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HomeMy WebLinkAboutDAQ-2024-007218,dttF$nctorr July 3,2023 Mr. Bryce Bird, Director Division of Air Quality Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, Utah 84Lt6 lnlnl : sr:!'i,:. i:'ii,il.'l"lT. c:fl Ehrvii{C.jr3ljr. ii }L\i. fi i J j ;.lTf illt lf 't-, l! _-J Hand Delivered *qn a Drvt$tcN be{i outd CF ir1m CI{-,AL''!Y RE: Relative Accuracy Test Audit (RATA)- Fuel Gas H2S Continuous Emission Monitor HF Sinclair Woods Cross Refining LLC - Woods Cross, Davis County Director: Enclosed please find the Relative Accuracy Test Audit Report for the continuous emission monitors on our refinery Fuel Gas system. The test was conducted on May 5rt, 2023. The relative accuracy was calculated tobe 0.73%o for the HzS monitor. The Refinery Manager (the position that most closely corresponds to Plant Manager) is Jeff Danielson. All other data required by R307-170-7(5) is found in the report or this cover letter. The following apply to this report:l. Testing was conducted while the point source was operating at the rate and/or conditions specified in the applicable approval order, operating permit, or federal regulation2. During testing, the point source combusted fuels, used raw materials, and maintained process conditions representative of normal operations, and operated under such other relevant conditions specified by the Director. I certify under penalties of law that, based upon reasonable inquiry of personnel involved the statements and information contained in this report are truthful and accurate, and are a complete record of all monitoring related testing events that occurred during the enclosed test audit. lf you have any questions or need additional information, please call Matt Howes at (801) 397-7412. Sincerely, Jeff Danielson Refinery Manager Enclosure HF Sinclair Woods Cross Refining LLC 1070 W. 500 S, West Bountiful, UT 84087 801 -299-6600 | HFSinclair.com File 2.4.L.2.2.7 REVIEWEDInitials: RL Date: 4/5/2024Status: Received. GC MethodNo DAQ Review. RA Calcs OK.File ID#: 10123-B5 {-"-' .' ' il-Aliare RATA Report HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountiful, UT 84087 Source Tested: Fuel Gas Test Date: May 5,2023 Proj ect No. AST-2023 -l 661 -002 T,riri;.lON OrO * *d Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 put6rpe TECHNICAL GROUP Source Tcst Rqort Test Prosram Summary Resulatorr Information Permit No. Regulatory Citations Source Information DAQE-ANI0t23004t-13 40 CFR 60, Appendix B, Performance Specification 7 and Subpart Ja Source Name Fuel Gas Contact Information Target Parameter HzS Test Location HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountiful, UT 84087 Eric Benson eric.benson@hfsinclair.com (801)29e-6623 Matthew Howes matthew.howes@hfsinclair.com (801) 3e7-7412 Tesl Company Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Project Manager Charles Horton charles.horton@alliancetg.com (3s2) 663-7s68 Field Team Leader Rob Burton robert.burton@all iancetg.com (224\ 358-soss QA/QC Manager Kathleen Shonk katie.shonk@alliancetg.com (812\ 4s2478s Report Coordinator Sarah Perry sarah.perry@alliancetg.com AST-2023- r 55 I -002 2 of 5l Page it{F Sinclair- West Bountiful, UT Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-fiee and legible. Onsite testing was conducted in accordance with approved intemal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative ofAlliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (pdf) and contains pages as identified in the bottom footer of this document. t! / ,'/ .i'it/'J ," -/n,n/-612812023 Charles Horton, QSTI Alliance Technical Group, LLC l#,L, Date AST-2023-1661-002 3 of 5l Page iiHF Sinclair- West Bountiful, UT purErlpe TECI]NICAI. GRO[JF)Source Test Reporl Table o{Contents TABLE OF CONTENTS l.l Process/Control System Descriptions .............. l-l 1.4 Site-Specific Test Plan & Notification................... ................ l-l 3.1 U.S. EPA Reference Test Method 15 - Hydrogen Sulfide .......................... 