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HomeMy WebLinkAboutDAQ-2024-007954 DAQE-AN104630032-24 {{$d1 }} Andrew Riddick Henkel Corporation 3540 West 1987 South Salt Lake City, UT 84104 Andrew.Riddick@henkel.com Dear Mr. Riddick: Re: Approval Order: Administrative Amendment to Approval Order DAQE-AN104630031-23 to Allow for Organic Liquids Handling Flexibility under R307-401-12 Project Number: N104630032 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on March 11, 2024. Henkel Corporation must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Christine Bodell, who can be contacted at (385) 290-2690 or cbodell@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. No public comments were received on this action. Sincerely, {{$s }} Bryce C. Bird Director BCB:CB:jg cc: Salt Lake County Health Department DJ Law, EPA Region 8 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director April 24, 2024 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN104630032-24 Administrative Amendment to Approval Order DAQE-AN104630031-23 to Allow for Organic Liquids Handling Flexibility under R307-401-12 Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Henkel Corporation - Detergent Manufacturing Plant Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality April 24, 2024 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 8 PERMIT HISTORY ................................................................................................................... 13 ACRONYMS ............................................................................................................................... 14 DAQE-AN104630032-24 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Henkel Corporation Henkel Corporation - Detergent Manufacturing Plant Mailing Address Physical Address 3540 West 1987 South 3540 West 1987 South Salt Lake City, UT 84104 Salt Lake City, UT 84104 Source Contact UTM Coordinates Name: Andrew Riddick 417,544 m Easting Phone: (270) 392-9845 4,509,170 m Northing Email: Andrew.Riddick@henkel.com Datum NAD83 UTM Zone 12 SIC code 2841 (Soaps & Other Detergent, Except Specialty Cleaners) SOURCE INFORMATION General Description Henkel Corporation (Henkel) operates a soap and detergent manufacturing plant in Salt Lake City. Emissions are primarily associated with particulate matter control equipment and natural gas combustion in a variety of boilers and emergency generators. Henkel employs baghouses, bin vents, dust collectors, and scrubbers. NSR Classification Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: SM Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), Dc: Standards of Performance for Small Industrial-Commercial-Institutional Steam Generating Units NSPS (Part 60), Kb: Standards of Performance for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid Storage Vessels) for Which Construction, Reconstruction, or Modification Commenced After July 23, 1984 NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal DAQE-AN104630032-24 Page 4 Combustion Engines NSPS (Part 60), JJJJ: Standards of Performance for Stationary Spark Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines Project Description Henkel is currently permitted to process a throughput of up to 3,495,680 gallons, combined, of Armosoft DEQ per rolling 12-month period in Tanks 63 and 63A (Condition II.B.6.a in the Approval Order DAQE-AN104630031-23). The current VOC potential to emit (PTE) of Tanks 63 and 63A was estimated in 2023 by using the Emission Master Tanks Software based on the 2019 EPA Revision. It was established that Armosoft DEQ had a true vapor pressure of 34.3 kPa, as determined in a laboratory using New Source Performance Standard (NSPS)-approved ASTM method 2879. The VOC emitted from Armosoft is ethanol. Henkel would like to replace "Armosoft DEQ" with "Volatile Organic Liquid with a true vapor pressure not to exceed 34.3 kPa." The removal of the specific brand name would provide Henkel with flexibility to handle other organic liquids with the same or lower true vapor pressure. Henkel will not be permitted to handle a volatile organic liquid that contains any VOCs except for ethanol through Tanks 63 and 63A. Additionally, the volatile organic liquid will not contain any HAPs. Henkel is not requesting to increase the maximum allowable throughput of Tanks 63 and 63A. Therefore, no emissions are increasing. This project meets the requirements of UAC R307-401-12 Reduction in Air Pollutants and does not require a public comment period. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) Ammonia 0 0.85 CO2 Equivalent 0 19094.00 Carbon Monoxide 0 13.47 Nitrogen Oxides 0 16.19 Particulate Matter - PM10 0 28.39 Particulate Matter - PM2.5 0 28.27 Sulfur Dioxide 0 0.13 Volatile Organic Compounds 0 9.87 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Formaldehyde (CAS #50000) 0 36 Generic HAPs (CAS #GHAPS) 0 35 Glycol Ethers (CAS #EDF109) 0 186 Hexane (CAS #110543) 0 571 DAQE-AN104630032-24 Page 5 Methanol (CAS #67561) 0 634 Change (TPY) Total (TPY) Total HAPs 0 0.73 SECTION I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Detergent Manufacturing Plant II.A.2 Baghouses and Bin Vents- Group #2 Outlet Emissions Rate: 0.02 grains/dscf Designations: LSL-6, SODA BV-1, LSL-9, LQD-5, LSL-1 Outlet Emissions Rates: 0.007 grains/dscf Designation: LSL-4 DAQE-AN104630032-24 Page 6 II.A.3 Baghouses and Bin Vents- Group #3 Outlet Emission Rates: 0.005 grains/dscf Designations: LSL-8 II.A.4 Baghouses and Bin Vents- Group #4 Outlet Emission Rate: 0.016 grains/dscf Designations: MESBH-1 and MESBV-2 II.A.5 One (1) Scrubber LSS-3/1 Model: Clean Gas System Size 54 II.A.6 One (1) Conditioning Drum Designation: LSL-3 Rating: 2.5 MMBtu/hr Fuel: Natural Gas II.A.7 Five (5) Boilers Fuel: Natural Gas Ratings: (1) 8.37 MMBtu/hr (2) 6.4 MMBtu/hr (3) 0.77 MMBtu/hr (4) 2.51 MMBtu/hr (5) 14.0 MMBtu/hr II.A.8 Five (5) Heat transfer Labelers Four (4) heat transfer labelers: Four (4) burners each Labeler Ratings: 0.17 MMBtu/hr Each (42,000 Btu/hr per burner) One (1) heat transfer labeler: Six (6) burners Labeler Rating: 0.25 MMBtu/hr Each (42,000 Btu/hr per burner) II.A.9 VideoJet coders Including 32 VideoJet coders II.A.10 One (1) Emergency Generator Engine Fuel: Diesel Engine Rating: 74 hp Manufacture Year: 2004 NSPS Applicability: None MACT Applicability: Subpart ZZZZ II.A.11 One (1) Emergency Generator Engine Fuel: Natural Gas Rating: 16 hp Manufacture Year: 1969 NSPS Applicability: None MACT Applicability: Subpart ZZZZ II.A.12 Six (6) Pre-mixers II.A.13 One (1) Paint booth Rating: 2,000 scfm equipped Control: high efficiency over-spray filters DAQE-AN104630032-24 Page 7 II.A.14 Ethanol and Other Organic Solution Storage Tanks Tank 52 Capacity: 29,000 gallons Contents: Citric Acid NSPS Applicability: None Tank 60 Capacity: 29,000 gallons Contents: Denatured Ethanol NSPS Applicability: None Tank 63 and Tank 63A Capacity: 34,000 gallons each Contents: Volatile Organic Liquid with a True Vapor Pressure not to exceed 34.3 kPa NSPS Applicability: Subpart Kb Tank 66 Capacity: 29,000 gallons Contents: Polyethylene glycol (PEG) 400 NSPS Applicability: None II.A.15 Storage Tanks Tank 1 (34,000 gallons) Tank 2 (32,700 gallons) Tank 21 (21,000 gallons) Tank 22 (34,000 gallons) Tank 23 (29,000 gallons) Tank 27 (34,000 gallons) Tank 45 (21,000 gallons) Tank 49 (34,000 gallons) Tank 65 (34,000 gallons) Tank 65A (34,000 gallons) NSPS Applicability: None Above tanks, except for Tank 2, contain a liquid with a VOC maximum true vapor pressure less than 15.0 kPa. Tank 2 does not contain a volatile organic liquid. II.A.16 Two (2) Vacuum pumps MESVP-1 and MESVP-2 Rating: 704 cfm Each Model Busch RC1000 for the MES conveying system II.A.17 One (1) Blower LSL-10 Rating: 600 cfm II.A.18 Plastic processing equipment Plastic and additive transfer, storage, mixing and grinding equipment Control: 13 sock filters II.A.19 Blow molding equipment Vents in the blow molding area II.A.20 Five (5) Electrostatic precipitators Smog Hog ESP mist collectors in the blow molding area II.A.21 Six (6) Cooling towers DAQE-AN104630032-24 Page 8 II.A.22 Four (4) Maintenance shops Including: parts cleaners, welding equipment, exhaust vents, welding fume collector, and grit blasting equipment II.A.23 Hoods Miscellaneous ventilation hoods in QA labs II.A.24 Miscellaneous equipment Liquid transfer, storage, and mixing equipment, including raw material and product storage tanks, pumps, vents, blending equipment, and bottle-filling equipment SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Opacity Requirement. II.B.1.a The owner/operator shall not allow visible emissions to exceed 20% opacity unless otherwise specified within this AO. [R307-401-8] II.B.1.a.1 Unless otherwise specified in this AO, opacity observations of visible emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-305-3] II.B.2 Site-Wide Natural Gas Requirements. II.B.2.a The owner/operator shall not consume more than 533.7 million scf of natural gas per rolling 12-month period. [R307-401-8] II.B.2.a.1 The owner/operator shall: A. Determine consumption by utility billing statements. B. Record consumption on a monthly basis. C. Use the consumption data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months. D. Keep the consumption records for all periods the plant is in operation. [R307-401-8] II.B.3 Liquid Detergent Production Requirements. II.B.3.a The owner/operator shall not produce more than 1,700,000,000 pounds of liquid detergents per rolling 12-month period. [R307-401-8] DAQE-AN104630032-24 Page 9 II.B.3.a.1 The owner/operator shall: A. Determine production with production records. B. Record production on a daily basis. C. Use the production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months. D. Keep the production records for all periods the plant is in operation. [R307-401-8] II.B.4 Scrubber Requirements. II.B.4.a The owner/operator shall maintain the liquid flow rate of Scrubber LSS-3/1 to not be less than 56 gallons/minute. [R307-401-8] II.B.4.a.1 The liquid flow rate shall be monitored with a flow meter located such that an inspector/operator can safely read the output anytime. [R307-401-8] II.B.4.a.2 The owner/operator shall install, calibrate, maintain, and operate each monitoring device certified by the manufacturer. Calibration shall be on an annual basis according to the manufacturer's instructions. Daily records of reading shall be maintained. [R307-401-8] II.B.5 VOC and HAP Requirements. II.B.5.a The owner/operator shall not allow visible emissions from the printing press dryers to exceed 10% opacity. [R307-401-8] II.B.5.b The owner/operator shall not emit more than the following from evaporative sources (painting, printing, coating, and/or cleaning) on site: 8.94 tons of VOC including HAPs per rolling 12-month period. 0.43 tons of all other HAPs combined per rolling 12-month period. [R307-351, R307-401-8] II.B.5.b.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed]. HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed]. [R307-401-8] DAQE-AN104630032-24 Page 10 II.B.5.b.2 The owner/operator shall keep records each month of the following: A. The name (as per the Safety Data Sheet) of the VOC- and HAP-emitting material. B. The maximum percent by weight of VOCs and each HAP in each material used. C. The density of each material used. D. The volume of each VOC- and HAP-emitting material used. E. The amount of VOCs and the amount of each HAP emitted from each material. F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material. G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons). [R307-401-8] II.B.5.c The owner/operator shall store VOC- or HAP-containing materials and VOC- or HAP-laden rags in covered containers, except when in use. [R307-401-8] II.B.5.d The owner/operator shall comply with the applicable requirements in R307-325 and R307-335. [R307-325, R307-335] II.B.6 Storage Tank (Storage Vessel) Requirements II.B.6.a The owner/operator shall not process more than the following throughput for the indicated tanks: A. Tank 52: 63,50,000 gallons of Citric Acid per rolling 12-month period. B. Tank 60: 606,466 gallons of Ethanol per rolling 12-month period. C. Tanks 63 and 63A: 3,495,680 gallons, combined, of volatile organic liquids with a true vapor pressure of no more than 34.3 kPa per rolling 12-month period. D. Tank 66: 63,510,000 gallons of PEG 400 per rolling 12-month period. [R307-401-8] DAQE-AN104630032-24 Page 11 II.B.6.a.1 The owner/operator shall: A. Determine the volume processed through each tank using process flow meters and/or sales records. B. Determine true vapor pressure with ASTM Method 2879. C. Record the volume processed through each tank on a daily basis. D. Use the monthly volume processed through each tank record to calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. E. Keep the volume processed through each tank record for all periods the plant is in operation. [R307-401-8] II.B.6.b The owner/operator shall not process a volatile organic liquid that contains any HAP and/or VOC except for ethanol through Tanks 63 and 63A. [R307-401-8] II.B.6.b.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the Safety Data Sheet (SDS) for the organic liquid. [R307-401-8] II.B.6.c The owner/operator shall keep the storage tank thief hatches and other tank openings closed and sealed except during tank unloading or other maintenance activities. [R307-401-8] II.B.6.d The owner/operator shall install a carbon canister of both Tank 63 and Tank 63A with a control efficiency of no less than 95%. [40 CFR 60 Subpart Kb, R307-401-8] II.B.6.d.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed carbon canister filters. [R307-401-8] II.B.6.e The owner/operator shall inspect and replaced the carbon canisters in accordance with the manufacturer's recommendations to ensure the 95% control efficiency is met. [R307-401-8] II.B.7 Baghouses and Bin Vents Requirements. II.B.7.a The owner/operator shall not allow visible emissions from baghouses and bin vents to exceed 10% opacity. [R307-305, R307-401-8] II.B.7.b The owner/operator shall install a manometer or magnehelic pressure gauge to measure the pressure drop across each baghouse filter. [R307-401-8] II.B.7.b.1 The pressure gauges shall be located such that a UDAQ representative/operator can safely read the indicator at any time. [R307-401-8] II.B.7.b.2 The pressure gauges shall each measure the pressure drop in 1-inch water column increments or less. [R307-401-8] II.B.7.c During operation of the baghouses, the owner/operator shall maintain the static pressure drop across each baghouse between 1.0 and 6.0 inches of water column. [R307-401-8] II.B.7.c.1 The owner/operator shall record the pressure drop at least once per operating day while each baghouse is operating. [R307-401-8] DAQE-AN104630032-24 Page 12 II.B.7.c.2 The owner/operator shall maintain the following records of the pressure drop readings: A. Unit identification; B. Date of reading; C. Daily pressure drop readings. [R307-401-8] II.B.7.d At least once every 12 months, the owner/operator shall calibrate the pressure gauges in accordance with the manufacturer's instructions or replace the gauges. [R307-401-8] II.B.7.d.1 The owner/operator shall maintain records of all pressure gauge calibrations and replacements. [R307-401-8] II.B.8 Combustion Equipment Requirements. II.B.8.a The owner/operator shall not operate each emergency engine on site for more than 100 hours per calendar year for maintenance checks and readiness testing. Each emergency engine on site may be operated for up to 50 hours per calendar year in non-emergency situations. Any operation in non-emergency situations shall be counted as part of the 100 hours per calendar year for maintenance and testing. There is no time limit on the use of the engines during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.8.a.1 To determine compliance with the annual operation limitation, records documenting the operation of each emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used. B. The duration of operation in hours. C. The reason for the emergency engine usage. [R307-401-8] II.B.8.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter for each emergency engine. [R307-401-8] II.B.8.b The owner/operator shall only use diesel fuel (e.g., fuel oil #1, #2, or diesel fuel oil additives) as fuel in the 74 hp emergency engine. The owner/operator shall only use natural gas as fuel in the conditioning drum heater, the 16 hp emergency engine, and all the boilers, water heaters, and heat transfer labelers. [R307-401-8] II.B.8.b.1 The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [R307-401-8] II.B.8.b.2 To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8] II.B.8.c Visible emissions from all-natural gas combustion equipment shall not exceed 10% opacity. [R307-201] II.B.8.d The owner/operator shall install boilers that each have low NOx burners certified by the manufacturer. [R307-401-8] DAQE-AN104630032-24 Page 13 II.B.8.e The owner/operator shall keep the manufacturer certification for each low NOx burners on site as long as each boiler is in operation. [R307-401-8] II.B.8.e.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed low-NOx burners. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN104630031-23 dated August 9, 2023 Is Derived From NOI dated March 11, 2024 DAQE-AN104630032-24 Page 14 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE- RN104630032 April 10, 2024 Andrew Riddick Henkel Corporation 3540 West 1987 South Salt Lake City, UT 84104 Andrew.Riddick@henkel.com Dear Andrew Riddick, Re: Engineer Review - Administrative Amendment: Administrative Amendment to Approval Order DAQE-AN104630031-23 to Allow for Organic Liquids Handling Flexibility under R307-401-12 Project Number: N104630032 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review (NSR) permitting program. Henkel Corporation should complete this review within 10 business days of receipt. Henkel Corporation should contact Christine Bodell at (385) 290-2690 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Christine Bodell at cbodell@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an Approval Order (AO) for signature by the DAQ Director. If Henkel Corporation does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Henkel Corporation has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature _____________________________________________________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N104630032 Owner Name Henkel Corporation Mailing Address 3540 West 1987 South Salt Lake City, UT, 84104 Source Name Henkel Corporation- Detergent Manufacturing Plant Source Location 3540 West 1987 South Salt Lake City, UT 84104 UTM Projection 417,544 m Easting, 4,509,170 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 2841 (Soaps & Other Detergent, Except Specialty Cleaners) Source Contact Andrew Riddick Phone Number (270) 392-9845 Email Andrew.Riddick@henkel.com Billing Contact Andrew Riddick Phone Number (270) 392-9845 Email Andrew.Riddick@henkel.com Project Engineer Christine Bodell, Engineer Phone Number (385) 290-2690 Email cbodell@utah.gov Notice of Intent (NOI) Submitted March 11, 2024 Date of Accepted Application March 14, 2024 Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 2 SOURCE DESCRIPTION General Description Henkel Corporation (Henkel), operates a soap and detergent manufacturing plant in Salt Lake City. Emissions are primarily associated with particulate matter control equipment and natural gas combustion in a variety of boilers and emergency generators. Henkel employs baghouses, bin vents, dust collectors, and scrubbers. NSR Classification: Administrative Amendment Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: SM Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), Dc: Standards of Performance for Small Industrial-Commercial-Institutional Steam Generating Units NSPS (Part 60), Kb: Standards of Performance for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid Storage Vessels) for Which Construction, Reconstruction, or Modification Commenced After July 23, 1984 NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines NSPS (Part 60), JJJJ: Standards of Performance for Stationary Spark Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines Project Proposal Administrative Amendment to Approval Order DAQE-AN104630031-23 to Allow for Organic Liquids Handling Flexibility under R307-401-12 Project Description Henkel is currently permitted to process a throughput up to 3,495,680 gallons, combined, of Armosoft DEQ per rolling 12-month period in Tanks 63 & 63A (Condition II.B.6.a in Approval Order DAQE-AN104630031-23). The current VOC potential to emit (PTE) of Tanks 63 & 63A were estimated in 2023 by using the Emission Master Tanks Software based on the 2019 EPA Revision. It was established that Armosoft DEQ had a true vapor pressure of 34.3 kPa, as determined in a laboratory using New Source Performance Standard (NSPS)-approved ASTM method 2879. The VOC emitted from Armosoft is ethanol. Henkel would like to replace "Armosoft DEQ" with "Volatile Organic Liquid with a true vapor pressure not to exceed 34.3 kPa". The removal of the specific brand name would provide Henkel with flexibility to handle other organic liquids with the same or lower true vapor pressure. Henkel Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 3 will not be permitted to handle a volatile organic liquid that contains any VOCs except for ethanol through Tanks 63 & 63A. Additionally, the volatile organic liquid will not contain any HAPs. Henkel is not requesting to increase the maximum allowable throughput of Tanks 63 & 63A. Therefore, no emissions are increasing. This project meets the requirements of UAC R307- 401-12 Reduction in Air Pollutants and does not require a public comment period. EMISSION IMPACT ANALYSIS This is an administrative amendment under R307-401-12. No changes to equipment or emissions are being made at this time. Therefore, modeling is not required. [Last updated April 10, 2024] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 4 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) Ammonia 0 0.85 CO2 Equivalent 0 19094.00 Carbon Monoxide 0 13.47 Nitrogen Oxides 0 16.19 Particulate Matter - PM10 0 28.39 Particulate Matter - PM2.5 0 28.27 Sulfur Dioxide 0 0.13 Volatile Organic Compounds 0 9.87 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Formaldehyde (CAS #50000) 0 36 Generic HAPs (CAS #GHAPS) 0 35 Glycol Ethers (CAS #EDF109) 0 186 Hexane (CAS #110543) 0 571 Methanol (CAS #67561) 0 634 Change (TPY) Total (TPY) Total HAPs 0 0.73 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 5 Review of BACT for New/Modified Emission Units 1. BACT review regarding Removing Brand Name This is an administrative amendment under R307-401-12. No changes to equipment or emissions are being made at this time. Therefore, a BACT analysis is not required. [Last updated April 10, 2024] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307- 150] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 6 SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 Detergent Manufacturing Plant II.A.2 Baghouses and Bin Vents- Group #2 Outlet Emissions Rate: 0.02 grains/dscf Designations: LSL-6, SODA BV-1, LSL-9, LQD-5, LSL-1 Outlet Emissions Rates: 0.007 grains/dscf Designation: LSL-4 II.A.3 Baghouses and Bin Vents- Group #3 Outlet Emission Rates: 0.005 grains/dscf Designations: LSL-8 II.A.4 Baghouses and Bin Vents- Group #4 Outlet Emission Rate: 0.016 grains/dscf Designations: MESBH-1 and MESBV-2 II.A.5 One (1) Scrubber LSS-3/1 Model: Clean Gas System Size 54 II.A.6 One (1) Conditioning Drum Designation: LSL-3 Rating: 2.5 MMBtu/hr Fuel: Natural Gas II.A.7 Five (5) Boilers Fuel: Natural Gas Ratings: (1) 8.37 MMBtu/hr (2) 6.4 MMBtu/hr (3) 0.77 MMBtu/hr (4) 2.51 MMBtu/hr (5) 14.0 MMBtu/hr II.A.8 Five (5) Heat transfer Labelers Four (4) heat transfer labelers: Four (4) burners each Labeler Ratings: 0.17 MMBtu/hr Each (42,000 Btu/hr per burner) One (1) heat transfer labeler: Six (6) burners Labeler Rating: 0.25 MMBtu/hr Each (42,000 Btu/hr per burner) Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 7 II.A.9 VideoJet coders Including 32 VideoJet coders II.A.10 One (1) Emergency Generator Engine Fuel: Diesel Engine Rating: 74 hp Manufacture Year: 2004 NSPS Applicability: None MACT Applicability: Subpart ZZZZ II.A.11 One (1) Emergency Generator Engine Fuel: Natural Gas Rating: 16 hp Manufacture Year: 1969 NSPS Applicability: None MACT Applicability: Subpart ZZZZ II.A.12 Six (6) Pre-mixers II.A.13 One (1) Paint booth Rating: 2,000 scfm equipped Control: high efficiency over-spray filters II.A.14 Ethanol and Other Organic Solution Storage Tanks Tank 52 Capacity: 29,000 gallons Contents: Citric Acid NSPS Applicability: None Tank 60 Capacity: 29,000 gallons Contents: Denatured Ethanol NSPS Applicability: None Tank 63 & Tank 63A Capacity: 34,000 gallons each Contents: Volatile Organic Liquid with a True Vapor Pressure not to exceed 34.3 kPa NSPS Applicability: Subpart Kb Tank 66 Capacity: 29,000 gallons Contents: Polyethylene glycol (PEG) 400 NSPS Applicability: None Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 8 II.A.15 Storage Tanks Tank 1 (34,000 gallons) Tank 2 (32,700 gallons) Tank 21 (21,000 gallons) Tank 22 (34,000 gallons) Tank 23 (29,000 gallons) Tank 27 (34,000 gallons) Tank 45 (21,000 gallons) Tank 49 (34,000 gallons) Tank 65 (34,000 gallons) Tank 65A (34,000 gallons) NSPS Applicability: None Above tanks, except for Tank 2, contain a liquid with a VOC maximum true vapor pressure less than 15.0 kPa. Tank 2 does not contain a volatile organic liquid. II.A.16 Two (2) Vacuum pumps MESVP-1 & MESVP-2 Rating: 704 cfm Each Model Busch RC1000 for MES conveying system II.A.17 One (1) Blower LSL-10 Rating: 600 cfm II.A.18 Plastic processing equipment Plastic and additive transfer, storage, mixing and grinding equipment Control: 13 sock filters II.A.19 Blow molding equipment Vents in the blow molding area II.A.20 Five (5) Electrostatic precipitators Smog Hog ESP mist collectors in the blow molding area II.A.21 Six (6) Cooling towers II.A.22 Four (4) Maintenance shops Including: parts cleaners, welding equipment, exhaust vents, welding fume collector, and grit blasting equipment II.A.23 Hoods Miscellaneous ventilation hoods in QA labs II.A.24 Miscellaneous equipment Liquid transfer, storage and mixing equipment including raw material and product storage tanks, pumps, vents, blending equipment, and bottle-filling equipment Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 9 SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Opacity Requirement. II.B.1.a The owner/operator shall not allow visible emissions to exceed 20% opacity unless otherwise specified within this AO. [R307-401-8] II.B.1.a.1 Unless otherwise specified in this AO, opacity observations of visible emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-305-3] II.B.2 Site-Wide Natural Gas Requirements. II.B.2.a The owner/operator shall not consume more than 533.7 million scf of natural gas per rolling 12-month period. [R307-401-8] II.B.2.a.1 The owner/operator shall: A. Determine consumption by utility billing statements B. Record consumption on a monthly basis C. Use the consumption data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the consumption records for all periods the plant is in operation. [R307-401-8] II.B.3 Liquid Detergent Production Requirements. II.B.3.a The owner/operator shall not produce more than 1,700,000,000 pounds of liquid detergents per rolling 12-month period. [R307-401-8] II.B.3.a.1 The owner/operator shall: A. Determine production with production records B. Record production on a daily basis C. Use the production data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the production records for all periods the plant is in operation. [R307-401-8] II.B.4 Scrubber Requirements. II.B.4.a The owner/operator shall maintain the liquid flow rate of Scrubber LSS-3/1 to not be less than 56 gallons/minute. [R307-401-8] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 10 II.B.4.a.1 The liquid flow rate shall be monitored with a flow meter located such that an inspector/operator can safely read the output anytime. [R307-401-8] II.B.4.a.2 The owner/operator shall install, calibrate, maintain, and operate each monitoring device certified by the manufacturer. Calibration shall be on an annual basis according to the manufacturer's instructions. Daily records of reading shall be maintained. [R307-401-8] II.B.5 VOC and HAP Requirements. II.B.5.a The owner/operator shall not allow visible emissions from the printing press dryers to exceed 10% opacity. [R307-401-8] II.B.5.b NEW The owner/operator shall not emit more than the following from evaporative sources (painting, printing, coating, and/or cleaning) on site: 8.94 tons of VOC including HAPs per rolling 12-month period 0.43 tons of all other HAPs combined per rolling 12-month period. [R307-351, R307-401-8] II.B.5.b.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed]. [R307-401-8] II.B.5.b.2 The owner/operator shall keep records each month of the following: A. The name (as per the Safety Data Sheet) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons). [R307-401-8] II.B.5.c The owner/operator shall store VOC- or HAP-containing materials and VOC- or HAP-laden rags in covered containers except when in use. [R307-401-8] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 11 II.B.5.d The owner/operator shall comply with the applicable requirements in R307-325 and R307- 335. [R307-325, R307-335] II.B.6 Storage Tank (Storage Vessel) Requirements II.B.6.a NEW The owner/operator shall not process more than the following throughput for the indicated tanks: A. Tank 52: 63,50,000 gallons of Citric Acid per rolling 12-month period B. Tank 60: 606,466 gallons of Ethanol per rolling 12-month period C. Tanks 63 & 63A: 3,495,680 gallons, combined, of volatile organic liquids with a true vapor pressure no more than 34.3 kPa per rolling 12-month period D. Tank 66: 63,510,000 gallons of PEG 400 per rolling 12-month period [R307-401-8] II.B.6.a.1 NEW The owner/operator shall: A. Determine the volume processed through each tank using process flow meters and/or sales records. B. Determine true vapor pressure with ASTM Method 2879 C. Record the volume processed through each tank on a daily basis. D. Use the monthly volume processed through each tank records to calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. E. Keep the volume processed through each tank records for all periods the plant is in operation. [R307-401-8] II.B.6.b NEW The owner/operator shall not process a volatile organic liquid that contains any HAP and/or VOC except for ethanol through Tanks 63 & 63A. [R307-401-8] II.B.6.b.1 NEW To demonstrate compliance with the above condition, the owner/operator shall maintain records of the Safety Data Sheet (SDS) for the organic liquid. [R307-401-8] II.B.6.c The owner/operator shall keep the storage tank thief hatches and other tank openings closed and sealed except during tank unloading or other maintenance activities. [R307-401-8] II.B.6.d The owner/operator shall install a carbon canister of both Tank 63 and Tank 63A with a control efficiency of no less than 95%. [40 CFR 60 Subpart Kb, R307-401-8] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 12 II.B.6.d.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed carbon canister filters. [R307-401-8] II.B.6.e The owner/operator shall inspect and replaced the carbon canisters in accordance with the manufacturer's recommendations to ensure the 95% control efficiency is met. [R307-401-8] II.B.7 Baghouses and Bin Vents Requirements. II.B.7.a The owner/operator shall not allow visible emissions from baghouses and bin vents to exceed 10% opacity. [R307-305, R307-401-8] II.B.7.b The owner/operator shall install a manometer or magnehelic pressure gauge to measure the pressure drop across each baghouse filter. [R307-401-8] II.B.7.b.1 The pressure gauges shall be located such that a UDAQ representative/operator can safely read the indicator at any time. [R307-401-8] II.B.7.b.2 The pressure gauges shall each measure the pressure drop in 1-inch water column increments or less. [R307-401-8] II.B.7.c During operation of the baghouses, the owner/operator shall maintain the static pressure drop across each baghouse between 1.0 and 6.0 inches of water column. [R307-401-8] II.B.7.c.1 The owner/operator shall record the pressure drop at least once per operating day while each baghouse is operating. [R307-401-8] II.B.7.c.2 The owner/operator shall maintain the following records of the pressure drop readings: A. Unit identification; B. Date of reading; C. Daily pressure drop readings. [R307-401-8] II.B.7.d At least once every 12 months, the owner/operator shall calibrate the pressure gauges in accordance with the manufacturer's instructions or replace the gauges. [R307-401-8] II.B.7.d.1 The owner/operator shall maintain records of all pressure gauge calibrations and replacements. [R307-401-8] II.B.8 Combustion Equipment Requirements. II.B.8.a The owner/operator shall not operate each emergency engine on site for more than 100 hours per calendar year for maintenance checks and readiness testing. Each emergency engine on site may be operated for up to 50 hours per calendrer year in non-emergency situations. Any operation in non-emergency situations shall be counted as part of the 100 hours per calendar year for maintenance and testing. There is no time limit on the use of the engines during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 13 II.B.8.a.1 To determine compliance with the annual operation limitation, records documenting the operation of each emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used B. The duration of operation in hours C. The reason for the emergency engine usage. [R307-401-8] II.B.8.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter for each emergency engine. [R307-401-8] II.B.8.b The owner/operator shall only use diesel fuel (e.g. fuel oil #1, #2, or diesel fuel oil additives) as fuel in the 74 hp emergency engine. The owner/operator shall only use natural gas as fuel in the conditioning drum heater, the 16 hp emergency engine, and all the boilers, water heaters, and heat transfer labelers. [R307-401-8] II.B.8.b.1 The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [R307-401-8] II.B.8.b.2 To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8] II.B.8.c Visible emissions from all natural gas combustion equipment shall not exceed 10% opacity. [R307-201] II.B.8.d The owner/operator shall install boilers that each have low NOx burners certified by the manufacturer. [R307-401-8] II.B.8.e The owner/operator shall keep the manufacturer certification for each low NOx burners on site as long as each boiler is in operation. [R307-401-8] II.B.8.e.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed low-NOx burners. [R307- 401-8] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 14 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN104630031-23 dated August 9, 2023 Is Derived From NOI dated March 11, 2024 REVIEWER COMMENTS 1. Comment regarding Federal Applicability (NSPS): 40 CFR Part 60 (NSPS) Subpart Dc (Standards of Performance for Small Industrial-Commercial- Institutional Steam Generating Units) Subpart Dc applies to owners and operators of steam generating units for which construction, modification, or reconstruction is commenced after June 9, 1989 and that has a maximum design heat input capacity of 100 million British thermal units per hour (MMBtu/hr) or less, but greater than or equal to 10 MMBtu/hr. Steam generating unit means a device that combusts any fuel and produces steam or heats water or heats any heat transfer medium. Henkel has miscellaneous boilers and a water heater that are subject to this subpart. Therefore, NSPS Subpart Dc applies to this facility. 40 CFR Part 60 (NSPS) Subpart Kb (Standards of Performance for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid Storage Vessels) for Which Construction, Reconstruction, or Modification Commenced After July 23, 1984) The affected facilities to which this subpart applies is each storage vessel with a capacity greater than or equal to 75 cubic meters (19,813 gallons) that is used to store volatile organic liquids (VOL) for which construction, reconstruction, or modification is commenced after July 23, 1984. This subpart does not apply to storage vessels with a capacity greater than or equal to 151 cubic meters (39,890 gallons) storing a liquid with a maximum true vapor pressure less than 3.5 kilopascals (kPa) or with a capacity greater than or equal to 75 cubic meters (19,813 gallons) but less than 151 cubic meters (39890 gallons) storing a liquid with a maximum true vapor pressure less than 15.0 kPa. Only two of the six storage tanks apply to this NSPS standard: Tank 1 (Sulfonic Acid), Tank 65 (70% SLES), Tank 65A (70% SLES) - Each tank has a capacity of 32,700 gallons, but contains contents with a maximum true vapor pressure of less than 15.0 kPa. Therefore, Subpart Kb does not apply to Tank 1, Tank 65, and Tank 65A. Tank 2 (Sodium Silicate Liquid Alkaline) - This tank does not contain a volatile organic liquid. Therefore, Subpart Kb does not apply to Tank 2. Tanks 63 and 63A (Organic Liquid w/Ethanol) - Each tank has a capacity of 32,700 gallons and contains contents exceeding a maximum true vapor pressure of 15.0 kPa. Therefore, Subpark Kb applies to Tank 63 and Tank 63A. [Last updated April 10, 2024] 2. Comment regarding Federal Applicability (MACT): 40 CFR Part 63 (MACT) Subpart ZZZZ (Standards of Performance for Stationary Compression Ignition Internal Combustion Engines) Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 15 All stationary engines on site are subject to 40 CFR Part 63, Subpart ZZZZ National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines). The provisions of Subpart ZZZZ apply as the stationary reciprocating internal combustion engine (RICE) is at an area source of HAP emissions and are applicable to one (1) diesel-fired, 74 HP, emergency generator engine and one (1) natural gas-fired, 16 HP, emergency engine. Each engine is not designated as nonroad, is not exempt, and is an affected sources under this regulation. The stationary engines on site that are subject to Subpart ZZZZ must meet the requirements of Subpart IIII. No further requirements apply to the engines under Subpart ZZZZ. [Last updated March 13, 2024] 3. Comment regarding Title V Applicability: Title V of the 1990 Clean Air Act (Title V) applies to the following: 1. Any major source 2. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources; 3. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants. 4. Any Title IV affected source. This facility is not a major source and is not a Title IV source. The facility is not subject to 40 CFR 61 (NESHAP) regulations. This facility is subject to 40 CFR 60 (NSPS) Subparts A, Dc, and Kb and 40 CFR 63 (MACT) Subparts A and ZZZZ. NSPS Subparts Dc and Kb do not specifically exempt the facility from the obligation to obtain a Title V permit. However, this facility is only subject to record-keeping requirements under NSPS Subparts Dc and Kb, and is not subject to a standard or limitation. Therefore, this facility is not a Title V source. [Last updated March 13, 2024] Engineer Review N104630032: Henkel Corporation- Detergent Manufacturing Plant April 10, 2024 Page 16 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Page 1 Revision 2 October 14, 2022 Attn: Permitting Utah Division of Air Quality 195 North 1950 West Salt Lake City, UT 84116 RE: Notice of Intent – Revision 2 Modification to Approval Order DAQE-AN104630029-19 Henkel US Operations Corporation Salt Lake City, Utah Dear Sir/Madam, Henkel US Operations Corporation ("Henkel") is submitting this Revision 2 to the last Notice of Intent (NOI) for a minor New Source Review revision to its Approval Order (AO) DAQE-AN104630029-19. The appropriate NOI application forms are included in Appendix A of this application. The changes requested follow. This revision corrects inconsistences found in earlier NOI submissions and responds to questions directed to Ms. Suzy Smith of ERM, Henkel’s environmental consultant, from Ms. Christine Bodell in an email dated July 29, 2022. The items highlighted in green pertain to revisions to the most recent version of this NOI. The items highlighted in yellow pertain to items revised in Revision 1. Henkel requests that Utah Division of Air Quality (UDAQ) include serial numbers to equipment where stated in this permit application when updating the AO. Names to equipment potentially change at the facility; however, serial numbers remain constant. Also, if UDAQ perceives no benefit to the UDAQ or Henkel in grouping air pollution control devices in the AO, such grouping can be omitted. It is not apparent that the groups in the AO serve a purpose. A change in the Potential to Emit (PTE) attributed to the following: • The PTE formerly included a R&D Laboratory. Emissions from this source are removed from the PTE analysis because the site does not have a R&D Laboratory. • The PTE formerly included carton printing. Emissions from this source are removed from the PTE analysis because the site does not conduct carton printing. Page 2 Revision 2 • The PTE formerly included refrigerant leaks from air conditioners and chillers subject to 40 CFR 82, which are normally not subject to air permitting. These emissions are removed from the PTE analysis. • LDQ-7 baghouse of Group 2 in the AO was removed from service because the process it was serving was removed. • LSL-7 Pkg GV Unit baghouse of Group 3 in the AO was removed from service because the process it was serving was removed. • SAS-1 Soda Ash Scrubber in the AO was removed from service. • LQD-4 baghouse was removed from service because the process it was serving was removed. • LQD-5 baghouse was added in the NOI because this baghouse was brought online. LQD-5 baghouse parameters have been revised from Revision 1. • LSL-1 baghouse, which services the Agglomerator 3 room, was added. • The PTE for the facility now accounts for the emissions from 13 sock filters that service plastic regrind operations, and vent outdoors. • The PTE includes information for five fabric filters that vent indoors. These filters are not considered emission points by the UDAQ. This was included in this NOI for completeness, but is assumed to have negligible particulate matter emissions to the environment; and therefore not included in the PTE. • Two Conditioning Drum Heaters were removed, leaving one remaining. The remaining Conditioning Drum is LSL-3 with a heat input capacity of 2.5 MMBtu/hr. • Three of the five permitted boilers on site were removed. The rated heat input capacity of each of the boilers is 2.08 MMBtu/hr, 2.08 MMBtu/hr, and 14 MMBtu/hr. The 7.3 MMBtu/hr LQD3PV01, included in the Initial NOI version, is a pressure vessel used for the 200 HP Steam Boiler. LQD3PV01 is not a boiler. • The Armstrong Flo Direct Water Heater with a heat input capacity of 14 MMBtu/hr was removed. This 14 MMBtu/hr Armstrong Flo Direct Water Heater was not removed, it is still in operation. • Addition of a 0.77 MMBtu/hr Parker Boiler. • Addition of a 1.62 MMBtu/hr Bessamaire Direct Industrial Air Handling Unit. • Correction of permitted Parker Boiler from the 6.4 MMBtu/hr to 6.3 MMBtu/hr. • The 13.05 MMBtu/hr miscellaneous boilers were removed. • Removal of two Natural Gas Emergency Generator Engines (33 HP and 255 HP). • Addition of an existing 16 HP Natural Gas Emergency Engine on the AO is requested. • Correction of the Diesel Emergency Generator Engine rating from 79 HP to 74 HP. Page 3 Revision 2 • Correction of the description of the heat transfer labelers to 5 heat transfer labelers, each with four burners and 1 heat transfer labeler with six burners (each burner has a rated heat input capacity of 42,000 Btu/hr for a total of 1,092,000 Btu/hr). • Accounted for the permitted Paint Booth. This paint booth is currently used for maintenance. Maintenance uses this paint booth to spray miscellaneous parts with aerosol spray paint cans. Henkel wishes to retain the paint booth in UDAQ records. • Accounted for unloading of soda ash and salt from railcar fugitive emissions. Emissions were quantified using AP-42 Emission Factors for Aggregate Handling and Storage Piles. • Addition of six pre-mixers were added to the existing two, four are currently in use. Six can potentially be used to prepare a solution of the optical brightener. The pre-mixers are a source of particulate matter and when using the optical brightener, the solution can emit a hazardous air pollutant (HAP). Emissions occur from charging of solids into the pre-mixer. The mixed solution is piped to its mixing tank downstream for use in formulation. • The PTE for natural gas emissions was based on the heat input capacity of each boiler or heater rather than the allowable site natural gas use of 533.7 million scf per rolling 12-month period. The PTE of the collective annual maximum design natural gas use was less than the allowable site natural gas use. • Repurposing Storage Tanks 63 and 63A, which contain Armosoft DEQ. Armosoft DEQ contains ethanol and is stored at an elevated temperature. These two tanks will be subject to 40 CFR 60 Subpart Kb. The controlled emissions from these sources are now quantified in the PTE. • Emissions from Tanks 63, 63A, and 60 were adjusted to reflect EPA’s 2019 revision to calculation methodologies. • Addition of Storage Tanks 65 and 65A, which will contain 70% SLES, and Storage Tank 1, which contains Sulfonic Acid. SLES and sulfonic acid contain organic material, but have low or no volatility with negligible if any VOC emissions at the storage tank operating temperature. • Addition of Storage Tank 2, which contains Sodium Silicate Liquid Alkaline. Sodium Silicate Liquid Alkaline is an inorganic material that has low to no volatility. • The PTE estimates account for potential emissions of Dimethyl Formamide, a Hazardous Air Pollutant (HAP), which can be present in low quantities in optical brightener. Optical brightener is a solid material charged in pre-mixers. Some of Page 4 Revision 2 the pre-mixers are controlled with fabric filters. For quantifying PTE, the PM from charging the pre-mixers is assumed uncontrolled. (Reworded) • The Summary sheet was updated and corrected in this revision. o Revised the Emergency Engine emissions in the Summary PTE Table to match the detailed summaries in the Emergency Engine Sheet. o Accounted for an additional baghouse, corrected parameters on another baghouse, removed a soda ash scrubber, and included emissions from 13 fabric filters (sock filters). o Added missing boilers and removed obsolete boilers. o Accounted for maintenance paint booth emissions. o Accounted for railcar unloading fugitive emissions. o Quantified controlled emissions from the carbon canisters on Tanks 63 and 63A. o Revised Emission Master Tanks Software to calculate breathing and working losses from Tanks 60, 63, and 63A based on EPA’s 2019 revision. FACILITY DESCRIPTION Henkel operates under AO DAQE-AN104630029-19, issued December 5, 2019. This AO is for a minor source of emissions. The stationary source manufactures soap and detergent products. Henkel formulates its product in blending systems. The stationary source uses storage tanks, mixing vessels, boilers, emergency generators, and a printing operation that adds dates to a label purchased to support production. A site layout is provided in Appendix B. The stationary source is located in Salt Lake County, which is a: • Serious non-attainment area for PM2.5 • A primary and secondary non-attainment area for SO2 • A 2015 8-hour ozone non-attainment area to the Southern Wasatch Front of Salt Lake County. PROJECT A summary of the PTE in the permit and in this permit application is provided in Table 1 below. The supporting calculations for the site’s PTE is detailed in Appendix C. Page 5 Revision 2 Table 1. Potential to Emit Regulated Air Pollutant Current AO This NOI Change Criteria Pollutants in tons per year Ammonia 0.85 0.85 0.00 CO2 Equivalent 32,813.27 19,088.32 -13,724.95 Carbon Monoxide 4.871 13.47 +8.60 Nitrogen Oxides 21.95 16.05 -5.90 Particulate Matter–PM10 20.93 29.12 +8.19 Particulate Matter-PM2.5 20.92 28.99 +8.07 Sulfur Dioxide 0.16 0.13 -0.03 Volatile Organic Compounds 11.48 9.91 -1.57 Hazardous Air Pollutant in tons per year Formaldehyde (CAS #50000) 0.023 0.018 -0.005 Generic HAPs (CAS #GHAPS)2 0.010 0.010 0.00 Glycol Ethers (CAS #EDF109) 0.093 0.093 0.00 Hexane (CAS #110543) 0.481 0.286 -0.195 Methanol (CAS #67561) 0.317 0.317 +0.00 Trichloroethylene (CAS #79016) 3.90 0.00 -3.90 Total HAP in tons per year3 4.82 0.723 -4.10 1 Incorrectly transcribed from the previous NOI used to develop this table in the AO 2 The generic HAP is attributed to liquid formulation where any HAP can occur. 3 The total HAP PTE at the facility was calculated to be 6.16 tons per year. The UDAQ Form 5 reflects the total calculated PTE of 6.16 tons per year too. The PTE in the Table 1 reflects the sum of the PTE for only the HAP currently listed in the AO and changes with respect to those HAP. The following describes changes Henkel wishes to include in its modified AO. Accounting for Potential PM and HAP from Charging Optical Brightener in a Pre-Mixer Henkel charges six pre-mixers with solid materials to prepare formulation for later use downstream in the mixing tanks. Of the six, four are in use and two are out of service. A pre-determined amount of solids materials is poured into the pre-mixers and result in dust emissions. The pre-mixers are operated in batches with a minimum batch time of 4 hours. A maximum of 1,000 pounds of solid material is charged into a pre-mixer per batch. For worst-case scenario for HAP emissions, the solids material optical brightener is assumed to be used in the six pre-mixers. The optical brightener, Tinopal contains up to 0.2% dimethyl formamide. The PTE PM and HAP is based on uncontrolled emissions. A Safety Data Sheet (SDS) for the current brand of optical brightener (Tinopal) is included in Appendix D. Page 6 Revision 2 Negligibly Volatile Organic Liquid Material in New Storage Tanks Henkel is installing three new storage tanks, which will contain organic liquids. Storage Tanks 65 and 65A will contain 70% SLES. The organic component in this material has a high molar mass, which is not conducive to evaporation. The VOC emissions from these tanks are negligible, if at all volatile. The SLES will be stored at 130ºF to maintain low viscosity of the liquid for adequate flow. Despite the additional heat, the molecular mass of the SLES will still lack the fugacity to escape the liquid surface into the air. Storage Tank 1 will contain sulfonic acid. Sulfonic acid is also an organic liquid with low volatility due to its high molar mass and the ability of the sulfonic acid to dissociate in water. The SLES and sulfonic acid SDS are provided in Appendix D. The range of the chemical molar mass in these mixture can be deduced from the information in the SDS. New Inorganic Liquid Storage Tank Additionally, Tank 2 will be installed and will store sodium silicate liquid alkaline. The SDS in Appendix D shows that this material does not contain organic compounds. Additionally, this material does not emit regulated air pollutants. Volatile Organic Liquid Storage Tanks Two 34,000-gallon storage tanks, Tank 63 and Tank 63A will be repurposed to store Armosoft DEQ. Armosoft DEQ contains a heavy organic molecule mixed with ethanol. Ethanol is a volatile organic liquid. The Armosoft DEQ will be stored at 160 ºF. This storage temperature will cause the material to evaporate at a vapor pressure of 34.3 kilopascals, as determined in a laboratory by use of the New Source Performance Standard (NSPS)-approved ASTM method. These two storage tanks will be subject to add-on air pollution control requirements as provided in the NSPS, 40 CFR 60 Subpart Kb for Volatile Organic Liquid Storage Tanks. The SDS for Armosoft DEQ is provided in Appendix D. MAXIMUM EMISSIONS QUANTIFICATION PM and HAP Emissions from Charging Solids into the Pre-Mixer There are eight pre-mixers onsite, which will be charged with solid materials. Six of the eight pre-mixers will be charged with the optical brightener, Tinopal, which contains a HAP, 0.2% by weight dimethyl formamide. The pre-mixers operate in batches, with a batch time of 4 hours and a maximum solids charge rate of 1,000 pounds per batch. For the maximum emissions from the source, it was assumed that all eight pre-mixers will be charged with the optical brightener with a maximum of 2,190 batches per year at a rate of 1,000 pounds per batch. The emission factor for loading of solids into the pre- mixers was quantified by the method described in AP-42, Section 13.2.4: Aggregate Handling and Storage Piles and selected as the optimum method to represent the Page 7 Revision 2 charging of pre-mixers with solids material. This method is based on the velocity of the downward pour of the material will be stripped of dust from the shearing forces of air interfacing with the solids particles. The maximum air shearing speed as the solids material as it reaches the end of a 12-foot drop was used in the method where wind speed is required. The annual PTE from PM-10 and PM-2.5 for the facility is 0.19 tons per year and 0.03 tons per year, respectively. The HAP emissions from the use of the optical brightener, were conservatively derived from particulate matter emissions with an aerodynamic diameter less than 30 μm. The annual PTE from HAP is 0.0008 tons per year. Organic Liquid Storage Tanks The air emissions from Volatile Organic Compounds (VOC) from Storage Tanks 63 and 63A are attributed to the ethanol ingredient in the Armosoft DEQ material. Other organic matter is present in the material, but the high molar mass of these components result in negligible vapor pressures, if any. Tank 60, which contains 200-Proof Denatured Ethanol, will have VOC emissions from the ethanol and the isopropyl alcohol component in the material. Other organic compounds exist in trace amounts. Tank 60 is an existing tank. The SDS for the Armosoft DEQ material did not list any Hazardous Air Pollutants (HAP) as ingredients in the material stored. The 200-Proof Denatured Ethanol SDS listed trace amounts of acetone, methanol and acetaldehyde. These HAP are in trace amounts and will release a negligible amount of emissions. Therefore, the released vapors from both tanks did not include HAP emissions from the trace amounts. The Emission Master Model for Storage Tanks was used to quantify uncontrolled VOC releases from Tanks 63, 63A, and 60. The storage tank characteristics that were used in the model are provided in Table 2. The vapor pressure of the Armosoft DEQ was based on laboratory-generated data, attached in Appendix E. For the Armosoft Storage Tanks, the model developed Antoine Equation coefficients based on the laboratory-measured vapor pressures with corresponding temperatures. For the 200-proof ethanol storage tank, the ethanol and isopropyl alcohol vapor pressures were supplied by the model’s database. The maximum annual throughput for each tank used in the model, was calculated from the forecasted throughput of each material from June 2022 to May 2023. The highest monthly forecast throughput was multiplied by 12 months and a 15% margin was added, to calculate the maximum annual throughput. The model report outputs appear in Appendix F. Page 8 Revision 2 Table 2. Emission Master Model Inputs Parameter Tank 63 Tank 63A Tank 60 Contents Armosoft DEQ Armosoft DEQ 200-Proof Denatured Ethanol Capacity (gal) 34,000 34,000 29,000 Tank Roof Cone Cone Cone Shell Height (ft) 34.5 34.5 26 Shell Diameter (ft) 13 13 14 Temperature (ºF) 160 160 85.7 Max. Annual Throughput (gal/yr) 1,747,840 1,747,840 606,466 Additionally, the VOC emissions from tanks 66 and 52 were analyzed. Tank 66 has a capacity of 29,000 gallons and contains the material PEG 400, which contains 100% polyethylene glycol (PEG). Tank 52 has a capacity of 29,000 gallons and will contain a citric acid solution. VOC emissions were calculated using an EPA formula developed for splash filling a container (not submerged filling). The emissions occur as the saturated air in the headspace is displaced during filling of the mixing tank. Calculations are summarized in Appendix C. NEW SOURCE PERFORMANCE STANDARD NOTIFICATIONS Volatile Organic Liquid Storage Tanks - 40 CFR 60 Subpart Kb Four new storage tanks and two repurposed tanks are included in this NOI. Only two of the six storage tanks apply to this NSPS standard. A summary of the applicability is provided in Table 3. Page 9 Revision 2 Table 3. Applicability of the Volatile Organic Liquid Storage Tank NSPS Storage Tank ID Content Applicability Tank 1 Sulfonic Acid Not applicable - 40 CFR §60.110b(b) states that storage tanks with an organic liquid true vapor pressure < 15.0 KPa or more in a storage tank with a capacity between 20,000 gallons and 39,800 gallons is not applicable to the standard. Tank 2 Sodium Silicate Liquid Alkaline Not applicable – This material does not contain an organic liquid. Tank 63 Armosoft DEQ Applicable - 40 CFR §60.110b(a) states that storage tanks with holding a volatile organic liquid with a capacity that exceeds 20,000 gallons and does not meet the exclusion in 40 CFR §60.110b(b) is subject to the standard. Tank 63A Armosoft DEQ Applicable - 40 CFR §60.110b(a) states that storage tanks with holding a volatile organic liquid with a capacity that exceeds 20,000 gallons and does not meet the exclusion in 40 CFR §60.110b(b) is subject to the standard. Tank 65 70% SLES Not applicable - 40 CFR §60.110b(b) states that storage tanks with an organic liquid true vapor pressure < 15.0 KPa or more in a storage tank with a capacity between 20,000 gallons and 39,800 gallons is not applicable to the standard. Tank 65A 70% SLES Not applicable - 40 CFR §60.110b(b) states that storage tanks with an organic liquid true vapor pressure < 15.0 KPa or more in a storage tank with a capacity between 20,000 gallons and 39,800 gallons is not applicable to the standard. The commencement of construction notification of 40 CFR §60.7(a)(1) does not apply to Storage Tanks 65 and 65A since these storage tanks have already been constructed and Page 10 Revision 2 existing units repurposed for the storage of Armosoft DEQ. However, the notification in 40 CFR §60.7(a)(4) applies because a change in the material used in these two tanks are subjecting the units to 40 CFR 60 Subpart Kb. Such notification shall be postmarked 60 days or as soon as practicable before the change is commenced. This notice contains the following: Nature of the change: Repurposed storage tanks Proposed emission control system: Carbon canister with closed vent Productive capacity of the facility: > 1,747,840 gallons throughput/yr/storage tank Expected completion date for storage of affected material: Unknown Regulatory Analysis Each of the Tanks 63 and 63A will have a capacity of 34,000 gallons. The New Source Performance Standard for Volatile Organic Liquid Storage in 40 CFR 60 Subpart Kb applies to this project because according to 40 CFR §60.110b(b), the true vapor pressure of the VOC in the heated Tanks 63 and 63A is more than the applicability threshold of 15.0 kPa. Table 4 Provides the true vapor pressures interpolated from a laboratory analysis performed on the storage tanks’ content. The vapor pressures are due to the ethanol component in the materials stored in the tanks at the tanks operating temperature. The ethanol composition is provided in the SDS in Appendix D. Table 4. Vapor Pressures of Materials in the Two Storage Tanks Tank ID Material Maximum Storage Temperature (°F) Maximum True Vapor Pressure* (kPa) 63 Armosoft DEQ 160 34.3 63A Armosoft DEQ 160 34.3 *Reduced from Marion Laboratories analysis for vapor pressure performed in accordance with ASTM D2879 in a report generated on February 17, 2022. The analysis appears in Appendix E. Implementing Compliance with 40 CFR 63 SUBPART Kb The NSPS requires the use of an air pollution control device that can achieve a minimum of 95% VOC control efficiency (40 CFR 60.112b(a)(3)(ii)). Henkel will use a carbon canister on each storage tank and will replace them when breakthrough occurs. An operating plan, as per the New Source Performance Standard, 40 CFR §60.113b(c)(1) is prepared and attached in Appendix G for approval. The approved plan will be implemented and maintained onsite by Henkel. Page 11 Revision 2 The volatile component of the materials stored in Tanks 63 and 63A is ethanol, which is a volatile organic liquid. These storage tanks have a fixed roof and have previously been uncontrolled. These tanks were found to be subject to 40 CFR 60 Subpart Kb requirements due to the heating of the tank increasing vapor pressure of the volatile organic liquid The Operating Plan demonstrates that the control device will achieve the required control efficiency during maximum loading conditions. The Plan includes a description of the gas stream, which enters the control device, including flow and VOC content under varying liquid level conditions (dynamic and static) and the manufacturer's design specifications for the control device. The Plan also addresses monitoring for leaks in the closed vent system leading to the air-pollution control device as well as monitoring practices assuring compliance with the 95% control efficiency of the air-pollution control device. Henkel is satisfied that the air-pollution control devices meet the requirements of 40 CFR 60 Subpart Kb. Stationary Spark Ignition Internal Combustion Engines – 40 CFR 60 Subpart JJJJ An existing natural gas fueled 2-cycle lean burn engine is included in this NOI because it is not included in the AO. This is a 16 HP Briggs and Stratton Model 303775 engine. The Model Year 1969. This engine is used to drive an emergency generator. According to 40 CFR §60.4230(a)(4)(iii), this engine does not apply to this NSPS because it was manufactured prior to July 1, 2008. NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS Reciprocating Internal Combustion Engines – 40 CFR 63 Subpart ZZZZ Henkel is adding an existing 1969 Model Year 16 HP natural gas fueled emergency engine not previously included on the AO. The Henkel facility is an area source of emissions. According to 40 CFR §63.6590(a)(1)(iii), this emergency engine is an existing source because it was constructed before June 12, 2006. BEST AVAILABLE CONTROL TECHNOLOGY (BACT) ANALYSIS In accordance with Utah Admin. Code 307-401-8, Henkel is completing a Best Available Control Technology (BACT) Analysis for the new and modified equipment proposed in this project (new pre-mixer, four new storage tanks and two modified storage tanks). Baghouse LQD-5 brought online is an existing unit that replaced an older baghouse. The new storage tanks are storage Tanks 65, 65A, 1, and 2. Tanks 63 and 63A (subject to 40 CFR 63, Subpart Kb), will be modified and therefore evaluated for BACT. In addition, a Page 12 Revision 2 cost feasibility analysis was performed for the new pre-mixing operations at the facility. Four New Storage Tanks with Respect to VOC Emissions There are four new storage tanks proposed in this application. Tanks 65 and 65A will each contain SLES 70%. This material is a solid at room temperature, has a high molar mass, and a high boiling point, which will not result in VOC emissions at the storage tanks elevated operating temperature. Tank 1 will contain Linear Alkylbenzene Sulfonic Acid (LAS). This material has 18 carbons and a high molar mass which is not conducive to an appreciable amount of evaporation, if any. In addition, this molecule has strong intermolecular bonds, an aromatic end and a straight alkene end which tend to form micelles like oil. Tank 2 will contain Sodium Silicate Liquid Alkaline, which does not contain any organic compounds. All four tanks will emit negligible uncontrolled VOC emissions, if any. Therefore, a cost analysis for potential air pollution control devices is not feasible for negligible to no VOC volatility. Two Modified Storage Tanks with Respect to VOC Emissions Tanks 63 and 63A are subject to NSPS because they will contain volatile organic liquids at elevated temperatures. The NSPS rule requires that an air pollution control device with a minimum control efficiency of 95% be installed (40 CFR 60.112b(a)(3)(ii)). Due to the low maximum VOC emission rate of 0.34 ton VOC per year per tank, this air pollution device will qualify for BACT as well. From the pricing quote for the carbon canisters at the Henkel Bowling Green site, provided by Industrial Air Purification, Inc. (IAP), the cost per carbon canister is $13,456.80. The quote is included in Appendix H. Assuming the installed cost doubles the cost of the canister, the total cost per canister is $26,913.60. The controlled VOC emissions from each tank, fitted with a carbon canister with a control efficiency of 95% is 0.017 ton VOC per year. The cost per ton of VOC removed for each carbon canister is $83,045.36. In conclusion, the cost effectiveness and the carbon canisters is too high and can be eliminated as an option for BACT. The majority of the time, the VOC emissions will represent 0.65% of the annual modeled VOC emissions of 0.34 tons per year due to breathing losses. The number of tank fills per year (turnovers) is estimated to be 51.4. This means tanks are filled approximately weekly. Assuming a 3.4-hour period to fill a tank (based on a fill rate of 10,000 gallons per hour), this means that 99.35% of the emissions occur over 174.8 hours of the year. The majority of the VOC emissions occur during storage tank filling. Other options such as carbon adsorption and catalytic oxidation and flaring are more expensive for similar control efficiencies, and will prove to be even less cost effective. Thermal oxidation has control efficiencies that are around 99%. Such air pollution control devices’ costs are significantly higher and are usually not cost effective at emission levels of the magnitude exhausting from the storage tanks. Igniting a thermal oxidizer or flare for 174.8 hours per year will make the cost even less economically feasible. Appendix A: UDAQ NOI Forms Form 1 Notice of Intent (NOI) Application Checklist Company __________________ Utah Division of Air Quality New Source Review Section Source Identification Information [R307-401-5] 1. Company name, mailing address, physical address and telephone number † 2. Company contact (Name, mailing address, and telephone number)† 3. Name and contact of person submitting NOI application (if different than 2)† 4. Source Universal Transverse Mercator (UTM) coordinates † 5. Source Standard Industrial Classification (SIC) code † 6. Area designation (attainment, maintenance, or nonattainment)† 7. Federal/State requirement applicability (NAAQS, NSPS, MACT, SIP, etc.)† 8. Source size determination (Major, Minor, PSD)† 9. Current Approval Order(s) and/or Title V Permit numbers † NOI Application Information:[R307-401] † † † † † † † † † † N/A † †N/A † A. Air quality analysis (air model, met data, background data, source impact analysis) †N/A † Detailed description of the project and source process Discussion of fuels, raw materials, and products consumed/produced Description of equipment used in the process and operating schedule Description of changes to the process, production rates, etc. Site plan of source with building dimensions, stack parameters, etc. Best Available Control Technology (BACT) Analysis [R307-401-8] $BACT analysis for all new and modified equipment Emissions Related Information: [R307-401-2(b)] $Emission calculations for each new/modified unit and site-wide (Include PM10, PM2.5,NOx, SO2, CO, VOCs, HAPs, and GHGs) %References/assumptions, SDS, for each calculation and pollutant &All speciated HAP emissions (list in lbs/hr) Emissions Impact Analysis – Approved Modeling Protocol [R307-410] $Composition and physical characteristics of effluent (emission rates, temperature, volume, pollutant types and concentrations) Nonattainment/Maintenance Areas – Major NSR/Minor (offsetting only) [R307-403] $NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirements %Alternative site analysis, Major source ownership compliance certification Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406] %Visibility impact analysis, Class I area impact  6LJQDWXUHRQ$SSOLFDWLRQ †N/A † Note: The Division of Air Quality will not accept documents containing confidential information or data. Documents containing confidential information will be returned to the Source submitting the application. Henkel Corporation ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ † ✔  Date Oct 2022____________ REVISION 2 TO INITAL NOI Page 1 of 1 Form 4 Company____________________________ Project Information Site ______________________________ Utah Division of Air Quality New Source Review Section Process Data - For Modification/Amendment ONLY 1. Permit Number_______________________________ If submitting a new permit, then use Form 3 Requested Changes 2. Name of process to be modified/added: _______________________________ End product of this process: _______________________________ 3. Permit Change Type: New Increase* Equipment Process Other ______________________________ Other ______________________________ 4. Does new emission unit affect existing permitted process limits? Yes No 6. Description of Permit/Process Change** 7. New or modified materials and quantities used in process. ** Material Quantity Annually 8. New or modified process emitting units ** Emitting Unit(s)Capacity(s)Manufacture Date(s) *If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. **If additional space is required, please generate a document to accommodate and attach to form. Henkel Corporation Salt Lake City AN-104630029-19 Soap Manufacturing Detergents, soaps, and fabric softeners ✔ ✔ Condition Change Section II: Permitted____________________Equipment Other Add/remove filters; Add_____________________________4 new _storage tanks Add 2 new stacks; Remove obsolete sources Realign permit limits; Description corrections ✔ 5.Condition(s) Changing: 1) Correction of Carbon Monoxide (CO) Limit 2) Adding/removing baghouses and scrubbers 3) Adding/ removing natural gas combustion units 4) Addition of pre-mixers and dry materials to process lines 5) Addition of 4 new storage tanks and 2 repurposed tanks 6) Removal or R&D Lab 7) Removal of carton printing 8) Correct description of heat transfer labelers 9) Removal of 33 HP and 255 HP Natural Gas Engines 10) Addition of 16 HP Natural Gas Engine 11) Correction of horsepower on Diesel Engine from 79 HP to 74 HP See Narrative and Appendices See Narrative and Appendicies See Appendix C Add 1 new NG engine; Update boiler/AHUs Page 1 of 1 Company___________________________ Site _____________________________ Form 5 Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants** (**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed SEE CR I T E R I A P O L L U T A N T MMARY O N P R E V I O U S P SU AGE Page 1 of 1 Company___________________________ 6LWH_____________________________ Form  Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants**(**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed Henkel Corporation Salt Lake City Methanol 0.32 0.00 0.32 0.00 Ethylene Glycol 0.00 0.00 0.00 0.00 Methjyl Isobutyl Ketone 0.00 0.00 0.00 0.00 Tricholorehtylene 3.90 -3.90 0.00 -0.89 Tetrachloroethylene 1.32 -1.32 0.00 -0.30 S ee Criteria P o l l u t a n t S u m m a r y o n F i r s t P a g e Docuinonl Ddlo: 02/28/2018 DAQ-2018-00226 ~7\ Page 1 of 2 Utah Division of Air Quality New Source Review Section Company Henkel Corporation Site/Source Salt Lake City Form 10 Date October 2022 Fabric Filters (Baghouses) Baghouse Description 1. Briefly describe the process controlled by this baghouse: BH ID: LQD-5 (Equipment Number LQPRDC005) Gas Stream Characteristics 2. Flow Rate (acfm): 3. Water Vapor Content of Effluent Stream (lb. water/lb. dry air) 0.5% est. 4. Particulate Loading (grain/scf) Design Max 4,300 est. Average Expected Unknown Inlet Unknown Outlet 0.02 5. Pressure Drop (inches H2O) High 6 Low 1 6. Gas Stream Temperature (°F): 70 est. 7. Fan Requirements (hp) (ft3/min) Not Determined Equipment Information and Filter Characteristics 8. Manufacturer and Model Number: MIKRO-PULSAIRE 64S-10-20 C 9. Bag Material: □ Nomex nylon □ Polyester □ Acrylics □ Fiber glass □ Cotton □ Teflon X N/A 0.02 gr/dscf 10. Bag Diameter (in.) 4.5 11. Bag Length (ft.) 10 12. Number of Bags: 64 13. Stack Height 69 feet Stack Inside Diameter 9 x 11 inches 14. Filtering Efficiency Rating: Unknown % 15. Air to Cloth Ratio: 6 est : 1 16. Hours of Operation: Max Per day 24 Max Per year 8760 17. Cleaning Mechanism: □ Reverse Air □ Shaker X Pulse Jet □ Other: Emissions Calculations (PTE) 18. Calculated emissions for this device PM10 0.74 Lbs/hr 3.23 Tons/yr PM2.5 0.74 Lbs/hr 3.23 Tons/yr NOx NA Lbs/hr NA Tons/yr SOx NA Lbs/hr NA Tons/yr CO NA Lbs/hr NA Tons/yr VOC NA Lbs/hr NA Tons/yr HAPs NA Lbs/hr (speciate) NA Tons/yr (speciate) Submit calculations as an appendix. Page 2 of 2 Instructions - Form 10 Fabric Filters (Baghouses) NOTE: 1. Submit this form in conjunction with Form 1 and Form 2. 2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this form. Ask to speak with a New Source Review engineer. We will be glad to help! 1. Describe the process equipment that the filter controls, what product is being controlled, particle size data (if available), i.e., cement silo, grain silo, nuisance dust in work place, process control with high dust potential, etc. 2. The maximum and design exhaust gas flow rates through the filter control device in actual cubic feet per minute (ACFM). Check literature or call the sales agent. 3. The water/moisture content of the gas stream going through the filter. 4. The amount of particulate in the gas stream going into the filter and the amount coming out if available. Outlet default value = 0.016 grains PM10/dscf. 5. The pressure drop range across the system. Usually given in the literature in inches of water. 6. The temperature of the gas stream entering the filter system in degrees Fahrenheit. 7. The horse power of the fan used to move the gas stream and/or the flow rate of the fan in ft3/min. 8. Name of the manufacturer of the filter equipment and the model number if available. 9. Check the type of filter bag material or fill in the blank. Check literature or call the sales agent. 10. The diameter of the bags in the system. Check literature or call the sales agent. 11. The length of the bags in the system. Check literature or call the sales agent. 12. The number of bags. Check literature or call the sales agent. 13. The height to the top of the stack from ground level and the stack inside diameter. 14. The filtering efficiency rating that the manufacturer quotes. Check literature or call the sales agent. 15. The ratio of the flow rate of air to the cloth area (A/C). 16. The number of hours that the process equipment is in operation, maximum per day and per year. 17. The way in which the filters bags are cleaned. Check the appropriate box. 18. Supply calculations for all criteria pollutants and HAPs. Use AP42 or Manufacturers data to complete your calculations. U:\aq\ENGINEER\GENERIC\Forms 2010\Form10 Baghouses.doc Revised 12/20/10 Page 1 of 2 Utah Division of Air Quality New Source Review Section Company Henkel Corporation Site/Source Salt Lake City Form 10 Date October 2022 Fabric Filters (Baghouses) Baghouse Description 1. Briefly describe the process controlled by this baghouse: BH ID: LSL-1 (Equipment Number PWDDC001) Gas Stream Characteristics 2. Flow Rate (acfm): 3. Water Vapor Content of Effluent Stream (lb. water/lb. dry air) 0.5% est. 4. Particulate Loading (grain/scf) Design Max 11,289 est. Average Expected Unknown Inlet Unknown Outlet 0.02 5. Pressure Drop (inches H2O) High 6 Low 1 6. Gas Stream Temperature (°F): 70 est. 7. Fan Requirements (hp) (ft3/min) Not Determined Equipment Information and Filter Characteristics 8. Manufacturer and Model Number: MIKRO-PULSAIRE M168S1020C 9. Bag Material: □ Nomex nylon □ Polyester □ Acrylics □ Fiber glass □ Cotton □ Teflon X N/A 0.02 gr/dscf 10. Bag Diameter (in.) 4.5 11. Bag Length (ft.) 10 12. Number of Bags: 168 13. Stack Height 56 feet Stack Inside Diameter 24 inches 14. Filtering Efficiency Rating: Unknown % 15. Air to Cloth Ratio: 6 est : 1 16. Hours of Operation: Max Per day 24 Max Per year 8760 17. Cleaning Mechanism: □ Reverse Air □ Shaker X Pulse Jet □ Other: Emissions Calculations (PTE) 18. Calculated emissions for this device PM10 1.94 Lbs/hr 8.48 Tons/yr PM2.5 1.94 Lbs/hr 8.48 Tons/yr NOx NA Lbs/hr NA Tons/yr SOx NA Lbs/hr NA Tons/yr CO NA Lbs/hr NA Tons/yr VOC NA Lbs/hr NA Tons/yr HAPs NA Lbs/hr (speciate) NA Tons/yr (speciate) Submit calculations as an appendix. Page 2 of 2 Instructions - Form 10 Fabric Filters (Baghouses) NOTE: 1. Submit this form in conjunction with Form 1 and Form 2. 2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this form. Ask to speak with a New Source Review engineer. We will be glad to help! 1. Describe the process equipment that the filter controls, what product is being controlled, particle size data (if available), i.e., cement silo, grain silo, nuisance dust in work place, process control with high dust potential, etc. 2. The maximum and design exhaust gas flow rates through the filter control device in actual cubic feet per minute (ACFM). Check literature or call the sales agent. 3. The water/moisture content of the gas stream going through the filter. 4. The amount of particulate in the gas stream going into the filter and the amount coming out if available. Outlet default value = 0.016 grains PM10/dscf. 5. The pressure drop range across the system. Usually given in the literature in inches of water. 6. The temperature of the gas stream entering the filter system in degrees Fahrenheit. 7. The horse power of the fan used to move the gas stream and/or the flow rate of the fan in ft3/min. 8. Name of the manufacturer of the filter equipment and the model number if available. 9. Check the type of filter bag material or fill in the blank. Check literature or call the sales agent. 10. The diameter of the bags in the system. Check literature or call the sales agent. 11. The length of the bags in the system. Check literature or call the sales agent. 12. The number of bags. Check literature or call the sales agent. 13. The height to the top of the stack from ground level and the stack inside diameter. 14. The filtering efficiency rating that the manufacturer quotes. Check literature or call the sales agent. 15. The ratio of the flow rate of air to the cloth area (A/C). 16. The number of hours that the process equipment is in operation, maximum per day and per year. 17. The way in which the filters bags are cleaned. Check the appropriate box. 18. Supply calculations for all criteria pollutants and HAPs. Use AP42 or Manufacturers data to complete your calculations. U:\aq\ENGINEER\GENERIC\Forms 2010\Form10 Baghouses.doc Revised 12/20/10 Appendix B: Site Map Henkel Corporation Outdoor Storage Tanks Salt Lake City, UT TANK 60 Ethanol TANK 52 Citric Acid TANK 66 PEG 400 TANK 23 L24-9 29,000 gal Capacity Storage Tanks TANK 49 Stepanol TANK 65A SLES 70% TANK 63 Armosoft DEQ TANK 22 COCO Fatty Acid TANK 27 7EO Non- Ionic TANK 1 Sulfonic Acid TANK 2 Sodium Silicate TANK 63A Armosoft DEQ TANK 65 SLES 70% Storage Tank 2 Capacity is 32,700 gal; the rest are 34,000 gal TANK 21 Natural 7EO Non- ionic TANK 45 Steol CS- 270 21,000 gal Capacity Storage Tanks Appendix C: Potential to Emit Calculations Appendix C Emissions Summary lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Criteria Pollutants Point Source ------91 0.05 Fugitive or Vertically Restricted Exhaust --5.8 0.003 2,411 1.21 -- Total --5.8 0.003 2,411 1.21 91 0.05 Point Source ------91 0.05 Fugitive or Vertically Restricted Exhaust --5.8 0.003 2,411 1.21 -- Total --5.8 0.003 2,411 1.21 91 0.05 Point Source -------- Fugitive or Vertically Restricted Exhaust --371 0.19 31,730 15.86 -- Total --371 0.19 31,730 15.86 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --76 0.04 190 0.10 -- Total --76 0.04 190 0.10 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --292 0.15 26,653 13.33 -- Total --292 0.15 26,653 13.33 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --107 0.05 1,745 0.87 -- Total --107 0.05 1,745 0.87 -- Greenhouse Gases CO2 mass --44656 22 38,088,223 19,044 -- GWP-1 CO2e --44656 22 38,088,223 19,044 -- Methane mass --1.76 0.001 718 0.4 -- GWP=25 CO2e --44 0.02 17,946 10.0 -- N2O mass --0.35 0.0002 72 0.04 -- GWP=298 CO2e --103 0.05 21,391 11.92 -- VOC PM10 PM2.5 NOx SO2 CO Printing - Labels Natural Gas Cooling TowersEmergency Engines Appendix C Emissions Summary lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Printing - Labels Natural Gas Cooling TowersEmergency Engines Hazardous Air Pollutants Point Source -------- Fugitive or Vertically Restricted Exhaust --10.61 0.00531 598.80 0.29940 -- Total --10.61 0.00531 598.80 0.29940 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --6.74 0.00337 23.80 0.012 -- Total --6.74 0.00337 23.80 0.012 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.93 0.00047 ---- Total --0.93 0.00047 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --1.10 0.00055 ---- Total --1.10 0.00055 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.058 0.00003 0.16 0.00008 -- Total --0.058 0.00003 0.16 0.00008 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.47 0.00023 0.67 0.00033 -- Total --0.468 0.00023 0.67 0.00033 -- Acrolein Acetaldehyde Propionaldehyde Dimethyl Formamide All HAP Formaldehyde Glycol Ether Lead Benzene Appendix C Emissions Summary lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Printing - Labels Natural Gas Cooling TowersEmergency Engines Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.38 0.00019 -- Total ----0.38 0.00019 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.05 0.00003 571 0.28557 -- Total --0.05 0.00003 571 0.28557 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.22 0.00011 1.08 0.00054 -- Total --0.22 0.00011 1.08 0.00054 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.03 0.00002 0.19 0.00010 -- Total --0.03 0.00002 0.19 0.00010 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.05 0.00002 0.03 0.00001 -- Total --0.05 0.00002 0.03 0.00001 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.06 0.00003 -- Total ----0.06 0.00003 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.00 0.000002 -- Total ----0.00 0.000002 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.35 0.00017 -- Total ----0.35 0.00017 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.04 0.00002 -- Total ----0.04 0.00002 -- Hexane Toluene Dichlorobenzene Polycyclic Organics Arsenic Cadmium Chromium Beryllium Naphthalene Appendix C Emissions Summary lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Printing - Labels Natural Gas Cooling TowersEmergency Engines Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.03 0.00001 -- Total ----0.03 0.00001 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.12 0.00006 -- Total ----0.12 0.00006 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.08 0.00004 -- Total ----0.08 0.00004 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.67 0.00033 -- Total ----0.67 0.00033 -- Point Source -------- Fugitive or Vertically Restricted Exhaust ----0.008 0.000004 -- Total ----0.008 0.000004 -- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.11 0.00005 ---- Total --0.11 0.00005 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.11 0.00005 ---- Total --0.11 0.00005 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0077 0.00000 ---- Total --0.0077 0.00000 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0061 0.00000 ---- Total --0.0061 0.00000 ---- Mercury Nickel Selenium Cobalt Manganese Xylene 1,3-Butadiene 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane Appendix C Emissions Summary lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Printing - Labels Natural Gas Cooling TowersEmergency Engines Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0051 0.00000 ---- Total --0.0051 0.00000 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0986 0.00005 ---- Total --0.0986 0.00005 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0071 0.000004 ---- Total --0.0071 0.000004 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0052 0.000003 ---- Total --0.0052 0.000003 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0055 0.000003 ---- Total --0.0055 0.000003 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0126 0.00001 ---- Total --0.0126 0.00001 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0086 0.000004 ---- Total --0.0086 0.000004 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.29 0.00014 ---- Total --0.29 0.00014 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0112 0.00001 ---- Total --0.0112 0.00001 ---- 1,3-Dichloropropene 2,2,4-Trimethylpentane Carbon Tetrachloride Chlorobenzene Chloroform Ethylbenzene Ethylene Dibromide Methylene Chloride Phenol Appendix C Emissions Summary lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Printing - Labels Natural Gas Cooling TowersEmergency Engines Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0064 0.000003 ---- Total --0.0064 0.000003 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.0029 0.000001 ---- Total --0.0029 0.000001 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust --0.29 0.00014 ---- Total --0.29 0.00014 ---- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Point Source -------- Fugitive or Vertically Restricted Exhaust -------- Total -------- Other Pollutants Point Source -------- Fugitive or Vertically Restricted Exhaust ----1708 0.85 -- Total ----1,708 0.85 -- * Previously reported and is unchanged from Approval Order AN104630023-17. Ammonia Methanol Ethylene Glycol Methyl Isobutyl Ketone Trichloro Ethylene Tetrachloro Ethylene Styrene Vinyl Chloride Appendix C Emissions Summary Criteria Pollutants Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Greenhouse Gases CO2 mass GWP-1 CO2e Methane mass GWP=25 CO2e N2O mass GWP=298 CO2e VOC PM10 PM2.5 NOx SO2 CO lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr ------53,469 26.73 7.83 0.004 --288.58 0.14 1,954 0.98 ---- --288.58 0.14 1,954 0.98 53,469 26.73 7.83 0.004 ------53,469 26.73 -- --43.70 0.02 1,954 0.98 ---- --43.70 0.02 1,954 0.98 53,469 26.73 -- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- --------188 0.09 1,980 0.99 9,049 4.52 4,104 2.05 ---- 1,980 0.99 9,049 4.52 4,104 2.05 --188 0.09 ---------- ---------- ---------- ---------- ---------- ---------- Blow Molding *Organic Liquid Storage Liquid Products Paint BoothDust Control Equipment Appendix C Emissions Summary Hazardous Air Pollutants Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Acrolein Acetaldehyde Propionaldehyde Dimethyl Formamide All HAP Formaldehyde Glycol Ether Lead Benzene lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Blow Molding *Organic Liquid Storage Liquid Products Paint BoothDust Control Equipment --------23 0.011 --1.22 0.00061 8.64 0.00430 ---- --1.22 0.00061 8.64 0.00430 --23 0.011 ---------- ----5.18 0.0026 ---- ----5.18 0.0026 ---- ---------- ---------- ---------- ---------- ----3.46 0.0017 ---- ----3.46 0.0017 ---- ---------- ---------- ---------- ---------- --1.2203 0.0006 ------ --1.2203 0.0006 ------ ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Hexane Toluene Dichlorobenzene Polycyclic Organics Arsenic Cadmium Chromium Beryllium Naphthalene lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Blow Molding *Organic Liquid Storage Liquid Products Paint BoothDust Control Equipment ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Mercury Nickel Selenium Cobalt Manganese Xylene 1,3-Butadiene 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Blow Molding *Organic Liquid Storage Liquid Products Paint BoothDust Control Equipment ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- --------9.79 0.0049 ---------- --------9.79 0.0049 ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total 1,3-Dichloropropene 2,2,4-Trimethylpentane Carbon Tetrachloride Chlorobenzene Chloroform Ethylbenzene Ethylene Dibromide Methylene Chloride Phenol lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Blow Molding *Organic Liquid Storage Liquid Products Paint BoothDust Control Equipment ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- --------3.26 0.0016 ---------- --------3.26 0.0016 ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Other Pollutants Point Source Fugitive or Vertically Restricted Exhaust Total * Previously reported and is unchanged from Approval Order AN10 Ammonia Methanol Ethylene Glycol Methyl Isobutyl Ketone Trichloro Ethylene Tetrachloro Ethylene Styrene Vinyl Chloride lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr Blow Molding *Organic Liquid Storage Liquid Products Paint BoothDust Control Equipment ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- --------9.79 0.0049 ---------- --------9.79 0.0049 ---------- ---------- ---------- ---------- ---------- ---------- -------- -------- -------- Appendix C Emissions Summary Criteria Pollutants Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Greenhouse Gases CO2 mass GWP-1 CO2e Methane mass GWP=25 CO2e N2O mass GWP=298 CO2e VOC PM10 PM2.5 NOx SO2 CO lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr ----53,568 26.78 6.99E-02 3.49E-05 --4,660 2.33 6.99E-02 3.49E-05 --58,228 29.12 ----53,560 26.78 0 0 --4,415 2.21 6.99E-02 3.49E-05 --57,975 28.99 ----0 0.00 ----32,101 16.05 ----32,101 16.05 ----0 0.00 ----266 0.13 ----266 0.13 ----0 0.00 ----26,945 13.47 ----26,945 13.47 ----188 0.09 --2,656 1.33 19,642 9.82 --2,656 1.33 19,830 9.91 ----38,132,879 19,066 ----38,132,879 19,066 ----720 0.40 ----17,990 10 ----72 0.04 ----21,495 12 TotalRailcar Unloading Miscellaneous Appendix C Emissions Summary Hazardous Air Pollutants Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Acrolein Acetaldehyde Propionaldehyde Dimethyl Formamide All HAP Formaldehyde Glycol Ether Lead Benzene lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr TotalRailcar Unloading Miscellaneous ----22.84 0.0114 --819.68 0.40984 1438.96 0.72 --819.68 0.40984 1,461.80 0.731 ------ ----35.71 0.02 ----35.71 0.018 ------ ----0.93 0.0005 ----0.93 0.0005 ------ ----4.56 0.002 ----4.56 0.002 ------ ------ ----0.00 0.00 ------ ----1.22 0.0006 ----1.22 0.0006 ------ --186.08 0.093 186.08 0.093 --186.08 0.093 186.08 0.093 ------ ----0.22 0.0001 ----0.22 0.0001 ------ ----1.13 0.0006 ----1.13 0.0006 Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Hexane Toluene Dichlorobenzene Polycyclic Organics Arsenic Cadmium Chromium Beryllium Naphthalene lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr TotalRailcar Unloading Miscellaneous ------ ----0.38 0.0002 ----0.38 0.0002 ------ ----571.19 0.29 ----571.19 0.286 ------ ----1.30 0.0006 ----1.30 0.0006 ------ ----0.23 0.0001 ----0.23 0.0001 ------ ----0.08 0.00004 ----0.08 0.00004 ------ ----0.06 0.00003 ----0.06 0.00003 ------ ----0.004 0.000002 ----0.004 0.000002 ------ ----0.35 0.0002 ----0.35 0.0002 ------ ----0.04 0.00002 ----0.04 0.00002 Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Mercury Nickel Selenium Cobalt Manganese Xylene 1,3-Butadiene 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr TotalRailcar Unloading Miscellaneous ------ ----0.03 0.00001 ----0.03 0.00001 ------ ----0.12 0.0001 ----0.12 0.0001 ------ ----0.08 0.00004 ----0.08 0.00004 ------ ----0.67 0.0003 ----0.67 0.0003 ------ ----0.008 0.000004 ----0.008 0.000004 ----9.79 0.0049 ----0.11 0.00 ----9.89 0.005 ------ ----0.11 0.0001 ----0.11 0.0001 ------ ----0.008 0.000004 ----0.008 0.000004 ------ ----0.006 0.000003 ----0.006 0.000003 Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total 1,3-Dichloropropene 2,2,4-Trimethylpentane Carbon Tetrachloride Chlorobenzene Chloroform Ethylbenzene Ethylene Dibromide Methylene Chloride Phenol lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr TotalRailcar Unloading Miscellaneous ------ ----0.005 0.000003 ----0.005 0.000003 ------ ----0.10 0.00005 ----0.10 0.00005 ------ ----0.007 0.000004 ----0.007 0.000004 ------ ----0.005 0.000003 ----0.005 0.000003 ------ ----0.005 0.000003 ----0.005 0.000003 ----3.26 0.0016 ----0.01 0.00 ----3.28 0.0016 ------ ----0.009 0.000004 ----0.009 0.000004 ------ ----0.29 0.0001 ----0.29 0.0001 ------ ----0.011 0.00001 ----0.011 0.00001 Appendix C Emissions Summary Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Point Source Fugitive or Vertically Restricted Exhaust Total Other Pollutants Point Source Fugitive or Vertically Restricted Exhaust Total * Previously reported and is unchanged from Approval Order AN10 Ammonia Methanol Ethylene Glycol Methyl Isobutyl Ketone Trichloro Ethylene Tetrachloro Ethylene Styrene Vinyl Chloride lbs/yr tons/yr lbs/yr tons/yr lbs/yr tons/yr TotalRailcar Unloading Miscellaneous ------ ----0.006 0.000003 ----0.006 0.000003 ------ ----0.0029 0.000001 ----0.0029 0.000001 ------ --633.60 0.3168 633.9 0.317 --633.60 0.3168 633.9 0.317 ------ ------ ----0.00 0.00 ----9.79 0.0049 ------ ----9.79 0.0049 ---- ------ ----0.00 0.00 ------ ------ -----0.00 ---- --1707.8 0.85 --1707.8 0.85 Appendix C - (2) Emergency Engines 74 HP Diesel & 16 HP Natural Gas Emergency Engine Fuel Type:Diesel Manufactured Date:10/18/2004 Manufacturer:John Deere Model number:3029HI530 Tier/Phase [1]:Final Stage 4/ Stage V Engine Rated Power [1]: 74 HP 55 kW 7,000 Btu/hp-hr Hours of Operation:500 hr/yr Potential to Emit Pollutant Reference Emissions (lb/yr) Emissions (tons/yr) Emissions (lb/hr) NMHC + NOX 3.10E-02 g/kWh Manufacturer [1]1.9 0.001 3.76E-03 CO 6.68E-03 lb/hp-hr AP-42, Table 3.3-1 247.2 0.12 0.49 SOX 2.05E-03 lb/hp-hr AP-42, Table 3.3-1 75.9 0.04 0.15 PM 2.20E-03 g/kWh Manufacturer [1]0.1 0.0001 2.67E-04 CO2 1.15E+00 lb/hp-hr AP-42, Table 3.3-1 42,550.0 21.28 85.10 VOC 2.51E-03 lb/hp-hr AP-42, Table 3.3-1 93.0 0.05 0.19 Average Brake-Specific fuel Consumption [2]: Emission Factor Appendix C - (2) Emergency Engines 74 HP Diesel & 16 HP Natural Gas Emergency Engine Pollutant Emission Factor (lb/MMBtu)Reference Emissions (lb/yr) Emissions (tons/yr) Emissions (lb/hr) Benzene 9.33E-04 AP-42, Table 3.3-2 0.24 1.21E-04 4.83E-04 Toluene 4.09E-04 AP-42, Table 3.3-2 0.11 5.30E-05 2.12E-04 Xylene 2.85E-04 AP-42, Table 3.3-2 0.07 3.69E-05 1.48E-04 1,3-Butadiene 3.91E-05 AP-42, Table 3.3-2 0.01 5.06E-06 2.03E-05 Formaldehyde 1.18E-03 AP-42, Table 3.3-2 0.31 1.53E-04 6.11E-04 Acetaldehyde 7.67E-04 AP-42, Table 3.3-2 0.20 9.93E-05 3.97E-04 Acrolein 9.25E-05 AP-42, Table 3.3-2 0.02 1.20E-05 4.79E-05 Naphthalene 8.48E-05 AP-42, Table 3.3-2 0.02 1.10E-05 4.39E-05 POM-HAP [3]1.68E-04 AP-42, Table 3.3-2 0.04 2.18E-05 8.70E-05 1.03 5.13E-04 2.05E-03 Greenhouse Gases Potential to Emit Gas Emission Factor (EF) (kg/MMBtu) Global Warming Potential (GWP)Reference Emissions (lb/yr)Emissions (ton/yr)Greenhouse Gas (ton CO2e/yr) CO2 73.96 1 EF: Table C-1 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 42,238 21 21 CH4 3.00E-03 25 EF: Table C-2 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 2 8.57E-04 0.02 N2O 6.00E-04 298 EF: Table C-2 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 0.34 1.71E-04 0.05 21.19 Notes: GHG (ton CO2e/yr) [1]: Information from manufacturer at: https://www.deere.com/en/industrial-engines/final-tier-4-stage-v/3029hi530/ [2]: Factor from AP-42, Chapter 3.3, Gasoline and Industrial Engines Total HAP [3] Emission factor for polycyclic organic matter (POM) is calculated by summing emission factors for individual constituents listed in AP-42, Table 3.3-2. Appendix C - (2) Emergency Engines 74 HP Diesel & 16 HP Natural Gas Emergency Engine Fuel Type:Natural Gas (converted from gasoline by use of a kit supplied by the manufacturer) Manufactured Date:1969 Manufacturer:Briggs and Stratton Model number:303775 Stroke: 2-Stroke Lean Burn Rated Power: 16 HP Rated Heat Output Capacity:0.04072 MMBtu/hr (output) Engine Thermal Efficiency [1]:17.5%(Assumed) Estimated Heat Input Capacity:0.233 MMBtu/hr (input) 1,020 Btu/scf Maximum Gas Usage 0.114 (No Suggestions)/yr Hours of Operation:500 hr/yr Potential to Emit Pollutant Reference Emissions (lb/yr) Emissions (tons/yr) Emissions (lb/hr) NOX 3.17E+00 lb/MMBtu AP-42, Table 3.2-1 369.3 1.85E-01 7.39E-01 CO 3.86E-01 lb/MMBtu AP-42, Table 3.2-1 45.0 2.25E-02 8.99E-02 Lead 5.00E-04 lb/MMBtu AP-42, Table 3.2-1 0.1 2.91E-05 1.17E-04 PM10 (Fil + Cond)4.83E-02 lb/MMBtu AP-42, Table 3.2-1 5.6 2.81E-03 1.13E-02 PM2.5 (Fil + Cond)4.83E-02 lb/MMBtu AP-42, Table 3.2-1 5.6 2.81E-03 1.13E-02 SO2 5.88E-04 lb/MMBtu AP-42, Table 3.2-1 0.1 3.43E-05 1.37E-04 VOC 1.20E-01 lb/MMBtu AP-42, Table 3.2-1 14.0 6.99E-03 2.80E-02 Natural Gas Heating Value [2]: Emission Factor Appendix C - (2) Emergency Engines 74 HP Diesel & 16 HP Natural Gas Emergency Engine Pollutant Emission Factor (lb/MMBtu)Reference Emissions (lb/yr) Emissions (tons/yr) Emissions (lb/hr) 1,1,2,2-Tetrachloroethane 6.63E-05 AP-42, Table 3.2-1 0.01 3.86E-06 1.54E-05 1,1,2-Trichloroethane 5.27E-05 AP-42, Table 3.2-1 0.01 3.07E-06 1.23E-05 1,3-Butadiene 8.20E-04 AP-42, Table 3.2-1 0.10 4.78E-05 1.91E-04 1,3-Dichloropropene 4.38E-05 AP-42, Table 3.2-1 0.01 2.55E-06 1.02E-05 2,2,4-Trimethylpentane 8.46E-04 AP-42, Table 3.2-1 0.10 4.93E-05 1.97E-04 Acetaldehyde 7.76E-03 AP-42, Table 3.2-1 0.90 4.52E-04 1.81E-03 Acrolein 7.78E-03 AP-42, Table 3.2-1 0.91 4.53E-04 1.81E-03 Benzene 1.94E-03 AP-42, Table 3.2-1 0.23 1.13E-04 4.52E-04 Carbon Tetrachloride 6.07E-05 AP-42, Table 3.2-1 0.01 3.54E-06 1.41E-05 Chlorobenzene 4.44E-05 AP-42, Table 3.2-1 0.01 2.59E-06 1.03E-05 Chloroform 4.71E-05 AP-42, Table 3.2-1 0.01 2.74E-06 1.10E-05 Ethylbenzene 1.08E-04 AP-42, Table 3.2-1 0.01 6.29E-06 2.52E-05 Ethylene Dibromide 7.34E-05 AP-42, Table 3.2-1 0.01 4.28E-06 1.71E-05 Formaldehyde 5.52E-02 AP-42, Table 3.2-1 6.43 3.22E-03 1.29E-02 Methanol 2.48E-03 AP-42, Table 3.2-1 0.29 1.44E-04 5.78E-04 Methylene Chloride 2.48E-03 AP-42, Table 3.2-1 0.29 1.44E-04 5.78E-04 n-Hexane 4.45E-04 AP-42, Table 3.2-1 0.05 2.59E-05 1.04E-04 Naphthalene 9.63E-05 AP-42, Table 3.2-1 0.01 5.61E-06 2.24E-05 Phenol 9.63E-05 AP-42, Table 3.2-1 0.01 5.61E-06 2.24E-05 Styrene 5.48E-05 AP-42, Table 3.2-1 0.01 3.19E-06 1.28E-05 Toluene 9.63E-04 AP-42, Table 3.2-1 0.11 5.61E-05 2.24E-04 Vinyl Chloride 2.47E-05 AP-42, Table 3.2-1 0.00 1.44E-06 5.76E-06 Xylene 2.68E-04 AP-42, Table 3.2-1 0.03 1.56E-05 6.24E-05 POM-HAP [3]3.04E-05 AP-42, Table 3.2-1 0.00 1.77E-06 7.07E-06 9.53 4.76E-03 1.91E-02Total HAP Appendix C - (2) Emergency Engines 74 HP Diesel & 16 HP Natural Gas Emergency Engine Greenhouse Gases Potential to Emit Gas Emission Factor (EF) (kg/MMBtu) Global Warming Potential (GWP)Reference Emissions (lb/yr)Emissions (ton/yr)Greenhouse Gas (ton CO2e/yr) CO2 53.86 1 EF: Table C-1 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 2,418 1 1 CH4 1.00E-03 25 EF: Table C-2 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 0 0 0 N2O 1.00E-04 298 EF: Table C-2 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 0 0 0 1 Notes: [1]: Present day natural gas engine efficiency is 35%. This engine efficiency was adjusted for lesser technology resulting in lower efficiencies by 50%. [2]: Factor from AP-42, Chapter 3.2, Natural Gas-fired Reciprocating Engines GHG (ton CO2e/yr) [3] Emission factor for polycyclic organic matter (POM) is calculated by summing emission factors for individual constituents listed in AP-42, Table 3.2-1 Appendix C - Particulate Control Equipment Dust Collectors, Bin Vents and Wet Scrubbers Updated Fabric Filter PM PTE [1] Old - Approved Equipment Process Name Old - Equipment Number Updated - Process Name Make / Model / Serial Number or Part Number Updated - Equipment Number Order Group Grain Loading (gr/dscf) Exhaust Flow Rate (dscfm) Particulate Matter (lb/hr) Particulate Matter (ton/yr) LSL-3 Bin Vent (SA 100)LSL1DUSTCOLLECTOR3 BH - Soda Ash 100 Silo (Tank 3)Unknown PWDDC003 (LSL-3)2 0.02 726 0.12 0.55 LSL-4 Bin Vent (Salt)LSL1DUSTCOLLECTOR4 BH - Salt Bin 1 Unknown PWDDC004 (LSL-4)2 0.007 1500 0.09 0.39 LSL-6 Process Baghouse LSL1DUSTCOLLECTOR6 BH - LS Line 10 Unknown PWDDC006 (LSL-6)2 0.02 2500 0.43 1.88 Soda BV-1 Bin Vent OXYDUSTCOLLECTOR1 BH - Soda Ash for Tank 29 Unknown RMC029 2 0.02 1413 0.24 1.06 LSL-9 Bin Vent (Salt)LSL1DUSTCOLLECTOR8 BH - Salt Bin 2 Unknown PWDDC008 (LSL-9)2 0.02 1000 0.17 0.75 LSL-8 Process GV Unit LSL1DUSTCOLLECTOR7 BH - General Vent for Agglomerator 3 Area Unknown PWDDC007 (LSL-8)3 0.005 9074 0.39 1.70 MESBH-1 MES Transfer Station Baghouse HSL1DUSTCOLLECTOR16 BH - MES Unloading Station Unknown PWDDC016 (MESBH- 1)4 0.016 3500 0.48 2.10 Appendix C - Particulate Control Equipment Dust Collectors, Bin Vents and Wet Scrubbers Updated Fabric Filter PM PTE [1] Old - Approved Equipment Process Name Old - Equipment Number Updated - Process Name Make / Model / Serial Number or Part Number Updated - Equipment Number Order Group Grain Loading (gr/dscf) Exhaust Flow Rate (dscfm) Particulate Matter (lb/hr) Particulate Matter (ton/yr) MESBV-2 MES Low Suds Bin Vent HSL1DUSTCOLLECTOR11 BH - Agglomerator 3 MES Bin MICRO-PULSAIR / 23-10-220 / Unknown PWDDC011 (MESBV- 1)4 0.016 1800 0.25 1.08 LQD-5 LQD1DUSTCOLLECTOR3 BH - Mixer 7 Soda Ash MIKRO-PULSAIRE / 64S-10-20 C / 205033 H1 LQPRDC005 N/A 0.02 4300 0.74 3.23 N/A N/A BH - General Vent for Agglomerator 3 Area MIKRO-PULSAIRE / M168S1020C / 880207H2 PWDDC001 (LSL-1)N/A 0.02 11289 1.94 8.48 N/A N/A BH - Sokalan MIKRO-PULSAIRE / M16S1020 / 980176H1GA PWDDC010 N/A [1][1][1][1] LSS-3/1 Low Suds Scrubber LSL3WETSCRUBBER BH - Agglomerator 3 Unknown PWD3LSLWETSCRU BBER (LSS-3/1)Scrubber 0.02 6824 1.17 5.12 N/A N/A BH - Single Dose Area Unknown SDLDC001 N/A [1][1][1][1] N/A N/A BH - Single Dose Area Unknown SDLDC003 N/A [1][1][1][1] N/A N/A Sock Fabric Filter - Plastic Regrind Indoors National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A [1][1][1][1] N/A N/A Sock Fabric Filter - Plastic Regrind Indoors National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A [1][1][1][1] N/A N/A Sock Fabric Filter - Plastic Regrind Line 5, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Line 5, No. 2 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Line 3, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Line 3, No. 2 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Line 3, No. 3 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Line 4, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Line 4, No. 2 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 Appendix C - Particulate Control Equipment Dust Collectors, Bin Vents and Wet Scrubbers Updated Fabric Filter PM PTE [1] Old - Approved Equipment Process Name Old - Equipment Number Updated - Process Name Make / Model / Serial Number or Part Number Updated - Equipment Number Order Group Grain Loading (gr/dscf) Exhaust Flow Rate (dscfm) Particulate Matter (lb/hr) Particulate Matter (ton/yr) N/A N/A Sock Fabric Filter - Plastic Regrind Line 4, No. 3 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Lines 15 & 17, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind PCR #1, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind PCR #2, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Lines 14 & 12, No. 1 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 N/A N/A Sock Fabric Filter - Plastic Regrind Lines 14 & 12, No. 2 National Filter Media Corporation / Part Number 0502820-196-227-030 N/A N/A 0.02 40 0.01 0.03 Total 6 26.73 Notes [1]: Baghouses highlighted in green are baghouses that are not currently in the Approval Order DAQE-AN104630027-19 dated April 11, 2019 and are being revised from the initial NOI submitted in July of 2022. [2]: Baghouses are vented indoors, and are not considered emission points. Information provided for informational purposes only. Removed Baghouses [1] Old - Approved Equipment Process Name Old - Equipment Number pdated - Process Nam Updated - Equipment Number Order Group Comment Grain Loading (gr/dscf) Exhaust Flow Rate (dscfm) LSL-7 Pkg GV Unit LSL4DUSTCOLLECTOR9 General Vent for Packaging Lines PWDDC009 3 Process Removed, baghouse not in service 0.01 9074 LQD-4 LQD3DUSTCOLLECTOR6 N/A N/A N/A Process Removed, baghouse not in service 0.01 3468 LQD 7 Dust Collector LQD1DUSTCOLLECTOR7 Soda Ash Transfer Mixer # 7 LQPRDC007 (LQD-7)2 Process Removed, baghouse not in service 0.02 450 LQD-6 LQD3DUSTCOLLECTOR8 Soda Ash Mixer #7 LQPRDC008 (LQD-6)N/A Process Removed, baghouse not in service 0.02 80 SAS-1 Soda Ash Scrubber LQPRWET074 Soda Ash Tank 10 LQDPRWET074 Scrubbers Does not run 0.01 3420 Notes [1]: Information provided is for informational purposes only. Appendix C- Boilers and Heaters Firing Natural Gas Permitted Emission Unit Rated Heat Input Capacity (MMBtu/hr)Boiler or Heater Description Comments 0.48 LSL-1 Permitted in current AO. 2.5 LSL-3 Permitted in current AO. 4.5 LSL-4 Permitted in current AO. 8.37 Sellers 200 HP Steam Boiler (LQD3STEAMBOILER1)Permitted in current AO. 2.51 Sellers 77 COMMODORE 60 HP Boiler (PWD3HSLBOILER)Not included in AO. 7.3 LQD3PV01 This is the pressure vessel used for the 8.37 MMBtu/hr Steam Boiler. This is not a boiler. 2.08 Permitted boiler Permitted in current AO. 2.08 Permitted boiler Permitted in current AO. 14 Permitted boiler Permitted in current AO. 6.3 Parker T6800LR Boiler (LQDBOILER04)Permitted as 6.4 MMBtu/hr in current AO. 0.77 Parker Boiler WH730 (LQD3BOILER01)Not included in AO. 14 Armstrong Flo-Direct Water Heater with Low NOx Burner Permitted in current AO. Air Handling Unit 1.62 Bessamaire Direct Industrial Air Handling Unit BCY-25TLF Not included in AO. 5 Heat Transfer labelers, each with 4 Burners and 1 Heat Transfer Labeler with 6 Burners 1.092 Each Burner at a rated heat input capacity of 42,000 BTU/hr Permitted in current AO. Miscellaneous Boilers 13.05 Miscellaneous Permitted Boilers Permitted in current AO. Total Rated Heat Input Capacity at the Facility 37.163 MMBtu/hr Natural Gas High Heat Value 1026 MMBtu/MMcuft natural gas 40 CFR 98 Subpart C, Table 1 Potential Hourly Use of Natural Gas 0.0362 MMcuft natural gas/hr Potential Annual Use of Natural Gas 317 MMcuft natural gas/yr Maximum Permitted Fuel Use 533.7 MMcuft natural gas/yr Potential to Emit Criteria Pollutants Pollutant AP-42 Emission Factor (lb/MMcuft) Source of Emission Factor Emissions (lb/yr)Emissions (tons/yr) Emissions (lb/hr) NOx from Conventional Burner 100 Table 1.4-1 31,730 15.86 3.62 CO 84 Table 1.4-1 26,653 13.33 3.04 PM10 (Primary)7.6 Table 1.4-2 2,411 1.21 0.28 SO2 0.6 Table 1.4-2 190 0.10 0.02 VOC 5.5 Table 1.4-2 1,745 0.87 0.20 Lead 0.0005 Table 1.4-2 0.16 0.000079 0.000018 One Conditioning Drum Heater Boilers and Water Heaters Appendix C- Boilers and Heaters Firing Natural Gas Potential to Emit Hazardous Air Pollutants Pollutant AP-42 Emission Factor (lb/MMcuft) Reference Emissions (lb/yr)Emissions (tons/yr) Emissions (lb/hr) Benzene 2.10E-03 AP-42, table 1.4-3 0.67 0.0003 7.61E-05 Dichlorobenzene 1.20E-03 AP-42, table 1.4-3 0.38 0.0002 4.35E-05 Formaldehyde 7.50E-02 AP-42, table 1.4-3 23.80 0.0119 2.72E-03 Hexane 1.80E+00 AP-42, table 1.4-3 571.14 0.2856 6.52E-02 Toluene 3.40E-03 AP-42, table 1.4-3 1.08 0.0005 1.23E-04 Naphthalene 6.10E-04 AP-42, table 1.4-3 0.19 0.0001 2.21E-05 Polycyclic Organic Matter *8.82E-05 AP-42, table 1.4-3 0.03 0.000014 3.19E-06 Arsenic 2.00E-04 AP-42, table 1.4-4 0.06 0.00003 7.24E-06 Beryllium 1.20E-05 AP-42, table 1.4-4 0.00 0.000002 4.35E-07 Cadmium 1.10E-03 AP-42, table 1.4-4 0.35 0.0002 3.98E-05 Chromium 1.40E-04 AP-42, table 1.4-4 0.04 0.00002 5.07E-06 Cobalt 8.40E-05 AP-42, table 1.4-4 0.03 0.00001 3.04E-06 Manganese 3.80E-04 AP-42, table 1.4-4 0.12 0.0001 1.38E-05 Mercury 2.60E-04 AP-42, table 1.4-4 0.08 0.0000 9.42E-06 Nickel 2.10E-03 AP-42, table 1.4-4 0.67 0.0003 7.61E-05 Selenium 2.40E-05 AP-42, table 1.4-4 0.01 0.000004 8.69E-07 0.299323 0.068339 Greenhouse Gases Potential to Emit Gas Emission Factor (EF) (kg/MMBtu) Global Warming Potential (GWP)Reference Emissions (lb/yr) Emissions (ton/yr) Greenhouse Gas (ton CO2e/yr) CO2 53.06 1 EF: Table C-1 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 38,088,223 19,044 19,044 CH4 1.00E-03 25 EF: Table C-2 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 718 0.4 10 N2O 1.00E-04 298 EF: Table C-2 of 40 CFR 98 Subpart C GWP: Table A-1 of 40 CFR 98 Subpart A 72 0.04 12 19,066 Potential to Emit Miscellaneous Air Pollutants Pollutant Emission Factor (lb/MMcuft) Reference Emissions (lb/yr)Emissions (tons/yr) Emissions (lb/hr) Ammonia 3.2 UDAQ Emission Factor by Process 1708 0.85 0.19 GHG (ton CO2e/yr) * Emission factor for polycyclic organic matter is calculated by summing emission factors for individual constituents listed in AP-42, table 1.4-3. Total HAP Appendix C - Miscellaneous Sources Source Emissions Accounted for Using Mass Balance Assuming 100% Evaporation QA Lab Totals (lbs) VideoJet 16-8530Q Ink VideoJet 16-8535F Make-Up Fluid VideoJet Marsh Ink IJ-P- BK2-G5 VideoJet Cleaning Solution V901-Q VideoJet Cleaning Solution V904-Q VideoJet 410-D Ink VideoJet V469-D Ink VideoJet MakeUp Fluid V705-D VideoJet V710-D Make-Up Fluid Methanol Container plastic bottle carboy carboy plastic bottle plastic bottle cartridge cartridge cartridge cartridge glass bottle Product/container (gallons)0.375 5 5 0.265 0.265 0.2 0.2 0.2 0.2 1 Density (lbs/gal)7.26 6.67 8.42 6.67 6.54 7.51 7.22 6.67 6.57 6.6 Calculate VOC content: % VOC 76%99%8%99%30%44%100%99%40%100% VOC/container (lbs)2.0691 33.0165 3.368 1.749875 0.51993 0.66088 1.444 1.32066 0.5256 6.6 Containers/year (actual)0 0 17 74 38 22 29 378 474 24 Actual VOC Emissions 0 0 57.26 129.49 19.76 14.54 41.88 499.21 249.13 158.4 Actual-PTE-Factor 2 2 2 2 2 2 2 2 2 4 Potential VOC (lb/yr)2656.13 0 0 114.51 258.98 39.51 29.08 83.75 998.42 498.27 633.6 HAP: Methanol % Methanol 100% Methanol/container (lbs)6.5969 Potential Methanol (lb/yr)633.6 633.6 Emission rate (lb/hr)0.018 0.018082192 HAP: Glycol Ether % Glycol Ether 13% Glycol Ether/container (lbs)5.47 Potential Glycol Ether (lb/yr)186.08 186.08 Emission rate (lb/hr)0.011 0.010621 HAP: Ethylene Glycol % Ethylene Glycol Ethylene Glycol/container (lbs) Potential Ethylene Glycol (lb/yr)0 Emission rate (lb/hr)0 HAP: MIBK % Methyl Isobutyl Ketone (MIBK) MIBK/container (lbs)1% Potential MIBK (lb/yr)0 0 Emission rate (lb/hr)0 0 HAP: Trichloroethylene (TCE) % Trichloroethylene (TCE) TCE/container (lbs) Potential TCE (lb/yr)0 Emission rate (lb/hr)0 HAP: Perc % Tetrachloroethylene (Perc) Perc/container (lbs) Potential Perc (lb/yr)0 Emission rate (lb/hr)0 HAP: All HAPs Potential Total (lb/yr)819.68 --186.08 ------633.60 Potential Total (ton/yr)0.41 --0.093 ------0.317 Total Emission rate (lb/hr)0.09 --0.021 ------0.072 VideoJet Coders - Printing lot and date codes of product containers Product Appendix C - Blending and Transferring Liquid Products Based on Generic Recipe Raw Material Constituent CASN Fraction in Raw Material Vapor Pressure (mm Hg 20° F)Molecular Weight % in Recipe % in Batch Molecular Abundance C12-C15 Alcohol Ethoxylate 7EO C12-C15 Alcohol Ethoxylate 6131-39-5 1.00 7.54E-11 406.61 17.50%17.50%0.0430 Glycerin Glycerin 56-81-5 1.00 3.00E-03 92.09 25.00%25.00%0.2715 Ethanol Ethyl Alcohol 64-17-5 1.00 4.46E+01 46.07 0.01%0.01%0.0002 Ethanolamine Ethanolamine 141-43-5 0.99 4.04E-01 61.08 1.80%1.78%0.0291 Water Water 0 1.00 1.75E+01 18.02 20.00%20.00%1.1099 0.25% Benzenesulfonic Acid, 2,2'-([1,1'-biphenyl]- 4,4'-diyldi-2,1-ethenediyl)bis-disodium salt 27344-41-8 0.90 0.00E+00 562.56 0.23%0.0004 N,N-dimethylformamide 68-12-2 0.15 3.87E+00 73.10 0.04%0.0005 4.50% Dodecylbenzene Sulfonic Acid 27176-87-0 0.96 7.93E-11 327.51 4.32%0.0132 Sulfuric Acid 7664-93-9 0.02 1.00E-03 98.08 0.09%0.0009 Coconut Oil Fatty Coconut Fatty Acid 61788-47-4 1.00 0.00E+00 200.32 7.50%7.50%0.0374 15.00% Sodium Laureth Sulfate 68585-34-2 0.60 0.00E+00 362.50 9.00%0.0248 Ethanol 0 0.14 4.46E+01 46.07 2.03%0.0441 Water 0 0.27 1.75E+01 18.02 3.98%0.2209 4.50% Aziridine, homopolymer 68130-99-4 0.80 0.00E+00 860.00 3.60%0.0042 Water 0.20 1.75E+01 18.02 0.90%0.0499 Enzyme: Coronase 48UL 3.00% Subtilisin 9014-01-1 0.07 0.00E+00 33,000.00 0.21%0.0000 Water 0 0.93 1.75E+01 18.02 2.79%0.1548 Orangina 1.00% Limonene 138-86-3 0.55 1.00E+00 136.24 0.55%0.0040 C100 Isomers 106-24-1 0.07 2.00E-01 154.25 0.07%0.0005 Nonvolatile Constituents 5413-60-5 0.38 0.00E+00 300.00 0.38%0.0013 100.06%99.98%2.0107 Sodium C12-C14 Alcohol Ethoxysulfate 3EO (AES) Tinopal CBS-X Swiss 2-Phenyl Sulfonic Acid (LAS) Totals Sokalan HP20 Polymer Appendix C - Blending and Transferring Liquid Products Based on Generic Recipe Raw Material Constituent CASN C12-C15 Alcohol Ethoxylate 7EO C12-C15 Alcohol Ethoxylate 6131-39-5 Glycerin Glycerin 56-81-5 Ethanol Ethyl Alcohol 64-17-5 Ethanolamine Ethanolamine 141-43-5 Water Water 0 Benzenesulfonic Acid, 2,2'-([1,1'-biphenyl]- 4,4'-diyldi-2,1-ethenediyl)bis-disodium salt 27344-41-8 N,N-dimethylformamide 68-12-2 Dodecylbenzene Sulfonic Acid 27176-87-0 Sulfuric Acid 7664-93-9 Coconut Oil Fatty Coconut Fatty Acid 61788-47-4 Sodium Laureth Sulfate 68585-34-2 Ethanol 0 Water 0 Aziridine, homopolymer 68130-99-4 Water Enzyme: Coronase 48UL Subtilisin 9014-01-1 Water 0 Orangina Limonene 138-86-3 C100 Isomers 106-24-1 Nonvolatile Constituents 5413-60-5 Sodium C12-C14 Alcohol Ethoxysulfate 3EO (AES) Tinopal CBS-X Swiss 2-Phenyl Sulfonic Acid (LAS) Sokalan HP20 Polymer Mole Fraction in Liquid Partial Pressure in Vapor (mmHg) Mole Fraction in Vapor (including non-VOC) Mole Fraction in Vapor (VOC only) 0.0214 0.00000 1.12E-13 1.63E-12 0.1350 0.00041 2.82E-05 4.08E-04 0.0001 0.00482 3.35E-04 4.86E-03 0.0145 0.00586 4.08E-04 5.90E-03 0.5520 9.65960 6.72E-01 0.0002 0.00000 0.00E+00 0.00E+00 0.0003 0.00105 7.33E-05 1.06E-03 0.0066 0.00000 3.62E-14 5.24E-13 0.0005 0.00000 3.18E-08 0.0186 0.00000 0.00E+00 0.00E+00 0.0123 0.00000 0.00E+00 0.00E+00 0.0219 0.97803 6.81E-02 9.86E-01 0.1098 1.92665 1.34E-01 0.0021 0.00000 0.00E+00 0.00E+00 0.0248 0.43568 3.03E-02 0.0000 0.00000 0.00E+00 0.00E+00 0.0770 1.35059 9.40E-02 0.0020 0.00201 1.40E-04 2.02E-03 0.0002 0.00005 3.14E-06 4.55E-05 0.0006 0.00000 0.00E+00 0.00E+00 1.0000 14.36473 1.00000 1.00 0.99221 0.06893 Non- Non- Non- Non- Excluding non-VOC Non- Appendix C - Blending and Transferring Liquid Products Based on Generic Recipe Raw Material Constituent CASN C12-C15 Alcohol Ethoxylate 7EO C12-C15 Alcohol Ethoxylate 6131-39-5 Glycerin Glycerin 56-81-5 Ethanol Ethyl Alcohol 64-17-5 Ethanolamine Ethanolamine 141-43-5 Water Water 0 Benzenesulfonic Acid, 2,2'-([1,1'-biphenyl]- 4,4'-diyldi-2,1-ethenediyl)bis-disodium salt 27344-41-8 N,N-dimethylformamide 68-12-2 Dodecylbenzene Sulfonic Acid 27176-87-0 Sulfuric Acid 7664-93-9 Coconut Oil Fatty Coconut Fatty Acid 61788-47-4 Sodium Laureth Sulfate 68585-34-2 Ethanol 0 Water 0 Aziridine, homopolymer 68130-99-4 Water Enzyme: Coronase 48UL Subtilisin 9014-01-1 Water 0 Orangina Limonene 138-86-3 C100 Isomers 106-24-1 Nonvolatile Constituents 5413-60-5 Sodium C12-C14 Alcohol Ethoxysulfate 3EO (AES) Tinopal CBS-X Swiss 2-Phenyl Sulfonic Acid (LAS) Sokalan HP20 Polymer Calculate Molecular weight of Vapor (VOC only) 6.61E-10 3.76E-02 2.24E-01 3.60E-01 0.00E+00 7.76E-02 1.72E-10 0.00E+00 0.00E+00 4.54E+01 0.00E+00 0.00E+00 2.76E-01 7.02E-03 0.00E+00 46.39 VOC VOC VOC VOC VOC Appendix C - Charging Solids into Pre-Mixer Blending Tanks Emission Factor Equation (1) from AP 42, Section 13.2.4: Aggregate Handling And Storage Piles Where: E = Emission Factor (lb/ton) k = Particle size multiplier U = Relative Air Shear Speed (mph) M = Material moisture content (%) 0.50 % 19 mph 0.74 0.35 0.053 8760 hr/yr Relative Air Shear Speed Calculation Rel. Air Shear Speed (ft/s) = sqrt[2 x g (ft/s2) x h (ft)], where: h = Drop Height (ft)12.00 ft g = Acceleration due to gravity (ft/s2)32 ft/s2 Calculations for PM Emission Factor Number of Tanks [2]6 tanks Batch Time per Tank 4 hr/batch Batches per year per Tank 2190 batch/yr Size of Powdered Ink Containers 50 lb/bag Maximum Solids Charge Rate 20 bag/batch Maximum Solids Charge Rate 1000 lb/batch AP-42 PM Emission Factor 9.29E-02 lb/ton AP-42 PM-10 Emission Factor 4.39E-02 lb/ton AP-42 PM-2.5 Emission Factor 6.65E-03 lb/ton Dry PigmentMaterial Delivered Moisture Content of Solids [1] AP-42 Particle Size Multiplier (<2.5 µm) [1] AP-42 Particle Size Multiplier (<30µm) [1] Parameters Relative Air Shear Speed (ft/s) AP-42 Particle Size Multiplier (<10 µm) [1] Maximum Operating Hours Appendix C - Charging Solids into Pre-Mixer Blending Tanks PM-10 Emissions PM-10 Emission Rate per Tank PM-10 Emission Rate per Tank Total Facility PM- 10 Emission Rate Total Facility PM- 10 Emission Rate (lb/hr)(ton/yr)(lb/hr)(ton/yr) 5.49E-03 2.40E-02 0.03 0.14 PM-2.5 Emissions PM-2.5 Emission Rate per Tank PM-2.5 Emission Rate per Tank Total Facility PM- 2.5 Emission Rate Total Facility PM- 2.5 Emission Rate (lb/hr)(ton/yr)(lb/hr)(ton/yr) 8.31E-04 3.64E-03 0.00 0.02 HAP Emissions HAP Content in Solids [3] HAP Emission Rate per Tank HAP Emission Rate per Tank Total Facility HAP Emission Rate Total Facility HAP Emission Rate (%)(lb/hr)(ton/yr)(lb/hr)(ton/yr) 0.20%2.32E-05 1.02E-04 1.39E-04 6.10E-04 Notes: [1]: From AP-42, Fifth Edition, Volume I, Section 13.2.4: Aggregate Handling And Storage Piles. [2]: For a worst-case emissions analysis, it was assumed that the 6 pre-mixers will be charged with solid Tinopal CBS-X. [3]: Tinopal CBS-X contains 0.20% of N,N-dimethylformamide (CAS Number: 68-12-2). Appendix C - Liquids Assuming 100% Evaporation Organic Vapor Losses S= Saturation Factor from Table 5.2-1 P= Vapor Pressure of liquid is psia (calculated from the table above) = 0.9922 mm Hg = 0.019 psia M = Molecular weight of vapor (calculated from table above) = 46.39 T= Temperature of liquid loaded in °R (°R = °F + 460) = 528 °R Saturation Factor is determined as follows: The above recipe does not represent any product in current or planned production. It is a generic representation of all batches, and it was chosen to be conservative, in that emissions would be higher than those from any actual recipe. For example: the ethanol concentration is higher than in any existing recipe; salts, which lower the partial vapor pressure of volatile constituents, are not included; and water, which also lowers the partial vapor pressure of volatile constituents, is reduced. The evaporation of volatile constituents and vapor losses during tank filling and transfers is analogous to looses during the transportation of petroleum products and is therefore quantified based on AP-42, Chapter 5. Loading losses = 12.46 X S X P XM / T where: There are three points at which liquid products may have VOC emissions: 1) Blending of raw materials to make products - The saturation factor for blending is based on submerged loading and dedicated normal service. Our tanks are often cleaned between batches by praying water into them. The small air emissions from cleaning would add to the emissions from submerged loading of a clean mixer, being roughly equal to emissions from dedicated service. Consequently, the Saturation Factor, S(blending) = 0.60 2) Transfer of blended products to storage tanks - The Saturation Factor for transfer to storage tanks is also based on submerged loading and dedicated normal service or transfer to a clean tank with small emissions from cleaning. Consequently, the Saturation Factor, S(transfer) = 0.60 3) Transfer from storage tanks to fillers - This activity does not results in air emissions because product is enclosed in this phase 4) The Saturation Factor for filling bottles is based on splash loading of a clean vessel. S(filling)= 1.45. Overall Saturation Factor = S(blending) + S(transfer) + S(filling) = 0.60 + 0.60 + 1.45 = 2.65 Appendix C - Liquids Overall VOC Emissions from Liquids Blending and Packaging = 12.46 X S X P X M / T = 12.46 X 2.65 X .019191 X 46.39 / 528 = 0.055679 pounds per 1000 gallons of liquid product = 6.684192 pounds per 1,000,000 pounds of liquid product Potential to Emit for Blending and Transferring Liquid Products 2018 Total Liquids Production=pounds of detergent =541.5408 million pounds of detergent 2.5 X Actual Production pounds of detergent =1,353.85 million pounds of detergent PTE (lbs/yr)PTE (tons/yr) 9049.407 4.52470351 Component VOC (Annualized based on 1st 11 months of the year) 541,540,800 1,353,852,000 Potential = Appendix C - Maintenance Paint Booth Estimated maximum number of cans used 348 can/yr Actual number of cans purchased 180 can/yr Highest net weight of cans 15 oz. Assumed Transfer Efficiency 25% Maximum % Solids 3.2% Maximum VOC content 58% Maximum HAP content 7% Methyl Isobutyl Ketone 3% Xylene 3% Ethylbenzene 1% Filter Control Efficiency 99% Current Maximum Aerosol Emissions Annual Uncontrolled Emission Rate Annual Controlled Emission Rate (ton/yr)(ton/yr) PM 3.92E-03 3.92E-05 VOC 9.40E-02 9.40E-02 Total HAP 1.14E-02 1.14E-02 Methyl Isobutyl Ketone 4.89E-03 4.89E-03 Xylene 4.89E-03 4.89E-03 Ethylbenzene 1.63E-03 1.63E-03 The maintenance paint booth is currently only used for painting parts with aerosol spray paint cans. The booth is equipped with high efficiency over-spray filters. *Maximum HAP content from Spray Paint with the highest HAP Content (Safety Orange Gloss, Safety Red Gloss, and Safety Yellow Gloss) Pollutant Appendix C - Railcar Unloading SODA ASH FUGITIVE EMISSIONS Emission Factor Equation (1) from AP 42, Section 13.2.4: Aggregate Handling And Storage Piles Where: E = Emission Factor (lb/ton) k = Particle size multiplier U = Relative Air Shear Speed (mph) M = Material moisture content (%) Material Delivered Soda Ash Moisture Content of Solids [1]0.50 % Relative Air Shear Speed 7 mph AP-42 Particle Size Multiplier (<30µm) [1]0.74 AP-42 Particle Size Multiplier (<10 µm) [1]0.35 AP-42 Particle Size Multiplier (<2.5 µm) [1]0.053 Relative Air Shear Speed Calculation Rel. Air Shear Speed (ft/s) = sqrt[2 x g (ft/s2) x h (ft)], where: h = Drop Height (ft)1.50 ft *Estimated height of Railcar hopper to ground g = Acceleration due to gravity (ft/s2)32 ft/s2 Soda Ash Cone Pile Diameter of Pile 3.5 feet Height of Pile 0.417 feet Volume of Pile 1.34 ft3 Density of Soda Ash 21.03 lb/ft3 Mass of Pile 28.10 lb Number of Piles Under Railcar 2 piles/railcar Number of Railcars per Year 208 railcar/yr Assuming 1 railcar fills the silo, the soda ash silo is filled 4x per week. Mass of Material Leaked into Piles 11690 lb/yr Calculated PM Emission Factor AP-42 PM Emission Factor 2.40E-02 lb/ton AP-42 PM-10 Emission Factor 1.14E-02 lb/ton AP-42 PM-2.5 Emission Factor 1.72E-03 lb/ton PM Emissions PM Emission Rate PM Emission Rate (lb/yr)(ton/yr) 1.40E-01 7.02E-05 PM-10 Emissions PM-10 Emission Rate PM-10 Emission Rate (lb/yr)(ton/yr) 6.64E-02 3.32E-05 PM-2.5 Emissions PM-2.5 Emission Rate PM-2.5 Emission Rate (lb/yr)(ton/yr) 1.01E-02 5.03E-06 Parameters SALT FUGITIVE EMISSIONS Emission Factor Equation (1) from AP 42, Section 13.2.4: Aggregate Handling And Storage Piles Where: E = Emission Factor (lb/ton) k = Particle size multiplier U = Relative Air Shear Speed (mph) M = Material moisture content (%) Material Delivered Salt Moisture Content of Solids [1]0.50 % Relative Air Shear Speed (ft/s)7 mph AP-42 Particle Size Multiplier (<30µm) [1]0.74 AP-42 Particle Size Multiplier (<10 µm) [1]0.35 AP-42 Particle Size Multiplier (<2.5 µm) [1]0.053 Relative Air Shear Speed Calculation Rel. Air Shear Speed (ft/s) = sqrt[2 x g (ft/s2) x h (ft)], where: h = Drop Height (ft)1.50 ft *Estimated height of Railcar hopper to ground g = Acceleration due to gravity (ft/s2)32 ft/s2 Salt Cone Pile Diameter of Pile 3.5 feet Height of Pile 0.417 feet Volume of Pile 1.34 ft3 Density of Salt (as sodium chloride)2.17 lb/ft3 Mass of Pile 2.90 lb Number of Piles Under Railcar 2 piles/railcar Number of Railcars per Year 104 railcar/yr Assuming 1 railcar fills the silo, the salt silo is filled 2x per week. Mass of Material Leaked into Piles 603 lb/yr Calculated PM Emission Factor AP-42 PM Emission Factor 2.40E-02 lb/ton AP-42 PM-10 Emission Factor 1.14E-02 lb/ton AP-42 PM-2.5 Emission Factor 1.72E-03 lb/ton PM Emissions PM Emission Rate PM Emission Rate (lb/yr)(ton/yr) 7.25E-03 3.62E-06 PM-10 Emissions PM-10 Emission Rate PM-10 Emission Rate (lb/yr)(ton/yr) 3.43E-03 1.71E-06 PM-2.5 Emissions PM-2.5 Emission Rate PM-2.5 Emission Rate (lb/yr)(ton/yr) 5.19E-04 2.60E-07 Parameters Combined Railcar PM Emissions Soda Ash Salt Total Emissions PM (ton/yr)7.02E-05 3.62E-06 7.39E-05 PM-10 (ton/yr)3.32E-05 1.71E-06 3.49E-05 PM-2.5 (ton/yr)5.03E-06 2.60E-07 5.29E-06 Notes: [1]: From AP-42, Fifth Edition, Volume I, Section 13.2.4: Aggregate Handling And Storage Piles. Appendix C - Storage Tank Emissions Summary Uncontrolled Hourly VOC Emission Rate Uncontrolled Annual VOC Emission Rate Controlled Annual VOC Emission Rate (lb/hr)(ton/yr)(ton/yr) Tank 27 7EO Synthetic 25-7 NA Negligible [1]Negligible [1]NA Tank 22 Coco Fatty NA Negligible [1]Negligible [1]NA Tank 63 Armosoft DEQ Ethanol 0.080 0.351 0.018 [3] Tank 49 Stepanol NA Negligible [1]Negligible [1]NA Tank 66 PEG 400 Polyethylene Glycol 0.004 0.017 NA Tank 52 Citric Acid Citric Acid 0.011 0.050 NA Ethanol 0.049 0.213 NA Isopropyl Alcohol 0.002 0.008 NA Tank 23 9EO Non-ionic (L24-9)NA Negligible [1]Negligible [1]NA Tank 21 Natural 7EO Non-ionic NA Negligible [1]Negligible [1]NA Tank 45 Steol CS-270 Ether Sulfate (AES)NA Negligible [1]Negligible [1]NA Tank 65 SLES 70%NA Negligible [1]Negligible [1]NA Tank 63A Armosoft DEQ Ethanol 0.080 0.351 0.018 [3] Tank 65A SLES 70%NA Negligible [1]Negligible [1]NA Tank 1 Sulfonic Acid NA Negligible [1]Negligible [1]NA Tank 2 Sodium Silicate Liquid Alkaline NA Negligible [2]Negligible [2]NA 0.226 0.990 0.035 Notes: [2]: This tank's content does not contain organic material. [3]: Uncontrolled VOC emissions from tank used in PTE Summary. [1]: The molar mass and vapor pressure of this tank's contents are not conducive to evaporation. The low vapor pressure and the high molar mass of this material indicates that it does not have a tendency to evaporate. PollutantContentsTank ID Total Tank 60 200 Proof Ethanol Appendix C - Storage Tank Emissions Tank 63 & 63A (Armsoft DEQ) Outdoor Storage Tank Parameters Number of Tanks 2 Capacity 34,000 gal/tank Diameter 13 ft Height 34.5 ft (w/ a 0.4062 ft conical top section) Tank Contents Armosoft DEQ Density 8.342 lb/gal Control Efficiency of Carbon Canisters 95%Carbtrol G-1 Vapor Phase Carbon Canisters will be used for both DEQ Tanks 14,579,696 lb/yr 1,747,840.16 gal/yr The following table is taken from Emission Master Tanks output. Report summaries are attached in Appendix D. Per Vessel: 34,000 gal Storage Tank Uncontrolled Working Loss Uncontrolled Breathing Loss Uncontrolled Total Loss Controlled Total Loss (lb/yr)(lb/yr)(lb/yr)(lb/yr) Ethanol (VOC)697.7357 4.2599 701.9956 35.10 Notes: Tanks modeling assumes a maximum annual throughput based on the maximum monthly throughput forecast from June 2022 to May 2023, with a 15% conservative multiplier. The storage tank emissions were modeled using the worst case plant processing rate of The following emissions are based on Emission Master Tanks Software based on 2019 EPA Revision. Pollutant Appendix C - Storage Tank Emissions Tank 60 (Ethanol) Outdoor Storage Tank Parameters Capacity 29,000 gal/tank Diameter 14 ft Height 26 ft (w/ a 0.4375 ft conical top section) Tank Contents Density 6.843 lb/gal 4,149,985 lb/yr 606,465.88 gal/yr The following table is taken from Emission Master Tanks output. Report summaries are attached in Appendix D. Vessel: 29,000 gal Storage Tank Working Loss Breathing Loss Total Loss (lb/yr)(lb/yr)(lb/yr) Ethanol (VOC)407.3536 18.8907 426.2443 Isopropyl Alcohol (VOC) 15.5041 0.7272 16.2313 Notes: 200 Proof Ethanol The following emissions are based on Emission Master Tanks Software based on 2019 EPA Revision. The storage tank emissions were modeled using the worst case plant processing rate of Pollutant Tanks modeling assumes a maximum annual throughput based on the maximum monthly throughput forecast from June 2022 to May 2023, with a 15% conservative multiplier. Appendix C - Storage Tank Emissions Tank 66 (PEG 400) Mix Tank Parameters Capacity 29,000 gal 109777 L Tank Contents Tank Radius 7.0 ft Tank Circumference 43.98 ft Surface Area of Liquid 153.94 sqft Single Load Batch Time 4 hr/batch Max. Operation Hours 8760 hr/yr Number of Batches 2,190 batch/yr Max. Volume Processed 63,510,000 gal/yr 1. Polyethylene Glycol Vessel Filling Emissions E VOC = 6.92 x (S x P x M x Q) / T (Note 1) Parameter Symbol Saturation Factor (Note 2)S 1.45 Vapor Pressure P 4.35E-05 psia Vapor Molecular Weight M 400.00 lb/lb-mol Volume of Material Loaded Q 63510 103 gal/yr Temperature of Loaded Liquid T 327.6 °K 0.004 lb/hr 0.015 lb/batch Notes PEG 400 [2]:Saturation Factor for Splash Loading of a Clean Cargo Tank from AP-42 Table 5.2-1, " Saturation (S) Factors for Calculating Petroleum Liquid For calculating emissions, assume that the most volatile solvent is at its saturation level in every mixing vessel's headspace. So, as the vessel is filled, it will displace the saturated air in the headspace to the exterior of the vessel. Air emissions are calculated using the ideal gas law, PVM=mRT. Value Loading VOC Emissions EVOC [1]: Equation to calculate emissions found in "Methods for Estimating Air Emissions from Paint, Ink, and Other Coating Manufacturing Facilities." EIIP. Volume II, Chapter 8, Page 4. February 2005. Appendix C - Storage Tank Emissions Tank 52 (Citric Acid) Mix Tank Parameters Capacity 29,000 gal 109777 L Tank Contents Tank Radius 7.0 ft Tank Circumference 43.98 ft Surface Area of Liquid 153.94 sqft Single Load Batch Time 4 hr/batch Max. Operation Hours 8760 hr/yr Number of Batches 2,190 batch/yr Max. Volume Processed 63,510,000 gal/yr 1. Citric Acid Vessel Filling Emissions E VOC = 6.92 x (S x P x M x Q) / T (Note 1) Parameter Symbol Saturation Factor (Note 2)S 1.45 Vapor Pressure P 1.45E-03 psia Vapor Molecular Weight M 46.07 lb/lb-mol Volume of Material Loaded Q 63510 103 gal/yr Temperature of Loaded Liquid T 426.5 °K 0.01 lb/hr 0.05 lb/batch Notes Loading VOC Emissions EVOC [1]: Equation to calculate emissions found in "Methods for Estimating Air Emissions from Paint, Ink, and Other Coating Manufacturing Facilities." EIIP. Volume II, Chapter 8, Page 4. February 2005. Citric Acid [2]:Saturation Factor for Splash Loading of a Clean Cargo Tank from AP-42 Table 5.2-1, " Saturation (S) Factors for Calculating Petroleum Liquid Loading Losses." For calculating emissions, assume that the most volatile solvent is at its saturation level in every mixing vessel's headspace. So, as the vessel is filled, it will displace the saturated air in the headspace to the exterior of the vessel. Air emissions are calculated using the ideal gas law, PVM=mRT. Value Appendix H - Cost Analysis for Baghouses and Carbon Canisters COST ANALYSIS FOR A BAGHOUSE ON PRE-MIXER For a baghouse flow rate range between 2,000 and 10,000 CFM, the average cost ranges between $10,000 and $80,000 [1]. Therefore, for a range between 2,000 and 10,000 cfm, the ratio of cost per cfm is:8.75$ /cfm Assuming that the pre-mixer exhaust flow rate is 3,000 cfm, the cost of a baghouse would be: $26,250.00 $52,500.00 PM Emission Rate for Different Baghouse Performances Baghouse Performance Flow Rate (gr/dscf)(cfm)(lb/hr)(ton/yr) 0.005 3000 0.13 0.56 0.01 3000 0.26 1.13 0.02 3000 0.51 2.25 Notes: COST ANALYSIS FOR A CARBON CANISTER ON TANKS 63 AND 63A From the quote from Industrial Air Purification, Inc. (IAP), the cost per carbon canister is:$13,456.80 Including installation (assumed to be double the cost of the canister), the total cost per canister is:$26,913.60 The PTE uncontrolled VOC from each tank is:0.351 ton/yr Controlled emissions from each tank, fitted with a carbon canister with a control efficiency of 95% is:0.018 ton/yr The cost per ton VOC removed, for a carbon canister with a control efficiency of 95% is:$80,713.06 /ton VOC Therefore, the cost per ton of VOC removed of $83,045.36 exceeds typical BACT cost effectiveness. Because the PM-10 emissions from the pre-mixer are 0.19 ton/yr, which emits less than half of the PM emissions from a baghouse with a grain loading of 0.005 gr/dscf, adding a baghouse on the pre-mixer is not a justifiable cost for these operations. [1]: Average cost of a baghouse from U.S. Air Filtration, Inc., "How Much Does a Dust Collector Cost?" April 2021. <https://www.usairfiltration.com/how-much-does-a-dust-collector-cost/> PM Emission Rate In addition, there is also the cost to install a baghouse, which was assumed to be double the cost of the baghouse. In total, the cost of the baghouse and installation would be: Appendix E: Armosoft DEQ Laboratory Results PETRO-LUBRICANT TESTING LABORATORIES, INC. Member A.S.T.M. February 17, 2022 Test Report 22021502 116 Sunset Inn Road Lafayette, N.J. 07848 phone 973-579-3448 www.petrolube. com Marion Environmental 115 Parmenas Lane Chattanooga, IN 37405 ATTN: Mr. Randall Woodlee RE: Your Sample of February 15, 2022 Final Report Dear Mme., Analysis of your sample has been completed. The results are as follows: SAMPLE: REWOQUAT Lab# 22021502 TEST METHOD ASTM D2879 ASTM D2879 ASTM D2879 ASTM D2879 DESCRIPTION Vapor Pressure by Isotenlscope @ 115°F Vapor Pressure by Isotenlscope @ 140°F Vapor Pressure by Isotenlscope @ 165°F Vapor Pressure by Isotenlscope @ 185°F RESULTS Graph Attached *95.5 mmHg (Extrapolated) 168.4 mmHg 265.0 mmHg 407.5 mmHg *Note- Sample beginning to solidify @ 140 °F, unable to make direct measurement at 115°F TEST METHOD ASTM D2879 ASTM D2879 ASTM D2879 SAMPLE: ARMASOFT Lab# 22021503 DESCRIPTION Vapor Pressure by Isotenlscope @ 115°F Vapor Pressure by Isotenlscope @ 140°F Vapor Pressure by Isotenlscope @ 165°F RESULTS Graph Attached 101.7 mmHg 177.4 mmHg 297.9 mmHg Please call If you have any questions regarding this report. Resj^ectfully submftted. Tohn WIntermute Technical Director JW:ak Attachments (2-ASTM D2879 Graphs) Letters and reports shall not be reproduced except in fuH without written permission of Petro-Lubricant Testing Laboratories. The information herein applies only to die specific matenal or products tested and is for the exclusive use of the diente to whom they aiB adriressed. The liability of Petro-Lubricant Testing Laboratories shall be limited to the anount of compensation paid for testing services. No warranty of any kind is implied. 