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HomeMy WebLinkAboutDAQ-2025-0019471 DAQC-350-25 Site ID 10335 (B4) MEMORANDUM TO: STACK TEST FILE – TESORO REFINING AND MARKETING COMPANY THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Paul Morris, Environmental Scientist DATE: April 8, 2025 SUBJECT: Location: 474 West 900 North, Salt Lake City, Salt Lake County, Utah Contact: Rheannon Schaefer – 801-367-8102 Tester: Alliance Technical Group, LLC Sources: Gasoline Hydrotreater (GHT) F701 FRS ID #: UT0000004903500004 AO# DAQE-AN0103350075-18 dated January 11, 2018 Subject: Review of Pretest Protocol dated March 31, 2025 On March 31, 2025, the Utah Division of Air Quality (DAQ) received a protocol for testing of the Tesoro Refining and Marketing Company’s GHT F701 located in Salt Lake City, Utah. Testing will be performed on April 29, 2025, to determine compliance with the emission limits found in AO Condition II.B.7.a PROTOCOL CONDITIONS: 1. RM 1 used to determine sample velocity traverses: OK 2. RM 3A used to determine O2 and CO2 concentrations: OK 3. RM 7E used to determine NOx emissions: OK DEVIATIONS: No deviations were noted. CONCLUSION: The protocol appears to be acceptable. RECOMMENDATION: Send protocol review and test date confirmation notice. ATTACHMENTS: Stack testing protocol 6 3 DEPARTMENT OF ENVIRONMENTAL OIJAUTY l'lAR 3 1 2025 DMSTON OF AIR Ou Unt March 31,2025 Mr. Paul Morris Division of Air Quality Department of Environmental Quality 195 North 1950 West P.O. Box 144820 Salt Lake city, uT 84114 Hand Delivered Tesoro Refining and Marketing Company's Salt Lake City Refinery GHT F-701 Nitrogen Oxides Emissions Test Protocol Dear Mr. Morris: Enclosed please find the protocol for the Gasoline Hydrotreater (GHT) F-701 Furnace Nitrogen Oxides (NOx) Emissions Performance Test tentatively scheduled to be conducted on April 29,2025. The purpose of the testing program is to determine the NOx emissions rate of the GHT F-701 furnace while the unit is running at maximum rate. Although this is not an annual environmental requirement, the operations group made this decision at the last minute. We recognize that it falls just within our 30-day protocol window and have generated the test plan as quickly as possible. Please contact Rheannon Schaefer at (801) 366-2033 ifyou have any questions. Sincerely, MU-"4pr Rheannon Schaefer U Environmental Specialist Attachment DEPANTMENT OF ENVIRONMENTAL OUATITY MAR 3 1 2325 DrvtsroN tr ArR Otrurv flawl 0elivcreA ' r_=Alta i [:.Ol--]NICA C;ROLI I) Site Specific Test Plan Tesoro Refining and Marketing Company Salt Lake City Refinery 474 West 900 North Salt Lake ciry, uT 84103 Source to be Tested: GHT - F70l Proposed Test Date: April 29,2025 Project No. AST -2025-1868 Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley Ciry, UT 84120 AI Fla T! C iIIIICAL GROUT-Site Specific Test Plan Test Program Summary I Resulatory Information '' :':..\ ;lO : i'.i Peymit No.. Source Information DAQE-AN103350075-18 Source Name Gasoline Hydrotreater (GHT) Contact Information Source ID F70l Target Parameter NOx Test Location Tesoro Refining and Marketing Company Salt Lake City Refinery 474 West 900 North Salt Lake City, UT 84103 Facility Contact Rheannon Schaefer Rschaefer@marathonpetro leum. com (801) 367-8r02 Test Company Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, Lm 84120 Project Manager Charles Horton charles.horton@alliancetg.com (3s2) 663-7s68 Field Team Leader Alan Jensen alan jensen@alliancetg.com (847)220-3949 (subject to change) QA/QC Manager Kathleen Shonk katie.shonk@alliancetg.com (8t2) 4s2-478s Test Plarfiepod Coordinator Delaine Spangler delaine. spangler@alliancetg. com AST-2025- I 868 Tesoro - Salt Lake City, UT Page i Site Spectfc Test Plan Table of Contents TABLE OF CONTENTS 2.0 Summary of Test Program .................2-l 2.1 Process/Confrol System Parameters to be Monitored and Recorded...... ...........2-l 3.1 U.S. EPA Reference Test Method I - Sample Point Determination.......... ....... 