DAQ-2024-010576

DAQE-AN119040015-24

{{$d1 }}

Bradley Smith
RR Donnelley and Sons Company
630 West 1000 North
Logan, UT 84321-9175
[e-mail]

Dear Mr. Smith:

Re: Approval Order: Modification to Approval Order DAQE-AN119040014-19 to Add Four (4)
Inkjet Printers
Project Number: N119040015

The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on June 4,
2024. RR Donnelley and Sons Company must comply with the requirements of this AO, all applicable
state requirements (R307), and Federal Standards.

The project engineer for this action is Christine Bodell, who can be contacted at [phone] or
[e-mail]. Future correspondence on this AO should include the engineer's name as well as the
DAQE number shown on the upper right-hand corner of this letter. No public comments were received on
this action.

Sincerely,

{{$s }}

Bryce C. Bird
Director

BCB:CB:jg

cc: Bear River Health Department

195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone [phone] • Fax [phone] • T.D.D. [phone]
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah

SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor

Department of
Environmental Quality

Kimberly D. Shelley
Executive Director

DIVISION OF AIR QUALITY
Bryce C. Bird
Director

August 21, 2024

STATE OF UTAH
Department of Environmental Quality
Division of Air Quality

{{#s=Sig_es_:signer1:signature}}
{{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}}
{{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}}

APPROVAL ORDER
DAQE-AN119040015-24
Modification to Approval Order DAQE-AN119040014-19 to Add
Four (4) Inkjet Printers

Prepared By
Christine Bodell, Engineer
[phone]
[e-mail]

Issued to
Logan Printing Plant

Issued On
{{$d2 }}

Issued By

{{$s }}

Bryce C. Bird
Director
Division of Air Quality

August 21, 2024
TABLE OF CONTENTS

TITLE/SIGNATURE PAGE ....................................................................................................... 1
GENERAL INFORMATION ...................................................................................................... 3
CONTACT/LOCATION INFORMATION ............................................................................... 3
SOURCE INFORMATION ........................................................................................................ 3
General Description ................................................................................................................ 3
NSR Classification .................................................................................................................. 3
Source Classification .............................................................................................................. 3
Applicable Federal Standards ................................................................................................. 3
Project Description.................................................................................................................. 3
SUMMARY OF EMISSIONS .................................................................................................... 4
SECTION I: GENERAL PROVISIONS .................................................................................... 4
SECTION II: PERMITTED EQUIPMENT .............................................................................. 5
SECTION II: SPECIAL PROVISIONS ..................................................................................... 6
PERMIT HISTORY ..................................................................................................................... 8
ACRONYMS ................................................................................................................................. 9

DAQE-AN119040015-24
Page 3

GENERAL INFORMATION

CONTACT/LOCATION INFORMATION

Owner Name Source Name
RR Donnelley and Sons Company Logan Printing Plant

Mailing Address Physical Address
630 West 1000 North 630 West 1000 North
Logan, UT 84321-9175 Logan, UT 84321-9175

Source Contact UTM Coordinates
Name: Bradley Smith 429,175 m Easting
Phone: [phone],622,303 m Northing
Email: [e-mail] Datum NAD83
UTM Zone 12
SIC code 2759 (Commercial Printing, NEC)

SOURCE INFORMATION
General Description
RR Donnelley and Sons Company (RR Donnelley) owns and operates a printing plant that manufactures
business forms and direct mailing pieces in Logan, Cache County. The plant consists of seventeen (17)
digital, high-speed inkjet printers. Waste paper from this operation is sent through a cyclone, where it is
shredded and baled. The bales are sent offsite for recycling.

NSR Classification
Minor Modification at Minor Source

Source Classification
Located in Attainment Area
Cache County
Airs Source Size: B

Applicable Federal Standards
MACT (Part 63), A: General Provisions
MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for
Stationary Reciprocating Internal Combustion Engines

Project Description
RR Donnelley is requesting to add four (4) digital printers to Approval Order DAQE-AN119040014-19.
RR Donnelley is not requesting to increase the VOC and HAPs limits outlined in Condition II.B.2.a. The
new digital printers will operate under the existing limitations outlined in Condition II.B.2.a. The new
DAQE-AN119040015-24
Page 4

printers will utilize ink that does not contain any HAP emissions except for glycol ethers, which is also
limited in Condition II.B.2.a. Therefore, no annual emissions are increasing.

RR Donnelley is currently permitted to operate fourteen (14) digital printers. However, only thirteen (13)
were installed at the time of this modification request. The addition of four (4) new digital printers results
in a new site-wide total of seventeen (17) printers.

SUMMARY OF EMISSIONS

The emissions listed below are an estimate of the total potential emissions from the source. Some
rounding of emissions is possible.

Criteria Pollutant Change (TPY) Total (TPY)
CO2 Equivalent 0 9097.80
Carbon Monoxide 0 6.55
Nitrogen Oxides 0 4.71
Particulate Matter - PM10 0 5.56
Particulate Matter - PM2.5 0 5.56
Sulfur Dioxide 0 0.52
Volatile Organic Compounds 0 18.78

Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr)
Acetaldehyde (CAS #75070) 0 800
Ethylene Glycol (CAS #107211) 0 2760
Formaldehyde (CAS #50000) 0 800
Glycol Ethers (CAS #EDF109) 0 1400
Methanol (CAS #67561) 0 800
Toluene (CAS #108883) 0 4880
Vinyl Acetate (CAS #108054) 0 800
Xylenes (Isomers And Mixture) (CAS #1330207) 0 3340
Change (TPY) Total (TPY)
Total HAPs 0 7.79

SECTION I: GENERAL PROVISIONS

I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]
I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1]
DAQE-AN119040015-24
Page 5

I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO,
including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to
the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4]

I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107]
I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150]

I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18]

SECTION II: PERMITTED EQUIPMENT
II.A THE APPROVED EQUIPMENT II.A.1 Logan Printing Plant
II.A.2 Production Laser Printers Print onto paper using toner. Listed for informational purposes only II.A.3 High-Volume Inserting System Mechanically inserts statements into envelopes. Listed for informational purposes only
II.A.4 Seventeen (17) Digital Printers (Four (4) New) Digital, high-speed, continuous-feed inkjet printers. II.A.5 Book Binders Perfect binders and mechanical binders Listed for informational purposes only
II.A.6 Suction & Trim System One (1) cyclone Rating: 66,000 cubic feet per minute
DAQE-AN119040015-24
Page 6

II.A.7 Welding Section Listed for informational purposes only II.A.8 Various Boilers and Heaters Rating: < 5 MMBtu/hr each
Fuel: Natural gas
II.A.9 Emergency Generator Engine Max Engine Rating: 600 kW (805 HP) Model Year: 2000 Fuel: Diesel MACT Applicability: 40 CFR 63 Subpart ZZZZ

SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS
II.B.1 Source-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. Emergency generator engine - 20% opacity. B. All other points or fugitive emission sources - 5% opacity. [R307-401-8]
II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8]

II.B.1.b The owner/operator shall comply with all applicable requirements of UAC R307-304 (Solvent Cleaning). [R307-304]
II.B.2 VOC and HAP Requirements
II.B.2.a The owner/operator shall not emit more than the following from evaporative sources (i.e., printing, coating, and/or cleaning). A. 18.78 tons per rolling 12-month period for VOCs. B. 1.38 tons per rolling 12-month period for Ethylene Glycol. C. 0.68 tons per rolling 12-month period for Glycol Ethers. D. 1.67 tons per rolling 12-month period for Xylene. E. 2.44 tons per rolling 12-month period for Toluene. F. 0.40 tons per rolling 12-month period for Formaldehyde. G. 0.40 tons per rolling 12-month period for each individual HAP not listed. H. 7.79 tons per rolling 12-month period for all HAPs combined. [R307-401-8]
DAQE-AN119040015-24
Page 7

II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance/material-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance material balance method: VOC = [% VOC by weight/100] x [Density] x [Volume Consumed]. HAP = [% HAP by weight/100] x [Density] x [Volume Consumed]. [R307-401-8] II.B.2.a.2 The owner/operator shall maintain records each month of the following for VOC- and/or HAP-emitting materials:
A. The name (i.e., material identifier) and type (i.e., ink, solvent) of the VOC- and/or
HAP-emitting material.
B. The maximum percent by weight of VOC and each HAP in each material used.

C. The density of each material used.
D. The volume of each material used.
E. The amount of VOC and of each HAP emitted monthly by each material used.

F. The total amount of VOC, of each HAP, and of all HAPs combined emitted from all materials (in tons).

[R307-401-8]
II.B.3 Emergency Generator Engine Requirements
II.B.3.a The owner/operator shall not operate the emergency generator engine on site for more than 100
hours per rolling 12-month period for maintenance checks and readiness testing. There is no time limit on the use of the engine during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8]

II.B.3.a.1 To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. Records documenting the operation of the emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used. B. The duration of operation in hours. C. The reason for the emergency engine usage. [40 CFR 63 Subpart ZZZZ, R307-401-8]
II.B.3.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour
meter on the emergency generator engine on site. [R307-401-8]

II.B.4 Fuel Requirements
II.B.4.a The owner/operator shall only use diesel fuel (fuel oil #1, #2, or diesel fuel oil additives) as fuel
in the emergency generator engine. [40 CFR 63 Subpart ZZZZ]

DAQE-AN119040015-24
Page 8

II.B.4.b The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.b.1 To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain
records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8]

PERMIT HISTORY

This Approval Order shall supersede (if a modification) or will be based on the following documents:
Supersedes AO DAQE-AN119040014-19 dated February 22, 2019 Is Derived From NOI dated June 4, 2024
DAQE-AN119040015-24
Page 9

ACRONYMS

The following lists commonly used acronyms and associated translations as they apply to this document:

40 CFR Title 40 of the Code of Federal Regulations
AO Approval Order
BACT Best Available Control Technology
CAA Clean Air Act
CAAA Clean Air Act Amendments
CDS Classification Data System (used by Environmental Protection Agency to classify
sources by size/type)
CEM Continuous emissions monitor
CEMS Continuous emissions monitoring system
CFR Code of Federal Regulations
CMS Continuous monitoring system
CO Carbon monoxide
CO2 Carbon Dioxide
CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98,
Subpart A, Table A-1
COM Continuous opacity monitor
DAQ/UDAQ Division of Air Quality
DAQE This is a document tracking code for internal Division of Air Quality use
EPA Environmental Protection Agency
FDCP Fugitive dust control plan
GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i)
GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818-
12(a)
HAP or HAPs Hazardous air pollutant(s)
ITA Intent to Approve
LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent
NOx Oxides of nitrogen
NSPS New Source Performance Standard
NSR New Source Review
PM10 Particulate matter less than 10 microns in size
PM2.5 Particulate matter less than 2.5 microns in size
PSD Prevention of Significant Deterioration
PTE Potential to Emit
R307 Rules Series 307
R307-401 Rules Series 307 - Section 401
SO2 Sulfur dioxide
Title IV Title IV of the Clean Air Act
Title V Title V of the Clean Air Act
TPY Tons per year
UAC Utah Administrative Code
VOC Volatile organic compounds

DAQE-IN119040015-24

July 18, 2024

Bradley Smith
RR Donnelley and Sons Company
630 West 1000 North
Logan, UT 84321-9175
[e-mail]

Dear Mr. Smith:

Re: Intent to Approve: Modification to Approval Order DAQE-AN119040014-19 to Add Four (4)
Inkjet Printers
Project Number: N119040015

The attached document is the Intent to Approve (ITA) for the above-referenced project. The ITA is
subject to public review. Any comments received shall be considered before an Approval Order (AO) is
issued. The Division of Air Quality is authorized to charge a fee for reimbursement of the actual costs
incurred in the issuance of an AO. An invoice will follow upon issuance of the final AO.

Future correspondence on this ITA should include the engineer's name, Christine Bodell, as well as the
DAQE number as shown on the upper right-hand corner of this letter. Christine Bodell, can be reached at
[phone] or [e-mail], if you have any questions.

Sincerely,

{{$s }}

Alan D. Humpherys, Manager
New Source Review Section

ADH:CB:jg

cc: Bear River Health Department

195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone [phone] • Fax [phone] • T.D.D. [phone]
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah

SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor

Department of
Environmental Quality

Kimberly D. Shelley
Executive Director

DIVISION OF AIR QUALITY
Bryce C. Bird
Director

STATE OF UTAH
Department of Environmental Quality
Division of Air Quality

INTENT TO APPROVE
DAQE-IN119040015-24
Modification to Approval Order DAQE-AN119040014-19
to Add Four (4) Inkjet Printers

Prepared By
Christine Bodell, Engineer
[phone]
[e-mail]

Issued to
Logan Printing Plant

Issued On
July 18, 2024

{{$s }}

New Source Review Section Manager
Alan D. Humpherys
{{#s=Sig_es_:signer1:signature}}

TABLE OF CONTENTS

TITLE/SIGNATURE PAGE ....................................................................................................... 1
GENERAL INFORMATION ...................................................................................................... 3
CONTACT/LOCATION INFORMATION ............................................................................... 3
SOURCE INFORMATION ........................................................................................................ 3
General Description ................................................................................................................ 3
NSR Classification .................................................................................................................. 3
Source Classification .............................................................................................................. 3
Applicable Federal Standards ................................................................................................. 3
Project Description.................................................................................................................. 3
SUMMARY OF EMISSIONS .................................................................................................... 4
PUBLIC NOTICE STATEMENT............................................................................................... 4
SECTION I: GENERAL PROVISIONS .................................................................................... 5
SECTION II: PERMITTED EQUIPMENT .............................................................................. 5
SECTION II: SPECIAL PROVISIONS ..................................................................................... 6
PERMIT HISTORY ..................................................................................................................... 8
ACRONYMS ................................................................................................................................. 9

DAQE-IN119040015-24
Page 3

GENERAL INFORMATION

CONTACT/LOCATION INFORMATION

Owner Name Source Name
RR Donnelley and Sons Company Logan Printing Plant

Mailing Address Physical Address
630 West 1000 North 630 West 1000 North
Logan, UT 84321-9175 Logan, UT 84321-9175

Source Contact UTM Coordinates
Name: Bradley Smith 429,175 m Easting
Phone: [phone],622,303 m Northing
Email: [e-mail] Datum NAD83
UTM Zone 12
SIC code 2759 (Commercial Printing, NEC)

SOURCE INFORMATION
General Description
RR Donnelley and Sons Company (RR Donnelley) owns and operates a printing plant that manufactures
business forms and direct mailing pieces in Logan, Cache County. The plant consists of seventeen (17)
digital, high-speed inkjet printers. Waste paper from this operation is sent through a cyclone, where it is
shredded and baled. The bales are sent offsite for recycling.
NSR Classification
Minor Modification at Minor Source

Source Classification
Located in Attainment Area
Cache County
Airs Source Size: B

Applicable Federal Standards
MACT (Part 63), A: General Provisions
MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for
Stationary Reciprocating Internal Combustion Engines

Project Description
RR Donnelley is requesting to add four (4) digital printers to Approval Order DAQE-AN119040014-19.
RR Donnelley is not requesting to increase the VOC and HAPs limits outlined in Condition II.B.2.a. The
new digital printers will operate under the existing limitations outlined in Condition II.B.2.a. The new
printers will utilize ink that does not contain any HAP emissions except for glycol ethers, which is also
DAQE-IN119040015-24
Page 4

limited in Condition II.B.2.a. Therefore, no annual emissions are increasing.

RR Donnelley is currently permitted to operate fourteen (14) digital printers. However, only thirteen (13)
were installed at the time of this modification request. The addition of four (4) new digital printers results
in a new site-wide total of seventeen (17) printers.

SUMMARY OF EMISSIONS

The emissions listed below are an estimate of the total potential emissions from the source. Some
rounding of emissions is possible.

Criteria Pollutant Change (TPY) Total (TPY)
CO2 Equivalent 0 9097.80
Carbon Monoxide 0 6.55
Nitrogen Oxides 0 4.71
Particulate Matter - PM10 0 5.56
Particulate Matter - PM2.5 0 5.56
Sulfur Dioxide 0 0.52
Volatile Organic Compounds 0 18.78

Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr)
Acetaldehyde (CAS #75070) 0 800
Ethylene Glycol (CAS #107211) 0 2760
Formaldehyde (CAS #50000) 0 800
Glycol Ethers (CAS #EDF109) 0 1400
Methanol (CAS #67561) 0 800
Toluene (CAS #108883) 0 4880
Vinyl Acetate (CAS #108054) 0 800
Xylenes (Isomers And Mixture) (CAS #1330207) 0 3340
Change (TPY) Total (TPY)
Total HAPs 0 7.79

PUBLIC NOTICE STATEMENT

The NOI for the above-referenced project has been evaluated and has been found to be consistent with the requirements of UAC R307. Air pollution producing sources and/or their air control facilities may not be constructed, installed, established, or modified prior to the issuance of an AO by the Director. A 30-day public comment period will be held in accordance with UAC R307-401-7. A notification of the intent to approve will be published in The Herald Journal on July 20, 2024. During the public comment period the proposal and the evaluation of its impact on air quality will be available for the public to review and provide comment. If anyone so requests a public hearing within 15 days of publication, it will be held in accordance with UAC R307-401-7. The hearing will be held as close as practicable to the location of the source. Any comments received during the public comment period and the hearing will be evaluated. The proposed conditions of the AO may be changed as a result of the comments received.

DAQE-IN119040015-24
Page 5

SECTION I: GENERAL PROVISIONS

The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO.

I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101]
I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]

I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1]
I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by
the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request.
Unless otherwise specified in this AO or in other applicable state and federal rules, records
shall be kept for a minimum of two (2) years. [R307-401-8]
I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4]
I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns.
[R307-107]
I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150]
I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if
construction is not commenced within 18 months from the date of this AO or if construction is
discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18]

SECTION II: PERMITTED EQUIPMENT

The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO.
II.A THE APPROVED EQUIPMENT

II.A.1 Logan Printing Plant
DAQE-IN119040015-24
Page 6

II.A.2 Production Laser Printers Print onto paper using toner. Listed for informational purposes only. II.A.3 High-Volume Inserting System
Mechanically inserts statements into envelopes. Listed for informational purposes only.
II.A.4 Seventeen (17) Digital Printers (Four (4) New) Digital, high-speed, continuous feed, inkjet printers. II.A.5 Book Binders
Perfect binders and mechanical binders. Listed for informational purposes only.
II.A.6 Suction & Trim System One (1) cyclone Rating: 66,000 cubic feet per minute
II.A.7 Welding Section Listed for informational purposes only.

II.A.8 Various Boilers and Heaters Rating: < 5 MMBtu/hr each Fuel: Natural gas
II.A.9 Emergency Generator Engine Max Engine Rating: 600 kW (805 HP)
Model Year: 2000
Fuel: Diesel MACT Applicability: 40 CFR 63 Subpart ZZZZ

SECTION II: SPECIAL PROVISIONS

The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.B REQUIREMENTS AND LIMITATIONS II.B.1 Source-Wide Requirements
II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. Emergency generator engine - 20% opacity. B. All other points or fugitive emission sources - 5% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8]
DAQE-IN119040015-24
Page 7

II.B.1.b The owner/operator shall comply with all applicable requirements of UAC R307-304 (Solvent Cleaning). [R307-304] II.B.2 VOC and HAP Requirements
II.B.2.a The owner/operator shall not emit more than the following from evaporative sources (i.e., printing, coating, and/or cleaning). A. 18.78 tons per rolling 12-month period for VOCs. B. 1.38 tons per rolling 12-month period for Ethylene Glycol. C. 0.68 tons per rolling 12-month period for Glycol Ethers. D. 1.67 tons per rolling 12-month period for Xylene. E. 2.44 tons per rolling 12-month period for Toluene. F. 0.40 tons per rolling 12-month period for Formaldehyde. G. 0.40 tons per rolling 12-month period for each individual HAP not listed. H. 7.79 tons per rolling 12-month period for all HAPs combined. [R307-401-8] II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using
data from the previous 12 months. The owner/operator shall use a mass-balance/material-balance
method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance material balance
method:
VOC = [% VOC by weight/100] x [Density] x [Volume Consumed].

HAP = [% HAP by weight/100] x [Density] x [Volume Consumed].
[R307-401-8]

II.B.2.a.2 The owner/operator shall maintain records each month of the following for VOC- and/or HAP-emitting materials: A. The name (i.e., material identifier) and type (i.e., ink, solvent) of the VOC- and/or HAP- emitting material. B. The maximum percent by weight of VOC and each HAP in each material used. C. The density of each material used. D. The volume of each material used. E. The amount of VOC and of each HAP emitted monthly by each material used. F. The total amount of VOC, of each HAP, and of all HAPs combined emitted from all materials (in tons). [R307-401-8]

DAQE-IN119040015-24
Page 8

II.B.3 Emergency Generator Engine Requirements II.B.3.a The owner/operator shall not operate the emergency generator engine on site for more than 100
hours per rolling 12-month period for maintenance checks and readiness testing. There is no time limit on the use of the engine during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8]
II.B.3.a.1 To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. Records documenting the operation of the emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used. B. The duration of operation in hours. C. The reason for the emergency engine usage. [40 CFR 63 Subpart ZZZZ, R307-401-8]
II.B.3.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter on the emergency generator engine on site. [R307-401-8]

II.B.4 Fuel Requirements
II.B.4.a The owner/operator shall only use diesel fuel (fuel oil #1, #2 or diesel fuel oil additives) as fuel in the emergency generator engine. [40 CFR 63 Subpart ZZZZ]

II.B.4.b The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8]
II.B.4.b.1 To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel
fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD
requirements. [R307-401-8]

PERMIT HISTORY

This Approval Order shall supersede (if a modification) or will be based on the following documents:
Supersedes AO DAQE-AN119040014-19 dated February 22, 2019 Is Derived From NOI dated June 4, 2024
DAQE-IN119040015-24
Page 9

ACRONYMS

The following lists commonly used acronyms and associated translations as they apply to this document:

40 CFR Title 40 of the Code of Federal Regulations
AO Approval Order
BACT Best Available Control Technology
CAA Clean Air Act
CAAA Clean Air Act Amendments
CDS Classification Data System (used by Environmental Protection Agency to classify
sources by size/type)
CEM Continuous emissions monitor
CEMS Continuous emissions monitoring system
CFR Code of Federal Regulations
CMS Continuous monitoring system
CO Carbon monoxide
CO2 Carbon Dioxide
CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98,
Subpart A, Table A-1
COM Continuous opacity monitor
DAQ/UDAQ Division of Air Quality
DAQE This is a document tracking code for internal Division of Air Quality use
EPA Environmental Protection Agency
FDCP Fugitive dust control plan
GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i)
GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818-
12(a)
HAP or HAPs Hazardous air pollutant(s)
ITA Intent to Approve
LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent
NOx Oxides of nitrogen
NSPS New Source Performance Standard
NSR New Source Review
PM10 Particulate matter less than 10 microns in size
PM2.5 Particulate matter less than 2.5 microns in size
PSD Prevention of Significant Deterioration
PTE Potential to Emit
R307 Rules Series 307
R307-401 Rules Series 307 - Section 401
SO2 Sulfur dioxide
Title IV Title IV of the Clean Air Act
Title V Title V of the Clean Air Act
TPY Tons per year
UAC Utah Administrative Code
VOC Volatile organic compounds

Herald Journal
Publication Name:
Herald Journal
Publication URL:
Publication City and State:
Logan, UT
Publication County:
Cache
Notice Popular Keyword Category:
Notice Keywords:
RR donnelley
Notice Authentication Number:
202407221157536725485
1761527914
Notice URL:
Back
Notice File:Notice Publish Date:
THJ-0720-ClassAd-538168-1.pdf Saturday, July 20, 2024
Notice Content
PLEASE NOTE: The following text was electronically converted from the PDF document above, and may not be 100% accurate. Because of this, please view the PDF for
the most accurate information.
NOTICE A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been
received for consideration by the Director: Company Name: RR Donnelley and Sons Company Location: Logan Printing Plant – 630 West
1000 North, Logan, UT Project Description: RR Donnelley and Sons Company (RR Donnelley) owns and operates a printing plant that
manufactures business forms and direct mailing pieces in Logan, Cache County. The plant consists of multiple digital, high-speed inkjet
printers. Waste paper from this operation is sent through a cyclone where it is shredded and baled. The bales are sent offsite for recycling.
RR Donnelley is requesting to add four (4) digital printers to Approval Order DAQE-AN119040014-19. RR Donnelley is not requesting to
increase the Volatile organic
Web display limited to 1,000 characters. Please view the PDF for the complete Public Notice.
Back

DAQE-NN119040015-24

July 18, 2024

The Herald Journal
Legal Advertising Dept
1068 W 130 S
Logan, UT 84321

RE: Legal Notice of Intent to Approve

This letter will confirm the authorization to publish the attached NOTICE in The Herald Journal on July
20, 2024.

