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HomeMy WebLinkAboutDERR-2025-002020Robin Keeler <rkeeler@utah.gov> UPDATED SAFETY DATA SHEETS - SOUTH DAVIS SEWER DISTRICT 1 message Lanese Hendrickson <lhendrickson@sdsdut.gov>Fri, Feb 28, 2025 at 3:48 PM To: "eqderrtier2@utah.gov" <eqderrtier2@utah.gov> This afternoon, the South Davis Sewer District submitted Tier II reports for the facilities owned and operated by the District via the Tier2 Submission Portal. These reports were also submitted to the LEPC and local fire department. Attached please find safety data sheets for chemicals first included for report year 2024. Please let me know if you have any questions. Thank you, Lanese B. Hendrickson, PE Assistant General Manager South Davis Sewer District PO Box 140111 Salt Lake City UT 84114-0111 801.295.3469 lhendrickson@sdsdut.gov **NOTICE FROM THE SOUTH DAVIS SEWER DISTRICT: OUR EMAIL ADDRESSES HAVECHANGED! PLEASE MAKE NOTE OF THE NEW EMAIL ADDRESS FOR THIS SENDER ANDUPDATE YOUR RECORDS ACCORDINGLY!** 6 attachments KEMIRA PIX 311_Iron (III) Chloride Solution.pdf 346K PHOSPHORIC ACID 75% BULK EN-1_GHS_NA_Univar.PDF 240K VEL Acrux AC_VEL International.pdf 209K Delo 400 XLE SB SAE 15W-40.pdf 254K Delo 400 XSP SAE 5W-40.pdf 135K SPX Hydraulic 32.pdf 336K SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 1 / 20 (c) Kemira OYJ. All rights reserved. SECTION 1. IDENTIFICATION Product name : KEMIRA PIX-311 Manufacturer or supplier's details Company name of supplier : Kemira Water Solutions, Inc. Address : 200 Galleria Parkway, Suite 1500 Atlanta GA 30339-5979 Telephone : (770) 436-1542 Telefax : (770) 436-3432 E-mail address of person responsible for the SDS : us-customerservice@kemira.com Emergency telephone num- ber : CHEMTREC (24 Hours): 1-800-424-9300 Recommended use of the chemical and restrictions on use Recommended use : Water treatment chemical Restrictions on use : Do not use for other purposes than the identified uses. SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Corrosive to metals : Category 1 Acute toxicity (Oral) : Category 4 Skin irritation : Category 2 Serious eye damage : Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H290 May be corrosive to metals. H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. Precautionary statements : Prevention: P234 Keep only in original container. P264 Wash face, hands and any exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 2 / 20 (c) Kemira OYJ. All rights reserved. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of water. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P362 Take off contaminated clothing and wash before reuse. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P390 Absorb spillage to prevent material damage. Storage: P406 Store in corrosive resistant container with a resistant inner liner. Disposal: P501 Dispose of contents/container as special waste in compli- ance with local and national regulations. Other hazards Heating above the decomposition temperature can cause formation of hydrogen chloride. May lower the pH of water and thus be harmful to aquatic organisms. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Iron (III) chloride solution Components Chemical name CAS-No. Concentration (% w/w) Iron trichloride 7705-08-0 > 35 - < 45 Hydrochloric acid 7647-01-0 <= 2 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Show this safety data sheet to the doctor in attendance. If inhaled : Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. If symptoms persist, seek medical advice. In case of skin contact : Take off all contaminated clothing immediately. Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 3 / 20 (c) Kemira OYJ. All rights reserved. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Rinse immediately with plenty of water, also under the eyelids. Prevent rinsing water from flowing into the other eye. Remove contact lenses, if present and easy to do. Continue rinsing. Continue rinsing eyes during transport to hospital. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Get medical advice/ attention if you feel unwell. Most important symptoms and effects, both acute and delayed : Harmful if swallowed. Causes serious eye damage. Causes skin irritation. Effects are immediate or delayed. Symptoms may include: Central nervous system depression Headache Nausea Dizziness Blistering Irritation Burn Pain Redness Rash Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing Notes to physician : All treatments should be based on observed signs and symp- toms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Not combustible. Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Unsuitable extinguishing media : No special requirements. Specific hazards during fire- fighting : Heating above the decomposition temperature can cause formation of hydrogen chloride. Further information : If possible remove containers / tanks from the dangerous ar- ea. Cool containers/tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : Exposure to decomposition products may be a hazard to health. In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 4 / 20 (c) Kemira OYJ. All rights reserved. Personal precautions, protec- tive equipment and emer- gency procedures : Keep unnecessary and unprotected personnel from entering the involved area. Ensure adequate ventilation. Wear respiratory protection. Use personal protective equipment. Wear suitable protective clothing, gloves and eye/face protec- tion. Environmental precautions : Do not allow uncontrolled discharge of product into the envi- ronment. Methods and materials for containment and cleaning up : Clean-up methods - small spillage Dilute residues with water and then neutralize with lime or limestone powder to a solid consistency. Shovel or sweep up. Must be disposed of in accordance with local and national regulations. Clean-up methods - large spillage Remove spill using a vacuum truck. Dilute residues with water and then neutralize with lime or limestone powder to a solid consistency. Shovel or sweep up remaining material. Must be disposed of in accordance with local and national regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. The work place and work methods shall be organized in such a way that direct contact with the product is prevented or min- imized. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Wear suitable gloves and eye/face protection. Keep away from incompatible materials. May be corrosive to metals. Bases Strong oxidizing agents Conditions for safe storage : Keep away from incompatible materials. Ensure adequate ventilation. For quality reasons: Keep at temperatures above 0 °C. Keep at temperatures below 30 °C. Materials to avoid : Metals Bases Strong acids Oxidizing agents SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 5 / 20 (c) Kemira OYJ. All rights reserved. Reducing agents Sulphides sulphites Packaging material : Suitable material: plastic (PE, PP, PVC), fiberglass-reinforced polyester, rubber-coated steel Unsuitable material: Avoid contact with unalloyed steel or galvanized surfaces., stainless steel (AISI 304), materials not resistant to acid, Copper, Aluminium, Iron, Zinc, brass, titani- um SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Iron trichloride 7705-08-0 TWA 1 mg/m3 (Iron) ACGIH TWA 1 mg/m3 (Iron) OSHA P0 TWA 1 mg/m3 (Iron) NIOSH REL Hydrochloric acid 7647-01-0 C 2 ppm ACGIH C 5 ppm 7 mg/m3 NIOSH REL C 5 ppm 7 mg/m3 OSHA Z-1 C 5 ppm 7 mg/m3 OSHA P0 Engineering measures : Ensure adequate ventilation. Personal protective equipment Respiratory protection : Respiratory protection is not required under normal handling conditions. Hand protection Remarks : Protective gloves and Chemical resistant gloves. Eye protection : Wear eye protection/ face protection. Tightly fitting safety goggles or face-shield. Skin and body protection : Wear protective clothing if necessary. Use rubber boots. face shield Protective measures : Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 6 / 20 (c) Kemira OYJ. All rights reserved. Colour : dark brown Odour : slightly acidic Odour Threshold : No data available pH : < 1 (68 °F / 20 °C) Concentration: 100 % Freezing point : -4 °F / -20 °C Melting point No data available Boiling point/boiling range : 212 - 228 °F / 100 - 109 °C Flash point : Not applicable inorganic compound Flammability (liquids) : Not flammable Upper explosion limit / Upper flammability limit : Not applicable Lower explosion limit / Lower flammability limit : Not applicable Vapour pressure : 23 hPa (68 °F / 20 °C) Relative vapour density : No data available Relative density : No data available Density : 1.38 - 1.50 g/cm3 (68 °F / 20 °C) Solubility(ies) Water solubility : miscible, At dilution to less than 1% of FeCl3, precipitation of iron hydroxide occurs. (68 °F / 20 °C) Partition coefficient: n- octanol/water : Not applicable inorganic compound Auto-ignition temperature : not auto-flammable Decomposition temperature : 572 °F / 300 °C Viscosity Viscosity, dynamic : 5 - 15 mPa.s (68 °F / 20 °C) Viscosity, kinematic : not determined Oxidizing properties : Not oxidizing Surface tension : No data available Particle characteristics SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 7 / 20 (c) Kemira OYJ. All rights reserved. Assessment : Not applicable SECTION 10. STABILITY AND REACTIVITY Reactivity : Corrosive to metals. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Contact with certain metals may form hydrogen gas, which in turn may form explosive mixtures of gases with air. Reacts with the following substances: Strong acids and strong bases Strong oxidizing agents Conditions to avoid : Avoid extreme temperatures. Do not freeze. Avoid storage at high temperatures. Incompatible materials : Metals Bases Strong acids Oxidizing agents Reducing agents Sulphides sulphites Hazardous decomposition products : Heating above the decomposition temperature can cause formation of hydrogen chloride. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Harmful if swallowed. Product: Acute oral toxicity : Acute toxicity estimate: approximately 1,000 - 1,700 mg/kg Remarks: Harmful if swallowed. Components: Iron trichloride: Acute oral toxicity : LD50 (Rat): 220 mg/kg Method: OECD Test Guideline 423 Remarks: Calculated as Fe Acute toxicity estimate: 500 mg/kg Acute inhalation toxicity : No observed adverse effect level: 1.1 mg/l Method: EPA OPP 81-3 Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Remarks: Read-across (Analogy) SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 8 / 20 (c) Kemira OYJ. All rights reserved. CAS-No. 7758-94-3 LD50 (Rat): > 881 mg/kg Method: OECD Test Guideline 402 Remarks: Calculated as Fe Hydrochloric acid: Acute inhalation toxicity : LC50 (Rat): 4701 ppm Exposure time: 30 min Test atmosphere: gas Remarks: gas LC50 (Rat): 8.3 mg/l Exposure time: 30 min Test atmosphere: aerosol Remarks: aerosol Acute dermal toxicity : Remarks: No data available Skin corrosion/irritation Causes skin irritation. Product: Remarks : Causes skin irritation. Components: Iron trichloride: Species : Rabbit Method : OECD Test Guideline 404 Result : irritating GLP : yes Test substance : ferrous sulfate heptahydrate Hydrochloric acid: Species : EPISKIN Human Skin Model Test Exposure time : 1 h Method : OECD Test Guideline 431 Result : Corrosive GLP : yes Serious eye damage/eye irritation Causes serious eye damage. Product: Remarks : Causes serious eye damage. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 9 / 20 (c) Kemira OYJ. All rights reserved. Components: Iron trichloride: Species : Rabbit Result : Causes serious eye damage. Method : OECD Test Guideline 405 GLP : yes Remarks : Read-across (Analogy) 7758-94-3 dry substance Hydrochloric acid: Species : Rabbit Result : Risk of serious damage to eyes. Method : OECD Test Guideline 405 Test substance : yes Remarks : 0,1 ml, conc. 10 % Respiratory or skin sensitisation Skin sensitisation Not classified due to lack of data. Respiratory sensitisation Not classified due to lack of data. Product: Remarks : contains Nickel dichloride May cause an allergic skin reaction. Components: Iron trichloride: Test Type : Local lymph node assay (LLNA) Species : Mouse Method : OECD Test Guideline 429 Result : Not sensitizing. Test substance : ferrous sulfate Hydrochloric acid: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Result : Not sensitizing. Germ cell mutagenicity Not classified due to lack of data. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 10 / 20 (c) Kemira OYJ. All rights reserved. Product: Genotoxicity in vitro : Remarks: Based on available data, the classification criteria are not met. Components: Iron trichloride: Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without Method: OECD Test Guideline 471 Result: negative Test substance: ferric chloride Hydrochloric acid: Genotoxicity in vitro : Test Type: In vitro mitotic recombination Test system: Saccharomyces cerevisiae Metabolic activation: with and without Result: negative Carcinogenicity Not classified due to lack of data. Product: Remarks : Based on available data, the classification criteria are not met. Components: Iron trichloride: Species : Rat Application Route : Oral Exposure time : 2 years NOAEL : > 0.5 % Test substance : ferric chloride Hydrochloric acid: Species : Rat Application Route : Inhalation : 15 mg/m³ Method : OECD Test Guideline 451 IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 11 / 20 (c) Kemira OYJ. All rights reserved. Reproductive toxicity Not classified due to lack of data. Product: Effects on fertility : Remarks: Based on available data, the classification criteria are not met. Components: Iron trichloride: Effects on fertility : Test Type: Reproductive effects Species: Rat Application Route: Oral General Toxicity - Parent: NOAEL: > 500 mg/kg body weight Method: OECD Test Guideline 422 Effects on foetal develop- ment : Species: Rat Application Route: Oral Teratogenicity: NOAEL: > 1,000 mg/kg body weight Method: OECD Test Guideline 422 Result: Did not show teratogenic effects in animal experi- ments. Hydrochloric acid: Effects on fertility : Remarks: No data available Effects on foetal develop- ment : Remarks: No data available STOT - single exposure Not classified due to lack of data. Product: Remarks : Based on available data, the classification criteria are not met. Components: Iron trichloride: Assessment : The substance or mixture is not classified as specific target organ toxicant, single exposure. Hydrochloric acid: Assessment : May cause respiratory irritation. STOT - repeated exposure Not classified due to lack of data. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 12 / 20 (c) Kemira OYJ. All rights reserved. Product: Remarks : Based on available data, the classification criteria are not met. Components: Iron trichloride: Assessment : The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Hydrochloric acid: Assessment : The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity Based on available data, the classification criteria are not met. Product: No aspiration toxicity classification Components: Iron trichloride: No aspiration toxicity classification Hydrochloric acid: No aspiration toxicity classification Experience with human exposure Product: Inhalation : Remarks: Effects are immediate and delayed. Inhalation may provoke the following symptoms: No symptoms known or expected. Remarks: Chronic Symptoms: None known. Skin contact : Remarks: Effects are immediate and delayed. Skin contact may provoke the following symptoms: Skin irritation skin rash Remarks: Chronic Symptoms: None known. Eye contact : Remarks: Effects are immediate and delayed. Corrosive to eyes and may cause severe damage including blindness. Remarks: Chronic Symptoms: None known. Ingestion : Remarks: Effects are immediate and delayed. Ingestion may provoke the following symptoms: Harmful by ingestion. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 13 / 20 (c) Kemira OYJ. All rights reserved. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Gastrointestinal discomfort Remarks: Chronic Symptoms: None known. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): >= 686 mg/l Exposure time: 48 h Test Type: Acute Fish toxicity Test substance: similar product Method: US EPA-821-R-02-012 Toxicity to daphnia and other aquatic invertebrates : LC50 (Ceriodaphnia dubia (Water flea)): >= 137 mg/l Exposure time: 48 h Test Type: Short-term (acute) aquatic hazard Test substance: similar product Method: US EPA-821-R-02-012 Components: Iron trichloride: Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 59 mg/l Exposure time: 96 h Remarks: hydrated substance NOEC (Lepomis macrochirus (Bluegill sunfish)): > 1 mg/l Exposure time: 96 h Remarks: hydrated substance Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 27 mg/l Exposure time: 48 h NOEC (Daphnia magna (Water flea)): > 1 mg/l Exposure time: 21 d Toxicity to algae/aquatic plants : EC50 (algae): 58 mg/l Exposure time: 15 d Test Type: rate of growth GLP: no Remarks: Test is not appropriate due to the flocculating char- acteristics of the product. The compound is considered to have no long term effec ts in aquatic systems due to the rapid formation of insoluble hy- droxides. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 14 / 20 (c) Kemira OYJ. All rights reserved. Toxicity to terrestrial organ- isms : Remarks: No data available Hydrochloric acid: Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 20.5 mg/l Exposure time: 96 h Test Type: semi-static test GLP: no Remarks: fresh water Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.45 mg/l Exposure time: 48 h Test Type: static test Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : EC50 (Chlorella vulgaris (Fresh water algae)): 0.73 mg/l Test Type: static test Method: OECD Test Guideline 201 Remarks: Fresh water Persistence and degradability Product: Biodegradability : Remarks: The methods for determining the biological degra- dability are not applicable to inorganic substances. Components: Iron trichloride: Biodegradability : Remarks: The methods for determining the biological degra- dability are not applicable to inorganic substances. Hydrochloric acid: Biodegradability : Remarks: The methods for determining the biological degra- dability are not applicable to inorganic substances. Bioaccumulative potential Components: Iron trichloride: Partition coefficient: n- octanol/water : Remarks: Not applicable inorganic compound Hydrochloric acid: Partition coefficient: n- octanol/water : Remarks: Not applicable inorganic compound SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 15 / 20 (c) Kemira OYJ. All rights reserved. Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological infor- mation : May lower the pH of water and thus be harmful to aquatic organisms. Components: Iron trichloride: Results of PBT and vPvB assessment : No information available. Hydrochloric acid: Results of PBT and vPvB assessment : This substance is not considered to be a PBT (Persistent, Bioaccumulation, Toxic) This substance is not considered to be vPvB (very Persistent nor very Bioaccumulating) SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. Dispose of in compliance with local and national regulations. Contaminated packaging : Must be disposed of in accordance with local and national regulations. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. : UN 2582 Proper shipping name : Ferric chloride solution (Ferric chloride) Class : 8 Packing group : III Labels : Corrosive Packing instruction (cargo aircraft) : 856 SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 16 / 20 (c) Kemira OYJ. All rights reserved. IMDG-Code UN number : UN 2582 Proper shipping name : FERRIC CHLORIDE SOLUTION (Ferric chloride) Class : 8 Packing group : III Labels : 8 EmS Code : F-A, S-B Marine pollutant : no Transport in bulk according to IMO instruments Not applicable for product as supplied. National Regulations 49 CFR UN/ID/NA number : UN 2582 Proper shipping name : Ferric chloride, solution Class : 8 Packing group : III Labels : CORROSIVE ERG Code : 154 Marine pollutant : no Special precautions for user Remarks : Corrosive in contact with metals, Metal containers must be lined. The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var- iations in regional or country regulations. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Iron trichloride 7705-08-0 1000 2479 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Corrosive to metals Acute toxicity (any route of exposure) Serious eye damage or eye irritation Skin corrosion or irritation SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 17 / 20 (c) Kemira OYJ. All rights reserved. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by t he U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: Iron trichloride 7705-08-0 >= 30 - < 50 % Hydrochloric acid 7647-01-0 >= 0.1 - < 1 % Iron dichloride 7758-94-3 >= 0.1 - < 1 % The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: Iron trichloride 7705-08-0 >= 30 - < 50 % Hydrochloric acid 7647-01-0 >= 0.1 - < 1 % Iron dichloride 7758-94-3 >= 0.1 - < 1 % This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 This product does not contain any priority pollutants related to the U.S. Clean Water Act California Prop. 65 WARNING: This product can expose you to chemicals including iron bis(arsenate), Cadmium chloride, Nickel dichloride, lead dichloride, which is/are known to the State of California to cause cancer, and mercury dichloride, Nickel dichloride, lead dichloride, which is/are known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. The components of this product are reported in the following inventories: TSCA : All components of this product are included in the United States TSCA Chemical Inventory with Active Status or are not required to be listed on the United States TSCA Chemic al Inventory. DSL : All components of this product are included in the Canada Domestic Substance List (DSL) or are not required to be listed on the Canada Domestic Substance List (DSL). AIIC : All components of this product are included in the Australian Inventory of Industrial Chemicals (AIIC) or are not required to be listed on the Australian Inventory of Industrial Chemicals (AIIC). IECSC : All components of this product are included on the Chinese inventory or are not required to be listed on the Chinese in- ventory. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 18 / 20 (c) Kemira OYJ. All rights reserved. KECI : All components of this product are included in the Korean (ECL) inventory or are not required to be listed on the Korean (ECL) inventory. PICCS : All components of this product are included on the Philippine (PICCS) inventory or are not required to be listed on the Phil- ippine (PICCS) inventory. ENCS : All components of this product are included on the Japanese (ENCS) inventory or are not required to be listed on the Japa- nese (ENCS) inventory. EINECS : All components of this product are included in the European Inventory of Existing Chemical Substances (EINECS) or are not required to be listed on EINECS. NZIoC : All components of this product are included in the New Zea- land inventory (NZIoC) or are not required to be listed on the New Zealand inventory(NZIoC). TCSI : This product's Taiwan Toxic Chemical Substances Control Act Inventory status has NOT been determined. TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. SECTION 16. OTHER INFORMATION Further information NFPA 704: HMIS® IV: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz- ards or risks, and 4 representing signifi- cant hazards or risks. Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits HEALTH 3 0 0 Flammability Instability Special hazard FLAMMABILITY PHYSICAL HAZARD / 3 0 4 Health SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 19 / 20 (c) Kemira OYJ. All rights reserved. OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / C : Ceiling limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / C : Ceiling value not be exceeded at any time. OSHA P0 / TWA : 8-hour time weighted average OSHA P0 / C : Ceiling limit OSHA Z-1 / C : Ceiling AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa- tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso- ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har- monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan- gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In- ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus- trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin- istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop- ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu- lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc- es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub- stance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Con- trol Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative Relevant changes have been marked with vertical lines. This Safety Data Sheet is prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200), an adoption of the UN Globally Harmonized System of Classification and Label- ling of Chemicals (GHS), Revision 3 by Kemira. Sources of key data used to : Regulations, databases, literature, own tests. SAFETY DATA SHEET according to the OSHA Hazard Communication Standard KEMIRA PIX-311 Version 1.9 Revision Date: 07/03/2024 Date of last issue: 07/03/2024 Date of first issue: 02/20/2015 20 / 20 (c) Kemira OYJ. All rights reserved. compile the Safety Data Sheet Revision Date : 07/03/2024 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN