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HomeMy WebLinkAboutDAQ-2025-001471 DAQE-AN160570002-25 {{$d1 }} Thomas Kubota Christensen Arms 550 North Cemetery Road Gunnison, UT 84634 thomask@christensenarms.com Dear Mr. Kubota: Re: Approval Order: Modification to Approval Order DAQE-AN160570001-22 to Add Two (2) Spray Paint Booths and Ten (10) Abrasive Blasting Units Project Number: N160570002 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on October 23, 2024. Christensen Arms must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Christine Bodell, who can be contacted at (385) 290-2690 or cbodell@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. No public comments were received on this action. Sincerely, {{$s }} Bryce C. Bird Director BCB:CB:jg cc: Central Utah Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Tim Davis Interim Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director March 19, 2025 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN160570002-25 Modification to Approval Order DAQE-AN160570001-22 to Add Two (2) Spray Paint Booths and Ten (10) Abrasive Blasting Units Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Christensen Arms - Gunnison Gun Manufacturing Plant Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality March 19, 2025 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 3 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 4 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 6 PERMIT HISTORY ..................................................................................................................... 9 ACRONYMS ............................................................................................................................... 10 DAQE-AN160570002-25 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Christensen Arms Christensen Arms - Gunnison Gun Manufacturing Plant Mailing Address Physical Address 550 North Cemetery Road 550 North Cemetery Road Gunnison, UT 84634 Gunnison, UT 84634 Source Contact UTM Coordinates Name: Thomas Kubota 430,617 m Easting Phone: (435) 469-2459 4,335,547 m Northing Email: thomask@christensenarms.com Datum NAD83 UTM Zone 12 SIC code 3484 (Small Arms) SOURCE INFORMATION General Description Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication, painting, assembly, and testing. Particulate emissions from contouring, machining, sanding, abrasive blasting, and spray booths are controlled by dust collectors or filters. NSR Classification Minor Modification at Minor Source Source Classification Located in Attainment Area Sanpete County Airs Source Size: B Applicable Federal Standards None Project Description Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to AO DAQE-AN160570001-22, issued March 16, 2022. DAQE-AN160570002-25 Page 4 The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen Arms is not requesting to increase the VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new spray booths will operate under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing. The ten (10) new abrasive sand blasting units will utilize two (2) cyclone dust collectors to control emissions. The existing abrasive sand blasting unit will continue to be controlled by the baghouse already permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase production or use of abrasive blasting material. While the addition of the new equipment may impact hourly emissions, production and paint usage are not increasing. Therefore, no annual emissions are increasing. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 1465.00 Carbon Monoxide 0 1.12 Nitrogen Oxides 0 1.12 Particulate Matter - PM10 0 0.31 Particulate Matter - PM2.5 0 0.31 Sulfur Dioxide 0 0.01 Volatile Organic Compounds 0 11.22 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Ethyl Benzene (CAS #100414) 0 1900 Generic HAPs (CAS #GHAPS) 0 100 Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 380 Phenol (CAS #108952) 0 560 Styrene (CAS #100425) 0 5720 Toluene (CAS #108883) 0 900 Xylenes (Isomers And Mixture) (CAS #1330207) 0 2780 Change (TPY) Total (TPY) Total HAPs 0 6.17 SECTION I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] DAQE-AN160570002-25 Page 5 I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Christensen Arms Gun Manufacturing Facility II.A.2 Contouring and Machining Areas Including forty-one (41) CNC machines equipped with coolant reservoirs, hydraulic presses, rifling machines, saws, tumblers, and grinders The work areas are controlled with a cyclone II.A.3 Various saws, tumblers, and grinders II.A.4 Fabrication of Carbon Fiber Composite Process II.A.5 Epoxy Resin Usage and Composite Molding Process Polyurethane and epoxy resins are mixed and combined with fiberglass prior to being used in the composite molding process II.A.6 Four (4) Spray Booths (Two (2) New) Controlled with filters DAQE-AN160570002-25 Page 6 II.A.7 Eleven (11) Abrasive Blasting Booths (Ten (10) New) Controlled with one (1) baghouse and two (2) new cyclones II.A.8 Sanding Operations Controlled with one (1) baghouse (same baghouse listed in II.A.7) II.A.9 Welding Operations II.A.10 Firing Range II.A.11 Misc. Natural Gas Combustion Equipment Including devices each rated less than 5 MMBtu/hr For information purposes only SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following sources to exceed the following opacity limits: A. Any baghouse or cyclone stack - 10% opacity B. Any filter stack - 10% opacity C. All other points - 20% opacity [R307-401-8] II.B.1.a.1 Opacity observations of visible emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.2 VOC & HAP Requirements II.B.2.a The owner/operator shall not emit more than the following from evaporative sources (solvent use, mold release, epoxy resin, lubricant use, adhesive, and paints) on site: A. 11.16 tons per rolling 12-month period of VOCs B. 0.95 tons per rolling 12-month period of ethyl benzene C. 0.19 tons per rolling 12-month period of methyl isobutyl ketone D. 0.28 tons per rolling 12-month period of phenol E. 2.86 tons per rolling 12-month period of styrene F. 0.45 tons per rolling 12-month period of toluene G. 1.39 tons per rolling 12-month period of xylene H. 6.15 tons per rolling 12-month period of all HAPs combined [R307-401-8] DAQE-AN160570002-25 Page 7 II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8] II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.2.a.3 The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons) [R307-401-8] II.B.2.b The owner/operator shall install and operate a set of paint arrestor particulate filters for each paint booth to control particulate emissions. All air exiting the booths shall pass through this control system before being vented to the atmosphere (outside building/operation). [R307-401-8] II.B.2.c The owner/operator shall install paint arrestor particulate filters that are each certified to meet a particulate matter control efficiency of no less than 84%. [R307-401-8] II.B.2.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed paint arrestor particulate filters. [R307-401-8] II.B.2.d The owner/operator shall maintain and replace the filters according to the manufacturer's instructions. [R307-401-8] II.B.2.e The paint booths shall be equipped with HVLP spray guns to control VOC emissions. [R307-401-8] II.B.2.f The owner/operator shall store the VOC/HAP-containing materials in closed and air tight containers when the materials are not in use. [R307-401-8] DAQE-AN160570002-25 Page 8 II.B.3 Sanding, Abrasive Blasting, Contouring, and Machining Operations Requirements II.B.3.a The owner/operator shall install and operate one (1) cyclone to control process streams from the contouring and machining operations. All exhaust air from the contouring and machining operations shall be routed through the cyclone before being vented to the atmosphere. [R307-401-8] II.B.3.b The owner/operator shall install and operate one (1) baghouse and two (2) cyclones to control process streams from the sanding and abrasive blasting operations. All exhaust air from the sanding and abrasive blasting operations shall be routed through a baghouse or cyclone before being vented to the atmosphere. [R307-401-8] II.B.3.c The owner/operator shall install a baghouse and cyclones that are each certified to meet a particulate matter control efficiency of no less than 99.9%. [R307-401-8] II.B.3.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed baghouse and cyclones. [R307-401-8] II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the differential pressure across each baghouse and cyclone. [R307-401-8] II.B.3.d.1 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.d.2 Each pressure gauge shall measure the pressure drop in 1-inch water column increments or less. [R307-401-8] II.B.3.e During operation of each baghouse and cyclone, the owner/operator shall maintain the static pressure differential across each baghouse and cyclone between 1.0 to 6.0 inches of water column. [R307-401-8] II.B.3.e.1 The owner/operator shall record the reading of each pressure gauge at least once per operating day. [R307-401-8] II.B.3.e.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Weekly static pressure differential readings; C. Date of reading [R307-401-8] II.B.3.f At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.f.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] DAQE-AN160570002-25 Page 9 PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN160570001-22 dated March 16, 2022 Is Derived From NOI dated October 23, 2024 Incorporates Additional Information dated December 6, 2024 DAQE-AN160570002-25 Page 10 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE-IN160570002-25 February 6, 2025 Thomas Kubota Christensen Arms 550 North Cemetery Road Gunnison, UT 84634 thomask@christensenarms.com Dear Mr. Kubota: Re: Intent to Approve: Modification to Approval Order DAQE-AN160570001-22 to Add Two (2) Spray Paint Booths and Ten (10) Abrasive Blasting Units Project Number: N160570002 The attached document is the Intent to Approve (ITA) for the above-referenced project. The ITA is subject to public review. Any comments received shall be considered before an Approval Order (AO) is issued. The Division of Air Quality is authorized to charge a fee for reimbursement of the actual costs incurred in the issuance of an AO. An invoice will follow upon issuance of the final AO. Future correspondence on this ITA should include the engineer's name, Christine Bodell, as well as the DAQE number as shown on the upper right-hand corner of this letter. Christine Bodell, can be reached at (385) 290-2690 or cbodell@utah.gov, if you have any questions. Sincerely, {{$s }} Alan D. Humpherys, Manager New Source Review Section ADH:CB:jg cc: Central Utah Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director STATE OF UTAH Department of Environmental Quality Division of Air Quality INTENT TO APPROVE DAQE-IN160570002-25 Modification to Approval Order DAQE-AN160570001-22 to Add Two (2) Spray Paint Booths and Ten (10) Abrasive Blasting Units Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Christensen Arms - Gunnison Gun Manufacturing Plant Issued On February 6, 2025 {{$s }} New Source Review Section Manager Alan D. Humpherys {{#s=Sig_es_:signer1:signature}} TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 3 SUMMARY OF EMISSIONS .................................................................................................... 4 PUBLIC NOTICE STATEMENT............................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 6 SECTION II: SPECIAL PROVISIONS ..................................................................................... 7 PERMIT HISTORY ..................................................................................................................... 9 ACRONYMS ............................................................................................................................... 10 DAQE-IN160570002-25 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Christensen Arms Christensen Arms - Gunnison Gun Manufacturing Plant Mailing Address Physical Address 550 North Cemetery Road 550 North Cemetery Road Gunnison, UT 84634 Gunnison, UT 84634 Source Contact UTM Coordinates Name: Thomas Kubota 430,617 m Easting Phone: (435) 469-2459 4,335,547 m Northing Email: thomask@christensenarms.com Datum NAD83 UTM Zone 12 SIC code 3484 (Small Arms) SOURCE INFORMATION General Description Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication, painting, assembly, and testing. Particulate emissions from contouring, machining, sanding, abrasive blasting, and spray booths are controlled by dust collectors or filters. NSR Classification Minor Modification at Minor Source Source Classification Located in Attainment Area Sanpete County Airs Source Size: B Applicable Federal Standards None Project Description Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to Approval Order DAQE-AN160570001-22, issued March 16, 2022. DAQE-IN160570002-25 Page 4 The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen Arms is not requesting to increase the VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new spray booths will operate under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing. The ten (10) new abrasive sandblasting units will utilize two (2) cyclone dust collectors to control emissions. The existing abrasive sand blasting unit will continue to be controlled by the baghouse already permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase production or use of abrasive blasting material. While the addition of the new equipment may impact hourly emissions, production and paint usage are not increasing. Therefore, no annual emissions are increasing. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 1465.00 Carbon Monoxide 0 1.12 Nitrogen Oxides 0 1.12 Particulate Matter - PM10 0 0.31 Particulate Matter - PM2.5 0 0.31 Sulfur Dioxide 0 0.01 Volatile Organic Compounds 0 11.22 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Ethyl Benzene (CAS #100414) 0 1900 Generic HAPs (CAS #GHAPS) 0 100 Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 380 Phenol (CAS #108952) 0 560 Styrene (CAS #100425) 0 5720 Toluene (CAS #108883) 0 900 Xylenes (Isomers And Mixture) (CAS #1330207) 0 2780 Change (TPY) Total (TPY) Total HAPs 0 6.17 PUBLIC NOTICE STATEMENT The NOI for the above-referenced project has been evaluated and has been found to be consistent with the requirements of UAC R307. Air pollution producing sources and/or their air control facilities may not be constructed, installed, established, or modified prior to the issuance of an AO by the Director. A 30-day public comment period will be held in accordance with UAC R307-401-7. A notification of the intent to approve will be published in the Sanpete Messenger on February 13, 2025. During the public comment period the proposal and the evaluation of its impact on air quality will be available for the public to review and provide comment. If anyone so requests a public hearing within 15 days of DAQE-IN160570002-25 Page 5 publication, it will be held in accordance with UAC R307-401-7. The hearing will be held as close as practicable to the location of the source. Any comments received during the public comment period and the hearing will be evaluated. The proposed conditions of the AO may be changed as a result of the comments received. SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] DAQE-IN160570002-25 Page 6 SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.A THE APPROVED EQUIPMENT II.A.1 Christensen Arms Gun Manufacturing Facility II.A.2 Contouring and Machining Areas Including forty-one (41) CNC machines equipped with coolant reservoirs, hydraulic presses, rifling machines, saws, tumblers, and grinders The work areas are controlled with a cyclone II.A.3 Various saws, tumblers, and grinders II.A.4 Fabrication of Carbon Fiber Composite Process II.A.5 Epoxy Resin Usage and Composite Molding Process Polyurethane and epoxy resins are mixed and combined with fiberglass prior to being used in the composite molding process II.A.6 Four (4) Spray Booths (Two (2) New) Controlled with filters II.A.7 Eleven (11) Abrasive Blasting Booths (Ten (10) New) Controlled with one (1) baghouse and two (2) new cyclones II.A.8 Sanding Operations Controlled with one (1) baghouse (same baghouse listed in II.A.7) II.A.9 Welding Operations II.A.10 Firing Range II.A.11 Misc. Natural Gas Combustion Equipment Including devices each rated less than 5 MMBtu/hr For information purposes only DAQE-IN160570002-25 Page 7 SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following sources to exceed the following opacity limits: A. Any baghouse or cyclone stack - 10% opacity B. Any filter stack - 10% opacity C. All other points - 20% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of visible emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.2 VOC & HAP Requirements II.B.2.a The owner/operator shall not emit more than the following from evaporative sources (solvent use, mold release, epoxy resin, lubricant use, adhesive, and paints) on site: A. 11.16 tons per rolling 12-month period of VOCs B. 0.95 tons per rolling 12-month period of ethyl benzene C. 0.19 tons per rolling 12-month period of methyl isobutyl ketone D. 0.28 tons per rolling 12-month period of phenol E. 2.86 tons per rolling 12-month period of styrene F. 0.45 tons per rolling 12-month period of toluene G. 1.39 tons per rolling 12-month period of xylene H. 6.15 tons per rolling 12-month period of all HAPs combined. [R307-401-8] II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8] DAQE-IN160570002-25 Page 8 II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.2.a.3 The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons). [R307-401-8] II.B.2.b The owner/operator shall install and operate a set of paint arrestor particulate filters for each paint booth to control particulate emissions. All air exiting the booths shall pass through this control system before being vented to the atmosphere (outside building/operation). [R307-401-8] II.B.2.c The owner/operator shall install paint arrestor particulate filters that are each certified to meet a particulate matter control efficiency of no less than 84%. [R307-401-8] II.B.2.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed paint arrestor particulate filters. [R307-401-8] II.B.2.d The owner/operator shall maintain and replaced the filters according to the manufacturer's instructions. [R307-401-8] II.B.2.e The paint booths shall be equipped with HVLP spray guns to control VOC emissions. [R307-401-8] II.B.2.f The owner/operator shall store the VOC/HAP-containing materials in closed and airtight containers when the materials are not in use. [R307-401-8] II.B.3 Sanding, Abrasive Blasting, Contouring, and Machining Operations Requirements II.B.3.a The owner/operator shall install and operate one (1) cyclone to control process streams from the contouring and machining operations. All exhaust air from the contouring and machining operations shall be routed through the cyclone before being vented to the atmosphere. [R307-401-8] II.B.3.b The owner/operator shall install and operate one (1) baghouse and two (2) cyclones to control process streams from the sanding and abrasive blasting operations. All exhaust air from the sanding and abrasive blasting operations shall be routed through a baghouse or cyclone before being vented to the atmosphere. [R307-401-8] DAQE-IN160570002-25 Page 9 II.B.3.c The owner/operator shall install a baghouse and cyclones that are each certified to meet a particulate matter control efficiency of no less than 99.9%. [R307-401-8] II.B.3.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed baghouse and cyclones. [R307-401-8] II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the differential pressure across each baghouse and cyclone. [R307-401-8] II.B.3.d.1 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.d.2 Each pressure gauge shall measure the pressure drop in 1-inch water column increments or less. [R307-401-8] II.B.3.e During operation of each baghouse and cyclone, the owner/operator shall maintain the static pressure differential across each baghouse and cyclone between 1.0 to 6.0 inches of water column. [R307-401-8] II.B.3.e.1 The owner/operator shall record the reading of each pressure gauge at least once per operating day. [R307-401-8] II.B.3.e.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Weekly static pressure differential readings; C. Date of reading. [R307-401-8] II.B.3.f At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.f.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN160570001-22 dated March 16, 2022 Is Derived From NOI dated October 22, 2024 Incorporates Additional Information dated December 6, 2024 DAQE-IN160570002-25 Page 10 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Sanpete Messenger Publication Name: Sanpete Messenger Publication URL: Publication City and State: Manti, UT Publication County: Sanpete Notice Popular Keyword Category: Notice Keywords: Christensen Arms Notice Authentication Number: 202502131101599157814 2892905420 Notice URL: Back Notice Publish Date: Thursday, February 13, 2025 Notice Content Utah Department of Environmental Quality, Division of Air Quality NOTICE OF INTENT A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for consideration by the Director: Company Name: Christensen Arms Location: Christensen Arms - Gunnison Gun Manufacturing Plant – 550 North Cemetery Road, Gunnison, UT Project Description: Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication, painting, assembly, and testing. Particulate emissions from contouring, machining, sanding, abrasive blasting, and spray booths are controlled by dust collectors or filters. Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to Approval Order (AO) DAQE- AN160570001-22, issued March 16, 2022. The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen Arms is not requesting to increase the VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new spray booths will operate under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing. The ten (10) new abrasive sand blasting units will utilize two (2) cyclone dust collectors to control emissions. The existing abrasive sandblasting unit will continue to be controlled by the baghouse already permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase production or use of abrasive blasting material. While the addition of the new equipment may impact hourly emissions, production and paint usage are not increasing. Therefore, no annual emissions are increasing. The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at the Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address on or before March 15, 2025, will be considered in making the final decision on the approval/disapproval of the proposed project. Email comments will also be accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this notice, a hearing will be held in accordance with R307-401-7, UAC. Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the Director to fully consider the substance and significance of the issue. Date of Notice: February 13, 2025 Published in the Sanpete Messenger Feb. 13, 2025 Back Jeree Greenwood <jereeg@utah.gov> Legal Notice to be published February 13, 2025 Jeree Greenwood <jereeg@utah.gov>Thu, Feb 6, 2025 at 7:00 AM To: Sanpete Messenger loyd <ads@sanpetemessenger.com> Please publish the following notice on February 13, 2025. Please also send this notice to Utahlegals.com. If you can, please reply to this email for my confirmation. Thank you, Jeree -- Jeree Greenwood Office Technician II | Minor NSR Section M: (385) 306-6514 airquality.utah.gov - DAQE-NN160570002-25.pdf 323K 2/11/25, 3:28 PM State of Utah Mail - Legal Notice to be published February 13, 2025 https://mail.google.com/mail/u/0/?ik=b4fd0e1085&view=pt&search=all&permmsgid=msg-a:r-8345006825049452198&simpl=msg-a:r-83450068250494…1/1 DAQE-NN160570002-25 February 6, 2025 Sanpete Messenger Legal Advertising Department 35 South Main Street Manti, UT 84646 RE: Legal Notice of Intent to Approve This letter will confirm the authorization to publish the attached NOTICE in the Sanpete Messenger on February 13, 2025. Please mail the invoice and affidavit of publication to the Utah State Department of Environmental Quality, Division of Air Quality, P.O. Box 144820, Salt Lake City, Utah 84114-4820. If you have any questions, contact Jeree Greenwood, who may be reached at (385) 306-6514. Sincerely, {{$s }} Jeree Greenwood Office Technician Enclosure cc: Six County Association of Governments cc: Sanpete County 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director DAQE-NN160570002-25 Page 2 NOTICE A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for consideration by the Director: Company Name: Christensen Arms Location: Christensen Arms - Gunnison Gun Manufacturing Plant – 550 North Cemetery Road, Gunnison, UT Project Description: Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication, painting, assembly, and testing. Particulate emissions from contouring, machining, sanding, abrasive blasting, and spray booths are controlled by dust collectors or filters. Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to Approval Order (AO) DAQE-AN160570001-22, issued March 16, 2022. The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen Arms is not requesting to increase the VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new spray booths will operate under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing. The ten (10) new abrasive sand blasting units will utilize two (2) cyclone dust collectors to control emissions. The existing abrasive sandblasting unit will continue to be controlled by the baghouse already permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase production or use of abrasive blasting material. While the addition of the new equipment may impact hourly emissions, production and paint usage are not increasing. Therefore, no annual emissions are increasing. The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at the Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address on or before March 15, 2025, will be considered in making the final decision on the approval/disapproval of the proposed project. Email comments will also be accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this notice, a hearing will be held in accordance with R307-401-7, UAC. Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the Director to fully consider the substance and significance of the issue. Date of Notice: February 13, 2025 {{#s=Sig_es_:signer1:signature}} AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 October 17, 2024 Utah Department of Environmental Quality (DEQ) 195 North 1950 West Salt Lake City, UT 84116 RE: NOI AO Modification Application Christensen Arms – Gunnison, Utah Project No. 117-RPS220197 To whom it may concern, On behalf of Christensen Arms, RPS Group, Inc. (dba RPS) a Tetra Tech Company is submitting a notice of intent (NOI) for an application for a modification to approval order (AO) DAQE-AN160570001-22 for Christensen Arms’ gun manufacturing facility located at 550 North Cemetery Road Gunnison, Utah. Operations at the site consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication, painting, assembly, and testing. The facility utilizes two dust collectors to control sanding emissions. Because the manufacturer and model information for one of the dust collectors is not available, emissions have been conservatively calculated excluding dust control. The facility also utilizes dry filters for the paint booth. This application encompasses administrative changes to the active AO, as well as the addition of two (2) spray booths, ten (10) blasters and two (2) dust collectors. This application consists of the following elements: • Utah Department of Environmental Quality Approval Order forms • Process Flow and Site Map • Emission Calculations • Best Available Control Technology (BACT) Analysis • Manufacturer Information Please do not hesitate to contact me with any questions regarding this application. Yours Sincerely, RPS Group, Inc. Macy Parchment Jena L. Grace Consultant lI Manager I, Air macy.parchment@tetratech.com jena.shaw@tetratech.com AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 Christensen Arms Gunnison, Utah NOI AO Modification Application Table of Contents Application Element Description Page No. Cover letter 1 Appendix A Forms 3 Form 1 – NOI Checklist 4 Form 2 – Company Information 5 Form 4 – Project Information – Abrasive Blasting Booths 6 Form 4 – Project Information – Metal Machining 7 Form 4 – Project Information – Spray Booths 8 Form 5 – Emissions Information 9 Form 13 – Spray Booth 3 10 Form 13 – Spray Booth 4 12 Form 6 – Cyclone 2 14 Form 6 – Cyclone 3 15 Appendix B Process Flow Diagram & Site Plan 16 Appendix C Emission Calculations 20 Appendix D BACT Analysis 35 Appendix E RBLC Data Base & Supporting Documentation 40 Appendix F Manufacture Specifications 143 Appendix G Safety Data Sheets 152 AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX A Forms Form 1 Date __________________ Notice of Intent (NOI) Application Checklist Company __________________ Utah Division of Air Quality New Source Review Section Source Identification Information [R307-401-5] 1. Company name, mailing address, physical address and telephone number 2. Company contact (Name, mailing address, and telephone number) 3. Name and contact of person submitting NOI application (if different than 2) 4. Source Universal Transverse Mercator (UTM) coordinates 5. Source Standard Industrial Classification (SIC) code 6. Area designation (attainment, maintenance, or nonattainment) 7. Federal/State requirement applicability (NAAQS, NSPS, MACT, SIP, etc.) 8. Source size determination (Major, Minor, PSD) 9. Current Approval Order(s) and/or Title V Permit numbers NOI Application Information:[R307-401] N/A N/A A. Air quality analysis (air model, met data, background data, source impact analysis)N/A Detailed description of the project and source process Discussion of fuels, raw materials, and products consumed/produced Description of equipment used in the process and operating schedule Description of changes to the process, production rates, etc. Site plan of source with building dimensions, stack parameters, etc. Best Available Control Technology (BACT) Analysis [R307-401-8] BACT analysis for all new and modified equipment Emissions Related Information: [R307-401-2(b)] Emission calculations for each new/modified unit and site-wide (Include PM10, PM2.5, NOx, SO2, CO, VOCs, HAPs, and GHGs) References/assumptions, SDS, for each calculation and pollutant All speciated HAP emissions (list in lbs/hr) Emissions Impact Analysis – Approved Modeling Protocol [R307-410] Composition and physical characteristics of effluent (emission rates, temperature, volume, pollutant types and concentrations) Nonattainment/Maintenance Areas – Major NSR/Minor (offsetting only) [R307-403] NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirements Alternative site analysis, Major source ownership compliance certification Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406] Visibility impact analysis, Class I area impact N/A Note: The Division of Air Quality will not accept documents containing confidential information or data. Documents containing confidential information will be returned to the Source submitting the application. 1 of 1 Form 2 Date ____________ Company Information/Notice of Intent (NOI) Utah Division of Air Quality New Source Review Section Application for: Initial Approval Order Approval Order Modification General Owner and Source Information 1.Company name and mailing address: ____________________________ ____________________________ ____________________________ Phone No.: ( ) Fax No.: ( ) 2. Company** contact for environmental matters: ____________________________ Phone no.: ( ) Email:_______________________ ** Company contact only; consultant or independent contractor contact information can be provided in a cover letter 3. Source name and physical address (if different from above):____________________________ ____________________________ ____________________________ Phone no.: ( ) Fax no.: ( ) 4. Source Property Universal Transverse Mercator coordinates (UTM), including System and Datum: UTM:_________________________ X:____________________________ Y:____________________________ 5. The Source is located in:__________________ County 6.Standard Industrial Classification Code (SIC) __ __ __ __ 7. If request for modification, AO# to be modified: DAQE #__________________ DATED: ____/____/____ 8. Brief (50 words or less) description of process. Electronic NOI 9. A complete and accurate electronic NOI submitted to DAQ Permitting Mangers Jon Black (jlblack@utah.gov) or Alan Humpherys (ahumpherys@utah.gov) can expedite review process. Please mark application type. Hard Copy Submittal Electronic Copy Submittal Authorization/Signature I hereby certify that the information and data submitted in and with this application is completely true, accurate and complete, based on reasonable inquiry made by me and to the best of my knowledge and belief. Signature: Title: _______________________________________ Name (Type or print) Telephone Number: ( ) Email: Date: Maintenance Manager (435)469-2459 thomask@christensenarms.com 10/18/2024 Thomas Kubota Page 1 of 1 Form 4 Company____________________________ Project Information Site ______________________________ Utah Division of Air Quality New Source Review Section Process Data -For Modification/Amendment ONLY 1. Permit Number_______________________________ If submitting a new permit, then use Form 3 Requested Changes 2. Name of process to be modified/added: _______________________________ End product of this process: _______________________________ 3. Permit Change Type: New Increase* Equipment Process Condition Change ____________________ Other ______________________________ Other ______________________________ Other ______________________________ 4. Does new emission unit affect existing permitted process limits? Yes No 5. Condition(s) Changing: 6. Description of Permit/Process Change** 7. New or modified materials and quantities used in process. ** Material Quantity Annually 8. New or modified process emitting units ** Emitting Unit(s)Capacity(s)Manufacture Date(s) *If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. **If additional space is required, please generate a document to accommodate and attach to form. Page 1 of 1 Form 4 Company____________________________ Project Information Site ______________________________ Utah Division of Air Quality New Source Review Section Process Data -For Modification/Amendment ONLY 1. Permit Number_______________________________ If submitting a new permit, then use Form 3 Requested Changes 2. Name of process to be modified/added: _______________________________ End product of this process: _______________________________ 3. Permit Change Type: New Increase* Equipment Process Condition Change ____________________ Other ______________________________ Other ______________________________ Other ______________________________ 4. Does new emission unit affect existing permitted process limits? Yes No 5. Condition(s) Changing: 6. Description of Permit/Process Change** 7. New or modified materials and quantities used in process. ** Material Quantity Annually 8. New or modified process emitting units ** Emitting Unit(s)Capacity(s)Manufacture Date(s) *If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. **If additional space is required, please generate a document to accommodate and attach to form. Page 1 of 1 Form 4 Company____________________________ Project Information Site ______________________________ Utah Division of Air Quality New Source Review Section Process Data -For Modification/Amendment ONLY 1. Permit Number_______________________________ If submitting a new permit, then use Form 3 Requested Changes 2. Name of process to be modified/added: _______________________________ End product of this process: _______________________________ 3. Permit Change Type: New Increase* Equipment Process Condition Change ____________________ Other ______________________________ Other ______________________________ Other ______________________________ 4. Does new emission unit affect existing permitted process limits? Yes No 5. Condition(s) Changing: 6. Description of Permit/Process Change** 7. New or modified materials and quantities used in process. ** Material Quantity Annually 8. New or modified process emitting units ** Emitting Unit(s)Capacity(s)Manufacture Date(s) *If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. **If additional space is required, please generate a document to accommodate and attach to form. two (2) Page 1 of 1 Company___________________________ 6LWH_____________________________ Form  Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants**(**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed See calculations Christensen Arms Gunnison, Utah Christensen Arms NOI AO 8/641 2/26/21 Utah Division of Air Quality New Source Review Section Company_____________________________ Site/Source___________________________ Form 13 Date ________________________________ Spray Booths Exhaust Gas Stream Characteristics 1. Flow Rate (acfm) Design maximum _________ Average expected _________ 2. Exhaust Stack Temperature (oF) __________ Height (ft) __________ Diameter (ft) __________ Vertically restricted? □ Yes □No 3. Control Device Particulate Loading (lb/hr) Inlet _______ Outlet ________ Type of Coating and Maximum Rate of Use 4. Type Max. rate of use (lb/hr) Max. rate of use (ton/yr) Volatile portion (% weight) lacquer varnish enamel metal primer metal spray resin sealer shellac stain zinc chromate epoxy polyurethane other ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ Solvent or Coating Composition and Rate of Use 5. Chemical composition of volatiles & wt. % _____________________________________ _____________________________________ _____________________________________ _____________________________________ _____________________________________ 6. Max. rate of use (lb/hr) __________________________ __________________________ __________________________ __________________________ __________________________ 7. Max rate of use (ton/yr) _________________________ _________________________ _________________________ _________________________ _________________________ Page 1 of 2 Christensen Arms See calculations See calculations ambient 2 9.5 1,000 cfm Spray Booth 3 Page 2 of 2 Form 13 - Spray Booths (Continued) Type Control Device 8. Type of pollution control device: □ spray chamber (use gal/hr water) __________ □ water curtain (use gal/hr water) __________ □ dry filter pads (no.) __________ (size) _____X_____ □ other (explain) □ automated replacement □ manual replacement 9. Method of spraying: 10. _______% overspray 11. ______% efficiency □ air atomization □ disc □ airless electrostatic □ airless □ air-atomized □ powdered □ other (describe) 12. Description of items to be coated (shape and size) Emissions Calculations (PTE) 13. Calculated emissions for this device: PM10 ___________Lbs/hr___________ Tons/yr PM2.5 ___________Lbs/hr___________ Tons/yr VOC ___________Lbs/hr___________ Tons/yr HAPs___________Lbs/hr (speciate)____________Tons/yr (speciate) Submit calculations as an appendix. Attach the following: (1) Material Safety Data Sheet for each coating or solvent. (2) An assembly drawing (plan and elevation) of the device dimensioned and to scale clearly showing the design size and shape. (3) Provide sheets showing VOC emission calculations and HAP specifications. Instructions NOTE: 1. Submit this form in conjunction with Form 1 and Form 2. 2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this form. Ask to speak with a New Source Review engineer. We will be glad to help! 1. The design maximum and average flow rate of the exhaust gas stream. 2. Exhaust stack temperature, stack height, stack diameter, and whether or not the flow is vertically restricted. 3. The amount of particulate released in the paint booth and exhaust gas in pounds per hour. 4. The type of coatings and maximum amount used in an hour and a year. 5. Chemical composition of VOCs and weight in percentage. 6. Maximum rate of use in pounds per hour. 7. Maximum rate of use in tons per year. 8. The type of control equipment you are using. 9. The method of spraying. Mark appropriate box. 10. The percent of paint that is lost in overspray. 11. The percent of efficiency for the equipment. 12. The approximate shape and size of the items being coated. 13. Supply calculations for all criteria pollutants and HAPs. Use AP42 or Manufacturers data to complete your calculations. U:\aq\ENGINEER\GENERIC\Forms 2010\Form13 Paint Booths.doc Revised 12/20/10 HVLP See calculations 85 Utah Division of Air Quality New Source Review Section Company_____________________________ Site/Source___________________________ Form 13 Date ________________________________ Spray Booths Exhaust Gas Stream Characteristics 1. Flow Rate (acfm) Design maximum _________ Average expected _________ 2. Exhaust Stack Temperature (oF) __________ Height (ft) __________ Diameter (ft) __________ Vertically restricted? □ Yes □No 3. Control Device Particulate Loading (lb/hr) Inlet _______ Outlet ________ Type of Coating and Maximum Rate of Use 4. Type Max. rate of use (lb/hr) Max. rate of use (ton/yr) Volatile portion (% weight) lacquer varnish enamel metal primer metal spray resin sealer shellac stain zinc chromate epoxy polyurethane other ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ ______________________ Solvent or Coating Composition and Rate of Use 5. Chemical composition of volatiles & wt. % _____________________________________ _____________________________________ _____________________________________ _____________________________________ _____________________________________ 6. Max. rate of use (lb/hr) __________________________ __________________________ __________________________ __________________________ __________________________ 7. Max rate of use (ton/yr) _________________________ _________________________ _________________________ _________________________ _________________________ Page 1 of 2 Christensen Arms Spray Booth 4 ambient 17 2 See calculations See calculations ,00 cfm Page 2 of 2 Form 13 - Spray Booths (Continued) Type Control Device 8. Type of pollution control device: □ spray chamber (use gal/hr water) __________ □ water curtain (use gal/hr water) __________ □ dry filter pads (no.) __________ (size) _____X_____ □ other (explain) □ automated replacement □ manual replacement 9. Method of spraying: 10. _______% overspray 11. ______% efficiency □ air atomization □ disc □ airless electrostatic □ airless □ air-atomized □ powdered □ other (describe) 12. Description of items to be coated (shape and size) Emissions Calculations (PTE) 13. Calculated emissions for this device: PM10 ___________Lbs/hr___________ Tons/yr PM2.5 ___________Lbs/hr___________ Tons/yr VOC ___________Lbs/hr___________ Tons/yr HAPs___________Lbs/hr (speciate)____________Tons/yr (speciate) Submit calculations as an appendix. Attach the following: (1) Material Safety Data Sheet for each coating or solvent. (2) An assembly drawing (plan and elevation) of the device dimensioned and to scale clearly showing the design size and shape. (3) Provide sheets showing VOC emission calculations and HAP specifications. Instructions NOTE: 1. Submit this form in conjunction with Form 1 and Form 2. 2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this form. Ask to speak with a New Source Review engineer. We will be glad to help! 1. The design maximum and average flow rate of the exhaust gas stream. 2. Exhaust stack temperature, stack height, stack diameter, and whether or not the flow is vertically restricted. 3. The amount of particulate released in the paint booth and exhaust gas in pounds per hour. 4. The type of coatings and maximum amount used in an hour and a year. 5. Chemical composition of VOCs and weight in percentage. 6. Maximum rate of use in pounds per hour. 7. Maximum rate of use in tons per year. 8. The type of control equipment you are using. 9. The method of spraying. Mark appropriate box. 10. The percent of paint that is lost in overspray. 11. The percent of efficiency for the equipment. 12. The approximate shape and size of the items being coated. 13. Supply calculations for all criteria pollutants and HAPs. Use AP42 or Manufacturers data to complete your calculations. U:\aq\ENGINEER\GENERIC\Forms 2010\Form13 Paint Booths.doc Revised 12/20/10 15 HVLP See calculations Utah Division of Air Quality New Source Review Section Company ________________________________ Site/Source ___________ Form 6 Date ____________________________________ Cyclones Equipment Information 1. Manufacturer: _____________________________ Model no.: ___________________ 2. Type of cyclone: □ wet □ dry □ Single □ Multiple: number ________ □ In series : number ___________ 3. Type of particulate: ___________________________ Particulate size: ________________________microns (mean geometric diameter) 4. Efficiency of cyclone: At design maximum:______________________% At average operation: % 5. Pressure drop through cyclone (inches water): 6. Method of handling material removed: Gas Stream Characteristics 7. Particulate grain loading: Inlet: __________________________ Outlet: _________________________ 8. Total flow rate (acfm): Design maximum: ________________________ Average expected: ________________________ 9. Gas stream temperature (oF): Emissions Calculations (PTE) 10. Calculated emissions for this device PM10 ____________Lbs/hr___________ Tons/yr PM2.5 _____________Lbs/hr_____________ Tons/yr Submit calculations as an appendix. Instructions NOTE: 1. Submit this form in conjunction with Form 1 and Form 2. 2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this form. Ask to speak with a New Source Review engineer. We will be glad to help! 1. Fill in the cyclone manufacturer's name and model number. 2. Indicate the type of cyclone being used. 3. Supply what the material is being controlled, and its mean geometric diameter in microns (μ). 4. Fill in the efficiency of the cyclone at the maximum and average operating levels. 5. Indicate the pressure drop through the cyclone (inches water). 6. Describe the method of handling the material removed by the cyclone. 7. Indicate the gas stream particulate grain loading at inlet and outlet. 8. Specify the flow rate in actual cubic feet per minute at the design maximum and average. 9. Specify the gas stream temperature as it goes through the cyclone. 10. Supply calculations for all criteria pollutants. Use AP42 or Manufacturers data to complete your calculations.   U:\aq\ENGINEER\GENERIC\Form 2010\Form06.doc Revised 12/20/2010 Christensen Arms Blasting Dust Collector 2 See calculations Mac2Flo 3m2f24 10,000 Utah Division of Air Quality New Source Review Section Company ________________________________ Site/Source ___________ Form 6 Date ____________________________________ Cyclones Equipment Information 1. Manufacturer: _____________________________ Model no.: ___________________ 2. Type of cyclone: □ wet □ dry □ Single □ Multiple: number ________ □ In series : number ___________ 3. Type of particulate: ___________________________ Particulate size: ________________________microns (mean geometric diameter) 4. Efficiency of cyclone: At design maximum:______________________% At average operation: % 5. Pressure drop through cyclone (inches water): 6. Method of handling material removed: Gas Stream Characteristics 7. Particulate grain loading: Inlet: __________________________ Outlet: _________________________ 8. Total flow rate (acfm): Design maximum: ________________________ Average expected: ________________________ 9. Gas stream temperature (oF): Emissions Calculations (PTE) 10. Calculated emissions for this device PM10 ____________Lbs/hr___________ Tons/yr PM2.5 _____________Lbs/hr_____________ Tons/yr Submit calculations as an appendix. Instructions NOTE: 1. Submit this form in conjunction with Form 1 and Form 2. 2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this form. Ask to speak with a New Source Review engineer. We will be glad to help! 1. Fill in the cyclone manufacturer's name and model number. 2. Indicate the type of cyclone being used. 3. Supply what the material is being controlled, and its mean geometric diameter in microns (μ). 4. Fill in the efficiency of the cyclone at the maximum and average operating levels. 5. Indicate the pressure drop through the cyclone (inches water). 6. Describe the method of handling the material removed by the cyclone. 7. Indicate the gas stream particulate grain loading at inlet and outlet. 8. Specify the flow rate in actual cubic feet per minute at the design maximum and average. 9. Specify the gas stream temperature as it goes through the cyclone. 10. Supply calculations for all criteria pollutants. Use AP42 or Manufacturers data to complete your calculations.   U:\aq\ENGINEER\GENERIC\Form 2010\Form06.doc Revised 12/20/2010 Christensen Arms United Air Specialist C-3620-1D 7000 See calculations Blasting Dust Collector 3 AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX B Process Flow Diagram, Site Layout, and Area Map DATE:PROJECT NO.2/17/2021 Figure 1 General Process Flow Diagram Christensen Arms Gunnison, Utah 206470 Bar Stock Machining Electric Oven Contour (Machining) PM Dust Resin Application VOC Sanding/ Abrasive Blasting PM Dust Paint Booth PM, VOC, HAPs MERV 8 Stack A Assembly/ Adhesive VOC Range/ Testing PM, CO, NOx, Lead Legend: Material Flow Emissions Flow 2/17/2021 Page 1 of 1 2:21 PMChristensen Arms NOI AO 16/641 2/26/21 AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX C Emission Calculations Christensen Arms Gunnison, UT Emissions Summary Actual Emissions Emission Source VOC (tpy) PM (tpy) PM10 (tpy) PM2.5 (tpy) NOx (tpy) CO (tpy) Combined HAP (tpy) Maximum Single HAP (tpy) Hydroquinone 123-31-9 (tpy) Hexane 110-54-3 (tpy) Cumene 98-82-8 (tpy) Lead (tpy) Xylene 1330-20-7 (tpy) Hexamethyl ene-1,6- diisocyanat e 822-06-0 (tpy) Ethyl Benzene 100-41-4 (tpy) Styrene 100-42-5 (tpy) Toluene 108-88-3 (tpy) Methyl isobutyl ketone (Hexone) 108-10-1 (tpy) 2,4- Toluene diisocyana te 584-84-9 (tpy) Phenol 108-95-2 (tpy) Methyl Alcohol 67-56-1 (tpy) Copper (tpy) Chromium (tpy) Manganese (tpy) Nickel (tpy) Solvent Use 0.03Mold Release 0.09Epoxy Resin 0.03Lubricant Usage 0.38Adhesive0.66 1.46E-03 3.51E-06 1.35E-03 1.03E-04 Paint[1]4.77 1.18E-01 1.18E-01 1.18E-01 3.28 1.53 0.74 0.02 0.51 1.53 0.24 0.10 1.26E-03 0.15 0.00E+00 Blasting [1]4.25E-09 4.25E-09 4.25E-09 Welding[1]1.77E-05 1.77E-05 1.77E-05 4.63E-08 2.08E-09 2.60E-08 1.04E-08 7.80E-09 Metal Machining 4.38E-06 2.50E-06 2.50E-06Combustion0.04 6.06E-02 6.06E-02 6.06E-02 0.80 0.67 0.02 1.43E-02Range2.73E-03 2.60E-03 1.84E-03 1.30E-03 9.53E-02 1.59E-04 1.59E-04Total6.01 0.18 0.18 0.18 7.98E-01 7.65E-01 3.30 1.53 3.51E-06 1.35E-03 1.03E-04 1.59E-04 0.74 0.02 0.51 1.53 0.24 0.10 1.26E-03 0.15 0.00E+00 2.08E-09 2.60E-08 1.04E-08 7.80E-09 Potential Emissions Emission Source VOC (tpy)PM(tpy) PM10(tpy) PM2.5(tpy)NOx(tpy)CO(tpy) Combined HAP(tpy) Maximum Single HAP(tpy) Hydroquinone 123-31-9(tpy) Hexane 110-54-3(tpy) Cumene 98-82-8(tpy)Lead (tpy) Xylene 1330-20-7(tpy) Hexamethylene-1,6- diisocyanate 822-06-0(tpy) Ethyl Benzene 100-41-4(tpy) Styrene 100-42-5(tpy) Toluene 108-88-3(tpy) Methyl isobutyl ketone (Hexone) 108-10-1(tpy) 2,4-Toluene diisocyanate 584-84-9(tpy) Phenol 108-95-2(tpy) Methyl Alcohol 67-56-1(tpy)Copper(tpy)Chromium(tpy)Manganese(tpy)Nickel(tpy) Solvent Use 0.05 Mold Release 0.18 Epoxy Resin 0.05Lubricant Usage 0.72Adhesive1.24 2.74E-03 6.56E-06 2.54E-03 1.93E-04Paint[1]8.93 0.22 0.22 0.22 6.15 2.86 1.39 0.04 0.95 2.86 0.45 0.19 2.35E-03 0.28 0.00E+00Blasting [1]2.98E-05 2.98E-05 2.98E-05 Welding[1]3.31E-05 3.31E-05 3.31E-05 8.66E-08 3.89E-09 4.87E-08 1.95E-08 1.46E-08 Metal Machining 0.00 0.00 0.00 Combustion 0.06 0.09 0.09 0.09 1.12 0.94 0.02 2.01E-02 Range 0.01 4.88E-03 3.45E-03 2.44E-03 1.78E-01 2.97E-04 2.97E-04 Total 11.22 0.31 0.31 0.31 1.12 1.12 6.17 2.86 6.56E-06 2.54E-03 1.93E-04 2.97E-04 1.39 0.04 0.95 2.86 0.45 0.19 2.35E-03 0.28 0.00E+00 3.89E-09 4.87E-08 1.95E-08 1.46E-08 [1]In lieu of data available to specidate emissions, PM10 and PM2.5 emissions conservatively estimted to equal PM emissions. HAPs HAPs rpsgroup.com Project Number:206470 Christensen Arms Gunnison, UT Abrasive Blasting PTEhr/day day/wk wk/yr hr/yr hr/yr1855246808760 Materials units (gals, cans, Liters, etc.)Size UOM Typical Annual Usage (Containers) Annual Usage (lbs) Usage (lb/hr) Usage (lb/day) Usage (tpy) MSC (Glass Bead)50 lbs 50 lbs 83 4150 0.89 15.96 2.08 MSC (Aluminum Oxide)50 lbs 50 lbs 19 950 0.20 3.65 0.48MSC (Silicon Carbide)50 lbs 50 lbs 24 1200 0.26 4.62 0.60 Total 6300 1.35 24.23 3.15 Emission Factor lb/1000 lb Abrasive Blasting1 27 1AP-42 Table 13.2.6-1 PM Factors for Abrasive Blasting - Sand blasting of mild steel value at 5 mph wind speed Control Factor Efficiency2 99.99% 2 Efficiency based on manufacturer provided documentation Actual, Controlled Emissions lb/hr lb/day lb/yr tpyAbrasive Blasting 3.63E-06 0.0001 8.50E-06 4.25E-09 Potential, Controlled Emissions lb./hr lb/day lb/yr tpyAbrasive Blasting 6.80E-06 1.63E-04 0.06 2.98E-05 Based on 8760 hr/yr Potential, Uncontrolled Emissions lb./hr lb/day lb/yr tpy Abrasive Blasting 0.07 1.63 595.97 0.30 Based on 8760 hr/yr Emission Unit PM Emission Unit PM Actual Hours Materials PM Materials PM Use outdoor factor since indoor not available: for wind at 5 mph is 27 lb/1000lb; wind at 10 mph is 55 lb/1000lb; wind at 15 mph is 91 lb/1000lb rpsgroup.com Project Number:206470 Christensen Arms Gunnison, UT Solvent Use Hours of Operation Hours per Day Days per Week Weeks Per Year Hours per Year Maximum Hours per Year 18 5 52 4680 8760 Solvent Characteristics Manufacturer Product Specific Gravity Density(lb/gallon)VOC(%)VOC(lb/gallon) Methanol 67-56-1% Methanol 67-56-1lb/gallon NA Acetone 0.79 6.59 100%6.59Barnescr-10[1]1.10 9.17 100%9.17HoppesNo. 9 gun oil 0.87 7.22 3%0.22 Lucas Bore solvent[1][2]0.84 6.99 100%6.99Hoppesno 9 bore cleaner[2]0.84 7.04 71%5.00 5 0.351948SHER WILL FINISH 1™ Wash Solvent 0.82 6.83 51%3.52 SHER WILL MAK Methyl Amyl Ketone R6K30 0.81 6.75 100%6.75 STAR META AquaVantage® 515 NF / FORMULA 515 NF 1.09 9.09 1%0.13 STAR META COMMAND CLEAN HEAVY-DUTY WATER-BASED DEGREASER 1.00 8.34 3%0.21 [1] Conservative VOC content used in lieu of product specific data Solvent Usage Manufacturer Product units (gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage Yearly Usage (gallons)NA Acetone 55 gallons 55 gallons 1 75 4125 Barnes cr-10[1]8 oz 8 oz 0 87 5.44 Hoppes No. 9 gun oil 2.25 oz 2.25 oz 0 60 1.05LucasBore solvent[1][2] Hoppes no 9 bore cleaner[2] SHER WILL FINISH 1™ Wash SolventSHER WILL MAK Methyl Amyl Ketone R6K30 STAR META AquaVantage® 515 NF / FORMULA 515 NFSTAR META COMMAND CLEAN HEAVY-DUTY WATER-BASED DEGREASER[2]Usage data not provided Actual Emissions Manufacturer Product VOC(lbs/year)VOC (tpy) Methanol 67-56-1(lb/year) Methanol 67-56-1(tpy) NA Acetone 27,177.98 13.59 0 0.00Barnescr-10[1]49.88 0.02 0 0.00HoppesNo. 9 gun oil 0.23 0.00 0 0.00 Lucas Bore solvent[1][2]0.00 0.00 0 0.00Hoppesno 9 bore cleaner[2]0.00 0.00 0 0.00SHER WILL FINISH 1™ Wash Solvent 0.00 0.00 0 0.00 SHER WILL MAK Methyl Amyl Ketone R6K30 0.00 0.00 0 0.00STAR META AquaVantage® 515 NF / FORMULA 0.00 0.00 0 0.00STAR META COMMAND CLEAN HEAVY-DUTY W 0.00 0.00 0 0.00 Total 50.11 0.03 0.00 0.00 Potential Emissions Manufacturer Product VOC (lbs/year) VOC (tpy) Methanol 67-56-1 (lb/year) Methanol 67-56-1 (tpy)NA Acetone 50,871.59 25.44 0 0Barnescr-10[1]93.37 0.05 0 0 Hoppes No. 9 gun oil 0.43 0.00 0 0LucasBore solvent[1][2]0.00 0.00 0 0Hoppesno 9 bore cleaner[2]0.00 0.00 0 0 SHER WILL FINISH 1™ Wash Solvent 0.00 0.00 0 0 SHER WILL MAK Methyl Amyl Ketone R6K30 0.00 0.00 0 0 STAR META AquaVantage® 515 NF / FORMULA 0.00 0.00 0 0 STAR META COMMAND CLEAN HEAVY-DUTY W 0.00 0.00 0 0 Total 93.80 0.05 0.00 0.00 rpsgroup.com Project Number:206470 Christensen Arms Gunnison, UT Mold Release Hours of Operation Hours per Day Days per Week Weeks Per Year Hours per Year Maximum Hours per Year1855246808760 Mold Release Characteristics Manufacturer Product Specific Gravity Density(lb/gallon)VOC(%)VOC(lb/gallon) Utah Foam Maverix DHSR-2[2] MSC/Comp One Mono-Coat 0.77 6.4218 98.54 6.32804172 zyvax Water Shield 1 8.34 0 0 [1] Conservative SG and VOC content used in lieu of product specific data [2]SDS not provided. To be updated. Mold Release Usage Manufacturer Product units (gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage Yearly Usage (gallons) Utah Foam Maverix DHSR-2[2]Buckets 5 gallon 1 46 230 MSC/Comp One Mono-Coat 5 gallon pail 5 gallon 1 6 30 zyvax Water Shield gallon 1 gallon 1 373 373 Actual Emissions Manufacturer Product VOC (lbs/year) VOC (tpy)Utah Foam Maverix DHSR-2[2]0.00 0.00MSC/Comp One Mono-Coat 189.84 0.09zyvaxWater Shield 0.00 0.00 Total 189.84 0.09 Potential Emissions Manufacturer Product VOC (lbs/year) VOC (tpy)Utah Foam Maverix DHSR-2[2]0.00 0.00 MSC/Comp One Mono-Coat 355.34 0.18zyvaxWater Shield 0.00 0.00 Total 355.34 0.18 rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTEpoxy/Resin Usage Hours of Operation Hours per Day Days per Week Weeks Per Year Hours per Year Maximum Hours per Year1855246808760 Epoxy Resin Characteristics Manufacturer Product SDS Name Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon) COMP ONE EXPANDING FOAM HP-8212 PART A POLYETHER POLYOL, HP 8212 A, ETECO.pd 1.23 9 0 0.00 0.00 COMP ONE EXPANDING FOAM HP-8212 PART B POLYETHER POLYOL, HP 8212 B, ETECO.pdf 1.12 8.8 0 0.00 0.00 COMP ONE RHINO LINER 1384 RESIN EPOXY RESIN, 1384 RESIN 'A', REV 3-30-2015.pdf 0.55 4.59 0 0.00 0.00 COMP ONE PRO SET EPOXY LAM-224-HARDENER[1] Pro-Set, Epoxy Hardener, LAM-224.pdf 1.00 8.34 1.13 1.06 0.10 COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1] Pro-Set, Epoxy Resin, LAM-145.pdf 1.17 9.75 1.13 1.06 0.10 COMP ONE RHINO LINER 1391R-1 RESIN RHINO LININGS, EPOXY RESIN, 1391R-1, 3-30-15.pdf 1.16 9.7 0 0.00 0.00 COMP ONE EPOXY/RESIN PART A[2] API-334-3 PART A EPOXY RESIN, API (APPLIED POLERAMIC, INC.).pd 1.14 9.51 22.79 2.00 0.19 COMP ONE EPOXY/RESIN HARDENER PART B[2] API-334-3 PART B EPOXY HARDENER, API (APPLIED POLERAMIC, INC.).pd 0.92 7.67 18.39 2.00 0.15 COMP ONE RHINO LINER 3136R-3 HARDNER RHINO LININGS, EPOXY HARDENER, 3136R-2, REV 3-26-15.pd 1.00 8.34 0.00 0.00 0 COMP ONE RHINO LINGER 3184 HARDNER RHINO LININGS, RHINO 3184 EPOXY HARDENER, REV 03-30-2015.pdf 1.00 8.34 0 0.00 0.00[1]VOC represents a combination of 3 parts resin, 1 part hardener. [2] Based on a conversation with the manufacturer, VOC is expected to be extremely low if present. In lieu of specific data a conservative estimate of 2% used. Paint Usage Manufacturer Product units (gals, cans, Liters, etc.)Yearly Usage Maximum Yearly Actual Usage Potential Yearly UsageCOMP ONE EXPANDING FOAM HP-8212 PART A lbs 17,338.50 17,338.50 32,454.12COMP ONE EXPANDING FOAM HP-8212 PART B LBS 15,582.15 15,582.15 29,166.59COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]LBS 29,321.48 29,321.48 54,883.80COMP ONE RHINO LINER 1384 RESIN LBS 494.16 494.16 924.97COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]LBS 1,708.89 1,708.89 3,198.69COMP ONE RHINO LINER 1391R-1 RESIN LBS 39,074.13 39,074.13 73,138.76COMP ONE EPOXY/RESIN PART A[2]LBS 1,117.53 1,117.53 2,091.79COMP ONE EPOXY/RESIN HARDENER PART B[2]LBS 227.91 227.91 426.60COMP ONE RHINO LINER 3136R-3 HARDNER LBS 661.40 661.40 1,238.01COMP ONE RHINO LINGER 3184 HARDNER LBS 8,372.07 8,372.07 15,670.80 Actual Emissions Manufacturer Product VOC(lbs/year)VOC (tpy) COMP ONE EXPANDING FOAM HP-8212 PART A 0.00 0.00COMP ONE EXPANDING FOAM HP-8212 PART B 0.00 0.00COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]0.00 0.00COMP ONE RHINO LINER 1384 RESIN 5.26 0.00COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]18.18 0.01COMP ONE RHINO LINER 1391R-1 RESIN 0.00 0.00COMP ONE EPOXY/RESIN PART A[2]22.35 0.01COMP ONE EPOXY/RESIN HARDENER PART B[2]4.56 0.00COMP ONE RHINO LINER 3136R-3 HARDNER 0.00 0.00COMP ONE RHINO LINGER 3184 HARDNER 0.00 0.00Total50.35 0.03 Potential Emissions Manufacturer Product VOC(lbs/year)VOC (tpy)COMP ONE EXPANDING FOAM HP-8212 PART A 0.00 0.00COMP ONE EXPANDING FOAM HP-8212 PART B 0.00 0.00COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]0.00 0.00COMP ONE RHINO LINER 1384 RESIN 9.84 0.00COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]34.04 0.02COMP ONE RHINO LINER 1391R-1 RESIN 0.00 0.00COMP ONE EPOXY/RESIN PART A[2]41.84 0.02COMP ONE EPOXY/RESIN HARDENER PART B[2]8.53 0.00COMP ONE RHINO LINER 3136R-3 HARDNER 0.00 0.00COMP ONE RHINO LINGER 3184 HARDNER 0.00 0.00Total94.25 0.05 rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTLubricant Usage Hours of Operation Hours per Day Days per Week Weeks Per Year Hours per Year Maximum Hours per Year1855246808760 Lubricant Characteristics Manufacturer Product SDS Name Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon) Star Metal WALPRODRWBB-005 Prodraw BB_sds (1)1.15 9.59 7.19 0.63 0.06 Star Metal QCM335XCOL-005 (Coolant)QCM 335 1.06 8.81 51.73 4.90 0.43 Star Metal BOSUNI150-055 (R&O Turbine Unilube)BOS UNILUBE 150 0.89 7.42 Star Metal QCM251CXCUT-055 QUALIC.XTREME_ CUT_251C.SDS_US .English 0.96 8.01 41.8 4.36 0.35Star Metal BOSUNI032-005 (R&O Turbine Unilube)BOS UNILUBE 32 0.89 7.42 Star Metal QCM740LMDR-055 QUALIC.MET-DRILL_740L.SDS_U S.English 0.88 7.34 13 1.48 0.11 Star Metal BOSSPIN10-005 sds BOS SPIN 0.89 7.42Star Metal BOSHYD046-005 (Hydraulic oil)BOS HYD AW46 0.87 7.26Star Metal BOSWAY2-055 (2 Way oil)sds BO Way 2 0.89 7.42 Star Metal COMHDCLN-005 (Degreaser)[2]SDS COM HD 1.00 8.35 25 2.50 0.21 Star Metal BOSGEA220-005 BOS GEAR 220 0.89 7.42 Star Metal BOSGEA150-005 BOS GEAR 150 0.89 7.42WD-40 WD-40 WD-40 AEROSOL 0.82 6.84 412 50.28 3.44 WD-40 WD-40 wd-40 gallon (MSDS)0.82 6.84 204 24.89 1.70 [1]Conservative VOC used in lieu of product specific data[2]As applied VOC used. VOC in bottle = 75 g/L Lubricant Usage Manufacturer Product units(gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage Yearly Usage(gallons)Star Metal WALPRODRWBB-005 5 Gal 5 gallon 1 5 25.00Star Metal QCM335XCOL-005 (Coolant)5 Gal 5 gallon 1 4 20.00Star Metal BOSUNI150-055 (R&O Turbine Unilube)55 Gal 55 gallon 1 14 770.00 Star Metal QCM251CXCUT-055 55 Gal 55 gallon 1 20 1100.00 Star Metal BOSUNI032-005 (R&O Turbine Unilube)5 Gal 5 gallon 1 15 75.00Star Metal QCM740LMDR-055 55 Gal 55 gallon 1 42 2310.00Star Metal BOSSPIN10-005 5 Gal 5 gallon 1 3 15.00Star Metal BOSHYD046-005 (Hydraulic oil)5 Gal 5 gallon 1 3 15.00 Star Metal BOSWAY2-055 (2 Way oil)55 Gal 55 gallon 1 4 220.00 Star Metal COMHDCLN-005 (Degreaser)[2]5 Gal 5 gallon 1 4 20.00Star Metal BOSGEA220-005 5 Gal 5 gallon 1 1 5.00Star Metal BOSGEA150-005 5 Gal 5 gallon 1 1 5.00WD-40 WD-40 11oz 11 oz 0 211 18.13281WD-40 WD-40 gallon 1 gallon 1 32 32 Actual Emissions Manufacturer Product VOC(lbs/year)VOC (tpy)Star Metal WALPRODRWBB-005 1.50 0.00Star Metal QCM335XCOL-005 (Coolant)8.63 0.00Star Metal BOSUNI150-055 (R&O Turbine Unilube)0.00 0.00Star Metal QCM251CXCUT-055 383.72 0.19Star Metal BOSUNI032-005 (R&O Turbine Unilube)0.00 0.00Star Metal QCM740LMDR-055 250.61 0.13Star Metal BOSSPIN10-005 0.00 0.00Star Metal BOSHYD046-005 (Hydraulic oil)0.00 0.00 Star Metal BOSWAY2-055 (2 Way oil)0.00 0.00Star Metal COMHDCLN-005 (Degreaser)[2]4.17 0.00Star Metal BOSGEA220-005 0.00 0.00Star Metal BOSGEA150-005 0.00 0.00WD-40 WD-40 62.35 0.03WD-40 WD-40 54.48 0.03 Total 765.47 0.38 Potential Emissions Manufacturer Product VOC(lbs/year)VOC (tpy)Star Metal WALPRODRWBB-005 2.81 0.00Star Metal QCM335XCOL-005 (Coolant)16.16 0.01 Star Metal BOSUNI150-055 (R&O Turbine Unilube)0.00 0.00Star Metal QCM251CXCUT-055 718.25 0.36Star Metal BOSUNI032-005 (R&O Turbine Unilube)0.00 0.00Star Metal QCM740LMDR-055 469.10 0.23Star Metal BOSSPIN10-005 0.00 0.00Star Metal BOSHYD046-005 (Hydraulic oil)0.00 0.00 Star Metal BOSWAY2-055 (2 Way oil)0.00 0.00Star Metal COMHDCLN-005 (Degreaser)[2]7.81 0.00Star Metal BOSGEA220-005 0.00 0.00Star Metal BOSGEA150-005 0.00 0.00WD-40 WD-40 116.70 0.06WD-40 WD-40 101.97 0.05 Total 1432.80 0.72 rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTAdhesive Usage Hours of Operation Hours per Day Days per Week Weeks Per Year Hours per Year Maximum Hours per Year1855246808760 Adhesive Characteristics Manufacturer Product SDS Name Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon) Hydroquinone123-31-9(%) Hydroquinone123-31-9(lb/gallon) Hexane110-54-3(%) Hexane110-54-3(lb/gallon) Cumene98-82-8(%) Cumene98-82-8(lb/gallon) 3m Super 77 Spray Adhesive 3m super 77 spray adhesive 0.73 6.05484 458.00 63.13 3.82 0.5 0.0302742pacerRX-50 pacer rx-50 sds 1.06 8.8404 20 1.89 0.17 0.1 0.01 devcon 5 minute epoxy DEVCON 5 MINUTE EPOXY AMBER 1-1 1.17 9.7578 0 0.00 0.00 vettec bovi-bond[1] bovi-bond-block-adhesive-46130-part-a-sds 1.20 10.008 1,199.22 100.00 10.01 pacer accelerator[1]ACETONE ACCELERATOR 0.80 6.672 799.48 100.00 6.67 Engineered Bonding SolutiFibertack[1] ENGINEERED BONDING SOLUTIONS, FIBERTACK MT-1, ADHESIVE, 6-16-2016 0.90 7.54 903.49 100.00 7.54 Loctite Blue BLUE LOCTITE 242 1.10 9.174 6.17 0.56 0.05 1 0.09174 Loctite Red RED LOCTITE 277 1.10 9.174 7.13 0.65 0.06 1 0.09174[1]Conservative VOC used in lieu of product specific data Adhesive Usage Manufacturer Product units (gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage Yearly Usage(gallons)3m Super 77 Spray Adhesive 16.75oz 16.75 oz 7.81E-03 684 89.51pacerRX-50 0.7oz 0.7 oz 7.81E-03 145 0.79devcon5 minute epoxy 50ml 50 ml 2.64E-04 2855 37.71vettecbovi-bond[1]166cc 166 cc 2.64E-04 1279 56.09paceraccelerator[1]2oz 2 oz 7.81E-03 154 2.41Engineered Bonding SoluFibertack[1]12oz 12 oz 7.81E-03 576 54.00LoctiteBlue250ml250ml2.64E-04 23 1.52LoctiteRed250ml250ml2.64E-04 11 0.73 Actual Emissions Manufacturer Product VOC(lbs/year)VOC (tpy) Hydroquinone123-31-9(lb/year) Hydroquinone123-31-9(tpy) Hexane110-54-3(lb/year) Hexane110-54-3(tpy) Cumene98-82-8(lb/year) Cumene98-82-8(tpy) 3m Super 77 Spray Adhesive 342.12 0.17 0 0 2.71 1.35E-03 0 0.00pacerRX-50 0.13 0.00 0.01 3.51E-06 0 0.00 0 0.00devcon5 minute epoxy 0.00 0.00 0 0.00 0 0.00 0 0.00vettecbovi-bond[1]561.32 0.28 0 0.00 0 0.00 0 0.00paceraccelerator[1]16.05 0.01 0 0.00 0 0.00 0 0.00Engineered Bonding SoluFibertack[1]407.16 0.20 0 0.00 0 0.00 0 0.00LoctiteBlue0.08 0.00 0 0.00 0 0.00 0.14 6.97E-05LoctiteRed0.04 0.00 0 0.00 0 0.00 0.07 3.33E-05Total1326.91 0.66 0.01 3.51E-06 2.71 1.35E-03 0.21 1.03E-04 Potential Emissions Manufacturer Product VOC(lbs/year)VOC (tpy) Hydroquinone123-31-9(lb/year) Hydroquinone123-31-9(tpy) Hexane110-54-3(lb/year) Hexane110-54-3(tpy) Cumene98-82-8(lb/year) Cumene98-82-8(tpy)3m Super 77 Spray Adhesive 640.37 0.32 0 0 5.07 2.54E-03 0 0pacerRX-50 0.25 0.00 0.01 6.56E-06 0 0 0 0devcon5 minute epoxy 0.00 0.00 0 0 0 0 0 0vettecbovi-bond[1]1,050.68 0.53 0 0 0 0 0 0paceraccelerator[1]30.05 0.02 0 0 0 0 0 0Engineered Bonding SoluFibertack[1]762.12 0.38 0 0 0 0 0 0LoctiteBlue0.15 0.00 0 0 0 0 0.26 1.30E-04LoctiteRed0.08 0.00 0 0 0 0 0.12 6.237E-05Total2483.70 1.24 0.01 6.56E-06 5.07 2.54E-03 0.39 1.93E-04 rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTPaint Usage Hours of Operation Hours per Day Days per Week Weeks Per Year Hours per Year Maximum Hours per Year1855246808760 Paint Characteristics Manufacturer Product SDS Name Application Method Transfer Efficiency4 Dropout Rate4 Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon) PM Solid Content (%) PM(lb/gallon) Xylene1330-20-7(%) Xylene1330-20-7(lb/gallon) Hexamethylene-1,6- diisocyanate822-06-0(%) Hexamethylene-1,6-diisocya nate822-06-0(lb/gallon) Ethyl Benzene100-41-4(%) Ethyl Benzene100-41-4(lb/gallon) Styrene100-42-5(%) Styrene100-42-5(lb/gallon) Toluene108-88-3(%) Toluene108-88-3(lb/gallon) Methyl isobutyl ketone (Hexone)108-10-1(%) Methyl isobutyl ketone (Hexone)108-10-1(lb/gallon) 2,4-Toluene diisocyanate 584-84-9(%) 2,4-Toluene diisocya nate 584-84-9(lb/gallon) Phenol108-95-2(%) Phenol108-95-2(lb/gallon) Methyl Alcohol67-56-1(%) Methyl Alcohol67-56-1(lb/gallon) SHERWIN WILLIAMS PAINT BLACK FLAT BLACK PAINT Spray 15.00%90.00%1.10 9.16 605 55.10 5.05 44.90 4.11 2 0.18 0.00 0.5 0.05 0.00 7 0.64 0.00 0.00 0.00 0.00 SHERWIN WILLIAMS K69 POLANE REDUCER k69 Spray 15.00%90.00%7.04 844 100.00 7.04 0.00 0.00 52 3.66 0.00 9 0.63 0.00 15 1.06 24 1.69 0.3 0.02 0.00 0.00SHERWIN WILLIAMS V66V27 CATALYST v66v27 Spray 15.00%90.00%1.15 9.57 459 40.00 3.83 60.00 5.74 0.00 0.00 0.00 0.00 0.00 0.00 0.00 32 3.06 0.00 NIC CERAKOTE[2] H-SERIES PART B NIC.pdf Spray 15.00%90.00%1.08 9.01554 0 0.00 0.00 100.00 9.02 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NCS VTK 34-20001 2K URETHANE PRIMER Vietek 34-200 SDS Spray 15.00%90.00%1.42 11.84 491 34.63 4.10 65.37 7.74 12 1.42 0.00 3 0.36 0.00 0.00 0.00 0.00 0.00 0.00NCSVTK 34-20204 ACTIVATOR Vietek 34-202 SDS Spray 15.00%90.00%0.96 8.01 635 66.17 5.30 33.83 2.71 24 1.92 0.00 6.1 0.49 0.00 7 0.56 0.00 0.00 0.00 0.00 NCS UPO714 DOLPHIN GLAZE Upol UP0714 SDS Spread with blade 100.00%0 1.21 10.0914 220 18.19 1.84 81.81 8.26 0.00 0.00 5 0.50 23 2.32 0.00 0.00 0.00 0.00 0.00 NCS 8984 GENERAL ADHESIVE REMOVER 3M (TM) ADHESIVE REMOVER Spray or wipe 15.00%90.00%0.84 7.0056 840 100.00 7.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NCS FIV 5186 FAST ACTIVATOR 4. 4 XTREME 4. 4 VOC FAST ACTIVATOR Spray 15.00%90.00%1.00 8.34 469.82 47.00 3.92 53.00 4.42 0.35 0.03 1 0.08 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NCS FIV 5185 X-TREME 4.4 VOC CLEAR 4. 4 XTREME FLAT FINISH KLEAR KOTE Spray 15.00%90.00%0.93 7.7562 543.81 58.53 4.54 41.47 3.22 0.00 13.1807 1.02 2.94 0.23 0.1622 0.01 0.00 0.00 0.00 0.00 0.00 NCS FIV 5165 ORIGINAL HARDENER Five Star 5165 SDS Spray 15.00%90.00%0.93 7.74 355 38.24 2.96 61.76 4.78 25 1.94 0.00 3 0.23 0.3 0.02 0.3 0.02 0.00 0.00 0.00 0.00 Sherwin Williams Garden Gate Green GARDEN GATE GREEN PAINT Spray 15.00%90.00%1.16 9.64 650 56.30 5.43 43.70 4.21 3 0.29 0.00 1 0.10 0.00 3 0.29 0.00 0.00 0.00 0.00 Sherwin WIlliams Grizzly Grey GRIZZLE GREY PAINT Spray 15.00%90.00%1.18 9.88 640 54.10 5.35 45.90 4.53 2.5 0.25 0.00 1 0.10 0.00 2.9 0.29 0.00 0.00 0.00 0.00 Sherwin Williams portobello Tan PORTOBELLO TAN PAINT Spray 15.00%90.00%1.24 10.32 627 50.70 5.23 49.30 5.09 2.5 0.26 0.00 1 0.10 0.00 3 0.31 0.00 0.00 0.00 0.00 surfin Ni-Black 40 Spray 15.00%90.00%100.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 adtech p-17 P-17 Spread with blade 100.00%0 1.59 13.2606 252 15.86 2.10 84.14 11.16 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1 0.13 hardener black PEROXIDE CREAM HARDENER Spread with blade 100.00%0 1.33 11.0922 252 0.00 0.00 100.00 11.09 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 hardener blue PEROXIDE CREAM HARDENER Spread with blade 100.00%0 1.33 11.0922 252 0.00 0.00 100.00 11.09 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 [1]Conservative VOC used in lieu of product specific data [2]Conservative SG used in lieu of product specific data [3] Usage not provided[4] Transfer Efficieny and Dropout rate based on TCEQ quidance Paint Usage Manufacturer Product units(gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage Yearly Usage (gallons) SHERWIN WILLIAMS PAINT BLACK Gal 1 gallon 1 326 326.00 SHERWIN WILLIAMS K69 POLANE REDUCER Gal 1 gallon 1 119 119.00SHERWIN WILLIAMS V66V27 CATALYST Gal 1 gallon 1 97 97.00 NIC CERAKOTE[2]QTS 1 quart 0.25 129 32.25 NCS VTK 34-20001 2K URETHANE PRIMER Gal 1 gallon 1 463 463.00NCSVTK 34-20204 ACTIVATOR Quart 1 quart 0.25 484 121.00 NCS UPO714 DOLPHIN GLAZE 440ml 440 ml 2.64E-04 11325 1316.36 NCS 8984 GENERAL ADHESIVE REMOVER Quart 1 quart 0.25 74 18.50NCSFIV 5186 FAST ACTIVATOR Quart 1 quart 0.25 53 13.25NCSFIV 5185 X-TREME 4.4 VOC CLEAR Gal 1 gallon 1 37 37.00 NCS FIV 5165 ORIGINAL HARDENER Gal 1 gallon 1 15 15.00Sherwin Williams Garden Gate Green Gal 1 gallon 1 168 168.00Sherwin WIlliams Grizzly Grey Gal 1 gallon 1 41 41.00 Sherwin Williams portobello Tan Gal 1 gallon 1 40 40.00surfinNi-Black 40 gal 1 gallon 1 3 3.00adtechp-17 3lb can 90 0.00 0 hardener black 4 oz 4 oz 0.0078125 320 10.000hardener blue 4oz 4 oz 0.0078125 21 0.66 rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTPaint Usage Filter Specification Filter Efficiency(%)84.9 Actual, Controlled Emissions Manufacturer Product VOC (lbs/year) VOC (tpy) PM (lbs/year) PM (tpy) Xylene1330-20-7 (lb/year) Xylene1330-20-7 (tpy) Hexamet hylene-1,6-diisocyanate822-06-0 (lb/year) Hexamethylene-1,6-diisocyanate822-06-0 (tpy) Ethyl Benzene100-41-4 (lb/year) Ethyl Benzene100-41-4 (tpy) Styrene100-42-5 (lb/year) Styrene100-42-5 (tpy) Toluene108-88-3 (lb/year) Toluene108-88-3 (tpy) Methyl isobutyl ketone (Hexone)108-10-1 (lb/year) Methyl isobutyl ketone (Hexone)108-10-1 (tpy) 2,4-Toluene diisocyanate 584-84-9 (lb/year) 2,4-Toluene diisocyanate 584-84-9 (tpy) Phenol108-95-2 (lb/year) Phenol108-95-2 (tpy) Methyl Alcohol67-56-1 (lb/year) Methyl Alcohol67-56-1 (tpy) SHERWIN WILLIAMS PAINT BLACK 1645.37 0.82 17.21 0.01 59.72 0.03 0 0.00 14.9308 0.01 0 0.00 209.03 0.10 0 0.00 0 0.00 0 0.00 0 0.00SHERWIN WILLIAMS K69 POLANE REDUCER 837.76 0.42 0.00 0.00 435.64 0.22 0 0.00 75.3984 0.04 0 0.00 125.66 0.06 201.0624 0.10 2.51328 0.00 0 0.00 0 0.00 SHERWIN WILLIAMS V66V27 CATALYST 371.32 0.19 7.15 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 297.0528 0.15 0 0.00 NIC CERAKOTE[2]0.00 0.00 3.73 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 NCS VTK 34-20001 2K URETHANE PRIMER 1898.30 0.95 46.00 0.02 657.8304 0.33 0 0.00 164.4576 0.08 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSVTK 34-20204 ACTIVATOR 641.30 0.32 4.21 0.00 232.6104 0.12 0 0.00 59.12181 0.03 0 0.00 67.84 0.03 0 0.00 0 0.00 0 0.00 0 0.00NCSUPO714 DOLPHIN GLAZE 2416.82 1.21 139.48 0.07 0 0.00 0 0.00 664.1953161 0.33 3055.3 1.53 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCS8984 GENERAL ADHESIVE REMOVER 129.69 0.06 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSFIV 5186 FAST ACTIVATOR 51.94 0.03 0.75 0.00 0.39 0.00 1.10505 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSFIV 5185 X-TREME 4.4 VOC CLEAR 167.98 0.08 1.53 0.00 0 0.00 37.82589 0.02 8.43719436 0.00 0.46548 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSFIV 5165 ORIGINAL HARDENER 44.40 0.02 0.92 0.00 29.025 0.01 0 0.00 3.483 0.00 0.3483 0.00 0.35 0.00 0 0.00 0 0.00 0 0.00 0 0.00Sherwin Williams Garden Gate Green 911.79 0.46 9.08 0.00 48.59 0.02 0.00 0.00 16.20 0.01 0.00 0.00 48.59 0.02 0 0.00 0 0.00 0 0.00 0 0.00Sherwin WIlliams Grizzly Grey 219.15 0.11 2.39 0.00 10.127 0.01 0 0.00 4.0508 0.00 0 0.00 11.75 0.01 0 0.00 0 0.00 0 0.00 0 0.00Sherwin Williams portobello Tan 209.29 0.10 2.61 0.00 10.32 0.01 0 0.00 4.128 0.00 0 0.00 12.38 0.01 0 0.00 0 0.00 0 0.00 0 0.00surfinNi-Black 40 0.00 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00adtechp-17 0.00 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.000hardener black 0.00 0.00 1.42 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.000hardener blue 0.00 0.00 0.09 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00Total9545.11 4.77 236.57 0.12 1484.24 0.74 38.93 0.02 1014.40 0.51 3,056.11 1.53 475.61 0.24 201.06 0.10 2.51 1.26E-03 297.05 0.15 0.00 0.00 Potential Controlled Emissions Manufacturer Product VOC (lbs/year) VOC (tpy) PM (lbs/year) PM (tpy) Xylene 1330-20-7 (lb/year) Xylene 1330-20-7 (tpy) Hexamet hylene-1,6-diisocyanate 822-06-0 (lb/year) Hexamethylene-1,6-diisocyanate 822-06-0 (tpy) Ethyl Benzene 100-41-4 (lb/year) Ethyl Benzene 100-41-4 (tpy) Styrene 100-42-5 (lb/year) Styrene 100-42-5 (tpy) Toluene 108-88-3 (lb/year) Toluene 108-88-3 (tpy) Methyl isobutyl ketone (Hexone) 108-10-1 (lb/year) Methyl isobutyl ketone (Hexone) 108-10-1 (tpy) 2,4-Toluene diisocyanate 584-84-9 (lb/year) 2,4-Toluene diisocyanate 584-84-9 (tpy) Phenol 108-95-2 (lb/year) Phenol 108-95-2 (tpy) Methyl Alcohol 67-56-1 (lb/year) Methyl Alcohol 67-56-1 (tpy)SHERWIN WILLIAMS PAINT BLACK 3,079.80 1.54 32.21 0.02 111.79 0.06 0 0 27.95 0.01 0 0 391.26 0.20 0 0 0.00 0.00 0 0 0 0SHERWIN WILLIAMS K69 POLANE REDUCER 1,568.11 0.78 0.00 0.00 815.42 0.41 0 0 141.13 0.07 0 0 235.22 0.12 376.35 0.19 4.70 0.00 0 0 0 0SHERWIN WILLIAMS V66V27 CATALYST 695.03 0.35 13.38 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 556.02 0.28 0 0NICCERAKOTE[2]0.00 0.00 6.99 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0 NCS VTK 34-20001 2K URETHANE PRIMER 3,553.23 1.78 86.09 0.04 1,231.32 0.62 0 0 307.83 0.15 0 0 0 0 0 0 0.00 0.00 0 0 0 0 NCS VTK 34-20204 ACTIVATOR 1,200.38 0.60 7.88 0.00 435.40 0.22 0 0 110.66 0.06 0 0 126.99 0.06 0 0 0.00 0.00 0 0 0 0 NCS UPO714 DOLPHIN GLAZE 4,523.79 2.26 261.08 0.13 0 0 0 0 1,243.24 0.62 5,718.89 2.86 0 0 0 0 0.00 0.00 0 0 0 0NCS8984 GENERAL ADHESIVE REMOVER 242.75 0.12 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0NCSFIV 5186 FAST ACTIVATOR 97.22 0.05 1.41 0.00 0.72 0.00 2.07 1.03E-03 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0NCSFIV 5185 X-TREME 4.4 VOC CLEAR 314.42 0.16 2.86 0.00 0 0 70.80 0.04 15.79 0.01 0.87 0.00 0 0 0 0 0.00 0.00 0 0 0 0NCSFIV 5165 ORIGINAL HARDENER 83.11 0.04 1.72 0.00 54.33 0.03 0 0 6.52 0.00 0.65 0.00 0.65 0.00 0 0 0.00 0.00 0 0 0 0Sherwin Williams Garden Gate Green 1,706.68 0.85 17.00 0.01 90.94 0.05 0 0 30.31 0.02 0 0 90.94 0.05 0 0 0.00 0.00 0 0 0 0Sherwin WIlliams Grizzly Grey 410.20 0.21 4.47 0.00 18.96 0.01 0 0 7.58 0.00 0 0 21.99 0.01 0 0 0.00 0.00 0 0 0 0Sherwin Williams portobello Tan 391.75 0.20 4.89 0.00 19.32 0.01 0 0 7.73 0.00 0 0 23.18 0.01 0 0 0.00 0.00 0 0 0 0surfinNi-Black 40 0.00 0.00 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0adtechp-17 0.00 0.00 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00hardener black 0.00 0.00 2.66 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 00hardener blue 0.00 0.00 0.17 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0Total17866.48 8.93 442.81 0.22 2778.20 1.39 72.87 0.04 1898.75 0.95 5720.42 2.86 890.24 0.45 376.35 0.19 4.70 2.35E-03 556.02 0.28 0.00 0.00 2.04 0.00 rpsgroup.com Project Number:206470 Christensen Arms Gunnison, UT Welding Material Welding Wire Iron Copper Chromium Manganese Nickel LeadWelding Material (MSC) - RG60-063-10T 98.0%1%10%4%3%0% Midwest Tungsten Service (Amazon) - B013K 0%0%0%0%0%0% Welding Rod [1]GTAW is assumed to be similar to GMAW SDAPCD Guidance Actual Usage Welding Wire lbs / year Welding Material (MSC) - RG60-063-10T 1.00 Midwest Tungsten Service (Amazon) - B013K 1.00Welding Rod 66.00 Hours of Operation hr/day day/wk wk/yr hr/yr 18 5 52 4680 8760 Emission Factor Welding Material (MSC) - RG60-063-10T 5.2 lb/10000lbMidwest Tungsten Service (Amazon) - B013K 5.2 lb/10000lbWelding Rod 5.2 lb/10000lb [1]AP-42 Table 12.19-1; Emission factors based on welding rod use: Steel E70S GMAW (no lead) and Aluminum Note AP-42 units: PM is lb/103lb; HAPs are 10-1lb/103lb Welding - Actual Emissions Based on Worst Case Welding Rod Factors lb/hr lbs/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy Welding Material (MSC) - RG60-063-10T 1.11E-07 5.20E-04 2.60E-07 1.97778E-08 9.26E-05 4.63E-08 8.89E-10 4.16E-06 2.08E-09 1.11E-08 5.20E-05 2.60E-08 4.44E-09 2.08E-05 1.04E-08 3.33E-09 1.56E-05 7.80E-09 0.00E+00 0.000 0.00E+00Midwest Tungsten Service (Amazon) - B013K 1.11E-07 5.20E-04 2.60E-07 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.000 0.00E+00Welding Rod 7.33E-06 3.43E-02 1.72E-05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.000 0.00E+00Total7.56E-06 3.54E-02 1.77E-05 1.98E-08 9.26E-05 4.63E-08 8.89E-10 4.16E-06 2.08E-09 1.11E-08 5.20E-05 2.60E-08 4.44E-09 2.08E-05 1.04E-08 3.33E-09 1.56E-05 7.80E-09 0.00E+00 0.00E+00 0.00E+00 Welding - Potential Emissions lb/hr lbs/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpyWelding Material (MSC) - RG60-063-10T 1.11E-07 9.73E-04 4.87E-07 1.89E-08 1.73E-04 8.66E-08 8.89E-10 7.79E-06 3.89E-09 1.11E-08 9.73E-05 4.87E-08 4.44E-09 3.89E-05 1.95E-08 3.33E-09 2.92E-05 1.46E-08 0.00E+00 0.00E+00 0.00E+00 Midwest Tungsten Service (Amazon) - B013K 1.11E-07 9.73E-04 4.87E-07 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Welding Rod 7.33E-06 6.42E-02 3.21E-05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00Total7.56E-06 6.62E-02 3.31E-05 1.89E-08 1.73E-04 8.66E-08 8.89E-10 7.79E-06 3.89E-09 1.11E-08 9.73E-05 4.87E-08 4.44E-09 3.89E-05 1.95E-08 3.33E-09 2.92E-05 1.46E-08 0.00E+00 0.00E+00 0.00E+00 Based on 8760 hr/yr Copper Actual Hours Maximum Hours per Year Materials PM Total HAPs Metal Materials PM Total HAPs Metal Copper Chromium Nickel Lead Chromium Manganese Nickel Lead Manganese rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTMachining PTEhr/day day/wk wk/yr hr/yr hr/yr1855246808760 Materials Annual Purchase(lbs) Machined Quantity(lbs/year) Usage[1](lb/hr)Usage(lb/day) Machined Usage(tpy)Aluminum 30,163.70 30,164 6.45 116.01 15.08Carbon89,258.67 89,259 19.07 343.30 44.63Stainless Steel 379,651.40 379,651 81.12 1460.20 189.83Titanium1,075.22 1,075 0.23 4.14 0.54Tool Steel 140.02 140 0.03 0.54 0.07Total500,148.98 500,148.98 106.87 1,923.65 250.07 [1]Purchase total based on known weights. Emission Factor lb/ton lb/ton lb/ton Machining[2]0.35 0.2 0.2 [2] Conservative emission factor for SCC 3-07-008-02 used in liu of site specific dataSee EIIP Vol II Ch. 14 https://www.epa.gov/sites/default/files/2015-08/documents/ii14_july2001.pdf Control Factor Efficiency3 99.99%3 Efficiency based on manufacturer provided documentation Actual Controlled Emissions lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy Machining 1.87E-06 3.37E-05 0.01 4.38E-06 1.07E-06 1.92E-05 0.01 2.50E-06 1.07E-06 1.92E-05 0.01 2.50E-06 Potential Controlled Emissions lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyMachining1.87E-06 4.49E-05 0.02 8.19E-06 1.07E-06 2.56E-05 0.01 4.68E-06 1.07E-06 2.56E-05 0.01 4.68E-06 Potential Uncontrolled Emissions lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyMachining0.02 0.45 163.83 0.08 0.01 0.26 93.62 0.05 0.01 0.26 93.62 0.05 Materials PM PM10 PM2.5 PM10 PM10 PM2.5 PM2.5MaterialsPM Materials PM Actual Hours Source PM PM10 PM2.5 rpsgroup.com Project Number:206470 Christensen ArmsGunnison, UTCombustion Equipment Btu/hr MMBtu/hr MMCF/hr Water Heater 1 STATE INDUSTRIES GS6-50-BCUT 400 1 40,000 0.04 3.92E-05 Exempt - 307-401-10(2) Water Heater 2 STATE INDUSTRIES GS6-50-BCUT 400 1 40,000 0.04 3.92E-05 Exempt - 307-401-10(2) Water Heater 3 STATE INDUSTRIES GS6-50-YBRT 1 40,000 0.04 3.92E-05 Exempt - 307-401-10(2) Oven 1 GRIEVE B1H-900 1 400,000 0.40 3.92E-04 Exempt - 307-401-10(1) Oven 2 GRIEVE B1H-900 1 400,000 0.40 3.92E-04 Exempt - 307-401-10(1) Paint Booth Heater TITAN TA-120 NG VRH 1 935,900 0.94 9.18E-04 Exempt - 307-401-10(1) Shop heater 1 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2) Shop heater 2 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2) Shop heater 3 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2) Shop heater 4 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2) Shop heater 5 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2)Total 11 2,605,900 2.01 2.E-031NG CF=1020Btu Maximum Hourshr/day day/wk day/yr hr/yr hr/day day/wk day/yr hr/yr hr/yr245.0 260 6240 24 7 365 8760 8760 NGF Heater- Emission Factors VOC PM[1]PM10[1]Direct PM2.5[1]NOx CO SO2 lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scfEmission Factors 5.5 7.6 7.6 7.6 100.0 84.0 0.6 Total HAP Benzene Benzene Dichloro- benzene Formald- ehyde Hexane Toluene Lead lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scfEmission Factors 1.9 0.002 0.002 0.001 0.08 1.8 0.003 0.0005[1] PM emission factor is filterable PM only. PM10 emission factor is filterable and condensable PM10 combined.[2] Assumed most conservative NOx emissions: Flue Gas Recirculation Burners Emission Factors for NOx: Assumed NOX and N2O are not controlledEmission Factors are from AP 42, Chapter 1.4, Tables 1.4-1, 1.4-2, 1.4-3, SCC #1-02-006-02, 1-01-006-02, 1-03-006-02, and 1-03-006-03 NGF Heaters - Calculated Actual Emissions lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 1.3 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 24.5 <0.1Water Heater 2 <0.1 <0.1 1.3 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 24.5 <0.1Water Heater 3 <0.1 <0.1 1.3 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 24.5 <0.1Oven 1 <0.1 <0.1 13.5 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 0.9 244.7 0.1Oven 2 <0.1 <0.1 13.5 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 0.9 244.7 0.1Paint Booth Heater <0.1 0.1 31.5 <0.1 <0.1 0.2 43.5 <0.1 <0.1 0.2 43.5 <0.1 <0.1 0.2 43.5 <0.1 <0.1 2.2 572.6 0.3 Shop heater 1 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Shop heater 2 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Shop heater 3 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1 Shop heater 4 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Shop heater 5 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Total<0.1 0.3 87.7 <0.1 <0.1 0.5 121.2 <0.1 <0.1 0.5 121.2 <0.1 <0.1 0.5 121.2 <0.1 0.3 6.1 1,594.2 0.8[1]Actual gas usage not available; use actual = potential at 8760 hr/yr lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 20.6 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 <0.1 <0.1 <0.1 0.4 <0.1 Water Heater 2 <0.1 <0.1 20.6 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 <0.1 <0.1 <0.1 0.4 <0.1Water Heater 3 <0.1 <0.1 20.6 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 <0.1 <0.1 <0.1 0.4 <0.1Oven 1 <0.1 0.8 205.6 0.1 <0.1 <0.1 1.5 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 4.6 <0.1 <0.1 <0.1 4.4 <0.1 Oven 2 <0.1 0.8 205.6 0.1 <0.1 <0.1 1.5 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 4.6 <0.1 <0.1 <0.1 4.4 <0.1Paint Booth Heater <0.1 1.8 480.9 0.2 <0.1 <0.1 3.4 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 10.8 <0.1 <0.1 <0.1 10.3 <0.1Shop heater 1 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1 Shop heater 2 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Shop heater 3 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Shop heater 4 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Shop heater 5 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Total 0.2 5.2 1,339.1 0.7 <0.1 <0.1 9.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 30.0 <0.1 <0.1 0.1 28.7 <0.10.014348 Actual Hours Maximum Hours Equipment Manufacturer Model Number of Units Rating1 Permit Applicability? Natural Gas Emission Factors Natural Gas Emission Factors - Continued Emission Factors are from AP 42, Table 1.4-2 SCC #1-02-006-02, 1-01-006-02, 1-03-006-02, and 1-03-006-03. Natural Gas Heating Units VOC PM PM10 PM2.5 NOx Natural Gas Heating Units CO SO2 Lead Total HAPs Single HAP Christensen ArmsGunnison, UTCombustion EquipmentNGF Heaters - Potential Emissions lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 34.4 <0.1Water Heater 2 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 34.4 <0.1 Water Heater 3 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 34.4 <0.1Oven 1 <0.1 <0.1 18.9 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 0.9 343.5 0.2Oven 2 <0.1 <0.1 18.9 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 0.9 343.5 0.2 Paint Booth Heater <0.1 0.1 44.2 <0.1 <0.1 0.2 61.1 <0.1 <0.1 0.2 61.1 <0.1 <0.1 0.2 61.1 <0.1 <0.1 2.2 803.8 0.4Shop heater 1 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1Shop heater 2 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1 Shop heater 3 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1Shop heater 4 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1D7CG036N07946A<0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1Total<0.1 0.3 123.1 <0.1 <0.1 0.5 170.1 <0.1 <0.1 0.5 170.1 <0.1 <0.1 0.5 170.1 <0.1 0.3 6.1 2,238.0 1.1 lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 28.9 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 0.6 <0.1Water Heater 2 <0.1 <0.1 28.9 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 0.6 <0.1Water Heater 3 <0.1 <0.1 28.9 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 0.6 <0.1Oven 1 <0.1 0.8 288.6 0.1 <0.1 <0.1 2.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6.5 <0.1 <0.1 <0.1 6.2 <0.1Oven 2 <0.1 0.8 288.6 0.1 <0.1 <0.1 2.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6.5 <0.1 <0.1 <0.1 6.2 <0.1Paint Booth Heater <0.1 1.8 675.2 0.3 <0.1 <0.1 4.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 15.1 <0.1 <0.1 <0.1 14.5 <0.1Shop heater 1 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1 Shop heater 2 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1Shop heater 3 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1Shop heater 4 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1D7CG036N07946A<0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1Total 0.2 5.2 1,879.9 0.9 <0.1 <0.1 13.4 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 42.2 <0.1 <0.1 0.1 40.3 <0.1 NGF Heaters - Actual GHG Emissions Water Heater 1 249.6 53.06 0.001 0.0001 0.001 13 2.50E-04 2.50E-05 13Water Heater 2 249.6 54.06 0.001 0.0001 0.001 13 2.50E-04 2.50E-05 14Water Heater 3 249.6 55.06 0.001 0.0001 0.001 14 2.50E-04 2.50E-05 14Oven 1 2496 56.06 0.001 0.0001 0.001 140 2.50E-03 2.50E-04 140Oven 2 2496 57.06 0.001 0.0001 0.001 142 2.50E-03 2.50E-04 143Paint Booth Heater 5840.016 58.06 0.001 0.0001 0.001 339 5.84E-03 5.84E-04 339Shop heater 1 936 59.06 0.001 0.0001 0.001 55 9.36E-04 9.36E-05 55Shop heater 2 936 60.06 0.001 0.0001 0.001 56 9.36E-04 9.36E-05 56Shop heater 3 936 61.06 0.001 0.0001 0.001 57 9.36E-04 9.36E-05 57Shop heater 4 936 62.06 0.001 0.0001 0.001 58 9.36E-04 9.36E-05 58D7CG036N07946A93663.06 0.001 0.0001 0.001 59 9.36E-04 9.36E-05 59Total16260.816 638.66 0.01 0.00 0.01 947.66 0.02 1.63E-03 948.55 NGF Heaters - Potential GHG Emissions Water Heater 1 350.4 53.06 0.001 0.0001 0.001 19 3.50E-04 3.50E-05 19Water Heater 2 350.4 54.06 0.001 0.0001 0.001 19 3.50E-04 3.50E-05 19Water Heater 3 350.4 55.06 0.001 0.0001 0.001 19 3.50E-04 3.50E-05 19Oven 1 3504 56.06 0.001 0.0001 0.001 196 3.50E-03 3.50E-04 197Oven 2 3504 57.06 0.001 0.0001 0.001 200 3.50E-03 3.50E-04 200Paint Booth Heater 8198.484 58.06 0.001 0.0001 0.001 476 8.20E-03 8.20E-04 476Shop heater 1 1314 59.06 0.001 0.0001 0.001 78 1.31E-03 1.31E-04 78Shop heater 2 1314 60.06 0.001 0.0001 0.001 79 1.31E-03 1.31E-04 79Shop heater 3 1314 61.06 0.001 0.0001 0.001 80 1.31E-03 1.31E-04 80Shop heater 4 1314 62.06 0.001 0.0001 0.001 82 1.31E-03 1.31E-04 82D7CG036N07946A131463.06 0.001 0.0001 0.001 83 1.31E-03 1.31E-04 83Total22827.684 638.66 0.01 0.00 0.01 1,330.37 0.02 2.28E-03 1,331.62 Single HAP - Hexane Natural Gas Heating Units VOC PM PM10 PM2.5 NOx Natural Gas Heating Units CO SO2 Lead Total HAPs Natural Gas Heating Units Potential Natural Gas Usage(mmbtu/year) CO2e Emissions(metric tons) N2O Emissions(metric tons) CH4 Emissions(metric tons) CO2 Emissions(metric tons) Conversion(Metric tons/kg) N2O EF(kg CO2/mmBtu) CH4 EF(kg CO2/mmBtu) CO2 EF(kg CO2/mmBtu) Natural Gas Heating Units Potential Natural Gas Usage(mmbtu/year) CO2 EF(kg CO2/mmBtu) CH4 EF(kg CO2/mmBtu) N2O EF(kg CO2/mmBtu) Conversion(Metric tons/kg) CO2 Emissions(metric tons) CH4 Emissions(metric tons) N2O Emissions(metric tons) CO2e Emissions(metric tons) Christensen Arms Gunnison, UT Firing Range PTE hr/day day/wk wk/yr hr/yr hr/yr1855246808760 Material Usage Materials Actual Annual Purchase Actual Quantity Maximu m Quantity UOM FACTORY AMMO 60027 RNDS 60,027 112,358 rounds POWDER 26 LBS 26 49 lbsBRASS3140 EA 3,140 5,877 eachBULLETS3500 EA 3,500 6,551 each Total 63,527 118,910 Rounds Emission Factors[1] PM[2]lb/item PM2.5lb/item PM10lb/item COlb/item NOxlb/item Leadlb/item8.60E-05 5.80E-05 8.20E-05 3.00E-03 4.10E-05 5.00E-06 [1] Emission factors from Table 15.1.16-1 of AP-42 [2]TSP used in lieu of PM Actual Emissions PM lb/year PM tpy PM2.5 lb/year PM2.5 tpy PM10 lb/year PM10 tpy CO lb/year CO tpy NOx lb/year NOx tpy Lead lb/year Lead tpy5.46 0.00 3.68 1.84E-03 5.21 2.60E-03 190.58 0.10 2.60 1.30E-03 0.32 1.59E-04 Potential Emissions PM lb/year PM tpy PM2.5 lb/year PM2.5 tpy PM10 lb/year PM10 tpy CO lb/year CO tpy NOx lb/year NOx tpy Lead lb/year Lead tpy10.23 0.01 6.90 3.45E-03 9.75 4.88E-03 356.73 0.18 4.88 2.44E-03 0.59 2.97E-04 Actual Hours rpsgroup.com Project Number:206470 AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX D BACT Analysis APPROVAL ORDER MODIFICATION APPLICATION rpsgroup.com Project Number: 220197 BACT ANALYSIS The following emission sources are operated at the facility: • Solvent Use • Mold Release • Epoxy Resin • Lubricant Usage • Adhesive • Paint Booth • Blasting • Welding • Metal Machining • Range The primary emission unit at the facility are three (3) paint booths which generates particulate matter (PM) and volatile organic compound (VOC) emissions. The following sources were reviewed to identify available control technologies: • EPA's RBLC Database • EPA’s Air Pollution Technology Fact Sheets Paint Booth - VOC Step 1 – Potential Control Technologies The following control technologies were identified: • Adsorption Systems • Regenerative Thermal Oxidation (RTO) • Catalytic Oxidation (CO) • Best Management Practices Step 2 – Technical Feasibility of Control Technologies Adsorption Systems Adsorption systems direct dilute concentrations of VOC streams through an adsorption material such as activated carbon or zeolite. The material adsorbs VOC from the stream. Because VOCs can be desorbed, adsorption systems are frequently used in conjunction with VOC incinerators or concentrators. VOC adsorption systems can achieve a VOC control efficiency of 95%-98% if the VOC input concentration is between 500 and 2000 parts per million (ppm). Solids in the waste stream that may coat the carbon decrease the efficiency of the VOC removal. Carbon cannot be used for certain compounds such as ketones and aldehydes because the exothermic adsorption reaction can cause fires. Compounds with boiling points above 200°F (such as Toluene) do not adequately desorb from the carbon, causing significant capacity reduction after repeated regeneration cycles. For this reason, adsorption systems may work, but are not ideal for paint booths. APPROVAL ORDER MODIFICATION APPLICATION rpsgroup.com Project Number: 220197 Regenerative Thermal Oxidation RTO technology destroys VOC by heating the incoming VOC stream and combusting it. Typically, the gas stream is filtered through a ceramic medium which heats the gas stream to around 1500 degrees Fahrenheit. The gas stream is then directed to the combustion chamber where natural gas is used to combust the VOCs. RTOs are most efficient when used on a high volume, low VOC gas stream. Control efficiencies range from 95% to 98%. Catalytic Oxidation CO systems convert VOC to carbon dioxide and water. CO systems utilize a catalyst, allowing oxidation to occur at a temperature between 650- and 1000-degrees Fahrenheit. VOC streams are heated in a mixing chamber and/or a heat exchanger. VOC and oxygen are adsorbed onto a catalyst where oxidation occurs. The oxidation byproducts are then desorbed back in the exhaust stream. Control efficiencies range from 95% to 98% for exhaust streams with constant concentrations. Catalysts typically consist of a ceramic or metallic substrate with a thin coating of noble metal (i.e., platinum or palladium). Careful attention must be paid to gas stream constituents and properties. Wide variation in VOC content can cause temperature swings and lead to sintering of the catalyst. Due to the nature of paint booth operations, VOC concentrations are not constant, making CO systems not technically feasible. Best Management Practices Best management practices minimize emissions by instituting operational and maintenance controls. Best management practices include keeping all VOC storing containers closed when not in use. The use of a high-volume low-pressure spray gun (HVLP) reduces the amount of overspray, which reduces the amount of VOC containing material used. Step 3 – Ranking of Control Technologies Based on the efficiencies of the identified controls, the controls were ranked as follows: 1. RTO 2. Best Management Practices 3. Adsorption System 4. CO Step 4 – Evaluation of most effective controls Economic Impacts The US EPA Air Pollution Control Cost Manual provides guidance on estimating the capital and annual cost of control systems. Site specific parameters were used where possible, including the emissions rate and exhaust characteristics. Detailed cost calculations for each control can be found in the attachment to this analysis. • Adsorption System - $17,600 to $17,700 per ton of VOC • RTO - $46,500 per ton of VOC • CO - $89,500 to $94,000 per ton of VOC • Best Management Practice - $0 per metric ton APPROVAL ORDER MODIFICATION APPLICATION rpsgroup.com Project Number: 220197 Environmental Impacts Each control system has its own environmental impact, affecting the overall effectiveness of the control. Adsorption systems require the collected VOC to be desorbed and discharged to a wastewater treatment system or be handled as waste. While RTO and CO systems destroy the VOC, thereby eliminating the need to manage waste VOC, fuel is required to start and maintain the VOC destruction, resulting in additional pollutants being emitted. Step 5 – BACT Selection Because the paint booth actual VOC emissions are less than five tons per year, implementing best management practices to reduce VOC emissions is the most efficient and cost-effective control. Paint Booth - PM Step 1 – Potential Control Technologies The following control technologies were identified: • Fabric filters/ Baghouse • Dry filter • Best Management Practices While other PM controls are on the market, no other PM controls were identified for paint booths in the RBLC database. Step 2 – Technical Feasibility of Control Technologies Fabric Filters/ Baghouse Baghouses remove particulates by collecting particulates on the filter bag as the exhaust stream passes through the baghouse. Baghouses typically cannot withstand high exhaust temperatures (greater than 500 °F). Fabric filters have been considered effective for medium and low gas flow streams with high particulate concentrations. Baghouses have been shown to obtain a particulate collection efficiency up to 99.5% for PM10, and up to 99% capture for PM2.5. Dry Filter Dry filters also remove PM by directing exhaust through the filter. Particulates collect on the filter while clean air exits through the stack. Dry filters are best for low-capacity air flow compared to fabric filter use. Efficiencies vary based on the type of dry filter. The facility currently utilizes a Minimum Efficiency Reporting Values (MERV) 8 filter which has an 84.9% filter efficiency according to EPA guidance. Step 3 – Ranking of Control Technologies Based on the efficiencies of the identified controls, the controls were ranked as follows: 1. Fabric Filter/ Baghouse 2. Dry Filter APPROVAL ORDER MODIFICATION APPLICATION rpsgroup.com Project Number: 220197 Step 4 – Evaluation of most effective controls Environmental Impacts Control efficiencies impact the quantity of particulate matter emitted. Both Fabric filter and dry filter control technologies results in particulate matter waste. Economic Impacts The EPA CACT Air Pollution Technology Fact Sheets and Technical Bulletins (EPA Fact Sheets) calculates the cost effectiveness of various control technologies. The EPA Fact Sheet for HEPA filters was used to represent dry filter cost in lieu of and EPA Fact Sheet applicable to all dry filters. •Fabric Filter - $46 to $293 per metric ton •Dry Filter - $6,400 to $8,500 per sm3/s Because the facility already has a dry filter installed, there are no capital costs associated with a dry filter. Step 5 – BACT Selection The currently installed dry filter is an efficient and cost-effective control. Because the magnitude of PM emissions is well below half a ton per year, it is not cost efficient to spend additional capital expenditure to minimally reduce the total PM emissions. All Other Emission Sources – Various Pollutants The other emission sources combined represent less than three tons per year of criteria pollutants. Because each individual emission source represents a small portion of total emissions, the installation of control technology for any one source would not be a cost-effective control option. Instead, best management practices will be used to minimize emissions from each of the following sources: •Solvent Use •Mold Release •Epoxy Resin •Lubricant Usage •Adhesive •Blasting •Welding •Metal Machining •Range Best management practices include the following: •Ensuring all lids to VOC containing material are kept closed when not in use •Minimize material use and operations as possible •Train employees on material efficient practices and emissions minimization AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX E RBLC Data Base & Supporting Documentation COMPREHENSIVE REPORT Report Date:02/11/2021 Facility Information RBLC ID:IN-0310 (final)Date Determination Last Updated:02/19/2019 Corporate/Company Name:FOREST RIVER, INC., COLLEGE AVENUE COMPLEX Permit Number:039-39722-00011 Facility Name:FOREST RIVER, INC., COLLEGE AVENUE COMPLEX Permit Date:12/07/2018 (actual) Facility Contact:FRS Number:110022525739 Facility Description:Stationary custom recreational vehicle and bus manufacturing complex.SIC Code:3792 Permit Type:C: Modify process at existing facility NAICS Code:336214 Permit URL:https://permits.air.idem.in.gov/39722f.pdf EPA Region:5 COUNTRY:USA Facility County:ELKHART Facility State:IN Facility ZIP Code:46526-5022 Permit Issued By:INDIANA DEPT OF ENV MGMT, OFC OF AIR (Agency Name) MR. MATT STUCKEY(Agency Contact) (317) 233-0203 mstuckey@idem.in.gov Permit Notes: Facility-wide Emissions:Pollutant Name:Facility-wide Emissions Increase: Carbon Monoxide 6.7300 (Tons/Year) Nitrogen Oxides (NOx)8.0100 (Tons/Year) Particulate Matter (PM)204.8900 (Tons/Year) Sulfur Oxides (SOx)0.0500 (Tons/Year) Volatile Organic Compounds (VOC)1599.7300 (Tons/Year) Process/Pollutant Information PROCESS NAME:FE-16 (Plant 420) Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput:0 Process Notes: Christensen Arms AO Modification 9/7/23 POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number:VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:99.9900 TPY Emission Limit 2:6.5000 LBS/GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements: Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best management practices for VOC Est. % Efficiency: Cost Effectiveness:127704 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Process/Pollutant Information PROCESS NAME:FE-13 (Plant 3) Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput:0 Process Notes: POLLUTANT NAME:Volatile Organic Compounds (VOC) CAS Number:VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:99.9900 TPY Emission Limit 2:6.5000 LBS/GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Christensen Arms AO Modification 9/7/23 Case-by-Case Basis:BACT-PSD Other Applicable Requirements: Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best management practices for VOC Est. % Efficiency: Cost Effectiveness:127704 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Process/Pollutant Information PROCESS NAME:FE-14c (Plant 44) Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput:0 Process Notes: POLLUTANT NAME:Volatile Organic Compounds (VOC) CAS Number:VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:99.9900 TPY Emission Limit 2:6.5000 LBS/GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements: Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best management practices for VOC Est. % Efficiency: Cost Effectiveness:127704 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Christensen Arms AO Modification 9/7/23 Process/Pollutant Information PROCESS NAME:FE-14d (Plant 27) Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput:0 Process Notes: POLLUTANT NAME:Volatile Organic Compounds (VOC) CAS Number:VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:99.9900 TPY Emission Limit 2:6.5000 LBS/GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements: Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best management practices for VOC Est. % Efficiency: Cost Effectiveness:127704 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Facility Information RBLC ID:IN-0309 (final)Date Determination Last Updated:02/19/2019 Corporate/Company Name:GRAND DESIGN RV Permit Number:039-40105-00747 Facility Name:GRAND DESIGN RV Permit Date:11/30/2018 (actual) Facility Contact:FRS Number:110041067733 Christensen Arms AO Modification 9/7/23 Facility Description:Stationary travel trailers and campers facility. SIC Code:3792 Permit Type:C: Modify process at existing facility NAICS Code:336214 Permit URL:https://permits.air.idem.in.gov/40105f.pdf EPA Region:5 COUNTRY:USA Facility County:ELKHART Facility State:IN Facility ZIP Code:46540-9632 Permit Issued By:INDIANA DEPT OF ENV MGMT, OFC OF AIR (Agency Name) MR. MATT STUCKEY(Agency Contact) (317) 233-0203 mstuckey@idem.in.gov Permit Notes: Facility-wide Emissions:Pollutant Name:Facility-wide Emissions Increase: Carbon Monoxide 11.7800 (Tons/Year) Nitrogen Oxides (NOx)14.0200 (Tons/Year) Particulate Matter (PM)160.3300 (Tons/Year) Sulfur Oxides (SOx)0.0800 (Tons/Year) Volatile Organic Compounds (VOC)754.4100 (Tons/Year) Process/Pollutant Information PROCESS NAME:RV-6 Line 1 Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput:0 Process Notes: POLLUTANT NAME:Volatile Organic Compounds (VOC) CAS Number:VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:30.0000 TPY Emission Limit 2:6.5000 LBS/GALLON Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis:BACT-PSD Other Applicable Requirements: Christensen Arms AO Modification 9/7/23 Control Method:(P) Total VOC usage shall be less than 30 tpy. VOC content limit for adhesives, sealants, glue, and cleaning materials shall not exceed 6.5 lbs/gallon. Est. % Efficiency: Cost Effectiveness:504219 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Facility Information RBLC ID:OH-0371 (final) Date Determination Last Updated:06/19/2019 Corporate/Company Name:SCHLAGE LOCK COMPANY LLC Permit Number:P0122993 Facility Name:SCHLAGE LOCK COMPANY LLC Permit Date:09/26/2017 (actual) Facility Contact:MATTHEW PORTER (513)766-4639 MATTHEW.PORTER@ALLEGION.COM FRS Number:110070283008 Facility Description:Manufacturer of Steel Doors SIC Code:3442 Permit Type:C: Modify process at existing facility NAICS Code:332321 Permit URL: EPA Region:5 COUNTRY:USA Facility County:HAMILTON Facility State:OH Facility ZIP Code:45242 Permit Issued By:OHIO ENVIRONMENTAL PROTECTION AGENCY (Agency Name) MICHAEL MALESKI(Agency Contact) (614) 644-3613 Michael.Maleski@epa.ohio.gov Permit Notes:PSD major modification of Frame Flow Coater Paint Line, K013 Facility-wide Emissions: Pollutant Name:Facility-wide Emissions Increase: Volatile Organic Compounds (VOC)60.0000 (Tons/Year) Process/Pollutant Information PROCESS NAME: Door Frame Line (K013) Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput: 0 Christensen Arms AO Modification 9/7/23 Process Notes:Frame Flow Coater Paint Line for miscellaneous metal parts. Includes natural-gas fired curing oven. POLLUTANT NAME:Volatile Organic Compounds (VOC) CAS Number:VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:60.0000 T/YR PER ROLLING 12 MONTH PERIOD Emission Limit 2:3.5000 LB/GAL SEE NOTES. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(P) VOC content restrictions, VOC input limitations, and the use of a flow coater. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:SIP: The VOC content for each extreme performance coating employed in this emissions unit shall not exceed 3.5 pounds of VOC per gallon of coating, excluding water and exempt solvents, as applied. Facility Information RBLC ID:KY-0109 (final)Date Determination Last Updated:01/25/2021 Corporate/Company Name: FRITZ WINTER NORTH AMERICA, LP Permit Number: V-16-022 R1 Facility Name:FRITZ WINTER NORTH AMERICA, LP Permit Date:10/24/2016 (actual) Facility Contact:DANIEL NEW 270-813-4000 DANIEL.NEW@FRITZWINTER.US FRS Number:Not Found Facility Description:This facility consists of a gray iron foundry, casting, and machining operation that produces automotive parts in Simpson County, Kentucky. The facility comprises an approximately 95 acre site, consisting of scrap handling and preparation equipment, melt furnaces, sand and mineral storage, mixing and handling equipment, mold and core making facilities, casting equipment, and finishing facilities where castings are machined and coated. Once the planned two-phase construction is complete, the facility will be capable of producing 91,586 tons of gray iron for pouring and 3.5 million automotive brake rotors per year. SIC Code:3321 Christensen Arms AO Modification 9/7/23 Permit Type:A: New/Greenfield Facility NAICS Code:331511 Permit URL:http://dep.gateway.ky.gov/eSearch/Search_AI_Detail.aspx?AgencyID=129745 EPA Region:4 COUNTRY:USA Facility County:SIMPSON Facility State:KY Facility ZIP Code:42134 Permit Issued By:KENTUCKY DEP, DIV FOR AIR QUALITY (Agency Name) MR. RICK SHEWEKAH, MGR(Agency Contact) (502)564-3999 Sreenivas.Kesaraju@ky.gov Other Agency Contact Info: Permit Reviewer: Amy Tempus-Doom Email: Amy.Tempus-Doom@ky.gov Phone: 502-782-6786 Permit Notes:Source Agency Interest Number: 129745 Initial Activity Number: APE20160001 This permit was issued, and then revised prior to beginning construction. The RBLC entry only include the revised limits. Revision Activity Number: APE20160004 Revision issued November 25, 2017. Affected Boundaries: Boundary Type:Class 1 Area State:Boundary:Distance: CLASS1 GA Cohutta > 250 km CLASS1 NC Great Smoky Mountains NP > 250 km CLASS1 TN Joyce Kilmer-Slickrock > 250 km CLASS1 KY Mammoth Cave NP < 100 km CLASS1 MO Mingo > 250 km Facility-wide Emissions: Pollutant Name:Facility-wide Emissions Increase: Carbon Monoxide 296.8100 (Tons/Year) Nitrogen Oxides (NOx)28.7000 (Tons/Year) Particulate Matter (PM)42.7000 (Tons/Year) Sulfur Oxides (SOx)1.4900 (Tons/Year) Volatile Organic Compounds (VOC)80.7400 (Tons/Year) Process/Pollutant Information PROCESS NAME:Scrap Drying (EU03) Process Type:19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel:Natural Gas Throughput:60.12 MMscf/yr Process Notes: POLLUTANT NAME:Particulate matter, filterable (FPM) CAS Number:PM Test Method:EPA/OAR Mthd 5 Christensen Arms AO Modification 9/7/23 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0130 LB/H Emission Limit 2:0.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:NESHAP , SIP , OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The scrap drying process (EU03) will produce particulates from natural gas combustion, only. Since the dryer heats ambient air and blows it across clean scrap to evaporate any moisture, no particulate from the drying itself is expected. Emission factors used in calculating potential from this equipment are from AP-42, Chapter 1.4, for natural gas combustion. The emissions are uncontrolled and do not pass through the melt shop baghouse. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0520 LB/H Emission Limit 2:0.2300 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:NESHAP , OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures Christensen Arms AO Modification 9/7/23 Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The scrap drying process (EU03) will produce particulates from natural gas combustion, only. Since the dryer heats ambient air and blows it across clean scrap to evaporate any moisture, no particulate from the drying itself is expected. Emission factors used in calculating potential from this equipment are from AP-42, Chapter 1.4, for natural gas combustion. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0520 LB/H Emission Limit 2:0.2300 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT , NESHAP Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Christensen Arms AO Modification 9/7/23 Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The scrap drying process (EU03) will produce particulates from natural gas combustion, only. Since the dryer heats ambient air and blows it across clean scrap to evaporate any moisture, no particulate from the drying itself is expected. Emission factors used in calculating potential from this equipment are from AP-42, Chapter 1.4, for natural gas combustion. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:0.0380 LB/H Emission Limit 2:0.1700 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Potential emissions of VOC from natural gas-fueled burners are based on emission factors from AP-42, Chapter 1.4, Natural Gas Combustion. POLLUTANT NAME: Carbon Monoxide Christensen Arms AO Modification 9/7/23 CAS Number: 630-08-0 Test Method:Unspecified Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1:0.5800 LB/H Emission Limit 2:2.5200 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Potential emissions of CO from natural gas-fueled burners are based on emission factors from AP-42, Chapter 1.4, Natural Gas Combustion. Process/Pollutant Information PROCESS NAME: Foundry Operations - NG Combustion Processes [EU04, EU05, EU06, EU11, EU12, EU15, EU16, EU18, EU44, EU45, EU46, EU47, EU52) Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Natural Gas Throughput: 0 MMscf/yr Process Notes: Natural Gas Combustion Processes: Scrap Cleaning (EU04), Refractory Burners #1 & #2 (EU05 & EU06) Holding Furnaces #1 & #2 (EU11 & EU12), Pouring Furnaces #1 & #2 (EU15 & EU16), Refractory Curing Mobile Burner (EU18), Dryers #1 - #4 (EU44, EU45, EU46, & EU47), and Cooling Tunnel (EU52). Christensen Arms AO Modification 9/7/23 POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:Unspecified Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measuresChristensen Arms AO Modification 9/7/23 Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Christensen Arms AO Modification 9/7/23 Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2: Standard Emission: Christensen Arms AO Modification 9/7/23 Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Process/Pollutant Information PROCESS NAME: Pouring Station #1 & #2 (EU50 & EU51) Process Type: 81.450 (Casting & Pouring Processes) Primary Fuel: Natural Gas Throughput: 45793.00 ton gray iron/year, each Process Notes: Molds are moved to the pouring and cooling area via a conveyor where the casting takes place along one continuous line. Molds are brought to the pouring furnaces on a rail system. The furnace is tilted and the molten material flows into the mold. The extreme heat of the material contacting carbon in the mold causes volatile organic compounds (VOCs) and carbon monoxide (CO) to be generated. These gases escape through vents designed into the mold and auto ignite due to the extreme heat. Natural gas pilot burners are placed around the mold conveyor to ensure vent gases ignite and burn off pollutants. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1: Christensen Arms AO Modification 9/7/23 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) The permittee shall install two natural gas burners along the conveyor downstream of the pouring station (EU50 and EU51). These burners shall be oriented such that they ignite the vents of the mold assemblies in the event that they are not already burning. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:Unspecified Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) The permittee shall install two natural gas burners along the conveyor downstream of the pouring station (EU50 and EU51). These burners shall be oriented such that they ignite the vents of the mold assemblies in the event that they are not already burning. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Process/Pollutant Information Christensen Arms AO Modification 9/7/23 PROCESS NAME: Foundry Operation Silos (EU17, EU19, EU20, EU21, EU35A, EU35B, EU57, EU58, & EU63) Process Type: 81.490 (Other Iron Foundry Processes) Primary Fuel: Throughput: 91586.00 ton gray iron/yr Process Notes: These silos are for various foundry operations, each controlled with a bin vent filter and any limits apply to each one individually: Melt Shop Baghouse Waste Dust Silo (EU17), Mold Silica Sand Silo (EU19), Blend Silo (EU20), Bentonite Silo (EU21), Core Silica Sand Silos A & B (EU35A & EU35B), Sand Plant Waste Silo (EU57), Mold Shop Baghouse Waste Dust Silo (EU58), Fettling Baghouse Waste Dust Silo (EU63). POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0150 LB/HR Emission Limit 2:0.0670 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(A) Bin vent filter with grain loading of 0.0030 for PM. 100% capture. Est. % Efficiency:99.710 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must be certified to meet a grain loading of 0.0030 gr/dscf. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0150 LB/HR Emission Limit 2:0.0670 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Christensen Arms AO Modification 9/7/23 Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Bin vent filter with grain loading of 0.0030 for PM10. 100% capture. Est. % Efficiency:99.400 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Bin vent filter must be certified to meet a grain loading of 0.0030 for PM10. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0090 LB/HR Emission Limit 2:0.0400 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Bin vent filter with grain loading of 0.0018 for PM2.5. 100% capture. Est. % Efficiency:99.210 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must be certified to meet a grain loading of 0.0018 gr/dscf for PM2.5. Process/Pollutant Information PROCESS NAME: Shakeout Conveyor (EU53) Process Type: 81.460 (Shake Out Processes) Primary Fuel: Throughput: 91586.00 ton gray iron/yr Christensen Arms AO Modification 9/7/23 Process Notes: Once the castings solidify, the mold frames are opened and the mold enters the shakeout conveyor where the mold is broken and the castings are separated. The shakeout conveyor also breaks off the sprues left over from the casting. Sprues are created in the pathways that allow the molten material to flow into the mold. When the mold is cooled any material in the pathways solidifies, too. The sprues are broken off and magnetically collected so they can be sent back to the melt shop for use as internal scrap. Sand from the shakeout conveyor is collected and routed through a screening sieve and sand cooler where air and water cool and hydrate the sand to the desired temperature and moisture content. Most of the sand is recycled back into the green sand mixing process. Approximately 5 percent, however, must be removed to prevent build-up of left over core sand binder (resins) decomposition byproducts. Waste sand is kept in a silo until it is shipped off site for disposal. Emissions from the shakeout conveyor and the sand separation and recycling processes are vented to the sand plant baghouse (CU06) that exhausts through a stack (ST07). POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:EPA/OAR Mthd 10 Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1:1.0000 LB/TON Emission Limit 2:25.3000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Mold Vent Auto-Ignition Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:These emissions are created from incomplete combustion of gases generated during pouring of the hot iron into the mold and oxidizing the carbon in the green sand and the organic binder present in the core. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 25 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:0.0380 LB/HR Emission Limit 2:0.1700 TON/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Christensen Arms AO Modification 9/7/23 Other Applicable Requirements:OPERATING PERMIT Control Method:(P) Mold Vent Auto-Ignition Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:These emissions are created from incomplete combustion of gases generated during pouring of the hot iron into the mold and oxidizing the carbon in the green sand and the organic binder present in the core. Process/Pollutant Information PROCESS NAME: Paint Booths #1, #2, and #3 (EU68, EU69, EU70) Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput: 28.90 lb post-induction coating/hr, each Process Notes: After machining, each brake rotor is coated with zinc. The castings are heated through induction before passing through a paint booth to receive the coating, and then enter a cooling unit. All paint booths are fitted with individual filters. Each of these paint booths are equipped with electrostatic spray nozzles that achieve at least 70% transfer efficiency. POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:EPA/OAR Mthd 5 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.3630 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100% efficiency. The permittee shall use fabric filters. Est. % Efficiency:99.900 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Christensen Arms AO Modification 9/7/23 Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of post-induction coating on a rolling 12-month basis. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.3630 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100% efficiency. The permittee shall use fabric filters. Est. % Efficiency:99.900 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of post-induction coating on a rolling 12-month basis. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:EPA/OAR OTM 27 and Mthd 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.3630 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating Christensen Arms AO Modification 9/7/23 Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100% efficiency. The permittee shall used fabric filters. Est. % Efficiency:99.900 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of post-induction coating on a rolling 12-month basis. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:3.5000 LB/GAL COATING LESS WATER, EXEMPT SOLVENTS, OR BOTH Emission Limit 2:25.7000 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(P) The permittee shall, within 90 days of startup, develop and implement a work practice plan to minimize VOC emissions from the storage, mixing, and conveying of coatings, thinners, and cleaning materials used in, and waste materials generated by, all coating operations. The plan shall specify practices and procedures to ensure that, at a minimum, the following elements are implemented: i. All VOC-containing coatings, thinners, cleaning materials, and waste materials shall be stored in closed containers. ii. The risk of spills of VOC-containing coatings, thinners, cleaning materials, and waste materials shall be minimized. iii. VOC-containing coatings, thinners, cleaning materials, and waste materials shall be conveyed from one location to another in closed containers or pipes. iv. Mixing vessels which contain VOC-containing coatings and other materials shall be closed except when adding to, removing, or mixing the contents. v. Emissions of VOC shall be minimized during cleaning of storage, mixing, and conveying equipment. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of post-induction coating on a rolling 12-month basis. The permittee shall limit thinner usage to a combined 6.9 tons/yr (from EU68-EU71) of thinner on a rolling 12-month basis. Christensen Arms AO Modification 9/7/23 Process/Pollutant Information PROCESS NAME: Paint Booth #4 (EU71) Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput: 2.38 lb pre-induction coating/hr Process Notes: After machining, each brake rotor is coated with zinc. Two types of coating operations are used. Castings first enter a paint booth which applies a solids-based coating, followed by treatment in a preheater and then final induction heating to cure the coating. All paint booths are fitted with individual filters.Each of these paint booths are equipped with electrostatic spray nozzles that achieve at least 70% transfer efficiency. This paint booths is equipped with electrostatic spray nozzles that achieve at least 70% transfer efficiency. POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:EPA/OAR Mthd 5 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0160 TONS/YR 12-MONTH ROLLING Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.35 lb/lb of coating delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100% efficiency. The permittee shall use fabric filters. Est. % Efficiency:99.000 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 15.5 tons/yr of pre-induction coating on a rolling 12-month basis. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Christensen Arms AO Modification 9/7/23 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0160 TONS/YR 12-MONTH ROLLING Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.35 lb/lb of coating delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100% efficiency. The permittee shall use fabric filters. Est. % Efficiency:99.000 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 15.5 tons/yr of pre-induction coating on a rolling 12-month basis. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:EPA/OAR OTM 27 and Mthd 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.0160 TONS/YR 12-MONTH ROLLING Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.35 lb/lb of coating delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100% efficiency. The permittee shall use fabric filters. Est. % Efficiency:99.000 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 15.5 tons/yr of pre-induction coating on a rolling 12-month basis. Christensen Arms AO Modification 9/7/23 POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 24 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:3.5000 LB/GAL COATING LESS WATER, OR EXEMPT SOLVENT OR BOTH Emission Limit 2:1.9400 TONS/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(P) The permittee shall, within 90 days of startup, develop and implement a work practice plan to minimize VOC emissions from the storage, mixing, and conveying of coatings, thinners, and cleaning materials used in, and waste materials generated by, all coating operations. The plan shall specify practices and procedures to ensure that, at a minimum, the following elements are implemented: i. All VOC-containing coatings, thinners, cleaning materials, and waste materials shall be stored in closed containers. ii. The risk of spills of VOC-containing coatings, thinners, cleaning materials, and waste materials shall be minimized. iii. VOC-containing coatings, thinners, cleaning materials, and waste materials shall be conveyed from one location to another in closed containers or pipes. iv. Mixing vessels which contain VOC-containing coatings and other materials shall be closed except when adding to, removing, or mixing the contents. v. Emissions of VOC shall be minimized during cleaning of storage, mixing, and conveying equipment. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 3.87 tons/yr of pre-induction coating on a rolling 12-month basis. The permittee shall limit thinner usage to a combined 6.9 tons/yr (used in all paint booths) of thinner on a rolling 12-month basis. Process/Pollutant Information PROCESS NAME: Emergency Generators #1, #2, & #3 (EU72, EU73, & EU74) Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: Diesel Throughput: 53.60 gal/hr Christensen Arms AO Modification 9/7/23 Process Notes: Three (3) diesel fired compression ignition emergency generators that generate 750 kW each, and have a displacement of less than 30 liters per cylinder. Emissions calculated at 500 hrs/yr. POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:Unspecified Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1:2.6000 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT Emission Limit 2:3.7300 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT , MACT Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Emissions calculated at 500 hrs/yr. POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.1490 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT. Emission Limit 2:0.2980 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Christensen Arms AO Modification 9/7/23 Case-by-Case Basis:BACT-PSD Other Applicable Requirements:MACT , OPERATING PERMIT Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Emissions calculated using 500 hrs/yr. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.1490 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT. Emission Limit 2:0.2980 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:MACT , OPERATING PERMIT Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Christensen Arms AO Modification 9/7/23 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Emissions calculated at 500 hrs/yr. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.1490 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT. Emission Limit 2:0.2980 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:MACT , OPERATING PERMIT Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Emissions calculated at 500 hrs/yr. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:4.7700 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT. Christensen Arms AO Modification 9/7/23 Emission Limit 2:3.5000 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:MACT , OPERATING PERMIT Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs were implemented in the final construction. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Emissions calculated using 500 hrs/yr. Process/Pollutant Information PROCESS NAME: Gasoline Storage Tank (EU75) Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput: 2000.00 Gallon (Capacity) Process Notes: A 2,000 gallon above-ground gasoline storage tank for fueling company vehicles. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2: Standard Emission: Christensen Arms AO Modification 9/7/23 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:NSPS , OPERATING PERMIT Control Method:(P) The permittee shall not allow gasoline to be handled in a manner that would result in vapor releases to the atmosphere for extended periods of time. Measures to be taken include, but are not limited to, the following: i. Minimize gasoline spills; ii. Clean up spills as expeditiously as practicable; iii. Cover all open gasoline containers and all gasoline storage tank fill-pipes with a gasketed seal when not in use; iv. Minimize gasoline sent to open waste collection systems that collect and transport gasoline to reclamation and recycling devices, such as oil/water separators. The gasoline storage tank (EU75) shall be equipped with a permanent submerged fill pipe. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Work practice requirements only. Process/Pollutant Information PROCESS NAME: Paved Roadways (EU76) Process Type: 99.140 (Paved Roads) Primary Fuel: Throughput: 0.43 Miles (length) Process Notes: POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or as needed in the event of a spill. Est. % Efficiency:Christensen Arms AO Modification 9/7/23 Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Work practice requirements only. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or as needed in the event of a spill. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Work practice requirements only. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Unspecified Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or asChristensen Arms AO Modification 9/7/23 Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or as needed in the event of a spill. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Work practice requirements only. Process/Pollutant Information PROCESS NAME: Melt Shop Baghouse Stack (CU01/ST02) [EU02, EU04, EU07, EU08, EU09, EU10, EU11, EU12, EU15, EU16] Process Type: 81.420 (Induction Furnaces) Primary Fuel: Natural Gas Throughput: 91586.00 ton gray iron/yr Process Notes: This group consists of the following emission units: Alloy Storage (EU02), Scrap Cleaning (EU04), Induction Furnaces #1-#4 (EU07, EU08, EU09, EU10), Holding Furnaces #1 & #2 (EU11 & EU12), and Pouring Furnaces #1 & #2 (EU15 & EU16). POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:EPA/OAR Mthd 5 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:1.4200 LB/HR 3-HOUR AVERAGE Emission Limit 2:6.2000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0010 gr/dscf. Est. % Efficiency:96.340 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0010 gr/dscf. Christensen Arms AO Modification 9/7/23 POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:1.4200 LB/HR 3-HOUR AVERAGE Emission Limit 2:6.2000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0010 gr/dscf Est. % Efficiency:92.600 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0010 gr/dscf. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:EPA/OAR OTM 27 and Mthd 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.8500 LB/HR 3-HOUR AVERAGE Emission Limit 2:3.7200 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.00060 gr/dscf. Est. % Efficiency:91.030 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.00060 gr/dscf. Christensen Arms AO Modification 9/7/23 POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 25 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:0.1400 LB/HR 3-HOUR AVERAGE Emission Limit 2:0.6100 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The only contributors to this limit are EU02, EU04, EU07, EU08, EU09, EU10, EU11, EU12, EU15, and EU16. POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:EPA/OAR Mthd 10 Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1:2.1100 LB/HR 3-HOUR AVERAGE Emission Limit 2:9.2500 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The only contributors to this limit are EU02, EU04, EU07, EU08, EU09, EU10, EU11, EU12, EU15, and EU16. Christensen Arms AO Modification 9/7/23 Process/Pollutant Information PROCESS NAME: Sand Plant Baghouse Stack (CU06/ST07) [EU22, EU23, EU24, EU25, EU26, EU27, EU28, EU29, EU30, EU31, EU32, EU54, EU55, EU56, EU53] Process Type: 81.440 (Sand, Core & Mold Making Processes) Primary Fuel: Throughput: 91586.00 tons gray iron/yr Process Notes: This group consists of the following emission units: Mold Silica Sand Bin (EU22), Blend Bin (EU23), Bentonite Bin (EU24), Dust Bin (EU25), Mold Silica Sand Weigh Hopper (EU26), Blend Weigh Hopper (EU27), Dust Weigh Hopper (EU29), Green Sand Mixers #1 - #3 (EU30, EU31, & EU32), Sand Cooler (EU54), Used Mold and Core Sand Storage (EU55), Sand Screening (EU56), and the Shakeout Conveyor (EU53) POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:EPA/OAR Mthd 5 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:2.1600 LB/HR 3-HOUR AVERAGE Emission Limit 2:9.4600 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP , OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf. Est. % Efficiency:99.880 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:2.1600 LB/HR 3-HOUR AVERAGE Emission Limit 2:9.4600 TON/YR 12-MONTH ROLLING Standard Emission: Christensen Arms AO Modification 9/7/23 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse, much achieve 0.0025 gr/dscf. Est. % Efficiency:99.250 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:EPA/OAR OTM 27 and Mthd 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:1.3000 LB/HR 3-HOUR AVERAGE Emission Limit 2:5.6700 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0015 gr/dscf Est. % Efficiency:99.530 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0015 gr/dscf. Process/Pollutant Information PROCESS NAME: Pouring & Cooling Baghouse (CU08/ST09)[EU33, EU34, EU36, EU37, EU38, EU43, EU44, EU45, EU46, EU47, EU48, EU49, EU50, EU51, EU52, & EU59] Process Type: 81.450 (Casting & Pouring Processes) Primary Fuel: Throughput: 91586.00 tons gray iron/yr Christensen Arms AO Modification 9/7/23 Process Notes: This group consists of the following emission units: Mold Stamping #1 & #2 (EU33 & 34), Sand Classifier (EU36), Core Silica Sand Bin (EU37), Core Silica Sand Weigh Hopper (EU38), Core Removal (EU43), Dryers #1-#4 (EU44, EU45, EU46, EU47), Mold Assembly #1 & #2 (EU48 & EU49), Pouring #1 & #2 (EU50 & EU51), Cooling Tunnel (EU52), & Forced Air Cooler (EU59). POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:EPA/OAR Mthd 5 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:3.5400 LB/HR 3-HOUR AVERAGE Emission Limit 2:15.5000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf Est. % Efficiency:99.500 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:3.5400 LB/HR 3-HOUR AVERAGE Emission Limit 2:15.5000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf. Est. % Efficiency:98.830 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Christensen Arms AO Modification 9/7/23 Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:EPA/OAR OTM 27 and Mthd 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:2.1200 LB/HR 3-HOUR AVERAGE Emission Limit 2:9.3000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0015 gr/dscf Est. % Efficiency:98.910 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0015 gr/dscf. POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:EPA/OAR Mthd 10 Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1:128.0000 LB/HR 3-HOUR AVERAGE Emission Limit 2:235.0000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Christensen Arms AO Modification 9/7/23 Compliance Verified:Unknown Pollutant/Compliance Notes:The only contributors to this limit are EU33, EU34, EU35A, EU35B, EU36, EU37, EU38, EU43, EU44, EU45, EU46, EU47, EU48, EU49, EU50, EU51, EU52, EU59. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 25 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:20.8000 LB/HR 3-HOUR AVERAGE Emission Limit 2:39.7000 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The only contributors to this limit are EU33, EU34, EU35A, EU35B, EU36, EU37, EU38, EU43, EU44, EU45, EU46, EU47, EU48, EU49, EU50, EU51, EU52, EU59. Process/Pollutant Information PROCESS NAME: Finishing Baghouse Stack (CU11/ST12) [EU60, EU61, EU62, EU64, EU65] Process Type: 81.490 (Other Iron Foundry Processes) Primary Fuel: Throughput: 91586.00 tons gray iron/yr Process This group consists of the following emission units: Sorting (EU60), Steel Shot Blasting #1 & #2 (EU61 & EU62), Grinding #1 & #2 (EU64 & EU65). Christensen Arms AO Modification 9/7/23 Process Notes: This group consists of the following emission units: Sorting (EU60), Steel Shot Blasting #1 & #2 (EU61 & EU62), Grinding #1 & #2 (EU64 & EU65). From shake-out, the castings are sent to a forced air cooler and then sorted to remove any remaining sprues. Finishing begins when the cast parts are sent to the steel shot blasting units, where a stream of abrasive material (steel shot) is forcibly propelled in a stream against the surface of the castings under high pressure. This process removes sand and smooths the casting surface. Grinders are then used to remove any raised areas or bits of sprue left on the surface of the product. The finished castings are placed in short term storage to allow the gray iron to fully crystallize and reach its desired structure before being sent to the final machining operation. Emissions from sorting, shot blasting, and milling are vented to the finishing baghouse (CU11) and exhausted through a stack (ST12). POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:EPA/OAR Mthd 5 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:1.3200 LB/HR 3-HOUR AVERAGE Emission Limit 2:5.7800 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - Must achieve 0.0025 gr/dscf Est. % Efficiency:99.630 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:EPA/OAR Mthd 201A and 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:1.3200 LB/HR 3-HOUR AVERAGE Emission Limit 2:5.7800 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf Christensen Arms AO Modification 9/7/23 Est. % Efficiency:96.340 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:EPA/OAR OTM 27 and Mthd 202 Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.7920 LB/HR 3-HOUR AVERAGE Emission Limit 2:3.4700 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Baghouse - must achieve 0.0015 gr/dscf Est. % Efficiency:97.800 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Must achieve 0.0015 gr/dscf Process/Pollutant Information PROCESS NAME: Core Machines #1-#4 (ST08) [EU39, EU40, EU41, EU42] Process Type: 81.440 (Sand, Core & Mold Making Processes) Primary Fuel: Throughput: 3.58 ton amine gas/yr, each Process Before the mold can be assembled, a core must be formed that is shaped to allow the hollows and voids of the brake rotor to form when the molten metal Christensen Arms AO Modification 9/7/23 Process Notes: Before the mold can be assembled, a core must be formed that is shaped to allow the hollows and voids of the brake rotor to form when the molten metal is poured into the mold. The core must be strong enough to stand up to the heat of the molten material and is formed of silica sand, resin and hardener. Core silica sand is processed through a sand classifier that sorts out fine-sized particles to ensure a uniform gain sized sand. It is then mixed with a two part phenolic resin and hardener in an enclosed mixer. This blend is sent to an automated core machine where it is shaped into the desired form and subjected to an amine gas that acts as a catalyst to accelerate curing of the resin. Hardened cores are separated from their molds and dipped into a coating that provides abrasive protection. The cores are then heated in a natural-gas fired dryer (4.0 MMBtu/hr, each) before exiting the automatic core machines. Emissions from most of the core making area, including the sand silos, sand classifier, sand bin, weigh hopper, core removal area and dryers are vented to the pouring and cooling baghouse (CU08) and then to stack (ST09). Emissions from use of the amine gas are sent through a sulfuric acid scrubber, to control odors, before exiting to the atmosphere through a stack. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 25 Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:0.7000 LB/HR 3-HOUR AVERAGE Emission Limit 2:1.6700 TON/YR 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(A) Sulfuric Acid Scrubber - controls amine gas, a VOC Est. % Efficiency:99.000 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:The core machines produce VOCs due to the use of amine gas, a mold release lubricant, and resin binders. Core machines #1–#4 (EU39–EU42) are a source of VOCs due to materials used in the process. The amine gas (vaporized dimethyl propylamine) is used as a catalyst to speed curing of the resins in the cores. The resins themselves are a source of VOC emissions as is the lubricant used to assist in mold release. Emissions from the machines are routed through a wet scrubber control which provides a 99 percent reduction of VOC emissions for the amine gases, only. The other VOCs pass through without effect. Calculations for emissions of VOC for the core machines are based on an American Foundry Society document from 2005 titled "Resin/CO2 Core and Mold making Process:Emission Characterization", Figure 11: PUCB Baseline. Process/Pollutant Information PROCESS NAME: Building Vents #1 (BV01a & b) [EU01, EU05, EU06, EU13, EU14, EU18, & uncaptured emissions from EU07, EU08, EU09, EU10, EU60, EU61, EU62, EU64, & EU65] Christensen Arms AO Modification 9/7/23 Process Type: 81.490 (Other Iron Foundry Processes) Primary Fuel: Throughput: 91586.00 tons gray iron/yr Process Notes: Some activities associated with the melt shop do not have active capture and control associated with the processes. These uncaptured emissions are released to the air within the building. In these cases the building itself provides containment and a partial barrier to emission of particulate to the outside ambient air. The pollutants, emitted by the melt shop, which do not settle out will exit the building via building vents (BV01a & BV01b). The emission group consists of the following emission units: Scrap Steel Storage (EU01), Refractory Burners #1 & #2 (EU05 & EU06), Transport Ladles #1 & #2 (EU13 & EU14), Refractory Curing Mobile Burner (EU18), and uncaptured emissions from Induction Furnaces #1-#4 (EU07, EU08, EU09, & EU10), sorting (EU60), shot blasting #1 and #2 (EU61 & EU62), and grinding (EU64 & EU65). POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:Other Other Test Method:Roof Monitor Sampling Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.7300 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:3.1800 TON/YR (COMBINED) 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:All building vent particulate emissions assume a 90 percent control for enclosure of the process within the building. POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:Other Other Test Method:Roof Monitor Sampling Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.3900 LB/HR (COMBINED) 3-HOUR AVERAGE Christensen Arms AO Modification 9/7/23 Emission Limit 2:1.7200 TON/YR (COMBINED) 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:All building vent particulate emissions assume a 90 percent control for enclosure of the process within the building. POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Other Other Test Method:Roof Monitor Sampling Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.2000 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:0.8700 TON/YR (COMBINED) 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:All building vent particulate emissions assume a 90 percent control for enclosure of the process within the building. POLLUTANT NAME: Carbon Monoxide CAS Number: 630-08-0 Test Method:Other Christensen Arms AO Modification 9/7/23 Other Test Method:Roof Monitor Sampling Pollutant Group(s):( InOrganic Compounds ) Emission Limit 1:0.0200 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:0.0700 TON/YR (COMBINED) 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Other Other Test Method:Roof Monitor Sampling Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:0.2500 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:1.0800 TON/YR (COMBINED) 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Christensen Arms AO Modification 9/7/23 Process/Pollutant Information PROCESS NAME: Building Vents #2 (BV02a & b)[EU66 & EU67] Process Type: 81.490 (Other Iron Foundry Processes) Primary Fuel: Throughput: 91586.00 tons gray iron/yr Process Notes: These building vents are associated with the machining shop and is the exit point for uncaptured emissions from those areas. The emissions are from the turning lathe (EU66) & drilling and milling (EU67). POLLUTANT NAME: Particulate matter, filterable (FPM) CAS Number: PM Test Method:Other Other Test Method:Roof Monitor Testing Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.2000 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:0.8800 TON/YR (COMBINED) 12-MONTH AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10) CAS Number: PM Test Method:Other Other Test Method:Roof Monitor Testing Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.2000 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:0.8800 TON/YR (COMBINED) 12-MONTH ROLLING Christensen Arms AO Modification 9/7/23 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5) CAS Number: PM Test Method:Other Other Test Method:Roof Monitor Testing Pollutant Group(s):( Particulate Matter (PM) ) Emission Limit 1:0.1200 LB/HR (COMBINED) 3-HOUR AVERAGE Emission Limit 2:0.5300 TON/YR (COMBINED) 12-MONTH ROLLING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes: Process/Pollutant Information PROCESS NAME: Diesel Storage Tank (EU76) Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Christensen Arms AO Modification 9/7/23 Primary Fuel: Throughput: 2000.00 gallons Process Notes: 2,000 gallon above-ground diesel storage tank POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:Unspecified Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:OPERATING PERMIT Control Method:(P) The diesel storage tank (EU76) shall be equipped with a permanent submerged fill pipe. Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:Work Practice Requirements only. Facility Information RBLC ID:WI-0257 (final) Date Determination Last Updated:07/06/2016 Corporate/Company Name:OSHKOSH CORPORATION Permit Number:11-JJW-094 Facility Name:OSHKOSH CORPORATION - MAIN PLANT Permit Date:07/21/2011 (actual) Facility Contact:SUE MURAWSKI (920) 233-9582 SMURAWSKI@DEFENSE.OSHKOSHCORP.COM FRS Number:110000497418 Facility Description:Manufacturer of heavy duty specialized trucks and transportation equipment SIC Code:3711 Permit Type:B: Add new process to existing facility NAICS Code:336120 Permit URL:http://dnr.wi.gov/cias/am/amexternal/AM_DownloadObject.aspx?id=222436 EPA Region:5 COUNTRY:USA Facility County:WINNEBAGO Christensen Arms AO Modification 9/7/23 Facility State:WI Facility ZIP Code:54903-2566 Permit Issued By:WISCONSIN DEPT OF NATURAL RESOURCES; AIR MGMT. PROGRAM (Agency Name) MS. KRISTIN HART(Agency Contact) (608)266-6876 kristin.hart@wisconsin.gov Permit Notes: Affected Boundaries: Boundary Type:Class 1 Area State:Boundary:Distance: CLASS1 WI Rainbow Lake > 250 km CLASS1 MI Seney > 250 km INTL BORDER US/Canada Border > 250 km Facility-wide Emissions: Pollutant Name:Facility-wide Emissions Increase: Carbon Monoxide 24.0000 (Tons/Year) Nitrogen Oxides (NOx)28.5000 (Tons/Year) Particulate Matter (PM)8.4500 (Tons/Year) Sulfur Oxides (SOx)0.0170 (Tons/Year) Volatile Organic Compounds (VOC)220.0000 (Tons/Year) Process/Pollutant Information PROCESS NAME: P51 - Two Electrodeposition Pretreatment Lines Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Natural Gas Throughput: 0 Process Notes: Including five make-up air units and eight bath heaters. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 24A Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements: Control Method:(N) Est. % Efficiency: Christensen Arms AO Modification 9/7/23 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per gallon. (b) The use of natural gas as a fuel for all make-up air units, bath heaters and ovens associated with these processes. (c) Limit the combined VOC emissions from all materials (including cleanup solvents) used on P51, P52, and P53 to 25,000 pounds per month, averaged over each consecutive 12 month period. POLLUTANT NAME: Visible Emissions (VE) CAS Number: VE Test Method:EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1:10.0000 PERCENT OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these processes. Process/Pollutant Information PROCESS NAME: P52 - Two Electrodeposition Primer Coating Lines Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Natural Gas Throughput: 0 Process Notes: Including two ovens. POLLUTANT NAME: Volatile Organic Compounds (VOC) Christensen Arms AO Modification 9/7/23 CAS Number: VOC Test Method:EPA/OAR Mthd 24A Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:3.5000 LBS VOC/GALLON AS APPLIED/EXCLUDING WATER Emission Limit 2:0.8000 LBS VOC/GALLON OF APPLIED COATINGS SOLIDS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:BACT-PSD Other Applicable Requirements:NESHAP , SIP Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per gallon. (b) The use of natural gas as a fuel for all make-up air units, bath heaters and ovens associated with these processes. (c) Limit the combined VOC emissions from all materials (including cleanup solvents) used on P51, P52, and P53 to 25,000 pounds per month, averaged over each consecutive 12 month period. POLLUTANT NAME: Visible Emissions (VE) CAS Number: VE Test Method:EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1:10.0000 PERCENT OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these Christensen Arms AO Modification 9/7/23 Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these processes. Process/Pollutant Information PROCESS NAME: P53 - Six Spray Booths Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Natural Gas Throughput: 0 Process Notes: Including two ovens. POLLUTANT NAME: Visible Emissions (VE) CAS Number: VE Test Method:EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1:10.0000 PERCENT OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(A) Overspray dry filters Est. % Efficiency:99.800 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Yes Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these processes. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 24A Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:3.5000 POUNDS VOC/GALLON AS APPLIED, EXCLUDING WATER Christensen Arms AO Modification 9/7/23 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per gallon. (b) the use of natural gas as a fuel for all make-up air units, bath heaters and ovens associated with these processes. (c) Limit the combined VOC emissions from all materials (including cleanup solvents) used on P51, P52, and P53 to 25,000 pounds per month, averaged over each consecutive 12 month period. (d) for Process P53, P54, and P55, the permittee may use up to 45 gallons per month, averaged over each consecutive 12 month period, of materials that exceed the applicable VOC content limit of 3.5 pounds of VOC per gallon as applied, excluding water. However, the VOC contents of these materials may not exceed the applicable VOC content limitations under ch. NR 422, Wis. Adm. Code. Process/Pollutant Information PROCESS NAME: P54 - Two Spray Booths Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput: 0 Process Notes: Including one make-up air unit. POLLUTANT NAME: Visible Emissions (VE) CAS Number: VE Test Method:EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1:10.0000 PERCENT OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Christensen Arms AO Modification 9/7/23 Other Applicable Requirements:SIP Control Method:(A) Overspray dry filters Est. % Efficiency:99.800 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Yes Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air unit associated with these processes. POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 24A Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:3.5000 LBS VOC/GALLON AS APPLIED, EXCLUDING WATER Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(N) Est. % Efficiency: Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per gallon. (b) The use of natural gas as a fuel for the make-up air unit associated with this process. (c) The permittee shall limit the combined VOC emissions from all materials (including cleanup solvents) used on processes P54A and P54B to 5,000 pounds per month each, averaged over each consecutive 12 month period. (d) For Process P53, P54, and P55, the permittee may use up to 45 gallons per month, averaged over each consecutive 12 month period, of materials that exceed the applicable VOC content limit of 3.5 pounds of VOC per gallon as applied excluding water. However, the VOC contents of these materials may not exceed the applicable VOC content limitations under ch. NR 422, Wis. Adm. Code. Process/Pollutant Information PROCESS NAME: P55 - One Spray Booth Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)Christensen Arms AO Modification 9/7/23 Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating) Primary Fuel: Throughput: 0 Process Notes: POLLUTANT NAME: Visible Emissions (VE) CAS Number: VE Test Method:EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1:10.0000 PERCENT OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(A) Overspray dry filters Est. % Efficiency:99.800 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Yes Pollutant/Compliance Notes: POLLUTANT NAME: Volatile Organic Compounds (VOC) CAS Number: VOC Test Method:EPA/OAR Mthd 24A Pollutant Group(s):( Volatile Organic Compounds (VOC) ) Emission Limit 1:3.5000 POUNDS VOC/GALLON AS APPLIED, EXCLUDING WATER Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis:BACT-PSD Other Applicable Requirements:SIP Control Method:(N) Est. % Efficiency: Christensen Arms AO Modification 9/7/23 Cost Effectiveness:0 $/ton Incremental Cost Effectiveness:0 $/ton Compliance Verified:Unknown Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per gallon. (b) The permittee shall limit the combined VOC emissions from all materials (including cleanup solvents) used on Process P55 to 1,666 pounds per month, averaged over each consecutive 12 month period. (c) for Process P53, P54, and P55, the permittee may use up to 45 gallons per month, averaged over each consecutive 12 month period, of materials that exceed the applicable VOC content limit of 3.5 pounds of VOC per gallon as applied excluding water. However, the VOC contents of these materials may not exceed the applicable VOC content limitations under ch. NR 422, Wis. Adm. Code. Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 United States Office of Air Quality EPA 456/F-99-004 Environmental Protection Planning and Standards May 1999 Agency Research Triangle Park, NC 27711 Air Christensen Arms AO Modification 9/7/23 EPA-456/F-99-004 May 1999 CATC TECHNICAL BULLETIN CHOOSING AN ADSORPTION SYSTEM FOR VOC: CARBON, ZEOLITE, OR POLYMERS? Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 Christensen Arms AO Modification 9/7/23 iii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade names or commercial products is not intended to constitute endorsement or recommendation for use. Copies of this report are available form the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Road, Springfield, Virginia 22161, telephone number (800) 553-6847. Christensen Arms AO Modification 9/7/23 iv FORWARD The Clean Air Technology Center (CATC) serves as a resource on all areas of emerging and existing air pollution prevention and control technologies, and provides public access to data and information on their use, effectiveness and cost. In addition, the CATC will provide technical support, including access to EPA’s knowledge base, to government agencies and others, as resources allow, related to the technical and economic feasibility, operation and maintenance of these technologies. Public Access and Information Transfer INTERNET / World Wide Web Home Page http://www.epa.gov/ttn/catc Communications CATC Info-Line: (919) 541-0800 (English) CATC/CICA Info-Line: (919) 541-1800 (Spanish) Toll-Free from Mexico (800) 304-1115 (Spanish) FAX: (919) 541-0242 E-Mail: catcmail@epamail.epa.gov Data Resources CC RACT/BACT/LAER Clearinghouse (RBLC) Query, view and download data you select on - Source Specific Technology Applications - Air Pollution Regulatory Requirements CC CATC PRODUCTS download technical reports, cost information and software Related Programs and Centers C CICA - U.S.-Mexico Border Information Center on Air Pollution / Centro de Información sobre Contaminación de Aire Para la Frontera entre EE.UU. Y México C SBAP - Small Business Assistance Program C International Technology Transfer Center for Global Greenhouse Gasses Christensen Arms AO Modification 9/7/23 v ACKNOWLEDGMENTS This technical bulletin was made possible through the diligent and persistent efforts of Lyndon Cox, Senior Environmental Employee with the Clean Air Technology Center (CATC). Lyndon did an exceptional job identifying information sources, gathering relative data and putting this bulletin together. The CATC also appreciates the helpful and timely comments and cooperation of the following peer reviewers: Madeleine Strum, Coating and Consumer Products Group, Emission Standards Division, Office of air Quality Planning and Standards, Office of Air and Radiation, U.S. EPA. William Vatavuk, Innovative Strategies and Economics Group, Air Strategies and Standards Division, Office of air Quality Planning and Standards, Office of Air and Radiation, U.S. EPA. Carlos Nuñez, Emissions Characterization and Prevention Branch, Air Pollution Prevention and Control Division, National Risk Management Research Laboratory, Office of Research and Development, U.S. EPA. In addition, the CATC thanks the individuals, companies and institutions who supplied information on adsorption technology used to prepare this Technical Bulletin. Contributors are indicated in the REFERENCES section of this bulletin. Christensen Arms AO Modification 9/7/23 vi TABLE OF CONTENTS TOPIC Page WHAT ARE ADSORBERS?...............................................................................................1 WHY ARE ADSORBERS IMPORTANT?..........................................................................2 HOW DOES ADSORPTION WORK?.................................................................................2 HOW ARE POLLUTANTS ADSORBED?.............................................................3 WHAT IS DESORBING?........................................................................................3 WHAT IS THE ADSORPTION ISOTHERM?........................................................4 HOW DO I PICK AN ADSORBENT?....................................................................4 ARE THERE OTHER DESIGN CONSIDERATIONS?..........................................6 MASS TRANSFER ZONE..........................................................................6 WORKING CAPACITY..............................................................................7 VAPOR PRESSURE....................................................................................8 MULTIPLE ADSORBENTS........................................................................8 ADSORPTION MODELS............................................................................8 BED FIRES..................................................................................................9 OFF-SITE ADSORBENT REGENERATION............................................9 AFFINITY....................................................................................................9 HOW CAN ADSORBERS BE REGENERATED?...........................................................10 THERMAL SWING REGENERATION...............................................................10 VACUUM REGENERATION...............................................................................11 VAPOR CONCENTRATOR.................................................................................13 PRESSURE SWING ADSORBER........................................................................15 ARE ADSORPTION SYSTEM DESIGN TOOLS AVAILABLE?...................................16 WHAT CONTROL EFFICIENCIES SHOULD YOU EXPECT TO GET?......................16 WHAT KIND OF SOURCES CAN USE ADSORPTION TECHNOLOGY?..................17 HOW MUCH DO ADSORBERS COSTS?......................................................................17 DECISIONS, DECISIONS,................................................................................................20 SOME REFERENCES.......................................................................................................22 Christensen Arms AO Modification 9/7/23 vii FIGURES 1. Molecule-Surface Distance..............................................................................................3 2. Potential Energy vs. Distance..........................................................................................3 3. Movement of MTZ with Time.........................................................................................6 4. Thermal Swing Adsorber (steam regeneration).............................................................10 5. Vacuum Regeneration Adsorber....................................................................................11 6. Cascade Vacuum Separation.........................................................................................12 7. VOC Concentrator.........................................................................................................13 8. Pressure Swing Adsorption............................................................................................15 TABLES 1. Cost of Thermal Swing (“regenerative”) Carbon Adsorption Systems.........................19 Christensen Arms AO Modification 9/7/23 1 Choosing an Adsorption System for VOC: Carbon, Zeolite, or Polymers? This paper will make you more familiar with the issues involved in choosing an adsorber system for your plant, company, or corporation. Carbon, zeolite, and polymer adsorbents have each been used to adsorb Volatile Organic Compounds (VOC) and other pollutants from relatively dilute concentrations in air (from tens to thousands of parts per million by volume) to control emissions. This paper discusses issues involved in deciding which adsorbent to use, what type of adsorption system to use, and whether it is the right emission control technology for you. WHAT ARE ADSORBERS? We are referring to adsorbers, not absorbers, because the pollutant is adsorbed on the surface (mostly the internal surface) of a granule, bead, or crystal of adsorbent material. It is not absorbed by a chemical reaction. This is an important difference. The adsorbed material is held physically, rather loosely, and can be released (desorbed) rather easily by either heat or vacuum. By contrast, an absorber reacts chemically with the substance being absorbed, and thus holds the absorbed substance much more strongly, requiring much more energy to release the absorbed substance. Unfortunately, one of the adsorbents is called “absorbent carbon.” This persisting misnomer came from the time before adsorption became understood in the 1920's. A better term is “activated carbon.” Carbon is activated by the pyrolysis of coal, wood, bark, coconut husks, etc. to remove all the volatile material as a gas or vapor, and leave only the carbon. This carbon might then also be partially oxidized to enlarge its pores. Another adsorbent is the alumino-silicate crystal structure known as “zeolite,” which has uniformly sized pores (also called windows) throughout its crystal structure. The crystal structure for the 118 established types of zeolite is determined by the ratio of silicon to aluminum in the crystal when the crystal is formed. All naturally occurring zeolite is hydrophilic (having an affinity for polar molecules, such as water) and contains aluminum. Dealuminizing natural zeolite makes it hydrophobic (having affinity for non-polar substances, such as many VOC). Zeolite is dealuminized by chemical replacement of the aluminum with silicon without changing the crystal structure. Hydrophobic zeolite can also be synthesized in crystals from 1 micron to 1 millimeter in diameter, and these can be bonded into larger granules to lower there resistance to air flow. Since synthesis is expensive, it is usually reserved for making either hydrophobic zeolite or zeolite catalysts with a specific large pore size. Polymeric adsorbents have pores built in when they are manufactured. These pores can range from macro-porous through molecular sizes, but the smallest pores are usually larger than the Christensen Arms AO Modification 9/7/23 2 micro-pores of an activated carbon. Polymers are used as granules or beads and, as the name implies, are plastics. They have been observed to desorb faster than carbon. Like carbon, they are not considered highly selective as to which VOC they will adsorb, although any specific polymer will adsorb some VOC better than others. Choosing the best adsorbent for the situation is not simple. There are several related problems which we will discuss to familiarize you with the different adsorbents and systems. WHY ARE ADSORBERS IMPORTANT? Adsorbers have been used principally to control the emission of VOC. The control of VOC emissions typically reduces the concentrations from between 400 and 2,000 parts per million (ppm) to under 50 ppm. Adsorption technology can now extend the range of VOC concentration from 20 ppm to one-fourth of the Lower Explosive Limit (LEL). At the lower end of this range, such small concentrations may be difficult or uneconomical to control by another technology or even by all adsorbents. Incinerators, membrane separators, and condensers may be economically feasible when used in place of adsorbers at the upper end of the range. In addition to emission control, the adsorber makes recovery of the VOC possible. Recovery of a reusable or marketable VOC can significantly offset the cost of emission control. Adsorbers can also increase the concentration of VOC to allow either destruction by incineration, or recovery by either membrane or condenser to be economically feasible. HOW DOES ADSORPTION WORK? The VOC are condensible vapors which appear to condense on the surface of the adsorbent. When the surface has adsorbed nearly as much as it can, the VOC is desorbed as part of regenerating the adsorbent. When desorbed, the VOC vapors are usually at a higher concentration, after which the VOC is either recovered or destroyed. One can think of all adsorbers as capturing VOC from a dilute concentration and releasing it in a higher concentration. Adsorbers can also be thought of as separating the flow of VOC from the air flow of a process. The actual concentration of the VOC is key to when and how an adsorber would be used. An adsorber becomes nearly useless when the inlet concentration gets so low that the VOC will not be effectively adsorbe, but it allows the recovery of the VOC to be at a high concentration. Safety reasons direct that VOC concentrations are held below one-fourth of the LEL. When the concentration is near one-fourth of the LEL, the VOC can be economically disposed of by an incinerator, captured by a membrane, or recovered with a condenser. However, a VOC concentration below one-fourth of the LEL is too lean to support combustion without adding auxiliary fuel. Therefore, as the VOC concentration exiting the adsorber drops below one-fourth of the LEL, more fuel must be added to give adequate combustion to the VOC in an incinerator. Christensen Arms AO Modification 9/7/23 3 potential energy x well Figure 2. Potential Energy vs. Distance x surface molecule Figure 1. Molecule-Surface Distance HOW ARE POLLUTANTS ADSORBED? Figure 1 shows a molecule above a surface, with the distance from the surface being the normal to the surface. There is a repulsion between the cloud of electrons in atoms that form the surface and those of the molecule, and there is also a Van der Waals nuclear attraction force. The nuclear attraction has a much shorter radius of influence, so there is a short distance (usually nanometers) from the surface where there is a “dip” or a “well” in the potential energy curve as shown in Figure 2. Molecules or atoms that reach this “well” are trapped or “adsorbed” by this potential energy “well” until they can obtain enough kinetic energy to fly out of the well and escape. Kinetic energy converts to potential energy, just as when you jump upward against gravity. Therefore, kinetic energy must be added to allow the molecules to escape, or desorb. Kinetic energy of molecules exhibits itself as the temperature, with hotter being more energetic. Historically, carbon was the first material to be observed to have a large amount of area with this property. Zeolite and polymer adsorbents have more recently been found to also have a large amount of internal surface area with this property. We have known for decades that before you can pull a “hard vacuum” (such as 1 micron Hg) even glass systems have to “outgas” adsorbed air. What is unique to these adsorbents is that they have such a large amount of area (mostly internal) with this property per unit of weight, and that this area can be desorbed so readily. WHAT IS DESORBING? Desorbing has been accomplished through both temperature and pressure swings. According to the kinetic theory of matter, the molecules gain kinetic energy when heated, and this allows a heated molecule to “fly” out of the well. Heat can be provided as steam, heated nitrogen, or by microwave among other techniques. For vacuum regeneration, the molecule will at some time Christensen Arms AO Modification 9/7/23 4 have sufficient energy to escape if molecular impacts do not cause it to rebound back into the well. Therefore, desorbing can be accomplished either by heating the adsorbed material or by evacuating the space over it. There is an equilibium between captured and escaping molecules. Giving the adsorbed material the kinetic energy to escape or desorb is part of the regeneration of the adsorbent. This regeneration of the adsorbent should be done before all of the absorbent has become unable to hold more, and must be done before the adsorbent can be used again. The remainder of regeneration is drying, cooling, or otherwise preparing the adsorbent to again adsorb the VOC. WHAT IS THE ADSORPTION ISOTHERM? Each adsorbent has an adsorption capacity which is referred to as the “adsorption isotherm”. Historically, with carbon, the isotherm was used to measure the pounds of pollutant per pound of adsorbent that could be adsorbed at a given temperature. However, the adsorption isotherm is also a function of pollutant concentration as measured by the partial pressure of the vapor, and it is also a function of the total ambient pressure around the adsorbent. The number of molecules that can be stored in the “well” is pressure dependent, with closer spacing of adsorbed molecules being associated with higher pressure. The adsorption isotherm is still defined as the pounds of material that can be adsorbed per pound of adsorbent. Thermal regeneration systems use the temperature isotherm; vacuum regeneration systems use the total and partial pressure isotherm; and pressure swing regeneration systems use the total ambient pressure isotherm. The “isotherm” is actually a function of all of these variables. Thus, the “isotherm” is actually a complex function that forms at least a 3-dimensional surface, rather than being either a constant or a two-dimensional plot. The isotherm can either be a linear function or a highly non-linear function depending upon the adsorbent, the pressure, and the material being adsorbed. The adsorption isotherm is also a function of the amount of adsorption area that molecules of the VOC can reach. Pores on the surface allow entry to the interior area of each of these adsorbents. The interior is where most of the adsorption area exists. Carbon has pores leading to smaller pores, which lead to even smaller pores. This apparently continues ad infinitum in carbon, and much of the internal surface area is in these micro-pores. Zeolite has uniform pores that are part of its crystal structure. Polymers have a range of pore sizes, but usually lack the very small micro- pores. Thus, the adsorption isotherm is different for each type of adsorbent and each type of pollutant. HOW DO I PICK AN ADSORBENT? There are many kinds of polymer adsorbents, many kinds of carbon adsorbents, and many kinds of zeolite adsorbents. To document all of these variations would make this paper quite a tome, and it would become a handbook rather than a concept paper. We do not intend to adequately Christensen Arms AO Modification 9/7/23 5 describe all of the variations in such detail. We can only deal with general properties and let specific selections be made by the designers and their customers with the aid of handbooks. A prime concern is the largest molecular size to be adsorbed versus the pore size of the adsorbent. This is principally a concern with zeolite, where uniform pores can be any size from 3 to 30 Dngstroms (0.3 to 3 nanometers) for different types of zeolite. Zeolite should not be expected to provide any adsorption area for molecules larger than its pores, nor for molecules for which it does not have affinity. Carbon and polymers also must have pores larger than the largest molecule to be adsorbed. However, the broad range of pore size in carbon and polymers makes this criterion less strict than it is for zeolite. The adsorption area to be reached via the pores should be excluded if the molecule to be adsorbed can neither reach it nor be desorbed from it. Regardless of the method of regeneration, the adsorption area cannot be regenerated when the adsorbed molecule jumps from a well on one side of the pore to a well on the other side of the pore. This can occur in the micro-pores of carbon and some polymers. Thus, this would prevent desorption from occurring from areas where the micro-pores get too small. The affinity of the adsorbent for some types of substances can be much greater than the affinity for others. As a result, when there is a stronger affinity for some of the molecules, the molecules having lesser affinity either get held with a smaller adsorption capacity or get released in favor of the molecules for which the affinity is greater. Carbon, which is neither fully hydrophobic or hydrophilic, retains some adsorption area with affinity for both polar and non-polar molecules. Humidity has a noticeable effect on carbon because of this. One research paper has even reported that desorbing of VOC from carbon occurs as steam condenses and the water displaces the VOC. All naturally occurring zeolite is hydrophilic, having an affinity for polar substances, such as water, but synthetic zeolite can be either hydrophilic or hydrophobic. Polymers are usually hydrophobic unless made specifically with other affinity. For example, amphophilic block copolymers can have both hydrophilic and hydrophobic affinities. Thus, the affinity has to be considered as part of selecting the particular adsorbent. Some polymers and hydrophobic zeolite are generally much less sensitive to humidity than carbons, and are also much less subject to fire, crumbling, or powdering. Therefore, they require much less frequent replacement. Carbons are cheaper (at least initially). The cost per pound of carbon is about $2.00, which is up to 20 times less than the cost per pound for either polymers or zeolite. However, the need to replace zeolite is very rare, and the replacement of polymers occurs only slightly more often. Carbon needs to be replaced every six months to five years, or when there is a bed fire. The frequency depends on the type of carbon, the frequency of regeneration, and the temperature at which it operates. Some polymeric adsorbents were evaluated by General Electric Co. for thermal desorption, and found to desorb faster than carbon, to have larger adsorption capacity in either high or low humidity after conditioning, and to desorb at lower temperatures. The maximum temperature for Christensen Arms AO Modification 9/7/23 6 in out concentration MTZ time Figure 3. Movement of MTZ with Time desorption must exceed the boiling point for the VOC, but must not exceed the polymer’s melting point. The maximum temperature for desorption is less confining for carbon, which may be taken to a much higher temperature (250E to 350EF) without melting. Carbon frequently catalyzes oxidation reactions when the temperature gets above this range. The same maximum temperature is commonly used for zeolite, but the real limit for zeolite depends on either the pyrolysis temperature, the catalyzation temperature of the adsorbed VOC, or the range of temperatures at which the crystal structure is stable for the zeolite. This metastable temperature range is generally considered to be up to about 1,000EF. ARE THERE OTHER DESIGN CONSIDERATIONS? YES! These other factors are described individually below: MASS TRANSFER ZONE The Mass Transfer Zone (MTZ), see Figure 3, exists in all adsorbents. In the MTZ, the concentration of VOC in air goes from 100% of the inlet vapor concentration to the lowest available vapor pressure in equilibrium with the desorbed adsorbent. The depth of the bed is the dimension of the adsorbent in the direction of air flow, and the MTZ is usually much shorter than the depth of the bed. The MTZ moves through the bed as the bed reaches its capacity (the absorption isotherm becomes filled). Upstream of the MTZ, the bed has reached its capacity, while downstream the bed remains essentially desorbed. Breakthrough occurs when the MTZ reaches the downstream end of the adsorption bed. Breakthrough is Christensen Arms AO Modification 9/7/23 7 observed as a rise in the VOC vapor concentration leaving the bed, which may occur at different times for different VOC. Adsorbents of all types share a characteristic with columns used in gas chromatography, for these too use adsorption. The adsorbed material will desorb spontaneously and migrate downstream with the gas flow in each system. This is caused by the pressure gradient, which is intentionally very low when adsorbers are used as an emission control technology, and rather high in the gas chromatography adsorption column. This migration of pollutants is generally slow enough that it may be neglected when emissions are being controlled. However, this property defines an absolute maximum time for adsorption before regeneration of the bed. Breakthrough is actually a gradual process because the equilibrium between the vapor pressure and the adsorbent is continuously varying. Thus, breakthrough can be defined as any noticeable rise in the effluent concentration. The MTZ will also migrate to breakthrough independent of the VOC loading. An input spike of VOC, along with the migration of the MTZ, will allow the spread of the VOC and reduce the concentration that will be desorbed at breakthrough. An example of how an adsorber might properly use the migration characteristic of the MTZ is in air flow from a hood in a plant that handles mercaptan. Natural gas is odorless and mercaptan is added to natural gas to provide an olfactory (odor) indication of a leak. If the mercaptan spill gave emissions in concentrations more than one part per billion, people would smell it, and be alarmed because they would think that there was a leak of natural gas. Therefore, hoods where mercaptan is handled are equipped with a suitably sized adsorber. This adsorber captures any vapors from spills and, when the MTZ migrates to breakthrough, the mercaptan is released at a lower concentration in this case. This is because the mercaptan was not a continuous emission, the adsorber did not reach its capacity, and therefore breakthrough occurred at a lower concentration which was below the threshold of smell. For this purpose, desorbing or regeneration is not necessary unless the spills are too frequent. WORKING CAPACITY The “conditioning cycles” are the number of cycles (often about five) that are required to achieve a stable amount of adsorption and regeneration. Carbon, after undergoing the conditioning cycles, is capable of adsorbing about 50% of the amount that was adsorbed by the virgin material. Zeolite is capable of adsorbing about 90% of the amount adsorbed by the virgin material. Polymers can vary over the range of 50% to 90%. This “conditioned isotherm” also defines the “working capacity” of the adsorbent. The fact that carbon and some polymers will typically desorb only 50% as much as the virgin material is thought to be caused by the continued recapture of molecules (i.e., depressed vapor pressure) in the micro-pores. VOC can be removed from these micro-pores only by pyrolysis, which would destroy the VOC, and either destroy the polymer or alter the properties of the carbon. Christensen Arms AO Modification 9/7/23 8 Zeolite has a uniform pore size and therefore does not exhibit this phenomenon. Polymers have an extended range of pore size, and in some respects are similar to carbons, but some polymers are thought to lack the very small micro-pores. Carbon also displays a time-related spreading of VOC from the macro-pores to the micro-pores. Zeolite and polymers show this time dependent spreading to a much less noticeable degree. The “working capacity” of the adsorbent is determined by the difference between the desorbed conditioned level and the full adsorption isotherm of the adsorbent. Thus, the conditioning effect must be considered when sizing the adsorbent bed. The conditioning effect can require up to twice as much adsorbent in the bed. Since regeneration should occur only about every 8 or 16 operating hours, the capacity of the bed(s) can be determined by the concentration of VOC, the air flow rate, the weight of adsorbent in the bed(s), the type of adsorbent, and the “working capacity” of the adsorbent. In this way, the “working capacity” can have a significant effect on the cost of installing, operating, and maintaining an adsorber. VAPOR PRESSURE Carbon and polymers have a linear adsorption isotherm relative to vapor pressure, while zeolite has a very non-linear adsorption isotherm relative to vapor pressure for the molecules it has an affinity to. This linearity makes either carbon or polymers the better adsorbent when the vapor pressure (or concentration) is higher, but the non-linearity makes zeolite the better adsorbent when the vapor pressure (or concentration) is lower. This property allows carbon or polymer adsorbent in a “sacrificial” (or first) bed followed in the air flow by a suitable zeolite in a “polishing” bed to produce the lowest vapor pressure of VOC in the outflow. The lower the partial pressure of the VOC in the outflow, the higher the control efficiency. MULTIPLE ADSORBENTS There is also an advantage to using a mixture of adsorbents. A mixture of carbon and zeolite removed mixed vapors of xylene and methanol better than an adsorbent composed of either. Hussey and Gupta of Durr Industries reported this at the Spring 1997 Meeting of American Institute of Chemical Engineers. They noted that the path through the mixture was greater than the path through either of the adsorbents when used alone, and they attributed the increased adsorption to the greater path length. However, both methanol and xylene were adsorbed, and since the authors stated that carbons adsorb xylene well while a six or eight Dngstrom pore size zeolite adsorbs methanol well, the depth would have had to be the sum of the individual bed depths to yield this result. This paper also observed that at high concentrations, carbon adsorbs better, and can be used as a “sacrificial” bed upstream of a zeolite “polishing” bed. ADSORPTION MODELS In order to know just how well the chosen adsorbent will perform, the adsorbent must be tested with the mix of pollutants that are to be adsorbed, and at the concentrations that are expected. Christensen Arms AO Modification 9/7/23 9 This must be done whether using one adsorbent alone or using a combination of adsorbents. It must also be done for a mixture of VOC vapors. Various multi-space adsorption models can predict how a combination of VOC will adsorb, but these are all based on assumptions that fit the results to the individual experiment. Examples are by V. Gusev and J. O’Brien of Yale University; and C. Jensen and N. Seaton of University of Cambridge; M. Heuchel of the University of Leipzig. The various multi-space adsorption models must be proven to apply to your mix and concentration of VOC, and the chosen adsorbent. BED FIRES All adsorption is exothermic, that means that adsorption gives off heat and causes a temperature rise. This property has been used for heat storage, but is not desirable for adsorption of VOC. Carbon or metals on the carbon have been known to catalyze the oxidation of some pollutants when the adsorbent is hot, resulting in bed fires which also consume part or all of the carbon. This is a hazard when adsorbing certain hydrocarbons (such as ketones or turpentines) at ambient temperatures that are close to those that cause the VOC to oxidize. Such a carbon bed fire can either alter the pore size of the remainder of the bed, or oxidize the bed to ash. These fires have been suppressed by humidification of the air, leaving some water in the bed after steam regeneration, and by intentional cooling of the carbon. Polymers usually are used at temperatures which do not lead to bed fires, but this must be assured. Zeolite is not flammable, but can catalyze oxidation if the temperature gets high enough. The pore size of the zeolite is not affected by temperatures that stay within the metastable range. Normally, in case of a bed fire with zeolite, only the VOC would be lost if the air flow is controlled to limit the temperature. If the temperature rises above the metastable range, the pore size of the zeolite will be reduced and the density of the zeolite will be increased. OFF-SITE ADSORBENT REGENERATION Some customers use the regeneration of the carbon off-site. For example, some “perc” dry cleaners use this technique. They replace their carbon canisters instead of regenerating them on the premises. This requires determining whether you want the bother of a boiler, fuel, and the labor charges that this entails (or else the vacuum pump and refrigerated condenser) or are willing to pay someone else to regenerate your adsorber for you. Speaking in economic terms, while remote regeneration spares you the direct expense of a boiler and its operation (or a vacuum pump and its operation) the regeneration facility will charge you a fee that will cover all costs, plus labor, collection, replacement, regeneration, disposal, and profit. This fee should be less per customer when it is spread across a customer base than when one firm must handle it alone. A shared capability would distribute the cost. However, if your adsorber loading is large enough, it should cost less to have your own regeneration capability. AFFINITY The affinity between the VOC to be adsorbed and the adsorbent must be considered. If the Christensen Arms AO Modification 9/7/23 10 adsorber adsorber boiler vapor in air out Figure 4. Thermal Swing Adsorber (steam regeneration) VOC affinity for one molecule in the flow is sufficiently greater than the affinity for another, then the adsorbent will preferentially adsorb the molecule for which it has the greater affinity, and allow transport of the other to occur at up to air flow velocity. Thus, the bed upstream of the MTZ would become saturated with the molecule for which the adsorbent had greater affinity (assuming that the pore size allowed it), while passing other molecules of lower affinity to adsorbent further through the bed and ultimately to the exhaust. As the MTZ moves through the bed, it would cause the release of the molecule with lower affinity, while adsorbing the molecules for which it has higher affinity. HOW CAN ADSORBERS BE REGENERATED? There are three methods of regeneration: Thermal Swing Regeneration, Vacuum Regeneration, and Pressure Swing Adsorption. We shall discuss these separately. THERMAL SWING REGENERATION The traditional carbon adsorber system uses steam to raise the temperature of the adsorbed VOC and boil it from a carbon adsorbent after the carbon has adsorbed the VOC. This has become known as a thermal swing regeneration adsorber system. It is so named because the temperature is usually swung between ambient and 250E to 350E F in regeneration. A thermal swing adsorber system is shown schematically in the diagram of Figure 4. Vapor in the air is transported into one adsorber (two are shown, but any larger number can be used), while the other is being regenerated. Steam flows into the adsorber being regenerated to heat the adsorbent, and thus desorb the VOC. After the VOC are desorbed, cooling air from a blower is admitted in place of the steam. When the adsorbent has cooled and dried to the extent intended, the “conditioned” adsorption capacity has been restored, and the bed is now regenerated. Christensen Arms AO Modification 9/7/23 11 adsorbervapor in air out purge gas vacuum pump adsorber Figure 5. Vacuum Regeneration Adsorber VOC Regeneration occurs in a preset time if the average VOC concentration is according to the design parameters. However, if either the air flow or the concentration vary unpredictably, a sensor should be used. A predictable air flow and concentration would allow the regeneration to occur at a given time before the breakthrough occurs. If the timer were properly set, it would avoid any breakthrough emissions. A sensor should be used to control regeneration if either the air flow or the concentration of VOC is unpredictable, or if the timer were improperly set. Prior to breakthrough, the emission concentration is actually very low, and a sensor would have to sense a concentration reading above this level to start regeneration of the adsorber bed. While some greater concentration of VOC will pass through before any regeneration occurs with a sensor, this may allow either more (by having a higher threshold) or less emissions (if the timer allowed breakthrough to happen) than using a timer. However, any increase in emissions may actually be a trivial amount when compared with the amount of the controlled emissions. Either a timer or a sensor can be suitable, if properly set and properly used. Either one can be unsuitable, if improperly set or improperly used. Thermal regeneration has historically used steam, but other heat sources have been tried successfully. These include: microwaves, embedded heaters, and heated nitrogen. These have been used with all adsorbents. Thermal regeneration becomes more practical when VOC have lower vapor pressures. VACUUM REGENERATION To enhance solvent recovery, and eliminate contamination of the VOC by steam, a vacuum regeneration system may be used. Figure 5 shows a schematic of a vacuum regeneration adsorbtion system. This uses a vacuum pump to lower the pressure in the adsorber to below the vapor pressure of the adsorbed VOC, which causes the VOC to boil off at the temperature that is ambient within the adsorbent, instead of at a higher temperature. In the process of boiling, the temperature of the adsorbent will actually go below the normal outside ambient temperature. This method can be used with carbon, polymer, and zeolite adsorbents. Christensen Arms AO Modification 9/7/23 12 adsorber 1 adsorber 2 adsorber 3 vapors in air out gas bleed in vacuum pump VOC recovery device Figure 6. Cascade Vacuum Separation Sometimes a small flow of purge gas is used to enhance transport of the VOC vapor. The VOC vapor is then recovered by separation (condensation, membrane separation, compression, or some similar process) of the flow from the vacuum pump. The purity of the recovered VOC is not affected by the vacuum, but may be affected by the mixture of the VOC vapors or the purity of the purge gas. If there are mixed VOC vapors that are being controlled, the recovered VOC will also be mixed unless the pore size or affinity of the adsorbent or the temperature of condensers separate the vapors. The purity of the purge gas is especially important when a water-soluble VOC, such as an alcohol or a ketone, is to be recovered and the purge gas contains moisture. The water vapor will be adsorbed and desorbed along with the VOC vapor, and the VOC may require subsequent purification if it is to be reused. Contamination by moisture has been avoided by using dry nitrogen as a purge gas. The recovered VOC is otherwise as pure as the VOC vapor. The desorbed VOC are sometimes purified by distillation, skimming, or membrane separation. The recovered VOC is then either recycled in the process that released it, used elsewhere in the plant, or sold. If the purity of the VOC is too low for economical recovery, or the value of the recovered solvent too low, the VOC would be destroyed in the vapor state. Choices of an appropriate process for destruction include flameless oxidation, thermal incineration, or catalytic incineration. When a zeolite adsorber is divided into several fixed beds in cascade flow as in Figure 6, and when granules of appropriate zeolite are used, the several types of VOC vapors can be adsorbed in separate beds. European firms have already adopted zeolite fixed beds. The acceptance may be based upon the fact that Europe and Asia are prime sources of natural zeolite. Christensen Arms AO Modification 9/7/23 13 vapor in air out air bleed heat incinerator Figure 7. V O C Concentrator rotation adsorber stack The VOC can then be recovered individually from these beds, and the resulting VOC can be purer than the mixed vapors. The key is in the selection of the zeolite. While nobody currently advertises the commercial availability of this vacuum regenerated zeolite adsorption system, research supporting it has been done. It is the next logical step, and its development is anticipated. VAPOR CONCENTRATOR Although adsorbers have historically been used independently as a pollution control device, the vapor concentrator has also appeared. The vapor concentrator is intended to raise the concentration of VOC vapor to provide more economical treatment in either combustion or condensation devices. The typical concentration ratio (output VOC concentration divided by input VOC concentration) that can be obtained from a vapor concentrator can range to well over a thousand. However, when the actual concentration of a combustible VOC is near one-fortieth of the LEL, you can economically justify using a rotary vapor concentrator, which may also include an incinerator. Figure 7 shows a rotary vapor concentrator. This is used where the VOC vapor is in a large air flow, and must be concentrated before it can be incinerated economically. (The concentrator air bleed is usually about 10%of the input air flow with an incinerator, and thus the concentration ratio is about ten.) Therefore, if the initial concentration is one-fortieth of the LEL, the resulting concentration is about one-fourth of the LEL. This means that, for incineration, a minimum of fuel would have to be added to assure enough heating value for adequate incineration. Christensen Arms AO Modification 9/7/23 14 The adsorbent is mounted in a wheel that is rotating either vertically or horizontally. If the wheel is rotating about a horizontal axis, the air flows axially through sectors in the wheel. If the wheel rotates about a vertical axis, the air flows radially through segments on the rim of the wheel. The adsorbent is located in relatively shallow beds in the sectors or the segments. The adsorbent can be zeolite alone, a mixture of zeolite with carbon, a mixture of zeolite with polymer adsorbents, or either carbon or polymer adsorbent beds with zeolite beds downstream. As shown in the rotary vapor concentrator diagram, the air bleed is heated by the incinerator, and the heat is then fed to a sector or segment of the rotating wheel to regenerate the adsorbent. This sector or segment is isolated by seals which allow the VOC to be recaptured and sent to the incinerator at a higher concentration than was present in the input air flow. This allows the VOC to have a greater heating value per cubic foot and, therefore, less additional fuel is required to raise the temperature to a level where the destruction or recovery efficiency (DRE) of the incinerator is above 98 %. The VOC is incinerated to provide heat to the air bleed for regeneration of the adsorbent bed. An alternative would be to regenerate at a lower temperature and condense the VOC. The temperature would have to be above the minimum temperature for regenerating the VOC with that adsorbent and the cost of refrigerated condensation would have to be included. This would use a “heat pump” to send the heat of condensation to the air bleed for desorbing the VOC. The fact that this uses only a tenth as much air flow reduces the cost of refrigeration. Both options are available. It is important for safety that the maximum concentration remain below one-fourth of the LEL, so the concentration ratio should be controlled to assure this. The closer the higher concentration gets to one-fourth of the LEL, the less fuel must be added to supplement the heating value of the VOC. The limit of one-fourth of the LEL is imposed by Occupational Safety and Health Administration (OSHA) and the National Fire Prevention Association (NFPA) for fire and explosion safety. As a result of using the rotary vapor concentrator, the incinerator can be much smaller, requiring only about 10% of the volume otherwise required to provide an equal residence time. The cost of an incinerator in the OAQPS Control Cost Manual is proportional to the air flow rate times the residence time raised to either the 0.25 or 0.55 power, depending upon the type of incinerator. Therefore, using the concentrator also produces savings in the cost of the incinerator. Fluidized bed concentrators have also been developed which are analogous to the rotary vapor concentrator. It is claimed that these are capable of raising the VOC concentration in the air flow by as much as 10,000:1. However, since carbon is not an efficient adsorbent at such low concentrations of VOC, zeolite or polymers may have been used as adsorbents or mixed with the carbon to allow such low concentrations to be adsorbed. The use of such an adsorber might be related to odor reduction, in which such low concentrations would be normal. The operating cycle is otherwise very similar to the rotating wheel concentrator. However, the cycle is based Christensen Arms AO Modification 9/7/23 15 adsorbermixture in one gas out other gas out Figure 8. Pressure Swing Adsorption upon fluidized transfer of the adsorbent from the adsorption bed to the desorption region. It uses the rate of adsorbent transport versus the rate of air flow to obtain the concentration ratio. PRESSURE SWING ADSORBER Figure 8 shows a schematic diagram of a pressure swing adsorption system. This is used for separation of gases or vapors from air based upon their adsorption isotherms being a function of total pressure, as well as vapor pressure, and temperature. It is also used to separate pollutants from flue gases. The mixture of gases or vapors is admitted to pressurize the adsorber, which contains the adsorbent. Some gases are adsorbed more quickly than others, and the cycling frequency is used to separate these. In other cases, one gas or vapor is adsorbed preferentially and the cycling frequency is less important. After admitting the gas mixture, the gas that is not adsorbed as strongly is vented, which brings the pressure to a lower level. When this venting is stopped, the pressure is further reduced to desorb the other gas or vapor. This has been used to separate oxygen from air, carbon dioxide from air, carbon dioxide from flue gas, sulfur dioxide from flue gas, and gasoline vapors from tanks venting to the atmosphere. It is effective when the preferentially adsorbed gas or vapor has a relatively large concentration. This is not usually considered as a control technology. The vapors have to be at concentrations of tens of thousands of parts per million, rather than the hundreds or thousands of parts per million which are usually controlled as emissions. However, they are used in control of vapors from vents on VOC storage tanks (such as gasoline). Christensen Arms AO Modification 9/7/23 16 ARE ADSORPTION SYSTEM DESIGN TOOLS AVAILABLE? EPA has design equations for the thermal swing carbon adsorber in the OAQPS Control Cost Manual. These equations are used in the Air Compliance Advisor (ACA) and the CO$T-AIR spreadsheet software (See References). The design equations for polymer and zeolite adsorbers and other adsorption systems have not yet been determined by EPA, but should be analogous when the differences have been accounted for. These differences have to do with weight of adsorbent, superficial air flow rate, cost of a vessel which must withstand evacuation, etc. The designers of an adsorption system really earn their fee. They must choose the type of system to be compatible with the VOC and the purpose. They must choose (or help choose) the adsorbent, the size and number of beds, the construction of the container for each bed, the regeneration method, the time that the adsorber should be used before regeneration (determined by air flow and the concentration of VOC), how many beds should be used in parallel, the choice of boiler or vacuum pump, the instrumentation and controls that will operate these in the proper sequence at the proper time, and the location and sequencing of pipes and valving for the operation. Then they must execute a design in which all of these things work together. They must assure that the adsorber does not experience breakthrough in too short a time. They must have the unit meet the customer’s specifications, and they must keep an eye on the costs, and assure the costs are not excessive. As a result, they must be familiar with the system they are designing. That is the rub, for each designer will choose the system that they are most familiar with, unless it is absolutely ruled out by the customer. The system that all designers are familiar with is the thermal swing carbon adsorber system, for it has been used for several decades. They are often not familiar with the newer systems, regeneration techniques, or adsorbents. The newer systems, regeneration techniques, and adsorbents have distinct advantages over the older ones. WHAT CONTROL EFFICIENCY SHOULD YOU EXPECT TO GET? You should expect a well designed adsorber system to achieve 95% - 98% control efficiency at input concentrations between 500 and 2000 ppm in air. This is independent of follow-up systems such as an incinerator or a condenser. Therefore, the control efficiency of a combined adsorber and incinerator might be: adsorber efficiency x incinerator efficiency = 95% x 98% = 93.1% while the efficiency of a combined adsorber and condenser might be: adsorber efficiency x condenser efficiency = 95% x 99% = 94.05% The actual control efficiency of both the adsorber and the follow-on device will be involved. Neither the efficiency of the adsorber nor the efficiency of the follow-on device is more dominant, Christensen Arms AO Modification 9/7/23 17 but whichever one that has the lower efficiency will cause more loss in the total efficiency. WHAT TYPE OF SOURCES CAN USE ADSORPTION TECHNOLOGY? VOC and organic hazardous air pollutant emissions can be controlled, recovered, recycled, or concentrated for additional treatment by adsorption technology. This includes emissions from: dry cleaning, degreasing, paint spraying, solvent extracting, metal foil coating, paper coating, plastic film coating, printing, pharmaceuticals, rubber, linoleum, and transparent wrapping. Any process that generates VOC emissions at low concentrations (as low as 20 ppm) at relative high air flows (greater than 5,000 acfm) should consider adsorption technology to concentrate VOC in the emission stream prior to final treatment and either recycling or destruction. HOW MUCH DO ADSORBERS COST? Procedures, data, and equations for sizing and estimating the capital and annual costs of thermal swing (“regenerative”) carbon adsorption systems are given in the OAQPS Control Cost Manual (5th edition, February 1996). For the users’ convenience, these OAQPS Control Cost Manual equations have been incorporated into the CO$T-AIR control cost spreadsheets and the Air Compliance Advisor program, all of which can be downloaded from the CATC Web page. We must emphasize, however, that these equations provide “study” (+/- 30% accuracy) cost estimates for only those adsorbers that use activated carbon. Cost-estimating procedures for polymer or zeolite-based adsorption systems have yet to be developed by EPA. Those interested in the latter should contact one or more vendors of those systems. (See extensive vendor list at the end of this bulletin.) Carbon adsorber costs depend on a variety of facility, regulatory, sizing, and cost parameters. For that reason, no meaningful cost rules-of-thumb can be developed. Facility parameters include, first of all, the exhaust gas and pollutant characteristics--volumetric flow rate, temperature, pressure, VOC composition, VOC loading, and moisture and particulate contents. Another important facility parameter is its status, i.e., new or existing. At an existing facility, the cost of installing the adsorber equipment typically will be higher. The difference between this higher installation cost and the cost of installing the same control system at a new facility is termed the “retrofit penalty”. Depending on how the regulation is written, the most pertinent regulatory parameter is either the mandated VOC outlet concentration or the corresponding adsorber control efficiency required to meet it. Sizing parameters include the material of construction (304 stainless steel is typical for carbon adsorbers), amount of insulation, pressure drop, adsorbent working capacity, and whether the system is factory-assembled (“packaged”) or built on site (“custom”). One of the most important design parameters is the adsorption time. This time is often selected to be compatible with production schedules. For example, an adsorber controlling a printing operation that runs in eight-hour shift increments might have an eight-hour adsorption time. At Christensen Arms AO Modification 9/7/23 18 the end of each shift, the adsorber bed(s) would be regenerated in time to be put back on line before the next shift begins. Clearly, as the adsorption time increases, so does the amount of adsorbent required and, hence, the size, number, and cost of the adsorber vessels. But while shorter adsorption times result in smaller adsorber systems and lower capital costs, higher annual costs are required because the adsorbent must be regenerated more frequently. These primarily consist of increases in the steam requirement (for bed regeneration) and electricity demand (for the bed drying/cooling fan). With steam regeneration the user has the option of either generating steam on-site via an existing boiler or purchasing a new boiler dedicated to that purpose. Alternatively, the user may choose to purchase the steam from an outside source. The above decisions and selections are within the user’s purview. However, the user will not have to be concerned with such details as sizing the steam lines, selecting the bed drying/cooling fan, designing the adsorber vessels, etc. Those kinds of specifications are determined by the adsorber vendor whose application experience and knowledge of the adsorption process is much more extensive. The cost and cost-related parameters, such as the annual operating hours, also heavily influence the “bottom line”. These include prices for carbon, electricity, steam, operating and maintenance labor, and replacement adsorbent (including the replacement labor cost), as well as the interest rate and the useful lives of the adsorbent and the rest of the control system. One of the most critical cost parameters is the value assigned to the recovered VOC. As the example below illustrates, if the quantity of recovered VOC is large enough, its value can offset the annual costs, resulting in a net annual credit. Obviously, this value must be chosen carefully, keeping in mind both the current market price of the VOC and the purity of the recovered organics. The greater the purity, the higher the value. (For more information on these and other parameters, refer to Chapter 4 (“Carbon Adsorbers”) of the OAQPS Control Cost Manual.) Consider the following hypothetical illustration. Four existing printing operations emit toluene (an ink solvent) in quantities large enough to attract the attention of a state air pollution control agency. The agency’s regulations for these printing operations require that 98% of the toluene be removed before the exhaust may be vented to the atmosphere. The smallest of these operations emits 50 lb/hour of toluene at a flow rate of 5,000 actual cubic feet/minute (acfm), while the largest emits 1,250 lb/hour at a 50,000 acfm flow rate. The other two emit 250 lb/hour each at 5,000 and 50,000 acfm, respectively. What would be the capital and total annual costs (TAC) of steam regeneration carbon adsorber systems installed to control the toluene from these operations? The Table 1 lists these costs for each of the four adsorber systems. Computed via the CO$T-AIR carbon adsorbers spreadsheet, these costs reflect second quarter 1998 prices for equipment, carbon, utilities, labor, and toluene. Price sources consulted included the Department of Energy’s Monthly Energy Review (electricity and distillate oil for steam production), the Bureau of Labor Statistics (printing and publishing labor), and the Chemical Marketing Reporter (toluene). (Note: All costs have been rounded to two significant figures.) Christensen Arms AO Modification 9/7/23 19 As we might expect, the capital costs increase with both increasing gas flow rate and toluene emission rate. Larger flow rates require larger and more costly adsorber vessels, decanters, condensers, and other equipment. By the same token, as the emission rate increases, more carbon must be provided for adsorption. Note that the unit capital cost ranges from $22/acfm to $87/acfm--a factor of four ratio. Such a wide range discourages the use of such rules of thumb for capital cost estimating. Gas Flow Rate (acfm) Toluene Emitted (lb/hr) Capital Cost Total Annual Cost (Credit) 1,000 $$/acfm 1,000 $/yr $/million acf 5,000 50 240 48 43 18 250 430 87 (19)(8.0) 50,000 250 1,100 22 110 4.6 1,250 1,700 33 (280)(12) Table 1. Cost of Thermal Swing (“regenerative”) Carbon Adsorption Systems Other important inputs to these costs include: * Operating hours/year: 8,000 * Adsorption and desorption times: 8 and 4 hours, respectively. * Inlet gas temperature: 77EF. * Annual interest rate: 7% * Equipment lives (years): 10 (adsorber system); 5 (carbon) The total annual cost (TAC) does not vary smoothly, however. Note that, for the 5,000 acfm systems, increasing the emission rate from 50 to 250 lb/hour decreases the TAC from $43,000/year to a net credit of $19,000/year. The annual costs for the 50,000 acfm systems behave similarly. Clearly, the toluene recovery credit heavily influences the TAC. This credit, in turn, depends on three parameters: the inlet emission rate, the control efficiency, and the value assigned to the recovered organic. The first two parameters will be essentially constant for a given emission source and control system. But, as discussed above, the expected recovery value can vary significantly according to market conditions and, for that reason, it must be selected carefully. Finally, the unit TAC ranges widely, from a credit of $12/million acfm treated to a cost of $18/million acfm. As we have shown, both the capital and total annual costs for these hypothetical systems cover a broad range. And remember that these costs vary so widely for adsorbers removing the same VOC (toluene) emitted from the same type of source (printing operation) based upon identical Christensen Arms AO Modification 9/7/23 20 input parameters (air flow rate and toluene emission rate excepted). Consider that the adsorption of other VOC’s (and VOC mixtures) could require much more or less carbon, that other sources could require much shorter or longer adsorption/desorption times, and that the input parameters could be vastly different under other control scenarios. Thus, the only conclusion we can safely draw about carbon adsorber costs--or, for that matter, the costs of any type of control system--is no conclusion. You must get quotes from vendors, consultants, or designers. For rotary vapor concentrators, zeolite is frequently used (either with or without other adsorbents) as the adsorbent in vapor concentrators because it is more effective in adsorbing lower concentrations of VOC. The cost of such a system depends upon air flow and VOC concentration, and runs from about $1000 to $1500 per ton of VOC destroyed at 100 ppm, to $3,250 per ton of VOC destroyed at 20 ppm, according to Munters ZEOL. DECISIONS, DECISIONS... Does your process have VOC emissions? Can you smell that your process is operating? If so, your process probably emits a VOC, and the emissions of the VOC probably should be controlled. Do emissions exceed 10 tons per year (55 pounds per day)? Do the emissions exceed your operating permit? Any “yes” answer means that you probably are emitting a VOC that is in need of control. Check with your state or local agency that issues operating permits if you are in doubt. VOCs often (but not always) have between 2 and 16 carbon atoms. VOCs also react in ultraviolet light (sunlight) with NO to multiply the NO2 which creates ozone. If you are not sure whether an emission from your plant is a VOC, call EPA’s Clean Air Technology Center (CATC) at 919-541-0800, or contact the CATC by FAX at 919-541-0242, or by e-mail at catcmail@epamail.epa.gov and you will be referred to someone who can help you determine this. We also have a CATC Web page at www.epa.gov/ttn/catc if you prefer to contact us by that route. If your process emits a VOC in any amount larger than 20 pounds per day, then you should look into the topic of controlling emissions. We have seen several advertisements on the Internet at URL’s (Internet addresses) for adsorber system designers and manufacturers. You can also use a search algorithm, and commercial advertisements usually come first in their output. When you have to control emissions of VOC, you have to make several decisions: 1. Will the VOC be destroyed or recovered? What re-use value will it have? This will affect the design of the system, and the economics of operating it. Perhaps you will want all options investigated. 2. If the VOC are to be recovered, how pure does it have to be? How much cost can be avoided by not buying VOC with the purity that you require? If it must be very pure, you must decide whether you are going to distill the VOC after recovery, or how that can be achieved. Christensen Arms AO Modification 9/7/23 21 3. If purity is either not needed or not possible, and the VOC is not water soluble, you might use a condenser with a skimmer to separate the condensed moisture or steam from the VOC. 4. You must decide whether you will use carbon, zeolite, or polymeric adsorbents. Each has its advantages, each has its disadvantages. You must make this preliminary decision with expert consultation before hiring a designer, because designers will design the kind of system that they are most familiar with. There are many designers for systems having carbon regenerated by steam because this system has been around for decades, but you will have fewer designers and consultants available for newer systems and adsorbents. 5. There are several firms that offer rotary or fluidized bed concentrators. Some of these are: (Note: Naming of these sources does not imply an endorsement, and this list is known to be abbreviated and incomplete.) ABB Paint Finishing 1400 Stephenson Hwy.Troy, MI 48099 Durr Environmental, Inc. 40600 Plymouth Rd.Plymouth, MI 48170 Engelhard 101 Wood Ave.Iselin, NJ 08830-0770 JWP AMCEC 2625 Butterfield Rd.Oak Brook, IL 60521 Met-Pro Corp.160 Cassel Road Harleyville, PA 19438 Munters ZEOL 79 Monroe St P.O.Box 600 Amesbury, MA 01913-0600 6. Some other sources for adsorber design and/or construction are: (see Note above) AMCEC Corp.2525 Cabot Dr.Suite 205 Lisle, IL 60532 ACR Activated Carbon Resources Inc.Westport, CT American Air Filter P.O.Box 35690 Louisville, KY 40232-5690 American Environmental Int’l 5 Revere Dr Suite 200 Northbrook, IL 60062-9998 Aquest Corp.Somers, NJ Atochem Inc. / CECA Division 266 Harristown Rd.Glen Rock, NJ 07452 Barneby & Sutcliffe P.O. Box 2526 Columbus, OH 43216 Baron-Blakeslee Inc.2001 N. Janice Ave. Melrose Park, IL 60160 COH Corp.2000 Eastern Pkwy Brooklyn, NY 11233 Calgon Carbon Corp.P.O.Box 717 Pittsburgh, PA 15230-0717 Carbtrol Corp.39 Riverside Dr.Westport, CT 06880 DR Technology Hidden Pines Drive Clarksburg, NJ 08510 Dedert Corp.2000 Governors Dr.Olympia Fields, IL 60461-1074 Ducon Environmental Syystems Co.110 BiCounty Rd.Farmingdale, NY 11735-3923 Envirotrol Inc.432 Green St P.O.Box 61 Sewickley, PA 15143 Filcorp Industries Milton, VT FMG P.O.Box 3043 Union Gap, WA 98903 Green and Green Associates Lexington, MA Hydrogroup Inc.1011 Hwy 22 Bridgewater, NJ 08807 HCT Corp.325 Lennon Lane Suite 200 Walnut Creek, CA 94598 Christensen Arms AO Modification 9/7/23 22 HydroQuip, Inc.63 N Washington St.N. Attleboro, MA 02761 Independent Equipment Corp. Rte. 202N P.O.Box 460 Three Bridges, NJ 08887 KX Industries Orange, CT Kensington Corp.Madison, CT Nuclear Consulting Services Inc. (NUCON)P.O.Box 29151, Columbus, OH 43229-1022 Penney Engineering Inc.Mansfield, MA Peroxidation Systems Inc. 4400 E. Broadway, Suite 602 Tucson, AZ 85711-3558 Prime Carbon Bow, NH R H Reimer Associates Needham, MA Remedial Systems Inc. 56 Leonard St.Foxboro, MA 02035 Service Tech Inc.Swansea, MA Tetrasolv Plymouth, MA Tigg Corp.800 Old Pond Rd.Bridgeville, PA 15017-3415 Unisorb Corp.1310 Genoa St.S. Houston, TX 77587 VARA International 1201 19th Place Vero Beach, FL 32960 Waste Min Inc.Groton, MA Westgates Carbon Inc. 2130 Leo Ave.Los Angeles, CA 90040-1634 Westport Environmental Systems 251 Forge Rd.Westport, MA 02790-0217 Wintek Corp.RR3 Box 337 Lime Rock Lane Califon, NJ 07830 Zimpro-Passavant Inc. 301 Military Rd.Rothschild, WI 5474 SOME REFERENCES: (some with Internet URL for the web page) Organic Sponges for Cost-Effective CVOC Abatement, Final Report - July 1994, US DOE Contract No. DE-AC21-92MC29110, General Electric Corporate Research and Development Control Techniques for Volatile Organic Compound Emissions from Stationary Sources, EPA 453/R-92-018 OAQPS Control Cost Manual, EPA 453/B-96-001, February 1996 www.epa.gov/ttn/catc Control of Gaseous Emissions, APTI, Course 415, Student Manual, EPA 450/2-81-005 Hydrophobic Zeolites as Adsorbents for Removal of VOC from Air, M. V. Chandak and Y. S. Lin, Dept. of Chemical Engineering, University of Cincinnati Impregnated Activated Carbon for Environmental Protection www.activated-carbon.com/enviro.html Christensen Arms AO Modification 9/7/23 23 Envirosense es.epa.gov/studies/cs593.html es.epa.gov/program/regional/state/wi/actcarbo.html Adsorptive Recovery of Problematic Solvents www.activated-carbon.com/probsol1.html Gas Adsorption chem.ufl.edu/`itl/4411L_f96/ads/ads_1.html Steam Regeneration of Activated Carbon Beds, M. Huggahalli and J. Fair, American Institute of Chemical Engineers, Annual Meeting, November 1996 Microwave Regeneration Field Test Unit www.me.utexas.edu/~prep/demo.html Preparation and Characteristics of Polymer-based Large Adsorbent Particles, Journal of Applied Polymer Science, Vol. 61, No. 11, September 1996, pp 1949-1956 www.interscience.wiley.com/jpages/0021-8995/abs/v61n11p1949.html Microwave Regeneration of Volatile Organic Compound Adsorbents, P. Di and D. Chang, 96- RA106.2, Air & Waste Manaagement Assn. PADREO Vapor Treatment Process www.nttc.edu/env/site95/demo/ongoing/purus.html Gas-Surface Dynamics www.ssci.liv.ac.uk/~darling/dynamica/index.html www.ssci.liv.ac.uk/~darling/dynamica/history/ancient.html The Desorption Process alpha.qmw.ac.uk/~ugca000/surfaces/scc/scat2_5.htm PE Curves & Energetics of Adsorption alpha.qmw.ac.uk/~ugca000/srfaces/scc/scat2_4.htm Adsorption Kinetics - The Rate of Adsorption alpha.qmw.ac.uk/~ugca000/srfaces/scc/scat2_3.htm How do Molecules Bond to Surfaces? alpha.qmw.ac.uk/~ugca000/srfaces/scc/scat2_2.htm Christensen Arms AO Modification 9/7/23 24 CO$T-AIR Spreadsheets www.epa.gov/ttn/catc Air Compliance Advisor www.epa.gov/ttn/catc Institute of Clean Air Companies www.icac.com Christensen Arms AO Modification 9/7/23 25 Christensen Arms AO Modification 9/7/23 EPA-452/F-03-018 Air Pollution Control Technology Fact Sheet EPA-CICA Fact Sheet Catalytic Incinerator1 Name of Technology: Catalytic Incinerator This type of incinerator is also referred to as a catalytic oxidizer, or catalytic reactor. Type of Technology: Destruction by oxidation. Applicable Pollutants: Volatile organic compounds (VOC) and many types of particulate matter (PM). In the past, catalytic incinerators were not recommended as a control device for PM, since the PM, unless removed prior to incineration, often coated (or “blinded”) the catalyst so that the catalyst’s active sites were prevented from aiding in the oxidation of pollutants in the gas stream (EPA, 1998). Examples are gases containing chlorine, sulfur, and other atoms, such as phosphorous, bismuth, lead, arsenic, antimony, mercury, iron oxide, tin, and zinc that may deactivate the supported noble metal catalysts (EPA, 1991). However, catalysts have been recently developed that can tolerate almost any compound. Most of these catalysts are single or mixed metal oxides, often supported by a mechanically strong carrier such as various types of alumina. Catalysts such as chromia/alumina, cobalt oxide, and copper oxide/manganese oxide have been used for oxidation of gases containing chlorinated compounds. Platinum-based catalysts are active for oxidation of sulfur containing VOC, although they are rapidly deactivated by the presence of chlorine (EPA, 1996a). Achievable Emission Limits/Reductions: VOC destruction efficiency is dependent upon VOC composition and concentration, operating temperature, oxygen concentration, catalyst characteristics, and space velocity. Space velocity is commonly defined as the volumetric flow of gas entering the catalyst bed chamber divided by the volume of the catalyst bed. The relationship between space velocity and VOC destruction efficiency is strongly influenced by catalyst operating temperature. As space velocity increases, VOC destruction efficiency decreases, and as temperature increases, VOC destruction efficiency increases. As an example, a catalytic unit operating at about 450/C (840/F) with a catalys t bed volume of 0.014 to 0.057 cubic meter (m3) (0.5 to 2 cubic feet (ft3)) per 0.47 standard cubic meters per second (sm3/sec) (1,000 standard cubic feet per minute (scfm)) of offgas passing through the device can achieve 95 percent VOC destruction efficiency (EPA, 1992). Higher destruction efficiencies of (98 - 99 percent) are achievable, but require larger catalyst volumes and/or higher temperatures, and are usually designed on a site-specific basis (EPA, 1991). In EPA’s 1990 National Inventory, incinerators as a group, including catalytic incinerators, were reported as being used as control devices for PM and were reported as achieving 25 - 99% control efficiency of PM10 at point source facilities (EPA, 1998). Table 1 presents a breakdown of the PM10 control efficiency ranges by industry where catalytic incinerators have been reported (EPA, 1996b). The VOC control efficiency reported for these devices ranged from 0 to 99.9%, however, it is assumed that reports of higher efficiencies (greater than 99%) are attributable to thermal incinerators. These ranges of control efficiencies are large because they include facilities that do not have VOC emissions and control only PM, as well as facilities which have low PM emissions and are primarily concerned with controlling VOC (EPA, 1998). Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Catalytic Incinerator2 Table 1. PM10 Destruction Efficiencies for Catalytic Incinerators and Catalytic Incinerators with Heat Exchanger by Industry (EPA, 1996b) Industry/Types of Sources PM10 Control Efficiency (%) Petroleum and Coal Products asphalt roofing processes (blowing, felt saturation); mineral calcining; petroleum refinery processes (asphalt blowing, catalytic cracking, coke calcining, sludge converter); sulfur manufacturing 25 - 99.9 Chemical and Allied Products carbon black manufacturing (mfg); charcoal mfg; liquid waste disposal; miscellaneous chemical mfg processes; pesticide mfg; phthalic anhydride mfg (xylene oxidation); plastics/synthetic organic fiber mfg; solid waste incineration (industrial) 50 - 99.9 Primary Metals Industries by-product coke processes (coal unloading, oven charging and pushing, quenching); gray iron cupola and other miscellaneous processes; secondary aluminum processes (burning/drying, smelting furnace); secondary copper processes (scrap drying, scrap cupola, and miscellaneous processes); steel foundry miscellaneous processes; surface coating oven 70 - 99.9 Electronic and Other Electric Equipment chemical mfg miscellaneous processes; electrical equipment bake furnace; fixed roof tank; mineral production miscellaneous processes; secondary aluminum roll/draw extruding; solid waste incineration (industrial) 70 - 99.9 Electric, Gas, and Sanitary Services internal combustion engines; solid waste incineration (industrial, commercial/ institutional) 90 - 98 Stone, Clay, and Glass Products barium processing kiln; coal cleaning thermal dryer; fabricated plastics machinery; wool fiberglass mfg 50 - 95 Mining asphalt concrete rotary dryer; organic chemical air oxidation units, sulfur production 70 - 99.6 Educational Services solid waste incineration (commercial/ institutional) 80 Paper and Allied Products boiler 95 Printing and Publishing surface coating dryer; fugitives 95 Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Catalytic Incinerator3 Applicable Source Type: Point Typical Industrial Applications: Catalytic incinerators can be used to reduce emissions from a variety of stationary sources. Solvent evaporation processes associated with surface coating and printing operations are a major source of VOC emissions, and catalytic incineration is widely used by many industries in this category. Catalytic incinerators are also used to control emissions from the following (EPA, 1992): •Varnish cookers; •Foundry core ovens; •Filter paper processing ovens; •Plywood veneer dryers; •Gasoline bulk loading stations; •Process vents in the synthetic organic chemical manufacturing industry (SOCMI); •Rubber products and polymer manufacturing; and •Polyethylene, polystyrene, and polyester resin manufacturing. Catalytic oxidation is most suited to systems with lower exhaust volumes, when there is little variation in the type and concentration of VOC, and where catalyst poisons or other fouling contaminants such as silicone, sulfur, heavy hydrocarbons and particulates are not present. Emission Stream Characteristics: a.Air Flow: Typical gas flow rates for packaged catalytic incinerators are 0.33 to 24 sm3/sec (700 to 50,000 scfm) (EPA, 1996a). b.Temperature: Catalysts in catalytic incinerators cause the oxidizing reaction to occur at a lower temperature than is required for thermal ignition. Waste gas is heated by auxiliary burners to approximately 320/C to 430/C (600/F to 800/F) before entering the catalyst bed (AW MA, 1992). The maximum design exhaust temperature of the catalyst is typically 540/ - 675/C (1000/ - 1250/F). c.Pollutant Loading: Catalytic incinerators can and have been used effectively at very low inlet loadings; down to 1 part per million by volume (ppmv) or less (EPA, 1995). As with thermal and recuperative incinerators, for safety considerations, the maximum concentration of the organics in the waste gas must be substantially below the lower flammable level (lower explosive limit, or LEL) of the specific compound being controlled. As a rule, a safety factor of four (i.e., 25% of the LEL) is used (EPA, 1991, AWMA, 1992). The waste gas may be diluted with ambient air, if necessary, to lower the concentration. d.Other Considerations: Characteristics of the inlet stream should be evaluated in detail, because of the sensitivity of catalytic incinerators to VOC inlet stream flow conditions, which may cause catalyst deactivation (EPA, 1992). Emission Stream Pretreatment Requirements: Typically, if design conditions are satisfied no pretreatment is required, however, in some cases, PM removal may be necessary before the waste gas enters the incinerator. Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Catalytic Incinerator4 Cost Information: The following are cost ranges (expressed in 2002 dollars) for packaged catalytic incinerators of conventional design with fixed beds under typical operating conditions, developed using EPA cost-estimating spreadsheets (EPA, 1996a) and referenced to the volumetric flow rate of the waste stream treated. The costs do not include costs for a post-oxidation acid gas treatment system. Costs can be substantially higher than the ranges shown when used for low-VOC concentration streams (less than around 100 ppmv). As a rule, smaller units controlling a low concentration waste stream will be much more expensive (per unit volumetric flow rate) than a large unit cleaning a high pollutant load flow. Operation and Maintenance (O & M) Costs, Annualized Cost, and Cost Effectiveness are dominated by the cost of supplemental fuel required. a.Capital Cost: $47,000 to $191,000 per sm3/sec ($22 to $90 per scfm) b.O & M Cost: $8,500 to $53,000 per sm3/sec ($4 to $25 per scfm), annually c.Annualized Cost: $17,000 to $106,000 per sm3/sec ($8 to $50 per scfm), annually d.Cost Effectiveness: $105 to $5,500 per metric ton ($100 to $5,000 per short ton), annualized cost per ton per year of pollutant controlled. However, when used to treat very low concentrations of toxic air pollutants (less than 100 ppmv), the cost per ton removed may be many thousands of dollars, because only a small amount of pollutant is being destroyed. Theory of Operation: Catalytic incinerators operate very similar to thermal/recuperative incinerators, with the primary difference that the gas, after passing through the flame area, passes through a catalyst bed. The catalyst has the effect of increasing the oxidation reaction rate, enabling conversion at lower reaction temperatures than in thermal incinerator units. Catalysts, therefore, also allow for smaller incinerator size. Catalysts typically used for VOC incineration include platinum and palladium. Other formulations include metal oxides, which are used for gas streams containing chlorinated compounds (EPA, 1998). In a catalytic incinerator, the gas stream is introduced into a mixing chamber where it is also heated. The waste gas usually passes through a recuperative heat exchanger where it is preheated by post combustion gas. The heated gas then passes through the catalyst bed. Oxygen and VOC migrate to the catalyst surface by gas diffusion and are adsorbed onto the catalyst active sites on the surface of the catalyst where oxidation then occurs. The oxidation reaction products are then desorbed from the active sites by the gas and transferred by diffusion back into the gas stream (EPA, 1998). Particulate matter can rapidly coat the catalyst so that the catalyst active sites are prevented from aiding in the oxidation of pollutants in the gas stream. This effect of PM on the catalyst is called blinding, and will deactivate the catalyst over time. Because essentially all the active surface of the catalyst is contained in relatively small pores, the PM need not be large to blind the catalyst. No general guidelines exist as to the PM concentration and size that can be tolerated by catalysts, because the pore size and volume of catalysts vary widely. This information is likely to be available from the catalyst manufacturers (EPA, 1996a). The method of contacting the VOC-containing stream with the catalyst serves to distinguish catalystic incineration systems. Both fixed-bed and fluid-bed systems are used. Fixed-bed catalytic incinerators may use a monolith catalyst or a packed-bed catalyst (EPA, 1996a): Monolith Catalyst Incinerators - The most widespread method of contacting the VOC-containing stream with the catalyst is the catalyst monolith. In this scheme the catalyst is a porous solid block containing parallel, non-intersecting channels aligned in the direction of the gas flow. Monoliths offer the Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Catalytic Incinerator5 advantages of minimal attrition due to thermal expansion/contraction during startup/shutdown and low overall pressure drop. Packed-Bed Catalytic Incinerators - A second contacting scheme is a simple packed-bed in which catalyst particles are supported either in a tube or in shallow trays through which the gases pass. This scheme is not in widespread use due to its inherently high pressure drop, compared to a monolith, and the breaking of catalyst particles due to thermal expansion when the confined catalyst bed is heated/cooled during startup/shutdown. However, the tray type arrangement of a packed-bed scheme, where the catalyst is pelletized, is used by several industries (e.g., heat-set web-offset printing). Pelletized catalyst is advantageous where large amounts of such contaminants as phosphorous or silicon compounds are present. Fluid-bed catalytic incinerators have the advantage of very high mass transfer rates, although the overall pressure drop is somewhat higher than for a monolith. An additional advantage of fluid-beds is a high bed- side heat transfer as compared to a normal gas heat transfer coefficient. This higher heat transfer rate to heat transfer tubes immersed in the bed allows higher heat release rates per unit volume of gas processed and, therefore, may allow waste gas with higher heating values to be processed without exceeding maximum permissible temperatures in the catalyst bed. In these reactors the gas phase temperature rise from gas inlet to gas outlet is low, depending on the extent of heat transfer through imbedded heat transfer surfaces. The catalyst temperatures depend on the rate of reaction occurring at the catalyst surface and the rate of heat exchange between the catalyst and imbedded heat transfer surfaces. As a general rule, fluid-bed systems are more tolerant of PM in the gas stream than either fixed-bed or monolithic catalysts. This is due to the constant abrasion of the fluidized catalyst pellets, which helps remove PM from the exterior of the catalysts in a continuous manner. A disadvantage of a fluid-bed is the gradual loss of catalyst by attrition. However, attrition-resistant catalysts have been developed to overcome this disadvantage. Advantages: Advantages of catalytic incinerators over other types of incinerators include (AWMA, 1992; Cooper and Alley, 1994): b.Lower fuel requirements; c.Lower operating temperatures; d.Little or no insulation requirements; e.Reduced fire hazards; f.Reduced flashback problems; and g.Less volume/size required. Disadvantages: Disadvantages of catalytic incinerators include (AWMA, 1992): a.High initial cost; b.Catalyst poisoning is possible; c.Particulate often must first be removed; and d.Spent catalyst that cannot be regenerated may need to be disposed. Other Considerations: Catalytic incinerators offer many advantages for the appropriate application. However, selection of a catalytic incinerator should be considered carefully, as the sensitivity of catalytic incinerators to VOC inlet Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Catalytic Incinerator6 stream flow conditions and catalyst deactivation limit their applicability for many industrial processes (EPA, 1992). References: AWMA, 1992. Air & W aste Management Association, Air Pollution Engineering Manual. Van Nostrand Reinhold, New York. Cooper & Alley, 1994. C. D. Cooper and F. C. Alley, Air Pollution Control: A Design Approach, Second Edition, Waveland Press, Inc. IL. EPA, 1991. U.S. EPA, Office of Research and Developm ent, “Control Technologies for Hazardous Air Pollutants,” EPA/625/6-91/014, Washington, D.C., June. EPA, 1992. U.S. EPA, Office of Air Quality Planning and Standards, “Control Techniques for Volatile Organic Emissions from Stationary Sources,” EPA-453/R-92-018, Research Triangle Park, NC., December. EPA, 1995. U.S. EPA, Office of Air Quality Planning and Standards, “Survey of Control Technologies for Low Concentration Organic Vapor Gas Streams,” EPA-456/R-95-003, Research Triangle Park, NC., May. EPA, 1996a. U.S. EPA, Office of Air Quality Planning and Standards, “OAQPS Control Cost Manual,” Fifth Edition, EPA 453/B-96-001, Research Triangle Park, NC. February. EPA, 1996b. U.S. EPA, “1990 National Inventory,” Research Triangle Park, NC, January. EPA, 1998. U.S. EPA, Office of Air Quality Planning and Standards, “Stationary Source Control Techniques Document for Fine Particulate Matter,” EPA-452/R-97-001, Research Triangle Park, NC., October. Christensen Arms AO Modification 9/7/23 EPA-452/F-03-021 Air Pollution Control Technology Fact Sheet EPA-CICA Fact Sheet Incinerator - Recuperative Type 1 Name of Technology: Regenerative Incinerator This type of incinerator is also referred to as a regenerative thermal oxidizer (RTO), or a regenerative catalytic oxidizer (RCO) if a catalyst is used. Type of Technology: Destruction by thermal or catalytic oxidation. Applicable Pollutants: Volatile organic compounds (VOC). RCO units also control carbon monoxide (CO). Achievable Emission Limits/Reductions: VOC destruction efficiency depends upon design criteria (i.e., chamber temperature, residence time, inlet VOC concentration, compound type, and degree of mixing) (EPA, 1992). Typical regenerative incinerator design efficiencies range from 95 to 99% for RTO systems and 90 to 99% for RCO systems, depending on system requirements and characteristics of the contaminated stream (EPA, 1995; Power, 1996; AWMA, 1992; EPA, 1991; Chen, 1996). Lower control efficiencies are generally associated with lower concentration flows (EPA, 1995). RCO systems using precious metal-based catalyst can destroy more than 98 percent of the CO in the VOC-laden air stream (Gay, 1997). RTO systems do not reduce the levels of CO. Applicable Source Type: Point Typical Industrial Applications: Regenerative incinerators can be used to reduce emissions from a variety of stationary sources. Generally, high flow (greater than 2.4 standard cubic meters per second (sm3/sec) (5,000 standard cubic feet per minute (scfm))), low VOC concentration (less than 1000 parts per million by volume (ppmv)) applications are best suited to control with regenerative incineration systems (Gay, 1997). This type of incinerator is applicable in controlling VOC from metalworking and coating operations, automotive manufacturing, and forest and wood products manufacturing. Particulate matter (PM) and condensables which can clog the incinerator’s packed bed or poison the catalyst (for RCOs) would have to be removed by an internal filter or some pretreatment technology prior to entering the reactor chamber (Biedel and Nester, 1995). The use of precious metal catalysts such as platinum and palladium have allowed VOC waste streams containing chlorides, bromides, and other halogens to be controlled with RCO systems. However, the potential for catalyst poisoning still exists if the VOC stream contains silicon, phosphorous, arsenic, or other heavy metals (Gay, 1997). Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Incinerator - Recuperative Type 2 Emission Stream Characteristics: a. Air Flow: Typical gas flow rates for regenerative incinerators are 2.4 to 240 sm3/sec (5,000 to 500,000 scfm) (Gay, 1997). b. Temperature: An RTO uses natural gas to heat the entering waste gas to typically from 760(C to 820(C (1400(F to 1500(F), however, it is capable of operating up to 1100 (C (2000(F) for those cases where maximum destruction is necessary. An RCO uses a precious metal catalyst, which allows oxidation to occur at approximately 400(C (800(F) (Gay, 1997). c. Pollutant Loading: Regenerative incinerators can and have been used effectively at inlet loadings as low as 100 ppmv or less (EPA, 1995). As with thermal and recuperative incinerators, for safety considerations, the maximum concentration of the organics in the waste gas must be substantially below the lower flammable level (lower explosive limit, or LEL) of the specific compound being controlled. As a rule, a safety factor of four (i.e., 25% of the LEL) is used (EPA, 1991; AWMA, 1992). The waste gas may be diluted with ambient air, if necessary, to lower the concentration. d. Other Considerations: Characteristics of the inlet stream should be evaluated in detail, because of the sensitivity of RCO systems to PM and VOC inlet stream flow conditions, which may cause catalyst deactivation (EPA, 1992). Emission Stream Pretreatment Requirements: Typically, if design conditions are satisfied, no pretreatment is required, however, in some cases, PM removal may be necessary before the waste gas enters the incinerator. This is more critical for RCOs than RTOs, as RTOs tolerate PM more than RCOs. Catalysts may be “blinded” by PM. Blinding is coating of the catalyst so that the catalyst active sites are prevented from aiding in the oxidation of pollutants in the gas stream. Catalytic systems may incorporate internal filters that process the air stream before it reaches the catalyst. A sacrificial bed also can be employed to prevent PM from reaching the catalyst. Some manufacturers fluidize the catalyst beds to assist in passing the PM through the system (Biedell and Nester, 1995). Cost Information: The following are cost ranges (expressed in 2002 dollars) for regenerative incinerators of conventional design both with and without a catalyst, under typical operating conditions, developed using EPA cost-estimating spreadsheets (EPA, 1996) and referenced to the volumetric flow rate of the waste stream flow treated. RTOs and RCOs are field-erected and not available as packaged units. The costs do not include costs for a post-oxidation acid gas treatment system. The upper level costs in the ranges shown apply when the control device is used for very low-VOC concentration streams (less than around 100 ppmv) at very low flow rates (around 2.4 scm/s or 5,000 scfm). As a rule, smaller units controlling a low concentration waste stream will be much more expensive (per unit volumetric flow rate) than a large unit cleaning a high pollutant load flow (EPA, 1996). a. Capital Cost: RTO: $85,000 to $320,000 per sm3/sec ($35 to $140 per scfm) RCO: $74,000 to $297,000 per sm3/sec ($35 to $140 per scfm) b. O & M Cost: RTO: $8,500 to $21,000 per sm3/sec ($4 to $10 per scfm), annually RCO: $13,000 to $42,000 per sm3/sec ($6 to $20 per scfm), annually Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Incinerator - Recuperative Type 3 c. Annualized Cost: RTO: $17,000 to $70,000 per sm3/sec ($8 to $33 per scfm), annually RCO: $23,000 to $89,000 per sm3/sec ($11 to $42 per scfm), annually d. Cost Effectiveness: RTO: $115 to $21,000 per metric ton ($100 to $17,000 per short ton), annualized cost per ton of pollutant controlled RCO: $137 to $23,000 per metric ton ($124 to $21,000 per short ton), annualized cost per ton of pollutant controlled Theory of Operation: RTOs use a high-density media such as a ceramic-packed bed still hot from a previous cycle to preheat an incoming VOC-laden waste gas stream. The preheated, partially oxidized gases then enter a combustion chamber where they are heated by auxiliary fuel (natural gas) combustion to a final oxidation temperature typically between 760(C to 820(C (1400 to 1500(F) and maintained at this temperature to achieve maximum VOC destruction, however, temperatures of up to 1100(C (2000(F) may be achieved, if required, for very high control efficiencies of certain toxic VOC. The purified, hot gases exit this chamber and are directed to one or more different ceramic-packed beds cooled by an earlier cycle. Heat from the purified gases is absorbed by these beds before the gases are exhausted to the atmosphere. The reheated packed bed then begins a new cycle by heating a new incoming waste gas stream. An RCO operates in the same manner as an RTO, however, it uses a catalyst material rather than ceramic material in the packed bed. This allows for destruction of VOC at a lower oxidation temperature. An RCO uses a precious metal catalyst in the packed bed, allowing oxidation to occur at approximately 400(C (800(F). The lower temperature requirement reduces the amount of natural gas needed to fuel the VOC abatement system and the overall size of the incinerator. Catalysts typically used for VOC incineration include platinum and palladium (Gay, 1997; Biedell and Nester, 1995). Advantages: Advantages of regenerative incinerators over other types of incinerators include the following (Gay, 1997; Stone, 1997; Biedell and Nester, 1995; Yewshenko, 1995): Advantages of RTOs: a. Lower fuel requirements because of high energy recovery (85 to 95 percent); b. High temperature capability (up to 1100(C (2000(F)) provides better destruction efficiency over recuperative incinerators, which are generally limited to 820(C (1500(F) due to heat exchanger limitations, and catalytic incinerators, which are generally limited to 600(C (1100(F) due to catalyst limitations; c. Less susceptible to problems with chlorinated compounds; and d. Generally lower NOx emissions than thermal oxidation (except when operating temperatures are above approximately 760 (C (1400(F)). Advantages of RCOs: a. Lower fuel requirements than RTOs because of lower temperature; b. Catalyst also destroys CO in waste stream; and c. Lower NOx emissions than RTOs. Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Incinerator - Recuperative Type 4 Disadvantages: Disadvantages include the following (Gay, 1997; Stone, 1997): Disadvantages of RTOs: a. High initial cost; b. Difficult and expensive installation; c. Large size and weight; and d. High maintenance demand for moving parts. Disadvantages of RCOs a. High initial cost; b. Difficult and expensive installation; c. Large size and weight; d. High maintenance demand for moving parts and catalyst monitoring; e. Catalyst poisoning is possible, however, precious metal catalysts are more resistant; f. PM often must first be removed; and g. Spent catalyst that cannot be regenerated may need to be disposed Other Considerations: Regenerative incinerators offer many advantages for the appropriate application. High flow, low concentration waste streams which are consistent over long time periods can be treated economically with either RTO or RCO systems, depending upon the waste stream composition. For either system, pretreatment to remove PM may be necessary to prevent the packed bed from clogging and/or the catalyst from poisoning. In RCO units, precious metal-based catalysts generally have a longer service life and are much more resistant to poisoning and fouling than less expensive base metal catalysts (Gay, 1997). References: AWMA, 1992. Air & Waste Management Association, Air Pollution Engineering Manual, Van Nostrand Reinhold, New York. Biedell and Nester, 1995. E. Biedell and J. Nester, “VOCs Pose a Sticky Situation for Industry,” Pollution Engineering, November. Chen, 1996. J. Chen, “Lower Operating Temperatures Oxidize VOCs,” Pollution Engineering, December. EPA, 1991. U.S. EPA, Office of Research and Development, “Control Technologies for Hazardous Air Pollutants,” EPA/625/6-91/014, Washington, D.C., June. EPA, 1992. U.S. EPA, Office of Air Quality Planning and Standards, “Control Techniques for Volatile Organic Emissions from Stationary Sources,” EPA-453/R-92-018, Research Triangle Park, NC, December. EPA, 1995. U.S. EPA, Office of Air Quality Planning and Standards, “Survey of Control Technologies for Low Concentration Organic Vapor Gas Streams,” EPA-456/R-95-003, Research Triangle Park, NC, May. EPA, 1996. U.S. EPA, Office of Air Quality Planning and Standards, “OAQPS Control Cost Manual,” Fifth Edition, EPA 453/B-96-001, Research Triangle Park, NC, February. Christensen Arms AO Modification 9/7/23 EPA-CICA Fact Sheet Incinerator - Recuperative Type 5 Gay, 1997. R. Gay, “In Search of the Best Control for Volatile Organics,” Environmental Technology, May/June. Power, 1996. Power Online, “Combu-Changer Regenerative Thermal-oxidizer System Provides Phased Low-solvent VOC Abatement,” Power Online Internet Web Page, www.poweronline.com/case-studies/cs121296.html, December 12, 1996. Stone, 1997. J. Stone, “Controlling VOC Emissions in Finishing Operations,” Products Finishing, July. Yewshenko, 1995. P. Yewshenko, “Hot Stuff Controls for VOC Emissions,” Environmental Protection, December. Christensen Arms AO Modification 9/7/23 AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX F Manufacture Specifications Cy cl o n e D u s t C o l l e c t o r s C SERIES Christensen Arms AO Modification 9/7/23 C SERIES CYCLONE DUST COLLECTORS The Most Effective Way To Remove Large Size Contaminants from your factory. HIGH-EFFICIENCY CYCLONE SEPARATOR Industrial processes generate contaminants in a variety of sizes. Some particles are visible to the human eye, while others are not. Large or small, many of these pollutants are harmful to your employees and need to be removed from the air to ensure a safe breathing environment. That’s why United Air Specialists (UAS) created the C Series Cyclone dust collector. The C Series Cyclone is designed to effectively remove large to moderate-size particles (chips, metal grindings, sawdust) from the air stream. Used alone or in conjunction with another dust collector, the Cyclone separates coarse contaminants from fine, non-visible particles, and exhausts clean air. UAS’ Cyclone dust collector offers airflow capacities ranging from 800 to 13,000 CFM. Its high-efficiency performance is accomplished by means of the unit’s long tapered cone, high-velocity inlet and welded helix. Dirty air enters the unit at a high speed and is then spun around in a spiral motion, throwing particles against its cone wall. Centrifugal force pushes the larger or heavy dust particles down through the narrow part of the cone and into a collection drum or hopper. Cleaned air runs back up through the center of the unit and is discharged back to the atmosphere or into a UAS after-filter for further processing. APPLICATIONS • Buffing • Polishing • Fiberglass/Plastic • Sawing • Grinding • Woodworking • Machining Christensen Arms AO Modification 9/7/23 www.dust-hog.net ENERGY EFFICIENT C Series Cyclone fans are self-cleaning, material handling radial blades designed to deliver peak airow with low horsepower to conserve energy. All models can be installed indoors or outdoors, and clean air can be returned inside your factory if the Cyclone is equipped with a UAS after-lter. One 30- or 55-Gallon Drum (30 gal. shown) Two 30- or 55-Gallon Drum (55 gal. shown)60ft3 or 110ft 3 Hopper (C110H shown) DISCHARGE OPTIONS CUSTOMIZED SYSTEM The C Series Cyclone oers a variety of congurations to help meet your company’s industrial air cleaning needs. With the assistance of a UAS Representative, you can actually “design” a Cyclone unit and after-lter to match your specic application. Select the direction of the inlet and discharge areas, exhaust clean air back into your plant or outdoors, or choose to use the Cyclone alone or with a UAS after-lter. Dierent ind ustrial applications generate varying amounts of dust and debris, so UAS oers a v ariety of discharge options. For small quantities, you have the choice of 30- and 55-gallon drums that can be congu r ed under the Cyclone unit as a single-or two-drum conguration . For larger loads, you may opt to use the Model C60H hopper, which has a storage capacity of 60 ft3 or Model C110H, which can hold 110 ft 3. Additionally, you can add rotary airlocks to your system to constantly discharge dust from a throw-out bin into an external dust storage container. Christensen Arms AO Modification 9/7/23 FEATURES AND BENEFITS Powder-Coated Finish Components have electrostatically applied paint that helps prevent fading and chalking. Come-Apart- Construction Allows for easy removal of cone section without replacing entire unit. Internal Helix Forces contaminants out of the air and down into the cone section. Insert Section Supports steep taper of cone to maximize efficiency. Complete Unitized Assembly Unit ships assembled for immediate use. True Storage Capacity Discharge Drum Cone sits flush with discharge area to maximize storage capacity. Blower Housing Taperlock bushing allows for easy replacement of fan wheel and motor. Durable Motor Able to withstand indoor and outdoor temperatures. Cone Section Christensen Arms AO Modification 9/7/23 www.dust-hog.net OPTIONS AND ACCESSORIES UAS pr ovides a comprehensive selection of options and accessories to enhance the performance of your C Series Cyclone dust collector. Some of these include: •Pressure Relief Panel —Minimizes damage and provides a degree of personal protection in the unlikely event of an explosion that may result when collecting explosive dusts. •Silencer Package —Duct-type and acoustical foam-lined silencers reduce unit noise levels. •Fully Welded Construction —Provides a complete, airtight seal to meet unique specications. • After-Filter Magnehelic ®Gage Kit —Monitors pressure drop to indicate when lters need to be changed. •Access doors •Aluminum fan wheel •Drum lid latch kit/slide gate •Explosion-proof motor •Explosion venting •Increased hopper clearance •Leg extensions •Lined plenum •208/3/60 motor option •Scroll outlet •Sprinkler heads •Throw out bin *Heights include motor/blower where applicable. **C-44 Series unit heights include throw-out bins. ***Weight does not include drum or hopper options. C SERIES CYCLONE CONFIGURATIONS Overall Height (inches)*After-lter Options Motor 1D 2D 60H 110H Weight Model CFM (Hp)Cyclone (One Drum) (Two Drums)(60ft3 Hopper)(110ft3 Hopper)(lbs)Interior Exterior ‘C-190 800-1,200 – 49 1/8" 92 7/8" 114 3/4"193 1/2"209 1/2"235 –– C-192 800-1,200 2 64 3/4" 108 1/4"130 3/8" 209 1/8" 225 1/8" 320 AF192 – C-200 1,250-2,250 –62 3/16"108 3/16"121 3/16"204 15/16"220 15/16" 320 –– C-203 1,250-2,000 3 79 3/16" 125 3/16"137 3/16"222"238 5/8"430 C-205 1,500-2,250 5 80 9/16"126 9/16"138 9/16" 223 3/8" 240" 450 C-240 2,000-3,500 – 73"119 1/8"131 1/8"210"226"435 –– C-247 2,000-3,500 C9-E, C18-E C18-W C-3000 3,000-5,500 –92 1/2"138 1/8"150 1/8" 228 13/16"245 3/32"621 –– C-3010 3,000-4,500 10 113 15/16"159 9/16" 171 9/16" 250 7/16"266 1/2"870 C-3015 4,000-5,500 15 119 1/2"165 1/8" 177 1/8"256"272 1/16"883 C-3600 4,500-8,000 – 112 1/16"154 3/4" 161 3/4"241 3/8"257 9/16"995 –– C-3620 4,500-7,000 20 151 3/16" 194" 201" 284 7/8"301 1/4" 1,763 AF12, C18-E C18-W C-3625 4,500-7,500 25 152 3/16" 195" 202"286"302 1/4" 1,857 C-3630 5,000-8,00 30 154 3/16" 197" 204" 287 1/2”303 3/4” 1,934 C-4400 **8,000-13,000 – 155"202 3/16" 211 3/16" 260 7/16"276 5/8"1,147 –– C-4440 **8,000-11,500 40 175 9/32" 249"257 13/16" 307"323 1/4" 1,594 AF18, Two Two C18-Es C18-Ws C-4450 **8,000-13,000 50 175 9/32"249"257 13/16" 307"323 1/4"1,745 AF24, Two Two C27-Es C27-Ws AF4, C9-E C9-W AF8, C18-E C18-W AF12, C27-E C27-W 7 1/2 95 3/8” 141 5/8”232 1/2”248 1/2”605153 5/8”AF4, AF8,C9-W, Christensen Arms AO Modification 9/7/23 AF- VERSUS C-SERIES For indoor Cyclone installations, UAS offers AF-Series after-filters. These after-filters bolt directly to the Cyclone blower outlet or are remotely mounted using interconnecting ducting. AF-Series after-filters consist of up to 24 10-oz. polyester felt zippered filter tubes. Another option is the C-Series after-filter, which can be installed inside or outside your facility. These units remotely connect to the Cyclone with ducting and empty into 55-gallon drums. Standard filter media are 9-oz. polyester felt bags. Outdoor C-Series units are designated with a “W” for weather enclosure, and are constructed using epoxy-coated cold rolled steel for the harshest environmental conditions. A UAS Representative can help you determine which after-filter is the best fit for your specific application. CHOOSING AN AFTER-FILTER Depending on your application, building specifications and other factors, it may be necessary to use an after-filter in conjunction with the C Series Cyclone. In this case, the Cyclone dust collector captures the heavier contaminants while the after-filter removes the fine particles that may not be seen, but are harmful to breathe. After-filters can be used indoors and outdoors, and can be directly mounted to the C Series Cyclone or remotely located using ducting. W AF4 Top C9-E Front C18-W Front C27-W Front C9-E Top C18-W Top C27-W Top W W W D D D D AF4 Front 70" or 100" 24" 20 9/16"20 9/16"20 9/16" Christensen Arms AO Modification 9/7/23 www.dust-hog.net AF-SERIES AFTER-FILTERS Model W D Height Filter No. of Unit RecommendedInterior Area Filters Weight Cyclone(ft2)(lbs) AF192 30"8" 72"25 1 20 C-192 AF4 51"27" 89" 72-104 4 91-95 C-203, C-205, C-247 AF8 78"27" 119" 208 8 182 C-247, C-3010, C-3015 AF12 78"40" 119" 312 12 244 C-3620, C3625, C-3630 AF18 105" 40" 119" 468 18 366 C-4440 AF24 132" 40" 119" 624 24 488 C-4450 STORAGE HOPPERS C-SERIES AFTER-FILTERS 170 1/4" 146 1/4" 67" 63 1/4" 73 1/2" 91 3/4" 154 1/4" 130 1/4" 67" 92 1/2" 24"24" 52" 68" Model C60H Side Model C60H Fr ont Model C110H Side Model C110H Fr ont E indicates indoor applications only. W indicates weather enclosure suitable for outdoor installation. Model W D Height Filter No. of Unit Recommended Interior Area Filters Weight Cyclone (ft2)(lbs) C9-E/C9-W 34" 34" 156" 119 9 600/645 C-203, C-205, C-247 C18-E/C18-W 68"34" 156" 238 18 1,175/1,225 C-247, C-3010, C-3015 C-3620, C-4440 C27-E/C27-W 102" 34" 156" 357 27 1,750/1,805 C-3625, C-3630, C-4450 44"81"57"81" Christensen Arms AO Modification 9/7/23 UAS, Inc. reserves the right to change design or without notice. IND-PSH-04-REV0208-PRO WHY CHOOSE UNITED AIR SPECIALISTS? A world-renowned reputation. For more than 40 years, we’ve been the industry leader in air quality technology — a proven track record that speaks for itself. Commitment to quality products. Measuring our quality against documented expectations, we practice continuous improvement methods to anticipate challenges and implement successful solutions. Unparalleled customer support. As a customer-driven solutions provider, we earn credibility and establish successful relationships by exceeding expectations for professional service and attitude. Innovative technical leadership. Always, we keep technology at the forefront — ensuring continuous product advancements through ongoing investments in design and manufacturing. Air Cleaning Specialists, Inc. 826 Horan Drive Fenton, MO 63026 Ph: (866) 651-9762 E-mail: info@aircleaningspecialists.com www.dust-hog.net Christensen Arms AO Modification 9/7/23 AIR PERMIT MODIFICATION APPLICATION rpsgroup.com Project Number: 117-RPS220197 APPENDIX G Safety Data Sheets Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2019,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group:22-4025-7 Version Number:18.00 Issue Date:09/05/19 Supercedes Date:05/24/18 SECTION 1: Identification 1.1. Product identifier 3M™ Super 77™ Multipurpose Adhesive Product Identification Numbers LN-A100-0323-8, LN-A100-0323-9, LN-A100-0324-0, 44-0061-0114-9, 44-0061-0164-4, 62-4977-4030-8, 62-4977-4920-0, 62-4977-4926-7, 62-4977-4977-0, 70-0065-8412-5, 70-0065-9982-6, 70-0069-1448-8, 70-0069-1451-2, 70-0069-2063-4, 70- 0069-3662-2, 70-0069-3663-0, 70-0069-4021-0, 70-0069-4139-0, 70-0069-4245-5, 70-0069-4840-3, 70-0069-5039-1, 70- 0069-6344-4, 70-0069-6870-8, 70-0069-6871-6, 70-0069-7043-1, 70-0069-7049-8, 70-0069-7050-6, 70-0069-7053-0, 70- 0069-7255-1, 70-0069-7269-2, 70-0069-7276-7, 70-0069-7277-5, 70-0069-9030-6, 70-0069-9031-4, 70-0069-9972-9, 70- 0714-1653-4, 70-0714-1654-2, 70-0714-1656-7, 70-0714-7444-2, 70-0714-7572-0, 70-0714-7640-5, 70-0714-7930-0, 70- 0714-8259-3, 70-0714-8947-3 7000144616, 7010377290, 7010312936, 7100076970, 7100127332, 7100132610, 7100126874, 7100127350, 7100135536, 7100130406, 7100144892, 7100144897, 7100159784, 7100159783, 7100173162 1.2. Recommended use and restrictions on use Recommended use Adhesive aerosol, General Purpose Aerosol Adhesive 1.3. Supplier’s details MANUFACTURER:3M DIVISION:Construction and Home Improvement Markets ADDRESS:3M Center, St. Paul, MN 55144-1000, USA Telephone:1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 2 of 14 Serious Eye Damage/Irritation: Category 2A. Reproductive Toxicity: Category 2. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 3 of 14 Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Repeated exposure may cause skin dryness or cracking. Repeated exposure may cause skin dryness or cracking. Supplemental Information: Intentional concentration and inhalation may be harmful or fatal. 20% of the mixture consists of ingredients of unknown acute oral toxicity. 20% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No.% by Wt Acetone 67-64-1 20 - 30 Trade Secret * Non-volatile components (N.J.T.S. Registry No. 04499600-6433P) Trade Secret* 20 - 30 Trade Secret * Propane 74-98-6 15 - 25 Trade Secret * Cyclohexane 110-82-7 10 - 20 Trade Secret * Petroleum Distillates 64742-49-0 10 - 20 Trade Secret * Hexane 110-54-3 < 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 4 of 14 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 5 of 14 product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No.Agency Limit type Additional Comments Hexane 110-54-3 ACGIH TWA:50 ppm SKIN Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human carcin Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm) Propane 74-98-6 ACGIH Limit value not established:simple asphyxiant Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 6 of 14 Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Colorless Specific Physical Form: Aerosol Odor Fruity Odor Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point Not Applicable Flash Point -42.00 ºF [Test Method:Tagliabue Closed Cup] Evaporation rate 1.9 [Ref Std:ETHER=1] Flammability (solid, gas)Not Applicable Flammable Limits(LEL)No Data Available Flammable Limits(UEL)No Data Available Vapor Pressure No Data Available Vapor Density 2.97 [Ref Std:AIR=1] Density 0.726 g/ml Specific Gravity 0.726 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Hazardous Air Pollutants 0.4 % weight [Test Method:Calculated] Hazardous Air Pollutants 0.016 lb HAPS/lb solids [Test Method:Calculated] Hazardous Air Pollutants 0.02 lb HAPS/gal [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds Approximately 51 % [Test Method:calculated SCAQMD rule 443.1] Percent volatile <=75 % weight VOC Less H2O & Exempt Solvents <=458 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 7 of 14 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Dermal Defatting: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 8 of 14 nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation- Vapor (4 hours) Rat LC50 76 mg/l Acetone Ingestion Rat LD50 5,800 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Petroleum Distillates Inhalation- Vapor (4 hours) Rat LC50 > 14.7 mg/l Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Non-volatile components (N.J.T.S. Registry No. 04499600- 6433P) Dermal LD50 estimated to be > 5,000 mg/kg Non-volatile components (N.J.T.S. Registry No. 04499600- 6433P) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Hexane Dermal Rabbit LD50 > 2,000 mg/kg Hexane Inhalation- Vapor (4 hours) Rat LC50 170 mg/l Hexane Ingestion Rat LD50 > 28,700 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Propane Rabbit Minimal irritation Acetone Mouse Minimal irritation Cyclohexane Rabbit Mild irritant Petroleum Distillates Rabbit Irritant Non-volatile components (N.J.T.S. Registry No. 04499600-6433P)Professio nal judgeme nt Minimal irritation Hexane Human and animal Mild irritant Serious Eye Damage/Irritation Name Species Value Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 9 of 14 Propane Rabbit Mild irritant Acetone Rabbit Severe irritant Cyclohexane Rabbit Mild irritant Petroleum Distillates Rabbit Mild irritant Hexane Rabbit Mild irritant Skin Sensitization Name Species Value Petroleum Distillates Guinea pig Not classified Hexane Human Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Propane In Vitro Not mutagenic Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not sufficient for classification Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Petroleum Distillates In Vitro Not mutagenic Hexane In Vitro Not mutagenic Hexane In vivo Not mutagenic Carcinogenicity Name Route Species Value Acetone Not Specified Multiple animal species Not carcinogenic Petroleum Distillates Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hexane Dermal Mouse Not carcinogenic Hexane Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700 mg/kg/day 13 weeks Acetone Inhalation Not classified for development Rat NOAEL 5.2 mg/l during organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation Hexane Ingestion Not classified for development Mouse NOAEL 2,200 mg/kg/day during organogenesi s Hexane Inhalation Not classified for development Rat NOAEL 0.7 mg/l during gestation Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 90 days Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 10 of 14 mg/kg/day Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52 mg/l 28 days Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s)Value Species Test Result Exposure Duration Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation Not classified Human NOAEL Not available Acetone Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Acetone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 hours Acetone Inhalation liver Not classified Guinea pig NOAEL Not available Acetone Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Petroleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Hexane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Hexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL Not available 8 hours Hexane Inhalation respiratory system Not classified Rat NOAEL 24.6 mg/l 8 hours Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s)Value Species Test Result Exposure Duration Acetone Dermal eyes Not classified Guinea pig NOAEL Not available 3 weeks Acetone Inhalation hematopoietic system Not classified Human NOAEL 3 mg/l 6 weeks Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 days Acetone Inhalation kidney and/or bladder Not classified Guinea pig NOAEL 119 mg/l not available Acetone Inhalation heart | liver Not classified Rat NOAEL 45 8 weeks Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 11 of 14 mg/l Acetone Ingestion kidney and/or bladder Not classified Rat NOAEL 900 mg/kg/day 13 weeks Acetone Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion hematopoietic system Not classified Rat NOAEL 200 mg/kg/day 13 weeks Acetone Ingestion liver Not classified Mouse NOAEL 3,896 mg/kg/day 14 days Acetone Ingestion eyes Not classified Rat NOAEL 3,400 mg/kg/day 13 weeks Acetone Ingestion respiratory system Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion muscles Not classified Rat NOAEL 2,500 mg/kg 13 weeks Acetone Ingestion skin | bone, teeth, nails, and/or hair Not classified Mouse NOAEL 11,298 mg/kg/day 13 weeks Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks Hexane Inhalation peripheral nervous system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Mouse LOAEL 1.76 mg/l 13 weeks Hexane Inhalation liver Not classified Rat NOAEL Not available 6 months Hexane Inhalation kidney and/or bladder Not classified Rat LOAEL 1.76 mg/l 6 months Hexane Inhalation hematopoietic system Not classified Mouse NOAEL 35.2 mg/l 13 weeks Hexane Inhalation auditory system | immune system | eyes Not classified Human NOAEL Not available occupational exposure Hexane Inhalation heart | skin | endocrine system Not classified Rat NOAEL 1.76 mg/l 6 months Hexane Ingestion peripheral nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,140 mg/kg/day 90 days Hexane Ingestion endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL Not available 13 weeks Aspiration Hazard Name Value Cyclohexane Aspiration hazard Petroleum Distillates Aspiration hazard Hexane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 12 of 14 SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Reproductive toxicity Serious eye damage or eye irritation Simple Asphyxiant Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 13 of 14 Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 Trade Secret 10 - 20 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations This material contains one or more ingredients that may be regulated by the International Traffic in Arms Regulation (ITAR), an export control of US military technology and chemicals. Prior to export of this material or any product containing this material, determine whether a proper license from the Department of State must be obtained. See 22CFR 120-130 for any specific requirements. Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: *4 Flammability: 4 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group:22-4025-7 Version Number:18.00 Issue Date:09/05/19 Supercedes Date:05/24/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its Christensen Arms AO Modification 9/7/23 3M™ Super 77™ Multipurpose Adhesive 09/05/19 __________________________________________________________________________________________ Page 14 of 14 completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 API-334-3 Part A, Epoxy Resin Safety Data Sheet Product Identifier API-334-3 Part A, Epoxy Resin Other Means ofIdentification API-334-3 A Applied Poleramic, Inc., 6166 Egret Court, Benicia, CA, 94598, service@poleramic.com,707-747-6738, poleramic.com Recommended Use SDS No. Product Family Epoxy Resin Emergency Phone No. SECTION 1. IDENTIFICATION Manufacturer /Supplier Industrial Use Only. 0041 Chemtrec International, 703-527-3887, 24 hour Chemtrec US, 800-424-9300, 24 hours Restrictions on Use None known. Date of Preparation June 24, 2015 GHS Label Elements SECTION 2. HAZARDS IDENTIFICATION Signal Word:WarningHazard Statement(s):H315 Causes skin irritation.H317 May cause an allergic skin reaction.H411 Toxic to aquatic life with long lasting effects.Precautionary Statement(s): Prevention:P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P280 Wear protective gloves.P264 Wash hands thoroughly after handling.P273 Avoid release to the environment. Response:P302 + P352 IF ON SKIN: Wash with plenty of water.P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. Disposal:P501 Dispose of contents/container in accordance with local, regional, national and international regulations. GHS Classification Other Hazards None known. Skin corrosion/irritation - Category 2; Skin sensitization - Category 1; Aquatic hazard (Chronic) - Category 4 SDS No.: Date of Preparation: 0041 Page of 0501 June 24, 2015 Product Identifier: API-334-3 Part A, Epoxy Resin Christensen Arms AO Modification 9/7/23 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No.Other Identifiers% Mixture: Cyclohexanol, 4,4'-(1-methylethylidene)bis-,polymer with (chloromethyl)oxirane 30583-72-3 90-100 Inhalation Remove source of exposure or move to fresh air. Skin Contact Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. If skin irritation or arash occurs, get medical advice/attention. Eye Contact Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.If eye irritation persists, get medical advice/attention. Ingestion Do not induce vomiting; immediately call for medical help. First-aid Comments Some of the first-aid procedures recommended here require advanced first-aid training. SECTION 4. FIRST-AID MEASURES First-aid Measures Most Important Symptoms and Effects, Acute and Delayed None known. Extinguishing Media Suitable Extinguishing Media CO2, extinguishing powder or water spray. Fight larger fires with water spray. Use fire fighting measures that suitthe environment. Unsuitable Extinguishing Media None known. Specific Hazards Arising from the Chemical Heating increases the release of toxic vapour. Special Protective Equipment and Precautions for Fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA).A full-body encapsulating chemical protective suit with positive pressure SCBA may be necessary. SECTION 5. FIRE-FIGHTING MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use thepersonal protective equipment recommended in Section 8 of this safety data sheet. Environmental Precautions If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas. Methods and Materials for Containment and Cleaning Up Contain and soak up spill with absorbent that does not react with spilled product. Dike spilled product to prevent runoff. Other Information Report spills to local health, safety and environmental authorities, as required. SECTION 6. ACCIDENTAL RELEASE MEASURES SDS No.: Date of Preparation: 0041 Page of 0502 June 24, 2015 Product Identifier: API-334-3 Part A, Epoxy Resin Christensen Arms AO Modification 9/7/23 Report spills to local health, safety and environmental authorities, as required. Precautions for Safe Handling Only use where there is adequate ventilation. Wear personal protective equipment to avoid direct contact with thischemical. Keep containers tightly closed when not in use or empty. Conditions for Safe Storage Store in an area that is: well-ventilated. Empty containers may contain hazardous residue. Store separately. Keepclosed. Follow all precautions given on this safety data sheet. SECTION 7. HANDLING AND STORAGE SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Appropriate Engineering Controls Individual Protection Measures Skin Protection Respiratory Protection Eye/Face Protection SEN = Sensitization (skin and/or respiratory). Wear a NIOSH approved air-purifying respirator with an organic vapour cartridge. Wear chemical protective clothing e.g. gloves, aprons, boots. Wear chemical safety goggles. Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air. Appearance Clear colourless - yellow liquid. Odour Faint Flash Point > 115 ºC (239 ºF) Relative Density (water = 1)~ 1.14 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Basic Physical and Chemical Properties LiquidPhysical State Other Information Chemical Stability Normally stable. Conditions to Avoid None known. Incompatible Materials Polymerizes on contact with: amines (e.g. triethylamine), strong acids (e.g. hydrochloric acid), strong bases (e.g.sodium hydroxide), strong oxidizing agents (e.g. perchloric acid). Not corrosive to metals. Hazardous Decomposition Products Carbon monoxide and carbon dioxide. Possibility of Hazardous Reactions Reacts with acids, alkalis and oxidizing agents reacts with amines. SECTION 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions of use. SDS No.: Date of Preparation: 0041 Page of 0503 June 24, 2015 Product Identifier: API-334-3 Part A, Epoxy Resin Christensen Arms AO Modification 9/7/23 Skin Corrosion/Irritation Human experience and animal tests show mild irritation. Serious Eye Damage/Irritation There is limited evidence of mild irritation. SECTION 11. TOXICOLOGICAL INFORMATION STOT (Specific Target Organ Toxicity) - Single Exposure Inhalation Reactive airways dysfunction syndrome (RADS). Skin Absorption Symptoms may include redness, rash, swelling and itching. Ingestion Irritation of the mouth, throat and stomach. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. STOT (Specific Target Organ Toxicity) - Repeated Exposure Respiratory and/or Skin Sensitization Respiratory sensitizer. Skin sensitizer. In sensitized people, exposure to a very small amount of product can causesymptoms including wheezing, difficult breathing, sneezing and runny or blocked nose. Can cause death. Symptomscan develop immediately following exposure or hours later. Repeated exposure will make the reaction worse. Carcinogenicity Not known to cause cancer. Development of Offspring Not known to harm the unborn child. Reproductive Toxicity Not known to cause effects on sexual function or fertility. Germ Cell Mutagenicity No information was located. Interactive Effects No information was located. Acute Toxicity Sexual Function and Fertility Effects on or via Lactation Not known to cause effects on or via lactation. Symptoms may include coughing, choking, shortness of breath, difficult or rapid breathing, and wheezing. Aspiration Hazard Skin absorption; eye contact. Likely Routes of Exposure Chemical Name LC50 LD50 (oral)LD50 (dermal) Cyclohexanol, 4,4'-(1-methylethylidene)bis-,polymer with(chloromethyl)oxirane 10000-11400 mg/kg (rat) SECTION 12. ECOLOGICAL INFORMATION Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Not readilybiodegradable. This product shows a low bioaccumulation potential. Toxicity SDS No.: Date of Preparation: 0041 Page of 0504 June 24, 2015 Product Identifier: API-334-3 Part A, Epoxy Resin Christensen Arms AO Modification 9/7/23 No information was located. There is no information available. No ingredient of this product or its degradation products is known to be highly persistent. Toxicity Persistence and Degradability Mobility in Soil Other Adverse Effects Acute Aquatic Toxicity Chemical Name LC50 Fish EC50 Crustacea ErC50 AquaticPlants ErC50 Algae Cyclohexanol, 4,4'-(1-methylethylidene)bis -, polymer with(chloromethyl)oxirane 1-10 mg/L SECTION 13. DISPOSAL CONSIDERATIONS Bury in a licensed landfill or burn in an approved incinerator according to federal, provincial/state, and local regulations. Disposal Methods SECTION 14. TRANSPORT INFORMATION Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations. Special Precautionsfor User Not applicable Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15. REGULATORY INFORMATION Canada Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL) All ingredients are listed on the DSL or are not required to be listed. USA Toxic Substances Control Act (TSCA) Section 8(b) All ingredients are listed on the TSCA Inventory. Safety, Health and Environmental Regulations SECTION 16. OTHER INFORMATION NFPA Rating SDS Prepared By Doyle Dixon Phone No.707-747-6738 Date of Preparation June 24, 2015 Health - 2 Flammability - 1 Instability - 0 SDS No.: Date of Preparation: 0041 Page of 0505 June 24, 2015 Product Identifier: API-334-3 Part A, Epoxy Resin Christensen Arms AO Modification 9/7/23 API-334-3 Part B, Epoxy Hardener Safety Data Sheet Product Identifier API-334-3 Part B, Epoxy Hardener Other Means ofIdentification API-334-3 B Applied Poleramic, Inc., 6166 Egret Court, Benicia, CA, 94598, service@poleramic.com,707-747-6738, poleramic.com Recommended Use SDS No. Product Family Amine Hardener Emergency Phone No. SECTION 1. IDENTIFICATION Manufacturer /Supplier Industrial Use Only. 0046 Chemtrec International, 703-527-3887, 24 hour Chemtrec US, 800-424-9300, 24 hours Restrictions on Use None known. Date of Preparation June 24, 2015 GHS Label Elements SECTION 2. HAZARDS IDENTIFICATION DangerHazard Statement(s):H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.H332 Harmful if inhaled.H412 Harmful to aquatic life with long lasting effects.Precautionary Statement(s): Prevention:P264 Wash hands and skin thoroughly after handling.P280 Wear protective gloves/protective clothing/eye protection/face protection. Response:P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P363 Wash contaminated clothing before reuse. Disposal:P501 Dispose of contents/container in accordance with local, regional, national and international regulations. GHS Classification Acute toxicity (Oral) - Category 4; Skin corrosion/irritation - Category 1B; Serious eye damage/eye irritation - Category2A; Skin sensitization - Category 1B; Aquatic hazard (Chronic) - Category 3 SDS No.: Date of Preparation: 0046 Page of 0601 June 24, 2015 Product Identifier: API-334-3 Part B, Epoxy Hardener Christensen Arms AO Modification 9/7/23 P363 Wash contaminated clothing before reuse. Disposal:P501 Dispose of contents/container in accordance with local, regional, national and international regulations. Other Hazards Warning. May be a health hazard in confined spaces. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No.Other Identifiers% Mixture: Isophorone diamine 2855-13-2 90-100 Inhalation Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment).Remove source of exposure or move to fresh air. If experiencing respiratory symptoms (e.g. coughing, shortness ofbreath, wheezing), call a Poison Centre or doctor. Immediately call a Poison Centre or doctor. Skin Contact Avoid direct contact. Wear chemical protective clothing if necessary. Take off contaminated clothing, shoes andleather goods (e.g. watchbands, belts). Immediately rinse with lukewarm, gently flowing water for 15-20 minutes. Ifskin irritation occurs get medical advice/attention. Eye Contact Avoid direct contact. Wear chemical protective gloves if necessary. Immediately rinse the contaminated eye(s) withlukewarm, gently flowing water for 15-20 minutes, while holding the eyelid(s) open. If eye irritation persists, getmedical advice/attention. Ingestion Rinse mouth with water. Never give anything by mouth if victim is rapidly losing consciousness, or is unconsciousor convulsing. Do not induce vomiting. Get medical advice/attention if you feel unwell or are concerned. Special Instructions Not applicable. SECTION 4. FIRST-AID MEASURES First-aid Measures Immediate Medical Attention and Special Treatment Medical Conditions Aggravated by Exposure None known. Target Organs Lungs, respiratory system, skin. Most Important Symptoms and Effects, Acute and Delayed If on skin: may cause moderate to severe irritation. If in eyes: may cause moderate to severe irritation. May be harmful if swallowed may cause sensitization by skin contact. Extinguishing Media Suitable Extinguishing Media Use water to keep non-leaking, fire-exposed containers cool. Unsuitable Extinguishing Media None known. Specific Hazards Arising from the Chemical SECTION 5. FIRE-FIGHTING MEASURES SDS No.: Date of Preparation: 0046 Page of 0602 June 24, 2015 Product Identifier: API-334-3 Part B, Epoxy Hardener Christensen Arms AO Modification 9/7/23 Specific Hazards Arising from the Chemical Heating increases the release of toxic vapour.In a fire, the following hazardous materials may be generated: very toxic carbon monoxide, carbon dioxide; corrosive,oxidizing nitrogen oxides. Special Protective Equipment and Precautions for Fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA).Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary. Personal Precautions, Protective Equipment, and Emergency Procedures Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Do nottouch damaged containers or spilled product unless wearing appropriate protective equipment. Increase ventilation toarea or move leaking container to a well-ventilated and secure area. Environmental Precautions Do not allow into any sewer, on the ground or into any waterway. If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas. Methods and Materials for Containment and Cleaning Up Small spills or leaks: stop or reduce leak if safe to do so. Contain and soak up spill with absorbent that does not reactwith spilled product. Place used absorbent into suitable, covered, labelled containers for disposal. Large spills or leaks:dike spilled product to prevent runoff. Collect using shovel/scoop or approved HEPA vacuum and place in a suitablecontainer for disposal. SECTION 6. ACCIDENTAL RELEASE MEASURES Precautions for Safe Handling Do not breathe in this product. Prevent all skin contact. Do not get in eyes. Only use where there is adequateventilation. Immediately report leaks, spills or failures of the safety equipment (e.g. ventilation system). If product istransferred to another container, ensure new container is suitable for the product. Wear personal protective equipmentto avoid direct contact with this chemical. Do NOT eat, drink or store food in work areas. Remove contaminated clothingand protective equipment before entering eating areas or leaving work area. Wash hands thoroughly after handling thismaterial. Conditions for Safe Storage Store in an area that is: ventilated. Store in corrosive resistant container with a resistant inner liner. Empty containersmay contain hazardous residue. Store separately. Keep closed. Follow all precautions given on this safety data sheet.Comply with all applicable health and safety regulations, fire and building codes. SECTION 7. HANDLING AND STORAGE SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Appropriate Engineering Controls Individual Protection Measures Skin Protection Respiratory Protection Eye/Face Protection Wear a NIOSH approved air-purifying respirator with an organic vapour cartridge. Wear chemical protective clothing e.g. gloves, aprons, boots.Butyl rubber, neoprene rubber, nitrile rubber. Wear chemical safety goggles. In a confined space: general ventilation is usually adequate. For large scale use of this product: do not allow product toaccumulate in the air in work or storage areas, or in confined spaces. Provide eyewash and safety shower if contact orsplash hazard exists. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Basic Physical and Chemical Properties SDS No.: Date of Preparation: 0046 Page of 0603 June 24, 2015 Product Identifier: API-334-3 Part B, Epoxy Hardener Christensen Arms AO Modification 9/7/23 pH > 12 Appearance Colourless liquid. Odour Ammonia-like Flash Point 117 ºC (243 ºF) Relative Density (water = 1)0.92 (estimated) Solubility Soluble (more than 10-50%) in water Basic Physical and Chemical Properties LiquidPhysical State Other Information Chemical Stability Normally stable. Conditions to Avoid Open flames, sparks, static discharge, heat and other ignition sources. Incompatible Materials Strong acids (e.g. hydrochloric acid), strong oxidizing agents (e.g. perchloric acid). Hazardous Decomposition Products Ammonia. Possibility of Hazardous Reactions None expected under normal conditions of storage and use. SECTION 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions of use. Skin Corrosion/Irritation Animal tests show moderate or severe irritation. Serious Eye Damage/Irritation Causes serious eye irritation based on skin irritation information. SECTION 11. TOXICOLOGICAL INFORMATION STOT (Specific Target Organ Toxicity) - Single Exposure Inhalation Symptoms may include coughing, shortness of breath, difficult breathing and tightness in the chest. Skin Absorption Corrosive to skin. Causes burns. May cause sensitization by skin contact. Ingestion Harmful if swallowed. May cause burns to mouth throat and stomach. Acute Toxicity Severely irritating to the respiratory system harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs andcause damage. May cause burns to mouth, throat and stomach. Corrosive to the skin. Causes burns. Corrosive to theeyes. Causes burns. Can cause lung damage if aspirated based on human experience. Aspiration Hazard Inhalation; skin contact; eye contact. Likely Routes of Exposure Chemical Name LC50 LD50 (oral)LD50 (dermal) Isophorone diamine 1030 mg/kg (rat) SDS No.: Date of Preparation: 0046 Page of 0604 June 24, 2015 Product Identifier: API-334-3 Part B, Epoxy Hardener Christensen Arms AO Modification 9/7/23 Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. STOT (Specific Target Organ Toxicity) - Repeated Exposure Respiratory and/or Skin Sensitization In sensitized people, exposure to a very small amount of product can cause symptoms including wheezing, difficultbreathing, sneezing and runny or blocked nose. Can cause death. Symptoms can develop immediately following exposure or hours later. Repeated exposure will make the reaction worse. Carcinogenicity Not known to cause cancer. Development of Offspring Not known to harm the unborn child. Reproductive Toxicity Not known to cause effects on sexual function or fertility. Germ Cell Mutagenicity Not known to be a mutagen. Interactive Effects No information was located. Key to Abbreviations A5 = Not suspected as a human carcinogen. Sexual Function and Fertility Effects on or via Lactation Not known to cause effects on or via lactation. Can cause lung damage if aspirated based on human experience. This product and its degradation products not expected to bioaccumulate based on the n-octanol/water partitioncoefficient (Log Kow). SECTION 12. ECOLOGICAL INFORMATION Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Not readilybiodegradable. This product shows a low bioaccumulation potential. Does not degrade rapidly based on quantitative tests. Toxicity Persistence and Degradability Bioaccumulative Potential Acute Aquatic Toxicity Chemical Name LC50 Fish EC50 Crustacea ErC50 AquaticPlants ErC50 Algae Isophorone diamine 110 mg/L (96-hour;semi-static) 23 mg/L (Daphniamagna (water flea);48-hour; static) 37 mg/L (72-hour;static) SECTION 13. DISPOSAL CONSIDERATIONS This product and its container must be disposed of as hazardous waste. Do NOT dump into any sewers, on the groundor into any body of water. Dispose of or recycle empty containers through an approved waste management facility. Disposal Methods SECTION 14. TRANSPORT INFORMATION UN No.Proper Shipping Name Packing Group Transport Hazard Class(es)Regulation SDS No.: Date of Preparation: 0046 Page of 0605 June 24, 2015 Product Identifier: API-334-3 Part B, Epoxy Hardener Christensen Arms AO Modification 9/7/23 UN 1760 Corrosive Liquid, N.O.S. (Alkyl Polyamine)8 IIIUS DOT UN 1760 Corrosive Liquid, N.O.S (Alkyl Polyamine)8 IIICanadian TDG UN 1760 Corrosive Liquid, N.O.S (Alkyl Polyamine)8 IIIIMO (Marine) Special Precautions for User Not applicable Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15. REGULATORY INFORMATION Canada WHMIS Classification Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL) All ingredients are listed on the DSL or are not required to be listed. USA Toxic Substances Control Act (TSCA) Section 8(b) All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by the Controlled Products Regulations. Safety, Health and Environmental Regulations Class EClass D2A; D2B D2A - Very Toxic (Chronic toxicity); D2B - Toxic (Skin irritant; Eye irritant; Skin sensitization); E - Corrosive SECTION 16. OTHER INFORMATION NFPA Rating SDS Prepared By Doyle Dixon Phone No.707-747-6738 Date of Preparation June 24, 2015 Health - 3 Flammability - 1 Instability - 0 SDS No.: Date of Preparation: 0046 Page of 0606 June 24, 2015 Product Identifier: API-334-3 Part B, Epoxy Hardener Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 SAFETY DATA SHEET Lubricating Oil According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200 1. Identification Product identifier Product name Lubricating Oil Chemical name Process Oil Product number 1003, 1003B, 1003RB, 1003CN Internal identification 1000-202 CAS number 64742-54-7 Recommended use of the chemical and restrictions on use Application Firearm Lubrication Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer Bushnell Holdings Inc 9200 Cody Overland Park, KS 66214 1-800-423-3537 dangerous.goods@vistaoutdoor.com Emergency telephone number Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) - (CHEMTREC, Day and Night) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Not Classified Health hazards Not Classified Environmental hazards Not Classified Label elements Hazard statements NC Not Classified Other hazards This substance is not classified as PBT or vPvB according to current EU criteria. 3. Composition/information on ingredients Substances Product name Lubricating Oil Chemical name Process Oil CAS number 64742-54-7 4. First-aid measures Description of first aid measures 1/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medical personnel. Inhalation No specific recommendations. If throat irritation or coughing persists, proceed as follows. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if any discomfort continues. Ingestion No specific recommendations. If throat irritation or coughing persists, proceed as follows. Rinse mouth. Get medical attention if any discomfort continues. Skin Contact No specific recommendations. Rinse with water. Get medical attention if any discomfort continues. Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical attention if any discomfort continues. Protection of first aiders Use protective equipment appropriate for surrounding materials. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation. Ingestion No specific symptoms known. May cause discomfort if swallowed. Skin contact No specific symptoms known. May cause discomfort. Eye contact No specific symptoms known. May be slightly irritating to eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. Specific treatments No special treatment required. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 2/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions No specific recommendations. For personal protection, see Section 8. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Methods and material for containment and cleaning up Methods for cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Dispose of contents/container in accordance with national regulations. Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). No specific recommendations. Storage class Unspecified storage. Specific end uses(s) Specific end use(s)The identified uses for this product are detailed in Section 1. 8. Exposure Controls/personal protection Control parameters Occupational exposure limits Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³ Long-term exposure limit (8-hour TWA): ACGIH 5 mg/m³ Short-term exposure limit (15-minute): ACGIH 10 mg/m³ OSHA = Occupational Safety and Health Administration. ACGIH = American Conference of Governmental Industrial Hygienists. Exposure controls Protective equipment Appropriate engineering controls No specific ventilation requirements. Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. 3/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves. Other skin and body protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke when using this product. Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Not regarded as dangerous for the environment. 9. Physical and Chemical Properties Information on basic physical and chemical properties Appearance Clear liquid. Color Water-white. Odor Odorless. pH Not applicable. Melting point Not determined. Initial boiling point and range 315°C/599°F Flash point 192°C/378°F Evaporation rate No information available. Flammability (solid, gas)Class IIIB Liquid Upper/lower flammability or explosive limits Not available. Vapor pressure < 0.01 mm Hg @ 25°C Vapor density > 1.0 g/cc Relative density 0.866 Bulk density 7.228 lb/gal Solubility(ies)Insoluble in water. Partition coefficient Not determined. Auto-ignition temperature 210°C/410°F Decomposition Temperature Not determined. Volatility 3% wt (Max) 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions No potentially hazardous reactions known. 4/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil Conditions to avoid There are no known conditions that are likely to result in a hazardous situation. Materials to avoid No specific material or group of materials is likely to react with the product to produce a hazardous situation. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. 11. Toxicological information Information on toxicological effects Toxicological effects Not regarded as a health hazard under current legislation. Acute toxicity - oral Notes (oral LD₅₀)Based on available data the classification criteria are not met. Acute toxicity - dermal Notes (dermal LD₅₀)Based on available data the classification criteria are not met. Acute toxicity - inhalation Notes (inhalation LC₅₀)Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Based on available data the classification criteria are not met. Serious eye damage/irritation Serious eye damage/irritation Based on available data the classification criteria are not met. Respiratory sensitization Respiratory sensitization Based on available data the classification criteria are not met. Skin sensitization Skin sensitization Based on available data the classification criteria are not met. Germ cell mutagenicity Genotoxicity - in vitro Based on available data the classification criteria are not met. Carcinogenicity Carcinogenicity Based on available data the classification criteria are not met. IARC carcinogenicity None of the ingredients are listed or exempt. Reproductive toxicity Reproductive toxicity - fertility Based on available data the classification criteria are not met. Reproductive toxicity - development Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure STOT - single exposure Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Based on available data the classification criteria are not met. 5/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil General information No specific health hazards known. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation. Ingestion No specific symptoms known. May cause discomfort if swallowed. Skin Contact No specific symptoms known. May cause discomfort. Eye contact No specific symptoms known. May be slightly irritating to eyes. Route of entry Ingestion Inhalation Skin and/or eye contact Target Organs No specific target organs known. 12. Ecological Information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment. Toxicity Based on available data the classification criteria are not met. Persistence and degradability Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient Not determined. Mobility in soil Mobility No data available. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste packaging should be collected for reuse or recycling. Incineration or landfill should only be considered when recycling is not feasible. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of the local water authority. 14. Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, DOT). UN Number Not applicable. UN proper shipping name Not applicable. 6/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil Transport hazard class(es) No transport warning sign required. Packing group Not applicable. Environmental hazards Environmentally Hazardous Substance No. Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. 15. Regulatory information US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) None of the ingredients are listed or exempt. SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting None of the ingredients are listed or exempt. CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories None of the ingredients are listed or exempt. OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-I) None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. 7/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil California Directors List of Hazardous Substances None of the ingredients are listed or exempt. Massachusetts "Right To Know" List None of the ingredients are listed or exempt. Rhode Island "Right To Know" List None of the ingredients are listed or exempt. Minnesota "Right To Know" List None of the ingredients are listed or exempt. New Jersey "Right To Know" List None of the ingredients are listed or exempt. Pennsylvania "Right To Know" List None of the ingredients are listed or exempt. Inventories US - TSCA None of the ingredients are listed or exempt. US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information Classification abbreviations and acronyms Asp. Tox. = Aspiration hazard Training advice Only trained personnel should use this material. Revision date 2/8/2019 Revision 7 Supersedes date 10/9/2017 SDS No.4634 End of Safety Data Sheet This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8/8Christensen Arms AO Modification 9/7/23      EU/EEC  According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]   Safety Data Sheet    Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • CR­10 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s)•Cleaning 1.3 Details of the supplier of the safety data sheet Manufacturer •Barnes Bullets PO Box 620 Mona, UT 84645 United States  www.barnesbullets.com email@barnesbullets.com  Telephone (General)•(435) 856­1000  1.4 Emergency telephone number Manufacturer •(435) 856­1000  Section 2: Hazards Identification 2.1 Classification of the substance or mixture CLP • Oxidizing Liquids 3 ­ H272 Acute Toxicity Oral 4 ­ H302 Acute Toxicity Dermal 3 ­ H311 Skin Corrosion 1B ­ H314 Serious Eye Damage 1 ­ H318 Acute Toxicity Inhalation 3 ­ H331 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation ­ H335 Reproductive Toxicity 1B ­ H360D  2.2 Label Elements CLP DANGER  Hazard statements •H272 ­ May intensify fire; oxidizer H302 ­ Harmful if swallowed  CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 1 of 14Page 1 of 14Page 1 of 14Page 1 of 14Christensen Arms AO Modification 9/7/23 United States (US)  According to: OSHA 29 CFR 1910.1200 HCS   H311 ­ Toxic in contact with skin H314 ­ Causes severe skin burns and eye damage. H318 ­ Causes serious eye damage H331 ­ Toxic if inhaled H335 ­ May cause respiratory irritation H360D ­ May damage the unborn child.  Precautionary statements Prevention •P201 ­ Obtain special instructions before use. P202 ­ Do not handle until all safety precautions have been read and understood. P210 ­ Keep away from heat. P220 ­ Keep/Store away from clothing and other combustible materials. P221 ­ Take any precaution to avoid mixing with combustibles P260 ­ Do not breathe mists, vapours, and/or spray. P264 ­ Wash thoroughly after handling. P270 ­ Do not eat, drink or smoke when using this product. P271 ­ Use only outdoors or in a well­ventilated area. P280 ­ Wear protective gloves/protective clothing/eye protection/face protection. P281 ­ Use personal protective equipment as required.  Response •P370+P378 ­ In case of fire: Use appropriate media for extinction. P304+P340 ­ IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311 ­ Call a POISON CENTER or doctor/physician. P303+P361+P353 ­ IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P310 ­ Immediately call a POISON CENTER or doctor/physician. P321 ­ Specific treatment, see supplemental first aid information. P363 ­ Wash contaminated clothing before reuse. P305+P351+P338 ­ IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P312 ­ IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell. P330 ­ Rinse mouth. P331 ­ Do NOT induce vomiting. P308+P313 ­ IF exposed or concerned: Get medical advice/attention.  Storage/Disposal •P403+P233 ­ Store in a well­ventilated place. Keep container tightly closed. P405 ­ Store locked up. P501 ­ Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.  Supplemental information •This product consists of ingredients of unknown toxicity: 45% via oral route, 80­90% via inhalation route, 80­90% via dermal route.  2.3 Other Hazards CLP •According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous.  2.1 Classification of the substance or mixture OSHA HCS 2012 •Oxidizing Liquids 3 Acute Toxicity Oral 4 Acute Toxicity Dermal 3 Skin Irritation 2 Serious Eye Damage 1 Acute Toxicity Inhalation 3 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Reproductive Toxicity 1B Specific Target Organ Toxicity Repeated Exposure 2  2.2 Label elements CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 2 of 14Page 2 of 14Page 2 of 14Page 2 of 14Christensen Arms AO Modification 9/7/23 Canada  According to: WHMIS    OSHA HCS 2012 DANGER  Hazard statements •May intensify fire; oxidizer Harmful if swallowed Toxic in contact with skin Causes skin irritation Causes serious eye damage Toxic if inhaled May cause respiratory irritation May cause drowsiness or dizziness May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure.  Precautionary statements Prevention •Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles Do not breathe mists, vapours, and/or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well­ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.  Response •In case of fire: Use appropriate media for extinction. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. If on skin: Wash with plenty of water . Specific treatment, see supplemental first aid information. Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell.  Storage/Disposal •Store in a well­ventilated place. Keep container tightly closed. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.  Supplemental information •This product consists of ingredients of unknown toxicity: 45% via oral route, 80­90% via inhalation route, 80­90% via dermal route.  2.3 Other hazards OSHA HCS 2012 •Under United States Regulations (29 CFR 1910.1200 ­ Hazard Communication Standard), this product is considered hazardous. 2.1 Classification of the substance or mixture WHMIS •Oxidizing ­ C Toxic ­ D1B  CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 3 of 14Page 3 of 14Page 3 of 14Page 3 of 14Christensen Arms AO Modification 9/7/23         Other Toxic Effects ­ D2A Corrosive ­ E  2.2 Label elements WHMIS •Oxidizing ­ C Toxic ­ D1B Other Toxic Effects ­ D2A Corrosive ­ E  2.3 Other hazards WHMIS •In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS).  Section 3 ­ Composition/Information on Ingredients 3.1 Substances •Material does not meet the criteria of a substance. 3.2 Mixtures Composition Chemical Name Identifiers %LD50/LC50 Classifications According to Regulation/Directive Comments Proprietary  Blend NDA 0% TO  100%  NDA EU CLP: Not Classified  OSHA HCS 2012: Not Classified NDA Ethylene glycol  monobutyl ether  CAS:111­76­2  EC  Number:203­ 905­0  EU Index:603­ 014­00­0 10%  TO  20%   Inhalation­Rat  LC50 • 450 ppm 4  Hour(s) Skin­Rabbit LD50 •  220 mg/kg Ingestion/Oral­Rat  LD50 • 250 mg/kg EU CLP: Annex VI, Table 3.1: Acute Tox. 3, H301;  Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Irrit. 2,  H315; Eye Irrit. 2, H319  OSHA HCS 2012: Flam. Liq. 4; Acute Tox. 3 (Orl);  Acute Tox. 3 (Skn); Acute Tox. 3 (Inhl); Eye Irrit. 2;  Repr. 2; STOT SE 3: Narc.; STOT SE 3: Resp. Irrit.  (Orl); STOT RE 2 (Blood, Inhl, Orl, Skn)  NDA Sodium nitrate  CAS:7631­99­4  EC  Number:231­ 554­3 10%  TO  15%   Ingestion/Oral­Rat  LD50 • 1267 mg/kg EU CLP: Skin Irrit. 2, H315; Eye Irrit. 2, H319; Acute  Tox. 4, H302; Ox. Sol. 3, H272  OSHA HCS 2012: Skin Irrit. 2; Eye Irrit. 2A; STOT SE  3: Resp. Irrit.; Acute Tox. 4 (Orl); Ox. Sol. 3  NDA Ammonium  hydroxide  CAS:1336­21­6  EC  Number:215­ 647­6  EU Index:007­ 001­01­2 5% TO  10%   Ingestion/Oral­Rat  LD50 • 350 mg/kg EU CLP: Annex VI, Table 3.1: Skin Corr. 1B, H314;  Aquatic Acute 1, H400   OSHA HCS 2012: Acute Tox. 3 (Orl); Eye Dam. 1;  Skin Corr. 1C; STOT SE 3: Resp. Irrit.  NDA 2­Pyrrolidinone,  1­methyl­  CAS:872­50­4  EC  Number:212­ 828­1  EU Index:606­ 021­00­7 5% TO  10%   Ingestion/Oral­Rat  LD50 • 3914 mg/kg Skin­Rabbit LD50 • 8  g/kg EU CLP: Annex VI, Table 3.1: Repr. 1B, H360D ***;  Eye Irrit. 2, H319; STOT SE 3: Resp. Irrit., H335; Skin  Irrit. 2, H315   OSHA HCS 2012: Eye Irrit. 2; Repr. 1B; Skin Irrit. 2;  Skin Sens. 1  NDA CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 4 of 14Page 4 of 14Page 4 of 14Page 4 of 14Christensen Arms AO Modification 9/7/23 See Section 16 for full text of H­statements.  Section 4 ­ First Aid Measures 4.1 Description of first aid measures Inhalation • Move victim to fresh air. Administer oxygen if breathing is difficult. Do not use mouth­to­mouth method if victim inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one­way valve or other proper respiratory medical device. Give artificial respiration if victim is not breathing. Get medical attention immediately. Skin • For minor skin contact, avoid spreading material on unaffected skin. In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Remove and isolate contaminated clothing. Get medical attention immediately. Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Ingestion • If swallowed, rinse mouth with water.(only if the person is conscious). Do NOT induce vomiting. Do not use mouth­to­mouth method if victim ingested the substance. Obtain medical attention immediately if ingested. 4.2 Most important symptoms and effects, both acute and delayed •Refer to Section 11 ­ Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician • All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 ­ Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media • SMALL FIRES: Use water. SMALL FIRES: CO2 or Halon® may provide limited control. LARGE FIRE: Flood fire area with water from a distance.  Unsuitable Extinguishing Media • SMALL FIRES: Do not use dry chemicals or foams.  5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards • Containers may explode when heated. May explode from heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.) Runoff may create fire or explosion hazard. Some may decompose explosively when heated or involved in a fire. Some will react explosively with hydrocarbons (fuels) These substances will accelerate burning when involved in a fire.  Hazardous Combustion Products • This product is not defined as flammable or combustible; however, under fire conditions it may support combustion and produce toxic oxides of carbon and various hydrocarbons.  5.3 Advice for firefighters •Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Wear positive pressure self­contained breathing apparatus (SCBA). Move containers from fire area if you can do it without risk.  Section 6 ­ Accidental Release Measures CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 5 of 14Page 5 of 14Page 5 of 14Page 5 of 14Christensen Arms AO Modification 9/7/23 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions • Ventilate enclosed areas. Do not walk through spilled material. Avoid contact with skin, eyes or clothing. Wear a self­contained breathing apparatus and appropriate Personal Protective Equipment (PPE) Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Contaminated clothing may be a fire risk when dry. Emergency Procedures • LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet) As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep combustibles (wood, paper, oil, etc.) away from spilled material. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Do not get water inside container. 6.2 Environmental precautions •Prevent entry into waterways, sewers, basements or confined areas. 6.3 Methods and material for containment and cleaning up Containment/Clean­up Measures • LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Following product recovery, flush area with water. SMALL LIQUID SPILLS: Use a non­combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.  6.4 Reference to other sections •Refer to Section 8 ­ Exposure Controls/Personal Protection and Section 13 ­ Disposal Considerations. Section 7 ­ Handling and Storage 7.1 Precautions for safe handling Handling •Handle and open container with care. Use only with adequate ventilation. Use caution when combining with water; DO NOT add water to corrosive liquid, ALWAYS add corrosive liquid to water while stirring to prevent release of heat, steam and fumes. Do not breathe mist, vapours, and/or spray. Do not get in eyes, on skin, or on clothing. Wear appropriate personal protective equipment, avoid direct contact. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 7.2 Conditions for safe storage, including any incompatibilities Storage • Keep container tightly closed. Store in a cool, dry, well­ventilated place. 7.3 Specific end use(s) •Refer to Section 1.2 ­ Relevant identified uses. Section 8 ­ Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result ACGIH NIOSH OSHA Ethylene glycol  monobutyl ether  (111­76­2) TWAs 20 ppm TWA 5 ppm TWA; 24 mg/m3 TWA 50 ppm TWA; 240 mg/m3 TWA 8.2 Exposure controls Engineering Measures/Controls • Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable  CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 6 of 14Page 6 of 14Page 6 of 14Page 6 of 14Christensen Arms AO Modification 9/7/23   level. Use explosion­proof electrical/ventilating/lighting/equipment. Personal Protective Equipment Respiratory •In case of insufficient ventilation, wear suitable respiratory equipment. Eye/Face •Wear chemical splash safety goggles. Skin/Body •Wear appropriate gloves. Wear long sleeves and/or protective coveralls. Environmental Exposure Controls • Follow best practice for site management and disposal of waste. Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Key to abbreviations ACGIH=American Conference of Governmental Industrial Hygiene NIOSH=National Institute of Occupational Safety and Health OSHA =Occupational Safety and Health Administration TWA =Time­Weighted Averages are based on 8h/day, 40h/week exposures Section 9 ­ Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Material Description   Physical Form Liquid Appearance/Description Light yellow to dark amber liquid  with strong ammonia odor. Color Light yellow to dark amber.Odor Strong ammonia. Odor Threshold Data lacking   General Properties   Boiling Point Data lacking Melting Point/Freezing Point Data lacking Decomposition Temperature Data lacking pH Data lacking Specific Gravity/Relative Density = 1.1 Water=1 Water Solubility Soluble 100 % Viscosity Data lacking Explosive Properties Data lacking Oxidizing Properties: Data lacking   Volatility   Vapor Pressure Data lacking Vapor Density Data lacking Evaporation Rate Data lacking   Flammability   Flash Point > 200 F(> 93.3333 C)UEL Data lacking LEL Data lacking Autoignition Data lacking Flammability (solid, gas) Data lacking   Environmental   Octanol/Water Partition coefficient Data lacking   9.2 Other Information •No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity •No dangerous reaction known under conditions of normal use. 10.2 Chemical stability •Stable under normal temperatures and pressures. CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 7 of 14Page 7 of 14Page 7 of 14Page 7 of 14Christensen Arms AO Modification 9/7/23   10.3 Possibility of hazardous reactions •Hazardous polymerization will not occur. 10.4 Conditions to avoid •Exposure to high temperatures. 10.5 Incompatible materials •Strong oxidizing agents. 10.6 Hazardous decomposition products •Toxic oxides of carbon and hydrocarbons. Section 11 ­ Toxicological Information 11.1 Information on toxicological effects Components Ethylene glycol  monobutyl ether  (10% TO 20%) 111­ 76­2 Acute Toxicity:Ingestion/Oral­Rat LD50 • 250 mg/kg; Ingestion/Oral­Man TDLo • 132 mg/kg; Behavioral:Sleep; Kidney,  Ureter, and Bladder:Hematuria; Nutritional and Gross Metabolic:Changes in Chemistry or Temperature:Metabolic  acidosis; Inhalation­Rat LC50 • 450 ppm 4 Hour(s); Behavioral:Ataxia; Nutritional and Gross Metabolic:Gross  Metabolite Changes:Weight loss or decreased weight gain; Skin­Rabbit LD50 • 220 mg/kg;   Irritation:Eye­Rabbit • 100 mg 24 Hour(s) • Moderate irritation; Skin­Rabbit • 500 mg­Open • Mild irritation;   Multi­dose Toxicity:Inhalation­Monkey TCLo • 500 mg/m³ 7 Hour(s) 12 Week(s)­Intermittent; Blood:Normocytic  anemia; Blood:Changes in serum composition (e.g., TP, bilirubin cholesterol); Inhalation­Rat TCLo • 10 mg/m³  90 Day(s)­Continuous; Endocrine:Hypoglycemia; Blood:Normocytic anemia; Nutritional and Gross  Metabolic:Gross Metabolite Changes:Weight loss or decreased weight gain; Inhalation­Rat TCLo • 10 mg/m³ 24  Hour(s) 13 Week(s)­Continuous; Endocrine:Hypoglycemia; Blood:Changes in erythrocyte (RBC) count;  Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:Transaminases; Skin­Rabbit TDLo •  4500 µL/kg 9 Day(s)­Intermittent; Liver:Changes in liver weight; Blood:Pigmented or nucleated red blood cells;  Blood:Changes in erythrocyte (RBC) count;   Reproductive:Ingestion/Oral­Rat TDLo • 600 mg/kg (9­11D preg); Reproductive Effects:Effects on Embryo or  Fetus:Fetal death; Inhalation­Rabbit TCLo • 100 ppm 6 Hour(s)(6­18D preg); Reproductive Effects:Specific  Developmental Abnormalities:Cardiovascular (circulatory) system; Inhalation­Rabbit TCLo • 483 mg/m³ (6H/6­15D  preg); Reproductive Effects:Effects on Fertility:Pre­implantation mortality; Reproductive Effects:Effects on  Fertility:Post­implantation mortality; Reproductive Effects:Specific Developmental  Abnormalities:Musculoskeletal system;   Tumorigen / Carcinogen:Inhalation­Mouse TCLo • 250 ppm 6 Hour(s) 2 Year(s)­Intermittent;  Tumorigenic:Carcinogenic by RTECS criteria; Liver:Tumors; Inhalation­Rat TCLo • 125 ppm 6 Hour(s) 2 Year(s)­ Intermittent; Tumorigenic:Equivocal tumorigenic agent by RTECS criteria; Endocrine:Tumors Ammonium  hydroxide (5%  TO 10%) 1336­ 21­6 Acute Toxicity:Ingestion/Oral­Rat LD50 • 350 mg/kg; Gastrointestinal:Other changes; Liver:Other changes;  Kidney, Ureter, and Bladder:Other changes;   Irritation:Eye­Rabbit • 44 µg • Severe irritation Sodium nitrate  (10% TO 15%) 7631­ 99­4 Acute Toxicity:Ingestion/Oral­Rat LD50 • 1267 mg/kg;   Tumorigen / Carcinogen:Ingestion/Oral­Rat TDLo • 100 g/kg 2 Year(s)­Continuous; Tumorigenic:Equivocal  tumorigenic agent by RTECS criteria; Liver:Tumors 2­Pyrrolidinone,  1­methyl­ (5%  TO 10%) 872­ 50­4 Acute Toxicity:Ingestion/Oral­Rat LD50 • 3914 mg/kg;   Irritation:Eye­Rabbit • 100 mg • Moderate irritation;   Multi­dose Toxicity:Ingestion/Oral­Rat TDLo • 33750 mg/kg 90 Day(s)­Intermittent; Behavioral:Muscle  weakness; Inhalation­Rat TCLo • 400 mg/m³ 6 Hour(s) 4 Week(s)­Intermittent; Lungs, Thorax, or Respiration:Acute  pulmonary edema; Blood:Changes in leucocyte (WBC) count; Related to Chronic Data:Death in the Other  Multiple Dose data type field;   Reproductive:Ingestion/Oral­Rat TDLo • 7.5 g/kg (6­20D preg); Reproductive Effects:Effects on Embryo or  Fetus:Fetotoxicity (except death, e.g., stunted fetus); Reproductive Effects:Specific Developmental  Abnormalities:Musculoskeletal system; Ingestion/Oral­Rat TDLo • 11.25 g/kg (6­20D preg); Reproductive  Effects:Specific Developmental Abnormalities:Craniofacial (including nose and tongue);   Tumorigen / Carcinogen:Ingestion/Oral­Mouse TDLo • 784 g/kg 78 Week(s)­Continuous;  Tumorigenic:Carcinogenic by RTECS criteria; Liver:Tumors CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 8 of 14Page 8 of 14Page 8 of 14Page 8 of 14Christensen Arms AO Modification 9/7/23     GHS Properties Classification Respiratory sensitization EU/CLP •Data lacking    OSHA HCS 2012 •Data lacking    Serious eye damage/Irritation EU/CLP •Serious Eye Damage 1   OSHA HCS 2012 •Serious Eye Damage 1   Acute toxicity EU/CLP •Acute Toxicity ­ Dermal 3 ­ ATEmix(dermal) = 220 mg/kg; Acute Toxicity ­  Inhalation 3 ­ ATEmix(inhl, vapors) = 450 ppm; Acute Toxicity ­ Oral 4 ­ ATEmix(oral) =  745.83 mg/kg    OSHA HCS 2012 •Acute Toxicity ­ Dermal 3 ­ ATEmix(dermal) = 220 mg/kg; Acute  Toxicity ­ Inhalation 3 ­ ATEmix(inhl) = 450 ppm; Acute Toxicity ­ Oral 4 ­ ATEmix(oral) =  720.85 mg/k    Aspiration Hazard EU/CLP •Data lacking    OSHA HCS 2012 •Data lacking    Carcinogenicity EU/CLP •Data lacking    OSHA HCS 2012 •Data lacking    Skin corrosion/Irritation EU/CLP •Skin Corrosion 1B   OSHA HCS 2012 •Skin Irritation 2   Skin sensitization EU/CLP •Data lacking    OSHA HCS 2012 •Data lacking    STOT­RE EU/CLP •Data lacking    OSHA HCS 2012 •Specific Target Organ Toxicity Repeated Exposure 2    STOT­SE EU/CLP •Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation     OSHA HCS 2012 •Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects;  Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation    Toxicity for Reproduction EU/CLP •Toxic to Reproduction 1B    OSHA HCS 2012 •Toxic to Reproduction 1B    Germ Cell Mutagenicity EU/CLP •Data lacking    OSHA HCS 2012 •Data lacking    Potential Health Effects Inhalation Acute (Immediate)•Toxic if inhaled. May cause corrosive burns ­ irreversible damage. May cause respiratory irritation. May affect the central nervous system. Symptoms may include dizziness, drowsiness, lethargy, coma and death. Chronic (Delayed)•Repeated or prolonged exposure to corrosive fumes may cause bronchial irritation with chronic cough. Skin Acute (Immediate)•Toxic in contact with skin. Causes severe skin burns and eye damage. Chronic (Delayed)•Repeated or prolonged exposure to corrosive materials will cause dermatitis. Eye Acute (Immediate)•Causes serious eye damage. Chronic (Delayed)•Repeated or prolonged exposure to corrosive materials or fumes may cause conjunctivitis. Ingestion Acute (Immediate)•Harmful if swallowed. May cause irreversible damage to mucous membranes. Chronic (Delayed)•Repeated or prolonged exposure to corrosive materials or fumes may cause  CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 9 of 14Page 9 of 14Page 9 of 14Page 9 of 14Christensen Arms AO Modification 9/7/23     gastrointestinal distrubances. Other Chronic (Delayed)•Repeated and prolonged exposure may affect the blood and/or immune system. Reproductive Effects •Repeated and prolonged exposure may cause reproductive effects. Key to abbreviations LC =Lethal Concentration  LD =Lethal Dose TC=Toxic Concentration TD=Toxic Dose Section 12 ­ Ecological Information 12.1 Toxicity •Material data lacking. 12.2 Persistence and degradability •Material data lacking. 12.3 Bioaccumulative potential •Material data lacking. 12.4 Mobility in Soil •Material data lacking. 12.5 Results of PBT and vPvB assessment •PBT and vPvB assessment has not been conducted. 12.6 Other adverse effects • No studies have been found. Section 13 ­ Disposal Considerations 13.1 Waste treatment methods Product waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 ­ Transport Information 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es)14.4 Packing group 14.5 Environmental hazards DOT NDA Not Regulated NDA NDA NDA TDG NDA Not Regulated NDA NDA NDA IMO/IMDG UN3082 ENVIRONMENTALLY HAZARDOUS  SUBSTANCE, LIQUID, N.O.S. (Ammonium  hydroxide)  9 III NDA CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 10 of 14Page 10 of 14Page 10 of 14Page 10 of 14Christensen Arms AO Modification 9/7/23   IATA/ICAO UN3082 Environmentally hazardous substance, liquid,  n.o.s. (Ammonium hydroxide) 9 III NDA 14.6 Special precautions for user • None specified. 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code • Data lacking. Section 15 ­ Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or  mixture SARA Hazard Classifications • Acute, Chronic, Fire Inventory Component CAS Canada DSL Canada NDSL EU EINECS EU ELNICS TSCA 2­Pyrrolidinone, 1­ methyl­872­50­4 Yes No Yes No Yes Ammonium  hydroxide 1336­21­6 Yes No Yes No Yes Ethylene glycol  monobutyl ether 111­76­2 Yes No Yes No Yes Sodium nitrate 7631­99­4 Yes No Yes No Yes Canada Labor  Canada ­ WHMIS ­ Classifications of Substances   •Ethylene glycol monobutyl ether  111­76­2  B3, D1A, D2B  •Ammonium hydroxide  1336­21­6  E   •Sodium nitrate  7631­99­4  C, D2B  •2­Pyrrolidinone, 1­methyl­ 872­50­4  B3, D2B    Canada ­ WHMIS ­ Ingredient Disclosure List   •Ethylene glycol monobutyl ether  111­76­2  1 %  •Ammonium hydroxide  1336­21­6  1 %  •Sodium nitrate  7631­99­4  1 %  •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed   Environment  Canada ­ CEPA ­ Priority Substances List   •Ethylene glycol monobutyl ether  111­76­2   Priority Substance List 2  (substance considered toxic,  added to CEPA's Schedule 1,  List of Toxic Substances)  •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed   United States CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 11 of 14Page 11 of 14Page 11 of 14Page 11 of 14Christensen Arms AO Modification 9/7/23 Labor  U.S. ­ OSHA ­ Process Safety Management ­ Highly Hazardous Chemicals   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ OSHA ­ Specifically Regulated Chemicals   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed   Environment  U.S. ­ CAA (Clean Air Act) ­ 1990 Hazardous Air Pollutants   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ CERCLA/SARA ­ Hazardous Substances and their Reportable Quantities   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  1000 lb final RQ; 454 kg final  RQ  •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ CERCLA/SARA ­ Radionuclides and Their Reportable Quantities   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ CERCLA/SARA ­ Section 302 Extremely Hazardous Substances EPCRA RQs   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ CERCLA/SARA ­ Section 302 Extremely Hazardous Substances TPQs   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ CERCLA/SARA ­ Section 313 ­ Emission Reporting   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  1.0 % de minimis  concentration    U.S. ­ CERCLA/SARA ­ Section 313 ­ PBT Chemical Listing •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 12 of 14Page 12 of 14Page 12 of 14Page 12 of 14Christensen Arms AO Modification 9/7/23   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed   United States ­ California Environment  U.S. ­ California ­ Proposition 65 ­ Carcinogens List   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ California ­ Proposition 65 ­ Developmental Toxicity   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  developmental toxicity, initial  date 6/15/01    U.S. ­ California ­ Proposition 65 ­ Maximum Allowable Dose Levels (MADL)   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4   3200 µg/day MADL  (inhalation); 17000 µg/day  MADL (dermal)   U.S. ­ California ­ Proposition 65 ­ No Significant Risk Levels (NSRL)   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ California ­ Proposition 65 ­ Reproductive Toxicity ­ Female   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed    U.S. ­ California ­ Proposition 65 ­ Reproductive Toxicity ­ Male   •Ethylene glycol monobutyl ether  111­76­2  Not Listed   •Ammonium hydroxide  1336­21­6  Not Listed   •Sodium nitrate  7631­99­4  Not Listed   •2­Pyrrolidinone, 1­methyl­ 872­50­4  Not Listed   15.2 Chemical Safety Assessment •No Chemical Safety Assessment has been carried out. 15.3 Other Information •WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Section 16 ­ Other Information CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 13 of 14Page 13 of 14Page 13 of 14Page 13 of 14Christensen Arms AO Modification 9/7/23   Relevant Phrases (code & full text) •H301 ­ Toxic if swallowed H315 ­ Causes skin irritation H319 ­ Causes serious eye irritation H400 ­ Very toxic to aquatic life  Revision Date • 10/November/2015 Preparation Date • 30/January/2015 Disclaimer/Statement of Liability • The information herein is given in good faith but no warranty, expressed or implied, is made. Key to abbreviations NDA=No Data Available CR-10CR-10CR-10CR-10 Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015 Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015 Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012WHMIS, EU CLP, OSHA HCS 2012Page 14 of 14Page 14 of 14Page 14 of 14Page 14 of 14Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE® 242® THREADLOCKER IDH number: 135355 Product type: Anaerobic Sealant Item number: 24231 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CAUSES SKIN AND EYE IRRITATION. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2B SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2 PICTOGRAM(S) Precautionary Statements Prevention: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Christensen Arms AO Modification 9/7/23 Oleic acid 5.5EO 9004-96-0 20 - 30 Saccharin 81-07-2 1 - 5 Silica, amorphous, fumed, crystal-free 112945-52-5 1 - 5 Cumene hydroperoxide 80-15-9 1 - 5 Propane-1,2-diol 57-55-6 1 - 5 Cumene 98-82-8 0.1 - 1 Titanium dioxide 13463-67-7 0.1 - 1 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Christensen Arms AO Modification 9/7/23 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8. Storage: For safe storage, store between 0 °C (32°F) and 32 °C (89.6 °F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Oleic acid 5.5EO None None None None Saccharin None None None None Silica, amorphous, fumed, crystal-free 10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA Respirable fraction. 20 MPPCF TWA 0.8 mg/m3 TWA None None Cumene hydroperoxide None None 1 ppm (6 mg/m3) TWA (SKIN) None Propane-1,2-diol None None 10 mg/m3 TWA Aerosol. None Cumene 50 ppm TWA 50 ppm (245 mg/m3) PEL (SKIN) None None Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total dust. 15 MPPCF TWA Respirable fraction. 15 mg/m3 TWA Total dust. 50 MPPCF TWA Total dust. 5 mg/m3 TWA Respirable fraction. None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Blue Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg (27 °C (80.6 °F)) Boiling point/range: > 149 °C (> 300.2 °F) Christensen Arms AO Modification 9/7/23 Melting point/ range: Not available. Specific gravity: 1.1 at 23.9 °C (75.02 °F) Vapor density: Not available. Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup Flame projection: Not applicable Flammable/Explosive limits - lower: 2.6 % (propylene glycol) Flammable/Explosive limits - upper: 12.5 % (propylene glycol) Autoignition temperature: Not determined Flammability: Not applicable Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.56 %; 6.17 g/l (California SCAQMD Method 316B) (Estimated) Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials. Hazardous decomposition products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. Incompatible materials: Strong oxidizing agents. Free radical initiators. Strong reducing agents. Alkalis. Oxygen scavengers. Other polymerization initiators. Copper. Iron. Zinc. Aluminum. Rust. Reactivity: Not available. Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Christensen Arms AO Modification 9/7/23 Potential Health Effects/Symptoms Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Skin contact: Causes skin irritation. Eye contact: Causes eye irritation. Ingestion: May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Oleic acid 5.5EO None Irritant Saccharin Oral LD50 (Mouse) = 17 g/kg No Target Organs Silica, amorphous, fumed, crystal-free None Nuisance dust Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l Allergen, Central nervous system, Corrosive, Irritant, Mutagen Propane-1,2-diol Oral LD50 (Rabbit) = 18 g/kg Oral LD50 (Mouse) = 23.9 g/kg Oral LD50 (Rat) = 30 g/kg Irritant Cumene Oral LD50 (Rat) = 2.91 g/kg Oral LD50 (Rat) = 1,400 mg/kg Inhalation LC50 (Rat, 4 h) = 8000 ppm Central nervous system, Irritant, Lung Titanium dioxide None Irritant, Respiratory, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Oleic acid 5.5EO No No No Saccharin No No No Silica, amorphous, fumed, crystal-free No No No Cumene hydroperoxide No No No Propane-1,2-diol No No No Cumene Reasonably Anticipated to be a Human Carcinogen. Group 2B No Titanium dioxide No Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III DOT Hazardous Substance(s): alpha,alpha-Dimethylbenzylhydroperoxide Christensen Arms AO Modification 9/7/23 International Air Transportation (ICAO/IATA) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9 Identification number: UN 3082 Packing group: III 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis. CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Saccharin (CAS# 81-07-2). Cumene hydroperoxide (CAS# 80-15-9). CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: 2 Prepared by: Product Safety and Regulatory Affairs Issue date: 01/11/2018 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name: Bos-Gear 150 Product Description: Extreme Pressure Industrial Gear Oil Product Code: BOSGEA150-055, BOSGEA150-005 Intended Use: Lubrication Oil For Gear Boxes Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Warning Causes Mild Skin Irritation – Category 3 Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3) OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point: >400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0 Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 3 of 6 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802. SECTION 7 HANDLING AND STORAGE General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Minimize exposure of this material to the environment. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 4 of 6 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 6 of 6 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 220 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name: Bos-Gear 220 Product Description: Extreme Pressure Industrial Gear Oil Product Code: BOSGEA220-055, BOSGEA220-005 Intended Use: Lubrication Oil For Gear Boxes Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Warning Causes Mild Skin Irritation – Category 3 Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 220 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3) OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point: >400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0 Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 220 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 3 of 6 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802. SECTION 7 HANDLING AND STORAGE General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Minimize exposure of this material to the environment. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 220 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 4 of 6 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 220 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Christensen Arms AO Modification 9/7/23 Product Name: Bos-Gear 220 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 6 of 6 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Christensen Arms AO Modification 9/7/23 Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name: Premium AW Hydraulic 46 Product Description: Anti-Wear Hydraulic Oil Product Code: BOSHYD046-005, BOSHYD046-055, BOSHYD046-275 Intended Use: High Pressure Hydraulic & General Machine Oil Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Warning Causes Mild Skin Irritation – Category 3 Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3) OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point: >400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0 Christensen Arms AO Modification 9/7/23 Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 3 of 6 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802. SECTION 7 HANDLING AND STORAGE General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Minimize exposure of this material to the environment. Christensen Arms AO Modification 9/7/23 Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 4 of 6 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.87 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available Christensen Arms AO Modification 9/7/23 Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Christensen Arms AO Modification 9/7/23 Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 6 of 6 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 32 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name: Unilube 32 Product Description: R&O Turbine Oil/Anti-Wear ISO 32 Product Code: BOSUNI032-275, BOSUNI032-055, BOSUNI032-005 Intended Use: Turbine, Circulating, Hydraulic & Bar Feed Oil Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Warning Causes Mild Skin Irritation – Category 3 Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 32 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3) OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point: >400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0 Christensen Arms AO Modification 9/7/23 Product Name: Unilube 32 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 3 of 6 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802. SECTION 7 HANDLING AND STORAGE General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Minimize exposure of this material to the environment. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 32 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 4 of 6 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available Christensen Arms AO Modification 9/7/23 Product Name: Unilube 32 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 32 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 6 of 6 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name: Unilube 150 Product Description: R&O Turbine Oil/Anti-Wear ISO 150 Product Code: BOSUNI150-275, BOSUNI150-055, BOSUNI150-005 Intended Use: Turbine, Circulating, Hydraulic & Bar Feed Oil Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Warning Causes Mild Skin Irritation – Category 3 Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3) OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point: >400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0 Christensen Arms AO Modification 9/7/23 Product Name: Unilube 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 3 of 6 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802. SECTION 7 HANDLING AND STORAGE General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Minimize exposure of this material to the environment. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 4 of 6 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available Christensen Arms AO Modification 9/7/23 Product Name: Unilube 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Christensen Arms AO Modification 9/7/23 Product Name: Unilube 150 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 6 of 6 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 1 of 8 SAFETY DATA SHEET Regulation (EC) No 1907/2006 (REACH) and 2015/830 Section 1. Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product Identifier Product Name: Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against Product Use: Adhesive 1.3 Details of the Supplier of the Safety Data Sheet Supplier: METREX® RESEARCH 28210 Wick Rd Romulus, MI 48174 U.S.A. 1.4 Emergency Telephone Number CHEMTREC: 1-703-527-3887 (Outside the US) Information Phone Number: 1-800-841-1428 (Customer Service) SDS Date of Preparation/Revision: March 26, 2018 Section 2. Hazards Identification 2.1 Classification of the Substance or Mixture GHS Classification: Acute Toxicity Category 4 H332 Skin Irritation Category 2 H315 Skin Sensitization Category 1 H317 Eye Irritation Category 2 H319 Respiratory Sensitization Category 1 H334 Specific Target Organ Toxicity – Single Exposure Category 3 H335 Carcinogen Category 2 H351 Specific Target Organ Toxicity – Repeated Exposure Category 2 H373 2.2 Label Elements Danger! Contains 4,4’-Methylenediphenyl diisocyanate, oligomers, Isocyanic acid, 3-(triethoxysilyl)propyl ester Hazard Phrases H315 Causes skin irritation. Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 2 of 8 H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory Irritation. H351 Suspected of causing cancer. H373 May cause damage to respiratory tract through prolonged or repeated exposure by inhalation. Prevention: P260 Do not breathe vapors. P280 Wear protective gloves. Response: P333 + P313 If skin irritation or rash occurs: Get medical attention. P304 + P340 IF INHALED: remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 2.3 Other Hazards: This product contains isocyanates. Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Section 3. Composition/Information On Ingredients 3.2 Mixture Component CAS No./ EC No. Amount GHS Classification 4,4’-Methylenediphenyl diisocyanate, oligomers None/ 500-0403 50-80 Acute Tox. 4 H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Resp. Sens. 1 H334 Skin Sens. 1B H317 Carc. 2 H351 STOT SE 3 H335 STOT RE 2 H373 Diphenylmethanediisocyanate prepolymer 68424-09-9 15-40 Not hazardous 3-(Trimethoxysilyl)propyl glycidyl ether 2530-83-8 / 219-784-2 <5 Eye Dam 1 H318 Isocyanic acid, 3-(triethoxysilyl)propyl ester 24801-88-5 / 246-467-6 <1 Acute Tox. 1 H330 Acute Tox. 4 H302, H312 Skin Corr 1B H314 Skin Sens. 1 H317 Eye Dam 1 H318 Resp. Sens. 1 H334 Section 4. First Aid Measures 4.1 Description of First Aid Measures Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 3 of 8 Eyes: Immediately flush eyes with water for 15 minutes while lifting the upper and lower lids. Get medical attention if irritation persists. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. If irritation or rash develop, get medical attention. Launder clothing before re-use. Inhalation: Immediately remove to fresh air. If breathing is difficult have qualified personnel administer oxygen. If breathing has stopped, administer artificial respiration. Get immediate medical attention. Asthma-like symptoms may develop immediately or delayed up to several hours. Ingestion: If conscious, rinse mouth with water. Never give anything by mouth to a person who is unconscious or convulsing. Do not induce vomiting. Get medical attention. 4.2 Most Important symptoms and effects, both acute and delayed: Irritating to eyes, skin and respiratory system. May cause allergic skin and respiratory reaction. Harmful if inhaled. Symptoms include respiratory irritation, breathlessness, and chest discomfort and reduced pulmonary function, bronchitis, bronchial spasms and pulmonary edema. Symptoms may be delayed. Individuals sensitized to isocyanates may have a life-threatening allergic reaction. Prolonged or repeated exposure may cause damage to the lungs by inhalation. May cause cancer based on animal data. 4.3 Indication of any immediate medical attention and special treatment needed: If respiratory sensitization reaction occurs, get immediate medical attention. Symptoms may be delayed for several hours after exposure. Respiratory sensitization may be life threatening. Section 5. Firefighting Measures 5.1 Extinguishing Media: Use any extinguishing media that is appropriate for the surrounding fire. Cool fire exposed containers with water. 5.2 Special Hazards arising from the Substance or Mixture: Combustion may produce carbon and nitrogen oxides, hydrogen cyanide and other toxic gases. 5.3 Advice for Firefighters: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Do not allow run-off from firefighting to enter drains or water courses. Decontaminate equipment and protective clothing before reuse. Section 6: Accidental Release Measures 6.1 Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective clothing as described in Section 8. Isolate the area and prevent access. Ventilate the area. Evacuate area. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. 6.2 Environmental Precautions: Avoid release to the environment. Report spill as required by local and federal regulations. 6 6.3 Methods and Material for Containment and Cleaning Up: Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 4 of 8 Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Place in an approved container for disposal. Do not seal the container for 48 hours to avoid pressure build-up. Clean up residue with an appropriate solvent. Ventilate the area with fresh air. 6.4 Reference to Other Sections: Refer to Section 8 for personal protective equipment and Section 13 for disposal information. Section 7. Handling and Storage 7.1 Precautions for Safe Handling: Do not breathe vapors or mists. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. 7.2 Conditions for Safe Storage, Including any Incompatibilities: Store in a well-ventilated place. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from acids and strong bases. 7.3 Specific end use(s): Adhesive Section 8. Exposure Controls/Personal Protection 8.1 Control Parameters: Chemical Exposure Limit 4,4’-Methylenediphenyl diisocyanate, oligomers None Established Diphenylmethanediisocyanate prepolymer None Established 3-(Trimethoxysilyl)propyl glycidyl ether None Established Isocyanic acid, 3-(triethoxysilyl)propyl ester None Established 8.2 Exposure Controls: Recommended Monitoring Procedures: Contact professional occupational hygienist for monitoring. Appropriate Engineering Controls: Use with adequate general or local exhaust ventilation to maintain exposures below the occupational exposure limits. If ventilation is not adequate, use respiratory protection equipment. Personal Protective Measurers Respiratory Protection: If the exposure limits are exceeded or if exposure levels are unknown, an approved positive pressure air supplied respirator with a full facepiece or air supplied hood should be used. Based on the results of the exposure assessment, a half-face full facepiece air-purifying respirator suitable for organic vapors and particulates should be used with A & P filters. Select in accordance with EU standard EN 140 or EN 136, other applicable regulations and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 5 of 8 Hand protection: Impervious gloves such as butyl rubber or fluoroelastomer are recommended. Select in accordance with EU standard EN 374 Eye Protection: Indirect vented goggles are recommended. Select in accordance with EU standard EN 166. Skin Protection: Wear protective clothing as needed to avoid skin contact. Other protection: Wash contaminated clothing or dispose of properly. A safety shower and eye wash should be available in the immediate work area. Section 9. Physical and Chemical Properties 9.1 Information on Basic Physical and Chemical Properties: Appearance: Viscous liquid Vapor Pressure:<0 pa @ 20°C Odor: No detectable odor. Vapor Density:>1 (air = 1) Odor Threshold: Not available Relative Density /Specific Gravity:1.2 pH: Not applicable Solubility in Water:Negligible Melting/Freezing Point: Not available Partition Coefficient: (n-octanol/water) Not applicable Initial Boiling Point/Range: >204.4°C / >399.9°F Auto-ignition Temperature: Not applicable Flash Point: >143.3°C (>289.94°F) TCC Decomposition Temperature: Not applicable Evaporation Rate: Gels with exposure to humidity Viscosity: Not determined Flammability: (solid/gas) Not applicable Explosive Properties: None Flammable/ Explosive Limits: Not applicable Oxidizing Properties: None 9.2 Other Information: None Section 10. Stability and Reactivity 10.1 Reactivity: Reacts with water to form carbon dioxide. 10.2 Chemical Stability: Stable under normal storage and handling conditions. 10.3 Possibility of Hazardous Reactions: Polymerization will occur when exposure to water or moisture. 10.4 Conditions to Avoid: Avoid contamination with moisture. 10.5 Incompatible Materials: Water, strong acids and strong bases. 10.6 Hazardous Decomposition Products: Thermal decomposition will produce oxides of carbon and nitrogen, hydrogen cyanide and other highly toxic gases. Section 11. Toxicological Information 11.1 Information on Toxicological Effects: Potential Health Effects: Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 6 of 8 Inhalation: Harmful if inhaled. May cause respiratory irritation with coughing, sneezing, nasal discharge, headache, hoarseness and nose and throat pain. May cause allergic respiratory reaction with difficulty in breathing, wheezing, cough and tightness of the chest. Symptoms may be delayed for several hours after exposure. The allergic respiratory reaction may be life threatening. Skin Contact: Causes skin irritation with localized redness, swelling, itching, dryness, cracking, blistering, and pain. May cause allergic skin reaction with redness, swelling, blistering, and itching. Eye Contact: Causes eye irritation with redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Swallowing may cause gastrointestinal irritation, abdominal pain, nausea, vomiting and diarrhea. Acute Toxicity Values: No toxicity data is available for the product. Acute Toxicity Estimate (ATE): Oral: >5,000 mg/kg, Inhalation 1.73 mg/L/4 hr, Dermal: >5,000 mg/kg 4,4’-Methylenediphenyl diisocyanate, oligomers: Oral rat LD50 31,600 mg/kg; Inhalation rat LC50 0.368 mg/L/4 hr; Dermal rabbit LD50 >5,000 mg/kg. 3-(Trimethoxysilyl)propyl glycidyl ether: Oral rat LD50 7,010 mg/kg; Inhalation rat LC50 >5.3 mg/L/4 hr; Dermal rabbit LD50 4,000 mg/kg. Isocyanic acid, 3-(triethoxysilyl)propyl ester: Oral rat LD50 706 mg/kg, Inhalation rat LC50 0.36 mg/L/4 hr, Dermal rabbit 1259 mg/kg Skin corrosion/irritation: Isocyanates are known to cause skin irritation in studies with laboratory animals. Eye damage/ irritation: Isocyanates are known to cause eye irritation is studies with laboratory animals Skin Sensitization: Isocyanates are known to cause skin sensitization in studies with laboratory animals. Respiratory Sensitization: Isocyanates are known to cause respiratory sensitization in humans. Animal tests have indicated that respiratory sensitization can result from skin contact with isocyanates. Germ Cell Mutagenicity: None of the components have been shown to cause gem cell mutagenicity. Carcinogenicity: 4,4’-Methylenediphenyl diisocyanate, oligomers is classified as a “Suspected of causing cancer” (Carcinogen Category 2) by the EU CLP. Developmental / Reproductive Toxicity: None of the components are classified as reproductive or developmental toxins. Specific Target Organ Toxicity (Single Exposure): Isocyanates are known to cause respiratory irritation. Specific Target Organ Toxicity (Repeated Exposure): Prolonged exposure to isocyanates may cause chronic irritation, decreased lung function and lung damage and conjunctivitis. Aspiration Toxicity: None of the components are aspiration hazards. Section 12. Ecological Information 12.1 Toxicity: No toxicity data available for product 4,4’-Methylenediphenyl diisocyanate, oligomers: 24 hr EC50 daphnia magna >100 mg/L Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 7 of 8 3-(Trimethoxysilyl)propyl glycidyl ether: 96 hr LC50 Common Carp 55 mg/L, 48 hr LC50 Crustecea 324 mg/L, 96 hr LC50 green algae 350 mg/L Isocyanic acid, 3-(triethoxysilyl)propyl ester: 96 hr LC50 zebra fish >934 mg/L, 48 hr EC50 daphnia magna 331 mg/L, 72 hr EC50 green algae >1,000 mg/L 12.2 Persistence and Degradability: 4,4’-Methylenediphenyl diisocyanate, oligomers is not readily biodegradable. 12.3 Bioaccumulative Potential: Isocyanates hydrolyze rapidly in aqueous solutions, therefore bioconcentration is not an important environmental fate process. 12.4 Mobility in Soil: Isocyanates hydrolyze rapidly in aqueous solutions, therefore leaching and adsorption to moist soil and sediment will not be an important environmental fate process. 12.5 Results of PBT and vPvB assessment: This product is not a PBT and vPvB. 12.6 Other Adverse Effects: None known. Section 13. Disposal Considerations 13.1 Waste Treatment Methods: Dispose of contents and container in accordance with all local and national regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incine polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Section 14. Transport Information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport Hazard Class(es) 14.4 Packing Group 14.5 Environmental Hazards US DOT Not Regulated EU ADR/RID Not Regulated IMDG Not Regulated IATA/ICAO Not Regulated 14.6 Special Precautions for User: None identified 14.7 Transport in Bulk According to Annex III MARPOL 73/78 and the IBC Code: Not applicable Section 15. Regulatory Information Christensen Arms AO Modification 9/7/23 Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A Date Prepared: 3/26/18 Page 8 of 8 15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture 16. Other Information GHS Classification for Reference (See Sections 2 and 3): Acute Tox. 1 Acute Toxicity Category 1 Acute Tox. 4 Acute Toxicity Category 4 Skin Corr 1B Skin Corrosion Category 1B Skin Irrit. 2 Skin Irritation Category 2 H315 Skin Sens. 1BSkin Sensitization Category 1 H317 Eye Dam 1 Eye Damage Category 1 Eye Irrit. 2 Eye Irritation Category 2 Resp. Sens. 1 Respiratory Sensitization Category 1 Carc. 2 Carcinogen Category 2 H351 STOT SE 3 Specific Target Organ Toxicity – Single Exposure Category 3 STOT RE 2 Specific Target Organ Toxicity – Repeated Exposure Category 2 H302 Harmful if swallowed H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H330 Fatal if inhaled. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory Irritation. H351 Suspected of causing cancer. H373 May cause damage to respiratory tract through prolonged or repeated exposure by inhalation. Effective Date: March 26, 2018 Supersedes Date: New SDS Revision Summary: New SDS The information and recommendations set forth herein are taken from sources believed to be accurate as of the date of preparation, however, METREX® RESEARCH makes no warranty with respect to the accuracy or suitability of the recommendations, and assumes no liability to any use thereof. Christensen Arms AO Modification 9/7/23 WATERSHIELD Page 1 of 2 DESCRIPTION WATERSHIELD can be considered a UNIVERSAL release. It is a high performance polymer coating that has been created to give multiple releases while exceeding the most demanding environmental requirements. WATERSHIELD has no VOC’s and is so versatile it can be used for most molding operations and is preferred for application directly on warm mold tools. For a totally solvent-free mold release system, use WATERCLEAN, SEALPROOF and WATERSHIELD. ENVIROSHIELD should be used for high temp applications when spraying is desired, and when applications for each part are specified. * ENVIRONMENTALLY SAFE * Thermal Stability * No solvents or alcohol * High Gloss * No CFC’s, VOC’s, or ODC’s * High slip/lubricity * Fast cure * Easy recoat/touch-up * Non-flammable * Aerospace approved * No build-up on mold TYPICAL PROPERTIES Appearance & Odor : Opaque liquid with bland odor Carrier : Water Flash Point [C.C] : None Coverage : Approximately 1200 Sq. Ft./Gallon Wt/Gallon : 8.0 lbs/Gallon Cure Requirement : Ambient or heat USES WATERSHIELD is recommended for releasing epoxies, phenolics, polyester resins, polyamides, polybismaleimides, various rubbers and elastomers. WATERSHIELD is specified for applications where the use of flammable products or solvent based materials are not desired. SURFACE PREPARATION Before applying WATERSHIELD, all previous waxes or oils should be removed using WATERCLEAN, and then a suitable mold sealer should be applied. If surfaces have been coated with a semi- permanent release agent, it may be possible to simply solvent wipe, dry, and apply WATERSHIELD. A test patch should be done to confirm this possibility. MOLD CLEANING WATERCLEAN has been developed to replace solvent-based cleaning solutions. WATERCLEAN is a stand-alone product that can be used to clean and prepare molds and/or parts when further processing is needed. WATERCLEAN provides an effective alternative for the removal of surface contaminants without harming the working surface of the mold and/or part. WATERCLEAN is RECOMMENDED FOR MOLD PREPARATION BEFORE APPLICATION OF AN APPROPRIATE MOLD SEALER. Christensen Arms AO Modification 9/7/23 MOLD SEALING For wood, gel coat, steel, carbon-graphite, fiberglass, polyester, epoxy, urethane, and aluminum use SEALPROOF for a durable, highly visible, penetrating film with superior adhesion and especially with poor or porous surfaces. Additional water based Zyvax sealers would be SEALMATTE (non-glossy surface) and SEALBRITE (high gloss surface). HOW TO APPLY WATERSHIELD 1. Apply one light coat of WATERSHIELD to a small area of the mold using a Bounty® paper towel, or hand sprayer. 2. Wait approximately 2 minutes, and then lightly wipe over the mold surface using a separate clean Bounty® paper towel. 3. Wait 15 minutes and apply the second coat of WATERSHIELD. 4. Wait approximately 2 minutes, and then lightly wipe over the mold surface using a separate clean Bounty® paper towel. 5. Allow a set time of 30 minutes before using mold. If application has been made to a warm surface, a shorter waiting period is needed. The use of heat (hot air, heat gun, oven) can enhance performance. 6. For touch up apply a single coat of WATERSHIELD as above and continue processing. STORAGE & SHELF LIFE Store product between 5°C and 30°C (41°F and 86°F). Shelf life is 18 months from the date of manufacture, in the original unopened container. USE LIFE Use life of product is 60 days from opening of container. Product must be kept in the original container and the lid replaced immediately after dispensing. After opening, product should continue to be stored properly. Maximum product life is not to exceed 18 months from Date of Manufacture. WARNING Never puncture any Zyvax product container. SAFETY DATA Material safety data sheets are available for all ZYVAX products and should be consulted prior to use of product. SHIPPING DATA DOT SHIPPING NAME: None DOT HAZARD CLASSIFICATION: None DOT I.D. NUMBER: None PACKAGING WATERSHIELD is available in the following sizes: 1-U.S. gallon can 5-U.S. gallon pail 55-U.S. gallon pail LIMITATIONS OF LIABILITY To the best of our knowledge, the technical data contained herein are true and accurate at the date of issuance, and are subject to change without prior notice. User must contact ZYVAX to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to conform to ZYVAX quality control. We assume no responsibility for coverage, performance, or injuries resulting from its use. Liability, if any, is limited to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY ZYVAX, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING FITNESS FOR A PARTICULAR PURPOSE. REV. 1/99 Zyvax Inc WaterShield Application Data Sheet - Issue 5 (706) 698-4405 Phone (706) 635-8103 Fax December 2007 Page 2 of 2 Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ +1 517 546 4520 SAFETY DATA SHEET Product name Emergency telephone number and Telephone number Section 1. Identification : : Supplier's details :Chem-Trend LP 1445 W McPherson Park Dr PO Box 860, Howell MI 48844-0860 517-546-4520 Zyvax® WaterShield™ Relevant identified uses of the substance or mixture and uses advised against Release Agent Section 2. Hazards identification Not classified.Classification of the substance or mixture : Signal word :No signal word. Hazard statements :No known significant effects or critical hazards. Precautionary statements Prevention :Not applicable. Response :Not applicable. Storage :Not applicable. Disposal :Not applicable. GHS label elements OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified :None known. Section 3. Composition/information on ingredients Surfactant ≤3 - Ingredient name CAS number% Substance/mixture :Mixture Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 1/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact :No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 2/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : Protective measures Put on appropriate personal protective equipment (see Section 8).: Precautions for safe handling Section 8. Exposure controls/personal protection Appropriate engineering controls :Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Control parameters Occupational exposure limits None. Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 3/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative densityVapor density Solubility Liquid. [Hazy liquid.] Not available. 1Not available. Not available. Insoluble in the following materials: cold water. Characteristic.Odor pH White.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: Not applicable. [Water-based product] Not available. 9 to 10.7 Viscosity Not available. Not available.Odor threshold Partition coefficient: n- octanol/water Boiling point 100°C (212°F) Flammability (solid, gas) Not available. Lower and upper explosive (flammable) limits Not available. Burning rate Not applicable.Burning time Not applicable. Decomposition temperature Not available. Solubility in water Not available. Volatility 92.089 SADT Not available. Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 4/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Section 9. Physical and chemical properties None identified. Lower and upper explosive (flammable) limits Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Formaldehyde and silicon dioxide may be evolved at elevated temperatures. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Not available. Information on the likely routes of exposure Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on toxicological effects :Not available. Potential acute health effects Irritation/Corrosion :No known significant effects or critical hazards. Sensitization :No known significant effects or critical hazards. Mutagenicity :No known significant effects or critical hazards. Carcinogenicity :No known significant effects or critical hazards. Reproductive toxicity :No known significant effects or critical hazards. Teratogenicity :No known significant effects or critical hazards. Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 5/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Section 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Skin contact IngestionInhalation No specific data.No specific data. No specific data. Eye contact No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Not available. Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods RCRA classification :Not applicable Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 6/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Section 14. Transport information - - - - - - Not regulated.Not regulated. DOT Classification IMDGIATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. TDG Classification Not regulated. - - - - - - - No. Not regulated.Not regulated. Not regulated - - No. Bulk No.No. - - Additional information Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : - DOT Classification TDG Classification IMDG IATA : : : : Section 15. Regulatory information Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Not applicable. SARA 302/304 SARA 304 RQ :Not applicable. No products were found. Composition/information on ingredients Inventory list Australia :All components are listed or exempted. All components are listed or exempted.:Canada China :All components are listed or exempted. Europe : Japan :Japan inventory (ENCS): All components are listed or exempted. Japan inventory (ISHL): All components are listed or exempted. Republic of Korea :All components are listed or exempted. New Zealand :All components are listed or exempted. Philippines :All components are listed or exempted. Taiwan :All components are listed or exempted. United States :All components are listed or exempted. Contact local supplier or distributor. Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 7/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Section 15. Regulatory information State regulations Massachusetts New York New Jersey Pennsylvania : : : : None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. SARA 311/312 Classification :Not applicable. Section 16. Other information History Date of issue/Date of revision Version Prepared by Information presented herein has been compiled from information provided to us by our suppliers and other sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or the use of any product in violation of any patent or in violation of any law or regulation. It is the users' responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us. Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. 10/30/2018 4/20/2018 4 Hazardous Material Information System (U.S.A.) 0 0 0 001 National Fire Protection Association (U.S.A.) Special :Instability/Reactivity :Flammability : Health :Flammability :Physical hazards :Personal protection Code :B Health : Chem-Trend Regulatory Affairs Department. - / Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 8/9Christensen Arms AO Modification 9/7/23 Zyvax® WaterShield™ Date of issue/Date of revision :10/30/2018 Date of previous issue :4/20/2018 Version :4 9/9Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : FiberTack MT-1, Fibertack MT-1 BLU 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Adhesive 1.3. Details of the supplier of the safety data sheet Engineered Bonding Solutions, LLC 801 Marina Road Titusville, FL 32796 T 321-747-0160 1.4. Emergency telephone number Emergency number : Chemtrec 1 800 424 9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 2 H225 Eye Irrit. 2A H319 STOT SE 3 H336 WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness Christensen Arms AO Modification 9/7/23 Precautionary statements (GHS-US) : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER/doctor/physician if you feel unwell P337+P313 - If eye irritation persists: Get medical advice/attention P370+P378 - In case of fire: Use Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog for extinction P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Acetone (CAS No) 67-64-1 40 - 50 Flam. Liq. 2, H225 Proprietary Polymer 1 (CAS No) Trade Secret 20 - 35 Not classified Cyclohexanone (CAS No) 108-94-1 10 - 20 Flam. Liq. 3, H226 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Proprietary Polymer 2 (CAS No) Trade Secret 10 - 15 Not classified Acetone (67-64-1) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Cyclohexanone (108-94-1) WHMIS Classification Class B Division 3 - Combustible Liquid Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Move person to fresh air.If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration and get medical attention. First-aid measures after skin contact : Wash thoroughly with soap and water. Remove contaminated clothing. Christensen Arms AO Modification 9/7/23 First-aid measures after eye contact : Flush with large quantities of water for 15 minutes. First-aid measures after ingestion : Do not induce vomiting, can cause chemical pneumonitis and pulmonary edema. Contact a Physician immediately. If any symptoms persist get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Excessive inhalation of vapors can cause nasal and respiratory irratation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. Symptoms/injuries after skin contact : Can dry and defat skin causing cracks, irritation and dermatitis. Symptoms/injuries after eye contact : Severe irritation, redness, tearing and blurred vision. Symptoms/injuries after ingestion : Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog Unsuitable extinguishing media : None 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : Pressure build up and possible auto-ignition or explosion may occur when exposed to extreme heat. 5.3. Advice for firefighters Firefighting instructions : During emergency conditions, overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Protection during firefighting : Firefighters should wear full protective gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel No additional information available 6.1.2. For emergency responders No additional information available 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment : Stop the flow of material, if this is without risk. Methods for cleaning up : Eliminate ignition sources, provide good ventilation, dike spill area and cover with inert, absorbent material and remove to disposal container. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Use in well ventilated areas. Keep containers closed when not in use. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep away from excessive heat and open flames. 7.3. Specific end use(s) Adhesive SECTION 8: Exposure controls/personal protection 8.1. Control parameters Christensen Arms AO Modification 9/7/23 Acetone (67-64-1) ACGIH ACGIH TWA (ppm) 500 ppm ACGIH ACGIH STEL (ppm) 750 ppm OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³ OSHA OSHA PEL (TWA) (ppm) 1000 ppm IDLH US IDLH (ppm) 2500 ppm (10% LEL) NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 250 ppm Alberta OEL STEL (mg/m³) 1800 mg/m³ Alberta OEL STEL (ppm) 750 ppm Alberta OEL TWA (mg/m³) 1200 mg/m³ Alberta OEL TWA (ppm) 500 ppm British Columbia OEL STEL (ppm) 500 ppm British Columbia OEL TWA (ppm) 250 ppm Manitoba OEL STEL (ppm) 750 ppm Manitoba OEL TWA (ppm) 500 ppm New Brunswick OEL STEL (mg/m³) 1782 mg/m³ New Brunswick OEL STEL (ppm) 750 ppm New Brunswick OEL TWA (mg/m³) 1188 mg/m³ New Brunswick OEL TWA (ppm) 500 ppm New Foundland & Labrador OEL STEL (ppm) 750 ppm New Foundland & Labrador OEL TWA (ppm) 500 ppm Nova Scotia OEL STEL (ppm) 750 ppm Nova Scotia OEL TWA (ppm) 500 ppm Nunavut OEL STEL (mg/m³) 2970 mg/m³ Nunavut OEL STEL (ppm) 1250 ppm Nunavut OEL TWA (mg/m³) 2370 mg/m³ Nunavut OEL TWA (ppm) 1000 ppm Northwest Territories OEL STEL (mg/m³) 2970 mg/m³ Northwest Territories OEL STEL (ppm) 1250 ppm Northwest Territories OEL TWA (mg/m³) 2370 mg/m³ Acetone (67-64-1) Northwest Territories OEL TWA (ppm) 1000 ppm Ontario OEL STEL (ppm) 750 ppm Ontario OEL TWA (ppm) 500 ppm Prince Edward Island OEL STEL (ppm) 750 ppm Prince Edward Island OEL TWA (ppm) 500 ppm Québec VECD (mg/m³) 2380 mg/m³ Québec VECD (ppm) 1000 ppm Québec VEMP (mg/m³) 1190 mg/m³ Québec VEMP (ppm) 500 ppm Saskatchewan OEL STEL (ppm) 750 ppm Saskatchewan OEL TWA (ppm) 500 ppm Christensen Arms AO Modification 9/7/23 Yukon OEL STEL (mg/m³) 3000 mg/m³ Yukon OEL STEL (ppm) 1250 ppm Yukon OEL TWA (mg/m³) 2400 mg/m³ Yukon OEL TWA (ppm) 1000 ppm Cyclohexanone (108-94-1) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 50 ppm OSHA OSHA PEL (TWA) (mg/m³) 200 mg/m³ OSHA OSHA PEL (TWA) (ppm) 50 ppm IDLH US IDLH (ppm) 700 ppm NIOSH NIOSH REL (TWA) (mg/m³) 100 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 25 ppm Alberta OEL STEL (mg/m³) 200 mg/m³ Alberta OEL STEL (ppm) 50 ppm Alberta OEL TWA (mg/m³) 80 mg/m³ Alberta OEL TWA (ppm) 20 ppm British Columbia OEL STEL (ppm) 50 ppm British Columbia OEL TWA (ppm) 20 ppm Manitoba OEL STEL (ppm) 50 ppm Manitoba OEL TWA (ppm) 20 ppm New Brunswick OEL TWA (mg/m³) 100 mg/m³ New Brunswick OEL TWA (ppm) 25 ppm New Foundland & Labrador OEL STEL (ppm) 50 ppm New Foundland & Labrador OEL TWA (ppm) 20 ppm Nova Scotia OEL STEL (ppm) 50 ppm Nova Scotia OEL TWA (ppm) 20 ppm Nunavut OEL STEL (mg/m³) 400 mg/m³ Nunavut OEL STEL (ppm) 100 ppm Nunavut OEL TWA (mg/m³) 100 mg/m³ Nunavut OEL TWA (ppm) 25 ppm Northwest Territories OEL STEL (mg/m³) 400 mg/m³ Northwest Territories OEL STEL (ppm) 100 ppm Northwest Territories OEL TWA (mg/m³) 100 mg/m³ Northwest Territories OEL TWA (ppm) 25 ppm Ontario OEL STEL (ppm) 50 ppm Ontario OEL TWA (ppm) 20 ppm Prince Edward Island OEL STEL (ppm) 50 ppm Prince Edward Island OEL TWA (ppm) 20 ppm Cyclohexanone (108-94-1) Québec VEMP (mg/m³) 100 mg/m³ Québec VEMP (ppm) 25 ppm Saskatchewan OEL STEL (ppm) 50 ppm Saskatchewan OEL TWA (ppm) 20 ppm Yukon OEL STEL (mg/m³) 200 mg/m³ Christensen Arms AO Modification 9/7/23 Yukon OEL STEL (ppm) 50 ppm Yukon OEL TWA (mg/m³) 200 mg/m³ Yukon OEL TWA (ppm) 50 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust and general ventilation must be adequate to meet exposure standards. Hand protection : Wear resistant gloves such as nitrile rubber. Eye protection : Use chemical safety glasses, goggles or faceshields for eye protection. Skin and body protection : Wear suitable working clothes. Respiratory protection : If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless to pale yellow or blue Odor : Solvent Odor threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : 131°F (55°C) Flash point : -2°F (-19°C) TCC Self ignition temperature : 788°F (420°C) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 175 mm Hg Relative vapor density at 20 °C : No data available Relative density : 7.54 lb/gal (0.90g/cc) Solubility : 22% in water at 20°C Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : 1.8 - 10.0 vol % 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions Christensen Arms AO Modification 9/7/23 Will not occur. 10.4. Conditions to avoid Excessive heat, ignition sources, poor ventilation, corrosive atmospheres, excessive aging. 10.5. Incompatible materials Strong oxidizers, strong acids, and strong bases, alkaline materials, amines. 10.6. Hazardous decomposition products Carbon dioxide, carbon monoxide, various hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Acetone (67-64-1) LC50 inhalation rat (mg/l) 50100 mg/m³ (Exposure time: 8 h) Cyclohexanone (108-94-1) LD50 oral rat 800 mg/kg LD50 dermal rabbit 948 mg/kg LC50 inhalation rat (ppm) 8000 ppm/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Cyclohexanone (108-94-1) IARC group 3 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated : Not classified exposure) Aspiration hazard : Not classified SECTION 12: Ecological information 12.1. Toxicity Acetone (67-64-1) LC50 fish 1 4.74 - 6.33 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) EC50 Daphnia 1 10294 - 17704 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) LC50 fish 2 6210 - 8120 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 2 12600 - 12700 mg/l (Exposure time: 48 h - Species: Daphnia magna) Cyclohexanone (108-94-1) Christensen Arms AO Modification 9/7/23 LC50 fish 1 481 - 578 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) LC50 fish 2 8.9 mg/l (Exposure time: 96 h - Species: Pimephales promelas) 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential Acetone (67-64-1) BCF fish 1 0.69 Log Pow -0.24 Cyclohexanone (108-94-1) BCF fish 1 (will not bioconcentrate) Log Pow 0.86 (at 25 °C) 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 14: Transport information In accordance with TDG Transport document description : UN1133 Adhesives containing a flammable liquid, 3, II UN-No.(DOT) : 1133 DOT NA no. : UN1133 DOT Proper Shipping Name : Adhesives containing a flammable liquid Department of Transportation (DOT) Hazard : Classes 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid Packing group (DOT) : II - Medium Danger Christensen Arms AO Modification 9/7/23 DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5 L (1.3 gallons). B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Packaging Non Bulk (49 CFR 173.xxx) : 173 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Quantity Limitations Passenger aircraft/rail : (49 CFR 173.27) 5 L DOT Quantity Limitations Cargo aircraft only (49 : CFR 175.75) 60 L DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Other information : No supplementary information available. SECTION 15: Regulatory information CANADA FiberTack MT-1 WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Proprietary Polymer 1 (Trade Secret) Listed on the Canadian DSL (Domestic Substances List) inventory. Acetone (67-64-1) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Cyclohexanone (108-94-1) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Class B Division 3 - Combustible Liquid Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects 15.2. International regulations Proprietary Polymer 1 (Trade Secret) Listed on the United States TSCA (Toxic Substances Control Act) inventory Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Christensen Arms AO Modification 9/7/23 Cyclohexanone (108-94-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2.2. National regulations Acetone (67-64-1) Listed on the Canadian Ingredient Disclosure List Cyclohexanone (108-94-1) Listed on the Canadian Ingredient Disclosure List SECTION 16: Other information Full text of H-phrases: ------ ------ ------ ------ ------ ------ ------ ------ ------ ------ ------ ------ VERSION 1.2 Revision Date 06/06/16 Print Date: 6/16/16 This version replaces all previous versions Previous Issue Date: 04/20/16 The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no other warranty, express or implied, as to its correctness or completeness, or as to the results of the reliance on this document. This product is intended for skilled users at their own risk. Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Flam. Liq. 2 Flammable liquids Category 2 Flam. Liq. 3 Flammable liquids Category 3 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H225 Highly flammable liquid and vapor H226 Flammable liquid and vapor H302 Harmful if swallowed H311 Toxic in contact with skin H319 Causes serious eye irritation H336 May cause drowsiness or dizziness Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Revision date 12-Jun-2017 Version 5 Supersedes Date:12-Jun-2017 Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Product Code FS-5165.G01 Product Name 4.4 XTREME FLAT FINISH KLEAR K Other means of identification No information available Recommended use of the chemical and restrictions on use Paint, Coatings Details of the supplier of the safety data sheet See section 16 for more information 5 STAR XTREME a division of IAMG/International Autobody Marketing Group 1505 N. Hayden Road Suite 111 Scottsdale, AZ 85257 www.5StarXtreme.com 1-87REFINISH E-mail address No information available Emergency telephone number United States of America Chemtrec: 800-424-9300 American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands Chemtrec: 800-424-9300 Section 2: HAZARDS IDENTIFICATION Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity (single exposure)Category 3 Specific target organ toxicity (repeated exposure)Category 2 Aspiration toxicity Category 1 Label elements Product Code FS-5165.G01 Page 1 / 10 AGHS - USA OSHA SDS Flammable liquids Category 2 Christensen Arms AO Modification 9/7/23 Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No weight-% Acetone 67-64-1 25 - 50 n-Butyl acetate 123-86-4 10 - 25 Signal word DANGER HAZARD STATEMENTS Highly flammable liquid and vapor Causes skin irritation Causes serious eye irritation May cause cancer Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways PREVENTION Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. RESPONSE IF exposed or concerned: Get medical advice/attention.Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.Skin If skin irritation occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing.Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Fire In case of fire: Use CO2, dry chemical, or foam for extinction. STORAGE Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. DISPOSAL Dispose of contents/containers in accordance with local regulations. HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) No information available. OTHER HAZARDS Not applicable. Product Code FS-5165.G01 Page 2 / 10 AGHS - USA OSHA SDS UNKNOWN ACUTE TOXICITY .0001% of the mixture consists of ingredient(s) of unknown toxicity. Christensen Arms AO Modification 9/7/23 Xylenes 1330-20-7 10 - 25 Ethylbenzene 100-41-4 1 - 3 1-Butanol 71-36-3 1 - 3 Styrene 100-42-5 0.1 - 0.3 Toluene 108-88-3 0.1 - 0.3 *The exact percentage (concentration) of composition has been withheld as a trade secret. Section 4: FIRST AID MEASURES First Aid Measures General adviceIF exposed or concerned: Get medical advice/attention. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact If skin irritation occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Section 5: FIRE FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO2, water spray or alcohol-resistant foam. Not to be used for safety reasons: Strong water jet Specific hazards arising from the chemical Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe fumes. Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses. Section 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Product Code FS-5165.G01 Personal precautions Avoid breathing vapors or mists. Remove all sources of ignition. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Take precautionary measures against static discharges. Page 3 / 10 AGHS - USA OSHA SDS For emergency responders Use personal protection recommended in Section 8. Christensen Arms AO Modification 9/7/23 Environmental precautions Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods and material for containment and cleaning up Methods for containmentPrevent further leakage or spillage if safe to do so. Methods for cleaning up Dispose of waste product or used containers according to local regulations. Clean with detergents. Avoid solvent cleaners. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. Section 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handlingPrevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal protection recommended in Section 8. Never use pressure to empty container. Comply with the health and safety at work laws. Prevent product from entering drains. Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Use only with adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in well-ventilated areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All equipment used when handling the product must be grounded. General Hygiene Considerations When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Avoid contact with skin, eyes or clothing. Conditions for safe storage, including any incompatibilities Storage Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed in a dry and well-ventilated place. Keep tightly closed in a dry and cool place. Incompatible materials Strong bases. Strong oxidizing agents. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits If S* appears in the OEL table, it indicates this chemical contains a skin notation. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Acetone 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 n-Butyl acetate 123-86-4 STEL: 200 ppm TWA: 150 ppm TWA: 150 ppm TWA: 710 mg/m3 IDLH: 1700 ppm TWA: 150 ppm TWA: 710 mg/m3 STEL: 200 ppm STEL: 950 mg/m3 Product Code FS-5165.G01 Xylenes 1330-20-7 Page 4 / 10 STEL: 150 ppm TWA: 100 ppm AGHS - USA OSHA SDS TWA: 100 ppm TWA: 435 mg/m3 Christensen Arms AO Modification 9/7/23 Ethylbenzene 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 1-Butanol 71-36-3 TWA: 20 ppm TWA: 100 ppmTWA: 300 mg/m3 IDLH: 1400 ppmCeiling: 50 ppm Ceiling: 150 mg/m3 Styrene 100-42-5 STEL: 40 ppm TWA: 20 ppm TWA: 100 ppm Ceiling: 200 ppm IDLH: 700 ppm TWA: 50 ppm TWA: 215 mg/m3 STEL: 100 ppm STEL: 425 mg/m3 Toluene 108-88-3 TWA: 20 ppm TWA: 200 ppm Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear suitable protective clothing. Personnel should wear anti-static clothing made of natural fiber or of high temperature resistant synthetic fiber. Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Wear protective gloves. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Thermal Protection No information available Section 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state liquid Appearance No information availableOdorSolventColorcolorless Odor Threshold No information availablepH value No information availableMelting point/freezing point No information available Boiling point / boiling range 56.05 °C / 133 °Fflash point -20 °C / -4 °F evaporation rate No information available Flammability (solid, gas)No information availableFlammability Limit in Air Upper flammability limit: Product Code FS-5165.G01 No information available Page 5 / 10 AGHS - USA OSHA SDS Lower flammability limit:No information available Christensen Arms AO Modification 9/7/23 Vapor Pressure No information available vapor density No information availableDensity (lbs per US gallon)7.74specific gravity .93 Solubility(ies)No information availablePartition coefficient No information availableAutoignition temperature No information available Decomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information available Other information Section 10: STABILITY AND REACTIVITY Reactivity No information available. Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong bases. Strong oxidizing agents. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Chlorine gas. Section 11: TOXICOLOGICAL INFORMATION Information on likely routes of exposure Eye contact Causes serious eye irritationSkin ContactCauses skin irritationIngestion May be fatal if swallowed and enters airways Inhalation May cause drowsiness or dizziness Numerical measures of toxicity - Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Acetone 67-64-1 = 5800 mg/kg ( Rat )-= 50100 mg/m3 ( Rat ) 8 h n-Butyl acetate 123-86-4 = 10768 mg/kg ( Rat ) > 17600 mg/kg ( Rabbit ) = 390 ppm ( Rat ) 4 h Xylenes 1330-20-7 = 3500 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) > 4350 mg/kg ( Rabbit ) = 29.08 mg/L ( Rat ) 4 h = 5000 ppm ( Rat ) 4 h Ethylbenzene 100-41-4 = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.2 mg/L ( Rat ) 4 h 1-Butanol 71-36-3 = 700 mg/kg ( Rat ) = 790 mg/kg ( Rat ) = 3402 mg/kg ( Rabbit ) = 3400 mg/kg ( Rabbit ) > 8000 ppm ( Rat ) 4 h Styrene 100-42-5 = 1000 mg/kg ( Rat ) - = 11.7 mg/L ( Rat ) 4 h Toluene 108-88-3 = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h Numerical measures of toxicity - Product Information Product Code FS-5165.G01 The following values are calculated based on chapter 3.1 of the GHS document . Page 6 / 10 AGHS - USA OSHA SDS ATEmix (oral)21088 Mg/kg Christensen Arms AO Modification 9/7/23 ATEmix (dermal)8394 Mg/kg ATEmix (inhalation-dust/mist)9.3 mg/lATEmix (inhalation-vapor)69 mg/l UNKNOWN ACUTE TOXICITY .0001% of the mixture consists of ingredient(s) of unknown toxicity. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chemical Name ACGIH IARC NTP OSHA Ethylbenzene 100-41-4 A3 Group 2B X Styrene 100-42-5 Group 2B Reasonably Anticipated X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen.IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans.NTP (National Toxicology Program)Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen.OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present. Skin corrosion/irritation Causes skin irritation Serious eye damage/eye irritation Causes serious eye irritationSkin sensitization Not applicableRespiratory sensitization Not applicable Germ cell mutagenicity Not applicableCarcinogenicityMay cause cancerReproductive Toxicity Suspected of damaging fertility or the unborn child Specific target organ toxicity (singleexposure)May cause drowsiness or dizziness Specific target organ toxicity(repeated exposure) May cause damage to organs through prolonged or repeated exposure Aspiration hazard Not applicable Section 12: ECOLOGICAL INFORMATION Ecotoxicity Environmental precautions Prevent product from entering drains. Persistence and degradability No information available Bioaccumulation No information available Mobility No information available Other adverse effects No information available Section 13: DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Product Code FS-5165.G01 Contaminated packaging Page 7 / 10 Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned. AGHS - USA OSHA SDS Section 14: TRANSPORT INFORMATION Christensen Arms AO Modification 9/7/23 14.5 Environmental hazard Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available The supplier may apply one of the following exceptions: Combustible Liquid (49 CFR 173.150(f)); Consumer Commodity (49 CFR 173.150(c), ICAO/IATA SP A112); Limited Quantity (49 CFR 173.150(b), ICAO Part 3 Chapter 4, IATA 2.7, IMDG Chapter 3.4); Viscous Liquid (49 CFR 173.121(b), IMDG 2.3.2.2, IATA 3.3.3.1.1, ICAO 3.2.2, ADR 2.2.3.1.5); Does Not Sustain Combustion (49 CFR 173.120(a), IATA 3.3.1.3, ICAO 3.1.3, IMDG 2.3.1.3, ADR 2.2.3.1.1 Note 1); or others as allowed under hazardous materials/dangerous goods regulations. Section 15: REGULATORY INFORMATION International Inventories TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt from listing.DSL - Canadian Domestic Substances List All components are listed or exempt from listing US Federal Regulations Chemical Name SARA 313 - Threshold Values%Metals Hazardous air pollutants(HAPs) content Xylenes 1330-20-7 10 - 25 1 Present Ethylbenzene 100-41-4 1 - 3 0.1 Present 1-Butanol 71-36-3 1 - 3 1 Styrene 100-42-5 0.1 - 0.3 0.1 Present Toluene 108-88-3 0.1 - 0.3 1 Present SARA 311/312 Hazard Categories Acute health hazard YesChronic Health Hazard Yes Fire hazard YesSudden release of pressure hazard NoReactive Hazard No Chemical Name CWA - ReportableQuantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances n-Butyl acetate 123-86-4 5000 lb X Xylenes 1330-20-7 100 lb X Ethylbenzene 100-41-4 1000 lb X X X Styrene 100-42-5 1000 lb X DOT IMDG IATA14.1 UN/ID no UN1263 UN1263 UN126314.2 Proper shipping name Paint Paint Paint 14.3 Hazard Class 33314.4 Packing Group II II II 14.6 Special Provisions A3, A72, A192 Product Code FS-5165.G01 149, B52, IB2, T4, TP1, TP8, TP28,367 Page 8 / 10 Emergency Response GuideNumber 128 AGHS - USA OSHA SDS 163, 367EmS-No F-E, S-E Christensen Arms AO Modification 9/7/23 Toluene 108-88-3 1000 lb X X X Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Acetone 67-64-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ n-Butyl acetate 123-86-4 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ Xylenes 1330-20-7 100 lb RQ 100 lb final RQRQ 45.4 kg final RQ Ethylbenzene 100-41-4 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ 1-Butanol 71-36-3 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ Styrene 100-42-5 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ Toluene 108-88-3 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations Rule 66 status of product Photochemically reactive. California Proposition 65 WARNING! This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. U.S. EPA Label informationEPA Pesticide registration number Not applicable U.S. State Right-to-Know Regulations Chemical Name Acetone 67-64-1 . n-Butyl acetate 123-86-4 . Proprietary Non-Hazardous Ingredient - Proprietary CAS . Xylenes 1330-20-7 . Proprietary Non-Hazardous Ingredient - Proprietary CAS . Proprietary Inert . Ethylbenzene 100-41-4 . 1-Butanol 71-36-3 . Styrene 100-42-5 . Toluene 108-88-3 . Section 16: OTHER INFORMATION HMISHealth hazards 3* * = Chronic Health Hazard Flammability 3 Product Code FS-5165.G01 Physical hazards Page 9 / 10 0 AGHS - USA OSHA SDS Personal Protection X Christensen Arms AO Modification 9/7/23 Prepared By Regulatory Department Revision date 12-Jun-2017Revision Note No information available DisclaimerThe information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current nationallegislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge andcontrol the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDSshould not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, ANDDISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR APARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Product Code FS-5165.G01 Page 10 / 10 End of Safety Data Sheet AGHS - USA OSHA SDS Christensen Arms AO Modification 9/7/23             !"#$%&&'()(*+,&& -. # /01&2*%&&*&&*)2(*&&!$3)'33*333+*23%%)( 4!,53 4                     !   " " " " #  "/6 6780*800- "-9 2&28 4:  "  ;6((223 $%    &   %   :     5,< 5,<   " !    ' " !"#%55*<))*+<2& -. #    $ !    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" #    ./01/'/, /2Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 SAFETY DATA SHEET No. 9 Gun Bore Cleaner According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200 1. Identification Product identifier Product name No. 9 Gun Bore Cleaner Product number 902, 902CN, 902RH, 904, 904CN, 904P, 916, 916CN, 932, 9501 Recommended use of the chemical and restrictions on use Application Remove leading and metal fouling from gun bores. Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer Bushnell Holdings Inc 9200 Cody Overland Park, KS 66214 1-800-423-3537 dangerous.goods@vistaoutdoor.com Emergency telephone number Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) - (CHEMTREC, Day and Night) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Flam. Liq. 2 - H225 Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335, H336 Asp. Tox. 1 - H304 Environmental hazards Aquatic Acute 3 - H402 Aquatic Chronic 2 - H411 Label elements Pictogram Signal word Danger Hazard statements H225 Highly flammable liquid and vapor. H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H402 Harmful to aquatic life. H411 Toxic to aquatic life with long lasting effects. 1/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames and hot surfaces. No smoking. P240 Ground/ bond container and receiving equipment. P241 Use explosion-proof electrical equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing vapor/ spray. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301+P310 If swallowed: Immediately call a poison center/ doctor. P301+P312 If swallowed: Call a poison center/ doctor if you feel unwell. P302+P352 If on skin: Wash with plenty of water. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned: Get medical advice/ attention. P321 Specific treatment (see medical advice on this label). P330 Rinse mouth. P331 Do NOT induce vomiting. P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container in accordance with national regulations. Contains Kerosene (petroleum), Ethanol, propan-2-ol, Proprietary, Proprietary, Proprietary, Proprietary, Proprietary, Proprietary, Citronellol Other hazards This product does not contain any substances classified as PBT or vPvB. 3. Composition/information on ingredients Mixtures 2/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Kerosene (petroleum)30-60% CAS number: 8008-20-6 Classification Flam. Liq. 4 - H227 Skin Irrit. 2 - H315 STOT SE 3 - H336 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Ethanol 10-30% CAS number: 64-17-5 Classification Flam. Liq. 2 - H225 Eye Irrit. 2A - H319 STOT SE 3 - H335, H336 propan-2-ol 5-10% CAS number: 67-63-0 Classification Flam. Liq. 2 - H225 Eye Irrit. 2A - H319 STOT SE 3 - H336 Amyl Acetate 1-5% CAS number: 628-63-7 Classification Flam. Liq. 3 - H226 2-methylbutyl acetat 1-5% CAS number: 624-41-9 Classification Flam. Liq. 3 - H226 methanol 1-5% CAS number: 67-56-1 Classification Flam. Liq. 2 - H225 Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 STOT SE 1 - H370 3/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Ammonium Hydroxide <1% CAS number: 1336-21-6 M factor (Acute) = 1 Classification Skin Corr. 1B - H314 Eye Dam. 1 - H318 STOT SE 3 - H335 Aquatic Acute 1 - H400 (R)-p-mentha-1,8-diene <1% CAS number: 5989-27-5 M factor (Acute) = 1 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 3 - H412 1,8 cineole <1% CAS number: 470-82-6 Classification Flam. Liq. 3 - H226 Skin Sens. 1B - H317 4-methylpentan-2-one <1% CAS number: 108-10-1 Classification Flam. Liq. 2 - H225 Acute Tox. 4 - H332 Eye Irrit. 2A - H319 STOT SE 3 - H335 geraniol <1% CAS number: 106-24-1 Classification Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Aquatic Acute 2 - H401 4/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner naphthalene <1% CAS number: 91-20-3 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Acute Tox. 4 - H302 Carc. 2 - H351 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Nerol <1% CAS number: 106-25-2 Classification Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1B - H317 Aquatic Acute 3 - H402 Citronellol <1% CAS number: 106-22-9 Classification Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 Skin Sens. 1 - H317 Aquatic Acute 2 - H401 p-Cymene 0.121% CAS number: 99-87-6 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 STOT SE 3 - H335 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 5/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner diammonium peroxodisulphate <1% CAS number: 7727-54-0 Classification Ox. Sol. 3 - H272 Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 STOT SE 3 - H335 The full text for all hazard statements is displayed in Section 16. Composition comments * The identity or exact percentage is withheld as a trade secret in accordance with 29 CFR 1910.1200. 4. First-aid measures Description of first aid measures General information Get medical attention immediately. Show this Safety Data Sheet to the medical personnel. Inhalation Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Place unconscious person on their side in the recovery position and ensure breathing can take place. Ingestion Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Place unconscious person on their side in the recovery position and ensure breathing can take place. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. Skin Contact It is important to remove the substance from the skin immediately. Take off immediately all contaminated clothing. Remove contamination with soap and water or recognized skin cleansing agent. Get medical attention. Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 10 minutes. Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. If it is suspected that volatile contaminants are still present around the affected person, first aid personnel should wear an appropriate respirator or self-contained breathing apparatus. Wash contaminated clothing thoroughly with water before removing it from the affected person, or wear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation. Most important symptoms and effects, both acute and delayed General information See Section 11 for additional information on health hazards. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. 6/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Inhalation A single exposure may cause the following adverse effects: Headache. Exhaustion and weakness. Prolonged or repeated exposure may cause the following adverse effects: Suspected of causing cancer. Ingestion May cause sensitization or allergic reactions in sensitive individuals. May cause discomfort if swallowed. Stomach pain. Nausea, vomiting. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Prolonged or repeated exposure may cause the following adverse effects: Suspected of causing cancer. Skin contact May cause skin sensitization or allergic reactions in sensitive individuals. Redness. Irritating to skin. Prolonged or repeated exposure may cause the following adverse effects: Suspected of causing cancer. Eye contact Irritating to eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. May cause sensitization or allergic reactions in sensitive individuals. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Flammable liquid and vapour. Vapors may be ignited by a spark, a hot surface or an ember. Vapors may form explosive mixtures with air. Fire-water run-off in sewers may create fire or explosion hazard. This product is toxic. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Toxic gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Special protective equipment for firefighters Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures 7/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Personal precautions No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure procedures and training for emergency decontamination and disposal are in place. Do not touch or walk into spilled material. Evacuate area. Provide adequate ventilation. No smoking, sparks, flames or other sources of ignition near spillage. Promptly remove any clothing that becomes contaminated. Avoid inhalation of vapors and spray/mists. Use suitable respiratory protection if ventilation is inadequate. Avoid contact with skin and eyes. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Methods and material for containment and cleaning up Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Eliminate all ignition sources if safe to do so. No smoking, sparks, flames or other sources of ignition near spillage. Do not allow material to enter confined spaces, due to the risk of explosion. Provide adequate ventilation. Absorb small quantities with paper towels and evaporate in a safe place. Once evaporation is complete, place paper in a suitable waste disposal container and seal securely. Large Spillages: If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Dangerous for the environment. Do not empty into drains. For waste disposal, see Section 13. Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. The product is flammable. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. In use may form flammable/explosive vapour-air mixture. Vapors may accumulate on the floor and in low- lying areas. Use explosion-proof electrical, ventilating and lighting equipment. Use only non- sparking tools. Take precautionary measures against static discharges. Suspected of causing cancer. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash at the end of each work shift and before eating, smoking and using the toilet. Change work clothing daily before leaving workplace. Conditions for safe storage, including any incompatibilities 8/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Eliminate all sources of ignition. Take precautionary measures against static discharges. Ground container and transfer equipment to eliminate sparks from static electricity. Keep away from oxidizing materials, heat and flames. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Utilize retaining walls to prevent soil and water pollution in the event of spillage. The storage area floor should be leak-tight, jointless and not absorbent. Storage class Flammable liquid storage. Specific end uses(s) Specific end use(s)The identified uses for this product are detailed in Section 1. 8. Exposure Controls/personal protection Control parameters Occupational exposure limits Kerosene (petroleum) Long-term exposure limit (8-hour TWA): ACGIH 200 mg/m³ A3, Sk Ethanol Short-term exposure limit (15-minute): ACGIH 1000 ppm 1880 mg/m³ A3 Long-term exposure limit (8-hour TWA): OSHA 1000 ppm 1900 mg/m³ propan-2-ol Long-term exposure limit (8-hour TWA): OSHA 400 ppm 980 mg/m³ Long-term exposure limit (8-hour TWA): ACGIH 200 ppm 492 mg/m³ Short-term exposure limit (15-minute): ACGIH 400 ppm 984 mg/m³ A4 Amyl Acetate Long-term exposure limit (8-hour TWA): OSHA 100 ppm 525 mg/m³ Long-term exposure limit (8-hour TWA): ACGIH 50 ppm 266 mg/m³ Short-term exposure limit (15-minute): ACGIH 100 ppm 532 mg/m³ 2-methylbutyl acetat Long-term exposure limit (8-hour TWA): ACGIH 50 ppm 266 mg/m³ Short-term exposure limit (15-minute): ACGIH 100 ppm 532 mg/m³ methanol Long-term exposure limit (8-hour TWA): ACGIH 200 ppm 262 mg/m³ Short-term exposure limit (15-minute): ACGIH 250 ppm 328 mg/m³ Sk Long-term exposure limit (8-hour TWA): OSHA 200 ppm 260 mg/m³ 4-methylpentan-2-one Long-term exposure limit (8-hour TWA): ACGIH 20 ppm 82 mg/m³ Short-term exposure limit (15-minute): ACGIH 75 ppm 307 mg/m³ A3 Long-term exposure limit (8-hour TWA): OSHA 100 ppm 410 mg/m³ naphthalene Long-term exposure limit (8-hour TWA): OSHA 10 ppm 50 mg/m³ Long-term exposure limit (8-hour TWA): ACGIH 10 ppm 52 mg/m³ A3, DSens, Sk 9/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner diammonium peroxodisulphate Long-term exposure limit (8-hour TWA): ACGIH 0.1 mg/m³ ACGIH = American Conference of Governmental Industrial Hygienists. OSHA = Occupational Safety and Health Administration. A3 = Confirmed Animal Carcinogen with Unknown Relevance to Humans. Sk = Danger of cutaneous absorption. A4 = Not Classifiable as a Human Carcinogen. DSens = Dermal sensitizer. Ethanol (CAS: 64-17-5) Immediate danger to life and health 3300 ppm propan-2-ol (CAS: 67-63-0) Immediate danger to life and health 2000 ppm Amyl Acetate (CAS: 628-63-7) Immediate danger to life and health 1000 ppm methanol (CAS: 67-56-1) Immediate danger to life and health 6000 ppm 4-methylpentan-2-one (CAS: 108-10-1) Immediate danger to life and health 500 ppm naphthalene (CAS: 91-20-3) Immediate danger to life and health 250 ppm Exposure controls Protective equipment Appropriate engineering controls Provide adequate ventilation. Personal, workplace environment or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimize worker exposure. Personal protective equipment should only be used if worker exposure cannot be controlled adequately by the engineering control measures. Ensure control measures are regularly inspected and maintained. Ensure operatives are trained to minimize exposure. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilating equipment. 10/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Personal protective equipment for eye and face protection should comply with OSHA 1910.133. Wear tight-fitting, chemical splash goggles or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resist degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended. Other skin and body protection Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible. Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment and the work area every day. Good personal hygiene procedures should be implemented. Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial medical examinations should be carried out. Warn cleaning personnel of any hazardous properties of the product. Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for its intended use and is NIOSH approved. Check that the respirator fits tightly and the filter is changed regularly. Gas and combination filter cartridges should comply with OSHA 1910.134. Full face mask respirators with replaceable filter cartridges should comply with OSHA 1910.134. Half mask and quarter mask respirators with replaceable filter cartridges should comply with OSHA 1910.134. Environmental exposure controls Keep container tightly sealed when not in use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. Physical and Chemical Properties Information on basic physical and chemical properties Appearance Clear liquid. Color Amber. Odor Characteristic. Odor threshold No information available. pH No information available. Melting point >-114.2°C/-173.5°F Initial boiling point and range >47.0°C/116.6°F Flash point > 12.8°C/55.0°F Evaporation rate No information available. Flammability (solid, gas)Class IB Liquid Upper/lower flammability or explosive limits Lower flammable/explosive limit: 0.70 % Upper flammable/explosive limit: 19 % 11/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Vapor pressure 248.35 mm Hg @ 25°C Vapor density 9.700 g/cc Maximum Relative density 0.844 g/cc Solubility(ies)No information available. Partition coefficient No information available. Auto-ignition temperature 210.0°C/410.0°F Decomposition Temperature No information available. Viscosity 4.2-4.8 cP @ 25°C Explosive properties No information available. Oxidizing properties Not available. Volatile organic compound This product contains a maximum VOC content of 73 %, WT. This product contains a maximum VOC content of 75 VOL, %. VOC Content 5.028 lbs/gal (602.474 g/L) 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions The following materials may react strongly with the product: Oxidizing agents. Conditions to avoid Avoid heat, flames and other sources of ignition. Containers can burst violently or explode when heated, due to excessive pressure build-up. Static electricity and formation of sparks must be prevented. Do not pressurize, cut, weld, drill, grind or otherwise expose containers to heat or sources of ignition. Materials to avoid Oxidizing materials. Acids - oxidizing. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Toxic gases or vapors. 11. Toxicological information Information on toxicological effects Acute toxicity - oral Notes (oral LD₅₀)Acute Tox. 4 - H302 Harmful if swallowed. ATE oral (mg/kg)1,595.38 Acute toxicity - dermal Notes (dermal LD₅₀)Acute Tox. 4 - H312 Harmful in contact with skin. ATE dermal (mg/kg)1,199.57 Acute toxicity - inhalation Notes (inhalation LC₅₀)Acute Tox. 4 - H332 Harmful if inhaled. 12/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner ATE inhalation (gases ppm)44,224.03 ATE inhalation (vapours mg/l)12.81 Skin corrosion/irritation Animal data Irritating. Serious eye damage/irritation Serious eye damage/irritation Causes serious eye irritation. Respiratory sensitization Respiratory sensitization Based on available data the classification criteria are not met. Skin sensitization Skin sensitization May cause skin sensitization or allergic reactions in sensitive individuals. Germ cell mutagenicity Genotoxicity - in vitro Based on available data the classification criteria are not met. Carcinogenicity Carcinogenicity Suspected of causing cancer. IARC carcinogenicity Contains a substance/a group of substances which may cause cancer. IARC Group 1 Carcinogenic to humans. Reproductive toxicity Reproductive toxicity - fertility Based on available data the classification criteria are not met. Reproductive toxicity - development Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure STOT - single exposure STOT SE 3 - H335, H336 May cause respiratory irritation. May cause drowsiness or dizziness. Target organs Respiratory system, lungs Central nervous system Specific target organ toxicity - repeated exposure STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Asp. Tox. 1 - H304 May be fatal if swallowed and enters airways. Pneumonia may be the result if vomited material containing solvents reaches the lungs. General information May cause cancer after repeated exposure. Risk of cancer depends on duration and level of exposure. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Headache. Exhaustion and weakness. Ingestion May cause sensitization or allergic reactions in sensitive individuals. May cause discomfort if swallowed. Stomach pain. Nausea, vomiting. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Skin Contact May cause skin sensitization or allergic reactions in sensitive individuals. Redness. Irritating to skin. Eye contact Irritating to eyes. 13/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Route of entry Ingestion Inhalation Skin and/or eye contact Target Organs Central nervous system Respiratory system, lungs Medical considerations Skin disorders and allergies. 12. Ecological Information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment. Toxicity Aquatic Chronic 2 - H411 Toxic to aquatic life with long lasting effects. Persistence and degradability Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility No data available. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. Disposal of this product, process solutions, residues and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any local authority requirements. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labeled with their contents. Incineration or landfill should only be considered when recycling is not feasible. Vapor from residual product may create a highly flammable or explosive atmosphere inside the container. Containers should be thoroughly emptied before disposal because of the risk of an explosion. Do not cut or weld used containers unless they have been thoroughly cleaned internally. 14. Transport information General For limited quantity packaging/limited load information, consult the relevant modal documentation using the data shown in this section. UN Number UN No. (TDG)1993 UN No. (IMDG)1993 14/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner UN No. (ICAO)1993 UN No. (DOT)UN1993 UN proper shipping name Proper shipping name (TDG)FLAMMABLE LIQUID, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum)) Proper shipping name (IMDG)FLAMMABLE LIQUID, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum), Ammonium Hydroxide, (R)-p-mentha-1,8-diene) Proper shipping name (ICAO)FLAMMABLE LIQUID, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum)) Proper shipping name (DOT)FLAMMABLE LIQUIDS, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum)) Transport hazard class(es) DOT hazard class 3 DOT hazard label 3 TDG class 3 TDG label(s)3 IMDG Class 3 ICAO class/division 3 Transport labels Limited Quantity Packaging (Class 3) Limited Quantity DOT Limited Quantity (Class 3) Limited Quantity diamond ICAO/IATA Limited Quantity (Class 3) TDG Limited Quantity Diamond (Class 3) IMDG Limited Quantity (Class 3) ADR Limited Quantity (Class 3) Packing group TDG Packing Group II IMDG packing group II ICAO packing group II DOT packing group II Environmental hazards 15/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Environmentally Hazardous Substance Special precautions for user Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. EmS F-E, S-E DOT reportable quantity RQ: Ammonium hydroxide (31172.0698 lbs), RQ: Naphthalene (63261.1102 lbs) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. 15. Regulatory information US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) The following ingredients are listed or exempt: naphthalene Final CERCLA RQ: 100(45.4) pounds (Kilograms) Ammonium Hydroxide Final CERCLA RQ: 1000(454) pounds (Kilograms) Amyl Acetate Final CERCLA RQ: 5000(2270) pounds (Kilograms) 4-methylpentan-2-one Final CERCLA RQ: 5000(2270) pounds (Kilograms) methanol Final CERCLA RQ: 5000(2270) pounds (Kilograms) SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting The following ingredients are listed or exempt: naphthalene 0.1 % diammonium peroxodisulphate 1.0 % Ammonium Hydroxide 1.0 % 4-methylpentan-2-one 1.0 % methanol 1.0 % 16/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories None of the ingredients are listed or exempt. OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins The following ingredients are listed or exempt: naphthalene Known to the State of California to cause cancer. 4-methylpentan-2-one Known to the State of California to cause cancer and developmental reproductive toxicity. methanol Known to the State of California to cause developmental and reproductive toxicity. California Air Toxics "Hot Spots" (A-I) The following ingredients are listed or exempt: naphthalene 4-methylpentan-2-one methanol propan-2-ol California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. California Directors List of Hazardous Substances The following ingredients are listed or exempt: naphthalene Ammonium Hydroxide Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol Massachusetts "Right To Know" List The following ingredients are listed or exempt: naphthalene Kerosene (petroleum) Ammonium Hydroxide 17/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol p-Cymene Rhode Island "Right To Know" List The following ingredients are listed or exempt: naphthalene Kerosene (petroleum) Oleic Acid Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol Minnesota "Right To Know" List The following ingredients are listed or exempt: naphthalene Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol New Jersey "Right To Know" List The following ingredients are listed or exempt: naphthalene Kerosene (petroleum) diammonium peroxodisulphate Ammonium Hydroxide Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol Pennsylvania "Right To Know" List The following ingredients are listed or exempt: naphthalene Kerosene (petroleum) Ammonium Hydroxide 18/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Oleic Acid Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol p-Cymene Inventories US - TSCA The following ingredients are listed or exempt: naphthalene Kerosene (petroleum) diammonium peroxodisulphate Ammonium Hydroxide Oleic Acid 2-methylbutyl acetat Amyl Acetate 4-methylpentan-2-one methanol propan-2-ol Ethanol g-Terpinene Nerol Citronellol p-Cymene geraniol (R)-p-mentha-1,8-diene 1,8 cineole US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information Classification abbreviations and acronyms Flam. Liq. = Flammable liquid Acute Tox. = Acute toxicity Asp. Tox. = Aspiration hazard Carc. = Carcinogenicity Eye Irrit. = Eye irritation Skin Irrit. = Skin irritation Skin Sens. = Skin sensitisation STOT SE = Specific target organ toxicity-single exposure Aquatic Chronic = Hazardous to the aquatic environment (chronic) Training advice Read and follow manufacturer's recommendations. Only trained personnel should use this material. 19/20Christensen Arms AO Modification 9/7/23 Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019 No. 9 Gun Bore Cleaner Revision comments Revised for new Authoring software Revision date 12/2/2019 Revision 10 Supersedes date 6/10/2019 SDS No.4517 Hazard statements in full H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H227 Combustible liquid. H272 May intensify fire; oxidizer. H301 Toxic if swallowed. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H370 Causes damage to organs . H400 Very toxic to aquatic life. H401 Toxic to aquatic life. H402 Harmful to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. End of Safety Data Sheet This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 20/20Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 SAFETY DATA SHEET Lubricating Oil According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200 1. Identification Product identifier Product name Lubricating Oil Chemical name Process Oil Product number 1003, 1003B, 1003RB, 1003CN Internal identification 1000-202 CAS number 64742-54-7 Recommended use of the chemical and restrictions on use Application Firearm Lubrication Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer Bushnell Holdings Inc 9200 Cody Overland Park, KS 66214 1-800-423-3537 dangerous.goods@vistaoutdoor.com Emergency telephone number Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) - (CHEMTREC, Day and Night) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Not Classified Health hazards Not Classified Environmental hazards Not Classified Label elements Hazard statements NC Not Classified Other hazards This substance is not classified as PBT or vPvB according to current EU criteria. 3. Composition/information on ingredients Substances Product name Lubricating Oil Chemical name Process Oil CAS number 64742-54-7 4. First-aid measures Description of first aid measures 1/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medical personnel. Inhalation No specific recommendations. If throat irritation or coughing persists, proceed as follows. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if any discomfort continues. Ingestion No specific recommendations. If throat irritation or coughing persists, proceed as follows. Rinse mouth. Get medical attention if any discomfort continues. Skin Contact No specific recommendations. Rinse with water. Get medical attention if any discomfort continues. Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical attention if any discomfort continues. Protection of first aiders Use protective equipment appropriate for surrounding materials. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation. Ingestion No specific symptoms known. May cause discomfort if swallowed. Skin contact No specific symptoms known. May cause discomfort. Eye contact No specific symptoms known. May be slightly irritating to eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. Specific treatments No special treatment required. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 2/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions No specific recommendations. For personal protection, see Section 8. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Methods and material for containment and cleaning up Methods for cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Dispose of contents/container in accordance with national regulations. Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). No specific recommendations. Storage class Unspecified storage. Specific end uses(s) Specific end use(s)The identified uses for this product are detailed in Section 1. 8. Exposure Controls/personal protection Control parameters Occupational exposure limits Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³ Long-term exposure limit (8-hour TWA): ACGIH 5 mg/m³ Short-term exposure limit (15-minute): ACGIH 10 mg/m³ OSHA = Occupational Safety and Health Administration. ACGIH = American Conference of Governmental Industrial Hygienists. Exposure controls Protective equipment Appropriate engineering controls No specific ventilation requirements. Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. 3/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves. Other skin and body protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke when using this product. Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Not regarded as dangerous for the environment. 9. Physical and Chemical Properties Information on basic physical and chemical properties Appearance Clear liquid. Color Water-white. Odor Odorless. pH Not applicable. Melting point Not determined. Initial boiling point and range 315°C/599°F Flash point 192°C/378°F Evaporation rate No information available. Flammability (solid, gas)Class IIIB Liquid Upper/lower flammability or explosive limits Not available. Vapor pressure < 0.01 mm Hg @ 25°C Vapor density > 1.0 g/cc Relative density 0.866 Bulk density 7.228 lb/gal Solubility(ies)Insoluble in water. Partition coefficient Not determined. Auto-ignition temperature 210°C/410°F Decomposition Temperature Not determined. Volatility 3% wt (Max) 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions No potentially hazardous reactions known. 4/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil Conditions to avoid There are no known conditions that are likely to result in a hazardous situation. Materials to avoid No specific material or group of materials is likely to react with the product to produce a hazardous situation. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. 11. Toxicological information Information on toxicological effects Toxicological effects Not regarded as a health hazard under current legislation. Acute toxicity - oral Notes (oral LD₅₀)Based on available data the classification criteria are not met. Acute toxicity - dermal Notes (dermal LD₅₀)Based on available data the classification criteria are not met. Acute toxicity - inhalation Notes (inhalation LC₅₀)Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Based on available data the classification criteria are not met. Serious eye damage/irritation Serious eye damage/irritation Based on available data the classification criteria are not met. Respiratory sensitization Respiratory sensitization Based on available data the classification criteria are not met. Skin sensitization Skin sensitization Based on available data the classification criteria are not met. Germ cell mutagenicity Genotoxicity - in vitro Based on available data the classification criteria are not met. Carcinogenicity Carcinogenicity Based on available data the classification criteria are not met. IARC carcinogenicity None of the ingredients are listed or exempt. Reproductive toxicity Reproductive toxicity - fertility Based on available data the classification criteria are not met. Reproductive toxicity - development Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure STOT - single exposure Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Based on available data the classification criteria are not met. 5/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil General information No specific health hazards known. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation. Ingestion No specific symptoms known. May cause discomfort if swallowed. Skin Contact No specific symptoms known. May cause discomfort. Eye contact No specific symptoms known. May be slightly irritating to eyes. Route of entry Ingestion Inhalation Skin and/or eye contact Target Organs No specific target organs known. 12. Ecological Information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment. Toxicity Based on available data the classification criteria are not met. Persistence and degradability Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient Not determined. Mobility in soil Mobility No data available. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste packaging should be collected for reuse or recycling. Incineration or landfill should only be considered when recycling is not feasible. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of the local water authority. 14. Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, DOT). UN Number Not applicable. UN proper shipping name Not applicable. 6/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil Transport hazard class(es) No transport warning sign required. Packing group Not applicable. Environmental hazards Environmentally Hazardous Substance No. Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. 15. Regulatory information US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) None of the ingredients are listed or exempt. SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting None of the ingredients are listed or exempt. CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories None of the ingredients are listed or exempt. OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-I) None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. 7/8Christensen Arms AO Modification 9/7/23 Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017 Lubricating Oil California Directors List of Hazardous Substances None of the ingredients are listed or exempt. Massachusetts "Right To Know" List None of the ingredients are listed or exempt. Rhode Island "Right To Know" List None of the ingredients are listed or exempt. Minnesota "Right To Know" List None of the ingredients are listed or exempt. New Jersey "Right To Know" List None of the ingredients are listed or exempt. Pennsylvania "Right To Know" List None of the ingredients are listed or exempt. Inventories US - TSCA None of the ingredients are listed or exempt. US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information Classification abbreviations and acronyms Asp. Tox. = Aspiration hazard Training advice Only trained personnel should use this material. Revision date 2/8/2019 Revision 7 Supersedes date 10/9/2017 SDS No.4634 End of Safety Data Sheet This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8/8Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 page 1 of 3 FLASH POINT 35 °F TCC Specific Gravity 0.85 Product Weight 7.04 lb/gal 12 00 [0365] ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) Date of Preparation May 21, 2019 PRODUCT NUMBER 530-2146 PRODUCT NAME Reducer NO. K69 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) 530-2146 = | Acute | Chronic | Fire | Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume Toluene 108-88-3 N Y Y Y 15 15 Ethylbenzene 100-41-4 N Y Y Y 9 9 Xylene 1330-20-7 N Y Y Y 52 51 Methyl Isobutyl Ketone 108-10-1 N Y Y Y 24 25 Volatile Organic Compounds - U.S. EPA / Canada 530-2146 LB/Gal g/L Coating Density 7.04 843 By wt By vol Total Volatiles 100.0% 100.0% Federally exempt solvents Water 0.0%0.0% Organic Volatiles 100.0% 100.0% Percent Non-Volatile 0.0%0.0% VOC Content LB/Gal g/L Total 7.03 843 Less exempt solvents 7.03 843 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg By wt By wt LVP-VOC 100.0% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 5.84 Christensen Arms AO Modification 9/7/23 530-2146 page 2 of 3 Volatile Organic Compounds - California 530-2146 LB/Gal g/L Coating Density 7.04 843 By wt By vol Total Volatiles 100.0% 100.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 100.0% 100.0% Percent Non-Volatile 0.0%0.0% VOC Content LB/Gal g/L Total 7.03 843 Less exempt solvents 7.03 843 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg By wt By wt LVP-VOC 100.0% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 5.77 Volatile Organic Compounds - South Coast Air Quality Management District, California, US 530-2146 LB/Gal g/L Coating Density 7.04 843 By wt By vol Total Volatiles 100.0% 100.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 100.0% 100.0% Percent Non-Volatile 0.0%0.0% VOC Content LB/Gal g/L Total 7.03 843 Less exempt solvents 7.03 843 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC 530-2146 By wt By vol Total Volatiles 100.0% 100.0% VOC Content LB/Gal g/L Total 7.03 843 Volatile Organic Compounds - EU Directive 2010/75/EU 530-2146 By wt By vol Total Volatiles 100.0% 100.0% VOC Content LB/Gal g/L Total 7.03 843 Christensen Arms AO Modification 9/7/23 530-2146 page 3 of 3 Volatile Organic Compounds - Mexico 530-2146 LB/Gal g/L Coating Density 7.04 843 By wt By vol Total Volatiles 100.0% 100.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 100.0% 100.0% Percent Non-Volatile 0.0%0.0% VOC Content LB/Gal g/L Total 7.03 843 Less exempt solvents 7.03 843 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg Hazardous Air Pollutants (Clean Air Act, Section 112(b)) 530-2146 LB/Gal kg/L Volatile HAPS 7.03 0.843 100.00 % by wt Of solids lb/gal kg/l of solids Not applicable Of solids lb/lb kg/kg of solids Not applicable Air Quality Data Density of Organic Solvent Blend 7.04 lb/gal Photochemically Reactive Yes Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Christensen Arms AO Modification 9/7/23      !"!# $ %&'()*+###"+!#," ,,#,,, #+,"!-.$ ,/./                    !   " " " " #  "(0'0'1)#1))2% %324 ++1 3.52 6 0!!++, $%    &   %  357 ,$#" !+ ,$#" !+   " !    ' "+##!8!#$8 ! %&2 $ !    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Identification : : Supplier's details :Chem-Trend LP 1445 W McPherson Park Dr PO Box 860, Howell MI 48844-0860 517-546-4520 Mono-Coat® E179 N-ODS Relevant identified uses of the substance or mixture and uses advised against Release Agent Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word :Danger Hazard statements :Highly flammable liquid and vapor. Harmful if inhaled. Causes serious eye damage. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Hazard pictograms : Precautionary statements Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 36.7% OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 1/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 2. Hazards identification Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Storage :Store locked up. Store in a well-ventilated place. Keep cool. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :None known. Section 3. Composition/information on ingredients propan-1-ol ≥25 - ≤50 71-23-8 Light aliphatic naphtha ≥25 - ≤50 - nonane ≥10 - ≤25 111-84-2 ethanol ≤3 64-17-5 Glycol ≤3 - Ingredient name CAS number% Substance/mixture :Mixture Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 2/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :Causes skin irritation. Causes serious eye damage.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: stomach pains nausea or vomiting Adverse symptoms may include the following: pain or irritation redness blistering may occur : : : Eye contact :Adverse symptoms may include the following: pain watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 3/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Precautions for safe handling Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 4/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits propan-1-ol OSHA PEL 1989 (United States, 3/1989). TWA: 200 ppm 8 hours. TWA: 500 mg/m³ 8 hours. STEL: 250 ppm 15 minutes. STEL: 625 mg/m³ 15 minutes. OSHA PEL (United States, 6/2016). TWA: 200 ppm 8 hours. TWA: 500 mg/m³ 8 hours. ACGIH TLV (United States, 3/2016). TWA: 100 ppm 8 hours. nonane ACGIH TLV (United States, 3/2016). TWA: 200 ppm 8 hours. TWA: 1050 mg/m³ 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 200 ppm 8 hours. TWA: 1050 mg/m³ 8 hours. ethanol ACGIH TLV (United States, 3/2016). STEL: 1000 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. OSHA PEL (United States, 6/2016). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. Glycol ACGIH TLV (United States, 3/2016). Absorbed through skin. TWA: 100 ppm 8 hours. TWA: 606 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 909 mg/m³ 15 minutes. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. Ingredient name Exposure limits Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 5/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. TWA: 100 ppm 8 hours. TWA: 600 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 900 mg/m³ 15 minutes. OSHA PEL (United States, 6/2016). Absorbed through skin. TWA: 100 ppm 8 hours. TWA: 600 mg/m³ 8 hours. Section 9. Physical and chemical properties Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 6/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative densityVapor density Solubility Liquid. Not available. 0.77>1 [Air = 1] Not available. Insoluble in the following materials: cold water. Hydrocarbon.Odor pH Colorless.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 14°C (57.2°F) [ Pensky-Martens] Not available. Not available. Viscosity Kinematic (40°C (104°F)): <0.2 cm2/s (<20 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water Boiling point 118°C (244.4°F) Flammability (solid, gas) Not available. Lower and upper explosive (flammable) limits Not available. Burning rate Not applicable.Burning time Not applicable. SADT Not available.Decomposition temperature Not available. Solubility in water Not available. Volatility 98.54 nonane Lower: 0.8% Upper: 2.9% Naphtha (petroleum), hydrotreated light Lower: 1.05% Upper: 7.6% (2-methoxymethylethoxy)propanol Lower: 1.1% Upper: 14% propan-1-ol Lower: 2.1% Upper: 13.5% ethanol Lower: 3.3% Upper: 19% Lower and upper explosive (flammable) limits Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Formaldehyde and silicon dioxide may be evolved at elevated temperatures. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 7/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 11. Toxicological information Acute toxicity propan-1-ol LD50 Dermal Rabbit 5040 mg/kg - LD50 Oral Rat 1870 mg/kg - nonane LC50 Inhalation Gas.Rat 3200 ppm 4 hours LC50 Inhalation Vapor Rat 17000 mg/m³4 hours ethanol LC50 Inhalation Vapor Rat 124700 mg/m³4 hours LD50 Oral Rat 7 g/kg - Product/ingredient name Result Species Dose Exposure Information on the likely routes of exposure Inhalation :Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :Causes skin irritation. Causes serious eye damage.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact IngestionInhalation Adverse symptoms may include the following: pain or irritation redness blistering may occur Eye contact Adverse symptoms may include the following: pain watering redness Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) propan-1-ol Narcotic effects Light aliphatic naphtha Narcotic effects Name Not available. Aspiration hazard Name Result Light aliphatic naphtha ASPIRATION HAZARD - Category 1 nonane ASPIRATION HAZARD - Category 1 Target organs Information on toxicological effects :Not available. Potential acute health effects Irritation/Corrosion :Causes serious eye damage. Causes skin irritation. Sensitization :No known significant effects or critical hazards. Mutagenicity :No known significant effects or critical hazards. Carcinogenicity : Reproductive toxicity :No known significant effects or critical hazards. Teratogenicity :No known significant effects or critical hazards. Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 8/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 11. Toxicological information Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: stomach pains nausea or vomiting Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Inhalation (gases)17993.6 ppm Inhalation (vapors)95.59 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods RCRA classification :D001 Because of its ignitability if the product is disposed of in its original form. Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 9/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 14. Transport information Flammable liquids, n.o.s. (Light aliphatic naphtha, nonane) 3 II FLAMMABLE LIQUID, N.O.S. (Light aliphatic naphtha, nonane) 3 II UN1993 UN1993 The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. Emergency schedules (EmS) F-E, _S-E_ Special provisions 274 DOT Classification IMDGIATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No.Yes. TDG Classification UN1993 FLAMMABLE LIQUID, N.O.S. (Light aliphatic naphtha, nonane) 3 II No. Flammable liquid, n.o.s. (Light aliphatic naphtha, nonane) 3 II The environmentally hazardous substance mark may appear if required by other transportation regulations. Passenger and Cargo Aircraft Quantity limitation: 5 L Packaging instructions: 353 Cargo Aircraft OnlyQuantity limitation: 60 L Packaging instructions: 364 Limited Quantities - Passenger AircraftQuantity limitation: 1 L Packaging instructions: Y341 Special provisions A3 No. UN1993UN1993 Flammable liquids, n.o.s.(Light aliphatic naphtha, nonane) 3 II Yes Bulk Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 5 L Cargo aircraft Quantity limitation: 60 L Special provisions IB2, T7, TP1, TP8, TP28 Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 18-2.19 (Class 3). Explosive Limit and Limited Quantity Index 1 Passenger Carrying Road or Rail Index 5 Special provisions 16 128Emergency Response Guidebook (ERG): Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 10/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 15. Regulatory information SARA 302/304 SARA 304 RQ :Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification :Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. Australia inventory (AICS) Canada inventory ( DSL/NDSL ) China inventory (IECSC) Europe inventory (EINECS) Japan inventory (ENCS): All components are listed or exempted. Japan inventory (ISHL): Not determined. Not determined. All components are listed or exempted. Japan inventory Korea inventory (KECI) New Zealand Inventory of Chemicals (NZIoC) Philippines inventory (PICCS) All components are listed or exempted.United States inventory (TSCA 8b) All components are listed or exempted. International lists : WHMIS (Canada)Class B-2: Flammable liquid Class D-2B: Material causing other toxic effects (Toxic). : Canada State regulations Massachusetts New York New Jersey Pennsylvania : : : : None of the components are listed. The following components are listed: NONANE; PROPYL ALCOHOL; PROPANOL; ETHYL ALCOHOL; DENATURED ALCOHOL; Glycol The following components are listed: NONANE; PROPYL ALCOHOL; 1-PROPANOL; ETHYL ALCOHOL; ALCOHOL; Glycol The following components are listed: NONANE; 1-PROPANOL; DENATURED ALCOHOL; ETHANOL; Glycol California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Not applicable. Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 11/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Section 15. Regulatory information methanol No.Yes.No.23000 µg/day (ingestion) 47000 µg/day (inhalation) ethylbenzene Yes.No.41 µg/day (ingestion) 54 µg/day (inhalation) No. toluene No.Yes.No.7000 µg/day (ingestion) 4-methylpentan-2-one Yes.Yes.No.No. benzene Yes.Yes.6.4 µg/day (ingestion) 13 µg/day (inhalation) 24 µg/day (ingestion) 49 µg/day (inhalation) naphthalene Yes.No.Yes.No. acetaldehyde Yes.No.90 µg/day (inhalation)No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level TSCA 12(b) one-time export: nonane Section 16. Other information History Date of issue/Date of revision Version Prepared by Information presented herein has been compiled from information provided to us by our suppliers and other sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or the use of any product in violation of any patent or in violation of any law or regulation. It is the users' responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us. Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. 8/19/2017 6/27/2017 3 Hazardous Material Information System (U.S.A.) 2 3 0 032 National Fire Protection Association (U.S.A.) Special :Instability/Reactivity :Flammability : Health :Flammability :Physical hazards :Personal protection Code :H Health : Chem-Trend Regulatory Affairs Department. - * Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 12/13Christensen Arms AO Modification 9/7/23 Mono-Coat® E179 N-ODS Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 13/13Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT DESCRIPTION: PRODUCT CODE: MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS Pacer Technology 3281 E. Guasti Road, Suite 260 Ontario, CA 91761 Emergency Contact: Chemtrec Emergency Phone: (800) 424-9300 Customer Service: (909) 987-0550 CHEMTREC (800) 424-9300 2. HAZARDS IDENTIFICATION GHS CLASSIFICATIONS Health: Eye Irritation, Category 2A Skin Irritation, Category 2 Target Organ Toxicity (Single exposure), Category 3 Skin Sensitization, Category 1 Physical: Flammable Liquids, Category 4 GHS LABEL Note: If this product is a consumer product it is labeled in accordance with the Consumer Product Safety Commission regulations and not OSHA regulations. The requirements for the labeling of consumer products take precedence over OSHA labeling so the actual product label will not contain the OSHA label elements shown below on this SDS. Exclamation mark SIGNAL WORD: WARNING HAZARD STATEMENTS H227: Combustible liquid. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H335: May cause respiratory irritation. PRECAUTIONARY STATEMENTS Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash skin and hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. Page 1 of 7 11740026_FG04010 RX-50 ADHESIVE 20GM 11740026_FG04010 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 P280: Wear protective gloves/protective clothing/eye protection/face protection. Response: P302+P352: IF ON SKIN: Wash with plenty of soap and water. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P313: Get medical advice/attention. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P337+P313: If eye irritation persists: Get medical advice/attention. P362: Take off contaminated clothing. P370: In case of fire: Use dry chemical, foam or carbon dioxide to extinguish. Storage: P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. Disposal: P501: Dispose of in a manner consistent with federal, state, and local regulations. HAZARDS NOT OTHERWISE CLASSIFIED: Skin contact through clothing may cause burns. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.%CAS ETHYL-2-CYANOACRYLATE 85 - 100 7085-85-0 Polymethyl methacrylate 10 - 30 9011-14-7 Hydroquinone < 0.1 123-31-9 4. FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. SKIN: Wash with soap and water. Peel or roll skin apart. INGESTION: Peel or roll skin apart. Adhesive becomes solid in contact with saliva and may adhere to inside of mouth. Saliva will lift adhesive in 1-2 days. Avoid swallowing solid adhesive after detachment. Not a toxic product. INHALATION: Remove to fresh air. Prolonged or repeated elevated exposure may cause allergic reactions with asthma-like symptoms in sensitive individuals. SIGNS AND SYMPTOMS OF OVEREXPOSURE EYES: Causes serious eye irritation. Will bond eyelids. Will cause excessive tearing. SKIN: Bonds skin in seconds. May cause skin irritation. May cause sensitization by skin contact. Cyanoacrylates generate heat on polymerization, so very large amounts will burn the skin. INGESTION: Adhesive becomes solid in contact with saliva and may adhere to inside of mouth. Saliva will lift adhesive in 1-2 days. Not a toxic product. INHALATION: Prolonged or excessive inhalation may cause respiratory tract irritation. ACUTE EFFECTS: Avoid exposure to vapor concentration in confined areas. CHRONIC EFFECTS: Frequent or prolonged contact may irritate the skin and cause a skin rash (dermatitis). Page 2 of 7 11740026_FG04010 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 5. FIRE FIGHTING MEASURES GENERAL HAZARD: Combustible liquid and vapor.Product polymerized to solid by water. EXTINGUISHING MEDIA: Use dry chemical extinguisher or flush with large amounts of water. HAZARDOUS COMBUSTION PRODUCTS: Can burn in fire, releasing irritanting vapors EXPLOSION HAZARDS: None known. FIRE FIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. FIRE EXPLOSION: None known. SENSITIVE TO STATIC DISCHARGE: None known. SENSITIVITY TO IMPACT: None known. HAZARDOUS DECOMPOSITION PRODUCTS: Combustible by-products of carbon monoxide/dioxide. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Polymerize with water. Solid material may be scraped from surface. LARGE SPILL: Polymerize with water. Increase ventilation to area. Solid material may be scraped from surface. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Use with adequate ventilation. Avoid contact with eyes, skin and clothing. HANDLING: Avoid breathing (dust, vapor, mist, gas). STORAGE: Store in a cool place in original container and protect from sunlight. STORAGE TEMPERATURE: Ideal storage: 41-50F (5-10C) SHELF LIFE: One year from the date of shipment from Pacer Technology, unless otherwise noted. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS Chemical Name Type ppm mg/m3 ETHYL-2-CYANOACRYLATE OSHA PEL TWA [1][1] ACGIH TLV TWA 0.2 1.0 STEL [2]0.3 ppm [2] Supplier OEL TWA 0.2 ppm Hydroquinone OSHA PEL TWA 2 Footnotes: 1. NL = Not Listed 2. 1.5 mg/m3 ENGINEERING CONTROLS: Use only in a well ventilated area. Local exhaust ventilation may be necessary to control any air Page 3 of 7 11740026_FG04010 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 contaminants to within their TLVs during the use of this product. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. SKIN: Use Nitrile gloves and aprons to prevent contact. Do not use PVC, Nylon or Cotton materials. RESPIRATORY: Use only in a well-ventilated area. In case of insufficient ventilation, wear suitable respiratory equipment. Recommended: Full-face NIOSH-approved respirator with organic vapor cartridge. WORK HYGIENIC PRACTICES: Avoid direct contact and breathing vapor. Use with adequate ventilation. Wash hands with soap and water after use. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Characteristic odor, intensely irritating. ODOR THRESHOLD: Odor Threshold = 1 ppm APPEARANCE: pH: Not Established PERCENT VOLATILE: No data available FLASH POINT AND METHOD: 80°C (176°F) to 93.4°C (200°F) TAG CC FLAMMABLE LIMITS: Not Established AUTOIGNITION TEMPERATURE: 485°C (905°F) VAPOR PRESSURE: < 0.2 mm Hg VAPOR DENSITY: No data available BOILING POINT: > 149°C (300°F) FREEZING POINT: No data available MELTING POINT: No data available THERMAL DECOMPOSITION: Not Established SOLUBILITY IN WATER: Insoluble PARTITION COEFFICIENT: N-OCTANOL/WATER: No data available EVAPORATION RATE: No data available DENSITY: Not Established SPECIFIC GRAVITY: VISCOSITY #1: MOLECULAR WEIGHT: Not Established (VOC): < 20.00 g/L Per SCAQMD Method 316B. 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIZATION: No CONDITIONS TO AVOID: Avoid temperatures above 176° F (80° C), moisture and alkalines. Page 4 of 7 11740026_FG04010 Transparent, colorless liquid. 1.06 g/mL at 25°C 30 to 70 Centipoise at 22°C (72°F) Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 POSSIBILITY OF HAZARDOUS REACTIONS: Possible polymerization reaction in the presence of water, amines, alkalis and alcohols. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide and other toxic or irritating compounds may form when heated to decomposition.Oxides of nitrogen and probably hydrogen cyanide are also possible. INCOMPATIBLE MATERIALS: Polymerized by water, alcohol, amines, alkaline materials. COMMENTS: REACTIVITY: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols. 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY Chemical Name ORAL LD50 DERMAL LD50 ETHYL-2-CYANOACRYLATE > 5000 mg/kg > 2000 mg/kg Hydroquinone 367.3 mg/kg > 2000 mg/kg DERMAL LD50: > 2000 mg/kg Notes: (Estimated) ORAL LD50: > 5000 mg/kg Notes: (Estimated) INHALATION LC50: Vapors may be irritating. Recommended TWA 0.2ppm. RESPIRATORY OR SKIN SENSITISATION: Possible skin sensitizer. CARCINOGENICITY IARC: None NTP: None OSHA: None 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: This material should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in a manner consistent with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: AIR (ICAO/IATA) SHIPPING NAME: ID8000, CONSUMER COMMODITY, 9 (PKG LESS THAN OR EQUAL TO 30 kg G); or UN3334, AVIATION REGULATED LIQUID, N.O.S (ETHYL CYANOACRYLATE), 9, III (LTD QTY, IP VOL LESS THAN OR EQUAL TO 5.0 L, OP WGT LESS THAN OR EQUAL TO 30 kg G) * VESSEL (IMO/IMDG) Page 5 of 7 11740026_FG04010 NOT REGULATED Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 SHIPPING NAME: NOT REGULATED COMMENTS: * This product may be shipped as EXCEPTED QUANTITIES OF CLASS 9, UN3334 (IP VOL LESS THAN OR EQUAL TO 0.03 L, OP VOL LESS THAN OR EQUAL TO 1.0 L) The transport information provided in this section only applies to the material formulation/itself, and is not specific to any package/configuration.This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. It is the responsibility of the transporting organizations to follow all applicable laws, regulations, and rules relating to the transportation of the material. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HEALTH HAZARDS: Immediate Health, Delayed Health, Fire, Reactive. 313 REPORTABLE INGREDIENTS: None above reporting de minimus. 302/304 EMERGENCY PLANNING EMERGENCY PLAN: None above reporting de minimus. TSCA (TOXIC SUBSTANCE CONTROL ACT) Chemical Name CAS ETHYL-2-CYANOACRYLATE 7085-85-0 Polymethyl methacrylate 9011-14-7 Hydroquinone 123-31-9 TSCA STATUS: All components are listed on or are exempt from listing on the Toxic Substances Control Act. CLEAN AIR ACT 40 CFR PART 68---RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVENTION: Not applicable. CALIFORNIA PROPOSITION 65: Consumer sizes of this product do not require a California Proposition 65 Warning based on potential exposure in normal consumer use. The following information applies to industrial use: WARNING: This product can expose you to chemicals including Sulfur Dioxide, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. 16. OTHER INFORMATION APPROVED BY: Pacer Technology Regulatory Affairs Department PREPARED BY: Pacer Technology Regulatory Affairs Department Date Revised: 03/30/2020 REVISION SUMMARY: This SDS replaces the 08/15/2018 SDS. Revised: Section 1: APPROVED BY, PREPARED BY, PRODUCT CODE. Page 6 of 7 11740026_FG04010 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Date Issued : 10/10/2014 SDS No : Date Revised : 03/30/2020 Revision No : 16 HMIS RATING HEALTH 2 FLAMMABILITY 2 PHYSICAL HAZARD 1 PERSONAL PROTECTION NFPA CODES 2 2 1 MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, Pacer Technology does not assume any liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Page 7 of 7 11740026_FG04010 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 1 SAFETY DATA SHEET PRODUCT NAME: HP 8212 A DATE: June 1, 2018 MSDS NUMBER: HP 8212 A SUPERSEDES MSDS: June 1, 2015 SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION MANUFACTURER: Eteco, Inc. 1000 South Linwood Ave. Santa Ana, CA 92705 Phone: 714 480 1370 TRANSPORTATION EMERGENCY CALL CHEMTREC: 800 424 9300 MEDICAL EMERGENCY INFORMATION: 800 328 8501 PRODUCT IDENTIFICATION NUMBER: HP 8212 A CHEMICAL FAMILY: POLYMERIC ISOCYANATE SECTION 2: HAZARD IDENTIFICATIONS This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200) Physical State and Appearance: Brown Liquid Emergency Overview: INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. Skin: HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING. Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT). Inhalation: HAZARDOUS IN CASE OF INHALATION (LUNG IRRITANT, LUNG SENSITIZER). Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION. Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema, bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m3, the highest dose tested. This is well above the recommended TLV of 5ppb (0.05 mg/m3). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years. Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure. Christensen Arms AO Modification 9/7/23 2 Aggravated Medical Conditions: Individuals who are sensitized to isocyanates and those with preexisting lung diseases of conditions, including non-specific bronchial hyper reactivity or asthma, must avoid all exposure to isocyanates. GHS Label Elements: Hazard pictograms Signal Word: Danger Hazard statement: Harmful if inhaled. Causes skin and eye irritation. May Cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. SECTION 3: HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT CAS NUMBER % BY WEIGHT POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 100% *Occupational Exposure Limit(s) if available, are listed in section 8. SECTION 4: FIRST AID MEASURES Eyes: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the eyelids open. Get immediate medical attention. Skin Contact: Remove contaminated clothing. In case of contact, immediately wash skin with soap and plenty of water. If symptoms develop obtain medical attention. Contaminated clothing should be thoroughly cleaned. An MDI study has demonstrated that a polyglycol-based skin cleaner or corn oil may be more effective than soap and water. Inhalation: If excessive inhalation of vapor occurs, remove patient to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical attention. Ingestion: If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. Get immediate medical attention. NOTES TO PHYSICIANS: There is no specific antidote to counteract the effects of MDI. Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. Other First Aid Procedures: Medical supervision of all employees who handle or come into contact with MDI is recommended. Pre-employment and periodic medical examinations with respiratory function test (PEV, PVC, as a minimum are suggested). Persons with asthmatic conditions chronic bronchitis, other chronic respiratory diseased, recurrent eczema or pulmonary sensitization should be excluded from working with MDI. Once a person is diagnosed as having pulmonary sensitization (allergic asthma) to MDI, further exposure is not permissible. SECTION 5: FIRE FIGHTING MEASURES Flash Point: >93.3°C, Closed Cup. Autoignition: >600°C. Flammable Limits: Not available. Christensen Arms AO Modification 9/7/23 3 Products of Combustion: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN. Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks and static discharge or combustible materials. Fire Fighting Media and Instructions: Small Fire: Use DRY chemical powder. Large Fire: Use water spray, fog or foam. Do not use water jet. Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Special Remarks on Fire Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture closed containers. This reaction accelerates at higher temperatures. SECTION 6: ACCIDENTAL RELEASE MEASURES For major spills call Chemtrec (800-424-9300) Small Spill and Leak: Clean-up should only be performed by trained personnel. People dealing with major spillages should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further leakage, spillage or entry into drains. Large Spill and Leak: Contain and absorb large spillages onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spillage area with Liquid decontaminant. Test atmosphere for MDI. Neutralize small spillages with decontaminant. Remove and properly dispose of residues (see Section 13 for disposal considerations). Notify applicable government authorities if release is reportable. The CERCLA RQ for 4,4-MDI is 5000 lbs (see CERCLA in Section 15). Decontaminant: Preparation of Decontaminant Solution: Prepare a decontamination solution of 0.2-0.5% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium hydroxide). Follow the precautions on the supplier’s material safety data sheets when preparing and using solution. Use of Decontamination Solution: Allow deactivated material to stand for at least 30 minutes before shoveling into drums. Do not tighten the bungs. Mixing with wet earth is also effective, but slower. SECTION 7: HANDLING AND STORAGE Handling: Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly because of the possibility of blockage. Avoid breathing aerosols, mists and vapors. (See Section 8 Exposure Control for details.) Storage: Keep containers properly sealed and when stored indoors, in a well ventilated area. Keep contents away from moisture. Due to reaction with water, producing CO2-gas, a hazardous build-up of pressure could result if contaminated containers are re-sealed. Do not reseal contaminated containers. Uncontaminated containers, free of moisture, may be resealed only after placing under a nitrogen blanket. Do not store in containers made of cooper, cooper alloys or galvanized surfaces. Ideal storage temperature is 16-38°C (60-100°F). Keep stocks of decontaminant (see Section 6) readily available. SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION Preventive Measures: Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Christensen Arms AO Modification 9/7/23 4 Engineering Controls: Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For guidance on engineering control measures refer to publications such as the ACGIH current edition of “ Industrial Ventilation, a manual of Recommended Practice”. Personal Protection Eyes: Chemical safety goggles. If there is a potential for splashing, use a full face shield. Body and Hands: The following protective materials are recommended: Gloves-neoprene, nitrile rubber, butyl rubber. Thin latex disposable gloves should be avoided for repeated or long term use. Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical Protective Clothing” published by ACGIH. Respiratory: When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has been developed in accordance with the OSHA respiratory protection standard (29 C.F.R. 1910.134). Personal Protection in Case of a Large Spills: Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Product Name Exposure Limits 4,4-Diphenylmethane Diisocyanate ACGIH TLV 0.05 mg/m3 (8-hour, 40 hours/week) OSHA PEL Ceiling Limit 0.20 mg/m3 NIOSH REL/TWA 0.05 mg/m3 (10-hour, 40 hours/week) NIOSH REL/CEILING 0.20 mg/m3 (10-minutes) Exposure control/ personal protection: Medical supervision of all employees who handle or come in contact with respiratory sensitizers is recommended. Persons with respiratory problems including asthmatic-type conditions, chronic Bronchitis, other chronic respiratory diseases or recurrent skin eczema or skin allergies should be evaluated for their suitability of working with this product. Once a person is diagnosed as sensitized, no further exposure to the material that caused the sensitization should be permitted. The Occupational Exposure limits do not apply to previously sensitized individuals. SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES APPEARANCE AND ODOR Brown Liquid Slightly Musty BOILING POINT (°C) >300°C MELTING POINT (°F/°C) Not available SPECIFIC GRAVITY ( WATER = 1) 1.23 gr/ml BULK DENSITY 9.0 lb/gal pH Not applicable VAPOR PRESSURE (MM Hg.) 0.000004 mmHg @ 25°C VAPOR DENSITY (AIR-1) 8.5 VISCOSITY 900-1300 cps @ 25° C PERCENT (%) VOC 0% FLASH POINTS >93.3°C (230°F) Closed Cup SECTION 10: STABILITY AND REACTIVITY Stability: Stable at room temperature. Incompatibility with various Substances: Reactive with moisture. Conditions of Instability: Avoid high temperatures. Avoid freezing. Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN. Christensen Arms AO Modification 9/7/23 5 Hazardous Polymerization: Polymerization may occur at elevated temperatures in the presence of alkalies, tertiary amines and metal compounds. SECTION 11: TOXICOLOGICAL INFORMATION Toxicity to Animals: LD50 Rat Oral: >5000mg/kg LD50 Rabbit Dermal: >5000 mg/kg Inhalation: This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapor or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. Symptoms may include irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive response to even minimal concentrations of MDI may develop in sensitized persons. Skin Contact: Moderate irritant. Repeated and/or prolonged contact may cause skin sensitization. There is limited evidence from animal studies that skin contact may play a role in respiratory sensitization. These results emphasize the need for protective clothing including gloves to be worn at all times when handling these chemicals or in maintenance work. Eye Contact: The vapor, aerosol, and liquid are irritant. Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Based on the acute oral LD50 this product is considered practically non-toxic by ingestion. Remarks: Short term test have shown that it is unlikely to be genotoxic. (BUTYLATEDHYDROXYTOLUENE) Carcinogenic Effects: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA, and not listed as carcinogens by NTP. Mutagenic Effects: There is no substantial evidence of mutagenic potential. Reproductive Effects: No adverse reproductive effects are anticipated. Teratogenic Effects: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at doses that were extremely toxic (including lethal) to the mother. Fetotoxicity was not observed at doses that were not maternally toxic. The doses used in these studies were maximal respirable concentrations well in excess of the defined limits. Remark: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to atmosphere of respirable polymeric MDI aerosol at concentrations of 0, 0.2, 1 or 6 mg/m3. No adverse effects were observed at 0.2 mg/m3. At the 1mg/m3 concentration, minimal nasal and lung irritant effect were seen. Only at the top concentration (6.0 mg/m3) was there an increased incidence of a benign tumor of the lung (adenoma). One malignant pulmonary tumor (adenocarcinoma) was seen in the 6.0 mg/m3 group. MDI administration to rats in this study did not change the distribution and incidence of tumors from those seen in control animals. The increased incidence of lung tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In the absence of prolonged exposure to high concentration leading to chronic irritation and lung damage, it is highly unlikely that tumor formation will occur. There are reports that excessive chronic exposure to diisocyanates may result in permanent decrease in lung function. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Polymeric MDI. LC50 (Zebra Fish) >1000 ml/l. EC50 (Daphnia magna) (24 hours) >1000 mg/l EC50 (E. Coli) > 100ml/l. Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise based on consideration of the production and use of the substance. Persistence and Degradation: Immiscible with water, but will react with water to produce inert and non-biodegradable solids. Christensen Arms AO Modification 9/7/23 6 SECTION 13: DISPOSAL CONSIDERATIONS Waste Information: The generation of waste should be avoided or minimized wherever possible. Disposal should be in accordance with local, state, provincial or national regulations, This material is not hazardous waste under RCRA 40 CFR 261. Small quantities should be treated with a decontaminant solution (see Section 6). The treated waste is not a hazardous material under RCRA 40 CFR 261. Chemical waste, even small quantities, should never be poured down drains, sewers or waterways. Empty containers should be decontaminated and either passed to an approved drum recycler or destroyed. SECTION 14: TRANSPORT INFORMATION For major spills call Chemtrec (800-424-9300). DOT Classification: Single containers less than 5000 lbs. are not regulated. Single containers with 5000 lbs. Or more of 4,4-Methylene Diphenyl Diisocyanate are regulated as: Other Regulated Substances, Liquid, N.O.S. (Methylene Diphenyl Diisocyanate), 9, NA3082, PGlll, RQ. TDG Classification: Not regulated. IMO/IMDG Classification: Not regulated. ICAO/IATA Classification: Not regulated. SECTION 15: REGULATORY INFORMATION U.S. Federal Regulations This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200). HCS Classification: Class: Toxic Class: Irritating substance. Class: Sensitizing substance. TSCA 8(b) inventory: All Ingredients Listed EPCRA Section 313 (40 CFR 372) Diisocyanate Compounds (Category Code N120) 100% CERCLA (Comprehensive Environmental Response, Compensation and Liability Act): This product does not contain nor is it manufactured with ozone depleting substances. State Regulations: Canadian Regulations: This material has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR. WHMIS (Canada): Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). Class D-2A: Material causing other toxic effects (VERY TOXIC). Class D-2B: Material causing other toxic effects (TOXIC). CEPA: DSL/NDSL: All Ingredients Listed. Christensen Arms AO Modification 9/7/23 7 SECTION 16: OTHER INFORMATION CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN AND EYES. MAY BE HARMFULL IF INHALED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION. Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.) Health: 2 Fire Hazard: 1 Reactivity: 1 Health: 2 Fire Hazard: 1 Reactivity: While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICATION OF SUCH INFORMATION AND RECOMMENDATIONS AND SUITABILITY OF ANY PRODUCT FOR IRS OWN PARTICULAR PURPOSE. THE PRODUCT MAY PRESENT HAZARD AND SHOULD BE USED WITH CAUTION, WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT ARE THE ONLY HAZARDS THAT EXIST. Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers, processors and end users. We disclaim liability for damage or injury incurring directly or indirectly from the use of this product. APROVED AND AUTHORIZED BY: Enes Christensen Arms AO Modification 9/7/23 1 SAFETY DATA SHEET PRODUCT NAME: HP 8212 B Black DATE: June 01,2015 MSDS NUMBER: HP 8212 B SUPERSEDES MSDS: April 20, 2012 SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION MANUFACTURER: Eteco, Inc. 1000 South Linwood Ave. Santa Ana, CA 92705 Phone: 714 480 1370 TRANSPORTATION EMERGENCY CALL CHEMTREC: 800 424 9300 MEDICAL EMERGENCY INFORMATION: 800 328 8501 PRODUCTION IDENTIFICATION NUMBER: HP 8212 B Black CHEMICAL FAMILY: POLYETHER POLYOL BLEND SECTION 2: HAZARDS IDENTIFICATION This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200). Physical State: Liquid Potential Acute Heath Effects: Eyes Corrosive to eyes. Skin Corrosive to skin on contact. Skin contact may produce burns. Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking or shortness of breath. Ingestion May cause burns to mouth, throat and stomach. GENERAL INFORMATION: Read the entire MSDS for more thorough evaluation of the hazards. GHS Label Elements: Hazard pictograms SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS MATERIAL OR COMPONENT CAS NUMBER % BY WEIGHT PROPRIETARY COMPONENT Mixture 55-90 % GLYCOLS Mixture 0-10 % *Occupational Exposure Limit(s), if available, are listed in Section 8. Christensen Arms AO Modification 9/7/23 2 SECTION 4: FIRST AID MEASURES Eye Contact: Check for and remove any contact lenses. In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Skin Contact: In case of contact, immediately wash skin with soap and plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention immediately. Inhalation: If excessive inhalation of vapor occurs, remove to fresh air. If breathing is difficult, qualified personnel may administer oxygen. Get medical attention immediately. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Notes to Physician: Symptomatic treatment and supportive therapy as indicated. Administer oxygen if necessary. Following severe exposure the patient should be kept under medical review for at least 48 hours as delayed pulmonary edema may develop. SECTION 5: FIRE FIGHTING MEASURES Flash Point: >212°F Closed Cup Auto Ignition Temp: Not available. Flammable Limits: Not available. Products of Combustion: Thermal Decomposition products are toxic and may include oxides of carbon and nitrogen, amines, possibly other irritating gases. Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. SECTION 6: ACCIDENTAL RELEASE MEASURES For major spills call Chemtrec (800-424-9300) See Safety Data Sheet section 8 Personal Protective Equipment Small Spill and Leak Absorb with an inert material and put the material in an appropriate waste disposal container. Large Spill and Leak Corrosive liquid. Toxic liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements of confined area; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Christensen Arms AO Modification 9/7/23 3 SECTION 7: HANDLING AND STORAGE Handling Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Storage Keep container tightly closed. Keep container in a cool, well-ventilated area. SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Engineering Controls Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable respiratory equipment should be used in case of insufficient ventilation or where operational procedures demand it. For guidance on engineering control measures refer to publications such as the ACGIH current edition of ‘Industrial Ventilation, a manual of Recommended Practice.’ Personal Protection Eyes Chemical safety goggles. If there is a potential for splashing, use a full-face shield. Body and Hands Full chemical suit. Gloves. Respiratory Wear appropriate respirator when ventilation is inadequate. Personal Protection in case of a Large Spill Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Product Name Exposure Limits SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES APPEARANCE AND ODOR Black Slight Odor BOILING POINT (°F/°C) Not determined MELTING POINT (°F/°C) Not determined SPECIFIC GRAVITY ( WATER = 1) 1.12 kg/l BULK DENSITY 8.8 lb/gal pH OF UNDILUTED PRODUCT Not determined VAPOR PRESSURE (MM Hg.) Not determined VAPOR DENSITY (AIR-1) >1 VISCOSITY 600 to 900 cps @ 25° C PERCENT (%) VOC 0 SOLUBILITY IN WATER Soluble SECTION 10: STABILITY AND REACTIVITY Stability and Reactivity This product is stable. Conditions of Stability Avoid moisture to protect product quality. Incompatibility with Various Substances Christensen Arms AO Modification 9/7/23 4 Slightly reactive to reactive with oxidizing agents, alkalis. Hazardous Decomposition Products Thermal decomposition products are toxic and may include oxides of carbon and nitrogen, amines, possibly other irritating gases. Hazardous Polymerization Will not occur. SECTION 11: TOXICOLOGICAL INFORMATION No applicable data for this section. SECTION 12I: ECOLOGICAL INFORMATION No applicable data for this section. SECTION 13: DISPOSAL CONSIDERATIONS Waste Information Incinerate or landfill in a licensed facility. Do not discharge into waterways of sewer systems. Container Disposal: Steel drums must be emptied (as defined by RCRA, Section 261.7 or state regulations that may be more stringent) and can be sent to a licensed drum reconditoiner for reuse, a scrap metal dealer or an approve landfill. Drums destined for scrap dealer of landfill must be punctured or crushed to prevent reuse. Material for disposal should be placed in appropriated sealed containers to avoid potential human and environmental exposure. It is the responsibility of the generator to comply with all federal, state, provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal contractor and environmental agency for relevant laws and regulations. Under the US, Resource Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determined at the time of disposal, whether the product meets relevant waste classification and to assure proper disposal. SECTION 14: TRANSPORT INFORMATION Transportation Emergency Number 1-800-424-9300 (CHEMTREC). DOT Classification Non Regulated TDG Classification Non Regulated IMO/IMDG Classification Non Regulated ICAO/IATA Classification Non Regulated SECTION 15: REGULATORY INFORMATION U.S. Federal Regulations This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200). HCS Classification Class: Corrosive material TSCA 8(b) inventory: All ingredients Listed. CERCLA (Comprehensive Environmental Response, Compensation and Liability Act): Christensen Arms AO Modification 9/7/23 5 Any spill or release above the RC must be reported to the National Response Center (800-424-8802) SARA 313 toxic chemical notification and release reporting: None State Regulations California prop 65: No ingredients listed. Canadian Regulations This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR. WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2B: Material causing other toxic effects (Toxic). CEPA DSL/NDSL Not all Ingredients Listed. SECTION 16: OTHER INFORMATION Causes respiratory tract, eye and skin burns. Harmful if inhaled. May be harmful if swallowed. Contains material, which may cause birth defects based on animal data. Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.) Health: 1 Health: 1 Fire Hazard: 1 Fire Hazard: 1 Reactivity: 0 Reactivity: 0 Notice to Reader While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONSAND THE SUITABILITY OF ANY PRIDUCT FOR ITS OWN PARTICULAR PURPOSE. THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZAEDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST. Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers, processors and end users. We disclaim liability for damage or injury incurring directly or indirectly from the use of this product. APPROVED AND AUTHORIZED BY: Enes Torlic Christensen Arms AO Modification 9/7/23      !   "#$% &'(% )*+,-.                    !   " " " " #  "   ,  // 0 %1$2 "$'$ $"$(344+ $%    &   %  1$$(5$% 4,4. 4,4.   " !    ' " "#$% $ !    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N!$(       "          4,4.     !    ./01/'/, /2Christensen Arms AO Modification 9/7/23  ;     !         9:       5    5  +           )   +     %    %     %    +% 5 + 5&   5%                  5)    6      6 5  5  &     5             5              $  7   H    +%     H      - -     % +  5  55 %  +                 I  - -                - -              +   +        +                  /5                   "           4,4.     !    ./01/'/, /2Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϭŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ Safety Data Sheet Section 1: Identification Product Identifier/Name Prodraw BB Product code ඵϭϬϯϴϲ Relevant identified uses of the substance or mixture and uses advised against Recommended use ඵKŝůďĂƐĞĚŵĞƚĂůĨŽƌŵŝŶŐůƵďƌŝĐĂŶƚ Restrictions on use ඵ&ŽƌŝŶƚĞŶĚĞĚŝŶĚƵƐƚƌŝĂůƵƐĞŽŶůLJ Details of the supplier of the safety data sheet Manufacturer ඵtĂůůŽǀĞƌKŝůŽŵƉĂŶLJ ϮϭϴϰϱƌĂŬĞZŽĂĚ ^ƚƌŽŶŐƐǀŝůůĞ͕K,ϰϰϭϰϵ hŶŝƚĞĚ^ƚĂƚĞƐ ǁǁǁ͘ǁĂůůŽǀĞƌ͘ĐŽŵ Telephone (General)ඵ;ϰϰϬͿϮϯϴͲϵϮϱϬ Emergency telephone number ඵ,DdZ͗ϴϬϬͲϰϮϰͲϵϯϬϬ;ŝŶƚŚĞh͘^͘Ϳ͕;нϭͿϳϬϯͲϱϮϳͲϯϴϴϳ;ŽƵƚƐŝĚĞƚŚĞh͘^͘Ϳ Section 2: Hazard Identification Classification of the substance or mixture In accordance with 29 CFR 1910.1200 OSHA HCS 2012 EŽƚůĂƐƐŝĨŝĞĚ Label elements  Signal word ඵEŽŶĞ Hazard symbol ඵEŽŶĞ Hazard statements ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚŵĞĞƚƚŚĞĐƌŝƚĞƌŝĂĨŽƌĐůĂƐƐŝĨŝĐĂƚŝŽŶ Precautionary statements Prevention ඵEŽƚĂƉƉůŝĐĂďůĞ Response ඵEŽƚĂƉƉůŝĐĂďůĞ Storage ඵEŽƚĂƉƉůŝĐĂďůĞ Disposal ඵEŽƚĂƉƉůŝĐĂďůĞ Hazards not otherwise classified ඵEŽƚĂƉƉůŝĐĂďůĞ Other hazards ඵEŽŶĞĚĞƚĞƌŵŝŶĞĚ Section 3: Composition/Information on Ingredients Substances ඵEŽƚĂƉƉůŝĐĂďůĞ Mixtures ,ĂnjĂƌĚŽƵƐŽŵƉŽŶĞŶƚƐ Chemical Name %(Wt.) CAS # EŽŶĞ Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϮŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ Section 4: First-Aid Measures Description of first aid measures Inhalation ඵDŽǀĞǀŝĐƚŝŵƚŽĨƌĞƐŚĂŝƌŝĨĂĚǀĞƌƐĞĞĨĨĞĐƚƐĂƌĞŽďƐĞƌǀĞĚ͘ Skin ඵ/&KE^</E͗tĂƐŚƐŬŝŶǁŝƚŚƐŽĂƉĂŶĚǁĂƚĞƌ͘ZĞŵŽǀĞĐŽŶƚĂŵŝŶĂƚĞĚĐůŽƚŚŝŶŐ ĂŶĚǁĂƐŚďĞĨŽƌĞƌĞƵƐĞ͘/ĨƐŬŝŶŝƌƌŝƚĂƚŝŽŶŽĐĐƵƌƐ͗'ĞƚŵĞĚŝĐĂůĂĚǀŝĐĞͬĂƚƚĞŶƚŝŽŶ͘ Eye ඵ/&/Ez^͗ZŝŶƐĞĐĂƵƚŝŽƵƐůLJǁŝƚŚǁĂƚĞƌĨŽƌƐĞǀĞƌĂůŵŝŶƵƚĞƐ͘ZĞŵŽǀĞ ĐŽŶƚĂĐƚůĞŶƐĞƐ͕ŝĨƉƌĞƐĞŶƚĂŶĚĞĂƐLJƚŽĚŽ͘ŽŶƚŝŶƵĞƌŝŶƐŝŶŐ͘/ĨĞLJĞŝƌƌŝƚĂƚŝŽŶ ƉĞƌƐŝƐƚƐ͗'ĞƚŵĞĚŝĐĂůĂĚǀŝĐĞͬĂƚƚĞŶƚŝŽŶ͘ Ingestion ඵŽEKdŝŶĚƵĐĞǀŽŵŝƚŝŶŐ͘^ĞĞŬŵĞĚŝĐĂůĂƚƚĞŶƚŝŽŶ͘ Most important symptoms and effects Acute ඵŝƌĞĐƚĐŽŶƚĂĐƚǁŝƚŚƉƌŽĚƵĐƚĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞƐůŝŐŚƚĞLJĞŝƌƌŝƚĂƚŝŽŶ͘ Delayed ඵWƌŽůŽŶŐĞĚͬƌĞƉĞĂƚĞĚĞdžƉŽƐƵƌĞŵĂLJĐĂƵƐĞŵŝůĚƐŬŝŶŝƌƌŝƚĂƚŝŽŶŝŶƐƵƐĐĞƉƚŝďůĞŝŶĚŝǀŝĚƵĂůƐ͘ Indication of any immediate medical attention and special treatment needed Note to Physician ඵůůƚƌĞĂƚŵĞŶƚƐƐŚŽƵůĚďĞďĂƐĞĚŽŶŽďƐĞƌǀĞĚƐŝŐŶƐĂŶĚƐLJŵƉƚŽŵƐŽĨ ĚŝƐƚƌĞƐƐŝŶƚŚĞƉĂƚŝĞŶƚ͘ŽŶƐŝĚĞƌĂƚŝŽŶƐŚŽƵůĚďĞŐŝǀĞŶƚŽƚŚĞƉŽƐƐŝďŝůŝƚLJ ƚŚĂƚŽǀĞƌĞdžƉŽƐƵƌĞƚŽŵĂƚĞƌŝĂůƐŽƚŚĞƌƚŚĂŶƚŚŝƐƉƌŽĚƵĐƚŵĂLJŚĂǀĞŽĐĐƵƌƌĞĚ͘ Section 5: Fire-Fighting Measures Extinguishing media Suitable Extinguishing Media ඵZĞŐƵůĂƌĨŽĂŵ͕ĐĂƌďŽŶĚŝŽdžŝĚĞ͕ĚƌLJĐŚĞŵŝĐĂů͘ Unsuitable Extinguishing ඵǀŽŝĚƚŚĞƵƐĞŽĨƐƚƌĞĂŵŝŶŐǁĂƚĞƌ͕ĂƐƚŚŝƐŵĂLJƐƉƌĞĂĚƚŚĞĨŝƌĞ͘ Media Special hazards arising from the substance or mixture Unusual Fire and Explosion ඵEŽƵŶƵƐƵĂůŚĂnjĂƌĚŶŽƚĞĚ͘dƌĞĂƚĂƐŽŝůĨŝƌĞ͘ Hazards  Hazarous Combustion ඵ^ŵŽŬĞ͕ƐŽŽƚ͕ĨƵŵĞƐŽƌǀĂƉŽƌƐ͕ŽdžŝĚĞƐŽĨ͗ĐĂƌďŽŶĂŶĚƐƵůĨƵƌ͘ Products Special Protective Equipment ඵ^ƚƌƵĐƚƵƌĂůĨŝƌĞĨŝŐŚƚĞƌƐΖƉƌŽƚĞĐƚŝǀĞĐůŽƚŚŝŶŐǁŝůůŽŶůLJƉƌŽǀŝĚĞůŝŵŝƚĞĚ and Precautions for Firefighters ƉƌŽƚĞĐƚŝŽŶ͘tĞĂƌĐŚĞŵŝĐĂůƉƌŽƚĞĐƚŝǀĞĐůŽƚŚŝŶŐƚŚĂƚŝƐƐƉĞĐŝĨŝĐĂůůLJ ƌĞĐŽŵŵĞŶĚĞĚďLJƚŚĞŵĂŶƵĨĂĐƚƵƌĞƌ͘/ƚŵĂLJƉƌŽǀŝĚĞůŝƚƚůĞŽƌŶŽƚŚĞƌŵĂů ƉƌŽƚĞĐƚŝŽŶ͘tĞĂƌƉŽƐŝƚŝǀĞƉƌĞƐƐƵƌĞƐĞůĨͲĐŽŶƚĂŝŶĞĚďƌĞĂƚŚŝŶŐĂƉƉĂƌĂƚƵƐ ;^Ϳ͘tĂƚĞƌƐƉƌĂLJŵĂLJďĞƵƐĞĚƚŽĐŽŽůĐŽŶƚĂŝŶĞƌƐĞdžƉŽƐĞĚƚŽĨŝƌĞ͘ Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions ඵtĞĂƌĂƉƉƌŽƉƌŝĂƚĞƉƌŽƚĞĐƚŝǀĞĞƋƵŝƉŵĞŶƚŝŶĐůƵĚŝŶŐƌĞƐƉŝƌĂƚŽƌLJ ƉƌŽƚĞĐƚŝŽŶĂƐĐŽŶĚŝƚŝŽŶƐǁĂƌƌĂŶƚ͘ŽŶŽƚƚŽƵĐŚŽƌǁĂůŬƚŚƌŽƵŐŚƐƉŝůůĞĚ ŵĂƚĞƌŝĂů͘ Environmental precautions ඵǀŽŝĚƌƵŶŽĨĨƚŽǁĂƚĞƌǁĂLJƐĂŶĚƐĞǁĞƌƐ͘ Methods and material for containment and cleaning up Containment/Clean-up ඵZĞĐŽǀĞƌĨƌĞĞůŝƋƵŝĚĨŽƌƌĞĐLJĐůĞŽƌĚŝƐƉŽƐĂů͘ĚĚĂďƐŽƌďĂŶƚƚŽƐƉŝůůĂƌĞĂ͘ Measures >Z'^W/>>^͗ŝŬĞĨĂƌĂŚĞĂĚŽĨůŝƋƵŝĚƐƉŝůůĨŽƌůĂƚĞƌĚŝƐƉŽƐĂů͘ Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϯŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ  Section7: Handling and Storage Precautions for safe handling Handling ඵKďƚĂŝŶƐƉĞĐŝĂůŝŶƐƚƌƵĐƚŝŽŶƐďĞĨŽƌĞƵƐĞ͘ŽŶŽƚďƌĞĂƚŚĞŵŝƐƚŽƌǀĂƉŽƌƐ͘WƌĞŐŶĂŶƚŽƌ ďƌĞĂƐƚĨĞĞĚŝŶŐǁŽŵĞŶŵƵƐƚŶŽƚŚĂŶĚůĞƚŚŝƐƉƌŽĚƵĐƚ͘ ŽŶŽƚŵŝdžǁŝƚŚŝŶĐŽŵƉĂƚŝďůĞŵĂƚĞƌŝĂůƐ͘ŵƉƚLJĐŽŶƚĂŝŶĞƌĐŽŶƚĂŝŶƐƉƌŽĚƵĐƚƌĞƐŝĚƵĞ ǁŚŝĐŚŵĂLJĞdžŚŝďŝƚŚĂnjĂƌĚƐŽĨƉƌŽĚƵĐƚ͘ǀŽŝĚƌĞůĞĂƐĞƚŽƚŚĞĞŶǀŝƌŽŶŵĞŶƚ͘ Conditions for safe storage, including any incompatibilities Storage ඵ^ƚŽƌĞŝŶĂĚƌLJ͕ǁĞůůǀĞŶƚŝůĂƚĞĚƉůĂĐĞ͘<ĞĞƉĐŽŶƚĂŝŶĞƌƚŝŐŚƚůLJĐůŽƐĞĚǁŚĞŶŶŽƚŝŶƵƐĞ͘ <ĞĞƉĂǁĂLJĨƌŽŵŽƉĞŶĨůĂŵĞĂŶĚŝŶĐŽŵƉĂƚŝďůĞŵĂƚĞƌŝĂůƐ͘ Incompatible Materials ඵ^ƚƌŽŶŐŽdžŝĚŝnjŝŶŐĂŐĞŶƚƐ͘ General Industrial Hygiene ඵ,ĂŶĚůĞŝŶĂĐĐŽƌĚĂŶĐĞǁŝƚŚŐŽŽĚŝŶĚƵƐƚƌŝĂůŚLJŐŝĞŶĞĂŶĚƐĂĨĞƚLJƉƌĂĐƚŝĐĞ͘ Considerations tĂƐŚƚŚŽƌŽƵŐŚůLJǁŝƚŚƐŽĂƉĂŶĚǁĂƚĞƌĂĨƚĞƌŚĂŶĚůŝŶŐĂŶĚďĞĨŽƌĞĞĂƚŝŶŐ ŽƌĚƌŝŶŬŝŶŐ͘^ĂĨĞƚLJƐŚŽǁĞƌĂŶĚĞLJĞǁĂƐŚƐŚŽƵůĚďĞĂǀĂŝůĂďůĞĐůŽƐĞƚŽ ǁŽƌŬƐƚĂƚŝŽŶ͘ Environmental Exposure ඵ&ŽůůŽǁďĞƐƚƉƌĂĐƚŝĐĞĨŽƌƐŝƚĞŵĂŶĂŐĞŵĞŶƚĂŶĚĚŝƐƉŽƐĂůŽĨǁĂƐƚĞ͘ Controls ǀŽŝĚƌĞůĞĂƐĞƚŽƚŚĞĞŶǀŝƌŽŶŵĞŶƚ͘ Section 8: Exposure Controls/Personal Protection Exposure Contols PEL/TLV /ŶŐƌĞĚŝĞŶƚK^,;W>Ϳ '/,;d>sͿ KƚŚĞƌ KŝůŵŝƐƚ͕ŵŝŶĞƌĂů ϱŵŐͬDϯ ϱŵŐͬDϯ ^d>ϭϬŵŐͬDϯ Engineering ඵhƐĞĂĚĞƋƵĂƚĞŵĞĐŚĂŶŝĐĂů;ŐĞŶĞƌĂůͿǀĞŶƚŝůĂƚŝŽŶŽƌůŽĐĂůĞdžŚĂƵƐƚĂƐŶĞĞĚĞĚ Measures/Controls ƚŽĐŽŶƚƌŽůĐŽŶĐĞŶƚƌĂƚŝŽŶŽĨĂŝƌďŽƌŶĞĐŽŶƚĂŵŝŶĂŶƚƐďĞůŽǁĂƉƉůŝĐĂůĞdžƉŽƐƵƌĞ ůŝŵŝƚǀĂůƵĞƐ͘ Personal Protective Equipment Pictograms Respiratory ඵEŽƚŶĞĐĞƐƐĂƌLJƵŶĚĞƌĐŽŶĚŝƚŝŽŶƐŽĨŶŽƌŵĂůƵƐĞ͘/ŶĐĂƐĞŽĨŝŶƐƵĨĨŝĐŝĞŶƚǀĞŶƚŝůĂƚŝŽŶ͕ ǁĞĂƌƐƵŝƚĂďůĞƌĞƐƉŝƌĂƚŽLJĞƋƵŝƉŵĞŶƚŝĨĞdžƉŽƐƵƌĞůŝŵŝƚƐĂƌĞĞdžĐĞĞĚĞĚ͘ Eye/Face ඵtĞĂƌƐĂĨĞƚLJŐůĂƐƐĞƐŽƌŐŽŐŐůĞƐ͘ Hands ඵtĞĂƌƉƌŽƚĞĐƚŝǀĞŐůŽǀĞƐͲŶĞŽƉƌĞŶĞ͕ďƵƚLJůŽƌŶŝƚƌŝůĞƌƵďďĞƌǁŝƚŚĐƵĨĨƐ͘ Skin/Body ඵtŚĞƌĞĞdžƚĞŶƐŝǀĞĚĞƌŵĂůĞdžƉŽƐƵƌĞŵĂLJďĞĞdžƉĞĐƚĞĚ͕ĞŝƚŚĞƌĂĐŚĞŵŝĐĂů ƐƵŝƚŽƌĐŚĞŵŝĐĂůĂƉƌŽŶǁŝůůďĞŶĞĞĚĞĚ͘ Section 9: Physical and Chemical Properties Information on physical and chemical properties Appearance KƉĂƋƵĞƚĂŶƉĂƐƚĞ Odor >ŽǁŽĚŽƌ Odor Threshold EŽƚĚĞƚĞƌŵŝŶĞĚ Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϰŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ pH EŽƚĂƉƉůŝĐĂďůĞ Melting Point/Freezing Point EŽƚĚĞƚĞƌŵŝŶĞĚ Boiling Point EŽƚĚĞƚĞƌŵŝŶĞĚ Flash Point ϯϯϴ϶&dLJƉŝĐĂů͕K Evaporation Rate Eŝů Flammability (solid, gas)EŽƚĂƉƉůŝĐĂďůĞ Flammability Limits EŽƚĚĞƚĞƌŵŝŶĞĚ Vapor Pressure Eŝů Vapor Density (Air=1)хϭ Specific Gravity/Relative ϭ͘ϭϱ Solubilities ^ŽůƵďůĞŝŶŵŽƐƚƉĞƚƌŽůĞƵŵƉƌŽĚƵĐƚƐ͘/ŶƐŽůƵďůĞŝŶǁĂƚĞƌ͘ Octanol/Water Partition coefficient EŽƚĚĞƚĞƌŵŝŶĞĚ Autoignition temperature EŽƚĚĞƚĞƌŵŝŶĞĚ Decomposition temperature EŽƚĚĞƚĞƌŵŝŶĞĚ Viscosity хϮϱĐ^ƚΛϰϬ϶ Section 10: Stability and Reactivity Reactivity ඵEŽĚĂŶŐĞƌŽƵƐƌĞĂĐƚŝŽŶŬŶŽǁŶƵŶĚĞƌĐŽŶĚŝƚŝŽŶƐŽĨŶŽƌŵĂůƵƐĞ͘ Chemical stability ඵ^ƚĂďůĞƵŶĚĞƌŶŽƌŵĂůƚĞŵƉĞƌĂƚƵƌĞƐĂŶĚƉƌĞƐƐƵƌĞƐ͘ Possibility of hazardous reaction ඵEŽƚĚĞƚĞƌŵŝŶĞĚ Conditions to avoid ඵEŽƚĚĞƚĞƌŵŝŶĞĚ Incompatible materials ඵŽŶŽƚŵŝdžǁŝƚŚƐƚƌŽŶŐŽdžŝĚĂŶƚƐ͘ Hazardous decomposition ඵEŽŶĞŬŶŽǁŶƵŶĚĞƌŶŽƌŵĂůƵƐĞ͘ products. Section 11: Toxicological Information Information on the likely routes of exposure; symptoms; and acute, delayed and chronic effects Inhalation ඵKǀĞƌĞdžƉŽƐƵƌĞƚŽŵŝƐƚƐŽƌǀĂƉŽƌƐŵĂLJŝƌƌŝƚĂƚĞƌĞƐƉŝƌĂƚŽƌLJƚƌĂĐƚ͘ Ingestion ඵ/ŶŐĞƐƚŝŽŶŽĨĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞŐĂƐƚƌŽŝŶƚĞƐƚŝŶĂůŝƌƌŝƚĂƚŝŽŶ͘ Eye ඵŝƌĞĐƚĐŽŶƚĂĐƚǁŝƚŚĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞŵŝůĚĞLJĞŝƌƌŝƚĂƚŝŽŶ ďĂƐĞĚŽŶĐŽŵƉŽŶĞŶƚŝŶĨŽƌŵĂƚŝŽŶ͘ Skin corrosion/irritation ඵWƌŽůŽŶŐĞĚͬƌĞƉĞĂƚĞĚĞdžƉŽƐƵƌĞƚŽĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞŵŝůĚƐŬŝŶŝƌƌŝƚĂƚŝŽŶ ŝŶƐŽŵĞŝŶĚŝǀŝĚƵĂůƐ͘ Numerical measures of toxicity Acute toxicity EŽƚůĂƐƐŝĨŝĞĚ Skin corrosion/irritation EŽƚůĂƐƐŝĨŝĞĚ Serious eye damage/irritation EŽƚůĂƐƐŝĨŝĞĚ Respiratory or skin sensitization EŽƚůĂƐƐŝĨŝĞĚ Germ cell mutagenicity EŽƚůĂƐƐŝĨŝĞĚ Carcinogenicity EŽƚůĂƐƐŝĨŝĞĚ Reproductive toxicity EŽƚůĂƐƐŝĨŝĞĚ STOT-single exposure EŽƚůĂƐƐŝĨŝĞĚ STOT-repeated exposure EŽƚůĂƐƐŝĨŝĞĚ Aspiration hazard EŽƚůĂƐƐŝĨŝĞĚ Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϱŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ Carcinogenicity ඵEŽƚůŝƐƚĞĚŝŶEdW͕K^,͕Žƌ/ZŵŽŶŽŐƌĂƉŚƐ͘ Additional Information ඵWƌĂĐƚŝĐĂůĞdžƉĞƌŝĞŶĐĞŚĂƐŶŽƚĚĞŵŽŶƐƚƌĂƚĞĚĂŶLJĂĚǀĞƌƐĞĞĨĨĞĐƚƐǁŝƚŚŶŽƌŵĂůƵƐĞ ŽĨƚŚŝƐƉƌŽĚƵĐƚ͘ ඵŽŶƚĂŝŶƐƉĞƚƌŽůĞƵŵŽŝů͕ǁŚŝĐŚŝĨŵŝƐƚĞĚŝŶĞdžĐĞƐƐĂƚĞdžƉŽƐƵƌĞůŝŵŝƚƐŵĂLJĐĂƵƐĞ ƌĞƐƉŝƌĂƚŽƌLJŝƌƌŝƚĂƚŝŽŶ͕ĐŽƵŐŚŝŶŐ͕ĂŶĚĞdžƚƌĞŵĞŽǀĞƌĞdžƉŽƐƵƌĞŵĂLJĐĂƵƐĞŽŝůƉŶĞƵŵŽŶŝƚŝƐ͘ Section 12: Ecological Information Toxicity ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘ Persistence and degradability ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘ Bioaccumulative potential ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘ Mobility in Soil ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘ Other adverse effects ඵKŝůƐƉŝůůƐĂƌĞŐĞŶĞƌĂůůLJŚĂnjĂƌĚŽƵƐƚŽƚŚĞĞŶǀŝƌŽŶŵĞŶƚ͘ Section 13: Disposal Considerations Waste treatment methods Product waste ඵŽŶŽƚĚŝƐĐĂƌĚŝŶƚŽĂŶLJƐĞǁĞƌƐ͕ŽŶƚŚĞŐƌŽƵŶĚ͕ŽƌĂŶLJďŽĚLJŽĨǁĂƚĞƌ͘ ඵŝƐƉŽƐĞŽĨƐƵƌƉůƵƐĂŶĚŶŽŶͲƌĞĐLJĐůĂďůĞƉƌŽĚƵĐƚƐǀŝĂĂůŝĐĞŶƐĞĚǁĂƐƚĞĚŝƐƉŽƐĂů ĐŽŶƚƌĂĐƚŽƌ͘ ඵdŚŝƐƉƌŽĚƵĐƚ͕ĂƐŵĂŶƵĨĂĐƚƵƌĞĚŝŶŝƚƐƉƌĞƐĞŶƚƐƚĂƚĞ͕ŝƐŶŽƚĐŽŶƐŝĚĞƌĞĚƚŽďĞĂ ŚĂnjĂƌĚŽƵƐǁĂƐƚĞĂĐĐŽƌĚŝŶŐƚŽϰϬ&ZϮϲϭ͘ϰ;ďͿ;ϰͿ͘hŶĚĞƌZZ͕ŝƚŝƐƚŚĞƌĞƐƉŽŶƐŝďŝůŝƚLJŽĨ ƚŚĞƵƐĞƌŽĨƚŚĞƉƌŽĚƵĐƚƚŽĚĞƚĞƌŵŝŶĞ͕ĂƚƚŚĞƚŝŵĞŽĨĚŝƐƉŽƐĂů͕ǁŚĞƚŚĞƌƚŚĞƉƌŽĚƵĐƚ ŵĞĞƚƐZZĐƌŝƚĞƌŝĂĨŽƌŚĂnjĂƌĚŽƵƐǁĂƐƚĞ͘dŚŝƐƉƌŽĚƵĐƚƐŚŽƵůĚďĞƌĞĐLJĐůĞĚŝĨƉŽƐƐŝďůĞ͕ ŽƚŚĞƌǁŝƐĞŝƚƐŚŽƵůĚďĞĚŝƐƉŽƐĞĚŽĨŝŶĂĐĐŽƌĚĂŶĐĞǁŝƚŚĂůůĂƉƉůŝĐĂďůĞĨĞĚĞƌĂů͕ƐƚĂƚĞ͕ ĂŶĚůŽĐĂůƌĞŐƵůĂƚŝŽŶƐ͘ Contaminated containers ඵŽŶƚĂŵŝŶĂƚĞĚĐŽŶƚĂŝŶĞƌƐƐŚŽƵůĚďĞŽĨĨĞƌĞĚĨŽƌƉƌŽĨĞƐƐŝŽŶĂůĐůĞĂŶŝŶŐďĞĨŽƌĞƌĞƵƐĞ͘ or packaging ඵŝƐƉŽƐĞŽĨƐƉĞŶƚĐŽŶƚĂŝŶĞƌŝŶĂĐĐŽƌĚĂŶĐĞǁŝƚŚůŽĐĂů͕ƌĞŐŝŽŶĂů͕ŶĂƚŝŽŶĂů͕ĂŶĚͬŽƌ ŝŶƚĞƌŶĂƚŝŽŶĂůƌĞŐƵůĂƚŝŽŶƐ͘ Section 14: Transport Information UN Number ඵEŽƚƌĞŐƵůĂƚĞĚĨŽƌƚƌĂŶƐƉŽƌƚ UN Proper Shipping Name ඵEŽƚĂƉƉůŝĐĂďůĞ Transport Hazard Class(es)ඵEŽƚĂƉƉůŝĐĂďůĞ Packing Group ඵEŽƚĂƉƉůŝĐĂďůĞ Environmental Hazards ඵEŽƚĚĞƚĞƌŵŝŶĞĚ Transport in Bulk ඵEŽƚƌĞŐƵůĂƚĞĚ Special Precautions for user ඵEŽŶĞƐƉĞĐŝĨŝĞĚ U.S. DOT ඵEŽƚƌĞŐƵůĂƚĞĚ Section 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϲŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ Global Chemical Inventories USA ůůĐŽŵƉŽŶĞŶƚƐŽĨƚŚŝƐŵĂƚĞƌŝĂůĂƌĞŽŶƚŚĞh^d^/ŶǀĞŶƚŽƌLJŽƌ ĂƌĞĞdžĞŵƉƚ͘ Other TSCA Reg.EŽƚĚĞƚĞƌŵŝŶĞĚ͘ Austrailia EŽƚĚĞƚĞƌŵŝŶĞĚ͘ Canada EŽƚĚĞƚĞƌŵŝŶĞĚ͘ China EŽƚĚĞƚĞƌŵŝŶĞĚ͘ EU EŽƚĚĞƚĞƌŵŝŶĞĚ͘ Japan EŽƚĚĞƚĞƌŵŝŶĞĚ͘ Korea EŽƚĚĞƚĞƌŵŝŶĞĚ͘ New Zealand EŽƚĚĞƚĞƌŵŝŶĞĚ͘ Switzerland EŽƚĚĞƚĞƌŵŝŶĞĚ͘ Other U.S. Federal Regulations SARA Ext. Haz. Subst.ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚĐŽŶƚĂŝŶŐƌĞĂƚĞƌƚŚĂŶϭ͘ϬйŽĨĂŶLJĐŚĞŵŝĐĂůƐƵďƐƚĂŶĐĞ ŽŶƚŚĞ^ZdžƚƌĞŵĞůLJ,ĂnjĂƌĚŽƵƐ^ƵďƐƚĂŶĐĞƐůŝƐƚ͘ SARA Section 313 ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚĐŽŶƚĂŝŶŐƌĞĂƚĞƌƚŚĂŶϭ͘Ϭй;хϬ͘ϭйĨŽƌĐĂƌĐŝŶŽŐĞŶŝĐ ƐƵďƐƚĂŶĐĞͿŽĨĂŶLJĐŚĞŵŝĐĂůƐƵďƐƚĂŶĐĞƐůŝƐƚĞĚƵŶĚĞƌ^Z^ĞĐƚŝŽŶϯϭϯ͘ EPCRA 311/312 Hazard Categories EŽƚůĂƐƐŝĨŝĞĚ CERCLA Hazardous ඵEŽŶĞŬŶŽǁŶ Substances FDA Approval ඵEŽƚĂƉƉůŝĐĂďůĞ State Regulations California Propositon 65 ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚĐŽŶƚĂŝŶĂŶLJWƌŽƉŽƐŝƚŝŽŶϲϱĐŚĞŵŝĐĂůƐ͘ Section 16: Other Information HMIS Ratings ,ĞĂůƚŚ ϭ &ůĂŵŵĂďŝůŝƚLJ ϭ ZĞĂĐƚŝǀŝƚLJ Ϭ WĞƌƐŽŶĂůWƌŽƚĞĐƚŝŽŶ  NFPA Ratings ,ĞĂůƚŚ ϭ &ůĂŵŵĂďŝůŝƚLJ ϭ ZĞĂĐƚŝǀŝƚLJ Ϭ Acronyms/Abbreviations ඵ NTPͲEĂƚŝŽŶĂůdŽdžŝĐŽůŽŐLJWƌŽŐƌĂŵZĞƉŽƌƚŽŶĂƌĐŝŶŽŐĞŶƐ;ůĂƚĞƐƚĞĚŝƚŝŽŶͿ ඵIARCͲ/ŶƚĞƌŶĂƚŝŽŶĂůŐĞŶĐLJĨŽƌƚŚĞZĞƐĞĂƌĐŚŽŶĂŶĐĞƌ ඵTSCAͲdŽdžŝĐ^ƵďƐƚĂŶĐĞŽŶƚƌŽůĐƚ ZĞǀŝƐŝŽŶĂƚĞ͗ ϵͬϳͬϮϬϭϴ ZĞƉůĂĐĞƐ͗ ϲͬϭͬϮϬϭϱ As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability Christensen Arms AO Modification 9/7/23 WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϳŽĨϳ &ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ K^,,^ϮϬϭϮ for any use of this product. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local regulations remains the responsibility of the user. Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Last Revised: 01JUN15 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ............................................. PRO-SET® LAM-224 Hardener APPLICABLE PRODUCT CODES: ................... LAM-224, LAM-224-1, LAM-224-2, LAM-224-3, LAM-224-4, LAM-224-5 CHEMICAL FAMILY: ......................................... Polyamine mixture. INTENDED PRODUCT USES: ........................... Curing agent for epoxy resins. PRODUCT RESTRICTIONS: ............................. None identified. SDS VERSION: ................................................. LAM-224 -2015a MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS): Gougeon Brothers, Inc. Transportation 100 Patterson Ave. CHEMTREC: .................... 800-424-9300 (U.S.) Bay City, MI 48706, U.S.A. 703-527-3887 (International) Phone: 888-377-6738 or 989-684-7286 Non-transportation www.prosetepoxy.com Poison Hotline: ................. 800-222-1222 2. HAZARDS IDENTIFICATION Classification of Substance or Mixture Acute toxicity, Dermal, Category 4 Acute toxicity, Inhalation, Category 4 Skin corrosion/irritation, Category 1B Skin sensitizer, Category 1 Eye damage/irritation, Category 1 Reproductive toxicity, Category 2 Acute aquatic toxicity, Category 1 Chronic aquatic toxicity, Category 1 Label Elements Hazard Pictogram(s): Signal Word: DANGER Hazard Statements: H312 Harmful in contact with skin H332 Harmful if inhaled H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H361 Suspected of damaging fertility or the unborn child H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects Precautionary Statements: Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood P260 Do not breathe dust/fume/gas/mist/vapors/spray P264 Wash hands thoroughly after handling P272 Contaminated work clothing should not be allowed out of the workplace P273 Avoid release to the environment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or shower). P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical attention or advice P310 Immediately call a POISON CENTER or doctor P313 + P333 If irritation or rash occurs: Get medical attention/advice P362 + P364 Take of contaminated clothing and wash it before reuse Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-224 Hardener Page 2 of 6 Last Revised: 01JUN15 P391 Collect spillage Storage P405 Store locked up. Disposal P501 Dispose of contents and container according to local, state, national and International regulations Other Hazards None known. 3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS INGREDIENT NAME CAS # CONCENTRATION (%) Aminoethylepiperazine 140-31-8 10-30 Benzene-1,3-dimethanamine 1477-55-0 10-25 Paratertiarybutylphenol 98-54-4 10-20 Trimethylhexamethylenediamine 25620-58-0 10-20 Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 10-20 N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 1-10 4-Nonylphenol, branched 84852-15-3 0.1-2 The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as a trade secret. 4. FIRST AID MEASURES FIRST AID FOR EYES ........................................................................ SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER or doctor. FIRST AID FOR SKIN ......................................................................... SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or doctor. FIRST AID FOR INHALATION............................................................ SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough. RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately consult with a physician if symptoms develop and persist. FIRST AID FOR INGESTION .............................................................. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway clear. Immediately call POISON CONTROL CENTER or doctor. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: .................................................................. SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE: Direct water stream. FIRE AND EXPLOSION HAZARDS: .................................................. During a fire, smoke may contain the original materials in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, cyanides, aldehydes, nitrosamines. When mixed with sawdust, wood chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it can ignite the sawdust. SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Use full-body protective gear and a self-contained breathing apparatus. Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ....... Keep unnecessary and unprotected personnel from entering area. Use appropriate safety and personal protective equipment as indicated in Section 8. MITIGATION AND CLEAN UP PROCEDURES: ................................. Stop leak without additional risk. Isolate area. Dike and absorb with inert material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual. ENVIRONMENTAL PRECAUTIONS:.................................................. Prevent from entering into soil, ditches, sewers, waterways and groundwater. See Section 12 for environmental impact information. Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-224 Hardener Page 3 of 6 Last Revised: 01JUN15 7. HANDLING AND STORAGE STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 90°F (32°C). STORAGE: ......................................................................................... Store in cool, dry place away from high temperatures and moisture. Keep container tightly closed. Store in a secure location with restricted access or store locked up. HANDLING PRECAUTIONS: ............................................................. Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to undergo thermal decomposition damage or ignite surrounding materials. Fumes and vapors released as a result of thermal decomposition can vary widely in composition and toxicity. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION GUIDELINES: ..................................................... Chemical splash-proof goggles or face shield. SKIN PROTECTION GUIDELINES: .................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene, butyl rubber or natural rubber) and full body-covering clothing. RESPIRATORY/VENTILATION GUIDELINES: ................................... Use with adequate general ventilation and/or local ventilation to keep exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other applicable respiratory protection standard. ADDITIONAL PROTECTIVE MEASURES: ......................................... Use where there is immediate access to safety shower and emergency eye wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions. OCCUPATIONAL EXPOSURE LIMITS: ............................................. Exposure limits may not be established for this product as a whole. For established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below. Ingredient Name CAS# Exposure Limit Information Aminoethylepiperazine 140-31-8 No data available Benzene-1,3-dimethanamine 1477-55-0 0.1 mg/m3 SKIN, Ceiling NIOSH; OSHA Z1A Remarks: potential for skin absorption Paratertiarybutylphenol 98-54-4 No data available Trimethylhexamethylenediamine 25620-58-0 No data available Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 No data available N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 No data available 4-Nonylphenol, branched 84852-15-3 No data available 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: ............................................................................. Liquid. COLOR: ............................................................................................. Colorless ODOR: ................................................................................................ Ammonia-like ODOR THRESHOLD: ......................................................................... No data available pH ....................................................................................................... 11.4 MELTING POINT / FREEZING POINT ................................................ No data. BOILING POINT (760mm/Hg): ........................................................... > 400°F (204°C) estimated based on similar product. FLASH POINT: ................................................................................... Estimated > 200ᵒF (93°C) estimated based similar product. AUTO IGNITION TEMPERATURE ...................................................... No data. LOWER EXPLOSIVE LIMIT (LEL) ...................................................... No data. UPPER EXPLOSIVE LIMIT (UEL) ...................................................... No data. VAPOR PRESSURE ........................................................................... < 1 mmHg @ 20°C (estimated based on ingredient data). SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.00 BULK DENSITY.................................................................................. 8.34 lbs./gal. (1.00 kg/L) VAPOR DENSITY (air = 1) ................................................................. No data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data. WATER SOLUBILITY (% BY WT.) ..................................................... No data. PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data. KINEMATIC VISCOSITY: ................................................................... 75 (mm2/s @ 20ᵒC) DECOMPOSITION TEMPERATURE: ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below. VOC Content Resin/Hardener (g/L) (lb/gal) LAM-125 / LAM-224 .................................................................... 3.60 0.03 LAM-135 / LAM-224 .................................................................... 1.66 0.01 Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-224 Hardener Page 4 of 6 Last Revised: 01JUN15 LAM-145 / LAM-224 .................................................................... 1.13 0.01 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure. INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to thermal decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, cyanides, nitrosamines, phenolics. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Aminoethylepiperazine 140-31-8 2097 mg/kg 866 mg/kg No data Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h mist / aerosol Paratertiarybutylphenol 98-54-4 > 2000 mg/kg No data. Intraperitoneal – mouse – 78 mg/kg. 5.6 mg/l; Remarks: Nutritional and Metabolic: Weight loss or decreased weight gain Trimethylhexamethylenediamine 25620-58-0 910 mg/kg No data No data Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 No data No data No data N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 1200 mg/kg 190-210 mg/kg No data 4-Nonylphenol, branched 84852-15-3 1412 mg/kg No data No data ACUTE TOXICITY: ............................................................................. No specific toxicity data exists for this mixture. Classification is based on acute toxicity estimation methods using ingredient data. Oral: ................................................................................... Not classified. Does not meet classification criteria. Dermal: .............................................................................. Category 4. Harmful in contact with skin. Significant exposure can result in absorption causing headache and nausea. Inhalation:........................................................................... Category 4. Harmful if inhaled. Repeated or prolonged exposures to mist or aerosol, or concentrated vapors may cause cough, shortness of breath, lung irritation and lung damage. SKIN CORROSION / IRRITATION: ..................................................... Category 1B. Causes severe skin burns. Effects may be immediate. May cause persistent irritation or dermatitis. SERIOUS EYE DAMAGE / IRRITATION:............................................ Category 1. Causes serious eye damage. May cause blurred vision. May cause corneal damage resulting in vision impairment or even blindness. RESPIRATORY SENSITIZATION: ...................................................... No data available. SKIN SENSITIZATION:....................................................................... Category 1. May cause allergic skin reaction. REPRODUCTIVE TOXICITY: .............................................................. Category 2. Suspected of damaging fertility or the unborn child. Rat studies involving nonylphenol indicate physical effects on newborns with reduced weight gain. MUTAGENICITY: ................................................................................ Not classified. Does not meet classification criteria. CARCINOGENICITY: .......................................................................... Not classified. Does not meet classification criteria. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet classification criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet classification criteria. ASPIRATION HAZARD: ..................................................................... Not classified. Does not meet classification criteria. OTHER HEALTH HAZARD INFORMATON: ....................................... OTHER HEALTH HAZARD INFORMATON: Repeated dose toxicity studies to nonylphenol, rat, male and female: NOAEL – 10 mg/kg. LOAEL – 50 mg/kg. 12. ECOLOGICAL INFORMATION Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-224 Hardener Page 5 of 6 Last Revised: 01JUN15 ACUTE AQUATIC TOXICITY:............................................................. No specific test data available for the mixture. Calculated Estimate: Aquatic Acute Category 1. Very toxic to aquatic life. Avoid release to the environment. CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 1. Very toxic to aquatic life with long lasting effects. Avoid release to the environment. PERSISTANCE AND BIODEGRADABILITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION: ................................... In the liquid, uncured state, this product may be harmful to aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Aminoethylepiperazine 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3 Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3 Paratertiarybutylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2 Trimethylhexamethylenediamine 25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3 Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1 N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 Not classified 4-Nonylphenol, branched 84852-15-3 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... No CANADA TDG UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... No IMDG UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II EmS Number: .................................................................................... F-A, S-B MARINE POLLUTANT ........................................................................ Yes ICAO/IATA UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... Yes 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-224 Hardener Page 6 of 6 Last Revised: 01JUN15 Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS All ingredients are listed or otherwise compliant. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. US EPA TSCA Requirements: This product may be subject to TSCA Section 12(b) SNUR requirements. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ...................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Immediate, Delayed. Subject to Section 313 ................................................................ 4-Nonylphenol, branched, CAS# 84852-15-3 US STATE REGULATORY INFORMATION: The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE 4-Nonylphenol, branched 84852-15-3 PA, NJ Paratertiarybutylphenol 98-54-4 PA, NJ Benzene-1,3-dimethanamine 1477-55-0 MA, PA, NJ Aminoethylepiperazine 140-31-8 MA, PA, NJ N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 PA, NJ 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Compliant to the requirements of the US OSHA 1910.1200 HazCom 2012 standard. PREPARED BY: ................................................................................. G. M. House APPROVED BY: ................................................................................. G. M. House SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ June 1, 2015 SUPERSEDES DATE: ........................................................................ October 25, 2012 SDS VERSION: .................................................................................. LAM-224-2015a OTHER HAZARD INFORMATION AND RATING SYSTEMS: HMIS® RATING NFPA® 704 CODES HEALTH: 3 FLAMMABILITY: 1 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 3 0 1 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Last Revised: 01JUN15 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ............................................. PRO-SET® LAM-145 Resin APPLICABLE PRODUCT CODES: ................... LAM-145, LAM-145-1, LAM-145-2, LAM-145-3, LAM-145-4, LAM-145-5, LAM-145-6 CHEMICAL FAMILY: ......................................... Epoxy resin mixture. INTENDED PRODUCT USES: ........................... Laminating resin for composites. PRODUCT RESTRICTIONS: ............................. None identified. SDS VERSION: ................................................. LAM-145 -2015a MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS): Gougeon Brothers, Inc. Transportation 100 Patterson Ave. CHEMTREC: .................... 800-424-9300 (U.S.) Bay City, MI 48706, U.S.A. 703-527-3887 (International) Phone: 888-377-6738 or 989-684-7286 Non-transportation www.prosetepoxy.com Poison Hotline: ................. 800-222-1222 2. HAZARDS IDENTIFICATION Classification of Substance or Mixture Skin corrosion/irritation, Category 2 Skin sensitizer, Category 1 Eye damage/irritation, Category 2A Chronic aquatic toxicity, Category 2 Label Elements Hazard Pictogram(s): Signal Word: WARNING Hazard Statements: H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects Precautionary Statements: Prevention P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P 280 Wear protective gloves/protective clothing/eye protection/face protection. Response P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical attention/advice. P337 + P313 If eye irritation persists: Get medical attention/advice. P362 + P364 Take off contaminated clothing and wash it before re-use. P391 Collect spillage. Disposal P501 Dispose of contents/container in accordance with local, regional and international regulations. Other Hazards None known. 3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS INGREDIENT NAME CAS # CONCENTRATION (%) Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 70-100 Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-145 Resin Page 2 of 6 Last Revised: 01JUN15 Trimethylpropanetriglycidylether 30499-70-8 10-30 The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as a trade secret. 4. FIRST AID MEASURES FIRST AID FOR EYES ........................................................................ SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure. FIRST AID FOR SKIN ......................................................................... SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and water. Consult a physician if effects occur. FIRST AID FOR INHALATION............................................................ SYMPTOMS: Not a likely route of exposure under normal conditions of use. RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing. FIRST AID FOR INGESTION .............................................................. SYMPTOMS: No acute adverse health effects expected from amounts ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: .................................................................. SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE: Direct water stream. FIRE AND EXPLOSION HAZARDS: .................................................. During a fire, smoke may contain the original materials in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: phenolics, carbon monoxide, and carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Wear a self-contained breathing apparatus and complete full-body personal protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ....... Keep unnecessary and unprotected personnel from entering area. Use appropriate safety and personal protective equipment as indicated in Section 8. MITIGATION AND CLEAN UP PROCEDURES: ................................. Stop leak without additional risk. Isolate area. Dike and absorb with inert material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual. ENVIRONMENTAL PRECAUTIONS:.................................................. Prevent from entering into soil, ditches, sewers, waterways and groundwater. See Section 12 for environmental impact information. 7. HANDLING AND STORAGE STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 120°F (49°C) STORAGE: ......................................................................................... Store in cool, dry place. Store in tightly sealed containers to prevent moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin. HANDLING PRECAUTIONS: ............................................................. Avoid all skin and eye contact. Wash thoroughly after handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION GUIDELINES: ..................................................... Safety glasses with side shields or chemical splash goggles. SKIN PROTECTION GUIDELINES: .................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene, butyl rubber or natural rubber) and full body-covering clothing. RESPIRATORY/VENTILATION GUIDELINES: ................................... Use with adequate general ventilation and/or local ventilation to keep exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other applicable respiratory protection standard. ADDITIONAL PROTECTIVE MEASURES: ......................................... Practice good caution and personal cleanliness to avoid skin and eye contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions. Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-145 Resin Page 3 of 6 Last Revised: 01JUN15 OCCUPATIONAL EXPOSURE LIMITS: ............................................. Exposure limits may not be established for this product as a whole. For established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below. Ingredient Name CAS# Exposure Limit Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 No data available. Trimethylpropanetriglycidylether 30499-70-8 No data available. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: ............................................................................. Viscous liquid. COLOR: ............................................................................................. Colorless. ODOR: ................................................................................................ Mild. ODOR THRESHOLD: ......................................................................... No data available pH ....................................................................................................... No data available MELTING POINT / FREEZING POINT ................................................ No data available BOILING POINT (760mm/Hg): ........................................................... > 400°F (204°C) FLASH POINT: ................................................................................... >200°F (93ᵒC) Based on ASTM D92 test results from similar product. AUTO IGNITION TEMPERATURE ...................................................... No data available LOWER EXPLOSIVE LIMIT (LEL) ...................................................... No data available UPPER EXPLOSIVE LIMIT (UEL) ...................................................... No data available VAPOR PRESSURE ........................................................................... No data available SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.17 BULK DENSITY.................................................................................. 9.75 lbs./gal. (1.17 kg/L) VAPOR DENSITY (air = 1) ................................................................. Heavier than air. Estimated based on ingredient data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available WATER SOLUBILITY (% BY WT.) ..................................................... No data available PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available KINEMATIC VISCOSITY: ................................................................... 8547 mm2/s @ 20ᵒC DECOMPOSITION TEMPERATURE: ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system. 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause polymerization. INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition. 11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 >15,000 mg/kg (rat) >23,000 mg/kg (rabbit) No data Trimethylpropanetriglycidylether 30499-70-8 >2,000 mg/kg >2,000 mg/kg No data ACUTE TOXICITY: ............................................................................. No specific toxicity data exists for this mixture. Classification is based on acute toxicity estimation methods using ingredient data. Oral: ................................................................................... Not classified. Does not meet acute oral toxicity criteria. Dermal: .............................................................................. Not classified. Does not meet acute dermal toxicity criteria. Inhalation:........................................................................... Not classified. Does not meet acute inhalation toxicity criteria. If product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations. SKIN CORROSION / IRRITATION: ..................................................... Causes skin irritation – Category 2. SERIOUS EYE DAMAGE / IRRITATION:............................................ Causes eye irritation. Category 2B. RESPIRATORY SENSITIZATION: ...................................................... Not classified. Does not meet criteria for respiratory sensitizer. Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of developing allergy symptoms to this product. Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-145 Resin Page 4 of 6 Last Revised: 01JUN15 SKIN SENSITZIATION:....................................................................... May cause allergic skin reaction. Category 1. REPRODUCTIVE TOXICITY: .............................................................. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally. MUTAGENICITY: ................................................................................ Not classified. Does not meet criteria for germ cell mutagenicity. Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in others. CARCINOGENICITY: .......................................................................... Not classified. Does not meet criteria for carcinogenicity. Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen. Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence – inadequate; animal evidence – sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD: ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION: ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY:............................................................. No specific test data available for the mixture. Calculated Estimate: Not classified. Does not meet acute aquatic classification criteria. CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 2. PERSISTANCE AND BIODEGRADABILITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION: ................................... In the liquid, uncured state, this product may be harmful to aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2 Trimethylpropanetriglycidylether 30499-70-8 Aquatic Chronic Cat. 3 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-145 Resin Page 5 of 6 Last Revised: 01JUN15 TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. IMDG UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes ICAO/IATA UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS All ingredients are listed or otherwise compliant. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. New Zealand NZIoC Not determined (CAS# 30499-70-8). US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Immediate. Subject to Section 313 ................................................................ No data available. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Compliant to the requirements of the US OSHA 1910.1200 HazCom 2012 standard. PREPARED BY: ................................................................................. G. M. House APPROVED BY: ................................................................................. G. M. House SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ June 1, 2015 SUPERSEDES DATE: ........................................................................ October 24, 2012 SDS VERSION: .................................................................................. LAM-145-2015a OTHER HAZARD INFORMATION AND RATING SYSTEMS: HMIS® RATING NFPA® 704 CODES Christensen Arms AO Modification 9/7/23 PRO-SET® LAM-145 Resin Page 6 of 6 Last Revised: 01JUN15 HEALTH: 2 FLAMMABILITY: 1 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. 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Identification XTREME CUT 251CProduct identifier None.Other means of identification Cutting and Grinding FluidRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer Name QualiChem, Inc. Address PO Box 926 Salem, VA USA Telephone +1-540-375-6700 Email customerservice@qualichem.com Website www.qualichem.com Emergency Phone Number For Chemical Emergency ONLY (spill, leak, fire, exposure, or accident), 24 hour emergency telephone, call Chemtel at +1-800-255-3924 (US, Canada); +1-813-248-0585 elsewhere. 2. Hazard(s) identification Not classified.Physical hazards Not classified.Health hazards Label elements None.Hazard symbol Signal word None. Hazard statement Not available. Precautionary statement Prevention Not available. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS numberCommon name and synonymsChemical name % 64742-52-5Distillates, (petroleum), hydrotreated heavy naphthenic 40 - 60 929-06-62-(2-Aminoethoxy)ethanol 1 - 5 15520-05-52,2'-(Octylimino)bisethanol 1 - 5 Not AvailableAmine neutralized carboxylic acid 1 - 5 110-97-4Diisopropanolamine 1 - 5 55406-53-63-Iodo-2-propynyl butylcarbamate 0.1 - 1 Other components below reportable levels 57-55-6Propylene glycol 0.1 - 1 40 - 60 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 1 / 6 Material name: XTREME CUT 251C 2029 Version #: 01 Issue date: 12-16-2016 SDS US BhristensenOVrmsOVOOModification 9/7/23 4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists.Skin contact Rinse with water. Get medical attention if irritation develops and persists.Eye contact Rinse mouth. Get medical attention if symptoms occur.Ingestion Direct contact with eyes may cause temporary irritation.Most important symptoms/effects, acute and delayed Treat symptomatically.Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk.Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods No unusual fire or explosion hazards noted.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures This product is miscible in water. Prevent product from entering drains. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 2 / 6 Material name: XTREME CUT 251C 2029 Version #: 01 Issue date: 12-16-2016 SDS US BhristensenOVrmsOVOOModification 9/7/23 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents FormType PEL 5 mg/m3 Mist.Distillates, (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values ValueComponents FormType TWA 5 mg/m3 Inhalable fraction.Distillates, (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType Ceiling 1800 mg/m3Distillates, (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) STEL 10 mg/m3 Mist. TWA 5 mg/m3 Mist. US. Workplace Environmental Exposure Level (WEEL) Guides ValueComponents FormType TWA 10 mg/m3 Aerosol.Propylene glycol (CAS 57-55-6) No biological exposure limits noted for the ingredient(s).Biological limit values Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves.Hand protection Wear suitable protective clothing.Other No personal respiratory protective equipment normally required.Respiratory protection Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Clear Liquid.Form AmberColor Mild amineOdor Odor threshold Not available. pH 9.0 - 10.0 Melting point/freezing point < 40 °F (< 4.4 °C) estimated Initial boiling point and boiling range > 212 °F (> 100 °C) estimated Flash point None Evaporation rate Not available. Not applicable.Flammability (solid, gas) 3 / 6 Material name: XTREME CUT 251C 2029 Version #: 01 Issue date: 12-16-2016 SDS US BhristensenOVrmsOVOOModification 9/7/23 Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure < 1.0 mm Hg estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water)Complete Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 0.96 g/cm3 8.03 lb/gal Not explosive.Explosive properties Not oxidizing.Oxidizing properties Percent volatile > 10 % estimated pH in aqueous solution 8.8 - 9.2 (5% Emulsion) Specific gravity 0.96 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Not available. Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization 4 / 6 Material name: XTREME CUT 251C 2029 Version #: 01 Issue date: 12-16-2016 SDS US BhristensenOVrmsOVOOModification 9/7/23 No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Toxic to aquatic life. Harmful to aquatic life with long lasting effects.Ecotoxicity No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Diisopropanolamine -0.82 Propylene glycol -0.92 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not regulated as dangerous goods.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 5 / 6 Material name: XTREME CUT 251C 2029 Version #: 01 Issue date: 12-16-2016 SDS US :hristensen6*rms6*"6Hodification 8@f@yL 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. NoSARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) California Proposition 65 - WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US state regulations International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesCanadaDomestic Substances List (DSL) YesChinaInventory of Existing Chemical Substances in China (IECSC) YesEuropeEuropean Inventory of Existing Commercial Chemical Substances (EINECS) YesKoreaExisting Chemicals List (ECL) YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 12-16-2016Issue date Version #01 QualiChem, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer 6 / 6 Material name: XTREME CUT 251C 2029 Version #: 01 Issue date: 12-16-2016 SDS US BhristensenOVrmsOVOOModification 9/7/23 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE® 277™ THREADLOCKER HIGH STRENGTH IDH number: 88448 Product type: Anaerobic Sealant Item number: 27731 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation Henkel Way One Rocky Hill, Connecticut 06067 Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2 PICTOGRAM(S) Precautionary Statements Prevention: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling. Wear protective gloves, eye protection, and face protection. Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Christensen Arms AO Modification 9/7/23 Hazardous Component(s) CAS Number Percentage* Cumene hydroperoxide 80-15-9 1 - 5 Saccharin 81-07-2 1 - 5 Cumene 98-82-8 0.1 - 1 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Christensen Arms AO Modification 9/7/23 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8. Storage: For safe storage, store at or below 38 °C (100.4 °F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Cumene hydroperoxide None None 1 ppm (6 mg/m3) TWA (SKIN) None Saccharin None None None None Cumene 50 ppm TWA 50 ppm (245 mg/m3) PEL (SKIN) None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Red Odor: Characteristic Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg (27 °C (80.6 °F)) Boiling point/range: > 149 °C (> 300.2 °F) Melting point/ range: Not available. Specific gravity: 1.1 Vapor density: Not available. Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Flammability: Not applicable Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.71 %; 7.13 g/l (California SCAQMD Method 316B) (Estimated) Viscosity: Not available. Decomposition temperature: Not available. Christensen Arms AO Modification 9/7/23 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials. Hazardous decomposition products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. Phenolics. Incompatible materials: Strong acids and oxidizing agents. Copper. Rust. Iron. Oxygen scavengers. Strong alkalis. Reducing agents. Other polymerization initiators. Reactivity: Not available. Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects/Symptoms Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Skin contact: Causes skin irritation. Eye contact: Causes serious eye irritation. Ingestion: May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l Allergen, Central nervous system, Corrosive, Irritant, Mutagen Saccharin Oral LD50 (Mouse) = 17 g/kg No Target Organs Cumene Oral LD50 (Rat) = 2.91 g/kg Oral LD50 (Rat) = 1,400 mg/kg Inhalation LC50 (Rat, 4 h) = 8000 ppm Central nervous system, Irritant, Lung Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Cumene hydroperoxide No No No Saccharin No No No Cumene Reasonably Anticipated to be a Human Carcinogen. Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. Christensen Arms AO Modification 9/7/23 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III DOT Hazardous Substance(s): alpha,alpha-Dimethylbenzylhydroperoxide International Air Transportation (ICAO/IATA) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Additional information: IMDG-Code: Segregation group 1- Acids 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis. CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2). CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: 2 Christensen Arms AO Modification 9/7/23 Prepared by: Product Safety and Regulatory Affairs Issue date: 01/19/2018 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET Part No.: 3136-R3 DATE: 08/18/2016 SUPERSEDES: PRODUCT NAME: Rhino® 3136R-3 Hardener CHEMICAL FAMILY: Cycloaliphatic Diamine Page 1 of 3 SECTION 1 – IDENTIFICATION MANUFACTURER’S NAME: Rhino Linings Corporation ADDRESS: 9747 Businesspark Avenue, San Diego, CA, 92131 INFORMATION PHONE: 858-450-0441 EMERGENCY CONTACT: (CHEMTREC): 800-424-9300 SECTION 2 – HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Corrosive epoxy hardener. Certain individuals may have pre-existing skin or respiratory conditions causing a sensitivity or allergy which manifests as various reactions. Heating or spraying this product or the mixed parts increases potential health hazards. Health and Safety personnel should examine the handling procedures and remedy any existing or potential health and safety hazards. POTENTIAL HEALTH EFFECTS: EYE: • Can cause irritation. Significant, prolonged, or repeated contact can damage the cornea. SKIN: • Can cause irritation. Significant, prolonged, or repeated exposure can cause severe irritation. INGESTION: • Can inflame or damage the G.I. tract. Ingestion can be harmful. INHALATION: • Can cause irritation. Significant, prolonged, or repeated exposure to mist or vapor can damage the respiratory system. CHRONIC EFFECTS: • Repeated exposure can cause irritation and sensitization. SIGNS & SYMPTOMS: • Skin rash, irritation, reddening, or eczema; breathing irritation or difficulty. SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT % CAS # EXPOSURE LIMITS Isophorone Diamine >99.7 2855-13-2 N/E SECTION 4 – FIRST-AID MEASURES USE APPROPRIATE BLOOD-BORNE PATHOGENS PROTECTIONS EYE: • Hold eyelids apart and flood with copious amounts of water. Seek medical attention. SKIN: • Remove excess product. Wash thoroughly with soap and water. If irritation persists, seek medical attention. INGESTION: • Do not induce vomiting unless directed by medical personnel. Seek medical attention. INHALATION: • Remove to fresh air. Seek medical attention. Christensen5Arms5AO5Modification 9/7/23 SAFETY DATA SHEET Part No.: 3136-R3 DATE: 08/18/2016 SUPERSEDES: PRODUCT NAME: Rhino® 3136R-3 Hardener CHEMICAL FAMILY: Cycloaliphatic Diamine Page 2 of 3 SECTION 5 – FIRE-FIGHTING MEASURES FLASH POINT: 117°C (DIN 51758) UEL: N.D.A.% LEL: 1.2% (V) VAPOR DENSITY: N.D.A. NFPA FLAMMABILITY RATING: 1 AUTOIGNITION: N.D.A. COMBUSTION PRODUCTS: CO, CO2, NOx, & misc. hydrocarbons SPECIAL HAZARDS: Firefighters should wear butyl rubber boots, gloves, and body suit with SCBA. May generate toxic and irritating combustion products. Use DOT Response Guide #153. EXTINGUISHING MEDIA: Use foam, CO2, dry chemical, water fog. FIRE FIGHTER INSTRUCTIONS: Stay upwind. Wear at least full bunker gear and SCBA. SECTION 6 – ACCIDENTAL RELEASE MEASURES Isolate the spill area. Keep out of sewer or storm drains. Stop the leak and contain the spill. Vacuum, scoop, or absorb spill with non- combustible materials. Clean up spill residues with soap and water. SECTION 7 – HANDLING AND STORAGE Avoid skin and eye contact and breathing vapors by appropriate measures. Do not eat or smoke while handling this product. Wash thoroughly with soap and water after handling or exposure to this product. Store in original sealed container at ambient temperatures (65°-80°F) in dry, well-ventilated areas. SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION For Personal Exposure Limits (PEL), Threshold Limit Values (TLV), or other exposure limits, see Sec. 3. GENERAL: Provide adequate ventilation that will keep airborne concentration at a minimum. EYE/FACE: Safety glasses or splash goggles with face shield. SKIN: Butyl or nitrile rubber chemical gloves. Don chemical resistant clothing where exposure may occur. RESPIRATORY: NIOSH approved respirator with organic vapor/HEPA filter cartridges. OTHER: Decontaminate or discard clothing and materials that have come in contact with this product. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: clear ODOR: slightly amine-like PHYSICAL STATE: liquid VAPOR PRESS: ca. 0.02 hpa(20°C) SPECIFIC GRAVITY: 0.924 @ 20°C pH: 11.6 BOILING PT: >252.9°C (1013 hPa) MELT PT: N.D.A. SOLUBILITY IN H2O: slight SECTION 10 – STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable. INCOMPATIBILITY: Strong oxidizers, acids, epoxy resins in uncontrolled conditions; contact with other unpolymerized monomers or polymers. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION: None known, other than Sec. 5’s Combustion Products. SECTION 11 – TOXICOLOGICAL INFORMATION Oral: N.D.A. Dermal: N.D.A. Inhalation: N.D.A. Carcinogens under OSHA, ACGIH, NTP, IARC, or Other: None 0.1%. Christensen5Arms5AO5Modification 9/7/23 SAFETY DATA SHEET Part No.: 3136-R3 DATE: 08/18/2016 SUPERSEDES: PRODUCT NAME: Rhino® 3136R-3 Hardener CHEMICAL FAMILY: Cycloaliphatic Diamine Page 3 of 3 SECTION 12 – ECOLOGICAL INFORMATION N.D.A. SECTION 13 – DISPOSAL CONSIDERATIONS Dispose of in accordance with applicable federal, state, and local laws and regulations. SECTION 14 – TRANSPORT INFORMATION DOT: ISOPHORONEDIAMINE, 8, UN 2289, PGIII. IATA: Regulated. IMO: UN 2289 Isophoronediamine, class 8, PG III SECTION 15 – REGULATORY INFORMATION OSHA: 1910.1200 Hazardous Chemical “Corrosive”, “Sensitizer”. TSCA: Contains listed ingredients. SARA III: Sec311 & 312 Immediate Health Hazard; Sec313 Chemicals above de minimus level: None. CA PROP. 65 NOTICE: Not listed. VOLATILE ORGANIC COMPOUND (VOC) %: Zero. NFPA: HEALTH 3 FIRE 1 REACTIVITY 0 OTHER N/A WHMIS: Hazard Classification: Class D Division 1B & 2A, Class E Corrosive. WHMIS Symbols: Stylized T, Corrosive. Trade Secrets: N/A. Hazardous Products Act Information: This product SDS contains ingredients which are Controlled and/or on the Ingredient Disclosure List (HPA sections 13 and 14). ABBREVIATIONS: N/A = not applicable; N.D.A. = no data available; NE = not established SECTION 16 – OTHER INFORMATION 3/30/2015 Change to SDS format. Supersedes. ABBREVIATIONS: N/A = not applicable; N.D.A. = no data available; NE = not established Disclaimer: The data set forth in this sheet are based on information provided by the suppliers of the raw materials and chemicals used in the manufacture of the aforementioned product. Rhino Linings Corporation makes no warranty with respect to the accuracy of the information provided by their suppliers, and disclaims all liability of reliance thereof. Christensen5Arms5AO5Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Product Name: Unilube 22 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name:Unilube 22 Product Description: R&O Turbine Oil/Anti-Wear ISO 32 Product Code:BOSUNI022-275, BOSUNI022-055, BOSUNI022-005 Intended Use:Turbine, Circulating, Hydraulic & Bar Feed Oil Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone:Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address:http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.Christensen Arms AO Modification 9/7/23 Product Name: Unilube 22 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3)OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media:Straight streams of water Fire Fighting Instructions:Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point:>400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 0 Flammability = 1 Reactivity = 0 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures:Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures:After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures:Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802.Christensen Arms AO Modification 9/7/23 Product Name: Unilube 22 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 3 of 6 SECTION 7 HANDLING AND STORAGE General Precautions:When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage:Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures:The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection:No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures:Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls:Minimize exposure of this material to the environment. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.Christensen Arms AO Modification 9/7/23 Product Name: Unilube 22 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 4 of 6 SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers:Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION OT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) :Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe- handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. End of SDS Christensen Arms AO Modification 9/7/23 Product Name: Bos-Way 2 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name:BOS-WAY 2 Product Description: Way Lubricant/Lubricating Oil ISO 68 Product Code:BOSWAY2-005, BOSWAY2-055, BOSWAY2-275 Intended Use:Way Lubricant or Lubricating Oil Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone:Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address:http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.Christensen Arms AO Modification 9/7/23 Product Name: Bos-Way 2 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3)OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media:Straight streams of water Fire Fighting Instructions:Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point:>400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 0 Flammability = 1 Reactivity = 0 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures:Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures:After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures:Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802.Christensen Arms AO Modification 9/7/23 Product Name: Bos-Way 2 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 3 of 6 SECTION 7 HANDLING AND STORAGE General Precautions:When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage:Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures:The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection:No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures:Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls:Minimize exposure of this material to the environment. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Viscous Liquid Mild N/D N/D N/A N/A 599oF N/D >400oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.Christensen Arms AO Modification 9/7/23 Product Name: Bos-Way 2 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page:Page 4 of 6 SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers:Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) :Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard:When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories:None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted.End of SDS Christensen Arms AO Modification 9/7/23 Product Name: Premium Spindle 10 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 1 of 6 Safety Data Sheet SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name: Premium Spindle 10 Oil Product Description: Spindle Oil ISO VG 10 Product Code: BOSSPIN10-005, BOSSPIN10-055 Intended Use: Spindle Oil/Fluid, Circulating, Light Lubrication Oil & Heat Transfer Oil Company Identification Bosse Lubricants Mailing Address Warehouse Address PO Box 11330 Glendale, AZ 85318 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Warning Causes Mild Skin Irritation – Category 3 Health Hazards This product should not present any health issues when used under normal conditions as intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is considered a low toxicity material. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Product Name: Premium Spindle 10 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 2 of 6 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredient CAS Number ACGIH (TWA mg/m3) OSHA No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 FIRST AID MEASURES General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended. Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have been ingested or person affected is not feeling well, seek medical attention. SECTION 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke). Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and sulfur oxides. Flash Point: >400oF Auto Ignition Temperature: N/D NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0 Christensen Arms AO Modification 9/7/23 Product Name: Premium Spindle 10 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 3 of 6 SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from entering rivers, streams, storm drains and any area that will allow the material to spread. Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate areas. A pump or vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water ways such as streams or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The National Response Center can be reached at 1.800.424.8802. SECTION 7 HANDLING AND STORAGE General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any special handling instructions. We still recommend personal protection just as a good safety practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial hygiene and safety practice. Always replace the lid or cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures are recommended. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Minimize exposure of this material to the environment. Christensen Arms AO Modification 9/7/23 Product Name: Premium Spindle 10 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 4 of 6 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor Threshold pH Melting Point Freezing Point Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas) Oily Liquid Mild N/D N/D N/A N/A 599oF N/D >260oF N/D N/D Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature LEL: 0.9 UEL: 7.0 N/D <0.01 mmHg @ 100oF >1 0.85 – 0.89 Soluble In Hydrocarbons; Insoluble In Water N/D N/D N/D These are typical physical and chemical properties SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity: No data available SECTION 12 ECOLOGICAL INFORMATION Mobility: No data available Eco-toxicity Effects: No data available Bioaccumulation Potential: No data available Aquatic Toxicity: No data available Christensen Arms AO Modification 9/7/23 Product Name: Premium Spindle 10 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste From Residues & Unused Products: Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Christensen Arms AO Modification 9/7/23 Product Name: Premium Spindle 10 Issue Date: 05/15/2015 Language: English Version: 2 Format: US Page: Page 6 of 6 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Christensen Arms AO Modification 9/7/23 Command Clean Heavy-Duty Degreaser Concentrate Issue Date 05/15/2015 1 GHS Safety Data Sheet (SDS) SECTION 1 MATERIAL AND COMPANY IDENTIFICATION Material Identification Product Name Identifier: Command Clean Heavy-Duty Degreaser Concentrate Product Description: Concentrated industrial aqueous cleaner / degreaser Product Code: COMHDCLN-005, COMHDCLN-055 Intended Use: Industrial Cleaning Supplier Details: Command Clean 5143 W. Roosevelt St Phoenix, AZ 85043 Phone 800.367.9966 Fax 602.256.2231 Email: customerservice@metalfluids.com 24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 SDS Internet Address: http://www.metalfluids.com SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS): Health, Causes eye irritation, 2 B GHS Label elements, including precautionary statements GHS Signal Word: WARNING GHS Hazard Pictograms: no GHS pictograms indicated for this product GHS Hazard Statements: Causes eye irritation GHS Precautionary Statements: IF SWALLOWED: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. IF ON SKIN: Wash with soap and water. IF INHALED: Prolonged exposure is not expected to cause adverse effects. IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice. Hazards not otherwise classified (HNOC) or not covered by GHS Inhalation: Prolonged exposure is not expected to cause adverse effects. Skin Contact: Non-irritating. Eye Contact: May cause slight eye irritation. Ingestion: Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Christensen Arms AO Modification 9/7/23 Command Clean Heavy-Duty Degreaser Concentrate Issue Date 05/15/2015 2 SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS Ingredients: The specific chemical identity and chemical composition has been withheld as a trade secret. The precise composition of this mixture is proprietary information. A complete disclosure will be provided to a physician or nurse in the event of a medical emergency. SECTION 4 FIRST AID MEASURES Inhalation If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention. Skin Contact Wash with soap and water. Eye Contact Flush eyes thoroughly with water for 15 minutes. Remove contact lenses after the initial 1 -2 minutes and continue flushing for several additional minutes. If effects occur, consult physician. Ingestion If swallowed, seek medical attention if symptoms develop. Do not induce vomiting unless directed to do so by medical attention SECTION 5 FIRE FIGHTING MEASURES Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective. Fire Fighting Procedures: Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Avoid accumulation of water. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting SECTION 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Spilled material may cause a slipping hazard. Use appropriate safety equipment. (See Section 8) Methods and materials for containment and cleaning up: Small spills: Absorb with materials such as: sand, vermiculite, absorbent pillows, pads and/or wipes. Do not use water for clean up. Collect in suitable and properly labeled containers. Large spills: Contain spilled material if possible. Pump into suitable and properly labeled containers. SECTION 7 HANDLING AND STORAGE Handling Precautions: Avoid contact with eyes. Wash thoroughly after handling. Storage Requirements: Store indoors away from direct sunlight. Keep containers closed when not in use. Shelf life: 24 Months SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: General ventilation should be sufficient for most operations. Personal Protection: HMIS PP, B I Safety Glasses, Gloves Respiratory Protection: Wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk Christensen Arms AO Modification 9/7/23 Command Clean Heavy-Duty Degreaser Concentrate Issue Date 05/15/2015 3 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odor Threshold Solubility Spec Gravity/Density Viscosity Boiling Point Freezing/Melting Point Flammability Flash Point Partition Coefficient Vapor Pressure Vapor Density pH VOC Evaporation Rate Auto Ignition Temperature Decomposition Temperature UFL/LFL Clear to yellowish Liquid Light Citrus N/D Miscible in water in all proportions 0.998 +/- 0.003 (Hydrometer) N/D N/D N/D N/D >200oF Test Method SW1010 A N/D <1.0 mm Hg @ 68°F (not including water content). N/D 8 – 10 75 g/l in "Neat" form. 25 g/l when diluted 2:1 with H20, SCAQMD certified clean air solvent. N/D N/D N/D N/D SECTION 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Materials To Avoid: This is a water-based product. Strong Acids; Strong Bases; Strong Oxidizing Agents. Hazardous Decomposition Products: Will not occur. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Likely routes of exposure Inhalation: Prolonged exposure is not expected to cause adverse effects. Ingestion: Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury. Skin: Non-irritating Eyes: May cause eye irritation Skin Corrosion/Irritation Non-irritant per Dermal Irritection assay modeling. No animal testing performed Eye Damage/Irritation May cause mild eye irritation per Oclular Irritection assay modeling. No animal testing performed. (GHS Hazard category 2B) Germ Cell Mutagenicity: Mixture does not classify under this category Carcinogenicity: Mixture does not classify under this category Reproductive Toxicity: Mixture does not classify under this category STOT-Single Exposure: Mixture does not classify under this category STOT-Repeated Exposure: Mixture does not classify under this category Aspiration Hazard: Mixture does not classify under this category SECTION 12 ECOLOGICAL INFORMATION Fish Toxicity LC50, Pimephales promelas, 96 hour: 156 ppm. Aquatic Invertebrate Toxicity LC50, Daphnia pulex, 48 hour: 340 ppm. Persistence and Degradability Biodegradation Tests: Fully biodegradable in accordance with ISO 9439. SECTION 13 DISPOSAL CONSIDERATIONS Dispose of uncontaminated material into sewer where applicable within Federal, State and/or local laws and regulations. Disposal of contaminated material must be in compliance with all Federal, State and/or local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. Christensen Arms AO Modification 9/7/23 Command Clean Heavy-Duty Degreaser Concentrate Issue Date 05/15/2015 4 SECTION 14 TRANSPORT INFORMATION DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport This information is not intended to convey all specific regulatory or operational requirements information relating to this product. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. SECTION 15 REGULATORY INFORMATION OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances. SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable Command Clean urges each customer or recipient of this SOS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this SOS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that its activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific SDS5, we are not and cannot be responsible for SDS5 obtained from any source other than ourselves. If you have obtained an SOS from another source or if you are not sure that the SOS you have is current, please contact us for the most current version. Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet DOL-US according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 08/10/2015 Revision date: 10/31/2017 Supersedes: 01/27/2016 Version: 2.1 10/31/2017 EN (English US) SDS ID: DOL-US Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : DOLPHIN GLAZE (DOL-US) Product group : bodyfiller Other means of identification : UP0713, UP0714 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Supplier U-POL US Inc 108 Commerce Way Stockertown PA 18083 - USA T 1-800-340-7824 - F 1-800-787-5150 technical.department@u-pol.com - www.u-pol.com 1.4. Emergency telephone number Emergency number : CHEMTREC - 1-800-424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flam. Liq. 3 H226 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Carc. 2 H351 Repr. 2 H361 STOT RE 1 H372 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H226 - Flammable liquid and vapor H315 - Causes skin irritation H319 - Causes serious eye irritation H351 - Suspected of causing cancer H361 - Suspected of damaging the unborn child. H372 - Causes damage to organs (hearing organs) through prolonged or repeated exposure (Inhalation) Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood. P263 - Avoid contact during pregnancy/while nursing. P264 - Wash hands thoroughly after handling. P280 - Wear eye protection, protective clothing, protective gloves. P302+P352 - If on skin: Wash with plenty of water P305 - IF IN EYES: Rinse first with plenty of water and if necessary take medical advice P332+P313 - If skin irritation occurs: Get medical advice/attention. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 2/9 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification styrene (CAS-No.) 100-42-5 5 - 23 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Repr. 2, H361 STOT RE 1, H372 TITANIUM DIOXIDE (CAS-No.) 13463-67-7 < 5 Carc. 2, H351 ethylbenzene (CAS-No.) 100-41-4 < 5 Flam. Liq. 2, H225 Acute Tox. 4 (Inhalation), H332 Carc. 2, H351 STOT RE 2, H373 Asp. Tox. 1, H304 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact : Irritation. Symptoms/effects after eye contact : Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapor. Reactivity : Flammable liquid and vapor. 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Safety glasses. Protective clothing. Gloves. Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe vapors, fume. Avoid contact with skin and eyes. Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 3/9 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapors may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe fume, vapors. Avoid contact with skin and eyes. Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Storage temperature : < 25 °C Storage area : Store in a well-ventilated place. Special rules on packaging : Keep only in original container. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters DOLPHIN GLAZE (DOL-US) ACGIH Not applicable OSHA Not applicable styrene (100-42-5) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 40 ppm ACGIH Remark (ACGIH) CNS impair; URT irr; peripheral OSHA Remark (OSHA) (2) See Table Z-2. ethylbenzene (100-41-4) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH Remark (ACGIH) URT irr; kidney dam (nephropathy) OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ OSHA OSHA PEL (TWA) (ppm) 100 ppm TITANIUM DIOXIDE (13463-67-7) ACGIH ACGIH TWA (mg/m³) 1 mg/m³ ACGIH Remark (ACGIH) LRT irr; A3 OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 4/9 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Personal protective equipment : Safety glasses. Gloves. Protective clothing. Materials for protective clothing : Impermeable clothing. Hand protection : Protective gloves. Eye protection : Safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear respiratory protection. Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Viscous. Liquid. Color : light green Odor : aromatic Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : Not applicable Freezing point : No data available Boiling point : No data available Flash point : 30 °C Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 °C : No data available Relative density : No data available Specific gravity / density : 1.17 - 1.21 Solubility : insoluble in water. soluble in most organic solvents. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : 20000 - 25000 cP Explosive properties : No data available Oxidizing properties : No data available Explosion limits : No data available 9.2. Other information VOC content - Regulatory : 220 g/l SECTION 10: Stability and reactivity 10.1. Reactivity Flammable liquid and vapor. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 5/9 10.4. Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified styrene (100-42-5) ATE US (gases) 4500 ppmV/4h ATE US (vapors) 11 mg/l/4h ATE US (dust, mist) 1.5 mg/l/4h ethylbenzene (100-41-4) ATE US (gases) 4500 ppmV/4h ATE US (vapors) 11 mg/l/4h ATE US (dust, mist) 1.5 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer. styrene (100-42-5) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 3 - Reasonably anticipated to be Human Carcinogen ethylbenzene (100-41-4) IARC group 2B - Possibly carcinogenic to humans TITANIUM DIOXIDE (13463-67-7) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Suspected of damaging the unborn child. Specific target organ toxicity – single exposure : Not classified Specific target organ toxicity – repeated exposure : Causes damage to organs (hearing organs) through prolonged or repeated exposure (Inhalation). Aspiration hazard : Not classified Symptoms/effects after skin contact : Irritation. Symptoms/effects after eye contact : Eye irritation. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 6/9 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known effects from this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. Additional information : Flammable vapors may accumulate in the container. SECTION 14: Transport information In accordance with DOT Transport document description : UN1866 Resin solution (flammable), 3, III UN-No.(DOT) : UN1866 Proper Shipping Name (DOT) : Resin solution flammable Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid Packing group (DOT) : III - Minor Danger DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672). T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Packaging Non Bulk (49 CFR 173.xxx) : 173 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 60 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 220 L DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel. Additional information Other information : No supplementary information available. ADR Transport document description : UN 1866 RESIN SOLUTION, 3, III, (D/E) Packing group (ADR) : III Class (ADR) : 3 - Flammable liquid Hazard identification number (Kemler No.) : 30 Classification code (ADR) : F1 Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 7/9 Hazard labels (ADR) : 3 - Flammable liquids Orange plates : Tunnel restriction code (ADR) : D/E LQ : 5l Excepted quantities (ADR) : E1 Transport by sea UN-No. (IMDG) : 1866 Proper Shipping Name (IMDG) : RESIN SOLUTION Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : III - substances presenting low danger Air transport UN-No. (IATA) : 1866 Proper Shipping Name (IATA) : Resin solution Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : III - Minor Danger SECTION 15: Regulatory information 15.1. US Federal regulations Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. styrene CAS-No. 100-42-5 5 - 23% ethylbenzene CAS-No. 100-41-4 < 5% xylene CAS-No. 1330-20-7 < 5% styrene (100-42-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 1000 lb ethylbenzene (100-41-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 1000 lb SARA Section 313 - Emission Reporting 0.1 % TITANIUM DIOXIDE (13463-67-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA styrene (100-42-5) Listed on the Canadian DSL (Domestic Substances List) ethylbenzene (100-41-4) Listed on the Canadian DSL (Domestic Substances List) TITANIUM DIOXIDE (13463-67-7) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 8/9 Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 H226 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Repr. 2 H361 STOT RE 1 H372 Full text of hazard classes and H-statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations styrene (100-42-5) Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) Listed on EPA Hazardous Air Pollutant (HAPS) \ ethylbenzene (100-41-4) Listed on IARC (International Agency for Research on Cancer) Listed on EPA Hazardous Air Pollutant (HAPS) \ TITANIUM DIOXIDE (13463-67-7) Listed on IARC (International Agency for Research on Cancer) \ 15.3. US State regulations California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer, developmental and/or reproductive harm styrene (100-42-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Yes No No No ethylbenzene (100-41-4) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Yes No No No 54 μg/day SECTION 16: Other information Revision date : 10/31/2017 Full text of H-phrases: ------ H225 Highly flammable liquid and vapour ------ H226 Flammable liquid and vapor ------ H304 May be fatal if swallowed and enters airways ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled ------ H351 Suspected of causing cancer ------ H361 Suspected of damaging fertility or the unborn child ------ H372 Causes damage to organs through prolonged or repeated exposure ------ H373 May cause damage to organs through prolonged or repeated exposure NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. NFPA reactivity : 1 - Materials that in themselves are normally stable but can become unstable at elevated temperatures and pressures. Christensen Arms AO Modification 9/7/23 DOLPHIN GLAZE (DOL-US) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) SDS ID: DOL-US 9/9 SDS US UPOL For professional use only. The information contained within this Safety Data Sheet (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL’s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at WWW.U-POL.COM. Christensen Arms AO Modification 9/7/23 page 1 of 3 FLASH POINT 108 °F TCC Specific Gravity 1.15 Product Weight 9.57 lb/gal 26 00 [0425] ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) Date of Preparation May 20, 2019 PRODUCT NUMBER V66V27 PRODUCT NAME POLANE® Catalyst MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) V66V27 = | Acute | Chronic | Fire | Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume 1-Methoxy-2-Propanol Acetate 108-65-6 N N N N 40 45 Non-Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume Toluene-2,4-diisocyanate (max.) 584-84-9 Y Y Y Y 0.3 < 1 Volatile Organic Compounds - U.S. EPA / Canada V66V27 LB/Gal g/L Coating Density 9.57 1146 By wt By vol Total Volatiles 40.0%45.3% Federally exempt solvents Water 0.0%0.0% Organic Volatiles 40.0%45.3% Percent Non-Volatile 60.0%54.7% VOC Content LB/Gal g/L Total 3.82 458 Less exempt solvents 3.82 458 Of solids 7.00 839 Of solids 0.66 lb/lb 0.66 kg/kg By wt By wt LVP-VOC 40.0% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.68 Christensen Arms AO Modification 9/7/23 V66V27 page 2 of 3 Volatile Organic Compounds - California V66V27 LB/Gal g/L Coating Density 9.57 1146 By wt By vol Total Volatiles 40.0%45.3% Exempt solvents Water 0.0%0.0% Organic Volatiles 40.0%45.3% Percent Non-Volatile 60.0%54.7% VOC Content LB/Gal g/L Total 3.82 458 Less exempt solvents 3.82 458 Of solids 7.00 839 Of solids 0.66 lb/lb 0.66 kg/kg By wt By wt LVP-VOC 40.0% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.67 Volatile Organic Compounds - South Coast Air Quality Management District, California, US V66V27 LB/Gal g/L Coating Density 9.57 1146 By wt By vol Total Volatiles 40.0%45.3% Exempt solvents Water 0.0%0.0% Organic Volatiles 40.0%45.3% Percent Non-Volatile 60.0%54.7% VOC Content LB/Gal g/L Total 3.82 458 Less exempt solvents 3.82 458 Of solids 7.00 839 Of solids 0.66 lb/lb 0.66 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC V66V27 By wt By vol Total Volatiles 40.0% 45.3% VOC Content LB/Gal g/L Total 3.82 458 Volatile Organic Compounds - EU Directive 2010/75/EU V66V27 By wt By vol Total Volatiles 40.0% 45.3% VOC Content LB/Gal g/L Total 3.82 458 Christensen Arms AO Modification 9/7/23 V66V27 page 3 of 3 Volatile Organic Compounds - Mexico V66V27 LB/Gal g/L Coating Density 9.57 1146 By wt By vol Total Volatiles 40.0%45.3% Exempt solvents Water 0.0%0.0% Organic Volatiles 40.0%45.3% Percent Non-Volatile 60.0%54.7% VOC Content LB/Gal g/L Total 3.82 458 Less exempt solvents 3.82 458 Of solids 7.00 839 Of solids 0.66 lb/lb 0.66 kg/kg Hazardous Air Pollutants (Clean Air Act, Section 112(b)) V66V27 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 8.44 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Christensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification 9/7/23  A      C    $%  C     ,,- !0N/L,O "!E ,771= N "M O        /               C @7 (!M ,!M: P"-(7"P"-(    "/  -+ " " " " " " " 9  5: "      < +   & % 9: "D/,%Q 55/,%,Q       "          ","-9%ER=     #  +"  55 (    >   % )        *    %   5 /(B= 5 /E/B 7 < 5//C6( 6D 6 / C6 /6/ 6=//'5( / . //(B= <  D 5/  ((7  D/(B /  //7 ( B / = 6. C /(75 5/( .   5/( ).5/(   * 2 ( /(75  D . .B D=7 /  'C=7 /  " " " !   "  )    "//7 ( B / = 6. C // ( D  ((/ $%"5(B(   /  / (      B/ .5/( / =/     &      & "#7 .' #,#7 .  .  (  <-</7 2  P-=E=# <-/ 2 -%"7=E= # ) <(   <-/ 2 !,%7=E= # -   $  &   !  -*   ) <(   E#///  2  #- 7 =/ 7 # -   $ &    %  )   !    &        "         8008"9    ./01/'/, /2Christensen Arms AO Modification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hristensen Arms AO Modification 9/7/23    &           ( C6 / /=(/ ( 7 ((/D. '5  /  D   ,  " 5( B( =( (/2EB( (/5/    B '5/ *  " ED=B(  BB( /(/ ( . C /#" &  7 = ./(.   " %  "ED=B(  BB( /(/ ( . C /  "ED=B(  BB( /(/ ( . C / 6  !  (( /(B D=. (/ B  . E  7 B/7  / 75 77 (  .B D= /(B D=. (/ B  . E  7 B/7  / 75 77 (  .B D= //  / /(B D=. (/ B  . E  7 B/7  " "              &   '    &        &    "        &      "         "      <  &      "       (      ? %   &                        "         8008"9    ./01/'/, /2Christensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification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hristensen Arms AO Modification 9/7/23      "          8008"9    ./01/'/, /2Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product name 5&,6SFUIBOF1SJNFS4VSGBDFS Product code 34-200 Formula date 2017-01-26 Recommended use Coating for professional use Responsible party National Coatings and Supplies 4900 Falls of Neuse Road Suite 150 Raleigh, NC 27609 Telephone Product information 866-529-1682 Medical emergency 800-424-9300 Transportation emergency 800-424-9300 2. HAZARDS IDENTIFICATION GHS-Classification Flammable liquids, Category 2 ; Skin corrosion/irritation, Category 2 ; Serious eye damage/eye irritation, Category 2A ; Carcinogenicity, Category 2 ; Toxicity for reproduction, Category2;TargetOrganSystemic Toxicant - Repeated exposure, Category 1 GHS-Labelling Hazard symbols: Signal word: Danger Hazard statements:Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Precautionary statements:Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. Specific treatment (see supplemental first aid instructions on this label). If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container in accordance with local regulations. Other hazards which do not result in classification Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: Creation date: 2018-04-10 Page 1 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en 0% 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture of synthetic resins, pigments, and solvents Components CAS-No. Chemical name Concentration 100-41-4 Ethylbenzene 3.0% 108-65-6 Propylene glycol monomethyl ether acetate 4 - 15% 110-12-3 Methyl isoamyl ketone 1 - 4% 123-86-4 Butyl acetate 4 - 15% 1330-20-7 Xylene 12% 1333-86-4 Carbon black 0.1% 13463-67-7 Titanium dioxide 5.8% 136-53-8 Zinc carboxylate 0.1% 78-93-3 Methyl ethyl ketone 4 - 15% Any concentration shown as a range is due to batch variation. Non-regulated ingredients 60 - 70% OSHA Hazardous: Yes 4. FIRST AID MEASURES Eye contact:Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical advice. Skin contact:Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use recognized skin cleanser. If skin irritation persists, call a physician. Inhalation:Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. Ingestion:If swallowed, seek medical advice immediately and show this safety data sheet (SDS) or product label. Do NOT induce vomiting. Keep at rest. Most Important Symptoms/effects, acute and delayed Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. If this product mixed with an isocyanate activator/hardener (see SDS for the activator), the following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, Creation date: 2018-04-10 Page 2 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Ingestion:May result in gastrointestinal distress. Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. If this product is mixed with an isocyanate, skin contact may cause sensitization. Indication of Immediate medical attention and special treatment needed if necessary:No data available on the product. See section 3 and 11 for hazardous ingredients found in the product. 5. FIREFIGHTING MEASURES Suitable extinguishing media:Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical Extinguishing media which shall not be used for safety reasons:High volume water jet Hazardous combustion products:CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section. Fire and Explosion Hazards:Flammable liquid. Vapor/air mixture will burn when an ignition source is present. Special Protective Equipment and Fire Fighting Procedures:Full protective flameproof clothing should be worn as appropriate. Wear self-contained breathing apparatus for firefighting if necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or public waterways. 6. ACCIDENTAL RELEASE MEASURES Procedures for cleaning up spills or leaks:Ventilate area. Remove sources of ignition. Prevent skin and eye contact and breathing of vapor. If the material contains, or is mixed with an isocyanate activator/hardener: Wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection, gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit at least 10 minutes. Typical decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TMN 10) and 80% Water OR 0 -10% Ammonia, 2-5% Detergent and Water (balance) Pressure can be generated. Do not seal waste containers for 48 hours to allow C02 to vent. After 48 hours, material may be sealed and disposed of properly. If material does not contain or is not mixed with an isocyanate activator/hardener: Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH approved TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of properly. Environmental precautions:Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers, lakes or waste water systems. 7. HANDLING AND STORAGE Precautions for safe handling:Observe label precautions. Keep away from heat, sparks, flame, static discharge and other sources of ignition. VAPORS MAY CAUSE FLASH FIRE. Close container after each use. Ground containers when pouring. Do not transfer contents to bottles or unlabeled containers. Wash thoroughly after handling and before eating or smoking. Do not store above 49 ◦C (120 ◦F). If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation, and gloves. Combustible dust clouds may be created where operations produce fine material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds. Build up of fine material should Creation date: 2018-04-10 Page 3 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods (e.g. compressed air) which can generate potentially combustible dust clouds should not be used. Advice on protection against fire and explosion:Solvent vapours are heavier than air and may spread along floors. Vapors may form explosive mixtures with air and will burn when an ignition source is present. Always keep in containers of same material as the original one. Never use pressure to empty container: container is not a pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards. Storage Requirements for storage areas and containers:Observe label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Advice on common storage:Store separately from oxidizing agents and strongly alkaline and strongly acidic materials. OSHA/NFPA Storage Classification: IB 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls and work practices:Provide adequate ventilation.This should be achieved by a good general extraction and -if practically feasible- by the use of a local exhaust ventilation.If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn. National occupational exposure limits CAS-No. Chemical name Source Time Type Value Note 1330-20-7 Xylene ACGIH 15 min STEL 150 ppm ACGIH 8 hr TWA 100 ppm OSHA 8 hr TWA 100 ppm 13463-67-7 Titanium dioxide OSHA 8 hr TWA 15 mg/m3 Total Dust 123-86-4 Butyl acetate ACGIH 15 min STEL 200 ppm ACGIH 8 hr TWA 150 ppm OSHA 8 hr TWA 150 ppm 78-93-3 Methyl ethyl ketone ACGIH 8 hr TWA 200 ppm OSHA 8 hr TWA 200 ppm 100-41-4 Ethylbenzene ACGIH 8 hr TWA 20 ppm OSHA 8 hr TWA 100 ppm 110-12-3 Methyl isoamyl ketone ACGIH 8 hr TWA 20 ppm 1333-86-4 Carbon black ACGIH 8 hr TWA 3 mg/m3 OSHA 8 hr TWA 3.5 mg/m3 Glossary CEIL Ceiling exposure limit STEL Short term exposure limit TL Threshold limits TLV Threshold Limit Value TWA Time weighted average TWAE Time-Weighted Average Protective equipment:Personal protective equipment should be worn to prevent contact with eyes, skin or clothing. Respiratory protection:Do not breathe vapors or mists. When this product is used with an isocyanate activator/hardener, wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C) while mixing activator/hardener with paint, during application and until all vapors and spray mist are exhausted. If product is used without isocyanate activator/hardener, a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH TC-23C) and particulate filter (NIOSH TC-84A) may be used. Follow respirator manufacturer’s directions for respirator Creation date: 2018-04-10 Page 4 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label instructions and SDS for further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates should not use or be exposed to this product if mixed with isocyanate activators/hardeners. Eye protection:Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash guard or side shields. Skin and body protection:Neoprene gloves and coveralls are recommended. Hygiene measures:Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Environmental exposure controls:Do not let product enter drains. For ecological information, refer to Ecological Information Section 12. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form:liquid Colour:grey Flash point 45◦F Lower Explosive Limit 1% Upper Explosive Limit 11.5 % Evaporation rate Slower than Ether Vapor pressure of principal solvent 12.8 hPa Water solubility appreciable Vapor density of principal solvent (Air = 1)3.7 Approx. Boiling Range 78◦C Approx. Freezing Range Not applicable. Gallon Weight (lbs/gal)11.84 Specific Gravity 1.42 Percent Volatile By Volume 58.29% Percent Volatile By Weight 35.17% Percent Solids By Volume 41.71% Percent Solids By Weight 64.83% pH (waterborne systems only)No data available. Partition coefficient: n-octanol/water No data available Ignition temperature 272◦C DIN 51794 Decomposition temperature Not applicable. Viscosity (23 ◦C)Not applicable. ISO 2431-1993 VOC* less exempt (lbs/gal)4.1 VOC* as packaged (lbs/gal)4.1 * VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of manufacture. 10. STABILITY AND REACTIVITY Stability:Stable Conditions to avoid:Stable under recommended storage and handling conditions (see section 7). Creation date: 2018-04-10 Page 5 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en Materials to avoid:None reasonably foreseeable. Hazardous decomposition products:When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, oxides of nitrogen. Hazardous Polymerization:Will not occur. Sensitivity to Static Discharge:Solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product. Sensitivity to Mechanical Impact:None known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. If this product mixed with an isocyanate activator/hardener (see SDS for the activator), the following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Ingestion:May result in gastrointestinal distress. Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. Delayed and immediate effects and also chronic effects from short and long term exposure: Acute oral toxicity not hazardous Acute dermal toxicity not hazardous Acute inhalation toxicity not hazardous % of unknown composition: 0 % Skin corrosion/irritation Xylene Category 2 Butyl acetate Category 3 Methyl ethyl ketone Category 3 Propylene glycol monomethyl ether acetate Category 3 Ethylbenzene Category 2 Methyl isoamyl ketone Category 3 Serious eye damage/eye irritation Xylene Category 2A Methyl ethyl ketone Category 2A Propylene glycol monomethyl ether acetate Category 2B Creation date: 2018-04-10 Page 6 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en Methyl isoamyl ketone Category 2A Respiratory sensitisation Not classified according to GHS criteria Skin sensitisation Not classified according to GHS criteria Germ cell mutagenicity Not classified according to GHS criteria Carcinogenicity Titanium dioxide Category 2 Ethylbenzene Category 2 Carbon black Category 2 Toxicity for reproduction Zinc carboxylate Category 2 Target Organ Systemic Toxicant - Single exposure Not classified according to GHS criteria Target Organ Systemic Toxicant - Repeated exposure •Inhalation Respiratory system Carbon black, Titanium dioxide Aspiration toxicity Not classified according to GHS criteria Numerical measures of toxicity (acute toxicity estimation (ATE),etc. ):No information available. Symptoms related to the physical, chemical and toxicological characteristics: Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Whether the hazardous chemical is listed by NTP, IARC or OSHA: Titanium dioxide IARC 2B Ethylbenzene IARC 2B Carbon black IARC 2B 12. ECOLOGICAL INFORMATION There are no data available on the product itself. The product should not be allowed to enter drains or watercourses. Creation date: 2018-04-10 Page 7 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en 13. DISPOSAL CONSIDERATIONS Waste Disposal Method:Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with Federal, State, Provincial, and local requirements. Do not incinerate in closed containers. 14. TRANSPORT INFORMATION International transport regulations IMDG (Sea transport) UN number: 1263 Proper shipping name: PAINT Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II Marine Pollutant: no EmS: F-E,S-E ICAO/IATA (Air transport) UN number: 1263 Proper shipping name: PAINT Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II DOT UN number: 1263 Proper shipping name: PAINT Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II Marine Pollutant: no The transport information is for bulk shipments. Exceptions may apply for smaller containers. Matters needing attention for transportation:Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with the relevant statutes and rules. 15. REGULATORY INFORMATION TSCA Status:In compliance with TSCA Inventory requirements for commercial purposes. DSL Status:All components of the mixture are listed on the DSL. Photochemical Reactivity:Photochemically reactive Creation date: 2018-04-10 Page 8 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en Regulatory information: —————— EPCRA —————– CERCLA CAA CAS # Ingredient 302 TPQ RQ 311/312 313 RQ(lbs) HAP 1330-20-7 Xylene N NR NR A,C,F,N,P,R Y 100 Y 13463-67-7 Titanium dioxide N NR NR A N NR N 123-86-4 Butyl acetate N NR NR A,C,F N NR N 78-93-3 Methyl ethyl ketone N NR NR A,C,F N 5,000 N 108-65-6 Propylene glycol monomethyl ether acetate NNRNR F N NRN 100-41-4 Ethylbenzene N NR NR A,C,F Y 1,000 Y 110-12-3 Methyl isoamyl ketone N NR NR C N NR N 136-53-8 Zinc carboxylate N NR NR A,C,F,N,P,R Y NR N 1333-86-4 Carbon black N NR NR C N NR N 16. OTHER INFORMATION HMIS rating:H:2;F:3;R:0 Glossary of Terms ACGIH American Conference of Governmental Industrial Hygienists. IARC International Agency for Research on Cancer. NTP National Toxicology Program. OEL Occupational Exposure Limit OSHA Occupational Safety and Health Administration. STEL Short term exposure limit TWA Time-weighted average. PNOR Particles not otherwise regulated. PNOC Particles not otherwise classified. EPCRA Emergency Planning and Community Right-to-know Act (aka Title III, SARA) 302 Extremely hazardous substances 311/312 Categories F = Fire Hazard A = Acute Hazard R = Reactivity Hazard C = Chronic Hazard P = Pressure Related Hazard 313 Information Section 313 Supplier Notification - The chemicals listed above with a ’Y’ in the 313 column are subject to reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know act of 1986 and of 40 CFR 372. CERCLA Comprehensive Emergency Response, Compensation and Liability Act of 1980. HAP Listed as a Clean Air Act Hazardous Air Pollutant. TPQ Threshold Planning Quantity. RQ Reportable Quantity NA not available NR not regulated NOTE: The list (above) of glossary terms may be modified. Creation date: 2018-04-10 Page 9 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-200 Version: 4.1 US - en Information is accurate and subject to change as new information is received. The information on this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. SDS Prepared by Regulatory Affairs Report version Version:4.1 Changes: Revision Date:2018-03-19 Creation date: 2018-04-10 Page 10 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product name 6SFUIBOF1SJNFS4VSGBDFS"DUJWBUPS "DUJWBUPSGPS5&, Product code 34-202 Formula date 2015-10-01 Recommended use Hardener for professional use Responsible party National Coatings and Supplies 4900 Falls of Neuse Road Suite 150 Raleigh, NC 27609 Telephone Product information 866-529-1682 Medical emergency 800-424-9300 Transportation emergency 800-424-9300 2. HAZARDS IDENTIFICATION GHS-Classification Flammable liquids, Category 2 ; Skin corrosion/irritation, Category 2 ; Serious eye damage/eye irritation, Category 2A ; Respiratory sensitisation, Category 1 ; Skin sensitisation, Category 1 ; Carcinogenicity, Category 2 ; Toxicity for reproduction, Category2;TargetOrganSystemic Toxicant - Single exposure, Category3;TargetOrganSystemic Toxicant - Repeated exposure, Category 2 GHS-Labelling Hazard symbols: Signal word: Danger Hazard statements:Highly flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Precautionary statements:Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see supplemental first aid instructions on this label). If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local regulations. Creation date: 2018-04-10 Page 1 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en Other hazards which do not result in classification Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: 0% 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture of synthetic resins and solvents Components CAS-No. Chemical name Concentration 100-41-4 Ethylbenzene 6.1% 108-88-3 Toluene 7% 123-86-4 Butyl acetate 1 - 4% 1330-20-7 Xylene 24% 141-78-6 Ethyl acetate 15 - 26% 28182-81-2 Aliphatic polyisocyanate resin 26 - 37% 4083-64-1 P-toluenesulfonyl isocyanate 0.1 - 1.0% 78-93-3 Methyl ethyl ketone 1 - 4% Any concentration shown as a range is due to batch variation. Non-regulated ingredients 1 - 5% OSHA Hazardous: Yes 4. FIRST AID MEASURES Eye contact:Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical advice. Skin contact:Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use recognized skin cleanser. If skin irritation persists, call a physician. Inhalation:Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. Ingestion:If swallowed, seek medical advice immediately and show this safety data sheet (SDS) or product label. Do NOT induce vomiting. Keep at rest. Most Important Symptoms/effects, acute and delayed Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for Creation date: 2018-04-10 Page 2 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Ingestion:May result in gastrointestinal distress. Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. Skin contact my cause skin sensitization. Indication of Immediate medical attention and special treatment needed if necessary:No data available on the product. See section 3 and 11 for hazardous ingredients found in the product. 5. FIREFIGHTING MEASURES Suitable extinguishing media:Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical Extinguishing media which shall not be used for safety reasons:High volume water jet Hazardous combustion products:CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section. Fire and Explosion Hazards:Flammable liquid. Vapor/air mixture will burn when an ignition source is present. Special Protective Equipment and Fire Fighting Procedures:Full protective flameproof clothing should be worn as appropriate. Wear self-contained breathing apparatus for firefighting if necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or public waterways. 6. ACCIDENTAL RELEASE MEASURES Procedures for cleaning up spills or leaks:Ventilate area. Remove sources of ignition. Do not breathe vapors. Do not get in eyes or on skin. Wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection, gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit at least 10 minutes. Typical decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TM 10) and 80% Water OR 0-10% Ammonia, 2-5% Detergent and Water (balance) Confine and remove with inert absorbent. Pressure can be generated. Do not seal waste containers for 48 hours to allow C02 to vent. After 48 hours, material may be sealed and disposed of properly. Environmental precautions:Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers, lakes or waste water systems. 7. HANDLING AND STORAGE Precautions for safe handling:Observe label precautions. Keep away from heat, sparks, flame, static discharge and other sources of ignition. VAPORS MAY CAUSE FLASH FIRE. Close container after each use. Ground containers when pouring. Do not transfer contents to bottles or unlabeled containers. Wash thoroughly after handling and before eating or smoking. Do not store above 49 ◦C (120 ◦F). If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation, and gloves. Combustible dust clouds may be created where operations produce fine material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds. Build up of fine material should be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods (e.g. compressed air) which can generate potentially combustible dust clouds should not be used. Creation date: 2018-04-10 Page 3 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en Advice on protection against fire and explosion:Solvent vapours are heavier than air and may spread along floors. Vapors may form explosive mixtures with air and will burn when an ignition source is present. Always keep in containers of same material as the original one. Never use pressure to empty container: container is not a pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards. Storage Requirements for storage areas and containers:Observe label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Advice on common storage:Store separately from oxidizing agents, strongly alkaline and strongly acidic materials, amines, alcohols and water. Precautions should be taken to avoid exposure to atmospheric humidity or water. Evolution of CO2 in closed containers causes overpressure and produces a risk of bursting. Additional information on storage conditions:Precautions should be taken to avoid exposure to atmospheric humidity or water. Humid air and/or water will produce carbon dioxide which will pressurize the container. Open drum carefully as content may be under pressure. OSHA/NFPA Storage Classification: IB 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls and work practices:Provide adequate ventilation. National occupational exposure limits CAS-No. Chemical name Source Time Type Value Note 1330-20-7 Xylene ACGIH 15 min STEL 150 ppm ACGIH 8 hr TWA 100 ppm OSHA 8 hr TWA 100 ppm 141-78-6 Ethyl acetate ACGIH 8 hr TWA 400 ppm OSHA 8 hr TWA 400 ppm 108-88-3 Toluene OSHA CEIL 300 ppm OSHA 10 min TWA 500 ppm OSHA 8 hr TWA 200 ppm 100-41-4 Ethylbenzene ACGIH 8 hr TWA 20 ppm OSHA 8 hr TWA 100 ppm 123-86-4 Butyl acetate ACGIH 15 min STEL 200 ppm ACGIH 8 hr TWA 150 ppm OSHA 8 hr TWA 150 ppm 78-93-3 Methyl ethyl ketone ACGIH 8 hr TWA 200 ppm OSHA 8 hr TWA 200 ppm Glossary CEIL Ceiling exposure limit STEL Short term exposure limit TL Threshold limits TLV Threshold Limit Value TWA Time weighted average TWAE Time-Weighted Average Protective equipment:Personal protective equipment should be worn to prevent contact with eyes, skin or clothing. Respiratory protection:Do not breathe vapors or mists. Wear a positive-pressure, supplied air respirator (NIOSH approved TC-19C), while mixing activator with paint, during application and until all vapors and spray mists are exhausted. Follow respirator manufacturer s directions for respirator use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label instructions for further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates should not use or be exposed to vapor or spray mist. Creation date: 2018-04-10 Page 4 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en Eye protection:Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash guard or side shields. Skin and body protection:Neoprene gloves and coveralls are recommended. Hygiene measures:Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Environmental exposure controls:Do not let product enter drains. For ecological information, refer to Ecological Information Section 12. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form:liquid Colour:clear Odour:Characteristic Paint Odor Flash point 38◦F Lower Explosive Limit 1% Upper Explosive Limit 11.4 % Evaporation rate Slower than Ether Vapor pressure of principal solvent 29.1 hPa Water solubility moderate Vapor density of principal solvent (Air = 1)3.7 Approx. Boiling Range 70◦C Approx. Freezing Range Not applicable. Gallon Weight (lbs/gal)8.01 Specific Gravity 0.96 Percent Volatile By Volume 71.74% Percent Volatile By Weight 65.57% Percent Solids By Volume 28.26% Percent Solids By Weight 34.43% pH (waterborne systems only)Not applicable Partition coefficient: n-octanol/water No data available Ignition temperature 404◦C DIN 51794 Decomposition temperature Not applicable. Viscosity (23 ◦C)Not applicable. ISO 2431-1993 VOC* less exempt (lbs/gal)5.3 VOC* as packaged (lbs/gal)5.3 * VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of manufacture. 10. STABILITY AND REACTIVITY Stability:Stable Conditions to avoid:Stable under recommended storage and handling conditions (see section 7). Materials to avoid:Keep away from oxidizing agents and strongly acid or alkaline materials. Amines and alcohols cause exothermic reactions. Mixture reacts slowly with water resulting in evolution of CO2. Evolution of CO2 in closed Creation date: 2018-04-10 Page 5 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en containers causes overpressure and produces a risk of bursting. Hazardous decomposition products:When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, oxides of nitrogen as well as hydrogen cyanide, amines, alcohols and water. Hazardous Polymerization:Will not occur. Sensitivity to Static Discharge:Solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product. Sensitivity to Mechanical Impact:None known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Ingestion:May result in gastrointestinal distress. Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. Delayed and immediate effects and also chronic effects from short and long term exposure: Acute oral toxicity not hazardous Acute dermal toxicity Not classified according to GHS criteria Acute inhalation toxicity Not classified according to GHS criteria % of unknown composition: 0 % Skin corrosion/irritation Xylene Category 2 Ethyl acetate Category 3 Toluene Category 2 Ethylbenzene Category 2 Butyl acetate Category 3 Methyl ethyl ketone Category 3 P-toluenesulfonyl isocyanate Category 2 Serious eye damage/eye irritation Xylene Category 2A Ethyl acetate Category 2A Creation date: 2018-04-10 Page 6 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en Methyl ethyl ketone Category 2A P-toluenesulfonyl isocyanate Category 2A Respiratory sensitisation P-toluenesulfonyl isocyanate Category 1 Skin sensitisation Aliphatic polyisocyanate resin Category 1 Germ cell mutagenicity Not classified according to GHS criteria Carcinogenicity Ethylbenzene Category 2 Toxicity for reproduction Toluene Category 2 Target Organ Systemic Toxicant - Single exposure •Inhalation Narcotic effects Ethyl acetate Respiratory system Aliphatic polyisocyanate resin Target Organ Systemic Toxicant - Repeated exposure No data available. Aspiration toxicity Not classified according to GHS criteria Numerical measures of toxicity (acute toxicity estimation (ATE),etc. ):No information available. Symptoms related to the physical, chemical and toxicological characteristics: Based on the properties of the isocyanate components and considering toxicological data on similar products, the following applies: This formulation may cause acute irritation and/or sensitization of the respiratory system leading to an asthmatic condition, wheeziness and a tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Components of the product may be absorbed into the body through the skin. Whether the hazardous chemical is listed by NTP, IARC or OSHA: Ethylbenzene IARC 2B 12. ECOLOGICAL INFORMATION There are no data available on the product itself. The product should not be allowed to enter drains or watercourses. Creation date: 2018-04-10 Page 7 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en 13. DISPOSAL CONSIDERATIONS Waste Disposal Method:Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with Federal, State, Provincial, and local requirements. Do not incinerate in closed containers. 14. TRANSPORT INFORMATION International transport regulations IMDG (Sea transport) UN number: 1263 Proper shipping name: PAINT RELATED MATERIAL Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II Marine Pollutant: no EmS: F-E,S-E ICAO/IATA (Air transport) UN number: 1263 Proper shipping name: PAINT RELATED MATERIAL Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II DOT UN number: 1263 Proper shipping name: PAINT RELATED MATERIAL Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II Marine Pollutant: no The transport information is for bulk shipments. Exceptions may apply for smaller containers. Matters needing attention for transportation:Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with the relevant statutes and rules. 15. REGULATORY INFORMATION Creation date: 2018-04-10 Page 8 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en TSCA Status:In compliance with TSCA Inventory requirements for commercial purposes. DSL Status:All components of the mixture are listed on the DSL. Photochemical Reactivity:Photochemically reactive Regulatory information: —————— EPCRA —————– CERCLA CAA CAS # Ingredient 302 TPQ RQ 311/312 313 RQ(lbs) HAP 28182-81-2 Aliphatic polyisocyanate resin N NR NR A,C,R N NR N 1330-20-7 Xylene N NR NR A,C,F,N,P,R Y 100 Y 141-78-6 Ethyl acetate N NR NR C,F N NR N 108-88-3 Toluene N NR NR A,C,F Y 1,000 Y 100-41-4 Ethylbenzene N NR NR A,C,F Y 1,000 Y 123-86-4 Butyl acetate N NR NR A,C,F N NR N 78-93-3 Methyl ethyl ketone N NR NR A,C,F N 5,000 N 4083-64-1 P-toluenesulfonyl iso- cyanate N NR NR A,C,R N NR N 16. OTHER INFORMATION HMIS rating:H:3;F:3;R:1 Glossary of Terms ACGIH American Conference of Governmental Industrial Hygienists. IARC International Agency for Research on Cancer. NTP National Toxicology Program. OEL Occupational Exposure Limit OSHA Occupational Safety and Health Administration. STEL Short term exposure limit TWA Time-weighted average. PNOR Particles not otherwise regulated. PNOC Particles not otherwise classified. EPCRA Emergency Planning and Community Right-to-know Act (aka Title III, SARA) 302 Extremely hazardous substances 311/312 Categories F = Fire Hazard A = Acute Hazard R = Reactivity Hazard C = Chronic Hazard P = Pressure Related Hazard 313 Information Section 313 Supplier Notification - The chemicals listed above with a ’Y’ in the 313 column are subject to reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know act of 1986 and of 40 CFR 372. CERCLA Comprehensive Emergency Response, Compensation and Liability Act of 1980. HAP Listed as a Clean Air Act Hazardous Air Pollutant. TPQ Threshold Planning Quantity. Creation date: 2018-04-10 Page 9 of 10 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET 34-202 Version: 5.0 US - en RQ Reportable Quantity NA not available NR not regulated NOTE: The list (above) of glossary terms may be modified. Information is accurate and subject to change as new information is received. The information on this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. SDS Prepared by Regulatory Affairs Report version Version:5.0 Changes: Revision Date:2018-03-23 Creation date: 2018-04-10 Page 10 of 10 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 Christensen Arms AO Modification 9/7/23 SAFETY DATA SHEET (SDS) SDS #500 1.IDENTIFICATION Product Type: Carbon steel and low alloy steel electrodes for arc welding Product Names: E8018-B2, E9018-B3, E8018-C1, E8018-C2, E8018-C3, E10018-D2, E9018M, E11018M, E12018M, E7010-P1, E8010-P1, ER70S-2, ER70S-3, ER70S-6, ER70S-7, E70C-6M, ER70S6 (Copper free) Specifications: AWS A5.5, A5.18, A5.28 Product Intended/Recommended Use: Arc welding Manufacturer: Welding Material Sales 1340 Reed Road Geneva, IL 60134 Tel: 630-232-6421 Fax: 888-733-1512 Email: info@weldingmaterialsales.com Emergency Telephone Number: 800-424-9300 2.HAZARD IDENTIFICATION Hazard Classification: Not classified as hazardous according to the applicable Globally Harmonized System of Classification and Labelling of Chemicals (GHS) and OSHA Hazard Communication Standard (29 CFR 1910.1200) criteria. Label Elements: Hazard Symbol – None Signal Word – None Hazard Statement – Not Applicable Precautionary Statement – Not Applicable Other Hazards: This product presents no hazards in its intrinsic form. However, several hazards are generated during welding operations that can be harmful. Christensen Arms AO Modification 9/7/23 ELECTRICITY- Electric shock can kill. HEAT- Molten metal and weld spatter can burn skin and start fires. RADIATION- Arc rays can injure eyes and burn skin. FUMES AND GASES - Fumes and gases generated during welding can be dangerous to your health. See Section 11. 3.COMPOSITION/INFORMATION ON INGREDIENTS Common Name Weight % Iron 70-98 Manganese 0-4 Silicon 0-3 Silica 0-3 Aluminum 0-5 Aluminum Oxide 0-1 Chromium 0-10.0 Nickel 0-3 Niobium 0-0.3 Magnesium and compounds 0-3 Molybdenum 0-1.2 Titanium 0-0.5 Titanium Dioxide 0-10 Vanadium 0-0.3 Barium Compounds 0-10 Lithium Compounds (as Li) 0-9 Iron Oxide 0-12 Zirconium and Compounds (as Zr) 0-1 Fluorides 0-12 Graphite 0-0.5 Copper 0-0.8 4.FIRST AID MEASURES Inhalation - If breathing has stopped, immediately seek medical assistance. Begin performing cardio pulmonary resuscitation (CPR) if you are trained to do so. If breathing is difficult, move to area with fresh air and seek medical attention immediately. Skin contact - For skin burns due to arc radiation flush with cold water. If burn and irritation persists seek medical attention. In case of skin contact with fume or dust, wash affected areas with soap and water. Thoroughly clean shoes and wash clothing. Seek medical attention if irritation develops and persists. Eye contact - In case of radiation burns due to arc flash move to a dark room and seek medical attention. To remove fume or dust flush with plenty of lukewarm water. Seek medical attention if irritation develops. In case of foreign metallic or slag material lodged in the eye, seek medical attention to remove it. Do not rub or agitate the eyes. Ingestion – Although unlikely due to product form, immediately seek medical attention if wire pieces or metal powders from inside the wire are ingested. Do not induce vomiting unless directed to do so by medical personnel. Christensen Arms AO Modification 9/7/23 Electric Shock - Disconnect power. Use non-conductive material to pull victim from contact with live wires. If no detectible pulse, seek medical attention immediately and begin cardio pulmonary resuscitation (CPR) if you are trained to do so. Most Serious Symptoms: Short Term Exposure – Acute overexposure to welding fumes may result in discomfort such as irritation of the respiratory system, metal fume fever, nausea, and may aggravate pre-existing respiratory conditions. Long Term Exposure – Chronic overexposure to welding fume may lead to iron deposits in the lungs (siderosis) and reduced pulmonary function. Manganese overexposure can lead to irreversible damage to the central nervous system resulting in impaired speech and movement. Chronic overexposure to nickel fumes and hexavalent chromium can cause cancer. Some of the products contain silica quartz, but not in an inhalable fraction. Silica quartz is a listed carcinogen. Refer to Section 11 for more information. 5. FIRE FIGHTING MEASURES General - Products are non-flammable as shipped. Welding arcs and spatter can ignite nearby combustible materials. Suitable Extinguishing Media- Use methods and materials appropriate for the combustible material. Specific Hazards Arising from the Chemical - Welding arcs and spatter can ignite nearby combustible materials. General Firefighting Procedures- Keep people away. Isolate fire and deny entry to the area by any non-essential personnel. Fight fire from protected location or safe distance. Special Actions for Firefighters- Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and hazardous fumes. Toxic and irritating fumes and gases may be given off during burning or thermal decomposition. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: For Non-Emergency Personnel – Isolate the area and keep non-essential people away. Do not touch or walk through spilled material. Allow the molten metallic material to solidify and cool before disposal. If molten metal spills out of the weldment, turn off the power. Contain the flow using sand or submerged arc flux. If airborne dust and or fumes are present, wear appropriate personal protective equipment (PPE) to avoid overexposure. For Emergency Personnel – Wear appropriate personal protective equipment (PPE), including clothes, gloves and breathing protection. Evacuate non-essential personnel. Environmental Precautions: Keep material out of waterways and drains. Methods and Materials for Containment and Cleaning Up: Isolate and clean up spills immediately. Avoid generating dust or airborne particles during clean up. Dispose of solidified mass per Federal, State and Local regulations. 7. HANDLING AND STORAGE Precautions for Safe Handling: Wear safety glasses and gloves to avoid cuts and abrasion when handling welding consumables and their packaging. Do not eat drink or smoke in areas where these products are being used. Conditions for Safe Storage, Including Any Incompatibilities: Store in a cool, dry area in the original packaging. Keep products away from heat, flame and moisture. Christensen Arms AO Modification 9/7/23 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Appropriate Engineering Controls: Provide adequate ventilation and/or local exhaust at the weld station to keep fumes and gases away from the welder. Train welders and welding operators to keep their head out of the fumes. See ANSI Z49.1 “Safety in Welding, Cutting, and Allied Processes” for recommendations of safe work practices. Personal Protective Equipment: Eye/Face Protection – Wear safety glasses or goggles with appropriate side shields. Wear a helmet or face shield with an appropriate filter lens. Use protective screens to shield others in the work area. Skin/Body Protection – Wear hand, head and body protection including welder’s gloves, protective face shield and long sleeved protective clothing. Respiratory Protection – Use NIOSH approved fume respirator or air supplied respirator when where ventilation is inadequate, welding in confined spaces or where required to by OSHA regulations. Fume sampling per AWS F1.1 “Method for Sampling Airborne Particulates Generated by Welding and Allied Processes” may be required. Other appropriate standards that may be considered include, but are not limited to, AWS F1.2 “Laboratory Method for Measuring Fume Generation Rate and Total Fume Emission of Welding and Allied Processes” and AWS F3.2 “Ventilation Guide for Weld Fume”. For actual weld fume and particulate analysis, refer to the appropriate analytical methods recommended by NIOSH or OSHA, and consult an industrial hygiene professional. Control Parameters: Exposure Limits - USA Common Name CAS Number Form Exposure Limit Source Aluminum Metal 7429-90-5 Total Dust 15 mg/m3 USA. OSHA PELs Total Dust 10 mg/m3 USA. California OSHA PELs Respirable 5 mg/m3 USA. OSHA PELs Respirable 1 mg/m3 USA. ACGIH TLVs Aluminum Oxide 1344-28-1 Total Dust 15 mg/m3 USA. OSHA PELs Respirable 5 mg/m3 USA. OSHA PELs Respirable 1 mg/m3 USA. ACGIH TLVs Barium Compounds 7440-39-3 Soluble Compounds 0.5 mg/m3 USA. OSHA PELs Soluble Compounds 0.5 mg/m3 USA. ACGIH TLVs Calcium Carbonate 1317-65-3 Total Dust 15 mg/m3 USA. OSHA PELs Total Dust 10 mg/m3 USA. California OSHA PELs Respirable 5 mg/m3 USA. OSHA PELs Chromium 7440-47-3 Metal 1 mg/m3 USA. OSHA PELs Metal 0.5 mg/m3 USA. ACGIH TLVs Cr II compounds 0.5 mg/m3 USA. OSHA PELs Cr III Compounds, Inorganic 0.5 mg/m3 USA. OSHA PELs Cr III Compounds, Inorganic 0.5 mg/m3 USA. ACGIH TLVs 18540-29-9 Cr VI Compounds 0.1 mg/m3 USA. OSHA PELs Ceiling Cr VI Compounds, Soluble 0.005 mg/m3 USA. OSHA PELs Christensen Arms AO Modification 9/7/23 (as Cr VI) Cr VI Compounds, Soluble 0.05 mg/m3 (as Cr) USA. ACGIH TLVs Cr VI Compounds, Insoluble 0.005 mg/m3 (as Cr VI) USA. OSHA PELs Cr VI Compounds, Insoluble 0.01 mg/m3 (as Cr) USA. ACGIH TLVs Cobalt 7440-48-4 As Metal, Dust & Fume 0.1 mg/m3 USA. OSHA PELs As Metal, Dust & Fume 0.02 mg/m3 USA. California OSHA PELs As Metal, Dust & Fume 0.02 mg/m3 USA. ACGIH TLVs Copper 7440-50-8 Dust 1 mg/m3 USA. OSHA PELs & ACGIH TLVs Fume 0.1 mg/m3 USA. OSHA PELs Fume 0.2 mg/m3 USA. ACGIH TLVs Fluorides 7789-75-5 As Fluorides 2.5 mg/m3 USA. OSHA PELs & ACGIH TLVs Iron & Iron Oxide 1309-37-1 Iron Oxide (As Fume) 10 mg/m3 USA. OSHA PELs Iron Oxide (As Fume) 5 mg/m3 USA. California OSHA PELs Respirable 5 mg/m3 USA. ACGIH TLVs Graphite 7782-42-5 Total Dust 15 mg/m3 USA. OSHA PELs Total Dust 10 mg/m3 USA. California OSHA PELs Respirable 5 mg/m3 USA. OSHA PELs Respirable 2 mg/m3 USA. ACGIH TLVs Magnesite 546-93-0 Total Dust 15 mg/m3 USA. OSHA PELs Total Dust 10 mg/m3 USA. California OSHA PELs Total Dust 10 mg/m3 USA. ACGIH TLVs Respirable 5 mg/m3 USA. OSHA PELs Respirable 2 mg/m3 USA. ACGIH TLVs Magnesium Oxide 1309-48-4 Fume 15 mg/m3 USA. OSHA PELs Fume 10 mg/m3 USA. California OSHA PELs Fume (Inhalable) 10 mg/m3 USA. ACGIH TLVs Manganese & Mn Compounds 7439-96-5 Fume 5 mg/m3 USA. OSHA PELs Ceiling Fume 0.2 mg/m3 USA. California OSHA PELs Fume (Respirable) 0.02 mg/m3 USA. ACGIH TLVs Fume (Inhalable) 0.1 mg/m3 USA. ACGIH TLVs Inorganic 5 mg/m3 USA. OSHA PELs Ceiling Inorganic 0.2 mg/m3 USA. California OSHA PELs Inorganic (Respirable) 0.02 mg/m3 USA. ACGIH TLVs Inorganic (Inhalable) 0.1 mg/m3 USA. ACGIH TLVs Molybdenum 7439-98-7 Soluble Compounds 5 mg/m3 USA. OSHA PELs Soluble Compounds (Respirable) 0.5 mg/m3 USA. ACGIH TLVs Insoluble compounds (Total Dust) 15 mg/m3 USA. OSHA PELs Insoluble compounds (Total Dust) 10 mg/m3 USA. California OSHA PELs Insoluble compounds (Respirable) 3 mg/m3 USA. ACGIH TLVs & California OSHA PELs Christensen Arms AO Modification 9/7/23 Insoluble compounds (Inhalable) 10 mg/m3 USA. ACGIH TLVs Nickel 7440-02-0 Metal 1 mg/m3 USA. OSHA PELs Metal (Inhalable) 1.5 mg/m3 USA. ACGIH TLVs Metal 0.015 mg/m3 USA. NIOSH RELs Soluble Compounds 1 mg/m3 USA. OSHA PELs Soluble Compounds (Inorganic) 0.1 mg/m3 USA. ACGIH TLVs Insoluble Compounds 1 mg/m3 USA. OSHA PELs Insoluble Compounds (Inorganic) 0.2 mg/m3 USA. ACGIH TLVs Potassium Silicate 1312-76-1 Total 10 mg/m3 USA. ACGIH TLVs Sodium Silicate 1344-09-8 Total 10 mg/m3 USA. ACGIH TLVs Silicon 7440-21-3 Total Dust 15 mg/m3 USA. OSHA PELs Total Dust 10 mg/m3 USA. California OSHA PELs Respirable 5 mg/m3 USA. OSHA PELs Silica (Quartz) 14808-60-7 Respirable 0.1 mg/m3 USA. OSHA PELs Respirable 0.025 mg/m3 USA. ACGIH TLVs Total Dust 0.3 mg/m3 USA. OSHA PELs Titanium Dioxide 13463-67-7 Total Dust 15 mg/m3 USA. OSHA PELs Total Dust 10 mg/m3 USA. ACGIH TLVs Tungsten 7440-33-7 Insoluble 5.0 mg/m3 USA. ACGIH TLVs Insoluble 10.0 mg/m3 USA. ACGIH TLVs Ceiling Soluble 1.0 mg/m3 USA. ACGIH TLVs Soluble 3.0 mg/m3 USA. ACGIH TLVs Ceiling Vanadium 7440-62-2 Oxide Dust 0.5 mg/m3 USA. OSHA PELs Ceiling Oxide Dust (Inhalable) 0.05 mg/m3 USA. ACGIH TLVs & California OSHA PELs Oxide Fume 0.1 mg/m3 USA. OSHA PELs Ceiling Oxide Fume (Inhalable) 0.05 mg/m3 USA. ACGIH TLVs & California OSHA PELs Zirconium & Zr Compounds 7440-67-7 Metal 5 mg/m3 USA. ACGIH TLVs Metal 10 mg/m3 USA. ACGIH TLVs Ceiling Compound 5 mg/m3 USA. OSHA PELs Compound 5 mg/m3 USA. ACGIH TLVs Compound 10 mg/m3 USA. ACGIH TLVs Ceiling Exposure Limits – Canada Common Name CAS Number Form Exposure Limit Source Calcium Carbonate 1317-65-3 Total Dust 10 mg/m3 Canada. Alberta OEL TWA Total Dust 20 mg/m3 Canada. British Columbia OEL TWA STEL Total Dust 10 mg/m3 Canada. British Columbia OEL TWA Respirable 3 mg/m3 Canada. British Columbia OEL TWA Christensen Arms AO Modification 9/7/23 Total Dust 10 mg/m3 Canada. Saskatchewan OEL for 8hr ACL Total Dust 20 mg/m3 Canada. Saskatchewan OEL for 15min ACL Total Dust 10 mg/m3 Canada. Quebec OEL TWA Manganese & Mn Compounds 7439-96-5 As Mn 0.2 mg/m3 Canada. Alberta OEL TWA As Mn 0.2 mg/m3 Canada. British Columbia OEL TWA As Mn (Inhalable) 0.1 mg/m3 Canada. Manitoba OEL TWA As Mn (Respirable) 0.02 mg/m3 Canada. Manitoba OEL TWA As Mn 0.2 mg/m3 Canada. New Brunswick OEL TWA As Mn 0.1 mg/m3 Canada. Newfoundland & Labrador OEL TWA As Mn 0.1 mg/m3 Canada. Nova Scotia OEL TWA As Mn 1 mg/m3 Canada. Nunavut OEL TWA As Mn 3 mg/m3 Canada. Nunavut OEL STEL As Mn 5 mg/m3 Canada. Nunavut OEL Ceiling As Mn 1 mg/m3 Canada. Northwest Territories OEL TWA As Mn 3 mg/m3 Canada. Northwest Territories OEL STEL As Mn 5 mg/m3 Canada. Northwest Territories OEL Ceiling As Mn 0.2 mg/m3 Canada. Ontario OEL TWA As Mn 0.2 mg/m3 Canada. Prince Edward Island OEL TWA As Mn 0.2 mg/m3 Canada. Quebec OEL TWA As Mn 0.2 mg/m3 Canada. Saskatchewan OEL TWA As Mn 0.6 mg/m3 Canada. Saskatchewan OEL STEL As Mn 5 mg/m3 Canada. Yukon OEL Ceiling Silicon 7440-21-3 Total Dust 10 mg/m3 Canada. British Columbia OEL TWA Total Dust 3 mg/m3 Canada. New Brunswick OEL TWA Total Dust 10 mg/m3 Canada. Nunavut OEL TWA Total Dust 10 mg/m3 Canada. Northwest Territories OEL TWA Total Dust 10 mg/m3 Canada. Ontario OEL TWA Total Dust 10 mg/m3 Canada. Quebec OEL TWA Total Dust 10 mg/m3 Canada. Saskatchewan OEL TWA Total Dust 20 mg/m3 Canada. Saskatchewan OEL STEL Total Dust 10 mg/m3 Canada. Yukon OEL TWA Total Dust 20 mg/m3 Canada. Yukon OEL STEL Silica (Quartz) 14808-60-7 Respirable Fraction 0.025 mg/m3 Canada. Alberta OEL TWA Respirable Fraction 0.025 mg/m3 Canada. British Columbia OEL TWA Respirable Fraction 0.025 mg/m3 Canada. Manitoba OEL TWA Respirable Fraction 0.1 mg/m3 Canada. Ontario OEL TWA Respirable Fraction 0.05 mg/m3 Canada. Quebec OEL TWA Respirable Fraction 0.1 mg/m3 Canada. Saskatchewan OEL TWA Titanium Dioxide 13463-67-7 Total Dust 10 mg/m3 Canada. Alberta OEL TWA Dust (Respirable) 3 mg/m3 Canada. British Columbia OEL TWA Christensen Arms AO Modification 9/7/23 Total Dust 10 mg/m3 Canada. British Columbia OEL TWA Total Dust 10 mg/m3 Canada. Manitoba OEL TWA Total Dust 10 mg/m3 Canada. Ontario OEL TWA Total Dust 10 mg/m3 Canada. Quebec OEL TWA Total Dust 10 mg/m3 Canada. Saskatchewan OEL TWA Total Dust 20 mg/m3 Canada. Saskatchewan OEL STEL Exposure Limits – Mexico Common Name CAS Number Form Exposure Limit Source Calcium Carbonate 1317-65-3 Total Dust 20 mg/m3 Mexico. OEL CTT Total Dust 10 mg/m3 Mexico. OEL CPT Manganese & Mn Compounds 7439-96-5 As Mn 0.2 mg/m3 Mexico. OEL CPT As Mn Fume 1.0 mg/m3 Mexico. OEL CPT As Mn Fume 3.0 mg/m3 Mexico. OEL CTT Silicon 7440-21-3 Total Dust 10 mg/m3 Mexico. OEL CPT Total Dust 20 mg/m3 Mexico. OEL CTT Silica 69012-46-2 Fume 10 mg/m3 Mexico. OEL CPT Fume (Respirable) 3 mg/m3 Mexico. OEL CPT Silica (Quartz) 14808-60-7 Respirable Fraction 0.1 mg/m3 Mexico. OEL CPT Titanium Dioxide 13463-67-7 Total Dust 20 mg/m3 Mexico. OEL CTT Total Dust 10 mg/m3 Mexico. OEL CPT 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Solid or tubular wire Color: Various Odor: None Odor threshold: Not Applicable pH: Not Applicable Melting point >2000F (1100C) Initial Boiling Point & Range: Data Not Available Flash point Data Not Available Evaporation rate Data Not Available Flammability Data Not Available Upper flammability/explosive limit: Data Not Available Lower flammability/explosive limit: Data Not Available Vapor pressure Not Applicable Vapor density: Not Applicable Relative density 0.2-0.3 lbs/in3 Solubility in water Data Not Available Solubility (other) Data Not Available Partition coefficient Data Not Available Auto-ignition temperature Data Not Available Decomposition temperature: Data Not Available Viscosity : Data Not Available Christensen Arms AO Modification 9/7/23 10. STABILITY AND REACTIVITY Reactivity – This product is not reactive under normal conditions as shipped. Chemical stability – This product is chemically stable under normal conditions as shipped. Possibility of hazardous reactions – Polymerization reactions will not occur. Conditions to avoid – Protect product from moisture and contamination. Incompatible materials – Data not available Hazardous decomposition products – Welding electrodes and wires emit fumes and gases when used under normal conditions. These fumes and gases produced during welding operations cannot be easily classified, and will differ in quantity and form from those ingredients listed in Section 3 of this SDS. The composition and quantity of these fumes and gases are directly dependent upon the metal being welded, any material coatings (such as primer or galvanizing), the welding process, the welding consumables and the welding procedures. Other conditions which also influence the composition and quantity of the fumes and gases produced include the number of welders in the work area, the volume of the work area, the quality and amount of ventilation or exhaust, and the proximity of the welder’s head to the fume plume. Decomposition products of welding consumables under normal operation include oxides of elements present in the welding consumable and base material. Manganese compounds may be present in the fume from manganese bearing electrodes. Hexavalent chromium may be present in the fume from electrodes containing chromium. Nickel compounds may be present in the fume from nickel bearing electrodes. Fluoride containing consumables may generate gaseous and particulate fluoride. Gases such as carbon monoxide, carbon dioxide, ozone and nitrogen oxides may also be produced in the arc area. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure: Oral – Unknown health effects, but this exposure is unlikely to occur. Inhalation – Inhalation of welding fumes may lead to acute and/or chronic health hazards (see table below). Skin –Arc rays can burn the skin. Weld fume deposited on the skin may cause irritation (see table below). Eye – Arc rays can injure the eyes. Weld fume contact with the eyes may cause irritation (see table below). Information on toxicological effects: The acute and chronic effects of compounds which may be exposed to the welder are listed in the table below. Also listed are the available measured values of toxicity for that substance and whether is it classified as carcinogenic. Substance Short-Term Exposure Effects Long Term Exposure Effects Toxicity Measure Carcinogenicity Aluminium Oxide May cause eye & respiratory irritation. May cause effects on central nervous system. LC50 (Rat, Oral Exposure) >5,000 mg/kg Not classifiable Barium Compounds May cause irritation to the nose, throat, and respiratory tract. May cause baratosis (deposits of barium in lungs). Baratosis is benign & does not progress to fibrosis. LD50 (Rat, Oral Exposure) = 418 mg/kg Not classifiable Chromium as Cr+3 May cause eye, skin & respiratory irritation. May cause chronic bronchitis, sinusitus, rhinitus and ashtma. LC50 (Rat,14 day Oral Exposure) >5,000 mg/kg Not classifiable Christensen Arms AO Modification 9/7/23 Chromium as Cr+6 May cause eye, skin & respiratory irritation. May cause lung, nasal and sinus cancer, ulceration and perforation of the nasal septum and skin rash. LC50 (Rat ,Oral Exposure) = 29 mg/kg IARC-1 NTP-known OSHA Cobalt Compounds May cause respiratory irritation and cardiovascular inflammation. May cause chronic irritation, diminished pulmonary function, asthma and fibrosis. LC50 (Rat, 30 min Inhalation Exposure) = 165mg/m3 Not classifiable Substance Short-Term Exposure Effects Long Term Exposure Effects Toxicity Measure Carcinogenicity Copper Oxide May cause metal fume fever with upper respiratory irritation, chills, and aching muscles. Prolonged contact may cause skin sensitization. LD50 (Rat, Oral Exposure) = 470mg/kg Not classifiable Fluorides May cause eye, skin & respiratory irritation. May cause serious bone erosion and mottling of teeth (fluorosis). LD50 (Rat, Oral Exposure) = 31 mg/kg Not classifiable Iron Oxide May cause respiratory irritation. May cause siderosis (deposits of iron in lungs). Siderosis is benign and does not progress to fibrosis. LD50 (Rat, Oral Exposure) > 10,000 mg/kg Not classifiable Lithium Compounds May cause eye & skin irritation. May adversely affect the central nervous system & kidneys, and may be a reproductive toxin. LC50 (Rat, 4 hour Inhalation Exposure) > 2.17 mg/L Not classifiable Magnesium Oxide May cause eye & respiratory irritation. May cause decreased lung function. LD50 (Rat, Oral Exposure) = 3870 mg/kg Not classifiable Manganese Oxide May cause respiratory irritation, metal fume fever with chills, fever, upset stomach, body ache, vomiting. May cause brain and central nervous system effects resulting in arm and leg tremors, slurred speech and poor coordination. LD50 (Rat, 4 hour Inhalation Exposure) = 19 mg mg/kg Not classifiable Molybdenum May cause eye & respiratory irritation. Not found. Not found Not classifiable Nickel Oxide May cause respiratory irritant, inhalation of fumes may cause pneumonitus. Prolonged exposure may lead to asthma. Nickel refinery workers showed a higher incidence of lung and nasal cancers. LD50 (Rat, Inhalation Exposure) > 5,000 mg/kg IARC-1 NTP-known Niobium May cause respiratory irritation. Not found. Not found Not classifiable Silica May cause eye & respiratory irritation. Crystalline silica is a known carcinogen. Overexposure may also result in silicosis. Not found IARC-1 NTP-known Titanium Dioxide May cause respiratory irritation. May be carcinogenic. LD50 (Rat, Oral Exposure) > 10 g/kg IARC-2B Tungsten compounds May cause respiratory irritation. Not found. Not found Not found Vanadium Oxide May cause eye, skin & respiratory irritation. Exposure to high concentrations of fume may lead to chronic nasal hyperplasia. LD50 (Rat, Oral Eposure) =10 mg/kg Not classifiable Zirconium Oxide May cause eye & respiratory irritation. May cause decreased lung function. Not found Not classifiable Carbon Dioxide At low levels, may cause headache, dizziness, loss of coordination, nausea. At Long term exposure may affect the body’s metabolism. LC50 (Human, Inhalation Exposure) =100,000 ppm/min Not classifiable Christensen Arms AO Modification 9/7/23 high levels can cause coma and possibly death. Carbon Monoxide May cause effects on the blood, resulting in carboxyhaemoglobinemia and cardiac disorders. High levels may result in death. May have effects on the cardiovascular system and central nervous system. May cause toxicity to human reproduction or development. LC50 (Rat, 4 hour Inhalation Exposure) =1807 ppm Not classifiable Substance Short-Term Exposure Effects Long Term Exposure Effects Toxicity Measure Carcinogenicity Ozone May cause eye and respiratory tract Irritation. Inhalation may cause lung oedema. May cause effects on the central nervous system, resulting in headache and impaired performance. May cause decreased lung function. LC50 (Rat, 3 hour Inhalation Exposure) =4.5 mg/m3 Not classifiable Nitric Oxide May cause respiratory irritation. Inhalation may cause lung oedema. Exposure far above the OEL may result in death. May cause decreased lung function. LC50 (Rat, Inhalation Exposure) =160 mg/m3 Not classifiable Nitrogen Dioxide Corrosive to the skin and respiratory tract. Inhalation may cause lung oedema. Exposure far above the OEL may result in death. May cause effects on the immune system and lungs, resulting in decrease in resistance to infection. LC50 (Rat, 4 hour Inhalation Exposure) =88 ppm Not classifiable Other information on toxicological effects: Germ cell mutagenicity – Not classified Reproductive toxicity – Not classified Specific target organ toxicity (Single exposure) – Not classified Specific target organ toxicity (Repeated exposure) – Not classified Aspiration hazard – Not classified 12. ECOLOGICAL INFORMATION Toxicity: Not classified Persistence and degradability: No information available Bioaccumulative potential: No information available Mobility in soil: No information available Other adverse effects: Unknown 13. DISPOSAL CONSIDERATIONS Discard any product, residue, waste or packaging in an environmentally acceptable manner in compliance with federal, State, or local laws. Do not dispose of any waste, remaining product or by-product in the sewer. 14. TRANSPORT INFORMATION UN Number: Not regulated UN Proper Shipping Name: Not regulated Christensen Arms AO Modification 9/7/23 Transport Hazard Class: Not regulated Packing Group: Not regulated IMDG: Not regulated ICAO/IATA: Not regulated 15. REGULATORY INFORMATION U.S. Federal Regulations: Emergency Planning & Community Right-To-Know Act (EPCRA) of 1986 Section 313 Hazardous Chemicals: Aluminum, Aluminum Oxide, Barium and Barium Compounds, Chromium, Copper, Lithium Carbonate, Manganese, Nickel, Silicon & Silica, Iron & Iron Oxide, Magnesium, Zirconium and Vanadium. Superfund Amendments and Reauthorization Act of 1986 (SARA): Hazard categories – Acute (Immediate) and Chronic (Delayed) Toxic Substances Control Act (TSCA) Inventory: Iron – Listed Silicon – Listed U.S. State Laws: California Proposition 65: Titanium Dioxide – Carcinogenic Silica (Quartz) - Carcinogenic Warning: These products contain chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm. New Jersey Community Worker and Right-to-Know Act Titanium Dioxide – Listed Manganese – Listed Massachusetts Right-to-Know Act Substance List Titanium Dioxide – Listed Manganese – Listed Silica (Quartz) – Listed Pennsylvania Right-to-Know Act Hazardous Substances List Titanium Dioxide – Listed Manganese – Listed Rhode Island Right-to-Know Act Substance List Manganese – Listed Minnesota Right-to-Know Act Hazardous Substances List Titanium Dioxide – Listed Manganese – Listed Silica (Quartz) – Listed Canadian Regulations: This product is classified according to the requirements of the Canadian Controlled Products Regulations Section 33, and this SDS contains all required information. Christensen Arms AO Modification 9/7/23 16. OTHER INFORMATION DISCLAIMER: Users should take all standard and reasonable precautions when using this product for its intended use. The manufacturer does not recommend this product for any uses other than that described. The manufacturer makes no claims and provides no warranty for non-standard use. NFPA 704: HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 0 HMIS: HEALTH: 2 FLAMMABILITY: 0 PHYSICAL HAZARD: 0 SDS Revisions Preparation date: 4/12/2017 Revision date: Revision number: Note: Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, the manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will the manufacturer be responsible for damages of any nature whatsoever resulting from the use of, misuse or reliance upon information. No representations or warranties, either express or implied, or merchantability, fitness for a particular purpose or any other nature are made hereunder with respect to information or the product to which information refers. Regulatory requirements are subject to change and may differ from one location to another. It is the buyer's responsibility to ensure its activities comply with federal, State, Provincial, and local laws and regulations. Christensen Arms AO Modification 9/7/23 Christine Bodell <cbodell@utah.gov> Utah Division of Air Quality - Christensen Arms NOI 21 messages Christine Bodell <cbodell@utah.gov>Tue, Nov 19, 2024 at 8:04 AM To: thomask@christensenarms.com, macy.parchment@tetratech.com, jena.shaw@tetratech.com Good Morning, I am reviewing the NOI submitted for the Christensen Arms Gunnison Gun Manufacturing Plant in Sanpete County. The NOI states that Christensen is requesting the addition of two (2) spray booths, ten (10) blasters and two (2) dust collectors. However, per a recent Compliance Advisory (DAQC-810-24, attached), "Christensen Arms failed to submit a Notice of Intent (NOI) prior to the installation and operation of two (2) additional paint spray booths, six (6) additional abrasive blasting booths, and three (3) additional baghouses. It appears that the inspector observed one more baghouse than what is requested on the NOI. Please advise at your earliest convenience. Best, Christine -- Christine Bodell Environmental Engineer Email | cbodell@utah.gov Phone| (385) 290-2690 Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements C-810-24.pdf 397K Grace, Jena <jena.shaw@tetratech.com>Fri, Nov 22, 2024 at 8:58 AM To: Christine Bodell <cbodell@utah.gov>, "thomask@christensenarms.com" <thomask@christensenarms.com> Cc: "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, I am the consultant assisting Christensen Arms with obtaining this NOI. I believe there was just a misunderstanding on the number of dust collectors that are currently permitted. The NOI indicated that there were two unpermitted baghouses, however, in speaking with the facility, it sounds like you are correct and there are three. What needs to be done to include this additional unit in the application that was submitted? Appreciate your attention to this and the assistance! Jena You don't often get email from cbodell@utah.gov. Learn why this is important Jena L Grace, P.E. | Manager, Air Pronouns: she/her/hers Direct +1 (617) 880-1436 | jena.grace@tetratech.com Time Zone: Eastern (UTC -05.00) This message, including any attachments, may include privileged, confidential and/or inside information. Any distribution or use of this communication by anyone other than the intended recipient is strictly prohibited and may be unlawful. If you are not the intended recipient, please notify the sender by replying to this message and then delete it from your system. From: Christine Bodell <cbodell@utah.gov> Sent: Tuesday, November 19, 2024 10:05 AM To: thomask@christensenarms.com; Parchment, Macy <macy.parchment@tetratech.com>; Grace, Jena <jena.shaw@tetratech.com> Subject: Utah Division of Air Quality - Christensen Arms NOI ⚠ CAUTION: This email originated from an external sender. Verify the source before opening links or attachments. ⚠ [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Fri, Nov 22, 2024 at 11:24 AM To: "Grace, Jena" <jena.shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Please send an NOI amendment reflecting this change. Please ensure all emission estimates calculations are updated as necessary. Thank you, Christine [Quoted text hidden] Grace, Jena <jena.shaw@tetratech.com>Mon, Dec 2, 2024 at 1:22 PM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, Hope you had a nice thanksgiving! Just wanted to confirm with the NOI amendment since the emission estimation calculations will not be changing (they already include the control devices) are we ok to include only the following NOI forms: 1 , 2, 4 and 6? Thanks, [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Mon, Dec 2, 2024 at 2:57 PM To: "Grace, Jena" <jena.shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Thank you. I hope you had a great Thanksgiving holiday weekend as well. If no emissions are changing, please just send the updated forms. Thank you, Christine [Quoted text hidden] Grace, Jena <jena.shaw@tetratech.com>Tue, Dec 3, 2024 at 7:43 AM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine Thank you for the quick response! This is very helpful. We will work on getting those forms together. Thank you, Jena Jena L Grace, P.E. | Manager, Air Pronouns: she/her/hers Direct +1 (617) 880-1436 | jena.grace@tetratech.com Time Zone: Eastern (UTC -05.00) This message, including any attachments, may include privileged, confidential and/or inside information. Any distribution or use of this communication by anyone other than the intended recipient is strictly prohibited and may be unlawful. If you are not the intended recipient, please notify the sender by replying to this message and then delete it from your system. From: Christine Bodell <cbodell@utah.gov> Sent: Monday, December 2, 2024 4:58 PM To: Grace, Jena <jena.shaw@tetratech.com> Cc: thomask@christensenarms.com; Parchment, Macy <MACY.PARCHMENT@tetratech.com> Subject: Re: Utah Division of Air Quality - Christensen Arms NOI ⚠ CAUTION: This email originated from an external sender. Verify the source before opening links or attachments. ⚠ [Quoted text hidden] Grace, Jena <jena.shaw@tetratech.com>Wed, Dec 4, 2024 at 8:49 AM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, We have been working through this with the facility, however, I believe there is some confusion as to what the agency indicated was unpermitted on-site during their inspection and what the facility actually operates. In their AO (DAQE-AN160570001-22) there are two dust collectors permitted (highlighted on page 6, 7 and 8, attached). The permit indicates that the baghouse controls the abrasive and sanding operations while the permitted cyclone controls the contouring and machining areas. I have confirmed with the site, and they indicated they have only a total of four dust collectors on-site and operating, meaning that two are unpermitted at the time. They operate only one baghouse and the remaining three are cyclones with cartridge filters. The document that you provided from the inspection in August 2024 indicates there are three unpermitted baghouses. But according to the site, the two unpermitted units are cyclones. Tryingto figure out the best way to go about this. What do you need from the site to show they have only a total of four dust collectors (1 baghouse, four cyclones)? It may be easier to talk this through on the phone – please feel free to give me a call with questions. We appreciate you working with us on this. Thank you, Jena Jena L Grace, P.E. | Manager, Air Pronouns: she/her/hers Direct +1 (617) 880-1436 | jena.grace@tetratech.com Time Zone: Eastern (UTC -05.00) This message, including any attachments, may include privileged, confidential and/or inside information. Any distribution or use of this communication by anyone other than the intended recipient is strictly prohibited and may be unlawful. If you are not the intended recipient, please notify the sender by replying to this message and then delete it from your system. From: Christine Bodell <cbodell@utah.gov> Sent: Monday, December 2, 2024 4:58 PM To: Grace, Jena <jena.shaw@tetratech.com> Cc: thomask@christensenarms.com; Parchment, Macy <MACY.PARCHMENT@tetratech.com> Subject: Re: Utah Division of Air Quality - Christensen Arms NOI ⚠ CAUTION: This email originated from an external sender. Verify the source before opening links or attachments. ⚠ [Quoted text hidden] Christensen Arms AO-markup.pdf 577K Christine Bodell <cbodell@utah.gov>Wed, Dec 4, 2024 at 11:06 AM To: "Grace, Jena" <jena.shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Okay, thank you for the explanation. So Christensen is requesting the addition of two (2) cyclones to control the four (4) spray booths, and the existing two (2) dust collection systems (sanding/abrasive blasting baghouse and contouring/machining area cyclone) will remain unchanged? Thank you, Christine [Quoted text hidden] Grace, Jena <jena.shaw@tetratech.com>Wed, Dec 4, 2024 at 1:26 PM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, The two additional cyclones that Christensen is requesting approval for will be for the sanding/abrasive blasting. The currently permitted baghouse and currently permitted cyclone remain unchanged. Christensen is only requesting two new additional paint booths which have particulate filters attached to the booths. There is currently one permitted paint booth already. So, a total of three paint booths. The emissions from the paint booths do not route to the dust collection units. Hope that clears this up. [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Thu, Dec 5, 2024 at 10:43 AM To: "Grace, Jena" <jena.shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Thank you for clarifying that. The only outstanding concern I have at this time is that a 99.99% efficiency was assumed for emission estimates for abrasive blasting. Cyclone's do not typically achieve this high of a collection efficiency for particulates. However, the NOI states that the manufacturer has provided documentation suggesting this level of control. Can you please show me where this number was obtained? And lastly, are the cyclones used in series with the existing baghouse? Or are some blasting units controlled by the cyclones while others by the baghouse? Thank you, Christine [Quoted text hidden] Grace, Jena <jena.shaw@tetratech.com>Thu, Dec 5, 2024 at 2:12 PM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, Thanks for the quick response! Appreciate your patience as we work through this..the site provided me the following as the filters they order: https://www.airmaxind.com/products/airmax-amx502-premium-cartridge-filter?variant=42794176479469 Reviewing this, it appears the material is an 80/20 blend which I believe has an efficiency of closer to 85%. Sorry for the error. Is that more in line with what you would expect in a cyclone? Please let us know what you need from us to correct this. The cyclones are not used in series – some of the blasting units are controlled by the cyclones and others by baghouse as you mention below. [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Thu, Dec 5, 2024 at 2:23 PM To: "Grace, Jena" <jena.shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Thank you for checking this. Yes, 85% control sounds more reasonable. My concern is that the calculations were submitted assuming a 99.99% control efficiency for the entire blasting process. Please re-submit the calculations with the updated control efficiency, as particulates can now be expected to increase. Thank you, Christine [Quoted text hidden] Grace, Jena <jena.shaw@tetratech.com>Thu, Dec 5, 2024 at 2:42 PM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, Please see the updated emissions summary form, updated blasting calcs, and updated machining calcs using an 85% CE. Please let usknow if you need anything else. [Quoted text hidden] 3 attachments Christensen Arms Permit Mod Updated Calc-updated 20241205 - Emission Summary.pdf 72K Christensen Arms Permit Mod Updated Calc-updated 20241205-blasting.pdf 71K Christensen Arms Permit Mod Updated Calc-updated 20241205-machining.pdf 70K Grace, Jena <Jena.Shaw@tetratech.com>Fri, Dec 6, 2024 at 7:42 AM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, As a follow up to our conversations yesterday, the facility forwarded me the attached document from the manufacturer of the cartridge filter. The document states that capture efficiency will be 99.99% on 0.5 micron particles. We would like the agency to consider this documentation to verify the original calcs that used the 99.99% CE. Can you please let us know how the state will proceed? Thanks for all the help on this matter. [Quoted text hidden] Christensen Arms M2F Megabond Emissions Statement.pdf 280K Grace, Jena <Jena.Shaw@tetratech.com>Tue, Dec 10, 2024 at 7:50 AM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hi Christine, Checking in to see if there is anything further you may need from us. [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Tue, Dec 10, 2024 at 8:01 AM To: "Grace, Jena" <Jena.Shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Thank you for reaching out. I would like to ensure that the following is correct: The paint booth will be equipped with both HVLP spray guns and paint arrestor fabric filters to reduce the overspray of paint. The paint arrestor fabric filters will each have a minimum 84% particulate control efficiency. The new cyclones will control emissions from sand and media blasting operations and have a minimum particulate control efficiency of 99.9%. Please be advised that both of the above assumptions will be enforceable conditions on the updated Approval Order. Thanks, Christine [Quoted text hidden] Grace, Jena <Jena.Shaw@tetratech.com>Tue, Dec 17, 2024 at 7:31 AM To: Christine Bodell <cbodell@utah.gov> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Good morning Christine, I just confirmed with the site, and they accept the conditions below for the paint arrestor fabric filters and the control efficiency on the new cyclones. Please let us know if you have any other questions. [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Tue, Dec 17, 2024 at 10:25 AM To: "Grace, Jena" <Jena.Shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Jena, Thank you for confirming! I hope to be able to send you the draft Approval Order to review within the next 1-2 weeks. Thank you, Christine [Quoted text hidden] Christine Bodell <cbodell@utah.gov>Wed, Dec 18, 2024 at 2:51 PM To: "Grace, Jena" <Jena.Shaw@tetratech.com> Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hey Jena, I am still a little confused about the cyclone. Appendix F of the NOI has the manufacturer specs for the cyclone C-series dust collector. What model number is being used and how does the cartridge with 99.99% control efficiency factor into the cyclone? Is the air first routed through the cyclone and then the filter? Is the filter built into the cyclone? Additionally, with a 99.99% capture efficiency for 0.5-micron particles, the filter will likely have to be replaced often. What is the maintenance schedule or metric that Christensen Arms uses to determine when it needs to be replaced to ensure maximum control efficiency? Thanks, Christine [Quoted text hidden] Thomas Kubota <ThomasK@christensenarms.com>Wed, Dec 18, 2024 at 3:32 PM To: Christine Bodell <cbodell@utah.gov>, "Grace, Jena" <Jena.Shaw@tetratech.com> Cc: "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> On 3 of our 4 dust collection units the air travels through the filters that are built into the cyclone then exhausts back into the building. There is no exhaust that vents outside of the building. Each of our dust collectors have differential pressure gauges installed and they are calibrated yearly. We document the pressure readings each day for all 4 dust collectors. Even with our gauges reading between the allowed 1-6 inH20 (We have not had a reading lower than 1.7 or higher than 3.2) we still replace these filters on a yearly basis. That being said there is no risk of the 3 dust collection systems exhausting any particulates outside of our facility. Thank you, -- Tom Kubota Maintenance Manager O 435.633.4667 / M 435.469.2459 ChristensenArms.com 550 N Cemetery Road Gunnison, UT 84634 From: Chrisne Bodell <cbodell@utah.gov> Sent: Wednesday, December 18, 2024 2:51:40 PM To: Grace, Jena Cc: Thomas Kubota; Parchment, Macy [Quoted text hidden] [Quoted text hidden] EXPORT WARNING: These Commodities, Technical Data or Software are subject to the export control of either the International Traffic in Arms Regulations (ITAR) or the Export Administration Regulations (EAR) and cannot be exported without the authorization of either the Department of State or the Department of Commerce prior to export. Export includes disclosure and or access to Commodities, Technical Data or Software by Foreign Nationals whether located in the United States or Abroad. This requirement applies equally to Foreign National employees of U.S. Companies and their foreign subsidiaries. If you have received the E-Mail in error, immediately notify the sender and permanently delete all data that was received. Christine Bodell <cbodell@utah.gov>Thu, Dec 19, 2024 at 8:13 AM To: Thomas Kubota <ThomasK@christensenarms.com> Cc: "Grace, Jena" <Jena.Shaw@tetratech.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com> Hello Thomas, Thank you for the explanation. Best, Christine [Quoted text hidden]