2.7 2.6 2.5 D) h o 3 (/> 0)2.3 O) o ®2.2 0) V) (0 m 2.1 1.9 0.0027 Petro-Lubricant Testing Laboratories, Inc. Marion Environmental ASTM D2879 Vapor Pressure by Isoteniscope 407.5 mm Hg fm 185"F V S' A V V V sS s 2bo.U mm Hg @ s s Si s ss V > s s SS sS V s s ¥ r \ s V- A 168.4 mm Hg 5) 140°F S V s s. s s s s 95.5 mm Hg 115°F H3 extapolated value S, V V- 0.0028 0.0029 0.003 0.0031 Reciprocal degrees Kelvin 0.0032 February 17, 2022 Sample: REWOQUAT Lab# 22021502 2.7 2.6 2.5 3 h o i_ 3 (A p2.3 o o !2.2 0) (0 <0 OQ 2.1 1.9 Petro-Lubricant Testing Laboratories, inc. Marion Environmental ASTM D2879 Vapor Pressure by isoteniscope s V V S N s S s \ s. s s V it 297.9 mm Ha (a.165°F \ s. s. s V * 3 3 177.4 mm Hg 140°Fw ss. > \ 101.7 mm Hg 115-F \ W S 0.0027 0.0026 0.0029 0.003 0.0031 0.0032 Reciprocal degrees Kelvin February 17, 2022 Sample: ARMASOFT Lab# 22021503 Appendix F: Emission Master Model Extended Report Emission Master 8.4.4.31 6:08:53 PM, 10/3/2022 page 1 C:\Users\Anielle.Duritza\OneDrive - ERM\Private\Desktop\Projects\Henkel\Henkel TANKS_SLC\Henkel_SLC.emm Title Page Product: Henkel_SLC Process: Tanks 60 & 63 Process Cycle Time: 365 days Final Product Amount: 2.35430604e6 gal Evaluation Date: 6/10/2022 File Name: C:\Users\Anielle.Duritza\OneDrive - ERM\Private\Desktop\Projects\Henkel\Henkel TANKS_SLC\Henkel_SLC.emm Connected Database: \\usbdclic01\EMTanks\Emaster Calculation type: MACT98 Condenser Calc. type:Single Stage Charge Calc. type: Initial Composition Material Balance: Subtract Emissions Last Saved User: Anielle.Duritza Last Saved Time: 8:42:26 AM, 6/15/2022 Comment: Defined Activities 1) [Storage] Tank 60 2) [Storage] Tank 63 Emission Master 8.4.4.31 6:08:53 PM, 10/3/2022 page 2 C:\Users\Anielle.Duritza\OneDrive - ERM\Private\Desktop\Projects\Henkel\Henkel TANKS_SLC\Henkel_SLC.emm 1: Storage Tank Activity Title: Tank 60 Start Date: 1/1/2022 End Date: 12/31/2022 Elapsed Time: 365.0 days Vent ID: Noncondensable: Air @ 0 Nm³/h Saturation: 100% Pressure: -2.08 psig Using Monthly Avg. Temp. Location: Utah, Salt Lake City Volume Throughput: 606465.88 gal Crude Oil Factor-Kc: 1 Vessel Name: Tank 60 - SLC Void Vol.: 30,108.07 gal Work Vol.: 29,000 gal No Control Devices Final Contents 29000.0 gal 190861.9392 lb -0.1 °C Weight Pure-Vp W[i] X[i] A[i] X*Vp*A [Liquid Phase] (lb) (kPa) (kPa) Ethanol 181815.0832 1.557 0.953 0.963 1 1.4998 Isopropyl Alcohol 9046.8559 1.0977 0.047 0.037 1 0.0403 Emissions From Vessel: Tank 60 - SLC Effective Vp Working Breathing Total Rate [Non Condensables] (mm Hg) (lb) (lb) (lb) (lb/hr) Air 82.6796 5101.7343 192.3078 5294.042 0.6043 [Condensables] (mm Hg) (lb) (lb) (lb) (lb/hr) Ethanol 4.186 407.3536 18.8907 426.2443 0.0487 Isopropyl Alcohol 0.1222 15.5041 0.7272 16.2313 0.0019 Emission Master 8.4.4.31 6:08:53 PM, 10/3/2022 page 3 C:\Users\Anielle.Duritza\OneDrive - ERM\Private\Desktop\Projects\Henkel\Henkel TANKS_SLC\Henkel_SLC.emm 2: Storage Tank Activity Title: Tank 63 Start Date: 1/1/2022 End Date: 12/31/2022 Elapsed Time: 365.0 days Vent ID: Noncondensable: Air @ 0 Nm³/h Saturation: 100% Pressure: -2.08 psig Using Monthly Avg. Temp. Location: Utah, Salt Lake City Volume Throughput: 1.74784016e6 gal Crude Oil Factor-Kc: 1 Vessel Name: Tank 63 - SLC Void Vol.: 34,389.32 gal Work Vol.: 34,000 gal No Control Devices Final Contents 34000.0 gal 283627.8524 lb -0.1 °C Weight Pure-Vp W[i] X[i] A[i] X*Vp*A [Liquid Phase] (lb) (kPa) (kPa) Armsoft DEQ 283627.8524 1.5235 1.0 1.0 1 1.5235 Emissions From Vessel: Tank 63 - SLC Effective Vp Working Breathing Total Rate [Non Condensables] (mm Hg) (lb) (lb) (lb) (lb/hr) Air 83.6952 11162.6528 58.1754 11220.8282 1.2809 [Condensables] (mm Hg) (lb) (lb) (lb) (lb/hr) Armsoft DEQ 3.2926 697.7357 4.2599 701.9956 0.0801 Emission Master 8.4.4.31 6:08:53 PM, 10/3/2022 page 4 C:\Users\Anielle.Duritza\OneDrive - ERM\Private\Desktop\Projects\Henkel\Henkel TANKS_SLC\Henkel_SLC.emm Summary Page Emissions for (Unspecified Vent): CAS Avg. Rate Max. Rate Total Weight Air 132259-10-0 1.8853 lb/hr 1.2809 lb/hr 16514.8702 lb Armsoft DEQ 64-17-5 0.0801 lb/hr 0.0801 lb/hr 701.9956 lb Ethanol 64-17-5 0.0487 lb/hr 0.0487 lb/hr 426.2443 lb Isopropyl Alcohol 67-63-0 0.0019 lb/hr 0.0019 lb/hr 16.2313 lb Total emissions for all vents: CAS Avg. Rate Max. Rate Total Weight Air 132259-10-0 1.8853 lb/hr 1.2809 lb/hr 16514.8702 lb Armsoft DEQ 64-17-5 0.0801 lb/hr 0.0801 lb/hr 701.9956 lb Ethanol 64-17-5 0.0487 lb/hr 0.0487 lb/hr 426.2443 lb Isopropyl Alcohol 67-63-0 0.0019 lb/hr 0.0019 lb/hr 16.2313 lb Appendix G: NSPS Operating Plan for Tanks 63 & 63A Operating Plan Air Pollution Control of Volatile Organic Liquid Storage Tanks 40 CFR 60 Subpart Kb This plan was drafted in order to satisfy the requirement of 40 CFR §60.113b(c)(1)(i) of the New Source Performance Standard for Volatile Organic Liquid Storage Tanks. This plan provides the necessary information needed to assure compliance with the 95% VOC reduction standard in 40 CFR §60.112b(a)(3)(ii). The plan addresses monitoring the performance of the air pollution control device and leaks from the closed vent system as required by 40 CFR §60.113b(c)(1)(ii) and (c)(2). The control device used for this application is a carbon canister. Carbon canisters are effective for storage tanks due to their ability to treat low flows. Use of a carbon canister as an air pollution control device can meet a performance level of 95% VOC control efficiency as EPA documentation indicates that activated carbon can reach control efficiencies that range from 95% to 98% under maximum loading conditions. The stream entering each carbon canister is from a fixed roof storage tank that contains raw materials with the volatile component being ethanol. Maximum loading on the canister occurs during tank filling. The filling rate of the tanks is 5000 gallons (802.7 cubic feet) per 30 minutes. This translates to 26.76 cubic feet per minute exhaust from the storage tank into the closed vent. Maximum gauge pressure is 8 inches of water column and maximum temperature is 160°F. A maximum VOC loading was measured during filling to be 242 ppmv (VOC). No breathing loss releases from the storage tank are anticipated because the tanks are maintained at near constant temperatures. The manufacturer’s design specifications for the control devices are attached. Monitoring and recordkeeping the performance of the carbon canisters: The carbon will be monitored weekly for break-through at the exit of the canister with a handheld monitor such as a flame detector or photoionization detector or a detector used for Method 25a of 40 CFR 60 Appendix A. The outlet of the canister will be monitored while the tanks are filling. In the absence of tank filling during a given week, no monitoring will take place. The monitoring equipment will be calibrated per manufacturer specifications. A concentration detected of 10 ppmv of VOC or more will signal that a canister is ready to be replaced. The spent canister will be removed and taken offsite. Each reading, time and date taken, and initials of the reader will be recorded in a log. The log will also indicate the time and date the canister was replaced. The log will be maintained onsite for inspection. Monitoring Leaks from the Closed Vent System Leading to the Carbon Canister In accordance with 40 CFR §60.112b(a)(3)(i), the closed vent system shall be monitored in accordance with 40 CFR §60.485(b). The standard for a detected leak is 500 ppmv VOC above background levels. Monitoring, repair or replacement of the closed vent system will be logged. Like monitoring for break- though, leak monitoring will be conducted weekly while tank filling is taking place. A leak detected must be repaired or replaced in a timely manner. Initial Inspection: The initial inspection shall be performed for the closed vent system as provided in 40 CFR §60.482- 10(f)(1) and (f)(2) in accordance with 40 CFR §60.485(b) in the following steps: 1. Method 21 of 40 CFR 60 Appendix A shall be used to determine the presence of a leak. The instrument shall be calibrated before use each day of its use by the procedures specified in Method 21. The following calibration gases shall be used: a. Zero air (less than 10 ppm of hydrocarbon in air); and b. A mixture of methane or n-hexane and air at a concentration of about, but less than, 10,000 ppm methane or n-hexane. 2. While filling the tank, measure the reading upwind of the point intended for measurement and recorded the reading as background concentration. 3. Take a reading as close as possible at the points inspected on the closed vent system. Record that reading. 4. Make repairs or parts replacements to correct leaks in a prompt manner. 5. Recheck measurements to assure repairs were successful. 6. Log the event, time and dates of measurements and repairs. Include names of participants. On-Going Annual Inspections: For a hard piped closed vent In accordance with 40 CFR §60.482-10(f)(1)(ii) the inspection will consist of a visual inspection for visible, audible, or olfactory indications of leaks. Log the time, date, person and result of the inspection. Also log repairs, verification inspections, and associated dates. For a ducted closed vent In accordance with 40 CFR §60.482-10(f)(2)(ii) the inspection will be performed in the manner performed for the initial inspection. Log the time, date, person and result of the inspection. Also log repairs, verification inspections and associated dates. 25 4 4 H i g h w a y 7 0 E a s t , Co o k e v i l l e , T N 3 8 5 0 6 Sa l e s @ I A P - A i r P r o d u c t s . c o m ww w . I A P - A i r P r o d u c t s . c o m Ca r b o n F i l t e r Ca r b o n F i l t e r -D i m e n s i o n : 1 5 " x 2 6 " ( 3 8 0 x 6 6 0 m m ) -M a t e r i a l : M 3 0 0 0 + M 9 0 0 0 Appendix H: Cost Analysis Supporting Calculations Appendix H - Cost Analysis for Baghouses and Carbon Canisters COST ANALYSIS FOR A BAGHOUSE ON PRE-MIXER For a baghouse flow rate range between 2,000 and 10,000 CFM, the average cost ranges between $10,000 and $80,000 [1]. Therefore, for a range between 2,000 and 10,000 cfm, the ratio of cost per cfm is:8.75$ /cfm Assuming that the pre-mixer exhaust flow rate is 3,000 cfm, the cost of a baghouse would be: $26,250.00 $52,500.00 PM Emission Rate for Different Baghouse Performances Baghouse Performance Flow Rate (gr/dscf)(cfm)(lb/hr)(ton/yr) 0.005 3000 0.13 0.56 0.01 3000 0.26 1.13 0.02 3000 0.51 2.25 Notes: COST ANALYSIS FOR A CARBON CANISTER ON TANKS 63 AND 63A From the quote from Industrial Air Purification, Inc. (IAP), the cost per carbon canister is:$13,456.80 Including installation (assumed to be double the cost of the canister), the total cost per canister is:$26,913.60 The PTE uncontrolled VOC from each tank is:0.351 ton/yr Controlled emissions from each tank, fitted with a carbon canister with a control efficiency of 95% is:0.018 ton/yr The cost per ton VOC removed, for a carbon canister with a control efficiency of 95% is:$80,713.06 /ton VOC Therefore, the cost per ton of VOC removed of $83,045.36 exceeds typical BACT cost effectiveness. Because the PM-10 emissions from the pre-mixer are 0.19 ton/yr, which emits less than half of the PM emissions from a baghouse with a grain loading of 0.005 gr/dscf, adding a baghouse on the pre-mixer is not a justifiable cost for these operations. [1]: Average cost of a baghouse from U.S. Air Filtration, Inc., "How Much Does a Dust Collector Cost?" April 2021. <https://www.usairfiltration.com/how-much-does-a-dust-collector-cost/> PM Emission Rate In addition, there is also the cost to install a baghouse, which was assumed to be double the cost of the baghouse. In total, the cost of the baghouse and installation would be: 1 Sub Total 26,913.60 KY STATE TAX (6%)1,614.82 Total $28,528.42 Thank you for the opportunity! Please contact me if you have any questions. Estimate #Q-220792 Estimate Date 02/25/2022 Reference VOC Tank Exhaust Sales Rep Michael Bradshaw Lead Time Stock Terms Net 30 Shipping Terms Prepay & Add Industrial Air Purification, Inc. 580 Technology Drive Sparta, Tennessee 38583 U.S.A Phone 931-372-0050 Bill To: Henkel US Operations Corporation 1 Henkel Way Rocky Hill CT 06067 Ship To: Henkel US Operations Corporation 385 Southwood Court Bowling Green KY 42101 Line Item Description Qty Rate Amount 1 MFE-1100 IAP Air Products Mobile Collector, MFE-1100, includes: - aluminum mesh pre-filter (washable) - 33 lb. carbon filter (refillable) - HEPA Filter (disposable) - filter gauge - 6" or 8" inlet - casters with brake - powder coated blue Note, the following to be removed before shipment: movable arm By Customer: - grounding/bonding 2 13,456.80 26,913.60 2 MFE-1100-HE MFE-1100, HEPA Filter and Frame. (1) per unit. 27 lbs.2 0.00 0.00 Terms & Conditions This quotation is limited to and conditioned upon acceptance of Industrial Air Purification's Terms and Conditions of Sale. These terms are incorporated herein by reference. By placing an order, customer accepts these terms. You may find a current copy at https://www. industrialairpurification.com/termsofsale Customer Authorized Signature QUOTATIONQUOTATION Christine Bodell <cbodell@utah.gov> Henkel Corporation Administrative Amendment_DAQE-AN104630031-23 Alyssa A Trujillo <alyssa.a.trujillo@henkel.com>Wed, Mar 13, 2024 at 1:51 PM To: Christine Bodell <cbodell@utah.gov> Cc: Roger Akel <Roger.Akel@erm.com>, Andrew Riddick <andrew.riddick@henkel.com> Hi Christine, Henkel Corporation would like to pursue an Administrative Amendment to Approval Order (AO) DAQE-AN104630031-23 instead of the Reduction of an Air Pollutant submitted and date March 8, 2024 (attached). During our call this morning, it was determined that an administrative amendment is the most appropriate avenue to accomplish Henkel’s intent. The objective is to allow for the storage of a material in Tanks 63 and 63A without being restricted to a specific brand name as it appears in the AO. Currently, the AO lists the brand name “Armosoft DEQ (Ethanol)” may be stored in Storage Tanks 63 and 63A at the following locations in the AO: 1. AO Condition II.A.14; and 2. AO Condition II.B.6.a(C) Henkel would like to replace “Armosoft DEQ (Ethanol)” with “Volatile Organic Liquid with a True Vapor Pressure not to exceed 34.3 kPa”. The True Vapor Pressure is measured by ASTM D2879. This vapor pressure is consistent with the NOI submitted for the development of AO DAQE-AN104630031-23. This NOI is attached. Thank you, Alyssa Trujillo Sr. Safety, Health, & Environmental Specialist Henkel Corporation | SLC Manufacturing USA Supply Chain Laundry & Home Care 3540 West 1987 South, Salt Lake City, UT 84104 Email: alyssa.a.trujillo@henkel.com Phone: (385) 444-1922 Web: www.henkel.com IMPORTANT NOTICE: This message may contain confidenal and/or privileged informaon. If you are not the intended recipient, please do not use its contents for any purpose, advise the sender immediately by reply e-mail and delete this message and any aachments without retaining any copy. ---------- Forwarded message ---------- From: Alyssa A Trujillo <alyssa.a.trujillo@henkel.com> To: Christine Bodell <cbodell@utah.gov> Cc: Roger Akel <Roger.Akel@erm.com>, Andrew Riddick <andrew.riddick@henkel.com> Bcc: Date: Tue, 12 Mar 2024 21:33:44 +0000 Subject: RE: [EXT] Re: Henkel Corporation Notification_DAQE-AN104630031-23 Absolutely, we will talk to you tomorrow. Thank you, Alyssa Trujillo Sr. Safety, Health, & Environmental Specialist Henkel Corporation | SLC Manufacturing USA Supply Chain Laundry & Home Care 3540 West 1987 South, Salt Lake City, UT 84104 Email: alyssa.a.trujillo@henkel.com Phone: (385) 444-1922 Web: www.henkel.com From: Christine Bodell <cbodell@utah.gov> Sent: Tuesday, March 12, 2024 3:32 PM To: Alyssa A Trujillo <alyssa.a.trujillo@henkel.com> Cc: Roger Akel <Roger.Akel@erm.com>; Andrew Riddick <andrew.riddick@henkel.com> Subject: Re: [EXT] Re: Henkel Corporation Notification_DAQE-AN104630031-23 This message is from an EXTERNAL SENDER – be CAUTIOUS, particularly with links and attachments 1130 works for me. I will send an invite. I just had some questions about the calculations/emission estimate approach. It would probably be easier to talk through them rather than go back and forth via email. Thanks, Christine On Tue, Mar 12, 2024 at 3:29 PM Alyssa A Trujillo <alyssa.a.trujillo@henkel.com> wrote: Hi Christine, Would 11:30am MDT work for you? Myself and Roger are available at this time; I am unsure if Andrew will be able to join us. Thank you, Alyssa Trujillo Sr. Safety, Health, & Environmental Specialist Henkel Corporation | SLC Manufacturing USA Supply Chain Laundry & Home Care 3540 West 1987 South, Salt Lake City, UT 84104 Email: alyssa.a.trujillo@henkel.com Phone: (385) 444-1922 Web: www.henkel.com From: Christine Bodell <cbodell@utah.gov> Sent: Tuesday, March 12, 2024 2:13 PM To: Alyssa A Trujillo <alyssa.a.trujillo@henkel.com> Cc: Roger Akel <Roger.Akel@erm.com>; Andrew Riddick <andrew.riddick@henkel.com> Subject: [EXT] Re: Henkel Corporation Notification_DAQE-AN104630031-23 This message is from an EXTERNAL SENDER – be CAUTIOUS, particularly with links and attachments Good Afternoon Alyssa, Thank you for taking my phone call this morning. I had some time to review the Reduction in Air Pollutants submission. Do you have time for a phone call tomorrow, any time after 11? Thanks, Christine On Mon, Mar 11, 2024 at 10:46 AM Alyssa A Trujillo <alyssa.a.trujillo@henkel.com> wrote: Good Morning, Attached please find the Notification in Reduction of an Air Pollutant for Henkel Corporation, DAQE-AN104630031-23. A copy of this notification was also submitted through the online portal. Please let me know if you have any questions or comments. Thank you, Alyssa Trujillo Sr. Safety, Health, & Environmental Specialist Henkel Corporation | SLC Manufacturing USA Supply Chain Laundry & Home Care 3540 West 1987 South, Salt Lake City, UT 84104 Email: alyssa.a.trujillo@henkel.com Phone: (385) 444-1922 Web: www.henkel.com IMPORTANT NOTICE: This message may contain confidential and/or privileged information. If you are not the intended recipient, please do not use its contents for any purpose, advise the sender immediately by reply e-mail and delete this message and any attachments without retaining any copy. IMPORTANT NOTICE: This message may contain confidential and/or privileged information. If you are not the intended recipient, please do not use its contents for any purpose, advise the sender immediately by reply e-mail and delete this message and any attachments without retaining any copy. 2 attachments RE: [EXT] Re: Henkel Corporation Notification_DAQE-AN104630031-23.eml 30K Henkel SLC Notice of Intent - Revision 2 Oct-14-22A sans SDS - Signed.pdf 11492K