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HomeMy WebLinkAboutDRC-2025-000412299 South Main Street, Suite 1700 Salt Lake City, Utah 84111 (801) 649-2000 Fax: (801) 880-2879 www.energysolutions.com February 4, 2025 CD-2025-021 Mr. Doug Hansen, Director Division of Waste Management and Radiation Control P.O. Box 144880 Salt Lake City, UT 84114-4880 Subject:Preliminary Analytical Measurements Dear Mr. Hansen: As part of our ongoing efforts related to the Federal Cell Facility Radioactive Material License Application (FCF Application), EnergySolutions hereby shares preliminary laboratory results for the analytical testing of rock material samples proposed for use in the final cover construction of our new facility. Enclosed with this letter are the results from the laboratory analysis of the first two rock samples processed. Should you have any questions or require further clarification regarding these preliminary measurements, please do not hesitate to contact me at 801-649-2000. Sincerely, Vern C. Rogers Director, Regulatory Affairs enclosures 299 South Main Street, Suite 1700 Salt Lake City, Utah 84111 (801) 649-2000 Fax: (801) 880-2879 www.energysolutions.com EXHIBIT A DBS&A LABORATORY REPORT ENERGYSOLUTIONS BORROW PIT Laboratory Report Prepared for Neptune and Company, Inc. Prepared by DBS&A Soil Testing & Research Laboratory 4400 Alameda Blvd. NE, Suite C Albuquerque, New Mexico 87113 (505) 889-7752 www.dbstephens.com DB24.1371.00 4400 Alameda Boulevard NE, Suite C (505) 889-7752 Albuquerque, New Mexico 87113 www.dbstephens.com Daniel G. Levitt Neptune & Company, Inc. 1435 Garrison Street, Suite 201 Lakewood, CO 80215 720-746-1803, X1012 Re: DBS&A Laboratory Report for P Borrow Pit Dear Daniel G. Levitt: Enclosed is the report for the requested laboratory services. Please review this report and provide any comments as samples will be held for a maximum of 30 days. After 30 days samples will be returned or disposed of in an appropriate manner. All testing results were evaluated subjectively for consistency and reasonableness, and the results appear to be reasonably representative of the material tested. However, DBS&A does not assume any responsibility for interpretations or analyses based on the data enclosed, nor can we guarantee that these data are fully representative of the undisturbed materials at the field site. We recommend that careful evaluation of these laboratory results be made for your particular application. The testing utilized to generate the enclosed report employs methods that are standard for the industry. The results do not constitute a professional opinion by DBS&A, nor can the results affect any professional or expert opinions rendered with respect thereto by DBS&A. You have acknowledged that all the testing undertaken by us, and the report provided, constitutes mere test results using standardized methods, and cannot be used to disqualify DBS&A from rendering any professional or expert opinion, having waived any claim of conflict of interest by DBS&A. We are pleased to provide this service and look forward to future laboratory testing on other projects. If you have any questions about the enclosed data, please do not hesitate to call. Sincerely, DANIEL B. STEPHENS & ASSOCIATES, INC. SOIL TESTING & RESEARCH LABORATORY Thane Morgan William Seward Laboratory Manager Technical Lead Summaries 3 Summary of Tests Performed Saturated Initial Soil Hydraulic Moisture Particle Specific Air Laboratory Properties1 Conductivity2 Characteristics3 Size4 Gravity5 Perm- Atterberg Proctor Sample Number G VM VD CH FH FW HC PP FP DPP RH EP WHC Kunsat DS WS H F C eability Limits Compaction LOT 5 (MR) (-1.25"/+#10) X X X X LOT 5 (Ksat) (-1.25"/+#10) X X X LOT 12 (MR) (-1.25"/+#10) X X X X LOT 12 (Ksat) (-1.25"/+#10) X X X 1 G = Gravimetric Moisture Content, VM = Volume Measurement Method, VD = Volume Displacement Method 2 CH = Constant Head Rigid Wall, FH = Falling Head Rigid Wall, FW = Falling Head Rising Tail Flexible Wall 3 HC = Hanging Column, PP = Pressure Plate, FP = Filter Paper, DPP = Dew Point Potentiometer, RH = Relative Humidity Box, EP = Effective Porosity, WHC = Water Holding Capacity, Kunsat = Calculated Unsaturated Hydraulic Conductivity 4 DS = Dry Sieve, WS = Wet Sieve, H = Hydrometer 5 F = Fine (<4.75mm), C = Coarse (>4.75mm) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 4 Notes D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . Sample Receipt: Fifteen samples, each as loose material in two five-gallon buckets sealed with lids, were received on September 11, 2024. The samples were packaged on pallets and were received in good order. Two samples were originally selected for testing and the remaining samples were placed on hold. Two additional samples were selected by the customer for this follow-on testing. Sample Preparation and Testing Notes: For each sample, the two buckets of material were combined into one large sample. Particles larger than 1.25” were removed from the bulk material of the selected test samples in order to achieve target particle diameter to test cell size ratios. Particles smaller than 2-mm (#10 mesh) were removed from the remaining material to simulate the fines washing out of the bulk of the bio- barrier layer. The -1.25”/+#10 portion was moisture adjusted to a moisture content that would facilitate compaction. Test samples were prepared by adding the material to 8” diameter test cells in three lifts for moisture retention (MR) testing. Each lift was hand compacted while shaking and tapping to encourage particle alignment. The prepared sub-samples in 8” rings were subjected to the hanging column portion of moisture retention testing. Secondary sub-samples were prepared in 12” diameter test rings using the same methods. The secondary sub-samples were subjected to saturated hydraulic conductivity (Ksat) testing. Dewpoint potentiometer and relative humidity chamber moisture retention testing methods were not performed as they are based on the fraction finer than 2-mm. The saturated volumetric moisture content and Theta S were set equal to the calculated total porosity, and Theta R was set to equal 0 prior to generating the predicted soil-water characteristic curves. Porosity and oversize correction calculations are based on the use of an assumed specific gravity value of 2.75. 5 Moisture Content Dry Bulk Density Moisture Content Dry Bulk Density % of Target Density Dry Bulk Density % Volume Change % of Initial Density Dry Bulk Density % Volume Change % of Initial Density Sample Number (%, g/g) (g/cm 3) (%, g/g) (g/cm 3) (%) (g/cm 3) (%) (%) (g/cm 3) (%) (%) LOT 5 (MR) (-1.25"/+#10)NA NA 0.4 1.71 NA 1.71 --- 100% NA NA NA LOT 5 (Ksat) (-1.25"/+#10)NA NA 0.0 1.72 NA 1.72 --- 100% NA NA NA LOT 12 (MR) (-1.25"/+#10)NA NA 1.1 1.69 NA 1.69 --- 100% NA NA NA LOT 12 (Ksat) (-1.25"/+#10)NA NA 1.2 1.69 NA 1.69 --- 100% NA NA NA NA = Not analyzed Summary of Sample Preparation/Volume Changes Target Remold Parameters1 Actual Remold Data Volume Change Post Saturation2 Volume Change Post Drying Curve3 1Target Remold Parameters: hand tamping while shaking and tapping 2Volume Change Post Saturation: Volume change measurements were obtained after saturated hydraulic conductivity testing. 3Volume Change Post Drying Curve: Volume change measurements were obtained throughout hanging column and pressure plate testing. The 'Volume Change Post Drying Curve' values represent the final sample dimensions after the last pressure plate point. Notes: "+" indicates sample swelling, "-" indicates sample settling, and "---" indicates no volume change occurred. D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 6 Summary of Initial Moisture Content, Dry Bulk Density Wet Bulk Density and Calculated Porosity Moisture Content As Received Remolded Dry Bulk Wet Bulk Calculated Gravimetric Volumetric Gravimetric Volumetric Density Density Porosity Sample Number (%, g/g)(%, cm3/cm3)(%, g/g)(%, cm3/cm3)(g/cm3)(g/cm3)(%) LOT 5 (MR) (-1.25"/+#10) NA NA 0.4 0.7 1.71 1.72 37.9 LOT 5 (Ksat) (-1.25"/+#10) NA NA 0.0 0.0 1.72 1.72 37.5 LOT 12 (MR) (-1.25"/+#10) NA NA 1.1 1.8 1.69 1.71 38.5 LOT 12 (Ksat) (-1.25"/+#10) NA NA 1.2 2.1 1.69 1.71 38.6 NA = Not analyzed D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 7 Summary of Saturated Hydraulic Conductivity Tests Oversize Corrected Ksat Ksat Method of Analysis Sample Number (cm/sec) (cm/sec) Constant Head Falling Head LOT 5 (Ksat) (-1.25"/+#10) 4.8E-02 3.9E-02 X LOT 12 (Ksat) (-1.25"/+#10) 4.3E-02 3.4E-02 X D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 8 Summary of Moisture Characteristics of the Initial Drainage Curve Pressure Head Moisture Content Sample Number (-cm water)(%, cm3/cm3) LOT 5 (MR) (-1.25"/+#10) 0 37.9 4 12.7 15 11.9 47 10.3 217 8.8 LOT 12 (MR) (-1.25"/+#10) 0 38.5 4 10.5 16 9.9 47 9.3 227 8.9 D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 9 Summary of Calculated Unsaturated Hydraulic Properties Oversize Corrected Sample Number (cm-1) N (dimensionless) r (% vol) s (% vol) r (% vol) s (% vol) LOT 5 (MR) (-1.25"/+#10) 9743 1.1002 0.00 37.85 0.00 33.03 LOT 12 (MR) (-1.25"/+#10) 22251 1.1048 0.00 38.48 0.00 33.35 D a n i e l B . S t e p h e n s & A s s o c i a t e s ,I n c . 10 Initial Properties 11 Data for Initial Moisture Content, Bulk Density, Porosity, and Percent Saturation Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 5 (MR) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 As Received Remolded Test Date:NA 16-Dec-24 Field weight* of sample (g):8028.04 Tare weight, ring (g):1015.40 Tare weight, pan/plate (g):0.00 Tare weight, other (g):0.00 Dry weight of sample (g):6982.26 Sample volume (cm3):4085.38 Assumed particle density (g/cm3):2.75 Gravimetric Moisture Content (% g/g):0.4 Volumetric Moisture Content (% vol):0.7 Dry bulk density (g/cm3):1.71 Wet bulk density (g/cm3):1.72 Calculated Porosity (% vol):37.9 Percent Saturation:2.0 Laboratory analysis by:F.Cerno Data entered by:F.Cerno Checked by:J. Hines Comments: * Weight including tares NA = Not applicable --- = This sample was not remolded 12 Data for Initial Moisture Content, Bulk Density, Porosity, and Percent Saturation Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 5 (Ksat) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 As Received Remolded Test Date:NA 12-Dec-24 Field weight* of sample (g):27961.58 Tare weight, ring (g):2988.83 Tare weight, pan/plate (g):0.00 Tare weight, other (g):0.00 Dry weight of sample (g):24972.75 Sample volume (cm3):14534.17 Assumed particle density (g/cm3):2.75 Gravimetric Moisture Content (% g/g):0.0 Volumetric Moisture Content (% vol):0.0 Dry bulk density (g/cm3):1.72 Wet bulk density (g/cm3):1.72 