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HomeMy WebLinkAboutDAQ-2025-000190 DAQE-AN161390002-25 {{$d1 }} William Kaiser Savage Services Corporation 901 West Legacy Center Way Midvale, UT 84047 WilliamKaiser@savageservices.com Dear Mr. Kaiser: Re: Approval Order: New Cedar City Liquid and Dry Bulk Transloading Facility Project Number: N161390002 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on August 2, 2024. Savage Services Corporation must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Christine Bodell, who can be contacted at (385) 290-2690 or cbodell@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. No public comments were received on this action. Sincerely, {{$s }} Bryce C. Bird Director BCB:CB:jg cc: Southwest Utah Public Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director January 8, 2025 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN161390002-25 New Cedar City Liquid and Dry Bulk Transloading Facility Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Savage Services Corporation - Cedar City Transloading Facility Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality January 8, 2025 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 6 PERMIT HISTORY ................................................................................................................... 10 ACRONYMS ............................................................................................................................... 11 DAQE-AN161390002-25 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Savage Services Corporation Savage Services Corporation - Cedar City Transloading Facility Mailing Address Physical Address 901 West Legacy Center Way 6635 West Sage Hills Drive Midvale, UT 84047 Cedar City, UT 84721 Source Contact UTM Coordinates Name: William Kaiser 306,873 m Easting Phone: (801) 424-7272 4,178,315 m Northing Email: WilliamKaiser@savageservices.com Datum NAD83 UTM Zone 12 SIC code 5171 (Petroleum Bulk Stations & Terminals) SOURCE INFORMATION General Description Savage Services Corporation (Savage) conducts transloading operations between railcars and trucks for various petroleum liquids and other organic liquids, inorganic liquids, and dry bulk goods. Equipment for the liquid transloading operation includes liquid transfer and vapor return lines. Equipment for dry transloading operations includes enclosed pneumatic systems or enclosed conveyors equipped with dust collectors and diesel-fired, Tier 4i engines to power the pneumatic system or conveyor movements. Savage will also store bulk lump gypsum on site, which will be controlled with water sprays. NSR Classification New Minor Source Source Classification Located in Attainment Area Iron County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), XXa-Standards of Performance for Bulk Gasoline Terminals that Commenced Construction, Modification, or Reconstruction After June 10, 2022 NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions DAQE-AN161390002-25 Page 4 MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines MACT (Part 63), BBBBBB: National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Title V (Part 70) Area Source Project Description Savage has requested a new AO for the Savage Transloading Facility located in Cedar City, Iron County. The source has historically operated under Utah Administrative Code (UAC) R307-401-9 "Small Source Exemption" (see AO DAQE-EN161390001-23, issued September 21, 2023), and is increasing site throughputs and operations and will now require an AO. Two major types of products are transloaded at the source, including liquids and dry bulk goods. Savage has requested to transload petroleum liquids, other organic liquids, and inorganic liquids using liquid transfer lines and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. In addition to the transloading of liquids, Savage will load and unload bulk solid materials such as minerals and grain. The equipment involved in the source's dry bulk goods transloading process includes a total of four (4) covered pneumatic systems or conveyor belts and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. Four (4) Tier 4i diesel engines power the movement of the pneumatic systems or conveyors. The pneumatic systems and conveyors will each be equipped with a baghouse filter with an estimated control efficiency of 99% Requested throughput includes 90 million gallons of unpressurized liquids per year and 12 million gallons of pressurized liquids per year. Additionally, Savage has requested a throughput of 375,000 tons per year of bulk solid materials, including grains and minerals such as gypsum. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 1187.00 Carbon Monoxide 7.60 Nitrogen Oxides 6.17 Particulate Matter - PM10 0.55 Particulate Matter - PM2.5 0.42 Sulfur Dioxide 0.01 Volatile Organic Compounds 7.90 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 260 Generic HAPs (CAS #GHAPS) 280 Naphthalene (CAS #91203) 220 Toluene (CAS #108883) 1020 DAQE-AN161390002-25 Page 5 Xylenes (Isomers And Mixture) (CAS #1330207) 320 Change (TPY) Total (TPY) Total HAPs 1.05 SECTION I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Cedar City Transloading Facility II.A.2 Liquid Transfer Lines Includes vapor balance lines and a pressure relief line DAQE-AN161390002-25 Page 6 II.A.3 Four (4) Enclosed Mobile Conveyor Belts *Or four (4) enclosed pneumatic systems* Control: Dust Collector II.A.4 Four (4) Mobile Conveyor Engines Rating: 48 hp (36 kW), each Tier: 4f Fuel: Diesel NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.5 Two (2) Storage Silos Capacities: 140-ton and 195-ton Content: Fly Ash SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a Unless otherwise specified in this AO, the owner/operator shall not allow visible emissions to exceed 10% opacity. [R307-401-8] II.B.1.a.1 Unless otherwise specified in this AO, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Method 9. [R307-401-8] II.B.2 Liquid Loading Requirements II.B.2.a The owner/operator shall not exceed the following organic liquid throughputs: A. 45,000,000 gallons of (unpressurized) low-vapor organic liquids that have an absolute vapor pressure of 0.05 psia or less per rolling 12-month period B. 22,500,000 gallons of (unpressurized) gasoline per rolling 12-month period C. 22,500,000 gallons of (unpressurized) ethanol per rolling 12-month period D. 12,000,000 gallons combined of (pressurized) propane, butane, or liquified petroleum gas (LPG) per rolling 12-month period. [R307-401-8] DAQE-AN161390002-25 Page 7 II.B.2.a.1 The owner/operator shall: A. Maintain records of each organic liquid type (low vapor pressure liquid, gasoline, ethanol, LPG, propane, butane) and the absolute vapor pressure of each organic liquid B. Determine throughput with supervisor monitoring and maintaining an operation log C Record throughput on a daily basis D. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months E. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.2.b The owner/operator shall only load the organic liquids to the rail cars on site directly from the tanker trucks or vice versa. [R307-401-8] II.B.2.c The owner/operator shall load the rail cars and tanker trucks on site by the use of bottom filling or a submerged fill pipe when loading unpressurized organic liquids. [R307-401-8] II.B.2.d The owner/operator shall connect a vapor balance line to the receiving and delivery vessels prior to venting to the atmosphere during on-site loading operations for the unpressurized organic liquids. The vapor balance line shall be used at all times during loading operations when conducting unpressurized organic liquid loading operations. [R307-401-8] II.B.2.e The owner/operator shall operate each vapor balance system according to the manufacturer's recommendations. [R307-401-8] II.B.2.e.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's recommendations for each installed vapor balance system. [R307-401-8] II.B.2.f The owner/operator shall only load propane, butane, or LPG under pressure. [R307-401-8] II.B.2.g The owner/operator shall only transload the organic liquids to tanker trucks and rail cars that are certified for the NSPS level annual leak test. [R307-401-8] II.B.2.g.1 To determine compliance with the above condition, the owner/operator shall maintain records of annual leak test certifications. [R307-401-8] II.B.3 Bulk Solids Transloading Requirements II.B.3.a The owner/operator shall not transfer more than 375,000 tons of dry bulk solids (minerals, fly ash, and grains) per rolling 12-month period. [R307-401-8] II.B.3.a.1 The owner/operator shall: A. Determine throughput with supervisor monitoring and maintaining an operation log B Record throughput on a daily basis C. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the throughput records for all periods the plant is in operation. [R307-401-8] DAQE-AN161390002-25 Page 8 II.B.3.b The owner/operator shall install a dust collector on each dry bulk goods conveyor or pneumatic system to control particulate emissions generated during the transfer of dry bulk goods. All displaced air from the dry bulk goods transferring operations shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.c The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across each dust collector. [R307-401-8] II.B.3.c.1 The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.c.2 The pressure gauge shall measure the static pressure differential in 1-inch water column increments or less. [R307-401-8] II.B.3.d During operation of each dust collector, the owner/operator shall maintain the static pressure differential within the range recommended by the manufacturer for normal operations. [R307-401-8] II.B.3.d.1 The owner/operator shall record the static pressure differential at least once per operating day while each dust collector is operating. [R307-401-8] II.B.3.d.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit; C. Daily static pressure differential readings; D. Date of reading. [R307-401-8] II.B.3.e At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.e.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] II.B.3.f The owner/operator shall install dust collectors on each dry bulk goods conveyor or pneumatic system with a control efficiency of no less than 99%, each. All air exiting each dry bulk goods conveyor or pneumatic system shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.f.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's control efficiency guarantee for the installed dust collector. [R307-401-8] II.B.4 Haul Road and Fugitive Dust Requirements II.B.4.a The owner/operator shall not allow visible emissions from haul roads and fugitive dust sources on site to exceed 20% opacity. [R307-401-8] DAQE-AN161390002-25 Page 9 II.B.4.a.1 Opacity observations of fugitive dust from intermittent sources shall be conducted according to 40 CFR 60, Appendix A, Method 9; however, the requirement for observations to be made at 15-second intervals over a six-minute period shall not apply. The number of observations and the time period shall be determined by the length of the intermittent source. For fugitive dust generated by mobile sources, visible emissions shall be measured at the densest point of the plume but at a point not less than one-half vehicle length behind the vehicle and not less than one-half the height of the vehicle. [R307-401-8] II.B.4.b The owner/operator shall control particulate emissions from storage piles using water application. The owner/operator shall apply water as required to ensure the opacity limits in this AO are not exceeded. [R307-401-8] II.B.4.b.1 Records of treatments to the storage piles shall include: A. The date, time, and location of applications B. The volume of water applied. [R307-401-8] II.B.4.c The owner/operator shall not have more than 3,696 feet (0.7 miles) of total haul roads on site. All haul roads on site shall be paved. [R307-401-8] II.B.4.c.1 Compliance shall be determined through GPS measurements or aerial photographs. [R307-401-8] II.B.4.d The owner/operator shall flush with water, as needed, the paved haul road on site to maintain opacity limits listed in this AO. If the temperature is below freezing, the owner/operator may stop applying water to the paved haul road. The owner/operator shall resume applying water to the paved haul road when the temperature is above freezing. [R307-401-8] II.B.4.d.1 Records of water application shall be kept for all periods when the plant is in operation. The records shall include the following items: A. Date and time treatments were made B. Number of treatments made and quantity of water applied C. Rainfall amount received, if any D. Records of temperature, if the temperature is below freezing. [R307-401-8] II.B.5 Engine Requirements II.B.5.a The owner/operator shall not allow visible emissions from any 48 hp (36 kW) engine to exceed 20% opacity. [R307-401-8] II.B.5.b The owner/operator shall install four (4) 48 hp (36 kW) generator engines that are each certified to meet a NOx + nonmethane hydrocarbons (NMHC) emission rate of 4.7 g/kW-hr (3.5 g/hp-hr) or less. [R307-401-8] II.B.5.b.1 The owner/operator shall keep a record of the manufacturer's certification of the emission rate. The record shall be kept for the life of the equipment. [R307-401-8] II.B.5.c The owner/operator shall operate and maintain each 48 (36 kW) diesel-fired engine according to the manufacturer's emission-related written instructions. [R307-401-8] DAQE-AN161390002-25 Page 10 II.B.5.d The owner/operator shall only use diesel fuel (e.g., fuel oil #1, #2, or diesel fuel oil additives) as fuel in each stationary diesel engine. [R307-401-8] II.B.5.e The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.5.e.1 To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Is Derived From NOI dated August 2, 2024 Incorporates Additional Information dated August 28, 2024 Incorporates Additional Information dated September 16, 2024 DAQE-AN161390002-25 Page 11 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE-IN161390002-24 November 21, 2024 William Kaiser Savage Services Corporation 901 West Legacy Center Way Midvale, UT 84047 WilliamKaiser@savageservices.com Dear Mr. Kaiser: Re: Intent to Approve: New Cedar City Liquid and Dry Bulk Transloading Facility Project Number: N161390002 The attached document is the Intent to Approve (ITA) for the above-referenced project. The ITA is subject to public review. Any comments received shall be considered before an Approval Order (AO) is issued. The Division of Air Quality is authorized to charge a fee for reimbursement of the actual costs incurred in the issuance of an AO. An invoice will follow upon issuance of the final AO. Future correspondence on this ITA should include the engineer's name, Christine Bodell, as well as the DAQE number as shown on the upper right-hand corner of this letter. Christine Bodell, can be reached at (385) 290-2690 or cbodell@utah.gov, if you have any questions. Sincerely, {{$s }} Alan D. Humpherys, Manager New Source Review Section ADH:CB:jg cc: Southwest Utah Public Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director STATE OF UTAH Department of Environmental Quality Division of Air Quality INTENT TO APPROVE DAQE-IN161390002-24 New Cedar City Liquid and Dry Bulk Transloading Facility Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Savage Services Corporation - Cedar City Transloading Facility Issued On November 21, 2024 {{$s }} New Source Review Section Manager Alan D. Humpherys {{#s=Sig_es_:signer1:signature}} TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 PUBLIC NOTICE STATEMENT............................................................................................... 5 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 6 SECTION II: SPECIAL PROVISIONS ..................................................................................... 6 PERMIT HISTORY ................................................................................................................... 10 ACRONYMS ............................................................................................................................... 11 DAQE-IN161390002-24 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Savage Services Corporation Savage Services Corporation - Cedar City Transloading Facility Mailing Address Physical Address 901 West Legacy Center Way 6635 West Sage Hills Drive Midvale, UT 84047 Cedar City, UT 84721 Source Contact UTM Coordinates Name: William Kaiser 306,873 m Easting Phone: (801) 424-7272 4,178,315 m Northing Email: WilliamKaiser@savageservices.com Datum NAD83 UTM Zone 12 SIC code 5171 (Petroleum Bulk Stations & Terminals) SOURCE INFORMATION General Description Savage Services Corporation (Savage) conducts transloading operations between railcars and trucks for various petroleum liquids and other organic liquids, inorganic liquids, and dry bulk goods. Equipment for the liquid transloading operation includes liquid transfer and vapor return lines. Equipment for dry transloading operations includes enclosed pneumatic systems or enclosed conveyors equipped with dust collectors and diesel-fired, Tier 4i engines to power the pneumatic system or conveyor movements. Savage will also store bulk lump gypsum on site, which will be controlled with water sprays. NSR Classification New Minor Source Source Classification Located in Attainment Area Iron County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), XXa-Standards of Performance for Bulk Gasoline Terminals that Commenced Construction, Modification, or Reconstruction After June 10, 2022 NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for DAQE-IN161390002-24 Page 4 Stationary Reciprocating Internal Combustion Engines MACT (Part 63), BBBBBB: National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Title V (Part 70) Area Source Project Description Savage has requested a new AO for the Savage Transloading Facility located in Cedar City, Iron County. The source has historically operated under Utah Administrative Code (UAC) R307-401-9 "Small Source Exemption" (see DAQE-EN161390001-23, issued September 21, 2023) and is increasing site throughputs and operations and will now require an AO. Two major types of products are transloaded at the source, including liquids and dry bulk goods. Savage has requested to transload petroleum liquids, other organic liquids, and inorganic liquids using liquid transfer lines and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. In addition to the transloading of liquids, Savage will load and unload bulk solid materials such as minerals and grain. The equipment involved in the source's dry bulk goods transloading process includes a total of four (4) covered pneumatic systems or conveyor belts and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. Four (4) Tier 4i diesel engines power the movement of the pneumatic systems or conveyors. The pneumatic systems and conveyors will each be equipped with a baghouse filter with an estimated control efficiency of 99%. Requested throughput includes 90 million gallons of unpressurized liquids per year and 12 million gallons of pressurized liquids per year. Additionally, Savage has requested a throughput of 375,000 tons per year of bulk solid materials, including grains and minerals such as gypsum. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 1187.00 Carbon Monoxide 7.60 Nitrogen Oxides 6.17 Particulate Matter - PM10 0.55 Particulate Matter - PM2.5 0.42 Sulfur Dioxide 0.01 Volatile Organic Compounds 7.90 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 260 Generic HAPs (CAS #GHAPS) 280 Naphthalene (CAS #91203) 220 Toluene (CAS #108883) 1020 Xylenes (Isomers And Mixture) (CAS #1330207) 320 Change (TPY) Total (TPY) Total HAPs 1.05 DAQE-IN161390002-24 Page 5 PUBLIC NOTICE STATEMENT The NOI for the above-referenced project has been evaluated and has been found to be consistent with the requirements of UAC R307. Air pollution producing sources and/or their air control facilities may not be constructed, installed, established, or modified prior to the issuance of an AO by the Director. A 30-day public comment period will be held in accordance with UAC R307-401-7. A notification of the intent to approve will be published in the Beaver County Journal on November 27, 2024. During the public comment period the proposal and the evaluation of its impact on air quality will be available for the public to review and provide comment. If anyone so requests a public hearing within 15 days of publication, it will be held in accordance with UAC R307-401-7. The hearing will be held as close as practicable to the location of the source. Any comments received during the public comment period and the hearing will be evaluated. The proposed conditions of the AO may be changed as a result of the comments received. SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] DAQE-IN161390002-24 Page 6 I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.A THE APPROVED EQUIPMENT II.A.1 Cedar City Transloading Facility II.A.2 Liquid Transfer Lines Includes vapor balance lines and a pressure relief line II.A.3 Four (4) Enclosed Mobile Conveyor Belts *Or four (4) enclosed pneumatic systems* Control: Dust Collector II.A.4 Four (4) Mobile Conveyor Engines Rating: 48 hp (36 kW), each Tier: 4f Fuel: Diesel NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.5 Two (2) Storage Silos Capacities: 140-ton and 195-ton Content: Fly Ash SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a Unless otherwise specified in this AO, the owner/operator shall not allow visible emissions to exceed 10% opacity. [R307-401-8] II.B.1.a.1 Unless otherwise specified in this AO, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Method 9. [R307-401-8] DAQE-IN161390002-24 Page 7 II.B.2 Liquid Loading Requirements II.B.2.a The owner/operator shall not exceed the following organic liquid throughputs: A. 45,000,000 gallons of (unpressurized) low vapor organic liquids that have an absolute vapor pressure of 0.05 psia or less per rolling 12-month period. B. 22,500,000 gallons of (unpressurized) gasoline per rolling 12-month period. C. 22,500,000 gallons of (unpressurized) ethanol per rolling 12-month period. D. 12,000,000 gallons combined of (pressurized) propane, butane, or liquified petroleum gas (LPG) per rolling 12-month period. [R307-401-8] II.B.2.a.1 The owner/operator shall: A. Maintain records of each organic liquid type (low vapor pressure liquid, gasoline, ethanol, LPG, propane, butane) and the absolute vapor pressure of each organic liquid. B. Determine throughput with supervisor monitoring and maintaining an operation log. C Record throughput on a daily basis. D. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months. E. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.2.b The owner/operator shall only load the organic liquids to the rail cars on site directly from the tanker trucks, or vice versa. [R307-401-8] II.B.2.c The owner/operator shall load the rail cars and tanker trucks on site by the use of bottom filling or a submerged fill pipe when loading unpressurized organic liquids. [R307-401-8] II.B.2.d The owner/operator shall connect a vapor balance line to the receiving and delivery vessels prior to venting to the atmosphere during on-site loading operations for the unpressurized organic liquids. The vapor balance line shall be used at all times during loading operations when conducting unpressurized organic liquid loading operations. [R307-401-8] II.B.2.e The owner/operator shall operate each vapor balance system according to the manufacturer's recommendations. [R307-401-8] II.B.2.e.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's recommendations for each installed vapor balance system. [R307-401-8] II.B.2.f The owner/operator shall only load propane, butane, or LPG under pressure. [R307-401-8] II.B.2.g The owner/operator shall only transload the organic liquids to tanker trucks and rail cars that are certified for the NSPS level annual leak test. [R307-401-8] II.B.2.g.1 To determine compliance with the above condition, the owner/operator shall maintain records of annual leak test certifications. [R307-401-8] DAQE-IN161390002-24 Page 8 II.B.3 Bulk Solids Transloading Requirements II.B.3.a The owner/operator shall not transfer more than 375,000 tons of dry bulk solids (minerals, fly ash, and grains) per rolling 12-month period. [R307-401-8] II.B.3.a.1 The owner/operator shall: A. Determine throughput with supervisor monitoring and maintaining an operation log. B Record throughput on a daily basis. C. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months. D. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.3.b The owner/operator shall install a dust collector on each dry bulk goods conveyor or pneumatic system to control particulate emissions generated during the transfer of dry bulk goods. All displaced air from the dry bulk goods transferring operations shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.c The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across each dust collector. [R307-401-8] II.B.3.c.1 The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.c.2 The pressure gauge shall measure the static pressure differential in 1-inch water column increments or less. [R307-401-8] II.B.3.d During operation of each dust collector, the owner/operator shall maintain the static pressure differential within the range recommended by the manufacturer for normal operations. [R307-401-8] II.B.3.d.1 The owner/operator shall record the static pressure differential at least once per operating day while each dust collector is operating. [R307-401-8] II.B.3.d.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit; C. Daily static pressure differential readings; D. Date of reading. [R307-401-8] II.B.3.e At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.e.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] DAQE-IN161390002-24 Page 9 II.B.3.f The owner/operator shall install dust collectors on each dry bulk goods conveyor or pneumatic system with a control efficiency of no less than 99%, each. All air exiting each dry bulk goods conveyor or pneumatic system shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.f.1 To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's control efficiency guarantee for the installed dust collector. [R307-401-8] II.B.4 Haul Road and Fugitive Dust Requirements II.B.4.a The owner/operator shall not allow visible emissions from haul roads and fugitive dust sources on site to exceed 20% opacity. [R307-401-8] II.B.4.a.1 Opacity observations of fugitive dust from intermittent sources shall be conducted according to 40 CFR 60, Appendix A, Method 9; however, the requirement for observations to be made at 15-second intervals over a six-minute period shall not apply. The number of observations and the time period shall be determined by the length of the intermittent source. For fugitive dust generated by mobile sources, visible emissions shall be measured at the densest point of the plume but at a point not less than one-half vehicle length behind the vehicle and not less than one-half the height of the vehicle. [R307-401-8] II.B.4.b The owner/operator shall control particulate emissions from storage piles using water application. The owner/operator shall apply water as required to ensure the opacity limits in this AO are not exceeded. [R307-401-8] II.B.4.b.1 Records of treatments to the storage piles shall include: A. The date, time, and location of applications. B. The volume of water applied. [R307-401-8] II.B.4.c The owner/operator shall not have more than 3,696 feet (0.7 miles) of total haul roads on site. All haul roads on site shall be paved. [R307-401-8] II.B.4.c.1 Compliance shall be determined through GPS measurements or aerial photographs. [R307-401-8] II.B.4.d The owner/operator shall flush with water, as needed, the paved haul road on site to maintain opacity limits listed in this AO. If the temperature is below freezing, the owner/operator may stop applying water to the paved haul road. The owner/operator shall resume applying water to the paved haul road when the temperature is above freezing. [R307-401-8] II.B.4.d.1 Records of water application shall be kept for all periods when the plant is in operation. The records shall include the following items: A. Date and time treatments were made. B. Number of treatments made and quantity of water applied. C. Rainfall amount received, if any. D. Records of temperature, if the temperature is below freezing. [R307-401-8] DAQE-IN161390002-24 Page 10 II.B.5 Engine Requirements II.B.5.a The owner/operator shall not allow visible emissions from any 48 hp (36 kW) engine to exceed 20% opacity. [R307-401-8] II.B.5.b The owner/operator shall install four (4) 48 hp (36 kW) generator engines that are each certified to meet a NOx + nonmethane hydrocarbons (NMHC) emission rate of 4.7 g/kW-hr (3.5 g/hp-hr) or less. [R307-401-8] II.B.5.b.1 The owner/operator shall keep a record of the manufacture's certification of the emission rate. The record shall be kept for the life of the equipment. [R307-401-8] II.B.5.c The owner/operator shall operate and maintain each 48 (36 kW) diesel-fired engine according to the manufacturer's emission-related written instructions. [R307-401-8] II.B.5.d The owner/operator shall only use diesel fuel (e.g., fuel oil #1, #2, or diesel fuel oil additives) as fuel in each stationary diesel engine. [R307-401-8] II.B.5.e The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.5.e.1 To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Is Derived From NOI dated August 1, 2024 Incorporates Additional Information dated August 28, 2024 Incorporates Additional Information dated September 16, 2024 DAQE-IN161390002-24 Page 11 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Jeree Greenwood <jereeg@utah.gov> Legal Notice to be published November 27, 2024 2 messages Jeree Greenwood <jereeg@utah.gov>Thu, Nov 21, 2024 at 7:00 AM To: Beaver County Journal <bcjnewspaper@gmail.com> Please publish the following notice on November 27, 2024. Please also send to Utahlegals.com. If you can, please reply to this email for my confirmation. Thank you, Jeree -- Jeree Greenwood Office Technician II | Minor NSR Section M: (385) 306-6514 airquality.utah.gov DAQE-NN161390002-24.pdf 322K Beaver County Journal <bcjnewspaper@gmail.com>Thu, Nov 21, 2024 at 12:30 PM To: Jeree Greenwood <jereeg@utah.gov> Hi Jeree, I'll get this in the next edition. Thanks Jared [Quoted text hidden] 11/21/24, 2:32 PM State of Utah Mail - Legal Notice to be published November 27, 2024 https://mail.google.com/mail/u/0/?ik=b4fd0e1085&view=pt&search=all&permthid=thread-a:r-957756529023443508&simpl=msg-a:r-408529861873063…1/1 Beaver County Journal Publication Name: Beaver County Journal Publication URL: www.beavercountyjournal.com/sub/account_login.php Publication City and State: Beaver, UT Publication County: Beaver Notice Popular Keyword Category: Notice Keywords: savage Notice Authentication Number: 202411271137412157883 1761527881 Notice URL: Back Notice Publish Date: Wednesday, November 27, 2024 Notice Content Public Notice A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for consideration by the Director: Company Name: Savage Services Corporation Location: Savage Services Corporation - Cedar City Transloading Facility – 6635 West Sage Hills Drive, Cedar City, UT Project Description: Savage Services Corporation (Savage) has requested a new Approval Order (AO) for the Savage Transloading Facility located in Cedar City, Iron County. The source has historically operated under Utah Administrative Code (UAC) R307- 401-9 «Small Source Exemption» (see DAQE-EN161390001-23, issued September 21, 2023) and is increasing site throughputs and operations and will now require an AO. Two major types of products are transloaded at the source, including liquids and dry bulk goods. Savage has requested to transload petroleum liquids, other organic liquids, and inorganic liquids using liquid transfer lines and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. In addition to the transloading of liquids, Savage will load and unload bulk solid materials such as minerals and grain. The equipment involved in the source's dry bulk goods transloading process includes a total of four (4) covered pneumatic systems or conveyor belts and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. Four (4) Tier 4i diesel engines power the movement of the pneumatic systems or conveyors. The pneumatic systems and conveyors will each be equipped with a baghouse filter with an estimated control efficiency of 99%. Requested throughput includes 90 million gallons of unpressurized liquids peryear and 12 million gallons of pressurized liquids per year. Additionally, Savage has requested a throughput of 375,000 tons per year of bulk solid materials, including grains and minerals such as gypsum. The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at the Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address on or before December 27, 2024, will be considered in making the final decision on the approval/disapproval of the proposed project. Email comments will also be accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this notice, a hearing will be held in accordance with R307-401-7, UAC. Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the Director to fully consider the substance and significance of the issue. Published in The Beaver County Journal Nov 27, 2024 Back DAQE-NN161390002-24 November 21, 2024 Beaver County Journal Legal Advertising Department P.O. Box 956 Beaver, UT 84713 RE: Legal Notice of Intent to Approve This letter will confirm the authorization to publish the attached NOTICE in the Beaver County Journal on November 27, 2024. Please mail the invoice and affidavit of publication to the Utah State Department of Environmental Quality, Division of Air Quality, P.O. Box 144820, Salt Lake City, Utah 84114-4820. If you have any questions, contact Jeree Greenwood, who may be reached at (385) 306-6514. Sincerely, {{$s }} Jeree Greenwood Office Technician Enclosure cc: Five County Association of Governments cc: Iron County 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director DAQE-NN161390002-24 Page 2 NOTICE A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for consideration by the Director: Company Name: Savage Services Corporation Location: Savage Services Corporation - Cedar City Transloading Facility – 6635 West Sage Hills Drive, Cedar City, UT Project Description: Savage Services Corporation (Savage) has requested a new Approval Order (AO) for the Savage Transloading Facility located in Cedar City, Iron County. The source has historically operated under Utah Administrative Code (UAC) R307- 401-9 "Small Source Exemption" (see DAQE-EN161390001-23, issued September 21, 2023) and is increasing site throughputs and operations and will now require an AO. Two major types of products are transloaded at the source, including liquids and dry bulk goods. Savage has requested to transload petroleum liquids, other organic liquids, and inorganic liquids using liquid transfer lines and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. In addition to the transloading of liquids, Savage will load and unload bulk solid materials such as minerals and grain. The equipment involved in the source's dry bulk goods transloading process includes a total of four (4) covered pneumatic systems or conveyor belts and associated hoses, pumps, valves, flanges, gauges, connections, and fittings. Four (4) Tier 4i diesel engines power the movement of the pneumatic systems or conveyors. The pneumatic systems and conveyors will each be equipped with a baghouse filter with an estimated control efficiency of 99%. Requested throughput includes 90 million gallons of unpressurized liquids per year and 12 million gallons of pressurized liquids per year. Additionally, Savage has requested a throughput of 375,000 tons per year of bulk solid materials, including grains and minerals such as gypsum. The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at the Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address on or before December 27, 2024, will be considered in making the final decision on the approval/disapproval of the proposed project. Email comments will also be accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this notice, a hearing will be held in accordance with R307-401-7, UAC. Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the Director to fully consider the substance and significance of the issue. Date of Notice: November 27, 2024 {{#s=Sig_es_:signer1:signature}} DAQE- RN161390002 October 2, 2024 William Kaiser Savage Services Corporation 901 West Legacy Center Way Midvale, UT 84047 WilliamKaiser@savageservices.com Dear William Kaiser, Re: Engineer Review: New Cedar City Liquid and Dry Bulk Transloading Facility Project Number: N161390002 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review permitting program. Savage Services Corporation should complete this review within 10 business days of receipt. Savage Services Corporation should contact Christine Bodell at (385) 290-2690 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Christine Bodell at cbodell@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an ITA for a 30-day public comment period. At the completion of the comment period, the DAQ will address any comments and will prepare an Approval Order (AO) for signature by the DAQ Director. If Savage Services Corporation does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Savage Services Corporation has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature _____________________________________________________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Lieutenant Governor October 15, 2024 Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N161390002 Owner Name Savage Services Corporation Mailing Address 901 West Legacy Center Way Midvale, UT, 84047 Source Name Savage Services Corporation- Cedar City Transloading Facility Source Location 6635 West Sage Hills Drive Cedar City, UT 84721 UTM Projection 306,873 m Easting, 4,178,315 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 5171 (Petroleum Bulk Stations & Terminals) Source Contact William Kaiser Phone Number (801) 424-7272 Email WilliamKaiser@savageservices.com Billing Contact William Kaiser Phone Number (801) 424-7272 Email WilliamKaiser@savageservices.com Project Engineer Christine Bodell, Engineer Phone Number (385) 290-2690 Email cbodell@utah.gov Notice of Intent (NOI) Submitted August 2, 2024 Date of Accepted Application October 2, 2024 Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 2 SOURCE DESCRIPTION General Description Savage conducts transloading operations between railcars and trucks for various petroleum liquids and other organic liquids, inorganic liquids, and dry bulk goods. Equipment for the liquid transloading operation includes liquid transfer and vapor return lines. Equipment for dry transloading operations includes enclosed pneumatic systems or enclosed conveyors equipped with dust collectors and diesel-fired, Tier 4i engines to power the pneumatic system or conveyor movements. Savage will also store bulk lump gypsum on site, which will be controlled with water sprays. NSR Classification: New Minor Source Source Classification Located in Attainment Area Iron County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines Project Proposal New Cedar City Liquid and Dry Bulk Transloading Facility Project Description Savage Services Corporation (Savage) has requested a new Approval Order (AO) for the Savage Transloading Facility located in Cedar City, Iron County. The source has historically operated under Utah Administrative Code (UAC) R307-401-9 "Small Source Exemption" (see DAQE- EN161390001-23, issued September 21, 2023), and is increasing site throughputs and operations and will now require an AO. Two major types of products are transloaded at the source, including liquids and dry bulk goods. Savage has requested to transload petroleum liquids, other organic liquids, and inorganic liquids using liquid transfer lines and associated hoses, pumps, valves, flanges, gauges, connections and fittings. In addition to the transloading of liquids, Savage will load and unload bulk solid materials such as minerals and grain. The equipment involved in the source's dry bulk goods transloading process include a total of four (4) covered pneumatic systems or conveyor belts and associated hoses, pumps, valves, flanges, gauges, connections and fittings. Four (4) Tier 4i, diesel engines power the movement of the pneumatic systems or conveyors. The pneumatic systems and conveyors will each be equipped with a baghouse filter with an estimated control efficiency of 99% Requested throughput includes 90 million gallons of unpressurized liquids per year and 12 Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 3 million gallons of pressurized liquids per year. Additionally, Savage has requested a throughput of 225,500 tons per year of bulk solid materials, including grains and minerals such as gypsum. EMISSION IMPACT ANALYSIS Savage Services does not exceed the criteria pollutant or HAPs modeling thresholds outlined in R307-410-4 and R307-410-5, respectively. Therefore, no modeling is required at this time [Last updated August 6, 2024] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 4 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 1187.00 Carbon Monoxide 7.60 Nitrogen Oxides 6.17 Particulate Matter - PM10 0.55 Particulate Matter - PM2.5 0.42 Sulfur Dioxide 0.01 Volatile Organic Compounds 7.90 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 260 Generic HAPs (CAS #GHAPS) 280 Naphthalene (CAS #91203) 220 Toluene (CAS #108883) 1020 Xylenes (Isomers And Mixture) (CAS #1330207) 320 Change (TPY) Total (TPY) Total HAPs 1.05 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 5 Review of BACT for New/Modified Emission Units 1. BACT review regarding Bulk Materials Loading Operations Materials Handling Savage is requesting to transload dry bulk goods, primarily minerals, fly ash, and grain. The main pollutant associated with transferring dry bulk goods is particulate matter. Relevant control technologies include the use of a baghouse/fabric filter, enclosures, watering, and best management practices. Enclosed conveyors and pneumatic systems are estimated to achieve a control efficiency of 50-70% while baghouses/fabric filters can achieve a control efficiency of up to 99%. Savage has elected to employ both technologies to achieve maximum control. Therefore, BACT to control particulate emissions from the transfer of dry bulk goods, including mineral, fly ash, and grain loading operations, is the use of enclosed conveyors or enclosed pneumatic systems and the use of automatic dust collectors. The dust collectors shall each have a certified control efficiency of no less than 99% for particulate matter. Additionally, visible emissions from materials handling operations shall be limited to 10% opacity. Storage Piles Savage will also store bulk lump gypsum on site. Fugitive particulate emissions will be emitted from the outdoor storage piles. Common control options for storage piles include water sprays, full enclosure, or partial enclosure. Water application systems are relatively inexpensive and offer 75% control efficiency of fugitive emissions. Therefore, BACT to control particulate emissions from the gypsum storage piles is the application of water. Visible emissions from conveyor drop points shall be limited to 20% opacity. BACT is also utilizing best operational practices, including but not limited to minimizing drop distance for material transfers and periodic inspections of material handling equipment. [Last updated October 2, 2024] 2. BACT review regarding Liquid Loading Operations Pollutants associated with organic liquid loading are VOCs and HAPs. The VOCs and HAPs will vary depending on the composition of the organic liquid. Emissions from liquid loading can often be controlled by the following: submerged-fill loading, vapor adsorption onto activated carbon, a vapor recovery system, vapor combustion, or a vapor balance system. High Vapor Pressure Organic Liquids (Gasoline and Ethanol) Rail car and truck loading are performed through submerged-fill loading. The fill tube extends towards the bottom of the car. Vapors are collected via a vapor balance system that routes emissions back to the truck being emptied. Per EPA's AP-42 5.2 Transportation and Marketing Of Petroleum Liquids, a collection efficiency of 98.7% should be assumed for trucks passing the NSPS-level annual test (3 inches pressure change). The trucks and rail cars are all annually leak tested. The remaining emissions can be controlled via vapor adsorption/recovery, combustion, or vented to the atmosphere. Savage utilizes ground-based transfer racks for safety purposes. These ground- level racks do not provide any allowance for mounting a drum or recovery unit and related ancillary equipment. Additionally, the source was unable to find any suitable kits to retrofit these racks. Therefore, use of vapor adsorption/recovery technology is not technically feasible. Additionally, due to the vapor balance system capturing 98.7% of vapors, thermal combustion is not cost effective and is therefore not selected. Therefore, BACT to control VOC and HAPs emissions from gasoline and ethanol loading operations is submerged loading and the use of a vapor-balance system. Additionally, Savage will ensure that gasoline and ethanol loading Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 6 operations are conducted with truck and rail car tank that are leak tested annually. Low Vapor Pressure Organic Liquids (Diesel, Kerosene, Food Oils) Absolute vapor pressure for this class of materials will be 0.05 psia or lower. Due to the low vapor pressure, additional add-on controls are not technically feasible. BACT is ensuring that rail car and truck loading are performed through submerged-fill loading. Additionally, BACT is using a vapor- balance system line to reduce emissions. Pressurized Organic Liquids (Liquified Petroleum Gas (LPG), Propane, Butane) For the pressurized organic liquids transfer, Savage will transfer liquefied petroleum gas (LPG), propane, or butane under pressure using a compressor. Emissions will be low in volume. Therefore, BACT is best operating practices, such as using auto-close hose connectors to minimize losses when decoupling the hoses after transfer. [Last updated August 28, 2024] 3. BACT review regarding Component Fugitive Emissions Operations at the Savage facility will generate fugitive VOC emissions. Due to the relatively low volume of VOC emissions, additional add-on control technologies are not technically feasible. Therefore, BACT to control fugitive VOC emissions from valves, pump seals, flanges, and fittings is best operating practices. [Last updated October 2, 2024] 4. BACT review regarding Haul Roads Operations at the Savage facility will result in the use of a haul road. The haul road on site is less than 0.5 miles in length. Controls for existing paved areas include sweeping, vacuum sweeping and/or watering. Paved roadways, combined with sweeping and watering, provides a 90% control efficiency; the use of a vacuum sweeper increases the control efficiency to 95%. For existing and proposed unpaved areas, control technologies include watering (70% control efficiency), watering combined with the use of a low silt content road base (75% control efficiency), and the application of chemical dust suppressants (85% control efficiency). Savage has elected to pave the haul road on site. This is considered BACT. Additionally, the haul road on site will be treated as necessary to maintain the opacity limitations in R307-205-4 (Emission Standards: Fugitive Emissions and Fugitive Dust). Water application will therefore be used to limit fugitive dust emissions to maintain visible emissions at or below 20% opacity on site. [Last updated August 20, 2024] 5. BACT review regarding Diesel Engines NOx, CO, SO2, PM10, PM2.5, VOC, and HAP emissions will be emitted from the proposed 48 hp, Tier 4i engines that power the movement of the pneumatic systems and enclosed conveyors. The potential to emits from each engine are as follows: 0.08 tpy of PM10, 0.08 tpy of PM2.5, 1.54 tpy of NOx, 0.003 tpy of SO2, 1.90 tpy of CO, 0.08 tpy of VOCs, and 0.02 tpy of HAPs. The source has selected an engine in compliance with EPA's 2013 Tier 4 standards, without an evaluation on other, lesser controls. Therefore, BACT to control emissions from the engine will be the use of a Tier 4f engine. Additionally, sulfur dioxide emissions occur from the reaction of various sulfur elements in the diesel fuel. Sulfur in diesel fuel oxidizes during combustion to form SO2 and sulfur trioxide (SO3). Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 7 Savage will use ultra-low sulfur diesel fuel containing no more than 15 parts per million by weight of sulfur. The engines will also be kept in good working condition. Other than startup, shutdown, or malfunction, visible emissions should be kept at 20% opacity or less. The use of Tier 4f engines, ultra-low sulfur diesel fuel, and the opacity limit are considered BACT for the engines. [Last updated August 28, 2024] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307- 150] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 8 I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 NEW Cedar City Transloading Facility II.A.2 NEW Liquid Transfer Lines Includes vapor balance lines and a pressure relief line II.A.3 NEW Four (4) Enclosed Mobile Conveyor Belts *Or four (4) enclosed pneumatic systems* Control: Dust Collector II.A.4 NEW Four (4) Mobile Conveyor Engines Rating: 48 hp (36 kW), each Tier: 4f Fuel: Diesel NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.5 NEW Two (2) Storage Silos Capacities: 140-ton and 195-ton Content: Fly Ash SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 NEW Site-Wide Requirements II.B.1.a NEW Unless otherwise specified in this AO, the owner/operator shall not allow visible emissions to exceed 10% opacity. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 9 II.B.1.a.1 NEW Unless otherwise specified in this AO, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Method 9. [R307-401-8] II.B.2 NEW Liquid Loading Requirements II.B.2.a NEW The owner/operator shall not exceed the following organic liquid throughputs: A. 45,000,000 gallons of (unpressurized) low vapor organic liquids that have an absolute vapor pressure of 0.05 psia or less per rolling 12-month period B. 22,500,000 gallons of (unpressurized) gasoline per rolling 12-month period C. 22,500,000 gallons of (unpressurized) ethanol per rolling 12-month period D. 12,000,000 gallons combined of (pressurized) propane, butane, or liquified petroleum gas (LPG) per rolling 12-month period. [R307-401-8] II.B.2.a.1 NEW The owner/operator shall: A. Maintain records of each organic liquid type (low vapor pressure liquid, gasoline, ethanol, LPG, propane, butane) and the absolute vapor pressure of each organic liquid B. Determine throughput with supervisor monitoring and maintaining an operation log C Record throughput on a daily basis D. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months E. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.2.b NEW The owner/operator shall only load the organic liquids to the rail cars on site directly from the tanker trucks, or vice versa. [R307-401-8] II.B.2.c NEW The owner/operator shall load the rail cars and tanker trucks on site by the use of bottom filling or a submerged fill pipe when loading unpressurized organic liquids. [R307-401-8] II.B.2.d NEW The owner/operator shall connect a vapor balance line to the receiving and delivery vessels prior to venting to the atmosphere during on-site loading operations for the unpressurized organic liquids. The vapor balance line shall be used at all times during loading operations when conducting unpressurized organic liquid loading operations. [R307-401-8] II.B.2.e NEW The owner/operator shall operate each vapor balance system according to the manufacturer's recommendations. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 10 II.B.2.e.1 NEW To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's recommendations for each installed vapor balance system. [R307-401-8] II.B.2.f NEW The owner/operator shall only load propane, butane, or liquified petroleum gas (LPG) under pressure. [R307-401-8] II.B.2.g NEW The owner/operator shall only transload the organic liquids to tanker trucks and rail cars that are certified for the NSPS level annual leak test. [R307-401-8] II.B.2.g.1 NEW To determine compliance with the above condition, the owner/operator shall maintain records of annual leak test certifications. [R307-401-8] II.B.3 NEW Bulk Solids Transloading Requirements II.B.3.a NEW The owner/operator shall not transfer more than 375,000 tons of dry bulk solids (minerals, fly ash, and grains) per rolling 12-month period. [R307-401-8] II.B.3.a.1 NEW The owner/operator shall: A. Determine throughput with supervisor monitoring and maintaining an operation log B Record throughput on a daily basis C. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.3.b NEW The owner/operator shall install a dust collector on each dry bulk goods conveyor or pneumatic system to control particulate emissions generated during the transfer of dry bulk goods. All displaced air from the dry bulk goods transferring operations shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.c NEW The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across each dust collector. [R307-401-8] II.B.3.c.1 NEW The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.c.2 NEW The pressure gauge shall measure the static pressure differential in 1-inch water column increments or less. [R307-401-8] II.B.3.d NEW During operation of each dust collector, the owner/operator shall maintain the static pressure differential within the range recommended by the manufacturer for normal operations. [R307- 401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 11 II.B.3.d.1 NEW The owner/operator shall record the static pressure differential at least once per operating day while each dust collector is operating. [R307-401-8] II.B.3.d.2 NEW The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit; C. Daily static pressure differential readings; D. Date of reading. [R307-401-8] II.B.3.e NEW At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.e.1 NEW The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] II.B.3.f NEW The owner/operator shall install dust collectors on each dry bulk goods conveyor or pneumatic system with a control efficiency of no less than 99%, each. All air exiting each dry bulk goods conveyor or pneumatic system shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.f.1 NEW To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's control efficiency guarantee for the installed dust collector. [R307-401-8] II.B.4 NEW Haul Road and Fugitive Dust Requirements II.B.4.a NEW The owner/operator shall not allow visible emissions from haul roads and fugitive dust sources on site to exceed 20% opacity. [R307-401-8] II.B.4.a.1 NEW Opacity observations of fugitive dust from intermittent sources shall be conducted according to 40 CFR 60, Appendix A, Method 9; however, the requirement for observations to be made at 15-second intervals over a six-minute period shall not apply. The number of observations and the time period shall be determined by the length of the intermittent source. For fugitive dust generated by mobile sources, visible emissions shall be measured at the densest point of the plume but at a point not less than one-half vehicle length behind the vehicle and not less than one-half the height of the vehicle. [R307-401-8] II.B.4.b NEW The owner/operator shall control particulate emissions from storage piles using water application. The owner/operator shall apply water as required to ensure the opacity limits in this AO are not exceeded. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 12 II.B.4.b.1 NEW Records of treatments to the storage piles shall include: A. The date, time, and location of applications. B. The volume of water applied. [R307-401-8] II.B.4.c NEW The owner/operator shall not have more than 2,640 feet (0.5 miles) of total haul roads on site. All haul roads on site shall be paved. [R307-401-8] II.B.4.c.1 NEW Compliance shall be determined through GPS measurements or aerial photographs. [R307- 401-8] II.B.4.d NEW An operational water truck shall be made available during each operating day. The owner/operator shall flush with water, as needed, the paved haul road on site to maintain opacity limits listed in this AO. If the temperature is below freezing, the owner/operator may stop applying water to the paved haul road. The owner/operator shall resume applying water to the paved haul road when the temperature is above freezing. [R307-401-8] II.B.4.d.1 NEW Records of water application shall be kept for all periods when the plant is in operation. The records shall include the following items: A. Date and time treatments were made B. Number of treatments made and quantity of water applied C. Rainfall amount received, if any D. Records of temperature, if the temperature is below freezing [R307-401-8] II.B.5 NEW Engine Requirements II.B.5.a NEW The owner/operator shall not allow visible emissions from any 48 hp (36 kW) engine to exceed 20% opacity. [R307-401-8] II.B.5.b NEW The owner/operator shall install four (4) 48 hp (36 kW) generator engines that are each certified to meet a NOx + nonmethane hydrocarbons (NMHC) emission rate of 4.7 g/kW-hr (3.5 g/hp-hr) or less. [R307-401-8] II.B.5.b.1 NEW The owner/operator shall keep a record of the manufacture's certification of the emission rate. The record shall be kept for the life of the equipment. [R307-401-8] II.B.5.c NEW The owner/operator shall operate and maintain each 48 (36 kW) diesel-fired engine according to the manufacturer's emission-related written instructions. [R307-401-8] II.B.5.d NEW The owner/operator shall only use diesel fuel (e.g. fuel oil #1, #2, or diesel fuel oil additives) as fuel in each stationary diesel engine. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 13 II.B.5.e NEW The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.5.e.1 NEW To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 14 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Is Derived From NOI dated August 1, 2024 Incorporates Additional Information dated August 28, 2024 Incorporates Additional Information dated September 16, 2024 REVIEWER COMMENTS 1. Comment regarding Federal Subpart Applicability: NSPS Subpart IIII Owners and operators of stationary CI ICE that commence construction after July 11, 2005 are subject to 40 CFR Part 60, Subpart IIII (Standards of Performance for Stationary Compression Ignition Internal Combustion Engines). The provisions of Subpart IIII are applicable to four (4) 48 hp, diesel-fired engines that is compliant with 2013 EPA Tier 4f standards. These engines are not designated as nonroad and are therefore not exempt from meeting the provisions of NSPS Subpart IIII. MACT Subpart ZZZZ The stationary engines on site are subject to 40 CFR Part 63, Subpart ZZZZ (National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines). The provisions of MACT Subpart ZZZZ apply as the stationary reciprocating internal combustion engines (RICE) are at an area source of HAP emissions. All engines not designated as nonroad and not exempt are affected sources under this regulation. The stationary engines on site that are subject to MACT Subpart ZZZZ must meet the requirements of NSPS Subpart IIII. No further requirements apply to the engines under MACT Subpart ZZZZ. [Last updated August 28, 2024] 2. Comment regarding Title V Applicability: Title V of the 1990 Clean Air Act (Title V) applies to the following: 1. Any major source 2. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources; 3. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants. 4. Any Title IV affected source. This facility is not a major source and is not a Title IV source. The facility is not subject to 40 CFR 61 (NESHAP) regulations. This facility is subject to 40 CFR 60 (NSPS) Subparts A and IIII and 40 CFR 63 (MACT) Subparts A and ZZZZ. Section 60.4200(c) of NSPS Subpart IIII and section 63.6585(d) of MACT Subpart ZZZZ both exempt the source from the obligation to obtain a permit under Title V, provided the source is not required to obtain a Title V permit for another reason. Therefore, Title V does not apply to this facility. [Last updated August 20, 2024] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 15 3. Comment regarding Source Emission Estimates and DAQ Acceptance: Liquid Loading Emission estimates from the loading of organic and inorganic liquids were calculated using Equation 1 from AP-42, Chapter 5.2 Transportation and Marketing of Petroleum Liquids dated June 2008. The calculations were conservatively based on a maximum operating schedule of 8,760 hours per year (24 hours/day, 7 days/week and 52 weeks/year). It is reasonably assumed that the vapor capture system and annual leak testing will reduce the VOC and HAPs emissions by approximately 98% Fugitive Leaks Emissions were calculated based on U.S. EPA's Protocol for Equipment Leak Estimates (EPA453/R- 95-017), and data from a similar Savage transloading facility located in Price, Utah. Dry Bulk Goods Loading Emission factors for the loading of dry bulk goods were calculated using AP-42 Chapter 11.19.2 Crushed Stone Processing and Pulverized Mineral Processing. Emissions from dry bulk goods materials handling were calculated using Equation 1 from AP-42, Chapter 13.2.4 Aggregate Handling and Storage Piles. The loading conveyor is equipped with a baghouse with a 99% control efficiency to reduce dust emissions from dry bulk transloading operations. Haul Roads Emissions estimations from haul roads were calculated from AP-42, Chapter 13.2.2 Paved Roads. 48 hp Diesel Engines Emissions estimations from the diesel engines were calculated from EPA's Tier 4i emission standards and AP-42, Chapter 3.3 Gasoline and Diesel Industrial Engines. The calculations were conservatively based on a maximum operating schedule of 8,760 hours per year. [Last updated October 2, 2024] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility October 2, 2024 Page 16 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE- RN161390002 November 2, 2024 William Kaiser Savage Services Corporation 901 West Legacy Center Way Midvale, UT 84047 WilliamKaiser@savageservices.com Dear William Kaiser, Re: Engineer Review: New Cedar City Liquid and Dry Bulk Transloading Facility Project Number: N161390002 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review permitting program. Savage Services Corporation should complete this review within 10 business days of receipt. Savage Services Corporation should contact Christine Bodell at (385) 290-2690 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Christine Bodell at cbodell@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an ITA for a 30-day public comment period. At the completion of the comment period, the DAQ will address any comments and will prepare an Approval Order (AO) for signature by the DAQ Director. If Savage Services Corporation does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Savage Services Corporation has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature _____________________________________________________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N161390002 Owner Name Savage Services Corporation Mailing Address 901 West Legacy Center Way Midvale, UT, 84047 Source Name Savage Services Corporation- Cedar City Transloading Facility Source Location 6635 West Sage Hills Drive Cedar City, UT 84721 UTM Projection 306,873 m Easting, 4,178,315 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 5171 (Petroleum Bulk Stations & Terminals) Source Contact William Kaiser Phone Number (801) 424-7272 Email WilliamKaiser@savageservices.com Billing Contact William Kaiser Phone Number (801) 424-7272 Email WilliamKaiser@savageservices.com Project Engineer Christine Bodell, Engineer Phone Number (385) 290-2690 Email cbodell@utah.gov Notice of Intent (NOI) Submitted August 2, 2024 Date of Accepted Application October 2, 2024 Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 2 SOURCE DESCRIPTION General Description Savage conducts transloading operations between railcars and trucks for various petroleum liquids and other organic liquids, inorganic liquids, and dry bulk goods. Equipment for the liquid transloading operation includes liquid transfer and vapor return lines. Equipment for dry transloading operations includes enclosed pneumatic systems or enclosed conveyors equipped with dust collectors and diesel-fired, Tier 4i engines to power the pneumatic system or conveyor movements. Savage will also store bulk lump gypsum on site, which will be controlled with water sprays. NSR Classification: New Minor Source Source Classification Located in Attainment Area Iron County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines NSPS (Part 60), XXa: Standards of Performance for Bulk Gasoline Terminals that Commenced Construction, Modification, or Reconstruction After June 10, 2022 MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines MACT (Part 63), BBBBBB: National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Title V (Part 70) Area Source Project Proposal New Cedar City Liquid and Dry Bulk Transloading Facility Project Description Savage Services Corporation (Savage) has requested a new Approval Order (AO) for the Savage Transloading Facility located in Cedar City, Iron County. The source has historically operated under Utah Administrative Code (UAC) R307-401-9 "Small Source Exemption" (see DAQE-EN161390001-23, issued September 21, 2023), and is increasing site throughputs and operations and will now require an AO. Two major types of products are transloaded at the source, including liquids and dry bulk goods. Savage has requested to transload petroleum liquids, other organic liquids, and inorganic liquids using liquid transfer lines and associated hoses, pumps, valves, flanges, gauges, connections and fittings. In addition to the transloading of liquids, Savage will load and unload bulk solid materials such as minerals and grain. The equipment involved in the source's dry bulk goods transloading process include a total of four (4) covered pneumatic systems or conveyor belts and associated hoses, Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 3 pumps, valves, flanges, gauges, connections and fittings. Four (4) Tier 4i, diesel engines power the movement of the pneumatic systems or conveyors. The pneumatic systems and conveyors will each be equipped with a baghouse filter with an estimated control efficiency of 99% Requested throughput includes 90 million gallons of unpressurized liquids per year and 12 million gallons of pressurized liquids per year. Additionally, Savage has requested a throughput of 375,000 tons per year of bulk solid materials, including grains and minerals such as gypsum. EMISSION IMPACT ANALYSIS Savage Services does not exceed the criteria pollutant or HAPs modeling thresholds outlined in R307-410-4 and R307-410-5, respectively. Therefore, no modeling is required at this time [Last updated August 6, 2024] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 4 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 1187.00 Carbon Monoxide 7.60 Nitrogen Oxides 6.17 Particulate Matter - PM10 0.55 Particulate Matter - PM2.5 0.42 Sulfur Dioxide 0.01 Volatile Organic Compounds 7.90 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Benzene (Including Benzene From Gasoline) (CAS #71432) 260 Generic HAPs (CAS #GHAPS) 280 Naphthalene (CAS #91203) 220 Toluene (CAS #108883) 1020 Xylenes (Isomers And Mixture) (CAS #1330207) 320 Change (TPY) Total (TPY) Total HAPs 1.05 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 5 Review of BACT for New/Modified Emission Units 1. BACT review regarding Bulk Materials Loading Operations Materials Handling Savage is requesting to transload dry bulk goods, primarily minerals, fly ash, and grain. The main pollutant associated with transferring dry bulk goods is particulate matter. Relevant control technologies include the use of a baghouse/fabric filter, enclosures, watering, and best management practices. Enclosed conveyors and pneumatic systems are estimated to achieve a control efficiency of 50-70% while baghouses/fabric filters can achieve a control efficiency of up to 99%. Savage has elected to employ both technologies to achieve maximum control. Therefore, BACT to control particulate emissions from the transfer of dry bulk goods, including mineral, fly ash, and grain loading operations, is the use of enclosed conveyors or enclosed pneumatic systems and the use of automatic dust collectors. The dust collectors shall each have a certified control efficiency of no less than 99% for particulate matter. Additionally, visible emissions from materials handling operations shall be limited to 10% opacity. Storage Piles Savage will also store bulk lump gypsum on site. Fugitive particulate emissions will be emitted from the outdoor storage piles. Common control options for storage piles include water sprays, full enclosure, or partial enclosure. Water application systems are relatively inexpensive and offer 75% control efficiency of fugitive emissions. Therefore, BACT to control particulate emissions from the gypsum storage piles is the application of water. Visible emissions from conveyor drop points shall be limited to 20% opacity. BACT is also utilizing best operational practices, including but not limited to minimizing drop distance for material transfers and periodic inspections of material handling equipment. [Last updated October 2, 2024] 2. BACT review regarding Liquid Loading Operations Pollutants associated with organic liquid loading are VOCs and HAPs. The VOCs and HAPs will vary depending on the composition of the organic liquid. Emissions from liquid loading can often be controlled by the following: submerged-fill loading, vapor adsorption onto activated carbon, a vapor recovery system, vapor combustion, or a vapor balance system. High Vapor Pressure Organic Liquids (Gasoline and Ethanol) Rail car and truck loading are performed through submerged-fill loading. The fill tube extends towards the bottom of the car. Vapors are collected via a vapor balance system that routes emissions back to the truck being emptied. Per EPA's AP-42 5.2 Transportation and Marketing Of Petroleum Liquids, a collection efficiency of 98.7% should be assumed for trucks passing the NSPS-level annual test (3 inches pressure change). The trucks and rail cars are all annually leak tested. The remaining emissions can be controlled via vapor adsorption/recovery, combustion, or vented to the atmosphere. Savage utilizes ground-based transfer racks for safety purposes. These ground- level racks do not provide any allowance for mounting a drum or recovery unit and related ancillary equipment. Additionally, the source was unable to find any suitable kits to retrofit these racks. Therefore, use of vapor adsorption/recovery technology is not technically feasible. Additionally, due to the vapor balance system capturing 98.7% of vapors, thermal combustion is not cost effective and is therefore not selected. Therefore, BACT to control VOC and HAPs emissions from gasoline and ethanol loading operations is submerged loading and the use of a vapor-balance system. Additionally, Savage will ensure that gasoline and ethanol loading Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 6 operations are conducted with truck and rail car tank that are leak tested annually. Low Vapor Pressure Organic Liquids (Diesel, Kerosene, Food Oils) Absolute vapor pressure for this class of materials will be 0.05 psia or lower. Due to the low vapor pressure, additional add-on controls are not technically feasible. BACT is ensuring that rail car and truck loading are performed through submerged-fill loading. Additionally, BACT is using a vapor-balance system line to reduce emissions. Pressurized Organic Liquids (Liquified Petroleum Gas (LPG), Propane, Butane) For the pressurized organic liquids transfer, Savage will transfer liquefied petroleum gas (LPG), propane, or butane under pressure using a compressor. Emissions will be low in volume. Therefore, BACT is best operating practices, such as using auto-close hose connectors to minimize losses when decoupling the hoses after transfer. [Last updated August 28, 2024] 3. BACT review regarding Component Fugitive Emissions Operations at the Savage facility will generate fugitive VOC emissions. Due to the relatively low volume of VOC emissions, additional add-on control technologies are not technically feasible. Therefore, BACT to control fugitive VOC emissions from valves, pump seals, flanges, and fittings is best operating practices. [Last updated October 2, 2024] 4. BACT review regarding Haul Roads Operations at the Savage facility will result in the use of a haul road. The haul road on site is less than 0.5 miles in length. Controls for existing paved areas include sweeping, vacuum sweeping and/or watering. Paved roadways, combined with sweeping and watering, provides a 90% control efficiency; the use of a vacuum sweeper increases the control efficiency to 95%. For existing and proposed unpaved areas, control technologies include watering (70% control efficiency), watering combined with the use of a low silt content road base (75% control efficiency), and the application of chemical dust suppressants (85% control efficiency). Savage has elected to pave the haul road on site. This is considered BACT. Additionally, the haul road on site will be treated as necessary to maintain the opacity limitations in R307-205-4 (Emission Standards: Fugitive Emissions and Fugitive Dust). Water application will therefore be used to limit fugitive dust emissions to maintain visible emissions at or below 20% opacity on site. [Last updated August 20, 2024] 5. BACT review regarding Diesel Engines NOx, CO, SO2, PM10, PM2.5, VOC, and HAP emissions will be emitted from the proposed 48 hp, Tier 4i engines that power the movement of the pneumatic systems and enclosed conveyors. The potential to emits from each engine are as follows: 0.08 tpy of PM10, 0.08 tpy of PM2.5, 1.54 tpy of NOx, 0.003 tpy of SO2, 1.90 tpy of CO, 0.08 tpy of VOCs, and 0.02 tpy of HAPs. The source has selected an engine in compliance with EPA's 2013 Tier 4 standards, without an evaluation on other, lesser controls. Therefore, BACT to control emissions from the engine will be the use of a Tier 4f engine. Additionally, sulfur dioxide emissions occur from the reaction of various sulfur elements in the diesel fuel. Sulfur in diesel fuel oxidizes during combustion to form SO2 and sulfur trioxide (SO3). Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 7 Savage will use ultra-low sulfur diesel fuel containing no more than 15 parts per million by weight of sulfur. The engines will also be kept in good working condition. Other than startup, shutdown, or malfunction, visible emissions should be kept at 20% opacity or less. The use of Tier 4f engines, ultra-low sulfur diesel fuel, and the opacity limit are considered BACT for the engines. [Last updated August 28, 2024] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 8 I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 NEW Cedar City Transloading Facility II.A.2 NEW Liquid Transfer Lines Includes vapor balance lines and a pressure relief line II.A.3 NEW Four (4) Enclosed Mobile Conveyor Belts *Or four (4) enclosed pneumatic systems* Control: Dust Collector II.A.4 NEW Four (4) Mobile Conveyor Engines Rating: 48 hp (36 kW), each Tier: 4f Fuel: Diesel NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.5 NEW Two (2) Storage Silos Capacities: 140-ton and 195-ton Content: Fly Ash SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 NEW Site-Wide Requirements Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 9 II.B.1.a NEW Unless otherwise specified in this AO, the owner/operator shall not allow visible emissions to exceed 10% opacity. [R307-401-8] II.B.1.a.1 NEW Unless otherwise specified in this AO, opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Method 9. [R307-401-8] II.B.2 NEW Liquid Loading Requirements II.B.2.a NEW The owner/operator shall not exceed the following organic liquid throughputs: A. 45,000,000 gallons of (unpressurized) low vapor organic liquids that have an absolute vapor pressure of 0.05 psia or less per rolling 12-month period B. 22,500,000 gallons of (unpressurized) gasoline per rolling 12-month period C. 22,500,000 gallons of (unpressurized) ethanol per rolling 12-month period D. 12,000,000 gallons combined of (pressurized) propane, butane, or liquified petroleum gas (LPG) per rolling 12-month period. [R307-401-8] II.B.2.a.1 NEW The owner/operator shall: A. Maintain records of each organic liquid type (low vapor pressure liquid, gasoline, ethanol, LPG, propane, butane) and the absolute vapor pressure of each organic liquid B. Determine throughput with supervisor monitoring and maintaining an operation log C Record throughput on a daily basis D. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months E. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.2.b NEW The owner/operator shall only load the organic liquids to the rail cars on site directly from the tanker trucks, or vice versa. [R307-401-8] II.B.2.c NEW The owner/operator shall load the rail cars and tanker trucks on site by the use of bottom filling or a submerged fill pipe when loading unpressurized organic liquids. [R307-401-8] II.B.2.d NEW The owner/operator shall connect a vapor balance line to the receiving and delivery vessels prior to venting to the atmosphere during on-site loading operations for the unpressurized organic liquids. The vapor balance line shall be used at all times during loading operations when conducting unpressurized organic liquid loading operations. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 10 II.B.2.e NEW The owner/operator shall operate each vapor balance system according to the manufacturer's recommendations. [R307-401-8] II.B.2.e.1 NEW To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's recommendations for each installed vapor balance system. [R307-401-8] II.B.2.f NEW The owner/operator shall only load propane, butane, or liquified petroleum gas (LPG) under pressure. [R307-401-8] II.B.2.g NEW The owner/operator shall only transload the organic liquids to tanker trucks and rail cars that are certified for the NSPS level annual leak test. [R307-401-8] II.B.2.g.1 NEW To determine compliance with the above condition, the owner/operator shall maintain records of annual leak test certifications. [R307-401-8] II.B.3 NEW Bulk Solids Transloading Requirements II.B.3.a NEW The owner/operator shall not transfer more than 375,000 tons of dry bulk solids (minerals, fly ash, and grains) per rolling 12-month period. [R307-401-8] II.B.3.a.1 NEW The owner/operator shall: A. Determine throughput with supervisor monitoring and maintaining an operation log B Record throughput on a daily basis C. Use the throughput data to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep the throughput records for all periods the plant is in operation. [R307-401-8] II.B.3.b NEW The owner/operator shall install a dust collector on each dry bulk goods conveyor or pneumatic system to control particulate emissions generated during the transfer of dry bulk goods. All displaced air from the dry bulk goods transferring operations shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.c NEW The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across each dust collector. [R307-401-8] II.B.3.c.1 NEW The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.c.2 NEW The pressure gauge shall measure the static pressure differential in 1-inch water column increments or less. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 11 II.B.3.d NEW During operation of each dust collector, the owner/operator shall maintain the static pressure differential within the range recommended by the manufacturer for normal operations. [R307-401-8] II.B.3.d.1 NEW The owner/operator shall record the static pressure differential at least once per operating day while each dust collector is operating. [R307-401-8] II.B.3.d.2 NEW The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit; C. Daily static pressure differential readings; D. Date of reading. [R307-401-8] II.B.3.e NEW At least once every 12 months, the owner/operator shall calibrate each pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.e.1 NEW The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] II.B.3.f NEW The owner/operator shall install dust collectors on each dry bulk goods conveyor or pneumatic system with a control efficiency of no less than 99%, each. All air exiting each dry bulk goods conveyor or pneumatic system shall pass through the dust collector before being vented to the atmosphere. [R307-401-8] II.B.3.f.1 NEW To demonstrate compliance with the above condition, the owner/operator shall maintain records of the manufacturer's control efficiency guarantee for the installed dust collector. [R307-401-8] II.B.4 NEW Haul Road and Fugitive Dust Requirements II.B.4.a NEW The owner/operator shall not allow visible emissions from haul roads and fugitive dust sources on site to exceed 20% opacity. [R307-401-8] II.B.4.a.1 NEW Opacity observations of fugitive dust from intermittent sources shall be conducted according to 40 CFR 60, Appendix A, Method 9; however, the requirement for observations to be made at 15-second intervals over a six-minute period shall not apply. The number of observations and the time period shall be determined by the length of the intermittent source. For fugitive dust generated by mobile sources, visible emissions shall be measured at the densest point of the plume but at a point not less than one-half vehicle length behind the vehicle and not less than one-half the height of the vehicle. [R307-401-8] II.B.4.b NEW The owner/operator shall control particulate emissions from storage piles using water application. The owner/operator shall apply water as required to ensure the opacity limits in this AO are not exceeded. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 12 II.B.4.b.1 NEW Records of treatments to the storage piles shall include: A. The date, time, and location of applications. B. The volume of water applied. [R307-401-8] II.B.4.c NEW The owner/operator shall not have more than 3,696 feet (0.7 miles) of total haul roads on site. All haul roads on site shall be paved. [R307-401-8] II.B.4.c.1 NEW Compliance shall be determined through GPS measurements or aerial photographs. [R307-401-8] II.B.4.d NEW The owner/operator shall flush with water, as needed, the paved haul road on site to maintain opacity limits listed in this AO. If the temperature is below freezing, the owner/operator may stop applying water to the paved haul road. The owner/operator shall resume applying water to the paved haul road when the temperature is above freezing. [R307-401-8] II.B.4.d.1 NEW Records of water application shall be kept for all periods when the plant is in operation. The records shall include the following items: A. Date and time treatments were made B. Number of treatments made and quantity of water applied C. Rainfall amount received, if any D. Records of temperature, if the temperature is below freezing [R307-401-8] II.B.5 NEW Engine Requirements II.B.5.a NEW The owner/operator shall not allow visible emissions from any 48 hp (36 kW) engine to exceed 20% opacity. [R307-401-8] II.B.5.b NEW The owner/operator shall install four (4) 48 hp (36 kW) generator engines that are each certified to meet a NOx + nonmethane hydrocarbons (NMHC) emission rate of 4.7 g/kW-hr (3.5 g/hp-hr) or less. [R307-401-8] II.B.5.b.1 NEW The owner/operator shall keep a record of the manufacture's certification of the emission rate. The record shall be kept for the life of the equipment. [R307-401-8] II.B.5.c NEW The owner/operator shall operate and maintain each 48 (36 kW) diesel-fired engine according to the manufacturer's emission-related written instructions. [R307-401-8] II.B.5.d NEW The owner/operator shall only use diesel fuel (e.g. fuel oil #1, #2, or diesel fuel oil additives) as fuel in each stationary diesel engine. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 13 II.B.5.e NEW The owner/operator shall only combust diesel fuel that meets the definition of ultra-low sulfur diesel (ULSD), which has a sulfur content of 15 ppm or less. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.5.e.1 NEW To demonstrate compliance with the ULSD fuel requirement, the owner/operator shall maintain records of diesel fuel purchase invoices or obtain certification of sulfur content from the diesel fuel supplier. The diesel fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements. [R307-401-8] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 14 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Is Derived From NOI dated August 1, 2024 Incorporates Additional Information dated August 28, 2024 Incorporates Additional Information dated September 16, 2024 REVIEWER COMMENTS 1. Comment regarding Federal Subpart Applicability: NSPS Subpart XXa The provisions of NSPS Subpart XXa (Standards of Performance for Bulk Gasoline Terminals that Commenced Construction, Modification, or Reconstruction After June 10, 2022) are applicable to owners and operators of gasoline loading rack affected facilities and each collection of equipment at a bulk gasoline terminal affected facility. A bulk gasoline terminal means any gasoline facility which receives gasoline by pipeline, ship, barge, or cargo tank and subsequently loads all or a portion of the gasoline into gasoline cargo tanks for transport to bulk gasoline plants or gasoline dispensing facilities and has a gasoline throughput greater than 20,000 gallons per day (75,700 liters per day). The Cedar City Transloading facility has a capacity to exceed 20,000 gallons of gasoline throughput each day. Therefore, this subpart applies to the affected facilities. NSPS Subpart IIII Owners and operators of stationary CI ICE that commence construction after July 11, 2005 are subject to 40 CFR Part 60, Subpart IIII (Standards of Performance for Stationary Compression Ignition Internal Combustion Engines). The provisions of Subpart IIII are applicable to four (4) 48 hp, diesel-fired engines that is compliant with 2013 EPA Tier 4f standards. These engines are not designated as nonroad and are therefore not exempt from meeting the provisions of NSPS Subpart IIII. MACT Subpart ZZZZ The stationary engines on site are subject to 40 CFR Part 63, Subpart ZZZZ (National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines). The provisions of MACT Subpart ZZZZ apply as the stationary reciprocating internal combustion engines (RICE) are at an area source of HAP emissions. All engines not designated as nonroad and not exempt are affected sources under this regulation. The stationary engines on site that are subject to MACT Subpart ZZZZ must meet the requirements of NSPS Subpart IIII. No further requirements apply to the engines under MACT Subpart ZZZZ. MACT Subpart BBBBBB The provisions of Subpart BBBBBB (National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities) apply to bulk gasoline terminals. The Cedar City Transloading Facility is considered a bulk gasoline terminal; therefore, MACT Subpart BBBBBB applies to this facility. [Last updated October 16, 2024] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 15 2. Comment regarding Title V Applicability: Title V of the 1990 Clean Air Act (Title V) applies to the following: 1. Any major source 2. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources; 3. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants. 4. Any Title IV affected source. This facility is not a major source and is not a Title IV source. The facility is not subject to 40 CFR 61 (NESHAP) regulations. This facility is subject to 40 CFR 60 (NSPS) Subparts A, XXa, and IIII and 40 CFR 63 (MACT) Subparts A, ZZZZ, and BBBBBB. Section 60.4200(c) of NSPS Subpart IIII, section 63.6585(d) of MACT Subpart ZZZZ, and section 63.11081(b) of MACT Subpart BBBBBB each exempt the source from the obligation to obtain a permit under Title V, provided the source is not required to obtain a Title V permit for another reason. However, NSPS Subpart XXa does not include this exemption. Therefore, Title V applies to this facility as an area source. [Last updated October 16, 2024] 3. Comment regarding Source Emission Estimates and DAQ Acceptance: Liquid Loading Emission estimates from the loading of organic and inorganic liquids were calculated using Equation 1 from AP-42, Chapter 5.2 Transportation and Marketing of Petroleum Liquids dated June 2008. The calculations were conservatively based on a maximum operating schedule of 8,760 hours per year (24 hours/day, 7 days/week and 52 weeks/year). It is reasonably assumed that the vapor capture system and annual leak testing will reduce the VOC and HAPs emissions by approximately 98% Fugitive Leaks Emissions were calculated based on U.S. EPA's Protocol for Equipment Leak Estimates (EPA453/R- 95-017), and data from a similar Savage transloading facility located in Price, Utah. Dry Bulk Goods Loading Emission factors for the loading of dry bulk goods were calculated using AP-42 Chapter 11.19.2 Crushed Stone Processing and Pulverized Mineral Processing. Emissions from dry bulk goods materials handling were calculated using Equation 1 from AP-42, Chapter 13.2.4 Aggregate Handling and Storage Piles. The loading conveyor is equipped with a baghouse with a 99% control efficiency to reduce dust emissions from dry bulk transloading operations. Haul Roads Emissions estimations from haul roads were calculated from AP-42, Chapter 13.2.2 Paved Roads. 48 hp Diesel Engines Emissions estimations from the diesel engines were calculated from EPA's Tier 4i emission standards and AP-42, Chapter 3.3 Gasoline and Diesel Industrial Engines. The calculations were conservatively based on a maximum operating schedule of 8,760 hours per year. [Last updated October 2, 2024] Engineer Review N161390002: Savage Services Corporation- Cedar City Transloading Facility November 2, 2024 Page 16 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Throughputs Grain LoadingBulk Minerals 210,000 tpy PM10 EF 0.06Conveyor150,000 tpy PM2.5 EF 0.01Pneumatic60,000 tpy Rate 100Flyash150,000 tpy Control (dust collecto 0.99 Grains 15,000 tpy lb/hr Bulk Minerals - Conveyor PM10 0.060 PM10/2.5 EF 0.003 lb/ton PM2.5 0.060Rate100ton/hrControl (dust collector)0.99 lb/hr tpy PM10 0.003 0.002 PM2.5 0.003 0.002 Bulk Minerals - PnuetmaticPM10 EF 0.06 lb/tonPM2.5 EF 0.01 lb/ton Rate 100 ton/hr Control (dust collector)0.99 lb/hr tpyPM100.060 0.018PM2.5 0.060 0.003 lb/tonlb/tonton/hr tpy 0.0050.001 Low VP Organic Liquids45 million gallon transferred/yr Ll = (12.46) SPM/T P-42 Section 5.2: Transportation And Marketing O LL = loading loss, pounds per 1000 gallons (lb/103 gal) of liquid loaded S = a saturation factor (see Table 5.2-1)S 0.6P = true vapor pressure of liquid loaded, pounds per square inch absolute (psia)M = molecular weight of vapors, pounds per pound-mole (lb/lb-mole)T = temperature of bulk liquid loaded, °R (°F + 460) Sample Calculation Organic no control 0.09 lb/1000 gal Highest P 0.05 Max annual throughput (gallon)Highest M 130 45000000Lowest T 525 VOC Emission 4165.2 lb/yr 0.5 lb/hr 2.1 ton/yr Gasoline 22.5 million gallon transferred/yr Ll = (12.46) SPM/T P-42 Section 5.2: Transportation And Marketing O LL = loading loss, pounds per 1000 gallons (lb/103 gal) of liquid loaded S = a saturation factor (see Table 5.2-1)S 1 P = true vapor pressure of liquid loaded, pounds per square inch absolute (psia) M = molecular weight of vapors, pounds per pound-mole (lb/lb-mole)T = temperature of bulk liquid loaded, °R (°F + 460) Sample CalculationOrganic no control 11.06 lb/1000 gal Highest P 7.5 Max annual throughput (gallon) Highest M 62 22,500,000 Lowest T 524 VOC Emission0.987 % control 3234.2 lb/yr0.4 lb/hr1.6 ton/yr Throughputs Gasoline 22,500,000 Ethanol 22,500,000 Of Petroleum Liquids Propane/Butane/LPG 12,000,000 *for submerged Low VP Organic Liquids 45,000,000 Propane/Butane/LPG 0.21 tpy VOC 0.21 Ethanol 22.5 million gallon tr Of Petroleum Liquids Ll = (12.46) SPM/T LL = loading loss, pounds per 1000 *for submerged and vapor balance S = a saturation factor (see Table 5. P = true vapor pressure of liquid load M = molecular weight of vapors, pou T = temperature of bulk liquid loaded Sample CalculationcontrolledOrganic 0.14 lb/1000 gal ***only if annually tested for leaks *NSPS level annual Highest P 0.75 Highest M 46 Lowest T 524 0.987 % control gal/yrgal/yr gal/yr gal/yr ransferred/yr P-42 Section 5.2: Transportation And Marketing Of Petroleum Liquids gallons (lb/103 gal) of liquid loaded .2-1)S 1 *for submerged ded, pounds per square inch absolute (psia) unds per pound-mole (lb/lb-mole) d, °R (°F + 460) no control controlled 0.82 lb/1000 gal 0.01 Max annual throughput (gallon)***only if annually tested for leaks *NSPS level annual leak* 22500000 VOC Emission240.0 lb/yr0.0 lb/hr0.1 ton/yr PM10/PM2.5 EF 2.3 lb/ton Max transfer:1,000 tons Control 70 % Total Pollutant Rate (lbs/hr) Total (tons/year)Pollutant Total (tons/yea PM10 0.29 0.35 PM10 0.48 PM2.5 0.29 0.35 PM2.5 0.37 Production Rates Hourly Rates 100 tons/hour Annual Production 150,000 tons/year Variables Number of Transfer P 2 Mean Wind Speed 14 mph Moisture Content 6 % Pollutant Emission Emission Emission ReferencePM100.00092 0.18 0.14PM2.5 0.00014 0.03 0.02 Storage Pile Material Handling AP-42 13.2.4.3 Equation #1 Fugitives Table 2-3 in EPA's Protocol for Equipment Emission Leak Estimates (EPA-435/R-95-017) Propane kg/hr lb/hrValvesGas1.30E-05 8.90E-03 5 4.45E-02 LL 4.30E-05 3.50E-03 10 3.50E-02 Flanges Gas 4.20E-05 2.90E-03 15 4.35E-02 LL 8.00E-06 5.00E-04 30 1.50E-02 Pump Seals Gas 0.00E+00 0.00E+00 0 0.00E+00LL5.40E-04 0.00E+00 0 0.00E+00PRVsGas1.20E-04 2.29E-01 1 2.29E-01CompressorsGas1.20E-04 5.00E-01 1 5.00E-01 Control 30 %0.867 lb/hr 2.6582 tpy Gasoline 0.41 tpyEthanol0.41 tpy ) for Petroleum Marketing Terminal Equipment DetailsRating 48 hp = (35.9 kw)Operational Hou 8,760 hours/yearSulfur Content 15 ppm or 0.0015% Criteria Emission Emission Emission Emission Reference NOX 3.45 0.37 1.54 CO 4.1 0.43 1.90PM100.02 0.00 0.01PM2.5 0.02 0.00 0.01VOC0.18 0.02 0.08SO21.21E-05 0.00 0.00 AP-42 Table HAP 0.00 0.01 See Below Green House Global Emission Emission Emission Reference CO2 (mass basi 1 1.15 55 242Methane (mass 25 0 0CO2e242 Hazardous Air Emission Emission Reference Benzene 9.33E-04 3.13E-04 1.37E-03 Toluene 4.09E-04 1.37E-04 6.02E-04 Xylenes 2.85E-04 9.58E-05 4.19E-04 1,3-Butadiene 3.91E-05 1.31E-05 5.75E-05 Formaldehyde 1.18E-03 3.96E-04 1.74E-03Acetaldehyde7.67E-04 2.58E-04 1.13E-03Acrolein9.25E-05 3.11E-05 1.36E-04Naphthalene8.48E-05 2.85E-05 1.25E-04 Acenaphthylene 5.06E-06 1.70E-06 7.45E-06 Acenaphthene 1.42E-06 4.77E-07 2.09E-06 Fluorene 2.92E-05 9.81E-06 4.30E-05 Phenanthrene 2.94E-05 9.88E-06 4.33E-05 Anthracene 1.87E-06 6.28E-07 2.75E-06Fluoranthene7.61E-06 2.56E-06 1.12E-05Pyrene4.78E-06 1.61E-06 7.03E-06Benz(a)anthracene 1.68E-06 5.64E-07 2.47E-06Chrysene3.53E-07 1.19E-07 5.20E-07 Benzo(b)fluoranthene 9.91E-08 3.33E-08 1.46E-07 Benzo(k)fluoranthene 1.55E-07 5.21E-08 2.28E-07 Benzo(a)pyrene 1.88E-07 6.32E-08 2.77E-07 Indeno(1,2,3-cd)pyrene 3.75E-07 1.26E-07 5.52E-07 AP-42 Table 3.3-2, Table 3.4-3, & Table 3.4-4 (1,3-Butadiene will not popluate if the engine size is greater than 600 hp. AP-42 does not list 1,3- Butadiene for engines greater than 600 hp.) Diesel-Fired Engines Emergency Engines should equal 100 hours of operation per year Manufacturer Data, AP-42 Table 3.3-1, & Table 3.4-1 AP-42 Table 3.3-1 & Table 3.4-1 Emission Factor Dibenz(a,h)anthracene 5.83E-07 1.96E-07 8.58E-07Benzo(g,h,l)perylene 4.89E-07 1.64E-07 7.20E-07 Criteria Bulk/Grain Organic Loading Gypsum Handling FugitivesNOXCOPM100.025 0.48PM2.5 0.006 0.37SO2VOC4.03 3.48 HAPs Formaldehyde Hexane 0.02Benzene0.1 0.0300Toluene0.41 0.1000AcetaldehydeNaphthalnese0.1 Xylene 0.1 0.06 Ethyl Benzene 0.02 Other 0.08 1,2,4 Trimethyl Benzene 0.08 0.02 TotalEnginesHaul 6.16 6.16 7.60 7.600.04 0.01 0.560.04 0.00 0.410.01 0.01 0.32 7.83 0.00 0.02 0.140.130.510.00 0.16 0.02 0.080 0.100 1.00 Discepancies are <0.25 TPY - NOI Calculations Accepted Page 1 of 1 Company___________________________ Site _____________________________ Form 5 Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants** (**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed Jccumonl Dcjlc: 02/28/2018 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __100_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. ton/hr 150,000 ton/yr Fly Ash Storage and Loading Fly ash will be unloaded from rail cars into a bucket elevator, and transferred to one of two storage silos. A dust collector will be used to minimize emissions from unloading from rail and loading into the silos. Fly ash will be transferred from silos to trucks and emissions for this transfer will be controlled by a dust collector as well. Fly Ash 150,000 tons Fly Ash Silos and Loading 100 tph 2024 Transfer and temporary storage of fly ash Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 07/31/2018 Fly Ash (All Types) Page 1 of 6 Safety Data Sheet Fly Ash (All Types) Date Prepared: 10/01/2020 SECTION 1: IDENTIFICATION 1.1 Product Identifier Product Name: Fly Ash, Class C fly ash, Class F fly ash, blends of Class C and F fly ash, Economizer Ash, Bottom Ash 1.2 Intended Use of the Product Component of wallboard, concrete, asphalt, roofing material, bricks, cement kiln feed functional filler and construction material for various civil engineering applications 1.3 Name, Address, and Telephone Number of the Responsible Party Company Bridgesource LLC. 730 North 1500 West Orem, UT 84057 (307) 382-7196 1.4 Emergency Telephone Number 1-800-424-9300 (CHEMTREC) SECTION 2: HAZARD(S) IDENTIFICATION 2.1 Classification of the Substance or Mixture (GHS-US) Skin Irritation 2 Eye Irritation 2A STOT-SE (Single Exposure) 2 (Respiratory) STOT-RE (Repeated Exposure) 1 (Respiratory) Carcinogenicity 1A 2.2 Label Elements Hazard Pictograms: Signal Word:  Danger Hazard Statements:  Causes skin irritation. (H315)  Causes serious eye irritation. (H319)  May cause respiratory irritation. (H335)  May cause cancer (H350) Causes respiratory harm through prolonged or repeated exposure. (H372) Precautionary Statements:  Do not handle until all safety precautions have been read and understood. (P202)  Avoid breathing dust. (P261)  Wash hands, forearms, and other exposed areas thoroughly after handling. (P264)  Wear protective gloves, protective clothing, and eye protection. (P280)  IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. (P301) (P330) (P331)  IF ON SKIN (OR HAIR): Remove all contaminated clothing immediately. Rinse skin with water/shower. (P303) (P353) (P361)  IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. (P304) (P340)  IF IN EYES: Rinse cautiously with water for at least 15 minutes. Remove contact lenses if present and easy to do. Continue rinsing until pain or irritation subsides. (P305) (P338) (P351)  If symptoms persist: Get medical advice/attention. (P308) (P313)  Remove contaminated clothing and wash before re-use. (P362) (P364) 07/31/2018 Fly Ash (All Types) Page 2 of 6 2.3 Other Hazards Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. Repeat inhalation exposure may cause obstructive pulmonary disease, chronic bronchitis, silicosis, and cancer. 2.4 California Proposition 65: WARNING: CANCER—www.P65Warnings.ca.gov SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description of Product Fly Ash—All Types 3.2 Mixture Ingredients and Hazard Classification Ingredient Product Identifier (CAS No.) % (w/w) Hazard Classification (GHS-US) Fly ash combustion residue (amorphous calcium-aluminum silicates)* 68131-74-8 70 – 90  Skin Irritation 2, H315  Eye Irritation 2A, H319  STOT-SE (Single Exposure) 3 (Respiratory), H332  STOT-RE (Repeated Exposure) 1 (Respiratory), H373 Crystalline silica 14808-60-7 < 16 < 2.1 (respirable fraction)  STOT-RE (Repeated Exposure) 1 (Respiratory), H373  Carcinogenicity 1 (H350) Calcium oxide 1305-78-8 < 30  Skin Irritation 2, H315  Eye Irritation 1, H320 Potassium oxide 12136-45-7 1 – 5  Skin Irritation 2, H315  Eye Irritation 2A, H319 Phosphorus pentoxide 1314-56-3 < 2  Skin Corrosivity 1, H313  Eye Irritation 1, H319 *Fly ash and other CCPs are UVCB substances (substance of unknown or variable composition or biological). Fly ash is defined by the U.S. EPA as: “The residuum from the burning of a combination of carbonaceous materials. The following elements may be present as oxides: aluminum, calcium, iron, magnesium, nickel, phosphorus, potassium, silicon, sulfur, titanium, and vanadium.” The exact composition of fly ash is dependent on the fuel source and flue additives composed of many constituents. The classification of the final substance is dependent on the presence of specific identified oxides as well as other trace elements. SECTION 4: FIRST AID MEASURES 4.1 Description of First Aid Measures General: Never give anything by mouth to an unconscious person. Any person who is experiencing symptoms of injury or illness should be moved to a comfortable area with fresh air, and the label or SDS of this material reviewed. If feeling unwell, seek medical advice. Inhalation: Move person to fresh air. Provide drinking water, if conscious, to flush mouth and irrigate upper respiratory tract. Seek medical attention if pain, coughing or other symptoms do not subside. Eye Contact: If the exposed person experiences burning eye irritation due to dust exposure, careful flushing with clean water should continue for at least 15 minutes. If contact lenses are present, they should be removed after flushing if easy to do. Continue flushing. Obtain medical attention if irritation persists. Skin: Flush skin with plenty of water until irritation subsides. If irritation persists, obtain medical assistance. Wash contaminated clothing before re-use. Ingestion: Ingestion of this material is not an expected route of exposure. Rinsing mouth with water is appropriate. 4.2 Most Important Symptoms and Effects—Both Acute and Delayed General: The most important symptoms and effects from exposure to this material after contact with dust are eye and skin irritation. Breathing dust can cause respiratory irritation and respiratory system chronic illness if significant exposures occur repeatedly. Inhalation: The immediate acute response to dust inhalation is respiratory system irritation. Upon repeated dust exposure at levels exceeding regulatory limits, crystalline silica content of the dust may cause delayed or chronic respiratory illnesses, including silicosis and cancer. Eye Contact: Exposures of the eyes to dust may result in irritation, which must be treated immediately with first aid (Section 4) followed by medical attention if irritation persists. 07/31/2018 Fly Ash (All Types) Page 3 of 6 Skin Contact: Skin contact can cause irritation. 4.3 Indication of Immediate Medical Attention and Special Treatment Any time symptoms of eye or respiratory irritation occur, immediate first aid should be provided as described in Section 4.1, and medical attention should be obtained if irritation persists. SECTION 5: FIRE-FIGHTING MEASURES 5.1 Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Material is not combustible. 5.2 Special Hazards Arising from the Substance or Mixture Fire Hazard: Not combustible. Explosion Hazard: Material is not explosive. Reactivity: Material is not reactive. 5.3 Advice for Firefighters Not applicable. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions, Protective Equipment, and Emergency Procedures General Measures: Do not breathe dust. Do not get dust in eyes or on skin. 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protective equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Personnel Protective Equipment: Equip responders and clean-up personnel with proper protection, including appropriate clothing, eye and face protection. Respiratory protection should be used as necessary to prevent dust exposure. Emergency Procedures: Ventilate area if dust is generated. 6.2 Environmental Precautions Reuse material as appropriate to avoid disposal. 6.3 Methods and Material for Containment and Clean-Up Containment: Contain and collect as any solid. Avoid actions that cause dust to become airborne. Do not breathe dust, and do not allow large quantities of dust or wetted material to contact skin or eyes. 6.4 Reference to Other Sections See Section 8. Exposure Controls and Personal Protection. For waste management information, refer to Section 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for Safe Handling Additional Hazards when Processed: Dust will be generated when transferring this material. Use engineered controls and other practices to control dust. Personal Protective Equipment (PPE) described in Section 8 should be used as necessary. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking, and again when leaving work. 7.2 Conditions for Safe Storage, Including any Incompatibilities Not applicable. 7.3 Specific End-Use(s) No applicable limits. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Exposure Limits The following exposure limits are based on a time-weighted full-shift exposure, unless otherwise noted. Ingredient OSHA PEL(1) ACGIH-TLV(2) Other Fly ash combustion residues(3) (amorphous calcium-aluminum silicates) 15 mg/m3 (total) 5 mg/m3 (respirable) 10 mg/m3 (total) 3 mg/m3 (respirable) Crystalline silica(3) (respirable fraction) 50 µg/m3 (respirable) 0.025 mg/m3 (respirable) 0.05 mg/m3 (respirable)(4) Calcium oxide 5 mg/m3 (total) 2 mg/m3 (total) 2 mg/m3 (total)(4) 07/31/2018 Fly Ash (All Types) Page 4 of 6 Ingredient OSHA PEL(1) ACGIH-TLV(2) Other Potassium oxide 2 mg/m3 (total, ceiling) 2 mg/m3 (total) 2 mg/m3 (total, ceiling)(4) Phosphorus pentoxide None Established None Established fn(1) OSHA PEL (Permissible Exposure Level) at 29 CFR 1910.1000) fn(2) ACGIH-TLV (American Conference of Governmental Industrial Hygienists-Threshold Limit Values 2018) fn(3) Crystalline silica is regulated by OSHA as Respirable Crystalline Silica (RCS) [29 CFR 1910.1053]. The amount of RCS in fly ash has been determined to be less than 4%. fn(4) NIOSH REL (National Institute for Occupational Safety and Health Recommended Exposure Limit) 8.2 Exposure Controls Appropriate Engineering Controls: Emergency eyewash equipment should be available in the immediate vicinity of any potential exposure. Use local exhaust or other suppression methods to maintain dust levels below exposure limits. Personal Protective Equipment: Protective goggles or safety glasses, gloves, protective clothing. Wear respiratory protection if dust is present when transferring or processing. Hand Protection: Protective gloves as appropriate to prevent irritation and other hand injuries. Eye and/or Face Protection: Approved safety glasses, goggles, and/or face-shield. Skin and Body Protection: Appropriate work clothing and footwear should be worn. Respiratory Protection: If exposure limits may be exceeded or irritation is experienced, approved respiratory protection should be worn in accordance with OSHA Respiratory Protection Standard [29 CFR 1910.134]. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on Basic Physical and Chemical Properties Physical State: Granular solid. Appearance: Flowable material—Various colors (gray to tan) Odor: Essentially odorless. Odor Threshold: Not applicable. pH: < 11 (in water) Evaporation Rate: Not applicable. Melting Point: Not applicable. Freezing Point: Not applicable. Boiling Point: Not applicable. Flashpoint: Not applicable. Auto-Ignition Temperature: Not applicable. Decomposition Temperature: Not applicable. Flammability (solid, gas): Not applicable. Lower Flammable Limit: Not applicable. Upper Flammable Limit: Not applicable. Vapor Pressure: Not applicable. Relative Vapor Density at 20° C: Not applicable. Relative Density: Not applicable. Specific Gravity: 2.2 – 2.8 Solubility: Slightly soluble in water. Partition Coefficient—N-Octanol/Water: Not applicable. Viscosity: Not applicable. Explosion Data—Sensitivity to Mechanical Impact: Not applicable. Explosion Data—Sensitivity to Static Discharge: Not applicable. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Hazardous reactions are not expected to occur under normal conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization or other reactions are not expected. For gas generation, see 10.6. 10.4 Conditions to Avoid Material can become airborne in moderate winds. Dry material should be stored in silos or other structures. Material stored outdoors should be covered or dampened to reduce dusting. 10.5 Incompatible Materials Not applicable. 10.6 Hazardous Decomposition Products Not expected under normal conditions. Wetted material, which contains ammonia, may release ammonia gas, which may result in nuisance odor or potential harmful exposure in a confined area. 07/31/2018 Fly Ash (All Types) Page 5 of 6 SECTION 11: TOXCOLOGICAL INFORMATION 11.1 Likely Routes of Exposure Skin Contact: Material may irritate unprotected skin. Eye Contact: Material may cause serious irritation of unprotected eyes. Inhalation: Respirable dust may be generated that if inhaled, can cause respiratory system irritation. Prolonged or repeated inhalation exposure may cause chronic respiratory illness, including silicosis and cancer. Ingestion: Not expected to be an exposure route of concern. 11.2 Symptoms Related to Physical, Chemical, and Toxicological Characteristics Immediate Effects: Irritation of skin, eyes, and respiratory tract due to dust inhalation or exposure of eyes and skin to material. Delayed and Chronic Effects: Inhalation of dust on a prolonged or repeated basis may result in chronic lung disease or silicosis, and may also result in lung cancer. 11.3 Numerical Measures of Toxicity The acute and chronic effects of exposure to this product’s dust have not been quantified. 11.4 Carcinogenicity The ingredient quartz, also known as crystalline silica, has been determined to be carcinogenic by the International Agency for Research on Cancer (IARC) and the National Toxicology Program (NTP). The potential cancer (H350) Hazard Class designation disclosed in Section 2 is conservative and based on the percentage of crystalline silica in this mixture product. Toxicological studies conducted on fly ash materials, including oral and inhalation repeated dose, as well as mutagenicity have shown no evidence of carcinogenic effects that, except for numerical percentage of crystalline silica and other potential carcinogenic substances included in OSHA GHHCS Guidance, classification as a carcinogen is not required. Reference: American Coal Ash Association Safety Data Sheet Guidance Document, May 2015. SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity No additional information available. 12.2 Persistence and Degradability Not available. 12.3 Bioaccumulative Potential Not available. 12.4 Mobility in Soil Not available. 12.5 Other Adverse Effects Not available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste Treatment Methods Waste Disposal Recommendations: Excess material should be re-used or recycled. Material as a waste is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) (40 CFR 261), but waste material should be prevented from entering sewer systems, surface waters or the environment. Dispose of waste material in accordance with all local, regional, national, provincial, territorial, and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1 DOT (U.S.) Not regulated for transport. 14.2 IMDG (Maritime Code) Not for transport. 14.3 IATA Not regulated for transport. 14.4 TDG (Canada) Not regulated for transport. 07/31/2018 Fly Ash (All Types) Page 6 of 6 SECTION 15: REGULATORY INFORMATION 15.1 U.S. Federal Regulations SARA Section 311/312 Hazard Classes (40 CFR 370) Reporting of fly ash is required if reporting threshold (10,000 pounds) is exceeded  Skin corrosion or irritation  Serious eye damage or irritation  Specific target organ toxicity (single or repeated exposure)—Respiratory SARA Section 313 Emission Reporting Fly ash is not a chemical listed at Part 372.65 Trace elements should be considered in TRI reporting. TSCA Inventory All constituents are included on the Toxic Substances Control Act Chemical Inventory (40 CFR 720) and exempt from inventory update reporting (40 CFR 710). 15.2 U.S. State Regulations State Right-to-Know Laws Fly ash contains hazardous substances subject to inventory reporting and other requirements of the Massachusetts, New Jersey, Pennsylvania and Rhode Island right-to-know laws. Component CAS No. Component CAS No. Calcium oxide 1305-78-8 Phosphorus pentoxide (or phosphorus oxide) 1314-56-3 Potassium oxide 12136-45-7 Silica – crystalline quartz 14808-60-7 References to Table: Massachusetts: 301 CMR 41, et seq. (January 16, 2015) New Jersey: New Jersey Revised Statutes 34:5A-5 (2016) and New Jersey Health Department List Pennsylvania: Title 34 Pennsylvania Code, Chapter 323 Rhode Island: Rhode Island General Laws Title 28, Chap. 21-3 List of Chemicals Note: These lists include specific chemicals and cross-references to other regulatory lists; for example, EPCRA § 313 and OSHA PELs at 29 CFR 1910.1000. California Proposition 65—Warning Required Refer to Section 2.4. 15.3 Canadian WHMIS Regulations Crystalline silica, titanium dioxide and other fly ash constituents are hazardous materials and subject to WHMIS 2015. 15.4 Other: HMIS and NFPA HMIS: NFPA: SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Party Responsible for Preparation of this Document BORAL RESOURCES LLC (801) 984-9400 Limitations The information and recommendations set forth herein are based on data we have in our possession, and we have reason to believe is accurate. It is, however, the user’s responsibility to determine the safety, toxicity, or suitability for his/her own use of the herein described product. Because the actions by others is beyond our control, Boral Resources LLC makes no warranty expressed or implied regarding accuracy of the data or the results to be obtained from the use thereof. NA GHS SDS TABLE B-1Emissions Summary Savage Services Cedar City, Utah VOC PM PM10 PM2.5 NOX SO2 CO (tpy)(tpy)(tpy)(tpy)(tpy)(tpy)(tpy) CONVLOAD Conveyor loading of bulk minerals -- 4.50E-03 1.65E-03 1.65E-03 -- -- -- PNEULOAD Pneumatic loading of bulk minerals --9.00E-04 3.30E-04 3.30E-04 ------GRAINLOAD Conveyor loading of bulk grains --0.03 0.01 1.50E-03 ------FLYUNLOAD Fly Ash Unloading --2.25E-03 8.25E-04 8.25E-04 ------FLYSILO1 Fly Ash Storage Silo 1 --1.13E-03 4.13E-04 4.13E-04 ------FLYSILO2 Fly Ash Storage Silo 2 --1.13E-03 4.13E-04 4.13E-04 ------ FLYLOAD Fly Ash Truck Loading --4.50E-03 1.65E-03 1.65E-03 ------ HAULROAD Haul road emissions --0.05 0.01 2.68E-03 ------ PILEGYP Gypsum storage pile --0.64 0.48 0.37 ------ CONVENG1 Conveyor Engine 1 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG2 Conveyor Engine 2 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90CONVENG3Conveyor Engine 3 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90CONVENG4Conveyor Engine 4 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90ORGLOADLow-vapor Pressure Organic loading 2.08 ------------ ORGFUG Low-vapor Pressure Organic loading fugitive components 0.06 -- -- -- -- -- -- BUTALOAD Pressurized butane loading 0.21 ------------ BUTAFUG Butane loading fugitive components 2.67 ------------ GASLOAD Gasoline loading 1.63 ------------ GASFUG Gasoline loading fugitive components 0.41 ------------ETHALOAD Ethanol loading 0.12 ------------ETHAFUG Ethanol loading fugitive components 0.41 ------------ Totals 7.90 0.77 0.55 0.42 6.17 0.01 7.60 lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy CONVLOAD Conveyor loading of bulk minerals -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- PNEULOAD Pneumatic loading of bulk minerals ----------------------------------------GRAINLOAD Conveyor loading of bulk grains ----------------------------------------HAULROAD Haul road emissions ----------------------------------------PILEGYP Gypsum storage pile ---------------------------------------- CONVENG1 Conveyor Engine 1 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 -------- CONVENG2 Conveyor Engine 2 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 -------- CONVENG3 Conveyor Engine 3 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 -------- CONVENG4 Conveyor Engine 4 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 -------- ORGLOAD Low-vapor Pressure Organic loading 0.03 0.02 ----------------------------0.13 0.10 0.03 0.02 ORGFUG Low-vapor Pressure Organic loading fugitive components 1.38E-04 6.06E-04 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 6.91E-04 3.03E-03 1.38E-04 6.06E-04BUTALOADPressurized butane loading ----------------------------------------BUTAFUG Butane loading fugitive components ----------------------------------------GASLOAD Gasoline loading 0.17 0.08 0.87 0.41 0.21 0.10 0.17 0.08 ------------------------ GASFUG Gasoline loading fugitive components 0.00 0.02 0.02 0.10 0.01 0.06 0.01 0.02 ------------------------ ETHALOAD Ethanol loading 2.58E-03 1.21E-03 ------------------------------------ETHAFUG Ethanol loading fugitive components 9.26E-04 4.05E-03 ------------------------------------ Totals 0.21 0.13 0.89 0.51 0.22 0.16 0.18 0.10 1.95E-03 0.01 1.27E-03 0.01 1.53E-04 6.71E-04 2.78E-04 1.22E-03 0.13 0.11 0.03 0.02 1.65 1.05 Total Emission Totals Naphthalene Ethyl BenzeneFormaldehyde Acetaldehyde Acrolein Total PAH EPN Description Emission Totals EPN Description Benzene Toluene Xylene 1,2,4 Trimethyl Benzene TABLE B-15 Fly Ash Unloading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- FLYUNLOAD Material Loaded --Fly Ash Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 150,000 Drop Points 1 Material is loaded from the rail car to a bucket elevator PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 3.00E-03 2.25E-03 PM10 1.10E-03 8.25E-04 PM2.5 1.10E-03 8.25E-04 Unloading is enclosed and emissions routed to a dust collector tons of mineral per rail car 1,500 railcars per year AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 1 of 3 TABLE B-16 Fly Ash Storage Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- FLYSILO1, FLYSILO2 Material Loaded --Fly Ash Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 75,000 Drop Points 1 Material is loaded from the bucket elevator to the silo PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 3.00E-03 1.13E-03 PM10 1.10E-03 4.13E-04 PM2.5 1.10E-03 4.13E-04 Unloading is enclosed and emissions routed to a dust collector tons of fly ash per rail car 1,500 railcars per year, divided into two silos AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 2 of 3 TABLE B-17 Fly Ash Storage Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- FLYLOAD Material Loaded --Minerals Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 150,000 Drop Points 2 Material is loaded from the silo to the truck PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 6.00E-03 4.50E-03 PM10 2.20E-03 1.65E-03 PM2.5 2.20E-03 1.65E-03 Unloading is enclosed and emissions routed to a dust collector loading rate into trucks per hour Annual quantity in silos AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 3 of 3 TABLE B-1 Emissions Summary Savage Services Cedar City, Utah VOC PM PM10 PM2.5 NOX SO2 CO (tpy)(tpy)(tpy)(tpy)(tpy)(tpy)(tpy) CONVLOAD Conveyor loading of bulk minerals -- 4.50E-03 1.65E-03 1.65E-03 -- -- -- PNEULOAD Pneumatic loading of bulk minerals --9.00E-04 3.30E-04 3.30E-04 ------ GRAINLOAD Conveyor loading of bulk grains --0.03 0.01 1.50E-03 ------ HAULROAD Haul road emissions --0.05 0.01 2.68E-03 ------ PILEGYP Gypsum storage pile --0.64 0.48 0.37 ------ CONVENG1 Conveyor Engine 1 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG2 Conveyor Engine 2 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG3 Conveyor Engine 3 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG4 Conveyor Engine 4 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 ORGLOAD Low-vapor Pressure Organic loading 2.08 ------------ ORGFUG Low-vapor Pressure Organic loading fugitive components 0.06 ------------ BUTALOAD Pressurized butane loading 0.21 ------------ BUTAFUG Butane loading fugitive components 2.67 ------------ GASLOAD Gasoline loading 1.63 ------------ GASFUG Gasoline loading fugitive components 0.41 ------------ ETHALOAD Ethanol loading 0.12 ------------ ETHAFUG Ethanol loading fugitive components 0.41 ------------ Totals 7.90 0.76 0.55 0.41 6.17 0.01 7.60 EPN Description Emission Totals TABLE B-2 Conveyed Mineral Transloading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- CONVLOAD Material Loaded --Minerals Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 150,000 Drop Points 2 Material is loaded from the rail car to a conveyor and then conveyor to the truck PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 0.01 4.50E-03 PM10 2.20E-03 1.65E-03 PM2.5 2.20E-03 1.65E-03 tons of mineral per rail car 1,500 railcars per year AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 2 of 15 TABLE B-3 Pneumatic Mineral Loading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- PNEULOAD Material Loaded --Minerals Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 60,000 Drop Points 1 Material is loaded from the rail car to truck directly by pneumatic transfer PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 3.00E-03 9.00E-04 PM10 1.10E-03 3.30E-04 PM2.5 1.10E-03 3.30E-04 tons of mineral per rail car 600 railcars per year AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 3 of 15 TABLE B-4 Grain Transloading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- GRAINLOAD Material Loaded --Grain Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 15,000 Drop Points 2 Material is loaded from the rail car to a conveyor and then conveyor to the truck PM Emission Factor lb/ton 0.18 PM10 Emission Factor lb/ton 0.06 PM2.5 Emission Factor lb/ton 0.01 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 0.36 0.03 PM10 0.12 0.01 PM2.5 0.02 1.50E-03 See Documentation in Attachment 5 Grain and grain related products tons of grain per rail car 150 railcars per year AP-42 Chapter 9.9.1-1 Emission factor for straight truck receiving grain Page 4 of 15 TABLE B-5 TABLE B-5Haul Road Emissions (FIN/EPN HAULROAD)Haul Road EmissionsSavage ServicesCedar City, Utah Trucks Per Year 15,000Haul Road Round Trip Length 0.66 milesVehicle Miles Per Hour 1.14 miles Vehicle Miles Per Year 9,943 miles Type of Control Chip Seal or Asphalt (lb/hr)(tpy) PM 0.011 0.01 0.05PM100.0022 2.50E-03 0.01 PM2.5 0.00054 6.13E-04 2.68E-03 NOTES:1. Taken from AP-42 13.2.1-1 for paved roads E (lb/VMT) = k*(s/12)a*(W/3)b Where k is a particle size-specific constant for PM/PM10/PM2.5 s is the surface material silt content in %W is the mean vehicle weighta is a particle size-specific constant for PM/PM10/PM2.5 b is a particle size-specific constant for PM/PM10/PM2.5 Controlled Emissions Facility Information Pollutant Emission Factor (lb/VMT) [1] TABLE B-6 Low Vapor Pressure Organic Liquid Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) ORGLOAD ORGLOAD 2.59 2.08 Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- ORGLOAD Material Loaded --Organic Liquids Low-vapor pressure organic liquids including but not limited to diesel, biodiesel, kerosene, lube oil, and food oils. Naphthalene Fraction Mass Fraction 0.05 Based on Kerosene SDS Ethyl Benzene Fraction Mass Fraction 0.01 Based on Diesel Fuel SDS Benzene Fraction Mass Fraction 0.01 Conservative Assumption Hourly Maximum Fill Rate gal/hr 28,000 Rail Cars Loaded Per Day cars/day 10.0 Maximum of 10 railcars per day of low vapor pressure organics Maximum Railcars Per year cars/year 1,500 Maximum of 1,500 railcars per year of low vapor pressure organics Weight Capacity of Railcar lbs 133,000 Product Density lb/gal 7.1 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids for No. 2 Fuel Oil used as representative Product Volume Per Railcar gal 30,000 Based on maximum allowable weight capacity per railcar Annual Net Throughput gal/yr 45,000,000 Based on maximum number of jet fuel railcars per year (1500) Molecular Weight (M)lb/lb-mole 130 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Saturation Factor (S)dimensionless 0.60 EPA AP-42, Chapter 5, Table 5.2-1: Saturation Factors for submerged loading: dedicated service °F 65.00 Per Guidance to derive maximum hourly emission rate °R 524.67 Conversion 1 °R = °F + 459.67 °F Vapor Pressure (P)psia 0.05 A maximum vapor pressure of 0.05 psia is specified for this group (For reference diesel and jet naphtha are near 0.02 psia) Loading Loss [1]lb/1,000 gal 0.09 AP-42 Chapter 5 Loading Loss Equation LL= 12.46 SPM/T Vapor Balance Back [2]% 0.0% Hourly Loading Losses lb/hr 2.59 Annual Loading Losses tpy 2.08 Hourly Loading Losses Naphthalene lb/hr 0.13 Emission Rate * Mass Fraction Annual Loading Losses Naphthalene tpy 0.10 Emission Rate * Mass Fraction Hourly Loading Losses Ethyl Benzene lb/hr 0.03 Emission Rate * Mass Fraction Annual Loading Losses Ethyl Benzene tpy 0.02 Emission Rate * Mass Fraction Hourly Loading Losses Benzene lb/hr 0.03 Emission Rate * Mass Fraction Annual Loading Losses Benzene tpy 0.02 Emission Rate * Mass Fraction NOTES: EPN FIN Temperature (T) [1] Loading Loss (lb/Mgal) calculated from Saturation Factor, Vapor Pressure, Vapor Molecular Weight, and Temperature according to Equation 1 in AP-42, Section 5.2, Transportation and Marketing of Petroleum Liquids (dated June 2008). Saturation Factor equals 1.0 for vapor balancing. No Vapor Balancing Loading Loss * Maximum Fill Rate Loading Loss * Net Throughput" Page 6 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-7 Butane Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) BUTALOAD BUTALOAD 0.84 0.21 Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- BUTALOAD Material Loaded --Butane Length of Loading Hose ft 30 Diameter of Loading Hose ft 0.5 Volume of Loading Hose ft3 6 Number of Loading Events Per Year 500 Molecular Weight (M)lb/lb-mole 58.12 Molar Volume at 100 °F ft3/lbmol 408.69 Based on the ideal gas law. = Molar Volume at 519 R * 559 R/519 R = 379.5 * 559.67 R/519.67 R Mass of butane in the hose lb 0.84 Hourly Loading Losses lb/hr 0.84 Assuming 1 hose volume vented per hour as maximum Annual Loading Losses tpy 0.21 EPN FIN Page 7 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-8 Gasoline Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) GASLOAD GASLOAD 3.47 1.63 Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- GASLOAD Material Loaded --Gasoline* Benzene Fraction in the Material Mass Fraction 0.049 Based on SDS, assuming maximum content for each compound with a range given Toluene Fraction in the Material Mass Fraction 0.25 Based on SDS, assuming maximum content for each compound with a range given Xylene Fraction in the Material Mass Fraction 0.15 Based on SDS, assuming maximum content for each compound with a range given 1,2,4 TMB Fraction in the Material Mass Fraction 0.06 Based on SDS, assuming maximum content for each compound with a range given Hourly Maximum Fill Rate gal/hr 24,000 Rail Cars Loaded Per Day cars/day 5.0 Maximum of 5 railcars per day of gasoline Maximum Railcars Per year cars/year 750 Product Density lbs/gal 5.6 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Product Volume Per Railcar gal 30,000 Based on maximum allowable weight capacity per railcar for gasoline Annual Net Throughput gal/yr 22,500,000 Based on maximum number of gasoline railcars per day (5) Molecular Weight (M)lb/lb-mole 62 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Saturation Factor (S)dimensionless 1.00 EPA AP-42, Chapter 5, Table 5.2-1: Saturation Factors for submerged loading: dedicated vapor balance service °F 64.40 Annual Average Temperature °R 524.07 Conversion 1 °R = °F + 459.67 °F Vapor Pressure (P) psia 7.54 RVP 13 Gasoline; EPA AP-42 Chapter 7, Table 7.1-2 Properties of Selected Petroleum Liquids formular for vapor pressure Uncontrolled Loading Loss [1]lb/1,000 gal 11.11 AP-42 Chapter 5 Loading Loss Equation LL= 12.46 SPM/T Controlled Loading Loss lb/1,000 gal 0.144 Meets 0.640 lb/1,000 gallon requirement in UAC 307-328-4 Vapor Balance Back [2]% 98.7% Vapor balancing per Subpart XX Hourly Loading Losses VOC lb/hr 3.47 Loading Loss * Maximum Fill Rate Annual Loading Losses VOC tpy 1.63 Loading Loss * Net Throughput" Hourly Loading Losses Benzene lb/hr 0.17 Emission Rate * Mass Fraction Annual Loading Losses Benzene tpy 0.08 Emission Rate * Mass Fraction Hourly Loading Losses Toluene lb/hr 0.87 Emission Rate * Mass Fraction Annual Loading Losses Toluene tpy 0.41 Emission Rate * Mass Fraction Hourly Loading Losses Xylene lb/hr 0.21 Emission Rate * Mass Fraction Annual Loading Losses Xylene tpy 0.10 Emission Rate * Mass Fraction Hourly Loading Losses 1,2,4 TMB lb/hr 0.17 Emission Rate * Mass Fraction Annual Loading Losses 1,2,4 TMB tpy 0.08 Emission Rate * Mass Fraction NOTES: [2] Vapor balancing is used for the loading. Assumed control efficiency of 98.7% according to AP-42, Chapter 5.2 for NSPS Subpart XX level control tanker trucks. EPN FIN Temperature (T) [1] Loading Loss (lb/Mgal) calculated from Saturation Factor, Vapor Pressure, Vapor Molecular Weight, and Temperature according to Equation 1 in AP-42, Section 5.2. Saturation Factor equals 1.0 Page 8 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-9 Ethanol Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) ETHALOAD ETHALOAD 0.26 0.12 Loading Specifications Parameter Unit Basis/Comment/Description FIN/EPN -- ETHALOAD Material Loaded --Ethanol Benzene Fraction in the Material Mass Fraction 0.01 Based on SDS, assuming maximum content Hourly Maximum Fill Rate gal/hr 24,000 2 Ethanol pumps @ 200 gpm each = 400 gpm loading rate Rail Cars Loaded Per Day cars/day 5.0 Maximum of 20,000 gal/day (rolling 30 days) for Ethanol Maximum Railcars Per year cars/year 750 Based on 5 railcar/day per 5-day work week, up to a maximum of 20,000 gal/day (rolling 30 days) for Ethanol Weight Capacity of Railcar lbs 133,000 30,100 gallon capacity, with a 198,000 lb load limit and 65,000 lb tare weight, for a weight capacity of 133,000 lb Product Density lbs/gal 6.59 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Product Volume Per Railcar gal 30,000.0 Based on maximum allowable weight capacity per railcar, for each compound Annual Net Throughput gal/yr 22,500,000 Based on Ethanol for 750 cars per year Molecular Weight (M)lb/lb-mole 46.07 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Saturation Factor (S)dimensionless 1.0 EPA AP-42, Chapter 5, Table 5.2-1: Saturation Factors for submerged loading: dedicated vapor balance service °F 64.40 Annual Average Temperature °R 524.07 Conversion 1 °R = °F + 459.67 °F psia 0.75 Based on Antoine's equation and the constants for ethanol 250.96 Denominator term in Pva in psia formula from AP 42 Chapter 7 Loading Loss [1]lb/1,000 gal 0.83 AP-42, Chapter 5 Loading Loss Equation LL= 12.46 SPM/T Vapor Balance Back [2]% 98.7% Vapor balancing per Subpart XX Hourly Loading Losses lb/hr 0.26 Loading Loss * Maximum Fill Rate Annual Loading Losses tpy 0.12 Loading Loss * Net Throughput" Hourly Loading Losses Benzene lb/hr 2.58E-03 Emission Rate * Mass Fraction Annual Loading Losses Benzene tpy 1.21E-03 Emission Rate * Mass Fraction [2] Vapor balancing is used for the loading. Assumed control efficiency of 98.7% according to AP-42, Chapter 5.2 for NSPS Subpart XX level control tanker trucks. EPN FIN Temperature (T) [1] Loading Loss (lb/Mgal) calculated from Saturation Factor, Vapor Pressure, Vapor Molecular Weight, and Temperature according to Equation 1 in AP-42, Section 5.2. Saturation Factor equals 1.0 Vapor Pressure (P) Page 9 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-10 Butane Fugitives Savage Services Cedar City, Utah FIN/EPN BUTAFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 5 0.0089 30% 8,760 0.0312 0.1364 LL 10 0.0035 30% 8,760 0.0245 0.1073 HL 0 0.0007 30% 8,760 0 0 Flanges GV 15 0.0029 30% 8,760 0.0305 0.1334 LL 30 0.0005 30% 8,760 0.0105 0.0460 HL 0 0.00007 30% 8,760 0 0 Pump LL 0 0.0366 30% 8,760 0.000 0.0000 Seals HL 0 0.0161 30% 8,760 0 0 PRVs G/V 1 0.2293 30% 8,760 0.1605 0.7030 Compressors G/V 1 0.5027 30%8,760 0.3519 1.5413 Total Fugitive Piping Emissions 0.61 2.67 NOTES: [1] Component counts estimated by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for SOCMI without Ethylene [3] Savage is proposing use of a monthly physical inspection program Component Total VOC Transloading Arm and Vapor Balance Line - Butane Page 10 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-11 Low-Vapor Pressure Organic Liquid Fugitives Savage Services Cedar City, Utah FIN/EPN ORGFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 0 0.0000287 0% 8,760 0.00 0.00 LL 0 0.0000948 0% 8,760 0.00 0.00 HL 5 0.0000948 0% 8,760 0.00 0.00 Flanges GV 0 0.000092604 0% 8,760 0.00 0.00 LL 0 0.00001762 0% 8,760 0.00 0.00 HL 15 0.0000176 0% 8,760 0.00 0.00 Pump LL 0 0.00119 0% 8,760 0.00 0.00 Seals HL 11 0.00119 0% 8,760 0.01 0.06 PRVs G/V 0 0.0194 0% 8,760 0.00 0.00 Compressors G/V 0 0.0194 0%8,760 0.00 0.00 Total Fugitive Piping Emissions 0.01 0.06 NOTES: [1] Component counts estimated by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for Petroleum Marketing Terminals. [3] No control credit is taken since there is no LDAR program in place [4] Annual operation conservatively assumes that the lines will always be in VOC service. Component Total VOC Loading Arm for Low- VP Organics Page 11 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-12 Gasoline Fugitives Savage Services Cedar City, Utah FIN/EPN GASFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 2 0.0000287 0% 8,760 0.0001 0.0003 LL 5 0.0000948 0% 8,760 0.0005 0.0021 HL 0 0.0000948 0% 8,760 0 0 Flanges GV 12 0.000092604 0% 8,760 0.0011 0.0049 LL 27 0.00001762 0% 8,760 0.0005 0.0021 HL 0 0.0000176 0% 8,760 0 0 Pump LL 11 0.00119 0% 8,760 0.013 0.0573 Seals HL 0 0.00119 0% 8,760 0 0 PRVs G/V 2 0.0194 0% 8,760 0.0388 0.1699 Compressors G/V 2 0.0194 0%8,760 0.0388 0.1699 Total Fugitive Piping Emissions 0.09 0.41 NOTES: [1] Component counts provided by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for Petroleum Marketing Terminals. [3] The control credits for the 28PET visual inspection program are included in the emission factor. [4] Annual operation conservatively assumes that the lines will always be in VOC service. Transloading Arm and Vapor Balance Line - Gasoline Loading Component Total VOC Page 12 of 15 0499913\App B. Cedar City Emissions - updated.xlsx TABLE B-13 Ethanol Fugitives Savage Services Cedar City, Utah FIN/EPN ETHAFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 2 0.0000287 0% 8,760 0.0001 0.0003 LL 5 0.0000948 0% 8,760 0.0005 0.0021 HL 0 0.0000948 0% 8,760 0 0 Flanges GV 10 0.000092604 0% 8,760 0.0009 0.0041 LL 23 0.00001762 0% 8,760 0.0004 0.0018 HL 0 0.0000176 0% 8,760 0 0 Pump LL 11 0.00119 0% 8,760 0.013 0.0573 Seals HL 0 0.00119 0% 8,760 0 0 PRVs G/V 2 0.0194 0% 8,760 0.0388 0.1699 Compressors G/V 2 0.0194 0%8,760 0.0388 0.1699 Total Fugitive Piping Emissions 0.09 0.41 NOTES: [1] Component counts provided by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for Petroleum Marketing Terminals. [3] The control credits for the 28PET visual inspection program are included in the emission factor. [4] Annual operation conservatively assumes that the lines will always be in VOC service. Component Total VOC Transloading Arm and Vapor Balance Line - Ethanol Page 13 of 15 TABLE B-14 Gypsum Storage Pile Emissions Savage Services Cedar City, Utah Silt Content 2 % Storage Duration 365 Days Dry Days Per Year 300 daysPercentage of time Wind Exceeds 12 mph1 100 % 1. Conservative Assumption Storage Pile Erosion Emissions (tons)(lb/ton)(lb/yr)(%)(lb/hr)(tpy)(lb/hr)(tpy)(lb/hr)(tpy) 1,000 2.30 2,301.02 70.00%0.08 0.35 0.08 0.35 0.08 0.35 1. Taken From Iron and Steel Plant Open Source Fugitive Emission Evaluation, Equation 8 (EPA-600/2-79-103) 2. Water Spray Number of Drops 2 Wind Speed 14 mph Moisture1 6.00 % 1. Water Sprays on the gypsum pile, so assuming maximum water content the emission equation allows Storage Pile Material Transfer Emissions PM PM10 PM2.5 ton/yr ton/hr (lb/ton)(lb/ton)(lb/ton)(lb/hr)(tpy)(lb/hr)(tpy)(lb/hr)(tpy) 150,000 100 1.94E-03 9.17E-04 1.39E-04 0.19 0.29 0.09 0.14 0.01 0.02 1. Taken from AP-42, Section 13.2.4, Equation 1 for Material Pile Storage Total Emissions (lb/hr)(tpy)(lb/hr)(tpy)(lb/hr)(tpy) 0.27 0.64 0.17 0.48 0.09 0.37 Uncontrolled Emission Rate Control Efficiency2 Emission Factors1 Transfer Data Erosion Data PM PM10 PM2.5 Uncontrolled Emissions Annual Throughput Hourly Throughput PM PM10 PM2.5 Conctrolled Emission Rate PM PM10 PM2.5Pile Size Emission Factor1 Generator Specifications 48 hp 36 kW 0.138 MMBtu/gal 3.0 gal/hr 0.4 MMBtu/hr 1. 2. Criteria Pollutant Emission Calculations (g/kW-hr)(lb/gal)(kg/MMBtu)Reference (lb/hr)(tpy) NOX 4.47 1 0.35 1.54 SOX 2.13E-04 2 6.39E-04 2.80E-03 CO 5.50 1 0.43 1.90 VOC 0.24 1 0.02 0.08 PM 0.03 1 2.37E-03 0.01 CO2 7.40E+01 3 67.52 295.72 CH4 3.00E-03 3 2.74E-03 1.20E-02 N2O 6.00E-04 3 5.48E-04 2.40E-03 CO2e -- 67.75 296.73 1. 2 3 EPA Emission Factors for GHG Inventories v2020 Hazardous Air Pollutant Emission Calculations (lb/MMBtu)Reference (lb/hr)(tpy) Benzene 9.33E-04 1 3.86E-04 1.69E-03 Toluene 4.09E-04 1 1.69E-04 7.42E-04 Xylenes 2.85E-04 1 1.18E-04 5.17E-04 Formaldehyde 1.18E-03 1 4.89E-04 2.14E-03 Acetaldehyde 7.67E-04 1 3.18E-04 1.39E-03 Acrolein 9.25E-05 1 3.83E-05 1.68E-04 Total PAH 1.68E-04 1 6.96E-05 3.05E-04 1.59E-03 6.95E-03 1.US EPA AP-42, Section 3.4: Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines Tier 4 Standards for nonroad engines, assuming an 95/5 split between NOX and VOC Mass balance based on 15 ppm sulfur in ULSD fuel Pollutant Emission Factor Potential Emissions for One Generator Total HAP Fuel consumption at 100% load 1 Based on manufacturer data Permitting for 8,760 use, but engines will not be used continuously Pollutant Emission Factor Potential Emissions for One Conveyor Engine Rated capacity1 Annual operating hours2 8,760 Fuel type Diesel Fuel high heat value 3 Rated capacity1 Table B-14 Conveyor Engine Emissions Savage Services Cedar City, Utah EPN CONVENG1 to 4 Page 15 TABLE B-1Emissions Summary Savage Services Cedar City, Utah VOC PM PM10 PM2.5 NOX SO2 CO (tpy)(tpy)(tpy)(tpy)(tpy)(tpy)(tpy) CONVLOAD Conveyor loading of bulk minerals -- 4.50E-03 1.65E-03 1.65E-03 -- -- -- PNEULOAD Pneumatic loading of bulk minerals --9.00E-04 3.30E-04 3.30E-04 ------GRAINLOAD Conveyor loading of bulk grains --0.03 0.01 1.50E-03 ------HAULROAD Haul road emissions --0.05 0.01 2.68E-03 ------PILEGYP Gypsum storage pile --0.64 0.48 0.37 ------CONVENG1 Conveyor Engine 1 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG2 Conveyor Engine 2 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG3 Conveyor Engine 3 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 CONVENG4 Conveyor Engine 4 0.08 0.01 0.01 0.01 1.54 2.80E-03 1.90 ORGLOAD Low-vapor Pressure Organic loading 2.08 ------------ ORGFUG Low-vapor Pressure Organic loading fugitive components 0.06 -- -- -- -- -- --BUTALOAD Pressurized butane loading 0.21 ------------BUTAFUG Butane loading fugitive components 2.67 ------------GASLOAD Gasoline loading 1.63 ------------ GASFUG Gasoline loading fugitive components 0.41 ------------ ETHALOAD Ethanol loading 0.12 ------------ ETHAFUG Ethanol loading fugitive components 0.41 ------------ Totals 7.90 0.76 0.55 0.41 6.17 0.01 7.60 lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy lb/hr tpy CONVLOAD Conveyor loading of bulk minerals -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- PNEULOAD Pneumatic loading of bulk minerals ---------------------------------------- GRAINLOAD Conveyor loading of bulk grains ---------------------------------------- HAULROAD Haul road emissions ---------------------------------------- PILEGYP Gypsum storage pile ---------------------------------------- CONVENG1 Conveyor Engine 1 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 --------CONVENG2 Conveyor Engine 2 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 --------CONVENG3 Conveyor Engine 3 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 --------CONVENG4 Conveyor Engine 4 3.86E-04 1.69E-03 1.69E-04 7.42E-04 1.18E-04 5.17E-04 ----4.89E-04 2.14E-03 3.18E-04 1.39E-03 3.83E-05 1.68E-04 6.96E-05 3.05E-04 -------- ORGLOAD Low-vapor Pressure Organic loading 0.03 0.02 ----------------------------0.13 0.10 0.03 0.02 ORGFUG Low-vapor Pressure Organic loading fugitive components 1.38E-04 6.06E-04 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 6.91E-04 3.03E-03 1.38E-04 6.06E-04 BUTALOAD Pressurized butane loading ---------------------------------------- BUTAFUG Butane loading fugitive components ---------------------------------------- GASLOAD Gasoline loading 0.17 0.08 0.87 0.41 0.21 0.10 0.17 0.08 ------------------------GASFUG Gasoline loading fugitive components 0.00 0.02 0.02 0.10 0.01 0.06 0.01 0.02 ------------------------ETHALOAD Ethanol loading 2.58E-03 1.21E-03 ------------------------------------ETHAFUG Ethanol loading fugitive components 9.26E-04 4.05E-03 ------------------------------------ Totals 0.21 0.13 0.89 0.51 0.22 0.16 0.18 0.10 1.95E-03 0.01 1.27E-03 0.01 1.53E-04 6.71E-04 2.78E-04 1.22E-03 0.13 0.11 0.03 0.02 1.65 1.05 TotalEmission Totals Naphthalene Ethyl BenzeneFormaldehyde Acetaldehyde Acrolein Total PAH EPN Description Emission Totals EPN Description Benzene Toluene Xylene 1,2,4 Trimethyl Benzene Page 1 of 1 Company___________________________ Site _____________________________ Form 5 Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants** (**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed Jccumonl Dcjlc: 02/28/2018 BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 1 of 7 This Safety Data Sheet complies with the United States Occupational Safety and Health Administration (OSHA) and Global Harmonized System of Classification and Labeling of Chemicals (GHS) hazard communication standard. SECTION I – PRODUCT AND SUPPLIER IDENTIFICATION General Product Name Biodiesel (B99.9) Synonyms Fatty Acid Methyl Ester (FAME), methyl soyate Chemical Family Methyl Ester from Lipid Source with 0.1% petroleum diesel Formula C14‐C24 Methyl Ester CAS No. Mixture of Methyl Soyate 67784‐80‐9 and other fatty acid methyl esters and Petroleum Diesel 68476-30-2 Manufacturer American Biodiesel, Inc. d.b.a. Community Fuels 809-C Snedeker Avenue, Stockton, CA 95203 (209) 466.4823 (non-emergency) Emergency#: CHEMTREC 1-800-424-9300 SECTION II – HAZARDS IDENTIFICATION HAZARD CLASSIFICATION Hazard Class Hazard Category Route of Exposure Skin Irritation Category 2 (irritation) Absorption Eye Irritation Category 2B (mildly irritating) Absorption SIGNAL WORD – WARNING PICTOGRAM – HAZARD STATEMENT – Causes skin and eye irritation Routes of Entry: INHALATION: HAZARD STATEMENT - Negligible unless heated to produce vapors. Vapors or finely misted materials may cause irritation and inflammation of mucous membranes. Decomposition fumes may be hazardous. Avoid inhaling vapors, decomposition fumes, or finely misted material. EYE CONTACT: HAZARD STATEMENT - May cause irritation. Avoid contact with eyes. SKIN CONTACT: HAZARD STATEMENT - Prolonged or repeated contact is not likely to produce significant skin irritation. Thermal burns are possible if material is hot. INGESTION: HAZARD STATEMENT - No hazards anticipated from ingestion incidental to industrial BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 2 of 7 exposure. May cause nausea. PRECAUTIONARY STATEMENT – Biodiesel‐soaked rags or absorbents can cause spontaneous combustion if stored near combustibles and not handled properly. Store biodiesel‐soaked rags or absorbents in approved safety containers and dispose of properly. SECTION III – CHEMICAL COMPOSITION CHEMICAL CAS# %(v/v) Exposure Limits LC50 (Aq) LC50 (Skin) LD50 (Oral) Methyl Ester from Vegetables and Animal Fats 67784-80-9; other >= 99 OIL MIST: ACGIH: TWA ‐ 5mg/m3, STEL ‐ 10mg/m3 48‐hr, 2.8‐ 4.6 ug/L (trout)* Skin >2000 mg/kg* > 5000 mg/kg* Fuels, Diesel #2 68476-34-6 <=0.1 10 ppm TWA 50 mg/m3 TWA 15 ppm STEL 75 mg/m3 STEL 96 Hr, 35 mg/L (pimephales promelas) >2500 mg/kg 490 mg/kg BC-EC 1c Proprietary 0.05 None Acute EC 50 72-hr,9.4 mg/l (algae) 48-hr,5.4 mg/l (daphnia) 96-hr,1.2mg/l (fish) Chronic NEOC 0.028 mg/l (Daphnia) 0.037 mg/l (Fish) 7500 mg/kg 2700 mg/kg * Determined by applying rapeseed methyl and/or ethyl esters. SECTION IV – FIRST AID MEASURES Seek medical attention if symptoms persist. EYES Irrigate eyes with a heavy water stream for at least 15 minutes. SKIN Wash exposed area with soap and water. INHALATION Remove to fresh air. INGESTION Give one or two glasses of water to drink. Never give anything by mouth to an unconscious person. SECTION V – FIREFIGHTING MEASURES This material will burn although it is not easily ignited. Flash Point: >284o F (140o C) – ASTM Lower explosion Limit: ND BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 3 of 7 D93 COMBUSTIBLE LIQUID Sensitivity to Impact: Low Auto ignition temperature: ND Sensitivity to Static Discharge: Low Extinguishing Media: Unsuitable Extinguishing Media: Special Firefighting procedure: Dry chemical, foam, clean agent, CO2, water spray (mist). Water stream may splash the burning liquid and spread fire. Use water spray to cool containers exposed to fire. Unusual Fire Hazard: Hazardous Combustion Products: Biodiesel‐soaked rags or absorbents can cause spontaneous combustion if stored near combustibles and not handled properly. Store biodiesel‐soaked rags or absorbents in approved safety containers and dispose of properly. Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrocarbons NATIONAL FIRE PROTECTION ASSSOCIATION (NFPA) HAZARD INDEX: HEALTH 0 FLAMMABILITY 1 REACTIVITY 0 SPECIAL HAZARDS SECTION VI – ACCIDENTAL RELEASE MEASURES Remedial Measures (Small Spill) Remove sources of ignition away from spill. Contain spill to smallest area possible. Stop leak; use absorbent material. Wash hard surfaces with safety solvent or detergent to remove oil film to eliminate slipping hazards, then rinse area with water. Large Spill A spill remediation contractor with oil booms and skimmers may be needed for larger spills or spills that come into contact with a waterway or sensitive wetland. Recover as much product as possible by pumping it into totes or similar intermediate containers. Remove any remaining product with a properly rated vacuum system, absorbent inert media (oil dri, sand, or earth), or absorbent pads. Use soapy water or degreaser to remove oily residue from the affected area, then rinse with water. Place saturated materials in an appropriate oily waste container (i.e. metal can with a metal lid). Personal Protection Wear appropriate PPE when responding to a release. See Section VIII. Environmental Precautions Contain release to prevent further contamination of soil, surface water or groundwater. Biodiesel will create a sheen on water. Keep in suitable, closed containers for disposal. BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 4 of 7 Disposal Where feasible and appropriate, remove contaminated soil. Dispose of contaminated materials in a manner consistent with local, state, and federal regulations. Reporting U.S. regulations require reporting spills of this material that could reach any surface waters. SECTION VII ‐ HANDLING AND STORAGE Handling Procedures No smoking or open flame in storage, use or handling areas. Storage Store in closed containers. Keep away from oxidizing agents, excessive heat, and ignition sources. Store in well‐ventilated areas. Avoid storage for prolonged periods of time. Material compatibility, metals: Brass, bronze, copper, lead, tin, and zinc may accelerate the oxidation of diesel and biodiesel fuels and potentially create fuel insolubles (sediments) or gels and salts when reacted with some fuel components. Lead solders and zinc linings should be avoided, as should copper pipes, brass regulators, and copper fittings. Affected equipment should be replaced with stainless steel, carbon steel, or aluminum. Material compatibility, polymers: B100 will degrade, soften, or seep through some hoses, gaskets, seals, elastomers, glues, and plastics with prolonged exposure. Nitrile rubber compounds, polypropylene, polyvinyl, and Tygon materials are particularly vulnerable to B100. Materials such as Teflon, Vinton, fluorinated plastics, and Nylon are generally compatible with B100. SECTION VIII ‐ EXPOSURE CONTROLS AND PERSONAL PROTECTION EQUIPMENT Engineering Controls In confined areas, local and general ventilation should be provided. Respiratory protection If mists are generated, wear a NIOSH-approved particulate respirator. Skin protection Nitrile gloves are recommended to prevent skin contact. Eye and Face protection Safety glasses, goggles, or face shields are recommended to protect eyes and face from splash hazards. SECTION IX ‐ PHYSICAL AND CHEMICAL PROPERTIES Boiling Point >280° C/536° F (1 atm) Appearance Clear to dark orange liquid Specific Gravity 0.87 – 0.89 @ 25° C Odor Mild, oily/fatty Vapor Density >1 (Air = 1) Odor Threshold ND Evaporation Rate No Available Information Solubility in water Negligible Vapor Pressure No Available Information pH Not applicable Viscosity 3.8 – 5.0 cST @ 40° C Physical State Liquid BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 5 of 7 SECTION X ‐ STABILITY AND REACTIVITY General This product is stable and hazardous polymerization will not occur. Incompatible Materials Strong oxidizing agents, strong reducing agents, strong acids, and strong bases. Hazardous combustion products Combustion produces carbon monoxide, carbon dioxide, products of incomplete combustion, including particulates and thick smoke. Reactivity When handled and stored properly, no dangerous reactions are known. Chemical Stability Stable in closed containers at room temperature under normal storage and handling conditions. SECTION XI ‐ TOXICOLOGICAL INFORMATION Biodiesel Fuel Acute Toxicity Oral ‐ Albino rats treated with neat rapeseed methyl and ethyl esters and 50% or 20% blends of biodiesel/diesel resulted in no lethality, and LD50 values were reported to be greater than the highest dose used, 5000 mg/kg. Dermal ‐ Albino rats (males and females) were treated one time (for 24 hours) via dermal exposure with 100% biodiesel (rapeseed methyl ester or rapeseed ethyl ester), resulting in no lethality, and LC50 values were reported to be greater than the single dose used, 2000 mg/kg. Very slight to slight erythema (skin reddening/irritation) was noted for all animals. Skin corrosion/irritation (rat) after 24 hour exposure, some irritation which subsided within 12 – 14 days (human) after 24 hour exposure, some minor irritation (less than that of a 4% soap & water solution) Serious eye damage/eye irritation Industrial experience has shown that product in the eyes can cause redness and irritation which subsides within 7 days. Carcinogenicity Not listed as a carcinogen by IARC, NTP, or OSHA Component carcinogenicity Fuels, Diesel (0.1% by vol.) ACGIH Group A3: Confirmed animal carcinogen with unknown relevance to humans GHS/CLP: Carcinogenicity Category 2 BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 6 of 7 SECTION XII - ECOLOGICAL INFORMATION Acute ecotoxicity- short-term exposure Aquatic ‐ The 48 hour LC50 value for rapeseed methyl ester in rainbow trout was in the range of 2.8‐4.6 ug/L. For Daphnia magna, 48 hour LCSO’s for 100% rapeseed ethyl ester, 100% rapeseed methyl ester, 100% methyl soyate, and 100% diesel were reported to be 99, 23, 332, and cl.43 ppm, respectively. Biodegradability – Product is biodegradable in aerobic conditions (90% biodegraded within 23 days) SECTION XIII ‐ DISPOSAL INFORMATION This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). Review federal, provincial or state, and local government requirements prior to disposal. Store material for disposal as indicated in Section "Handling and Storage". Disposal by controlled incineration or by secure land fill may be acceptable. SECTION XIV ‐ TRANSPORT INFORMATION UN Hazard Class NA National Motor Freight Classification: Proper Shipping Name: Fatty Acid Ester Identification No.: 144920 Shipping Classification: 65 SECTION XV ‐ REGULATORY INFORMATION OSHA Status This product is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. However, thermal processing and decomposition fumes may be hazardous. Petroleum diesel fuel is hazardous under the criteria of the Federal OSHA Hazard Communication Standard. TSCA Status Product is listed on TSCA. DSL Status – This product is listed on DSL CERCLA (Comprehensive Response Compensation and Liability Act): Not reportable SARA TITLE III (Superfund Amendments and Reauthorization Act): Section 312 Extremely Hazardous Substances: None BIODIESEL (B99.9) SDS Revision: 1 Date: 06-25-2018 Community Fuels Biodiesel (B99.9) SDS Page 7 of 7 Section 311/312 Hazard Categories: Biodiesel Non-hazardous under section 311/312 Petroleum diesel fuel: Acute health hazard, chronic health hazard, fire hazard Section 313 Toxic Chemicals: This product contains the following component(s) that may be subject to reporting on the Toxic Release Inventory (TRI) from R: Naphthalene 0.1% de minimis concentration RCRA Status: If discarded in its purchased form, this product would not be a RCRA‐hazardous waste either by listing or by characteristic. However, under RCRA it is the responsibility of the product user to determine whether a material containing the product or derived from the product should be classified as hazardous waste. CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986. While biodiesel (B100) is not listed in the list of chemicals in Proposition 65, this product can contain up to 0.01% of methanol, which is listed as a chemical known to the State of California to cause cancer, birth, or any other reproductive defects. This product also contains up to 0.1% petroleum diesel fuel which contains a chemical known to the state of California to cause cancer. SECTION XVI ‐ OTHER Preparation Date: February 21, 2018 Prepared by: American Biodiesel, d.b.a. Community Fuels Revision: 0 Disclaimer: The information above is believed to be accurate and represents the best information currently available to us. Users should make their own investigations to determine the suitability of the information for their particular purposes. guide to the appropriate precautionary handling This document is intended as a of the material by a properly trained person using this product. However, no representation, warranty or guarantee of any kind, express or implied, is made as to its accuracy, reliability or completeness and we assume no responsibility for any loss, damage or expense, direct or consequential, arising out of use. Accordingly, Community Fuels will not be responsible for damages resulting from use of or reliance upon this information. _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 1 of 12 Renewable Diesel Fuel SDS : 47213 Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Renewable Diesel Fuel Product Use: Solvent, Fuel, Refinery feed stock Product Number(s): 204172990 ULS S R99 DF2, 204174990 CALCO ULS S R99 DF2, 204176990 CALCO ULS S R99 DF2 DYED, 270072990 ULS S R99 B0-5 DF2, 270073990 ULS S R99 B0-5 DF2 DYED, 270074990 CAL ULS S R99 B0-5 DF2, 270075990 CAL ULS S R99 B0-5 DF2DY Synonyms: Diesel R99 Company Identification Chevron Products Company 6001 Bollinger Canyon Rd. San Ramon, CA 94583 United States of America Transportation Emergency Response CHEMTREC: (800) 424-9300 or (703) 527-3887 Health Emergency Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or (510) 231-0623 Product Information Product Information: (800) 582-3835 SDS Requests: lubemsds@chevron.com SECTION 2 HAZARDS IDENTIFICATION _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 2 of 12 Renewable Diesel Fuel SDS : 47213 CLASSIFICATION: Flammable liquid: Category 3. Aspiration toxicant: Category 1. Carcinogen: Category 1B. Target organ toxicant (repeated exposure): Category 2. Signal Word: Danger Physical Hazards: Flammable liquid and vapor. Health Hazards: May be fatal if swallowed and enters airways. May cause cancer. Target Organs: May cause damage to organs (Blood/Blood Forming Organs, Liver, Thymus) through prolonged or repeated exposure. PRECAUTIONARY STATEMENTS: General: Keep out of reach of children. Read label before use. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Response: In case of fire: Use media specified in the SDS to extinguish. IF exposed or concerned: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Get medical advice/attention if you feel unwell. Storage: Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 3 of 12 Renewable Diesel Fuel SDS : 47213 HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER AMOUNT Fuels, diesel, C9-18 alkane branched and linear 1159170-26-9 95 - 100 %weight Diesel Fuel No. 2 - Vacuum Gas Oil category 68476-34-6 0 - 2 %weight SECTION 4 FIRST AID MEASURES Description of first aid measures Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical attention if any symptoms develop. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person. Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if breathing difficulties continue. Most important symptoms and effects, both acute and delayed IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Skin contact may cause drying or defatting of the skin. Symptoms may include pain, itching, discoloration, swelling, and blistering. Contact with the skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: Highly toxic; may be fatal if swallowed. Because of its low viscosity, this material can directly enter the lungs, if swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death. _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 4 of 12 Renewable Diesel Fuel SDS : 47213 Inhalation: Not expected to be harmful if inhaled. If this material is heated, fumes may be unpleasant and produce nausea and irritation of the eye and upper respiratory tract. DELAYED OR OTHER HEALTH EFFECTS: Cancer: Prolonged or repeated exposure to this material may cause cancer. Target Organs: Contains material that may cause damage to the following organ(s) following repeated exposure based on animal data:Liver Blood/Blood Forming Organs Thymus See Section 11 for additional information. Risk depends on duration and level of exposure. Indication of any immediate medical attention and special treatment needed Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light hydrocarbon liquid, which may cause pneumonitis. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unusual Fire Hazards: See Section 7 for proper handling and storage. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this material is released into the work area, evacuate the area immediately. Monitor area with combustible gas indicator. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 5 of 12 Renewable Diesel Fuel SDS : 47213 applying non-combustible absorbent materials or pumping. All equipment used when handling the product must be grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non- sparking tools to collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 as appropriate or required. SECTION 7 HANDLING AND STORAGE General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or fumes from heated material. Do not taste or swallow. Wash thoroughly after handling. Keep out of the reach of children. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 6 of 12 Renewable Diesel Fuel SDS : 47213 GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits. Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may include gloves, apron, boots, and complete facial protection depending on operations conducted. Suggested materials for protective gloves include: Nitrile Rubber, Viton. Respiratory Protection: No respiratory protection is normally required. Determine if airborne concentrations are below the recommended occupational exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits: Component Agency TWA STEL Ceiling Notation Fuels, diesel, C9-18 alkane branched and linear Not Applicable -- -- -- -- Diesel Fuel No. 2 - Vacuum Gas Oil category ACGIH 100 mg/m3 -- -- Skin A3 total hydrocarbon _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 7 of 12 Renewable Diesel Fuel SDS : 47213 Diesel Fuel No. 2 - Vacuum Gas Oil category CVX 100 mg/m3 -- -- Skin total hydrocarbon Consult local authorities for appropriate values. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Attention: the data below are typical values and do not constitute a specification. Color: Colorless Physical State: Liquid Odor: Hydrocarbon odor Odor Threshold: No data available pH: Not Applicable Vapor Pressure: No data available Vapor Density (Air = 1): No data available Initial Boiling Point: 179°C (354.2°F) - 309°C (588.2°F) Solubility: Insoluble in water. Freezing Point: No data available Melting Point: No data available Specific Gravity: 0.77 Density: 0.77 g/ml @ 15°C (59°F) Viscosity: 1.90 cSt - 4.10 cSt @ 40°C (104°F) Coefficient of Therm. Expansion / °F: No data available Evaporation Rate: No data available Decomposition temperature: No data available Octanol/Water Partition Coefficient: No data available FLAMMABLE PROPERTIES: Flammability (solid, gas): No Data Available Flashpoint: (Pensky-Martens Closed Cup) 52 °C (126 °F) (Minimum) Autoignition: 257 °C (495 °F) Flammability (Explosive) Limits (% by volume in air): Lower: 0.6 Upper: 4.7 _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 8 of 12 Renewable Diesel Fuel SDS : 47213 SECTION 10 STABILITY AND REACTIVITY Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: Not applicable Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components. Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials or product components. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or product components. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product components. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components. Acute Toxicity Estimate: Not Determined Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material. Carcinogenicity: The hazard evaluation is based on data for components or a similar material. _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 9 of 12 Renewable Diesel Fuel SDS : 47213 Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for components or a similar material. SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY This material is not expected to be harmful to aquatic organisms. The product has not been tested. The statement has been derived from the properties of the individual components. MOBILITY No data available. PERSISTENCE AND DEGRADABILITY This material is not expected to be readily biodegradable. The product has not been tested. The statement has been derived from products of a similar structure and composition. POTENTIAL TO BIOACCUMULATE Bioconcentration Factor: No data available. Octanol/Water Partition Coefficient: No data available SECTION 13 DISPOSAL CONSIDERATIONS Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by international, country, or local laws and regulations. SECTION 14 TRANSPORT INFORMATION _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 10 of 12 Renewable Diesel Fuel SDS : 47213 The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode- specific or quantity-specific shipping requirements. DOT Shipping Description: UN1202, GAS OIL, 3, III; ADDITIONAL INFORMATION: NON-BULK PACKAGES ARE NOT REGULATED IN THE U.S.A. UNLESS SHIPPED BY AIRCRAFT OR VESSEL PER 49 CFR 173.150(f). OPTIONAL DISCLOSURE UNLESS SHIPPED BY AIRCRAFT OR VESSEL: UN1202, GAS OIL, COMBUSTIBLE LIQUID, III IMO/IMDG Shipping Description: UN1202, GAS OIL, 3, III, FLASH POINT SEE SECTION 5 OR 9 ICAO/IATA Shipping Description: UN1202, GAS OIL, 3, III Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES 2. Delayed (Chronic) Health Effects: YES 3. Fire Hazard: YES 4. Sudden Release of Pressure Hazard: NO 5. Reactivity Hazard: NO REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 03=EPCRA 313 01-2A=IARC Group 2A 04=CA Proposition 65 01-2B=IARC Group 2B 05=MA RTK 02=NTP Carcinogen 06=NJ RTK 07=PA RTK The following components of this material are found on the regulatory lists indicated. _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 11 of 12 Renewable Diesel Fuel SDS : 47213 Diesel Fuel No. 2 - Vacuum Gas Oil category 07 CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: TSCA (United States). One or more components does not comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan). SECTION 16 OTHER INFORMATION NFPA RATINGS: Health: 1 Flammability: 2 Reactivity: 0 HMIS RATINGS: Health: 1* Flammability: 2 Reactivity: 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). REVISION STATEMENT: SECTION 01 - Product Code(s) information was modified. SECTION 01 - Product Identifier information was modified. SECTION 03 - Composition information was modified. SECTION 16 - HMIS Rating information was modified. Revision Date: November 16, 2018 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit GHS - Globally Harmonized System CAS - Chemical Abstract Service Number ACGIH - American Conference of Governmental Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods Code _____________________________________________________________________ Revision Number: 1 Revision Date: November 16, 2018 12 of 12 Renewable Diesel Fuel SDS : 47213 API - American Petroleum Institute SDS - Safety Data Sheet HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA) DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA) IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency SCBA - Self-Contained Breathing Apparatus Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001 Bollinger Canyon Road, San Ramon, CA 94583. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 1 of 14 ______________________________________________________________________________________________________________________ SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: NO. 2 DIESEL FUEL Product Description: Hydrocarbons and Additives Product Code: 123455-22, 123455-29, 152017-00 Intended Use: Diesel engine fuel, Heating Oil COMPANY IDENTIFICATION Supplier:EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX 77389 USA 24 Hour Health Emergency 609-737-4411 Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC Product Technical Information 800-662-4525 MSDS Internet Address www.exxon.com, www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is hazardous according to regulatory guidelines (see (M)SDS Section 15). CLASSIFICATION: Flammable liquid: Category 3. Acute inhalation toxicant: Category 4. Skin irritation: Category 2. Carcinogen: Category 2. Specific target organ toxicant (repeated exposure): Category 2. Aspiration toxicant: Category 1. LABEL: Pictogram: Signal Word: Danger Hazard Statements: Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 2 of 14 ______________________________________________________________________________________________________________________ H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H332: Harmful if inhaled. H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure. Bone marrow, Liver, Thymus Precautionary Statements: P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use.P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. P233: Keep container tightly closed. P240: Ground / bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, and lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe mist / vapours. P264: Wash skin thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P331: Do NOT induce vomiting. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P362 + P364: Take off contaminated clothing and wash it before reuse. P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish. P391: Collect spillage.P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.P501: Dispose of contents and container in accordance with local regulations. Contains: DIESEL OIL..C9-20 Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS Material can accumulate static charges which may cause an ignition. Material can release vapors that readily form flammable mixtures. Vapor accumulation could flash and/or explode if ignited. HEALTH HAZARDS May cause central nervous system depression. High-pressure injection under skin may cause serious damage. Under conditions of poor personal hygiene and prolonged repeated contact, some polycyclic aromatic compounds (PACs) have been suspected as a cause of skin cancer in humans. May be irritating to the eyes, nose, throat, and lungs. ENVIRONMENTAL HAZARDS Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. NFPA Hazard ID: Health: 2 Flammability: 2 Reactivity: 0 HMIS Hazard ID: Health: 2*Flammability: 2 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 3 of 14 ______________________________________________________________________________________________________________________ This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes DIESEL OIL..C9-20 68334-30-5 80 - > 99% H226, H304, H332, H351, H315, H373, H401, H411 Hazardous Constituent(s) Contained in Complex Substance(s) required for disclosure Name CAS#Concentration*GHS Hazard Codes ETHYL BENZENE 100-41-4 0.1 - 1% H225, H304, H332, H373, H401, H412 NAPHTHALENE 91-20-3 0.1 - 1% H228(2), H302, H351, H400(M factor 1), H410(M factor 1) * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. NOTE: Composition may contain up to 0.5% performance additives and / or dyes. As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph (i). SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 4 of 14 ______________________________________________________________________________________________________________________ PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Flammable. Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Vapors are flammable and heavier than air. Vapors may travel across the ground and reach remote ignition sources causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >38°C (100°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 7.0 Autoignition Temperature: >200°C (392°F) SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water- resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 5 of 14 ______________________________________________________________________________________________________________________ with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do it without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapor; but may not prevent ignition in closed spaces. Water Spill: Stop leak if you can do it without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 degrees C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid all personal contact. Do not siphon by mouth. Do not use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put fuel into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapors and cause fire. Place container on ground when filling and keep nozzle in contact with container. Do not use electronic devices (including but not limited to cellular phones, computers, calculators, pagers or other electronic devices, etc.) during safety critical tasks, such as bulk fuel loading or unloading operations, or in storage areas where vapors may be present, unless the devices are certified intrinsically safe by an approved national testing agency and to the safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid. Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 6 of 14 ______________________________________________________________________________________________________________________ STORAGE The type of container used to store the material may affect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be grounded and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit / Standard NOTE Source DIESEL OIL..C9-20 Stable Aerosol. TWA 5 mg/m3 Skin ExxonMobil DIESEL OIL..C9-20 Vapor.TWA 200 mg/m3 Skin ExxonMobil DIESEL OIL..C9-20 [total hydrocarb, vapor&aerosol] Inhalable fraction and vapor TWA 100 mg/m3 Skin ACGIH ETHYL BENZENE TWA 435 mg/m3 100 ppm N/A OSHA Z1 ETHYL BENZENE TWA 20 ppm N/A ACGIH NAPHTHALENE TWA 50 mg/m3 10 ppm N/A OSHA Z1 NAPHTHALENE TWA 10 ppm Skin ACGIH NOTE: Limits/standards shown for guidance only. Follow applicable regulations. Biological limits Substance Specimen Sampling Time Limit Determinant Source ETHYL BENZENE Creatinine in urine End of shift 0.15 g/g Sum of mandelic acid and phenylglyoxylic acid ACGIH BELs (BEIs) NAPHTHALENE No Biological Specimen provided End of shift Not Assigned 1-Naphthol, with hydrolysis + 2-Naphthol, with hydrolysis ACGIH BELs (BEIs) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Use explosion-proof ventilation equipment to stay below exposure limits. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 7 of 14 ______________________________________________________________________________________________________________________ with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: Half-face filter respirator For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves. Eye Protection: If contact with material is likely, chemical goggles are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Clear (May Be Dyed) Odor: Petroleum/Solvent Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 °C): 0.81 - 0.87 Density (at 15 ºC): 810 kg/m³ (6.76 lbs/gal, 0.81 kg/dm³) - 876 kg/m³ (7.31 lbs/gal, 0.88 kg/dm³) Flammability (Solid, Gas): N/A Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 8 of 14 ______________________________________________________________________________________________________________________ Flash Point [Method]: >38°C (100°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 7.0 Autoignition Temperature: >200°C (392°F) Boiling Point / Range: 145°C (293°F) - 370°C (698°F) Decomposition Temperature: N/D Vapor Density (Air = 1): > 2 at 101 kPa Vapor Pressure: 0.067 kPa (0.5 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 1.7 cSt (1.7 mm2/sec) at 40 °C - 4.1 cSt (4.1 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: < -6°C (21°F) SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Halogens, Strong Acids, Strong Bases, Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: (Rat) 4 hour(s) LC50 4100 mg/m3 (Vapor and aerosol) Moderately toxic. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 403 Irritation: No end point data for material.Elevated temperatures or mechanical action may form vapors, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Ingestion Acute Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 401 Skin Acute Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 434 Skin Corrosion/Irritation (Rabbit): Data Irritating to the skin. Based on test data for structurally similar Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 9 of 14 ______________________________________________________________________________________________________________________ available.materials. Test(s) equivalent or similar to OECD Guideline 404 Eye Serious Eye Damage/Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 405 Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: Data available.Not expected to be a skin sensitizer. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 406 Aspiration: Data available.May be fatal if swallowed and enters airways. Based on physico- chemical properties of the material. Germ Cell Mutagenicity: Data available.Not expected to be a germ cell mutagen. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 471 475 Carcinogenicity: Data available.Caused cancer in laboratory animals, but the relevance to humans is uncertain. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 451 Reproductive Toxicity: Data available.Not expected to be a reproductive toxicant. Test(s) equivalent or similar to OECD Guideline 414 Lactation: No end point data for material.Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: Data available.Concentrated, prolonged or deliberate exposure may cause organ damage. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 410 413 TOXICITY FOR SUBSTANCES NAME ACUTE TOXICITY ETHYL BENZENE Inhalation Lethality: 4 hour(s) LC50 17.8 mg/l (Vapor) (Rat); Oral Lethality: LD50 3.5 g/kg (Rat) NAPHTHALENE Inhalation Lethality: 4 hour(s) LC50 > 0.4 mg/l (Max attainable vapor conc.) (Rat); Oral Lethality: LD50 533 mg/kg (Mouse) OTHER INFORMATION For the product itself: Target Organs Repeated Exposure: Bone marrow, Liver, Thymus Vapor concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Diesel fuel: Caused cancer in animal tests. Caused mutations in vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. Diesel exhaust fumes: Carcinogenic in animal tests. Inhalation exposures to exhaust for 2 years in test animals resulted in lung tumors and lymphoma. Extract of particulate produced skin tumors in test animals. Caused mutations Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 10 of 14 ______________________________________________________________________________________________________________________ in vitro. Contains: NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain. ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations ETHYL BENZENE 100-41-4 5 NAPHTHALENE 91-20-3 2, 5 --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data for the material, components of the material, or for similar materials, through the application of bridging principals. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids. High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air ECOLOGICAL DATA Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 11 of 14 ______________________________________________________________________________________________________________________ Ecotoxicity Test Duration Organism Type Test Results Aquatic - Acute Toxicity 48 hour(s) Daphnia magna EL50 1 - 1000 mg/l: data for similar materials Aquatic - Acute Toxicity 96 hour(s) Fish LL50 1 - 100 mg/l: data for similar materials Aquatic - Acute Toxicity 72 hour(s) Pseudokirchneriella subcapitata EL50 1 - 100 mg/l: data for similar materials Aquatic - Chronic Toxicity 72 hour(s) Pseudokirchneriella subcapitata NOELR 1 - 10 mg/l: data for similar materials Persistence, Degradability and Bioaccumulation Potential Media Test Type Duration Test Results Water Ready Biodegradability 28 day(s) Percent Degraded < 60 : similar material SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: Disposal of unused product may be subject to RCRA regulations (40 CFR 261). Disposal of the used product may also be regulated due to ignitability, corrosivity, reactivity or toxicity as determined by the Toxicity Characteristic Leaching Procedure (TCLP). Potential RCRA characteristics: IGNITABILITY. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT) Proper Shipping Name: DIESEL FUEL Hazard Class & Division: COMBUSTIBLE LIQUID ID Number: NA1993 Packing Group: III Marine Pollutant: Yes ERG Number: 128 Label(s): NONE Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 12 of 14 ______________________________________________________________________________________________________________________ Transport Document Name: NA1993, DIESEL FUEL, COMBUSTIBLE LIQUID, PG III, MARINE POLLUTANT Footnote: The flash point of this material is greater than 100 F. Regulatory classification of this material varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid. This material is not regulated under 49 CFR in a container of 119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance. LAND (TDG) Proper Shipping Name: GAS OIL Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Special Provisions: 88, 150 SEA (IMDG) Proper Shipping Name: GAS OIL Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1202 Packing Group: III Marine Pollutant: Yes Label(s): 3 Transport Document Name: UN1202, GAS OIL, 3, PG III, (>38°C c.c.), MARINE POLLUTANT AIR (IATA) Proper Shipping Name: GAS OIL Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1202, GAS OIL, 3, PG III SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, KECI, PICCS, TSCA SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302 CERCLA: This material is not subject to any special reporting under the requirements of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA). Contact local authorities to determine if other reporting requirements apply. Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 13 of 14 ______________________________________________________________________________________________________________________ SARA (311/312) REPORTABLE GHS HAZARD CLASSES: Acute Toxicity (any route of exposure), Aspiration Hazard, Carcinogenicity, Flammable (gases, aerosols, liquids, or solids), Skin Corrosion or Irritation, Specific Target Organ toxicity (single or repeated exposure) SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ETHYL BENZENE 100-41-4 0.1 - 1% NAPHTHALENE 91-20-3 0.1 - 1% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIESEL OIL..C9-20 68334-30-5 1, 18 ETHYL BENZENE 100-41-4 1, 4, 10, 17, 19 NAPHTHALENE 91-20-3 1, 4, 10, 17, 19 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov. Chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm are created by the combustion of this product. This warning is given to comply with California Health and Safety Code 25249.6 and does not constitute an admission or a waiver of rights. N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H225: Highly flammable liquid and vapor; Flammable Liquid, Cat 2 H226: Flammable liquid and vapor; Flammable Liquid, Cat 3 H302: Harmful if swallowed; Acute Tox Oral, Cat 4 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H332: Harmful if inhaled; Acute Tox Inh, Cat 4 H351: Suspected of causing cancer; GHS Carcinogenicity, Cat 2 H373: May cause damage to organs through prolonged or repeated exposure; Target Organ, Repeated, Cat 2 H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 Product Name: NO. 2 DIESEL FUEL Revision Date: 22 Oct 2019 Page 14 of 14 ______________________________________________________________________________________________________________________ H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Composition: Component Table information was modified. Section 07: Handling and Storage - Handling information was modified. Section 12: information was modified. Section 14: Special Provisions information was added. THIS MSDS COVERS THE FOLLOWING MATERIALS: DIESEL EFFICIENT | DIESEL NO. 2 | ESSO DIESEL FUEL | EXXON DIESEL FUEL | EXXON SYNERGY DIESEL EFFICIENT | LOW SULFUR DIESEL | MARINE DIESEL FUEL | MOBIL DIESEL EFFICIENT | MOBIL DIESEL FUEL | MOBIL SYNERGY DIESEL EFFICIENT | ULTRA LOW SULFUR DIESEL | WINTERIZED DIESEL FUEL ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- Internal Use Only MHC: 1A, 0B, 2, 0, 4, 1 PPEC: C DGN: 7079307XUS (1012398) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Exxon Mobil Corporation, All rights reserved Safety Data Sheet (SDS) Kerosene Revision Date: 02/12/2022 1. Identification 1.1. Product identifier Product Identity Kerosene Alternate Names 1K Kerosene; K1; K-1; Kerosene 15PPM; Low Sulfur Kerosene; No. 1 Diesel; No. 1 , Heating Oil, Kerosene 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use Fuel 1.3. Details of the supplier of the safety data sheet Company Name Guttman Energy, Inc. 200 Speers Street Belle Vernon, PA 15012 United States www.guttmanenergy.com safety@guttmangroup.com Emergency 24 hour Emergency Telephone No. 1-800-535-5053 - INFOTRAC Customer Service: Guttman Energy, Inc. 2. Hazard(s) identification 2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Carc. 2;H351 Suspected of causing cancer. Asp. Tox. 1;H304 May be fatal if swallowed and enters airways. Aquatic Chronic 2;H411 Toxic to aquatic life with long lasting effects. 2.2. Label elements Danger H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. [Prevention] P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames, and other ignition sources - No smoking. P233 Keep container tightly closed. P240 Ground, bond container and receiving equipment. P241 Use explosion-proof electrical, ventilating, light, equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P273 Avoid release to the environment. P280 Wear protective gloves, eye protection, face protection. [Response] P301+310 IF SWALLOWED: Immediately call a POISON CENTER, doctor or physician. P303+361+353 IF ON SKIN (or hair): Remove, take off immediately all contaminated clothing. Rinse skin with water, shower. P308+313 IF exposed or concerned: Get medical advice or attention. P331 Do NOT induce vomiting. P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction. P391 Collect spillage. [Storage] P403+235 Store in a well ventilated place. Keep cool. P405 Store locked up. [Disposal] P501 Dispose of contents or container in accordance with local and national regulations. 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Kerosene (petroleum) CAS Number: 0008008-20-6 100 Asp. Tox. 1;H304 ---- Naphthalene CAS Number: 0000091-20-3 1 - 5 Carc. 2;H351 Acute Tox. 4;H302 Aquatic Acute 1;H400 Aquatic Chronic 1;H410 ---- The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. *PBT/vPvB - PBT-substance or vPvB-substance. The full texts of the phrases are shown in Section 16. Section 4. First aid measures 4.1. Description of first aid measures General In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious, place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser. Ingestion If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Overview Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 3 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure. Treat symptomatically. Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. Check section 2.2 (GHS Label Elements) for further details. Section 5. Fire-fighting measures 5.1. Extinguishing media Suitable Extinguishing Media • CAUTION: For mixtures containing a high percentage of an alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Dry chemical, CO2, water spray or alcohol-resistant foam. LARGE FIRES: Water spray, fog or alcohol-resistant foam. Unsuitable Extinguishing Media • Avoid using direct water stream. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition: High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide. Keep away from heat, sparks, open flames, and other ignition sources - No smoking. Keep container tightly closed. Ground, bond container and receiving equipment. Use explosion-proof electrical, ventilating, light, equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 5.3. Advice for fire-fighters As with all fires, wear positive pressure, self-contained breathing apparatus, (SCBA) with a full face piece and protective clothing. Persons without respiratory protection should leave area. Wear SCBA during clean-up immediately after fire. No smoking. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Containers may explode when heated. Many liquids are lighter than water. Vapors may form explosive mixtures with air. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Move containers from fire area if you can do it without risk. Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. ERG Guide No. 128 Section 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8). 6.2. Environmental precautions Do not allow spills to enter drains or waterways. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. 6.3. Methods and material for containment and cleaning up Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material. A vapor suppressing foam may be used to reduce vapors. All equipment used when handling the product must be grounded. LARGE SPILLS: Dike far ahead of spill for later disposal. LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition in closed spaces. Section 7. Handling and storage 7.1. Precautions for safe handling Handle containers carefully to prevent damage and spillage. Keep away from heat, sparks, and flame. Do not use sparking tools. Take precautionary measures against static charges. All equipment used when handling the product must be grounded. Do not breathe mist, vapors and/or spray. Avoid contact with skin, eyes or clothing. Wear appropriate personal protective equipment, avoid direct contact. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.. Check section 2.2 (GHS Label Elements) for further details. - [Prevention] 7.2. Conditions for safe storage, including any incompatibilities Store in a tightly closed container. Store in a cool/low-temperature, well-ventilated place. Incompatible materials: Strong oxidizing agents and acids. Check section 2.2 (GHS Label Elements) for further details. - [Storage] 7.3. Specific end use(s) No data available. Section 8. Exposure controls / personal protection 8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000091-20-3 Naphthalene OSHA TWA 10 ppm (50 mg/m3) STEL 15 ppm ACGIH TWA: 10 ppm STEL: 15 ppm NIOSH TWA 10 ppm (50 mg/m3) STEL: 15 ppm (75 mg/m3) 0008008-20-6 Kerosene (petroleum) OSHA No Established Limit ACGIH TWA: 200 mg/m3 NIOSH TWA 100 mg/m3 8.2. Exposure controls Respiratory If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators. Eyes Protective safety glasses recommended Skin Protective gloves recommended. Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. Check section 2.2 (GHS Label Elements) for further details. Section 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Color: Various colors, Note: red dye is added to non-taxable fuel. Physical State: Liquid Odor Not Available Odor threshold Not determined pH Not Measured Melting point / freezing point Not Measured Initial boiling point and boiling range 300 to 617 °F(148.8889 to 325 °C) Flash Point > 96 °F(> 35.5556 °C ) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive limits Lower Explosive Limit: 0.7 % Upper Explosive Limit: 7 % Vapor pressure (Pa) Not Measured Vapor Density > 1 Air=1 Relative Density 0.775 to 0.84 Water=1 Solubility in Water Not Measured Partition coefficient n-octanol/water (Log Kow) Not Measured Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) Not Measured Volatility/Vol (%) > 98 % Volatile by Weight > 98 % 9.2. Other information No other relevant information. Section 10. Stability and reactivity 10.1. Reactivity Hazardous Polymerization will not occur. 10.2. Chemical stability Stable under normal circumstances. 10.3. Possibility of hazardous reactions No data available. 10.4. Conditions to avoid Excessive heat and open flame. 10.5. Incompatible materials Strong oxidizing agents and acids. 10.6. Hazardous decomposition products High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide. Section 11. Toxicological information Acute toxicity Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Ingredient Oral LD50, mg/kg Skin LD50, mg/kg Inhalation Vapor LC50, mg/L/4hr Inhalation Dust/Mist LC50, mg/L/4hr Inhalation Gas LC50, ppm Kerosene (petroleum) - (8008-20-6) > 5,000.00, Rat - Category: NA >2,000.00, Rabbit - Category: 5 No data available No data available No data available Naphthalene - (91-20-3) 490.00, Rat - Category: 4 20,000.00, Rabbit - Category: NA No data available No data available No data available Carcinogen Data CAS No. Ingredient Source Value 0000091-20-3 Naphthalene OSHA Regulated Carcinogen: No; NTP Known: No; Suspected: Yes; IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No; ACGIH A3 0008008-20-6 Kerosene (petroleum) OSHA Regulated Carcinogen: No; NTP Known: No; Suspected: No; IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; ACGIH A3 Classification Category Hazard Description Acute toxicity (oral) --- Not Applicable Acute toxicity (dermal) --- Not Applicable Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation --- Not Applicable Serious eye damage/irritation --- Not Applicable Respiratory sensitization --- Not Applicable Skin sensitization --- Not Applicable Germ cell mutagenicity --- Not Applicable Carcinogenicity 2 Suspected of causing cancer. Reproductive toxicity --- Not Applicable STOT-single exposure --- Not Applicable STOT-repeated exposure --- Not Applicable Aspiration hazard --- Not Applicable Section 12. Ecological information 12.1. Toxicity Toxic to aquatic life with long lasting effects. No additional information provided for this product. See Section 3 for chemical specific data. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l Kerosene (petroleum) - (8008-20-6) 5.00, Oncorhynchus mykiss 1.40, Daphnia magna 3.00 (72 hr), Pseudokirchneriella subcapitata Naphthalene - (91-20-3) 0.99, Oncorhynchus gorbuscha 1.60, Daphnia magna 68.21 (96 hr), Scenedesmus subspicatus 12.2. Persistence and degradability There is no data available on the preparation itself. 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available. Section 13. Disposal considerations 13.1. Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. Section 14. Transport information DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) ICAO/IATA 14.1. UN number UN1993 UN1993 UN1993 14.2. UN proper shipping name UN1993, Flammable liquids, n.o.s., (Kerosene, Combustible liquid ), 3, III Flammable liquids, n.o.s., (Kerosene, Combustible liquid ) Flammable liquids, n.o.s., (Kerosene, Combustible liquid ) 14.3. Transport hazard class(es) DOT Hazard Class: 3 Sub Class: Not Applicable IMDG: 3 Sub Class: Not Applicable Air Class: 3 Sub Class: Not Applicable 14.4. Packing group III III III 14.5. Environmental hazards IMDG Marine Pollutant: Yes; ( Naphthalene ) 14.6. Special precautions for user Not Applicable Section 15. Regulatory information Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. Toxic Substance Control Act ( TSCA) All components of this material are either listed or exempt from listing on the TSCA Inventory. EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 313 Toxic Chemicals: Ethylbenzene Naphthalene Proposition 65 - Carcinogens (>0.0%): Ethylbenzene Naphthalene Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 Label Warning: WARNING: This product can expose you to chemicals including [Ethylbenzene , Naphthalene], which are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. Section 16. Other information Revision Date 02/12/2022 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H351 Suspected of causing cancer. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Prepared By Quantum Compliance Revision Notes: Revision Date:February, 12, 2022 Previous Publish Date: November 23, 2015 Revised Sections: The following sections have been updated: Section 1 to 16 End of Document Castrol Vecton 10W-30 FA-4 SAFETY DATA SHEET Product name Section 1. Identification SDS # Product use Engine Oils. For specific application advice see appropriate Technical Data Sheet or consult our company representative. Code 469317-US06 Supplier BP Lubricants USA Inc. 1500 Valley Road Wayne, NJ 07470 Telephone: (973) 633-2200 EMERGENCY HEALTH INFORMATION: 1 (800) 447-8735 Outside the US: +1 703-527-3887 (CHEMTREC) EMERGENCY SPILL INFORMATION: 1 (800) 424-9300 CHEMTREC (USA) 469317 Relevant identified uses of the substance or mixture and uses advised against Section 2. Hazards identification Not classified.Classification of the substance or mixture Signal word No signal word. Hazard statements No known significant effects or critical hazards. Precautionary statements Prevention Not applicable. Response Not applicable. Storage Not applicable. Disposal Not applicable. GHS label elements General Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified Defatting to the skin. USED ENGINE OILS Used engine oil may contain hazardous components which have the potential to cause skin cancer. See Toxicological Information, section 11 of this Safety Data Sheet. Date of issue 11/07/2016. Page: 1/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Highly refined base oil (IP 346 DMSO extract < 3%). Proprietary performance additives. Base oil - highly refined Varies - See Key to abbreviations ≥75 - ≤90 zinc bis[O-(6-methylheptyl)] bis[O-(sec-butyl)] bis(dithiophosphate)93819-94-4 ≤3 Molybdenum polysulfide long chain alkyl dithiocarbamide complex Not available.≤0.3 Ingredient name CAS number % Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention. If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention if symptoms occur. Section 4. First aid measures Eye contact Inhalation Ingestion Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Treatment should in general be symptomatic and directed to relieving any effects. Description of necessary first aid measures Specific treatments No specific treatment. Indication of immediate medical attention and special treatment needed, if necessary See Section 11 for more detailed information on health effects and symptoms. Most important symptoms/effects, acute and delayed Skin contact Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if symptoms occur. Section 5. Fire-fighting measures Hazardous combustion products Specific hazards arising from the chemical Combustion products may include the following: carbon dioxide carbon monoxide nitrogen oxides sulfur oxides phosphorus oxides metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray. Extinguishing media Do not use water jet. Suitable extinguishing media Unsuitable extinguishing media Date of issue 11/07/2016. Page: 2/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. Special protective equipment for fire-fighters Special protective actions for fire-fighters Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Protective measures Put on appropriate personal protective equipment (see Section 8). Precautions for safe handling Not suitable Prolonged exposure to elevated temperature Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Date of issue 11/07/2016. Page: 3/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 8. Exposure controls/personal protection Base oil - highly refined ACGIH TLV (United States). TWA: 5 mg/m³ 8 hours. Issued/Revised: 11/2009 Form: Inhalable fraction OSHA PEL (United States). TWA: 5 mg/m³ 8 hours. Issued/Revised: 6/1993 zinc bis[O-(6-methylheptyl)] bis[O-(sec-butyl)] bis(dithiophosphate)None. Molybdenum polysulfide long chain alkyl dithiocarbamide complex None. Hand protection Wear protective gloves if prolonged or repeated contact is likely. Wear chemical resistant gloves. Recommended: Nitrile gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/ manufacturer and with a full assessment of the working conditions. Safety glasses with side shields.Eye/face protection Body protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures Individual protection measures Skin protection Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions. Date of issue 11/07/2016. Page: 4/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 8. Exposure controls/personal protection In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Respiratory protection Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Vapor density Liquid. Not available. Not available. Not available. Not available.Odor pH Brown.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 204°C (399.2°F) [Pensky-Martens.] Not available. Not available. Viscosity Kinematic: 69.33 mm2/s (69.33 cSt) at 40°C Kinematic: 10.52 mm2/s (10.52 cSt) at 100°C Not available.Odor threshold Partition coefficient: n- octanol/water Appearance Boiling point Not available. Lower and upper explosive (flammable) limits Not available. Decomposition temperature Not available. Density Solubility 870 kg/m³ (0.87 g/cm³) at 15°C insoluble in water. Not applicable. Based on - Physical stateFlammability (solid, gas) Pour point -42 °C Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Incompatible materials Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information. Avoid all possible sources of ignition (spark or flame). Reactive or incompatible with the following materials: oxidizing materials. Date of issue 11/07/2016. Page: 5/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 11. Toxicological information Information on the likely routes of exposure No known significant effects or critical hazards.Ingestion Skin contact No known significant effects or critical hazards. No known significant effects or critical hazards.Eye contact USED ENGINE OILS Combustion products resulting from the operation of internal combustion engines contaminate engine oils during use. Used engine oil may contain hazardous components which have the potential to cause skin cancer. Frequent or prolonged contact with all types and makes of used engine oil must therefore be avoided and a high standard of personal hygiene maintained. General No known significant effects or critical hazards.Carcinogenicity No known significant effects or critical hazards.Mutagenicity No known significant effects or critical hazards.Teratogenicity Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion No specific data. Adverse symptoms may include the following: irritation dryness cracking Eye contact No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 172413.8 mg/kg Route ATE value Acute toxicity estimates Routes of entry anticipated: Dermal, Inhalation. Potential acute health effects Potential immediate effects Not available. Short term exposure Potential delayed effects Not available. Potential immediate effects Not available. Long term exposure Potential delayed effects Not available. Information on toxicological effects Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Inhalation No specific data. Date of issue 11/07/2016. Page: 6/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 12. Ecological information Mobility Spillages may penetrate the soil causing ground water contamination. Bioaccumulative potential Other adverse effects No known significant effects or critical hazards. Toxicity Persistence and degradability Soil/water partition coefficient (KOC) Not available. Mobility in soil No testing has been performed by the manufacturer. Expected to be biodegradable. This product is not expected to bioaccumulate through food chains in the environment. Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal methods Section 14. Transport information - - - - - - Not regulated. - - Not regulated.Not regulated. --- DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code No.No.No. Not available. Not available. TDG Classification Not regulated. - - - No. - - Date of issue 11/07/2016. Page: 7/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 15. Regulatory information U.S. Federal regulations The following components are listed: OIL MIST, MINERALMassachusetts SARA 313 Product name CAS number Concentration SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. zinc bis[O-(6-methylheptyl)] bis[O-(sec-butyl)] bis (dithiophosphate) 93819-94-4 0.90625 - 1.45 zinc bis[O-(6-methylheptyl)] bis[O-(sec-butyl)] bis (dithiophosphate) 93819-94-4 0.90625 - 1.45 Form R - Reporting requirements Supplier notification New Jersey The following components are listed: ZINC compounds; MINERAL OIL (UNTREATED and MILDLY TREATED) Pennsylvania The following components are listed: ZINC COMPOUNDS; MINERAL OIL MIST State regulations SARA 302/304 No products were found. Composition/information on ingredients SARA 311/312 Classification Not applicable. Other regulations At least one component is not listed.United States inventory (TSCA 8b) All components are listed or exempted. At least one component is not listed. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. China inventory (IECSC) Japan inventory (ENCS) Korea inventory (KECI) Philippines inventory (PICCS) Australia inventory (AICS) California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer. Nickel Canada inventory All components are listed or exempted. REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1. Taiwan Chemical Substances Inventory (TCSI) All components are listed or exempted. Section 16. Other information History Date of issue/Date of revision Prepared by Date of previous issue 11/07/2016. 10/13/2016. 0 1 1 National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Product Stewardship Date of issue 11/07/2016. Page: 8/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Section 16. Other information Notice to reader Indicates information that has changed from previously issued version. Key to abbreviations ACGIH = American Conference of Industrial Hygienists ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor CAS Number = Chemical Abstracts Service Registry Number GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OEL = Occupational Exposure Limit SDS = Safety Data Sheet STEL = Short term exposure limit TWA = Time weighted average UN = United Nations UN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods. Varies = may contain one or more of the following 101316-69-2, 101316-70-5, 101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4, 64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7, 64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0, 72623-87-1, 74869-22-0, 90669-74-2 All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet. The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group. It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited. Date of issue 11/07/2016. Page: 9/9Castrol Vecton 10W-30 FA-4 ENGLISH (ENGLISH) Product name Product code Version 2 Format LanguageUS 469317-US06 (US) Page 1 of 9 Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.1200) Section 1: Identification Product Identifier: Certified Butane Other means of identification: - Liquefied Petroleum Gas (LPG) - Normal Butane (n-Butane) - Butane Mixture SDS Number: H2001.5 Intended Use: Fuel Blendstock- Certified Butane Intended for Use by Certified Butane Blenders Uses Advised Against: All others Texon Midstream, LLC Emergency Health and Safety Number: 11757 Katy Freeway, Suite 1400 Chemtrec: 800-424-9300 (24 Hours) Houston, TX 77079 281-531-8400 Section 2: Hazards Identification 2.1 Classified Hazards: H220 – Flammable gases – Category 1 H280 – Gases under pressure – Liquefied gas Other Hazards: May displace oxygen and cause rapid suffocation. 2.2 Label Elements: Hazard Pictograms: Signal Word: DANGER! Hazard Statements: Extremely flammable gas. (H220)* Precautionary Statements: Contains gas under pressure; may explode if heated. (H280)* Prevention: Keep away from heat/sparks/open flames/hot surfaces and other ignition sources. No smoking. (P210)* Response: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. (P377)* Eliminate all ignition sources if safe to do so. (P381)* Storage: Protect from sunlight. Store in well-ventilated place. (P410 +P403)* Disposal: Dispose in accordance with all applicable laws and regulations. (P501)* Supplemental label information: Not applicable. 2.3 Other Hazards: May displace oxygen and cause rapid suffocation. Page 2 of 9 2.4 Known acute toxicity: Not acutely toxic. *(Applicable GHS hazard code) Section 3: Composition/Information on Ingredients Chemical Name CASRN Concentration1 n-Butane 106-97-8 >85% Isobutane 75-28-5 < 1-30% n-Pentane 109-66-0 < 0-5% Isopentane 78-78-4 <0-5% Propane 74-98-6 < 0-2% 1 All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Section 4: First Aid Measures Eye Contact: For contact with the liquefied gas, remove contact lenses if present and easy to do, hold eyelids apart and gently flush the affected eye(s) with lukewarm water or saline solution for 20 to 30 minutes. Seek immediate medical attention. Skin Contact: Liquefied gases may cause cryogenic burns or injury. Treat burned or frostbitten skin by flushing or immersing the affected area(s) in lukewarm water. Do not rub affected area. Do not remove clothing that adheres due to freezing. After sensation has returned to the frostbitten skin, keep skin warm, dry, and clean. If blistering occurs, apply a sterile dressing. Seek immediate medical attention. Inhalation (Breathing): If respiratory symptoms develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. If breathing is difficult, oxygen or artificial respiration should be administered by qualified personnel. If symptoms persist, seek medical attention. Ingestion (Swallowing): This material is a gas under normal atmospheric conditions and ingestion is unlikely. Most important symptoms and effects: Acute: Anesthetic effects at high concentrations Delayed: None know or anticipated. See Section 11 for information on toxicological effects. Notes to Physician: Epinephrine and sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to high concentrations of hydrocarbon solvents (e.g., in enclosed spaces or with deliberate abuse). The use of other drugs with less arrhythmogenic potential should be considered. If sympathomimetic drugs are administered, observe for the development of cardiac arrhythmias. Section 5: Fire-Fighting Measures NFPA 704 Hazard Class Health: 1 Flammability: 4 Instability: 0 0 (Moderate) 1 (Slight) 2 (Moderate) 3 (Serious) 4 (Severe) DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.(Cameo Chemicals, noaa.gov) Extinguishing Media: Dry chemical or carbon dioxide is recommended. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Page 3 of 9 Specific hazards arising from the material: Unusual Fire & Explosion Hazards: Extremely flammable. Contents under pressure. This material can be ignited by heat, sparks, flames, or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, and electronic devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically safe). Vapors may travel considerable distances to a source of ignition where they can ignite, flash back, or explode. May create vapor/air explosion hazards indoors, in confined spaces, outdoors, or in sewers. If container is not properly cooled, it can rupture in the heat of a fire. Drains can be plugged and valves made inoperable by the formation of ice if rapid evaporation of large quantities of the liquefied gas occurs. Do not allow run-off from firefighting to enter drains and may cause explosion hazard in drains and may reignite. Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of nitrogen and sulfur may also be formed. Special protective actions for firefighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self- contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. If this cannot be done, allow fire to burn. Move undamaged containers from immediate hazard area if it can be done safely. Stay away from ends of container. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. See Section 9 for flammable properties, including flash point and upper and lower explosive limits. Section 6: Accidental Release Measures Isolation and Evacuation: As an immediate precautionary measure, isolate spill or leak for at least 100 meter (330 feet) in all directions. Large spill: Consider initial downwind evacuation for at least 800 meters (1/2 mile). Fire: If tank, rail car or tank truck is involved in a fire, isolate for 1600 meters (1 mile) in all directions and consider initial evacuation of 1600 meters (1 mile) in all directions. Refer to ERG Guide 115 for Gases-Flammable and BLEVE –Safety Precautions, ERG page 368. Personal precautions, protective equipment and emergency procedures: Extremely flammable. Release of liquid product will create a fire hazard and may form an explosive atmosphere. Keep all sources of ignition and hot metal surfaces away from spill/release if safe to do so. The use of explosion-proof electrical equipment is recommended. Beware of accumulation of gas in low areas or contained areas, where explosive concentrations may occur. Prevent from entering drains or any place where accumulation may occur. Ventilate area and allow to evaporate. Stay upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons down-wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). See Sections 2 and 7 for additional information on hazards, handling and storage. Environmental Precautions: Stop spill/release if it can be done safely. Water spray may be useful in minimizing or dispersing vapors. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicable regulations. Recommended measures are based on the most likely release scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. Section 7: Handling and Storage Precautions for safe handling: Keep away from ignition sources such as heat/sparks/open flames – No smoking. Take precautionary measures against static discharge. Use good personal hygiene practices and wear appropriate personal protective equipment (see Section 8). Extremely flammable. Contents under pressure. Gas can accumulate in confined spaces and limit oxygen available for breathing. Use only with adequate ventilation. The use of explosion-proof electrical equipment is recommended and may be required (see appropriate fire codes). Refer to NFPA-70 and/or API RP 2003 for specific bonding/grounding requirements. Electrostatic charge may accumulate and create a hazardous condition when handling or processing this material. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding Page 4 of 9 containers and equipment before transferring material. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29 CFR 1910.146. Cold burns may occur during filling operations. Containers and delivery lines may become cold enough to present cold burn during hazard. Conditions for safe storage: Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved containers. Post in area “No Smoking or Open Flame.” Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Outdoor or detached storage is preferred. Indoor storage should meet OSHA standards and appropriate fire codes. “Empty” containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. Avoid exposing any part of compressed-gas cylinder to temperatures above 125°F (51.6°C). Gas cylinders should be stored outdoors or in well ventilated storerooms at no lower than ground level and should be quickly removable in an emergency. Section 8: Exposure Controls/Personal Protection Chemical Name ACGIH OSHA Other n-Butane TWA: 1000 ppm as Aliphatic Hydrocarbon Gases: Alkane (C1-C4) ___ ___ Isobutane TWA: 1000 ppm as Aliphatic Hydrocarbon Gases: Alkane (C1-C4) ___ ___ n-Pentane & Isopentane TWA: 600 ppm TWA: 1000 ppm TWA: 2950 mg/m3 ___ Propane TWA: 1000 ppm as Aliphatic Hydrocarbon Gases: Alkane (C1-C4) TWA: 1000 ppm TWA: 1800 mg/m3 ___ Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. Eye/Face Protection: The use of eye protection (such as splash goggles) that meets or exceeds ANSI Z87.1 is recommended when there is potential liquid contact to the eye. Depending on conditions of use, a face shield may be necessary. Protective Clothing: Wear appropriate personal protective clothing to prevent skin form becoming frozen form contact with the liquid. Remove work clothing that becomes wet due to its flammability hazard. Skin/Hand Protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. If contact with the liquid is possible, insulated gloves suitable for low temperatures should be worn. Respiratory Protection: A NIOSH approved, self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode should be used in situations of oxygen deficiency (oxygen content less than 19.5 percent), unknown exposure concentrations, or situations that are immediately dangerous to life or health (IDLH). A respiratory protection program that meets OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator’s use. Suggestions provided in this Section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. Section 9: Physical and Chemical Properties Page 5 of 9 Data represent typical values and are not intended to be specifications. N/A = Not Applicable; N/D = Not Determined Appearance: Colorless liquid under pressure Flash Point: -76°F Physical Form: Liquefied Gas Test Method: (estimate) Odor: Faint Petroleum-odor (not odorized) Initial Boiling Point/Range: 31 °F / -1 °C Odor Threshold: N/D Vapor Pressure: 2670 mm Hg / 37 psig (Reid VP) @ 100°F / 37.8°C pH: N/A Partition Coefficient (n-octanol/water) (Kow): N/D Vapor Density (air=1): 2 Melting/Freezing Point: -217°F Relative Density: .5037 - .601 Auto Ignition Temperature: 550 °F Upper Explosive Limits (vol % in air): 8.5% Decomposition Temperature: N/D Lower Explosive Limits (vol % in air): 1.9% Specific Gravity (water=1): 0.58 @ 60°F (15.6°C) Evaporation Rate (nBuAc=1): >1 Bulk Density: N/D Particle Size: N/A Viscosity: N/D Percent Volatile: 100% Solubility in Water: Slightly Flammability (solid, gas): Extremely Flammable Corrosivity: non-corrosive Section 10: Stability and Reactivity Chemical Stability: Stable under normal ambient and anticipated conditions of use. Reactivity Alerts: Highly Flammable Reactivity Profile: Butane can explode when exposed to flame or when mixed with nickel carbonyl + oxygen. Reactive Group(s): Hydrocarbons, Aliphatic Saturated Conditions to Avoid: Avoid all possible sources of ignition. Heat will increase pressure in the storage tank. Material to Avoid (Incompatible Materials): Avoid contact with acids, aluminum chloride, chlorine, chlorine dioxide, halogens and oxidizing agents. Strong oxidizers may ignite this material. Hazardous Decomposition Products: Not anticipated under normal conditions of use. Hazardous Polymerization: Not known to occur. Section 11: Toxicological Information Information on Toxicological Effects of Substance/Mixture Acute Toxicity Hazard Additional Information LC50/LD50 Data Inhalation Unlikely to be harmful Asphyxiant. High concentrations in confined spaces may limit oxygen available for breathing. See signs and symptoms below. >20,000 ppm Dermal Skin absorption is not anticipated N/A Oral Ingestion is not anticipated N/A Aspiration Hazard: N/A Skin Corrosion/Irritation: Not expected to be irritating. Contact with the liquefied or pressurized gas may cause frostbite (“cold” burn). Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Not expected to be irritating. Contact with the liquefied or pressurized gas may cause momentary freezing followed by swelling and eye damage. Page 6 of 9 Symptoms of Overexposure: Light hydrocarbon gases are simple asphyxiants and can cause anesthetic effects at high concentrations. Symptoms of overexposure, which may be reversible if exposure is stopped, can include shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting. Continued exposure can lead to hypoxia (inadequate oxygen), rapid breathing, cyanosis (bluish discoloration of the skin), numbing of the extremities, unconsciousness and death. Skin Sensitization: Skin contact is not anticipated. Respiratory Sensitization: Not expected to be a respiratory sensitizer. Specific Target Organ Toxicity (Single Exposure): Not expected to cause organ effects from single exposure. Specific Target Organ Toxicity (Repeated Exposure): Not expected to cause organ effects from repeated exposure. Carcinogenicity: Not expected to cause cancer. Germ Cell Mutagenicity: Not expected to cause inheritable genetic effects. Reproductive Toxicity: Not expected to cause reproductive toxicity. Other Comments: High concentrations may reduce the amount of oxygen available for breathing, especially in confined spaces. Hypoxia (inadequate oxygen) during pregnancy may have adverse effects on the developing fetus. Toxicological Effects of Components n-Butane: Target Organs: No systemic or neurotoxic effects were noted in rats exposed to concentrations of butane as high as 9,000 ppm for 28 days. Reproductive Toxicity: No adverse reproductive or developmental effects were observed in rats exposed to butane; no observed adverse effect level at 12,000 ppm. Isobutane: Target Organs: No systemic or neurotoxic effects were noted in rats exposed to concentrations of isobutene as high as 9,000 ppm for 28 days Reproductive Toxicity: No adverse developmental effects were observed in rats exposed to concentrations of isobutane as high as 9000 ppm. Fertility and mating indices may have been affected at 9000 ppm but no effects were observed at 3000 ppm (NOAEL). Propane: Target Organs: No systemic or neurotoxic effects were noted in rats exposed to concentrations of propane as high as 12,000 ppm for 28 days. Reproductive Toxicity: No adverse reproductive or developmental effects were observed in rats exposed to propane; no observed adverse effect level at 12,000 ppm. Pentane: Target Organs: Studies of pentane isomers in laboratory animals indicate exposure to extremely high levels (roughly 10%) may induce cardiac arrhythmias (irregular heartbeats) which may be serious or fatal. Reproductive Toxicity: No adverse reproductive or developmental effects were observed in rats exposed to pentanes as high as 2,000 mg/kg. Section 12: Ecological Information Toxicity: Petroleum gases will readily evaporate from the surface and would not be expected to have significant adverse effects in the aquatic environment. Persistence and Degradability: The hydrocarbons in this material are expected to be inherently biodegradable. In practice, hydrocarbon gases are not likely to remain in solution long enough for biodegradation to be a significant loss process. Bioaccumulative Potential: Since the log Kow values measured for refinery gas constituents are below 3, they are not regarded as having the potential to bioaccumulate. Mobility in Soil: Due to the extreme volatility of petroleum gases, air is the only environmental compartment in which they will be found. In air, these hydrocarbons undergo photodegradation by reaction with hydroxyl radical with half-lives ranging from 3.2 days for n-butane to 7 days for propane. Other Adverse Effects: None anticipated. Page 7 of 9 Section 13: Disposal Considerations Disposal Instructions: Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration. Local Disposal Regulations: Dispose of product in accordance with local regulations. Hazardous Waste Code D001: Ignitable waste. Waste from Residues/Un-used Dispose of product in accordance with local regulations. Products: Contaminated Packaging: Not applicable. Section 14: Transport Information U.S. Department of Transportation (DOT) Shipping Description: UN1011, Butane, 2.1, see also UN1075 (Liquefied Petroleum Gas) Proper Shipping Name: Butane Identification Nos.: UN1011 Hazard Class/Label Code: 2.1 PG: none Bulk Package/Placard Marking: Flammable gas/1011 Non-Bulk Package Marking: Butane, UN1011 Non-Bulk Package Labeling: Flammable gas Packaging – References: 49 CFR: 173.306 (Exceptions); 173.304 (Non-Bulk); 173.314 & .315 (Bulk) Hazardous Substance: None Emergency Response Guide: 115 See also: Shipping Description: UN1075, Petroleum Gases, Liquefied, 2.1 Proper Shipping Name: Petroleum Gases, Liquefied or Liquefied Petroleum Gas Identification Nos.: UN1075 Hazard Class/Label Code: 2.1 PG: none Bulk Package/Placard Marking: Flammable gas/1075 Non-Bulk Package Marking: Petroleum Gases, Liquefied, UN1075 Non-Bulk Package Labeling: Flammable gas Packaging – References: 49 CFR: 173.306 (Exceptions); 173.304 (Non-Bulk); 173.314 & .315 (Bulk) ERAP Index: 3000 Emergency Response Guide: 115 International Maritime Dangerous Goods (IMDG) Shipping Description: UN1011, Butane, 2.1, see also UN1075 (Liquefied Petroleum Gas) Non-Bulk Package Marking: Butane, UN1011 Labels: Flammable gas Placards/Marking (Bulk): Flammable gas/1011 Packaging – Non-Bulk: P200 EMS: F-D, S-U Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code N/A International Civil Aviation Org. / International Air Transport Assoc. (ICAO/IATA) UN/ID #: UN1011, Butane, 2.1, see also UN1075 (Liquefied Petroleum Gas) Proper Shipping Name: Butane Hazard Class/Division: 2.1 Page 8 of 9 Subsidiary risk: None Non-Bulk Package Marking: Butane, UN1011 Labels: Flammable gas, Cargo Aircraft Only ERG Code: 10L LTD. QTY Passenger Aircraft Cargo Aircraft Only Packaging Instruction #: Forbidden Forbidden 200 Max. Net. Qty. Per Package: Forbidden Forbidden 150 kg Section 15: Regulatory Information OSHA HAZARD COMMUNICATION STANDARD This material has been evaluated and determined to be a “Hazardous Chemical” as defined in OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA – Section 302 Extremely Hazardous Substances and TPQs (in pounds) This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA – Section 311/312 (Title III Hazard Categories) Acute Health: Yes Chronic Health: No Fire Hazard: Yes Pressure Hazard: Yes Reactive Hazard: No CERCLA/SARA – Section 313 and 40 CFR 372 This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. EPA (CERCLA) Reportable Quantity (in pounds) EPA’s Petroleum Exclusion applies to this material – (CERCLA 101(14)). California Proposition 65 This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm at concentrations that trigger the warning requirements of California Proposition 65. Right to Know Information The recipient of this Safety Data Sheet should review applicable state and local regulations in order to determine whether additional “Right to Know” information is required (see https://www.osha.gov/dcsp/osp/statestandards.html). If applicable, the recipient may contact Texon (see Section 1) to obtain any such additional information. International Hazard Classification Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the Safety Data Sheet contains all the information required by the CPR. WHMIS Hazard Class: A – Compressed Gas B1 – Flammable Gases Canada DSL: All components are either on the DSL, or are exempt from DSL listing requirements. National Chemical Inventories All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are either on the DSL, or are exempt from DSL listing requirements. U.S. Export Control Classification Number: EAR99 Page 9 of 9 Section 16: Other Information Date of Issue: Previous Issue Date: SDS Number: Status: 07/25/2024 05/03/2021 H2001.5 Final Revised Sections or Basis for Revision: GHS Updates, EPA 1090 Intended use as a blendstock (2021) Identification (Section 1) Hazards Identification (Section 2) Composition/ Information on Ingredients (Section 3) First Aid Measures (Section 4) Fire-Fighting Measures (Section 5) Accidental Release Measures (Section 6) Handling and Storage (Section 7) Exposure Controls/Personal Protection (Section 8) Physical and Chemical Properties (Section 9) Stability and Reactivity (Section 10) Toxicological Information (Section 11) Ecological Information (Section 12) Disposal Considerations (Section 13) Transport Information (Section 14) Regulatory Information (Section 15) Other Information (Section 16) Guide to Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; GHS = Globally Harmonized System; IARC = International Agency for Research on Cancer; INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = Not Established; NFPA = Nation Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIAH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Disclaimer of Expressed and Implied Warranties: The information presented in this Safety Data Sheet is based upon data reasonably believed to be accurate as of the date this Safety Data Sheet was prepared, and such information is specific only to the product described herein. If the product described herein is used as a component of any other product or process, this information may not be valid. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER REPRESENTATION, WARRANTY OR GUARANTEE IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. It is the recipient’s obligation to evaluate this Safety Data Sheet and to investigate the product in order to make its own determination as to the suitability of the product for its particular purpose, to use this product safely and to comply with all applicable laws and regulations. Texon shall not be liable or responsible for any personal or property loss, damage, illness, death or injury arising out of or in any way connected to the handling, transportation, storage, disposal or use of the product, which is not the intended product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information contained in this Safety Data Sheet. Employers have a duty to tell employees and others who may be affected or be exposed to the product of any hazards described herein and of any precautions that should be taken. The recipient may contact Texon (see Section 1) to ensure that this Safety Data Sheet is the most current available. Alteration of this Safety Data Sheet by any party other than Texon is strictly prohibited. Savage Services Corporation • 901 W. Legacy Center Way • Midvale, Utah 84047 • 801-944-6600 • www.savageservices.com August 1, 2024 Attn: Permitting Utah Division of Air Quality 195 North 1950 West Salt Lake City, Utah 84116 Project Number: 120.021703.00001 Subject: Initial Notice of Intent Savage Services Corporation Savage Services Cedar City Transloading Facility Cedar City, Utah To the Agency: Savage Services Corporation (Savage) is submitting this Utah Initial Notice of Intent Application for the Savage Services Cedar City Transloading Facility. The intent of this application is to authorize transloading operations, fugitive components, and facility haul roads. The facility will transload the following materials: Bulk Minerals (existing) Bulk Grains (existing) Low Vapor Pressure Organic Liquids (existing) Gasoline (new) Ethanol (new) Pressurized Organic Liquids (existing) Diesel Emission Fluid (note this is non-emitting because of the negligible vapor pressure) Aqueous Salt Solutions (note this is non-emitting because of the negligible vapor pressure) If you have any questions regarding this submittal or require additional information, please feel free to contact me at (801) 424-7272 or WilliamKaiser@savageservices.com. Sincerely, Savage Services Corporation William Kaiser, PMP, CHMM, REM, CSP, CESCO Environmental Director  Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent Prepared for: Savage Services Corporation Prepared by: SLR International Corporation SLR Project No.: 120.021703.00001 August 2024 Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 Table of Contents 1.0 Introduction ...................................................................................................................... 1 1.1 Background ........................................................................................................................ 1 1.2 Process Description ........................................................................................................... 1 2.0 Area Maps ......................................................................................................................... 3 3.0 Emission Rate Estimation Methodologies ...................................................................... 5 3.1 Bulk Mineral Loading Operations ........................................................................................ 5 3.2 Grain Loading Operations .................................................................................................. 5 3.3 Haul Road Emissions ......................................................................................................... 5 3.4 Low-Vapor Pressure Organic Liquid Loading Operations ................................................... 5 3.5 Gasoline and Ethanol Loading Operations ......................................................................... 6 3.6 Fugitive Component Emissions .......................................................................................... 6 3.7 Gypsum Storage Pile Emissions ........................................................................................ 6 4.0 Best Available Control Technology Review ................................................................... 7 4.1 BACT for Gasoline and Ethanol Liquid Transloading .......................................................... 7 4.2 BACT for Low Vapor Pressure Organic Liquid Transloading .............................................. 7 4.3 BACT for Pressurized Organic Liquid Transloading ............................................................ 7 4.4 BACT for Transloading piping fugitives ............................................................................... 7 5.0 Regulatory Applicability Analysis ................................................................................... 8 5.1 State regulations ................................................................................................................ 8 5.1.1 UAC R307-201-3 ................................................................................................................ 8 5.1.2 UAC R307-205-4 ................................................................................................................ 8 5.1.3 UAC R307-328 ................................................................................................................... 8 5.1.4 UAC R307-401-2&5 ........................................................................................................... 8 5.2 Federal Regulations ........................................................................................................... 8 6.0 Closure .............................................................................................................................. 9 Figures in Text Figure 1-1 Process Flow Diagram ..............................................................................................2 Figure 2-1 Area Map ...................................................................................................................4 Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 Appendices Appendix A UDEQ Forms Appendix B Emission Calculations Appendix C Material SDS Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 1 1.0 Introduction 1.1 Background Savage Services Corporation (Savage) is submitting this initial Notice of Intent air permit application to the Utah Department of Environmental Quality (UDEQ) to authorize operation of the transloading facility to be located in Cedar City, Utah (the Site). With this application Savage is requesting authorization for gasoline and ethanol loading and associated fugitive piping components and a gypsum storage pile. The other operations were previously authorized under a small source exemption; they are already constructed and operational. All sources will need to be added to the NOI, because after this project Savage will no longer qualify for the small source exemption. 1.2 Process Description Savage Services will operate a transloading facility transferring organic liquids at atmospheric and pressurized conditions, bulk minerals, and bulk grain from trucks to railcars and vice versa. For the bulk minerals transfer (two stations), Savage will either use a conveyor to move the material or a pneumatic transfer system. Emissions from both kinds of transfer will be controlled by a baghouse dust collector. Savage will also store bulk lump gypsum on site, which will be wetted with water sprays. For the bulk grains transfer (1 station), Savage will use a conveyor belt to move the material. Emissions from the grain transfer will be controlled by a baghouse dust collector. For the low vapor pressure organic liquids transfer, Savage will transfer diesel fuel, jet kerosene, and vegetable oil at atmospheric conditions using a liquid pump. Diesel fuel and jet fuel will use a vapor return line to reduce emissions. The atmospheric low-vapor pressure organic liquid loading racks will have associated fugitive piping components. Savage will also transfer ethanol and gasoline at atmospheric conditions using a liquid pump. Both will use a vapor return line to reduce emissions. Both operations will have associated fugitive piping components. For the pressurized organic liquids transfer, Savage will transfer liquefied petroleum gas (LPG), propane, or butane under pressure using a compressor to move the butane. Emissions will occur from small amounts of vapor being emitted when disconnecting the transfer hoses. The pressurized organic liquid loading rack will also have associated fugitive components. Trucks will drive on chip sealed or asphalt roads. Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 2 Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 3 2.0 Area Maps A current area map is included as Figure 2-1 in this section. The map contains a true north arrow, the entire plant property, and the location of the property relative to prominent geographical features such as highways, roads, streams, and significant landmarks. Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 4 Figure 2-1 Area Map Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 5 3.0 Emission Rate Estimation Methodologies Emission estimates for this application were prepared in accordance with AP-42 methodologies, EPA Fugitive Emissions Guidance, and equipment specific emissions factors as described in the following sections for each source type. Detailed emissions estimates are provided in Appendix B. A summary of sitewide uncontrolled and controlled emissions are included as Table B-1. 3.1 Bulk Mineral Loading Operations Emissions of particulate matter (PM/PM10/PM2.5) from loading bulk minerals to and from rail cars and trucks were estimated using a widely accepted material handling emission factor for dust emissions for crushed stone processing, AP-42, Section 11.19.2 for a transfer point since truck loading does not have an emission factor given for PM or PM2.5. Emissions were based on maximum hourly and annual loading rates, the above identified emission factor, and a 99% control efficiency for the associated dust collector. Detailed emissions estimates are represented in Tables B-2 and B-3 for conveyed (EPN CONVLOAD) and pneumatic loading (EPN PNEULOAD), respectively. 3.2 Grain Loading Operations Emissions of particulate matter (PM/PM10/PM2.5) from loading bulk grains to and from rail cars and trucks were estimated using a widely accepted material handling emission factor for dust emissions for crushed stone processing, AP-42, Section 9.9.1-1 for truck loading of grain. Emissions were based on maximum hourly and annual loading rates, the above identified emission factor, and a 99% control efficiency for the associated dust collector. Detailed emissions estimates are represented in Table B-4 for grain loading (EPN GRAINLOAD) operations. 3.3 Haul Road Emissions Particulate emissions from the haul roads were estimated using emission factors from AP-42, Chapter 13.2.1 table 13.2.1-1 for paved industrial roads, the maximum number of trucks that would be loaded hourly and annually and the round-trip driving distance per truck. The haul roads will either be made of asphalt or coated in chip seal. Table B-5 of Appendix B provides details of these emissions estimates. 3.4 Low-Vapor Pressure Organic Liquid Loading Operations Volatile Organic Compound (VOC) emissions due to the atmospheric loading of low vapor pressure organic liquid materials into rail cars and tanker trucks were estimated using the AP- 42, Chapter 5 loading loss equation for organic liquids, the most conservative material properties of the liquids, average annual temperature, and maximum hourly and annual loading rates. Loading operations for low vapor pressure organic liquids will not use vapor return lines, and emissions will be released directly to the atmosphere. Detailed emissions estimates for low- vapor pressure organic liquid loading (EPN ORGLOAD) are represented in Table B-6. Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 6 3.5 Gasoline and Ethanol Loading Operations Volatile Organic Compound (VOC) emissions due to the atmospheric loading of gasoline and ethanol into rail cars and tanker trucks were estimated using the AP-42, Chapter 5 loading loss equation for organic liquids, material properties of the liquids, average annual temperature, and maximum hourly and annual loading rates. All loading operations for ethanol and gasoline will use vapor return lines (i.e., vapor balancing). The trucks and rail cars are all annually leak tested to meet NSPS Subpart XX standards, so a 98.7% collection efficiency was used for vapor balancing. Detailed emissions estimates are represented in Table B-8 for gasoline loading (EPN GASLOAD) and Table B-9 for ethanol loading (EPN ETHALOAD). 3.6 Fugitive Component Emissions VOC emissions result from fugitive components associated with the equipment and piping used to transfer the low vapor pressure organic liquids, ethanol, gasoline, and pressurized organic liquids. Total fugitive VOC emissions were estimated for streams in VOC service using emission factors for Petroleum Marketing Terminals for low vapor pressure organic liquids, gasoline, and ethanol and SOCMI without ethylene for the pressurized organic liquid transfer systems taken from the 1995 Protocol for Equipment Leak Emission Estimates (EPA-453/R-95-017). Tables B- 10 through B-13 of Appendix B provide details of these emissions estimates for EPNs BUTAFUG, ORGFUG, GASFUG, and ETHAFUG. 3.7 Gypsum Storage Pile Emissions Particulate emissions result from wind erosion of the piles and loading material in and out of the pile. For material handling, emissions were estimated using hourly and annual throughput, material properties, high water content from water sprays, and AP-42, Section 13.2-4, equation 1 for bulk material drop points. Wind erosion emissions were estimated using pile size, material properties, a control efficiency for water sprays, and Equation 8 from “Iron and Steel Plant Open Source Fugitive Emission Evaluation”. Detailed emission estimates for storage and loading (EPN PYLEGYP) are represented in Table B-14 in Appendix B. Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 7 4.0 Best Available Control Technology Review Savage has completed a Best Available Control Technology (BACT) analysis for the operations being authorized with this notice of intent. This analysis was conducted according to regulation UAC R307-401-5. 4.1 BACT for Gasoline and Ethanol Liquid Transloading Submerged-fill piping combined with vapor return lines on leak-tested cargo tanks on both the trucks and rail cars is standard procedure for minimizing emissions from gasoline and ethanol loading and can reduce emissions by 98.7%. Savage is proposing their use as BACT for all gasoline and ethanol liquid transloading. This level of control meets the requirements of MACT Subpart BBBBBB for gasoline loading operations at bulk gasoline terminals transferring less than 250,000 gallons per day. 4.2 BACT for Low Vapor Pressure Organic Liquid Transloading Vapor pressure for this class of materials will be 0.05 psia or lower, so using dedicated service trucks with submerged fill loading is being proposed as BACT. 4.3 BACT for Pressurized Organic Liquid Transloading The loading operations are sealed so there are no direct emissions during loading, but after loading there will be residual vapor left in the transfer hoses. Savage proposed using auto-close hose connectors to minimize losses when decoupling after transfer as BACT. 4.4 BACT for Transloading piping fugitives Savage will transload a variety of liquid fuel products and pressurized liquids that will have associated piping fugitive components. Savage is proposing a monthly physical inspection LDAR program to reduce emissions. Physical inspection programs are standard BACT for petroleum marketing terminals and meet the requirements of MACT Subpart BBBBBB for bulk gasoline terminals. Annual emissions of VOC from piping fugitives under this program are less than 5 tons per year, so implementing an instrument-based LDAR program would not be warranted. Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 8 5.0 Regulatory Applicability Analysis 5.1 State regulations 5.1.1 UAC R307-201-3 This rule requires that all sources constructed after April 25, 1971, meet a visible emissions limit of 20% opacity. Savage will comply by using water sprays on the storage pile, dust collectors on all bulk solids transfers, and either paved or chip sealed roads. 5.1.2 UAC R307-205-4 This rule requires that any fugitive dust emissions from sources constructed after April 25, 1971, meet a visible emissions limit of 20% opacity. Savage will comply with this rule by using water sprays on storage piles and paved or chip sealed roads. 5.1.3 UAC R307-328 Savage will be transloading gasoline into tank trucks and will be subject to this rule. The trucks will be leak tested according to standards in MACT Subpart BBBBBB, which meet the requirements for leak testing in R307-328-7. Savage will perform the semi-annual leak testing of the transfer apparatus as required in R307-328-4. Savage will use dry break connections to minimize leaks when decoupling after loading as required in R307-328-4. 5.1.4 UAC R307-401-2&5 This rule requires that anyone that plans to construct or modify a source of air pollution seek an air permit authorization. Since Savage will be constructing new emitting equipment, a permit will be required. Savage will comply with this rule by submitting this notice of intent application. Savage will not construct or operate the sources in the notice of intent until it receives an Approval Order (AO). The site will not be a major source, therefore PSD and NNSR requirements do not apply. 5.2 Federal Regulations The facility is not a major source of criteria pollutants or hazardous air pollutants, as such the facility will not be subject to major source federal permitting under Title V or PSD. There are no regulations under 40 CFR 60 New Source Performance Standards and 40 CFR 61 National Emissions Standards for Hazardous Air Pollutants that apply to this facility. The facility will transfer between 20,000 and 250,000 gallons of gasoline per day, and thus subject to 40 CFR 63, Subpart BBBBBB for Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities. Savage Services Corporation Cedar City Transloading Facility Initial Notice of Intent August 2024 SLR Project No.: 120.021703.00001 9 6.0 Closure Initial Notice of Intent Application Prepared for: Savage Services Cedar City Transloading Facility This document has been prepared by SLR International Corporation (SLR). The material and data in this report were prepared under the supervision and direction of the undersigned. Deever Bradley, P.E. Senior Principal Conor Braman Senior Engineer Appendix A UDEQ Forms 1 of 1 Form 2 Date ____________ Company Information/Notice of Intent (NOI) Utah Division of Air Quality New Source Review Section Application for: □ Initial Approval Order □Approval Order Modification General Owner and Source Information 1.Company name and mailing address: ____________________________ ____________________________ ____________________________ Phone No.: ( ) Fax No.: ( ) 2.Company** contact for environmental matters: ____________________________ Phone no.: ( ) Email: _______________________ ** Company contact only; consultant or independent contractor contact information can be provided in a cover letter 3.Source name and physical address (if different from above):____________________________ ____________________________ ____________________________ Phone no.: ( ) Fax no.: ( ) 4. Source Property Universal Transverse Mercator coordinates (UTM), including System and Datum: UTM:_________________________ X:____________________________ Y:____________________________ 5.The Source is located in:__________________ County 6.Standard Industrial Classification Code (SIC) __ __ __ __ 7. If request for modification, AO# to be modified: DAQE #__________________ DATED: ____/____/____ 8. Brief (50 words or less) description of process. Electronic NOI 9.A complete and accurate electronic NOI submitted to DAQ Permitting Mangers Jon Black (jlblack@utah.gov) or Alan Humpherys (ahumpherys@utah.gov) can expedite review process. Please mark application type. Hard Copy Submittal Electronic Copy Submittal □ Both Authorization/Signature I hereby certify that the information and data submitted in and with this application is completely true, accurate and complete, based on reasonable inquiry made by me and to the best of my knowledge and belief. Signature: Title: _______________________________________ Name (Type or print) Telephone Number: ( ) Email: Date: 435 630-8403 6635 W Sage Hills Dr., Cedar City, Utah Cedar City Transloading Facility WilliamKaiser@savageco.com Environmental Director DAO 2018 002272 Page 1 of 1 Company___________________________ Site _____________________________ Form 5 Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants** (**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed Jccumonl Dcjlc: 02/28/2018 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __24,000_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. gal/hr 22,500,000 gal/yr Gasoline Transloading Gasoline will be loaded from rail cars into tanker trucks. Vapor balancing will be used to minimize emissions. Gasoline 22,500,000 gallons Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __24,000_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. gal/hr 22,500,000 gal/yr Ethanol Transloading Ethanol will be loaded from rail cars into tanker trucks. Vapor balance will be used to minimize emissions. Ethanol 22,500,000 gallons Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __24,000_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. gal/hr 12,000,000 gal/yr Pressurized Liquids Transloading Pressurized liquids like propane and butane will be loaded from rail cars into tanker trucks. Auto close couplings will be used to minimize emissions. Propane or Butane or LPG 12,000,000 gallons Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __28,000_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. gal/hr 45,000,000 gal/yr Low VP Liquids Transloading Low VP liquids like diesel or kerosene or food oils will be loaded from rail cars into tanker trucks. Submerged fill loading will be used to minimize emissions. Low VP Organic Liquids 45,000,000 gallons Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __200_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. ton/hr 210,000 ton/yr Bulk Mineral Transloading Bulk minerals will be loaded from rail cars into trucks using either a conveyor or pneu- matic system. A dust collector will be used to minimize emissions. Bulk Minerals 210,000 tons Bulk mineral loading 2024200 tph Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6. Maximum Hourly production (indicate units.): __100_____ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. ton/hr 15,000 ton/yr Grain Transloading Grain will be loaded from rail cars into trucks using either a conveyor. A dust collector will be used to minimize emissions. Grains 15,000 tons Grain loading 2024100 tph Docuitiunl Dale;: 02/28,;2018 DAQ 2018 II002273 Form 1 Date __________________ Notice of Intent (NOI) Application Checklist Company __________________ Utah Division of Air Quality New Source Review Section Source Identification Information [R307-401-5] 1. Company name, mailing address, physical address and telephone number  2. Company contact (Name, mailing address, and telephone number) 3.Name and contact of person submitting NOI application (if different than 2) 4.Source Universal Transverse Mercator (UTM) coordinates  5. Source Standard Industrial Classification (SIC) code  6.Area designation (attainment, maintenance, or nonattainment) 7.Federal/State requirement applicability (NAAQS, NSPS, MACT, SIP, etc.) 8.Source size determination (Major, Minor, PSD) 9. Current Approval Order(s) and/or Title V Permit numbers  NOI Application Information: [R307-401]           N/A  N/A  A.Air quality analysis (air model, met data, background data, source impact analysis) N/A  1.Detailed description of the project and source process 2.Discussion of fuels, raw materials, and products consumed/produced3.Description of equipment used in the process and operating schedule 4.Description of changes to the process, production rates, etc. 5.Site plan of source with building dimensions, stack parameters, etc. 6.Best Available Control Technology (BACT) Analysis [R307-401-8]A.BACT analysis for all new and modified equipment 7.Emissions Related Information: [R307-401-2(b)] A.Emission calculations for each new/modified unit and site-wide (Include PM10, PM2.5, NOx, SO2, CO, VOCs, HAPs, and GHGs)B.References/assumptions, SDS, for each calculation and pollutant C.All speciated HAP emissions (list in lbs/hr) 8.Emissions Impact Analysis – Approved Modeling Protocol [R307-410] A.Composition and physical characteristics of effluent(emission rates, temperature, volume, pollutant types and concentrations) 9.Nonattainment/Maintenance Areas – Major NSR/Minor (offsetting only) [R307-403] A.NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirements B.Alternative site analysis, Major source ownership compliance certification 10.Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406] B.Visibility impact analysis, Class I area impact 11.Signature on Application N/A  Note: The Division of Air Quality will not accept documents containing confidential information or data. Documents containing confidential information will be returned to the Source submitting the application. iJoc.i-iirKji'il Dale:' (X!/AS,‘2C U DAQ 2018-002271 Appendix B Emission Calculations TABLE B-1 Emissions Summary Savage Services Cedar City, Utah VOC PM PM10 PM2.5 (tpy)(tpy)(tpy)(tpy) CONVLOAD Conveyor loading of bulk minerals -- 4.50E-03 1.65E-03 1.65E-03 PNEULOAD Pneumatic loading of bulk minerals -- 9.00E-04 3.30E-04 3.30E-04 GRAINLOAD Conveyor loading of bulk grains -- 0.03 0.01 1.50E-03 HAULROAD Haul road emissions -- 0.05 0.01 2.68E-03 PILEGYP Gypsum storage pile -- 0.64 0.48 0.37 ORGLOAD Low-vapor Pressure Organic loading 2.08 -- -- -- ORGFUG Low-vapor Pressure Organic loading fugitive components 0.06 -- -- -- BUTALOAD Pressurized butane loading 0.21 -- -- -- BUTAFUG Butane loading fugitive components 2.67 -- -- -- GASLOAD Gasoline loading 3.25 -- -- -- GASFUG Gasoline loading fugitive components 0.41 -- -- -- ETHALOAD Ethanol loading 0.12 -- -- -- ETHAFUG Ethanol loading fugitive components 0.41 ------ Totals 9.20 0.72 0.50 0.37 EPN Description Emission Totals Page 1 of 14 TABLE B-2 Conveyed Mineral Transloading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- CONVLOAD Material Loaded --Minerals Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 150,000 Drop Points 2 Material is loaded from the rail car to a conveyor and then conveyor to the truck PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 0.01 4.50E-03 PM10 2.20E-03 1.65E-03 PM2.5 2.20E-03 1.65E-03 tons of mineral per rail car 1,500 railcars per year AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 2 of 14 TABLE B-3 Pneumatic Mineral Loading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- PNEULOAD Material Loaded --Minerals Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 60,000 Drop Points 1 Material is loaded from the rail car to truck directly by pneumatic transfer PM Emission Factor lb/ton 0.0030 PM10 Emission Factor lb/ton 1.10E-03 PM2.5 Emission Factor lb/ton 1.10E-03 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 3.00E-03 9.00E-04 PM10 1.10E-03 3.30E-04 PM2.5 1.10E-03 3.30E-04 tons of mineral per rail car 600 railcars per year AP-42 Chapter 11.19.2 Table 11.19.2-2 for a conveyor transfer point Page 3 of 14 TABLE B-4 Grain Transloading Savage Services Cedar City, Utah Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- GRAINLOAD Material Loaded --Grain Hourly Loading Rate ton/hr 100 Annual Loading Rate ton/yr 15,000 Drop Points 2 Material is loaded from the rail car to a conveyor and then conveyor to the truck PM Emission Factor lb/ton 0.18 PM10 Emission Factor lb/ton 0.06 PM2.5 Emission Factor lb/ton 0.01 Dust Collector Control Efficiency % 99 Pollutant Hourly Emissions (lb/hr) Annual Emissions (tpy) PM 0.36 0.03 PM10 0.12 0.01 PM2.5 0.02 1.50E-03 See Documentation in Attachment 5 Grain and grain related products tons of grain per rail car 150 railcars per year AP-42 Chapter 9.9.1-1 Emission factor for straight truck receiving grain Page 4 of 14 TABLE B-5 TABLE B-5 Haul Road Emissions (FIN/EPN HAULROAD)Haul Road Emissions Savage Services Cedar City, Utah Trucks Per Year 15,000 Haul Road Round Trip Length 0.66 milesVehicle Miles Per Hour 1.14 miles Vehicle Miles Per Year 9,943 miles Type of Control Chip Seal or Asphalt (lb/hr)(tpy) PM 0.011 0.01 0.05 PM10 0.0022 2.50E-03 0.01 PM2.5 0.00054 6.13E-04 2.68E-03 NOTES: 1. Taken from AP-42 13.2.1-1 for paved roads E (lb/VMT) = k*(s/12)a*(W/3)b Where k is a particle size-specific constant for PM/PM10/PM2.5 s is the surface material silt content in % W is the mean vehicle weight a is a particle size-specific constant for PM/PM10/PM2.5 b is a particle size-specific constant for PM/PM10/PM2.5 Controlled Emissions Facility Information Pollutant Emission Factor (lb/VMT) [1] TABLE B-6 Low Vapor Pressure Organic Liquid Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) ORGLOAD ORGLOAD 2.59 2.08 Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- ORGLOAD Material Loaded --Organic Liquids Low-vapor pressure organic liquids including but not limited to diesel, biodiesel, kerosene, lube oil, and food oils. Hourly Maximum Fill Rate gal/hr 28,000 Rail Cars Loaded Per Day cars/day 10.0 Maximum of 10 railcars per day of low vapor pressure organics Maximum Railcars Per year cars/year 1,500 Maximum of 1,500 railcars per year of low vapor pressure organics Weight Capacity of Railcar lbs 133,000 Product Density lb/gal 7.1 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids for No. 2 Fuel Oil used as representative Product Volume Per Railcar gal 30,000 Based on maximum allowable weight capacity per railcar Annual Net Throughput gal/yr 45,000,000 Based on maximum number of jet fuel railcars per year (1500) Molecular Weight (M) lb/lb-mole 130 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Saturation Factor (S) dimensionless 0.60 EPA AP-42, Chapter 5, Table 5.2-1: Saturation Factors for submerged loading: dedicated service °F 65.00 Per Guidance to derive maximum hourly emission rate °R 524.67 Conversion 1 °R = °F + 459.67 °F Vapor Pressure (P) psia 0.05 A maximum vapor pressure of 0.05 psia is specified for this group (For reference diesel and jet naphtha are near 0.02 psia) Loading Loss [1]lb/1,000 gal 0.09 AP-42 Chapter 5 Loading Loss Equation LL= 12.46 SPM/T Vapor Balance Back [2]%0.0%Vapor balancing Hourly Loading Losses lb/hr 2.59 Loading Loss * Maximum Fill Rate Annual Loading Losses tpy 2.08 Loading Loss * Net Throughput" NOTES: EPN FIN Temperature (T) [1] Loading Loss (lb/Mgal) calculated from Saturation Factor, Vapor Pressure, Vapor Molecular Weight, and Temperature according to Equation 1 in AP-42, Section 5.2, Transportation and Marketing of Petroleum Liquids (dated June 2008). Saturation Factor equals 1.0 for vapor balancing. Page 6 of 14 TABLE B-7 Butane Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) BUTALOAD BUTALOAD 0.84 0.21 Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- BUTALOAD Material Loaded --Butane Length of Loading Hose ft 30 Diameter of Loading Hose ft 0.5 Volume of Loading Hose ft3 6 Number of Loading Events Per Year 500 Molecular Weight (M)lb/lb-mole 58.12 Molar Volume at 100 °F ft3/lbmol 408.69 Based on the ideal gas law. = Molar Volume at 519 R * 559 R/519 R = 379.5 * 559.67 R/519.67 R Mass of butane in the hose lb 0.84 Hourly Loading Losses lb/hr 0.84 Assuming 1 hose volume vented per hour as maximum Annual Loading Losses tpy 0.21 EPN FIN Page 7 of 14 TABLE B-8 Gasoline Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) GASLOAD GASLOAD 3.47 3.25 Loading Specifications Parameter Unit Value Basis/Comment/Description FIN/EPN -- GASLOAD Material Loaded --Gasoline* Benzene Fraction in the Material Mass Fraction 0.049 Based on SDS, assuming maximum content for each compound with a range given Toluene Fraction in the Material Mass Fraction 0.25 Based on SDS, assuming maximum content for each compound with a range given Xylene Fraction in the Material Mass Fraction 0.15 Based on SDS, assuming maximum content for each compound with a range given 1,2,4 TMB Fraction in the Material Mass Fraction 0.06 Based on SDS, assuming maximum content for each compound with a range given Hourly Maximum Fill Rate gal/hr 24,000 Rail Cars Loaded Per Day cars/day 5.0 Maximum of 5 railcars per day of gasoline Maximum Railcars Per year cars/year 750 Product Density lbs/gal 5.6 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Product Volume Per Railcar gal 30,000 Based on maximum allowable weight capacity per railcar for gasoline Annual Net Throughput gal/yr 22,500,000 Based on maximum number of gasoline railcars per day (5) Molecular Weight (M)lb/lb-mole 62 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Saturation Factor (S)dimensionless 1.00 EPA AP-42, Chapter 5, Table 5.2-1: Saturation Factors for submerged loading: dedicated vapor balance service °F 64.40 Annual Average Temperature °R 524.07 Conversion 1 °R = °F + 459.67 °F Vapor Pressure (P) psia 7.54 RVP 13 Gasoline; EPA AP-42 Chapter 7, Table 7.1-2 Properties of Selected Petroleum Liquids formular for vapor pressure Uncontrolled Loading Loss [1]lb/1,000 gal 11.11 AP-42 Chapter 5 Loading Loss Equation LL= 12.46 SPM/T Controlled Loading Loss lb/1,000 gal 0.14 Meets 0.640 lb/1,000 gallon requirement in UAC 307-328-4 Vapor Balance Back [2]% 98.7% Vapor balancing per Subpart XX Hourly Loading Losses VOC lb/hr 3.47 Loading Loss * Maximum Fill Rate Annual Loading Losses VOC tpy 3.25 Loading Loss * Net Throughput" Hourly Loading Losses Benzene lb/hr 0.17 Emission Rate * Mass Fraction Annual Loading Losses Benzene tpy 0.16 Emission Rate * Mass Fraction Hourly Loading Losses Toluene lb/hr 0.87 Emission Rate * Mass Fraction Annual Loading Losses Toluene tpy 0.81 Emission Rate * Mass Fraction Hourly Loading Losses Xylene lb/hr 0.21 Emission Rate * Mass Fraction Annual Loading Losses Xylene tpy 0.20 Emission Rate * Mass Fraction Hourly Loading Losses 1,2,4 TMB lb/hr 0.17 Emission Rate * Mass Fraction Annual Loading Losses 1,2,4 TMB tpy 0.16 Emission Rate * Mass Fraction NOTES: [2] Vapor balancing is used for the loading. Assumed control efficiency of 98.7% according to AP-42, Chapter 5.2 for NSPS Subpart XX level control tanker trucks. EPN FIN Temperature (T) [1] Loading Loss (lb/Mgal) calculated from Saturation Factor, Vapor Pressure, Vapor Molecular Weight, and Temperature according to Equation 1 in AP-42, Section 5.2. Saturation Factor equals 1.0 Page 8 of 14 TABLE B-9 Ethanol Loading Savage Services Cedar City, Utah Loading Emissions Summary VOC Emissions (lb/hr) (tpy) ETHALOAD ETHALOAD 0.26 0.12 Loading Specifications Parameter Unit Basis/Comment/Description FIN/EPN -- ETHALOAD Material Loaded --Ethanol Hourly Maximum Fill Rate gal/hr 24,000 2 Ethanol pumps @ 200 gpm each = 400 gpm loading rate Rail Cars Loaded Per Day cars/day 5.0 Maximum of 20,000 gal/day (rolling 30 days) for Ethanol Maximum Railcars Per year cars/year 750 Based on 5 railcar/day per 5-day work week, up to a maximum of 20,000 gal/day (rolling 30 days) for Ethanol Weight Capacity of Railcar lbs 133,000 30,100 gallon capacity, with a 198,000 lb load limit and 65,000 lb tare weight, for a weight capacity of 133,000 lb Product Density lbs/gal 6.59 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Product Volume Per Railcar gal 30,000.0 Based on maximum allowable weight capacity per railcar, for each compound Annual Net Throughput gal/yr 22,500,000 Based on Ethanol for 750 cars per year Molecular Weight (M)lb/lb-mole 46.07 EPA AP-42, Chapter 7, Table 7.1-2: Properties of Selected Petroleum Liquids Saturation Factor (S)dimensionless 1.0 EPA AP-42, Chapter 5, Table 5.2-1: Saturation Factors for submerged loading: dedicated vapor balance service °F 64.40 Annual Average Temperature °R 524.07 Conversion 1 °R = °F + 459.67 °F psia 0.75 Based on Antoine's equation and the constants for ethanol 250.96 Denominator term in Pva in psia formula from AP 42 Chapter 7 Loading Loss [1]lb/1,000 gal 0.83 AP-42, Chapter 5 Loading Loss Equation LL= 12.46 SPM/T Vapor Balance Back [2]% 98.7% Vapor balancing per Subpart XX Hourly Loading Losses lb/hr 0.26 Loading Loss * Maximum Fill Rate Annual Loading Losses tpy 0.12 Loading Loss * Net Throughput" NOTES: [2] Vapor balancing is used for the loading. Assumed control efficiency of 98.7% according to AP-42, Chapter 5.2 for NSPS Subpart XX level control tanker trucks. EPN FIN Temperature (T) [1] Loading Loss (lb/Mgal) calculated from Saturation Factor, Vapor Pressure, Vapor Molecular Weight, and Temperature according to Equation 1 in AP-42, Section 5.2. Saturation Factor equals 1.0 for vapor balancing. Vapor Pressure (P) Page 9 of 14 TABLE B-10 Butane Fugitives Savage Services Cedar City, Utah FIN/EPN BUTAFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 5 0.0089 30% 8,760 0.0312 0.1364 LL 10 0.0035 30% 8,760 0.0245 0.1073 HL 0 0.0007 30% 8,760 0 0 Flanges GV 15 0.0029 30% 8,760 0.0305 0.1334 LL 30 0.0005 30% 8,760 0.0105 0.0460 HL 0 0.00007 30% 8,760 0 0 Pump LL 0 0.0366 30% 8,760 0.000 0.0000 Seals HL 0 0.0161 30% 8,760 0 0 PRVs G/V 1 0.2293 30% 8,760 0.1605 0.7030 Compressors G/V 1 0.5027 30%8,760 0.3519 1.5413 Total Fugitive Piping Emissions 0.61 2.67 NOTES: [1] Component counts estimated by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for SOCMI without Ethylene [3] Savage is proposing use of a monthly physical inspection program Component Total VOC Transloading Arm and Vapor Balance Line - Butane Page 10 of 14 TABLE B-11 Low-Vapor Pressure Organic Liquid Fugitives Savage Services Cedar City, Utah FIN/EPN ORGFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 0 0.0000287 0% 8,760 0.00 0.00 LL 0 0.0000948 0% 8,760 0.00 0.00 HL 5 0.0000948 0% 8,760 0.00 0.00 Flanges GV 0 0.000092604 0% 8,760 0.00 0.00 LL 0 0.00001762 0% 8,760 0.00 0.00 HL 15 0.0000176 0% 8,760 0.00 0.00 Pump LL 0 0.00119 0% 8,760 0.00 0.00 Seals HL 11 0.00119 0% 8,760 0.01 0.06 PRVs G/V 0 0.0194 0% 8,760 0.00 0.00 Compressors G/V 0 0.0194 0%8,760 0.00 0.00 Total Fugitive Piping Emissions 0.01 0.06 NOTES: [1] Component counts estimated by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for Petroleum Marketing Terminals. [3] No control credit is taken since there is no LDAR program in place [4] Annual operation conservatively assumes that the lines will always be in VOC service. Component Total VOC Loading Arm for Low- VP Organics Page 11 of 14 TABLE B-12 Gasoline Fugitives Savage Services Cedar City, Utah FIN/EPN GASFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 2 0.0000287 0% 8,760 0.0001 0.0003 LL 5 0.0000948 0% 8,760 0.0005 0.0021 HL 0 0.0000948 0% 8,760 0 0 Flanges GV 12 0.000092604 0% 8,760 0.0011 0.0049 LL 27 0.00001762 0% 8,760 0.0005 0.0021 HL 0 0.0000176 0% 8,760 0 0 Pump LL 11 0.00119 0% 8,760 0.013 0.0573 Seals HL 0 0.00119 0% 8,760 0 0 PRVs G/V 2 0.0194 0% 8,760 0.0388 0.1699 Compressors G/V 2 0.0194 0%8,760 0.0388 0.1699 Total Fugitive Piping Emissions 0.09 0.41 NOTES: [1] Component counts provided by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for Petroleum Marketing Terminals. [3] The control credits for the 28PET visual inspection program are included in the emission factor. [4] Annual operation conservatively assumes that the lines will always be in VOC service. Transloading Arm and Vapor Balance Line - Gasoline Loading Component Total VOC Page 12 of 14 TABLE B-13 Ethanol Fugitives Savage Services Cedar City, Utah FIN/EPN ETHAFUG Component Factor [2]Control Annual Description Type Service Count [1](lb/hr/source)Credit [3]Operation [4] (hr)(lb/hr) (tpy) Valves G/V 2 0.0000287 0% 8,760 0.0001 0.0003 LL 5 0.0000948 0% 8,760 0.0005 0.0021 HL 0 0.0000948 0% 8,760 0 0 Flanges GV 10 0.000092604 0% 8,760 0.0009 0.0041 LL 23 0.00001762 0% 8,760 0.0004 0.0018 HL 0 0.0000176 0% 8,760 0 0 Pump LL 11 0.00119 0% 8,760 0.013 0.0573 Seals HL 0 0.00119 0% 8,760 0 0 PRVs G/V 2 0.0194 0% 8,760 0.0388 0.1699 Compressors G/V 2 0.0194 0%8,760 0.0388 0.1699 Total Fugitive Piping Emissions 0.09 0.41 NOTES: [1] Component counts provided by Savage. Flange counts were assumed to be 3 flanges per valve. [2] Emission factors were taken from (EPA) document EPA 453/R-95-017, page 2-14 for Petroleum Marketing Terminals. [3] The control credits for the 28PET visual inspection program are included in the emission factor. [4] Annual operation conservatively assumes that the lines will always be in VOC service. Component Total VOC Transloading Arm and Vapor Balance Line - Ethanol Page 13 of 14 TABLE B-14 Gypsum Storage Pile Emissions Savage Services Cedar City, Utah Silt Content 2 % Storage Duration 365 Days Dry Days Per Year 300 daysPercentage of time Wind Exceeds 12 mph1 100 % 1. Conservative Assumption Storage Pile Erosion Emissions (tons)(lb/ton)(lb/yr)(%)(lb/hr)(tpy)(lb/hr)(tpy)(lb/hr)(tpy) 1,000 2.30 2,301.02 70.00%0.08 0.35 0.08 0.35 0.08 0.35 1. Taken From Iron and Steel Plant Open Source Fugitive Emission Evaluation, Equation 8 (EPA-600/2-79-103) 2. Water Spray Number of Drops 2 Wind Speed 14 mph Moisture1 6.00 % 1. Water Sprays on the gypsum pile, so assuming maximum water content the emission equation allows Storage Pile Material Transfer Emissions PM PM10 PM2.5 ton/yr ton/hr (lb/ton)(lb/ton)(lb/ton)(lb/hr)(tpy)(lb/hr)(tpy)(lb/hr)(tpy) 150,000 100 1.94E-03 9.17E-04 1.39E-04 0.19 0.29 0.09 0.14 0.01 0.02 1. Taken from AP-42, Section 13.2.4, Equation 1 for Material Pile Storage Total Emissions (lb/hr)(tpy)(lb/hr)(tpy)(lb/hr)(tpy) 0.27 0.64 0.17 0.48 0.09 0.37 Uncontrolled Emission Rate Control Efficiency2 Emission Factors1 Transfer Data Erosion Data PM PM10 PM2.5 Uncontrolled Emissions Annual Throughput Hourly Throughput PM PM10 PM2.5 Conctrolled Emission Rate PM PM10 PM2.5Pile Size Emission Factor1 Page 14 of 14 Appendix C Material SDS Safety Data Sheet Gasoline 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Ingredient Percentage by weight Gasoline (86290-81-5) 100 Benzene (71-43-2) 0.1 - 4.9 n-Butane (106-97-8) < 10 Isopentane (201-142-8) 0 – 20 Cyclopentane (287-92-3) 0 – 20 Cyclohexane (110-82-7) 0 – 1 Hexene (592-41-6) 0 – 5 Iso-Octane (540-84-1) 0 – 10 Ethyl Alcohol (Ethanol) (64-17-5) 0 - 10 Ethyl benzene (100-41-4) < 3 Methyl-tertiary butyl ether (MTBE) (1634-04-4) 0 to 15.0 Tertiary-amyl methyl ether (TAME) (994-05-8) 0 to 17.2 Toluene (108-88-3) 1 - 25 1,2,4- Trimethylbenzene (95-63-6) < 6 Xylene, mixed isomers (1330-20-7) 1 - 15 Issued Date 18 May 2011 Use: Industrial use only Other Names: Regular Gasoline, Premium Gasoline, Conventional Gasoline; Reformulated Gasoline (RFG); Reformulated Gasoline Blendstock for Oxygenate Blending (RBOB); Unleaded Motor or Automotive Gasoline; Light Gasoline Supplier Telephone Numbers Emergency Tel. + 44 7775607852 Telephone Number: + 44 2071732236 Email: michele.sloan@trafigura.com Gasoline Page 2 of 9 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture 2.1.1. Classification according to Regulation (EU) 1272/2008 CLP-Classification : The product is classified as hazardous in accordance with Directive 1272/2008/EEC. Flam. Liq. 1 H224 Asp.Tox. 1 H304 Skin Irrit. 2 H315 Carc. 1B H350 Muta. 1B H340 Repr. 2 H361 STOT SE 3 H336 Aquatic Chronic 2 H411 For the full text of classification codes and/or H-phrases in this section, see section 16. 2.1.2. Classification according to EU Directives 67/548/EEC or 1999/45/EC Classification : The product is classified as dangerous in accordance with Directive 67/548/EEC. Carc.Cat.1;R45 Muta.Cat.1;R46 Repr.Cat.3;R62 Repr.Cat.3;R63 F+;R12 Xn;R65 Xi;R38 N;R51/53 R67 For the full text of R-phrases in this section, see section 16. 2.2 Label elements 2.2.1. Labelling according to Regulation (EU) 1272/2008 Signal word : Danger CLP Hazard statements : H224 - Extremely flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H340 - May cause genetic defects H350 - May cause cancer H361 - Suspected of damaging fertility or the unborn child H411 - Toxic to aquatic life with long lasting effects. CLP Precautionary statements: P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P202 - Do not handle until all safety precautions have been read and understood P308+P313 - IF exposed or concerned: Get medical advice/attention 2.2.2. Labelling according to Directives (67/548/EEC - 1999/45/EC) Not relevant 2.3. Other hazards No data available 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical composition: A mixture of refined petroleum product streams May contain small quantities of proprietary additives. 4. FIRST AID MEASURES Gasoline Page 3 of 9 Inhalation Get medical attention immediately. Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and wash underlying skin. Medical advice must be obtained urgently if product under high pressure has been injected through the skin. Eye Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists. Ingestion Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.. Advice to Doctor Symptomatic treatment and supportive therapy as indicated. Following severe exposure the patient should be kept under medical review for at least 48 hours. 5. FIRE FIGHTING MEASURES Specific Hazards Highly flammable liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway sewer or drain. Extinguishing Media Foam, fine water spray and dry chemical powder. Carbon dioxide, Clean Agents (e.g. Inergen, Argonite etc.), sand or earth may be used for small fires only. Unsuitable Extinguishing Media Do not use water in a jet. Hazardous Combustion Materials: Products are carbon oxides e.g. carbon monoxide and carbon dioxide Protective Equipment Proper protective equipment must be worn; this should include breathing apparatus when approaching a fire in a confined space. Other Information Gasoline Page 4 of 9 Keep adjacent drums and tanks cool by spraying with water from a safe location. If possible remove them from the danger zone. If adequate cooling cannot be achieved, the area needs to be evacuated, and further fire fighting and cooling attempts should be carried out from a safe location. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Remove all possible sources of ignition in the surrounding area. May ignite on surfaces at temperatures above auto-ignition temperature. Evacuate all personnel. Do not breathe fumes, vapour. Avoid contact with skin, eyes, clothing. Ventilate contaminated area thoroughly. Wear chemical resistant knee length safety boots and PVC jacket and trousers. Wear safety glasses or full face shield if splashes are likely to occur. Environmental Precautions Prevent from spreading or entering into drains and surface waters (e.g. lakes, ponds, ditches, rivers and streams) by using sand, earth, or other appropriate non-combustible barriers. Inform local authorities if impacts cannot be prevented. Clean-up Methods - Small Spillages To minimize soil and groundwater contamination, absorb liquid with sand, earth or other recommended sorbent material, which is commercially available. Sweep up and remove to a suitable, clearly marked container for disposal in accordance with local regulations. Do not disperse using water. Clean-up Methods - Large Spillages Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Dispose of as for small spills. Maritime Spillages Maritime spillages should be dealt with using a Shipboard Oil Pollution Emergency Plan (SOPEP), as required by MARPOL Annex 1 Regulation 26. Other Information Local authorities should be advised if significant spillages cannot be contained. If contamination of sites occurs remediation may require specialist advice. Observe all relevant local regulations. 7. HANDLING AND STORAGE Handling When using do not eat, drink or smoke. Only use in well-ventilated areas. Take precautionary measures against static discharges. Ensure all equipment is properly earthed. If using pressurised equipment, take extra care to avoid injection under the skin. Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Avoid prolonged or repeated contact with skin. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Prevent spillages. Cloth, paper and other materials that are used to absorb spills present a fire hazard. Avoid their accumulation by disposing of them safely and immediately. In addition to any specific recommendations given for controls of risks to health, safety and the environment, an assessment of risks must be made to help determine controls appropriate to local circumstances. Storage This product must never be stored in buildings occupied by people. Keep in a bunded area with a sealed (low permeability) floor, to provide containment against spillage. Seek specialist advice for the design, construction and operation of bulk storage facilities. Product Transfer Electrostatic charges may be generated during pumping. Ensure electrical continuity by bonding all equipment. Wait 2 minutes after tank filling (for tanks such as those on road tanker vehicles) before opening hatches or manholes. Wait 30 minutes after tank filling (for large storage tanks) before opening hatches or manholes. Tank Cleaning Cleaning, inspection and maintenance of storage tanks is a specialist operation that requires the implementation of strict procedures and precautions. These include issuing of work permits, gas-freeing of tanks, using a manned harness, lifelines, and wearing air-supplied breathing apparatus. Prior to entry and whilst cleaning is underway, the atmosphere within the tank must be monitored using an oxygen meter and Gasoline Page 5 of 9 explosimeter. In addition, appropriate electrochemical sensors or colorimetric tubes must be used to check for the presence of hydrogen sulphide. Recommended Materials For containers or container linings, use mild steel or stainless steel. Aluminium may also be used for applications where it does not present an unnecessary fire hazard. Examples of suitable materials are: high density polyethylene (HDPE), polypropylene (PP), and Viton (FKM), which have been specifically tested for compatibility with this product. For container linings, use amine-adduct cured epoxy paint. For seals and gaskets use: graphite, PTFE, Viton A, Viton B. Unsuitable Materials Synthetic materials such as plastics and fibreglass may be unsuitable for containers or container linings depending on the material specification and intended use. Examples of materials to avoid are: natural rubber (NR), nitrile rubber (NBR), ethylene propylene rubber (EPDM), polymethyl methacrylate (PMMA), polystyrene, polyvinyl chloride (PVC), polyisobutylene. However, some may be suitable for glove materials. Other Information Ensure that all local and international regulations regarding handling and storage facilities are followed. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION 8.1. Control parameters Component : Gasoline (86290-81-5) TLV-TWA (mg/m³) : 5 (Belgium, United Kingdom, France, the Netherlands, Spain, Finland, Denmark, Norway); 1 (Sweden); 250 (UT4, Kraftstoff, Germany) TLV-STEL (mg/m³) : 10 (Belgium, United Kingdom); 3 (Sweden) DNEL : Exposure scenario PNEC : Exposure scenario 8.2. Exposure controls Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. Respirator with a full face mask (EN 136) Respirator with a half face mask(EN 140) Recommended Filter type: A (EN 141) Hand protection: Rubber gloves - Nitrile rubber (EN 374). The selection of specific gloves for a specific application and time of use in a working area, should also take into account other factors on the working space, such as (but not limited to): other chemicals that are possibly used, physical requirements (protection against cutting/drilling, skill, thermal protection), and the instructions/specification of the supplier of gloves. Eye protection : Safety glasses (EN166) Engineering measures : Use only in area provided with appropriate exhaust ventilation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Colour Colourless to yellow Odour Petroleum hydrocarbon like Odour threshold Not available pH Value Not applicable Melting/Freezing Point Less that 60 ºC Initial Boiling Point Circa 25 to 200 ºC. Final Boiling Point Not determined Flash Point Less than minus 40 ºC Evaporation rate Not available Flammability (vapour) Yes Flammable Limits – Upper 7.6% in air Flammable Limits – Lower 1.4% in air Vapour Pressure 350 to 900 hPa @ 37.8 ºC Vapour Density (Air=1) Not available Gasoline Page 6 of 9 Density 660 to 750 kg/m3 at 15 ºC Solubility in Water Negligible Auto-Ignition Temperature Greater than 257 ºC Decomposition Temperature Not available Partition co-efficient, n-octanol/water 2.1 to 6 Kinematic Viscosity Less than 7 mm2/s at 40 ºC Explosive Properties Not available Oxidising Properties Not available The above properties are generic. There may be parameters for which National Specifications apply. 10. STABILITY AND REACTIVITY Stability Stable under normal use conditions. Hazardous polymerisation reactions will not occur. Conditions to Avoid Heat, flames and sparks. Materials to Avoid Strong oxidizing agents e.g. chlorates and ammonium nitrate. Hazardous Decomposition Products Hazardous decomposition products are not expected to form during normal storage. Thermal decomposition products will vary with conditions. Incomplete combustion will generate smoke, carbon dioxide and hazardous gases, including carbon monoxide 11. TOXICOLOGICAL INFORMATION Acute Toxicity - Oral Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death. Acute Toxicity - Dermal Likely to cause skin irritation. Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident). Acute Toxicity - Inhalation Aspiration hazard if swallowed- can enter lungs and cause damage. Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled. May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled. Eye Irritation Unlikely to cause more than transient stinging or redness if accidental eye contact occurs. Skin Irritation Slightly irritating. Respiratory Irritation Aspiration hazard if swallowed- can enter lungs and cause damage. Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled. May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled. Carcinogenicity No component of this product at levels greater than 0.1% is identified as a carcinogen by ACGIH, the International Agency for Research on Cancer (IARC) or the European Commission (EC). Mutagenicity Data not available Gasoline Page 7 of 9 Reproductive Toxicity Contains material which may cause birth defects based on animal data. Toluene Human Effects Data not available Other Information High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed. 12. ECOLOGICAL INFORMATION Basis for Assessment Fuels are typically made from blending several refinery streams. Ecotoxicological studies have been carried out on a variety of hydrocarbon blends and streams but not those containing additives. Information given is based on knowledge of the components and the ecotoxicology of similar products. Mobility Will float on fresh and seawater. Contains volatile components. Partly evaporates from water or soil surfaces, but a small proportion will remain after one day. If it enters soil, it will adsorb to soil particles and will not be mobile. Large volumes may penetrate soil and could contaminate groundwater. Some components may partition to the aqueous phase. Persistence / Degradability Major components are inherently biodegradable. Persists under anaerobic conditions. The volatile components oxidise rapidly by photochemical reactions in air. Bioaccumulation Contains components which may have the potential to bioaccumulate. May cause tainting of fish and shellfish. Ecotoxicity Poorly soluble mixture. Product is classified as harmful to aquatic organisms, May cause physical fouling of aquatic organisms. 13. DISPOSAL CONSIDERATIONS Disposal should always be via an authorised person/licensed waste disposal contractor with local regulations Waste Disposal Waste arising from a spillage or tank cleaning should be disposed of in accordance with prevailing regulations. The competence of the collector or contractor to deal satisfactorily with this type of product should be established beforehand. Do not dispose into the environment, in drains or in water courses. Do not dispose of tank water bottoms by allowing them to drain into the ground. This will result in soil and groundwater contamination. Product Disposal As for waste disposal. Container Disposal Recycle or dispose of in accordance with the legislation in force with a recognised collector or contractor. Do not pollute the soil, water or environment with the waste product. 14. TRANSPORT INFORMATION Transport Information Regulatory Information UN number Proper Shipping Name Class Packing Group Label Additional Information ADR/RID 1203 Motor Spirit or Gasoline or Petrol 3 II UK Emergency Action Code: 3YE Gasoline Page 8 of 9 ADNR 1203 Motor Spirit or Gasoline or Petrol 3 II IMDG 1203 Motor Spirit or Gasoline or Petrol 3 II IATA/ICAO 1203 Motor Spirit or Gasoline or Petrol 3 II Other Information MARPOL rules apply for bulk shipments by sea. 15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations No data available 15.1.2. National regulations WGK : 3 15.2. Chemical Safety Assessment Chemical Safety assessment : A Chemical Safety Assessment has been carried out for this substance 16. OTHER INFORMATION Text of R phrases mentioned in Section 3 : R12 -Extremely flammable. R38 -Irritating to skin. R45 -May cause cancer. R46 -May cause heritable genetic damage. R51/53 -Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 -Possible risk of impaired fertility. R65 -Harmful: may cause lung damage if swallowed. R67 -Vapours may cause drowsiness and dizziness. H-statements components : H224 -Extremely flammable liquid and vapour. H304 -May be fatal if swallowed and enters airways. H315 -Causes skin irritation. H336 -May cause drowsiness or dizziness. H340 -May cause genetic defects H350 -May cause cancer H361 -Suspected of damaging fertility or the unborn child H411 -Toxic to aquatic life with long lasting effects. Sources of key data used to compile the datasheet : European Chemicals Bureau 20100824 CONCAWE C&L update version 3.0 SDS Distribution This document contains important information to ensure the safe storage, handling and use of this product. The information in this document should be brought to the attention of the person in your organisation responsible for advising on safety matters. Restrictions This product must not be used in applications other than those recommended without first seeking the advice of the supplier. Restricted to professional users only. Gasoline Page 9 of 9 Further Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It does not constitute a guarantee for any specific property of the product. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with the other materials or in any other process. The stated MSDS is reliable to the best of the company’s knowledge and believed accurate as of the date indicated. However, no representation, warranty or guarantee of any kind, express or implied, is made as to its accuracy, reliability or completeness and we assume no responsibility for any loss, damage or expense, direct or consequential, arising out of use. It is the user’s responsibility to satisfy themselves as to the suitableness and completeness of such information for their own particular use. SAFETY DATA SHEET 1. Identification ETHANOL (FUEL GRADE)Product identifier Other means of identification 5393SDS number FHR_ETOHFG_US_ENProduct code DENATURED FUEL ETHANOL * ETHANOL - DENATURED * ETHYL ALCOHOL (FUEL GRADE)Synonyms Gasoline blending component.Recommended use Not for human consumptionRecommended restrictions Manufacturer/Importer/Supplier/Distributor information Flint Hills Resources, LPSupplier 4111 E. 37th St. North Wichita, KS 67220-3203 United States Telephone Numbers - 24 hour Emergency Assistance 800-424-9300 (CCN: 8586)Chemtrec (US) Telephone numbers General Assistance 316-828-79888-4:45 (M-F, CST) msdsrequest@fhr.comSDS Assistance E-mail 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 2ASerious eye damage/eye irritationHealth hazards Category 1BGerm cell mutagenicity Category 1ACarcinogenicity Category 2Reproductive toxicity Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. Harmful to aquatic life with long lasting effects. ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 1 / 10 U.S. Oil SDS #3320 Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist/vapors. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. In case of fire: Use appropriate media to extinguish. Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information None. 3. Composition/information on ingredients Mixtures 64-17-5 92 - 100Ethanol CAS number %Chemical name Mixture 1 - < 3Denaturant 7732-18-5 1Water 71-43-2 < 1Benzene 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. Get medical attention if symptoms occur.Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Coughing. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Water fog. Alcohol resistant foam. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 2 / 10 U.S. Oil SDS #3320 Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Highly flammable liquid and vapor.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapors. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. This product is miscible in water. Prevent product from entering drains. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Put material in suitable, covered, labeled containers. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist/vapors. Avoid contact with eyes. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 3 / 10 U.S. Oil SDS #3320 8. Exposure controls/personal protection Occupational exposure limits U.S. - OSHA ValueComponentsType TWA 1 ppmBenzene (CAS 71-43-2) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) ValueComponentsType STEL 5 ppmBenzene (CAS 71-43-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponentsType PEL 1900 mg/m3Ethanol (CAS 64-17-5) 1000 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) ValueComponentsType Ceiling 25 ppmBenzene (CAS 71-43-2) TWA 10 ppm US. ACGIH Threshold Limit Values ValueComponentsType STEL 2.5 ppmBenzene (CAS 71-43-2) TWA 0.5 ppm STEL 1000 ppmEthanol (CAS 64-17-5) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponentsType STEL 1 ppmBenzene (CAS 71-43-2) TWA 0.1 ppm TWA 1900 mg/m3Ethanol (CAS 64-17-5) 1000 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 25 µg/g S-Phenylmerca pturic acid Creatinine in urine *Benzene (CAS 71-43-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Benzene (CAS 71-43-2)Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Benzene (CAS 71-43-2)Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station and safety shower. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Nitrile, butyl rubber or neoprene gloves are recommended. Hand protection ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 4 / 10 U.S. Oil SDS #3320 Skin protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other Use a chemical respirator with organic vapor cartridge and full facepiece when concentration exceeds exposure limits. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards Observe any medical surveillance requirements. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Liquid.Form Clear, colorless.Color Alcohol.Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range > 150 °F (> 65.6 °C) Flash point < 32.0 °F (< 0 °C) Pensky-Martens Closed Cup Evaporation rate Not available. Not applicable.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.4 % Flammability limit - upper (%) 19 % Explosive limit - lower (%)See flammability limit. Explosive limit - upper (%)See flammability limit. Vapor pressure 7.91 kPa at 25°C Vapor density 1.59 Relative density 0.791 - 0.793 Relative density temperature 68 °F (20 °C) Solubility(ies) Solubility (water)Very soluble. Partition coefficient (n-octanol/water) -0.31 (as ethanol) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 0.79 g/cm³ estimated at 20 °C Dynamic viscosity 0.5 mPa·s Dynamic viscosity temperature 158 °F (70 °C) Electrostatic properties Conductivity > 2000 pS/m Not explosive.Explosive properties Heat of combustion 24.7 kJ/g Kinematic viscosity 0.6389 mm²/s estimated Not oxidizing.Oxidizing properties ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 5 / 10 U.S. Oil SDS #3320 Percent volatile 100 Surface tension 22.75 mN/m 68°F (20°C) VOC 100 % 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Prolonged skin contact may cause temporary irritation. Eye contact Causes serious eye irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Coughing. Information on toxicological effects Acute toxicity Test ResultsComponentsSpecies Benzene (CAS 71-43-2) Inhalation Acute LC50 Rat 10000 mg/l, 7 Hours Oral LD50 Rat 3306 mg/kg Ethanol (CAS 64-17-5) Inhalation Acute LC50 Mouse 39 g/m3, 4 Hours Vapor Oral LD50 Rat 7000 - 11000 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization May cause genetic defects.Germ cell mutagenicity Carcinogenicity May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Benzene (CAS 71-43-2)1 Carcinogenic to humans. NTP Report on Carcinogens Benzene (CAS 71-43-2)Known To Be Human Carcinogen. ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 6 / 10 U.S. Oil SDS #3320 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Benzene (CAS 71-43-2)Cancer Suspected of damaging fertility or the unborn child.Reproductive toxicity Specific target organ toxicity - single exposure May cause respiratory irritation. May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. 12. Ecological information Harmful to aquatic life with long lasting effects.Ecotoxicity Components Test ResultsSpecies Benzene (CAS 71-43-2) Aquatic EC50Crustacea 8.76 - 15.6 mg/l, 48 HoursWater flea (Daphnia magna) LC50Fish 5 mg/l, 96 HoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Ethanol (CAS 64-17-5) Aquatic Acute LC50Crustacea 5012 mg/l, 48 hoursCeriodaphnia dubia 454 mg/l, 11 daysDaphnia magna LC50Fish 13480 mg/l, 96 hoursPimephales promelas Chronic NOECCrustacea 9.6 mg/l, 10 daysCeriodaphnia dubia No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Benzene (CAS 71-43-2)2.13 Ethanol (CAS 64-17-5)-0.31 The product is soluble in water.Mobility in soil Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer of the waste, and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1987UN number Alcohols, n.o.s. (Ethanol, Gasoline)UN proper shipping name ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 7 / 10 U.S. Oil SDS #3320 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 172, IB2, T7, TP1, TP8, TP28Special provisions 4b, 150Packaging exceptions 202Packaging non bulk 242Packaging bulk IATA UN1987UN number Alcohols, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Environmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1987UN number ALCOHOLS, N.O.S.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Marine pollutant Environmental hazards F-E, S-DEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Benzene (CAS 71-43-2)Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Benzene (CAS 71-43-2)Cancer Central nervous system Blood Aspiration Skin Eye respiratory tract irritation Flammability All components of the mixture on the TSCA 8(b) inventory are designated “active”.Toxic Substances Control Act (TSCA) SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 8 / 10 U.S. Oil SDS #3320 YesSARA 311/312 Hazardous chemical Flammable (gases, aerosols, liquids, or solids) Serious eye damage or eye irritation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single or repeated exposure) Hazard not otherwise classified (HNOC) Classified hazard categories SARA 313 (TRI reporting) Chemical name % by wt.CAS number Benzene < 171-43-2 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Benzene (CAS 71-43-2) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Contains component(s) regulated under the Safe Drinking Water Act.Safe Drinking Water Act (SDWA) FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace Ethanol (CAS 64-17-5)Low priority US state regulations US. Massachusetts RTK - Substance List Benzene (CAS 71-43-2) Ethanol (CAS 64-17-5) US. New Jersey Worker and Community Right-to-Know Act Benzene (CAS 71-43-2) Ethanol (CAS 64-17-5) US. Pennsylvania Worker and Community Right-to-Know Law Benzene (CAS 71-43-2) Ethanol (CAS 64-17-5) US. Rhode Island RTK Benzene (CAS 71-43-2) Ethanol (CAS 64-17-5) California Proposition 65 This product can expose you to Benzene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. WARNING: California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2)Listed: February 27, 1987 California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2)Listed: December 26, 1997 California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2)Listed: December 26, 1997 US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Benzene (CAS 71-43-2) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS)YesAustralia Domestic Substances List (DSL)YesCanada Non-Domestic Substances List (NDSL)NoCanada Inventory of Existing Chemical Substances in China (IECSC)YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS)NoEurope Inventory of Existing and New Chemical Substances (ENCS)YesJapan ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 9 / 10 U.S. Oil SDS #3320 Country(s) or region Inventory name On inventory (yes/no)* Existing Chemicals List (ECL)YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesPhilippines Taiwan Chemical Substance Inventory (TCSI)YesTaiwan *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico 16. Other information, including date of preparation or last revision 03-April-2019Issue date -Revision date Version #01 WARNING -- WARNING: THIS PRODUCT, AS INDICATED, CONTAINS ETHANOL. ETHANOL, OR FUELS BLENDED WITH ETHANOL, MAY DAMAGE OR HARM FUEL STORAGE TANKS, PIPING, METERS, ENGINES AND/OR RELATED FUEL SYSTEMS (INCLUDING, BUT NOT LIMITED TO MARINE EQUIPMENT). IT IS IMPERATIVE THAT BEFORE YOU USE OR STORE THIS PRODUCT YOU CONDUCT AN ASSESSMENT TO DETERMINE WHETHER THIS FUEL IS COMPATIBLE WITH YOUR PARTICULAR EQUIPMENT/MACHINERY IN WHICH THIS FUEL MIGHT BE STORED, TRANSPORTED OR COMBUSTED. DISCLAIMER OF ALL WARRANTIES: FLINT HILLS RESOURCES MAKES NO WARRANTY EXPRESS OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR WARRANTY FOR FITNESS FOR ANY PARTICULAR PURPOSE AND HEREBY DISCLAIMS ALL SUCH WARRANTIES REGARDING THIS PRODUCT. Further information Health: 2* Flammability: 3 Physical hazard: 0 HMIS® ratings NFPA ratings 02 3 NOTICE: The information contained in this document is based on data considered to be accurate as of the preparation date of this Safety Data Sheet (SDS) and was prepared pursuant to applicable Government regulation(s). This SDS may not be used as a commercial specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made as to the accuracy or comprehensiveness of the above data and safety information, nor is any authorization given or implied to practice any patented invention without a license. Additional information may be needed to evaluate other uses of the product, including use of the product in combination with any materials or in any processes other than those specifically referenced. Information provided about any hazards that may be associated with the product is not meant to suggest that use of the product in a given application will necessarily result in any exposure or risk to workers or the general public. Purchasers and users of the product are responsible for determining that this product is suitable for the intended use and application. No responsibility can be assumed by vendor for any damage or injury resulting from failure to adhere to recommended uses, or from any hazards inherent to the product. Purchasers and users assume all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. Purchasers and users of the product should explicitly advise their employees, agents, contractors and customers who will use the product of this SDS. Disclaimer ETHANOL (FUEL GRADE)SDS US 948670 Version #: 01 Revision date: - Issue date: 03-April-2019 10 / 10 U.S. Oil SDS #3320