459956 4002001501436844630443 1,2,3-Trimethylbenzene AveDCBd4 46531 90073 232236 466047 2281379 1.00 2.00 5.00 10.0 50.0 3488033 20010075.092964464615757 FORM VI 8260D Page 316 of 426 FORM VI Lab Name:Job No.: GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA Eurofins Denver 280-197896-1 Analy Batch No.:671165 RESPONSE AND CONCENTRATION SDG No.: Calibration ID: Instrument ID:Heated Purge: (Y/N)VMS_MS1 98212Calibration Start Date:Calibration End Date:10/16/2024 04:36 N 10/16/2024 07:06 GC Column:DB-624 (60.25)ID:0.25(mm) ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (UG/L) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8 1,3,5-Trichlorobenzene AveDCBd4 14181 25951 72169 145402 712117 1.00 2.00 5.00 10.0 50.0 1068442 20010075.031105221453718 Curve Type Legend: Ave = Average ISTD Lin1 = Linear 1/conc ISTD Lin2 = Linear 1/conc^2 ISTD Qua = Quadratic ISTD FORM VI 8260D Page 317 of 426 Report Date: 16-Oct-2024 08:31:39 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0309.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 1 Inject. Date: 16-Oct-2024 04:36:30 ALS Bottle#: 14 Worklist Smp#: 49 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 1 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:39 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:35:48 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2940621 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 669988 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1046465 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 100 36549 60.0 60.6 25 Isopropyl alcohol 45 3.587 3.587 0.000 98 45913 10.0 12.2 27 Acetonitrile 41 3.726 3.726 0.000 100 55006 10.0 10.2 40 Isopropyl ether 87 4.550 4.550 0.000 96 9795 1.00 0.9610 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 88 16296 1.00 1.06 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 95 34049 1.00 1.06 47 Ethyl acetate 43 5.039 5.039 0.000 98 47675 2.00 2.33 48 Propionitrile 54 5.081 5.081 0.000 99 49466 10.0 10.3 50 Methacrylonitrile 41 5.207 5.207 0.000 89 112997 10.0 10.9 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 96 35296 1.00 1.09 65 n-Butanol 56 6.226 6.226 0.000 85 40051 25.0 22.2 70 Methyl methacrylate 100 6.589 6.589 0.000 90 9384 2.00 1.88 74 2-Nitropropane 41 6.980 6.981 0.000 84 5535 2.00 3.78 106 cis-1,4-Dichloro-2-butene 53 9.830 9.774 0.056 0 1397 2.00 2.11 122 1,2,3-Trimethylbenzene 105 11.100 11.101 -0.001 96 46531 1.00 1.06 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 96 14181 1.00 1.04 135 t-Amyl alcohol 1 0.000 ND ND 142 Ethyl acrylate 55 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Page 318 of 426 Report Date: 16-Oct-2024 08:31:39 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 1.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 319 of 426 Report Date: 16-Oct-2024 08:31:39 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0309.D Injection Date: 16-Oct-2024 04:36:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 49 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 14 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 Y ( X10 0 0 0 0 ) MS1_0309[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 70) I s o p r o p yl a l c o h o l ( 3 . 5 73) A c e t o n i t r i l e ( 3 . 726 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 3 9 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 77 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d 5 ( 8 . 768 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 8 1 6 ) * 1 ,4- D i c h l o r o b e n zen e - d 4 ( 1 1 . 0 4 5 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 320 of 426 Report Date: 16-Oct-2024 08:31:41 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0310.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 2 Inject. Date: 16-Oct-2024 04:58:30 ALS Bottle#: 15 Worklist Smp#: 50 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 2 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:41 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:36:14 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3000053 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 686849 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1086164 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 99 72974 120.0 118.6 25 Isopropyl alcohol 45 3.573 3.587 -0.014 98 78394 20.0 20.5 27 Acetonitrile 41 3.726 3.726 0.000 99 91021 20.0 19.5 40 Isopropyl ether 87 4.550 4.550 0.000 95 20987 2.00 2.02 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 91 30668 2.00 1.95 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 97 63847 2.00 1.95 47 Ethyl acetate 43 5.039 5.039 0.000 97 82860 4.00 3.98 48 Propionitrile 54 5.081 5.081 0.000 99 96963 20.0 19.8 50 Methacrylonitrile 41 5.207 5.207 0.000 89 221248 20.0 20.8 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 96 61028 2.00 1.85 65 n-Butanol 56 6.226 6.226 0.000 88 80730 50.0 43.9 70 Methyl methacrylate 100 6.589 6.589 0.000 87 19903 4.00 3.91 74 2-Nitropropane 41 6.980 6.981 0.000 97 10601 4.00 5.42 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 10472 4.00 4.89 122 1,2,3-Trimethylbenzene 105 11.100 11.101 -0.001 98 90073 2.00 1.97 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 97 25951 2.00 1.83 135 t-Amyl alcohol 1 0.000 ND ND 142 Ethyl acrylate 55 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Page 321 of 426 Report Date: 16-Oct-2024 08:31:41 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 2.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 322 of 426 Report Date: 16-Oct-2024 08:31:41 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0310.D Injection Date: 16-Oct-2024 04:58:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 50 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 15 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0310[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 70) I s o p r o p yl a l c o h o l ( 3 . 5 73) A c e t o n i t r i l e ( 3 . 726 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 3 9 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 77 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d 5 ( 8 . 768 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 77 4) * 1 ,4- D i c h l o r o b e n zen e - d 4 ( 1 1 . 0 4 5 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 323 of 426 Report Date: 16-Oct-2024 08:31:42 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0311.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 3 Inject. Date: 16-Oct-2024 05:19:30 ALS Bottle#: 16 Worklist Smp#: 51 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 3 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:42 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:36:26 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3002376 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 676997 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.045 11.059 -0.014 96 1094358 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 98 199094 300.0 323.3 25 Isopropyl alcohol 45 3.573 3.587 -0.014 98 199319 50.0 52.0 27 Acetonitrile 41 3.726 3.726 0.000 100 192058 50.0 46.4 40 Isopropyl ether 87 4.550 4.550 0.000 94 46886 5.00 4.51 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 88 67816 5.00 4.32 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 98 150939 5.00 4.62 47 Ethyl acetate 43 5.039 5.039 0.000 98 188659 10.0 9.05 48 Propionitrile 54 5.081 5.081 0.000 99 234749 50.0 47.8 50 Methacrylonitrile 41 5.207 5.207 0.000 88 513598 50.0 48.3 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 98 154859 5.00 4.68 65 n-Butanol 56 6.226 6.226 0.000 85 254196 125.0 138.1 70 Methyl methacrylate 100 6.589 6.589 0.000 86 46763 10.0 9.18 74 2-Nitropropane 41 6.980 6.981 0.000 97 25402 10.0 10.3 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 26476 10.0 9.77 122 1,2,3-Trimethylbenzene 105 11.101 11.101 -0.001 97 232236 5.00 5.04 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 97 72169 5.00 5.05 142 Ethyl acrylate 55 0.000 ND ND 135 t-Amyl alcohol 1 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Page 324 of 426 Report Date: 16-Oct-2024 08:31:42 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 5.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 325 of 426 Report Date: 16-Oct-2024 08:31:42 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0311.D Injection Date: 16-Oct-2024 05:19:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 51 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 16 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0311[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 70) I s o p r o p yl a l c o h o l ( 3 . 5 73) A c e t o n i t r i l e ( 3 . 726 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 8 1 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 77 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d 5 ( 8 . 768 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 77 4) * 1 ,4- D i c h l o r o b e n zen e - d 4 ( 1 1 . 0 4 5 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 326 of 426 Report Date: 16-Oct-2024 08:31:43 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0312.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 4 Inject. Date: 16-Oct-2024 05:41:30 ALS Bottle#: 17 Worklist Smp#: 52 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 4 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:43 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:37:40 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3032829 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 703239 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1099586 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 99 364623 600.0 586.2 25 Isopropyl alcohol 45 3.573 3.587 -0.014 98 364741 100.0 94.1 27 Acetonitrile 41 3.726 3.726 0.000 99 407924 100.0 102.9 40 Isopropyl ether 87 4.550 4.550 0.000 94 107956 10.0 10.3 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 89 159583 10.0 10.1 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 97 332003 10.0 10.0 47 Ethyl acetate 43 5.039 5.039 0.000 98 419479 20.0 19.9 48 Propionitrile 54 5.081 5.081 0.000 99 518330 100.0 104.6 50 Methacrylonitrile 41 5.207 5.207 0.000 89 1136186 100.0 105.9 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 99 337075 10.0 10.1 65 n-Butanol 56 6.226 6.226 0.000 85 446941 250.0 240.4 70 Methyl methacrylate 100 6.589 6.589 0.000 87 102779 20.0 20.0 74 2-Nitropropane 41 6.994 6.981 0.014 98 52624 20.0 18.9 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 51980 20.0 17.5 122 1,2,3-Trimethylbenzene 105 11.100 11.101 -0.001 97 466047 10.0 10.1 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 97 145402 10.0 10.1 135 t-Amyl alcohol 1 0.000 ND ND 142 Ethyl acrylate 55 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Page 327 of 426 Report Date: 16-Oct-2024 08:31:43 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 10.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 328 of 426 Report Date: 16-Oct-2024 08:31:43 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0312.D Injection Date: 16-Oct-2024 05:41:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 52 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 17 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 Y ( X10 0 0 0 0 ) MS1_0312[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 7 0 ) I s o p r o p yl a l c o h o l ( 3 . 5 7 3 ) A c e t o n i t r i l e ( 3 . 7 2 6 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 8 1 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7 ) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 7 7 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 7 7 4 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 4 5 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 329 of 426 Report Date: 16-Oct-2024 08:31:44 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 5 Inject. Date: 16-Oct-2024 06:02:30 ALS Bottle#: 18 Worklist Smp#: 53 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 5 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:38:10 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2998216 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 86 682533 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.045 11.059 -0.014 96 1090993 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 99 1820113 3000.0 2959.8 25 Isopropyl alcohol 45 3.587 3.587 0.000 99 1780701 500.0 464.9 27 Acetonitrile 41 3.726 3.726 0.000 100 1924711 500.0 508.9 40 Isopropyl ether 87 4.550 4.550 0.000 93 527516 50.0 50.8 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 89 816252 50.0 52.0 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 98 1659465 50.0 50.8 47 Ethyl acetate 43 5.039 5.039 0.000 98 2083452 100.0 100.0 48 Propionitrile 54 5.081 5.081 0.000 99 2490079 500.0 508.1 50 Methacrylonitrile 41 5.207 5.207 0.000 88 5483202 500.0 516.9 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 99 1675315 50.0 50.7 65 n-Butanol 56 6.226 6.226 0.000 84 2315216 1250.0 1259.9 70 Methyl methacrylate 100 6.589 6.589 0.000 89 524573 100.0 103.2 74 2-Nitropropane 41 6.980 6.981 0.000 99 321132 100.0 98.6 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 293281 100.0 91.7 M 122 1,2,3-Trimethylbenzene 105 11.100 11.101 -0.001 97 2281379 50.0 49.7 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 97 712117 50.0 50.0 135 t-Amyl alcohol 1 0.000 ND ND 142 Ethyl acrylate 55 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Review Flags M - Manually Integrated Page 330 of 426 Report Date: 16-Oct-2024 08:31:44 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 50.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 331 of 426 Report Date: 16-Oct-2024 08:31:45 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Injection Date: 16-Oct-2024 06:02:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 53 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 18 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Y ( X10 0 0 0 0 0 ) MS1_0313[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 70) I s o p r o p yl a l c o h o l ( 3 . 5 8 7) A c e t o n i t r i l e ( 3 . 726 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 8 1 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 6 3 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d 5 ( 8 . 768 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 77 4) * 1 ,4- D i c h l o r o b e n zen e - d 4 ( 1 1 . 1 0 0 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 332 of 426 Report Date: 16-Oct-2024 08:31:45 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Injection Date: 16-Oct-2024 06:02:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 18 Worklist Smp#: 53 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 106 cis-1,4-Dichloro-2-butene, CAS: 1476-11-5 Signal: 1 Processing Integration Results RT: 9.82 Area: 3619 Amount: 2.101089 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Y ( X10 0 ) m/z 53.0 9 . 8 1 6 Manual Integration Results RT: 9.77 Area: 293281 Amount: 91.743316 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min RT 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 0 ) m/z 53.0 9 . 77 4 Reviewer: AF7X, 16-Oct-2024 07:38:03 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Wrong peak Page 333 of 426 Report Date: 16-Oct-2024 08:31:46 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0314.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 6 Inject. Date: 16-Oct-2024 06:23:30 ALS Bottle#: 19 Worklist Smp#: 54 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 6 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:45 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 08:12:39 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3096199 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 702452 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1105925 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 99 2774123 4500.0 4368.4 25 Isopropyl alcohol 45 3.587 3.587 0.000 99 2755180 750.0 696.6 27 Acetonitrile 41 3.726 3.726 0.000 100 2912149 750.0 747.8 40 Isopropyl ether 87 4.550 4.550 0.000 94 827452 75.0 77.1 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 89 1244077 75.0 76.8 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 96 2545190 75.0 75.5 47 Ethyl acetate 43 5.039 5.039 0.000 98 3190995 150.0 148.4 48 Propionitrile 54 5.081 5.081 0.000 99 3737050 750.0 738.5 50 Methacrylonitrile 41 5.207 5.207 0.000 89 8318020 750.0 759.3 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 99 2607694 75.0 76.4 65 n-Butanol 56 6.226 6.226 0.000 85 3634586 1875.0 1915.3 70 Methyl methacrylate 100 6.589 6.589 0.000 87 821025 150.0 156.4 74 2-Nitropropane 41 6.981 6.981 0.000 98 532478 150.0 149.7 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 459956 150.0 141.0 M 122 1,2,3-Trimethylbenzene 105 11.101 11.101 0.000 97 3488033 75.0 74.9 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 98 1068442 75.0 74.0 142 Ethyl acrylate 55 0.000 ND ND 135 t-Amyl alcohol 1 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Review Flags M - Manually Integrated Page 334 of 426 Report Date: 16-Oct-2024 08:31:46 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 75.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 335 of 426 Report Date: 16-Oct-2024 08:31:46 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0314.D Injection Date: 16-Oct-2024 06:23:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 54 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 19 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 Y ( X10 0 0 0 0 0 ) MS1_0314[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 70) I s o p r o p yl a l c o h o l ( 3 . 5 8 7) A c e t o n i t r i l e ( 3 . 726 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 8 1 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 6 3 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 )* C h l o r o b e n zen e - d 5 ( 8 . 754 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 77 4) * 1 ,4- D i c h l o r o b e n zen e - d 4 ( 1 1 . 1 0 1 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 336 of 426 Report Date: 16-Oct-2024 08:31:46 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0314.D Injection Date: 16-Oct-2024 06:23:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 19 Worklist Smp#: 54 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 106 cis-1,4-Dichloro-2-butene, CAS: 1476-11-5 Signal: 1 Processing Integration Results RT: 9.82 Area: 3402 Amount: 1.746255 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min 0 3 6 9 12 15 18 21 24 27 30 33 Y ( X10 0 ) m/z 53.0 9 . 8 1 6 Manual Integration Results RT: 9.77 Area: 459956 Amount: 141.0321 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min RT 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Y ( X10 0 0 0 ) m/z 53.0 9 . 77 4 Reviewer: AF7X, 16-Oct-2024 08:12:32 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Wrong peak Page 337 of 426 Report Date: 16-Oct-2024 08:31:47 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0315.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 7 Inject. Date: 16-Oct-2024 06:45:30 ALS Bottle#: 20 Worklist Smp#: 55 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 7 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:47 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 08:13:01 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3152639 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 726828 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.045 11.059 -0.014 96 1138214 50.0 50.0 17 Ethanol 45 3.070 3.070 0.000 100 3715484 6000.0 5746.0 25 Isopropyl alcohol 45 3.587 3.587 0.000 99 3684982 1000.0 915.0 27 Acetonitrile 41 3.726 3.726 0.000 99 3888286 1000.0 982.0 40 Isopropyl ether 87 4.550 4.550 0.000 93 1106593 100.0 101.3 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 89 1636825 100.0 99.2 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 96 3386018 100.0 98.6 47 Ethyl acetate 43 5.039 5.039 0.000 98 4171342 200.0 190.5 48 Propionitrile 54 5.081 5.081 0.000 99 4947469 1000.0 960.1 50 Methacrylonitrile 41 5.207 5.207 0.000 88 10709000 1000.0 960.1 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 99 3386631 100.0 97.4 65 n-Butanol 56 6.226 6.226 0.000 85 4920486 2500.0 2546.5 70 Methyl methacrylate 100 6.589 6.589 0.000 87 1072980 200.0 200.7 74 2-Nitropropane 41 6.981 6.981 0.001 99 766331 200.0 201.2 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 630443 200.0 187.3 M 122 1,2,3-Trimethylbenzene 105 11.101 11.101 0.000 98 4615757 100.0 96.4 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 98 1453718 100.0 97.8 135 t-Amyl alcohol 1 0.000 ND ND 142 Ethyl acrylate 55 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND Review Flags M - Manually Integrated Page 338 of 426 Report Date: 16-Oct-2024 08:31:47 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 100.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 339 of 426 Report Date: 16-Oct-2024 08:31:47 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0315.D Injection Date: 16-Oct-2024 06:45:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 55 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 20 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 Y ( X10 0 0 0 0 0 ) MS1_0315[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 7 0 ) I s o p r o p yl a l c o h o l ( 3 . 5 8 7 ) A c e t o n i t r i l e ( 3 . 7 2 6 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 8 1 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7 ) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 6 3 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 2 6 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d5( 8 . 7 5 4 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 7 7 4 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 1 0 1 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 340 of 426 Report Date: 16-Oct-2024 08:31:47 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0315.D Injection Date: 16-Oct-2024 06:45:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 20 Worklist Smp#: 55 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 106 cis-1,4-Dichloro-2-butene, CAS: 1476-11-5 Signal: 1 Processing Integration Results RT: 9.83 Area: 2309 Amount: 1.065149 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Y ( X10 0 ) m/z 53.0 9 . 8 3 0 Manual Integration Results RT: 9.77 Area: 630443 Amount: 187.2730 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min RT 0 3 6 9 12 15 18 21 24 27 30 33 36 Y ( X10 0 0 0 ) m/z 53.0 9 . 7 7 4 Reviewer: AF7X, 16-Oct-2024 08:12:54 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Wrong peak Page 341 of 426 Report Date: 16-Oct-2024 08:31:48 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Lims ID: ic Client ID: Sample Type: IC Calib Level: 8 Inject. Date: 16-Oct-2024 07:06:30 ALS Bottle#: 21 Worklist Smp#: 56 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: ic 8 Operator ID: bj Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub194 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 08:31:48 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 08:14:11 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3102288 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 86 719646 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1119692 50.0 50.0 17 Ethanol 45 3.098 3.070 0.028 99 7880230 12000 12385 25 Isopropyl alcohol 45 3.601 3.587 0.014 99 7931339 2000.0 2001.3 27 Acetonitrile 41 3.726 3.726 0.000 99 8133704 2000.0 2092.9 40 Isopropyl ether 87 4.550 4.550 0.000 93 2249946 200.0 209.2 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 89 3365114 200.0 207.4 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 96 6919513 200.0 204.8 47 Ethyl acetate 43 5.039 5.039 0.000 97 8589627 400.0 398.6 48 Propionitrile 54 5.081 5.081 0.000 99 10329963 2000.0 2037.3 50 Methacrylonitrile 41 5.207 5.207 0.000 77 18434862 2000.0 1679.5 e 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 99 7095269 200.0 207.5 65 n-Butanol 56 6.240 6.226 0.014 85 10630721 5000.0 5591.0 70 Methyl methacrylate 100 6.589 6.589 0.000 86 2284341 400.0 434.2 74 2-Nitropropane 41 6.994 6.981 0.014 98 1774023 400.0 399.9 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 1436844 400.0 431.7 M 122 1,2,3-Trimethylbenzene 105 11.100 11.101 -0.001 98 9296446 200.0 197.3 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 97 3110522 200.0 212.7 135 t-Amyl alcohol 1 0.000 ND ND 142 Ethyl acrylate 55 0.000 ND ND QC Flag Legend Processing Flags ND - Not Detected or Marked ND e - Potential Peak Saturated Review Flags M - Manually Integrated Page 342 of 426 Report Date: 16-Oct-2024 08:31:48 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Reagents: MV-Supp A_00097 Amount Added: 200.00 Units: uL mv-Cent IS_00009 Amount Added: 5.00 Units: uL Page 343 of 426 Report Date: 16-Oct-2024 08:31:48 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Injection Date: 16-Oct-2024 07:06:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: ic Worklist Smp#: 56 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 21 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 0 ) MS1_0316[MS SCAN Chro]:Total E t h a n o l ( 3 . 0 8 4 ) I s o p r o p yl a l c o h o l ( 3 . 6 0 1 ) A c e t o n i t r i l e ( 3 . 7 2 6 ) I s o p r o p yl e t h e r ( 4 . 5 5 0 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) E t h yl a c e t a t e ( 5 . 0 8 1 )+ M e t h a c r ylo n i t r i l e ( 5 . 2 0 7 ) Ter t - a m yl m e t h yl e t h e r ( 5 . 8 6 3 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) n - B u t a n o l ( 6 . 2 4 0 ) M e t h yl m e t h a c r yla t e ( 6 . 5 8 9 ) 2 - Nit r o p r o p a n e ( 6 . 9 9 4 ) * C h l o r o b e n zen e - d5( 8 . 7 5 4 ) c i s - 1 ,4- D i c h l o r o - 2 - b u t e n e ( 9 . 7 7 4 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 1 0 0 )+ 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) Page 344 of 426 Report Date: 16-Oct-2024 08:31:48 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Manual Integration/User Assign Peak Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Injection Date: 16-Oct-2024 07:06:30 Instrument ID: VMS_MS1 Lims ID: ic Client ID: Operator ID: bj ALS Bottle#: 21 Worklist Smp#: 56 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Detector MS SCAN 106 cis-1,4-Dichloro-2-butene, CAS: 1476-11-5 Signal: 1 Processing Integration Results RT: 9.84 Area: 4603 Amount: 2.042540 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 Y ( X10 0 ) m/z 53.0 9 . 8 4 4 Manual Integration Results RT: 9.77 Area: 1436844 Amount: 431.6909 Amount Units: ug/l 9.4 9.6 9.8 10.0 10.2 Min RT 0 6 12 18 24 30 36 42 48 54 60 66 72 78 84 Y ( X10 0 0 0 ) m/z 53.0 9 . 7 7 4 Reviewer: AF7X, 16-Oct-2024 08:13:15 -06:00:00 (UTC) Audit Action: Manually Integrated Audit Reason: Wrong peak Page 345 of 426 Calibration / Ethanol Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.01026 Error Coefficients Relative Standard Deviation:3.9 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 60.0 0.62145 50.0 2940621.0 0.010358 Y 2 IC 280-671165/50 120.0 1.216212 50.0 3000053.0 0.010135 Y 3 IC 280-671165/51 300.0 3.315607 50.0 3002376.0 0.011052 Y 4 IC 280-671165/52 600.0 6.011269 50.0 3032829.0 0.010019 Y 5 IC 280-671165/53 3000.0 30.353267 50.0 2998216.0 0.010118 Y 6 IC 280-671165/54 4500.0 44.798849 50.0 3096199.0 0.009955 Y 7 IC 280-671165/55 6000.0 58.926569 50.0 3152639.0 0.009821 Y 8 IC 280-671165/56 12000.0 127.006745 50.0 3102288.0 0.010584 Y RelResp = [0.01026]x Concentration 0 10000 20000 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 346 of 426 Calibration / Isopropyl alcohol Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.06387 Error Coefficients Relative Standard Deviation:10.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 10.0 0.780668 50.0 2940621.0 0.078067 Y 2 IC 280-671165/50 20.0 1.306544 50.0 3000053.0 0.065327 Y 3 IC 280-671165/51 50.0 3.319354 50.0 3002376.0 0.066387 Y 4 IC 280-671165/52 100.0 6.013214 50.0 3032829.0 0.060132 Y 5 IC 280-671165/53 500.0 29.696009 50.0 2998216.0 0.059392 Y 6 IC 280-671165/54 750.0 44.492941 50.0 3096199.0 0.059324 Y 7 IC 280-671165/55 1000.0 58.442816 50.0 3152639.0 0.058443 Y 8 IC 280-671165/56 2000.0 127.830475 50.0 3102288.0 0.063915 Y RelResp = [0.06387]x Concentration 0 1000 2000 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 347 of 426 Calibration / Acetonitrile Curve Type:Linear Weighting:Conc_Sq Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0.2962 Slope:0.0625 Error Coefficients Relative Standard Deviation:4.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 10.0 0.935279 50.0 2940621.0 0.093528 Y 2 IC 280-671165/50 20.0 1.51699 50.0 3000053.0 0.075849 Y 3 IC 280-671165/51 50.0 3.198434 50.0 3002376.0 0.063969 Y 4 IC 280-671165/52 100.0 6.72514 50.0 3032829.0 0.067251 Y 5 IC 280-671165/53 500.0 32.097604 50.0 2998216.0 0.064195 Y 6 IC 280-671165/54 750.0 47.027807 50.0 3096199.0 0.062704 Y 7 IC 280-671165/55 1000.0 61.667162 50.0 3152639.0 0.061667 Y 8 IC 280-671165/56 2000.0 131.09202 50.0 3102288.0 0.065546 Y RelResp = [0.2962] + [0.0625]x Concentration 0 1000 2000 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Intercept = -4.74 Page 348 of 426 Calibration / Isopropyl ether Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1733 Error Coefficients Relative Standard Deviation:4.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 1.0 0.166546 50.0 2940621.0 0.166546 Y 2 IC 280-671165/50 2.0 0.349777 50.0 3000053.0 0.174889 Y 3 IC 280-671165/51 5.0 0.780815 50.0 3002376.0 0.156163 Y 4 IC 280-671165/52 10.0 1.77979 50.0 3032829.0 0.177979 Y 5 IC 280-671165/53 50.0 8.797165 50.0 2998216.0 0.175943 Y 6 IC 280-671165/54 75.0 13.362384 50.0 3096199.0 0.178165 Y 7 IC 280-671165/55 100.0 17.550265 50.0 3152639.0 0.175503 Y 8 IC 280-671165/56 200.0 36.262687 50.0 3102288.0 0.181313 Y RelResp = [0.1733]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/56 Page 349 of 426 Calibration / 2-Chloro-1,3-butadiene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.2616 Error Coefficients Relative Standard Deviation:6.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 1.0 0.277084 50.0 2940621.0 0.277084 Y 2 IC 280-671165/50 2.0 0.511124 50.0 3000053.0 0.255562 Y 3 IC 280-671165/51 5.0 1.129372 50.0 3002376.0 0.225874 Y 4 IC 280-671165/52 10.0 2.630926 50.0 3032829.0 0.263093 Y 5 IC 280-671165/53 50.0 13.612295 50.0 2998216.0 0.272246 Y 6 IC 280-671165/54 75.0 20.090391 50.0 3096199.0 0.267872 Y 7 IC 280-671165/55 100.0 25.959601 50.0 3152639.0 0.259596 Y 8 IC 280-671165/56 200.0 54.236003 50.0 3102288.0 0.27118 Y RelResp = [0.2616]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 Re l a t i v e R e s p o n s e IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 350 of 426 Calibration / Tert-butyl ethyl ether Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.5447 Error Coefficients Relative Standard Deviation:4.1 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 1.0 0.578942 50.0 2940621.0 0.578942 Y 2 IC 280-671165/50 2.0 1.064098 50.0 3000053.0 0.532049 Y 3 IC 280-671165/51 5.0 2.513659 50.0 3002376.0 0.502732 Y 4 IC 280-671165/52 10.0 5.473487 50.0 3032829.0 0.547349 Y 5 IC 280-671165/53 50.0 27.674207 50.0 2998216.0 0.553484 Y 6 IC 280-671165/54 75.0 41.101848 50.0 3096199.0 0.548025 Y 7 IC 280-671165/55 100.0 53.701328 50.0 3152639.0 0.537013 Y 8 IC 280-671165/56 200.0 111.522737 50.0 3102288.0 0.557614 Y RelResp = [0.5447]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 351 of 426 Calibration / Ethyl acetate Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.3473 Error Coefficients Relative Standard Deviation:7.5 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 2.0 0.810628 50.0 2940621.0 0.405314 Y 2 IC 280-671165/50 4.0 1.380976 50.0 3000053.0 0.345244 Y 3 IC 280-671165/51 10.0 3.141828 50.0 3002376.0 0.314183 Y 4 IC 280-671165/52 20.0 6.915639 50.0 3032829.0 0.345782 Y 5 IC 280-671165/53 100.0 34.744862 50.0 2998216.0 0.347449 Y 6 IC 280-671165/54 150.0 51.530845 50.0 3096199.0 0.343539 Y 7 IC 280-671165/55 200.0 66.156353 50.0 3152639.0 0.330782 Y 8 IC 280-671165/56 400.0 138.440193 50.0 3102288.0 0.3461 Y RelResp = [0.3473]x Concentration 0 100 200 300 400 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 Page 352 of 426 Calibration / Propionitrile Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.08172 Error Coefficients Relative Standard Deviation:3.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 10.0 0.841081 50.0 2940621.0 0.084108 Y 2 IC 280-671165/50 20.0 1.616021 50.0 3000053.0 0.080801 Y 3 IC 280-671165/51 50.0 3.909387 50.0 3002376.0 0.078188 Y 4 IC 280-671165/52 100.0 8.545322 50.0 3032829.0 0.085453 Y 5 IC 280-671165/53 500.0 41.526011 50.0 2998216.0 0.083052 Y 6 IC 280-671165/54 750.0 60.348996 50.0 3096199.0 0.080465 Y 7 IC 280-671165/55 1000.0 78.465517 50.0 3152639.0 0.078466 Y 8 IC 280-671165/56 2000.0 166.489427 50.0 3102288.0 0.083245 Y RelResp = [0.08172]x Concentration 0 1000 2000 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 353 of 426 Calibration / Methacrylonitrile Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.1769 Error Coefficients Relative Standard Deviation:7.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 10.0 1.921312 50.0 2940621.0 0.192131 Y 2 IC 280-671165/50 20.0 3.687402 50.0 3000053.0 0.18437 Y 3 IC 280-671165/51 50.0 8.553193 50.0 3002376.0 0.171064 Y 4 IC 280-671165/52 100.0 18.731455 50.0 3032829.0 0.187315 Y 5 IC 280-671165/53 500.0 91.441077 50.0 2998216.0 0.182882 Y 6 IC 280-671165/54 750.0 134.326314 50.0 3096199.0 0.179102 Y 7 IC 280-671165/55 1000.0 169.841837 50.0 3152639.0 0.169842 Y 8 IC 280-671165/56 2000.0 297.117192 50.0 3102288.0 0.148559 Y RelResp = [0.1769]x Concentration 0 1000 2000 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 Page 354 of 426 Calibration / Tert-amyl methyl ether Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.5512 Error Coefficients Relative Standard Deviation:5.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 1.0 0.600145 50.0 2940621.0 0.600145 Y 2 IC 280-671165/50 2.0 1.017115 50.0 3000053.0 0.508558 Y 3 IC 280-671165/51 5.0 2.578941 50.0 3002376.0 0.515788 Y 4 IC 280-671165/52 10.0 5.557105 50.0 3032829.0 0.555711 Y 5 IC 280-671165/53 50.0 27.938531 50.0 2998216.0 0.558771 Y 6 IC 280-671165/54 75.0 42.111214 50.0 3096199.0 0.561483 Y 7 IC 280-671165/55 100.0 53.71105 50.0 3152639.0 0.53711 Y 8 IC 280-671165/56 200.0 114.355421 50.0 3102288.0 0.571777 Y RelResp = [0.5512]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 355 of 426 Calibration / n-Butanol Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.03065 Error Coefficients Relative Standard Deviation:8.8 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 25.0 0.680996 50.0 2940621.0 0.02724 Y 2 IC 280-671165/50 50.0 1.345476 50.0 3000053.0 0.02691 Y 3 IC 280-671165/51 125.0 4.233247 50.0 3002376.0 0.033866 Y 4 IC 280-671165/52 250.0 7.368384 50.0 3032829.0 0.029474 Y 5 IC 280-671165/53 1250.0 38.609893 50.0 2998216.0 0.030888 Y 6 IC 280-671165/54 1875.0 58.694322 50.0 3096199.0 0.031304 Y 7 IC 280-671165/55 2500.0 78.037574 50.0 3152639.0 0.031215 Y 8 IC 280-671165/56 5000.0 171.336784 50.0 3102288.0 0.034267 Y RelResp = [0.03065]x Concentration 0 1000 2000 3000 4000 5000 0.0 0.5 1.0 1.5 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/56 Page 356 of 426 Calibration / Methyl methacrylate Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.08479 Error Coefficients Relative Standard Deviation:5.