3-1 3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide........ ............ 3-1 3.3 U.S. EPA Reference Test Method 7E - Nitrogen Oxides ............ 3-1 3.4 U.S. EPA Reference Test Method 19 -Mass Emission Factors ........................3-2 3.5 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification. ........................3-2 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Methods 3A and 7E................................3-2 LIST OF TABLES Table 2-l: Program Outline and Tentative Test Schedu1e................... ......2-l LIST OF APPENDICES AppendixA MethodlData Appendix B Example Field Data Sheets AST-2025- I 868 Tesoro - Salt Lake City, UT Page ii pul6rpe Gno[i:-'Site Specific Test Plan Introduction 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by Marathon Petroleum Corporation (MPC) to conduct compliance testing at the Tesoro Refining and Marketing Company (Tesoro) Salt Lake City, Utah refinery. Portions of the facility are subject to provisions of the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN103350075-18. Testing will be conducted to determine the emission rate of nihogen oxides (NOx) from the Gasoline Hydrotreater (GHT) F70l fumace stack. This site-specific test plan (SSTP) has been prepared to address the notification and testing requirements of the UDAQ permit. 1.1 Facility Descriptions The Gasoline Hydrotreating Unit (GHT) F-701 furnace is fired using plant gas to preheat gasoline range material. The unit produces low sulfur gasoline to meet Tier III standards. 1.2 Project Team Personnel planned to be involved in this project are identified in the following table. Table 1-1: Project Team 1.3 Safety Requirements Testing personnel will undergo site-specific safety taining for all applicable areas upon arrival at the site. Alliance personnel will have current OSHA or MSHA safety taining and be equipped with hard hats, safety glasses with side shields, steel-toed safety shoes, hearing protection, fue resistant clothing, and fall protection (including shock corded lanyards and full-body hamesses). Alliance personnel will conduct themselves in a manner consistent wittr Client and Alliance's safety policies. A Job Safety Analysis (JSA) will be completed daily by the Alliance Field Team Leader. MPC Personnel Rheannon Schaefer Regulatory Agency UDAQ Alliance Personnel Alan Jensen other field personnel assigned at time of testing event AST-2025- l 868 Tesoro - Salt Lake City, UT Page l-l AI Site Specific Test Plan Summary ofTest Programs 2.0 Summary of Test Program All testing will be performed in accordance with specifications stipulated in U.S. EPA Reference Test Methods 3A, 78, and 19. Table 2-1 presents an outline and tentative schedule for the emissions testing program. The following is a sunmary of the test objectives. o Emissions testing will be conducted on the exhaust of the F-701 furnace stack. o Each of the three (3) test runs will be I hour in duration. 2.1 Process/Control System Parameters to be Monitored and Recorded Plant personnel will collect operational and parametric data at least once every 15 minutes during the testing. The following list identifies the measurements, observations and records that will be collected during the testing program: . Fuel Gas Analysis - one per test program o Fuel Firing Rate 2.2 Proposed Test Schedule Table 2-l presents an outline and tentative schedule for the emissions testing program. Table 2-1: Program Outline and Tentative Test Schedule 2.3 Test Report The final test report must be submitted within 60 days of the completion of the performance test and will include the following information. o Introduction -Bief discussion of project scope of work and activities. . Results and Discussion - A summary of test results and process/control system operational data with comparison to regulatory requirements or vendor guarantees along with a description of process conditions and/or testing deviations that may have