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HomeMy WebLinkAboutDAQ-2024-008611 DAQE-AN103670030-24 {{$d1 }} Stewart Hogan Asahi Refining USA, Incorporated 4601 West 2100 South West Valley City, UT 84120 stewart.hogan@asahirefining.com Dear Mr. Hogan: Re: Approval Order: Administrative Amendment to Approval Order DAQE-AN103670029-24 to Replace a Melt Furnace under R307-401-12 Project Number: N103670030 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on May 28, 2024. Asahi Refining USA, Incorporated must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Christine Bodell, who can be contacted at (385) 290-2690 or cbodell@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. No public comments were received on this action. Sincerely, {{$s }} Bryce C. Bird Director BCB:CB:jg cc: Salt Lake County Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director June 26, 2024 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN103670030-24 Administrative Amendment to Approval Order DAQE-AN103670029-24 to Replace a Melt Furnace under R307-401-12 Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Asahi Refining USA, Incorporated - Precious Metals Refinery Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality June 26, 2024 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 4 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 7 PERMIT HISTORY ................................................................................................................... 11 ACRONYMS ............................................................................................................................... 12 DAQE-AN103670030-24 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Asahi Refining USA, Incorporated Asahi Refining USA, Incorporated - Precious Metals Refinery Mailing Address Physical Address 4601 West 2100 South 4601 West 2100 South West Valley City, UT 84120 West Valley City, UT 84120 Source Contact UTM Coordinates Name: Stewart Hogan 415,495 m Easting Phone: (801) 924-6089 4,508,700 m Northing Email: stewart.hogan@asahirefining.com Datum NAD83 UTM Zone 12 SIC code 3339 (Primary Smelting & Refining of Nonferrous Metals, Except Copper & Aluminum) SOURCE INFORMATION General Description Asahi Refining USA, Incorporated (Asahi) currently operates a precious metals refinery in West Valley City, Salt Lake County. Mined doré and scrap are melted and tested for purity using small electric induction furnaces, and then separated depending on gold and silver content. Separation is achieved by using various inorganic chemicals and electrolytic methods. Silver is poured into anode molds and then placed into the electrolytic cells. The cells contain silver nitrate solution, and the low voltage current causes silver crystals to form onto a cathode plate. The silver crystal is scraped off and collected. NSR Classification Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: B Applicable Federal Standards MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines DAQE-AN103670030-24 Page 4 Project Description Asahi is currently permitted to operate three (3) natural gas-fueled melt furnaces, each rated less than 5 MMBtu/hr (see Approval Order DAQE-AN103670029-24, Equipment ID II.A.14). Asahi will be replacing one (1) melt furnace with one (1) electric tilt furnace. The new and existing electric tilt furnaces (see Approval Order DAQE-AN103670029-24, Equipment ID II.A.15) use the same control technologies as the melt furnaces: a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. Asahi is not requesting to increase any production and/or operational limits. No emissions are increasing. This project meets the requirements of UAC R307-401-12 Reduction in Air Pollutants and does not require a public comment period. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) Ammonia 0 0.06 CO2 Equivalent 0 994.70 Carbon Monoxide 0 0.73 Lead 0 0.01 Nitrogen Oxides 0 4.31 Particulate Matter - PM10 0 2.01 Particulate Matter - PM2.5 0 2.01 Sulfur Dioxide 0 6.11 Volatile Organic Compounds 0 0.09 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Chlorine (CAS #7782505) 0 800 Hexane (CAS #110543) 0 20 Hydrochloric Acid (Hydrogen Chloride) (CAS #7647010) 0 1600 Lead (CAS #7439921) 0 20 Selenium & Compounds (CAS #253) 0 60 Change (TPY) Total (TPY) Total HAPs 0 1.25 SECTION I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] DAQE-AN103670030-24 Page 5 I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Metal Refinery Precious Metals Refinery Plant. II.A.2 Wastewater Treatment Wastewater effluent treatment. Process controlled by scrubber #760. II.A.3 Electrolytic Cells Silver electrolytic cell (refining of silver). Process controlled by scrubber #761. II.A.4 Electrolytic Cells Gold electrolytic cell (refining of gold). Process controlled by scrubber #359. II.A.5 Wet Circuit Gold refinery wet circuits (part of the gold refining process). Process controlled by scrubber #359. DAQE-AN103670030-24 Page 6 II.A.6 Chlorination Gold chloride electrolytic production (refining of gold). Process controlled by scrubber #359. II.A.7 Slime Washing Silver anode slime washing process (recovery of gold). Process controlled by scrubber #248. II.A.8 Wet Chlorides Treatment Hydrometallurgical process for silver chloride sludge processing (recovery of gold). Controlled by scrubber #359. II.A.9 Fabric-Filter Baghouse Four (4) fabric-filter baghouses One (1) baghouse controls emissions from the sweep preparation process. Two (2) baghouses control emissions from the melt room furnaces, the electric tilt furnaces, and the electric push -out furnaces. One (1) baghouse controls the ashing furnace (Item II.A.26). II.A.10 Boiler One (1) boiler, natural gas-fueled, rated less than 5 MMBtu/hr. II.A.11 Dust Collector Dust collector for welding fume and grinding dust control in maintenance shop. II.A.12 Electrostatic Precipitator One (1) wet-electrostatic precipitator (ID: WESP II). II.A.13 Chlorination Furnaces Four (4) electric-induction chlorination furnaces. Process controlled by venturi scrubber, WESP II, and scrubber #359. II.A.14 Melt Furnaces Two (2) melt-room furnaces, natural gas-fueled, rated less than 5 MMBtu/hr each. Process controlled by a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.15 Tilt Furnaces (One (1) New) Eight (8) electric-tilt furnaces. Process controlled by a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.16 Push-out Furnaces Four (4) electric push-out furnaces. Process controlled by baghouse or the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.17 Emergency Generator Engine One (1) emergency power generator engine, natural gas-fueled, rated at 60 kW. II.A.18 Combustion Afterburner One (1) incinerator, natural gas-fueled, rated less than 5 MMBtu/hr. II.A.19 Nitrate Plant Silver nitrate plant (recovery of silver). Process controlled by scrubber #248. II.A.20 Slime Plant Slime plant (recovery of gold). Process controlled by scrubber #248. DAQE-AN103670030-24 Page 7 II.A.21 Drying Cabinets Five (5) electric drying cabinets. Process controlled by the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.22 Drying Cabinet One (1) drying cabinet, natural gas-fueled, rated less than 5 MMBtu/hr. II.A.23 Wet Scrubbers Four (4) packed bed wet scrubbers (ID: 760, 359, 248, 761). II.A.24 Venturi Scrubber One (1) venturi scrubber attached to WESP II as a pre-scrubber. II.A.25 Tank System Silver reduction tanks (recovery of silver). Process controlled by scrubber #248. II.A.26 Ashing Furnace One (1) dental scrap ashing furnace. Process controlled by baghouse (Item II.A.9) and activated carbon adsorption system (Item II.A.27). II.A.27 Activated Carbon Adsorption System One (1) activated carbon adsorption system controls the ashing furnace (Item II.A.26). SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. All fabric filter baghouse exhaust stacks - 10%. B. All electrostatic precipitator exhaust stacks - 10% . C. All scrubber exhaust stacks - 10%. D. All incinerator exhaust stacks - 10%. E. All boiler exhaust stacks - 10%. F. All other points - 20%. [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] DAQE-AN103670030-24 Page 8 II.B.1.b The owner/operator shall not produce more than the following: A. 12,000,000 troy ounces of gold per rolling 12-month period. B. 60,000,000 troy ounces of silver per rolling 12-month period. C. 400 tons of sweeps per rolling 12-month period. [R307-401-8] II.B.1.b.1 The owner/operator shall: A. Determine gold, silver, and sweeps production by company production records. B. Record gold and silver production on a daily basis and record sweeps production. on a monthly basis C. Use the gold and silver production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months. D. Use the sweeps production data to calculate a new rolling 12-month total by the 20th day of January, April, July, and October of each year using data from the previous 12 months. E. Keep the gold, silver, and sweeps production records for all periods the plant is in operation. [R307-401-8] II.B.2 Baghouse Requirements II.B.2.a The owner/operator shall use baghouses to control particulate emissions from the sweeps preparation process, melt room furnaces, electric tilt furnaces, electric push-out furnaces, and the ashing furnace. [R307-401-8] II.B.2.b The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across each baghouse. [R307-401-8] II.B.2.b.1 The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.2.b.2 The pressure gauge shall measure the static pressure differential in 1-inch water column increments or less. [R307-401-8] II.B.2.c During operation of each baghouse, the owner/operator shall maintain the static pressure differential within the range recommended by the manufacturer for normal operations. [R307-401-8] II.B.2.c.1 The owner/operator shall record the static pressure differential at least once per operating day while each baghouse is operating. [R307-401-8] DAQE-AN103670030-24 Page 9 II.B.2.c.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential range for the unit; C. Daily static pressure differential readings; D. Date of reading. [R307-401-8] II.B.2.d At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.2.d.1 The owner/operator shall maintain records of each pressure gauge calibrations and replacements. [R307-401-8] II.B.3 Emergency Engine Requirements II.B.3.a The owner/operator shall not operate the emergency engine on site for more than 100 hours per rolling 12-month period during non-emergency situations. There is no time limit on the use of the engine during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.3.a.1 To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. Records documenting the operation of the emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used. B. The duration of operation in hours. C. The reason for the emergency engine usage. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.3.b The owner/operator shall only use natural gas as fuel in the emergency engine. [R307-401-8] DAQE-AN103670030-24 Page 10 II.B.4 Wet Scrubber Requirements II.B.4.a The owner/operator shall use the following scrubbers to control the following process streams: Scrubber Process Stream Scrubber #248 silver anode slime washing process, silver nitrate plant, and slime plant. Scrubber #359 gold electrolytic cells, gold refinery wet circuits, gold chloride electrolytic production, silver chlorides sludge processing, chlorination furnaces, melt furnaces, tilt furnaces, push-out furnaces, and drying cabinets. Scrubber #760 wastewater treatment tanks and laboratory. Scrubber #761 silver electrolytic cells. All exhaust air from the above-mentioned process streams shall be routed through the indicated scrubber before being vented to the atmosphere. [R307-401-8] II.B.4.b During operation of each scrubber, the owner/operator shall maintain both the pressure drop and the liquid flow rate within the respective range recommended by the manufacturer for normal operations. [R307-401-8] II.B.4.b.1 The parameters shall be monitored with instruments located such that an inspector/operator can safely read the output any time. [R307-401-8] II.B.4.c The owner/operator shall record both the pressure drop and liquid flow rate at least once per operating day while each scrubber is operating. [R307-401-8] II.B.4.c.1 The owner/operator shall maintain the following records of the pressure drop and liquid flow rate: A. Unit identification; B. Manufacturer-recommended pressure drop and liquid flow rate range; C. Daily pressure drop and liquid flow rate readings; D. Date of reading. [R307-401-8] II.B.4.d At least once every 12 months, the owner/operator shall calibrate each instrument in accordance with the manufacturer's instructions or replace the instrument. [R307-401-8] II.B.4.d.1 The owner/operator shall maintain records of each instrument calibrations and replacements. [R307-401-8] II.B.4.e The owner/operator shall install a scrubber (ID# 761) that is certified to meet a NOx emission reduction of no less than 24%. [R307-401-8] II.B.4.e.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed scrubber. [R307-401-8] DAQE-AN103670030-24 Page 11 PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN103670029-24 dated April 4, 2024 Is Derived From NOI dated May 28, 2024 DAQE-AN103670030-24 Page 12 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE- RN103670030 June 11, 2024 Stewart Hogan Asahi Refining USA, Inc. 4601 West 2100 South West Valley City, UT 84120 stewart.hogan@asahirefining.com Dear Stewart Hogan, Re: Engineer Review - Administrative Amendment: Administrative Amendment to Approval Order DAQE-AN103670029-24 to Replace a Melt Furnace under R307-401-12 Project Number: N103670030 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review (NSR) permitting program. Asahi Refining USA, Inc. should complete this review within 10 business days of receipt. Asahi Refining USA, Inc. should contact Christine Bodell at (385) 290-2690 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Christine Bodell at cbodell@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an Approval Order (AO) for signature by the DAQ Director. If Asahi Refining USA, Inc. does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Asahi Refining USA, Inc. has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature _____________________________________________________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N103670030 Owner Name Asahi Refining USA, Inc. Mailing Address 4601 West 2100 South West Valley City, UT, 84120 Source Name Asahi Refining USA, Inc.- Precious Metals Refinery Source Location 4601 West 2100 South West Valley City, UT 84120 UTM Projection 415,495 m Easting, 4,508,700 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 3339 (Primary Smelting & Refining of Nonferrous Metals, Except Copper & Aluminum) Source Contact Stewart Hogan Phone Number (801) 924-6089 Email stewart.hogan@asahirefining.com Billing Contact Stewart Hogan Phone Number 801-924-6089 Email stewart.hogan@asahirefining.com Project Engineer Christine Bodell, Engineer Phone Number (385) 290-2690 Email cbodell@utah.gov Notice of Intent (NOI) Submitted May 28, 2024 Date of Accepted Application May 31, 2024 Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 2 SOURCE DESCRIPTION General Description Asahi Refining USA, Inc. (Asahi) currently operates a precious metals refinery in West Valley City, Salt Lake County. Mined doré and scrap are melted and tested for purity using small electric induction furnaces and then separated depending on gold and silver content. Separation is achieved by using various inorganic chemicals and electrolytic methods. Silver is poured into anode molds and then placed into the electrolytic cells. The cells contain silver nitrate solution, and the low voltage current causes silver crystal to form onto a cathode plate. The silver crystal is scraped off and collected. NSR Classification: Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: B Applicable Federal Standards MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines Project Proposal Administrative Amendment to Approval Order DAQE-AN103670029-24 to Replace a Melt Furnace under R307-401-12 Project Description Asahi Refining Inc. (Asahi) is currently permitted to operate three (3) natural gas-fueled melt furnaces, each rated less than 5 MMBtu/hr (see Approval Order DAQE-AN103670029-24, Equipment ID II.A.14). Asahi will be replacing one (1) melt furnace with one (1) electric tilt furnaces. The new and existing electric tilt furnaces (see Approval Order DAQE-AN103670029- 24, Equipment ID II.A.15) use the same control technologies as the melt furnaces: a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. Asahi is not requesting to increase any production and/or operational limits. No emissions are increasing. This project meets the requirements of UAC R307-401-12 Reduction in Air Pollutants and does not require a public comment period. EMISSION IMPACT ANALYSIS This is an administrative amendment under R307-401-12. No emissions are increasing at this time. Therefore, modeling is not required. [Last updated May 31, 2024] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 3 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) Ammonia 0 0.06 CO2 Equivalent 0 994.70 Carbon Monoxide 0 0.73 Lead 0 0.01 Nitrogen Oxides 0 4.31 Particulate Matter - PM10 0 2.01 Particulate Matter - PM2.5 0 2.01 Sulfur Dioxide 0 6.11 Volatile Organic Compounds 0 0.09 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Chlorine (CAS #7782505) 0 800 Hexane (CAS #110543) 0 20 Hydrochloric Acid (Hydrogen Chloride) (CAS #7647010) 0 1600 Lead (CAS #7439921) 0 20 Selenium & Compounds (CAS #253) 0 60 Change (TPY) Total (TPY) Total HAPs 0 1.25 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 4 Review of BACT for New/Modified Emission Units 1. BACT review regarding New Electric Tilt Furnace This is an administrative amendment under R307-401-12. No emissions are increasing at this time. Therefore, a BACT analysis is not required. [Last updated May 31, 2024] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307- 150] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 5 I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 Metal Refinery Precious Metals Refinery Plant II.A.2 Wastewater Treatment Wastewater effluent treatment. Process controlled by scrubber #760 II.A.3 Electrolytic Cells Silver electrolytic cell (refining of silver). Process controlled by scrubber #761. II.A.4 Electrolytic Cells Gold electrolytic cell (refining of gold). Process controlled by scrubber #359. II.A.5 Wet Circuit Gold refinery wet circuits (part of the gold refining process). Process controlled by scrubber #359. II.A.6 Chlorination Gold chloride electrolytic production (refining of gold). Process controlled by scrubber #359. II.A.7 Slime Washing Silver anode slime washing process (recovery of gold). Process controlled by scrubber #248. II.A.8 Wet Chlorides Treatment Hydrometallurgical process for silver chlorides sludge processing (recovery of gold). Controlled by scrubber #359. II.A.9 Fabric-Filter Baghouse Four (4) fabric-filter baghouses One baghouse controls emissions from the sweeps preparation process. Two baghouses control emissions from the melt room furnaces, the electric tilt furnaces, and the electric push- out furnaces. One baghouse controls the ashing furnace (Item II.A.26). Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 6 II.A.10 Boiler One (1) boiler, natural gas-fueled, rated less than 5 MMBtu/hr II.A.11 Dust Collector Dust collector for welding fume and grinding dust control in maintenance shop II.A.12 Electrostatic Precipitator One (1) wet-electrostatic precipitator (ID: WESP II) II.A.13 Chlorination Furnaces Four (4) electric-induction chlorination furnaces. Process controlled by venturi scrubber, WESP II, and scrubber #359. II.A.14 Melt Furnaces Two (2) melt-room furnaces, natural gas-fueled, rated less than 5 MMBtu/hr each. Process controlled by a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.15 Tilt Furnaces (One New) Eight (8) electric-tilt furnaces. Process controlled by a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.16 Push-out Furnaces Four (4) electric push-out furnaces. Process controlled by baghouse or the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.17 Emergency Generator Engine One (1) emergency power generator engine, natural gas-fueled, rated at 60 kW II.A.18 Combustion Afterburner One (1) incinerator, natural gas-fueled, rated less than 5 MMBtu/hr II.A.19 Nitrate Plant Silver nitrate plant (recovery of silver). Process controlled by scrubber #248. II.A.20 Slime Plant Slime plant (recovery of gold). Process controlled by scrubber #248. II.A.21 Drying Cabinets Five (5) electric drying cabinets. Process controlled by the combination of the venturi scrubber, WESP II, and scrubber #359. II.A.22 Drying Cabinet One (1) drying cabinet, natural gas-fueled, rated less than 5 MMBtu/hr. II.A.23 Wet Scrubbers Four (4) packed bed wet scrubbers (ID: 760, 359, 248, 761) Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 7 II.A.24 Venturi Scrubber One (1) venturi scrubber attached to WESP II as a pre-scrubber. II.A.25 Tank System Silver reduction tanks (recovery of silver). Process controlled by scrubber #248. II.A.26 Ashing Furnace One (1) dental scrap ashing furnace. Process controlled by baghouse (Item II.A.9) and activated carbon adsorption system (Item II.A.27). II.A.27 Activated Carbon Adsorption System One (1) activated carbon adsorption system controls the ashing furnace (Item II.A.26) SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. All fabric filter baghouse exhaust stacks - 10% B. All electrostatic precipitator exhaust stacks - 10% C. All scrubber exhaust stacks - 10% D. All incinerator exhaust stacks - 10% E. All boiler exhaust stacks - 10% F. All other points - 20% [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 8 II.B.1.b The owner/operator shall not produce more than the following: A. 12,000,000 troy ounces of gold per rolling 12-month period B. 60,000,000 troy ounces of silver per rolling 12-month period C. 400 tons of sweeps per rolling 12-month period [R307-401-8] II.B.1.b.1 The owner/operator shall: A. Determine gold, silver, and sweeps production by company production records B. Record gold and silver production on a daily basis and record sweeps production on a monthly basis C. Use the gold and silver production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Use the sweeps production data to calculate a new rolling 12-month total by the 20th day of January, April, July and October of each year using data from the previous 12 months. E. Keep the gold, silver, and sweeps production records for all periods the plant is in operation. [R307-401-8] II.B.2 Baghouse Requirements II.B.2.a The owner/operator shall use baghouses to control particulate emissions from the sweeps preparation process, melt room furnaces, electric tilt furnaces, electric push-out furnaces, and the ashing furnace. [R307-401-8] II.B.2.b The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across each baghouse. [R307-401-8] II.B.2.b.1 The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.2.b.2 The pressure gauge shall measure the static pressure differential in 1-inch water column increments or less. [R307-401-8] II.B.2.c During operation of each baghouse, the owner/operator shall maintain the static pressure differential within the range recommended by the manufacturer for normal operations. [R307- 401-8] II.B.2.c.1 The owner/operator shall record the static pressure differential at least once per operating day while each baghouse is operating. [R307-401-8] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 9 II.B.2.c.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential range for the unit; C. Daily static pressure differential readings; D. Date of reading. [R307-401-8] II.B.2.d At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.2.d.1 The owner/operator shall maintain records of each pressure gauge calibrations and replacements. [R307-401-8] II.B.3 Emergency Engine Requirements II.B.3.a The owner/operator shall not operate the emergency engine on site for more than 100 hours per rolling 12-month period during non-emergency situations. There is no time limit on the use of the engine during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.3.a.1 To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. Records documenting the operation of the emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used B. The duration of operation in hours C. The reason for the emergency engine usage [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.3.b The owner/operator shall only use natural gas as fuel in the emergency engine. [R307-401-8] II.B.4 Wet Scrubber Requirements Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 10 II.B.4.a The owner/operator shall use the following scrubbers to control the following process streams. Scrubber Process Stream Scrubber #248 silver anode slime washing process, silver nitrate plant, and slime plant Scrubber #359 gold electrolytic cells, gold refinery wet circuits, gold chloride electrolytic production, silver chlorides sludge processing, chlorination furnaces, melt furnaces, tilt furnaces, push-out furnaces, and drying cabinets Scrubber #760 wastewater treatment tanks and laboratory Scrubber #761 silver electrolytic cells All exhaust air from the above-mentioned process streams shall be routed through the indicated scrubber before being vented to the atmosphere. [R307-401-8] II.B.4.b During operation of each scrubber, the owner/operator shall maintain both the pressure drop and the liquid flow rate within the respective range recommended by the manufacturer for normal operations. [R307-401-8] II.B.4.b.1 The parameters shall be monitored with instruments located such that an inspector/operator can safely read the output any time. [R307-401-8] II.B.4.c The owner/operator shall record both the pressure drop and liquid flow rate at least once per operating day while each scrubber is operating. [R307-401-8] II.B.4.c.1 The owner/operator shall maintain the following records of the pressure drop and liquid flow rate: A. Unit identification; B. Manufacturer recommended pressure drop and liquid flow rate range; C. Daily pressure drop and liquid flow rate readings; D. Date of reading. [R307-401-8] II.B.4.d At least once every 12 months, the owner/operator shall calibrate each instrument in accordance with the manufacturer's instructions or replace the instrument. [R307-401-8] II.B.4.d.1 The owner/operator shall maintain records of each instrument calibrations and replacements. [R307-401-8] II.B.4.e The owner/operator shall install a scrubber (ID# 761) that is certified to meet a NOx emission reduction of no less than 24%. [R307-401-8] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 11 II.B.4.e.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed scrubber. [R307-401-8] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 12 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN103670029-24 dated April 4, 2024 Is Derived From NOI dated May 28, 2024 REVIEWER COMMENTS 1. Comment regarding Reduction in Air Pollutant Applicability: Asahi has requested to replace one (1) natural gas-fired melt furnaces, rated less than 5 MMBtu/hr, with one (1) electric tilt furnace. All the natural gas-fired and electric tilt furnaces on site are controlled by a nanofilter baghouse made by UAS or the combination of the venturi scrubber, WESP II, and scrubber #359. The replacement results in a reduction of emissions from natural gas combustion. The new equipment will operate under existing emissions limitations. Therefore, this project meets the requirements of Utah Administrative Code R307-401-12, Reduction in Air Pollutants. Asahi has elected to make no adjustments the current Potential to Emit (PTE). Therefore, the Summary of Emissions table will not reflect any changes. [Last updated May 31, 2024] 2. Comment regarding NSPS and MACT Applicability: 40 CFR 63 Subpart ZZZZ - National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines The provisions of this subpart are applicable to owners/operators of stationary RICE at a major or area sources of HAP emissions. The facility includes (1) 60 kW, natural gas-fired emergency stationary engine. The provisions of MACT Subpart ZZZZ apply as the stationary reciprocating internal combustion engine (RICE) is at an area source of HAP emissions. The engine is not designated as nonroad and are not exempt are affected sources under this regulation. Therefore, MACT Subpart ZZZZ applies to this facility. The engine was installed prior to June 12, 2006. Therefore, 40 CFR 60 Subpart JJJJ (Standards of Performance for Stationary Spark Ignition Internal Combustion Engines) does not apply. [Last updated May 31, 2024] 3. Comment regarding Title V Applicability: Title V of the 1990 CAA (Title V) applies to the following: A. Any major source B. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources C. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants D. Any Title IV-affected source This facility is not a major source and is not a Title IV source, but is subject to 40 CFR 63 MACT Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 13 Subparts A and ZZZZ regulations. However, Title V does not apply because MACT Subpart ZZZZ exempts sources from the obligation to obtain a permit under 40 CFR part 70 (Title V permit) if the source is not otherwise required by law to obtain a permit. There are no other reasons why this source would be required to obtain a part 70 permit; therefore, Title V does not apply to this facility. [Last updated May 31, 2024] Engineer Review N103670030: Asahi Refining Inc. June 11, 2024 Page 14 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds