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HomeMy WebLinkAboutDAQ-2025-0026321 DAQC-520-25 Site ID 10123 (B5) MEMORANDUM TO: CEM FILE – HF SINCLAIR WOODS CROSS REFINING LLC THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: May 28, 2025 SUBJECT: Source: Crude Unit Process Heater 8H2 Contact: Matt Howes – 801-397-7412 Location: HF Sinclair Woods Cross Refinery, Davis County, UT Test Contractor: Alliance Technical Group FRS ID#: UT0000004901100013 Permit/AO#: AO DAQE-AN101230057-23 dated November 15, 2023 Subject: Review of RA/PST Protocol dated May 6, 2025 On May 15, 2025, Utah Division of Air Quality (DAQ) received a protocol for a RA/PST (relative accuracy/performance specification test) of the HF Sinclair Woods Cross Refinery Crude Unit Process Heater 8H2 in Woods Cross, Utah. Testing will be performed on July 2, 2025, to determine the relative accuracy of the O2 monitoring systems. PROTOCOL CONDITIONS: 1. RM 3A used to determine dry molecular weight of the gas stream: OK 2. RM 4 used to determine moisture content: OK 3. RM 205 used to validate gas dilution systems for field instrument calibration: OK DEVIATIONS: No deviations were noted. CONCLUSION: The protocol appears to be acceptable. RECOMMENDATION: Send attached protocol review and test date confirmation notice. 1 8 2 I RE:Relative Accuracy Test Audit (RATA) - Crude Unit Process Heater 8H2 HF Sinclair Woods Cross Refining LLC - Woods Cross, Davis County Director Bird: ln accordance with Section R307-165-3, and Condition ll.B.1.a of Approval Order AN101230053-22, HF Sinclair Woods Cross Refining LLC is providing notification of source testing planned to be conducted at the Woods Cross Refinery. Alliance Source Testing of Salt Lake City, UT. has been contracted to conduct: Relative Accuracy Test Audit (RATA) of the Crude Unit Process Heater 8H2 (Unit 8) Continuous Emission Monitoring System (CEMS). ThistestingprogramisplannedforJuly2nd,2O2S. Acopyofthetestprotocolisenclosed. lfyouhave any questions or need additional information, please contact me at (801) 397-7472. May 6th, 2025 Director Division of Air Quality Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, Utah 84116 Matt Howes Environmenta I Engineering Specialist Enclosure E. Benson (r) File 2.4.L.4.2.1 D. Simmonds Certified Mail: 9589 0710 5270 2858 5275 72 DEPARTMENT OF ENVIRONMENIA OUAI'TY MAY I 5 Zl?s Drvtstor.t oF AtR qnuw ,.tttF$nctor HF Sinclair Woods Cross Refining LLC 1070 W. 500 S, West Bountiful, UT 84087 801-299-6600 | HFSinclair.com FlareAI TECHNICAL GBOU Site Specific Test Plan HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountiful, UT 84087 Source to be Tested: Heater 8H2 Proposed Test Date: July 2,2025 Proj ect No. AST- 2025 -2 l2l -002 Prepared By Alliance Technical Group, L 3683 W 2270 S, Suite West Valley City, UT UTAH DEPARTMENT OF ENVTRONMENTAL OUALITY lilAY 1 5 2n25 I DIVISION OF AIR OUALITY I T AI ii'Site Specific Test Plan Test Program Summary t Requlatorv Information Permit No. Regulatory Citation Source Information DAQE-AN l0 t230055-23 40 CFR 60, Appendix B, Performance Specification 3t t I Source Name Process Heater 8H2 Contact Information Target Parameter Oz I T I I T I I t I I Test Location HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountitul, UT 84087 Eric Benson eric.benson@HF Sinclair.com (801) 2e9-6623 Matthew Howes matthew.howes@HFS inclair.com (80t\ 397-7412 Test Company Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Project Manager Charles Horton charles.horton@all iancetg.com (3s2) 464-0372 Field Team Leader Ryan Lyons ryan. lyons@stacktest. com (708) 2 l 4-4850 (subject to change) QA/QC Manager Kathleen Shonk katie.shonk@al I iancetg. com (8t2) 4s2-478s Test PlanlReport Coordinator Delaine Spangler delaine.spangler@stacktest. com AST-2025-2t21-002 HF Sinclair - West Bountiful, UT I I I I I t AI Site Specific Test Plan Table ofContents TABLE OF CONTENTS l.l Process/Control System Descriptions.. ................ l-l 2.0 Summary of Test Program ............2-l 2.2 Process/Control System Parameters to be Monitored and Recorded ................. ...................2-l 3.1 U.S. EPA Reference Test Method 3.{ - Oxygen. ......................3-l 3.2 U.S. EPA Reference Test Method 4 - Moisture Content......... .......................3-1 3.3 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification. .......................3-1 3.4 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3A................. .......3-2 LIST OF TABLES Table 2- l: Program Outline and Tentative Test Schedule ......................2-l lEerla ir .'. I I t t I I I t t I T t t AST-2025-212t-002 HF Sinclair - West Bountifirl. UT Page ii I I I T t t I I put6rpe Tf CIlNICAL GNOI,t F) Site Specific Test Plan Intoduction 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by HF Sinclair Woods Cross Refining, LLC (HF Sinclair) to conduct compliance testing at the West Bountiful, Utah facility. Portions of the facility are subject to provisions of 40 CFR 60, Appendix B, PS 3 and the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN101230055-23. Testing will include conducting a relative accuracy test audit (RATA) to determine the relative accuracy (RA) as outlined in Table l-l below. Table l-l: Test Matrix This site-specific test plan (SSTP) has been prepared to address the notification and testing requirements of the UDAQ permit. 1.1 Process/ControlSystemDescriptions The 8H2 process heater is fired with refinery gas and is rated at 99 MMBtu/trr. Refinery personnel will access and report refinery CEMS results on the day of the RATA. 1.2 CEMS Descriptions Pollutant Oz(wet) Ametek Thermox WDG-IV 10208656 High 1.3 Project Team Personnel planned to be involved in this project are identified in the following table. Table l-2: Project Team Parameter: Make: Model: Serial No.: Span: t t t I I I I I I I I HF Sinclair Personnel Eric Benson Matthew Howes Regulatory Agency UDAQ Alliance Personnel Ryan Lyons other field personnel assigned at time oftesting event AST-2025-2 I 2 l -002 HF Sinclair- West Bountifirl, UT Page l-l t t I I I T t I I I t t I I t I I I pjlt6 :; t'I' Site Specrfic Test Plan Introduction 1.4 Safety Requirements Testing personnel will undergo site-specific safety training for all applicable areas upon arrival at the site. Alliance personnel will have current OSHA or MSHA safety training and be equipped with hard hats, safety glasses with side shields, steel-toed safety shoes, hearing protection, fire resistant clothing, and fall protection (including shock corded lanyards and futl-body harnesses). Alliance personnel will conduct themselves in a manner consistent with Client and Alliance's safety policies. A Job Safety Analysis (JSA) will be completed daily by the Alliance Field Team Leader. I AST-2025-2I2l-002 HF Sinclair - West Bountiful. UT Page l-2 I I t T t I . Testing will be performed to demonstrate compliance with the UDAQ permit and 40 CFR 60, Appendix B, t l:'or,""s testing will be conducted on the GEMS serving Heater 8H2. o PS testing will be conducted at greater than 50% of the maximum normal [oad.I ' ::::,::T.l;l'"x:iTiil#il:;:J,:::;'JiTffi:::.'+;'ilfiJ l'l':,1#ilH:l;'Lt ff; I 2.2 ;::"::r:- ;'",,.,.., to be Monitored and Recorded Plant personnel will collect operational and parametric data at least once every l5 minutes during the testing. The I fotlowing list identifies the measurements, observations and records that will be collected during the testingI program: I o GEMS Data o Operating Load I 23 Proposed Test ScheduleI Table2-l presentsanoutlineandtentativeschedulefortheemissionstestingprogram. I Table 2-l: Program Outline and Tentative Test Schedule Tcsting Locetion Peremcter US EPA Mcthod No ofRuns Run Duretlon Est Onsite Time DAY l-luly2,2025 Heater 8H2 BWS 4 3-4 60 min l0 hr o:3A 9-12 2l min 2.4 Emission Limits Emission limits for each pollutant are below. Table 2-2: Emission Limits 1r-Alianoe Sire Spec(ic Test Plan SummaryofTest Programs 2.0 Summary of Test Program To satisfy the requirements of the UDAQ permit, the facility will conduct a performance test program to determine the compliance status of Heater 8H2. 2.1 General Description All testing will be performed in accordance with specifications stipulated in U.S. EPA Reference Test Methods 3A and 4. Table 2-l presents an outline and tentative schedule for the emissions testing program. The following is a summary of the test objectives. I I t I t I Source CEMS Required Relative Accuracv Citation Heater 8H2 O: (o/o vw)<20 % (RM) or r I 7o O: (avg. diff.)60, Appendix B, PS 3 AST-2025-2121-002 HF Sinclair - West Bountrt'ul IJT Page 2- I I I I I t T I I t I AI Site Specrfc Test Plan Sumnary ofTest Programs 2.5 Test Report The final test report must be submitted within 60 days of the completion of the performance test and will include the following information. o Introduction - Brief discussion of project scope of work and activities. c Results and Discussion - A summary of test results and process/control system operational data with comparison to regulatory requirements or vendor guarantees along with a description of process conditions and/or testing deviations that may have affected the testing results. o Methodologt - A description of the sampling and analytical methodologies. o Sample Calculations - Example calculations for each target parameter. o Field Dara - Copies of actual handwritten or electronic field data sheets. o Quality Control Data - Copies of all instrument calibration data and/or calibration gas certificates. o Process Operating/Control System Data - Process operating and control system data (as provided by HF Sinclair) to support the test results. =lalEe I I I I I t I I I AST-2025-2 l2 l -002 lii I I Aliatpe Site Spectfc Test Plan 7'esting lvle thodology I T I I I I t T T I I t T I t t 3.0 Testing Methodology This section provides a description of the sampling and analytical procedures for each test method that will be employed during the test program. All equipment, procedures and quality assurance measures necessary for the completion of the test program meet or exceed the specifications of each relevant test method. The emission testing program will be conducted in accordance with the test methods listed in Table 3-1. Table 3-l: Source Testing Methodology All stack diameters, depths, widths. upstream and downstream disturbance distances and nipple lengths will be measured on site with an EPA Method I verification measurement provided by the Field Team Leader. These measurements will be included in the test report. 3.1 U.S. EPA Reference Test Method 3A - Oxygen The oxygen (O:) testing will be conducted in accordance with U.S. EPA Reference Test Method 3A. Data will be collected online and reported in one-minute av€rages. The sampling system will consist of a stainless steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system will be a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line is used, then a portable non-contact condenser will be placed in the system directly after the probe. Otherwise, a heated Teflon sample line will be used. The quality control measures are described in Section 3.4. The relative accuracy of the O: CEMS will be determined based on procedures found in 40 CFR 60, Appendix B, Performance Specifi cation 3. 3.2 U.S. EPA Reference Test Method 4 - Moisture Content The stack gas moisture content will be determined in accordance with U.S. E,PA Reference Test Method 4. The gas conditioning train will consist of a series of chilled impingers. Prior to testing, each impinger will be filled with a knownquantityofwaterorsilicagel. Eachimpingerwill beanalyzedgravimetricallybeforeandaftereachtestrun on the same analytical balance to determine the amount of moisture condensed. 3.3 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification A calibration gas dilution system field check will be conducted in accordance with U.S. EPA Reference Method 205. An initial three (3) point calibration will be conducted, using individual Protocol I gases, on the analyzer used to complete the dilution system field check. Multiple dilution rates and total gas flow rates will be utilized to force the dilution system to perform fwo dilutions on each mass flow controller. The diluted calibration gases will be sent directly to the analyzer, and the analyzer response will be recorded in an electronic field data sheet. A mid-level supply gas, with a cylinder concentration within l0% of one of the gas divider settings described above, will be introduced directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. The cylinder concentration and the analyzer response must agree within 2%. These steps will be repeated three (3) Pemmetcr U.S. EPA Rcference Test Methods Notos/Remerks Oxygen 3A Instrumental Analysis Moisture Content 4 Gravimetric Analysis Gas Dilution Syslem Certification 20s t AsT-2025-2r2r-002 FIF Sinclarr - West Bountiful. UT Page 3- | I I I t I t T t I I I T I t I I I I Site Specrfic Test Plan Testing Methodology times. The average analyzer response must agree within2oh of the predicted gas concentration. No single injection shall differ more than 2o/o from the average instrument response for that dilution. 3.4 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3A Cylinder calibration gases will meet EPA Protocol I (+l- 2o/r) standards. Copies of all calibration gas certificates will be included in the Quality Assurance/Quality Control Appendix of the report. Low Level gas will be introduced directly to the analyzer. After adjusting the analyzer to the Low Level gas concentration and once the analyzer reading is stable, the analyzer value will be recorded. This process will be repeated for the High Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases will be sequentially introduced directly to the analyzer. The Calibration Error for each gas must be within 2.0 percent of the Calibration Span or 0.5% absolute difference. High or Mid Level gas (whichever is closer to the stack gas concentration) will be introduced at the probe and the time required for the analyzer reading to reach 95 percent or 0.5o/o (whichever was less restrictive) of the gas concentration will be recorded. The analyzer reading will be observed until it reaches a stable value, and this value will be recorded. Next, Low Level gas will be introduced at the probe and the time required for the analyzer reading to decrease to a value within 5.0 percent or 0.5o/o (whichever was less restrictive) will be recorded. If the Low Level gas is zero gas, the acceptable response must be 5.0 percent of the upscale gas concentration or 0.5%o (whichever was less restrictive). The analyzer reading will be observed until it reaches a stable value and this value will be recorded. The measurement system response time and initial system bias will be determined from these data. The System Bias for each gas must be within 5.0 percent of the Calibration Span or 0.5oh absolute difference. High or Mid Level gas (whichever is closer to the stack gas concentration) will be introduced at the probe. After the analyzer response is stable, the value will be recorded. Next, Low Level gas will be introduced at the probe, and the analyzer value will be recorded once it reaches a stable response. The System Bias for each gas must be within 5.0 percent of the Calibration Span or 0.5o/o absolute difference or the data is invalidated and the Calibration Error Test and System Bias must be repeated. The Drift between pre- and post-run System Bias must be within 3 percent of the Calibration Span or 0.5o/o absolute difference or the Calibration Error Test and System Bias must be repeated. To determine the number of sampling points, a gas stratification check will be conducted prior to initiating testing. The pollutant concentrations will be measured at fwelve traverse points (as described in Method I ) or three points (16.7, 50.0 and 83.3 percent of the measurement line). Each traverse point will be sampled for a minimum of twice the system response time. If the pollutant concentration at each traverse point does not differ more than 5o/o or 0.3o/o (whichever is less restrictive) of the average pollutant concentration, then single point sampling will be conducted duringthe test runs. Ifthe pollutant concentration does not meet these specifications but differs less than l0% or 0.5% from the average concentration, then three (3) point sampling will be conducted (stacks less than 7.8 feet in diameter - 16.7,50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, 1.0, and 2.0 meters from the stack wall). If the pollutant concentration differs by more than l0% or 0.5Yo from the average concentration, then sampling will be conducted at a minimum of fwelve ( l2) traverse points. Copies of stratification check data will be included in the Quality Assurance/Quality Control Appendix of the report. I AST-202s-2l2l-002 HF Sinclair - West Bountiful. UT Page 3-2 I I I I I I I I I I I I AI Site Specrfic Test Plan Testing Methodology A Data Acquisition System with battery backup will be used to record the instument response in one (l) minute averages. The data will be continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data will also be saved to the Alliance server. All data will be reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data will be relinquished to the report coordinator and then a final review will be performed by the Project Manager. FIA t I I I I I T AST-2025-2 I2l-002 HF Sinclair - West Bountiful, UT t I I T I t I I t t T I I I I T I I Site Specific Test Plan Qualiry Assurance Program 4.0 Quality Assurance Program Alliance follows the procedures outlined in the Quality Assurance/Quality Control Management Plan to ensure the continuous production of useful and valid data throughout the course of this test program. The QC checks and procedures described in this section represent an integral part of the overall sampling and analytical scheme. Adherence to prescribed procedures is quite often the most applicable QC check. 4.1 Equipment Field test equipment is assigned a unique, permanent identification number. Prior to mobilizing for the test progrnm, equipment is inspected before being packed to detect equipment problems prior to arriving on site. This minimizes lost time on the job site due to equipment failure. Occasional equipment failure in the field is unavoidable despite the most rigorous inspection and maintenance procedures. Therefore, replacements for critical equipment or components are brought to the job site. Equipment returning from the field is inspected before it is returned to storage. During the course of these inspections, items are cleaned, repaired, reconditioned and recalibrated where necessary. Calibrations are conducted in a manner, and at a frequency, which meets or exceeds U.S. EPA specifications. The calibration procedures outlined in the U.S. EPA Methods, and those recommended within the Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III (EPA-600/R-941038c, September 1994) are utilized. When these methods are inapplicable, methods such as those prescribed by the American Society for Testing and Materials (ASTM) or other nationally recognized agency may be used. Data obtained during calibrations is checked for completeness and accuracy. Copies of calibration forms are included in the report. The following sections elaborate on the calibration procedures followed by Alliance for these items of equipment. o Dry Gas Meter and Orifice. A full meter calibration using critical orifices as the calibration standard is conducted at least semi-annually, more frequently if required. The meter calibration procedure determines the meter correction factor (Y) and the meter's orifice pressure differential (AH@). Alliance uses approved Alternative Method 009 as a post-test calibration check to ensure that the correction factor has not changed more than 5%o since the last full meter calibration. This check is performed after each test series. e Pitot Tubes and Manometers. Type-S pitot tubes that meet the geometric criteria required by U.S. EPA Reference Test Method 2 are assigned a coefficient of 0.84 unless a specific coefficient has been determined from a wind tunnel calibration. If a specific coefficient from a wind tunnel calibration has been obtained that coeflicient will be used in lieu of 0.84. Standard pitot tubes that meet the geometric criteria required by U.S. EPA Reference Test Method 2 are assigned a coefficient of 0.99. Any pitot tubes not meeting the appropriate geometric criteria are discarded and replaced. Manometers are verified to be level and zeroed prior to each test run and do not require further calibration. o Temperature Measuring Devices. All thermocouple sensors mounted in Dry Gas Meter Consoles are calibrated semi-annually with a NlST-traceable thermocouple calibrator (temperature simulator) and verified during field use using a second NlST-traceable meter. NlST-traceable thermocouple calibrators are calibrated annually by an outside laboratory. . Nozzles. Nozzles are measured three (3) times prior to initiating sampling with a caliper. The maximum difference between any two (2) dimensions is 0.004 in. . Diqital Calipers. Calipers are calibrated annually by Alliance by using gage blocks that are calibrated annually by an outside laboratory. t AST-2025-2t21-002 HF Sinclair - West Bountiful, UT Page 4- I t t I T I T T I t t t t I I I T I I Site Specific Test Plan Quality Assurance Program Barometer. The barometric pressure is obtained from a nationally recognized agency or a calibrated barometer. Calibrated barometers are checked prior to each field trip against a mercury barometer. The barometer is acceptable if the values agree within i 2 percent absolute. Barometers not meeting this requirement are adjusted or taken out ofservice. Balances and Weishts. Balances are calibrated annually by an outside laboratory. A functional check is conducted on the balance each day it is used in the field using a calibration weight. Weights are re-certified every two (2) years by an outside laboratory or internally. If conducted internally, they are weighed on a NIST traceable balance. If the weight does not meet the expected criteria, they are replaced. Other Equipment. A mass flow controller calibration is conducted on each Environics system annually following the procedures in the Manufacturer's Operation manual. A methane/ethane penetration factor check is conducted on the total hydrocarbon analyzers equipped with non-methane cutters every six (6) months following the procedures in 40 CFR 60, Subpart JJJJ. Other equipment such as probes, umbilical lines, cold boxes, etc. are routinely maintained and inspected to ensure that they are in good working order. They are repaired or replaced as needed. 4.2 Field Sampling Field sampling will be done in accordance with the Standard Operating Procedures (SOP) for the applicable test method(s). General QC measures for the test program include: o Cleaned glassware and sample train components will be sealed until assembly. o Sample trains will be leak checked before and after each test run. . Appropriate probe, filter and impinger temperatures will be maintained. o The sampling port will be sealed to prevent air from leaking from the port. . Dry gas meter, AP, AH, temperature and pump vacuum data will be recorded during each sample point. o An isokinetic sampling rate of 90-l l0% will be maintained, as applicable. r All raw data will be maintained in organized manner. . All raw data will be reviewed on a daily basis for completeness and acceptability. I AST-202s-2l2l-002 HF Sinclair - West Bountiful, UT Page 4-2