affected the testing results. o Methodologt - A description of the sampling and analytical methodologies. . Sample Calculations - Example calculations for each target parameter. o Field Data - Copies of actual handwritten or electronic field data sheets. o Quality Control Data - Copies of all instrument calibration data and/or calibration gas certificates. c Process Operating/Control System Data - Process operating and control system data (as provided by Tesoro) to support the test results. Fla Testing Locetion Perameter US EPA Method No. of Runs Run Duration EsL Onsite Time DAY I -ApriI29,2025 Equipment Setup & Pretest QA/QC Checks 8hr GHT Oz/COz 3A J 60 minNOx7E Mass Emission Factors l9 AST-2025- l 868 Tesoro - Satt Lake City, UT Pagc 2-l put6rpe Sile Specific Test Plan Testing Methodologt 3.0 Testing Methodology This section provides a description of the sampling and analyical procedures for each test method that will be employed during the test progrirm. All equipment, procedures and quality assurance measures necessary for the completion of the test program meet or exceed the specifications of each relevant test method. The emission testing program will be conducted in accordance with the test methods listed in Table 3-1. Table 3-l: Source Testing Methodology All stack diameters, depths, widths, upstream and downstream disturbance distances and nipple lengths will be measured on site with an EPA Method I verification measurement provided by the Field Team Leader. These measurements will be included in the test report. 3.1 U.S. EPA Reference Test Method 1 - Sample Point Determination The sampling location and number of traverse (sampling) points will be selected in accordance with U.S. EPA Reference Test Method l. To determine the minimum number of traverse points, the upstream and downstream distances will be equated into equivalent diameters and compared to Figure l-2 (measuring velocity alone) in U.S. EPA Reference Test Method l. 3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide The oxygen (Oz) and carbon dioxide (COz) testing will be conducted in accordance with U.S. EPA Reference Test Method 3A. Data will be collected online and reported in one-minute averages. The sampling system will consist of a stainless steel probe, Teflon sample line(s), gas conditioning system and the identif,red gas analyzer. The gas conditioning system will be a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line is used, then a portable non-contact condenser will be placed in the system directly after the probe. Otherwise, a heated Teflon sample line will be used. The quality control measures are described in Section 3.6. 3.3 U.S. EPA Reference Test Method 7E - Nitrogen Oxides The nitrogen oxides (NOx) testing will be conducted in accordance with U.S. EPA Reference Test Method 78. Data will be collected online and reported in one-minute averages. The sampling system will consist of a stainless steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system will be a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line is used, then a portable non-contact condenser will be placed in the system directly after the probe. Otherwise, a heated Teflon sample line will be used. The quality control measlues are described in Section 3.6. Peremeter U.S. EPA Reference Test Methods Notes/Remlrks Sample Point Determination I Oxygen/Carbon Dioxide 3A lnstrumental Analysis Nitrogen Oxides 7E Instrumental Analysis Mass Emission Factors r9 Fuel Factors/Fleat lnputs Gas Dilution System Certification 205 AST-2025- l 868 Tesoro Salt Lake Ciry, UT Page 3-l pd/IATEEI Site SpeciJlc Test Plan Testing Methodologt.,. il t) i--t i: 3.4 U.S. EPA Reference Test Method 19 -Mass Emission Factors A Fuel sample will be procured and sent to the identified analytical laboratory. The laboratory analysis will be used to calculate a wet or dry O, based F-Factor in accordance with U.S. EPA Reference Test Method 19. The mass emission factor (lb/Ir,IMBtu) will be calculated using the pollutant concenfation, 02 concentration and the calculated F-Factor. 3.5 U.S. EPA Reference Test Method 205 - Ges Dilution System Certilicetion A calibration gas dilution system field check will be conducted in accordance with U.S. EPA Reference Method 205. An initial three (3) point calibration will be conducted, using individual Protocol I gases, on the analyzer used to complete the dilution system field check. Multiple dilution rates and total gas flow rates will be utilized to force the dilution system to perform two dilutions on each mass flow conffoller. The diluted calibration gases will be sent directly to the analyzer, and the analyzer response will be recorded in an electronic field data sheet. A mid-level supply gas, with a cylinder concentration within lDYo of one of the gas divider settings described above, will be introduced directly to the analyzer, and the analyzer response recorded in an electonic field data sheet. The cylinder concentration and the analyzer response must agree within 2o/o. T\ese steps will be repeated three (3) times. The average analyzer response must agree within 2Yo of the predicted gas concentration. No single injection shall differ more than ZYo from the average instrument response for that dilution. 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Methods 3A and 7E Cylinder calibration gases will meet EPA Protocol I (+l- 2%) standards. Copies of all calibration gas certificates will be included in the Quality Assurance/Quality Control Appendix of the report. Low Level gas will be intoduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading is stable, the analyzer value will be recorded. This process will be repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High-Level calibration gases will be sequentially introduced directly to the analyzer. The Calibration Error for each gas must be within 2.0 percent of the Calibration Span or 0.5 ppmv/Yo absolute difference. High or Mid-Level gas (whichever is closer to the stack gas concentration) will be introduced at the probe and the time required for the analyzer reading to reach 95 percent or 0.5 ppm/% (whichever was less restrictive) of the gas concentration will be recorded. The analyzer reading will be observed until it reaches a stable value, and this value will be recorded. Next, Low-Level gas will be introduced at the probe and the time required for the malyzer reading to decrease to a value within 5.0 percent or 0.5 ppm/% (whichever was less restrictive) will be recorded. If the Low- Level gas is zero gas, the acceptable response must be 5.0 percent of the upscale gas concentration or 0.5 ppm/% (whichever was less restrictive). The analyzer reading will be observed until it reaches a stable value, and this value will be recorded. The measurement system response time and initial system bias will be determined from these data. The System Bias for each gas must be within 5.0 percent of the Calibration Span or 0.5 ppmv/% absolute difference. High or Mid-Level gas (whichever is closer to the stack gas concentration) will be introduced at the probe. After the analyzer response is stable, the value will be recorded. Next, Low-Level gas will be introduced at the probe, and the atalyzer value will be recorded once it reaches a stable response. The System Bias for each gas must be within 5.0 percent of the Calibration Span or 0.5 ppmv/% absolute difference or the data is invalidated, and the Calibration Error Test and System Bias must be repeated. AST-2025- I 868 Tesoro - Salt Lake City, UT Page3-2 pul6nrcE) ciitJt{1.\i (l fl tl ., r;Site Specific Test Plan Testing Methodologl The Drift between pre- and post-run System Bias must be within 3 percent of the Calibration Span or 0.5 ppmv/% absolute difference or the Calibration Error Test and System Bias must be repeated. To determine the number of sampling points, a gas stratification check will be conducted prior to initiating testing. The pollutant concenffations will be measured at twelve traverse points (as described in Method l) or three points (16.7, 50.0 and 83.3 percent of the measurement line). Each haverse point will be sampled for a minimum of twice the system response time. If the pollutant concentrations at each traverse point do not differ more than SYo or 0.5 ppml0.3% (whichever is less restrictive) of the average pollutant concentration, then single point sampling will be conducted during the test runs. If the pollutant concentration does not meet these specifications but differs less than l0o/o or I .0 ppml0.5% from the average concentration, then three (3) point sampling will be conducted (stacks less than 7.8 feet in diameter - 16.'7, 50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, 1.0, and 2.0 meters from the stack wall). If the pollutant concentration differs by more than l0% or 1.0 ppm/0.5o/ofrom the average concentration, then sampling will be conducted at a minimum of twelve (12) traverse points. Copies of stratification check data will be included in the Quality Assurance/Quality Control Appendix of the report. An NOu - NO converter check will be performed on the analyzer prior to initiating testing or at the completion of testing. An approximately 50 ppm nitrogen dioxide cylinder gas will be introduced directly to the NOx analyzer and the instrument response will be recorded in an electonic data sheet. The instrument response must be within +/- l0 percent of the cylinder concentration. A Data Acquisition System with battery backup will be used to record the instrument response in one (1) minute averages. The data will be continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data will also be saved to the Alliance server. All data will be reviewed by the Field Team Leader before leaving *re facility. Once arriving at Alliance's office, all written and electronic data will be relinquished to the report coordinator and then a final review will be performed by the Project Manager. AST-2025- I 868 Tesoro - Salt Lake City, UT Page 3-3 AIrIlll la_-.r Site Specific Test Plan Ouality Assuranc e Pr o gr am 4.0 Quality Assurance Progrem Alliance follows the procedures outlined in the Quality Assurance/Quality Control Management Plan to ensure the continuous production of useful and valid data throughout the course of this test program. The QC checks and procedures described in this section represent an integral part of the overall sampling and analytical scheme. Adherence to prescribed procedures is quite often the most applicable QC check. 4.1 Equipment Field test equipment is assigned a unique, permanent identification number. Prior to mobilizing for the test program, equipment is inspected before being packed to detect equipment problems prior to arriving on site. This minimizes lost time on the job site due to equipment failure. Occasional equipment failure in the field is unavoidable despite the most rigorous inspection and maintenance procedures. Therefore, replacements for critical equipment or components are brought to the job site. Equipment retuming from the field is inspected before it is returned to storage. During the course of these inspections, items are cleaned, repaired, reconditioned and recalibrated where necessary. Calibrations are conducted in a manner, and at a frequency, which meets or exceeds U.S. EPA specifications. The calibration procedures outlined in the U.S. EPA Methods, and those recommended within the Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III (EPA-600/R-94/038c, September 1994) are utilized. When these methods are inapplicable, methods such as those prescribed by the American Society for Testing and Materials (ASTM) or other nationally recognized agency may be used. Data obtained during calibrations is checked for completeness and accuracy. Copies of calibration forms are included in the report. The following sections elaborate on the calibration procedures followed by Alliance for these items of equipment. o Dry Gas