Calculated Porosity (% vol):37.5 Percent Saturation:0.0 Laboratory analysis by:F.Cerno Data entered by:F.Cerno Checked by:J. Hines Comments: * Weight including tares NA = Not applicable --- = This sample was not remolded 13 Data for Initial Moisture Content, Bulk Density, Porosity, and Percent Saturation Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 12 (MR) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 As Received Remolded Test Date:NA 16-Dec-24 Field weight* of sample (g):8071.65 Tare weight, ring (g):1022.31 Tare weight, pan/plate (g):0.00 Tare weight, other (g):0.00 Dry weight of sample (g):6973.94 Sample volume (cm3):4122.17 Assumed particle density (g/cm3):2.75 Gravimetric Moisture Content (% g/g):1.1 Volumetric Moisture Content (% vol):1.8 Dry bulk density (g/cm3):1.69 Wet bulk density (g/cm3):1.71 Calculated Porosity (% vol):38.5 Percent Saturation:4.8 Laboratory analysis by:F.Cerno Data entered by:F.Cerno Checked by:J. Hines Comments: * Weight including tares NA = Not applicable --- = This sample was not remolded 14 Data for Initial Moisture Content, Bulk Density, Porosity, and Percent Saturation Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 12 (Ksat) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 As Received Remolded Test Date:NA 15-Dec-24 Field weight* of sample (g):27843.70 Tare weight, ring (g):2988.83 Tare weight, pan/plate (g):0.00 Tare weight, other (g):0.00 Dry weight of sample (g):24556.38 Sample volume (cm3):14534.17 Assumed particle density (g/cm3):2.75 Gravimetric Moisture Content (% g/g):1.2 Volumetric Moisture Content (% vol):2.1 Dry bulk density (g/cm3):1.69 Wet bulk density (g/cm3):1.71 Calculated Porosity (% vol):38.6 Percent Saturation:5.3 Laboratory analysis by:F.Cerno Data entered by:F.Cerno Checked by:J. Hines Comments: * Weight including tares NA = Not applicable --- = This sample was not remolded 15 Saturated Hydraulic Conductivity 16 Saturated Hydraulic Conductivity Constant Head Method Job Name:Neptune & Company, Inc.Type of water used:TAP Job Number:DB24.1371.00 Collection vessel tare (g):67.62 Sample Number:LOT 5 (Ksat) (-1.25"/+#10)Sample length (cm):20.26 Project Name:Energy Solutions Borrow Pit Sample diameter (cm):30.22 PO Number:726460 Sample x-sectional area (cm2):717.45 Temp Head Q + Tare Q Elapsed Ksat Ksat @ 20°C Date Time (°C) (cm) (g)(cm3)time (sec) (cm/sec) (cm/sec) Test # 1: 12-Dec-24 9:45:00 18.5 1.3 139.53 71.9 30 5.2E-02 5.4E-02 12-Dec-24 9:45:30 Test # 2: 12-Dec-24 10:58:00 18.5 2.2 166.27 98.7 30 4.2E-02 4.4E-02 12-Dec-24 10:58:30 Test # 3: 12-Dec-24 11:23:00 18.5 1.9 154.72 87.1 30 4.3E-02 4.5E-02 12-Dec-24 11:23:30 Test # 4: 12-Dec-24 11:55:00 18.5 1.5 142.13 74.5 30 4.7E-02 4.9E-02 12-Dec-24 11:55:30 Average Ksat (cm/sec):4.8E-02 Oversize Corrected Ksat (cm/sec):3.9E-02 Comments: --- = Oversize correction is unnecessary since coarse fraction < 5% of composite mass Laboratory analysis by:F. Cerno Data entered by:F. Cerno Checked by:J. Hines 0.0028 0.0032 0.0036 0.0040 0.0044 0.0048 0.06 0.07 0.08 0.09 0.10 0.11 0.12 Ve l o c i t y ( c m / s ) Hydraulic Gradient (cm/cm) Velocity vs. Hydraulic Gradient 17 Oversize Correction Data Sheet Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 5 (Ksat) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 Split (3/4", 3/8", #4):1.25" Calculated Porosity of Fines (% vol):37.5 Coarse Fraction*Fines Fraction Composite Subsample Mass (g):0.19 0.81 1.00 Bulk Density (g/cm3):2.75 1.72 1.85 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.54 Volumetric Fraction (%):12.78 87.22 100.00 Mass Fraction (%):19.00 81.00 100.00 Ksat (cm/sec):NM 4.8E-02 3.9E-02 * = Porosity and moisture content of coarse fraction assumed to be zero. --- = Oversize correction is unnecessary since coarse fraction < 5% of composite mass NM = Not measured Laboratory analysis by:F. Cerno Data entered by:F. Cerno Checked by: J. Hines 18 Saturated Hydraulic Conductivity Constant Head Method Job Name:Neptune & Company, Inc.Type of water used:TAP Job Number:DB24.1371.00 Collection vessel tare (g):68.62 Sample Number:LOT 12 (Ksat) (-1.25"/+#10)Sample length (cm):20.26 Project Name:Energy Solutions Borrow Pit Sample diameter (cm):30.22 PO Number:726460 Sample x-sectional area (cm2):717.45 Temp Head Q + Tare Q Elapsed Ksat Ksat @ 20°C Date Time (°C) (cm) (g)(cm3)time (sec) (cm/sec) (cm/sec) Test # 1: 15-Dec-24 11:55:00 18.6 1.3 131.88 63.3 30 4.6E-02 4.7E-02 15-Dec-24 11:55:30 Test # 2: 15-Dec-24 12:51:30 18.7 2.6 155.31 86.7 25 3.8E-02 3.9E-02 15-Dec-24 12:51:55 Test # 3: 15-Dec-24 13:02:30 18.7 2 140.14 71.5 25 4.0E-02 4.2E-02 15-Dec-24 13:02:55 Test # 4: 15-Dec-24 13:19:00 18.7 1.5 124.82 56.2 25 4.2E-02 4.4E-02 15-Dec-24 13:19:25 Average Ksat (cm/sec):4.3E-02 Oversize Corrected Ksat (cm/sec):3.4E-02 Comments: --- = Oversize correction is unnecessary since coarse fraction < 5% of composite mass Laboratory analysis by:F. Cerno Data entered by:F. Cerno Checked by:J. Hines 0.001 0.002 0.003 0.004 0.005 0.006 0.03 0.05 0.07 0.09 0.11 0.13 0.15 Ve l o c i t y ( c m / s ) Hydraulic Gradient (cm/cm) Velocity vs. Hydraulic Gradient 19 Oversize Correction Data Sheet Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 12 (Ksat) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 Split (3/4", 3/8", #4):1.25" Calculated Porosity of Fines (% vol):38.6 Coarse Fraction*Fines Fraction Composite Subsample Mass (g):0.20 0.80 1.00 Bulk Density (g/cm3):2.75 1.69 1.83 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.55 Volumetric Fraction (%):13.31 86.69 100.00 Mass Fraction (%):20.00 80.00 100.00 Ksat (cm/sec):NM 4.3E-02 3.4E-02 * = Porosity and moisture content of coarse fraction assumed to be zero. --- = Oversize correction is unnecessary since coarse fraction < 5% of composite mass NM = Not measured Laboratory analysis by:F. Cerno Data entered by:F. Cerno Checked by: J. Hines 20 Moisture Retention Characteristics 21 Moisture Retention Data Hanging Column / Pressure Plate (Soil-Water Characteristic Curve) Job Name:Neptune & Company, Inc.Dry wt. of sample (g):6982.26 Job Number:DB24.1371.00 Tare wt., ring (g):1015.40 Sample Number:LOT 5 (MR) (-1.25"/+#10)Tare wt., screen & clamp (g):82.62 Project Name:Energy Solutions Borrow Pit Initial sample volume (cm3):4085.38 PO Number:726460 Initial dry bulk density (g/cm3):1.71 Assumed particle density (g/cm3):2.75 Initial calculated total porosity (%):37.85 Matric Moisture Weight* Potential Content † Date Time (g) (-cm water) (% vol) Hanging column:16-Dec-24 16:00 9626.60 0 37.85 20-Dec-24 14:30 8597.90 3.5 12.67 26-Dec-24 11:30 8568.40 15.0 11.95 30-Dec-24 11:30 8501.40 46.5 10.31 3-Jan-25 10:00 8438.40 217.0 8.77 Volume Adjusted Data 1 Adjusted Matric Adjusted % Volume Adjusted Calculated Potential Volume Change 2 Density Porosity (-cm water)(cm3)(%)(g/cm3)(%) Hanging column:0.0 --- --- --- --- 3.5 --- --- --- --- 15.0 --- --- --- --- 46.5 --- --- --- --- 217.0 --- --- --- --- Comments: 1 2 * Weight including tares †Assumed density of water is 1.0 g/cm3 ‡‡ Technician Notes: Laboratory analysis by:F.Cerno Data entered by:T.Morgan Checked by:J.Hines Represents percent volume change from original sample volume. A '+' denotes measured sample swelling, a '-' denotes measured sample settling, and '---' denotes no volume change occurred. Applicable if the sample experienced volume changes during testing. ‘Volume Adjusted’ values represent each of the volume change measurements obtained after saturated hydraulic conductivity testing and throughout hanging column/pressure plate testing. "---" indicates no volume changes occurred. Volume adjustments are applicable at this matric potential (see comment #1). Changes in volume, if applicable, are estimated based on obtainable measurements of changes in sample length and diameter. 22 Water Retention Data Points Sample Number: LOT 5 (MR) (-1.25"/+#10) 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 0 10 20 30 40 50 60 70 Pr e s s u r e H e a d ( - c m w a t e r ) Moisture Content (%,cm3/cm3) Hanging column Pressure plate Dew point potentiometer Rh box D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 23 Predicted Water Retention Curve and Data Points Sample Number: LOT 5 (MR) (-1.25"/+#10) 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 0 10 20 30 40 50 60 70 Pr e s s u r e H e a d ( - c m w a t e r ) Moisture Content (%,cm3/cm3) Hanging column Pressure plate Dew point potentiometer Rh box Predicted curve Oversize corrected D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 24 Plot of Relative Hydraulic Conductivity vs Moisture Content Sample Number: LOT 5 (MR) (-1.25"/+#10) 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 0 10 20 30 40 50 60 70 Re l a t i v e H y d r a u l i c C o n d u c t i v i t y Moisture Content (%,cm3/cm3) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 25 Plot of Hydraulic Conductivity vs Moisture Content Sample Number: LOT 5 (MR) (-1.25"/+#10) 1.E-12 1.E-11 1.E-10 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 0 10 20 30 40 50 60 70 Hy d r a u l i c C o n d u c t i v i t y ( c m / s ) Moisture Content (%,cm3/cm3) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 26 Plot of Relative Hydraulic Conductivity vs Pressure Head Sample Number: LOT 5 (MR) (-1.25"/+#10) 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 Re l a t i v e H y d r a u l i c C o n d u c t i v i t y Pressure Head (-cm water) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 27 Plot of Hydraulic Conductivity vs Pressure Head Sample Number: LOT 5 (MR) (-1.25"/+#10) 1.E-12 1.E-11 1.E-10 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 Hy d r a u l i c C o n d u c t i v i t y ( c m / s ) Pressure Head (-cm water) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 28 Oversize Correction Data Sheet Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 5 (MR) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 Split (3/4", 3/8", #4):1.25" Coarse Fraction*Fines Fraction**Composite Subsample Mass (g):0.19 0.81 1.00 Mass Fraction (%):19.00 81.00 100.00 Initial Sample i Bulk Density (g/cm3):2.75 1.71 1.84 Calculated Porosity (% vol):0.00 37.85 33.04 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.54 Volumetric Fraction (%):12.72 87.28 100.00 Initial Moisture Content (% vol):0.00 0.74 0.65 Saturated Sample s Bulk Density (g/cm3):2.75 1.71 1.84 Calculated Porosity (% vol):0.00 37.85 33.04 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.54 Volumetric Fraction (%):12.72 87.28 100.00 Saturated Moisture Content (% vol):0.00 37.85 33.03 Residual Sample r Bulk Density (g/cm3):2.75 1.71 1.84 Calculated Porosity (% vol):0.00 37.85 33.04 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.54 Volumetric Fraction (%):12.72 87.28 100.00 Residual Moisture Content (% vol):0.00 0.00 0.00 Ksat (cm/sec):NM 4.8E-02 3.9E-02 * = Porosity and moisture content of coarse fraction assumed to be zero. ** = Volume adjusted, if applicable. See notes on Moisture Retention Data pages. NM = Not measured Laboratory analysis by:F.Cerno Data entered by:T.Morgan Checked by: J.Hines 29 Moisture Retention Data Hanging Column / Pressure Plate (Soil-Water Characteristic Curve) Job Name:Neptune & Company, Inc.Dry wt. of sample (g):6973.94 Job Number:DB24.1371.00 Tare wt., ring (g):1022.31 Sample Number:LOT 12 (MR) (-1.25"/+#10)Tare wt., screen & clamp (g):84.63 Project Name:Energy Solutions Borrow Pit Initial sample volume (cm3):4122.17 PO Number:726460 Initial dry bulk density (g/cm3):1.69 Assumed particle density (g/cm3):2.75 Initial calculated total porosity (%):38.48 Matric Moisture Weight* Potential Content † Date Time (g) (-cm water) (% vol) Hanging column:16-Dec-24 16:30 9667.09 0 38.48 20-Dec-24 14:30 8513.70 3.5 10.50 12/26/20224 11:30 8487.30 15.5 9.86 30-Dec-24 11:30 8464.10 47.0 9.30 3-Jan-25 10:00 8446.60 227.0 8.87 Volume Adjusted Data 1 Adjusted Matric Adjusted % Volume Adjusted Calculated Potential Volume Change 2 Density Porosity (-cm water)(cm3)(%)(g/cm3)(%) Hanging column:0.0 --- --- --- --- 3.5 --- --- --- --- 15.5 --- --- --- --- 47.0 --- --- --- --- 227.0 --- --- --- --- Comments: 1 2 * Weight including tares †Assumed density of water is 1.0 g/cm3 ‡‡ Technician Notes: Laboratory analysis by:F.Cerno Data entered by:T.Morgan Checked by:J.Hines Represents percent volume change from original sample volume. A '+' denotes measured sample swelling, a '-' denotes measured sample settling, and '---' denotes no volume change occurred. Applicable if the sample experienced volume changes during testing. ‘Volume Adjusted’ values represent each of the volume change measurements obtained after saturated hydraulic conductivity testing and throughout hanging column/pressure plate testing. "---" indicates no volume changes occurred. Volume adjustments are applicable at this matric potential (see comment #1). Changes in volume, if applicable, are estimated based on obtainable measurements of changes in sample length and diameter. 30 Water Retention Data Points Sample Number: LOT 12 (MR) (-1.25"/+#10) 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 0 10 20 30 40 50 60 70 Pr e s s u r e H e a d ( - c m w a t e r ) Moisture Content (%,cm3/cm3) Hanging column Pressure plate Dew point potentiometer Rh box D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 31 Predicted Water Retention Curve and Data Points Sample Number: LOT 12 (MR) (-1.25"/+#10) 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 0 10 20 30 40 50 60 70 Pr e s s u r e H e a d ( - c m w a t e r ) Moisture Content (%,cm3/cm3) Hanging column Pressure plate Dew point potentiometer Rh box Predicted curve Oversize corrected D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 32 Plot of Relative Hydraulic Conductivity vs Moisture Content Sample Number: LOT 12 (MR) (-1.25"/+#10) 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 0 10 20 30 40 50 60 70 Re l a t i v e H y d r a u l i c C o n d u c t i v i t y Moisture Content (%,cm3/cm3) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 33 Plot of Hydraulic Conductivity vs Moisture Content Sample Number: LOT 12 (MR) (-1.25"/+#10) 1.E-12 1.E-11 1.E-10 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 0 10 20 30 40 50 60 70 Hy d r a u l i c C o n d u c t i v i t y ( c m / s ) Moisture Content (%,cm3/cm3) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 34 Plot of Relative Hydraulic Conductivity vs Pressure Head Sample Number: LOT 12 (MR) (-1.25"/+#10) 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 Re l a t i v e H y d r a u l i c C o n d u c t i v i t y Pressure Head (-cm water) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 35 Plot of Hydraulic Conductivity vs Pressure Head Sample Number: LOT 12 (MR) (-1.25"/+#10) 1.E-12 1.E-11 1.E-10 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00 1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 Hy d r a u l i c C o n d u c t i v i t y ( c m / s ) Pressure Head (-cm water) D a n i e l B . S t e p h e n s & A s s o c i a t e s , I n c . 36 Oversize Correction Data Sheet Job Name:Neptune & Company, Inc. Job Number:DB24.1371.00 Sample Number:LOT 12 (MR) (-1.25"/+#10) Project Name:Energy Solutions Borrow Pit PO Number:726460 Split (3/4", 3/8", #4):1.25" Coarse Fraction*Fines Fraction**Composite Subsample Mass (g):0.20 0.80 1.00 Mass Fraction (%):20.00 80.00 100.00 Initial Sample i Bulk Density (g/cm3):2.75 1.69 1.83 Calculated Porosity (% vol):0.00 38.48 33.35 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.55 Volumetric Fraction (%):13.33 86.67 100.00 Initial Moisture Content (% vol):0.00 1.83 1.59 Saturated Sample s Bulk Density (g/cm3):2.75 1.69 1.83 Calculated Porosity (% vol):0.00 38.48 33.35 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.55 Volumetric Fraction (%):13.33 86.67 100.00 Saturated Moisture Content (% vol):0.00 38.48 33.35 Residual Sample r Bulk Density (g/cm3):2.75 1.69 1.83 Calculated Porosity (% vol):0.00 38.48 33.35 Volume of Solids (cm3):0.07 0.29 0.36 Volume of Voids (cm3):0.00 0.18 0.18 Total Volume (cm3):0.07 0.47 0.55 Volumetric Fraction (%):13.33 86.67 100.00 Residual Moisture Content (% vol):0.00 0.00 0.00 Ksat (cm/sec):NM 4.3E-02 3.4E-02 * = Porosity and moisture content of coarse fraction assumed to be zero. ** = Volume adjusted, if applicable. See notes on Moisture Retention Data pages. NM = Not measured Laboratory analysis by:F.Cerno Data entered by:T.Morgan Checked by: J.Hines 37 Laboratory Tests and Methods 38 Dry Bulk Density: ASTM D7263 Moisture Content: ASTM D7263, ASTM D2216 Calculated Porosity: ASTM D7263 Saturated Hydraulic Conductivity: Falling or Constant Head: (Rigid Wall) ASTM D2434 Hanging Column Method: ASTM D6836 (burette, rather than capillary tube, used for water potential monitoring) Pressure Plate Method: ASTM D6836 Water Potential (Dewpoint Potentiometer) Method: ASTM D6836 Relative Humidity (Box) Method: Campbell, G. and G. Gee. 1986. Water Potential: Miscellaneous Methods. Chp. 25, pp. 631-632, in A. Klute (ed.), Methods of Soil Analysis. Part 1. American Society of Agronomy, Madison, WI; Karathanasis & Hajek. 1982. Quantitative Evaluation of Water Adsorption on Soil Clays. SSA Journal 46:1321-1325 Moisture Retention Characteristics & Calculated Unsaturated Hydraulic Conductivity: ASTM D6836; van Genuchten, M.T. 1980. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. SSSAJ 44:892-898; van Genuchten, M.T., F.J. Leij, and S.R. Yates. 1991. The RETC code for quantifying the hydraulic functions of unsaturated soils. Robert S. Kerr Environmental Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency, Ada, Oklahoma. EPA/600/2091/065. December 1991 Coarse Fraction (Gravel) Correction (calc): ASTM D4718; Bouwer, H. and Rice, R.C. 1984. Hydraulic Properties of Stony Vadose Zones. Groundwater Vol. 22, No. 6 Tests and Methods D a n i e l B .S t e p h e n s & A s s o c i a t e s , I n c . 39