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 2.0 0.159558 50.0 2940621.0 0.079779 Y 2 IC 280-671165/50 4.0 0.331711 50.0 3000053.0 0.082928 Y 3 IC 280-671165/51 10.0 0.778767 50.0 3002376.0 0.077877 Y 4 IC 280-671165/52 20.0 1.694441 50.0 3032829.0 0.084722 Y 5 IC 280-671165/53 100.0 8.748086 50.0 2998216.0 0.087481 Y 6 IC 280-671165/54 150.0 13.258595 50.0 3096199.0 0.088391 Y 7 IC 280-671165/55 200.0 17.017172 50.0 3152639.0 0.085086 Y 8 IC 280-671165/56 400.0 36.817036 50.0 3102288.0 0.092043 Y RelResp = [0.08479]x Concentration 0 100 200 300 400 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Re l a t i v e R e s p o n s e IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/56 Page 357 of 426 Calibration / 2-Nitropropane Curve Type:Quadratic Weighting:None Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:-0.09532 Slope:0.04988 Second Order:5.469E-05 Error Coefficients Relative Standard Deviation:18.0 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 2.0 0.094113 50.0 2940621.0 0.047056 N 2 IC 280-671165/50 4.0 0.17668 50.0 3000053.0 0.04417 Y 3 IC 280-671165/51 10.0 0.423032 50.0 3002376.0 0.042303 Y 4 IC 280-671165/52 20.0 0.867573 50.0 3032829.0 0.043379 Y 5 IC 280-671165/53 100.0 5.355385 50.0 2998216.0 0.053554 Y 6 IC 280-671165/54 150.0 8.598898 50.0 3096199.0 0.057326 Y 7 IC 280-671165/55 200.0 12.153802 50.0 3152639.0 0.060769 Y 8 IC 280-671165/56 400.0 28.592171 50.0 3102288.0 0.07148 Y RelResp = [-0.09532] + [0.04988]x + [5.469E-05]x^2 Concentration 0 100 200 300 400 0.0 0.5 1.0 1.5 2.0 2.5 Re l a t i v e R e s p o n s e IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 Intercept = 1.91 Page 358 of 426 Calibration / cis-1,4-Dichloro-2-butene Curve Type:Linear Weighting:Conc Origin:None Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:-0.2474 Slope:0.1492 Error Coefficients Relative Standard Deviation:12.2 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 2.0 0.066749 50.0 1046465.0 0.033374 Y 2 IC 280-671165/50 4.0 0.482063 50.0 1086164.0 0.120516 Y 3 IC 280-671165/51 10.0 1.209659 50.0 1094358.0 0.120966 Y 4 IC 280-671165/52 20.0 2.363617 50.0 1099586.0 0.118181 Y 5 IC 280-671165/53 100.0 13.441012 50.0 1090993.0 0.13441 Y 6 IC 280-671165/54 150.0 20.795081 50.0 1105925.0 0.138634 Y 7 IC 280-671165/55 200.0 27.694397 50.0 1138214.0 0.138472 Y 8 IC 280-671165/56 400.0 64.162466 50.0 1119692.0 0.160406 Y RelResp = [-0.2474] + [0.1492]x Concentration 0 100 200 300 400 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Re l a t i v e R e s p o n s e IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Intercept = 1.66 Page 359 of 426 Calibration / 1,2,3-Trimethylbenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:2.104 Error Coefficients Relative Standard Deviation:2.7 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 1.0 2.223247 50.0 1046465.0 2.223247 Y 2 IC 280-671165/50 2.0 4.146381 50.0 1086164.0 2.073191 Y 3 IC 280-671165/51 5.0 10.610605 50.0 1094358.0 2.122121 Y 4 IC 280-671165/52 10.0 21.19193 50.0 1099586.0 2.119193 Y 5 IC 280-671165/53 50.0 104.555162 50.0 1090993.0 2.091103 Y 6 IC 280-671165/54 75.0 157.697538 50.0 1105925.0 2.102634 Y 7 IC 280-671165/55 100.0 202.763145 50.0 1138214.0 2.027631 Y 8 IC 280-671165/56 200.0 415.134073 50.0 1119692.0 2.07567 Y RelResp = [2.104]x Concentration 0 100 200 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 Page 360 of 426 Calibration / 1,3,5-Trichlorobenzene Curve Type:Average Weighting:Conc_Sq Origin:Force Dependency:Response Calib Mode:ISTD Response Base:AREA RF Rounding:0 Curve Coefficients Intercept:0 Slope:0.6532 Error Coefficients Relative Standard Deviation:4.4 ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used 1 IC 280-671165/49 1.0 0.677567 50.0 1046465.0 0.677567 Y 2 IC 280-671165/50 2.0 1.194617 50.0 1086164.0 0.597309 Y 3 IC 280-671165/51 5.0 3.297321 50.0 1094358.0 0.659464 Y 4 IC 280-671165/52 10.0 6.61167 50.0 1099586.0 0.661167 Y 5 IC 280-671165/53 50.0 32.636186 50.0 1090993.0 0.652724 Y 6 IC 280-671165/54 75.0 48.305355 50.0 1105925.0 0.644071 Y 7 IC 280-671165/55 100.0 63.859608 50.0 1138214.0 0.638596 Y 8 IC 280-671165/56 200.0 138.900787 50.0 1119692.0 0.694504 Y RelResp = [0.6532]x Concentration 0 100 200 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Re l a t i v e R e s p o n s e ( X 1 0 0 ) IC 280-671165/49 IC 280-671165/50 IC 280-671165/51 IC 280-671165/52 IC 280-671165/53 IC 280-671165/54 IC 280-671165/55 IC 280-671165/56 Page 361 of 426 FORM VII Lab Name:Job No.: GC/MS VOA CONTINUING CALIBRATION DATA 280-197896-1Eurofins Denver SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID:0.25(mm) VMS_MS1 10/16/2024 03:54 10/16/2024 00:19 10/16/2024 03:11 ICV 280-671165/48 DB-624 (60.25) Lab File ID:MS1_0307.D Heated Purge: (Y/N)NConc. Units:ug/L ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Dichlorodifluoromethane 0.22930.2185 0.1000 52.5 50.0 4.9 30.0Ave Chloromethane 0.21370.2264 0.1000 47.2 50.0 -5.6 30.0Ave Vinyl chloride 0.20800.2067 0.0100 50.3 50.0 0.6 30.0Ave Bromomethane 0.1411 0.0100 56.7 50.0 13.3 30.0Lin1 Chloroethane 0.13170.1420 0.0100 46.4 50.0 -7.3 30.0Ave Dichlorofluoromethane 0.33940.3502 0.0100 48.5 50.0 -3.1 30.0Ave Trichlorofluoromethane 0.24250.2566 0.0100 47.2 50.0 -5.5 30.0Ave Ethyl ether 0.15770.1674 0.0100 47.1 50.0 -5.8 30.0Ave Acrolein 0.02660.0360 0.0010 366 494 -25.9 30.0Ave 1,1-Dichloroethene 0.17440.1753 0.0600 49.8 50.0 -0.5 30.0Ave 1,1,2-Trichloro-1,2,2-trifluoroethane 0.12620.1316 0.0500 48.0 50.0 -4.1 30.0Ave Acetone 0.1539 0.0100 201 200 0.5 30.0Lin2 Iodomethane 0.2018 0.0100 50.3 50.0 0.7 30.0Lin1 Carbon disulfide 0.50230.4763 0.1000 52.7 50.0 5.5 30.0Ave Methyl acetate 0.27300.2886 0.0100 94.6 100 -5.4 30.0Ave 3-Chloro-1-propene 0.2384 0.0100 55.5 50.0 11.0 30.0Lin2 Methylene Chloride 0.1983 0.0100 51.3 50.0 2.6 30.0Lin2 2-Methyl-2-propanol 0.11440.1146 0.0010 499 500 -0.2 30.0Ave Acrylonitrile 0.15210.1520 0.0100 500 500 0.0 30.0Ave Methyl tert-butyl ether 0.58680.5861 0.1000 50.1 50.0 0.1 30.0Ave trans-1,2-Dichloroethene 0.19210.1928 0.1000 49.8 50.0 -0.4 30.0Ave Hexane 1.0831.077 0.0100 50.3 50.0 0.6 30.0Ave Vinyl acetate 0.34030.3741 0.0100 90.9 100 -9.1 30.0Ave 1,1-Dichloroethane 0.32330.3281 0.1000 49.3 50.0 -1.4 30.0Ave 2-Butanone (MEK)0.24570.2639 0.0100 186 200 -6.9 30.0Ave 2,2-Dichloropropane 0.21530.2105 0.0100 51.2 50.0 2.3 30.0Ave cis-1,2-Dichloroethene 0.21640.2175 0.1000 49.7 50.0 -0.5 30.0Ave sec-Butyl Alcohol 0.08400.0805 0.0100 1250 1200 4.4 30.0Ave Chlorobromomethane 0.08740.0991 0.0500 44.1 50.0 -11.9 30.0Ave Tetrahydrofuran 0.16100.1654 0.0010 97.3 100 -2.7 30.0Ave Chloroform 0.31290.3181 0.2000 49.2 50.0 -1.6 30.0Ave 1,1,1-Trichloroethane 0.25770.2460 0.0500 52.4 50.0 4.7 30.0Ave Cyclohexane 0.31670.3182 0.0100 49.8 50.0 -0.5 30.0Ave 1,1-Dichloropropene 0.26170.2656 0.0100 49.3 50.0 -1.4 30.0Ave Carbon tetrachloride 0.19670.1812 0.1000 54.3 50.0 8.6 30.0Ave Isobutyl alcohol 0.0310 0.0010 1220 1250 -2.6 30.0Lin2 Benzene 0.80240.8262 0.2000 48.6 50.0 -2.9 30.0Ave 1,2-Dichloroethane 0.23050.2479 0.0700 46.5 50.0 -7.0 30.0Ave n-Heptane 0.19310.1974 48.9 50.0 -2.1 20.0Ave Trichloroethene 0.89040.8504 0.2000 52.4 50.0 4.7 30.0Ave FORM VII 8260D Page 362 of 426 FORM VII Lab Name:Job No.: GC/MS VOA CONTINUING CALIBRATION DATA 280-197896-1Eurofins Denver SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID:0.25(mm) VMS_MS1 10/16/2024 03:54 10/16/2024 00:19 10/16/2024 03:11 ICV 280-671165/48 DB-624 (60.25) Lab File ID:MS1_0307.D Heated Purge: (Y/N)NConc. Units:ug/L ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 2-Pentanone 0.35960.3706 0.0010 155 160 -3.0 30.0Ave Methylcyclohexane 0.23170.2446 0.0500 47.4 50.0 -5.3 30.0Ave 1,2-Dichloropropane 0.19460.1912 0.1000 50.9 50.0 1.8 30.0Ave 1,4-Dioxane 0.01060.0111 0.0010 958 1000 -4.2 30.0Ave Dibromomethane 0.11830.1205 0.0100 49.1 50.0 -1.8 30.0Ave Dichlorobromomethane 0.21710.2036 0.2000 53.3 50.0 6.6 30.0Ave 2-Chloroethyl vinyl ether 0.06770.0640 0.0100 52.9 50.0 5.8 30.0Ave cis-1,3-Dichloropropene 1.1771.131 0.2000 52.0 50.0 4.1 30.0Ave 4-Methyl-2-pentanone (MIBK)0.34440.3481 0.0300 198 200 -1.0 30.0Ave Toluene 0.85530.8801 0.3000 48.6 50.0 -2.8 30.0Ave trans-1,3-Dichloropropene 0.25510.2172 0.2000 58.7 50.0 17.5 30.0Ave Ethyl methacrylate 1.3411.352 0.0100 49.6 50.0 -0.8 30.0Ave 1,1,2-Trichloroethane 0.18760.1889 0.1000 49.7 50.0 -0.7 30.0Ave Tetrachloroethene 0.65820.6752 0.1000 48.7 50.0 -2.5 30.0Ave 1,3-Dichloropropane 1.3691.402 0.0100 48.8 50.0 -2.4 30.0Ave 2-Hexanone 1.3231.327 0.0100 199 200 -0.3 30.0Ave Chlorodibromomethane 0.68990.6062 0.1000 56.9 50.0 13.8 30.0Ave Ethylene Dibromide 0.86950.8362 0.1000 52.0 50.0 4.0 30.0Ave 1-Chlorohexane 1.1441.208 0.0100 37.9 40.0 -5.3 30.0Ave Chlorobenzene 2.3272.359 0.3000 49.3 50.0 -1.3 30.0Ave 1,1,1,2-Tetrachloroethane 0.70570.6248 0.0100 56.5 50.0 12.9 30.0Ave Ethylbenzene 1.3291.348 0.3000 49.3 50.0 -1.4 30.0Ave m-Xylene & p-Xylene 1.6081.580 0.1000 50.9 50.0 1.8 30.0Ave o-Xylene 1.5551.563 0.2000 49.8 50.0 -0.5 30.0Ave Styrene 2.6702.547 0.2000 52.4 50.0 4.8 30.0Ave Bromoform 0.4485 0.1000 47.7 50.0 -4.7 30.0Lin1 Isopropylbenzene 2.4762.253 0.3000 54.9 50.0 9.9 30.0Ave Cyclohexanone 0.21240.1963 0.0010 1620 1500 8.2 30.0Ave 1,1,2,2-Tetrachloroethane 0.80840.8359 0.3000 48.4 50.0 -3.3 30.0Ave Bromobenzene 0.58150.6009 0.0100 48.4 50.0 -3.2 30.0Ave trans-1,4-Dichloro-2-butene 0.1812 0.0100 49.6 50.0 -0.9 30.0Lin1 1,2,3-Trichloropropane 0.2822 0.0100 51.0 50.0 1.9 30.0Lin1 N-Propylbenzene 0.68600.7062 0.0100 48.6 50.0 -2.9 30.0Ave 2-Chlorotoluene 0.56440.5730 0.0100 49.2 50.0 -1.5 30.0Ave 1,3,5-Trimethylbenzene 2.0131.971 0.0100 51.1 50.0 2.1 30.0Ave 4-Chlorotoluene 0.59100.6186 0.0100 47.8 50.0 -4.5 30.0Ave tert-Butylbenzene 1.7071.711 0.0100 49.9 50.0 -0.2 30.0Ave 1,2,4-Trimethylbenzene 2.0362.057 0.3000 49.5 50.0 -1.0 30.0Ave sec-Butylbenzene 0.50550.4942 0.0100 51.1 50.0 2.3 30.0Ave 1,3-Dichlorobenzene 1.0971.129 0.5000 48.6 50.0 -2.8 30.0Ave 4-Isopropyltoluene 2.0732.109 0.0100 49.2 50.0 -1.7 30.0Ave FORM VII 8260D Page 363 of 426 FORM VII Lab Name:Job No.: GC/MS VOA CONTINUING CALIBRATION DATA 280-197896-1Eurofins Denver SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID:0.25(mm) VMS_MS1 10/16/2024 03:54 10/16/2024 00:19 10/16/2024 03:11 ICV 280-671165/48 DB-624 (60.25) Lab File ID:MS1_0307.D Heated Purge: (Y/N)NConc. Units:ug/L ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 1,4-Dichlorobenzene 1.1051.156 0.5000 47.8 50.0 -4.4 30.0Ave n-Butylbenzene 1.8371.865 0.0100 49.3 50.0 -1.5 30.0Ave 1,2-Dichlorobenzene 1.0421.079 0.5000 48.3 50.0 -3.4 30.0Ave 1,2-Dibromo-3-Chloropropane 0.24360.2288 0.0100 53.2 50.0 6.5 30.0Ave 1,2,4-Trichlorobenzene 0.61100.6081 0.2000 50.2 50.0 0.5 30.0Ave Hexachlorobutadiene 0.21860.2112 0.0100 51.7 50.0 3.5 30.0Ave Naphthalene 2.4112.385 0.0100 50.6 50.0 1.1 30.0Ave 1,2,3-Trichlorobenzene 0.54870.5424 0.3000 50.6 50.0 1.2 30.0Ave Dibromofluoromethane (Surr)0.22590.2239 0.0100 50.5 50.0 0.9 30.0Ave 1,2-Dichloroethane-d4 (Surr)0.24050.2448 0.0100 49.1 50.0 -1.8 30.0Ave Toluene-d8 (Surr)4.3374.272 0.0100 50.8 50.0 1.5 30.0Ave 4-Bromofluorobenzene (Surr)0.91350.9285 0.0100 49.2 50.0 -1.6 30.0Ave FORM VII 8260D Page 364 of 426 Report Date: 16-Oct-2024 07:47:35 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0307.D Lims ID: icv Client ID: Sample Type: ICV Inject. Date: 16-Oct-2024 03:54:30 ALS Bottle#: 12 Worklist Smp#: 48 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: icv Operator ID: bj Instrument ID: VMS_MS1 Sublist: Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:47:34 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: AF7X Date:16-Oct-2024 07:27:54 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 2995118 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 685344 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.045 11.059 -0.014 96 1101212 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 676701 50.0 50.5 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 720417 50.0 49.1 $ 6 Toluene-d8 (Surr) 98 7.427 7.428 -0.001 92 2972290 50.0 50.8 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 89 1005993 50.0 49.2 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 686664 50.0 52.5 10 Chloromethane 50 2.008 2.009 -0.001 99 639991 50.0 47.2 11 Vinyl chloride 62 2.134 2.134 0.000 98 622903 50.0 50.3 13 Bromomethane 94 2.483 2.483 0.000 89 422661 50.0 56.7 14 Chloroethane 64 2.609 2.609 0.000 99 394458 50.0 46.4 15 Dichlorofluoromethane 67 2.846 2.847 -0.001 97 1016471 50.0 48.5 16 Trichlorofluoromethane 101 2.874 2.875 -0.001 99 726206 50.0 47.2 18 Ethyl ether 59 3.168 3.168 0.000 87 472326 50.0 47.1 20 Acrolein 56 3.307 3.307 0.000 99 788150 493.8 365.6 22 1,1-Dichloroethene 96 3.405 3.405 0.000 97 522426 50.0 49.8 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 91 378100 50.0 48.0 23 Acetone 43 3.447 3.447 0.000 99 1844343 200.0 201.1 24 Iodomethane 142 3.559 3.559 0.000 97 604488 50.0 50.3 26 Carbon disulfide 76 3.628 3.629 -0.001 98 1504521 50.0 52.7 28 Methyl acetate 43 3.740 3.740 0.000 96 1635301 100.0 94.6 29 3-Chloro-1-propene 41 3.754 3.754 0.000 91 713907 50.0 55.5 30 Methylene Chloride 84 3.880 3.880 0.000 86 593932 50.0 51.3 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 100 3425247 500.0 499.2 32 Acrylonitrile 53 4.103 4.104 -0.001 99 4554733 500.0 500.3 33 Methyl tert-butyl ether 73 4.117 4.118 -0.001 93 1757539 50.0 50.1 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 97 575269 50.0 49.8 36 Hexane 57 4.383 4.383 0.000 88 742032 50.0 50.3 38 Vinyl acetate 43 4.522 4.523 -0.001 97 2038217 100.0 90.9 39 1,1-Dichloroethane 63 4.536 4.537 0.000 95 968411 50.0 49.3 Page 365 of 426 Report Date: 16-Oct-2024 07:47:35 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0307.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 2943435 200.0 186.2 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 648145 50.0 49.7 46 2,2-Dichloropropane 77 5.039 5.039 0.000 86 644978 50.0 51.2 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 6041415 1200.0 1253.2 52 Tetrahydrofuran 42 5.249 5.249 0.000 84 964151 100.0 97.3 51 Chlorobromomethane 128 5.235 5.249 -0.014 93 261645 50.0 44.1 53 Chloroform 83 5.318 5.319 -0.001 92 937196 50.0 49.2 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 771708 50.0 52.4 57 Cyclohexane 56 5.542 5.542 0.000 86 948544 50.0 49.8 59 Carbon tetrachloride 117 5.612 5.612 0.000 78 589037 50.0 54.3 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 783846 50.0 49.3 60 Isobutyl alcohol 41 5.654 5.668 -0.014 95 2323822 1250.0 1216.9 61 Benzene 78 5.779 5.780 -0.001 96 2403329 50.0 48.6 62 1,2-Dichloroethane 62 5.821 5.821 0.000 98 690448 50.0 46.5 64 n-Heptane 43 6.003 6.003 0.000 89 578458 50.0 48.9 66 Trichloroethene 95 6.338 6.338 0.000 99 610248 50.0 52.4 67 2-Pentanone 43 6.478 6.478 0.000 97 3446720 160.0 155.3 68 Methylcyclohexane 55 6.547 6.548 -0.001 89 693917 50.0 47.4 69 1,2-Dichloropropane 63 6.575 6.576 -0.001 98 582770 50.0 50.9 71 1,4-Dioxane 88 6.631 6.631 0.000 89 637710 1000.0 958.0 72 Dibromomethane 93 6.659 6.645 0.014 97 354283 50.0 49.1 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 650160 50.0 53.3 75 2-Chloroethyl vinyl ether 63 7.022 7.023 0.000 91 202629 50.0 52.9 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 806547 50.0 52.0 79 4-Methyl-2-pentanone (MIBK) 43 7.288 7.288 0.000 95 4126593 200.0 197.9 80 Toluene 91 7.483 7.483 0.000 98 2561599 50.0 48.6 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 764091 50.0 58.7 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 919356 50.0 49.6 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 561977 50.0 49.7 89 Tetrachloroethene 164 7.958 7.958 0.000 97 451095 50.0 48.7 90 1,3-Dichloropropane 76 8.014 8.014 0.000 97 938128 50.0 48.8 91 2-Hexanone 43 8.042 8.042 0.000 93 3626034 200.0 199.4 93 Chlorodibromomethane 129 8.223 8.224 -0.001 90 472795 50.0 56.9 95 Ethylene Dibromide 107 8.349 8.349 0.000 99 595936 50.0 52.0 96 1-Chlorohexane 91 8.754 8.754 0.000 93 627158 40.0 37.9 97 Chlorobenzene 112 8.796 8.796 0.000 96 1595105 50.0 49.3 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 483633 50.0 56.5 98 Ethylbenzene 106 8.880 8.880 0.000 97 911062 50.0 49.3 100 m-Xylene & p-Xylene 106 9.005 9.006 -0.001 0 1101882 50.0 50.9 101 o-Xylene 106 9.369 9.369 0.000 96 1065872 50.0 49.8 103 Styrene 104 9.383 9.383 0.000 95 1829986 50.0 52.4 104 Bromoform 173 9.578 9.578 0.000 96 307373 50.0 47.7 105 Isopropylbenzene 105 9.718 9.718 0.000 95 2726737 50.0 54.9 107 Cyclohexanone 55 9.830 9.830 0.000 88 4367591 1500.0 1623.5 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 890196 50.0 48.4 109 Bromobenzene 156 10.053 10.053 0.000 94 640361 50.0 48.4 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 85 199534 50.0 49.6 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 310717 50.0 51.0 112 N-Propylbenzene 120 10.137 10.137 0.000 98 755465 50.0 48.6 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 621554 50.0 49.2 114 1,3,5-Trimethylbenzene 105 10.304 10.305 -0.001 94 2216588 50.0 51.1 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 650808 50.0 47.8 Page 366 of 426 Report Date: 16-Oct-2024 07:47:35 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0307.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 1880288 50.0 49.9 117 1,2,4-Trimethylbenzene 105 10.681 10.682 -0.001 97 2242594 50.0 49.5 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 556678 50.0 51.1 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 1207804 50.0 48.6 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 2283194 50.0 49.2 121 1,4-Dichlorobenzene 146 11.073 11.073 -0.001 95 1217338 50.0 47.8 124 n-Butylbenzene 91 11.408 11.408 0.000 97 2023238 50.0 49.3 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 99 1147785 50.0 48.3 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 90 268308 50.0 53.2 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 672829 50.0 50.2 129 Hexachlorobutadiene 225 13.195 13.196 -0.001 98 240719 50.0 51.7 130 Naphthalene 128 13.335 13.335 0.000 96 2655402 50.0 50.6 132 1,2,3-Trichlorobenzene 180 13.558 13.559 -0.001 96 604208 50.0 50.6 S 147 1,2-Dichloroethene, Total (URS) 96 0 100.0 99.6 S 148 Xylenes, Total 106 0 100.0 100.6 S 150 Xylenes, Total (URS) 1 0 100.0 100.6 S 152 Trihalomethanes, Total 1 0 200.0 207.0 S 153 1,2-Dichloroethene, Total 1 0 100.0 99.6 S 154 1,3-Dichloropropene, Total 1 0 100.0 110.8 QC Flag Legend Processing Flags Reagents: MV-MegaMain B_00110 Amount Added: 25.00 Units: uL MV-Gas B_00173 Amount Added: 10.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 367 of 426 Report Date: 16-Oct-2024 07:47:36 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0307.D Injection Date: 16-Oct-2024 03:54:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: icv Worklist Smp#: 48 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 12 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 0 0 ) MS1_0307[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 8 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ C a r b o n dis u l f i de( 3 . 6 2 8 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 8 6 6 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 ) A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 7 2 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 5 4 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C yclo h e xan o n e ( 9 . 8 3 0 )+ $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) 1 ,1,2,2- Tet r a c h l o r o e t h a n e ( 1 0 . 1 2 3 )+ 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 5 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 2 1 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 368 of 426 FORM VII Lab Name:Job No.: GC/MS VOA CONTINUING CALIBRATION DATA 280-197896-1Eurofins Denver SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID:0.25(mm) VMS_MS1 10/20/2024 21:38 10/16/2024 00:19 10/16/2024 03:11 CCV 280-671719/2 DB-624 (60.25) Lab File ID:MS1_0595.D Heated Purge: (Y/N)NConc. Units:ug/L ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Dichlorodifluoromethane 0.21030.2185 0.1000 48.1 50.0 -3.8 20.0Ave Chloromethane 0.22690.2264 0.1000 50.1 50.0 0.2 20.0Ave Vinyl chloride 0.21560.2067 0.0100 52.2 50.0 4.3 20.0Ave Bromomethane 0.1281 0.0100 51.4 50.0 2.7 20.0Lin1 Chloroethane 0.14420.1420 0.0100 50.8 50.0 1.5 20.0Ave Dichlorofluoromethane 0.34740.3502 0.0100 49.6 50.0 -0.8 20.0Ave Trichlorofluoromethane 0.23990.2566 0.0100 46.8 50.0 -6.5 20.0Ave Ethyl ether 0.15790.1674 0.0100 47.2 50.0 -5.6 20.0Ave Acrolein 0.03310.0360 0.0010 454 494 -8.0 20.0Ave 1,1-Dichloroethene 0.16410.1753 0.0600 46.8 50.0 -6.4 20.0Ave 1,1,2-Trichloro-1,2,2-trifluoroethane 0.11610.1316 0.0500 44.1 50.0 -11.8 20.0Ave Acetone 0.1575 0.0100 206 200 2.9 20.0Lin2 Iodomethane 0.1808 0.0100 45.1 50.0 -9.8 20.0Lin1 Carbon disulfide 0.45250.4763 0.1000 47.5 50.0 -5.0 20.0Ave Methyl acetate 0.28960.2886 0.0100 100 100 0.3 20.0Ave 3-Chloro-1-propene 0.2359 0.0100 54.9 50.0 9.9 20.0Lin2 Methylene Chloride 0.1901 0.0100 49.1 50.0 -1.7 20.0Lin2 2-Methyl-2-propanol 0.11960.1146 0.0010 522 500 4.4 20.0Ave Acrylonitrile 0.16000.1520 0.0100 526 500 5.3 20.0Ave Methyl tert-butyl ether 0.57300.5861 0.1000 48.9 50.0 -2.2 20.0Ave trans-1,2-Dichloroethene 0.18390.1928 0.1000 47.7 50.0 -4.6 20.0Ave Hexane 1.0471.077 0.0100 48.6 50.0 -2.8 20.0Ave Vinyl acetate 0.21950.3741 0.0100 58.7 100 -41.3* 20.0Ave 1,1-Dichloroethane 0.31530.3281 0.1000 48.1 50.0 -3.9 20.0Ave 2-Butanone (MEK)0.25960.2639 0.0100 197 200 -1.6 20.0Ave 2,2-Dichloropropane 0.19320.2105 0.0100 45.9 50.0 -8.2 20.0Ave cis-1,2-Dichloroethene 0.20380.2175 0.1000 46.8 50.0 -6.3 20.0Ave sec-Butyl Alcohol 0.09050.0805 0.0100 1350 1200 12.5 20.0Ave Chlorobromomethane 0.08820.0991 0.0500 44.5 50.0 -11.0 20.0Ave Tetrahydrofuran 0.17080.1654 0.0010 103 100 3.3 20.0Ave Chloroform 0.29560.3181 0.2000 46.5 50.0 -7.1 20.0Ave 1,1,1-Trichloroethane 0.23410.2460 0.0500 47.6 50.0 -4.9 20.0Ave Cyclohexane 0.31290.3182 0.0100 49.2 50.0 -1.7 20.0Ave 1,1-Dichloropropene 0.25340.2656 0.0100 47.7 50.0 -4.6 20.0Ave Carbon tetrachloride 0.16940.1812 0.1000 46.7 50.0 -6.5 20.0Ave Isobutyl alcohol 0.0330 0.0010 1290 1250 3.5 20.0Lin2 Benzene 0.77700.8262 0.2000 47.0 50.0 -6.0 20.0Ave 1,2-Dichloroethane 0.22150.2479 0.0700 44.7 50.0 -10.6 20.0Ave n-Heptane 0.17290.1974 43.8 50.0 -12.4Ave Trichloroethene 0.88450.8504 0.2000 52.0 50.0 4.0 20.0Ave FORM VII 8260D Page 369 of 426 FORM VII Lab Name:Job No.: GC/MS VOA CONTINUING CALIBRATION DATA 280-197896-1Eurofins Denver SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID:0.25(mm) VMS_MS1 10/20/2024 21:38 10/16/2024 00:19 10/16/2024 03:11 CCV 280-671719/2 DB-624 (60.25) Lab File ID:MS1_0595.D Heated Purge: (Y/N)NConc. Units:ug/L ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 2-Pentanone 0.38340.3706 0.0010 166 160 3.4 20.0Ave Methylcyclohexane 0.22470.2446 0.0500 45.9 50.0 -8.1 20.0Ave 1,2-Dichloropropane 0.19230.1912 0.1000 50.3 50.0 0.6 20.0Ave 1,4-Dioxane 0.01090.0111 0.0010 982 1000 -1.8 20.0Ave Dibromomethane 0.11280.1205 0.0100 46.8 50.0 -6.4 20.0Ave Dichlorobromomethane 0.19430.2036 0.2000 47.7 50.0 -4.6 20.0*Ave 2-Chloroethyl vinyl ether 0.07650.0640 0.0100 59.8 50.0 19.6 20.0Ave cis-1,3-Dichloropropene 1.2281.131 0.2000 54.3 50.0 8.6 20.0Ave 4-Methyl-2-pentanone (MIBK)0.36200.3481 0.0300 208 200 4.0 20.0Ave Toluene 0.81280.8801 0.3000 46.2 50.0 -7.6 20.0Ave trans-1,3-Dichloropropene 0.23420.2172 0.2000 53.9 50.0 7.8 20.0Ave Ethyl methacrylate 1.4131.352 0.0100 52.2 50.0 4.5 20.0Ave 1,1,2-Trichloroethane 0.18150.1889 0.1000 48.0 50.0 -4.0 20.0Ave Tetrachloroethene 0.61530.6752 0.1000 45.6 50.0 -8.9 20.0Ave 1,3-Dichloropropane 1.3811.402 0.0100 49.2 50.0 -1.5 20.0Ave 2-Hexanone 1.4161.327 0.0100 214 200 6.8 20.0Ave Chlorodibromomethane 0.61940.6062 0.1000 51.1 50.0 2.2 20.0Ave Ethylene Dibromide 0.82690.8362 0.1000 49.4 50.0 -1.1 20.0Ave 1-Chlorohexane 1.1011.208 0.0100 36.5 40.0 -8.9 20.0Ave Chlorobenzene 2.2662.359 0.3000 48.0 50.0 -4.0 20.0Ave 1,1,1,2-Tetrachloroethane 0.64940.6248 0.0100 52.0 50.0 3.9 20.0Ave Ethylbenzene 1.2711.348 0.3000 47.1 50.0 -5.7 20.0Ave m-Xylene & p-Xylene 1.5411.580 0.1000 48.8 50.0 -2.5 20.0Ave o-Xylene 1.4991.563 0.2000 48.0 50.0 -4.1 20.0Ave Styrene 2.5232.547 0.2000 49.5 50.0 -0.9 20.0Ave Bromoform 0.3847 0.1000 41.0 50.0 -18.0 20.0Lin1 Isopropylbenzene 2.1502.253 0.3000 47.7 50.0 -4.6 20.0Ave Cyclohexanone 0.23020.1963 0.0010 1760 1500 17.3 20.0Ave 1,1,2,2-Tetrachloroethane 0.78320.8359 0.3000 46.8 50.0 -6.3 20.0Ave Bromobenzene 0.55710.6009 0.0100 46.4 50.0 -7.3 20.0Ave trans-1,4-Dichloro-2-butene 0.1755 0.0100 48.0 50.0 -3.9 20.0Lin1 1,2,3-Trichloropropane 0.2831 0.0100 51.1 50.0 2.2 20.0Lin1 N-Propylbenzene 0.65680.7062 0.0100 46.5 50.0 -7.0 20.0Ave 2-Chlorotoluene 0.53730.5730 0.0100 46.9 50.0 -6.2 20.0Ave 1,3,5-Trimethylbenzene 1.9021.971 0.0100 48.2 50.0 -3.5 20.0Ave 4-Chlorotoluene 0.55910.6186 0.0100 45.2 50.0 -9.6 20.0Ave tert-Butylbenzene 1.6171.711 0.0100 47.3 50.0 -5.5 20.0Ave 1,2,4-Trimethylbenzene 1.9642.057 0.3000 47.7 50.0 -4.5 20.0Ave sec-Butylbenzene 0.48170.4942 0.0100 48.7 50.0 -2.5 20.0Ave 1,3-Dichlorobenzene 1.0461.129 0.5000 46.3 50.0 -7.4 20.0Ave 4-Isopropyltoluene 2.0032.109 0.0100 47.5 50.0 -5.0 20.0Ave FORM VII 8260D Page 370 of 426 FORM VII Lab Name:Job No.: GC/MS VOA CONTINUING CALIBRATION DATA 280-197896-1Eurofins Denver SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID:0.25(mm) VMS_MS1 10/20/2024 21:38 10/16/2024 00:19 10/16/2024 03:11 CCV 280-671719/2 DB-624 (60.25) Lab File ID:MS1_0595.D Heated Purge: (Y/N)NConc. Units:ug/L ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 1,4-Dichlorobenzene 1.0771.156 0.5000 46.6 50.0 -6.8 20.0Ave n-Butylbenzene 1.7421.865 0.0100 46.7 50.0 -6.6 20.0Ave 1,2-Dichlorobenzene 1.0001.079 0.5000 46.3 50.0 -7.4 20.0Ave 1,2-Dibromo-3-Chloropropane 0.22960.2288 0.0100 50.2 50.0 0.3 20.0Ave 1,2,4-Trichlorobenzene 0.55520.6081 0.2000 45.7 50.0 -8.7 20.0Ave Hexachlorobutadiene 0.18850.2112 0.0100 44.6 50.0 -10.7 20.0Ave Naphthalene 2.3332.385 0.0100 48.9 50.0 -2.2 20.0Ave 1,2,3-Trichlorobenzene 0.50490.5424 0.3000 46.5 50.0 -6.9 20.0Ave Dibromofluoromethane (Surr)0.22250.2239 0.0100 49.7 50.0 -0.6 20.0Ave 1,2-Dichloroethane-d4 (Surr)0.23930.2448 0.0100 48.9 50.0 -2.2 20.0Ave Toluene-d8 (Surr)4.4454.272 0.0100 52.0 50.0 4.1 20.0Ave 4-Bromofluorobenzene (Surr)0.95730.9285 0.0100 51.6 50.0 3.1 20.0Ave FORM VII 8260D Page 371 of 426 Report Date: 21-Oct-2024 01:06:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595.D Lims ID: CCV Client ID: Sample Type: CCV Inject. Date: 20-Oct-2024 21:38:30 ALS Bottle#: 25 Worklist Smp#: 2 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: lcsd m Operator ID: bustillose Instrument ID: VMS_MS1 Sublist:chrom-AQ_VMS1_8260*sub164 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:06:26 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:06:26 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3552508 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 86 790375 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 93 1240331 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 790462 50.0 49.7 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 850230 50.0 48.9 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3513235 50.0 52.0 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 86 1187331 50.0 51.6 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 746948 50.0 48.1 10 Chloromethane 50 2.009 2.009 0.000 99 806190 50.0 50.1 11 Vinyl chloride 62 2.134 2.134 0.000 98 765928 50.0 52.2 13 Bromomethane 94 2.483 2.483 0.000 89 455030 50.0 51.4 14 Chloroethane 64 2.609 2.609 0.000 99 512286 50.0 50.8 15 Dichlorofluoromethane 67 2.846 2.846 0.000 96 1234222 50.0 49.6 16 Trichlorofluoromethane 101 2.874 2.874 0.000 99 852366 50.0 46.8 18 Ethyl ether 59 3.168 3.168 0.000 88 561093 50.0 47.2 20 Acrolein 56 3.307 3.307 0.000 99 1161175 493.8 454.2 22 1,1-Dichloroethene 96 3.405 3.405 0.000 98 583007 50.0 46.8 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 92 412397 50.0 44.1 23 Acetone 43 3.447 3.447 0.000 99 2237799 200.0 205.8 24 Iodomethane 142 3.559 3.559 0.000 97 642142 50.0 45.1 26 Carbon disulfide 76 3.629 3.629 0.000 98 1607390 50.0 47.5 28 Methyl acetate 43 3.740 3.740 0.000 97 2057501 100.0 100.3 29 3-Chloro-1-propene 41 3.754 3.754 0.000 93 838083 50.0 54.9 30 Methylene Chloride 84 3.880 3.880 0.000 88 675238 50.0 49.1 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 100 4248996 500.0 522.0 32 Acrylonitrile 53 4.103 4.103 0.000 99 5684550 500.0 526.4 33 Methyl tert-butyl ether 73 4.117 4.117 0.000 95 2035426 50.0 48.9 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 98 653136 50.0 47.7 36 Hexane 57 4.383 4.383 0.000 88 827456 50.0 48.6 38 Vinyl acetate 43 4.522 4.522 0.000 97 1559343 100.0 58.7 39 1,1-Dichloroethane 63 4.536 4.536 0.000 96 1120043 50.0 48.1 Page 372 of 426 Report Date: 21-Oct-2024 01:06:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 3689097 200.0 196.7 46 2,2-Dichloropropane 77 5.039 5.039 0.000 85 686353 50.0 45.9 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 723946 50.0 46.8 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 7716282 1200.0 1349.5 52 Tetrahydrofuran 42 5.249 5.249 0.000 88 1213270 100.0 103.3 51 Chlorobromomethane 128 5.249 5.249 0.000 93 313446 50.0 44.5 53 Chloroform 83 5.319 5.319 0.000 92 1049950 50.0 46.5 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 831503 50.0 47.6 57 Cyclohexane 56 5.542 5.542 0.000 87 1111506 50.0 49.2 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 900206 50.0 47.7 59 Carbon tetrachloride 117 5.612 5.612 0.000 73 601770 50.0 46.7 60 Isobutyl alcohol 41 5.668 5.668 0.000 95 2932664 1250.0 1294.1 61 Benzene 78 5.779 5.779 0.000 95 2760195 50.0 47.0 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 786778 50.0 44.7 64 n-Heptane 43 6.003 6.003 0.000 90 614332 50.0 43.8 66 Trichloroethene 95 6.338 6.338 0.000 98 699118 50.0 52.0 67 2-Pentanone 43 6.478 6.478 0.000 98 4358384 160.0 165.5 68 Methylcyclohexane 55 6.548 6.548 0.000 89 798214 50.0 45.9 69 1,2-Dichloropropane 63 6.575 6.575 0.000 97 683164 50.0 50.3 71 1,4-Dioxane 88 6.631 6.631 0.000 90 775430 1000.0 982.1 72 Dibromomethane 93 6.659 6.659 0.000 98 400666 50.0 46.8 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 690231 50.0 47.7 75 2-Chloroethyl vinyl ether 63 7.022 7.022 0.000 91 271752 50.0 59.8 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 970710 50.0 54.3 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.302 0.000 93 5144180 200.0 208.0 80 Toluene 91 7.483 7.483 0.000 98 2887551 50.0 46.2 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 831829 50.0 53.9 84 Ethyl methacrylate 69 7.707 7.707 0.000 88 1116562 50.0 52.2 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 644710 50.0 48.0 89 Tetrachloroethene 164 7.958 7.958 0.000 97 486349 50.0 45.6 90 1,3-Dichloropropane 76 8.014 8.014 0.000 98 1091391 50.0 49.2 91 2-Hexanone 43 8.042 8.042 0.000 92 4477367 200.0 213.5 93 Chlorodibromomethane 129 8.223 8.223 0.000 90 489566 50.0 51.1 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 653586 50.0 49.4 96 1-Chlorohexane 91 8.754 8.754 0.000 95 696326 40.0 36.5 97 Chlorobenzene 112 8.796 8.796 0.000 95 1790632 50.0 48.0 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 513278 50.0 52.0 98 Ethylbenzene 106 8.880 8.880 0.000 97 1004432 50.0 47.1 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 1217760 50.0 48.8 101 o-Xylene 106 9.369 9.369 0.000 96 1184807 50.0 48.0 103 Styrene 104 9.397 9.397 0.000 96 1994257 50.0 49.5 104 Bromoform 173 9.578 9.578 0.000 97 304025 50.0 41.0 105 Isopropylbenzene 105 9.718 9.718 0.000 96 2666817 50.0 47.7 107 Cyclohexanone 55 9.830 9.830 0.000 89 5459034 1500.0 1759.5 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 971419 50.0 46.8 109 Bromobenzene 156 10.053 10.053 0.000 94 691032 50.0 46.4 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 79 217691 50.0 48.0 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 351076 50.0 51.1 112 N-Propylbenzene 120 10.137 10.137 0.000 98 814672 50.0 46.5 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 666390 50.0 46.9 114 1,3,5-Trimethylbenzene 105 10.304 10.304 0.000 94 2359030 50.0 48.2 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 693503 50.0 45.2 Page 373 of 426 Report Date: 21-Oct-2024 01:06:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 2005447 50.0 47.3 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 97 2435920 50.0 47.7 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 597425 50.0 48.7 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 1297126 50.0 46.3 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 2484717 50.0 47.5 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 1335901 50.0 46.6 124 n-Butylbenzene 91 11.408 11.408 0.000 98 2160659 50.0 46.7 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 1239803 50.0 46.3 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 87 284742 50.0 50.2 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 688650 50.0 45.7 129 Hexachlorobutadiene 225 13.195 13.195 0.000 98 233856 50.0 44.6 130 Naphthalene 128 13.335 13.335 0.000 97 2893379 50.0 48.9 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 96 626261 50.0 46.5 S 147 1,2-Dichloroethene, Total (URS) 96 0 100.0 94.5 S 154 1,3-Dichloropropene, Total 1 0 100.0 108.2 S 153 1,2-Dichloroethene, Total 1 0 100.0 94.5 S 152 Trihalomethanes, Total 1 0 200.0 186.2 S 150 Xylenes, Total (URS) 1 0 100.0 96.7 S 148 Xylenes, Total 106 0 100.0 96.7 QC Flag Legend Processing Flags Reagents: MV-MegaMainA_00115 Amount Added: 25.00 Units: uL MV-Gas A_00200 Amount Added: 10.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 374 of 426 Report Date: 21-Oct-2024 01:06:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595.D Injection Date: 20-Oct-2024 21:38:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: CCV Worklist Smp#: 2 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 25 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Y ( X10 0 0 0 0 0 ) MS1_0595[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ I o dom e t h a n e ( 3 . 6 2 9 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 )+ A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) 1 ,1- D i c h l o r o p r o p e n e ( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 9 . 0 0 6 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 3 0 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) N-P r o p ylb e n zen e ( 1 0 . 1 3 7 ) 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 375 of 426 Report Date: 16-Oct-2024 07:47:34 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0292.D Lims ID: BFB Client ID: Sample Type: BFB Inject. Date: 15-Oct-2024 22:07:30 ALS Bottle#: 1 Worklist Smp#: 1 Injection Vol: 2.0 uL Dil. Factor: 1.0000 Sample Info: bfb Operator ID: bj Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 16-Oct-2024 07:47:34 Calib Date: 16-Oct-2024 06:02:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0313.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: V8PV Date:15-Oct-2024 23:49:00 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags $ 8 BFB 95 9.900 9.900 0.000 0 1010921 NR NR QC Flag Legend Processing Flags NR - Missing Quant Standard Reagents: mv-Cent BFB_00007 Amount Added: 5.00 Units: uL Page 376 of 426 Report Date: 16-Oct-2024 07:47:34 Chrom Revision: 2.3 24-Sep-2024 15:19:46 MS Tune Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0292.D Injection Date: 15-Oct-2024 22:07:30 Instrument ID: VMS_MS1 Lims ID: BFB Client ID: Operator ID: bj ALS Bottle#: 1 Worklist Smp#: 1 Injection Vol: 2.0 uL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Tune Method: BFB Method 8260 $ 8 BFB 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 m/z 0 3 6 9 12 15 18 21 24 27 30 33 36 39 Y ( X10 0 0 0 ) Tune Spec :Average 588-590( 9.89-9.91 ) Bgrd 582( 9.80) 95 174 176 75 50 74 94 96 177 m/z Ion Abundance Criteria %Relative Abundance 95 Base peak,100%relative abundance 100.0 50 15 to 40%of m/z 95 15.6 75 30 to 60%of m/z 95 45.4 96 5 to 9%of m/z 95 6.9 173 Less than 2%of m/z 174 0.0 (0.0) 174 50 to 120%of m/z 95 77.3 175 5 to 9%of m/z 174 6.0 (7.8) 176 Greater than 95%but less than 101%of m/z 174 73.7 (95.3) 177 5 to 9%of m/z 176 5.1 (6.9) Page 377 of 426 Report Date: 16-Oct-2024 07:47:34 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Data File:\\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0292.D\AQ_VMS1_8260.rslt\spectra.d Injection Date: 15-Oct-2024 22:07:30 Spectrum:Tune Spec :Average 588-590( 9.89-9.91 ) Bgrd 582( 9.80) Base Peak:95.00 Minimum % Base Peak: 0 Number of Points: 114 m/z Y m/z Y m/z Y m/z Y 36.00 1988 72.00 1927 110.00 151 145.00 231 37.00 13547 73.00 14853 111.00 225 146.00 401 38.00 12210 74.00 54968 112.00 282 147.00 259 39.00 4953 75.00 175040 113.00 136 148.00 709 40.00 306 76.00 14987 115.00 323 149.00 486 44.00 1360 77.00 1998 116.00 871 150.00 330 45.00 2704 78.00 1593 117.00 1567 151.00 64 46.00 308 79.00 6140 118.00 955 152.00 84 47.00 4262 80.00 1841 119.00 1457 153.00 148 48.00 1610 81.00 6311 120.00 54 154.00 165 49.00 13383 82.00 1350 122.00 58 155.00 858 50.00 60008 83.00 1 123.00 161 156.00 62 51.00 19016 85.00 76 124.00 164 157.00 643 52.00 884 86.00 555 126.00 70 159.00 186 55.00 363 87.00 18024 128.00 933 161.00 232 56.00 4517 88.00 17208 129.00 767 168.00 60 57.00 8107 91.00 1032 130.00 1206 169.00 119 58.00 271 92.00 9079 131.00 401 170.00 56 60.00 2711 93.00 14155 134.00 83 171.00 101 61.00 13622 94.00 40592 134.00 64 172.00 212 62.00 14590 95.00 385664 135.00 526 174.00 298304 63.00 11057 96.00 26472 137.00 102 175.00 23280 64.00 928 97.00 819 137.00 434 176.00 284224 65.00 274 100.00 50 139.00 110 177.00 19664 67.00 662 103.00 92 140.00 120 178.00 686 68.00 33552 104.00 1109 141.00 2674 295.00 63 69.00 34840 105.00 416 142.00 228 303.00 58 70.00 2245 106.00 1072 143.00 2497 71.00 114 107.00 368 144.00 203 Page 378 of 426 Report Date: 16-Oct-2024 07:47:34 Chrom Revision: 2.3 24-Sep-2024 15:19:46 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0292.D Injection Date: 15-Oct-2024 22:07:30 Instrument ID: VMS_MS1 Operator ID: bj Lims ID: BFB Worklist Smp#: 1 Client ID: Injection Vol: 2.0 uL Dil. Factor: 1.0000 ALS Bottle#: 1 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 Y ( X10 0 0 0 0 ) MS1_0292[MS SCAN Chro]:Total $ B F B ( 9 . 9 0 0 ) Page 379 of 426 Report Date: 21-Oct-2024 00:50:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0594A.D Lims ID: BFB Client ID: Sample Type: BFB Inject. Date: 20-Oct-2024 21:17:30 ALS Bottle#: 24 Worklist Smp#: 1 Injection Vol: 2.0 uL Dil. Factor: 1.0000 Sample Info: ccvc m Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 00:50:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags $ 8 BFB 95 9.900 9.900 0.000 0 1162009 NR NR QC Flag Legend Processing Flags NR - Missing Quant Standard Reagents: mv-Cent BFB_00007 Amount Added: 5.00 Units: uL Page 380 of 426 Report Date: 21-Oct-2024 00:50:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22 MS Tune Report Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0594A.D Injection Date: 20-Oct-2024 21:17:30 Instrument ID: VMS_MS1 Lims ID: BFB Client ID: Operator ID: bustillose ALS Bottle#: 24 Worklist Smp#: 1 Injection Vol: 2.0 uL Dil. Factor: 1.0000 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Tune Method: BFB Method 8260 $ 8 BFB 30 51 72 93 114 135 156 177 198 219 240 m/z 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 Y ( X10 0 0 0 ) Tune Spec :Average 588-590( 9.89-9.91 ) Bgrd 582( 9.80) Apex 589( 9.90) 95 174 176 75 50 74 94 96 m/z Ion Abundance Criteria %Relative Abundance 95 Base peak,100%relative abundance 100.0 50 15 to 40%of m/z 95 15.4 75 30 to 60%of m/z 95 41.8 96 5 to 9%of m/z 95 6.9 173 Less than 2%of m/z 174 0.0 (0.0) 174 50 to 120%of m/z 95 75.3 175 5 to 9%of m/z 174 5.7 (7.6) 176 Greater than 95%but less than 101%of m/z 174 73.0 (96.9) 177 5 to 9%of m/z 176 4.9 (6.7) Page 381 of 426 Report Date: 21-Oct-2024 00:50:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0594A.D\AQ_VMS1_8260.rslt\spectra.d Injection Date: 20-Oct-2024 21:17:30 Spectrum:Tune Spec :Average 588-590( 9.89-9.91 ) Bgrd 582( 9.80) Apex 589( 9.90) Base Peak:95.00 Minimum % Base Peak: 0 Number of Points: 101 m/z Y m/z Y m/z Y m/z Y 35.00 68 74.00 62576 112.00 61 146.00 528 36.00 2174 75.00 185088 113.00 142 147.00 203 37.00 15620 76.00 17336 115.00 333 148.00 687 38.00 12015 78.00 1648 116.00 1254 149.00 267 44.00 1280 79.00 6990 117.00 1957 150.00 329 45.00 3042 80.00 1924 118.00 1011 152.00 194 46.00 186 81.00 6756 119.00 1526 153.00 233 47.00 5599 82.00 1527 123.00 85 154.00 342 48.00 2043 86.00 133 125.00 104 155.00 775 49.00 12633 86.00 128 127.00 121 156.00 70 50.00 68360 87.00 21064 128.00 1072 157.00 646 51.00 18632 88.00 8100 129.00 594 159.00 258 56.00 4473 92.00 11002 130.00 1191 161.00 436 57.00 9345 93.00 17128 131.00 483 162.00 64 58.00 523 94.00 47472 132.00 57 170.00 53 59.00 111 95.00 443264 134.00 50 171.00 299 60.00 3745 96.00 30704 135.00 567 174.00 333888 61.00 16111 97.00 790 136.00 51 175.00 25464 62.00 13315 103.00 143 137.00 602 176.00 323392 63.00 12155 104.00 1152 139.00 83 177.00 21616 68.00 36904 105.00 451 140.00 171 178.00 695 69.00 39032 106.00 1373 141.00 2636 208.00 53 70.00 2141 107.00 418 142.00 500 231.00 53 71.00 60 108.00 55 143.00 2525 72.00 1949 110.00 57 144.00 251 73.00 15753 111.00 257 145.00 286 Page 382 of 426 Report Date: 21-Oct-2024 00:50:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0594A.D Injection Date: 20-Oct-2024 21:17:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: BFB Worklist Smp#: 1 Client ID: Injection Vol: 2.0 uL Dil. Factor: 1.0000 ALS Bottle#: 24 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 Y ( X10 0 0 0 0 ) MS1_0594A[MS SCAN Chro]:Total $ B F B ( 9 . 9 0 0 ) Page 383 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:Lab Sample ID:MB 280-671719/9 Matrix:MS1_0600.DLab File ID: Date Collected:8260DAnalysis Method: Water Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/20/2024 23:26 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.14U71-43-2 Benzene 0.14 1.0 0.14U100-41-4 Ethylbenzene 0.14 3.0 0.99U91-20-3 Naphthalene 0.99 1.0 0.32U108-88-3 Toluene 0.32 1.0 0.11U1330-20-7 Xylenes, Total 0.11 %RECCAS NO.LIMITSQSURROGATE 99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 102 78-120460-00-4 4-Bromofluorobenzene (Surr) 104 80-1252037-26-5 Toluene-d8 (Surr) 96 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 384 of 426 Report Date: 21-Oct-2024 01:20:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0600.D Lims ID: MB Client ID: Sample Type: MB Inject. Date: 20-Oct-2024 23:26:30 ALS Bottle#: 30 Worklist Smp#:9 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: rinse Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:17:05 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3405826 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 751539 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1182798 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 735206 50.0 48.2 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.751 0.001 0 821597 50.0 49.3 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3326119 50.0 51.8 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 87 1122743 50.0 51.1 $ 8 BFB 95 9.899 9.900 -0.001 83 1122743 NR 9 Dichlorodifluoromethane 85 1.799 ND 10 Chloromethane 50 2.009 ND 11 Vinyl chloride 62 2.134 ND 12 Ethylene oxide 43 2.260 2.260 0.000 95 2937 NC 13 Bromomethane 94 2.483 ND 7 14 Chloroethane 64 2.609 ND 15 Dichlorofluoromethane 67 2.846 ND 16 Trichlorofluoromethane 101 2.874 ND 17 Ethanol 45 3.070 3.070 0.000 57 3556 5.09 18 Ethyl ether 59 3.168 ND 19 Propene oxide 58 3.238 ND 20 Acrolein 56 3.321 3.307 0.014 27 1119 0.4565 22 1,1-Dichloroethene 96 3.405 ND 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 ND 23 Acetone 43 3.447 3.447 0.000 100 47659 0.8229 24 Iodomethane 142 3.559 3.559 0.000 94 7238 0.4552 25 Isopropyl alcohol 45 3.573 3.587 -0.014 95 16305 3.75 26 Carbon disulfide 76 3.629 ND 7 27 Acetonitrile 41 3.726 3.726 0.000 98 34475 3.36 28 Methyl acetate 43 3.740 ND 29 3-Chloro-1-propene 41 3.754 ND U 30 Methylene Chloride 84 3.880 ND 7 31 2-Methyl-2-propanol 59 3.964 ND 32 Acrylonitrile 53 4.103 ND U Page 385 of 426 Report Date: 21-Oct-2024 01:20:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0600.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 33 Methyl tert-butyl ether 73 4.117 ND 34 trans-1,2-Dichloroethene 96 4.131 ND 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.383 ND 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 ND 39 1,1-Dichloroethane 63 4.536 ND 40 Isopropyl ether 87 4.550 ND 41 2-Chloro-1,3-butadiene 53 4.592 ND 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 ND 44 2-Butanone (MEK) 43 5.011 5.011 0.000 93 3733 0.2077 46 2,2-Dichloropropane 77 5.039 ND 45 cis-1,2-Dichloroethene 96 5.039 ND 47 Ethyl acetate 43 5.039 ND 7 48 Propionitrile 54 5.081 ND 49 sec-Butyl Alcohol 45 5.165 ND 50 Methacrylonitrile 41 5.207 ND 52 Tetrahydrofuran 42 5.249 ND 51 Chlorobromomethane 128 5.249 ND 53 Chloroform 83 5.319 ND 54 1,1,1-Trichloroethane 97 5.472 ND 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.505 ND 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.542 ND 58 1,1-Dichloropropene 75 5.612 ND 59 Carbon tetrachloride 117 5.612 ND 60 Isobutyl alcohol 41 5.668 ND 61 Benzene 78 5.779 ND 62 1,2-Dichloroethane 62 5.821 ND 63 Tert-amyl methyl ether 73 5.877 ND 64 n-Heptane 43 6.003 ND U 65 n-Butanol 56 6.226 ND U 66 Trichloroethene 95 6.338 ND 67 2-Pentanone 43 6.478 ND 68 Methylcyclohexane 55 6.548 ND 69 1,2-Dichloropropane 63 6.575 ND 70 Methyl methacrylate 100 6.590 ND 71 1,4-Dioxane 88 6.631 ND 72 Dibromomethane 93 6.659 ND 73 Dichlorobromomethane 83 6.799 ND 74 2-Nitropropane 41 6.995 ND 75 2-Chloroethyl vinyl ether 63 7.022 ND 76 cis-1,3-Dichloropropene 75 7.176 ND 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 ND 80 Toluene 91 7.483 ND 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 ND 83 3,3-Dimethylpentane 43 7.682 ND 84 Ethyl methacrylate 69 7.707 ND Page 386 of 426 Report Date: 21-Oct-2024 01:20:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0600.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 85 2-Methylhexane 43 7.810 ND 86 1,1,2-Trichloroethane 97 7.860 ND 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 7.949 ND 89 Tetrachloroethene 164 7.958 ND 90 1,3-Dichloropropane 76 8.014 ND 91 2-Hexanone 43 8.042 ND 7 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 ND 94 Tetrahydrothiophene 60 8.224 ND 95 Ethylene Dibromide 107 8.349 ND 96 1-Chlorohexane 91 8.754 ND U 97 Chlorobenzene 112 8.796 ND 99 1,1,1,2-Tetrachloroethane 131 8.880 ND 98 Ethylbenzene 106 8.880 ND 100 m-Xylene & p-Xylene 106 9.006 ND 101 o-Xylene 106 9.369 ND 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 ND 104 Bromoform 173 9.578 ND 105 Isopropylbenzene 105 9.718 ND 7 106 cis-1,4-Dichloro-2-butene 53 9.774 ND 107 Cyclohexanone 55 9.830 9.830 0.000 87 6525 2.21 108 1,1,2,2-Tetrachloroethane 83 10.025 ND 109 Bromobenzene 156 10.053 ND 110 trans-1,4-Dichloro-2-butene 53 10.053 ND 111 1,2,3-Trichloropropane 110 10.081 ND 112 N-Propylbenzene 120 10.137 ND 113 2-Chlorotoluene 126 10.235 ND 114 1,3,5-Trimethylbenzene 105 10.304 ND 115 4-Chlorotoluene 126 10.346 ND 116 tert-Butylbenzene 119 10.626 ND 117 1,2,4-Trimethylbenzene 105 10.682 ND 118 sec-Butylbenzene 134 10.849 ND 119 1,3-Dichlorobenzene 146 10.975 ND 7 120 4-Isopropyltoluene 119 10.989 ND 121 1,4-Dichlorobenzene 146 11.073 ND 7 122 1,2,3-Trimethylbenzene 105 11.101 ND 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 ND 7 125 1,2-Dichlorobenzene 146 11.436 ND 126 1,2-Dibromo-3-Chloropropane 157 12.232 ND 127 1,3,5-Trichlorobenzene 180 12.413 ND 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 89 2440 0.1696 129 Hexachlorobutadiene 225 13.195 ND 130 Naphthalene 128 13.335 13.335 0.000 95 16163 0.2865 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.545 13.559 -0.014 93 2529 0.1971 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND Page 387 of 426 Report Date: 21-Oct-2024 01:20:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0600.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 135 t-Amyl alcohol 1 0.000 ND 137 1-Chlorohexane TIC 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7 S 154 1,3-Dichloropropene, Total 1 0.000 ND 7 S 153 1,2-Dichloroethene, Total 1 0.000 ND 7 S 152 Trihalomethanes, Total 1 0.000 ND 7 S 151 Total BTEX 1 0.000 ND 7 S 150 Xylenes, Total (URS) 1 0.000 ND 7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0.000 ND 7 QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated 7 - Failed Limit of Detection Review Flags U - Marked Undetected Reagents: mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 388 of 426 Report Date: 21-Oct-2024 01:20:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0600.D Injection Date: 20-Oct-2024 23:26:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: MB Worklist Smp#: 9 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 30 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 Y ( X10 0 0 0 0 ) MS1_0600[MS SCAN Chro]:Total E t h yle n e o xide( 2 . 2 6 0 ) A c r o l e i n ( 3 . 3 2 1 ) A c e t o n e ( 3 . 4 4 7 ) I o dom e t h a n e ( 3 . 5 7 3 )+ A c e t o n i t r i l e ( 3 . 7 2 6 ) 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 ) $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 5 2 ) * F l u o r o b e n zen e ( 6 . 0 3 1 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 ) $ B F B ( 9 . 8 9 9 )+ * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 )+ 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 4 5 ) Page 389 of 426 Report Date: 21-Oct-2024 01:20:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0600.D Lims ID: MB Client ID: Sample Type: MB Inject. Date: 20-Oct-2024 23:26:30 ALS Bottle#: 30 Worklist Smp#: 9 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: rinse Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:19:44 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 01:17:05 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 48.2 96.41 $ 5 1,2-Dichloroethane-d4 (Surr)50.0 49.3 98.53 $6 Toluene-d8 (Surr)50.0 51.8 103.61 $7 4-Bromofluorobenzene (Surr)50.0 51.1 102.24 Page 390 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:Lab Sample ID:LCS 280-671719/4 Matrix:MS1_0595A.DLab File ID: Date Collected:8260DAnalysis Method: Water Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/20/2024 21:38 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.1471-43-2 Benzene 47.0 1.0 0.14100-41-4 Ethylbenzene 47.1 3.0 0.9991-20-3 Naphthalene 48.9 1.0 0.32108-88-3 Toluene 46.2 1.0 0.111330-20-7 Xylenes, Total 96.8 %RECCAS NO.LIMITSQSURROGATE 98 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 103 78-120460-00-4 4-Bromofluorobenzene (Surr) 104 80-1252037-26-5 Toluene-d8 (Surr) 99 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 391 of 426 Report Date: 21-Oct-2024 01:04:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595A.D Lims ID: LCS Client ID: Sample Type: LCS Inject. Date: 20-Oct-2024 21:38:30 ALS Bottle#: 25 Worklist Smp#: 4 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: lcsd m Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:03:50 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 00:49:54 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3552508 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 86 790375 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 93 1240331 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 93 790462 50.0 49.7 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.752 -0.001 0 850230 50.0 48.9 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3513235 50.0 52.0 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.900 -0.001 86 1187331 50.0 51.6 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 746948 50.0 48.1 10 Chloromethane 50 2.009 2.009 0.000 99 806190 50.0 50.1 11 Vinyl chloride 62 2.134 2.134 0.000 98 765928 50.0 52.2 13 Bromomethane 94 2.483 2.483 0.000 89 455030 50.0 51.4 14 Chloroethane 64 2.609 2.609 0.000 99 512286 50.0 50.8 15 Dichlorofluoromethane 67 2.846 2.846 0.000 96 1234222 50.0 49.6 16 Trichlorofluoromethane 101 2.874 2.874 0.000 99 852366 50.0 46.8 18 Ethyl ether 59 3.168 3.168 0.000 88 561093 50.0 47.2 20 Acrolein 56 3.307 3.307 0.000 99 1161175 493.8 454.2 22 1,1-Dichloroethene 96 3.405 3.405 0.000 98 583007 50.0 46.8 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 92 412397 50.0 44.1 23 Acetone 43 3.447 3.447 0.000 99 2237799 200.0 205.8 24 Iodomethane 142 3.559 3.559 0.000 97 642142 50.0 45.1 26 Carbon disulfide 76 3.629 3.629 0.000 98 1607390 50.0 47.5 28 Methyl acetate 43 3.740 3.740 0.000 97 2057501 100.0 100.3 29 3-Chloro-1-propene 41 3.754 3.754 0.000 93 838083 50.0 54.9 30 Methylene Chloride 84 3.880 3.880 0.000 88 675238 50.0 49.1 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 100 4248996 500.0 522.0 32 Acrylonitrile 53 4.103 4.103 0.000 99 5684550 500.0 526.4 33 Methyl tert-butyl ether 73 4.117 4.117 0.000 95 2035426 50.0 48.9 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 98 653136 50.0 47.7 36 Hexane 57 4.383 4.383 0.000 88 827456 50.0 48.6 38 Vinyl acetate 43 4.522 4.522 0.000 97 1559343 100.0 58.7 39 1,1-Dichloroethane 63 4.536 4.536 0.000 96 1120043 50.0 48.1 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 3689097 200.0 196.7 Page 392 of 426 Report Date: 21-Oct-2024 01:04:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595A.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 46 2,2-Dichloropropane 77 5.039 5.039 0.000 85 686353 50.0 45.9 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 79 723946 50.0 46.8 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 7716282 1200.0 1349.5 52 Tetrahydrofuran 42 5.249 5.249 0.000 88 1213270 100.0 103.3 51 Chlorobromomethane 128 5.249 5.249 0.000 93 313446 50.0 44.5 53 Chloroform 83 5.319 5.319 0.000 92 1049950 50.0 46.5 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 831503 50.0 47.6 57 Cyclohexane 56 5.542 5.542 0.000 87 1111506 50.0 49.2 58 1,1-Dichloropropene 75 5.612 5.612 0.000 96 900206 50.0 47.7 59 Carbon tetrachloride 117 5.612 5.612 0.000 73 601770 50.0 46.7 60 Isobutyl alcohol 41 5.668 5.668 0.000 95 2932664 1250.0 1294.1 61 Benzene 78 5.779 5.779 0.000 95 2760195 50.0 47.0 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 786778 50.0 44.7 64 n-Heptane 43 6.003 6.003 0.000 90 614332 50.0 43.8 66 Trichloroethene 95 6.338 6.338 0.000 98 699118 50.0 52.0 67 2-Pentanone 43 6.478 6.478 0.000 98 4358384 160.0 165.5 68 Methylcyclohexane 55 6.548 6.548 0.000 89 798214 50.0 45.9 69 1,2-Dichloropropane 63 6.575 6.575 0.000 97 683164 50.0 50.3 71 1,4-Dioxane 88 6.631 6.631 0.000 90 775430 1000.0 982.1 72 Dibromomethane 93 6.659 6.659 0.000 98 400666 50.0 46.8 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 690231 50.0 47.7 75 2-Chloroethyl vinyl ether 63 7.022 7.022 0.000 91 271752 50.0 59.8 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 970710 50.0 54.3 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.302 0.000 93 5144180 200.0 208.0 80 Toluene 91 7.483 7.483 0.000 98 2887551 50.0 46.2 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 831829 50.0 53.9 84 Ethyl methacrylate 69 7.707 7.707 0.000 88 1116562 50.0 52.2 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 644710 50.0 48.0 89 Tetrachloroethene 164 7.958 7.958 0.000 97 486349 50.0 45.6 90 1,3-Dichloropropane 76 8.014 8.014 0.000 98 1091391 50.0 49.2 91 2-Hexanone 43 8.042 8.042 0.000 92 4477367 200.0 213.5 93 Chlorodibromomethane 129 8.223 8.223 0.000 90 489566 50.0 51.1 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 653586 50.0 49.4 96 1-Chlorohexane 91 8.754 8.754 0.000 95 696326 40.0 36.5 97 Chlorobenzene 112 8.796 8.796 0.000 95 1790632 50.0 48.0 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 513278 50.0 52.0 98 Ethylbenzene 106 8.880 8.880 0.000 97 1004432 50.0 47.1 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 1217760 50.0 48.8 101 o-Xylene 106 9.369 9.369 0.000 96 1184807 50.0 48.0 103 Styrene 104 9.397 9.397 0.000 96 1994257 50.0 49.5 104 Bromoform 173 9.578 9.578 0.000 97 304025 50.0 41.0 105 Isopropylbenzene 105 9.718 9.718 0.000 96 2666817 50.0 47.7 107 Cyclohexanone 55 9.830 9.830 0.000 89 5459034 1500.0 1759.5 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 971419 50.0 46.8 109 Bromobenzene 156 10.053 10.053 0.000 94 691032 50.0 46.4 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 79 217691 50.0 48.0 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 351076 50.0 51.1 112 N-Propylbenzene 120 10.137 10.137 0.000 98 814672 50.0 46.5 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 666390 50.0 46.9 114 1,3,5-Trimethylbenzene 105 10.304 10.304 0.000 94 2359030 50.0 48.2 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 693503 50.0 45.2 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 2005447 50.0 47.3 Page 393 of 426 Report Date: 21-Oct-2024 01:04:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595A.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 97 2435920 50.0 47.7 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 597425 50.0 48.7 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 1297126 50.0 46.3 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 2484717 50.0 47.5 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 1335901 50.0 46.6 124 n-Butylbenzene 91 11.408 11.408 0.000 98 2160659 50.0 46.7 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 1239803 50.0 46.3 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 87 284742 50.0 50.2 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 688650 50.0 45.7 129 Hexachlorobutadiene 225 13.195 13.195 0.000 98 233856 50.0 44.6 130 Naphthalene 128 13.335 13.335 0.000 97 2893379 50.0 48.9 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 96 626261 50.0 46.5 S 147 1,2-Dichloroethene, Total (URS) 96 0 100.0 94.5 S 154 1,3-Dichloropropene, Total 1 0 100.0 108.2 S 153 1,2-Dichloroethene, Total 1 0 100.0 94.5 S 152 Trihalomethanes, Total 1 0 200.0 186.2 S 150 Xylenes, Total (URS) 1 0 100.0 96.7 S 148 Xylenes, Total 106 0 100.0 96.7 QC Flag Legend Processing Flags Reagents: MV-MegaMainA_00115 Amount Added: 25.00 Units: uL MV-Gas A_00200 Amount Added: 10.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 394 of 426 Report Date: 21-Oct-2024 01:04:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595A.D Injection Date: 20-Oct-2024 21:38:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: LCS Worklist Smp#: 4 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 25 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Y ( X10 0 0 0 0 0 ) MS1_0595A[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 6 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ I o dom e t h a n e ( 3 . 6 2 9 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 )+ A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) 1 ,1- D i c h l o r o p r o p e n e ( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 9 . 0 0 6 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 3 0 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 8 9 9 ) N-P r o p ylb e n zen e ( 1 0 . 1 3 7 ) 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 395 of 426 Report Date: 21-Oct-2024 01:04:16 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0595A.D Lims ID: LCS Client ID: Sample Type: LCS Inject. Date: 20-Oct-2024 21:38:30 ALS Bottle#: 25 Worklist Smp#: 4 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: lcsd m Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:03:50 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 00:49:54 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 49.7 99.37 $5 1,2-Dichloroethane-d4 (Surr)50.0 48.9 97.75 $6 Toluene-d8 (Surr)50.0 52.0 104.06 $7 4-Bromofluorobenzene (Surr)50.0 51.6 103.10 Page 396 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:Lab Sample ID:LCSD 280-671719/6 Matrix:MS1_0597.DLab File ID: Date Collected:8260DAnalysis Method: Water Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/20/2024 22:21 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 1.0 0.1471-43-2 Benzene 47.8 1.0 0.14100-41-4 Ethylbenzene 47.8 3.0 0.9991-20-3 Naphthalene 50.3 1.0 0.32108-88-3 Toluene 47.4 1.0 0.111330-20-7 Xylenes, Total 98.6 %RECCAS NO.LIMITSQSURROGATE 99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 102 78-120460-00-4 4-Bromofluorobenzene (Surr) 103 80-1252037-26-5 Toluene-d8 (Surr) 100 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 397 of 426 Report Date: 21-Oct-2024 01:04:21 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0597.D Lims ID: LCSD Client ID: Sample Type: LCSD Inject. Date: 20-Oct-2024 22:21:30 ALS Bottle#: 27 Worklist Smp#:6 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: lcsd Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:03:50 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 00:50:35 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3528958 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 86 791702 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 93 1236899 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 788723 50.0 49.9 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.752 0.000 0 858535 50.0 49.7 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 93 3495520 50.0 51.7 $ 7 4-Bromofluorobenzene (Surr) 95 9.900 9.900 0.000 87 1172294 50.0 51.0 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 679976 50.0 44.1 10 Chloromethane 50 2.009 2.009 0.000 99 826626 50.0 51.7 11 Vinyl chloride 62 2.134 2.134 0.000 97 768039 50.0 52.7 13 Bromomethane 94 2.483 2.483 0.000 89 459646 50.0 52.2 14 Chloroethane 64 2.609 2.609 0.000 99 511961 50.0 51.1 15 Dichlorofluoromethane 67 2.847 2.846 0.001 97 1248198 50.0 50.5 16 Trichlorofluoromethane 101 2.875 2.874 0.000 98 806998 50.0 44.6 18 Ethyl ether 59 3.168 3.168 0.000 88 584100 50.0 49.4 20 Acrolein 56 3.307 3.307 0.000 99 1303019 493.8 513.1 22 1,1-Dichloroethene 96 3.405 3.405 0.000 97 568626 50.0 46.0 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.419 3.419 0.000 91 376635 50.0 40.6 23 Acetone 43 3.447 3.447 0.000 99 2334488 200.0 216.3 24 Iodomethane 142 3.559 3.559 0.000 97 622537 50.0 44.0 26 Carbon disulfide 76 3.629 3.629 0.000 98 1611485 50.0 47.9 28 Methyl acetate 43 3.740 3.740 0.000 97 2182588 100.0 107.1 29 3-Chloro-1-propene 41 3.754 3.754 0.000 92 859503 50.0 56.8 30 Methylene Chloride 84 3.880 3.880 0.000 87 690607 50.0 50.6 31 2-Methyl-2-propanol 59 3.964 3.964 0.000 100 4365211 500.0 539.9 32 Acrylonitrile 53 4.104 4.103 0.001 99 5835338 500.0 544.0 33 Methyl tert-butyl ether 73 4.117 4.117 0.000 94 2076733 50.0 50.2 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 97 651377 50.0 47.9 36 Hexane 57 4.383 4.383 0.000 88 806378 50.0 47.3 38 Vinyl acetate 43 4.523 4.522 0.001 97 2915670 100.0 110.4 39 1,1-Dichloroethane 63 4.536 4.536 0.000 95 1132335 50.0 48.9 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 3812574 200.0 204.7 Page 398 of 426 Report Date: 21-Oct-2024 01:04:21 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0597.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 46 2,2-Dichloropropane 77 5.039 5.039 0.000 84 793337 50.0 53.4 45 cis-1,2-Dichloroethene 96 5.039 5.039 0.000 80 727919 50.0 47.4 49 sec-Butyl Alcohol 45 5.165 5.165 0.000 98 7910744 1200.0 1392.7 52 Tetrahydrofuran 42 5.249 5.249 0.000 86 1264473 100.0 108.3 51 Chlorobromomethane 128 5.249 5.249 0.000 93 314417 50.0 44.9 53 Chloroform 83 5.319 5.319 0.001 93 1077438 50.0 48.0 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 822804 50.0 47.4 57 Cyclohexane 56 5.542 5.542 0.000 86 1007732 50.0 44.9 58 1,1-Dichloropropene 75 5.612 5.612 0.000 97 906014 50.0 48.3 59 Carbon tetrachloride 117 5.612 5.612 0.000 73 603696 50.0 47.2 60 Isobutyl alcohol 41 5.668 5.668 0.000 95 3002031 1250.0 1333.2 61 Benzene 78 5.779 5.779 0.000 96 2786691 50.0 47.8 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 799124 50.0 45.7 64 n-Heptane 43 6.003 6.003 0.000 90 635098 50.0 45.6 66 Trichloroethene 95 6.338 6.338 0.000 99 659503 50.0 49.0 67 2-Pentanone 43 6.478 6.478 0.000 98 4481816 160.0 171.3 68 Methylcyclohexane 55 6.548 6.548 0.000 90 736103 50.0 42.6 69 1,2-Dichloropropane 63 6.576 6.575 0.001 97 688593 50.0 51.0 71 1,4-Dioxane 88 6.631 6.631 0.000 91 785207 1000.0 1001.1 72 Dibromomethane 93 6.659 6.659 0.000 97 415933 50.0 48.9 73 Dichlorobromomethane 83 6.799 6.799 0.000 100 703971 50.0 49.0 75 2-Chloroethyl vinyl ether 63 7.022 7.022 0.000 91 287572 50.0 63.7 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 1012252 50.0 56.5 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.302 0.000 93 5299287 200.0 215.7 80 Toluene 91 7.483 7.483 0.000 99 2944613 50.0 47.4 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 870857 50.0 56.8 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 1163858 50.0 54.4 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 90 656469 50.0 49.2 89 Tetrachloroethene 164 7.958 7.958 0.000 97 487556 50.0 45.6 90 1,3-Dichloropropane 76 8.014 8.014 0.000 97 1140761 50.0 51.4 91 2-Hexanone 43 8.042 8.042 0.000 93 4587515 200.0 218.4 93 Chlorodibromomethane 129 8.224 8.223 0.001 90 501229 50.0 52.2 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 691702 50.0 52.2 96 1-Chlorohexane 91 8.754 8.754 0.000 94 709039 40.0 37.1 97 Chlorobenzene 112 8.796 8.796 0.000 95 1797340 50.0 48.1 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 42 517538 50.0 52.3 98 Ethylbenzene 106 8.880 8.880 0.000 98 1019946 50.0 47.8 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 1244842 50.0 49.8 101 o-Xylene 106 9.369 9.369 0.000 96 1206707 50.0 48.8 103 Styrene 104 9.397 9.397 0.000 96 2022363 50.0 50.1 104 Bromoform 173 9.578 9.578 0.000 96 316190 50.0 42.5 105 Isopropylbenzene 105 9.718 9.718 0.000 96 2739133 50.0 49.1 107 Cyclohexanone 55 9.830 9.830 0.000 88 5970435 1500.0 1921.1 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 1076009 50.0 52.0 109 Bromobenzene 156 10.053 10.053 0.000 94 702905 50.0 47.3 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 88 240320 50.0 53.1 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 362048 50.0 52.9 112 N-Propylbenzene 120 10.137 10.137 0.000 99 827620 50.0 47.4 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 691588 50.0 48.8 114 1,3,5-Trimethylbenzene 105 10.305 10.304 0.001 94 2415610 50.0 49.5 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 735171 50.0 48.0 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 2034810 50.0 48.1 Page 399 of 426 Report Date: 21-Oct-2024 01:04:21 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0597.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 2480285 50.0 48.7 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 600494 50.0 49.1 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 1325607 50.0 47.5 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 2518008 50.0 48.3 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 94 1356053 50.0 47.4 124 n-Butylbenzene 91 11.408 11.408 0.000 97 2256274 50.0 48.9 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 1268485 50.0 47.5 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 87 300488 50.0 53.1 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 95 702826 50.0 46.7 129 Hexachlorobutadiene 225 13.196 13.195 0.001 98 238614 50.0 45.7 130 Naphthalene 128 13.335 13.335 0.000 97 2967351 50.0 50.3 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 95 648051 50.0 48.3 S 147 1,2-Dichloroethene, Total (URS) 96 0 100.0 95.3 S 154 1,3-Dichloropropene, Total 1 0 100.0 113.3 S 153 1,2-Dichloroethene, Total 1 0 100.0 95.3 S 152 Trihalomethanes, Total 1 0 200.0 191.7 S 150 Xylenes, Total (URS) 1 0 100.0 98.5 S 148 Xylenes, Total 106 0 100.0 98.5 QC Flag Legend Processing Flags Reagents: MV-MegaMainA_00115 Amount Added: 25.00 Units: uL MV-Gas A_00200 Amount Added: 10.00 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 400 of 426 Report Date: 21-Oct-2024 01:04:21 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0597.D Injection Date: 20-Oct-2024 22:21:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: LCSD Worklist Smp#: 6 Client ID: Purge Vol: 5.000 mL Dil. Factor: 1.0000 ALS Bottle#: 27 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Y ( X10 0 0 0 0 0 ) MS1_0597[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) B r o m o m e t h a n e ( 2 . 4 8 3 ) C h l o r o e t h a n e ( 2 . 6 0 9 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 7 )+ E t h yl e t h e r ( 3 . 1 6 8 ) A c r o l e i n ( 3 . 3 0 7 ) 1 ,1- D i c h l o r o e t h e n e ( 3 . 4 0 5 )+ C a r b o n dis u l f i de( 3 . 6 2 9 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 6 4 )+ A c r ylo n i t r i l e ( 4 . 1 0 4 )+ Hexan e ( 4 . 3 8 3 ) V i n yl a c e t a t e ( 4 . 5 2 3 )+ 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ s e c - B u t yl A l c o h o l ( 5 . 1 6 5 ) Tet r a h yd ro f u r a n ( 5 . 2 4 9 )+ C h l o r o f o r m ( 5 . 3 3 3 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 7 2 )+ C ycl o h e xan e ( 5 . 5 4 2 ) C a r b o n t e t r a c h l o r i de( 5 . 6 6 8 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 ) 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 2 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 2 2 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tri c h l o r o e t h a n e ( 7 . 8 6 0 ) 1 ,3- D i c h l o r o p r o p a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 4 ) E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 ) C ycl o h e xan o n e ( 9 . 8 3 0 ) $ 4 - B r o m o f l u o r o b e n zen e (Su r r )( 9 . 9 0 0 ) N-P r o p ylb e n zen e ( 1 0 . 1 3 7 ) 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Trim e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) 1 ,3- D i c h l o r o b e n zen e ( 1 0 . 9 8 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 401 of 426 Report Date: 21-Oct-2024 01:04:21 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0597.D Lims ID: LCSD Client ID: Sample Type: LCSD Inject. Date: 20-Oct-2024 22:21:30 ALS Bottle#: 27 Worklist Smp#: 6 Purge Vol: 5.000 mL Dil. Factor: 1.0000 Sample Info: lcsd Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 01:03:50 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1626 First Level Reviewer: BX8N Date:21-Oct-2024 00:50:35 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 49.9 99.82 $5 1,2-Dichloroethane-d4 (Surr)50.0 49.7 99.37 $6 Toluene-d8 (Surr)50.0 51.7 103.36 $7 4-Bromofluorobenzene (Surr)50.0 51.0 102.08 Page 402 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:MW-03 MS Lab Sample ID:280-197896-5 MS Matrix:MS1_0612.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 12:30 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:5 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 03:49 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 5.0 0.7271-43-2 Benzene 285 5.0 0.72100-41-4 Ethylbenzene 121 15 5.091-20-3 Naphthalene 130 5.0 1.6108-88-3 Toluene 123 5.0 0.571330-20-7 Xylenes, Total 249 %RECCAS NO.LIMITSQSURROGATE 101 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 101 78-120460-00-4 4-Bromofluorobenzene (Surr) 103 80-1252037-26-5 Toluene-d8 (Surr) 99 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 403 of 426 Report Date: 21-Oct-2024 07:14:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0612.D Lims ID: 280-197896-A-5 MS Client ID: MW-03 Sample Type: MS Inject. Date: 21-Oct-2024 03:49:30 ALS Bottle#: 12 Worklist Smp#: 24 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Sample Info: 280-197896-A-5 MS 5x Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3385221 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 89 771285 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 94 1209239 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 746688 50.0 49.3 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.751 5.751 0.000 0 833920 50.0 50.3 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3385390 50.0 51.4 $ 7 4-Bromofluorobenzene (Surr) 95 9.899 9.899 0.000 87 1138111 50.0 50.7 $ 8 BFB 95 9.899 9.900 -0.001 84 1138111 NR 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 333544 25.0 22.5 10 Chloromethane 50 2.008 2.009 -0.001 99 412488 25.0 26.9 11 Vinyl chloride 62 2.134 2.134 0.000 97 364735 25.0 26.1 12 Ethylene oxide 43 2.260 2.260 0.000 91 40018 NC 13 Bromomethane 94 2.455 2.483 -0.028 90 95429 25.0 10.9 14 Chloroethane 64 2.581 2.609 -0.028 99 218948 25.0 22.8 15 Dichlorofluoromethane 67 2.832 2.846 -0.014 97 613112 25.0 25.9 16 Trichlorofluoromethane 101 2.860 2.874 -0.014 98 385215 25.0 22.2 17 Ethanol 45 3.098 3.070 0.028 91 8905 12.8 18 Ethyl ether 59 3.168 3.168 0.000 87 279391 25.0 24.7 19 Propene oxide 58 3.307 3.238 0.069 21 2226 NC 20 Acrolein 56 3.307 3.307 0.000 99 628110 246.9 257.8 22 1,1-Dichloroethene 96 3.391 3.405 -0.014 98 281400 25.0 23.7 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.405 3.419 -0.014 94 174871 25.0 19.6 23 Acetone 43 3.447 3.447 0.000 100 1156979 100.0 109.9 24 Iodomethane 142 3.545 3.559 -0.014 97 278417 25.0 20.5 25 Isopropyl alcohol 45 3.601 3.587 0.014 43 19253 4.45 26 Carbon disulfide 76 3.615 3.629 -0.014 98 724193 25.0 22.5 27 Acetonitrile 41 3.726 ND 28 Methyl acetate 43 3.740 3.740 0.000 97 1046504 50.0 53.6 29 3-Chloro-1-propene 41 3.754 3.754 0.000 92 404182 25.0 26.9 30 Methylene Chloride 84 3.880 3.880 0.000 87 334467 25.0 25.4 31 2-Methyl-2-propanol 59 3.978 3.964 0.014 99 2052385 250.0 264.6 32 Acrylonitrile 53 4.103 4.103 0.000 99 2854889 250.0 277.4 33 Methyl tert-butyl ether 73 4.117 4.117 0.000 94 981603 25.0 24.7 Page 404 of 426 Report Date: 21-Oct-2024 07:14:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0612.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 96 315470 25.0 24.2 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.369 4.383 -0.014 89 362198 25.0 21.8 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.522 4.522 0.000 97 1419549 50.0 56.0 39 1,1-Dichloroethane 63 4.522 4.536 -0.014 96 552765 25.0 24.9 40 Isopropyl ether 87 4.522 4.550 -0.028 31 21121 1.80 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 90 11471 0.6477 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 96 20946 0.5680 44 2-Butanone (MEK) 43 5.011 5.011 0.000 99 1965874 100.0 110.0 46 2,2-Dichloropropane 77 5.039 5.039 0.000 89 345168 25.0 24.2 45 cis-1,2-Dichloroethene 96 5.025 5.039 -0.014 80 349562 25.0 23.7 47 Ethyl acetate 43 5.039 ND 48 Propionitrile 54 5.081 5.081 0.000 96 7500 1.36 49 sec-Butyl Alcohol 45 5.165 ND ND 50 Methacrylonitrile 41 5.179 5.207 -0.028 39 465851 38.9 52 Tetrahydrofuran 42 5.249 5.249 0.000 87 624491 50.0 55.8 51 Chlorobromomethane 128 5.235 5.249 -0.014 94 156297 25.0 23.3 53 Chloroform 83 5.318 5.319 0.000 92 518541 25.0 24.1 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 388966 25.0 23.4 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.472 5.505 -0.033 45 54526 NC 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.528 5.542 -0.014 88 488251 25.0 22.7 58 1,1-Dichloropropene 75 5.612 5.612 0.000 98 431974 25.0 24.0 59 Carbon tetrachloride 117 5.612 5.612 0.000 70 267469 25.0 21.8 60 Isobutyl alcohol 41 5.682 5.668 0.014 96 1429154 625.0 667.0 61 Benzene 78 5.779 5.779 0.000 96 3189581 25.0 57.0 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 390681 25.0 23.3 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 95 18247 0.4890 64 n-Heptane 43 6.003 6.003 0.000 90 297939 25.0 22.3 65 n-Butanol 56 6.254 6.226 0.028 80 4524 2.18 66 Trichloroethene 95 6.338 6.338 0.000 98 308981 25.0 23.6 67 2-Pentanone 43 6.478 6.478 0.000 98 2178914 80.0 86.8 68 Methylcyclohexane 55 6.547 6.548 -0.001 90 345755 25.0 20.9 69 1,2-Dichloropropane 63 6.575 6.575 0.000 98 329356 25.0 25.4 70 Methyl methacrylate 100 6.589 6.590 -0.001 81 8553 1.49 71 1,4-Dioxane 88 6.645 6.631 0.014 90 390418 500.0 518.9 72 Dibromomethane 93 6.645 6.659 -0.014 98 191798 25.0 23.5 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 305718 25.0 22.2 74 2-Nitropropane 41 6.995 ND 75 2-Chloroethyl vinyl ether 63 7.022 7.022 0.000 53 2474 25.0 0.5714 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 98 450363 25.0 25.8 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.302 0.000 93 2549700 100.0 108.2 80 Toluene 91 7.483 7.483 0.000 98 1461089 25.0 24.5 81 2,2,3-Trimethylbutane 57 7.469 7.502 -0.033 23 1449 NC 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 384147 25.0 26.1 83 3,3-Dimethylpentane 43 7.707 7.682 0.025 32 17858 NC 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 532080 25.0 25.5 85 2-Methylhexane 43 7.810 ND Page 405 of 426 Report Date: 21-Oct-2024 07:14:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0612.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 88 315640 25.0 24.7 87 3-Methylhexane 43 7.916 7.903 0.013 46 2129 NC 88 2,3-Dimethylpentane 56 8.042 7.949 0.093 47 26438 NC 89 Tetrachloroethene 164 7.958 7.958 0.000 96 238750 25.0 22.9 90 1,3-Dichloropropane 76 8.014 8.014 0.000 88 551451 25.0 25.5 91 2-Hexanone 43 8.042 8.042 0.000 94 2223533 100.0 108.7 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.223 8.223 0.000 90 204192 25.0 21.8 94 Tetrahydrothiophene 60 8.209 8.224 -0.015 43 3200 NC 95 Ethylene Dibromide 107 8.349 8.349 0.000 99 321501 25.0 24.9 96 1-Chlorohexane 91 8.754 8.754 0.000 95 355035 20.0 19.0 97 Chlorobenzene 112 8.796 8.796 0.000 96 890291 25.0 24.5 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 41 233500 25.0 24.2 98 Ethylbenzene 106 8.880 8.880 0.000 97 503128 25.0 24.2 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 612094 25.0 25.1 101 o-Xylene 106 9.369 9.369 0.000 96 591891 25.0 24.6 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.397 9.397 0.000 96 965166 25.0 24.6 104 Bromoform 173 9.578 9.578 0.000 95 118776 25.0 16.9 105 Isopropylbenzene 105 9.718 9.718 0.000 95 1346194 25.0 24.7 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 7792 3.82 107 Cyclohexanone 55 9.830 9.830 0.000 89 1700265 750.0 561.6 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 93 523242 25.0 25.9 109 Bromobenzene 156 10.053 10.053 0.000 94 339372 25.0 23.4 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 83 97176 25.0 22.4 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 171498 25.0 25.5 112 N-Propylbenzene 120 10.137 10.137 0.000 98 401288 25.0 23.5 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 334052 25.0 24.1 114 1,3,5-Trimethylbenzene 105 10.304 10.304 0.000 93 1169276 25.0 24.5 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 355419 25.0 23.8 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 990328 25.0 23.9 117 1,2,4-Trimethylbenzene 105 10.681 10.682 -0.001 97 1234534 25.0 24.8 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 282606 25.0 23.6 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 98 630307 25.0 23.1 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 1238862 25.0 24.3 121 1,4-Dichlorobenzene 146 11.073 11.073 -0.001 96 653769 25.0 23.4 122 1,2,3-Trimethylbenzene 105 11.100 11.101 -0.001 93 47059 0.9247 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 11.408 0.000 97 1090680 25.0 24.2 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 98 610511 25.0 23.4 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 86 129137 25.0 23.3 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 93 14073 0.8909 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 95 348756 25.0 23.7 129 Hexachlorobutadiene 225 13.195 13.195 0.000 96 122635 25.0 24.0 130 Naphthalene 128 13.335 13.335 0.000 97 1495303 25.0 25.9 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 13.559 -0.001 96 327939 25.0 25.0 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND 135 t-Amyl alcohol 1 0.000 ND Page 406 of 426 Report Date: 21-Oct-2024 07:14:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0612.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 137 1-Chlorohexane TIC 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 0 50.0 47.9 S 154 1,3-Dichloropropene, Total 1 0 50.0 51.9 S 153 1,2-Dichloroethene, Total 1 0 50.0 47.9 S 152 Trihalomethanes, Total 1 0 100.0 85.0 S 151 Total BTEX 1 0 155.4 S 150 Xylenes, Total (URS) 1 0 50.0 49.7 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0 50.0 49.7 QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated ND - Not Detected or Marked ND Reagents: MV-Gas A_00200 Amount Added: 5.00 Units: uL MV-MegaMainA_00115 Amount Added: 12.50 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 407 of 426 Report Date: 21-Oct-2024 07:14:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0612.D Injection Date: 21-Oct-2024 03:49:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-A-5 MS Worklist Smp#: 24 Client ID: MW-03 Purge Vol: 5.000 mL Dil. Factor: 5.0000 ALS Bottle#: 12 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 Y ( X10 0 0 0 0 ) MS1_0612[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 8 ) V i n yl c h l o r i de( 2 . 1 7 6 ) E t h yle n e o xide( 2 . 2 7 4 ) B r o m o m e t h a n e ( 2 . 4 5 5 ) C h l o r o e t h a n e ( 2 . 5 8 1 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 3 2 )+ E t h a n o l ( 3 . 1 6 8 )+ P r o p e n e o xide( 3 . 3 0 7 )+ 1 ,1- D i c h l o r o e t h e n e ( 3 . 3 9 1 )+ I o dom e t h a n e ( 3 . 6 1 5 )+ M e t h yl a c e t a t e ( 3 . 7 5 4 )+ M e t h yle n e C h l o r i de( 3 . 8 8 0 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 7 8 ) A c r ylo n i t r i l e ( 4 . 1 0 3 )+ Hexan e ( 4 . 3 6 9 ) V i n yl a c e t a t e ( 4 . 5 2 2 )+ 2 - C h l o r o - 1 ,3- b u t a die n e ( 4 . 6 2 0 ) Ter t - b u t yl e t h yl e t h e r ( 4 . 8 5 8 ) 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ M e t h a c r ylo n i t r i l e ( 5 . 1 7 9 )+ C h l o r o f o r m ( 5 . 3 3 2 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 )+ I s o b u t yl a l c o h o l ( 5 . 6 8 2 ) $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 )+ 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 1 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 3 6 ) c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 1 ,1,2- Tric h l o r o e t h a n e ( 7 . 8 6 0 )+ 2 ,3- D i m e t h ylp e n t a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 3 )+ E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 9 . 0 0 6 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 )+ C yclo h e xan o n e ( 9 . 8 3 0 )+ N-P r o p ylb e n zen e ( 1 0 . 1 3 7 ) 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 5 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 5 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 408 of 426 Report Date: 21-Oct-2024 07:14:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0612.D Lims ID: 280-197896-A-5 MS Client ID: MW-03 Sample Type: MS Inject. Date: 21-Oct-2024 03:49:30 ALS Bottle#: 12 Worklist Smp#: 24 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Sample Info: 280-197896-A-5 MS 5x Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 49.3 98.51 $5 1,2-Dichloroethane-d4 (Surr)50.0 50.3 100.61 $6 Toluene-d8 (Surr)50.0 51.4 102.76 $7 4-Bromofluorobenzene (Surr)50.0 50.7 101.37 Page 409 of 426 FORM I GC/MS VOA ORGANICS ANALYSIS DATA SHEET Lab Name:Job No.:280-197896-1Eurofins Denver SDG No.: Client Sample ID:MW-03 MSD Lab Sample ID:280-197896-5 MSD Matrix:MS1_0613.DLab File ID: Date Collected:8260DAnalysis Method: Water 10/09/2024 12:30 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:5 Level: (low/med)Low 5(mL) 0.25(mm) Date Analyzed:10/21/2024 04:10 ID:DB-624 (60.25) % Solids: NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH: Analysis Batch No.:671719 ug/LUnits: Preparation Batch No.:Instrument ID:VMS_MS1 CAS NO.COMPOUND NAME RESULT Q MDLRL 5.0 0.7271-43-2 Benzene 283 5.0 0.72100-41-4 Ethylbenzene 121 15 5.091-20-3 Naphthalene 129 5.0 1.6108-88-3 Toluene 122 5.0 0.571330-20-7 Xylenes, Total 248 %RECCAS NO.LIMITSQSURROGATE 99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr) 101 78-120460-00-4 4-Bromofluorobenzene (Surr) 102 80-1252037-26-5 Toluene-d8 (Surr) 98 77-1201868-53-7 Dibromofluoromethane (Surr) FORM I 8260D Page 410 of 426 Report Date: 21-Oct-2024 07:14:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Target Compound Quantitation Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0613.D Lims ID: 280-197896-A-5 MSD Client ID: MW-03 Sample Type: MSD Inject. Date: 21-Oct-2024 04:10:30 ALS Bottle#: 13 Worklist Smp#: 25 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Sample Info: 280-197896-A-5 MSD 5x Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags * 1 Fluorobenzene 96 6.031 6.031 0.000 99 3466509 50.0 50.0 * 2 Chlorobenzene-d5 119 8.768 8.768 0.000 85 786657 50.0 50.0 * 3 1,4-Dichlorobenzene-d4 152 11.059 11.059 0.000 95 1220901 50.0 50.0 $ 4 Dibromofluoromethane (Surr) 111 5.458 5.458 0.000 94 760371 50.0 49.0 $ 5 1,2-Dichloroethane-d4 (Surr) 65 5.752 5.751 0.001 0 843875 50.0 49.7 $ 6 Toluene-d8 (Surr) 98 7.427 7.427 0.000 92 3443469 50.0 51.2 $ 7 4-Bromofluorobenzene (Surr) 95 9.900 9.899 0.001 87 1150375 50.0 50.7 $ 8 BFB 95 9.900 9.900 0.000 84 1150375 NR 9 Dichlorodifluoromethane 85 1.799 1.799 0.000 99 333164 25.0 22.0 10 Chloromethane 50 2.009 2.009 0.000 99 409816 25.0 26.1 11 Vinyl chloride 62 2.134 2.134 0.000 97 368069 25.0 25.7 12 Ethylene oxide 43 2.260 2.260 0.000 92 41471 NC 13 Bromomethane 94 2.455 2.483 -0.028 90 96663 25.0 10.7 14 Chloroethane 64 2.567 2.609 -0.042 100 222731 25.0 22.6 15 Dichlorofluoromethane 67 2.833 2.846 -0.013 97 627551 25.0 25.9 16 Trichlorofluoromethane 101 2.861 2.874 -0.013 97 390807 25.0 22.0 17 Ethanol 45 3.168 3.070 0.098 65 196049 275.7 18 Ethyl ether 59 3.168 3.168 0.000 88 277745 25.0 23.9 19 Propene oxide 58 3.307 3.238 0.069 21 2899 NC 20 Acrolein 56 3.307 3.307 0.000 99 621400 246.9 249.1 22 1,1-Dichloroethene 96 3.391 3.405 -0.014 97 289124 25.0 23.8 21 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.405 3.419 -0.014 91 177840 25.0 19.5 23 Acetone 43 3.447 3.447 0.000 99 1150024 100.0 106.6 24 Iodomethane 142 3.545 3.559 -0.014 96 273856 25.0 19.7 25 Isopropyl alcohol 45 3.629 3.587 0.042 52 18711 4.23 26 Carbon disulfide 76 3.615 3.629 -0.014 98 739362 25.0 22.4 27 Acetonitrile 41 3.726 ND 28 Methyl acetate 43 3.740 3.740 0.000 97 1046916 50.0 52.3 29 3-Chloro-1-propene 41 3.754 3.754 0.000 92 412203 25.0 26.8 30 Methylene Chloride 84 3.880 3.880 0.000 88 344945 25.0 25.5 31 2-Methyl-2-propanol 59 3.978 3.964 0.014 99 2042800 250.0 257.2 32 Acrylonitrile 53 4.104 4.103 0.001 99 2845714 250.0 270.0 33 Methyl tert-butyl ether 73 4.117 4.117 0.000 95 1008585 25.0 24.8 Page 411 of 426 Report Date: 21-Oct-2024 07:14:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0613.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 34 trans-1,2-Dichloroethene 96 4.131 4.131 0.000 94 322327 25.0 24.1 35 Chlorotrifluoroethene 116 4.248 ND 36 Hexane 57 4.369 4.383 -0.014 89 364679 25.0 21.5 37 1,2-Dichloro-1,1,2,2-tetrafluoro 85 4.472 ND 38 Vinyl acetate 43 4.523 4.522 0.000 97 1409996 50.0 54.4 39 1,1-Dichloroethane 63 4.523 4.536 -0.014 96 559537 25.0 24.6 40 Isopropyl ether 87 4.523 4.550 -0.028 30 23270 1.94 41 2-Chloro-1,3-butadiene 53 4.592 4.592 0.000 87 11755 0.6482 42 2-Chloro-1,1,1-Trifluoroethane 118 4.737 ND 43 Tert-butyl ethyl ether 59 4.858 4.858 0.000 94 22786 0.6034 44 2-Butanone (MEK) 43 5.011 5.011 0.000 98 1959057 100.0 107.1 46 2,2-Dichloropropane 77 5.039 5.039 0.000 83 355256 25.0 24.3 45 cis-1,2-Dichloroethene 96 5.025 5.039 -0.014 80 362042 25.0 24.0 47 Ethyl acetate 43 5.039 ND 48 Propionitrile 54 5.081 5.081 0.000 96 7432 1.31 49 sec-Butyl Alcohol 45 5.165 ND ND 50 Methacrylonitrile 41 5.179 5.207 -0.028 39 477779 39.0 52 Tetrahydrofuran 42 5.249 5.249 0.000 88 630555 50.0 55.0 51 Chlorobromomethane 128 5.235 5.249 -0.014 95 156905 25.0 22.8 53 Chloroform 83 5.319 5.319 0.001 93 532623 25.0 24.2 54 1,1,1-Trichloroethane 97 5.472 5.472 0.000 98 401044 25.0 23.5 55 1,2-Dichloro-1,1,2-trifluoroetha 117 5.472 5.505 -0.033 45 54674 NC 56 1,1,1-Trifluoro-2,2-dichloroetha 83 5.533 ND 57 Cyclohexane 56 5.528 5.542 -0.014 89 492512 25.0 22.3 58 1,1-Dichloropropene 75 5.612 5.612 0.000 98 440207 25.0 23.9 59 Carbon tetrachloride 117 5.612 5.612 0.000 69 268416 25.0 21.4 60 Isobutyl alcohol 41 5.682 5.668 0.014 95 1413663 625.0 644.7 61 Benzene 78 5.779 5.779 0.000 96 3240041 25.0 56.6 62 1,2-Dichloroethane 62 5.821 5.821 0.000 97 396476 25.0 23.1 63 Tert-amyl methyl ether 73 5.877 5.877 0.000 93 18403 0.4816 64 n-Heptane 43 6.003 6.003 0.000 89 299244 25.0 21.9 65 n-Butanol 56 6.240 6.226 0.014 77 3749 1.76 66 Trichloroethene 95 6.338 6.338 0.000 99 327333 25.0 24.5 67 2-Pentanone 43 6.478 6.478 0.000 98 2183131 80.0 85.0 68 Methylcyclohexane 55 6.548 6.548 0.000 90 360379 25.0 21.2 69 1,2-Dichloropropane 63 6.576 6.575 0.001 97 334215 25.0 25.2 70 Methyl methacrylate 100 6.590 6.590 0.000 79 7810 1.33 71 1,4-Dioxane 88 6.631 6.631 0.000 91 386172 500.0 501.2 72 Dibromomethane 93 6.645 6.659 -0.014 97 197121 25.0 23.6 73 Dichlorobromomethane 83 6.799 6.799 0.000 99 305825 25.0 21.7 74 2-Nitropropane 41 6.981 6.995 -0.014 61 1192 2.25 75 2-Chloroethyl vinyl ether 63 7.022 7.022 0.000 54 1756 25.0 0.3960 76 cis-1,3-Dichloropropene 75 7.176 7.176 0.000 97 455229 25.0 25.6 77 2,2-Dimethylpentane 57 7.278 ND 78 2,4-Dimethylpentane 43 7.292 ND 79 4-Methyl-2-pentanone (MIBK) 43 7.302 7.302 0.000 94 2553650 100.0 105.8 80 Toluene 91 7.483 7.483 0.000 98 1483410 25.0 24.3 81 2,2,3-Trimethylbutane 57 7.502 ND 82 trans-1,3-Dichloropropene 75 7.679 7.679 0.000 90 379259 25.0 25.2 83 3,3-Dimethylpentane 43 7.707 7.682 0.025 33 17143 NC 84 Ethyl methacrylate 69 7.707 7.707 0.000 87 541457 25.0 25.5 85 2-Methylhexane 43 7.846 7.810 0.036 11 1366 NC Page 412 of 426 Report Date: 21-Oct-2024 07:14:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0613.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 86 1,1,2-Trichloroethane 97 7.860 7.860 0.000 89 316165 25.0 24.1 87 3-Methylhexane 43 7.903 ND 88 2,3-Dimethylpentane 56 8.042 7.949 0.093 56 23600 NC 89 Tetrachloroethene 164 7.958 7.958 0.000 97 243540 25.0 22.9 90 1,3-Dichloropropane 76 8.014 8.014 0.000 97 546311 25.0 24.8 91 2-Hexanone 43 8.042 8.042 0.000 93 2208621 100.0 105.8 92 3-Ethylpentane 43 8.214 ND 93 Chlorodibromomethane 129 8.224 8.223 0.001 91 206160 25.0 21.6 94 Tetrahydrothiophene 60 8.210 8.224 -0.014 44 3411 NC 95 Ethylene Dibromide 107 8.349 8.349 0.000 98 327706 25.0 24.9 96 1-Chlorohexane 91 8.754 8.754 0.000 96 358111 20.0 18.8 97 Chlorobenzene 112 8.796 8.796 0.000 95 890888 25.0 24.0 99 1,1,1,2-Tetrachloroethane 131 8.880 8.880 0.000 41 232913 25.0 23.7 98 Ethylbenzene 106 8.880 8.880 0.000 97 512319 25.0 24.2 100 m-Xylene & p-Xylene 106 9.006 9.006 0.000 0 617800 25.0 24.9 101 o-Xylene 106 9.369 9.369 0.000 97 608110 25.0 24.7 102 Dimethyl disulfide 94 9.388 ND 103 Styrene 104 9.383 9.397 -0.014 95 971751 25.0 24.2 104 Bromoform 173 9.578 9.578 0.000 96 120087 25.0 16.7 105 Isopropylbenzene 105 9.718 9.718 0.000 95 1375505 25.0 25.0 106 cis-1,4-Dichloro-2-butene 53 9.774 9.774 0.000 0 6379 3.41 107 Cyclohexanone 55 9.830 9.830 0.000 89 1712552 750.0 554.6 108 1,1,2,2-Tetrachloroethane 83 10.025 10.025 0.000 94 519407 25.0 25.4 109 Bromobenzene 156 10.053 10.053 0.000 94 350549 25.0 23.9 110 trans-1,4-Dichloro-2-butene 53 10.053 10.053 0.000 80 94332 25.0 21.5 111 1,2,3-Trichloropropane 110 10.081 10.081 0.000 83 168766 25.0 24.9 112 N-Propylbenzene 120 10.137 10.137 0.000 98 403050 25.0 23.4 113 2-Chlorotoluene 126 10.235 10.235 0.000 97 344375 25.0 24.6 114 1,3,5-Trimethylbenzene 105 10.305 10.304 0.001 94 1201719 25.0 25.0 115 4-Chlorotoluene 126 10.346 10.346 0.000 98 351165 25.0 23.2 116 tert-Butylbenzene 119 10.626 10.626 0.000 92 1026202 25.0 24.6 117 1,2,4-Trimethylbenzene 105 10.682 10.682 0.000 96 1235127 25.0 24.6 118 sec-Butylbenzene 134 10.849 10.849 0.000 93 297255 25.0 24.6 119 1,3-Dichlorobenzene 146 10.975 10.975 0.000 97 644629 25.0 23.4 120 4-Isopropyltoluene 119 10.989 10.989 0.000 97 1261623 25.0 24.5 121 1,4-Dichlorobenzene 146 11.073 11.073 0.000 95 661284 25.0 23.4 122 1,2,3-Trimethylbenzene 105 11.101 11.101 0.000 94 48933 0.9523 123 Pentachloroethane 167 11.283 ND 124 n-Butylbenzene 91 11.408 11.408 0.000 98 1107586 25.0 24.3 125 1,2-Dichlorobenzene 146 11.436 11.436 0.000 97 615769 25.0 23.4 126 1,2-Dibromo-3-Chloropropane 157 12.232 12.232 0.000 83 122096 25.0 21.9 127 1,3,5-Trichlorobenzene 180 12.413 12.413 0.000 97 12934 0.8109 128 1,2,4-Trichlorobenzene 180 13.056 13.056 0.000 94 348097 25.0 23.4 129 Hexachlorobutadiene 225 13.196 13.195 0.001 97 128749 25.0 25.0 130 Naphthalene 128 13.335 13.335 0.000 97 1503447 25.0 25.8 131 n-Nonyl Aldehyde 57 13.340 ND 132 1,2,3-Trichlorobenzene 180 13.559 13.559 0.000 96 334973 25.0 25.3 140 n-Nonane TIC 1 0.000 ND 143 1,4-Dibromobenzene 1 0.000 ND 138 Pentachloroethane TIC 1 0.000 ND 139 1-Chloro-1-fluoroethane TIC 1 0.000 ND 135 t-Amyl alcohol 1 0.000 ND Page 413 of 426 Report Date: 21-Oct-2024 07:14:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0613.D Compound Sig RT (min.) Exp RT (min.) Dlt RT (min.)Q Response Cal Amt ug/l OnCol Amt ug/l Flags 137 1-Chlorohexane TIC 1 0.000 ND 134 1,3-Dibromobenzene 1 0.000 ND 136 4-Bromofluorobenzene 95 0.000 ND 141 Benzene, 1-bromo-4-ethyl- 1 0.000 ND 145 4-Chlorobenzotrifluoride 1 0.000 ND 146 Benzene, 1-bromo-3-fluoro- 1 0.000 ND 144 1-Bromo-2-chloroethane 1 0.000 ND 133 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND 142 Ethyl acrylate 55 0.000 ND S 147 1,2-Dichloroethene, Total (URS) 96 0 50.0 48.1 S 154 1,3-Dichloropropene, Total 1 0 50.0 50.8 S 153 1,2-Dichloroethene, Total 1 0 50.0 48.1 S 152 Trihalomethanes, Total 1 0 100.0 84.2 S 151 Total BTEX 1 0 154.6 S 150 Xylenes, Total (URS) 1 0 50.0 49.6 S 149 TAH 1 0 0 S 148 Xylenes, Total 106 0 50.0 49.6 QC Flag Legend Processing Flags NR - Missing Quant Standard NC - Not Calibrated ND - Not Detected or Marked ND Reagents: MV-Gas A_00200 Amount Added: 5.00 Units: uL MV-MegaMainA_00115 Amount Added: 12.50 Units: uL mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent Page 414 of 426 Report Date: 21-Oct-2024 07:14:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0613.D Injection Date: 21-Oct-2024 04:10:30 Instrument ID: VMS_MS1 Operator ID: bustillose Lims ID: 280-197896-A-5 MSD Worklist Smp#: 25 Client ID: MW-03 Purge Vol: 5.000 mL Dil. Factor: 5.0000 ALS Bottle#: 13 Method:AQ_VMS1_8260 Limit Group: MSV - 8260B Water and Solid Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) MS1_0613[MS SCAN Chro]:Total C h l o r o m e t h a n e ( 2 . 0 0 9 ) V i n yl c h l o r i de( 2 . 1 7 6 ) E t h yle n e o xide( 2 . 2 7 4 ) B r o m o m e t h a n e ( 2 . 4 5 5 ) C h l o r o e t h a n e ( 2 . 5 6 7 ) D i c h l o r o f l u o r o m e t h a n e ( 2 . 8 4 7 )+ E t h a n o l ( 3 . 1 6 8 )+ P r o p e n e o xide( 3 . 3 0 7 )+ 1 ,1- D i c h l o r o e t h e n e ( 3 . 3 9 1 )+ I o dom e t h a n e ( 3 . 6 1 5 )+ M e t h yl a c e t a t e ( 3 . 7 4 0 )+ M e t h yle n e C h l o r i de( 3 . 8 8 0 ) 2 - M e t h yl- 2 - p r o p a n o l ( 3 . 9 7 8 ) A c r ylo n i t r i l e ( 4 . 1 0 4 )+ Hexan e ( 4 . 3 6 9 ) V i n yl a c e t a t e ( 4 . 5 2 3 )+ Ter t - b u t yl e t h yl e t h e r ( 4 . 8 7 2 ) 2 - B u t a n o n e (ME K) ( 5 . 0 2 5 )+ M e t h a c r ylo n i t r i l e ( 5 . 1 7 9 )+ C h l o r o f o r m ( 5 . 3 3 3 ) $ D i b r o m o f l u o r o m e t h a n e (Su r r )( 5 . 4 5 8 )+ C ycl o h e xan e ( 5 . 5 4 2 ) I s o b u t yl a l c o h o l ( 5 . 6 8 2 )+ $ 1 ,2- D i c h l o r o e t h a n e - d4 (Su r r )( 5 . 7 7 9 )+ * F l u o r o b e n zen e ( 6 . 0 3 1 )+ Tri c h l o r o e t h e n e ( 6 . 3 3 8 )+ 2 - P e n t a n o n e ( 6 . 4 7 8 ) M e t h ylc ycl o h e xan e ( 6 . 5 6 2 )+ D i c h l o r o b r o m o m e t h a n e ( 6 . 7 9 9 ) 2 - C h l o r o e t h yl v i n yl e t h e r ( 7 . 0 3 6 )+ c i s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 1 7 6 ) 4 - M e t h yl- 2 - p e n t a n o n e (MI B K) ( 7 . 3 0 2 ) $ Tol u e n e - d8 (Su r r )( 7 . 4 2 7 )+ t r a n s - 1 ,3- D i c h l o r o p r o p e n e ( 7 . 7 0 7 )+ 2 - M e t h ylh e xan e ( 7 . 8 6 0 )+ 2 ,3- D i m e t h ylp e n t a n e ( 8 . 0 4 2 )+ C h l o r o dib r o m o m e t h a n e ( 8 . 2 2 4 )+ E t h yle n e D i b r o m i de( 8 . 3 4 9 ) * C h l o r o b e n zen e - d5( 8 . 7 6 8 )+ 1 ,1,1,2- Tet r a c h l o r o e t h a n e ( 8 . 8 8 0 )+ m - Xy le n e & p - Xy le n e ( 8 . 9 9 2 ) o - Xy le n e ( 9 . 3 8 3 )+ B r o m o f o r m ( 9 . 5 7 8 ) I s o p r o p ylb e n zen e ( 9 . 7 1 8 )+ C yclo h e xan o n e ( 9 . 8 3 0 )+ N-P r o p ylb e n zen e ( 1 0 . 1 3 7 ) 2 - C h l o r o t o l u e n e ( 1 0 . 2 3 5 ) 1 ,3,5- Tri m e t h ylb e n zen e ( 1 0 . 3 4 6 )+ t e r t - B u t ylb e n zen e ( 1 0 . 6 2 6 ) 1 ,2,4- Tri m e t h ylb e n zen e ( 1 0 . 6 9 6 ) s e c - B u t ylb e n zen e ( 1 0 . 8 4 9 ) * 1 ,4- D i c h l o r o b e n zen e - d4( 1 1 . 0 5 9 )+ n - B u t ylb e n zen e ( 1 1 . 4 0 8 )+ 1 ,2- D i b r o m o - 3 - C h l o r o p r o p a n e ( 1 2 . 2 3 2 ) 1 ,3,5- Tri c h l o r o b e n zen e ( 1 2 . 4 1 3 ) 1 ,2,4- Tri c h l o r o b e n zen e ( 1 3 . 0 5 6 ) Hexac h l o r o b u t a die n e ( 1 3 . 1 9 6 ) Nap h t h a l e n e ( 1 3 . 3 3 5 ) 1 ,2,3- Tri c h l o r o b e n zen e ( 1 3 . 5 5 9 ) Page 415 of 426 Report Date: 21-Oct-2024 07:14:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22 Eurofins Denver Recovery Report Data File: \\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\MS1_0613.D Lims ID: 280-197896-A-5 MSD Client ID: MW-03 Sample Type: MSD Inject. Date: 21-Oct-2024 04:10:30 ALS Bottle#: 13 Worklist Smp#: 25 Purge Vol: 5.000 mL Dil. Factor: 5.0000 Sample Info: 280-197896-A-5 MSD 5x Operator ID: bustillose Instrument ID: VMS_MS1 Method:\\chromfs\Denver\ChromData\VMS_MS1\20241020-138811.b\AQ_VMS1_8260.m Limit Group: MSV - 8260B Water and Solid Last Update: 21-Oct-2024 07:12:53 Calib Date: 16-Oct-2024 07:06:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Denver\ChromData\VMS_MS1\20241015-138641.b\MS1_0316.D Column 1 : DB-624 (60.25) ( 0.25 mm)Det: MS SCAN Process Host: CTX1687 Compound Amount Added Amount Recovered %Rec. $4 Dibromofluoromethane (Surr)50.0 49.0 97.96 $5 1,2-Dichloroethane-d4 (Surr)50.0 49.7 99.43 $6 Toluene-d8 (Surr)50.0 51.2 102.48 $7 4-Bromofluorobenzene (Surr)50.0 50.7 101.48 Page 416 of 426 Lab Name:Job No.: GC/MS VOA ANALYSIS RUN LOG Eurofins Denver 280-197896-1 SDG No.: Instrument ID: Analysis Batch Number: DILUTION FACTOR COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID VMS_MS1 671165 Start Date: End Date:10/16/2024 07:49 10/15/2024 22:07 BFB 280-671165/1 DB-624 (60.25) 0.25(mm)110/15/2024 22:07 MS1_0292.D IC 280-671165/13 DB-624 (60.25) 0.25(mm)110/16/2024 00:19 MS1_0297.D IC 280-671165/40 DB-624 (60.25) 0.25(mm)110/16/2024 00:40 MS1_0298.D IC 280-671165/41 DB-624 (60.25) 0.25(mm)110/16/2024 01:02 MS1_0299.D IC 280-671165/42 DB-624 (60.25) 0.25(mm)110/16/2024 01:23 MS1_0300.D IC 280-671165/43 DB-624 (60.25) 0.25(mm)110/16/2024 01:45 MS1_0301.D ICIS 280-671165/44 DB-624 (60.25) 0.25(mm)110/16/2024 02:06 MS1_0302.D IC 280-671165/45 DB-624 (60.25) 0.25(mm)110/16/2024 02:28 MS1_0303.D IC 280-671165/46 DB-624 (60.25) 0.25(mm)110/16/2024 02:49 MS1_0304.D IC 280-671165/47 DB-624 (60.25) 0.25(mm)110/16/2024 03:11 MS1_0305.D ICV 280-671165/48 DB-624 (60.25) 0.25(mm)110/16/2024 03:54 MS1_0307.D IC 280-671165/49 DB-624 (60.25) 0.25(mm)110/16/2024 04:36 MS1_0309.D IC 280-671165/50 DB-624 (60.25) 0.25(mm)110/16/2024 04:58 MS1_0310.D IC 280-671165/51 DB-624 (60.25) 0.25(mm)110/16/2024 05:19 MS1_0311.D IC 280-671165/52 DB-624 (60.25) 0.25(mm)110/16/2024 05:41 MS1_0312.D IC 280-671165/53 DB-624 (60.25) 0.25(mm)110/16/2024 06:02 MS1_0313.D IC 280-671165/54 DB-624 (60.25) 0.25(mm)110/16/2024 06:23 MS1_0314.D IC 280-671165/55 DB-624 (60.25) 0.25(mm)110/16/2024 06:45 MS1_0315.D IC 280-671165/56 DB-624 (60.25) 0.25(mm)110/16/2024 07:06 MS1_0316.D ICV 280-671165/57 DB-624 (60.25) 0.25(mm)110/16/2024 07:49 MS1_0318.D 8260D Page 417 of 426 Lab Name:Job No.: GC/MS VOA ANALYSIS RUN LOG Eurofins Denver 280-197896-1 SDG No.: Instrument ID: Analysis Batch Number: DILUTION FACTOR COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID VMS_MS1 671719 Start Date: End Date:10/21/2024 04:53 10/20/2024 21:17 BFB 280-671719/1 DB-624 (60.25) 0.25(mm)110/20/2024 21:17 MS1_0594A.D CCV 280-671719/3 DB-624 (60.25) 0.25(mm)110/20/2024 21:17 ZZZZZ (QC)DB-624 (60.25) 0.25(mm)110/20/2024 21:17 CCV 280-671719/2 DB-624 (60.25) 0.25(mm)110/20/2024 21:38 MS1_0595.D LCS 280-671719/4 DB-624 (60.25) 0.25(mm)110/20/2024 21:38 MS1_0595A.D ZZZZZ (QC)DB-624 (60.25) 0.25(mm)110/20/2024 22:00 LCSD 280-671719/6 DB-624 (60.25) 0.25(mm)110/20/2024 22:21 MS1_0597.D MB 280-671719/9 DB-624 (60.25) 0.25(mm)110/20/2024 23:26 MS1_0600.D 280-197896-1 TB-100924 DB-624 (60.25) 0.25(mm)110/20/2024 23:53 MS1_0601.D 280-197896-2 FB-100924 DB-624 (60.25) 0.25(mm)110/21/2024 00:15 MS1_0602.D 280-197896-5 MW-03 DB-624 (60.25) 0.25(mm)510/21/2024 00:36 MS1_0603.D ZZZZZ (Client)DB-624 (60.25) 0.25(mm)110/21/2024 00:58 ZZZZZ (Client)DB-624 (60.25) 0.25(mm)110/21/2024 01:19 ZZZZZ (Client)DB-624 (60.25) 0.25(mm)110/21/2024 01:40 280-197896-3 MW-05 DB-624 (60.25) 0.25(mm)110/21/2024 02:02 MS1_0607.D 280-197896-4 MW-905 DB-624 (60.25) 0.25(mm)110/21/2024 02:23 MS1_0608.D 280-197896-6 MW-16 DB-624 (60.25) 0.25(mm)110/21/2024 02:45 MS1_0609.D ZZZZZ (QC)DB-624 (60.25) 0.25(mm)110/21/2024 03:06 ZZZZZ (QC)DB-624 (60.25) 0.25(mm)110/21/2024 03:28 280-197896-5 MS MW-03 MS DB-624 (60.25) 0.25(mm)510/21/2024 03:49 MS1_0612.D 280-197896-5 MSD MW-03 MSD DB-624 (60.25) 0.25(mm)510/21/2024 04:10 MS1_0613.D CCVC 280-671719/27 DB-624 (60.25) 0.25(mm)110/21/2024 04:32 CCVC 280-671719/28 DB-624 (60.25) 0.25(mm)110/21/2024 04:53 8260D Page 418 of 426 Lab Name:Job No.: SDG No.: GC/MS VOA BATCH WORKSHEET 280-197896-1 Batch Number:Batch Analyst:Batch Start Date: Batch End Date: Jones, Branden M10/15/24 22:07671165 Batch Method: Eurofins Denver 8260D Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount Cal Dil Std 00422 mv-Cent BFB 00007 mv-Cent IS 00009 MV-Gas A 00198Matrix 2 uL 2 uL 5 uL8260DBFB 280-671165/1 5 mL 5 mL 5 uL8260DIC 280-671165/13 5 mL 5 mL 10 uL8260DIC 280-671165/40 5 mL 5 mL 20 uL8260DIC 280-671165/41 5 mL 5 mL 1 uL8260DIC 280-671165/42 5 mL 5 mL 2 uL8260DIC 280-671165/43 5 mL 5 mL 10 uL8260DICIS 280-671165/44 5 mL 5 mL 15 uL8260DIC 280-671165/45 5 mL 5 mL 20 uL8260DIC 280-671165/46 5 mL 5 mL 40 uL8260DIC 280-671165/47 5 mL 5 mL8260DICV 280-671165/48 5 mL 5 mL 5 uL8260DIC 280-671165/49 5 mL 5 mL 5 uL8260DIC 280-671165/50 5 mL 5 mL 5 uL8260DIC 280-671165/51 5 mL 5 mL 5 uL8260DIC 280-671165/52 5 mL 5 mL 5 uL8260DIC 280-671165/53 5 mL 5 mL 5 uL8260DIC 280-671165/54 5 mL 5 mL 5 uL8260DIC 280-671165/55 5 mL 5 mL 5 uL8260DIC 280-671165/56 5 mL 5 mL 5 uL8260DICV 280-671165/57 The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent. Page 1 of 38260D Page 419 of 426 Lab Name:Job No.: SDG No.: GC/MS VOA BATCH WORKSHEET 280-197896-1 Batch Number:Batch Analyst:Batch Start Date: Batch End Date: Jones, Branden M10/15/24 22:07671165 Batch Method: Eurofins Denver 8260D Lab Sample ID Client Sample ID Method Chain Basis MV-Gas B 00173 mv-IS_SS 00086 MV-MegaMain B 00110 MV-MegaMainA 00115 MV-Supp A 00097 MV-Supp B 00075 Matrix 8260DBFB 280-671165/1 5 uL8260DIC 280-671165/13 5 uL8260DIC 280-671165/40 5 uL8260DIC 280-671165/41 5 uL 2.5 uL8260DIC 280-671165/42 5 uL 5 uL8260DIC 280-671165/43 5 uL 25 uL8260DICIS 280-671165/44 5 uL 37.5 uL8260DIC 280-671165/45 5 uL 50 uL8260DIC 280-671165/46 5 uL 100 uL8260DIC 280-671165/47 10 uL 5 uL 25 uL8260DICV 280-671165/48 1 uL8260DIC 280-671165/49 2 uL8260DIC 280-671165/50 5 uL8260DIC 280-671165/51 10 uL8260DIC 280-671165/52 50 uL8260DIC 280-671165/53 75 uL8260DIC 280-671165/54 100 uL8260DIC 280-671165/55 200 uL8260DIC 280-671165/56 50 uL8260DICV 280-671165/57 The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent. Page 2 of 38260D Page 420 of 426 Lab Name:Job No.: SDG No.: GC/MS VOA BATCH WORKSHEET 280-197896-1 Batch Number:Batch Analyst:Batch Start Date: Batch End Date: Jones, Branden M10/15/24 22:07671165 Batch Method: Eurofins Denver 8260D Batch Notes Basis Basis Description The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent. Page 3 of 38260D Page 421 of 426 Lab Name:Job No.: SDG No.: GC/MS VOA BATCH WORKSHEET 280-197896-1 Batch Number:Batch Analyst:Batch Start Date: Batch End Date: Dobransky, Michael E10/20/24 21:17671719 Batch Method: Eurofins Denver 8260D Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount Initial pH Headspace mv-Cent BFB 00007 MV-Gas A 00200Matrix 2 uL 2 uL 5 uL8260DBFB 280-671719/1 5 mL 5 mL 10 uL8260DCCV 280-671719/2 5 mL 5 mL 10 uL8260DLCS 280-671719/4 5 mL 5 mL 10 uL8260DLCSD 280-671719/6 5 mL 5 mL8260DMB 280-671719/9 TB-100924 5 mL 5 mL <2 SU n8260DT280-197896-B-1 Water FB-100924 5 mL 5 mL <2 SU n8260DT280-197896-B-2 Water MW-03 5 mL 5 mL <2 SU n8260DT280-197896-A-5 Water MW-05 5 mL 5 mL <2 SU n8260DT280-197896-A-3 Water MW-905 5 mL 5 mL <2 SU n8260DT280-197896-A-4 Water MW-16 5 mL 5 mL <2 SU n8260DT280-197896-A-6 Water MW-03 5 mL 5 mL <2 SU n 5 uL8260DT280-197896-A-5 MS Water MW-03 5 mL 5 mL <2 SU n 5 uL8260DT280-197896-A-5 MSD Water Lab Sample ID Client Sample ID Method Chain Basis mv-IS_SS 00086 MV-MegaMainA 00115 Matrix 8260DBFB 280-671719/1 5 uL 25 uL8260DCCV 280-671719/2 5 uL 25 uL8260DLCS 280-671719/4 5 uL 25 uL8260DLCSD 280-671719/6 5 uL8260DMB 280-671719/9 TB-100924 5 uL8260DT280-197896-B-1 Water FB-100924 5 uL8260DT280-197896-B-2 Water MW-03 5 uL8260DT280-197896-A-5 Water MW-05 5 uL8260DT280-197896-A-3 Water MW-905 5 uL8260DT280-197896-A-4 Water The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent. Page 1 of 28260D Page 422 of 426 Lab Name:Job No.: SDG No.: GC/MS VOA BATCH WORKSHEET 280-197896-1 Batch Number:Batch Analyst:Batch Start Date: Batch End Date: Dobransky, Michael E10/20/24 21:17671719 Batch Method: Eurofins Denver 8260D Lab Sample ID Client Sample ID Method Chain Basis mv-IS_SS 00086 MV-MegaMainA 00115 Matrix MW-16 5 uL8260DT280-197896-A-6 Water MW-03 5 uL 12.5 uL8260DT280-197896-A-5 MS Water MW-03 5 uL 12.5 uL8260DT280-197896-A-5 MSD Water Batch Notes Basis Basis Description T Total/NA The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent. Page 2 of 28260D Page 423 of 426 Shipping and Receiving Documents Page 424 of 426 Page 425 of 426 Login Sample Receipt Checklist Client: AECOM Job Number: 280-197896-1 Login Number: 197896 Question Answer Comment Creator: Roehsner, Karen P List Source: Eurofins Denver List Number: 1 TrueRadioactivity wasn't checked or is </= background as measured by a survey meter. TrueThe cooler's custody seal, if present, is intact. TrueSample custody seals, if present, are intact. TrueThe cooler or samples do not appear to have been compromised or tampered with. TrueSamples were received on ice. TrueCooler Temperature is acceptable. TrueCooler Temperature is recorded. TrueCOC is present. TrueCOC is filled out in ink and legible. TrueCOC is filled out with all pertinent information. TrueIs the Field Sampler's name present on COC? TrueThere are no discrepancies between the containers received and the COC. TrueSamples are received within Holding Time (excluding tests with immediate HTs) TrueSample containers have legible labels. TrueContainers are not broken or leaking. TrueSample collection date/times are provided. TrueAppropriate sample containers are used. TrueSample bottles are completely filled. N/ASample Preservation Verified. TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4"). TrueMultiphasic samples are not present. TrueSamples do not require splitting or compositing. N/AResidual Chlorine Checked. Eurofins Denver Page 426 of 426