Meter and Orifice. A full meter calibration using critical orifices as the calibration standard is conducted at least semi-annually, more frequently if required. The meter calibration procedure determines the meter correction factor (Y) and the meter's orifice pressure differential (AH@). Alliance uses approved Alternative Method 009 as a post-test calibration check to ensure that the correction factor has not changed more than 5% since the last full meter calibration. This check is performed after each test series. r Pitot Tubes and Manometers. Type-S pitot tubes that meet the geometric criteria required by U.S. EPA Reference Test Method 2 are assigned a coefficient of 0.84 unless a specific coefficient has been determined from a wind tunnel calibration. If a specific coeffrcient from a wind tunnel calibration has been obtained that coeffrcient will be used in lieu of 0.84. Standard pitot tubes that meet the geometric criteria required by U.S. EPA Reference Test Method 2 are assigned a coefficient of 0.99. Any pitot tubes not meeting the appropriate geometric criteria are discarded and replaced. Manometers are verified to be level and zeroed prior to each test run and do not require further calibration. o Temoerature Measurins Devices. All thermocouple sensors mounted in Dry Gas Meter Consoles are calibrated semi-annually with a MST-traceable thermocouple calibrator (temperature simulator) and verified during field use using a second NlST-raceable meter. NlST-traceable thermocouple calibrators are calibrated annually by an outside laboratory. o Nozzles. Nozzles are measured three (3) times prior to initiating sampling with a caliper. The maximum difference between any two (2) dimensions is 0.004 in. o Digital Calipers. Calipers are calibrated annually by Alliance by using gage blocks that are calibrated annually by an outside laboratory. 7la AST-2025-l 868 Tesoro - Salt Lake City, UT Page 4- I 4.2 TECtll.l uct,lF Site SpeciJic Test Plan Oua liv As sur anc e Pro gr amH'I Barometer. The barometric pressure is obtained from a nationally recognized agency or a calibrated barometer. Calibrated barometers are checked prior to each field trip against a mercury barometer. The barometer is acceptable if the values agree within + 2 percent absolute. Barometers not meeting this requirement are adjusted or taken out ofservice. Balances and Weights. Balances are calibrated annually by an outside laboratory. A functional check is conducted on the balance each day it is use in the field using a calibration weight. Weights are re-certified every two (2) years by an outside laboratory or internally. If conducted internally, they are weighed on a NIST traceable balance. If the weight does not meet the expected criteria, they are replaced. Other Equipment. A mass flow controller calibration is conducted on each Environics system annually following the procedures in the Manufacturer's Operation manual. A methane/ethane penetration factor check is conducted on the total hydrocarbon analyzers equipped with non-methane cutters every six (6) months following the procedures in 40 CFR 60, Subpart JJJJ. Other equipment such as probes, umbilical lines, cold boxes, etc. are routinely maintained and inspected to ensure that they are in good working order. They are repaired or replaced as needed. Field Sampling Field sampling will be done in accordance with the Standard Operating Procedures (SOP) for the applicable test method(s). General QC measures for the test program include: . Cleaned glassware and sample tain components will be sealed until assembly. o Sample tains will be leak checked before and after each test run. o Appropriate probe, filter and impinger temperatures will be maintained. . The sampling port will be sealed to prevent air from leaking from the pod. . Dry gas meter, AP, AH, temperahue and pump vacuum data will be recorded during each sample point. o An isokinetic sampling rate of 90-l l0% will be maintained, as applicable. . All raw data will be maintained in organized manner. . All raw data will be reviewed on a daily basis for completeness and acceptability. AST-2025- r 868 Tesoro - Salt Lake City, UT Page 4-2 -'Al6rrcesOr traF IL:s'\.-, Ifirdor Tmrc R.ftrhr - Srlt hk. CItv R.filcry Method I Data So!rcG GET Ihct Orlcltrdo!: Duct Dalgr: Irlrtrlc. froE Fu W.ll to Ortddc ot Port: NtPpl. L.ngthl Dcptl ofDrd: Vdicd Circular 'xgu-r*.*-lbln lo h96.J0 Crox Sccdonrt A16 ofDuc: 50.79 tt' No. ofTql Port : 2 Dl.trlcc Ar 15.0 ll Dlttac. A Dld lrlro.t 6r I J (D!tl bc > 0.5) D1.4.tr.. Br 20.0 i Dttrc. B Doct IXrDCtcn: 2.5 (E!tt b. > 2) L It. 6H-.&CFdl-b.(rdt*c-h-r , CIRCULARDU L(rcATION OF STNATIFICATION FOI\TTS Nufrbet oftruvrsc poldls oil o diuhalet t 3 1 5 6 1t 9 IO ll t2 2 I I S 6 1 t I l0 ll t2 14.6 t5.4 6.7 25.0 ?5.0 ,:_, 4.4 11.6 29.6 70.4 85.4 ,r_, 3.2 10.5 t9.4 32.3 67.',| t0.6 E9.5 ,:t 2.6 8.2 14.6 27.6 14.2 65.E 11.4 t5.,1 91.8 't,.0 2.1 6.7 l l.t 't7.7 25,0 35.6 64.4 75.0 t2.3 tt.2 93.3 919 'l'$crnt ol \ht.k.lMnttlar liom Ihst.k \|dll fi, lrllvet\a lilnl l.t-tL Travc* Poht /. ol I)lfine uuurca froo I)hmd.r rrll outtld. of I 3 1 5 5 1 t 9 l0 il t2 16.7 50.0 83.3 16.12 4t.25 80.38 20.12 52.25 t4.3t Stack Disgrm A= 15ft- B=20ft. Dcpth ofDuct = 96.5 in. Cro66 ScctioBl Arce lrownst].am okturbanc! Upstlarm lxsturban.. QA Data Location -- - -- Source -- Project No. - Parameter 0r - Outlet CO" - Outlet NOx - Outlet Make Model SAI Operatinq Range Cylinder ID Znro Low Mid Hish NA Y NA r1 NA Y Cylinder Certifed Values Tnro Low Mid Hish NA Y NA NA NA Y Cylinder Expiretion Date Znro Low Mid Hiph NA Y NA NA NA Y Calibration Data Location: -- - - Source: -- Project No.: -- Date: -- Parameter Or - Outlet COr - Outlet NOx - Outlet Exnected Averase Concentretion Span Between Low High Desired Span Low Range Gas Low Hiph NA NA NA NA NA NA Mid Range Gas Low Hish High Range Gas Low Hish NA NA NA NA NA NA Actual Concentration (o/o or ppm) 7*ro Low Mid Hish 0.00 NA 0.00 NA 0.00 NA Resnonse Time (seconds) Upscale Calibration Ges (Cpj Instrument Response (7o or ppm) 7*ro Low Mid Hish NA NA NA Performance (7o of Span or Cal. Gas Conc.) 7*ro Low Mid Hish NA NA NA Performance Criteria 7*ro Low Mid Hieh 2.00 NA 2.00 2.00 2.00 NA 2.00 2.00 2.00 NA 2.00 2.00 Znro Low Mid Hish Stetus NA NA NA Bias/Drift Determinations Locetion: Source: ProJect No.: Peremeter 0r - 0utlet COr - Outlet NOx - Outlet Run I Dete Span Value Initial Instrument Zero Cal Response Initial Instrument Upscale Cal Response Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest System Upscale Response #N/A #N/A #N/A Bias (%) Pretest Zero Posttest Zero Pretest Span Posttest Soan Drift(%) Zero Mid Run 2 Drte Span Value lnstrument Zero Cal Response lnstrument Upscale Cal Response Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest Svstem Upscale Response fN/A #N/A #N/A 3ias (%) Jretest Zero losttest Zero ?retest Span )nsttesf Snan )rift (%) Zero \rid Run 3 Date Span Value lnstrument Zero Cal Response lnstrument Upscale Cal Response Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest Svstem Uoscale Response #N/A #N/A #N/A Bias (%) Pretest Zero Posttest Zero Pretest Span Posttest Span Drift(%) Zero Mid Emissions Celculations Locetion -- - -- Source -- ProjectNo. - Run Number Runl Run2 Run3 Average Date Start Time Stop Time Source Data Source [nad, o/o Fuel Factor (O2 dry), dscf/I,IMBtu EL Fd Calculated Data - Outlet Oz Concentration. % dry co, COz Concentration, % dry Cco, NOx Concentration, ppmvd NOx Emission Factor, lbA,IMBtu (O2d) CNo' EFNoroza Run 1 - RM Data' Lmdm: --- Somc: -- ProJct No.: - Drtc: - Or-Ouflct COr-Oqtlct NOr-Oudct %dry %dty pprvd V8lid Vdid vdid Pumctrr U[orat d Ru Avcr.l. (C-) Cd G{ Colccrtrrdon (Cyj ProtdtSFt DZBoX.apom Potttdt Syttcm Zcro Rdpoile Avcr{c7rro Rapou (Co) Pr.t6t Syltcm Cd Rgponlc P6ttdt S}|tcD Cd RcrDo[r. AvErgc Cd Rcryolrc (Cf,) Locetion: -- - -- Project No.: -- NO2 Converter Check - Outlet Andyzer Make Analyzer Model Serial Number Cylinder ID Number Cylinder Exp. Date Cvlinder Concentratlon. Dnm Pre.Test Date Time Pre-Test Efficiencv. 7o Post-Test Date Time Post-Test Concentration, ppm Post-Test Elliciencv. 7o *Required Elficiency is > 90 %. Location: -- - -- Source: -- Project No.: -- Traverse Point Time NOx (nnm) o2 (o/"\ Cor (o/"\ A-l 1 3 4 5 6 0:00 0:00 0:00 0:00 0:00 B-l 2 3 4 5 6 0:00 0:00 0:00 0:00 0:00 0:00 Average Criteria Met Sinsle Point Sinsle Point Sinele Point Location: Project No.: FUEL FACTOR CALCULATION BASED ON FUEL AI\ALYSIS COMPONENI MW MOLE%MOLES C MOLESH MOLES O MOLES N MOLES S HYDROGEI\2.016 HELIUM 4.003 METHANE 16.043 WATEB 18.015 CARBON MONO)flDE 28.010 MTROGEN 28.013 ETI{YLENE 28.054 ETI{ANE 30.070 OXYGE\3 1.999 I{YDROGEN SULFIDE 34.0',16 ARCON 39.948 PROPYLENE 42.081 CARBON DIO)ODE ,t4.010 PROPANE 44.097 BUTYLENES 56 08 ISO.BTTTANE 58 24 N.BUTANE 58.24 PENTENES 70.35 ISO-PENTANE 72.5l N.PENTANE 72.5l BENZENE 78.t4 HEXANE 86 78 TOLUENE 92 4l TIEPTANE 100.205 ET}TYLBENZENE 106.1 68 XYLENE l 06.1 68 TOTAI WEIGHT (LBS] WEIGHT% LEV BTU/SCFI:: SUM [ (MOLE%, . LHV ) + 100 ] = SUM [ (MOLE%, c HHV) + 100 ] = SUM [ (MOLE %i . DENSITY) + 100 ] = DENSrry (LB/SCF) - DENSrry,crn p.0763 LB/SCF) : HlfV + DENSITY = StlM [ (MOLE%I . MW) + 100] :106 . [(3.64.%H) + (1.53.%oC) + (0.14o%N) + (0.57'%S) - (0.46.%O)]+ cCV : 106 . t F.57.%H) + (1.53 o%C) + (0.14.%N) + (0.57.%S) - (0.46.%O) I + cCV = 106 . (0.321 o%C) + GCV =0.209.Fa+F" HIIVGTU/SCFI: DENSITY [B/SCD: SPECIFIC GRAYITY: GCVGTU/LB): MW OB/LBMOLE): F6 @SCF/I}IMBTU): F- (WSCFIIIIMBTID: F" (SCF/I}IMBT[D: Expected Foi Location: -- - -- Source: -- Project No.: -- Run No. /IllethodRun I / Method 3A Or - Outlet Concentration (CqJ, Yo dry co: (cou._co)* ( ,""*-fu" "J where,Cou.J: average anallzer value during test % dryCo.3: average of pretest & posttest zero responses,Yo dry C"oA: actual concentation of calibration gas, % dry CM : average ofpretest & posttest calibration responses, o/o dry Co, Oz Concentation,Yo dry Location: -- - - Source: -- ProJect No.: - Run No. /l}Iethod Run I / Method 3A COr - Ouflet Concentretion (C6sJ, '/o dry Cco: (Cou,-Co)* ( ffi,J = average analyzer value during test % dry Co.;: average of pretest & posttest zero responses, 7o dry Cr,&{ #N/A = actual concentation of calibration gas,o/o dry cM Cco, average ofpretest & posttest calibration responses, o/o dry: COz Concentation,o/o dry where, Location: -- - -- Source: -- Project No.: - Run No. /Itlethod Run I / Method 7E NOx - Outlet Concentretion (Cp6), ppmvd Cwo*: (Co5.-Cs)x f ,?*, \'uo! -v'-- \ CCidql'/ where,Cou.J: average analyzervalue during test ppmvd Co.;: average of pretest & posttest zero responses, ppmvd CMA #N/A : actual concentation of calibration gas, ppmvd Cr.;: average of pretest & posttest calibration responses, ppmvd CNo* NOx Concentation, ppmvd NOr - Outlet Emlsslon Factor (EFr.roroJ,lb/IIMBtu EFxo*oa: ERNo,xKxFd. (7.dffi;) where,Cn*::NOx - Outlet Concentration, ppmvd K 1.19482F.07 : constrant, lb/dscf . ppmvd Fd .T : fuel factor, dscflMMBtu Cr...-: oxygen concentration, oZ EFNo*oa : lb/lvIMBtu piltErre lEoF[]i.J.ga! cnouP Sourcc: - Protcst No.: -D.tc tttttrod untcnl EPA 02 MTXG Modcl SAl Snrn ;vllnder Numbcr II)bro Mtd Hlrh NA Cvllndcr Cerdflcd Vducs aa?o Mld IIloh u.u Zerc Mld IIloh adlbradon G{ Selccdotr ('/. of SDan) Mtd l{leh Cdlbrrtlor Eror Perfomrncc (7r of Sorn) LG?O Mid IIloh Llne*llt ('/e of Rrtrsc) Analyza Matc: Analpcr Modcl: Analpa SN: Environics ID: CompooaVBalucc Ga: Cylindcr Gas ID @ilution): Cylindcr Ga Conccntration (Dilution), %: Cytinda Gm ID (Mid-kvct): Cylinda Gas ConccnEatior (Mid-Irvel), %: allASTEnvironicUnishavc2-l0LMdsFlowConEollcs. Forthcscuitsthe90%@7lpmnd80%@Tlpminjcctiooswillnotbccouducted Avcrrge Anelyrcr Cotrccntrrdon(./^\ Inlccdon I Error ( +2y.\ I{ccdotr 2 Error ( *2./.r Iulccdon 3 Emor ( +2./.r to ulllDnnon Gu Conccntrrdo[t./^\ hlftfion I Andyrrr Concenfrdotrl./^r lnJccuon z ADdyr.r Conccntrrflon l./.\ rnJccnotr J Altrllz.l Concentrrtlonl./-\ Avcrrgc Andlzer Concentrrtlont./.\ DlffercDcel./.\ Avcrrgc Error ( +2%r