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HomeMy WebLinkAboutDAQ-2024-011067 DAQE-AN141770005-24 {{$d1 }} Gene Chrisenbery Mountain States Asphalt, Inc. PO Box 1268 Tooele, UT 84074 gene.msa@outlook.com Dear Mr. Chrisenbery: Re: Approval Order: Administrative Amendment to Approval Order DAQE-AN141770004-21 to Update VOC Emissions from the Plant Project Number: N141770005 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on May 15, 2024. Mountain States Asphalt, Inc. must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Mr. Tim DeJulis, who can be contacted at (385) 306-6523 or tdejulis@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. Sincerely, {{$s }} Bryce C. Bird Director BCB:TD:jg cc: Tooele County Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director September 10, 2024 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN141770005-24 Administrative Amendment to Approval order DAQE-AN141770004-21 to Update VOC Emissions from the Plant Prepared By Mr. Tim DeJulis, Engineer (385) 306-6523 tdejulis@utah.gov Issued to Mountain States Asphalt, Inc. - Liquid Asphalt, ATB's, and Crude Oil Terminal Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality September 10, 2024 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 4 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 7 PERMIT HISTORY ................................................................................................................... 10 ACRONYMS ............................................................................................................................... 11 DAQE-AN141770005-24 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Mountain States Asphalt, Inc. Mountain States Asphalt, Inc. - Liquid Asphalt, ATB's, and Crude Oil Terminal Mailing Address Physical Address PO Box 1268 205 South Emerald Road Tooele, UT 84074 Tooele, UT 84074 Source Contact UTM Coordinates Name: Gene Chrisenbery 386,886 m Easting Phone: (435) 659-1984 4,487,155 m Northing Email: gene.msa@outlook.com Datum NAD83 UTM Zone 12 SIC code 2951 (Asphalt Paving Mixtures & Blocks) SOURCE INFORMATION General Description Mountain States Asphalt, Inc. (MSA) receives asphalt, atmospheric tower bottoms (ATB), and other assorted crude oils (ACO) at the plant, located in Tooele, Tooele County, by train or truck. Thirty-six (36) vertical fixed roof (VFR) tanks will store the asphalt, ATBs, or ACO. Thirty-one (31) train/truck unloading/loading stations are in the plant. The emissions from the asphalt, ATB, or ACO unloading/loading and storage tanks will be controlled by a submerged filling system, a vapor balancing system, and an enclosed flare device. The asphalt is sold to third-party customers to make asphalt paving materials at various locations throughout the area. The local petroleum refineries will use this terminal to store ATBs and ACO until they are ready to process it in their separate plants. The ATBs and ACO terminal will be capable of a throughput of 3,266,750 barrels (137,203,500 gallons) per rolling 12-month period. The production of asphalt will be capable of a throughput of 1,095,238 barrels (46,000,000 gallons) per rolling 12-month period. NSR Classification Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA Tooele County Airs Source Size: SM DAQE-AN141770005-24 Page 4 Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), Dc: Standards of Performance for Small Industrial-Commercial-Institutional Steam Generating Units NSPS (Part 60), Kb: Standards of Performance for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid Storage Vessels) for Which Construction, Reconstruction, or Modification Commenced After July 23, 1984 Project Description MSA has requested permission to update AO DAQE-AN141770004-21, dated February 18, 2021. MSA will use the latest EPA Tanks 5.0 to estimate the emissions of VOC. Using EPA Tanks 5.0, the emissions from the source will be reduced from 60.24 tpy to 31.18 tpy. This methodology will make the source a synthetic minor source under serious ozone nonattainment area thresholds. No other changes are being made to the plant. This change is done under R307-401-12, Reduction in Air Pollutants. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 6544.00 Carbon Monoxide 0 22.84 Nitrogen Oxides 0 15.21 Particulate Matter - PM10 0 1.26 Particulate Matter - PM2.5 0 0.12 Sulfur Dioxide 0 0.12 Sulfur Oxides 0.12 Volatile Organic Compounds -29.06 31.18 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 0 660 Ethyl Benzene (CAS #100414) 0 1300 Generic HAPs (CAS #GHAPS) 0 340 PAH, Total (CAS #234) 0 3260 Toluene (CAS #108883) 0 6500 Xylenes (Isomers And Mixture) (CAS #1330207) 0 6500 Change (TPY) Total (TPY) Total HAPs 0 9.28 DAQE-AN141770005-24 Page 5 SECTION I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Distribution Terminal Asphalt, ATBs, and Crude Oil Distribution Terminal II.A.2 Primary Storage Tanks Four (4) VFR tanks Capacity: 120,861 barrels each Service: asphalt Three (3) VFR tanks Capacity: 83,932 barrels each Service: ATBs or ACO NSPS Subpart Kb DAQE-AN141770005-24 Page 6 II.A.3 Asphalt Blending Tanks Fifteen (15) vertical, fixed roof storage tanks Capacity: 38,000 barrels each Three (3) vertical, fixed roof storage tanks Capacity: 20,144 barrels each Four (4) vertical, fixed roof storage tanks Capacity: 6,855 barrels each Four (4) vertical, fixed roof storage tanks Capacity: 5,036 barrels each Ten (10) vertical, fixed roof storage tanks Capacity: 1,095 barrels each Twelve (12) vertical, fixed roof storage tanks Capacity: 895 barrels each II.A.4 Water or Latex Storage Tanks Seven (7) vertical, fixed roof storage tanks Capacity: 476 barrels each For information purposes only. II.A.5 Boilers Three (3) boilers Capacity: 10 MMBtu/hr each Fuel: natural gas NSPS Subpart Dc II.A.6 Asphalt/Crude Oil Product Loading Racks Thirty-one (31) Unloading/Loading Racks Ten (10) rail car asphalt unloading/loading racks One (1) truck asphalt unloading rack Three (3) truck asphalt loading racks Two (2) truck asphalt emulsion loading racks Thirteen (13) rail car unloading/loading racks Two (2) truck unloading/loading racks Attached equipment: submerged filling and vapor capture system II.A.7 Flare Device Capacity: 9 MMBtu/hr Pilot light fuel is natural gas DAQE-AN141770005-24 Page 7 SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site Requirements II.B.1.a Unless otherwise stated in this AO, the owner/operator shall not allow visible emissions to exceed the following: A. All boilers - 10% opacity. B. Flare device - 0% opacity. C. Haul roads and mobile equipment operating areas - 20% opacity. D. At the property boundary - 10% opacity. [R307-309-5, R307-401-8] II.B.1.a.1 Unless otherwise stated, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.1.a.2 Visible fugitive dust emissions from haul-road traffic and mobile equipment in operational areas shall not exceed the above opacity limit at any point. Visible emission determinations shall use procedures similar to Method 9. The normal requirement for observations to be made at 15-second intervals over a six-minute period, however, shall not apply. Visible emissions shall be measured at the densest point of the plume but at a point not less than 1/2 vehicle length behind the vehicle and not less than 1/2 the height of the vehicle. [R307-309-9] II.B.2 Roads and Fugitive Dust II.B.2.a An electronic FDCP can be completed through the Utah DEQ Fugitive Dust Plan Permit Application Website. If a written FDCP is completed, it shall be submitted to the Director, Attention: Compliance Branch, for approval. The owner/operator shall comply with the FDCP for control of all fugitive dust sources associated with the asphalt, ATBs, or black wax crude oil terminal. [R307-309-6] II.B.2.b The owner/operator shall pave in-plant haul roads. The paved in-plant haul roads shall not be less than 0.50 miles in combined length. [R307-401-8] II.B.2.b.1 Compliance shall be determined through Global Positioning System (GPS) measurements or aerial photographs. [R307-401-8] II.B.2.c The owner/operator shall sweep, or spray clean the paved in-plant haul roads to maintain the opacity limits in this AO. [R307-309-6, R307-401-8] II.B.2.c.1 Records of cleaning paved roads shall be kept for all periods the plant is in operation. The records shall include the following items: 1. Date of cleaning(s). 2. Time of day cleaning(s) were performed. [R307-309-6, R307-401-8] DAQE-AN141770005-24 Page 8 II.B.3 Loading Rack and Storage Tank Requirements II.B.3.a The owner/operator shall not exceed the following limits: A. 1,095,238 barrels (46,000,000 gallons) of asphalt product throughput per rolling 12-month period. B. 3,266,750 barrels (137,203,500 gallons) of ATBs, or ACO throughput per rolling 12-month period. [R307-401-8] II.B.3.a.1 The owner/operator shall: A. Determine the asphalt product, ATB, and ACO throughput by examination of company and/or customer billing records. B. Record production on a daily basis. C. Use the production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months. D. Keep the asphalt product, ATB, and ACO throughput records for all periods the plant is in operation. [R307-401-8] II.B.3.b The owner/operator shall not store any crude oil with an RVP greater than 11.2 psi. [R307-401-8] II.B.3.b.1 The owner/operator shall: A. Record the RVP of the ACO each time the owner/operator changes to a new crude oil. B. Determine the RVP by the SDS records accompanying each rail car or tanker truck that arrives at the plant. C. Record the RVP for all periods when the plant is in operation. D. Record the RVP in a supervisor's log book. [R307-401-8] II.B.3.c The owner/operator shall load the tanker trucks and rail cars on site by the use of submerged loading. [R307-401-8] II.B.3.d The owner/operator shall control emissions from the loading racks and storage tanks that process the ATB or ACO with a vapor capture system and flare device at all times. [R307-401-8] II.B.4 Flare and Fuel Requirements II.B.4.a The owner/operator shall only use natural gas as fuel in the boilers. [R307-401-8] II.B.4.b The owner/operator shall operate each flare device with a continuous pilot flame and be equipped with an auto-igniter. [R307-503-4] II.B.4.c The owner/operator shall operate each flare device with no visible emissions. [R307-401-8] DAQE-AN141770005-24 Page 9 II.B.4.c.1 Visual determination of emissions from each flare shall be conducted according to 40 CFR 60, Appendix A, Method 22. [R307-401-8] II.B.4.d The owner/operator shall install a flare device that has a certified control efficiency of 99%. [R307-401-8] II.B.4.d.1 To demonstrate compliance with the control efficiency, the owner/operator shall keep a record of the manufacturer's certification of the control efficiency. The record shall be kept for the life of the equipment. [R307-401-8] II.B.5 LDAR Requirements II.B.5.a The owner/operator shall develop a fugitive emissions monitoring plan for the storage tanks and flare operations. At a minimum, the plan shall include: A. Monitoring frequency. B. Monitoring technique and equipment. C. Procedures and timeframes for identifying and repairing leaks. D. Recordkeeping practices. E. Calibration and maintenance procedures. [R307-401-8] II.B.5.b The plan shall address monitoring for "difficult-to-monitor" and "unsafe-to-monitor" components. [R307-401-8] II.B.5.c Monitoring surveys shall be conducted according to the following schedule: A. No later than 60 days after startup of production, as defined in 40 CFR 60.5430a. B. Semiannually after the initial monitoring survey. Consecutive semiannual monitoring surveys shall be conducted at least 4 months apart. C. Annually after the initial monitoring survey for "difficult to monitor" components. D. As required by the owner/operator's monitoring plan for "unsafe to monitor" components. [R307-401-8] II.B.5.c.1 Monitoring surveys shall be conducted using one or both of the following to detect fugitive emissions: A. Optical gas imaging (OGI) equipment. OGI equipment shall be capable of imaging gases in the spectral range for the compound of highest concentration in the potential fugitive emissions. B. Monitoring equipment that meets U.S. EPA Method 21, 40 CFR Part 60, Appendix A. [R307-401-8] II.B.5.c.2 If fugitive emissions are detected at any time, the owner/operator shall repair the fugitive emissions component as soon as possible but no later than 30 calendar days after detection. [R307-401-8] DAQE-AN141770005-24 Page 10 II.B.5.c.3 The owner/operator shall resurvey the repaired or replaced fugitive emissions component no later than 30 calendar days after the fugitive emissions component was repaired. [R307-401-8] II.B.5.d The owner/operator shall maintain records of the fugitive emissions monitoring plan, monitoring surveys, repairs, and resurveys. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN141770004-21 dated February 18, 2021 Is Derived From NOI dated May 15, 2024 DAQE-AN141770005-24 Page 11 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE- RN141770005 August 7, 2024 Gene Chrisenbery Mountain States Asphalt, Inc. PO Box 1268 Tooele, UT 84074 gene.msa@outlook.com Dear Gene Chrisenbery, Re: Engineer Review - Administrative Amendment to DAQE-AN141770004-21 to Update VOC Emissions from the Plant Project Number: N141770005 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review (NSR) permitting program. Mountain States Asphalt, Inc. should complete this review within 10 business days of receipt. Mountain States Asphalt, Inc. should contact Mr. Tim DeJulis at (385) 306-6523 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Mr. Tim DeJulis at tdejulis@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an Approval Order (AO) for signature by the DAQ Director. If Mountain States Asphalt, Inc. does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Mountain States Asphalt, Inc. has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature __Robert E. Chrisenbery________________9/4/2024_______________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N141770005 Owner Name Mountain States Asphalt, Inc. Mailing Address PO Box 1268 Tooele, UT, 84074 Source Name Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal Source Location 205 S. Emerald Rd. Tooele, UT 84074 UTM Projection 386,886 m Easting, 4,487,155 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 2951 (Asphalt Paving Mixtures & Blocks) Source Contact Gene Chrisenbery Phone Number (435) 659-1984 Email gene.msa@outlook.com Billing Contact Gene Chrisenbery Phone Number 435-659-1984 Email gene.msa@outlook.com Project Engineer Mr. Tim DeJulis, Engineer Phone Number (385) 306-6523 Email tdejulis@utah.gov Notice of Intent (NOI) Submitted May 15, 2024 Date of Accepted Application May 15, 2024 Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 2 SOURCE DESCRIPTION General Description Mountain States Asphalt, Inc. (MSA) receives asphalt, atmospheric tower bottoms (ATB), and other assorted crude oils (ACO) at the plant, located in Tooele, Tooele County, by train or truck. Thirty-six vertical fixed roof (VFR) tanks will store the asphalt, ATBs, or ACO. Thirty-one train/truck unloading/loading stations are in the plant. The emissions from the asphalt, ATB, or ACO unloading/loading and storage tanks will be controlled by a submerged filling system; vapor balancing system; and enclosed flare device. The asphalt is sold to third party customers to make asphalt paving materials at various locations throughout the area. The local petroleum refineries will use this terminal to store ATBs and ACO until they are ready to process it in their separate plants. The ATBs and ACO terminal will be capable of a throughput of 3,266,750 barrels (137,203,500 gallons) per rolling 12-month period. The production of asphalt will be capable of a throughput of 1,095,238 barrels (46,000,000 gallons) per rolling 12-month period. NSR Classification: Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA Tooele County Airs Source Size: SM Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), Dc: Standards of Performance for Small Industrial-Commercial-Institutional Steam Generating Units NSPS (Part 60), Kb: Standards of Performance for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid Storage Vessels) for Which Construction, Reconstruction, or Modification Commenced After July 23, 1984 Project Proposal Administrative Amendment to DAQE-AN141770004-21 to Update VOC Emissions from the Plant Project Description MSA has requested permission to update DAQE-AN141770004-21, dated February 18, 2021. MSA will use the latest EPA Tanks 5.0 to estimate the emissions of VOC. Using EPA Tanks 5.0, the emissions from the source will be reduced from 60.24 tpy to 31.18 tpy. This methodology will make the source a synthetic minor source under serious ozone nonattainment area thresholds. No other changes are being made to the plant. This change is done under R307-401-12, Reduction in Air Pollutants. EMISSION IMPACT ANALYSIS This is an administrative amendment for an update of VOC emissions using Tanks 5.0. There is no increase in emissions associated with this update. Therefore, this amendment does not trigger the modeling requirements in R307-410-4 or R307-410-5. [Last updated July 29, 2024] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 3 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 6544.00 Carbon Monoxide 0 22.84 Nitrogen Oxides 0 15.21 Particulate Matter - PM10 0 1.26 Particulate Matter - PM2.5 0 0.12 Sulfur Dioxide 0 0.12 Sulfur Oxides 0.12 Volatile Organic Compounds -29.06 31.18 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 0 660 Ethyl Benzene (CAS #100414) 0 1300 Generic HAPs (CAS #GHAPS) 0 340 PAH, Total (CAS #234) 0 3260 Toluene (CAS #108883) 0 6500 Xylenes (Isomers And Mixture) (CAS #1330207) 0 6500 Change (TPY) Total (TPY) Total HAPs 0 9.28 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 4 Review of BACT for New/Modified Emission Units 1. BACT review regarding Process Equipment This is an administrative amendment for an update of VOC emissions using the EPA Tanks 5.0. A BACT analysis is not required for these administrative amendments. [Last updated July 29, 2024] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 5 SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 Distribution Terminal Asphalt, ATBs, and Crude Oil Distribution Terminal II.A.2 Primary Storage Tanks Four (4) vertical fixed roof tanks Capacity: 120,861 barrels each Service: asphalt Three (3) vertical fixed roof tanks Capacity: 83,932 barrels each Service: ATBs or assorted crude oils NSPS Subpart Kb II.A.3 Asphalt Blending Tanks Fifteen (15) vertical, fixed roof storage tanks Capacity: 38,000 barrels each Three (3) vertical, fixed roof storage tanks Capacity: 20,144 barrels each Four (4) vertical, fixed roof storage tanks Capacity: 6,855 barrels each Four (4) vertical, fixed roof storage tanks Capacity: 5,036 barrels each Ten (10) vertical, fixed roof storage tanks Capacity: 1,095 barrels each Twelve (12) vertical, fixed roof storage tanks Capacity: 895 barrels each II.A.4 Water or Latex Storage Tanks Seven (7) vertical, fixed roof storage tanks Capacity: 476 barrels each For information purpose only. Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 6 II.A.5 Boilers Three (3) boilers Capacity: 10 MMBtu/hr each Fuel: natural gas NSPS Subpart Dc II.A.6 Asphalt/Crude Oil Product Loading Racks Thirty-one (31) Unloading/Loading Racks Ten (10) rail car asphalt unloading/loading racks One (1) truck asphalt unloading rack Three (3) truck asphalt loading racks Two (2) truck asphalt emulsion loading racks Thirteen (13) rail car unloading/loading racks Two (2) truck unloading/loading racks Attached equipment: submerged filling and vapor capture system II.A.7 Flare Device Capacity: 9 MMBtu/hr Pilot light fuel is natural gas SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site Requirements II.B.1.a NEW Unless otherwise stated in this AO, the owner/operator shall not allow visible emissions to exceed the following: A. Haul roads and mobile equipment operating areas - 20% opacity B. At the property boundary - 10% opacity. [R307-309-5, R307-401-8] II.B.1.a.1 Unless otherwise stated, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 7 II.B.1.a.2 NEW Visible fugitive dust emissions from haul-road traffic and mobile equipment in operational areas shall not exceed the above opacity limit at any point. Visible emission determinations shall use procedures similar to Method 9. The normal requirement for observations to be made at 15-second intervals over a six-minute period, however, shall not apply. Visible emissions shall be measured at the densest point of the plume but at a point not less than 1/2 vehicle length behind the vehicle and not less than 1/2 the height of the vehicle. [R307-309-9] II.B.2 Roads and Fugitive Dust II.B.2.a NEW An electronic FDCP can be completed through the Utah DEQ Fugitive Dust Plan Permit Application Website. If a written FDCP is completed, it shall be submitted to the Director, attention: Compliance Branch, for approval. The owner/operator shall comply with the FDCP for control of all fugitive dust sources associated with the asphalt, ATBs or black wax crude oil terminal. [R307-309-6] II.B.2.b The owner/operator shall pave in-plant haul roads. The paved in-plant haul roads shall not be less than 0.50 miles in combined length. [R307-401-8] II.B.2.b.1 Compliance shall be determined through Global Positioning System (GPS) measurements or aerial photographs. [R307-401-8] II.B.2.c The owner/operator shall sweep, or spray clean the paved in-plant haul roads to maintain the opacity limits in this AO. [R307-309-6, R307-401-8] II.B.2.c.1 NEW Records of cleaning paved roads shall be kept for all periods the plant is in operation. The records shall include the following items: 1. Date of cleaning(s) 2. Time of day cleaning(s) were performed. [R307-309-6, R307-401-8] II.B.3 Loading Rack and Storage Tank Requirements II.B.3.a NEW The owner/operator shall not exceed the following limits: A. 1,095,238 barrels (46,000,000 gallons) of asphalt product throughput per rolling 12- month period B. 3,266,750 barrels (137,203,500 gallons) of ATBs, or ACO throughput per rolling 12- month period. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 8 II.B.3.a.1 NEW The owner/operator shall: A. Determine the asphalt product, ATB and ACO throughput by examination of company and/or customer billing records B. Record production on a daily basis C. Use the production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the asphalt product, ATB, and ACO throughput records for all periods the plant is in operation. [R307-401-8] II.B.3.b NEW The owner/operator shall not store any crude oil with an RVP greater than 11.2 psi. [R307-401-8] II.B.3.b.1 NEW The owner/operator shall: A. Record the RVP of the ACO each time the owner/operator changes to a new crude oil. B. Determine the RVP by the SDS records accompanying each rail car or tanker truck that arrives at the plant. C. Record the RVP for all periods when the plant is in operation. D. Record the RVP in a supervisor's log book. [R307-401-8] II.B.3.c The owner/operator shall load the tanker trucks and rail cars on site by the use of submerged loading. [R307-401-8] II.B.3.d The owner/operator shall control emissions from the loading racks and storage tanks that process the ATB or ACO, with a vapor capture system and flare device at all times. [R307-401-8] II.B.4 Flare and Fuel Requirements II.B.4.a The owner/operator shall only use natural gas as fuel in the boilers. [R307-401-8] II.B.4.b The owner/operator shall operate each flare device with a continuous pilot flame and be equipped with an auto-igniter. [R307-503-4] II.B.4.c The owner/operator shall operate each flare device with no visible emissions. [R307-401-8] II.B.4.c.1 Visual determination of emissions from each flare shall be conducted according to 40 CFR 60, Appendix A, Method 22. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 9 II.B.4.d The owner/operator shall install a flare device that has a certified control efficiency of 99%. [R307-401-8] II.B.4.d.1 To demonstrate compliance with the control efficiency, the owner/operator shall keep a record of the manufacturer's certification of the control efficiency. The record shall be kept for the life of the equipment. [R307-401-8] II.B.5 LDAR Requirements II.B.5.a The owner/operator shall develop a fugitive emissions monitoring plan for the storage tanks and flare operations. At a minimum, the plan shall include: A. Monitoring frequency B. Monitoring technique and equipment C. Procedures and timeframes for identifying and repairing leaks D. Recordkeeping practices E. Calibration and maintenance procedures. [R307-401-8] II.B.5.b The plan shall address monitoring for "difficult-to-monitor" and "unsafe-to-monitor" components. [R307-401-8] II.B.5.c Monitoring surveys shall be conducted according to the following schedule: A. No later than 60 days after startup of production, as defined in 40 CFR 60.5430a. B. Semiannually after the initial monitoring survey. Consecutive semiannual monitoring surveys shall be conducted at least 4 months apart. C. Annually after the initial monitoring survey for "difficult-to-monitor" components. D. As required by the owner/operator's monitoring plan for "unsafe-to-monitor" components. [R307-401-8] II.B.5.c.1 Monitoring surveys shall be conducted using one or both of the following to detect fugitive emissions: A. Optical gas imaging (OGI) equipment. OGI equipment shall be capable of imaging gases in the spectral range for the compound of highest concentration in the potential fugitive emissions. B. Monitoring equipment that meets U.S. EPA Method 21, 40 CFR Part 60, Appendix A. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 10 II.B.5.c.2 If fugitive emissions are detected at any time, the owner/operator shall repair the fugitive emissions component as soon as possible but no later than 30 calendar days after detection. [R307-401-8] II.B.5.c.3 The owner/operator shall resurvey the repaired or replaced fugitive emissions component no later than 30 calendar days after the fugitive emissions component was repaired. [R307-401-8] II.B.5.d The owner/operator shall maintain records of the fugitive emissions monitoring plan, monitoring surveys, repairs, and resurveys. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 11 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Supersedes DAQE-AN141770004-21 dated February 18, 2021 Is Derived From NOI dated May 15, 2024 REVIEWER COMMENTS 1. Comment regarding Emissions Estimates: The emissions estimates were calculated as follows: Unloading/loading of oil products by AP-42 Section 5.2 Storing asphalt, ATBs, and ACO in tanks by EPA Tanks version 5.0 (ACO is represented by the highest Reid vapor pressure crude oil in the emission calculations due it having a higher emissions potential, compared to ATB's or asphalt.) Flare device by AP-42 Section 13.5 Boiler operation by AP-42 Section 1.4 Equipment leaks by EPA-435/R-95-017 CO2e by AP-42 Table 1.4-2; and Part 98, Subpart A, Table A-1. [Last updated July 29, 2024] 2. Comment regarding NSPS and MACT: 40 CFR 60 (NSPS) 40 CFR 60 Subpart Dc applies to owners and operators of small industrial-commercial-institutional steam generating units (boilers) between 100 MMBtu/hr and 10 MMBtu/hr. This steam generating unit or boiler uses NG and the reporting is to document how much NG is used. Since this source will have three steam generators or boilers at 10 MMBtu/hr, NSPS Subpart Dc will apply to this plant. 40 CFR 60 Subpart Kb applies to owners and operators of organic liquid storage vessels greater than 75 m3 (with a vapor pressure greater than 15 kPa) and 151 m3 (with a vapor pressure greater than 3.5 kPa). This site has three storage tanks with 19,215 m3; therefore, Subpart Kb applies to this source. 40 CFR 60 Subpart VVa applies to owners and operators of equipment leaks in the synthetic organic chemicals manufacturing industry (SOCMI). The source does not manufacture any SOCMI with the asphalt or black wax crude oil it receives; therefore, this subpart doesn't apply to this source. 40 CFR 63 (MACT) 40 CFR 63 Subpart LLLLL applies to the asphalt processing and asphalt roofing manufacturing plants (at major sources of HAPs). This is an area source and therefore, Subpart LLLLL doesn't apply to this source. 40 CFR 63 Subpart JJJJJJ applies to industrial, commercial and institutional boilers at area sources. This subpart is for coal or fuel oil-firing of the boilers and the plant uses natural gas. Therefore, Subpart JJJJJJ doesn't apply to this source. 40 CFR 63 Subpart AAAAAAA applies to asphalt processing and asphalt roofing manufacturing plants (at minor sources of HAPs). This is an area source, but does not blow air through the asphalt; therefore, Subpart AAAAAAA does not apply to this source. [Last updated May 15, 2024] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 12 3. Comment regarding Title V Requirments: Title V of the 1990 Clean Air Act (Title V) applies to the following: 1. Any major source 2. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources; 3. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants. 4. Any Title IV affected source. This facility is not a major source and is not a Title IV source. The facility is subject to 40 CFR 60 (NSPS) and 40 CFR 63 (MACT) regulations. The facility is not subject to 40 CFR 61 (NESHAP) regulations. NSPS Subpart Dc, when natural gas is used, requires the maintenance of consumption records that support no consumption limit. NSPS Subpart Kb requires the source to maintain storage tank dimensions for the life of the tank. Title V does not apply because NSPS Subpart Dc and Kb have record keeping-only requirements. Recordkeeping requirements are not considered standards or limitations. There are no other reasons why this source would be required to obtain a part 70 permit; therefore, Title V does not apply to this facility. [Last updated May 15, 2024] 4. Comment regarding Use of EPA Tanks 5.0: In the existing AO, MSA used EPA Tanks 4.0b tool for the estimation of the VOC emissions from the Tooele asphalt, ATB, and ACO plant, with the result of 60.24 tpy. MSA has proposed to use EPA Tanks 5.0 tool for the estimation of the VOC emissions in the future AO. Use of EPA Tanks 5.0 will result in a VOC emissions rate of 31.18 tpy. [Last updated June 14, 2024] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal August 7, 2024 Page 13 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE- RN141770005 July 29, 2024 Gene Chrisenbery Mountain States Asphalt, Inc. PO Box 1268 Tooele, UT 84074 gene.msa@outlook.com Dear Gene Chrisenbery, Re: Engineer Review - Administrative Amendment to DAQE-AN141770004-21 to Update VOC Emissions from the Plant Project Number: N141770005 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review (NSR) permitting program. Mountain States Asphalt, Inc. should complete this review within 10 business days of receipt. Mountain States Asphalt, Inc. should contact Mr. Tim DeJulis at (385) 306-6523 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Mr. Tim DeJulis at tdejulis@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an Approval Order (AO) for signature by the DAQ Director. If Mountain States Asphalt, Inc. does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Mountain States Asphalt, Inc. has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature _____________________________________________________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N141770005 Owner Name Mountain States Asphalt, Inc. Mailing Address PO Box 1268 Tooele, UT, 84074 Source Name Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal Source Location 205 S. Emerald Rd. Tooele, UT 84074 UTM Projection 386,886 m Easting, 4,487,155 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 2951 (Asphalt Paving Mixtures & Blocks) Source Contact Gene Chrisenbery Phone Number (435) 659-1984 Email gene.msa@outlook.com Billing Contact Gene Chrisenbery Phone Number 435-659-1984 Email gene.msa@outlook.com Project Engineer Mr. Tim DeJulis, Engineer Phone Number (385) 306-6523 Email tdejulis@utah.gov Notice of Intent (NOI) Submitted May 15, 2024 Date of Accepted Application May 15, 2024 Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 2 SOURCE DESCRIPTION General Description Mountain States Asphalt, Inc. (MSA) receives asphalt, atmospheric tower bottoms (ATB), and other assorted crude oils (ACO) at the plant, located in Tooele, Tooele County, by train or truck. Thirty-six vertical fixed roof (VFR) tanks will store the asphalt, ATBs, or ACO. Thirty-one train/truck unloading/loading stations are in the plant. The emissions from the asphalt, ATB, or ACO unloading/loading and storage tanks will be controlled by a submerged filling system; vapor balancing system; and enclosed flare device. The asphalt is sold to third party customers to make asphalt paving materials at various locations throughout the area. The local petroleum refineries will use this terminal to store ATBs and ACO until they are ready to process it in their separate plants. The ATBs and ACO terminal will be capable of a throughput of 3,266,750 barrels (137,203,500 gallons) per rolling 12-month period. The production of asphalt will be capable of a throughput of 1,095,238 barrels (46,000,000 gallons) per rolling 12-month period. NSR Classification: Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA Tooele County Airs Source Size: SM Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), Dc: Standards of Performance for Small Industrial-Commercial-Institutional Steam Generating Units NSPS (Part 60), Kb: Standards of Performance for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid Storage Vessels) for Which Construction, Reconstruction, or Modification Commenced After July 23, 1984 Project Proposal Administrative Amendment to DAQE-AN141770004-21 to Update VOC Emissions from the Plant Project Description MSA has requested permission to update DAQE-AN141770004-21, dated February 18, 2021. MSA will use the latest EPA Tanks 5.0 to reduce the emissions of VOC to 31.18 tpy making it a minor ozone source. No other changes are being made to the plant. EMISSION IMPACT ANALYSIS This is an administrative amendment for an update of VOC emissions using Tanks 5.0. There is no increase in emissions associated with this update. Therefore, this amendment does not trigger the modeling requirements in R307-410-4 or R307-410-5. [Last updated July 29, 2024] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 3 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 6544.00 Carbon Monoxide 0 22.84 Nitrogen Oxides 0 15.21 Particulate Matter - PM10 0 1.26 Particulate Matter - PM2.5 0 0.12 Sulfur Dioxide 0 0.12 Sulfur Oxides 0.12 Volatile Organic Compounds -29.06 31.18 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 0 660 Ethyl Benzene (CAS #100414) 0 1300 Generic HAPs (CAS #GHAPS) 0 340 PAH, Total (CAS #234) 0 3260 Toluene (CAS #108883) 0 6500 Xylenes (Isomers And Mixture) (CAS #1330207) 0 6500 Change (TPY) Total (TPY) Total HAPs 0 9.28 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 4 Review of BACT for New/Modified Emission Units 1. BACT review regarding Process Equipment This is an administrative amendment for an update of VOC emissions using the EPA Tanks 5.0. A BACT analysis is not required for these administrative amendments. [Last updated July 29, 2024] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 5 SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 Distribution Terminal Asphalt, ATB's, and Crude Oil Distribution Terminal II.A.2 Primary Storage Tanks Four (4) vertical fixed roof tanks Capacity: 120,861 barrels each Service: asphalt Three (3) vertical fixed roof tanks Capacity: 83,932 barrels each Service: ATBs or assorted crude oils NSPS Subpart Kb II.A.3 Asphalt Blending Tanks Fifteen (15) vertical, fixed roof storage tanks Capacity: 38,000 barrels each Three (3) vertical, fixed roof storage tanks Capacity: 20,144 barrels each Four (4) vertical, fixed roof storage tanks Capacity: 6,855 barrels each Four (4) vertical, fixed roof storage tanks Capacity: 5,036 barrels each Ten (10) vertical, fixed roof storage tanks Capacity: 1,095 barrels each Twelve (12) vertical, fixed roof storage tanks Capacity: 895 barrels each II.A.4 Water or Latex Storage Tanks Seven (7) vertical, fixed roof storage tanks Capacity: 476 barrels each For information purpose only. II.A.5 Boilers Three (3) boilers Capacity: 10 MMBtu/hr each Fuel: natural gas NSPS Subpart Dc Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 6 II.A.6 Asphalt/Crude Oil Product Loading Racks Thirty-one (31) Unloading/Loading Racks Ten (10) rail car asphalt unloading/loading racks One (1) truck asphalt unloading rack Three (3) truck asphalt loading racks Two (2) truck asphalt emulsion loading racks Thirteen (13) rail car unloading/loading racks Two (2) truck unloading/loading racks Attached equipment: submerged filling and vapor capture system II.A.7 Flare Device Capacity: 9 MMBtu/hr Pilot light fuel is natural gas SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site Requirements II.B.1.a NEW Unless otherwise stated in this AO, the owner/operator shall not allow visible emissions to exceed the following: A. Haul roads and mobile equipment areas - 20% opacity B. Off property boundary - 10% opacity. [R307-401-8, R307-309-5] II.B.1.a.1 Unless otherwise stated, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.1.a.2 NEW Visible fugitive dust emissions from haul-road traffic and mobile equipment in operational areas shall not exceed the above opacity limit at any point. Visible emission determinations shall use procedures similar to Method 9. The normal requirement for observations to be made at 15-second intervals over a six-minute period, however, shall not apply. Visible emissions shall be measured at the densest point of the plume but at a point not less than 1/2 vehicle length behind the vehicle and not less than 1/2 the height of the vehicle. [R307-309-9] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 7 II.B.2 Roads and Fugitive Dust II.B.2.a NEW An electronic FDCP can be completed through the Utah DEQ Fugitive Dust Plan Permit Application Website. If a written FDCP is completed, it shall be submitted to the Director, attention: Compliance Branch, for approval. The owner/operator shall comply with the FDCP for control of all fugitive dust sources associated with the asphalt, ATBs or black wax crude oil terminal. [R307-309-6] II.B.2.b The owner/operator shall pave in-plant haul roads. The paved in-plant haul roads shall not be less than 0.50 miles in combined length. [R307-401-8] II.B.2.b.1 Compliance shall be determined through Global Positioning System (GPS) measurements or aerial photographs. [R307-401-8] II.B.2.c The owner/operator shall sweep, or spray clean the paved in-plant haul roads to maintain the opacity limits in this AO. [R307-309-6, R307-401-8] II.B.2.c.1 NEW Records of cleaning paved roads shall be kept for all periods the plant is in operation. The records shall include the following items: 1. Date of cleaning(s) 2. Time of day cleaning(s) were performed. [R307-309-6, R307-401-8] II.B.3 Loading Rack and Storage Tank Requirements II.B.3.a NEW The owner/operator shall not exceed the following limits: A. 1,095,238 barrels (46,000,000 gallons) of asphalt product throughput per rolling 12- month period B. 3,266,750 barrels (137,203,500 gallons) of ATBs, or ACO throughput per rolling 12- month period. [R307-401-8] II.B.3.a.1 NEW The owner/operator shall: A. Determine the asphalt product, ATB and ACO throughput by examination of company and/or customer billing records B. Record production on a daily basis C. Use the production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the asphalt product, ATB, and ACO throughput records for all periods the plant is in operation. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 8 II.B.3.b NEW The owner/operator shall not store any crude oil with an RVP greater than 11.2 psi. [R307-401-8] II.B.3.b.1 NEW The owner/operator shall: A. Record the RVP of the ACO each time the owner/operator changes to a new crude oil. B. Determine the RVP by the SDS records accompanying each rail car or tanker truck that arrives at the plant. C. Record the RVP for all periods when the plant is in operation. D. Record the RVP in a supervisor's log book. [R307-401-8] II.B.3.c The owner/operator shall load the tanker trucks and rail cars on site by the use of submerged loading. [R307-401-8] II.B.3.d The owner/operator shall control emissions from the loading racks and storage tanks that process the ATB or ACO, with a vapor capture system and flare device at all times. [R307-401-8] II.B.4 Flare and Fuel Requirements II.B.4.a The owner/operator shall only use natural gas as fuel in the boilers. [R307-401-8] II.B.4.b The owner/operator shall operate each flare device with a continuous pilot flame and be equipped with an auto-igniter. [R307-503-4] II.B.4.c The owner/operator shall operate each flare device with no visible emissions. [R307-401-8] II.B.4.c.1 Visual determination of emissions from each flare shall be conducted according to 40 CFR 60, Appendix A, Method 22. [R307-401-8] II.B.4.d The owner/operator shall install a flare device that has a certified control efficiency of 99%. [R307-401-8] II.B.4.d.1 To demonstrate compliance with the control efficiency, the owner/operator shall keep a record of the manufacturer's certification of the control efficiency. The record shall be kept for the life of the equipment. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 9 II.B.5 LDAR Requirements II.B.5.a The owner/operator shall develop a fugitive emissions monitoring plan for the storage tanks and flare operations. At a minimum, the plan shall include: A. Monitoring frequency B. Monitoring technique and equipment C. Procedures and timeframes for identifying and repairing leaks D. Recordkeeping practices E. Calibration and maintenance procedures. [R307-401-8] II.B.5.b The plan shall address monitoring for "difficult-to-monitor" and "unsafe-to-monitor" components. [R307-401-8] II.B.5.c Monitoring surveys shall be conducted according to the following schedule: A. No later than 60 days after startup of production, as defined in 40 CFR 60.5430a. B. Semiannually after the initial monitoring survey. Consecutive semiannual monitoring surveys shall be conducted at least 4 months apart. C. Annually after the initial monitoring survey for "difficult-to-monitor" components. D. As required by the owner/operator's monitoring plan for "unsafe-to-monitor" components. [R307-401-8] II.B.5.c.1 Monitoring surveys shall be conducted using one or both of the following to detect fugitive emissions: A. Optical gas imaging (OGI) equipment. OGI equipment shall be capable of imaging gases in the spectral range for the compound of highest concentration in the potential fugitive emissions. B. Monitoring equipment that meets U.S. EPA Method 21, 40 CFR Part 60, Appendix A. [R307-401-8] II.B.5.c.2 If fugitive emissions are detected at any time, the owner/operator shall repair the fugitive emissions component as soon as possible but no later than 30 calendar days after detection. [R307-401-8] II.B.5.c.3 The owner/operator shall resurvey the repaired or replaced fugitive emissions component no later than 30 calendar days after the fugitive emissions component was repaired. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 10 II.B.5.d The owner/operator shall maintain records of the fugitive emissions monitoring plan, monitoring surveys, repairs, and resurveys. [R307-401-8] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 11 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Supersedes DAQE-AN141770004-21 dated February 18, 2021 Is Derived From NOI dated May 15, 2024 REVIEWER COMMENTS 1. Comment regarding Emissions Estimates: The emissions estimates were calculated as follows: Unloading/loading of oil products by AP-42 Section 5.2 Storing asphalt, ATBs, and ACO in tanks by EPA Tanks version 5.0 (ACO is represented by the highest Reid vapor pressure crude oil in the emission calculations due it having a higher emissions potential, compared to ATB's or asphalt.) Flare device by AP-42 Section 13.5 Boiler operation by AP-42 Section 1.4 Equipment leaks by EPA-435/R-95-017 CO2e by AP-42 Table 1.4-2; and Part 98, Subpart A, Table A-1. [Last updated July 29, 2024] 2. Comment regarding NSPS and MACT: 40 CFR 60 (NSPS) 40 CFR 60 Subpart Dc applies to owners and operators of small industrial-commercial-institutional steam generating units (boilers) between 100 MMBtu/hr and 10 MMBtu/hr. This steam generating unit or boiler uses NG and the reporting is to document how much NG is used. Since this source will have three steam generators or boilers at 10 MMBtu/hr, NSPS Subpart Dc will apply to this plant. 40 CFR 60 Subpart Kb applies to owners and operators of organic liquid storage vessels greater than 75 m3 (with a vapor pressure greater than 15 kPa) and 151 m3 (with a vapor pressure greater than 3.5 kPa). This site has three storage tanks with 19,215 m3; therefore, Subpart Kb applies to this source. 40 CFR 60 Subpart VVa applies to owners and operators of equipment leaks in the synthetic organic chemicals manufacturing industry (SOCMI). The source does not manufacture any SOCMI with the asphalt or black wax crude oil it receives; therefore, this subpart doesn't apply to this source. 40 CFR 63 (MACT) 40 CFR 63 Subpart LLLLL applies to the asphalt processing and asphalt roofing manufacturing plants (at major sources of HAPs). This is an area source and therefore, Subpart LLLLL doesn't apply to this source. 40 CFR 63 Subpart JJJJJJ applies to industrial, commercial and institutional boilers at area sources. This subpart is for coal or fuel oil-firing of the boilers and the plant uses natural gas. Therefore, Subpart JJJJJJ doesn't apply to this source. 40 CFR 63 Subpart AAAAAAA applies to asphalt processing and asphalt roofing manufacturing plants (at minor sources of HAPs). This is an area source, but does not blow air through the asphalt; therefore, Subpart AAAAAAA does not apply to this source. [Last updated May 15, 2024] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 12 3. Comment regarding Title V Requirments: Title V of the 1990 Clean Air Act (Title V) applies to the following: 1. Any major source 2. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources; 3. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants. 4. Any Title IV affected source. This facility is not a major source and is not a Title IV source. The facility is subject to 40 CFR 60 (NSPS) and 40 CFR 63 (MACT) regulations. The facility is not subject to 40 CFR 61 (NESHAP) regulations. NSPS Subpart Dc, when natural gas is used, requires the maintenance of consumption records that support no consumption limit. NSPS Subpart Kb requires the source to maintain storage tank dimensions for the life of the tank. Title V does not apply because NSPS Subpart Dc and Kb have record keeping-only requirements. Recordkeeping requirements are not considered standards or limitations. There are no other reasons why this source would be required to obtain a part 70 permit; therefore, Title V does not apply to this facility. [Last updated May 15, 2024] 4. Comment regarding Use of EPA Tanks 5.0: In the existing AO, MSA used EPA Tanks 4.0b tool for the estimation of the VOC emissions from the Tooele asphalt, ATB, and ACO plant, with the result of 60.24 tpy. MSA has proposed to use EPA Tanks 5.0 tool for the estimation of the VOC emissions in the future AO. Use of EPA Tanks 5.0 will result in a VOC emissions rate of 31.18 tpy. [Last updated June 14, 2024] Engineer Review N141770005: Mountain States Asphalt, Inc.- Liquid Asphalt, ATB's, and Crude Oil Terminal July 29, 2024 Page 13 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds tankType tankIdentiflocation tankChar tankFit tankConte tanSolAbs petChem petDist {"tanTyp":" {"tankID":" {"loc":"Salt {"sheLen": {"accHatTy{"inputTyp {"sheCol":" {"annData"{"annData" ":{"chemName":"Asphalt Cement","vapMolWei":84,"liqMolWei":1000,"liqDen":8,"vapPreEquCon_A A":20.796,"vapPreEquCon_B":15032.54,"crudeOil":true},"monData":{}} customOrgcustomMixcustomPetcustomLocations {}{}{"Asphalt C {} Tank ID Tank Type Description City, State Company Emissions Type Annual Standing Losses (lb/yr) Tanks 1-4 Vertical Fixed Roof Tank Four (4) 5,000,000- Gallon Bulk Receiving Tanks - 2 Turnovers Per Year Tooele, Active Mountain States Asphalt Total VOC 1 Annual Working Losses (lb/yr) Annual Total Losses (lb/yr) 740 741 Notes Bulk Asphalt Cement Sorage Tanks 1-4. 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{"annData":{},{"annData":{"chemName":"Asphalt Cement","vapMolWei":84,"liqMolWei":1000,"liq {"annData":{},{"annData":{"chemName":"Asphalt Cement","vapMolWei":84,"liqMolWei":1000,"liq {"annData":{},{"annData":{"chemName":"Asphalt Cement","vapMolWei":84,"liqMolWei":1000,"liq {"annData":{},{"annData":{"chemName":"Asphalt Cement","vapMolWei":84,"liqMolWei":1000,"liq {"annData":{},{"annData":{"chemName":"Asphalt Cement","vapMolWei":84,"liqMolWei":1000,"liq qDen":8,"vapPreEquCon_A":20.796,"vapPreEquCon_B":15032.54,"crudeOil":true},"monData":{}} qDen":8,"vapPreEquCon_A":20.796,"vapPreEquCon_B":15032.54,"crudeOil":true},"monData":{}} qDen":8,"vapPreEquCon_A":20.796,"vapPreEquCon_B":15032.54,"crudeOil":true},"monData":{}} qDen":8,"vapPreEquCon_A":20.796,"vapPreEquCon_B":15032.54,"crudeOil":true},"monData":{}} qDen":8,"vapPreEquCon_A":20.796,"vapPreEquCon_B":15032.54,"crudeOil":true},"monData":{}} customOrgan customMixedcustomPetrol customLocations {}{}{"Asphalt Cem {} Estimates of Air Emissions from Asphalt Storage Tanks and Truck Loading David C. Trumbore Asphalt Technology Laboratory. Owens Corning, Summit, IL 60501 Title V of the 1990 Clean Air Act requires the accurate estimation of emissions processes, and places theburden rom all U.S. manufacturing of proof for that estimate on the process owner. This paper is published as a tool to assist in the estimation of air emissions from hot asphalt storage tanks and asphalt truck Loading operations. Data are presented on asphalt vapor pressure, vapor molecular weight, and the emission split between volatile organic compounds and particulate emissions that can be used with AP-42 calculation techniques to estimate air emissions from asphalt storage tanks and truck loading operations.Since current AP-42 techniques are not valid in asphalt tanks with active fume removal, a different technique for estimation of air emissions in those tanks, based on direct measurement of vapor space combustible gas content, is proposed. Likewise, since AP-42 does not address carbon monoxide or hydrogen sulfide emissions that are known to be present in asphalt operations, this paper proposes Finally, techniques for estimation of those emissions. data are presented on the effectiveness of fiber bed jilters in reducing air emissions in asphalt operations. INTRODUCTION The use of asphalt is prevalent throughout recorded history. It is produced in refinery distillation towers and solvent extraction units. Asphalt is modified by several means: reacting with oxygen in blowing operations to produce roofing asphalts, emulsifying to produce an aqueous liquid at ambient temperature, blending with solvents to make asphalt cutback, or blending or even reacting with polymers to make polymer modified asphalt. In all these cases the asphalt is stored in tanks, usually fixed roof tanks, and is loaded into trucks to ship to customers. Title V of the 1990 Clean Air Act required the accurate estimation of emissions from all U.S. manufacturing processes, and placed the burden of proof for that estimate on the process owner. In response to Title V, Owens Corning analyzed options for estimating emissions from 250 Winter 1999 asphalt tanks and loading operations and this paper is the result of that study. In particular, attempts have been made to develop data to be used with existing calculation methods to estimate air emissions in asphalt operations, to develop calculation schemes that work when existing methods cannot be used, and to expand the number of pollutants estimated. The techniques described in this paper have been used by Owens Corning to estimate asphalt emissions from their asphalt plants for many Title V permit applications. Owens Corning also evaluated appropriate emission factors for the asphalt blowing process and that analysis has been published [I]. The Emission Factor and Inventory Group in the U. S. Environmental Protection Agency’s (EPA) Office of Air Quality Planning and Standards develops and maintains a database of emission factors and a series of calculation methods for estimating air emissions from manufacturing processes. These emission factors are published in a series known as AP-42 [2]. One technique published in AP-42 calculates hydrocarbon emissions from a fixed roof tank storing petroleum products [3], and another calculates emissions for loading trucks with petroleum products [4]. These techniques require data on asphalt vapor pressure and the molecular weight of the -asphalt vapor. The calculations result in an estimate of the amount of hydrocarbons emitted from the process. To complete the emission estimate, these hydrocarbons need to be split into particulate emissions (PM) and volatile organic compounds (VOC), and any control device collection or destruction efficiencies need to be applied. In the AP-42 calculation of emissions from fixed roof tanks it is assumed that the motive force pushing vapor out of the tank comes from either the pumping of liquid into the tank or the expansion of tank contents due to temperature changes. For tanks with an active ventilation system this assumption is invalid and a different method of emission estimation is required. This is especially true if an air sweep is used to control the vapor space composition to Environmental Progress (Vol.18, No.4) No.4) prevent explosive conditions [5,6]. A technique to estimate emissions from these actively controlled tanks is described in the section of this paper on non AP-42 estimates. AP-42 EMISSION ESTIMATING TECHNIQUES FOR ASPHALT EQUIPMENT Passive vented hot asphalt tanks: AP-42 for fixed roof petroleum tanks can be used to calculate total hydrocarbon emissions from asphalt and oil tanks that are passively vented to the atmosphere. This AP-42 calculation, simply stated, determines the amount of hydrocarbon in the tank vapor space from the vapor pressure of the material in the tank at the liquid surface temperature, and then calculates the amount of vapor forced out of the tank due to liquid being actively pumped into the tank (working losses), or due to thermal expansion or contraction of tank contents driven by ambient temperature changes (breathing losses). The result is an actual weight of hydrocarbon emissions in a specified time period. A detailed description of the tank calculations is available from th e EPA web site [3]. The AP- 42 calculation requires a vapor pressure versus temperature curve for the asphalt, and also estimates of the vapor phase molecular weight and partition of hydrocarbons into VOC and particulate, in addition to process data like asphalt throughput. temperature. and tank level. If the tank passively breathes through a control device, then the appropriate control efficiency is applied to the VOC and particulate emissions calculated from AP-42. Hot Asphalt Loading: The AP-42 calculation for hydrocarbon emissions from truck or rail tank car loading of asphalt is done by estimating the amount of evaporation during the loading process. The estimate takes into account the turbulence and vapor liquid contact induced by the method of loading, i.e . submerged versus splash loading. The calculation result is an emission related to the number of tons of material loaded into the truck. Vapor pressure versus temperature c urve s,, temperature of loading, and throughputs are key variables in this calculation. Again, the hydrocarbon emission resulting from this calculation needs to be split into pa rticu latess and VOC s and control device collection and destruction efficiencies need to be applied. A detailed description of the loading calculations is available from the EPA web site [4]. DATA NEEDED FOR APPLICATION OF AP-42 TO ASPHALT EQUIPMENT Vapor Pressure: Information on asphalt vapor pressure as a function of temperature is not readily available in the literature and its measurement is not common. However, these data are essential to use AP-42 calculations for estimating asphalt tank and loading emissions. Asphalts from different crude oil sources and from different processes will differ in composition and vapor pressure. In the extreme, every residual material used in asphalt processing would need to be measured for vapor pressure at multiple temperatures. This would entail a prohibitive estimates. To provide a cost effective solution to this problem for its emission calculations, Owens Corning has Environmental Progress (Vol.18 , No.4) characterized the vapor pressure of three basic classes of asphalt materials. chosen by their processing history. An estimate of the vapor pressure of each asphalt class was made by measuring asphalts from multiple crude oil source s in each class and using the average vapor pressure at each temperature in a regression to generate one vapor pressure equation for tha t class. The three classes of asphalt chosen for this analysis follow. Flux asphalts. or vacuum tower bottoms that can be in the asphalt blowing process to make specification roofing asphalts. These materials generally have a higher vapor pressure than paving asphalts. Paving asphalts, or vacuum tower bottoms that meet paving specifications. Oxidized asphalt, or vacuum tower bottoms that have been reacted with oxygen in the asphalt blowing process to increase their softening point and viscosity. Typical softening points are greater than 190°F (88°C) These materials are also called air blown asphalts and are used extensively in the roofing industry. They generally have lower vapor pressure than the other two classes. Va por pressure measurements described in this paper were clone by the Phoenix Chemical Lab in Chicago using the Isoteniscope (ASTM D2879). To facilitate computer calculations it is desirable to develop an equation that accurately describes the relationship of vapor pressure and temperature. Thermodynamic treatment of the dependence of vapor pressure on temperature has led to the Clausius modification of the Clapeyron equation [7]. Clausius Clapeyron Treatment of Vapor Pressure Data In P = a + b/T Where: P is the equilibrium vapor pressure of the liquid in question, a & b are constants. and T is the absolute temperature of the liquid in question. Values of a & b depend on the choice of pressure and temperature units. Table 1 and Figure 1 give an example of the agreement of this equation with vapor pressure data for oxidized asphalts from 13 sources around the country. In Figure 1 , vapor pressure of each asphalt is plotted versus temperature to show each individual asphalt’s data to the Clausius Clapeyron rela tio ns hip .. The correlation coefficients in Table 1 indicate that the agreement of this equation to all individual asphalt vapor pressure ve rsus temperature data is excellent, with correlation coefficients for the individual asphalts greater than 0.9999. The agreement is also excellent for the individual asphalts making up the other two asphalt classes. Table 1 also presents the methodology to choose constants to use with the Winter 1999 251 amount of testing for minimal gain in accuracy of emission the differences between asphalt's data to the Clausius Clapeyron used Table l.Vapor Pressure Data for Oxidized Asphalts Temperature (°F1)All Data in mm Hg2 200 250 350 400 450 500 600 r value3 Plant A 0.39 2 7.9 26 77 550 Plant C 0.42 2 7.9 26 670 H 0.43 2 7.7 25 z: 180 165 410 590 Plant I 0.44 1.9 7.2 22 59 140 340 680 PlantK 0.43 1.7 6.1 18.5 50 115 205 510 680 PlantM 0.28 1.2 4.6 15 41 97 210 640 PlantN 0.19 0.88 3.5 12 34 85 190 430 590 PlantP 0.46 1.8 6 44 96 195 410 710 Plant0 0.11 0.47 1.7 13.2 34 74 142 Plant J 0.16 0.64 2.2 6.2 14.8 36 72 135 PlantS 0.28 1.05 3.3 9.4 23 50 105 200 350 PlantS 0.28 1 3.2 10 25 58 PlantX 0.1 0.4 1.5 4.7 12.5 33 75 152 Class Standard 0.22 0.91 3.2 9.5 24.9 58.8 127 254 351 477 Average 0.33 0.75 2.6 7.9 22.3 54.7 122 284 634 347 13459 b in Clausius Clapeyron curve for average vapor pressure data 1. 1 °C = (°F - 32) * 5/9 2. 1 Pa = 0.0075 mm Hg the r value is for the fit of the vapor pressure data to the Clausius Clapeyron Equation -0.999922929 -0.999934558 -0.999939281 -0.999945804 -0.999660554 -0.999948167 -0.999965421 -0.999948079 -0.999916578 -0.999838114 -0.999986213 -0.999875798 -0.999930649 -0.994026635 1000 100 FIGURE 1.Oxidized Asphalt Vapor Pressure Data in Clausius Clapeyron Format 9 10 11 12 13 14 16 Asphalt 300 550 575 225 400 460 5.2 17.5 Plant Vp 18.86 a in Clausius Clapeyron curve for average vapor pressure data 10,000 * 1/T (°R)2 15 0.1 Environmental Progress (Vol.18, No.4)252 Winter 1999 I II I A Plant A t I w-e I IIII I I A Plant H 0 Plant I x Plant K 0 Plant M + Plant N - Plant P - Plant 0 l Plant J m Plant S 1 0.1 2. 1 ° C = (° F-32)*5/9 I/I I A I . Temperature (°F2) 1000 FIGURE 2. Oxidized Asphalt Vapor Pressure Data in Double Log Format Clausius Clapeyron equation to calculate 3 representative vapor pressure at any temperature for the class of oxidized asphalts. Essentially the technique consists of averaging the vapor pressures of the 13 asphalts at each temperature and then using those averages to curve fit the data to the desired equation. This gives higher values and is more conservative than averaging the vapor pressures after the log transformation is made. The standard curve is developed by using this regression equation to calculate vapor pressures at different temperatures. and for the oxidized class that data is indicated in Table 1 and also by the straight line in Figure 1. The form of the Clausius Clapeyron equation is somewhat cumbersome to use, especially in graphical form, and so an alternative equation was developed which used a log/log relationship to characterize the data. Log Log Treatment of Vapor Pressure Data log Vp = A * log(T) + B Vp is the vapor pressure. T is the temperature (not absolute A & B are constants Analyses of oxidized asphalts using this equation to establish the standard curve are presented in Figure 2. The agreement is also very good. w ith correlation coefficients for the individual asphalts greater than 0.999. Again all three Class of Asphalt a Average n correlation coefficient Flux Paving Oxidized 18.2891 12725.60 10 -0.99976 20.7962 15032.54 8 -0.99985 18.8642 -0.99991 For a log log Equation log Vp (mm Hg) = A * log T (°F 3) + B Class of Asphalt a Average n correlation coefficient Flux 7.0850 -16.8999 10 0.99736 Paving 7.8871 -19.0600 8 0.99965 Oxidized 7.0607 -16.9570 13 0.99981 Table 2. Vapor Pressure Correlations for Asphalts For the Clausius Clapeyron Equation In Vp (mm Hg1) = a - b/T( R2 Environmental Progress (Vol.18, No.4)Winter 1999 253 13458.56 13 where 100 5 5 classes of asphalts show similar agreement, Pressure Summary: Table 2 gives a summary of the regression constants to be used in either of the equations discussed above to calculate the vapor pressure for the three classes of asphalt at any temperature. Also indicated are the number of asphalts that were used to develop the equation for each class. and the average correlation coefficient characterizing the agreement of the data to the form of the equation for each individual asphalt in the class. In AP-42 for tanks, the correct temperature to use in the Table 2 equations is the asphalt surface temperature in the tank. Since the surface temperature is rarely. if ever, known with certainty, the bulk temperature should be used to estimate emissions. In a well mixed tank the bulk temperature will be a good approximation of the surface temperature. Where mixing is not effective the surface will be lower in temperature than the bulk and the use of the bulk temperature will give a conservative estimate of emissions. In for loading trucks, the bulk temperature of the tank from which material is being loaded provides a good estimate of the actual loading temperature. Asphalt Vapor Molecular Weight: Asphalt vapor molecular weight was determined by separation and analysis of the organic species in the vapor spaces of 12 tanks storing different types of asphalt. These profiles were obtained by drawing known volumes of the tank vapor space through a charcoal tube, sealing and freezing the tube to limit loss of the sample, and then desorbing the organic material from the charcoal with carbon disulfide and analyzing with gas chromatography using packed columns and flame ionization detectors. Analyses were performed by CHEMIR Laboratory in St. Louis. Quantitative standards were used to identify the amount of individual normal alkanes from n-pentane to n- pentadecane. Peaks eluting between the normal alkanes were assumed to he isomers of the hordering alkanes, especially cyclic isomers of the lower carbon number alkane, and branched or unsaturated isomers of the higher carbon number alkane. The molecular weights for the n-alkane species and molecular weight estimates for the intermediate species were used with the amount of that material measured to calculate a weighted average vapor molecular weight for each tank, and then the twelve tanks were averaged together to get the molecular weight used for hot asphalt vapors in the AP-42 calculations. The result was a molecular weight of 84, which is used with all three classes of asphalts. This analysis is detailed in Table 3. Not enough data were available to assign different values to the three asphalt classes, however, from the table the unblown flux material in two tanks gave molecular weights which bracketed the average. as did the two paving blend stocks. This analysis gave a lower molecular weight for the vapor space of asphalt tanks than for several petroleum solvents and fuel oils. This seems like a contradiction considering the nature of asphalt as the residuum material collected upon distillation. This contradiction is resolved by considering that asphalt is not a uniform material chemically and that the lower molecular weight materials AP-42 Vapor Environmental Progress (Vol.18, No.4)254 Winter 1999 Table 4. PM/VOC Partition Data from Owens Corning Testing Asphalt Plant 0 Tank A Tank B Tank c VOC Test 0.73 PM Test 0.21 VOC Fraction 0.78 1.16 0.98 0.38 0.30 0.75 0.77 lb/hr1 lb/hr Koofing Plant S Coater Results: Measured at different points. Data indicated 22% of total emission (VOC + PM) was PM and 78% was VOC 1. 1 kg/sec = 0.0076 * lb/hr are preferentially evaporated More importantly. it has also been established that thermal cracking of asphalt in hot storage tanks creates low molecular weight materials which accumulate in the tank vapor spaces [5,6]. Asphalt Liquid Molecular Weight: The actual bulk asphalt molecular weight is not needed for AP-42 calculations of emissions from tanks or loading racks. but is useful in some calculations that are beyond the scope of this paper, for example using Raoult's law for crude estimates of emissions from mixtures of asphalt and other materials. Molecular weight of bulk asphalt is not a well defined material property, both because asphalt is such a complex mixture and because intermolecular interactions in the asphalt create the appearance of high molecular weight in many measurement techniques. The measured molecular weight is usually not truly representative of the covalently bonded molecules, The difficulty in getting accurate asphalt molecular weight measurements is extensively discussed in the literature [8, 9, 10]. The use of Gel Permeation Chromatography[8], Field-Ionization Mass Spectrometry [8]. Vapor Pressure Osmometry [8,9,10], and Freezing Point Depression [10] have all been evaluated as methods for measuring the molecular weight of asphalt or its components. The topic is further complicated for emission calculations by the fact that many of the measurements have been made on fractions of the asphalt and not on the neat asphalt. In general. for very rough estimates, a value of 1000 [8] can be used for the molecular weight of bulk asphalt. This value should be used with the understanding that there is much variation in the true molecular weight and in the tendency for intermolecular interaction due to petroleum crude source and processing conditions. Partition of hydrocarbon emissions that are particulate and VOC: Because of its heterogeneous nature, asphalt fumes are varied and may have components that are classified as condensed particulates (PM) or as volatile organic compounds (VOCs). It m-as evident in analyzing asphalt fume results that the difference between these two classes of criteria pollutants is really defined by the method used to test for the pollutants. Estimation schemes described in this paper calculate the sum of both (AP-42) or just the VOC component (non-AP-42 technique described below), and the partition needs to be understood to provide the best estimated values of the two pollutants. To that end. tests have been done on both asphalt tank exhausts in an Owens Corning asphalt plant and on the asphalt shingle coater exhausts in an Owens Corning roofing plant using EPA Methods 5 & 25A sampling protocols which define VOC and PM emissions in hydrocarbon fumes. Under conditions specified by the test method some fraction of the fume is captured on a filter and this is defined as a particulate emission, while a fraction of the hydrocarbon emission passes through the filter and this is defined as a VOC emission. The results of the split in the total hydrocarbon fume between VOC and particulate were approximately 78% VOC and 22% particulate in the asphalt equipment. in spite of the basic difference between a shingle coater and a storage tank. Data from these tests are given in Table 4. NON AP-42 CALCULATIONS TECHNIQUES: Estimation of VOC and particulate emissions from tanks with fume control: Many asphalt tanks have their fumes actively collected and treated in a control device, either a fiber bed filter or an incinerator. In these tanks it is common at Owens Corning to allow some air to pass through the tank vapor spaces to create an air sweep that controls combustible fumes well below the lower explosion limit (LEL) in order to prevent explosions. Because of the active removal of fumes in these systems, and the bleeding of air into the vapor space. the assumptions underlying the AP-42 tank calculations no longer apply. Specifically the driving force for the flow of fumes out of the tank is no longer just the working and breathing losses. and an alternative method of emission calculation is needed. Several years ago safety concerns with asphalt tanks prompted Owens Corning to institute the periodic measurement of the combustible gas concentration in all asphalt tank vapor spaces [5]. With the advent of Title V it was recognized that these measurements could be used to estimate VOC emissions. As part of the safety program. techniques were developed to make this routine measurement simple and easy. and the result was the use of Mine Safety Appliance (MSA) combustion meters to quantify the hydrocarbon concentration in terms of the fraction (or %) of the LEL. This technique and the validation of its accuracy has been described in detail in a separate publication [6]. In addition to the combustible gas measurement, a slightly more complicated technique is also described and validated that gives the concentration of ethane, methane. and other light combustible gases separate from propane and larger hydrocarbons. This technique involves using a charcoal tube in the line between the tank and the MSA meter. The charcoal tube adsorbs all propane and higher hydrocarbons [6], with the resultant reading at the MSA meter due only to the lighter Environmental Progress (Vol.18, No.4)Winter 1999 255 Table 5. Fraction of Measured Combustible Gas that is not VOC or Particulate Asphalt Type Number tanks measured Oxidized Unoxidized 109 47 Fraction combustible gas that is non-VOC/PM Average 0.52 0.23 Standard Deviation 0.12 0.23 materials. The charcoal tube technique was developed to troubleshoot excessive thermal cracking in asphalt tanks as a cause of high combustible gas levels in tank vapor spaces, and it is not routinely performed. It is important for emission calculations since the smaller combustibles found in the tank vapor spaces and measured with the charcoal tube in place (ethane, methane. hydrogen sulfide. and carbon monoxide) are not classified asVOCs because they do not react with ozone in the atmosphere. Nor are they particulate. The other hydrocarbons trapped by the tube and only measured when the charcoal tube is not present. are VOCs or particulate. Table 5 gives the results of testing of vapor spaces of oxidized and unoxidized asphalts for these two types of combustible gas measurements. This analysis was done to see if the routine combustible gas numbers should be adjusted for significant and predictable non-VOC/PM components. For the average tank storing oxidized asphalt. 52% of the combustible gas is non- VOC/PM anti this value n-as used for this class of asphalt. For unoxidized asphalts, both paving and flux,the non- VOC/PM % LEL varied widely and was not nearly as large a fraction of the total. For these asphalts, all of the combustible gas measurement was considered to be either VOC or particulate. Calculation of VOC & PM fromcombustible gas readings: Given this background the actual calculation of VOC emissions from combustion meter measurements is as follows: Combustion meter measurements from tank vapor spaces read in %LEL are adjusted for the fraction of that reading that is non-VOC/PM. This value depends on the type of asphalt in the tank. The adjusted %LEL is then turned into a weight per volume concentration. Hydrocarbons have a relatively constant actual LEL concentration. 45 mg/liter, when expressed on 3 weight per volume basis [11], and this constant is used to make this calculation. The weight per volume concentration from step 2 is multiplied by the fume removal flow (in volume/time) in the tank to get the VOC emission (n-eight/time) going to Calc CO = 142 l LEL + 800 8000 -II II 6000 -- 0 20 40 60 80 100 120 % LEL 256 Winter 1999 FIGURE 3. Relation of CO with % LEL Data for Oxidized Asphalts Environmental Progress (Vol.18, No.4) 2500 2000 1500 1000 500 0 I I I I 0 20 40 60 80 100 120 % LEL FIGURE 4. Relation of H2S with % LEL Data for Oxidized Asphalts a control device. It is consistent that the %LEL method measures VOC and not total hydrocarbon since the fume is drawn through a cotton filter prior to entering the combustion meter, and particulate will be filtered out. The particulate emission going to the control device is estimated from the constant ratio of 22%PM/78%VOC outlined in Table 4. The control device destruction efficiency is applied to both VOC and particulate emissions separately to get the final hydrocarbon based emissions from the tank. This is done after the calculation of PM emissions since the control efficiency for particulate and VOCs can be different depending on the control device. This methodology’s accuracy has been confirmed by tests in an Owens Corning asphalt plant on several Table 6. Owens Corning Tank Fume Sampling Results - VOC Emissions Tank A Tank B Tank C VOC Method 2jA Test 0.73 1.16 0.98 LEL Based Estimate 0.72 0.91 0.83 AP-42 Based Estimate 3.17 4.5 3.39 = 0.0076 *lb/hr passively vented tanks while material was pumped into the tank and vapors forced out by the known pumping rate. Emissions calculated with the method outlined above were compared to tank emissions calculated using AP-42 (valid in theory in this case due to the lack of a ventilation system), and to emissions measured using EPA Method 25A. As can be seen in Table 6 the method based on actual combustion meter tests is similar to the measured VOCs while AP-42 estimates are 3 to 5 times higher. Estimation of CO and H2S emissions from asphalt tanks: As part of the safety monitoring program mentioned above. Owens Corning has also used detector tubes in asphalt tanks to measure the vapor space concentration of carbon monoxide and hydrogen sulfide [6]. These emissions are usually ignored in asphalt tanks, however. the data Owens Corning has taken clearly indicates their presence in tank vapor spaces and therefore their emission [il. These gases are not routinely measured in Owens Corning asphalt tanks. unlike combustible gas measurements, and thus fresh data are not available for current calculation. nor are data available for every one of our tanks. To apply these data to all tanks. a surrogate measurement is necessary. Since the same mechanism, thermal cracking, that produces light hydrocarbons in asphalt tank vapor spaces also produces carbon monoxide and hydrogen sulfide, the periodic combustion meter measurement of tank vapor spaces was 4. 5. % 1. 1 kg/sec H2S ( p p m ) 3000 H2S Calc H2S Calc H2S = 12.43 * LEL + 400.5 Environmental Progress (Vol.18, No.4) Winter 1999 257 Table 7. Asphalt Plant 0: Tank Emissions of H2S and CO Tank A Tank B Tank C Data Actual Test % LEL based estimate 0.06 0.12 0.15 lb/hr1 0.19 0.18 0.20 lb/hr CO Data Actual Test % LEL based estimate 0.20 0.17 0.23 lb/hr 0.74 0.85 0.83 1. 1 kg/sec = 0.0076 * lb/hr investigated as a surrogate for CO and Data for CO and are plotted in Figures 3 and 4. Because of the scatter of data in the correlations a representative line was chosen for each material that was more conservative than nearly all of the data, in other words a line that defined a maximum concentration of CO and that could be expected in an asphalt tank from the combustion meter measurement. The equations used in the calculation of CO and concentrations from combustion meter results CO (ppm) = 142 *%LEL + 800 for oxidized asphalt = 12.43 *%LEL + 400.5 for oxidized asphalt In unoxidized asphalt no such correlation was seen and values of 500 ppm are used for both species. To estimate an emission from this correlation the CO and concentrations are multiplied by the flow out of the tank to get emissions. and conversion factors are used to transform this into a weight per time emission. Any control device destruction efficiency is then applied. The emissions using these techniques can be significant. Limited direct measurement in an Owens Corning asphalt plant was consistent with this approach. at least in so far as that the approach was conservative. was the closer of the two estimates. Data are presented in Table 7. One consequence of fume incineration is that one mole of in the fumes is oxidized to one mole of The amount of oxidized to SO, is the amount of generated minus both the amount that escapes at the source and the amount that is not incinerated at the control device. or in effect the total uncontrolled H2S emissions minus the emissions g after control. Because of the reaction with oxygen and the molecular weight differences between H2S and SO2, every pound (2.2 kg) of H2S emission is oxidized to 1.88 pounds (4.14 kg) of SO2 emission. LoadingRack emissions of CO and H2S: As in the tanks. %LEL versus CO and H2S correlations are used to estimate these components in loading rack emissions. Again, with incineration, the H2S is oxidized to SO2. Flow out of the tank truck during loading is needed for CO and H2S calculations. When fumes are collected, that flow can be either the more conservative flow induced by the fume fan, or the lower and more realistic displacement of air by the asphalt being loaded. When no collection takes place that flow is the displacement of air by asphalt being loaded. Combustion meter measurements of %LELs from the tanks for loading are used for these calculations. EFFECTIVENESS OF FIBER BED FILTERS FOR ASPHALT FUME EMISSION CONTROL One device used extensively to control asphalt fumes is a fiber bed filter. Fumes are actively pulled through these filters or passively hreathe through these filters. Their first use at Owens Corning was to control opacity to comply NSPS regulations, and for this application they have proven to he quite effective. Testing was done on both asphalt tanks and on a roofing line center to determine the control efficiency of fiber bed filters for both VOC and particulate emissions. Data from the testing are summarized in Table 8. In all cases. the particulate collection in the filter exceeded 90% of the emissions in the input stream. This value agrees well manufacturer’s estimate of 95% and with the observation that these devices can eliminate opacity. However, VOC removal varied widely in the tests. With the average removal near zero, and a very large variation, it decided that no removal of VOC by these filters could assumed. Although organic oil is collected. this oil is considered part of the particulate fraction of the hydrocarbons in the fumes and not the VOC fraction. Indeed the lack of removal of VOCs by these filters is consistent with the method of partitioning hydrocarbons into VOC and particulate described above -- namely VOCs pass through a testing filter and particulate do not. Based on the effectiveness of these control devices to eliminate opacity it is assumed that particulate greater than 10 micron is captured by the fiber bed filter so that the total particulate emissions from the fiber bed filter are to be PM10 emissions. Fiber bed filters are not considered to he a control device for CO and H2S in tank or loading rack fume streams. Table 8. Effectiveness of Fiber Bed Filters for Emission Control from Asphalt Tanks Equipment Pollutant Control Efficiency 0 Tank 1 Tank 57 Tank 1 Asphalt 0 0 Tank 1 0 57 Roofing I Coater 0 Asphalt 0 Asphalt 0 Asphalt 0 Tank 1 Total Particulate Tank 57 Total Particulate 90.7% Tank 1 Filterable Particulate 100.0% Filterable 100.0% H2S lb/br with used was with considered be Plant Asphalt Asphalt Asphalt Asphalt Tank VOC VOC VOC VOC VOC -35.7% 5.7% 43.4% 5.3% 0.0% 95.7% remaining H2S H2S H2S H2S H2S H2S H2S H2S H2S H2S SO2 %LEL conservative (ppm) 258 Winter 1999 Environmental Progress (Vol.18, No.4) Table 9. Summary of Data for Calculating Asphalt Tank Emissions Data Type Flux Asphalt Paving Asphalt Oxidized Asphalt Clausius Clapeyron constant a for vapor pressure 1 18.2891 20.7962 18.8642 Clausius Clapeyron constant b for vapor pressure 1 12725.6 15032.54 13458.56 Log Log constant A for vapor pressure 2 7.085 7.8871 7.0607 Log Log constant B for vapor pressure 2 -16.8999 -19.06 -16.957 Asphalt vapor molecular weight use 84 for all types of asphalt Asphalt liquid molecular weight very rough estimate - 1000 Partition of hydrocarbon fumes into particulate and VOC use 22% particulate, 78% VOC for all types % fumes that are VOC or particulate, versus non VOC/PM 100% 100% 48% Vapor space carbon monoxide (conservative estimate)ppm 500 500 142* % LEL + 800 Vapor space hydrogen sulfide (conservative estimate) ppm 500 500 12.43*%LEL + 400.5 Fiber bed filter control of VOC use 0% for all asphalt types Fibe4r bed filter control of particulate use 90% for all asphalt types 1.In Vp(mm Hg) = a + b/T(°R) 1 Pa = 0.0075mm Hg, 1 °K = (°R-492)*5/9 +273 2.log Vp (mm Hg) = A*log T(°F) + B 1 °C = (°F - 32)* 5/9 CONCLUSIONS Estimation of air emissions for asphalt tanks and loading racks can be done using AP-42 calculation methods given appropriate data on asphalt properties. More precise estimates of emissions, or estimates for tanks using ventilation schemes that compromise the AP-42 assumptions, can be done using a simple measurement of the combustible gas in the vapor space. Methods to do this are outlined in the paper. Data that is useful with all these methods are summarized in Table 9. These data are given for three major classes of asphalt: paving, flux and oxidized LITERATURE CITED 1. Trumbore, D.C., "The magnitude and source of air emissions from asphalt blowing operations," Environmental Progress,17, (1), pp. 53-59 (Spring 1998). 2. U.S.Environmental Protection Agency, "Introduction to 5th edition of AP-42 Emission Factors," U. S. EPA, January,1995,from the Internet at http://www.epa.gov/ ttn/chief/ap42.html (accessed May 14, 1998). 3. U.S Environmental Protection Agency, Chapter 7.1 of the 5th edition of AP-42 Emission Factors, U.S.EPA, "Organic Liquid Storage Tanks," September, 1997, from the Internet at http://www.epa.gov/ttn/chief/ap42.html (accessed May 14, 1998). 4. U.S.Envoironmental Protection Agency, Chapter 5.2 of the 5th edition of AP-42 Emission Factors, U.S. EPA, "Transportation and Marketing of Petroleum Liquids," January, 1995, from the Internet at http://www.epa.gov/ ttn/chief/ap42.html (accessed May 14, 1998). 5. Trumbore, D.C. and C.R.Wilkinson, "Better understanding needed for asphalt tank-explosion hazards," Oil Gas J., 87, pp.38-41 (September 18, 1989). 6. Trumbore, D.C., C.R.Wilkinson, and S.Wolfersberger, "Evaluation of techniques for in situ determination of explosion hazards in asphalt tanks," J.Loss Prev. Process Ind., 4, pp. 230-235 (July,1991). 7. Schmidt, A.X. and H.L. List, "Material and Energy Balance," Prentice Hall, Inc., Englewood Cliffs, New Jersey, pp. 40-41 (1962). 8. Boduszynski, M.M., "Asphaltenes in petroleum Asphalt: Composition and Formation," Chapter 7, in "The Chemistry of Asphaltenes," American Chemical Society, Washington, D.C., pp. 119-135 (1981). 9. Storm, D.A., et al., "Upper bound on number average molecular weight of asphaltenes," Fuel, 69, pp. 735-738 (June, 1990). 10. Speight, J.G., and S.E.Moschopedis, "Asphaltene molecular weights by a cryoscopic method," Fuel, 56, pp 344-345 (July, 1977). 11. Bodurtha, F.T., "Industrial Explosion Prevention and Protection," McGraw Hill, Inc, New york, New York, page 11 (1980). Environmental Progress (Vol.18, No.4) Winter 1999 259 RMEC PJ23E-4681 May 15, 2024 Bryce Bird Director Utah Division of Air Quality 195 North 1950 West P.O. Box 144820 Salt Lake City, Utah 84114-4820 SUBJECT: ADMINISTRATIVE AMENDMENT REQUEST RE: MOUNTAIN STATES ASPHALT, INC. – LIQUID ASPHALT, ATBS, AND CRUDE OIL TERMINAL (UDAQ Approval Order: DAQE-AN141770004-21) 205 South Emerald Road Tooele, UT 84074 Dear Mr. Bird: On behalf of Mountain States Asphalt, Inc. (MSA), RMEC Environmental, Inc. (RMEC) is hereby providing you with the following request for an administrative amendment of the above-referenced Approval Order (AO) with the Utah Division of Air Quality (UDAQ). The basis for this request is due to a recalculation of volatile organic compound (VOC) emissions associated with the facility’s asphalt cement (AC) storage operations. The outcome of these recalculations results in a significant reduction in facility- wide VOC emissions. RECALCULATION OF VOC EMISSIONS FROM AC STORAGE OPERATIONS Recently, the EPA released the final version of the TANKS 5.0 web program, which is a browser-based application that estimates volatile organic compound (VOC) and hazardous air pollutant (HAP) emissions from fixed- and floating-roof storage tanks. TANKS 5.0 is based on the most recent emission estimation procedures from Chapter 7 of EPA's Compilation of Air Pollutant Emission Factors (AP-42). An older, outdated version of the TANKS program was used for the initial NOI back in 2009. The facility’s current asphalt storage tanks and associated processing operations were the subject of the initial Notice of Intent (NOI) in 2009. As presented in the excerpts from the initial Notice of Intent (NOI) in 2009, provided herein as Attachment A, a total of 36.42 tons of VOC were attributed to the facility’s AC storage operations. While the facility has expanded operations to include storage of atmospheric tank bottoms (ATB) and assorted crude oils (ACO), the AC storage operations have remained unchanged since the 2009 NOI. A summary of the parameters used in the recalculation of the VOC emission in the TANKS 5.0 program are detailed in the following sections. Asphalt Cement Custom Petroleum Liquid Parameters Since AC is not one of the standard chemical inputs in the TANKS 5.0, AC emissions can be calculated by setting up a custom petroleum liquid using the following chemical properties as prescribed in AP-42, Chapter 11 Section 1.2.5: IDEQ-AQD RMEC PJ23E-4681 Page 2 of 3 May 15, 2024 ▪ Liquid Density (lb/gal): 8.0 ▪ Vapor Molecular Weight (lb/lb-mole): 105 ▪ Liquid Molecular Weight (lb/lb-mole): 1,000 ▪ Antoine’s Vapor Pressure Equation Constant A: 75,350.06 ▪ Antoine’s Vapor Pressure Equation Constant B (°R): 9.00346 Tank Data and AC Throughput MSA operates five (5) different types of AC storage tanks. Summaries of the characteristics of each tank type are provided in Attachment B. Information from the tank profile summary for each tank type was entered into the TANKS 5.0 program. A copy of the TANKS 5.0 base file containing MSA’s Tank Data is being transmitted with this email submission. A mix of these standard tank types are utilized within the following six (6) categories of AC product storage or processing: ▪ Primary Asphalt Storage Tanks ▪ Secondary Asphalt Storage Tanks ▪ Asphalt Sales Tanks ▪ Mill Feed Tanks ▪ Reaction Tanks ▪ Asphalt Emulsion Tanks Each category of AC storage along with tank dimensions, annual throughput and specific operational parameters, such as maximum fill height and target heating temperatures, are presented in the AC Storage Tank Profiles Summaries provided in the attached Table 1. This summary also includes the standing and working losses of VOCs for each tank type within each storage category. The VOC emissions were obtained by performing a loss run for each individual stage of AC product storage using the customized AC profile as the throughput for each tank type within the respective category. A copy of the TANKS 5.0 loss run output file and tank data file for each category is being transmitted with this email submission. SUMMARY OF NET CHANGE IN VOC EMISSIONS As previously discussed, the initial NOI allocated 36.42 tons of VOC emissions towards the AC storage operations. As indicated in Table 1, the recalculation of VOC emissions for AC storage operations yields a total of 7.36 tons of VOC emissions, resulting in a 29.06-ton reduction in the facility-wide VOC emissions. The proposed amendment of the AO would reduce the current AO limits for VOC emissions from 60.24 tons per year, to 31.18 tons per year. IDEQ-AQD RMEC PJ23E-4681 Page 3 of 3 May 15, 2024 CLOSING Please feel free to contact me or Gene Chrisenbery if you have any questions or concerns regarding this request. Gene can be reached at 435.659.1984 or by email at gene.msa@outlook.com. I can be reached at 801.467.3661 or by email at dhancock@rmec.net. Sincerely, Daryl Hancock, CHMM, CEM Principal Scientist RMEC ENVIRONMENTAL, INC. ATTACHMENTS: Attachment A – Excerpts from 2009 NOI Attachment B – Tank Characteristics Summaries Table 1 – Summary of AC Storage and Associated VOC Emissions TABLE 1 – SUMMARY OF AC STORAGE AND ASSOCIATED VOC EMISSIONS Shell Diameter Shell Height Max Fill Height Tank Working Volume Turnovers Per Year Annual Throughput Annual Standing Losses Annual Working Losses (feet)(feet)(gallons)(gallons)(lbs)(lbs)(lbs)(tons) 1 1 Primary Asphalt Storage Tank 120 60 58 4,906,952 2.00 9,813,904 2 1 Primary Asphalt Storage Tank 120 60 58 4,906,952 2.00 9,813,904 3 1 Primary Asphalt Storage Tank 120 60 58 4,906,952 2.00 9,813,904 4 1 Primary Asphalt Storage Tank 120 60 58 4,906,952 2.00 9,813,904 19,627,807 8 39,255,614 28 1,081 1,109 0.55 5 2 Secondary Asphalt Storage Tank 60 40 38 803,725 15.34 12,331,061 6 2 Secondary Asphalt Storage Tank 60 40 38 803,725 15.34 12,331,061 7 4 Secondary Asphalt Storage Tank 30 40 38 200,931 15.34 3,082,765 8 4 Secondary Asphalt Storage Tank 30 40 38 200,931 15.34 3,082,765 17 5 Secondary Asphalt Storage Tank 14 35 33 37,598 15.34 576,838 5 123 128 0.06 2,046,910 76.71 31,404,491 120 6,688 6,808 3.40 11 3 Asphalt Sales Tank 35 40 38 273,490 17.94 4,906,952 12 3 Asphalt Sales Tank 35 40 38 273,490 17.94 4,906,952 13 3 Asphalt Sales Tank 35 40 38 273,490 17.94 4,906,952 14 3 Asphalt Sales Tank 35 40 38 273,490 17.94 4,906,952 1,093,959 71.77 19,627,807 31 2,444 2,475 1.24 20 4 Mill Feed Tank 30 40 38 200,931 10.42 2,094,489 20 4 Mill Feed Tank 30 40 38 200,931 10.42 2,094,489 21 4 Mill Feed Tank 30 40 38 200,931 10.42 2,094,489 22 5 Mill Feed Tank 14 35 33 37,598 10.42 391,914 23 5 Mill Feed Tank 14 35 33 37,598 10.42 391,914 24 5 Mill Feed Tank 14 35 33 37,598 10.42 391,914 25 5 Mill Feed Tank 14 35 33 37,598 10.42 391,914 753,184 72.97 7,851,123 28 1,636 1,664 0.832 9 4 Reaction Tank 30 40 38 200,931 82.29 16,534,013 23 1,871 1,894 0.947 10 5 Reaction Tank 14 40 33 37,598 82.29 3,093,794 5 353 358 0.179 238,529 164.57 19,627,807 28 2,224 2,252 1.126 30 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 31 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 32 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 33 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 34 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 35 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 36 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 37 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 38 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 39 5 Asphalt Emulsion Tank 14 40 33 37,598 12.77 480,000 375,976 127.67 4,800,000 5 413 418 0.209 24,136,365 522 122,566,842 240 14,486 14,726 7.36 72,840 36.42 -58,114 -29.06 1 VOC emissions are based on EPA TANKS 5.0 ouput files for each tank type. TOTAL: 28 1,081 1,109 0.55 Asphalt Emulsion Tank Total: 92 5,252 5,344 2.67 23 1,313 1,336 Tank Type Tank Type Description VOC EMISSIONS1 Mill Feed Tank Total: 23 298 1,338 STORAGE TANKS Tank # 0.67 31 2,444 2,475 1.24 0.6805 303 0.1515 5 Total Annual Losses 413 418 0.209 NET CHANGE IN VOC EMISSIONS: TABLE 1: SUMMARY OF AC STORAGE AND ASSOCIATED VOC EMISSIONS MOUNTAIN STATE ASPHALT - TOOELE, UTAH FACILITY PRIOR VOC EMISSIONS FROM AC STORAGE OPERATIONS (2009 NOI): Primary Asphalt Storage Tank Total: Secondary Asphalt Storage Tank Total: Asphalt Sales Tank Total: Reaction Tank Total: 5 1,361 ATTACHMENT A – EXCERPTS FROM 2009 NOI Projected Emission Calculations Source: UNCONTROLLED EMISSION SUMMARY Company: Mountain States Asphalt Site: Tooele, Utah Date: April 2009 Uncontrolled in tons per year SOURCE PM10 PM2.s SO2 NOx co voe HAP Boilers 0.651 ND 0.08 12.51 10.51 0.69 0.24 Tanks 0.000 ND 0 0 0 36.425 0 Truck Loading 0.000 ND 0 0 0 7.24 0 Fugitive Emissions ND ND ND ND ND ND ND Unpaved Road Dust 2.762 0.000 0 0 0 0 0 Paved Road Dust ND ND 0 0 0 0 0 Total 3.413 0.000 0.080 12.510 10.510 44.355 0.240 Projected Emission Calculations Source: CONTROLLED EMISSION SUMMARY Company: Mountain States Asphalt Site: Tooele, Utah Date: April 2009 Controlled in tons per year SOURCE PM10 PM2s SO2 NOx co voe HAP Boilers 0.651 ND 0.080 12.510 10.510 0.690 0.240 Tanks 0.000 ND 0 0 0 36.425 0 Truck Loading 0.000 ND 0 0 0 7.240 0 Fugitive Emissions ND ND ND ND ND ND ND Unpaved Road Dust ND 0.000 0 0 0 0 0 Paved Road Dust 0.276 ND 0 0 0 0 0 Total 0.927 0.000 0.080 12.510 10.510 44.355 0.240 Petroleum Product Distribution Terminal Emissions (Fuel, Crude Oil, Asphalt) Mountain States Asphalt Tooele, Utah April 2009 46,000,000 0.6 0.43 84.25 860 0.3149265 = = = = = = or Annual throughput, tanker capacity in gallons s p M T Eff 0.000315 pounds per gallon VOC emissions from Tanker Loading 14486.6 pounds per year 7.24 tons per year Loading Losses LL s p M T Eff loading losses in pounds VOC per 1000 gallons saturation factor, AP-42 Chapter 5.2, Table 5.2 Reid vapor pressure of material, psia vapor molecular weight of material temperature of material in Rankine average control efficiency ATTACHMENT B – TANK CHARACTERSTICS SUMMARIES MSA Tank Type 1 Primary Asphalt Storage Tanks Tank Characteristics Tank Shape Cylinder Shell Height:60 feet Shell Diameter:120 feet Shell Capacity:5,076,157 gallons Tank Count 4 Combined Shell Capacity:20,304,628 gallons Maximum Liquid Height:58 feet Average Liquid Level Height:29 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:690 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:635 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 2 Asphalt Blending Tanks Tank Characteristics Tank Shape Cylinder Shell Height:40 feet Shell Diameter:60 feet Shell Capacity:846,026 gallons Tank Count 3 Combined Shell Capacity:2,538,078 gallons Maximum Liquid Height:38 feet Average Liquid Level Height:19 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 3 Asphalt Blending Tanks Tank Characteristics Tank Shape Cylinder Shell Height:40 feet Shell Diameter:35 feet Shell Capacity:287,884 gallons Tank Count 4 Combined Shell Capacity:1,151,536 gallons Maximum Liquid Height:38 feet Average Liquid Level Height:19 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 4 Primary Asphalt Storage Tanks Tank Characteristics Tank Shape Cylinder Shell Height:40 feet Shell Diameter:30 feet Shell Capacity:211,507 gallons Tank Count 4 Combined Shell Capacity:846,026 gallons Maximum Liquid Height:38 feet Average Liquid Level Height:19 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 5 Asphalt Blending Tanks Tank Shape Cylinder Height:40 feet Diameter:14 feet Shell Capacity:46,061 gallons Tank Count 12 Combined Shell Capacity:552,737 gallons Tank Count 4 Combined Shell Capacity:2,210,948 gallons Maximum Liquid Height:32.65 feet Average Liquid Level Height:16.325 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 1 Primary Asphalt Storage Tanks Tank Characteristics Tank Shape Cylinder Shell Height:60 feet Shell Diameter:120 feet Shell Capacity:5,076,157 gallons Tank Count 4 Combined Shell Capacity:20,304,628 gallons Maximum Liquid Height:58 feet Average Liquid Level Height:29 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:690 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:635 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 2 Asphalt Blending Tanks Tank Characteristics Tank Shape Cylinder Shell Height:40 feet Shell Diameter:60 feet Shell Capacity:846,026 gallons Tank Count 3 Combined Shell Capacity:2,538,078 gallons Maximum Liquid Height:38 feet Average Liquid Level Height:19 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 3 Asphalt Blending Tanks Tank Characteristics Tank Shape Cylinder Shell Height:40 feet Shell Diameter:35 feet Shell Capacity:287,884 gallons Tank Count 4 Combined Shell Capacity:1,151,536 gallons Maximum Liquid Height:38 feet Average Liquid Level Height:19 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 4 Primary Asphalt Storage Tanks Tank Characteristics Tank Shape Cylinder Shell Height:40 feet Shell Diameter:30 feet Shell Capacity:211,507 gallons Tank Count 4 Combined Shell Capacity:846,026 gallons Maximum Liquid Height:38 feet Average Liquid Level Height:19 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary MSA Tank Type 5 Asphalt Blending Tanks Tank Shape Cylinder Height:40 feet Diameter:14 feet Shell Capacity:46,061 gallons Tank Count 12 Combined Shell Capacity:552,737 gallons Tank Count 4 Combined Shell Capacity:2,210,948 gallons Maximum Liquid Height:32.65 feet Average Liquid Level Height:16.325 feet Tank Bottom Type:Flat Liquid Heel Type at Tank Minimum:None Vapor Space Pressure at Normal Operating Conditions:12.64 default Insulated:Fully Insulated Heated:Yes Typical Max Liquid Bulk Temperature in Heating Cycle:790 degrees R Typical Avg. Liquid Bulk Temperature in Heating Cycle:668 degrees R Typical Minimum Liquid Bulk Temperature in Heating Cycle:530 degrees R Number of Heat Cycles per Year:1 Shell Characteristics Shell Color/Shade:Aluminum - Mill finish, unpainted Shell Condition:Average Roof Characteristics Roof Color/Shade:Aluminum - Specular Roof Condition:Average Roof Type:Cone Tank Cone Roof Slope (ft/ft)0.05 Breather Vent Settings Vaccum Setting:0.00 (atmospheric)psig Pressure Setting:0.00 (atmospheric)psig Control Device Settings Is Tank Equiped with a Control Device?:No Control Device AC Storage Tank Profile Summary TANK Type 11 March April May June July August (lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(tons) Standing Losses 174 187 212 214 221 211 Working Losses 4989 4989 4989 4989 4989 4989 Total Losses 5163 5176 5201 5203 5210 5200 31,153 15.6 TANK Type 2 March April May June July August (lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(tons) Standing Losses 71 77.3 88 89 92 87 Working Losses 3563 3563 3563 3563 3563 3563 Total Losses 3634 3640.3 3651 3652 3655 3650 21,882 10.9 TANK Type 3 March April May June July August (lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(tons) Standing Losses 12 13 15 15 15 15 Working Losses 1511 1511 1511 1511 1511 1511Total Losses 1523 1524 1526 1526 1526 1526 9,151 4.6 TANK Type 4 March April May June July August (lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(lbs)(tons) Standing Losses 16 18 20 20 21 20 Working Losses 1758 1758 1758 1758 1758 1758Total Losses 1774 1776 1778 1778 1779 1778 10,663 5.3 (lbs)(tons) 72,849 36.42 Total: GRAND TOTAL: SUMMARY OF ASPHALT EMISSIONS - MOUNTAIN STATES INITIAL NOI (2009) Total: Total: Total: Total: