HomeMy WebLinkAboutDAQ-2025-001471
DAQE-AN160570002-25
{{$d1 }}
Thomas Kubota
Christensen Arms
550 North Cemetery Road
Gunnison, UT 84634
thomask@christensenarms.com
Dear Mr. Kubota:
Re: Approval Order: Modification to Approval Order DAQE-AN160570001-22 to Add Two (2)
Spray Paint Booths and Ten (10) Abrasive Blasting Units
Project Number: N160570002
The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on October
23, 2024. Christensen Arms must comply with the requirements of this AO, all applicable state
requirements (R307), and Federal Standards.
The project engineer for this action is Christine Bodell, who can be contacted at (385) 290-2690 or
cbodell@utah.gov. Future correspondence on this AO should include the engineer's name as well as the
DAQE number shown on the upper right-hand corner of this letter. No public comments were received on
this action.
Sincerely,
{{$s }}
Bryce C. Bird
Director
BCB:CB:jg
cc: Central Utah Health Department
195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah
SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor
Department of
Environmental Quality
Tim Davis
Interim Executive Director
DIVISION OF AIR QUALITY
Bryce C. Bird
Director
March 19, 2025
STATE OF UTAH
Department of Environmental Quality
Division of Air Quality
{{#s=Sig_es_:signer1:signature}}
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APPROVAL ORDER
DAQE-AN160570002-25
Modification to Approval Order DAQE-AN160570001-22
to Add Two (2) Spray Paint Booths and Ten (10) Abrasive
Blasting Units
Prepared By
Christine Bodell, Engineer
(385) 290-2690
cbodell@utah.gov
Issued to
Christensen Arms - Gunnison Gun Manufacturing Plant
Issued On
{{$d2 }}
Issued By
{{$s }}
Bryce C. Bird
Director
Division of Air Quality
March 19, 2025
TABLE OF CONTENTS
TITLE/SIGNATURE PAGE ....................................................................................................... 1
GENERAL INFORMATION ...................................................................................................... 3
CONTACT/LOCATION INFORMATION ............................................................................... 3
SOURCE INFORMATION ........................................................................................................ 3
General Description ................................................................................................................ 3
NSR Classification .................................................................................................................. 3
Source Classification .............................................................................................................. 3
Applicable Federal Standards ................................................................................................. 3
Project Description.................................................................................................................. 3
SUMMARY OF EMISSIONS .................................................................................................... 4
SECTION I: GENERAL PROVISIONS .................................................................................... 4
SECTION II: PERMITTED EQUIPMENT .............................................................................. 5
SECTION II: SPECIAL PROVISIONS ..................................................................................... 6
PERMIT HISTORY ..................................................................................................................... 9
ACRONYMS ............................................................................................................................... 10
DAQE-AN160570002-25
Page 3
GENERAL INFORMATION
CONTACT/LOCATION INFORMATION
Owner Name Source Name
Christensen Arms Christensen Arms - Gunnison Gun Manufacturing Plant
Mailing Address Physical Address
550 North Cemetery Road 550 North Cemetery Road
Gunnison, UT 84634 Gunnison, UT 84634
Source Contact UTM Coordinates
Name: Thomas Kubota 430,617 m Easting
Phone: (435) 469-2459 4,335,547 m Northing
Email: thomask@christensenarms.com Datum NAD83
UTM Zone 12
SIC code 3484 (Small Arms)
SOURCE INFORMATION
General Description
Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations
consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication,
painting, assembly, and testing. Particulate emissions from contouring, machining, sanding, abrasive
blasting, and spray booths are controlled by dust collectors or filters.
NSR Classification
Minor Modification at Minor Source
Source Classification
Located in Attainment Area
Sanpete County
Airs Source Size: B
Applicable Federal Standards
None
Project Description
Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to AO
DAQE-AN160570001-22, issued March 16, 2022.
DAQE-AN160570002-25
Page 4
The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already
permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen Arms is not requesting to increase the
VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new spray booths will operate
under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing.
The ten (10) new abrasive sand blasting units will utilize two (2) cyclone dust collectors to control
emissions. The existing abrasive sand blasting unit will continue to be controlled by the baghouse already
permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase
production or use of abrasive blasting material.
While the addition of the new equipment may impact hourly emissions, production and paint usage are
not increasing. Therefore, no annual emissions are increasing.
SUMMARY OF EMISSIONS
The emissions listed below are an estimate of the total potential emissions from the source. Some
rounding of emissions is possible.
Criteria Pollutant Change (TPY) Total (TPY)
CO2 Equivalent 0 1465.00
Carbon Monoxide 0 1.12
Nitrogen Oxides 0 1.12
Particulate Matter - PM10 0 0.31
Particulate Matter - PM2.5 0 0.31
Sulfur Dioxide 0 0.01
Volatile Organic Compounds 0 11.22
Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr)
Ethyl Benzene (CAS #100414) 0 1900
Generic HAPs (CAS #GHAPS) 0 100
Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 380
Phenol (CAS #108952) 0 560
Styrene (CAS #100425) 0 5720
Toluene (CAS #108883) 0 900
Xylenes (Isomers And Mixture) (CAS #1330207) 0 2780
Change (TPY) Total (TPY)
Total HAPs 0 6.17
SECTION I: GENERAL PROVISIONS
I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in
the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions
refer to those rules. [R307-101]
I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]
DAQE-AN160570002-25
Page 5
I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon
request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8]
I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4]
I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107]
I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150]
I.8 The owner/operator shall submit documentation of the status of construction or modification
to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is
discontinued for 18 months or more. To ensure proper credit when notifying the Director, send
the documentation to the Director, attn.: NSR Section. [R307-401-18]
SECTION II: PERMITTED EQUIPMENT
II.A THE APPROVED EQUIPMENT
II.A.1 Christensen Arms Gun Manufacturing Facility II.A.2 Contouring and Machining Areas Including forty-one (41) CNC machines equipped with coolant reservoirs, hydraulic presses, rifling machines, saws, tumblers, and grinders The work areas are controlled with a cyclone
II.A.3 Various saws, tumblers, and grinders II.A.4 Fabrication of Carbon Fiber Composite Process
II.A.5 Epoxy Resin Usage and Composite Molding Process Polyurethane and epoxy resins are mixed and combined with fiberglass prior to being used in the composite molding process II.A.6 Four (4) Spray Booths (Two (2) New) Controlled with filters
DAQE-AN160570002-25
Page 6
II.A.7 Eleven (11) Abrasive Blasting Booths (Ten (10) New) Controlled with one (1) baghouse and two (2) new cyclones II.A.8 Sanding Operations Controlled with one (1) baghouse (same baghouse listed in II.A.7)
II.A.9 Welding Operations II.A.10 Firing Range
II.A.11 Misc. Natural Gas Combustion Equipment Including devices each rated less than 5 MMBtu/hr For information purposes only
SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS
II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following sources to exceed the following opacity limits: A. Any baghouse or cyclone stack - 10% opacity B. Any filter stack - 10% opacity C. All other points - 20% opacity [R307-401-8]
II.B.1.a.1 Opacity observations of visible emissions from stationary sources shall be conducted according
to 40 CFR 60, Appendix A, Method 9. [R307-401-8]
II.B.2 VOC & HAP Requirements
II.B.2.a The owner/operator shall not emit more than the following from evaporative sources (solvent
use, mold release, epoxy resin, lubricant use, adhesive, and paints) on site:
A. 11.16 tons per rolling 12-month period of VOCs
B. 0.95 tons per rolling 12-month period of ethyl benzene
C. 0.19 tons per rolling 12-month period of methyl isobutyl ketone
D. 0.28 tons per rolling 12-month period of phenol E. 2.86 tons per rolling 12-month period of styrene
F. 0.45 tons per rolling 12-month period of toluene
G. 1.39 tons per rolling 12-month period of xylene H. 6.15 tons per rolling 12-month period of all HAPs combined
[R307-401-8]
DAQE-AN160570002-25
Page 7
II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8]
II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs.
[R307-401-8]
II.B.2.a.3 The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons) [R307-401-8]
II.B.2.b The owner/operator shall install and operate a set of paint arrestor particulate filters for each paint booth to control particulate emissions. All air exiting the booths shall pass through this
control system before being vented to the atmosphere (outside building/operation). [R307-401-8]
II.B.2.c The owner/operator shall install paint arrestor particulate filters that are each certified to meet a particulate matter control efficiency of no less than 84%. [R307-401-8]
II.B.2.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed paint arrestor particulate filters.
[R307-401-8]
II.B.2.d The owner/operator shall maintain and replace the filters according to the manufacturer's instructions. [R307-401-8]
II.B.2.e The paint booths shall be equipped with HVLP spray guns to control VOC emissions.
[R307-401-8]
II.B.2.f The owner/operator shall store the VOC/HAP-containing materials in closed and air tight containers when the materials are not in use. [R307-401-8]
DAQE-AN160570002-25
Page 8
II.B.3 Sanding, Abrasive Blasting, Contouring, and Machining Operations Requirements II.B.3.a The owner/operator shall install and operate one (1) cyclone to control process streams from the
contouring and machining operations. All exhaust air from the contouring and machining operations shall be routed through the cyclone before being vented to the atmosphere. [R307-401-8]
II.B.3.b The owner/operator shall install and operate one (1) baghouse and two (2) cyclones to control process streams from the sanding and abrasive blasting operations. All exhaust air from the sanding and abrasive blasting operations shall be routed through a baghouse or cyclone before being vented to the atmosphere. [R307-401-8] II.B.3.c The owner/operator shall install a baghouse and cyclones that are each certified to meet a
particulate matter control efficiency of no less than 99.9%. [R307-401-8]
II.B.3.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed baghouse and cyclones. [R307-401-8] II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the
differential pressure across each baghouse and cyclone. [R307-401-8]
II.B.3.d.1 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8]
II.B.3.d.2 Each pressure gauge shall measure the pressure drop in 1-inch water column increments or less. [R307-401-8]
II.B.3.e During operation of each baghouse and cyclone, the owner/operator shall maintain the static pressure differential across each baghouse and cyclone between 1.0 to 6.0 inches of water column. [R307-401-8]
II.B.3.e.1 The owner/operator shall record the reading of each pressure gauge at least once per operating day. [R307-401-8]
II.B.3.e.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Weekly static pressure differential readings; C. Date of reading [R307-401-8]
II.B.3.f At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8]
II.B.3.f.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8]
DAQE-AN160570002-25
Page 9
PERMIT HISTORY
This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN160570001-22 dated March 16, 2022 Is Derived From NOI dated October 23, 2024 Incorporates Additional Information dated December 6, 2024
DAQE-AN160570002-25
Page 10
ACRONYMS
The following lists commonly used acronyms and associated translations as they apply to this document:
40 CFR Title 40 of the Code of Federal Regulations
AO Approval Order
BACT Best Available Control Technology
CAA Clean Air Act
CAAA Clean Air Act Amendments
CDS Classification Data System (used by Environmental Protection Agency to classify
sources by size/type)
CEM Continuous emissions monitor
CEMS Continuous emissions monitoring system
CFR Code of Federal Regulations
CMS Continuous monitoring system
CO Carbon monoxide
CO2 Carbon Dioxide
CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98,
Subpart A, Table A-1
COM Continuous opacity monitor
DAQ/UDAQ Division of Air Quality
DAQE This is a document tracking code for internal Division of Air Quality use
EPA Environmental Protection Agency
FDCP Fugitive dust control plan
GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i)
GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818-
12(a)
HAP or HAPs Hazardous air pollutant(s)
ITA Intent to Approve
LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent
NOx Oxides of nitrogen
NSPS New Source Performance Standard
NSR New Source Review
PM10 Particulate matter less than 10 microns in size
PM2.5 Particulate matter less than 2.5 microns in size
PSD Prevention of Significant Deterioration
PTE Potential to Emit
R307 Rules Series 307
R307-401 Rules Series 307 - Section 401
SO2 Sulfur dioxide
Title IV Title IV of the Clean Air Act
Title V Title V of the Clean Air Act
TPY Tons per year
UAC Utah Administrative Code
VOC Volatile organic compounds
DAQE-IN160570002-25
February 6, 2025
Thomas Kubota
Christensen Arms
550 North Cemetery Road
Gunnison, UT 84634
thomask@christensenarms.com
Dear Mr. Kubota:
Re: Intent to Approve: Modification to Approval Order DAQE-AN160570001-22 to Add Two (2)
Spray Paint Booths and Ten (10) Abrasive Blasting Units
Project Number: N160570002
The attached document is the Intent to Approve (ITA) for the above-referenced project. The ITA is
subject to public review. Any comments received shall be considered before an Approval Order (AO) is
issued. The Division of Air Quality is authorized to charge a fee for reimbursement of the actual costs
incurred in the issuance of an AO. An invoice will follow upon issuance of the final AO.
Future correspondence on this ITA should include the engineer's name, Christine Bodell, as well as the
DAQE number as shown on the upper right-hand corner of this letter. Christine Bodell, can be reached at
(385) 290-2690 or cbodell@utah.gov, if you have any questions.
Sincerely,
{{$s }}
Alan D. Humpherys, Manager
New Source Review Section
ADH:CB:jg
cc: Central Utah Health Department
195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah
SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor
Department of
Environmental Quality
Kimberly D. Shelley
Executive Director
DIVISION OF AIR QUALITY
Bryce C. Bird
Director
STATE OF UTAH
Department of Environmental Quality
Division of Air Quality
INTENT TO APPROVE
DAQE-IN160570002-25
Modification to Approval Order DAQE-AN160570001-22
to Add Two (2) Spray Paint Booths and Ten (10)
Abrasive Blasting Units
Prepared By
Christine Bodell, Engineer
(385) 290-2690
cbodell@utah.gov
Issued to
Christensen Arms - Gunnison Gun Manufacturing Plant
Issued On
February 6, 2025
{{$s }}
New Source Review Section Manager
Alan D. Humpherys
{{#s=Sig_es_:signer1:signature}}
TABLE OF CONTENTS
TITLE/SIGNATURE PAGE ....................................................................................................... 1
GENERAL INFORMATION ...................................................................................................... 3
CONTACT/LOCATION INFORMATION ............................................................................... 3
SOURCE INFORMATION ........................................................................................................ 3
General Description ................................................................................................................ 3
NSR Classification .................................................................................................................. 3
Source Classification .............................................................................................................. 3
Applicable Federal Standards ................................................................................................. 3
Project Description.................................................................................................................. 3
SUMMARY OF EMISSIONS .................................................................................................... 4
PUBLIC NOTICE STATEMENT............................................................................................... 4
SECTION I: GENERAL PROVISIONS .................................................................................... 5
SECTION II: PERMITTED EQUIPMENT .............................................................................. 6
SECTION II: SPECIAL PROVISIONS ..................................................................................... 7
PERMIT HISTORY ..................................................................................................................... 9
ACRONYMS ............................................................................................................................... 10
DAQE-IN160570002-25
Page 3
GENERAL INFORMATION
CONTACT/LOCATION INFORMATION
Owner Name Source Name
Christensen Arms Christensen Arms - Gunnison Gun Manufacturing Plant
Mailing Address Physical Address
550 North Cemetery Road 550 North Cemetery Road
Gunnison, UT 84634 Gunnison, UT 84634
Source Contact UTM Coordinates
Name: Thomas Kubota 430,617 m Easting
Phone: (435) 469-2459 4,335,547 m Northing
Email: thomask@christensenarms.com Datum NAD83
UTM Zone 12
SIC code 3484 (Small Arms)
SOURCE INFORMATION
General Description
Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations
consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication,
painting, assembly, and testing. Particulate emissions from contouring, machining, sanding, abrasive
blasting, and spray booths are controlled by dust collectors or filters.
NSR Classification
Minor Modification at Minor Source
Source Classification
Located in Attainment Area
Sanpete County
Airs Source Size: B
Applicable Federal Standards
None
Project Description
Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to
Approval Order DAQE-AN160570001-22, issued March 16, 2022.
DAQE-IN160570002-25
Page 4
The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already
permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen Arms is not requesting to increase the
VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new spray booths will operate
under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing.
The ten (10) new abrasive sandblasting units will utilize two (2) cyclone dust collectors to control
emissions. The existing abrasive sand blasting unit will continue to be controlled by the baghouse already
permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase
production or use of abrasive blasting material.
While the addition of the new equipment may impact hourly emissions, production and paint usage are
not increasing. Therefore, no annual emissions are increasing.
SUMMARY OF EMISSIONS
The emissions listed below are an estimate of the total potential emissions from the source. Some
rounding of emissions is possible.
Criteria Pollutant Change (TPY) Total (TPY)
CO2 Equivalent 0 1465.00
Carbon Monoxide 0 1.12
Nitrogen Oxides 0 1.12
Particulate Matter - PM10 0 0.31
Particulate Matter - PM2.5 0 0.31
Sulfur Dioxide 0 0.01
Volatile Organic Compounds 0 11.22
Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr)
Ethyl Benzene (CAS #100414) 0 1900
Generic HAPs (CAS #GHAPS) 0 100
Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 380
Phenol (CAS #108952) 0 560
Styrene (CAS #100425) 0 5720
Toluene (CAS #108883) 0 900
Xylenes (Isomers And Mixture) (CAS #1330207) 0 2780
Change (TPY) Total (TPY)
Total HAPs 0 6.17
PUBLIC NOTICE STATEMENT
The NOI for the above-referenced project has been evaluated and has been found to be consistent with the
requirements of UAC R307. Air pollution producing sources and/or their air control facilities may not be
constructed, installed, established, or modified prior to the issuance of an AO by the Director.
A 30-day public comment period will be held in accordance with UAC R307-401-7. A notification of the
intent to approve will be published in the Sanpete Messenger on February 13, 2025. During the public comment period the proposal and the evaluation of its impact on air quality will be available for the
public to review and provide comment. If anyone so requests a public hearing within 15 days of
DAQE-IN160570002-25
Page 5
publication, it will be held in accordance with UAC R307-401-7. The hearing will be held as close as
practicable to the location of the source. Any comments received during the public comment period and the hearing will be evaluated. The proposed conditions of the AO may be changed as a result of the comments received.
SECTION I: GENERAL PROVISIONS
The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO.
I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]
I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8]
I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107]
I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18]
DAQE-IN160570002-25
Page 6
SECTION II: PERMITTED EQUIPMENT
The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO.
II.A THE APPROVED EQUIPMENT II.A.1 Christensen Arms Gun Manufacturing Facility
II.A.2 Contouring and Machining Areas Including forty-one (41) CNC machines equipped with coolant reservoirs, hydraulic presses, rifling machines, saws, tumblers, and grinders The work areas are controlled with a cyclone II.A.3 Various saws, tumblers, and grinders
II.A.4 Fabrication of Carbon Fiber Composite Process II.A.5 Epoxy Resin Usage and Composite Molding Process Polyurethane and epoxy resins are mixed and combined with fiberglass prior to being used in the composite molding process
II.A.6 Four (4) Spray Booths (Two (2) New) Controlled with filters II.A.7 Eleven (11) Abrasive Blasting Booths (Ten (10) New) Controlled with one (1) baghouse and two (2) new cyclones
II.A.8 Sanding Operations Controlled with one (1) baghouse (same baghouse listed in II.A.7) II.A.9 Welding Operations
II.A.10 Firing Range II.A.11 Misc. Natural Gas Combustion Equipment Including devices each rated less than 5 MMBtu/hr For information purposes only
DAQE-IN160570002-25
Page 7
SECTION II: SPECIAL PROVISIONS
The intent is to issue an air quality AO authorizing the project with the following recommended
conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements
II.B.1.a The owner/operator shall not allow visible emissions from the following sources to exceed the following opacity limits: A. Any baghouse or cyclone stack - 10% opacity B. Any filter stack - 10% opacity C. All other points - 20% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of visible emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8]
II.B.2 VOC & HAP Requirements II.B.2.a The owner/operator shall not emit more than the following from evaporative sources (solvent use, mold release, epoxy resin, lubricant use, adhesive, and paints) on site: A. 11.16 tons per rolling 12-month period of VOCs B. 0.95 tons per rolling 12-month period of ethyl benzene C. 0.19 tons per rolling 12-month period of methyl isobutyl ketone D. 0.28 tons per rolling 12-month period of phenol E. 2.86 tons per rolling 12-month period of styrene F. 0.45 tons per rolling 12-month period of toluene G. 1.39 tons per rolling 12-month period of xylene H. 6.15 tons per rolling 12-month period of all HAPs combined. [R307-401-8]
II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8]
DAQE-IN160570002-25
Page 8
II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8]
II.B.2.a.3 The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material
B. The maximum percent by weight of VOCs and each HAP in each material used
C. The density of each material used D. The volume of each VOC- and HAP-emitting material used
E. The amount of VOCs and the amount of each HAP emitted from each material
F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material
G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons).
[R307-401-8]
II.B.2.b The owner/operator shall install and operate a set of paint arrestor particulate filters for each paint booth to control particulate emissions. All air exiting the booths shall pass through this control system before being vented to the atmosphere (outside building/operation). [R307-401-8]
II.B.2.c The owner/operator shall install paint arrestor particulate filters that are each certified to meet a
particulate matter control efficiency of no less than 84%. [R307-401-8]
II.B.2.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed paint arrestor particulate filters. [R307-401-8]
II.B.2.d The owner/operator shall maintain and replaced the filters according to the manufacturer's
instructions. [R307-401-8]
II.B.2.e The paint booths shall be equipped with HVLP spray guns to control VOC emissions. [R307-401-8] II.B.2.f The owner/operator shall store the VOC/HAP-containing materials in closed and airtight
containers when the materials are not in use. [R307-401-8]
II.B.3 Sanding, Abrasive Blasting, Contouring, and Machining Operations Requirements
II.B.3.a The owner/operator shall install and operate one (1) cyclone to control process streams from the
contouring and machining operations. All exhaust air from the contouring and machining
operations shall be routed through the cyclone before being vented to the atmosphere.
[R307-401-8]
II.B.3.b The owner/operator shall install and operate one (1) baghouse and two (2) cyclones to control process streams from the sanding and abrasive blasting operations. All exhaust air from the sanding and abrasive blasting operations shall be routed through a baghouse or cyclone before being vented to the atmosphere. [R307-401-8]
DAQE-IN160570002-25
Page 9
II.B.3.c The owner/operator shall install a baghouse and cyclones that are each certified to meet a particulate matter control efficiency of no less than 99.9%. [R307-401-8] II.B.3.c.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's emissions guarantee for the installed baghouse and cyclones. [R307-401-8]
II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the differential pressure across each baghouse and cyclone. [R307-401-8]
II.B.3.d.1 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8]
II.B.3.d.2 Each pressure gauge shall measure the pressure drop in 1-inch water column increments or less. [R307-401-8]
II.B.3.e During operation of each baghouse and cyclone, the owner/operator shall maintain the static
pressure differential across each baghouse and cyclone between 1.0 to 6.0 inches of water column. [R307-401-8]
II.B.3.e.1 The owner/operator shall record the reading of each pressure gauge at least once per operating day. [R307-401-8]
II.B.3.e.2 The owner/operator shall maintain the following records of the static pressure differential:
A. Unit identification;
B. Weekly static pressure differential readings;
C. Date of reading.
[R307-401-8]
II.B.3.f At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8]
II.B.3.f.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements.
[R307-401-8]
PERMIT HISTORY
This Approval Order shall supersede (if a modification) or will be based on the following documents:
Supersedes AO DAQE-AN160570001-22 dated March 16, 2022 Is Derived From NOI dated October 22, 2024 Incorporates Additional Information dated December 6, 2024
DAQE-IN160570002-25
Page 10
ACRONYMS
The following lists commonly used acronyms and associated translations as they apply to this document:
40 CFR Title 40 of the Code of Federal Regulations
AO Approval Order
BACT Best Available Control Technology
CAA Clean Air Act
CAAA Clean Air Act Amendments
CDS Classification Data System (used by Environmental Protection Agency to classify
sources by size/type)
CEM Continuous emissions monitor
CEMS Continuous emissions monitoring system
CFR Code of Federal Regulations
CMS Continuous monitoring system
CO Carbon monoxide
CO2 Carbon Dioxide
CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98,
Subpart A, Table A-1
COM Continuous opacity monitor
DAQ/UDAQ Division of Air Quality
DAQE This is a document tracking code for internal Division of Air Quality use
EPA Environmental Protection Agency
FDCP Fugitive dust control plan
GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i)
GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818-
12(a)
HAP or HAPs Hazardous air pollutant(s)
ITA Intent to Approve
LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent
NOx Oxides of nitrogen
NSPS New Source Performance Standard
NSR New Source Review
PM10 Particulate matter less than 10 microns in size
PM2.5 Particulate matter less than 2.5 microns in size
PSD Prevention of Significant Deterioration
PTE Potential to Emit
R307 Rules Series 307
R307-401 Rules Series 307 - Section 401
SO2 Sulfur dioxide
Title IV Title IV of the Clean Air Act
Title V Title V of the Clean Air Act
TPY Tons per year
UAC Utah Administrative Code
VOC Volatile organic compounds
Sanpete Messenger
Publication Name:
Sanpete Messenger
Publication URL:
Publication City and State:
Manti, UT
Publication County:
Sanpete
Notice Popular Keyword Category:
Notice Keywords:
Christensen Arms
Notice Authentication Number:
202502131101599157814
2892905420
Notice URL:
Back
Notice Publish Date:
Thursday, February 13, 2025
Notice Content
Utah Department of
Environmental Quality,
Division of Air Quality
NOTICE OF INTENT
A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for
consideration by the Director:
Company Name: Christensen Arms
Location: Christensen Arms - Gunnison Gun Manufacturing Plant
– 550 North Cemetery Road, Gunnison, UT
Project Description: Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete County. Operations consist of carbon
fiber and fiberglass composite manufacturing, metal and composite fabrication, painting, assembly, and testing. Particulate emissions from
contouring, machining, sanding, abrasive blasting, and spray booths are controlled by dust collectors or filters.
Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive blasting units to Approval Order (AO) DAQE-
AN160570001-22, issued March 16, 2022.
The two (2) new spray booths will be controlled by paint arrestor filters, similar to those already permitted by Equipment ID# II.A.6 in the
2022 AO. Christensen Arms is not requesting to increase the VOC and HAP limits outlined in Condition II.B.3.a of the 2022 AO. The new
spray booths will operate under the existing limitations outlined in Condition II.B.3.a. Paint usage will not be increasing.
The ten (10) new abrasive sand blasting units will utilize two (2) cyclone dust collectors to control emissions. The existing abrasive
sandblasting unit will continue to be controlled by the baghouse already permitted under Equipment ID# II.A.7 in the 2022 AO. Christensen
Arms is not requesting to increase production or use of abrasive blasting material.
While the addition of the new equipment may impact hourly emissions, production and paint usage are not increasing. Therefore, no annual
emissions are increasing.
The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air
quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period.
The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at
the
Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address
on or before March 15, 2025, will be considered in making the final decision on the approval/disapproval of the proposed project. Email
comments will also be accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this
notice, a hearing will be held in accordance with R307-401-7, UAC.
Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory
proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the
Director to fully consider the
substance and significance of the issue.
Date of Notice: February 13, 2025
Published in the Sanpete Messenger Feb. 13, 2025
Back
Jeree Greenwood <jereeg@utah.gov>
Legal Notice to be published February 13, 2025
Jeree Greenwood <jereeg@utah.gov>Thu, Feb 6, 2025 at 7:00 AM
To: Sanpete Messenger loyd <ads@sanpetemessenger.com>
Please publish the following notice on February 13, 2025. Please also send this notice to Utahlegals.com.
If you can, please reply to this email for my confirmation.
Thank you,
Jeree
--
Jeree Greenwood
Office Technician II | Minor NSR Section
M: (385) 306-6514
airquality.utah.gov
-
DAQE-NN160570002-25.pdf
323K
2/11/25, 3:28 PM State of Utah Mail - Legal Notice to be published February 13, 2025
https://mail.google.com/mail/u/0/?ik=b4fd0e1085&view=pt&search=all&permmsgid=msg-a:r-8345006825049452198&simpl=msg-a:r-83450068250494…1/1
DAQE-NN160570002-25
February 6, 2025
Sanpete Messenger
Legal Advertising Department
35 South Main Street
Manti, UT 84646
RE: Legal Notice of Intent to Approve
This letter will confirm the authorization to publish the attached NOTICE in the Sanpete Messenger on
February 13, 2025.
Please mail the invoice and affidavit of publication to the Utah State Department of Environmental
Quality, Division of Air Quality, P.O. Box 144820, Salt Lake City, Utah 84114-4820. If you have any
questions, contact Jeree Greenwood, who may be reached at (385) 306-6514.
Sincerely,
{{$s }}
Jeree Greenwood
Office Technician
Enclosure
cc: Six County Association of Governments
cc: Sanpete County
195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820
Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah
SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor
Department of
Environmental Quality
Kimberly D. Shelley
Executive Director
DIVISION OF AIR QUALITY
Bryce C. Bird
Director
DAQE-NN160570002-25
Page 2
NOTICE
A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah
Administrative Code (UAC), has been received for consideration by the Director:
Company Name: Christensen Arms
Location: Christensen Arms - Gunnison Gun Manufacturing Plant – 550 North Cemetery
Road, Gunnison, UT
Project Description: Christensen Arms operates a gun manufacturing facility in Gunnison in Sanpete
County. Operations consist of carbon fiber and fiberglass composite
manufacturing, metal and composite fabrication, painting, assembly, and testing.
Particulate emissions from contouring, machining, sanding, abrasive blasting,
and spray booths are controlled by dust collectors or filters.
Christensen Arms is requesting to add two (2) spray booths and ten (10) abrasive
blasting units to Approval Order (AO) DAQE-AN160570001-22, issued March
16, 2022.
The two (2) new spray booths will be controlled by paint arrestor filters, similar
to those already permitted by Equipment ID# II.A.6 in the 2022 AO. Christensen
Arms is not requesting to increase the VOC and HAP limits outlined in
Condition II.B.3.a of the 2022 AO. The new spray booths will operate under the
existing limitations outlined in Condition II.B.3.a. Paint usage will not be
increasing.
The ten (10) new abrasive sand blasting units will utilize two (2) cyclone dust
collectors to control emissions. The existing abrasive sandblasting unit will
continue to be controlled by the baghouse already permitted under Equipment
ID# II.A.7 in the 2022 AO. Christensen Arms is not requesting to increase
production or use of abrasive blasting material.
While the addition of the new equipment may impact hourly emissions,
production and paint usage are not increasing. Therefore, no annual emissions are
increasing.
The completed engineering evaluation and air quality impact analysis showed the proposed project meets
the requirements of federal air quality regulations and the State air quality rules. The Director intends to
issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the
effect on local air quality and draft Approval Order are available for public inspection and comment at the
Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments
received by the Division at this same address on or before March 15, 2025, will be considered in making
the final decision on the approval/disapproval of the proposed project. Email comments will also be
accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of
publication of this notice, a hearing will be held in accordance with R307-401-7, UAC.
Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or
argument during an adjudicatory proceeding that was raised during the public comment period and was
supported with sufficient information or documentation to enable the Director to fully consider the
substance and significance of the issue.
Date of Notice: February 13, 2025
{{#s=Sig_es_:signer1:signature}}
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
October 17, 2024
Utah Department of Environmental Quality (DEQ)
195 North 1950 West
Salt Lake City, UT 84116
RE: NOI AO Modification Application
Christensen Arms – Gunnison, Utah
Project No. 117-RPS220197
To whom it may concern,
On behalf of Christensen Arms, RPS Group, Inc. (dba RPS) a Tetra Tech Company is submitting a notice of
intent (NOI) for an application for a modification to approval order (AO) DAQE-AN160570001-22 for
Christensen Arms’ gun manufacturing facility located at 550 North Cemetery Road Gunnison, Utah. Operations
at the site consist of carbon fiber and fiberglass composite manufacturing, metal and composite fabrication,
painting, assembly, and testing. The facility utilizes two dust collectors to control sanding emissions. Because
the manufacturer and model information for one of the dust collectors is not available, emissions have been
conservatively calculated excluding dust control. The facility also utilizes dry filters for the paint booth. This
application encompasses administrative changes to the active AO, as well as the addition of two (2) spray
booths, ten (10) blasters and two (2) dust collectors.
This application consists of the following elements:
• Utah Department of Environmental Quality Approval Order forms
• Process Flow and Site Map
• Emission Calculations
• Best Available Control Technology (BACT) Analysis
• Manufacturer Information
Please do not hesitate to contact me with any questions regarding this application. Yours Sincerely,
RPS Group, Inc.
Macy Parchment Jena L. Grace Consultant lI Manager I, Air macy.parchment@tetratech.com jena.shaw@tetratech.com
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
Christensen Arms Gunnison, Utah NOI AO Modification Application
Table of Contents
Application
Element
Description
Page
No.
Cover letter 1
Appendix A Forms 3
Form 1 – NOI Checklist 4
Form 2 – Company Information 5
Form 4 – Project Information – Abrasive Blasting Booths 6
Form 4 – Project Information – Metal Machining 7
Form 4 – Project Information – Spray Booths 8
Form 5 – Emissions Information 9
Form 13 – Spray Booth 3 10
Form 13 – Spray Booth 4 12
Form 6 – Cyclone 2 14
Form 6 – Cyclone 3 15
Appendix B Process Flow Diagram & Site Plan 16
Appendix C Emission Calculations 20
Appendix D BACT Analysis 35
Appendix E RBLC Data Base & Supporting Documentation 40
Appendix F Manufacture Specifications 143
Appendix G Safety Data Sheets 152
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX A
Forms
Form 1 Date __________________
Notice of Intent (NOI) Application Checklist
Company __________________
Utah Division of Air Quality
New Source Review Section
Source Identification Information [R307-401-5]
1. Company name, mailing address, physical address and telephone number
2. Company contact (Name, mailing address, and telephone number)
3. Name and contact of person submitting NOI application (if different than 2)
4. Source Universal Transverse Mercator (UTM) coordinates
5. Source Standard Industrial Classification (SIC) code
6. Area designation (attainment, maintenance, or nonattainment)
7. Federal/State requirement applicability (NAAQS, NSPS, MACT, SIP, etc.)
8. Source size determination (Major, Minor, PSD)
9. Current Approval Order(s) and/or Title V Permit numbers
NOI Application Information:[R307-401]
N/A
N/A
A. Air quality analysis (air model, met data, background data, source impact analysis)N/A
Detailed description of the project and source process
Discussion of fuels, raw materials, and products consumed/produced
Description of equipment used in the process and operating schedule
Description of changes to the process, production rates, etc.
Site plan of source with building dimensions, stack parameters, etc.
Best Available Control Technology (BACT) Analysis [R307-401-8]
BACT analysis for all new and modified equipment
Emissions Related Information: [R307-401-2(b)]
Emission calculations for each new/modified unit and site-wide
(Include PM10, PM2.5, NOx, SO2, CO, VOCs, HAPs, and GHGs)
References/assumptions, SDS, for each calculation and pollutant
All speciated HAP emissions (list in lbs/hr)
Emissions Impact Analysis – Approved Modeling Protocol [R307-410]
Composition and physical characteristics of effluent
(emission rates, temperature, volume, pollutant types and concentrations)
Nonattainment/Maintenance Areas – Major NSR/Minor (offsetting only) [R307-403]
NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirements
Alternative site analysis, Major source ownership compliance certification
Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406]
Visibility impact analysis, Class I area impact N/A
Note: The Division of Air Quality will not accept documents containing confidential information or data.
Documents containing confidential information will be returned to the Source submitting the application.
1 of 1
Form 2 Date ____________
Company Information/Notice of Intent (NOI)
Utah Division of Air Quality
New Source Review Section
Application for: Initial Approval Order Approval Order Modification
General Owner and Source Information
1.Company name and mailing address:
____________________________
____________________________
____________________________
Phone No.: ( )
Fax No.: ( )
2. Company** contact for environmental matters:
____________________________
Phone no.: ( )
Email:_______________________
** Company contact only; consultant or independent contractor contact
information can be provided in a cover letter
3. Source name and physical address (if different from
above):____________________________
____________________________
____________________________
Phone no.: ( )
Fax no.: ( )
4. Source Property Universal Transverse Mercator
coordinates (UTM), including System and Datum:
UTM:_________________________
X:____________________________
Y:____________________________
5. The Source is located in:__________________ County 6.Standard Industrial Classification Code (SIC)
__ __ __ __
7. If request for modification, AO# to be modified: DAQE #__________________ DATED: ____/____/____
8. Brief (50 words or less) description of process.
Electronic NOI
9. A complete and accurate electronic NOI submitted to DAQ Permitting Mangers Jon Black (jlblack@utah.gov) or Alan
Humpherys (ahumpherys@utah.gov) can expedite review process. Please mark application type.
Hard Copy Submittal Electronic Copy Submittal
Authorization/Signature
I hereby certify that the information and data submitted in and with this application is completely true, accurate and
complete, based on reasonable inquiry made by me and to the best of my knowledge and belief.
Signature: Title:
_______________________________________
Name (Type or print)
Telephone Number:
( )
Email:
Date:
Maintenance Manager
(435)469-2459
thomask@christensenarms.com
10/18/2024
Thomas Kubota
Page 1 of 1
Form 4 Company____________________________
Project Information Site ______________________________
Utah Division of Air Quality
New Source Review Section
Process Data -For Modification/Amendment ONLY
1. Permit Number_______________________________
If submitting a new permit, then use Form 3
Requested Changes
2. Name of process to be modified/added:
_______________________________
End product of this process:
_______________________________
3. Permit Change Type: New Increase*
Equipment
Process
Condition Change ____________________
Other ______________________________
Other ______________________________
Other ______________________________
4. Does new emission unit affect existing
permitted process limits?
Yes No
5. Condition(s) Changing:
6. Description of Permit/Process Change**
7. New or modified materials and quantities used in process. **
Material Quantity Annually
8. New or modified process emitting units **
Emitting Unit(s)Capacity(s)Manufacture Date(s)
*If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an
emissions increase and a public comment period.
**If additional space is required, please generate a document to accommodate and attach to form.
Page 1 of 1
Form 4 Company____________________________
Project Information Site ______________________________
Utah Division of Air Quality
New Source Review Section
Process Data -For Modification/Amendment ONLY
1. Permit Number_______________________________
If submitting a new permit, then use Form 3
Requested Changes
2. Name of process to be modified/added:
_______________________________
End product of this process:
_______________________________
3. Permit Change Type: New Increase*
Equipment
Process
Condition Change ____________________
Other ______________________________
Other ______________________________
Other ______________________________
4. Does new emission unit affect existing
permitted process limits?
Yes No
5. Condition(s) Changing:
6. Description of Permit/Process Change**
7. New or modified materials and quantities used in process. **
Material Quantity Annually
8. New or modified process emitting units **
Emitting Unit(s)Capacity(s)Manufacture Date(s)
*If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an
emissions increase and a public comment period.
**If additional space is required, please generate a document to accommodate and attach to form.
Page 1 of 1
Form 4 Company____________________________
Project Information Site ______________________________
Utah Division of Air Quality
New Source Review Section
Process Data -For Modification/Amendment ONLY
1. Permit Number_______________________________
If submitting a new permit, then use Form 3
Requested Changes
2. Name of process to be modified/added:
_______________________________
End product of this process:
_______________________________
3. Permit Change Type: New Increase*
Equipment
Process
Condition Change ____________________
Other ______________________________
Other ______________________________
Other ______________________________
4. Does new emission unit affect existing
permitted process limits?
Yes No
5. Condition(s) Changing:
6. Description of Permit/Process Change**
7. New or modified materials and quantities used in process. **
Material Quantity Annually
8. New or modified process emitting units **
Emitting Unit(s)Capacity(s)Manufacture Date(s)
*If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an
emissions increase and a public comment period.
**If additional space is required, please generate a document to accommodate and attach to form.
two (2)
Page 1 of 1
Company___________________________
6LWH_____________________________
Form
Emissions Information
Criteria/GHGs/ HAP’s
Utah Division of Air Quality
New Source Review Section
Potential to Emit* Criteria Pollutants & GHGs
Criteria Pollutants Permitted Emissions
(tons/yr)
Emissions Increases
(tons/yr)
Proposed Emissions
(tons/yr)
PM10 Total
PM10 Fugitive
PM2.5
NOx
SO2
CO
VOC
VOC Fugitive
NH3
Greenhouse Gases CO2e CO2e CO2e
CO2
CH4
N2O
HFCs
PFCs
SF6
Total CO2e
*Potential to emit to include pollution control equipment as defined by R307-401-2.
Hazardous Air Pollutants**(**Defined in Section 112(b) of the Clean Air Act )
Hazardous Air
Pollutant***
Permitted Emissions
(tons/yr)
Emission Increase
(tons/yr)
Proposed
Emission (tons/yr)
Emission Increase
(lbs/hr)
Total HAP
*** Use additional sheets for pollutants if needed
See calculations
Christensen Arms
Gunnison, Utah
Christensen Arms NOI AO 8/641 2/26/21
Utah Division of Air Quality
New Source Review Section Company_____________________________
Site/Source___________________________
Form 13 Date ________________________________
Spray Booths
Exhaust Gas Stream Characteristics
1. Flow Rate (acfm)
Design maximum _________
Average expected _________
2. Exhaust Stack
Temperature (oF) __________
Height (ft) __________
Diameter (ft) __________
Vertically restricted? □ Yes
□No
3. Control Device Particulate
Loading (lb/hr)
Inlet _______ Outlet ________
Type of Coating and Maximum Rate of Use
4. Type Max. rate of use (lb/hr) Max. rate of use (ton/yr) Volatile portion (% weight)
lacquer
varnish
enamel
metal primer
metal spray
resin
sealer
shellac
stain
zinc chromate
epoxy
polyurethane
other
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
Solvent or Coating Composition and Rate of Use
5. Chemical composition of volatiles & wt. %
_____________________________________
_____________________________________
_____________________________________
_____________________________________
_____________________________________
6. Max. rate of use (lb/hr)
__________________________
__________________________
__________________________
__________________________
__________________________
7. Max rate of use (ton/yr)
_________________________
_________________________
_________________________
_________________________
_________________________
Page 1 of 2
Christensen Arms
See calculations
See calculations
ambient
2
9.5
1,000 cfm
Spray Booth 3
Page 2 of 2
Form 13 - Spray Booths (Continued)
Type Control Device
8. Type of pollution control device:
□ spray chamber (use gal/hr water) __________ □ water curtain (use gal/hr water) __________
□ dry filter pads (no.) __________ (size) _____X_____ □ other (explain)
□ automated replacement □ manual replacement
9. Method of spraying:
10. _______% overspray
11. ______% efficiency
□ air atomization □ disc
□ airless electrostatic □ airless
□ air-atomized □ powdered
□ other (describe)
12. Description of items to be coated (shape and size)
Emissions Calculations (PTE)
13. Calculated emissions for this device:
PM10 ___________Lbs/hr___________ Tons/yr PM2.5 ___________Lbs/hr___________ Tons/yr
VOC ___________Lbs/hr___________ Tons/yr
HAPs___________Lbs/hr (speciate)____________Tons/yr (speciate)
Submit calculations as an appendix.
Attach the following:
(1) Material Safety Data Sheet for each coating or solvent.
(2) An assembly drawing (plan and elevation) of the device dimensioned and to scale clearly showing the design size
and shape.
(3) Provide sheets showing VOC emission calculations and HAP specifications.
Instructions
NOTE: 1. Submit this form in conjunction with Form 1 and Form 2.
2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out
this form. Ask to speak with a New Source Review engineer. We will be glad to help!
1. The design maximum and average flow rate of the exhaust gas stream.
2. Exhaust stack temperature, stack height, stack diameter, and whether or not the flow is vertically restricted.
3. The amount of particulate released in the paint booth and exhaust gas in pounds per hour.
4. The type of coatings and maximum amount used in an hour and a year.
5. Chemical composition of VOCs and weight in percentage.
6. Maximum rate of use in pounds per hour.
7. Maximum rate of use in tons per year.
8. The type of control equipment you are using.
9. The method of spraying. Mark appropriate box.
10. The percent of paint that is lost in overspray.
11. The percent of efficiency for the equipment.
12. The approximate shape and size of the items being coated.
13. Supply calculations for all criteria pollutants and HAPs. Use AP42 or Manufacturers data to complete your
calculations.
U:\aq\ENGINEER\GENERIC\Forms 2010\Form13 Paint Booths.doc
Revised 12/20/10
HVLP
See calculations
85
Utah Division of Air Quality
New Source Review Section Company_____________________________
Site/Source___________________________
Form 13 Date ________________________________
Spray Booths
Exhaust Gas Stream Characteristics
1. Flow Rate (acfm)
Design maximum _________
Average expected _________
2. Exhaust Stack
Temperature (oF) __________
Height (ft) __________
Diameter (ft) __________
Vertically restricted? □ Yes
□No
3. Control Device Particulate
Loading (lb/hr)
Inlet _______ Outlet ________
Type of Coating and Maximum Rate of Use
4. Type Max. rate of use (lb/hr) Max. rate of use (ton/yr) Volatile portion (% weight)
lacquer
varnish
enamel
metal primer
metal spray
resin
sealer
shellac
stain
zinc chromate
epoxy
polyurethane
other
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
______________________
Solvent or Coating Composition and Rate of Use
5. Chemical composition of volatiles & wt. %
_____________________________________
_____________________________________
_____________________________________
_____________________________________
_____________________________________
6. Max. rate of use (lb/hr)
__________________________
__________________________
__________________________
__________________________
__________________________
7. Max rate of use (ton/yr)
_________________________
_________________________
_________________________
_________________________
_________________________
Page 1 of 2
Christensen Arms
Spray Booth 4
ambient
17
2
See calculations
See calculations
,00 cfm
Page 2 of 2
Form 13 - Spray Booths (Continued)
Type Control Device
8. Type of pollution control device:
□ spray chamber (use gal/hr water) __________ □ water curtain (use gal/hr water) __________
□ dry filter pads (no.) __________ (size) _____X_____ □ other (explain)
□ automated replacement □ manual replacement
9. Method of spraying:
10. _______% overspray
11. ______% efficiency
□ air atomization □ disc
□ airless electrostatic □ airless
□ air-atomized □ powdered
□ other (describe)
12. Description of items to be coated (shape and size)
Emissions Calculations (PTE)
13. Calculated emissions for this device:
PM10 ___________Lbs/hr___________ Tons/yr PM2.5 ___________Lbs/hr___________ Tons/yr
VOC ___________Lbs/hr___________ Tons/yr
HAPs___________Lbs/hr (speciate)____________Tons/yr (speciate)
Submit calculations as an appendix.
Attach the following:
(1) Material Safety Data Sheet for each coating or solvent.
(2) An assembly drawing (plan and elevation) of the device dimensioned and to scale clearly showing the design size
and shape.
(3) Provide sheets showing VOC emission calculations and HAP specifications.
Instructions
NOTE: 1. Submit this form in conjunction with Form 1 and Form 2.
2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out
this form. Ask to speak with a New Source Review engineer. We will be glad to help!
1. The design maximum and average flow rate of the exhaust gas stream.
2. Exhaust stack temperature, stack height, stack diameter, and whether or not the flow is vertically restricted.
3. The amount of particulate released in the paint booth and exhaust gas in pounds per hour.
4. The type of coatings and maximum amount used in an hour and a year.
5. Chemical composition of VOCs and weight in percentage.
6. Maximum rate of use in pounds per hour.
7. Maximum rate of use in tons per year.
8. The type of control equipment you are using.
9. The method of spraying. Mark appropriate box.
10. The percent of paint that is lost in overspray.
11. The percent of efficiency for the equipment.
12. The approximate shape and size of the items being coated.
13. Supply calculations for all criteria pollutants and HAPs. Use AP42 or Manufacturers data to complete your
calculations.
U:\aq\ENGINEER\GENERIC\Forms 2010\Form13 Paint Booths.doc
Revised 12/20/10
15
HVLP
See calculations
Utah Division of Air Quality
New Source Review Section Company ________________________________
Site/Source ___________
Form 6 Date ____________________________________
Cyclones
Equipment Information
1. Manufacturer: _____________________________
Model no.: ___________________
2. Type of cyclone: □ wet □ dry
□ Single □ Multiple: number ________
□ In series : number ___________
3. Type of particulate: ___________________________
Particulate size:
________________________microns
(mean geometric diameter)
4. Efficiency of cyclone:
At design maximum:______________________%
At average operation: %
5. Pressure drop through cyclone (inches water): 6. Method of handling material removed:
Gas Stream Characteristics
7. Particulate grain loading:
Inlet: __________________________
Outlet: _________________________
8. Total flow rate (acfm):
Design maximum: ________________________
Average expected: ________________________
9. Gas stream temperature (oF):
Emissions Calculations (PTE)
10. Calculated emissions for this device
PM10 ____________Lbs/hr___________ Tons/yr PM2.5 _____________Lbs/hr_____________ Tons/yr
Submit calculations as an appendix.
Instructions
NOTE: 1. Submit this form in conjunction with Form 1 and Form 2.
2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this
form. Ask to speak with a New Source Review engineer. We will be glad to help!
1. Fill in the cyclone manufacturer's name and model number.
2. Indicate the type of cyclone being used.
3. Supply what the material is being controlled, and its mean geometric diameter in microns (μ).
4. Fill in the efficiency of the cyclone at the maximum and average operating levels.
5. Indicate the pressure drop through the cyclone (inches water).
6. Describe the method of handling the material removed by the cyclone.
7. Indicate the gas stream particulate grain loading at inlet and outlet.
8. Specify the flow rate in actual cubic feet per minute at the design maximum and average.
9. Specify the gas stream temperature as it goes through the cyclone.
10. Supply calculations for all criteria pollutants. Use AP42 or Manufacturers data to complete your calculations.
U:\aq\ENGINEER\GENERIC\Form 2010\Form06.doc
Revised 12/20/2010
Christensen Arms
Blasting Dust Collector 2
See calculations
Mac2Flo
3m2f24
10,000
Utah Division of Air Quality
New Source Review Section Company ________________________________
Site/Source ___________
Form 6 Date ____________________________________
Cyclones
Equipment Information
1. Manufacturer: _____________________________
Model no.: ___________________
2. Type of cyclone: □ wet □ dry
□ Single □ Multiple: number ________
□ In series : number ___________
3. Type of particulate: ___________________________
Particulate size:
________________________microns
(mean geometric diameter)
4. Efficiency of cyclone:
At design maximum:______________________%
At average operation: %
5. Pressure drop through cyclone (inches water): 6. Method of handling material removed:
Gas Stream Characteristics
7. Particulate grain loading:
Inlet: __________________________
Outlet: _________________________
8. Total flow rate (acfm):
Design maximum: ________________________
Average expected: ________________________
9. Gas stream temperature (oF):
Emissions Calculations (PTE)
10. Calculated emissions for this device
PM10 ____________Lbs/hr___________ Tons/yr PM2.5 _____________Lbs/hr_____________ Tons/yr
Submit calculations as an appendix.
Instructions
NOTE: 1. Submit this form in conjunction with Form 1 and Form 2.
2. Call the Division of Air Quality (DAQ) at (801) 536-4000 if you have problems or questions in filling out this
form. Ask to speak with a New Source Review engineer. We will be glad to help!
1. Fill in the cyclone manufacturer's name and model number.
2. Indicate the type of cyclone being used.
3. Supply what the material is being controlled, and its mean geometric diameter in microns (μ).
4. Fill in the efficiency of the cyclone at the maximum and average operating levels.
5. Indicate the pressure drop through the cyclone (inches water).
6. Describe the method of handling the material removed by the cyclone.
7. Indicate the gas stream particulate grain loading at inlet and outlet.
8. Specify the flow rate in actual cubic feet per minute at the design maximum and average.
9. Specify the gas stream temperature as it goes through the cyclone.
10. Supply calculations for all criteria pollutants. Use AP42 or Manufacturers data to complete your calculations.
U:\aq\ENGINEER\GENERIC\Form 2010\Form06.doc
Revised 12/20/2010
Christensen Arms
United Air Specialist
C-3620-1D
7000
See calculations
Blasting Dust Collector 3
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX B
Process Flow Diagram, Site Layout, and Area Map
DATE:PROJECT NO.2/17/2021
Figure 1
General Process Flow Diagram
Christensen Arms
Gunnison, Utah
206470
Bar
Stock Machining Electric
Oven
Contour
(Machining)
PM
Dust
Resin
Application
VOC
Sanding/
Abrasive
Blasting
PM
Dust
Paint Booth
PM, VOC, HAPs
MERV 8
Stack A
Assembly/
Adhesive
VOC
Range/
Testing
PM, CO,
NOx, Lead
Legend:
Material Flow
Emissions Flow
2/17/2021 Page 1 of 1 2:21 PMChristensen Arms NOI AO 16/641 2/26/21
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX C
Emission Calculations
Christensen Arms
Gunnison, UT
Emissions Summary
Actual Emissions
Emission Source
VOC
(tpy)
PM
(tpy)
PM10
(tpy)
PM2.5
(tpy)
NOx
(tpy)
CO
(tpy)
Combined
HAP
(tpy)
Maximum
Single HAP
(tpy)
Hydroquinone
123-31-9
(tpy)
Hexane
110-54-3
(tpy)
Cumene
98-82-8
(tpy)
Lead
(tpy)
Xylene
1330-20-7
(tpy)
Hexamethyl
ene-1,6-
diisocyanat
e
822-06-0
(tpy)
Ethyl
Benzene
100-41-4
(tpy)
Styrene
100-42-5
(tpy)
Toluene
108-88-3
(tpy)
Methyl
isobutyl
ketone
(Hexone)
108-10-1
(tpy)
2,4-
Toluene
diisocyana
te
584-84-9
(tpy)
Phenol
108-95-2
(tpy)
Methyl
Alcohol
67-56-1
(tpy)
Copper
(tpy)
Chromium
(tpy)
Manganese
(tpy)
Nickel
(tpy)
Solvent Use 0.03Mold Release 0.09Epoxy Resin 0.03Lubricant Usage 0.38Adhesive0.66 1.46E-03 3.51E-06 1.35E-03 1.03E-04
Paint[1]4.77 1.18E-01 1.18E-01 1.18E-01 3.28 1.53 0.74 0.02 0.51 1.53 0.24 0.10 1.26E-03 0.15 0.00E+00
Blasting [1]4.25E-09 4.25E-09 4.25E-09
Welding[1]1.77E-05 1.77E-05 1.77E-05 4.63E-08 2.08E-09 2.60E-08 1.04E-08 7.80E-09
Metal Machining 4.38E-06 2.50E-06 2.50E-06Combustion0.04 6.06E-02 6.06E-02 6.06E-02 0.80 0.67 0.02 1.43E-02Range2.73E-03 2.60E-03 1.84E-03 1.30E-03 9.53E-02 1.59E-04 1.59E-04Total6.01 0.18 0.18 0.18 7.98E-01 7.65E-01 3.30 1.53 3.51E-06 1.35E-03 1.03E-04 1.59E-04 0.74 0.02 0.51 1.53 0.24 0.10 1.26E-03 0.15 0.00E+00 2.08E-09 2.60E-08 1.04E-08 7.80E-09
Potential Emissions
Emission Source VOC (tpy)PM(tpy)
PM10(tpy)
PM2.5(tpy)NOx(tpy)CO(tpy)
Combined
HAP(tpy)
Maximum
Single HAP(tpy)
Hydroquinone
123-31-9(tpy)
Hexane
110-54-3(tpy)
Cumene
98-82-8(tpy)Lead (tpy)
Xylene
1330-20-7(tpy)
Hexamethylene-1,6-
diisocyanate
822-06-0(tpy)
Ethyl Benzene
100-41-4(tpy)
Styrene
100-42-5(tpy)
Toluene
108-88-3(tpy)
Methyl isobutyl
ketone (Hexone)
108-10-1(tpy)
2,4-Toluene
diisocyanate
584-84-9(tpy)
Phenol
108-95-2(tpy)
Methyl Alcohol
67-56-1(tpy)Copper(tpy)Chromium(tpy)Manganese(tpy)Nickel(tpy)
Solvent Use 0.05
Mold Release 0.18
Epoxy Resin 0.05Lubricant Usage 0.72Adhesive1.24 2.74E-03 6.56E-06 2.54E-03 1.93E-04Paint[1]8.93 0.22 0.22 0.22 6.15 2.86 1.39 0.04 0.95 2.86 0.45 0.19 2.35E-03 0.28 0.00E+00Blasting [1]2.98E-05 2.98E-05 2.98E-05
Welding[1]3.31E-05 3.31E-05 3.31E-05 8.66E-08 3.89E-09 4.87E-08 1.95E-08 1.46E-08
Metal Machining 0.00 0.00 0.00
Combustion 0.06 0.09 0.09 0.09 1.12 0.94 0.02 2.01E-02
Range 0.01 4.88E-03 3.45E-03 2.44E-03 1.78E-01 2.97E-04 2.97E-04
Total 11.22 0.31 0.31 0.31 1.12 1.12 6.17 2.86 6.56E-06 2.54E-03 1.93E-04 2.97E-04 1.39 0.04 0.95 2.86 0.45 0.19 2.35E-03 0.28 0.00E+00 3.89E-09 4.87E-08 1.95E-08 1.46E-08
[1]In lieu of data available to specidate emissions, PM10 and PM2.5 emissions conservatively estimted to equal PM emissions.
HAPs
HAPs
rpsgroup.com Project Number:206470
Christensen Arms
Gunnison, UT
Abrasive Blasting
PTEhr/day day/wk wk/yr hr/yr hr/yr1855246808760
Materials units
(gals, cans,
Liters, etc.)Size UOM
Typical
Annual
Usage
(Containers)
Annual
Usage
(lbs)
Usage
(lb/hr)
Usage
(lb/day)
Usage
(tpy)
MSC (Glass Bead)50 lbs 50 lbs 83 4150 0.89 15.96 2.08
MSC (Aluminum Oxide)50 lbs 50 lbs 19 950 0.20 3.65 0.48MSC (Silicon Carbide)50 lbs 50 lbs 24 1200 0.26 4.62 0.60
Total 6300 1.35 24.23 3.15
Emission Factor
lb/1000 lb
Abrasive Blasting1 27
1AP-42 Table 13.2.6-1 PM Factors for Abrasive Blasting - Sand blasting of mild steel value at 5 mph wind speed
Control Factor
Efficiency2 99.99%
2 Efficiency based on manufacturer provided documentation
Actual, Controlled Emissions
lb/hr lb/day lb/yr tpyAbrasive Blasting 3.63E-06 0.0001 8.50E-06 4.25E-09
Potential, Controlled Emissions
lb./hr lb/day lb/yr tpyAbrasive Blasting 6.80E-06 1.63E-04 0.06 2.98E-05
Based on 8760 hr/yr
Potential, Uncontrolled Emissions
lb./hr lb/day lb/yr tpy
Abrasive Blasting 0.07 1.63 595.97 0.30
Based on 8760 hr/yr
Emission Unit PM
Emission Unit PM
Actual Hours
Materials PM
Materials PM
Use outdoor factor since indoor not available: for wind at 5 mph is 27 lb/1000lb; wind at 10 mph is 55 lb/1000lb; wind at 15 mph is 91
lb/1000lb
rpsgroup.com Project Number:206470
Christensen Arms
Gunnison, UT
Solvent Use
Hours of Operation
Hours per Day Days per Week Weeks Per Year Hours per Year
Maximum
Hours per Year
18 5 52 4680 8760
Solvent Characteristics
Manufacturer Product Specific Gravity Density(lb/gallon)VOC(%)VOC(lb/gallon)
Methanol
67-56-1%
Methanol
67-56-1lb/gallon
NA Acetone 0.79 6.59 100%6.59Barnescr-10[1]1.10 9.17 100%9.17HoppesNo. 9 gun oil 0.87 7.22 3%0.22
Lucas Bore solvent[1][2]0.84 6.99 100%6.99Hoppesno 9 bore cleaner[2]0.84 7.04 71%5.00 5 0.351948SHER WILL FINISH 1™ Wash Solvent 0.82 6.83 51%3.52
SHER WILL MAK Methyl Amyl Ketone R6K30 0.81 6.75 100%6.75
STAR META AquaVantage® 515 NF / FORMULA 515 NF 1.09 9.09 1%0.13
STAR META
COMMAND CLEAN HEAVY-DUTY
WATER-BASED DEGREASER 1.00 8.34 3%0.21
[1] Conservative VOC content used in lieu of product specific data
Solvent Usage
Manufacturer Product
units
(gals, cans,
Liters, etc.)Size UOM
Gallon
Conversion
Yearly
Usage
Yearly
Usage
(gallons)NA Acetone 55 gallons 55 gallons 1 75 4125
Barnes cr-10[1]8 oz 8 oz 0 87 5.44
Hoppes No. 9 gun oil 2.25 oz 2.25 oz 0 60 1.05LucasBore solvent[1][2]
Hoppes no 9 bore cleaner[2]
SHER WILL FINISH 1™ Wash SolventSHER WILL MAK Methyl Amyl Ketone R6K30
STAR META AquaVantage® 515 NF / FORMULA 515 NFSTAR META COMMAND CLEAN HEAVY-DUTY WATER-BASED DEGREASER[2]Usage data not provided
Actual Emissions
Manufacturer Product VOC(lbs/year)VOC (tpy)
Methanol
67-56-1(lb/year)
Methanol
67-56-1(tpy)
NA Acetone 27,177.98 13.59 0 0.00Barnescr-10[1]49.88 0.02 0 0.00HoppesNo. 9 gun oil 0.23 0.00 0 0.00
Lucas Bore solvent[1][2]0.00 0.00 0 0.00Hoppesno 9 bore cleaner[2]0.00 0.00 0 0.00SHER WILL FINISH 1™ Wash Solvent 0.00 0.00 0 0.00
SHER WILL MAK Methyl Amyl Ketone R6K30 0.00 0.00 0 0.00STAR META AquaVantage® 515 NF / FORMULA 0.00 0.00 0 0.00STAR META COMMAND CLEAN HEAVY-DUTY W 0.00 0.00 0 0.00
Total 50.11 0.03 0.00 0.00
Potential Emissions
Manufacturer Product
VOC
(lbs/year)
VOC
(tpy)
Methanol
67-56-1
(lb/year)
Methanol
67-56-1
(tpy)NA Acetone 50,871.59 25.44 0 0Barnescr-10[1]93.37 0.05 0 0
Hoppes No. 9 gun oil 0.43 0.00 0 0LucasBore solvent[1][2]0.00 0.00 0 0Hoppesno 9 bore cleaner[2]0.00 0.00 0 0
SHER WILL FINISH 1™ Wash Solvent 0.00 0.00 0 0
SHER WILL MAK Methyl Amyl Ketone R6K30 0.00 0.00 0 0
STAR META AquaVantage® 515 NF / FORMULA 0.00 0.00 0 0
STAR META COMMAND CLEAN HEAVY-DUTY W 0.00 0.00 0 0
Total 93.80 0.05 0.00 0.00
rpsgroup.com Project Number:206470
Christensen Arms
Gunnison, UT
Mold Release
Hours of Operation
Hours per Day Days per Week Weeks Per Year
Hours per
Year
Maximum
Hours per
Year1855246808760
Mold Release Characteristics
Manufacturer Product Specific Gravity Density(lb/gallon)VOC(%)VOC(lb/gallon)
Utah Foam Maverix DHSR-2[2]
MSC/Comp One Mono-Coat 0.77 6.4218 98.54 6.32804172
zyvax Water Shield 1 8.34 0 0
[1] Conservative SG and VOC content used in lieu of product specific data
[2]SDS not provided. To be updated.
Mold Release Usage
Manufacturer Product
units
(gals, cans,
Liters, etc.)Size UOM
Gallon
Conversion
Yearly
Usage
Yearly
Usage
(gallons)
Utah Foam Maverix DHSR-2[2]Buckets 5 gallon 1 46 230
MSC/Comp One Mono-Coat 5 gallon pail 5 gallon 1 6 30
zyvax Water Shield gallon 1 gallon 1 373 373
Actual Emissions
Manufacturer Product
VOC
(lbs/year)
VOC
(tpy)Utah Foam Maverix DHSR-2[2]0.00 0.00MSC/Comp One Mono-Coat 189.84 0.09zyvaxWater Shield 0.00 0.00
Total 189.84 0.09
Potential Emissions
Manufacturer Product
VOC
(lbs/year)
VOC
(tpy)Utah Foam Maverix DHSR-2[2]0.00 0.00
MSC/Comp One Mono-Coat 355.34 0.18zyvaxWater Shield 0.00 0.00
Total 355.34 0.18
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTEpoxy/Resin Usage
Hours of Operation
Hours per Day Days per Week Weeks Per Year Hours per Year
Maximum Hours per Year1855246808760
Epoxy Resin Characteristics
Manufacturer Product SDS Name Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon)
COMP ONE EXPANDING FOAM HP-8212 PART A
POLYETHER POLYOL, HP 8212 A, ETECO.pd 1.23 9 0 0.00 0.00
COMP ONE EXPANDING FOAM HP-8212 PART B
POLYETHER POLYOL, HP 8212 B, ETECO.pdf 1.12 8.8 0 0.00 0.00
COMP ONE RHINO LINER 1384 RESIN
EPOXY RESIN, 1384 RESIN 'A', REV 3-30-2015.pdf 0.55 4.59 0 0.00 0.00
COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]
Pro-Set, Epoxy Hardener, LAM-224.pdf 1.00 8.34 1.13 1.06 0.10
COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]
Pro-Set, Epoxy Resin, LAM-145.pdf 1.17 9.75 1.13 1.06 0.10
COMP ONE RHINO LINER 1391R-1 RESIN
RHINO LININGS, EPOXY RESIN, 1391R-1, 3-30-15.pdf 1.16 9.7 0 0.00 0.00
COMP ONE EPOXY/RESIN PART A[2]
API-334-3 PART A EPOXY RESIN, API (APPLIED POLERAMIC, INC.).pd 1.14 9.51 22.79 2.00 0.19
COMP ONE EPOXY/RESIN HARDENER PART B[2]
API-334-3 PART B EPOXY HARDENER, API (APPLIED POLERAMIC, INC.).pd 0.92 7.67 18.39 2.00 0.15
COMP ONE RHINO LINER 3136R-3 HARDNER
RHINO LININGS, EPOXY HARDENER, 3136R-2, REV 3-26-15.pd 1.00 8.34 0.00 0.00 0
COMP ONE RHINO LINGER 3184 HARDNER
RHINO LININGS, RHINO 3184 EPOXY HARDENER, REV 03-30-2015.pdf 1.00 8.34 0 0.00 0.00[1]VOC represents a combination of 3 parts resin, 1 part hardener. [2] Based on a conversation with the manufacturer, VOC is expected to be extremely low if present. In lieu of specific data a conservative estimate of 2% used.
Paint Usage
Manufacturer Product
units
(gals, cans, Liters, etc.)Yearly Usage
Maximum Yearly
Actual Usage
Potential
Yearly UsageCOMP ONE EXPANDING FOAM HP-8212 PART A lbs 17,338.50 17,338.50 32,454.12COMP ONE EXPANDING FOAM HP-8212 PART B LBS 15,582.15 15,582.15 29,166.59COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]LBS 29,321.48 29,321.48 54,883.80COMP ONE RHINO LINER 1384 RESIN LBS 494.16 494.16 924.97COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]LBS 1,708.89 1,708.89 3,198.69COMP ONE RHINO LINER 1391R-1 RESIN LBS 39,074.13 39,074.13 73,138.76COMP ONE EPOXY/RESIN PART A[2]LBS 1,117.53 1,117.53 2,091.79COMP ONE EPOXY/RESIN HARDENER PART B[2]LBS 227.91 227.91 426.60COMP ONE RHINO LINER 3136R-3 HARDNER LBS 661.40 661.40 1,238.01COMP ONE RHINO LINGER 3184 HARDNER LBS 8,372.07 8,372.07 15,670.80
Actual Emissions
Manufacturer Product
VOC(lbs/year)VOC (tpy)
COMP ONE EXPANDING FOAM HP-8212 PART A 0.00 0.00COMP ONE EXPANDING FOAM HP-8212 PART B 0.00 0.00COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]0.00 0.00COMP ONE RHINO LINER 1384 RESIN 5.26 0.00COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]18.18 0.01COMP ONE RHINO LINER 1391R-1 RESIN 0.00 0.00COMP ONE EPOXY/RESIN PART A[2]22.35 0.01COMP ONE EPOXY/RESIN HARDENER PART B[2]4.56 0.00COMP ONE RHINO LINER 3136R-3 HARDNER 0.00 0.00COMP ONE RHINO LINGER 3184 HARDNER 0.00 0.00Total50.35 0.03
Potential Emissions
Manufacturer Product VOC(lbs/year)VOC (tpy)COMP ONE EXPANDING FOAM HP-8212 PART A 0.00 0.00COMP ONE EXPANDING FOAM HP-8212 PART B 0.00 0.00COMP ONE PRO SET EPOXY LAM 145 BK RESIN[1]0.00 0.00COMP ONE RHINO LINER 1384 RESIN 9.84 0.00COMP ONE PRO SET EPOXY LAM-224-HARDENER[1]34.04 0.02COMP ONE RHINO LINER 1391R-1 RESIN 0.00 0.00COMP ONE EPOXY/RESIN PART A[2]41.84 0.02COMP ONE EPOXY/RESIN HARDENER PART B[2]8.53 0.00COMP ONE RHINO LINER 3136R-3 HARDNER 0.00 0.00COMP ONE RHINO LINGER 3184 HARDNER 0.00 0.00Total94.25 0.05
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTLubricant Usage
Hours of Operation
Hours per Day Days per Week Weeks Per Year
Hours per
Year
Maximum
Hours per
Year1855246808760
Lubricant Characteristics
Manufacturer Product SDS Name Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon)
Star Metal WALPRODRWBB-005 Prodraw BB_sds (1)1.15 9.59 7.19 0.63 0.06
Star Metal QCM335XCOL-005 (Coolant)QCM 335 1.06 8.81 51.73 4.90 0.43
Star Metal BOSUNI150-055 (R&O Turbine Unilube)BOS UNILUBE 150 0.89 7.42
Star Metal QCM251CXCUT-055
QUALIC.XTREME_
CUT_251C.SDS_US
.English 0.96 8.01 41.8 4.36 0.35Star Metal BOSUNI032-005 (R&O Turbine Unilube)BOS UNILUBE 32 0.89 7.42
Star Metal QCM740LMDR-055
QUALIC.MET-DRILL_740L.SDS_U
S.English 0.88 7.34 13 1.48 0.11
Star Metal BOSSPIN10-005 sds BOS SPIN 0.89 7.42Star Metal BOSHYD046-005 (Hydraulic oil)BOS HYD AW46 0.87 7.26Star Metal BOSWAY2-055 (2 Way oil)sds BO Way 2 0.89 7.42
Star Metal COMHDCLN-005 (Degreaser)[2]SDS COM HD 1.00 8.35 25 2.50 0.21
Star Metal BOSGEA220-005 BOS GEAR 220 0.89 7.42
Star Metal BOSGEA150-005 BOS GEAR 150 0.89 7.42WD-40 WD-40 WD-40 AEROSOL 0.82 6.84 412 50.28 3.44
WD-40 WD-40
wd-40 gallon
(MSDS)0.82 6.84 204 24.89 1.70
[1]Conservative VOC used in lieu of product specific data[2]As applied VOC used. VOC in bottle = 75 g/L
Lubricant Usage
Manufacturer Product
units(gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage
Yearly Usage(gallons)Star Metal WALPRODRWBB-005 5 Gal 5 gallon 1 5 25.00Star Metal QCM335XCOL-005 (Coolant)5 Gal 5 gallon 1 4 20.00Star Metal BOSUNI150-055 (R&O Turbine Unilube)55 Gal 55 gallon 1 14 770.00
Star Metal QCM251CXCUT-055 55 Gal 55 gallon 1 20 1100.00
Star Metal BOSUNI032-005 (R&O Turbine Unilube)5 Gal 5 gallon 1 15 75.00Star Metal QCM740LMDR-055 55 Gal 55 gallon 1 42 2310.00Star Metal BOSSPIN10-005 5 Gal 5 gallon 1 3 15.00Star Metal BOSHYD046-005 (Hydraulic oil)5 Gal 5 gallon 1 3 15.00
Star Metal BOSWAY2-055 (2 Way oil)55 Gal 55 gallon 1 4 220.00
Star Metal COMHDCLN-005 (Degreaser)[2]5 Gal 5 gallon 1 4 20.00Star Metal BOSGEA220-005 5 Gal 5 gallon 1 1 5.00Star Metal BOSGEA150-005 5 Gal 5 gallon 1 1 5.00WD-40 WD-40 11oz 11 oz 0 211 18.13281WD-40 WD-40 gallon 1 gallon 1 32 32
Actual Emissions
Manufacturer Product VOC(lbs/year)VOC (tpy)Star Metal WALPRODRWBB-005 1.50 0.00Star Metal QCM335XCOL-005 (Coolant)8.63 0.00Star Metal BOSUNI150-055 (R&O Turbine Unilube)0.00 0.00Star Metal QCM251CXCUT-055 383.72 0.19Star Metal BOSUNI032-005 (R&O Turbine Unilube)0.00 0.00Star Metal QCM740LMDR-055 250.61 0.13Star Metal BOSSPIN10-005 0.00 0.00Star Metal BOSHYD046-005 (Hydraulic oil)0.00 0.00
Star Metal BOSWAY2-055 (2 Way oil)0.00 0.00Star Metal COMHDCLN-005 (Degreaser)[2]4.17 0.00Star Metal BOSGEA220-005 0.00 0.00Star Metal BOSGEA150-005 0.00 0.00WD-40 WD-40 62.35 0.03WD-40 WD-40 54.48 0.03
Total 765.47 0.38
Potential Emissions
Manufacturer Product VOC(lbs/year)VOC (tpy)Star Metal WALPRODRWBB-005 2.81 0.00Star Metal QCM335XCOL-005 (Coolant)16.16 0.01
Star Metal BOSUNI150-055 (R&O Turbine Unilube)0.00 0.00Star Metal QCM251CXCUT-055 718.25 0.36Star Metal BOSUNI032-005 (R&O Turbine Unilube)0.00 0.00Star Metal QCM740LMDR-055 469.10 0.23Star Metal BOSSPIN10-005 0.00 0.00Star Metal BOSHYD046-005 (Hydraulic oil)0.00 0.00
Star Metal BOSWAY2-055 (2 Way oil)0.00 0.00Star Metal COMHDCLN-005 (Degreaser)[2]7.81 0.00Star Metal BOSGEA220-005 0.00 0.00Star Metal BOSGEA150-005 0.00 0.00WD-40 WD-40 116.70 0.06WD-40 WD-40 101.97 0.05
Total 1432.80 0.72
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTAdhesive Usage
Hours of Operation
Hours per Day Days per Week Weeks Per Year Hours per Year
Maximum Hours per Year1855246808760
Adhesive Characteristics
Manufacturer Product SDS Name Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon)
Hydroquinone123-31-9(%)
Hydroquinone123-31-9(lb/gallon)
Hexane110-54-3(%)
Hexane110-54-3(lb/gallon)
Cumene98-82-8(%)
Cumene98-82-8(lb/gallon)
3m Super 77 Spray Adhesive 3m super 77 spray adhesive 0.73 6.05484 458.00 63.13 3.82 0.5 0.0302742pacerRX-50 pacer rx-50 sds 1.06 8.8404 20 1.89 0.17 0.1 0.01
devcon 5 minute epoxy
DEVCON 5 MINUTE EPOXY AMBER 1-1 1.17 9.7578 0 0.00 0.00
vettec bovi-bond[1]
bovi-bond-block-adhesive-46130-part-a-sds 1.20 10.008 1,199.22 100.00 10.01
pacer accelerator[1]ACETONE ACCELERATOR 0.80 6.672 799.48 100.00 6.67
Engineered Bonding SolutiFibertack[1]
ENGINEERED BONDING SOLUTIONS, FIBERTACK MT-1,
ADHESIVE, 6-16-2016 0.90 7.54 903.49 100.00 7.54
Loctite Blue BLUE LOCTITE 242 1.10 9.174 6.17 0.56 0.05 1 0.09174
Loctite Red
RED LOCTITE 277 1.10 9.174 7.13 0.65 0.06 1 0.09174[1]Conservative VOC used in lieu of product specific data
Adhesive Usage
Manufacturer Product
units
(gals, cans, Liters, etc.)Size UOM Gallon Conversion Yearly Usage
Yearly
Usage(gallons)3m Super 77 Spray Adhesive 16.75oz 16.75 oz 7.81E-03 684 89.51pacerRX-50 0.7oz 0.7 oz 7.81E-03 145 0.79devcon5 minute epoxy 50ml 50 ml 2.64E-04 2855 37.71vettecbovi-bond[1]166cc 166 cc 2.64E-04 1279 56.09paceraccelerator[1]2oz 2 oz 7.81E-03 154 2.41Engineered Bonding SoluFibertack[1]12oz 12 oz 7.81E-03 576 54.00LoctiteBlue250ml250ml2.64E-04 23 1.52LoctiteRed250ml250ml2.64E-04 11 0.73
Actual Emissions
Manufacturer Product
VOC(lbs/year)VOC (tpy)
Hydroquinone123-31-9(lb/year)
Hydroquinone123-31-9(tpy)
Hexane110-54-3(lb/year)
Hexane110-54-3(tpy)
Cumene98-82-8(lb/year)
Cumene98-82-8(tpy)
3m Super 77 Spray Adhesive 342.12 0.17 0 0 2.71 1.35E-03 0 0.00pacerRX-50 0.13 0.00 0.01 3.51E-06 0 0.00 0 0.00devcon5 minute epoxy 0.00 0.00 0 0.00 0 0.00 0 0.00vettecbovi-bond[1]561.32 0.28 0 0.00 0 0.00 0 0.00paceraccelerator[1]16.05 0.01 0 0.00 0 0.00 0 0.00Engineered Bonding SoluFibertack[1]407.16 0.20 0 0.00 0 0.00 0 0.00LoctiteBlue0.08 0.00 0 0.00 0 0.00 0.14 6.97E-05LoctiteRed0.04 0.00 0 0.00 0 0.00 0.07 3.33E-05Total1326.91 0.66 0.01 3.51E-06 2.71 1.35E-03 0.21 1.03E-04
Potential Emissions
Manufacturer Product VOC(lbs/year)VOC (tpy)
Hydroquinone123-31-9(lb/year)
Hydroquinone123-31-9(tpy)
Hexane110-54-3(lb/year)
Hexane110-54-3(tpy)
Cumene98-82-8(lb/year)
Cumene98-82-8(tpy)3m Super 77 Spray Adhesive 640.37 0.32 0 0 5.07 2.54E-03 0 0pacerRX-50 0.25 0.00 0.01 6.56E-06 0 0 0 0devcon5 minute epoxy 0.00 0.00 0 0 0 0 0 0vettecbovi-bond[1]1,050.68 0.53 0 0 0 0 0 0paceraccelerator[1]30.05 0.02 0 0 0 0 0 0Engineered Bonding SoluFibertack[1]762.12 0.38 0 0 0 0 0 0LoctiteBlue0.15 0.00 0 0 0 0 0.26 1.30E-04LoctiteRed0.08 0.00 0 0 0 0 0.12 6.237E-05Total2483.70 1.24 0.01 6.56E-06 5.07 2.54E-03 0.39 1.93E-04
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTPaint Usage
Hours of Operation
Hours per Day Days per Week Weeks Per Year Hours per Year
Maximum Hours per Year1855246808760
Paint Characteristics
Manufacturer Product SDS Name
Application Method
Transfer
Efficiency4 Dropout
Rate4 Specific Gravity Density(lb/gallon)VOC(g/L)VOC(%)VOC(lb/gallon)
PM Solid Content (%)
PM(lb/gallon)
Xylene1330-20-7(%)
Xylene1330-20-7(lb/gallon)
Hexamethylene-1,6-
diisocyanate822-06-0(%)
Hexamethylene-1,6-diisocya
nate822-06-0(lb/gallon)
Ethyl Benzene100-41-4(%)
Ethyl
Benzene100-41-4(lb/gallon)
Styrene100-42-5(%)
Styrene100-42-5(lb/gallon)
Toluene108-88-3(%)
Toluene108-88-3(lb/gallon)
Methyl isobutyl
ketone (Hexone)108-10-1(%)
Methyl isobutyl ketone
(Hexone)108-10-1(lb/gallon)
2,4-Toluene
diisocyanate 584-84-9(%)
2,4-Toluene diisocya
nate 584-84-9(lb/gallon)
Phenol108-95-2(%)
Phenol108-95-2(lb/gallon)
Methyl Alcohol67-56-1(%)
Methyl
Alcohol67-56-1(lb/gallon)
SHERWIN WILLIAMS PAINT BLACK FLAT BLACK PAINT Spray 15.00%90.00%1.10 9.16 605 55.10 5.05 44.90 4.11 2 0.18 0.00 0.5 0.05 0.00 7 0.64 0.00 0.00 0.00 0.00
SHERWIN WILLIAMS K69 POLANE REDUCER k69 Spray 15.00%90.00%7.04 844 100.00 7.04 0.00 0.00 52 3.66 0.00 9 0.63 0.00 15 1.06 24 1.69 0.3 0.02 0.00 0.00SHERWIN WILLIAMS V66V27 CATALYST v66v27 Spray 15.00%90.00%1.15 9.57 459 40.00 3.83 60.00 5.74 0.00 0.00 0.00 0.00 0.00 0.00 0.00 32 3.06 0.00
NIC CERAKOTE[2]
H-SERIES PART B
NIC.pdf Spray 15.00%90.00%1.08 9.01554 0 0.00 0.00 100.00 9.02 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
NCS VTK 34-20001 2K URETHANE PRIMER Vietek 34-200 SDS Spray 15.00%90.00%1.42 11.84 491 34.63 4.10 65.37 7.74 12 1.42 0.00 3 0.36 0.00 0.00 0.00 0.00 0.00 0.00NCSVTK 34-20204 ACTIVATOR Vietek 34-202 SDS Spray 15.00%90.00%0.96 8.01 635 66.17 5.30 33.83 2.71 24 1.92 0.00 6.1 0.49 0.00 7 0.56 0.00 0.00 0.00 0.00
NCS UPO714 DOLPHIN GLAZE Upol UP0714 SDS
Spread with
blade 100.00%0 1.21 10.0914 220 18.19 1.84 81.81 8.26 0.00 0.00 5 0.50 23 2.32 0.00 0.00 0.00 0.00 0.00
NCS 8984 GENERAL ADHESIVE REMOVER
3M (TM)
ADHESIVE
REMOVER Spray or wipe 15.00%90.00%0.84 7.0056 840 100.00 7.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
NCS FIV 5186 FAST ACTIVATOR
4. 4 XTREME 4. 4
VOC FAST ACTIVATOR Spray 15.00%90.00%1.00 8.34 469.82 47.00 3.92 53.00 4.42 0.35 0.03 1 0.08 0.00 0.00 0.00 0.00 0.00 0.00 0.00
NCS FIV 5185 X-TREME 4.4 VOC CLEAR
4. 4 XTREME FLAT
FINISH KLEAR KOTE Spray 15.00%90.00%0.93 7.7562 543.81 58.53 4.54 41.47 3.22 0.00 13.1807 1.02 2.94 0.23 0.1622 0.01 0.00 0.00 0.00 0.00 0.00
NCS FIV 5165 ORIGINAL HARDENER Five Star 5165 SDS Spray 15.00%90.00%0.93 7.74 355 38.24 2.96 61.76 4.78 25 1.94 0.00 3 0.23 0.3 0.02 0.3 0.02 0.00 0.00 0.00 0.00
Sherwin Williams Garden Gate Green
GARDEN GATE
GREEN PAINT Spray 15.00%90.00%1.16 9.64 650 56.30 5.43 43.70 4.21 3 0.29 0.00 1 0.10 0.00 3 0.29 0.00 0.00 0.00 0.00
Sherwin WIlliams Grizzly Grey
GRIZZLE GREY
PAINT Spray 15.00%90.00%1.18 9.88 640 54.10 5.35 45.90 4.53 2.5 0.25 0.00 1 0.10 0.00 2.9 0.29 0.00 0.00 0.00 0.00
Sherwin Williams portobello Tan
PORTOBELLO TAN
PAINT Spray 15.00%90.00%1.24 10.32 627 50.70 5.23 49.30 5.09 2.5 0.26 0.00 1 0.10 0.00 3 0.31 0.00 0.00 0.00 0.00
surfin Ni-Black 40 Spray 15.00%90.00%100.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
adtech p-17 P-17
Spread with
blade 100.00%0 1.59 13.2606 252 15.86 2.10 84.14 11.16 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1 0.13
hardener black
PEROXIDE CREAM HARDENER Spread with blade 100.00%0 1.33 11.0922 252 0.00 0.00 100.00 11.09 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
hardener blue
PEROXIDE CREAM HARDENER Spread with blade 100.00%0 1.33 11.0922 252 0.00 0.00 100.00 11.09 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
[1]Conservative VOC used in lieu of product specific data
[2]Conservative SG used in lieu of product specific data
[3] Usage not provided[4] Transfer Efficieny and Dropout rate based on TCEQ quidance
Paint Usage
Manufacturer Product
units(gals, cans,
Liters, etc.)Size UOM
Gallon
Conversion
Yearly
Usage
Yearly Usage
(gallons)
SHERWIN WILLIAMS PAINT BLACK Gal 1 gallon 1 326 326.00
SHERWIN WILLIAMS K69 POLANE REDUCER Gal 1 gallon 1 119 119.00SHERWIN WILLIAMS V66V27 CATALYST Gal 1 gallon 1 97 97.00
NIC CERAKOTE[2]QTS 1 quart 0.25 129 32.25
NCS VTK 34-20001 2K URETHANE PRIMER Gal 1 gallon 1 463 463.00NCSVTK 34-20204 ACTIVATOR Quart 1 quart 0.25 484 121.00
NCS UPO714 DOLPHIN GLAZE 440ml 440 ml 2.64E-04 11325 1316.36
NCS 8984 GENERAL ADHESIVE REMOVER Quart 1 quart 0.25 74 18.50NCSFIV 5186 FAST ACTIVATOR Quart 1 quart 0.25 53 13.25NCSFIV 5185 X-TREME 4.4 VOC CLEAR Gal 1 gallon 1 37 37.00
NCS FIV 5165 ORIGINAL HARDENER Gal 1 gallon 1 15 15.00Sherwin Williams Garden Gate Green Gal 1 gallon 1 168 168.00Sherwin WIlliams Grizzly Grey Gal 1 gallon 1 41 41.00
Sherwin Williams portobello Tan Gal 1 gallon 1 40 40.00surfinNi-Black 40 gal 1 gallon 1 3 3.00adtechp-17 3lb can 90 0.00
0 hardener black 4 oz 4 oz 0.0078125 320 10.000hardener blue 4oz 4 oz 0.0078125 21 0.66
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTPaint Usage
Filter Specification
Filter Efficiency(%)84.9
Actual, Controlled Emissions
Manufacturer Product
VOC
(lbs/year)
VOC
(tpy)
PM
(lbs/year)
PM
(tpy)
Xylene1330-20-7
(lb/year)
Xylene1330-20-7
(tpy)
Hexamet
hylene-1,6-diisocyanate822-06-0
(lb/year)
Hexamethylene-1,6-diisocyanate822-06-0
(tpy)
Ethyl Benzene100-41-4
(lb/year)
Ethyl Benzene100-41-4
(tpy)
Styrene100-42-5
(lb/year)
Styrene100-42-5
(tpy)
Toluene108-88-3
(lb/year)
Toluene108-88-3
(tpy)
Methyl isobutyl ketone (Hexone)108-10-1
(lb/year)
Methyl isobutyl ketone (Hexone)108-10-1
(tpy)
2,4-Toluene diisocyanate 584-84-9
(lb/year)
2,4-Toluene diisocyanate 584-84-9
(tpy)
Phenol108-95-2
(lb/year)
Phenol108-95-2
(tpy)
Methyl Alcohol67-56-1
(lb/year)
Methyl Alcohol67-56-1
(tpy)
SHERWIN WILLIAMS PAINT BLACK 1645.37 0.82 17.21 0.01 59.72 0.03 0 0.00 14.9308 0.01 0 0.00 209.03 0.10 0 0.00 0 0.00 0 0.00 0 0.00SHERWIN WILLIAMS K69 POLANE REDUCER 837.76 0.42 0.00 0.00 435.64 0.22 0 0.00 75.3984 0.04 0 0.00 125.66 0.06 201.0624 0.10 2.51328 0.00 0 0.00 0 0.00
SHERWIN WILLIAMS V66V27 CATALYST 371.32 0.19 7.15 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 297.0528 0.15 0 0.00
NIC CERAKOTE[2]0.00 0.00 3.73 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00
NCS VTK 34-20001 2K URETHANE PRIMER 1898.30 0.95 46.00 0.02 657.8304 0.33 0 0.00 164.4576 0.08 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSVTK 34-20204 ACTIVATOR 641.30 0.32 4.21 0.00 232.6104 0.12 0 0.00 59.12181 0.03 0 0.00 67.84 0.03 0 0.00 0 0.00 0 0.00 0 0.00NCSUPO714 DOLPHIN GLAZE 2416.82 1.21 139.48 0.07 0 0.00 0 0.00 664.1953161 0.33 3055.3 1.53 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCS8984 GENERAL ADHESIVE REMOVER 129.69 0.06 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSFIV 5186 FAST ACTIVATOR 51.94 0.03 0.75 0.00 0.39 0.00 1.10505 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSFIV 5185 X-TREME 4.4 VOC CLEAR 167.98 0.08 1.53 0.00 0 0.00 37.82589 0.02 8.43719436 0.00 0.46548 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00NCSFIV 5165 ORIGINAL HARDENER 44.40 0.02 0.92 0.00 29.025 0.01 0 0.00 3.483 0.00 0.3483 0.00 0.35 0.00 0 0.00 0 0.00 0 0.00 0 0.00Sherwin Williams Garden Gate Green 911.79 0.46 9.08 0.00 48.59 0.02 0.00 0.00 16.20 0.01 0.00 0.00 48.59 0.02 0 0.00 0 0.00 0 0.00 0 0.00Sherwin WIlliams Grizzly Grey 219.15 0.11 2.39 0.00 10.127 0.01 0 0.00 4.0508 0.00 0 0.00 11.75 0.01 0 0.00 0 0.00 0 0.00 0 0.00Sherwin Williams portobello Tan 209.29 0.10 2.61 0.00 10.32 0.01 0 0.00 4.128 0.00 0 0.00 12.38 0.01 0 0.00 0 0.00 0 0.00 0 0.00surfinNi-Black 40 0.00 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00adtechp-17 0.00 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.000hardener black 0.00 0.00 1.42 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.000hardener blue 0.00 0.00 0.09 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0.00 0.00 0 0.00 0 0.00 0 0.00 0 0.00Total9545.11 4.77 236.57 0.12 1484.24 0.74 38.93 0.02 1014.40 0.51 3,056.11 1.53 475.61 0.24 201.06 0.10 2.51 1.26E-03 297.05 0.15 0.00 0.00
Potential Controlled Emissions
Manufacturer Product
VOC
(lbs/year)
VOC
(tpy)
PM
(lbs/year)
PM
(tpy)
Xylene
1330-20-7
(lb/year)
Xylene
1330-20-7
(tpy)
Hexamet
hylene-1,6-diisocyanate
822-06-0
(lb/year)
Hexamethylene-1,6-diisocyanate
822-06-0
(tpy)
Ethyl Benzene
100-41-4
(lb/year)
Ethyl Benzene
100-41-4
(tpy)
Styrene
100-42-5
(lb/year)
Styrene
100-42-5
(tpy)
Toluene
108-88-3
(lb/year)
Toluene
108-88-3
(tpy)
Methyl isobutyl ketone (Hexone)
108-10-1
(lb/year)
Methyl isobutyl ketone (Hexone)
108-10-1
(tpy)
2,4-Toluene diisocyanate
584-84-9
(lb/year)
2,4-Toluene diisocyanate
584-84-9
(tpy)
Phenol
108-95-2
(lb/year)
Phenol
108-95-2
(tpy)
Methyl Alcohol
67-56-1
(lb/year)
Methyl Alcohol
67-56-1
(tpy)SHERWIN WILLIAMS PAINT BLACK 3,079.80 1.54 32.21 0.02 111.79 0.06 0 0 27.95 0.01 0 0 391.26 0.20 0 0 0.00 0.00 0 0 0 0SHERWIN WILLIAMS K69 POLANE REDUCER 1,568.11 0.78 0.00 0.00 815.42 0.41 0 0 141.13 0.07 0 0 235.22 0.12 376.35 0.19 4.70 0.00 0 0 0 0SHERWIN WILLIAMS V66V27 CATALYST 695.03 0.35 13.38 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 556.02 0.28 0 0NICCERAKOTE[2]0.00 0.00 6.99 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0
NCS VTK 34-20001 2K URETHANE PRIMER 3,553.23 1.78 86.09 0.04 1,231.32 0.62 0 0 307.83 0.15 0 0 0 0 0 0 0.00 0.00 0 0 0 0
NCS VTK 34-20204 ACTIVATOR 1,200.38 0.60 7.88 0.00 435.40 0.22 0 0 110.66 0.06 0 0 126.99 0.06 0 0 0.00 0.00 0 0 0 0
NCS UPO714 DOLPHIN GLAZE 4,523.79 2.26 261.08 0.13 0 0 0 0 1,243.24 0.62 5,718.89 2.86 0 0 0 0 0.00 0.00 0 0 0 0NCS8984 GENERAL ADHESIVE REMOVER 242.75 0.12 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0NCSFIV 5186 FAST ACTIVATOR 97.22 0.05 1.41 0.00 0.72 0.00 2.07 1.03E-03 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0NCSFIV 5185 X-TREME 4.4 VOC CLEAR 314.42 0.16 2.86 0.00 0 0 70.80 0.04 15.79 0.01 0.87 0.00 0 0 0 0 0.00 0.00 0 0 0 0NCSFIV 5165 ORIGINAL HARDENER 83.11 0.04 1.72 0.00 54.33 0.03 0 0 6.52 0.00 0.65 0.00 0.65 0.00 0 0 0.00 0.00 0 0 0 0Sherwin Williams Garden Gate Green 1,706.68 0.85 17.00 0.01 90.94 0.05 0 0 30.31 0.02 0 0 90.94 0.05 0 0 0.00 0.00 0 0 0 0Sherwin WIlliams Grizzly Grey 410.20 0.21 4.47 0.00 18.96 0.01 0 0 7.58 0.00 0 0 21.99 0.01 0 0 0.00 0.00 0 0 0 0Sherwin Williams portobello Tan 391.75 0.20 4.89 0.00 19.32 0.01 0 0 7.73 0.00 0 0 23.18 0.01 0 0 0.00 0.00 0 0 0 0surfinNi-Black 40 0.00 0.00 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0adtechp-17 0.00 0.00 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00hardener black 0.00 0.00 2.66 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 00hardener blue 0.00 0.00 0.17 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0Total17866.48 8.93 442.81 0.22 2778.20 1.39 72.87 0.04 1898.75 0.95 5720.42 2.86 890.24 0.45 376.35 0.19 4.70 2.35E-03 556.02 0.28 0.00 0.00
2.04 0.00
rpsgroup.com Project Number:206470
Christensen Arms
Gunnison, UT
Welding
Material
Welding Wire Iron Copper Chromium Manganese Nickel LeadWelding Material (MSC) - RG60-063-10T 98.0%1%10%4%3%0%
Midwest Tungsten Service (Amazon) - B013K 0%0%0%0%0%0%
Welding Rod
[1]GTAW is assumed to be similar to GMAW SDAPCD Guidance
Actual Usage
Welding Wire lbs / year
Welding Material (MSC) - RG60-063-10T 1.00
Midwest Tungsten Service (Amazon) - B013K 1.00Welding Rod 66.00
Hours of Operation
hr/day day/wk wk/yr hr/yr
18 5 52 4680 8760
Emission Factor
Welding Material (MSC) - RG60-063-10T 5.2 lb/10000lbMidwest Tungsten Service (Amazon) - B013K 5.2 lb/10000lbWelding Rod 5.2 lb/10000lb
[1]AP-42 Table 12.19-1; Emission factors based on welding rod use: Steel E70S GMAW (no lead) and Aluminum
Note AP-42 units: PM is lb/103lb; HAPs are 10-1lb/103lb
Welding - Actual Emissions Based on Worst Case Welding Rod Factors
lb/hr lbs/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy
Welding Material (MSC) - RG60-063-10T 1.11E-07 5.20E-04 2.60E-07 1.97778E-08 9.26E-05 4.63E-08 8.89E-10 4.16E-06 2.08E-09 1.11E-08 5.20E-05 2.60E-08 4.44E-09 2.08E-05 1.04E-08 3.33E-09 1.56E-05 7.80E-09 0.00E+00 0.000 0.00E+00Midwest Tungsten Service (Amazon) - B013K 1.11E-07 5.20E-04 2.60E-07 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.000 0.00E+00Welding Rod 7.33E-06 3.43E-02 1.72E-05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.000 0.00E+00Total7.56E-06 3.54E-02 1.77E-05 1.98E-08 9.26E-05 4.63E-08 8.89E-10 4.16E-06 2.08E-09 1.11E-08 5.20E-05 2.60E-08 4.44E-09 2.08E-05 1.04E-08 3.33E-09 1.56E-05 7.80E-09 0.00E+00 0.00E+00 0.00E+00
Welding - Potential Emissions
lb/hr lbs/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpy lb/hr lb/yr tpyWelding Material (MSC) - RG60-063-10T 1.11E-07 9.73E-04 4.87E-07 1.89E-08 1.73E-04 8.66E-08 8.89E-10 7.79E-06 3.89E-09 1.11E-08 9.73E-05 4.87E-08 4.44E-09 3.89E-05 1.95E-08 3.33E-09 2.92E-05 1.46E-08 0.00E+00 0.00E+00 0.00E+00
Midwest Tungsten Service (Amazon) - B013K 1.11E-07 9.73E-04 4.87E-07 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00
Welding Rod 7.33E-06 6.42E-02 3.21E-05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00Total7.56E-06 6.62E-02 3.31E-05 1.89E-08 1.73E-04 8.66E-08 8.89E-10 7.79E-06 3.89E-09 1.11E-08 9.73E-05 4.87E-08 4.44E-09 3.89E-05 1.95E-08 3.33E-09 2.92E-05 1.46E-08 0.00E+00 0.00E+00 0.00E+00
Based on 8760 hr/yr
Copper
Actual Hours Maximum
Hours per
Year
Materials PM Total HAPs Metal
Materials PM Total HAPs Metal Copper Chromium Nickel Lead
Chromium Manganese Nickel Lead
Manganese
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTMachining
PTEhr/day day/wk wk/yr hr/yr hr/yr1855246808760
Materials Annual Purchase(lbs)
Machined Quantity(lbs/year)
Usage[1](lb/hr)Usage(lb/day)
Machined Usage(tpy)Aluminum 30,163.70 30,164 6.45 116.01 15.08Carbon89,258.67 89,259 19.07 343.30 44.63Stainless Steel 379,651.40 379,651 81.12 1460.20 189.83Titanium1,075.22 1,075 0.23 4.14 0.54Tool Steel 140.02 140 0.03 0.54 0.07Total500,148.98 500,148.98 106.87 1,923.65 250.07
[1]Purchase total based on known weights.
Emission Factor
lb/ton lb/ton lb/ton
Machining[2]0.35 0.2 0.2
[2] Conservative emission factor for SCC 3-07-008-02 used in liu of site specific dataSee EIIP Vol II Ch. 14 https://www.epa.gov/sites/default/files/2015-08/documents/ii14_july2001.pdf
Control Factor
Efficiency3 99.99%3 Efficiency based on manufacturer provided documentation
Actual Controlled Emissions
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy
Machining 1.87E-06 3.37E-05 0.01 4.38E-06 1.07E-06 1.92E-05 0.01 2.50E-06 1.07E-06 1.92E-05 0.01 2.50E-06
Potential Controlled Emissions
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyMachining1.87E-06 4.49E-05 0.02 8.19E-06 1.07E-06 2.56E-05 0.01 4.68E-06 1.07E-06 2.56E-05 0.01 4.68E-06
Potential Uncontrolled Emissions
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyMachining0.02 0.45 163.83 0.08 0.01 0.26 93.62 0.05 0.01 0.26 93.62 0.05
Materials PM PM10 PM2.5
PM10
PM10
PM2.5
PM2.5MaterialsPM
Materials PM
Actual Hours
Source PM PM10 PM2.5
rpsgroup.com Project Number:206470
Christensen ArmsGunnison, UTCombustion Equipment
Btu/hr MMBtu/hr MMCF/hr
Water Heater 1 STATE INDUSTRIES GS6-50-BCUT 400 1 40,000 0.04 3.92E-05 Exempt - 307-401-10(2)
Water Heater 2 STATE INDUSTRIES GS6-50-BCUT 400 1 40,000 0.04 3.92E-05 Exempt - 307-401-10(2)
Water Heater 3 STATE INDUSTRIES GS6-50-YBRT 1 40,000 0.04 3.92E-05 Exempt - 307-401-10(2)
Oven 1 GRIEVE B1H-900 1 400,000 0.40 3.92E-04 Exempt - 307-401-10(1)
Oven 2 GRIEVE B1H-900 1 400,000 0.40 3.92E-04 Exempt - 307-401-10(1)
Paint Booth Heater TITAN TA-120 NG VRH 1 935,900 0.94 9.18E-04 Exempt - 307-401-10(1)
Shop heater 1 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2)
Shop heater 2 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2)
Shop heater 3 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2)
Shop heater 4 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2)
Shop heater 5 ROBERTS GORDON CTH2-150 1 150,000 0.15 1.47E-04 Exempt - 307-401-10(2)Total 11 2,605,900 2.01 2.E-031NG CF=1020Btu
Maximum Hourshr/day day/wk day/yr hr/yr hr/day day/wk day/yr hr/yr hr/yr245.0 260 6240 24 7 365 8760 8760
NGF Heater- Emission Factors
VOC PM[1]PM10[1]Direct PM2.5[1]NOx CO SO2
lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scfEmission Factors 5.5 7.6 7.6 7.6 100.0 84.0 0.6
Total HAP Benzene Benzene Dichloro- benzene Formald- ehyde Hexane Toluene Lead
lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scf lb/106 scfEmission Factors 1.9 0.002 0.002 0.001 0.08 1.8 0.003 0.0005[1] PM emission factor is filterable PM only. PM10 emission factor is filterable and condensable PM10 combined.[2] Assumed most conservative NOx emissions: Flue Gas Recirculation Burners Emission Factors for NOx: Assumed NOX and N2O are not controlledEmission Factors are from AP 42, Chapter 1.4, Tables 1.4-1, 1.4-2, 1.4-3, SCC #1-02-006-02, 1-01-006-02, 1-03-006-02, and 1-03-006-03
NGF Heaters - Calculated Actual Emissions
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 1.3 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 24.5 <0.1Water Heater 2 <0.1 <0.1 1.3 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 24.5 <0.1Water Heater 3 <0.1 <0.1 1.3 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 24.5 <0.1Oven 1 <0.1 <0.1 13.5 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 0.9 244.7 0.1Oven 2 <0.1 <0.1 13.5 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 <0.1 18.6 <0.1 <0.1 0.9 244.7 0.1Paint Booth Heater <0.1 0.1 31.5 <0.1 <0.1 0.2 43.5 <0.1 <0.1 0.2 43.5 <0.1 <0.1 0.2 43.5 <0.1 <0.1 2.2 572.6 0.3
Shop heater 1 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Shop heater 2 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Shop heater 3 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1
Shop heater 4 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Shop heater 5 <0.1 <0.1 5.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 <0.1 7.0 <0.1 <0.1 0.4 91.8 <0.1Total<0.1 0.3 87.7 <0.1 <0.1 0.5 121.2 <0.1 <0.1 0.5 121.2 <0.1 <0.1 0.5 121.2 <0.1 0.3 6.1 1,594.2 0.8[1]Actual gas usage not available; use actual = potential at 8760 hr/yr
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 20.6 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 <0.1 <0.1 <0.1 0.4 <0.1
Water Heater 2 <0.1 <0.1 20.6 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 <0.1 <0.1 <0.1 0.4 <0.1Water Heater 3 <0.1 <0.1 20.6 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 <0.1 <0.1 <0.1 0.4 <0.1Oven 1 <0.1 0.8 205.6 0.1 <0.1 <0.1 1.5 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 4.6 <0.1 <0.1 <0.1 4.4 <0.1
Oven 2 <0.1 0.8 205.6 0.1 <0.1 <0.1 1.5 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 4.6 <0.1 <0.1 <0.1 4.4 <0.1Paint Booth Heater <0.1 1.8 480.9 0.2 <0.1 <0.1 3.4 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 10.8 <0.1 <0.1 <0.1 10.3 <0.1Shop heater 1 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1
Shop heater 2 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Shop heater 3 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Shop heater 4 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Shop heater 5 <0.1 0.3 77.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.7 <0.1 <0.1 <0.1 1.7 <0.1Total 0.2 5.2 1,339.1 0.7 <0.1 <0.1 9.6 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 30.0 <0.1 <0.1 0.1 28.7 <0.10.014348
Actual Hours Maximum Hours
Equipment Manufacturer Model Number of Units Rating1 Permit Applicability?
Natural Gas Emission Factors
Natural Gas Emission Factors - Continued
Emission Factors are from AP 42, Table 1.4-2 SCC #1-02-006-02, 1-01-006-02, 1-03-006-02, and 1-03-006-03.
Natural Gas Heating Units VOC PM PM10 PM2.5 NOx
Natural Gas Heating Units CO SO2 Lead Total HAPs Single HAP
Christensen ArmsGunnison, UTCombustion EquipmentNGF Heaters - Potential Emissions
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 34.4 <0.1Water Heater 2 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 34.4 <0.1
Water Heater 3 <0.1 <0.1 1.9 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 2.6 <0.1 <0.1 <0.1 34.4 <0.1Oven 1 <0.1 <0.1 18.9 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 0.9 343.5 0.2Oven 2 <0.1 <0.1 18.9 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 <0.1 26.1 <0.1 <0.1 0.9 343.5 0.2
Paint Booth Heater <0.1 0.1 44.2 <0.1 <0.1 0.2 61.1 <0.1 <0.1 0.2 61.1 <0.1 <0.1 0.2 61.1 <0.1 <0.1 2.2 803.8 0.4Shop heater 1 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1Shop heater 2 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1
Shop heater 3 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1Shop heater 4 <0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1D7CG036N07946A<0.1 <0.1 7.1 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 <0.1 9.8 <0.1 <0.1 0.4 128.8 <0.1Total<0.1 0.3 123.1 <0.1 <0.1 0.5 170.1 <0.1 <0.1 0.5 170.1 <0.1 <0.1 0.5 170.1 <0.1 0.3 6.1 2,238.0 1.1
lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpy lb/hr lb/day lb/yr tpyWater Heater 1 <0.1 <0.1 28.9 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 0.6 <0.1Water Heater 2 <0.1 <0.1 28.9 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 0.6 <0.1Water Heater 3 <0.1 <0.1 28.9 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 <0.1 <0.1 0.6 <0.1Oven 1 <0.1 0.8 288.6 0.1 <0.1 <0.1 2.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6.5 <0.1 <0.1 <0.1 6.2 <0.1Oven 2 <0.1 0.8 288.6 0.1 <0.1 <0.1 2.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6.5 <0.1 <0.1 <0.1 6.2 <0.1Paint Booth Heater <0.1 1.8 675.2 0.3 <0.1 <0.1 4.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 15.1 <0.1 <0.1 <0.1 14.5 <0.1Shop heater 1 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1
Shop heater 2 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1Shop heater 3 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1Shop heater 4 <0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1D7CG036N07946A<0.1 0.3 108.2 <0.1 <0.1 <0.1 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 <0.1 <0.1 2.3 <0.1Total 0.2 5.2 1,879.9 0.9 <0.1 <0.1 13.4 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 42.2 <0.1 <0.1 0.1 40.3 <0.1
NGF Heaters - Actual GHG Emissions
Water Heater 1 249.6 53.06 0.001 0.0001 0.001 13 2.50E-04 2.50E-05 13Water Heater 2 249.6 54.06 0.001 0.0001 0.001 13 2.50E-04 2.50E-05 14Water Heater 3 249.6 55.06 0.001 0.0001 0.001 14 2.50E-04 2.50E-05 14Oven 1 2496 56.06 0.001 0.0001 0.001 140 2.50E-03 2.50E-04 140Oven 2 2496 57.06 0.001 0.0001 0.001 142 2.50E-03 2.50E-04 143Paint Booth Heater 5840.016 58.06 0.001 0.0001 0.001 339 5.84E-03 5.84E-04 339Shop heater 1 936 59.06 0.001 0.0001 0.001 55 9.36E-04 9.36E-05 55Shop heater 2 936 60.06 0.001 0.0001 0.001 56 9.36E-04 9.36E-05 56Shop heater 3 936 61.06 0.001 0.0001 0.001 57 9.36E-04 9.36E-05 57Shop heater 4 936 62.06 0.001 0.0001 0.001 58 9.36E-04 9.36E-05 58D7CG036N07946A93663.06 0.001 0.0001 0.001 59 9.36E-04 9.36E-05 59Total16260.816 638.66 0.01 0.00 0.01 947.66 0.02 1.63E-03 948.55
NGF Heaters - Potential GHG Emissions
Water Heater 1 350.4 53.06 0.001 0.0001 0.001 19 3.50E-04 3.50E-05 19Water Heater 2 350.4 54.06 0.001 0.0001 0.001 19 3.50E-04 3.50E-05 19Water Heater 3 350.4 55.06 0.001 0.0001 0.001 19 3.50E-04 3.50E-05 19Oven 1 3504 56.06 0.001 0.0001 0.001 196 3.50E-03 3.50E-04 197Oven 2 3504 57.06 0.001 0.0001 0.001 200 3.50E-03 3.50E-04 200Paint Booth Heater 8198.484 58.06 0.001 0.0001 0.001 476 8.20E-03 8.20E-04 476Shop heater 1 1314 59.06 0.001 0.0001 0.001 78 1.31E-03 1.31E-04 78Shop heater 2 1314 60.06 0.001 0.0001 0.001 79 1.31E-03 1.31E-04 79Shop heater 3 1314 61.06 0.001 0.0001 0.001 80 1.31E-03 1.31E-04 80Shop heater 4 1314 62.06 0.001 0.0001 0.001 82 1.31E-03 1.31E-04 82D7CG036N07946A131463.06 0.001 0.0001 0.001 83 1.31E-03 1.31E-04 83Total22827.684 638.66 0.01 0.00 0.01 1,330.37 0.02 2.28E-03 1,331.62
Single HAP - Hexane
Natural Gas Heating Units VOC PM PM10 PM2.5 NOx
Natural Gas Heating Units CO SO2 Lead Total HAPs
Natural Gas Heating Units
Potential Natural Gas Usage(mmbtu/year)
CO2e Emissions(metric tons)
N2O Emissions(metric tons)
CH4 Emissions(metric tons)
CO2 Emissions(metric tons)
Conversion(Metric tons/kg)
N2O EF(kg CO2/mmBtu)
CH4 EF(kg CO2/mmBtu)
CO2 EF(kg CO2/mmBtu)
Natural Gas Heating Units
Potential Natural Gas Usage(mmbtu/year)
CO2 EF(kg CO2/mmBtu)
CH4 EF(kg CO2/mmBtu)
N2O EF(kg CO2/mmBtu)
Conversion(Metric tons/kg)
CO2 Emissions(metric tons)
CH4 Emissions(metric tons)
N2O Emissions(metric tons)
CO2e Emissions(metric tons)
Christensen Arms
Gunnison, UT
Firing Range
PTE
hr/day day/wk wk/yr hr/yr hr/yr1855246808760
Material Usage
Materials
Actual
Annual Purchase
Actual Quantity
Maximu
m Quantity UOM
FACTORY AMMO 60027 RNDS 60,027 112,358 rounds
POWDER 26 LBS 26 49 lbsBRASS3140 EA 3,140 5,877 eachBULLETS3500 EA 3,500 6,551 each
Total 63,527 118,910 Rounds
Emission Factors[1]
PM[2]lb/item PM2.5lb/item PM10lb/item COlb/item NOxlb/item Leadlb/item8.60E-05 5.80E-05 8.20E-05 3.00E-03 4.10E-05 5.00E-06
[1] Emission factors from Table 15.1.16-1 of AP-42
[2]TSP used in lieu of PM
Actual Emissions
PM
lb/year
PM
tpy
PM2.5
lb/year
PM2.5
tpy
PM10
lb/year
PM10
tpy
CO
lb/year
CO
tpy
NOx
lb/year
NOx
tpy
Lead
lb/year
Lead
tpy5.46 0.00 3.68 1.84E-03 5.21 2.60E-03 190.58 0.10 2.60 1.30E-03 0.32 1.59E-04
Potential Emissions
PM
lb/year
PM
tpy
PM2.5
lb/year
PM2.5
tpy
PM10
lb/year
PM10
tpy
CO
lb/year
CO
tpy
NOx
lb/year
NOx
tpy
Lead
lb/year
Lead
tpy10.23 0.01 6.90 3.45E-03 9.75 4.88E-03 356.73 0.18 4.88 2.44E-03 0.59 2.97E-04
Actual Hours
rpsgroup.com Project Number:206470
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX D
BACT Analysis
APPROVAL ORDER MODIFICATION APPLICATION
rpsgroup.com Project Number: 220197
BACT ANALYSIS
The following emission sources are operated at the facility:
• Solvent Use
• Mold Release
• Epoxy Resin
• Lubricant Usage
• Adhesive
• Paint Booth
• Blasting
• Welding
• Metal Machining
• Range
The primary emission unit at the facility are three (3) paint booths which generates particulate matter (PM)
and volatile organic compound (VOC) emissions. The following sources were reviewed to identify available
control technologies:
• EPA's RBLC Database
• EPA’s Air Pollution Technology Fact Sheets
Paint Booth - VOC
Step 1 – Potential Control Technologies
The following control technologies were identified:
• Adsorption Systems
• Regenerative Thermal Oxidation (RTO)
• Catalytic Oxidation (CO)
• Best Management Practices
Step 2 – Technical Feasibility of Control Technologies
Adsorption Systems
Adsorption systems direct dilute concentrations of VOC streams through an adsorption material such as
activated carbon or zeolite. The material adsorbs VOC from the stream. Because VOCs can be desorbed,
adsorption systems are frequently used in conjunction with VOC incinerators or concentrators. VOC
adsorption systems can achieve a VOC control efficiency of 95%-98% if the VOC input concentration is
between 500 and 2000 parts per million (ppm). Solids in the waste stream that may coat the carbon
decrease the efficiency of the VOC removal. Carbon cannot be used for certain compounds such as
ketones and aldehydes because the exothermic adsorption reaction can cause fires. Compounds with
boiling points above 200°F (such as Toluene) do not adequately desorb from the carbon, causing significant
capacity reduction after repeated regeneration cycles. For this reason, adsorption systems may work, but
are not ideal for paint booths.
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Regenerative Thermal Oxidation
RTO technology destroys VOC by heating the incoming VOC stream and combusting it. Typically, the gas
stream is filtered through a ceramic medium which heats the gas stream to around 1500 degrees
Fahrenheit. The gas stream is then directed to the combustion chamber where natural gas is used to
combust the VOCs. RTOs are most efficient when used on a high volume, low VOC gas stream. Control
efficiencies range from 95% to 98%.
Catalytic Oxidation
CO systems convert VOC to carbon dioxide and water. CO systems utilize a catalyst, allowing oxidation to
occur at a temperature between 650- and 1000-degrees Fahrenheit. VOC streams are heated in a mixing
chamber and/or a heat exchanger. VOC and oxygen are adsorbed onto a catalyst where oxidation occurs.
The oxidation byproducts are then desorbed back in the exhaust stream. Control efficiencies range from
95% to 98% for exhaust streams with constant concentrations. Catalysts typically consist of a ceramic or
metallic substrate with a thin coating of noble metal (i.e., platinum or palladium). Careful attention must be
paid to gas stream constituents and properties. Wide variation in VOC content can cause temperature
swings and lead to sintering of the catalyst. Due to the nature of paint booth operations, VOC
concentrations are not constant, making CO systems not technically feasible.
Best Management Practices
Best management practices minimize emissions by instituting operational and maintenance controls. Best
management practices include keeping all VOC storing containers closed when not in use. The use of a
high-volume low-pressure spray gun (HVLP) reduces the amount of overspray, which reduces the amount
of VOC containing material used.
Step 3 – Ranking of Control Technologies
Based on the efficiencies of the identified controls, the controls were ranked as follows:
1. RTO
2. Best Management Practices
3. Adsorption System
4. CO
Step 4 – Evaluation of most effective controls
Economic Impacts
The US EPA Air Pollution Control Cost Manual provides guidance on estimating the capital and annual cost
of control systems. Site specific parameters were used where possible, including the emissions rate and
exhaust characteristics. Detailed cost calculations for each control can be found in the attachment to this
analysis.
• Adsorption System - $17,600 to $17,700 per ton of VOC
• RTO - $46,500 per ton of VOC
• CO - $89,500 to $94,000 per ton of VOC
• Best Management Practice - $0 per metric ton
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Environmental Impacts
Each control system has its own environmental impact, affecting the overall effectiveness of the control.
Adsorption systems require the collected VOC to be desorbed and discharged to a wastewater treatment
system or be handled as waste. While RTO and CO systems destroy the VOC, thereby eliminating the need
to manage waste VOC, fuel is required to start and maintain the VOC destruction, resulting in additional
pollutants being emitted.
Step 5 – BACT Selection
Because the paint booth actual VOC emissions are less than five tons per year, implementing best
management practices to reduce VOC emissions is the most efficient and cost-effective control.
Paint Booth - PM
Step 1 – Potential Control Technologies
The following control technologies were identified:
• Fabric filters/ Baghouse
• Dry filter
• Best Management Practices
While other PM controls are on the market, no other PM controls were identified for paint booths in the RBLC
database.
Step 2 – Technical Feasibility of Control Technologies
Fabric Filters/ Baghouse
Baghouses remove particulates by collecting particulates on the filter bag as the exhaust stream passes
through the baghouse. Baghouses typically cannot withstand high exhaust temperatures (greater than 500
°F). Fabric filters have been considered effective for medium and low gas flow streams with high particulate
concentrations. Baghouses have been shown to obtain a particulate collection efficiency up to 99.5% for
PM10, and up to 99% capture for PM2.5.
Dry Filter
Dry filters also remove PM by directing exhaust through the filter. Particulates collect on the filter while clean
air exits through the stack. Dry filters are best for low-capacity air flow compared to fabric filter use.
Efficiencies vary based on the type of dry filter. The facility currently utilizes a Minimum Efficiency Reporting
Values (MERV) 8 filter which has an 84.9% filter efficiency according to EPA guidance.
Step 3 – Ranking of Control Technologies
Based on the efficiencies of the identified controls, the controls were ranked as follows:
1. Fabric Filter/ Baghouse
2. Dry Filter
APPROVAL ORDER MODIFICATION APPLICATION
rpsgroup.com Project Number: 220197
Step 4 – Evaluation of most effective controls
Environmental Impacts
Control efficiencies impact the quantity of particulate matter emitted. Both Fabric filter and dry filter control
technologies results in particulate matter waste.
Economic Impacts
The EPA CACT Air Pollution Technology Fact Sheets and Technical Bulletins (EPA Fact Sheets) calculates
the cost effectiveness of various control technologies. The EPA Fact Sheet for HEPA filters was used to
represent dry filter cost in lieu of and EPA Fact Sheet applicable to all dry filters.
•Fabric Filter - $46 to $293 per metric ton
•Dry Filter - $6,400 to $8,500 per sm3/s
Because the facility already has a dry filter installed, there are no capital costs associated with a dry filter.
Step 5 – BACT Selection
The currently installed dry filter is an efficient and cost-effective control. Because the magnitude of PM
emissions is well below half a ton per year, it is not cost efficient to spend additional capital expenditure to
minimally reduce the total PM emissions.
All Other Emission Sources – Various Pollutants
The other emission sources combined represent less than three tons per year of criteria pollutants. Because
each individual emission source represents a small portion of total emissions, the installation of control
technology for any one source would not be a cost-effective control option. Instead, best management
practices will be used to minimize emissions from each of the following sources:
•Solvent Use
•Mold Release
•Epoxy Resin
•Lubricant Usage
•Adhesive
•Blasting
•Welding
•Metal Machining
•Range
Best management practices include the following:
•Ensuring all lids to VOC containing material are kept closed when not in use
•Minimize material use and operations as possible
•Train employees on material efficient practices and emissions minimization
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX E
RBLC Data Base & Supporting Documentation
COMPREHENSIVE REPORT
Report Date:02/11/2021
Facility Information
RBLC ID:IN-0310 (final)Date Determination
Last Updated:02/19/2019
Corporate/Company Name:FOREST RIVER, INC., COLLEGE AVENUE COMPLEX Permit Number:039-39722-00011
Facility Name:FOREST RIVER, INC., COLLEGE AVENUE COMPLEX Permit Date:12/07/2018 (actual)
Facility Contact:FRS Number:110022525739
Facility Description:Stationary custom recreational vehicle and bus manufacturing complex.SIC Code:3792
Permit Type:C: Modify process at existing facility NAICS Code:336214
Permit URL:https://permits.air.idem.in.gov/39722f.pdf
EPA Region:5 COUNTRY:USA
Facility County:ELKHART
Facility State:IN
Facility ZIP Code:46526-5022
Permit Issued By:INDIANA DEPT OF ENV MGMT, OFC OF AIR (Agency Name)
MR. MATT STUCKEY(Agency Contact) (317) 233-0203 mstuckey@idem.in.gov
Permit Notes:
Facility-wide Emissions:Pollutant Name:Facility-wide Emissions Increase:
Carbon Monoxide 6.7300 (Tons/Year)
Nitrogen Oxides (NOx)8.0100 (Tons/Year)
Particulate Matter (PM)204.8900 (Tons/Year)
Sulfur Oxides (SOx)0.0500 (Tons/Year)
Volatile Organic Compounds (VOC)1599.7300 (Tons/Year)
Process/Pollutant Information
PROCESS NAME:FE-16 (Plant 420)
Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput:0
Process Notes:
Christensen Arms AO Modification 9/7/23
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number:VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:99.9900 TPY
Emission Limit 2:6.5000 LBS/GAL
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:
Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best
management practices for VOC
Est. % Efficiency:
Cost Effectiveness:127704 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Process/Pollutant Information
PROCESS NAME:FE-13 (Plant 3)
Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput:0
Process Notes:
POLLUTANT NAME:Volatile Organic Compounds (VOC)
CAS Number:VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:99.9900 TPY
Emission Limit 2:6.5000 LBS/GAL
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Christensen Arms AO Modification 9/7/23
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:
Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best
management practices for VOC
Est. % Efficiency:
Cost Effectiveness:127704 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Process/Pollutant Information
PROCESS NAME:FE-14c (Plant 44)
Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput:0
Process Notes:
POLLUTANT NAME:Volatile Organic Compounds (VOC)
CAS Number:VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:99.9900 TPY
Emission Limit 2:6.5000 LBS/GAL
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:
Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best
management practices for VOC
Est. % Efficiency:
Cost Effectiveness:127704 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Christensen Arms AO Modification 9/7/23
Process/Pollutant Information
PROCESS NAME:FE-14d (Plant 27)
Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput:0
Process Notes:
POLLUTANT NAME:Volatile Organic Compounds (VOC)
CAS Number:VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:99.9900 TPY
Emission Limit 2:6.5000 LBS/GAL
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:
Control Method:(P) Total VOC input: 99.99 tpy Cleaners and solvents limit: 6.5 lbs/gal Use HVLP spray applicators Best
management practices for VOC
Est. % Efficiency:
Cost Effectiveness:127704 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Facility Information
RBLC ID:IN-0309 (final)Date Determination
Last Updated:02/19/2019
Corporate/Company Name:GRAND DESIGN RV Permit Number:039-40105-00747
Facility Name:GRAND DESIGN RV Permit Date:11/30/2018 (actual)
Facility Contact:FRS Number:110041067733
Christensen Arms AO Modification 9/7/23
Facility Description:Stationary travel trailers and campers facility. SIC Code:3792
Permit Type:C: Modify process at existing facility NAICS Code:336214
Permit URL:https://permits.air.idem.in.gov/40105f.pdf
EPA Region:5 COUNTRY:USA
Facility County:ELKHART
Facility State:IN
Facility ZIP Code:46540-9632
Permit Issued By:INDIANA DEPT OF ENV MGMT, OFC OF AIR (Agency Name)
MR. MATT STUCKEY(Agency Contact) (317) 233-0203 mstuckey@idem.in.gov
Permit Notes:
Facility-wide Emissions:Pollutant Name:Facility-wide Emissions Increase:
Carbon Monoxide 11.7800 (Tons/Year)
Nitrogen Oxides (NOx)14.0200 (Tons/Year)
Particulate Matter (PM)160.3300 (Tons/Year)
Sulfur Oxides (SOx)0.0800 (Tons/Year)
Volatile Organic Compounds (VOC)754.4100 (Tons/Year)
Process/Pollutant Information
PROCESS NAME:RV-6 Line 1
Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput:0
Process Notes:
POLLUTANT NAME:Volatile Organic Compounds (VOC)
CAS Number:VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:30.0000 TPY
Emission Limit 2:6.5000 LBS/GALLON
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: Y
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:
Christensen Arms AO Modification 9/7/23
Control Method:(P) Total VOC usage shall be less than 30 tpy. VOC content limit for adhesives, sealants, glue, and cleaning
materials shall not exceed 6.5 lbs/gallon.
Est. % Efficiency:
Cost Effectiveness:504219 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Facility Information
RBLC ID:OH-0371 (final) Date Determination
Last Updated:06/19/2019
Corporate/Company Name:SCHLAGE LOCK COMPANY LLC Permit Number:P0122993
Facility Name:SCHLAGE LOCK COMPANY LLC Permit Date:09/26/2017 (actual)
Facility Contact:MATTHEW PORTER (513)766-4639 MATTHEW.PORTER@ALLEGION.COM FRS Number:110070283008
Facility Description:Manufacturer of Steel Doors SIC Code:3442
Permit Type:C: Modify process at existing facility NAICS Code:332321
Permit URL:
EPA Region:5 COUNTRY:USA
Facility County:HAMILTON
Facility State:OH
Facility ZIP Code:45242
Permit Issued By:OHIO ENVIRONMENTAL PROTECTION AGENCY (Agency Name)
MICHAEL MALESKI(Agency Contact) (614) 644-3613 Michael.Maleski@epa.ohio.gov
Permit Notes:PSD major modification of Frame Flow Coater Paint Line, K013
Facility-wide Emissions: Pollutant Name:Facility-wide Emissions Increase:
Volatile Organic Compounds (VOC)60.0000 (Tons/Year)
Process/Pollutant Information
PROCESS NAME: Door Frame Line (K013)
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput: 0
Christensen Arms AO Modification 9/7/23
Process Notes:Frame Flow Coater Paint Line for miscellaneous metal parts. Includes natural-gas fired curing oven.
POLLUTANT NAME:Volatile Organic Compounds (VOC)
CAS Number:VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:60.0000 T/YR PER ROLLING 12 MONTH PERIOD
Emission Limit 2:3.5000 LB/GAL SEE NOTES.
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(P) VOC content restrictions, VOC input limitations, and the use of a flow coater.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:SIP: The VOC content for each extreme performance coating employed in this emissions unit shall not exceed
3.5 pounds of VOC per gallon of coating, excluding water and exempt solvents, as applied.
Facility Information
RBLC ID:KY-0109 (final)Date
Determination
Last Updated:01/25/2021
Corporate/Company
Name:
FRITZ WINTER NORTH AMERICA, LP Permit
Number:
V-16-022 R1
Facility Name:FRITZ WINTER NORTH AMERICA, LP Permit Date:10/24/2016
(actual)
Facility Contact:DANIEL NEW 270-813-4000 DANIEL.NEW@FRITZWINTER.US FRS Number:Not Found
Facility Description:This facility consists of a gray iron foundry, casting, and machining operation that produces automotive parts in
Simpson County, Kentucky. The facility comprises an approximately 95 acre site, consisting of scrap handling and
preparation equipment, melt furnaces, sand and mineral storage, mixing and handling equipment, mold and core
making facilities, casting equipment, and finishing facilities where castings are machined and coated. Once the
planned two-phase construction is complete, the facility will be capable of producing 91,586 tons of gray iron for
pouring and 3.5 million automotive brake rotors per year.
SIC Code:3321
Christensen Arms AO Modification 9/7/23
Permit Type:A: New/Greenfield Facility NAICS Code:331511
Permit URL:http://dep.gateway.ky.gov/eSearch/Search_AI_Detail.aspx?AgencyID=129745
EPA Region:4 COUNTRY:USA
Facility County:SIMPSON
Facility State:KY
Facility ZIP Code:42134
Permit Issued By:KENTUCKY DEP, DIV FOR AIR QUALITY (Agency Name)
MR. RICK SHEWEKAH, MGR(Agency Contact) (502)564-3999 Sreenivas.Kesaraju@ky.gov
Other Agency
Contact Info:
Permit Reviewer: Amy Tempus-Doom
Email: Amy.Tempus-Doom@ky.gov
Phone: 502-782-6786
Permit Notes:Source Agency Interest Number: 129745 Initial Activity Number: APE20160001 This permit was issued, and then revised prior to beginning
construction. The RBLC entry only include the revised limits. Revision Activity Number: APE20160004 Revision issued November 25, 2017.
Affected Boundaries: Boundary Type:Class 1 Area State:Boundary:Distance:
CLASS1 GA Cohutta > 250 km
CLASS1 NC Great Smoky Mountains NP > 250 km
CLASS1 TN Joyce Kilmer-Slickrock > 250 km
CLASS1 KY Mammoth Cave NP < 100 km
CLASS1 MO Mingo > 250 km
Facility-wide
Emissions:
Pollutant Name:Facility-wide Emissions Increase:
Carbon Monoxide 296.8100 (Tons/Year)
Nitrogen Oxides (NOx)28.7000 (Tons/Year)
Particulate Matter (PM)42.7000 (Tons/Year)
Sulfur Oxides (SOx)1.4900 (Tons/Year)
Volatile Organic Compounds (VOC)80.7400 (Tons/Year)
Process/Pollutant Information
PROCESS NAME:Scrap Drying (EU03)
Process Type:19.600 (Misc. Boilers, Furnaces, Heaters)
Primary Fuel:Natural Gas
Throughput:60.12 MMscf/yr
Process Notes:
POLLUTANT NAME:Particulate matter, filterable (FPM)
CAS Number:PM
Test Method:EPA/OAR Mthd 5
Christensen Arms AO Modification 9/7/23
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0130 LB/H
Emission Limit 2:0.0600 T/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:NESHAP , SIP , OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The scrap drying process (EU03) will produce particulates from natural gas combustion, only. Since the dryer
heats ambient air and blows it across clean scrap to evaporate any moisture, no particulate from the drying itself
is expected. Emission factors used in calculating potential from this equipment are from AP-42, Chapter 1.4, for
natural gas combustion. The emissions are uncontrolled and do not pass through the melt shop baghouse.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0520 LB/H
Emission Limit 2:0.2300 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:NESHAP , OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
Christensen Arms AO Modification 9/7/23
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The scrap drying process (EU03) will produce particulates from natural gas combustion, only. Since the dryer
heats ambient air and blows it across clean scrap to evaporate any moisture, no particulate from the drying itself
is expected. Emission factors used in calculating potential from this equipment are from AP-42, Chapter 1.4, for
natural gas combustion.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0520 LB/H
Emission Limit 2:0.2300 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT , NESHAP
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Christensen Arms AO Modification 9/7/23
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The scrap drying process (EU03) will produce particulates from natural gas combustion, only. Since the dryer
heats ambient air and blows it across clean scrap to evaporate any moisture, no particulate from the drying itself
is expected. Emission factors used in calculating potential from this equipment are from AP-42, Chapter 1.4, for
natural gas combustion.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:0.0380 LB/H
Emission Limit 2:0.1700 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Potential emissions of VOC from natural gas-fueled burners are based on emission factors from AP-42, Chapter
1.4, Natural Gas Combustion.
POLLUTANT NAME: Carbon Monoxide
Christensen Arms AO Modification 9/7/23
CAS Number: 630-08-0
Test Method:Unspecified
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:0.5800 LB/H
Emission Limit 2:2.5200 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Potential emissions of CO from natural gas-fueled burners are based on emission factors from AP-42, Chapter
1.4, Natural Gas Combustion.
Process/Pollutant Information
PROCESS
NAME:
Foundry Operations - NG Combustion Processes [EU04, EU05, EU06, EU11, EU12, EU15, EU16, EU18, EU44, EU45, EU46, EU47, EU52)
Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters)
Primary Fuel: Natural Gas
Throughput: 0 MMscf/yr
Process Notes: Natural Gas Combustion Processes: Scrap Cleaning (EU04), Refractory Burners #1 & #2 (EU05 & EU06) Holding Furnaces #1 & #2 (EU11 & EU12),
Pouring Furnaces #1 & #2 (EU15 & EU16), Refractory Curing Mobile Burner (EU18), Dryers #1 - #4 (EU44, EU45, EU46, & EU47), and Cooling
Tunnel (EU52).
Christensen Arms AO Modification 9/7/23
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:Unspecified
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measuresChristensen Arms AO Modification 9/7/23
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Christensen Arms AO Modification 9/7/23
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Christensen Arms AO Modification 9/7/23
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Within 90 days of startup, a good combustion and operation practices plan (GCOP) that defines, measures
and verifies the use of operational and design practices determined as BACT for minimizing CO, VOC, PM,
PM10, and PM2.5 emissions. Any revisions requested by the Division shall be made and the plan shall be
maintained on site. The permittee shall operate according to the provisions of this plan at all times, including
periods of startup, shutdown, and malfunction. The plan shall be incorporated into the plant standard operating
procedures (SOP) and shall be made available for the Division’s inspection. The plan shall include, but not be
limited to: i. A list of combustion optimization practices and a means of verifying the practices have occurred. ii.
A list of combustion and operation practices to be used to lower energy consumption and a means of verifying the
practices have occurred. iii. A list of the design choices determined to be BACT and verification that designs
were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Process/Pollutant Information
PROCESS
NAME:
Pouring Station #1 & #2 (EU50 & EU51)
Process Type: 81.450 (Casting & Pouring Processes)
Primary Fuel: Natural Gas
Throughput: 45793.00 ton gray iron/year, each
Process
Notes:
Molds are moved to the pouring and cooling area via a conveyor where the casting takes place along one continuous line. Molds are brought to the
pouring furnaces on a rail system. The furnace is tilted and the molten material flows into the mold. The extreme heat of the material contacting carbon in
the mold causes volatile organic compounds (VOCs) and carbon monoxide (CO) to be generated. These gases escape through vents designed into the
mold and auto ignite due to the extreme heat. Natural gas pilot burners are placed around the mold conveyor to ensure vent gases ignite and burn off
pollutants.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:
Christensen Arms AO Modification 9/7/23
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) The permittee shall install two natural gas burners along the conveyor downstream of the pouring station
(EU50 and EU51). These burners shall be oriented such that they ignite the vents of the mold assemblies in the
event that they are not already burning.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:Unspecified
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) The permittee shall install two natural gas burners along the conveyor downstream of the pouring station
(EU50 and EU51). These burners shall be oriented such that they ignite the vents of the mold assemblies in the
event that they are not already burning.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Process/Pollutant Information
Christensen Arms AO Modification 9/7/23
PROCESS
NAME:
Foundry Operation Silos (EU17, EU19, EU20, EU21, EU35A, EU35B, EU57, EU58, & EU63)
Process Type: 81.490 (Other Iron Foundry Processes)
Primary Fuel:
Throughput: 91586.00 ton gray iron/yr
Process Notes: These silos are for various foundry operations, each controlled with a bin vent filter and any limits apply to each one individually: Melt Shop Baghouse
Waste Dust Silo (EU17), Mold Silica Sand Silo (EU19), Blend Silo (EU20), Bentonite Silo (EU21), Core Silica Sand Silos A & B (EU35A & EU35B),
Sand Plant Waste Silo (EU57), Mold Shop Baghouse Waste Dust Silo (EU58), Fettling Baghouse Waste Dust Silo (EU63).
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0150 LB/HR
Emission Limit 2:0.0670 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(A) Bin vent filter with grain loading of 0.0030 for PM. 100% capture.
Est. % Efficiency:99.710
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must be certified to meet a grain loading of 0.0030 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0150 LB/HR
Emission Limit 2:0.0670 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Christensen Arms AO Modification 9/7/23
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Bin vent filter with grain loading of 0.0030 for PM10. 100% capture.
Est. % Efficiency:99.400
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Bin vent filter must be certified to meet a grain loading of 0.0030 for PM10.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0090 LB/HR
Emission Limit 2:0.0400 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Bin vent filter with grain loading of 0.0018 for PM2.5. 100% capture.
Est. % Efficiency:99.210
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must be certified to meet a grain loading of 0.0018 gr/dscf for PM2.5.
Process/Pollutant Information
PROCESS
NAME:
Shakeout Conveyor (EU53)
Process
Type:
81.460 (Shake Out Processes)
Primary
Fuel:
Throughput: 91586.00 ton gray iron/yr
Christensen Arms AO Modification 9/7/23
Process
Notes:
Once the castings solidify, the mold frames are opened and the mold enters the shakeout conveyor where the mold is broken and the castings are
separated. The shakeout conveyor also breaks off the sprues left over from the casting. Sprues are created in the pathways that allow the molten material
to flow into the mold. When the mold is cooled any material in the pathways solidifies, too. The sprues are broken off and magnetically collected so they
can be sent back to the melt shop for use as internal scrap. Sand from the shakeout conveyor is collected and routed through a screening sieve and sand
cooler where air and water cool and hydrate the sand to the desired temperature and moisture content. Most of the sand is recycled back into the green
sand mixing process. Approximately 5 percent, however, must be removed to prevent build-up of left over core sand binder (resins) decomposition
byproducts. Waste sand is kept in a silo until it is shipped off site for disposal. Emissions from the shakeout conveyor and the sand separation and
recycling processes are vented to the sand plant baghouse (CU06) that exhausts through a stack (ST07).
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:EPA/OAR Mthd 10
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:1.0000 LB/TON
Emission Limit 2:25.3000 LB/H
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Mold Vent Auto-Ignition
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:These emissions are created from incomplete combustion of gases generated during pouring of the hot iron into
the mold and oxidizing the carbon in the green sand and the organic binder present in the core.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 25
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:0.0380 LB/HR
Emission Limit 2:0.1700 TON/YR
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT Christensen Arms AO Modification 9/7/23
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) Mold Vent Auto-Ignition
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:These emissions are created from incomplete combustion of gases generated during pouring of the hot iron into
the mold and oxidizing the carbon in the green sand and the organic binder present in the core.
Process/Pollutant Information
PROCESS
NAME:
Paint Booths #1, #2, and #3 (EU68, EU69, EU70)
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput: 28.90 lb post-induction coating/hr, each
Process Notes: After machining, each brake rotor is coated with zinc. The castings are heated through induction before passing through a paint booth to receive the
coating, and then enter a cooling unit. All paint booths are fitted with individual filters. Each of these paint booths are equipped with electrostatic spray
nozzles that achieve at least 70% transfer efficiency.
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:EPA/OAR Mthd 5
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.3630 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70)
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating
delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100%
efficiency. The permittee shall use fabric filters.
Est. % Efficiency:99.900
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Christensen Arms AO Modification 9/7/23
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of
post-induction coating on a rolling 12-month basis.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.3630 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70)
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating
delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100%
efficiency. The permittee shall use fabric filters.
Est. % Efficiency:99.900
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of
post-induction coating on a rolling 12-month basis.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:EPA/OAR OTM 27 and Mthd 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.3630 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70)
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating
Christensen Arms AO Modification 9/7/23
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.87 lb/lb of coating
delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100%
efficiency. The permittee shall used fabric filters.
Est. % Efficiency:99.900
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of
post-induction coating on a rolling 12-month basis.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:3.5000 LB/GAL COATING LESS WATER, EXEMPT SOLVENTS, OR BOTH
Emission Limit 2:25.7000 TONS/YR 12-MONTH ROLLING COMBINED (EU68-EU70)
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(P) The permittee shall, within 90 days of startup, develop and implement a work practice plan to minimize VOC
emissions from the storage, mixing, and conveying of coatings, thinners, and cleaning materials used in, and
waste materials generated by, all coating operations. The plan shall specify practices and procedures to ensure
that, at a minimum, the following elements are implemented: i. All VOC-containing coatings, thinners, cleaning
materials, and waste materials shall be stored in closed containers. ii. The risk of spills of VOC-containing
coatings, thinners, cleaning materials, and waste materials shall be minimized. iii. VOC-containing coatings,
thinners, cleaning materials, and waste materials shall be conveyed from one location to another in closed
containers or pipes. iv. Mixing vessels which contain VOC-containing coatings and other materials shall be
closed except when adding to, removing, or mixing the contents. v. Emissions of VOC shall be minimized during
cleaning of storage, mixing, and conveying equipment.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU68, EU69, and EU70 to a combined 138.9 tons/yr of
post-induction coating on a rolling 12-month basis. The permittee shall limit thinner usage to a combined 6.9
tons/yr (from EU68-EU71) of thinner on a rolling 12-month basis.
Christensen Arms AO Modification 9/7/23
Process/Pollutant Information
PROCESS
NAME:
Paint Booth #4 (EU71)
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput: 2.38 lb pre-induction coating/hr
Process Notes: After machining, each brake rotor is coated with zinc. Two types of coating operations are used. Castings first enter a paint booth which applies a
solids-based coating, followed by treatment in a preheater and then final induction heating to cure the coating. All paint booths are fitted with individual
filters.Each of these paint booths are equipped with electrostatic spray nozzles that achieve at least 70% transfer efficiency. This paint booths is equipped
with electrostatic spray nozzles that achieve at least 70% transfer efficiency.
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:EPA/OAR Mthd 5
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0160 TONS/YR 12-MONTH ROLLING
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.35 lb/lb of coating
delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100%
efficiency. The permittee shall use fabric filters.
Est. % Efficiency:99.000
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 15.5 tons/yr of pre-induction coating on a rolling
12-month basis.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Christensen Arms AO Modification 9/7/23
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0160 TONS/YR 12-MONTH ROLLING
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.35 lb/lb of coating
delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100%
efficiency. The permittee shall use fabric filters.
Est. % Efficiency:99.000
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 15.5 tons/yr of pre-induction coating on a rolling
12-month basis.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:EPA/OAR OTM 27 and Mthd 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.0160 TONS/YR 12-MONTH ROLLING
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(B) The permittee shall only use post-induction coatings with a solids content of less than 0.35 lb/lb of coating
delivered to the applicators. The permittee shall ensure that each paint booth capture system achieves 100%
efficiency. The permittee shall use fabric filters.
Est. % Efficiency:99.000
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 15.5 tons/yr of pre-induction coating on a rolling
12-month basis.
Christensen Arms AO Modification 9/7/23
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 24
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:3.5000 LB/GAL COATING LESS WATER, OR EXEMPT SOLVENT OR BOTH
Emission Limit 2:1.9400 TONS/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(P) The permittee shall, within 90 days of startup, develop and implement a work practice plan to minimize VOC
emissions from the storage, mixing, and conveying of coatings, thinners, and cleaning materials used in, and
waste materials generated by, all coating operations. The plan shall specify practices and procedures to ensure
that, at a minimum, the following elements are implemented: i. All VOC-containing coatings, thinners, cleaning
materials, and waste materials shall be stored in closed containers. ii. The risk of spills of VOC-containing
coatings, thinners, cleaning materials, and waste materials shall be minimized. iii. VOC-containing coatings,
thinners, cleaning materials, and waste materials shall be conveyed from one location to another in closed
containers or pipes. iv. Mixing vessels which contain VOC-containing coatings and other materials shall be
closed except when adding to, removing, or mixing the contents. v. Emissions of VOC shall be minimized during
cleaning of storage, mixing, and conveying equipment.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The permittee shall limit the throughput through EU71 to 3.87 tons/yr of pre-induction coating on a rolling
12-month basis. The permittee shall limit thinner usage to a combined 6.9 tons/yr (used in all paint booths) of
thinner on a rolling 12-month basis.
Process/Pollutant Information
PROCESS
NAME:
Emergency Generators #1, #2, & #3 (EU72, EU73, & EU74)
Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel))
Primary Fuel: Diesel
Throughput: 53.60 gal/hr
Christensen Arms AO Modification 9/7/23
Process Notes: Three (3) diesel fired compression ignition emergency generators that generate 750 kW each, and have a displacement of less than 30 liters per
cylinder. Emissions calculated at 500 hrs/yr.
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:Unspecified
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:2.6000 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT
Emission Limit 2:3.7300 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT , MACT
Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good
combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and
design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions
requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate
according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The
plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the
Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices
and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used
to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design
choices determined to be BACT and verification that designs were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Emissions calculated at 500 hrs/yr.
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.1490 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT.
Emission Limit 2:0.2980 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT.
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Christensen Arms AO Modification 9/7/23
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:MACT , OPERATING PERMIT
Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good
combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and
design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions
requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate
according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The
plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the
Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices
and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used
to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design
choices determined to be BACT and verification that designs were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Emissions calculated using 500 hrs/yr.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.1490 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT.
Emission Limit 2:0.2980 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT.
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:MACT , OPERATING PERMIT
Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good
combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and
design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions
requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate
according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The
plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the
Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices
and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used
to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design
choices determined to be BACT and verification that designs were implemented in the final construction.
Est. % Efficiency:
Christensen Arms AO Modification 9/7/23
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Emissions calculated at 500 hrs/yr.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.1490 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT.
Emission Limit 2:0.2980 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT.
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:MACT , OPERATING PERMIT
Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good
combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and
design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions
requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate
according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The
plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the
Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices
and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used
to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design
choices determined to be BACT and verification that designs were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Emissions calculated at 500 hrs/yr.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:4.7700 G/HP-HR (EU72 &EU73) REQ. MANUFACTURER'S CERT.
Christensen Arms AO Modification 9/7/23
Emission Limit 2:3.5000 G/HP-HR (EU74) REQ. MANUFACTURER'S CERT.
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:MACT , OPERATING PERMIT
Control Method:(P) The permittee shall prepare and maintain for EU72, EU73, and EU74, within 90 days of startup, a good
combustion and operation practices plan (GCOP) that defines, measures and verifies the use of operational and
design practices determined as BACT for minimizing CO, VOC, PM, PM10, and PM2.5 emissions. Any revisions
requested by the Division shall be made and the plan shall be maintained on site. The permittee shall operate
according to the provisions of this plan at all times, including periods of startup, shutdown, and malfunction. The
plan shall be incorporated into the plant standard operating procedures (SOP) and shall be made available for the
Division’s inspection. The plan shall include, but not be limited to: i. A list of combustion optimization practices
and a means of verifying the practices have occurred. ii. A list of combustion and operation practices to be used
to lower energy consumption and a means of verifying the practices have occurred. iii. A list of the design
choices determined to be BACT and verification that designs were implemented in the final construction.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Emissions calculated using 500 hrs/yr.
Process/Pollutant Information
PROCESS NAME: Gasoline Storage Tank (EU75)
Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks)
Primary Fuel:
Throughput: 2000.00 Gallon (Capacity)
Process Notes: A 2,000 gallon above-ground gasoline storage tank for fueling company vehicles.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Christensen Arms AO Modification 9/7/23
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:NSPS , OPERATING PERMIT
Control Method:(P) The permittee shall not allow gasoline to be handled in a manner that would result in vapor releases to the
atmosphere for extended periods of time. Measures to be taken include, but are not limited to, the following: i.
Minimize gasoline spills; ii. Clean up spills as expeditiously as practicable; iii. Cover all open gasoline containers
and all gasoline storage tank fill-pipes with a gasketed seal when not in use; iv. Minimize gasoline sent to open
waste collection systems that collect and transport gasoline to reclamation and recycling devices, such as
oil/water separators. The gasoline storage tank (EU75) shall be equipped with a permanent submerged fill pipe.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Work practice requirements only.
Process/Pollutant Information
PROCESS NAME: Paved Roadways (EU76)
Process Type: 99.140 (Paved Roads)
Primary Fuel:
Throughput: 0.43 Miles (length)
Process Notes:
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or as
needed in the event of a spill.
Est. % Efficiency:Christensen Arms AO Modification 9/7/23
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Work practice requirements only.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or as
needed in the event of a spill.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Work practice requirements only.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Unspecified
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or asChristensen Arms AO Modification 9/7/23
Control Method:(P) The permittee shall vacuum sweep the pavement at least weekly, except during recent rain events, or as
needed in the event of a spill.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Work practice requirements only.
Process/Pollutant Information
PROCESS
NAME:
Melt Shop Baghouse Stack (CU01/ST02) [EU02, EU04, EU07, EU08, EU09, EU10, EU11, EU12, EU15, EU16]
Process Type: 81.420 (Induction Furnaces)
Primary Fuel: Natural Gas
Throughput: 91586.00 ton gray iron/yr
Process Notes: This group consists of the following emission units: Alloy Storage (EU02), Scrap Cleaning (EU04), Induction Furnaces #1-#4 (EU07, EU08, EU09,
EU10), Holding Furnaces #1 & #2 (EU11 & EU12), and Pouring Furnaces #1 & #2 (EU15 & EU16).
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:EPA/OAR Mthd 5
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:1.4200 LB/HR 3-HOUR AVERAGE
Emission Limit 2:6.2000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: Y
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0010 gr/dscf.
Est. % Efficiency:96.340
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0010 gr/dscf.
Christensen Arms AO Modification 9/7/23
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:1.4200 LB/HR 3-HOUR AVERAGE
Emission Limit 2:6.2000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: Y
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0010 gr/dscf
Est. % Efficiency:92.600
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0010 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:EPA/OAR OTM 27 and Mthd 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.8500 LB/HR 3-HOUR AVERAGE
Emission Limit 2:3.7200 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.00060 gr/dscf.
Est. % Efficiency:91.030
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.00060 gr/dscf.
Christensen Arms AO Modification 9/7/23
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 25
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:0.1400 LB/HR 3-HOUR AVERAGE
Emission Limit 2:0.6100 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The only contributors to this limit are EU02, EU04, EU07, EU08, EU09, EU10, EU11, EU12, EU15, and EU16.
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:EPA/OAR Mthd 10
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:2.1100 LB/HR 3-HOUR AVERAGE
Emission Limit 2:9.2500 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The only contributors to this limit are EU02, EU04, EU07, EU08, EU09, EU10, EU11, EU12, EU15, and EU16.
Christensen Arms AO Modification 9/7/23
Process/Pollutant Information
PROCESS
NAME:
Sand Plant Baghouse Stack (CU06/ST07) [EU22, EU23, EU24, EU25, EU26, EU27, EU28, EU29, EU30, EU31, EU32, EU54, EU55, EU56, EU53]
Process Type: 81.440 (Sand, Core & Mold Making Processes)
Primary Fuel:
Throughput: 91586.00 tons gray iron/yr
Process Notes: This group consists of the following emission units: Mold Silica Sand Bin (EU22), Blend Bin (EU23), Bentonite Bin (EU24), Dust Bin (EU25), Mold
Silica Sand Weigh Hopper (EU26), Blend Weigh Hopper (EU27), Dust Weigh Hopper (EU29), Green Sand Mixers #1 - #3 (EU30, EU31, & EU32),
Sand Cooler (EU54), Used Mold and Core Sand Storage (EU55), Sand Screening (EU56), and the Shakeout Conveyor (EU53)
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:EPA/OAR Mthd 5
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:2.1600 LB/HR 3-HOUR AVERAGE
Emission Limit 2:9.4600 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP , OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf.
Est. % Efficiency:99.880
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:2.1600 LB/HR 3-HOUR AVERAGE
Emission Limit 2:9.4600 TON/YR 12-MONTH ROLLING
Standard Emission:
Christensen Arms AO Modification 9/7/23
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse, much achieve 0.0025 gr/dscf.
Est. % Efficiency:99.250
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:EPA/OAR OTM 27 and Mthd 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:1.3000 LB/HR 3-HOUR AVERAGE
Emission Limit 2:5.6700 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0015 gr/dscf
Est. % Efficiency:99.530
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0015 gr/dscf.
Process/Pollutant Information
PROCESS
NAME:
Pouring & Cooling Baghouse (CU08/ST09)[EU33, EU34, EU36, EU37, EU38, EU43, EU44, EU45, EU46, EU47, EU48, EU49, EU50, EU51, EU52, &
EU59]
Process Type: 81.450 (Casting & Pouring Processes)
Primary Fuel:
Throughput: 91586.00 tons gray iron/yr
Christensen Arms AO Modification 9/7/23
Process Notes: This group consists of the following emission units: Mold Stamping #1 & #2 (EU33 & 34), Sand Classifier (EU36), Core Silica Sand Bin (EU37), Core
Silica Sand Weigh Hopper (EU38), Core Removal (EU43), Dryers #1-#4 (EU44, EU45, EU46, EU47), Mold Assembly #1 & #2 (EU48 & EU49),
Pouring #1 & #2 (EU50 & EU51), Cooling Tunnel (EU52), & Forced Air Cooler (EU59).
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:EPA/OAR Mthd 5
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:3.5400 LB/HR 3-HOUR AVERAGE
Emission Limit 2:15.5000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: Y
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf
Est. % Efficiency:99.500
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:3.5400 LB/HR 3-HOUR AVERAGE
Emission Limit 2:15.5000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf.
Est. % Efficiency:98.830
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Christensen Arms AO Modification 9/7/23
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:EPA/OAR OTM 27 and Mthd 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:2.1200 LB/HR 3-HOUR AVERAGE
Emission Limit 2:9.3000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0015 gr/dscf
Est. % Efficiency:98.910
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0015 gr/dscf.
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:EPA/OAR Mthd 10
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:128.0000 LB/HR 3-HOUR AVERAGE
Emission Limit 2:235.0000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Christensen Arms AO Modification 9/7/23
Compliance Verified:Unknown
Pollutant/Compliance Notes:The only contributors to this limit are EU33, EU34, EU35A, EU35B, EU36, EU37, EU38, EU43, EU44, EU45,
EU46, EU47, EU48, EU49, EU50, EU51, EU52, EU59.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 25
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:20.8000 LB/HR 3-HOUR AVERAGE
Emission Limit 2:39.7000 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The only contributors to this limit are EU33, EU34, EU35A, EU35B, EU36, EU37, EU38, EU43, EU44, EU45,
EU46, EU47, EU48, EU49, EU50, EU51, EU52, EU59.
Process/Pollutant Information
PROCESS
NAME:
Finishing Baghouse Stack (CU11/ST12) [EU60, EU61, EU62, EU64, EU65]
Process
Type:
81.490 (Other Iron Foundry Processes)
Primary
Fuel:
Throughput: 91586.00 tons gray iron/yr
Process This group consists of the following emission units: Sorting (EU60), Steel Shot Blasting #1 & #2 (EU61 & EU62), Grinding #1 & #2 (EU64 & EU65).
Christensen Arms AO Modification 9/7/23
Process
Notes:
This group consists of the following emission units: Sorting (EU60), Steel Shot Blasting #1 & #2 (EU61 & EU62), Grinding #1 & #2 (EU64 & EU65).
From shake-out, the castings are sent to a forced air cooler and then sorted to remove any remaining sprues. Finishing begins when the cast parts are sent
to the steel shot blasting units, where a stream of abrasive material (steel shot) is forcibly propelled in a stream against the surface of the castings under
high pressure. This process removes sand and smooths the casting surface. Grinders are then used to remove any raised areas or bits of sprue left on the
surface of the product. The finished castings are placed in short term storage to allow the gray iron to fully crystallize and reach its desired structure
before being sent to the final machining operation. Emissions from sorting, shot blasting, and milling are vented to the finishing baghouse (CU11) and
exhausted through a stack (ST12).
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:EPA/OAR Mthd 5
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:1.3200 LB/HR 3-HOUR AVERAGE
Emission Limit 2:5.7800 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - Must achieve 0.0025 gr/dscf
Est. % Efficiency:99.630
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:EPA/OAR Mthd 201A and 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:1.3200 LB/HR 3-HOUR AVERAGE
Emission Limit 2:5.7800 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0025 gr/dscf
Christensen Arms AO Modification 9/7/23
Est. % Efficiency:96.340
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0025 gr/dscf.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:EPA/OAR OTM 27 and Mthd 202
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.7920 LB/HR 3-HOUR AVERAGE
Emission Limit 2:3.4700 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: Y
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Baghouse - must achieve 0.0015 gr/dscf
Est. % Efficiency:97.800
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Must achieve 0.0015 gr/dscf
Process/Pollutant Information
PROCESS
NAME:
Core Machines #1-#4 (ST08) [EU39, EU40, EU41, EU42]
Process
Type:
81.440 (Sand, Core & Mold Making Processes)
Primary
Fuel:
Throughput: 3.58 ton amine gas/yr, each
Process Before the mold can be assembled, a core must be formed that is shaped to allow the hollows and voids of the brake rotor to form when the molten metal
Christensen Arms AO Modification 9/7/23
Process
Notes:
Before the mold can be assembled, a core must be formed that is shaped to allow the hollows and voids of the brake rotor to form when the molten metal
is poured into the mold. The core must be strong enough to stand up to the heat of the molten material and is formed of silica sand, resin and hardener.
Core silica sand is processed through a sand classifier that sorts out fine-sized particles to ensure a uniform gain sized sand. It is then mixed with a two
part phenolic resin and hardener in an enclosed mixer. This blend is sent to an automated core machine where it is shaped into the desired form and
subjected to an amine gas that acts as a catalyst to accelerate curing of the resin. Hardened cores are separated from their molds and dipped into a coating
that provides abrasive protection. The cores are then heated in a natural-gas fired dryer (4.0 MMBtu/hr, each) before exiting the automatic core machines.
Emissions from most of the core making area, including the sand silos, sand classifier, sand bin, weigh hopper, core removal area and dryers are vented to
the pouring and cooling baghouse (CU08) and then to stack (ST09). Emissions from use of the amine gas are sent through a sulfuric acid scrubber, to
control odors, before exiting to the atmosphere through a stack.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 25
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:0.7000 LB/HR 3-HOUR AVERAGE
Emission Limit 2:1.6700 TON/YR 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: Y
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(A) Sulfuric Acid Scrubber - controls amine gas, a VOC
Est. % Efficiency:99.000
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:The core machines produce VOCs due to the use of amine gas, a mold release lubricant, and resin binders. Core
machines #1–#4 (EU39–EU42) are a source of VOCs due to materials used in the process. The amine gas
(vaporized dimethyl propylamine) is used as a catalyst to speed curing of the resins in the cores. The resins
themselves are a source of VOC emissions as is the lubricant used to assist in mold release. Emissions from the
machines are routed through a wet scrubber control which provides a 99 percent reduction of VOC emissions for
the amine gases, only. The other VOCs pass through without effect. Calculations for emissions of VOC for the
core machines are based on an American Foundry Society document from 2005 titled "Resin/CO2 Core and
Mold making Process:Emission Characterization", Figure 11: PUCB Baseline.
Process/Pollutant Information
PROCESS
NAME:
Building Vents #1 (BV01a & b) [EU01, EU05, EU06, EU13, EU14, EU18, & uncaptured emissions from EU07, EU08, EU09, EU10, EU60, EU61,
EU62, EU64, & EU65]
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Process Type: 81.490 (Other Iron Foundry Processes)
Primary
Fuel:
Throughput: 91586.00 tons gray iron/yr
Process
Notes:
Some activities associated with the melt shop do not have active capture and control associated with the processes. These uncaptured emissions are
released to the air within the building. In these cases the building itself provides containment and a partial barrier to emission of particulate to the outside
ambient air. The pollutants, emitted by the melt shop, which do not settle out will exit the building via building vents (BV01a & BV01b). The emission
group consists of the following emission units: Scrap Steel Storage (EU01), Refractory Burners #1 & #2 (EU05 & EU06), Transport Ladles #1 & #2
(EU13 & EU14), Refractory Curing Mobile Burner (EU18), and uncaptured emissions from Induction Furnaces #1-#4 (EU07, EU08, EU09, & EU10),
sorting (EU60), shot blasting #1 and #2 (EU61 & EU62), and grinding (EU64 & EU65).
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:Other
Other Test Method:Roof Monitor Sampling
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.7300 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:3.1800 TON/YR (COMBINED) 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:All building vent particulate emissions assume a 90 percent control for enclosure of the process within the
building.
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:Other
Other Test Method:Roof Monitor Sampling
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.3900 LB/HR (COMBINED) 3-HOUR AVERAGE
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Emission Limit 2:1.7200 TON/YR (COMBINED) 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:All building vent particulate emissions assume a 90 percent control for enclosure of the process within the
building.
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Other
Other Test Method:Roof Monitor Sampling
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.2000 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:0.8700 TON/YR (COMBINED) 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:All building vent particulate emissions assume a 90 percent control for enclosure of the process within the
building.
POLLUTANT NAME: Carbon Monoxide
CAS Number: 630-08-0
Test Method:Other
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Other Test Method:Roof Monitor Sampling
Pollutant Group(s):( InOrganic Compounds )
Emission Limit 1:0.0200 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:0.0700 TON/YR (COMBINED) 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Other
Other Test Method:Roof Monitor Sampling
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:0.2500 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:1.0800 TON/YR (COMBINED) 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
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Process/Pollutant Information
PROCESS
NAME:
Building Vents #2 (BV02a & b)[EU66 & EU67]
Process Type: 81.490 (Other Iron Foundry Processes)
Primary Fuel:
Throughput: 91586.00 tons gray iron/yr
Process Notes: These building vents are associated with the machining shop and is the exit point for uncaptured emissions from those areas. The emissions are from
the turning lathe (EU66) & drilling and milling (EU67).
POLLUTANT NAME: Particulate matter, filterable (FPM)
CAS Number: PM
Test Method:Other
Other Test Method:Roof Monitor Testing
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.2000 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:0.8800 TON/YR (COMBINED) 12-MONTH AVERAGE
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Particulate matter, total < 10 µ (TPM10)
CAS Number: PM
Test Method:Other
Other Test Method:Roof Monitor Testing
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.2000 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:0.8800 TON/YR (COMBINED) 12-MONTH ROLLING
Christensen Arms AO Modification 9/7/23
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
POLLUTANT NAME: Particulate matter, total < 2.5 µ (TPM2.5)
CAS Number: PM
Test Method:Other
Other Test Method:Roof Monitor Testing
Pollutant Group(s):( Particulate Matter (PM) )
Emission Limit 1:0.1200 LB/HR (COMBINED) 3-HOUR AVERAGE
Emission Limit 2:0.5300 TON/YR (COMBINED) 12-MONTH ROLLING
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:
Process/Pollutant Information
PROCESS NAME: Diesel Storage Tank (EU76)
Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks)
Primary Fuel: Christensen Arms AO Modification 9/7/23
Primary Fuel:
Throughput: 2000.00 gallons
Process Notes: 2,000 gallon above-ground diesel storage tank
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:Unspecified
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:OPERATING PERMIT
Control Method:(P) The diesel storage tank (EU76) shall be equipped with a permanent submerged fill pipe.
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:Work Practice Requirements only.
Facility Information
RBLC ID:WI-0257 (final) Date Determination
Last Updated:07/06/2016
Corporate/Company Name:OSHKOSH CORPORATION Permit Number:11-JJW-094
Facility Name:OSHKOSH CORPORATION - MAIN PLANT Permit Date:07/21/2011 (actual)
Facility Contact:SUE MURAWSKI (920)
233-9582 SMURAWSKI@DEFENSE.OSHKOSHCORP.COM
FRS Number:110000497418
Facility Description:Manufacturer of heavy duty specialized trucks and transportation equipment SIC Code:3711
Permit Type:B: Add new process to existing facility NAICS Code:336120
Permit URL:http://dnr.wi.gov/cias/am/amexternal/AM_DownloadObject.aspx?id=222436
EPA Region:5 COUNTRY:USA
Facility County:WINNEBAGO
Christensen Arms AO Modification 9/7/23
Facility State:WI
Facility ZIP Code:54903-2566
Permit Issued By:WISCONSIN DEPT OF NATURAL RESOURCES; AIR MGMT. PROGRAM (Agency Name)
MS. KRISTIN HART(Agency Contact) (608)266-6876 kristin.hart@wisconsin.gov
Permit Notes:
Affected Boundaries: Boundary Type:Class 1 Area State:Boundary:Distance:
CLASS1 WI Rainbow Lake > 250 km
CLASS1 MI Seney > 250 km
INTL BORDER US/Canada Border > 250 km
Facility-wide Emissions: Pollutant Name:Facility-wide Emissions Increase:
Carbon Monoxide 24.0000 (Tons/Year)
Nitrogen Oxides (NOx)28.5000 (Tons/Year)
Particulate Matter (PM)8.4500 (Tons/Year)
Sulfur Oxides (SOx)0.0170 (Tons/Year)
Volatile Organic Compounds (VOC)220.0000 (Tons/Year)
Process/Pollutant Information
PROCESS NAME: P51 - Two Electrodeposition Pretreatment Lines
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel: Natural Gas
Throughput: 0
Process Notes: Including five make-up air units and eight bath heaters.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 24A
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:
Control Method:(N)
Est. % Efficiency:
Christensen Arms AO Modification 9/7/23
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per
gallon. (b) The use of natural gas as a fuel for all make-up air units, bath heaters and ovens associated with these
processes. (c) Limit the combined VOC emissions from all materials (including cleanup solvents) used on P51,
P52, and P53 to 25,000 pounds per month, averaged over each consecutive 12 month period.
POLLUTANT NAME: Visible Emissions (VE)
CAS Number: VE
Test Method:EPA/OAR Mthd 9
Pollutant Group(s):
Emission Limit 1:10.0000 PERCENT OPACITY
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these
processes.
Process/Pollutant Information
PROCESS NAME: P52 - Two Electrodeposition Primer Coating Lines
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel: Natural Gas
Throughput: 0
Process Notes: Including two ovens.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
Christensen Arms AO Modification 9/7/23
CAS Number: VOC
Test Method:EPA/OAR Mthd 24A
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:3.5000 LBS VOC/GALLON AS APPLIED/EXCLUDING WATER
Emission Limit 2:0.8000 LBS VOC/GALLON OF APPLIED COATINGS SOLIDS
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: U
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:NESHAP , SIP
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per
gallon. (b) The use of natural gas as a fuel for all make-up air units, bath heaters and ovens associated with these
processes. (c) Limit the combined VOC emissions from all materials (including cleanup solvents) used on P51,
P52, and P53 to 25,000 pounds per month, averaged over each consecutive 12 month period.
POLLUTANT NAME: Visible Emissions (VE)
CAS Number: VE
Test Method:EPA/OAR Mthd 9
Pollutant Group(s):
Emission Limit 1:10.0000 PERCENT OPACITY
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these
Christensen Arms AO Modification 9/7/23
Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these
processes.
Process/Pollutant Information
PROCESS NAME: P53 - Six Spray Booths
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel: Natural Gas
Throughput: 0
Process Notes: Including two ovens.
POLLUTANT NAME: Visible Emissions (VE)
CAS Number: VE
Test Method:EPA/OAR Mthd 9
Pollutant Group(s):
Emission Limit 1:10.0000 PERCENT OPACITY
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(A) Overspray dry filters
Est. % Efficiency:99.800
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Yes
Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air units, bath heaters and ovens associated with these
processes.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 24A
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:3.5000 POUNDS VOC/GALLON AS APPLIED, EXCLUDING WATER
Christensen Arms AO Modification 9/7/23
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per
gallon. (b) the use of natural gas as a fuel for all make-up air units, bath heaters and ovens associated with these
processes. (c) Limit the combined VOC emissions from all materials (including cleanup solvents) used on P51,
P52, and P53 to 25,000 pounds per month, averaged over each consecutive 12 month period. (d) for Process
P53, P54, and P55, the permittee may use up to 45 gallons per month, averaged over each consecutive 12 month
period, of materials that exceed the applicable VOC content limit of 3.5 pounds of VOC per gallon as applied,
excluding water. However, the VOC contents of these materials may not exceed the applicable VOC content
limitations under ch. NR 422, Wis. Adm. Code.
Process/Pollutant Information
PROCESS NAME: P54 - Two Spray Booths
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput: 0
Process Notes: Including one make-up air unit.
POLLUTANT NAME: Visible Emissions (VE)
CAS Number: VE
Test Method:EPA/OAR Mthd 9
Pollutant Group(s):
Emission Limit 1:10.0000 PERCENT OPACITY
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Christensen Arms AO Modification 9/7/23
Other Applicable Requirements:SIP
Control Method:(A) Overspray dry filters
Est. % Efficiency:99.800
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Yes
Pollutant/Compliance Notes:(a) The permittee shall only fire natural gas in the make-up air unit associated with these processes.
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 24A
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:3.5000 LBS VOC/GALLON AS APPLIED, EXCLUDING WATER
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(N)
Est. % Efficiency:
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per
gallon. (b) The use of natural gas as a fuel for the make-up air unit associated with this process. (c) The permittee
shall limit the combined VOC emissions from all materials (including cleanup solvents) used on processes P54A
and P54B to 5,000 pounds per month each, averaged over each consecutive 12 month period. (d) For Process
P53, P54, and P55, the permittee may use up to 45 gallons per month, averaged over each consecutive 12 month
period, of materials that exceed the applicable VOC content limit of 3.5 pounds of VOC per gallon as applied
excluding water. However, the VOC contents of these materials may not exceed the applicable VOC content
limitations under ch. NR 422, Wis. Adm. Code.
Process/Pollutant Information
PROCESS NAME: P55 - One Spray Booth
Process Type:41.013 (Miscellaneous Metal Parts and Products Surface Coating)Christensen Arms AO Modification 9/7/23
Process Type: 41.013 (Miscellaneous Metal Parts and Products Surface Coating)
Primary Fuel:
Throughput: 0
Process Notes:
POLLUTANT NAME: Visible Emissions (VE)
CAS Number: VE
Test Method:EPA/OAR Mthd 9
Pollutant Group(s):
Emission Limit 1:10.0000 PERCENT OPACITY
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(A) Overspray dry filters
Est. % Efficiency:99.800
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Yes
Pollutant/Compliance Notes:
POLLUTANT NAME: Volatile Organic Compounds (VOC)
CAS Number: VOC
Test Method:EPA/OAR Mthd 24A
Pollutant Group(s):( Volatile Organic Compounds (VOC) )
Emission Limit 1:3.5000 POUNDS VOC/GALLON AS APPLIED, EXCLUDING WATER
Emission Limit 2:
Standard Emission:
Did factors, other then air pollution technology considerations influence the BACT decisions: N
Case-by-Case Basis:BACT-PSD
Other Applicable Requirements:SIP
Control Method:(N)
Est. % Efficiency:
Christensen Arms AO Modification 9/7/23
Cost Effectiveness:0 $/ton
Incremental Cost Effectiveness:0 $/ton
Compliance Verified:Unknown
Pollutant/Compliance Notes:(a) The use of wipe cleaning solvents with an as applied VOC content of no more than 6.8 pounds of VOC per
gallon. (b) The permittee shall limit the combined VOC emissions from all materials (including cleanup
solvents) used on Process P55 to 1,666 pounds per month, averaged over each consecutive 12 month period. (c)
for Process P53, P54, and P55, the permittee may use up to 45 gallons per month, averaged over each
consecutive 12 month period, of materials that exceed the applicable VOC content limit of 3.5 pounds of VOC
per gallon as applied excluding water. However, the VOC contents of these materials may not exceed the
applicable VOC content limitations under ch. NR 422, Wis. Adm. Code.
Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
United States Office of Air Quality EPA 456/F-99-004
Environmental Protection Planning and Standards May 1999
Agency Research Triangle Park, NC 27711
Air
Christensen Arms AO Modification 9/7/23
EPA-456/F-99-004
May 1999
CATC TECHNICAL BULLETIN
CHOOSING AN ADSORPTION
SYSTEM FOR VOC:
CARBON, ZEOLITE, OR POLYMERS?
Prepared by
Clean Air Technology Center (MD-12)
Information Transfer and Program Integration Division
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Christensen Arms AO Modification 9/7/23
iii
DISCLAIMER
This report has been reviewed by the Information Transfer and Program Integration
Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection
Agency and approved for publication. Approval does not signify that the contents of this report
reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade
names or commercial products is not intended to constitute endorsement or recommendation for
use. Copies of this report are available form the National Technical Information Service,
U.S. Department of Commerce, 5285 Port Royal Road, Springfield, Virginia 22161, telephone
number (800) 553-6847.
Christensen Arms AO Modification 9/7/23
iv
FORWARD
The Clean Air Technology Center (CATC) serves as a resource on all areas of
emerging and existing air pollution prevention and control technologies, and provides public
access to data and information on their use, effectiveness and cost. In addition, the CATC will
provide technical support, including access to EPA’s knowledge base, to government agencies
and others, as resources allow, related to the technical and economic feasibility, operation and
maintenance of these technologies.
Public Access and Information Transfer
INTERNET / World Wide Web Home Page
http://www.epa.gov/ttn/catc
Communications
CATC Info-Line: (919) 541-0800 (English)
CATC/CICA Info-Line: (919) 541-1800 (Spanish)
Toll-Free from Mexico (800) 304-1115 (Spanish)
FAX: (919) 541-0242
E-Mail: catcmail@epamail.epa.gov
Data Resources
CC RACT/BACT/LAER Clearinghouse (RBLC)
Query, view and download data you select on
- Source Specific Technology Applications
- Air Pollution Regulatory Requirements
CC CATC PRODUCTS
download technical reports, cost information and software
Related Programs and Centers
C CICA - U.S.-Mexico Border Information Center on Air Pollution /
Centro de Información sobre Contaminación de Aire Para la Frontera
entre EE.UU. Y México
C SBAP - Small Business Assistance Program
C International Technology Transfer Center for Global Greenhouse Gasses
Christensen Arms AO Modification 9/7/23
v
ACKNOWLEDGMENTS
This technical bulletin was made possible through the diligent and persistent efforts of
Lyndon Cox, Senior Environmental Employee with the Clean Air Technology Center (CATC).
Lyndon did an exceptional job identifying information sources, gathering relative data and putting
this bulletin together. The CATC also appreciates the helpful and timely comments and
cooperation of the following peer reviewers:
Madeleine Strum, Coating and Consumer Products Group, Emission Standards Division,
Office of air Quality Planning and Standards, Office of Air and Radiation, U.S. EPA.
William Vatavuk, Innovative Strategies and Economics Group, Air Strategies and Standards
Division, Office of air Quality Planning and Standards, Office of Air and Radiation, U.S. EPA.
Carlos Nuñez, Emissions Characterization and Prevention Branch, Air Pollution Prevention and
Control Division, National Risk Management Research Laboratory, Office of Research and
Development, U.S. EPA.
In addition, the CATC thanks the individuals, companies and institutions who supplied
information on adsorption technology used to prepare this Technical Bulletin. Contributors are
indicated in the REFERENCES section of this bulletin.
Christensen Arms AO Modification 9/7/23
vi
TABLE OF CONTENTS
TOPIC Page
WHAT ARE ADSORBERS?...............................................................................................1
WHY ARE ADSORBERS IMPORTANT?..........................................................................2
HOW DOES ADSORPTION WORK?.................................................................................2
HOW ARE POLLUTANTS ADSORBED?.............................................................3
WHAT IS DESORBING?........................................................................................3
WHAT IS THE ADSORPTION ISOTHERM?........................................................4
HOW DO I PICK AN ADSORBENT?....................................................................4
ARE THERE OTHER DESIGN CONSIDERATIONS?..........................................6
MASS TRANSFER ZONE..........................................................................6
WORKING CAPACITY..............................................................................7
VAPOR PRESSURE....................................................................................8
MULTIPLE ADSORBENTS........................................................................8
ADSORPTION MODELS............................................................................8
BED FIRES..................................................................................................9
OFF-SITE ADSORBENT REGENERATION............................................9
AFFINITY....................................................................................................9
HOW CAN ADSORBERS BE REGENERATED?...........................................................10
THERMAL SWING REGENERATION...............................................................10
VACUUM REGENERATION...............................................................................11
VAPOR CONCENTRATOR.................................................................................13
PRESSURE SWING ADSORBER........................................................................15
ARE ADSORPTION SYSTEM DESIGN TOOLS AVAILABLE?...................................16
WHAT CONTROL EFFICIENCIES SHOULD YOU EXPECT TO GET?......................16
WHAT KIND OF SOURCES CAN USE ADSORPTION TECHNOLOGY?..................17
HOW MUCH DO ADSORBERS COSTS?......................................................................17
DECISIONS, DECISIONS,................................................................................................20
SOME REFERENCES.......................................................................................................22
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vii
FIGURES
1. Molecule-Surface Distance..............................................................................................3
2. Potential Energy vs. Distance..........................................................................................3
3. Movement of MTZ with Time.........................................................................................6
4. Thermal Swing Adsorber (steam regeneration).............................................................10
5. Vacuum Regeneration Adsorber....................................................................................11
6. Cascade Vacuum Separation.........................................................................................12
7. VOC Concentrator.........................................................................................................13
8. Pressure Swing Adsorption............................................................................................15
TABLES
1. Cost of Thermal Swing (“regenerative”) Carbon Adsorption Systems.........................19
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1
Choosing an Adsorption System for VOC:
Carbon, Zeolite, or Polymers?
This paper will make you more familiar with the issues involved in choosing an adsorber system
for your plant, company, or corporation. Carbon, zeolite, and polymer adsorbents have each been
used to adsorb Volatile Organic Compounds (VOC) and other pollutants from relatively dilute
concentrations in air (from tens to thousands of parts per million by volume) to control emissions.
This paper discusses issues involved in deciding which adsorbent to use, what type of adsorption
system to use, and whether it is the right emission control technology for you.
WHAT ARE ADSORBERS?
We are referring to adsorbers, not absorbers, because the pollutant is adsorbed on the surface
(mostly the internal surface) of a granule, bead, or crystal of adsorbent material. It is not
absorbed by a chemical reaction. This is an important difference. The adsorbed material is held
physically, rather loosely, and can be released (desorbed) rather easily by either heat or vacuum.
By contrast, an absorber reacts chemically with the substance being absorbed, and thus holds the
absorbed substance much more strongly, requiring much more energy to release the absorbed
substance.
Unfortunately, one of the adsorbents is called “absorbent carbon.” This persisting misnomer came
from the time before adsorption became understood in the 1920's. A better term is “activated
carbon.” Carbon is activated by the pyrolysis of coal, wood, bark, coconut husks, etc. to remove
all the volatile material as a gas or vapor, and leave only the carbon. This carbon might then also
be partially oxidized to enlarge its pores.
Another adsorbent is the alumino-silicate crystal structure known as “zeolite,” which has
uniformly sized pores (also called windows) throughout its crystal structure. The crystal structure
for the 118 established types of zeolite is determined by the ratio of silicon to aluminum in the
crystal when the crystal is formed. All naturally occurring zeolite is hydrophilic (having an affinity
for polar molecules, such as water) and contains aluminum. Dealuminizing natural zeolite makes
it hydrophobic (having affinity for non-polar substances, such as many VOC). Zeolite is
dealuminized by chemical replacement of the aluminum with silicon without changing the crystal
structure.
Hydrophobic zeolite can also be synthesized in crystals from 1 micron to 1 millimeter in diameter,
and these can be bonded into larger granules to lower there resistance to air flow. Since synthesis
is expensive, it is usually reserved for making either hydrophobic zeolite or zeolite catalysts with a
specific large pore size.
Polymeric adsorbents have pores built in when they are manufactured. These pores can range
from macro-porous through molecular sizes, but the smallest pores are usually larger than the
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2
micro-pores of an activated carbon. Polymers are used as granules or beads and, as the name
implies, are plastics. They have been observed to desorb faster than carbon. Like carbon, they
are not considered highly selective as to which VOC they will adsorb, although any specific
polymer will adsorb some VOC better than others.
Choosing the best adsorbent for the situation is not simple. There are several related problems
which we will discuss to familiarize you with the different adsorbents and systems.
WHY ARE ADSORBERS IMPORTANT?
Adsorbers have been used principally to control the emission of VOC. The control of VOC
emissions typically reduces the concentrations from between 400 and 2,000 parts per million
(ppm) to under 50 ppm. Adsorption technology can now extend the range of VOC concentration
from 20 ppm to one-fourth of the Lower Explosive Limit (LEL). At the lower end of this range,
such small concentrations may be difficult or uneconomical to control by another technology or
even by all adsorbents. Incinerators, membrane separators, and condensers may be economically
feasible when used in place of adsorbers at the upper end of the range.
In addition to emission control, the adsorber makes recovery of the VOC possible. Recovery of
a reusable or marketable VOC can significantly offset the cost of emission control. Adsorbers can
also increase the concentration of VOC to allow either destruction by incineration, or recovery by
either membrane or condenser to be economically feasible.
HOW DOES ADSORPTION WORK?
The VOC are condensible vapors which appear to condense on the surface of the adsorbent.
When the surface has adsorbed nearly as much as it can, the VOC is desorbed as part of
regenerating the adsorbent. When desorbed, the VOC vapors are usually at a higher
concentration, after which the VOC is either recovered or destroyed. One can think of all
adsorbers as capturing VOC from a dilute concentration and releasing it in a higher concentration.
Adsorbers can also be thought of as separating the flow of VOC from the air flow of a process.
The actual concentration of the VOC is key to when and how an adsorber would be used. An
adsorber becomes nearly useless when the inlet concentration gets so low that the VOC will not
be effectively adsorbe, but it allows the recovery of the VOC to be at a high concentration.
Safety reasons direct that VOC concentrations are held below one-fourth of the LEL. When the
concentration is near one-fourth of the LEL, the VOC can be economically disposed of by an
incinerator, captured by a membrane, or recovered with a condenser. However, a VOC
concentration below one-fourth of the LEL is too lean to support combustion without adding
auxiliary fuel. Therefore, as the VOC concentration exiting the adsorber drops below one-fourth
of the LEL, more fuel must be added to give adequate combustion to the VOC in an incinerator.
Christensen Arms AO Modification 9/7/23
3
potential
energy
x
well
Figure 2. Potential Energy vs. Distance
x
surface
molecule
Figure 1. Molecule-Surface Distance
HOW ARE POLLUTANTS ADSORBED?
Figure 1 shows a molecule above a surface, with the distance from the surface being the normal to
the surface. There is a repulsion between the cloud of electrons in atoms that form the
surface and those of the molecule, and there is also a Van der Waals nuclear attraction force. The
nuclear attraction has a much shorter radius of influence, so there is a short distance (usually
nanometers) from the surface where there is a “dip” or a “well” in the potential energy curve as
shown in Figure 2. Molecules or atoms that reach this “well” are trapped or “adsorbed” by this
potential energy “well” until they can obtain enough kinetic energy to fly out of the well and
escape. Kinetic energy converts to potential energy, just as when you jump upward against
gravity. Therefore, kinetic energy must be added to allow the molecules to escape, or desorb.
Kinetic energy of molecules exhibits itself as the temperature, with hotter being more energetic.
Historically, carbon was the first material to be observed to have a large amount of area with this
property. Zeolite and polymer adsorbents have more recently been found to also have a large
amount of internal surface area with this property.
We have known for decades that before you can pull a “hard vacuum” (such as 1 micron Hg)
even glass systems have to “outgas” adsorbed air. What is unique to these adsorbents is that they
have such a large amount of area (mostly internal) with this property per unit of weight, and that
this area can be desorbed so readily.
WHAT IS DESORBING?
Desorbing has been accomplished through both temperature and pressure swings. According to
the kinetic theory of matter, the molecules gain kinetic energy when heated, and this allows a
heated molecule to “fly” out of the well. Heat can be provided as steam, heated nitrogen, or by
microwave among other techniques. For vacuum regeneration, the molecule will at some time
Christensen Arms AO Modification 9/7/23
4
have sufficient energy to escape if molecular impacts do not cause it to rebound back into the
well. Therefore, desorbing can be accomplished either by heating the adsorbed material or by
evacuating the space over it. There is an equilibium between captured and escaping molecules.
Giving the adsorbed material the kinetic energy to escape or desorb is part of the regeneration of
the adsorbent. This regeneration of the adsorbent should be done before all of the absorbent has
become unable to hold more, and must be done before the adsorbent can be used again. The
remainder of regeneration is drying, cooling, or otherwise preparing the adsorbent to again adsorb
the VOC.
WHAT IS THE ADSORPTION ISOTHERM?
Each adsorbent has an adsorption capacity which is referred to as the “adsorption isotherm”.
Historically, with carbon, the isotherm was used to measure the pounds of pollutant per pound of
adsorbent that could be adsorbed at a given temperature. However, the adsorption isotherm is
also a function of pollutant concentration as measured by the partial pressure of the vapor, and it
is also a function of the total ambient pressure around the adsorbent. The number of molecules
that can be stored in the “well” is pressure dependent, with closer spacing of adsorbed molecules
being associated with higher pressure. The adsorption isotherm is still defined as the pounds of
material that can be adsorbed per pound of adsorbent.
Thermal regeneration systems use the temperature isotherm; vacuum regeneration systems use the
total and partial pressure isotherm; and pressure swing regeneration systems use the total ambient
pressure isotherm. The “isotherm” is actually a function of all of these variables. Thus, the
“isotherm” is actually a complex function that forms at least a 3-dimensional surface, rather than
being either a constant or a two-dimensional plot. The isotherm can either be a linear function or
a highly non-linear function depending upon the adsorbent, the pressure, and the material being
adsorbed.
The adsorption isotherm is also a function of the amount of adsorption area that molecules of the
VOC can reach. Pores on the surface allow entry to the interior area of each of these adsorbents.
The interior is where most of the adsorption area exists. Carbon has pores leading to smaller
pores, which lead to even smaller pores. This apparently continues ad infinitum in carbon, and
much of the internal surface area is in these micro-pores. Zeolite has uniform pores that are part
of its crystal structure. Polymers have a range of pore sizes, but usually lack the very small micro-
pores. Thus, the adsorption isotherm is different for each type of adsorbent and each type of
pollutant.
HOW DO I PICK AN ADSORBENT?
There are many kinds of polymer adsorbents, many kinds of carbon adsorbents, and many kinds of
zeolite adsorbents. To document all of these variations would make this paper quite a tome, and it
would become a handbook rather than a concept paper. We do not intend to adequately
Christensen Arms AO Modification 9/7/23
5
describe all of the variations in such detail. We can only deal with general properties and let
specific selections be made by the designers and their customers with the aid of handbooks.
A prime concern is the largest molecular size to be adsorbed versus the pore size of the adsorbent.
This is principally a concern with zeolite, where uniform pores can be any size from 3 to 30
Dngstroms (0.3 to 3 nanometers) for different types of zeolite. Zeolite should not be expected to
provide any adsorption area for molecules larger than its pores, nor for molecules for which it
does not have affinity. Carbon and polymers also must have pores larger than the largest
molecule to be adsorbed. However, the broad range of pore size in carbon and polymers makes
this criterion less strict than it is for zeolite. The adsorption area to be reached via the pores
should be excluded if the molecule to be adsorbed can neither reach it nor be desorbed from it.
Regardless of the method of regeneration, the adsorption area cannot be regenerated when the
adsorbed molecule jumps from a well on one side of the pore to a well on the other side of the
pore. This can occur in the micro-pores of carbon and some polymers. Thus, this would prevent
desorption from occurring from areas where the micro-pores get too small.
The affinity of the adsorbent for some types of substances can be much greater than the affinity
for others. As a result, when there is a stronger affinity for some of the molecules, the molecules
having lesser affinity either get held with a smaller adsorption capacity or get released in favor of
the molecules for which the affinity is greater. Carbon, which is neither fully hydrophobic or
hydrophilic, retains some adsorption area with affinity for both polar and non-polar molecules.
Humidity has a noticeable effect on carbon because of this. One research paper has even reported
that desorbing of VOC from carbon occurs as steam condenses and the water displaces the VOC.
All naturally occurring zeolite is hydrophilic, having an affinity for polar substances, such as
water, but synthetic zeolite can be either hydrophilic or hydrophobic. Polymers are usually
hydrophobic unless made specifically with other affinity. For example, amphophilic block
copolymers can have both hydrophilic and hydrophobic affinities. Thus, the affinity has to be
considered as part of selecting the particular adsorbent.
Some polymers and hydrophobic zeolite are generally much less sensitive to humidity than
carbons, and are also much less subject to fire, crumbling, or powdering. Therefore, they require
much less frequent replacement. Carbons are cheaper (at least initially). The cost per pound of
carbon is about $2.00, which is up to 20 times less than the cost per pound for either polymers or
zeolite. However, the need to replace zeolite is very rare, and the replacement of polymers occurs
only slightly more often. Carbon needs to be replaced every six months to five years, or when
there is a bed fire. The frequency depends on the type of carbon, the frequency of regeneration,
and the temperature at which it operates.
Some polymeric adsorbents were evaluated by General Electric Co. for thermal desorption, and
found to desorb faster than carbon, to have larger adsorption capacity in either high or low
humidity after conditioning, and to desorb at lower temperatures. The maximum temperature for
Christensen Arms AO Modification 9/7/23
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in out
concentration
MTZ
time
Figure 3. Movement of MTZ with Time
desorption must exceed the boiling point for the VOC, but must not exceed the polymer’s melting
point.
The maximum temperature for desorption is less confining for carbon, which may be taken to a
much higher temperature (250E to 350EF) without melting. Carbon frequently catalyzes
oxidation reactions when the temperature gets above this range. The same maximum temperature
is commonly used for zeolite, but the real limit for zeolite depends on either the pyrolysis
temperature, the catalyzation temperature of the adsorbed VOC, or the range of temperatures at
which the crystal structure is stable for the zeolite. This metastable temperature range is generally
considered to be up to about 1,000EF.
ARE THERE OTHER DESIGN CONSIDERATIONS?
YES! These other factors are described individually below:
MASS TRANSFER ZONE
The Mass Transfer Zone (MTZ), see Figure 3, exists in all adsorbents. In the MTZ, the
concentration of VOC in air goes from 100% of the inlet vapor concentration to the lowest
available vapor pressure in equilibrium with the desorbed adsorbent.
The depth of the bed is the dimension of the adsorbent in the direction of air flow, and the MTZ is
usually much shorter than the depth of the bed. The MTZ moves through the bed as the bed
reaches its capacity (the absorption isotherm becomes filled). Upstream of the MTZ, the bed has
reached its capacity, while downstream the bed remains essentially desorbed. Breakthrough
occurs when the MTZ reaches the downstream end of the adsorption bed. Breakthrough is
Christensen Arms AO Modification 9/7/23
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observed as a rise in the VOC vapor concentration leaving the bed, which may occur at different
times for different VOC.
Adsorbents of all types share a characteristic with columns used in gas chromatography, for these
too use adsorption. The adsorbed material will desorb spontaneously and migrate downstream
with the gas flow in each system. This is caused by the pressure gradient, which is intentionally
very low when adsorbers are used as an emission control technology, and rather high in the gas
chromatography adsorption column. This migration of pollutants is generally slow enough that it
may be neglected when emissions are being controlled. However, this property defines an
absolute maximum time for adsorption before regeneration of the bed. Breakthrough is actually a
gradual process because the equilibrium between the vapor pressure and the adsorbent is
continuously varying. Thus, breakthrough can be defined as any noticeable rise in the effluent
concentration.
The MTZ will also migrate to breakthrough independent of the VOC loading. An input spike of
VOC, along with the migration of the MTZ, will allow the spread of the VOC and reduce the
concentration that will be desorbed at breakthrough. An example of how an adsorber might
properly use the migration characteristic of the MTZ is in air flow from a hood in a plant that
handles mercaptan. Natural gas is odorless and mercaptan is added to natural gas to provide an
olfactory (odor) indication of a leak. If the mercaptan spill gave emissions in concentrations more
than one part per billion, people would smell it, and be alarmed because they would think that
there was a leak of natural gas. Therefore, hoods where mercaptan is handled are equipped with a
suitably sized adsorber. This adsorber captures any vapors from spills and, when the MTZ
migrates to breakthrough, the mercaptan is released at a lower concentration in this case. This is
because the mercaptan was not a continuous emission, the adsorber did not reach its capacity, and
therefore breakthrough occurred at a lower concentration which was below the threshold of smell.
For this purpose, desorbing or regeneration is not necessary unless the spills are too frequent.
WORKING CAPACITY
The “conditioning cycles” are the number of cycles (often about five) that are required to achieve
a stable amount of adsorption and regeneration. Carbon, after undergoing the conditioning
cycles, is capable of adsorbing about 50% of the amount that was adsorbed by the virgin material.
Zeolite is capable of adsorbing about 90% of the amount adsorbed by the virgin material.
Polymers can vary over the range of 50% to 90%. This “conditioned isotherm” also defines the
“working capacity” of the adsorbent. The fact that carbon and some polymers will typically
desorb only 50% as much as the virgin material is thought to be caused by the continued
recapture of molecules (i.e., depressed vapor pressure) in the micro-pores. VOC can be removed
from these micro-pores only by pyrolysis, which would destroy the VOC, and either destroy the
polymer or alter the properties of the carbon.
Christensen Arms AO Modification 9/7/23
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Zeolite has a uniform pore size and therefore does not exhibit this phenomenon. Polymers have
an extended range of pore size, and in some respects are similar to carbons, but some polymers
are thought to lack the very small micro-pores. Carbon also displays a time-related spreading of
VOC from the macro-pores to the micro-pores. Zeolite and polymers show this time dependent
spreading to a much less noticeable degree.
The “working capacity” of the adsorbent is determined by the difference between the desorbed
conditioned level and the full adsorption isotherm of the adsorbent. Thus, the conditioning effect
must be considered when sizing the adsorbent bed. The conditioning effect can require up to
twice as much adsorbent in the bed. Since regeneration should occur only about every 8 or 16
operating hours, the capacity of the bed(s) can be determined by the concentration of VOC, the
air flow rate, the weight of adsorbent in the bed(s), the type of adsorbent, and the “working
capacity” of the adsorbent. In this way, the “working capacity” can have a significant effect on
the cost of installing, operating, and maintaining an adsorber.
VAPOR PRESSURE
Carbon and polymers have a linear adsorption isotherm relative to vapor pressure, while zeolite
has a very non-linear adsorption isotherm relative to vapor pressure for the molecules it has an
affinity to. This linearity makes either carbon or polymers the better adsorbent when the vapor
pressure (or concentration) is higher, but the non-linearity makes zeolite the better adsorbent
when the vapor pressure (or concentration) is lower. This property allows carbon or polymer
adsorbent in a “sacrificial” (or first) bed followed in the air flow by a suitable zeolite in a
“polishing” bed to produce the lowest vapor pressure of VOC in the outflow. The lower the
partial pressure of the VOC in the outflow, the higher the control efficiency.
MULTIPLE ADSORBENTS
There is also an advantage to using a mixture of adsorbents. A mixture of carbon and zeolite
removed mixed vapors of xylene and methanol better than an adsorbent composed of either.
Hussey and Gupta of Durr Industries reported this at the Spring 1997 Meeting of American
Institute of Chemical Engineers. They noted that the path through the mixture was greater than
the path through either of the adsorbents when used alone, and they attributed the increased
adsorption to the greater path length. However, both methanol and xylene were adsorbed, and
since the authors stated that carbons adsorb xylene well while a six or eight Dngstrom pore size
zeolite adsorbs methanol well, the depth would have had to be the sum of the individual bed
depths to yield this result. This paper also observed that at high concentrations, carbon adsorbs
better, and can be used as a “sacrificial” bed upstream of a zeolite “polishing” bed.
ADSORPTION MODELS
In order to know just how well the chosen adsorbent will perform, the adsorbent must be tested
with the mix of pollutants that are to be adsorbed, and at the concentrations that are expected.
Christensen Arms AO Modification 9/7/23
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This must be done whether using one adsorbent alone or using a combination of adsorbents. It
must also be done for a mixture of VOC vapors. Various multi-space adsorption models can
predict how a combination of VOC will adsorb, but these are all based on assumptions that fit the
results to the individual experiment. Examples are by V. Gusev and J. O’Brien of Yale
University; and C. Jensen and N. Seaton of University of Cambridge; M. Heuchel of the
University of Leipzig. The various multi-space adsorption models must be proven to apply to
your mix and concentration of VOC, and the chosen adsorbent.
BED FIRES
All adsorption is exothermic, that means that adsorption gives off heat and causes a temperature
rise. This property has been used for heat storage, but is not desirable for adsorption of VOC.
Carbon or metals on the carbon have been known to catalyze the oxidation of some pollutants
when the adsorbent is hot, resulting in bed fires which also consume part or all of the carbon.
This is a hazard when adsorbing certain hydrocarbons (such as ketones or turpentines) at ambient
temperatures that are close to those that cause the VOC to oxidize. Such a carbon bed fire can
either alter the pore size of the remainder of the bed, or oxidize the bed to ash. These fires have
been suppressed by humidification of the air, leaving some water in the bed after steam
regeneration, and by intentional cooling of the carbon. Polymers usually are used at temperatures
which do not lead to bed fires, but this must be assured. Zeolite is not flammable, but can
catalyze oxidation if the temperature gets high enough. The pore size of the zeolite is not affected
by temperatures that stay within the metastable range. Normally, in case of a bed fire with
zeolite, only the VOC would be lost if the air flow is controlled to limit the temperature. If the
temperature rises above the metastable range, the pore size of the zeolite will be reduced and the
density of the zeolite will be increased.
OFF-SITE ADSORBENT REGENERATION
Some customers use the regeneration of the carbon off-site. For example, some “perc” dry
cleaners use this technique. They replace their carbon canisters instead of regenerating them on
the premises. This requires determining whether you want the bother of a boiler, fuel, and the
labor charges that this entails (or else the vacuum pump and refrigerated condenser) or are willing
to pay someone else to regenerate your adsorber for you. Speaking in economic terms, while
remote regeneration spares you the direct expense of a boiler and its operation (or a vacuum
pump and its operation) the regeneration facility will charge you a fee that will cover all costs,
plus labor, collection, replacement, regeneration, disposal, and profit. This fee should be less per
customer when it is spread across a customer base than when one firm must handle it alone. A
shared capability would distribute the cost. However, if your adsorber loading is large enough, it
should cost less to have your own regeneration capability.
AFFINITY
The affinity between the VOC to be adsorbed and the adsorbent must be considered. If the
Christensen Arms AO Modification 9/7/23
10
adsorber
adsorber
boiler
vapor in air out
Figure 4. Thermal Swing Adsorber
(steam regeneration)
VOC
affinity for one molecule in the flow is sufficiently greater than the affinity for another, then the
adsorbent will preferentially adsorb the molecule for which it has the greater affinity, and allow
transport of the other to occur at up to air flow velocity. Thus, the bed upstream of the MTZ
would become saturated with the molecule for which the adsorbent had greater affinity (assuming
that the pore size allowed it), while passing other molecules of lower affinity to adsorbent further
through the bed and ultimately to the exhaust. As the MTZ moves through the bed, it would
cause the release of the molecule with lower affinity, while adsorbing the molecules for which it
has higher affinity.
HOW CAN ADSORBERS BE REGENERATED?
There are three methods of regeneration: Thermal Swing Regeneration, Vacuum Regeneration,
and Pressure Swing Adsorption. We shall discuss these separately.
THERMAL SWING REGENERATION
The traditional carbon adsorber system uses steam to raise the temperature of the adsorbed VOC
and boil it from a carbon adsorbent after the carbon has adsorbed the VOC. This has become
known as a thermal swing regeneration adsorber system. It is so named because the temperature
is usually swung between ambient and 250E to 350E F in regeneration.
A thermal swing adsorber system is shown schematically in the diagram of Figure 4. Vapor in the
air is transported into one adsorber (two are shown, but any larger number can be used), while the
other is being regenerated. Steam flows into the adsorber being regenerated to heat the
adsorbent, and thus desorb the VOC. After the VOC are desorbed, cooling air from a blower is
admitted in place of the steam. When the adsorbent has cooled and dried to the extent intended,
the “conditioned” adsorption capacity has been restored, and the bed is now regenerated.
Christensen Arms AO Modification 9/7/23
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adsorbervapor in air out
purge gas
vacuum pump
adsorber
Figure 5. Vacuum Regeneration Adsorber
VOC
Regeneration occurs in a preset time if the average VOC concentration is according to the design
parameters. However, if either the air flow or the concentration vary unpredictably, a sensor
should be used. A predictable air flow and concentration would allow the regeneration to occur
at a given time before the breakthrough occurs. If the timer were properly set, it would avoid any
breakthrough emissions. A sensor should be used to control regeneration if either the air flow or
the concentration of VOC is unpredictable, or if the timer were improperly set.
Prior to breakthrough, the emission concentration is actually very low, and a sensor would have
to sense a concentration reading above this level to start regeneration of the adsorber bed. While
some greater concentration of VOC will pass through before any regeneration occurs with a
sensor, this may allow either more (by having a higher threshold) or less emissions (if the timer
allowed breakthrough to happen) than using a timer. However, any increase in emissions may
actually be a trivial amount when compared with the amount of the controlled emissions. Either a
timer or a sensor can be suitable, if properly set and properly used. Either one can be unsuitable,
if improperly set or improperly used.
Thermal regeneration has historically used steam, but other heat sources have been tried
successfully. These include: microwaves, embedded heaters, and heated nitrogen. These have
been used with all adsorbents. Thermal regeneration becomes more practical when VOC have
lower vapor pressures.
VACUUM REGENERATION
To enhance solvent recovery, and eliminate contamination of the VOC by steam, a vacuum
regeneration system may be used. Figure 5 shows a schematic of a vacuum regeneration
adsorbtion system. This uses a vacuum pump to lower the pressure in the adsorber to below the
vapor pressure of the adsorbed VOC, which causes the VOC to boil off at the temperature that is
ambient within the adsorbent, instead of at a higher temperature. In the process of boiling, the
temperature of the adsorbent will actually go below the normal outside ambient temperature. This
method can be used with carbon, polymer, and zeolite adsorbents.
Christensen Arms AO Modification 9/7/23
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adsorber 1
adsorber 2
adsorber 3
vapors in
air out
gas bleed in
vacuum
pump VOC recovery device
Figure 6. Cascade Vacuum Separation
Sometimes a small flow of purge gas is used to enhance transport of the VOC vapor. The VOC
vapor is then recovered by separation (condensation, membrane separation, compression, or some
similar process) of the flow from the vacuum pump.
The purity of the recovered VOC is not affected by the vacuum, but may be affected by the
mixture of the VOC vapors or the purity of the purge gas. If there are mixed VOC vapors that
are being controlled, the recovered VOC will also be mixed unless the pore size or affinity of the
adsorbent or the temperature of condensers separate the vapors. The purity of the purge gas is
especially important when a water-soluble VOC, such as an alcohol or a ketone, is to be
recovered and the purge gas contains moisture. The water vapor will be adsorbed and desorbed
along with the VOC vapor, and the VOC may require subsequent purification if it is to be reused.
Contamination by moisture has been avoided by using dry nitrogen as a purge gas. The recovered
VOC is otherwise as pure as the VOC vapor.
The desorbed VOC are sometimes purified by distillation, skimming, or membrane separation.
The recovered VOC is then either recycled in the process that released it, used elsewhere in the
plant, or sold. If the purity of the VOC is too low for economical recovery, or the value of the
recovered solvent too low, the VOC would be destroyed in the vapor state. Choices of an
appropriate process for destruction include flameless oxidation, thermal incineration, or catalytic
incineration.
When a zeolite adsorber is divided into several fixed beds in cascade flow as in Figure 6, and
when granules of appropriate zeolite are used, the several types of VOC vapors can be adsorbed
in separate beds. European firms have already adopted zeolite fixed beds. The acceptance may
be based upon the fact that Europe and Asia are prime sources of natural zeolite.
Christensen Arms AO Modification 9/7/23
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vapor in air out
air bleed
heat
incinerator
Figure 7. V O C Concentrator
rotation
adsorber
stack
The VOC can then be recovered individually from these beds, and the resulting VOC can be purer
than the mixed vapors. The key is in the selection of the zeolite. While nobody currently
advertises the commercial availability of this vacuum regenerated zeolite adsorption system,
research supporting it has been done. It is the next logical step, and its development is
anticipated.
VAPOR CONCENTRATOR
Although adsorbers have historically been used independently as a pollution control device, the
vapor concentrator has also appeared. The vapor concentrator is intended to raise the
concentration of VOC vapor to provide more economical treatment in either combustion or
condensation devices.
The typical concentration ratio (output VOC concentration divided by input VOC concentration)
that can be obtained from a vapor concentrator can range to well over a thousand. However,
when the actual concentration of a combustible VOC is near one-fortieth of the LEL, you can
economically justify using a rotary vapor concentrator, which may also include an incinerator.
Figure 7 shows a rotary vapor concentrator. This is used where the VOC vapor is in a large air
flow, and must be concentrated before it can be incinerated economically. (The concentrator air
bleed is usually about 10%of the input air flow with an incinerator, and thus the concentration
ratio is about ten.) Therefore, if the initial concentration is one-fortieth of the LEL, the resulting
concentration is about one-fourth of the LEL. This means that, for incineration, a minimum of
fuel would have to be added to assure enough heating value for adequate incineration.
Christensen Arms AO Modification 9/7/23
14
The adsorbent is mounted in a wheel that is rotating either vertically or horizontally. If the wheel
is rotating about a horizontal axis, the air flows axially through sectors in the wheel. If the wheel
rotates about a vertical axis, the air flows radially through segments on the rim of the wheel. The
adsorbent is located in relatively shallow beds in the sectors or the segments. The adsorbent can
be zeolite alone, a mixture of zeolite with carbon, a mixture of zeolite with polymer adsorbents, or
either carbon or polymer adsorbent beds with zeolite beds downstream.
As shown in the rotary vapor concentrator diagram, the air bleed is heated by the incinerator, and
the heat is then fed to a sector or segment of the rotating wheel to regenerate the adsorbent. This
sector or segment is isolated by seals which allow the VOC to be recaptured and sent to the
incinerator at a higher concentration than was present in the input air flow. This allows the VOC
to have a greater heating value per cubic foot and, therefore, less additional fuel is required to
raise the temperature to a level where the destruction or recovery efficiency (DRE) of the
incinerator is above 98 %. The VOC is incinerated to provide heat to the air bleed for
regeneration of the adsorbent bed.
An alternative would be to regenerate at a lower temperature and condense the VOC. The
temperature would have to be above the minimum temperature for regenerating the VOC with
that adsorbent and the cost of refrigerated condensation would have to be included. This would
use a “heat pump” to send the heat of condensation to the air bleed for desorbing the VOC. The
fact that this uses only a tenth as much air flow reduces the cost of refrigeration. Both options are
available.
It is important for safety that the maximum concentration remain below one-fourth of the LEL, so
the concentration ratio should be controlled to assure this. The closer the higher concentration
gets to one-fourth of the LEL, the less fuel must be added to supplement the heating value of the
VOC. The limit of one-fourth of the LEL is imposed by Occupational Safety and Health
Administration (OSHA) and the National Fire Prevention Association (NFPA) for fire and
explosion safety.
As a result of using the rotary vapor concentrator, the incinerator can be much smaller, requiring
only about 10% of the volume otherwise required to provide an equal residence time. The cost of
an incinerator in the OAQPS Control Cost Manual is proportional to the air flow rate times the
residence time raised to either the 0.25 or 0.55 power, depending upon the type of incinerator.
Therefore, using the concentrator also produces savings in the cost of the incinerator.
Fluidized bed concentrators have also been developed which are analogous to the rotary vapor
concentrator. It is claimed that these are capable of raising the VOC concentration in the air flow
by as much as 10,000:1. However, since carbon is not an efficient adsorbent at such low
concentrations of VOC, zeolite or polymers may have been used as adsorbents or mixed with the
carbon to allow such low concentrations to be adsorbed. The use of such an adsorber might be
related to odor reduction, in which such low concentrations would be normal. The operating
cycle is otherwise very similar to the rotating wheel concentrator. However, the cycle is based
Christensen Arms AO Modification 9/7/23
15
adsorbermixture in one gas out
other gas out
Figure 8. Pressure Swing Adsorption
upon fluidized transfer of the adsorbent from the adsorption bed to the desorption region. It uses
the rate of adsorbent transport versus the rate of air flow to obtain the concentration ratio.
PRESSURE SWING ADSORBER
Figure 8 shows a schematic diagram of a pressure swing adsorption system. This is used for
separation of gases or vapors from air based upon their adsorption isotherms being a function of
total pressure, as well as vapor pressure, and temperature. It is also used to separate pollutants
from flue gases.
The mixture of gases or vapors is admitted to pressurize the adsorber, which contains the
adsorbent. Some gases are adsorbed more quickly than others, and the cycling frequency is used
to separate these. In other cases, one gas or vapor is adsorbed preferentially and the cycling
frequency is less important. After admitting the gas mixture, the gas that is not adsorbed as
strongly is vented, which brings the pressure to a lower level. When this venting is stopped, the
pressure is further reduced to desorb the other gas or vapor. This has been used to separate
oxygen from air, carbon dioxide from air, carbon dioxide from flue gas, sulfur dioxide from flue
gas, and gasoline vapors from tanks venting to the atmosphere. It is effective when the
preferentially adsorbed gas or vapor has a relatively large concentration.
This is not usually considered as a control technology. The vapors have to be at concentrations of
tens of thousands of parts per million, rather than the hundreds or thousands of parts per million
which are usually controlled as emissions. However, they are used in control of vapors from
vents on VOC storage tanks (such as gasoline).
Christensen Arms AO Modification 9/7/23
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ARE ADSORPTION SYSTEM DESIGN TOOLS AVAILABLE?
EPA has design equations for the thermal swing carbon adsorber in the OAQPS Control Cost
Manual. These equations are used in the Air Compliance Advisor (ACA) and the CO$T-AIR
spreadsheet software (See References). The design equations for polymer and zeolite adsorbers
and other adsorption systems have not yet been determined by EPA, but should be analogous
when the differences have been accounted for. These differences have to do with weight of
adsorbent, superficial air flow rate, cost of a vessel which must withstand evacuation, etc.
The designers of an adsorption system really earn their fee. They must choose the type of system
to be compatible with the VOC and the purpose. They must choose (or help choose) the
adsorbent, the size and number of beds, the construction of the container for each bed, the
regeneration method, the time that the adsorber should be used before regeneration (determined
by air flow and the concentration of VOC), how many beds should be used in parallel, the choice
of boiler or vacuum pump, the instrumentation and controls that will operate these in the proper
sequence at the proper time, and the location and sequencing of pipes and valving for the
operation. Then they must execute a design in which all of these things work together. They
must assure that the adsorber does not experience breakthrough in too short a time. They must
have the unit meet the customer’s specifications, and they must keep an eye on the costs, and
assure the costs are not excessive.
As a result, they must be familiar with the system they are designing. That is the rub, for each
designer will choose the system that they are most familiar with, unless it is absolutely ruled out
by the customer. The system that all designers are familiar with is the thermal swing carbon
adsorber system, for it has been used for several decades. They are often not familiar with the
newer systems, regeneration techniques, or adsorbents. The newer systems, regeneration
techniques, and adsorbents have distinct advantages over the older ones.
WHAT CONTROL EFFICIENCY SHOULD YOU EXPECT TO GET?
You should expect a well designed adsorber system to achieve 95% - 98% control efficiency at
input concentrations between 500 and 2000 ppm in air. This is independent of follow-up systems
such as an incinerator or a condenser. Therefore, the control efficiency of a combined adsorber
and incinerator might be:
adsorber efficiency x incinerator efficiency = 95% x 98% = 93.1%
while the efficiency of a combined adsorber and condenser might be:
adsorber efficiency x condenser efficiency = 95% x 99% = 94.05%
The actual control efficiency of both the adsorber and the follow-on device will be involved.
Neither the efficiency of the adsorber nor the efficiency of the follow-on device is more dominant,
Christensen Arms AO Modification 9/7/23
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but whichever one that has the lower efficiency will cause more loss in the total efficiency.
WHAT TYPE OF SOURCES CAN USE ADSORPTION TECHNOLOGY?
VOC and organic hazardous air pollutant emissions can be controlled, recovered, recycled, or
concentrated for additional treatment by adsorption technology. This includes emissions from:
dry cleaning, degreasing, paint spraying, solvent extracting, metal foil coating, paper coating,
plastic film coating, printing, pharmaceuticals, rubber, linoleum, and transparent wrapping. Any
process that generates VOC emissions at low concentrations (as low as 20 ppm) at relative high
air flows (greater than 5,000 acfm) should consider adsorption technology to concentrate VOC in
the emission stream prior to final treatment and either recycling or destruction.
HOW MUCH DO ADSORBERS COST?
Procedures, data, and equations for sizing and estimating the capital and annual costs of thermal
swing (“regenerative”) carbon adsorption systems are given in the OAQPS Control Cost Manual
(5th edition, February 1996). For the users’ convenience, these OAQPS Control Cost Manual
equations have been incorporated into the CO$T-AIR control cost spreadsheets and the Air
Compliance Advisor program, all of which can be downloaded from the CATC Web page. We
must emphasize, however, that these equations provide “study” (+/- 30% accuracy) cost estimates
for only those adsorbers that use activated carbon. Cost-estimating procedures for polymer or
zeolite-based adsorption systems have yet to be developed by EPA. Those interested in the latter
should contact one or more vendors of those systems. (See extensive vendor list at the end of this
bulletin.)
Carbon adsorber costs depend on a variety of facility, regulatory, sizing, and cost parameters. For
that reason, no meaningful cost rules-of-thumb can be developed. Facility parameters include,
first of all, the exhaust gas and pollutant characteristics--volumetric flow rate, temperature,
pressure, VOC composition, VOC loading, and moisture and particulate contents. Another
important facility parameter is its status, i.e., new or existing. At an existing facility, the cost of
installing the adsorber equipment typically will be higher. The difference between this higher
installation cost and the cost of installing the same control system at a new facility is termed the
“retrofit penalty”.
Depending on how the regulation is written, the most pertinent regulatory parameter is either the
mandated VOC outlet concentration or the corresponding adsorber control efficiency required to
meet it. Sizing parameters include the material of construction (304 stainless steel is typical for
carbon adsorbers), amount of insulation, pressure drop, adsorbent working capacity, and whether
the system is factory-assembled (“packaged”) or built on site (“custom”).
One of the most important design parameters is the adsorption time. This time is often selected to
be compatible with production schedules. For example, an adsorber controlling a printing
operation that runs in eight-hour shift increments might have an eight-hour adsorption time. At
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the end of each shift, the adsorber bed(s) would be regenerated in time to be put back on line
before the next shift begins. Clearly, as the adsorption time increases, so does the amount of
adsorbent required and, hence, the size, number, and cost of the adsorber vessels. But while
shorter adsorption times result in smaller adsorber systems and lower capital costs, higher annual
costs are required because the adsorbent must be regenerated more frequently. These primarily
consist of increases in the steam requirement (for bed regeneration) and electricity demand (for
the bed drying/cooling fan). With steam regeneration the user has the option of either generating
steam on-site via an existing boiler or purchasing a new boiler dedicated to that purpose.
Alternatively, the user may choose to purchase the steam from an outside source.
The above decisions and selections are within the user’s purview. However, the user will not
have to be concerned with such details as sizing the steam lines, selecting the bed drying/cooling
fan, designing the adsorber vessels, etc. Those kinds of specifications are determined by the
adsorber vendor whose application experience and knowledge of the adsorption process is much
more extensive.
The cost and cost-related parameters, such as the annual operating hours, also heavily influence
the “bottom line”. These include prices for carbon, electricity, steam, operating and maintenance
labor, and replacement adsorbent (including the replacement labor cost), as well as the interest
rate and the useful lives of the adsorbent and the rest of the control system. One of the most
critical cost parameters is the value assigned to the recovered VOC. As the example below
illustrates, if the quantity of recovered VOC is large enough, its value can offset the annual costs,
resulting in a net annual credit. Obviously, this value must be chosen carefully, keeping in mind
both the current market price of the VOC and the purity of the recovered organics. The greater
the purity, the higher the value. (For more information on these and other parameters, refer to
Chapter 4 (“Carbon Adsorbers”) of the OAQPS Control Cost Manual.)
Consider the following hypothetical illustration. Four existing printing operations emit toluene
(an ink solvent) in quantities large enough to attract the attention of a state air pollution control
agency. The agency’s regulations for these printing operations require that 98% of the toluene be
removed before the exhaust may be vented to the atmosphere. The smallest of these operations
emits 50 lb/hour of toluene at a flow rate of 5,000 actual cubic feet/minute (acfm), while the
largest emits 1,250 lb/hour at a 50,000 acfm flow rate. The other two emit 250 lb/hour each at
5,000 and 50,000 acfm, respectively. What would be the capital and total annual costs (TAC) of
steam regeneration carbon adsorber systems installed to control the toluene from these
operations?
The Table 1 lists these costs for each of the four adsorber systems. Computed via the CO$T-AIR
carbon adsorbers spreadsheet, these costs reflect second quarter 1998 prices for equipment,
carbon, utilities, labor, and toluene. Price sources consulted included the Department of Energy’s
Monthly Energy Review (electricity and distillate oil for steam production), the Bureau of Labor
Statistics (printing and publishing labor), and the Chemical Marketing Reporter (toluene). (Note:
All costs have been rounded to two significant figures.)
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As we might expect, the capital costs increase with both increasing gas flow rate and toluene
emission rate. Larger flow rates require larger and more costly adsorber vessels, decanters,
condensers, and other equipment. By the same token, as the emission rate increases, more carbon
must be provided for adsorption. Note that the unit capital cost ranges from $22/acfm to
$87/acfm--a factor of four ratio. Such a wide range discourages the use of such rules of thumb
for capital cost estimating.
Gas Flow
Rate (acfm)
Toluene
Emitted
(lb/hr)
Capital Cost Total Annual Cost (Credit)
1,000 $$/acfm 1,000 $/yr $/million acf
5,000
50 240 48 43 18
250 430 87 (19)(8.0)
50,000
250 1,100 22 110 4.6
1,250 1,700 33 (280)(12)
Table 1. Cost of Thermal Swing (“regenerative”) Carbon Adsorption Systems
Other important inputs to these costs include:
* Operating hours/year: 8,000
* Adsorption and desorption times: 8 and 4 hours, respectively.
* Inlet gas temperature: 77EF.
* Annual interest rate: 7%
* Equipment lives (years): 10 (adsorber system); 5 (carbon)
The total annual cost (TAC) does not vary smoothly, however. Note that, for the 5,000 acfm
systems, increasing the emission rate from 50 to 250 lb/hour decreases the TAC from
$43,000/year to a net credit of $19,000/year. The annual costs for the 50,000 acfm systems
behave similarly. Clearly, the toluene recovery credit heavily influences the TAC. This credit, in
turn, depends on three parameters: the inlet emission rate, the control efficiency, and the value
assigned to the recovered organic. The first two parameters will be essentially constant for a
given emission source and control system. But, as discussed above, the expected recovery value
can vary significantly according to market conditions and, for that reason, it must be selected
carefully. Finally, the unit TAC ranges widely, from a credit of $12/million acfm treated to a cost
of $18/million acfm.
As we have shown, both the capital and total annual costs for these hypothetical systems cover a
broad range. And remember that these costs vary so widely for adsorbers removing the same
VOC (toluene) emitted from the same type of source (printing operation) based upon identical
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input parameters (air flow rate and toluene emission rate excepted). Consider that the adsorption
of other VOC’s (and VOC mixtures) could require much more or less carbon, that other sources
could require much shorter or longer adsorption/desorption times, and that the input parameters
could be vastly different under other control scenarios. Thus, the only conclusion we can safely
draw about carbon adsorber costs--or, for that matter, the costs of any type of control system--is
no conclusion. You must get quotes from vendors, consultants, or designers.
For rotary vapor concentrators, zeolite is frequently used (either with or without other
adsorbents) as the adsorbent in vapor concentrators because it is more effective in adsorbing
lower concentrations of VOC. The cost of such a system depends upon air flow and VOC
concentration, and runs from about $1000 to $1500 per ton of VOC destroyed at 100 ppm, to
$3,250 per ton of VOC destroyed at 20 ppm, according to Munters ZEOL.
DECISIONS, DECISIONS...
Does your process have VOC emissions? Can you smell that your process is operating? If so,
your process probably emits a VOC, and the emissions of the VOC probably should be controlled.
Do emissions exceed 10 tons per year (55 pounds per day)? Do the emissions exceed your
operating permit? Any “yes” answer means that you probably are emitting a VOC that is in need
of control. Check with your state or local agency that issues operating permits if you are in
doubt. VOCs often (but not always) have between 2 and 16 carbon atoms. VOCs also react in
ultraviolet light (sunlight) with NO to multiply the NO2 which creates ozone.
If you are not sure whether an emission from your plant is a VOC, call EPA’s Clean Air
Technology Center (CATC) at 919-541-0800, or contact the CATC by FAX at 919-541-0242, or
by e-mail at catcmail@epamail.epa.gov and you will be referred to someone who can help you
determine this. We also have a CATC Web page at www.epa.gov/ttn/catc if you prefer to contact
us by that route.
If your process emits a VOC in any amount larger than 20 pounds per day, then you should look
into the topic of controlling emissions. We have seen several advertisements on the Internet at
URL’s (Internet addresses) for adsorber system designers and manufacturers. You can also use a
search algorithm, and commercial advertisements usually come first in their output.
When you have to control emissions of VOC, you have to make several decisions:
1. Will the VOC be destroyed or recovered? What re-use value will it have? This will affect the
design of the system, and the economics of operating it. Perhaps you will want all options
investigated.
2. If the VOC are to be recovered, how pure does it have to be? How much cost can be avoided
by not buying VOC with the purity that you require? If it must be very pure, you must decide
whether you are going to distill the VOC after recovery, or how that can be achieved.
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3. If purity is either not needed or not possible, and the VOC is not water soluble, you might use
a condenser with a skimmer to separate the condensed moisture or steam from the VOC.
4. You must decide whether you will use carbon, zeolite, or polymeric adsorbents. Each has its
advantages, each has its disadvantages. You must make this preliminary decision with expert
consultation before hiring a designer, because designers will design the kind of system that they
are most familiar with. There are many designers for systems having carbon regenerated by steam
because this system has been around for decades, but you will have fewer designers and
consultants available for newer systems and adsorbents.
5. There are several firms that offer rotary or fluidized bed concentrators. Some of these are:
(Note: Naming of these sources does not imply an endorsement, and this list is known to be
abbreviated and incomplete.)
ABB Paint Finishing 1400 Stephenson Hwy.Troy, MI 48099
Durr Environmental, Inc. 40600 Plymouth Rd.Plymouth, MI 48170
Engelhard 101 Wood Ave.Iselin, NJ 08830-0770
JWP AMCEC 2625 Butterfield Rd.Oak Brook, IL 60521
Met-Pro Corp.160 Cassel Road Harleyville, PA 19438
Munters ZEOL 79 Monroe St P.O.Box 600 Amesbury, MA 01913-0600
6. Some other sources for adsorber design and/or construction are: (see Note above)
AMCEC Corp.2525 Cabot Dr.Suite 205 Lisle, IL 60532
ACR Activated Carbon Resources Inc.Westport, CT
American Air Filter P.O.Box 35690 Louisville, KY 40232-5690
American Environmental Int’l 5 Revere Dr Suite 200 Northbrook, IL 60062-9998
Aquest Corp.Somers, NJ
Atochem Inc. / CECA Division 266 Harristown Rd.Glen Rock, NJ 07452
Barneby & Sutcliffe P.O. Box 2526 Columbus, OH 43216
Baron-Blakeslee Inc.2001 N. Janice Ave. Melrose Park, IL 60160
COH Corp.2000 Eastern Pkwy Brooklyn, NY 11233
Calgon Carbon Corp.P.O.Box 717 Pittsburgh, PA 15230-0717
Carbtrol Corp.39 Riverside Dr.Westport, CT 06880
DR Technology Hidden Pines Drive Clarksburg, NJ 08510
Dedert Corp.2000 Governors Dr.Olympia Fields, IL 60461-1074
Ducon Environmental Syystems Co.110 BiCounty Rd.Farmingdale, NY 11735-3923
Envirotrol Inc.432 Green St P.O.Box 61 Sewickley, PA 15143
Filcorp Industries Milton, VT
FMG P.O.Box 3043 Union Gap, WA 98903
Green and Green Associates Lexington, MA
Hydrogroup Inc.1011 Hwy 22 Bridgewater, NJ 08807
HCT Corp.325 Lennon Lane Suite 200 Walnut Creek, CA 94598
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HydroQuip, Inc.63 N Washington St.N. Attleboro, MA 02761
Independent Equipment Corp. Rte. 202N P.O.Box 460 Three Bridges, NJ 08887
KX Industries Orange, CT
Kensington Corp.Madison, CT
Nuclear Consulting Services Inc. (NUCON)P.O.Box 29151, Columbus, OH 43229-1022
Penney Engineering Inc.Mansfield, MA
Peroxidation Systems Inc. 4400 E. Broadway, Suite 602 Tucson, AZ 85711-3558
Prime Carbon Bow, NH
R H Reimer Associates Needham, MA
Remedial Systems Inc. 56 Leonard St.Foxboro, MA 02035
Service Tech Inc.Swansea, MA
Tetrasolv Plymouth, MA
Tigg Corp.800 Old Pond Rd.Bridgeville, PA 15017-3415
Unisorb Corp.1310 Genoa St.S. Houston, TX 77587
VARA International 1201 19th Place Vero Beach, FL 32960
Waste Min Inc.Groton, MA
Westgates Carbon Inc. 2130 Leo Ave.Los Angeles, CA 90040-1634
Westport Environmental Systems 251 Forge Rd.Westport, MA 02790-0217
Wintek Corp.RR3 Box 337 Lime Rock Lane Califon, NJ 07830
Zimpro-Passavant Inc. 301 Military Rd.Rothschild, WI 5474
SOME REFERENCES: (some with Internet URL for the web page)
Organic Sponges for Cost-Effective CVOC Abatement, Final Report - July 1994, US DOE
Contract No. DE-AC21-92MC29110, General Electric Corporate Research and Development
Control Techniques for Volatile Organic Compound Emissions from Stationary Sources, EPA
453/R-92-018
OAQPS Control Cost Manual, EPA 453/B-96-001, February 1996
www.epa.gov/ttn/catc
Control of Gaseous Emissions, APTI, Course 415, Student Manual, EPA 450/2-81-005
Hydrophobic Zeolites as Adsorbents for Removal of VOC from Air, M. V. Chandak and Y. S.
Lin, Dept. of Chemical Engineering, University of Cincinnati
Impregnated Activated Carbon for Environmental Protection
www.activated-carbon.com/enviro.html
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23
Envirosense
es.epa.gov/studies/cs593.html
es.epa.gov/program/regional/state/wi/actcarbo.html
Adsorptive Recovery of Problematic Solvents
www.activated-carbon.com/probsol1.html
Gas Adsorption
chem.ufl.edu/`itl/4411L_f96/ads/ads_1.html
Steam Regeneration of Activated Carbon Beds, M. Huggahalli and J. Fair, American Institute of
Chemical Engineers, Annual Meeting, November 1996
Microwave Regeneration Field Test Unit
www.me.utexas.edu/~prep/demo.html
Preparation and Characteristics of Polymer-based Large Adsorbent Particles,
Journal of Applied Polymer Science, Vol. 61, No. 11, September 1996, pp 1949-1956
www.interscience.wiley.com/jpages/0021-8995/abs/v61n11p1949.html
Microwave Regeneration of Volatile Organic Compound Adsorbents, P. Di and D. Chang, 96-
RA106.2, Air & Waste Manaagement Assn.
PADREO Vapor Treatment Process
www.nttc.edu/env/site95/demo/ongoing/purus.html
Gas-Surface Dynamics
www.ssci.liv.ac.uk/~darling/dynamica/index.html
www.ssci.liv.ac.uk/~darling/dynamica/history/ancient.html
The Desorption Process
alpha.qmw.ac.uk/~ugca000/surfaces/scc/scat2_5.htm
PE Curves & Energetics of Adsorption
alpha.qmw.ac.uk/~ugca000/srfaces/scc/scat2_4.htm
Adsorption Kinetics - The Rate of Adsorption
alpha.qmw.ac.uk/~ugca000/srfaces/scc/scat2_3.htm
How do Molecules Bond to Surfaces?
alpha.qmw.ac.uk/~ugca000/srfaces/scc/scat2_2.htm
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CO$T-AIR Spreadsheets
www.epa.gov/ttn/catc
Air Compliance Advisor
www.epa.gov/ttn/catc
Institute of Clean Air Companies
www.icac.com
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EPA-452/F-03-018
Air Pollution Control Technology
Fact Sheet
EPA-CICA Fact Sheet Catalytic Incinerator1
Name of Technology: Catalytic Incinerator
This type of incinerator is also referred to as a catalytic oxidizer, or catalytic reactor.
Type of Technology: Destruction by oxidation.
Applicable Pollutants:
Volatile organic compounds (VOC) and many types of particulate matter (PM). In the past, catalytic
incinerators were not recommended as a control device for PM, since the PM, unless removed prior to
incineration, often coated (or “blinded”) the catalyst so that the catalyst’s active sites were prevented from
aiding in the oxidation of pollutants in the gas stream (EPA, 1998). Examples are gases containing chlorine,
sulfur, and other atoms, such as phosphorous, bismuth, lead, arsenic, antimony, mercury, iron oxide, tin, and
zinc that may deactivate the supported noble metal catalysts (EPA, 1991).
However, catalysts have been recently developed that can tolerate almost any compound. Most of these
catalysts are single or mixed metal oxides, often supported by a mechanically strong carrier such as various
types of alumina. Catalysts such as chromia/alumina, cobalt oxide, and copper oxide/manganese oxide have
been used for oxidation of gases containing chlorinated compounds. Platinum-based catalysts are active for
oxidation of sulfur containing VOC, although they are rapidly deactivated by the presence of chlorine (EPA,
1996a).
Achievable Emission Limits/Reductions:
VOC destruction efficiency is dependent upon VOC composition and concentration, operating temperature,
oxygen concentration, catalyst characteristics, and space velocity. Space velocity is commonly defined as
the volumetric flow of gas entering the catalyst bed chamber divided by the volume of the catalyst bed. The
relationship between space velocity and VOC destruction efficiency is strongly influenced by catalyst operating
temperature. As space velocity increases, VOC destruction efficiency decreases, and as temperature
increases, VOC destruction efficiency increases. As an example, a catalytic unit operating at about 450/C
(840/F) with a catalys t bed volume of 0.014 to 0.057 cubic meter (m3) (0.5 to 2 cubic feet (ft3)) per 0.47
standard cubic meters per second (sm3/sec) (1,000 standard cubic feet per minute (scfm)) of offgas passing
through the device can achieve 95 percent VOC destruction efficiency (EPA, 1992). Higher destruction
efficiencies of (98 - 99 percent) are achievable, but require larger catalyst volumes and/or higher
temperatures, and are usually designed on a site-specific basis (EPA, 1991).
In EPA’s 1990 National Inventory, incinerators as a group, including catalytic incinerators, were reported as
being used as control devices for PM and were reported as achieving 25 - 99% control efficiency of PM10 at
point source facilities (EPA, 1998). Table 1 presents a breakdown of the PM10 control efficiency ranges by
industry where catalytic incinerators have been reported (EPA, 1996b). The VOC control efficiency reported
for these devices ranged from 0 to 99.9%, however, it is assumed that reports of higher efficiencies (greater
than 99%) are attributable to thermal incinerators. These ranges of control efficiencies are large because they
include facilities that do not have VOC emissions and control only PM, as well as facilities which have low PM
emissions and are primarily concerned with controlling VOC (EPA, 1998).
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EPA-CICA Fact Sheet Catalytic Incinerator2
Table 1. PM10 Destruction Efficiencies for Catalytic Incinerators and Catalytic
Incinerators with Heat Exchanger by Industry (EPA, 1996b)
Industry/Types of Sources
PM10 Control
Efficiency (%)
Petroleum and Coal Products
asphalt roofing processes (blowing, felt saturation); mineral calcining;
petroleum refinery processes (asphalt blowing, catalytic cracking,
coke calcining, sludge converter); sulfur manufacturing
25 - 99.9
Chemical and Allied Products
carbon black manufacturing (mfg); charcoal mfg; liquid waste
disposal; miscellaneous chemical mfg processes; pesticide mfg;
phthalic anhydride mfg (xylene oxidation); plastics/synthetic organic
fiber mfg; solid waste incineration (industrial)
50 - 99.9
Primary Metals Industries
by-product coke processes (coal unloading, oven charging and
pushing, quenching); gray iron cupola and other miscellaneous
processes; secondary aluminum processes (burning/drying, smelting
furnace); secondary copper processes (scrap drying, scrap cupola,
and miscellaneous processes); steel foundry miscellaneous
processes; surface coating oven
70 - 99.9
Electronic and Other Electric Equipment
chemical mfg miscellaneous processes; electrical equipment bake
furnace; fixed roof tank; mineral production miscellaneous processes;
secondary aluminum roll/draw extruding; solid waste incineration
(industrial)
70 - 99.9
Electric, Gas, and Sanitary Services
internal combustion engines; solid waste incineration (industrial,
commercial/ institutional)
90 - 98
Stone, Clay, and Glass Products
barium processing kiln; coal cleaning thermal dryer; fabricated
plastics machinery; wool fiberglass mfg
50 - 95
Mining
asphalt concrete rotary dryer; organic chemical air oxidation units,
sulfur production
70 - 99.6
Educational Services
solid waste incineration (commercial/ institutional)
80
Paper and Allied Products
boiler
95
Printing and Publishing
surface coating dryer; fugitives
95
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EPA-CICA Fact Sheet Catalytic Incinerator3
Applicable Source Type: Point
Typical Industrial Applications:
Catalytic incinerators can be used to reduce emissions from a variety of stationary sources. Solvent
evaporation processes associated with surface coating and printing operations are a major source of VOC
emissions, and catalytic incineration is widely used by many industries in this category. Catalytic incinerators
are also used to control emissions from the following (EPA, 1992):
•Varnish cookers;
•Foundry core ovens;
•Filter paper processing ovens;
•Plywood veneer dryers;
•Gasoline bulk loading stations;
•Process vents in the synthetic organic chemical manufacturing industry (SOCMI);
•Rubber products and polymer manufacturing; and
•Polyethylene, polystyrene, and polyester resin manufacturing.
Catalytic oxidation is most suited to systems with lower exhaust volumes, when there is little variation in
the type and concentration of VOC, and where catalyst poisons or other fouling contaminants such as
silicone, sulfur, heavy hydrocarbons and particulates are not present.
Emission Stream Characteristics:
a.Air Flow: Typical gas flow rates for packaged catalytic incinerators are 0.33 to 24 sm3/sec (700
to 50,000 scfm) (EPA, 1996a).
b.Temperature: Catalysts in catalytic incinerators cause the oxidizing reaction to occur at a lower
temperature than is required for thermal ignition. Waste gas is heated by auxiliary burners to
approximately 320/C to 430/C (600/F to 800/F) before entering the catalyst bed (AW MA, 1992).
The maximum design exhaust temperature of the catalyst is typically 540/ - 675/C (1000/ - 1250/F).
c.Pollutant Loading: Catalytic incinerators can and have been used effectively at very low inlet
loadings; down to 1 part per million by volume (ppmv) or less (EPA, 1995). As with thermal and
recuperative incinerators, for safety considerations, the maximum concentration of the organics in
the waste gas must be substantially below the lower flammable level (lower explosive limit, or LEL)
of the specific compound being controlled. As a rule, a safety factor of four (i.e., 25% of the LEL)
is used (EPA, 1991, AWMA, 1992). The waste gas may be diluted with ambient air, if necessary,
to lower the concentration.
d.Other Considerations: Characteristics of the inlet stream should be evaluated in detail, because
of the sensitivity of catalytic incinerators to VOC inlet stream flow conditions, which may cause
catalyst deactivation (EPA, 1992).
Emission Stream Pretreatment Requirements:
Typically, if design conditions are satisfied no pretreatment is required, however, in some cases, PM removal
may be necessary before the waste gas enters the incinerator.
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EPA-CICA Fact Sheet Catalytic Incinerator4
Cost Information:
The following are cost ranges (expressed in 2002 dollars) for packaged catalytic incinerators of conventional
design with fixed beds under typical operating conditions, developed using EPA cost-estimating spreadsheets
(EPA, 1996a) and referenced to the volumetric flow rate of the waste stream treated. The costs do not include
costs for a post-oxidation acid gas treatment system. Costs can be substantially higher than the ranges
shown when used for low-VOC concentration streams (less than around 100 ppmv). As a rule, smaller units
controlling a low concentration waste stream will be much more expensive (per unit volumetric flow rate) than
a large unit cleaning a high pollutant load flow. Operation and Maintenance (O & M) Costs, Annualized Cost,
and Cost Effectiveness are dominated by the cost of supplemental fuel required.
a.Capital Cost: $47,000 to $191,000 per sm3/sec ($22 to $90 per scfm)
b.O & M Cost: $8,500 to $53,000 per sm3/sec ($4 to $25 per scfm), annually
c.Annualized Cost: $17,000 to $106,000 per sm3/sec ($8 to $50 per scfm), annually
d.Cost Effectiveness: $105 to $5,500 per metric ton ($100 to $5,000 per short ton), annualized
cost per ton per year of pollutant controlled. However, when used to treat very low
concentrations of toxic air pollutants (less than 100 ppmv), the cost per ton removed may be
many thousands of dollars, because only a small amount of pollutant is being destroyed.
Theory of Operation:
Catalytic incinerators operate very similar to thermal/recuperative incinerators, with the primary difference that
the gas, after passing through the flame area, passes through a catalyst bed. The catalyst has the effect of
increasing the oxidation reaction rate, enabling conversion at lower reaction temperatures than in thermal
incinerator units. Catalysts, therefore, also allow for smaller incinerator size. Catalysts typically used for VOC
incineration include platinum and palladium. Other formulations include metal oxides, which are used for gas
streams containing chlorinated compounds (EPA, 1998).
In a catalytic incinerator, the gas stream is introduced into a mixing chamber where it is also heated. The
waste gas usually passes through a recuperative heat exchanger where it is preheated by post combustion
gas. The heated gas then passes through the catalyst bed. Oxygen and VOC migrate to the catalyst surface
by gas diffusion and are adsorbed onto the catalyst active sites on the surface of the catalyst where oxidation
then occurs. The oxidation reaction products are then desorbed from the active sites by the gas and
transferred by diffusion back into the gas stream (EPA, 1998).
Particulate matter can rapidly coat the catalyst so that the catalyst active sites are prevented from aiding in
the oxidation of pollutants in the gas stream. This effect of PM on the catalyst is called blinding, and will
deactivate the catalyst over time. Because essentially all the active surface of the catalyst is contained in
relatively small pores, the PM need not be large to blind the catalyst. No general guidelines exist as to the
PM concentration and size that can be tolerated by catalysts, because the pore size and volume of catalysts
vary widely. This information is likely to be available from the catalyst manufacturers (EPA, 1996a).
The method of contacting the VOC-containing stream with the catalyst serves to distinguish catalystic
incineration systems. Both fixed-bed and fluid-bed systems are used.
Fixed-bed catalytic incinerators may use a monolith catalyst or a packed-bed catalyst (EPA, 1996a):
Monolith Catalyst Incinerators - The most widespread method of contacting the VOC-containing stream
with the catalyst is the catalyst monolith. In this scheme the catalyst is a porous solid block containing
parallel, non-intersecting channels aligned in the direction of the gas flow. Monoliths offer the
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EPA-CICA Fact Sheet Catalytic Incinerator5
advantages of minimal attrition due to thermal expansion/contraction during startup/shutdown and low
overall pressure drop.
Packed-Bed Catalytic Incinerators - A second contacting scheme is a simple packed-bed in which
catalyst particles are supported either in a tube or in shallow trays through which the gases pass. This
scheme is not in widespread use due to its inherently high pressure drop, compared to a monolith, and
the breaking of catalyst particles due to thermal expansion when the confined catalyst bed is
heated/cooled during startup/shutdown. However, the tray type arrangement of a packed-bed scheme,
where the catalyst is pelletized, is used by several industries (e.g., heat-set web-offset printing).
Pelletized catalyst is advantageous where large amounts of such contaminants as phosphorous or silicon
compounds are present.
Fluid-bed catalytic incinerators have the advantage of very high mass transfer rates, although the overall
pressure drop is somewhat higher than for a monolith. An additional advantage of fluid-beds is a high bed-
side heat transfer as compared to a normal gas heat transfer coefficient. This higher heat transfer rate to heat
transfer tubes immersed in the bed allows higher heat release rates per unit volume of gas processed and,
therefore, may allow waste gas with higher heating values to be processed without exceeding maximum
permissible temperatures in the catalyst bed. In these reactors the gas phase temperature rise from gas inlet
to gas outlet is low, depending on the extent of heat transfer through imbedded heat transfer surfaces. The
catalyst temperatures depend on the rate of reaction occurring at the catalyst surface and the rate of heat
exchange between the catalyst and imbedded heat transfer surfaces.
As a general rule, fluid-bed systems are more tolerant of PM in the gas stream than either fixed-bed or
monolithic catalysts. This is due to the constant abrasion of the fluidized catalyst pellets, which helps remove
PM from the exterior of the catalysts in a continuous manner. A disadvantage of a fluid-bed is the gradual loss
of catalyst by attrition. However, attrition-resistant catalysts have been developed to overcome this
disadvantage.
Advantages:
Advantages of catalytic incinerators over other types of incinerators include (AWMA, 1992; Cooper and
Alley, 1994):
b.Lower fuel requirements;
c.Lower operating temperatures;
d.Little or no insulation requirements;
e.Reduced fire hazards;
f.Reduced flashback problems; and
g.Less volume/size required.
Disadvantages:
Disadvantages of catalytic incinerators include (AWMA, 1992):
a.High initial cost;
b.Catalyst poisoning is possible;
c.Particulate often must first be removed; and
d.Spent catalyst that cannot be regenerated may need to be disposed.
Other Considerations:
Catalytic incinerators offer many advantages for the appropriate application. However, selection of a
catalytic incinerator should be considered carefully, as the sensitivity of catalytic incinerators to VOC inlet
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EPA-CICA Fact Sheet Catalytic Incinerator6
stream flow conditions and catalyst deactivation limit their applicability for many industrial processes (EPA,
1992).
References:
AWMA, 1992. Air & W aste Management Association, Air Pollution Engineering Manual. Van Nostrand
Reinhold, New York.
Cooper & Alley, 1994. C. D. Cooper and F. C. Alley, Air Pollution Control: A Design Approach, Second
Edition, Waveland Press, Inc. IL.