3-l 3.2 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification.. ...................3-l LIST OF TABLES Table 2-l: Summary of Performance Specification Test Results ................... ..............2-l APPENDICES Appendix A Example Calculations Appendix B RATA Calculations and GC Data Appendix C Quality Assurance/Quality Control Data Appendix D CEMS Data AST-2023-1661-002 4 of 5l HF Sinclair- West Bountiful, UT 5 of5l AI Parameter: Make: Model: Serial No.: Span: lf lIl Son'ce Test Reporl Introduction 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by LIF Sinclair Woods Cross Refining,LLC (HF Sinclair) to conduct performance specification (PS) testing at the Woods Cross refinery in West Bountiful, Utah. Portions of the facility are subject to provisions of the 40 CFR 60, Appendix B, PS 7 and Subpart Ja and the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-ANl0123004l-13. PS testing included conducting a relative accuracy test audit (RATA) to determine the relative accuracy (RA) of the hydrogen sulfide (HzS) gas chromatography (GC) continuous emissions monitoring systems (CEMS) serving the Fuel Gas. l.l Process/ControlSystemDescriptions Refinery fuel gas is a byproduct generated by the crude oil refining process. Fuel gas is then combusted in refinery heaters and boilers as part of the crude refining process. The HzS content of fuel gas combusted in any fuel gas combustion device is limited by 40 CFR 60.104(a). The concentration of tIzS will be measured by a process gas chromatograph which was installed to comply with NSPS Subpart Ja requirements. Refinery personnel will access and report refinery CEMS results on the day of the RATA. 1.2 CEMS Descriptions Pollutant HzS Siemens Maxum II 300494567000010 0-300 ppm 1.3 Project Team Personnel involved in this project are identified in the following table. Table 1-l: Project Team 1.4 Site.Specific Test Plan & Notification Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to I-IDAQ by HF Sinclair. 1.5 Test Program Notes The post test drift exceeded 5%. Verified that test run data would result in lower values when using the post test calibration data. Therefore, the initial calibration (the data set that results in the higher concentration test run data) were used, per Section 8.3.2 of EPA Method 15. HF Sinclair - West Bountiful, I I"T HF Sinclair Personnel Matthew Howes Alliance Personnel Rob Burton Alan Jensen Alex Lawrence Dillon Brown AST-2023- l 66 l -002 6 of 5l Page l-l 7 of51 pdltfu TECHNICAL GROUP Sowce Tesl Report Summov of Results 2.0 Summary of Results Alliance conducted PS testing at the IIF Sinclair Woods Cross refinery in West Bountiful, Utah on May 5,2023. Testing included conducting a RATA to determine the RA of the HzS GC CEMS serving the Fuel Gas. Table 2-l provides a summary of the RA results in comparison to the applicable RA requirements. Any difference between the summary results listed in the following table and the detailed results contained in appendices is due to rounding for presentation. Teble 2-l: Summary of Performence Specificetion Test Results I Calculated using the applicable source standard for the pollutant. See Appendix B for the applicable standard used. AST-2023-1661-002 8 of5l Page2-lHF Sinclair-West Bountifirl, UT 9 of 5l pi/a6rpe It(;ilNlcAt ()R()tJP Sowce Test Reporl Testing Methodologt 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix C. Table 3-l: Source Testing Methodology 3.1 U.S. EPA Reference Test Method 15 - Hydrogen Sulfide The hydrogen sulfide testing was conducted in accordance with U.S. EPA Reference Test Method 15. The sampling system consisted of a heated Teflon probe, heated Teflon sample line, gas conditioning system, leak-free pump, unheated Teflon sample line, and a gas chromatograph (GC) equipped with a flame photometric detector (FPD). The gas conditioning system consisted of three (3) Teflon impingers. The frst two (2) impingers contained 100 mL of citrate buffer (for SO2 removal) and the last was empty. Each test run consisted of 3 injections performed over a period of at least 60 minutes. The GC/FPD was calibrated for HzS with a certified calibration gas diluted with a dilution system validated in accordance with EPA Method 205 to produce three (3) or more concentration levels spanning the linear range of the FPD. Calibration precision, sample line loss, and calibration drift test values were maintained in accordance with EPA Method 15 requirements. The relative accuracy of the HzS CEMS was determined based on procedures found in 40 CFR 60, performance Specification 7. 3.2 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification A calibration gas dilution system field check was conducted in accordance with U.S. EPA Reference Method 205. Multiple dilution rates and total gas flow rates were utilized to force the dilution system to perform two dilutions on each mass flow controller. The diluted calibration gases were sent directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. The analyzer response agreed within 2o/o of the actual diluted gas concentration. A second Protocol I calibration gas, with a cylinder concentration within l0% of one of the gas divider settings described above, was introduced directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. The cylinder concentration and the analyzer respons€ agreed within 2%o. These steps were repeated three (3) times. Copies of the Method 205 data can be found in the Quality Assurance/Quality Control Appendix. AST-2023- I 66 l -002 l0 of 5l I I ofSl Al6me Appendix A Example Calculntions Corrected Concentration, ppmvd Cnzs : CorrxRF where, CoBs 18.94 : average H2S concentration observed during test, ppmvd RF l.l0 _= system recovery correction factor, unitless Cr"r -t65--: average II2S concentration during test, ppmvd l2 of5l l3 of51 N,AlEe SoURCE TESTING H2SRATA Location: HF Sinclair Woods Cross Refinine, LLC - West Bountiful, UT Source: Fuel Gas Project No.: 2023-1661 Run No.Date Time Reference Method H2S ppmvd CEMS H2S ppmvd Average Difference ppmvdStartEnd I 2 J 4 5 6 7 8 9 t0 ll l2 5/5123 5/5123 5/5123 5/5123 s/st23 5/5123 5/s123 515123 515123 5/5123 515t23 5/5123 l4:35 l5:21 l6:07 t6:53 17:39 t8:25 t9:l I 19:57 l0:43 ,-1:29 t-2:15 13:01 l5:20 t6:06 l6:52 l7:38 l8.24 t9:10 t9:56 l0:42 !l:28 l2:14 !3:00 t3:46 * * 20.9 2t.2 20.1 19.5 20.4 20.1 19.7 t9.9 19.7 19.7 20.9 21.2 19.6 22.4 23.2 22.7 20.2 20.2 20.1 18.6 19.5 18.4 18. r 18.8 1.30 -1.20 -3.20 0.20 -0.10 -0.40 1.30 0.20 1.30 Average 20.1 20.2 -0.07 Standard Deviation (Sd t.46 Applicable Source Standard (AS 162 Confi dence Coeffi cient (CC l.l t9 Relative Accuracy (RA 0.73Y" Acceptability Criteria - Applicable Source Standard Sl0"/" Performance Specifi cation Method PS 7 (RM ls) * Delimiter for runs not used in RA calculations Confidence Coeflicient, CC CC: where, logts $"sa!tl 2.306 = degrees offreedom n 9 : number of runs selected for calculating the RA Sd L46 : standard deviation of difference CC tJ t9 : confidence coefficient Relative Accuracy, RA rt,t - | * " ", ar*, ",, "l rl?;, < sa ll .15 ot Rll where, mean differen..A: average difference of Reference Method and CEMS toj,s 2.306 : degrees of freedom n 9 : number of runs selected for calculating the RA Sd L46 = standard deviation of difference AS 162 = applicable standard RA AT : relative accuracy 14 of51 ;dN R.P {ft: tf9N5o- sit;:x {;E ; = ::,i {sF (ax a: y'r i:t!er aen!€€ {il8!?he {nF l5 of5l II N N z .F e. O o q CE CBn u) o th(r) frl fli-.\\i0: e; all6rce so(rP.rF I r s. 1,,!{i Run I Data Location: tIF Sinclair Woods Cross Refining,LLC - West Bountiful, UT Source: Project Xo.: Datez 5/512023 Injection Start Time HzS l4:35 l4:57 l5: l8 18.76 18.93 19.13 Parameter H,S Uncorrected Run Average (Co6")18.94 Corrected Run Averase (Corr)20.91 l6 of 5l AI6rce S()\rflr:F 1[ li]lr!(i Location: tIF Sinclair Woods C.o.r R"@Sor.""tffi Project Xo.t Datez 515/2023 Injection Start Time HzS Run 2 Data l5:40 l6:01 19.20 19. l3 Parameter H,S Uncorrected Run Average (Co6.)19.17 Corrected Run Averase (Corr)21.16 l7 of 51 AI6rces,)\rtr(:r r t: Trr!,, RUn 3 Data Location: FIF Sinclair Woods Cross Refining,LLC - West Bountiful, Ul Source: Project No.: Datez 51512023 Injection Start Time HzS l6:23 l6:44 18.71 17.74 Parameter H,S Uncorrected Run Average (Co6)18.23 Corrected Run Averase (Corr)20.12 l8 of 5l 9='Alhrrce s,r {rr1 r.F 1 f s 1 rN (. Run 4 Data Location: IIF Sinclair Woods Cross Refining, LLC - West Bountiful, U' Source: Project No.: Date: 51512023 Injection Start Time HzS t7;06 17:21 17.52 17.73 Parameter HzS Uncorrected Run Average (Co6)17.63 orrected Run Average (Corr)19.46 l9 of 51 AI6rrce Location: FIF Sin.luisor.""tEiGi Project Xo., Datez 51512023 Injection Start Time HzS Run 5 Data 17:49 l8: l0 18.46 18.58 Parameter HzS Uncorrected Run Average (C"6*)t8.52 Corrected Run Averase (Corr)20.45 20 of5l AI6rce:r|rl1 !:E rf sr r!,, Run6Data Location: tIF Sinclair Woods C.o.* @Source:ffi Project No.: 2023-1661 D^te: Injection Start Time HzS l8:32 l8:53 18.43 17.98 Parameter HzS Uncorrected Run Average (Co6.)18.21 Corrected Run Average (Corr)20.10 2l of 5l AI6rrces()rrri()€ r.sriN' RunTData Location: FIF Sinclair Woods Cross Refining, LLC - West Bountiful, UTSou.ce:ffi Project No.: 2023-1661 Date: Injection Start Time HzS l9: l5 l9:36 17.70 17.95 Parameter H,S Uncorrected Run Average (Cos)17.82 Corrected Run Average (Corr)19.68 22 of 51 AI6rrce SOLIIi(:f. IFSIIN'i Location: HF Sinclair Woods C.o.r R44!4grLLC - W"rt Bourtiful, UT Sou""ut Project No.: 2023-1661 Dat", Injection Start Time HzS Run 8 Data l9:58 20 19 20:41 18.25 18.16 17.70 Parameter HzS Uncorrected Run Average (C"6")18.04 Corrected Run Averase (Corr)19.91 23 of 5l Al6rrce srJLltlCF ltS.TrN(i Location: IIF Sinclair Woods C.or. R@Source:ffi Project Xo.t Date; 51512023 Injection Start Time HzS Run 9 Data 2l:02 2l:24 17.79 17.87 Parameter HzS Uncorrected Run Average (C,5)17.83 Corrected Run Averase (Corr)19.69 24 of 5l Al6rceso\rri(:E rrslrN.i Run 10 Data Location: FIF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Project Xo.t Datez 51512023 Injection Start Time HrS 2l:45 22:07 17.82 17.94 Parameter HzS Uncorrected Run Average (C"5")17.88 Corrected Run Averase (Corr)19.74 25 of5l Al6rce SDLIFiL:F IIST]IiG Location: tIF Sinclair Woods Crorr R"@ Source:ffi Project No.: Datez 51512023 Injection Start Time HzS Run 11 Data 22:28 22:50 18.86 18.93 Parameter HzS Uncorrected Run Average (Co6")18.90 orrected Run Average (Corr)20.86 26 of 5l Run 12 Data Locetion: IIF Sinclair Woods Cross Refining, T.I.C - West Bountiful, UT Source: Fuel Gas Project Xo.: D*ez 51512023 Injection Start Time II2S 23:ll 23:33 t9.22 19.17 Parameter HrS Uncorrected Run Average (Co5)19.20 Corrected Run Averege (Corr)21.t9 27 of 51 28 of5l Al6rce SOURCE TESTING L@tion: HF Sinclair Woods Cross Refinim. LLC - Wesl Bomdfril. UT QA/QC Soure: Fuel Gas Projet No.: Dwice GC-TPD l{rke sRt l{odel 86r0c t/t{N3202 ConD Boflle ID C orcentration ExDimlion Date Mol./fu(. H2S DT0A2rc7t 298 411912025 34 08 29 of5l Al6rce.:r_)trrlr;F IIsrrN{l Location FIF Sinclair Woods Cross Refining,LLC - West Bountiful, UT Source Fuel Gas Project No. 2023-1661 Date: 51512023 Time: 9:55 *""Calibration injections are reanallzed using the calibration curve ""*No injeciton can vary from the mean of all 3 injections by >5% ***Chromatograms from calilbration injections are contained in the appendix Cal QA H2S High Level calibration Standard conc' (ppm) 100.00 Calibration Standard Inieclion RT ppm % Variation RT ppm I .046 100.3 0.3o/o .046 49.6 2 .043 101.7 7.7o/o 046 49.6 J 046 98.0 2.0o/o .046 51.9 Mean .045 100.000 .046 50.34 30 of5l Alhlrces.llricF'!:si rn. Recovery-DriftQA Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Fuel Gas Project No.: 2023-1661 GC Drift (Using H2S Gas) Pre-Test Post-Test Date 5t5t2023 Datr 516/2023 Time I l:52 AM Timr I0:00 AM Iniection #Measured Concentration (ppm)% Variation Measured Concentration (ppm o% Variation o/oDrift I 25.0 0.4,22.58 0-3o/"l0.5Yo ,25.0 0.00/o 22.64 0.|Yo 10.60/o 3 25.1 0.3%22.71 0.3%l0.7Yo Mean 25.04 22.64 t0.6,/, Pre Test System Recovery (Using HzS Gas) Date 5t5t2023 Time I l:52 AM Iniection #Measured Concentration (ppm)oZ Variation Gas Concentration 7o Recovery I 25.0 0.40h 25.00 99.8% 2 25.0 0.Oo/"l0O.2o/o 3 25.1 0.3"4 100.5o/o Mean 25.04 l00.zYr Post Test System Recovery (Using H2S Gas) Datr 51612023 Timr l0:00 AM Iniection #Measured Concentration (ppm o% Variation Gas Concentration 7o Recoven I 22.58 0.3o/o 25.00 90.3o/o )22.64 0.0010 90.6Y" 3 22.71 O.3o/o 90.8o/o Mean 22.64 90.6'/. Correction Factor I l.tO 31 of 5l AI lr EPA Method 205 Field Calibration of Dilution System Loc.tion, fIF Sin"l"i. woods CrossRefining,Llc.w Sou."ar Unit 4 Proj.cl No,: AST-2023-1661 Dtt.5ll/23 M.lbod Crit.ri.EPA Prramaler 02 Mrk Mod. SA Servomex t440lD 14208-676 250 lvlinder Nrmha D Z.ao Mid NA E80074557 E80074557 lylirder C.nifi.d Vrlu.s hro Mid Hioh 00 l0 20 !nl Rshonr. /./. or nDm) Ztro Mid 00 t00 20.0 }librrlion Grr SC...ion /./. of Sr.n) Mid Hioh 400 t00 l'rlibretion Enor Prrfomrn.. (o/. of SD.D) Ttro Mid 00 0.0 -02 inE#tu t./" of R.no.I ol ilil _ 1uuL / AIR OI-IAI ITY Analyar Make Analyzer Model Analyar SN Envrronrcs ID Componen/Balane Gas Cylinder Gas lD @ilution) Cylinder Gas Concenration (Dilution). % Cylinder Gas ID (Mid-Level) Cylinder Gas Concentration (Mid-Level), 7o: 4 14208-616 T.rg.t M.!r Flow Trrgcl Dilution TrrSGl Flor Rrte T.rget Conc.nlr.lion Aclurl Conccotrelion Itrjcction I ADdyzar Conaanlrrtior hj.ctiotr 2 An.lyr.r Con.cnaration Inicclion 3 ADrbzcr Concautralion Avarrga AndFcr Cotrcatrarrtion DirIcr.o.. Avarag. Enor l0L/5L 800 50 t9n 9S 19.5 195 l9 5 I S3 oo o 10/" I OI /5r 500 50 4 4 2.4 tz4 t2 38 -0 02 -o 10/" 101./)oo 4.0 50 50 50 50 50 5.02 002 o 50/" I 0I-ll I.to 0 4l 2.5 25 25 5 oo 10/" iNorallASTEnvironicstlnitshave2-l0LMassFlowContollers Fortheseunibthego./o@TlpfrandEO%@llpminlectionswillnotb€conducled Avtrrgc Anrbzcr Corccnlralion Inj.ctiotr I Enor ( t 2./.1 Inj.ction 2 f,nor IDi.c,ioD 3 Error rq 5 o N/"-O.lo/o 0.2o/o t2 38 .o 10/"n )./"0.to/o 502 -o 30/6 -o to/"o 1./" -t.to/o 0 50h o 50/" 32 of 51 Mass Flow Controller Calibration Deument lI 620.009 Revisior 22.4 Fffe.live Datr 12/16/22 ltsuinq Department Tech Services Pao(lofl Diluton S)6tem Make: Dilution System Model: Dilution S)6tem S/N: Calib,ration Equiprnent Make: Calibration Equipment Model: Calibration Equiprnent S/N: Flow Cell S/N: Flow Cell S/N: Calibration Gas: Barornetric Pressure, mmHg: Ambient Temperature,'F: Environics 4040 8028 Alicat Scientinc M-lOSLPD/5MM- D/5IV, 197208/197206 197208 191206 Nitrogen 25.13 63.5 t"4-lSLPtV D/stV Mass Flow Controller lD Size, ccm: Make: Model: 5/N: #1 10,000 Environics EFC 202 0455242015 #2 10,000 Environics EFC 202 0455242016 #3 1,000 Environics Etc 202 0455238008 Set Flow True Flow Difbrerre cdmin cdmin Set Flow True Flow Diffurence cdmin cclmin Set Flow True Flow Difference cclmin cdmin 100k 20"/" 30"k 40o/o 50o/o 60"/. 700k 800k 90"/. 1000k 500 502 0.40k 1,000 '1,013 1.30k 2,000 2,039 2.00/o 3,000 3,059 200k 4,000 4,080 2.00,6 5,000 5,100 2.00/o 6,000 6,118 2.00/o 7,000 7,148 2.1% 8,000 8,181 2.3Vo 9,000 9,207 23% 10,000 10,242 24% 500 499 0.2y" 1,000 '1,016 1.60/0 2,000 2,037 1.9% 3,000 3,062 2.1"/" 4,000 4,086 2.2Yo 5,000 5,1u 2170 6,000 6,122 2.0Yo 7,000 1 ,146 2.1Vo 8,000 8,173 2 20/o 9,000 9,199 2 2"A 10,000 10,235 2.40/o 50 484 32% '100 98 5 1.5.,6 200 199.8 0.1Vo 300 300.5 Q.20/o 400 401.4 0 3"/. 500 502.3 0.50/" 600 604.3 0.7o/o 700 706.2 0970 800 809 1 11% 900 9141 160k 1,000 1020.5 21Vo Notel The mass flow controller's calibration values are used by the dilution system's operating softlvare to improve accuracy. These calibrations are not necessarily indicative ofthe systems overall performance. Performance is verified by conductinq a Method 205 prior to each field use. Ca|bratron Performed By TCH Dare 3/27/2023 33 of51 ilrgas m Ai Lhuir6 company Airgas USA, LLC 525 North Industrial laop Road Tooele, UT 84o74 Airgas.com CERTIFICATE OF ANALYSIS Grade of Froduct: EPA Protocol Part Number: E03N152E15A38Q7 Cylinder Number: E80074557Laboratory: 124 - Tooele (SAP)- UT PGVP Number: 872020 Gas Code: CO2,O2,BALN Explratlon Date: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certilication Date: Jun 23.2028 1534018375,4,4-1 163.9 CF 201s PSIG 296 Jun 23,2020 C€nrllcato.r porformed in accodanc. wilh 'EPA fraceatility Prdocol br A6.ay and Cerfification of Gas.ous Crlibr8tion SfDndard3 (Mry 20'12)' doal.nenf EPA 600/R-'121531. ushg Stc assay proccdurcs Isled. Analylical Molhodology dooB nol ,equaro @roclion tor analy{ical interforcncc. ThiE cyindsr has a lotal analflacat unco.tarnty as sleled b€bw wilh a confidonca lavel of 95%. There a,e no 3€nillcanl lrpurilie3 whlch afecl thc uss of lhis c8libfatbn mrxlur". All @ncent albni ars on a Trlad Data Avallable Upon Request mole/mol€ b8sb mla&3 olhcrwisG rEted. Regueeied Concantration AIYALYTICAL RE-SI.'LTS Actual ProtocolConcentraUon Method CARBON DIOXIOE OXYGEN NITROGEN 21.N o/o 21.00 0A Balance G2 G2 24.05 ol" 24.B',t o/. +b 0.5% NIST Traccable +/- 0.306 NIST Traoabb 06,n3t2020 06n3no20 CALIBRATION STANDARDSType Lot lD Cylinder No ConcentraUon 0.5% 0,20/o NTRM NTRM 0601 1 806 r206200E 23,U OA CARBON DIOX IO E/NITROGEN 22.8E3'A OXYGEN/NIIROGEN K012659 cc367433 AIYALYTICAL EQUIPMENT Analytlcal Principle Hodba VIA-510 SV4MEUTJ CO2 Horiba MPA-510 W503MM58 02 Jun 1 1, 2020 Jun 16.2020 34 of51 Page I of 153-'101837544-l Red Ball Technical Gas Servace 555 Gralg Kennedy Way Shreveport LA 7tt07 800€5r€150 PGVP vendor lD # G{2021 EPA PROTOCOL GAS GERTIFICATE OF ANALYSIS qdind€r Number: Produst lD Number: Cylinder Pressure: coA# Customer PO. NO.: Customer: ]c519879 t2s77'l t900 PstG lcs1 9879.2021 0624-0 Certification h: Expiradon D&i MFG Facility: Lot Number: Tracking Number: Previous Cerdfi cation Dates: )7t08D021 )7t06,na2e -shFmr,l-l-A )c519879.20210624 t03894559 AnaMical Chemist Assay Laboratory: Red Ball TGS V6ion 02J. Revised on 201&0917 This calibration standerd per the May 2012 EPA Traceability Protocol. lTlis iS tO cenify th€ gases relerenced hrvc bacn calibraGd/tect d, and vetified to meet the defined spacifications. This catibration/Est wai performecl using Gase3 or Scales that are traceable through National lnstifute of Standards and Technotogy (NtsT) to tne tntemationat system of uniB (sl). The basis of compliance stated is a comparison of ule measurement ;;rameters to the specfied or required calibration/testing process. The expanded uncertainties use a @verage taaoi of f=Z to approximate the gic/o @nfidence level of the measurement unless olherwise noted' This calibration certificate '--'appfies onty to'the item descfibed and shell not b€ reprduced other than in full, Wthout witten approval Fom Red Ball ::Lft;;'ilir".. ft *t inliloeo, the uncerbinty of c€librations are available upon request and were taken into account when determining Pass orfail. Concentration UncerEinty Analyticat PrlnclPle Assayedon c,7a7932f,,201c@. 