Please mail the invoice and affidavit of publication to the Utah State Department of Environmental
Quality, Division of Air Quality, P.O. Box 144820, Salt Lake City, Utah 84114-4820. If you have any
questions, contact Jeree Greenwood, who may be reached at [phone].

Sincerely,

{{$s }}

Jeree Greenwood
Office Technician

Enclosure

cc: Bear River Association of Governments
cc: Cache County

195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone [phone] • Fax [phone] • T.D.D. [phone]
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah

SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor

Department of
Environmental Quality

Kimberly D. Shelley
Executive Director

DIVISION OF AIR QUALITY
Bryce C. Bird
Director

DAQE-NN119040015-24
Page 2
NOTICE

A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah
Administrative Code (UAC), has been received for consideration by the Director:

Company Name: RR Donnelley and Sons Company
Location: Logan Printing Plant – 630 West 1000 North, Logan, UT
Project Description: RR Donnelley and Sons Company (RR Donnelley) owns and operates a printing
plant that manufactures business forms and direct mailing pieces in Logan, Cache
County. The plant consists of multiple digital, high-speed inkjet printers. Waste
paper from this operation is sent through a cyclone where it is shredded and
baled. The bales are sent offsite for recycling.

RR Donnelley is requesting to add four (4) digital printers to Approval Order
DAQE-AN119040014-19. RR Donnelley is not requesting to increase the
Volatile organic compounds and Hazardous air pollutant(s) limits outlined in
Condition II.B.2.a. The new digital printers will operate under the existing
limitations outlined in Condition II.B.2.a. The new printers will utilize ink that
does not contain any Hazardous air pollutant(s) emissions except for glycol
ethers, which is also limited in Condition II.B.2.a. Therefore, no annual
emissions are increasing.

RR Donnelley is currently permitted to operate fourteen (14) digital printers.
However, only thirteen (13) were installed at the time of this modification
request. The addition of four (4) new digital printers results in a new site-wide
total of seventeen (17) printers.

The completed engineering evaluation and air quality impact analysis showed the proposed project meets
the requirements of federal air quality regulations and the State air quality rules. The Director intends to
issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the
effect on local air quality and draft Approval Order are available for public inspection and comment at the
Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments
received by the Division at this same address on or before August 19, 2024, will be considered in making
the final decision on the approval/disapproval of the proposed project. Email comments will also be
accepted at [e-mail]. If anyone so requests to the Director in writing within 15 days of
publication of this notice, a hearing will be held in accordance with
R307-401-7, UAC.

Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or
argument during an adjudicatory proceeding that was raised during the public comment period and was
supported with sufficient information or documentation to enable the Director to fully consider the
substance and significance of the issue.

Date of Notice: July 20, 2024

{{#s=Sig_es_:signer1:signature}}

DAQE-

RN119040015 July 10, 2024 Bradley Smith RR Donnelley and Sons Company 630 West 1000 North Logan, UT 84321
[e-mail] Dear Bradley Smith,
Re: Engineer Review: Modification to Approval Order DAQE-AN119040014-19 to Add Four (4) Inkjet Printers
Project Number: N119040015 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This
ER identifies all applicable elements of the New Source Review permitting program. RR Donnelley and Sons Company should complete this review within 10 business days of receipt.
RR Donnelley and Sons Company should contact Christine Bodell at [phone] if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Christine Bodell at [e-mail] the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an ITA for a 30-day public comment period. At the completion of the comment period, the DAQ will address any comments and will prepare an Approval Order (AO) for signature by the DAQ Director. If RR Donnelley and Sons Company does not respond to this letter within 10 business days, the project
will move forward without source concurrence. If RR Donnelley and Sons Company has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction.
Approval Signature _____________________________________________________________ (Signature & Date)

195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone [phone] • Fax [phone] • T.D.D. [phone]
www.deq.utah.gov
Printed on 100% recycled paper
Department of Environmental Quality
Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director
State of Utah
SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 1
UTAH DIVISION OF AIR QUALITY
ENGINEER REVIEW

SOURCE INFORMATION
Project Number N119040015 Owner Name RR Donnelley and Sons Company Mailing Address 630 West 1000 North Logan, UT, 84321 Source Name Logan Printing Plant Source Location 630 West 1000 North Logan, UT 84321-9175
UTM Projection 429,175 m Easting, 4,622,303 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12
SIC Code 2759 (Commercial Printing, NEC) Source Contact Bradley Smith
Phone Number [phone] Email [e-mail]
Billing Contact Bradley Smith Phone Number [phone] Email [e-mail] Project Engineer Christine Bodell, Engineer Phone Number [phone] Email [e-mail]
Notice of Intent (NOI) Submitted June 4, 2024 Date of Accepted Application June 14, 2024

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 2
SOURCE DESCRIPTION General Description
RR Donnelley and Sons Company (RR Donnelley) owns and operates a printing plant that manufactures business forms and direct mailing pieces in Logan, Cache County. The plant consists of seventeen (17) digital, high-speed inkjet printers. Waste paper from this operation is
sent through a cyclone where it is shredded and baled. The bales are sent offsite for recycling. NSR Classification:
Minor Modification at Minor Source Source Classification
Located in Attainment Area Cache County Airs Source Size: B
Applicable Federal Standards MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines Project Proposal Modification to Approval Order DAQE-AN119040014-19 to Add Four (4) Inkjet Printers
Project Description RR Donnelley is requesting to add four (4) digital printers to Approval Order DAQE-
AN119040014-19. RR Donnelley is not requesting to increase the VOC and HAPs limits outlined in Condition II.B.2.a. The new digital printers will operate under the existing limitations outlined in Condition II.B.2.a. The new printers will utilize ink that does not contain any HAP emissions
except for glycol ethers, which is also limited in Condition II.B.2.a. Therefore, no annual emissions are increasing.
RR Donnelley is currently permitted to operate fourteen (14) digital printers. However, only thirteen (13) were installed at the time of this modification request. The addition of four (4) new digital printers results in a new site-wide total of seventeen (17) printers.

EMISSION IMPACT ANALYSIS No criteria or hazardous air pollutant emissions are increasing. Therefore, modeling is not required. [Last updated June 13, 2024]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 3
SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible.
Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 9097.80
Carbon Monoxide 0 6.55
Nitrogen Oxides 0 4.71
Particulate Matter - PM10 0 5.56
Particulate Matter - PM2.5 0 5.56
Sulfur Dioxide 0 0.52 Volatile Organic Compounds 0 18.78 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr)
Acetaldehyde (CAS #75070) 0 800
Ethylene Glycol (CAS #107211) 0 2760
Formaldehyde (CAS #50000) 0 800
Glycol Ethers (CAS #EDF109) 0 1400 Methanol (CAS #67561) 0 800 Toluene (CAS #108883) 0 4880
Vinyl Acetate (CAS #108054) 0 800
Xylenes (Isomers And Mixture) (CAS #1330207) 0 3340
Change (TPY) Total (TPY)
Total HAPs 0 7.79
Note: Change in emissions indicates the difference between previous AO and proposed modification.

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 4
Review of BACT for New/Modified Emission Units 1. BACT review regarding Four (4) New Printers
The source has proposed to install three (3) Ricoh printers and one (1) Xerox printer. Emissions from the new printers consist of VOCs and HAPs. Emissions are generated from the application of ink onto the selected paper/material and the subsequent evaporation of the solvents in the ink. The
source assessed the following for controlling the release of VOCs/HAPs from the printers: 1. Use of low VOC inks 2. Capture and regenerative thermal oxidation (RTO) of emissions 3. Capture and carbon adsorption of VOCs from air stream 4. Proper maintenance and operation of the printers to minimize emissions
Inks for digital printers are specific to the manufacturer and are not interchangeable. Therefore, the
use of inks with lower VOC content is not technically feasible. To evaluate the use of an RTO and carbon adsorption, RR Donnelley utilized an analysis developed in January 2018 by the Sacramento Metropolitan Air Quality Management District for an HP Indigo Digital Sheetfed Press. While the HP Indigo press is manufactured by different
suppliers and utilize different printing technologies than the Ricoh and Xerox printers, the presses share several common attributes that make the BACT Analysis relevant. All three presses utilize digital technology where an electronic file is used to produce a digital image that is transferred to the substrate. All three presses also operate using inks produced by the press manufacturer specifically for their printing press meaning the use of alternative inks for either press is not an option. Neither press has a dedicated exhaust so all emissions of VOCs are fugitive. Lastly, add-on controls are the only viable option to reduce the emissions of VOCs.
The three (3) Ricoh presses each have the potential to emit 4.91 tpy of VOCs and 3.62 tpy of glycol ethers (a VOC HAP), while the one (1) Xerox press has the potential to emit 3.83 tpy of
VOCs. Both add on controls have a control efficiency of 98.5%. The capture is dependent on design and method of capture. A 100% capture rate was assumed for the analysis. According to the 2018 document, the total annualized cost of an RTO and carbon adsorption system is approximately $247,347 and $74,841, respectively. Utilizing a VOC control efficiency of
98.5% results in the following cost effectiveness for each printer and control technology: Ricoh: RTO: $51,143/ton of VOC reduced Carbon Adsorption: $15,475/ton VOC reduced
Xerox: RTO: $65,565/ton of VOC reduced Carbon Adsorption: $19,838/ton VOC reduced
The DAQ has determined that neither control option is cost effective and has eliminated RTO and carbon adsorption as BACT.
The source is subject to UAC R307-304 for solvent cleaning if it uses 55 gallons or more of VOC
containing solvents. Specifically, (1) the source shall comply with the VOC content limits in R307-304-5; (2) the source shall comply with the requirements for any add-on controls; (3) the source shall store used applicators and shop towels in closed containers; and (4) the source shall maintain

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 5
records, such as VOC content or vapor pressure of solvents, and key control system parameters, to demonstrate compliance with R307-304. The DAQ considers this to be BACT. [Last updated June
14, 2024]
SECTION I: GENERAL PROVISIONS
The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label):
I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in
the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101]
I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]

I.3 Modifications to the equipment or processes approved by this AO that could affect the
emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon
request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8]

I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air
pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity
observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4]

I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107]
I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 6
I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18]

SECTION II: PERMITTED EQUIPMENT
The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT
II.A.1 Logan Printing Plant

II.A.2 Production Laser Printers Print onto paper using toner. Listed for informational purposes only
II.A.3 High-Volume Inserting System
Mechanically inserts statements into envelopes. Listed for informational purposes only
II.A.4 Seventeen (17) Digital Printers (Four (4) New)
Digital, high-speed, continuous feed, inkjet printers. II.A.5 Book Binders Perfect binders and mechanical binders
Listed for informational purposes only
II.A.6 Suction & Trim System One (1) cyclone Rating: 66,000 cubic feet per minute

II.A.7 Welding Section Listed for informational purposes only
II.A.8 Various Boilers and Heaters
Rating: < 5 MMBtu/hr each Fuel: Natural gas
II.A.9 Emergency Generator Engine Max Engine Rating: 600 kW (805 HP)
Model Year: 2000 Fuel: Diesel MACT Applicability: 40 CFR 63 Subpart ZZZZ

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 7

SECTION II: SPECIAL PROVISIONS
The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 NEW Source-Wide Requirements
II.B.1.a NEW The owner/operator shall not allow visible emissions from the following emission points to exceed the following values:
A. Emergency generator engine - 20% opacity
B. All other points or fugitive emission sources - 5% opacity [R307-401-8]
II.B.1.a.1 NEW Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8]
II.B.1.b NEW The owner/operator shall comply with all applicable requirements of UAC R307-304 (Solvent Cleaning). [R307-304]
II.B.2
NEW
VOC and HAP Requirements
II.B.2.a
NEW
The owner/operator shall not emit more than the following from evaporative sources (i.e.
printing, coating, and/or cleaning) A. 18.78 tons per rolling 12-month period for VOCs B. 1.38 tons per rolling 12-month period for Ethylene Glycol
C. 0.68 tons per rolling 12-month period for Glycol Ethers
D. 1.67 tons per rolling 12-month period for Xylene E. 2.44 tons per rolling 12-month period for Toluene F. 0.40 tons per rolling 12-month period for Formaldehyde G. 0.40 tons per rolling 12-month period for each individual HAP not listed H. 7.79 tons per rolling 12-month period for all HAPs combined [R307-401-8]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 8
II.B.2.a.1 NEW The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance/material-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance material balance method: VOC = [% VOC by weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by weight/100] x [Density] x [Volume Consumed] [R307-401-8]

II.B.2.a.2 NEW The owner/operator shall maintain records each month of the following for VOC- and/or HAP- emitting materials: A. The name (i.e. material identifier) and type (i.e. ink, solvent) of the VOC- and/or
HAP- emitting material B. The maximum percent by weight of VOC and each HAP in each material used C. The density of each material used D. The volume of each material used E. The amount of VOC and of each HAP emitted monthly by each material used F. The total amount of VOC, of each HAP, and of all HAPs combined emitted from
all materials (in tons) [R307-401-8] II.B.3 Emergency Generator Engine Requirements
II.B.3.a NEW The owner/operator shall not operate the emergency generator engine on site for more than 100 hours per rolling 12-month period for maintenance checks and readiness testing. There is no time limit on the use of the engine during emergencies. [40 CFR 63 Subpart ZZZZ, R307-
401-8] II.B.3.a.1 NEW To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months.
Records documenting the operation of the emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used B. The duration of operation in hours C. The reason for the emergency engine usage [40 CFR 63 Subpart ZZZZ, R307-401-8]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 9
II.B.3.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter on the emergency generator engine on site. [R307-401-8] II.B.4 Fuel Requirements II.B.4.a NEW The owner/operator shall only use diesel fuel (fuel oil #1, #2 or diesel fuel oil additives) as fuel in the emergency generator engine. [40 CFR 63 Subpart ZZZZ]

II.B.4.b
NEW
The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur
diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8]
II.B.4.b.1
NEW
To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall
maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 10
PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the
following documents: Supersedes DAQE-AN119040014-19 dated February 22, 2019
Is Derived From NOI dated June 4, 2024
REVIEWER COMMENTS

1. Comment regarding Source Emission Estimates and DAQ Acceptance: RR Donnelley is installing four (4) additional printers, consisting of three (3) Ricoh printers and one (1) Xerox printer. Emissions from the printers are generated through the evaporation of VOCs from
the inks. There will be an increase in actual ink consumption; however, the increase will not exceed the potential ink usage that was evaluated during the source's last approval order modification. The addition will addition of printers does not result in an increased PTE.
The VOC and/or HAPs emissions are based on the ink SDS sheets and manufacturer data. The
source estimated emissions from the inks assuming the highest VOC and/or HAP content associated with each ink for a conservative estimate. Ricoh Printing Press Based on manufacturer provided data and ink SDS sheets, the following parameters were used when estimating emissions: Maximum ink usage: 0.09806 milliliters/image Image rate: 2 images/ft
Printer speed: 492 ft/min Ink density: 9.01 lb/gal VOC content by weight: 8.14%
HAP (glycol ethers) content by weight: 6% Xerox Printing Press Based on manufacturer provided data and ink SDS sheets, the following parameters were used when estimating emissions: Maximum ink usage: 80 microliters/impression Impression rate: 11,820 impressions/hour Ink density: 8.75 lb/gal VOC content by weight: 40% HAP content by weight: 0% [Last updated June 14, 2024] 2. Comment regarding Federal Subpart Applicability: 40 CFR 63 Subpart ZZZZ - Standards of Performance for Stationary Spark Ignition Internal Combustion Engines The provisions of this subpart are applicable to owners/operators of stationary RICE at a major or
area sources of HAP emissions. The facility includes one (1) diesel-fired emergency stationary engine. The provisions of MACT Subpart ZZZZ apply as the stationary reciprocating internal combustion engine (RICE) is at an area source of HAP emissions. The engine is not designated as
nonroad and is not exempt are affected sources under this regulation. Therefore, MACT Subpart ZZZZ applies to this facility. [Last updated June 13, 2024]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 11

3. Comment regarding Title V Applicability: Title V of the 1990 CAA (Title V) applies to the following: A. Any major source B. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources
C. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants D. Any Title IV-affected source
This facility is not a major source and is not a Title IV source, and is not subject 40 CFR 60 (NSPS)
and/or 40 CFR 61 (NESHAP) regulations. The facility is subject to 40 CFR 63 (MACT) Subparts A and ZZZZ. However, MACT Subpart ZZZZ exempts sources from the obligation to obtain a permit under 40 CFR part 70 (Title V permit) if the source is not otherwise required by law to obtain a
permit. There are no other reasons why this source would be required to obtain a part 70 permit; therefore, Title V does not apply to this facility. [Last updated June 13, 2024]

Engineer Review N119040015: Logan Printing Plant July 10, 2024 Page 12
ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document:
40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology
CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type)
CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations
CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide
CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a)
HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour
LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units
NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants
NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard
NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit
R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide
Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year
UAC Utah Administrative Code VOC Volatile organic compounds
Mark O'Donoghue <[e-mail]>
[EXTERNAL] RE: RR Donnelley and Xerox HF Emissions Calcs
Gojdics, Robert <[e-mail]>Mon, Feb 28, 2022 at 4:29 PM
To: Mark O'Donoghue <[e-mail]>, "Bay, William" <[e-mail]>
Cc: "[e-mail]" <[e-mail]>, "Smith, Sheryl M" <[e-mail]>, "Clark, Merrill"
<[e-mail]>
Good afternoon Mark,

Follow-up on a few recent questions you had:

1. Does the press have an exhaust stack? Something that would vent through the roof or a wall? Yes, the Baltoro
printer includes an optional Vent kit. Each site may choose to vent the printer
2. I am using a density of 8.34 lb/gal for the inks. Can you provide the actual ink density? Our specific gravity is
1.0485 g/ml, 3785 ml/gallon = 3969 g/gal, 453.59 g/lb = 8.75 lb/gal
3. Do you have ink use information for your existing customers? Is 5,300 liters per year realistic? If not, what can we
expect for annual ink use? The measurements we gathered from measuring RR Donnelley BCS statements,
totaled less than 1000 L annually. The transactional nature of these jobs is one reason your measurement for the
gap between your estimate and 1000L annually. Another reason for the large delta, the 1000L estimate is based
on medium ink usage setting, 5300 liters is based on max possible ink usage.
Mark, if you feel we may benefit from a follow-up call please let us know – with a few dates/times and we’ll arrange a
follow up meeting. Thank you!
Bob G

From: Mark O'Donoghue <[e-mail]>
Sent: Thursday, February 24, 2022 5:14 PM
To: Bay, William <[e-mail]>
[Quoted text hidden]
[Quoted text hidden]
6/11/24, 2:18 PM RR Donnelley Mail - [EXTERNAL] RE: RR Donnelley and Xerox HF Emissions Calcs
https://mail.google.com/mail/u/0/?ik=6eb39c4bde&view=pt&search=all&permmsgid=msg-f:1726043939639908817&simpl=msg-f:1726043939639908…1/1
Maximum Ink Use*Images Speed Min/Hour Hour/Year Liters/Mililiter Gallons/Liter Density VOC %
Annual VOC
Emissions
Annual VOC
Emissions
(Mililiters/Image)(Images/Ft)(Ft/Min)(Lb/Gal)(Lb/Year)(Ton/Year)
0.09806 x 2 x 492 x 60 x 8760 x 0.001 x 0.264 x 9.01 x 8.14%=9820 4.91
Maximum Ink Use*Images Speed Min/Hour Hour/Year Liters/Mililiter Gallons/Liter Density HAP %
Annual HAP
(Glycol
Ethers)
Emissions
Annual HAP
(Glycol
Ethers)
Emissions
(Mililiters/Image)(Images/Ft)(Ft/Min)(Lb/Gal)(Lb/Year)(Ton/Year)
0.09806 x 2 x 492 x 60 8760 0.001 0.264 x 9.01 x 6.00%=7238 3.62
Maximum Ink Use*Speed Hours/Year Gallons/Liter Density VOC %
Annual VOC
Emissions
(Microliters/Impression)(Impressions/Hr)(Lb/Gal)(Lb/Year)
80 x 11820 x 8760 x 0.264 x 8.75 x 40%=7654
Xerox Baltoro PTE Calculations
POTENTIAL VOC EMISSIONS CALCULATION
POTENTIAL HAP (GLYCOL ETHERS) EMISSIONS CALCULATION
Ricoh VC40000 PTE CALCULATIONS
*Maximum Ink Use based on data provided by manufacturer
*Maximum Ink Use based on data provided by manufacturer
Annual VOC
Emissions
(Ton/Year)
3.83
MAXIMUM EMISSIONS CALCULATION - RRD FORD LETTER
Black Cyan Magenta Yellow
Ink Density (Lb/Gal)9.01 8.91 9.01 8.85
VOC %8.14%4.14%0.55%6.34%
VOC Density (Lb/Gal)0.73 0.37 0.05 0.56
HAP %2%2%6%6%
HAP Density (Lb/Gal)0.18 0.18 0.54 0.53
Application Type
Application
Sheet Size
Speed Mode
Ink per Impression C
Ink per Impression Y
Ink per Impression M
Ink per Impression K
Ink per Impression (uL)**
Max Impressions Per Minute *
Max Impressions Per Hour *
Max Ink Per Hour (L)
The table above provides examples of the types of work that will be printed on the Xerox Baltoro.
* Max Impressions per minute or hour assume 100% productivity, i.e. no stoppages for paper loading, job programming, etc.
** Potential to Emit Calculations are based on the highest ink use of 80.0 uL per impression, scaled up by 25% for a total of 100 uL per impression
XEROX BALTORO
RRD Ford Letter RRD ComEd Statement
Employee Benefit Booklet
(RRD Veritas)
Optimize For Color Optimize For Color Optimize For Color
Letter Letter 12x18
37.76
70.5
99
5940
0.42
7.98
12.73
9.14
20.36
50.2
197
11820
0.59
19.71
5.87
7.12
197
11820
0.95
36.37
14.61
5.84
23.14
80.0

May 31, 2024
Mr. Alan Humpherys
Manager, Minor NSR Section Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116

Re: BACT Analysis RR Donnelley and Sons Logan Printing Plant 630 West 1000 North Logan, Utah 84321

Dear Mr. Humpherys: The RR Donnelley and Sons Logan Printing Plant (Logan) is submitting this application for a revision to the site’s Approval Order (AO) DAQE-AN119040013-17. The site intends to install two additional digital printers, one Ricoh VC40000 inkjet printing press and one Xerox Baltoro
inkjet printing press. The current AO, lists 14 Digital Printers, but the site currently operates 13
digital printers. The addition of the two proposed digital printers will bring the total to 15 digital printers. The site would like to request that the current emissions limits, listed in Section II.B.2.a of the
AO, remain the same. While the potential VOC emissions for these two presses are 4.91
tons/year and 3.83 tons/year respectively, actual emissions for both presses are significantly lower. Based on this and on the site’s actual 2023 VOC emissions of 0.82 tons, the site is confident it will remain below all current emissions limits.
The site intends to install the two proposed presses in September and requests that the permit
revision be issued by this timeframe. If you have any questions or require any additional information, please do not hesitate to contact Mark O’Donoghue at [e-mail].

