Loading...
HomeMy WebLinkAboutDERR-2025-002023Wexpro Company 333 South State Street Salt Lake City, Utah 84111 United States March 10, 2025 BY EMAIL Robin Keeler Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84114 RE: Wexpro Company, Horseshoe Bend Natural Gas Field, LP Federal 23 Pad: EPCRA Section 311 Notification Dear Robin Keeler: In accordance with Section 311 of the Emergency Planning and Community Right-to-Know Act (EPCRA), Wexpro Company is submitting safety data sheets (SDS) for storage of new chemicals at the LP Federal 23 Natural Gas Production Pad in quantities greater than the threshold planning quantity. The pad is located at the following GPS coordinates: (40.192635°, -109.514544°). The materials referenced below will be included in the facility’s 2025 Tier II chemical inventory report submitted by March 1, 2026. The Emergency Coordinator for the Horseshoe Bend natural gas field located in Uintah County, Utah is Chet Deru, who can be contacted at (307)-352-7950 or chet.deru@dominionenergy.com Chemical CAS # EHS Storage Locations Amount Onsite Dyed and Clear No. 2 Diesel Fuel 68476-34-6 No 7,500-gal tanker trailer and 16,000-gal bulk storage tank 747,784 lbs Silica Sand – 100 mesh and 30/50 mesh 14808-60-7 No 24-ton sand trailers 944,513 lbs Wexpro Company 333 South State Street Salt Lake City, Utah 84111 United States Utah Department of Environmental Quality March 10, 2025 Page 2 If you have any questions or require additional information, please contact Jace Capraro at (801) 598-8394 or john.capraro@enbridge.com Sincerely, Adam Plonsky, Environmental Compliance Manager cc: BY EMAIL Utah Department of Environmental Quality Mr. Tom Daniels; tdaniels@utah.gov Uintah County LEPC: Heidi Lundberg; hlundberg@uintah.utah.gov Uintah Fire District: Jeremy Raymond; Uintahfire@ubtanet.com Enclosures: Marathon No. 2 Diesel Fuel SDS Natural Silica Sand SDS SAFETY DATA SHEET SDS ID NO.: 0290MAR019 Revision date 10/01/2020 1. IDENTIFICATION Product Name Marathon Petroleum No. 2 Diesel Synonym No. 2 Ultra Low Sulfur Diesel (15 ppm Sulfur Max); No. 2 Low Sulfur Diesel (500 ppm Sulfur Max); ULSD No. 2; ULSD No. 2, dyed; ULSD No. 2 with Additives; ULSD No. 2 w/o Additives; ULSD No. 2 Winter Blends; No 2 MV15 CFI; Export Diesel; No. 2 Fuel Oil; Heating Oil; No. 2 Non-Road Locomotive Marine, Dyed; MGO; ULSD; LSD; NRLM; CARB Diesel Product code 0290MAR019 Chemical family Complex Hydrocarbon Substance Recommended use Fuel. Restrictions on use All others. SDS Information 1-419-421-3070 (M-F; 8-5 EST) 24 Hour Emergency Telephone CHEMTREC: 1-800-424-9300 (CCN# 13740) 2. HAZARD IDENTIFICATION OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Classification Acute toxicity - Inhalation (Dusts/Mists)Category 4 Skin corrosion/irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity (single exposure)Category 3 Specific target organ toxicity (repeated exposure)Category 2 Aspiration toxicity Category 1 Chronic aquatic toxicity Category 2 Hazards Not Otherwise Classified (HNOC) Static accumulating flammable liquid Label Elements Manufacturer, Importer, or Responsible Party Name and Address MARATHON PETROLEUM COMPANY LP 539 South Main Street Findlay, OH 45840 Flammable liquids Category 3 Danger FLAMMABLE LIQUID AND VAPOR May accumulate electrostatic charge and ignite or explode SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 1 of 11 May be fatal if swallowed and enters airways Harmful if inhaled Causes skin irritation May cause respiratory irritation _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools. Use explosion-proof electrical/ventilating/lighting/equipment Take precautionary measures against static discharge Do not breathe mist/vapors/spray Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Wash hands and any possibly exposed skin thoroughly after handling Avoid release to the environment Precautionary Statements - Response IF exposed or concerned: Get medical attention If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation occurs: Get medical attention Wash contaminated clothing before reuse If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor if you feel unwell If swallowed: Immediately call a poison center or doctor Do NOT induce vomiting In case of fire: Use water spray, fog or regular foam for extinction Collect spillage Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Keep cool Store locked up Precautionary Statements - Disposal Dispose of contents/container at an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS May contain up to 5% Biodiesel. Composition Information Name CAS Number % Concentration No. 2 Diesel Fuel 68476-34-6 50-100 Kerosine (petroleum)8008-20-6 0-50 May cause drowsiness or dizziness Suspected of causing cancer May cause damage to organs (thymus, liver, bone marrow) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Appearance Yellow to Red Liquid Physical State Liquid SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 2 of 11 Odor Hydrocarbon _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 Fuels, Diesel, C9-18-Alkane Branched and Linear 1159170-26-9 0-5 Alkanes, C10-C20 branched and linear 928771-01-1 0-5 Naphthalene 91-20-3 0.3-2.6 All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. 4. FIRST AID MEASURES First aid measures General advice In case of accident or if you feel unwell, seek medical advice immediately (show directions for use or safety data sheet if possible). Inhalation Remove to fresh air. If not breathing, utilize bag valve mask or other form of barrier device to institute rescue breathing. If breathing is difficult, ensure airway is clear, give oxygen and continue to monitor. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). Keep affected person warm and at rest. Get immediate medical attention. Skin contact Immediately wash exposed skin with plenty of soap and water while removing contaminated clothing and shoes. May be absorbed through the skin in harmful amounts. Get medical attention if irritation persists. Any injection injury from high pressure equipment should be evaluated immediately by a physician as potentially serious (See NOTES TO PHYSICIAN). Place contaminated clothing in closed container until cleaned or discarded. If clothing is to be laundered, inform the person performing the operation of contaminant's hazardous properties. Destroy contaminated, non-chemical resistant footwear. Eye contact Flush immediately with large amounts of water for at least 15 minutes. Gently remove contacts while flushing. Eyelids should be held away from the eyeball to ensure thorough rinsing. Gently remove contacts while flushing. Get medical attention if irritation persists. Ingestion Do not induce vomiting because of danger of aspirating liquid into lungs, causing serious damage and chemical pneumonitis. If spontaneous vomiting occurs, keep head below hips, or if patient is lying down, turn body and head to side to prevent aspiration and monitor for breathing difficulty. Never give anything by mouth to an unconscious person. Keep affected person warm and at rest. Get immediate medical attention. Most important signs and symptoms, both short-term and delayed with overexposure Adverse effects Irritating to the skin and mucous membranes. Symptoms may include redness, itching, and inflammation. May cause nausea, vomiting, diarrhea, and signs of nervous system depression: headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Aspiration hazard. May cause coughing, chest pains, shortness of breath, pulmonary edema and/or chemical pneumonitis. Prolonged or repeated exposure may cause adverse effects to the thymus, liver, and bone marrow. Repeated or prolonged skin contact may cause drying, reddening, itching and cracking. Indication of any immediate medical attention and special treatment needed Notes to physician INHALATION: This material (or a component) sensitizes the myocardium to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in individuals exposed to this material. Administration of sympathomimetic drugs should be avoided. SKIN: Leaks or accidents involving high-pressure equipment may inject a stream of material through the skin and initially produce an injury that may not appear serious. Only a small puncture wound may appear on the skin surface but, without proper treatment and depending on the nature, original pressure, volume, and location of the injected material, can compromise blood supply to an affected body part. Prompt surgical debridement of the wound may be necessary to prevent irreversible loss of function and/or the affected body part. High pressure injection injuries may be SERIOUS SURGICAL EMERGENCIES. SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 3 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 INGESTION: This material represents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media For small fires, Class B fire extinguishing media such as CO2, dry chemical, foam or water spray can be used. For large fires, water spray, fog or foam can be used. Firefighting should be attempted only by those who are adequately trained and equipped with proper protective equipment. Unsuitable extinguishing media Do not use straight water streams to avoid spreading fire. Specific hazards arising from the chemical This product has been determined to be a flammable liquid per the OSHA Hazard Communication Standard and should be handled accordingly. May accumulate electrostatic charge and ignite or explode. Vapors may travel along the ground or be moved by ventilation and ignited by many sources such as pilot lights, sparks, electric motors, static discharge, or other ignition sources at locations distant from material handling. Flashback can occur along vapor trail. For additional fire related information, see NFPA 30 or the Emergency Response Guidebook 128. Hazardous combustion products Smoke, carbon monoxide, and other products of incomplete combustion. Explosion data Sensitivity to mechanical impact: No. Sensitivity to static discharge:Yes. Special protective equipment and precautions for firefighters Firefighters should wear full protective clothing and positive-pressure self-contained breathing apparatus (SCBA) with a full face-piece, as appropriate. Avoid using straight water streams. Water spray and foam must be applied carefully to avoid frothing and from as far a distance as possible. Avoid excessive water spray application. Keep surrounding area cool with water spray from a distance and prevent further ignition of combustible material. Keep run-off water out of sewers and water sources. Additional firefighting tactics FIRES INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after the fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles: if this is impossible, withdraw from area and let fire burn. EVACUATION: Consider initial downwind evacuation for at least 1000 feet. If tank, rail car or tank truck is involved in a fire, ISOLATE for 5280 feet (1 mile) in all directions; also, consider initial evacuation of 5280 feet (1 mile) in all directions. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Keep public away. Isolate and evacuate area. Shut off source if safe to do so. Eliminate all ignition sources. All contaminated surfaces will be slippery. Protective equipment Use personal protection measures as recommended in Section 8. Emergency procedures Advise authorities and National Response Center (800-424-8802) if the product has entered a water course or sewer. Notify local health and pollution control agencies, if appropriate. Environmental precautions Avoid release to the environment. Avoid subsoil penetration. NFPA Health 1 Flammability 2 Instability 0 Special Hazard - SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 4 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 Methods and materials for containment Contain liquid with sand or soil. Prevent spilled material from entering storm drains, sewers, and open waterways. Methods and materials for cleaning up Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual liquids. Recover and return free product to proper containers. When recovering free liquids ensure all equipment is grounded and bonded. Use only non-sparking tools. 7. HANDLING AND STORAGE Safe handling precautions NEVER SIPHON THIS PRODUCT BY MOUTH. Use appropriate grounding and bonding practices. Static accumulating flammable liquid. Bonding and grounding may be insufficient to eliminate the hazard from static electricity. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Vapors may travel along the ground or be moved by ventilation. Flashback may occur along vapor trails. No smoking. Use only non-sparking tools. Avoid breathing fumes, gas, or vapors. Use only with adequate ventilation. Avoid repeated and prolonged skin contact. Use personal protection measures as recommended in Section 8. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap and water. Do not cut, drill, grind or weld on empty containers since explosive residues may remain. Refer to applicable EPA, OSHA, NFPA and consistent state and local requirements. Hydrocarbons are basically non-conductors of electricity and can become electrostatically charged during mixing, filtering, pumping at high flow rates or loading and transfer operations. If this charge reaches a sufficiently high level, sparks can form that may ignite the vapors of flammable liquids. Sudden release of hot organic chemical vapors or mists from process equipment operating under elevated temperature and pressure, or sudden ingress of air into vacuum equipment may result in ignition of vapors or mists without the presence of obvious ignition sources. Nozzle spouts must be kept in contact with the containers or tank during the entire filling operation. Portable containers should never be filled while in or on a motor vehicle or marine craft. Containers should be placed on the ground. Static electric discharge can ignite fuel vapors when filling non-grounded containers or vehicles on trailers. The nozzle spout must be kept in contact with the container before and during the entire filling operation. Use only approved containers. A buildup of static electricity can occur upon re-entry into a vehicle during fueling especially in cold or dry climate conditions. The charge is generated by the action of dissimilar fabrics (i.e., clothing and upholstery) rubbing across each other as a person enters/exits the vehicle. A flash fire can result from this discharge if sufficient flammable vapors are present. Therefore, do not get back in your vehicle while refueling. Cellular phones and other electronic devices may have the potential to emit electrical charges (sparks). Sparks in potentially explosive atmospheres (including fueling areas such as gas stations) could cause an explosion if sufficient flammable vapors are present. Therefore, turn off cellular phones and other electronic devices when working in potentially explosive atmospheres or keep devices inside your vehicle during refueling. High-pressure injection of any material through the skin is a serious medical emergency even though the small entrance wound at the injection site may not initially appear serious. These injection injuries can occur from high-pressure equipment such as paint spray or grease or guns, fuel injectors, or pinhole leaks in hoses or hydraulic lines and should all be considered serious. High pressure injection injuries may be SERIOUS SURGICAL EMERGENCIES (See First Aid Section 4). Storage conditions Store in properly closed containers that are appropriately labeled and in a cool, well-ventilated area. Do not store near an open flame, heat or other sources of ignition. Incompatible materials Strong oxidizing agents. SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 5 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Name ACGIH TLV OSHA PELS NIOSH IDLH No. 2 Diesel Fuel 68476-34-6 100 mg/m3 TWA Skin - potential significant contribution to overall exposure by the cutaneous route -- Kerosine (petroleum) 8008-20-6 200 mg/m3 TWA Skin - potential significant contribution to overall exposure by the cutaneous route -- Naphthalene 91-20-3 10 ppm TWA Skin - potential significant contribution to overall exposure by the cutaneous route TWA: 10 ppm TWA: 50 mg/m3 250 ppm Notes:No further information available. Engineering measures Local or general exhaust required in an enclosed area or with inadequate ventilation. Use mechanical ventilation equipment that is explosion-proof. Personal protective equipment Eye protection Use goggles or face-shield if the potential for splashing exists. Skin and body protection Wear neoprene, nitrile or PVA gloves to prevent skin contact. Glove suitability is based on workplace conditions and usage. Contact the glove manufacturer for specific advice on glove selection and breakthrough times. Respiratory protection Use a NIOSH approved organic vapor chemical cartridge or supplied air respirators when there is the potential for airborne exposures to exceed permissible exposure limits or if excessive vapors are generated. Observe respirator assigned protection factors (APFs) criteria cited in federal OSHA 29 CFR 1910.134. Self-contained breathing apparatus should be used for fire fighting. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Yellow to Red Liquid Physical State Liquid Color Yellow to Red Odor Hydrocarbon Odor Threshold No data available. Property Values (method) pH Not applicable Melting Point / Freezing Point No data available. Initial Boiling Point / Boiling Range 154-366 °C / 310-691 °F (ASTM D86) Flash Point 58-76 °C / 136-168 °F (ASTM D93) Evaporation Rate No data available. Flammability (solid, gas)Not applicable. Flammability Limit in Air (%): Upper Flammability Limit:No data available. Lower Flammability Limit:No data available. Explosion Limits No data available. Vapor Pressure No data available. Vapor Density No data available. Specific Gravity / Relative Density 0.82-0.86 SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 6 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 Water Solubility No data available. Partition Coefficient No data available. Autoignition Temperature No data available. Decomposition Temperature No data available. Kinematic Viscosity 1.7-4.1 cSt @ 40°C (ASTM D445) VOC Content (%)No data available. 10. STABILITY AND REACTIVITY Chemical stability The material is stable at 70°F (21°C ), 760 mmHg pressure. Possibility of hazardous reactions None under normal processing. Hazardous polymerization Will not occur. Conditions to avoid Excessive heat, sources of ignition, open flame. Incompatible materials Strong oxidizing agents. Hazardous decomposition products None known under normal conditions of use. However, use in an area without adequate ventilation may result in hazardous levels of carbon monoxide and carbon dioxide. 11. TOXICOLOGICAL INFORMATION Potential short-term adverse effects from overexposures Inhalation Harmful if inhaled. May cause irritation of respiratory tract. May cause drowsiness or dizziness. Breathing high concentrations of this material in a confined space or by intentional abuse can cause irregular heartbeats which can cause death. Eye contact Exposure to vapor or contact with liquid may cause mild eye irritation, including tearing, stinging, and redness. Skin contact Irritating to skin. Effects may become more serious with repeated or prolonged contact. May be absorbed through the skin in harmful amounts. Ingestion May be fatal if swallowed or vomited and enters airways. May cause irritation of the mouth, throat and gastrointestinal tract. Acute toxicological data Name Oral LD50 Dermal LD50 Inhalation LC50 No. 2 Diesel Fuel 68476-34-6 > 5000 mg/kg (Rat)> 2000 mg/kg (Rabbit)>1 - <5 mg/L (Rat) 4 h Kerosine (petroleum) 8008-20-6 > 5000 mg/kg (Rat)> 2000 mg/kg (Rabbit)> 5.28 mg/L (Rat) 4 h Fuels, Diesel, C9-18-Alkane Branched and Linear 1159170-26-9 -->1 - <5 mg/l (Rat) 4 h Alkanes, C10-C20 branched and linear 928771-01-1 -->1 - <5 mg/l (Rat) 4 h Naphthalene 91-20-3 533 mg/kg (Mouse)> 2000 mg/kg (Rabbit)> 340 mg/m3 (Rat) 1 h Immediate and delayed effects as well as chronic effects from short and long-term exposure PETROLEUM MIDDLE DISTILLATES: Petroleum derived middle distillates have produced skin tumors in mice after repeated and prolonged skin contact. Additional studies indicated prolonged skin irritation contributes to tumor development. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and weight, and increased fetal resorptions at doses Reactivity The product is non-reactive under normal conditions. SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 7 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 toxic to the mother. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. Repeated dermal application of petroleum gas oils resulted in decreased liver, thymus, and spleen weights, and altered bone marrow function. Microscopic alterations included liver hypertrophy and necrosis, decreased hematopoiesis and lymphocyte depletion. Altered mental state, drowsiness, peripheral motor neuropathy, irreversible brain damage (so-called Petrol Sniffer's Encephalopathy), delirium, seizures, and sudden death have been reported from repeated overexposure to some hydrocarbon solvents, naphthas, and gasoline. NAPHTHALENE: Excessive exposure to naphthalene may cause nausea, vomiting, diarrhea, blood in the urine, and a yellow color to the skin. Lifetime inhalation exposure of laboratory rodents to naphthalene resulted in cancers of the respiratory tract in male and female rats. A small increase in cancer of the lung was observed in female mice, but no evidence of lung cancer was observed in male mice. Long-term exposure to excessive airborne naphthalene concentrations may result in destruction of red blood cells, a condition referred to as hemolytic anemia. DIESEL EXHAUST: The combustion of diesel fuels produces gases including carbon monoxide, carbon dioxide, oxides of nitrogen and/or sulfur, and hydrocarbons that can be irritating and hazardous with overexposure. Long-term occupational overexposure to diesel exhaust and diesel exhaust particulate matter has been associated with an increased risk of respiratory disease, including lung cancer, and is characterized as a “known human carcinogen” by the International Agency for Research on Cancer (IARC), as “a reasonably anticipated human carcinogen” by the National Toxicology Program, and as “likely to be carcinogenic to humans” by the EPA, based upon animal and occupational exposure studies. However, uncertainty exists with these classifications because of deficiencies in the supporting occupational exposure/epidemiology studies, including reliable exposure estimates. Lifetime animal inhalation studies with pulmonary overloading exposure concentrations of diesel exhaust emissions have produced tumors and other adverse health effects. However, in more recent long-term animal inhalation studies of diesel exhaust emissions, no increase in tumor incidence and in fact a substantial reduction in adverse health effects along with significant reductions in the levels of hazardous material emissions were observed and are associated with fuel composition alterations coupled with new technology diesel engines. Adverse effects related to the physical, chemical and toxicological characteristics Signs and symptoms Irritating to the skin and mucous membranes. Symptoms may include redness, itching, and inflammation. May cause nausea, vomiting, diarrhea, and signs of nervous system depression: headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Aspiration hazard. May cause coughing, chest pains, shortness of breath, pulmonary edema and/or chemical pneumonitis. Repeated or prolonged skin contact may cause drying, reddening, itching and cracking. Prolonged or repeated exposure may cause damage to organs. Acute toxicity Harmful if inhaled. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation None known. Sensitization None known. Mutagenic effects None known. Carcinogenicity Suspected of causing cancer. Name ACGIH (Class) IARC (Class) NTP OSHA No. 2 Diesel Fuel 68476-34-6 Confirmed animal carcinogen (A3) Not Classifiable (3)Not Listed Not Listed Kerosine (petroleum) 8008-20-6 Confirmed animal carcinogen (A3) Not Classifiable (3)Not Listed Not Listed Naphthalene 91-20-3 Confirmed animal carcinogen (A3) Possible human carcinogen (2B) Reasonably anticipated to be a human carcinogen Not Listed Reproductive toxicity None known. Specific Target Organ Toxicity (STOT) - single exposure May cause respiratory irritation. May cause drowsiness or dizziness. Specific Target Organ Toxicity May cause damage to organs (thymus, liver, bone marrow) through prolonged or repeated SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 8 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 (STOT) - repeated exposure exposure. Aspiration hazard May be fatal if swallowed or vomited and enters airways. 12. ECOLOGICAL INFORMATION Ecotoxicity This product should be considered toxic to aquatic organisms, with the potential to cause long lasting adverse effects in the aquatic environment. Name Fish Crustacea Algae/aquatic plants No. 2 Diesel Fuel 68476-34-6 96-hr LC50 = 35 mg/l Fathead minnow (flow-through) 48-hr EL50 = 6.4 mg/l Daphnia magna - Kerosine (petroleum) 8008-20-6 96-hr LL50 = 18-25 mg/l Fish 48-hr EL50 = 1.4-21 mg/l Invertebrates 72-hr EL50 = 5.0-11 mg/l Algae Naphthalene 91-20-3 96-hr LC50 = 0.91-2.82 mg/l Rainbow trout (static) 96-hr LC50 = 1.99 mg/l Fathead minnow (static) 48-hr LC50 = 1.6 mg/l Daphnia magna - Persistence and degradability Expected to be inherently biodegradable. Bioaccumulation Has the potential to bioaccumulate. Mobility in soil May partition into air, soil and water. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Description of waste residues This material may be a flammable liquid waste. Safe handling of wastes Handle in accordance with applicable local, state, and federal regulations. Use personal protection measures as required. Use appropriate grounding and bonding practices. Use only non-sparking tools. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. No smoking. Disposal of wastes / methods of disposal The user is responsible for determining if any discarded material is a hazardous waste (40 CFR 262.11). Dispose of in accordance with federal, state and local regulations. Contaminated packaging disposal Empty containers should be completely drained and then discarded or recycled, if possible. Do not cut, drill, grind or weld on empty containers since explosive residues may be present. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT UN/Identification No:NA 1993 UN Proper Shipping Name:Diesel Fuel Transport Hazard Class(es):3 Packing Group:III IATA UN/Identification No:UN 1202 UN Proper Shipping Name:Diesel Fuel Transport Hazard Class(es):3 Packing Group:III ERG code:3L IMDG UN/Identification No:UN 1202 SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 9 of 11 _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 UN Proper Shipping Name:Diesel Fuel Transport Hazard Class(es):3 Packing Group:III EmS No:F-E, S-E Marine Pollutant:Yes Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable 15. REGULATORY INFORMATION Regulatory Information US TSCA Chemical Inventory This product and/or its components are listed on the TSCA Chemical Inventory or are exempt. Canada DSL/NDSL Inventory This product and/or its components are listed either on the Domestic Substances List (DSL) or are exempt. EPA Superfund Amendment & Reauthorization Act (SARA) SARA Section 302 This product does not contain any component(s) included on EPA's Extremely Hazardous Substance (EHS) List above the de minimis threshold. SARA Section 304 This product may contain component(s) identified either as an EHS or a CERCLA Hazardous substance which in case of a spill or release may be subject to SARA reporting requirements: Name Hazardous Substances RQs Naphthalene 91-20-3 100 lb 45.4 kg SARA Section 311/312 The following EPA hazard categories apply to this product: Flammable Hazard Not Otherwise Classified (HNOC)-Physical Acute toxicity Skin corrosion or irritation Carcinogenicity Specific target organ toxicity Aspiration hazard SARA Section 313 This product may contain component(s), which if in exceedance of the de minimus threshold, may be subject to the reporting requirements of SARA Title III Section 313 Toxic Release Reporting (Form R). Name CERCLA/SARA 313 Emission reporting Naphthalene 91-20-3 0.1 % de minimis concentration U.S. State Regulations California Proposition 65 This product can expose you to chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm. Name California Proposition 65 No. 2 Diesel Fuel 68476-34-6 Engine exhaust, Carcinogen, initial date 10/01/90 Naphthalene 91-20-3 Carcinogen, initial date 04/19/02 SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 10 of 11 For more information, go to www.P65Warnings.ca.gov. _____________________________________________________________________________________________ 0290MAR019 Marathon Petroleum No. 2 Diesel Revision date 10/01/2020 State Right-To-Know Regulations The following component(s) of this material are identified on the regulatory lists below: Name New Jersey Right-To-Know Pennsylvania Right-To-Know Massachusetts Right-To Know No. 2 Diesel Fuel 68476-34-6 Listed Listed Not Listed Kerosine (petroleum) 8008-20-6 Listed Listed Listed Naphthalene 91-20-3 Listed Listed Listed 16. OTHER INFORMATION Prepared by Toxicology & Product Safety NFPA Revision Notes Revision date 10/01/2020 Previous publish date 06/01/2016 Revised sections The following sections (§) have been updated: 3. COMPOSITION/INFORMATION ON INGREDIENTS 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 14. TRANSPORT INFORMATION 15. REGULATORY INFORMATION Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is intended as guidance for safe handling, use, processing, storage, transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Diesel Page 11 of 11 SAFETY DATA SHEET SDS No: 011-U-GHS 011-u-silica-ghs.doc Page 1 of 8 Date Prepared: April 2015 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: Crystalline Silica in the form of Quartz – various grades Synonyms: Quartz, Crystalline Silica, Silicon Dioxide Relevant Identified Uses of the Substance or Mixture and Uses Advised Against: Product Use: Various commercial and industrial uses Manufacturer: UNIMIN CORPORATION Emergency Telephone Number 258 Elm Street (203) 966-8880 New Canaan, CT 06840 Telephone Number for Information (203) 966-8880 SDS Date of Preparation/Revision: April 2014 SECTION 2: HAZARDS IDENTIFICATION GHS/ Hazcom 2012 Classification: Physical: Health: Environmental Not Hazardous Carcinogen Category 1A Specific Target Organ Toxicity (Repeated Exposure) Category 1 Not Hazardous GHS/Hazcom 2012 Label: DANGER Statements of Hazard Prevention May cause cancer by inhalation. Causes damage to lungs through prolonged or repeated exposure by inhalation Response: If exposed or concerned: Get medical advice. Disposal: Dispose of contents/containers in accordance with local regulation. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust. Do not eat, drink or smoke when using this product. Wear protective gloves and safety glasses or goggles. In case of inadequate ventilation wear respiratory protection. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS CAS# Component Percentage 14808-60-7 Crystalline Silica in the form of Quartz 87 - 99.9% SECTION 4: FIRST AID MEASURES Gross Inhalation: Remove victim to fresh air. If breathing has stopped, perform artificial respiration. If breathing is difficult have qualified personnel administer oxygen. Get prompt medical attention. SDS No: 011-U-GHS Page 2 of 8 Date Prepared: April 2015 Skin Contact: No first aid should be needed since dermal contact with this product does not affect the skin. Wash exposed skin with soap and water before breaks and at the end of the shift. Eye Contact: Flush the eyes immediately with large amounts of running water, lifting the upper and lower lids occasionally. If irritation persists or for imbedded foreign body, get immediate medical attention. Ingestion: If large amounts are swallowed, get immediate medical attention. Most Important Symptoms and Effects, Both Acute and Delayed: May cause eye irritation with redness and tearing. Exposure to dust may cause mucous membrane and respiratory irritation, cough, sore throat, nasal congestion, sneezing and shortness of breath. However, there may be no immediate signs or symptoms of exposure to hazardous concentrations of respirable crystalline silica (quartz). Indication of immediate medical attention and Special Treatment Needed: None required. SECTION 5: FIREFIGHTING MEASURES Suitable Extinguishing Media: This product will not burn but is compatible with all extinguishing media. Use any media that is appropriate for the surrounding fire. Specific Hazards Arising from the Chemical: Unusual Fire and Explosion Hazards: Not flammable or combustible. Dry powders may accumulate static charge in handling which can be a source of ignition for flammable atmospheres. Hazardous Combustion Products: None. Special Protective Equipment and Precautions for Fire-Fighters: None required with respect to this product. Firefighters should always wear self-contained breathing apparatus for fires indoors or in confined areas. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective equipment. Environmental Precautions: Report spills and releases as required to appropriate authorities. Methods and Material for Containment/Cleanup: If uncontaminated, collect using dustless method (HEPA vacuum or wet method) and place in appropriate container for use. If contaminated: a) use appropriate method for the nature of contamination, and b) consider possible toxic or fire hazards associated with the contaminating substances. Collect for appropriate disposal. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling: Do not breathe dust. Do not rely on your sight to determine if dust is in the air. Silica may be in the air without a visible dust cloud. Use normal precautions against bag breakage or spills of bulk material. Avoid creation of respirable dust. Use good housekeeping in storage and use areas to prevent accumulation of dust in work area. To reduce the risk of developing silicosis, lung cancer and other adverse health effects, the ACGIH recommends that the industrial hygienist use every means available to keep exposures below the recommended TLV. NIOSH recommends reducing airborne exposure levels as low as possible below NIOSH’s recommended exposure limit, substituting less hazardous materials when feasible, using appropriate respiratory protection when source controls cannot keep exposures below the recommended limit and making medical examinations available to exposed workers. Use adequate ventilation and dust collection. To minimize exposure, wear a respirator approved for silica dust when using, handling, storing or disposing of this product or bag. Refer to the most recent government and local regulations when selecting a respirator. Maintain, clean and fit test respirators in accordance with the most recent government and local SDS No: 011-U-GHS Page 3 of 8 Date Prepared: April 2015 regulations. Maintain and test ventilation and dust collection equipment. Launder clothing that has become dusty. Empty containers (bags, bulk containers, storage tanks, etc.) retain silica residue and must be handled in accordance with the provisions of this Material Safety Data Sheet. WARN and TRAIN employees in accordance with state and federal regulations. WARN YOUR EMPLOYEES (AND YOUR CUSTOMERS AND USERS IN CASE OF RESALE) BY POSTING, AND OTHER MEANS, OF THE HAZARDS AND OSHA AND ANY OTHER APPLICABLE REGULATORY PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT OSHA PRECAUTIONS. Dust can accumulate electrostatic charges due to friction from transfer and mixing operations and cause an electrical spark (ignition source) which can ignite flammable liquids and atmospheres. Provide adequate precautions when adding this product to flammable and combustible mixtures like paints and coating, such as electrical grounding and bonding, inert atmosphere or non-sparking tools. However, bonding and grounds may not eliminate the hazard for static accumulation. See also American Society for Testing and Materials (ASTM) Standard Practice E1132-99a, “Standard Practice for Health Requirements Relating to Occupational Exposure to Respirable Crystalline Silica”. Additional information on silica hazards and precautionary measures can be found at the following websites: NIOSH Joint Campaign on Silicosis Prevention http://www.cdc.gov/niosh/topics/silica/default.html OSHA Crystalline Silica Website http://www.osha.gov/dsg/topics/silicacrystalline/index.html MSHA Silicosis Prevention Website http://www.msha.gov/S&HINFO/SILICO/SILICO.HTM NIOSH Hazard Review – Health Effects of Occupational Exposure to Respirable Crystalline Silica Website http://www.cdc.gov/niosh/docs/2002-129/ Conditions for Safe Storage, Including any Incompatibilities: Store in a dry location. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: Definitions: NIOSH means National Institute for Occupational Safety and Health. REL means the NIOSH Recommended Exposure Limit. TLV means American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value. TWA means time-weighted average. OSHA PEL and MSHA Exposure Limit for Crystalline Silica, Quartz 10 mg/m3 (Respirable measured as an 8-hour TWA) % Silica + 2 TLV- 0.025 mg/m3 8-hour TWA (respirable fraction) In 2006 the ACGIH lowered the TLV for Silica, Crystalline: α-Quartz and Cristobalite to 0.025 mg/m3 stating in the Documentation of the TLV “Because the time between exposure and signs of fibrosis is characteristically very long, as much as 30 to 40 years, the margin of safety for exposure to crystalline silica at the proposed TLV-TWA is not known precisely. Given the observed association between silicosis and lung cancer, it is recommended that air concentrations be maintained as far below the proposed TLV as prudent practices permit. The recommended TLV-TWA of 0.025 mg/m3, respirable particulate mass, is intended to prevent pulmonary fibrosis that may be a risk factor for lung cancer. An A2, Suspected Human Carcinogen, notation is based on the demonstrated association between lung cancer and the presence of silicosis.” The documentation further states “A lack of toxicological and industrial hygiene data does not permit the recommendation of a TLV-STEL. However, it should be noted that high exposures of short duration to freshly fragmented crystalline particles do produce an acute and rapidly progressive form of silicosis. The reader is encouraged to review the section on Excursion Limits in the “Introduction to the Chemical Substances” of the current TLVs and BEIs book for guidance and control of excursions above the TLV-TWA, even when the 8-hour TWA is within the recommended limits” SDS No: 011-U-GHS Page 4 of 8 Date Prepared: April 2015 NIOSH has issued its REL of 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour working day, 40 hours per week. NIOSH has recommended that OSHA and MSHA adopt the NIOSH REL as the OSHA PEL and the MSHA Exposure Limit. The 1974 NIOSH Criteria for a Recommended Standard for Occupational Exposure to Crystalline Silica should be consulted for more detailed information. Additionally, NIOSH, In a publication entitled NIOSH Hazard Review Health Effects of Occupational Exposure to Respirable Silica (April 2002), NIOSH stated “…that workers have a significant risk of developing chronic silicosis when they are exposed to respirable crystalline silica over a working lifetime at the current Occupational Safety and Health Administration (OSHA) permissible exposure limit (PEL), the Mine Safety and Health Administration (MSHA) PEL, or the National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit (REL). …Current sampling and analytical methods used to evaluate occupational exposure to respirable crystalline silica do not meet the accuracy criterion needed to quantify exposures at concentrations below the NIOSH REL of 0.05 mg/m3 as a time-weighted average (TWA) for up to a 10-hr workday during a 40-hr workweek. Until improved sampling and analytical methods are developed for respirable crystalline silica, NIOSH will continue to recommend an exposure limit of 0.05 mg/m3 to reduce the risk of developing silicosis, lung cancer, and other adverse health effects. NIOSH also recommends minimizing the risk of illness that remains for workers exposed at the REL by substituting less hazardous materials for crystalline silica when feasible, by using appropriate respiratory protection when source controls cannot keep exposures below the NIOSH REL, and by making medical examinations available to exposed workers.” Crystalline silica exists in several forms, the most common of which are quartz (i.e. this product), trydimite and cristobalite, with quartz being the most common form found in nature. If quartz is heated to more than 870°C, it can change form to trydimite and if quartz is heated to more than 1450°C, it can change form to cristobalite. Appropriate Engineering Controls: Use local exhaust as required to maintain exposures as far as possible below applicable occupational exposure limits. See also ACGIH "Industrial Ventilation - A Manual for Recommended Practice" (current edition). Control of exposure to dust must be accomplished as far as feasible by accepted engineering control measures (for example, enclosure or confinement of the operation, general or local exhaust ventilation and substitution of less toxic materials). Personal Protective Equipment: Respiratory Protection: When effective engineering controls are not feasible, or while they are being implemented, appropriate respiratory protection must be used. Use appropriate respiratory protection for respirable particulates based on consideration of airborne workplace concentrations and duration of exposure arising from intended end use. Refer to the most recent government and local standards. Gloves: Protective gloves recommended. Eye Protection: Safety glasses or goggles recommended. Other Protective Equipment/Clothing: As appropriate for the work environment. Dusty clothing should be laundered before reuse. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Form: Solid Appearance: White powder Viscosity: Not applicable Odor: None pH: Not applicable Odor Threshold: Not applicable Boiling Point/Range: 4046°F / 2230°C Vapor Density: Not applicable Melting point/freezing point: 2930°F / 1610°C Evaporation Rate: Not applicable Flammability (solid, gas): Fully oxidized, will not burn Partition coefficient (n- octanol/water): Not applicable Decomposition Temperature: Not applicable Vapor Pressure: Not applicable Flash Point: Not applicable Relative Density: 2.65 Lower Explosion Limit: Not applicable Solubilities: Insoluble in water SDS No: 011-U-GHS Page 5 of 8 Date Prepared: April 2015 Upper Explosion Limit: Not applicable Autoignition Temperature: Will not burn SECTION 10: STABILITY AND REACTIVITY Reactivity: This product is not reactive under normal conditions of storage and use. Chemical Stability: This product is stable at normal temperatures. Possibility of Hazardous Reactions: None known Conditions to Avoid: None known. Incompatible Materials: Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, etc. Hazardous Decomposition Products: Silica will dissolve in hydrofluoric acid producing a corrosive gas, silicon tetrafluoride. SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects Potential Health Effects: Inhalation: Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have serious chronic health effects (see below Repeat Dose Toxicity.) Skin Contact: No adverse effects expected. Eye Contact: Contact may cause mechanical irritation and possible injury. Ingestion: No adverse effects expected for normal, incidental ingestion. Chronic Health Effects: See Repeat Dose Toxicity below with respect to silicosis, cancer status and other data with possible relevance to human health. Signs and Symptoms of Exposure: Exposure to dust may cause mucous membrane and respiratory irritation, cough, sore throat, nasal congestion, sneezing and shortness of breath. However, there may be no immediate signs or symptoms of exposure to hazardous concentrations of respirable crystalline silica (quartz). See Repeat Dose Toxicity below for symptoms of silicosis. The absence of symptoms is not necessarily indicative of safe conditions. Acute Toxicity Values: Silica: LD50 oral rat >22,500 mg/kg. Skin Sensitization: Not a skin sensitizer in animals or humans. Repeated Dose Toxicity: Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling and sometimes fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop mycobacterial infections (tuberculous and non-tuberculous) and fungal infections. Inhalation of air with a very high concentration of respirable silica dust can cause the most serious forms of silicosis in a matter of months or a few years. Some epidemiologic studies have concluded that there is significant risk of developing silicosis even at airborne exposure levels that are equal to the recommended NIOSH REL, and ACGIH TLV. SDS No: 011-U-GHS Page 6 of 8 Date Prepared: April 2015 Other Data with Possible Relevance to Human Health: There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) rheumatoid arthritis, systemic lupus, erythematosus, sarcoidosis, chronic bronchitis, chronic obstructive pulmonary disease (COPD), emphysema, chronic kidney disease and end-stage renal disease. For further information consult "Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine, Volume 155, pages 761-768, 1997, and see also NIOSH Hazard Review – Health Effects of Occupational Exposure to Respirable Crystalline Silica, April 2002 (see Section 7 for NIOSH Hazard Review Website). Carcinogenicity: The International Agency for Research on Cancer has determined that crystalline silica is carcinogenic to humans (Group 1 - carcinogenic to humans). Refer to IARC Monograph 100C, A Review of Human Carcinogens: Arsenic, Fibres, and Dusts (published in 2011) in conjunction with the use of these materials. The National Toxicology Program classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the Twelfth Report on Carcinogens (2011). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2). Developmental / Reproductive Toxicity: No specific data is available, however, there is no evidence that silica exposure has any effect on reproduction. Genetic Toxicity: No specific data is available, however, there is no evidence that silica is a germ cell mutagen. SECTION 12: ECOLOGICAL INFORMATION Toxicity: Practically non-toxic to aquatic organisms. Silica: LC50 carp >10,000 mg/L/72 hr. Persistence and Degradability: Silica is not degradable. Bioaccumulative Potential: Not expected to bioaccumulate. Mobility in Soil: Not applicable. Results of PBT and vPvB Assessment: None required. Other Adverse Effects: None known SECTION 13: DISPOSAL CONSIDERATIONS Waste Treatment Methods: If uncontaminated, dispose as an inert, non-metallic mineral. If contaminated, dispose in accordance with all applicable local, state/provincial and national/ federal regulations in light of the contamination present. Local regulations may be more stringent than regional and national requirements. It is the responsibility of the waste generator to determine the toxicity and physical characteristics of the material to determine the proper waste identification and disposal in compliance with applicable regulations. SECTION 14: TRANSPORT INFORMATION Not regulated for transportation under IATA/ICAO, IMDG, US DOT, EU ADR, or Canadian TDG Regulations. Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code: None SECTION 15: REGULATORY INFORMATION SDS No: 011-U-GHS Page 7 of 8 Date Prepared: April 2015 SARA 311/312: Hazard Categories for SARA Section 311/312 Reporting: Chronic Health SARA 313 This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under the SARA Section 313 (40 CFR 372): None CERCLA Section 103 Reportable Quantity: None California Proposition 65: This product contains crystalline silica (respirable) which is known to the State of California to cause cancer. Toxic Substances Control Act: All of the components of this product are listed on the EPA TSCA Inventory or exempt from premanufacture notification requirements. EU Inventory: All of the components of this product are listed on the EINECS inventory or exempt from notification requirements. EU REACH Status: This substance is exempt from REACH registration. Canadian Environmental Protection Act: All the components of this product are listed on the Canadian Domestic Substances List or exempt from notification requirements. Canadian WHMIS Classification: Class D, Division 2, Subdivision A (Very Toxic Material causing other Toxic Effects) This SDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the SDS contains all of the information required by the CPR. Japan EITI: All of the components of this product are existing chemical substances as defined in the Chemical Substance Control Law. Australian Inventory of Chemical Substances: All of the components of this product are listed on the AICS inventory or exempt from notification requirements. Australian National Occupational Health & Safety Commission Status: Hazardous according to the criteria of Australian National Occupational Health & Safety Commission -Harmful (Xn) R48/20 Harmful: Danger of serious damage to health by prolonged exposure by inhalation. Korea: All of the components of this product are listed on the KECL inventory or exempt from notification requirements. Philippines: All of the components of this product are listed on the PICCS inventory or exempt from notification requirements. New Zealand: All of the components of this product are listed on the HSNO inventory or exempt from notification requirements. China: All of the components of this product are listed on the IECSC inventory or exempt from notification requirements. Taiwan: All of the components of this product are listed on the CSNN inventory or exempt from notification requirements. 16: OTHER INFORMATION NFPA Hazard Rating: Health: 1 Fire: 0 Reactivity: 0 HMIS Hazard Rating: Health: * Fire: 0 Reactivity: 0 SDS No: 011-U-GHS Page 8 of 8 Date Prepared: April 2015 * Warning - Chronic health effect possible - inhalation of silica dust may cause lung injury/disease (silicosis). Take appropriate measures to avoid breathing dust. See Section 3. References: Registry for Toxic Effects of Chemical Substances (RTECS), 2014 Patty's Industrial Hygiene and Toxicology NIOSH Hazard Review – Health Effects of Occupational Exposure to Respirable Crystalline Silica, April 2002 NTP Twelfth Report on Carcinogens, 2011 IARC Monograph Volume100C, A Review of Human Carcinogens: Arsenic, Fibres, and Dusts (2011) Hazardous Substances Data Bank (HSDB), 2014 Documentation of the TLV – Silica, Crystalline: α-Quartz and Cristobalite, American Conference of Governmental Industrial Hygienists, 2006 SDS Date of Preparation/Revision: April 2014 Revision Summary: Conversion to US Hazcom 2012 format – GHS Classification added. The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. The information set forth herein is based on technical data the Unimin Corporation believes reliable. It is intended for use by persons having technical skill and at their own discretion and risk. Since conditions of use are outside the control of Unimin Corporation, no warranties, expressed or implied, are made and no liability is assumed in connection with any use of this information. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws and regulations.