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Home My WebLink AboutDAQ-2025-0015171 DAQC-273-25 Site ID 10007 (B5) MEMORANDUM TO: CEM FILE – HOLCIM (US), INC. THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: March 11, 2025 SUBJECT: Source: Portland Cement Rotary Kiln (K-1) and Clinker Cooler (CC-1) Contact: Mark Miller – Director Land and Environment – 972-221-4646 Javier Ortiz – Plant Manager – 801-829-6821 Clinton Badger – 801-829-2122 Location: 6055 East Croydon Road, Morgan, Weber County, UT Test Contractor: Mostardi Platt FRS ID#: UT00000049002900001 Permit/AO#: Title V operating permit 2900001004 dated November 18, 2021 Last revised March 25, 2022 40 CFR 63 Subpart LLL Subject: Review of RA/PST Report dated September 23, 2024 On September 23, 2024, Utah Division of Air Quality (DAQ) received a Relative Accuracy/Performance Specification Test (RA/PST) report for the Holcim Devil’s Slide Cement Manufacturing Plant K-1 and CC-1 exhaust stacks in Morgan, Utah. Testing was performed on July 18, 2024, determine the relative accuracy of the Hg, THC, O2, CO2, NOX, and SO2 monitoring systems. The DAQ-calculated test results are: RA/PST EVALUATION: Kiln NSPS RATA Test Date 7/18/2024 Primary Channel Manufacturer Serial No. Units CEM Value RM Value Relative Accuracy Status SO2 ppm 2.220 2.390 19.7% Passed lbs/hr 4.056 3.730 0.1% Passed CO2 % 15.570 14.920 5.7% Passed NOx Sick MCS 100 E 3030519 ppm 282.367 294.089 5.8% Passed lbs/hr 340.944 356.167 5.8% Passed O2 % 9.220 10.220 10.4% Passed CO ppm 275.856 264.111 7.8% Passed VOC/THC ABB-Multi FID 14 33447621 Ppm 30.91 29.18 12.1% Passed Hg µg/scm 1.07 1.37 31.38% Passed Volumetric Flow Rate dscfh 10150189 10139252 1.0% Passed Explanation: 1. Performance Specification 12A - Total Vapor Phase Mercury CEMS in Stationary Sources. 13.3 Relative Accuracy (RA). The RA of the CEMS must be no greater than 20 percent of the mean value of the RM test data in terms of units of µg/scm. Alternatively, if the mean RM is less than 5.0 µg/scm, the results are acceptable if the absolute value of the difference between the mean RM and CEMS values does not exceed 1.0 µg/scm. 1 8 2 2 DEVIATIONS: No deviations were noted in this report. CONCLUSION: Holcim operates the continuous emissions monitor (CEM) on the kiln stack to measure Hg, THC, O2, CO2, NOX, and SO2 emissions. The CEM was audited by the DAQ and found to meet quality assurance requirements found in 40 CFR Part 60, Appendix B, Performance Specification 1, and R307-170, Continuous Emission Monitoring System Program. Quarterly cylinder gas audits and an annual relative accuracy test audit were conducted in accordance with the procedures outlined in UAC R307-170. RECOMMENDATION: The Holcim Kiln CEM system was operating as required in R307-170 and 40 CFR 60.13 at the time of this evaluation. HPV: Yes, due to prior outstanding violations. ATTACHMENTS: RATA Review Spreadsheets. RATA Report Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Reference Methods 2, 3A, 6C, 7E, 10, & 19 Source Information Company Name Holcim USA Inc. Company Contact:Javier Sosa Ortiz Contact Phone No.(810) 829-2122 Stack Designation:Kiln Test & Review Dates Test Date:7/18/2024 Review Date: 2/19/2024 Observer:Not Observed Reviewer:Rob Leishman Emission Limits Emission Rates SO2 NOX CO SO2 NOX CO lbs./MMBtu lbs./hr. ppm %O2 Correction as a whole # Test Information Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) Ps Stack Pressure 134.00 97.935 1.0120 1.92 0.84 24.12 -0.5 24.083235 Contractor Information Contact:Christ Eldridge Contracting Company: Mostardi Platt Address: 7715 Commercial Way, Suite 155, Henderson, NV 89011 Phone No.: 630-993-2100 Project No.: Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Round Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc dscf/MMBtu wscf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthracite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 CO2 Interference w/CO Yes Yes Yes Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Company Holcim USA Inc. Point Source Kiln Test Date 7/18/24 Start Time End Time Run CO PPM CO2 % NOx PPM NOx lb/hr O2 % SO2 PPM SO2 lb/hr Flow SCFH Moisture % Headers Here Headers Here Headers Here 10:59 11:20 1 275.9 15.4 334.2 411.2 9.4 4.9 7.6 10306036 12.7 11:35 11:56 2 255 15.5 290..4 349.7 9.3 2 4.9 10083468 13 12:10 12:31 3 283.6 15.7 281.8 342.7 9.2 3.3 6.8 10188565 13.9 13:05 13:26 4 254 15.3 278.6 340 9.4 2.5 4.7 10208973 12.9 13:44 14:05 5 258.6 15.5 269.2 328.2 9.3 1.3 2.8 10211647 13 14:19 14:40 6 258 15.6 277 330 9.2 1.2 2.6 9975403 13.1 15:14 15:35 7 296 15.7 269.3 326.2 9.1 1.8 2.9 10142380 13.2 16:00 16:21 8 326.1 15.7 268 320 9.1 2.1 4.6 9998990 13.2 16:39 17:00 9 292 15.6 272.8 330.9 9.2 1.9 4.6 10163755 13.2 17:31 17:52 10 267.1 15.6 274 332.3 9.2 1.2 2.6 10155948 13 11 12 13 14 15 16 Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Kiln SO2 Analyzer:Serial No.: CO2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:475.00 Test Date SO2 Dry SO2 Dry SO2 Test Date % CO2 Dry 7/18/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 7/18/2024 RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. Run# Start Time End Time %c %c 1 10:59 11:20 Y 4.1 4.9 -0.80 7.05 7.6 1 10:59 11:20 14.0 15.4 2 11:35 11:56 Y 2.6 2 0.60 Y 4.53 4.9 -0.4 2 11:35 11:56 Y 14.3 15.5 -1.20 3 12:10 12:31 Y 3.6 3.3 0.30 Y 6.26 6.8 -0.5 3 12:10 12:31 Y 14.8 15.7 -0.90 4 13:05 13:26 Y 2.6 2.5 0.10 Y 4.41 4.7 -0.3 4 13:05 13:26 Y 14.6 15.3 -0.70 5 13:44 14:05 Y 1.5 1.3 0.20 Y 2.52 2.8 -0.3 5 13:44 14:05 Y 14.9 15.5 -0.60 6 14:19 14:40 Y 1.4 1.2 0.20 Y 2.33 2.6 -0.3 6 14:19 14:40 Y 15.1 15.6 -0.50 7 15:14 15:35 Y 1.6 1.8 -0.20 Y 2.68 2.9 -0.2 7 15:14 15:35 Y 15.2 15.7 -0.50 8 16:00 16:21 Y 2.6 2.1 0.50 Y 4.30 4.6 -0.3 8 16:00 16:21 Y 15.2 15.7 -0.50 9 16:39 17:00 Y 2.5 1.9 0.60 Y 4.16 4.6 -0.4 9 16:39 17:00 Y 15.1 15.6 -0.50 10 17:31 17:52 Y 1.4 1.2 0.20 Y 2.35 2.6 -0.3 10 17:31 17:52 Y 15.1 15.6 -0.50 11 11 12 12 13 13 14 14 15 15 16 16 Average = 2.4 2.22 0.17 3.7 4.056 0.329 Average = 14.920 15.570 0.655 Sd Standard Deviation = 0.42 Sd Standard Deviation = Sd Standard Deviation = 0.100 Sd Standard Deviation = 0.25 Confidence Coefficient = 0.30 Confidence Coefficient = Confidence Coefficient = 0.1 Confidence Coefficient = 0.188 RA - Relative Accuracy =19.70%RA RA RA - Relative Accuracy =5.65% n = 10 0 9 n = 9 or RA of 1%0.65% t0.975 = 2.262 2.306 t0.975 = 2.306 E.L. Relative Accuracy = 1% 0.09% a For steam generators;b Average of three samples;9 c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 13.2 Relative accuracy Performance Specification. The RA of the CEMSS must be not greater than 20 percent when RM is used in the denominator of Eq. 2-6 (average emissions during test are greater than 50 percent of the emission standard)or 10 percent when the applicable emission standard is used in the denominator of Eq. 2-6 (average emissions during test are less than 50 percent of the emission standard). Up dated January 17, 2006 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 13.2 CEMS Relative Accuracy Perfromance Specification. The RA of the CEMS must be no grater than 20 percent of the mean value of the reference method (RM) data. 1 percent O2 or CO2. The results are also acceptable if the absolute value of the difference between the mean RM value and the mean CEMS value is less than or equal to 1.0 percent O2 (or CO2). Up dated September 14, 2016 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 PassedPassedPassed Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Division of Air Quality Relative Accuracy Test Audit of Holcim USA Inc. Kiln NOX Analyzer:Serial No.: O2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:415.00 Date NOx Dry NOx Dry NOx Test Date % O2 Dry 7/18/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 9/30/2014 RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. Run# Start Time End Time %c %c 1 10:59 11:20 Y 330.7 334.2 -3.5 Y 408.55 411.2 -2.65 1 10:59 11:20 10.5 9.4 2 11:35 11:56 Y 294.8 290.4 4.4 Y 369.36 349.7 19.66 2 11:35 11:56 Y 10.3 9.3 1.000 3 12:10 12:31 Y 293.0 281.8 11.2 366.42 342.7 3 12:10 12:31 Y 10.0 9.2 0.800 4 13:05 13:26 Y 295.0 278.6 16.4 Y 359.52 340 19.52 4 13:05 13:26 Y 10.5 9.4 1.100 5 13:44 14:05 Y 283.0 269.2 13.8 Y 341.86 328.2 13.66 5 13:44 14:05 Y 10.3 9.3 1.000 6 14:19 14:40 Y 292.0 277 15.0 Y 348.61 330 18.61 6 14:19 14:40 Y 10.2 9.2 1.000 7 15:14 15:35 Y 285.2 269.3 15.9 Y 342.98 326.2 16.79 7 15:14 15:35 Y 10.2 9.1 1.100 8 16:00 16:21 Y 284.5 268 16.5 Y 338.21 320 18.21 8 16:00 16:21 Y 10.1 9.1 1.000 9 16:39 17:00 Y 288.6 272.8 15.8 Y 345.51 330.9 14.61 9 16:39 17:00 Y 10.2 9.2 1.000 10 17:31 17:52 291.2 274 Y 350.89 332.3 18.59 10 17:31 17:52 Y 10.2 9.2 1.000 11 11 12 12 13 13 14 14 15 15 16 16 Average = 294.1 282.4 11.722 356.17 340.94 15.22 Average = 10.220 9.220 1.000 Sd Standard Deviation = 6.89 Sd Standard Deviation = Sd Standard Deviation = 7.025 Sd Standard Deviation = 0.09 Confidence Coefficient = 5.294 Confidence Coefficient = Confidence Coefficient = 5.400 Confidence Coefficient = 0.066 RA - Relative Accuracy =5.80%Relative Accuracy = Relative Accuracy =5.80%RA - Relative Accuracy =10.43% n = 9 0 9 n = 9 or RA of 1%1.00% t0.975 = 2.306 t0.975 = t0.975 = 2.306 t0.975 = 2.306 E.L. Relative Accuracy = EMRA EMRA 86% a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 4. Performance and Equipment Specifications 4.3 Relative accuracy. The RA of the CEMSS shall be no grater than 20 percent of the mean value of the RM test data in terms of the units of the emission standard or 10 percent of the applicable standard, whichever is greater For SO2 emission standards between 0.30 and 0.20 lbs./MMBtu use 15 Percent of the applicable standard; For SO2 emission standards below 0.20 lbs./MMBtu use 20 Percent of the emission standard; 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 12. Calculate the arithmetic difference between the RM and the CEMSS output for each run. The average of the nine (of more) data sets constitute the RA. 13.2 Relative accuracy. The RA of the CEMSS must be no grater than 1 percent O2 or CO2. 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? PassedPassedPassed 3030519Sick MCS 100 E Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Division of Air Quality Relative Accuracy Test Audit of Holcim USA Inc. Kiln CO Analyzer:Serial No.: Acquisition System: Acquisition System: Serial No.: Equivalent Emission Limit: Date CO Dry CO Dry CO 7/18/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. 1 10:59 11:20 Y 242.80 275.9 33.10 182.58 2 11:35 11:56 Y 261.70 255 -6.70 199.59 3 12:10 12:31 242.70 283.6 184.75 4 13:05 13:26 Y 249.00 254 5.00 184.71 5 13:44 14:05 Y 247.70 258.6 10.90 182.13 6 14:19 14:40 Y 252.70 258 5.30 183.64 7 15:14 15:35 Y 282.30 296 13.70 206.65 8 16:00 16:21 Y 301.60 326.1 24.50 218.24 9 16:39 17:00 Y 280.50 292 11.50 204.41 10 17:31 17:52 Y 258.70 267.1 8.40 189.75 11 12 13 14 15 16 Average = 264.11 275.86 11.74 Sd Standard Deviation = 11.52 Confidence Coefficient = 8.855 RA - Relative Accuracy =7.80% n = 9 0 0 t0.975 = 2.306 E.L. Relative Accuracy = a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 4 For Carbon Monoxide (CO) Continuous Emission Monitoring Systems applicable emission standard is used to calculate RA. 40 CFR 60 Performance Specification 4A For Carbon Monoxide (CO) Continuous Emission Monitoring Systems 13.2 Relative accuracy. The RA of the CEMSS must be no greater than 10 percent when the average RM value is used to calculate RA, 5 percent when the applicable emission standard is used to calculate RA, or within 5 ppmv when the RA is calculated as the absolute average difference between the RM and CEMSS plus the 2.5 percent confidence coefficient. 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 13.2 Relative accuracy. The RA of the CEMSS must be no grater than 10 percent when the average of the RM value is used to calculate RA or 5 percent when the Passed Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Dry Volumetric Flow dscfh Run Date Start Time End Time RM CEM Diff 1 7/18/24 10:59 11:20 Y 10,342,459.25 10306036 36,423.25 2 7/18/24 11:35 11:56 10,489,208.75 10083468 3 7/18/24 12:10 12:31 Y 10,469,551.49 10188565 280,986.49 4 7/18/24 13:05 13:26 Y 10,202,739.03 10208973 (6,233.97) 5 7/18/24 13:44 14:05 Y 10,112,972.71 10211647 (98,674.29) 6 7/18/24 14:19 14:40 Y 9,994,890.43 9975403 19,487.43 7 7/18/24 15:14 15:35 Y 10,067,943.61 10142380 (74,436.39) 8 7/18/24 16:00 16:21 Y 9,952,301.36 9998990 (46,688.64) 9 7/18/24 16:39 17:00 Y 10,022,667.35 10163755 (141,087.65) 10 7/18/24 17:31 17:52 Y 10,087,746.58 10155948 (68,201.42) 11 7/18/24 12 7/18/24 13 7/18/24 14 7/18/24 15 7/18/24 16 7/18/24 Average = 10,139,252.42 10,150,188.56 10,936.13 Standard Deviation 123,307 Confidence Coefficient = 94782 RA - Relative Accuracy =Passed 1.0% n = 9 t0.975 =2.306 Dry Volumetric Flow dscfm Run Date Start Time End Time RM CEM Diff 1 7/18/24 10:59 11:20 172,374.32 2 7/18/24 11:35 11:56 174,820.15 3 7/18/24 12:10 12:31 174,492.52 4 7/18/24 13:05 13:26 170,045.65 5 7/18/24 13:44 14:05 168,549.55 6 7/18/24 14:19 14:40 166,581.51 7 7/18/24 15:14 15:35 167,799.06 8 7/18/24 16:00 16:21 165,871.69 9 7/18/24 16:39 17:00 167,044.46 10 7/18/24 17:31 17:52 168,129.11 11 7/18/24 12 7/18/24 13 7/18/24 14 7/18/24 15 7/18/24 16 7/18/24 Average = Standard Deviation En t e r Us e En t e r Us e Holcim USA Inc. Kiln Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Kiln Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Actual Volumetric Flow acfm Run Date Start Time End Time RM CEM Diff 1 7/18/24 10:59 11:20 323,831.87 2 7/18/24 11:35 11:56 330,706.91 3 7/18/24 12:10 12:31 330,824.43 4 7/18/24 13:05 13:26 322,597.89 5 7/18/24 13:44 14:05 318,543.38 6 7/18/24 14:19 14:40 315,605.33 7 7/18/24 15:14 15:35 317,897.01 8 7/18/24 16:00 16:21 314,900.20 9 7/18/24 16:39 17:00 316,075.42 10 7/18/24 17:31 17:52 319,601.08 11 7/18/24 12 7/18/24 13 7/18/24 14 7/18/24 15 7/18/24 16 7/18/24 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = WET VOLUMETRIC FLOW wscfh Run Date Start Time End Time RM CEM Diff 1 7/18/24 10:59 11:20 11,620,740.73 2 7/18/24 11:35 11:56 11,830,824.22 3 7/18/24 12:10 12:31 11,836,689.08 4 7/18/24 13:05 13:26 11,518,106.84 5 7/18/24 13:44 14:05 11,430,962.71 6 7/18/24 14:19 14:40 11,306,437.14 7 7/18/24 15:14 15:35 11,404,557.78 8 7/18/24 16:00 16:21 11,274,840.10 9 7/18/24 16:39 17:00 11,351,984.76 10 7/18/24 17:31 17:52 11,406,316.80 11 7/18/24 12 7/18/24 13 7/18/24 En t e r Us e En t e r Us e Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Kiln 14 7/18/24 15 7/18/24 16 7/18/24 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Wet Volumetric Flow wscfm Run Date Start Time End Time RM CEM Diff 1 7/18/24 10:59 11:20 193,679.01 2 7/18/24 11:35 11:56 197,180.40 3 7/18/24 12:10 12:31 197,278.15 4 7/18/24 13:05 13:26 191,968.45 5 7/18/24 13:44 14:05 190,516.05 6 7/18/24 14:19 14:40 188,440.62 7 7/18/24 15:14 15:35 190,075.96 8 7/18/24 16:00 16:21 187,914.00 9 7/18/24 16:39 17:00 189,199.75 10 7/18/24 17:31 17:52 190,105.28 11 7/18/24 12 7/18/24 13 7/18/24 14 7/18/24 15 7/18/24 16 7/18/24 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = En t e r Us e Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Test Overview NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Point Source Kiln Contact Phone No.Javier Sosa Ortiz Stack Designation:Kiln Project No.:0 Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12 Test Date 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 Start Time 10:59 11:35 12:10 13:05 13:44 14:19 15:14 16:00 16:39 17:31 Stop Time 11:20 11:56 12:31 13:26 14:05 14:40 15:35 16:21 17:00 17:52 Run Time 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 Stack I.D. (inches)134.00 134.00 134.00 134.00 134.00 134.00 134.00 134.00 134.00 134.00 134.00 134.00 As ft^2 97.94 97.94 97.94 97.94 97.94 97.94 97.94 97.94 97.94 97.94 97.94 97.94 Cp (Pitot Tube Coefficient)0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 Yd Meter Y Factor (unit less)1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 1.0120 Pbar Barometric Pressure ("Hg)24.12 24.12 24.12 24.12 24.12 24.12 24.12 24.12 24.12 24.12 24.12 24.12 Pq (Static Pressure)-0.50 -0.50 -0.50 -0.50 -0.50 -0.50 -0.50 -0.50 -0.50 -0.50 -0.50 -0.50 Ps (Pressure of the Stack)24.08 24.08 24.08 24.08 24.08 24.08 24.08 24.08 24.08 24.08 24.08 24.08 Ts Stack Temp Avg. oF 250.60 252.80 252.70 254.20 250.60 251.80 250.80 252.20 250.00 254.50 Tm Meter Temperature oF CO2 (carbon dioxide)14.00 14.30 14.80 14.60 14.90 15.10 15.20 15.20 15.10 15.10 O2 (oxygen)10.50 10.30 10.00 10.50 10.30 10.20 10.20 10.10 10.20 10.20 Md Molecular Weight Dry 30.66 30.70 30.77 30.76 30.80 30.82 30.84 30.84 30.82 30.82 #VALUE!#VALUE! Ms Molecular Weight Wet 29.27 29.26 29.30 29.30 29.32 29.33 29.34 29.33 29.32 29.34 #VALUE!#VALUE! N2 (nitrogen)75.50 75.40 75.20 74.90 74.80 74.70 74.60 74.70 74.70 74.70 #VALUE!#VALUE! Vm Sample Volume (cf)0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Vm std Standard Volume (dscf) Vlc Moisture (g) Vwstd Moisture Volume (scf) Bws Moisture Content (%100)11.00%11.34%11.55%11.42%11.53%11.60%11.72%11.73%11.71%11.56% S Bws (saturation moisture) AvgSqrtDlp √∆P 0.764 0.779 0.780 0.760 0.753 0.745 0.751 0.743 0.747 0.753 Vs. Gas Velocity (ft./sec)55.11 56.28 56.30 54.90 54.21 53.71 54.10 53.59 53.79 54.39 Qa (stack actual flow rate) acfm 323,832 330,707 330,824 322,598 318,543 315,605 317,897 314,900 316,075 319,601 Qs (stack std. flow rate) dscfm 172,374 174,820 174,493 170,046 168,550 166,582 167,799 165,872 167,044 168,129 #VALUE!#VALUE! Qsd (stack std. flow rate) dscfh 10,342,459 10,489,209 10,469,551 10,202,739 10,112,973 9,994,890 10,067,944 9,952,301 10,022,667 10,087,747 Qw (stack flow rate) wscfm 11,620,741 11,830,824 11,836,689 11,518,107 11,430,963 11,306,437 11,404,558 11,274,840 11,351,985 11,406,317 Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Test Overview NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Point Source Kiln Contact Phone No.Javier Sosa Ortiz Stack Designation:Kiln Project No.:0 Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12 Test Date 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 7/18/2024 Heat Input - BTU/hr. F factor - scf/MMBtu Fuel Analysis - ft3/min 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 Fuel Flow - ft3/min 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Heat Input - BTU/hr. SO2 Concentrations Uncorrected 4.10 2.60 3.60 2.60 1.50 1.40 1.60 2.60 2.50 1.40 Dry Corrected 4.10 2.60 3.60 2.60 1.50 1.40 1.60 2.60 2.50 1.40 Wet Corrected NOx Concentrations Uncorrected 330.70 294.80 293.00 295.00 283.00 292.00 285.20 284.50 288.60 291.20 Dry Corrected 330.70 294.80 293.00 295.00 283.00 292.00 285.20 284.50 288.60 291.20 Wet Corrected CO Concentrations Uncorrected 242.80 261.70 242.70 249.00 247.70 252.70 282.30 301.60 280.50 258.70 Dry Corrected 242.80 261.70 242.70 249.00 247.70 252.70 282.30 301.60 280.50 258.70 Wet Corrected CO2 Concentrations Uncorrected 14.00 14.30 14.80 14.60 14.90 15.10 15.20 15.20 15.10 15.10 Dry Corrected 14.00 14.30 14.80 14.60 14.90 15.10 15.20 15.20 15.10 15.10 Wet Corrected O2 Concentrations Uncorrected 10.50 10.30 10.00 10.50 10.30 10.20 10.20 10.10 10.20 10.20 Dry Corrected 10.50 10.30 10.00 10.50 10.30 10.20 10.20 10.10 10.20 10.20 Wet Corrected Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Kiln Average Emission Dry SO2 NOX CO lbs./MMBtu Average % concentration lbs./hr.CO2 O2 ppm or % 2.39 293.80 261.97 14.83 10.25 Run 1 Enter O2 or CO2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 6.814E-07 3.950E-05 1.765E-05 lbs./hr.7.05 408.55 182.58 14.00 10.50 ppm or %4.10 330.70 242.80 14.00 10.50 Run 2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 4.321E-07 3.521E-05 1.903E-05 lbs./hr.4.53 369.36 199.59 14.30 10.30 ppm or %2.60 294.80 261.70 14.00 10.30 Raw Value Run 3 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 5.983E-07 3.500E-05 1.765E-05 lbs./hr.6.26 366.42 184.75 14.80 10.00 ppm or %3.60 293.00 242.70 14.80 10.00 Raw Value Run 4 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 4.321E-07 3.524E-05 1.810E-05 lbs./hr.4.41 359.52 184.71 14.60 10.50 ppm or %2.60 295.00 249.00 14.60 10.50 Raw Value Run 5 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 2.493E-07 3.380E-05 1.801E-05 lbs./hr.2.52 341.8610 182.13 14.90 10.30 ppm or %1.50 283.00 247.70 14.90 10.30 Raw Value Corrected For Cal. Drift Raw Value Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift O2 CO2 Clear lbs./MMBTU Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Kiln O2 CO2 Clear lbs./MMBTU Run 6 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 2.327E-07 3.488E-05 1.837E-05 lbs./hr.2.33 348.6143 183.64 15.10 10.20 ppm or %1.40 292.00 252.70 15.10 10.20 Raw Value Run 7 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 2.659E-07 3.407E-05 2.053E-05 lbs./hr.2.68 342.98 206.65 15.20 10.20 ppm or %1.60 285.20 282.30 15.20 10.20 Raw Value Run 8 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 4.321E-07 3.398E-05 2.193E-05 lbs./hr.4.30 338.21 218.24 15.20 10.10 ppm or %2.60 284.50 301.60 15.20 10.10 Raw Value Run 9 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 4.155E-07 3.447E-05 2.039E-05 lbs./hr.4.16 345.51 204.41 15.10 10.20 ppm or %2.50 288.60 280.50 15.10 10.20 Raw Value Run 10 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 2.327E-07 3.478E-05 1.881E-05 lbs./hr.2.35 350.89 189.75 15.10 10.20 ppm or %1.40 291.20 258.70 15.10 10.20 Raw Value Run 11 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Holcim RATA $RM 1, 2, 3A, 320 FTIR (Tested 7-18-2024)-w Calibration Error Test Test Date July 18, 2024 O2 CS - Cal. Span 20.00 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.00% Passed Cal. Mid-level 10.00 10.00 0.00 0.00% Passed Cal. High-level 20.00 20.00 0.00 0.00% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of CS - Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date July 18, 2024 CO2 CS - Cal. Span 20.00 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 10.00 10.00 0.00 0.000% Passed Cal. High-level 20.00 20.00 0.00 0.000% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date July 18, 2024 SO2 CS - Cal. Span 10.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 5.00 5.00 0.00 0.000% Passed Cal. High-level 10.00 10.00 0.00 0.000% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date July 18, 2024 NOx CS - Cal. Span 600.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 300.00 300.00 0.00 0.000% Passed Cal. High-level 600.00 600.00 0.00 0.000% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date July 18, 2024 CO CS - Cal. Span 600.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 300.00 300.00 0.00 0.000% Passed Cal. High-level 600.00 600.00 0.00 0.000% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Holcim RATA $RM25A THC (Tested 7-18-2024) Reference Methods 25 A & B Compromised Source Information Company Name Holcim USA Inc. Main Kiln Stack Company Contact:Ty Howard Contact Phone No.801-829-2122 Point Source:Holcim USA Inc. Test & Review Dates Test Date: Tabs Are Shown Review Date: Observer:Not Observed Reviewer:Rob Leishman Emission Limits Emission Rates VOC VOC mg/L gas 24.0 lbs./hr. %O2 Correction as a whole #7.00 Test Information Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) Ps Stack Pressure 131.5 94.3 0 Contractor Information Contact: Contracting Company: Address: Phone No.: Btu/hr Selected Project No.: Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Round ppm corrected for %O2 Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc dscf/MMBtu wscf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthracite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 Yes Yes Holcim RATA $RM25A THC (Tested 7-18-2024) D$I$v$I$s$I$on of A$I$r Qual$I$ty NSPS Relat$I$ve Accuracy Performance Spec$I$f$I$cat$I$on Test - CEMS Cert$I$f$I$cat$I$on Holcim USA Inc. Main Kiln Stack Holcim USA Inc. VOC/THC Analyzer:ABB - Multi FID 14 Serial No.:3.344762.1 O2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:24 I & J Test Date VOC Dry VOC Test Date % O2 Dry 1/0/1900 ppm corrected for %O2 lbs/hr 9/30/2014 RM CEMS Diff Run#Start Time End Time RM CEMS Diff RM CEMS Diff Run# Start Time End Time %c %c 1 10:59 11:20 Y 26.35 30.5 -4.15 1 10:59 11:20 10.6 2 11:35 11:56 Y 25.12 29.9 -4.78 2 11:35 11:56 10.4 3 12:10 12:31 Y 25.07 30.4 -5.33 3 12:10 12:31 10.1 4 13:05 13:26 Y 28.82 29.6 -0.78 4 13:05 13:26 10.6 5 13:44 14:05 Y 28.50 29 -0.50 5 13:44 14:05 10.5 6 14:19 14:40 Y 29.29 30 -0.71 6 14:19 14:40 10.4 7 15:14 15:35 Y 31.33 31.8 -0.47 7 15:14 15:35 10.4 8 16:00 16:21 Y 35.69 34.6 1.09 8 16:00 16:21 10.3 9 16:39 17:00 Y 32.46 32.4 0.06 9 16:39 17:00 10.4 10 17:31 17:52 29.39 21.5 10 17:31 17:52 10.4 11 11 12 12 13 13 14 14 15 15 16 16 Average = 29.2 30.91 1.73 Average = Sd Standard Deviation = 2.35 Sd Standard Deviation = Sd Standard Deviation = Confidence Coefficient = 1.81 Confidence Coefficient = Confidence Coefficient = RA - Relative Accuracy =12.10%RA RA - Relative Accuracy = n = 9 0 n = 0 or RA of 1% t0.975 = 2.306 t0.975 = E.L. Relative Accuracy = 14.75% a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 13.2 Relative accuracy Performance Specification. The RA of the CEMSS must be not greater than 20 percent when RM is used in the denominator of Eq. 2-6 (average emissions during test are greater than 50 percent of the emission standard)or 10 percent when the applicable emission standard is used in the denominator of Eq. 2-6 (average emissions during test are less than 50 percent of the emission standard). Up dated January 17, 2006 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 13.2 CEMS Relative Accuracy Perfromance Specification. The RA of the CEMS must be no grater than 20 percent of the mean value of the reference method (RM) data. 1 percent O2 or CO2. The results are also acceptable if the absolute value of the difference between the mean RM value and the mean CEMS value is less than or equal to 1.0 percent O2 (or CO2). Up dated September 14, 2016 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Passed Holcim RATA $RM25A THC (Tested 7-18-2024) Holcim RATA $RM25A THC (Tested 7-18-2024) State of Utah CalError Page 5 VOC K3 (Propane)O2 Span Value 10,000.00 Span Value 21.98 Units ppm Units % Cylinder No. Expiration Date Cylinder Value: Response Difference CAL. ERROR Status Cylinder No. Expiration Date Cylinder Value:Response Difference CAL. ERROR Status Zero Gas 0.00 0.00 0.00 0.00%Passed Cal.Zero Gas 0.00 0.00 0.00 0.00%Passed Cal. Low-level Cal. Gas 29.71 28.98 0.73 0.01%Passed Cal.Mid-level Cal. Gas 12.05 12.00 0.05 0.23%Passed Cal. Mid-level Cal. Gas 49.33 49.74 0.41 0.00%Passed Cal.High-level Cal. Gas 21.98 22.04 0.06 0.27%Passed Cal. High-level Cal. Gas 90.30 89.13 1.17 0.01%Passed Cal. <0.25% of span value Zero Gas 0.00% <0.10% of span value Zero Gas 0.00%40 to 60% of span value Low-level Cal. Gas 54.8% 25 to 35% of span value Low-level Cal. Gas 0.30%80 to 100% of span value Mid-level Cal. Gas 100.00% 45 to 55% of span value Mid-level Cal. Gas 0.49% 80 to 90% of span value High-level Cal. Gas 0.90% VOC K4 (Butane)CO2 Span Value Span Value Units ppm Units % Cylinder No. Expiration Date Cylinder Value: Response Difference CAL. ERROR Status Cylinder No. Expiration Date Cylinder Value:Response Difference CAL. ERROR Status Zero Gas Zero Gas Low-level Cal. Gas Mid-level Cal. Gas Mid-level Cal. Gas High-level Cal. Gas High-level Cal. Gas <0.25% of span value Zero Gas <0.10% of span value Zero Gas 40 to 60% of span value Low-level Cal. Gas 25 to 35% of span value Low-level Cal. Gas 80 to 100% of span value Mid-level Cal. Gas 45 to 55% of span value Mid-level Cal. Gas 80 to 90% of span value High-level Cal. Gas 0.00 VOC K2 (Ethane) 0.00 Span Value 0.00 Units ppm Cylinder No. Expiration Date Cylinder Value: Response Difference CAL. ERROR Status Zero Gas Low-level Cal. Gas Mid-level Cal. Gas High-level Cal. Gas <0.10% of span value Zero Gas 25 to 35% of span value Low-level Cal. Gas 45 to 55% of span value Mid-level Cal. Gas 80 to 90% of span value High-level Cal. Gas Page 5 Holcim RATA $RM25A THC (Tested 7-18-2024) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Main Kiln Stack Holcim USA Inc. Average Emission Dry VOC (Propane) VOC (Butane) VOC (Ethane)Average % concentration lbs./hr.CO2 O2 ppm corrected for %O2 29.20 10.40 Run 1 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 26.36 10.56 lbs/hr #VALUE! 10.50 Run 2 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 25.13 10.39 lbs/hr #VALUE!10.30 Run 3 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 25.07 10.09 lbs/hr #VALUE!10.00 Run 4 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 28.83 10.63 lbs/hr #VALUE!10.50 Run 5 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 28.51 10.47 lbs/hr #VALUE!10.30 Run 6 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 29.29 10.37 lbs/hr #VALUE!10.20 Raw Value Corrected Value Raw Value Corrected Value Raw Value mg/Liter of gasoline Corrected Value Corrected Value Raw Value Corrected Value Raw Value Corrected Value Raw Value Wet CEM Yes Correct For O2 Yes Holcim RATA $RM25A THC (Tested 7-18-2024) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Main Kiln Stack Holcim USA Inc. Wet CEM Yes Correct For O2 Yes Run 7 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 31.34 10.39 lbs/hr #VALUE!10.20 Run 8 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 35.69 10.31 lbs/hr #VALUE!10.10 Run 9 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 32.46 10.41 lbs/hr #VALUE!10.20 Run 10 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 29.40 10.40 lbs/hr #VALUE!10.20 Run 11 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 lbs/hr Run 12 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 lbs/hr Run 13 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 lbs/hr Corrected Value Raw Value Raw Value Corrected Value Raw Value Raw Value Corrected Value Raw Value Corrected Value Corrected Value Corrected Value Raw Value Corrected Value Raw Value Holcim RATA $RM25A THC (Tested 7-18-2024) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Holcim USA Inc. Main Kiln Stack Holcim USA Inc. Wet CEM Yes Correct For O2 Yes Run 14 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 lbs/hr Run 15 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 lbs/hr Run 16 Dry VOC (Propane) VOC (Butane) VOC (Ethane) Molecular Weight 44.1 58.1 30.1 Qs dscf min CO2 O2 ppm corrected for %O2 lbs/hr Corrected Value Raw Value Corrected Value Raw Value Corrected Value Raw Value RATA Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogeneration Associates Unit 1 Mercury Analyzer: Serial No.: Equivalent Emission Limit: 6.50E-07 Hg Hg dry Hg µg/wscm µg/dscm lbs/MMBtu Run# Test Dates Start Time End Time RM CEMS Diff RM CEMS Diff RM CEMS Diff 1 7/18/24 10:59 11:29 Y 1.71069 1.200 0.511 1.92213 2 7/18/24 11:35 12:05 Y 1.47785 1.100 0.378 1.66688 3 7/18/24 12:10 12:40 Y 1.18279 1.070 0.113 1.33724 4 7/18/24 13:05 13:35 1.79115 1.000 2.01802 5 7/18/24 13:44 14:14 Y 1.57911 1.000 0.579 1.78491 6 7/18/24 14:20 14:50 Y 1.29957 1.000 0.300 1.47010 7 7/18/24 15:14 15:44 Y 1.27737 1.000 0.277 1.44695 8 7/18/24 16:00 16:30 Y 1.20293 1.100 0.103 1.36279 9 7/18/24 16:40 17:10 Y 1.25969 1.090 0.170 1.42677 10 7/18/24 17:31 18:01 Y 1.35140 1.050 3.01E-01 1.52805 11 12 ABS Diff Average = 1.371 1.068 0.303 Sd Standard Deviation =0.1657 Confidence Coefficient =0.1274 RA - Relative Accuracy =31.38% n = 9 0 0 t0.975 = 2.306 Alternate Relative Accuracy: 0.431 Passed Perfromance Specification 12A - Total Vapor Phose Mercury CEMS in Stationary Sources. 13.3 Relative Accuracy (RA). The RA of the CEMS must be no greater than 20 percent of the mean valure of the RM test data in terms of units of µg/scm. Alternati vely, if the mean Activate Run w/Use Activate Run w/Use Activate Run w/Use Page 1 SourceReference Methods 30B Source Information Company Name Sunnyside Cogeneration Associates Company Contact:Rusty Netz Contact Phone No.435-888-4476 Stack Designation:Unit 1 Test & Review Dates Test Date:7/18/2024 Review Date: 2/26/2025 Observer:Unobserved Reviewer:Rob Leishman Emission Limits Emission Rates Hg Hg lb/MM tons clinker 1.371 µg/dscm 1.60 lb/MMBtu 6.50E-07 % Reduction % O2 Correction as a whole No. Test Information Equivalent Diameter (in.)As ft^2 Train I.D.Y ∆H @ Cp Pbar Pq (static) MDL ng Hg 101.00 55.638 Train "A"0.9850 10 Train "B"1.0000 Electrical Output of the Unit Heat Input Average. MW Load Max Elecctrical Output (MEO) MW Load Contractor Information Contact:Chris Eldridge Contracting Company:Mostardi Platt Address:7715 Commercial Way, Ste 115, Nenderson NV 89011 Phone No.:630-993-2100 Project No.: Tabs Are Shown Round Maximum Annual Electrical Output GW-hr MHI Maximum Heat Input of the unit MMBTU/hr Maximum annual Potential Heat Input TBTU/yr Division of Air Quality Instrumental Reference Methods - Gaseous Measurements through 12/10/2017 Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc dscf/mmBtu wscf/mmBtu dscf/mmBtu Diluent F factor used O2 CO2 Anthracite 2 Bituminous 2 Lignite Natural Propane Butane 10100COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 10320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Page 2 Memo&Notes RM 30B Average => 1.4133 1.5964 9.96E-11 0.00 Run Validation Run Date µg/wscm µg/dscm lbs/dscf E lb/hr E lb/yr %CO2 Fc dscf/MMBTU lbs/MMBtu lbs/Tbtu Run Valid Run 1 7/18/24 1.7107 1.92213 1.199E-10 #VALUE! #VALUE!0.00 Run Valid Run 2 7/18/24 1.4779 1.66688 1.040E-10 #VALUE! #VALUE!0.00 Run Valid Run 3 7/18/24 1.1828 1.33724 8.344E-11 #VALUE! #VALUE!0.00 Run Valid Run 4 7/18/24 1.7912 2.01802 1.259E-10 #VALUE! #VALUE!0.00 Run Valid Run 5 7/18/24 1.5791 1.78491 1.114E-10 #VALUE! #VALUE!0.00 Run Valid Run 6 7/18/24 1.2996 1.47010 9.173E-11 #VALUE! #VALUE!0.00 Run Valid Run 7 7/18/24 1.2774 1.44695 9.029E-11 #VALUE! #VALUE!0.00 Run Valid Run 8 7/18/24 1.2029 1.36279 8.504E-11 #VALUE! #VALUE!0.00 Run Valid Run 9 7/18/24 1.2597 1.42677 8.903E-11 #VALUE!0.00 Run Valid Run 10 7/18/24 1.3514 1.52805 9.535E-11 Run 11 Run 12 Page 3 RM 30B Cal. Curve used:Linear MDL = 10.0000 Average Spike Recovery = 95.1% Sunnyside Cogeneration Associates Unit 1 Nunber of Runs Used for Spike Recovery Calculation 3 Cal. Curve Used Train ID Start Date Start Time End Date End Time Trap ID Section 1 Area Count Section 1 Mass (ng) Section 2 Area Count Section 2 Mass (ng) Total Mass (ng) (Section 2) Breakthrough (%) 1A 4,310.00 46.130 145.00 1.5500 46.130 3.36% 1B 4,000.00 42.810 107.00 1.1400 42.810 2.66% 2A 3,520.00 37.670 53.00 0.5600 37.670 1.48% 2B 3,680.00 39.390 -89.00 -0.9500 39.390 -2.41% 3A 2,930.00 31.360 -110.00 -1.1700 31.360 -3.73% 3B 2,830.00 30.290 114.00 1.2200 30.290 4.02% 4A 4,410.00 47.200 179.00 1.9100 47.200 4.04% 4B 9,010.00 96.440 -66.00 -0.7000 96.440 -0.72% 5A 4,050.00 43.350 -59.00 -0.6300 43.350 -1.45% 5B 8,370.00 89.590 100.00 1.0700 89.590 1.19% 6A 3,225.00 34.520 121.00 1.2900 34.520 3.73% 6B 7,770.00 83.170 109.00 1.1600 83.170 1.39% 7A 3,020.00 32.320 250.00 2.6700 32.320 8.26% 7B 3,200.00 34.250 199.00 2.1300 34.250 6.21% 8A 3,200.00 34.250 -5.00 -0.0500 34.250 -0.14% 8B 2,640.00 28.250 249.00 2.6600 28.250 9.41% 9A 2,850.00 30.500 -46.00 -0.4900 30.500 -1.60% 9B 3,260.00 34.890 250.00 2.6700 34.890 7.65% 10A 3,290.00 35.210 225.00 2.4000 35.210 6.81% 10B 3,300.00 35.320 142.00 1.5100 35.320 4.27% 13:05 13:35 13:44 14:14 14:20 14:507/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 7/18/24 Spike recovery Specification between 85 - 115% 3-Sets of Spike Recoveries Requiered 16:00 16:30 17:1016:40 17:31 18:01 11:29 11:35 12:05 12:10 12:40 15:14 7/18/24 7/18/24 7/18/24 7/18/24 15:44 7/18/24 7/18/24 10:591 1 1 1 1 1 1 1 1 1 Page 4 RM 30B Unit 1 Cal. Curve Used Train ID 1A 1B 2A 2B 3A 3B 4A 4B 5A 5B 6A 6B 7A 7B 8A 8B 9A 9B 10A 10B 1 1 1 1 1 1 1 1 1 1 RED is "Input Data" Black is "Calculation" FALSE 0.5 AGREE Spike Mass (ng) Field (Spike) Recovery "R" Between 85% & 115% Mosture (%) Std Sample Volume (Std L) Wet Basis Concentraion (µg/m3) - Spike Mass Avg. Wet Basis Concentration (µg/m3) (%) Relative Deviation µg/dscm Dry Basis Concentration (µg/dscm) Avg Dry Basis Concentration (µg/dscm) 22.990 1.785806873 2.006525 23.295 1.635582743 1.837733 22.990 1.452728230 1.638538 23.236 1.502977018 1.695214 22.913 1.210575656 1.368655 23.196 1.155005389 1.305829 23.197 1.805999741 2.034746 50.00 98.41%23.205 1.776307485 2.001293 23.177 1.654732925 1.870389 50.00 91.56%23.296 1.503488711 1.699433 22.882 1.333610698 1.508609 50.00 95.23%23.170 1.265527838 1.431593 22.964 1.242470650 1.407420 23.041 1.312265093 1.486481 22.862 1.322389773 1.498119 23.015 1.083479253 1.227460 22.932 1.174273940 1.330019 22.901 1.345110738 1.523514 23.046 1.351198646 1.527814 23.111 1.351607806 1.528277 11.73% 11.71% 11.56% 1.710694808 4.39%1.92213 1.477852624 1.70%1.66688 1.182790522 2.35%1.33724 1.299569268 2.62% 1.47010 1.277367871 2.73% 1.44695 11.00% 11.34% 11.55% 11.24% 11.53% 11.60% 11.72% 1.791153613 0.83% 2.01802 1.579110818 4.79% 1.78491 1.202934513 9.93% 1.36279 1.259692339 6.78% 1.42677 1.351403226 0.02% 1.52805 Page 5 4? HolcrM September 13,2024 State of Utah Utah Division of Air Quality P.O. Box 144820 Salt Lake City, UT 84116 Holcim (US), lnc.'s Devil's Slide Cement Plant Title V Operating Permit No. 2900001004 RATA July 18,2024 To Whom lt May Concern, Holcim (US) lnc. ("Holcim") submits the enclosed information in relation to performance testing conducted July 18,2024 at the Devil's Slide Cement Plant. Find enclosed the compliance test report and certification of RATA testing at the Kiln exhaust. The RATAs were performed on Oz, COz, NO,, SOz, THC, flow, and Hg on July 18,2024 with passing results. Certification statements are included. Should you have any questions, please contact Clinton Badger, Environmental Manager at 801- 829 -21 22 or clinton. bad ger@ ho lci m. com. Sincerely,+ Javier Sosa Ortiz Plant Manager Enclosures: RATA Certification (1), Continuous Emission Monitoring System Relative Accuracy Test Audit Report (2) Holcim (US) lnc. 6055 E. Croydon Rd Morgan, Utah 84050 Phone 801 829 6821 www.holcim.com/us tjT.r\H DEPARTTTENT OF ENVIRONMENTAL QUAIJTY llq,'ul do\ t (ercd sEP 1i tl"! DIV]S]ON OF AIR OUAUTY O HoLctM Holcim (US) lnc. 6055 E. Croydon Rd. Morgan, Utah 84050 Phone 801 8296821 www. holcim.com/us Annual RATA - Holcim Devil's Slide Rotary Kiln Exhaust July 18,2024 Gertification ln accordance with the testing protocol for the enclosed report, testing was conducted while the source was operating at the rate and or condition specified in the applicable approval order of 50% or greater production levels. During testing, the kiln and cooler operations were representative of normal conditions and operated under such conditions as specified in the permit by the Executive Secretary. I certify, based on information and belief formed by reasonable inquiry, the statements and information contained in the report are true, accurate and complete. g ltaf zozl Date Javier Sosa Ortiz Plant Manaoer Print or type the name and title of Responsible Official @lroF! eruvlnoNMENrAL euAtrry $anl 4el t{er td Signature of a Responsible Official for the Source DIVISION OF AIR OUAI.Iry UJ-(d trl9. () o{dt{(d+,ao E Gontinuous Emissions Monitoring System Relative Accuracy Test Audit Report Holcim (US) !nc. Devil's Slide Cement Manufacturing Facility Morgan, Utah Report No. M242910A July 18,2024 Rotary Kiln Exhaust (K-1) mostardi?platt Continuous Emissions Monitoring System Relative Accuracy Test Audit Report Holcim (US) lnc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-l ) Morgan, Utah July 18,2024 Report Submittal Date September 6, 2024 UT/.ll DEpAA]uI_i{T OF EI'IVI}TONMEMHL QUAUry t{an a "le li tareal SEP i ': ,?,'l!' DMSION OF AIR OUAUTY @ Copyright2024 All rights reserved in Mostardi Platt Report No. M2429104 TABLE OF CONTENTS 1.0 EXECUTIVE SUMMARY............... ............1 2.0 TEST METHODOLOGY........... .................2 Method 1 Sample and Velocity Traverse Determination................. .................2 Method 2 Volumetric Flow Rate Determination................. ..........-.2 Method 3A Oxygen (Oz) Determination ......................3 Method 25A Total Hydrocarbons (THC) Determination ................ ...................3 Method 30B Mercury Determination................. ..........4 Method 320 Fourier Transform lnfrared (FTIR) Detector for Moisture .............4 3.0 TEST RESULT SUMMAR|ES................. ......................6 APPENDICES Appendix A - Test Section Diagrams ....................... 18 Appendix B - Sample Train Diagrams.............. ........21 Appendix C - Calculation Nomenclature and Formulas ..............25 Appendix D - Reference Method Test Data .............35 Appendix E - Continuous Emissions Monitoring System Data and Plant Operating Data...................63 Appendix F - Field Data Sheets .............75 Appendix G - Calibration and Response Time Data .................116 Appendix H - Calibration Gas Cylinder Data ........... .................. 139 Appendix I - Mercury Laboratory Analysis..... .........147 Appendix J - Mercury QA/QC Data ........... .............152 Project No. M242910A Rotary Kiln Exhaust (K-1) @Mostardi Platt 1.0 EXECUTIVE SUMMARY Mostardi Platt conducted a Continuous Emissions Monitoring System (CEMS) relative accuracy test audit (RATA) program for Holcim (US) lnc. at the Devil's Slide Cement Manufacturing Facility in Morgan, Utah, on the Rotary Kiln Exhaust (K-1) on July 18,2024. This report summarizes the results of the test program and test methods. The test location, test date, and test parameters are summarized below. The purpose of the test program was to demonstrate the relative accuracies of the Rotary Kiln Exhaust Oz, COz, NO,, SOz, THC, Hg, and Volumetric Flow analyzers during the specified operating condition. The test results from this test program indicate that each CEMS meets the United States Environmental Protection Agency (USEPA) annual performance specification for relative accuracy and certification as published in 40 Code of Federa! Regulations Part 60 (40cFR60). Project No. M2429104 Rotary Kiln Exhaust (K-1) TEST INFORMATION Test Location Test Dates Test Parameters K-1 July 18,2024 Oxygen (Oz), Carbon Dioxide (COz), Nitrogen Oxides (NO,), Sulfur Dioxide (SOz), Total Hydrocarbons (THC), Mercury (Hg), and Volumetric Flow TEST RESULTS Parameter Unlts Requlred Performance Actual Performance Oz % (Wet)s20.0o/o of the mean reference method value 10.40yo COz o/o (Wet)s20.0o/o of the mean reference method value 5.660/o metric ton/hr < 2O.Oo/" of the mean reference method value 5.85o/" NO, ppmvw s20.0o/o of the mean reference method value 5.63Yo lb/hr 320.0o/o of the mean reference method value 13.680/o SOz ppmvw s20.0% of the mean reference method value 17.99Yo lb/hr s 10.0% of the applicable standard of 475 lb/hr 0.27o/o THC ppmvd @7o/o Oz sz0.Oo/" of the mean reference method value 10.32Yo Volumetric Flow scfh s 10.0o/o of the mean reference method value 9.57o/o Hg pg/scm < +/- 1.0 ug/scm of the mean reference method value 0.485 ug/scm 1 of 159 @Mostardi Platt All CEMS monitor information is as follows: The identifications of the individuals associated with the test program are summarized below. 2.0 TEST METHODOLOGY Emission testing was conducted following the United States Environmental Protection Agency (USEPA) methods specified in 40CFR60, Appendix A in addition the Mostardi Platt Quality Manual. Schematics of the test section diagrams and sampling trains used are included in Appendix A and B respectively. Calculation nomenclature are included in Appendix C. Copies of analyzer print-outs for each test run are included in Appendix D. CEM data and process data as provided by Holcim (US) lnc. are also included in Appendix E. The following methodologies were used during the test program: Method 1 Sample and Velocity Traverse Determination Test measurement points were selected in accordance with USEPA Method 1, 40CFR60, Appendix A. The characteristics of the measurement location are summarized below. Method 2 Volumetric Flow Rate Determination Gas velocity was measured following USEPA Method 2, 40CFR60, Appendix A, for purposes of calculating stack gas volumetric flow rate. An S-type pitot tube, 0-1O-inch differential pressure Project No. M2429104 Rotary Kiln Exhaust (K-1) Locatlon Make Model Serlal Channe! K-1 ABB ACFs000 3.368022.6 0 ABB MultiFlD 14 3.344762.',|0 Sick SP 1OO 143/,8410 0 TEST PERSONNEL INFORMATION Location Address Gontact Test Facility Holcim (US) lnc. 6055 East Croydon Road Morgan, UT 84050 Clinton Badger Area Manager, Environment & Public Affairs (801) 829-2122 Clinton.badoer@holcim.com Testing Company Supervisor MostardiPlatt 7715 CommercialWay, Suite 155 Henderson, Nevada 8901 1 Chris Eldridge Project Manager (630) 993-2100 (phone) celd ridoetD m n-ma il -cnm TEST POINT INFORMATION AT ROTARY KILN EXHAUST Stack Dlmenslons llnchesl Stack Area (Square Feetl Upstream Dlameters Downstream Dlameters Tesi Parameter Number of Sampllng Polnts 131.5 94.27 2.5 10.9 Oz, COz, SOz, NOx, Hg, and THC 3 Volumetric Flow 16 2 of 159 @[,lostardi Platt gauge, and K-type thermocouple and temperature readout were used to determine gas velocity at each sample point. All of the equipment used was calibrated in accordance with the specifications of the Method. Copies of field data sheets are included in Appendix F. Calibration data are presented in Appendix G. This testing met the performance specifications as outlined in the Method. Method 3A Oxygen (Oz) Determination Stack gas Oz concentrations were determined in accordance with USEPA Method 3A for volumetric flow molecular weight and the Oz RATA. A Servomex analyzer was used to determine the Oz concentrations in the manner specified in the Method. The instrument has a paramagnetic detector and the Oz operates in the nominal range of 0% to 25o/o with the specific range determined by the high-level calibration gas. High-range calibrations were performed using USEPA Protoco! gas. Zero nitrogen (a low ppm pollutant in balance nitrogen calibration gases) was introduced during other instrument calibrations to check instrument zero. High- and a mid- range % Oz levels in balance nitrogen were also introduced. Zero and mid-range calibrations were performed using USEPA Protocol gas after each test run. Copies of the gas cylinder certifications are found in Appendix H. This testing met the performance specifications as outlined in the Method. Method 25A Total Hydrocarbons (THC) Determination The Method 25A sampling and measurement system meets the requirements for stack sampling of THC set forth by the USEPA. ln particular, it meets the requirements of USEPA Reference Method 25A, "Determination of Total Gaseous Organic Concentration Using a Flame lonization Analyzer," 40CFR60, Appendix A. This method applies to the measurement of total gaseous organic concentration of hydrocarbons. With this method, the gas sample was extracted from the sample location through a heated Teflon sample line to the analyzer. The flame ionization detector (FlD) used during this program, was a Thermo 51i High- Temperature Hydrocarbon Analyzer. lt is a highly sensitive FID that provides a direct reading of organic vapor concentrations with linear ranges of 0-10, 100, 1000, and 10,000 ppm by volume. The instrument was calibrated using ultra-zero air and propane in air EPA Protocol standards for the total hydrocarbon (THC) determination. The calibrations were performed before and after sampling with calibration checks performed between each test run. Sample times and locations were logged simultaneously on data loggers. The calibration data are found in Appendix G and copies of the calibration gas cylinder certifications are found in Appendix H. Project No. M242910A Rotary Kiln Exhaust (K-'l) 3 of 159 @ft'lostardi Platt Method 30B Mercury Determination Paired trains were utilized sampling three test points per test run. Per Method 308 sampling, each sample was collected on the paired in-situ sorbent traps. A tube of silica was used to capture remaining moisture prior to the sample reaching the gas metering system. The sample train used for this test program was designed by APEX, lnc. and meets al! requirements for Method 30B sampling. All samples were analyzed onsite utilizing an Ohio Lumex, lnc. analyzer for tota! gaseous mercury. Sample analysis data and mercury quality assurance and control data are found in Appendix I and Appendix J, respectively. All of the equipment used was calibrated in accordance with the specifications of the Method. Method 320 Fourier Transform lnfrared (FTIR) Detector for Moisture, COz, NOx, and SOz Determination Extractive Fourier transform infrared (FTIR) spectrometry following USEPA Method 320 was performed for determination of moisture, COz, NOx, and SOz. FTIR technology works on the principle that most gases absorb infrared light. This is true for a!! compounds with the exception of homonuclear diatomic molecules and noble gases such as: Nz, Oz, Hz, He, Ne, and Ar. Vibrations, stretches, bends, and rotations within the bonds of a molecule determine the infrared absorption distinctiveness. The absorption creates a "fingerprint" which is unique to each given compound. The quantity of infrared light absorbed is proportionalto the gas concentration. Most compounds have absorbencies at different infrared frequencies, thus allowing the simultaneous analysis of multiple compounds at one time. The FTIR software compares each sample spectrum to a user-selected list of calibration references and concentration data is generated. FTIR data was collected using an MKS MultiGas 2030 FTIR spectrometer. Analyte spiking was performed to assure the ability of the FTIR to quantify analytes in the presence of effluent gas. All analyte spikes were introduced using an instrument grade stainless steel rotometer. All QA/QC procedures were within the acceptance criteria allowance of Method 320. Projecl No. M2429104 Rotary Kiln Exhaust (K-1) 4 of 159 @Mostardi Platt FTIR QA/QC Procedures oA/ac Specification Purpose Callbration Gas Analyte Dellvery Frequency Acceptance Criteria Result M32O'.Zero Verify that the FTIR is free of contaminants & zero the FTIR Nitrogen (zero)Direct to FTIR pre/post test < MDL or Noise Pass M320: Calibration Transfer Standard (CTS)Direct Verify FTIR stability, confirm optical path length Ethylene Direct to FTIR PretesUpost lest +l- 5% cerl. value Pass M320: CTS Response Verify system stability, recovery, response time Ethylene Sampling System pretest +l'5o/o of Direct Measurement Pass M320:Zero Response Verify system is free of contaminants, system bias Nitrogen oxide Sampling System pretest Bias correct data Pass M320:Analyte Spike Verify system ability to deliver and quantify analyte of interest in the presence of other effluent gases Acetaldehyde Dynamic Addition to Sampling System, -1:10 effluent pretest and minimum 3 times throughout testing +l- 30o/o theoretical recovery Pass Note: The determined concentrations from direct analyses were used in all system/spike recovery calculations. Analyte Spiking Spiking was performed prior to testing to verify the ability of the sampling system to quantitatively deliver a sample containing acetaldehyde and methano! from the base of the probe to the FTIR. Analyte spiking assures the ability of the FTIR sampling system to recover acid gases in the presence of effluent gas. As part of the spiking procedure, samples were measured to determine native acetaldehyde and methanol concentrations to be used in the spike recovery calculations. The analyte spiking gases contained a low concentration of sulfur hexafluoride (SFo). The determined SFo concentration in the spiked sample was used to calculate the dilution factor of the spike and thus used to calculate the concentration of the spiked Acetaldehyde. The spike target dilution ratio was 1:10 or less. Spike recovery as calculated per Section 9.2.3 (3) of Method 320. QA/QC data are found in Appendix G. Copies of gas cylinder certifications are found in Appendix H. All concentration data were recorded on a wet, volume basis. The sample and data collection followed the procedures outlined in Method 320. Project No. M2429104 Rotary Kiln Exhaust (K-1) 5 of 159 @Mostardi Platt 3.0 TEST RESULT SUMMARIES Projeci No. M2429104 Rotary Kiln Exhaust (K-1) Cllent: Holcim (US) lnc. Faclllty: DeMls Slide Cement Plant Prolec{ #: M242910 Locatlon: Main Kiln Date:7118124 Ted Method: 3A 02 % (wet) RATA 1=accept 0=reJec{ Test Run Test Date Start Time End Time RM02% (wet) cEM 02 % (wet) (RM€EM) Dlfference (di) (RMCEM) Dlfierence2 (di2) 1 1 07t18t24 10:59 11:28 10.5 9.4 1.1 1.21 1 2 07t18t24 11:35 12:M 10.3 9.3 't.0 1.00 ,l 3 07t18124 '12:10 12:39 10.0 9.2 0.8 0.64 ,l 4 07118124 13:05 13:34 10.5 9.4 1.1 't.21 1 5 07t18t24 '13:44 14:13 10.3 9.3 1.0 1.00 ,|6 07t1u24 14:19 14:48 10.2 9.2 1.0 1.00 0 7 07t18t24 15:14 15:43 10.2 9.1 1.1 1.21 1 8 07t18t24 16:00 16:29 10.1 9.1 1.0 1.00 1 I 07t18124 16:39 17:08 10.2 9.2 1.0 1.00 1 10 07t18124 17:31 18:00 10.2 9.2 1.0 1.00 n 9 (0.e75)2.306 Mean Reference Method Value 10.256 Rtl avq Mean CEM Value 9.256 cEt avo Sum of Dlfferences 9.000 dl Mean Dlfierence 1.000 d Sum of Dlfhrences Squared 9.060 dlz Standard Devlation 0.087 sd Conlidence Coeffi cient 2.5oh Error (1 {aill 0.067 cc Relatlve Accuracy 10.40 RA 6 of 159 @ltlostardi Platt Client: Holcim (US) lnc. Facility: Devils Slide Cement Project #: M242910 Plant Location: Main Kiln Test Method: 320 CO2% (wet) RATA CEM Analvzer lnformation COz Monitor/Mode!:ABB ACFsOOO CO2 Serial#:3.368022.6 1=accept 0=reject Tesil Run Test Date Start Time End Time RM CO2 % (wet) cEM CO2 % (wet) (RM4EM) Dlfference (di) (RM€EM) Difference2 (di2) 0 1 07t18t24 10:59 11:28 14.0 15.4 -1.4 1.96 1 2 07t18t24 11:35 12:M 14.3 15.5 1.2 1.44 1 3 07t18t24 12:10 12:39 14.8 15.7 4.9 0.81 1 4 07118124 13:05 13:3tl 14.6 15.3 4.7 0.49 1 5 07t18t24 13:44 14:13 14.9 15.5 4.6 0.36 1 6 07118t24 14:19 14:48 15.'t 15.6 -0.5 0.25 1 7 07t18t24 15:14 15:43 15.2 15.7 -0.5 0.25 1 I 07t18t24 16:00 16:29 15.2 15.7 4.5 0.25 1 I 07t18t24 16:39 17:08 15.1 15.6 {.5 0.25 I 10 07t18t24 17:31 18:00 15.1 15.6 {.5 0.25 n I t(0.s75)2.306 Mean Refurence Method Value 14.922 RM avq Mean CEM Value 15.578 CEM avq Sum of Differences 6.900 di Mean Diffurence {.656 d Sum of Differences Squared 4.350 di2 Standard Deviation 0.246 sd Confidence Coefficie nt 2.5oh Error (1 -ta il)0.189 cc Relative Accuracv 5.66 RA Project No. M2429104 Rotary Kiln Exhaust (K-1) 7 of 159 @Mostardi Platt Client: Holcim (US) lnc. Facility: Devils Slide Cement Plant Project #: M242910 Location: Main Kiln Date:.7118124 Test Method: 320,2 CO2 metric tons/hr RATA CEM Analyzer lnformation CO2 Monitor/Mode!:ABB ACFsOOO CO2 Serial #:3.368022.6 l=accept 0=reject Test Run Iest Date Start Time End Time RM CO2 % metric tons/hr cEM CO2 metric tons/hr (RM4EM) Difference (di) (RM4EM) Difference2 (di2) 1 1 07118t24 10:59 11:28 82.00 82.50 4.50 0.2500 1 2 07t18124 11:35 12:04 85.19 80.80 4.39 19.2721 0 3 07t18t24 12:10 12:39 88.29 82.70 5.59 31.2481 I 4 07118124 13:05 13:34 84.66 80.90 3.76 14.1376 1 5 07t18t24 1344 14:13 85.46 82.20 3.26 10.6276 1 6 07t18t24 14:19 14:48 85.58 80.80 4.78 22.UU 1 7 07t18t24 15:14 15:43 87.20 82.60 4.60 21.1600 1 I 07t18124 16:00 16:29 85.88 81.20 4.68 21.9024 1 9 07t18t24 16:39 17:08 86.07 82.10 3.97 15.7609 1 10 07118124 17:31 18:00 86.77 82.20 4.57 20.8849 (0.e7s) Mean Reference Method Value Mean GEM Value Sum of Differences Mean Difference Sum of Differences Squared Standard Deviation Confi de nce Coefft cient 2.5Yo Error (1 -ta i l) Relative Accuracy 9 2.306 85-423 RM avq 81.700 CEM avq 33.510 di 3.723 d 146.84 di2 1.661 sd 1.277 CG 5.85 RA Project No. M2429104 Rotary Kiln Exhaust (K-1 ) OMostardi Platt Client: Holcim (US) lnc. Facility: Devils Slide Cement Plant Project #: M242910 Location: Date: Test Method: NOx ppmvw RATA CEM Ana lyze r lnformation Main Kiln 7t18t24 320 NO, Monitor/Model:ABB ACFsOOO NO, Serial #:3.368022.6 1=accept 0=reject Tes( Run fed Date Start Time End Time RM NOx ppmvw CEM NOx ppmvu, (RMCEM) Difference (di) (RMCEM) Difference2 (di2) 1 1 07t18124 10:59 11:28 330.7 3U.2 -3.5 12.37 1 2 07t18t24 11:35 12:04 294.8 290.4 4.4 19.17 1 3 07118124 12:10 12:39 293.0 281.8 11.2 126.32 1 4 07t18124 13:05 13:34 292.O 278.6 13.4 178.40 1 5 07118124 13:44 14:13 283.0 269.2 13.8 191.39 1 6 07t18t24 14:19 14:48 292.0 277.0 15.0 224.10 1 7 07t18t24 15:14 15:43 285.2 269.3 15.9 251.93 1 8 07t18124 16:00 16:29 2U.5 268.0 16.5 273.82 1 I 07118t24 16:39 17:08 288.6 272.8 15.8 249.01 0 10 07t18t24 17:31 18:00 291.2 274.0 17.2 295.02 n I (0.e75)2.306 Mean Refurence Method Value 293.751 RM avq 282.367 CEM avo Sum of Differences 102-462 di Mean Difference 11.385 d Sum of Differences Squared 1526.514 di2 Standard Deviation 6.708 sd Confi de nce Coeffi cie nt 2.5oh Error (1 -ta i !l 5.157 cc Relative Accuract 5.63 RA Project No. M2429104 Rotary Kiln Exhaust (K-1) @Mostardi Platt Clienr: Hotcim (Us;T- Facitity: DeMls Stide Cement ptant Project #: M242910 Location: Main Kiln Test Method: 320, 2 NO, lb/hr RATA 1=accept 0=reiect Test Run Test Date Start Time End Time N\rx uonal #3.368022.6 RM NOI lb/hr cEM NOx lb/hr (RM4EM) Difference (di) (RMCEM) Difference2 (di2)1 1 07t18t24 10:59 1 2 4/.5.04 411.2007t18t2411:35 12:04 33.84 J145.145603oTtlAtrA12:10 403.78 349.70 54 0R 2924.646/i 1 4 12:39 401.62 u2.70olt18t2413:05 13:34 c6.92 u71.5664 1 5 07t18t24 13:44 389.43 340 0n 49.43 2443.324914:13 374.661607t18t2414:19 14:48 5t6.20 46.46 2158.5316 1 7 07/18t24 15:14 15:43 382.21 330.00 52.21 2725.88r1 1 8 07t18t24 16:00 16:29 371.U 326.20 I san 2527.0729 1 9 07t18t24 16:39 320 00 51.34 2635.795617:08 379.1811007t18t2417:31 18:00 J3U.90 48.2A 2330.9584384.49 332.30 52.19 2723.7961 ---2.306E5"6t -140-54--€s-.Tdo=- RM avo eEU avg ---r!!Yrv..es- M;-^ r;-di Sum of Diffe;;o". -q-*-4,A.Ar6 - 21615.156 d - oEnGEZffii d,2 confidence coefliffi 0 sd ----=-l_Relative Accuracv ,la cc {A Project No. M242}1OA Rotary Kitn Exhaust (K_1)@Mostardi platt Gient Holcim (US) lnc. Facility: Devils Slide Cement Plztt Project li [1242910 Location: lvlain Kiln Dnb:7t1U24 Test tlethod: 320 SO2 ppmvw RATA CEll Ana lyre r I nfiormation SO, Monibr/illodel:ABB ACFsOM SOr Sedal il 3.368@2.6 l=accept (Freiec{ Ted Run Test llab Start Time End Time Rlr, SO2 pp,mYw cElt so2 ppmYv (Ril€Elr) [Iftrence (di) (F[ri4E l Diftrence2 (d.1 1 1 07t18124 10:59 '11.28 4.1 4.9 {.8 0.67 1 2 07t1u24 11:35 12:M 2.6 2.0 0.6 0.32 'l 3 07t1u24 12:10 l2:39 3.6 3.3 0.3 0.07 1 4 07t1u24 13:05 13:34 2.6 2.5 0.1 0.00 1 5 07n8t24 13:M 14:13 1.5 1.3 0.2 0.05 1 6 07t1u24 14:19 14:tE 't.4 'i..2 0.2 0.06 1 7 07t18t24 15:14 15:4i 1.6 1.8 4.2 0.05 1 8 07t18124 16:00 16:29 2.6 2.'.|0.5 0.20 0 I 07t18124 16:39 17:08 2.5 1.9 0.6 0.39 1 t0 07t1u24 17:31 18:00 1.4 'l .2 0.2 0.05 n I (0.e75 2.9,6 tlean ReErcnce }bthod Value z.3tt3 RM avg rean cExt vatue 2.ru6 sEr avg Sum of Diftrencer 0.067 da Ilean Dafrrrence 0.t07 d Sum of DiftrencesSquand 1.171 di2 Standard [bviation 0.413 d gonnoenoe goemctenr af,b Eror tr{at!0.318 cc Relalive Accuracl 17.99 RA Project No. M2429104 Rotary Kiln Exhaust (K-1) 11 of159 @Mostardi Platl Client: Holcim (US)lnc. Location: Main Kiln Facility: Devils Slide Cement Plant Tesil Method: 320,2 ProJect #: M242910 Applicable Standard: 475 SO2 lb/hr RATA CEM Analyzer lnformation SOz Monitor/Model:ABB ACFsOOO SO, Serial #:3.368022.6 1=accept 0=reject Test Run Tesf Date Start Time End Time RM SO2 lb/hr cEM SO2 lb/hr (RM4EM) Difference (di) (RM4EM) Difference2 (di') 1 1 07t18t24 10:59 11:28 7.6 8.40 4.77 0.5929 1 2 07118t24 11:35 12:M 4.9 3.30 1.58 2.496/i 0 3 07118t24 12:10 12:39 6.8 1.07 5.71 32.6041 1 4 07t18124 13:05 13:34 4.7 4.30 0.44 0.1936 1 5 07t18124 13:44 14:13 2.8 2.30 0.50 0.2500 1 6 07t18t24 14:19 14:48 2.6 1.00 1.62 2.6244 1 7 07t18t24 15:14 15:43 2.9 3.00 {.11 0.0121 1 8 07t't8t24 16:00 16:29 4.6 3.40 1.23 1.5129 1 9 07t18124 16:39 17:08 4.6 3.20 1.42 2.0164i 1 10 07t18124 17:31 18:00 2.6 3.10 {.48 0.2304 n I t(0.975)2.306 Mean Reference Method Value 4.159 RM avo Mean CEM Value 3.556 CEM avg Sum of Differences 5.430 di Mean Difference 0.603 d Sum of Differences Squared 9.929 di2 Standard Deviation 0.912 sd Confi dence Coefficient 2.5o/o Error (1 {ai ll 0.701 BC Relative Accuracv - APS o.27 RA Project No. M2429104 Rotary Kiln Exhaust (K-'l) 12 of 159 @Mostardi Platt Client: Holcim (US) lnc. Location: Main Kiln Facility: Devils Slide Cement Plant Test Method: 25A, 3A Project #: M242910 THC ppmvd @ 7% 02 RATA CEM Ana lyzer lnformation THC Monitor/Model:ABB Multi FID 14 THC Serial#:3.344762.1 1=accept 0=reject Test Run Te$ Date Start Time End Time RM THC ppmvd @ 7% 02 CEM THC ppmvd @ 7% 02 (RM4EM) Difference (di) (RMCEM) Difference2 (di2) 1 I 07t18t24 10:59 11:28 33.5 30.5 3.0 8.89 1 2 07t18124 11:35 12:04 28.1 29.9 -1.8 3.35 1 3 07t18t24 12:10 12:39 28.2 30.4 -2.2 4.85 1 4 07t18t24 13:05 13:34 32.3 29.6 2.7 7.29 1 5 07t18t24 13:44 14:13 31.7 29.0 2.7 7.27 1 6 07118t24 14:19 14:48 32.7 30.0 2.7 7.08 1 7 07t18t24 15:14 15:43 34.8 31.8 3.0 9.18 0 8 07t18124 16:00 16:29 39.9 34.6 5.3 27.94 1 I 07t18t24 16:39 17:08 36.1 32.4 3.7 13.42 1 10 071'tBt24 17:31 18:00 32.6 31.5 1.1 1.20 n 9 (0.e75)2.306 Mean Reference Method Value 32.212 RM avq Mean CEM Value 30.568 CEM avq Sum of Differences 14.796 di Mean Difference 1.W d Sum of Differences Squared 62.529 di2 Standard Deviation 2.185 sd Confide nce Coefficie nt 2.5Yo Error (1 -ta i ll 1.680 cc Relative Accuracr 10.32 RA Project No. M2429104 Rotary Kiln Exhaust (K-1) 13 of 159 @Mostardi Plaft Client: Holcim (US) lnc. Facility: Der,il's Slide Cement Plant Project #: M242910 Test Location: Main Kiln Test Date: 711812024 Tes{ Method: 2 Vohrrretric Eow RATA - Millqr CEM Analvzer lnformatlon Flow Monitor/Model:Sick SP 100 Flow Serial # :143r'8410 1=accept 0=reject Test Run Test Date Start Time End Time Reference Method Flow SCFH CEM Flow SCFH (RM4EM) Difference (di) (RM4EM) olfference 2 (dl2) 1 1 07t18124 '10:59 1'l:29 11.271.461 10,306,036 965.426 932.046.628.460 0 2 07t18124 11:35 12:OS 11.472.199 10.083.468 1,388,731 '1 .928.572.806.379 1 3 07t18124 12:10 '12:40 11.478,385 10.188.565 1.289.820 1 .663.635.873.814 1 4 07t18124 13:05 1 3:35 11.171.507 10,208,973 962,533 926.470.616.311 1 5 07t18t24 13:M 14:14 11.085.409 10.211.647 874.762 76s.209. 1 3s.489 1 6 07t18t24 14:20 14:50 10.963.877 9,975,403 988.473 977.O79.538.711 1 7 07t18t24 15:14 15:44 1't.056.675 1 0.142.380 9'.t4.295 835.934.527.336 1 8 07t18t24 16:00 16:30 10.929.755 9.998.990 930.765 866.322.870.080 1 I 07t18124 16:40 17:10 11,004,593 10,163,755 840.838 707.008.s86.439 1 10 07t18124 17:31 18:01 11.059.349 10.1 55.948 903.401 816. 132.887.915 n 9 (0.97s)2.306 Mean Reference Method Value 1t t't 3ss6.638 RM avo Mean CEM Value 101 50188.522 UEM avq Sum of Diffurences 8670313.039 di Mean DlffiErence 963368.115 d Sum of Differences Squared 8489M1064555.420 ci2 Standard lleviation 130928.383 sd ]onfidence Coefficient 2.5% Error (1{ail)100640.284 DC Relative Accuracv 9.57 RA Project No. M2429104 Rotary Kiln Exhaust (K-1) OMostardi Platt Client: Holcim (US)lnc. Location: Main Kiln Plant: Der,il's Slide Cement Plant Date:.7118124 Project #: M242910 Test Method: Sorbent Hg (308) Hg ug/wscm RATA CMMS Monltor lnformation Hg Monitor/Model:TEKMN 2537X Hg Serial#:6014 1=accept 0=reject Tes( Run Tesil Date Start Time End Time RM ug/wscm CMMS ug/wscm (RMCMMS) Difference (d.) (RMCMMS) Difference2 (di2) 1 1 07118t24 10:59 11:29 1.76 1.20 0.56 0.3136 1 2 07118t24 11:35 12:05 1.49 1.10 0.39 o.1521 1 3 07t18124 12:10 12:40 1.21 1.07 0.14 0.0196 0 4 07t18t24 13:05 13:35 1.83 1.00 0.83 0.6889 1 5 07118t24 13:44 14:14 1.6'l 1.00 0.61 0.3721 1 6 07118124 14:20 14:50 '1.35 1.00 0.35 0.1225 1 7 07t18124 15:14 15:M 1.35 1.00 0.35 0.1225 1 8 07118t24 16:00 16:30 1.24 1.10 0.14 0.0196 1 9 07t18t24 16:40 17:10 1.44 1.09 0.35 0.1225 1 10 07118124 17:31 18:01 1.43 1.05 0.38 0.1M4 (0.02s) Mean Reference Method Value Mean CMM Value Sum of Differences Mean Difference Sum of Differences Squared Standard Deviation Confi de nce Coeffi cie nt 2.5oh Error (1 -ta i l) Relative Accuracv.APS 9 2.306 1.431 RM avo 1.068 CMM AVO 3.270 di 0.363 d 1.389 di2 0.158 sd 0.122 cc 0.485 RAA ^ Relative Accuracy based on nean diff erence of +^1 .0 ug/w scm plus CC f or enission sources <5.0 ugAiv scm of nrercury Project No. M2429104 Rotary Kiln Exhaust (K-'l) @Mostardi Platt 4.0 CERTIFICATION Mostardi Platt is pleased to have been of service to Holcim (US) lnc. lf you have any questions regarding this test report, please do not hesitate to contact us at 630-993-2100. As the program manager, I hereby certify that this test report represents a true and accurate summary of emissions test results and the methodologies employed to obtain those results. The test program was performed in accordance with the test methods and the Mostardi Platt Quality Manual, as applicable. MOSTARDI PLATT Project Manager Christopher S. Eldridge Project No. M242910A Rotary Kiln Exhaust (K-1) Quality Assurance Richard J. Sollars 16 of 159 @fi'lostardi Platt APPEND!CES Project No. M2429104 Rotary Kiln Exhaust (K-1) 17 of 159 @Mostardi Platt Appendix A - Test Section Diagrams Project No. M242910A. Rotary Kiln Exhaust (K-1) 18 of 159 @Mostardi Platt Date: Test Location: Duct Diameter: Duct Area: No. Points Across Diameter: No. of Ports: GASEOUS TRAVERSE FOR ROUND DUCTS (Oz, COz, NOx, SOz, Hg and THC traverses) Length > 1l2Oia.T Length > 2 Dia.I Job:Holcim (US) lnc. Devil's Slide Cement Manufacturing Facility Morgan, UT July 18,2024 Rotary Kiln 131 .5 lnches 94.31 Square Feet 3 1 Project No. M242910A Rotary Kiln Exhaust (K-1) 19 of 159 @Mostardi Platl EQUAL AREA TRAVERSE FOR ROUND DUCTS (Volumetric flow rate) Job: Holcim (US) lnc. Devil's Slide Cement Manufacturing Facility Morgan, UT Date: July 18,2424 Test Location: Rotary Kiln Duct Diameter: 131.5 lnches Duct Area: 94.31 Square Feet No. Points Across Diameter: 8 No. of Ports: 4 ** > 1l2Dia.T Length > 2 Dia.I Project No. M2429104 Rotary Kiln Exhaust (K-1) 4 3 ? 1 't234 I 2 3 4 20 of 159 OMostardi Platt Appendix B - Sample Train Diagrams ProJo€t No. M2429104 Rotary Kiln Exhaust (K-1) 7.62 cm (3 in,)' USEPA Method 2 - Type S Pitot Tube Manometer Assembly 1.90-2.S cm (0.75 -1.0 in,)' 'Suggested (lnterference Free) Pitot tube/ Thermocouple Spacing ATD-001 USEPA Method 2 Project No. M242910A Rotary Kiln Exhaust (K-l) + T- l-toItrloIr! l" USEPA Methods 3A, 25A, and 320 - Sample Train Diagram rl ETrl- r I lfi:'-rl ATD{81C USEPA Method 3l2sN32o Projec{ No. M242910A Rotary Kiln Exhaust (K-1) Rev.0.1 23 of 159 LlLl2ozt @Mostardi Platt USEPA Method 308- Mercury Sorbent Trap Sampling Train ATD{71 USEPAMethod 308 Project No. M242910A Rotary Kiln Exhaust (K-1) 1t1t2021 Appendix C - Calculation Nomenclature and Formulas Projec{ No. M2429'l0A Rotary Kiln Exhaust (K-1) 25 of 159 @ttitostardi Platl Cllent: Holcim (US) lnc. Faclllty: Dsvils Slide Coment Planl Pioj.ct t: M242910 Tr.t Loc.tlon: Main Klln Dal.. 7118124 ( 11.68 0/6 - 0.02 0,6) x = 11.75 90 THC ppmvd @ 7o/o Oz19.6 ppmvw / 242.8 CO Wm x cF=(c-cJ *-L C'" 'Co where: NOr lb/hr (1.194rE10^-7) x 11271461.1 =.145.fi NOx lb/hr SOZ lb/hr (1,56*E10^-7) x 11271461.1 = 7.63 SO2 lb/hr CO lblhr (7.266*E10^{) x 11271461.1 = 198.89 CO lb/hr Cg = Effiuent gas concentrc0on, dry basls, ppm or % c = Average gas concentratlon lndicated by gas anatfzer, dry basls, ppm or yo C! = Average of lnlual and final system calibrauon blas check responses for the zero gas, ppm or % c. = Average of lnlttal and final system callbrauon bias che* nesponses for th€ up6cale callbrauon gas, ppm or % Q* = Actual concentrauon of the upscale calibrauon gas, ppm or % Samole Calculatlons ()2 % (dry) 12.05 9o 11.98% - 0.020/o THC ppmvd O 7Vo (l2 ((20.9-7.0)/(20.9-11.7)) =33.5 330.7 NOx ppm x 4.1 SO2 ppm x Mostardi Plstt Project No. M2429104 Rotary Kiln Exhaust (K-1) v6.0 26 of 159 RATA FTIR 228123 @Mostardi Platt Clicnt; Hotcim (US) lnc.Flclllty; Oevib Slide Coment planl Projcct il: M2429tOT..t Locrtion: Main Kiln Dat t Zt1At24 Dlnc{ Racoy.ry % o, Crllb[llon Tnnrf.r St nd.rd DR-= gg.rf Rccovcry % wlth Clllbmilon Tnn3f.r Standard Syrtcm purgo i6= Syr- algg Dd syr- = e7.o Rd- 93% Dircct Racovory 7. of Analylc Splka Glt sF6 DR.r' D.r a 1gg Cm. Cmr. a.9 D&r = e6.9% Dllufion F$to, for An.h^r Splktng pp, Sptr.r D.r SpLn _ 0.,99 DF: O'"0 Rccovcry % lor Anrlytc Splk, Wth Acct ldrhyd. &- spk, - 21.1 DFT FTIR Samole Calculations t[llon Tnnrf.r St nd.rd DR- = D* 11g,q Cma CmtE lOO.3 Da - 99.4 Do' f9.a D.r - 1.7 D.n E 4.736 Ac.t ldchydc DR-c- Dq x IOO Cma Cm.E 20a.9 D&.e . roo.z% R,t 3.6 205.4 0,095 95, N,= D.r = Dq. 205.,1 RATA FTIR 228123 @Mostardi platt wharc: D&r . Recovery 9o of the cillbrauon tansfer standard direcdy to th€ anatlzerCme = 6srfi6ed a..centrauon of cailbrauon gas, pprnu6 r Concentration of the eltbruRa . Recowry % sr $g calt6766lu_o:transfer staDdard gas dlrecuy to the ana Wet, wmsy]:.c-."itlui;;";;il;;;:ff;HilHr,ffxJ;:r*mru!gr*, .::;:;i+1iili#"1;t1r.s:flf,ffi;;; - " v'J u r'uen' Dpr: . AnaMe concenb.at on ln pffu€nt drang ap"kingD.r . Concentrauon of the analvt( "t : :ruh,ttr 3[T'Hh'ffi;H"T the anarrzer' ppm xr = Nauve efilu€nt (AcetaUehyde) o-ncentration prior to anatyte splke Mostardi ptatt Project No. M242}1OA Rotary Kitn Exhaust (K_1) v6.0 27 of 159 volumetriCEoffiEE Client: Plant: Location: Run: Date: FT-004 Mp pilot Project No. M24211OA Rotary Kitn Exhaust (K_1) Holcim (US) Inc. Devil's Slide Cement plant Main Kiln MillOn Load, Run I oil18124 Moisture Content Bws = 0.110 Dry Molecular Weight Md=0.44x(o/oCO2) o/oCO2 = 15.8 Md=l;;;- Wet Molecutar Weight Average Duct Velocity Vs = 54.14 Volumetric Flow Rate Q (Actual Basis)= Vs x A x 60 + 0.32 x (o/oO2) + o/oO2 = ll.7 0.28 x %Nz o/oN2 = 72.5 Ms = Md x (l-Bws) + (18.0 x Bws) Md = 31.00 Bws = 0,110 Ms = 29.57 Vs = 85.49 x Cp x Sqft ^p (avg) x (Ts (avg) + 4601(ps x M5;;uz :? = +rs (avs) = 250.6 sqrt aP avs: 0.764^-Ps = 24.69 MS= )q\729.57 Vs= Q= 54.74 [ = 94.340 DS 460 + Ts (avg) Ps = 24.68 306,475 acfm Qs (Standard Basis)= t7.647 x e x Q = 30647S Qs = 1g4g5g scfm Qs (Standard Basis)= scfm x 60 min/hr Qs = 11,271,461 scfh Ts (avg) = 250.6 v24.4 28 of 159 4t6/2022 @Mostardi platt MOSTARDI PLATT Relative Accuracy Test Audit (RATA) Calculations Mean Difference n1std=-) dinLi=1 Standard Deviation lzr=,0? -tl,T=ra't'e) - I_______________-I n-L t Confidence Goefficient sd Lu - LO.97S-,,ln Relative Accuracv *o--W#!x1oo CN&F-029 Part 60 RA Calcs Project No. M242910A Rotary Kiln Exhaust (K-1) Rev. 1.2 11112021 29 of 159 @Mostardi Platt MOSTARDI PLATT ppm Conversion Calculations and Factors ppm to lbs/scf (ppm X) x (conversion factor X) = X lbs/scf lbs/scf to lbs/hr Dry ppm's with dry flow, and wet ppm,s with wet flow. (X lbs/scf) x (airflow scf/min) x (60 min/hr) = X lbs/hr lbs/scf to lbs/mmBtu Dry ppm's with dry diruent, and wet ppm,s with wet diruent. COz - (X lbs/scf) x (F.) x (100/COz) = X tbs/mmBtu Oz - (X lbs/scf) x (Fa) x (20.9t(20.9-Oz)) = X lbs/mmBtu Conversion Factors NO,-1.19396 x1O-7 SOz-1.6625x10'7 CN&F-026 ppM Converstion Calcs & Factors 111t2021 Project No. M24211OA Rotary Kitn Exhaust (K-1) Rev. 1.2 @Mostardi platt MOSTARDI PLATT Volumetric Air Flow Calculations Vm (std) = (Poo,+t+]) 17.647" ,-, I ]"(460 + Tm) Vw (std) :0.0477 xVlc Bws=l#*u*r*u^rrro) Md = (0.44 x o/oCO2) + (0.32 x o/o0z) + [0.28 x (100 - o/oCO2 - o/oo)) Ms = Mdx (1 - Bws) + (18 x Bws) I(rk + 460)tk = Jffi x"DP x cP x85'4e Acfm = 7s x Area (of stack or duct) x 60 scfm = Acfm x 77.647" [i7uo}5l minScfh= Scfmx60 * Dscfm=Scfmx(1 -Bws) CN&F-031 Volumetric Flow Calcs Project No. M242910A Rotary Kiln Exhaust (K-1) Rev. 1.2 11112021 31 of 159 @lvlostardi Platt MOSTARD! PLATT Volumetric Flow Nomenclature fi= Bws = cp= Md= Ms= Mw= Pbar = Pg= DH= Ps= Pstd = Acfm = Scfm= Dscfm = Q= Ts= Tm= Tstd = vs= Vm(std)= Vw(std) = Vlc= != Ap= K1 = ohEA= o/oCO2 = YoO2 = o/oN2 = 0.264 = 0.28 = 0.32 = 0.44 = 13.6 = Cross-sectional area of stack or duct, ft2 Water vapor in gas stream, proportion by volume Pitot tube coefficient, dimensionless Dry molecular weight of gas, lb/lb-mole Molecular weight of gas, wet basis, lb/lb-mole Molecular weight of water, 18.0 lb/lb-mole Barometric pressure at testing site, in. Hg Static pressure of gas, in. Hg (in. H2Ol13.6) Static pressure of gas, in.H2O Absolute pressure of gas, in. Hg = Pbar + Pg Standard absolute pressure, 29.92 in. Hg Actual volumetric gas flow rate Volumetric gas flow rate, corrected to standard conditions Standard volumetric flow rate, corrected to dry conditions ldeal gas constant, 21.85 in. Hg-ft3/'R-lb-mole Average stack gas temperature, "F Average dry gas meter temperature, oF Standard absolute temperature, 528'R Gas velocity, fUsec Volume of gas sampled, corrected to standard conditions, scf Volume of water vapor in gas sample, corrected to standard conditions, scf Volume of liquid collected Dry gas meter calibration factor Velocity head of gas, in. H2O 17.647 "R/in. Hg Percent excess air Percent carbon dioxide by volume, dry basis Percent oxygen by volume, dry basis Percent nitrogen by volume, dry basis Ratio of 02 to N2 in air, v/v Molecular weight of N2 or CO, divided by 100 Molecular weight of 02 divided by 100 Molecular weight of CO2 divided by 100 Specific gravity of mercury (Hg) CN&F-024 Nomenclature Pitol Project No. M242910A Rotary Kiln Exhaust (K-1) Rev. 1.2 111t2021 32 of 159 @Mostardi Platt B*, = MOSTARDI PLATT Moisture Calculations vwc(std) - (vr -li)l,y'Rruo = o.o47o7(vr - v,), sg6,lye \ v --.--., =(wr - wi)fonr,to: 0.04715( wr - w,)vwsg(std) - psftMw - v'v, r' _LHD L-'bar t 73.6Vm(std) = 77.64 VmY T^ Vwc@ta) * Vwss1td) Vwcgta) * Vwss Gtd) * Vm3td) Water vapor in gas stream, proportion by volume Molecular weight of water, 18.015 lb/lb-mole Barometric pressure at the testing site, in. Hg Standard absolute pressure, 29.92 in. Hg ldealgas constant, 0.048137 (in. HgXft3y(g-mole)('R) = [2 1 . 8348(i n. H g Xft 3)/(l b-mole )(" R)] I 453.592 g-mole/l b-mole Absolute average dry gas meter temperature, 'R Standard absolute temperature, 528 "R Final volume of condenser water, ml lnitial volume of condenser water, ml Dry gas volume measured by dry gas meter, dcf Dry gas volume measured by dry gas meter, corrected to standard conditions, scf Volume of condensed water vapor, corrected to standard conditions, scf Volume of water vapor collected in silica gel, corrected to standard conditions, scf Final weight of silica gel, g lnitial weight of silica gel, g Dry gas meter calibration factor Average pressure exerted on dry gas meter outlet by gas sample bag, in. HzO Density of water, 0.9982 g/ml Specific gravity of mercury (Hg) Where: B*. = M*= Pb",. = Psro = R. Tl6- Tlstd- !1 = Vi = V.n= Vm(std) = l/vwc(std) - l,Vwsg(std) - Wr= Wi = l= AH= P*= 13.6 = 17.64 = 0.04707 = Tsto/Psro ft3/ml CN&F-021 Moisture Calculations Project No. M2429104 Rotary Kiln Exhaust (K-1) Rev. 1.1 8t1012015 0.04715 = ft3/9 33 of 159 @Mostardi Platt MOSTARDI PLATT Mercury Emission Calculations Concentration ng Emission Rate CN&F-0'18 Mercury Emission Calcs Project No. M2429104 Rotary Kiln Exhaust (K-1) m3 dscf uolume sampled. x o.ozf]g|-4" "'"-""- f t, .7 x 70-e gramsng ol Sample X - lbs of mercurv mtnx dscfm x 60- = lbs of mercuryf hrV^(std)sample ' hr ng of mercury : lbs of mercury Rev. 1.2 11112021 34 of 159 @Mostardi Platl Appendix D - Reference Method Test Data Project No. M242910A- Rotary Kiln Exhaust (K-1) 35 of 159 @l\Iostardi Platt aNNs tr O F- O- E. -<pKE to o6(DtO oF9b (o(v ) -5e6 ,f ; EE g 9E € ! :: s f Ei - E iEo& Il!(Joiot- @-.Nsl oo6iNa o@@F{. 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' : og \ C a e q r{ o o o o N N t N N o 3 - o - oo o - o o o F N o F F N N o oI N N N N N N N N N N N NN N O@ N N N N N N N N N N N N N *r l ogg - * oN r o N o o a ? s a N e N @ F o N o o o F o @ o o @ E :1 . ! c! I 61 9 c? q a? a' : ' : q q q q q u? q': n q a q q q a? c? a \ ?s l - - -- N F o o F F oF - - F F F -o l - - ol O) ro 9blr ) t ocft oGotFr Z,.9o-o_= 9B :o6@ J= O E E a 9 ? Y d !t s s . : @ fr i s : :5 # ! J o= x - Y o uE s t i ooF a <Y ir g N= IPif r ci S z? E O > \ oo H L' = . ! : Er & .Eo= N@NNT -6tr ( L L.-<E FOfr E o ilElo s o @ 6 N o o @ h N N o t s b o @ o o o o o t r o N @ @ @ OI N o@ o N t s O N N o O O F N N O o t @ N o 6 O @ O a O oN q s ri si c i d .i t - ai t di .t ai .i si .i . i ni - 6i 6 i Gi - ci - - - ; - oI N N N N N O N N N N N N N N N N N N N N N N N N N N N N N sI l oogS = * r N q - os - oo o @ @ o @ o o o N o t s o a a b o s @ E :l ^ t "t q q c ? a \ n c! a? q a? a q a a q oq q u? q q q q \ q q u? <. ' t : : : : : == = : == == = = : : : = : : == = : : E : = ol No o) r, ) oFgb(o{ og50t oGox.E coo-co :o ,; a=EJ= O C E -Q Y ' i 6 6 N o- -6 > > F E} * E g o= t : . ! a G Eg * E " rE o LJ oF <! 2 \6N: J IPNi>u J ci s z? t o ; ^ s o = o- 'F i: :t s o eo _ ( go= Client: Facility: Test Location: Project #: Test Method: Test Engineer: Test Techniclan: Meter lD: Pitot lD: Pitot Type: Pitot Tube Coefficient: Probe Length: Sample Plane: Port Length: Port Size (diameter): Port Type: Duct Shape: Diameter: Duct Area: Upstream Diameters: Downstream Diameters: Number of Ports Sampled: Number of Points per Port: Total Number of Traverse Points: Operating Leve!: Moisture Balance lD: Stack Liner Material: Holcim (US)lnc. Devil's Slide Cement Plant Main Kiln M242910 2 (RATA) EV ztcl cM22 001 S-Type 0.84 8.0 Horizontal 12.00 6.00 Flange Circular 10.96 94.34 2.5 10.9 4 4 16 MillOn Deh-O1 S ft ln. tn. fr Sq. Ft. FT-004 MP Pitot Project No. M2429104 Rotary Kiln Exhaust (K-1) v24.4 47 ol 159 41612022 @Mostardi Platt lilETHOD 2 VOLUMETRIC FLOW DATA Proloct Number: Client: Faclllty: Test Locatlon: Pltot lD: Pltot Coefflclent: Probe Length, Feet: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 8 Operatlng Level: Run No.: Test Date: Start Tlme: End Tlme: Tett Englneer: Port Length, lnches: Mill On 1 711812024 10:59 11:29 EV TestTech: ZlCl 12 Port Polnt A1 A2 A3 A4 DP (ln. HzO) 0.56 0.58 0.64 0.60 0.53 0.55 0.63 0.61 Sqrt. DP 0.7483 0.7616 0.8000 o.7746 Temp ("F) 215.0 225.0 235.0 248.O 250.0 253.0 256.0 2s6.0 Veloclty (v) 51.68 52.99 56.06 54.79 51.57 52.64 56.46 55.55 DP (ln. H2O) 0.55 0.62 0.60 0.58 0.55 0.52 0.60 0.63 Sqrt. DP 0.74'.t6 0.7874 0.7746 0.7616 0.7416 0.7211 o.7746 0.7937 306,475 167,193 187,858 11,271,461 Port Polntc1 Temp Veloclty fF) (v) 256.0 52.75 256.0 56.01 259.0 55.2'r 259.0 U.28 2 3 1 ,| 2 3 1 D D D D B B B B c c c 0.7280 0.7416 0.7937 0.7810 Test Parameters P6", - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H20 P. - Absolute stack pressure, inches Hg t" - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Relult3 Average DP Average Sqrt DP Average Velocig Vs (fUsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) 1 2 3 4 o/o CO2 15.80 Yo Oz 11.70 % Nz 72.50 Md - dry basis lb/lb mole 31.00 Ms - wet basis lb/lb mole 29.566 Bwa - tolsture content fractlon Moisture determined by wb/db? 52.90 51.44 55.29 56.65 41612022 @Mostardi Platt 260.0 260.0 261.0 26'1.0 24.72 4.50 24.68 250.6 Circular 10.96 94.34 0.5844 0.7ill 54.144 0.1100 N O. ACFM Qsd - DSCFM Qs - SCFM Qs - SCFH v24.4 48 of 159 METHOD 2 VOLUMETRIC FLOW DATA Proroct Number: Cllent: Faclllty: Test Locatlon: Pltot !D: Pltot Coefflclent: Probe Length, Feet: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 8 Operatlng Level: Run No,: Test Date: Start Tlme: End Tlme: Test Englneer: Port Length, lnches: Mill On 2 71'.t812024 11:35 12:OS EV 12 Sqrt. DP 0.7416 0.7746 0.7937 0.8062 0.7348 0.7616 0.7937 0.8185 312,893 169,521 191 ,203 11.472.199 Port Polnt A1 A2 A3 A4 DP (in. H2O) 0.14 0.59 0.63 0.65 0.58 0.60 0.63 0.65 Sqrt. DP 0.7348 0.7681 0.7937 0_8062 Temp fF) 255.0 255.0 255.0 255.0 244.0 244.0 250.0 250.0 Veloclty (v) 52.22 54.59 56.41 57.30 53.71 54.62 56.21 57.10 DP (in. HrO) 0.55 0.60 0.63 0.65 Port Polnt c1c2c3c4 TestTech: ZlCl Temp Veloclty fF) (v) 253.0 s2.63 253.0 54.97 253.0 56.33 255.0 s7.30 0.7616 0.7746 o.7937 0.8062 Test Parameters Ps", - Barometric pressure, inches Hg P, - Stack Pressure, inches of H20 P" - Absolute stack pressure, inches Hg t" - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Results Average DP Average Sqrl DP Average Velocity Vs (fvsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) D D D D B B B B I 2 3 4 1 2 3 4 0.54 0.58 0.63 0.67 255.0 256.0 256.0 256.0 52.22 54.'t6 56.45 58.21 4t6t2022 @Mostardi Platt 24.72 -0.50 24.68 252.8 Circular 10.96 94.34 0.6075 0.7790 55.278 o/o CO2 '16.20 a/o 02 11.60 % Nz 72.20 Md - dry basis lb/lb mole 31.06 Ms - wet basis lb/lb mole 29.575 Bws - Molsture content fractlon 0.1 134 Moisture determined by wb/db (Y or N) N Q - ACFM Qsd - DSCFM Qs - SCFM Qs - SCFH v24.4 49 of 159 METHOD 2 VOLUMETRIC FLOW DATA Project Number: Glient: Facility: Test Location: Pltot lD: Pitot Coefficient: Probe Length, Feet: M2429'.t0 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 8 Operating Level: Run No.: Test Date: Start Time: End Time: Test Engineer: Port Length, lnches: Mill On 3 7t18t2024 12:10 '12:40 EV Tesi Tech: ZlCl 't2 Port Point A1 A2 A3 A4 DP (ln. H2O) 0.56 0.60 0.62 0.60 0.58 0.63 0.65 0.56 Sqrt. DP 0.7483 0.7746 0.7874 0.7746 Temp (oF) 253.0 254.0 254.0 254.0 253.0 2*.0 254.0 2U.0 Velocity M 53.07 il.97 55.88 54.97 Port Pointc1c2c3c4 DP (in. H2O) 0.58 0.61 0.63 0.65 0.58 0.62 0.65 0.62 Sqrt. DP 0.7616 0.7810 0.7937 0.8062 0.76't6 0.7874 0.8062 0.7874 313,035 169,211 191,306 11.478.385 Temp Velocity ("F) M251.0 53.93 251.0 55.31 251.0 56.21 251.0 57.09 0.7616 0.7937 0.8062 0.7483 Test Parameters P6", - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H2O P. - Absolute stack pressure, inches Hg L - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Results Average DP Average Sqrt DP Average Velocity Vs (fVsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) 1 2 3 4 1 2 3 4 B B B B 54.01 56.33 57.21 53.10 D o o D 252.0 252.0 253.0 253.0 53.97 55.80 57.17 55.84 4t6t2022 @Mostardi Plaft 24.72 -0.50 24.68 252.8 Circular 10.96 94.34 0.6088 0.7800 55.303 o/o CO2 16.80 o/o 02 '11.30 % Nz 71.90 Md - dry basis lb/lb mole 31.'14 Ms - wet basis lb/lb mole 29.622 Bws - Moieture contont fraction 0.1155 Moisture determined by wb/db (Y or N) N O - ACFM Qsd - DSCFM Qs - SCFM Os - SCFH v24.4 50 of 159 METHOD 2 VOLUMETRIC FLOW DATA ProJect Number: Client: Facllity: Test Localion: Pitot lD: Pltot Coefficient: Probe Length, Feet: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 I Operatlng Level: Run No.: Test Date: Start Time: End Time: Test Engineer: Port Length, lnches: Mill On 4 711812024 13:05 13:35 EV 12 Sgrt. DP 0.7348 0.7874 0.7746 0.7616 0.7348 o.7141 0.7746 o.7874 305,307 1il,929 1 86,1 92 11,171,507 Port Point A1 A2 A3 A4 DP (in. H2O) 0.55 0.57 0.63 0.61 o.52 0.53 0.63 0.60 Sqrt. DP 0.7416 0.7550 0.7937 0.7810 0.7211 0.7280 0.7937 0.7746 Temp fF) 256.0 256.0 256.0 256.0 255.0 255.0 255.0 255.0 Velocity M 52.71 53.65 56.41 55.51 Port Polnt cl c2 c3 c4 DP (in. H2O) 0.54 0.62 0.60 0.58 Test Tech: ZlCl Temp Velocityfrl u)252.0 52.08 252.0 55.80 252.0 54.89 252.0 53.97 B B B B 1 2 3 4 51.21 51.70 s6.37 55.01 D D D D 1 2 3 4 0.54 0.51 0.60 0.62 254.0 254.0 2U.0 254.0 52.15 50.68 54.97 55_88 4t6t2022 @Mostardi Platt Tost Parametors P6r, - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H20 P" - Absolute stack pressure, inches Hg te - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Results Average DP Average Sqrt DP Average Velocity Vs (fVsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) 24.72 -0.50 24.68 254.3 Circular 10.96 94.34 0.5781 0.7599 53.937 o/o CO2 16.50 % oz 1 1.90 % Nz 71.60 Md - dry basis lb/lb mole 31.12 Ms - wet basis lb/lb mole 29.618 Bws - Moisture contont fractlon 0.1142 Moisture determined by wb/db (Y or N) N O - ACFM Qsd - DSCFM Qs - SCFM Os - SCFH v24.4 51 of 159 METHOO 2 VOLUMETRIC FLOW DATA Project Number: Client: Facility: Test Location: Pltot lD: Pltot Coefficient: Probe Length, Feel: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 I Operating Level: Run No.: Test Date: Start Timo: End Tims: Teet Engineer: Port Length, lnchoB: Mill On 5 711812024 13:44 14:14 EV TestTech: ZlCl 12 Port Point A1 A2 A3 A4 Sqrt. DP 0.73/,8 0.7483 0.7874 0.7746 1 2 3 4 0.51 0.52 0.61 0.60 0.7141 0.7211 0.7810 0.7746 Test Parameters P6", - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H2O PE - Absolute stack pressure, inches Hg t" - Average stack temperalure, oF Duct Shape: Diameter, F6et Cross Sectional Area of Stack, Ft2 Method 2 Results Average DP Average Sqrt DP Average Velocity Vs (fUsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) DP (ln. H2O) 0.54 0.56 0.62 0.60 Temp fF) 252.0 252.0 252.0 252.0 Veloclty (v) 52.06 53.02 55.79 54.88 50.56 51.09 55.33 u.92 Port Pointc1c2c3c4 DP (in. HrO) 0.53 0.61 0.58 0.58 0.53 0.50 0.58 0.60 Sqrt. DP 0.7280 0.7810 0.7616 0.7616 0.7280 0.7071 0.7616 0.7746 301,496 163,469 1U,773 11,086,409 Temp Velocityfrl u) 248.0 51 .43 248.0 55.18 248.0 53.80 248.0 53.80 1 2 3 4 B B B B 251.0 252.0 252.0 253.0 251.0 25't.0 251.0 25'1.0 D D D D 51.54 50.06 53.92 54.84 416t2022 @Mostardi Platt 24.72 -0.s0 24.68 250.8 Circular 10.96 94.U 0.5669 0.7525 53.264 o/o CO2 16.80 o/o 02 11.60 % Na 71.60 Md - dry basis lb/lb mole 31.15 Ms - wet basis lb/lb mole 29.636 Bws - Moisture content fraction 0.1 153 Moisture determined by wb/db (Y or N) N Q - ACFM Osd - DSCFM Qs - SCFM Qs - SCFH v24.4 52 of 159 METHOD 2 VOLUMETRIC FLOW DATA Project Number: Client: Facility: Test Location: Pitot tD: Pitot Coefficient: Probe Length, Feet: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 I Operating Level: Run No.: Test Date: Start Time: End Time: Test Engineer: Port Length, lnchos: Port Point A'I A2 A3 A4 Sqrt. DP 0.7280 0.7416 0.7810 0.7810 Temp ("F) 253.0 253.0 253.0 253.0 Velocity (v) 51 .60 52.56 55.35 55.35 50.08 50.58 53.94 54.86 Port Pointc1c2c3c4 Mill On 6 7118t2024 14:20 '14;50 EV 12 Sqrt. OP 0.7211 0.7616 0.7616 0.7681 DP (in. H2O) 0.53 0.55 0.61 0.61 0.50 0.51 0.58 0.60 DP (in. H2O) 0.52 0.58 0.58 0.59 0.51 0.51 0.55 0.56 Test Tech: ZlCl Temp Volocity fF) (v) 251.0 s1 .04 251.0 53.90 251.0 53.90 251.0 54.36 0.7071 0.7141 0.7616 0.7746 Test Parameters P6", - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H20 P" - Absolute stack pressure, inches Hg t" - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Results Average DP Average Sqrt DP Average Velocity Vs (fvsec) FT-004 MP Pitot Project No. M2429104 Rotary Kiln Exhaust (K-1) B B B B D D D o 1 2 3 4 252.0 252.0 2s2.0 252.0 0.7141 0.7141 0.7416 0.7483 252.0 252.O 251.0 251.0 Q . ACFM Qsd - DSCFM Qs - SCFM Qs - SCFH 298,636 161,534 182,731 10,963,877 50.58 50.58 52.49 52.96 416t2022 @Mostardi Platt 1 2 3 4 24.72 -0.50 24.68 251 .9 Circular 10.96 94.34 0.5556 0.7450 52.759 % co2 17.00 o/o 02 11.60 % Nz 71.40 Md - dry basis lb/lb mole 31.18 Ms - wet basis lb/lb mole 29.655 Bws - Moisture contont fraction 0.1160 Moisture determined by wb/db (Y or N) N v24.4 53 of 159 METHOD 2 VOLUMETRIC FLOW DATA Project Number: Client: Facility: Test Location: Pitot !D: Pitot Coefflcient: Probe Length, Feot: M242910 Holcim (US) lnc. Devil's Slide Cemont Plant Main Kiln 001 0.840 I Operating Level: Run Jto.: Test Date: Start Tlme: End Tlme: Teet Engineer: Port Length, lnchos: Mill On 7 7t18t2024 1 5:14 15:44 EV 12 Sqrt. DP 0.7280 0.7746 0.7746 0.7616 0.7141 0.7211 0.7746 0.7810 300,7'14 162,681 18r'.,278 11,056,675 Port Point A1 A2 A3 A4 Sqrt. DP 0.7483 0.7746 0.7616 0.7141 1 2 3 4 0.53 0.55 0.60 0.55 0.7280 0.7416 o.7746 0.7416 Tsst Param.tor3 P6", - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H20 P" - Absolute stack pressure, inches Hg t. - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Rosults Average DP Average Sgrt DP Average Velocity Vs (fUsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) DP (in. H2O) 0.56 0.60 0.58 0.51 Temp fF) 253.0 253.0 253.0 253.0 252.0 252.0 252.0 253.0 Veloclty M 53.03 54.89 53.97 50.60 51 .55 52.51 54.85 52.55 Port Point cl c2 c3 c4 DP (in. H2O) 0.53 0.60 0.60 0.58 0.51 0.52 0.60 0.61 Test Tech: ZlCl Temp Velocity fF) (v) 250.0 51.48 250.0 *.77 250.0 54.77 250.0 53.85 'l 2 3 4 B B B B o D D D 248.0 248.0 248.0 248.0 50.43 50.92 u.70 55. t5 41612022 @Mostardi Platt 24.72 -0.50 24.68 250.8 Circular 10.96 94.34 0.5044 0.7509 53.126 o/o CO2 '17.20 o/o 02 11.60 % Nz 71.20 Md - dry basis lb/lb mole 31.22 Ms - wet basis lb/lb mole 29.667 Bws - Moisture contont fraction 0.1172 Moisture determined by wb/db (Y or N) N Q - ACFM Qsd - DSCFM Qs - SCFM Qs - SCFH v24.4 54 of 159 METHOD 2 VOLUMETRIC FLOW OATA Project Number: Cliont: Facillty: Test Location: Pitot lD: Pitot Coefficient: Probe Length, Feet: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 I Operating Leve!: Run No.: Tosl Datc: Start Time: End Time: Test Engineer: Port Length, lnches: Mill On 8 7118t2024 16:00 16:30 EV TestTech: ZlCl 12 Port Point A1 A2 A3 A4 OP (in. H2O) 0.55 0.58 0.58 0.51 0.51 0.51 0.60 0.53 Sqrt. DP 0.7416 0.7616 0.7616 0.7141 0.7141 o.7'141 0.7746 0.7280 Temp ("F) 254.0 254.0 254.0 254.0 253.0 253.0 253.0 253.0 Velocity M s2.59 54.01 54.01 50.04 50.6"1 50.61 54.89 51.59 Port Point cl c2 c3 c4 DP (ln. H2O) 0.53 0.58 0.59 0.56 0.51 0.52 0.60 0.58 Sqrt. DP 0.7280 0.7616 0.7681 0.7483 0.714'.1 0.721'.! 0.7746 0.7616 297,863 160,795 't 82,163 't 0,929,75s Temp Veloclty fF) M250.0 51 .48 250.0 53.86 250.0 u.32 250.0 52.92 B B B B D D D o 1 2 3 1 1 2 3 4 252.0 252.0 252.0 252.0 50.57 51.07 54.85 53.93 4t6t2022 @Mostardi Platt Tost Parametors P6r, - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H20 P. - Absolute stack pressure, inches Hg L - Average stack temperature, oF Duci Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Results Average DP Average Sqrt DP Average Velocity Vs (fUsec) FT-004 MP Pitot Project No. M2429104 Rotary Kiln Exhaust (K-1) 24.72 -0.50 24.68 252.3 Circular 10.96 94.34 0.5525 0.7430 52.622 o/o CO2 17.20 o/o 02 11.50 % Nz 71.30 Md - dry basis lb/lb mole 31.21 Ms - wet basis lb/lb mole 29.662 Bws - lUloisture contont fraction 0.1173 Moisture determined by wb/db (Y or N) N Q. ACFM Qsd - DSCFM Qs - SCFM Qs - SCFH v24.4 55 of 159 METHOD 2 VOLUMETRIC FLOW DATA Prolect Number: Client: Facility: Test Location: Pitot lD: Pitot Coofficiont: Probe Length, Feet: M242910 Holcim (US) lnc. Devil's Slide Cement Plant Main Kiln 001 0.840 8 Operatlng Level: Run No.: Test Date: Start Time: End Time: Test Engineer: Port Length, lnches: Mill On I 711812024 '16:40 '17:10 EV Test Tech: ZlCl 12 Port Point A1 A2 A3 A4 DP (in. H2O) 0.54 0.55 0.60 0.58 0.51 o.52 0.58 0.60 Sqrt. DP 0.7348 0.7416 0.7746 0.7616 Temp (oF) 255.0 255.0 255.0 255.0 254.0 254.0 254.0 254.0 Velocity M 52.16 52.U 54.98 54.05 50.65 51.14 54.01 54.94 Port Pointctc2c3c4 OP (in. H2O) 0.53 0.55 0.58 0.58 Sqrt. OP 0.7280 0.7416 0.7616 0.7616 0.7280 0.7071 0.7616 0.7746 298,956 161,933 183,410 11,004,59s Temp Velocity ("F) M243.0 51.23 243.0 52.19 243.0 53.60 243.0 53.60 1 2 3 4 B B B B I 2 3 4 0.714',1 0.7211 0.7616 0.7746 D D D D 0.53 0.50 0.58 0.60 248.0 248.0 248.0 248.0 51.42 49.94 53.79 94.7',! 416t2022 @Mostardi Platt Teat Parameters P6r, - Barometric pressure, inches Hg Pn - Stack Pressure, inches of H20 P" - Absolute stack pressure, inches Hg t. - Average stack temperature, oF Duct Shape: Diameter, Feet Cross Sectional Area of Siack, Ft2 Method 2 Resulti Average DP Average Sqrt DP Average Velocity Vs (fUsec) FT-004 MP Pitot Project No. M242910A Rotary Kiln Exhaust (K-1) 24.72 -0.50 24.68 250.0 Circular 't0.96 94.34 0.5581 0.7468 52.815 o/o CO2 17.10 o/o 02 11.60 % Nz 71.30 Md - dry basis lb/lb mole 31.20 Ms - wet basis lb/lb mole 29.654 Bws - Moisture content fractlon 0.1171 Moisture determined by wb/db (Y or N) N O. ACFM Qsd - DSCFM Qs - SCFM Os - SCFH v24.4 56 of 159 METHOD 2 VOLUMETRIC FLOW DATA Project Number: Cliont: Facillty: Test Localion: Pitot tD: Pitot Coefflcient: Probe Length, Feet: M242910 Holcim (US) tnc. Devil's Slide Cement plant Main Kiln 001 0.840 I Operating Level: Run No,: Test Date: Start Time: End Time: Test Engineer: Port Length, lnches: Test Tech: ZlCl Sqrt. DP 0.721'l 0.7616 0.7746 0.7874 Temp fF) 254.0 254.0 2U.0 254.0 Velocity M 5 1.13 54.00 54.92 55.83 53.06 u.46 s4.00 u.92 Port Point C1 C2 G3 C4 DP (in. H2O) 0.52 0.56 0.58 0.55 Mill On 10 7118t2024 17:3'l 18:01 EV 't2 Sqrt. DP 0.721'l 0.7483 0.7616 0.7416 0.7211 0.7416 0.7746 0.7416 Port Point A1 A2 A3 A4 1 2 3 4 0.56 0.59 0.58 0.60 0.7483 0.7681 0.7616 0.7746 Test paramotors P5"r - Baromelric prossure, inches Hg Pn - Stack pressure, inches of H2O P, - Absolute slack pressure, inches Hg L - Average stack temperalure, oF Ducl Shape: Diameter, Feet Cross Sectional Area of Stack, Ft2 Method 2 Results Average Dp Average Sqrt Dp Average Velocity Vs (fl/sec) FT-004 Mp pitot Projoct No. M24211OA Rotary Kitn err,"r.iik-ry DP (in. H2O) 0.52 0.58 0.60 0.62 Temp VelocityfF) U)255.0 51 .17255.0 $.10255.0 54.04255.0 52.62 B B B B 254.0 254.0 254.0 254.0 D D D o 1 2 3 4 0.52 0.55 0.60 0.55 255.0 255.0 255.0 255.0 51 .17 52.62 54.96 52.62 24.72 -0.50 24.68 254.5 Circular 10.96 94.U 0.5675 0.7s31 53.414 Q . ACFM Qsd - DSCFM Qs - SCFM Qs - SCFH 17.10 11.50 7't.40 31.20 29.671 302,U7 163,015 184,322 1 1,059,349 %co2 %o, %N, Md - dry basis lb/tb mole Ms - wet basis lb/lb mole Bws - Moisture content fraction 0.1156Moisture determined by wb/db (y or N) N v24.4 57 of 't 59 4t6t2022 @l\iostardi platt FT-008 Hg Template Project No. M2429104 Rotary Kiln Exhaust (K-1) Method 308 (Sorbent Trap) Mercury Test Results Summary Holclm (US) lnc. Devl!'s Sllde Cement Plant Main Klln v5.4.3 58 of 159 41612022 @Mostardi Platt Te3t No.Dale Stert Tlme End Tlme V- (atandard L)no detectod ppb ug/dscm ugLhrccm palred trap rgreement, % dlfforence Bre.kthrouoh % 1A 7t18t2024 10:59 11:29 22.990 47.7 0.249 2.O75 1.U7 3_47 1B 23.295 43.9 0.226 1.884 1.677 2.57 Avcrage 23.142 45.8 0.237 1.980 1.762 4.81 2A 7t18t2024 1 1:35 12:05 22.999 38.3 0.200 1.665 1.476 1.59 2B 23.236 39_6 0.204 1.704 1.51 1 0.51 Averaoe 23.1 18 39_0 o.202 1.685 1.191 1.16 3A 7n8no24 12:1O 12:40 22.913 31.6 0.165 1.379 1.220 0.64 3B 23.1 96 31.5 0.1 63 1.358 1.201 3.96 AYeraqe 23.054 31.6 0.164 '1.369 1.210 0.77 tlA 7t18t2024 13:05 '13:35 23.197 49.1 0.254 2.117 '1.875 4.03 4B 23.205 46.6 0.241 2.008 1.779 0.21 Avoraqe 23.201 47.9 0.247 2.062 1,827 2.63 5A 7t18t2024 13'.44 14:14 23.177 43.6 0.226 1.881 .564 0.46 5B 23.296 40.7 0.209 1.747 .546 1.23 Averaqe 23.236 42.2 0.217 1.814 .605 3.70 6A 7t18t2024 14:20 14:50 22.882 35.8 0.1 88 1"565 383 3.77 6B 23.170 34.4 0.1 78 1.485 312 1.44 Averaqe 23.026 35.1 0.183 1.525 .3la 2.62 7A 7t18t2024 15:14 15:44 22.9U 35.0 0.183 1.524 .323 8.36 ?B 23.041 36.4 0.189 1.580 .371 6.12 Averaqe 23.002 35.7 0.186 1.552 .311 1.79 8A 7t18t2024 16:00 16:30 22.862 34.5 0.181 1.509 .310 0.58 8B 23.015 31.0 0.161 't.u7 169 9.54 Avoraqe 22.939 32.8 0.171 1.428 .239 5.68 9A 711812024 16:40 17:10 22.932 30.7 0.1 60 1.339 .339 0.66 9B 22.901 35.1 0.184 1.533 .533 0.57 Averaoe 22.917 32.9 0.172 1.436 .tl36 6.75 10A 7t18t2024 17:31 18:01 23.046 37.6 0.1 96 1.632 .443 6.82 'l0B 23.111 36.8 0.'191 't.592 .408 4.25 Average 23.078 37.2 0.1 93 't.612 .126 1.22 METHOD 3OB TEST RESULTS Project#: 11212910Cllent: Holclm (US) ]nc. Facility: Devil'B Sllde Comont Plant Analrror lD: Ohio Lumex Locatlon: Maln Klln Condltlon: Mlll On Oata Taken By: R.Flschet Date: Start Tlme: End Tlme: Pressu16, Barometrlc(Hg"): Water Vapor in Flue Gaa (Bwa): 'lA Trap lO: Hg (ng): Meter Temperaturo (oF): Meter lD: Meter Callbratlon (Y): lnltlal Volume (llter3): Flnal Volume (lltere ): Meter Volume (Standard llters): Hs (ppb): Hg (ug/dscm): Hg (ug/wecm): 711812024 10:59 11:29 24.720 0.'110 oL726414 47.7 103.43 MM13 0.985 0 30.145 22.990 0.249 2.075 1.847 Hg (ng): 43.9 ltetor Tempereture (oF): 105.57 Meter lD: MM13 Meter Callbratlon (Y): 1.000 lnltlalVolume(llters): 0 Flnal Volume (llters): 30.2O2 Meter Volume (Standard llters): 23.295 Hg (ppb): 0.226 Hg (ug/drcm): 1.884 Hg (ug/w3cm): 1.677 Spiked Trap Run: N Start Tlme: End Time: Preorure, Barometrlc(Hg'): Wator Vapor ln Flue Gar (Bwa): Hg (ng): Meter Temperature (oF): Meter lD: Meter Callbration (Y): lnltlal Volume (lltorc): Flnal Volume (llters): Meter Volume (Standard llters): Hs (ppb): Hg (ug/dccm): Hg (ug/wscm); 1 'l:35 '12:05 24.720 0.113 38.3 102.43 MM13 0.985 0 30.104 ?2.999 0.200 1.665 1.476 Hg (ng): 39.6 MeterTemperature(oF): 105.00 Meter lO: MM13 Meter Calibration (Y): 1.000 lnltial Volume (llters): 0 FinalVolume(literE): 30.095 Meter Volume (Standard lltera): 23.236 Hg (ppb): 0.204 Hg (ugy'dscm): 1.704 Hg (ug/wecm): 1.511 Stert Tlme: End Timo: Pres3uro, Baromotrlc(Hg"): Water Vapor In Flue Gas (Bwr): FT-008 Hg Template Project No. M242910A Rotary Kiln Exhaust (K-1) Hg (ns): Meter Temporature (oF): M6ter lD: Meter Callbtation (Y): lnltlal Volume (lhers): Flnal Volume (llters): Meter Voluma (Standard llters): Hs (ppb): Hg (ugy'drcm): Hg (ug/wscm): v5.4.3 59 of 159 12:10 12:40 24.720 0.116 31.6 103.7 t MM13 0.985 0 30.059 22.913 0.165 1.379 1.220 Hg (ng): 31 .5 Metor Tempereture (oF): 106.29 Metar lD: MM13 lieter Callbratlon (Y): 1.000 lnltlal Volume (llters): 0 Final Volume (lltsrs): 30.112 Metei Volume (Standsrd llt.rs): 23.196 Hg (ppb): 0.163 Hg (ug/d3cm): '1.358 Hg (ug/wecm): 1.201 Splkod Trap Run: N Spike Concentration: 416t2022 @Mostardi Platt tEIH(,U JUI' tESl I(E:'ULtli Projoct #: M242910Cllent: Holcim (US) lnc. Faclllty: Dovll's Sllde Cement Plant Analyzer lD: Ohlo Lumex Locailon: Maln KllnCondltion: Mlll On Data Taken By: R.Fischer Date: 711812024 Start Time: 13:05 End Time: 13:35 Prosaure,Barometrlc(Hg"l: 24.720 Water Vapor ln Flue Gae (Bwa): 0.114 Hg (ng): Meter Temperature fF): Meter lD: Moter Crllbratlon (Y): lnltial Volumo (llters): Flnal Volumo (lltcrs): Meter Volume (Standard llters): Hs (ppb): Hg (ug/d3cm): Hg (ug/wscm): 4A Trap lD: 01726419 49.1 95.43 MM13 0.985 0 30.039 23.197 0.254 2.117 1.875 Hg (ng): 46.6 Moter fomporature fF): 105.43 Meter lD: MM13 Moter Callbratlon (Y): 1.000 lnltlal Volume (liters): 0 Final Volume (lltere): 30.077 Meter Volume (Standard llterr): 23.205 Hg (ppb): 0.241 Hg (ug/drcm): 2.008 Hg (ug/wscm): 1.779 Splked Trap Run: Y Splke Concentratlon: 50 Start Time: 13.44 End Timo: 14i14 Pressure,Barom6trlc(Hg"l: 24.720 Wator Vapor ln Flue Gac (Bwt): 0.115 Hg (ng): Moter Temporature fF): Meter lD: Meter C8llbratlon (Y): lnltlal Volumo (llters): Flnal Voluma (lltors): Meter Volume (Standard llters): Hg (ppb): Hg (ug/dacm): Hg (ug/wscm): 43.6 97.29 MM13 0.985 0 30.059 23.177 0.226 1.881 1.664 58 Trap lD: OLC167418 Hg (ng): 40.7 MeterTemperaturefF): 103 Meter lO: MM13 Iilotor Calibration (Y): 1.000 lnltlal Volume (lltors): 0 Final Volume (llters): 30.065 Meter Volume (Stand.rd llters): 23.25G Hg (ppb): 0.20s Hg (ug/decm): 1.747 Hg (ug/wscm): 1.546 Splked Trap Run: Y Spike Concontratlon: 50 Start Tlme: End Tlme: Pressure, Beromotrlc(Hg") : Water Vapor ln Flue Gae (Bws): Hs (ns): Moter Temperature fF): Meter lD: Meter Callbratlon (Y): lnltlal Volume (llters): Final Volume (llters): Moter Volumo (Standard llters): Hs (ppb): Hg (ug/dscm): Hg (ug/wscm): 14:20 14:50 24.720 0.116 35.8 103.71 MM.I3 0.985 0 30.019 22.882 0.1 88 1.565 1.383 o1c178231 34.4 105.57 MM13 1.000 0 30.039 23.170 0.1 78 't.485 1.312 50 68 Trap lD: Hs (ns): Moter Tomperature fF): Meter lO: Motar Callbration (Y): lnitial Volumo (lltors): Flnal Volume (llters): Moter Volume (Standard llto13): Hs (ppb): Hg (ug/dlcm): Hg (ug/w3cm): Splksd Trap Run: Splke Concentratlon: FT-008 Hg Template Project No. M242910A Rotary Kiln Exhaust (K-1) v5.4.3 60 of 159 4t6t2022 @Mostardi Platt Project#: ',.242910Cllent: Holclm (US) lnc.Faclllty: Dovll's Sllde Cement Plant Analyzer lD: Ohlo Lumex Locatlon: Maln KllnCondltlon: Mlll On Data Taken By: R.Flschor Start Time: End Tlme: Pressure, Barometric(Hg'): Water Vapor ln Flue Gac (Bwe): Start Time: End Time: Pressure, Barometric(Hg'): Wat6r Vapor ln Flue Gac (Bws): Hg (ng): Metor Tomporature fF):ileter lD: Meter Callbration (Y): lnitlel Volume (litors): Flnal Volumo (llto13): Meter Volume (Standard liters): Hs (ppb): Hg (ug/dccm): Hg (ugr\rscm): Hg (ng): lreter Tomporature f F): Itleter lD: Metor Callbratlon (Y): lnitlal Voluma (litors): Final Volumo (llto6): Metor Volume (Standerd lltors): Hs (ppb): Hg (ug/dscm): Hg (ug/w3cm): Hs (ns): Moter Temperature fF): Itleter lD: Metor Callbratlon (Y): lnitial Volume (litert): Final Volume (litere): M6t6r Volume (Standard lltere): Hs (ppb!: Hg (ug/d6cm): Hg (ug/wscm): 7118t2024 15:14 15:44 24.720 o.132 o1726298 35.0 102.57 MM13 0.985 0 30.065 22.964 0.183 1.524 1.323 o1c191621 34.5 104.71 MM13 0.985 0 30.046 22.862 0.181 1.509 1 .310 7t18t2024 16:00 16:30 24.720 0.132 78 Trap lD: O1C191407 Hg (ng): 36.4 Metor Temperature fF): 109.57 Moter lD: MM13 Moter Callbratlon (Y): 1.000 lnltlal Volumo (lltorc): 0 Flnal Volume (llters): 30.083 Meter Volume (Standard llters): 23.041 Hg (ppb): 0.189 Hg (ug/dscm): 1.580 Hg (ug/wrcm): 1.371 EB Trap lD: O1C190993 Hg (ng): 31.0 ileter Temperature fF): 109.14 Meter lD: MM'13 Metor Callbratlon (Y): 1.000 Inltlal Volume (llters): 0 Flnal Volume (llters): 30.027 Meter Volume (Standard lltors): 23.015 Hg (ppb): 0.161 Hg (ug/dscm): 1.U7 Hg (ug/wacm): 1.169 olc191 180 Hg (ng): 85.1 Moter Tcmperaturo fF): 112.29 Meter lD: MMl3 Meter Callbratlon (Y): 1.000 lnltlal Volume (llters): 0 Flnal Volumo (lltors): 30.044 Meter Volume (Standard llters): 22.901 Hg (ppb): 0.184 Hg (ug/dscm): 1.533 Hg (ug/wscm): 1.533 Splked Trap Run: N Start Tlme: End Tlme: Presrure, Barometrlc(Hg'): Wator Vapor ln Fluo Gas (Bws): 16:40 17:10 24.720 0.000 30.7 103.57 MM13 0.985 0 30.077 22.932 0.1 60 't.339 't.339 FT-008 Hg Template Project No. M242910A Rotary Kiln Exhaust (K-1) v5.4.3 61 of 159 4t6t2022 @Mostardi Platt ProJect#: n24291O Cllent: Holclm (US) lnc.Faclllty: Devlfe Sllde Gement Planl Analyzor tD: Ohlo Lumox METHOD 3OE IESI RESULTS Moter Tomporaturc fF1:t6tor lD: Motcr Callbr.tlon (Y): lnltlal Volume (lltoE): Flnal Volume (lltera): M.tor Volume (Standrrd lltor.): Hs (PPb): Hg (ug/dlcm): Hg (ug/rvrcm): v5.4.3 62 of 159 Locatlon: ilrln KllnCondltlon: tlll On Drta Taken By: R.Flrcher 37.6 100.57 MM,I3 0.985 0 30.065 23.046 0.196 1.632 1.443 Stert Tlme: End Tlmo: Pre33uro, Baromctrlc(Hg') : Walcr Vapor ln Fluo Ge! (Bw!): FT-008 Hg Template Project No. M2429104 Rotary Kiln Exhaust (K-1) 17:31 18:01 24.720 0. fi6 Hg (ns): Motor Tcmporaturo fF):lloter lD: Motor Callbrstlon (YJ: lnltl.l Volumo (lltcrs): Flnal Volumo (lltoB): llctor Volumo (Standerd llterr): Hs (ppb): Hg (ug/d!cm): Hg (ug/wrcm): Splked Trap Run: 36.8 108.00 MM13 1.000 0 30.092 23.111 0.19'l 1.592 '1.408 N 4t6t2022 @Mostardi Plaft Hg (ng): Appendix E - Continuous Emissions Monitoring System Data and Plant Operating Data ProJect No. M242910A Rotary Klh Exhaust (K-1) 63 of 159 @Mostardl Platt oN@NNEE* h:3E fr E =(9o) to oF9blt(o sGoEo5 '= d !o .o . ! EE E 3. 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Ot^l @\ oa @o)o ooo @6o q ts- @@o osto o)oN aolN o\olN qOlN @qo F\oN raFdt oo o Jd i o i o 6$ N Ee I' AF UIFrh - o >< r : u= G d u5 d > @<t^iN xdN ^l!iN oqNN €tN a NN@N tsoqNN NqN tN o)N Nv!N tdiN q @d!N N qN ..1N Or^iN FaNN €qNN oqNN {NN @cooN @\N FqN {^!N ot:N FqN {^i Olo!N ilr tal tt o+o a o - did i o o gAAIa EUe' 6 ud , ? ' $ . ,E = H Fi qooNo c8$NNolo co6OrCOI ociosooo oEoro6 qoo6@rO6o qI!tFI qg@g g8Noo qINNto q8ara ocioocoF.olo qINol jts q8ro+o q8tsOro!o qoodlNo qoooOlNo qoo$oNo qooNoo qoo6+o qoo63 qIN@6o q8Io qooN@o qI{o qoIo6o qoo@No coIoo qootoo qooNtsI qI3o i.dtlalaFo $E ; gE B " TH='I t3EH d, i F , t 9 o ;b 3 : * o o No 8 o oo @o COo coo @o oo oo I I 3 q o o o q q o 6oo 6oo No tso Fo tsq tsq tso Fe o 60 0 c. 1 E 1= B t2 Ee " q! ' - .o o; 8 , 3 $ " Eo ' o F : H9 9 . 8 { @ 0q q di cN q ^lN dl dl N^i ryN u) q !N qN ryN a A,l !I I ! di e d] o q a ! 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F s a(o \(oN -N o) qol \@ vlN cN roi ao atsN 6^iN NoiN qts oot di !' ts{ q N^iN tsN ry$ aoo qN No{ F@ .!o 6|o qo @dirt 6 !i n! l{an it d| q o ) r3 xosE E ; i .t€FN oqNN qlooN oloN 093N d!tF-N d!NoN oN 6(o(oN cNtsN 6^iFN cFN .qtttsN oq@FN ^lotsN qFtsN aFN oi !oN FoN NoFN OtrotsN a6N uloN qtsN ^iFN 6{tsN oqrtFN aoFN .!6N aoN \oN C'dFN q\ - r: c i @ 6 NN N 3t;oz R rE g t ; di Ndi di !tdi o o 6{ Ndi d i q tdi $Ndi N o c !loN oc6N {N o^i @6^i o^i oo^i F^i 6qN No^i ooN Nq Fq E C' rr t hN o om @ F ri d i ^ i o goilI -, cN^ O ;B 9 $ ; nui I oo oo) oq o Na {Na Nui oui od N6ri 3ui 6t'i rri aOoui Ft' i \ N@ Nri ui oui (oa oui c o^l @ui \tNri Nvi a ri rO|a @m O e vi@ u i o f; " 8t s It $f i , s s t ao@ o@ o3 qN@ oqo6 \ol ts .!o .!3 FoaO qNo di@ ^l€ ^i6 eaO @ 6 .. 1o \co \6 o6 qNco .!aO s IN@ .!@ ol@ \@ ao6 qo@ oo \@ GlNo NN F ^i u i o i = @6 F -BOE \, l aE ' s ; ; {ui q o(o oovi o@ui oui No {No v) q q@ No) a oq \ E tsu) \ N!q Nd] o4 @t od,! q on @i. l ttNui Nd) a n rOraF @o O - ui c i u i 6 Ea{oL' ;E , e : r qNN oi I6 FdiN ctsoN (ocoN ocoo qN \oN \NNN oiN qtN oqrtN crN o)sN N\oIN {3N o)tN \N qoNN @dN d!N oqttN qtN ^isN oqN oqFN rtN @NN 6riN NN Fr9r\ l iQ q N6 N g C'EEo6a qqts!tNo6-ts qrl ts!toct6ts g!J\to;N ilFebN q'lFio; r0qr l ts!toq6N I\qtNn6-' ts aoqlFto6ts orft{ob.F o*Fno;. tto;' ts iFrto6ts iFtloa.- *F!to;ts h*Ftod''F o*,\rtoq6 F*F+o;F 6_itFtooF or:to>F fi,\tod6ts Frtoots 6Frtob' ts o6Frl6ots 3Ftoa\F 6Nto6ts ron*o6'' ts Fl-toots ol-too-F o! !f6aN B@n6o eo!to6 ta l (,cIl( o;x c 5 ti = 8 IEt O) rOott\ a <Y \aNJ<PNi >u J o!z?6> .9 - E e6 o- ( Project No. M2429104 Rotary Kiln Exhaust (K-1) Appendix F - Field Data Sheets 75 of '159 @Mostardi Platt Project Number: Client: Test Location: Source Condition: Test Engineer: Volumetric Flow Rate Determination Field Data Sheet r.t ) { 2e rL\ Date: l-ir:irlrn ( v'r) lnr Test Number Start Time: End Time: Test Tech: Upstream Disturbance, Diameters Z.iL u Downstream Disturbance, Diameters rc (tao' ol I t6l:r-t2\ Pcl..'1 t,tn f^u,r',',t (f - t) r.r,r\ 0rr tv CO2% i5 'au O2o/o f1 10 Ne% I2 sc Meter No. 22 LIL 7 PortLength r1o " PortSize GO 'PortType Ftu"gr PitotlD_q''1_ PitotCoefficient(Cp) r)s'i Duct Diameter ro.ctb ft Flue Area - ft? P*, 24.12 "Hg Static -o.i "H2O Static_ "Hg P. "Hg Wet Bulb Temp Drv Bulb Temo8,, 0.,10 Fluke # Leak Checks Passed@Pre I lnches H2O Post 1 lnches H2O UmbilicallD Port- Point #AP Temp. "F J^P Null Point Angle, Degrees Port- Point #AP Temp. OF J^t' Null Point Angle, Degrees A- |1/.5Lr ?. 15 (- I O "cs Lr1L A-2 o. 5<)2q a-2 O 6,L 16b o-1 O (r'l 13'r c -3 o60 t5(i n -1 A-c,L 2 't3 C-Zi O..;(15q ll -l o 5i L5ut r)1 o. 5i:2[. o tl' 2 u..;rj 15 .)D '2-..) <r 2QC) t]l D(,,19(J D3 U. GO ')(, I ;l '{o c,t L5b rl'-1 r)(2bl Averaoe .44 x COzok + .32 x Ozo/o + .28 X Nzo/o = - (Md) ( Md , -1-Bws1 + (18 '-Bws) = - (Ms) 85.49 x cp* Vs " _ FlueArea . 60 = _acfm .,F: 17.647 , DS-001 Method 2 Pitot Sheel Project No. M242910A Rotary Kiln Exhaust (K-1) acftn ,. PS =Ts'R scfmx60=_sclh Rev. 1.3 76 of 159 1t25t2022 @Mostardi Platt ft/sec (Vs) Project Number: Client: Test Location: Source Condition: Test Engineer: Volumetric Flow Rate Determinatlon Field Data Sheet r11 .llTrC Date: Test Number: Start Time: End Time: Test Tech: Upstream Disturbance, Diameters "L Sou Downstream Disturbance, Diameters iL .<lc'a, Ul IrE I tui4 li.lcinr {u';) lnr tir,iu, . it.tr, E,rrru.'ri ( K'I ) ilrtt 0n EV Duct Diameter iu.,rG q Flue Area _tl' Port Length tL " Port Size__1ll" Port Type Flu,v,c Pitot lD uol Pitot Coefficient (Co) u i(l P5., 2t 12 "Hg CO2o/o t6.?D Wet Bulb Temp Leak Checks Passed@ ll J'r r2 O5 7t( I Static-rL! "HzOStatic_ "HgP. "Hg Vs' 17.647 " Oz% tr 0D Nz% :l?10 Meter No. 22 Dry Bulb Temp8,. O'll!. Fluke # acfm scftnx60=_scrh Rev. 1.3 77 of 159 Pre ;l lnches H2O Post { lnches HzO UmbilicallD .44 x COzo/o + .32 x Ozo/o + .28 x N2/6 = - (Md) (_ Md ' _1-Bws) + (18 '_Bws; = _ (Ms) 85.49 x cp-x ".fp-: Flue Area . 60 = acfrn ,. PS =Ts "R DS-001 Method 2 Pilol Sheer Project No. M242910A Rotary Kiln Exhaust (K-1) '125t2022 @Mostardi Platt Port- Point #AP Temp. OF .AF Null Point Angle, Degrees Port- Point #AP Temp. "F J^P Null Point Angle, Degrees A-l O.5'i 25t L-l O "'t 2s) A-2 o r(l 2 5'l (-r-o.co 251 A-3 o0l 155 c-J O(,3 25) n -rl Lr. o5 155 c-ri o o';2Sc, l1r' I osg 2'15 r) -l (, sri 255 fl-2 c cc)2'1 ^'i r)l ().\g 25b B1 o (1 2Sc)E-j Ct.L J '25a 6{r, ri 75t'r D{ o Ll 25{o Averaoe -)Ts "RMsr Ps ft/sec (vs) Project Number: Client: Test Location: Source Condition: Test Engineer: Volumetric Flow Rate Determination Field Data Sheet i"l l{1q ic Date: Test Number Start Time: End Time: Test Tech: H Jr,.n ( u',; ) lrt 17.-i-,* ilrlrr Erlr,u',1 /f -t) o t l,g /tu2t tI r0 r*1. l\ O n 11:{0 EV 44xCOzo/o +.32 x Ozo/o+ .28 X N20/o =-(Md) (_ Md . _1-Bws)+ (18 , 85.49 x cp" Vsr Flue Area , 60 = 17.647 ,acfm' Ts oR DS-001 Method 2 Pitot Sheel Project No. M242910A Rotary Kiln Exhaust (K-1) Upstream Disturbance, Diameters t 5ct., Downstream Disturbance, Diameters iL.'ldt - (Ms) .,F: acftn scfmx60=_sclh Rev. 1.3 78 of 159 ZIC 1 Duc{ Diameter r0.rtG ft Flue Area fi2 Port Length tL " Port Size_.Q.1L " Port Type Flq,,qc Piiot lD3cr - Pitot Coefficient (Co) o v{ P6", 2r.'l t "Hg CO2% r c tj (-) Wet Birlb Temp Leak Checks Passed@ Staticlr.'i "H2O Ozo/o rr 'l C Dry Bulb Ter4p - Pre ^i lnches H2O Static_ "Hg Nz % .lt tL B*. A.ll5 Post 5 lnches H2O P. "Ho Meter No. L2 Fluke # Umbilical lD Ps= 1t25t2022 @Mostardi Platt Port- Point #AP Temp. OF fiF Null Point Angle, Degrees Port- Point #AP Temp. "F J^t' Null Point Angle, Degrees A -t oso 25)(-o5b 151 A.'o 6o 2 6.{(-L Oat 25r A-3 A. t'1- 254 c-1 o. b5 l5t G -lt O.GC)25q c-4 o05 251 qr osy 1_53 D.a o.qg 25rL A2 oLi L?A OL o c2.25'2 n' j O L.5 i5t t) .l 0 G.,251 G^t o5(/2 1 5't ol obL )51 Averaqe ttlsec (vs) Project Number: Client: Test Location: Source Condition: Test Engineer: Volumetric Flow Rate Determination Field Data Sheet i1 'Ltl tY r C Date: Test Number: Start Time: End Time: Test Tech: i{..ir.m Iu:>) lnc. utlli8 l2a2\ [.oir,,, [,] n E,',huu:rt (f 't) EV Oz o/o 11.70 Nz % 7t.(,o Meter No. 22 l1 os t3 t5 LIL L Duct Diameter i o cac ft Flue Area ft2 Port Length lL " Porl Size u O " Porl Type Ftu,xrr Pitot lD Lbt Pitot Coetficient (Cr) r; sl e*, rr it rtg cor@ weffii6-Terp - Leak checks Passed@ Upstream Disturbance, Diameters l '5 Downstream Disturbance, Diameters ru.cJ Static:t).i "HzOStatic "HgPr- "Hg Drv Bulb Temo8,. o.ll.l Pre 5 lnches H2OPost fi lnches H2O .44 xCOzo/o + .32 x Ozo/o + .28 x N2/s = - (Md) (_ Md . _1-Bws) + (18 ,_Bws) = _ (Ms) 85.49 x Cpx Vs"Flue Area x 60 Fluke # Umbilical lD _ ..re: 17.il7 , acfm , PS = Ts "R DS-001 Method 2 Pitot Sheet Project No. M2429104 Rotary Kiln Exhaust (K-1) scfmx60=_scftl Rev. 1.3 79 of 159 1t25/2022 @Mostardi Platt Port- Point #AP Temp. "F J^P Null Point Angle, Degrees Port- Polnt #AP Temp. OF J^P Null Point Angle, Degrees A-t )55 25 r,c-l o5\t52 A-2 0', 1 75d -L o. cL 25i A-3 0 c3 75b r -3 ooo 25 L R -ri 0cr 't5C,c -1 O 5is 2s2 B-l a, c.l1 25g,i)-a O,.iAI 2 5.1 a-7 rl..irl is5 D -2_o 5i 1s1 (\1 O.OJ 25 ct r) -3 a.c o 2 5',1 i") '{O t@ z5 tj D1 o aL 25',1 Averaqe ft/sec (vs) Project Number: Client: Test Location: Source Condrtion: Test Engineer: Volumetric Flow Rate Eletermination Field Data Sheet l-12{lqlD Date: Test Number. Start Time: End Time. Test Tech: l-luic,r, (ur) Iu. 11,t\ ()n Upstream Disturbance, Diameters 2 5 Downstream Disturbance, Diameters ro.cl tt1l,8 llcz\ t2c[ q,, E,ln L=i hurt,] ( ]'l)li {{ l1 r{ EU O2o/o ,1.7O Nz % 'tl.'c) Meter No. 22 Fluke # Drv Bulb TemoB*, o.ng Pre { lnches H2O Post at lnches H2O Umbilical lD _ zrc I DuctDiameter lw (tQ ft Flue Area ft2 Port Length tL " Port Sizel.o_" Port Type_ELray.r: Pitot lD_9.141 Pitot Coefficient (Cp) C'.U{ P5", 2'r 12 "Hg C}zyo ll.lo Wet BUlb Temp Leak Checks Passed@ Statica.s "H2OStatic_ "HgPr- "Hg Port- Point #AP Temp. OF ..^F Null Point Angle, Degrees Port- Point #AP Temp. OF J,\P Null Point Angle, Degrees A-l O -q,{')-51 L-l osi 2'4 Y A-L c.gb 7-5L L-2 obt 2'lk A.,o c'i 2.5 'I C.o.5.9 219 n -q o.Lo 152 c-'l O, EY 1\g o5l 25f D-l D.5 i 2s l8'2,().sz 152 n2 1).5O LS rfl 0Gl 7$L a)o.'j3 t5 11' (o (,c '151 )'1 O.6D 2S Averaqe .44 x COzo/o + 32 x Ozo/o + .28 x Nz% = - (Md) (_ Md ' _1-Bws) + ('!8 '_Bws) = _ (Ms) 85.49 x cp. Vs'Flue Area , 60 =acftn G: 17.647 , acfm , Ps =Ts oR DS-001 Method 2 Pitot Sheet Project No. M2429'l0A Rotary Kiln Exhaust (K-1) Scfmx60=_scftl Rev. 1.3 80 of 159 1t25t2022 @Mostardi Platl ft/sec (vs) l-lulr,,. (ut\ lnr project Number: Volumetric Flow Rate Determination Field Data Sheet Client: t'11.t Zq iu Date: Start Time:SOUrCeCOndition: ffi v,qr,,,ri. __lJ iO TestEnginee, t-t"t o'1 Endrime: J,,..!iz-Ev TestTech; F zt(LDuct Diameter rL .(r g ft ,,_^^-- -Frue Area _---rtl Hff,'::T^?Xfa1ce, Diameters 2.s 44 x COzo/o + .32 x Ozo/o + .2gX N2o/s = -- (Md) ( Md , 1-Bvra) + (1g ,,Bws) = _ (Ms) 85.49 x Vs. .,m: Flue Area , 60 = ill^X1eJ';;rJ"n.%_i;p,,ilTfi Xffi Yfl l:i,iiT"""H-cient(cp)ox1_ Static -.p. 1 ,'H2o o, i/o tm il'r#r#X Leak Checki pG,d@33=,J' ilin^ffi F,*";"flf 5j:,+lH::fl:S, ,e^e r Umbilical lD 17.647, _acfm r,_PS DS-001 Method 2 pitot Sheet Project No. M242}1OA Rotary Kiln Exhaust (K_1) Rev. 1.3 81 of 159 1D5/2022 @Mostardi platt Cp, -/ (-)Ts'R -Ms x ps-ft/sec (Vs) Project Number: Client: Test Location: Source Condition: Test Engineer: 17.U7 . Volumetric Flow Rate Determination Field Data Sheet 11 it{2qt0 Date: Test Number: Start Time: End Time: Test Tech: a,,,,,,- {u.:5) lrrt. 2.-iu,. l(rln Erh,:,r.,{ (r-l) oIf,8 lto'i9. r5 i\ r-\, tI O r,i5 'i{ EV zrc I DS-001 Method 2 Pitot Sheel Project No. M242910A Rotary Kiln Exhaust (K-1) Upstream Disturbance, Diameters I b Downstream Disturbance, Diameters lo.(i F: acfm schnx60=_scfh Rev. 1.3 82 of 159 DuctDiameter ru.rrt: fl Flue Area - t( Port Length tZ " Port Size to.o " Port Type Flrrntr Pitot lDllLi Pitot Coefficient (Cr) r,' gq Pbar 1'r -1'L "Hg CO2o/o t?.LO Wet BUlb Temp Leak Checks Passed@ Static_ "Hg Nz % -?l.b B*. O,ll1 Post 'l lnches H2OP" "Hg Meter No. 2 2 Fluke # Umbilical lD - .44 x COzo/o + .3? x O2o/o + .28 x N276 = _ (Md) (_ Md ' _1-Bws) + (18 '_Bua; = _ (Ms) 85.49 x cp* Vs,Flue Area , 60 = acfm . Ps =Ts'R 1n5t2022 @Mostardi Platt Port- Point #AP Temp. OF J^t' Null Point Angle, Degrees Port- Point #AP Temp. "F J.^P Null Point Angle, Degrees e-l c.s r,L51 A',; 3 25() o -?o. Lo 25]L-2 0. GO 75o A -_)o .;s 253 L-3 o60 )-50 A.A 0st Ls-)( 'r-i o 5q,iso tl'l 05i t5z r)-,() ,;i )4y .1 L O tr5 ?5,L l)1 o.5'z 2qY 11 '"Q, C.O 252 D3 O,LO 2'l Y ar -q D.55 1.5 1^r) 't O. al Lly Averaoe ft/sec (vs) Project Number: Client: Test Location: Source Condition: Test Engineer: 17.647 , Volumetric Flow Rate Determination Field Data Sheet i"lt{ }{ 16 Date i{uirun ( u': ) l-n, .Test Number: Start Time. End Time: Test Tech: tZ.io.* (rln Erh.^,;:ri ti.-t) m,',r Dn Upstream Disturbance, Diameters 2'5 Downstream Disturbance, Diameters scfrnx60=_sclh Rev 1.3 83 of 159 <-i1 1,8 / Zo2'i ,o dc) la .t o EV 1-rc 1 Duct Diameter i0.4t(, ft Flue Area fi2 Port Length t 1 " Port Size G L, " Port Type Flu',r:lt Pitot lD cc I Pitot Coefficient (Cp) o. gq Po.,.[]:_ "Hg CO2o/o t?,IO Wet Brilb Temp Leak Checks Passed@ Static;1).:1"H2O O2o/o 11.50 Dry Bulb Temp Pre '{ lnches H2O Static- "Hg Ne % 1 I )o B*, o' t l', Post '1 lnches H2O P.- "Hg Meter No. 22 Fluke # Umbilical lD .44 x COzo/o + .32 x Ozo/o + .28 X N2o/6 = - (Md) ( Md ,, _1-Bws) + (18 ,_Bws) = _ (Ms) 85.49 x cp-x vFp-: Vs,Flue Area ^ 60 =acfm ""frn,-E =Ts'R DS-001 Method 2 Pitot Sheet Project No. M242910A Rotary Kiln Exhaust (K-1) 1t25t2022 @Mostardi Platt Port- Point #AP Temp. OF J^P Null Point Angle, Degrees Port- Polnt #AP Temp. OF J^t'} Null Point Angle, Degrees A-(1 .55 ,5tl (. -l O 5l l5L) A-t 0.5<26q ('-2 o.sy 2s-o A-7 r_)s('15'i L-1 O scl 25o o-4 o.'; I 25q L- ti osb 2SU R-l C.c, i L53 DI ost 2qz f\2 O.s I 2€J D.L )L zq'L B3 A.GC 2€t Dl o.60 2E2 n11 o 53 is)t) .i (-r Ty zs.2 Average -)TS.R Msx Ps ft/sec (vs) Project Number: Client: Test Location: Source Condition: Test Engineer: 17.U7 Volumetric Flow Rate Determination Field Data Sheet t*r2{ )9 rC Date: Test Number: Start Time: End Time: Test Tech: H._icim (u:))tn( o I l.D ltu 2\ q O-io,t lt,ln F,rh,-.,:it (u -l) i1'\\ o rT EV Jt, q0 tl,it) Lrc 1 Duct Diameter t0.9t, {tFlue Area ft2 PortLength-l-L" PortSize-&-!-"PortType r-lu'n$l PitotlD c't:t PitotCoefficient(Cp)_!,jL P6", 2{. 12 "flg CO2o/o l?.10 Wet BUlb Temp Leak Checks Passed@ Statn- o-., "FlrO Oz% ll.LO Dry Bulb Temp Pre 5 lnches H2O Static- "Hg Nz % "1.)0 8,. O'll1 Post 5 lnches HzO P. "Ho Meter No.'L )- Fluke # Umbilical lD UpstreamDisturbance,Diameters l'5 Downstream Disturbance, Diameters ta.9 .re.- scfmx60=_sclh 44 x COzo/o + .32 x Ozo/o + .28 x N276 = - (Md) ( Md , -1-Bws1 + (18 .-Bws1 = - (Ms) 85.,49 x soR Vst Flue Area , 60 = HS acfm acfm,,E =Ts'R DS-001 Method 2 Pitot Sheet Project No. M2429104 Rotary Kiln Exhaust (K-1) 1t25t2022 @Mostardi Platt Port- Point #AP Temp. OF J^t' Null Point Angle, Degrees Port- Point #AP Temp. OF J^P Null Point Angle, Degrees n-l 0. srl 1-5t)-t D s1 2q3 A-t 0. s5 25s r-L 0ss zra3 R-1 O.6 L)25.j ( _rt 0.sg ltl ) A-ri O.5q L5S c-9 0s9 )e) BI 0. Sr 7E4 DI 0 sl 21q AL 0.,;2 ,t5'l DA o 5()2qa R3 O.':5 lsl D c sb'L1,S (:, r{0. co ls1 p'\O. (.Ll 21Y Average cp * ./-(: 84 of 159 ft/sec (vs) M,r\ On Project Number: Client: Test Location: Source Condition: Test Engineer: Volumetric Flow Rate Determination Field Data Sheet l"lt\ 2tr r (J Date: Test Number: Start Time: End Time: Test Tech: l-1,:lr,m tU-:) in( ll 3r c r, ,8 I :cz'1 /L) (l( 0t Ev Duct Diameter ,io.9b ft Upstream Disturbance, Diameters 2'S - Flue Area ft2 Downslream Disturbance, Diameters tb q eorttengttrll" Portsize r,,l_'PortType Flunqc PitotlD uot PitotCoefficient(Cp) L -({ Pb", 21 12 "Hg CO2o/o 17.19 Wet Bulb Temp Leak Checks Passed@ Static-o.l "ttrO O2o/o ll.5o Dry Bulb Te-mp Pre 1 lnches H2O static- "t-tg ru, y" 1t.qo B*. o.lll Post 5 lnches H2o P.- "Hg Meter No. 2L Fluke # Umbilical lD - .44 x COzo/o + .32 x Ozo/o + .28 X Nzo/o = - (Md) Md' _1-Bws) + (18,_Bws) = _(Ms) 85.49 x cp--f,\P : Vs '. Flue Area , 60 z,Ll 17.647 ,-acfm ' PS = Ts oR DS-001 Method 2 Pitot She€t Project No. M242910A Rotary Kiln Exhaust (K-1 ) scfmx60=_sclh Rev. 1.3 85 of 159 1t25tn22 @Mostardi Platl Port- Point #AP Temp. OF "rAF Null Point Angle, Degrees Port- Point #AP Temp. OF J^P Null Point Angle, Degrees o-t o.5i 7qtl ( -l os7 2s5 fi-2_0-c9 251 L.L c .j(,75E A'l o.L0 25 ri (- )o 5g 255 A-{o c')?5i C-'r r). rr!,2s5 13 "l D. Sb 15'1 9l O.crZ 'zss B.L o.-5q 25r t)Z o- 55 z5S q' .3 05s 2si r)"1 061-)zs, 15-{o.G o 151 D'1 O. i(;)59 Averaqe rtlsec (vs) MERCURY SORBENT TRAP FIELD DATA SHEET :ffiilils,#* oate: 1 / aa / Lq Barometric Pressure: A '4. ^ ? sort"" conoition, m Il o rest Engineer: eO< Dry Gas Meter No.Y= O.98S Trap Number: OL7'Z-bqll Sample Traln A Clock Tlme 2l hour moler Volumeru-l literr Meter lemp.(t-) oF Moter vlcuum,,,Hr ltoroonl r rtP! T.mp. cF Stach Temp. oF loiEe ^. cra tos a aqo ztsll:rr\c- qL t0Y S zqz zss lt',Oi ta, "{t03 q '7,q9 7-AO l: lcl /s. 12-{01 s ZLI9 -7-s9 ,l: 19 2o. L1 lc,3 s z\'.i ZqZ Y,A1 2s. r!,o3 E zLlg zEv tlfl,)3O. r -rs roi 5 zql L4A, Tot UAverlge Dry Gas Meter No. AAft v = l.Nl) Trap Number.oL1L6aZ9 Spike Value - ng Sample Traln B Clock Tim. )A llanr Motar VolumeIV-l llt n Meter lemp. (t-) cF Motor Vlcuum, "l{a [O;tr;o.o@ t0L 3 ll:Dcl s.zl toL 3 lr'.o9 to. 63 loL -1 l,l: lt-t ,8,q5 lr9a .,ls L0, o7 ro5 3 t.,44 25.35 tDs 3 l "'1. ao, Loz t05 3 TotaUAYer!ge Notes Train A: Train B: DS-021 Method 308 Hg Sorbent Trap Project No. M242910A Rotary Kiln Exhaust (K-1) Pre-Test Leak Check - Pass g '?'O "Hg (Must be 2 15"Hg) Post-Test Leak Check - Pass @-LO "Hg Pre-Test Leak Check - Pass @ t$ "Hg (Must be 2 15"H9) Post-Test Leak Check - Pass @_?9-"Hg Rev. 2.'l 86 of 159 Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form D SPIKED AT: Spike Date: Spike Time: SAMPLING INFORMATION A UNSPIKED Production Lot: U-t32a Carbon Lot. 4C QA/QC Signature 1sp,r";. Faciriry / Source: ,Dtfit J f ltl t Boiler tD; samprins Location hbn l{ih Run Number (Optional): LffiAIT / I I l"d} Sampling Train: IG trB tr FAIL sAM pltryc coNDtTlo_N! ANDJARAM ETERS Avg Duct Temp (F"): Avg Trap Temp (F.): Avg Flow Rate (cclmin): TotalVolume (L): or (dscm) Estimated Avg. Hg Concentration (pgldscm): Event 0ccurred During Sampling. tr Startup fl Shutcjown CEMENT ONLY: # of RAW MILL OFF events during sampling. lEqy.LLED tF RETURN|NG ro oHto LUMEX Estimated Hg Mass in Section .l of Sorbent Trap (ng): CHAIN OF CUSTODY ilIIililililIilililItil oL726414 QA/QC SignaturerrrapAssembry)i # tr High Flow tr Fluffy pre-fitter El 185 mm tr 240 mmD Static Pre.filter D AGS O 300 mm O 450 mm Type of Trap: 308 PRE-Run Leak Check: fi eaSS Run Start Date/Time: -t/t0/zl Run End Date/Time: -? /O/21 POST-Run Leak Check: peaSS tr FAIL lb', f7 Sample(s) taken by lf applicable ptace chain of custody seal here. (see security seal instruction sheet) Sample(s) prepared for shipment by Courier/Other (if appticabte) Sanrple(s) received by lab Sample(s) analyzed by Sea I intact aslecelvEd- Lnsurc sampling condilion. tLsprking Method cord vapor Adsorprio^ vi, rrrirg., ip";gi.;'c;,,ii"o a".rracy r .r0%. Traceabre to Nrsr www.gl2i6{qryx.com mail@ohiolumex.com measurement failure in sorbent traps should be prevented Best Before: April ZO2T fl \. 44qq frEfrir&fftrrce*W6mE?{afuqlt_tpe :[*:::'s,lY#y${HF{t( Ont utllEx Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form A UNSPIKED Production Lot: u 1324 Carbon Lot: 4C QA/QC Si gnature (spt.): D SPIKED AT: Spike Date: Spike Time: QA/QC Signature firep rssembty)l D High Flow D Fluffy Pre'filter O Static Pre-filter D AGS Type of Trap: _.308_ SAMPLING INFORMATION Facirig,/Source: "Dt fttt 5 \lu C+l"qt PRE-Run Leak Check: dPass tr FAIL Boiler lD. SamptinsLocation: h4'\A (l tn Run Number (Optional): I SamplingTrain: trA AB SAMPLING CONDITIONS AND PARAMETERS Run Start Dare/rime: >/ I /Zl I p : t T Run End Date/rime: ll t0/zl t I l:J f- POST-Run Leak Check: fnSS tr FAIL ill I til ililll lill lllllll lll oL726329k El 185 mm tr 300 mm tr 240 mm E 450 mm Avg. Duct Temp (F'): Avg. Trap Temp (F"): Avg. Flow Rate (cc/min): TotalVolume (L): Estimated Avg. Hg Concentration (Ug/dscm): Event Occurred During Sampling: D Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling:or (dscm) REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY lf appllcable place chain ot custody seal here. (see security seal instructton sheet) Sample(s) prepared for shipment by Seal intact as received: ves E ruoESample(s) received by lab Seal intact as received: ves El r.ro ElSample(s) analyzed by Sample(s)taken by Ensure sampling conditions prevent moisture in the trap media Moisture condensation is a major cause measurement Sprking Method Cold vapor Adsorplion Via lmpinger Sparging Certified Accuracy t 1096, Tiaceable to NIST \'-..7 44O 264 2500 office etOGE Ern6EaUBl0A free Rotary Kiln Exhaust (K-1) www.ohiolumex.com mail@0fiU|[fr0ex.com ? in sorbent lraps and should be 30350 Bruce lndustrial Pkwy. Cleveland, OH tDM&tdgAlatt Best Before:April 2027 MERCURY SORBENT TRAP FIELD DATA SHEET Project NameNumber: Sampling Location: Date: Source Condition: Dry Gas Meter No Train A: Train B: DS-021 Method 308 Hg Sorbent Trap . Project No. M242910A Rotary Kiln Exhaust (K-1) Run Number: Z Trap Number: Ot-TLbqLo Dry Gas MeterNo. AA\T v = l,@ Trap Number oLlZLSq'l Spike Value - rE Notes: Pre-Test Leak Check - Pass @ l$ "Hg (Must be 2 15"Hg) Post-Test Leak Check - Pass @J-o "Hg Pre-Test Leak Check - Pass @ l1 "Hg (Must be 2 15"H9) Post-Test Leak Check - Pass @_'7-o *Hg Rev.2.1 89 of 159 1nnv21 @Mostardi Platt Sample Train A Clock Time 71 hout Meter Volume ,V-l llt a Merer rGmP. (r.) cF Meter Vecuum, "l.la Sorbent Tr.p! Temp. cF Steck Temp. cF tt95 O.oOo lo7 q ZLiO zsL4 ,'.no B,2t rba 7 z5z zsq ll: qs ,0,1,loz zss 7-s ? u,.60 ,s.63 loz 5 260 2Sj l/: 55 7.o.qti lq a 270 z* 11.-ba 25. o,{or- L -7 (,s .?,9< l?: O(30.loli 1O 7_63 'LE? Total/Average Sample Train B Clock Time )A hant Meter Volume,V-l llt n M€l.r remp. (r-) oF Metor Vlcuum, "Ho l:3\o.ooo loL L ll;t+O 5.Sr l0G t-{ ljqs lo,3:,(25 3 ll,So ,s. E7 ,o5 ?- ,J:trS -?o. 7,4.lo\3 l'LtgD 74s. 36 I O'l q l?t6\3D. tre S la<Lt TotaUAYerrgo illlillillililill oL726420 Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form A UNSPIKED Production Lot: U.132A Carbon Lot: 4C QA/QC Signature (sp*u): SAMPLING INFORMATION Facility / Source: Boiler tD: Sampling Location: Run Number (Optionat) tr SPIKED AT: Spike Date. __ Spike Time: QA/QCSignature(rrapAssembry). .% tr High Flow D Fluffy pre-filter D Statrc pre-fitter O AGS Type ofTrap: 3OB PRE-Run Leak Check Run Start Date/Time: Run End Date/Time: tr FAIL 11r35 lzt05 / /l -/oo* Sampling Train:trB POST-Run Leak Check:D FAIL 9AUpllNG qoNgtfloNs AND PARAMETERS Avg. Ducr Temp (F.);Estimated Avg. Hg Concentration (pgldscm): Avg Trap Temp (F'): Event occurred During sampring: tr startup D shutdownAvg Flow Rate (cclmin) GEMENT oNLy: TotalVolume (L) or (dscm) #of RAW M,LL oFF events during sampling:RlqyllEp tF REr-uRNtNc ro oHto LUMEX Estimared Hg Mass in Section I of Sorbent Trap (ng): CHAIN OF CUSTODY {eass z,/t?/zt z/ts/2.1 E 185 mm O 240 mmO 300 mm D 450 mm Sample(s)taken by lf applicable place chain of custody seal here.(see security seal instruction sheet) Sample(s) prepared for shipment by Courier/Other (if appticabte) Sample(s) received by tab ves El ruo ESample(s) analyzed by www.ohiolumex.com mail@eObltaaex.com Best Before:Aprit ZOZT 30350 Bruce tndustrial pkwy. Cleveland, OH 6&&t6ftratt() \ . r aao 264 25oo office'' Pt48A Ba6rrlftEbioA free Rotary Kitn Exhaust (K_1) Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form lllllilllllllllilllllllllil D oL726347 I 185 mm tr 240 mm O 300 mm tr 450 mm A UNSPIKED Production Lot: Carbon Lot: 4C ! SPIKED AT: u-l32A spike Date: QA/QC Signature (rr8p Asscmblv): Spike Time: tr High Flow tr Static Pre-filter Type of Trap: tr Fluffy Pre-filter tr AGS 308QA/QC Signature tsoii.): SAMPLING INFORMATION Facility / Source: Boiler lD. Sampling Location: Run Number (Optional): Sampling Train: n A PRE-Run Leak Check: Run Start Date/Time: Run End Date/Time: ,d.pass z/tz/z< zlA/zq / I D FAIL ,,;35 1a:oS * POST-Run Leak Check: zAPnSS D FAIL SAMPLING CONDITIONS AND PARAMETERS Avg Duct TemP (F'): Avg. Trap Temp (F'): Avg. Flow Rate (cc/min) TotalVolume (L):or (dscm) REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): - CHAIN OF CUSTODY Estimated Avg. Hg Concentration (pg/dscm): Event Occurred During Sampling: tr Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling: gnsure sampling conOitions prevent moisture condensation in the trap media. Moisture condensation is a major cause spiking Method cold vapor Adsorption via lmpinger sparging certified Accurac-y t '10%, Traceable to NlsT measurement in sorbenl lraps and should be www.ohiolumex.conl .aiter$h$ttf,$ex.com Best Before:April 2027 30350 Bruce lndustrial Pkwy. Clevela nd, OH Qllt5i9tSbAlattI lf appllcable place chain of custody seal here. (see security seal instruction sheet)Sample(s) prepared for shipment by Seal intact as received: ves E r.ro ECourier/Other (if applicable) Sample(s) received by lab Seal intact as received: ves EI ruo ESample(s) analyzed by t L44o2G4 25oo office'.$ffi$f,#ffi18?l_{t"" MERCURY SORBENT TRAP FIELD DATA SHEET Project Name/Number: Sampling Location: Date Source Condition: Dry Gas Meter No. Dry Gas Meter No. /VlR v = l.0@ Trap Number Ou17-6\lO Train A: Train B: Run Number: Pressure: Z\. Test Engineer: PbS Trap Number: OLI?AaZ7 SpikeValue - rE Notes: DS-02't Method 308 Hg Sorbent Trap Project No. M242910A Rotary Kiln Exhaust (K-1) Pre-Test Leak Check - Pass @ l-7 "Hg (Must be ) 15"Hg) Post-Test Leak Check - Pass @_L"Hg Pre-Test Leak Check - Pass @ ,-7 "Hg (Must be 2 15"H9) Post-Test Leak Check - Pass @-!]_"Hg Rev. 2.1 92 of 159 1nno21 @Mostardi Platt Sample Train A Clock Tlmo 21hour Moter Volume lV-l lhon turotor lomp.(t).F Meter Vacuum, "Ha sorbent Tmp! Tomp. cF Strck Temp. oF t?-:lo O.oso los q.253 -z-Ei 12r t!5,51 t(2B -7 a_.1 s 84 l'L'.'i1o,to, ob lDe 7 7-Ltg ?sa 1LzL5 t5.Ltg t04 5 LS7 ?sn t?..a6 ao,6L to5 q,asq zSLl l2:iS 1A. Lj VL -7.57 ZSL( l'7.:40 10. 6q?VZ L z5-7 Z,SLI Tot UAverago Sample Traln B Clock Tlmo 2l hour Metor Volumolv-l ltt I! ilolrr rGmP, (t-) cF Moter Vacuum,it"td lallo 6,ocp l05 2 1artS 5,71 lOt"L l-L'.'to 10, aE 'ltl1 t- 17..L5 I S.5s t01 L 17..'1o.Lo .7't l01 -?- t7.t3s "s. ,s tob l-7 .-,,1O 3o.t tL Itx,3 TotaUAverage Onr I Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form illilffiilll ilililllllll 6327UIUEX X UNSPIKED Production Lot: _U-132A _ Carbon Lot: 4C QA/QC Signature (sp,ke). SAMPLING INFORMATION oL72 ! SPIKED AT: Spike Date: QA/QC Si gnature Crrap Assembry)l D High Flow tr Fluffy Pre-filter E 185 mm tr 240 mm Spike Time D Static Pre-filter D AGS D 300 mm tr 450 mm ype of Trap: 30B_ Facility / Source. Boiler lD: Sampling Location: Run Number (Optional): Sampling Train: fi,a trB SAMPLING CONDITIONS AND PARAMETERS PRE-Run Leak Check: Run Start Date/Time: dnnss z/ts /z* / Run End Date/rime: z/tg lz'l t l1A0 POST-Run Leak Check: flenSS tr FAIL lZ:t0 tr FAIL Avg Duct Temp (F') Avg. Trap Temp (F"): Avg. Flow Rate (cclmin) TotalVolume (L): Estimated Avg. Hg Concentration (pg/dscm): Event Occurred During Sampling: tr Startup CEMENT ONLY: tr Shutdown or (dscm)# of RAW MILL OFF events during sampling: REQUIRED IF RETURNING TO OHIO LUMEX CHAIN OF CUSTOOY Ensure sahpting conditions prevent moisture condensation in lhe trap media. Moislure condensation is a maior cause Splkrng Method Cold Vapor Adsorption Via |mpinger Sparging Certif ied Accuracy t 10%, Traceable to NIST traps and should be preventedm€asuremenl ***.&rt8IJf,P"r."o, mail@ohiolumex.com Best Before:April 2027 30350 Bruce I ngUEHhfbR'lAY. Cleveland, OH 44139 USAI lf applicable place charn ol custody seal here. (see security seal instruction sheet) Sample(s) taken by Sample(s) prepared for shipment by Sample(s) received by lab Seal intact as received: ves El ruo EISample(s) analyzed by \{"ffiff,gffi{lf,n" W. ng so,oe,:?,: :H:;:1lffiody Form illillflffiflfll/lilttt roL726410 A UNSPIKED Production Lot: - u-t3za Carbon Lot: 4C QA/QC Signature (sptu). tr SPIKED AT: Spike Date: Spike Time QA/QC Signature firap assembry). ! Hioh Flow D Ftufty Pre-filtertr Static pre-filter tr AGS Type of Trap: 3OB E 185mm O 240 mmD 300 mm tr 450 mm SAMPLING INFORMATION Facility / Source: Boiler tD; Sampling Location. Run Number (Optional): Sampling Train: D A s4yl.lrNc CoNDtfl oNS AND PARAMETERS Avg. Trap Temp (F,): Avg. Flow Rate (cclmin): n"*.0*0.- ccuracy i 1 0%, Traceabte to N|ST Estimated Avg. Hg Concentration (pgldscm): - .,, Event Occurred During Sampling: D Startup D Shutdown PRE-Run Leak Check: EpaSS Run Start Date/Time: 7/t€/z1 Run End Date/Time: 7/e/2r1 POST-Run Leak Check: ffooSS / / D FAIL 1tu16 lZ'L\o D FAIL TotatVolume (L):or (dscm) CEMENT ONLY: # of RAW MILL OFF events during sampling8FQURED tF RETURNING TO OHto LUMEX -____l Estimated Hg Mass in Seetion 1 nf en,r,^^+ T-^^ ,*,,,*",r",""Fff,"r^i::.l,pj-:gIbentTrap(ng):Notc Anotnet catibrction rcnsc wiil be;;;es;;,r:J;[ Yir% ,,s btank may rcsutt tn Ntor.catibreton anatysts ptcas CHAIN OF CUSTOD' -'--ttvttct'otv'ts nqseconttctusit)lourequ,eossisrtrc. cstimatingthisvatue Sampte(s) taken by Sample(s) prepared or shipment by )ourier/Other (if appticabte) ample(s) received by lab ample(s) analyzed by measuremenl m sorbent lraps Best Before:April ZOZT 7 440 264 2500 office 1 888 sTFeEtrlrteJMpeesr on Rotary Kiln Exhaust (K-1);Iff"1"J,11:X1#" lf appllcable place chain of. custody seal here.(see security seal instruction sheet) ves E ruoE Q :l?l? "ure lndustriat e?S9't"'oi et"ttr Lreveland, OH 44139 USA IIIERC Project Name/Number: Sampling Location: ./ Y?I8o*"ENr rRnp FIELD DArA sHEEr Run Number Pressure: Test Engineer: Trap Number: Source Condition Dry Gas Meter No. Train A: Train B: DS-021 Method 3OB Hg Sorbent Trap Project No. M242910A Rotary Kiln Exhaust (K-1) spike varue Eo --ng ffi;tl'-"*:l;:6g;ffi*;;;Post-rest.";* "i"l* _'iii"fofi x-g rrru", be 2 ls,,Hs) [,".ff l"**l*i;:::.friiltlEi;:,:x*:I";lC;i3:"@%+ Notes: Rev. 2.1 95 of 159 1/lOEtFtardi Platt Onr E UNSPIKED Production Lot: Carbon Lot: 4C N SPIKED AT: u-r 32A Spike Date: QA/QC Signature flrap Assembrv)i tr High Flow tr FluffY Pre-filter tr Static Pre-filter D AGS Type ofTrap: 308 lll I lll lllllll il llllllll lll oL726419 E 185 mm tr 240 mm O 300 mm D 450 mm UfllEX Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form Spike Time: QA/QC Signature (se'ke): SAMPLING INFORMATION Facility / Source: Boiler lD: Sampling Location. Run Number (Optional): LI Sampling Train: fu- tr B SAMPLING CONDITIONS AND PARAMETERS PRE-Run Leak Check. {enSS Run Start Date/Time: Z/t*/4 t Run End Date/rime: Z/ t7fut I PoST-Run Leak Check: { eaSS tr FAIL 19'.6 li r3f tr FAIL Avg. Duct Temp (F'). Avg. Trap Temp (F"): Avg. Flow Rate (cclmin): TotalVolume (L): Estimated Avg. Hg Concentration (Ugldscm): Event Occurred During Sampling: tr Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling:or (dscm) REQUIRED !F RETURNING TO OHIO LUMEX Estimated Hg Mass in Sectlon 1 of Sorbent Trap (ng): - CHAIN OF CUSTODY in sorbent traps be prevented ri r r aoo 264 25oo office' pldfffl rQJ.QrlfrDb {e! free Rotary Kiln Exhaust (K-1) www.ohiolumex.com mail@$rplggex.com Best Before:April 2027 30350 Bruce lndustrial Pkwy. Clevel a nd, oH 6*ffiSldi0r"tt ,nlfI lf appllcable place chain of custodY seal here. (see security seal instruction sheet)Sample(s) prepared for shipment by Seal intact as received: ves El No ECourier/0ther (if appl icable) Seal intact as received ves El r'ro ESample(s) recetved by lab Seal intact as received: ves El ruo El Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form I 1tililil OLC ill 178266 ! UNSPIKED Production Lot: S-5787 Carbon Lot: 4C QA/QC Signature rsp*.r E SPIKED AT: Sons Spike Date: 7/12/2023 Spike Time: 0840 7- QA/QC Signature (Trap Assembry). D High Ftow O Ftuffy pre_fitter tr Static Pre.frtter tr AGS Type of Trap. 3OB PRE-Run Leak Check: deaSS Run End Date/rime: -/t9/'At Run Start Date/Time: -/ / tg lzrl I 185 mm tr 300 mm D 240 mm tr 450 mm SAMPLING TNFORMATION Facility / Source: Boiler lD. Sampling Location: Run Number (Optional): tt Sampling Train. D A Avg. Duct Temp (F.). Avg. Trap Temp (F"). Avg. Flow Rate (cclmin): TotalVolume (L) tr FAIL 13: o5 13:1S POST-Run Leak Check: tr PASS tr FAIL SAMPLING CONDTTIONS AND PARAMETERS Estimated Avg. Hg Concentration (pgldscm). Event Occurred During Sampling: D Startup flshutdown CEMENT ONLY: # of RAW MtLL OFF events during sampling: REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section .l of Sorbent Trap (ng): CHAIN OF CUSTODY or (dscm) Sample(s)taken by lf applicable place charn of custody seal here (see security seal rnstruction sheet) Sample(s) prepared for shipment by Courier/Other (if appticable)Seal intact as rece,ved ves E NoE Sample(s) received by tab Seal intact as receired Seal rntact as rEce;red- Ensure sanptrno Condrlrons orerent msprking Merhod cord vapor ldsorption vra rmpingei ip-ariing i.i,iii.o a..rracy r 10es, Traceabre to Nrsr 1, 44O 264 2500 office $effiUvelvtJU?0leil rreeKotary Kiln Exhaust (K_1) www.ohiolumex.com m a i I @itri6 l.163r e x. co m 30350 Bruce lndustrial pkwy. Cleveland, oH 6t&l$ld$Aratt measurement Spike Varue (D ng Train B: DS-021 Method 3OB Hg Sorbent Trap Project No. M242910A Rotary Kiln Exhaust (K-1 ) [ti$i+i*:fr:{iiffii$r":-l,:; Notes: Rev. 2.1 98 of 159 Train A: l6ff03laroiPtatt A UNSPIKED Production Lot. _ U-rg2a Carbon Lot: 4C QA/QC Signature (sp*.): 9i!t!1!gryF_o_!-MAfloN Facility / Source: Boiler lD: Sampling Location: Run Number (Optionat). Sampling Train 94M?r.lryc coND'flo QAIQC Si gnature Or8p Assembry): 3 !,j,l.ll?L,,,", S iit, Pre-rirrer fype of Trap: 3O_B ilW,, 5Jffflfr o"il3ilfl PRE-Run Leak Check:{eass DB Run End Dare/rime: al g/Zq Run Staft Date/Time: 7/ tg/Zl rneasurem€rtt_t ,nso'beniTEEfrn-E-iE6fr tr FAIL / l3:qq / lq,/c/ tr Shutdown Avg. Duct femp (F"). Avg Trap Temp (F"): Avg. Flow Rate (cclmin) TotalVolume (L): SamOle(s) taken by Sample(s) pruprr"d--.-..-.-- or shrpment by )ourierlOther (if applicable) ample(s) received by lab rmple(s) anatyzed by ry94ry_D $RAMfiERS or (dscm) POST-Run Leak Check:\ cess tr FAIL Estrmated Avg Hg Concentration (i,gzOscm} Event Occurred During Sampling: D Startup \ l;**;,tii,"J[:"" project No. UZniglOA Rotary Kitn Exhaust (K-1) Best Before: April2027 fl 3[t[il:t lXtg...j#,eutardi P,arr ;xb:?fi,il[aaffi, Ohio L Hs so rbe ,,i'i;H ll,i?,l,lody Fo rm ' ,t.. tr SPIKEDhT: Spike Date. _ Spike fime: tr appticabre pr..ullll .^_ custodysealhere (see security s-e] jnliir.,ion v9r E rvo EseatintiEiJGffi I"r E rvo E Unr QA/QC SignatUre (rrap Assembry)i D High Flow D Fluffy Pre-filter tr Static Pre-frlter tr AGS Type ofTrap: 308 ill ru il r ilillll lllllll I lll o1C167418 8l 185 mm D 240 mm tr 300 mm O 450 mm tr FAIL ll:er{ tq lq UIJ4EX Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form D UNSPIKED Production Lot: S-55EA Carbon Lot. 4C QA/QC Signature (sp,re): A SPIKED AT: Sone Spike Date: 4/2112023 Spike Time. 1257 -7,t SAMPLING INFORMATION Facility / Source: Boiler lD: Sampling Location: Run Number (Optional): Sampling Tratn: flA SAMPLING CONDITIONS AND PARAMETERS Avg Trap Temp (F"). Avg Flow Rate (cclmin) TotalVolume (L): A.-/ PRE-Run Leak Check: ,ftott Run start Date/Time: 7/ 14 /4 Run End Date/rime: z /tgkl / / POST-Run Leak Check: tr PASS tr FAIL Event Occurred During Sampling. tr Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling:or (dscm) REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY lf applicable place chain of custody seal here (see security seal instruction sheet) Sample(s)taken by Sample(s) prepared for shipment by Courier/Other (if applicable) Seal intact as received ves E r.ro E Seal intact as received: ves El r.ro E Seal intact as received ves E r'ro E Sample(s) received by lab Sample(s) analyzed by Ensure sampllng condrtions prevent moisture condensation in the trap medra Moisture condensation is a major cause Spikrng Method Cold Vapor Adsorption Vra lmprnger Sparging Certified Accuracy t 10%. Traceable to NIST in sorb€nl traps and should be prevented Best Before: April 2026 I 44O 264 2500 office 1 888 876 2611 toll free Project No. M242910A Rotary Kiln Exhaust (K-1) www.ohiolumex. co m mail@ohiolumex.com 30350 Bruce lndustrial Pkwy Cleveland, OH 44139 USA 100 of 't 59 measuremenl @Mostardi Platl MERCURY SORBENT TRAP FIELD DATA SHEET ProiectName/Number: /qZLlA?tO Sampling Loca{on: Date: 7/l Source Condition:il Dry Gas Meter No. Antt la5 V - Dry Gas Meter No. Nll3 Y = LAAO Trap Number. Run Number; 6 Pressure: aJ+32 Test Engineer: Trap Number: OLIZCZS? --owcll%L?l Spixe Vatue SO ng Notes: Train A: Train B: Pre-Test Leak Check - Pass @ la "Hg (Must be 2 15"Hg) Post-Test Leak Check - Pass @jE-"Hg DS-021 Method 308 Hg Sotent Trap Project No. M2429104 Rotary Kiln Exhaust (K-1) Pre-Test Leak Check - Pass @ 18 "Hg (Must be ) 15"Hg) Post-Test Leak Check - Pass @-|]-"Hg Rev. 2.1 101 of '159 1t1/2021 @Mostardi Platl Samole Train A Clock Tlmo 24 hout Metar Volumelv-l liiaB Motor Temp. (t-) cF Metor vlcuum, "lld lioro3nt r raPl Tcmp.cF St ck Tomp. oF lLl'..7l)o.@ tb7,b ?1z a93 t4flE s. ls lol tr 2qq zE< l4tJg Lo. z5 lol 1 7t3 a57 14t Jb 1q.73 ra 5 2K7 zsz tn'.L{n 7p.13 ,D5 5 -735 ZEtT I Y:qq ?$ , Llj l01 a a-7?L5 lHz5o.3Q. ot'.tn Z1\z5a Tot UAvetrgo Samole Train B Clock Tlme ,A h^tt? Meter Volume IVJ llters Mster Tomp. (t").F MGtor Vrcuum, "t{o lLlr1n D-oq9 lo?L. lu:z>S,\A los -?- t1"70 lh-01 ros -z_ llt2S ls. sa l06 '7- lLi Ib 79.6b l(Y^tl- lLtt[g '7s. -71 t07 z l9rED ,Lr)-o 30 ICJ? TotalrAverrgo A UNSPIKED Production Lot: Carbon Lot. 4C QA/QC Signature (spir.). SAMPLING INFORMATION Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form ililIililIIilililrilil oL726289 tr SPIKED AT: Spike Date: QA/QC Si gnature (rrop Assembrv): tr High Flow D Fluffy Pre-filter El 185 mm tr 240 mm Spike Time: D Static Pre-filter D AGS o 300 mm O 450 mm Type of Trap: _ 308_ Facility / Source: Boiler lD. Sampling Location: Run Number (Optional): Sampling Train: d.A PRE-Run Leak Check: Run Start Date/Time: Run End Date/Time: {Gass 7/(81?A t/t{/zq tr FAIL 11tn6 tLt250, I / 6 trB POST-Run Leak Check: tr PASS I] FAIL SAMPLING CONDITIONS AND PARAMETERS Avg. Duct Temp (F'): Avg Trap Temp (F'): Avg Flow Rate (cc/min). TotalVolume (L): Estimated Avg. Hg Concentration (pg/dscm): Event Occurred During Sampling: tr Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling:or (dscm) REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY gns.lre sarnptrnO conOitions prevent moisture condensation in the Itap media. Moisture condensation is a major cause Spiking Method Cold Vapor Adsorption Via hpinger Spargrng Certified Accuracy I 10%, Traceable to NIST traps and should be prevenledmeasurament t . r 44o26425oooffice' +"?"8.q ffi 9#r4}tl8l r'"" Rotary Kiln Exhaust (K-1) www.ohiolumex.com e Best Before:April 2027 30350 Bruce lndustrial Pkwy. Cleveland. OH 44139 USA' @Mostardi Platt lf appllcable place chain of custody seal here. (see security seal instruction sheet)Sample(s) prepared for shipment by Seal intact as received: ves EI r.ro ECourier/Other (tf apphcable) ves E ruoESample(s) received by lab Seal intact as received: ves fl ruo ElSample(s) analyzed by mail@,9!ioJqg6ex.com l)ut Ohio Lumex Co., lnc' Hg Sorbent Trap Chain of Custody Form Iil I lil lll I llilllllllll llll I lil o1c178231 I 185 mm tr 240 mm D 300 mm D 450 mm ! FAIL t lt+{?n t llr '50 Urj4EX D UNSPIKED Production Lot: S-5787 Carbon Lot: 4C QA/QC Signature (se'ke): I SPIKED AT: Sons Spike Date: 7 /12/2023 Spike Time: 0840 1---' SAMPLING INFORMATION Facility / Source: Boiler lD: Sampling Location: Run Number (OPtional): Sampling Train: tr A SAMPLING CONDITIONS AND PARAMETERS Avg Duct Temp (F"): Avg. Trap Temp (F"): Avg. Flow Rate (cc/min): TotalVolume (L): QA/QC Si gnature (Trap Assembrv)l D High Flow D FluffY Pre-filter D Static Pre-filter tr AGS Type ofTrap: 30B Run Start Date/rime: 7/l</"4 PRE-Run Leak Check: fifnSs Run End Date/rime: 7/H k'l POST-Run Leak Check. tr PASS tr FAIL Estimated Avg. Hg Concentration (pg/dscm) Event Occurred During Sampling: tr Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampltng:or (dscm) REQUTRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng)' CHAIN OF CUSTODY lf applicable place charn of custody seal here (see security seal instruction sheet) Sample(s) taken by Sample(s) prepared for shipment by Seal intact as received ves fl ruoECourier/Other (if applicable) Seal intact as received ves fl ruo DSample(s) received bY lab Seal intact as received: ves f] r.ro ESample(s) analyzed bY is a ma'or cause of measurementEnsr/e sarnpi,ng cond,f@rn the trap medla. Molsture condensation Sp*,ng Naefi'odtold Vapor Ad:orpton Via lmprnger Sparging Certified Accuracy t 1096, Traceable lo NIST traps and should b€ Prevented Best Before: July 2026 . 1 440 264 2500 office 1 888 876 2611 toll free Project No. M2429104 Rotary Kiln Exhaust (K-1) \,,www.olriolumex.com mail@ohiolumex.com 103 of 159 s0350 Bruce lndustrial PkwY Cleveland, OH 44139 USA @Mostardi Platt MERCURY SORBENT TRAP FIELD DATA SHEET Project Name/Number: fln-qZ9 tO Sampling Locetion:aiM Run Number: 7 Date:Barometric Pressure: ?-({,-t Z Source Condition Test Engineer Dry Gas Meter No.Trap Number: Samole Traln A Clock Time ,A h^ttr Mot r Volumeru-l llt.E Meter ramp.(t) .F Meter Vacuum, "Ha Sorbent Trrp. Temp. cF Stlck T€mp. cF tq: lq U,W roi t-a.7O zs7 lS; l:5, E7 lol *7 z-33 z5? l\!zq LA, qZ lo -777 )<< t\"1,9 Lq,7?lo'1 1 2-70 a1.t ls j3tt ?,0, l9 h? 5 Trel ?-s,3 lS:?9 aq,3t (f{a aal ?-sz tS,1'f 30, o-6E,to-5 1 z5?75?, TotalrAvotege DryGasMeterNo. f1At3v= l'@O Trapruumber OLCI?I\O7 spikevalue - ng Samole Train B Clock Tlme 24 hour lleter Volumalv-l llt E Meter Temp.(t.) cF Moter Vrcuum, "l.la lE:ltl u.o@ Iro L lE: l9 q.q I ) t 5'. zq lo-zz o j t5:Zy ls, ti o t5:311 zO.zt 1 Z l5:39 zs. qs LW L lS'Ll{3o.os a I()-(- TotrlrAvor!go Pre-Test Leak Check - Pass @ l-7 "Hg (Must be 2 1S"Hg) Post-Test Leak Check - Pass @-]$--"Hg Pre-Test Leak Check - Pass @ l-7 "Hg (Must be 2 15"H9) Post-Test Leak Check - Pass @J-2-"Hg Notes: 1t1t2021 @Mostardi Platt Train A: Train B: DS-021 Method 30B Hg Sorbent Trap Project No. M2429104 Rotary Kiln Exhaust (K-1) Rev. 2.1 104 of 159 Ohio Lumex Co., lnc. A UNSPIKED Production Lot.. U-12E7 Carbon Lot: 4C QA/QC Signalure (sp,ke) SAMPLING INFORMATION Facility / Source: Boiler tD: Sampling Location: Run Number (Optional): Sampling Train: tr A Avg. Duct Temp (F"): Avg. Trap Temp (F.): Avg. Flow Rate (cclmin) TotalVotume (L): QA/QC SignatUre (Trep Assembty). D High Flow D Ftuffy pre-filter E .lg5 mmtr Static Pre-fitter O AGS O gOO mm Type of Trap: 308 PRE-Run Leak Check: Run Start Date/Time: Run End Date/Time: Inass*// t(lzLl lS'.tt1 Z/ts/z't t 6: Llq POST-Run Leak Check:tr PASS tr FAIL SAMPLING CONDITIONS AND PARAMETERS REQUIRED IF RETURNING TO OHIO LUMEX Estimated Avg Hg Concentratlon (pgldscm). Event Occurred During Sampling: D Startup D Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling: Estimated Hg Mass in Section 1 of Sorbent Trap (ng). CHAIN OF CUSTODY Hg Sorbent Trap Chain of Custody Form D SPIKED AT: Spike Date. Spike Time. }{B or (dscm) iluiltiltiliiiflitili oLcLgL407 ,/. . ,r'r/,/ L- D FAIL tr 240 mm tr 450 mm Sample(s) taken by f- signature I I Time Seet rriiv Qaai lf applicable ptace chain of custody seal here (see securrty seal instruction sheet) Sample(s) prepared for shipment by Courier/Other (if applicable)seat rntact as received ves E ruo flSample(s) received by tab Sea I tntact ail66er=iEJ yes fl ruo flSample(s) analyzed by sorben Seal intact as recerved yes fl ro Esp*ins r'aet[oj"coil;;", i;ffi ;#,,;.',ff,""H:3iXtil[;:..ffi,o IS#,$"]m ?"# ,ensation and should be 1 440 264 2500 office P8ft8t$76 0p42etdAfree Rotary Kiln Exhaust (K_1) www.ohiolumex.com mail@SBqlpruBx com Best Before: January 2027 30350 Bruce tndustrial pkwy. clevelarr d, oH UrIJS#SSr"n ti') Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form X UNSPIKED D SPIKED AT: Production Lot: U-l32A SPike Date. C High Flow tr Fluffy Pre-filter Carbon Lot: 4C Spike Time: tr static Pre-filter 0 AGS QA/QC Signature 1so*.1: Type of Trap 99-B SAMPLING INFORMATION QA/QC Signature (rrap Assembly)l lll llillllllll lllilll llllil ft oL726298 z@ El 185 mm D 240 mm tr 300 mm tr 450 mm Facility / Source, Boiler lD: Sampling Location: Run Number (Optional) Sampling Train; Xa trB SAMPLTNG CONDTTIONS AND PARAMETERS a PRE-Run Leak Check Run Start Date/Time Run End Date/Time ftenss lfi<lttt 7/s/zq I I tr FAIL 15,tl I s:qq POST-Run Leak Check: y'g PASS tr FAIL Avg. Duct Temp (F"): Avg. Trap Temp (F"). Avg. Flow Rate (cclmin) lotal Volume (L): Estimated Avg. Hg Concentration (Ug/dscm): Event Occurred During Sampling: u Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling:or (dscm) REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY Ensure sampllno condiiions prevenl moisture condensation in the trap media. Moislure condensation ls a major cause Spiking Method Cold Vapor Adsorption Via lmpinger Sparging Certified Accuracy ! '101, Traceable to NIST measurement traps and should be prevented Best Before:April 2027 \. r 44026425oooffice- #r8"8"q fi36jf[tl8X free www.ohiolumex.com mail@,'9[io/1gex.com 30350 Bruce lndustrial Pkwy. Cleveland. OH 44139 USA' @Mostardi PlattI lf applicable place chain of custody seal here. (see security seal instruction sheet) Sample(s)taken by Sample(s) prepared for shipment by Seal intact as received: ves E NoECourier/Other (if appltcable) Seal intact as received ves E ruoESample(s) received by lab Seal intact as received: ves E ruo EI Rotary Kiln Exhaust (K-1) MERCURY SORBENT TRAP FIELD DATA SHEET Project Name/Number:Y?9lb Sampling Location:Run Number: At8.Barometric Pressure: aLL1.7 z Source Condition; Dry Gas Meter No TestEngineer: &< Trap Number: Ol-CPlGZl Dry Gas 11is1s1vs./'All3 y = l'O@ Trap Number OuLtjo?93 Spike Value - ng Notes: Train A: Train B: Pre-Test Leak Gheck - Pass @ lg "Hg (Must be 2 15"Hg) Post-Test Leak Check - Pass @)-- "Hg Pre-Test Leak Check - Pass @ lZ "Hg (Must be 2 15"H9) Post-Test Leak Check - Pass @_!-E-_"Hg DS-021 Method 308 Hg Sorbent Trap Project No. M2429'l0A Rotary Kiln Exhaust (K-1) 1nno21 @Mostardi Platt Samole Train A Clock Time 24 hout Itlcter VolumeIV-l llten moter Tomp. (t-) cF Meter Vacuum, "l{d sorDenr r rapl femp.cF Stlck Tomp. CE th|6 o.@ loi q z'19 ZSLl tG..o5 S, U7 {o\7 zal zss tL-.to lu.q5 loi 1 ?1i zq,L. lb" ls !tr,, 1L lrfl 5 7L9 2gs l-','lrv 46 .9\lo S q atA z5q tb'.as 7,q,$s lo7 -t '7 L'7 zss tL-9 1s.o!.L OA 4 z<9 7q< Tot l/Avorage Samole Traln B Clock Tlms )l hann Meter Volumo lv-l lit.n il3tor remp. (t-) oF Moter Vrcuum, "Ho lL'.@ (o.006 lo9 '7 lL,.o\q.qL tdt 'z_, lL:lO n.qq lOo '?_ |L-lq lq,, Lg,ld Z .-'7 n ?,D. 3t ilo (r lL'.',?-s 25,'LA lo9 Z tL.a(39.o7.-7 lo 4,, Tot!UAvotrga Rev.2.1 107 of '159 Run Start Date/rime: 7/rc/At illltiltililliifiiillltltr,, D FAIL r l6,ra Run Number (Optional): Sampling Train: ,ru SAMPLING CONDITIONS AND PARAMETERS PoSr-Run Leak Check: yIeASS RunEndDare/rime: 7/tt/zq t 16t3d D FAIL Estimated Avg. Hg Concentration (prgldscm): Event Occurred During Sampling: tr Startup tr Shutdown CEMENT ONLY: # of RAW MtLL OFF events during sampling: REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form E UNSPIKED Production Lot: U-l2E7 Carbon Lot. 4C QA/QC Signature (sp,ke): SAMPLING INFORMATTON Facility / Source. Boiler lD: Sampling Location; Avg. Duct Temp (F.): Avg. Trap Temp (F.). Avg. Flow Rate (cclmin) TotalVolume (L). oLclg1.62L QA/QC Si gnature firap Assembry).'/:'(' D High Flow D Fluffy pre-fitter g tgS mm tr 240 mmO Static Pre-fitler tr AGS O 300 mm D 450 mm Type of Trap: 308 PRE-Run Leak Check; _,,(naSS N SPIKED AT: Spike Date: Spike Time: trB or (dscm) Sample(s)taken by lf applicable place chain of custody seal here (see security seal instruction sheet) Sample(s) received by tab Sample(s) anatyzedby ves E NoEmeasuremenl failure in l44O 264 2500 office lo8utSgo EBiEtulAfreeRotary Kiln Exhaust (K_1) , . www.ohiolumer.com' mail@t08dtr160x.com Best Before: January 2OZ7 30350 Bruce lndustrial pkwy. Cleveland, OH 6p3ig491p,",, o,,Trap lD Ull4EX Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form A UNSPIKED Production Lot: U-l2E7 Carbon Lot: 4C QA/QC Signature (sp,r.): N SPIKED AT: Spike Date: Spike Time: SAMPLING INFORMAT!ON Facility / Source: Boiler lD: Sampling Location. Run Number (Optional): Sampling Train. tr A SAMPLING CONDITIONS AND PARAMETERS Avg. Duct Temp (F"): Avg Trap Temp (F'): Avg. Flow Rate (cclmin): TotalVolume (L): or (dscm) I tr 240 mm tr 450 mm / I ilt r tilu l lffilllll ll llll lil o1C190993 I 185 mm D 300 mm QA/QC Si gnature (rrap Ass€mbly). D High Flow tr Fluffy Pre'filter O Static Pre-filter D AGS Type of Trap. 308 Run End Date/rime: Z/lglZl T] FAIL l6:oo 16,% POST-Run Leak Check. tr PASS tr FAIL Estimated Avg. Hg Concentratron (pgldscm). Event Occurred During Sampling: tr Startup D Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling PRE-Run Leak Check: {raSS Run Start Date/rime: 7/rc/Z'l g 6€ REQUIRED tF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY lf applicable place chain of custody seal here. (see security seal instruction sheet) Sample(s)taken by Sample(s) prepared for shipment by intact as recerved Courier/Other (if applicable) Seal intact as received ves E ruo flSample(s) received by lab Sample(s) analyzed by Seal intact as receiveci ves E r.ro f] conditrons prevenl moisture Spiking Methodbold Vapor AdsorptDn Via lmprnger Sparging Cerlifled Accuracy t 107,. Traceable to Nlsl rn lhe trap rnedra Motsture ion is a maior cause of measurement rn sorb€nt lraps and should be prevented L 440 264 2500 office fstrhUs lBfft8tqrreeRotary Kiln Exhaust (K-1) ' . www.ohiolumex.com i :''j mail@Aflfld[rtF8x,com Best Before: January 2027 30350 Bruce lndustrial Pkwy. cleveland, oH gilg91r$Flatt{ proiect Name/N,,#,2ZTrY.t ?IB E NT TRA p Fr E L D DA TA s H E E T Train A: Train B: DS-021 Method 3OB Hg Sorbent Trap Project No. M242910A Rotary Kiln Exhaust (K-1) Sampling Location: -dafi-E Source Condition: Dry Ges Meter No. Dry Gas Meter No.@y = l.@ Trap Number oLc trt t I"fl:l';;;""1ps_TrapNumber:_algE Run Number: Spike Value rE Notes: Itt*[ril*ii.iriffiiiffi :::];1,, Rev.2.1 110 of 159 SampteffiT lollGilardi Platt Oxr UT}4EX Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form A UNSPIKED Production Lot: U-12E7 Carbon Lot: 4C QA/QC Signalure (se,kc): D SPIKED AT: Spike Date. Spike Time: QA/QC Signature (rrap Assembry)l ft High Flow D Fluffy Pre-filter tr Statrc Pre.filter U AGS Type of Trap: 308 PRE-Run Leak Check.PASS tr FAIL SAMPLING INFORMATION Facility / Source. Boiler lD: Sampling Location: Run Number (Optional): Sampling Train:trB SAMPLING CONDITIONS AND PARAMETERS Avg Duct Temp (F"): Avg. Trap Temp (F"): Avg Flow Rate (cc/min): TotalVolume (L). ilffiililliftinllmlllil oIc191012 /I/,y ( 8185mm D240mm O 300 mm D 450 mm Run Staft Date/rime: 7/ lzf Z1 /l6r Lto Run End Date/rime: 7/tg lZ,l r 11 : lb or (dscm) REQUIRED !F RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng). CHAIN OF CUSTODY POST-Run Leak Check: D PASS tr FAIL Estimated Avg. Hg Concentration (pg/dscm): Event Occurred During Sampling. tr Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling: lf applicable place chain of custody seal nere (see security seal tnstruction shee0Sample(s) prepared for shipment by Seal intact as received ves fl r.ro ECourier/Other (if apPlicable) Sample(s) received by lab Seal intact as received. ves fl uo fl Ens,lre sarnpll|lg conditions prevent moisture condensation in lhe trap media. Molsture condensatlon ls a maror cause ip*lng M"ritodtoH vapor Adsorpuon Vra hpinger Spatging Certilred Accuracy t '101, Traceabh lo NIST . i 440 264 2500 office' P8fi8tStS frQ4tu@Afree Rotary Kiln Exhaust (K-1) www.ohiolumex.com mail@9f{qffi6x.com Seal intact as received ves E NoD sorbent traps and should be Best Before: January 2027 30350 Bruce lndustrial PkwY. cleveland, oH 6tr3&#fiSr.tt measuremenl rr Ont lrap lt) ilr I tilililllllllll lllllril lll o 1c191180Ul)tEX Ohio Lumex Co., Inc. Hg Sorbent Trap Chain of Custody Form A UNSPIKED Production Lot: U-12E7 Carbon Lot: 4C QA/QC Signature (sp,ke): SAMPLING INFORMATION Facility / Source: Boiler lD: Sampling Location: 'ORun Number (Optional): / Sampling Train: tr A tr SPIKED AT: Spike Date. Spike Ttme: (B QA/QC Si gnature (rrap As$mbty): ! High Flow D Fluffy Pre'filter D Static Pre-frlter tr AGS Type of Trap: 308 ,. ,//Z'" \- E 185 mm tr 240 mm D 300 mm E 450 nrnr PRE-Run Leak Check. Run Start Date/Trme: Run End Date/Time 4pnss 7/tul zt 7/r<lut tr FAIL r \L'no r lz: lo SAMPLING CONDITIONS AND PARAMETERS Avg. Duct Temp (F"). Avg. Trap Temp (F"): Avg Florv Rate (cclmin): Total Volume (L). or (dscm) POST-Run Leak Check: D PASS tr FAIL Estimated Avg. Hg Concentration (pg/dscm): Event Occurred During Samphng: D Startup tr Shutdown CEMENT ONLY: # of RAW MILL OFF events during sampling. REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY lf applicable place chain of custody seal here (see security seal instruction sheet) Sample(s) taken by Sarnple(s) prepared for shipment by Seal inlact as recerved Yes E ruoECourier/Other (if appIcable) Sample(s) received by lab Sample(s) analyzed by @o|sturecondensalioninthetrapmedia'MoistUrecondensationisama,orcauseolrneasUremeot Sprktng Melhod Cold Vapor Adsorptron Vta lmpinger Sparging Cerlified Acculacy I l01,, Traceable to NIST in sorbent traps www.olr iolu mex. com mail@olnir6frmcx.com intact as received: ves E No fl Seal intact as received. ves fl No E be prevented Best Before: January 2027 :, 30350 Bruce lndustrial Pkwy. Cleveland, oH 4dr{l3&#8&ratr L 44O 264 2500 office P8f&8il6. l,&hltldhf re e Rotary Kiln Exhaust (K-1) MERCURY SORBENT TRAP FIELD DATA SHEET Project Name/Number:llrzYz"lo Sampling Locationr Sn lllln Run Number: Date .BarometricPressure: Zq.aZ Source Condition: Dry Gas Meter No DryGasMeterNo. flqo '= lo@ TrapNumber Ovc,t9tO\l Test Engineer: Ea Trap Number: 01L19l ?a\ Spike Value = ,r9 Notes: Train A: Train B: Pre-Test Leak Check - Pass @ tb -"Hg (Must be ) 15"Hg) Post-Test Leak Check - Pass @_]^?_"Hg Pre-Test Leak Check - Pass @ l-7 "Hg (Must be ) 15"Hg) Post-Test Leak Check - Pass @__17__"Hg Rev. 2.1 113of159 D$021 Method 308 Hg Sorbent Trap Project No. M242910A Rotary Kiln Exhaust (K-1) 1t'12021 @Mostardi Platt Sample Train A Clock Tlme 24 hour Metor Volume(V-l liter! ilete7 temp(t) .F iloter V!cuum, "Ho soroonr r raps Temp. cF Stlck Tomp. cF H;al o.o@ tfl L{zb3 7-e q lz:5c S,o-7 lot 7 2*o zSS t-7 lLtl lo. tl7 o-L 7 z-72 'z(q l-l:'lr"15,37 oz S 7r{.7 AELll:5 lD,69 v a 7-1"5 zs\ l-t'.9L '7 9. ct 9'a -7 t^r 7qL la'.ot jo, o b5 ?-7 ?.5',)aE/- TotrUAwitge Samole Train B Clock Time 24 hour Metcr VolumelV-l lltcn Meter T.mp.(t) oF ileter Vlcuum, "Ho t-?|il h.ooo ICB n- l-?21[,,,8 L toz <-, l-:Lll lo' lz 0:{t?:4L 15.?'DY.'5 l-?:51 a,\q ax -L l-?.5L z5.ob tcR L8'.Ot '10.@1.oa TotluA\rorage Cur A UNSPIKED Productron Lot: U-12E7 Carbon Lot. 4C QA/QC Signature rsp,r.t: t] SPIKED AT: Spike Date. Spike Time: QA/QC Signature (Trap Assembry); D High Flow tr Ftuffy pre,fitter D Statrc Pre-frtter D AGS Type ofTrap: 308 illlIiltililliitiliill olc19 L394 ,l -../-//'- ( I 185 mm D 240 mm tr 300 mm D 450 mm UMEX Ohio Lumex Co., lnc. Hg Sorbent Trap Chain of Custody Form SAMPLING INFORMATION Facility / Source: Boiler lD. Sampling Location. Run Number (Optional):to Sampling Train:uB SAMPLING CONDITIONS AND PARAMETERS Avg. Duct Temp (F"). Avg Trap Temp (F.): Avg Flow Rate (cclmin) TotalVolume (L):or (dscm) PRE-Run Leak Check: Run Start Date/Time Run End Date/Time: tr FAIL l-t:Sl lg !ol POST-Run Leak Check. tr PASS I] FAIL Estimated Avg Hg Concentration (pgldscm): Event Occurred During Sampling: tr Startup D Shutdown CEMENT ONLY: # of RAW MtLL OFF events during sampling. REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY ;d_enss 7ls/z''l 7/oft4 Sample(s) taken by lf applicable place chain of custody seal here (see security seal instruction sheet) Sample(s) prepared for shipment by Courier/Other (if applicabte)Seal rntact aslecE,veO yes E ruo EI Seal intact as rec-erve-_i' ves fl ruo E Sample(s) recerved by lab Sample(s) anatyzed by Seal intact as received Entrra aaap sprkrng Merhod cord vapor ldsorprion v," r.prg"i ip;-ig,;',q'i";r,i*d l*uracy I 10,,, Traceabre ro Nrsr tn traps and Best Before: January 2027 1440 264 2500 officeP&E8il6 l&ltgrdAfree Rotary Kiln Exhaust (K_1) www.ohiolumex.com mail@qh4{pfBgx.com 1 30350 Bruce tndustrial pkwy. Cleveland, oH €r*i$#5fFr"tr UMEX Ohio Lumex Co., tnc. Hg Sorbent Trap Chain of Custody Form Trao lD lltIilliltlflilililIltItil, o1C191041 QA/QC Signature firap Assembly). E Hrgh Flow tr Ftuffy pre-fitter O Statrc Pre-fiiter tr AGS Type ofTrap: 308 SAMPLING INFORMATION Facility / Source: Boiler tD: Sampling Location. Run Number (Optionat): l0 SamplingTrain: DA N SAMPLING CONDITIONS AND PARAMETERS Orr A UNSPIKED Production Lot: U-12E7 Carbon Lot: 4C QA/QC Signature (sp,ke): D SPIKED AT: Spike Date: Spike Time: 4-C E 185mm D240mm D 300 mm tr 450 mm PRE-Run Leak Check Run Start Date/Time: Run End Date/Time: Ieass tr FAIL 7/6/2tl lz:jt l8'.ot7/ts/z,r POST-Run Leak Check: tr PASS I] FAIL Avg Duct Temp (F'): Estimated Avg Hg concentration (pg/dscm). Avg Trap Temp (F"): Event occurred During sampring: D startup D ShutdownAvg. Flow Rate (cclmin): CEMENT ONLY:Total Volume (L): or (dscm) # of RAW MtLL OFF events during sampting. REQUIRED IF RETURNING TO OHIO LUMEX Estimated Hg Mass in Section 1 of Sorbent Trap (ng): CHAIN OF CUSTODY lf applicable place chain of custody seal here(see securrty seal instructron sheet) Sample(s) prepared Courier/Other (if appticable) Sample(s) received by tab seat intactislE6Evdd Sample(s) anatyzed by Seat intaciaiE6EGd measurement rn sorbent lraps be prevented 7 44O 264 2500 office [Em$ts D8fieCIAfreeRotary Kitn Exhaust (K_1i ,--, www.ohiolumex.com\ . 1 mail@Ot6dtr160x.com Best Before: January 2027 r 1 30350 Bruce lndustrial pkwy., Cleveland, OH tftilES#fflrratr Appendix G - Calibration and Response Time Data Project No. M242910A Rotary Kiln Exhaust (K-1) 1 16 of 159 @Mostardi Platt ENN- tr a ! tdSE f, E oo=oO) ro 9s9or\ il ai 1 I f, I i{Ittti I i3t -I!!Iir:ExlIrE $n {n i Et :,a( :tr :i:r :,a( IE IE IIrF 1EEF rlrI t It *t *l ; {i t :lfi i I3I EEtE.3{ Eal ol tPJtEEEe :Ia 3Ia JIa :Iz -t*l I t E ,E BIIBt.1 I Et!&E. :t3iI- n o[*EF n a E? :fi :tz :EZ :ti a35&, 9 N= IPNi> IT J ci S z*6> 8. 9 . 8 E 95 'E o . 0 a oI .: 8 , ai i ? ;= E !! i E g z .EtA S = B r l a r t EE I€ T *^ E E 'I tiii6o NNN- tr OEESEbE oo=oO) lr , 9s9o@ B!ItIIa2!i3{ E8r IrtF B 6EI 5: t?t; E Br ;t!rIc I t t IIE!&El!3iEai {rEF E Et :EI :€I 1E :qEt IP :E IEa r <Y ovL6$E9! i = lr J ci S z26> E. q 6 E 96 Eo c oo sI $ i9 E sH I >i o o il l t iE i : 3 5E n; zEq AsE -e ! fE i = i T . ! != E d 6 3 qi Lt s E c3 Ito (r OEdbE oo2o EI It.t 6s II , lr5T I ! I Hi tl+i lrrl iiet IE3E!&E. Eg FsiEraFEI ::c :!:I :I( o) ro qo 'a rltE l t 6t,Efr lt!E!tttEI t ctEt!&EoIrEEE?t 1II I ii as , I I * *l E 3r IIttg; EttE=t Esl IrEEEEt ::ti( I;3 <Y :oN: r) ! Nt>f i ci S z26> E. q 6 E 96 'P [ t r so .r gE9 6 =. a o r5 i ; *E i , i 8E ; E l6Ep R A t 5 i : ft i = :5 i i 6. 1 3! d3 !t6 NNEa ! EE <=FYSE ooo IEIElrETtrlr$; IIIt3l .tEtt.irEo6:E E taEat t IEI EI tt!l I l lr5E t $r!rItI3l0E 3 3 I!I,3E-tIrEEaI 1o 1o 3I O) rr ) 9s9ooN * aaI tIt2IPItrl ItCBsl ,RI IEII ii { II , I hitT$iIt3l rtsIE. !rI0EBlEr i EtET 1II :Ec !EI II Isbc 3Ea t -t*l g $t *i!rIttia5l rEtEiEsi l*I B E?tt 7a 35 \6r* ESf r ci. E z?5> t .o r . 6 E 96 EL t r go s* $ -\!6: U ,io o ir i E ?c .E .E p R t I5 r : fE i = : s- i r- E T E t4 i EE E 43 t o) lr ) 9b(\ s! $ ;s i Ii i o oge ; s ! " lE J OE 3 <V oe5E C\ , J \t !9 sf t o!zuo> \ E. d , E E 96 E[ t r cI o=I!!ao E9! :aI6!= cll.il: Hddm {Us) lnc. Faclllty: Oovib Slide Comont PleolPol.dr: M242010 T..l Lcrdon: Mrln Kih O.Li 7t1a12024 Op.nior: C.Eldidga Op.dlng Condltlon Mill On smPL 3y.l.m: PrcD. L.i!th: P.ob. Typ.: SahPh PLn.: PoTt L.ncth: Pon 3E (dl.tulrr): Pod Typ.: Ousl 3h.p.: Locatlon olT..t Potu: ,{uhb.r ot Potu E.mpLd: l{umb.r ol Pdtu p.. Pon: Total l{umbar ol Thv.E. Polnb: FTIR 6.0 FTIR Horirontal 6I Nrppl€ Rocl.ngular Sids ot dud 1 1 1 Callbratlon Gasee ld6rl Up8t8am DGlm6 ldcel Domdrcrm Diaiere ln. ln. 0.0 F*l 0.0 Fmt TF &ldnt Cylnd.r D Cyllnd.. Vrlo. \nalfar R..por Dfraonca,Er9ldon o2 'L ldwl Type s.ldne cylnd.. lt)Cyllnd.. V.ll.PEdlcLd V.M anrlrrar CvIh&l uPrmnDd.Cr THC ppmw TyP.Compnd Cylhd.r D Cylhd.r V.10.Erplndon Dft Zarc Gar l{llrcg.n ar M457435 0.0000 5t29t2032 failDntlon rnnataa EthyLn.cc 1899E3 ! 00.3 sl23t2031 mme lpu.cci20039 u11t2032 MGbrdi ftan Project No. M2429104 Rotary Kiln Exhaust (K-1) v6.0 '122 ol 159 mTA ffrR 228123 @Mostardi Platt Cll.nl; Holcim (US) lnc.Frcllity: Oevils Slid6 Cem€nt planl Projrct * M2429tO Fual Typ.: Cat. Sub€rtumhousFucl Ftctor: 9820 T.rt Loc.{on: Main XilnO.L:7t18t24Optntor: C.Etdddoe02 '/o Cornction: 7 - Dll[nt: 02 % ofeBge Pre and posi SDan Mostardr plstt Project No. M242}1OA Rotary Kitn Exhaust (K_1) L = Averag€ value of t6tCaas = Cor(ted gas vafue of t6t MTA FTIR 228123 @Mostardi platt C.llbotion Comcild tnd CIIGULtrd Dat v6.0 123 of 159 Client: Holcim (US) lnc. Facility: Devils Slide Cement Plant Test Location: Main Kiln Date:7118124 Project #z M242910 Linearity Cal/Pre 1 Cal Time 6:58 6:59 7:00 7:01 7:02 7:03 7:49 7:50 7:51 7:52 7:53 7:54 7:55 7:56 7:57 7:58 7:59 8:00 8:01 O2o/o (dwl 22.04 13.28 0.00 3.66 12.11 12.00 20.21 17.05 0.81 0.07 3.99 12.63 20_15 20.20 17.87 19.58 20.22 17.72 12.00 THC pomvw 0.00 0.00 0.00 0.00 0.00 0.00 89.13 74.34 6.30 0.00 23.69 33.79 28.2',1 28.98 28.41 45.00 49.74 46.27 6.40 ih tz tm MostardiPlatt Project No. M2429104 Rotary Kiln Exhaust (K-1) v6.0 124 of 159 RATA FTIR2I28I23 @Mostardi Platt (f)ao-Q6 NO - 0( E i- 6f, E<= F9 r t fl = u: = s E : t $ * + E= u: = u B $ rooo.tooo. 9, * { E q q q il | " -: : s R R E9s s S E S N 3I I 5 E sl q ; =: s R R R R R R t\ a !otil i l El s x e E e E E i 4 E E EI s x P E e E q H A E E ,r l o * <r i o rr j 3 5 E $ S S ,1 o * o. i o ri g 5 5 $ S $ II II FI FI c{ N E r t N E EESE *A - tl < o , a (O lO (\ l N @ O O r N - tl r o , ^ (O lf ) N N @ O O r N i, -1 6 x t o r ls @ o, o, o) o) a, =6 x \t o F l. - @ o) c') o) o) t: o l q J: = s R R R R R R I fl e ; i i s R R R R R R 8l ol (aoGNooo. o, lr , oF(o o )r o N<Y or c sd - =, I (E ci c i zY .- 6 > p. s r E 6 Yo 'a tE o 6, l N (f ) S tr ) (O F- @ O) O r N 6, l $ lO (O t- @ O , O il l r ) l. r ) lr ) l r ) lr ) lr ) tr ) lr ) O O O al O O O O O O r ,: l o i oi ai oi e. i e. i e . i e . i <" i c" i c. j '= l t i ' j rh i rb i? lb ri . j 6 Fr r r r r r r F r F F F Ft r r 6, l N (O $ lO (o F* @ O) O r N ot N (f ) t lf ) (O N @ q, O r N al r o rr ) 1r ) 1 r ) lr ) r o r o rr ) o o o -l 1( ) ro r o lo lo ro lr , l r ) o o o r= l e. i 6i c. i c. i e . i e. i c. i <r i ci c. i c' j := l oi c. i e. i c. i 6i 6 i e. i c. i <" i ei <" i Fl r - r r r r r r F t r r r r r r r r F F F Eo(LCo .E9b :oOe J= o c cY l b , V I o' ; $ . L @ fE S E S t tl # H. u o= i i . Y o 5 E 5E " o- J JooF (f)sco - s6 N( L sE i- ( EIE<= F( J ) t- il i l E= u: = I * g E= : x = * u u v, Cf l - ' -' - -' s $ EI II FI FI o, lr ) OF(o o )< o C\t $= u :: l H H 9* * q q e E E il | " " : = s R R o)Eo-oooo. oo- (oooo. ol $ lO (O l- @ O, O ol N (f ) t lO @ N cO El e e Q 9 9 9: Ft 9 ! $ t S! S! 9! 9! S! ,= l rb rb r b tb rb ri ' i 6 ': l F- F- r- r - r. - r . . r. - Ft r r r - r r r Ft r F F r r r r ol s f lO (O t- @ O, O ol N cD t lO (O N @ EI O O O O O O T aI N N N N N N N '= l t i rb &i i" i i' i rb rb '= l F - # r. - F- F- F- F. Ft r r r - r r r F l r r r r r r r il i l H= s: = r ; e E= * * = s e $ -l -l FI FI @N E @ N E EE -s f l SE ;9 s s s h I3 P ;9 9 * 3 $ I3 R t sl q I j: S R R t: s l Q . l j j S R R NI NI ol ol Lo(Lco .99b=o 6' q J: O c -A e = - E o9 ? Y N o' ; t . = @ fE S S S I ; # E id L- ^ -o= x . Y o 5 E AE " o- J #ooF =35 a) o sd - =' i (E ci c A ZY .- a) >\ p. q . E a e6 6 Lt o (Y )N6-qE N( L tr E i- 6EE f, 6 t fl = = r e $ $ o) rr , oF(o o )x N 3N E H g= s2 h E D E -tI v, sl d o. i : = R R NIotfl = * * = * E $ Ol s t lO (O l- @ O) tr I I: : : I : ,! l o o o @ @ 6 Fl r r r F r r a <Yar g $Esi - au J o ci S A ZY .- 6 > p. g L E E 95 -a tE o= =N E E*E I9 s n E Q e q I ^6 : * l g ". i = = S R R EN I ol (I, (Lo .Ee6 :o6' s 2 J. = O C -( / ) - -- - E -9 ? Y i t .-- \ ! - \o' = $ .s co fE s s s rx # E i i Lg ^ -o= i i . Y l ! 6 E $E " rJ #ooF ol N (A t tr ) (O l- cO al N N N $r $ r (\ N ,: l N N N t - t - t - t - Flr e F F F F F MOSTARD! PLATT Procedures for Method 4 and FIow Calibration Dry Gas Meters The test meters are calibrated according to Method 5, Section 10.3 and 16.1. and "Procedures for Calibrating and Using Dry Gas Volume Meters as Calibration Standards" by P.R. Westlin and R.T. Shigehara, March 10, 1978. Analytica! Balance The accuracy of the analytical balance is checked with Class S, Stainless Steel Type 303 weights manufactured by F. Hopken and Son, Jersey City, New Jersey. Temperature Sensing Devices The potentiometer and thermocouples are calibrated utilizing a NIST traceable millivolt source. Pitot Tubes The pitot tubes utilized during this test program are manufactured according to the specification described and illustrated in the Code of Federal Regulations, Title 40, Part 60, Appendix A, Methods 1 and 2. The pitot tubes comply with the alignment specifications in Method 2, Section 10.1 ; and the pitot tube assemblies are in compliance with specifications in the same section. CN&F-0028 Cal Procedures M4 & flow Rev.2.2 'U1t2021 Project No. M2429104 Rotary Kiln Exhaust (K-1) 128 of 159 @Mostardi Platt Dry Gas lUeter/controt Modute caribration Diagram ATD-090 Dry Gas Metor Catibration Projoc{ No. M24211OA Rotary Klln Exhaust (K-1) Rev. 1.2 1t112021 129 of 159 @Itloetrardi platt Eo i !+(L 3 .- NE6(E Aoi>!@E O) lr , ib; od35 \ail E>* , i ds zE65 .s l 5P5 (L I r *: O)\ r\oo (o@o)c; @@o)o @oq(r ) rO o) (ooC\ l ) oooriloqt)o @66c. i lo o \ov NNNdN €Oa|o(o o oo.io t-rOtJ )d(? J t q {ts tt\ o lf )N )2l )?q oIo(t oqo ?)o oco(f) oN oq 6EE=t Gtlr EoF o=NE:d EoF zod6Jotr II J II J- go6Eosoa)- a-- l-NoNIIr-rf )dEE tl o; -Q + (L s .- $ t6(E l t o>o:>i oE o) tO o Fbbt ;p<Y ov\6NJ<xsf r os zEE5 .o 8ts e5 (L I r : lol.( )orooqGI (oqO) ) \ot N|r )Foi o\f! (oqrtN o \o u?o 0f) o@(o o6c; Gcc=t oElr oEoF zotroJotIJ JLrJ. a;NNIIt- - ilEt Stack Temperature Sensor Calibration leference Source Temperature (o F Test Thermometer Temperature (o F)Te m peratu re D iffere n c e lo0-2 0.4 0.4 0/ nr 250 247 600 596 I 200 1 198 Project No. M242910A Rotary Kitn Exhaust (K-1)132 of 159 @Mostardi platt (Dro * o:3F /glP l ts l /r / ls l .E lEIEIgt IPt;:goEc.s lSI€l3lEl oEo6ot 3 <Y ov*esf A IIJ zv ii L .o & od x o. E P: zotr@J<lol tlur l FI u. r I -l a-- tInl rNIc.lNIt. . r{E= N th iEN .- oEt J 6r i i, Nos 6E f o)u) s Fto;TF (\ rOciO)qoF-d 3 o @ 3 o-,)D (oo)d N N\ u?l'- f3 ooo(Y ) ooC; (r ) or. )o EcF)EIE ocl! qto roIl. -oqlOat(o o NrJ )@+(n NrO@+(n o ro@qNs rO@qNt O) t\ oo u, )o, t\ ooc, ooo(v ) ooo(v ) oo .!trNtrG, Glr gEo Nqoeo\I\ro 3 \to(odta , $o(')dro 3 (f ,aoN (oaot\ D O) t\ lr ,@t\ f?) ooC, (f , ooo(r ) ooN 6cfE oc qsEoF o=oov, EeEEE} 5* ' Ea E6 oNGo oEr ! ot (, - OE J! c , E -! - 6E !E eo;o Ga!oC.9(E.oGo .Po=eg E eo;o oo.oGo si EEe6 ooE o9 .E E rn o E tl - 0, .EFcd Eoooslr J @ .EE G'(,-]ou- Eoo,oo .cEoc)= oEoEcooEol!_-oGo $NIf-NNoa!ocoIea!o = <Y ii ( ,$Esf r ci S z*6$o. hos o- r&: thxIe{IN6tIt-(f) tr .9oEocoo- ),Lf,5,)hf.lJE6UoEoooTJEU zo=ouJt6Eo.oN=t!oF oozLIJ-oEo-so,9ooEoF dI(') ooq No o.az -2 , ovoo -6DO6ll (9 o >6ai i o.!6oF IEcltooolrst!(,at ,oN=oo O(oc{Iox rONYa o!,6-o6oEoo otto-(,(,.oa!o zouoJouut Lr J= Stack Temperature Sensor Calibration Temoerature lD :cM22 Name:REF Ambient Temperature, o F :69 Date:Mav 3,2024 Temperature Calibrator Model#:CL23A Certification Date:October 19 2023 Serial# :T-314718 Exoiration Date:October 18,2024 Directly Traceable National lnstitute of Standards and Technology Reference Source Temperature (" F) Test Thermometer Temoerature (" F)Tem peratu re D iffere n ce lo 0 -1 0.2 250 249 0.1 600 599 0.1 1200 1203 0.2 Primary Project No. M242910A Rotary Kiln Exhaust (K-1) (Ref. Temp.. "F + 460) - (Test Therm. Temp.. "F + 460) * 100 <: 1.5 % Ref. Temp., "F + 460 135 of 159 @Mostardi Platl Sfack Temoerature Sensor Calibration Temperature lD :cM22 Name:REF Ambient Temperature. o F :69 Date:Julv 25, 2024 Temoerature Cal ibrator Model# :CL23A CerTification Date:October 19,2023 Serial#:T-314718 Exoiration Date:October 18,2024 Primary Sfandards Directly Traceable National lnstitute of Standards and Technology (NIST) Reference Source Temoerature (" F) Test Thermometer Temoerature (o Fl Temoerature D ifference lo 0 -1 0.2 250 250 0.0 600 600 0.0 1200 1203 0.2 (Ref. Temp.. 'F + 460) - (Test Therm. Temp.. 'F + 460) * 100 <= 1.5 % Ref. Temp.,'F + 460 Project No. M242910A Rotary Kiln Exhaust (K-1) 136 of 159 @Mostardi Platt 8 TYPE PNOT TUBE NEPECTIOT{ UYORKEHEET Pltot Tr.lbc tlo: 'l Typ. of Prob.: (drdo onr) oahj 6tun021 ftobrl.ne[h: 4 ft. x0[:n.6 q<Fr <r.s 0I '.'", [r-J 'ru,, tst3 : E-xl lnapccbGNam.: DV Itr sst$f'l+ is-. a ,,) t.s ,1 r-30t PuNr.-7' ,cffirs."xr ,L- ;,,Jo.o cr <or <o.t! cr '-slol u{t (!/r6 rff.) I!,/l rN.) tiliswE. luaa 116I rotl{- 'r "" -' {, -i-tiJ1<u i"'' lE -C). )i, )r' z i'i . rmswrsr .r - -- :Mr 1-rlr lir Pltor tubc uoc|bly hvcl? _I_ytl _no Pliol hlbc op.nhg. d.m!gcd? _y.. (axd.h b.low) lrr oS o(r10o) 1.= I o(s10) br = r.5 "(i5') b2= 4 o(sso) y= 1.5' o= 0.6' A= 0.9:]o (hJ C.llbflsonr,qulrcd? _n -Lno A8.O! 8 Ttf. Plbt Tl.6. h.pacdoo Fm Pro,ect No. M2429104 Rdary Kih Extauet (K-1) 4no z-A.try= C.oa! (h.);(O.126h.) w - A.ln 0. o,0oatt (h.); (10.03125 tn.) P^ E oITo (h.), Pr = 0.a70 (h.), q = o.3ZS (h.) @Moetardi Phtt Pitot Tubc No: Typc of Prcbo: (clrds me) 1 S TYPE PITOT TUBE IilSPECTIOT{ WORXsHEET O!tr: 7n6fa02t Probo Lcngfi; 4 ft Iil I l_srDa PUiI-"1 ,o*orro,*..i o, ^rult rrE I B o.! cr (0. <0.9s c! 8_sDa'PuNt(r/re rr ) ill! rfl ) lnspcctors N!mc: DV TffiIHI,, i s 4rf;=_- 3 NOT': Pitot tub. lssembly lcvol? Pitd tubc opsnings dameg6d? _ ra^xsvt6(ruBa rr,sIA9P9 - @o'5, rle I X yos _no _y68 (sxplein bolqn) r o (s1oo) 2 " (Js') " A= o.e3e(h.) l'l t^ I 01 tr i^ o ,'^l =_,1 i !r= 0.5 o(3100) br = .t.S "(ls") b:= y= 1.5 " s= 1 Calibratlon r6quircd?_ycs X no Xno z=Aslny=0.025 (h.); (s0.125 h.) w=Alin0= o.olcre (in.);(ro.o3r2stn.) P^ = 0.470 (in.), P8 = 0.470 (h.), Dr = 0.375 (in.) Rw. t.0 138 of 159 PIS{I S typ. pttd Tr$. t p..doi Fm Project No. M24291OA Rotary Kitn Exhaust (K_1)2t17t2020 @Mostardi Platt Appendix H - Calibration Gas Cylinder Data Project No. M242910A Rotary Kiln Exhaust (K-1) 139 of '159 @Mostardi Platt Airgas. an Air Liquide company Airgac Specidty Gases Airgas USA LLC 525 North Industrial laop Road Tooele, W 84o74 Airgas.com Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: 153403021553-1 152.0 CF 2015 PS|G 590 Apr 23,2024 Expiration Date: Aor 23,2032 CERTIFICATE OF AIVALYSIS Grade of Product: EPA PROTOCOL STAMARD E03Nt78E15A1066 ALM052228 124 - Tooele (SAP) - UT 872024 CO2,02,BALN CertlficaUon porform€d ln accordance with "EPA Traceabllity Protocol for Assay and Certmcation of Gaseous Callbration Standards (May 2012)' document EPA 600/R-12y531 , using the assay procedures listed. Analytical Methodology do€s not roquire conection for analytical interforenco. This cylind€r has a total anaMical uncertainty as stated below with a confidence levsl of 95%. There are no significanl lmpudtles which afiocl th6 use of this callbration mixture. All concentrations are on a mole/molo basis unless otherwise noted. The results relate only to th€ items tested. The r€port shall not b€ reproduced except in full without approval of the laboratory. Do Not use This below 100 i.e. 0 ANALYTICAL RESI,'LTS Component Requested Concentratlon Actual Concentratlon Protocol Method Total Relatlve Uncertalnty Assay Dates CARBON DIOXIDE OXYGEN NITROGEN 10.00 % 't2.o0 yo Balanca 9.717 Yo 12.05 0/o G1 G1 +l- 0.8o/o NIST Traceable +l- 0.60/o NIST Traceable 04t23t2024 0412312024 CALIBRATION STANDARDS Type Lot lD Cyllnder No Concentratlon Uncertalntyr Explratlon Date NTRM NTRM 1306041 1 1 1060604 cc413537 cc338173 7,489 YO CARBON DIOXIDE/NITROGEN 1 4.93 O/O OXYGEN/NITROGEN 0.6% 0.2% May'14,2025 Nov 02. 2028 InstrumenUMake/Model ANALYTICAL EQI.IIPMENT Analytical Principle Last Multlpoint Galibration Horiba VIA-510 SV4MEUTJ CO2 Horiba MPA-S10 W603MM58 02 CO2 NDIR (Dixon) 02 Paramagnetic (DIXON) Apr 03,2024 Apr 03,2024 Trlad Data Avallable Upon Request Slonature on flle Project No. MlPPlqred for Release Rotary Kiln Exhaust (K-1) 140 of '159 @Mostardi PFlge I of 1 Airgas. an Air Liquide company Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: lUrtas Specialty Gases Airgas USA LLC 525 North Industrial L,oop RTooele, UI Saoza Airgas.com Reference Number: Cylinder Volume: Cylinder Pressure: Valve Ouflet: Certification Date: 1 53*403021 556_1 159.0 CF 2015 PStc 590 Apr 22,2024 CERTIFICATE OF AIVALYSIS Grade of products EpA pRorocol STAI\IDARD E03Nt59E15A3452 cc199733 124 -Tooete (SAp) - UT872024 CO2,02,BALN ation Date: l=---. -=..-; "=-.-,"i1'i:il'J::l;,HH,lf ff*ilr6x;lf;*""ffi,"[$y#$,,q[iffifl:m#airu"m,tr*nmg.,,l*1,;**i::l:l:,#fl"" lft,i.#:l:tl*r;xy,:*excoptinfullwithoutapprovaio?iiiJnuoratory.oo CARBON DIOXIDE OXYGEN NITROGEN 19.00 o/o 22.00 % Balance +l- 1.0% NIST Traceable- +l- 0.4o/o NIST Traceable 24.U % CARBON OrOrroelr,r rrno6 22,53 IO OXY GE N/N ITROGEN Horiba V|A-Si0 SVAUzur.l COi Horiba MPA-S10 W6O3MM58 02 Trlad Data Avallable Upon Request Projecr No. rulnpWed for ReteaseRotary Kitn Exhaust (K-1)141 of '159 @lVlostardi Phlgo 1 of I Ailgas Grade of Product: E02A|99E15A0705 cc212108 124 - Chicago (SAP) - lL 812020 PPN,BALA Expiration EPA Protocol Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: Date: Jan24,2028 il401709074-1 146.2CF 2015 PS|G 590 Jan24,2020 CERTIFICATE OF AI{ALYSIS Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: Certification performed in accordancr with 'EPA Traceability Protocol for Assay and Certifcation of Gaseous Calibration Standards (May 2012l'document EPA 600/R-1 2/531 , using the assay procedures listed. Analytical Methodology does nol require conection for analytical intorference. This cylinder has a total analytical uncertainty as stated below with a confidanc€ level of 95%. There are no significant impurities which affect tho use of this calibration mixture. All concantrations are on a mob/molo besis unless otherwise noted. PROPANE 3O.OO PPM 29.71PPM AIR Balanco G'l +l- O.60/o NIST Traceable 0112412020 CALIBRATION STANDARDS Lot !D Cyllnder No Goncentration Uncertalnty Explration Date NTRM 17061015 ND61584 49.13 PPM PROPANE/AIR +l-0.4o/o Ju|24,2023 ANALYTICAL EQI.IIPMENT lnstrumenUMake/Model Analytical Prlnciple Last Multipoint Galibration Nicolet 6700 AHR0801 332 FTIR Jan 0'1, 2020 Trlad Data Avallable Upon Request Slonatrrra an flla Project NoAmagiod for Release Rotary Kiln Exhaust (K-1) '142 ot '159 Pa$10$i6{4Dt?09074-t Airgas. an Air Liquide company Airgas Specidty Gaces Airyas USA LL,C Sz5 North Industrial laop Road Tooele, UT 84o74 Airgas.com Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: 1 53-402491 690-1 146.0 CF 2015 PSIG 590 Jul 19,2022 Expiration Date: Jul 19.2030 CERTIFICATE OF AI{ALYSIS Grade of Product: EPA PROTOCOL STAMARD E02A|99E15A0456 cc347477 124 -Tooele (SAP) - UT 872022 PPN,BALA Certlfication performed ln accordance wlth "EPA Traceablllty Protocolfor Assay and Certification of Gaseous Callbration Standards (May 2012)'documenl EPA 600/R-12/531, using the assay procedures listed. Analytical Methodobgy do€s not requir€ conection for analytical interference. This cy'inder has a total analytical uncertainty as stated below with a conlidence level of 95%. Thoro aro no Bignificant impurities whlch affect the use oI this calibration mixturo. All concanlrallons ar€ on a mole/molo besis unless othorwise noted. Th6 results relate only to the items tested. Tho roport 6hall not b€ reprcduced excspt in full without approval of th€ laboratory. Do Not U3€ This below 100 p8iq, i.e.0. ANALYTICAL RESI,'LTS Component Requested Concentratlon Actual Concentratlon Protocol Method Total Relatlve Uncertalnty Assay Dates PROPANE 5O.OO PPM 49.98 PPM Gl +l- 0.5o/o NIST Traceable 0711912022 AIR Balance CALIBRATION STANDARDSType Lot lD Cyllnder No Goncentratlon Uncertaln$r Explratlon Date NTRM 1706,1003 ND61228 49.13 PPM PROPANE/AIR 0.4%Jul 21,2023 lnstrumenUMake/Mode! ANALYTICAL EQIIIPMENT Analytlca! Princlple Last Multipolnt Callbration Nicolet iS50 AUP2110269 C3H8 LC3HB FTIR Jul 07,2022 Triad Data Avallable Upon Request Slonatura on flla Project No. trllpplured for Release Rotary Kiln Exhaust (K-1) 143 of 159 @Mostardi PFtge 1 of I ,1il lrrlrr, an Ak Uquido company l(xrElsr u r o{v/'t Airggs.com E02A199E15A0565 EBo1 17588 124 - Tooele (SAP) - UT 87201 I PPN,BALA Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: 153401590950-1 146.2 CF 2015 PSIG s90 Sep 10, 2019 CERTIFICATE OF AIVALYSrc Grade of Product: EPA Protocol Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: Certificalionperformedin".ffi,.,."aii]EFnJ,".."b@ertficationofGaseouscalil 600/R-12/531, usins the assav procedurest'"* g',';9n'ga,'!!*-"111i"tnT",lfrX11f'Tffin"[:?;:';::?llSm5;l*?#lyfi 5*l ,*Tinil'i3:i;,:?t1lffiffiil:ffi'ffi':"Jilri;ii TffiiiE:tli,*;."ir:TilXp3JJ:i'X*,'g;ffS . ^ ,,-^ --'- A.rr^4. trar^{ IOO ocin. l.e. O.7 mg0iDo Not Use Actual- Goncentration e0.30 PPM 2027 A}.IALYTICAL RESI.}LTS Protocal Method Tctal RelaUve. Uncertai *t- O.So/o NIST Traceable Last MultiPoint Calibradot 28,2019 -Component PROPANE AIR e0.00 PPM Balance . Reqrrested Concentration RATION STAI{DARDS Type NTRM lnstrumenUMake/Model ffir"t-ezoo-icor"t ezoo nuPogoo119 c3HB Lc3HB Triad Data Avallable UPon Request Project No. M242910A Lot lD Cyllnder No Concentration 1 7061 01 1 ND61547 aq13 ppv PRoPA|'IE4!E A}-IIALYTI CAL EQUIPMENT Princlple Rotary Kiln Exhaus!6-1) t -/-., / 144 of 159 @Mostardi Platt Airgas. an Air Uquide company Part Number: Cylinder Number: Laboratory: Analysis Date: Lot Number: x02Nt99C1541268 cc189983 124 - Tooele (SAP) - UT May 23,2023 153402750890-1 Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Airgac Speclalty Gases Airgas USA LIf 525 North Industrial Loop Road Tooele, W 84074 Airgas.mm 153-402750890-1 144.0 CF 2015 PSIG 350 CERTIFICATE OF AIVALYSIS Grade of Product: CERTIFIED STAI{DARD-SPEC Expiration Date: May 23,2031 Product composition verified by direct comparison to calibration standards traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. Component Req Gonc AIVALYTICAL RESULTS Actual Concentration (Mole %) Analytlcal Uncertainty ETHYLENE NITROGEN 100.0 PPM Balance 100.3 PPM +l- 2o/" Slanrftrra an flla Project No. urlprured for Release Rotary Kiln Exhaust (K-1) 145 of 159 @fi,tostardi Phlge I of I Airgas. an Air Liquide company Alrgas Specialty Gacee Airgas USA LLC 98To BAYAREA BLVD Pasadena, TXnSoT Airgas.com CERTIFICATE OF AIYALYSIS Grade of Product: CERTIFIED IIYDROCARBON PartNumber: XMN|99C15A00B5 CylinderNumber: CC120039 Laboratory:124 - Pasadena (SG06) - TX Analysis Date: May 22,2023 Lot Number: 163402710937-1 Exoiration Date: Mav 22,2024 Reference Number: 163402710937-1 Cylinder Volume: 144.0 CF Cylinder Pressure: 2015 PSIG Valve Outlet: 350SS Traceability Statement: Hydrocarbon Process standards are NIST traceable either directly by weight or by comparison to Airgas laboratory standards that are directly NIST traceable by weight. CERTIFIED CONCENTRATIONS Requested Reported Component Concentration Mole % Accuracy ACETALDEHYDE METHANOL NITROGEN 200.0 PPM 200.0 PPM Balance 200.6 PPM 204.9 PPM Balance +l- 2oh +l- 2o/o Permanent Notes:-NA- Slonature on flle Projec{ No. ulpplqred for Release Rotary Kiln Exhaust (K-1) 146 of 159 @fi,lostardi Phlge 1 of I Appendix I - Mercury Laboratory Analysis Project No. M242}1OA Rotary Kiln Exhaust (K_1) ProJect #: Cllent: Facllity: Analyzer lD: M242910 Holclm (US) lnc. Devll's Slide Cement Plant Ohio Lumex METHOD 3OB CALiBMTION SUMMARY Locatlon: Condltion: Data Taken By: Maln Klln Mlll On R.Flscher Callbratlon lD:CAL{1 Standard Mass (ns) Ohio Lumex Response (Area) Calculated Mass (ng) Percent Error (%) 250 23000 246.19 1.52o/o 100 10000 107.04 7.O4yo 50 5030 53.84 7.68% 25 2250 24.O8 3.68% t0 950 10.17 1.7OYo Slope:0.010704 0.01050 RSquared:0.998330 Enter Lowest Callbratlon Polnt Standard Mass (ns) Ohio Lumex Response (Area) Calculated Mass (ng) Percent Error (%) 10 950 9.98 O.20Yo !ndependent Callbratlon Verlflcatlon Standard Mass (ns) Ohio Lumex Response (Area) Calculated Mass (ng) Percent Error (%) 50 5040 53.95 7.90o/o Contlnulnq Callbratlon Verlfl catlon Standard Mass (ns) Ohio Lumex Response (Area) Calculated Mass (ng) Percent Error (o/.1 50 5080 54.38 8.760/o 50 5120 54.8 9.60% 50 51 35 54.97 9.94% 50 5098 54.57 9.14o/o 50 5089 54.47 8.940/o FT-008 Hg Template Project No. M242910A Rotary Kiln Exhaust (K-1) v5.4.3 148 of 159 4t612022 @Mostardi Platt !o:5 8 lU ' . - + == t r o .. t r '. c o E ^J O E. G .E = F 3E E 6g . E JC ) c t :)oII JtrFoII J@e(v loo-UJ. "? E1b {o r -< , cgo.co .EooEo aO X (r , tr o o3 t ; E 5s - r i $E E . e N o A r E -r o o a <Y in L d) N * E NT q> [ i E "s I zY or 6 > r .9 2 . 6 o 9 6 o o- E oFLL o r* ! .. h E- D I oE = - 'g g ' H E O. ( ) r ! < NNoN- (o 6 \t ( L E(uooo othsgUl - - q<tn (f, c. l (oco (\l a?N(Y ) \N c?Io N I<fy) (\ lo a?@(\ t \N qo(f ) No o)t(Y ) qo :\ i f):a aN a?ro(r ) 1O xoo5 Ha .e rs 6t r rJ )NN(v ) N ot\t-t* oo ONo(f) oN oo(\ I (r ) O)O) ooN(7 ) o os(oN o)tN o|o€N oT o(oN({ ) orJ )NI ooN(, oNN :r : Ns go(,oo -9oEooI -c .qf,o-c.YGoGTIN -9oE(!C)I o=oE.YGoc)IN ooE(!oI coaoE.v ,GEd!N -gcE(l (t ) Eo=e-c.YoodtN ooE(UoI co=eE.Y(Eol0 IN -9oEGoI ooE.v ,Go(DIcr l -goEGaI E.o=oE.v ,o(,GIIN -goEGaI o)o-c.v ,oo) tr ] IN -goEooI .c .o=oE.v ,Go(DIN -goE(!oI E.o=oLE.v ,Go)d)IN eCLt! O)@(\ l@Nl'-Jo (oN@l' -oJo @O)N(oNl' -Jo F-otO)oJo N(oO)oJo (oo)o)oo,oJo NoO)oJo ocoO)oJo $o) (oo,oJo t+oooJo etrtr o@ N ElF- d)co O) @o, o dto oEoTEo oIJo oIJo oIJo oIJo oIJo oJo oIJo oJo oJo oIJo ooSE ol - I (os q qN$ \F-(, G aO)(, c!o n(r ) c!o c?o(v ) N c! l'-I O) a@o, 1\3 a(,\i c!o occ x6r o E Pa -, l o o o o < 5e - o(7 's ro$ oot r-o oNlf ) (f , (' ) ro o@rO(, ,!I o(t ,o)N oI €N s o$\t o)t- ooo) (o(o tnos o) lr , oN(,@ oo tro(,oo -9oEoa c.oaI.c .x,(Itoc)IN -9oEoaI cofIE.Yooc0IN IIoEGn E,ofoE.Yooc0(\ t -9oEoa Eo=I.C.v ,oodIN oEE(!a .c .ooc. .Y(Uoo oEEoaI EoIv,ood)N IoEG'n -cofIE.Yoo)d)I (\I -9oEoa oEEoa .c .o=oEv,Go) tr t o,oEoa ofoE.v .oEtr )N erL.E rf$@(\ I t-Jo O)N(v ,@Nt-Jo o(\s@Nt-Jo F-$(f,@Nr\)o r-N(f ,@Nl' -Jo o$@Nt-Jo O)3Nt-Jo (o@N@t-oJo @d) (0e{rrJo 6$t\(ooJo etrtr d) N d)N d)(, dIsl rO corr , ot)o.Eo oIJo oJo oJo oJo o)o oIJ() o-)o oJo o)o oJo Ohio Lumex Calibration and Results Summary Holcim (US) lnc. - Devil's Slide Cement Plant Main Kiln July 1.8,2024 Description std_250_HP std_100_HP std_so_HP std_25_HP std_10_HP ICV_50_Ricca R1a_O1726414_Sec1 R1a_O1725414_Sec2 R1b_O1726329_Sec1 R1b_O1726329_Sec2 R2a_OL72642O_Sec1 R2a_OL72642O_Sec2 R2b_O1726347_Sec1 R2b_O17253 47 _Sec2 CCV_S0_Post2 R3a_O1726327_Sec1 R3a_O1726327 _Sec2 R3b_O1726410_Sec1 R3b_O1726410_Sec2 R4a_OL726419_SecL R4a_OL726419_Sec2 R4b_O1C178266_Sec1 R4b_O1C178265_Sec2 CCV_50_Post4 R5a_O1726361_Sec1 R5a_O1726361_Sec2 R5b_O1C167418_Sec1 R5b_O1C167418_Sec2 R5a_O1726289_SecL R6a_O1726289_Sec2 R6b_O1C17823 1_Sec1 R6b_O1C17823 1_Sec2 CCV_50_Post6 R7a_OL726298_5ec1 R7a_OL726298_5ec2 R7b_O1C191407_Sec1 R7b_O1C191407_Sec2 R8a_O1C19152 1_Sec1 Maximum Time 2t70 1150 433 22s 63 480 367 74 189 74 150 11 165 10 269 101 9 105 12 129 13 559 9 378 156 16 501 L7 113 12 468 10 387 L54 13 316 10 146 10:04:02 AM 10:06:42 AM 10:09:15 AM 10:11:46 AM 10:14:59 AM 10:22:25 AM 12:43:28 PM 72:45:57 PM 12:49:06 PM 12:51:25 PM 1:14:14 PM l:77:32PM 1:23:36 PM 1:26:20 PM 1:35:16 PM 1:49:00 PM 1:51:51 PM 1:55:59 PM 1:59:34 PM 2:45:28 PM 2:47:58 PM 2:53:48 PM 2:55:53 PM 3:03:51 PM 3:24:55 PM 3:28:41 PM 3:31:46 PM 3:35:00 PM 4:03:29 PM 4:07:21PM 4:12:36 PM 4:15:41 PM 4:22:47 PM 4:58:25 PM 5:01:37 PM 5:05:54 PM 5:08:43 PM 5:40:36 PM Area 23000 10000 5030 2250 950 s040 4310 745 4000 707 3520 53 3680 -89 5080 2930 -110 2830 114 44tO 779 9010 -66 s120 4050 -59 8370 100 3225 72L 7770 109 5135 3020 250 3200 199 3200 1 50 of '159 @Mostardi Platt Ohio Lumex Calibration and Results Summary Holcim (US) lnc. - Devil,s Slide Cement plant Main Kiln tuly t8,2024 Description R8a_OLC191G2 1_Sec2 R8b_O1C190993_Sec1 R8b_O1C190993_Sec2 CCV_50_post8 R9a_O1C191012_Sec1 R9a_OlC191012_Sec2 R9b_O1C191180_Sec1 R9b_OLC191 180_Sec2 R1Oa_OlC191394_Sec1 R10a_O1C191394_Sec2- RlOb_OlC191041_Sec1 R1Ob_OlC191041_Sec2 CCV_50_post10 Project No. M242}1OA Rotary Kiln Exhaust (K_,1) Area -5 2640 249 5098 2850 -46 3260 -250 3290 225 3300 742 s089 Maximum 10 746 L1, 377 747 9 776 77 220 10 770 9 275 Time 5:43:18 pM 5:47:00 pM 5:50:18 PM 5:54:14 pM 6:21:33 pM 6:23:57 pM 6:29:38 pM 6:33:03 PM 7:13:04 pM 7:16:08 PM 7:78:52pM 7:27:33 pM 7:24:24 Plt4t 151 of 159 @Mostardi plaft Project No. M242910A Rotary Kiln Exhaust (K-1) Appendix J - Mercury QA/QC Data 152 of 159 @Mostardi Platt NNoNIaf ot oooo qlo(, )soo)oobooootro!CLo O) a? Pnt9s GEEe=t tr (, ) g ;q O. b; i Ps e8 = E€ E o* @6- 'E' t Ec l o5o= a<* o o- aE o ) q o- U E E SE F ci S or z ? IE > oo 9E 8 EE IFtr soooot Fq\t(, ) lo\(eO) o(f)(o(, ) 9e=g9; o, G o. =Et !Bu , F-o)<" i C. { looq(eN F-t-c" iN (oo)q(f)(\ c!ooqNN or-cr )N E, 0r t r 3_rEoi ! 9t s ir t r 0r o a9xE rr 6 z or' ) z olo z olo oci -o IE 'E ,G9E \o otroo o;t q@o, q(e$ \oo) @ri (f ) a$@ oEFEcIU roe(9 v+ oY?\t oEoa roI(v ) $s(f) oftt o(Eo $NoN@t- -fNoN@F* $NoNot- cfuooF ro$ dt lo (o d] (o tphRs 7221 lnvestment Drive . North Charleston, SC 29418 843.767.79O0.info@highpuritystandards.comowrrw.highpuritystandards.com @efiittcste of Aniltysii Certified Reference Material Mercury t0003J- r - r00 2333833-r00 2% t-tN03 l.0ll g/ml. * 0.002 glml.rti,2l.4oC * 0.3'C Elernent llg Cu <0.02 Dy <0.02 []r <0 02 Eu <0 02 I;e <l Ga <0.02 (id <0.02 Ge <12 ltI <0 02 tl8 M llo <0 02 ln <0.02 lr <0.8 K <l Januarl 202J Jull 31, 2025 Decembcr 20.202i lhe('ertiliedvalueisbasedongravimctricandvolumctricpreparation.andverrfic{againstNISl SRM3100scrieswhenavailablevrainductivell coupled plasma optical emission spectrornctry'(ICP{)US) and/or inductively coupled plasnra nuss spectrornetr) (ICP-MS) using an inlernal lahoratory{eveloped mcthod. I'he uncertaintl in the cenrfied value is calculated for a 95oloconfidence interval and coverage factor k is ahout 2.i ReGr to 1'raceability lnformation. Section 4 [lncertified Values: TrrctllttrllmpurigScrn:I'hcdatareJmrlcdarcbaseduF)nascanol'thrsspcilickxvial('P{)US/l('P-MSanallsis I'hevalucsarere6rrtedinpg/l Packaging end Storage Conditions: l he standard is packaged in a prc-cleaned grlycthvlcne bottlc. 'l o nuintain thc integrrty 01'this pr(iuct, thc yrlurron should bc kept tightly capped and stored under normal lahoraton' condit ions. Expiretion lnformetion: l'he expirl date is guaranteed to bc valid lbr eightccn months liom thc shipping date providcd and is guarantced through the month ol'cxpiratxrn For this reasron. standards liom the sanrc loi may hal,e diflercnl cxpiration datcs Product Description: Product Number: [.ot Number: Malrir: [)cnsitl': Certified Velue: Ag 7.6 Al <0.05 As na Au <0.2 Il <l Ba <0 02 Bc <0 02 Bi <0 02 ('a <l c'd <0 02 ('e <0.()2 Co <0 05 ('r <0 05 ('s na l-a <0.02 l.i <0.02 l.u <0 02 lllg <0 I Mn <05 Mo <0.02 Na <3 Nb <16 Nd <0t Ni <0 02 Os <l9 Pb <0 05 Pd <0 02 Pr <0 02 ue.h[. 1000 r 6 y!!!a! y_'!e!,tr!,1accetorTEo--------eflrcBI'@@ rso 17034 2016 (RMP) Afficditslion Csililicsl6 Numb€r AR-1436 n8 <0.02 <0.02 <0 02 <o.02 <0.05 <0 05 <0.02 <0.02 <0.02 <0.02 <0 02 SRM ID 3ll3 PI Rh Rc Rh Ru Sb Sc Se :ii Snt Sn Sr 'ta l'b <0.02 I e <0.02 Th <l Ti <002 il <0 4 'l'm <5.7 t' <002 v naW <5Y <0 02 Yb <0 5 7.n <0.02 7,r <0.02 <0.02 Shipped Detc: Expirrtion Date: Certificrte lssue Date: I ot Numbcr: 23J3833-100 .?ihh38ffilrvtOffror Rotary Kiln Exhaust (K-1) t-=--,2'-Z Julio Sotrl. Qualitl Managcr Rcvision: 0 PagcO,$&tardi Platl154 of 159 Preparetion lnformation: This Certified Reference Material is prepared using 99.999o/o pwe Mercury Metal which was purchased from a qualified vendor per ISO 9001 guidelines and assayed by analyical methods for conformity prior to use. This standard was manufactured under appropriate laboratory conditions using the methods developed at NIST for SRM Spectrometric Standard Solutions. Sub-boiling distilled high-purity acid has been used to place the materials in solution and stabilize the standard. The matrix is as noted above in l8 megaohm deionized water. Stability of this product is based upon rigorous short-term and long-term testing ofthe solution for the certified value. This testing includes. but is not limited to, the effect of temperature and packaging on the product. lf, during the period of validity, a recall is instituted due to substantial changes in the stability ofthis product, the purchaser will be notified. Homogeneity: This product is determined to be homogeneous following in-house procedures developed in accordance with the requirements of ISO 17034 and ISO Guide 35. lntended Use: This product is intended for use as a calibration standard. quality control standard. and/or for the validation of analyical methods. The standard is confirmed homogeneoust therefore, the minimum sample size should be consistent with the end user's measuremenl capabilities. Treceebility lnformation: The traceability of this standard is maintained through an unbroken chain of comparisons to appropriate standards with suitable procedure and measurement uncertainties. The maintenance of the base and derived units of International System of Units (Sl) with traceability of measurement results (contemporary metrology) to Sl ensures their comparability over time as follows. 1. Standard Weight and Analytical Balance The standard weights (NBS weights lnventory No 20231A) are calibrated every two years by South Carolina Metrology Laboratory that is a participant in 'NIST Weights and Measures Measurement Assurance Program' with a certificate of measurement traceability to NIST primary standards. The balances are calibrated yearly by the ISO 17025 accredited metrology service. and are verified weekly by an in-house method using standard weights.2. Volumetric Device The calibrations of volumetric vessels are verified using the ASTM method E542. 3. Thermometer The standard thermometers are calibrated every year by the lSO 17025 accredited metrology service. The thermometers used in-house are verified against the standard thermometers yearly. 4. CalibretionStendards The Calibration Standard is traceable to SRM 3100 Series Spectrometric Standard Solutions. lf an SRM is not available, a second source standard or independent lot is used' Refer to Safety Datasheet (SDS) for hazardous information. rrritlen appnrval from HiXfi-Punlv Standrds PPJiUHlts1frf4ffi6loo R6603B8eih100R-1) 155 of 159 lfff{'rto,,'"n n RrccA CHEMTCAL COMPANY' -Certificate of Analysis 1490 Lan Batesvillehttp:77*rn*.;;;;;- 1-888-co. customereervice@riccachemici Merctuy ICp Standard, 1000 ppm Hg in S% HNd, Iot Number 44OZyr45 Product Number: PHG1KN Manrrfacture Data: FEB OT, ZOi t rhe uncer,"Y,T*:T;iYlil;vatue is + 0.8% relative, whicb i, ,rr"-r"_iit.iii ffi1.ff"fl:i,",i;'1";::::f"*:i::,{i*yCfl,.-,* "*'-:* to the puritv "t,i"-',*i"i"frii, tr" uoru."li;;;";;;;", orthe sorution,an,;#":"T:,ffi:T"Xl;elements were determined by ICp o" fCFlUs.- -, - Water Nitric Acid Mercury 7732-18-6 7697-37-2 7439-97-6 Appearance Aluminum (Al) Antimony (Sb) Arsenic (As) Barium (Ba) Beryllium (Be) Bismuth (Bi) Boron (B) Cadmium (CO Calcium (Ca) Cerium (Ce) Cesium (Cs) Chromium (Cr) Cobalt (Co) Copper (Cu) Dysprosium (Dy) Erbium (Er) Europium (Eu) Gadolinium (Gd) Gallium (Ga) Germanium (Ge) Gold Gu) Hafnium (H0 Holmium (Ho) Indium (In) Iridium (Ir) < 0.0009 ppm < 0.0001ppm < 0.0002 ppm < 0.0001 ppm < 0.0fi)l ppm 0.0058 ppm < 0.00006 ppn < 0.00007 ppn < 0.004 ppm < 0.00003 ppn 0.022t ppm 0.1452 ppm < 0.00002 ppn < 0.00006 ppn < 0.0001 ppm < 0.00002 ppn < 0.00008 ppn 0.0010 ppm < 0.0006 ppm 0.0009 ppm I 0.0024 ppm < 0.0001 ppm < 0.00003 ppn < 0.00002 ppn Platinum (pt) Potassium (K) $r:3V (vs. Potassium Thiocyanate/Volhard,sIndicator) Colorleee liquid 996-1008 ppm Hs < 0.00008 ppu I Passed 1000 ppm Hg 999 lbace_ Elements by ICp or ICp _ MSAll values reported i" -glf,-(pp*) -'- Iron (Fe) N Lanthanum (Ld < 0.0oo04 ppnLead (pb) Lithium (1il :;XTJJJ Lutetium (Lu) < 0.0003 ppm Magneeium (Mg) < 0.0002 ppmManganese(Md 0.01a1ppi Molybdenum (Mo) 0.0SZn ppmNeodymium (Nd < 0.oooi ppmNickel (ND < 0.oo0r ppmNiobium (M) 0.001g ppmOsmium (Os) O.OBOZ ppmPalladium (pO 0.0g86 ppm Phosphorus (p) I I=Spectral Interterence N=Not Teeted Silver (Ad I Sodium (Nd IStrontium (Sr) < 0.0oo06 ppnSultur (S) 0.7628 ppmTantalum (Td 0.2642 ppmTellurium (Te) I Terbium (Tb) < 0.00008 ppnThaltium (It) 0.0b0b ppmThorium (TD 0.0012 ppmThulium (Td < o.ooo-oi ppn ltn (Sd o.oooz ppmfitanium (Til < 0.001ppmTungeten (W) < o.OOOippm _U_ranium (U) < o.ooooippn Vanadium (V) < 0.00001ppnYtterbium (yb) < 0.001 ppmYttrium ff) 0.oo16 ppmZinc (Zn) I Zirconium Or) < 0.002 ppm Praseodymium (pr) < 0.00008 ppnRhenium (Re) < 0.0000A ppnBhodium (RD 0.004? ppmRubidium (Rb) < 0.0000a ppnRuthenium (Ru) 0.0011 ppmSamarium (Sm) < 0.002 ppmScandium(Sc) 0.000gppm Selenium (Se) < 0.004 ppmSilicon (Sil I PlodrrctMrebc: pHCfXN Projec{ No. M242}1OA Rotary Kiln Exhaust (K_1) Version: 1.6 Iot Nunbe: 4402F46 156 of 159 @Mostardi platt Page 1 of2 Mercury ICP Standard, 1 mL = 1 mB Hg (t,000 ppm Hg) HginSo/o EPA(200.7) HNOs This standard is guaranteed to be stable and accurate provided the product ie kept tightly capped and stored under normal laboratory conditions. Balances are calibrated using NIST traceable weights whoae verification of maintenance and recalibration is documented per in'house Standard Operating Procedurea. Clasa A glaseware is also calibrated and routinely rechecked per in-houee Standard Operating Procedures. Ilace metal analyzed acide and Trace Metale Analyzed Water are ueed in the manufacture of this product. Triple cleaned containers are used in the manufacture of thia product. PHG1KN-100 100 mL natural I.DPE Reommended Storagp. 15'C '30'C (59'F - 86'F) 18 months /?e6r'^-tn Paul Brand on @2107 12024) Production Manager firis document ia deeigned to comply with ISO Guide 31 "Reference Materials " Contente of Certificatee and Labela." This teat report shall not be reproduced, except in full, without the written approval of Bicrca Chemical Company. Version: 1.5 Iat Nnmba: 4402F46 Page 2 of 2 Projecrt No. M2429104 Rotary Kiln Exhaust (K-1) htdrrct NuEbel: PHG1KN 157 of 159 @Mostardi Platt Ohio Lumex - Analytical Bias TestAnalyzer No.35!i Project No. M242g,lOA Rotary Kiln Exhaust (K_1)@Mostardi platt Pqleci tlo. M2429104 Rotary Kih Etdtetrt (K-1) END OF THE REPORT UTAH DEPARTMENT OFENVIEONME-NIA! Q UAL|TY DIVISION OF AIR OUALITY 159 d't59 Oilo.tBrdl Platt