Sincerely,
Brian Ravenberg
VP - Operations
BACT ANALYSIS
As required, the RR Donnelley and Sons Logan Printing Plant (Logan) is providing the attached BACT Analysis for your review. Logan requests that the BACT Analysis be used to satisfy Utah Administrative Code R307-401-6 as it pertains to the Notice of Intent application, submitted on TBD for the installation of one Ricoh VC40000 Inkjet Printer and one Xerox Baltoro Inkjet
printer at the Logan facility. The analysis was developed in January 2018 by the Sacramento Metropolitan Air Quality Management District for an HP Indigo Digital Sheetfed Press. While the HP Indigo press is manufactured by different suppliers and utilize different printing technologies than the Ricoh
VC40000 and the Xerox Baltoro: Liquid Electrophotography for the HP and Inkjet for the Ricoh & Xerox, the presses have several common attributes that make the BACT Analysis relevant to both. To start, all three presses utilize digital technology where an electronic file is used to produce a
digital image that is transferred to the substrate. All three presses also operate using inks produced by the press manufacturer specifically for their printing press meaning the use of alternative inks for either press is not an option. Neither press has a dedicated exhaust so all emissions of Volatile Organic Compounds are fugitive. Lastly, add-on controls are the only viable option to reduce the emissions of Volatile Organic Compounds.
Additionally, Logan is also providing potential VOC emissions calculations for the Ricoh VC40000 and the Xerox Baltoro presses. As you can see, the emissions for the press are dependent upon the amount of ink used (coverage %) and have worst case emission rate of 4.91 tons per year
and 3.83 tons per year. In reality, Logan expects the actual emissions to be much lower, less than
0.5 tons per year per press. Under either emission scenario, potential versus actual, the BACT Analysis results in the following total annual cost determinations:

Carbon Adsorption: $74,840 @ 4.91 tons/year VOC (Potential): $15,242 per ton of VOC controlled @ 0.5 tons/year VOC (Projected Actual): $49,680 per ton of VOC controlled
Thermal Oxidation: $247,347
@ 4.91 tons/year VOC (Potential): $50,376 per ton of VOC controlled @ 0.5 tons/year VOC (Projected Actual): $494,694 per ton of VOC controlled
Form 1 Date __________________ Notice of Intent (NOI) Application Checklist Company __________________ Utah Division of Air QualityNew Source Review SectionSource Identification Information [R307-401-5] 1. Company name, mailing address, physical address and telephone number 2. Company contact (Name, mailing address, and telephone number) 3.Name and contact of person submitting NOI application (if different than 2) 4.Source Universal Transverse Mercator (UTM) coordinates 5. Source Standard Industrial Classification (SIC) code 6.Area designation (attainment, maintenance, or nonattainment) 7.Federal/State requirement applicability (NAAQS, NSPS, MACT, SIP, etc.) 8.Source size determination (Major, Minor, PSD) 9. Current Approval Order(s) and/or Title V Permit numbers NOI Application Information: [R307-401]           N/A N/A A.Air quality analysis (air model, met data, background data, source impact analysis) N/A  1.Detailed description of the project and source process2.Discussion of fuels, raw materials, and products consumed/produced3.Description of equipment used in the process and operating schedule4.Description of changes to the process, production rates, etc.5.Site plan of source with building dimensions, stack parameters, etc.6.Best Available Control Technology (BACT) Analysis [R307-401-8]A.BACT analysis for all new and modified equipment7.Emissions Related Information: [R307-401-2(b)]A.Emission calculations for each new/modified unit and site-wide(Include PM10, PM2.5, NOx, SO2, CO, VOCs, HAPs, and GHGs)B.References/assumptions, SDS, for each calculation and pollutantC.All speciated HAP emissions (list in lbs/hr)8.Emissions Impact Analysis – Approved Modeling Protocol [R307-410]A.Composition and physical characteristics of effluent(emission rates, temperature, volume, pollutant types and concentrations)9.Nonattainment/Maintenance Areas – Major NSR/Minor (offsetting only) [R307-403]A.NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirementsB.Alternative site analysis, Major source ownership compliance certification10.Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406]B.Visibility impact analysis, Class I area impact11.Signature on Application N/A Note: The Division of Air Quality will not accept documents containing confidential information or data. Documents containing confidential information will be returned to the Source submitting the application.
iJoc.i-iirKji'il Dale:' (X!/AS,‘2C UDAQ 2018-002271
Page 1 of 1 Company___________________________Site _____________________________ Form 5 Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2.Hazardous Air Pollutants** (**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed
Jccumonl Dcjlc: 02/28/2018
1 of 1 Form 2 Date ____________ Company Information/Notice of Intent (NOI) Utah Division of Air QualityNew Source Review Section Application for: □ Initial Approval Order □Approval Order ModificationGeneral Owner and Source Information1.Company name and mailing address:____________________________________________________________________________________Phone No.: ( ) Fax No.: ( ) 2.Company** contact for environmental matters:____________________________Phone no.: ( ) Email: _______________________ ** Company contact only; consultant or independent contractor contact information can be provided in a cover letter 3.Source name and physical address (if different fromabove):____________________________ ____________________________ ____________________________ Phone no.: ( ) Fax no.: ( ) 4.Source Property Universal Transverse Mercatorcoordinates (UTM), including System and Datum:UTM:_________________________ X:____________________________ Y:____________________________ 5.The Source is located in:__________________ County6.Standard Industrial Classification Code (SIC) __ __ __ __7.If request for modification, AO# to be modified: DAQE #__________________ DATED: ____/____/____8.Brief (50 words or less) description of process.Electronic NOI 9.A complete and accurate electronic NOI submitted to DAQ Permitting Mangers Jon Black ([e-mail]) or AlanHumpherys ([e-mail]) can expedite review process. Please mark application type.Hard Copy Submittal Electronic Copy Submittal □ Both Authorization/Signature I hereby certify that the information and data submitted in and with this application is completely true, accurate and complete, based on reasonable inquiry made by me and to the best of my knowledge and belief. Signature: Title: _______________________________________ Name (Type or print) Telephone Number: ( ) Email: Date:
DAO 2018002272
Page 1 of 1 Form 4 Company____________________________ Project Information Site ______________________________ Utah Division of Air Quality New Source Review Section Process Data - For Modification/Amendment ONLY 1. Permit Number_______________________________ If submitting a new permit, then use Form 3 Requested Changes 2. Name of process to be modified/added: _______________________________ End product of this process: _______________________________ 3. Permit Change Type: New Increase* Equipment Process Condition Change ____________________ Other ______________________________ Other ______________________________ Other ______________________________ 4. Does new emission unit affect existing permitted process limits? Yes No 5. Condition(s) Changing: 6. Description of Permit/Process Change** 7. New or modified materials and quantities used in process. ** Material Quantity Annually 8. New or modified process emitting units ** Emitting Unit(s) Capacity(s) Manufacture Date(s) *If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. **If additional space is required, please generate a document to accommodate and attach to form.
Doc.uim:i'ii D^lc: 02/28/2018DAQ 2018-002274
Version 8.0 Page n. 1 of 8Revison 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: Large Bottle Ink, 18L, Dye, ID, M71.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: 6&5((1*UDSKLFDQG3UHFLVLRQ6ROXWLRQV&R/WG6D\DPD6KLQNDLFKL.XPL\DPDFKR.XVHJXQ.\RWR-DSDQ3KRQHQXPEHU)$;QXPEHUDate:13/07/2016Revision:1.01.4. Emergency telephone number 3KRQHQXPEHU0RQ)UL6&5((1*3(XURSH%9$PVWHOYHHQ1HWKHUODQGV3KRQHQXPEHU0RQ)UL6&5((1*3$PHULFDV//&,/$PHULFDVSECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Hazard pictograms: None Hazard statements: None Precautionary statements: None Special Provisions: EUH210 Safety data sheet available on request. EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May produce an allergic reaction. Special provisions according to Annex XVII of REACH and subsequent amendments: None 2.3. Other hazards vPvB Substances: None - PBT Substances: None Other Hazards: No other hazards SECTION 3: Composition/information on ingredients 3.1. Substances No data available 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty Name Ident. Number ClassificationProduct Name :RICOH Pro Ink Cartridge Magenta VC40000 Type ASDS Number :719319Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data SheetRICOH Pro Ink CartridgeMagenta VC40000 Type A (719319)Company Name :Ricoh Company, Ltd.Department :Safety and Reliability Engineering Department, Quarity Management DivisonAddress :146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007, JapanTelephone Number :055-920-1470, Japan ,Telefax Number :055-920-1479, JapanRicoh USA, IncEnvironmental Sustainability and Product Compliance5 Dedrick Place West Caldwell, NJ 07006 USA1-973-882-2000 or 1-973-882-5218 (For product information)1-800-336-6737 (for emergencies)Telefax Number :E-mail :[e-mail]
Version 8.0 Page n. 2 of 8Revison 1.0 65% ~ 80% Water CAS: 7732-18-5 EC: 231-791-2 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). 5% ~ 7% 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Indexnumber: 603-183-00-0 CAS: 143-22-6 EC: 205-592-6 REACH No.: 01-2119475107-383.3/1 Eye Dam. 1 H318 0.25% ~ 0.5%Triethanol amine CAS: 102-71-6 EC: 203-049-8 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). < 0.05% 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one Indexnumber: 613-088-00-6 CAS: 2634-33-5 EC: 220-120-9 3.1/4/Oral Acute Tox. 4 H302 3.2/2 Skin Irrit. 2 H315 3.3/1 Eye Dam. 1 H318 3.4.2/1-1A-1B Skin Sens. 1,1A,1B H317 4.1/A1 Aquatic Acute 1 H400 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed None 4.3. Indication of any immediate medical attention and special treatment needed Treatment: None SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 3 of 8Revison 1.0 Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3. Methods and material for containment and cleaning up Wash with plenty of water. 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment. 7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3. Specific end use(s) None in particular SECTION 8: Exposure controls/personal protection 8.1. Control parameters No occupational exposure limit available DNEL Exposure Limit Values No data available PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 8.2. Exposure controls Eye protection: Not needed for normal use. Anyway, operate according good working practices. Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 4 of 8Revison 1.0 Protection for skin: No special precaution must be adopted for normal use. Protection for hands: Not needed for normal use. Respiratory protection: Not needed for normal use. Thermal Hazards: None Environmental exposure controls: None Appropriate engineering controls: None SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance and colour: Magenta Liquid Odour:SlightlyOdour threshold: No data available pH: 8.8 ~ 9.8 at 20 °C Melting point / freezing point: No data available Initial boiling point and boiling range: No data available Solid/gas flammability: No data available Upper/lower flammability or explosive limits: No data available Vapour density: No data available Flash point: Not detected until 100 °C / 212 ° F (closed cup method, ASTM D 3278) Evaporation rate: No data available Vapour pressure: No data available Relative density: No data available Solubility in water: Complete Solubility in oil: No data available Partition coefficient (n-octanol/water): No data available Auto-ignition temperature: No data available Decomposition temperature: No data available Viscosity:< 5 mPa·s at 20 °C Explosive properties: No data available Oxidizing properties: No data available 9.2. Other information Miscibility:No data available Fat Solubility: No data available Conductivity: No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 5 of 8Revison 1.0 None. SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the mixture: e) germ cell mutagenicity:Test: Mutagenesis - Species: Salmonella Typhimurium and Escherichia coli Negative Toxicological information of the main substances found in the mixture: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 a) acute toxicity:Test: LD50 - Route: Dermal - Species: Rabbit = 3.54 ml/kg - Source: American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. Test: LD50 - Route: Oral - Species: Rat = 5300 mg/kg - Source: Office of Toxic Substances Report. Vol. OTS, Triethanol amine - CAS: 102-71-6 a) acute toxicity:Test: LD50 - Route: Oral - Species: Guinea pig = 2200 mg/kg - Source: "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 114, 1982. Test: LD50 - Route: Oral - Species: Mouse = 5846 mg/kg - Source: Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989. - Notes: GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" KIDNEY, URETER, AND BLADDER: OTHER CHANGES BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Substance(s) listed on the IARC Monographs: Triethanol amine - Group 3. If not differently specified, the information required in Regulation (EU) 2015/830 listed below must be considered as 'No data available': a) acute toxicity;b) skin corrosion/irritation;c) serious eye damage/irritation;d) respiratory or skin sensitisation;e) germ cell mutagenicity;f) carcinogenicity;g) reproductive toxicity;h) STOT-single exposure;i) STOT-repeated exposure;j) aspiration hazard.SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. No data available 12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential No data available 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 6 of 8Revison 1.0 vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects None SECTION 13: Disposal considerations 13.1. Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force.SECTION 14: Transport information 14.1. UN number Not classified as dangerous in the meaning of transport regulations. 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU Information: Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013 Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP) Regulation (EU) n. 618/2012 (ATP 3 CLP) Regulation (EU) n. 487/2013 (ATP 4 CLP) Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Restrictions related to the product: No restriction. Restrictions related to the substances contained: No restriction. Where applicable, refer to the following regulatory provisions : Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): No data available USA Information: TSCA - Toxic Substances Control Act Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 7 of 8Revison 1.0 TSCA inventory: all the components are listed on the TSCA inventory. TSCA listed substances: None. SARA - Superfund Amendments and Reauthorization Act Section 302 – Extremely Hazardous Substances: no substances listed. Section 304 – Hazardous substances: no substances listed. Section 313 – Toxic chemical list: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether. CAA - Clean Air Act CAA listed substances: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether is listed in CAA Section 112, Section 112(b) - HON. California Proposition 65 Substance(s) listed under California Proposition 65: None. NFPA rating: HMIS rating: Canada Information: WHMIS Controlled Product: WHMIS item number from Ingredient Disclosure List : Triethylene glycol: 1625 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether: 1627 Australia Information: Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC New Zealand Information: Hazardous Substances and New Organisms Act 1996: Not regulated 15.2. Chemical safety assessment No SECTION 16: Other information Full text of phrases referred to in Section 3: H318 Causes serious eye damage. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. This safety data sheet has been completely updated in compliance to Regulation 2015/830. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 8 of 8Revison 1.0 ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold CCNL - Appendix 1 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This Safety Data Sheet cancels and replaces any preceding release. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. CAS: Chemical Abstracts Service (division of the American Chemical Society). CLP: Classification, Labeling, Packaging. DNEL: Derived No Effect Level. EINECS: European Inventory of Existing Commercial Chemical Substances. GefStoffVO: Ordinance on Hazardous Substances, Germany. GHS: Globally Harmonized System of Classification and Labeling of Chemicals. HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO). IMDG: International Maritime Code for Dangerous Goods. INCI: International Nomenclature of Cosmetic Ingredients. KSt: Explosion coefficient.LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. LTE: Long-term exposure.NFPA: National Fire Protection Association NOHSC: National Occupational Health and Safety Commission OSHA: Occupational Safety and Health Administration PNEC: Predicted No Effect Concentration. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. STE: Short-term exposure.STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. TLV: Threshold Limiting Value. TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). WGK: German Water Hazard Class. WHMIS: Workplace Hazardous Materials Information System Product Name : RICOH Pro Ink Cartridge Magenta VC40000 Type A SDS Number : 719319Date Prepared : 07/13/2016 Date Printed : 07/07/2017Safety Data Sheet
Version 8.0 Page n. 1 of 9Revison 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: Large Bottle Ink, 18L, Dye, ID, BK71.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: 6&5((1*UDSKLFDQG3UHFLVLRQ6ROXWLRQV&R/WG6D\DPD6KLQNDLFKL.XPL\DPDFKR.XVHJXQ.\RWR-DSDQ3KRQHQXPEHU)$;QXPEHUDate:13/07/2016Revision:1.01.4. Emergency telephone number 3KRQHQXPEHU0RQ)UL6&5((1*3(XURSH%9$PVWHOYHHQ1HWKHUODQGV3KRQHQXPEHU0RQ)UL6&5((1*3$PHULFDV//&,/$PHULFDVSECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Hazard pictograms: None Hazard statements: None Precautionary statements: None Special Provisions: EUH210 Safety data sheet available on request. EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May produce an allergic reaction. Special provisions according to Annex XVII of REACH and subsequent amendments: None 2.3. Other hazards vPvB Substances: None - PBT Substances: None Other Hazards: No other hazards SECTION 3: Composition/information on ingredients 3.1. Substances No data available 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty Name Ident. Number ClassificationProduct Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data SheetCompany Name :Ricoh Company, Ltd.Department :Safety and Reliability Engineering Department, Quarity Management DivisonAddress :146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007, JapanTelephone Number :055-920-1470, Japan ,Telefax Number :055-920-1479, JapanRICOH Pro Ink Cartridge Black VC40000 Type A (719317)
Version 8.0 Page n. 2 of 9Revison 1.0 50% ~ 65% Water CAS: 7732-18-5 EC: 231-791-2 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). 10% ~ 12.5% Glycerol CAS: 56-81-5 EC: 200-289-5 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). 1% ~ 3% 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Indexnumber: 603-183-00-0 CAS: 143-22-6 EC: 205-592-6 REACH No.: 01-2119475107-383.3/1 Eye Dam. 1 H318 0.5% ~ 1%Triethanol amine CAS: 102-71-6 EC: 203-049-8 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). < 0.05% 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one Indexnumber: 613-088-00-6 CAS: 2634-33-5 EC: 220-120-9 3.1/4/Oral Acute Tox. 4 H302 3.2/2 Skin Irrit. 2 H315 3.3/1 Eye Dam. 1 H318 3.4.2/1-1A-1B Skin Sens. 1,1A,1B H317 4.1/A1 Aquatic Acute 1 H400 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed None 4.3. Indication of any immediate medical attention and special treatment needed Treatment: None SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 3 of 9Revison 1.0 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3. Methods and material for containment and cleaning up Wash with plenty of water. 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Do not eat or drink while working. See also section 8 for recommended protective equipment. 7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3. Specific end use(s) None in particular SECTION 8: Exposure controls/personal protection 8.1. Control parameters Glycerol - CAS: 56-81-5 - OEL Type: OSHA - LTE: 5 mg/m3 - Notes: PEL, as mist, respirable fraction - OEL Type: OSHA - LTE: 15 mg/m3 - Notes: PEL, as mist, total dust DNEL Exposure Limit Values No data available PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 8.2. Exposure controls Eye protection: Not needed for normal use. Anyway, operate according good working practices. Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 4 of 9Revison 1.0 Protection for skin: No special precaution must be adopted for normal use. Protection for hands: Not needed for normal use. Respiratory protection: Not needed for normal use. Thermal Hazards: None Environmental exposure controls: None Appropriate engineering controls: None SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance and colour: Black Liquid Odour:SlightlyOdour threshold: No data available pH: 7.4 ~ 8.4 at 20 °C Melting point / freezing point: No data available Initial boiling point and boiling range: No data available Solid/gas flammability: No data available Upper/lower flammability or explosive limits: No data available Vapour density: No data available Flash point: Not detected until 100 °C / 212 ° F (closed cup method, ASTM D 3278) Evaporation rate: No data available Vapour pressure: No data available Relative density: No data available Solubility in water: Complete Solubility in oil: No data available Partition coefficient (n-octanol/water): No data available Auto-ignition temperature: No data available Decomposition temperature: No data available Viscosity:< 5 mPa·s at 20 °C Explosive properties: No data available Oxidizing properties: No data available 9.2. Other information Miscibility:No data available Fat Solubility: No data available Conductivity: No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 5 of 9Revison 1.0 None. SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the mixture: e) germ cell mutagenicity:Test: Mutagenesis - Species: Salmonella Typhimurium and Escherichia coli Negative Toxicological information of the main substances found in the mixture: Glycerol - CAS: 56-81-5 a) acute toxicity:Test: LD50 - Route: Oral - Species: Guinea pig = 7750 mg/kg - Source: Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941 Test: LDLo - Route: Oral - Species: Human = 1428 mg/kg - Source: "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 288, 1969. - Notes: BEHAVIORAL: HEADACHE GASTROINTESTINAL: NAUSEA OR VOMITING 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 a) acute toxicity:Test: LD50 - Route: Dermal - Species: Rabbit = 3.54 ml/kg - Source: American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. Test: LD50 - Route: Oral - Species: Rat = 5300 mg/kg - Source: Office of Toxic Substances Report. Vol. OTS, Triethanol amine - CAS: 102-71-6 a) acute toxicity:Test: LD50 - Route: Oral - Species: Guinea pig = 2200 mg/kg - Source: "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 114, 1982. Test: LD50 - Route: Oral - Species: Mouse = 5846 mg/kg - Source: Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989. - Notes: GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" KIDNEY, URETER, AND BLADDER: OTHER CHANGES BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Substance(s) listed on the IARC Monographs: Triethanol amine - Group 3. If not differently specified, the information required in Regulation (EU) 2015/830 listed below must be considered as 'No data available': a) acute toxicity;b) skin corrosion/irritation;c)serious eye damage/irritation;d) respiratory or skin sensitisation;e) germ cell mutagenicity;f) carcinogenicity;g) reproductive toxicity;h) STOT-single exposure;i) STOT-repeated exposure;j) aspiration hazard.SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 6 of 9Revison 1.0 No data available 12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential No data available 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects None SECTION 13: Disposal considerations 13.1. Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force.SECTION 14: Transport information 14.1. UN number Not classified as dangerous in the meaning of transport regulations. 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU Information: Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013 Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP) Regulation (EU) n. 618/2012 (ATP 3 CLP) Regulation (EU) n. 487/2013 (ATP 4 CLP) Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Restrictions related to the product: No restriction. Restrictions related to the substances contained: No restriction. Where applicable, refer to the following regulatory provisions : Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 7 of 9Revison 1.0 Directive 2003/105/CE ('Activities linkedto risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): No data available USA Information: TSCA - Toxic Substances Control Act TSCA inventory: all the components are listed on the TSCA inventory. TSCA listed substances: None. SARA - Superfund Amendments and Reauthorization Act Section 302 – Extremely Hazardous Substances: no substances listed. Section 304 – Hazardous substances: no substances listed. Section 313 – Toxic chemical list: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether. CAA - Clean Air Act CAA listed substances: Glycerol is listed in CAA Section 111 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether is listed in CAA Section 112, Section 112(b) - HON. California Proposition 65 Substance(s) listed under California Proposition 65: None. NFPA rating: HMIS rating: Canada Information: WHMIS Controlled Product: WHMIS item number from Ingredient Disclosure List : 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether: 1627 Australia Information: Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC New Zealand Information: Hazardous Substances and New Organisms Act 1996: Not regulated 15.2. Chemical safety assessment No SECTION 16: Other information Full text of phrases referred to in Section 3: H318 Causes serious eye damage. Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 8 of 9Revison 1.0 H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. This safety data sheet has been completely updated in compliance to Regulation 2015/830. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold CCNL - Appendix 1 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This Safety Data Sheet cancels and replaces any preceding release. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. CAS: Chemical Abstracts Service (division of the American Chemical Society). CLP: Classification, Labeling, Packaging. DNEL: Derived No Effect Level. EINECS: European Inventory of Existing Commercial Chemical Substances. GefStoffVO: Ordinance on Hazardous Substances, Germany. GHS: Globally Harmonized System of Classification and Labeling of Chemicals. HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO). IMDG: International Maritime Code for Dangerous Goods. INCI: International Nomenclature of Cosmetic Ingredients. KSt: Explosion coefficient.LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. LTE: Long-term exposure.NFPA: National Fire Protection Association NOHSC: National Occupational Health and Safety Commission OSHA: Occupational Safety and Health Administration PNEC: Predicted No Effect Concentration. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. STE: Short-term exposure.STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. TLV: Threshold Limiting Value. TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 9 of 9Revison 1.0 WGK: German Water Hazard Class. WHMIS: Workplace Hazardous Materials Information System Product Name :RICOH Pro Ink Cartridge Black VC40000 Type ASDS Number :719317Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
RICOHPro VC40000Continuous Feed Inkjet PrinterPro VC40000492fpm590fpmfull-colorb&w
With over 40 years of inkjet leadership, Ricoh is a true partner that provides ongoing support and consultative services that enable your success.Create new value for your businessQuality is at the core of compelling print that captures attention. Breaking new ground in the transactional and direct mail space, the RICOH Pro VC40000 delivers crisp text and fine detail with high-precision printing at speeds of up to 590 feet per minute and an impressive range of media support. This combination gives you the ability to cost-effectively create a wide breadth of applications — including personalized communications, MICR applications, direct mail, booklets, brochures and sales collateral — while built-in technology ensures optimal system performance. Gain a competitive advantage with the efficiency and reliability of the RICOH Pro VC40000:• Printing speeds up to 590 feet per minute improve productivity, throughput and the capacity to deliver on-demand jobs and meet SLAs. • Ricoh's Variable Drop Technology delivers only the exact amount of ink needed, resulting in predictable, accurate and consistent color. • Support for printing on uncoated, inkjet-treated and inkjet-coated papers at 600 dpi gives your business more agility.• Inline cooling for maximum print quality, powerful drying that supports high-coverage applications and a built-in auto-adjustment scanner let you deliver exceptional materials that elevate your clients’ engagement with their customers. • A modern flexible, scalable design supports continuous enhancements to help you stay technology-forward and protect your investment. • Advanced cleaning mechanisms and drop-down printheads support easy maintenance, optimal performance and system longevity. • A digital front-end powerful enough for the most demanding jobs facilitates efficiency and productivity. • Color printheads equipped with dye or pigment-based inks remain static during black-and-white printing and deploy for full color (with an optional MICR printhead) expand to meet requirements as needed.
Accuracy, efficiency and added valueDeliver high quality and fast turnarounds. With the RICOH Pro VC40000, operators can put jobs into production with minimal setup, while a touchscreen interface makes it easy to run them accurately. A built-in high-resolution scanner automates printhead cleaning and makes quality adjustments, reducing the need for manual intervention. Different workflows can be integrated, so they won’t slow you down, even in mixed environments. Reliable performance, optimized for your needs Reliability is built into all aspects of Ricoh's continuous feed inkjet systems, including in the use of industrial-strength materials, proven paper transports and printhead technology. The life of the color printheads is extended as they remain stationary during monochrome printing, which also reduces ink consumption significantly. Compared to those of competing systems, the printheads require fewer and less time-consuming operator maintenance tasks. A configurable design allows L, H, inline and dual-simplex system configurations that fit your space. Also available in a monochrome-only configuration.Effective marketing for less With technology that manages ink consumption without compromising quality, the RICOH Pro VC40000 lets you meet customers’ on-demand needs for marketing that makes an impact. Pioneering variable drop-size technology optimizes each dot to create crisp lines and smooth halftones, avoiding flaws like moiré patterns produced by fixed drop-size systems. What’s more, Ricoh’s color management experts can help you fine-tune ink usage to control costs and optimize production as well as assist with color matching, calibration and conformance to standards.Support and services to maximize your ROIRicoh’s rigorous approach to implementation lets you start running revenue-producing production as quickly as possible. Sustain success with Ricoh’s dedicated production print service organization, one of the largest in the country. Our escalation and alert process results in timely response and resolution, while a nationwide network ensures that parts are readily available. After installation, we follow up regularly to confirm that we and our products continue to meet your expectations. After all, Ricoh's success is based on your success.page 1 of 2Sign up for paperless billing to get your bill by email and help save a tree. Register at WTREwards.co/paperlessAMBASSADORPeakTrailCARD HOLDERYISAPOINT EARNED THIS MONTH: 66759,000 points to reach AMBASSADORJohn Smith123 River StLos Angeles, CA 90189ACCOUNT SUMMARYMember Since2017FAVORITE STORESoho# OF WANDERLUST BADGES7POINTs TOTAL250,000CURRENT LEVELWanderlustTHE OFFICIAL MYLO & THURSTONLOYALTY REWARDS PROGRAMCOMING SOON.THE MYLO & THURSTON CREDIT CARD.FOR EVERY DOLLAR YOU SPEND YOU EARN TWO M&T POINTS. 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Unless otherwise specified, product prices already reflect final sale discounts.1&1Refer a friend to the Climbers Club and get entered into the PEAK Adventure Giveaway!0celebrateLET’SYearsTime to party and unwind.Join us for chef-prepared hors d’oeuvres, cocktails and good times to be had by all as we celebrate 20 wonderful years in the community.The Black Tie BarFriday, March 24, 20176:30PM - 7:30PMSEE YOU THERE!7 oak lnPrinted on a RICOH VC40000 Continuous Inkjet System
Engine TechnologyPrint System Drop on demand (DOD), piezolectricColor 4-color (CMYK), 2 bits per spot, dynamic variable drop size at every point on the page, stochastic screening, Optional K-Only Monochrome ConfigurationResolution/Speed 600 x 600 dpi @ 394 ft./min (120 m/min) 600x450 dpi @ 492ft/min (150m/min), 600x600 dpi Monochrome Only @ 590ft/min (180m/min) Print Width 5.9–20.5 inches (150~520 mm)Page Length 4–54 inches (101.6–1,371 mm))Paper Width 6.5–20.5 inches (165–520 mm)Paper Weight 40–250 gsm*Over 157 gsm, maximum print speed is 328 ft./min. (100 m/min)Paper Types Uncoated, inkjet treated, inkjet coated, pinless and pin-fedEngine ComponentsBase Unit* Dimensions (WxDxH) 127.6" (3240 mm) x 73.6" (1870 mm) x 77.6" (1971 mm) Weight 6063 lbs. (2750 kg)Power RequirementsConnection: Low Voltage: 208–240V 102A per engine High Voltage: 380–415V, 69A per enginePower Consumption: Idle: 16kWh, 51kBTU/hr Printing: 63kWh, 216kBTU/hr*Typical printing conditions for 20-24lb bond paper at 394 ft/min, dryer temperature 60° COperating RangeTemperature: Recommended: 64.4º F~75.2º F (18~24º C)Humidity: Recommended: 40–60%Noise: 85dBDryer: Single-drum dryer per engineDryer Temperature: Range: Up to 194º F (90º C) Ventilation: Optional Ink: Dye and pigment ink, 2 18L cartridges for each color. Replace on the flyController: TotalFlow R600A Digital Front EndData Stream Support: Postscript Level 3, PDF 1.7, PDF/VT, IPDS (IS3)Connectivity: Gigabit EthernetColor ManagementICC Profile SupportEnhanced Color Management by Side and Object TypeDevice Link SupportSpot color dictionaries (Pantone, Toyo, DIC, and HKS) CMR Support (AFP/IPDS)Software SupportRicoh ProcessDirector for AIX, Linux, or WindowsVersion 3.2 or later releasesTotalFlow BatchBuilder for WindowsVersion 1.1InfoPrint Manager for AIX, Linux, or WindowsVersion 4.5 or later releasesPrint Services Facility for AIX, Linux or Windows Version 3.1 or later releasesNote: For Linux SLES or Red HatTotalFlow R600A Digital Front EndArchitectureProcessor Architecture Intel Xeon x64OS Linux Physical CharacteristicsDimensions (WxDxH) 39.5" (1003 mm) x 24" (609 mm) x 49" (1245 mm)Weight 716.5 lbs. (325 kg)Data Stream SupportPostScriptPDF (APPE)PDF/VTIPDSJob SubmissionFTPIPPLPRRaw PortOperator ConsoleVirtual Printer/Hot Folder SupportGraphical User InterfaceDisplay on each print engineLogin by Role: Admin, Operator, Maintenance or CustomizableHighly customizable user interface layout by roleGraphical Printer & Supplies StatusOperator MessagesPaper Catalog/Paper SetupJob ManagementGraphical Job Ticketing/Job Preview – Native JDF Banner Operator Comments Sides Printed Copies Rotate, Reduce/Enlarge, Image Alignment Special MarksJob ImpositionJob Queue Management Submit Suspend Hold Process Next Delete JobView Jobs Job Status Active Inactive Stored All Jobs Job HistorySYSTEM SPECIFICATIONSRICOH Pro VC40000R3876-2Ricoh USA, Inc., 300 Eagleview Blvd, Exton, PA 19341, 1-800-63-RICOH ©2020. Ricoh USA, Inc. All rights reserved. Ricoh® and the Ricoh logo are registered trademarks of Ricoh Company, Ltd. All other trademarks are the property of their respective owners. The content of this document, and the appearance, features and specifications of Ricoh products and services are subject to change from time to time without notice. Products are shown with optional features. While care has been taken to ensure the accuracy of this information, Ricoh makes no representation or warranties about the accuracy, completeness or adequacy of the information contained herein, and shall not be liable for any errors or omissions in these materials. Actual results will vary depending upon use of the products and services, and the conditions and factors affecting performance. The only warranties for Ricoh products and services are as set forth in the express warranty statements accompanying them.www.ricoh-usa.com
Safety Data Sheet______________________________________________________________________________________________ActivePage 1 / 7SDS # : F-60039Aqueous Ink -CyanIssuing Date 2018-10-02Revision Date 2019-05-13Version 11. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct Identifier Product NamePart no.008R13257ColorCyanPure substance/mixtureMixtureRelevant identified uses of the substance or mixture and uses advised against Recommended UseInk jet printingDetails of the supplier of the safety data sheet For further information, please contactEmergency telephoneSafety Information US: [phone]Chemical Emergency only (Chemtrec) [phone]For the most current documenthttps://safetysheets.business.xerox.com2. HAZARDS IDENTIFICATIONClassification of the substance or mixture Not classifiedLabel elements Symbol(s)None requiredSignal WordNoneHazard StatementsNone requiredPrecautionary StatementsNone requiredOther hazards Contains a chemical that can cause an allergic reaction in susceptible people3. COMPOSITION/INFORMATION ON INGREDIENTSMixtures HF Aqueous InkforXerox® Baltoro™ HF InkJet PressSupplierXerox CorporationWebster, NY 14580Contact personManager, Environment, Health, Safety & SustainabilityE-mail [e-mail]607E26170BR547
______________________________________________________________________________________________SDS # : F-60039Aqueous Ink -CyanPage 2 / 7Chemical NameCAS No.Weight %Classification (Reg.1272/2008)Hazard StatementsWater7732-18-550-60----Propylene glycol57-55-615-35----1,2-Hexanediol6920-22-5<8Eye Irrit. 2H319Cyan pigmentProprietary<5----Triethanolamine102-71-6<1----1,2-Benzisothiazolin-3-one2634-33-5<0.05Acute Tox. 4Skin Irrit. 2Eye Dam. 1Skin Sens. 1Aquatic Acute 1H302H315H318H317H400"--" indicates no classification or hazard statements apply.Full text of H- statements: see section 164. FIRST AID MEASURESDescription of first-aid measures General adviceIN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL CARE.Eye contactImmediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes, If eye irritation persists, consult a specialistSkin contactWash off with warm water and soap, Get medical attention if irritation develops and persistsInhalationMove to fresh air, Get medical attention immediately if symptoms occurIngestionIf swallowed, do not induce vomiting - seek medical adviceMost important symptoms and effects, both acute and delayed Acute toxicityEyesMay cause slight irritationSkinNo known effectInhalationNo known effectIngestionNo known effectChronic toxicityRepeated contact may cause allergic reactions in very susceptible personsMain symptoms Overexposure may cause:Eye irritationSkin irritationIndication of immediate medical attention and special treatment needed Protection of first-aidersNo special protective equipment requiredNotes to physicianTreat symptomatically5. FIRE-FIGHTING MEASURESExtinguishing media Suitable extinguishing mediaWater spray, Foam, Carbon dioxide (CO2)Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fireSpecial hazards arising from the substance or mixture None in particularHazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors607E26170BR547
______________________________________________________________________________________________SDS # : F-60039Aqueous Ink -CyanPage 3 / 7Advice for fire-fighters Wear self-contained breathing apparatus and protective suitOther information Flash point > 100 °C / > 212 °F6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures Avoid contact with the skin and the eyes, Use personal protective equipmentEnvironmental precautions Should not be released into the environment, Do not allow material to contaminate ground water systemMethods and material for containment and cleaning up Methods for containmentPrevent further leakage or spillage if safe to do so, Dike to collect large liquid spills, Prevententry into waterways, sewers, basements or confined areasMethods for cleaning upSoak up with inert absorbent material, Prevent product from entering drainsReference to other sections See section 12 for additional ecological informationSee Section 13 for additional information7. HANDLING AND STORAGEPrecautions for safe handling Advice on safe handlingHandle in accordance with good industrial hygiene and safety practice, Avoid contact withskin and eyes, Ensure adequate ventilation, Handle and open container with careConditions for safe storage, including any incompatibilities Technical measures and storageconditionsKeep container tightly closed in a dry and well-ventilated place, Keep out of the reach ofchildren, Handle with careIncompatible productsAlkali metals, Strong oxidizing agents, PeroxidesSpecific end uses Ink jet printing8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters Exposure LimitsChemical NameACGIH TLVOSHA PELCyan pigmentTWA: 1 mg/m3TriethanolamineTWA: 5 mg/m3Exposure controls Engineering measuresEnsure adequate ventilation, especially in confined areasIndividual protection measures, such as personal protective equipment (PPE) Eye/Face protectionIf splashes are likely to occur, wear:, GogglesHand protectionProtective glovesSkin and body protectionNone under normal use conditionsRespiratory protectionUse only with adequate ventilation.607E26170BR547
______________________________________________________________________________________________SDS # : F-60039Aqueous Ink -CyanPage 4 / 79. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical properties Boiling point/rangeNot determinedSoftening pointNot applicableEvaporation rateNo information availableFlammability Limits in AirNo information availableVapor pressureNo information availableVapor densityNo information availableSpecific gravityNo information availableWater solubilityDispersablePartition coefficientNo information availableAutoignition temperatureNo information availableDecomposition temperatureNot determinedViscosity5-7 mPa.s @ 25 ° CExplosive propertiesNot explosiveOxidizing propertiesNot applicableOther information None10. STABILITY AND REACTIVITYReactivity No dangerous reaction known under conditions of normal useChemical stability Stable under normal conditions.Possibility of hazardous reactions Hazardous reactionsNone under normal processingHazardous polymerizationHazardous polymerization does not occurConditions to avoid Strong oxidizing agents, Extremes of temperature and direct sunlightIncompatible Materials Alkali metals, Strong oxidizing agents, PeroxidesHazardous decomposition products Undefined, but may include toxic oxides of carbon and nitrogen11. TOXICOLOGICAL INFORMATIONInformation on toxicological effects Acute toxicity Product InformationAppearanceOpaqueOdorSlightPhysical stateLiquidOdor thresholdNo information availableColorCyanpH 7-9.5Flash point > 100 °C / > 212 °F607E26170BR547
______________________________________________________________________________________________SDS # : F-60039Aqueous Ink -CyanPage 5 / 7IrritationMay cause eye irritationComponent InformationChemical NameOral LD50Dermal LD50LC50 InhalationPropylene glycol20 g/kg ( Rat )20800 mg/kg ( Rabbit )Cyan pigment10000 mg/kg ( Rat )Triethanolamine4190 mg/kg ( Rat )20 mL/kg ( Rabbit )16 mL/kg ( Rat )1,2-Benzisothiazolin-3-one1020 mg/kg ( Rat )Chronic toxicity SensitizationContains a chemical that can cause an allergic reaction in susceptible peopleNo hazard expected under normal conditions of useNeurological EffectsNo information availableTarget organ effectsNo information availableCMR Effects Mutagenic effectsNo information availableReproductive toxicityNo information availableCarcinogenicityContains no ingredient listed as a carcinogenOther toxic effects Aspiration HazardNo information available12. ECOLOGICAL INFORMATIONToxicity Acute Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Chronic Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Component InformationChemical NameToxicity to algaeToxicity to fishToxicity tomicroorganismsToxicity to daphnia andother aquatic invertebratesPropylene glycol19000 mg/L EC50 96 h(Pseudokirchneriellasubcapitata)LC50= 51600 mg/LOncorhynchus mykiss 96 hLC50= 51400 mg/LPimephales promelas 96 hLC50 41 - 47 mL/LOncorhynchus mykiss 96 hLC50= 710 mg/LPimephales promelas 96 hEC50 > 1000 mg/L 48 hEC50 > 10000 mg/L 24 hTriethanolamine216 mg/L EC50 72 h(Desmodesmussubspicatus) 169 mg/L EC5096 h (Desmodesmussubspicatus)LC50 10600 - 13000 mg/LPimephales promelas 96 hLC50> 1000 mg/LPimephales promelas 96 hLC50 450 - 1000 mg/LLepomis macrochirus 96 hEC50 = 1386 mg/L 24 hPersistence and degradability No product level data availableBioaccumulative potential No product level data availableMobility in soil Soluble in waterComponent InformationChemical Namelog Pow607E26170BR547
______________________________________________________________________________________________SDS # : F-60039Aqueous Ink -CyanPage 6 / 7Cyan pigment6.6Triethanolamine-2.531,2-Benzisothiazolin-3-one1.3Other adverse effects No information available13. DISPOSAL CONSIDERATIONSWaste treatment methods Waste Disposal MethodsDo not dispose of waste into sewerDispose of in accordance with all applicable local and national environmental laws andregulationsContaminated packagingEmpty containers should be taken to an approved waste handling site for recycling ordisposalCalifornia Waste StatusThis product does not contain any substances listed with the State of California as a hazardous waste.14. TRANSPORT INFORMATIONThis material is not regulated as a Hazardous Material (Dangerous Good) under 49 CFR, IATA/ICAO, IMO/IMDG, or TDG15. REGULATORY INFORMATIONSafety, health and environmental regulations/legislation specific for the substance or mixture OSHA Regulatory StatusThis material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)Canada This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (HPR),and the SDS contains all the information required by the HPR.International Inventories TSCACompliesDSL/NDSLCompliesU.S. Federal Regulations SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean AirAct:Chemical NameCAS No.Weight %HAPS dataVOC ChemicalsClass 1 OzoneDepletorsClass 2 OzoneDepletorsPropylene glycol57-55-615-35Group ITriethanolamine102-71-6<1Group I607E26170BR547CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
______________________________________________________________________________________________SDS # : F-60039Aqueous Ink -CyanPage 7 / 7Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this materialUS State Regulations California Proposition 65This product does not contain any Proposition 65 chemicalsU.S. State Right-to-Know RegulationsThis product is subject to U.S. State Right-to-know regulations as noted below.Chemical NameMassachusettsNew JerseyPennsylvaniaIllinoisRhode IslandWaterXPropylene glycolXXTriethanolamineXXX16. OTHER INFORMATIONIssuing Date2018-10-02Revision Date2019-05-13Revision NoteInitial ReleaseFull text of H-Statements referred to under sections 2 and 3H302 - Harmful if swallowedH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH319 - Causes serious eye irritationH400 - Very toxic to aquatic lifeDisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. Theinformation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered as a warranty or quality specification. The information relates only to the specific material designated and may not bevalid for such material used in combination with any other material or in any process, unless specified in the text.end607E26170BR547
Xerox Internal Use Only Re: VOC content of Baltoro HF Aqueous Inks The intent of this letter is to respond to your inquiry regarding Volatile Organic Content (VOC) in the Xerox inks listed below. Per Directive 2004.42 EC Products Part Description VOC (wt%) Xerox 008R13256 PKG ASSY (K) Ink 28 Xerox 008R13257 PKG ASSY (C) Ink 40 Xerox 008R13258 PKG ASSY (M) Ink 27 Xerox 008R13259 PKG ASSY (Y) Ink 33 Best regards, Deborah Gualtieri Product Safety & Materials Compliance Manager Global Government Affairs / EHS&S Xerox Corporation 800 Phillips Rd., MS 0207-01Z Webster, NY 14580 USA To: Whom It May Concern From: Deborah Gualtieri Product Safety & Material Compliance Manager OGC/EHS&S Date: March 10, 2022 Xerox Corporation 800 Phillips Road MS 0207-01Z Webster, NY 14580 [e-mail] tel [phone] Declaration of VOC Content
Xerox® Baltoro™ HF Inkjet PressInspired Innovation
To learn more, visit www.xerox.com/BaltoroHF.Beyond Inkjet — This isn’t inkjet as you know it. It’s all that and more. The applications you expect, plus higher-end direct mail, books and commercial print. We’re just getting started.SIGNATURE INNOVATIONEnjoy game-changing results with the simplicity of inkjet augmented by heritage-inspired design and leading-edge technology. A powerful blend of High Fusion Print Heads and Ink, native 1200 x 1200 dpi and advanced image controls helps you live on the cutting edge of artistry and innovation.PEAK PRODUCTIVITY Best-in-class automation, class-leading print width and blazing fast speeds of up to 300 ipm will propel your organization forward with the shortest time to productivity and profitability in the market.OPTIMIZED ECONOMICSMigrate jobs effortlessly from more places. Get the most out of every ink drop and tailor IQ to exact specifications with Cost Quality Optimization. And deliver more value than ever before.INVESTMENT PROTECTIONFinishing options such as inline dynamic perf, perfect binding, saddle stitching and punching, plus add-on capabilities and expanded media options, mean future-proof flexibility and new applications for years to come.We designed the Xerox® Baltoro HF Inkjet Press to give you the optimum balance of value, volume and velocity. With a powerful combination of heritage design, automation and exceptional High Fusion image quality, it has the tools you need to get the job done today, and say yes to more jobs tomorrow.Disruptive performance and economics. Virtually endless opportunities.
XEROX INNOVATION Productivity Starts With WorkflowXerox® FreeFlow® Core removes manual prepress steps, reducing both your costs and turnaround times. It automates your print processes and adds a drag-and-drop interface that simplifies remaining manual tasks. And, most importantly, it frees your people to pursue higher-value jobs and integrates hardware and software for enhanced productivity.To learn more and get started, visit www.xerox.com/Automate.PERFECTED BY AIXerox® Automated Intelligence and Advanced Image Controls (AI) deliver signature IQ in real time. By making automatic adjustments based on substrate type, they help you achieve the ideal fusion of media and ink — and outstanding results.ILLUMINATED BY HIGH FUSION INKLow-cost, high-performance, extensible media support without the need for priming - designed to deliver maximum value and impact. You can enjoy greater application versatility and higher image quality than ever before. INSIGHTFULLY BALANCED BY CQOCost Quality Optimization (CQO) makes it easy to find the ideal balance of ink coverage, cost and quality. Fine-tune your image quality to deliver custom color for every job.E XECUTED BY INDUSTRY-E S TA B L I S H E D P R I N T H E A D SPeak accuracy at high frequency. True high-definition 1200 x 1200 dpi resolution. 115% more productive than the competition with a 13.76”/350 mm print area — the widest in its class. With signature IQ, the 100% Xerox-developed and manufactured High Fusion W-Series Print Heads empower you to deliver more.POWERED BY A HIGH-PERFORMANCE, ALL-NEW, ALL XEROX-DEVELOPED PRINT ENGINEAn all-new, Xerox-developed, High Fusion Print Engine accelerates your ROI with built-in performance of up to 300 IPM.Unmatched performance. Superb intelligence and control. Seamless upgradeability and a single-vendor design. With a powerful innovation engine at its core, Xerox® Baltoro HF is ready to propel your business forward.A brilliant engine, built on inspired innovation.
653178910653178910Select “Scan” and focus the camera on the High Fusion Print Engine graphic above.BRING THE HIGH FUSION PRINT ENGINE TO LIFE WITH THE SOLIMAR SYSTEMS AUGMENTED REALITY APP!8WIDEST PRINT AREA IN ITS CLASSDeliver more signature quality across more of the page with Xerox-innovated W-series Print Heads. At up to 13.76"/350 mm, Baltoro unlocks new opportunities for multi-up productivity.7UP TO 300 IPM — BUILT RIGHT INTurn jobs blazingly fast — up to 300 ipm2 — with a combination of robust, production-proven technology and automated intelligence.6UP TO EIGHT PICK POINTSConnect up to four Sheet Feed Modules to the press and liberate true cut-sheet productivity. Each two-tray module holds 2,500 sheets of 90 gsm stock per tray. 5DESIGNED FOR MEDIA VERSATILITYRun commonly available coated and inkjet stocks as well as low-cost uncoated media without primers, pre-treatments or coatings.The Baltoro HF Inkjet Press unlocks game-changing results with a powerful combination of proven heritage design and new technology innovations. An all-new High Fusion Print Engine, Automated Intelligence, expanded finishing options and easy self-service are just part of a dynamic technology powerhouse that will drive new inkjet applications and opportunities.THE INNOVATION ENGINEXerox® Baltoro HF Inkjet Press
2314121113.76"/ 350 mm print area1 Based on running legal-sized documents, 2-up simplex on 17" x 14" long-edge feed media — a capability unique to Baltoro.2 Consult the Xerox® Baltoro HF Tested Substrate List for supported media, weights, speeds, and more.12MORE FINISHING OPTIONSAdd a second high-capacity unload while run stacker, the new inline Tecnau Dynamic Perforator, or Bourg BB3202 Inline Perfect Binder for new, higher-value applications and enhanced flexibility.11AUTOMATED COLOR PROFILINGCreate color profiles for select media in minutes using the latest X-Rite Inline Spectrophotometer technology. Ensure cost quality optimization from stock to stock, and job to job.10COMPACT, EFFICIENT DRYINGComplete the High Fusion Printing process with optimized inline, near-infrared drying technology designed to ensure ultimate image durability on Baltoro’s full range of extensible media. 9REAL-TIME MISSING JET COMPENSATIONIntegrated Full Width Array technology scans a diagnostic page for potential missing jet defects. If detected, surrounding jets are automatically adjusted so they can compensate in real-time.on legal-sized jobs than other presses in its class.1MORE PRODUCTIVE%115UP TO4COST QUALITY OPTIMIZATIONDial in and automate the ideal balance of ink coverage, cost and quality with operator-accessible features on the Xerox® FreeFlow® Print Server that make it easier to meet individual client demands. 3HIGH FUSION INKLiberate yourself from costly media with an ink optimized for stunning quality and versatility on a range of in-demand, high-quality media.2AUTOMATED INTELLIGENCEDeliver signature image quality via a set of evergreen Advanced Image Controls that monitor, diagnose and perfect images in real-time using technologies such as Xerox-exclusive Clear Pixel Plus.1HIGH FUSION W-SERIES PRINT HEADSOptimized for High Fusion inks, Xerox-innovated W-series Print Heads are true high-definition 1200 x 1200 dpi resolution, delivering high performance and remarkable accuracy.A business-driving balance of quality, productivity and cost starts with the High Fusion Print Engine — our innovative combination of advanced technology and intelligent software. UNLEASH SIGNATURE QUALITY WITH LESS EFFORT AND LOWER COSTS1211
Onboard and exceed expectations.Migrating volume to Xerox® Baltoro HF is fast and simple regardless of the source. Onboard volume from litho, toner and even competitive inkjet technologies. Best-in-class press automation on and off the press plus advanced color controls means the fastest onboarding and migration in the industry for incredible productivity from day one.BRILLIANT QUALITY ON IN-DEMAND MEDIA.Offset-like quality is now within your grasp. The powerhouse performance of High Fusion Print Engines and Ink allows you to run an extensive and expanding array of the coated media customers are asking for. Primer-free printing also means more sustainable printing and your substrate texture and sheen get to shine.RAISE YOUR PRINT IQ. High Fusion Ink and our W-series Print Heads offer a range of IQ benefits. Incredibly fine line detail and edges. Amazingly smooth sweeps and gradients. Perfect registration. Sharp white knock-out, intense blacks and a wide gamut of vibrant colors. Plus access to a range of IQ features including: • Color Registration Optimization• Object-level Ink Limiting• Multi-level Halftoning • Anti-Aliasing and Edge Enhancement• Clear Pixel Plus with Deterministic Technology• Real-time Missing Jet Detection and Compensation 2.0Achieving perfect harmony between media and ink, Xerox® Baltoro HF gives you the power to expand your applications and explore new paths to profitability.Signature IQ without compromise.Powered by High Fusion.
Visit xerox.com to see our full line of offerings and learn more.Let our thinking guide your productivity transformation.Xerox is helping change the way the world works with innovations in both xerography and inkjet technology. By applying our expertise in imaging business process, analytics, automation and user-centric insights, we engineer the flow of work to provide greater productivity, efficiency and personalization — making a real difference for our clients and their customers.The Ideal Balance of Versatility and ProductivityUPGRADE YOUR AGILITYSome jobs require stunning image quality. Others, next-day turnarounds of high volumes at an affordable cost. With inkjet you can free up your machines to do what they do best by increasing capacity, accelerating turnarounds and adding new capabilities.ACHIEVE PEAK UPTIME Never underestimate the power of redundancy. Pair similar inkjet systems to increase your volumes, safeguard your commitments and maximize your operation’s productivity. All with consistent image quality.REALIZE WORKFLOW’S FULL POTENTIALAll the benefits of workflow automation and hyper-personalization — now at massive scale. By complementing workflows with inkjet, you can unlock new levels of volume and value and take advantage of new growth opportunities.Meet the missing element in your productivity ecosystem. Thanks to its unprecedented ability to balance cost, quality and speed, inkjet gives you the power to supplement the effectiveness of your existing machines and deliver new, high-value, “no compromise” applications.See what happens when you increase the flexibility of your operation with this pivotal production technology.Better Together: A Powerful Strategy to Maximize Technology
* See your Xerox representative for availabilityThis wrap was printed on the Xerox® iGen® 5 Press. © 2019 Xerox Corporation. All rights reserved. Xerox®, FreeFlow®, iGen®, “Baltoro” and “Made To Think” are trademarks of Xerox Corporation in the United States and/or other countries. PN03400 BR26798 XPIBR-13UB PRESS SPECIFICATIONSSize 22'3.5" x 5'4.5" x 6'9" (W x D x H) / 6.79 m x 1.63 m x 2.06 m (W x D x H)Weight 6769 lb (3070 kg) base configurationPRINT SERVER SPECIFICATIONSDigital Front End Xerox® FreeFlow® Print ServerData Streams PDF, PDF-VT, IPDS, PostScript, TIFF, JPEG, PPML, VIPPHardware (2) 2.6 GHz Intel® Intel Xeon Gold ProcessorsWindows 10 operating system(6) 1.2TB hard drives(8) USB ports (3x2.0, 5x3.0)22" flat panel featuring one additional USB portTECHNOLOGYPrint Resolution True High Definition 1200 x 1200 dpiDrop Volumes Multi-bit simulation option (small, medium, large, max)K-Only ModeUnique option to cap cyan, magenta and yellow heads when printing in black and whiteMaximum Image Area 13.76" x 20.25" / (350 mm x 514 mm)PRODUCTIVITY Images Per Minute (With Speed License) 8.5” x 11” – 182 simplex / 271 duplex ipmA4 – 197 simplex / 276 duplex ipmA3 / 11” x 17” – 200 simplex / 300 duplex ipm (2-up)SRA3 / 12” x 18” – 174 simplex / 254 duplex ipm (2-up)14.33” x 20.5” / (364 mm x 520 mm) – 168 simplex / 252 duplex ipm (2-up)Up to 18,000 images per hourPAPER Paper Characteristics Uncoated plain, inkjet treated, coated paper Paper Weight Uncoated, inkjet treated: 60 gsm to 270 gsm (16# bond – 100# cover) See the Baltoro Tested Substrate List for the latest supported mediaFEEDING / PAPER SUPPLYCapacity 10" (254 mm) of stock per tray / 2,500 sheets (.004 caliper, 90 gsm)Feeder Module Two trays/drawers per Feeder ModuleMaximum of four (4) Feeder Modules/eight (8) paper drawers – total of 20,000 sheet capacityOptional High Capacity FeederMinimum Sheet Size 7.0" x 10.0" / (177.8 mm x 254 mm)Maximum Sheet Size 14.33" x 20.5" / (364 mm x 520 mm)Load While Run All paper drawersOptional Tecnau SheetFeeder BVFINISHING*Stacking Xerox® Production Stacker –5,700 sheets stacking capacity –Unload while run without interruption –Stacks 6.9" x 9.8" LEF to 14.3" x 19.7" (175 mm x 249 mm to 364 mm x 500 mm) sheetsOptional Second Xerox® Production StackerMultigraf PST-52 StackerBooklet Making CP Bourg BDFNx / BDFE-x Booklet Maker –22 sheet capacity with optional corner edge staplingCP Bourg BME –30 sheet capacity with optional corner edge staplingWatkiss PowerSquare 224 –Sticking, folding and trimming with optional cover feeder –52 sheets, 6 position stapleBinding CP Bourg BB3202 Inline Perfect Binder –Binds from 1 to 60 mm (0.04" to 2.36") with support for EVA or PURXerox® Tape Binder –Binds up to 100 sheetsDynamic Perforation Tecnau TC 1530 Dynamic Perforator –Static, still and dynamic perforations with optional 2D bar code reader –Up to 2 horizontal perf cylinders and 4 vertical perf wheelsPunching GBC Fusion Punch IISheet Feeding CP Bourg BSF –Dual mode sheet feedingAVERAGE PRINT VOLUMERecommended 750,000 – 3,000,000 per monthDuty Cycle 6,000,000INSPIRED INNOVATIONXerox® Baltoro™ HF Inkjet Press
Safety Data Sheet______________________________________________________________________________________________ActivePage 1 / 7SDS # : F-60041Aqueous Ink - YellowIssuing Date 2018-10-02Revision Date 2019-05-08Version 11. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct Identifier Product NamePart no.008R13259ColorYellowPure substance/mixtureMixtureRelevant identified uses of the substance or mixture and uses advised against Recommended UseInk jet printingDetails of the supplier of the safety data sheet For further information, please contactEmergency telephoneSafety Information US: [phone]Chemical Emergency only (Chemtrec) [phone]For the most current documenthttps://safetysheets.business.xerox.com2. HAZARDS IDENTIFICATIONClassification of the substance or mixture Not classifiedLabel elements Symbol(s)None requiredSignal WordNoneHazard StatementsNone requiredPrecautionary StatementsNone requiredOther hazards Contains a chemical that can cause an allergic reaction in susceptible people3. COMPOSITION/INFORMATION ON INGREDIENTSMixtures HF Aqueous InkforXerox® Baltoro™ HF InkJet PressSupplierXerox CorporationWebster, NY 14580Contact personManager, Environment, Health, Safety & SustainabilityE-mail [e-mail]607E26190BR547
______________________________________________________________________________________________SDS # : F-60041Aqueous Ink - YellowPage 2 / 7Chemical NameCAS No.Weight %Classification (Reg.1272/2008)Hazard StatementsWater7732-18-550-60----Propylene glycol57-55-615-35----1,2-Hexanediol6920-22-5<8Eye Irrit. 2H319Yellow pigmentProprietary<5----Triethanolamine102-71-6<1----1,2-Benzisothiazolin-3-one2634-33-5<0.05Acute Tox. 4Skin Irrit. 2Eye Dam. 1Skin Sens. 1Aquatic Acute 1H302H315H318H317H400"--" indicates no classification or hazard statements apply.Full text of H- statements: see section 164. FIRST AID MEASURESDescription of first-aid measures General adviceIN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL CARE.Eye contactImmediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes, If eye irritation persists, consult a specialistSkin contactWash off with warm water and soap, Get medical attention if irritation develops and persistsInhalationMove to fresh air, Get medical attention immediately if symptoms occurIngestionIf swallowed, do not induce vomiting - seek medical adviceMost important symptoms and effects, both acute and delayed Acute toxicityEyesMay cause slight irritationSkinNo known effectInhalationNo known effectIngestionNone knownChronic toxicityRepeated contact may cause allergic reactions in very susceptible personsMain symptoms Overexposure may cause:Eye irritationSkin irritationIndication of immediate medical attention and special treatment needed Protection of first-aidersNo special protective equipment requiredNotes to physicianTreat symptomatically5. FIRE-FIGHTING MEASURESExtinguishing media Suitable extinguishing mediaWater spray, Foam, Carbon dioxide (CO2)Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fireSpecial hazards arising from the substance or mixture None in particularHazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors607E26190BR547
______________________________________________________________________________________________SDS # : F-60041Aqueous Ink - YellowPage 3 / 7Advice for fire-fighters Wear self-contained breathing apparatus and protective suitOther information Flash point > 100 °C / > 212 °F6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures Avoid contact with the skin and the eyes, Use personal protective equipmentEnvironmental precautions Should not be released into the environment, Do not allow material to contaminate ground water systemMethods and material for containment and cleaning up Methods for containmentPrevent further leakage or spillage if safe to do so, Dike to collect large liquid spills, Prevententry into waterways, sewers, basements or confined areasMethods for cleaning upSoak up with inert absorbent material, Prevent product from entering drainsReference to other sections See section 12 for additional ecological informationSee Section 13 for additional information7. HANDLING AND STORAGEPrecautions for safe handling Advice on safe handlingHandle in accordance with good industrial hygiene and safety practice, Avoid contact withskin and eyes, Ensure adequate ventilation, Handle and open container with careConditions for safe storage, including any incompatibilities Technical measures and storageconditionsKeep container tightly closed in a dry and well-ventilated place, Keep out of the reach ofchildren, Handle with careIncompatible productsAlkali metals, Strong oxidizing agents, PeroxidesSpecific end uses Ink jet printing8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters Exposure LimitsChemical NameACGIH TLVOSHA PELTriethanolamineTWA: 5 mg/m3Exposure controls Engineering measuresEnsure adequate ventilation, especially in confined areasIndividual protection measures, such as personal protective equipment (PPE) Eye/Face protectionIf splashes are likely to occur, wear:, GogglesHand protectionProtective glovesSkin and body protectionNone under normal use conditionsRespiratory protectionUse only with adequate ventilation.607E26190BR547
______________________________________________________________________________________________SDS # : F-60041Aqueous Ink - YellowPage 4 / 79. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical properties Boiling point/rangeNot determinedSoftening pointNot applicableEvaporation rateNo information availableFlammability Limits in AirNo information availableVapor pressureNo information availableVapor densityNo information availableSpecific gravityNo information availableWater solubilityDispersablePartition coefficientNo information availableAutoignition temperatureNo information availableDecomposition temperatureNot determinedViscosity5-7 mPa.s @ 25 ° CExplosive propertiesNot explosiveOxidizing propertiesNot applicableOther information None10. STABILITY AND REACTIVITYReactivity No dangerous reaction known under conditions of normal useChemical stability Stable under normal conditions.Possibility of hazardous reactions Hazardous reactionsNone under normal processingHazardous polymerizationHazardous polymerization does not occurConditions to avoid Strong oxidizing agents, Extremes of temperature and direct sunlightIncompatible Materials Alkali metals, Strong oxidizing agents, PeroxidesHazardous decomposition products Undefined, but may include toxic oxides of carbon and nitrogen11. TOXICOLOGICAL INFORMATIONInformation on toxicological effects Acute toxicity Product InformationNo acute toxicity information is available for this productAppearanceOpaqueOdorSlightPhysical stateLiquidOdor thresholdNo information availableColorYellowpH 7-9.5Flash point > 100 °C / > 212 °F607E26190BR547
______________________________________________________________________________________________SDS # : F-60041Aqueous Ink - YellowPage 5 / 7IrritationMay cause eye irritationComponent InformationChemical NameOral LD50Dermal LD50LC50 InhalationPropylene glycol20 g/kg ( Rat )20800 mg/kg ( Rabbit )Triethanolamine4190 mg/kg ( Rat )20 mL/kg ( Rabbit )16 mL/kg ( Rat )1,2-Benzisothiazolin-3-one1020 mg/kg ( Rat )Chronic toxicity SensitizationContains a chemical that can cause an allergic reaction in susceptible peopleNeurological EffectsNo information availableTarget organ effectsNo information availableCMR Effects Mutagenic effectsNo information availableReproductive toxicityNo information availableCarcinogenicityContains no ingredient listed as a carcinogenOther toxic effects Aspiration HazardNo information available12. ECOLOGICAL INFORMATIONToxicity Acute Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Chronic Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Component InformationChemical NameToxicity to algaeToxicity to fishToxicity tomicroorganismsToxicity to daphnia andother aquatic invertebratesPropylene glycol19000 mg/L EC50 96 h(Pseudokirchneriellasubcapitata)LC50= 51600 mg/LOncorhynchus mykiss 96 hLC50= 51400 mg/LPimephales promelas 96 hLC50 41 - 47 mL/LOncorhynchus mykiss 96 hLC50= 710 mg/LPimephales promelas 96 hEC50 > 1000 mg/L 48 hEC50 > 10000 mg/L 24 hTriethanolamine216 mg/L EC50 72 h(Desmodesmussubspicatus) 169 mg/L EC5096 h (Desmodesmussubspicatus)LC50 10600 - 13000 mg/LPimephales promelas 96 hLC50> 1000 mg/LPimephales promelas 96 hLC50 450 - 1000 mg/LLepomis macrochirus 96 hEC50 = 1386 mg/L 24 hPersistence and degradability No product level data availableBioaccumulative potential No product level data availableMobility in soil Soluble in waterComponent InformationChemical Namelog PowTriethanolamine-2.531,2-Benzisothiazolin-3-one1.3607E26190BR547
______________________________________________________________________________________________SDS # : F-60041Aqueous Ink - YellowPage 6 / 7Other adverse effects No information available13. DISPOSAL CONSIDERATIONSWaste treatment methods Waste Disposal MethodsDo not dispose of waste into sewerDispose of in accordance with all applicable local and national environmental laws andregulationsContaminated packagingEmpty containers should be taken to an approved waste handling site for recycling ordisposalCalifornia Waste StatusThis product does not contain any substances listed with the State of California as a hazardous waste.14. TRANSPORT INFORMATIONThis material is not regulated as a Hazardous Material (Dangerous Good) under 49 CFR, IATA/ICAO, IMO/IMDG, or TDG15. REGULATORY INFORMATIONSafety, health and environmental regulations/legislation specific for the substance or mixture OSHA Regulatory StatusThis material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)Canada This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (HPR),and the SDS contains all the information required by the HPR.International Inventories TSCACompliesDSL/NDSLCompliesU.S. Federal Regulations SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean AirAct:Chemical NameCAS No.Weight %HAPS dataVOC ChemicalsClass 1 OzoneDepletorsClass 2 OzoneDepletorsPropylene glycol57-55-615-35Group ITriethanolamine102-71-6<1Group ICERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this materialUS State Regulations 607E26190BR547
______________________________________________________________________________________________SDS # : F-60041Aqueous Ink - YellowPage 7 / 7California Proposition 65This product does not contain any Proposition 65 chemicalsU.S. State Right-to-Know RegulationsThis product is subject to U.S. State Right-to-know regulations as noted below.Chemical NameMassachusettsNew JerseyPennsylvaniaIllinoisRhode IslandWaterXPropylene glycolXXTriethanolamineXXX16. OTHER INFORMATIONIssuing Date2018-10-02Revision Date2019-05-08Revision NoteInitial ReleaseFull text of H-Statements referred to under sections 2 and 3H302 - Harmful if swallowedH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH319 - Causes serious eye irritationH400 - Very toxic to aquatic lifeDisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. Theinformation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered as a warranty or quality specification. The information relates only to the specific material designated and may not bevalid for such material used in combination with any other material or in any process, unless specified in the text.end607E26190BR547
11/05/2020 To Whom It May Concern, Regarding the content of VOC and HAP for Ricoh VC40000 Dye Ink supply; please refer to the following information presented in % by weight: VOC Content (% x wt.) Black 8.14% Cyan 4.40% Magenta 0.55% Yellow 6.34% HAP Content (% x wt.) Black 2.0% Cyan 2.0% Magenta 6.0% Yellow 6.0% Sincerely, Bryan Gervais, CSP Manager – EH&S, Product Compliance and Release [e-mail] Ricoh Americas Corporation 6300 Diagonal Hwy. Boulder, Co 80301
BACT Size:Minor Source BACTDIGITAL PRINTING - LIQUID ELCTROPHOTOGRAPHYCATEGORY:PRINTING PROCESSSMAQMD BACT CLEARINGHOUSEACTIVENo StandardNo StandardNo StandardNo StandardBACT Determination Date:BACT Determination Number:Permit Number:DIGITAL PRINTING - LIQUID ELCTROPHOTOGRAPHYEquipment Description:Equipment Location:OFFICE OF STATE PUBLISHING1050 RICHARDS BLVDSACRAMENTO, CAEquipment InformationUnit Size/Rating/Capacity:< 8,663 lbs uncontrolled VOC/yearBACT Determination InformationVOC Control System. SMAQMD Rules 466 & 441.1. Integral air pollution control system, consisting of an oil/water separator and refigeratedcondenser, with an assumed control efficiency of 80% or equivalent system. Comply with SMAQMDrules 466 & 411.ROCsStandard:TechnologyDescription:Basis:NOxStandard:TechnologyDescription:Basis:SOxStandard:TechnologyDescription:Basis:PM10Standard:TechnologyDescription:Basis:COStandard:TechnologyDescription:Basis:District Contact:Achieved in Practice24724Printed:1/3/2018Comments:T-BACT is the following:1.A VOC control device that has an overall system efficiency (collection and destruction) of at least 98.5% for VOC.2.Comply with SMAQMD Rule 466 - Solvent Cleaning & SMAQMD Rule 441 - Organic Solvents.For projects also involving publication rotogravure presses, product and packaging rotogravure presses, or wide-webflexographic printing presses, T-BACT will be determined on a case-by-case basis.Jeff Quok Phone No.: [phone] email: [e-mail]1471/3/2018No StandardPM2.5Standard:TechnologyDescription:Basis:LEADStandard:TechnologyDescription:Basis:
BACT Size:Minor Source BACTDIGITAL PRINTING - LIQUID ELCTROPHOTOGRAPHYCATEGORY:PRINTING PROCESSSMAQMD BACT CLEARINGHOUSEACTIVENo StandardNo StandardNo StandardNo StandardBACT Determination Date:BACT Determination Number:Permit Number:DIGITAL PRINTING - LIQUID ELCTROPHOTOGRAPHYEquipment Description:Equipment Location:Equipment InformationUnit Size/Rating/Capacity:≥ 8,683 lbs uncontrolled VOC/yearBACT Determination InformationOverall system efficiency of at least 98.5% VOC1. VOC control device with overall efficiency of 98.5%. 2. Use of materials compliant with SMAQMDRule 466. 3. Comply with VOC emission standards of SMAQMD Rule 411.ROCsStandard:TechnologyDescription:Basis:NOxStandard:TechnologyDescription:Basis:SOxStandard:TechnologyDescription:Basis:PM10Standard:TechnologyDescription:Basis:COStandard:TechnologyDescription:Basis:District Contact:Cost EffectiveN/A -- Generic BACT DeterminationPrinted:1/3/2018Comments:T-BACT will be the same as BACT for VOCs. For projects also involving publication rotogravure presses, product andpackaging rotogravure presses, or wide-web flexographic printing presses, T-BACT will be determined on a case-by-casebasis.1801/3/2018No StandardPM2.5Standard:TechnologyDescription:Basis:LEADStandard:TechnologyDescription:Basis:
BACT Template Version 071315 777 12th Street, Third Floor Sacramento, CA 95814 BEST AVAILABLE CONTROL TECHNOLOGY DETERMINATION DETERMINATION NO.: 147 & 180 DATE: 1/3/18 ENGINEER: Jeffrey Quok Category/General Equip Description: Printing Process Equipment Specific Description: Digital Printing – Liquid Electrophotography Equipment Size/Rating: Minor Source BACT Previous BACT Det. No.: N/A This BACT/T-BACT determination will be made for digital printing – liquid electrophotography. BACT/T-BACT ANALYSIS A: ACHIEVED IN PRACTICE (Rule 202, §205.1a) The following control technologies are currently employed as BACT for digital printing – liquid electrophotography by the following air pollution control districts: District/Agency Best Available Control Technology (BACT)/Requirements US EPA BACT Source: EPA RACT/BACT/LAER Clearinghouse For Digital Printing - Liquid Electrophotography Pollutant Standard VOC No standard NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard
BACT Determination Digital Printing – Liquid Electrophotography Page 2 of 19 District/Agency Best Available Control Technology (BACT)/Requirements US EPA T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: 40 CFR 63 Subpart KK – National Emission Standards for the Printing and Publishing Industry (Amended 4/21/11) This regulation applies to new and existing facilities that are a major source of hazardous air pollutants at which publication rotogravure, product and packaging rotogravure, or wide-web flexographic printing presses are operated. [40 CFR §63.820] Since liquid electrophotography does not qualify as publication rotogravure, product and packaging rotogravure, or wide-web flexographic printing presses, this rule will not generally be considered T-BACT for this source category. However, for projects that include digital printing as well as one of the affected printing processes, compliance with 40 CFR, 63, Subpart KK will be considered technologically feasible T-BACT for the project. ARB BACT Source: ARB BACT Clearinghouse T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: None. For Digital Printing - Liquid Electrophotography Pollutant Standard VOC No standard NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard
BACT Determination Digital Printing – Liquid Electrophotography Page 3 of 19 District/Agency Best Available Control Technology (BACT)/Requirements SMAQMD BACT Source: SMAQMD BACT Clearinghouse For Digital Printing - Liquid Electrophotography Pollutant Standard VOC No standard NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: Rule 450 – Graphic Arts Operations (Amended 10/23/08) This rule applies to graphic arts operations. Graphic arts operations is defined as any gravure, screen printing, flexographic, lithographic, or letterpress printing operation, or any coating or laminating operation that manufactures flexible packaging material for the packing industry. Liquid electrophotography does not meet this definition and therefore this rule does not apply. Rule 466 – Solvent Cleaning (Amended 10/28/10) This rule applies to all persons who use VOC-containing materials in solvent cleaning operations during the production, repair, maintenance or servicing of parts, products, tools, machinery, or equipment, or in general work areas, and to all persons who store and dispose of VOC-containing materials used in solvent cleaning. Section 301 VOC Standards: Solvent Cleaning Activity VOC limits g/l (lb/gal) (A) General (wipe cleaning, maintenance cleaning) 25 (0.21) (B) Product cleaning during manufacturing process or surface preparation for coating, adhesive, or ink application (i) General 25 (0.21) (ii) Electrical apparatus components & electronic components 100 (0.83) (iii) Medical Devices & pharmaceuticals 800 (6.7)
BACT Determination Digital Printing – Liquid Electrophotography Page 4 of 19 District/Agency Best Available Control Technology (BACT)/Requirements SMAQMD (C) Repair and Maintenance Cleaning VOC limits g/l (lb/gal) (i) General 25 (0.21) (ii) Electrical apparatus components & electronic components 100 (0.83) As an alternative to complying with the Solvent VOC limits, a person may use air pollution control equipment provided it satisfies all of the following: 1. The air pollution control equipment is approved by the Air Pollution Control Officer pursuant to Rule 201, General Permit Requirements, 2. The air pollution control equipment is designed and operated with: a. A control device efficiency of at least 95% on a mass basis, as determined pursuant to Sections 402 and 502.3, and b. An emission collection efficiency of at least 90% on a mass basis of the emissions generated by the solvent cleaning operations, as determined pursuant to Section 502.4, or c. An output of less than 50 parts per million calculated as carbon with no dilution. 3. The air pollution control equipment shall result in VOC emissions per calendar quarter no greater than would have resulted from compliance with Section 301, as calculated by the following equation: Where: CE = Control device efficiency, % by mass CL = Collection efficiency, % by mass ACTi = Actual VOC content of material “i,” grams per liter LIMi = Applicable VOC limit for material “i" in Section 301, grams per liter Ui = Usage of material “i,” liters per calendar quarter. Since the costs and feasibility of installing control equipment depend on the operation and type of control equipment, this alternative isn’t considered achieved in practice. Alternative emissions control equipment options are addressed in the cost effective analysis. Rule 441 – Organic Solvents (Adopted 12/6/78) This rule limits the emissions of organic solvents into the atmosphere that may result from the use of organic solvents. Standards For Organic Materials A person shall not discharge into the atmosphere more than 6.8 kilograms (15 pounds) of organic materials in any one day, nor more than 1.4 kilograms (3.1 pounds) in any one hour, from any article, machine, equipment or other contrivance, in which any organic solvent or any material containing organic solvent comes into contact with flame or is baked, heat-cured or heat-polymerized, in the presence of oxygen, unless said discharge has been reduced
BACT Determination Digital Printing – Liquid Electrophotography Page 5 of 19 District/Agency Best Available Control Technology (BACT)/Requirements SMAQMD by at least 85%. Those portions of any series of articles, machines, equipment or other contrivances designed for processing a continuous web, strip or wire which emit organic materials and using operations described in this section shall be collectively subject to compliance with this section. For Photochemically Reactive Solvents A person shall not discharge into the atmosphere more than 18 kilograms (39.7 pounds) of organic materials in any one day, no more than 3.6 kilograms (7.9 pounds) in any one hour, from any article, machine, equipment or other contrivance used under conditions other than described in Section 301 for employing, or applying, any photochemically reactive solvent, as defined in Section 203, or material containing such photochemically reactive solvent, unless said discharge has been reduced by at least 85%. Emissions of organic materials into the atmosphere resulting from air or heated drying of products for the first 12 hours after their removal from any article, machine, equipment, or other contrivance described in this section shall be included in determining compliance with this section. Emissions resulting from baking, heat-curing, or heat-polymerizing as described in Section 201 shall be excluded from determination of compliance with this section. Those portions of any series of articles, machines, equipment or other contrivances designed for processing for a continuous web, strip, or wire which emit organic materials and using operations described in this section shall be collectively subject to compliance with this section. For Non-Photochemically Reactive Solvents A person shall not discharge into the atmosphere more than 1350 kilograms (441 pounds) in any one hour, from any article, machine, equipment or other contrivance which any non-photochemically reactive organic solvent or any material containing such solvent is employed or applied, unless said discharge has been reduced by at least 85%. Emissions of organic materials into the atmosphere resulting from air or heated drying of products for the first 12 hours after their removal from any article, machine, equipment, or other contrivance described in this section shall be included in determining compliance with this section. Emissions resulting from baking, heat-curing, or heat-polymerizing as described in Section 301 shall be excluded from determination of compliance with this section. Those portions of any series of articles, machines, equipment, or other contrivance designed for processing a continuous web, strip or wire which emit organic materials and using operations described in this section shall be collectively subject to compliance with this section. Material Hourly Emission Limit [kg/hr] (lbs/hr) Daily Emission Limit [kg/day] (lbs/day) Organic Materials Organic Materials which come into contact with a flame or is baked, heat-cured or heat-polymerized, in the presence of oxygen [1.4] (3.1) [6.8] (15) Photochemically Reactive Solvents [3.6] (7.9) [18] (39.7)
BACT Determination Digital Printing – Liquid Electrophotography Page 6 of 19 District/Agency Best Available Control Technology (BACT)/Requirements SMAQMD Material Hourly Emission Limit [kg/hr] (lbs/hr) Daily Emission Limit [kg/day] (lbs/day) Non-photochemically reactive solvents [200] (441) [1,350] (2,970) Solvent Disposal: A person shall not, during any one day, dispose of a total of more than 5 liters (1.3 gallons) of any photochemically reactive solvent, as defined in section 203 or of any material containing more than 5 liters (1.3 gallons) of any such photochemically reactive solvent by any means which will permit the evaporation of such solvent into the atmosphere. Cleanup Emissions of organic materials into the atmosphere from cleanup with cleanup with photochemically reactive solvent as defined in Section 203 of any article, machine, equipment or other contrivance described in Sections 301, 302 or 303 shall be included with the other emissions of organic materials from that article, machine, equipment or other contrivance for determining compliance with this rule. Required Reductions Emissions of organic materials into the atmosphere required to be controlled by Sections 301, 302 or 303 shall be reduced by: 1. Incineration, provided that 90% or more of the carbon in the organic material being incinerated is oxidized to carbon dioxide, or 2. Absorption, or 3. Processing in a manner determined by the Air Pollution Control Office to be not less effective than incineration or absorption.
BACT Determination Digital Printing – Liquid Electrophotography Page 7 of 19 District/Agency Best Available Control Technology (BACT)/Requirements South Coast AQMD BACT Source: SCAQMD Evaluation A/N 562397 (See Attachment C) For Digital Printing - Liquid Electrophotography Pollutant Standard VOC Integral air pollution control system, consisting of an oil/water separator and a refrigeration condenser. NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: Rule 1130 – Graphic Arts (Amended 5/2/14) This rule applies to any person performing graphic arts operations or who supplies, sells, offers for sale, markets, manufactures, blends, repackages, stores at a worksite, distributes, applies or solicits the application of graphic arts materials for use in the District. Graphics arts operations is define as gravure, letterpress, flexographic, and offset lithographic printing processes or related coating or laminating processes. Liquid electrophotography does not meet this definition and therefore this rule does not apply. Rule 1171 – Solvent Cleaning Operations (Last amended 5/1/2009) This rule applies to all persons who use solvent materials in solvent cleaning operations during the production, repair, maintenance, or servicing of parts, products, tools, machinery, equipment, or general work areas; all persons who store and dispose of these materials used in solvent cleaning operations; and all solvent suppliers who supply, sell, or offer for sale solvent cleaning materials for use in solvent cleaning operations. This rule does not apply to cleaning operations in printing pre-press or graphic arts pre-press areas, including the cleaning of film processors, color scanners, plate processors, film cleaning, and plate cleaning.
BACT Determination Digital Printing – Liquid Electrophotography Page 8 of 19 District/Agency Best Available Control Technology (BACT)/Requirements South Coast AQMD Solvent Requirements: Solvent Cleaning Activity VOC limits g/l (lb/gal) (A) Product cleaning during manufacturing process or surface preparation for coating, adhesive, or ink application (i) General 25 (0.21) (ii) Electrical apparatus components & electronic components 100 (0.83) (iii) Medical Devices & pharmaceuticals 800 (6.7) (B) Repair and Maintenance Cleaning (i) General 25 (0.21) (ii) Electrical apparatus components & electronic components 100 (0.83) (C) Cleaning of coatings or adhesives application equipment 25 (0.1) (D) Cleaning of Ink Application Equipment (i) General 25 (0.1) In lieu of complying with the above solvent requirements, a person may comply by using a VOC emission collection and control system in association with the solvent cleaning operation provided: (A) The emission control system shall collect at least 90%, by weight, of the emissions generated by the solvent cleaning operation and i. Have a destruction efficiency of at least 95%, by weight, or ii. Have an output of less than 50 parts per million (ppm) calculated as carbon with no dilution; (B) The emission control system meets the requirements of the applicable source rule of the District’s Regulation XI. The collection system for cleaning in graphic arts and screen printing and cleaning of application equipment used for graphic arts materials and screen printing materials, shall collect at least 70%, by weight, of emissions generated. This control system shall reduce emissions from the emission collection system by at least 95%.
BACT Determination Digital Printing – Liquid Electrophotography Page 9 of 19 District/Agency Best Available Control Technology (BACT)/Requirements San Diego County APCD BACT Source: NSR Requirements for BACT For Digital Printing - Liquid Electrophotography Pollutant Standard VOC No standard NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: Rule 67.16 – Graphic Arts Operations (Effective 5/9/12) This rule applies to all continuous web or single sheet fed graphic arts printing, processing, laminating or drying operations and digital printing operations. This rule has an exemption for digital printing operations. Digital printing operations are exempt from provisions of this rule. However, digital printing operations that meet the definition of a “Large digital printing operation” are required to maintain records. Large digital printing operation is defined as a commercial digital printing operation where a print capacity of any individual printer that uses solvent based inks is 1,000 ft2/hr or higher; or an operation where a print capacity of any individual printer that uses water based or UV inks is 10,000 ft2/hr or higher. Standards For Large Commercial Digital Printing Operations 1. Maintain a current list of graphic arts materials and cleaning materials used; 2. Provide documentation containing the VOC content, less water and exempt compounds of each graphic arts material (excluding thinner), as applied and VOC content of each thinner and cleaning material and/or total VOC vapor pressure, as used 3. Keep monthly records of the type and amount of graphic arts material cleaning material used. Rule 66.1 Miscellaneous Surface Coating Operations and Other Processes Emitting Volatile Organic Compounds (Adopted 2/24/10) This rule is applicable to all surface coating, solvent cleaning or other operations or processes that may result in emissions of VOCs and are not subject to or exempt from, the following rules… (See Rule 66.1 for full list). Exemptions This rule does not apply to digital printing operations [Section(b)(1)(X)].
BACT Determination Digital Printing – Liquid Electrophotography Page 10 of 19 District/Agency Best Available Control Technology (BACT)/Requirements Bay Area AQMD BACT Source: BAAQMD Application # 28111 (See Attachment D) For Digital Printing - Liquid Electrophotography Pollutant Standard VOC Collect and control emissions with an overall emission rate equivalent to 2.5 lb/gal NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: Reg. 8, Rule 20 Graphic Arts Printing and Coating Operations (Amended 4/12/80) This rule applies to graphic arts operations which is defined as a gravure, publication gravure, flexographic printing, digital printing, screen printing, letterpress, or lithographic printing operation; an associated coating, laminating, or adhesive operation to produce a printed product; and the use of solvents for any surface preparation or cleanup for any of the operations stated above. However, per Section 8-20-120, Digital Printing is exempt from the flexographic, gravure, publication gravure, letterpress, and lithographic product limit requirements (Section 8-20-302) and the cleaning product requirements (Section 8-20-309) of this rule. Solvent Evaporative Loss Minimization: Per Section 8-20-320, the requirements of this Section shall apply to the use of solvent for surface preparation and cleanup and to the use, mixing, storage, and disposal of ink, coating or adhesive: 1. An owner or operator shall not use open containers for the storage or disposal of cloth or paper impregnated with organic compounds that are used for surface preparation, cleanup or ink, coating or adhesive removal. 2. An owner or operator shall not store in open containers spent or fresh organic compounds used for surface preparation, cleanup or removal of inks, coatings, or adhesives. 3. An owner or operator shall not leave containers of ink, coating, adhesive or fountain solution open when not in use. Reg. 8, Rule 4 General Solvent and Surface Coating Operations (Amended
BACT Determination Digital Printing – Liquid Electrophotography Page 11 of 19 District/Agency Best Available Control Technology (BACT)/Requirements Bay Area AQMD 10/16/02) This rule applies to the use of solvents and surface coatings in any operation other than those specified by other Rules of Regulation 8. Digital printing is regulated by Reg. 8 Rule 20 Graphics Art Printing. Therefore, Digital printing would be exempt from the requirements of this rule. San Joaquin Valley APCD BACT Source: SJVUAPCD BACT Clearinghouse For Digital Printing - Liquid Electrophotography Pollutant Standard VOC No standard NOx No standard SOx No standard PM10 No standard PM2.5 No standard CO No standard T-BACT There are no T-BACT standards published in the clearinghouse for this category. RULE REQUIREMENTS: Rule 4607 Graphic Arts and Paper, Film, Foil and Fabric Coatings (Amended 12/18/08) This rule applies to any graphics arts printing operation, to digital printing operations, and to any paper, film, foil, or fabric coating operation and to the organic solvent cleaning materials and processes associated with such operations. According to Section 4.0, the requirements of this rule, except for the recordkeeping requirements of Section 6.1, shall not apply to digital printers and digital printing operations. Rule 4663 Organic Solvent Cleaning, Storage, and Disposal (Amended 9/20/07) The purpose of this rule is to limit the emissions of volatile organic compounds (VOCs) from organic solvent cleaning and from the storage and disposal of solvents and waste solvent materials. This rule exempts any source that is subject to or specifically exempted from the Rules listed in Section 4.3. Section 4.3 lists Rule 4607 (Graphic Arts). Therefore, digital printing is exempt from Rule 4663 Organic Solvent Cleaning, Storage, and Disposal. The following control technologies have been identified and are ranked based on stringency:
BACT Determination Digital Printing – Liquid Electrophotography Page 12 of 19 SUMMARY OF ACHIEVED IN PRACTICE CONTROL TECHNOLOGIES Pollutant Standard VOC For Printing Operations: 1. Integral air pollution control system, consisting of an oil/water separator and refrigerated condenser, with an assumed control efficiency of 80%(A) [SCAQMD] 2. Collect and control equipment with an overall emission rate equivalent to 2.5 lb/gal [BAAQMD] 3. Comply with VOC emission standards of SMAQMD Rule 466. [SMAQMD] 4. Comply with VOC emission standards of SCAQMD Rule 1171. [SCAQMD] 5. Comply with VOC emission standards BAAQMD Regulation 8, Rule 20, Sections 8-20-320 and 8-20-308. [BAAQMD] For Organic Solvent Operations: Comply with VOC emission standards of SMAQMD Rule 441. [SMAQMD] NOx N/A – [SMAQMD, SCAQMD, SDCAPCD, BAAQMD, SJVAPCD, ARB, EPA] SOx N/A – [SMAQMD, SCAQMD, SDCAPCD, BAAQMD, SJVAPCD, ARB, EPA] PM10 N/A – [SMAQMD, SCAQMD, SDCAPCD, BAAQMD, SJVAPCD, ARB, EPA] PM2.5 N/A – [SMAQMD, SCAQMD, SDCAPCD, BAAQMD, SJVAPCD, ARB, EPA] CO N/A – [SMAQMD, SCAQMD, SDCAPCD, BAAQMD, SJVAPCD, ARB, EPA] T-BACT (VOC) N/A – [SMAQMD, SCAQMD, SDCAPCD, BAAQMD, SJVAPCD, ARB, EPA] (A) A control efficiency of 80% is based on EPA’s Air Pollution Control Cost Manual for Refrigerated Condensers, pg 2-15 (https://www3.epa.gov/ttn/catc/dir1/cs3-1ch2.pdf). An integral air pollution control system consisting of an oil/water separator and refrigeration condenser is considered the most stringent control. Both SCAQMD and BAAQMD performed an evaluation on HP Indigo model printers which use the integral air pollution control system. SCAQMD determined that the control system is considered BACT while BAAQMD considers BACT to be an overall emission control system equivalent to less than 2.5 lb/gal. In BAAQMD’s evaluation the integral air pollution system was calculated to have an overall emission control system equivalent to 0.55 lb/gal (see Attachment D). Since there is limited test data on these control systems, a standard percent control will be reevaluated as more systems as more test data becomes available. For now, an estimation of a 80% control efficiency will be used based on EPA’s Air Pollution Control Cost Manual for Refrigerated Condensers. Digital printing is exempt from all districts’ graphic art rules and only requires record keeping for solvent and ink/coating usage. However, the digital printing operations would still be subject to solvent cleaning rules of SCAQMD, SMAQMD, and BAAQMD. The emission limits for solvent cleaning activities related to digital printing are consistent across SCAQMD Rule 1171 and SMAQMD Rule 466. Although the emission limits for solvent cleaning are the same for SCAQMD and SMAQMD Rules, the SCAQMD Rule exempts printing pre-press or graphic arts pre-press areas from the solvent cleaning limits and SMAQMD does not. Therefore, SMAQMD’s rule is considered more stringent than SCAQMD’s Rule. BAAQMD’s solvent
BACT Determination Digital Printing – Liquid Electrophotography Page 13 of 19 cleaning rule is less stringent with a surface preparation solvent VOC limit of 50 g/l (0.42 lbs/gal) compared to SCAQMD & SMAQMD general solvent cleaning VOC limit of 25 g/l (0.21 lbs/gal). The following control technologies have been identified as the most stringent, achieved in practice control technologies: BEST CONTROL TECHNOLOGIES ACHIEVED IN PRACTICE Pollutant Standard Source VOC For Digital Printing Operations: 1. Integral air pollution control system, consisting of an oil/water separator and refrigerated condenser, with an assumed control efficiency of 80%(A) or equivalent system. 2. For Organic Solvents used with inks, comply with VOC emission limits of SMAQMD Rule 441 (See Table Below) For Solvent Cleaning Operations: Use of materials compliant with SMAQMD Rule 466. SCAQMD & SMAQMD NOx No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB SOx No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB PM10 No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB PM2.5 No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB CO No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB VOC (T-BACT) No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB (A) A control efficiency of 80% is based on EPA’s Air Pollution Control Cost Manual for Refrigerated Condensers, pg 2-15 (https://www3.epa.gov/ttn/catc/dir1/cs3-1ch2.pdf). This assumed control efficiency is subject to change as more test data becomes available. SMAQMD Rule 441 Emission Limits
BACT Determination Digital Printing – Liquid Electrophotography Page 14 of 19 Material Hourly Emission Limit [kg/hr] (lbs/hr) Daily Emission Limit [kg/day] (lbs/day) Organic Materials which come into contact with a flame or is baked, heat-cured or heat-polymerized, in the presence of oxygen [1.4] (3.1) [6.8] (15) Photochemically Reactive Solvents [3.6] (7.9) [18] (39.7) Non-photochemically reactive solvents [200] (441) [1,350] (2,970) B: TECHNOLOGICALLY FEASIBLE AND COST EFFECTIVE (Rule 202, §205.1.b.) Technologically Feasible Alternatives: Any alternative basic equipment, fuel, process, emission control device or technique, singly or in combination, determined to be technologically feasible by the Air Pollution Control Officer. Low VOC Ink Discussion BAAQMD released the Bay Area 2010 Clean Air Plan and discussed possible control techniques. The possibility of low VOC inks were discussed but it was found that no low VOC inks are currently available. BAAQMD states that “Lower VOC inks may be able to be developed, although the necessary properties of inks for some types of digital printing may preclude low-VOC formulations.” Therefore, low VOC inks currently aren’t technologically feasible. The table below shows the technologically feasible alternatives identified as capable of reducing emissions beyond the levels determined to be “Achieved in Practice” as per Rule 202, §205.1.a. Pollutant Technologically Feasible Alternatives VOC VOC control device with 98.5% overall system efficiency(A) NOx No other technologically feasible option identified SOx No other technologically feasible option identified PM10 No other technologically feasible option identified PM2.5 No other technologically feasible option identified CO No other technologically feasible option identified VOC (T-BACT) No other technologically feasible option identified (A) An overall system efficiency of 98.5% is based on technologies such as carbon adsorbers and thermal oxidizers. Cost Effective Determination:
BACT Determination Digital Printing – Liquid Electrophotography Page 15 of 19 After identifying the technologically feasible control options, a cost analysis is performed to take into consideration economic impacts for all technologically feasible controls identified. Maximum Cost per Ton of Air Pollutants Controlled 1. A control technology is considered to be cost-effective if the cost of controlling one ton of that air pollutant is less than the limits specified below: Pollutant Maximum Cost ($/ton) VOC 17,500 NOX 24,500 PM10 11,400 SOX 18,300 CO TBD if BACT triggered Cost Effectiveness Analysis Summary The cost analysis was processed in accordance with the EPA OAQPS Air Pollution Control Cost Manual (Sixth Edition). The sales tax rate was based on the District’s standard rate of 8.5% as approved on 10/17/16. The electricity (11.24 cents/kWh) and natural gas (6.41 dollars/1,000 cubic feet) rates were based on an industrial application as approved by the District on 10/17/16. The life of the equipment was based on the EPA cost manual recommendation. The interest rate was based on the previous 6-month average interest rate on United States Treasury Securities (based on the life of the equipment) and addition of two percentage points and rounding up to the next higher integer rate. The labor (Occupation Code 51-5112: Printing press operators) and maintenance (Occupation Code 49-9099: Installation, maintenance, and repair workers, all other) rates were based on data from the Bureau of Labor Statistics. Background: The digital printing operation will be reviewed by using the pressroom as the emission source and updating the cost inputs in accordance with the EPA OAQPS Air Pollution Control Cost Manual (Sixth Edition). This BACT will only look at the price of the control systems. This will ensure that a single digital printer enclosed in a small enough room to not require the addition of a hood or a permanent total enclosure to be covered under this BACT. The addition of a hood would increase the cost of the system due to the cost of the hood and associated equipment (ducting, louvers, dampers, air make-up units, etc.). Section 2 Chapter 1 Hoods, Ductwork and Stacks of the Cost Manual includes cost estimating methods that would increase the cost of the system. The addition of the hood would also require an increase in flowrate. A 6 ft x 6 ft hood (assumed to just cover the printing section of the printer) and 5 feet above the printing mechanism, would require a flowrate of 33,600 ft3/min (based on equation 1.24 (Q = 1.4Pxuc) of this section). This would require bigger and more expensive emissions control system. Operational costs of the system would also be higher. Section 2, Chapter 3, Permanent Total Enclosures (PTE) of the Cost Manual, includes cost estimating information for enclosing a unit. This section of the Cost Manual includes cost information (cost of walls/ft2, installation costs of walls, rollup door costs, makeup air fans,
BACT Determination Digital Printing – Liquid Electrophotography Page 16 of 19 etc.) that would increase the cost of the control system. The PTE would also require additional ducting work to handle the higher air flow to the control device, which would further increase the cost. Therefore, the cost of just the control device is a conservative estimate. Basic assumptions: 1) Single digital printing press. 2) Press room dimensions: 40’W x 60’L x 20’H (because the press room is relatively small, a hood or smaller full enclosure is not necessary) 3) The press room is assumed to be the enclosure with a collection efficiency of 100%, venting through a general ventilation system to a control device capable of achieving a 98.5% control efficiency. Therefore, the carbon adsorption system will have an over-all collection/control efficiency of 98.5%. This is similar to the collection/control efficiency listed as technologically feasible in the BAAQMD BACT Guideline 83.1. 4) General ventilation with an 8,000 CFM blower (10 air changes per hour). 5) Cost calculations and assumptions are based on the EPA Air Pollution Control Cost Manual. Carbon Adsorption System Equipment Life = 10 years Total Capital Investment = $231,299.51 Annualized Total Capital Investment = $43,556.61 per year Direct Annual Cost = $18,801.19 per year Indirect Annual Cost = $12,482.97 per year Total Annual Cost = $74,840.77 per year VOC Removed = 4.28 tons per year Cost of VOC Removal = $17,500.97 per ton reduced A detailed calculation of the cost effectiveness for VOC removal with a carbon absorber is shown in Attachment A. Uncontrolled VOC emissions of 8,683 lb/year or greater is the cost-effective threshold for control equipment using carbon absorption control technology. Thermal Oxidizer: Equipment Life = 10 years Total Capital Investment = $401,329 Direct Annual Cost = $152,437.41 per year Indirect Annual Cost = $94,909.62 per year Total Annual Cost = $247,347.02 per year VOC Removed = 14.13 tons per year
BACT Determination Digital Printing – Liquid Electrophotography Page 17 of 19 Cost of VOC Removal = $17,500.43 per ton reduced A detailed calculation of the cost effectiveness for VOC removal with a thermal oxidizer is shown in Attachment B. Uncontrolled VOC emissions of 28,698 lb/year or greater is the cost-effective threshold for control equipment using thermal oxidation control technology. Conclusion: In this analysis, different emission operating levels are presented with the corresponding total cost per ton of VOC controlled using either a carbon adsorption control or a thermal oxidizer. Uncontrolled VOC emission level of 8,683 lb per year or greater must be reached in order for the carbon absorption control option to be cost effective. Uncontrolled VOC emission level of 28,698 lb per year or greater must be reached in order for a thermal oxidizer to be cost effective. The emissions level for the cost effectiveness of controls is based on the District cost effective limit for VOC of $17,500 per ton controlled. C: SELECTION OF BACT TABLE 1: BACT (#147) FOR DIGITAL PRINTING – LIQUID ELECTROPHOTOGRAPHY < 8,683 LBS UNCONTROLLED VOC PER YEAR Pollutant Standard Source VOC 1. Integral air pollution control system, consisting of an oil/water separator and refrigerated condenser, with an assumed control efficiency of 80%(A) or equivalent system. 2. Use of materials compliant with SMAQMD Rule 466 – Solvent Cleaning. 3. Comply with VOC emission standards of SMAQMD Rule 441 – Organic Solvents. SMAQMD,SCAQMD, BAAQMD NOx No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB SOx No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB PM10 No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB PM2.5 No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB CO No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB (A) A control efficiency of 80% is based on EPA’s Air Pollution Control Cost Manual for Refrigerated Condensers, pg 2-15 (https://www3.epa.gov/ttn/catc/dir1/cs3-1ch2.pdf). This assumed control efficiency is subject to change as more test data becomes available.
BACT Determination Digital Printing – Liquid Electrophotography Page 18 of 19 TABLE 2: BACT (#180) FOR DIGITAL PRINTING – LIQUID ELECTROPHOTOGRAPHY ≥ 8,683 LBS UNCONTROLLED VOC PER YEAR Pollutant Standard Source VOC 1. A VOC control device that has an overall system efficiency (collection and destruction) of at least 98.5% for VOC. 2. Use of materials compliant with SMAQMD Rule 466 – Solvent Cleaning. 3. Comply with VOC emission standards of SMAQMD Rule 441 – Organic Solvents. SMAQMD NOx No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB SOx No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB PM10 No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB PM2.5 No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB CO No Standard SMAQMD, SCAQMD, SJVUAPCD, SDCAPCD, BAAQMD, EPA, ARB
BACT Template Version 071315 Attachment A Cost Effectiveness Analysis for Carbon Adsorption
BACT Template Version 071315 COST EFFECTIVENESS ANALYSIS FOR CARBON ADSORPTION This cost effectiveness analysis was performed using EPA's OAQPS Control Cost Manual EPA Publication No. 452/B-02-001 Carbon Adsorbers (9/1999) FACILITY NAME: Office of State Publishing LOCATION: 1050 Richards Blvd., Sacramento, CA 95811 PERMIT NO.: 24724 EQUIPMENT DESCRIPTION: VOC Parameters VOC of concern (using the physical properties of toluene) Various Cost of pure VOC ($/ton) 100 Molecular weight of VOC (Refer to Control Cost Manual, pg 3-63) 92.13 Emission rate (lbs/hr - inlet) 4.17 Emission rate (lbs/yr - inlet) 8683 Inlet concentration (ppm) 38 k factor (Refer to Control Cost Manual, Table 1.1 pg 1-9) 0.551 m factor (Refer to Control Cost Manual, Table 1.1 pg 1-9) 0.11 Partial pressure (psi) 0.000552279 Gas Parameters Total gas flow rate (acfm - inlet) 8,000 Total gas pressure (psi - inlet) 14.7 Equipment Parameters Removal efficiency (%) 98.5% Adsorption time (hours) 8 Desorption time (hours) 8 Number of adsorbing beds 1 Number of Desorbing beds 1 Equipment life (years) 10 Operating Parameters Hours per day 8 Days per week 5 Weeks per year 52 Carbon Requirements Carbon working capacity (lb VOC/lb carbon) (k factor)*((partial pressure)^(m factor))/2 0.121 Amount of carbon needed (lbs) (Emission Rate)*(hrs/day)/(Carbon Working Capacity) 553
Carbon cost ($1/lb carbon)*(lbs of carbon needed) $1,107 Carbon life (years) 5 Adsorber Vessel Dimension and Cost Superficial bed velocity (ft/min) 75 Diameter of each vessel (ft) 0.33 Length of each vessel (ft) 324 Surface area (sq. ft) 335 Fm factor (see Control Cost Manual, Table 1.2, p. 1-21 - Stainless Steel) 1.3 Cost per vessel $32,471.47 Adsorber Equipment Cost $116,327.36 Direct Costs: Purchased Equipment Cost Adsorber and auxiliary equipment To be conservative assume auxiliary costs = $0 $116,327.36 Instrumentation 1% of equipment cost $11,632.74 Sales taxes 8.5% of equipment cost $9,887.83 Freight 5% of equipment cost $5,816.37 Total Purchased Equipment Cost $143,664.29 Direct installation costs Foundations & supports 8% of total equipment cost $11,493.14 Handling & erection 14% of total equipment cost $20,113.00 Electrical 4% of total equipment cost $5,746.57 Piping 2% of total equipment cost $2,873.29 Insulation 1% of total equipment cost $1,436.64 Painting 1% of total equipment cost $1,436.64 Direct installation costs $43,099.29 Total Direct Cost Total equipment cost + Direct installation costs $186,763.58 Indirect Costs: Indirect Costs (installation) Engineering 10% of total equipment cost $14,366.43 Construction and field expenses 5% of total equipment cost $7,183.21 Contractor fees 10% of total equipment cost $14,366.43 Start-up 2% of total equipment cost $2,873.29 Performance test 1% of total equipment cost $1,436.64 Contingencies 3% of total equipment cost $4,309.93 Total Indirect Costs $44,535.93
Total Capital Investment total direct cost + total indirect costs $231,299.51 Interest Rate 0.05 Equipment Life (years) 10 Capital Recovery Factor (CRF) 0.1295 Capital recovery cost (total capital investment)*(CRF) $29,954.34 Capital Recovery Inflation adjustment (capital recovery cost)*[(1+0.0199)^19] $43,556.61 (Avg. interest rate is from the Bureau of Labor Statistics website) Direct Annual Costs Operator wage ($/hr) 18.01 Maintenance wage ($/hr) 20.13 operator hour (hrs/shift) 0.5 shifts per day (shift/day) 2 days of work per year (days/year) 260 Operator labor Operator (labor wage)*(hours/shift)*(shifts/day)*(days/year) $4,682.60 Supervisor 15% of operator labor $702.39 Maintenance Maintenance labor (labor wage)*(hours/shift)*(shifts/day)*(days/year) $5,233.80 Materials 100% of maintenance labor $5,233.80 Utilities System Fan (kWh/yr) Refer to EPA cost manual 4917 Bed drying/cooling fan (kWh/yr) Refer to EPA cost manual 42 Cooling water pump (kWh/yr) Refer to EPA cost manual 52 Total Power Used (kWh/yr) 5011 Electricity Cost 0.138 $/kWh = District Practice $691.52 Steam Cost $1,770.32 Cooling water $202.41 Carbon Replacement Interest Rate 0.05 Carbon Life (yrs) 5 Capital Recovery Factor 0.2310 Replacement Labor CRF*$0.05/lb*carbon needed $6.39
Carbon Cost CRF*initial carbon cost*1.0875 $277.97 Total Direct Annual Costs $18,801.19 Indirect Annual Costs Overhead 60% of maintenance labor and materials $3,230.99 Administrative Charges 2% of Total Capital Investment $4,625.99 Property Tax 1% of Total Capital Investment $2,313.00 Insurance 1% of Total Capital Investment $2,313.00 Total Indirect Annual Costs $12,482.97 Total Annual Costs CRC and Inflation Total Capital Investment + Total Direct Annual Costs + Total Indirect Annual Costs $74,840.77 Tons VOC reduced (Emission Rate)*(reduction efficiency)*(hrs/yr)/2000 4.28 Cost of VOC Removal (Total Annual Costs)/(Tons VOC Controlled) $17,500.97
Attachment B Cost Effectiveness Analysis for Thermal Oxidizers
COST EFFECTIVENESS ANALYSIS FOR THERMAL INCINERATION This cost effectiveness analysis was performed using EPA's OAQPS Control Cost Manual EPA publication No. 452/B-02-001 Incinerators (9/2000) FACILITY NAME: Office of State Publishing LOCATION: 1050 Richards Blvd., Sacramento, CA 95811 PERMIT NO.: 24724 EQUIPMENT DESCRIPTION: Digital Printing Press VOC Parameters VOC of concern (Using the physical properties of toluene) Various Molecular weight of VOC 92.13 Heat of combustion (Btu/lb) 17,601 Heating value of VOC (Btu/scf) 4,074 Emission rate (lbs/hr - inlet) 13.8 Emission rate (lbs/year - inlet) 28,698 Inlet concentration (ppm) 120 Gas Parameters Total gas flow rate (scfm - inlet) 8000 Total gas pressure (psi - inlet) 14.7 Inlet gas temperature (deg F) 71 Equipment Parameters Level of energy recovery (0%, 35%, 50% or 70%) 70% Control efficiency (%) 98.5% Equipment life (years) 10 Operating Parameters Hours per day 8 Days per week 5 Weeks per year 52 Shifts per day 1 Incinerator Parameters Volumetric heat of combustion of effluent (Btu/scf) 0.49 Heat of combustion per pound of effluent (Btu/lb) 6.62 Temperature Required for incineration (deg F) 1,500.00 Gas temperature at exit of pre-heater (deg F) 1,071.30 Effluent gas temperature (deg F) 499.7 Electricity Usage Price of electricity ($/kWh) $0.11 System fan (kWh/yr) 61,651.20 Total Power Used (kWh/yr) 61,651.20 Gas Usage Price of gas ($/1000 cu.ft.) $6.41
Auxiliary fuel required (scfm) 171.98 CAPITAL COST Direct Costs: Incinerator $201,840 Auxiliary equipment (if not included above) $0 Equipment Cost (A) $201,840 Instrumentation (0.1A if not included above) $20,184 Sales taxes (0.085A) $17,156 Freight (0.05A) $10,092 Total Equipment Cost (B) $249,273 Direct Installation Costs: Foundation & Supports (0.08B) $19,942 Handling & erection (0.14B) $34,898 Electrical (0.04B) $9,971 Piping (0.02B) $4,985 Insulation for duct work (0.01B) $2,493 Painting (0.01B) $2,493 Direct Installation Cost $74,782 Site preparation $0 Facilities & buildings $0 Total Direct Costs $324,054 Indirect Costs (installation) Engineering (0.10B) $24,927 Construction & field expenses (0.05B) $12,464 Contractor fees (0.10B) $24,927 Start-up (0.02B) $4,985 Performance test (0.01B) $2,493 Contingencies (0.03B) $7,478 Total Indirect Costs $77,275 TOTAL CAPITAL INVESTMENT $401,329 ANNUAL COST Direct Annual Costs Operating Cost
Operator (@ $18.01/hr & .5 hr per shift ) $2,341.30 Supervisor (15% of operator) $351.20 Operating materials $0.00 Maintenance Labor (@20.13/hr & .5 hr per shift) $2,616.90 Material (same as labor) $2,616.90 Utilities Price of electricity ($/kWh) $0.11 Price of gas ($/1000 cu.ft.) $6.41 Electricity ($/yr) $6,929.59 Natural Gas ($/yr) $137,581.52 Total Direct Costs $152,437.41 Indirect Annual Costs Overhead $4,755.78 Administrative charges $8,026.58 Property taxes $4,013.29 Insurance $4,013.29 Interest rate (%) 5% Equipment life (years) 10 CRF 0.1295 Capital recovery $51,973.93 Capital Recovery Inflation Adjustment $74,100.68 Total Indirect Costs $94,909.62 TOTAL ANNUAL COST $247,347.02 Annual Cost ($/yr) $247,347.02 Annual Emissions Reductions (tons/yr) 14.13 (annual emissions based on BACT determination limit for add-on controls) COST PER TON OF VOCs REDUCED ($/ton) $17,500.43
Attachment C SCAQMD Evaluation A/N 2562397

Attachment D BAAQMD Evaluation Application #28111

Attachment E Public Notice Comment Memo
SACRAMENTO METROPOLITAN AIR QUALITY MANAGEMENT DISTRICT Intra-Office Memo To : FILE (BACT Determinations #147 & #180) From : Jeffrey Quok Date : January 3, 2018 Subject : Public Notice for BACT Determinations #147 & #180 No comments were received during the public noticing period (12/1/17-1/2/18).
Safety Data Sheet______________________________________________________________________________________________ActivePage 1 / 7SDS # : F-60040Aqueous Ink - MagentaIssuing Date 2018-10-02Revision Date 2019-05-13Version 11. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct Identifier Product NamePart no.008R13258ColorMagentaPure substance/mixtureMixtureRelevant identified uses of the substance or mixture and uses advised against Recommended UseInk jet printingDetails of the supplier of the safety data sheet For further information, please contactEmergency telephoneSafety Information US: [phone]Chemical Emergency only (Chemtrec) [phone]For the most current documenthttps://safetysheets.business.xerox.com2. HAZARDS IDENTIFICATIONClassification of the substance or mixture Not classifiedLabel elements Symbol(s)None requiredSignal WordNoneHazard StatementsNone requiredPrecautionary StatementsNone requiredOther hazards Contains a chemical that can cause an allergic reaction in susceptible people3. COMPOSITION/INFORMATION ON INGREDIENTSMixtures HF Aqueous InkforXerox® Baltoro™ HF InkJet PressSupplierXerox CorporationWebster, NY 14580Contact personManager, Environment, Health, Safety & SustainabilityE-mail [e-mail]607E26180BR547
______________________________________________________________________________________________SDS # : F-60040Aqueous Ink - MagentaPage 2 / 7Chemical NameCAS No.Weight %Classification (Reg.1272/2008)Hazard StatementsWater7732-18-550-60----Propylene glycol57-55-615-35----1,2-Hexanediol6920-22-5<8Eye Irrit. 2H319Magenta pigmentProprietary<5----Triethanolamine102-71-6<1----1,2-Benzisothiazolin-3-one2634-33-5<0.05Acute Tox. 4Skin Irrit. 2Eye Dam. 1Skin Sens. 1Aquatic Acute 1H302H315H318H317H400"--" indicates no classification or hazard statements apply.Full text of H- statements: see section 164. FIRST AID MEASURESDescription of first-aid measures General adviceIN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL CARE.Eye contactImmediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes, If eye irritation persists, consult a specialistSkin contactWash off with warm water and soap, Get medical attention if irritation develops and persistsInhalationMove to fresh air, Get medical attention immediately if symptoms occurIngestionIf swallowed, do not induce vomiting - seek medical adviceMost important symptoms and effects, both acute and delayed Acute toxicityEyesMay cause slight irritationSkinNo known effectInhalationNo known effectIngestionNo known effectChronic toxicityRepeated contact may cause allergic reactions in very susceptible personsMain symptoms Overexposure may cause:Eye irritationSkin irritationIndication of immediate medical attention and special treatment needed Protection of first-aidersNo special protective equipment requiredNotes to physicianTreat symptomatically5. FIRE-FIGHTING MEASURESExtinguishing media Suitable extinguishing mediaWater spray, Foam, Carbon dioxide (CO2)Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fireSpecial hazards arising from the substance or mixture None in particularHazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors607E26180BR547
______________________________________________________________________________________________SDS # : F-60040Aqueous Ink - MagentaPage 3 / 7Advice for fire-fighters Wear self-contained breathing apparatus and protective suitOther information Flash point > 100 °C / > 212 °F6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures Avoid contact with the skin and the eyes, Use personal protective equipmentEnvironmental precautions Should not be released into the environment, Do not allow material to contaminate ground water systemMethods and material for containment and cleaning up Methods for containmentPrevent further leakage or spillage if safe to do so, Dike to collect large liquid spills, Prevententry into waterways, sewers, basements or confined areasMethods for cleaning upSoak up with inert absorbent material, Prevent product from entering drainsReference to other sections See section 12 for additional ecological informationSee Section 13 for additional information7. HANDLING AND STORAGEPrecautions for safe handling Advice on safe handlingHandle in accordance with good industrial hygiene and safety practice, Avoid contact withskin and eyes, Ensure adequate ventilation, Handle and open container with careConditions for safe storage, including any incompatibilities Technical measures and storageconditionsKeep container tightly closed in a dry and well-ventilated place, Keep out of the reach ofchildren, Handle with careIncompatible productsAlkali metals, Strong oxidizing agents, PeroxidesSpecific end uses Ink jet printing8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters Exposure LimitsChemical NameACGIH TLVOSHA PELTriethanolamineTWA: 5 mg/m3Exposure controls Engineering measuresEnsure adequate ventilation, especially in confined areasIndividual protection measures, such as personal protective equipment (PPE) Eye/Face protectionIf splashes are likely to occur, wear:, GogglesHand protectionProtective glovesSkin and body protectionNone under normal use conditionsRespiratory protectionUse only with adequate ventilation.607E26180BR547
______________________________________________________________________________________________SDS # : F-60040Aqueous Ink - MagentaPage 4 / 79. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical properties Boiling point/rangeNot determinedSoftening pointNot applicableEvaporation rateNo information availableFlammability Limits in AirNo information availableVapor pressureNo information availableVapor densityNo information availableSpecific gravityNo information availableWater solubilityDispersablePartition coefficientNo information availableAutoignition temperatureNo information availableDecomposition temperatureNot determinedViscosity5-7 mPa.s @ 25 ° CExplosive propertiesNot explosiveOxidizing propertiesNot applicableOther information None10. STABILITY AND REACTIVITYReactivity No dangerous reaction known under conditions of normal useChemical stability Stable under normal conditions.Possibility of hazardous reactions Hazardous reactionsNone under normal processingHazardous polymerizationHazardous polymerization does not occurConditions to avoid Strong oxidizing agents, Extremes of temperature and direct sunlightIncompatible Materials Alkali metals, Strong oxidizing agents, PeroxidesHazardous decomposition products Undefined, but may include toxic oxides of carbon and nitrogen11. TOXICOLOGICAL INFORMATIONInformation on toxicological effects Acute toxicity Product InformationNo acute toxicity information is available for this productAppearanceOpaqueOdorSlightPhysical stateLiquidOdor thresholdNo information availableColorMagentapH 7-9.5Flash point > 100 °C / > 212 °F607E26180BR547
______________________________________________________________________________________________SDS # : F-60040Aqueous Ink - MagentaPage 5 / 7IrritationMay cause eye irritationComponent InformationChemical NameOral LD50Dermal LD50LC50 InhalationPropylene glycol20 g/kg ( Rat )20800 mg/kg ( Rabbit )Magenta pigment23 g/kg ( Rat )3 g/kg ( Rabbit )Triethanolamine4190 mg/kg ( Rat )20 mL/kg ( Rabbit )16 mL/kg ( Rat )1,2-Benzisothiazolin-3-one1020 mg/kg ( Rat )Chronic toxicity SensitizationContains a chemical that can cause an allergic reaction in susceptible peopleNeurological EffectsNo information availableTarget organ effectsNo information availableCMR Effects Mutagenic effectsNo information availableReproductive toxicityNo information availableCarcinogenicityContains no ingredient listed as a carcinogenOther toxic effects Aspiration HazardNo information available12. ECOLOGICAL INFORMATIONToxicity Acute Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Chronic Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Component InformationChemical NameToxicity to algaeToxicity to fishToxicity tomicroorganismsToxicity to daphnia andother aquatic invertebratesPropylene glycol19000 mg/L EC50 96 h(Pseudokirchneriellasubcapitata)LC50= 51600 mg/LOncorhynchus mykiss 96 hLC50= 51400 mg/LPimephales promelas 96 hLC50 41 - 47 mL/LOncorhynchus mykiss 96 hLC50= 710 mg/LPimephales promelas 96 hEC50 > 1000 mg/L 48 hEC50 > 10000 mg/L 24 hTriethanolamine216 mg/L EC50 72 h(Desmodesmussubspicatus) 169 mg/L EC5096 h (Desmodesmussubspicatus)LC50 10600 - 13000 mg/LPimephales promelas 96 hLC50> 1000 mg/LPimephales promelas 96 hLC50 450 - 1000 mg/LLepomis macrochirus 96 hEC50 = 1386 mg/L 24 hPersistence and degradability No product level data availableBioaccumulative potential No product level data availableMobility in soil Soluble in waterComponent InformationChemical Namelog PowTriethanolamine-2.531,2-Benzisothiazolin-3-one1.3607E26180BR547
______________________________________________________________________________________________SDS # : F-60040Aqueous Ink - MagentaPage 6 / 7Other adverse effects No information available13. DISPOSAL CONSIDERATIONSWaste treatment methods Waste Disposal MethodsDo not dispose of waste into sewerDispose of in accordance with all applicable local and national environmental laws andregulationsContaminated packagingEmpty containers should be taken to an approved waste handling site for recycling ordisposalCalifornia Waste StatusThis product does not contain any substances listed with the State of California as a hazardous waste.14. TRANSPORT INFORMATIONThis material is not regulated as a Hazardous Material (Dangerous Good) under 49 CFR, IATA/ICAO, IMO/IMDG, or TDG15. REGULATORY INFORMATIONSafety, health and environmental regulations/legislation specific for the substance or mixture OSHA Regulatory StatusThis material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)Canada This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (HPR),and the SDS contains all the information required by the HPR.International Inventories TSCACompliesDSL/NDSLCompliesU.S. Federal Regulations SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean AirAct:Chemical NameCAS No.Weight %HAPS dataVOC ChemicalsClass 1 OzoneDepletorsClass 2 OzoneDepletorsPropylene glycol57-55-615-35Group ITriethanolamine102-71-6<1Group ICERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material607E26180BR547
______________________________________________________________________________________________SDS # : F-60040Aqueous Ink - MagentaPage 7 / 7US State Regulations California Proposition 65This product does not contain any Proposition 65 chemicalsU.S. State Right-to-Know RegulationsThis product is subject to U.S. State Right-to-know regulations as noted below.Chemical NameMassachusettsNew JerseyPennsylvaniaIllinoisRhode IslandWaterXPropylene glycolXXTriethanolamineXXX16. OTHER INFORMATIONIssuing Date2018-10-02Revision Date2019-05-13Revision NoteInitial ReleaseFull text of H-Statements referred to under sections 2 and 3H302 - Harmful if swallowedH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH319 - Causes serious eye irritationH400 - Very toxic to aquatic lifeDisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. Theinformation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered as a warranty or quality specification. The information relates only to the specific material designated and may not bevalid for such material used in combination with any other material or in any process, unless specified in the text.end607E26180BR547
Safety Data Sheet______________________________________________________________________________________________ActivePage 1 / 7SDS # : F-60038Aqueous Ink - BlackIssuing Date 2018-10-02Revision Date 2019-05-08Version 11. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct Identifier Product NamePart no.008R13256ColorBlackPure substance/mixtureMixtureRelevant identified uses of the substance or mixture and uses advised against Recommended UseInk jet printingDetails of the supplier of the safety data sheet For further information, please contactEmergency telephoneSafety Information US: [phone]Chemical Emergency only (Chemtrec) [phone]For the most current documenthttps://safetysheets.business.xerox.com2. HAZARDS IDENTIFICATIONClassification of the substance or mixture Serious eye damage/eye irritationCategory 2Label elements Symbol(s)Signal WordWarningHazard StatementsH319 - Causes serious eye irritationPrecautionary StatementsP280 - Wear protective gloves/protective clothing/eye protection/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.HF Aqueous InkforXerox® Baltoro™ HF InkJet PressSupplierXerox CorporationWebster, NY 14580Contact personManager, Environment, Health, Safety & SustainabilityE-mail [e-mail]607E26160BR547
______________________________________________________________________________________________SDS # : F-60038Aqueous Ink - BlackPage 2 / 7Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attentionOther hazards Contains a chemical that can cause an allergic reaction in susceptible people3. COMPOSITION/INFORMATION ON INGREDIENTSMixtures Chemical NameCAS No.Weight %Classification (Reg.1272/2008)Hazard StatementsWater7732-18-550-60----Propylene glycol57-55-615-35----1,2-Hexanediol6920-22-5<15Eye Irrit. 2H319Carbon black1333-86-4<8----Triethanolamine102-71-6<1----1,2-Benzisothiazolin-3-one2634-33-5<0.05Acute Tox. 4Skin Irrit. 2Eye Dam. 1Skin Sens. 1Aquatic Acute 1H302H315H318H317H400"--" indicates no classification or hazard statements apply.Full text of H- statements: see section 164. FIRST AID MEASURESDescription of first-aid measures General adviceIN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL CARE.Eye contactImmediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes, If eye irritation persists, consult a specialistSkin contactWash off with warm water and soap, Get medical attention if irritation develops and persistsInhalationMove to fresh air, Get medical attention immediately if symptoms occurIngestionIf swallowed, do not induce vomiting - seek medical adviceMost important symptoms and effects, both acute and delayed Acute toxicityEyesIrritating to eyesSkinNo known effectInhalationNo known effectIngestionNo known effectChronic toxicityRepeated contact may cause allergic reactions in very susceptible personsMain symptoms Overexposure may cause:Eye irritationSkin irritationIndication of immediate medical attention and special treatment needed Protection of first-aidersNo special protective equipment requiredNotes to physicianTreat symptomatically5. FIRE-FIGHTING MEASURES607E26160BR547
______________________________________________________________________________________________SDS # : F-60038Aqueous Ink - BlackPage 3 / 7Extinguishing media Suitable extinguishing mediaWater spray, Foam, Carbon dioxide (CO2)Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fireSpecial hazards arising from the substance or mixture Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vaporsAdvice for fire-fighters Wear self-contained breathing apparatus and protective suitOther information Flash point > 100 °C / > 212 °F6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures Avoid contact with the skin and the eyes, Use personal protective equipmentEnvironmental precautions Should not be released into the environment, Do not allow material to contaminate ground water systemMethods and material for containment and cleaning up Methods for containmentPrevent further leakage or spillage if safe to do so, Dike to collect large liquid spills, Prevententry into waterways, sewers, basements or confined areasMethods for cleaning upSoak up with inert absorbent material, Prevent product from entering drainsReference to other sections See section 12 for additional ecological informationSee Section 13 for additional information7. HANDLING AND STORAGEPrecautions for safe handling Advice on safe handlingHandle in accordance with good industrial hygiene and safety practice, Avoid contact withskin and eyes, Ensure adequate ventilation, Handle and open container with careConditions for safe storage, including any incompatibilities Technical measures and storageconditionsKeep container tightly closed in a dry and well-ventilated place, Keep out of the reach ofchildren, Handle with careIncompatible productsAlkali metals, Strong oxidizing agents, PeroxidesSpecific end uses Ink jet printing8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters Exposure LimitsChemical NameACGIH TLVOSHA PELCarbon blackTWA: 3 mg/m3TWA: 3.5 mg/m3TriethanolamineTWA: 5 mg/m3607E26160BR547Exposure controls
______________________________________________________________________________________________SDS # : F-60038Aqueous Ink - BlackPage 4 / 7Engineering measuresEnsure adequate ventilation, especially in confined areasIndividual protection measures, such as personal protective equipment (PPE) Eye/Face protectionIf splashes are likely to occur, wear:, GogglesHand protectionProtective glovesSkin and body protectionNone under normal use conditionsRespiratory protectionUse only with adequate ventilation.9. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical properties Boiling point/rangeNot determinedSoftening pointNot applicableEvaporation rateNo information availableFlammability Limits in AirNo information availableVapor pressureNo information availableVapor densityNo information availableSpecific gravityNo information availableWater solubilityDispersablePartition coefficientNo information availableAutoignition temperatureNo information availableDecomposition temperatureNot determinedViscosity5-7 mPa.s @ 25 ° CExplosive propertiesNot explosiveOxidizing propertiesNot applicableOther information None10. STABILITY AND REACTIVITYReactivity No dangerous reaction known under conditions of normal useChemical stability Stable under normal conditions.Possibility of hazardous reactions Hazardous reactionsNone under normal processingHazardous polymerizationHazardous polymerization does not occurConditions to avoid Strong oxidizing agents, Extremes of temperature and direct sunlightIncompatible Materials Alkali metals, Strong oxidizing agents, PeroxidesAppearanceOpaqueOdorSlightPhysical stateLiquidOdor thresholdNo information availableColorBlackpH 7-9.5Flash point > 100 °C / > 212 °F607E26160BR547
______________________________________________________________________________________________SDS # : F-60038Aqueous Ink - BlackPage 5 / 7Hazardous decomposition products Undefined, but may include toxic oxides of carbon and nitrogen11. TOXICOLOGICAL INFORMATIONInformation on toxicological effects Acute toxicity Product InformationIrritationIrritating to eyesComponent InformationChemical NameOral LD50Dermal LD50LC50 InhalationPropylene glycol20 g/kg ( Rat )20800 mg/kg ( Rabbit )Carbon black15400 mg/kg ( Rat )3 g/kg ( Rabbit )Triethanolamine4190 mg/kg ( Rat )20 mL/kg ( Rabbit )16 mL/kg ( Rat )1,2-Benzisothiazolin-3-one1020 mg/kg ( Rat )Chronic toxicity SensitizationContains a chemical that can cause an allergic reaction in susceptible peopleNeurological EffectsNo information availableTarget organ effectsNo information availableCMR Effects Mutagenic effectsNo information availableReproductive toxicityNo information availableCarcinogenicitySee "Other Information" in this section.Chemical NameIARCNTPCarbon black2BOther informationThe IARC (International Agency for Research on Cancer) has listed carbon black as "possibly carcinogenic to humans". Theclassification is based on studies evaluating pure, "free" carbon black. In the process of making this product, the small amountof carbon black is dispersed in a liquid and is not expressed as “free” carbon black. Therefore, this classification does notapply to this product.Other toxic effects Aspiration HazardNo information available12. ECOLOGICAL INFORMATIONToxicity Acute Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Chronic Aquatic ToxicityOn available data, substance is not harmful to aquatic life.Component InformationChemical NameToxicity to algaeToxicity to fishToxicity tomicroorganismsToxicity to daphnia andother aquatic invertebratesPropylene glycol19000 mg/L EC50 96 h(Pseudokirchneriellasubcapitata)LC50= 51600 mg/LOncorhynchus mykiss 96 hLC50= 51400 mg/LPimephales promelas 96 hLC50 41 - 47 mL/LOncorhynchus mykiss 96 hLC50= 710 mg/LPimephales promelas 96 hEC50 > 1000 mg/L 48 hEC50 > 10000 mg/L 24 hCarbon blackEC50 > 5600 mg/L 24 hTriethanolamine216 mg/L EC50 72 hLC50 10600 - 13000 mg/LEC50 = 1386 mg/L 24 h607E26160BR547
______________________________________________________________________________________________SDS # : F-60038Aqueous Ink - BlackPage 6 / 7(Desmodesmussubspicatus) 169 mg/L EC5096 h (Desmodesmussubspicatus)Pimephales promelas 96 hLC50> 1000 mg/LPimephales promelas 96 hLC50 450 - 1000 mg/LLepomis macrochirus 96 hPersistence and degradability No product level data availableBioaccumulative potential No product level data availableMobility in soil Soluble in waterComponent InformationChemical Namelog PowTriethanolamine-2.531,2-Benzisothiazolin-3-one1.3Other adverse effects No information available13. DISPOSAL CONSIDERATIONSWaste treatment methods Waste Disposal MethodsDo not dispose of waste into sewerDispose of in accordance with all applicable local and national environmental laws andregulationsContaminated packagingNo special precautions are needed in handling this materialCalifornia Waste StatusThis product does not contain any substances listed with the State of California as a hazardous waste.14. TRANSPORT INFORMATIONThis material is not subject to regulation as a hazardous material for shipping15. REGULATORY INFORMATIONSafety, health and environmental regulations/legislation specific for the substance or mixture OSHA Regulatory StatusThis material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)Canada This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (HPR),and the SDS contains all the information required by the HPR.International Inventories TSCACompliesDSL/NDSLCompliesU.S. Federal Regulations 607E26160BR547SARA 313
______________________________________________________________________________________________SDS # : F-60038Aqueous Ink - BlackPage 7 / 7Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean AirAct:Chemical NameCAS No.Weight %HAPS dataVOC ChemicalsClass 1 OzoneDepletorsClass 2 OzoneDepletorsPropylene glycol57-55-615-35Group ITriethanolamine102-71-6<1Group ICERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this materialUS State Regulations California Proposition 65Carbon black is regulated under California Proposition 65 only if in the form of "airborne, unbound particles of respirable size". Thisproduct does not contain carbon black in the form of "airborne, unbound particles of respirable size". Therefore, the requirementsof Proposition 65 do not apply to this product.Chemical NameCAS No.California Prop. 65Carbon black1333-86-4CarcinogenU.S. State Right-to-Know RegulationsThis product is subject to U.S. State Right-to-know regulations as noted below.Chemical NameMassachusettsNew JerseyPennsylvaniaIllinoisRhode IslandWaterXPropylene glycolXXCarbon blackXXXXTriethanolamineXXX16. OTHER INFORMATIONIssuing Date2018-10-02Revision Date2019-05-08Revision NoteInitial ReleaseFull text of H-Statements referred to under sections 2 and 3H302 - Harmful if swallowedH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH319 - Causes serious eye irritationH400 - Very toxic to aquatic lifeDisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. Theinformation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered as a warranty or quality specification. The information relates only to the specific material designated and may not bevalid for such material used in combination with any other material or in any process, unless specified in the text.end607E26160BR547
Version 8.0 Page n. 1 of 8Revison 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: Large Bottle Ink, 18L, Dye, ID, Y71.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: 6&5((1*UDSKLFDQG3UHFLVLRQ6ROXWLRQV&R/WG6D\DPD6KLQNDLFKL.XPL\DPDFKR.XVHJXQ.\RWR-DSDQ3KRQHQXPEHU)$;QXPEHUDate:13/07/2016Revision:1.01.4. Emergency telephone number 3KRQHQXPEHU0RQ)UL6&5((1*3(XURSH%9$PVWHOYHHQ1HWKHUODQGV3KRQHQXPEHU0RQ)UL6&5((1*3$PHULFDV//&,/$PHULFDVSECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Hazard pictograms: None Hazard statements: None Precautionary statements: None Special Provisions: EUH210 Safety data sheet available on request. EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May produce an allergic reaction. Special provisions according to Annex XVII of REACH and subsequent amendments: None 2.3. Other hazards vPvB Substances: None - PBT Substances: None Other Hazards: No other hazards SECTION 3: Composition/information on ingredients 3.1. Substances No data available 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty Name Ident. Number ClassificationProduct Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data SheetRICOH Pro Ink Cartridge Yellow VC40000 Type A (719320)Company Name :Ricoh Company, Ltd.Department :Safety and Reliability Engineering Department, Quarity Management DivisonAddress :146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007, JapanTelephone Number :055-920-1470, Japan ,Telefax Number :055-920-1479, JapanRicoh USA, IncEnvironmental Sustainability and Product Compliance5 Dedrick Place West Caldwell, NJ 07006 USA1-973-882-2000 or 1-973-882-5218 (For product information)1-800-336-6737 (for emergencies)Telefax Number :E-mail :[e-mail]
Version 8.0 Page n. 2 of 8Revison 1.0 50% ~ 65% Water CAS: 7732-18-5 EC: 231-791-2 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). 5% ~ 7% 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Indexnumber: 603-183-00-0 CAS: 143-22-6 EC: 205-592-6 REACH No.: 01-2119475107-383.3/1 Eye Dam. 1 H318 0.25% ~ 0.5%Triethanol amine CAS: 102-71-6 EC: 203-049-8 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). < 0.05% 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one Indexnumber: 613-088-00-6 CAS: 2634-33-5 EC: 220-120-9 3.1/4/Oral Acute Tox. 4 H302 3.2/2 Skin Irrit. 2 H315 3.3/1 Eye Dam. 1 H318 3.4.2/1-1A-1B Skin Sens. 1,1A,1B H317 4.1/A1 Aquatic Acute 1 H400 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed None 4.3. Indication of any immediate medical attention and special treatment needed Treatment: None SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 3 of 8Revison 1.0 Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3. Methods and material for containment and cleaning up Wash with plenty of water. 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Do not eat or drink while working. See also section 8 for recommended protective equipment. 7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3. Specific end use(s) None in particular SECTION 8: Exposure controls/personal protection 8.1. Control parameters No occupational exposure limit available DNEL Exposure Limit Values No data available PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 8.2. Exposure controls Eye protection: Not needed for normal use. Anyway, operate according good working practices. Protection for skin: No special precaution must be adopted for normal use. Protection for hands: Not needed for normal use. Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 4 of 8Revison 1.0 Respiratory protection: Not needed for normal use. Thermal Hazards: None Environmental exposure controls: None Appropriate engineering controls: None SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance and colour: Yellow Liquid Odour:SlightlyOdour threshold: No data available pH: 8.3 ~ 9.3 at 20 °C Melting point / freezing point: No data available Initial boiling point and boiling range: No data available Solid/gas flammability: No data available Upper/lower flammability or explosive limits: No data available Vapour density: No data available Flash point: Not detected until 100 °C / 212 ° F (closed cup method, ASTM D 3278) Evaporation rate: No data available Vapour pressure: No data available Relative density: No data available Solubility in water: Complete Solubility in oil: No data available Partition coefficient (n-octanol/water): No data available Auto-ignition temperature: No data available Decomposition temperature: No data available Viscosity:< 5 mPa·s at 20 °C Explosive properties: No data available Oxidizing properties: No data available 9.2. Other information Miscibility:No data available Fat Solubility: No data available Conductivity: No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None. SECTION 11: Toxicological information 11.1. Information on toxicological effects Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 5 of 8Revison 1.0 Toxicological information of the mixture: e) germ cell mutagenicity:Test: Mutagenesis - Species: Salmonella Typhimurium and Escherichia coli Negative Toxicological information of the main substances found in the mixture: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 a) acute toxicity:Test: LD50 - Route: Dermal - Species: Rabbit = 3.54 ml/kg - Source: American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. Test: LD50 - Route: Oral - Species: Rat = 5300 mg/kg - Source: Office of Toxic Substances Report. Vol. OTS, Triethanol amine - CAS: 102-71-6 a) acute toxicity:Test: LD50 - Route: Oral - Species: Guinea pig = 2200 mg/kg - Source: "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 114, 1982. Test: LD50 - Route: Oral - Species: Mouse = 5846 mg/kg - Source: Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989. - Notes: GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" KIDNEY, URETER, AND BLADDER: OTHER CHANGES BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Substance(s) listed on the IARC Monographs: Triethanol amine - Group 3. If not differently specified, the information required in Regulation (EU) 2015/830 listed below must be considered as 'No data available': a) acute toxicity;b) skin corrosion/irritation;c) serious eye damage/irritation;d) respiratory or skin sensitisation;e) germ cell mutagenicity;f) carcinogenicity;g) reproductive toxicity;h) STOT-single exposure;i) STOT-repeated exposure;j) aspiration hazard.SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. No data available 12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential No data available 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects None Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 6 of 8Revison 1.0 SECTION 13: Disposal considerations 13.1. Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force.SECTION 14: Transport information 14.1. UN number Not classified as dangerous in the meaning of transport regulations. 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU Information: Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013 Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP) Regulation (EU) n. 618/2012 (ATP 3 CLP) Regulation (EU) n. 487/2013 (ATP 4 CLP) Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Restrictions related to the product: No restriction. Restrictions related to the substances contained: No restriction. Where applicable, refer to the following regulatory provisions : Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): No data available USA Information: TSCA - Toxic Substances Control Act TSCA inventory: all the components are listed on the TSCA inventory. TSCA listed substances: None. SARA - Superfund Amendments and Reauthorization Act Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 7 of 8Revison 1.0 Section 302 – Extremely Hazardous Substances: no substances listed. Section 304 – Hazardous substances: no substances listed. Section 313 – Toxic chemical list: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether. CAA - Clean Air Act CAA listed substances: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether is listed in CAA Section 112, Section 112(b) - HON. California Proposition 65 Substance(s) listed under California Proposition 65: None. NFPA rating: HMIS rating: Canada Information: WHMIS Controlled Product: WHMIS item number from Ingredient Disclosure List : Triethylene glycol: 1625 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether: 1627 Australia Information: Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC New Zealand Information: Hazardous Substances and New Organisms Act 1996: Not regulated 15.2. Chemical safety assessment No SECTION 16: Other information Full text of phrases referred to in Section 3: H318 Causes serious eye damage. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. This safety data sheet has been completely updated in compliance to Regulation 2015/830. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold CCNL - Appendix 1 Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 8 of 8Revison 1.0 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This Safety Data Sheet cancels and replaces any preceding release. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. CAS: Chemical Abstracts Service (division of the American Chemical Society). CLP: Classification, Labeling, Packaging. DNEL: Derived No Effect Level. EINECS: European Inventory of Existing Commercial Chemical Substances. GefStoffVO: Ordinance on Hazardous Substances, Germany. GHS: Globally Harmonized System of Classification and Labeling of Chemicals. HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO). IMDG: International Maritime Code for Dangerous Goods. INCI: International Nomenclature of Cosmetic Ingredients. KSt: Explosion coefficient.LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. LTE: Long-term exposure.NFPA: National Fire Protection Association NOHSC: National Occupational Health and Safety Commission OSHA: Occupational Safety and Health Administration PNEC: Predicted No Effect Concentration. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. STE: Short-term exposure.STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. TLV: Threshold Limiting Value. TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). WGK: German Water Hazard Class. WHMIS: Workplace Hazardous Materials Information System Product Name :RICOH Pro Ink Cartridge Yellow VC40000 Type ASDS Number :719320Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 1 of 9Revison 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: Large Bottle Ink, 18L, Dye, ID, C71.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: 6&5((1*UDSKLFDQG3UHFLVLRQ6ROXWLRQV&R/WG6D\DPD6KLQNDLFKL.XPL\DPDFKR.XVHJXQ.\RWR-DSDQ3KRQHQXPEHU)$;QXPEHUDate:13/07/2016Revision:1.01.4. Emergency telephone number 3KRQHQXPEHU0RQ)UL6&5((1*3(XURSH%9$PVWHOYHHQ1HWKHUODQGV3KRQHQXPEHU0RQ)UL6&5((1*3$PHULFDV//&,/$PHULFDVSECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Hazard pictograms: None Hazard statements: None Precautionary statements: None Special Provisions: EUH210 Safety data sheet available on request. EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May produce an allergic reaction. Special provisions according to Annex XVII of REACH and subsequent amendments: None 2.3. Other hazards vPvB Substances: None - PBT Substances: None Other Hazards: No other hazards SECTION 3: Composition/information on ingredients 3.1. Substances No data available 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty Name Ident. Number ClassificationProduct Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data SheetRICOH Pro Ink CartridgeCyan VC40000 Type A (719318)Company Name :Ricoh Company, Ltd.Department :Safety and Reliability Engineering Department, Quarity Management DivisonAddress :146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007, JapanTelephone Number :055-920-1470, Japan ,Telefax Number :055-920-1479, JapanRicoh USA, IncEnvironmental Sustainability and Product Compliance5 Dedrick Place West Caldwell, NJ 07006 USA1-973-882-2000 or 1-973-882-5218 (For product information)1-800-336-6737 (for emergencies)Telefax Number :E-mail :[e-mail]
Version 8.0 Page n. 2 of 9Revison 1.0 50% ~ 65% Water CAS: 7732-18-5 EC: 231-791-2 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). 10% ~ 12.5% Glycerol CAS: 56-81-5 EC: 200-289-5 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). 1% ~ 3% 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Indexnumber: 603-183-00-0 CAS: 143-22-6 EC: 205-592-6 REACH No.: 01-2119475107-383.3/1 Eye Dam. 1 H318 0.25% ~ 0.5%Triethanol amine CAS: 102-71-6 EC: 203-049-8 The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). < 0.05% 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one Indexnumber: 613-088-00-6 CAS: 2634-33-5 EC: 220-120-9 3.1/4/Oral Acute Tox. 4 H302 3.2/2 Skin Irrit. 2 H315 3.3/1 Eye Dam. 1 H318 3.4.2/1-1A-1B Skin Sens. 1,1A,1B H317 4.1/A1 Aquatic Acute 1 H400 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed None 4.3. Indication of any immediate medical attention and special treatment needed Treatment: None SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 3 of 9Revison 1.0 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3. Methods and material for containment and cleaning up Wash with plenty of water. 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Do not eat or drink while working. See also section 8 for recommended protective equipment. 7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3. Specific end use(s) None in particular SECTION 8: Exposure controls/personal protection 8.1. Control parameters Glycerol - CAS: 56-81-5 - OEL Type: OSHA - LTE: 5 mg/m3 - Notes: PEL, as mist, respirable fraction - OEL Type: OSHA - LTE: 15 mg/m3 - Notes: PEL, as mist, total dust DNEL Exposure Limit Values No data available PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 8.2. Exposure controls Eye protection: Not needed for normal use. Anyway, operate according good working practices. Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 4 of 9Revison 1.0 Protection for skin: No special precaution must be adopted for normal use. Protection for hands: Not needed for normal use. Respiratory protection: Not needed for normal use. Thermal Hazards: None Environmental exposure controls: None Appropriate engineering controls: None SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance and colour: Cyan Liquid Odour:SlightlyOdour threshold: No data available pH: 8.9 ~ 9.9 at 20 °C Melting point / freezing point: No data available Initial boiling point and boiling range: No data available Solid/gas flammability: No data available Upper/lower flammability or explosive limits: No data available Vapour density: No data available Flash point: Not detected until 100 °C / 212 ° F (closed cup method, ASTM D 3278) Evaporation rate: No data available Vapour pressure: No data available Relative density: No data available Solubility in water: Complete Solubility in oil: No data available Partition coefficient (n-octanol/water): No data available Auto-ignition temperature: No data available Decomposition temperature: No data available Viscosity:< 5 mPa·s at 20 °C Explosive properties: No data available Oxidizing properties: No data available 9.2. Other information Miscibility:No data available Fat Solubility: No data available Conductivity: No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 5 of 9Revison 1.0 None. SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the mixture: e) germ cell mutagenicity:Test: Mutagenesis - Species: Salmonella Typhimurium and Escherichia coli Negative Toxicological information of the main substances found in the mixture: Glycerol - CAS: 56-81-5 a) acute toxicity:Test: LD50 - Route: Oral - Species: Guinea pig = 7750 mg/kg - Source: Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941 Test: LDLo - Route: Oral - Species: Human = 1428 mg/kg - Source: "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 288, 1969. - Notes: BEHAVIORAL: HEADACHE GASTROINTESTINAL: NAUSEA OR VOMITING 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether - CAS: 143-22-6 a) acute toxicity:Test: LD50 - Route: Dermal - Species: Rabbit = 3.54 ml/kg - Source: American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. Test: LD50 - Route: Oral - Species: Rat = 5300 mg/kg - Source: Office of Toxic Substances Report. Vol. OTS, Triethanol amine - CAS: 102-71-6 a) acute toxicity:Test: LD50 - Route: Oral - Species: Guinea pig = 2200 mg/kg - Source: "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 114, 1982. Test: LD50 - Route: Oral - Species: Mouse = 5846 mg/kg - Source: Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989. - Notes: GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" KIDNEY, URETER, AND BLADDER: OTHER CHANGES BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Substance(s) listed on the IARC Monographs: Triethanol amine - Group 3. If not differently specified, the information required in Regulation (EU) 2015/830 listed below must be considered as 'No data available': a) acute toxicity;b) skin corrosion/irritation;c)serious eye damage/irritation;d) respiratory or skin sensitisation;e) germ cell mutagenicity;f) carcinogenicity;g) reproductive toxicity;h) STOT-single exposure;i) STOT-repeated exposure;j) aspiration hazard.SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 6 of 9Revison 1.0 No data available 12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential No data available 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects None SECTION 13: Disposal considerations 13.1. Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force.SECTION 14: Transport information 14.1. UN number Not classified as dangerous in the meaning of transport regulations. 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU Information: Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013 Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP) Regulation (EU) n. 618/2012 (ATP 3 CLP) Regulation (EU) n. 487/2013 (ATP 4 CLP) Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Restrictions related to the product: No restriction. Restrictions related to the substances contained: No restriction. Where applicable, refer to the following regulatory provisions : Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 7 of 9Revison 1.0 Directive 2003/105/CE ('Activities linkedto risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): No data available USA Information: TSCA - Toxic Substances Control Act TSCA inventory: all the components are listed on the TSCA inventory. TSCA listed substances: None. SARA - Superfund Amendments and Reauthorization Act Section 302 – Extremely Hazardous Substances: no substances listed. Section 304 – Hazardous substances: no substances listed. Section 313 – Toxic chemical list: 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether. CAA - Clean Air Act CAA listed substances: Glycerol is listed in CAA Section 111 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether is listed in CAA Section 112, Section 112(b) - HON. California Proposition 65 Substance(s) listed under California Proposition 65: None. NFPA rating: HMIS rating: Canada Information: WHMIS Controlled Product: WHMIS item number from Ingredient Disclosure List : Triethylene glycol: 1625 Propylene glycol: 1362 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether: 1627 Australia Information: Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC New Zealand Information: Hazardous Substances and New Organisms Act 1996: Not regulated 15.2. Chemical safety assessment No SECTION 16: Other information Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 8 of 9Revison 1.0 Full text of phrases referred to in Section 3: H318 Causes serious eye damage. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. This safety data sheet has been completely updated in compliance to Regulation 2015/830. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold CCNL - Appendix 1 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This Safety Data Sheet cancels and replaces any preceding release. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. CAS: Chemical Abstracts Service (division of the American Chemical Society). CLP: Classification, Labeling, Packaging. DNEL: Derived No Effect Level. EINECS: European Inventory of Existing Commercial Chemical Substances. GefStoffVO: Ordinance on Hazardous Substances, Germany. GHS: Globally Harmonized System of Classification and Labeling of Chemicals. HMIS: Hazardous Materials Identification System IARC:International Agency for Research on Cancer IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO). IMDG: International Maritime Code for Dangerous Goods. INCI: International Nomenclature of Cosmetic Ingredients. KSt: Explosion coefficient.LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. LTE: Long-term exposure.NFPA:National Fire Protection Association NOHSC: National Occupational Health and Safety Commission OSHA: Occupational Safety and Health Administration PNEC: Predicted No Effect Concentration. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. STE: Short-term exposure.STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. TLV: Threshold Limiting Value. Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet
Version 8.0 Page n. 9 of 9Revison 1.0 TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). WGK: German Water Hazard Class. WHMIS: Workplace Hazardous Materials Information System Product Name :RICOH Pro Ink Cartridge Cyan VC40000 Type ASDS Number :719318Date Prepared :07/13/2016Date Printed:07/07/2017Safety Data Sheet