DAQ-2024-007120

1
DAQC-CI119920001-24
Site ID 11992 (B1)

MEMORANDUM

TO: FILE – AMERICAN CARGO GROUP TRAILERS, LLC UT DIVISION – Ogden
Trailer Manufacturing

THROUGH: Chad Gilgen, Minor Source Compliance Section Manager

FROM: Daniel Riddle, Environmental Scientist

DATE: March 21, 2024

SUBJECT: FULL COMPLIANCE EVALUATION, Minor, Weber County

INSPECTION DATE: February 1, 2024

SOURCE LOCATION: 1741 West 2550 South
Ogden, UT 84401
SOURCE CONTACTS: April Cooper, Manager
385-206-3161 [e-mail]

OPERATING STATUS: Operating normally at the time of inspection.

PROCESS DESCRIPTION: Manufactures utility trailers that are used for various purposes
ranging from concession trailers to mobile office trailers. The
process begins with raw steel or aluminum that is welded and cut
to shape. The steel frames are assembled including wheel axles
then cleaned with a pressure washer and portions that will be
exposed are coated in the large paint booths (North end of long
building on South west corner) to protect them from weather.
Wells utilizes HVLP guns to minimize the amount of VOC over
spray. The old booths in north buildings have been dismantled.
The coated trailer is taken to the assembly area where pre-coated
aluminum side panels, flooring, and any specialty items are
installed. The product is then taken to a storage area awaiting
final shipment. The source has welders, 2 paint booths with two
filter banks (one on each side), natural gas unit heaters, a parts
cleaner, and one small dust collector that now vents to the
outside due to noise.

APPLICABLE REGULATIONS: Approval Order (AO) DAQE-AN119920002-23, dated May 22,
2023.

2
SOURCE EVALUATION:

Name of Permittee: Permitted Location:

American Cargo Group Trailers, LLC UT
Division - Ogden Trailer Manufacturing

1741 West 2550 South 1741 West 2550 South
Ogden, UT 84401 Ogden, UT 84401

SIC Code: 3715: (Truck Trailers)

Section I: GENERAL PROVISIONS

I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the
UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to
those rules. [R307-101]

I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]

I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions
covered by this AO must be reviewed and approved. [R307-401-1]

I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by
the owner/operator, shall be made available to the Director or Director's representative upon
request, and the records shall include the two-year period prior to the date of the request. Unless
otherwise specified in this AO or in other applicable state and federal rules, records shall be kept
for a minimum of two (2) years. [R307-401-8]

I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall,
to the extent practicable, maintain and operate any equipment approved under this AO, including
associated air pollution control equipment, in a manner consistent with good air pollution control
practice for minimizing emissions. Determination of whether acceptable operating and
maintenance procedures are being used will be based on information available to the Director
which may include, but is not limited to, monitoring results, opacity observations, review of
operating and maintenance procedures, and inspection of the source. All maintenance performed
on equipment authorized by this AO shall be recorded. [R307-401-4]

I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns.
[R307-107]

I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150]

Status: In Compliance. No limits set forth in this AO appear to have been exceeded. The
source stated that there have been no modifications to the equipment or processes. The
equipment appeared to be properly operated and maintained according to manufacturer
recommendations. Records are kept as required and were made available after the
inspection. No breakdowns have been reported since the previous inspection. An emissions
inventory was submitted for 2022, and emissions data are reported below.

Section II: SPECIAL PROVISIONS

II.A The approved installations shall consist of the following equipment:

II.A.1 Trailer Manufacturing Facility

3
II.A.2 Two (2) Paint Booths
Controls: Particulate Filters

II.A.3 Sawing Operations
Four (4) Panel Saws and One (1) Table Saw
Controls: Baghouse

II.A.4 One (1) Baghouse
Controls Sawing Operations
Flow Rate: 25,500 ACFM

II.A.5 One (1) Storage Tank
Fuel: Diesel
Capacity: 600 gallons

II.A.6 Miscellaneous Heaters*
Rating: <5 MMBtu/hr
Fuel: Natural Gas
*This equipment is listed for informational purposes only.

Status: In Compliance. No unapproved equipment was observed at the time of inspection.
II.B Requirements and Limitations

II.B.1 Site-Wide Requirements

II.B.1.a The owner/operator shall not allow visible emissions from any stationary point or fugitive
emission source to exceed 10% opacity. [R307-401-8]

II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted in accordance with
40 CFR 60, Appendix A, Method 9. [R307-201-3]

Status: In Compliance. No visible emissions were observed from any point at the time of
inspection. Method 9 was utilized to verify opacity limits. See attached VEO form.

II.B.1.b The owner/operator shall use submerged fill pipes to fill the diesel storage tank. [R307-401-8]

Status: In Compliance. The source uses submerged fill pipes to fill the diesel storage tank.

II.B.2 VOC & HAP Requirements

II.B.2.a The owner/operator shall equip each paint booth with a set of paint arrestor particulate filters to
control particulate emissions. All air exiting the booth shall pass through this control system
before being vented to the atmosphere. [R307-401-8]

Status: In Compliance. Each booth was observed to be properly equipped with particulate
filters. Filters are changed as necessary.

II.B.2.b The owner/operator shall not emit more than the following from evaporative sources (painting,
printing, coating, and/or cleaning) on site:

44.97 tons per rolling 12-month period of VOCs
9.35 tons per rolling 12-month period of Xylenes
7.78 tons per rolling 12-month period of Toluene
2.21 tons per rolling 12-month period of Methanol
19.34 tons per rolling 12-month period of all HAPs combined. [R307-401-8]

4
II.B.2.b.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using
data from the previous 12 months. The owner/operator shall use a mass-balance method to
calculate emissions from evaporative sources. The owner/operator may use the following
equations with applicable units to comply with the mass-balance method:

VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed]

HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed]

[R307-401-8]

II.B.2.b.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs
reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the
quantities calculated above to provide the monthly total emissions of VOCs and HAPs.
[R307-401-8]

II.B.2.b.3 The owner/operator shall keep records each month of the following:

A. The name (as per SDS) of the VOC- and HAP-emitting material

B. The maximum percent by weight of VOCs and each HAP in each material used

C. The density of each material used

D. The volume of each VOC- and HAP-emitting material used

E. The amount of VOCs and the amount of each HAP emitted from each material

F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from
each material

G. The total amount of VOCs, the total amount of each HAP, and the total amount of all
HAPs combined emitted from all materials (in tons)

[R307-401-8]

Status: In Compliance. For the rolling 12-month period from January 2023 - December
2023, emissions are as follows:

13.33 tons of VOCs
0 tons of Xylenes
0 tons of toluene
0 tons of methanol
4.63 tons of HAPs combined

See the attached excel tables below for more information.

II.B.2.c The owner/operator shall comply with all applicable requirements and VOC content limits
established in R307-342 "Adhesives and Sealants.". [R307-342]

Status: In Compliance. All of the adhesives and sealants' VOC contents appear to be within
the limits from Table 1 of this area source rule. See the attached SDS and TDS for more
information.

5
II.B.2.d The owner/operator shall comply with all applicable requirements and VOC content limits
established in R307-350 "Miscellaneous Metal Parts and Products Coatings.". [R307-350]

Status: In Compliance. All of the coatings' VOC contents appear to comply with the limits
from Table 1 of this area source rule. See attached SDS.

The source uses a Zero VOC Acrylic Lacquer Thinner for solvent cleaning which has a
nonexempt VOC partial pressure of 0.0 mm of Hg at 20 degrees Celsius. See the attached
SDS.

II.B.3 Sawing Operation Requirements

II.B.3.a The owner/operator shall install a baghouse to control particulate emissions from the sawing
operations. All exhaust air from the sawing operations shall be routed through the baghouse
before being vented to the atmosphere. [R307-401-8]

Status: In Compliance. The baghouse has been installed as required, and exhaust air from
the sawing operations are routed here before venting to the atmosphere.

II.B.3.b The owner/operator shall install a manometer or magnehelic pressure gauge to measure the
differential pressure across the baghouse. The static pressure differential across the baghouse
shall be between one (1) and six (6) inches of water column. [R307-401-8]

II.B.3.b.1 The pressure gauge shall be located such that an inspector/operator can safely read the indicator
at any time. The pressure gauge shall measure the pressure drop in 1-inch water column
increments or less. The pressure gauge shall be calibrated according to the manufacturer's
instructions at least once every 12 months. [R307-401-8]

Status: In Compliance. The magnehelic gauge read at 5 inches of water column at the time
of inspection. Compliance assistance was provided to replace or calibrate the magnehelic
pressure gauge annually. See the attached order from Grainger on February 7, 2024.

II.B.3.b.2 The owner/operator shall record the reading of the pressure gauge at least once per operating day.
[R307-401-8]

Status: In Compliance. See the attached log showing 2-months of checks. Other months
were observed at the time of inspection.

Section III: APPLICABLE FEDERAL REQUIREMENTS

In addition to the requirements of this AO, all applicable provisions of the following federal programs
have been found to apply to this installation. This AO in no way releases the owner or operator from any
liability for compliance with all other applicable federal, state, and local regulations including UAC
R307.

AREA SOURCE RULES EVALUATION:

The following Area Source Rules were evaluated during this inspection:

Nonattainment and Maintenance Areas for PM10: Emission Standards [R307-305]

Status: In Compliance. No visible emissions were observed from any point at the time of inspection.
See attached VEO form for additional information.

6
Nonattainment and Maintenance Areas for PM10:Emissions and Fugitive Emissions and Fugitive Dust
[R307-309]

Status: In Compliance. No fugitive dust was observed from the gravel-covered dirt lot used for
storage.

Ozone Nonattainment and Maintenance Areas: General Requirements [R307-325]

Status: In Compliance. No VOC containing materials were observed spilled, discarded, stored in
open containers, or handled in any other way that would result in greater evaporation.

Adhesives and Sealants [R307-342]

Status: In Compliance. See Condition II.B.2.c above for more information.

Miscellaneous Metal Parts and Products Coatings [R307-350]

Status: In Compliance. See Condition II.B.2.d above for more information.

EMISSION INVENTORY:

Listed before are the Actual Emissions Inventory provided from American Cargo Group Trailers, LLC
UT Division Ogden Trailer Manufacturing for the 2022 emissions year. A comparison of the estimated
total potential emissions (PTE) on AO: DAQE-AN119920002-23, date May 22, 2023, is provided.
PTE are supplied for supplemental purposes only.

Criteria Pollutant PTE tons/yr Actuals tons/yr
CO2 Equivalent 3274.00 N/A
Carbon Monoxide 0.65 0.57259
Nitrogen Oxides 3.09 0.91975
Particulate Matter - PM10 1.01 0.7824
Particulate Matter - PM2.5 1.01 0.7824
Sulfur Dioxide 0.02 0.00552
Volatile Organic Compounds 44.97 18.7507

Hazardous Air Pollutant PTE lbs/yr Actuals lbs/yr
Methanol (CAS #67561) 4420 N/A
Toluene (CAS #108883) 15560 0.1
Xylenes (Isomers And Mixture) (CAS #1330207) 18700 0.08

PREVIOUS ENFORCEMENT
ACTIONS: No enforcement actions within the past five years.

COMPLIANCE STATUS &
RECOMMENDATIONS: In regards to Approval Order (AO) DAQE-AN119920002-23,
dated May 22, 2023: In compliance at the time of inspection.
Steel-toed boots are required PPE for this inspection.
7
HPV STATUS: Not Applicable.

RECOMMENDATION FOR
NEXT INSPECTION: Inspect at typical frequency.

NSR RECOMMENDATIONS: None at this time.

ATTACHMENTS: VEO form, email correspondence, emissions data order for new
magnehelic, installation of new magnehelic, SDS, and TDS
3/6/24, 9:56 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r3859615779120677405&simpl=msg-a:r80002256247841…1/3
Daniel Riddle <[e-mail]>
11992 - follow up to air quality inspection
4 messages
Daniel Riddle <[e-mail]>Thu, Feb 1, 2024 at 2:12 PM
To: [e-mail], [e-mail]
April and John,
Thank you for taking the time to meet today for your air quality inspection. As discussed, here are the records I still require to complete my inspection
report:
From AO DAQE-AN119920002-23:
Condition II.B.2.b: VOC and HAP emissions (January - December 2023)
Condition II.B.3.b.1 - record of calibration of magnehelic gauge
Condition II.B.3.b.2 - daily check of magnehelic gauge
Additionally, I will need SDS or EDS/TDS (whatever shows the VOC/gal) for all adhesive and sealants and metal product coatings in use at the facility
at this time to ensure their VOC emissions ratings are in compliance with the tables in R307-342 and R307-350. I'm attaching these rules for your
reference.
Please provide these records by February 8, 2024. Let me know if you have any questions.
Best,
Daniel
--
Daniel Riddle (he/him)
Environmental Scientist | Minor Source Compliance
M: [phone]
airquality.utah.gov
2 attachments
R307-350.pdf
99K
R307-342.pdf
103K
Daniel Riddle <[e-mail]>Mon, Feb 5, 2024 at 10:11 AM
To: [e-mail], [e-mail]
One additional follow up - you are required to submit a yearly emission report to our SLEIS program, and that is something you should have an
account for. I've attached your SLEIS summaries for 2022 and 2021 for your reference - perhaps you've seen them before? Your 2023 report is due
by April 15, 2024.
[Quoted text hidden]
2 attachments
2021_11992_Emissions_Report.pdf
143K
2022_11992_Emissions_Report.pdf
140K
April Cooper <[e-mail]>Mon, Feb 5, 2024 at 10:37 AM
To: Daniel Riddle <[e-mail]>
Cc: John Sprenkle <[e-mail]>, Brent Shuman <[e-mail]>
3/6/24, 9:56 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r3859615779120677405&simpl=msg-a:r80002256247841…2/3
You don't often get email from [e-mail]. Learn why this is important
Daniel,
No, this is not something John or I have seen before but we will start looking into it.

Thank you,

April Cooper
Office Manager/HR

American Cargo Group Trailers
1741 W 2550 S / Ogden Ut 84401
Office: 801-621-3637 ext:7507
Direct: 385-206-3161

Upcoming Out of Office : 

From: Daniel Riddle <[e-mail]>
Sent: Monday, February 5, 2024 10:12 AM
To: John Sprenkle <[e-mail]>; April Cooper <[e-mail]>
Subject: Re: 11992 - follow up to air quality inspection

One additional follow up - you are required to submit a yearly emission report to our SLEIS program, and that is something you should have an
account for. I've attached your SLEIS summaries for 2022 and 2021 for your reference - perhaps you've seen them before? Your 2023 report is due
by April 15, 2024.

On Thu, Feb 1, 2024 at 2:12 PM Daniel Riddle <[e-mail]> wrote:
April and John,

Thank you for taking the time to meet today for your air quality inspection. As discussed, here are the records I still require to complete my
inspection report:

3/6/24, 9:56 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r3859615779120677405&simpl=msg-a:r80002256247841…3/3
From AO DAQE-AN119920002-23:
Condition II.B.2.b: VOC and HAP emissions (January - December 2023)
Condition II.B.3.b.1 - record of calibration of magnehelic gauge
Condition II.B.3.b.2 - daily check of magnehelic gauge

Additionally, I will need SDS or EDS/TDS (whatever shows the VOC/gal) for all adhesive and sealants and metal product coatings in use at the
facility at this time to ensure their VOC emissions ratings are in compliance with the tables in R307-342 and R307-350. I'm attaching these rules
for your reference.

Please provide these records by February 8, 2024. Let me know if you have any questions.

Best,
Daniel

--
Daniel Riddle (he/him)
Environmental Scientist | Minor Source Compliance
M: [phone]
airquality.utah.gov

2 attachments
2021_11992_Emissions_Report.pdf
143K
2022_11992_Emissions_Report.pdf
140K
Daniel Riddle <[e-mail]>Mon, Feb 5, 2024 at 10:41 AM
To: April Cooper <[e-mail]>
Cc: John Sprenkle <[e-mail]>, Brent Shuman <[e-mail]>
Reach out to [e-mail] if you have any questions.
[Quoted text hidden]
3/6/24, 9:57 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-f:1790436033756100049&simpl=msg-f:17904360337561000…1/5
Daniel Riddle <[e-mail]>
11992 - follow up to air quality inspection
7 messages
April Cooper <[e-mail]>Fri, Feb 9, 2024 at 8:34 AM
To: Daniel Riddle <[e-mail]>
Cc: John Sprenkle <[e-mail]>, Abby Francis <[e-mail]>, Cheryl Horn
<[e-mail]>
Daniel,
I do apologize, I had to leave the office early yesterday and these two attachments did not get added to the email that
was sent over to you.

Thank you,

April Cooper
Office Manager/HR

American Cargo Group Trailers
1741 W 2550 S / Ogden Ut 84401
Office: 801-621-3637 ext:7507
Direct: 385-206-3161

Upcoming Out of Office : 

3/6/24, 9:57 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-f:1790436033756100049&simpl=msg-f:17904360337561000…2/5
From: April Cooper
Sent: Thursday, February 8, 2024 10:25 AM
To: Jamie Eddy <[e-mail]>
Subject: 11992 - follow up to air quality inspecon

Daniel,

Attached is the information you have requested from our inspection.

Thank you,

April Cooper
Office Manager/HR

American Cargo Group Trailers
1741 W 2550 S / Ogden Ut 84401
Office: 801-621-3637 ext:7507
Direct: 385-206-3161

Upcoming Out of Office : 

2 attachments
OneDrive_2024-02-06.zip
4526K
3/6/24, 9:57 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-f:1790436033756100049&simpl=msg-f:17904360337561000…3/5
JANUARY 2024-- Daily baghouse report.pdf
54K
Daniel Riddle <[e-mail]>Mon, Feb 12, 2024 at 9:20 AM
To: April Cooper <[e-mail]>
Thanks for adding those. I'll let you know if I have any questions.
[Quoted text hidden]
Daniel Riddle <[e-mail]>Mon, Feb 26, 2024 at 9:45 AM
To: April Cooper <[e-mail]>
April
One final question regarding R307-350-7(2) which states: "Solvent cleaning operations shall be performed using cleaning materials
having a VOC composite vapor pressure
no greater than 1 mm Hg at 20 degrees Celsius, unless an add-on control device is used as specified in R307-350-8"
Do you do any solvent cleaning on your metal parts? If so, could you send me verification from an SDS or TDS of your product you are using
that it meets this VOC composite vapor pressure requirement? If not, just let me know here.
Thank you,
Daniel
[Quoted text hidden]
April Cooper <[e-mail]>Tue, Feb 27, 2024 at 3:04 PM
To: Daniel Riddle <[e-mail]>
Cc: John Sprenkle <[e-mail]>
Daniel,
I am working with Aeterra to obtain this information. As soon as I her back from them, I will provide you with the
requested information.

Thank you,

April Cooper
Office Manager/HR

American Cargo Group Trailers
1741 W 2550 S / Ogden Ut 84401
Office: 801-621-3637 ext:7507
Direct: 385-206-3161

3/6/24, 9:57 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-f:1790436033756100049&simpl=msg-f:17904360337561000…4/5
You don't often get email from [e-mail]. Learn why this is important

Upcoming Out of Office : 

From: Daniel Riddle <[e-mail]>
Sent: Monday, February 26, 2024 9:45 AM
To: April Cooper <[e-mail]>
Subject: Re: 11992 - follow up to air quality inspection

[Quoted text hidden]
Daniel Riddle <[e-mail]>Wed, Feb 28, 2024 at 6:46 AM
To: April Cooper <[e-mail]>
Cc: John Sprenkle <[e-mail]>
Sounds good, thank you.
[Quoted text hidden]
April Cooper <[e-mail]>Tue, Mar 5, 2024 at 11:32 AM
To: Daniel Riddle <[e-mail]>
Cc: John Sprenkle <[e-mail]>
Daniel,
Attached are the requested SDS for what is use it to clean the HVLP spray guns.
[Quoted text hidden]
2 attachments
SDS Prime LT20 Lacquer thinner.pdf
366K
THINNER DT8020.pdf
364K
Daniel Riddle <[e-mail]>Wed, Mar 6, 2024 at 9:56 AM
To: April Cooper <[e-mail]>
Cc: John Sprenkle <[e-mail]>
3/6/24, 9:57 AM State of Utah Mail - 11992 - follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-f:1790436033756100049&simpl=msg-f:17904360337561000…5/5
Thank you very much.
[Quoted text hidden]
Column1 ID Active SDS Date Vendor
Current Products
56 A Jul-14 AIS
1 A Mar-16 AIS
58 A Jun-20 PPG AIS
60 A Jun-21 Prime AIS
62 A May-15 Smalley
63 A May-15 Smalley
54 A Aug-21 3M
6 A Aug-21 3M
26 A Apr-15 JR Performance
27 A Apr-15 JR Performance
67 A May-15 JR Performance
2 A Jun-15 Z-tech
70 A Jul-22 Wesco
75 A Aug-19 Smalley
76 A Aug-19 Smalley
77 A Aug-19 Smalley
20 A Jan-18 Lavanture
Historic Products
61 A Jun-16 Prime AIS
Description Part #Gal Equiv Jan-23 Feb-23 Mar-23 Apr-23
Zero VOC Acrylic Lacquer Thinner - DT8020 1710150 1.0 53 0 0 0
Paint Z Black High Gloss - F75BL13 530130 1.0 200 265 348 336
Acetone - Q30 600260 1.0 1 2 2 2
Paint enamel black 12OZ cans - KRY S01770 530515 0.1 12 14 42 66
Manus #76 AM 55 gal Drum - Roof Sealant 601520 55.0 2 3 5 5
Manus #76 AM 12 oz tube - Roof Sealant 2800034 0.1 41 36 3 2
PB999 #27 tank 2800113 4.7 21 17 24 24
PB999 #139 tank 2800115 24.6 7 10 15 18
Cobra Liner A side 530150 1.0 130 170 146 138
Cobra Liner B Side 530150 1.0 130 170 146 138
PHOS Clean 300 530155 1.0 1 1 1 1
Z Guard 20060B-2 UT Black 530140 1.0 330 415 697 683
Parabond Signature Series 4094 604815 4.0 70 50 80 100
Dowsil Silicone White 2800030 0.1 2058 1936 2058 2422
Dowsil Silicone Black 2800032 0.1 850 2000 2450 2726
Dowsil Silicone Aluminum 2800031 0.1 800 500 2200 2400
ADHESION PRIMER, 3M,8 oz 604710 3.4
Paint enamel grey 12 oz cans - UPO 741 530535 0.12 0 0 0 0
May-23 Jun-23 Jul-23 Aug-23 Sep-23 Oct-23 Nov-23 Dec-23 Jan-24 Feb-24 Mar-24
53 0 53 0 0 53 15 5 15
350 232 310 356 320 385 358 220 330
2 1 2 3 2 3 2 1 2
70 24 24 36 48 54 48 12 36
6 4 5 6 5 6 5 3 5
3 2 46 1 1 2 1 0 1
30 18 24 20 24 24 20 14 20
21 10 18 90 90 88 70 53 70
164 110 125 140 100 150 133 100 150
164 110 125 140 100 150 133 100 150
1 1 1 1 1 1 1 1 1
726 471 625 698 627 660 600 440 630
120 60 60 60 60 40 32 28 48
2422 2058 2422 2422 2058 2101 1730 1617 2163
2200 2400 969 2180 3029 2596 1607 1658 2215
1800 800 2600 2800 1800 1607 1730 1370 1823
0 0 0
Apr-24 May-24 Jun-24 Jul-24 Aug-24 Sep-24 Oct-24 Nov-24 Dec-24
Column1 ID Active SDS Date Vendor
Current Products
56 A Jul-14 AIS
1 A Mar-16 AIS
58 A Jun-20 PPG AIS
60 A Jun-21 Prime AIS
62 A May-15 Smalley
63 A May-15 Smalley
54 A Aug-21 3M
6 A Aug-21 3M
26 A Apr-15 JR Performance
27 A Apr-15 JR Performance
67 A May-15 JR Performance
2 A Jun-15 Z-tech
70 A Jul-22 Wesco
75 A Aug-19 Smalley
76 A Aug-19 Smalley
77 A Aug-19 Smalley
20 A Jan-18 Lavanture
Historic Products
61 A Jun-16 Prime AIS
Description Part #Gal Equiv Jan-19 Feb-19 Mar-19
Zero VOC Acrylic Lacquer Thinner - DT8020 1710150 1.0 15 15 15
Paint Z Black High Gloss - F75BL13 530130 1.0 285 495 444
Acetone - Q30 600260 1.0 0 0 0
Paint enamel black 12OZ cans - KRY S01770 530515 0.1 0 0 0
Manus #76 AM 55 gal Drum - Roof Sealant 601520 55.0 355 240 280
Manus #76 AM 12 oz tube - Roof Sealant 2800034 0.1 0 0 0
PB999 #27 tank 2800113 4.7 45 44 40
PB999 #139 tank 2800115 24.6 619 982 854
Cobra Liner A side 530150 1.0 158 247 140
Cobra Liner B Side 530150 1.0 198 274 186
PHOS Clean 300 530155 1.0 1 1 1
Z Guard 20060B-2 UT Black 530140 1.0 715 635 575
Parabond Signature Series 4094 604815 4.0 0 0 0
Dowsil Silicone White 2800030 0.1 0 0 0
Dowsil Silicone Black 2800032 0.1 0 0 0
Dowsil Silicone Aluminum 2800031 0.1 0 0 0
ADHESION PRIMER, 3M,8 oz 604710 3.4 0 0 0
Paint enamel grey 12 oz cans - UPO 741 530535 0.12 0 0 0
Apr-19 May-19 Jun-19 Jul-19 Aug-19 Sep-19 Oct-19 Nov-19 Dec-19 Jan-20
6 2 0 8 5 0 0 5 5 5
453 250 243 230 310 313 338 317 333 317
0 0 0 1 1 1 1 2 1 1
3 2 3 2 3 2 2 1 1 1
325 238 253 145 240 200 210 140 105 153
0 1 0 0 1 0 1 1 1 1
20 106 76 68 94 73 48 28 16 48
747 683 704 533 533 640 427 320 213 373
240 123 196 98 196 221 123 147 130 145
209 90 270 49 221 172 123 147 130 145
1 1 1 1 1 1 1 1 1 1
715 630 620 400 510 570 560 345 470 425
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
Feb-20 Mar-20 Apr-20 May-20 Jun-20 Jul-20 Aug-20 Sep-20 Oct-20 Nov-20
3 5 3 5 5 5 5 5 5 5
313 320 325 330 350 352 351 388 390 399
1 1 2 1 2 1 2 2 1 1
1 1 2 1 1 2 1 1 1 1
167 175 188 208 224 217 215 255 245 243
2 2 1 2 1 2 2 2 2 2
44 40 32 32 28 28 31 34 36 36
554 591 427 468 480 505 491 533 510 542
150 159 159 160 165 155 168 178 178 177
151 159 159 160 168 156 167 177 178 177
1 1 1 1 1 1 2 1 1 1
495 485 510 420 485 510 500 525 570 560
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
Dec-20 Jan-21 Feb-21 Mar-21 Apr-21 May-21 Jun-21 Jul-21 Aug-21 Sep-21
3 5 10 12 8 10 8 6 9 10
302 390 395 405 418 428 415 380 395 355
0 2 1 1 1 2 1 0 2 0
1 1 1 2 2 2 2 2 3 2
200 246 263 283 300 300 325 275 288 323
1 2 2 3 4 4 4 4 3 4
28 36 42 48 65 65 48 65 73 129
427 533 640 640 854 854 854 0 533 427
149 180 218 250 260 258 260 159 170 167
149 180 218 250 258 255 260 159 170 167
1 1 1 1 2 1 1 0 1 0
500 580 865 990 1045 1100 1030 950 990 1040
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
Oct-21 Nov-21 Dec-21 Jan-22 Feb-22 Mar-22 Apr-22 May-22 Jun-22 Jul-22
11 25 10 5 10 10 10 15 18 12
390 360 245 375 380 350 340 345 335 340
3 2 3 2 2 1 2 2 1 2
2 2 2 2 2 2 2 2 2 1
298 288 175 275 300 260 258 261 270 250
4 4 3 4 4 4 4 5 4 4
178 145 145 162 210 193 208 189 190 178
277 213 0 319 214 319 278 214 319 427
205 188 173 202 226 216 215 225 200 210
205 188 173 202 226 216 215 225 200 210
1 0 1 1 0 1 1 0 1 1
1070 990 860 990 1000 970 940 870 870 760
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
Aug-22 Sep-22 Oct-22 Nov-22 Dec-22 Jan-23 Feb-23 Mar-23 Apr-23 May-23 Jun-23
10 10 10 10 5 53 0 0 0 53 0
330 275 325 250 185 200 265 348 336 350 232
1 2 1 1 0 1 2 2 2 2 1
2 1 1 1 1 1 2 5 8 9 3
220 190 191 117 102 110 150 289 286 326 212
4 4 3 2 2 2 2 0 0 0 0
178 129 129 89 97 97 81 114 114 142 85
427 427 319 214 145 174 255 368 442 516 246
200 200 190 145 120 130 170 146 138 164 110
200 200 190 145 120 130 170 146 138 164 110
0 0 0 0 0 1 1 1 1 1 1
705 610 580 405 300 330 415 697 683 726 471
0 0 0 0 0 280 200 320 400 480 240
0 0 0 0 0 165 155 165 194 194 165
0 0 0 0 0 68 160 196 218 176 192
0 0 0 0 0 64 40 176 192 144 64
0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0
Jul-23 Aug-23 Sep-23 Oct-23 Nov-23 Dec-23 Jan-24 Feb-24 Mar-24 Apr-24 May-24
53 0 0 53 15 5 15 0 0 0 0
310 356 320 385 358 220 330 0 0 0 0
2 3 2 3 2 1 2 0 0 0 0
3 4 6 7 6 1 4 0 0 0 0
276 316 274 303 275 165 275 0 0 0 0
2 0 0 0 0 0 0 0 0 0 0
114 95 114 113 97 65 97 0 0 0 0
442 2211 2211 2149 1719 1289 1719 0 0 0 0
125 140 100 150 133 100 150 0 0 0 0
125 140 100 150 133 100 150 0 0 0 0
1 1 1 1 1 1 1 0 0 0 0
625 698 627 660 600 440 630 0 0 0 0
240 240 240 160 128 112 192 0 0 0 0
194 194 165 168 138 129 173 0 0 0 0
78 174 242 208 129 133 177 0 0 0 0
208 224 144 129 138 110 146 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0
Jun-24 Jul-24 Aug-24 Sep-24 Oct-24 Nov-24 Dec-24
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
Column3 VOC Content
Material lb/gal
Zero VOC Acrylic Lacquer Thinner - DT8020 0.00
Paint Z Black High Gloss - F75BL13 3.47
Acetone - Q30 0.00
Paint enamel black 12OZ cans - KRY S01770 3.02
Manus #76 AM 55 gal Drum - Roof Sealant 0.08
Manus #76 AM 12 oz tube - Roof Sealant 0.08
PB999 #27 tank [1]4.54
PB999 #139 tank [1]4.54
Cobra Liner A side 0.00
Cobra Liner B Side 0.00
PHOS Clean 300 0.00
Z Guard 20060B-2 UT Black 1.50
Parabond Signature Series 4094 0.00
Dowsil Silicone White 0.69
Dowsil Silicone Black 0.69
Dowsil Silicone Aluminum 0.69
ADHESION PRIMER, 3M,8 oz [2]6.52
VOC Emissions, ton/month
Running 12 month total
[1] The Facility has hired Aeterra, LLC as their new environmental consultant. Aeterra performed an env
[2] The Facility purchases this item in exclusively 8 oz containers to comply with the exemption found in
Jan-23 Feb-23 Mar-23 Apr-23 May-23 Jun-23 Jul-23 Aug-23 Sep-23
56 57 58 59 60 61 62 63 64
lb
VOCs/mont
h
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
0 0 0 0 0 0 0 0 0
694 920 1,208 1,166 1,215 805 1,076 1,235 1,110
0 0 0 0 0 0 0 0 0
4 5 15 24 26 9 9 13 18
9 12 23 23 26 17 22 25 22
0 0 0 0 0 0 0 0 0
441 368 516 516 645 387 516 430 516
792 1,160 1,673 2,008 2,342 1,115 2,008 10,038 10,038
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
495 623 1,046 1,025 1,089 707 938 1,047 941
0 0 0 0 0 0 0 0 0
114 107 114 134 134 114 134 134 114
47 111 136 151 122 133 54 121 168
44 28 122 133 100 44 144 155 100
0.67 0.85 1.24 1.22 1.30 0.84 1.12 1.42 1.31
14.84 13.99 13.29 13.05 12.83 12.76 12.22 12.04 12.22
vironmental audit on September 27, 2023. This material was identified as being non-compliant with UAC R307-342-5 Table 1
n R307-342-3(1)(d).
Oct-23 Nov-23 Dec-23 Jan-24 Feb-24 Mar-24 Apr-24 May-24 Jun-24
65 66 67 68 69 70 71 72 73
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mon
th
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mon
th
0 0 0 0 0 0 0 0 0
1,336 1,241 763 1,145 0 0 0 0 0
0 0 0 0 0 0 0 0 0
20 18 4 13 0 0 0 0 0
24 22 13 22 0 0 0 0 0
0 0 0 0 0 0 0 0 0
514 440 294 440 0 0 0 0 0
9,759 7,807 5,855 7,807 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
990 900 660 945 0 0 0 0 0
0 0 0 0 0 0 0 0 0
117 96 90 120 0 0 0 0 0
144 89 92 123 0 0 0 0 0
89 96 76 101 0 0 0 0 0
0 0 0 0 0 0
1.44 1.30 0.87 1.27 0.00 0.00 0.00 0.00 0.00
12.49 12.83 13.33 13.59 14.19 13.34 12.10 10.88 9.58
. ACG is actively looking for a replacement material.
Jul-24 Aug-24 Sep-24 Oct-24 Nov-24 Dec-24
74 75 76 77 78 79
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mo
nth
lb
VOCs/mon
th
lb
VOCs/mon
th
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0.00 0.00 0.00 0.00 0.00 0.00
8.74 7.62 6.20 4.89 3.45 2.15
Column1 ID #Vendor Description CAS
Current Products
56 AIS Zero VOC Acrylic Lacquer Thinner - DT8020
1 AIS Paint Z Black High Gloss - F75BL13
58 PPG AIS Acetone - Q30
60 Prime AIS Paint enamel black 12OZ cans - KRY S01770
61 Prime AIS Paint enamel grey 12 oz cans - UPO 741 78-93-3
61 100-41-4
61 108-88-3
61 1330-20-7
61 108-95-2
62 Smalley Manus #76 AM 55 gal Drum - Roof Sealant
63 Smalley Manus #76 AM 12 oz tube - Roof Sealant
54 3M PB999 #27 tank
6 3M PB999 #139 tank
26 JR Performance Cobra Liner A side 101-68-8
27 JR Performance Cobra Liner B Side
67 JR Performance PHOS Clean 300
2 Z-tech Z Guard 20060B-2 UT Black
70 Wesco Parabond Signature Series 4094
75 Smalley Dowsil Silicone White
76 Smalley Dowsil Silicone Black
77 Smalley Dowsil Silicone Aluminum
20 Lavanture ADHESION PRIMER, 3M,8 oz
20
20
12
12 m
Mont
12-Mont
HAPs Density l HAP FractJan-23 Feb-23 Mar-23 Apr-23 May-23 Jun-23 Jul-23
56 57 58 59 60 61 62
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
MEK 6.26 0.23 0 0 0 0 0 0 0
Ethylbenzene 6.26 0.05 0 0 0 0 0 0 0
Toluene 6.26 0.05 0 0 0 0 0 0 0
Xylenes 6.26 0.05 0 0 0 0 0 0 0
Phenol 6.26 0.05 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
MDI 9.61 0.6 750 980 842 796 946 634 721
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
None 0 0 0 0 0 0 0
Toluene 6.84 0.05
Xylenes 6.84 0.35
Ethylbenzene 6.84 0.11
Total HAP lb/month 750 980 842 796 946 634 721
Total HAP ton/month 0.37 0.49 0.42 0.40 0.47 0.32 0.36
2 month Rolling total HAPs (lbs)13,137 12,812 12,408 11,961 11,607 11,088 10,598
month Rolling total HAPs (tons)6.57 6.41 6.20 5.98 5.80 5.54 5.30
hly HAP Emissions (ton/month)
Xylenes 0 0 0 0 0 0 0
Toluene 0 0 0 0 0 0 0
Ethylbenzene 0 0 0 0 0 0 0
MIBK 0 0 0 0 0 0 0
Hexane 0 0 0 0 0 0 0
HMDI 0 0 0 0 0 0 0
Naphthalene 0 0 0 0 0 0 0
Butanone 0 0 0 0 0 0 0
Methanol 0 0 0 0 0 0 0
MDI 0.375 0.490 0.421 0.398 0.473 0.317 0.360
Cumene 0 0 0 0 0 0 0
MEK 0 0 0 0 0 0 0
th Rolling HAP Emissions (tons)
Xylenes 0.0004695 0.000313 0.000313 0.0001565 0 0 0
Toluene 0.0004695 0.000313 0.000313 0.0001565 0 0 0
Ethylbenzene 0.0004695 0.000313 0.000313 0.0001565 0 0 0
MIBK 0 0 0 0 0 0 0
Hexane 0 0 0 0 0 0 0
HMDI 0 0 0 0 0 0 0
Naphthalene 0 0 0 0 0 0 0
Butanone 0 0 0 0 0 0 0
Methanol 0 0 0 0 0 0 0
MDI 6.56 6.40 6.20 5.98 5.80 5.54 5.30
Cumene 0 0 0 0 0 0 0
MEK 0.0021597 0.0014398 0.0014398 0.0007199 0 0 0
Aug-23 Sep-23 Oct-23 Nov-23 Dec-23 Jan-24 Feb-24 Mar-24 Apr-24 May-24
63 64 65 66 67 68 69 70 71 72
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
807 577 865 764 577 865 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
807 577 865 764 577 865 0 0 0 0
0.40 0.29 0.43 0.38 0.29 0.43 0.00 0.00 0.00 0.00
10,252 9,675 9,445 9,373 9,257 9,373 8,392 7,551 6,755 5,809
5.13 4.84 4.72 4.69 4.63 4.69 4.20 3.78 3.38 2.90
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0.40362 0.2883 0.43245 0.3819975 0.2883 0.43245 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
5.13 4.84 4.72 4.69 4.63 4.69 4.20 3.78 3.38 2.90
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
Jun-24 Jul-24 Aug-24 Sep-24 Oct-24 Nov-24 Dec-24
73 74 75 76 77 78 79
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0.00 0.00 0.00 0.00 0.00 0.00 0.00
5,175 4,454 3,647 3,070 2,205 1,442 865
2.59 2.23 1.82 1.54 1.10 0.72 0.43
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
2.59 2.23 1.82 1.54 1.10 0.72 0.43
0 0 0 0 0 0 0
0 0 0 0 0 0 0
3M™ Primer 94 06/05/23

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Page 1 of 22
Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:06-8243-5 Version Number:32.14
Issue Date:06/05/23 Supercedes Date:08/23/22
SECTION 1: Identification
1.1. Product identifier
3M™ Primer 94

Product Identification Numbers
70-0075-4882-2, 70-0160-4782-4, 70-0160-5476-2, 70-0160-5477-0, 70-0160-5478-8, 75-0400-2417-8
7000001579, 7000001583, 7000001584, 7100003278, 7100155663, 7100261001
1.2. Recommended use and restrictions on use
Recommended use
Adhesion Promoter, Primer
1.3. Supplier’s details
MANUFACTURER:3M
DIVISION:Industrial Adhesives and Tapes Division
ADDRESS:3M Center, St. Paul, MN 55144-1000, USA
Telephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or [phone] (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Flammable Liquid: Category 2.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1A.
Aspiration Hazard: Category 1.
Reproductive Toxicity: Category 1B.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
Signal word
Danger
3M™ Primer 94 06/05/23

__________________________________________________________________________________________

Page 2 of 22
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Highly flammable liquid and vapor.
Causes serious eye irritation.
May cause an allergic skin reaction.
May be fatal if swallowed and enters airways.
May cause drowsiness or dizziness.
May damage fertility or the unborn child.
Suspected of causing cancer.
Causes damage to organs:
sensory organs |
Causes damage to organs through prolonged or repeated exposure:
nervous system |
May cause damage to organs through prolonged or repeated exposure:
sensory organs |
Precautionary Statements
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
3M™ Primer 94 06/05/23

__________________________________________________________________________________________

Page 3 of 22
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Do NOT induce vomiting.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Keep cool.
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2% of the mixture consists of ingredients of unknown acute oral toxicity.
2% of the mixture consists of ingredients of unknown acute dermal toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No.% by Wt
Cyclohexane 110-82-7 30 - 60 Trade Secret *
Xylene 1330-20-7 15 - 35 Trade Secret *
Ethylbenzene 100-41-4 1 - 15 Trade Secret *
Ethyl Alcohol 64-17-5 5 - 10 Trade Secret *
Ethyl Acetate 141-78-6 1 - 5 Trade Secret *
Acrylate Polymer (NJTS Reg. No. 04499600-5984P)Trade Secret* 1 - 5 Trade Secret *
Chlorinated Polyolefin 68609-36-9 < 2 Trade Secret *
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane 3388-04-3 < 1 Trade Secret *
Isopropyl Alcohol 67-63-0 < 1 Trade Secret *
Toluene 108-88-3 < 1 Trade Secret *
Epoxy Resin 25068-38-6 < 0.5 Trade Secret *
Methyl Alcohol 67-56-1 < 0.5 Trade Secret *
MIBK 108-10-1 < 0.5 Trade Secret *
Cumene 98-82-8 < 0.2 Trade Secret *
Chlorobenzene 108-90-7 < 0.11 Trade Secret *
Maleic Anhydride 108-31-6 < 0.1 Trade Secret *
Naphthalene 91-20-3 < 0.1 Trade Secret *
NJTS or NJTSRN: New Jersey Trade Secret Registry Number.
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
3M™ Primer 94 06/05/23

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Page 4 of 22
Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing.
Immediately get medical attention.
If Swallowed:
Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Allergic skin reaction (redness, swelling, blistering, and itching). Aspiration pneumonitis (coughing, gasping, choking, burning of the
mouth, and difficulty breathing). Central nervous system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred
speech, giddiness, and unconsciousness). Target organ effects. See Section 11 for additional details. Target organ effects following
prolonged or repeated exposure. See Section 11 for additional details.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Formaldehyde During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion

5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.
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Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and
authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal
the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes,
on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash
contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static
or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the
risk of ignition, determine applicable electrical classifications for the process using this product and select specific local
exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if
there is potential for static electricity accumulation during transfer.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Protect from sunlight. Store away from
heat. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No.Agency Limit type Additional Comments
Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal
carcin., Ototoxicant
Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm)
MIBK 108-10-1 ACGIH TWA:20 ppm;STEL:75 ppm A3: Confirmed animal
carcin.
MIBK 108-10-1 OSHA TWA:410 mg/m3(100 ppm)
Maleic Anhydride 108-31-6 ACGIH TWA(inhalable fraction and
vapor):0.01 mg/m3
A4: Not class. as human
carcin,
Dermal/Respiratory
Sensitizer
Maleic Anhydride 108-31-6 OSHA TWA:1 mg/m3(0.25 ppm)
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human
carcin, Ototoxicant
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
Chlorobenzene 108-90-7 ACGIH TWA:10 ppm A3: Confirmed animal
carcin.
Chlorobenzene 108-90-7 OSHA TWA:350 mg/m3(75 ppm)
Cyclohexane 110-82-7 ACGIH TWA:100 ppm
Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm)
Xylene 1330-20-7 ACGIH TWA:20 ppm;STEL:150 ppm A4: Not class. as human
carcin
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Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm)
Ethyl Acetate 141-78-6 ACGIH TWA:400 ppm
Ethyl Acetate 141-78-6 OSHA TWA:1400 mg/m3(400 ppm)
Ethyl Alcohol 64-17-5 ACGIH STEL:1000 ppm A3: Confirmed animal
carcin.
Ethyl Alcohol 64-17-5 OSHA TWA:1900 mg/m3(1000 ppm)
Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm Danger of cutaneous
absorption
Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm)
Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human
carcin
Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm)
Naphthalene 91-20-3 ACGIH TWA:10 ppm A3: Confirmed animal
carcin., Danger of
cutaneous absorption
Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm)
Cumene 98-82-8 ACGIH TWA:5 ppm A3: Confirmed animal
carcin.
Cumene 98-82-8 OSHA TWA:245 mg/m3(50 ppm)SKIN
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment. Provide appropriate local exhaust ventilation on open containers.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
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An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
Half facepiece or full facepiece supplied-air respirator
Organic vapor respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
Amber
Specific Physical Form: Liquid
Odor Solvent
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point 170 ºF
Flash Point 1 ºF [Test Method:Closed Cup]
Evaporation rate No Data Available
Flammability (solid, gas)Not Applicable
Flammable Limits(LEL)1 %
Flammable Limits(UEL)11 %
Vapor Pressure 68 mmHg [@ 68 ºF]
Vapor Density No Data Available
Density 0.82 g/ml
Specific Gravity 0.82 [@ 77 ºF] [Ref Std:WATER=1]
Solubility in Water Negligible
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 1 - 35 centipoise [@ 73.4 ºF ]
Hazardous Air Pollutants 35.2 - 45.3 % weight [Test Method:Calculated]
Hazardous Air Pollutants <=15.11 lb HAPS/lb solids [Test Method:Calculated]
Molecular weight No Data Available
Volatile Organic Compounds 781 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:low solids less exempts]
Percent volatile 95.3 - 97 % weight [Test Method:Estimated]
VOC Less H2O & Exempt Solvents 781 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:low solids less exempts]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.

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10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
Sparks and/or flames

10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
May be harmful in contact with skin.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin
Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
May cause additional health effects (see below).
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth,
difficulty breathing, bluish colored skin (cyanosis), and may be fatal.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
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Additional Health Effects:
Single exposure may cause target organ effects:
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause target organ effects:
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient CAS No.Class Description Regulation
Cumene 98-82-8 Grp. 2B: Possible human carc.International Agency for Research on Cancer
Cumene 98-82-8 Anticipated human carcinogen National Toxicology Program Carcinogens
Ethylbenzene 100-41-4 Grp. 2B: Possible human carc.International Agency for Research on Cancer
Methyl isobutyl ketone 108-10-1 Grp. 2B: Possible human carc.International Agency for Research on Cancer
Naphthalene 91-20-3 Grp. 2B: Possible human carc.International Agency for Research on Cancer
Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens
Additional Information:
This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the
International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human
consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the
foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >2,000 - =5,000
mg/kg
Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE >20 - =50 mg/l
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Cyclohexane Dermal Rat LD50 > 2,000 mg/kg
Cyclohexane Inhalation-
Vapor (4
hours)
Rat LC50 > 32.9 mg/l
Cyclohexane Ingestion Rat LD50 6,200 mg/kg
Xylene Dermal Rabbit LD50 > 4,200 mg/kg
Xylene Inhalation-
Vapor (4
hours)
Rat LC50 29 mg/l
Xylene Ingestion Rat LD50 3,523 mg/kg
Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg
Ethylbenzene Inhalation-Rat LC50 17.4 mg/l
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Vapor (4
hours)
Ethylbenzene Ingestion Rat LD50 4,769 mg/kg
Ethyl Alcohol Dermal Rabbit LD50 > 15,800 mg/kg
Ethyl Alcohol Inhalation-
Vapor (4
hours)
Rat LC50 124.7 mg/l
Ethyl Alcohol Ingestion Rat LD50 17,800 mg/kg
Ethyl Acetate Dermal Rabbit LD50 > 18,000 mg/kg
Ethyl Acetate Inhalation-
Vapor (4
hours)
Rat LC50 70.5 mg/l
Ethyl Acetate Ingestion Rat LD50 5,620 mg/kg
Chlorinated Polyolefin Dermal Guinea
pig
LD50 > 1,000 mg/kg
Chlorinated Polyolefin Ingestion Rat LD50 > 3,200 mg/kg
Isopropyl Alcohol Dermal Rabbit LD50 12,870 mg/kg
Isopropyl Alcohol Inhalation-
Vapor (4
hours)
Rat LC50 72.6 mg/l
Isopropyl Alcohol Ingestion Rat LD50 4,710 mg/kg
Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg
Methyl Alcohol Inhalation-
Vapor
LC50 estimated to be 10 - 20 mg/l
Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane Dermal Rabbit LD50 6,700 mg/kg
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane Inhalation-
Vapor (4
hours)
Rat LC50 > 7 mg/l
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane Ingestion Rat LD50 13,100 mg/kg
Epoxy Resin Dermal Rat LD50 > 1,600 mg/kg
Epoxy Resin Ingestion Rat LD50 > 1,000 mg/kg
Toluene Dermal Rat LD50 12,000 mg/kg
Toluene Inhalation-
Vapor (4
hours)
Rat LC50 30 mg/l
Toluene Ingestion Rat LD50 5,550 mg/kg
MIBK Dermal Rabbit LD50 > 16,000 mg/kg
MIBK Inhalation-
Vapor (4
hours)
Rat LC50 11 mg/l
MIBK Ingestion Rat LD50 3,038 mg/kg
Cumene Dermal Rabbit LD50 > 3,160 mg/kg
Cumene Inhalation-
Vapor (4
hours)
Rat LC50 39.4 mg/l
Cumene Ingestion Rat LD50 1,400 mg/kg
Chlorobenzene Dermal Rabbit LD50 2,212 mg/kg
Chlorobenzene Inhalation-
Vapor (4
hours)
Rat LC50 16.7 mg/l
Chlorobenzene Ingestion Rat LD50 1,419 mg/kg
Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg
Naphthalene Inhalation-
Vapor
Human LC50 estimated to be 20 - 50 mg/l
Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg
Maleic Anhydride Dermal Rabbit LD50 2,620 mg/kg
Maleic Anhydride Ingestion Rat LD50 1,030 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Cyclohexane Rabbit Mild irritant
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Xylene Rabbit Mild irritant
Ethylbenzene Rabbit Mild irritant
Ethyl Alcohol Rabbit No significant irritation
Ethyl Acetate Rabbit Minimal irritation
Chlorinated Polyolefin Guinea
pig
No significant irritation
Isopropyl Alcohol Multiple
animal
species
No significant irritation
Methyl Alcohol Rabbit Mild irritant
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane Rabbit Minimal irritation
Epoxy Resin Rabbit Mild irritant
Toluene Rabbit Irritant
MIBK Rabbit Mild irritant
Cumene Rabbit Minimal irritation
Chlorobenzene Rabbit Irritant
Naphthalene Rabbit Minimal irritation
Maleic Anhydride Human
and
animal
Corrosive
Serious Eye Damage/Irritation
Name Species Value
Cyclohexane Rabbit Mild irritant
Xylene Rabbit Mild irritant
Ethylbenzene Rabbit Moderate irritant
Ethyl Alcohol Rabbit Severe irritant
Ethyl Acetate Rabbit Mild irritant
Chlorinated Polyolefin Professio
nal
judgeme
nt
Mild irritant
Isopropyl Alcohol Rabbit Severe irritant
Methyl Alcohol Rabbit Moderate irritant
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane Rabbit No significant irritation
Epoxy Resin Rabbit Moderate irritant
Toluene Rabbit Moderate irritant
MIBK Rabbit Mild irritant
Cumene Rabbit Mild irritant
Chlorobenzene Rabbit Mild irritant
Naphthalene Rabbit No significant irritation
Maleic Anhydride Rabbit Corrosive
Skin Sensitization
Name Species Value
Ethylbenzene Human Not classified
Ethyl Alcohol Human Not classified
Ethyl Acetate Guinea
pig
Not classified
Isopropyl Alcohol Guinea
pig
Not classified
Methyl Alcohol Guinea
pig
Not classified
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane similar
compoun
ds
Sensitizing
Epoxy Resin Human
and
animal
Sensitizing
Toluene Guinea
pig
Not classified
MIBK Guinea
pig
Not classified
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Cumene Guinea
pig
Not classified
Chlorobenzene Multiple
animal
species
Not classified
Maleic Anhydride Multiple
animal
species
Sensitizing
Respiratory Sensitization
Name Species Value
Epoxy Resin Human Not classified
Maleic Anhydride Human Sensitizing
Germ Cell Mutagenicity
Name Route Value
Cyclohexane In Vitro Not mutagenic
Cyclohexane In vivo Some positive data exist, but the data are not
sufficient for classification
Xylene In Vitro Not mutagenic
Xylene In vivo Not mutagenic
Ethylbenzene In vivo Not mutagenic
Ethylbenzene In Vitro Some positive data exist, but the data are not
sufficient for classification
Ethyl Alcohol In Vitro Some positive data exist, but the data are not
sufficient for classification
Ethyl Alcohol In vivo Some positive data exist, but the data are not
sufficient for classification
Ethyl Acetate In Vitro Not mutagenic
Ethyl Acetate In vivo Not mutagenic
Isopropyl Alcohol In Vitro Not mutagenic
Isopropyl Alcohol In vivo Not mutagenic
Methyl Alcohol In Vitro Some positive data exist, but the data are not
sufficient for classification
Methyl Alcohol In vivo Some positive data exist, but the data are not
sufficient for classification
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane In Vitro Some positive data exist, but the data are not
sufficient for classification
Epoxy Resin In vivo Not mutagenic
Epoxy Resin In Vitro Some positive data exist, but the data are not
sufficient for classification
Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic
MIBK In Vitro Not mutagenic
Cumene In Vitro Not mutagenic
Cumene In vivo Not mutagenic
Chlorobenzene In Vitro Not mutagenic
Maleic Anhydride In vivo Not mutagenic
Maleic Anhydride In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Xylene Dermal Rat Not carcinogenic
Xylene Ingestion Multiple
animal
species
Not carcinogenic
Xylene Inhalation Human Some positive data exist, but the data are not
sufficient for classification
Ethylbenzene Inhalation Multiple
animal
species
Carcinogenic
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Ethyl Alcohol Ingestion Multiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Isopropyl Alcohol Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Methyl Alcohol Inhalation Multiple
animal
species
Not carcinogenic
Beta-(3,4-Epoxycyclohexyl)Ethyltrimethoxy Silane Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Epoxy Resin Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
MIBK Inhalation Multiple
animal
species
Carcinogenic
Cumene Inhalation Multiple
animal
species
Carcinogenic
Chlorobenzene Ingestion Multiple
animal
species
Not carcinogenic
Naphthalene Inhalation Multiple
animal
species
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24
mg/l
2 generation
Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24
mg/l
2 generation
Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9
mg/l
2 generation
Xylene Inhalation Not classified for female reproduction Human NOAEL Not
available
occupational
exposure
Xylene Ingestion Not classified for development Mouse NOAEL Not
available
during
organogenesi
s
Xylene Inhalation Not classified for development Multiple
animal
species
NOAEL Not
available
during
gestation
Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3
mg/l
premating &
during
gestation
Ethyl Alcohol Inhalation Not classified for development Rat NOAEL 38
mg/l
during
gestation
Ethyl Alcohol Ingestion Not classified for development Rat NOAEL 5,200
mg/kg/day
premating &
during
gestation
Isopropyl Alcohol Ingestion Not classified for female reproduction Rat NOAEL 1,000
mg/kg/day
2 generation
Isopropyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 500
mg/kg/day
2 generation
Isopropyl Alcohol Ingestion Not classified for development Rat NOAEL 400
mg/kg/day
during
organogenesi
s
Isopropyl Alcohol Inhalation Not classified for development Rat LOAEL 9 during
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mg/l gestation
Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600
mg/kg/day
21 days
Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000
mg/kg/day
during
organogenesi
s
Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3
mg/l
during
organogenesi
s
Beta-(3,4-
Epoxycyclohexyl)Ethyltrimethoxy Silane
Ingestion Not classified for development Rabbit NOAEL 0.27
mg/kg/day
during
organogenesi
s
Epoxy Resin Ingestion Not classified for female reproduction Rat NOAEL 750
mg/kg/day
2 generation
Epoxy Resin Ingestion Not classified for male reproduction Rat NOAEL 750
mg/kg/day
2 generation
Epoxy Resin Dermal Not classified for development Rabbit NOAEL 300
mg/kg/day
during
organogenesi
s
Epoxy Resin Ingestion Not classified for development Rat NOAEL 750
mg/kg/day
2 generation
Toluene Inhalation Not classified for female reproduction Human NOAEL Not
available
occupational
exposure
Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3
mg/l
1 generation
Toluene Ingestion Toxic to development Rat LOAEL 520
mg/kg/day
during
gestation
Toluene Inhalation Toxic to development Human NOAEL Not
available
poisoning
and/or abuse
MIBK Inhalation Not classified for female reproduction Multiple
animal
species
NOAEL 8.2
mg/l
2 generation
MIBK Ingestion Not classified for male reproduction Rat NOAEL 1,000
mg/kg/day
13 weeks
MIBK Inhalation Not classified for male reproduction Multiple
animal
species
NOAEL 8.2
mg/l
2 generation
MIBK Inhalation Not classified for development Mouse NOAEL 12.3
mg/l
during
organogenesi
s
Cumene Inhalation Not classified for development Rabbit NOAEL 11.3
mg/l
during
organogenesi
s
Chlorobenzene Inhalation Not classified for female reproduction Rat NOAEL 2.07
mg/l
2 generation
Chlorobenzene Ingestion Not classified for development Rat NOAEL 300
mg/kg/day
during
organogenesi
s
Chlorobenzene Inhalation Not classified for development Rat NOAEL 2.07
mg/l
2 generation
Chlorobenzene Inhalation Not classified for male reproduction Rat NOAEL 2.07
mg/l
2 generation
Maleic Anhydride Ingestion Not classified for female reproduction Rat NOAEL 55
mg/kg/day
2 generation
Maleic Anhydride Ingestion Not classified for male reproduction Rat NOAEL 55
mg/kg/day
2 generation
Maleic Anhydride Ingestion Not classified for development Rat NOAEL 140
mg/kg/day
during
organogenesi
s
Lactation
Name Route Species Value
Xylene Ingestion Mouse Not classified for effects on or via lactation
Target Organ(s)
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Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Cyclohexane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
Cyclohexane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human
and
animal
NOAEL Not
available
Cyclohexane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3
mg/l
8 hours
Xylene Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Xylene Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Xylene Inhalation eyes Not classified Rat NOAEL 3.5
mg/l
not available
Xylene Inhalation liver Not classified Multiple
animal
species
NOAEL Not
available
Xylene Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
Xylene Ingestion eyes Not classified Rat NOAEL 250
mg/kg
not applicable
Ethylbenzene Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human
and
animal
NOAEL Not
available
Ethyl Alcohol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human LOAEL 9.4
mg/l
not available
Ethyl Alcohol Inhalation central nervous
system depression
Not classified Human
and
animal
NOAEL not
available
Ethyl Alcohol Ingestion central nervous
system depression
Not classified Multiple
animal
species
NOAEL not
available
Ethyl Alcohol Ingestion kidney and/or
bladder
Not classified Dog NOAEL
3,000 mg/kg
Ethyl Acetate Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Ethyl Acetate Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Ethyl Acetate Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Isopropyl Alcohol Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Isopropyl Alcohol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Isopropyl Alcohol Inhalation auditory system Not classified Guinea
pig
NOAEL 13.4
mg/l
24 hours
Isopropyl Alcohol Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not
available
occupational
exposure
Methyl Alcohol Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
not available
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Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
6 hours
Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not
available
poisoning
and/or abuse
Methyl Alcohol Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
Toluene Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Toluene Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Toluene Inhalation immune system Not classified Mouse NOAEL
0.004 mg/l
3 hours
Toluene Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
MIBK Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human LOAEL 0.1
mg/l
2 hours
MIBK Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
MIBK Inhalation vascular system Not classified Dog NOAEL Not
available
not available
MIBK Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Rat LOAEL 900
mg/kg
not applicable
Cumene Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not available
Cumene Inhalation respiratory irritation May cause respiratory irritation Human LOAEL 0.2
mg/l
occupational
exposure
Cumene Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not available
Chlorobenzene Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Chlorobenzene Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
occupational
exposure
Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not
available
poisoning
and/or abuse
Maleic Anhydride Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Cyclohexane Inhalation liver Not classified Rat NOAEL 24
mg/l
90 days
Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7
mg/l
90 days
Cyclohexane Inhalation kidney and/or
bladder
Not classified Rabbit NOAEL 2.7
mg/l
10 weeks
Cyclohexane Inhalation hematopoietic
system
Not classified Mouse NOAEL 24
mg/l
14 weeks
Cyclohexane Inhalation peripheral nervous
system
Not classified Rat NOAEL 8.6
mg/l
30 weeks
Xylene Inhalation nervous system Causes damage to organs through
prolonged or repeated exposure
Rat LOAEL 0.4
mg/l
4 weeks
Xylene Inhalation auditory system May cause damage to organs
though prolonged or repeated
exposure
Rat LOAEL 7.8
mg/l
5 days
Xylene Inhalation liver Not classified Multiple
animal
species
NOAEL Not
available
Xylene Inhalation heart | endocrine
system |
Not classified Multiple
animal
NOAEL 3.5
mg/l
13 weeks
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gastrointestinal tract
| hematopoietic
system | muscles |
kidney and/or
bladder | respiratory
system
species
Xylene Ingestion auditory system Not classified Rat NOAEL 900
mg/kg/day
2 weeks
Xylene Ingestion kidney and/or
bladder
Not classified Rat NOAEL
1,500
mg/kg/day
90 days
Xylene Ingestion liver Not classified Multiple
animal
species
NOAEL Not
available
Xylene Ingestion heart | skin |
endocrine system |
bone, teeth, nails,
and/or hair |
hematopoietic
system | immune
system | nervous
system | respiratory
system
Not classified Mouse NOAEL
1,000
mg/kg/day
103 weeks
Ethylbenzene Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 1.1
mg/l
2 years
Ethylbenzene Inhalation liver Some positive data exist, but the
data are not sufficient for
classification
Mouse NOAEL 1.1
mg/l
103 weeks
Ethylbenzene Inhalation hematopoietic
system
Not classified Rat NOAEL 3.4
mg/l
28 days
Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4
mg/l
5 days
Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3
mg/l
103 weeks
Ethylbenzene Inhalation gastrointestinal tract Not classified Rat NOAEL 3.3
mg/l
2 years
Ethylbenzene Inhalation bone, teeth, nails,
and/or hair |
muscles
Not classified Multiple
animal
species
NOAEL 4.2
mg/l
90 days
Ethylbenzene Inhalation heart | immune
system | respiratory
system
Not classified Multiple
animal
species
NOAEL 3.3
mg/l
2 years
Ethylbenzene Ingestion liver | kidney and/or
bladder
Not classified Rat NOAEL 680
mg/kg/day
6 months
Ethyl Alcohol Inhalation liver Some positive data exist, but the
data are not sufficient for
classification
Rabbit LOAEL 124
mg/l
365 days
Ethyl Alcohol Inhalation hematopoietic
system | immune
system
Not classified Rat NOAEL 25
mg/l
14 days
Ethyl Alcohol Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL
8,000
mg/kg/day
4 months
Ethyl Alcohol Ingestion kidney and/or
bladder
Not classified Dog NOAEL
3,000
mg/kg/day
7 days
Ethyl Acetate Inhalation endocrine system |
liver | nervous
system
Not classified Rat NOAEL
0.043 mg/l
90 days
Ethyl Acetate Inhalation hematopoietic
system
Not classified Rabbit LOAEL 16
mg/l
40 days
Ethyl Acetate Ingestion hematopoietic
system | liver |
kidney and/or
bladder
Not classified Rat NOAEL
3,600
mg/kg/day
90 days
Isopropyl Alcohol Inhalation kidney and/or
bladder
Not classified Rat NOAEL 12.3
mg/l
24 months
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Isopropyl Alcohol Inhalation nervous system Not classified Rat NOAEL 12
mg/l
13 weeks
Isopropyl Alcohol Ingestion kidney and/or
bladder
Not classified Rat NOAEL 400
mg/kg/day
12 weeks
Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55
mg/l
4 weeks
Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1
mg/l
6 weeks
Methyl Alcohol Ingestion liver | nervous
system
Not classified Rat NOAEL
2,500
mg/kg/day
90 days
Epoxy Resin Dermal liver Not classified Rat NOAEL
1,000
mg/kg/day
2 years
Epoxy Resin Dermal nervous system Not classified Rat NOAEL
1,000
mg/kg/day
13 weeks
Epoxy Resin Ingestion auditory system |
heart | endocrine
system |
hematopoietic
system | liver | eyes |
kidney and/or
bladder
Not classified Rat NOAEL
1,000
mg/kg/day
28 days
Toluene Inhalation auditory system |
eyes | olfactory
system
Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
poisoning
and/or abuse
Toluene Inhalation nervous system May cause damage to organs
though prolonged or repeated
exposure
Human NOAEL Not
available
poisoning
and/or abuse
Toluene Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 2.3
mg/l
15 months
Toluene Inhalation heart | liver | kidney
and/or bladder
Not classified Rat NOAEL 11.3
mg/l
15 weeks
Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1
mg/l
4 weeks
Toluene Inhalation immune system Not classified Mouse NOAEL Not
available
20 days
Toluene Inhalation bone, teeth, nails,
and/or hair
Not classified Mouse NOAEL 1.1
mg/l
8 weeks
Toluene Inhalation hematopoietic
system | vascular
system
Not classified Human NOAEL Not
available
occupational
exposure
Toluene Inhalation gastrointestinal tract Not classified Multiple
animal
species
NOAEL 11.3
mg/l
15 weeks
Toluene Ingestion nervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 625
mg/kg/day
13 weeks
Toluene Ingestion heart Not classified Rat NOAEL
2,500
mg/kg/day
13 weeks
Toluene Ingestion liver | kidney and/or
bladder
Not classified Multiple
animal
species
NOAEL
2,500
mg/kg/day
13 weeks
Toluene Ingestion hematopoietic
system
Not classified Mouse NOAEL 600
mg/kg/day
14 days
Toluene Ingestion endocrine system Not classified Mouse NOAEL 105
mg/kg/day
28 days
Toluene Ingestion immune system Not classified Mouse NOAEL 105
mg/kg/day
4 weeks
MIBK Inhalation liver Not classified Rat NOAEL 0.41
mg/l
13 weeks
MIBK Inhalation heart Not classified Multiple
animal
species
NOAEL 0.8
mg/l
2 weeks
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MIBK Inhalation kidney and/or
bladder
Not classified Multiple
animal
species
NOAEL 0.4
mg/l
90 days
MIBK Inhalation respiratory system Not classified Multiple
animal
species
NOAEL 4.1
mg/l
14 weeks
MIBK Inhalation endocrine system |
hematopoietic
system
Not classified Multiple
animal
species
NOAEL 0.41
mg/l
90 days
MIBK Inhalation nervous system Not classified Multiple
animal
species
NOAEL 0.41
mg/l
13 weeks
MIBK Ingestion endocrine system |
hematopoietic
system | liver |
kidney and/or
bladder
Not classified Rat NOAEL
1,000
mg/kg/day
13 weeks
MIBK Ingestion heart | immune
system | muscles |
nervous system |
respiratory system
Not classified Rat NOAEL
1,040
mg/kg/day
120 days
Cumene Inhalation auditory system |
endocrine system |
hematopoietic
system | liver |
nervous system |
eyes
Not classified Rat NOAEL 59
mg/l
13 weeks
Cumene Inhalation kidney and/or
bladder
Not classified Rat NOAEL 4.9
mg/l
13 weeks
Cumene Inhalation respiratory system Not classified Rat NOAEL 59
mg/l
13 weeks
Cumene Ingestion kidney and/or
bladder | heart |
endocrine system |
hematopoietic
system | liver |
respiratory system
Not classified Rat NOAEL 769
mg/kg/day
6 months
Chlorobenzene Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 0.69
mg/l
2 generation
Chlorobenzene Inhalation liver Not classified Rat NOAEL 2.1
mg/l
2 generation
Chlorobenzene Inhalation blood Not classified Rat NOAEL 0.35
mg/l
24 weeks
Chlorobenzene Ingestion bone marrow Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 250
mg/kg/day
13 weeks
Chlorobenzene Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 188
mg/kg/day
192 days
Chlorobenzene Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 125
mg/kg/day
13 weeks
Chlorobenzene Ingestion immune system Not classified Rat NOAEL 750
mg/kg/day
13 weeks
Naphthalene Dermal blood Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
poisoning
and/or abuse
Naphthalene Dermal eyes Not classified Human NOAEL Not
available
occupational
exposure
Naphthalene Inhalation respiratory system Causes damage to organs through
prolonged or repeated exposure
Rat LOAEL 0.01
mg/l
13 weeks
Naphthalene Inhalation blood Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
poisoning
and/or abuse
Naphthalene Inhalation eyes Not classified Human NOAEL Not
available
occupational
exposure
Naphthalene Ingestion blood Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
poisoning
and/or abuse
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Naphthalene Ingestion eyes May cause damage to organs
though prolonged or repeated
exposure
Rabbit LOAEL 500
mg/kg/day
15 days
Maleic Anhydride Inhalation respiratory system Causes damage to organs through
prolonged or repeated exposure
Rat LOAEL
0.0011 mg/l
6 months
Maleic Anhydride Inhalation endocrine system |
hematopoietic
system | nervous
system | kidney
and/or bladder |
heart | liver | eyes
Not classified Rat NOAEL
0.0098 mg/l
6 months
Maleic Anhydride Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 55
mg/kg/day
80 days
Maleic Anhydride Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 250
mg/kg/day
183 days
Maleic Anhydride Ingestion heart | nervous
system
Not classified Rat NOAEL 600
mg/kg/day
183 days
Maleic Anhydride Ingestion gastrointestinal tract Not classified Rat NOAEL 150
mg/kg/day
80 days
Maleic Anhydride Ingestion hematopoietic
system
Not classified Dog NOAEL 60
mg/kg/day
90 days
Maleic Anhydride Ingestion skin | endocrine
system | immune
system | eyes |
respiratory system
Not classified Rat NOAEL 150
mg/kg/day
80 days
Aspiration Hazard
Name Value
Cyclohexane Aspiration hazard
Xylene Aspiration hazard
Ethylbenzene Aspiration hazard
Toluene Aspiration hazard
MIBK Some positive data exist, but the data are not sufficient for
classification
Cumene Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Combustion products will include halogen acid (HCl/HF/HBr). Facility
must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
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Page 21 of 22
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D021 (Chlorobenzene)
SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical Hazards
Flammable (gases, aerosols, liquids, or solids)
Health Hazards
Aspiration Hazard
Carcinogenicity
Reproductive toxicity
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Cyclohexane 110-82-7 Trade Secret 30 - 60
Xylene 1330-20-7 Trade Secret 15 - 35
Xylene (Benzene, dimethyl-) 1330-20-7 Trade Secret 15 - 35
Ethylbenzene 100-41-4 Trade Secret 1 - 15
Cumene 98-82-8 Trade Secret < 0.2
MIBK 108-10-1 Trade Secret < 0.5

15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the China "Measures on Environmental Management of New
Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information.
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
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Page 22 of 22
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 3 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group:06-8243-5 Version Number:32.14
Issue Date:06/05/23 Supercedes Date:08/23/22
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
Safety Data Sheet
1. Product and Company Identification
Product Name: Phos-Clean 300
Supplier: ENCHEM Corporation
10424 Timberline Road
Kingston, OK 73439
Information Telephone: [phone]
Emergency Telephone: [phone]
Prepared: January 2019
2. Hazards Identification
Emergency Overview: There are no known acute toxic health hazards that are associated with
this product. The product is a known to be an eye irritant and precau-
tions should be taken to protect eyes from direct contact (R36). Prod-
uct may cause irritation to skin and precautions should be taken to
minimize skin exposure (S24/25).
Over Exposure Symptoms: Repeated exposure to eyes, without proper protection, could cause
redness, tearing and blurred vision. Eye irritation could be accompa-
nied with a stinging sensation. Repeated exposure to eyes, without
proper protection, could cause permanent damage to the optical lens.
Repeated exposure to skin could induce a rash that resembles heat
rash. Effects are more likely to occur in hot temperatures when skin
pours expand.
3. Composition/Information on Ingredients
Contains: Material Quantity CAS-#
Water Water Base 7732-18-5
Monosodium Phosphate 0 - 5% 7758-80-7
Sodium Xylene Sulfonate 0 – 5% 1300-72-7
Propylene Glycol Propyl Ether 0 – 5% 1569-01-3
Phosphoric Acid 0 – 3.5% 7664-38-2
Nonylphenol Ethoxylate 0 – 1.5% 9016-45-9 (215-185-5)
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or to the environment and hence
require reporting in this section.
COBRA PHOS-CLEAN 300
4. First Aid Measures
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with
running water for at least 15 minutes, keeping eyelids open. Seek im-
mediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Wash skin thoroughly with
soap and water or use recognized skin cleanser. Wash contaminated
clothing before reuse.
Inhalation: Remove to fresh air and keep person at rest. If any symptoms continue
following inhalation, obtain medical advice.
Ingestion: If swallowed, seek medical advice immediately and show this container
or label. Induce vomiting promptly using physician’s instructions or by
having patient stick finger down throat. Never give anything by mouth
to an unconscious person.
5. Fire-Fighting Measures
Flammability of Product: With the current knowledge of the supplier this product contains no
flammable properties.
Extinguishing Media: Use appropriate extinguishing media for surrounding fires.
Fire Fighting Procedures: Promptly isolate the scene by removing all persons from the vicinity of
the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Do not enter confined fire-
space without full bunker gear. (Helmet with face shield, bunker
coats, bunker pants, gloves & rubber boots). Use NIOSH approved posi-
tive-pressure self-contained breathing apparatus.
Unusual Explosion/Fire Hazards: Non-Combustible
Keep container tightly closed.
Closed containers may rupture if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
6. Accidental Release Measures
Containment Techniques: Isolate spill area from unprotected personnel. Wear appropriate per-
sonal protective equipment given in Section VIII. Ventilate spill area.
Locate spill source. Stop leak if without risk. Dike and contain product
at source if possible without risk.
Large Spill: Clean up product with absorbent materials. Dispose of absorbent ma -
terials.
Small Spill: Mop up product and dispose.
7. Handling and Storage
Handling: Use only with adequate ventilation. Wear OSHA Standard goggles with
rear facing vents or face shield. Consult Safety Equipment Supplier.
Wear gloves, apron & footwear impervious to this material. Wash cloth -
ing before reuse.
Storage: Do not store product above 49oC/120oF. Keep container tightly closed &
upright when not in use to prevent leakage.
8. Exposure Controls/Personal Protection
Respiratory Exposure Controls: A respiratory protection program that meets OSHA 29 CFR
1910.134 and ANSI Z86.2 requirements or European Standard EN 149
must be followed whenever workplace conditions warrant a respirator’s
use.
Ventilation: Local Exhaust: Necessary
Mechanical (general): Acceptable
Special: None
Other: None
Please refer to ACGIH document “Industrial Ventilation, A Manual of Recommended Practices”, most
recent
edition, for details.
Personal Protection: Wear OSHA Standard goggles with rear facing vents or face shield. If
applicable consult Safety Equipment Supplier. Wear gloves, jacket, leg-
gings and footwear impervious to this product. Wash any exposed cloth -
ing before reuse.
Work/Hygienic Practices: Provide readily accessible eye wash stations & safety showers. Wash at
end of each work shift & before eating, smoking or using the toilet.
Promptly remove clothing that becomes contaminated. Destroy conta-
minated leather articles. Launder or discard contaminated clothing.
9. Physical and Chemical Properties
Physical State: Liquid
Appearance: Milky liquid
Odor: Slight surfactant odor
Boiling Point: 100oC/212oF
Auto-Ignition Point: N/A
Flash Point: N/A
Flammability Classification: Non-combustible
Specific Gravity: 1.087
Pounds Per Gallon: 9.055
Total VOC’S (TVOC): 0.000 lbs/gal
Hazardous Air Pollutants: 0.000 lbs/gal
Vapor Pressure: 17.5
Vapor Density: 0.6
Solubility in Water: SOLUBLE
pH (1% solution): 2.6
Evaporation Rate (WATER = 1) 1
10. Stability and Reactivity
Stability: Stable under normal conditions.
Conditions to Avoid: Temperatures that meet or exceed 49oC/120oF.
Materials to Avoid: Strong oxidizers such as permanganates, chromates and perox-
ides. Product is known as a slight corrosive to metals.
Hazardous Decomposition Products: Phosphorus Pentoxide, Sodium Oxide & Hydroxide, Carbon Ox-
ides from heating.
Hazardous Polymerization: Under normal conditions of storage and use, hazardous poly-
merization will not occur.
11. Toxicological Information
Material CAS# TWA (OSHA) TLV (ACGIH)
HAP
Water 7732-18-5 None known None known No
Monosodium Phosphate 7758-80-7 None known None known No
Sodium Xylene Sulfonate 1300-72-7 50 ppm None known No
Phosphoric Acid 7664-38-2 1 mg/m3 None known No
This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1%
MATERIAL CAS# CEILING STEL (OSHA/ACGIH)
Monosodium Phosphate 7758-80-7 None known 3ppm
Phosphoric Acid 7664-38-2 None known 3 mg/m3
Sodium Xylene Sulfonate 1300-72-7 None known None known
Wastewaters produced by use of this product at recommended concentrations yield pH & total
phosphorus values within acceptable regulatory levels.
Acute Hazards:
Skin and Eye Exposure - Primary irritation to skin, defatting, dermatitis. Primary irrita-
tion to eyes, redness, tearing, blurred visions. Liquid can cause
eye irritation. Wash thoroughly after handling.
Inhalation - Anesthetic. Irritates respiratory tract.
Ingestion - Swallowing can cause abdominal irritation, nausea, vomiting &
diarrhea.
Chronic Hazards:
Cancer, Reproductive and other Chronic Hazards -
This product has no carcinogens listed by IARC, NTP, NIOSH,
OSHA or ACGIH, as of this date, greater than or equal to 0.1%
12. Ecological Information
Mammalian Information: No mammalian information is available on this product.
Aquatic Animal Information: No aquatic animal information is available on this product.
Mobility: Mobility of this material has not been determined.
Degradability: This product is completely biodegradable.
Accumulation: Bioaccumulaton of this product has not been determined.
13. Disposal Considerations
Waste Disposal: Processing, use or contamination may change the waste man-
agement options. Recycle/dispose of this product in observance
of national, regional, state, provincial and local health, safety
& pollution laws. If in doubt, contact appropriate agencies be-
fore disposal occurs.
14. Transport Information
DOT Shipping Description: Compounds, Cleaning Liquid (Containing Monosodium Phos-
phate)
Transporting Recommendations: Transport in tightly sealed containers. Carry a spill kit in the
vehicle for use in the event that a spill occurs.
15. Regulatory Information
Inventory Information: Not classified as a substance hazardous for supply.
16. Other Information
Hazardous Material Information System (HMIS):
Health 1
Flammability 0
Reactivity 0
National Fire Protection Association (NFPA):
Health 1
Flammability 0
Reactivity 0
OSHA Globally Harmonized System (GHS) Pictograms:

Disclaimer:
The information contained in this data sheet is based on present scientific and technical knowledge.
The purpose
of this information is to draw attention to the health and safety aspects concerning the products sup -
plied by
EnChem Corporation, and to recommend precautionary measures for the storage and handling of the
products.
No warranty or guarantee is given in respect of the properties of the products. No liability can be ac-
cepted for any
failure to observe the precautionary measures described in this data sheet or for any misuse of the
products. Any
liability is not acceptable since application of this product is not within our control.

SECTION 2) HAZARDS IDENTIFICATION
Classification
Acute toxicity Oral - Category 5
Carcinogenicity - Category 2
Eye Irritation - Category 2A
Respiratory Sensitizer (Solid/Liquid) - Category 1
Skin Irritation - Category 2
Skin Sensitizer - Category 1
Specific Target Organ Toxicity - Repeated Exposure - Category 2
Specific Target Organ Toxicity -Single Exposure (Respiratory Tract Irritation) - Category 3
Pictograms
Signal Word
Danger
Hazardous Statements - Health
H303 - May be harmful if swallowed
H351 - Suspected of causing cancer.
H319 - Causes serious eye irritation
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H373 - May cause damage to organs through prolonged or repeated exposure.
H335 - May cause respiratory irritation
Cobra HP, A-Side
Feb 22, 2018
Cobra Liner HP, A-Side
SAFETY DATA SHEET
Feb 22, 2018
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER'S IDENTIFICATION
1.0
Revision Date: Date Printed:Sep 21, 2021
Version: Supersedes Date:N.A.
Product ID:
Product Name:
10-12197
Cobra HP, A-Side
Manufacturer's Name:
Address:
Emergency Phone:
Information Phone Number:
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
Cobra HP, A-Side Page 1 of 8

JR Performance Inc.
54090 Eastview Dr, Bristol, IN US, 46507
Chemtrec:800-424-9300
574-215-7901
H335 - May cause respiratory irritation
Precautionary Statements - General
P101 - If medical advice is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P103 - Read label before use.
Precautionary Statements - Prevention
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P264 - Wash thoroughly after handling.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P284 - [In case of inadequate ventilation] wear respiratory protection.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
P271 - Use only outdoors or in a well-ventilated area.
P233 - Keep container tightly closed.
Precautionary Statements - Response
P312 - Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see section 4 on this SDS).
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P362 + P364 - Take off contaminated clothing. And wash it before reuse.
P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention.
P314 - Get Medical advice/attention if you feel unwell.
Precautionary Statements - Storage
P405 - Store locked up.
P403 + P405 - Store in a well-ventilated place. Store locked up.
Precautionary Statements - Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant.
SECTION 4) FIRST-AID MEASURES
Inhalation
CAS Chemical Name % By Weight
0068092-58-0 32% - 59%
0000101-68-8 31% - 57%
0000108-32-7
POLYURETHANE PREPOLYMER
4,4'-METHYLENEDIPHENYL DIISOCYANATE
4-METHYL-1,3-DIOXOLAN-2-ONE 5% - 10%
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS
Cobra HP, A-Side Page 2 of 8
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call
a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the
POISON CENTER/doctor.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Eliminate all ignition sources if safe to do so.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash
with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/
attention. Wash contaminated clothing before re-use or discard.
IF exposed or concerned: Get medical advice/attention.
Eye Contact
Avoid direct contact. Wear chemical protective gloves, if necessary.
Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if
present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto
the face. If eye irritation persists: Get medical advice/attention.
Ingestion
Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in
the recovery position.
IF exposed or concerned: Get medical advice/attention.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures.
Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and
water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media
If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.
Specific Hazards in Case of Fire
Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur.
Excessive pressure or temperature may cause explosive rupture of containers.
Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be
exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves
(neoprene), goggles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area.
Notify authorities if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment
Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions
Cobra HP, A-Side Page 3 of 8
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless
wearing appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized
drainage systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and
3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide).
Follow the precautions on the supplier's safety data sheets.
Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react
for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as
described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste.
Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved
carbon dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with
all relevant local, state, and federal laws and regulations regarding treatment.
SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended
to control emissions near the source.
Storage Room Requirements
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely
sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened
must be carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground
all structures, transfer containers and equipment to conform to the national electrical code. Use procedures that prevent static electrical
sparks. Static electricity may accumulate and create a fire hazard.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids.
If additional protection is needed for entire face, use in combination with a face shield.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
decontaminated.
Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body
suit. Wash contaminated clothing before re-wearing.
Respiratory Protection
If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure
supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained
breathing apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.
Appropriate Engineering Controls
Cobra HP, A-Side Page 4 of 8
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value.
Chemical
Name
OSHA TWA
(ppm)
OSHA TWA
(mg/m3)
OSHA STEL
(ppm)
OSHA STEL
(mg/m3)
OSHA Tables
(Z1, Z2, Z3)
OSHA
Carcinogen
OSHA Skin
designation
NIOSH TWA
(ppm)
4,4'-
METHYLENEDI
PHENYL
DIISOCYANAT
E
0.02 ceiling 0.2 ceiling 1 0.005
Chemical
Name
NIOSH TWA
(mg/m3)
NIOSH STEL
(ppm)
NIOSH STEL
(mg/m3)
NIOSH
Carcinogen
ACGIH TWA
(ppm)
ACGIH TWA
(mg/m3)
ACGIH STEL
(ppm)
ACGIH STEL
(mg/m3)
4,4'-
METHYLENEDI
PHENYL
DIISOCYANAT
E
0.050 0.005
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Clear Liquid
N.A.
N.A.
N.A.
Slower than
ether N/A
200 °F
N.A.
N.A.
N.A.
302 °F
N.A.
N.A.
Aromatic
N.A.
N.A.
N.A.
Appearance
Auto Ignition Temp
Coefficient Water/Oil
Decomposition Pt
Evaporation Rate
Flammability
Flash Point
Flash Point Symbol
Freezing Point
High Boiling Point
Low Boiling Point
Lower Explosion Level
Melting Point
Odor Description
Odor Threshold
pH
Upper Explosion Level
Vapor Density
Vapor Pressure
Viscosity
VOC Part A & B Combined
Water Solubility
Heavier than air
N.A.
500-1000 cps
N.A.
Reacts With Water
9.61 lb/gal
1.15
Density
Specific Gravity
VOC Regulatory(lb/gal)0.00 lb/gal
SECTION 10) STABILITY AND REACTIVITY
Stability
Cobra HP, A-Side Page 5 of 8
Material is stable at standard temperature and pressure.
Conditions to Avoid
Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation
of carbon dioxide and buildup of pressure.
Hazardous Reactions/Polymerization
Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds
will accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.
Incompatible Materials
This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the
reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal
compounds. Some reactions can be violent. Material can react with strong oxidizing agents.
Hazardous Decomposition Products
Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may
be formed during combustion.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation
Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash,
scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these
symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor.
Causes skin irritation
Serious Eye Damage/Irritation
Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may
cause conjunctivitis. Any level of contact should not be left untreated.
Causes serious eye irritation
Respiratory/Skin Sensitization
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause an allergic skin reaction
Carcinogenicity
Suspected of causing cancer.
Germ Cell Mutagenicity
No data available.
Reproductive Toxicity
No data available.
Specific Target Organ Toxicity - Single Exposure
May cause respiratory irritation
Specific Target Organ Toxicity - Repeated Exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard
No data available.
Acute Toxicity
May be harmful if swallowed
0000101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
LC50 (rat): 369-490 mg/m3 (aerosol) (4-hour exposure) (1)
LC50 (rat): 178 mg/m3 (17.4 ppm) (duration of exposure not reported) (2)
LD50 (oral, rat): greater than 10,000 mg/kg (1,2)
LD50 (dermal, rabbit): greater than 10,000 mg/kg (1)
LD50 (oral, mouse): 2,200 mg/kg (3)
Cobra HP, A-Side Page 6 of 8
SECTION 12) ECOLOGICAL INFORMATION
Toxicity
No data available.
Persistence and Degradability
No data available.
Bioaccumulative Potential
No data available.
Mobility in Soil
No data available.
Other Adverse Effects
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets
RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for
any other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
Not regulated
IMDG Information
Not regulated.
IATA Information
Not regulated.
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0068092-58-0 32% - 59%DSL,SARA312,TSCA
0000101-68-8
POLYURETHANE PREPOLYMER
4,4'-METHYLENEDIPHENYL
DIISOCYANATE
31% - 57%SARA313,
DSL,CERCLA,HAPS,SARA312,VHA
PS,VOC,TSCA
0000108-32-7 4-METHYL-1,3-DIOXOLAN-2-ONE 5% - 10%DSL,SARA312,TSCA
SECTION 16) OTHER INFORMATION
OTHER INFORMATION
Note: As per GHS, category 1 is the greatest level of hazard within each class.
GLOSSARY
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65-
California Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec-
Chemical Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List;
EC- Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and
Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;
LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and
Cobra HP, A-Side Page 7 of 8
Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and
Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing
Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA-
Toxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries
assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is
the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based
on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the
product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of
this information.
Cobra HP, A-Side Page 8 of 8
SECTION 2) HAZARDS IDENTIFICATION
Classification
Acute aquatic toxicity - Category 2
Acute toxicity Dermal - Category 5
Acute toxicity Oral - Category 5
Carcinogenicity - Category 2
Chronic aquatic toxicity - Category 2
Eye Irritation - Category 2
Specific Target Organ Toxicity - Repeated Exposure - Category 2
Pictograms
Signal Word
Warning
Hazardous Statements - Health
H313 - May be harmful in contact with skin
H303 - May be harmful if swallowed
H351 - Suspected of causing cancer.
H319 - Causes serious eye irritation
H373 - May cause damage to organs through prolonged or repeated exposure.
Hazardous Statements - Environmental
H411 - Toxic to aquatic life with long lasting effects
Precautionary Statements - General
P101 - If medical advice is needed, have product container or label at hand.
Cobra Liner HP, B-Side
Apr 02, 2018
Cobra Liner HP, Black
SAFETY DATA SHEET
Jun 08, 2020
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER'S IDENTIFICATION
1.0
Jun 08, 2020Date Printed:
Supersedes Date:N.A.
Product ID:
Product Name:
10-12198
Cobra Liner HP, B-Side
Revision Date:
Version:
Manufacturer's Name:
Address:
Emergency Phone:
Information Phone Number:
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
Cobra Liner HP, B-Side Page 1 of 8
JR Performance Inc.
54090 Eastview Dr, Bristol, IN US, 46507
Chemtrec:800-424-9300
574-215-7901
P101 - If medical advice is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P103 - Read label before use.
Precautionary Statements - Prevention
P273 - Avoid release to the environment.
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P264 - Wash thoroughly after handling.
P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
Precautionary Statements - Response
P312 - Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical advice/attention.
P391 - Collect spillage.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P314 - Get Medical advice/attention if you feel unwell.
Precautionary Statements - Storage
P405 - Store locked up.
Precautionary Statements - Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant.
SECTION 4) FIRST-AID MEASURES
Inhalation
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call
a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the
POISON CENTER/doctor.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash
with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/
attention. Wash contaminated clothing before re-use or discard.
IF exposed or concerned: Get medical advice/attention.
Eye Contact
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes.
Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Ingestion
IF exposed or concerned: Get medical advice/attention.
Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the
recovery position.
CAS Chemical Name % By Weight
0068479-98-1 AROMATIC AMINE 13% - 25%
0001333-86-4 CARBON BLACK 4% - 7%
0014808-60-7 SILICA, CRYSTALLINE 0.3% - 0.4%
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS
Cobra Liner HP, B-Side Page 2 of 8
Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an
unconscious person.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide water spray or fog is recommended. Water spray is recommended to cool or protect exposed
materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces.
Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for
small fires only.Specific Hazards in Case of Fire
Sudden reaction and fire may result when the product is exposed to oxidizing agents.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be
exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves
(neoprene), goggles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Recommended Equipment
Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless
wearing appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized
drainage systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work
area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as
hazardous waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended
to control emissions near the source.
Storage Room Requirements
Cobra Liner HP, B-Side Page 3 of 8
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely
sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened
must be carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above
ground and surround by dikes to contain spills or leaks.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids.
If additional protection is needed for entire face, use in combination with a face shield.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
decontaminated.
Respiratory Protection
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory
protective equipment suppliers.
When airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air
respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-container breathing apparatus.
Appropriate Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value.
Chemical
Name
OSHA TWA
(ppm)
OSHA TWA
(mg/m3)
OSHA STEL
(ppm)
OSHA STEL
(mg/m3)
OSHA Tables
(Z1, Z2, Z3)
OSHA
Carcinogen
OSHA Skin
designation
NIOSH TWA
(ppm)
CARBON
BLACK
3.5 1
SILICA,
CRYSTALLINE
a [10 mg/m3
percent SiO2+2
/ 250 percent
SiO2+5 mppcf];
[30 mg/m3
percent
SiO2+2];
[1,3]; [3];
Chemical
Name
NIOSH TWA
(mg/m3)
NIOSH STEL
(ppm)
NIOSH STEL
(mg/m3)
NIOSH
Carcinogen
ACGIH TWA
(ppm)
ACGIH TWA
(mg/m3)
ACGIH STEL
(ppm)
ACGIH STEL
(mg/m3)
CARBON
BLACK
3.5a 1 3 (I)
SILICA,
CRYSTALLINE
0.05e 1 0.025 (R)
(I) - Inhalable fraction, (R) - Respirable fraction
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Density 8.65 lb/gal
Specific Gravity 1.04
Cobra Liner HP, B-Side Page 4 of 8
VOC Part A & B Combined
Appearance
Odor Threshold
Odor Description
pH
Water Solubility
Flammability
Flash Point Symbol Flash
Point
Viscosity
Lower Explosion Level
Upper Explosion Level
Vapor Pressure
Vapor Density
Freezing Point
Melting Point
Low Boiling Point
High Boiling Point
Auto Ignition Temp
Decomposition Pt
Evaporation Rate
Coefficient Water/Oil
N.A.
Liquid
N.A.
N.A.
N.A.
N.A.
N/A
N.A.
130 °C
N.A.
N.A.
N.A.
N.A.
Heavier than air
N.A.
N.A.
N.A.
N.A.
N.A.
N.A.
Slower than ether
N.A.
VOC Regulatory 0.00 lb/gal
SECTION 10) STABILITY AND REACTIVITY
Stability
Material is stable at standard temperature and pressure.
Conditions to Avoid
Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.
Hazardous Reactions/Polymerization
Will not occur.
Incompatible Materials
This product will react with any material containing isocyanate. Some reactions can be violent.
Hazardous Decomposition Products
Combustion products: organic vapors and thermal decomposition fragments.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation
Product may be absorbed through skin and cause nausea, headache, and general discomfort.
No data available.
Serious Eye Damage/Irritation
Vapors can irritate the eyes. Chemical burns may result due to overexposure. Affects of exposure may be delayed.
Causes serious eye irritation
Respiratory/Skin Sensitization
Inhalation : Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate
or delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.
Cobra Liner HP, B-Side Page 5 of 8
Skin sensitization may develop after repeated and/or prolonged contact.
No data available.
Carcinogenicity
Suspected of causing cancer.
Germ Cell Mutagenicity
No data available.
Reproductive Toxicity
No data available.
Specific Target Organ Toxicity - Single Exposure
No data available.
Specific Target Organ Toxicity - Repeated Exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard
No data available.
Acute Toxicity
If ingested : In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion,
and injury may be severe and cause death.
Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders.
May be harmful in contact with skin
May be harmful if swallowed
Likely Routes of Exposure
Inhalation, Ingestion, Skin contact, Eye contact
Chronic Exposure
0001333-86-4 CARBON BLACK
CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to
carbon black for which there is inadequate human evidence, but sufficient animal evidence.
Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and
reduced pulmonary function.
0014808-60-7 SILICA, CRYSTALLINE
Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms
include coughing, shortness of breath, wheezing and reduced pulmonary function.
Potential Health Effects - Miscellaneous
0001333-86-4 CARBON BLACK
Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is
unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical
is known to the State of California to cause cancer.
0014808-60-7 SILICA, CRYSTALLINE
Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung
disease. Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to the
State of California to cause cancer.
0001333-86-4 CARBON BLACK
LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3)
SECTION 12) ECOLOGICAL INFORMATION
Toxicity
Toxic to aquatic life
Toxic to aquatic life with long lasting effects
Mobility in Soil
Cobra Liner HP, B-Side Page 6 of 8
No data available.
Other Adverse Effects
No data available.
Bio-accumulative Potential
No data available.
Persistence and Degradability
0001333-86-4 CARBON BLACK
Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in
the natural environment.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets
RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for
any other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
Not regulated
IMDG Information
UN/NA #: 3082
UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS AROMATIC AMINE)
Class: 9
Packing group: III
Marine Pollutant : Yes
IATA Information
UN/NA #: 3082
UN Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS AROMATIC AMINE)
Class: 9
Packing group: III
Placard: Class 9
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0068479-98-1 13% - 25%DSL,SARA312,VOC,TSCA
0001333-86-4
AROMATIC AMINE
CARBON BLACK 4% - 7%DSL,SARA312,TSCA,CA_Prop65
- California Proposition 65
0014808-60-7 SILICA, CRYSTALLINE 0.3% - 0.4%DSL,SARA312,TSCA,CA_Prop65
- California Proposition 65
SECTION 16) OTHER INFORMATION
OTHER INFORMATION
*There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for
the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases,
our system will say UN GHS.
GLOSSARY
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65-
California Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec-
Chemical
Cobra Liner HP, B-Side Page 7 of 8
Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC-
Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and
Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;
LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and
Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and
Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing
Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA-
Toxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.
ACGIH - American Conference of Governmental Industrial Hygienists; CAS - Chemical Abstracts Service ; Chemtrec - Chemical
Transportation Emergency Center; DSL - Domestic Substances List; ESL- Effects screening levels; GHS - "Globally Harmonized System
of Classification and Labelling of Chemicals" developed by the United Nations; HMIS - Hazardous Material Information Service; IATA -
Dangerous Goods Regulations (DGR) for the air transport (IATA); IMDG - International Maritime Dangerous Goods Code; LC - Lethal
Concentration; LD - Lethal Dose; NFPA - National Fire Protection Association; OEL - Occupational Exposure Limits; OSHA-
Occupational Safety and Health Administration, US Department of Labor; PEL - Permissible Exposure Limit; SARA 313 - Superfund
Amendments and Reauthorization Act, Section 313; SCBA - Self Contained Breathing Apparatus; ppm - parts per million; STEL - Short-
term exposure limit; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act Public Law 94-469; TWA - Time-weighted
average; US DOT- US Department of Transportation.
Version 1.0:
Revision Date: Jun 08,
2020 Version 1.0
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries
assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is
the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based
on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the
product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of
this information.
Cobra Liner HP, B-Side Page 8 of 8

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

____________________________________________________________
Page 1 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

* * *Section 1 - IDENTIFICATION* * *
Product Identifier:
Manus Bond 76-AM Self Leveling
Recommended Use
adhesives / sealant
Restrictions on Use
None known.

Manufacturer Information
Manus Products, Inc. Phone: [phone]
866 Industrial Blvd. West
Waconia, MN 55387 Emergency # [phone]

* * *Section 2 - HAZARD(S) IDENTIFICATION* * *
Classification in accordance with 29 CFR 1910.1200.
Toxic to reproduction, Category 2
Hazardous to the Aquatic Environment - Acute Hazard, Category 3
Hazardous to the Aquatic Environment - Chronic Hazard, Category 3
GHS LABEL ELEMENTS
Symbol(s)

Signal Word
WARNING
Hazard Statement(s)
Suspected of damaging fertility or the unborn child
Harmful to aquatic life with long lasting effects
Precautionary Statement(s)
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Wear protective gloves/clothing and eye/face protection. Avoid release to the environment.
Response
IF exposed or concerned: Get medical advice/attention.
Storage
Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
* * *Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS* * *

CAS Component Percent
1317-65-3 Calcium Carbonate 30-55
471-34-1 Carbonic acid, calcium salt (1:1) 15-25
53306-54-0 1,2-Benzenedicarboxylic acid, bis(2-propylheptyl)ester 5-15

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

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Page 2 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

1760-24-3 N-[3-(Trimethyoxysilyl)propyl]-1,2-ethanediamine 0.5-2
13463-67-7 Titanium dioxide 0.1-1
1333-86-4 Carbon black 0.01-0.09

* * *Section 4 - FIRST-AID MEASURES* * *
Description of Necessary Measures
Inhalation
IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Skin Contact
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
Eye Contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion
If a large amount is swallowed, get immediate medical attention.
Most Important Symptoms/Effects
Acute
skin irritation and eye irritation.
Delayed
reproductive effects
Indication of Immediate Medical Attention and Special Treatment Needed, If Needed
Treat symptomatically and supportively.
* * *Section 5 - FIRE-FIGHTING MEASURES* * *
Suitable Extinguishing Media
Use carbon dioxide, regular dry chemical, regular foam or water.
Unsuitable Extinguishing Media
None known.
Special Hazards Arising from the Chemical
Hazardous Combustion Products
Combustion: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular
weight hydrocarbons.
Special Protective Equipment and Precautions for Firefighters
May burn, but does not ignite readily.
Fire Fighting Measures
Move material from fire area if it can be done without risk. Cool containers with water. Avoid inhalation of vapors
or combustion by-products. Use extinguishing agents appropriate for surrounding fire. Dike for later disposal. Stay
upwind and keep out of low areas.
Protective Equipment and Precautions for Firefighters
Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing.
Firefighters should avoid inhaling any combustion products.

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

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Page 3 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

* * *Section 6 - ACCIDENTAL RELEASE MEASURES* * *
Personal Precautions, Protective Equipment and Emergency Procedures
Wear personal protective clothing and equipment, see Section 8. Keep unnecessary people away, isolate hazard
area and deny entry. Only personnel trained for the hazards of this material should perform clean up and
disposal.
Methods and Materials for Containment and Cleaning Up
Ventilate the area. Stop leak if possible without personal risk. Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal. Avoid release to the environment.
* * *Section 7 - HANDLING AND STORAGE* * *
Precautions for Safe Handling
Do not handle until all safety precautions have been read and understood. Do not breathe vapor or mist. Avoid
contact with skin and eyes. Do not eat, drink, or smoke when using this product. Always wear recommended
personal protective equipment. Wear personal protective clothing and equipment, see Section 8. Wash thoroughly
after handling.
Conditions for Safe Storage, including any Incompatibilities
Store and handle in accordance with all current regulations and standards. Keep container tightly closed. Keep
separated from incompatible substances.
Incompatibilities: strong acids, strong oxidizing materials
* * *Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION* * *
Component Exposure Limits
Calcium Carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
Mexico 10 mg/m3 TWA LMPE-PPT
20 mg/m3 STEL [LMPE-CT]
Carbonic acid, calcium salt (1:1) (471-34-1)
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
Titanium dioxide (White, Gray, Beige and Neutral only) (13463-67-7)
ACGIH: 10 mg/m3 TWA
OSHA: 15 mg/m3 TWA (total dust)
Mexico 10 mg/m3 TWA LMPE-PPT (as Ti)
20 mg/m3 STEL [LMPE-CT] (as Ti)
Dibutyl tin (818-08-6)
ACGIH: 0.1 mg/m3 TWA (as Sn); 0.2 mg/m3 STEL (as Sn)
NIOSH: 0.1 mg/m3 TWA (except Cyhexatin, as Sn)
Carbon black (*used in Gray and Black ONLY) (1333-86-4)
ACGIH: 3 mg/m3 TWA (inhalable fraction)
OSHA: 3.5 mg/m3 TWA
NIOSH: 3.5 mg/m3 TWA; 0.1 mg/m3 TWA (Carbon black in presence of Polycyclic aromatic
hydrocarbons, as PAH)
Mexico 3.5 mg/m3 TWA LMPE-PPT
7 mg/m3 STEL [LMPE-CT]
Appropriate Engineering Controls
Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

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Page 4 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

Individual Protection Measures, such as Personal Protective Equipment
Eyes/Face Protection
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick
drench shower in the immediate work area.
Skin Protection
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Protective Materials
nitrile
Respiratory Protection
Use an approved respirator if exposure limits are exceeded or if irritation develops or persists.
* * *Section 9 - PHYSICAL AND CHEMICAL PROPERTIES* * *

Physical State: Liquid Appearance: paste
Color: various Physical Form: paste
Odor: mild Odor Threshold: Not available
pH: Not available Melting Point: Not available
Boiling Point: Not available Decomposition: Not available
Flash Point: >200 °F Evaporation Rate: Not available
OSHA Flammability Class: Not available Vapor Pressure: Not available
Vapor Density (air = 1): Not available Density: Not available
Specific Gravity (water = 1): 1.5-1.7 Water Solubility: Slightly soluble
Log KOW: Not available Coeff. Water/Oil Dist: Not available
KOC: Not available Auto Ignition: Not available
Viscosity: Not available VOC: 10 g/L
Volatility: Not available Molecular Formula: Not available

* * *Section 10 - STABILITY AND REACTIVITY* * *
Reactivity
No reactivity hazard is expected.
Chemical Stability
Stable at normal temperatures and pressure.
Possibility of Hazardous Reactions
Will not polymerize.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.
Incompatible Materials
strong acids, strong oxidizing materials
Hazardous Decomposition Products
Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight
hydrocarbons.
Hazardous Decomposition
Combustion: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular
weight hydrocarbons.

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

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Page 5 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

* * *Section 11 - TOXICOLOGICAL INFORMATION* * *
Acute Toxicity
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are
published:
Carbonic acid, calcium salt (1:1) (471-34-1)
Oral LD50 Rat 6450 mg/kg
Titanium dioxide (White, Gray, Beige and Neutral only) (13463-67-7)
Oral LD50 Rat >10000 mg/kg

Information on Likely Routes of Exposure
Inhalation
May be harmful if inhaled.
Ingestion
May be harmful if swallowed.
Skin Contact
May cause irritation of the skin. May cause irritation, redness, itching and burning.
Eye Contact
May cause irritation of the eyes. Contact may cause tearing, redness, a stinging or burning feeling, swelling, and
blurred vision.
Immediate Effects
skin irritation, eye irritation
Delayed Effects
No information is available.
Medical Conditions Aggravated by Exposure
skin disorders,eye disorders
Irritation/Corrosivity Data
Causes skin, eye and respiratory irritation.
Respiratory Sensitization
No information available for the product.
Dermal Sensitization
No information available for the product.
Germ Cell Mutagenicity
No information available for the product.
Carcinogenicity
Results of a DuPont epidemiology study showed that employees who had been exposed to titanium dioxide
pigments were at no greater risk of developing lung cancer than were employees who had not been exposed to
titanium dioxide pigments. No pulmonary fibrosis was found in any of the employees and no associations were
observed between titanium dioxide pigment exposure and chronic respiratory disease or lung abnormalities.
Based on the results of this study, DuPont concluded that titanium dioxide pigment will not cause lung cancer or
chronic respiratory disease in humans at concentrations experienced in the workplace.

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

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Page 6 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

Component Carcinogenicity
Titanium dioxide (13463-67-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 93 [2010]; Monograph 47 [1989] (Group 2B (possibly carcinogenic to humans))
DFG: Category 3A (could be carcinogenic for man, inhalable fraction with the exception of ultra small
particles)
OSHA: Present
Carbon black (1333-86-4)
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC: Monograph 93 [2010]; Monograph 65 [1996] (Group 2B (possibly carcinogenic to humans))
DFG: Category 3B (could be carcinogenic for man, inhalable fraction)
OSHA: Present
Reproductive Toxicity
May damage fertility or the unborn child
Specific Target Organ Toxicity - Single Exposure
No target organs identified.
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
Aspiration Hazard
No information available for the product.
* * *Section 12 - ECOLOGICAL INFORMATION* * *
Ecotoxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Analysis - Aquatic Toxicity
Diisononyl phthalate (28553-12-0)
Fish: 96 Hr LC50 Brachydanio rerio: >100 mg/L [semi-static]; 96 Hr LC50 Lepomis
macrochirus: >0.14 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: >0.17 mg/L
[static]; 96 Hr LC50 Pimephalespromelas: >0.19 mg/L [flow-through]; 96 Hr LC50
Pimephales promelas: >0.14 mg/L [static]
Algae: 72 Hr EC50 Desmodesmus subspicatus: >500 mg/L; 96 Hr EC50 Pseudokirchneriella
subcapitata: >1.8
mg/L [static
Invertebrate: 48 Hr EC50 Daphnia magna: >500 mg/L; 48 Hr EC50 Daphnia magna: >0.06 mg/L
[Static]
Persistence and Degradability
No information available for the product.
Bioaccumulation
No information available for the product.
Mobility
No information available for the product.
Biodegradation
No information available for the product.
* * *Section 13 - DISPOSAL CONSIDERATIONS* * *
Disposal Methods
Dispose in accordance with all applicable federal, state/regional and local laws and regulations.
Disposal of Contaminated Packaging
Dispose of properly. Recycle if possible.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

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Page 7 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

* * *Section 14 - TRANSPORT INFORMATION* * *
US DOT Information
Not regulated as a hazardous material.
TDG Information
Not regulated as dangerous goods.
* * *Section 15 - REGULATORY INFORMATION* * *
U.S. Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section
311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require
an OSHA process safety plan.

Acute Health: No Chronic Health: Yes Fire: No Pressure: No Reactive: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA
Calcium Carbonate 1317-65-3 No Yes Yes Yes Yes
Titanium dioxide 13463-67-7 No Yes Yes Yes Yes
Carbon black 1333-86-4 Yes Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of
1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
WARNING! This product contains a chemical known to the state of California to cause
reproductive/developmental effects.

Component Analysis - Inventory
Component CAS US CA EU AU PH JP KR CN NZ
Calcium Carbonate 1317-65-3 Yes NSL EIN Yes Yes Yes Yes Yes Yes
Carbonic acid, calcium salt
(1:1)
471-34-1 Yes DSL EIN Yes Yes Yes Yes Yes Yes
1,2-Benzenedicarboxylic
acid, bis(2-
propylheptyl)ester
53306-54-0 Yes DSL EIN Yes Yes Yes Yes Yes Yes
N-[3-
(Trimethyoxysilyl)propyl]-
1,2-ethanediamine
1760-24-3 Yes DSL EIN Yes Yes Yes Yes Yes Yes
Titanium dioxide 13463-67-7 Yes DSL EIN Yes Yes Yes Yes Yes Yes
Carbon black 1333-86-4 Yes DSL EIN Yes Yes Yes Yes Yes Yes

Safety Data Sheet
Product Identifier: Manus Bond 76-AM Self Leveling SDS ID: MAN-007

____________________________________________________________
Page 8 of 8 Issue Date: 05/05/15 Revision 1.0000 Print Date: 40/29/15/2015

* * *Section 16 - OTHER INFORMATION* * *
Summary of Changes
New SDS: 1.00

Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU -
Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service;
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR -
Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of
Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European
Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European
Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport
Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IMDG - International
Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower
Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration
Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH -
National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National
Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH -
Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry
of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL -
Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act;
TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
The information contained herein is based on data considered accurate which has been obtained from other
companies and organizations.

End of Sheet MAN-007
3
PB999 General Purpose
Fast Dry Spray Adhesive

Technical Data October 2017

Product Description Extremely versatile, fast tacking industrial grade spray adhesive with unique wide-web
spray pattern. Ideal for bonding a variety of substrates, including polystyrene.

Key Features • Creates quick permanent bonds on many substrates, including polystyrene, drainboard,
FRP panels, insulation, foams and fabrics.
• It features a very fast tacking adhesive that bonds almost immediately and has a
long bonding range.
• It has a unique heavy body spray pattern with low soak-in ideally suited for irregular
or porous substrates.
• Typically used in construction, specialty vehicle, RV, manufactured housing and HVAC.

Typical Properties Note: The following technical information and data should be considered
representative or typical only and should not be used for specification purposes.

Product PB 999 Cylinder Spray Adhesive
Base: Synthetic Elastomer
Solids Content - (by wt.): 21%
Density (lbs/gal): 5.7
Viscosity (cps): N/A
Color(s): Translucent, Green
Volatile Organic Compounds (VOC): 544 g/L
Hazardous Air Pollutants (HAPS) % wt
(calculated):
No
CARB Compliant: N/A
SCAQMD 1168 Compliant: No
GREENGUARD Indoor Air Quality
Certified®:
No
LEED® Eligible: No
Coverage @ 2.5 gms /ft2 per lb (sqft): 38
Spray Pattern: Lace
Dry Time: 30 seconds – 1 minute
Bonding Range: 30 seconds – 60 minutes
Shear Adhesion Failure Test - SAFT(1): 190F
Flammable Solvent: Yes
Flammable Propellant: Yes

(1)SAFT Shear Adhesion Failure Test with birch plywood, 1 inch overlap, 100 grams used, temperature start at 90F and ramped 10F every
10 mn. until complete failure.

Available Sizes
Container Size Stock Number UPC Number
Large Cylinder – 27.3 lbs. 17-0000-0815-5 0-00-51131-28222-3
Intermediate Cylinder – 139 lbs. 17-0000-0814-8 0-00-51131-28221-6
Jumbo Cylinder – 288 lbs. 17-0000-0816-3 0-00-51131-28223-0

Large Cylinder – 27.3 lbs. Green 17-0000-1765-1 0-00-51131-28401-9

Cylinder Spray Adhesive Applicators and Accessories 3M ID Numbers UPC Numbers
Applicators Cylinder Adhesive Applicator w/ 9501 tip 62-9880-9930-5 00-048011-61706-0
Cylinder Adhesive Applicator High Output w/ QSS tip 62-9880-9960-2 00-051111-07329-2
Hoses Cylinder Adhesive 6’ Hose 62-9880-0006-3 00-051115-25036-1
Cylinder Adhesive 12’ Hose 62-9880-0012-1 00-048011-61988-0
Cylinder Adhesive 25’ Hose 62-9880-0025-3 00-048011-61989-7
Cylinder Adhesive 50’ Hose 62-9880-0050-1 00-051115-25782-7
For application of PB999 at high volume and wide widths, the Cylinder Adhesive Applicator High Output with QSS
Tip is available. Please refer to Cylinder Spray Adhesives User’s Guide for additional detail.

3M™ PB999 General Purpose Fast Dry Spray Adhesive

Storage Store product at 60o-80oF (16o-27oC) for maximum storage life. Higher
temperatures reduce normal storage life. Lower temperatures may cause increased
viscosity of a temporary nature. Rotate stock on a “first in-first out” basis.

Shelf Life When stored at the recommended conditions in original, unopened container, this
product has a shelf life if 15 months from date of shipment.

Precautionary Information Refer to product label and Material Safety Data Sheet for health and safety
information before using this product. For additional health and safety information,
call 1-800-364-3577 or [phone].

Technical Information The technical information, guidance, and other statements contained in this
document or otherwise provided by 3M are based upon records, tests, or
experience that 3M believes to be reliable, but the accuracy, completeness, and
representative nature of such information is not guaranteed. Such information is
intended for people with knowledge and technical skills sufficient to assess and
apply their own informed judgment to the information. No license under any 3M or
third party intellectual property rights is granted or implied with this information.
Product Use Many factors beyond 3M’s control and uniquely within user’s knowledge and control
can affect the use and performance of a 3M product in a particular application. As a
result, customer is solely responsible for evaluating the product and determining
whether it is appropriate and suitable for customer’s application, including
conducting a workplace hazard assessment and reviewing all applicable regulations
and standards (e.g., OSHA, ANSI, etc.). Failure to properly evaluate, select, and use
a 3M product and appropriate safety products, or to meet all applicable safety
regulations, may result in injury, sickness, death, and/or harm to property

Warranty, Limited Remedy, Unless a different warranty is specifically stated on the applicable 3M product
and Disclaimer packaging or product literature (in which case such warranty governs), 3M
warrants that each 3M product meets the applicable 3M product specification at the
time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR
CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE, OR ARISING OUT OF A COURSE OF DEALING, CUSTOM,
OR USAGE OF TRADE. If a 3M product does not conform to this warranty, then the
sole and exclusive remedy is, at 3M’s option, replacement of the 3M product or
refund of the purchase price.

Limitation of Liability Except for the limited remedy stated above, and except to the extent prohibited by
law, 3M will not be liable for any loss or damage arising from or related to the 3M
product, whether direct, indirect, special, incidental, or consequential (including, but
not limited to, lost profits or business opportunity), regardless of the legal or equitable
theory asserted, including, but not limited to, warranty, contract, negligence, or strict
liability.

ISO 9 001
This Industrial Adhesives and Tapes Division product was manufactured under a 3M quality system registered to ISO 9001 standards.

  Industrial Adhesives and Tapes Division
3M Center, Building 225-3S-06
St. Paul, MN 55144-1000
800-362-3550 • 877-369-2923 (Fax) 3M is a trademark of 3M Company.
www.3M.com/sprayadhesives ©3M 2017

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Page 1 of 16
Safety Data Sheet
Copyright,2021, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:30-7214-7 Version Number:8.00
Issue Date:08/27/21 Supercedes Date:07/16/21
SECTION 1: Identification
1.1. Product identifier
3M™ PB999 General Purpose Fast Dry Adhesive, Cylinder

1.2. Recommended use and restrictions on use
Recommended use
Adhesive
This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(13)) for consumer paint or
coating removal.
1.3. Supplier’s details
MANUFACTURER:3M
DIVISION:Industrial Adhesives and Tapes Division
ADDRESS:3M Center, St. Paul, MN 55144-1000, USA
Telephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or [phone] (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Flammable Liquid: Category 1.
Reproductive Toxicity: Category 1B.
Simple Asphyxiant.
Specific Target Organ Toxicity (single exposure): Category 3.
2.2. Label elements
Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
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Hazard Statements
Extremely flammable liquid and vapor.
May cause drowsiness or dizziness.
May damage fertility or the unborn child.
May displace oxygen and cause rapid suffocation.
Precautionary Statements
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
Repeated exposure may cause skin dryness or cracking.
Supplemental Information:
Intentional concentration and inhalation may be harmful or fatal.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No.% by Wt
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Dimethyl Ether 115-10-6 30 - 60 Trade Secret *
Pentane 109-66-0 10 - 30 Trade Secret *
Non-Hazardous Components Trade Secret* 10 - 30 Trade Secret *
Acetone 67-64-1 < 6 Trade Secret *
Nitrogen 7727-37-9 <= 3 Trade Secret *
Cyclopentane 287-92-3 < 2 Trade Secret *
Isopentane 78-78-4 < 2 Trade Secret *
Heptane 142-82-5 < 1 Trade Secret *
Toluene 108-88-3 < 0.21 Trade Secret *
Talc 14807-96-6 < 0.1 Trade Secret *
Methylene Chloride 75-09-2 < 0.011 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Central nervous system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and
unconsciousness).
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Hydrocarbons During Combustion
Methane During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
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Ketones During Combustion
Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.
Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and
authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal
the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes,
on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid
release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or
properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk
of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust
ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is
potential for static electricity accumulation during transfer.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Protect from sunlight. Store away from
heat. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
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If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No.Agency Limit type Additional Comments
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human
carcin, Ototoxicant
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
Pentane 109-66-0 ACGIH TWA:1000 ppm
Pentane 109-66-0 OSHA TWA:2950 mg/m3(1000 ppm)
Dimethyl Ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm)
Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm
Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm)
Talc 14807-96-6 ACGIH TWA(respirable fraction):2
mg/m3
A4: Not class. as human
carcin
TALC 14807-96-6 OSHA TWA - Use asbestos limits:
Talc 14807-96-6 OSHA TWA
concentration(respirable):0.1
mg/m3(2.4 millions of
particles/cu. ft.);TWA:20
millions of particles/cu. ft.
Cyclopentane 287-92-3 ACGIH TWA:600 ppm
Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human
carcin
Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm)
Methylene Chloride 75-09-2 ACGIH TWA:50 ppm A3: Confirmed animal
carcin.
Methylene Chloride 75-09-2 OSHA TWA:25 ppm;STEL:125 ppm 29 CFR 1910.1052,
SKIN
Nitrogen 7727-37-9 ACGIH Limit value not established:simple asphyxiant
Isopentane 78-78-4 ACGIH TWA:1000 ppm
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray.
If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
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Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
Half facepiece or full facepiece supplied-air respirator
Organic vapor respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
Multicolor
Odor Solvent
Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point -25 ºC
Flash Point -41 ºC [Test Method:Closed Cup]
Evaporation rate No Data Available
Flammability (solid, gas)Not Applicable
Flammable Limits(LEL)3.4 % volume
Flammable Limits(UEL)18 % volume
Vapor Pressure No Data Available
Vapor Density >=1.6 [Ref Std:AIR=1]
Density 0.68 - 0.72 g/ml
Specific Gravity 0.68 - 0.72 [Ref Std:AIR=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature 350 ºC
Decomposition temperature No Data Available
Viscosity No Data Available
Hazardous Air Pollutants 0 % weight [Test Method:Calculated]
Volatile Organic Compounds < 580 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:EU VOC Value]
VOC Less H2O & Exempt Solvents < 570 g/l [Test Method:calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents < 4.8 lb/gal [Test Method:calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents < 80 % [Test Method:calculated per CARB title 2]
Solids Content < 20 %
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
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10.2. Chemical stability
Stable.

10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Sparks and/or flames
Heat

10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Prolonged or repeated exposure may cause: Dermal Defatting: Signs/symptoms may include localized redness, itching,
drying and cracking of skin.
Eye Contact:
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
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Single exposure may cause target organ effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
Ingredient CAS No.Class Description Regulation
Methylene Chloride 75-09-2 Grp. 2A: Probable human carc.International Agency for Research on Cancer
Methylene Chloride 75-09-2 Anticipated human carcinogen National Toxicology Program Carcinogens
Methylene Chloride 75-09-2 Cancer hazard OSHA Carcinogens
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE >50 mg/l
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Dimethyl Ether Inhalation-
Gas (4
hours)
Rat LC50 164,000 ppm
Pentane Dermal Rabbit LD50 3,000 mg/kg
Pentane Inhalation-
Vapor (4
hours)
Rat LC50 > 18 mg/l
Pentane Ingestion Rat LD50 > 2,000 mg/kg
Acetone Dermal Rabbit LD50 > 15,688 mg/kg
Acetone Inhalation-
Vapor (4
hours)
Rat LC50 76 mg/l
Acetone Ingestion Rat LD50 5,800 mg/kg
Non-Hazardous Components Dermal Not
available
LD50 > 2,000 mg/kg
Non-Hazardous Components Ingestion Not
available
LD50 > 2,000 mg/kg
Nitrogen Dermal LD50 estimated to be > 5,000 mg/kg
Nitrogen Inhalation-
Gas
LC50 estimated to be > 50,000 ppm
Nitrogen Ingestion LD50 estimated to be > 5,000 mg/kg
Isopentane Dermal Rabbit LD50 3,000 mg/kg
Isopentane Inhalation-
Vapor (4
hours)
Rat LC50 > 18 mg/l
Isopentane Ingestion Rat LD50 > 2,000 mg/kg
Heptane Dermal Rabbit LD50 3,000 mg/kg
Heptane Inhalation-
Vapor (4
hours)
Rat LC50 103 mg/l
Heptane Ingestion Rat LD50 > 15,000 mg/kg
Cyclopentane Dermal LD50 estimated to be > 5,000 mg/kg
Cyclopentane Inhalation-
Vapor (4
hours)
Rat LC50 > 25.3 mg/l
Cyclopentane Ingestion Rat LD50 > 5,000 mg/kg
Toluene Dermal Rat LD50 12,000 mg/kg
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Toluene Inhalation-
Vapor (4
hours)
Rat LC50 30 mg/l
Toluene Ingestion Rat LD50 5,550 mg/kg
Talc Dermal LD50 estimated to be > 5,000 mg/kg
Talc Ingestion LD50 estimated to be > 5,000 mg/kg
Methylene Chloride Dermal Rat LD50 > 2,000 mg/kg
Methylene Chloride Inhalation-
Vapor (4
hours)
Rat LC50 63.7 mg/l
Methylene Chloride Ingestion Rat LD50 1,410 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Pentane Rabbit Minimal irritation
Acetone Mouse Minimal irritation
Non-Hazardous Components Professio
nal
judgeme
nt
No significant irritation
Nitrogen Professio
nal
judgeme
nt
No significant irritation
Isopentane Rabbit Minimal irritation
Heptane Human Mild irritant
Cyclopentane Rabbit Minimal irritation
Toluene Rabbit Irritant
Talc Rabbit No significant irritation
Methylene Chloride Rabbit Irritant
Serious Eye Damage/Irritation
Name Species Value
Pentane Rabbit Mild irritant
Acetone Rabbit Severe irritant
Non-Hazardous Components Professio
nal
judgeme
nt
No significant irritation
Nitrogen Professio
nal
judgeme
nt
No significant irritation
Isopentane Rabbit Mild irritant
Heptane Professio
nal
judgeme
nt
Moderate irritant
Cyclopentane Rabbit Mild irritant
Toluene Rabbit Moderate irritant
Talc Rabbit No significant irritation
Methylene Chloride Rabbit Severe irritant
Skin Sensitization
Name Species Value
Pentane Guinea
pig
Not classified
Non-Hazardous Components Not classified
Isopentane Guinea
pig
Not classified
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Toluene Guinea
pig
Not classified
Respiratory Sensitization
Name Species Value
Talc Human Not classified
Germ Cell Mutagenicity
Name Route Value
Dimethyl Ether In Vitro Not mutagenic
Dimethyl Ether In vivo Not mutagenic
Pentane In vivo Not mutagenic
Pentane In Vitro Some positive data exist, but the data are not
sufficient for classification
Acetone In vivo Not mutagenic
Acetone In Vitro Some positive data exist, but the data are not
sufficient for classification
Isopentane In vivo Not mutagenic
Isopentane In Vitro Some positive data exist, but the data are not
sufficient for classification
Heptane In Vitro Not mutagenic
Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic
Talc In Vitro Not mutagenic
Talc In vivo Not mutagenic
Methylene Chloride In vivo Not mutagenic
Methylene Chloride In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Dimethyl Ether Inhalation Rat Not carcinogenic
Acetone Not
Specified
Multiple
animal
species
Not carcinogenic
Toluene Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
Talc Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Methylene Chloride Inhalation Multiple
animal
species
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Dimethyl Ether Inhalation Not classified for development Rat NOAEL
40,000 ppm
during
organogenesi
s
Pentane Ingestion Not classified for development Rat NOAEL 1,000
mg/kg/day
during
organogenesi
s
Pentane Inhalation Not classified for development Rat NOAEL 30
mg/l
during
organogenesi
s
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Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700
mg/kg/day
13 weeks
Acetone Inhalation Not classified for development Rat NOAEL 5.2
mg/l
during
organogenesi
s
Isopentane Ingestion Not classified for development Rat NOAEL 1,000
mg/kg/day
during
organogenesi
s
Isopentane Inhalation Not classified for development Rat NOAEL 30
mg/l
during
organogenesi
s
Toluene Inhalation Not classified for female reproduction Human NOAEL Not
available
occupational
exposure
Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3
mg/l
1 generation
Toluene Ingestion Toxic to development Rat LOAEL 520
mg/kg/day
during
gestation
Toluene Inhalation Toxic to development Human NOAEL Not
available
poisoning
and/or abuse
Talc Ingestion Not classified for development Rat NOAEL 1,600
mg/kg
during
organogenesi
s
Methylene Chloride Inhalation Not classified for female reproduction Rat NOAEL 5.2
mg/l
2 generation
Methylene Chloride Inhalation Not classified for male reproduction Rat NOAEL 5.2
mg/l
2 generation
Methylene Chloride Inhalation Not classified for development Multiple
animal
species
NOAEL 4.3
mg/l
during
gestation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Dimethyl Ether Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Rat LOAEL
10,000 ppm
30 minutes
Dimethyl Ether Inhalation cardiac sensitization Some positive data exist, but the
data are not sufficient for
classification
Dog NOAEL
100,000 ppm
5 minutes
Pentane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not available
Pentane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
available
not available
Pentane Inhalation cardiac sensitization Not classified Dog NOAEL Not
available
not available
Pentane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
not available
Acetone Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Acetone Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Acetone Inhalation immune system Not classified Human NOAEL 1.19
mg/l
6 hours
Acetone Inhalation liver Not classified Guinea
pig
NOAEL Not
available
Acetone Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
Isopentane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not available
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Isopentane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
available
not available
Isopentane Inhalation cardiac sensitization Not classified Dog NOAEL Not
available
not available
Isopentane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
not available
Heptane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Heptane Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Heptane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Cyclopentane Inhalation central nervous
system depression
May cause drowsiness or
dizziness
similar
compoun
ds
NOAEL Not
available
Cyclopentane Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Professio
nal
judgeme
nt
NOAEL Not
available
Toluene Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Toluene Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Toluene Inhalation immune system Not classified Mouse NOAEL
0.004 mg/l
3 hours
Toluene Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
Methylene Chloride Dermal blood Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
4 hours
Methylene Chloride Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
occupational
exposure
Methylene Chloride Inhalation blood Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Methylene Chloride Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Dimethyl Ether Inhalation hematopoietic
system
Not classified Rat NOAEL
25,000 ppm
2 years
Dimethyl Ether Inhalation liver Not classified Rat NOAEL
20,000 ppm
30 weeks
Pentane Inhalation peripheral nervous
system
Not classified Human NOAEL Not
available
occupational
exposure
Pentane Inhalation heart | skin |
endocrine system |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system
Not classified Rat NOAEL 20
mg/l
13 weeks
Pentane Ingestion kidney and/or Not classified Rat NOAEL 28 days
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bladder 2,000
mg/kg/day
Acetone Dermal eyes Not classified Guinea
pig
NOAEL Not
available
3 weeks
Acetone Inhalation hematopoietic
system
Not classified Human NOAEL 3
mg/l
6 weeks
Acetone Inhalation immune system Not classified Human NOAEL 1.19
mg/l
6 days
Acetone Inhalation kidney and/or
bladder
Not classified Guinea
pig
NOAEL 119
mg/l
not available
Acetone Inhalation heart | liver Not classified Rat NOAEL 45
mg/l
8 weeks
Acetone Ingestion kidney and/or
bladder
Not classified Rat NOAEL 900
mg/kg/day
13 weeks
Acetone Ingestion heart Not classified Rat NOAEL
2,500
mg/kg/day
13 weeks
Acetone Ingestion hematopoietic
system
Not classified Rat NOAEL 200
mg/kg/day
13 weeks
Acetone Ingestion liver Not classified Mouse NOAEL
3,896
mg/kg/day
14 days
Acetone Ingestion eyes Not classified Rat NOAEL
3,400
mg/kg/day
13 weeks
Acetone Ingestion respiratory system Not classified Rat NOAEL
2,500
mg/kg/day
13 weeks
Acetone Ingestion muscles Not classified Rat NOAEL
2,500 mg/kg
13 weeks
Acetone Ingestion skin | bone, teeth,
nails, and/or hair
Not classified Mouse NOAEL
11,298
mg/kg/day
13 weeks
Isopentane Inhalation peripheral nervous
system
Not classified Human NOAEL Not
available
occupational
exposure
Isopentane Inhalation heart | skin |
endocrine system |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system
Not classified Rat NOAEL 20
mg/l
13 weeks
Isopentane Ingestion kidney and/or
bladder
Not classified Rat NOAEL
2,000
mg/kg/day
28 days
Heptane Inhalation liver | nervous
system | kidney
and/or bladder
Not classified Rat NOAEL 12
mg/l
26 weeks
Toluene Inhalation auditory system |
eyes | olfactory
system
Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
poisoning
and/or abuse
Toluene Inhalation nervous system May cause damage to organs
though prolonged or repeated
exposure
Human NOAEL Not
available
poisoning
and/or abuse
Toluene Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 2.3
mg/l
15 months
Toluene Inhalation heart | liver | kidney
and/or bladder
Not classified Rat NOAEL 11.3
mg/l
15 weeks
Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1
mg/l
4 weeks
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Toluene Inhalation immune system Not classified Mouse NOAEL Not
available
20 days
Toluene Inhalation bone, teeth, nails,
and/or hair
Not classified Mouse NOAEL 1.1
mg/l
8 weeks
Toluene Inhalation hematopoietic
system | vascular
system
Not classified Human NOAEL Not
available
occupational
exposure
Toluene Inhalation gastrointestinal tract Not classified Multiple
animal
species
NOAEL 11.3
mg/l
15 weeks
Toluene Ingestion nervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 625
mg/kg/day
13 weeks
Toluene Ingestion heart Not classified Rat NOAEL
2,500
mg/kg/day
13 weeks
Toluene Ingestion liver | kidney and/or
bladder
Not classified Multiple
animal
species
NOAEL
2,500
mg/kg/day
13 weeks
Toluene Ingestion hematopoietic
system
Not classified Mouse NOAEL 600
mg/kg/day
14 days
Toluene Ingestion endocrine system Not classified Mouse NOAEL 105
mg/kg/day
28 days
Toluene Ingestion immune system Not classified Mouse NOAEL 105
mg/kg/day
4 weeks
Talc Inhalation pneumoconiosis Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational
exposure
Talc Inhalation pulmonary fibrosis |
respiratory system
Not classified Rat NOAEL 18
mg/m3
113 weeks
Methylene Chloride Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 6.95
mg/l
2 years
Methylene Chloride Inhalation liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 0.17
mg/l
2 years
Methylene Chloride Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
LOAEL 35
mg/l
8 weeks
Methylene Chloride Inhalation heart Not classified Human NOAEL Not
available
Methylene Chloride Inhalation immune system Not classified Rat NOAEL 18
mg/l
28 days
Methylene Chloride Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL
1,200
mg/kg/day
3 months
Methylene Chloride Ingestion blood Not classified Rat NOAEL 249
mg/kg/day
2 years
Methylene Chloride Ingestion kidney and/or
bladder
Not classified Rat NOAEL
1,469
mg/kg/day
3 months
Methylene Chloride Ingestion eyes Not classified Rat NOAEL 249
mg/kg/day
104 weeks
Aspiration Hazard
Name Value
Pentane Aspiration hazard
Isopentane Aspiration hazard
Heptane Aspiration hazard
Cyclopentane Aspiration hazard
Toluene Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
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Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact manufacturer for more information

EPCRA 311/312 Hazard Classifications:
Physical Hazards
Flammable (gases, aerosols, liquids, or solids)
Health Hazards
Hazard Not Otherwise Classified (HNOC)
Reproductive toxicity
Simple Asphyxiant
Specific target organ toxicity (single or repeated exposure)
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable)C.A.S. No Regulation Status
Methylene Chloride 75-09-2 Toxic Substances Control Act (TSCA) 6
Banned or Restricted Use Chemicals
Applicable

Additional TSCA Information
Components CAS No Additional Information
Methylene Chloride 75-09-2 This chemical/product is not and cannot be distributed in
commerce (as defined in TSCA section 3(5)) or processed (as
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defined in TSCA section 3(13)) for consumer paint or coating
removal.
15.2. State Regulations
Contact manufacturer for more information

15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact manufacturer for more information
15.4. International Regulations
Contact manufacturer for more information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 1 Flammability: 4 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group:30-7214-7 Version Number:8.00
Issue Date:08/27/21 Supercedes Date:07/16/21
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
Z Guard ™ 20060B-2 OR
page 1 of 14 :

This Safety Data Sheet (SDS) has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (CFR 29 1910.1200).US

GHS product identifier Z Guard ™ 20060B-2
Synonyms Black Undercoating
Material uses Coating to Protect Semi-Trailers

Updated January 22, 2019

Supplier's details Z Technologies Corp.
26500 Capitol Ave.
Redford, MI 48239 USA 3132
www.ztechprotection.com

Emergency telephone [phone] Medical Emergency
number
For chemical emergency, spill, leak, fire, exposure
or accident: call CHEMTREC day or night.
24 Hour Emergency Contact: PERS 1-800-633 8253 PERS Customer # 10971
The emergency telephone number is to be used only in the event of a chemical
emergency involving a spill, leak, fire, exposure, or accident

OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).
Classification of the FLAMMABLE LIQUIDS - Category 2
Substance or mixture ACUTE TOXICITY: INHALATION - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Narcotic effects] -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) [central nervous
system (CNS)] - Category 2
ASPIRATION HAZARD - Category 1

GHS label elements
Hazard pictograms

Signal word Danger
Hazard statements Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May be fatal if swallowed and enters airways. May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure. (central nervous system
(CNS))

Section 2. Hazards identification
Section 1. Identification

Z Guard ™ 20060B-2 OR
page 2 of 14 Version :

Section 2. Hazards identification
Precautionary statements
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and
understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or
face protection. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use
explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container tightly closed.
Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after
handling.
Response Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF
INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON
CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and
water. Take off contaminated clothing. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazards not otherwise SKIN INJECTION HAZARD
classified
Spray from an airless spray tip, airless hose leaks or ruptured airless components can inject
fluid into your body and cause extremely serious injury, including the need for amputation.
Fluid injected into the skin might look like just a cut, but it is a serious injury. Get immediate
surgical attention.

Substance/mixture STODDARD SOLVENT (Mineral Spirits) Acetone (2 Propanone; Di methyl ketone)

Other means of Low boiling point naphtha - unspecified; Low aromatic hydrocarbon solvents - medium
identification flashpoint.; Petroleum distillates; mineral spirits; White spirits; Stoddard Solvent; Solvent Naphthas;
Petroleum hydrocarbon solvent;
CAS number/other identifiers
CAS number Stoddard Solvent 8052-41-3 13.1% by weight in coating
Acetone 67-64-1 4.1% by weight in coating

* - Various ** - Mixture *** - Proprietary
Any concentration shown as a range is due to process variation.
Occupational exposure limits, if available, are listed in Section 8.

Description of necessary first aid measures
Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Ingredient name % CAS number
C9-C15 Cycloalkanes 8.1 **
Acetone 4.1 67-64-1
C9-C15 Alkanes 3.7 **
C9-C15 1.2 **
Section 4. First aid measures
Section 3. Composition/Information on ingredients
Z Guard ™ 20060B-2 OR
page 3 of 14 Version :

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not
breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt
or waistband

Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to
rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes
thoroughly before reuse.

Ingestion Get medical attention immediately. Call a poison center or physician. Wash out mouth with water.
Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce
vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
Never give anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.

Most important symptoms/effects, acute Potential acute health effects
Eye contact Causes serious eye irritation.
Inhalation Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness
and dizziness.
Skin contact Causes skin irritation.
Ingestion Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
Irritating to mouth, throat and stomach.

Over-exposure signs/symptoms
Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness

Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

Skin contact Adverse symptoms may include the following:
irritation
redness

Ingestion Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician If ingested, this material presents a significant aspiration and chemical pneumonitis hazard.
Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If
patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body
in a Trendelenburg and left lateral decubitus position.

Specific treatments Treat symptomatically and supportively.

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that
gas or vapor is still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus.

See toxicological information (Section 11)

Section 4. First aid measures
Z Guard ™ 20060B-2 OR
page 4 of 14 Version :

Specific hazards Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the
arising from the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier
chemical than air and will spread along the ground. Vapors may accumulate in low or confined areas
o r travel a considerable distance to a source of ignition and flash back. Runoff to sewer
may create fire or explosion hazard.

Extinguishing media
Suitable extinguishing Use dry chemical, C02, water spray (fog) or foam.
media

Unsuitable extinguishing Do not use water jet.
media

Hazardous thermal Decomposition products may include the following materials:
decomposition carbon dioxide
products carbon monoxide

Special protective Promptly isolate the scene by removing all persons from the vicinity of the incident if there is
actions for fire-fighters a fire. No action shall be taken involving any personal risk or without suitable training. Move
containers from fire area if this can be done without risk. Use water spray to keep fire-exposed
containers cool.

Special protective Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire- breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
fighters

Personal precautions, protective equipment and emergency procedures

For non-emergency No action shall be taken involving any personal risk or without suitable training. Evacuate
Personnel surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or
walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard
area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency If specialized clothing is required to deal with the spillage, take note of any information in
responders Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel"

Environmental Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
Precautions and sewers. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill Stop leak if without risk. Move containers from spill area. Use s park-proof tools and explosion-proof
equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb
with an inert dry material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.

large spill Stop leak if without risk. Move containers from spill area. Use spark -proof tools and explosion-proof
equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or
confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulat ions (see Section
13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may
pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information
and Section 13 for waste disposal.

Section 6. Accidental release measures
Section 5. Fire-fighting measures
Z Guard ™ 20060B-2 OR
page 5 of 14 Version :

Precautions for safe handling

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special
instructions before use. Do not handle until all safety precautions have been read and understood.
Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter
storage areas and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in use. Store and
use away from heat, sparks, open flame or any other ignition source. Use explosion -proof electrical
(ventilating, lighting and material handling) equipment. Us e only non-sparking tools. Take
precautionary measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous: and can fatally explode if welded! Non equilibrium conditions may
increase the fire hazard associated with this product.
Always bond receiving containers to the fill pipe before and during loading. Always confirm that
receiving container is properly grounded. Bonding and grounding alone may be inadequate to
eliminate fire and explosion hazards. Carefully review operations that may increase the risks such as
tank and container filling, tank cleaning, sampling, gauging, loading, filtering, mixing, agitation, etc. In
addition to bonding and grounding, efforts to mitigate the hazards may include, but are not limited to,
ventilation, inerting and/or reduction of transfer velocities.
Always keep nozzle in contact with the container throughout the loading process. Do NOT fill any
portable container in or on a vehicle.

Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and
smoking. Remove contaminated clothing and protective equipment before entering eating areas.
See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area. Store in
including any original container protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for
use. Containers that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.

Bulk Storage Conditions: Maintain all storage tanks in accordance with applicable regulations. Use
necessary controls to monitor tank inventories. Inspect all storage tanks on a periodic basis. Test
tanks and associated piping for tightness. Maintain the automatic leak detection devices to assure
proper working condition.

Control parameters Occupational exposure limits
Ingredient name Exposure limits
C9-C15 Cycloalkanes
C9-C15 Aromatics
Nonane, all isomer
ACGIH TlV (United States).
TWA: 400 ppm 8 hours. Form: Methylcyclohexane
ACGIH TlV (United States).
TWA: 400 ppm 8 hours. Form: (Methylcyclohexane)
ACGIH TlV (United States, 4/2014).
TWA: 200 ppm 8 hours.
TWA: 1050 mg/m3 8 hours.

Component ACGIH TLV OSHA PEL NIOSH IDLH
Acetone TWA: 500 ppm
STEL: 750 ppm
(Vacated) TWA: 750 ppm
(Vacated) TWA: 1800 mg/m3
(Vacated) STEL: 2400 mg/m3
(Vacated) STEL: 1000 ppm
TWA: 1000 ppm
TWA: 2400 mg/m3
IDLH: 2500 ppm
TWA: 250 ppm
TWA: 590 mg/m3

Section 8. Exposure controls/personal protection
Section 7. Handling and storage
Z Guard ™ 20060B-2 OR
page 6 of 14 Version :

Component Quebec Mexico OEL (TWA) Ontario TWAEV
Acetone TWA: 500 ppm
TWA: 1190 mg/m3
STEL: 1000 ppm
STEL: 2380 mg/m3
TWA: 1000 ppm
TWA: 2400 mg/m3
STEL: 1260 ppm
STEL: 3000 mg/m3
TWA: 500 ppm
STEL: 750 ppm
Legend

ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health

Appropriate engineering Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other
Controls engineering controls to keep worker exposure to airborne contaminants below any recommended or
statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below
any lower explosive limits. Use explosion-proof ventilation equipment.

Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they comply
Controls with the requirements of environmental protection legislation. In some cases, vapor controls, filters
or engineering modifications to the process equipment will be necessary to reduce emissions to
acceptable levels.

Individual protection measures
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking
and using the lavatory and at the end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location.

Eye/face protection Safety glasses equipped with side shields are recommended as minimum protection in industrial
settings. If contact is possible, the following protection should be worn, unless the assessment
indicates a higher degree of protection: Splash goggles. Safety eyewear complying with an
approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts. chemical splash goggles. If inhalation hazards
exist, a full-face respirator may be required instead.

Skin protection
Hand protection Chemical-resistant gloves complying with an approved standard should be worn at all times when
handling chemical products if a risk assessment indicates this is necessary. Considering the
parameters specified by the glove manufacturer, check during use that the gloves are still retaining
their protective properties. It should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers.

Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling this product.

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the
task being performed and the risks involved and should be approved by a specialist before handling
this product.

Respiratory protection Use a properly fitted, air-purifying or supplied-air respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the selected
respirator.
Physical state Liquid. [Syrupy liquid.]

Color Black.

Odor Characteristic hydrocarbon solvent odor.

(less than ½% alcohol, present in this composition, is detectable by smell)

Section 9. Physical and chemical properties
Section 8. Exposure controls/personal protection
Z Guard ™ 20060B-2 OR
page 7 of 14 Version :

ph Not available Boiling point/boiling range 157 to 218°C (314.6 to 424.4°F) Flash point Closed cup: 20°C (-4°F) [Tagliabue (ASTM D-56)] Evaporation rate Not determined Lower and upper explosive Lower: 2.5 vol% (flammable) limits Upper: vol 12.8% Vapor pressure not determined Vapor density not determined Density lbs/gal 11.6 lbs/gal Solubility Very slightly soluble in the following materials: cold water. Auto-ignition temperature 230 to 240°C (446 to 464°F)

V.O.C. lb/gal (less acetone) 1.5

VOC less weight of exempt 1.9
Solvents per volume of non
exempt liquid
Reactivity Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US
GHS Definition(s).

Chemical stability The product is stable.

Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill,
grind or expose containers to heat or sources of ignition. Fatal explosion can occur upon welding
empty container! Do not allow vapor to accumulate in low or confined areas.

Incompatible materials Reactive or incompatible with the following materials:
oxidizing materials

Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should not be
products produced.

Acute toxicity
Product/ingredient
name Result Species Dose Exposure
Nonane, all isomers LC50 Inhalation Gas. Rat 3200 ppm 4 hours

Component LD50 Oral LD50 Dermal LC50 Inhalation
Acetone 5800 mg/kg ( Rat ) > 15800 mg/kg (rabbit)
> 7400 mg/kg (rat)
76 mg/l, 4 h, (rat)

Conclusion/Summary C9-C15 Alkanes: In animal studies utilizing mineral spirits containing up to 22% aromatics indicated
that the acute central nervous system effects are reversible. Based on existing animal studies, the
potential for persistent effects is not clear.

Section 11. Toxicological information
Section 10. Stability and reactivity
Section 9. Physical and chemical properties
Z Guard ™ 20060B-2 OR
page 8 of 14 Version :

Irritation/Corrosion
Product/ingredient
name Result Species Score Exposure Observation
C9-C15 Aromatics Skin - Mild irritant Rabbit - 24 hours 500
microliters -
Nonane, all isomers Skin - Mild irritant Pig - 24 hours 250
microliters -
Skin - Moderate
irritant Rat - 96 hours 300
microliters -

Skin C9-C15 Alkanes: Primary dermal irritation studies (four hour exposure) in rabbits utilizing mineral
spirits containing less than 2% aromatics resulted in slight to moderate skin irritation. In humans,
mineral spirits have produced slight to moderate skin irritation particularly with evaporation from the
skin is prevented.

Eyes No additional information.

Respiratory C9-C15 Alkanes: Animal studies have demonstrated that mineral spirits produced mild respiratory
tract irritation at elevated concentrations. Also, sensory respiratory tract irritation was evident by
reduced breathing rates in the test animals in certain studies.

Sensitization
Skin C9-C15 Alkanes: In animal studies utilizing mineral spirits containing up to 18%, aromatics skin
sensitization is not evident.

Respiratory No additional information.

Mutagenicity
Conclusion/Summary C9-C15 Alkanes: In vivo and in vitro studies on mineral spirits containing up to 22 % aromatics
indicate that these products are not genotoxic

Carcinogenicity
Conclusion/Summary C9-C15 Alkanes: The National Toxicology Program (NTP) conducted two-year carcinogenicity
studies in rats and mice with Stoddard Solvent IIC (less than 2% aromatics). The studies indicated
that there was some evidence of carcinogenic activity in male rats (adrenal medulla neoplasms and
renal tubule adenoma) but no evidence of carcinogenic activity in female rats. Further, there was
equivocal evidence of carcinogenic activity in female mice (hepatocellular adenoma) but no evidence
of carcinogenic activity in male mice. A low carcinogenic potential is suggested by a lack of genotoxic
potential identified in in vivo and in vitro genetic toxicity tests (with and without metabolic activation).

Acetone The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component CAS-No IARC NTP ACGIH OSHA Mexico
Acetone 67-64-1 Not listed Not listed Not listed Not listed Not listed

Classification Reproductive toxicity
Conclusion/Summary C9-C15 Alkanes: There were no treatment-related effects on pregnancy rate, mortality or gross Post
mortem observations in animals studies utilizing mineral spirits containing less than 2% Aromatics.

Teratogenicity
Conclusion/Summary C9-C15 Alkanes: There were no treatment-related effects on pregnancy rate, mortality or gross post
mortem observations in animal studies utilizing mineral spirits containing less than 2% aromatics.

Section 11. Toxicological information
Z Guard ™ 20060B-2 OR
page 9 of 14 Version :

Specific target organ toxicity (single exposure)

Name Category Route of
exposure
Target organs
C9-C15 Cycloalkanes Category 3 Not applicable. Narcotic effects
C9-C15 Alkanes Category 3 Not applicable. Narcotic effects
C9-C15 Aromatics Category 3 Not applicable. Narcotic effects
Nonane, all isomers Category 3 Not applicable. Narcotic effects

Aspiration hazard

Name Result
C9-C15 Cycloalkanes ASPIRATION HAZARD - Category 1
C9-C15 Alkanes ASPIRATION HAZARD - Category 1
C9-C15 Aromatics ASPIRATION HAZARD - Category 1
Nonane, all isomers ASPIRATION HAZARD - Category 1

Information on the likely Routes of entry anticipated: Oral, Dermal, Inhalation.
routes of exposure

Potential acute health effects
Eye contact Causes serious eye irritation.

Inhalation Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness
and dizziness.

Skin contact Causes skin irritation.

Ingestion Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics
Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness

Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

Skin contact Adverse symptoms may include the following:
irritation
redness

Ingestion Adverse symptoms may include the following:
nausea or
vomiting

Potential chronic health effects
General May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity Some aromatic impurities at concentrations below threshold of reporting are suspected of causing
cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity No known significant effects or critical hazards.

Section 11. Toxicological information
Z Guard ™ 20060B-2 OR
page 10 of 14 Version :

Teratogenicity No known significant effects or critical hazards.

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.
Toxicity
Eco toxicity
Component Freshwater Algae Freshwater Fish Microtox Water Flea
Acetone NOEC = 430 mg/l (algae; 96 h) Oncorhynchus mykiss: LC50
= 5540 mg/l 96h
Alburnus alburnus: LC50 =
11000 mg/l 96h
Leuciscus idus: LC50 =
11300 mg/L/48h
Salmo gairdneri: LC50 =
6100 mg/L/24h
EC50 = 14500 mg/L/15 min EC50 = 8800 mg/L/48h
EC50 = 12700 mg/L/48h
EC50 = 12600 mg/L/48h

Conclusion/Summary Not available.

Persistence and degradability
Conclusion/Summary Not available.

Bioaccumulative potential

Product/ingredient name logPow BCF Potential
C9-C15 Aromatics 2.8 to 6.5 99 to 5780 high
Nonane, all isomers 5.65 105 low
Acetone -0.24

Mobility in soil
Soil/water partition \ Not available
coefficient (KOC)

Other adverse effects No known significant effects or critical hazards.

Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction. Waste packaging should be recycled. This material and its container
must be disposed of in a safe way. Care should be taken when handling emptied containers that
have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers: a fatal explosion may occur.. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

RCRA classification Stoddard Solvent: D001, D018 Acetone U002

Section 13. Disposal considerations
Section 12. Ecological information
Section 11. Toxicological information
Z Guard ™ 20060B-2 OR
page 11 of 14 Version :

DOT Classification IMDG IATA
UN number UN1268 UN1268 UN1268
UN proper
shipping name
UN1268, Petroleum Distillates,
n.o.s. (Stoddard Solvent), 3, PG lII
UN1268, Petroleum Distillates,
n.o.s. (Stoddard Solvent), 3, PG II
UN1268, Petroleum Distillates, n.o.s.
(Stoddard Solvent), 3, PG II
Transport
hazard class(es)
3 3 3
Packing group ll ll ll
Environmental
hazards
No Yes No
Additional
information
No additional remark

Special precautions for user Transport within user's premises always transport in closed containers that are upright and
secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.

U.S. Federal regulations TSCA 12(b) one-time export: Nonane, all isomers
United States inventory (TSCA 8b): All components are listed or exempted.
CERCLA Hazardous Substance List (40 CFR 302.4): Acetone Reportable quantity: 5000 lbs.
Clean Water Act (CWA) 307: Naphthalene
Clean Water Act (CWA) 311: Naphthalene;
This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil
Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the
United States, their adjoining shorelines, or into conduits leading to surface waters must be reported
to the EPA's National Response Center at [phone].

SARA 302/304
Composition/information on ingredients

S ARA 304 RQ Not applicable.

SARA 311/312
Classification Fire hazard

Immediate (acute) health hazard
Delayed (chronic) health hazard

Composition/information on ingredients

Name Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
C9-C15 Cycloalkanes Yes. No. No. Yes. No. C9-C15 Alkanes Yes. No. No. Yes. No.
C9-C15 Aromatics Yes. No. No. Yes. No.
Nonane, all isomers Yes. No. No. Yes. No.

Section 15. Regulatory information
Section 14. Transport information
Z Guard ™ 20060B-2 OR
page 12 of 14 Version :

SARA 313

Product name CAS number %
Form R - Reporting
requirements
None present in regulated quantities
Supplier notification
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

State regulations
Massachusetts The following components are listed: STODDARD SOLVENT
New Jersey The following components are listed: STODDARD SOLVENT
Pennsylvania The following components are listed: STODDARD SOLVENT

International regulations
International lists Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: All components are listed or exempted.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Taiwan inventory (CSNN): Not determined.

Canada inventory All components are listed or exempted.
EU Inventory All components are listed or exempted.

Other International Regulations
Mexico - Grade Serious risk, Grade 3

Canada This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the information required by the CPR

WHMIS Hazard Class B2 Flammable liquid
D2B Toxic Materials

Section 15. Regulatory information
Z Guard ™ 20060B-2 OR
page 13 of 14 Version :

National Fire Protection Association (U.S.A.)

3 Flammability
Health 1 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright
©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official
position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in
its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted
and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is
referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.

History
Date of issue/Date of May 29, 2015 ATE -
revision

Key to abbreviations Acute Toxicity Estimate
BCF - Bioconcentration Factor
GHS - Globally Harmonized System of Classification and Labelling of Chemicals
IATA - International Air Transport Association
IBC - Intermediate Bulk Container
IMDG - International Maritime Dangerous Goods
LogPow - logarithm of the octanol/water partition coefficient
MARPOL 73/78 - International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" - marine pollution)
UN - United Nations\

Section 16. Other information
Z Guard ™ 20060B-2 OR
page 14 of 14 Version :

Z GUARD ™ IS A REGISTERED TRADEMARK OF Z TECHNOLOGIES CORPORATION.
Z Technologies Corporation Inc. Safety Data Sheet

For Additional Information contact MSDS Coordinator during business hours, EST time:( 313) 9370710
Notice
Z Technologies Corporation Inc. (”Z Tech”) expressly disclaims all express or implied warranties of merchantability and
fitness for a particular purpose, with respect to the product or information provided herein, and shall under no
circumstances be liable for incidental or consequential damages.

All information appearing herein is based upon data obtained from the manufacturers and/or recognized technical
sources. While the information is believed to be accurate, Z Technologies makes no representations as to its accuracy or
sufficiency. Conditions of use are beyond Z Tech’s control and therefore users are responsible to verify this data under
their own operating conditions to determine whether the product is suitable for their particular purposes and they assume
all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information
contained herein.

This information relates only to the product designated herein, and does not relate to its use in combination with any other
material or in any other process.

END OF SDS

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : PARABOND® SIGNATURE SERIES 4094
Product code : 100000010878
Manufacturer or supplier's details
Company : H.B. Fuller Construction Products

Address : 1105 South Frontenac
Aurora, IL, 60504
Telephone : [phone]

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Adhesive

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance liquid
Color white
Odor characteristic

GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Potential Health Effects

Carcinogenicity:
IARC No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
kaolin 1332-58-7 20 - 30
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.

If inhaled : Move to fresh air in case of accidental inhalation of vapors or
decomposition products.

In case of skin contact : Wash off with soap and water.
Get medical attention if irritation develops and persists.

In case of eye contact : Flush eyes with water at least 15 minutes. Get medical
attention if eye irritation develops or persists.

If swallowed : If conscious, drink plenty of water.
Never give anything by mouth to an unconscious person.
Consult a physician if necessary.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Unsuitable extinguishing
media
: None known.

Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

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SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Prevent product from entering drains.
Should not be released into the environment.

Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
Shovel into suitable container for disposal.

SECTION 7. HANDLING AND STORAGE

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Use only with adequate ventilation/personal protection.
Keep container closed when not in use.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
kaolin 1332-58-7 TWA
(Respirable
particulate
matter)
2 mg/m3 ACGIH
TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA (Total) 10 mg/m3 OSHA P0
TWA 5 mg/m3 OSHA P0

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(Respirable
fraction)
TWA (Total
dust)
10 mg/m3 OSHA P0
TWA
(respirable
dust fraction)
5 mg/m3 OSHA P0

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Organic vapor Type

Hand protection
Material : Nitrile rubber

Eye protection : Safety glasses with side-shields

Skin and body protection : Skin should be washed after contact.

Protective measures : Avoid contact with skin.

Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : white
Odor : characteristic
Odor Threshold : no data available
pH : is not determined
9.3 - 9.6
: is not determined
: is not determined
Flash point : is not determined
Evaporation rate : is not determined
Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined

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Density : 9 lb/gal
Solubility(ies)
Water solubility : is not determined
Partition coefficient: n-
octanol/water
: no data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined
VOC, less water, in g/l : < 1

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: No decomposition if stored and applied as directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available

Print Date
07/13/2022
Page 6 of 8
SAFETY DATA SHEET

PARABOND® SIGNATURE SERIES 4094
Version 1.1 Revision Date 07/13/2022

6 / 8

STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

No data available
Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of together with household waste.
The hazard and precautionary statements displayed on the
label also apply to any residues left in the container.Do not
dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good

Print Date
07/13/2022
Page 7 of 8
SAFETY DATA SHEET

PARABOND® SIGNATURE SERIES 4094
Version 1.1 Revision Date 07/13/2022

7 / 8

IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : No SARA Hazards

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).

US State Regulations
California Prop 65 Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AIIC (Australia), NZIoC (New
Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV (Taiwan)

SECTION 16. OTHER INFORMATION

Prepared by: Global Regulatory Office - phone: [phone] - email: [e-mail]

Print Date
07/13/2022
Page 8 of 8
SAFETY DATA SHEET

PARABOND® SIGNATURE SERIES 4094
Version 1.1 Revision Date 07/13/2022

8 / 8

Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, th e H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

Flammability

He
a
l
t
h

In
s
t
a
b
i
l
i
t
y

0
1
0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1

0

0

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Safety Data Sheet
Product Name: Z Shield ® 7800HG ID: AB012 V3
Page 1 of 10
SDS

Product Trade Name: Z SHIELD® 7800 High Gloss Protective Coating
Revised Aug 01 2019

Manufacturer Information
Z Technologies Corporation For Chemical Emergency; Spill, Leak, Fire, Exposure, or Accident:
Call PERS Day or Night within USA and CANADA:
PERS 1-800-633-8253
Outside USA and CANADA: 1-801-629-0667
PERS Customer # 10971
Contact Phone: [phone]
Redford, MI 48239 USA
Contact Phone: [phone]

Emergency Overview: WARNING! - Contact with this material may cause irritation to the skin, eyes and mucous membranes.
Eye Contact: This product is irritating to the eyes.
Skin Contact: This product may irritate the skin. Contact with the skin or mucous membranes may cause irritation. A component in the product may induce skin sanitization.
Skin Absorption: A component of this product may be absorbed through the skin.
Ingestion: This product may cause irritation to the throat, esophagus, and gastrointestinal tract if it is swallowed.
Inhalation: Inhalation of dusts or mists of this product may cause irritation to the nasal passages and respiratory tract.
Medical Conditions Aggravated by Exposure: Pre-existing eye, skin, gastrointestinal and respiratory disorders may be aggravated by exposure.

* * * Section 1 - Chemical Product and Company Identification * * *
* * * Section 2 - Hazards Identification * * *
Safety Data Sheet
Product Name: Z Shield ® 7800HG ID: AB012 V3
Page 2 of 10
SDS

Description
CAS# % BY
WT
FLASH
POINT
(TCC)

VM&P NAPTHA 64742 49
0 45.2 69 F
ACETONE 67 64 1 11.0 2 F
STODDARD
SOLVENT
8052 41
3

0.6

˃ 110 F Additional Information: This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

Eye Contact: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Do not wear contact lenses when working with any chemicals.
Skin Contact: If this chemical contacts the skin wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing and wash the skin with water. If symptoms occur after washing, get medical attention immediately.
Ingestion: If this chemical has been swallowed, get medical attention immediately. Give victim several glasses of water to drink. Vomiting may occur spontaneously; do not induce vomiting. Do not give anything by mouth to an unconscious person.
Inhalation: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing difficulty persists or develops, get prompt medical attention.
First Aid: Notes to Physician No additional information is available.
* * * Section 3 - Composition / Information on Ingredients * * *
* * * Section 4 - First Aid Measures * * *
Page 3 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

Auto Ignition, F (C ): >770(>410)
Flash Point,F(C ): 2 F (-16C) Upper Flammable Limit
(UFL):
Not applicable
Flammability
Classification:
Flammable Lower Flammable Limit
(LFL):
Not applicable

Fire & Explosion Hazards: Unknown.
Decomposition Products: Upon decomposition, this product emits carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, toxic nitrogen oxide (NOx) fumes and/or toxic sulfur oxide (SOx) fumes.
Extinguishing Media: Use dry chemical, foam, carbon dioxide, and/or water fog.
Fire-Fighting Instructions: Firefighters: Wear full protective clothing including self-contained breathing apparatus. Properly decontaminate all equipment after use.

Containment and Clean up procedures must be conducted in accordance with all local, state,
and federal regulations.

Containment Procedures: Stop the flow of material, if this can be done without risk. Wear appropriate protective equipment and clothing during clean up.
Clean-Up Procedures: Absorb spill with inert material and transfer material into appropriate container(s) for disposal. Dispose of collected material according to local, state, and federal regulations
* * * Section 5 - Fire Fighting Measures * * *
* * * Section 6 - Accidental Release Measures * * *
Page 4 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

Handling Procedures: Wear appropriate personal protective clothing to prevent eye and skin contact. Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of this product. Use with adequate ventilation. This product is for industrial use only. Do not take internally.
Storage Procedures: Freezing damages this product. Keep container tightly closed when not in use. Store in a cool, well-ventilated area away from incompatible materials.

Exposure Guidelines:
A: General Product Information Follow all applicable exposure limits. Keep formation of airborne mists to a minimum.
B: Component Exposure Limits
TOXICITY EXPOSURE CONTROLS

INGREDIENT

CAS#
%
BY
WT
LD 50
Mg/Kg LC50 TWA
(OSHA)
TLV
(ACGIH) STEL

VM&P
NAPTHA

64742
49 0
45.2 intra 40
Mg/Kg
mouse
INHAL/
RAT 3400
PPM/4H

500
ppm

300 ppm

ACETONE

67 64
1
11.0
ORAL
acute 5800
mg/Kg rat.
3000
Mg/Kg
mouse.
5340Mg/Kg
rabbit

VAPOR
acute 50100
Mg/m 8
hrs. Rat.
44000mg/m
4 hrs.

1000
ppm

500 ppm
A4

750 ppm
* * * Section 7 - Handling and Storage * * *
* * * Section 8 - Exposure Controls / Personal Protection * * *
Page 5 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

STODDARD
SOLVENT

8052
41 3

0.6 ˃ 6 mg/Kg
Rat
8500
mg/m3
4Hr. Rat
100
ppm

100 ppm

-

This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1%.
Engineering Controls: Set up ventilation to effectively remove and prevent buildup of any vapor or mist generated from the handling of this product.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Protective Equipment: Wear appropriate eye protection to prevent eye contact.
Skin Protection: Wear appropriate personal protective clothing to prevent skin contact. The worker should immediately wash the skin when it becomes contaminated.
Respiratory Protection: If ventilation is not sufficient to effectively prevent buildup of mists or vapors, provide appropriate NIOSH/MSHA respiratory protection.
Personal Protective Equipment: Provide eyewash fountains in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Provide facilities for quickly drenching the body within the immediate work area for emergency use where there is a possibility of exposure. Depending on the specific circumstances, a deluge shower, a sink or hose could be considered adequate.
Page 6 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

Physical State: Liquid Appearance: Black Liquid
Odor: Solvent Vapor Pressure: <10
Vapor Density: >1 Boiling Point: >347°F (175 °C)
Specific Gravity: 0.91 pH: NA
Viscosity: ND VOC coating¹ 3.4 lbs/gal ,( 416 g/L)
Solubility in Water: Not Miscible
VOC Material² 3.4 lbs/gal(412 g/L) Percent Solids
(by weight):
43 1. Also referred to as the regulatory VOC or the VOC less water and exempt compounds. 2. Also referred to as the actual VOC
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Avoid freezing. Keep away from incompatible materials.
Incompatibility: Do not expose this product to strong oxidizers.
Decomposition Products: Upon decomposition, this product emits carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, toxic sulfur oxide (SOx) fumes and/or nitrogen oxide (NOx) fumes.
Hazardous Polymerization: Will not occur.

Acute Toxicity:
A: General Product Information
TOXICITY EXPOSURE CONTROLS
TOXICITY EXPOSURE CONTROLS

INGREDIENT

CAS# % BY
WT
LD 50
Mg/Kg LC50 TWA
(OSHA)
TLV
(ACGIH) STEL

* * * Section 9 - Physical & Chemical Properties * * *
* * * Section 10 - Chemical Stability & Reactivity Information * * *
* * * Section 11 - Toxicological Information * * *
Page 7 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

VM&P
NAPTHA

64742
49 0

45.2
intra 40
Mg/Kg
mouse
INHAL/
RAT 3400
PPM/4H

500
ppm

300 ppm

ACETONE

67 64 1

11.0

ORAL
acute 5800
mg/Kg rat.
3000
Mg/Kg
mouse.
5340Mg/Kg
rabbit

VAPOR
acute 50100
Mg/m 8
hrs. Rat.
44000mg/m
4 hrs.

1000
ppm

500 ppm
A4

750
ppm

STODDARD
SOLVENT

8052
41 3

0.6 ˃ 6 mg/Kg
Rat
8500
mg/m3
4Hr. Rat
100
ppm

100 ppm

-

This product contains no
EPA Hazardous Air
Pollutants (HAP) in
amounts > 0.1%.

Carcinogenicity:
A: General Product Information No information is available for the product.
B: Component Carcinogenicity None of this product’s components are on IARC or NTP lists.
Chronic Toxicity No information is available for the product.
Other Toxicological Information: No information is available for the product.
* * * Section 12 - Ecological Information * * *
Page 8 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

Ecotoxicity:
A: General Product Information No data is available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components.
Environmental Fate: Product and solutions may be toxic to fish and wildlife. Do not discharge to natural waterways. Avoid contaminating public water supplies.
Wastes must be tested using methods described in 40 CFR Part 261. It is the generator’s responsibly to determine if the waste meets applicable definitions of hazardous wastes. State and local regulations may differ from Federal disposal regulations. Dispose of waste material according to Local, State, Federal and Provincial Environmental Regulations.

US DOT Information
Proper Shipping Name Petroleum Distillates nos Hazard Class 3 UN / NA Number 1268 Packing Group II Labels required FLAMMABLE LIQUID Placard FLAMMABLE LIQUID
* * * Section 13 - Disposal Considerations * * *
* * * Section 14 - Transportation Information * * *
Page 9 of 10
SDS
Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

US Federal Regulations
A: General Product Information No additional information is available.
B: Component Analysis None of this product’s components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).
SARA 311/312: Acute: no Chronic: No Fire: Yes Pressure: No Reactive: No
State Regulations
A: General Product Information No information is available.
B: Component Analysis - State None of this product's components are listed on the state lists from CA, FL, MA, MN, NJ, PA or RI.
Other Regulations
A: General Product Information All components are on the U.S. EPA TSCA Inventory List.
B: Component Analysis - WHMIS IDL No components are listed in the WHMIS IDL.
* * * Section 15 - Regulatory Information * * *
Page 10 of 10
SDS

Safety Data Sheet
Product Name: Z Shield ™ 7800HG ID: AB012 V1

NFPA Ratings: Health: 2 Fire: 2 Reactivity: 0 Other: Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
HMIS Ratings: Health: 2 Fire: 2 Reactivity: 0 Personal Protection: Hazard Scale: 0 = Minimal hazard 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic
Key/Legend:
ACGIH = American Conference of Governmental Industrial Hygienists NFPA = National Fire Protection Association CERCLA = Comprehensive Environmental Response, Compensation and Liability Act NIOSH = National Institute for Occupational Safety and Health EPA = Environmental Protection Agency NTP = National Toxicology Program HMIS = Hazardous Material Identification System OSHA = Occupational Safety and Health Administration IARC = International Agency for Research on Cancer SARA = Superfund Amendments and Reauthorization Act MSHA = Mine Safety and Health Administration TSCA = Toxic Substance Control Act
The information presented herein is believed to be factual as it has been derived from the works and opinions of persons believed to be qualified experts; however, nothing contained in this information is to be taken as a warranty or representation for which Z Technologies, Inc bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate.
Contact: Regulatory Affairs
Contact Phone: [phone]
* * * Section 16 – Other Information * * *
Page 1 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020
SAFETY DATA SHEET

This Safety Data Sheet conforms to ANSI Z400.5, and to the
format requirements of the Global Harmonizing System.
THIS SDS COMPLIES WITH 29 CFR 19 10.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this SDS before handling & disposing of this product.
Pass this information on to employees, customers, & users of this product.

SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER

PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER
PRODUCT USES: Acrylic Lacquer Thinner

COMPANY IDENTITY: T C I Products Company
COMPANY ADDRESS: 420 E Desoto
COMPANY CITY: St.Louis, MO 63147
COMPANY PHONE: [phone]
EMERGENCY PHONES: CHEMTREC: 1-800-424-9300 (USA)
CANUTEC: 1-613-996-6666 (CANADA)

SECTION 2. HAZARDS IDENTIFICATION

DANGER!!

2.1 HAZARD STATEMENTS: (CAT = Hazard Category)
(H200s) PHYSICAL: Flammable Liquids(CAT:1)
H224 EXTREMELY FLAMMABLE LIQUID AND VAPOR.
(H300s) HEALTH: Skin Corrosion/Irritati on(CAT:2)
H315 CAUSES SKIN IRRITATION.
(H300s) HEALTH: Serious Eye Damage/Eye Irritation(CAT:2)
H320 CAUSES EYE IRRIT ATION.
(H300s) HEALTH: Target Organ Toxicity, Single Exposure(CAT:3)
H335 MAY CAUSE RESPIRATORY IRRITATION.
H336 MAY CAUSE DROWSINESS OR DIZZINESS.

2.2 PRECAUTIONARY STATEMENTS:
EXPOSURE PREVENTION:
P100s = General, P200s = Prevention, P300s = Response, P400s = Storage, P500s = Disposal
P210 Keep away from heat/sparks/open flames/hot surfa ces -- No Smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion -proof electrical/ventilating/lighting equipment.
P242 Use only non -sparking tools.
P243 Take precautionary measures against st atic discharge.
P264 Wash with soap & water thoroughly after handling.
P271 Use only outdoors or in a well -ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+352 IF ON SKIN: Wash with soap & water.
P304+340 IF INHALED: Remove victim to fresh air & keep at rest in a position
comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses if present & easy to do - Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P337+313 If eye irritation persists, get medical advice/attention.
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.

SEE SECTIONS 8, 11 & 12 FOR TOXICOLOGICAL INFORMATION.

Page 2 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

MATERIAL CAS# EINECS# WT %
Acetone 67-64-1 200-662-2 75-85
Methyl Acetate 79-20-9 201-185-2 10-20

TRACE COMPONENTS: Trace ingredients (if any) are present in < 1% concentration,
(< 0.1% for potential carcinogens, reproductive toxins, respiratory tract mutagens,
and sensitizers). None of the trace ingredients contribute significant additional
hazards at the concentrations that may be present in this product. All pertinent hazard
information has been provided in this document, per the requirements of the Federal
Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State
equivalents, and Canadian Hazardous Materials Identification System Standard (CPR 4).

SECTION 4. FIRST AID MEASURES

4.1 MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE & CHRONIC:
See Section 11 for symptoms/effects, acute & chronic.

4.2 GENERAL ADVICE:
First Aid responders should pay attention to self -protection and use the recommended
protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists, refer to Section 8 for specific personal protective equipment.

4.3 EYE CONTACT:
If this product enters the eyes, check for and remove any contact lenses. Open eyes while
under gently running water. Use sufficient force to open eyelids. "Roll" eyes to e xpose
more surface. Minimum flushing is for 15 minutes. Seek immediate medical attention.

4.4 SKIN CONTACT:
If the product contaminates the skin, immediately begin decontamination with running
water. Minimum flushing is for 15 minutes. Remove contaminated clothing, tak ing care not
to contaminate eyes. If skin becomes irritated and irritation persists, medical attention
may be necessary. Wash contaminated clothing before reuse , discard contaminated shoes.

4.5 INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult, give
oxygen. If breathing has stopped, trained personnel should immediately begin artificial
respiration. If the heart has stopped, trained personnel should immediately begin
cardiopulmonary resuscitation (CPR). Seek immediate medical attention.

4.6 SWALLOWING:
If swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRE NT INFORMATION. If
professional advice is not available, give two glasses of water to drink. DO NOT INDUCE
VOMITING. Never induce vomiting or give liquids to someone who is unconscious, having
convulsions, or unable to swallow. Seek immediate medic al attention.

4.7 RESCUERS: Victims of chemical exposure must be taken for medical attention. Rescuers
should be taken for medical attention, if necessary. Take a copy of label and SDS to
physician or health professional with victim.

4.8 NOTES TO PHYSICIAN:
There is no specific antidote. Treatment of overexposure should be directed at the control
of symptoms and the clinical condition of the patient. Any material aspirated during
vomiting may cause lung injury. Therefore, emesis should not be in duced mechanically or
pharmacologically. If it is considered necessary to evacuate the stomach contents, this
should be done by means least likely to cause aspiration (such as: Gastric lavage after
endotracheal intubation).

SECTION 5. FIRE FIGHTING MEASURES

5.1 FIRE & EXPLOSION PREVENTIVE MEASURES:
NO open flames, NO sparks, & NO smoking. Use a closed system, ventilatio n,
explosion-proof electrical equipment, lighting.
Do NOT use compressed air for filling, discharging, or handling.

5.2 SUITABLE (& UNSUITABLE) EXTINGUISHING MEDIA:
Use dry powder, carbon dioxide.

Page 3 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 5. FIRE FIGHTING MEASURES (CONTINUED)

5.3 SPECIAL PROTECTIVE EQUIPMENT & PRECAUTIONS FOR FIRE FIGHTERS:
Water spray may be ineffective on fire but can protect fire-fighters
& cool closed containers. Use fog nozzles if water is used.
Do not enter confined fire -space without full bunker gear.
(Helmet with face shi eld, bunker coats, gloves & rubber boots).

5.4 SPECIFIC HAZARDS OF CHEMICAL & HAZARDOUS COMBUSTION PRODUCTS:
EXTREMELY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions!

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 SPILL AND LEAK RESPONSE AND ENVIRONMENTAL PRECAUTIONS:
Uncontrolled releases should be responded to by trained personnel using pre -planned
procedures. Proper protective equipment should be used. In case of a spill, clear the
affected area, protect people, and respond with trained personnel. ELIMINATE all
ignition sources (no smoking, flares, sparks, or flames in immediate area).

6.2 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, EMERGENCY PROCEDURES :
The proper personal protective equipment for incidental releases (such as: 1 Liter of the
product released in a well -ventilated area), use impermeable gloves, they should be Level
B: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant
suit and boots, hard-hat, and Self-Contained Breathing Apparatus specific for the material
handled, goggles, face shield, and appropriate body protection. In the event of a lar ge
release, use impermeable gloves, specific for the material handled, chemically resistant
suit and boots, and hard hat. Self -Contained Breathing Apparatus or respirator may be
required where engineering controls are not adequate or conditions for p otential exposure
exist. When respirators are required, select NIOSH/MSHA approved based on actual or
potential airborne concentrations in accordance with latest OSHA and/or ANSI
recommendations.

6.3 ENVIRONMENTAL PRECAUTIONS:
Stop spill at source. Construct temporary dikes of dirt, sand, or any appropriate readily
available material to preve nt spreading of the material. Close or cap valves and/or
block or plug hole in leaking container and transfer to another container. K eep from
entering storm sewers and ditches which lead to waterways , and if necessary, call the
local fire or police department for immediate emergency assistance.

6.4 METHODS AND MATERIAL FOR CONTAINMENT & CLEAN-UP:
Absorb spilled liquid with polypads or other suitable absorbent materials. If necessary,
neutralize using suitable buffering material, (acid with soda ash or base with phosphoric
acid), and test area with litmus paper to confirm neutralization. Clean up with
non-combustible absorbent (such as: sand, soil, and so on). Shovel up and place all spill
residue in suitable containers. dispose of at an appropriate waste disposal facility
according to current applicable laws and regulations and product characte ristics at time
of disposal (see Section 13 - Disposal Considerations).

SECTION 7. HANDLING AND STORAGE

7.1 PRECAUTIONS FOR SAFE HANDLING:
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Use only with adequate ventilation. Avoid breathing of vapor or spray mi st.
Avoid contact with skin & eyes. Wear OSHA Standard goggles or face shield. Consult Safety
Equipment Supplier. Wear goggles, face shield, gloves, apron & footwear impervious to
material. Wash clothing before reuse.
Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, saw,
drill, braze, or weld. Empty container very hazardous! Continue all label precautions!

7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
Vapors may ignite explosively & spread long distances. Prevent vapor buildup. Put out
pilot lights & turn off heaters, electric equipment & other ignition sources during use
& until all vapors are gone. strong oxidants. Do not store above 49 C/120 F.
Keep container tightly clos ed & upright when not in use to prevent leakage.

Page 4 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 7. HANDLING AND STORAGE (CONTINUED)

7.3 NONBULK: CONTAINERS:
Store containers in a cool, dry location, away from direct sunlight, sources of intense
heat, or where freezing is possible. Material should be stored in sec ondary containers or
in a diked area, as appropriate. Store containers away from incompatible chemicals (see
Section 10, Stability and Reactivity). Post warning and "NO SMOKING" signs in storage and
use areas, as appropriate. Empty containers should be handled with care. Never store food,
feed, or drinking water in containers which held this product.

7.4 BULK CONTAINERS:
All tanks and pipelines which contain this material must be labeled. Perform routine
maintenance on tanks or pipelines which contain this product. Report all leaks immediately
to the proper personnel.

7.5 TANK CAR SHIPMENTS:
Tank cars carrying this product should be loaded and unloaded in strict accordance with
tank-car manufacturer's recommendation and all established on-site safety procedures.
Appropriate personal protective equipment must be used (see Section 8, Engineering
Controls and Personal Protective Equipment.). All loading and unloading equipment must be
inspected, prior to each use. Loading and unloading operations must be attended, at all
times. Tank cars must be level, brakes must be set or wheels must be locked or blocked
prior to loading or unloading. Tank car (for loading) or storage tanks (for unloading)
must be verified to be correct for receiving this product and be properly prepared,
prior to starting the transfer operations. Hoses must be verified to be in the correct
positions, before starting transfer operations. A sample (if required) must b e taken
and verified (if required) prior to starting transfer operations. All lines must be
blown-down and purged before disconnecting them from the tank car or vessel.

7.6 PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT:
Follow practices indicated in Section 6 (Accidental Release Measures). Make certain
application equipment is locked and tagged -out safely. Always use this product in areas
where adequate ventilation is provided. Collect all rinsates and dispose of according
to applicable Federal, State, Provincial, or local procedures.

7.7 EMPTY CONTAINER WARNING:
Empty containers may contain residue and can be dangerous. Do not attempt to refill or
clean containers without proper instructions. Empty drums sh ould be completely drained
and safely stored until appropriately reconditioned or disposed. Empty containers should
be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental re gulations. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY BURST AND CAUSE INJURY OR DEATH.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 EXPOSURE LIMITS:
MATERIAL CAS# EINECS# TWA (OSHA) TLV (ACGIH)
Acetone 67 -64-1 200-662-2 1000 ppm 500 ppm A4
Methyl Acetate 79 -20-9 201-185-2 200 ppm 200 ppm

MATERIAL CAS# EINECS# CEILING STEL(OSHA/ACGIH) HAP
Acetone 67 -64-1 200-662-2 None Known 750 ppm No
Methyl Acetate 79 -20-9 201-185-2 None Known 250 ppm No

This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1%.

Page 5 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED)

8.2 APPROPRIATE ENGINEERING CONTROLS:

RESPIRATORY EXPOSURE CONTROLS
Airborne concentrations should be kept to lowest levels possible. If vapor, dust or mist
is generated and the occupational exposure limit of the product, or any component of the
product, is exceeded, use appropriate NIOSH or MSHA approved air purifying or air -supplied
respirator authorized in 29 CFR 1910.134, European Standard EN 149, or applicable State
regulations, after determining the airborne concentration of the contaminant. Air supplied
respirators should always be worn when airborne concentration of the contaminant or
oxygen content is unknown. Maintain airborne contaminant concentrations below exposure
limits. If adequate ventilation is not available or there is potential for airborne
exposure above the exposure limits, a respirator may be worn up to the respirato r exposure
limitations, check with respirator equipment manufacturer's recommendations/limitations.
For particulates, a particulate respirator (NIOSH Type N95 or better filters) may be worn.
If oil particles (such as: lubricants, cutting fluids, g lycerine, and so on) are present,
use a NIOSH Type R or P filter. For a higher level of protection, use positive pressure
supplied air respiration protection or Self -Contained Breathing Apparatus or if oxygen
levels are below 19.5% or are unknown.

EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS
Positive pressure, full -face piece Self-Contained Breathing Apparatus; or positive
pressure, full-face piece Self-Contained Breathing Apparatus with an auxilliary positive
pressure Self-Contained Breathing Apparatus.

VENTILATION
LOCAL EXHAUST: Necess ary MECHANICAL (GENERAL): Necessary
SPECIAL: None OTHER: None
Please refer to ACGIH document, "Industrial Ventilation, A Manual of
Recommended Practices", most recent edition, for details.

8.3 INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:

EYE PROTECTION:
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, chemical splash goggles should be worn, when a higher
degree of protection is necessary, use splash goggles or safety glasses. Face -shields
are recommended when the operation can generate splashes , sprays or mists.

HAND PROTECTION:
Use gloves chemically resistant to this material. Preferred examples: Butyl rubber,
Chlorinated Polyethylene, Polyethylene, Ethyl vinyl alcohol laminate ("EVAL"),
Polyvinyl alcohol ("PVA"). Examples of acceptab le glove barrier materials include:
Natural rubber ("latex"), Neoprene, Nitrile/butadiene rubber ("nitril") or ("NBR"),
Polyvinyl chloride ("PVC") or "vinyl"), Viton. Chemical-resistant, impervious gloves
complying with an approved standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering the parameters
specified by the glove manufacturer, check during use that the gloves are still retaining
their protective properties . It should be noted that the time to breakthrough for any
glove material may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the gloves cannot be
accurately estimated.

BODY PROTECTION:
Use body protection appropriate for task. Cover -all, rubber aprons, or chemical protective
clothing made from impervious materials are generally acceptable, depending on the task.

WORK & HYGIENIC PRACTICES:
Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using toilet facilities and at the end of the working period. Provide readily
accessible eye wash stations & safety showers. Remove clothing that becomes contaminated.
Destroy contaminated leather articles. Launder or discard contaminated clothing.

Page 6 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 9. PHYSICAL & CHEMICAL PROPERTIES

APPEARANCE: Liquid, Water-White
ODOR: Ketone
ODOR THRESHOLD: Not Available
pH (Neutrality): Not Available
MELTING POINT/FREEZING POINT: Not Available
BOILING RANGE (IBP,50%,Dry Point): 54 56 58 C / 130 134 138 F
FLASH POINT (TEST METHOD): -16 C / 2 F (TCC) (Lowest Component)
EVAPORATION RATE (n-Butyl Acetate=1): 4.9
FLAMMABILITY CLASSIFICATION: Class I B
LOWER FLAMMABLE LIMIT IN AIR (% by vol): 2.7
UPPER FLAMMABLE LIMIT IN AIR (% by vol): Not Available
VAPOR PRESSURE (mm of Hg)@20 C 187.9
VAPOR DENSITY (air=1): 2.1
GRAVITY @ 68/68 F / 20/20 C:
DENSITY: 0.808
SPECIFIC GRAVITY (Water=1): 0.809
POUNDS/GALLON: 6.739
WATER SOLUBILITY: Appreciable
PARTITION COEFFICIENT (n-Octane/Water): Not Available
AUTO IGNITION TEMPERATURE: 501 C / 935 F
DECOMPOSITION TEMPERATURE: Not Available
TOTAL VOC'S (TVOC)*: 100.0 Vol% / 809.0 g/L / 6.7 Lbs/Gal
NONEXEMPT VOC'S (CVOC)*: 0.0 Vol% /0.0 g/L / 0.000 Lbs/Gal
HAZARDOUS AIR POLLUTANTS (HAPS): 0.0 Wt% /0.0 g/L / 0.000 Lbs/Gal
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C) 0.0
VISCOSITY @ 20 C (ASTM D445): Not Available
* Using CARB (California Air Resources Board Rules).

SECTION 10. STABILITY & REACTIVITY

10.1 REACTIVITY & CHEMICAL STABILITY:
Stable under normal conditions, no hazardous reactions when kept from incompatibles.

10.2 POSSIBILITY OF HAZARDOUS REACTIONS & CONDITIONS TO AVOID:
Isolate from oxidizers, heat, sparks, electric equipment & open flame.

10.3 INCOMPATIBLE MATERIALS:
Reacts with strong oxidants, causing fire & explosion hazard.

10.4 HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide from burning.

10.5 HAZARDOUS POLYMERIZATION:
Will not occur.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 ACUTE HAZARDS

11.11 EYE & SKIN CONTACT:
Primary irritation to skin, defatting, dermatitis.
Primary irritation to eyes, redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.

11.12 INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure
can cause serious nervous system depression. Vapor harmful.

11.13 SWALLOWING:
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.

Page 7 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

11.2 SUBCHRONIC HAZARDS/CONDITIONS AGGRAVATED

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Pre-existing disorders of any target organs mentioned in this Document can be
aggravated by over-exposure by routes of entry to components of this product.
Persons with these disorders should avoid use of this product.

11.3 CHRONIC HAZARDS

11.31 CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
This product has no carcinogens listed by IARC, NTP, NIOSH,
OSHA or ACGIH, as of this date, greater or equal to 0.1%.

11.32 TARGET ORGANS: May cause damage to target organs, based on animal data.

11.33 IRRITANCY: Irrit ating to contaminated tissue.

11.34 SENSITIZATION: No component is known as a sensitizer.

11.35 MUTAGENICITY: No known reports of mutagenic effects in humans.

11.36 EMBRYOTOXICITY: No known reports of embryotoxic effects in humans.

11.37 TERATOGENICITY: No known reports of teratogenic effects in humans.

11.38 REPRODUCTIVE TOXICITY: No known reports of reprodu ctive effects in humans.

SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED)

A MUTAGEN is a chemical which causes permanent changes to genetic material (DNA)
such that the changes will propagate across generational lines. An EMBRYOTOXIN
is a chemical which causes damage to a developing embryo (such as: within the first
8 weeks of pregnancy in humans), but the damage does not propagate across
generational lines. A TERATOGEN is a chemical which causes damage to a developing
fetus, but the damage does not propagate across generational lines. A REPRODUCTIVE
TOXIN is any substance which interferes in any way with the reproductive proce ss.

11.4 MAMMALIAN TOXICITY INFORMATION

MATERIAL CAS# EINECS# LOWEST KNOWN LETHAL DOSE DATA
LOWEST KNOWN LD50 (ORAL)
Acetone 67 -64-1 200-662-2 5340.0 mg/kg(Rabbits)
LOWEST KNOWN LC50 (VAPORS)
Acetone 67 -64-1 200-662-2 2100 ppm (Cats)

SECTION 12. ECOLOGICAL INFORMATION

12.1 ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.

12.2 EFFECT OF MATERIAL ON PLANTS AND ANIMALS:
This product may be harmful or fatal to plant and animal life if released
into the environment. Refer to Section 11 (Toxicologica l Information) for
further data on the effects of this product's components on test animals.

12.3 EFFECT OF MATERIAL ON AQUATIC LIFE:
The most sensitive known aquatic group to any component of this product is:
Fathead Minnow 360 ppm or mg/L (96 hour exposure).
Keep out of sewers an d natural water supplies.

12.4 MOBILITY IN SOIL
This material is a mobile liquid.

12.5 DEGRADABILITY
This product is completely biodegradable.

12.6 ACCUMULATION
This product does not accumulate or biomagnify in the environment.

Page 8 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 13. DISPOSAL CONSIDERATIONS

The generation of waste should be avoided or minimized wherever possible.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste should not be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible.
This material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty containers
and liners may retain some product residues. Vapor from some product residues may create a
highly flammable or explosive atmosphere inside the conta iner. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE USED CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY BURST AND CAUSE INJURY OR DEATH. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Processing, use or contamination may change the waste disposal requirements. Do not
dispose of on land, in surface waters, or in storm drains. Waste should be recycled
or disposed of in accordance with regulations. Large amounts should be collected
for reuse or consigned to licensed hazardous waste haulers for disposal.
ALL DISPOSAL MUST BE IN ACCORDANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL
REGULATIONS. IF IN DOUBT, CONTACT PROPER AGENCIES. EPA CHARACTERISTIC: D001

SECTION 14. TRANSPORT INFORMATION

IF > 6024 LB / 2738 KG OF THIS PRODUCT IS IN 1 CONTAINER, IT EXCEEDS THE RQ OF
ACETONE. "RQ" MUST BE PUT BEFORE THE DOT SHIPPING NAME.

MARINE POLLUTANT: No
DOT/TDG SHIP NAME: UN1263, Paint Related Material, 3, PG-II
DRUM LABEL: (FLAMMABLE LIQUID)
IATA / ICAO: UN1263, Paint Related Material, 3, PG-II
IMO / IMDG: UN1263, Paint Related Material, 3, PG-II
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128

SECTION 15. REGULATORY INFORMATION

15.1 EPA REGULATION:
SARA SECTION 311/312 HAZARDS: Acute Health, Fire

All components of this product are on the TSCA lis t.
This material contains no known products restricted under SARA Title III,
Section 313 in amounts greater or equal to 1%.

SARA TITLE III INGREDIENTS CAS# EINECS# WT% (REG.SECTION) RQ(LBS)
Acetone 67 -64-1 200-662-2 75-85 (311,312) 5000

Any release equal to or exceeding the RQ must be reported to the National
Response Center (800-424-8802) and appropriate state and local regulatory
agencies as described in 40 CFR 302.6 and 40 CFR 355.40 respectively.
Failure to report may result in substantial civil and criminal penalties.
State & local regulations may be more restrictive than federal regulations.

15.2 STATE REGULATIONS:
THIS PRODUCT MEETS REQUIREMENTS OF SOUTHERN
CALIFORNIA AQMD RULE 443.1 & SIMILAR REGULATIONS

CALIFORNIA SAFE DRINKING WATER & TOXIC ENFORCEMENT ACT (PROPOSITION 65):
This product contains no chemicals known to the State of California
to cause cancer or reproductive toxicity.

15.3 INTERNATIONAL REGULATIONS
The identified components of this product are listed on the chemical inventories
of the following countries:
Australia (AICS), Canada (DSL or NDSL), China (IECSC), Europe (EINECS, ELINCS),
Japan (METI/CSCL, MHLW/ISHL), South Korea (KECI), New Zealand (NZIoC),
Philippines (PICCS), Switzerland (SW ISS), Taiwan (NECSI), USA (TSCA).

Page 9 of 9

COMPANY IDENTITY: T C I Products Company SDS DATE: 07/24/2014
PRODUCT IDENTITY: DT8020 ZERO VOC ACRYLIC LACQUER THINNER ORIGINAL: 07/24/2014
SDS NUMBER: DT8020

SECTION 15. REGULATORY INFORMATION (CONTINUED)

15.4 CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
B2: Flammable Liquid.
D2B: Irritating to skin / eyes.

This product was classified using the hazard criteria of the Controlled Products
Regulations (CPR). This Document contains all information required by the CPR.

SECTION 16. OTHER INFORMATION

16.1 HAZARD RATINGS:
HEALTH (NFPA): 1, HEALTH (HMIS): 2, FLAMMABILITY: 3, PHYSICAL HAZA RD: 0
(Personal Protection Rating to be supplied by user based on use conditions.)
This information is intended solely for the use of individuals
trained in the NFPA & HMIS hazard rating systems.

16.2 EMPLOYEE TRAINING
See Section 2 for Risk & Safety Statem ents. Employees should be made aware
of all hazards of this material (as stated in this SDS) before handling it.

16.3 SDS DATE: 07/24/2014
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or fitness
for a specific use, with respect to the product or the information provided herein,
except for conformation to contracted specifications. All information appearing herein
is based upon data obtained from manufacturers and/or recognized technical sources.
While the information is believed to be accurate, we make no representations as to its
accuracy or sufficiency.
Conditions of use are beyond our control, and therefore users are responsible for
verifying the data under their own operating conditions to determine whether the product
is suitable for their particular purposes and they assume all risks of their handling,
and disposal of the product. Users also assume all risks in regards to the publication
or use of, or reliance upon information contained herein.
This information relates only to the product designated herein, and does not relate to
its use in combination with any other material or process.

Unless updated, the Safety Data Sheet is valid until 07/24/2017.