HomeMy WebLinkAboutDERR-2025-002023Wexpro Company
333 South State Street
Salt Lake City, Utah 84111
United States
March 10, 2025
BY EMAIL
Robin Keeler
Utah Department of Environmental Quality
195 North 1950 West
Salt Lake City, UT 84114
RE: Wexpro Company, Horseshoe Bend Natural Gas Field,
LP Federal 23 Pad: EPCRA Section 311 Notification
Dear Robin Keeler:
In accordance with Section 311 of the Emergency Planning and Community Right-to-Know Act
(EPCRA), Wexpro Company is submitting safety data sheets (SDS) for storage of new chemicals at
the LP Federal 23 Natural Gas Production Pad in quantities greater than the threshold planning
quantity. The pad is located at the following GPS coordinates:
(40.192635°, -109.514544°). The materials referenced below will be included in the facility’s 2025
Tier II chemical inventory report submitted by March 1, 2026.
The Emergency Coordinator for the Horseshoe Bend natural gas field located in Uintah County,
Utah is Chet Deru, who can be contacted at (307)-352-7950 or chet.deru@dominionenergy.com
Chemical CAS # EHS Storage Locations Amount
Onsite
Dyed and Clear No. 2
Diesel Fuel 68476-34-6 No
7,500-gal tanker trailer
and 16,000-gal bulk
storage tank 747,784 lbs
Silica Sand – 100 mesh
and 30/50 mesh 14808-60-7 No 24-ton sand trailers 944,513 lbs
Wexpro Company
333 South State Street
Salt Lake City, Utah 84111
United States
Utah Department of Environmental Quality
March 10, 2025
Page 2
If you have any questions or require additional information, please contact Jace Capraro at
(801) 598-8394 or john.capraro@enbridge.com
Sincerely,
Adam Plonsky, Environmental Compliance Manager
cc: BY EMAIL
Utah Department of Environmental Quality
Mr. Tom Daniels; tdaniels@utah.gov
Uintah County LEPC:
Heidi Lundberg; hlundberg@uintah.utah.gov
Uintah Fire District:
Jeremy Raymond; Uintahfire@ubtanet.com
Enclosures:
Marathon No. 2 Diesel Fuel SDS
Natural Silica Sand SDS
SAFETY DATA SHEET
SDS ID NO.: 0290MAR019 Revision date 10/01/2020
1. IDENTIFICATION
Product Name Marathon Petroleum No. 2 Diesel
Synonym No. 2 Ultra Low Sulfur Diesel (15 ppm Sulfur Max); No. 2 Low Sulfur Diesel (500 ppm Sulfur
Max); ULSD No. 2; ULSD No. 2, dyed; ULSD No. 2 with Additives; ULSD No. 2 w/o
Additives; ULSD No. 2 Winter Blends; No 2 MV15 CFI; Export Diesel; No. 2 Fuel Oil;
Heating Oil; No. 2 Non-Road Locomotive Marine, Dyed; MGO; ULSD; LSD; NRLM; CARB
Diesel
Product code 0290MAR019
Chemical family Complex Hydrocarbon Substance
Recommended use Fuel.
Restrictions on use All others.
SDS Information 1-419-421-3070 (M-F; 8-5 EST)
24 Hour Emergency Telephone CHEMTREC: 1-800-424-9300 (CCN# 13740)
2. HAZARD IDENTIFICATION
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Classification
Acute toxicity - Inhalation (Dusts/Mists)Category 4
Skin corrosion/irritation Category 2
Carcinogenicity Category 2
Specific target organ toxicity (single exposure)Category 3
Specific target organ toxicity (repeated exposure)Category 2
Aspiration toxicity Category 1
Chronic aquatic toxicity Category 2
Hazards Not Otherwise Classified (HNOC)
Static accumulating flammable liquid
Label Elements
Manufacturer, Importer, or
Responsible Party Name and
Address
MARATHON PETROLEUM COMPANY LP
539 South Main Street
Findlay, OH 45840
Flammable liquids Category 3
Danger
FLAMMABLE LIQUID AND VAPOR
May accumulate electrostatic charge and ignite or explode
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 1 of 11
May be fatal if swallowed and enters airways
Harmful if inhaled
Causes skin irritation
May cause respiratory irritation
_____________________________________________________________________________________________
0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use only non-sparking tools.
Use explosion-proof electrical/ventilating/lighting/equipment
Take precautionary measures against static discharge
Do not breathe mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wear protective gloves/protective clothing/eye protection/face protection
Wash hands and any possibly exposed skin thoroughly after handling
Avoid release to the environment
Precautionary Statements - Response
IF exposed or concerned: Get medical attention
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
If skin irritation occurs: Get medical attention
Wash contaminated clothing before reuse
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a poison center or doctor if you feel unwell
If swallowed: Immediately call a poison center or doctor
Do NOT induce vomiting
In case of fire: Use water spray, fog or regular foam for extinction
Collect spillage
Precautionary Statements - Storage
Store in a well-ventilated place. Keep container tightly closed
Keep cool
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container at an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS
May contain up to 5% Biodiesel.
Composition Information
Name CAS Number % Concentration
No. 2 Diesel Fuel 68476-34-6 50-100
Kerosine (petroleum)8008-20-6 0-50
May cause drowsiness or dizziness
Suspected of causing cancer
May cause damage to organs (thymus, liver, bone marrow) through prolonged or repeated exposure
Toxic to aquatic life with long lasting effects
Appearance Yellow to Red Liquid Physical State Liquid
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 2 of 11
Odor Hydrocarbon
_____________________________________________________________________________________________
0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
Fuels, Diesel, C9-18-Alkane Branched and Linear 1159170-26-9 0-5
Alkanes, C10-C20 branched and linear 928771-01-1 0-5
Naphthalene 91-20-3 0.3-2.6
All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
4. FIRST AID MEASURES
First aid measures
General advice In case of accident or if you feel unwell, seek medical advice immediately (show directions
for use or safety data sheet if possible).
Inhalation Remove to fresh air. If not breathing, utilize bag valve mask or other form of barrier device
to institute rescue breathing. If breathing is difficult, ensure airway is clear, give oxygen and
continue to monitor. If heart has stopped, immediately begin cardiopulmonary resuscitation
(CPR). Keep affected person warm and at rest. Get immediate medical attention.
Skin contact Immediately wash exposed skin with plenty of soap and water while removing contaminated
clothing and shoes. May be absorbed through the skin in harmful amounts. Get medical
attention if irritation persists. Any injection injury from high pressure equipment should be
evaluated immediately by a physician as potentially serious (See NOTES TO PHYSICIAN).
Place contaminated clothing in closed container until cleaned or discarded. If clothing is to
be laundered, inform the person performing the operation of contaminant's hazardous
properties. Destroy contaminated, non-chemical resistant footwear.
Eye contact Flush immediately with large amounts of water for at least 15 minutes. Gently remove
contacts while flushing. Eyelids should be held away from the eyeball to ensure thorough
rinsing. Gently remove contacts while flushing. Get medical attention if irritation persists.
Ingestion Do not induce vomiting because of danger of aspirating liquid into lungs, causing serious
damage and chemical pneumonitis. If spontaneous vomiting occurs, keep head below hips,
or if patient is lying down, turn body and head to side to prevent aspiration and monitor for
breathing difficulty. Never give anything by mouth to an unconscious person. Keep affected
person warm and at rest. Get immediate medical attention.
Most important signs and symptoms, both short-term and delayed with overexposure
Adverse effects Irritating to the skin and mucous membranes. Symptoms may include redness, itching, and
inflammation. May cause nausea, vomiting, diarrhea, and signs of nervous system
depression: headache, drowsiness, dizziness, loss of coordination, disorientation and
fatigue. Aspiration hazard. May cause coughing, chest pains, shortness of breath,
pulmonary edema and/or chemical pneumonitis. Prolonged or repeated exposure may
cause adverse effects to the thymus, liver, and bone marrow. Repeated or prolonged skin
contact may cause drying, reddening, itching and cracking.
Indication of any immediate medical attention and special treatment needed
Notes to physician INHALATION: This material (or a component) sensitizes the myocardium to the effects of
sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate
cardiac arrhythmias in individuals exposed to this material. Administration of
sympathomimetic drugs should be avoided.
SKIN: Leaks or accidents involving high-pressure equipment may inject a stream of material
through the skin and initially produce an injury that may not appear serious. Only a small
puncture wound may appear on the skin surface but, without proper treatment and
depending on the nature, original pressure, volume, and location of the injected material,
can compromise blood supply to an affected body part. Prompt surgical debridement of the
wound may be necessary to prevent irreversible loss of function and/or the affected body
part. High pressure injection injuries may be SERIOUS SURGICAL EMERGENCIES.
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 3 of 11
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0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
INGESTION: This material represents a significant aspiration and chemical pneumonitis
hazard. Induction of emesis is not recommended.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media For small fires, Class B fire extinguishing media such as CO2, dry chemical, foam or water
spray can be used. For large fires, water spray, fog or foam can be used. Firefighting
should be attempted only by those who are adequately trained and equipped with proper
protective equipment.
Unsuitable extinguishing media Do not use straight water streams to avoid spreading fire.
Specific hazards arising from the
chemical
This product has been determined to be a flammable liquid per the OSHA Hazard
Communication Standard and should be handled accordingly. May accumulate electrostatic
charge and ignite or explode. Vapors may travel along the ground or be moved by
ventilation and ignited by many sources such as pilot lights, sparks, electric motors, static
discharge, or other ignition sources at locations distant from material handling. Flashback
can occur along vapor trail. For additional fire related information, see NFPA 30 or the
Emergency Response Guidebook 128.
Hazardous combustion products Smoke, carbon monoxide, and other products of incomplete combustion.
Explosion data
Sensitivity to mechanical
impact:
No.
Sensitivity to static discharge:Yes.
Special protective equipment and
precautions for firefighters
Firefighters should wear full protective clothing and positive-pressure self-contained
breathing apparatus (SCBA) with a full face-piece, as appropriate. Avoid using straight
water streams. Water spray and foam must be applied carefully to avoid frothing and from
as far a distance as possible. Avoid excessive water spray application. Keep surrounding
area cool with water spray from a distance and prevent further ignition of combustible
material. Keep run-off water out of sewers and water sources.
Additional firefighting tactics FIRES INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance
or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities
of water until well after the fire is out. Do not direct water at source of leak or safety devices;
icing may occur. Withdraw immediately in case of rising sound from venting safety devices
or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire,
use unmanned hose holders or monitor nozzles: if this is impossible, withdraw from area
and let fire burn.
EVACUATION: Consider initial downwind evacuation for at least 1000 feet. If tank, rail car
or tank truck is involved in a fire, ISOLATE for 5280 feet (1 mile) in all directions; also,
consider initial evacuation of 5280 feet (1 mile) in all directions.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Keep public away. Isolate and evacuate area. Shut off source if safe to do so. Eliminate all
ignition sources. All contaminated surfaces will be slippery.
Protective equipment Use personal protection measures as recommended in Section 8.
Emergency procedures Advise authorities and National Response Center (800-424-8802) if the product has
entered a water course or sewer. Notify local health and pollution control agencies, if
appropriate.
Environmental precautions Avoid release to the environment. Avoid subsoil penetration.
NFPA Health 1 Flammability 2 Instability 0 Special Hazard -
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 4 of 11
_____________________________________________________________________________________________
0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
Methods and materials for
containment
Contain liquid with sand or soil. Prevent spilled material from entering storm drains, sewers,
and open waterways.
Methods and materials for cleaning
up
Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual
liquids. Recover and return free product to proper containers. When recovering free liquids
ensure all equipment is grounded and bonded. Use only non-sparking tools.
7. HANDLING AND STORAGE
Safe handling precautions NEVER SIPHON THIS PRODUCT BY MOUTH. Use appropriate grounding and bonding
practices. Static accumulating flammable liquid. Bonding and grounding may be insufficient
to eliminate the hazard from static electricity. Do not expose to heat, open flames, strong
oxidizers or other sources of ignition. Vapors may travel along the ground or be moved by
ventilation. Flashback may occur along vapor trails. No smoking. Use only non-sparking
tools. Avoid breathing fumes, gas, or vapors. Use only with adequate ventilation. Avoid
repeated and prolonged skin contact. Use personal protection measures as recommended
in Section 8. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water. Do not cut, drill, grind or weld on empty containers
since explosive residues may remain. Refer to applicable EPA, OSHA, NFPA and
consistent state and local requirements.
Hydrocarbons are basically non-conductors of electricity and can become electrostatically
charged during mixing, filtering, pumping at high flow rates or loading and transfer
operations. If this charge reaches a sufficiently high level, sparks can form that may ignite
the vapors of flammable liquids. Sudden release of hot organic chemical vapors or mists
from process equipment operating under elevated temperature and pressure, or sudden
ingress of air into vacuum equipment may result in ignition of vapors or mists without the
presence of obvious ignition sources. Nozzle spouts must be kept in contact with the
containers or tank during the entire filling operation.
Portable containers should never be filled while in or on a motor vehicle or marine craft.
Containers should be placed on the ground. Static electric discharge can ignite fuel vapors
when filling non-grounded containers or vehicles on trailers. The nozzle spout must be kept
in contact with the container before and during the entire filling operation. Use only
approved containers.
A buildup of static electricity can occur upon re-entry into a vehicle during fueling especially
in cold or dry climate conditions. The charge is generated by the action of dissimilar fabrics
(i.e., clothing and upholstery) rubbing across each other as a person enters/exits the
vehicle. A flash fire can result from this discharge if sufficient flammable vapors are
present. Therefore, do not get back in your vehicle while refueling.
Cellular phones and other electronic devices may have the potential to emit electrical
charges (sparks). Sparks in potentially explosive atmospheres (including fueling areas
such as gas stations) could cause an explosion if sufficient flammable vapors are present.
Therefore, turn off cellular phones and other electronic devices when working in potentially
explosive atmospheres or keep devices inside your vehicle during refueling.
High-pressure injection of any material through the skin is a serious medical emergency
even though the small entrance wound at the injection site may not initially appear serious.
These injection injuries can occur from high-pressure equipment such as paint spray or
grease or guns, fuel injectors, or pinhole leaks in hoses or hydraulic lines and should all be
considered serious. High pressure injection injuries may be SERIOUS SURGICAL
EMERGENCIES (See First Aid Section 4).
Storage conditions Store in properly closed containers that are appropriately labeled and in a cool,
well-ventilated area. Do not store near an open flame, heat or other sources of ignition.
Incompatible materials Strong oxidizing agents.
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 5 of 11
_____________________________________________________________________________________________
0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Name ACGIH TLV OSHA PELS NIOSH IDLH
No. 2 Diesel Fuel
68476-34-6
100 mg/m3 TWA
Skin - potential significant
contribution to overall exposure
by the cutaneous route
--
Kerosine (petroleum)
8008-20-6
200 mg/m3 TWA
Skin - potential significant
contribution to overall exposure
by the cutaneous route
--
Naphthalene
91-20-3
10 ppm TWA
Skin - potential significant
contribution to overall exposure
by the cutaneous route
TWA: 10 ppm
TWA: 50 mg/m3
250 ppm
Notes:No further information available.
Engineering measures Local or general exhaust required in an enclosed area or with inadequate ventilation. Use
mechanical ventilation equipment that is explosion-proof.
Personal protective equipment
Eye protection Use goggles or face-shield if the potential for splashing exists.
Skin and body protection Wear neoprene, nitrile or PVA gloves to prevent skin contact. Glove suitability is based on
workplace conditions and usage. Contact the glove manufacturer for specific advice on
glove selection and breakthrough times.
Respiratory protection Use a NIOSH approved organic vapor chemical cartridge or supplied air respirators when
there is the potential for airborne exposures to exceed permissible exposure limits or if
excessive vapors are generated. Observe respirator assigned protection factors (APFs)
criteria cited in federal OSHA 29 CFR 1910.134. Self-contained breathing apparatus should
be used for fire fighting.
Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Yellow to Red Liquid
Physical State Liquid
Color Yellow to Red
Odor Hydrocarbon
Odor Threshold No data available.
Property Values (method)
pH Not applicable
Melting Point / Freezing Point No data available.
Initial Boiling Point / Boiling Range 154-366 °C / 310-691 °F (ASTM D86)
Flash Point 58-76 °C / 136-168 °F (ASTM D93)
Evaporation Rate No data available.
Flammability (solid, gas)Not applicable.
Flammability Limit in Air (%):
Upper Flammability Limit:No data available.
Lower Flammability Limit:No data available.
Explosion Limits No data available.
Vapor Pressure No data available.
Vapor Density No data available.
Specific Gravity / Relative Density 0.82-0.86
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 6 of 11
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0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
Water Solubility No data available.
Partition Coefficient No data available.
Autoignition Temperature No data available.
Decomposition Temperature No data available.
Kinematic Viscosity 1.7-4.1 cSt @ 40°C (ASTM D445)
VOC Content (%)No data available.
10. STABILITY AND REACTIVITY
Chemical stability The material is stable at 70°F (21°C ), 760 mmHg pressure.
Possibility of hazardous reactions None under normal processing.
Hazardous polymerization Will not occur.
Conditions to avoid Excessive heat, sources of ignition, open flame.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition products None known under normal conditions of use. However, use in an area without adequate
ventilation may result in hazardous levels of carbon monoxide and carbon dioxide.
11. TOXICOLOGICAL INFORMATION
Potential short-term adverse effects from overexposures
Inhalation Harmful if inhaled. May cause irritation of respiratory tract. May cause drowsiness or
dizziness. Breathing high concentrations of this material in a confined space or by
intentional abuse can cause irregular heartbeats which can cause death.
Eye contact Exposure to vapor or contact with liquid may cause mild eye irritation, including tearing,
stinging, and redness.
Skin contact Irritating to skin. Effects may become more serious with repeated or prolonged contact. May
be absorbed through the skin in harmful amounts.
Ingestion May be fatal if swallowed or vomited and enters airways. May cause irritation of the mouth,
throat and gastrointestinal tract.
Acute toxicological data
Name Oral LD50 Dermal LD50 Inhalation LC50
No. 2 Diesel Fuel
68476-34-6
> 5000 mg/kg (Rat)> 2000 mg/kg (Rabbit)>1 - <5 mg/L (Rat) 4 h
Kerosine (petroleum)
8008-20-6
> 5000 mg/kg (Rat)> 2000 mg/kg (Rabbit)> 5.28 mg/L (Rat) 4 h
Fuels, Diesel, C9-18-Alkane
Branched and Linear
1159170-26-9
-->1 - <5 mg/l (Rat) 4 h
Alkanes, C10-C20 branched and
linear
928771-01-1
-->1 - <5 mg/l (Rat) 4 h
Naphthalene
91-20-3
533 mg/kg (Mouse)> 2000 mg/kg (Rabbit)> 340 mg/m3 (Rat) 1 h
Immediate and delayed effects as well as chronic effects from short and long-term exposure
PETROLEUM MIDDLE DISTILLATES: Petroleum derived middle distillates have produced skin tumors in mice after repeated and
prolonged skin contact. Additional studies indicated prolonged skin irritation contributes to tumor development. Repeated dermal
exposures to high concentrations in test animals resulted in reduced litter size and weight, and increased fetal resorptions at doses
Reactivity The product is non-reactive under normal conditions.
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 7 of 11
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0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
toxic to the mother. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung
changes/infiltration/accumulation, and reduction in lung function. Repeated dermal application of petroleum gas oils resulted in
decreased liver, thymus, and spleen weights, and altered bone marrow function. Microscopic alterations included liver hypertrophy
and necrosis, decreased hematopoiesis and lymphocyte depletion. Altered mental state, drowsiness, peripheral motor neuropathy,
irreversible brain damage (so-called Petrol Sniffer's Encephalopathy), delirium, seizures, and sudden death have been reported
from repeated overexposure to some hydrocarbon solvents, naphthas, and gasoline.
NAPHTHALENE: Excessive exposure to naphthalene may cause nausea, vomiting, diarrhea, blood in the urine, and a yellow color
to the skin. Lifetime inhalation exposure of laboratory rodents to naphthalene resulted in cancers of the respiratory tract in male and
female rats. A small increase in cancer of the lung was observed in female mice, but no evidence of lung cancer was observed in
male mice. Long-term exposure to excessive airborne naphthalene concentrations may result in destruction of red blood cells, a
condition referred to as hemolytic anemia.
DIESEL EXHAUST: The combustion of diesel fuels produces gases including carbon monoxide, carbon dioxide, oxides of nitrogen
and/or sulfur, and hydrocarbons that can be irritating and hazardous with overexposure. Long-term occupational overexposure to
diesel exhaust and diesel exhaust particulate matter has been associated with an increased risk of respiratory disease, including
lung cancer, and is characterized as a “known human carcinogen” by the International Agency for Research on Cancer (IARC), as
“a reasonably anticipated human carcinogen” by the National Toxicology Program, and as “likely to be carcinogenic to humans” by
the EPA, based upon animal and occupational exposure studies. However, uncertainty exists with these classifications because of
deficiencies in the supporting occupational exposure/epidemiology studies, including reliable exposure estimates. Lifetime animal
inhalation studies with pulmonary overloading exposure concentrations of diesel exhaust emissions have produced tumors and
other adverse health effects. However, in more recent long-term animal inhalation studies of diesel exhaust emissions, no increase
in tumor incidence and in fact a substantial reduction in adverse health effects along with significant reductions in the levels of
hazardous material emissions were observed and are associated with fuel composition alterations coupled with new technology
diesel engines.
Adverse effects related to the physical, chemical and toxicological characteristics
Signs and symptoms Irritating to the skin and mucous membranes. Symptoms may include redness, itching, and
inflammation. May cause nausea, vomiting, diarrhea, and signs of nervous system
depression: headache, drowsiness, dizziness, loss of coordination, disorientation and
fatigue. Aspiration hazard. May cause coughing, chest pains, shortness of breath,
pulmonary edema and/or chemical pneumonitis. Repeated or prolonged skin contact may
cause drying, reddening, itching and cracking. Prolonged or repeated exposure may cause
damage to organs.
Acute toxicity Harmful if inhaled.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye irritation None known.
Sensitization None known.
Mutagenic effects None known.
Carcinogenicity Suspected of causing cancer.
Name ACGIH
(Class)
IARC
(Class)
NTP OSHA
No. 2 Diesel Fuel
68476-34-6
Confirmed animal
carcinogen (A3)
Not Classifiable (3)Not Listed Not Listed
Kerosine (petroleum)
8008-20-6
Confirmed animal
carcinogen (A3)
Not Classifiable (3)Not Listed Not Listed
Naphthalene
91-20-3
Confirmed animal
carcinogen (A3)
Possible human carcinogen
(2B)
Reasonably anticipated to
be a human carcinogen
Not Listed
Reproductive toxicity None known.
Specific Target Organ Toxicity
(STOT) - single exposure
May cause respiratory irritation. May cause drowsiness or dizziness.
Specific Target Organ Toxicity May cause damage to organs (thymus, liver, bone marrow) through prolonged or repeated
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 8 of 11
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0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
(STOT) - repeated exposure exposure.
Aspiration hazard May be fatal if swallowed or vomited and enters airways.
12. ECOLOGICAL INFORMATION
Ecotoxicity This product should be considered toxic to aquatic organisms, with the potential to cause
long lasting adverse effects in the aquatic environment.
Name Fish Crustacea Algae/aquatic plants
No. 2 Diesel Fuel
68476-34-6
96-hr LC50 = 35 mg/l Fathead
minnow (flow-through)
48-hr EL50 = 6.4 mg/l Daphnia
magna
-
Kerosine (petroleum)
8008-20-6
96-hr LL50 = 18-25 mg/l
Fish
48-hr EL50 = 1.4-21 mg/l
Invertebrates
72-hr EL50 = 5.0-11 mg/l
Algae
Naphthalene
91-20-3
96-hr LC50 = 0.91-2.82 mg/l
Rainbow trout (static)
96-hr LC50 = 1.99 mg/l Fathead
minnow (static)
48-hr LC50 = 1.6 mg/l Daphnia
magna
-
Persistence and degradability Expected to be inherently biodegradable.
Bioaccumulation Has the potential to bioaccumulate.
Mobility in soil May partition into air, soil and water.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Description of waste residues This material may be a flammable liquid waste.
Safe handling of wastes Handle in accordance with applicable local, state, and federal regulations. Use personal
protection measures as required. Use appropriate grounding and bonding practices. Use
only non-sparking tools. Do not expose to heat, open flames, strong oxidizers or other
sources of ignition. No smoking.
Disposal of wastes / methods of
disposal
The user is responsible for determining if any discarded material is a hazardous waste (40
CFR 262.11). Dispose of in accordance with federal, state and local regulations.
Contaminated packaging disposal Empty containers should be completely drained and then discarded or recycled, if possible.
Do not cut, drill, grind or weld on empty containers since explosive residues may be
present. Dispose of in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT
UN/Identification No:NA 1993
UN Proper Shipping Name:Diesel Fuel
Transport Hazard Class(es):3
Packing Group:III
IATA
UN/Identification No:UN 1202
UN Proper Shipping Name:Diesel Fuel
Transport Hazard Class(es):3
Packing Group:III
ERG code:3L
IMDG
UN/Identification No:UN 1202
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 9 of 11
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0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
UN Proper Shipping Name:Diesel Fuel
Transport Hazard Class(es):3
Packing Group:III
EmS No:F-E, S-E
Marine Pollutant:Yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15. REGULATORY INFORMATION
Regulatory Information
US TSCA Chemical Inventory This product and/or its components are listed on the TSCA Chemical Inventory or are
exempt.
Canada DSL/NDSL Inventory This product and/or its components are listed either on the Domestic Substances List (DSL)
or are exempt.
EPA Superfund Amendment & Reauthorization Act (SARA)
SARA Section 302 This product does not contain any component(s) included on EPA's Extremely Hazardous
Substance (EHS) List above the de minimis threshold.
SARA Section 304 This product may contain component(s) identified either as an EHS or a CERCLA
Hazardous substance which in case of a spill or release may be subject to SARA reporting
requirements:
Name Hazardous Substances RQs
Naphthalene
91-20-3
100 lb
45.4 kg
SARA Section 311/312 The following EPA hazard categories apply to this product:
Flammable
Hazard Not Otherwise Classified (HNOC)-Physical
Acute toxicity
Skin corrosion or irritation
Carcinogenicity
Specific target organ toxicity
Aspiration hazard
SARA Section 313 This product may contain component(s), which if in exceedance of the de minimus
threshold, may be subject to the reporting requirements of SARA Title III Section 313 Toxic
Release Reporting (Form R).
Name CERCLA/SARA 313 Emission reporting
Naphthalene
91-20-3
0.1 % de minimis concentration
U.S. State Regulations
California Proposition 65 This product can expose you to chemicals which are known to the State of California to
cause cancer, birth defects or other reproductive harm.
Name California Proposition 65
No. 2 Diesel Fuel
68476-34-6
Engine exhaust, Carcinogen, initial date 10/01/90
Naphthalene
91-20-3
Carcinogen, initial date 04/19/02
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 10 of 11
For more information, go to www.P65Warnings.ca.gov.
_____________________________________________________________________________________________
0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020
State Right-To-Know Regulations The following component(s) of this material are identified on the regulatory lists below:
Name New Jersey Right-To-Know Pennsylvania Right-To-Know Massachusetts Right-To
Know
No. 2 Diesel Fuel
68476-34-6
Listed Listed Not Listed
Kerosine (petroleum)
8008-20-6
Listed Listed Listed
Naphthalene
91-20-3
Listed Listed Listed
16. OTHER INFORMATION
Prepared by Toxicology & Product Safety
NFPA
Revision Notes
Revision date 10/01/2020
Previous publish date 06/01/2016
Revised sections The following sections (§) have been updated:
3. COMPOSITION/INFORMATION ON INGREDIENTS
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information is intended as guidance for safe handling, use, processing, storage,
transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 11 of 11
SAFETY DATA SHEET SDS No: 011-U-GHS
011-u-silica-ghs.doc Page 1 of 8 Date Prepared: April 2015
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name: Crystalline Silica in the form of Quartz – various grades
Synonyms: Quartz, Crystalline Silica, Silicon Dioxide
Relevant Identified Uses of the Substance or Mixture and Uses Advised Against:
Product Use: Various commercial and industrial uses
Manufacturer:
UNIMIN CORPORATION Emergency Telephone Number
258 Elm Street (203) 966-8880
New Canaan, CT 06840
Telephone Number for Information
(203) 966-8880
SDS Date of Preparation/Revision: April 2014
SECTION 2: HAZARDS IDENTIFICATION
GHS/ Hazcom 2012 Classification:
Physical: Health: Environmental
Not Hazardous Carcinogen Category 1A
Specific Target Organ Toxicity
(Repeated Exposure) Category 1
Not Hazardous
GHS/Hazcom 2012 Label:
DANGER
Statements of Hazard Prevention
May cause cancer by inhalation.
Causes damage to lungs through prolonged or repeated
exposure by inhalation
Response:
If exposed or concerned: Get medical advice.
Disposal:
Dispose of contents/containers in accordance with local
regulation.
Obtain special instructions before use.
Do not handle until all safety precautions have been read
and understood.
Do not breathe dust.
Do not eat, drink or smoke when using this product.
Wear protective gloves and safety glasses or goggles.
In case of inadequate ventilation wear respiratory
protection.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
CAS# Component Percentage
14808-60-7 Crystalline Silica in the form of Quartz 87 - 99.9%
SECTION 4: FIRST AID MEASURES
Gross Inhalation: Remove victim to fresh air. If breathing has stopped, perform artificial respiration. If breathing is difficult
have qualified personnel administer oxygen. Get prompt medical attention.
SDS No: 011-U-GHS
Page 2 of 8 Date Prepared: April 2015
Skin Contact: No first aid should be needed since dermal contact with this product does not affect the skin. Wash exposed
skin with soap and water before breaks and at the end of the shift.
Eye Contact: Flush the eyes immediately with large amounts of running water, lifting the upper and lower lids occasionally.
If irritation persists or for imbedded foreign body, get immediate medical attention.
Ingestion: If large amounts are swallowed, get immediate medical attention.
Most Important Symptoms and Effects, Both Acute and Delayed: May cause eye irritation with redness and
tearing. Exposure to dust may cause mucous membrane and respiratory irritation, cough, sore throat, nasal congestion,
sneezing and shortness of breath. However, there may be no immediate signs or symptoms of exposure to hazardous
concentrations of respirable crystalline silica (quartz).
Indication of immediate medical attention and Special Treatment Needed: None required.
SECTION 5: FIREFIGHTING MEASURES
Suitable Extinguishing Media: This product will not burn but is compatible with all extinguishing media. Use any media
that is appropriate for the surrounding fire.
Specific Hazards Arising from the Chemical:
Unusual Fire and Explosion Hazards: Not flammable or combustible. Dry powders may accumulate static charge
in handling which can be a source of ignition for flammable atmospheres.
Hazardous Combustion Products: None.
Special Protective Equipment and Precautions for Fire-Fighters: None required with respect to this product.
Firefighters should always wear self-contained breathing apparatus for fires indoors or in confined areas.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective equipment.
Environmental Precautions: Report spills and releases as required to appropriate authorities.
Methods and Material for Containment/Cleanup: If uncontaminated, collect using dustless method (HEPA vacuum
or wet method) and place in appropriate container for use. If contaminated: a) use appropriate method for the nature of
contamination, and b) consider possible toxic or fire hazards associated with the contaminating substances. Collect for
appropriate disposal.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling: Do not breathe dust. Do not rely on your sight to determine if dust is in the air.
Silica may be in the air without a visible dust cloud. Use normal precautions against bag breakage or spills of bulk
material. Avoid creation of respirable dust. Use good housekeeping in storage and use areas to prevent accumulation
of dust in work area.
To reduce the risk of developing silicosis, lung cancer and other adverse health effects, the ACGIH recommends that the
industrial hygienist use every means available to keep exposures below the recommended TLV. NIOSH recommends
reducing airborne exposure levels as low as possible below NIOSH’s recommended exposure limit, substituting less
hazardous materials when feasible, using appropriate respiratory protection when source controls cannot keep exposures
below the recommended limit and making medical examinations available to exposed workers.
Use adequate ventilation and dust collection. To minimize exposure, wear a respirator approved for silica dust when using,
handling, storing or disposing of this product or bag. Refer to the most recent government and local regulations when
selecting a respirator. Maintain, clean and fit test respirators in accordance with the most recent government and local
SDS No: 011-U-GHS
Page 3 of 8 Date Prepared: April 2015
regulations. Maintain and test ventilation and dust collection equipment. Launder clothing that has become dusty. Empty
containers (bags, bulk containers, storage tanks, etc.) retain silica residue and must be handled in accordance with the
provisions of this Material Safety Data Sheet. WARN and TRAIN employees in accordance with state and federal
regulations.
WARN YOUR EMPLOYEES (AND YOUR CUSTOMERS AND USERS IN CASE OF RESALE) BY POSTING,
AND OTHER MEANS, OF THE HAZARDS AND OSHA AND ANY OTHER APPLICABLE REGULATORY
PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT OSHA
PRECAUTIONS.
Dust can accumulate electrostatic charges due to friction from transfer and mixing operations and cause an electrical spark
(ignition source) which can ignite flammable liquids and atmospheres. Provide adequate precautions when adding this
product to flammable and combustible mixtures like paints and coating, such as electrical grounding and bonding, inert
atmosphere or non-sparking tools. However, bonding and grounds may not eliminate the hazard for static accumulation.
See also American Society for Testing and Materials (ASTM) Standard Practice E1132-99a, “Standard Practice for Health
Requirements Relating to Occupational Exposure to Respirable Crystalline Silica”.
Additional information on silica hazards and precautionary measures can be found at the following websites:
NIOSH Joint Campaign on Silicosis Prevention http://www.cdc.gov/niosh/topics/silica/default.html
OSHA Crystalline Silica Website http://www.osha.gov/dsg/topics/silicacrystalline/index.html
MSHA Silicosis Prevention Website http://www.msha.gov/S&HINFO/SILICO/SILICO.HTM
NIOSH Hazard Review – Health Effects of Occupational Exposure to Respirable Crystalline Silica Website
http://www.cdc.gov/niosh/docs/2002-129/
Conditions for Safe Storage, Including any Incompatibilities: Store in a dry location.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines:
Definitions:
NIOSH means National Institute for Occupational Safety and Health.
REL means the NIOSH Recommended Exposure Limit.
TLV means American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value.
TWA means time-weighted average.
OSHA PEL and MSHA Exposure Limit for Crystalline Silica, Quartz 10 mg/m3
(Respirable measured as an 8-hour TWA) % Silica + 2
TLV- 0.025 mg/m3 8-hour TWA (respirable fraction)
In 2006 the ACGIH lowered the TLV for Silica, Crystalline: α-Quartz and Cristobalite to 0.025 mg/m3 stating in the
Documentation of the TLV “Because the time between exposure and signs of fibrosis is characteristically very long, as much
as 30 to 40 years, the margin of safety for exposure to crystalline silica at the proposed TLV-TWA is not known precisely.
Given the observed association between silicosis and lung cancer, it is recommended that air concentrations be maintained as
far below the proposed TLV as prudent practices permit. The recommended TLV-TWA of 0.025 mg/m3, respirable
particulate mass, is intended to prevent pulmonary fibrosis that may be a risk factor for lung cancer. An A2, Suspected
Human Carcinogen, notation is based on the demonstrated association between lung cancer and the presence of silicosis.”
The documentation further states “A lack of toxicological and industrial hygiene data does not permit the recommendation of
a TLV-STEL. However, it should be noted that high exposures of short duration to freshly fragmented crystalline particles do
produce an acute and rapidly progressive form of silicosis. The reader is encouraged to review the section on Excursion
Limits in the “Introduction to the Chemical Substances” of the current TLVs and BEIs book for guidance and control of
excursions above the TLV-TWA, even when the 8-hour TWA is within the recommended limits”
SDS No: 011-U-GHS
Page 4 of 8 Date Prepared: April 2015
NIOSH has issued its REL of 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full
shift sample up to 10-hour working day, 40 hours per week. NIOSH has recommended that OSHA and MSHA adopt the
NIOSH REL as the OSHA PEL and the MSHA Exposure Limit. The 1974 NIOSH Criteria for a Recommended Standard for
Occupational Exposure to Crystalline Silica should be consulted for more detailed information. Additionally, NIOSH, In a
publication entitled NIOSH Hazard Review Health Effects of Occupational Exposure to Respirable Silica (April 2002),
NIOSH stated “…that workers have a significant risk of developing chronic silicosis when they are exposed to respirable
crystalline silica over a working lifetime at the current Occupational Safety and Health Administration (OSHA) permissible
exposure limit (PEL), the Mine Safety and Health Administration (MSHA) PEL, or the National Institute for Occupational
Safety and Health (NIOSH) recommended exposure limit (REL). …Current sampling and analytical methods used to
evaluate occupational exposure to respirable crystalline silica do not meet the accuracy criterion needed to quantify
exposures at concentrations below the NIOSH REL of 0.05 mg/m3 as a time-weighted average (TWA) for up to a 10-hr
workday during a 40-hr workweek. Until improved sampling and analytical methods are developed for respirable crystalline
silica, NIOSH will continue to recommend an exposure limit of 0.05 mg/m3 to reduce the risk of developing silicosis, lung
cancer, and other adverse health effects. NIOSH also recommends minimizing the risk of illness that remains for workers
exposed at the REL by substituting less hazardous materials for crystalline silica when feasible, by using appropriate
respiratory protection when source controls cannot keep exposures below the NIOSH REL, and by making medical
examinations available to exposed workers.”
Crystalline silica exists in several forms, the most common of which are quartz (i.e. this product), trydimite and cristobalite,
with quartz being the most common form found in nature. If quartz is heated to more than 870°C, it can change form to
trydimite and if quartz is heated to more than 1450°C, it can change form to cristobalite.
Appropriate Engineering Controls: Use local exhaust as required to maintain exposures as far as possible below
applicable occupational exposure limits. See also ACGIH "Industrial Ventilation - A Manual for Recommended
Practice" (current edition). Control of exposure to dust must be accomplished as far as feasible by accepted engineering
control measures (for example, enclosure or confinement of the operation, general or local exhaust ventilation and
substitution of less toxic materials).
Personal Protective Equipment:
Respiratory Protection: When effective engineering controls are not feasible, or while they are being implemented,
appropriate respiratory protection must be used. Use appropriate respiratory protection for respirable particulates based on
consideration of airborne workplace concentrations and duration of exposure arising from intended end use. Refer to the most
recent government and local standards.
Gloves: Protective gloves recommended.
Eye Protection: Safety glasses or goggles recommended.
Other Protective Equipment/Clothing: As appropriate for the work environment. Dusty clothing should be laundered
before reuse.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Form: Solid Appearance: White powder
Viscosity: Not applicable Odor: None
pH: Not applicable Odor Threshold: Not applicable
Boiling Point/Range: 4046°F / 2230°C Vapor Density: Not applicable
Melting point/freezing
point:
2930°F / 1610°C Evaporation Rate: Not applicable
Flammability (solid, gas): Fully oxidized, will not burn Partition coefficient (n-
octanol/water):
Not applicable
Decomposition
Temperature:
Not applicable Vapor Pressure: Not applicable
Flash Point: Not applicable Relative Density: 2.65
Lower Explosion Limit: Not applicable Solubilities: Insoluble in water
SDS No: 011-U-GHS
Page 5 of 8 Date Prepared: April 2015
Upper Explosion Limit: Not applicable Autoignition Temperature: Will not burn
SECTION 10: STABILITY AND REACTIVITY
Reactivity: This product is not reactive under normal conditions of storage and use.
Chemical Stability: This product is stable at normal temperatures.
Possibility of Hazardous Reactions: None known
Conditions to Avoid: None known.
Incompatible Materials: Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, etc.
Hazardous Decomposition Products: Silica will dissolve in hydrofluoric acid producing a corrosive gas, silicon
tetrafluoride.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects
Potential Health Effects:
Inhalation: Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be
occurring. Inhalation of dust may have serious chronic health effects (see below Repeat Dose Toxicity.)
Skin Contact: No adverse effects expected.
Eye Contact: Contact may cause mechanical irritation and possible injury.
Ingestion: No adverse effects expected for normal, incidental ingestion.
Chronic Health Effects: See Repeat Dose Toxicity below with respect to silicosis, cancer status and other data with possible
relevance to human health.
Signs and Symptoms of Exposure: Exposure to dust may cause mucous membrane and respiratory irritation, cough, sore
throat, nasal congestion, sneezing and shortness of breath. However, there may be no immediate signs or symptoms of
exposure to hazardous concentrations of respirable crystalline silica (quartz). See Repeat Dose Toxicity below for symptoms
of silicosis. The absence of symptoms is not necessarily indicative of safe conditions.
Acute Toxicity Values: Silica: LD50 oral rat >22,500 mg/kg.
Skin Sensitization: Not a skin sensitizer in animals or humans.
Repeated Dose Toxicity:
Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling and sometimes
fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific
chest illness and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with
silicosis are predisposed to develop mycobacterial infections (tuberculous and non-tuberculous) and fungal
infections. Inhalation of air with a very high concentration of respirable silica dust can cause the most
serious forms of silicosis in a matter of months or a few years. Some epidemiologic studies have
concluded that there is significant risk of developing silicosis even at airborne exposure levels that are
equal to the recommended NIOSH REL, and ACGIH TLV.
SDS No: 011-U-GHS
Page 6 of 8 Date Prepared: April 2015
Other Data with Possible Relevance to Human Health:
There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with
an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder
manifested by fibrosis of the lungs, skin and other internal organs) rheumatoid arthritis, systemic lupus,
erythematosus, sarcoidosis, chronic bronchitis, chronic obstructive pulmonary disease (COPD),
emphysema, chronic kidney disease and end-stage renal disease.
For further information consult "Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic
Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine,
Volume 155, pages 761-768, 1997, and see also NIOSH Hazard Review – Health Effects of Occupational Exposure to
Respirable Crystalline Silica, April 2002 (see Section 7 for NIOSH Hazard Review Website).
Carcinogenicity: The International Agency for Research on Cancer has determined that crystalline silica is carcinogenic to
humans (Group 1 - carcinogenic to humans). Refer to IARC Monograph 100C, A Review of Human Carcinogens: Arsenic,
Fibres, and Dusts (published in 2011) in conjunction with the use of these materials. The National Toxicology Program
classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the Twelfth Report on Carcinogens
(2011). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
Developmental / Reproductive Toxicity: No specific data is available, however, there is no evidence that silica exposure
has any effect on reproduction.
Genetic Toxicity: No specific data is available, however, there is no evidence that silica is a germ cell mutagen.
SECTION 12: ECOLOGICAL INFORMATION
Toxicity: Practically non-toxic to aquatic organisms. Silica: LC50 carp >10,000 mg/L/72 hr.
Persistence and Degradability: Silica is not degradable.
Bioaccumulative Potential: Not expected to bioaccumulate.
Mobility in Soil: Not applicable.
Results of PBT and vPvB Assessment: None required.
Other Adverse Effects: None known
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Treatment Methods:
If uncontaminated, dispose as an inert, non-metallic mineral. If contaminated, dispose in accordance with all applicable local,
state/provincial and national/ federal regulations in light of the contamination present. Local regulations may be more
stringent than regional and national requirements. It is the responsibility of the waste generator to determine the toxicity and
physical characteristics of the material to determine the proper waste identification and disposal in compliance with
applicable regulations.
SECTION 14: TRANSPORT INFORMATION
Not regulated for transportation under IATA/ICAO, IMDG, US DOT, EU ADR, or Canadian TDG Regulations.
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code: None
SECTION 15: REGULATORY INFORMATION
SDS No: 011-U-GHS
Page 7 of 8 Date Prepared: April 2015
SARA 311/312: Hazard Categories for SARA Section 311/312 Reporting: Chronic Health
SARA 313 This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under the
SARA Section 313 (40 CFR 372): None
CERCLA Section 103 Reportable Quantity: None
California Proposition 65: This product contains crystalline silica (respirable) which is known to the State of California to
cause cancer.
Toxic Substances Control Act: All of the components of this product are listed on the EPA TSCA Inventory or exempt
from premanufacture notification requirements.
EU Inventory: All of the components of this product are listed on the EINECS inventory or exempt from notification
requirements.
EU REACH Status: This substance is exempt from REACH registration.
Canadian Environmental Protection Act: All the components of this product are listed on the Canadian Domestic
Substances List or exempt from notification requirements.
Canadian WHMIS Classification: Class D, Division 2, Subdivision A (Very Toxic Material causing other Toxic Effects)
This SDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the SDS
contains all of the information required by the CPR.
Japan EITI: All of the components of this product are existing chemical substances as defined in the Chemical Substance
Control Law.
Australian Inventory of Chemical Substances: All of the components of this product are listed on the AICS inventory or
exempt from notification requirements.
Australian National Occupational Health & Safety Commission Status: Hazardous according to the criteria of Australian
National Occupational Health & Safety Commission -Harmful (Xn) R48/20 Harmful: Danger of serious damage to health by
prolonged exposure by inhalation.
Korea: All of the components of this product are listed on the KECL inventory or exempt from notification requirements.
Philippines: All of the components of this product are listed on the PICCS inventory or exempt from notification
requirements.
New Zealand: All of the components of this product are listed on the HSNO inventory or exempt from notification
requirements.
China: All of the components of this product are listed on the IECSC inventory or exempt from notification requirements.
Taiwan: All of the components of this product are listed on the CSNN inventory or exempt from notification
requirements.
16: OTHER INFORMATION
NFPA Hazard Rating: Health: 1 Fire: 0 Reactivity: 0
HMIS Hazard Rating: Health: * Fire: 0 Reactivity: 0
SDS No: 011-U-GHS
Page 8 of 8 Date Prepared: April 2015
* Warning - Chronic health effect possible - inhalation of silica dust may cause lung injury/disease (silicosis). Take
appropriate measures to avoid breathing dust. See Section 3.
References:
Registry for Toxic Effects of Chemical Substances (RTECS), 2014
Patty's Industrial Hygiene and Toxicology
NIOSH Hazard Review – Health Effects of Occupational Exposure to Respirable Crystalline Silica, April 2002
NTP Twelfth Report on Carcinogens, 2011
IARC Monograph Volume100C, A Review of Human Carcinogens: Arsenic, Fibres, and Dusts (2011)
Hazardous Substances Data Bank (HSDB), 2014
Documentation of the TLV – Silica, Crystalline: α-Quartz and Cristobalite, American Conference of Governmental
Industrial Hygienists, 2006
SDS Date of Preparation/Revision: April 2014
Revision Summary: Conversion to US Hazcom 2012 format – GHS Classification added.
The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in
combination with any other material or in any process. The information set forth herein is based on technical data the Unimin
Corporation believes reliable. It is intended for use by persons having technical skill and at their own discretion and risk.
Since conditions of use are outside the control of Unimin Corporation, no warranties, expressed or implied, are made and no
liability is assumed in connection with any use of this information. Any use of these data and information must be
determined by the user to be in accordance with federal, state and local laws and regulations.