04m2@9 GMIS t{2 e-riooogces:orsrorz - bi?072088-- GMts *- - --'lv2-- -a8{,cfpgrn.friu2l ulw2t27 GMIS N2 E800875T20191@5 03A8/'202S GMIS N2 02 20.01 % __o2 - _ _-=-_ __6 Ol 'r coz 9.48 % 0.11s SRM 2659s 0.756 C15rc010.02 0.331 C1847810.03 116a980@5 cl,D5t2g2.1 11@980@5 6l2ns21 Refercnce lnstrumentation SMARTCERT 35 of5l rfihe ou rdd rro.e grodmhf, tocNumb.r: a622ls Cus,,oaetir. ttln trloG r,aEx^tR IHffiRTISIE, Cc ttifi cati o a f nlo r m a ti o n.. Ararfr.d By Llflh O.r & Equlpmcnt lnc.tru8.ALnrd.gtrt.t Lot Angobr CA 0OOEST.l: 323-5tf>2tSa F.r:71+542{6!e PAYPto:FUN,iEl (-dilt bl...t Nth/t. I tqra (ltr,ot ,,.na* pJrrtnt' Ct,t'rm rc a*rhar.r oarzi?(n? c33at t0, rar |a3(xlE As tSattaa n*rrnohrllnl: Typt}yfr;, Cocrotrrlon I Uurnny .. Erpr.alim DaIe|nEr5lb: SAII,/Sangt,/Crrrb,, SRll Coorll[to., / Lrno.E ry sRfl Eqr[ion D.b: Fil O.l, O:l/29t2022 t d tknb. ,ilrrra2ltatt02 CrWWtAiu ^S COAXXCfrtuFrynrnv*tu 2rln,lq !{)t3 ProSpec EZ Ccrt w'm***smu*iffi #ffi*is*ffir**#i::n:,-_, Aaalvdcat Data:r. .6-' *r*r_".F-s.rd'd.zrzc,6rr,c.cacre.r, CcnificatonDaFjo{lU2opp Term Galls / 0@025r 231 g9n , pln o'r^7/&4 PRU/C2t6aOr i 0,5!7.7. aq).a lDn / rl2 !0n oit:?or&. &LC..tlbd ay ffiHffimpgmumffi#Hk cylincler Number: o'/re/202t 36 of5l 37 of5l Date/Time 05/051202i1 13:35 05os/20231i:36 OSIOSPOZS rS:SZ 05/05202313:38 osroryoal tise 05/05202313:lo 05/05202313:41 05/0512023 13:42 05O5/202313:4il 0$0ffi02313:tl4 05/05X2023 13145 05/05P0?it 13:4,6 05/05f2023 13:47 0so5/202313:48 05105/202313{9 05&5t2023 13:50 05/0512023 13:51 05rt)52{X23 13:52 05/05202313:53 05/05/2023 13:&t 0905t2023 13:55 05O51202313:56 05105D02313:57 0S0512023'13:58 05/05202313:50 0505t202314:00 05/05202314:01 05/052@3'14:02 0510512023 14:03 05OSl2@i! 14:o4 05/0520231405 05/05202314:06 05O5202314:07 0$05t2023 14:08 0U051202314:09 05O51202314:10 05to$802314211 (Mt5t202314:12 0905t2023 14:13 0,51051202314:14 0905t2023 14:15 090512023 14:16 05t05Zs2314:17 0S0512023 14:18 FGASTO H2SPPM (PPM) Value 20.3 19.8 19.8 19.8 19.8 19.8 19.8 19.8 19.8 ir; 19.9 19.9 19.9 18.1 18.1 't8.1 18.2 19.3 19.3 19.3 19.3 19.6 19.6 i 19.6 l . 1e'! 18.9 : 18.9 18.9 18.9 20.7 20.7 20.7 20.6 18.3 18.3 18.3 18.3 20.5 20.7 20.7 20.7 20.9 20.9 20.9 38 of5l Date/Time 05t052.02311:19 05t05t7fi2314:N OS1OS:ZOZ ttZt 05nwn23u.2. o$ol)r2ox1i?a 0505t2023 1494 0510,5,12U2311:25 0$05202314:26 05lffit20/311:27 45/0v20231428 05/0512023 1429 0510il20,?IJ14:30 05/05t2023 14:31 0fl05X2023 t4:32 05/05202314:3il 05/05/2023 14:34 030512023 14:35 05/05202314:36 05/0512023 14:37 05O52023't4:38 0S0512023 14:39 05i051202314:lo 05t05fi202314:41 0510il2t2311:42 05O5202314:43 05195f202314:4 0505202314:45 OStEt-202311:46 05to51202314.47 0U05lz-023 14:tA 0905X202314:49 05O51202314:50 0405/202314:51 05t05ti02314:52 o5o5/2b814:53 0$1051202314:t4 0&0V202314:55 0U05202314:56 05lOSt2O2314:57 05O81202314:58 0S05202314:59 0S(8202315:fi) 05O51202315:01 090V202315:02 FCIAST0 H2SPPM (PPM) Value 20.9 21.9 22 22 22 2'.t.5 21.4 21.4 21.4 22.4 22.5 22.5 22.5 22.8 22.8 22.8 22.8 22.s 22.4 22.4 22.4 23.4 23.5 ?3.s 23.5 22.5 22.5 22.5 22.5 21.4 21.3 21.3 21.3 21.9 21.9 21.9 21.9 23.4 23.5 23.5 23.s 22.7 22.7 22.7 Run l Avg 19.6 39 of51 Date/Time 0s0V20231i:08 050512O2315:04 0U052023'15:05 05O5t2O23'15:06 05/0ffi023'15:07 050512023 1s{r8 0S05t2023 t5:Gl 05/0512023 15:10 0S05202315:11 0S0512023 15:12 0S0512023 15:13 05O5/202315:1it 05/05202316:15 05O512023 15:16 05O512023 15:17 0U05I2023 15:18 05/t)512t}23 15:19 os,osaois ri2o 0fl0#02315:21 oylwfr2w3't5-.2. 05/05X2023 15:23 OilO5t2A23t5:24 0ry0$20231525 0S051202315:26 0ry058023 152J 05O51202315:28 05/0512023 15:29 05O5202315:30 05/05/2O23 15:31 05O512023 15:32 05O5202315:33 05O512023 15:3{ 05/05202315:35 05/0512023 15:36 05/0512023 15:37 05O51202315:38 05OV202315:39 05O5t202315:40 0ry05r202315:41 0g05t202315|42 0S05t202315:4il 0S05/i202315:44 090512023 15:45 0S051202315:i[6 FGASTO H2SPPM (PPM) Value 22.7 21.4 21.3 21.3 21.3 23.4 23.6 2?.9 23.6 23 it 23 23 22.6 22.6 22.6 22.6 22.3 22.3 22.3 22.3 23.4 23.5 23.5 23.5 24.1 24.1 24.1 24.1 23.5 23.5 23.5 23.5 23.3 23.3 23.3 23.3 23.1 23.1 23.1 23.1 23.9 24 24 Run 2 avg. 22.4 40 of5l Date/Time 05/052U2315:47 OS0SAOZ3 tS:48 05O5202315:49 05O5202315:50 05/05/2023 15:51 0Y05/202315:52 0405[202315:53 0U05202315:8f 05/052O2315:55 05OSX202315:56 05/05/:2023 15:57 05O6202315:58 05/0512023 15:59 OSIOSPOZS tO:m 0U0512023 16:01 0U05/202316:02 OSIOCUO2g tO:Oe 05O91202316:04 090512023 16:05 05O5202316:06 0U05802316;07 05O51202316:08 0EO5/i202316:09 050512023 t6l0 05O5/2!2316:11 -0$052O2316:12 0!0520?316:13 05(}52(12316:14 0505/202lil 16:15 05O5202316:16 05t0512023 16:17 05O5/202316:18 OYOSAOA rO:lS 0s05/2023 1620 0il05tfr2316121 05/05roB 1622 0ff05/202316:23 05il0V202316:24 0505120231625 0$05P02316:20 05to5t202316:n 05OSr202316:28 05CI5t2023't629 0V05X2023 16:30 FGASTO H2SPPM (PPM) Value 24 23.2 23.2 23.2 23.2 Run 3 avg 23.2 23.8 23.9 23.9 23.9 ztc 24 1 24 23.1 23.1 23.1 23.1 23.3 23.3 23.3 23.3 22.4 22.3 22.3 22.3.: 22.8 22.8 i 22.8 23.4 23.4 23.4 23.4 21.5 z'.t.4 21.4 2'.t.4 22.6 22.7 22.7 22.7 22.3 22.3 22.3 41 of5l Date/Time ; 05D5/?)2316:31 : 05n5D02316;32 : 05/0512023 16:33 I ososaozg to:el i oryosaoza re,ss , 0U05202316:36 r 05/0512023 16:37 :, 0S05t202316:38 I 090512023 16:39 r 090512023 16:rO , 05/0512023 16:41 , 0U0512023 16:il2 i 0905202316:4il Ii oryosr2oz3 ts:a t' 0905x2023'16:45 r 05/05X2023 16:46 : Nt05fi202316:47 ' 0i/052{I2316:48 i 05DSI2023'16:49 i 0U05r1202316:50 I 090512023 16:51 ; 05/05f2023 16:52 :; 05l05X2(I23'16:53 i 05O5202316:54 Ii oryoryzoaa to:ss r 05O51202318:56 I 0S05X202316:57 , OryOSAOZS lS:5S i: 0909202316:59 ; 0il05r12023 17:fl) i 05/05/2023 17:01 ', OSt05l2Q2317:02 : 05105t1202317:,W ' 051051202317:M : 0S0512023 17:05 ii 05/0512023 17:06 , 05105t2O2317:07 ; 0S0$202317:08 ' 0505202317:09 05O51202317:10 051051202317t11 0ilO5t7102317:'12 0S052023'17:13 0it0il202317:14 FGASTO H2SPPM (PPM) Value 22.3 21.3 21.2 21.2 21.2 21.2 21.2 21.2 21.2 20.6 20.6 20.6 20.6 Run 4 avg 22.7 21.1 : 2',t.1 2't.1 21.1 21 21 21 21 20.4 20.3 20.3 20.3 21.1 21.1 21.1 21.1 20.1 19.9 19.9 20.1 20.1 20.1 20.1 19.2 19 19 19 19.3 19.4 19.4 42 of 51 Date/Time 05O5O02317:15 0fl0512023 17:16 omsruiitt:tt 05O5202317:18 05O5202317:19 0!05202317:20 05/05/20231721 OSlOEffi2317:2. ostovzwn.n 05t05/20231721 050sr2023 17* 0S0@02317:26 ow$ry}y?l oefiEtw2917fr o6tffit2t2317.29 0$05f2{I2317:fl} 05,05202i! 17:31 O$l05lilnx2517:32 0&0M0Zll7:3il 05O51202317:31 0s05I2023 173s 0505/2!a3 1736 o5t05f2u,3_1797 05t0ry2vz317-.$ 05O58m317:39 0505202317:40 06fi/ff2s2317:11 05105fi2t2317:12 osto5,tlrgB 17-a3 05O5202317:41 O5lO5//2t2317:$ oilwno?3fl:d6, 05|OW2&?B17:47 (M)51202317:48 OSOYZOZS tZ:le 05/05202317:50 05O5/2023 17:61 0U05P02317:!2 0S051202317:53 0S05/202317:Af 0g05t2023 17:55 0S05202317:56 05tmt202317-.67 05/051208 17:58 FGASTO H2SPPM (PPM) . . Vclue 19.4 19.3 19.3 19.3 19.3 19.7 Je.7 19.7 19J 19 18.9 18.9 18.9 19.6 19.7 19.7 19.7 20.1 20.2 20.2 20.2 Je.5 . 19.5 19.5 20.3 20.5 20.5 20.5 20.3 20.3 20.3 20.3 20.2 20.2 20.2 20.2 i2o.e I l21 : 21 21 21.3 21.3 21.3 Run 5 avg 2O.2 43 of51 Date/Time 05/0512023 17:59 0s051202318:00 05O51202318:01 0510512023 18:02 0S0512023't8:fi1 0t05/202318:04 05/05f2023 18:05 0S051202318:06 0v058023 18S7 05/0512023 18:08 0U05t202318:09 0S05f2023 18:10 05O5202318:11 05O512023 18:12 0S0512023 18:13 0510512023 18:14 05/0512023 1 8:'15 05/0512023 18:'16 o5to5t&2318;17 05/0512023 18:18 05/0512023 18:19 05105fr2t2318:20 0810il1202318:2'l OSlOrStZO2318:.2. 05/052081813 o5n5fD231821 05t05r20?.318.25 0S052(2318:26 0il05t1202318227 0S051202318:28 05O51202318:29 05O51202318:30 05O51202318:31 0,st0v202318-.32 0il05t202318|33 0V05/2023 18:34 0U0512023 18:35 0$0512023 18:36 0ff0$202318:37 05/05/2023 '18:38 0S0512023 18:39 0S05/2023 18:40 05/0512023 18:41 0510W2O2'318:42 FGASTO H2SPPM (PPM) Value 21.3 20.7 20.5 20.5 20.5 19.5 19.4 19.4 19.4 v0 20.1 20.1 20.1 20.2 20.3 20.3 20.3 20.2 20.2 20.2 20.2 20.1 20.1 20.1 20.1 20.6 20.7 20.7 20.7 20.4 20.4 20.4 20.4 20.6 20.6 20.6 20.6 20.'l 20.1 20.1 20.1 20.4 20.5 20.5 Run 5 avg 20.2 44 of 5l Date/Time O505t202lit 18:43 0soy2o2i 18:44 O5/05D023 l8:il5 0SI)5202318:46 OSIO5D02318:17 05051202318:48 0ry05r202318:49 05OSt202318:50 05/05/2023 18:51 05/05202318:52 05O512023 18:53 0S05202318:81 05O52023'18:55 0905202318:56 080512023 t8:57 05,052!23 1S58 05(}52(12318:59 05,o5,202i1r9$0 05O5202319:01 05t05fi102319:02 05/05n0231903 05O5/202319:O4 05O51202319:05 0S05t2023 19:06 05O5202319:07 0fl05r2!2319:08 05O51202319:09 05O5202319:10 05/0512023 19:11 05/0512023 19:12 0U05202ii 19:13 05O5202319:14 05/0S2023 19:15 0S0512023 19:16 05OSt20?319:17 05105P02319:18 030512023 19:19 0505/20231920 0S051202319:21 ostos/Ioz31g.2. 0S0V202319:23 05t051202319|21 05O51202319:25 05O51202319:26 FCaASTO H2SPPM (PPM) Value 20.5 19.4 19.3 19.3 19.3 19.7 19.8 19.8 19.8 1?.2 19.1 19.1 19.1 18.8 18.8 18.8 18.8 18.5 18.4 18.4 18.4 18.9 18.9 18.9 18.9 18.4 18.3 18.3 18.3 18.7 '18.7 18.7 18.1 18.4 18.4 18.4 18.4 18.7 : 18.7 18.7 18.7 18.2 18.1 18.1 Run 7 avg 2O.7 45 of5l Date/Time awy?{l/B192t 05fi)5/202319:28 0s052023 1929 OsOSnOaS ter30 G5/05202319:31 05O52{t231i:32 0805/20?319:33 05/I)5t20819:34 05O51202319:35 05(}M02319:36 05O5202319:37 05O52([X119:38 0M)52023 19:39 q/o?ry29:0:40 05/05rXr2319:4I 05t(fitfff2319:42 05/0@0Zl19:€ 05(8202319:4tl bsosziii rsras 05O5/2021t 10:46 05/051412310:47 {E/051202i1 19:48 o5o*g41e;4e 0&O5/202319:50 05O520?319:5t (M)5202310:52 OgroSrZOa tgrst 05O5202319:!l 05I05f2023 19:55 05/05202319:56 05/05X2023 l9:5-l 05O5/202319:58 05O5202319:59 0505/:?023 20:00 05/052023 20:01 aaooni2s,r,iw 0il)5/202320:03 05O5202320:O4 0&I!512023 20:05 05O5/2023 2I):06 05OSl20Zl20:07 05O5/12023 20:08 05O512023 20:09 FGASTO H2SPPM (PPM) Value 18.1 18.3 18.3 18.3 18.3 18.5 18.5 1815 't8.5 19 19.1 19.1 19.1 19.1 19.1 19.1 't9.1 is.t 19.9 19.9 19.9 19.7 19.6 19.6 19.6 18.8 18.7 18.7 18.7 19.3 19.5 19.5 19.5 19.3 19.2 19.2 19.2 19.s 19.6 19.6 19.6 20.1 20.2 20.2 Run 8 avg 18.5 05O5202320:10 46 of5l Dat€/Time 05O512023 20:I1 0U05/2023 20:12 05O_5/202320:13 QAOWXfrJ320:14 05/05202i120:15 0905/2023 20:16 o,5t0il2V232s;17 OstffifiN2320|18 0305/202320:19 05/05i2023 2020 05t05fr20292021'istostzrrliio.n O5lOSt2lt23?J:% 05,()52023 2024 05/0512023202s o$t0il2023?0,26 05t0Y92320/.27 os/Fry232028 05/05/2023 2029 05O5t2023 20:30 0$t0512023 20:31 05fr5t'12@320:32 05/05t283 20:311 0&05tr02320:3'l o$osaoes2ms 05/0520820A6 05O512023 20:37 llosaoazo;p 05052023 2039 05/05X2023 20:tO 05105202320:41 ostoBt?oz,32aA2 OSIOSTZO2S ZOraS 05O@02320:41 05to$t202320:45 05O5X2023 20:46 0ffi5tr02320:41 05O5202320:48 0510512023 20:49 05O512023 20:50 05O52023 20:51 05t05f,&2320;52 0S05204120:53 0S05202320:&t FCrASTO H2SPPM (PPM) Value 20.2 20.1 20.'l 20.1 20.1 19.7 19.6 19.6 1e:6 19-:1 18.9 18.9 18.9 19.3 't9-4 19.4 19.4 18.7 . 18.5 18.5 18.5 19 19.1 1e.l 19.1 18.4 18.2 18.2 18.2 .t9 19.2 19.2 19.2 18.7 18.6 18.6 18.6 17.9 17.7 17.7 17.7 17.9 17.9 17.9 Run 9 avg 19.5 47 of 5l Date/Time , 05/051202320:55 05/052023 20:56 ii O5|O5f,2o232O:87 i .'I 05/051202320:5E i 05105t2t2320::59 i0505/20232100 t 0510511M321:01 | 05t05ti202321:,02 ; owosamrztros I: 05f052023 21:0rf t, 05OSI2023 2'l:05 i 0U05I202321:06 I oaosntztzt::ot 1, 05/05120?3 21:08 I 0fl05/11023 21:09 i i05O51202321:10 05/05/2023 21:1 1 ' oltosFzo2g21ltz r05/05202321:13 ; i 05t052.U2321:14 ; 051051202321:15 i 0U05t202321:16 ; OSlOil2A232l:17 i0S05202321:18 I' 051051242321:19 i 05t0$r202321:20 ', 05t0ilN2321:21 ; 05t0il202321:D. , 05t05n0232't:23 t, ostolsr2}z32't'zq , 0il05t1102321:25 05to5tM321:,s, , 05lo5tiD2321:27 ' 05t0iB02321:28 : 0il05?o2321:N 05/05t2023 21:30 05t05t&2321.31 ' OSlO5t1N2321:32 0S0512023 2t:33 i 0il05B02321:4 05105112Q2321:35 05O512023 21:36 O5lOSl12O2321:37 05t05D02321|* FC1AS70 H2SPPM (PPM) Value 17.9 18.6 18.7 '18.7 18.7 18.1 17.9 17.9 17.9 18.3 18.4 18.4 18.4 18.2 18.1 18.1 18.1 18.7 18.9 18.9 18.9 18.2 18.1 18.1 18.1 17.6 17.4 17.4 17.4 18,1 18.3 18.3 18.3 18.4 18.5 18.5 18.5 18.7 18.7 18.7 18.7 18.3 18.2 18.2 Run 10 avg 78.4 48 of5l Date/Time 0S05202321:39 050ffi02321:40 05f)5r204i21:tll osffi*za OilOSAtZ321:49 oiffisx:q 05/0512043 21:rl5 ffil05lElfi?B21:46 O5lO5fi2U232l:.17 05/05f21!23 21:'O 0S0520232'l:49om Jirtso 05O5202321:5t A$1Eff202ts21:52 05O5202321:53 05t0$frM821|il 05/0512@321:55 gio_ry1_ir'so 05O5i2023 21:57 05tost2o2321|W 05O5{2023 21:59 0ff)5t12t232:00 oilwnw3?,,fil .05t05t2023?2:A2 05/t)5r2o2it 22{}3 05105f2A232.V 05m5802322s5 05/05120211 22:06 05105frlIJE,32l:O 0ffi5fr2W2322:8 O*OqA*oarZtOo 0-5t0ilN2322:10 06t05112U232:11 A5$51'Z}23Z2:,12 0ilO51i2023/2:13 OilOil?{)xfJ22:114 OSt06li202322:15 0S0S?12322:16 05105fi2023D.17 0Blg5li2H322:,18 05t05fri{fif 7)t19 Q5t05f2A2322:20 6105fi2423*2:21 OStOSt 2o,?'322:2, FGASTO H2SPPM (PPM) Valug 18.2 17.7 17.6 17.6 17.6 18.4 18.7 18.7 18.7 18 17.8 17.8 17.8 17.7 '17.6 17.6 17.6 17.8 17.9 17.9 17.5 18.2 18.3 18.3 18.3 l 1l-2 18.2 i 18.2 l 18.2 : 17.9 17.9 17.9 17.7 17.7 17.7 17.7 17.9 18 18 18, 18.9 19.2 19.2 Run 11 avg 18.1 49 of51 Date/Time 0il05t202322-23 OSIOSI-202322:A 05n5r2u2322-2s O5t0ilil0i23fl:26 05$5nt2322.21 051051i202322:28 05105f202322:N OAO5€;02322:& 05105fi202322:31 0il05fi202322:32 05105t202322:13 O5l05ti2023?P.:94 0ff]6t202322:35 OSIO5/|2$232:36 051051202322:.37 05N$1202322:* 09052023 22:39 0,805til,2322t4o 0ffi5frN23?,:41 o5/ail?&2sn.42 05t05ti2023?2:43 0il05t?o23?2;44 4ffi5fr202322145 a6to5t1202322:S FGASTO H2SPPM (PPM) Value 19.2 18.7 18.5 18.5 18.5 19.2 19.4 19.4 19.4 19t6 19.7 19.7 19.7 19.8 19.8 19.8 19.8 19.6 19.6 19.6 19.6 20 20.1 20.1 Run 12 avg 50 of5l ) UTAH DI.PARTI'/EiJT OF E N,v! B g-ry U trELQUn- I t rv._-'1 JUL - 3 2023 I DIVISION OF AIR OUALITY 5l of5l