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DAQ-2025-000685
Small Source Registration DAQE-EN159540002-25 {{$d1 }} Ashley Zapp EDSCO Fasteners, LLC 6565 North MacArthur Blvd, Suite 800 Irving, TX 75039 Ashley.Zapp@cmc.com Dear Ms. Zapp: Re: Request for Evaluation of Compliance with Rule R307-401-9, UAC: Small Source Exemption Project Fee Code: N159540002 On January 3, 2025, the Division of Air Quality (DAQ) received your request for a small source exemption for EDSCO Fasteners, LLC’s Fastener Manufacturing Plant. The source is located at 3562 North 600 West, Units 8-13 in Spanish Fork, Utah County. The DAQ has determined the small source exemption applies to the source, as long as the equipment and associated processes operate as specified in the registration request. Specifically, the source shall cut no more than 8,320 tons of low carbon steel annually in the plasma cutter and shall use no more than 1,000 pounds of abrasive blasting media per hour. The small source exemption does not exempt a source from complying with other applicable federal, state, and local regulations and the current Utah Administrative Code. Based on the emissions that you submitted to the DAQ with your registration request, EDSCO Fasteners, LLC’s Fastener Manufacturing Plant is not required to obtain an approval order under R307-401. If you change your operation such that there is an increase in emissions, we recommend that you notify us, as an approval order may be required. As authorized by the Utah Legislature, the fee for issuing this small source exemption is a one-time filing fee in addition to the actual time spent by the review engineer and all other staff on the project. Payment should be sent to the DAQ upon receipt of the invoice. 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director + 2 / 6 Ü Ù Û Ù Û Þ DAQE-EN159540002-25 Page 2 Thank you for registering your source with the DAQ. If you have any additional questions, please contact Lucia Mason at (385) 707-7669 or lbmason@utah.gov. Sincerely, Bryce C. Bird Director {{$s }} Alan D. Humpherys, Manager New Source Review Section BCB:ADH:LM:jg {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#s=Sig_es_:signer1:signature}} Copyright ©2024 , Yorke Engineering, LLC Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr)Total (ton/yr)Limit (ton/yr) CO 1048.32 ---1048.32 0.52 5.00 NOx 1248.00 ---1248.00 0.62 5.00 ROG 68.64 ---68.64 0.034 5.00 SOx 7.49 ---7.49 0.0037 5.00 PM10 94.85 0.07 2870.40 4160.00 7125.32 3.56 5.00 Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr)HAP?Limit (lb/yr) Benzene 0.100 ---0.100 Yes 500 Formaldehyde 0.212 ---0.212 Yes 500 Ammonia 224.64 ---224.64 No 500 Tin -0.001 --0.001 No 500 Copper -0.003 -41.60 41.603 Yes 500 Aluminum -0.003 --0.003 No 500 Lead -0.004 --0.004 Yes 500 Cadmium -0.004 --0.004 Yes 500 Arsenic ----0.000 Yes 500 Beryllium ----0.000 Yes 500 Manganese --34.445 104.00 138.44 Yes 500 Nickel --5.741 41.60 47.34 Yes 500 Phosphorous --1.435 -1.44 Yes 500 Silicon --43.056 -43.06 No 500 Sulfur --1.435 -1.44 No 500 Chromium (total)---41.60 41.60 Yes 500 Molybdenum ---41.60 41.60 Yes 500 312.34 -2000 269.14 -2000Total Other Summary of Hazardous Air Pollutants and Other Air Contaminents Emissions Emissions Summary of Criteria Pollutants Criteria Pollutant Pollutant Total HAPs Copyright ©2024, Yorke Engineering, LLC Confirmed: boilers are size -5-B with a maximum input rating of 0.75 MMBtu/hr. See attachemtns to 5-22-2024 evaluation. Limit (lb/yr)(ton/yr)(ton/yr) CO 1.05E+03 5.24E-01 5NOx1.25E+03 6.24E-01 5 ROG 6.86E+01 3.43E-02 5SOx7.49E+00 3.74E-03 5 PM10 9.48E+01 4.74E-02 5 Operation Schedule Hours/Day Days/Week Weeks/Year Equipment Maximum 24 7 52Facility Maximum 24 7 52 Emissions Calculation Data Description Value Units Burner Rating 1.50 mmBtu/hrHeating Value of Fuel* 1,050 mmBtu/mmscf Annual Fuel Usage 12.48 mmscf CO EF 84.00 lbs/mmscf NOx EF 100.00 lbs/mmscf ROG EF 5.50 lbs/mmscfSOx Emission 0.60 lbs/mmscf PM10 Emission 7.60 lbs/mmscf *EIA for Utah list 1042-1045 for 2020's, 1040 for 2018 EF Limit (lb/mmscf)(lb/yr)Hap?(lb/yr) Benzene 0.0080 9.98E-02 Yes 500 Formaldehyde 0.017 2.12E-01 Yes 500 Ammonia 18.00 2.25E+02 No 500 3.12E-01 -2000 2.25E+02 -2000 AP-42 Toxic Air Contaminent (TAC) Emission Factors for Natural Gas (lbs/mmscf) External Combustion Equipment Burner Combustion Emission Calculations – Criteria Pollutants Total HAPs Total Other Burner Combustion Emission Calculations – Hazardous Air Pollutants and Other Air Contaminents Emissions Pollutant AP42 SCAQMD Default Combustion Emission Factors (Revised January 2022)External Combustion Equipment EF Table - NG/Other Equipment AP42 Criteria Pollutant Standard Conversion Factor Reference Burner Specifications, 2x 0.75 Emissions Copyright ©2024, Yorke Engineering, LLC Limit (lb/yr)(ton/yr)(ton/yr) PM10 1.44E+02 7.21E-02 5 Emissions Calculation Data Description Value Units US ZINC SDS 43,713 lb/yr <-- This is "on average." I decided not to ask for use r 21.86 ton/yr PM EF*6.6 lb/ton 144.25 lb/yr 0.072 ton/yr 1. 8% Zinc by weight *6.6 lb/ton is the EF for Zinc throughput * TACs = % from sds of total pm * 43,713 lbs/year is the maximum annual zinc usage from purchase data Content Limit (Percent)(lb/yr)(ton/yr)HAP?(lb/yr) Lead 0.003%4.33E-03 2.16E-06 Yes 500 Cadmium 0.003%4.33E-03 2.16E-06 Yes 500 Tin 0.001%1.44E-03 7.21E-07 No 500 Copper 0.002%2.89E-03 1.44E-06 Yes 500 Aluminum 0.002%2.89E-03 1.44E-06 No 500 1.44E-02 7.21E-06 -2000 4.33E-03 2.16E-06 -2000 Criteria Pollutant Emissions Galvanizing Kettle Emission Calculations – Criteria Pollutants Total HAPs Total Other Pollutant Maximum Zinc Throughput Total PM Galvanizing Kettle Emission Calculations – Hazardous Air Pollutants and Other Air Contaminents Emissions Copyright ©2024 , Yorke Engineering, LLC Limit (lb/yr)(ton/yr)(ton/yr) Cabinet 1 1435.20 7.18E-01 5 Cabinet 2 1435.20 7.18E-01 5 Description Value Units Reference Amount of Abrassive Used 1000.00 lbs/hr 2018 application <-- Used in SSE PM EF1 0.69 lb/1000lbs of abrasive AP-42 13.2.6-1 Time Period Equipment Maximum Facility Maximum Hours/Day 8 24 Days/Week 5 7 Weeks/Year 52 52 Result Limit (wt. %)(lb/yr)HAP? (lb/yr) Manganese 1.20000%3.44E+01 Yes 500 Silicon 1.50000%4.31E+01 No 500 Sulfur 0.05000%1.44E+00 No 500 Nickel 0.20000%5.74E+00 Yes 500 Phosphorous 0.0500%1.44E+00 Yes 500 8.61E+01 -2000 0.00E+00 -2000 EmissionsSource Blasting Cabinet Emission Calculations – Criteria Pollutants Operating Schedule Emissions Parameters Blasting Cabinet Emission Calculations – HAP and Other Air Contaminent Emissions Emissions Total Other Total HAPs Pollutant Copyright ©2024, Yorke Engineering, LLC Limit(lb/yr)(ton/yr)(ton/yr) PM10 4.16E+03 2.08E+00 5 Limit(lb/yr)HAP?(lb/yr) Manganese 1.04E+02 Yes 500Nickel4.16E+01 Yes 500 Copper 4.16E+01 Yes 500 Chromium 4.16E+01 Yes 500Molybdenum4.16E+01 Yes 500 Total HAPs 2.70E+02 -2000Total Other 0.00E+00 -2000 Metals are calculated assuming that the fume (PM10) emissions have the same composition as the table above, i.e., PM10 emissions multiplied by the applicable weight percentage. Emissions Calculation Data Description Value Units Material Cut (ton/year)8,320 tons/yr Percent of Material Removed by Cutting 5%Percent Fume (PM10) EF - Dry (lb/lb cut) 5%% Fume (PM10) EF - Semi-Wet (lb/lb cut) 0.5%% Fume (PM10) EF - Wet (lb/lb cut) 0.05%% Filter Efficiency (%)0% Low Carbon (mild steel) Steel ProductsManganese2.5% Nickel 1.0%Copper 1.0%Chromium 1.0% Molybdenum 1.0% Source Applicant AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) Engineering Estimation Summary of Constituents in Metals Cut AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) No Filtration AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) Pollutant Emissions Plasma Cutting - Semi-Wet - Mild Steel Emission Calculations – HAP and Other Air Contaminents Plasma Cutting - Semi-Wet - Mild Steel Emission Calculations – Criteria Pollutants Criteria Pollotant Emissions LOS ANGELES/ORANGE COUNTY/RIVERSIDE/VENTURA/SAN DIEGO/FRESNO/BERKELEY/BAKERSFIELD 31726 Rancho Viejo Road, Suite 218 ▼ San Juan Capistrano, CA 92675 ▼ Tel: (949) 248-8490 ▼ Fax: (949) 248-8499 May 22, 2024 Ms. Ashley Zapp Area Environmental Manager, West Division Commercial Metals Company Office: (909) 637-9299 Cell: (909) 977-1555 E-mail: Ashley.Zapp@CMC.com Subject: Evaluation of Small Source Exemption for a Zinc Galvanizing Process at EDSCO Fasteners, LLC Dear Ms. Zapp: Yorke Engineering, LLC (Yorke) is pleased to provide Commercial Metals Company (CMC) with this small source exemption evaluation for the anchor bolt and fastener manufacturing process at EDSCO Fasteners, LLC (EDSCO). BACKGROUND In July 2018, EDSCO submitted a Small Source Exemption Registration to Utah’s Department of Environmental Quality Division of Air Quality (DAQ) to confirm exemption from requiring an air permit for their anchor bolt and fastener manufacturing process in Spanish Fork, Utah. Since 2018, CMC has acquired EDSCO and requested that Yorke perform an evaluation of the previously submitted exemption registration. This study includes a review of the previous evaluation, including a description of the equipment and a summary of the relevant Utah rules and regulations with respect to equipment permitting. Equipment Description EDSCO is a manufacturer and distributor of anchor bolts and fasteners for large steel structures. Raw materials are received by the facility, where they are processed with hand-held machines to create anchor bolts and fasteners. The bolts and fasteners are then processed through abrasive blasting cabinets and dipped into a galvanizing kettle for a zinc coating. Zinc alloy ingots of at least 99.995% zinc are melted in the galvanizing kettle heated by two 0.75 million British thermal units (MMBtu) per hour burners fueled by natural gas. The kettle’s capacity is 3,600 pounds and processes an average of 43,713 pounds per year of zinc. Plasma arc cutting stations are located at the site to cut raw materials as well as other material for maintenance-related purposes. SMALL SOURCE EXEMPTION REGISTRATION SUMMARY This section includes a listing of the DAQ’s Small Source Exemption Registration requirements that are potentially applicable to the metal processing, abrasive blasting, and zinc galvanizing equipment. Rule 307-401-9 – Small Source Exemption Rule 307-401 identifies operations that emit small quantities of air contaminants that may be exempted from requiring an approval order. Ms. Ashley Zapp May 22, 2024 Page 2 of 5 Rule 307-401-9 provides the requirements for a small source exemption from the application and permitting for new installations and modifications to existing installations throughout the State of Utah. Small stationary sources are exempt from the requirement to obtain an approval order through the requirements of Rule 307-401-5 through 8, including Notice of Intent, Review Period, and Public Notice, if the following conditions are met: Rule 307-401-9(1)(a): The small stationary source’s emissions are less than 5 tons per year per criteria air pollutant [sulfur dioxide (SO2), carbon monoxide (CO), nitrogen oxides (NOx), particulate matter less than 10 microns in size (PM10), ozone (O3), or volatile organic compounds (VOCs)]; Rule 307-401-9(1)(b): The small stationary source’s emissions are less than 500 pounds per year of any hazardous air pollutant (HAP) and less than 2,000 pounds per year of any combination of HAPs; and Rule 307-401-9(1)(c): The small stationary source’s emissions are less than 500 pounds per year of any air pollutant not listed in Rule 307-401-9(1)(a) or Rule 307-401-9(1)(b) above and less than 2,000 pounds per year of any combination of air pollutants not listed above. The following section presents the emission calculations from EDSCO used to determine compliance with Rules 307-401-9(1)(a-c). EMISSION CALCULATIONS Rule 307-401-9(1)(a) limits the quantity of criteria pollutant emissions emitted from any small stationary source, and Rule 307-401-9(1)(b) limits the quantity of HAP emissions emitted from any small stationary source. Rule 307-401-9(1)(c) limits the quantity of air pollutants not included in Rule 307-401-9(1)(a) or Rule 307-401-9(1)(b). Emissions of criteria pollutants must be less than 5 tons per year. HAPs and non-HAP toxic air contaminants are limited to 500 pounds per year per pollutant and less than 2,000 pounds per year of combined pollutants (HAPs and non- HAPs, compared separately). Criteria pollutants, HAPs, and non-HAP toxics are emitted from EDSCO as a byproduct of the metal cutting, abrasive blasting, natural gas combustion, and the hot dip galvanizing process. Methods for calculating emissions from EDSCO are reviewed below. Metal Cutting EDSCO receives various raw materials, which are processed through six cutting stations prior to processing. In 2018, emissions from metal cutting were calculated using AP-42 Section 12.5.1 emission factors for billet cutting torches. Upon review, the facility confirmed that plasma arc cutters are used to cut all material at the facility. Emissions are calculated for the plasma cutters as described below. PM10 is emitted from the plasma cutting operations. Emissions were calculated using emission factors from the 1994 Swedish Institute of Production Engineering Research1. Since the cutting occurs over a water table, the semidry emission factor was used which assumes 99.5% of the material cut remains in the table, and the remaining 0.5% is emitted as fumes. An estimated 5% of the total material is removed during cutting. The emission 1 “Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel”, Bromeen B. et al, The Swedish Institute of Production Engineering Research (1994) Ms. Ashley Zapp May 22, 2024 Page 3 of 5 calculations assume that all raw materials are processed in the plasma cutters and are assumed to not contain any stainless steel. Metal HAPs emissions were calculated assuming a general metals speciation profile for mild steel. Emission calculations for the plasma cutters are shown in Attachment 4. Abrasive Blasting The abrasive blasting process occurs in two small, enclosed blast cabinets, after raw materials are cut and processed into anchor bolts and fasteners, in preparation for the hot dip galvanizing process. In 2018, PM10 emissions from abrasive blasting were calculated using AP-42 Section 13.2.6 emission factors for abrasive blasting operations. More detailed emissions can be calculated with more specific information on each abrasive blasting station, including the blasting nozzle diameter, outlet pressure, blower rating, and dust collection control efficiency. However, the AP-42 emission factors are widely accepted and are representative of the operations. In this review, PM10 emissions were calculated the same as in 2018. Metal HAPs emissions were calculated using the metals speciation of AMASTEEL, the blast media used by the abrasive machines. Emission calculations for the abrasive blasting stations are shown in Attachment 4. Galvanizing Kettle – Burners Bolts and fastener products are dipped into the hot galvanizing kettle for a zinc coating. The galvanizing kettle is equipped with two burners for melting the zinc ingots. In 2018, criteria pollutant emissions including NOx, SOx, CO, PM10, and VOCs from galvanizing kettle combustion were calculated using AP-42 emission factors for natural gas combustion. Additionally, the burners reviewed in 2018 were two burners rated at 0.5 MMBtu/hr. While the emission factors are representative of the galvanizing kettle burners, each of the burners currently at the facility is rated at a maximum heat input capacity of 0.75 MMBtu per hour. Criteria pollutant emissions in this analysis are calculated using the new burner ratings. Speciated HAPs and non-HAP toxics were calculated based on the speciation profile for natural gas combustion in AP-42 Section 1.4, Table 1.4-3. Emission calculations for the combustion in the galvanizing kettles are shown in Attachment 4. Galvanizing Kettle – Hot Dip Galvanizing The galvanizing kettle process of dipping bolts and fasteners into the galvanizing kettle of melted zinc ingots produces PM10 emissions. In 2018, PM10 emissions were calculated using an emission factor from the EPA’s Emissions from Hot-Dip Galvanizing Process2 based on pounds of PM10 per ton of galvanized product. Although the emission factor used is representative of the process, the facility confirmed that the maximum annual production of galvanized product is not tracked. Since the annual purchase of zinc is tracked by the facility, this analysis uses an emission factor from the same source document in terms of pounds of PM10 per ton of zinc used. Metal HAPs emissions were calculated assuming the speciation profile for Zinc Special High Grade. Emission calculations for the galvanizing process are shown in Attachment 4. Criteria pollutant emissions from the facility are expected to be below the Rule 307-401-9(1)(a) limits of 5 tons per year per criteria air pollutant for CO, NOx, ROG, SOx, and PM10. All HAP 2 “Emissions from Hot-Dip Galvanizing Processes”, Peter J. Drivas, U.S. Environmental Protection Agency (1976) Ms. Ashley Zapp May 22, 2024 Page 4 of 5 emissions from the facility are expected to be below the Rule 307-401-9(1)(b) limits of 500 pounds per year per HAP and 2,000 lbs. per year of combined HAPs. Table 1 below provides a summary of criteria pollutant emissions from the facility, and Table 2 provides a summary of the HAP emissions from the facility. Table 1: Summary of Criteria Pollutants Summary of Criteria Pollutants Criteria Pollutant Emissions Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr) Total (ton/yr) Limit (ton/yr) CO 1048.32 - - - 1048.32 0.52 5.00 NOx 1248.00 - - - 1248.00 0.62 5.00 ROG 68.64 - - - 68.64 0.034 5.00 SOx 7.49 - - - 7.49 0.0037 5.00 PM10 94.85 144.25 2870.40 4160.00 7269.50 3.63 5.00 Table 2: Summary of HAPs and non-HAP Toxics Summary of Hazardous Air Pollutants and Other Air Contaminants Pollutant Emissions Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr) HAP? Limit (lb/yr) Benzene 0.100 - - - 0.100 Yes 500 Formaldehyde 0.212 - - - 0.212 Yes 500 Ammonia 224.64 - - - 224.64 No 500 Tin - 0.001 - - 0.001 No 500 Copper - 0.001 - - 0.001 Yes 500 Aluminum - 0.001 - - 0.001 No 500 Lead - 0.004 0.020 - 0.024 Yes 500 Cadmium - 0.004 0.020 - 0.024 Yes 500 Arsenic - - 0.014 - 0.014 Yes 500 Beryllium - - 0.004 - 0.004 Yes 500 Selenium - - 0.063 - 0.063 Yes 500 Mercury - - 0.0001 - 0.0001 Yes 500 Chromium (hex) - - 0.006 - 0.006 Yes 500 Chromium (total) - - 0.459 41.60 42.06 Yes 500 Copper - - 2.038 41.60 43.64 Yes 500 Manganese - - 0.106 104.00 104.11 Yes 500 Nickel - - 1.521 41.60 43.12 Yes 500 Molybdenum - - - 41.60 41.60 Yes 500 Total HAPs 316.57 - 2000 Total Other 224.64 - 2000 CONCLUSION The facility, including operations of metal cutting, abrasive blasting, and galvanizing kettle processes, is exempt from permitting in accordance with the Utah DAQ Small Source Exemption requirements. Although registration is not required to be submitted to the Utah DAQ team, this letter documents compliance with the small source provisions of Rule 307-401-9. Please note that Ms. Ashley Zapp May 22, 2024 Page 5 of 5 other regulations may apply to the facility’s equipment, and records of burner heat input rating, annual throughput of the galvanizing kettle, abrasive blasting machines, and plasma cutters, and material metal content should be kept on-site. If any processes change at the facility or if equipment is modified, then a revised review may be required. Please feel free to contact me should you have any questions or concerns regarding this analysis at (949) 248-8490. Sincerely, Taylor Wheelon Scientist Yorke Engineering, LLC TWheelon@YorkeEngr.com cc: Michele Floren, York Engineering, LLC Sean Gildea, York Engineering, LLC Alberto Mendoza, CMC Enclosures: 1. Attachment 1 – Zinc Alloy Safety Data Sheet 2. Attachment 2 – AMASTEEL Safety Data Sheet 3. Attachment 3 – Burner Specifications 4. Attachment 4 – Emission Calculations ATTACHMENT 1 – ZINC ALLOY SAFETY DATA SHEET USZ_SHGZincSDS_Rev2018 Page 1 of 12 SAFETY DATA SHEET PRODUCT NAME: ZINC SPECIAL HIGH GRADE (SHG) EFFECTIVE DATE: SEPTEMBER 18, 2018 SCOPE: THIS SDS IS VALID FOR ALL ZINC SHG 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier Trade Name: Zinc Metal Synonyms: SHG CAS number: 7440-66-6 EINECS number: 231-175-3 Reach Registration: 01-2119467174-37-0057 (Tonnage Band >1000 t/yr) 1.2 Relevant identified uses of the substance/mixture and uses advised against In EEA member countries, use is restricted to only uses registered under REACH, i.e., raw material for metal galvanizing. See sec. 16 for list of uses Generic Exposure Scenarios (GES) were REACH registered No uses advised against. 1.3 Details of the supplier of the data sheet Supplier Address U.S. Zinc Corporation 2727 Allen Parkway; Suite 800 Houston TX 77019 Supplier Phone +001 713 926 1705 Supplier Contact John Williams Supplier Fax +001 713 924 4829 Contact Email HSE@USZinc.com Contact Phone +001 713 775 9163 1.4 Emergency Contact Phone Number: +001 888 298 3509 +001 760 602 8703 Use Client Code 10381 1.5 REACH Only Representative (OR): Nexa Resources S.A. OR Address: 26-28 Rue Edward Steichen, 2nd Floor – Luxembourg, 2540 Luxembourg OR contact person: Murillo Ayres +352 2826 3736, email: murillo.ayres@nexaresources.com USZ_SHGZincSDS_Rev2018 Page 2 of 12 2 HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture 2.1.1 U.S.A.: Not Regulated 2.1.2 EEA member countries: Regulated 2.1.2.1 Classification according to Regulation (EC) No 1272/2008 [CLP] None 2.1.2.2 Classification according to Directive 67/548/EEC No Classifications 2.1.2.3 Additional Information None 2.2 GHS Labeling Zinc Metal – no warnings 3 COMPOSITION/INFORMATION ON INGREDIENTS Component Name CAS# EC# % Composition Type Zinc (Zn) 7440-66-6 215-222-5 >=98.5% Main Lead (PbO) 7439-92-1 231-152-8 <1.45%* Impurity Cadmium (CdO) 7440-43-9 215-146-2 <0.02%* Impurity Note: all other constituents are found at trace levels or are not regulated. See individual product specifications for specific composition limits. *- All grades are below these values but some have lower limits 1) Impurity (naturally occurring) in SHG, HG, IG and LME. Spec alloy range in PWG (2) This SDS is not a TDS (Technical Data Sheet) or Specification, and covers a range of product grades and customer specifications where the hazards and controls are substantially similar and covered by the same SDS. The grade limits in effect as of the date of this SDS as follows (%): Color Code Zn min by bal Pb Fe max Cd max Al max Cu max Sn max Non-Zn max Special High Grade SHG Yellow 99.99 0.003 max 0.003 0.003 0.002 0.002 0.001 0.01 High Grade HG Green 99.95 0.02 max 0.02 0.01 0.01 0.002 0.001 0.05 Intermediate Grade IG Blue 99.5 0.05 max 0.05 0.01 0.01 0.20 - 0.5 LME Grade LME White 99.995 0.002 max 0.003 0.003 0.001 0.001 0.001 0.005 Prime Western PW Black 98.5 0.5-1.4 0.05 0.2 0.01 0.1 - 1.5 USZ_SHGZincSDS_Rev2018 Page 3 of 12 4 FIRST AID MEASURES 4.1 Description of first aid measures Skin Contact Wash with soap and water. Eye Contact Immediately flush eyes with plenty of water. Get medical attention if irritation occurs. Ingestion Drink plenty of water. Do not induce vomiting. Seek medical attention or contact Poison Control. Inhalation Remove victim to fresh air. Seek medical attention if feeling unwell or experiencing respiratory distress 4.2 Most important symptoms and effects, both acute and delayed Acute: None known Delayed: No delayed symptoms or effects expected 4.3 Indication of any immediate medical attention and special treatment needed None known 5 FIRE-FIGHTING MEASURES 5.1 Extinguishing Media – Substance will NOT burn. Substance will melt to molten phase during a sustained fire and will re-solidify when cooled (melting point 786F/420C). If sustained fire is hot enough substance will boil (boiling point 1665F/907C) and emit zinc vapor, which converts to zinc oxide (ZnO) with O2 in ambient air (ZnO is a white powder, see ZnO SDS for more information). There is no hazard with substance contacting water. However if substance is in fine form (i.e. powder or dust), water will cause rapid substance degradation to more natural stable state which is zinc oxide, and this process generates heat and H gas by-product. For this reason, if substance is on fire, do not use water and water will cause this degradation process and worsen the fire situation. Suitable Extinguishing Media Use metal extinguishing media (Class D), CO2, Smother with sand or dirt Unsuitable Extinguishing media WATER 5.2 Special hazards arising from the substance or mixture Hazards from the substance Water contaminated with this material must be contained and prevented from being discharged to environment DO NOT inhale gases or smoke from burning substance Hazardous thermal decomposition products Decomposition products may include Zinc Oxide fumes at high temperatures USZ_SHGZincSDS_Rev2018 Page 4 of 12 5.3 Advice for fire-fighters Special protective actions for fire-fighters No special measures required Special protective equipment for fire-fighters Suitable breathing apparatus In Europe EEA member countries, collect contaminated fire extinguishing media – do not release down drains. Move undamaged containers from immediate hazard area if it can be done safely. Do not spread product. 6 ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions Avoid breathing dust. Refer to Section 7 and Section 8 for advice on handling/storage and PPE. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment as appropriate. If spilled, scoop into suitable labeled container. Spills not mixed with other chemicals is recyclable. 6.2 Environmental Precautions Zinc in metallic form has limited bioavailability and poses no immediate ecological risk. In EEA countries, zinc is regulated any release to the environment must be per regulation. 6.3 Spill Cleanup Recommendation Recover the product with machine loader, shovel, etc. Dispose of waste via licensed waste disposal contractor. 7 HANDLING AND STORAGE 7.1 Precautions for Safe Handling Zinc must be thoroughly dry before being added to a molten bath. Ingots may contain cavities that collect moisture that must be dried. Entrained moisture will expand explosively when immersed in a molten bath. Practice good hygiene, refrain from eating, drinking or smoking in work areas, and wash hands before eating or drinking. 7.2 Conditions for Safe Storage/Instabilities Keep Dry 7.3 Specific end use(s) Most common use is ingredient in metal galvanizing. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control Parameters - Biological limit values: The product does not contain any hazards with biological limits. Standard Units Limit Form ACGIH STE mg/m3 5 Zn (fume) OSHA STE mg/m3 5 Zn (fume) ACGIH STE mg/m3 5 ZnO USZ_SHGZincSDS_Rev2018 Page 5 of 12 OSHA STE mg/m3 5 ZnO (respirable fraction) OSHA STE mg/m3 15 ZnO OSHA STE mg/m3 50 Pb OSHA STE mg/m3 5 Cd 8.2 Exposure Controls Respiratory Protection If exposure levels exceed limits, respiratory protection approved for the work being performed must be worn. Hand Protection Always wear glove approved for the work being performed Skin Protection Wear normal chemical work clothing. Eye Protection Always wear approved protective eyewear if there is a potential for dust being created while handling the material. General Protective Hygiene Measures None required 8.3 Other Route(s) of entry None Carcinogen Status Not a NTP/IARC carcinogen Signs and symptoms of exposure None known Notes None 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance: Silver/grey powder Typical Particle Size: 2 to 8 microns Flammability Limits: Zn is not flammable Explosive Limits: Zn is not explosive Odor: Odorless Vapor Pressure: @590 C, 810 F= 10 mm HG Odor Threshold: N/A Vapor Density: N/A pH: N/A Relative Density: 7,1 (H2O = 1) Melting point: 1975 °C Solubility in water: Insoluble (<2 mg/l) Boiling Point: 907 C, 1665 F Flash Point: Not flammable Evaporation Rate N/A Specific Gravity: 6.9 - 7.2 Molecular Weight: Zn = 65.409 Suggested Solvents: Acids and bases Fire qualities: Will not burn Explosive Qualities: Not explosive Volatile: 0.3% nominal 10 STABILITY AND REACTIVITY Reactivity Stable under normal, dry conditions Chemical stability This product is stable Possibility of hazardous reactions None Conditions to avoid or incompatible materials Heated magnesium. Water, flames and other possible sources of ignition Hazardous decomposition products Potential for ZnO fumes at elevated temperatures. ZnO may cause metal fume fever if inhaled in sufficient quantity USZ_SHGZincSDS_Rev2018 Page 6 of 12 11 TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Routes of Entry Oral, Inhalation, thru the skin (if broken up or melted) Acute Toxicity LD50(rat, Inhalation)> 5.4 mg/L, 4 hours (arts, 1996); LD50(rat, Oral) >2000 mg/kg (Prinsen, 1996) Chronic Toxicity NOAEL: none, although doses up to 2mg/kg/day may result in copper deficiency Mutagenicity No data available Carcinogenicity None known 11.2 Acute Exposure Symptoms Eye Contact Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes. Inhalation No sensitizing effects known (Van huygevoort, 1999 g,h) Skin Contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards Handle as a nuisance dust. Lead (Pb), an impurity in all zinc, is a reproductive toxic. – 0.003 to 0.5% varies 12 ECOLOGICAL INFORMATION 12.1 Toxicity Species Exposure Freshwater Algae 0.11-0.271 mg/L EC50 96hr; 0.09-0.125 mg/L EC50 72hr Water Flea 0.139-0.908 mg/L EC50 48hr Freshwater Fish 0.24 mg/L LC50 96 h; 0.41 mg/L LC50 96h; 2.16-3.05 mg/L LC50 96h; 0.211-0.269 mg/L LC50 96h; 7.8 mg/L LC50 96 h; 30 mg/L LC50 96h; 3.5 mg/L LC50 96h; 2.66 mg/L LC50 96h; 0.59 mg/L LC50 96h; 0.45 mg/L LC50 96h. 12.2 Persistence and degradability Not rapidly degradable 12.3 Bio accumulative potential No evidence to indicate significant bio accumulative potential 12.4 Mobility in soil N/A (solids-water partitioning coefficient of 158.5 l/kg, log value 2.2). 12.5 Results of PBT and vPvB assessment ZnO is not PBT or vPvB. 12.6 Other adverse effects None 13 DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Generation of product waste should be minimized wherever possible. Disposal of product, solutions, and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional or local authority requirements. Dispose of surplus and non-recyclable products via licensed waste disposal contractor. Waste should not be released into sewer system unless regulations permit such release. Material may be recyclable – contact US Zinc for more information. USZ_SHGZincSDS_Rev2018 Page 7 of 12 Containers/Packaging Generation of packaging waste should be minimized wherever possible. Waste packaging should be recycled when possible. Incineration and/or landfill dumping should only be considered when recycling isn’t feasible. Make sure to follow all local, state, federal, and international regulations when disposing of packaging materials. 14 TRANSPORTATION INFORMATION 14.1 US Information NAFTA Tariff Class 7903.10.000, Sched. B. Country of Origin U.S.A. Responsible party U.S. Zinc, Houston Texas USA Classification code M7 (Formerly: Item Number 12C) Hazard identification/reconnaissance # 90 NMFC Class N/A USDOT Information This material is not regulated for USA, Mexico or Canada ground shipments 14.2 EU Information ADR/RID IMDG IATA 14.2.1 UN Number UN3077 UN3077 UN3077 14.2.4 Packing Group III III III Additional Information Tunnel code (E) 400kg (packing group 956) 30kg (packing group Y956) 400kg (packing group 956) A97, A158, A179 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (ZINC OXIDE) 14.2.2 UN proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (ZINC OXIDE), MARINE POLLUTANT (ZINC OXIDE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (ZINC OXIDE) 14.2.3 Transport hazard Class(es) IATA Label: MiscellaneousSea (IMO): DG, MPHazard Identification Number: 90 IATA special precautions for users IATA-S.P.: IATA- Cargo Aircraft: IATA- Passenger Aircraft: IATA- Passenger Aircraft: 14.2.5 Environmental Hazards 14.2.6 Special precautions for users Yes Yes, Dangerous to the environment Yes Yes (see below)NoNo USZ_SHGZincSDS_Rev2018 Page 8 of 12 *The EU diamond for Dangerous to the Environment has a red border. A copy of this document may not be in color resulting in the above border incorrectly being displayed in black. 15 REGULATORY INFORMATION 15.1 EEA This SDS complies with GHS-CLP, and EEA/EUI REACH, HCS 2012 and SDS rules 15.2 TSCA Equivalent ‘inventory’ regulations AICS Yes SWISS Yes PICCS Yes DSL Yes NDSL No ASIA-PAC Yes EINECS Yes, on inventory ELINCS No, notification/reporting not required 15.3 USDOT Not Transport regulated, 49CFR172 SARA 302 Yes, name listed (Zinc). RQ= None, TPQ= None SARA311/312 Yes, acute hazard, 29CFR1200 SARA313 Yes, Zn & Pb compounds CA Prop.65 Yes, Pb & Cd CAA 112, 61 HAP No, not regulated, no HAP’s FIFRA 152 et seq. No (product is not subject to FIFRA) CERCLA 102/103 Name List, RQ=None NSF 60/61 Submitted NSF, UL FCC Listed CONEG Compliant ODS/ODC 82 No TSCA Yes, on Inventory, Compliant with TSCA, Notification not required RCRA 261 If governing spec is >1000 ppm Pb or >20 ppm Cd, product must be TCLP tested for Pb and Cd to determine if waste product is subject to RCRA USFDA Listed as GRAS at 21CRF182.8991 15.4 EU REACH Information Product Origin – REACH ID 01-2119463881-32-0075 (Tonnage >1000 t/year) P.R.C. Pre-Registration # 05-2114620034-66-0000 Brazil Pre-Registration # 05-2114626885-37-0000 16 OTHER INFORMATION 16.1 Safety Phrases S60 in additional languages: (FR): Eliminer le produit et son recipient comme un déchet dangereux. (IT): Questo material e il suo contenitore devono essere smaltiti come rifiuti pericolosi. (DE): Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen. USZ_SHGZincSDS_Rev2018 Page 9 of 12 16.2 Safety phrases S61 in additional languages: (FR): Eviter le rejet dand l’environnement. Consulter les instructions specials/la fiche de donnees de secruite. (IT): Non disperdere nell’ambiente. Riferirsi alle istruzioni speciali/ scede informative in material di sicurezza. (DE): Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/ Sicherheitsdatenblatt zu Rate ziehen. 16.3 Risk phrases R50/53 in additional laungages (FR): Tres toxique pour les organismes aquatiques, peut entrainer des effets nefastes a long terme pour l'environnement aquatique. (DE) : Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben. (IT): Altamente tossico per gli organismi acquatici, può provocare a lungo termine effetti negativi per l`ambiente acquatico 16.4 Signal Word, H and P phrases in additional languages: 16.4.1 DE Deutsch (German). ZINKOXID. Signalwort: Achtung. H410: Sehr giftig für Wasserorganismen mit langfristiger Wirkung. P273: Freisetzung in die Umwelt vermeiden. P391: Verschüttete Mengen aufnehmen. P501: Diesen Stoff und seine(n) Behälter entsprechend geltendem Recht der Problemabfallentsorgung zuführen. 16.4.2 FR Français (French). OXYDE DE ZINC. Mention d'avertissement: Attention. H410: Très toxique pour les organismes aquatiques, entraîne des effets néfastes à long terme. P273: Éviter le rejet dans l'environnement. P391: Recueillir le produit répandu. P501: Éliminer le contenu/récipient dans des déchets dangereux ou spéciaux conformément à la loi qui s’applique. 16.4.3 IT Italiano (Italian). OSSIDO DI ZINCO. Avvertenza: Attenzione. H410: Molto tossico per gli organismi acquatici con effetti di lunga durata. P273: Non disperdere nell'ambiente. P391: Raccogliere il materiale fuoriuscito. P501: Smaltire il prodotto/recipiente in conformità alla normativa vigente sui rifiuti speciali e pericolosi. 16.4.4 NL Dutch, Flemish (Dutch). ZINKOXIDE. Signaalwoord: Waarschuwing. H410: Zeer giftig voor in het water levende organismen, met langdurige gevolgen. P273: Voorkom lozing in het milieu. P391: Gelekte/gemorste stof opruimen. P501: Verwijder inhoud/container als gevaarlijk of bijzonder afval in overeenstemming met de geldende wetgeving. 16.4.5 ES Espanıl (Spainish). OXIDO DEL CINC. Palabra de advertencia: Atención. H410: Muy tóxico para los organismos acuáticos, con efectos nocivos duraderos. P273: Evitar su liberación al medio ambiente. P391: Recoger el vertido. USZ_SHGZincSDS_Rev2018 Page 10 of 12 P501: Disponga del contenido/envase como basura peligrosa o especial de acuerdo con la ley aplicable. 16.4.6 DA Dansih, Dansk (Danish). ZINK OXID. Signalord: Advarsel. H410: Meget giftig med langvarige virkninger for vandlevende organismer. P273: Undgå udledning til miljøet. P391: Udslip opsamles. P501: Indholdet/beholderen bortskaffes som farligt affald i overensstemmelse med gældende regler. 16.4.7 PL Polish, Polska (Polish). TLENED CYNKU. Haslo ostrzegawcze: Uwaga. H410: Dziala bardzo toksycznie na organizmy wodne, powodujac dlugotrwale skutki. P273: Unikac uwolnienia do srodowiska. P391: Zebrac wyciek. P501: Wyzucac pojemniki zawierajace toksyczne i niebezpieczne substancje zgodnie z instrukcja 16.5 HMIS Hazard Rating (Paint and Coating Industry) 16.5.1 Health 1 (Slight) 16.5.2 Flammability 0 16.5.3 Reactivity 0 16.5.4 Personal Protection E (in bulk dust conditions gloves, mask, and goggles are recommended) 16.6 CMS Hazard Rating (GHS) Zinc Oxide. Signal word: Warning. H410: Very toxic to aquatic life with long lasting effects. P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container as hazardous or special waste in accordance with applicable law. 16.7 Table: Identified uses for ZnO and corresponding Generic Exposure Scenarios (GES) as provided by studies conducted by the International Zinc Association (2016) Tables as listed: Table 1. Generic exposure scenarios for zinc oxide Number Sector Uses Code 0 Zinc production Manufacture Substance GESZnO 0 1 Formulation step Formulation general GESZnO 1 2 First tier applications Manufacturing of other zinc compounds GESZnO 2 3 Laboratory reagent GESZnO 3 4 As component for solid blends & matrices GESZnO 4 USZ_SHGZincSDS_Rev2018 Page 11 of 12 5 As component for production of dispersions, pastes and other viscous matrices GESZnO 5 6 Second tier applications DU of Zn-containing solid preparations GESZnO 6 7 DU of Zn-containing liquid & pasty preparations GESZnO 7 8 Generic wide dispersive use GESZnO 8 Table 128 is specific for nano- ZnO that is not present in US Zinc product Table 2. Identified uses for ZnO and corresponding Generic Exposure Scenario (GES) Identified Use (IU) name Brief description of use process GES code 1 Zinc metal production RLE GESZn 0 2 Zinc metal production ISF GESZn 0 3 Storage of ingots‐slabs in warehouses GESZn 1 4 Production of chemicals (pyro) GESZn 3 5 Production of chemicals (hydro) GESZn 3 6 Additive for production of inorganic catalysts GESZn 2 7 Melting, alloying and casting GESZn 1 8 Cathodic protection ‐ sacrificial anodes GESZn 1 9 Downstream use of zinc‐based sacrificial anodes GESZn 8 10 Extraction of PM (Parkes process) GESZn 5 11 Zinc casting / granules, pellets, prills, … GESZn 1, GESZn 6 12 Zinc sheet casting and rolling GESZn 1, GESZn 6 13 Wire and rods manufacturing GESZn 1, GESZn 6 14 Downstream use of Zn based wire for metal spraying GESZn 8 15 Component for soldering/brazing/ welding products GESZn 1, GESZn 6 16 Downstream use of Zinc based brazing/soldering products GESZn 8 17 Strips and coins manufacturing GESZn 1, GESZn 6 18 Batteries ballots, cans manufacturing GESZn 1, GESZn 6 19 Zinc (pure or alloyed) powder manufacturing GESZn 2 20 Passivated zinc powder manufacturing (pure or alloyed) GESZn 2 21 Use of active powders for batteries GESZn 7 22 Use of Zinc powders, pure or slightly alloyed, for formulation of paints, coatings, and inks GESZn 7 23 Use of zinc powder based paints, coatings and inks GESZn 9 24 Use of zinc powder for mechanical plating GESZn 7 USZ_SHGZincSDS_Rev2018 Page 12 of 12 25 Use of zinc powder as reductant reagent GESZn 4, GESZn 7 26 Use of (alloyed) Zn powder as corrosion inhibitor for lubricants GESZn 7 27 Use of zinc powder (pure or alloyed) in the manufacture of diamond tools GESZn 7 28 Use of zinc powder (pure or alloyed) in the manufacture of friction lining GESZn 7 29 Use of zinc powder (pure or alloyed) in the manufacture of carbon brushes GESZn 7 30 Brass manufacturing GESZn 1 31 Use of brass casts for transformation into semi‐products GESZn 6 32 Use of brass containing products GESZn 8 33 Die‐casting alloys manufacturing GESZn 1 34 Use of die‐casting ingots GESZn 6 35 Manufacturing of Zinc containing Al‐alloys GESZn 1 36 Use of zinc containing Al alloys GESZn 6 37 General hot dip galvanizing GESZn 5 38 Continuous hot dip galvanizing GESZn 5 39 Electro-galvanizing GESZn 5 40 Electroplating GESZn 5 41 Production of "targets by (EB) PVD or other sputtering techniques GESZn 5, Generic consumer/environment* 42 Use of galvanized goods Generic consumer/environment *Corresponds to “GES 10” in IUCLID 16.8 Preparation Date (see heading) 16.9 Other This Safety Data Sheet (SDS) provides information on the safety requirements working with this material. This SDS is not a guarantee of the product’s properties. The information is believed to be accurate by the preparer utilizing reasonably available published data. We are not responsible for any inadvertent error or omission. End use of this product will include many factors beyond our control, and we cannot accept liability for any accident, injury, or damage caused by its use. ATTACHMENT 2 – AMASTEEL SAFETY DATA SHEET Page 1/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 55.2.3 1 Identification 2 Hazard(s) identification Classification of the substance or mixture The product is not classified, according to the Globally Harmonized System (GHS). Label elements GHS label elements Void Hazard pictograms Void Signal word Void Hazard statements Void Classification system: NFPA ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description:Mixture: consisting of the following components. Dangerous components: carbon7440-44-0 0.80-1.20% manganese7439-96-5 0.35-1.20% silicon7440-21-3 0.40-1.50% sulfur7704-34-9 <0.05% Nickel7440-02-0 <0.2% (Contd. on page 2) US Product identifier Trade name: AMASTEEL Details of the supplier of the safety data sheet Manufacturer/Supplier: Ervin Industries, Inc. 3893 Research Park Drive Ann Arbor, MI 48108-2217 Phone: (734)-769-4600/Fax: (734)-663-0136 sales@ervinindustries.com http://www.ervinindustries.com Information department: Quality Assurance Department (mo-thu: 8 a.m.-4 p.m., fr: 8 a.m. - 1 p.m.) Emergency telephone number: Phone: (734)-769-4600/Fax: (734)-663-0136 EUPCS: PC-TEC-12 Page 2/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 1) 55.2.3 7723-14-0 red phosphorus <0.05% 4 First-aid measures Description of first aid measures General information:No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. Consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. Use fire fighting measures that suit the environment. For safety reasons unsuitable extinguishing agents:Water Special hazards arising from the substance or mixture Product is not flammable. Fine metal dust removed as a waste stream and / or contamination during the blasting process, poses a small minor risk of causing a fire or explosion. Advice for firefighters Protective equipment:No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Scrap and debris can cause slip and fall hazards. It is recommended that floors and work areas be kept clean at all times. floors and work areas clean at all times. Environmental precautions:No special measures required. Methods and material for containment and cleaning up:Pick up mechanically. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. None None (Contd. on page 3) US Page 3/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 2) 55.2.3 Protective Action Criteria for Chemicals PAC-1: 7439-96-5 manganese 3 mg/m³ 7440-21-3 silicon 45 mg/m³ 7440-44-0 carbon 6 mg/m³ 7723-14-0 red phosphorus 0.27 mg/m³ 7440-02-0 Nickel 6 mg/m³ PAC-2: 7439-96-5 manganese 5 mg/m³ 7440-21-3 silicon 100 mg/m³ 7440-44-0 carbon 330 mg/m³ 7723-14-0 red phosphorus 3 mg/m³ 7440-02-0 Nickel 330 mg/m³ PAC-3: 7439-96-5 manganese 1,800 mg/m³ 7440-21-3 silicon 630 mg/m³ 7440-44-0 carbon 2,000 mg/m³ 7723-14-0 red phosphorus 18 mg/m³ 7440-02-0 Nickel 2,000 mg/m³ 7 Handling and storage Handling: Precautions for safe handling Take special care to prevent the product from leaking. Exercise special care when removing the tie-down straps that are part of the bulk pallet shipments. Information about protection against explosions and fires:No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:None. Storage class:13 Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. (Contd. on page 4) US Page 4/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 3) 55.2.3 7439-96-5 manganese PEL Ceiling limit value: 5 mg/m³ as Mn REL Short-term value: 3 mg/m³ Long-term value: 1 mg/m³ fume, as Mn TLV Long-term value: 0.02* 0.1** mg/m³ as Mn; A4, *respirable **inhalable fraction 7440-21-3 silicon PEL Long-term value: 15* 5** mg/m³ *total dust **respirable fraction REL Long-term value: 10* 5** mg/m³ *total dust **respirable fraction TLV TLV withdrawn Regulatory information PEL: Guide to Occupational Exposure Values (OSHA PELs) REL: Guide to Occupational Exposure Values (NIOSH RELs) TLV: Guide to Occupational Exposure Values (TLV) Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. Filter P2 Protection of hands:Leather gloves Material of gloves Recommended thickness of the material: - mm Penetration time of glove material Value for the permeation: Level - Eye protection:Safety glasses Body protection:Protective work clothing 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form:Solid Odor:Odorless Odor threshold:Not determined. pH-value:Not applicable. Change in condition Melting point/Melting range:1500 °C (2,732 °F) (~2700 °F) Boiling point/Boiling range:3000 °C (5,432 °F) (~5400 °F) Flash point:Not applicable. Flammability (solid, gaseous):Not determined. Decomposition temperature:Not determined. Auto igniting:Product is not selfigniting. Danger of explosion:Product does not present an explosion hazard. (Contd. on page 5) US Page 5/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 4) 55.2.3 Explosion limits: Lower:Not determined. Upper:Not determined. Vapor pressure:Not applicable. Density at 20 °C (68 °F):7.8 g/cm³ (65.09 lbs/gal) Relative density Not determined. Vapor density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water:Insoluble. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic:Not applicable. Kinematic:Not applicable. Solvent content: VOC content:0.00 % Solids content:100.0 % Other information No further relevant information available. 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin:No irritant effect. on the eye:No irritating effect. Sensitization: Examination nickel release in accordance with DIN EN 1811: 2012-10: done Sample Number 2016-00916 <0.1 g per cm2 and week therefore no sensitization detected Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. Carcinogenic categories IARC (International Agency for Research on Cancer) 7440-02-0 Nickel 1 (Contd. on page 6) US Page 6/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 5) 55.2.3 NTP (National Toxicology Program) 7440-02-0 Nickel R OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes:Not hazardous for water. Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. completely emptied packaging in 25kg paper bag: paper recycling completely emptied packaging in big bags: commercial waste disposal completely emptied packaging in steel barrels: metal recycling 14 Transport information UN-Number DOT, ADR, ADN, IMDG, IATA Void UN proper shipping name DOT, ADR, ADN, IMDG, IATA Void Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class Void Packing group DOT, ADR, IMDG, IATA Void Environmental hazards:Not applicable. Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. (Contd. on page 7) US Page 7/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 6) 55.2.3 UN "Model Regulation":Void 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): 7723-14-0 red phosphorus Section 313 (Specific toxic chemical listings): 7439-96-5 manganese 7723-14-0 red phosphorus TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Hazardous Air Pollutants 7439-96-5 manganese 7723-14-0 red phosphorus Proposition 65 Warning: This product can expose you to chemicals including Nickel, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov Chemicals known to cause cancer: 7440-02-0 Nickel Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Cancerogenity categories EPA (Environmental Protection Agency) 7439-96-5 manganese D 7723-14-0 red phosphorus D TLV (Threshold Limit Value) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. GHS label elements Void Hazard pictograms Void Signal word Void Hazard statements Void National regulations: Information about limitation of use:Employment restrictions concerning young persons must be observed. Water hazard class:Generally not hazardous for water. (Contd. on page 8) US Page 8/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 7) 55.2.3 Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Motivo da mudança: Version 2: 28.05.2015: Section 5.1 Extinguishing agents; 8.1 AGW measuring method. Version 3: 06.09.2015: Section 1, 15, adaptation to the regulation 453/2015/EC, 830/2015/EU, 18/2012/EU Version 4: 05.03.2016: Section 1.3 Version 5: 19.06.2016: Section 13 Version 6: 07.06.2019: Section 3, 8 Version 7: 16.02.2020: Section 13 Version 8: 18.02.2021: Section 1, 13, 15 Version 9: 11.05.2022: Section 2, 8, 15 Contact:Dr. W. Assmann Date of preparation / last revision 01/15/2023 Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit * Data compared to the previous version altered.Amasteel Safety Data Sheet:AMASTEEL US ATTACHMENT 3 – BURNER SPECIFICATIONS ATTACHMENT 4 – EMISSION CALCULATIONS Copyright ©2024 , Yorke Engineering, LLC Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr) Total (ton/yr) Limit (ton/yr) CO 1048.32 - - - 1048.32 0.52 5.00 NOx 1248.00 - - - 1248.00 0.62 5.00 ROG 68.64 - - - 68.64 0.034 5.00 SOx 7.49 - - - 7.49 0.0037 5.00 PM10 94.85 144.25 2870.40 4160.00 7269.50 3.63 5.00 Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr) HAP? Limit (lb/yr) Benzene 0.100 - - - 0.100 Yes 500 Formaldehyde 0.212 - - - 0.212 Yes 500 Ammonia 224.64 - - - 224.64 No 500 Tin - 0.001 - - 0.001 No 500 Copper - 0.001 - - 0.001 Yes 500 Aluminum - 0.001 - - 0.001 No 500 Lead - 0.004 0.020 - 0.024 Yes 500 Cadmium - 0.004 0.020 - 0.024 Yes 500 Arsenic - - 0.014 - 0.014 Yes 500 Beryllium - - 0.004 - 0.004 Yes 500 Selenium - - 0.063 - 0.063 Yes 500 Mercury - - 0.0001 - 0.000 Yes 500 Chromium (hex) - - 0.006 - 0.006 Yes 500 Chromium (total) - - 0.459 41.60 42.06 Yes 500 Copper - - 2.038 41.60 43.64 Yes 500 Manganese - - 0.106 104.00 104.11 Yes 500 Nickel - - 1.521 41.60 43.12 Yes 500 Molybdenum - - - 41.60 41.60 Yes 500 316.57 - 2000 224.64 - 2000Total Other Summary of Hazardous Air Pollutants and Other Air Contaminents Emissions Emissions Summary of Criteria Pollutants Criteria Pollutant Pollutant Total HAPs Copyright ©2024 , Yorke Engineering, LLC Limit (lb/yr) (ton/yr) (ton/yr) CO 1.05E+03 5.24E-01 5 NOx 1.25E+03 6.24E-01 5 ROG 6.86E+01 3.43E-02 5 SOx 7.49E+00 3.74E-03 5 PM10 9.48E+01 4.74E-02 5 Operation Schedule Hours/Day Days/Week Weeks/Year Equipment Maximum 24 7 52 Facility Maximum 24 7 52 Emissions Calculation Data Description Value Units Burner Rating 1.50 mmBtu/hr Heating Value of Fuel* 1,050 mmBtu/mmscf Annual Fuel Usage 12.48 mmscf CO EF 84.00 lbs/mmscf NOx EF 100.00 lbs/mmscf ROG EF 5.50 lbs/mmscf SOx Emission 0.60 lbs/mmscf PM10 Emission 7.60 lbs/mmscf *EIA for Utah list 1042-1045 for 2020's, 1040 for 2018 EF Limit (lb/mmscf) (lb/yr) Hap? (lb/yr) Benzene 0.0080 9.98E-02 Yes 500 Formaldehyde 0.017 2.12E-01 Yes 500 Ammonia 18.00 2.25E+02 No 500 3.12E-01 - 2000 2.25E+02 - 2000 AP-42 Toxic Air Contaminent (TAC) Emission Factors for Natural Gas (lbs/mmscf) External Combustion Equipment Burner Combustion Emission Calculations – Criteria Pollutants Total HAPs Total Other Burner Combustion Emission Calculations – Hazardous Air Pollutants and Other Air Contaminents Emissions Pollutant AP42 SCAQMD Default Combustion Emission Factors (Revised January 2022) External Combustion Equipment EF Table - NG/Other Equipment AP42 Criteria Pollutant Standard Conversion Factor Reference Burner Specifications, 2x 0.75 Emissions Copyright ©2024 , Yorke Engineering, LLC Limit (lb/yr) (ton/yr) (ton/yr) PM10 1.44E+02 7.21E-02 5 Emissions Calculation Data Description Value Units 43,713 lb/yr 21.86 ton/yr PM EF*6.6 lb/ton 144.25 lb/yr 0.072 ton/yr 1. 8% Zinc by weight *6.6 lb/ton is the EF for Zinc throughput * TACs = % from sds of total pm * 43,713 lbs/year is the maximum annual zinc usage from purchase data Content Limit (Percent)(lb/yr) (ton/yr) HAP? (lb/yr) Lead 0.003% 4.33E-03 2.16E-06 Yes 500 Cadmium 0.003% 4.33E-03 2.16E-06 Yes 500 Tin 0.001% 1.44E-03 7.21E-07 No 500 Copper 0.001% 1.44E-03 7.21E-07 Yes 500 Aluminum 0.001% 1.44E-03 7.21E-07 No 500 1.15E-02 5.77E-06 - 2000 2.89E-03 1.44E-06 - 2000 Criteria Pollutant Emissions Galvanizing Kettle Emission Calculations – Criteria Pollutants Total HAPs Total Other Pollutant Maximum Zinc Throughput Total PM Galvanizing Kettle Emission Calculations – Hazardous Air Pollutants and Other Air Contaminents Emissions Copyright ©2024, Yorke Engineering, LLC Limit (lb/yr) (ton/yr) (ton/yr) Cabinet 1 1435.20 7.18E-01 5 Cabinet 2 1435.20 7.18E-01 5 Description Value Units Reference Amount of Abrassive Used 1000.00 lbs/hr 2018 application PM EF1 0.69 lb/1000lbs of abrasive AP-42 13.2.6-1 Time Period Equipment Maximum Facility Maximum Hours/Day 8 24 Days/Week 5 7 Weeks/Year 52 52 Result Limit (wt. %) (lb/yr) HAP? (lb/yr) Arsenic 0.00050% 1.44E-02 Yes 500 Lead 0.00069% 1.98E-02 Yes 500 Cadmium 0.00010% 2.87E-03 Yes 500 Beryllium 0.00013% 3.73E-03 Yes 500 Manganese 0.0037% 1.06E-01 Yes 500 Nickel 0.053% 1.52E+00 Yes 500 Selenium 0.0022% 6.31E-02 Yes 500 Mercury 0.0000050% 1.44E-04 Yes 500 Chromium (total) 0.016% 4.59E-01 Yes 500 Chromium (hex) 0.00020% 5.74E-03 Yes 500 Copper 0.071% 2.04E+00 Yes 500 2.20E+00 - 2000 0.00E+00 - 2000 Blasting Cabinet Emission Calculations – HAP and Other Air Contaminent Emissions Emissions Total Other Total HAPs Pollutant EmissionsSource Blasting Cabinet Emission Calculations – Criteria Pollutants Operating Schedule Emissions Parameters Copyright ©2024, Yorke Engineering, LLC Limit (lb/yr)(ton/yr)(ton/yr) PM10 4.16E+03 2.08E+00 5 Limit (lb/yr)HAP?(lb/yr) Manganese 1.04E+02 Yes 500 Nickel 4.16E+01 Yes 500 Copper 4.16E+01 Yes 500 Chromium 4.16E+01 Yes 500 Molybdenum 4.16E+01 Yes 500 Total HAPs 2.70E+02 - 2000 Total Other 0.00E+00 - 2000 Metals are calculated assuming that the fume (PM10) emissions have the same composition as the table above, i.e., PM10 emissions multiplied by the applicable weight percentage. Emissions Calculation Data Description Value Units Material Cut (ton/year)8,320 tons/yr Percent of Material Removed by Cutting 5% Percent Fume (PM10) EF - Dry (lb/lb cut) 5% % Fume (PM10) EF - Semi-Wet (lb/lb cut) 0.5% % Fume (PM10) EF - Wet (lb/lb cut) 0.05% % Filter Efficiency (%) 0% Manganese 2.5% Nickel 1.0% Copper 1.0% Chromium 1.0% Molybdenum 1.0% Pollutant Emissions Plasma Cutting - Semi-Wet - Mild Steel Emission Calculations – HAP and Other Air Contaminents Plasma Cutting - Semi-Wet - Mild Steel Emission Calculations – Criteria Pollutants Criteria Pollotant Emissions Summary of Constituents in Metals Cut AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) No Filtration AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) Source Applicant AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) Engineering Estimation Copyright ©2024 , Yorke Engineering, LLC Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr)Total (ton/yr)Limit (ton/yr) CO 1048.32 ---1048.32 0.52 5.00 NOx 1248.00 ---1248.00 0.62 5.00 ROG 68.64 ---68.64 0.034 5.00 SOx 7.49 ---7.49 0.0037 5.00 PM10 94.85 144.25 2870.40 4160.00 7269.50 3.63 5.00 Burners Kettle Abrasive Blasting Plasma Cutting Total (lb/yr)HAP?Limit (lb/yr) Benzene 0.100 ---0.100 Yes 500 Formaldehyde 0.212 ---0.212 Yes 500 Ammonia 224.64 ---224.64 No 500 Tin -0.001 --0.001 No 500 Copper -0.001 --0.001 Yes 500 Aluminum -0.001 --0.001 No 500 Lead -0.004 0.020 -0.024 Yes 500 Cadmium -0.004 0.020 -0.024 Yes 500 Arsenic --0.014 -0.014 Yes 500 Beryllium --0.004 -0.004 Yes 500 Selenium --0.063 -0.063 Yes 500 Mercury --0.0001 -0.000 Yes 500 Chromium (hex)--0.006 -0.006 Yes 500 Chromium (total)--0.459 41.60 42.06 Yes 500 Copper --2.038 41.60 43.64 Yes 500 Manganese --0.106 104.00 104.11 Yes 500 Nickel --1.521 41.60 43.12 Yes 500 Molybdenum ---41.60 41.60 Yes 500 316.57 -2000 224.64 -2000Total Other Summary of Hazardous Air Pollutants and Other Air Contaminents Emissions Emissions Summary of Criteria Pollutants Criteria Pollutant Pollutant Total HAPs Copyright ©2024, Yorke Engineering, LLC Limit (lb/yr)(ton/yr)(ton/yr)CO 1048.32 5.24E-01 5 1048.32 5.24E-01NOx1248.00 6.24E-01 5 1248 6.24E-01 ROG 68.64 3.43E-02 5 68.64 3.43E-02SOx7.49 3.74E-03 5 7.488 3.74E-03PM1094.85 4.74E-02 5 94.848 4.74E-02 Operation Schedule Hours/Day Days/Week Weeks/Year Equipment Maximum 24 7 52Facility Maximum 24 7 52 Emissions Calculation DataDescription Value UnitsBurner Rating 1.50 mmBtu/hr <-- ask for document (also the burner is exempt)Heating Value of Fuel* 1,050 mmBtu/mmscfAnnual Fuel Usage 12.48 mmscfCO EF 84.00 lbs/mmscfNOx EF 100.00 lbs/mmscfROG EF 5.50 lbs/mmscfSOx Emission 0.60 lbs/mmscfPM10 Emission 7.60 lbs/mmscf*EIA for Utah list 1042-1045 for 2020's, 1040 for 2018 EF Limit (lb/mmscf)(lb/yr)Hap?(lb/yr) Benzene 0.0080 9.98E-02 Yes 500Formaldehyde0.017 2.12E-01 Yes 500Ammonia18.00 2.25E+02 No 500 3.12E-01 -20002.25E+02 -2000 AP-42 Toxic Air Contaminent (TAC) Emission Factors for Natural Gas (lbs/mmscf) External Combustion Equipment ^ Sourced from South Coast AQMD Emissions Calculator References for Emission Factors, not AP-42. There should be more HAPs but again, exempt equipment so it doesn't matter. Burner Combustion Emission Calculations – Criteria Pollutants Total HAPsTotal Other Burner Combustion Emission Calculations – Hazardous Air Pollutants and Other Air Contaminents Emissions Pollutant AP42 SCAQMD Default Combustion Emission Factors (Revised January 2022) External Combustion Equipment EF Table - NG/Other Equipment AP42 Criteria Pollutant Standard Conversion Factor ReferenceBurner Specifications, 2x 0.75 Emissions Copyright ©2024, Yorke Engineering, LLC Limit (lb/yr)(ton/yr)(ton/yr) PM10 1.44E+02 7.21E-02 5 Emissions Calculation Data Description Value Units 43,713 lb/yr 21.86 ton/yr PM EF*6.6 lb/ton 144.25 lb/yr 0.072 ton/yr 1. 8% Zinc by weight *6.6 lb/ton is the EF for Zinc throughput * TACs = % from sds of total pm <-- Ask for SDS * 43,713 lbs/year is the maximum annual zinc usage from purchase data Content Limit (Percent)(lb/yr)(ton/yr)HAP?(lb/yr) Lead 0.003%4.33E-03 2.16E-06 Yes 500 Cadmium 0.003%4.33E-03 2.16E-06 Yes 500 Tin 0.001%1.44E-03 7.21E-07 No 500 Copper 0.001%1.44E-03 7.21E-07 Yes 500 Aluminum 0.001%1.44E-03 7.21E-07 No 500 1.15E-02 5.77E-06 -2000 2.89E-03 1.44E-06 -2000 Criteria Pollutant Emissions Galvanizing Kettle Emission Calculations – Criteria Pollutants Total HAPs Total Other Pollutant Maximum Zinc Throughput Total PM Galvanizing Kettle Emission Calculations – Hazardous Air Pollutants and Other Air Contaminents Emissions Copyright ©2024, Yorke Engineering, LLC Limit (lb/yr)(ton/yr)(ton/yr) Cabinet 1 1435.20 7.18E-01 5 Cabinet 2 1435.20 7.18E-01 5 Description Value Units Reference Amount of Abrassive Used 1000.00 lbs/hr 2018 application PM EF1 0.69 lb/1000lbs of abrasive AP-42 13.2.6-1 Time Period Equipment Maximum Facility Maximum Hours/Day 8 24 Days/Week 5 7 Weeks/Year 52 52 Result Limit (wt. %)(lb/yr)HAP? (lb/yr) Arsenic 0.00050%1.44E-02 Yes 500 Lead 0.00069%1.98E-02 Yes 500 Cadmium 0.00010%2.87E-03 Yes 500 Beryllium 0.00013%3.73E-03 Yes 500 Manganese 0.0037%1.06E-01 Yes 500 Nickel 0.053%1.52E+00 Yes 500 Selenium 0.0022%6.31E-02 Yes 500 Mercury 0.0000050%1.44E-04 Yes 500 Chromium (total)0.016%4.59E-01 Yes 500 Chromium (hex)0.00020%5.74E-03 Yes 500 Copper 0.071%2.04E+00 Yes 500 2.20E+00 -2000 0.00E+00 -2000 Blasting Cabinet Emission Calculations – HAP and Other Air Contaminent Emissions Emissions Total Other Total HAPs Pollutant EmissionsSource Blasting Cabinet Emission Calculations – Criteria Pollutants Operating Schedule Emissions Parameters Copyright ©2024, Yorke Engineering, LLC Limit(lb/yr)(ton/yr)(ton/yr) PM10 4.16E+03 2.08E+00 5 Limit(lb/yr)HAP?(lb/yr) Manganese 1.04E+02 Yes 500Nickel4.16E+01 Yes 500 Copper 4.16E+01 Yes 500 Chromium 4.16E+01 Yes 500Molybdenum4.16E+01 Yes 500 Total HAPs 2.70E+02 -2000Total Other 0.00E+00 -2000 Metals are calculated assuming that the fume (PM10) emissions have the same composition as the table above, i.e., PM10 emissions multiplied by the applicable weight percentage. Emissions Calculation Data Description Value Units Material Cut (ton/year)8,320 tons/yr Percent of Material Removed by Cutting 5%Percent Fume (PM10) EF - Dry (lb/lb cut) 5%% Fume (PM10) EF - Semi-Wet (lb/lb cut) 0.5%% Fume (PM10) EF - Wet (lb/lb cut) 0.05%% Filter Efficiency (%)0% <-- Ask to provide evedence of thisManganese2.5% Nickel 1.0%Copper 1.0%Chromium 1.0% Molybdenum 1.0% Pollutant Emissions Plasma Cutting - Semi-Wet - Mild Steel Emission Calculations – HAP and Other Air Contaminents Plasma Cutting - Semi-Wet - Mild Steel Emission Calculations – Criteria Pollutants Criteria Pollotant Emissions Source Applicant AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) Engineering Estimation Summary of Constituents in Metals Cut AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) No Filtration AP-42, Emission of Fume, Nitrogen Oxides and Noise in Plasma Cutting of Stainless and Mild Steel, by Broman B. et al, The Swedish Institute of Production Engineering (March 1994) Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 1 of 7 - 2019-01-24 Low Carbon (mild steel) Steel Products SAFETY DATA SHEET (Complies with OSHA 29 CFR 1910.1200) SECTION I: PRODUCT IDENTIFICATION Contech® Engineered Solutions LLC. 9025 Centre Pointe Drive West Chester, Ohio 45069 Information: 513-645-7055 Emergency Telephone Number (ChemTel) 1-800-255-3924 The most recent version of this document can be found at www.ContechES.com SDS CON1 Revision: Jan-19 Product(s): Low Carbon (mild steel) Steel Products #200,209,221,231,400 Product Use: Industrial use or Construction Use SECTION II - HAZARD IDENTIFICATION Hazard-determining components of labeling: Cold Rolled, Hot Rolled Steel and Enameling Steel is considered an article under Reach regulation (REACH REGULATION (EC) No 1907/2006) and is not subject to classification under CLP regulation (REGULATION (EC) No 1272/2008). However, Cold Rolled, Hot Rolled Steel and Enameling Steel is not exempt as an article under OSHA's Hazard Communication Standard (29 CFR 1910.1200) due to its downstream use, thus this product is considered a mixture and a hazardous material. Therefore, the categories of Health Hazards as defined in “GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS (GHS), Third revised edition ST/SG/AC.10/30/Rev. 3” United Nations, New York and Geneva, 2009 have been evaluated. Refer to Section 3, 8 and 11 for additional information. This formed solid metal product poses little or no immediate health or fire hazard. When product is subjected to welding, burning, melting, sawing, brazing, grinding or other processes, potentially hazardous airborne particulate and fumes may be generated. The hazards identified below are only relevant to these processes. 2.1 Classification of the substance or mixture Skin Sensitization – Category 1 Specific Target Organ Toxicity Repeat Exposure – Category 1 (lung) Carcinogen – Category 2 Toxic to Reproduction – Category 2 Eye Irritation – Category 2B Specific Target Organ Toxicity: Single Exposure – Category 3 (Lung) Acute Toxicity – Oral – Category 4 Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 2 of 7 - 2019-01-24 2.2a Signal word DANGER! 2.2b Hazard Statements May cause an allergic skin reaction May cause damage to lungs through prolonged or repeated inhalation Suspected of causing cancer Suspected of damaging fertility or the unborn child Dust, particles and fumes cause eye irritation May cause respiratory irritation Harmful if swallowed. 2.2c Pictograms 2.2d Precautionary statements Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Wear impervious gloves, eye protection, and protective clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Wash contaminated clothing after use, before re-use, and before removing from workplace. Concentration in air of the various contaminants determines the extent of respiratory protection needed. Half-face, air- negative-pressure purifying respirator equipped with P100 filter is acceptable for concentrations up to 10 times the exposure limit. Full-face, negative-pressure, air-purifying respirator equipped with P100 filter is acceptable for concentrations up to 50 times the exposure limit. Respirators should be selected by and used under the direction of a trained health and safety professional, following requirements found in OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection (Z88.2). Do not breathe dust / fumes. If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin (or hair): Wash thoroughly with water. If significant skin irritation or rash occurs: get medical advice or attention. Immediately seek medical attention if symptoms are significant or persist. Dispose of material in accordance with all regulations. 2.3 Additional Information None 2.3a HNOC – Hazards not otherwise classified: None known 2.3b Unknown Acute Toxicity: None known SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Components CAS No. % by Weight Iron 7439-89-6 > 96 Manganese 7439-96-5 ≤ 2.5 Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 3 of 7 - 2019-01-24 Chromium 7440-47-3 ≤ 1.0 Copper 7440-50-8 ≤ 1.0 Molybdenum 7439-98-7 ≤ 1.0 Nickel 7440-02-0 ≤ 1.0 SECTION IV – FIRST AID MEASURES 4.1 Description of the first-aid measures General information: This formed solid metal product poses little or no immediate health or fire hazard. When product is subjected to welding, burning, melting, sawing, brazing, grinding or other processes, potentially hazardous airborne particulate and fumes may be generated. The hazards identified below are only relevant to these processes. After inhalation:. Remove person to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration. In case of unconsciousness, place patient stably in side position for transportation. After skin contact: Wash skin with cool water and pH-neutral soap or a mild detergent. If significant skin irritation or rash occurs: get medical advice or attention. After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. After swallowing: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. Never give anything by mouth to an unconscious person. 4.2 Most important symptoms/effects, acute and delayed Inhalation: May cause damage to lungs through prolonged or repeated inhalation Skin contact: May cause an allergic skin reaction Eye Contact: Dust, particles and fumes cause eye irritation Ingestion: Harmful if swallowed. 4.3 Indication of immediate medical attention and special treatment needed: None known. SECTION V - FIRE FIGHTING MEASURES This formed solid metal product poses little or no immediate health or fire hazard. When product is subjected to welding, burning, melting, sawing, brazing, grinding or other processes, potentially hazardous airborne particulate and fumes may be generated. The hazards identified below are only relevant to these processes. 5.1 Flammability of the Product: Non-flammable and non-combustible. Finely divided dust is combustible. 5.2 Suitable extinguishing agents: Treat for surrounding material 5.3 Special hazards arising from the substance or mixture: None 5.3a Products of Combustion: None 5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of shocks SECTION VI – ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Wear personal protective equipment (See section VIII). Keep unprotected persons away. 6.2 Methods and material for containment and cleaning up: For spills involving finely divided particles, clean-up personnel should be protected against contact with eyes and skin. IF material is in a dry state, avoid inhalation of dust. Dispose of unwanted materials and containers properly in accordance with all regulations. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE 7.1 Handling Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 4 of 7 - 2019-01-24 Precautions for safe handling: Wear protective equipment for hands to protect from sharp edges. Wear protective equipment to protect feet and body from injury due to the weight of this material. Further processing including welding, burning, & grinding, etc., has the potential for generating high concentrations of airborne particulates and fumes and should be evaluated and controlled as necessary. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. 7.2 Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep out of the reach of children.. SECTION VIII – EXPOSURE CONTROL MEASURES / PERSONAL PROTECTION 8.1 Components with limit values that require monitoring at the workplace: Hazardous Components PEL (OSHA) TLV (ACGIH) mg/M3 mg/M3 Iron 10 (as FeOx fume) 5.0 Chromium 0.5 (as Cr II & III) 0.5 1.0 (as Cr, metal) 0.5 0.005 (as Cr VI, inorganics) 0.01 Copper 0.1 (as fume, Cu) 0.1 1.0 (as dust & mist) 1.0 Manganese 5.0 (as fume, Mn compounds) 0.2 Molybdenum 15 (as total dust) 10 5 (respirable fraction) 10 Nickel 1.0 (as Ni & insoluble) 1.5 (resp metal), 0.2 (resp inorganics) 8.2 Exposure Controls Use ventilation adequate to keep exposures below recommended exposure limits. 8.3 General protective and hygienic measures Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. 8.3a Personal protective equipment Protection of hands: Wear gloves of adequate length to offer appropriate skin protection. Cut resistant gloves have been found to offer adequate protection for incidental contact. Eye protection: Wear approved eye protection (properly fitted dust- or splash-proof chemical safety glasses. Respiratory protection: Concentration in air of the various contaminants determines the extent of respiratory protection needed. Half-face, air- negative-pressure purifying respirator equipped with P100 filter is acceptable for concentrations up to 10 times the exposure limit. Full-face, negative-pressure, air-purifying respirator equipped with P100 filter is acceptable for concentrations up to 50 times the exposure limit. Respirators should be selected by and used under the direction of a trained health and safety professional, following requirements found in OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection (Z88.2). SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS General Information Appearance Form: Metallic Color: Gray Odor: None Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 5 of 7 - 2019-01-24 pH-value at 20°C (68 °F): Not applicable Boiling point/Boiling range: Not applicable Melting point/Freezing Point: ~2750oF (~1510oC) Flash point: Not applicable Auto igniting: Product is not self-igniting Vapor pressure at 21°C (70°F) Not available Density at 25°C (77 °F): 7.85 g/cm3 Solubility in Water: Insoluble VOC content: Not applicable SECTION X – STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal storage conditions. Keep in dry storage. 10.3 Possibility of hazardous reaction No dangerous reaction known under conditions of normal use. 10.4 Thermal decomposition / conditions to be avoided No decomposition if used according to specifications. 10.5 Incompatible materials Will react with strong acids to form hydrogen. Iron oxide dusts in contact with calcium hypochlorite evolve oxygen and may cause an explosion. 10.6 Hazardous Decomposition or By-products Thermal oxidative decomposition of steel products can produce flames containing oxides of iron and manganese as well as other alloying elements. SECTION XI – TOXICOLOGICAL INFORMATION 11.1 Exposure Routes: Skin contact, skin adsorption, eye contact, inhalation, or ingestion. 11.2 Symptoms related to physical/chemical/toxicological characteristics: Inhalation: As sold/shipped is not likely form of exposure Skin contact: As sold/shipped is not likely form of exposure. Eye Contact: As sold/shipped is not likely form of exposure Ingestion: As sold/shipped is not likely form of exposure. 11.3 Delayed, immediate and chronic effects of short-term and long-term exposure This formed solid metal product poses little or no immediate health or fire hazard. When product is subjected to welding, burning, melting, sawing, brazing, grinding or other processes, potentially hazardous airborne particulate and fumes may be generated. The hazards identified below are relevant to these processes. Short Term Skin Corrosion/Irritation: Not corrosive. Skin Sensitization: May cause an allergic skin reaction. Eye Damage/Irritation: Causes eye irritation. Respiratory Sensitization: Not available Specific Target Organ Toxicity-Single Exposure: (Category 3) May cause an allergic skin reaction. Aspiration Hazard: Not available Harmful if swallowed. Long Term Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 6 of 7 - 2019-01-24 Carcinogenicity: Suspected of causing cancer through chronic inhalation of dust or fumes. Germ Cell Mutagenicity: Not available Reproductive Toxicity: Toxic to reproduction – Category 2. Specific Target Organ Toxicity- Repeated Exposure: (Category 1) Causes damage to lungs through prolonged/repeated exposure of dust or fumes. Synergistic/Antagonistic Effects: Not available. SECTION XII – ECOLOGICAL INFORMATION 12.1 Ecotoxicity No further relevant information available. 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential: No further relevant information available. 12.4 Mobility in soil No further relevant information available. 12.5 Other Adverse Effects No further relevant information available. SECTION XIII – DISPOSAL CONSIDERATIONS 13.1 Waste Disposal Method The material should be recycled whenever possible, but may be land filled. This product is not classified as a hazardous waste under the authority of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance with local, state and federal regulations. 13.2 Other disposal considerations Uncleaned packaging Recommendation: Disposal must be made in accordance with local, state and federal regulations. Recommended cleansing agent: Not applicable SECTION XIV – TRANSPORT INFORMATION DOT (U.S.) TDG (Canada) UN-Number Not Regulated Not Regulated UN proper shipping name Not Regulated Not Regulated Transport Hazard Class(es) Not Regulated Not Regulated Packing Group (if applicable) Not Regulated Not Regulated 14.1 Environmental hazards: Not Available 14.2 Transport in bulk according to Annex II of Marpol 73/78 and the IBC Code Not available 14.3 Special precautions for user Do not handle until all safety precautions have been read and understood. SECTION XV – OTHER REGULATORY INFORMATION 15.1 Safety, Health and Environmental Regulations/Legislations specific for the chemical Canada Contech ES - 9025 Centre Pointe Drive West Chester, Ohio 45069 - SDS# CON1 - Page 7 of 7 - 2019-01-24 WHMIS Classification: Considered to be a hazardous material under the Hazardous Products Act as defined by the Hazardous Products Regulations and subject to the requirements of Health Canada’s Workplace Hazardous Material Information (WHMIS). This document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and the HPR. 15.2 US Federal Information SARA 302/311/312/313 Components The product contains the following toxic chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372: CAS Chemical % by Weight 7440-47-3 Chromium 1.0 max 7440-50-8 Copper 1.0 max 7439-96-5 Manganese 2.5 max 7440-02-0 Nickel 1.0 max 15.3 State Right to Know Laws California Prop. 65 Components WARNING: This product can expose you to chemicals including nickel which is known to the State of California to cause cancer and hexavalent chromium compounds which are known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. SECTION XVI – OTHER INFORMATION Last Updated: January 24, 2019 NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. Prepared by CONTECH® Engineered Solutions www.ContechES.com End of SDS Page 1/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 55.2.3 1 Identification 2 Hazard(s) identification Classification of the substance or mixture The product is not classified, according to the Globally Harmonized System (GHS). Label elements GHS label elements Void Hazard pictograms Void Signal word Void Hazard statements Void Classification system: NFPA ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description:Mixture: consisting of the following components. Dangerous components: carbon7440-44-0 0.80-1.20% manganese7439-96-5 0.35-1.20% silicon7440-21-3 0.40-1.50% sulfur7704-34-9 <0.05% Nickel7440-02-0 <0.2% (Contd. on page 2) US Product identifier Trade name: AMASTEEL Details of the supplier of the safety data sheet Manufacturer/Supplier: Ervin Industries, Inc. 3893 Research Park Drive Ann Arbor, MI 48108-2217 Phone: (734)-769-4600/Fax: (734)-663-0136 sales@ervinindustries.com http://www.ervinindustries.com Information department: Quality Assurance Department (mo-thu: 8 a.m.-4 p.m., fr: 8 a.m. - 1 p.m.) Emergency telephone number: Phone: (734)-769-4600/Fax: (734)-663-0136 EUPCS: PC-TEC-12 Page 2/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 1) 55.2.3 7723-14-0 red phosphorus <0.05% 4 First-aid measures Description of first aid measures General information:No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. Consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. Use fire fighting measures that suit the environment. For safety reasons unsuitable extinguishing agents:Water Special hazards arising from the substance or mixture Product is not flammable. Fine metal dust removed as a waste stream and / or contamination during the blasting process, poses a small minor risk of causing a fire or explosion. Advice for firefighters Protective equipment:No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Scrap and debris can cause slip and fall hazards. It is recommended that floors and work areas be kept clean at all times. floors and work areas clean at all times. Environmental precautions:No special measures required. Methods and material for containment and cleaning up:Pick up mechanically. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. None None (Contd. on page 3) US Page 3/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 2) 55.2.3 Protective Action Criteria for Chemicals PAC-1: 7439-96-5 manganese 3 mg/m³ 7440-21-3 silicon 45 mg/m³ 7440-44-0 carbon 6 mg/m³ 7723-14-0 red phosphorus 0.27 mg/m³ 7440-02-0 Nickel 6 mg/m³ PAC-2: 7439-96-5 manganese 5 mg/m³ 7440-21-3 silicon 100 mg/m³ 7440-44-0 carbon 330 mg/m³ 7723-14-0 red phosphorus 3 mg/m³ 7440-02-0 Nickel 330 mg/m³ PAC-3: 7439-96-5 manganese 1,800 mg/m³ 7440-21-3 silicon 630 mg/m³ 7440-44-0 carbon 2,000 mg/m³ 7723-14-0 red phosphorus 18 mg/m³ 7440-02-0 Nickel 2,000 mg/m³ 7 Handling and storage Handling: Precautions for safe handling Take special care to prevent the product from leaking. Exercise special care when removing the tie-down straps that are part of the bulk pallet shipments. Information about protection against explosions and fires:No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:None. Storage class:13 Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. (Contd. on page 4) US Page 4/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 3) 55.2.3 7439-96-5 manganese PEL Ceiling limit value: 5 mg/m³ as Mn REL Short-term value: 3 mg/m³ Long-term value: 1 mg/m³ fume, as Mn TLV Long-term value: 0.02* 0.1** mg/m³ as Mn; A4, *respirable **inhalable fraction 7440-21-3 silicon PEL Long-term value: 15* 5** mg/m³ *total dust **respirable fraction REL Long-term value: 10* 5** mg/m³ *total dust **respirable fraction TLV TLV withdrawn Regulatory information PEL: Guide to Occupational Exposure Values (OSHA PELs) REL: Guide to Occupational Exposure Values (NIOSH RELs) TLV: Guide to Occupational Exposure Values (TLV) Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. Filter P2 Protection of hands:Leather gloves Material of gloves Recommended thickness of the material: - mm Penetration time of glove material Value for the permeation: Level - Eye protection:Safety glasses Body protection:Protective work clothing 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form:Solid Odor:Odorless Odor threshold:Not determined. pH-value:Not applicable. Change in condition Melting point/Melting range:1500 °C (2,732 °F) (~2700 °F) Boiling point/Boiling range:3000 °C (5,432 °F) (~5400 °F) Flash point:Not applicable. Flammability (solid, gaseous):Not determined. Decomposition temperature:Not determined. Auto igniting:Product is not selfigniting. Danger of explosion:Product does not present an explosion hazard. (Contd. on page 5) US Page 5/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 4) 55.2.3 Explosion limits: Lower:Not determined. Upper:Not determined. Vapor pressure:Not applicable. Density at 20 °C (68 °F):7.8 g/cm³ (65.09 lbs/gal) Relative density Not determined. Vapor density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water:Insoluble. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic:Not applicable. Kinematic:Not applicable. Solvent content: VOC content:0.00 % Solids content:100.0 % Other information No further relevant information available. 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin:No irritant effect. on the eye:No irritating effect. Sensitization: Examination nickel release in accordance with DIN EN 1811: 2012-10: done Sample Number 2016-00916 <0.1 g per cm2 and week therefore no sensitization detected Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. Carcinogenic categories IARC (International Agency for Research on Cancer) 7440-02-0 Nickel 1 (Contd. on page 6) US Page 6/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 5) 55.2.3 NTP (National Toxicology Program) 7440-02-0 Nickel R OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes:Not hazardous for water. Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. completely emptied packaging in 25kg paper bag: paper recycling completely emptied packaging in big bags: commercial waste disposal completely emptied packaging in steel barrels: metal recycling 14 Transport information UN-Number DOT, ADR, ADN, IMDG, IATA Void UN proper shipping name DOT, ADR, ADN, IMDG, IATA Void Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class Void Packing group DOT, ADR, IMDG, IATA Void Environmental hazards:Not applicable. Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. (Contd. on page 7) US Page 7/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 6) 55.2.3 UN "Model Regulation":Void 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): 7723-14-0 red phosphorus Section 313 (Specific toxic chemical listings): 7439-96-5 manganese 7723-14-0 red phosphorus TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Hazardous Air Pollutants 7439-96-5 manganese 7723-14-0 red phosphorus Proposition 65 Warning: This product can expose you to chemicals including Nickel, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov Chemicals known to cause cancer: 7440-02-0 Nickel Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Cancerogenity categories EPA (Environmental Protection Agency) 7439-96-5 manganese D 7723-14-0 red phosphorus D TLV (Threshold Limit Value) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. GHS label elements Void Hazard pictograms Void Signal word Void Hazard statements Void National regulations: Information about limitation of use:Employment restrictions concerning young persons must be observed. Water hazard class:Generally not hazardous for water. (Contd. on page 8) US Page 8/8 Safety Data Sheet acc. to OSHA HCS Printing date 01/15/2023 Reviewed on 05/11/2022 Trade name: Amasteel (Contd. of page 7) 55.2.3 Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Motivo da mudança: Version 2: 28.05.2015: Section 5.1 Extinguishing agents; 8.1 AGW measuring method. Version 3: 06.09.2015: Section 1, 15, adaptation to the regulation 453/2015/EC, 830/2015/EU, 18/2012/EU Version 4: 05.03.2016: Section 1.3 Version 5: 19.06.2016: Section 13 Version 6: 07.06.2019: Section 3, 8 Version 7: 16.02.2020: Section 13 Version 8: 18.02.2021: Section 1, 13, 15 Version 9: 11.05.2022: Section 2, 8, 15 Contact:Dr. W. Assmann Date of preparation / last revision 01/15/2023 Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit * Data compared to the previous version altered.Amasteel Safety Data Sheet:AMASTEEL US Department of Environmental Quality Alan Matheson Executive Director GARY R. HERBERT Governor SPENCER J. COX Lieutenant Governor DIVISION OF AIR QUALITY Biyce C. Bird Director Small Source Registration DAQE-EN159540001-18 September 21, 2018 Mike Delesandri EDSCO Fasteners LLC 2200 Worthington Drive Denton, TX 76207 Dear Mr. Delesandri: DAQ-2018-015929 Re: Request for Evaluation of Compliance with Rule R307-401-9, UAC: Small Source Exemption Project Fee Code: N15954-0001 On August 10, 2018, the Division of Air Quality (DAQ) received your request for a small source exemption for EDSCO Fasteners LLC - Fastener Manufacturing Plant. The source is located at 1350 Calpac Avenue, Spanish Fork, Utah County. DAQ has determined the small source exemption applies to the source as long as the equipment and associated processes operate as specified in the registration request. The small source exemption does not exempt a source from complying with other applicable federal, state, and local regulations and the current Utah Administrative Code. Based on the emissions you submitted to DAQ with your registration request, EDSCO Fasteners LLC Fastener Manufacturing Plant is not required to obtain an approval order under R307-401. If you change your operation such that there is an increase in emissions, we recommend you notify us, as an approval order may be required. As authorized by the Utah Legislature, the fee for issuing this small source exemption is a one-time filing fee in addition to the actual time spent by the review engineer and all other staff on the project. Payment should be sent to DAQ upon receipt of the invoice. 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper DAQE-EN159540001-18 Page 2 Thank you for registering your source with the DAQ. If you have any additional questions, please contact Mr. Enqiang He at (801) 536-4010. Sincerely, Bryce C. Bird Director aL, Alan D. Humpherys, Manager New Source Review Section BCB:ADH:EH:sa Attachments: Small Source Exemption Registration Request and attached forms '1 SITE ID # AND PROJECT #: COMPANY NAME: REGARDING: NI 59540001-18 EDSCO Fasteners, LLC-Fastener Manufacturing Plant Request for Evaluation of Compliance -Small Source Exemption THE ATTACHED DOCUMENT IS CATEGORIZED AS: (PLEASE CHOOSE ONE) NEWSPAPER NOTICE (NN) Office Tech signs cover letter of Newspaper Notice INTENT TO APPROVE (!TA) Cover letter and IT A signed by associated Section Manager Office Tech Attached PDF into TEMPO APPROVAL ORDER (AO) Copy of purple sheet and cover letter of AO to Teri Weiss EXPERIMENT AL AO Copy of purple sheet and cover letter of AO to Teri Weiss CORRESPONDENCE Signatory varies SOIL REMEDIATION If associated fee, send copy of purple sheet and letter to Teri Weiss SALES TAX EXEMPTION (TAX) ~MA[C SOURCEcXEMPTf(!~ Copy of purple sheet and letter to Teri Weiss EMISSIONS BANKING LETTER Copy of letter to Catherine Wyffies NAME CHANGE Copy of purple sheet and letter to Teri Weiss COPIES TO BE SENT TO THE FOLLOWING PARTIES: (PLEASE CHECK AS THEY APPLY) Manilafi e Folder (w_o · g file) ~s Folder J Health Department (see letter for which) EPA -Patrick Wauters Compliance (associated Section Manager) Finance -Teri Weiss Name Change Letters: Brett Wilding, Utah State Tax Commission, Technical Research Unit Catherine Williams Susan Weisenberg Dave Beatty Offsets Used? Enter final Name Change Letters in /engineer/aoname Copy of document(s) to Catherine Wyffles Copy To: Enter in /engineer/aocond & in AO Log: (AOs, AO not needed, Replacement in Kind) NEWSPAPER NOTICE-COPIES TO: PSD PROJECTS: Cities, Counties, Gov. Agencies, & etc./& a copy of Copy the NOi, Engineering Review, IT A, NOTICE & AO Public Official letter with self-addressed envelope Send to: E-Mail To: dvd.kvd@juno.com, Jodie Swanson, Lori Patrick Wauters, EPA Walker, Debbie Obemdorfer, Bill Sinclair, Beverly Don Banks, Bureau of Land Management Rasmussen & Jen Burge, Donna Spangler, and Kelly Chris Hocket, U.S. Forest Service Beck Chris Shaver, National Park Service E-Mail COQi'. & Fax to Newsgager Agencies TITLE V: Check w/ SR Engineer for which document(s) to be copied. REVIEWED BY AND DOCUMENT SIGN OFF DATES: Completeness determination Peer review of project Section Manager sign off September 19, 2018 September 19, 2018 ,..r.,.d// q w }0..-f'l UOK Enqtang e Ana Williams Alan Humpherys AARC ENVIRONMENTAL, INC. E o ,; I r o n m t ·n l a I 1 n c Environmental, Occupational Health & Safety Solutions UTAH DEPARTMENT OF ENVIRONME NTAL QUALITY AUG 1 0 2018 DIVISION OF AIR QUALITY AIR SMALL SOURCE EXEMPTION REGISTRATION EDSCO FASTENERS, LLC. EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 SPANISH FORK, TX JULY 2018 Prepared for: EDSCO Fasteners, LLC. 1350 Calpac Avenue, Span ish Fork, UT 84660 Submitted to: Utah Department of Environmental Quality Permits, Division of Air Quality POB 144820 Salt Lake City, Utah 84114 AARC Project No: 90-E-7143-91 AARC Environmental, Inc. © 1994 -2018 TABLE OF CONTENTS SECTION PAGE INTRODUCTION ............................................................................................................................................. l SMALL SOURCE EXEMPTION REGISTRATION FORM ..................................................................................... 2 ATIACHMENT-PROCESS FLOW DIAGRAM .................................................................................................. 5 ATIACHMENT -PROCESS DESCRIPTION ....................................................................................................... 7 ATIACHMENT -EMISSIONS CALCULATIONS ................................................................................................. 8 ATIACHMENT-MAP ................................................................................................................................... 12 APPENDIX A: FEDERAL REGULATORY REQUIREMENTS ............................................................................... 14 APPENDIX B: SPECIFICATIONS ..................................................................................................................... 15 EDSCO Fasteners, LLC. • Spanish Fork, UT July 2018 ii AARC Environmental, Inc. © 1994 -2018 INTRODUCTION EDSCO Fasteners, LLC -Spanish Fork, UT (EDSCO) is a manufacturer of anchor bolts and fasteners for large steel structures. The facility engages in cutting, sawing, welding of metals and is currently intends to install a zinc galvanizing process at the site, which involves natural gas burner and zinc galvanizing kettle. The facility is seeking to register these operations in accordance with UAC R307-401-9: Small Source Exemption Registration. EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 1 AARC Environmental, Inc. © 1994 -2018 SMALL SOURCE EXEMPTION REGISTRATION FORM EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 2 AARC Environmental, Inc. © 1994-2018 Utah Division of Air Quality Revised: 6121106 SMALL SOURCE EXEMPTION REGISTRATION Businesses eligible for this exemption shall not: 1) emit more than 5 tons per year of each of the following pollutants: sulfur dioxide (S02), carbon monoxide (CO), nitrogen oxides (NOx), particulate matter (PM10), ozone (03), or volatile organic compounds (VOCs) or 2) emit more than 500 pounds per year of any single hazardous air pollutant (HAP), and emit more than 2000 pounds per year for any combination of HAPs, or 3) emit less than 500 pounds per year of any air contaminant not listed in (1)( or (2) above and less than 2000 pounds per year of any combination of air contaminants not listed in (1) or (2) above. Please keep copies of the registration notice and worksheets on site at your business to verify your permit exemption status. Please be aware that the small source exemption only exempts your business from the permitting requirements of R307-401-5 through 8 of the Utah Administrative Code, not other applicable air quality regulations. 1. Business Name and Mailing Address: 2. Business Contact for Air Quality Issues: EDSCO Fasteners, LLC. AARC Environmental. Inc. Mr. Mike Delesandri Mr. Venkata Godasi 2200 Worthington Drive, 2 Riverwa)l, Suite# 1780. Denton. TX 76207 Houston. TX 77056 Phone # (940) 380-8000 Phone# (713) 974-2272 Email: MDelesandri@edsco.com Email: vgodasi@aarcenv.com 3. Owners Name and Mailing Address: 4. Business Location (street address if EDSCO Fasteners, LLC. different from above and directions to site): Mr. Mike Delesandri 1350 Caleac Avenue, 2200 Worthington Drive, Seanish Fork, UT 84660 Denton, TX 76207 Phone # (940) 380-8000 Email: MDelesandri@edsco.com 5. County where business is located: 6. Start-up Date of Business: Utah Month: Janua!Y Year: 2011 7. Briefly describe your process by describing end products, raw materials, and process equipment used at your business. Attach additional sheets if necessary. Please refer the application document for process description and process flow diagram 8. List any pollution control equipment: ~N=o=n=e~----------------- 9. Typical operating Schedule: Monday through Friday - 8 am to 5 pm 10. Annual Emission Rates: Provide an estimate of the actual annual emissions of the following air contaminants from your business. Emission calculation worksheets are available for some common processes. Please attach all worksheets and calculations. Sulfur Dioxide (S02}... .. 1.22 lbs/ year Particulate Matter (PM10} ............. 1,962.4 lbs / year Carbon Monoxide (CO) 171.3 lbs / year Ozone (03) ............................. . ___ lbs / year Nitrogen Oxides (Nox) 203.9 lbs / year Volatile Organic Compounds (VOC) 11.2 lbs/ year Other Air Contaminants ___ lbs/ year Describe _______________ _ HAZARDOUS AIR POLLUTANTS: Complete Attachment C before selecting one of the following emission estimate ranges. For an individual hazardous air pollutant: 0 -250 lbs/year: X 250-350 lbs/year: ___ _ 350-500 lbs/year: ___ _ For a combination of hazardous air pollutants: 0-1000 lbs/year: X 1000-1500 lbs/year: ____ _ 1500-2000 lbs/year: ___ _ 11. [gJ By checking this box, I hereby certify that the information and data submitted in this notice fully describes this site and only this site and is true, accurate, and complete, based on reasonable inquiry and to the best of my knowledge. I recognize that falsification of the information and data submitted in this notice is a violation of R 19-2-115, Utah Administrative Code. [gJ By checking this box, I understand that I am responsible for determining whether I remain eligible for this exemption before making operational or process changes in the future and :~::p:~o~.otify the Divisi:,(::;;r ::ty d]n this business is no longer eligible for this Signature of Owner/Manager: ?'bill~' Title: Director of Business 7 Print Name: Mr. MIKE DELESANDRI Phone#: {940) 380-8000 Date: &'~.//~ Small Source Applicable Yes..i,L' No_---------------------- n ATIACHMENT-PROCESS FLOW DIAGRAM EDSCO Fasteners, LLC. • Spanish Fork, UT July 2018 5 AARC Environmental, Inc. © 1994 ·2018 Raw Material~ I Welding /Hand- = -= = --=>I held Equipment Legend ==> Process Line ' Material Supply t Air Emissions ...__..r-e Heat • Waste Steams Bolts/Fasteners ~========= EDSCO Fasteners, LLC. -Spanish Fork, UT Process Flow Diagram Blast Cabinets POC Bolts/Fasteners Zinc Ingots/ Filters POf Burner #2 39 PM Hot Galvanizing Kettle Zinc Galvanized Products ================> Zinc Ingots Stored/Shipped Used Materials/Filters AARC Environmental, Inc. Environmental Inc EDSCO Fasteners, LLC. -Spanish Fork, UT TCEQ Air -Small Source Exemption Registration July, 2018 ATTACHMENT-PROCESS DESCRIPTION EDSCO Fasteners, LLC -Spanish Fork, UT (EDSCO) is a manufacturer of anchor bolts and fasteners for large steel structures. The facility engages in cutting, sawing, welding of metals and is currently intends to install a zinc galvanizing process at the site, which involves natural gas burners and zinc galvanizing kettle. The facility is seeking to register these operations in accordance with UAC R307-401-9: Small Source Exemption Registration. PROCESS Facility receives various raw materials via trucks and stored in designated area. The materials are processed to hand-held machines to manufacture anchor bolts and fasteners for use in large steel structures. The bolts and fasteners are then processed through small enclosed blast cabinets with dust collectors. The bolts and fasteners are then processed to dip in galvanizing kettle. The galvanizing kettle uses atleast 99 .995% zinc ingots. The bolts and fasteners are dipped into hot galvanizing kettle for zinc coating. The maximum rated capacity of the kettle is 3,600 pounds. The kettle is equipped with two burners for melting zinc ingots. Each of the burners is rated at the capacity of 0.50 MM BTU/hr and uses natural gas as fuel. The zinc galvanized products are then packed and stored/shipped. The facility is seeking small source exemption registration since the actual emissions are 1) less than 5 tpy of each of the following pollutants: sulfur dioxide (502), carbon monoxide (CO), nitrogen oxides (NOx), particulate matter (PMlO), ozone (03), or volatile organic compounds (VOCs) and 2) less than 500 pounds per year of single HAP and less than 2000 pounds per year of any air combination of HAPs and less than 500 pounds per year of any air contaminant not listed in (1)( or (2) above and less than 2000 pounds per year of any combination of air contaminants not listed in (1) or (2) above. EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 7 AARC Environmental, Inc. © 1994 -2018 ATTACHMENT -EMISSIONS CALCULATIONS EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 8 AARC Environmental, Inc. © 1994-2018 Table G-1 EDSCO Fasteners, LLC. -Spanish Fork, UT Emissions from Zinc Galvanizing Kettle Parameters HP Maximum Hourly Production in Pounds/Hour of Galvanized Product (lbs/hr) AH Maximum Annual Operating Hours Per Year (hrs/yr) AP Maximum Annual Production in Tons/Year of Galvanized Product (tpy) EF Zinc Kettle Emission Factor (lbs/hr) EH Hourly Uncontrolled PMlO Emissions (lbs/hr)* EA Annual Uncontrolled PMlO Emissions (tpy)** Notes: * Emissions from Hot-Dip Galvanizing Process -Final Report EPA-905/4-76-002 -Page 5 Summary EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 9 Data 3,600 2080 3,744 0.52 0.94 ., 0.97/ Units lbs/hr hrs/yr tpy lbs/ton lbs/hr tpy ) Information Source Rated Capacity of Kettle 8 hours/day* 5 days/week * 52 weeks/year Based annual operating hours EPA-905/4-76-002 * EDSCO Fasteners, LLC. -Spanish Fork, UT EDSCO Fasteners, LLC. -Spanish Fork, UT AARC Environmental, Inc. © 1994 -2018 Equipement Name Pollutant Burners (0.50+0.SO) MMBTU/hr) EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 PM co S02 NOx voe Emission Factor lb/10"6 sd 7.6 84 0.6 100 5.5 Table G-2 EDSCO Fasteners, LLC. -Spanish Fork, UT Emissions from Burners Rated Capacity Heat Content Fuel Usage 10"6 BTU/hr 10"6 BTU/ 10"6 scf 10"6 scf / hr 1.00 1020 0.0010 1.00 1020 0.0010 1.00 1020 0.0010 1.00 1020 0.0010 1.00 1020 0.0010 10 Emissions Operating Hours lbs/hr hrs/yr 0.01 2080 0.08 2080 0.001 2080 0.10 2080 0.01 2080 Annual Emissions tpy 0.01 0.09 0.001 0.10 0.01 AARC Environmental, Inc. © 1994-2018 Source Galvanizing Kettle ----------- EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 Burners TOTAL* PM-10 (tpy) 0.97 -------- 0.01 0.98 Table G-3 EDSCO Fasteners, LLC. -Spanish Fork, UT Summary of Emissions from Facility Maximum Annual Emissions PM-2.5 co s~~/ ,, (tpy) (tpy) _,.../(tpy) / ,,., 0.97 --_.,. ,· ------------:r-----------/ 0.01 /0.09 0.001 , 0.98 .,. 0.09 0.001 ; ./,,. 4~·r ./ 'h :) II / {)) t--·~· I', 11 .,,.,..,, / / NOx voe (tpy) (tpy) -- ---------------- 0.10 0.01 0.10 0.01 AARC Environmental, Inc. © 1994 -2018 EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 ATIACHMENT-MAP 12 AARC Environmental, Inc. © 1994-2018 EDSCO Fastners, LLC 1350 Ca/pac A venue, Spanish Fork, UT 84660 ~ Prepared By: ©1994 -2018 AARC Environmental~ Inc . Efl'<lronmontlll,01:cup11tlDNilHea1tn&SalcLySOlutloos Lat: 40° 05' 26.85" N Long: 111° 39' 30.47" W O' 100' 400' ~ 200' Image Source: Google Earth Imagery Date: 06/17/2017 Date: 07/30/2018 I Visit By NIA Rev1s1on: NIA Drawn By: VG Dwg. Type: Air Map l ] APPENDIX A: FEDERAL REGULATORY REQUIREMENTS A. New Source Performance Standard (40 CFR Part 60 -NSPS) The facility's operations as described in this application are not subject to any subpart of the New Source Performance Standards (NSPS) listed in 40 CFR Part 60. B. National Emission Standard for Hazardous Air Pollutants (40 CFR Part 61-NESHAP) The facility's operations as described in this application are not subject to any subpart of National Emission Standard for Hazardous Air Pollutants (NESHAP) listed in 40 CFR Part 61. C. Maximum Achievable Control Technology (40 CFR Part 63 -MACT) The facility's operations as described in this application are not subject to any subpart of Maximum Achievable Control Technology (MACT) listed in 40 CFR Part 63. EDSCO Fasteners, LLC. • Spanish Fork, UT July 2018 14 AARC Environmental, Inc. © 1994 -2018 """ EDSCO Fasteners, LLC. -Spanish Fork, UT July 2018 APPENDIX 8: SPECIFICATIONS 15 AARC Environmental, Inc. © 1994-2018 I Jan 2017 ny"rstar Uses Zinc ingo1s of high purity for tube. wire, sheet or general galvarnzing. Nyrstar A-Z Z1 (99.995%) is an LME-and SHFE-approved brand, conforming to the specifications covering quality. shape and weigl1t as defined by the special contr·act rules of the LME and SHFE Standards .. Chemical specification .yJ. 2:;) __ -.... ~ -., ... . . . . ... ' ..... , . . ., . ~ : :. -"' ....... ·, ~~: ,i, _. _ . Ch~mical specifi~tion Pb Cd Fe Sn Cu Al Total of 6 elements above Z11. rrnn. Standards Guaranteed analysis ~ :. .. ... ~ . :-;: 0.003"!., s 0.003°/., :5 0.002% s 0.001 % :50.001% :5 0.001% :5 0.005% 99.995% Typical SHG analysis (2Q16) 0.0021% 0.0005% 0.0003'.,;, <0.0004'!·c 0.0002% 0.0002% <0.0038%, .;15.., • .: ..... ~ ..... -..-, • ' • -... ' ;, /, ... • .. • ." standard r ... • • ~ • ",, • .-• ~· , • • • • ~ "":~ . .... ,,. . Grade · .. lntemational lS0 752:2004 China GB;T 470:2008 European EN 1179:2003 Japanese JIS H2107-1957 Ame1icc1n ASTM 86:07 rUNS) Physical data ZN-1 Zn99.995 Z1 . . H1gl1est Pure Zinc Metal LME (Z1 2002) ~=,. .. .:;v,-~ •••• ~ ...... • ,. ..... """•·''"<· , .. ,,: ....... ~ •••....... ,,. ... )7.• '""""' •) .... ""'•. ~:... ... Physical property I Density solid liquid (@419 '-C J t,lelting point Superficial tension(@ 450"C1 Mel ting enthalpy Thermal capacity solid liquid Available shapes/package ..;-~ ... .. Shape/package Slc1h Slab bundle (40 slabs per bundle: L bloc!< ~block .. ' kg!drn2 kg!cim? 'C Nim kJ:kg J/kg f< J,kg f{ Nominal weight (in kg) 2fi 1040 1135:: 45 1089 .:. 30 7.14 6.62 419 0.78 iOO 460 628 i Dimensions (in mm) - 480 ){ 240 X 39 860 X 480 X 430 1820 :< 455 x 260 14 i O X .160 X 290 .. .•. ~ ~ -· Nyrstar Sales & Marketing AG • Tessinerplatz 7 • CH-8002 Zurich (Switzerland)· T +41 44 745 81 00 • F ~4 1 44 745 81 10 sales@nvrstar.com • www.nvrstar.com . _,. ,,. I Jan 2017 n}rstar Nominal mass 26 kg Dimensions 480 x 240 x 39 Slab bundle {40 slabs per bundle) [ Nominal mass -J 040kg ·--·------------·----------------·---··-··---·--------·--------Dimensions 960 x 480 x 430 Nyrstar Sales & Marketing AG • Tessinerplatz 7 • CH-8002 Zurich (Switzerland} • T +41 44 745 81 oo • F +41 44 745 81 1 o sales@nyrstar.com • www.nyrstar.com I Jan2017 I n}rstar L block (jumbo} Nominal mass 1135 ± 45kg Dimensions 1820 x 455 x 260 ---------------------------------------------------·-------------------·------------------·---- 455 .. Top Diameter 100mm Bottom Diameter 130mm 490 1790 630 . " .. G block (jumbo) Top Diameter 105mm . Bottom Diameter 145mm 460 ;, .. · 470 1350 960 ... ... 1820 t 430 ·65 ' .. 195 Nominal mass 1089 ± 30kg Dimensions 1410 x 460 x 290 1410 290 40S Nyrstar Sales & Marketing AG • Tessinerplatz 7 • CH-8002 Zurich (Switzerland)· T +41 44 745 81 00 • F +4 1 44 745 81 10 sales@nvrstar.com • www.nvrstar.com EMISSIONS FROM HOT-DIP GALVANIZING PROCESSES FINAL REPORT EPA -905/4-76-002 by Peter J. Drivas Pacific Environmental Services, Inc. 1930 14th Street Santa Monica, Ca11forn~a 90404 213-393-9449 Contra.ct No. 68-01-3156 Task Order No. 7 Projec_t Offf cer: Wflliam E. Beyer U.S. Environmental . P~.~ect1on· ~gency Region V 230 South Dearborn Street Chicago, I111nofs 60604 .... 2. SUMMARY, CO NCLUSIONS, AND RECOMME NDATIONS A comprehensive literature search was performed to locate and identify all sources· of information on emissions from hot-dip galvanizing proces .ses. O~servat ions of current galvanizing practices, procedures, and equipment were made in a total of five plant visits -two in the Los Angeles area and three in the Chicago area. To detennine accurate emissions of particulates from current galvanizing operations, the PES staff perfonned three separate source tests, us ing EPA Method 5, on one galvanizing plant in the Los Angeles area. Particulate emission data from a total of seventeen source tests on hot-dip galvanizing plants were considered relevant in developing an emission factor for galvanizing kettles. Fourteen of the source tests measured both kettle emissions and emissions from control devices; the control devices tested were mainly water scrubbers and baghouses. There was no significant differe.nce between the kettle and control device emissions. An averaged emission factor based on galvanized product process wefght was calculated, considering both kettle and control device emfssfons as one data base: Em1ss1on factor = 0.26 kg/metric ton ·ga 1van1zed product (a=0.28) <fcf.'s2 lb/short ton galvanfze-ct-prcidu~) . ·-________ · -------- or, assuming 8% zfnc by weight in the galvanized product. Emission factor • 3.3 leg/metric ton of zinc used (c,.• 3.5) ~~6 lb/short ~fnc · used) It 1s recomnended that an emission factor 1n terms of process weight be defined per weight of galvanized product, since only this quantity is nonnally measured by galvanfzfng ·plants. -5- ~ .a -.r 0 ( '1 1 r. C Ill & •'J O'J (1 -' -r \'. : I'" ' f. [ r, 8/17/2018 ·- Small Source Exemption (SSE) request 1 message Enqiang He <ehe@utah.gov> To: mdelesandri@edsco.com Cc: vgodasi@aarcenv.com Dear Mike, State of Utah Mail -Small Source Exemption (SSE) request Enqiang He <ehe@utah.gov> Fri, Aug 17, 2018 at 6:43 PM The Utah Division of Air Quality has received your SSE request for your facility at 1350 Calpac Avenue, Spanish Fork, UT 84660. I was assigned to review your application. Emission thresholds that qualify a facility to be a small source should include all emission points in a source. In your case, we also would like to see any emissions from operations such as cutting, sawing, blasting, and welding processes. ·Please provide these emissions ASAP but no later than two I weeks from today. Let me know if you have any questions. Thanks. https://mail.google.com/mail/u/2/?ui=2&ik=20ff41 d2e4&jsver=Q_ d 13qeAqJE.en.&cbl=gmail_fe _ 180813.12_p2&view=pt&search=sent&th=1654a 7ce29ec52e3&siml= 1654a 7 ce29ec52e3 1 /2 8/17/2018 EQ He Minor NSR Section Permitting Branch State of Utah Mail -Small Source Exemption (SSE) request Utah Division of Air Quality (801) 536-4010 https://mail.google.com/mail/u/2/?ui=2&ik=20ff41 d2e4&jsver=Q_d1 3qeAqJE.en .&cbl=gmail_fe_ 180813.12_p2&view=pt&search=sent&th=1654a 7 ce29ec52e3&siml=1654a 7 ce29ec52e3 2/2 Source Galvanizing Kettle EDSCO Fasteners, LLC. -Spanish Fork, UT August 2018 Burners Blast Cabinets Cutting Stations TOTAL* PM-10 (tpy) 0.97 0.01 1.44 0.80 3.22 Table G-3 EDSCO Fasteners, LLC. -Spanish Fork, UT Summary of Emissions from Facility Maximum Annual Emissions PM-2.5 co S02 (tpy) (tpy) (tpy) / 0.97 / . . I 0.01 / 0.09 0.001 I / I 1.44 ./ . . I 0.80 / / I 3.22 I 0.09 0.001 10 NOx (tpy) . 0.10 . 0.10 voe (tpy) . 0.01 . 0.01 AARC Environmental, Inc. © 1994 · 2018 Table G-3 EDSCO Fasteners, LLC. -Spanish Fork, UT Hourly & Annual Emissions from Abrasive Blasting in Blast Cabinets Parameters Maximum Hourly Abrasive Consumption Rate Maximum Annual Operating Hours Per Year (hrs/yr) Maximum Annual Abrasive Consumption Rate Control Device TPM Emission Factor Number of Blast Cabinets Pollutant PM Pollutant PM Notes: Hourly Usage (lbs/hr) 1,000 Annual Usage (lbs/yr) 2,080,000 For worst case-scenario PM = PMlO = PM2.5 EDSCO Fasteners, LLC. -Spanish Fork, UT August 2018 Data 1,000 2,080 2,080,000 Dust Collector -\_ 0.69 ' 2 Emission Factor (lb/1,000 lb) / 0.69 I Emission Factor (lb/1,000 lb) 0.69 Units lbs/hr hrs/yr lbs/yr lb/1000 lb abrasive Number of Blast Cabinets - 2 Unit Conversion (lb/ton) 2,000 10 Information Source EDSCO Fasteners, LLC. -Spanish Fork, UT 8 hours/day * 5 days/week * 52 weeks/year EDSCO Fasteners, LLC. -Spanish Fork, UT EDSCO Fasteners, LLC. -Spanish Fork, UT EPA AP 42 Table 13.2.6-1 EDSCO Fasteners, LLC. -Spanish Fork, UT Hourly Emissions (lb/hr) 1.38 Number of Blast Cabinets Annual Emissions - 2 , (tpy) / 1.44 / AARC Environmental, Inc. © 1994 -2018 Table G-4 EDSCO Fasteners, LLC. -Spanish Fork, UT Hourly & Annual Emissions from Abrasive Blasting in Blast Cabinets Parameters Maximum Hourly Material Process Rate (Worst-Case Scenario) Maximum Annual Operating Hours Per Year (hrs/yr) Maximum Annual Material Process Rate TPM Emission Factor Number of Cutting Stations Hourly Process Rate Pollutant (tons/hr) PM 4 Annual Process Rate Pollutant (tons/hr) PM 8,320 Notes: Data 4 2,080 8,320 0.032 6 Emission Factor (lb/ton) 0.032 Emission Factor (lb/ton) 0.032 Units Information Source tons/hr EDSCO Fasteners, LLC. -Spanish Fork, UT hrs/yr 8 hours/day * 5 days/week * 52 weeks/year tons/yr EDSCO Fasteners, LLC. -Spanish Fork, UT lb/ton EPA AP 42 Table 12.5.1-1 EDSCO Fasteners, LLC. -Spanish Fork, UT Number of Cutting Stations Hourly Emissions . (lb/hr) 6 0.77 Unit Conversion Number of Cutting Stations Annual Emissions (lb/ton) . (tpy) 2,000 6 0.80 / No emission factor are readily available for metal cutting operations; hence emission factor for billet cutting torches from EPA AP 42 Table 12.5.1-1 are used for worst case scenario For worst case-scenario PM = PMlO = PM2.5 EDSCO Fasteners, LLC. - Spanish Fork, UT August 2018 10 AARC Environmental, Inc. © 1994 -2018