EPA, 1991. U.S. EPA, Office of Research and Developm ent, “Control Technologies for Hazardous Air
Pollutants,” EPA/625/6-91/014, Washington, D.C., June.
EPA, 1992. U.S. EPA, Office of Air Quality Planning and Standards, “Control Techniques for Volatile
Organic Emissions from Stationary Sources,” EPA-453/R-92-018, Research Triangle Park, NC.,
December.
EPA, 1995. U.S. EPA, Office of Air Quality Planning and Standards, “Survey of Control Technologies for
Low Concentration Organic Vapor Gas Streams,” EPA-456/R-95-003, Research Triangle Park, NC., May.
EPA, 1996a. U.S. EPA, Office of Air Quality Planning and Standards, “OAQPS Control Cost Manual,”
Fifth Edition, EPA 453/B-96-001, Research Triangle Park, NC. February.
EPA, 1996b. U.S. EPA, “1990 National Inventory,” Research Triangle Park, NC, January.
EPA, 1998. U.S. EPA, Office of Air Quality Planning and Standards, “Stationary Source Control
Techniques Document for Fine Particulate Matter,” EPA-452/R-97-001, Research Triangle Park, NC.,
October.
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EPA-452/F-03-021
Air Pollution Control Technology
Fact Sheet
EPA-CICA Fact Sheet Incinerator - Recuperative Type
1
Name of Technology: Regenerative Incinerator
This type of incinerator is also referred to as a regenerative thermal oxidizer (RTO), or a regenerative catalytic
oxidizer (RCO) if a catalyst is used.
Type of Technology: Destruction by thermal or catalytic oxidation.
Applicable Pollutants: Volatile organic compounds (VOC). RCO units also control carbon monoxide
(CO).
Achievable Emission Limits/Reductions:
VOC destruction efficiency depends upon design criteria (i.e., chamber temperature, residence time, inlet
VOC concentration, compound type, and degree of mixing) (EPA, 1992). Typical regenerative incinerator
design efficiencies range from 95 to 99% for RTO systems and 90 to 99% for RCO systems, depending on
system requirements and characteristics of the contaminated stream (EPA, 1995; Power, 1996; AWMA, 1992;
EPA, 1991; Chen, 1996). Lower control efficiencies are generally associated with lower concentration flows
(EPA, 1995).
RCO systems using precious metal-based catalyst can destroy more than 98 percent of the CO in the
VOC-laden air stream (Gay, 1997). RTO systems do not reduce the levels of CO.
Applicable Source Type: Point
Typical Industrial Applications:
Regenerative incinerators can be used to reduce emissions from a variety of stationary sources. Generally,
high flow (greater than 2.4 standard cubic meters per second (sm3/sec) (5,000 standard cubic feet per minute
(scfm))), low VOC concentration (less than 1000 parts per million by volume (ppmv)) applications are best
suited to control with regenerative incineration systems (Gay, 1997). This type of incinerator is applicable in
controlling VOC from metalworking and coating operations, automotive manufacturing, and forest and wood
products manufacturing. Particulate matter (PM) and condensables which can clog the incinerator’s packed
bed or poison the catalyst (for RCOs) would have to be removed by an internal filter or
some pretreatment technology prior to entering the reactor chamber (Biedel and Nester, 1995).
The use of precious metal catalysts such as platinum and palladium have allowed VOC waste streams
containing chlorides, bromides, and other halogens to be controlled with RCO systems. However, the potential
for catalyst poisoning still exists if the VOC stream contains silicon, phosphorous, arsenic, or other heavy
metals (Gay, 1997).
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EPA-CICA Fact Sheet Incinerator - Recuperative Type
2
Emission Stream Characteristics:
a. Air Flow: Typical gas flow rates for regenerative incinerators are 2.4 to 240 sm3/sec (5,000 to
500,000 scfm) (Gay, 1997).
b. Temperature: An RTO uses natural gas to heat the entering waste gas to typically from 760(C
to 820(C (1400(F to 1500(F), however, it is capable of operating up to 1100 (C (2000(F) for those
cases where maximum destruction is necessary. An RCO uses a precious metal catalyst, which
allows oxidation to occur at approximately 400(C (800(F) (Gay, 1997).
c. Pollutant Loading: Regenerative incinerators can and have been used effectively at inlet loadings
as low as 100 ppmv or less (EPA, 1995). As with thermal and recuperative incinerators, for safety
considerations, the maximum concentration of the organics in the waste gas must be substantially
below the lower flammable level (lower explosive limit, or LEL) of the specific compound being
controlled. As a rule, a safety factor of four (i.e., 25% of the LEL) is used (EPA, 1991; AWMA, 1992).
The waste gas may be diluted with ambient air, if necessary, to lower the concentration.
d. Other Considerations: Characteristics of the inlet stream should be evaluated in detail, because
of the sensitivity of RCO systems to PM and VOC inlet stream flow conditions, which may cause
catalyst deactivation (EPA, 1992).
Emission Stream Pretreatment Requirements:
Typically, if design conditions are satisfied, no pretreatment is required, however, in some cases, PM removal
may be necessary before the waste gas enters the incinerator. This is more critical for RCOs than RTOs, as
RTOs tolerate PM more than RCOs. Catalysts may be “blinded” by PM. Blinding is coating of the catalyst so
that the catalyst active sites are prevented from aiding in the oxidation of pollutants in the gas stream. Catalytic
systems may incorporate internal filters that process the air stream before it reaches the catalyst. A sacrificial
bed also can be employed to prevent PM from reaching the catalyst. Some manufacturers fluidize the catalyst
beds to assist in passing the PM through the system (Biedell and Nester, 1995).
Cost Information:
The following are cost ranges (expressed in 2002 dollars) for regenerative incinerators of conventional design
both with and without a catalyst, under typical operating conditions, developed using EPA cost-estimating
spreadsheets (EPA, 1996) and referenced to the volumetric flow rate of the waste stream flow treated. RTOs
and RCOs are field-erected and not available as packaged units. The costs do not include costs for a
post-oxidation acid gas treatment system. The upper level costs in the ranges shown apply when the control
device is used for very low-VOC concentration streams (less than around 100 ppmv) at very low flow rates
(around 2.4 scm/s or 5,000 scfm). As a rule, smaller units controlling a low concentration waste stream will
be much more expensive (per unit volumetric flow rate) than a large unit cleaning a high pollutant load flow
(EPA, 1996).
a. Capital Cost:
RTO: $85,000 to $320,000 per sm3/sec ($35 to $140 per scfm)
RCO: $74,000 to $297,000 per sm3/sec ($35 to $140 per scfm)
b. O & M Cost:
RTO: $8,500 to $21,000 per sm3/sec ($4 to $10 per scfm), annually
RCO: $13,000 to $42,000 per sm3/sec ($6 to $20 per scfm), annually
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EPA-CICA Fact Sheet Incinerator - Recuperative Type
3
c. Annualized Cost:
RTO: $17,000 to $70,000 per sm3/sec ($8 to $33 per scfm), annually
RCO: $23,000 to $89,000 per sm3/sec ($11 to $42 per scfm), annually
d. Cost Effectiveness:
RTO: $115 to $21,000 per metric ton ($100 to $17,000 per short ton), annualized cost per ton of
pollutant controlled
RCO: $137 to $23,000 per metric ton ($124 to $21,000 per short ton), annualized cost per ton of
pollutant controlled
Theory of Operation:
RTOs use a high-density media such as a ceramic-packed bed still hot from a previous cycle to preheat an
incoming VOC-laden waste gas stream. The preheated, partially oxidized gases then enter a combustion
chamber where they are heated by auxiliary fuel (natural gas) combustion to a final oxidation temperature
typically between 760(C to 820(C (1400 to 1500(F) and maintained at this temperature to achieve maximum
VOC destruction, however, temperatures of up to 1100(C (2000(F) may be achieved, if required, for very high
control efficiencies of certain toxic VOC. The purified, hot gases exit this chamber and are directed to
one or more different ceramic-packed beds cooled by an earlier cycle. Heat from the purified gases is
absorbed by these beds before the gases are exhausted to the atmosphere. The reheated packed bed
then begins a new cycle by heating a new incoming waste gas stream.
An RCO operates in the same manner as an RTO, however, it uses a catalyst material rather than ceramic
material in the packed bed. This allows for destruction of VOC at a lower oxidation temperature. An RCO uses
a precious metal catalyst in the packed bed, allowing oxidation to occur at approximately 400(C (800(F). The
lower temperature requirement reduces the amount of natural gas needed to fuel the VOC abatement system
and the overall size of the incinerator. Catalysts typically used for VOC incineration include platinum and
palladium (Gay, 1997; Biedell and Nester, 1995).
Advantages:
Advantages of regenerative incinerators over other types of incinerators include the following (Gay, 1997;
Stone, 1997; Biedell and Nester, 1995; Yewshenko, 1995):
Advantages of RTOs:
a. Lower fuel requirements because of high energy recovery (85 to 95 percent);
b. High temperature capability (up to 1100(C (2000(F)) provides better destruction
efficiency over recuperative incinerators, which are generally limited to 820(C
(1500(F) due to heat exchanger limitations, and catalytic incinerators, which are
generally limited to 600(C (1100(F) due to catalyst limitations;
c. Less susceptible to problems with chlorinated compounds; and
d. Generally lower NOx emissions than thermal oxidation (except when operating
temperatures are above approximately 760 (C (1400(F)).
Advantages of RCOs:
a. Lower fuel requirements than RTOs because of lower temperature;
b. Catalyst also destroys CO in waste stream; and
c. Lower NOx emissions than RTOs.
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EPA-CICA Fact Sheet Incinerator - Recuperative Type
4
Disadvantages:
Disadvantages include the following (Gay, 1997; Stone, 1997):
Disadvantages of RTOs:
a. High initial cost;
b. Difficult and expensive installation;
c. Large size and weight; and
d. High maintenance demand for moving parts.
Disadvantages of RCOs
a. High initial cost;
b. Difficult and expensive installation;
c. Large size and weight;
d. High maintenance demand for moving parts and catalyst monitoring;
e. Catalyst poisoning is possible, however, precious metal catalysts are more resistant;
f. PM often must first be removed; and
g. Spent catalyst that cannot be regenerated may need to be disposed
Other Considerations:
Regenerative incinerators offer many advantages for the appropriate application. High flow, low concentration
waste streams which are consistent over long time periods can be treated economically with either RTO or
RCO systems, depending upon the waste stream composition. For either system, pretreatment to remove PM
may be necessary to prevent the packed bed from clogging and/or the catalyst from poisoning. In RCO units,
precious metal-based catalysts generally have a longer service life and are much more resistant to poisoning
and fouling than less expensive base metal catalysts (Gay, 1997).
References:
AWMA, 1992. Air & Waste Management Association, Air Pollution Engineering Manual, Van Nostrand
Reinhold, New York.
Biedell and Nester, 1995. E. Biedell and J. Nester, “VOCs Pose a Sticky Situation for Industry,” Pollution
Engineering, November.
Chen, 1996. J. Chen, “Lower Operating Temperatures Oxidize VOCs,” Pollution Engineering, December.
EPA, 1991. U.S. EPA, Office of Research and Development, “Control Technologies for Hazardous Air
Pollutants,” EPA/625/6-91/014, Washington, D.C., June.
EPA, 1992. U.S. EPA, Office of Air Quality Planning and Standards, “Control Techniques for Volatile
Organic Emissions from Stationary Sources,” EPA-453/R-92-018, Research Triangle Park, NC,
December.
EPA, 1995. U.S. EPA, Office of Air Quality Planning and Standards, “Survey of Control Technologies for
Low Concentration Organic Vapor Gas Streams,” EPA-456/R-95-003, Research Triangle Park, NC, May.
EPA, 1996. U.S. EPA, Office of Air Quality Planning and Standards, “OAQPS Control Cost Manual,” Fifth
Edition, EPA 453/B-96-001, Research Triangle Park, NC, February.
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EPA-CICA Fact Sheet Incinerator - Recuperative Type
5
Gay, 1997. R. Gay, “In Search of the Best Control for Volatile Organics,” Environmental Technology,
May/June.
Power, 1996. Power Online, “Combu-Changer Regenerative Thermal-oxidizer System Provides Phased
Low-solvent VOC Abatement,” Power Online Internet Web Page,
www.poweronline.com/case-studies/cs121296.html, December 12, 1996.
Stone, 1997. J. Stone, “Controlling VOC Emissions in Finishing Operations,” Products Finishing, July.
Yewshenko, 1995. P. Yewshenko, “Hot Stuff Controls for VOC Emissions,” Environmental Protection,
December.
Christensen Arms AO Modification 9/7/23
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX F
Manufacture Specifications
Cy
cl
o
n
e
D
u
s
t
C
o
l
l
e
c
t
o
r
s
C SERIES
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C SERIES
CYCLONE DUST
COLLECTORS
The Most
Effective Way To
Remove Large
Size Contaminants
from your factory.
HIGH-EFFICIENCY CYCLONE SEPARATOR
Industrial processes generate contaminants in a variety of sizes. Some
particles are visible to the human eye, while others are not. Large or
small, many of these pollutants are harmful to your employees and
need to be removed from the air to ensure a safe breathing environment.
That’s why United Air Specialists (UAS) created the C Series Cyclone
dust collector.
The C Series Cyclone is designed to effectively remove large to
moderate-size particles (chips, metal grindings, sawdust) from the air
stream. Used alone or in conjunction with another dust collector, the
Cyclone separates coarse contaminants from fine, non-visible particles,
and exhausts clean air.
UAS’ Cyclone dust collector offers airflow capacities ranging from
800 to 13,000 CFM. Its high-efficiency performance is accomplished
by means of the unit’s long tapered cone,
high-velocity inlet and welded helix. Dirty air
enters the unit at a high speed and is then
spun around in a spiral motion, throwing
particles against its cone wall. Centrifugal
force pushes the larger or heavy dust particles
down through the narrow part of the cone
and into a collection drum or hopper. Cleaned
air runs back up through the center of the unit
and is discharged back to the atmosphere or
into a UAS after-filter for further processing.
APPLICATIONS
• Buffing • Polishing
• Fiberglass/Plastic • Sawing
• Grinding • Woodworking
• Machining
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www.dust-hog.net
ENERGY EFFICIENT
C Series Cyclone fans are self-cleaning, material handling
radial blades designed to deliver peak airow with low
horsepower to conserve energy. All models can be
installed indoors or outdoors, and clean air can be
returned inside your factory if the Cyclone is equipped
with a UAS after-lter.
One 30- or 55-Gallon Drum
(30 gal. shown)
Two 30- or 55-Gallon Drum (55 gal. shown)60ft3 or 110ft 3 Hopper
(C110H shown)
DISCHARGE OPTIONS
CUSTOMIZED SYSTEM
The C Series Cyclone oers a variety of congurations
to help meet your company’s industrial air cleaning
needs. With the assistance of a UAS Representative, you
can actually “design” a Cyclone unit and after-lter to
match your specic application. Select the direction of
the inlet and discharge areas, exhaust clean air back into
your plant or outdoors, or choose to use the Cyclone
alone or with a UAS after-lter.
Dierent ind ustrial applications generate varying amounts
of dust and debris, so UAS oers a v ariety of discharge
options. For small quantities, you have the choice of
30- and 55-gallon drums that can be congu r ed under
the Cyclone unit as a single-or two-drum conguration .
For larger loads, you may opt to use the Model C60H
hopper, which has a storage capacity of 60 ft3 or Model
C110H, which can hold 110 ft 3. Additionally, you can
add rotary airlocks to your system to constantly
discharge dust from a throw-out bin into an external
dust storage container.
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FEATURES AND BENEFITS
Powder-Coated Finish
Components have electrostatically
applied paint that helps prevent fading
and chalking.
Come-Apart-
Construction
Allows for easy removal of
cone section without
replacing entire unit.
Internal Helix
Forces contaminants out of
the air and down into the
cone section.
Insert Section
Supports steep taper of
cone to maximize efficiency.
Complete Unitized
Assembly
Unit ships assembled for
immediate use.
True Storage Capacity
Discharge Drum
Cone sits flush with discharge area
to maximize storage capacity.
Blower Housing
Taperlock bushing allows for easy
replacement of fan wheel and motor.
Durable Motor
Able to withstand indoor and
outdoor temperatures.
Cone Section
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OPTIONS AND ACCESSORIES
UAS pr ovides a comprehensive selection of options and
accessories to enhance the performance of your
C Series Cyclone dust collector. Some of these include:
•Pressure Relief Panel —Minimizes damage and
provides a degree of personal protection in the
unlikely event of an explosion that may result when
collecting explosive dusts.
•Silencer Package —Duct-type and acoustical
foam-lined silencers reduce unit noise levels.
•Fully Welded Construction —Provides a complete,
airtight seal to meet unique specications.
• After-Filter Magnehelic ®Gage Kit —Monitors pressure
drop to indicate when lters need to be changed.
•Access doors
•Aluminum fan wheel
•Drum lid latch kit/slide gate
•Explosion-proof motor
•Explosion venting
•Increased hopper clearance
•Leg extensions
•Lined plenum
•208/3/60 motor option
•Scroll outlet
•Sprinkler heads
•Throw out bin
*Heights include motor/blower where applicable.
**C-44 Series unit heights include throw-out bins.
***Weight does not include drum or hopper options.
C SERIES CYCLONE CONFIGURATIONS
Overall Height (inches)*After-lter Options
Motor 1D 2D 60H 110H Weight
Model CFM (Hp)Cyclone (One Drum) (Two Drums)(60ft3 Hopper)(110ft3 Hopper)(lbs)Interior Exterior
‘C-190 800-1,200 – 49 1/8" 92 7/8" 114 3/4"193 1/2"209 1/2"235 ––
C-192 800-1,200 2 64 3/4" 108 1/4"130 3/8" 209 1/8" 225 1/8" 320 AF192 –
C-200 1,250-2,250 –62 3/16"108 3/16"121 3/16"204 15/16"220 15/16" 320 ––
C-203 1,250-2,000 3 79 3/16" 125 3/16"137 3/16"222"238 5/8"430
C-205 1,500-2,250 5 80 9/16"126 9/16"138 9/16" 223 3/8" 240" 450
C-240 2,000-3,500 – 73"119 1/8"131 1/8"210"226"435 ––
C-247 2,000-3,500
C9-E, C18-E C18-W
C-3000 3,000-5,500 –92 1/2"138 1/8"150 1/8" 228 13/16"245 3/32"621 ––
C-3010 3,000-4,500 10 113 15/16"159 9/16" 171 9/16" 250 7/16"266 1/2"870
C-3015 4,000-5,500 15 119 1/2"165 1/8" 177 1/8"256"272 1/16"883
C-3600 4,500-8,000 – 112 1/16"154 3/4" 161 3/4"241 3/8"257 9/16"995 ––
C-3620 4,500-7,000 20 151 3/16" 194" 201" 284 7/8"301 1/4" 1,763 AF12, C18-E C18-W
C-3625 4,500-7,500 25 152 3/16" 195" 202"286"302 1/4" 1,857
C-3630 5,000-8,00 30 154 3/16" 197" 204" 287 1/2”303 3/4” 1,934
C-4400 **8,000-13,000 – 155"202 3/16" 211 3/16" 260 7/16"276 5/8"1,147 ––
C-4440 **8,000-11,500 40 175 9/32" 249"257 13/16" 307"323 1/4" 1,594 AF18, Two
Two C18-Es C18-Ws
C-4450 **8,000-13,000 50 175 9/32"249"257 13/16" 307"323 1/4"1,745 AF24, Two
Two C27-Es C27-Ws
AF4, C9-E C9-W
AF8, C18-E C18-W
AF12, C27-E C27-W
7 1/2 95 3/8” 141 5/8”232 1/2”248 1/2”605153 5/8”AF4, AF8,C9-W,
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AF- VERSUS C-SERIES
For indoor Cyclone installations, UAS offers AF-Series
after-filters. These after-filters bolt directly to the
Cyclone blower outlet or are remotely mounted using
interconnecting ducting. AF-Series after-filters consist
of up to 24 10-oz. polyester felt zippered filter tubes.
Another option is the C-Series after-filter, which can be
installed inside or outside your facility. These units
remotely connect to the Cyclone with ducting and
empty into 55-gallon drums. Standard filter media
are 9-oz. polyester felt bags. Outdoor C-Series units
are designated with a “W” for weather enclosure,
and are constructed using epoxy-coated cold rolled
steel for the harshest environmental conditions.
A UAS Representative can help you determine which
after-filter is the best fit for your specific application.
CHOOSING AN AFTER-FILTER
Depending on your application, building specifications
and other factors, it may be necessary to use an
after-filter in conjunction with the C Series Cyclone.
In this case, the Cyclone dust collector captures the
heavier contaminants while the after-filter removes the
fine particles that may not be seen, but are harmful to
breathe. After-filters can be used indoors and outdoors,
and can be directly mounted to the C Series Cyclone
or remotely located using ducting.
W
AF4 Top
C9-E Front C18-W Front C27-W Front
C9-E Top C18-W Top C27-W Top
W W W
D D D
D
AF4 Front
70"
or
100"
24"
20 9/16"20 9/16"20 9/16"
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AF-SERIES AFTER-FILTERS
Model W D Height Filter No. of Unit RecommendedInterior Area Filters Weight Cyclone(ft2)(lbs)
AF192 30"8" 72"25 1 20 C-192
AF4 51"27" 89" 72-104 4 91-95 C-203, C-205, C-247
AF8 78"27" 119" 208 8 182 C-247, C-3010, C-3015
AF12 78"40" 119" 312 12 244 C-3620, C3625, C-3630
AF18 105" 40" 119" 468 18 366 C-4440
AF24 132" 40" 119" 624 24 488 C-4450
STORAGE HOPPERS
C-SERIES AFTER-FILTERS
170 1/4"
146 1/4"
67"
63 1/4"
73 1/2"
91 3/4"
154 1/4"
130 1/4"
67"
92 1/2"
24"24"
52"
68"
Model C60H Side Model C60H Fr ont Model C110H Side Model C110H Fr ont
E indicates indoor applications only.
W indicates weather enclosure suitable for outdoor installation.
Model W D Height Filter No. of Unit Recommended
Interior Area Filters Weight Cyclone
(ft2)(lbs)
C9-E/C9-W 34" 34" 156" 119 9 600/645 C-203, C-205, C-247
C18-E/C18-W 68"34" 156" 238 18 1,175/1,225 C-247, C-3010, C-3015
C-3620, C-4440
C27-E/C27-W 102" 34" 156" 357 27 1,750/1,805 C-3625, C-3630, C-4450
44"81"57"81"
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UAS, Inc. reserves the right to change design or without notice. IND-PSH-04-REV0208-PRO
WHY CHOOSE UNITED AIR SPECIALISTS?
A world-renowned reputation. For more than 40 years, we’ve been
the industry leader in air quality technology — a proven track record that
speaks for itself.
Commitment to quality products. Measuring our quality against
documented expectations, we practice continuous improvement methods
to anticipate challenges and implement successful solutions.
Unparalleled customer support. As a customer-driven solutions provider,
we earn credibility and establish successful relationships by exceeding
expectations for professional service and attitude.
Innovative technical leadership. Always, we keep technology at the
forefront — ensuring continuous product advancements through ongoing
investments in design and manufacturing.
Air Cleaning Specialists, Inc.
826 Horan Drive
Fenton, MO 63026
Ph: (866) 651-9762
E-mail: info@aircleaningspecialists.com
www.dust-hog.net
Christensen Arms AO Modification 9/7/23
AIR PERMIT MODIFICATION APPLICATION
rpsgroup.com Project Number: 117-RPS220197
APPENDIX G
Safety Data Sheets
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3M™ Super 77™ Multipurpose Adhesive 09/05/19
__________________________________________________________________________________________
Page 1 of 14
Safety Data Sheet
Copyright,2019,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:22-4025-7 Version Number:18.00
Issue Date:09/05/19 Supercedes Date:05/24/18
SECTION 1: Identification
1.1. Product identifier
3M™ Super 77™ Multipurpose Adhesive
Product Identification Numbers
LN-A100-0323-8, LN-A100-0323-9, LN-A100-0324-0, 44-0061-0114-9, 44-0061-0164-4, 62-4977-4030-8, 62-4977-4920-0,
62-4977-4926-7, 62-4977-4977-0, 70-0065-8412-5, 70-0065-9982-6, 70-0069-1448-8, 70-0069-1451-2, 70-0069-2063-4, 70-
0069-3662-2, 70-0069-3663-0, 70-0069-4021-0, 70-0069-4139-0, 70-0069-4245-5, 70-0069-4840-3, 70-0069-5039-1, 70-
0069-6344-4, 70-0069-6870-8, 70-0069-6871-6, 70-0069-7043-1, 70-0069-7049-8, 70-0069-7050-6, 70-0069-7053-0, 70-
0069-7255-1, 70-0069-7269-2, 70-0069-7276-7, 70-0069-7277-5, 70-0069-9030-6, 70-0069-9031-4, 70-0069-9972-9, 70-
0714-1653-4, 70-0714-1654-2, 70-0714-1656-7, 70-0714-7444-2, 70-0714-7572-0, 70-0714-7640-5, 70-0714-7930-0, 70-
0714-8259-3, 70-0714-8947-3
7000144616, 7010377290, 7010312936, 7100076970, 7100127332, 7100132610, 7100126874, 7100127350, 7100135536,
7100130406, 7100144892, 7100144897, 7100159784, 7100159783, 7100173162
1.2. Recommended use and restrictions on use
Recommended use
Adhesive aerosol, General Purpose Aerosol Adhesive
1.3. Supplier’s details
MANUFACTURER:3M
DIVISION:Construction and Home Improvement Markets
ADDRESS:3M Center, St. Paul, MN 55144-1000, USA
Telephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Flammable Aerosol: Category 1.
Gas Under Pressure: Liquefied gas.
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Serious Eye Damage/Irritation: Category 2A.
Reproductive Toxicity: Category 2.
Simple Asphyxiant.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
2.2. Label elements
Signal word
Danger
Symbols
Flame | Gas cylinder | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Suspected of damaging fertility or the unborn child.
May displace oxygen and cause rapid suffocation.
Causes damage to organs:
cardiovascular system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see Notes to Physician on this label).
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Storage:
Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
2.3. Hazards not otherwise classified
Repeated exposure may cause skin dryness or cracking. Repeated exposure may cause skin dryness or cracking.
Supplemental Information:
Intentional concentration and inhalation may be harmful or fatal.
20% of the mixture consists of ingredients of unknown acute oral toxicity.
20% of the mixture consists of ingredients of unknown acute dermal toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No.% by Wt
Acetone 67-64-1 20 - 30 Trade Secret *
Non-volatile components (N.J.T.S. Registry No.
04499600-6433P)
Trade Secret* 20 - 30 Trade Secret *
Propane 74-98-6 15 - 25 Trade Secret *
Cyclohexane 110-82-7 10 - 20 Trade Secret *
Petroleum Distillates 64742-49-0 10 - 20 Trade Secret *
Hexane 110-54-3 < 0.5 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. Get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
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4.3. Indication of any immediate medical attention and special treatment required
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or
if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is
available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam
(AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding
an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material
as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities.
Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh
air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as
soon as possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety
precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
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product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use
personal protective equipment (gloves, respirators, etc.) as required.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures
exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No.Agency Limit type Additional Comments
Hexane 110-54-3 ACGIH TWA:50 ppm SKIN
Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm)
Cyclohexane 110-82-7 ACGIH TWA:100 ppm
Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm)
Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human
carcin
Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm)
Propane 74-98-6 ACGIH Limit value not established:simple asphyxiant
Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm)
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Nitrile Rubber
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Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece supplied-air respirator
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
Colorless
Specific Physical Form: Aerosol
Odor Fruity Odor
Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point Not Applicable
Flash Point -42.00 ºF [Test Method:Tagliabue Closed Cup]
Evaporation rate 1.9 [Ref Std:ETHER=1]
Flammability (solid, gas)Not Applicable
Flammable Limits(LEL)No Data Available
Flammable Limits(UEL)No Data Available
Vapor Pressure No Data Available
Vapor Density 2.97 [Ref Std:AIR=1]
Density 0.726 g/ml
Specific Gravity 0.726 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity Not Applicable
Hazardous Air Pollutants 0.4 % weight [Test Method:Calculated]
Hazardous Air Pollutants 0.016 lb HAPS/lb solids [Test Method:Calculated]
Hazardous Air Pollutants 0.02 lb HAPS/gal [Test Method:Calculated]
Molecular weight No Data Available
Volatile Organic Compounds Approximately 51 % [Test Method:calculated SCAQMD rule
443.1]
Percent volatile <=75 % weight
VOC Less H2O & Exempt Solvents <=458 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
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10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Dermal Defatting: Signs/symptoms may include localized redness, itching, drying and cracking of skin.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
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nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be
fatal.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Propane Inhalation-
Gas (4
hours)
Rat LC50 > 200,000 ppm
Acetone Dermal Rabbit LD50 > 15,688 mg/kg
Acetone Inhalation-
Vapor (4
hours)
Rat LC50 76 mg/l
Acetone Ingestion Rat LD50 5,800 mg/kg
Cyclohexane Dermal Rat LD50 > 2,000 mg/kg
Cyclohexane Inhalation-
Vapor (4
hours)
Rat LC50 > 32.9 mg/l
Cyclohexane Ingestion Rat LD50 6,200 mg/kg
Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg
Petroleum Distillates Inhalation-
Vapor (4
hours)
Rat LC50 > 14.7 mg/l
Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg
Non-volatile components (N.J.T.S. Registry No. 04499600-
6433P)
Dermal LD50 estimated to be > 5,000 mg/kg
Non-volatile components (N.J.T.S. Registry No. 04499600-
6433P)
Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Hexane Dermal Rabbit LD50 > 2,000 mg/kg
Hexane Inhalation-
Vapor (4
hours)
Rat LC50 170 mg/l
Hexane Ingestion Rat LD50 > 28,700 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propane Rabbit Minimal irritation
Acetone Mouse Minimal irritation
Cyclohexane Rabbit Mild irritant
Petroleum Distillates Rabbit Irritant
Non-volatile components (N.J.T.S. Registry No. 04499600-6433P)Professio
nal
judgeme
nt
Minimal irritation
Hexane Human
and
animal
Mild irritant
Serious Eye Damage/Irritation
Name Species Value
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Propane Rabbit Mild irritant
Acetone Rabbit Severe irritant
Cyclohexane Rabbit Mild irritant
Petroleum Distillates Rabbit Mild irritant
Hexane Rabbit Mild irritant
Skin Sensitization
Name Species Value
Petroleum Distillates Guinea
pig
Not classified
Hexane Human Not classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Propane In Vitro Not mutagenic
Acetone In vivo Not mutagenic
Acetone In Vitro Some positive data exist, but the data are not
sufficient for classification
Cyclohexane In Vitro Not mutagenic
Cyclohexane In vivo Some positive data exist, but the data are not
sufficient for classification
Petroleum Distillates In Vitro Not mutagenic
Hexane In Vitro Not mutagenic
Hexane In vivo Not mutagenic
Carcinogenicity
Name Route Species Value
Acetone Not
Specified
Multiple
animal
species
Not carcinogenic
Petroleum Distillates Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
Hexane Dermal Mouse Not carcinogenic
Hexane Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700
mg/kg/day
13 weeks
Acetone Inhalation Not classified for development Rat NOAEL 5.2
mg/l
during
organogenesi
s
Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24
mg/l
2 generation
Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24
mg/l
2 generation
Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9
mg/l
2 generation
Hexane Ingestion Not classified for development Mouse NOAEL 2,200
mg/kg/day
during
organogenesi
s
Hexane Inhalation Not classified for development Rat NOAEL 0.7
mg/l
during
gestation
Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 90 days
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mg/kg/day
Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52
mg/l
28 days
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not
available
Propane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Propane Inhalation respiratory irritation Not classified Human NOAEL Not
available
Acetone Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Acetone Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Acetone Inhalation immune system Not classified Human NOAEL 1.19
mg/l
6 hours
Acetone Inhalation liver Not classified Guinea
pig
NOAEL Not
available
Acetone Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
Cyclohexane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Cyclohexane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human
and
animal
NOAEL Not
available
Cyclohexane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
Petroleum Distillates Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not
available
Petroleum Distillates Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
Hexane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
not available
Hexane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Rabbit NOAEL Not
available
8 hours
Hexane Inhalation respiratory system Not classified Rat NOAEL 24.6
mg/l
8 hours
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Acetone Dermal eyes Not classified Guinea
pig
NOAEL Not
available
3 weeks
Acetone Inhalation hematopoietic
system
Not classified Human NOAEL 3
mg/l
6 weeks
Acetone Inhalation immune system Not classified Human NOAEL 1.19
mg/l
6 days
Acetone Inhalation kidney and/or
bladder
Not classified Guinea
pig
NOAEL 119
mg/l
not available
Acetone Inhalation heart | liver Not classified Rat NOAEL 45 8 weeks
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mg/l
Acetone Ingestion kidney and/or
bladder
Not classified Rat NOAEL 900
mg/kg/day
13 weeks
Acetone Ingestion heart Not classified Rat NOAEL
2,500
mg/kg/day
13 weeks
Acetone Ingestion hematopoietic
system
Not classified Rat NOAEL 200
mg/kg/day
13 weeks
Acetone Ingestion liver Not classified Mouse NOAEL
3,896
mg/kg/day
14 days
Acetone Ingestion eyes Not classified Rat NOAEL
3,400
mg/kg/day
13 weeks
Acetone Ingestion respiratory system Not classified Rat NOAEL
2,500
mg/kg/day
13 weeks
Acetone Ingestion muscles Not classified Rat NOAEL
2,500 mg/kg
13 weeks
Acetone Ingestion skin | bone, teeth,
nails, and/or hair
Not classified Mouse NOAEL
11,298
mg/kg/day
13 weeks
Cyclohexane Inhalation liver Not classified Rat NOAEL 24
mg/l
90 days
Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7
mg/l
90 days
Cyclohexane Inhalation kidney and/or
bladder
Not classified Rabbit NOAEL 2.7
mg/l
10 weeks
Cyclohexane Inhalation hematopoietic
system
Not classified Mouse NOAEL 24
mg/l
14 weeks
Cyclohexane Inhalation peripheral nervous
system
Not classified Rat NOAEL 8.6
mg/l
30 weeks
Hexane Inhalation peripheral nervous
system
Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational
exposure
Hexane Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Mouse LOAEL 1.76
mg/l
13 weeks
Hexane Inhalation liver Not classified Rat NOAEL Not
available
6 months
Hexane Inhalation kidney and/or
bladder
Not classified Rat LOAEL 1.76
mg/l
6 months
Hexane Inhalation hematopoietic
system
Not classified Mouse NOAEL 35.2
mg/l
13 weeks
Hexane Inhalation auditory system |
immune system |
eyes
Not classified Human NOAEL Not
available
occupational
exposure
Hexane Inhalation heart | skin |
endocrine system
Not classified Rat NOAEL 1.76
mg/l
6 months
Hexane Ingestion peripheral nervous
system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
1,140
mg/kg/day
90 days
Hexane Ingestion endocrine system |
hematopoietic
system | liver |
immune system |
kidney and/or
bladder
Not classified Rat NOAEL Not
available
13 weeks
Aspiration Hazard
Name Value
Cyclohexane Aspiration hazard
Petroleum Distillates Aspiration hazard
Hexane Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
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SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. Dispose of completely cured (or polymerized) material
in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration
facility. Facility must be capable of handling aerosol cans. If no other disposal options are available, waste product that has
been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical Hazards
Flammable (gases, aerosols, liquids, or solids)
Gas under pressure
Health Hazards
Reproductive toxicity
Serious eye damage or eye irritation
Simple Asphyxiant
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
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Ingredient C.A.S. No % by Wt
Cyclohexane 110-82-7 Trade Secret 10 - 20
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information.
15.4. International Regulations
This material contains one or more ingredients that may be regulated by the International Traffic in Arms Regulation
(ITAR), an export control of US military technology and chemicals. Prior to export of this material or any product containing
this material, determine whether a proper license from the Department of State must be obtained. See 22CFR 120-130 for any
specific requirements.
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 4 Instability: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: *4 Flammability: 4 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:22-4025-7 Version Number:18.00
Issue Date:09/05/19 Supercedes Date:05/24/18
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
Christensen Arms AO Modification 9/7/23
3M™ Super 77™ Multipurpose Adhesive 09/05/19
__________________________________________________________________________________________
Page 14 of 14
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M
3M USA SDSs are available at www.3M.com
Christensen Arms AO Modification 9/7/23
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API-334-3 Part A, Epoxy Resin
Safety Data Sheet
Product Identifier API-334-3 Part A, Epoxy Resin
Other Means ofIdentification API-334-3 A
Applied Poleramic, Inc., 6166 Egret Court, Benicia, CA, 94598, service@poleramic.com,707-747-6738, poleramic.com
Recommended Use
SDS No.
Product Family Epoxy Resin
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer /Supplier
Industrial Use Only.
0041
Chemtrec International, 703-527-3887, 24 hour
Chemtrec US, 800-424-9300, 24 hours
Restrictions on Use None known.
Date of Preparation June 24, 2015
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:WarningHazard Statement(s):H315 Causes skin irritation.H317 May cause an allergic skin reaction.H411 Toxic to aquatic life with long lasting effects.Precautionary Statement(s): Prevention:P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P280 Wear protective gloves.P264 Wash hands thoroughly after handling.P273 Avoid release to the environment. Response:P302 + P352 IF ON SKIN: Wash with plenty of water.P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. Disposal:P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
GHS Classification
Other Hazards
None known.
Skin corrosion/irritation - Category 2; Skin sensitization - Category 1; Aquatic hazard (Chronic) - Category 4
SDS No.:
Date of Preparation:
0041 Page of 0501
June 24, 2015
Product Identifier: API-334-3 Part A, Epoxy Resin
Christensen Arms AO Modification 9/7/23
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No.Other Identifiers%
Mixture:
Cyclohexanol, 4,4'-(1-methylethylidene)bis-,polymer with (chloromethyl)oxirane 30583-72-3 90-100
Inhalation
Remove source of exposure or move to fresh air.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. If skin irritation or arash occurs, get medical advice/attention.
Eye Contact
Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.If eye irritation persists, get medical advice/attention.
Ingestion
Do not induce vomiting; immediately call for medical help.
First-aid Comments
Some of the first-aid procedures recommended here require advanced first-aid training.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Most Important Symptoms and Effects, Acute and Delayed
None known.
Extinguishing Media
Suitable Extinguishing Media
CO2, extinguishing powder or water spray. Fight larger fires with water spray. Use fire fighting measures that suitthe environment.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Heating increases the release of toxic vapour.
Special Protective Equipment and Precautions for Fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA).A full-body encapsulating chemical protective suit with positive pressure SCBA may be necessary.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use thepersonal protective equipment recommended in Section 8 of this safety data sheet.
Environmental Precautions
If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas.
Methods and Materials for Containment and Cleaning Up
Contain and soak up spill with absorbent that does not react with spilled product. Dike spilled product to prevent runoff.
Other Information
Report spills to local health, safety and environmental authorities, as required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SDS No.:
Date of Preparation:
0041 Page of 0502
June 24, 2015
Product Identifier: API-334-3 Part A, Epoxy Resin
Christensen Arms AO Modification 9/7/23
Report spills to local health, safety and environmental authorities, as required.
Precautions for Safe Handling
Only use where there is adequate ventilation. Wear personal protective equipment to avoid direct contact with thischemical. Keep containers tightly closed when not in use or empty.
Conditions for Safe Storage
Store in an area that is: well-ventilated. Empty containers may contain hazardous residue. Store separately. Keepclosed. Follow all precautions given on this safety data sheet.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
SEN = Sensitization (skin and/or respiratory).
Wear a NIOSH approved air-purifying respirator with an organic vapour cartridge.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Wear chemical safety goggles.
Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air.
Appearance Clear colourless - yellow liquid.
Odour Faint
Flash Point > 115 ºC (239 ºF)
Relative Density (water = 1)~ 1.14
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
LiquidPhysical State
Other Information
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
Polymerizes on contact with: amines (e.g. triethylamine), strong acids (e.g. hydrochloric acid), strong bases (e.g.sodium hydroxide), strong oxidizing agents (e.g. perchloric acid).
Not corrosive to metals.
Hazardous Decomposition Products
Carbon monoxide and carbon dioxide.
Possibility of Hazardous Reactions
Reacts with acids, alkalis and oxidizing agents reacts with amines.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
SDS No.:
Date of Preparation:
0041 Page of 0503
June 24, 2015
Product Identifier: API-334-3 Part A, Epoxy Resin
Christensen Arms AO Modification 9/7/23
Skin Corrosion/Irritation
Human experience and animal tests show mild irritation.
Serious Eye Damage/Irritation
There is limited evidence of mild irritation.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Reactive airways dysfunction syndrome (RADS).
Skin Absorption
Symptoms may include redness, rash, swelling and itching.
Ingestion
Irritation of the mouth, throat and stomach.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
Respiratory sensitizer. Skin sensitizer. In sensitized people, exposure to a very small amount of product can causesymptoms including wheezing, difficult breathing, sneezing and runny or blocked nose. Can cause death. Symptomscan develop immediately following exposure or hours later. Repeated exposure will make the reaction worse.
Carcinogenicity
Not known to cause cancer.
Development of Offspring
Not known to harm the unborn child.
Reproductive Toxicity
Not known to cause effects on sexual function or fertility.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Acute Toxicity
Sexual Function and Fertility
Effects on or via Lactation
Not known to cause effects on or via lactation.
Symptoms may include coughing, choking, shortness of breath, difficult or rapid breathing, and wheezing.
Aspiration Hazard
Skin absorption; eye contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral)LD50 (dermal)
Cyclohexanol, 4,4'-(1-methylethylidene)bis-,polymer with(chloromethyl)oxirane
10000-11400 mg/kg (rat)
SECTION 12. ECOLOGICAL INFORMATION
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Not readilybiodegradable. This product shows a low bioaccumulation potential.
Toxicity
SDS No.:
Date of Preparation:
0041 Page of 0504
June 24, 2015
Product Identifier: API-334-3 Part A, Epoxy Resin
Christensen Arms AO Modification 9/7/23
No information was located.
There is no information available.
No ingredient of this product or its degradation products is known to be highly persistent.
Toxicity
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea ErC50 AquaticPlants ErC50 Algae
Cyclohexanol, 4,4'-(1-methylethylidene)bis
-, polymer with(chloromethyl)oxirane
1-10 mg/L
SECTION 13. DISPOSAL CONSIDERATIONS
Bury in a licensed landfill or burn in an approved incinerator according to federal, provincial/state, and local regulations.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautionsfor User Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Safety, Health and Environmental Regulations
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By Doyle Dixon
Phone No.707-747-6738
Date of Preparation June 24, 2015
Health - 2 Flammability - 1 Instability - 0
SDS No.:
Date of Preparation:
0041 Page of 0505
June 24, 2015
Product Identifier: API-334-3 Part A, Epoxy Resin
Christensen Arms AO Modification 9/7/23
API-334-3 Part B, Epoxy Hardener
Safety Data Sheet
Product Identifier API-334-3 Part B, Epoxy Hardener
Other Means ofIdentification API-334-3 B
Applied Poleramic, Inc., 6166 Egret Court, Benicia, CA, 94598, service@poleramic.com,707-747-6738, poleramic.com
Recommended Use
SDS No.
Product Family Amine Hardener
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer /Supplier
Industrial Use Only.
0046
Chemtrec International, 703-527-3887, 24 hour
Chemtrec US, 800-424-9300, 24 hours
Restrictions on Use None known.
Date of Preparation June 24, 2015
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
DangerHazard Statement(s):H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.H332 Harmful if inhaled.H412 Harmful to aquatic life with long lasting effects.Precautionary Statement(s): Prevention:P264 Wash hands and skin thoroughly after handling.P280 Wear protective gloves/protective clothing/eye protection/face protection. Response:P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P363 Wash contaminated clothing before reuse. Disposal:P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
GHS Classification
Acute toxicity (Oral) - Category 4; Skin corrosion/irritation - Category 1B; Serious eye damage/eye irritation - Category2A; Skin sensitization - Category 1B; Aquatic hazard (Chronic) - Category 3
SDS No.:
Date of Preparation:
0046 Page of 0601
June 24, 2015
Product Identifier: API-334-3 Part B, Epoxy Hardener
Christensen Arms AO Modification 9/7/23
P363 Wash contaminated clothing before reuse. Disposal:P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
Warning. May be a health hazard in confined spaces.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No.Other Identifiers%
Mixture:
Isophorone diamine 2855-13-2 90-100
Inhalation
Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment).Remove source of exposure or move to fresh air. If experiencing respiratory symptoms (e.g. coughing, shortness ofbreath, wheezing), call a Poison Centre or doctor. Immediately call a Poison Centre or doctor.
Skin Contact
Avoid direct contact. Wear chemical protective clothing if necessary. Take off contaminated clothing, shoes andleather goods (e.g. watchbands, belts). Immediately rinse with lukewarm, gently flowing water for 15-20 minutes. Ifskin irritation occurs get medical advice/attention.
Eye Contact
Avoid direct contact. Wear chemical protective gloves if necessary. Immediately rinse the contaminated eye(s) withlukewarm, gently flowing water for 15-20 minutes, while holding the eyelid(s) open. If eye irritation persists, getmedical advice/attention.
Ingestion
Rinse mouth with water. Never give anything by mouth if victim is rapidly losing consciousness, or is unconsciousor convulsing. Do not induce vomiting. Get medical advice/attention if you feel unwell or are concerned.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Target Organs
Lungs, respiratory system, skin.
Most Important Symptoms and Effects, Acute and Delayed
If on skin: may cause moderate to severe irritation. If in eyes: may cause moderate to severe irritation. May be harmful
if swallowed may cause sensitization by skin contact.
Extinguishing Media
Suitable Extinguishing Media
Use water to keep non-leaking, fire-exposed containers cool.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0046 Page of 0602
June 24, 2015
Product Identifier: API-334-3 Part B, Epoxy Hardener
Christensen Arms AO Modification 9/7/23
Specific Hazards Arising from the Chemical
Heating increases the release of toxic vapour.In a fire, the following hazardous materials may be generated: very toxic carbon monoxide, carbon dioxide; corrosive,oxidizing nitrogen oxides.
Special Protective Equipment and Precautions for Fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA).Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Do nottouch damaged containers or spilled product unless wearing appropriate protective equipment. Increase ventilation toarea or move leaking container to a well-ventilated and secure area.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway. If the spill is inside a building, prevent product from
entering drains, ventilation systems and confined areas.
Methods and Materials for Containment and Cleaning Up
Small spills or leaks: stop or reduce leak if safe to do so. Contain and soak up spill with absorbent that does not reactwith spilled product. Place used absorbent into suitable, covered, labelled containers for disposal. Large spills or leaks:dike spilled product to prevent runoff. Collect using shovel/scoop or approved HEPA vacuum and place in a suitablecontainer for disposal.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Do not breathe in this product. Prevent all skin contact. Do not get in eyes. Only use where there is adequateventilation. Immediately report leaks, spills or failures of the safety equipment (e.g. ventilation system). If product istransferred to another container, ensure new container is suitable for the product. Wear personal protective equipmentto avoid direct contact with this chemical. Do NOT eat, drink or store food in work areas. Remove contaminated clothingand protective equipment before entering eating areas or leaving work area. Wash hands thoroughly after handling thismaterial.
Conditions for Safe Storage
Store in an area that is: ventilated. Store in corrosive resistant container with a resistant inner liner. Empty containersmay contain hazardous residue. Store separately. Keep closed. Follow all precautions given on this safety data sheet.Comply with all applicable health and safety regulations, fire and building codes.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Wear a NIOSH approved air-purifying respirator with an organic vapour cartridge.
Wear chemical protective clothing e.g. gloves, aprons, boots.Butyl rubber, neoprene rubber, nitrile rubber.
Wear chemical safety goggles.
In a confined space: general ventilation is usually adequate. For large scale use of this product: do not allow product toaccumulate in the air in work or storage areas, or in confined spaces. Provide eyewash and safety shower if contact orsplash hazard exists.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0046 Page of 0603
June 24, 2015
Product Identifier: API-334-3 Part B, Epoxy Hardener
Christensen Arms AO Modification 9/7/23
pH > 12
Appearance Colourless liquid.
Odour Ammonia-like
Flash Point 117 ºC (243 ºF)
Relative Density (water = 1)0.92 (estimated)
Solubility Soluble (more than 10-50%) in water
Basic Physical and Chemical Properties
LiquidPhysical State
Other Information
Chemical Stability
Normally stable.
Conditions to Avoid
Open flames, sparks, static discharge, heat and other ignition sources.
Incompatible Materials
Strong acids (e.g. hydrochloric acid), strong oxidizing agents (e.g. perchloric acid).
Hazardous Decomposition Products
Ammonia.
Possibility of Hazardous Reactions
None expected under normal conditions of storage and use.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
Skin Corrosion/Irritation
Animal tests show moderate or severe irritation.
Serious Eye Damage/Irritation
Causes serious eye irritation based on skin irritation information.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Symptoms may include coughing, shortness of breath, difficult breathing and tightness in the chest.
Skin Absorption
Corrosive to skin. Causes burns. May cause sensitization by skin contact.
Ingestion
Harmful if swallowed. May cause burns to mouth throat and stomach.
Acute Toxicity
Severely irritating to the respiratory system harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs andcause damage. May cause burns to mouth, throat and stomach. Corrosive to the skin. Causes burns. Corrosive to theeyes. Causes burns.
Can cause lung damage if aspirated based on human experience.
Aspiration Hazard
Inhalation; skin contact; eye contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral)LD50 (dermal)
Isophorone diamine 1030 mg/kg (rat)
SDS No.:
Date of Preparation:
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June 24, 2015
Product Identifier: API-334-3 Part B, Epoxy Hardener
Christensen Arms AO Modification 9/7/23
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
In sensitized people, exposure to a very small amount of product can cause symptoms including wheezing, difficultbreathing, sneezing and runny or blocked nose. Can cause death. Symptoms can develop immediately following
exposure or hours later. Repeated exposure will make the reaction worse.
Carcinogenicity
Not known to cause cancer.
Development of Offspring
Not known to harm the unborn child.
Reproductive Toxicity
Not known to cause effects on sexual function or fertility.
Germ Cell Mutagenicity
Not known to be a mutagen.
Interactive Effects
No information was located.
Key to Abbreviations
A5 = Not suspected as a human carcinogen.
Sexual Function and Fertility
Effects on or via Lactation
Not known to cause effects on or via lactation.
Can cause lung damage if aspirated based on human experience.
This product and its degradation products not expected to bioaccumulate based on the n-octanol/water partitioncoefficient (Log Kow).
SECTION 12. ECOLOGICAL INFORMATION
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Not readilybiodegradable. This product shows a low bioaccumulation potential.
Does not degrade rapidly based on quantitative tests.
Toxicity
Persistence and Degradability
Bioaccumulative Potential
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea ErC50 AquaticPlants ErC50 Algae
Isophorone diamine 110 mg/L (96-hour;semi-static) 23 mg/L (Daphniamagna (water flea);48-hour; static)
37 mg/L (72-hour;static)
SECTION 13. DISPOSAL CONSIDERATIONS
This product and its container must be disposed of as hazardous waste. Do NOT dump into any sewers, on the groundor into any body of water. Dispose of or recycle empty containers through an approved waste management facility.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No.Proper Shipping Name Packing
Group
Transport
Hazard Class(es)Regulation
SDS No.:
Date of Preparation:
0046 Page of 0605
June 24, 2015
Product Identifier: API-334-3 Part B, Epoxy Hardener
Christensen Arms AO Modification 9/7/23
UN 1760 Corrosive Liquid, N.O.S. (Alkyl Polyamine)8 IIIUS DOT
UN 1760 Corrosive Liquid, N.O.S (Alkyl Polyamine)8 IIICanadian TDG
UN 1760 Corrosive Liquid, N.O.S (Alkyl Polyamine)8 IIIIMO (Marine)
Special Precautions
for User Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class EClass D2A; D2B
D2A - Very Toxic (Chronic toxicity); D2B - Toxic (Skin irritant; Eye irritant; Skin sensitization); E - Corrosive
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By Doyle Dixon
Phone No.707-747-6738
Date of Preparation June 24, 2015
Health - 3 Flammability - 1 Instability - 0
SDS No.:
Date of Preparation:
0046 Page of 0606
June 24, 2015
Product Identifier: API-334-3 Part B, Epoxy Hardener
Christensen Arms AO Modification 9/7/23
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
SAFETY DATA SHEET
Lubricating Oil
According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200
1. Identification
Product identifier
Product name Lubricating Oil
Chemical name Process Oil
Product number 1003, 1003B, 1003RB, 1003CN
Internal identification 1000-202
CAS number 64742-54-7
Recommended use of the chemical and restrictions on use
Application Firearm Lubrication
Uses advised against No specific uses advised against are identified.
Details of the supplier of the safety data sheet
Manufacturer Bushnell Holdings Inc
9200 Cody
Overland Park, KS 66214
1-800-423-3537
dangerous.goods@vistaoutdoor.com
Emergency telephone number
Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation
Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) -
(CHEMTREC, Day and Night)
2. Hazard(s) identification
Classification of the substance or mixture
Physical hazards Not Classified
Health hazards Not Classified
Environmental hazards Not Classified
Label elements
Hazard statements NC Not Classified
Other hazards
This substance is not classified as PBT or vPvB according to current EU criteria.
3. Composition/information on ingredients
Substances
Product name Lubricating Oil
Chemical name Process Oil
CAS number 64742-54-7
4. First-aid measures
Description of first aid measures
1/8Christensen Arms AO Modification 9/7/23
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medical
personnel.
Inhalation No specific recommendations. If throat irritation or coughing persists, proceed as follows.
Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if any
discomfort continues.
Ingestion No specific recommendations. If throat irritation or coughing persists, proceed as follows.
Rinse mouth. Get medical attention if any discomfort continues.
Skin Contact No specific recommendations. Rinse with water. Get medical attention if any discomfort
continues.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical
attention if any discomfort continues.
Protection of first aiders Use protective equipment appropriate for surrounding materials.
Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.
Ingestion No specific symptoms known. May cause discomfort if swallowed.
Skin contact No specific symptoms known. May cause discomfort.
Eye contact No specific symptoms known. May be slightly irritating to eyes.
Indication of immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
Specific treatments No special treatment required.
5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry
powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Special hazards arising from the substance or mixture
Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Hazardous combustion
products
Thermal decomposition or combustion products may include the following substances:
Harmful gases or vapors.
Advice for firefighters
Protective actions during
firefighting
Avoid breathing fire gases or vapors. Evacuate area. Cool containers exposed to heat with
water spray and remove them from the fire area if it can be done without risk. Cool containers
exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use
water spray to disperse vapors and protect men stopping the leak.
Special protective equipment
for firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will
provide a basic level of protection for chemical incidents.
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Lubricating Oil
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions No specific recommendations. For personal protection, see Section 8.
Environmental precautions
Environmental precautions Avoid discharge into drains or watercourses or onto the ground.
Methods and material for containment and cleaning up
Methods for cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage.
Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.
Dispose of contents/container in accordance with national regulations.
Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
7. Handling and storage
Precautions for safe handling
Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimize spills. Keep container tightly sealed
when not in use. Avoid the formation of mists.
Advice on general
occupational hygiene
Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash
before reuse. Wash contaminated clothing before reuse.
Conditions for safe storage, including any incompatibilities
Storage precautions Store away from incompatible materials (see Section 10). No specific recommendations.
Storage class Unspecified storage.
Specific end uses(s)
Specific end use(s)The identified uses for this product are detailed in Section 1.
8. Exposure Controls/personal protection
Control parameters
Occupational exposure limits
Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 5 mg/m³
Short-term exposure limit (15-minute): ACGIH 10 mg/m³
OSHA = Occupational Safety and Health Administration.
ACGIH = American Conference of Governmental Industrial Hygienists.
Exposure controls
Protective equipment
Appropriate engineering
controls
No specific ventilation requirements.
Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying
with an approved standard should be worn if a risk assessment indicates eye contact is
possible.
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Lubricating Oil
Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves.
Other skin and body
protection
Wear appropriate clothing to prevent repeated or prolonged skin contact.
Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke
when using this product.
Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is
inadequate, suitable respiratory protection must be worn.
Environmental exposure
controls
Not regarded as dangerous for the environment.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Appearance Clear liquid.
Color Water-white.
Odor Odorless.
pH Not applicable.
Melting point Not determined.
Initial boiling point and range 315°C/599°F
Flash point 192°C/378°F
Evaporation rate No information available.
Flammability (solid, gas)Class IIIB Liquid
Upper/lower flammability or
explosive limits
Not available.
Vapor pressure < 0.01 mm Hg @ 25°C
Vapor density > 1.0 g/cc
Relative density 0.866
Bulk density 7.228 lb/gal
Solubility(ies)Insoluble in water.
Partition coefficient Not determined.
Auto-ignition temperature 210°C/410°F
Decomposition Temperature Not determined.
Volatility 3% wt (Max)
10. Stability and reactivity
Reactivity See the other subsections of this section for further details.
Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.
Possibility of hazardous
reactions
No potentially hazardous reactions known.
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Lubricating Oil
Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.
Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.
Hazardous decomposition
products
Does not decompose when used and stored as recommended. Thermal decomposition or
combustion products may include the following substances: Harmful gases or vapors.
11. Toxicological information
Information on toxicological effects
Toxicological effects Not regarded as a health hazard under current legislation.
Acute toxicity - oral
Notes (oral LD₅₀)Based on available data the classification criteria are not met.
Acute toxicity - dermal
Notes (dermal LD₅₀)Based on available data the classification criteria are not met.
Acute toxicity - inhalation
Notes (inhalation LC₅₀)Based on available data the classification criteria are not met.
Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.
Serious eye damage/irritation
Serious eye damage/irritation Based on available data the classification criteria are not met.
Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.
Skin sensitization
Skin sensitization Based on available data the classification criteria are not met.
Germ cell mutagenicity
Genotoxicity - in vitro Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
IARC carcinogenicity None of the ingredients are listed or exempt.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity -
development
Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.
Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.
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Lubricating Oil
General information No specific health hazards known. The severity of the symptoms described will vary
dependent on the concentration and the length of exposure.
Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.
Ingestion No specific symptoms known. May cause discomfort if swallowed.
Skin Contact No specific symptoms known. May cause discomfort.
Eye contact No specific symptoms known. May be slightly irritating to eyes.
Route of entry Ingestion Inhalation Skin and/or eye contact
Target Organs No specific target organs known.
12. Ecological Information
Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.
Toxicity Based on available data the classification criteria are not met.
Persistence and degradability
Persistence and degradability The degradability of the product is not known.
Bioaccumulative potential
Bio-Accumulative Potential No data available on bioaccumulation.
Partition coefficient Not determined.
Mobility in soil
Mobility No data available.
Other adverse effects
Other adverse effects None known.
13. Disposal considerations
Waste treatment methods
General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way.
Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposal
contractor. Waste packaging should be collected for reuse or recycling. Incineration or landfill
should only be considered when recycling is not feasible. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of the local water
authority.
14. Transport information
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DOT).
UN Number
Not applicable.
UN proper shipping name
Not applicable.
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Lubricating Oil
Transport hazard class(es)
No transport warning sign required.
Packing group
Not applicable.
Environmental hazards
Environmentally Hazardous Substance
No.
Special precautions for user
Not applicable.
Transport in bulk according to
Annex II of MARPOL 73/78
and the IBC Code
Not applicable.
15. Regulatory information
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)
None of the ingredients are listed or exempt.
SARA Extremely Hazardous Substances EPCRA Reportable Quantities
None of the ingredients are listed or exempt.
SARA 313 Emission Reporting
None of the ingredients are listed or exempt.
CAA Accidental Release Prevention
None of the ingredients are listed or exempt.
FDA - Essential Chemical
None of the ingredients are listed or exempt.
FDA - Precursor Chemical
None of the ingredients are listed or exempt.
SARA (311/312) Hazard Categories
None of the ingredients are listed or exempt.
OSHA Highly Hazardous Chemicals
None of the ingredients are listed or exempt.
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the ingredients are listed or exempt.
California Air Toxics "Hot Spots" (A-I)
None of the ingredients are listed or exempt.
California Air Toxics "Hot Spots" (A-II)
None of the ingredients are listed or exempt.
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Lubricating Oil
California Directors List of Hazardous Substances
None of the ingredients are listed or exempt.
Massachusetts "Right To Know" List
None of the ingredients are listed or exempt.
Rhode Island "Right To Know" List
None of the ingredients are listed or exempt.
Minnesota "Right To Know" List
None of the ingredients are listed or exempt.
New Jersey "Right To Know" List
None of the ingredients are listed or exempt.
Pennsylvania "Right To Know" List
None of the ingredients are listed or exempt.
Inventories
US - TSCA
None of the ingredients are listed or exempt.
US - TSCA 12(b) Export Notification
None of the ingredients are listed or exempt.
16. Other information
Classification abbreviations
and acronyms
Asp. Tox. = Aspiration hazard
Training advice Only trained personnel should use this material.
Revision date 2/8/2019
Revision 7
Supersedes date 10/9/2017
SDS No.4634
End of Safety Data Sheet
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
8/8Christensen Arms AO Modification 9/7/23
EU/EEC
According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]
Safety Data Sheet
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product identifier
Product Name • CR10
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s)•Cleaning
1.3 Details of the supplier of the safety data sheet
Manufacturer •Barnes Bullets
PO Box 620 Mona, UT 84645 United States
www.barnesbullets.com email@barnesbullets.com
Telephone (General)•(435) 8561000
1.4 Emergency telephone number
Manufacturer •(435) 8561000
Section 2: Hazards Identification
2.1 Classification of the substance or mixture
CLP • Oxidizing Liquids 3 H272 Acute Toxicity Oral 4 H302 Acute Toxicity Dermal 3 H311 Skin Corrosion 1B H314 Serious Eye Damage 1 H318 Acute Toxicity Inhalation 3 H331 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation H335 Reproductive Toxicity 1B H360D
2.2 Label Elements
CLP
DANGER
Hazard statements •H272 May intensify fire; oxidizer H302 Harmful if swallowed
CR-10CR-10CR-10CR-10
Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015
Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)
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United States (US)
According to: OSHA 29 CFR 1910.1200 HCS
H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage H331 Toxic if inhaled H335 May cause respiratory irritation H360D May damage the unborn child.
Precautionary statements
Prevention •P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat. P220 Keep/Store away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles P260 Do not breathe mists, vapours, and/or spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a wellventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required.
Response •P370+P378 In case of fire: Use appropriate media for extinction. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311 Call a POISON CENTER or doctor/physician. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment, see supplemental first aid information. P363 Wash contaminated clothing before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P312 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P331 Do NOT induce vomiting. P308+P313 IF exposed or concerned: Get medical advice/attention.
Storage/Disposal •P403+P233 Store in a wellventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Supplemental information •This product consists of ingredients of unknown toxicity: 45% via oral route, 8090% via inhalation route, 8090% via dermal route.
2.3 Other Hazards
CLP •According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous.
2.1 Classification of the substance or mixture
OSHA HCS 2012 •Oxidizing Liquids 3 Acute Toxicity Oral 4 Acute Toxicity Dermal 3 Skin Irritation 2 Serious Eye Damage 1 Acute Toxicity Inhalation 3 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Reproductive Toxicity 1B Specific Target Organ Toxicity Repeated Exposure 2
2.2 Label elements
CR-10CR-10CR-10CR-10
Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015
Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)
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Canada
According to: WHMIS
OSHA HCS 2012
DANGER
Hazard statements •May intensify fire; oxidizer Harmful if swallowed Toxic in contact with skin Causes skin irritation Causes serious eye damage Toxic if inhaled May cause respiratory irritation May cause drowsiness or dizziness May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention •Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles Do not breathe mists, vapours, and/or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a wellventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response •In case of fire: Use appropriate media for extinction. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. If on skin: Wash with plenty of water . Specific treatment, see supplemental first aid information. Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell.
Storage/Disposal •Store in a wellventilated place. Keep container tightly closed. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Supplemental information •This product consists of ingredients of unknown toxicity: 45% via oral route, 8090% via inhalation route, 8090% via dermal route.
2.3 Other hazards
OSHA HCS 2012 •Under United States Regulations (29 CFR 1910.1200 Hazard Communication Standard), this product is considered hazardous.
2.1 Classification of the substance or mixture
WHMIS •Oxidizing C Toxic D1B
CR-10CR-10CR-10CR-10
Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015
Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)
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Other Toxic Effects D2A Corrosive E
2.2 Label elements
WHMIS
•Oxidizing C Toxic D1B Other Toxic Effects D2A Corrosive E
2.3 Other hazards
WHMIS •In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS).
Section 3 Composition/Information on Ingredients
3.1 Substances
•Material does not meet the criteria of a substance.
3.2 Mixtures
Composition
Chemical Name Identifiers %LD50/LC50 Classifications According to Regulation/Directive Comments
Proprietary
Blend NDA 0% TO
100% NDA EU CLP: Not Classified
OSHA HCS 2012: Not Classified NDA
Ethylene glycol
monobutyl ether
CAS:111762
EC
Number:203
9050
EU Index:603
014000
10%
TO
20%
InhalationRat
LC50 • 450 ppm 4
Hour(s)
SkinRabbit LD50 •
220 mg/kg
Ingestion/OralRat
LD50 • 250 mg/kg
EU CLP: Annex VI, Table 3.1: Acute Tox. 3, H301;
Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Irrit. 2,
H315; Eye Irrit. 2, H319
OSHA HCS 2012: Flam. Liq. 4; Acute Tox. 3 (Orl);
Acute Tox. 3 (Skn); Acute Tox. 3 (Inhl); Eye Irrit. 2;
Repr. 2; STOT SE 3: Narc.; STOT SE 3: Resp. Irrit.
(Orl); STOT RE 2 (Blood, Inhl, Orl, Skn)
NDA
Sodium nitrate
CAS:7631994
EC
Number:231
5543
10%
TO
15%
Ingestion/OralRat
LD50 • 1267 mg/kg
EU CLP: Skin Irrit. 2, H315; Eye Irrit. 2, H319; Acute
Tox. 4, H302; Ox. Sol. 3, H272
OSHA HCS 2012: Skin Irrit. 2; Eye Irrit. 2A; STOT SE
3: Resp. Irrit.; Acute Tox. 4 (Orl); Ox. Sol. 3
NDA
Ammonium
hydroxide
CAS:1336216
EC
Number:215
6476
EU Index:007
001012
5% TO
10%
Ingestion/OralRat
LD50 • 350 mg/kg
EU CLP: Annex VI, Table 3.1: Skin Corr. 1B, H314;
Aquatic Acute 1, H400
OSHA HCS 2012: Acute Tox. 3 (Orl); Eye Dam. 1;
Skin Corr. 1C; STOT SE 3: Resp. Irrit.
NDA
2Pyrrolidinone,
1methyl
CAS:872504
EC
Number:212
8281
EU Index:606
021007
5% TO
10%
Ingestion/OralRat
LD50 • 3914 mg/kg
SkinRabbit LD50 • 8
g/kg
EU CLP: Annex VI, Table 3.1: Repr. 1B, H360D ***;
Eye Irrit. 2, H319; STOT SE 3: Resp. Irrit., H335; Skin
Irrit. 2, H315
OSHA HCS 2012: Eye Irrit. 2; Repr. 1B; Skin Irrit. 2;
Skin Sens. 1
NDA
CR-10CR-10CR-10CR-10
Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015
Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)
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See Section 16 for full text of Hstatements.
Section 4 First Aid Measures
4.1 Description of first aid measures
Inhalation • Move victim to fresh air. Administer oxygen if breathing is difficult. Do not use mouthtomouth method if victim inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a oneway valve or other proper respiratory medical device. Give artificial respiration if victim is not breathing. Get medical attention immediately.
Skin • For minor skin contact, avoid spreading material on unaffected skin. In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Remove and isolate contaminated clothing. Get medical attention immediately.
Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately.
Ingestion • If swallowed, rinse mouth with water.(only if the person is conscious). Do NOT induce vomiting. Do not use mouthtomouth method if victim ingested the substance. Obtain medical attention immediately if ingested.
4.2 Most important symptoms and effects, both acute and delayed
•Refer to Section 11 Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician • All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
Section 5 Firefighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media • SMALL FIRES: Use water. SMALL FIRES: CO2 or Halon® may provide limited control. LARGE FIRE: Flood fire area with water from a distance.
Unsuitable Extinguishing Media • SMALL FIRES: Do not use dry chemicals or foams.
5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion Hazards • Containers may explode when heated. May explode from heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.) Runoff may create fire or explosion hazard. Some may decompose explosively when heated or involved in a fire. Some will react explosively with hydrocarbons (fuels) These substances will accelerate burning when involved in a fire.
Hazardous Combustion Products • This product is not defined as flammable or combustible; however, under fire conditions it may support combustion and produce toxic oxides of carbon and various hydrocarbons.
5.3 Advice for firefighters
•Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Wear positive pressure selfcontained breathing apparatus (SCBA). Move containers from fire area if you can do it without risk.
Section 6 Accidental Release Measures
CR-10CR-10CR-10CR-10
Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015Preparation Date: 30/January/2015
Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015Revision Date: 10/November/2015
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)
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6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions • Ventilate enclosed areas. Do not walk through spilled material. Avoid contact with skin, eyes or clothing. Wear a selfcontained breathing apparatus and appropriate Personal Protective Equipment (PPE) Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Contaminated clothing may be a fire risk when dry.
Emergency Procedures • LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet) As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep combustibles (wood, paper, oil, etc.) away from spilled material. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Do not get water inside container.
6.2 Environmental precautions
•Prevent entry into waterways, sewers, basements or confined areas.
6.3 Methods and material for containment and cleaning up
Containment/Cleanup Measures • LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Following product recovery, flush area with water. SMALL LIQUID SPILLS: Use a noncombustible material like vermiculite or sand to soak up the product and place into a container for later disposal.
6.4 Reference to other sections
•Refer to Section 8 Exposure Controls/Personal Protection and Section 13 Disposal Considerations.
Section 7 Handling and Storage
7.1 Precautions for safe handling
Handling •Handle and open container with care. Use only with adequate ventilation. Use caution when combining with water; DO NOT add water to corrosive liquid, ALWAYS add corrosive liquid to water while stirring to prevent release of heat, steam and fumes. Do not breathe mist, vapours, and/or spray. Do not get in eyes, on skin, or on clothing. Wear appropriate personal protective equipment, avoid direct contact. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.
7.2 Conditions for safe storage, including any incompatibilities
Storage • Keep container tightly closed. Store in a cool, dry, wellventilated place.
7.3 Specific end use(s)
•Refer to Section 1.2 Relevant identified uses.
Section 8 Exposure Controls/Personal Protection
8.1 Control parameters
Exposure Limits/Guidelines
Result ACGIH NIOSH OSHA
Ethylene glycol
monobutyl ether
(111762)
TWAs 20 ppm TWA 5 ppm TWA; 24 mg/m3 TWA 50 ppm TWA; 240 mg/m3 TWA
8.2 Exposure controls
Engineering Measures/Controls • Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable
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level. Use explosionproof electrical/ventilating/lighting/equipment.
Personal Protective Equipment
Respiratory •In case of insufficient ventilation, wear suitable respiratory equipment.
Eye/Face •Wear chemical splash safety goggles.
Skin/Body •Wear appropriate gloves. Wear long sleeves and/or protective coveralls.
Environmental Exposure Controls • Follow best practice for site management and disposal of waste. Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways.
Key to abbreviations
ACGIH=American Conference of Governmental Industrial Hygiene
NIOSH=National Institute of Occupational Safety and Health
OSHA =Occupational Safety and Health Administration
TWA =TimeWeighted Averages are based on 8h/day, 40h/week exposures
Section 9 Physical and Chemical Properties
9.1 Information on Physical and Chemical Properties
Material Description
Physical Form Liquid Appearance/Description Light yellow to dark amber liquid
with strong ammonia odor.
Color Light yellow to dark amber.Odor Strong ammonia.
Odor Threshold Data lacking
General Properties
Boiling Point Data lacking Melting Point/Freezing Point Data lacking
Decomposition Temperature Data lacking pH Data lacking
Specific Gravity/Relative Density = 1.1 Water=1 Water Solubility Soluble 100 %
Viscosity Data lacking Explosive Properties Data lacking
Oxidizing Properties: Data lacking
Volatility
Vapor Pressure Data lacking Vapor Density Data lacking
Evaporation Rate Data lacking
Flammability
Flash Point > 200 F(> 93.3333 C)UEL Data lacking
LEL Data lacking Autoignition Data lacking
Flammability (solid, gas) Data lacking
Environmental
Octanol/Water Partition coefficient Data lacking
9.2 Other Information
•No additional physical and chemical parameters noted.
Section 10: Stability and Reactivity
10.1 Reactivity
•No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
•Stable under normal temperatures and pressures.
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10.3 Possibility of hazardous reactions
•Hazardous polymerization will not occur.
10.4 Conditions to avoid
•Exposure to high temperatures.
10.5 Incompatible materials
•Strong oxidizing agents.
10.6 Hazardous decomposition products
•Toxic oxides of carbon and hydrocarbons.
Section 11 Toxicological Information
11.1 Information on toxicological effects
Components
Ethylene glycol
monobutyl ether
(10% TO 20%)
111
762
Acute Toxicity:Ingestion/OralRat LD50 • 250 mg/kg; Ingestion/OralMan TDLo • 132 mg/kg; Behavioral:Sleep; Kidney,
Ureter, and Bladder:Hematuria; Nutritional and Gross Metabolic:Changes in Chemistry or Temperature:Metabolic
acidosis; InhalationRat LC50 • 450 ppm 4 Hour(s); Behavioral:Ataxia; Nutritional and Gross Metabolic:Gross
Metabolite Changes:Weight loss or decreased weight gain; SkinRabbit LD50 • 220 mg/kg;
Irritation:EyeRabbit • 100 mg 24 Hour(s) • Moderate irritation; SkinRabbit • 500 mgOpen • Mild irritation;
Multidose Toxicity:InhalationMonkey TCLo • 500 mg/m³ 7 Hour(s) 12 Week(s)Intermittent; Blood:Normocytic
anemia; Blood:Changes in serum composition (e.g., TP, bilirubin cholesterol); InhalationRat TCLo • 10 mg/m³
90 Day(s)Continuous; Endocrine:Hypoglycemia; Blood:Normocytic anemia; Nutritional and Gross
Metabolic:Gross Metabolite Changes:Weight loss or decreased weight gain; InhalationRat TCLo • 10 mg/m³ 24
Hour(s) 13 Week(s)Continuous; Endocrine:Hypoglycemia; Blood:Changes in erythrocyte (RBC) count;
Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:Transaminases; SkinRabbit TDLo •
4500 µL/kg 9 Day(s)Intermittent; Liver:Changes in liver weight; Blood:Pigmented or nucleated red blood cells;
Blood:Changes in erythrocyte (RBC) count;
Reproductive:Ingestion/OralRat TDLo • 600 mg/kg (911D preg); Reproductive Effects:Effects on Embryo or
Fetus:Fetal death; InhalationRabbit TCLo • 100 ppm 6 Hour(s)(618D preg); Reproductive Effects:Specific
Developmental Abnormalities:Cardiovascular (circulatory) system; InhalationRabbit TCLo • 483 mg/m³ (6H/615D
preg); Reproductive Effects:Effects on Fertility:Preimplantation mortality; Reproductive Effects:Effects on
Fertility:Postimplantation mortality; Reproductive Effects:Specific Developmental
Abnormalities:Musculoskeletal system;
Tumorigen / Carcinogen:InhalationMouse TCLo • 250 ppm 6 Hour(s) 2 Year(s)Intermittent;
Tumorigenic:Carcinogenic by RTECS criteria; Liver:Tumors; InhalationRat TCLo • 125 ppm 6 Hour(s) 2 Year(s)
Intermittent; Tumorigenic:Equivocal tumorigenic agent by RTECS criteria; Endocrine:Tumors
Ammonium
hydroxide (5%
TO 10%)
1336
216
Acute Toxicity:Ingestion/OralRat LD50 • 350 mg/kg; Gastrointestinal:Other changes; Liver:Other changes;
Kidney, Ureter, and Bladder:Other changes;
Irritation:EyeRabbit • 44 µg • Severe irritation
Sodium nitrate
(10% TO 15%)
7631
994
Acute Toxicity:Ingestion/OralRat LD50 • 1267 mg/kg;
Tumorigen / Carcinogen:Ingestion/OralRat TDLo • 100 g/kg 2 Year(s)Continuous; Tumorigenic:Equivocal
tumorigenic agent by RTECS criteria; Liver:Tumors
2Pyrrolidinone,
1methyl (5%
TO 10%)
872
504
Acute Toxicity:Ingestion/OralRat LD50 • 3914 mg/kg;
Irritation:EyeRabbit • 100 mg • Moderate irritation;
Multidose Toxicity:Ingestion/OralRat TDLo • 33750 mg/kg 90 Day(s)Intermittent; Behavioral:Muscle
weakness; InhalationRat TCLo • 400 mg/m³ 6 Hour(s) 4 Week(s)Intermittent; Lungs, Thorax, or Respiration:Acute
pulmonary edema; Blood:Changes in leucocyte (WBC) count; Related to Chronic Data:Death in the Other
Multiple Dose data type field;
Reproductive:Ingestion/OralRat TDLo • 7.5 g/kg (620D preg); Reproductive Effects:Effects on Embryo or
Fetus:Fetotoxicity (except death, e.g., stunted fetus); Reproductive Effects:Specific Developmental
Abnormalities:Musculoskeletal system; Ingestion/OralRat TDLo • 11.25 g/kg (620D preg); Reproductive
Effects:Specific Developmental Abnormalities:Craniofacial (including nose and tongue);
Tumorigen / Carcinogen:Ingestion/OralMouse TDLo • 784 g/kg 78 Week(s)Continuous;
Tumorigenic:Carcinogenic by RTECS criteria; Liver:Tumors
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GHS Properties Classification
Respiratory sensitization EU/CLP •Data lacking
OSHA HCS 2012 •Data lacking
Serious eye damage/Irritation EU/CLP •Serious Eye Damage 1
OSHA HCS 2012 •Serious Eye Damage 1
Acute toxicity
EU/CLP •Acute Toxicity Dermal 3 ATEmix(dermal) = 220 mg/kg; Acute Toxicity
Inhalation 3 ATEmix(inhl, vapors) = 450 ppm; Acute Toxicity Oral 4 ATEmix(oral) =
745.83 mg/kg
OSHA HCS 2012 •Acute Toxicity Dermal 3 ATEmix(dermal) = 220 mg/kg; Acute
Toxicity Inhalation 3 ATEmix(inhl) = 450 ppm; Acute Toxicity Oral 4 ATEmix(oral) =
720.85 mg/k
Aspiration Hazard EU/CLP •Data lacking
OSHA HCS 2012 •Data lacking
Carcinogenicity EU/CLP •Data lacking
OSHA HCS 2012 •Data lacking
Skin corrosion/Irritation EU/CLP •Skin Corrosion 1B
OSHA HCS 2012 •Skin Irritation 2
Skin sensitization EU/CLP •Data lacking
OSHA HCS 2012 •Data lacking
STOTRE EU/CLP •Data lacking
OSHA HCS 2012 •Specific Target Organ Toxicity Repeated Exposure 2
STOTSE
EU/CLP •Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation
OSHA HCS 2012 •Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects;
Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation
Toxicity for Reproduction EU/CLP •Toxic to Reproduction 1B
OSHA HCS 2012 •Toxic to Reproduction 1B
Germ Cell Mutagenicity EU/CLP •Data lacking
OSHA HCS 2012 •Data lacking
Potential Health Effects
Inhalation
Acute (Immediate)•Toxic if inhaled. May cause corrosive burns irreversible damage. May cause respiratory irritation. May affect the central nervous system. Symptoms may include dizziness, drowsiness, lethargy, coma and death.
Chronic (Delayed)•Repeated or prolonged exposure to corrosive fumes may cause bronchial irritation with chronic cough.
Skin
Acute (Immediate)•Toxic in contact with skin. Causes severe skin burns and eye damage.
Chronic (Delayed)•Repeated or prolonged exposure to corrosive materials will cause dermatitis.
Eye
Acute (Immediate)•Causes serious eye damage.
Chronic (Delayed)•Repeated or prolonged exposure to corrosive materials or fumes may cause conjunctivitis.
Ingestion
Acute (Immediate)•Harmful if swallowed. May cause irreversible damage to mucous membranes.
Chronic (Delayed)•Repeated or prolonged exposure to corrosive materials or fumes may cause
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gastrointestinal distrubances.
Other
Chronic (Delayed)•Repeated and prolonged exposure may affect the blood and/or immune system.
Reproductive Effects •Repeated and prolonged exposure may cause reproductive effects.
Key to abbreviations
LC =Lethal Concentration
LD =Lethal Dose
TC=Toxic Concentration
TD=Toxic Dose
Section 12 Ecological Information
12.1 Toxicity
•Material data lacking.
12.2 Persistence and degradability
•Material data lacking.
12.3 Bioaccumulative potential
•Material data lacking.
12.4 Mobility in Soil
•Material data lacking.
12.5 Results of PBT and vPvB assessment
•PBT and vPvB assessment has not been conducted.
12.6 Other adverse effects
• No studies have been found.
Section 13 Disposal Considerations
13.1 Waste treatment methods
Product waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Section 14 Transport Information
14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es)14.4 Packing group
14.5 Environmental hazards
DOT NDA Not Regulated NDA NDA NDA
TDG NDA Not Regulated NDA NDA NDA
IMO/IMDG UN3082
ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (Ammonium
hydroxide)
9 III NDA
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IATA/ICAO UN3082 Environmentally hazardous substance, liquid,
n.o.s. (Ammonium hydroxide) 9 III NDA
14.6 Special precautions for user • None specified.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
• Data lacking.
Section 15 Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
SARA Hazard Classifications • Acute, Chronic, Fire
Inventory
Component CAS Canada DSL Canada NDSL EU EINECS EU ELNICS TSCA
2Pyrrolidinone, 1
methyl872504 Yes No Yes No Yes
Ammonium
hydroxide 1336216 Yes No Yes No Yes
Ethylene glycol
monobutyl ether 111762 Yes No Yes No Yes
Sodium nitrate 7631994 Yes No Yes No Yes
Canada
Labor Canada WHMIS Classifications of Substances
•Ethylene glycol monobutyl ether 111762 B3, D1A, D2B
•Ammonium hydroxide 1336216 E
•Sodium nitrate 7631994 C, D2B
•2Pyrrolidinone, 1methyl 872504 B3, D2B
Canada WHMIS Ingredient Disclosure List
•Ethylene glycol monobutyl ether 111762 1 %
•Ammonium hydroxide 1336216 1 %
•Sodium nitrate 7631994 1 %
•2Pyrrolidinone, 1methyl 872504 Not Listed
Environment Canada CEPA Priority Substances List
•Ethylene glycol monobutyl ether 111762
Priority Substance List 2
(substance considered toxic,
added to CEPA's Schedule 1,
List of Toxic Substances)
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
United States
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Labor U.S. OSHA Process Safety Management Highly Hazardous Chemicals
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. OSHA Specifically Regulated Chemicals
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
Environment U.S. CAA (Clean Air Act) 1990 Hazardous Air Pollutants
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. CERCLA/SARA Hazardous Substances and their Reportable Quantities
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 1000 lb final RQ; 454 kg final
RQ
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. CERCLA/SARA Radionuclides and Their Reportable Quantities
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. CERCLA/SARA Section 302 Extremely Hazardous Substances EPCRA RQs
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. CERCLA/SARA Section 302 Extremely Hazardous Substances TPQs
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. CERCLA/SARA Section 313 Emission Reporting
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 1.0 % de minimis
concentration
U.S. CERCLA/SARA Section 313 PBT Chemical Listing
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
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•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
United States California
Environment U.S. California Proposition 65 Carcinogens List
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. California Proposition 65 Developmental Toxicity
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 developmental toxicity, initial
date 6/15/01
U.S. California Proposition 65 Maximum Allowable Dose Levels (MADL)
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504
3200 µg/day MADL
(inhalation); 17000 µg/day
MADL (dermal)
U.S. California Proposition 65 No Significant Risk Levels (NSRL)
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. California Proposition 65 Reproductive Toxicity Female
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
U.S. California Proposition 65 Reproductive Toxicity Male
•Ethylene glycol monobutyl ether 111762 Not Listed
•Ammonium hydroxide 1336216 Not Listed
•Sodium nitrate 7631994 Not Listed
•2Pyrrolidinone, 1methyl 872504 Not Listed
15.2 Chemical Safety Assessment
•No Chemical Safety Assessment has been carried out.
15.3 Other Information
•WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.
Section 16 Other Information
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Relevant Phrases (code & full text)
•H301 Toxic if swallowed H315 Causes skin irritation H319 Causes serious eye irritation H400 Very toxic to aquatic life
Revision Date • 10/November/2015
Preparation Date • 30/January/2015
Disclaimer/Statement of Liability • The information herein is given in good faith but no warranty, expressed or implied, is made.
Key to abbreviations
NDA=No Data Available
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1. PRODUCT AND COMPANY IDENTIFICATION
Product name: LOCTITE® 242® THREADLOCKER IDH number: 135355 Product type: Anaerobic Sealant Item number: 24231
Restriction of Use: None identified Region: United States
Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067
Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN AND EYE IRRITATION. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2 EYE IRRITATION 2B SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S)
Precautionary Statements Prevention: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling. Wear protective gloves.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Component(s) CAS Number Percentage*
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Oleic acid 5.5EO 9004-96-0 20 - 30
Saccharin 81-07-2 1 - 5
Silica, amorphous, fumed, crystal-free 112945-52-5 1 - 5
Cumene hydroperoxide 80-15-9 1 - 5
Propane-1,2-diol 57-55-6 1 - 5
Cumene 98-82-8 0.1 - 1
Titanium dioxide 13463-67-7 0.1 - 1
* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.
4. FIRST AID MEASURES
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Symptoms: See Section 11.
5. FIRE FIGHTING MEASURES
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers.
Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.
6. ACCIDENTAL RELEASE MEASURES
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions: Do not allow product to enter sewer or waterways.
Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.
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7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8.
Storage: For safe storage, store between 0 °C (32°F) and 32 °C (89.6 °F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER
Oleic acid 5.5EO None None None None
Saccharin None None None None
Silica, amorphous, fumed, crystal-free
10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA Respirable fraction.
20 MPPCF TWA 0.8 mg/m3 TWA None None
Cumene hydroperoxide None None 1 ppm (6 mg/m3) TWA (SKIN) None
Propane-1,2-diol None None 10 mg/m3 TWA Aerosol. None
Cumene 50 ppm TWA 50 ppm (245 mg/m3) PEL (SKIN) None None
Titanium dioxide 10 mg/m3 TWA
15 mg/m3 PEL Total dust. 15 MPPCF TWA Respirable fraction. 15 mg/m3 TWA Total dust. 50 MPPCF TWA Total dust. 5 mg/m3 TWA Respirable fraction.
None None
Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Blue
Odor: Mild Odor threshold: Not available.
pH: Not applicable
Vapor pressure: < 5 mm hg (27 °C (80.6 °F))
Boiling point/range: > 149 °C (> 300.2 °F)
Christensen Arms AO Modification 9/7/23
Melting point/ range: Not available.
Specific gravity: 1.1 at 23.9 °C (75.02 °F)
Vapor density: Not available. Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup
Flame projection: Not applicable
Flammable/Explosive limits - lower: 2.6 % (propylene glycol)
Flammable/Explosive limits - upper: 12.5 % (propylene glycol)
Autoignition temperature: Not determined Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available.
VOC content: 0.56 %; 6.17 g/l (California SCAQMD Method 316B) (Estimated) Viscosity: Not available.
Decomposition temperature: Not available.
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials.
Hazardous decomposition
products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.
Incompatible materials: Strong oxidizing agents. Free radical initiators. Strong reducing agents. Alkalis. Oxygen scavengers. Other polymerization initiators. Copper. Iron. Zinc. Aluminum. Rust.
Reactivity: Not available.
Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials.
11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Christensen Arms AO Modification 9/7/23
Potential Health Effects/Symptoms
Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Skin contact: Causes skin irritation.
Eye contact: Causes eye irritation.
Ingestion: May cause gastrointestinal tract irritation if swallowed.
Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Oleic acid 5.5EO None Irritant Saccharin Oral LD50 (Mouse) = 17 g/kg No Target Organs
Silica, amorphous, fumed, crystal-free None Nuisance dust
Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l Allergen, Central nervous system, Corrosive, Irritant, Mutagen
Propane-1,2-diol Oral LD50 (Rabbit) = 18 g/kg Oral LD50 (Mouse) = 23.9 g/kg Oral LD50 (Rat) = 30 g/kg Irritant
Cumene
Oral LD50 (Rat) = 2.91 g/kg Oral LD50 (Rat) = 1,400 mg/kg Inhalation LC50 (Rat, 4 h) = 8000 ppm Central nervous system, Irritant, Lung
Titanium dioxide None Irritant, Respiratory, Some evidence of carcinogenicity
Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen
(Specifically Regulated)
Oleic acid 5.5EO No No No Saccharin No No No
Silica, amorphous, fumed, crystal-free No No No Cumene hydroperoxide No No No Propane-1,2-diol No No No
Cumene Reasonably Anticipated to be a Human Carcinogen. Group 2B No
Titanium dioxide No Group 2B No
12. ECOLOGICAL INFORMATION
Ecological information: Not available.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082 Packing group: III
DOT Hazardous Substance(s): alpha,alpha-Dimethylbenzylhydroperoxide
Christensen Arms AO Modification 9/7/23
International Air Transportation (ICAO/IATA)
Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9 Identification number: UN 3082
Packing group: III
Water Transportation (IMO/IMDG)
Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9
Identification number: UN 3082
Packing group: III
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
CERCLA/SARA Section 302 EHS: None above reporting de minimis.
CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Saccharin (CAS# 81-07-2). Cumene hydroperoxide (CAS# 80-15-9).
CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg)
California Proposition 65: This product contains a chemical known in the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details.
16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: 2
Prepared by: Product Safety and Regulatory Affairs
Issue date: 01/11/2018 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name: Bos-Gear 150
Product Description: Extreme Pressure Industrial Gear Oil Product Code: BOSGEA150-055, BOSGEA150-005 Intended Use: Lubrication Oil For Gear Boxes
Company Identification
Bosse Lubricants Mailing Address
Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email:
customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Warning
Causes Mild Skin Irritation – Category 3
Health Hazards This product should not present any health issues when used under normal conditions as
intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild
skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As
with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may
cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting
and diarrhea. It is considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to
person.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3) OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions
as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical
attention. Remove and wash contaminated clothing before re-use. In the unlikely event the
product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be sent to the hospital immediately.
In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in
these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical
attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for
dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If
large amounts have been ingested or person affected is not feeling well, seek medical
attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard
protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and
gases (smoke). Incomplete combustion products, Oxides of carbon, carbon
monoxide, aldehydes, zinc and sulfur oxides.
Flash Point: >400oF Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 3 of 6
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal
protective gear to limit exposure. Contain spill immediately. Do not allow material to enter
the environment. Prevent material from entering rivers, streams, storm drains and any
area that will allow the material to spread.
Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate
areas. A pump or vacuum can be used for large spills and inert material such as
appropriate absorbent (sand) can be used for smaller spills. Place excess material and
absorbent materials in appropriate containers. Follow the appropriate disposal guidelines
for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water
ways such as streams or rivers. Should the spill occur on a roadway, contact the
appropriate government or city agencies. The National Response Center can be reached
at 1.800.424.8802.
SECTION 7 HANDLING AND STORAGE
General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any
special handling instructions. We still recommend personal protection just as a good safety
practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we
still recommend using gloves and safety goggles when handling to limit exposure. Handle
in accordance with good industrial hygiene and safety practice. Always replace the lid or
cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination.
Ambient temperatures are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: The level of protection and types of controls necessary will vary depending upon
potential exposure conditions. Control measures to consider: No special requirements
under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions
such as applications, handling practices, concentration and ventilation. Information on
the selection of protective equipment for use with this material, as provided below, is
based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance
with good industrial hygiene practices, precautions should be taken to avoid skin
contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case
of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are
recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Environmental Exposure Controls: Minimize exposure of this material to the environment.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 4 of 6
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold pH Melting Point Freezing Point
Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density
Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 5 of 6
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused Products:
Disposal must be in accordance with current applicable laws and regulations, and material
characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums should be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of
California to cause cancer, birth defects or other reproductive harm.
Christensen Arms AO Modification 9/7/23
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Language: English Version: 2
Format: US Page: Page 6 of 6
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate
and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current
available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages
this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with
and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of
this document, in whole or in part, is not permitted.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 220 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name: Bos-Gear 220
Product Description: Extreme Pressure Industrial Gear Oil Product Code: BOSGEA220-055, BOSGEA220-005 Intended Use: Lubrication Oil For Gear Boxes
Company Identification
Bosse Lubricants Mailing Address
Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email:
customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Warning
Causes Mild Skin Irritation – Category 3
Health Hazards This product should not present any health issues when used under normal conditions as
intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild
skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As
with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may
cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting
and diarrhea. It is considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to
person.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 220 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3) OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions
as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical
attention. Remove and wash contaminated clothing before re-use. In the unlikely event the
product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be sent to the hospital immediately.
In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in
these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical
attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for
dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If
large amounts have been ingested or person affected is not feeling well, seek medical
attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard
protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and
gases (smoke). Incomplete combustion products, Oxides of carbon, carbon
monoxide, aldehydes, zinc and sulfur oxides.
Flash Point: >400oF Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 220 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 3 of 6
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal
protective gear to limit exposure. Contain spill immediately. Do not allow material to enter
the environment. Prevent material from entering rivers, streams, storm drains and any
area that will allow the material to spread.
Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate
areas. A pump or vacuum can be used for large spills and inert material such as
appropriate absorbent (sand) can be used for smaller spills. Place excess material and
absorbent materials in appropriate containers. Follow the appropriate disposal guidelines
for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water
ways such as streams or rivers. Should the spill occur on a roadway, contact the
appropriate government or city agencies. The National Response Center can be reached
at 1.800.424.8802.
SECTION 7 HANDLING AND STORAGE
General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any
special handling instructions. We still recommend personal protection just as a good safety
practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we
still recommend using gloves and safety goggles when handling to limit exposure. Handle
in accordance with good industrial hygiene and safety practice. Always replace the lid or
cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination.
Ambient temperatures are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: The level of protection and types of controls necessary will vary depending upon
potential exposure conditions. Control measures to consider: No special requirements
under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions
such as applications, handling practices, concentration and ventilation. Information on
the selection of protective equipment for use with this material, as provided below, is
based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance
with good industrial hygiene practices, precautions should be taken to avoid skin
contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case
of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are
recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Environmental Exposure Controls: Minimize exposure of this material to the environment.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 220 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 4 of 6
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold pH Melting Point Freezing Point
Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density
Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 220 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 5 of 6
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused Products:
Disposal must be in accordance with current applicable laws and regulations, and material
characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums should be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of
California to cause cancer, birth defects or other reproductive harm.
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Gear 220 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 6 of 6
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate
and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current
available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages
this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with
and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of
this document, in whole or in part, is not permitted.
Christensen Arms AO Modification 9/7/23
Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name: Premium AW Hydraulic 46
Product Description: Anti-Wear Hydraulic Oil Product Code: BOSHYD046-005, BOSHYD046-055, BOSHYD046-275 Intended Use: High Pressure Hydraulic & General Machine Oil
Company Identification
Bosse Lubricants Mailing Address
Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email:
customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Warning
Causes Mild Skin Irritation – Category 3
Health Hazards This product should not present any health issues when used under normal conditions as
intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild
skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As
with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may
cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting
and diarrhea. It is considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to
person.
Christensen Arms AO Modification 9/7/23
Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3) OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions
as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical
attention. Remove and wash contaminated clothing before re-use. In the unlikely event the
product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be sent to the hospital immediately.
In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in
these cases could be critical.
Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical
attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for
dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If
large amounts have been ingested or person affected is not feeling well, seek medical
attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard
protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and
gases (smoke). Incomplete combustion products, Oxides of carbon, carbon
monoxide, aldehydes, zinc and sulfur oxides.
Flash Point: >400oF Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0
Christensen Arms AO Modification 9/7/23
Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 3 of 6
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal
protective gear to limit exposure. Contain spill immediately. Do not allow material to enter
the environment. Prevent material from entering rivers, streams, storm drains and any
area that will allow the material to spread.
Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate
areas. A pump or vacuum can be used for large spills and inert material such as
appropriate absorbent (sand) can be used for smaller spills. Place excess material and
absorbent materials in appropriate containers. Follow the appropriate disposal guidelines
for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water
ways such as streams or rivers. Should the spill occur on a roadway, contact the
appropriate government or city agencies. The National Response Center can be reached
at 1.800.424.8802.
SECTION 7 HANDLING AND STORAGE
General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any
special handling instructions. We still recommend personal protection just as a good safety
practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we
still recommend using gloves and safety goggles when handling to limit exposure. Handle
in accordance with good industrial hygiene and safety practice. Always replace the lid or
cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination.
Ambient temperatures are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: The level of protection and types of controls necessary will vary depending upon
potential exposure conditions. Control measures to consider: No special requirements
under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions
such as applications, handling practices, concentration and ventilation. Information on
the selection of protective equipment for use with this material, as provided below, is
based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance
with good industrial hygiene practices, precautions should be taken to avoid skin
contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case
of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are
recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Environmental Exposure Controls: Minimize exposure of this material to the environment.
Christensen Arms AO Modification 9/7/23
Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 4 of 6
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold pH Melting Point Freezing Point
Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density
Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.87
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
Christensen Arms AO Modification 9/7/23
Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 5 of 6
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused Products:
Disposal must be in accordance with current applicable laws and regulations, and material
characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums should be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of
California to cause cancer, birth defects or other reproductive harm.
Christensen Arms AO Modification 9/7/23
Product Name: Premium AW Hydraulic 46 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 6 of 6
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate
and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current
available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages
this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with
and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of
this document, in whole or in part, is not permitted.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 32 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name: Unilube 32
Product Description: R&O Turbine Oil/Anti-Wear ISO 32 Product Code: BOSUNI032-275, BOSUNI032-055, BOSUNI032-005 Intended Use: Turbine, Circulating, Hydraulic & Bar Feed Oil
Company Identification
Bosse Lubricants Mailing Address
Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email:
customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Warning
Causes Mild Skin Irritation – Category 3
Health Hazards This product should not present any health issues when used under normal conditions as
intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild
skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As
with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may
cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting
and diarrhea. It is considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to
person.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 32 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3) OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions
as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical
attention. Remove and wash contaminated clothing before re-use. In the unlikely event the
product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be sent to the hospital immediately.
In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in
these cases could be critical.
Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical
attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for
dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If
large amounts have been ingested or person affected is not feeling well, seek medical
attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard
protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and
gases (smoke). Incomplete combustion products, Oxides of carbon, carbon
monoxide, aldehydes, zinc and sulfur oxides.
Flash Point: >400oF Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 32 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 3 of 6
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal
protective gear to limit exposure. Contain spill immediately. Do not allow material to enter
the environment. Prevent material from entering rivers, streams, storm drains and any
area that will allow the material to spread.
Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate
areas. A pump or vacuum can be used for large spills and inert material such as
appropriate absorbent (sand) can be used for smaller spills. Place excess material and
absorbent materials in appropriate containers. Follow the appropriate disposal guidelines
for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water
ways such as streams or rivers. Should the spill occur on a roadway, contact the
appropriate government or city agencies. The National Response Center can be reached
at 1.800.424.8802.
SECTION 7 HANDLING AND STORAGE
General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any
special handling instructions. We still recommend personal protection just as a good safety
practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we
still recommend using gloves and safety goggles when handling to limit exposure. Handle
in accordance with good industrial hygiene and safety practice. Always replace the lid or
cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination.
Ambient temperatures are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: The level of protection and types of controls necessary will vary depending upon
potential exposure conditions. Control measures to consider: No special requirements
under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions
such as applications, handling practices, concentration and ventilation. Information on
the selection of protective equipment for use with this material, as provided below, is
based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance
with good industrial hygiene practices, precautions should be taken to avoid skin
contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case
of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are
recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Environmental Exposure Controls: Minimize exposure of this material to the environment.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 32 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 4 of 6
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold pH Melting Point Freezing Point
Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density
Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 32 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 5 of 6
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused Products:
Disposal must be in accordance with current applicable laws and regulations, and material
characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums should be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of
California to cause cancer, birth defects or other reproductive harm.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 32 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 6 of 6
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate
and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current
available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages
this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with
and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of
this document, in whole or in part, is not permitted.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name: Unilube 150
Product Description: R&O Turbine Oil/Anti-Wear ISO 150 Product Code: BOSUNI150-275, BOSUNI150-055, BOSUNI150-005 Intended Use: Turbine, Circulating, Hydraulic & Bar Feed Oil
Company Identification
Bosse Lubricants Mailing Address
Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email:
customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Warning
Causes Mild Skin Irritation – Category 3
Health Hazards This product should not present any health issues when used under normal conditions as
intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild
skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As
with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may
cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting
and diarrhea. It is considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to
person.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3) OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions
as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical
attention. Remove and wash contaminated clothing before re-use. In the unlikely event the
product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be sent to the hospital immediately.
In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in
these cases could be critical.
Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical
attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for
dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If
large amounts have been ingested or person affected is not feeling well, seek medical
attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard
protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and
gases (smoke). Incomplete combustion products, Oxides of carbon, carbon
monoxide, aldehydes, zinc and sulfur oxides.
Flash Point: >400oF Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 3 of 6
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal
protective gear to limit exposure. Contain spill immediately. Do not allow material to enter
the environment. Prevent material from entering rivers, streams, storm drains and any
area that will allow the material to spread.
Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate
areas. A pump or vacuum can be used for large spills and inert material such as
appropriate absorbent (sand) can be used for smaller spills. Place excess material and
absorbent materials in appropriate containers. Follow the appropriate disposal guidelines
for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water
ways such as streams or rivers. Should the spill occur on a roadway, contact the
appropriate government or city agencies. The National Response Center can be reached
at 1.800.424.8802.
SECTION 7 HANDLING AND STORAGE
General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any
special handling instructions. We still recommend personal protection just as a good safety
practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we
still recommend using gloves and safety goggles when handling to limit exposure. Handle
in accordance with good industrial hygiene and safety practice. Always replace the lid or
cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination.
Ambient temperatures are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: The level of protection and types of controls necessary will vary depending upon
potential exposure conditions. Control measures to consider: No special requirements
under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions
such as applications, handling practices, concentration and ventilation. Information on
the selection of protective equipment for use with this material, as provided below, is
based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance
with good industrial hygiene practices, precautions should be taken to avoid skin
contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case
of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are
recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Environmental Exposure Controls: Minimize exposure of this material to the environment.
Christensen Arms AO Modification 9/7/23
Product Name: Unilube 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 4 of 6
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold pH Melting Point Freezing Point
Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density
Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
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Product Name: Unilube 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 5 of 6
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused Products:
Disposal must be in accordance with current applicable laws and regulations, and material
characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums should be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of
California to cause cancer, birth defects or other reproductive harm.
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Product Name: Unilube 150 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 6 of 6
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate
and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current
available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages
this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with
and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of
this document, in whole or in part, is not permitted.
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Date Prepared: 3/26/18
Page 1 of 8
SAFETY DATA SHEET Regulation (EC) No 1907/2006 (REACH) and 2015/830
Section 1. Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product Identifier
Product Name: Bovi-Bond Block Adhesive 46130, 46139C, Fast Set, Clear Part A
1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against
Product Use: Adhesive
1.3 Details of the Supplier of the Safety Data Sheet
Supplier: METREX® RESEARCH
28210 Wick Rd
Romulus, MI 48174
U.S.A.
1.4 Emergency Telephone Number
CHEMTREC: 1-703-527-3887 (Outside the US)
Information Phone Number: 1-800-841-1428 (Customer Service) SDS Date of Preparation/Revision: March 26, 2018
Section 2. Hazards Identification
2.1 Classification of the Substance or Mixture
GHS Classification:
Acute Toxicity Category 4 H332
Skin Irritation Category 2 H315
Skin Sensitization Category 1 H317
Eye Irritation Category 2 H319
Respiratory Sensitization Category 1 H334
Specific Target Organ Toxicity – Single Exposure Category 3 H335
Carcinogen Category 2 H351
Specific Target Organ Toxicity – Repeated Exposure Category 2 H373 2.2 Label Elements Danger!
Contains 4,4’-Methylenediphenyl diisocyanate, oligomers, Isocyanic acid, 3-(triethoxysilyl)propyl ester
Hazard Phrases
H315 Causes skin irritation.
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H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory Irritation.
H351 Suspected of causing cancer.
H373 May cause damage to respiratory tract through prolonged or repeated exposure by inhalation.
Prevention:
P260 Do not breathe vapors.
P280 Wear protective gloves. Response:
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P304 + P340 IF INHALED: remove person to fresh air and keep comfortable for breathing.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. 2.3 Other Hazards: This product contains isocyanates. Persons previously sensitized to isocyanates may develop
a cross-sensitization reaction to other isocyanates.
Section 3. Composition/Information On Ingredients
3.2 Mixture
Component CAS No./ EC No. Amount GHS Classification
4,4’-Methylenediphenyl
diisocyanate, oligomers
None/
500-0403
50-80 Acute Tox. 4 H332
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Resp. Sens. 1 H334
Skin Sens. 1B H317
Carc. 2 H351
STOT SE 3 H335
STOT RE 2 H373
Diphenylmethanediisocyanate
prepolymer
68424-09-9 15-40 Not hazardous
3-(Trimethoxysilyl)propyl glycidyl
ether
2530-83-8 /
219-784-2
<5 Eye Dam 1 H318
Isocyanic acid, 3-(triethoxysilyl)propyl ester
24801-88-5 /
246-467-6
<1 Acute Tox. 1 H330
Acute Tox. 4 H302, H312
Skin Corr 1B H314
Skin Sens. 1 H317
Eye Dam 1 H318
Resp. Sens. 1 H334
Section 4. First Aid Measures
4.1 Description of First Aid Measures
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Eyes: Immediately flush eyes with water for 15 minutes while lifting the upper and lower lids. Get medical attention if
irritation persists.
Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. If irritation or rash develop, get
medical attention. Launder clothing before re-use.
Inhalation: Immediately remove to fresh air. If breathing is difficult have qualified personnel administer oxygen. If
breathing has stopped, administer artificial respiration. Get immediate medical attention. Asthma-like symptoms may
develop immediately or delayed up to several hours.
Ingestion: If conscious, rinse mouth with water. Never give anything by mouth to a person who is unconscious or
convulsing. Do not induce vomiting. Get medical attention.
4.2 Most Important symptoms and effects, both acute and delayed: Irritating to eyes, skin and respiratory
system. May cause allergic skin and respiratory reaction. Harmful if inhaled. Symptoms include respiratory
irritation, breathlessness, and chest discomfort and reduced pulmonary function, bronchitis, bronchial spasms and
pulmonary edema. Symptoms may be delayed. Individuals sensitized to isocyanates may have a life-threatening
allergic reaction. Prolonged or repeated exposure may cause damage to the lungs by inhalation. May cause cancer
based on animal data. 4.3 Indication of any immediate medical attention and special treatment needed: If respiratory sensitization
reaction occurs, get immediate medical attention. Symptoms may be delayed for several hours after exposure.
Respiratory sensitization may be life threatening.
Section 5. Firefighting Measures
5.1 Extinguishing Media: Use any extinguishing media that is appropriate for the surrounding fire. Cool fire
exposed containers with water.
5.2 Special Hazards arising from the Substance or Mixture: Combustion may produce carbon and nitrogen
oxides, hydrogen cyanide and other toxic gases.
5.3 Advice for Firefighters: Firefighters should wear positive pressure self-contained breathing apparatus and
full protective clothing for fires in areas where chemicals are used or stored. Do not allow run-off from firefighting to
enter drains or water courses. Decontaminate equipment and protective clothing before reuse.
Section 6: Accidental Release Measures
6.1 Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective
clothing as described in Section 8. Isolate the area and prevent access. Ventilate the area. Evacuate area. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good
industrial hygiene practice. 6.2 Environmental Precautions: Avoid release to the environment. Report spill as required by local and federal
regulations. 6 6.3 Methods and Material for Containment and Cleaning Up: Contain spill. Pour isocyanate decontaminant
solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour
water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the
edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material.
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Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Place in an
approved container for disposal. Do not seal the container for 48 hours to avoid pressure build-up. Clean up
residue with an appropriate solvent. Ventilate the area with fresh air.
6.4 Reference to Other Sections:
Refer to Section 8 for personal protective equipment and Section 13 for disposal information.
Section 7. Handling and Storage
7.1 Precautions for Safe Handling: Do not breathe vapors or mists. Do not get in eyes, on skin, or on clothing. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing
should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before
reuse.
7.2 Conditions for Safe Storage, Including any Incompatibilities: Store in a well-ventilated place. Keep
container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal
container. Store away from acids and strong bases.
7.3 Specific end use(s): Adhesive
Section 8. Exposure Controls/Personal Protection
8.1 Control Parameters:
Chemical Exposure Limit
4,4’-Methylenediphenyl
diisocyanate, oligomers
None Established
Diphenylmethanediisocyanate
prepolymer
None Established
3-(Trimethoxysilyl)propyl glycidyl ether
None Established
Isocyanic acid, 3-(triethoxysilyl)propyl
ester
None Established
8.2 Exposure Controls: Recommended Monitoring Procedures: Contact professional occupational hygienist for monitoring.
Appropriate Engineering Controls: Use with adequate general or local exhaust ventilation to maintain exposures
below the occupational exposure limits. If ventilation is not adequate, use respiratory protection equipment.
Personal Protective Measurers
Respiratory Protection: If the exposure limits are exceeded or if exposure levels are unknown, an approved
positive pressure air supplied respirator with a full facepiece or air supplied hood should be used. Based on the
results of the exposure assessment, a half-face full facepiece air-purifying respirator suitable for organic vapors and particulates should be used with A & P filters. Select in accordance with EU standard EN 140 or EN 136, other applicable
regulations and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus.
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Hand protection: Impervious gloves such as butyl rubber or fluoroelastomer are recommended. Select in
accordance with EU standard EN 374
Eye Protection: Indirect vented goggles are recommended. Select in accordance with EU standard EN 166.
Skin Protection: Wear protective clothing as needed to avoid skin contact.
Other protection: Wash contaminated clothing or dispose of properly. A safety shower and eye wash should be
available in the immediate work area.
Section 9. Physical and Chemical Properties
9.1 Information on Basic Physical and Chemical Properties:
Appearance: Viscous liquid Vapor Pressure:<0 pa @ 20°C
Odor: No detectable odor. Vapor Density:>1 (air = 1)
Odor Threshold: Not available Relative Density /Specific Gravity:1.2
pH: Not applicable Solubility in Water:Negligible
Melting/Freezing
Point:
Not available Partition Coefficient:
(n-octanol/water)
Not applicable
Initial Boiling
Point/Range:
>204.4°C / >399.9°F Auto-ignition Temperature: Not applicable
Flash Point: >143.3°C (>289.94°F)
TCC
Decomposition Temperature: Not applicable
Evaporation Rate: Gels with exposure to
humidity
Viscosity: Not determined
Flammability:
(solid/gas)
Not applicable Explosive Properties: None
Flammable/
Explosive Limits:
Not applicable Oxidizing Properties: None
9.2 Other Information: None
Section 10. Stability and Reactivity
10.1 Reactivity: Reacts with water to form carbon dioxide.
10.2 Chemical Stability: Stable under normal storage and handling conditions. 10.3 Possibility of Hazardous Reactions: Polymerization will occur when exposure to water or moisture.
10.4 Conditions to Avoid: Avoid contamination with moisture. 10.5 Incompatible Materials: Water, strong acids and strong bases. 10.6 Hazardous Decomposition Products: Thermal decomposition will produce oxides of carbon and nitrogen,
hydrogen cyanide and other highly toxic gases.
Section 11. Toxicological Information
11.1 Information on Toxicological Effects:
Potential Health Effects:
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Inhalation: Harmful if inhaled. May cause respiratory irritation with coughing, sneezing, nasal discharge, headache,
hoarseness and nose and throat pain. May cause allergic respiratory reaction with difficulty in breathing, wheezing,
cough and tightness of the chest. Symptoms may be delayed for several hours after exposure. The allergic
respiratory reaction may be life threatening.
Skin Contact: Causes skin irritation with localized redness, swelling, itching, dryness, cracking, blistering, and
pain. May cause allergic skin reaction with redness, swelling, blistering, and itching.
Eye Contact: Causes eye irritation with redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Ingestion: Swallowing may cause gastrointestinal irritation, abdominal pain, nausea, vomiting and diarrhea.
Acute Toxicity Values: No toxicity data is available for the product.
Acute Toxicity Estimate (ATE): Oral: >5,000 mg/kg, Inhalation 1.73 mg/L/4 hr, Dermal: >5,000 mg/kg
4,4’-Methylenediphenyl diisocyanate, oligomers: Oral rat LD50 31,600 mg/kg; Inhalation rat LC50 0.368
mg/L/4 hr; Dermal rabbit LD50 >5,000 mg/kg.
3-(Trimethoxysilyl)propyl glycidyl ether: Oral rat LD50 7,010 mg/kg; Inhalation rat LC50 >5.3 mg/L/4 hr;
Dermal rabbit LD50 4,000 mg/kg.
Isocyanic acid, 3-(triethoxysilyl)propyl ester: Oral rat LD50 706 mg/kg, Inhalation rat LC50 0.36 mg/L/4 hr,
Dermal rabbit 1259 mg/kg
Skin corrosion/irritation: Isocyanates are known to cause skin irritation in studies with laboratory animals. Eye damage/ irritation: Isocyanates are known to cause eye irritation is studies with laboratory animals
Skin Sensitization: Isocyanates are known to cause skin sensitization in studies with laboratory animals. Respiratory Sensitization: Isocyanates are known to cause respiratory sensitization in humans. Animal tests
have indicated that respiratory sensitization can result from skin contact with isocyanates. Germ Cell Mutagenicity: None of the components have been shown to cause gem cell mutagenicity. Carcinogenicity: 4,4’-Methylenediphenyl diisocyanate, oligomers is classified as a “Suspected of causing cancer”
(Carcinogen Category 2) by the EU CLP. Developmental / Reproductive Toxicity: None of the components are classified as reproductive or developmental
toxins.
Specific Target Organ Toxicity (Single Exposure): Isocyanates are known to cause respiratory irritation.
Specific Target Organ Toxicity (Repeated Exposure): Prolonged exposure to isocyanates may cause chronic
irritation, decreased lung function and lung damage and conjunctivitis.
Aspiration Toxicity: None of the components are aspiration hazards.
Section 12. Ecological Information
12.1 Toxicity: No toxicity data available for product
4,4’-Methylenediphenyl diisocyanate, oligomers: 24 hr EC50 daphnia magna >100 mg/L
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3-(Trimethoxysilyl)propyl glycidyl ether: 96 hr LC50 Common Carp 55 mg/L, 48 hr LC50 Crustecea 324
mg/L, 96 hr LC50 green algae 350 mg/L
Isocyanic acid, 3-(triethoxysilyl)propyl ester: 96 hr LC50 zebra fish >934 mg/L, 48 hr EC50 daphnia
magna 331 mg/L, 72 hr EC50 green algae >1,000 mg/L
12.2 Persistence and Degradability: 4,4’-Methylenediphenyl diisocyanate, oligomers is not readily
biodegradable.
12.3 Bioaccumulative Potential: Isocyanates hydrolyze rapidly in aqueous solutions, therefore bioconcentration
is not an important environmental fate process.
12.4 Mobility in Soil: Isocyanates hydrolyze rapidly in aqueous solutions, therefore leaching and adsorption to
moist soil and sediment will not be an important environmental fate process.
12.5 Results of PBT and vPvB assessment: This product is not a PBT and vPvB.
12.6 Other Adverse Effects: None known.
Section 13. Disposal Considerations
13.1 Waste Treatment Methods:
Dispose of contents and container in accordance with all local and national regulations.
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incine polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as
per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations.
Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
Section 14. Transport Information
14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport Hazard Class(es)
14.4 Packing Group
14.5 Environmental Hazards
US DOT Not Regulated
EU ADR/RID Not Regulated
IMDG Not Regulated
IATA/ICAO Not Regulated
14.6 Special Precautions for User: None identified
14.7 Transport in Bulk According to Annex III MARPOL 73/78 and the IBC Code: Not applicable
Section 15. Regulatory Information
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15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture
16. Other Information
GHS Classification for Reference (See Sections 2 and 3):
Acute Tox. 1 Acute Toxicity Category 1
Acute Tox. 4 Acute Toxicity Category 4
Skin Corr 1B Skin Corrosion Category 1B
Skin Irrit. 2 Skin Irritation Category 2 H315
Skin Sens. 1BSkin Sensitization Category 1 H317
Eye Dam 1 Eye Damage Category 1
Eye Irrit. 2 Eye Irritation Category 2
Resp. Sens. 1 Respiratory Sensitization Category 1
Carc. 2 Carcinogen Category 2 H351
STOT SE 3 Specific Target Organ Toxicity – Single Exposure Category 3
STOT RE 2 Specific Target Organ Toxicity – Repeated Exposure Category 2
H302 Harmful if swallowed
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory Irritation.
H351 Suspected of causing cancer.
H373 May cause damage to respiratory tract through prolonged or repeated exposure by inhalation.
Effective Date: March 26, 2018
Supersedes Date: New SDS Revision Summary: New SDS
The information and recommendations set forth herein are taken from sources believed to be accurate
as of the date of preparation, however, METREX® RESEARCH makes no warranty with respect to the
accuracy or suitability of the recommendations, and assumes no liability to any use thereof.
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WATERSHIELD
Page 1 of 2
DESCRIPTION
WATERSHIELD can be considered a UNIVERSAL release. It is a high performance polymer
coating that has been created to give multiple releases while exceeding the most demanding environmental
requirements. WATERSHIELD has no VOC’s and is so versatile it can be used for most molding operations
and is preferred for application directly on warm mold tools. For a totally solvent-free mold release system, use
WATERCLEAN, SEALPROOF and WATERSHIELD. ENVIROSHIELD should be used for high temp
applications when spraying is desired, and when applications for each part are specified.
* ENVIRONMENTALLY SAFE * Thermal Stability
* No solvents or alcohol * High Gloss
* No CFC’s, VOC’s, or ODC’s * High slip/lubricity
* Fast cure * Easy recoat/touch-up
* Non-flammable * Aerospace approved
* No build-up on mold
TYPICAL PROPERTIES
Appearance & Odor : Opaque liquid with bland odor
Carrier : Water
Flash Point [C.C] : None
Coverage : Approximately 1200 Sq. Ft./Gallon
Wt/Gallon : 8.0 lbs/Gallon
Cure Requirement : Ambient or heat
USES
WATERSHIELD is recommended for releasing epoxies, phenolics, polyester resins, polyamides,
polybismaleimides, various rubbers and elastomers. WATERSHIELD is specified for applications where the
use of flammable products or solvent based materials are not desired.
SURFACE PREPARATION
Before applying WATERSHIELD, all previous waxes or oils should be removed using
WATERCLEAN, and then a suitable mold sealer should be applied. If surfaces have been coated with a semi-
permanent release agent, it may be possible to simply solvent wipe, dry, and apply WATERSHIELD. A test
patch should be done to confirm this possibility.
MOLD CLEANING
WATERCLEAN has been developed to replace solvent-based cleaning solutions. WATERCLEAN
is a stand-alone product that can be used to clean and prepare molds and/or parts when further processing is
needed. WATERCLEAN provides an effective alternative for the removal of surface contaminants without
harming the working surface of the mold and/or part. WATERCLEAN is RECOMMENDED FOR MOLD
PREPARATION BEFORE APPLICATION OF AN APPROPRIATE MOLD SEALER.
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MOLD SEALING
For wood, gel coat, steel, carbon-graphite, fiberglass, polyester, epoxy, urethane, and aluminum use
SEALPROOF for a durable, highly visible, penetrating film with superior adhesion and especially with poor or
porous surfaces. Additional water based Zyvax sealers would be SEALMATTE (non-glossy surface) and
SEALBRITE (high gloss surface).
HOW TO APPLY WATERSHIELD
1. Apply one light coat of WATERSHIELD to a small area of the mold using a Bounty® paper
towel, or hand sprayer.
2. Wait approximately 2 minutes, and then lightly wipe over the mold surface using a separate clean
Bounty® paper towel.
3. Wait 15 minutes and apply the second coat of WATERSHIELD.
4. Wait approximately 2 minutes, and then lightly wipe over the mold surface using a separate clean
Bounty® paper towel.
5. Allow a set time of 30 minutes before using mold. If application has been made to a warm surface,
a shorter waiting period is needed. The use of heat (hot air, heat gun, oven) can enhance
performance.
6. For touch up apply a single coat of WATERSHIELD as above and continue processing.
STORAGE & SHELF LIFE Store product between 5°C and 30°C (41°F and 86°F). Shelf life is 18 months
from the date of manufacture, in the original unopened container.
USE LIFE Use life of product is 60 days from opening of container. Product must be kept in the original
container and the lid replaced immediately after dispensing. After opening, product should continue to be stored
properly. Maximum product life is not to exceed 18 months from Date of Manufacture.
WARNING Never puncture any Zyvax product container.
SAFETY DATA
Material safety data sheets are available for all ZYVAX products and should be consulted prior to use
of product.
SHIPPING DATA
DOT SHIPPING NAME: None
DOT HAZARD CLASSIFICATION: None
DOT I.D. NUMBER: None
PACKAGING
WATERSHIELD is available in the following sizes:
1-U.S. gallon can
5-U.S. gallon pail
55-U.S. gallon pail
LIMITATIONS OF LIABILITY
To the best of our knowledge, the technical data contained herein are true and accurate at the date of issuance, and are subject to change without prior notice.
User must contact ZYVAX to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to
conform to ZYVAX quality control. We assume no responsibility for coverage, performance, or injuries resulting from its use. Liability, if any, is limited to
replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY ZYVAX, EXPRESSED OR IMPLIED, STATUTORY,
BY OPERATION OF LAW OR OTHERWISE, INCLUDING FITNESS FOR A PARTICULAR PURPOSE.
REV. 1/99
Zyvax Inc WaterShield Application Data Sheet - Issue 5
(706) 698-4405 Phone (706) 635-8103 Fax December 2007 Page 2 of 2
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Zyvax® WaterShield™
+1 517 546 4520
SAFETY DATA SHEET
Product name
Emergency telephone
number and Telephone
number
Section 1. Identification
:
:
Supplier's details :Chem-Trend LP
1445 W McPherson Park Dr
PO Box 860, Howell MI 48844-0860
517-546-4520
Zyvax® WaterShield™
Relevant identified uses of the substance or mixture and uses advised against
Release Agent
Section 2. Hazards identification
Not classified.Classification of the
substance or mixture
:
Signal word :No signal word.
Hazard statements :No known significant effects or critical hazards.
Precautionary statements
Prevention :Not applicable.
Response :Not applicable.
Storage :Not applicable.
Disposal :Not applicable.
GHS label elements
OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
Surfactant ≤3 -
Ingredient name CAS number%
Substance/mixture :Mixture
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Zyvax® WaterShield™
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or
confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with
non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for
disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use.
:
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
Section 8. Exposure controls/personal protection
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Control parameters
Occupational exposure limits
None.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative densityVapor density
Solubility
Liquid. [Hazy liquid.]
Not available.
1Not available.
Not available.
Insoluble in the following
materials: cold water.
Characteristic.Odor
pH
White.Color
Evaporation rate Not available.
Auto-ignition
temperature
Flash point
Not available.
Closed cup: Not applicable.
[Water-based product]
Not available.
9 to 10.7
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
Boiling point 100°C (212°F)
Flammability (solid,
gas)
Not available.
Lower and upper
explosive (flammable)
limits
Not available.
Burning rate Not applicable.Burning time Not applicable.
Decomposition
temperature
Not available.
Solubility in water Not available.
Volatility 92.089
SADT Not available.
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Section 9. Physical and chemical properties
None identified.
Lower and upper explosive (flammable) limits
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Formaldehyde and silicon dioxide may be evolved at elevated temperatures.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Information on toxicological effects
:Not available.
Potential acute health effects
Irritation/Corrosion :No known significant effects or critical hazards.
Sensitization :No known significant effects or critical hazards.
Mutagenicity :No known significant effects or critical hazards.
Carcinogenicity :No known significant effects or critical hazards.
Reproductive toxicity :No known significant effects or critical hazards.
Teratogenicity :No known significant effects or critical hazards.
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Section 11. Toxicological information
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
IngestionInhalation
No specific data.No specific data.
No specific data.
Eye contact
No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
No known significant effects or critical hazards.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
RCRA classification :Not applicable
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Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Environmental
hazards
No.
TDG
Classification
Not regulated.
-
-
-
-
-
-
-
No.
Not regulated.Not regulated.
Not regulated
-
-
No.
Bulk
No.No.
-
-
Additional information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
-
DOT Classification
TDG Classification
IMDG
IATA
:
:
:
:
Section 15. Regulatory information
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
Not applicable.
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
Inventory list
Australia :All components are listed or exempted.
All components are listed or exempted.:Canada
China :All components are listed or exempted.
Europe :
Japan :Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): All components are listed or exempted.
Republic of Korea :All components are listed or exempted.
New Zealand :All components are listed or exempted.
Philippines :All components are listed or exempted.
Taiwan :All components are listed or exempted.
United States :All components are listed or exempted.
Contact local supplier or distributor.
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Section 15. Regulatory information
State regulations
Massachusetts
New York
New Jersey
Pennsylvania
:
:
:
:
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
SARA 311/312
Classification :Not applicable.
Section 16. Other information
History
Date of issue/Date of
revision
Version
Prepared by
Information presented herein has been compiled from information provided to us by our suppliers and other
sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is
not guaranteed to be so. Nothing herein is to be construed as recommending any practice or the use of any
product in violation of any patent or in violation of any law or regulation. It is the users' responsibility to
determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be
necessary. We make no warranty as to the results to be obtained in using any material and, since conditions of
use are not under our control, we must necessarily disclaim all liability with respect to the use of any material
supplied by us.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
10/30/2018
4/20/2018
4
Hazardous Material Information System (U.S.A.)
0 0 0
001
National Fire Protection Association (U.S.A.)
Special :Instability/Reactivity :Flammability :
Health :Flammability :Physical hazards :Personal protection Code :B
Health :
Chem-Trend Regulatory Affairs Department.
-
/
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name : FiberTack MT-1, Fibertack MT-1 BLU
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Adhesive
1.3. Details of the supplier of the safety data sheet
Engineered Bonding Solutions, LLC
801 Marina Road
Titusville, FL 32796
T 321-747-0160
1.4. Emergency telephone number
Emergency number : Chemtrec 1 800 424 9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (GHS-US)
Flam. Liq. 2 H225
Eye Irrit. 2A H319
STOT SE 3 H336
WHMIS Classification
Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US)
:
GHS02 GHS07
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
Christensen Arms AO Modification 9/7/23
Precautionary statements (GHS-US) : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233
- Keep container tightly closed
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical/ventilating/lighting equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264
- Wash thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P312 - Call a POISON CENTER/doctor/physician if you feel unwell
P337+P313 - If eye irritation persists: Get medical advice/attention
P370+P378 - In case of fire: Use Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog for
extinction
P403+P233 - Store in a well-ventilated place. Keep container tightly closed
P403+P235 - Store in a well-ventilated place. Keep cool P405
- Store locked up
P501 - Dispose of contents/container in accordance with local/regional/national/international
regulations.
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Acetone (CAS No) 67-64-1 40 - 50 Flam. Liq. 2, H225
Proprietary Polymer 1 (CAS No) Trade Secret 20 - 35 Not classified
Cyclohexanone (CAS No) 108-94-1 10 - 20 Flam. Liq. 3, H226
Acute Tox. 4 (Oral), H302
Acute Tox. 3 (Dermal), H311
Proprietary Polymer 2 (CAS No) Trade Secret 10 - 15 Not classified
Acetone (67-64-1)
WHMIS Classification Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Cyclohexanone (108-94-1)
WHMIS Classification Class B Division 3 - Combustible Liquid
Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures after inhalation : Move person to fresh air.If breathing is difficult, administer oxygen. If breathing has stopped give
artificial respiration and get medical attention.
First-aid measures after skin contact : Wash thoroughly with soap and water. Remove contaminated clothing.
Christensen Arms AO Modification 9/7/23
First-aid measures after eye contact : Flush with large quantities of water for 15 minutes.
First-aid measures after ingestion :
Do not induce vomiting, can cause chemical pneumonitis and pulmonary edema. Contact a
Physician immediately. If any symptoms persist get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Excessive inhalation of vapors can cause nasal and respiratory irratation, dizziness, weakness,
fatigue, nausea, headache and possible unconsciousness.
Symptoms/injuries after skin contact : Can dry and defat skin causing cracks, irritation and dermatitis.
Symptoms/injuries after eye contact : Severe irritation, redness, tearing and blurred vision.
Symptoms/injuries after ingestion :
Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into the
lungs can cause chemical pneumonitis.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog Unsuitable extinguishing media :
None
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapor.
Explosion hazard
: Pressure build up and possible auto-ignition or explosion may occur when exposed to extreme
heat.
5.3. Advice for firefighters
Firefighting instructions : During emergency conditions, overexposure to decomposition products may cause a health
hazard. Symptoms may not be immediately apparent.
Protection during firefighting : Firefighters should wear full protective gear.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
No additional information available
6.1.2. For emergency responders
No additional information available
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment : Stop the flow of material, if this is without risk.
Methods for cleaning up : Eliminate ignition sources, provide good ventilation, dike spill area and cover with inert,
absorbent material and remove to disposal container.
6.4. Reference to other sections
No additional information available
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Use in well ventilated areas. Keep containers closed when not in use.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep away from excessive heat and open flames.
7.3. Specific end use(s)
Adhesive
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Christensen Arms AO Modification 9/7/23
Acetone (67-64-1)
ACGIH ACGIH TWA (ppm) 500 ppm
ACGIH ACGIH STEL (ppm) 750 ppm
OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³
OSHA OSHA PEL (TWA) (ppm) 1000 ppm
IDLH US IDLH (ppm) 2500 ppm (10% LEL)
NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³
NIOSH NIOSH REL (TWA) (ppm) 250 ppm
Alberta OEL STEL (mg/m³) 1800 mg/m³
Alberta OEL STEL (ppm) 750 ppm
Alberta OEL TWA (mg/m³) 1200 mg/m³
Alberta OEL TWA (ppm) 500 ppm
British Columbia OEL STEL (ppm) 500 ppm
British Columbia OEL TWA (ppm) 250 ppm
Manitoba OEL STEL (ppm) 750 ppm
Manitoba OEL TWA (ppm) 500 ppm
New Brunswick OEL STEL (mg/m³) 1782 mg/m³
New Brunswick OEL STEL (ppm) 750 ppm
New Brunswick OEL TWA (mg/m³) 1188 mg/m³
New Brunswick OEL TWA (ppm) 500 ppm
New Foundland & Labrador OEL STEL (ppm) 750 ppm
New Foundland & Labrador OEL TWA (ppm) 500 ppm
Nova Scotia OEL STEL (ppm) 750 ppm
Nova Scotia OEL TWA (ppm) 500 ppm
Nunavut OEL STEL (mg/m³) 2970 mg/m³
Nunavut OEL STEL (ppm) 1250 ppm
Nunavut OEL TWA (mg/m³) 2370 mg/m³
Nunavut OEL TWA (ppm) 1000 ppm
Northwest Territories OEL STEL (mg/m³) 2970 mg/m³
Northwest Territories OEL STEL (ppm) 1250 ppm
Northwest Territories OEL TWA (mg/m³) 2370 mg/m³
Acetone (67-64-1)
Northwest Territories OEL TWA (ppm) 1000 ppm
Ontario OEL STEL (ppm) 750 ppm
Ontario OEL TWA (ppm) 500 ppm
Prince Edward Island OEL STEL (ppm) 750 ppm
Prince Edward Island OEL TWA (ppm) 500 ppm
Québec VECD (mg/m³) 2380 mg/m³
Québec VECD (ppm) 1000 ppm
Québec VEMP (mg/m³) 1190 mg/m³
Québec VEMP (ppm) 500 ppm
Saskatchewan OEL STEL (ppm) 750 ppm
Saskatchewan OEL TWA (ppm) 500 ppm
Christensen Arms AO Modification 9/7/23
Yukon OEL STEL (mg/m³) 3000 mg/m³
Yukon OEL STEL (ppm) 1250 ppm
Yukon OEL TWA (mg/m³) 2400 mg/m³
Yukon OEL TWA (ppm) 1000 ppm
Cyclohexanone (108-94-1)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 50 ppm
OSHA OSHA PEL (TWA) (mg/m³) 200 mg/m³
OSHA OSHA PEL (TWA) (ppm) 50 ppm
IDLH US IDLH (ppm) 700 ppm
NIOSH NIOSH REL (TWA) (mg/m³) 100 mg/m³
NIOSH NIOSH REL (TWA) (ppm) 25 ppm
Alberta OEL STEL (mg/m³) 200 mg/m³
Alberta OEL STEL (ppm) 50 ppm
Alberta OEL TWA (mg/m³) 80 mg/m³
Alberta OEL TWA (ppm) 20 ppm
British Columbia OEL STEL (ppm) 50 ppm
British Columbia OEL TWA (ppm) 20 ppm
Manitoba OEL STEL (ppm) 50 ppm
Manitoba OEL TWA (ppm) 20 ppm
New Brunswick OEL TWA (mg/m³) 100 mg/m³
New Brunswick OEL TWA (ppm) 25 ppm
New Foundland & Labrador OEL STEL (ppm) 50 ppm
New Foundland & Labrador OEL TWA (ppm) 20 ppm
Nova Scotia OEL STEL (ppm) 50 ppm
Nova Scotia OEL TWA (ppm) 20 ppm
Nunavut OEL STEL (mg/m³) 400 mg/m³
Nunavut OEL STEL (ppm) 100 ppm
Nunavut OEL TWA (mg/m³) 100 mg/m³
Nunavut OEL TWA (ppm) 25 ppm
Northwest Territories OEL STEL (mg/m³) 400 mg/m³
Northwest Territories OEL STEL (ppm) 100 ppm
Northwest Territories OEL TWA (mg/m³) 100 mg/m³
Northwest Territories OEL TWA (ppm) 25 ppm
Ontario OEL STEL (ppm) 50 ppm
Ontario OEL TWA (ppm) 20 ppm
Prince Edward Island OEL STEL (ppm) 50 ppm
Prince Edward Island OEL TWA (ppm) 20 ppm
Cyclohexanone (108-94-1)
Québec VEMP (mg/m³) 100 mg/m³
Québec VEMP (ppm) 25 ppm
Saskatchewan OEL STEL (ppm) 50 ppm
Saskatchewan OEL TWA (ppm) 20 ppm
Yukon OEL STEL (mg/m³) 200 mg/m³
Christensen Arms AO Modification 9/7/23
Yukon OEL STEL (ppm) 50 ppm
Yukon OEL TWA (mg/m³) 200 mg/m³
Yukon OEL TWA (ppm) 50 ppm
8.2. Exposure controls
Appropriate engineering controls : Local exhaust and general ventilation must be adequate to meet exposure standards.
Hand protection : Wear resistant gloves such as nitrile rubber.
Eye protection : Use chemical safety glasses, goggles or faceshields for eye protection.
Skin and body protection : Wear suitable working clothes.
Respiratory protection : If airborne concentrations are above the applicable exposure limits, use NIOSH approved
respiratory protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Colorless to pale yellow or blue
Odor : Solvent
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 131°F (55°C)
Flash point : -2°F (-19°C) TCC
Self ignition temperature : 788°F (420°C)
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 175 mm Hg
Relative vapor density at 20 °C : No data available
Relative density : 7.54 lb/gal (0.90g/cc)
Solubility : 22% in water at 20°C
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits
: 1.8 - 10.0 vol %
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
The product is stable at normal handling and storage conditions.
10.3. Possibility of hazardous reactions
Christensen Arms AO Modification 9/7/23
Will not occur.
10.4. Conditions to avoid
Excessive heat, ignition sources, poor ventilation, corrosive atmospheres, excessive aging.
10.5. Incompatible materials
Strong oxidizers, strong acids, and strong bases, alkaline materials, amines.
10.6. Hazardous decomposition products
Carbon dioxide, carbon monoxide, various hydrocarbons.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
Acetone (67-64-1)
LC50 inhalation rat (mg/l) 50100 mg/m³ (Exposure time: 8 h)
Cyclohexanone (108-94-1)
LD50 oral rat 800 mg/kg
LD50 dermal rabbit 948 mg/kg
LC50 inhalation rat (ppm) 8000 ppm/4h
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Cyclohexanone (108-94-1)
IARC group 3
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness.
Specific target organ toxicity (repeated : Not classified exposure)
Aspiration hazard : Not classified
SECTION 12: Ecological information
12.1. Toxicity
Acetone (67-64-1)
LC50 fish 1 4.74 - 6.33 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
EC50 Daphnia 1 10294 - 17704 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC50 fish 2 6210 - 8120 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Daphnia 2 12600 - 12700 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Cyclohexanone (108-94-1)
Christensen Arms AO Modification 9/7/23
LC50 fish 1 481 - 578 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
LC50 fish 2 8.9 mg/l (Exposure time: 96 h - Species: Pimephales promelas)
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Acetone (67-64-1)
BCF fish 1 0.69
Log Pow -0.24
Cyclohexanone (108-94-1)
BCF fish 1 (will not bioconcentrate)
Log Pow 0.86 (at 25 °C)
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
No additional information available SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations.
SECTION 14: Transport information
In accordance with TDG
Transport document description : UN1133 Adhesives containing a flammable liquid, 3, II
UN-No.(DOT) : 1133
DOT NA no. : UN1133
DOT Proper Shipping Name : Adhesives containing a
flammable liquid
Department of Transportation (DOT) Hazard
: Classes
3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : II - Medium Danger
Christensen Arms AO Modification 9/7/23
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net capacity
specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5 L (1.3
gallons).
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks. IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail :
(49 CFR 173.27)
5 L
DOT Quantity Limitations Cargo aircraft only (49 :
CFR 175.75)
60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Other information :
No supplementary information available.
SECTION 15: Regulatory information
CANADA
FiberTack MT-1
WHMIS Classification Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Proprietary Polymer 1 (Trade Secret)
Listed on the Canadian DSL (Domestic Substances List) inventory.
Acetone (67-64-1)
Listed on the Canadian DSL (Domestic Substances List) inventory.
WHMIS Classification Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Cyclohexanone (108-94-1)
Listed on the Canadian DSL (Domestic Substances List) inventory.
WHMIS Classification Class B Division 3 - Combustible Liquid
Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
15.2. International regulations
Proprietary Polymer 1 (Trade Secret)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Acetone (67-64-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Christensen Arms AO Modification 9/7/23
Cyclohexanone (108-94-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2.2. National regulations
Acetone (67-64-1)
Listed on the Canadian Ingredient Disclosure List
Cyclohexanone (108-94-1)
Listed on the Canadian Ingredient Disclosure List
SECTION 16: Other information
Full text of H-phrases:
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VERSION 1.2 Revision Date 06/06/16 Print Date: 6/16/16
This version replaces all previous versions
Previous Issue Date: 04/20/16
The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no other warranty, express or implied, as to its
correctness or completeness, or as to the results of the reliance on this document. This product is intended for skilled users at their own risk.
Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3
Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapor
H226 Flammable liquid and vapor
H302 Harmful if swallowed
H311 Toxic in contact with skin
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
Christensen Arms AO Modification 9/7/23
SAFETY DATA SHEET
Revision date 12-Jun-2017 Version 5 Supersedes Date:12-Jun-2017
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product identifier Product Code FS-5165.G01
Product Name 4.4 XTREME FLAT FINISH KLEAR K
Other means of identification
No information available
Recommended use of the chemical and restrictions on use
Paint, Coatings
Details of the supplier of the safety data sheet
See section 16 for more
information
5 STAR XTREME
a division of IAMG/International Autobody Marketing Group
1505 N. Hayden Road
Suite 111
Scottsdale, AZ 85257
www.5StarXtreme.com
1-87REFINISH
E-mail address No information available
Emergency telephone number
United States of America Chemtrec: 800-424-9300
American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands Chemtrec: 800-424-9300
Section 2: HAZARDS IDENTIFICATION
Classification
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Carcinogenicity Category 1B
Reproductive toxicity Category 2
Specific target organ toxicity (single exposure)Category 3
Specific target organ toxicity (repeated exposure)Category 2
Aspiration toxicity Category 1
Label elements
Product Code FS-5165.G01 Page 1 / 10 AGHS - USA OSHA SDS
Flammable liquids Category 2
Christensen Arms AO Modification 9/7/23
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No weight-%
Acetone 67-64-1 25 - 50
n-Butyl acetate 123-86-4 10 - 25
Signal word DANGER
HAZARD STATEMENTS
Highly flammable liquid and vapor
Causes skin irritation
Causes serious eye irritation
May cause cancer
Suspected of damaging fertility or the unborn child
May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure
May be fatal if swallowed and enters airways
PREVENTION
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective
gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not
breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. P210 - Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use
explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static
discharge.
RESPONSE
IF exposed or concerned: Get medical advice/attention.Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.Skin
If skin irritation occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower. Wash contaminated clothing before reuse.
Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing.Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction.
STORAGE
Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
DISPOSAL
Dispose of contents/containers in accordance with local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)
No information available.
OTHER HAZARDS
Not applicable.
Product Code FS-5165.G01 Page 2 / 10 AGHS - USA OSHA SDS
UNKNOWN ACUTE TOXICITY .0001% of the mixture consists of ingredient(s) of unknown toxicity.
Christensen Arms AO Modification 9/7/23
Xylenes 1330-20-7 10 - 25
Ethylbenzene 100-41-4 1 - 3
1-Butanol 71-36-3 1 - 3
Styrene 100-42-5 0.1 - 0.3
Toluene 108-88-3 0.1 - 0.3
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Section 4: FIRST AID MEASURES
First Aid Measures
General adviceIF exposed or concerned: Get medical advice/attention.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
If skin irritation occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower. Wash contaminated clothing before reuse.
Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Dry chemical, CO2, water spray or alcohol-resistant foam.
Not to be used for safety reasons: Strong water jet
Specific hazards arising from the chemical
Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe
fumes.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is
out. Do not allow run-off from fire-fighting to enter drains or water courses.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Product Code FS-5165.G01
Personal precautions
Avoid breathing vapors or mists. Remove all sources of ignition. Use personal protective equipment as required. Avoid contact with
skin, eyes or clothing. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Take precautionary
measures against static discharges.
Page 3 / 10 AGHS - USA OSHA SDS
For emergency responders
Use personal protection recommended in Section 8.
Christensen Arms AO Modification 9/7/23
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations. Prevent further leakage or spillage if safe to do so. Local authorities
should be advised if significant spillages cannot be contained.
Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so.
Methods for cleaning up
Dispose of waste product or used containers according to local regulations. Clean with detergents. Avoid solvent cleaners. Dam
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to
properly labeled containers. Clean contaminated surface thoroughly.
Section 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handlingPrevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the
occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Use personal protection recommended in Section 8. Never use pressure to empty container. Comply with the health and safety at
work laws. Prevent product from entering drains. Vapors are heavier than air and may spread along floors. Vapors may form
explosive mixtures with air. Use only with adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in
well-ventilated areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All
equipment used when handling the product must be grounded.
General Hygiene Considerations
When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Avoid contact with skin, eyes or clothing.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed in a dry and
well-ventilated place. Keep tightly closed in a dry and cool place.
Incompatible materials
Strong bases. Strong oxidizing agents.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits
If S* appears in the OEL table, it indicates this chemical contains a skin notation.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Acetone
67-64-1
STEL: 500 ppm
TWA: 250 ppm
TWA: 1000 ppm
TWA: 2400 mg/m3
IDLH: 2500 ppm
TWA: 250 ppm
TWA: 590 mg/m3
n-Butyl acetate
123-86-4
STEL: 200 ppm
TWA: 150 ppm
TWA: 150 ppm
TWA: 710 mg/m3
IDLH: 1700 ppm
TWA: 150 ppm
TWA: 710 mg/m3
STEL: 200 ppm
STEL: 950 mg/m3
Product Code FS-5165.G01
Xylenes
1330-20-7
Page 4 / 10
STEL: 150 ppm
TWA: 100 ppm
AGHS - USA OSHA SDS
TWA: 100 ppm
TWA: 435 mg/m3
Christensen Arms AO Modification 9/7/23
Ethylbenzene
100-41-4
TWA: 20 ppm TWA: 100 ppm
TWA: 435 mg/m3
IDLH: 800 ppm
TWA: 100 ppm
TWA: 435 mg/m3
STEL: 125 ppm
STEL: 545 mg/m3
1-Butanol 71-36-3 TWA: 20 ppm TWA: 100 ppmTWA: 300 mg/m3
IDLH: 1400 ppmCeiling: 50 ppm
Ceiling: 150 mg/m3
Styrene
100-42-5
STEL: 40 ppm
TWA: 20 ppm
TWA: 100 ppm
Ceiling: 200 ppm
IDLH: 700 ppm
TWA: 50 ppm
TWA: 215 mg/m3
STEL: 100 ppm
STEL: 425 mg/m3
Toluene
108-88-3
TWA: 20 ppm TWA: 200 ppm
Ceiling: 300 ppm
IDLH: 500 ppm
TWA: 100 ppm
TWA: 375 mg/m3
STEL: 150 ppm
STEL: 560 mg/m3
Appropriate engineering controls
Engineering Controls
Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin and body protection
Wear suitable protective clothing. Personnel should wear anti-static clothing made of natural fiber or of high temperature
resistant synthetic fiber.
Hand Protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of
chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on
breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance
or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Wear protective gloves.
Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Thermal Protection
No information available
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state liquid
Appearance No information availableOdorSolventColorcolorless
Odor Threshold No information availablepH value No information availableMelting point/freezing point No information available
Boiling point / boiling range 56.05 °C / 133 °Fflash point -20 °C / -4 °F
evaporation rate No information available
Flammability (solid, gas)No information availableFlammability Limit in Air
Upper flammability limit:
Product Code FS-5165.G01
No information available
Page 5 / 10 AGHS - USA OSHA SDS
Lower flammability limit:No information available
Christensen Arms AO Modification 9/7/23
Vapor Pressure No information available
vapor density No information availableDensity (lbs per US gallon)7.74specific gravity .93
Solubility(ies)No information availablePartition coefficient No information availableAutoignition temperature No information available
Decomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information available
Other information
Section 10: STABILITY AND REACTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Strong bases. Strong oxidizing agents.
Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Chlorine gas.
Section 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Eye contact
Causes serious eye irritationSkin ContactCauses skin irritationIngestion
May be fatal if swallowed and enters airways
Inhalation
May cause drowsiness or dizziness
Numerical measures of toxicity - Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Acetone
67-64-1
= 5800 mg/kg ( Rat )-= 50100 mg/m3 ( Rat ) 8 h
n-Butyl acetate
123-86-4
= 10768 mg/kg ( Rat ) > 17600 mg/kg ( Rabbit ) = 390 ppm ( Rat ) 4 h
Xylenes
1330-20-7
= 3500 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) > 4350
mg/kg ( Rabbit )
= 29.08 mg/L ( Rat ) 4 h = 5000
ppm ( Rat ) 4 h
Ethylbenzene
100-41-4
= 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.2 mg/L ( Rat ) 4 h
1-Butanol
71-36-3
= 700 mg/kg ( Rat ) = 790 mg/kg (
Rat )
= 3402 mg/kg ( Rabbit ) = 3400
mg/kg ( Rabbit )
> 8000 ppm ( Rat ) 4 h
Styrene
100-42-5
= 1000 mg/kg ( Rat ) - = 11.7 mg/L ( Rat ) 4 h
Toluene
108-88-3
= 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h
Numerical measures of toxicity - Product Information
Product Code FS-5165.G01
The following values are calculated based on chapter 3.1 of the GHS document .
Page 6 / 10 AGHS - USA OSHA SDS
ATEmix (oral)21088 Mg/kg
Christensen Arms AO Modification 9/7/23
ATEmix (dermal)8394 Mg/kg
ATEmix (inhalation-dust/mist)9.3 mg/lATEmix (inhalation-vapor)69 mg/l
UNKNOWN ACUTE TOXICITY .0001% of the mixture consists of ingredient(s) of unknown toxicity.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chemical Name ACGIH IARC NTP OSHA
Ethylbenzene
100-41-4
A3 Group 2B X
Styrene
100-42-5
Group 2B Reasonably Anticipated X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen.IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans.NTP (National Toxicology Program)Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen.OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present.
Skin corrosion/irritation Causes skin irritation
Serious eye damage/eye irritation Causes serious eye irritationSkin sensitization Not applicableRespiratory sensitization Not applicable
Germ cell mutagenicity Not applicableCarcinogenicityMay cause cancerReproductive Toxicity Suspected of damaging fertility or the unborn child
Specific target organ toxicity (singleexposure)May cause drowsiness or dizziness
Specific target organ toxicity(repeated exposure)
May cause damage to organs through prolonged or repeated exposure
Aspiration hazard Not applicable
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Environmental precautions Prevent product from entering drains.
Persistence and degradability
No information available
Bioaccumulation
No information available
Mobility
No information available
Other adverse effects No information available
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Product Code FS-5165.G01
Contaminated packaging
Page 7 / 10
Improper disposal or reuse of this container may be dangerous and illegal. Empty
containers must be scrapped or reconditioned.
AGHS - USA OSHA SDS
Section 14: TRANSPORT INFORMATION
Christensen Arms AO Modification 9/7/23
14.5 Environmental hazard Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
The supplier may apply one of the following exceptions: Combustible Liquid (49 CFR 173.150(f)); Consumer Commodity (49 CFR 173.150(c),
ICAO/IATA SP A112); Limited Quantity (49 CFR 173.150(b), ICAO Part 3 Chapter 4, IATA 2.7, IMDG Chapter 3.4); Viscous Liquid (49 CFR
173.121(b), IMDG 2.3.2.2, IATA 3.3.3.1.1, ICAO 3.2.2, ADR 2.2.3.1.5); Does Not Sustain Combustion (49 CFR 173.120(a), IATA 3.3.1.3, ICAO
3.1.3, IMDG 2.3.1.3, ADR 2.2.3.1.1 Note 1); or others as allowed under hazardous materials/dangerous goods regulations.
Section 15: REGULATORY INFORMATION
International Inventories TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt
from listing.DSL - Canadian Domestic Substances List All components are listed or exempt
from listing
US Federal Regulations
Chemical Name SARA 313 - Threshold Values%Metals Hazardous air pollutants(HAPs) content
Xylenes
1330-20-7
10 - 25
1 Present
Ethylbenzene
100-41-4
1 - 3
0.1 Present
1-Butanol
71-36-3
1 - 3
1
Styrene
100-42-5
0.1 - 0.3
0.1 Present
Toluene
108-88-3
0.1 - 0.3
1 Present
SARA 311/312 Hazard Categories Acute health hazard YesChronic Health Hazard Yes
Fire hazard YesSudden release of pressure hazard NoReactive Hazard No
Chemical Name CWA - ReportableQuantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances
n-Butyl acetate
123-86-4
5000 lb X
Xylenes 1330-20-7 100 lb X
Ethylbenzene
100-41-4
1000 lb X X X
Styrene
100-42-5
1000 lb X
DOT IMDG IATA14.1 UN/ID no UN1263 UN1263 UN126314.2 Proper shipping name Paint Paint Paint
14.3 Hazard Class 33314.4 Packing Group II II II
14.6 Special Provisions A3, A72, A192
Product Code FS-5165.G01
149, B52, IB2, T4, TP1, TP8, TP28,367
Page 8 / 10
Emergency Response GuideNumber
128
AGHS - USA OSHA SDS
163, 367EmS-No
F-E, S-E
Christensen Arms AO Modification 9/7/23
Toluene
108-88-3
1000 lb X X X
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
Acetone
67-64-1
5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
n-Butyl acetate
123-86-4
5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
Xylenes 1330-20-7 100 lb RQ 100 lb final RQRQ 45.4 kg final RQ
Ethylbenzene
100-41-4
1000 lb RQ 1000 lb final RQ
RQ 454 kg final RQ
1-Butanol
71-36-3
5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
Styrene
100-42-5
1000 lb RQ 1000 lb final RQ
RQ 454 kg final RQ
Toluene
108-88-3
1000 lb RQ 1000 lb final RQ
RQ 454 kg final RQ
US State Regulations
Rule 66 status of product
Photochemically reactive.
California Proposition 65
WARNING! This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or
other reproductive harm.
U.S. EPA Label informationEPA Pesticide registration number Not applicable
U.S. State Right-to-Know Regulations
Chemical Name
Acetone
67-64-1
.
n-Butyl acetate
123-86-4
.
Proprietary Non-Hazardous Ingredient - Proprietary CAS .
Xylenes
1330-20-7
.
Proprietary Non-Hazardous Ingredient - Proprietary CAS .
Proprietary Inert .
Ethylbenzene
100-41-4
.
1-Butanol
71-36-3
.
Styrene
100-42-5
.
Toluene
108-88-3
.
Section 16: OTHER INFORMATION
HMISHealth hazards 3*
* = Chronic Health Hazard
Flammability 3
Product Code FS-5165.G01
Physical hazards
Page 9 / 10
0
AGHS - USA OSHA SDS
Personal Protection X
Christensen Arms AO Modification 9/7/23
Prepared By Regulatory Department
Revision date 12-Jun-2017Revision Note No information available
DisclaimerThe information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current nationallegislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge andcontrol the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDSshould not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS
SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, ANDDISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR APARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES.
Product Code FS-5165.G01 Page 10 / 10
End of Safety Data Sheet
AGHS - USA OSHA SDS
Christensen Arms AO Modification 9/7/23
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Revision date: 12/2/2019 Revision: 10 Supersedes date: 6/10/2019
SAFETY DATA SHEET
No. 9 Gun Bore Cleaner
According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200
1. Identification
Product identifier
Product name No. 9 Gun Bore Cleaner
Product number 902, 902CN, 902RH, 904, 904CN, 904P, 916, 916CN, 932, 9501
Recommended use of the chemical and restrictions on use
Application Remove leading and metal fouling from gun bores.
Uses advised against No specific uses advised against are identified.
Details of the supplier of the safety data sheet
Manufacturer Bushnell Holdings Inc
9200 Cody
Overland Park, KS 66214
1-800-423-3537
dangerous.goods@vistaoutdoor.com
Emergency telephone number
Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation
Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) -
(CHEMTREC, Day and Night)
2. Hazard(s) identification
Classification of the substance or mixture
Physical hazards Flam. Liq. 2 - H225
Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2A
- H319 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335, H336 Asp. Tox. 1 - H304
Environmental hazards Aquatic Acute 3 - H402 Aquatic Chronic 2 - H411
Label elements
Pictogram
Signal word Danger
Hazard statements H225 Highly flammable liquid and vapor.
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H402 Harmful to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
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No. 9 Gun Bore Cleaner
Precautionary statements P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, sparks, open flames and hot surfaces. No smoking.
P240 Ground/ bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing vapor/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P310 If swallowed: Immediately call a poison center/ doctor.
P301+P312 If swallowed: Call a poison center/ doctor if you feel unwell.
P302+P352 If on skin: Wash with plenty of water.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308+P313 If exposed or concerned: Get medical advice/ attention.
P321 Specific treatment (see medical advice on this label).
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.
Contains Kerosene (petroleum), Ethanol, propan-2-ol, Proprietary, Proprietary, Proprietary, Proprietary,
Proprietary, Proprietary, Citronellol
Other hazards
This product does not contain any substances classified as PBT or vPvB.
3. Composition/information on ingredients
Mixtures
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No. 9 Gun Bore Cleaner
Kerosene (petroleum)30-60%
CAS number: 8008-20-6
Classification
Flam. Liq. 4 - H227
Skin Irrit. 2 - H315
STOT SE 3 - H336
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411
Ethanol 10-30%
CAS number: 64-17-5
Classification
Flam. Liq. 2 - H225
Eye Irrit. 2A - H319
STOT SE 3 - H335, H336
propan-2-ol 5-10%
CAS number: 67-63-0
Classification
Flam. Liq. 2 - H225
Eye Irrit. 2A - H319
STOT SE 3 - H336
Amyl Acetate 1-5%
CAS number: 628-63-7
Classification
Flam. Liq. 3 - H226
2-methylbutyl acetat 1-5%
CAS number: 624-41-9
Classification
Flam. Liq. 3 - H226
methanol 1-5%
CAS number: 67-56-1
Classification
Flam. Liq. 2 - H225
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT SE 1 - H370
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No. 9 Gun Bore Cleaner
Ammonium Hydroxide <1%
CAS number: 1336-21-6
M factor (Acute) = 1
Classification
Skin Corr. 1B - H314
Eye Dam. 1 - H318
STOT SE 3 - H335
Aquatic Acute 1 - H400
(R)-p-mentha-1,8-diene <1%
CAS number: 5989-27-5
M factor (Acute) = 1
Classification
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Skin Sens. 1 - H317
Asp. Tox. 1 - H304
Aquatic Acute 1 - H400
Aquatic Chronic 3 - H412
1,8 cineole <1%
CAS number: 470-82-6
Classification
Flam. Liq. 3 - H226
Skin Sens. 1B - H317
4-methylpentan-2-one <1%
CAS number: 108-10-1
Classification
Flam. Liq. 2 - H225
Acute Tox. 4 - H332
Eye Irrit. 2A - H319
STOT SE 3 - H335
geraniol <1%
CAS number: 106-24-1
Classification
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Acute 2 - H401
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No. 9 Gun Bore Cleaner
naphthalene <1%
CAS number: 91-20-3
M factor (Acute) = 1 M factor (Chronic) = 1
Classification
Acute Tox. 4 - H302
Carc. 2 - H351
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
Nerol <1%
CAS number: 106-25-2
Classification
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1B - H317
Aquatic Acute 3 - H402
Citronellol <1%
CAS number: 106-22-9
Classification
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Skin Sens. 1 - H317
Aquatic Acute 2 - H401
p-Cymene 0.121%
CAS number: 99-87-6
Classification
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
STOT SE 3 - H335
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411
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No. 9 Gun Bore Cleaner
diammonium peroxodisulphate <1%
CAS number: 7727-54-0
Classification
Ox. Sol. 3 - H272
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Resp. Sens. 1 - H334
Skin Sens. 1 - H317
STOT SE 3 - H335
The full text for all hazard statements is displayed in Section 16.
Composition comments * The identity or exact percentage is withheld as a trade secret in accordance with 29 CFR
1910.1200.
4. First-aid measures
Description of first aid measures
General information Get medical attention immediately. Show this Safety Data Sheet to the medical personnel.
Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Maintain an open airway.
Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. Place unconscious person on
their side in the recovery position and ensure breathing can take place.
Ingestion Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water
or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not
induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing. Place unconscious person on their side in the recovery
position and ensure breathing can take place. Maintain an open airway. Loosen tight clothing
such as collar, tie or belt.
Skin Contact It is important to remove the substance from the skin immediately. Take off immediately all
contaminated clothing. Remove contamination with soap and water or recognized skin
cleansing agent. Get medical attention.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 10 minutes.
Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. If it is
suspected that volatile contaminants are still present around the affected person, first aid
personnel should wear an appropriate respirator or self-contained breathing apparatus. Wash
contaminated clothing thoroughly with water before removing it from the affected person, or
wear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.
Most important symptoms and effects, both acute and delayed
General information See Section 11 for additional information on health hazards. The severity of the symptoms
described will vary dependent on the concentration and the length of exposure.
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Inhalation A single exposure may cause the following adverse effects: Headache. Exhaustion and
weakness. Prolonged or repeated exposure may cause the following adverse effects:
Suspected of causing cancer.
Ingestion May cause sensitization or allergic reactions in sensitive individuals. May cause discomfort if
swallowed. Stomach pain. Nausea, vomiting. Aspiration hazard if swallowed. Entry into the
lungs following ingestion or vomiting may cause chemical pneumonitis. Prolonged or repeated
exposure may cause the following adverse effects: Suspected of causing cancer.
Skin contact May cause skin sensitization or allergic reactions in sensitive individuals. Redness. Irritating to
skin. Prolonged or repeated exposure may cause the following adverse effects: Suspected of
causing cancer.
Eye contact Irritating to eyes.
Indication of immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically. May cause sensitization or allergic reactions in sensitive individuals.
5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder
or water fog. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Special hazards arising from the substance or mixture
Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Flammable liquid and vapour. Vapors may be ignited by a spark, a hot surface or an ember.
Vapors may form explosive mixtures with air. Fire-water run-off in sewers may create fire or
explosion hazard. This product is toxic.
Hazardous combustion
products
Thermal decomposition or combustion products may include the following substances: Toxic
gases or vapors.
Advice for firefighters
Protective actions during
firefighting
Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of
gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool
containers exposed to heat with water spray and remove them from the fire area if it can be
done without risk. Cool containers exposed to flames with water until well after the fire is out.
If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping
the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and
keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate
authorities.
Special protective equipment
for firefighters
Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus
(SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets,
protective boots and gloves will provide a basic level of protection for chemical incidents.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
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No. 9 Gun Bore Cleaner
Personal precautions No action shall be taken without appropriate training or involving any personal risk. Keep
unnecessary and unprotected personnel away from the spillage. Wear protective clothing as
described in Section 8 of this safety data sheet. Follow precautions for safe handling
described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure
procedures and training for emergency decontamination and disposal are in place. Do not
touch or walk into spilled material. Evacuate area. Provide adequate ventilation. No smoking,
sparks, flames or other sources of ignition near spillage. Promptly remove any clothing that
becomes contaminated. Avoid inhalation of vapors and spray/mists. Use suitable respiratory
protection if ventilation is inadequate. Avoid contact with skin and eyes.
Environmental precautions
Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the
aquatic environment.
Methods and material for containment and cleaning up
Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills
immediately and dispose of waste safely. Eliminate all ignition sources if safe to do so. No
smoking, sparks, flames or other sources of ignition near spillage. Do not allow material to
enter confined spaces, due to the risk of explosion. Provide adequate ventilation. Absorb
small quantities with paper towels and evaporate in a safe place. Once evaporation is
complete, place paper in a suitable waste disposal container and seal securely. Large
Spillages: If the product is soluble in water, dilute the spillage with water and mop it up.
Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and
place it in a suitable waste disposal container. The contaminated absorbent may pose the
same hazard as the spilled material. Label the containers containing waste and contaminated
materials and remove from the area as soon as possible. Flush contaminated area with plenty
of water. Wash thoroughly after dealing with a spillage. Dangerous for the environment. Do
not empty into drains. For waste disposal, see Section 13.
Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.
7. Handling and storage
Precautions for safe handling
Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimize spills. Keep container tightly sealed
when not in use. Avoid the formation of mists. The product is flammable. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. In use may
form flammable/explosive vapour-air mixture. Vapors may accumulate on the floor and in low-
lying areas. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-
sparking tools. Take precautionary measures against static discharges. Suspected of causing
cancer. Avoid discharge to the aquatic environment. Do not handle until all safety precautions
have been read and understood. Do not handle broken packages without protective
equipment. Do not reuse empty containers.
Advice on general
occupational hygiene
Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash
before reuse. Wash contaminated clothing before reuse. Do not eat, drink or smoke when
using this product. Wash at the end of each work shift and before eating, smoking and using
the toilet. Change work clothing daily before leaving workplace.
Conditions for safe storage, including any incompatibilities
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Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Eliminate all
sources of ignition. Take precautionary measures against static discharges. Ground container
and transfer equipment to eliminate sparks from static electricity. Keep away from oxidizing
materials, heat and flames. Keep only in the original container. Keep container tightly closed,
in a cool, well ventilated place. Keep containers upright. Protect containers from damage.
Utilize retaining walls to prevent soil and water pollution in the event of spillage. The storage
area floor should be leak-tight, jointless and not absorbent.
Storage class Flammable liquid storage.
Specific end uses(s)
Specific end use(s)The identified uses for this product are detailed in Section 1.
8. Exposure Controls/personal protection
Control parameters
Occupational exposure limits
Kerosene (petroleum)
Long-term exposure limit (8-hour TWA): ACGIH 200 mg/m³
A3, Sk
Ethanol
Short-term exposure limit (15-minute): ACGIH 1000 ppm 1880 mg/m³
A3
Long-term exposure limit (8-hour TWA): OSHA 1000 ppm 1900 mg/m³
propan-2-ol
Long-term exposure limit (8-hour TWA): OSHA 400 ppm 980 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 200 ppm 492 mg/m³
Short-term exposure limit (15-minute): ACGIH 400 ppm 984 mg/m³
A4
Amyl Acetate
Long-term exposure limit (8-hour TWA): OSHA 100 ppm 525 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 50 ppm 266 mg/m³
Short-term exposure limit (15-minute): ACGIH 100 ppm 532 mg/m³
2-methylbutyl acetat
Long-term exposure limit (8-hour TWA): ACGIH 50 ppm 266 mg/m³
Short-term exposure limit (15-minute): ACGIH 100 ppm 532 mg/m³
methanol
Long-term exposure limit (8-hour TWA): ACGIH 200 ppm 262 mg/m³
Short-term exposure limit (15-minute): ACGIH 250 ppm 328 mg/m³
Sk
Long-term exposure limit (8-hour TWA): OSHA 200 ppm 260 mg/m³
4-methylpentan-2-one
Long-term exposure limit (8-hour TWA): ACGIH 20 ppm 82 mg/m³
Short-term exposure limit (15-minute): ACGIH 75 ppm 307 mg/m³
A3
Long-term exposure limit (8-hour TWA): OSHA 100 ppm 410 mg/m³
naphthalene
Long-term exposure limit (8-hour TWA): OSHA 10 ppm 50 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 10 ppm 52 mg/m³
A3, DSens, Sk
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diammonium peroxodisulphate
Long-term exposure limit (8-hour TWA): ACGIH 0.1 mg/m³
ACGIH = American Conference of Governmental Industrial Hygienists.
OSHA = Occupational Safety and Health Administration.
A3 = Confirmed Animal Carcinogen with Unknown Relevance to Humans.
Sk = Danger of cutaneous absorption.
A4 = Not Classifiable as a Human Carcinogen.
DSens = Dermal sensitizer.
Ethanol (CAS: 64-17-5)
Immediate danger to life
and health
3300 ppm
propan-2-ol (CAS: 67-63-0)
Immediate danger to life
and health
2000 ppm
Amyl Acetate (CAS: 628-63-7)
Immediate danger to life
and health
1000 ppm
methanol (CAS: 67-56-1)
Immediate danger to life
and health
6000 ppm
4-methylpentan-2-one (CAS: 108-10-1)
Immediate danger to life
and health
500 ppm
naphthalene (CAS: 91-20-3)
Immediate danger to life
and health
250 ppm
Exposure controls
Protective equipment
Appropriate engineering
controls
Provide adequate ventilation. Personal, workplace environment or biological monitoring may
be required to determine the effectiveness of the ventilation or other control measures and/or
the necessity to use respiratory protective equipment. Use process enclosures, local exhaust
ventilation or other engineering controls as the primary means to minimize worker exposure.
Personal protective equipment should only be used if worker exposure cannot be controlled
adequately by the engineering control measures. Ensure control measures are regularly
inspected and maintained. Ensure operatives are trained to minimize exposure. The
engineering controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits. Use explosion-proof ventilating equipment.
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Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Personal protective equipment for eye and face protection should
comply with OSHA 1910.133. Wear tight-fitting, chemical splash goggles or face shield. If
inhalation hazards exist, a full-face respirator may be required instead.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. The most suitable glove should be
chosen in consultation with the glove supplier/manufacturer, who can provide information
about the breakthrough time of the glove material. To protect hands from chemicals, gloves
should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical
and resist degradation. Considering the data specified by the glove manufacturer, check
during use that the gloves are retaining their protective properties and change them as soon
as any deterioration is detected. Frequent changes are recommended.
Other skin and body
protection
Appropriate footwear and additional protective clothing complying with an approved standard
should be worn if a risk assessment indicates skin contamination is possible.
Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not be
allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment
and the work area every day. Good personal hygiene procedures should be implemented.
Wash at the end of each work shift and before eating, smoking and using the toilet. When
using do not eat, drink or smoke. Preventive industrial medical examinations should be carried
out. Warn cleaning personnel of any hazardous properties of the product.
Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective
equipment is suitable for its intended use and is NIOSH approved. Check that the respirator
fits tightly and the filter is changed regularly. Gas and combination filter cartridges should
comply with OSHA 1910.134. Full face mask respirators with replaceable filter cartridges
should comply with OSHA 1910.134. Half mask and quarter mask respirators with replaceable
filter cartridges should comply with OSHA 1910.134.
Environmental exposure
controls
Keep container tightly sealed when not in use. Emissions from ventilation or work process
equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to
the process equipment will be necessary to reduce emissions to acceptable levels.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Appearance Clear liquid.
Color Amber.
Odor Characteristic.
Odor threshold No information available.
pH No information available.
Melting point >-114.2°C/-173.5°F
Initial boiling point and range >47.0°C/116.6°F
Flash point > 12.8°C/55.0°F
Evaporation rate No information available.
Flammability (solid, gas)Class IB Liquid
Upper/lower flammability or
explosive limits
Lower flammable/explosive limit: 0.70 % Upper flammable/explosive limit: 19 %
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No. 9 Gun Bore Cleaner
Vapor pressure 248.35 mm Hg @ 25°C
Vapor density 9.700 g/cc Maximum
Relative density 0.844 g/cc
Solubility(ies)No information available.
Partition coefficient No information available.
Auto-ignition temperature 210.0°C/410.0°F
Decomposition Temperature No information available.
Viscosity 4.2-4.8 cP @ 25°C
Explosive properties No information available.
Oxidizing properties Not available.
Volatile organic compound This product contains a maximum VOC content of 73 %, WT. This product contains a
maximum VOC content of 75 VOL, %.
VOC Content 5.028 lbs/gal (602.474 g/L)
10. Stability and reactivity
Reactivity See the other subsections of this section for further details.
Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.
Possibility of hazardous
reactions
The following materials may react strongly with the product: Oxidizing agents.
Conditions to avoid Avoid heat, flames and other sources of ignition. Containers can burst violently or explode
when heated, due to excessive pressure build-up. Static electricity and formation of sparks
must be prevented. Do not pressurize, cut, weld, drill, grind or otherwise expose containers to
heat or sources of ignition.
Materials to avoid Oxidizing materials. Acids - oxidizing.
Hazardous decomposition
products
Does not decompose when used and stored as recommended. Thermal decomposition or
combustion products may include the following substances: Toxic gases or vapors.
11. Toxicological information
Information on toxicological effects
Acute toxicity - oral
Notes (oral LD₅₀)Acute Tox. 4 - H302 Harmful if swallowed.
ATE oral (mg/kg)1,595.38
Acute toxicity - dermal
Notes (dermal LD₅₀)Acute Tox. 4 - H312 Harmful in contact with skin.
ATE dermal (mg/kg)1,199.57
Acute toxicity - inhalation
Notes (inhalation LC₅₀)Acute Tox. 4 - H332 Harmful if inhaled.
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ATE inhalation (gases ppm)44,224.03
ATE inhalation (vapours mg/l)12.81
Skin corrosion/irritation
Animal data Irritating.
Serious eye damage/irritation
Serious eye damage/irritation Causes serious eye irritation.
Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.
Skin sensitization
Skin sensitization May cause skin sensitization or allergic reactions in sensitive individuals.
Germ cell mutagenicity
Genotoxicity - in vitro Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Suspected of causing cancer.
IARC carcinogenicity Contains a substance/a group of substances which may cause cancer. IARC Group 1
Carcinogenic to humans.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity -
development
Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure STOT SE 3 - H335, H336 May cause respiratory irritation. May cause drowsiness or
dizziness.
Target organs Respiratory system, lungs Central nervous system
Specific target organ toxicity - repeated exposure
STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.
Aspiration hazard
Aspiration hazard Asp. Tox. 1 - H304 May be fatal if swallowed and enters airways. Pneumonia may be the
result if vomited material containing solvents reaches the lungs.
General information May cause cancer after repeated exposure. Risk of cancer depends on duration and level of
exposure. The severity of the symptoms described will vary dependent on the concentration
and the length of exposure.
Inhalation A single exposure may cause the following adverse effects: Headache. Exhaustion and
weakness.
Ingestion May cause sensitization or allergic reactions in sensitive individuals. May cause discomfort if
swallowed. Stomach pain. Nausea, vomiting. Aspiration hazard if swallowed. Entry into the
lungs following ingestion or vomiting may cause chemical pneumonitis.
Skin Contact May cause skin sensitization or allergic reactions in sensitive individuals. Redness. Irritating to
skin.
Eye contact Irritating to eyes.
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Route of entry Ingestion Inhalation Skin and/or eye contact
Target Organs Central nervous system Respiratory system, lungs
Medical considerations Skin disorders and allergies.
12. Ecological Information
Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.
Toxicity Aquatic Chronic 2 - H411 Toxic to aquatic life with long lasting effects.
Persistence and degradability
Persistence and degradability The degradability of the product is not known.
Bioaccumulative potential
Bio-Accumulative Potential No data available on bioaccumulation.
Partition coefficient No information available.
Mobility in soil
Mobility No data available.
Other adverse effects
Other adverse effects None known.
13. Disposal considerations
Waste treatment methods
General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way. Disposal of this product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and
any local authority requirements. When handling waste, the safety precautions applying to
handling of the product should be considered. Care should be taken when handling emptied
containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners
may retain some product residues and hence be potentially hazardous.
Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a
licensed waste disposal contractor. Waste, residues, empty containers, discarded work
clothes and contaminated cleaning materials should be collected in designated containers,
labeled with their contents. Incineration or landfill should only be considered when recycling is
not feasible. Vapor from residual product may create a highly flammable or explosive
atmosphere inside the container. Containers should be thoroughly emptied before disposal
because of the risk of an explosion. Do not cut or weld used containers unless they have been
thoroughly cleaned internally.
14. Transport information
General For limited quantity packaging/limited load information, consult the relevant modal
documentation using the data shown in this section.
UN Number
UN No. (TDG)1993
UN No. (IMDG)1993
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UN No. (ICAO)1993
UN No. (DOT)UN1993
UN proper shipping name
Proper shipping name (TDG)FLAMMABLE LIQUID, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum))
Proper shipping name (IMDG)FLAMMABLE LIQUID, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum), Ammonium
Hydroxide, (R)-p-mentha-1,8-diene)
Proper shipping name (ICAO)FLAMMABLE LIQUID, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum))
Proper shipping name (DOT)FLAMMABLE LIQUIDS, N.O.S. (CONTAINS Ethanol, Kerosene (petroleum))
Transport hazard class(es)
DOT hazard class 3
DOT hazard label 3
TDG class 3
TDG label(s)3
IMDG Class 3
ICAO class/division 3
Transport labels
Limited Quantity Packaging (Class 3)
Limited Quantity
DOT Limited Quantity (Class 3) Limited Quantity diamond
ICAO/IATA Limited Quantity (Class 3)
TDG Limited Quantity Diamond (Class 3)
IMDG Limited Quantity (Class 3)
ADR Limited Quantity (Class 3)
Packing group
TDG Packing Group II
IMDG packing group II
ICAO packing group II
DOT packing group II
Environmental hazards
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Environmentally Hazardous Substance
Special precautions for user
Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to
do in the event of an accident or spillage.
EmS F-E, S-E
DOT reportable quantity RQ: Ammonium hydroxide (31172.0698 lbs), RQ: Naphthalene (63261.1102 lbs)
Transport in bulk according to
Annex II of MARPOL 73/78
and the IBC Code
Not applicable.
15. Regulatory information
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)
The following ingredients are listed or exempt:
naphthalene
Final CERCLA RQ: 100(45.4) pounds (Kilograms)
Ammonium Hydroxide
Final CERCLA RQ: 1000(454) pounds (Kilograms)
Amyl Acetate
Final CERCLA RQ: 5000(2270) pounds (Kilograms)
4-methylpentan-2-one
Final CERCLA RQ: 5000(2270) pounds (Kilograms)
methanol
Final CERCLA RQ: 5000(2270) pounds (Kilograms)
SARA Extremely Hazardous Substances EPCRA Reportable Quantities
None of the ingredients are listed or exempt.
SARA 313 Emission Reporting
The following ingredients are listed or exempt:
naphthalene
0.1 %
diammonium peroxodisulphate
1.0 %
Ammonium Hydroxide
1.0 %
4-methylpentan-2-one
1.0 %
methanol
1.0 %
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CAA Accidental Release Prevention
None of the ingredients are listed or exempt.
FDA - Essential Chemical
None of the ingredients are listed or exempt.
FDA - Precursor Chemical
None of the ingredients are listed or exempt.
SARA (311/312) Hazard Categories
None of the ingredients are listed or exempt.
OSHA Highly Hazardous Chemicals
None of the ingredients are listed or exempt.
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
The following ingredients are listed or exempt:
naphthalene
Known to the State of California to cause cancer.
4-methylpentan-2-one
Known to the State of California to cause cancer and developmental reproductive toxicity.
methanol
Known to the State of California to cause developmental and reproductive toxicity.
California Air Toxics "Hot Spots" (A-I)
The following ingredients are listed or exempt:
naphthalene
4-methylpentan-2-one
methanol
propan-2-ol
California Air Toxics "Hot Spots" (A-II)
None of the ingredients are listed or exempt.
California Directors List of Hazardous Substances
The following ingredients are listed or exempt:
naphthalene
Ammonium Hydroxide
Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
Massachusetts "Right To Know" List
The following ingredients are listed or exempt:
naphthalene
Kerosene (petroleum)
Ammonium Hydroxide
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Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
p-Cymene
Rhode Island "Right To Know" List
The following ingredients are listed or exempt:
naphthalene
Kerosene (petroleum)
Oleic Acid
Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
Minnesota "Right To Know" List
The following ingredients are listed or exempt:
naphthalene
Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
New Jersey "Right To Know" List
The following ingredients are listed or exempt:
naphthalene
Kerosene (petroleum)
diammonium peroxodisulphate
Ammonium Hydroxide
Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
Pennsylvania "Right To Know" List
The following ingredients are listed or exempt:
naphthalene
Kerosene (petroleum)
Ammonium Hydroxide
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Oleic Acid
Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
p-Cymene
Inventories
US - TSCA
The following ingredients are listed or exempt:
naphthalene
Kerosene (petroleum)
diammonium peroxodisulphate
Ammonium Hydroxide
Oleic Acid
2-methylbutyl acetat
Amyl Acetate
4-methylpentan-2-one
methanol
propan-2-ol
Ethanol
g-Terpinene
Nerol
Citronellol
p-Cymene
geraniol
(R)-p-mentha-1,8-diene
1,8 cineole
US - TSCA 12(b) Export Notification
None of the ingredients are listed or exempt.
16. Other information
Classification abbreviations
and acronyms
Flam. Liq. = Flammable liquid
Acute Tox. = Acute toxicity
Asp. Tox. = Aspiration hazard
Carc. = Carcinogenicity
Eye Irrit. = Eye irritation
Skin Irrit. = Skin irritation
Skin Sens. = Skin sensitisation
STOT SE = Specific target organ toxicity-single exposure
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Training advice Read and follow manufacturer's recommendations. Only trained personnel should use this
material.
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Revision comments Revised for new Authoring software
Revision date 12/2/2019
Revision 10
Supersedes date 6/10/2019
SDS No.4517
Hazard statements in full H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H227 Combustible liquid.
H272 May intensify fire; oxidizer.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H370 Causes damage to organs .
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life.
H402 Harmful to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
End of Safety Data Sheet
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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SAFETY DATA SHEET
Lubricating Oil
According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200
1. Identification
Product identifier
Product name Lubricating Oil
Chemical name Process Oil
Product number 1003, 1003B, 1003RB, 1003CN
Internal identification 1000-202
CAS number 64742-54-7
Recommended use of the chemical and restrictions on use
Application Firearm Lubrication
Uses advised against No specific uses advised against are identified.
Details of the supplier of the safety data sheet
Manufacturer Bushnell Holdings Inc
9200 Cody
Overland Park, KS 66214
1-800-423-3537
dangerous.goods@vistaoutdoor.com
Emergency telephone number
Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation
Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) -
(CHEMTREC, Day and Night)
2. Hazard(s) identification
Classification of the substance or mixture
Physical hazards Not Classified
Health hazards Not Classified
Environmental hazards Not Classified
Label elements
Hazard statements NC Not Classified
Other hazards
This substance is not classified as PBT or vPvB according to current EU criteria.
3. Composition/information on ingredients
Substances
Product name Lubricating Oil
Chemical name Process Oil
CAS number 64742-54-7
4. First-aid measures
Description of first aid measures
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Lubricating Oil
General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medical
personnel.
Inhalation No specific recommendations. If throat irritation or coughing persists, proceed as follows.
Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if any
discomfort continues.
Ingestion No specific recommendations. If throat irritation or coughing persists, proceed as follows.
Rinse mouth. Get medical attention if any discomfort continues.
Skin Contact No specific recommendations. Rinse with water. Get medical attention if any discomfort
continues.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical
attention if any discomfort continues.
Protection of first aiders Use protective equipment appropriate for surrounding materials.
Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.
Ingestion No specific symptoms known. May cause discomfort if swallowed.
Skin contact No specific symptoms known. May cause discomfort.
Eye contact No specific symptoms known. May be slightly irritating to eyes.
Indication of immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
Specific treatments No special treatment required.
5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry
powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Special hazards arising from the substance or mixture
Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Hazardous combustion
products
Thermal decomposition or combustion products may include the following substances:
Harmful gases or vapors.
Advice for firefighters
Protective actions during
firefighting
Avoid breathing fire gases or vapors. Evacuate area. Cool containers exposed to heat with
water spray and remove them from the fire area if it can be done without risk. Cool containers
exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use
water spray to disperse vapors and protect men stopping the leak.
Special protective equipment
for firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will
provide a basic level of protection for chemical incidents.
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Lubricating Oil
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions No specific recommendations. For personal protection, see Section 8.
Environmental precautions
Environmental precautions Avoid discharge into drains or watercourses or onto the ground.
Methods and material for containment and cleaning up
Methods for cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage.
Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.
Dispose of contents/container in accordance with national regulations.
Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
7. Handling and storage
Precautions for safe handling
Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimize spills. Keep container tightly sealed
when not in use. Avoid the formation of mists.
Advice on general
occupational hygiene
Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash
before reuse. Wash contaminated clothing before reuse.
Conditions for safe storage, including any incompatibilities
Storage precautions Store away from incompatible materials (see Section 10). No specific recommendations.
Storage class Unspecified storage.
Specific end uses(s)
Specific end use(s)The identified uses for this product are detailed in Section 1.
8. Exposure Controls/personal protection
Control parameters
Occupational exposure limits
Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 5 mg/m³
Short-term exposure limit (15-minute): ACGIH 10 mg/m³
OSHA = Occupational Safety and Health Administration.
ACGIH = American Conference of Governmental Industrial Hygienists.
Exposure controls
Protective equipment
Appropriate engineering
controls
No specific ventilation requirements.
Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying
with an approved standard should be worn if a risk assessment indicates eye contact is
possible.
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Lubricating Oil
Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves.
Other skin and body
protection
Wear appropriate clothing to prevent repeated or prolonged skin contact.
Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke
when using this product.
Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is
inadequate, suitable respiratory protection must be worn.
Environmental exposure
controls
Not regarded as dangerous for the environment.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Appearance Clear liquid.
Color Water-white.
Odor Odorless.
pH Not applicable.
Melting point Not determined.
Initial boiling point and range 315°C/599°F
Flash point 192°C/378°F
Evaporation rate No information available.
Flammability (solid, gas)Class IIIB Liquid
Upper/lower flammability or
explosive limits
Not available.
Vapor pressure < 0.01 mm Hg @ 25°C
Vapor density > 1.0 g/cc
Relative density 0.866
Bulk density 7.228 lb/gal
Solubility(ies)Insoluble in water.
Partition coefficient Not determined.
Auto-ignition temperature 210°C/410°F
Decomposition Temperature Not determined.
Volatility 3% wt (Max)
10. Stability and reactivity
Reactivity See the other subsections of this section for further details.
Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.
Possibility of hazardous
reactions
No potentially hazardous reactions known.
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Lubricating Oil
Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.
Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.
Hazardous decomposition
products
Does not decompose when used and stored as recommended. Thermal decomposition or
combustion products may include the following substances: Harmful gases or vapors.
11. Toxicological information
Information on toxicological effects
Toxicological effects Not regarded as a health hazard under current legislation.
Acute toxicity - oral
Notes (oral LD₅₀)Based on available data the classification criteria are not met.
Acute toxicity - dermal
Notes (dermal LD₅₀)Based on available data the classification criteria are not met.
Acute toxicity - inhalation
Notes (inhalation LC₅₀)Based on available data the classification criteria are not met.
Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.
Serious eye damage/irritation
Serious eye damage/irritation Based on available data the classification criteria are not met.
Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.
Skin sensitization
Skin sensitization Based on available data the classification criteria are not met.
Germ cell mutagenicity
Genotoxicity - in vitro Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
IARC carcinogenicity None of the ingredients are listed or exempt.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity -
development
Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.
Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.
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Lubricating Oil
General information No specific health hazards known. The severity of the symptoms described will vary
dependent on the concentration and the length of exposure.
Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.
Ingestion No specific symptoms known. May cause discomfort if swallowed.
Skin Contact No specific symptoms known. May cause discomfort.
Eye contact No specific symptoms known. May be slightly irritating to eyes.
Route of entry Ingestion Inhalation Skin and/or eye contact
Target Organs No specific target organs known.
12. Ecological Information
Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.
Toxicity Based on available data the classification criteria are not met.
Persistence and degradability
Persistence and degradability The degradability of the product is not known.
Bioaccumulative potential
Bio-Accumulative Potential No data available on bioaccumulation.
Partition coefficient Not determined.
Mobility in soil
Mobility No data available.
Other adverse effects
Other adverse effects None known.
13. Disposal considerations
Waste treatment methods
General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way.
Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposal
contractor. Waste packaging should be collected for reuse or recycling. Incineration or landfill
should only be considered when recycling is not feasible. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of the local water
authority.
14. Transport information
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DOT).
UN Number
Not applicable.
UN proper shipping name
Not applicable.
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Lubricating Oil
Transport hazard class(es)
No transport warning sign required.
Packing group
Not applicable.
Environmental hazards
Environmentally Hazardous Substance
No.
Special precautions for user
Not applicable.
Transport in bulk according to
Annex II of MARPOL 73/78
and the IBC Code
Not applicable.
15. Regulatory information
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)
None of the ingredients are listed or exempt.
SARA Extremely Hazardous Substances EPCRA Reportable Quantities
None of the ingredients are listed or exempt.
SARA 313 Emission Reporting
None of the ingredients are listed or exempt.
CAA Accidental Release Prevention
None of the ingredients are listed or exempt.
FDA - Essential Chemical
None of the ingredients are listed or exempt.
FDA - Precursor Chemical
None of the ingredients are listed or exempt.
SARA (311/312) Hazard Categories
None of the ingredients are listed or exempt.
OSHA Highly Hazardous Chemicals
None of the ingredients are listed or exempt.
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the ingredients are listed or exempt.
California Air Toxics "Hot Spots" (A-I)
None of the ingredients are listed or exempt.
California Air Toxics "Hot Spots" (A-II)
None of the ingredients are listed or exempt.
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Lubricating Oil
California Directors List of Hazardous Substances
None of the ingredients are listed or exempt.
Massachusetts "Right To Know" List
None of the ingredients are listed or exempt.
Rhode Island "Right To Know" List
None of the ingredients are listed or exempt.
Minnesota "Right To Know" List
None of the ingredients are listed or exempt.
New Jersey "Right To Know" List
None of the ingredients are listed or exempt.
Pennsylvania "Right To Know" List
None of the ingredients are listed or exempt.
Inventories
US - TSCA
None of the ingredients are listed or exempt.
US - TSCA 12(b) Export Notification
None of the ingredients are listed or exempt.
16. Other information
Classification abbreviations
and acronyms
Asp. Tox. = Aspiration hazard
Training advice Only trained personnel should use this material.
Revision date 2/8/2019
Revision 7
Supersedes date 10/9/2017
SDS No.4634
End of Safety Data Sheet
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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FLASH POINT
35 °F TCC
Specific Gravity
0.85
Product Weight
7.04 lb/gal
12 00 [0365]
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
Date of Preparation
May 21, 2019
PRODUCT NUMBER
530-2146
PRODUCT NAME
Reducer NO. K69
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
530-2146 = | Acute | Chronic | Fire |
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Toluene
108-88-3 N Y Y Y 15 15
Ethylbenzene
100-41-4 N Y Y Y 9 9
Xylene
1330-20-7 N Y Y Y 52 51
Methyl Isobutyl Ketone
108-10-1 N Y Y Y 24 25
Volatile Organic Compounds - U.S. EPA / Canada
530-2146
LB/Gal g/L
Coating Density 7.04 843
By wt By vol
Total Volatiles 100.0% 100.0%
Federally exempt solvents
Water 0.0%0.0%
Organic Volatiles 100.0% 100.0%
Percent Non-Volatile 0.0%0.0%
VOC Content LB/Gal g/L
Total 7.03 843
Less exempt solvents 7.03 843
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 100.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 5.84
Christensen Arms AO Modification 9/7/23
530-2146
page 2 of 3
Volatile Organic Compounds - California
530-2146
LB/Gal g/L
Coating Density 7.04 843
By wt By vol
Total Volatiles 100.0% 100.0%
Exempt solvents
Water 0.0%0.0%
Organic Volatiles 100.0% 100.0%
Percent Non-Volatile 0.0%0.0%
VOC Content LB/Gal g/L
Total 7.03 843
Less exempt solvents 7.03 843
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 100.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 5.77
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
530-2146
LB/Gal g/L
Coating Density 7.04 843
By wt By vol
Total Volatiles 100.0% 100.0%
Exempt solvents
Water 0.0%0.0%
Organic Volatiles 100.0% 100.0%
Percent Non-Volatile 0.0%0.0%
VOC Content LB/Gal g/L
Total 7.03 843
Less exempt solvents 7.03 843
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
530-2146
By wt By vol
Total Volatiles 100.0% 100.0%
VOC Content LB/Gal g/L
Total 7.03 843
Volatile Organic Compounds - EU Directive 2010/75/EU
530-2146
By wt By vol
Total Volatiles 100.0% 100.0%
VOC Content LB/Gal g/L
Total 7.03 843
Christensen Arms AO Modification 9/7/23
530-2146
page 3 of 3
Volatile Organic Compounds - Mexico
530-2146
LB/Gal g/L
Coating Density 7.04 843
By wt By vol
Total Volatiles 100.0% 100.0%
Exempt solvents
Water 0.0%0.0%
Organic Volatiles 100.0% 100.0%
Percent Non-Volatile 0.0%0.0%
VOC Content LB/Gal g/L
Total 7.03 843
Less exempt solvents 7.03 843
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
530-2146
LB/Gal kg/L
Volatile HAPS 7.03 0.843 100.00 % by wt
Of solids lb/gal kg/l of solids Not applicable
Of solids lb/lb kg/kg of solids Not applicable
Air Quality Data
Density of Organic Solvent Blend
7.04 lb/gal
Photochemically Reactive
Yes
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
Christensen Arms AO Modification 9/7/23
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Mono-Coat® E179 N-ODS
+1 517 546 4520
SAFETY DATA SHEET
Product name
Emergency telephone
number and Telephone
number
Section 1. Identification
:
:
Supplier's details :Chem-Trend LP
1445 W McPherson Park Dr
PO Box 860, Howell MI 48844-0860
517-546-4520
Mono-Coat® E179 N-ODS
Relevant identified uses of the substance or mixture and uses advised against
Release Agent
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
ASPIRATION HAZARD - Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye damage.
Causes skin irritation.
May be fatal if swallowed and enters airways.
May cause drowsiness or dizziness.
Hazard pictograms :
Precautionary statements
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor.
Wash hands thoroughly after handling.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 36.7%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 1/13Christensen Arms AO Modification 9/7/23
Mono-Coat® E179 N-ODS
Section 2. Hazards identification
Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a
POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take
off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or physician.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
propan-1-ol ≥25 - ≤50 71-23-8
Light aliphatic naphtha ≥25 - ≤50 -
nonane ≥10 - ≤25 111-84-2
ethanol ≤3 64-17-5
Glycol ≤3 -
Ingredient name CAS number%
Substance/mixture :Mixture
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns
must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Flush
contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a
physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision :8/19/2017 Date of previous issue :6/27/2017 Version :3 2/13Christensen Arms AO Modification 9/7/23
Mono-Coat® E179 N-ODS
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
stomach pains
nausea or vomiting
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Mono-Coat® E179 N-ODS
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway,
sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages
into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may
pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for
waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Precautions for safe handling
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Mono-Coat® E179 N-ODS
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
propan-1-ol OSHA PEL 1989 (United States, 3/1989).
TWA: 200 ppm 8 hours.
TWA: 500 mg/m³ 8 hours.
STEL: 250 ppm 15 minutes.
STEL: 625 mg/m³ 15 minutes.
OSHA PEL (United States, 6/2016).
TWA: 200 ppm 8 hours.
TWA: 500 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2016).
TWA: 100 ppm 8 hours.
nonane ACGIH TLV (United States, 3/2016).
TWA: 200 ppm 8 hours.
TWA: 1050 mg/m³ 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 200 ppm 8 hours.
TWA: 1050 mg/m³ 8 hours.
ethanol ACGIH TLV (United States, 3/2016).
STEL: 1000 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
Glycol ACGIH TLV (United States, 3/2016). Absorbed through skin.
TWA: 100 ppm 8 hours.
TWA: 606 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 909 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.
Ingredient name Exposure limits
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Individual protection measures
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
TWA: 100 ppm 8 hours.
TWA: 600 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 900 mg/m³ 15 minutes.
OSHA PEL (United States, 6/2016). Absorbed through skin.
TWA: 100 ppm 8 hours.
TWA: 600 mg/m³ 8 hours.
Section 9. Physical and chemical properties
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Mono-Coat® E179 N-ODS
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative densityVapor density
Solubility
Liquid.
Not available.
0.77>1 [Air = 1]
Not available.
Insoluble in the following
materials: cold water.
Hydrocarbon.Odor
pH
Colorless.Color
Evaporation rate Not available.
Auto-ignition
temperature
Flash point
Not available.
Closed cup: 14°C (57.2°F) [
Pensky-Martens]
Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): <0.2
cm2/s (<20 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
Boiling point 118°C (244.4°F)
Flammability (solid,
gas)
Not available.
Lower and upper
explosive (flammable)
limits
Not available.
Burning rate Not applicable.Burning time Not applicable.
SADT Not available.Decomposition
temperature
Not available.
Solubility in water Not available.
Volatility 98.54
nonane Lower: 0.8% Upper: 2.9%
Naphtha (petroleum), hydrotreated light Lower: 1.05% Upper: 7.6%
(2-methoxymethylethoxy)propanol Lower: 1.1% Upper: 14%
propan-1-ol Lower: 2.1% Upper: 13.5%
ethanol Lower: 3.3% Upper: 19%
Lower and upper explosive (flammable) limits
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Formaldehyde and silicon dioxide may be evolved at elevated temperatures.
The product is stable.Chemical stability
Reactive or incompatible with the following materials: oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Mono-Coat® E179 N-ODS
Section 11. Toxicological information
Acute toxicity
propan-1-ol LD50 Dermal Rabbit 5040 mg/kg -
LD50 Oral Rat 1870 mg/kg -
nonane LC50 Inhalation Gas.Rat 3200 ppm 4 hours
LC50 Inhalation Vapor Rat 17000 mg/m³4 hours
ethanol LC50 Inhalation Vapor Rat 124700 mg/m³4 hours
LD50 Oral Rat 7 g/kg -
Product/ingredient name Result Species Dose Exposure
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye damage.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
IngestionInhalation
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Eye contact
Adverse symptoms may include the following:
pain
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
propan-1-ol Narcotic effects
Light aliphatic naphtha Narcotic effects
Name
Not available.
Aspiration hazard
Name Result
Light aliphatic naphtha ASPIRATION HAZARD - Category 1
nonane ASPIRATION HAZARD - Category 1
Target organs
Information on toxicological effects
:Not available.
Potential acute health effects
Irritation/Corrosion :Causes serious eye damage. Causes skin irritation.
Sensitization :No known significant effects or critical hazards.
Mutagenicity :No known significant effects or critical hazards.
Carcinogenicity :
Reproductive toxicity :No known significant effects or critical hazards.
Teratogenicity :No known significant effects or critical hazards.
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Section 11. Toxicological information
Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
stomach pains
nausea or vomiting
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Inhalation (gases)17993.6 ppm
Inhalation (vapors)95.59 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
No known significant effects or critical hazards.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
RCRA classification :D001 Because of its ignitability if the product is disposed of in its original form.
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Mono-Coat® E179 N-ODS
Section 14. Transport information
Flammable liquids,
n.o.s. (Light
aliphatic naphtha,
nonane)
3
II
FLAMMABLE
LIQUID, N.O.S.
(Light aliphatic
naphtha, nonane)
3
II
UN1993 UN1993
The marine
pollutant mark is
not required when
transported in
sizes of ≤5 L or ≤5
kg.
Emergency
schedules (EmS)
F-E, _S-E_
Special
provisions
274
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No.Yes.
TDG
Classification
UN1993
FLAMMABLE
LIQUID, N.O.S.
(Light aliphatic
naphtha, nonane)
3
II
No.
Flammable liquid,
n.o.s. (Light
aliphatic naphtha,
nonane)
3
II
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
Passenger and
Cargo Aircraft
Quantity limitation:
5 L
Packaging
instructions: 353
Cargo Aircraft
OnlyQuantity
limitation: 60 L
Packaging
instructions: 364
Limited
Quantities -
Passenger
AircraftQuantity
limitation: 1 L
Packaging
instructions: Y341
Special
provisions
A3
No.
UN1993UN1993
Flammable liquids,
n.o.s.(Light
aliphatic naphtha,
nonane)
3
II
Yes
Bulk
Limited quantity
Yes.
Packaging
instruction
Passenger
aircraft
Quantity limitation:
5 L
Cargo aircraft
Quantity limitation:
60 L
Special
provisions
IB2, T7, TP1, TP8,
TP28
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations: 2.
18-2.19 (Class 3).
Explosive Limit
and Limited
Quantity Index
1
Passenger
Carrying Road or
Rail Index
5
Special
provisions
16
128Emergency Response Guidebook (ERG):
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Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
Australia inventory (AICS)
Canada inventory ( DSL/NDSL )
China inventory (IECSC)
Europe inventory (EINECS)
Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): Not determined.
Not determined.
All components are listed or exempted.
Japan inventory
Korea inventory (KECI)
New Zealand Inventory of Chemicals (NZIoC)
Philippines inventory (PICCS)
All components are listed or exempted.United States inventory (TSCA 8b)
All components are listed or exempted.
International lists :
WHMIS (Canada)Class B-2: Flammable liquid
Class D-2B: Material causing other toxic effects (Toxic).
:
Canada
State regulations
Massachusetts
New York
New Jersey
Pennsylvania
:
:
:
:
None of the components are listed.
The following components are listed: NONANE; PROPYL ALCOHOL; PROPANOL;
ETHYL ALCOHOL; DENATURED ALCOHOL; Glycol
The following components are listed: NONANE; PROPYL ALCOHOL; 1-PROPANOL;
ETHYL ALCOHOL; ALCOHOL; Glycol
The following components are listed: NONANE; 1-PROPANOL; DENATURED
ALCOHOL; ETHANOL; Glycol
California Prop. 65
WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
Not applicable.
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Mono-Coat® E179 N-ODS
Section 15. Regulatory information
methanol No.Yes.No.23000 µg/day
(ingestion)
47000 µg/day
(inhalation)
ethylbenzene Yes.No.41 µg/day (ingestion)
54 µg/day (inhalation)
No.
toluene No.Yes.No.7000 µg/day
(ingestion)
4-methylpentan-2-one Yes.Yes.No.No.
benzene Yes.Yes.6.4 µg/day (ingestion)
13 µg/day (inhalation)
24 µg/day (ingestion)
49 µg/day (inhalation)
naphthalene Yes.No.Yes.No.
acetaldehyde Yes.No.90 µg/day (inhalation)No.
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
TSCA 12(b) one-time export: nonane
Section 16. Other information
History
Date of issue/Date of
revision
Version
Prepared by
Information presented herein has been compiled from information provided to us by our suppliers and other
sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is
not guaranteed to be so. Nothing herein is to be construed as recommending any practice or the use of any
product in violation of any patent or in violation of any law or regulation. It is the users' responsibility to
determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be
necessary. We make no warranty as to the results to be obtained in using any material and, since conditions of
use are not under our control, we must necessarily disclaim all liability with respect to the use of any material
supplied by us.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
8/19/2017
6/27/2017
3
Hazardous Material Information System (U.S.A.)
2 3 0
032
National Fire Protection Association (U.S.A.)
Special :Instability/Reactivity :Flammability :
Health :Flammability :Physical hazards :Personal protection Code :H
Health :
Chem-Trend Regulatory Affairs Department.
-
*
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
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Mono-Coat® E179 N-ODS
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Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
Christensen Arms AO Modification 9/7/23
SAFETY DATA SHEET
Date Issued : 10/10/2014
SDS No :
Date Revised : 03/30/2020
Revision No : 16
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT DESCRIPTION:
PRODUCT CODE:
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
Pacer Technology
3281 E. Guasti Road, Suite 260
Ontario, CA 91761
Emergency Contact: Chemtrec
Emergency Phone: (800) 424-9300
Customer Service: (909) 987-0550
CHEMTREC (800) 424-9300
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Eye Irritation, Category 2A
Skin Irritation, Category 2
Target Organ Toxicity (Single exposure), Category 3
Skin Sensitization, Category 1
Physical:
Flammable Liquids, Category 4
GHS LABEL
Note: If this product is a consumer product it is labeled in accordance with the Consumer Product Safety Commission
regulations and not OSHA regulations. The requirements for the labeling of consumer products take precedence over OSHA
labeling so the actual product label will not contain the OSHA label elements shown below on this SDS.
Exclamation
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H227: Combustible liquid.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash skin and hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
Page 1 of 7
11740026_FG04010
RX-50 ADHESIVE 20GM
11740026_FG04010
Christensen Arms AO Modification 9/7/23
SAFETY DATA SHEET
Date Issued : 10/10/2014
SDS No :
Date Revised : 03/30/2020
Revision No : 16
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P313: Get medical advice/attention.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing.
P370: In case of fire: Use dry chemical, foam or carbon dioxide to extinguish.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
Disposal:
P501: Dispose of in a manner consistent with federal, state, and local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED: Skin contact through clothing may cause burns.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.%CAS
ETHYL-2-CYANOACRYLATE 85 - 100 7085-85-0
Polymethyl methacrylate 10 - 30 9011-14-7
Hydroquinone < 0.1 123-31-9
4. FIRST AID MEASURES
EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention.
SKIN: Wash with soap and water. Peel or roll skin apart.
INGESTION: Peel or roll skin apart. Adhesive becomes solid in contact with saliva and may adhere to inside of mouth. Saliva will
lift adhesive in 1-2 days. Avoid swallowing solid adhesive after detachment. Not a toxic product.
INHALATION: Remove to fresh air. Prolonged or repeated elevated exposure may cause allergic reactions with asthma-like
symptoms in sensitive individuals.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES: Causes serious eye irritation. Will bond eyelids. Will cause excessive tearing.
SKIN: Bonds skin in seconds. May cause skin irritation. May cause sensitization by skin contact. Cyanoacrylates generate heat
on polymerization, so very large amounts will burn the skin.
INGESTION: Adhesive becomes solid in contact with saliva and may adhere to inside of mouth. Saliva will lift adhesive in 1-2
days. Not a toxic product.
INHALATION: Prolonged or excessive inhalation may cause respiratory tract irritation.
ACUTE EFFECTS: Avoid exposure to vapor concentration in confined areas.
CHRONIC EFFECTS: Frequent or prolonged contact may irritate the skin and cause a skin rash (dermatitis).
Page 2 of 7
11740026_FG04010
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SAFETY DATA SHEET
Date Issued : 10/10/2014
SDS No :
Date Revised : 03/30/2020
Revision No : 16
5. FIRE FIGHTING MEASURES
GENERAL HAZARD: Combustible liquid and vapor.Product polymerized to solid by water.
EXTINGUISHING MEDIA: Use dry chemical extinguisher or flush with large amounts of water.
HAZARDOUS COMBUSTION PRODUCTS: Can burn in fire, releasing irritanting vapors
EXPLOSION HAZARDS: None known.
FIRE FIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance.
FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH
approved or equivalent) and full protective gear.
FIRE EXPLOSION: None known.
SENSITIVE TO STATIC DISCHARGE: None known.
SENSITIVITY TO IMPACT: None known.
HAZARDOUS DECOMPOSITION PRODUCTS: Combustible by-products of carbon monoxide/dioxide.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Polymerize with water. Solid material may be scraped from surface.
LARGE SPILL: Polymerize with water. Increase ventilation to area. Solid material may be scraped from surface.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Use with adequate ventilation. Avoid contact with eyes, skin and clothing.
HANDLING: Avoid breathing (dust, vapor, mist, gas).
STORAGE: Store in a cool place in original container and protect from sunlight.
STORAGE TEMPERATURE: Ideal storage: 41-50F (5-10C)
SHELF LIFE: One year from the date of shipment from Pacer Technology, unless otherwise noted.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m3
ETHYL-2-CYANOACRYLATE
OSHA PEL TWA [1][1]
ACGIH TLV TWA 0.2 1.0
STEL [2]0.3 ppm [2]
Supplier OEL TWA 0.2 ppm
Hydroquinone OSHA PEL TWA 2
Footnotes:
1. NL = Not Listed
2. 1.5 mg/m3
ENGINEERING CONTROLS: Use only in a well ventilated area. Local exhaust ventilation may be necessary to control any air
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contaminants to within their TLVs during the use of this product.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear
splash-proof goggles.
SKIN: Use Nitrile gloves and aprons to prevent contact. Do not use PVC, Nylon or Cotton materials.
RESPIRATORY: Use only in a well-ventilated area. In case of insufficient ventilation, wear suitable respiratory equipment.
Recommended: Full-face NIOSH-approved respirator with organic vapor cartridge.
WORK HYGIENIC PRACTICES: Avoid direct contact and breathing vapor. Use with adequate ventilation. Wash hands with soap
and water after use.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety
shower.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Characteristic odor, intensely irritating.
ODOR THRESHOLD: Odor Threshold = 1 ppm
APPEARANCE:
pH: Not Established
PERCENT VOLATILE: No data available
FLASH POINT AND METHOD: 80°C (176°F) to 93.4°C (200°F) TAG CC
FLAMMABLE LIMITS: Not Established
AUTOIGNITION TEMPERATURE: 485°C (905°F)
VAPOR PRESSURE: < 0.2 mm Hg
VAPOR DENSITY: No data available
BOILING POINT: > 149°C (300°F)
FREEZING POINT: No data available
MELTING POINT: No data available
THERMAL DECOMPOSITION: Not Established
SOLUBILITY IN WATER: Insoluble
PARTITION COEFFICIENT: N-OCTANOL/WATER: No data available
EVAPORATION RATE: No data available
DENSITY: Not Established
SPECIFIC GRAVITY:
VISCOSITY #1:
MOLECULAR WEIGHT: Not Established
(VOC): < 20.00 g/L Per SCAQMD Method 316B.
10. STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION: No
CONDITIONS TO AVOID: Avoid temperatures above 176° F (80° C), moisture and alkalines.
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Transparent, colorless liquid.
1.06 g/mL at 25°C
30 to 70 Centipoise at 22°C (72°F)
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POSSIBILITY OF HAZARDOUS REACTIONS: Possible polymerization reaction in the presence of water, amines, alkalis and
alcohols.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide and other toxic or irritating compounds may
form when heated to decomposition.Oxides of nitrogen and probably hydrogen cyanide are also possible.
INCOMPATIBLE MATERIALS: Polymerized by water, alcohol, amines, alkaline materials.
COMMENTS: REACTIVITY: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50
ETHYL-2-CYANOACRYLATE > 5000 mg/kg > 2000 mg/kg
Hydroquinone 367.3 mg/kg > 2000 mg/kg
DERMAL LD50: > 2000 mg/kg
Notes: (Estimated)
ORAL LD50: > 5000 mg/kg
Notes: (Estimated)
INHALATION LC50: Vapors may be irritating. Recommended TWA 0.2ppm.
RESPIRATORY OR SKIN SENSITISATION: Possible skin sensitizer.
CARCINOGENICITY
IARC: None
NTP: None
OSHA: None
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA:
This material should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of
water.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in a manner consistent with federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME:
AIR (ICAO/IATA)
SHIPPING NAME: ID8000, CONSUMER COMMODITY, 9 (PKG LESS THAN OR EQUAL TO 30 kg G); or UN3334, AVIATION
REGULATED LIQUID, N.O.S (ETHYL CYANOACRYLATE), 9, III (LTD QTY, IP VOL LESS THAN OR EQUAL TO 5.0 L, OP
WGT LESS THAN OR EQUAL TO 30 kg G) *
VESSEL (IMO/IMDG)
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SHIPPING NAME: NOT REGULATED
COMMENTS: * This product may be shipped as EXCEPTED QUANTITIES OF CLASS 9, UN3334 (IP VOL LESS THAN OR
EQUAL TO 0.03 L, OP VOL LESS THAN OR EQUAL TO 1.0 L)
The transport information provided in this section only applies to the material formulation/itself, and is not specific to any
package/configuration.This information is not intended to convey all specific regulatory or operational requirements/information
relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or
country variations in regulations. It is the responsibility of the transporting organizations to follow all applicable laws, regulations,
and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HEALTH HAZARDS: Immediate Health, Delayed Health, Fire, Reactive.
313 REPORTABLE INGREDIENTS: None above reporting de minimus.
302/304 EMERGENCY PLANNING
EMERGENCY PLAN: None above reporting de minimus.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
Chemical Name CAS
ETHYL-2-CYANOACRYLATE 7085-85-0
Polymethyl methacrylate 9011-14-7
Hydroquinone 123-31-9
TSCA STATUS: All components are listed on or are exempt from listing on the Toxic Substances Control Act.
CLEAN AIR ACT
40 CFR PART 68---RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVENTION: Not applicable.
CALIFORNIA PROPOSITION 65: Consumer sizes of this product do not require a California Proposition 65 Warning based on
potential exposure in normal consumer use. The following information applies to industrial use: WARNING: This product
can expose you to chemicals including Sulfur Dioxide, which is known to the State of California to cause birth defects or other
reproductive harm. For more information go to www.P65Warnings.ca.gov.
16. OTHER INFORMATION
APPROVED BY: Pacer Technology Regulatory Affairs Department
PREPARED BY: Pacer Technology Regulatory Affairs Department Date Revised: 03/30/2020
REVISION SUMMARY: This SDS replaces the 08/15/2018 SDS. Revised: Section 1: APPROVED BY, PREPARED BY,
PRODUCT CODE.
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HMIS RATING
HEALTH 2
FLAMMABILITY 2
PHYSICAL HAZARD 1
PERSONAL PROTECTION
NFPA CODES
2
2 1
MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, Pacer
Technology does not assume any liability for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards which exist.
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SAFETY DATA SHEET
PRODUCT NAME: HP 8212 A DATE: June 1, 2018
MSDS NUMBER: HP 8212 A SUPERSEDES MSDS: June 1, 2015
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCT IDENTIFICATION NUMBER: HP 8212 A
CHEMICAL FAMILY: POLYMERIC ISOCYANATE
SECTION 2: HAZARD IDENTIFICATIONS
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical State and Appearance: Brown Liquid
Emergency Overview:
INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST
DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION
WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE
SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING.
Skin: HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS
IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING.
Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT).
Inhalation: HAZARDOUS IN CASE OF INHALATION (LUNG IRRITANT, LUNG SENSITIZER).
Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION.
Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime
inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m3, the highest dose tested. This is well above
the recommended TLV of 5ppb (0.05 mg/m3). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No
birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric
MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of
maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop
isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well
below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic
attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust,
cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years.
Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung
function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause
reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can
develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure.
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Aggravated Medical Conditions:
Individuals who are sensitized to isocyanates and those with preexisting lung diseases of conditions, including non-specific
bronchial hyper reactivity or asthma, must avoid all exposure to isocyanates.
GHS Label Elements:
Hazard pictograms
Signal Word: Danger
Hazard statement: Harmful if inhaled. Causes skin and eye irritation.
May Cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
SECTION 3: HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 100%
*Occupational Exposure Limit(s) if available, are listed in section 8.
SECTION 4: FIRST AID MEASURES
Eyes: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the
eyelids open. Get immediate medical attention.
Skin Contact: Remove contaminated clothing. In case of contact, immediately wash skin with soap and plenty of water.
If symptoms develop obtain medical attention. Contaminated clothing should be thoroughly cleaned. An MDI study has
demonstrated that a polyglycol-based skin cleaner or corn oil may be more effective than soap and water.
Inhalation: If excessive inhalation of vapor occurs, remove patient to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical
attention.
Ingestion: If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if the victim
is unconscious or having convulsions. Get immediate medical attention.
NOTES TO PHYSICIANS: There is no specific antidote to counteract the effects of MDI. Symptomatic and supportive
therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.
Other First Aid Procedures: Medical supervision of all employees who handle or come into contact with MDI is
recommended. Pre-employment and periodic medical examinations with respiratory function test (PEV, PVC, as a
minimum are suggested). Persons with asthmatic conditions chronic bronchitis, other chronic respiratory diseased,
recurrent eczema or pulmonary sensitization should be excluded from working with MDI. Once a person is diagnosed as
having pulmonary sensitization (allergic asthma) to MDI, further exposure is not permissible.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >93.3°C, Closed Cup.
Autoignition: >600°C.
Flammable Limits: Not available. Christensen Arms AO Modification 9/7/23
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Products of Combustion: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks
and static discharge or combustible materials.
Fire Fighting Media and Instructions: Small Fire: Use DRY chemical powder.
Large Fire: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be
used to avoid inhalation of the product.
Special Remarks on Fire Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture closed
containers. This reaction accelerates at higher temperatures.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
Small Spill and Leak: Clean-up should only be performed by trained personnel. People dealing with major spillages
should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further
leakage, spillage or entry into drains.
Large Spill and Leak: Contain and absorb large spillages onto an inert, non-flammable adsorbent carrier (such as earth
or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spillage area
with
Liquid decontaminant. Test atmosphere for MDI. Neutralize small spillages with decontaminant. Remove and properly
dispose of residues (see Section 13 for disposal considerations). Notify applicable government authorities if release is
reportable. The CERCLA RQ for 4,4-MDI is 5000 lbs (see CERCLA in Section 15).
Decontaminant: Preparation of Decontaminant Solution: Prepare a decontamination solution of 0.2-0.5% liquid detergent
and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium
hydroxide). Follow the precautions on the supplier’s material safety data sheets when preparing and using solution.
Use of Decontamination Solution: Allow deactivated material to stand for at least 30 minutes before shoveling into drums.
Do not tighten the bungs. Mixing with wet earth is also effective, but slower.
SECTION 7: HANDLING AND STORAGE
Handling: Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that
the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly
because of the possibility of blockage. Avoid breathing aerosols, mists and vapors. (See Section 8 Exposure Control for
details.)
Storage: Keep containers properly sealed and when stored indoors, in a well ventilated area. Keep contents away from
moisture. Due to reaction with water, producing CO2-gas, a hazardous build-up of pressure could result if contaminated
containers are re-sealed. Do not reseal contaminated containers. Uncontaminated containers, free of moisture, may be
resealed only after placing under a nitrogen blanket. Do not store in containers made of cooper, cooper alloys or
galvanized surfaces.
Ideal storage temperature is 16-38°C (60-100°F).
Keep stocks of decontaminant (see Section 6) readily available.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Preventive Measures: Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
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Engineering Controls: Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For
guidance on engineering control measures refer to publications such as the ACGIH current edition of “ Industrial
Ventilation, a manual of Recommended Practice”.
Personal Protection
Eyes: Chemical safety goggles. If there is a potential for splashing, use a full face shield.
Body and Hands: The following protective materials are recommended: Gloves-neoprene, nitrile rubber, butyl
rubber. Thin latex disposable gloves should be avoided for repeated or long term use. Protective clothing should be
selected and used in accordance with “Guidelines for the Selection of Chemical Protective Clothing” published by ACGIH.
Respiratory: When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH
positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges
and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has
been developed in accordance with the OSHA respiratory protection standard (29 C.F.R. 1910.134).
Personal Protection in Case of a Large Spills: Splash goggles. Full suit. Vapor respirator or a self-contained breathing
apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Product Name Exposure Limits
4,4-Diphenylmethane Diisocyanate ACGIH TLV 0.05 mg/m3 (8-hour, 40 hours/week) OSHA PEL Ceiling Limit 0.20 mg/m3
NIOSH REL/TWA 0.05 mg/m3 (10-hour, 40 hours/week)
NIOSH REL/CEILING 0.20 mg/m3 (10-minutes)
Exposure control/ personal protection: Medical supervision of all employees who handle or come in contact with
respiratory sensitizers is recommended. Persons with respiratory problems including asthmatic-type conditions, chronic
Bronchitis, other chronic respiratory diseases or recurrent skin eczema or skin allergies should be evaluated for their
suitability of working with this product. Once a person is diagnosed as sensitized, no further exposure to the material that
caused the sensitization should be permitted. The Occupational Exposure limits do not apply to previously sensitized
individuals.
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Brown Liquid Slightly Musty
BOILING POINT (°C) >300°C
MELTING POINT (°F/°C) Not available
SPECIFIC GRAVITY ( WATER = 1) 1.23 gr/ml
BULK DENSITY 9.0 lb/gal
pH Not applicable
VAPOR PRESSURE (MM Hg.) 0.000004 mmHg @ 25°C
VAPOR DENSITY (AIR-1) 8.5
VISCOSITY 900-1300 cps @ 25° C
PERCENT (%) VOC 0%
FLASH POINTS >93.3°C (230°F) Closed Cup
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable at room temperature.
Incompatibility with various Substances: Reactive with moisture.
Conditions of Instability: Avoid high temperatures. Avoid freezing.
Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
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Hazardous Polymerization: Polymerization may occur at elevated temperatures in the presence of alkalies, tertiary
amines and metal compounds.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity to Animals: LD50 Rat Oral: >5000mg/kg
LD50 Rabbit Dermal: >5000 mg/kg
Inhalation: This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapor or
aerosol at levels above the occupational exposure limit could cause respiratory sensitization. Symptoms may include
irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty
in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive
response to even minimal concentrations of MDI may develop in sensitized persons.
Skin Contact: Moderate irritant. Repeated and/or prolonged contact may cause skin sensitization. There is limited
evidence from animal studies that skin contact may play a role in respiratory sensitization. These results emphasize the
need for protective clothing including gloves to be worn at all times when handling these chemicals or in maintenance
work.
Eye Contact: The vapor, aerosol, and liquid are irritant.
Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Based on the acute oral LD50 this product is
considered practically non-toxic by ingestion.
Remarks: Short term test have shown that it is unlikely to be genotoxic. (BUTYLATEDHYDROXYTOLUENE)
Carcinogenic Effects: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not
regulated as carcinogens by OSHA, and not listed as carcinogens by NTP.
Mutagenic Effects: There is no substantial evidence of mutagenic potential.
Reproductive Effects: No adverse reproductive effects are anticipated.
Teratogenic Effects: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at
doses that were extremely toxic (including lethal) to the mother. Fetotoxicity was not observed at doses that were not
maternally toxic. The doses used in these studies were maximal respirable concentrations well in excess of the defined
limits.
Remark: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to
atmosphere of respirable polymeric MDI aerosol at concentrations of 0, 0.2, 1 or 6 mg/m3. No adverse effects were
observed at 0.2 mg/m3. At the 1mg/m3 concentration, minimal nasal and lung irritant effect were seen. Only at the top
concentration (6.0 mg/m3) was there an increased incidence of a benign tumor of the lung (adenoma). One malignant
pulmonary tumor (adenocarcinoma) was seen in the 6.0 mg/m3 group. MDI administration to rats in this study did not
change the distribution and incidence of tumors from those seen in control animals. The increased incidence of lung
tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In
the absence of prolonged exposure to high concentration leading to chronic irritation and lung damage, it is highly unlikely
that tumor formation will occur.
There are reports that excessive chronic exposure to diisocyanates may result in permanent decrease in lung function.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: Polymeric MDI. LC50 (Zebra Fish) >1000 ml/l. EC50 (Daphnia magna) (24 hours) >1000 mg/l EC50 (E. Coli)
> 100ml/l.
Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise
based on consideration of the production and use of the substance.
Persistence and Degradation: Immiscible with water, but will react with water to produce inert and non-biodegradable
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SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information: The generation of waste should be avoided or minimized wherever possible.
Disposal should be in accordance with local, state, provincial or national regulations, This material is not hazardous waste
under RCRA 40 CFR 261. Small quantities should be treated with a decontaminant solution (see Section 6). The treated
waste is not a hazardous material under RCRA 40 CFR 261. Chemical waste, even small quantities, should never be
poured down drains, sewers or waterways.
Empty containers should be decontaminated and either passed to an approved drum recycler or destroyed.
SECTION 14: TRANSPORT INFORMATION
For major spills call Chemtrec (800-424-9300).
DOT Classification: Single containers less than 5000 lbs. are not regulated. Single containers with 5000 lbs. Or more of
4,4-Methylene Diphenyl Diisocyanate are regulated as: Other Regulated Substances, Liquid, N.O.S. (Methylene Diphenyl
Diisocyanate), 9, NA3082, PGlll, RQ.
TDG Classification: Not regulated.
IMO/IMDG Classification: Not regulated.
ICAO/IATA Classification: Not regulated.
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification: Class: Toxic
Class: Irritating substance.
Class: Sensitizing substance.
TSCA 8(b) inventory: All Ingredients Listed
EPCRA Section 313 (40 CFR 372)
Diisocyanate Compounds (Category Code N120) 100%
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
This product does not contain nor is it manufactured with ozone depleting substances.
State Regulations:
Canadian Regulations: This material has been classified in accordance with the hazard criteria of the CPR (Controlled
Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
WHMIS (Canada): Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
CEPA: DSL/NDSL: All Ingredients Listed.
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SECTION 16: OTHER INFORMATION
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN AND EYES. MAY BE
HARMFULL IF INHALED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 2 Fire Hazard: 1 Reactivity: 1 Health: 2 Fire Hazard: 1 Reactivity:
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date
of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICATION OF SUCH INFORMATION AND
RECOMMENDATIONS AND SUITABILITY OF ANY PRODUCT FOR IRS OWN PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARD AND SHOULD BE USED WITH CAUTION, WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS
PUBLICATION, NO GUARANTEE IS MADE THAT ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon the manufacturing
circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers,
processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APROVED AND AUTHORIZED BY: Enes Christensen Arms AO Modification 9/7/23
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SAFETY DATA SHEET
PRODUCT NAME: HP 8212 B Black DATE: June 01,2015
MSDS NUMBER: HP 8212 B SUPERSEDES MSDS: April 20, 2012
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCTION IDENTIFICATION NUMBER: HP 8212 B Black
CHEMICAL FAMILY: POLYETHER POLYOL BLEND
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
Physical State: Liquid
Potential Acute Heath Effects:
Eyes Corrosive to eyes.
Skin Corrosive to skin on contact. Skin contact may produce burns.
Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking or shortness of breath.
Ingestion May cause burns to mouth, throat and stomach.
GENERAL INFORMATION: Read the entire MSDS for more thorough evaluation of the hazards.
GHS Label Elements:
Hazard pictograms
SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 55-90 %
GLYCOLS Mixture 0-10 %
*Occupational Exposure Limit(s), if available, are listed in Section 8.
Christensen Arms AO Modification 9/7/23
2
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: In case of contact, immediately wash skin with soap and plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention
immediately.
Inhalation: If excessive inhalation of vapor occurs, remove to fresh air. If breathing is difficult, qualified
personnel may administer oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Notes to Physician: Symptomatic treatment and supportive therapy as indicated. Administer oxygen if
necessary.
Following severe exposure the patient should be kept under medical review for at least 48 hours as
delayed pulmonary edema may develop.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >212°F Closed Cup
Auto Ignition Temp: Not available.
Flammable Limits: Not available.
Products of Combustion:
Thermal Decomposition products are toxic and may include oxides of carbon and nitrogen,
amines, possibly other irritating gases.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire):
Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to
avoid inhalation of the product.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
See Safety Data Sheet section 8 Personal Protective Equipment
Small Spill and Leak Absorb with an inert material and put the material in an appropriate waste disposal container.
Large Spill and Leak Corrosive liquid. Toxic liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water
spray to reduce vapors. Prevent entry into sewers, basements of confined area; dike if needed. Eliminate
all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is
not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Christensen Arms AO Modification 9/7/23
3
SECTION 7: HANDLING AND STORAGE
Handling Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in case of insufficient ventilation or where operational procedures
demand it. For guidance on engineering control measures refer to publications such as the ACGIH
current edition of ‘Industrial Ventilation, a manual of Recommended Practice.’
Personal Protection
Eyes Chemical safety goggles. If there is a potential for splashing, use a full-face shield.
Body and Hands Full chemical suit. Gloves.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Personal Protection in case of a Large Spill
Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots.
Gloves.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Black Slight Odor
BOILING POINT (°F/°C) Not determined
MELTING POINT (°F/°C) Not determined
SPECIFIC GRAVITY ( WATER = 1) 1.12 kg/l
BULK DENSITY 8.8 lb/gal
pH OF UNDILUTED PRODUCT Not determined
VAPOR PRESSURE (MM Hg.) Not determined
VAPOR DENSITY (AIR-1) >1
VISCOSITY 600 to 900 cps @ 25° C
PERCENT (%) VOC 0
SOLUBILITY IN WATER Soluble
SECTION 10: STABILITY AND REACTIVITY
Stability and Reactivity This product is stable.
Conditions of Stability Avoid moisture to protect product quality.
Incompatibility with Various Substances Christensen Arms AO Modification 9/7/23
4
Slightly reactive to reactive with oxidizing agents, alkalis.
Hazardous Decomposition Products
Thermal decomposition products are toxic and may include oxides of carbon and
nitrogen, amines, possibly other irritating gases.
Hazardous Polymerization Will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
No applicable data for this section.
SECTION 12I: ECOLOGICAL INFORMATION
No applicable data for this section.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information Incinerate or landfill in a licensed facility. Do not discharge into waterways of sewer systems.
Container Disposal: Steel drums must be emptied (as defined by RCRA, Section 261.7 or state
regulations that may be more stringent) and can be sent to a licensed drum reconditoiner for reuse, a
scrap metal dealer or an approve landfill. Drums destined for scrap dealer of landfill must be punctured or
crushed to prevent reuse.
Material for disposal should be placed in appropriated sealed containers to avoid potential human and
environmental exposure. It is the responsibility of the generator to comply with all federal, state,
provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal
contractor and environmental agency for relevant laws and regulations. Under the US, Resource
Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determined at
the time of disposal, whether the product meets relevant waste classification and to assure proper
disposal.
SECTION 14: TRANSPORT INFORMATION
Transportation Emergency Number 1-800-424-9300 (CHEMTREC).
DOT Classification Non Regulated
TDG Classification Non Regulated
IMO/IMDG Classification Non Regulated
ICAO/IATA Classification Non Regulated
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification
Class: Corrosive material
TSCA 8(b) inventory: All ingredients Listed.
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
Christensen Arms AO Modification 9/7/23
5
Any spill or release above the RC must be reported to the National Response Center (800-424-8802)
SARA 313 toxic chemical notification and release reporting: None
State Regulations California prop 65: No ingredients listed.
Canadian Regulations
This product has been classified in accordance with the hazard criteria of the CPR
(Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the
information required by the CPR.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA DSL/NDSL Not all Ingredients Listed.
SECTION 16: OTHER INFORMATION
Causes respiratory tract, eye and skin burns.
Harmful if inhaled.
May be harmful if swallowed.
Contains material, which may cause birth defects based on animal data.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 1 Health: 1
Fire Hazard: 1 Fire Hazard: 1
Reactivity: 0 Reactivity: 0
Notice to Reader
While the information and recommendations in this publication are to the best of our knowledge, information and
belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARANTY, EXPRESS
OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONSAND THE SUITABILITY OF ANY PRIDUCT FOR ITS OWN PARTICULAR
PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZAEDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be
determined by the user and made known to handlers, processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APPROVED AND AUTHORIZED BY: Enes Torlic
Christensen Arms AO Modification 9/7/23
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Safety Data Sheet
Section 1: Identification
Product Identifier/Name Prodraw BB
Product code ඵϭϬϯϴϲ
Relevant identified uses of the substance or mixture and uses advised against
Recommended use ඵKŝůďĂƐĞĚŵĞƚĂůĨŽƌŵŝŶŐůƵďƌŝĐĂŶƚ
Restrictions on use ඵ&ŽƌŝŶƚĞŶĚĞĚŝŶĚƵƐƚƌŝĂůƵƐĞŽŶůLJ
Details of the supplier of the safety data sheet
Manufacturer ඵtĂůůŽǀĞƌKŝůŽŵƉĂŶLJ
ϮϭϴϰϱƌĂŬĞZŽĂĚ
^ƚƌŽŶŐƐǀŝůůĞ͕K,ϰϰϭϰϵ
hŶŝƚĞĚ^ƚĂƚĞƐ
ǁǁǁ͘ǁĂůůŽǀĞƌ͘ĐŽŵ
Telephone (General)ඵ;ϰϰϬͿϮϯϴͲϵϮϱϬ
Emergency telephone number ඵ,DdZ͗ϴϬϬͲϰϮϰͲϵϯϬϬ;ŝŶƚŚĞh͘^͘Ϳ͕;нϭͿϳϬϯͲϱϮϳͲϯϴϴϳ;ŽƵƚƐŝĚĞƚŚĞh͘^͘Ϳ
Section 2: Hazard Identification
Classification of the substance or mixture
In accordance with 29 CFR 1910.1200 OSHA HCS 2012
EŽƚůĂƐƐŝĨŝĞĚ
Label elements
Signal word ඵEŽŶĞ
Hazard symbol ඵEŽŶĞ
Hazard statements ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚŵĞĞƚƚŚĞĐƌŝƚĞƌŝĂĨŽƌĐůĂƐƐŝĨŝĐĂƚŝŽŶ
Precautionary statements
Prevention ඵEŽƚĂƉƉůŝĐĂďůĞ
Response ඵEŽƚĂƉƉůŝĐĂďůĞ
Storage ඵEŽƚĂƉƉůŝĐĂďůĞ
Disposal ඵEŽƚĂƉƉůŝĐĂďůĞ
Hazards not otherwise classified ඵEŽƚĂƉƉůŝĐĂďůĞ
Other hazards ඵEŽŶĞĚĞƚĞƌŵŝŶĞĚ
Section 3: Composition/Information on Ingredients
Substances ඵEŽƚĂƉƉůŝĐĂďůĞ
Mixtures
,ĂnjĂƌĚŽƵƐŽŵƉŽŶĞŶƚƐ
Chemical Name %(Wt.) CAS #
EŽŶĞ
Christensen Arms AO Modification 9/7/23
WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ
ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϮŽĨϳ
&ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ
K^,,^ϮϬϭϮ
Section 4: First-Aid Measures
Description of first aid measures
Inhalation ඵDŽǀĞǀŝĐƚŝŵƚŽĨƌĞƐŚĂŝƌŝĨĂĚǀĞƌƐĞĞĨĨĞĐƚƐĂƌĞŽďƐĞƌǀĞĚ͘
Skin ඵ/&KE^</E͗tĂƐŚƐŬŝŶǁŝƚŚƐŽĂƉĂŶĚǁĂƚĞƌ͘ZĞŵŽǀĞĐŽŶƚĂŵŝŶĂƚĞĚĐůŽƚŚŝŶŐ
ĂŶĚǁĂƐŚďĞĨŽƌĞƌĞƵƐĞ͘/ĨƐŬŝŶŝƌƌŝƚĂƚŝŽŶŽĐĐƵƌƐ͗'ĞƚŵĞĚŝĐĂůĂĚǀŝĐĞͬĂƚƚĞŶƚŝŽŶ͘
Eye ඵ/&/Ez^͗ZŝŶƐĞĐĂƵƚŝŽƵƐůLJǁŝƚŚǁĂƚĞƌĨŽƌƐĞǀĞƌĂůŵŝŶƵƚĞƐ͘ZĞŵŽǀĞ
ĐŽŶƚĂĐƚůĞŶƐĞƐ͕ŝĨƉƌĞƐĞŶƚĂŶĚĞĂƐLJƚŽĚŽ͘ŽŶƚŝŶƵĞƌŝŶƐŝŶŐ͘/ĨĞLJĞŝƌƌŝƚĂƚŝŽŶ
ƉĞƌƐŝƐƚƐ͗'ĞƚŵĞĚŝĐĂůĂĚǀŝĐĞͬĂƚƚĞŶƚŝŽŶ͘
Ingestion ඵŽEKdŝŶĚƵĐĞǀŽŵŝƚŝŶŐ͘^ĞĞŬŵĞĚŝĐĂůĂƚƚĞŶƚŝŽŶ͘
Most important symptoms and effects
Acute ඵŝƌĞĐƚĐŽŶƚĂĐƚǁŝƚŚƉƌŽĚƵĐƚĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞƐůŝŐŚƚĞLJĞŝƌƌŝƚĂƚŝŽŶ͘
Delayed ඵWƌŽůŽŶŐĞĚͬƌĞƉĞĂƚĞĚĞdžƉŽƐƵƌĞŵĂLJĐĂƵƐĞŵŝůĚƐŬŝŶŝƌƌŝƚĂƚŝŽŶŝŶƐƵƐĐĞƉƚŝďůĞŝŶĚŝǀŝĚƵĂůƐ͘
Indication of any immediate medical attention and special treatment needed
Note to Physician ඵůůƚƌĞĂƚŵĞŶƚƐƐŚŽƵůĚďĞďĂƐĞĚŽŶŽďƐĞƌǀĞĚƐŝŐŶƐĂŶĚƐLJŵƉƚŽŵƐŽĨ
ĚŝƐƚƌĞƐƐŝŶƚŚĞƉĂƚŝĞŶƚ͘ŽŶƐŝĚĞƌĂƚŝŽŶƐŚŽƵůĚďĞŐŝǀĞŶƚŽƚŚĞƉŽƐƐŝďŝůŝƚLJ
ƚŚĂƚŽǀĞƌĞdžƉŽƐƵƌĞƚŽŵĂƚĞƌŝĂůƐŽƚŚĞƌƚŚĂŶƚŚŝƐƉƌŽĚƵĐƚŵĂLJŚĂǀĞŽĐĐƵƌƌĞĚ͘
Section 5: Fire-Fighting Measures
Extinguishing media
Suitable Extinguishing Media ඵZĞŐƵůĂƌĨŽĂŵ͕ĐĂƌďŽŶĚŝŽdžŝĚĞ͕ĚƌLJĐŚĞŵŝĐĂů͘
Unsuitable Extinguishing ඵǀŽŝĚƚŚĞƵƐĞŽĨƐƚƌĞĂŵŝŶŐǁĂƚĞƌ͕ĂƐƚŚŝƐŵĂLJƐƉƌĞĂĚƚŚĞĨŝƌĞ͘
Media
Special hazards arising from the substance or mixture
Unusual Fire and Explosion ඵEŽƵŶƵƐƵĂůŚĂnjĂƌĚŶŽƚĞĚ͘dƌĞĂƚĂƐŽŝůĨŝƌĞ͘
Hazards
Hazarous Combustion ඵ^ŵŽŬĞ͕ƐŽŽƚ͕ĨƵŵĞƐŽƌǀĂƉŽƌƐ͕ŽdžŝĚĞƐŽĨ͗ĐĂƌďŽŶĂŶĚƐƵůĨƵƌ͘
Products
Special Protective Equipment ඵ^ƚƌƵĐƚƵƌĂůĨŝƌĞĨŝŐŚƚĞƌƐΖƉƌŽƚĞĐƚŝǀĞĐůŽƚŚŝŶŐǁŝůůŽŶůLJƉƌŽǀŝĚĞůŝŵŝƚĞĚ
and Precautions for Firefighters ƉƌŽƚĞĐƚŝŽŶ͘tĞĂƌĐŚĞŵŝĐĂůƉƌŽƚĞĐƚŝǀĞĐůŽƚŚŝŶŐƚŚĂƚŝƐƐƉĞĐŝĨŝĐĂůůLJ
ƌĞĐŽŵŵĞŶĚĞĚďLJƚŚĞŵĂŶƵĨĂĐƚƵƌĞƌ͘/ƚŵĂLJƉƌŽǀŝĚĞůŝƚƚůĞŽƌŶŽƚŚĞƌŵĂů
ƉƌŽƚĞĐƚŝŽŶ͘tĞĂƌƉŽƐŝƚŝǀĞƉƌĞƐƐƵƌĞƐĞůĨͲĐŽŶƚĂŝŶĞĚďƌĞĂƚŚŝŶŐĂƉƉĂƌĂƚƵƐ
;^Ϳ͘tĂƚĞƌƐƉƌĂLJŵĂLJďĞƵƐĞĚƚŽĐŽŽůĐŽŶƚĂŝŶĞƌƐĞdžƉŽƐĞĚƚŽĨŝƌĞ͘
Section 6: Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Personal Precautions ඵtĞĂƌĂƉƉƌŽƉƌŝĂƚĞƉƌŽƚĞĐƚŝǀĞĞƋƵŝƉŵĞŶƚŝŶĐůƵĚŝŶŐƌĞƐƉŝƌĂƚŽƌLJ
ƉƌŽƚĞĐƚŝŽŶĂƐĐŽŶĚŝƚŝŽŶƐǁĂƌƌĂŶƚ͘ŽŶŽƚƚŽƵĐŚŽƌǁĂůŬƚŚƌŽƵŐŚƐƉŝůůĞĚ
ŵĂƚĞƌŝĂů͘
Environmental precautions ඵǀŽŝĚƌƵŶŽĨĨƚŽǁĂƚĞƌǁĂLJƐĂŶĚƐĞǁĞƌƐ͘
Methods and material for containment and cleaning up
Containment/Clean-up ඵZĞĐŽǀĞƌĨƌĞĞůŝƋƵŝĚĨŽƌƌĞĐLJĐůĞŽƌĚŝƐƉŽƐĂů͘ĚĚĂďƐŽƌďĂŶƚƚŽƐƉŝůůĂƌĞĂ͘
Measures >Z'^W/>>^͗ŝŬĞĨĂƌĂŚĞĂĚŽĨůŝƋƵŝĚƐƉŝůůĨŽƌůĂƚĞƌĚŝƐƉŽƐĂů͘
Christensen Arms AO Modification 9/7/23
WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ
ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϯŽĨϳ
&ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ
K^,,^ϮϬϭϮ
Section7: Handling and Storage
Precautions for safe handling
Handling ඵKďƚĂŝŶƐƉĞĐŝĂůŝŶƐƚƌƵĐƚŝŽŶƐďĞĨŽƌĞƵƐĞ͘ŽŶŽƚďƌĞĂƚŚĞŵŝƐƚŽƌǀĂƉŽƌƐ͘WƌĞŐŶĂŶƚŽƌ
ďƌĞĂƐƚĨĞĞĚŝŶŐǁŽŵĞŶŵƵƐƚŶŽƚŚĂŶĚůĞƚŚŝƐƉƌŽĚƵĐƚ͘
ŽŶŽƚŵŝdžǁŝƚŚŝŶĐŽŵƉĂƚŝďůĞŵĂƚĞƌŝĂůƐ͘ŵƉƚLJĐŽŶƚĂŝŶĞƌĐŽŶƚĂŝŶƐƉƌŽĚƵĐƚƌĞƐŝĚƵĞ
ǁŚŝĐŚŵĂLJĞdžŚŝďŝƚŚĂnjĂƌĚƐŽĨƉƌŽĚƵĐƚ͘ǀŽŝĚƌĞůĞĂƐĞƚŽƚŚĞĞŶǀŝƌŽŶŵĞŶƚ͘
Conditions for safe storage, including any incompatibilities
Storage ඵ^ƚŽƌĞŝŶĂĚƌLJ͕ǁĞůůǀĞŶƚŝůĂƚĞĚƉůĂĐĞ͘<ĞĞƉĐŽŶƚĂŝŶĞƌƚŝŐŚƚůLJĐůŽƐĞĚǁŚĞŶŶŽƚŝŶƵƐĞ͘
<ĞĞƉĂǁĂLJĨƌŽŵŽƉĞŶĨůĂŵĞĂŶĚŝŶĐŽŵƉĂƚŝďůĞŵĂƚĞƌŝĂůƐ͘
Incompatible Materials ඵ^ƚƌŽŶŐŽdžŝĚŝnjŝŶŐĂŐĞŶƚƐ͘
General Industrial Hygiene ඵ,ĂŶĚůĞŝŶĂĐĐŽƌĚĂŶĐĞǁŝƚŚŐŽŽĚŝŶĚƵƐƚƌŝĂůŚLJŐŝĞŶĞĂŶĚƐĂĨĞƚLJƉƌĂĐƚŝĐĞ͘
Considerations tĂƐŚƚŚŽƌŽƵŐŚůLJǁŝƚŚƐŽĂƉĂŶĚǁĂƚĞƌĂĨƚĞƌŚĂŶĚůŝŶŐĂŶĚďĞĨŽƌĞĞĂƚŝŶŐ
ŽƌĚƌŝŶŬŝŶŐ͘^ĂĨĞƚLJƐŚŽǁĞƌĂŶĚĞLJĞǁĂƐŚƐŚŽƵůĚďĞĂǀĂŝůĂďůĞĐůŽƐĞƚŽ
ǁŽƌŬƐƚĂƚŝŽŶ͘
Environmental Exposure ඵ&ŽůůŽǁďĞƐƚƉƌĂĐƚŝĐĞĨŽƌƐŝƚĞŵĂŶĂŐĞŵĞŶƚĂŶĚĚŝƐƉŽƐĂůŽĨǁĂƐƚĞ͘
Controls ǀŽŝĚƌĞůĞĂƐĞƚŽƚŚĞĞŶǀŝƌŽŶŵĞŶƚ͘
Section 8: Exposure Controls/Personal Protection
Exposure Contols
PEL/TLV
/ŶŐƌĞĚŝĞŶƚK^,;W>Ϳ '/,;d>sͿ KƚŚĞƌ
KŝůŵŝƐƚ͕ŵŝŶĞƌĂů ϱŵŐͬDϯ ϱŵŐͬDϯ ^d>ϭϬŵŐͬDϯ
Engineering ඵhƐĞĂĚĞƋƵĂƚĞŵĞĐŚĂŶŝĐĂů;ŐĞŶĞƌĂůͿǀĞŶƚŝůĂƚŝŽŶŽƌůŽĐĂůĞdžŚĂƵƐƚĂƐŶĞĞĚĞĚ
Measures/Controls ƚŽĐŽŶƚƌŽůĐŽŶĐĞŶƚƌĂƚŝŽŶŽĨĂŝƌďŽƌŶĞĐŽŶƚĂŵŝŶĂŶƚƐďĞůŽǁĂƉƉůŝĐĂůĞdžƉŽƐƵƌĞ
ůŝŵŝƚǀĂůƵĞƐ͘
Personal Protective Equipment
Pictograms
Respiratory ඵEŽƚŶĞĐĞƐƐĂƌLJƵŶĚĞƌĐŽŶĚŝƚŝŽŶƐŽĨŶŽƌŵĂůƵƐĞ͘/ŶĐĂƐĞŽĨŝŶƐƵĨĨŝĐŝĞŶƚǀĞŶƚŝůĂƚŝŽŶ͕
ǁĞĂƌƐƵŝƚĂďůĞƌĞƐƉŝƌĂƚŽLJĞƋƵŝƉŵĞŶƚŝĨĞdžƉŽƐƵƌĞůŝŵŝƚƐĂƌĞĞdžĐĞĞĚĞĚ͘
Eye/Face ඵtĞĂƌƐĂĨĞƚLJŐůĂƐƐĞƐŽƌŐŽŐŐůĞƐ͘
Hands ඵtĞĂƌƉƌŽƚĞĐƚŝǀĞŐůŽǀĞƐͲŶĞŽƉƌĞŶĞ͕ďƵƚLJůŽƌŶŝƚƌŝůĞƌƵďďĞƌǁŝƚŚĐƵĨĨƐ͘
Skin/Body ඵtŚĞƌĞĞdžƚĞŶƐŝǀĞĚĞƌŵĂůĞdžƉŽƐƵƌĞŵĂLJďĞĞdžƉĞĐƚĞĚ͕ĞŝƚŚĞƌĂĐŚĞŵŝĐĂů
ƐƵŝƚŽƌĐŚĞŵŝĐĂůĂƉƌŽŶǁŝůůďĞŶĞĞĚĞĚ͘
Section 9: Physical and Chemical Properties
Information on physical and chemical properties
Appearance KƉĂƋƵĞƚĂŶƉĂƐƚĞ
Odor >ŽǁŽĚŽƌ
Odor Threshold EŽƚĚĞƚĞƌŵŝŶĞĚ
Christensen Arms AO Modification 9/7/23
WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ
ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϰŽĨϳ
&ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ
K^,,^ϮϬϭϮ
pH EŽƚĂƉƉůŝĐĂďůĞ
Melting Point/Freezing Point EŽƚĚĞƚĞƌŵŝŶĞĚ
Boiling Point EŽƚĚĞƚĞƌŵŝŶĞĚ
Flash Point ϯϯϴ϶&dLJƉŝĐĂů͕K
Evaporation Rate Eŝů
Flammability (solid, gas)EŽƚĂƉƉůŝĐĂďůĞ
Flammability Limits EŽƚĚĞƚĞƌŵŝŶĞĚ
Vapor Pressure Eŝů
Vapor Density (Air=1)хϭ
Specific Gravity/Relative ϭ͘ϭϱ
Solubilities ^ŽůƵďůĞŝŶŵŽƐƚƉĞƚƌŽůĞƵŵƉƌŽĚƵĐƚƐ͘/ŶƐŽůƵďůĞŝŶǁĂƚĞƌ͘
Octanol/Water Partition coefficient EŽƚĚĞƚĞƌŵŝŶĞĚ
Autoignition temperature EŽƚĚĞƚĞƌŵŝŶĞĚ
Decomposition temperature EŽƚĚĞƚĞƌŵŝŶĞĚ
Viscosity хϮϱĐ^ƚΛϰϬ϶
Section 10: Stability and Reactivity
Reactivity ඵEŽĚĂŶŐĞƌŽƵƐƌĞĂĐƚŝŽŶŬŶŽǁŶƵŶĚĞƌĐŽŶĚŝƚŝŽŶƐŽĨŶŽƌŵĂůƵƐĞ͘
Chemical stability ඵ^ƚĂďůĞƵŶĚĞƌŶŽƌŵĂůƚĞŵƉĞƌĂƚƵƌĞƐĂŶĚƉƌĞƐƐƵƌĞƐ͘
Possibility of hazardous reaction ඵEŽƚĚĞƚĞƌŵŝŶĞĚ
Conditions to avoid ඵEŽƚĚĞƚĞƌŵŝŶĞĚ
Incompatible materials ඵŽŶŽƚŵŝdžǁŝƚŚƐƚƌŽŶŐŽdžŝĚĂŶƚƐ͘
Hazardous decomposition ඵEŽŶĞŬŶŽǁŶƵŶĚĞƌŶŽƌŵĂůƵƐĞ͘
products.
Section 11: Toxicological Information
Information on the likely routes of exposure; symptoms; and acute, delayed and chronic effects
Inhalation ඵKǀĞƌĞdžƉŽƐƵƌĞƚŽŵŝƐƚƐŽƌǀĂƉŽƌƐŵĂLJŝƌƌŝƚĂƚĞƌĞƐƉŝƌĂƚŽƌLJƚƌĂĐƚ͘
Ingestion ඵ/ŶŐĞƐƚŝŽŶŽĨĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞŐĂƐƚƌŽŝŶƚĞƐƚŝŶĂůŝƌƌŝƚĂƚŝŽŶ͘
Eye ඵŝƌĞĐƚĐŽŶƚĂĐƚǁŝƚŚĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞŵŝůĚĞLJĞŝƌƌŝƚĂƚŝŽŶ
ďĂƐĞĚŽŶĐŽŵƉŽŶĞŶƚŝŶĨŽƌŵĂƚŝŽŶ͘
Skin corrosion/irritation ඵWƌŽůŽŶŐĞĚͬƌĞƉĞĂƚĞĚĞdžƉŽƐƵƌĞƚŽĐŽŶĐĞŶƚƌĂƚĞŵĂLJĐĂƵƐĞŵŝůĚƐŬŝŶŝƌƌŝƚĂƚŝŽŶ
ŝŶƐŽŵĞŝŶĚŝǀŝĚƵĂůƐ͘
Numerical measures of toxicity
Acute toxicity EŽƚůĂƐƐŝĨŝĞĚ
Skin corrosion/irritation EŽƚůĂƐƐŝĨŝĞĚ
Serious eye damage/irritation EŽƚůĂƐƐŝĨŝĞĚ
Respiratory or skin sensitization EŽƚůĂƐƐŝĨŝĞĚ
Germ cell mutagenicity EŽƚůĂƐƐŝĨŝĞĚ
Carcinogenicity EŽƚůĂƐƐŝĨŝĞĚ
Reproductive toxicity EŽƚůĂƐƐŝĨŝĞĚ
STOT-single exposure EŽƚůĂƐƐŝĨŝĞĚ
STOT-repeated exposure EŽƚůĂƐƐŝĨŝĞĚ
Aspiration hazard EŽƚůĂƐƐŝĨŝĞĚ
Christensen Arms AO Modification 9/7/23
WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ
ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϱŽĨϳ
&ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ
K^,,^ϮϬϭϮ
Carcinogenicity ඵEŽƚůŝƐƚĞĚŝŶEdW͕K^,͕Žƌ/ZŵŽŶŽŐƌĂƉŚƐ͘
Additional Information
ඵWƌĂĐƚŝĐĂůĞdžƉĞƌŝĞŶĐĞŚĂƐŶŽƚĚĞŵŽŶƐƚƌĂƚĞĚĂŶLJĂĚǀĞƌƐĞĞĨĨĞĐƚƐǁŝƚŚŶŽƌŵĂůƵƐĞ
ŽĨƚŚŝƐƉƌŽĚƵĐƚ͘
ඵŽŶƚĂŝŶƐƉĞƚƌŽůĞƵŵŽŝů͕ǁŚŝĐŚŝĨŵŝƐƚĞĚŝŶĞdžĐĞƐƐĂƚĞdžƉŽƐƵƌĞůŝŵŝƚƐŵĂLJĐĂƵƐĞ
ƌĞƐƉŝƌĂƚŽƌLJŝƌƌŝƚĂƚŝŽŶ͕ĐŽƵŐŚŝŶŐ͕ĂŶĚĞdžƚƌĞŵĞŽǀĞƌĞdžƉŽƐƵƌĞŵĂLJĐĂƵƐĞŽŝůƉŶĞƵŵŽŶŝƚŝƐ͘
Section 12: Ecological Information
Toxicity ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘
Persistence and degradability ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘
Bioaccumulative potential ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘
Mobility in Soil ඵEŽƚĚĞƚĞƌŵŝŶĞĚ͘
Other adverse effects ඵKŝůƐƉŝůůƐĂƌĞŐĞŶĞƌĂůůLJŚĂnjĂƌĚŽƵƐƚŽƚŚĞĞŶǀŝƌŽŶŵĞŶƚ͘
Section 13: Disposal Considerations
Waste treatment methods
Product waste ඵŽŶŽƚĚŝƐĐĂƌĚŝŶƚŽĂŶLJƐĞǁĞƌƐ͕ŽŶƚŚĞŐƌŽƵŶĚ͕ŽƌĂŶLJďŽĚLJŽĨǁĂƚĞƌ͘
ඵŝƐƉŽƐĞŽĨƐƵƌƉůƵƐĂŶĚŶŽŶͲƌĞĐLJĐůĂďůĞƉƌŽĚƵĐƚƐǀŝĂĂůŝĐĞŶƐĞĚǁĂƐƚĞĚŝƐƉŽƐĂů
ĐŽŶƚƌĂĐƚŽƌ͘
ඵdŚŝƐƉƌŽĚƵĐƚ͕ĂƐŵĂŶƵĨĂĐƚƵƌĞĚŝŶŝƚƐƉƌĞƐĞŶƚƐƚĂƚĞ͕ŝƐŶŽƚĐŽŶƐŝĚĞƌĞĚƚŽďĞĂ
ŚĂnjĂƌĚŽƵƐǁĂƐƚĞĂĐĐŽƌĚŝŶŐƚŽϰϬ&ZϮϲϭ͘ϰ;ďͿ;ϰͿ͘hŶĚĞƌZZ͕ŝƚŝƐƚŚĞƌĞƐƉŽŶƐŝďŝůŝƚLJŽĨ
ƚŚĞƵƐĞƌŽĨƚŚĞƉƌŽĚƵĐƚƚŽĚĞƚĞƌŵŝŶĞ͕ĂƚƚŚĞƚŝŵĞŽĨĚŝƐƉŽƐĂů͕ǁŚĞƚŚĞƌƚŚĞƉƌŽĚƵĐƚ
ŵĞĞƚƐZZĐƌŝƚĞƌŝĂĨŽƌŚĂnjĂƌĚŽƵƐǁĂƐƚĞ͘dŚŝƐƉƌŽĚƵĐƚƐŚŽƵůĚďĞƌĞĐLJĐůĞĚŝĨƉŽƐƐŝďůĞ͕
ŽƚŚĞƌǁŝƐĞŝƚƐŚŽƵůĚďĞĚŝƐƉŽƐĞĚŽĨŝŶĂĐĐŽƌĚĂŶĐĞǁŝƚŚĂůůĂƉƉůŝĐĂďůĞĨĞĚĞƌĂů͕ƐƚĂƚĞ͕
ĂŶĚůŽĐĂůƌĞŐƵůĂƚŝŽŶƐ͘
Contaminated containers ඵŽŶƚĂŵŝŶĂƚĞĚĐŽŶƚĂŝŶĞƌƐƐŚŽƵůĚďĞŽĨĨĞƌĞĚĨŽƌƉƌŽĨĞƐƐŝŽŶĂůĐůĞĂŶŝŶŐďĞĨŽƌĞƌĞƵƐĞ͘
or packaging ඵŝƐƉŽƐĞŽĨƐƉĞŶƚĐŽŶƚĂŝŶĞƌŝŶĂĐĐŽƌĚĂŶĐĞǁŝƚŚůŽĐĂů͕ƌĞŐŝŽŶĂů͕ŶĂƚŝŽŶĂů͕ĂŶĚͬŽƌ
ŝŶƚĞƌŶĂƚŝŽŶĂůƌĞŐƵůĂƚŝŽŶƐ͘
Section 14: Transport Information
UN Number ඵEŽƚƌĞŐƵůĂƚĞĚĨŽƌƚƌĂŶƐƉŽƌƚ
UN Proper Shipping Name ඵEŽƚĂƉƉůŝĐĂďůĞ
Transport Hazard Class(es)ඵEŽƚĂƉƉůŝĐĂďůĞ
Packing Group ඵEŽƚĂƉƉůŝĐĂďůĞ
Environmental Hazards ඵEŽƚĚĞƚĞƌŵŝŶĞĚ
Transport in Bulk ඵEŽƚƌĞŐƵůĂƚĞĚ
Special Precautions for user ඵEŽŶĞƐƉĞĐŝĨŝĞĚ
U.S. DOT ඵEŽƚƌĞŐƵůĂƚĞĚ
Section 15: Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Christensen Arms AO Modification 9/7/23
WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ
ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϲŽĨϳ
&ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ
K^,,^ϮϬϭϮ
Global Chemical Inventories
USA ůůĐŽŵƉŽŶĞŶƚƐŽĨƚŚŝƐŵĂƚĞƌŝĂůĂƌĞŽŶƚŚĞh^d^/ŶǀĞŶƚŽƌLJŽƌ
ĂƌĞĞdžĞŵƉƚ͘
Other TSCA Reg.EŽƚĚĞƚĞƌŵŝŶĞĚ͘
Austrailia EŽƚĚĞƚĞƌŵŝŶĞĚ͘
Canada EŽƚĚĞƚĞƌŵŝŶĞĚ͘
China EŽƚĚĞƚĞƌŵŝŶĞĚ͘
EU EŽƚĚĞƚĞƌŵŝŶĞĚ͘
Japan EŽƚĚĞƚĞƌŵŝŶĞĚ͘
Korea EŽƚĚĞƚĞƌŵŝŶĞĚ͘
New Zealand EŽƚĚĞƚĞƌŵŝŶĞĚ͘
Switzerland EŽƚĚĞƚĞƌŵŝŶĞĚ͘
Other U.S. Federal Regulations
SARA Ext. Haz. Subst.ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚĐŽŶƚĂŝŶŐƌĞĂƚĞƌƚŚĂŶϭ͘ϬйŽĨĂŶLJĐŚĞŵŝĐĂůƐƵďƐƚĂŶĐĞ
ŽŶƚŚĞ^ZdžƚƌĞŵĞůLJ,ĂnjĂƌĚŽƵƐ^ƵďƐƚĂŶĐĞƐůŝƐƚ͘
SARA Section 313 ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚĐŽŶƚĂŝŶŐƌĞĂƚĞƌƚŚĂŶϭ͘Ϭй;хϬ͘ϭйĨŽƌĐĂƌĐŝŶŽŐĞŶŝĐ
ƐƵďƐƚĂŶĐĞͿŽĨĂŶLJĐŚĞŵŝĐĂůƐƵďƐƚĂŶĐĞƐůŝƐƚĞĚƵŶĚĞƌ^Z^ĞĐƚŝŽŶϯϭϯ͘
EPCRA 311/312 Hazard Categories EŽƚůĂƐƐŝĨŝĞĚ
CERCLA Hazardous ඵEŽŶĞŬŶŽǁŶ
Substances
FDA Approval ඵEŽƚĂƉƉůŝĐĂďůĞ
State Regulations
California Propositon 65 ඵdŚŝƐƉƌŽĚƵĐƚĚŽĞƐŶŽƚĐŽŶƚĂŝŶĂŶLJWƌŽƉŽƐŝƚŝŽŶϲϱĐŚĞŵŝĐĂůƐ͘
Section 16: Other Information
HMIS Ratings ,ĞĂůƚŚ ϭ
&ůĂŵŵĂďŝůŝƚLJ ϭ
ZĞĂĐƚŝǀŝƚLJ Ϭ
WĞƌƐŽŶĂůWƌŽƚĞĐƚŝŽŶ
NFPA Ratings ,ĞĂůƚŚ ϭ
&ůĂŵŵĂďŝůŝƚLJ ϭ
ZĞĂĐƚŝǀŝƚLJ Ϭ
Acronyms/Abbreviations
ඵ NTPͲEĂƚŝŽŶĂůdŽdžŝĐŽůŽŐLJWƌŽŐƌĂŵZĞƉŽƌƚŽŶĂƌĐŝŶŽŐĞŶƐ;ůĂƚĞƐƚĞĚŝƚŝŽŶͿ
ඵIARCͲ/ŶƚĞƌŶĂƚŝŽŶĂůŐĞŶĐLJĨŽƌƚŚĞZĞƐĞĂƌĐŚŽŶĂŶĐĞƌ
ඵTSCAͲdŽdžŝĐ^ƵďƐƚĂŶĐĞŽŶƚƌŽůĐƚ
ZĞǀŝƐŝŽŶĂƚĞ͗ ϵͬϳͬϮϬϭϴ ZĞƉůĂĐĞƐ͗ ϲͬϭͬϮϬϭϱ
As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability
Christensen Arms AO Modification 9/7/23
WƌŽĚƵĐƚŶĂŵĞ͗WƌŽĚƌĂǁ
ZĞǀŝƐŝŽŶĂƚĞ͗ϬϵͬϬϳͬϮϬϭϴ WĂŐĞϳŽĨϳ
&ŽƌŵĂƚ͗',^>ĂŶŐƵĂŐĞ͗ŶŐůŝƐŚ;h^Ϳ
K^,,^ϮϬϭϮ
for any use of this product. Information contained herein is believed to be true and accurate but all statements or suggestions are made
without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the
results to be obtained from the use thereof. Compliance with all applicable federal, state, and local regulations remains the responsibility
of the user.
Christensen Arms AO Modification 9/7/23
SAFETY DATA SHEET
Last Revised: 01JUN15
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ............................................. PRO-SET® LAM-224 Hardener APPLICABLE PRODUCT CODES: ................... LAM-224, LAM-224-1, LAM-224-2, LAM-224-3, LAM-224-4, LAM-224-5
CHEMICAL FAMILY: ......................................... Polyamine mixture.
INTENDED PRODUCT USES: ........................... Curing agent for epoxy resins. PRODUCT RESTRICTIONS: ............................. None identified.
SDS VERSION: ................................................. LAM-224 -2015a MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS): Gougeon Brothers, Inc. Transportation 100 Patterson Ave. CHEMTREC: .................... 800-424-9300 (U.S.) Bay City, MI 48706, U.S.A. 703-527-3887 (International) Phone: 888-377-6738 or 989-684-7286 Non-transportation www.prosetepoxy.com Poison Hotline: ................. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture Acute toxicity, Dermal, Category 4 Acute toxicity, Inhalation, Category 4 Skin corrosion/irritation, Category 1B Skin sensitizer, Category 1 Eye damage/irritation, Category 1 Reproductive toxicity, Category 2 Acute aquatic toxicity, Category 1 Chronic aquatic toxicity, Category 1 Label Elements
Hazard Pictogram(s):
Signal Word: DANGER
Hazard Statements: H312 Harmful in contact with skin H332 Harmful if inhaled H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H361 Suspected of damaging fertility or the unborn child H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects
Precautionary Statements: Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood P260 Do not breathe dust/fume/gas/mist/vapors/spray P264 Wash hands thoroughly after handling P272 Contaminated work clothing should not be allowed out of the workplace P273 Avoid release to the environment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or shower). P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical attention or advice P310 Immediately call a POISON CENTER or doctor P313 + P333 If irritation or rash occurs: Get medical attention/advice P362 + P364 Take of contaminated clothing and wash it before reuse Christensen Arms AO Modification 9/7/23
PRO-SET® LAM-224 Hardener
Page 2 of 6 Last Revised: 01JUN15
P391 Collect spillage Storage P405 Store locked up. Disposal P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Aminoethylepiperazine 140-31-8 10-30
Benzene-1,3-dimethanamine 1477-55-0 10-25
Paratertiarybutylphenol 98-54-4 10-20
Trimethylhexamethylenediamine 25620-58-0 10-20
Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 10-20
N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 1-10
4-Nonylphenol, branched 84852-15-3 0.1-2
The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as a trade secret.
4. FIRST AID MEASURES
FIRST AID FOR EYES ........................................................................ SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER or doctor.
FIRST AID FOR SKIN ......................................................................... SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or doctor. FIRST AID FOR INHALATION............................................................ SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough. RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately consult with a physician if symptoms develop and persist.
FIRST AID FOR INGESTION .............................................................. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: .................................................................. SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE: Direct water stream.
FIRE AND EXPLOSION HAZARDS: .................................................. During a fire, smoke may contain the original materials in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, cyanides, aldehydes, nitrosamines. When mixed with sawdust, wood chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Use full-body protective gear and a self-contained breathing apparatus. Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ....... Keep unnecessary and unprotected personnel from entering area. Use appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: ................................. Stop leak without additional risk. Isolate area. Dike and absorb with inert material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS:.................................................. Prevent from entering into soil, ditches, sewers, waterways and groundwater. See Section 12 for environmental impact information. Christensen Arms AO Modification 9/7/23
PRO-SET® LAM-224 Hardener
Page 3 of 6 Last Revised: 01JUN15
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 90°F (32°C).
STORAGE: ......................................................................................... Store in cool, dry place away from high temperatures and moisture. Keep container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ............................................................. Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to undergo thermal decomposition damage or ignite surrounding materials. Fumes and vapors released as a result of thermal decomposition can vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION GUIDELINES: ..................................................... Chemical splash-proof goggles or face shield. SKIN PROTECTION GUIDELINES: .................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene, butyl rubber or natural rubber) and full body-covering clothing. RESPIRATORY/VENTILATION GUIDELINES: ................................... Use with adequate general ventilation and/or local ventilation to keep exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ......................................... Use where there is immediate access to safety shower and emergency eye wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ............................................. Exposure limits may not be established for this product as a whole. For established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Aminoethylepiperazine 140-31-8 No data available Benzene-1,3-dimethanamine 1477-55-0 0.1 mg/m3 SKIN, Ceiling NIOSH; OSHA Z1A Remarks: potential for skin absorption
Paratertiarybutylphenol 98-54-4 No data available Trimethylhexamethylenediamine 25620-58-0 No data available Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 No data available
N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 No data available 4-Nonylphenol, branched 84852-15-3 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ............................................................................. Liquid.
COLOR: ............................................................................................. Colorless
ODOR: ................................................................................................ Ammonia-like
ODOR THRESHOLD: ......................................................................... No data available
pH ....................................................................................................... 11.4
MELTING POINT / FREEZING POINT ................................................ No data. BOILING POINT (760mm/Hg): ........................................................... > 400°F (204°C) estimated based on similar product.
FLASH POINT: ................................................................................... Estimated > 200ᵒF (93°C) estimated based similar product.
AUTO IGNITION TEMPERATURE ...................................................... No data.
LOWER EXPLOSIVE LIMIT (LEL) ...................................................... No data.
UPPER EXPLOSIVE LIMIT (UEL) ...................................................... No data.
VAPOR PRESSURE ........................................................................... < 1 mmHg @ 20°C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.00 BULK DENSITY.................................................................................. 8.34 lbs./gal. (1.00 kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... 75 (mm2/s @ 20ᵒC)
DECOMPOSITION TEMPERATURE: ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal) LAM-125 / LAM-224 .................................................................... 3.60 0.03 LAM-135 / LAM-224 .................................................................... 1.66 0.01 Christensen Arms AO Modification 9/7/23
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LAM-145 / LAM-224 .................................................................... 1.13 0.01
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to thermal decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, cyanides, nitrosamines, phenolics.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Aminoethylepiperazine 140-31-8 2097 mg/kg 866 mg/kg No data Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h mist / aerosol
Paratertiarybutylphenol 98-54-4 > 2000 mg/kg No data. Intraperitoneal – mouse – 78 mg/kg.
5.6 mg/l; Remarks: Nutritional and Metabolic: Weight loss or decreased weight gain Trimethylhexamethylenediamine 25620-58-0 910 mg/kg No data No data
Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 No data No data No data
N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 1200 mg/kg 190-210 mg/kg No data 4-Nonylphenol, branched 84852-15-3 1412 mg/kg No data No data
ACUTE TOXICITY: ............................................................................. No specific toxicity data exists for this mixture. Classification is based on acute toxicity estimation methods using ingredient data. Oral: ................................................................................... Not classified. Does not meet classification criteria. Dermal: .............................................................................. Category 4. Harmful in contact with skin. Significant exposure can result in absorption causing headache and nausea.
Inhalation:........................................................................... Category 4. Harmful if inhaled. Repeated or prolonged exposures to mist or aerosol, or concentrated vapors may cause cough, shortness of breath, lung irritation and lung damage.
SKIN CORROSION / IRRITATION: ..................................................... Category 1B. Causes severe skin burns. Effects may be immediate. May cause persistent irritation or dermatitis.
SERIOUS EYE DAMAGE / IRRITATION:............................................ Category 1. Causes serious eye damage. May cause blurred vision. May cause corneal damage resulting in vision impairment or even blindness. RESPIRATORY SENSITIZATION: ...................................................... No data available.
SKIN SENSITIZATION:....................................................................... Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: .............................................................. Category 2. Suspected of damaging fertility or the unborn child. Rat studies involving nonylphenol indicate physical effects on newborns with reduced weight gain.
MUTAGENICITY: ................................................................................ Not classified. Does not meet classification criteria.
CARCINOGENICITY: .......................................................................... Not classified. Does not meet classification criteria. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet classification criteria.
ASPIRATION HAZARD: ..................................................................... Not classified. Does not meet classification criteria.
OTHER HEALTH HAZARD INFORMATON: ....................................... OTHER HEALTH HAZARD INFORMATON: Repeated dose toxicity studies to nonylphenol, rat, male and female: NOAEL – 10 mg/kg. LOAEL – 50 mg/kg.
12. ECOLOGICAL INFORMATION
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ACUTE AQUATIC TOXICITY:............................................................. No specific test data available for the mixture. Calculated Estimate: Aquatic Acute Category 1. Very toxic to aquatic life. Avoid release to the environment. CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 1. Very toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION: ................................... In the liquid, uncured state, this product may be harmful to aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information Aminoethylepiperazine 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3 Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3 Paratertiarybutylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2 Trimethylhexamethylenediamine 25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3 Reaction products of benzene-1,3-dimethanamine with phenol and formaldehyde 57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 Not classified 4-Nonylphenol, branched 84852-15-3 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... No
CANADA TDG UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... No
IMDG UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II EmS Number: .................................................................................... F-A, S-B MARINE POLLUTANT ........................................................................ Yes ICAO/IATA UN NUMBER: ..................................................................................... UN 2735 SHIPPING NAME: ............................................................................... Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Benzene-1,3-dimethanamine HAZARD CLASS: ................................................................................ Class 8 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Christensen Arms AO Modification 9/7/23
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Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS All ingredients are listed or otherwise compliant. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: This product may be subject to TSCA Section 12(b) SNUR requirements. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ...................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Immediate, Delayed. Subject to Section 313 ................................................................ 4-Nonylphenol, branched, CAS# 84852-15-3
US STATE REGULATORY INFORMATION: The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE 4-Nonylphenol, branched 84852-15-3 PA, NJ Paratertiarybutylphenol 98-54-4 PA, NJ Benzene-1,3-dimethanamine 1477-55-0 MA, PA, NJ Aminoethylepiperazine 140-31-8 MA, PA, NJ N,N’-Bis(3-aminopropyl)ethylenediamine 10563-26-5 PA, NJ
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Compliant to the requirements of the US OSHA 1910.1200 HazCom 2012 standard. PREPARED BY: ................................................................................. G. M. House
APPROVED BY: ................................................................................. G. M. House SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ June 1, 2015
SUPERSEDES DATE: ........................................................................ October 25, 2012
SDS VERSION: .................................................................................. LAM-224-2015a OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS® RATING NFPA® 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data.
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SAFETY DATA SHEET
Last Revised: 01JUN15
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ............................................. PRO-SET® LAM-145 Resin APPLICABLE PRODUCT CODES: ................... LAM-145, LAM-145-1, LAM-145-2, LAM-145-3, LAM-145-4, LAM-145-5, LAM-145-6
CHEMICAL FAMILY: ......................................... Epoxy resin mixture.
INTENDED PRODUCT USES: ........................... Laminating resin for composites. PRODUCT RESTRICTIONS: ............................. None identified.
SDS VERSION: ................................................. LAM-145 -2015a MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS): Gougeon Brothers, Inc. Transportation 100 Patterson Ave. CHEMTREC: .................... 800-424-9300 (U.S.) Bay City, MI 48706, U.S.A. 703-527-3887 (International) Phone: 888-377-6738 or 989-684-7286 Non-transportation www.prosetepoxy.com Poison Hotline: ................. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture Skin corrosion/irritation, Category 2 Skin sensitizer, Category 1 Eye damage/irritation, Category 2A Chronic aquatic toxicity, Category 2 Label Elements
Hazard Pictogram(s):
Signal Word: WARNING Hazard Statements: H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects
Precautionary Statements: Prevention P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P 280 Wear protective gloves/protective clothing/eye protection/face protection. Response P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical attention/advice. P337 + P313 If eye irritation persists: Get medical attention/advice. P362 + P364 Take off contaminated clothing and wash it before re-use. P391 Collect spillage. Disposal P501 Dispose of contents/container in accordance with local, regional and international regulations. Other Hazards None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 70-100 Christensen Arms AO Modification 9/7/23
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Trimethylpropanetriglycidylether 30499-70-8 10-30
The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as a trade secret.
4. FIRST AID MEASURES
FIRST AID FOR EYES ........................................................................ SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ......................................................................... SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and water. Consult a physician if effects occur. FIRST AID FOR INHALATION............................................................ SYMPTOMS: Not a likely route of exposure under normal conditions of use. RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION .............................................................. SYMPTOMS: No acute adverse health effects expected from amounts ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: .................................................................. SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE: Direct water stream.
FIRE AND EXPLOSION HAZARDS: .................................................. During a fire, smoke may contain the original materials in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Wear a self-contained breathing apparatus and complete full-body personal protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ....... Keep unnecessary and unprotected personnel from entering area. Use appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: ................................. Stop leak without additional risk. Isolate area. Dike and absorb with inert material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS:.................................................. Prevent from entering into soil, ditches, sewers, waterways and groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 120°F (49°C)
STORAGE: ......................................................................................... Store in cool, dry place. Store in tightly sealed containers to prevent moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ............................................................. Avoid all skin and eye contact. Wash thoroughly after handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION GUIDELINES: ..................................................... Safety glasses with side shields or chemical splash goggles. SKIN PROTECTION GUIDELINES: .................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene, butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY/VENTILATION GUIDELINES: ................................... Use with adequate general ventilation and/or local ventilation to keep exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ......................................... Practice good caution and personal cleanliness to avoid skin and eye contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions. Christensen Arms AO Modification 9/7/23
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OCCUPATIONAL EXPOSURE LIMITS: ............................................. Exposure limits may not be established for this product as a whole. For established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 No data available. Trimethylpropanetriglycidylether 30499-70-8 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ............................................................................. Viscous liquid.
COLOR: ............................................................................................. Colorless.
ODOR: ................................................................................................ Mild.
ODOR THRESHOLD: ......................................................................... No data available
pH ....................................................................................................... No data available MELTING POINT / FREEZING POINT ................................................ No data available
BOILING POINT (760mm/Hg): ........................................................... > 400°F (204°C)
FLASH POINT: ................................................................................... >200°F (93ᵒC) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ...................................................... No data available
LOWER EXPLOSIVE LIMIT (LEL) ...................................................... No data available
UPPER EXPLOSIVE LIMIT (UEL) ...................................................... No data available
VAPOR PRESSURE ........................................................................... No data available
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.17 BULK DENSITY.................................................................................. 9.75 lbs./gal. (1.17 kg/L)
VAPOR DENSITY (air = 1) ................................................................. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... 8547 mm2/s @ 20ᵒC
DECOMPOSITION TEMPERATURE: ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 >15,000 mg/kg (rat) >23,000 mg/kg (rabbit) No data
Trimethylpropanetriglycidylether 30499-70-8 >2,000 mg/kg >2,000 mg/kg No data
ACUTE TOXICITY: ............................................................................. No specific toxicity data exists for this mixture. Classification is based on acute toxicity estimation methods using ingredient data. Oral: ................................................................................... Not classified. Does not meet acute oral toxicity criteria. Dermal: .............................................................................. Not classified. Does not meet acute dermal toxicity criteria. Inhalation:........................................................................... Not classified. Does not meet acute inhalation toxicity criteria. If product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: ..................................................... Causes skin irritation – Category 2.
SERIOUS EYE DAMAGE / IRRITATION:............................................ Causes eye irritation. Category 2B.
RESPIRATORY SENSITIZATION: ...................................................... Not classified. Does not meet criteria for respiratory sensitizer. Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of developing allergy symptoms to this product. Christensen Arms AO Modification 9/7/23
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SKIN SENSITZIATION:....................................................................... May cause allergic skin reaction. Category 1. REPRODUCTIVE TOXICITY: .............................................................. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: ................................................................................ Not classified. Does not meet criteria for germ cell mutagenicity. Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in others.
CARCINOGENICITY: .......................................................................... Not classified. Does not meet criteria for carcinogenicity. Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen. Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence – inadequate; animal evidence – sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD: ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION: ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY:............................................................. No specific test data available for the mixture. Calculated Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION: ................................... In the liquid, uncured state, this product may be harmful to aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Trimethylpropanetriglycidylether 30499-70-8 Aquatic Chronic Cat. 3
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. Christensen Arms AO Modification 9/7/23
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TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable.
IMDG UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes ICAO/IATA UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS All ingredients are listed or otherwise compliant. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. New Zealand NZIoC Not determined (CAS# 30499-70-8).
US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Immediate. Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1CA
1. These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Compliant to the requirements of the US OSHA 1910.1200 HazCom 2012 standard.
PREPARED BY: ................................................................................. G. M. House
APPROVED BY: ................................................................................. G. M. House
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ June 1, 2015
SUPERSEDES DATE: ........................................................................ October 24, 2012 SDS VERSION: .................................................................................. LAM-145-2015a
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS® RATING NFPA® 704 CODES Christensen Arms AO Modification 9/7/23
PRO-SET® LAM-145 Resin
Page 6 of 6 Last Revised: 01JUN15
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data.
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Christensen Arms AO Modification 9/7/23
SAFETY DATA SHEET
1. Identification
XTREME CUT 251CProduct identifier
None.Other means of identification
Cutting and Grinding FluidRecommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer Name QualiChem, Inc.
Address PO Box 926
Salem, VA USA
Telephone +1-540-375-6700
Email customerservice@qualichem.com
Website www.qualichem.com
Emergency Phone Number For Chemical Emergency ONLY (spill, leak, fire, exposure, or accident), 24 hour
emergency telephone, call Chemtel at +1-800-255-3924 (US, Canada);
+1-813-248-0585 elsewhere.
2. Hazard(s) identification
Not classified.Physical hazards
Not classified.Health hazards
Label elements
None.Hazard symbol
Signal word None.
Hazard statement Not available.
Precautionary statement
Prevention Not available.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS numberCommon name and synonymsChemical name %
64742-52-5Distillates, (petroleum),
hydrotreated heavy naphthenic
40 - 60
929-06-62-(2-Aminoethoxy)ethanol 1 - 5
15520-05-52,2'-(Octylimino)bisethanol 1 - 5
Not AvailableAmine neutralized carboxylic acid 1 - 5
110-97-4Diisopropanolamine 1 - 5
55406-53-63-Iodo-2-propynyl butylcarbamate 0.1 - 1
Other components below reportable levels
57-55-6Propylene glycol 0.1 - 1
40 - 60
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
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Material name: XTREME CUT 251C
2029 Version #: 01 Issue date: 12-16-2016
SDS US
BhristensenOVrmsOVOOModification 9/7/23
4. First-aid measures
Move to fresh air. Call a physician if symptoms develop or persist.Inhalation
Wash off with soap and water. Get medical attention if irritation develops and persists.Skin contact
Rinse with water. Get medical attention if irritation develops and persists.Eye contact
Rinse mouth. Get medical attention if symptoms occur.Ingestion
Direct contact with eyes may cause temporary irritation.Most important
symptoms/effects, acute and
delayed
Treat symptomatically.Indication of immediate
medical attention and special
treatment needed
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
General information
5. Fire-fighting measures
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk.Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
No unusual fire or explosion hazards noted.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local
authorities should be advised if significant spillages cannot be contained. For personal protection,
see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
This product is miscible in water. Prevent product from entering drains.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Environmental precautions
7. Handling and storage
Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective
equipment. Avoid release to the environment. Observe good industrial hygiene practices.
Precautions for safe handling
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
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Material name: XTREME CUT 251C
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US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents FormType
PEL 5 mg/m3 Mist.Distillates, (petroleum),
hydrotreated heavy
naphthenic (CAS
64742-52-5)
2000 mg/m3
500 ppm
US. ACGIH Threshold Limit Values
ValueComponents FormType
TWA 5 mg/m3 Inhalable fraction.Distillates, (petroleum),
hydrotreated heavy
naphthenic (CAS
64742-52-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents FormType
Ceiling 1800 mg/m3Distillates, (petroleum),
hydrotreated heavy
naphthenic (CAS
64742-52-5)
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueComponents FormType
TWA 10 mg/m3 Aerosol.Propylene glycol (CAS
57-55-6)
No biological exposure limits noted for the ingredient(s).Biological limit values
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear protective gloves.Hand protection
Wear suitable protective clothing.Other
No personal respiratory protective equipment normally required.Respiratory protection
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Clear Liquid.Form
AmberColor
Mild amineOdor
Odor threshold Not available.
pH 9.0 - 10.0
Melting point/freezing point < 40 °F (< 4.4 °C) estimated
Initial boiling point and boiling
range
> 212 °F (> 100 °C) estimated
Flash point None
Evaporation rate Not available.
Not applicable.Flammability (solid, gas)
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Material name: XTREME CUT 251C
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Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure < 1.0 mm Hg estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water)Complete
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 0.96 g/cm3
8.03 lb/gal
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
Percent volatile > 10 % estimated
pH in aqueous solution 8.8 - 9.2 (5% Emulsion)
Specific gravity 0.96
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizing agents.Incompatible materials
No hazardous decomposition products are known.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity Not available.
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Direct contact with eyes may cause temporary irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
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Material name: XTREME CUT 251C
2029 Version #: 01 Issue date: 12-16-2016
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No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Toxic to aquatic life. Harmful to aquatic life with long lasting effects.Ecotoxicity
No data is available on the degradability of this product. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Diisopropanolamine -0.82
Propylene glycol -0.92
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not established.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Not regulated as dangerous goods.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
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Material name: XTREME CUT 251C
2029 Version #: 01 Issue date: 12-16-2016
SDS US
:hristensen6*rms6*"6Hodification 8@f@yL
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
NoSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
California Proposition 65 - WARNING: This product contains a chemical known to the State of
California to cause cancer and birth defects or other reproductive harm.
US state regulations
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesCanadaDomestic Substances List (DSL)
YesChinaInventory of Existing Chemical Substances in China (IECSC)
YesEuropeEuropean Inventory of Existing Commercial Chemical
Substances (EINECS)
YesKoreaExisting Chemicals List (ECL)
YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
12-16-2016Issue date
Version #01
QualiChem, Inc. cannot anticipate all conditions under which this information and its product, or
the products of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
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Material name: XTREME CUT 251C
2029 Version #: 01 Issue date: 12-16-2016
SDS US
BhristensenOVrmsOVOOModification 9/7/23
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: LOCTITE® 277™ THREADLOCKER HIGH STRENGTH IDH number: 88448
Product type: Anaerobic Sealant Item number: 27731
Restriction of Use: None identified Region: United States
Company address: Contact information: Henkel Corporation Henkel Way One Rocky Hill, Connecticut 06067
Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW WARNING: CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S)
Precautionary Statements
Prevention: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling. Wear protective gloves, eye protection, and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Christensen Arms AO Modification 9/7/23
Hazardous Component(s) CAS Number Percentage*
Cumene hydroperoxide 80-15-9 1 - 5
Saccharin 81-07-2 1 - 5
Cumene 98-82-8 0.1 - 1 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.
4. FIRST AID MEASURES
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Symptoms: See Section 11.
5. FIRE FIGHTING MEASURES
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray.
Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers.
Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.
6. ACCIDENTAL RELEASE MEASURES
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Environmental precautions: Do not allow product to enter sewer or waterways.
Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.
Christensen Arms AO Modification 9/7/23
7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8.
Storage: For safe storage, store at or below 38 °C (100.4 °F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER
Cumene hydroperoxide None None 1 ppm (6 mg/m3) TWA (SKIN) None
Saccharin None None None None
Cumene 50 ppm TWA 50 ppm (245 mg/m3) PEL (SKIN) None None
Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Red
Odor: Characteristic
Odor threshold: Not available. pH: Not applicable
Vapor pressure: < 5 mm hg (27 °C (80.6 °F))
Boiling point/range: > 149 °C (> 300.2 °F)
Melting point/ range: Not available.
Specific gravity: 1.1
Vapor density: Not available.
Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available. VOC content: 0.71 %; 7.13 g/l (California SCAQMD Method 316B) (Estimated)
Viscosity: Not available.
Decomposition temperature: Not available.
Christensen Arms AO Modification 9/7/23
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and use.
Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials.
Hazardous decomposition
products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. Phenolics.
Incompatible materials: Strong acids and oxidizing agents. Copper. Rust. Iron. Oxygen scavengers. Strong alkalis. Reducing agents. Other polymerization initiators.
Reactivity: Not available. Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials.
11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Potential Health Effects/Symptoms
Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Skin contact: Causes skin irritation. Eye contact: Causes serious eye irritation.
Ingestion: May cause gastrointestinal tract irritation if swallowed.
Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l Allergen, Central nervous system, Corrosive, Irritant, Mutagen Saccharin Oral LD50 (Mouse) = 17 g/kg No Target Organs
Cumene
Oral LD50 (Rat) = 2.91 g/kg Oral LD50 (Rat) = 1,400 mg/kg Inhalation LC50 (Rat, 4 h) = 8000 ppm Central nervous system, Irritant, Lung
Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen
(Specifically Regulated)
Cumene hydroperoxide No No No Saccharin No No No
Cumene Reasonably Anticipated to be a Human Carcinogen. Group 2B No
12. ECOLOGICAL INFORMATION
Ecological information: Not available.
Christensen Arms AO Modification 9/7/23
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082 Packing group: III
DOT Hazardous Substance(s): alpha,alpha-Dimethylbenzylhydroperoxide
International Air Transportation (ICAO/IATA)
Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9
Identification number: UN 3082
Packing group: III
Water Transportation (IMO/IMDG) Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III Additional information: IMDG-Code: Segregation group 1- Acids
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
CERCLA/SARA Section 302 EHS: None above reporting de minimis.
CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2).
CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer.
Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details.
16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: 2
Christensen Arms AO Modification 9/7/23
Prepared by: Product Safety and Regulatory Affairs
Issue date: 01/19/2018
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.
Christensen Arms AO Modification 9/7/23
SAFETY DATA SHEET Part No.: 3136-R3
DATE: 08/18/2016
SUPERSEDES:
PRODUCT NAME: Rhino® 3136R-3 Hardener
CHEMICAL FAMILY: Cycloaliphatic Diamine
Page 1 of 3
SECTION 1 – IDENTIFICATION
MANUFACTURER’S NAME: Rhino Linings Corporation
ADDRESS: 9747 Businesspark Avenue, San Diego, CA, 92131
INFORMATION PHONE: 858-450-0441
EMERGENCY CONTACT: (CHEMTREC): 800-424-9300
SECTION 2 – HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Corrosive epoxy hardener. Certain individuals may have pre-existing skin or respiratory conditions causing
a sensitivity or allergy which manifests as various reactions. Heating or spraying this product or the mixed parts increases potential
health hazards. Health and Safety personnel should examine the handling procedures and remedy any existing or potential health and
safety hazards.
POTENTIAL HEALTH EFFECTS:
EYE:
• Can cause irritation. Significant, prolonged, or repeated contact can damage the cornea.
SKIN:
• Can cause irritation. Significant, prolonged, or repeated exposure can cause severe irritation.
INGESTION:
• Can inflame or damage the G.I. tract. Ingestion can be harmful.
INHALATION:
• Can cause irritation. Significant, prolonged, or
repeated exposure to mist or vapor can damage the respiratory
system.
CHRONIC EFFECTS:
• Repeated exposure can cause irritation and sensitization.
SIGNS & SYMPTOMS:
• Skin rash, irritation, reddening, or eczema; breathing irritation or difficulty.
SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT % CAS # EXPOSURE LIMITS
Isophorone Diamine >99.7 2855-13-2 N/E
SECTION 4 – FIRST-AID MEASURES
USE APPROPRIATE BLOOD-BORNE PATHOGENS PROTECTIONS
EYE:
• Hold eyelids apart and flood with copious amounts of water. Seek medical attention.
SKIN:
• Remove excess product. Wash thoroughly with soap and water. If irritation persists, seek medical attention.
INGESTION:
• Do not induce vomiting unless directed by medical personnel. Seek medical attention.
INHALATION:
• Remove to fresh air. Seek medical attention.
Christensen5Arms5AO5Modification 9/7/23
SAFETY DATA SHEET Part No.: 3136-R3
DATE: 08/18/2016
SUPERSEDES:
PRODUCT NAME: Rhino® 3136R-3 Hardener
CHEMICAL FAMILY: Cycloaliphatic Diamine
Page 2 of 3
SECTION 5 – FIRE-FIGHTING MEASURES
FLASH POINT: 117°C (DIN 51758) UEL: N.D.A.% LEL: 1.2% (V) VAPOR DENSITY: N.D.A.
NFPA FLAMMABILITY RATING: 1 AUTOIGNITION: N.D.A.
COMBUSTION PRODUCTS: CO, CO2, NOx, & misc. hydrocarbons
SPECIAL HAZARDS: Firefighters should wear butyl rubber boots, gloves, and body suit with SCBA. May generate toxic and irritating
combustion products. Use DOT Response Guide #153.
EXTINGUISHING MEDIA: Use foam, CO2, dry chemical, water fog.
FIRE FIGHTER INSTRUCTIONS: Stay upwind. Wear at least full bunker gear and SCBA.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Isolate the spill area. Keep out of sewer or storm drains. Stop the leak and contain the spill. Vacuum, scoop, or absorb spill with non-
combustible materials. Clean up spill residues with soap and water.
SECTION 7 – HANDLING AND STORAGE
Avoid skin and eye contact and breathing vapors by appropriate measures. Do not eat or smoke while handling this product. Wash
thoroughly with soap and water after handling or exposure to this product.
Store in original sealed container at ambient temperatures (65°-80°F) in dry, well-ventilated areas.
SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION
For Personal Exposure Limits (PEL), Threshold Limit Values (TLV), or other exposure limits, see Sec. 3.
GENERAL: Provide adequate ventilation that will keep airborne concentration at a minimum.
EYE/FACE: Safety glasses or splash goggles with face shield.
SKIN: Butyl or nitrile rubber chemical gloves. Don chemical resistant clothing where exposure may occur.
RESPIRATORY: NIOSH approved respirator with organic vapor/HEPA filter cartridges.
OTHER: Decontaminate or discard clothing and materials that have come in contact with this product.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: clear ODOR: slightly amine-like PHYSICAL STATE: liquid
VAPOR PRESS: ca. 0.02 hpa(20°C) SPECIFIC GRAVITY: 0.924 @ 20°C pH: 11.6
BOILING PT: >252.9°C (1013 hPa) MELT PT: N.D.A. SOLUBILITY IN H2O: slight
SECTION 10 – STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable.
INCOMPATIBILITY: Strong oxidizers, acids, epoxy resins in uncontrolled conditions; contact with other unpolymerized monomers or
polymers.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION: None known, other than Sec. 5’s Combustion Products.
SECTION 11 – TOXICOLOGICAL INFORMATION
Oral: N.D.A.
Dermal: N.D.A.
Inhalation: N.D.A.
Carcinogens under OSHA, ACGIH, NTP, IARC, or Other: None 0.1%.
Christensen5Arms5AO5Modification 9/7/23
SAFETY DATA SHEET Part No.: 3136-R3
DATE: 08/18/2016
SUPERSEDES:
PRODUCT NAME: Rhino® 3136R-3 Hardener
CHEMICAL FAMILY: Cycloaliphatic Diamine
Page 3 of 3
SECTION 12 – ECOLOGICAL INFORMATION
N.D.A.
SECTION 13 – DISPOSAL CONSIDERATIONS
Dispose of in accordance with applicable federal, state, and local laws and regulations.
SECTION 14 – TRANSPORT INFORMATION
DOT: ISOPHORONEDIAMINE, 8, UN 2289, PGIII.
IATA: Regulated.
IMO: UN 2289 Isophoronediamine, class 8, PG III
SECTION 15 – REGULATORY INFORMATION
OSHA: 1910.1200 Hazardous Chemical “Corrosive”, “Sensitizer”.
TSCA: Contains listed ingredients.
SARA III: Sec311 & 312 Immediate Health Hazard; Sec313 Chemicals above de minimus
level: None.
CA PROP. 65 NOTICE: Not listed.
VOLATILE ORGANIC COMPOUND (VOC) %: Zero.
NFPA: HEALTH 3 FIRE 1 REACTIVITY 0 OTHER N/A
WHMIS: Hazard Classification: Class D Division 1B & 2A, Class E Corrosive.
WHMIS Symbols: Stylized T, Corrosive.
Trade Secrets: N/A.
Hazardous Products Act Information: This product SDS contains ingredients which are Controlled and/or on the Ingredient Disclosure
List (HPA sections 13 and 14).
ABBREVIATIONS: N/A = not applicable; N.D.A. = no data available; NE = not established
SECTION 16 – OTHER INFORMATION
3/30/2015 Change to SDS format. Supersedes.
ABBREVIATIONS: N/A = not applicable; N.D.A. = no data available; NE = not established
Disclaimer: The data set forth in this sheet are based on information provided by the suppliers of the raw materials and
chemicals used in the manufacture of the aforementioned product. Rhino Linings Corporation makes no warranty with
respect to the accuracy of the information provided by their suppliers, and disclaims all liability of reliance thereof. Christensen5Arms5AO5Modification 9/7/23
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Christensen Arms AO Modification 9/7/23
Product Name: Unilube 22 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name:Unilube 22
Product Description: R&O Turbine Oil/Anti-Wear ISO 32
Product Code:BOSUNI022-275, BOSUNI022-055, BOSUNI022-005
Intended Use:Turbine, Circulating, Hydraulic & Bar Feed Oil
Company Identification
Bosse Lubricants
Mailing Address Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053
Transportation Emergency Phone:Infotrac 800.535.5053
Product Technical Information: 800.367.9966
MSDS Internet Address:http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
This material is not hazardous according to regulatory guidelines (see SDS Section 15).
Other hazard information:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200.
PHYSICAL / CHEMICAL HAZARDS
No significant hazards.
HEALTH HAZARDS
High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation.
ENVIRONMENTAL HAZARDS
No significant hazards.
NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0
HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown
that chemical exposure may cause potential human health risks which may vary from person to person.Christensen Arms AO Modification 9/7/23
Product Name: Unilube 22 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3)OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and
wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or
into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to
the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment
in these cases could be critical.
Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention.
Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or
unconsciousness. Seek medical attention.
Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have
been ingested or person affected is not feeling well, seek medical attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Unsuitable Extinguishing Media:Straight streams of water
Fire Fighting Instructions:Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or
drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed
surfaces and to protect personnel.
Unusual Fire Hazards: Pressurized mists may form a flammable mixture.
Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke).
Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and
sulfur oxides.
Flash Point:>400oF
Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 0 Flammability = 1 Reactivity = 0
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures:Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit
exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from
entering rivers, streams, storm drains and any area that will allow the material to spread.
Clean Up Measures:After the material has been contained, begin to remove the material from the inappropriate areas. A pump or
vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for
smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the
appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill.
Notification Measures:Report any spill that has entered the environment directly or thru storm drains and water ways such as streams
or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The
National Response Center can be reached at 1.800.424.8802.Christensen Arms AO Modification 9/7/23
Product Name: Unilube 22 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 3 of 6
SECTION 7 HANDLING AND STORAGE
General Precautions:When this material is used as intended it is very safe to handle and doesn’t require any special handling
instructions. We still recommend personal protection just as a good safety practice.
Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend
using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial
hygiene and safety practice. Always replace the lid or cap after use.
Storage:Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures
are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures:The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider: No special requirements under ordinary conditions of use and
with adequate ventilation.
Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection of protective
equipment for use with this material, as provided below, is based upon intended, normal usage.
Skin And Body Protection:No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial
hygiene practices, precautions should be taken to avoid skin contact.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or
aerosol exposure, wear suitable personal respiratory protection.
Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good
general prevention.
Specific Hygiene Measures:Always observe good personal hygiene measures, such as washing after handling the material and before
eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.
Environmental Exposure Controls:Minimize exposure of this material to the environment.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odor
Odor Threshold
pH
Melting Point
Freezing Point
Initial Boiling Point
Boiling Range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits
(Approx. Volume % In Air)
Explosive Limits
Vapor Pressure
Vapor Density
Relative Density
Solubility
Partition Coefficient
Auto Ignition Temperature
Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions.
Conditions To Avoid: Excessive heat. High energy sources of ignition.
Materials To Avoid: Strong oxidizers
Hazardous Decomposition Products: Material does not decompose at ambient temperatures.
Hazardous Polymerization: Will not occur.Christensen Arms AO Modification 9/7/23
Product Name: Unilube 22 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 4 of 6
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available
Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused
Products:
Disposal must be in accordance with current applicable laws and regulations, and material characteristics at
time of disposal.
Used Empty Containers:Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers
without proper instructions. Empty drums should be completely drained and safely stored until appropriately
reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through
suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT
PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
OT: Not Regulated for Land Transport
TDG(Canada): Not Regulated for Land Transport
IMO/IMDG: Not Regulated for Sea Transport
AIR (IATA) :Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR
1910.1200.
Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA
EPCRA SECTION 302: This material contains no extremely hazardous substances.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals
subject to the supplier notification requirements of the SARA 313 Toxic Release Program.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the date issued. You
can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and recommendations are offered for
the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product,
it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-
handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or
retransmission of this document, in whole or in part, is not permitted.
End of SDS
Christensen Arms AO Modification 9/7/23
Product Name: Bos-Way 2 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name:BOS-WAY 2
Product Description: Way Lubricant/Lubricating Oil ISO 68
Product Code:BOSWAY2-005, BOSWAY2-055, BOSWAY2-275
Intended Use:Way Lubricant or Lubricating Oil
Company Identification
Bosse Lubricants
Mailing Address Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053
Transportation Emergency Phone:Infotrac 800.535.5053
Product Technical Information: 800.367.9966
MSDS Internet Address:http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Health Hazards This product should not present any health issues when used under normal conditions as intended.
Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild skin irritant.
Prolonged exposure could clog the pores of the skin.
Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As with any industrial
liquid, avoid contact with eyes at all times.
Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may cause irritation of
the respiratory tract.
Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting and diarrhea. It is
considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown
that chemical exposure may cause potential human health risks which may vary from person to person.Christensen Arms AO Modification 9/7/23
Product Name: Bos-Way 2 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3)OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical attention. Remove and
wash contaminated clothing before re-use. In the unlikely event the product is injected into or under the skin, or
into any part of the body, regardless of the appearance of the wound or its size, the individual should be sent to
the hospital immediately. In this circumstance, do not wait for symptoms to develop. The timeliness of treatment
in these cases could be critical.
Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical attention.
Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for dizziness, nausea or
unconsciousness. Seek medical attention.
Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If large amounts have
been ingested or person affected is not feeling well, seek medical attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Unsuitable Extinguishing Media:Straight streams of water
Fire Fighting Instructions:Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or
drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed
surfaces and to protect personnel.
Unusual Fire Hazards: Pressurized mists may form a flammable mixture.
Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and gases (smoke).
Incomplete combustion products, Oxides of carbon, carbon monoxide, aldehydes, zinc and
sulfur oxides.
Flash Point:>400oF
Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 0 Flammability = 1 Reactivity = 0
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures:Contaminated surfaces will be extremely slippery. Recommend wearing personal protective gear to limit
exposure. Contain spill immediately. Do not allow material to enter the environment. Prevent material from
entering rivers, streams, storm drains and any area that will allow the material to spread.
Clean Up Measures:After the material has been contained, begin to remove the material from the inappropriate areas. A pump or
vacuum can be used for large spills and inert material such as appropriate absorbent (sand) can be used for
smaller spills. Place excess material and absorbent materials in appropriate containers. Follow the
appropriate disposal guidelines for all materials that were cleaned and removed as a result of the spill.
Notification Measures:Report any spill that has entered the environment directly or thru storm drains and water ways such as streams
or rivers. Should the spill occur on a roadway, contact the appropriate government or city agencies. The
National Response Center can be reached at 1.800.424.8802.Christensen Arms AO Modification 9/7/23
Product Name: Bos-Way 2 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 3 of 6
SECTION 7 HANDLING AND STORAGE
General Precautions:When this material is used as intended it is very safe to handle and doesn’t require any special handling
instructions. We still recommend personal protection just as a good safety practice.
Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we still recommend
using gloves and safety goggles when handling to limit exposure. Handle in accordance with good industrial
hygiene and safety practice. Always replace the lid or cap after use.
Storage:Keep containers dry and tightly closed to avoid moisture absorption and contamination. Ambient temperatures
are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures:The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider: No special requirements under ordinary conditions of use and
with adequate ventilation.
Personal Protection: Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection of protective
equipment for use with this material, as provided below, is based upon intended, normal usage.
Skin And Body Protection:No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial
hygiene practices, precautions should be taken to avoid skin contact.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case of mist, spray or
aerosol exposure, wear suitable personal respiratory protection.
Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are recommended as good
general prevention.
Specific Hygiene Measures:Always observe good personal hygiene measures, such as washing after handling the material and before
eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.
Environmental Exposure Controls:Minimize exposure of this material to the environment.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odor
Odor Threshold
pH
Melting Point
Freezing Point
Initial Boiling Point
Boiling Range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Viscous Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>400oF
N/D
N/D
Flammability Limits
(Approx. Volume % In Air)
Explosive Limits
Vapor Pressure
Vapor Density
Relative Density
Solubility
Partition Coefficient
Auto Ignition Temperature
Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions.
Conditions To Avoid: Excessive heat. High energy sources of ignition.
Materials To Avoid: Strong oxidizers
Hazardous Decomposition Products: Material does not decompose at ambient temperatures.
Hazardous Polymerization: Will not occur.Christensen Arms AO Modification 9/7/23
Product Name: Bos-Way 2 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page:Page 4 of 6
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available
Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused
Products:
Disposal must be in accordance with current applicable laws and regulations, and material characteristics at
time of disposal.
Used Empty Containers:Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers
without proper instructions. Empty drums should be completely drained and safely stored until appropriately
reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through
suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT
PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport
TDG(Canada): Not Regulated for Land Transport
IMO/IMDG: Not Regulated for Sea Transport
AIR (IATA) :Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard:When used for its intended purposes, this material is not classified as hazardous
in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories:None.
SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
California Proposition 65: This material does not contain any chemicals known to the State of California to
cause cancer, birth defects or other reproductive harm.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate and reliable as of the
date issued. You can contact Bosse Lubricants to insure that this document is the most current available from Bosse Lubricants. The information and
recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for
the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of
this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not
permitted.End of SDS
Christensen Arms AO Modification 9/7/23
Product Name: Premium Spindle 10 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 1 of 6
Safety Data Sheet
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name: Premium Spindle 10 Oil
Product Description: Spindle Oil ISO VG 10 Product Code: BOSSPIN10-005, BOSSPIN10-055 Intended Use: Spindle Oil/Fluid, Circulating, Light Lubrication Oil & Heat Transfer Oil
Company Identification
Bosse Lubricants Mailing Address
Warehouse Address
PO Box 11330
Glendale, AZ 85318
Phone 800.367.9966
Fax 602.256.2231
Email:
customerservice@metalfluids.com
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053 Transportation Emergency Phone: Infotrac 800.535.5053 Product Technical Information: 800.367.9966 MSDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Warning
Causes Mild Skin Irritation – Category 3
Health Hazards This product should not present any health issues when used under normal conditions as
intended. Skin Contact This material is not expected to cause any skin irritation. It is possible that it could be a mild
skin irritant. Prolonged exposure could clog the pores of the skin. Eye Contact Avoid contact with eyes. Not expected to cause any damage but could cause irritation. As
with any industrial liquid, avoid contact with eyes at all times. Inhalation When used as intended, this should not occur. In the event it is breathed in as a mist, it may
cause irritation of the respiratory tract. Ingestion If this product is swallowed, it may cause some gastrointestinal irritation, nausea, vomiting
and diarrhea. It is considered a low toxicity material.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to
person.
Christensen Arms AO Modification 9/7/23
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Language: English Version: 2
Format: US Page: Page 2 of 6
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredient CAS Number ACGIH (TWA mg/m3) OSHA
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 4 FIRST AID MEASURES
General Information Consult a physician. Not expected to be a health hazard when used under normal conditions
as intended.
Skin Contact Wash contact areas with soap and water. If persistent irritation occurs, obtain medical
attention. Remove and wash contaminated clothing before re-use. In the unlikely event the
product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be sent to the hospital immediately.
In this circumstance, do not wait for symptoms to develop. The timeliness of treatment in
these cases could be critical. Eye Contact Flush eye(s) with water for 15 minutes. If irritation persists after flushing, seek medical
attention. Inhalation Remove from further exposure. If breathing is difficult, give oxygen. Observe individual for
dizziness, nausea or unconsciousness. Seek medical attention. Ingestion First aid is normally not required. Drink 1 or 2 glasses of water. Do not induce vomiting. If
large amounts have been ingested or person affected is not feeling well, seek medical
attention.
SECTION 5 FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Unsuitable Extinguishing Media: Straight streams of water Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard
protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: May include a complex mixture of airborne solid and liquid particulates and
gases (smoke). Incomplete combustion products, Oxides of carbon, carbon
monoxide, aldehydes, zinc and sulfur oxides.
Flash Point: >400oF Auto Ignition Temperature: N/D
NFPA Hazard ID Health = 1 Flammability = 1 Reactivity = 0
Christensen Arms AO Modification 9/7/23
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Language: English Version: 2
Format: US Page: Page 3 of 6
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Contaminated surfaces will be extremely slippery. Recommend wearing personal
protective gear to limit exposure. Contain spill immediately. Do not allow material to enter
the environment. Prevent material from entering rivers, streams, storm drains and any
area that will allow the material to spread.
Clean Up Measures: After the material has been contained, begin to remove the material from the inappropriate
areas. A pump or vacuum can be used for large spills and inert material such as
appropriate absorbent (sand) can be used for smaller spills. Place excess material and
absorbent materials in appropriate containers. Follow the appropriate disposal guidelines
for all materials that were cleaned and removed as a result of the spill. Notification Measures: Report any spill that has entered the environment directly or thru storm drains and water
ways such as streams or rivers. Should the spill occur on a roadway, contact the
appropriate government or city agencies. The National Response Center can be reached
at 1.800.424.8802.
SECTION 7 HANDLING AND STORAGE
General Precautions: When this material is used as intended it is very safe to handle and doesn’t require any
special handling instructions. We still recommend personal protection just as a good safety
practice. Handling: Prevent small spills and leakage to avoid slip hazard. Even though the material is inert, we
still recommend using gloves and safety goggles when handling to limit exposure. Handle
in accordance with good industrial hygiene and safety practice. Always replace the lid or
cap after use. Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination.
Ambient temperatures are recommended. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: The level of protection and types of controls necessary will vary depending upon
potential exposure conditions. Control measures to consider: No special requirements
under ordinary conditions of use and with adequate ventilation. Personal Protection: Personal protective equipment selections vary based on potential exposure conditions
such as applications, handling practices, concentration and ventilation. Information on
the selection of protective equipment for use with this material, as provided below, is
based upon intended, normal usage. Skin And Body Protection: No skin protection is ordinarily required under normal conditions of use. In accordance
with good industrial hygiene practices, precautions should be taken to avoid skin
contact. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Respiratory Protection: No respiratory protection is ordinarily required under normal conditions of use. In case
of mist, spray or aerosol exposure, wear suitable personal respiratory protection. Hand Protection: No protection is ordinarily required under normal conditions of use. Gloves are
recommended as good general prevention. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Environmental Exposure Controls: Minimize exposure of this material to the environment.
Christensen Arms AO Modification 9/7/23
Product Name: Premium Spindle 10 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 4 of 6
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold pH Melting Point Freezing Point
Initial Boiling Point Boiling Range Flash Point Evaporation Rate Flammability (solid, gas)
Oily Liquid
Mild
N/D
N/D
N/A
N/A
599oF
N/D
>260oF
N/D
N/D
Flammability Limits (Approx. Volume % In Air) Explosive Limits Vapor Pressure Vapor Density Relative Density
Solubility Partition Coefficient Auto Ignition Temperature Decomposition Temperature
LEL: 0.9 UEL: 7.0
N/D
<0.01 mmHg @ 100oF
>1
0.85 – 0.89
Soluble In Hydrocarbons;
Insoluble In Water
N/D
N/D
N/D
These are typical physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions. Conditions To Avoid: Excessive heat. High energy sources of ignition. Materials To Avoid: Strong oxidizers Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available Eco-toxicity Effects: No data available
Bioaccumulation Potential: No data available
Aquatic Toxicity: No data available
Christensen Arms AO Modification 9/7/23
Product Name: Premium Spindle 10 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 5 of 6
SECTION 13 DISPOSAL CONSIDERATIONS
Waste From Residues & Unused Products:
Disposal must be in accordance with current applicable laws and regulations, and material
characteristics at time of disposal. Used Empty Containers: Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums should be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport TDG(Canada): Not Regulated for Land Transport IMO/IMDG: Not Regulated for Sea Transport AIR (IATA) : Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program. California Proposition 65: This material does not contain any chemicals known to the State of
California to cause cancer, birth defects or other reproductive harm.
Christensen Arms AO Modification 9/7/23
Product Name: Premium Spindle 10 Issue Date: 05/15/2015
Language: English Version: 2
Format: US Page: Page 6 of 6
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
The information and recommendations contained herein are, to the best of Bosse Lubricants knowledge and belief, accurate
and reliable as of the date issued. You can contact Bosse Lubricants to insure that this document is the most current
available from Bosse Lubricants. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages
this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with
and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of
this document, in whole or in part, is not permitted.
Christensen Arms AO Modification 9/7/23
Command Clean Heavy-Duty Degreaser Concentrate Issue Date
05/15/2015
1
GHS Safety Data Sheet (SDS)
SECTION 1 MATERIAL AND COMPANY IDENTIFICATION
Material Identification
Product Name Identifier: Command Clean Heavy-Duty Degreaser Concentrate
Product Description: Concentrated industrial aqueous cleaner / degreaser
Product Code: COMHDCLN-005, COMHDCLN-055
Intended Use: Industrial Cleaning
Supplier Details: Command Clean
5143 W. Roosevelt St
Phoenix, AZ 85043
Phone 800.367.9966
Fax 602.256.2231
Email: customerservice@metalfluids.com
24 Hour Health Emergency: Infotrac 800.535.5053
Transportation Emergency Phone: Infotrac 800.535.5053
Product Technical Information: 800.367.9966
SDS Internet Address: http://www.metalfluids.com
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS): Health, Causes eye irritation, 2 B
GHS Label elements, including precautionary statements GHS Signal Word: WARNING
GHS Hazard Pictograms: no GHS pictograms indicated for this product
GHS Hazard Statements:
Causes eye irritation
GHS Precautionary Statements: IF SWALLOWED: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury;
however, swallowing larger amounts may cause injury.
IF ON SKIN: Wash with soap and water. IF INHALED: Prolonged exposure is not expected to cause adverse effects.
IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice.
Hazards not otherwise classified (HNOC) or not covered by GHS
Inhalation: Prolonged exposure is not expected to cause adverse effects.
Skin Contact: Non-irritating.
Eye Contact: May cause slight eye irritation.
Ingestion: Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical
exposure may cause potential human health risks which may vary from person to person.
Christensen Arms AO Modification 9/7/23
Command Clean Heavy-Duty Degreaser Concentrate Issue Date
05/15/2015
2
SECTION 3 INFORMATION/COMPOSITION ON INGREDIENTS
Ingredients:
The specific chemical identity and chemical composition has been withheld as a trade secret.
The precise composition of this mixture is proprietary information. A complete disclosure will be provided to a physician or nurse in the event of a medical emergency.
SECTION 4 FIRST AID MEASURES
Inhalation If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention.
Skin Contact Wash with soap and water.
Eye Contact Flush eyes thoroughly with water for 15 minutes. Remove contact lenses after the initial 1 -2 minutes and continue flushing for several additional minutes. If effects occur, consult physician.
Ingestion If swallowed, seek medical attention if symptoms develop. Do not induce vomiting unless directed to do so by medical attention
SECTION 5 FIRE FIGHTING MEASURES
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. General purpose synthetic foams (including
AFFF) or protein foams may function, but will be less effective.
Fire Fighting Procedures: Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Move container
from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Avoid
accumulation of water.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire
fighting
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions: Spilled material may cause a slipping hazard. Use appropriate safety equipment. (See Section 8)
Methods and materials for containment and cleaning up:
Small spills: Absorb with materials such as: sand, vermiculite, absorbent pillows, pads and/or wipes. Do not use water for clean up. Collect in suitable and properly
labeled containers.
Large spills: Contain spilled material if possible. Pump into suitable and properly labeled containers.
SECTION 7 HANDLING AND STORAGE
Handling Precautions: Avoid contact with eyes. Wash thoroughly after handling.
Storage Requirements: Store indoors away from direct sunlight. Keep containers closed when not in use.
Shelf life: 24 Months
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: General ventilation should be sufficient for most operations. Personal Protection: HMIS PP, B I Safety Glasses, Gloves
Respiratory Protection: Wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced,
or where indicated by your risk
Christensen Arms AO Modification 9/7/23
Command Clean Heavy-Duty Degreaser Concentrate Issue Date
05/15/2015
3
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State
Odor Odor Threshold
Solubility
Spec Gravity/Density Viscosity
Boiling Point
Freezing/Melting Point
Flammability
Flash Point
Partition Coefficient
Vapor Pressure
Vapor Density
pH
VOC
Evaporation Rate
Auto Ignition Temperature Decomposition Temperature
UFL/LFL
Clear to yellowish
Liquid
Light Citrus N/D
Miscible in water in all proportions
0.998 +/- 0.003 (Hydrometer) N/D
N/D
N/D N/D
>200oF Test Method SW1010 A
N/D
<1.0 mm Hg @ 68°F (not including water content).
N/D
8 – 10
75 g/l in "Neat" form. 25 g/l when diluted 2:1 with H20, SCAQMD certified clean air solvent.
N/D
N/D N/D
N/D
SECTION 10 STABILITY AND REACTIVITY
Stability: Material is stable under normal conditions.
Materials To Avoid: This is a water-based product. Strong Acids; Strong Bases; Strong Oxidizing Agents.
Hazardous Decomposition Products: Will not occur.
Hazardous Polymerization: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Likely routes of exposure
Inhalation: Prolonged exposure is not expected to cause adverse effects.
Ingestion: Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury.
Skin: Non-irritating
Eyes: May cause eye irritation
Skin Corrosion/Irritation Non-irritant per Dermal Irritection assay modeling. No animal testing performed
Eye Damage/Irritation May cause mild eye irritation per Oclular Irritection assay modeling. No animal testing performed. (GHS Hazard
category 2B)
Germ Cell Mutagenicity: Mixture does not classify under this category
Carcinogenicity: Mixture does not classify under this category
Reproductive Toxicity: Mixture does not classify under this category
STOT-Single Exposure: Mixture does not classify under this category
STOT-Repeated Exposure: Mixture does not classify under this category
Aspiration Hazard: Mixture does not classify under this category
SECTION 12 ECOLOGICAL INFORMATION
Fish Toxicity LC50, Pimephales promelas, 96 hour: 156 ppm.
Aquatic Invertebrate Toxicity LC50, Daphnia pulex, 48 hour: 340 ppm.
Persistence and Degradability Biodegradation Tests: Fully biodegradable in accordance with ISO 9439.
SECTION 13 DISPOSAL CONSIDERATIONS
Dispose of uncontaminated material into sewer where applicable within Federal, State and/or local laws and regulations.
Disposal of contaminated material must be in compliance with all Federal, State and/or local laws and regulations. Regulations may vary in different locations. Waste
characterizations and compliance with applicable laws are the responsibility solely of the waste generator.
Christensen Arms AO Modification 9/7/23
Command Clean Heavy-Duty Degreaser Concentrate Issue Date
05/15/2015
4
SECTION 14 TRANSPORT INFORMATION
DOT: Not Regulated for Land Transport
TDG(Canada): Not Regulated for Land Transport
IMO/IMDG: Not Regulated for Sea Transport
AIR (IATA) : Not Regulated for Air Transport
This information is not intended to convey all specific regulatory or operational requirements information relating to this product. It is the responsibility of the
transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.
SECTION 15 REGULATORY INFORMATION
OSHA Hazard Communication Standard: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA
29 CFR 1910.1200.
National Chemical Inventory Listing: IECSC, PICCS, ENCS, EINECS, AICS, KECI, TSCA, DSL
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) Reportable Hazard Categories: None. SARA (313) Toxic Release Inventory: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic
Release Program.
California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
Command Clean urges each customer or recipient of this SOS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware
of and understand the data contained in this SOS and any hazards associated with the product. The information herein is provided in good faith and believed to be
accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that its activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's
duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific SDS5, we
are not and cannot be responsible for SDS5 obtained from any source other than ourselves. If you have obtained an SOS from another source or if you are not sure
that the SOS you have is current, please contact us for the most current version.
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet DOL-US
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 08/10/2015 Revision date: 10/31/2017 Supersedes: 01/27/2016 Version: 2.1
10/31/2017 EN (English US) SDS ID: DOL-US Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Product name : DOLPHIN GLAZE (DOL-US)
Product group : bodyfiller
Other means of identification : UP0713, UP0714
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier
U-POL US Inc
108 Commerce Way
Stockertown PA 18083 - USA
T 1-800-340-7824 - F 1-800-787-5150
technical.department@u-pol.com - www.u-pol.com
1.4. Emergency telephone number
Emergency number : CHEMTREC - 1-800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Carc. 2 H351 Repr. 2 H361
STOT RE 1 H372
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 - Flammable liquid and vapor
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H351 - Suspected of causing cancer
H361 - Suspected of damaging the unborn child. H372 - Causes damage to organs (hearing organs) through prolonged or repeated exposure
(Inhalation)
Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood.
P263 - Avoid contact during pregnancy/while nursing.
P264 - Wash hands thoroughly after handling.
P280 - Wear eye protection, protective clothing, protective gloves.
P302+P352 - If on skin: Wash with plenty of water
P305 - IF IN EYES: Rinse first with plenty of water and if necessary take medical advice
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 2/9
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
styrene (CAS-No.) 100-42-5 5 - 23 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Repr. 2, H361
STOT RE 1, H372
TITANIUM DIOXIDE (CAS-No.) 13463-67-7 < 5 Carc. 2, H351
ethylbenzene (CAS-No.) 100-41-4 < 5 Flam. Liq. 2, H225
Acute Tox. 4 (Inhalation), H332
Carc. 2, H351
STOT RE 2, H373
Asp. Tox. 1, H304
Full text of H-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact : Irritation.
Symptoms/effects after eye contact : Eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapor.
Reactivity : Flammable liquid and vapor.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Safety glasses. Protective clothing. Gloves.
Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe vapors, fume. Avoid contact with skin and eyes.
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 3/9
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment : Contain released substance, pump into suitable containers. Collect spillage.
Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Ground/bond container and receiving
equipment. Use only non-sparking tools. Take precautionary measures against static
discharge. Flammable vapors may accumulate in the container. Use explosion-proof
equipment. Wear personal protective equipment. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not breathe fume,
vapors. Avoid contact with skin and eyes.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ground/bond container and receiving equipment.
Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Storage temperature : < 25 °C
Storage area : Store in a well-ventilated place.
Special rules on packaging : Keep only in original container.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
DOLPHIN GLAZE (DOL-US)
ACGIH Not applicable
OSHA Not applicable
styrene (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
ACGIH Remark (ACGIH) CNS impair; URT irr; peripheral
OSHA Remark (OSHA) (2) See Table Z-2.
ethylbenzene (100-41-4)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH Remark (ACGIH) URT irr; kidney dam (nephropathy)
OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³
OSHA OSHA PEL (TWA) (ppm) 100 ppm
TITANIUM DIOXIDE (13463-67-7)
ACGIH ACGIH TWA (mg/m³) 1 mg/m³
ACGIH Remark (ACGIH) LRT irr; A3
OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 4/9
8.2. Exposure controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Personal protective equipment : Safety glasses. Gloves. Protective clothing.
Materials for protective clothing : Impermeable clothing.
Hand protection : Protective gloves.
Eye protection : Safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear respiratory protection.
Environmental exposure controls : Avoid release to the environment.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Viscous. Liquid.
Color : light green Odor : aromatic
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : No data available
Flash point : 30 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1.17 - 1.21
Solubility : insoluble in water. soluble in most organic solvents. Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available Viscosity, dynamic : 20000 - 25000 cP
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
VOC content - Regulatory : 220 g/l
SECTION 10: Stability and reactivity
10.1. Reactivity
Flammable liquid and vapor.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 5/9
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
styrene (100-42-5)
ATE US (gases) 4500 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
ethylbenzene (100-41-4)
ATE US (gases) 4500 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene (100-42-5)
IARC group 2B - Possibly carcinogenic to humans
National Toxicology Program (NTP) Status 3 - Reasonably anticipated to be Human Carcinogen
ethylbenzene (100-41-4)
IARC group 2B - Possibly carcinogenic to humans
TITANIUM DIOXIDE (13463-67-7)
IARC group 2B - Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging the unborn child.
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated
exposure
: Causes damage to organs (hearing organs) through prolonged or repeated exposure
(Inhalation).
Aspiration hazard : Not classified
Symptoms/effects after skin contact : Irritation.
Symptoms/effects after eye contact : Eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 6/9
12.5. Other adverse effects
Effect on ozone layer : No additional information available
Effect on the global warming : No known effects from this product.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Additional information : Flammable vapors may accumulate in the container.
SECTION 14: Transport information
In accordance with DOT
Transport document description : UN1866 Resin solution (flammable), 3, III
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
flammable
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid
Packing group (DOT) : III - Minor Danger
DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the
bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a
flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this
subchapter are applicable.
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672).
T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 60 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 220 L
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
Additional information
Other information : No supplementary information available.
ADR
Transport document description : UN 1866 RESIN SOLUTION, 3, III, (D/E)
Packing group (ADR) : III
Class (ADR) : 3 - Flammable liquid
Hazard identification number (Kemler No.) : 30
Classification code (ADR) : F1
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 7/9
Hazard labels (ADR) : 3 - Flammable liquids
Orange plates :
Tunnel restriction code (ADR) : D/E
LQ : 5l
Excepted quantities (ADR) : E1
Transport by sea
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
Air transport
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act
(SARA) of 1986 and 40 CFR Part 372.
styrene CAS-No. 100-42-5 5 - 23%
ethylbenzene CAS-No. 100-41-4 < 5%
xylene CAS-No. 1330-20-7 < 5%
styrene (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
ethylbenzene (100-41-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 313 - Emission Reporting 0.1 %
TITANIUM DIOXIDE (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
ethylbenzene (100-41-4)
Listed on the Canadian DSL (Domestic Substances List)
TITANIUM DIOXIDE (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 8/9
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3 H226 Skin Irrit. 2 H315
Eye Irrit. 2 H319
Repr. 2 H361
STOT RE 1 H372
Full text of hazard classes and H-statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
15.2.2. National regulations
styrene (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
Listed on EPA Hazardous Air Pollutant (HAPS)
\ ethylbenzene (100-41-4)
Listed on IARC (International Agency for Research on Cancer)
Listed on EPA Hazardous Air Pollutant (HAPS)
\ TITANIUM DIOXIDE (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
\ 15.3. US State regulations
California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of
California to cause cancer, developmental and/or reproductive harm
styrene (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk level
(NSRL)
Yes No No No
ethylbenzene (100-41-4)
U.S. - California - Proposition 65 -
Carcinogens List
U.S. - California - Proposition 65 -
Developmental Toxicity
U.S. - California - Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California - Proposition 65 -
Reproductive Toxicity -
Male
No significant risk level (NSRL)
Yes No No No 54 μg/day
SECTION 16: Other information
Revision date : 10/31/2017
Full text of H-phrases:
------ H225 Highly flammable liquid and vapour
------ H226 Flammable liquid and vapor
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled
------ H351 Suspected of causing cancer
------ H361 Suspected of damaging fertility or the unborn child
------ H372 Causes damage to organs through prolonged or repeated exposure
------ H373 May cause damage to organs through prolonged or repeated exposure
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.
NFPA fire hazard : 2 - Materials that must be moderately heated or exposed to
relatively high ambient temperatures before ignition can
occur.
NFPA reactivity : 1 - Materials that in themselves are normally stable but can
become unstable at elevated temperatures and pressures.
Christensen Arms AO Modification 9/7/23
DOLPHIN GLAZE (DOL-US)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/31/2017 EN (English US) SDS ID: DOL-US 9/9
SDS US UPOL
For professional use only. The information contained within this Safety Data Sheet (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products,
considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage
resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL’s recommendations for use, may substantially alter
the composition and hazards of the product. U-POL data sheets are available via the U-POL website at WWW.U-POL.COM.
Christensen Arms AO Modification 9/7/23
page 1 of 3
FLASH POINT
108 °F TCC
Specific Gravity
1.15
Product Weight
9.57 lb/gal
26 00 [0425]
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
Date of Preparation
May 20, 2019
PRODUCT NUMBER
V66V27
PRODUCT NAME
POLANE® Catalyst
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
V66V27 = | Acute | Chronic | Fire |
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
1-Methoxy-2-Propanol Acetate
108-65-6 N N N N 40 45
Non-Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Toluene-2,4-diisocyanate (max.)
584-84-9 Y Y Y Y 0.3 < 1
Volatile Organic Compounds - U.S. EPA / Canada
V66V27
LB/Gal g/L
Coating Density 9.57 1146
By wt By vol
Total Volatiles 40.0%45.3%
Federally exempt solvents
Water 0.0%0.0%
Organic Volatiles 40.0%45.3%
Percent Non-Volatile 60.0%54.7%
VOC Content LB/Gal g/L
Total 3.82 458
Less exempt solvents 3.82 458
Of solids 7.00 839
Of solids 0.66 lb/lb 0.66 kg/kg
By wt
By wt LVP-VOC 40.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.68
Christensen Arms AO Modification 9/7/23
V66V27
page 2 of 3
Volatile Organic Compounds - California
V66V27
LB/Gal g/L
Coating Density 9.57 1146
By wt By vol
Total Volatiles 40.0%45.3%
Exempt solvents
Water 0.0%0.0%
Organic Volatiles 40.0%45.3%
Percent Non-Volatile 60.0%54.7%
VOC Content LB/Gal g/L
Total 3.82 458
Less exempt solvents 3.82 458
Of solids 7.00 839
Of solids 0.66 lb/lb 0.66 kg/kg
By wt
By wt LVP-VOC 40.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.67
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
V66V27
LB/Gal g/L
Coating Density 9.57 1146
By wt By vol
Total Volatiles 40.0%45.3%
Exempt solvents
Water 0.0%0.0%
Organic Volatiles 40.0%45.3%
Percent Non-Volatile 60.0%54.7%
VOC Content LB/Gal g/L
Total 3.82 458
Less exempt solvents 3.82 458
Of solids 7.00 839
Of solids 0.66 lb/lb 0.66 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
V66V27
By wt By vol
Total Volatiles 40.0% 45.3%
VOC Content LB/Gal g/L
Total 3.82 458
Volatile Organic Compounds - EU Directive 2010/75/EU
V66V27
By wt By vol
Total Volatiles 40.0% 45.3%
VOC Content LB/Gal g/L
Total 3.82 458
Christensen Arms AO Modification 9/7/23
V66V27
page 3 of 3
Volatile Organic Compounds - Mexico
V66V27
LB/Gal g/L
Coating Density 9.57 1146
By wt By vol
Total Volatiles 40.0%45.3%
Exempt solvents
Water 0.0%0.0%
Organic Volatiles 40.0%45.3%
Percent Non-Volatile 60.0%54.7%
VOC Content LB/Gal g/L
Total 3.82 458
Less exempt solvents 3.82 458
Of solids 7.00 839
Of solids 0.66 lb/lb 0.66 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
V66V27
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
8.44 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
Christensen Arms AO Modification 9/7/23
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SAFETY DATA SHEET
34-200 Version: 4.1 US - en
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product name 5&,6SFUIBOF1SJNFS4VSGBDFS
Product code 34-200
Formula date 2017-01-26
Recommended use Coating for professional use
Responsible party National Coatings and Supplies
4900 Falls of Neuse Road Suite 150
Raleigh, NC 27609
Telephone Product information 866-529-1682
Medical emergency 800-424-9300
Transportation emergency 800-424-9300
2. HAZARDS IDENTIFICATION
GHS-Classification
Flammable liquids, Category 2 ; Skin corrosion/irritation, Category 2 ; Serious eye damage/eye irritation, Category 2A ;
Carcinogenicity, Category 2 ; Toxicity for reproduction, Category2;TargetOrganSystemic Toxicant - Repeated
exposure, Category 1
GHS-Labelling
Hazard symbols:
Signal word: Danger
Hazard statements:Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation.
Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure.
Precautionary statements:Obtain special instructions before use. Keep away from heat/sparks/open flames/hot
surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use
explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures
against static discharge. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Do not eat, drink or smoke when
using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with
plenty of soap and water. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin
with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. Specific treatment (see
supplemental first aid instructions on this label). If skin irritation occurs: Get medical advice/ attention. If eye
irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Store in a
well-ventilated place. Keep cool. Store locked up. Dispose of contents/container in accordance with local regulations.
Other hazards which do not result in classification
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
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0%
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture of synthetic resins, pigments, and solvents
Components
CAS-No. Chemical name Concentration
100-41-4 Ethylbenzene 3.0%
108-65-6 Propylene glycol monomethyl ether acetate 4 - 15%
110-12-3 Methyl isoamyl ketone 1 - 4%
123-86-4 Butyl acetate 4 - 15%
1330-20-7 Xylene 12%
1333-86-4 Carbon black 0.1%
13463-67-7 Titanium dioxide 5.8%
136-53-8 Zinc carboxylate 0.1%
78-93-3 Methyl ethyl ketone 4 - 15%
Any concentration shown as a range is due to batch variation.
Non-regulated ingredients 60 - 70%
OSHA Hazardous: Yes
4. FIRST AID MEASURES
Eye contact:Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the
eyelids apart. Seek medical advice.
Skin contact:Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly
with soap and water or use recognized skin cleanser. If skin irritation persists, call a physician.
Inhalation:Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If
breathing is irregular or stopped, administer artificial respiration. If unconscious place in recovery position and seek
medical advice. If symptoms persist, call a physician.
Ingestion:If swallowed, seek medical advice immediately and show this safety data sheet (SDS) or product label. Do
NOT induce vomiting. Keep at rest.
Most Important Symptoms/effects, acute and delayed
Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following
progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated
repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. If this product
mixed with an isocyanate activator/hardener (see SDS for the activator), the following health effects may apply:
Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an
asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be
delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function,
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which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be
exposed to vapors or spray mist of this product.
Ingestion:May result in gastrointestinal distress.
Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin
irritation with discomfort and dermatitis. If this product is mixed with an isocyanate, skin contact may cause
sensitization.
Indication of Immediate medical attention and special treatment needed if necessary:No data available on the
product. See section 3 and 11 for hazardous ingredients found in the product.
5. FIREFIGHTING MEASURES
Suitable extinguishing media:Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical
Extinguishing media which shall not be used for safety reasons:High volume water jet
Hazardous combustion products:CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition,
Information on Ingredients” section.
Fire and Explosion Hazards:Flammable liquid. Vapor/air mixture will burn when an ignition source is present.
Special Protective Equipment and Fire Fighting Procedures:Full protective flameproof clothing should be worn as
appropriate. Wear self-contained breathing apparatus for firefighting if necessary. In the event of fire, cool tanks with
water spray. Do not allow run-off from fire fighting to enter public sewer systems or public waterways.
6. ACCIDENTAL RELEASE MEASURES
Procedures for cleaning up spills or leaks:Ventilate area. Remove sources of ignition. Prevent skin and eye contact
and breathing of vapor. If the material contains, or is mixed with an isocyanate activator/hardener: Wear a
positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection, gloves and protective clothing. Pour
liquid decontamination solution over the spill and allow to sit at least 10 minutes. Typical decontamination solutions
for isocyanate containing materials are: 20% Surfactant (Tergitol TMN 10) and 80% Water OR 0 -10% Ammonia, 2-5%
Detergent and Water (balance) Pressure can be generated. Do not seal waste containers for 48 hours to allow C02 to
vent. After 48 hours, material may be sealed and disposed of properly. If material does not contain or is not mixed with
an isocyanate activator/hardener: Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH
approved TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of
properly.
Environmental precautions:Do not let product enter drains. Notify the respective authorities in accordance with local
law in the case of contamination of rivers, lakes or waste water systems.
7. HANDLING AND STORAGE
Precautions for safe handling:Observe label precautions. Keep away from heat, sparks, flame, static discharge and
other sources of ignition. VAPORS MAY CAUSE FLASH FIRE. Close container after each use. Ground containers when
pouring. Do not transfer contents to bottles or unlabeled containers. Wash thoroughly after handling and before eating
or smoking. Do not store above 49
◦C (120
◦F). If material is a coating: do not sand, flame cut, braze or weld dry coating
without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation, and gloves.
Combustible dust clouds may be created where operations produce fine material (dust). Avoid formation of significant
deposits of material as they may become airborne and form combustible dust clouds. Build up of fine material should
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be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods (e.g. compressed
air) which can generate potentially combustible dust clouds should not be used.
Advice on protection against fire and explosion:Solvent vapours are heavier than air and may spread along floors.
Vapors may form explosive mixtures with air and will burn when an ignition source is present. Always keep in
containers of same material as the original one. Never use pressure to empty container: container is not a pressure
vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards
and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards.
Storage
Requirements for storage areas and containers:Observe label precautions. Store in a dry, well ventilated place away
from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Advice on common storage:Store separately from oxidizing agents and strongly alkaline and strongly acidic materials.
OSHA/NFPA Storage Classification: IB
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls and work practices:Provide adequate ventilation.This should be achieved by a good general
extraction and -if practically feasible- by the use of a local exhaust ventilation.If these are not sufficient to maintain
concentrations of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.
National occupational exposure limits
CAS-No. Chemical name Source Time Type Value Note
1330-20-7 Xylene ACGIH 15 min STEL 150 ppm
ACGIH 8 hr TWA 100 ppm
OSHA 8 hr TWA 100 ppm
13463-67-7 Titanium dioxide OSHA 8 hr TWA 15 mg/m3 Total Dust
123-86-4 Butyl acetate ACGIH 15 min STEL 200 ppm
ACGIH 8 hr TWA 150 ppm
OSHA 8 hr TWA 150 ppm
78-93-3 Methyl ethyl ketone ACGIH 8 hr TWA 200 ppm
OSHA 8 hr TWA 200 ppm
100-41-4 Ethylbenzene ACGIH 8 hr TWA 20 ppm
OSHA 8 hr TWA 100 ppm
110-12-3 Methyl isoamyl ketone ACGIH 8 hr TWA 20 ppm
1333-86-4 Carbon black ACGIH 8 hr TWA 3 mg/m3
OSHA 8 hr TWA 3.5 mg/m3
Glossary
CEIL Ceiling exposure limit
STEL Short term exposure limit
TL Threshold limits
TLV Threshold Limit Value
TWA Time weighted average
TWAE Time-Weighted Average
Protective equipment:Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection:Do not breathe vapors or mists. When this product is used with an isocyanate
activator/hardener, wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C) while mixing
activator/hardener with paint, during application and until all vapors and spray mist are exhausted. If product is used
without isocyanate activator/hardener, a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH
TC-23C) and particulate filter (NIOSH TC-84A) may be used. Follow respirator manufacturer’s directions for respirator
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use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label instructions
and SDS for further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates
should not use or be exposed to this product if mixed with isocyanate activators/hardeners.
Eye protection:Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses
are substituted, include splash guard or side shields.
Skin and body protection:Neoprene gloves and coveralls are recommended.
Hygiene measures:Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners.
Environmental exposure controls:Do not let product enter drains.
For ecological information, refer to Ecological Information Section 12.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form:liquid Colour:grey
Flash point 45◦F
Lower Explosive Limit 1%
Upper Explosive Limit 11.5 %
Evaporation rate Slower than Ether
Vapor pressure of principal solvent 12.8 hPa
Water solubility appreciable
Vapor density of principal solvent (Air = 1)3.7
Approx. Boiling Range 78◦C
Approx. Freezing Range Not applicable.
Gallon Weight (lbs/gal)11.84
Specific Gravity 1.42
Percent Volatile By Volume 58.29%
Percent Volatile By Weight 35.17%
Percent Solids By Volume 41.71%
Percent Solids By Weight 64.83%
pH (waterborne systems only)No data available.
Partition coefficient: n-octanol/water No data available
Ignition temperature 272◦C DIN 51794
Decomposition temperature Not applicable.
Viscosity (23
◦C)Not applicable. ISO 2431-1993
VOC* less exempt (lbs/gal)4.1
VOC* as packaged (lbs/gal)4.1
* VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at
the point of manufacture.
10. STABILITY AND REACTIVITY
Stability:Stable
Conditions to avoid:Stable under recommended storage and handling conditions (see section 7).
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Materials to avoid:None reasonably foreseeable.
Hazardous decomposition products:When exposed to high temperatures may produce hazardous decomposition
products such as carbon monoxide and dioxide, smoke, oxides of nitrogen.
Hazardous Polymerization:Will not occur.
Sensitivity to Static Discharge:Solvent vapors in air may explode if static grounding and bonding is not used during
transfer of this product.
Sensitivity to Mechanical Impact:None known.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following
progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated
repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. If this product
mixed with an isocyanate activator/hardener (see SDS for the activator), the following health effects may apply:
Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an
asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be
delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function,
which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be
exposed to vapors or spray mist of this product.
Ingestion:May result in gastrointestinal distress.
Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin
irritation with discomfort and dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
Acute oral toxicity
not hazardous
Acute dermal toxicity
not hazardous
Acute inhalation toxicity
not hazardous
% of unknown composition: 0 %
Skin corrosion/irritation
Xylene Category 2
Butyl acetate Category 3
Methyl ethyl ketone Category 3
Propylene glycol monomethyl ether acetate Category 3
Ethylbenzene Category 2
Methyl isoamyl ketone Category 3
Serious eye damage/eye irritation
Xylene Category 2A
Methyl ethyl ketone Category 2A
Propylene glycol monomethyl ether acetate Category 2B
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Methyl isoamyl ketone Category 2A
Respiratory sensitisation
Not classified according to GHS criteria
Skin sensitisation
Not classified according to GHS criteria
Germ cell mutagenicity
Not classified according to GHS criteria
Carcinogenicity
Titanium dioxide Category 2
Ethylbenzene Category 2
Carbon black Category 2
Toxicity for reproduction
Zinc carboxylate Category 2
Target Organ Systemic Toxicant - Single exposure
Not classified according to GHS criteria
Target Organ Systemic Toxicant - Repeated exposure
•Inhalation
Respiratory system Carbon black, Titanium dioxide
Aspiration toxicity
Not classified according to GHS criteria
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. ):No information available.
Symptoms related to the physical, chemical and toxicological characteristics:
Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result
in adverse health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver
and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness
and in extreme cases, loss of consciousness. Through skin resorbtion, solvents can cause some of the effects described
here. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in
non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation
and reversible damage.
Whether the hazardous chemical is listed by NTP, IARC or OSHA:
Titanium dioxide IARC 2B
Ethylbenzene IARC 2B
Carbon black IARC 2B
12. ECOLOGICAL INFORMATION
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
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13. DISPOSAL CONSIDERATIONS
Waste Disposal Method:Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose
of waste material in accordance with Federal, State, Provincial, and local requirements. Do not incinerate in closed
containers.
14. TRANSPORT INFORMATION
International transport regulations
IMDG (Sea transport)
UN number: 1263
Proper shipping name: PAINT
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
Marine Pollutant: no
EmS: F-E,S-E
ICAO/IATA (Air transport)
UN number: 1263
Proper shipping name: PAINT
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
DOT
UN number: 1263
Proper shipping name: PAINT
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
Marine Pollutant: no
The transport information is for bulk shipments. Exceptions may apply for smaller containers.
Matters needing attention for transportation:Confirm that there is no breakage, corrosion, or leakage from the
container before shipping. Be sure to prevent damage to cargo by loading so as to avoid falling, dropping, or collapse.
Ship in appropriate containers with denotation of the content in accordance with the relevant statutes and rules.
15. REGULATORY INFORMATION
TSCA Status:In compliance with TSCA Inventory requirements for commercial purposes.
DSL Status:All components of the mixture are listed on the DSL.
Photochemical Reactivity:Photochemically reactive
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Regulatory information:
—————— EPCRA —————– CERCLA CAA
CAS # Ingredient 302 TPQ RQ 311/312 313 RQ(lbs) HAP
1330-20-7 Xylene N NR NR A,C,F,N,P,R Y 100 Y
13463-67-7 Titanium dioxide N NR NR A N NR N
123-86-4 Butyl acetate N NR NR A,C,F N NR N
78-93-3 Methyl ethyl ketone N NR NR A,C,F N 5,000 N
108-65-6 Propylene glycol
monomethyl ether
acetate
NNRNR F N NRN
100-41-4 Ethylbenzene N NR NR A,C,F Y 1,000 Y
110-12-3 Methyl isoamyl ketone N NR NR C N NR N
136-53-8 Zinc carboxylate N NR NR A,C,F,N,P,R Y NR N
1333-86-4 Carbon black N NR NR C N NR N
16. OTHER INFORMATION
HMIS rating:H:2;F:3;R:0
Glossary of Terms
ACGIH American Conference of Governmental Industrial Hygienists.
IARC International Agency for Research on Cancer.
NTP National Toxicology Program.
OEL Occupational Exposure Limit
OSHA Occupational Safety and Health Administration.
STEL Short term exposure limit
TWA Time-weighted average.
PNOR Particles not otherwise regulated.
PNOC Particles not otherwise classified.
EPCRA Emergency Planning and Community Right-to-know Act (aka Title III,
SARA)
302 Extremely hazardous substances
311/312 Categories F = Fire Hazard A = Acute Hazard
R = Reactivity Hazard C = Chronic Hazard
P = Pressure Related Hazard
313 Information Section 313 Supplier Notification - The chemicals listed above with
a ’Y’ in the 313 column are subject to reporting requirements of
Section 313 of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA Comprehensive Emergency Response, Compensation and Liability Act of
1980.
HAP Listed as a Clean Air Act Hazardous Air Pollutant.
TPQ Threshold Planning Quantity.
RQ Reportable Quantity
NA not available
NR not regulated
NOTE: The list (above) of glossary terms may be modified.
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Information is accurate and subject to change as new information is received.
The information on this Safety Data Sheet relates only to the specific material designated herein and does not relate to
use in combination with any other material or in any process.
SDS Prepared by Regulatory Affairs
Report version
Version:4.1
Changes:
Revision Date:2018-03-19
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SAFETY DATA SHEET
34-202 Version: 5.0 US - en
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product name
6SFUIBOF1SJNFS4VSGBDFS"DUJWBUPS
"DUJWBUPSGPS5&,
Product code 34-202
Formula date 2015-10-01
Recommended use Hardener for professional use
Responsible party National Coatings and Supplies
4900 Falls of Neuse Road Suite 150
Raleigh, NC 27609
Telephone Product information 866-529-1682
Medical emergency 800-424-9300
Transportation emergency 800-424-9300
2. HAZARDS IDENTIFICATION
GHS-Classification
Flammable liquids, Category 2 ; Skin corrosion/irritation, Category 2 ; Serious eye damage/eye irritation, Category 2A ;
Respiratory sensitisation, Category 1 ; Skin sensitisation, Category 1 ; Carcinogenicity, Category 2 ; Toxicity for
reproduction, Category2;TargetOrganSystemic Toxicant - Single exposure, Category3;TargetOrganSystemic
Toxicant - Repeated exposure, Category 2
GHS-Labelling
Hazard symbols:
Signal word: Danger
Hazard statements:Highly flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause
respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging
fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure.
Precautionary statements:Obtain special instructions before use. Keep away from heat/sparks/open flames/hot
surfaces. No smoking. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static
discharge. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye
protection/face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with
plenty of soap and water. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin
with water/ shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific
treatment (see supplemental first aid instructions on this label). If skin irritation or rash occurs: Get medical advice/
attention. If eye irritation persists: Get medical advice/ attention. If experiencing respiratory symptoms: Call a
POISON CENTER/doctor. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep
container tightly closed. Store locked up. Dispose of contents/container in accordance with local regulations.
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Other hazards which do not result in classification
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
0%
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture of synthetic resins and solvents
Components
CAS-No. Chemical name Concentration
100-41-4 Ethylbenzene 6.1%
108-88-3 Toluene 7%
123-86-4 Butyl acetate 1 - 4%
1330-20-7 Xylene 24%
141-78-6 Ethyl acetate 15 - 26%
28182-81-2 Aliphatic polyisocyanate resin 26 - 37%
4083-64-1 P-toluenesulfonyl isocyanate 0.1 - 1.0%
78-93-3 Methyl ethyl ketone 1 - 4%
Any concentration shown as a range is due to batch variation.
Non-regulated ingredients 1 - 5%
OSHA Hazardous: Yes
4. FIRST AID MEASURES
Eye contact:Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the
eyelids apart. Seek medical advice.
Skin contact:Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly
with soap and water or use recognized skin cleanser. If skin irritation persists, call a physician.
Inhalation:Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If
breathing is irregular or stopped, administer artificial respiration. If unconscious place in recovery position and seek
medical advice. If symptoms persist, call a physician.
Ingestion:If swallowed, seek medical advice immediately and show this safety data sheet (SDS) or product label. Do
NOT induce vomiting. Keep at rest.
Most Important Symptoms/effects, acute and delayed
Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following
progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated
repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Exposure to
isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like
reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for
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several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may
be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to
vapors or spray mist of this product.
Ingestion:May result in gastrointestinal distress.
Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin
irritation with discomfort and dermatitis. Skin contact my cause skin sensitization.
Indication of Immediate medical attention and special treatment needed if necessary:No data available on the
product. See section 3 and 11 for hazardous ingredients found in the product.
5. FIREFIGHTING MEASURES
Suitable extinguishing media:Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical
Extinguishing media which shall not be used for safety reasons:High volume water jet
Hazardous combustion products:CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition,
Information on Ingredients” section.
Fire and Explosion Hazards:Flammable liquid. Vapor/air mixture will burn when an ignition source is present.
Special Protective Equipment and Fire Fighting Procedures:Full protective flameproof clothing should be worn as
appropriate. Wear self-contained breathing apparatus for firefighting if necessary. In the event of fire, cool tanks with
water spray. Do not allow run-off from fire fighting to enter public sewer systems or public waterways.
6. ACCIDENTAL RELEASE MEASURES
Procedures for cleaning up spills or leaks:Ventilate area. Remove sources of ignition. Do not breathe vapors. Do not
get in eyes or on skin. Wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection,
gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit at least 10 minutes.
Typical decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TM 10) and 80%
Water OR 0-10% Ammonia, 2-5% Detergent and Water (balance) Confine and remove with inert absorbent. Pressure can
be generated. Do not seal waste containers for 48 hours to allow C02 to vent. After 48 hours, material may be sealed
and disposed of properly.
Environmental precautions:Do not let product enter drains. Notify the respective authorities in accordance with local
law in the case of contamination of rivers, lakes or waste water systems.
7. HANDLING AND STORAGE
Precautions for safe handling:Observe label precautions. Keep away from heat, sparks, flame, static discharge and
other sources of ignition. VAPORS MAY CAUSE FLASH FIRE. Close container after each use. Ground containers when
pouring. Do not transfer contents to bottles or unlabeled containers. Wash thoroughly after handling and before eating
or smoking. Do not store above 49
◦C (120
◦F). If material is a coating: do not sand, flame cut, braze or weld dry coating
without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation, and gloves.
Combustible dust clouds may be created where operations produce fine material (dust). Avoid formation of significant
deposits of material as they may become airborne and form combustible dust clouds. Build up of fine material should
be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods (e.g. compressed
air) which can generate potentially combustible dust clouds should not be used.
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Advice on protection against fire and explosion:Solvent vapours are heavier than air and may spread along floors.
Vapors may form explosive mixtures with air and will burn when an ignition source is present. Always keep in
containers of same material as the original one. Never use pressure to empty container: container is not a pressure
vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards
and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards.
Storage
Requirements for storage areas and containers:Observe label precautions. Store in a dry, well ventilated place away
from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Advice on common storage:Store separately from oxidizing agents, strongly alkaline and strongly acidic materials,
amines, alcohols and water. Precautions should be taken to avoid exposure to atmospheric humidity or water.
Evolution of CO2 in closed containers causes overpressure and produces a risk of bursting.
Additional information on storage conditions:Precautions should be taken to avoid exposure to atmospheric
humidity or water. Humid air and/or water will produce carbon dioxide which will pressurize the container. Open drum
carefully as content may be under pressure.
OSHA/NFPA Storage Classification: IB
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls and work practices:Provide adequate ventilation.
National occupational exposure limits
CAS-No. Chemical name Source Time Type Value Note
1330-20-7 Xylene ACGIH 15 min STEL 150 ppm
ACGIH 8 hr TWA 100 ppm
OSHA 8 hr TWA 100 ppm
141-78-6 Ethyl acetate ACGIH 8 hr TWA 400 ppm
OSHA 8 hr TWA 400 ppm
108-88-3 Toluene OSHA CEIL 300 ppm
OSHA 10 min TWA 500 ppm
OSHA 8 hr TWA 200 ppm
100-41-4 Ethylbenzene ACGIH 8 hr TWA 20 ppm
OSHA 8 hr TWA 100 ppm
123-86-4 Butyl acetate ACGIH 15 min STEL 200 ppm
ACGIH 8 hr TWA 150 ppm
OSHA 8 hr TWA 150 ppm
78-93-3 Methyl ethyl ketone ACGIH 8 hr TWA 200 ppm
OSHA 8 hr TWA 200 ppm
Glossary
CEIL Ceiling exposure limit
STEL Short term exposure limit
TL Threshold limits
TLV Threshold Limit Value
TWA Time weighted average
TWAE Time-Weighted Average
Protective equipment:Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection:Do not breathe vapors or mists. Wear a positive-pressure, supplied air respirator (NIOSH
approved TC-19C), while mixing activator with paint, during application and until all vapors and spray mists are
exhausted. Follow respirator manufacturer s directions for respirator use. Do not permit anyone without protection in
the painting area. Refer to the hardener/activator label instructions for further information. Individuals with history of
lung or breathing problems or prior reaction to isocyanates should not use or be exposed to vapor or spray mist.
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Eye protection:Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses
are substituted, include splash guard or side shields.
Skin and body protection:Neoprene gloves and coveralls are recommended.
Hygiene measures:Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners.
Environmental exposure controls:Do not let product enter drains.
For ecological information, refer to Ecological Information Section 12.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form:liquid Colour:clear Odour:Characteristic Paint Odor
Flash point 38◦F
Lower Explosive Limit 1%
Upper Explosive Limit 11.4 %
Evaporation rate Slower than Ether
Vapor pressure of principal solvent 29.1 hPa
Water solubility moderate
Vapor density of principal solvent (Air = 1)3.7
Approx. Boiling Range 70◦C
Approx. Freezing Range Not applicable.
Gallon Weight (lbs/gal)8.01
Specific Gravity 0.96
Percent Volatile By Volume 71.74%
Percent Volatile By Weight 65.57%
Percent Solids By Volume 28.26%
Percent Solids By Weight 34.43%
pH (waterborne systems only)Not applicable
Partition coefficient: n-octanol/water No data available
Ignition temperature 404◦C DIN 51794
Decomposition temperature Not applicable.
Viscosity (23
◦C)Not applicable. ISO 2431-1993
VOC* less exempt (lbs/gal)5.3
VOC* as packaged (lbs/gal)5.3
* VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at
the point of manufacture.
10. STABILITY AND REACTIVITY
Stability:Stable
Conditions to avoid:Stable under recommended storage and handling conditions (see section 7).
Materials to avoid:Keep away from oxidizing agents and strongly acid or alkaline materials. Amines and alcohols
cause exothermic reactions. Mixture reacts slowly with water resulting in evolution of CO2. Evolution of CO2 in closed
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containers causes overpressure and produces a risk of bursting.
Hazardous decomposition products:When exposed to high temperatures may produce hazardous decomposition
products such as carbon monoxide and dioxide, smoke, oxides of nitrogen as well as hydrogen cyanide, amines,
alcohols and water.
Hazardous Polymerization:Will not occur.
Sensitivity to Static Discharge:Solvent vapors in air may explode if static grounding and bonding is not used during
transfer of this product.
Sensitivity to Mechanical Impact:None known.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following
progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated
repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Exposure to
isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like
reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for
several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may
be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to
vapors or spray mist of this product.
Ingestion:May result in gastrointestinal distress.
Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin
irritation with discomfort and dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
Acute oral toxicity
not hazardous
Acute dermal toxicity
Not classified according to GHS criteria
Acute inhalation toxicity
Not classified according to GHS criteria
% of unknown composition: 0 %
Skin corrosion/irritation
Xylene Category 2
Ethyl acetate Category 3
Toluene Category 2
Ethylbenzene Category 2
Butyl acetate Category 3
Methyl ethyl ketone Category 3
P-toluenesulfonyl isocyanate Category 2
Serious eye damage/eye irritation
Xylene Category 2A
Ethyl acetate Category 2A
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Methyl ethyl ketone Category 2A
P-toluenesulfonyl isocyanate Category 2A
Respiratory sensitisation
P-toluenesulfonyl isocyanate Category 1
Skin sensitisation
Aliphatic polyisocyanate resin Category 1
Germ cell mutagenicity
Not classified according to GHS criteria
Carcinogenicity
Ethylbenzene Category 2
Toxicity for reproduction
Toluene Category 2
Target Organ Systemic Toxicant - Single exposure
•Inhalation
Narcotic effects Ethyl acetate
Respiratory system Aliphatic polyisocyanate resin
Target Organ Systemic Toxicant - Repeated exposure
No data available.
Aspiration toxicity
Not classified according to GHS criteria
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. ):No information available.
Symptoms related to the physical, chemical and toxicological characteristics:
Based on the properties of the isocyanate components and considering toxicological data on similar products, the
following applies: This formulation may cause acute irritation and/or sensitization of the respiratory system leading to
an asthmatic condition, wheeziness and a tightness of the chest. Sensitized persons may subsequently show asthmatic
symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent
respiratory disability. Exposure to component solvents vapours concentration in excess of the stated occupational
exposure limit may result in adverse health effect such as mucous membrane and respiratory system irritation and
adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue,
muscular weakness, drowsiness and in extreme cases, loss of consciousness. Through skin resorbtion, solvents can
cause some of the effects described here. Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid
splashed in the eyes may cause irritation and reversible damage. Components of the product may be absorbed into the
body through the skin.
Whether the hazardous chemical is listed by NTP, IARC or OSHA:
Ethylbenzene IARC 2B
12. ECOLOGICAL INFORMATION
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
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13. DISPOSAL CONSIDERATIONS
Waste Disposal Method:Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose
of waste material in accordance with Federal, State, Provincial, and local requirements. Do not incinerate in closed
containers.
14. TRANSPORT INFORMATION
International transport regulations
IMDG (Sea transport)
UN number: 1263
Proper shipping name: PAINT RELATED MATERIAL
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
Marine Pollutant: no
EmS: F-E,S-E
ICAO/IATA (Air transport)
UN number: 1263
Proper shipping name: PAINT RELATED MATERIAL
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
DOT
UN number: 1263
Proper shipping name: PAINT RELATED MATERIAL
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
Marine Pollutant: no
The transport information is for bulk shipments. Exceptions may apply for smaller containers.
Matters needing attention for transportation:Confirm that there is no breakage, corrosion, or leakage from the
container before shipping. Be sure to prevent damage to cargo by loading so as to avoid falling, dropping, or collapse.
Ship in appropriate containers with denotation of the content in accordance with the relevant statutes and rules.
15. REGULATORY INFORMATION
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TSCA Status:In compliance with TSCA Inventory requirements for commercial purposes.
DSL Status:All components of the mixture are listed on the DSL.
Photochemical Reactivity:Photochemically reactive
Regulatory information:
—————— EPCRA —————– CERCLA CAA
CAS # Ingredient 302 TPQ RQ 311/312 313 RQ(lbs) HAP
28182-81-2 Aliphatic polyisocyanate
resin
N NR NR A,C,R N NR N
1330-20-7 Xylene N NR NR A,C,F,N,P,R Y 100 Y
141-78-6 Ethyl acetate N NR NR C,F N NR N
108-88-3 Toluene N NR NR A,C,F Y 1,000 Y
100-41-4 Ethylbenzene N NR NR A,C,F Y 1,000 Y
123-86-4 Butyl acetate N NR NR A,C,F N NR N
78-93-3 Methyl ethyl ketone N NR NR A,C,F N 5,000 N
4083-64-1 P-toluenesulfonyl iso-
cyanate
N NR NR A,C,R N NR N
16. OTHER INFORMATION
HMIS rating:H:3;F:3;R:1
Glossary of Terms
ACGIH American Conference of Governmental Industrial Hygienists.
IARC International Agency for Research on Cancer.
NTP National Toxicology Program.
OEL Occupational Exposure Limit
OSHA Occupational Safety and Health Administration.
STEL Short term exposure limit
TWA Time-weighted average.
PNOR Particles not otherwise regulated.
PNOC Particles not otherwise classified.
EPCRA Emergency Planning and Community Right-to-know Act (aka Title III,
SARA)
302 Extremely hazardous substances
311/312 Categories F = Fire Hazard A = Acute Hazard
R = Reactivity Hazard C = Chronic Hazard
P = Pressure Related Hazard
313 Information Section 313 Supplier Notification - The chemicals listed above with
a ’Y’ in the 313 column are subject to reporting requirements of
Section 313 of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA Comprehensive Emergency Response, Compensation and Liability Act of
1980.
HAP Listed as a Clean Air Act Hazardous Air Pollutant.
TPQ Threshold Planning Quantity.
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RQ Reportable Quantity
NA not available
NR not regulated
NOTE: The list (above) of glossary terms may be modified.
Information is accurate and subject to change as new information is received.
The information on this Safety Data Sheet relates only to the specific material designated herein and does not relate to
use in combination with any other material or in any process.
SDS Prepared by Regulatory Affairs
Report version
Version:5.0
Changes:
Revision Date:2018-03-23
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SAFETY DATA SHEET (SDS)
SDS #500
1.IDENTIFICATION
Product Type: Carbon steel and low alloy steel electrodes for arc welding
Product Names: E8018-B2, E9018-B3, E8018-C1, E8018-C2, E8018-C3, E10018-D2, E9018M,
E11018M, E12018M, E7010-P1, E8010-P1, ER70S-2, ER70S-3, ER70S-6,
ER70S-7, E70C-6M, ER70S6 (Copper free)
Specifications: AWS A5.5, A5.18, A5.28
Product Intended/Recommended Use: Arc welding
Manufacturer: Welding Material Sales
1340 Reed Road
Geneva, IL 60134
Tel: 630-232-6421
Fax: 888-733-1512
Email: info@weldingmaterialsales.com
Emergency Telephone Number: 800-424-9300
2.HAZARD IDENTIFICATION
Hazard Classification: Not classified as hazardous according to the applicable Globally Harmonized System of
Classification and Labelling of Chemicals (GHS) and OSHA Hazard Communication Standard (29 CFR 1910.1200) criteria.
Label Elements:
Hazard Symbol – None
Signal Word – None
Hazard Statement – Not Applicable
Precautionary Statement – Not Applicable
Other Hazards: This product presents no hazards in its intrinsic form. However, several hazards are generated during
welding operations that can be harmful.
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ELECTRICITY- Electric shock can kill.
HEAT- Molten metal and weld spatter can burn skin and start fires.
RADIATION- Arc rays can injure eyes and burn skin.
FUMES AND GASES - Fumes and gases generated during welding can be dangerous to your health. See Section
11.
3.COMPOSITION/INFORMATION ON INGREDIENTS
Common Name Weight %
Iron 70-98
Manganese 0-4
Silicon 0-3
Silica 0-3
Aluminum 0-5
Aluminum Oxide 0-1
Chromium 0-10.0
Nickel 0-3
Niobium 0-0.3
Magnesium and compounds 0-3
Molybdenum 0-1.2
Titanium 0-0.5
Titanium Dioxide 0-10
Vanadium 0-0.3
Barium Compounds 0-10
Lithium Compounds (as Li) 0-9
Iron Oxide 0-12
Zirconium and Compounds (as Zr) 0-1
Fluorides 0-12
Graphite 0-0.5
Copper 0-0.8
4.FIRST AID MEASURES
Inhalation - If breathing has stopped, immediately seek medical assistance. Begin performing cardio pulmonary
resuscitation (CPR) if you are trained to do so. If breathing is difficult, move to area with fresh air and seek medical
attention immediately.
Skin contact - For skin burns due to arc radiation flush with cold water. If burn and irritation persists seek medical
attention. In case of skin contact with fume or dust, wash affected areas with soap and water. Thoroughly clean shoes and
wash clothing. Seek medical attention if irritation develops and persists.
Eye contact - In case of radiation burns due to arc flash move to a dark room and seek medical attention. To remove fume
or dust flush with plenty of lukewarm water. Seek medical attention if irritation develops. In case of foreign metallic or slag
material lodged in the eye, seek medical attention to remove it. Do not rub or agitate the eyes.
Ingestion – Although unlikely due to product form, immediately seek medical attention if wire pieces or metal powders
from inside the wire are ingested. Do not induce vomiting unless directed to do so by medical personnel.
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Electric Shock - Disconnect power. Use non-conductive material to pull victim from contact with live wires. If no
detectible pulse, seek medical attention immediately and begin cardio pulmonary resuscitation (CPR) if you are trained to
do so.
Most Serious Symptoms:
Short Term Exposure – Acute overexposure to welding fumes may result in discomfort such as irritation of the respiratory
system, metal fume fever, nausea, and may aggravate pre-existing respiratory conditions.
Long Term Exposure – Chronic overexposure to welding fume may lead to iron deposits in the lungs (siderosis) and
reduced pulmonary function. Manganese overexposure can lead to irreversible damage to the central nervous system
resulting in impaired speech and movement. Chronic overexposure to nickel fumes and hexavalent chromium can cause
cancer. Some of the products contain silica quartz, but not in an inhalable fraction. Silica quartz is a listed carcinogen.
Refer to Section 11 for more information.
5. FIRE FIGHTING MEASURES
General - Products are non-flammable as shipped. Welding arcs and spatter can ignite nearby combustible materials.
Suitable Extinguishing Media- Use methods and materials appropriate for the combustible material.
Specific Hazards Arising from the Chemical - Welding arcs and spatter can ignite nearby combustible materials.
General Firefighting Procedures- Keep people away. Isolate fire and deny entry to the area by any non-essential personnel.
Fight fire from protected location or safe distance.
Special Actions for Firefighters- Firefighters should be equipped with self-contained breathing apparatus to protect against
potentially toxic and hazardous fumes. Toxic and irritating fumes and gases may be given off during burning or thermal
decomposition.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures:
For Non-Emergency Personnel – Isolate the area and keep non-essential people away. Do not touch or walk through
spilled material. Allow the molten metallic material to solidify and cool before disposal. If molten metal spills out of
the weldment, turn off the power. Contain the flow using sand or submerged arc flux. If airborne dust and or fumes are
present, wear appropriate personal protective equipment (PPE) to avoid overexposure.
For Emergency Personnel – Wear appropriate personal protective equipment (PPE), including clothes, gloves and
breathing protection. Evacuate non-essential personnel.
Environmental Precautions: Keep material out of waterways and drains.
Methods and Materials for Containment and Cleaning Up: Isolate and clean up spills immediately. Avoid generating dust
or airborne particles during clean up. Dispose of solidified mass per Federal, State and Local regulations.
7. HANDLING AND STORAGE
Precautions for Safe Handling: Wear safety glasses and gloves to avoid cuts and abrasion when handling welding
consumables and their packaging. Do not eat drink or smoke in areas where these products are being used.
Conditions for Safe Storage, Including Any Incompatibilities: Store in a cool, dry area in the original packaging. Keep
products away from heat, flame and moisture.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Appropriate Engineering Controls: Provide adequate ventilation and/or local exhaust at the weld station to keep fumes and
gases away from the welder. Train welders and welding operators to keep their head out of the fumes. See ANSI Z49.1
“Safety in Welding, Cutting, and Allied Processes” for recommendations of safe work practices.
Personal Protective Equipment:
Eye/Face Protection – Wear safety glasses or goggles with appropriate side shields. Wear a helmet or face shield
with an appropriate filter lens. Use protective screens to shield others in the work area.
Skin/Body Protection – Wear hand, head and body protection including welder’s gloves, protective face shield and
long sleeved protective clothing.
Respiratory Protection – Use NIOSH approved fume respirator or air supplied respirator when where ventilation is
inadequate, welding in confined spaces or where required to by OSHA regulations. Fume sampling per AWS F1.1
“Method for Sampling Airborne Particulates Generated by Welding and Allied Processes” may be required. Other
appropriate standards that may be considered include, but are not limited to, AWS F1.2 “Laboratory Method for
Measuring Fume Generation Rate and Total Fume Emission of Welding and Allied Processes” and AWS F3.2
“Ventilation Guide for Weld Fume”. For actual weld fume and particulate analysis, refer to the appropriate analytical
methods recommended by NIOSH or OSHA, and consult an industrial hygiene professional.
Control Parameters:
Exposure Limits - USA
Common Name CAS
Number Form Exposure Limit Source
Aluminum Metal 7429-90-5 Total Dust 15 mg/m3 USA. OSHA PELs
Total Dust 10 mg/m3 USA. California OSHA PELs
Respirable 5 mg/m3 USA. OSHA PELs
Respirable 1 mg/m3 USA. ACGIH TLVs
Aluminum Oxide 1344-28-1 Total Dust 15 mg/m3 USA. OSHA PELs
Respirable 5 mg/m3 USA. OSHA PELs
Respirable 1 mg/m3 USA. ACGIH TLVs
Barium
Compounds
7440-39-3 Soluble Compounds 0.5 mg/m3 USA. OSHA PELs
Soluble Compounds 0.5 mg/m3 USA. ACGIH TLVs
Calcium
Carbonate
1317-65-3 Total Dust 15 mg/m3 USA. OSHA PELs
Total Dust 10 mg/m3 USA. California OSHA PELs
Respirable 5 mg/m3 USA. OSHA PELs
Chromium 7440-47-3 Metal 1 mg/m3 USA. OSHA PELs
Metal 0.5 mg/m3 USA. ACGIH TLVs
Cr II compounds 0.5 mg/m3 USA. OSHA PELs
Cr III Compounds, Inorganic 0.5 mg/m3 USA. OSHA PELs
Cr III Compounds, Inorganic 0.5 mg/m3 USA. ACGIH TLVs
18540-29-9 Cr VI Compounds 0.1 mg/m3 USA. OSHA PELs Ceiling
Cr VI Compounds, Soluble 0.005 mg/m3 USA. OSHA PELs
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(as Cr VI)
Cr VI Compounds, Soluble 0.05 mg/m3
(as Cr)
USA. ACGIH TLVs
Cr VI Compounds, Insoluble 0.005 mg/m3
(as Cr VI)
USA. OSHA PELs
Cr VI Compounds, Insoluble 0.01 mg/m3
(as Cr)
USA. ACGIH TLVs
Cobalt 7440-48-4 As Metal, Dust & Fume 0.1 mg/m3 USA. OSHA PELs
As Metal, Dust & Fume 0.02 mg/m3 USA. California OSHA PELs
As Metal, Dust & Fume 0.02 mg/m3 USA. ACGIH TLVs
Copper 7440-50-8 Dust 1 mg/m3 USA. OSHA PELs & ACGIH TLVs
Fume 0.1 mg/m3 USA. OSHA PELs
Fume 0.2 mg/m3 USA. ACGIH TLVs
Fluorides 7789-75-5 As Fluorides 2.5 mg/m3 USA. OSHA PELs & ACGIH TLVs
Iron & Iron Oxide 1309-37-1 Iron Oxide (As Fume) 10 mg/m3 USA. OSHA PELs
Iron Oxide (As Fume) 5 mg/m3 USA. California OSHA PELs
Respirable 5 mg/m3 USA. ACGIH TLVs
Graphite 7782-42-5 Total Dust 15 mg/m3 USA. OSHA PELs
Total Dust 10 mg/m3 USA. California OSHA PELs
Respirable 5 mg/m3 USA. OSHA PELs
Respirable 2 mg/m3 USA. ACGIH TLVs
Magnesite 546-93-0 Total Dust 15 mg/m3 USA. OSHA PELs
Total Dust 10 mg/m3 USA. California OSHA PELs
Total Dust 10 mg/m3 USA. ACGIH TLVs
Respirable 5 mg/m3 USA. OSHA PELs
Respirable 2 mg/m3 USA. ACGIH TLVs
Magnesium Oxide 1309-48-4 Fume 15 mg/m3 USA. OSHA PELs
Fume 10 mg/m3 USA. California OSHA PELs
Fume (Inhalable) 10 mg/m3 USA. ACGIH TLVs
Manganese & Mn
Compounds
7439-96-5 Fume 5 mg/m3 USA. OSHA PELs Ceiling
Fume 0.2 mg/m3 USA. California OSHA PELs
Fume (Respirable) 0.02 mg/m3 USA. ACGIH TLVs
Fume (Inhalable) 0.1 mg/m3 USA. ACGIH TLVs
Inorganic 5 mg/m3 USA. OSHA PELs Ceiling
Inorganic 0.2 mg/m3 USA. California OSHA PELs
Inorganic (Respirable) 0.02 mg/m3 USA. ACGIH TLVs
Inorganic (Inhalable) 0.1 mg/m3 USA. ACGIH TLVs
Molybdenum 7439-98-7 Soluble Compounds 5 mg/m3 USA. OSHA PELs
Soluble Compounds
(Respirable)
0.5 mg/m3 USA. ACGIH TLVs
Insoluble compounds
(Total Dust)
15 mg/m3 USA. OSHA PELs
Insoluble compounds
(Total Dust)
10 mg/m3 USA. California OSHA PELs
Insoluble compounds
(Respirable)
3 mg/m3 USA. ACGIH TLVs & California
OSHA PELs
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Insoluble compounds
(Inhalable)
10 mg/m3 USA. ACGIH TLVs
Nickel 7440-02-0 Metal 1 mg/m3 USA. OSHA PELs
Metal (Inhalable) 1.5 mg/m3 USA. ACGIH TLVs
Metal 0.015 mg/m3 USA. NIOSH RELs
Soluble Compounds 1 mg/m3 USA. OSHA PELs
Soluble Compounds
(Inorganic)
0.1 mg/m3 USA. ACGIH TLVs
Insoluble Compounds 1 mg/m3 USA. OSHA PELs
Insoluble Compounds
(Inorganic)
0.2 mg/m3 USA. ACGIH TLVs
Potassium Silicate 1312-76-1 Total 10 mg/m3 USA. ACGIH TLVs
Sodium Silicate 1344-09-8 Total 10 mg/m3 USA. ACGIH TLVs
Silicon 7440-21-3 Total Dust 15 mg/m3 USA. OSHA PELs
Total Dust 10 mg/m3 USA. California OSHA PELs
Respirable 5 mg/m3 USA. OSHA PELs
Silica (Quartz) 14808-60-7 Respirable 0.1 mg/m3 USA. OSHA PELs
Respirable 0.025 mg/m3 USA. ACGIH TLVs
Total Dust 0.3 mg/m3 USA. OSHA PELs
Titanium Dioxide 13463-67-7 Total Dust 15 mg/m3 USA. OSHA PELs
Total Dust 10 mg/m3 USA. ACGIH TLVs
Tungsten 7440-33-7 Insoluble 5.0 mg/m3 USA. ACGIH TLVs
Insoluble 10.0 mg/m3 USA. ACGIH TLVs Ceiling
Soluble 1.0 mg/m3 USA. ACGIH TLVs
Soluble 3.0 mg/m3 USA. ACGIH TLVs Ceiling
Vanadium 7440-62-2 Oxide Dust 0.5 mg/m3 USA. OSHA PELs Ceiling
Oxide Dust (Inhalable) 0.05 mg/m3 USA. ACGIH TLVs & California
OSHA PELs
Oxide Fume 0.1 mg/m3 USA. OSHA PELs Ceiling
Oxide Fume (Inhalable) 0.05 mg/m3 USA. ACGIH TLVs & California
OSHA PELs
Zirconium &
Zr Compounds
7440-67-7 Metal 5 mg/m3 USA. ACGIH TLVs
Metal 10 mg/m3 USA. ACGIH TLVs Ceiling
Compound 5 mg/m3 USA. OSHA PELs
Compound 5 mg/m3 USA. ACGIH TLVs
Compound 10 mg/m3 USA. ACGIH TLVs Ceiling
Exposure Limits – Canada
Common Name CAS
Number Form Exposure
Limit Source
Calcium
Carbonate
1317-65-3 Total Dust 10 mg/m3 Canada. Alberta OEL TWA
Total Dust 20 mg/m3 Canada. British Columbia OEL TWA
STEL
Total Dust 10 mg/m3 Canada. British Columbia OEL TWA
Respirable 3 mg/m3 Canada. British Columbia OEL TWA
Christensen Arms AO Modification 9/7/23
Total Dust 10 mg/m3 Canada. Saskatchewan OEL for 8hr
ACL
Total Dust 20 mg/m3 Canada. Saskatchewan OEL for 15min
ACL
Total Dust 10 mg/m3 Canada. Quebec OEL TWA
Manganese & Mn
Compounds
7439-96-5 As Mn 0.2 mg/m3 Canada. Alberta OEL TWA
As Mn 0.2 mg/m3 Canada. British Columbia OEL TWA
As Mn (Inhalable) 0.1 mg/m3 Canada. Manitoba OEL TWA
As Mn (Respirable) 0.02 mg/m3 Canada. Manitoba OEL TWA
As Mn 0.2 mg/m3 Canada. New Brunswick OEL TWA
As Mn 0.1 mg/m3 Canada. Newfoundland & Labrador OEL
TWA
As Mn 0.1 mg/m3 Canada. Nova Scotia OEL TWA
As Mn 1 mg/m3 Canada. Nunavut OEL TWA
As Mn 3 mg/m3 Canada. Nunavut OEL STEL
As Mn 5 mg/m3 Canada. Nunavut OEL Ceiling
As Mn 1 mg/m3 Canada. Northwest Territories OEL TWA
As Mn 3 mg/m3 Canada. Northwest Territories OEL STEL
As Mn 5 mg/m3 Canada. Northwest Territories OEL
Ceiling
As Mn 0.2 mg/m3 Canada. Ontario OEL TWA
As Mn 0.2 mg/m3 Canada. Prince Edward Island OEL TWA
As Mn 0.2 mg/m3 Canada. Quebec OEL TWA
As Mn 0.2 mg/m3 Canada. Saskatchewan OEL TWA
As Mn 0.6 mg/m3 Canada. Saskatchewan OEL STEL
As Mn 5 mg/m3 Canada. Yukon OEL Ceiling
Silicon 7440-21-3 Total Dust 10 mg/m3 Canada. British Columbia OEL TWA
Total Dust 3 mg/m3 Canada. New Brunswick OEL TWA
Total Dust 10 mg/m3 Canada. Nunavut OEL TWA
Total Dust 10 mg/m3 Canada. Northwest Territories OEL TWA
Total Dust 10 mg/m3 Canada. Ontario OEL TWA
Total Dust 10 mg/m3 Canada. Quebec OEL TWA
Total Dust 10 mg/m3 Canada. Saskatchewan OEL TWA
Total Dust 20 mg/m3 Canada. Saskatchewan OEL STEL
Total Dust 10 mg/m3 Canada. Yukon OEL TWA
Total Dust 20 mg/m3 Canada. Yukon OEL STEL
Silica (Quartz) 14808-60-7 Respirable Fraction 0.025 mg/m3 Canada. Alberta OEL TWA
Respirable Fraction 0.025 mg/m3 Canada. British Columbia OEL TWA
Respirable Fraction 0.025 mg/m3 Canada. Manitoba OEL TWA
Respirable Fraction 0.1 mg/m3 Canada. Ontario OEL TWA
Respirable Fraction 0.05 mg/m3 Canada. Quebec OEL TWA
Respirable Fraction 0.1 mg/m3 Canada. Saskatchewan OEL TWA
Titanium Dioxide 13463-67-7 Total Dust 10 mg/m3 Canada. Alberta OEL TWA
Dust (Respirable) 3 mg/m3 Canada. British Columbia OEL TWA
Christensen Arms AO Modification 9/7/23
Total Dust 10 mg/m3 Canada. British Columbia OEL TWA
Total Dust 10 mg/m3 Canada. Manitoba OEL TWA
Total Dust 10 mg/m3 Canada. Ontario OEL TWA
Total Dust 10 mg/m3 Canada. Quebec OEL TWA
Total Dust 10 mg/m3 Canada. Saskatchewan OEL TWA
Total Dust 20 mg/m3 Canada. Saskatchewan OEL STEL
Exposure Limits – Mexico
Common Name CAS
Number Form Exposure
Limit Source
Calcium
Carbonate
1317-65-3 Total Dust 20 mg/m3 Mexico. OEL CTT
Total Dust 10 mg/m3 Mexico. OEL CPT
Manganese & Mn
Compounds
7439-96-5 As Mn 0.2 mg/m3 Mexico. OEL CPT
As Mn Fume 1.0 mg/m3 Mexico. OEL CPT
As Mn Fume 3.0 mg/m3 Mexico. OEL CTT
Silicon 7440-21-3 Total Dust 10 mg/m3 Mexico. OEL CPT
Total Dust 20 mg/m3 Mexico. OEL CTT
Silica 69012-46-2 Fume 10 mg/m3 Mexico. OEL CPT
Fume (Respirable) 3 mg/m3 Mexico. OEL CPT
Silica (Quartz) 14808-60-7 Respirable Fraction 0.1 mg/m3 Mexico. OEL CPT
Titanium Dioxide 13463-67-7 Total Dust 20 mg/m3 Mexico. OEL CTT
Total Dust 10 mg/m3 Mexico. OEL CPT
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Solid or tubular wire
Color: Various
Odor: None
Odor threshold: Not Applicable
pH: Not Applicable
Melting point >2000F (1100C)
Initial Boiling Point & Range: Data Not Available
Flash point Data Not Available
Evaporation rate Data Not Available
Flammability Data Not Available
Upper flammability/explosive limit: Data Not Available
Lower flammability/explosive limit: Data Not Available
Vapor pressure Not Applicable
Vapor density: Not Applicable
Relative density 0.2-0.3 lbs/in3
Solubility in water Data Not Available
Solubility (other) Data Not Available
Partition coefficient Data Not Available
Auto-ignition temperature Data Not Available
Decomposition temperature: Data Not Available
Viscosity : Data Not Available
Christensen Arms AO Modification 9/7/23
10. STABILITY AND REACTIVITY
Reactivity – This product is not reactive under normal conditions as shipped.
Chemical stability – This product is chemically stable under normal conditions as shipped.
Possibility of hazardous reactions – Polymerization reactions will not occur.
Conditions to avoid – Protect product from moisture and contamination.
Incompatible materials – Data not available
Hazardous decomposition products – Welding electrodes and wires emit fumes and gases when used under normal
conditions. These fumes and gases produced during welding operations cannot be easily classified, and will differ in quantity
and form from those ingredients listed in Section 3 of this SDS. The composition and quantity of these fumes and gases are
directly dependent upon the metal being welded, any material coatings (such as primer or galvanizing), the welding process, the
welding consumables and the welding procedures. Other conditions which also influence the composition and quantity of the
fumes and gases produced include the number of welders in the work area, the volume of the work area, the quality and amount
of ventilation or exhaust, and the proximity of the welder’s head to the fume plume.
Decomposition products of welding consumables under normal operation include oxides of elements present in the welding
consumable and base material. Manganese compounds may be present in the fume from manganese bearing electrodes.
Hexavalent chromium may be present in the fume from electrodes containing chromium. Nickel compounds may be present in
the fume from nickel bearing electrodes. Fluoride containing consumables may generate gaseous and particulate fluoride.
Gases such as carbon monoxide, carbon dioxide, ozone and nitrogen oxides may also be produced in the arc area.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure:
Oral – Unknown health effects, but this exposure is unlikely to occur.
Inhalation – Inhalation of welding fumes may lead to acute and/or chronic health hazards (see table below).
Skin –Arc rays can burn the skin. Weld fume deposited on the skin may cause irritation (see table below).
Eye – Arc rays can injure the eyes. Weld fume contact with the eyes may cause irritation (see table below).
Information on toxicological effects:
The acute and chronic effects of compounds which may be exposed to the welder are listed in the table below. Also listed are
the available measured values of toxicity for that substance and whether is it classified as carcinogenic.
Substance Short-Term
Exposure Effects
Long Term
Exposure Effects Toxicity Measure Carcinogenicity
Aluminium
Oxide
May cause eye & respiratory
irritation.
May cause effects on central
nervous system.
LC50 (Rat, Oral
Exposure)
>5,000 mg/kg
Not classifiable
Barium
Compounds
May cause irritation to the
nose, throat, and respiratory
tract.
May cause baratosis (deposits of
barium in lungs). Baratosis is
benign & does not progress to
fibrosis.
LD50 (Rat, Oral
Exposure)
= 418 mg/kg
Not classifiable
Chromium as
Cr+3
May cause eye, skin &
respiratory irritation.
May cause chronic bronchitis,
sinusitus, rhinitus and ashtma.
LC50 (Rat,14 day
Oral Exposure)
>5,000 mg/kg
Not classifiable
Christensen Arms AO Modification 9/7/23
Chromium as
Cr+6
May cause eye, skin &
respiratory irritation.
May cause lung, nasal and sinus
cancer, ulceration and
perforation of the nasal septum
and skin rash.
LC50 (Rat ,Oral
Exposure)
= 29 mg/kg
IARC-1
NTP-known
OSHA
Cobalt
Compounds
May cause respiratory
irritation and cardiovascular
inflammation.
May cause chronic irritation,
diminished pulmonary function,
asthma and fibrosis.
LC50 (Rat, 30 min
Inhalation Exposure)
= 165mg/m3
Not classifiable
Substance Short-Term
Exposure Effects
Long Term
Exposure Effects Toxicity Measure Carcinogenicity
Copper Oxide May cause metal fume fever
with upper respiratory
irritation, chills, and aching
muscles.
Prolonged contact may cause
skin sensitization.
LD50 (Rat, Oral
Exposure)
= 470mg/kg
Not classifiable
Fluorides May cause eye, skin &
respiratory irritation.
May cause serious bone erosion
and mottling of teeth (fluorosis).
LD50 (Rat, Oral
Exposure)
= 31 mg/kg
Not classifiable
Iron Oxide May cause respiratory
irritation.
May cause siderosis (deposits of
iron in lungs). Siderosis is benign
and does not progress to fibrosis.
LD50 (Rat, Oral
Exposure)
> 10,000 mg/kg
Not classifiable
Lithium
Compounds
May cause eye & skin
irritation.
May adversely affect the central
nervous system & kidneys, and
may be a reproductive toxin.
LC50 (Rat, 4 hour
Inhalation Exposure)
> 2.17 mg/L
Not classifiable
Magnesium
Oxide
May cause eye & respiratory
irritation.
May cause decreased lung
function.
LD50 (Rat, Oral
Exposure)
= 3870 mg/kg
Not classifiable
Manganese
Oxide
May cause respiratory
irritation, metal fume fever
with chills, fever, upset
stomach, body ache,
vomiting.
May cause brain and central
nervous system effects resulting
in arm and leg tremors, slurred
speech and poor coordination.
LD50 (Rat, 4 hour
Inhalation Exposure)
= 19 mg mg/kg
Not classifiable
Molybdenum May cause eye & respiratory
irritation.
Not found. Not found Not classifiable
Nickel Oxide May cause respiratory
irritant, inhalation of fumes
may cause pneumonitus.
Prolonged exposure may lead to
asthma. Nickel refinery workers
showed a higher incidence of
lung and nasal cancers.
LD50 (Rat,
Inhalation Exposure)
> 5,000 mg/kg
IARC-1
NTP-known
Niobium May cause respiratory
irritation.
Not found. Not found Not classifiable
Silica May cause eye & respiratory
irritation.
Crystalline silica is a known
carcinogen. Overexposure may
also result in silicosis.
Not found IARC-1
NTP-known
Titanium
Dioxide
May cause respiratory
irritation.
May be carcinogenic. LD50 (Rat, Oral
Exposure)
> 10 g/kg
IARC-2B
Tungsten
compounds
May cause respiratory
irritation.
Not found. Not found Not found
Vanadium Oxide May cause eye, skin &
respiratory irritation.
Exposure to high concentrations
of fume may lead to chronic
nasal hyperplasia.
LD50 (Rat, Oral
Eposure)
=10 mg/kg
Not classifiable
Zirconium Oxide May cause eye & respiratory
irritation.
May cause decreased lung
function.
Not found Not classifiable
Carbon Dioxide At low levels, may cause
headache, dizziness, loss of
coordination, nausea. At
Long term exposure may affect
the body’s metabolism.
LC50 (Human,
Inhalation Exposure)
=100,000 ppm/min
Not classifiable
Christensen Arms AO Modification 9/7/23
high levels can cause coma
and possibly death.
Carbon
Monoxide
May cause effects on the
blood, resulting in
carboxyhaemoglobinemia
and cardiac disorders. High
levels may result in death.
May have effects on the
cardiovascular system and
central nervous system. May
cause toxicity to human
reproduction or development.
LC50 (Rat, 4 hour
Inhalation Exposure)
=1807 ppm
Not classifiable
Substance Short-Term
Exposure Effects
Long Term
Exposure Effects Toxicity Measure Carcinogenicity
Ozone May cause eye and
respiratory tract Irritation.
Inhalation may cause lung
oedema. May cause effects
on the central nervous
system, resulting in
headache and impaired
performance.
May cause decreased lung
function.
LC50 (Rat, 3 hour
Inhalation Exposure)
=4.5 mg/m3
Not classifiable
Nitric Oxide May cause respiratory
irritation. Inhalation may
cause lung oedema.
Exposure far above the OEL
may result in death.
May cause decreased lung
function.
LC50 (Rat, Inhalation
Exposure)
=160 mg/m3
Not classifiable
Nitrogen
Dioxide
Corrosive to the skin and
respiratory tract. Inhalation
may cause lung oedema.
Exposure far above the OEL
may result in death.
May cause effects on the
immune system and lungs,
resulting in decrease in
resistance to infection.
LC50 (Rat, 4 hour
Inhalation Exposure)
=88 ppm
Not classifiable
Other information on toxicological effects:
Germ cell mutagenicity – Not classified
Reproductive toxicity – Not classified
Specific target organ toxicity (Single exposure) – Not classified
Specific target organ toxicity (Repeated exposure) – Not classified
Aspiration hazard – Not classified
12. ECOLOGICAL INFORMATION
Toxicity: Not classified
Persistence and degradability: No information available
Bioaccumulative potential: No information available
Mobility in soil: No information available
Other adverse effects: Unknown
13. DISPOSAL CONSIDERATIONS
Discard any product, residue, waste or packaging in an environmentally acceptable manner in compliance with federal, State,
or local laws. Do not dispose of any waste, remaining product or by-product in the sewer.
14. TRANSPORT INFORMATION
UN Number: Not regulated
UN Proper Shipping Name: Not regulated
Christensen Arms AO Modification 9/7/23
Transport Hazard Class: Not regulated
Packing Group: Not regulated
IMDG: Not regulated
ICAO/IATA: Not regulated
15. REGULATORY INFORMATION
U.S. Federal Regulations:
Emergency Planning & Community Right-To-Know Act (EPCRA) of 1986
Section 313 Hazardous Chemicals:
Aluminum, Aluminum Oxide, Barium and Barium Compounds, Chromium, Copper, Lithium Carbonate,
Manganese, Nickel, Silicon & Silica, Iron & Iron Oxide, Magnesium, Zirconium and Vanadium.
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Hazard categories – Acute (Immediate) and Chronic (Delayed)
Toxic Substances Control Act (TSCA) Inventory:
Iron – Listed
Silicon – Listed
U.S. State Laws:
California Proposition 65:
Titanium Dioxide – Carcinogenic
Silica (Quartz) - Carcinogenic
Warning: These products contain chemicals known to the State of California to cause cancer, birth defects, or other
reproductive harm.
New Jersey Community Worker and Right-to-Know Act
Titanium Dioxide – Listed
Manganese – Listed
Massachusetts Right-to-Know Act Substance List
Titanium Dioxide – Listed
Manganese – Listed
Silica (Quartz) – Listed
Pennsylvania Right-to-Know Act Hazardous Substances List
Titanium Dioxide – Listed
Manganese – Listed
Rhode Island Right-to-Know Act Substance List
Manganese – Listed
Minnesota Right-to-Know Act Hazardous Substances List
Titanium Dioxide – Listed
Manganese – Listed
Silica (Quartz) – Listed
Canadian Regulations:
This product is classified according to the requirements of the Canadian Controlled Products Regulations Section 33, and this
SDS contains all required information.
Christensen Arms AO Modification 9/7/23
16. OTHER INFORMATION
DISCLAIMER: Users should take all standard and reasonable precautions when using this product for its intended use. The
manufacturer does not recommend this product for any uses other than that described. The manufacturer makes no claims
and provides no warranty for non-standard use.
NFPA 704: HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 0
HMIS: HEALTH: 2 FLAMMABILITY: 0 PHYSICAL HAZARD: 0
SDS Revisions
Preparation date: 4/12/2017 Revision date: Revision
number:
Note: Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as
of the date hereof, the manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that
persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will the manufacturer be
responsible for damages of any nature whatsoever resulting from the use of, misuse or reliance upon information. No representations or warranties, either
express or implied, or merchantability, fitness for a particular purpose or any other nature are made hereunder with respect to information or the product to
which information refers. Regulatory requirements are subject to change and may differ from one location to another. It is the buyer's responsibility to
ensure its activities comply with federal, State, Provincial, and local laws and regulations.
Christensen Arms AO Modification 9/7/23
Christine Bodell <cbodell@utah.gov>
Utah Division of Air Quality - Christensen Arms NOI
21 messages
Christine Bodell <cbodell@utah.gov>Tue, Nov 19, 2024 at 8:04 AM
To: thomask@christensenarms.com, macy.parchment@tetratech.com, jena.shaw@tetratech.com
Good Morning,
I am reviewing the NOI submitted for the Christensen Arms Gunnison Gun Manufacturing Plant in Sanpete County. The NOI states that
Christensen is requesting the addition of two (2) spray booths, ten (10) blasters and two (2) dust collectors.
However, per a recent Compliance Advisory (DAQC-810-24, attached), "Christensen Arms failed to submit a Notice of Intent (NOI) prior to
the installation and operation of two (2) additional paint spray booths, six (6) additional abrasive blasting booths, and three (3) additional
baghouses.
It appears that the inspector observed one more baghouse than what is requested on the NOI. Please advise at your earliest convenience.
Best,
Christine
--
Christine Bodell
Environmental Engineer
Email | cbodell@utah.gov
Phone| (385) 290-2690
Emails to and from this email address may be considered public records and
thus subject to Utah GRAMA requirements
C-810-24.pdf
397K
Grace, Jena <jena.shaw@tetratech.com>Fri, Nov 22, 2024 at 8:58 AM
To: Christine Bodell <cbodell@utah.gov>, "thomask@christensenarms.com" <thomask@christensenarms.com>
Cc: "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
I am the consultant assisting Christensen Arms with obtaining this NOI. I believe there was just a misunderstanding on the number of
dust collectors that are currently permitted. The NOI indicated that there were two unpermitted baghouses, however, in speaking with
the facility, it sounds like you are correct and there are three. What needs to be done to include this additional unit in the application that
was submitted?
Appreciate your attention to this and the assistance!
Jena
You don't often get email from cbodell@utah.gov. Learn why this is important
Jena L Grace, P.E. | Manager, Air
Pronouns: she/her/hers
Direct +1 (617) 880-1436 | jena.grace@tetratech.com
Time Zone: Eastern (UTC -05.00)
This message, including any attachments, may include privileged, confidential and/or inside information. Any distribution or use of this communication
by anyone other than the intended recipient is strictly prohibited and may be unlawful. If you are not the intended recipient, please notify the sender by
replying to this message and then delete it from your system.
From: Christine Bodell <cbodell@utah.gov>
Sent: Tuesday, November 19, 2024 10:05 AM
To: thomask@christensenarms.com; Parchment, Macy <macy.parchment@tetratech.com>; Grace, Jena <jena.shaw@tetratech.com>
Subject: Utah Division of Air Quality - Christensen Arms NOI
⚠ CAUTION: This email originated from an external sender. Verify the source before opening links or attachments. ⚠
[Quoted text hidden]
Christine Bodell <cbodell@utah.gov>Fri, Nov 22, 2024 at 11:24 AM
To: "Grace, Jena" <jena.shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Please send an NOI amendment reflecting this change. Please ensure all emission estimates calculations are updated as necessary.
Thank you,
Christine
[Quoted text hidden]
Grace, Jena <jena.shaw@tetratech.com>Mon, Dec 2, 2024 at 1:22 PM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
Hope you had a nice thanksgiving!
Just wanted to confirm with the NOI amendment since the emission estimation calculations will not be changing (they already include
the control devices) are we ok to include only the following NOI forms: 1 , 2, 4 and 6?
Thanks,
[Quoted text hidden]
Christine Bodell <cbodell@utah.gov>Mon, Dec 2, 2024 at 2:57 PM
To: "Grace, Jena" <jena.shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Thank you. I hope you had a great Thanksgiving holiday weekend as well.
If no emissions are changing, please just send the updated forms.
Thank you,
Christine
[Quoted text hidden]
Grace, Jena <jena.shaw@tetratech.com>Tue, Dec 3, 2024 at 7:43 AM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine
Thank you for the quick response! This is very helpful. We will work on getting those forms together.
Thank you,
Jena
Jena L Grace, P.E. | Manager, Air
Pronouns: she/her/hers
Direct +1 (617) 880-1436 | jena.grace@tetratech.com
Time Zone: Eastern (UTC -05.00)
This message, including any attachments, may include privileged, confidential and/or inside information. Any distribution or use of this communication
by anyone other than the intended recipient is strictly prohibited and may be unlawful. If you are not the intended recipient, please notify the sender by
replying to this message and then delete it from your system.
From: Christine Bodell <cbodell@utah.gov>
Sent: Monday, December 2, 2024 4:58 PM
To: Grace, Jena <jena.shaw@tetratech.com>
Cc: thomask@christensenarms.com; Parchment, Macy <MACY.PARCHMENT@tetratech.com>
Subject: Re: Utah Division of Air Quality - Christensen Arms NOI
⚠ CAUTION: This email originated from an external sender. Verify the source before opening links or attachments. ⚠
[Quoted text hidden]
Grace, Jena <jena.shaw@tetratech.com>Wed, Dec 4, 2024 at 8:49 AM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
We have been working through this with the facility, however, I believe there is some confusion as to what the agency indicated was
unpermitted on-site during their inspection and what the facility actually operates. In their AO (DAQE-AN160570001-22) there are two
dust collectors permitted (highlighted on page 6, 7 and 8, attached). The permit indicates that the baghouse controls the abrasive and
sanding operations while the permitted cyclone controls the contouring and machining areas. I have confirmed with the site, and they
indicated they have only a total of four dust collectors on-site and operating, meaning that two are unpermitted at the time. They operate
only one baghouse and the remaining three are cyclones with cartridge filters. The document that you provided from the inspection in
August 2024 indicates there are three unpermitted baghouses. But according to the site, the two unpermitted units are cyclones. Tryingto figure out the best way to go about this. What do you need from the site to show they have only a total of four dust collectors (1
baghouse, four cyclones)?
It may be easier to talk this through on the phone – please feel free to give me a call with questions. We appreciate you working with us
on this.
Thank you,
Jena
Jena L Grace, P.E. | Manager, Air
Pronouns: she/her/hers
Direct +1 (617) 880-1436 | jena.grace@tetratech.com
Time Zone: Eastern (UTC -05.00)
This message, including any attachments, may include privileged, confidential and/or inside information. Any distribution or use of this communication
by anyone other than the intended recipient is strictly prohibited and may be unlawful. If you are not the intended recipient, please notify the sender by
replying to this message and then delete it from your system.
From: Christine Bodell <cbodell@utah.gov>
Sent: Monday, December 2, 2024 4:58 PM
To: Grace, Jena <jena.shaw@tetratech.com>
Cc: thomask@christensenarms.com; Parchment, Macy <MACY.PARCHMENT@tetratech.com>
Subject: Re: Utah Division of Air Quality - Christensen Arms NOI
⚠ CAUTION: This email originated from an external sender. Verify the source before opening links or attachments. ⚠
[Quoted text hidden]
Christensen Arms AO-markup.pdf
577K
Christine Bodell <cbodell@utah.gov>Wed, Dec 4, 2024 at 11:06 AM
To: "Grace, Jena" <jena.shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Okay, thank you for the explanation. So Christensen is requesting the addition of two (2) cyclones to control the four (4) spray booths, and
the existing two (2) dust collection systems (sanding/abrasive blasting baghouse and contouring/machining area cyclone) will remain
unchanged?
Thank you,
Christine
[Quoted text hidden]
Grace, Jena <jena.shaw@tetratech.com>Wed, Dec 4, 2024 at 1:26 PM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
The two additional cyclones that Christensen is requesting approval for will be for the sanding/abrasive blasting. The currently permitted
baghouse and currently permitted cyclone remain unchanged. Christensen is only requesting two new additional paint booths which have
particulate filters attached to the booths. There is currently one permitted paint booth already. So, a total of three paint booths. The
emissions from the paint booths do not route to the dust collection units. Hope that clears this up.
[Quoted text hidden]
Christine Bodell <cbodell@utah.gov>Thu, Dec 5, 2024 at 10:43 AM
To: "Grace, Jena" <jena.shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Thank you for clarifying that.
The only outstanding concern I have at this time is that a 99.99% efficiency was assumed for emission estimates for abrasive blasting.
Cyclone's do not typically achieve this high of a collection efficiency for particulates. However, the NOI states that the manufacturer has
provided documentation suggesting this level of control. Can you please show me where this number was obtained?
And lastly, are the cyclones used in series with the existing baghouse? Or are some blasting units controlled by the cyclones while others
by the baghouse?
Thank you,
Christine
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Grace, Jena <jena.shaw@tetratech.com>Thu, Dec 5, 2024 at 2:12 PM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
Thanks for the quick response! Appreciate your patience as we work through this..the site provided me the following as the filters they
order: https://www.airmaxind.com/products/airmax-amx502-premium-cartridge-filter?variant=42794176479469
Reviewing this, it appears the material is an 80/20 blend which I believe has an efficiency of closer to 85%. Sorry for the error. Is that
more in line with what you would expect in a cyclone? Please let us know what you need from us to correct this.
The cyclones are not used in series – some of the blasting units are controlled by the cyclones and others by baghouse as you mention
below.
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Christine Bodell <cbodell@utah.gov>Thu, Dec 5, 2024 at 2:23 PM
To: "Grace, Jena" <jena.shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Thank you for checking this. Yes, 85% control sounds more reasonable. My concern is that the calculations were submitted assuming a
99.99% control efficiency for the entire blasting process. Please re-submit the calculations with the updated control efficiency, as
particulates can now be expected to increase.
Thank you,
Christine
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Grace, Jena <jena.shaw@tetratech.com>Thu, Dec 5, 2024 at 2:42 PM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
Please see the updated emissions summary form, updated blasting calcs, and updated machining calcs using an 85% CE. Please let usknow if you need anything else.
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3 attachments
Christensen Arms Permit Mod Updated Calc-updated 20241205 - Emission Summary.pdf
72K
Christensen Arms Permit Mod Updated Calc-updated 20241205-blasting.pdf
71K
Christensen Arms Permit Mod Updated Calc-updated 20241205-machining.pdf
70K
Grace, Jena <Jena.Shaw@tetratech.com>Fri, Dec 6, 2024 at 7:42 AM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
As a follow up to our conversations yesterday, the facility forwarded me the attached document from the manufacturer of the cartridge
filter. The document states that capture efficiency will be 99.99% on 0.5 micron particles. We would like the agency to consider this
documentation to verify the original calcs that used the 99.99% CE. Can you please let us know how the state will proceed?
Thanks for all the help on this matter.
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Christensen Arms M2F Megabond Emissions Statement.pdf
280K
Grace, Jena <Jena.Shaw@tetratech.com>Tue, Dec 10, 2024 at 7:50 AM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hi Christine,
Checking in to see if there is anything further you may need from us.
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Christine Bodell <cbodell@utah.gov>Tue, Dec 10, 2024 at 8:01 AM
To: "Grace, Jena" <Jena.Shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Thank you for reaching out.
I would like to ensure that the following is correct:
The paint booth will be equipped with both HVLP spray guns and paint arrestor fabric filters to reduce the overspray of paint. The paint
arrestor fabric filters will each have a minimum 84% particulate control efficiency. The new cyclones will control emissions from sand and
media blasting operations and have a minimum particulate control efficiency of 99.9%.
Please be advised that both of the above assumptions will be enforceable conditions on the updated Approval Order.
Thanks,
Christine
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Grace, Jena <Jena.Shaw@tetratech.com>Tue, Dec 17, 2024 at 7:31 AM
To: Christine Bodell <cbodell@utah.gov>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Good morning Christine,
I just confirmed with the site, and they accept the conditions below for the paint arrestor fabric filters and the control efficiency on the
new cyclones. Please let us know if you have any other questions.
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Christine Bodell <cbodell@utah.gov>Tue, Dec 17, 2024 at 10:25 AM
To: "Grace, Jena" <Jena.Shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Jena,
Thank you for confirming!
I hope to be able to send you the draft Approval Order to review within the next 1-2 weeks.
Thank you,
Christine
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Christine Bodell <cbodell@utah.gov>Wed, Dec 18, 2024 at 2:51 PM
To: "Grace, Jena" <Jena.Shaw@tetratech.com>
Cc: "thomask@christensenarms.com" <thomask@christensenarms.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hey Jena,
I am still a little confused about the cyclone. Appendix F of the NOI has the manufacturer specs for the cyclone C-series dust collector.
What model number is being used and how does the cartridge with 99.99% control efficiency factor into the cyclone? Is the air first routed
through the cyclone and then the filter? Is the filter built into the cyclone?
Additionally, with a 99.99% capture efficiency for 0.5-micron particles, the filter will likely have to be replaced often. What is the
maintenance schedule or metric that Christensen Arms uses to determine when it needs to be replaced to ensure maximum control
efficiency?
Thanks,
Christine
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Thomas Kubota <ThomasK@christensenarms.com>Wed, Dec 18, 2024 at 3:32 PM
To: Christine Bodell <cbodell@utah.gov>, "Grace, Jena" <Jena.Shaw@tetratech.com>
Cc: "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
On 3 of our 4 dust collection units the air travels through the filters that are built into the cyclone then exhausts
back into the building. There is no exhaust that vents outside of the building. Each of our dust collectors have
differential pressure gauges installed and they are calibrated yearly. We document the pressure readings each
day for all 4 dust collectors. Even with our gauges reading between the allowed 1-6 inH20 (We have not had a
reading lower than 1.7 or higher than 3.2) we still replace these filters on a yearly basis. That being said there is
no risk of the 3 dust collection systems exhausting any particulates outside of our facility.
Thank you,
--
Tom Kubota
Maintenance Manager
O 435.633.4667 / M 435.469.2459
ChristensenArms.com
550 N Cemetery Road
Gunnison, UT 84634
From: Chris ne Bodell <cbodell@utah.gov>
Sent: Wednesday, December 18, 2024 2:51:40 PM
To: Grace, Jena
Cc: Thomas Kubota; Parchment, Macy
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EXPORT WARNING: These Commodities, Technical Data or Software are subject to the export control of either the International Traffic in
Arms Regulations (ITAR) or the Export Administration Regulations (EAR) and cannot be exported without the authorization of either the
Department of State or the Department of Commerce prior to export. Export includes disclosure and or access to Commodities, Technical
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Christine Bodell <cbodell@utah.gov>Thu, Dec 19, 2024 at 8:13 AM
To: Thomas Kubota <ThomasK@christensenarms.com>
Cc: "Grace, Jena" <Jena.Shaw@tetratech.com>, "Parchment, Macy" <MACY.PARCHMENT@tetratech.com>
Hello Thomas,
Thank you for the explanation.
Best,
Christine
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