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HomeMy WebLinkAboutDERR-2025-001202DYNO DynoNobel Bucky Whitehouse Tooele County Local Emergency Planning Commission » bucky.whitehouse@tooeleco.gov February 12, 2025 Dyno Nobel Inc .. 6440 S Millrock Drive, Suite 150 Salt Lake City, UT 84121 Ph: 800.473.2675 dynonobel.com Re: Dyno Nobel Tooele R&D Facility EPCRA 311 Notification Dear Mr. Whitehouse: In accordance with Section 311 of Title Ill of the Superfund Amendments and Reauthorization Act (SARA), Dyno Nobel Inc. is submitting notification of the presence of hazardous materials above regulatory thresholds at the Dyna Nobel, Inc. Pilot Plant and Research & Development Facility in Tooele County, Utah (73 N. Stark Rd., Stockton, UT 84071): Date Material Arrived Chemical Name CASNo. On-Site Mineral Oil 64742-53-6 9/19/2024 Diesel Fuel #2 68476-34-6 9/20/2024 Ammonium Nitrate.Solution 6484-52-2 11/5/2024 Titan 1000G 11/10/2024 Ammonium Nitrate Prill 6484-52-2 11/20/2024 Recycle Emulsion 11/15/2024 Please review this information at your earliest convenience. If you should have any questions, please feel free to contact me at 423-255-9300. Regards, Patrick Bowden Sr. Manager Operations Ph: 385-455-3523 E: Patrick. bowden@am .dynonobel. com cc: Utah State Emergency Response Commission Anthony Bott, Deputy Chief/Fire Marshall (anthony.bott@tooeleco.gov) Enclosures: Safety Data Sheets Groundbreaking Performance· Page 1 of 1 SDS# 1052 Date: 10/02/2018 Page 1 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 1 – IDENTIFICATION Name, Address, and Telephone of the Responsible Party Dyno Nobel Inc. 2795 East Cottonwood Parkway, Suite 500 Salt Lake City, Utah 84121 Phone: 801-364-4800 Fax 801-321-6703 E-Mail: dnna.hse@am.dynonobel.com www.dynonobel.com SDS #: 1052 Date: 10/02/2018 Supersedes: 06/10/2016 Product Identifier Product Form: Mixture Product Name: Bulk Emulsion Other Means of Identification Synonyms: DYNO GOLD® TITAN® 2000 DYNO GOLD® LITE TITAN® 2000G EXTRAMITE 1000 TITAN® PB 1000 RUG-1 (Canada Only) TITAN® PB 2000 TITAN® 1000 TITAN® PB 2000 HF TITAN® 1000 GREEN TITAN® SME 1000 TITAN® 1000G TITAN® SME 1000 GREEN TITAN® 1000G GREEN TITAN® XL1000 GREEN TITAN® XL1000 TITAN® HD SMS 1116, 1116A, 1126P, 1136P, 1146P TITAN® SME 2000 DX5037 TITAN® 5000 TITAN® 5000 G Intended Use of the Product Industrial blasting applications as emulsion explosive precursor Emergency Telephone Number FOR 24 HOUR EMERGENCY, CALL CHEMTREC (USA) 800-424-9300 CANUTEC (CANADA) 613-996-6666 SECTION 2 – HAZARD(S) IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Ox. Liq. 2 H272 Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Carc. 2 H351 STOT RE 2 H373 Asp. Tox. 1 H304 Eye Irrit. 2B H320 Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS03 GHS07 GHS08 Signal Word (GHS-US) : Danger SDS# 1052 Date: 10/02/2018 Page 2 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Hazard Statements (GHS-US) : H272 - May intensify fire; oxidizer H302 - Harmful if swallowed H304 – May be fatal if swallowed and enters airways H315 - Causes skin irritation H320 – Causes eye irritation H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure Precautionary Statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P220 - Keep/Store away from clothing, combustible materials, combustibles P221 - Take any precaution to avoid mixing with combustible materials, clothing, combustibles P233 - Keep container tightly closed P260 - Do not breathe dust, fume, mist, spray, vapors P264 - Wash exposed areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P370+P378 - In case of fire: Use appropriate media to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container according to local, regional, national, and international regulations Other Hazards Hazards Not Otherwise Classified (HNOC): Not available Other Hazards: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product identifier % (w/w) Ingredient Classification (GHS- US) Ammonium nitrate (CAS No) 6484-52-2 45 - 80 Ox. Sol. 3, H272 Eye Irrit. 2A, H319 Calcium nitrate (CAS No) 10124-37-5 0.1 - 35 Ox. Sol. 3, H272 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Sodium nitrate (CAS No) 7631-99-4 0.1 - 18 Ox. Sol. 3, H272 SDS# 1052 Date: 10/02/2018 Page 3 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Acute Tox. 4 (Oral), H302 Eye Irrit. 2A, H319 *Methylamine nitrate (CAS No) 22113-87-7 0.1 – 3 Expl. 1.5, H205 Skin Corr. 1A, H314 Eye Dam. 1 – H318 **Fuels, diesel, no. 2 (CAS No) 68476-34-6 0.1 - 10 Flam. Liq. 4, H227 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Carc. 2, H351 STOT RE 2, H373 Asp. Tox. 1, H304 Distillates, petroleum, chemically neutralized light naphthenic (CAS No) 64742-35-4 0.1 - 6 Asp. Tox. 1, H304 * This ingredient is not used in most products, including in GREEN-named products. ** This ingredient is not used in GREEN-named products. Ingredients, other than those mentioned above, as used in this product are not hazardous as defined under current Department of Labor regulations or are present in deminimus concentrations (less than 0.1% for carcinogens, less than 1.0% for other hazardous materials). Full text of H-phrases: see section 16 SECTION 4 - FIRST AID MEASURES Description of First Aid Measures General: Never give anything orally to an unconscious person. If you feel unwell, seek medical advice (provide this Safety Data Sheet to medical personnel). Inhalation: If symptoms occur, go into fresh air and ventilate suspected area. Seek medical attention. Skin Contact: Remove contaminated clothing. Wash with soap and water followed by rinsing with water. Seek medical attention if irritation develops or persists. Wash contaminated clothing before reuse. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Obtain medical attention if irritation develops or persists. Ingestion: Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately. Most Important Symptoms and Effects Both Acute and Delayed General: May be harmful if swallowed. May cause eye or skin irritation. Inhalation: May cause respiratory irritation. Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Ingestion: Likely to be harmful if swallowed. Chronic Symptoms: Contains an ingredient which may cause cancer. Causes damage to organs through prolonged or repeated exposure. Indication of Any Immediate Medical Attention and Special Treatment Needed If symptoms occur, seek medical attention. SECTION 5 - FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Do not attempt to fight fires involving explosive materials or emulsion explosive precursors. Evacuate all personnel to a predetermined safe location, no less than 1/2 mile (800 meters) in all directions. Unusual Fire and Explosion Hazards: May explode or detonate under fire conditions. Burning material may produce toxic vapors. Unsuitable Extinguishing Media: Not available Special Hazards Arising from the Substance or Mixture In large, intense fires the emulsion can behave more like an explosive and detonate from confinement or strong shocks. Evacuation of at least 1 mile is recommended if a largeamount of emulsion is involved in a large fire. SDS# 1052 Date: 10/02/2018 Page 4 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Fire Hazard: May intensify fire; oxidizer. Will burn if exposed to heat, and in addition, will accelerate the burning of other combustibles, resulting in more rapid spread of fire. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. May explode when subjected to fire, supersonic shock or high-energy projectile impact, especially when confined or in large quantities. Reactivity: May cause or intensify fire; oxidizer. May accelerate the burning of other combustible materials. Advice for Firefighters Precautionary Measures Fire: DO NOT ATTEMPT TO FIGHT FIRES INVOLVING EXPLOSIVE MATERIALS. Evacuate all personnel to a predetermined safe location, no less than 1/2 mile (800 meters) in all directions. Can explode or detonate under fire conditions. Burning material may produce toxic vapors. Firefighting Instructions: DO NOT ATTEMPT TO FIGHT FIRE. Immediately evacuate all personnel from the area to a safe distance. Guard against re-entry. Thermal decomposition can lead to release of irritating gases and vapors. Protection During Firefighting: When controlling fire before involvement of explosives or explosive precursors, fire- fighters should wear positive pressure self -containing breathing apparatus (SCBA) and full turnout gear. Hazardous Combustion Products: Nitrogen oxides. Carbon oxides (CO, CO2). Ammonia. Other information: Do not attempt to fight fires involving explosive materials or emulsion explosive precursors. Evacuate all personnel to a predetermined safe location, no less than 1/2 mile (800 meters) in all directions. Reference to Other Sections: Refer to section 9 for flammability properties. SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing dust, mist, or spray. Keep a way from heat/sparks/open flames/hot surfaces. No smoking. Eliminate every possible source of ignition. Evacuate danger area. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Ventilate area. Environmental Precautions Prevent entry to sewers and public waters. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes as necessary to prevent migration and entry into sewers or streams. Do not take up in combustible material such as: saw dust or cellulosic material. Methods for Cleaning Up: Collect spillage for possible reuse. Clean up spills immediately and dispose of waste in accordance with appropriate state, federal and local regulations. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection SECTION 7 - HANDLING AND STORAGE Precautions for Safe Handling It is recommended that users of explosives material be familiar with the Institute of Makers of Explosives Safety Library publications. Additional Hazards When Processed: When heated to decomposition, emits toxic fumes. Do not puncture or incinerate containers. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Conditions for Safe Storage, Including Any Incompatibilities SDS# 1052 Date: 10/02/2018 Page 5 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Translucent to opaque viscous liquid. Odor : Fuel Odor Threshold : Not available pH : Not available Relative Evaporation Rate (butylacetate=1) : < 1 Melting Point : Not available Freezing Point : Not available Boiling Point : Not available Flash Point : Not available Auto-ignition Temperature : Not available Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep /store away from combustible materials, extremely high or low temperatures, direct sunlight, ignition sources, incompatible materials. Incompatible Materials: Corrosives, strong acids, strong bases and alkalis. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Occupational Exposure Limits Ingredients: Product identifier: ACGIH TLV-TWA OSHA PEL-TWA Ammonium nitrate (CAS No) 6484-52-2 None None Sodium nitrate (CAS No) 7631-99-4 None None Calcium nitrate (CAS No) 10124-37-5 None None Methylamine nitrate (CAS No) 22113-87-7 None None Fuels, diesel, no. 2 (CAS No) 68476-34-6 100 ppm None Distillates, petroleum, chemically neutralized light naphthenic (CAS No) 64742-35-4 5 mg/m3 (mist) None Exposure Controls Under normal conditions of use, over-exposure is not expected to occur. Appropriate Engineering Controls: Ensure all national/local regulations are observed. Ensure adequate ventilation, especially in confined areas. Keep containers tightly sealed. Personal Protective Equipment: Protective goggles. Gloves. Protective clothing. Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical goggles or face shield. Skin and Body Protection: Not available. Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits. Under normal conditions of use and handling there is minimal likelihood for the this exposure limit to be reached. Other Information: When using or handling, do not eat, drink or smoke. SDS# 1052 Date: 10/02/2018 Page 6 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Specific Gravity : 0.8 - 1.5 g/cc Solubility : Water: Nitrate salts are completely soluble, but emulsion dissolution is very slow. Partition coefficient: n-octanol/water : Not available Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not sensitive to mechanical impact. May be sensitive to supersonic explosively driven projectile impacts. . Explosion Data – Sensitivity to Static Discharge : Not sensitive to static discharge. SECTION 10 - STABILITY AND REACTIVITY Reactivity: May cause or intensify fire. May accelerate the burning of other combustible materials. Chemical Stability: May intensify fire. May explode when subjected to fire, supersonic shock or high-energy projectile impact, especially when confined or in large quantities. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Direct sunlight. Extremely high temperatures. Heat. Sparks. Overheating. Open flame. Combustible materials. Sources of ignition. Incompatible materials. Incompatible Materials: Corrosives, strong acids, strong bases and alkalis. Hazardous Decomposition Products: Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Nitrogen oxides. Toxic vapors. Ammonia. Carbon monoxide. SECTION 11 - TOXICOLOGICAL INFORMATION Under normal conditions of use, over-exposure is not expected to occur. Minor skin exposure is most likely. Information on Toxicological Effects - Product Acute Toxicity: Harmful if swallowed. LD50 and LC50 Data: ATE Oral 1,510 (mg/kg) Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: May cause eye irritation Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not available Carcinogenicity: Contains a substance which has been shown to cause cancer in laboratory animals. IARC Group 2A Probably carcinogenic to humans. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. SDS# 1052 Date: 10/02/2018 Page 7 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: May cause skin irritation. Symptoms/Injuries After Eye Contact: May cause eye irritation. Symptoms/Injuries After Ingestion: May be harmful if swallowed. May be harmful if swallowed and enters airways. Aspiration into the lungs can occur during ingestion or vomiting and may cause lung injury. Chronic Symptoms: May cause cancer. May cause damage to organs through prolonged or repeated exposure. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Ammonium nitrate (6484-52-2) LD50 Oral Rat 2217 mg/kg (REACH dossier 2950 mg/kg) LC50 Inhalation Rat > 88.8 mg/l/4h ATE CLP (oral) 2217.000 mg/kg body weight Sodium nitrate (7631-99-4) LD50 Oral Rat 1267 mg/kg (REACH dossier 3430 mg/kg) ATE CLP (oral) 1267.000 mg/kg body weight Fuels, diesel, no. 2 (68476-34-6) ATE CLP (vapors) 11.000 mg/l/4h Distillates, petroleum, chemically neutralized light naphthenic (64742-35-4) LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rabbit > 2000 mg/kg SECTION 12: ECOLOGICAL INFORMATION Toxicity Harmful to aquatic life with long lasting effects. Ammonium nitrate (6484-52-2) LC50 Fish 1 95-102 mg/l (Exposure time: 48 h - Cyprinus carpio (Common carp)) EC 50 Aquatic Invertebrates 490 mg/l (Exposure time 48 h - Daphnia magna) Sodium nitrate (7631-99-4) LC50 Fish 1 2000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) LC 50 Fish 2 994.4 - 1107 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) Fuels, diesel, no. 2 (68476-34-6) LC50 Fish 1 35 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) Calcium nitrate (10124-37-5) LC50 Fish 1 10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) Persistence and Degradability Bulk Emulsion Persistence and Degradability Not established. Sodium nitrate (7631-99-4) Persistence and Degradability Readily biodegradable in water. SDS# 1052 Date: 10/02/2018 Page 8 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Bioaccumulative Potential Bulk Emulsion Bioaccumulative Potential Not established. Ammonium nitrate (6484-52-2) BCF fish 1 (no bioaccumulation expected) Log Pow -3.1 (at 25 °C) Sodium nitrate (7631-99-4) Log Pow -3.8 (at 25 °C) Bioaccumulative Potential Not expected to bioaccumulate. Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13 – DISPOSAL CONSIDERATIONS Waste Treatment Methods: Contact manufacturer for advice on proper disposal methods. Waste Disposal Recommendations: Collect spillage for possible reuse. Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. Additional Information: Clean up even minor leaks or spills if possible without unnecessary risk. SECTION 14 - TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name : AMMONIUM NITRATE EMULSION Hazard Class : 5.1 Identification Number : UN3375 Label Codes : 5.1 Packing Group : II ERG Number : 140 14.2 In Accordance with IMDG Proper Shipping Name : AMMONIUM NITRATE EMULSION Hazard Class : 5.1 Identification Number : UN3375 Packing Group : II Label Codes : 5.1 EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q 14.3 In Accordance with IATA Proper Shipping Name : AMMONIUM NITRATE EMULSION Identification Number : UN3375 Hazard Class : 5 Label Codes : 5.1 ERG Code (IATA) : 5L 14.4 In Accordance with TDG No UN number exists for blasting intermediates for Transport Canada (use the following for Canadian shipments) Proper Shipping Name : EXPLOSIVE, BLASTING, TYPE E Packing Group : II Hazard Class : 1.5D Identification Number : UN0332 SDS# 1052 Date: 10/02/2018 Page 9 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Label Codes : 1.5D SECTION 15 - REGULATORY INFORMATION US Federal Regulations Bulk Emulsion SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Delayed (chronic) health hazard Fire hazard Ammonium nitrate (6484-52-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Sodium nitrate (7631-99-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Fuels, diesel, no. 2 (68476-34-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Calcium nitrate (10124-37-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, chemically neutralized light naphthenic (64742-35-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory US State Regulations Ammonium nitrate (6484-52-2) U.S. – California – Air Toxics “Hot Spots” (A-I) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List U.S. – Rhode Island – RTK (Right to Know) List Sodium nitrate (7631-99-4) U.S. - Massachusetts - Right To Know List U.S. - Pennsylvania - RTK (Right to Know) List U.S. – Rhode Island – RTK (Right to Know) List Fuels, diesel, no. 2 (68476-34-6) U.S. - New Jersey - Right to Know Hazardous Substance List Calcium nitrate (10124-37-5) U.S. - New Jersey - Right to Know Hazardous Substance List Canadian Regulations Bulk Emulsion WHMIS Classification Note: Explosives are not regulated under WHMIS. They are subject to the regulations of the Explosives Act of Canada. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date : 10/02/2018 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. SDS# 1052 Date: 10/02/2018 Page 10 of 10 Safety Data Sheet ssssSSherrSheetSSh eeSheet Disclaimer Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, the information contained herein, or the results to be obtained, whether express or implied, INCLUDING WITHOUT LIMITATION, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. The information contained herein is provided for reference purposes only and is intended only for persons having relevant technical skills. Because conditions and manner of use are outside of our control, the user is responsible for determining the conditions of safe use of the product. Buyers and users assume all risk, responsibility and liabili ty whatsoever from any and all injuries (including death), losses, or damages to persons or property arising from the use of thi s product or information. Under no circumstances shall either Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or incidental damages or for anticipated loss of profits. Dyno Nobel SDS GHS Full Text Phrases: Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 Asp. Tox. 1 Aspiration hazard Category 1 Carc. 2 Carcinogenicity Category 2 Eye Dam. 1 Serious eye damage/eye irritation Category 1 Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Flam. Liq. 3 Flammable liquids Category 3 Ox. Liq. 2 Oxidizing liquids Category 2 Ox. Sol. 3 Oxidizing solids Category 3 Skin Irrit. 2 Skin corrosion/irritation Category 2 STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 H205 May mass explode in fire H227 Combustible liquid H272 May intensify fire; oxidizer H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H332 Harmful if inhaled H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure H373 May cause damage to organs (Thymus, Liver, bone marrow) through prolonged or repeated exposure Party Responsible for the Preparation of This Document Dyno Nobel Inc. 2795 East Cottonwood Parkway, Suite 500 Salt Lake City, Utah 84121 Phone: 801-364-4800 SDS# 1355 Date: 03/06/2015 Page 1 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 1 – IDENTIFICATION Name, Address, and Telephone of the Responsible Party Dyno Nobel Inc. 2795 East Cottonwood Parkway, Suite 500 Salt Lake City, Utah 84121 Phone: 801-364-4800 Fax 801-321-6703 E-Mail: dnna.hse@am.dynonobel.com www.dynonobel.com SDS #: 1355 Date: 03/06/2015 Supercedes: 03/22/2013 Product Identifier Product Form: Mixture Product Name: 1355 Recycle Emulsion Product Code: 1355 Other Means of Identification Product Class: Recycle Emulsion Intended Use of the Product Industrial applications. Emergency Telephone Number FOR 24 HOUR EMERGENCY, CALL CHEMTREC (USA) 800-424-9300 CANUTEC (CANADA) 613-996-6666 SECTION 2 – HAZARD(S) IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Carc. 1A H350 STOT RE 2 H373 Asp. Tox. 1 H304 Aquatic Chronic 3 H412 Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS05 GHS07 GHS08 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H318 - Causes serious eye damage. H350 - May cause cancer. H373 - May cause damage to organs through prolonged or repeated exposure. H412 - Harmful to aquatic life with long lasting effects. Precautionary Statements (GHS-US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe vapors, spray, mist. P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, face protection, eye SDS# 1355 Date: 03/06/2015 Page 2 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary due to varying composition. protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER, a doctor. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P310 - Immediately call a POISON CENTER, a doctor. P314 - Get medical advice/attention if you feel unwell. P321 - Specific treatment (see Section 4). P330 - Rinse mouth. P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. Other Hazards Hazards Not Otherwise Classified (HNOC): Not available Other Hazards: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product identifier % (w/w) Ingredient Classification (GHS-US) Ammonium nitrate (CAS No) 6484-52-2 30 - 60 Ox. Sol. 3, H272 Eye Irrit. 2A, H319 Water (CAS No) 7732-18-5 35 - 45 Not classified Calcium nitrate (CAS No) 10124-37-5 < 0.1, 0.1 – 1, 1 - 5, 5 - 10, 10 - 30 Ox. Sol. 3, H272 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Sodium nitrate (CAS No) 7631-99-4 < 0.1, 0.1 – 1, 1 - 5, 5 - 10, 10 - 20 Ox. Sol. 3, H272 Eye Irrit. 2A, H319 Fuels, diesel, no. 2 (CAS No) 68476-34-6 < 0.1, 0.1 – 1, 1 - 5, 5 - 10 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Carc. 2, H351 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Acute 3, H402 Aquatic Chronic 2, H411 Distillates, petroleum, chemically neutralized light naphthenic (CAS No) 64742-35-4 < 0.1, 0.1 – 1, 1 - 5, 5 - 10 Carc. 1A, H350 Asp. Tox. 1, H304 Aluminum (CAS No) 7429-90-5 < 0.1, 0.1 – 1, 1 - 5 Comb. Dust, H232 Flam. Sol. 1, H228 Water-react. 2, H261 Full text of H-phrases: see section 16 SDS# 1355 Date: 03/06/2015 Page 3 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 4 - FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least 15 minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Eye Contact: Rinse cautiously with water for severa l minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 60 minutes. Immediately call a POISON CENTER or doctor/physician. Ingestion: Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor/physici an. Most Important Symptoms and Effects Both Acute and Delayed General: Causes skin irritation. Causes serious eye damage. May be fatal if swallowed and enters airways. May cause cancer. Harmful if swallowed. Inhalation: Harmful if inhaled. Skin Contact: Causes skin irritation. Eye Contact: Causes serious eye damage. Ingestion: The major health threat of ingestion occurs from the danger of aspiration(breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death. Harmful if swallowed. Chronic Symptoms: May cause cancer. May damage organs through prolonged or repeated exposure. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell, seek medical advice (show the label where possible). SECTION 5 - FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not considered flammable but may burn at high temperatures. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Carbon oxides (CO, CO2). Hydrocarbons. Nitrogen compounds. Reference to Other Sections: Refer to section 9 for flammability properties. SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing (vapor, mist, spray). For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. SDS# 1355 Date: 03/06/2015 Page 4 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet Emergency Procedures: Stop leak if safe to do so. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection SECTION 7 - HANDLING AND STORAGE Precautions for Safe Handling Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leav ing work. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Alkalis. Chromates, zinc, copper and copper alloys,chlorates. Specific End Use(s) Industrial applications. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Fuels, diesel, no. 2 (68476-34-6) USA ACGIH ACGIH TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Alberta OEL TWA (mg/m³) 100 mg/m³ British Columbia OEL TWA (mg/m³) 100 mg/m³ (aerosol, inhalable, and vapour) Manitoba OEL TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Newfoundland & Labrador OEL TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Nova Scotia OEL TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Ontario OEL TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Prince Edward Island OEL TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Saskatchewan OEL STEL (mg/m³) 150 mg/m³ (vapour) Saskatchewan OEL TWA (mg/m³) 100 mg/m³ (vapour) Aluminum (7429-90-5) Mexico OEL TWA (mg/m³) 10 mg/m³ (dust) USA ACGIH ACGIH TWA (mg/m³) 1 mg/m³ (respirable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) Alberta OEL TWA (mg/m³) 10 mg/m³ (dust) British Columbia OEL TWA (mg/m³) 1.0 mg/m³ (respirable) Manitoba OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 10 mg/m³ (metal dust) Newfoundland & OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) SDS# 1355 Date: 03/06/2015 Page 5 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Translucent to opaque viscous liquid. May be varied in color (tan, pink, cream, silver, etc.) Odor : May have a fuel odor Odor Threshold : Not available pH : Not available Evaporation Rate : Not available Melting Point : Not available Freezing Point : Not available Boiling Point : Not available Flash Point : > 100 °C (212 °F) Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Labrador Nova Scotia OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) Nunavut OEL STEL (mg/m³) 20 mg/m³ Nunavut OEL TWA (mg/m³) 10 mg/m³ Northwest Territories OEL STEL (mg/m³) 20 mg/m³ Northwest Territories OEL TWA (mg/m³) 10 mg/m³ Ontario OEL TWA (mg/m³) 1 mg/m³ (respirable) Prince Edward Island OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) Québec VEMP (mg/m³) 10 mg/m³ Saskatchewan OEL STEL (mg/m³) 20 mg/m³ (dust) Saskatchewan OEL TWA (mg/m³) 10 mg/m³ (dust) Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential e xposure. Ensure all national/local regulations are observed. Personal Protective Equipment: Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory protection. Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical goggles. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits. Environmental Exposure Controls: Do not allow the product to be released into the environment. Consumer Exposure Controls: Do not eat, drink or smoke during use SDS# 1355 Date: 03/06/2015 Page 6 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet Relative Vapor Density at 20 °C : Not applicable Relative Density : Not available Specific gravity / density : 1 - 1.4 g/cc Specific Gravity : Not available Solubility : Nitrate salts are completely soluble, but emulsion dissolution is very slow Partition Coefficient: N-octanol/water : Not available Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge. SECTION 10 - STABILITY AND REACTIVITY Reactivity: Hazardous reactions will not occur under normal conditions. Chemical Stability: Stable under recommended handling and storage conditions (see section 7). Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Ignition sources. Incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Hazardous Decomposition Products: Thermal decomposition generates : Carbon oxides (CO, CO2). Nitrogen oxides. SECTION 11 - TOXICOLOGICAL INFORMATION Information on Toxicological Effects - Product Acute Toxicity: Harmful if swallowed. LD50 and LC50 Data: 1355 Recycle Emulsion ATE US (oral) 500.00 mg/kg body weight Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not classified Carcinogenicity: May cause cancer. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Harmful if inhaled. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Symptoms/Injuries After Ingestion: The major health threat of ingestion occurs from the danger of aspiration(breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death. Harmful if swallowed. Chronic Symptoms: May cause cancer. May damage organs through prolonged or repeated exposure. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Ammonium nitrate (6484-52-2) LD50 Oral Rat 2217 mg/kg SDS# 1355 Date: 03/06/2015 Page 7 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet LC50 Inhalation Rat > 88.8 mg/l/4h Sodium nitrate (7631-99-4) LD50 Oral Rat > 2000 mg/kg Calcium nitrate (10124-37-5) ATE US (oral) 500.00 mg/kg body weight Fuels, diesel, no. 2 (68476-34-6) LD50 Oral Rat 18.7 - 24.9 ml/kg LD50 Dermal Rabbit > 4300 mg/kg ATE US (dust, mist) 1.50 mg/l/4h Distillates, petroleum, chemically neutralized light naphthenic (64742-35-4) LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rabbit > 2000 mg/kg SECTION 12: ECOLOGICAL INFORMATION Toxicity Ecology - General: Harmful to aquatic life with long lasting effects. Sodium nitrate (7631-99-4) LC50 Fish 1 2000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) LC 50 Fish 2 994.4 - 1107 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) Calcium nitrate (10124-37-5) LC50 Fish 1 10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) Fuels, diesel, no. 2 (68476-34-6) LC50 Fish 1 57 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) Persistence and Degradability Sodium nitrate (7631-99-4) Persistence and Degradability Readily biodegradable in water. Bioaccumulative Potential Ammonium nitrate (6484-52-2) BCF fish 1 (no bioaccumulation expected) Log Pow -3.1 (at 25 °C) Sodium nitrate (7631-99-4) Log Pow -3.8 (at 25 °C) Bioaccumulative Potential Not expected to bioaccumulate. Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. SECTION 14 - TRANSPORT INFORMATION In Accordance with DOT Not regulated for transport In Accordance with IMDG Not regulated for transport In Accordance with IATA Not regulated for transport In Accordance with TDG Not regulated for transport SDS# 1355 Date: 03/06/2015 Page 8 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 15 - REGULATORY INFORMATION US Federal Regulations 1355 Recycle Emulsion SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Ammonium nitrate (6484-52-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Sodium nitrate (7631-99-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Calcium nitrate (10124-37-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Fuels, diesel, no. 2 (68476-34-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, chemically neutralized light naphthenic (64742-35-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Aluminum (7429-90-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 1.0 % (dust or fume only) US State Regulations Ammonium nitrate (6484-52-2) U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 RTK - U.S. - Massachusetts - Right To Know List RTK - U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Special Health Hazards Substances List RTK - U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List RTK - U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Sodium nitrate (7631-99-4) RTK - U.S. - Massachusetts - Right To Know List RTK - U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Calcium nitrate (10124-37-5) RTK - U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Fuels, diesel, no. 2 (68476-34-6) SDS# 1355 Date: 03/06/2015 Page 9 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances U.S. - New Jersey - Environmental Hazardous Substances List RTK - U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - California - Safer Consumer Products - Initial List of Candidate Chemicals and Chemical Groups U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Distillates, petroleum, chemically neutralized light naphthenic (64742-35-4) U.S. - Maine - Chemicals of High Concern U.S. - Minnesota - Chemicals of High Concern Aluminum (7429-90-5) U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Colorado - Primary Drinking Water Regulations - Secondary Maximum Contaminant Levels (SMCLs) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr) U.S. - Connecticut - Water Quality Standards - Acute Freshwater Aquatic Life Criteria U.S. - Connecticut - Water Quality Standards - Chronic Freshwater Aquatic Life Criteria U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Florida - Drinking Water Standards - Secondary Maximum Contaminant Levels (SMCLs) U.S. - Georgia - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs) U.S. - Maryland - Surface Water Quality Standards - Acute Freshwater Aquatic Life U.S. - Maryland - Surface Water Quality Standards - Chronic Freshwater Aquatic Life U.S. - Massachusetts - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) RTK - U.S. - Massachusetts - Right To Know List U.S. - Massachusetts - Toxics Use Reduction Act U.S. - Michigan - Occupational Exposure Limits - TWAs U.S. - Minnesota - Hazardous Substance List U.S. - Minnesota - Permissible Exposure Limits - TWAs U.S. - Missouri - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) U.S. - Nevada - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) U.S. - New Hampshire - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances U.S. - New Jersey - Environmental Hazardous Substances List RTK - U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Secondary Drinking Water Standards - Recommended Upper Limits (RULs) U.S. - New Jersey - Special Health Hazards Substances List U.S. - New Jersey - Water Quality - Ground Water Quality Criteria U.S. - New Jersey - Water Quality - Practical Quantitation Levels (PQLs) U.S. - New Mexico - Water Quality - Standards for Ground Water of 10,000 mg/L TDS Concentration or Less U.S. - New York - Occupational Exposure Limits - TWAs U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour U.S. - Oregon - Permissible Exposure Limits - TWAs U.S. - California - Safer Consumer Products - Initial List of Candidate Chemicals and Chemical Groups U.S. - Pennsylvania - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) RTK - U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List RTK - U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Rhode Island - Water Quality Standards - Acute Freshwater Aquatic Life Criteria SDS# 1355 Date: 03/06/2015 Page 10 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet U.S. - Rhode Island - Water Quality Standards - Chronic Freshwater Aquatic Life Criteria U.S. - South Carolina - Secondary Maximum Contaminant Levels (SMCLs) U.S. - Tennessee - Occupational Exposure Limits - TWAs U.S. - Texas - Drinking Water Standards - Secondary Constituent Levels (SCLs) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term U.S. - Utah - Drinking Water - Secondary Maximum Contaminant Levels (SMCLs) U.S. - Vermont - Permissible Exposure Limits - TWAs U.S. - Washington - Permissible Exposure Limits - STELs U.S. - Washington - Permissible Exposure Limits - TWAs U.S. - Alaska - Water Quality Standards - Acute Aquatic Life Criteria for Fresh Water U.S. - Alaska - Water Quality Standards - Chronic Aquatic Life Criteria for Fresh Water Canadian Regulations 1355 Recycle Emulsion WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Ammonium nitrate (6484-52-2) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class C - Oxidizing Material Class D Division 2 Subdivision B - Toxic material causing other toxic effects Sodium nitrate (7631-99-4) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class C - Oxidizing Material Class D Division 2 Subdivision B - Toxic material causing other toxic effects Calcium nitrate (10124-37-5) Listed on the Canadian DSL (Domestic Substances List) Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Fuels, diesel, no. 2 (68476-34-6) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class B Division 3 - Combustible Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Distillates, petroleum, chemically neutralized light naphthenic (64742-35-4) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Aluminum (7429-90-5) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) SDS# 1355 Date: 03/06/2015 Page 11 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet IDL Concentration 1 % WHMIS Classification Class B Division 6 - Reactive Flammable Material Class B Division 4 - Flammable Solid This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date : 03/06/2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3 Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3 Asp. Tox. 1 Aspiration hazard Category 1 Carc. 1A Carcinogenicity Category 1A Carc. 2 Carcinogenicity Category 2 Comb. Dust Combustible Dust Eye Dam. 1 Serious eye damage/eye irritation Category 1 Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Flam. Liq. 3 Flammable liquids Category 3 Flam. Sol. 1 Flammable solids Category 1 Ox. Sol. 3 Oxidizing solids Category 3 Skin Irrit. 2 Skin corrosion/irritation Category 2 STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 Water-react. 2 Substances and mixtures which in contact with water emit flammable gases Category 2 H226 Flammable liquid and vapor H228 Flammable solid H232 May form combustible dust concentrations in air H261 In contact with water releases flammable gases H272 May intensify fire; oxidizer H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H332 Harmful if inhaled H350 May cause cancer H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure H402 Harmful to aquatic life H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects SDS# 1355 Date: 03/06/2015 Page 12 of 12 Safety Data Sheet ssssSSherrSheetSSh eeSheet Disclaimer Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, the information contained herein, or the results to be obtained, whether express or implied, INCLUDING WITHOUT LIMITATION, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. The information contained herein is provided for reference purposes only and is intended only for persons having relevant technical skills. Because conditions and manner of use are outside of our control, the user is responsible for determining the conditions of safe use of the product. Buyers and users assume all risk, responsibility and liability whatsoever from any and all injuries (including death), losses, or damages to persons or property arising from the use of thi s product or information. Under no circumstances shall either Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or incidental damages or for anticipated loss of profits. Dyno Nobel SDS NFPA Health Hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA Fire Hazard : 1 - Must be preheated before ignition can occur. NFPA Reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Party Responsible for the Preparation of This Document Dyno Nobel Inc. 2795 East Cottonwood Parkway, Suite 500 Salt Lake City, Utah 84121 Phone: 801-364-4800 SDS# 1020 Date: 07/20/2020 Page 1 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 1 – IDENTIFICATION Name, Address, and Telephone of the Responsible Party Dyno Nobel Inc. 6440 S. Millrock Drive, Suite 150 Salt Lake City, Utah 84121 Phone: 801-364-4800 Fax 801-321-6703 E-Mail: dnna.hse@am.dynonobel.com www.dynonobel.com SDS #: 1022 Date: 07/20/2020 Supersedes: 06/20/2015 Product Identifier Product Name: Ammonium Nitrate Other Means of Identification Synonyms: Superprill™, Prilled Ammonium Nitrate, Industrial Grade LoDAN, Ammonium Nitrate, Industrial Grade HiDAN, Ammonium Nitrate, Agricultural Grade Intended Use of the Product Industrial applications Emergency Telephone Number FOR 24 HOUR EMERGENCY, CALL CHEMTREC (USA) 800-424-9300 CANUTEC (CANADA) 613-996-6666 SECTION 2 – HAZARD(S) IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Ox. Sol. 3 H272 Eye Irrit. 2A H319 Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS03 GHS07 Signal Word (GHS-US) : Warning Hazard Statements (GHS-US) : H272 - May intensify fire; oxidizer H319 - Causes serious eye irritation Precautionary Statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking P220 - Keep/Store away from combustible materials, clothing, incompatible materials P221 - Take any precaution to avoid mixing with combustibles, organic material, clothing, incompatible materials P260 - Do not breathe fume, dust. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention P370+P378 - In case of fire: Use water only on AN fires. P405 - Store locked up. P501 - Dispose of contents/container according to local, regional, national, SDS# 1020 Date: 07/20/2020 Page 2 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet territorial, provincial, and international regulations* *Do not perform hot work on contaminated equipment. Other Hazards Other Hazards: Aquatic Acute 3 H402 H402 – Harmful to aquatic life SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product identifier % (w/w) Ingredient Classification (GHS-US) Ammonium nitrate (CAS No) 6484-52-2 98 - 100 Ox. Sol. 3, H272 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4 - FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Inhalation: If symptoms occur, go into fresh air and ventilate suspected area. Seek medical attention. Skin Contact: Remove contaminated clothing. Wash with soap and water followed by rinsing with water. Seek medical attention if irritation develops or persists. Wash contaminated clothing before reuse. Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. Ingestion: Rinse mouth. Do NOT induce vomiting. Seek medical attention. Most Important Symptoms and Effects Both Acute and Delayed General: Irritation to eyes, skin and respiratory tract. Inhalation: May cause irritation to the respiratory tract, sneezing, coughing, burning sensation of throat with constricting sensation of the larnyx and difficulty breathing. Skin Contact: May cause skin irritation. Eye Contact: Causes serious eye irritation. Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: None known. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. If ingested, may cause methemoglobenemia – emergency response should treat appropriately, such as by intravenous administration of methylene blue. SECTION 5 - FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Evacuate the area for 1 mile if ammonium nitrate is involved in a fire. Only water shall be used on ammonium nitrate fires. Dry chemical, foams, steam and smothering devices are not effective and can lead to possible explosion of the ammonium nitrate. General extinguishers may be used on fires not involving the ammonium nitrate such as conveyors, electrical equipment, tires, bearings, general plant equipment or the like when only minimal amounts of ammonium nitrate are present. For large fires use unmanned monitor nozzles if available. Unsuitable Extinguishing Media: Dry chemical, carbon dioxide, or regular foam. Special Hazards Arising From the Substance or Mixture In intense fires, the ammonium nitrate can melt and detonate from confinement or strong shocks. Evacuation of at least 1 mile is recommended if the ammonium nitrate is involved in a fire. Fire Hazard: May intensify fire; oxidizer. Will accelerate the burning of other combustibles, resulting in more rapid spread of fire. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and SDS# 1020 Date: 07/20/2020 Page 3 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet injuries. Smothering, contact with organic material, or combustible material may cause an explosive situation. Reactivity: May cause or intensify fire; oxidizer. May accelerate the burning of other combustible materials. Smothering, contact with organic material, or combustible material may cause an explosive situation. Advice for Firefighters Precautions for Firefighting: Evacuate the area for 1 mile if ammonium nitrate is involved in a fire. Only fires which are in the initial or beginning stage or those involving minimal amounts of ammonium nitrate in a manufacturing setting or in an area where ammonium nitrate is stored or in vehicles transporting ammonium nitrate should be attacked using manual fire extinguishing methods (fire extinguishers, hose streams, etc.) that require a human operator. If a fire in an area where ammonium nitrate is stored or in vehicles transporting ammonium nitrate progresses beyond the incipient stage or involves the ammonium nitrate, evacuation is required. Fire fighters downw ind from a fire should wear self- contained breathing apparatus. Fire fighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves and rubber boots. Hazardous Combustion Products: Nitrogen oxides. Toxic fumes are released. Carbon oxides (CO, CO2). Ammonia. Additional Information: If a fire has not reached the ammonium nitrate, cool the ammonium nitrate or container thereof to prevent the fire from reaching it. Ammonium nitrate does not burn by itself and thus needs to be kept separate from combustible materials. Ammonium nitrate is an oxidizer and will significantly increase the burning rate of combustible materials. When in confinement and in the presence of a strong detonation sources the material can explode when subject to sudden shock, pressure, or high temperatures. Avoid temperatures above 210 C (410 F) which may cause thermal decomposition or explosion, especially in confined or poorly ventilated spaces. Do not allow run-off from fire fighting to enter drains or water courses. Reference to Other Sections: Refer to section 9 for flammability properties. Not flammable. SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing (dust, vapor, mist, gas). Avoid getting in eyes or on skin. Keep away from combustible material. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Ventilate area. Environmental Precautions Prevent entry to sewers and public waters. Methods and Material for Containment and Cleaning Up For Containment: Avoid generation of dust during clean-up of spills. Use a broom for small spills do not mix with other materials. Methods for Cleaning Up: Collect spillage for possible reuse. Clean up spills immediately and dispose of waste safely. Contact competent authorities after a spill. Do not take up in combustible material such as: saw dust or cellulosic material. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection SECTION 7 - HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: When heated to decomposition, emits toxic fumes. Smothering, contact with organic material, or combustible material in a fire situation may be an explosive situation. Do not puncture or incinerate container. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. SDS# 1020 Date: 07/20/2020 Page 4 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Solid Appearance : Colorless to off-white prills Odor : Odorless Odor Threshold : Not available pH : Not available Relative Evaporation Rate (butylacetate=1) : Not available Melting Point : 170 °C (337°F) Freezing Point : Not available Boiling Point : 177 - 210 °C Decomposition (350 - 410°F) Flash Point : Not available Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not flammable Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations 29 CFR 1910.109(i). Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from combustible materials, ignition sources, and incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. halogens (F, Cl, Br, I). Chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. Organic materials. Combustible materials. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters No Occupational Exposure Limits (OELs) have been established for this product or its chemical components. Exposure Controls Appropriate Engineering Controls: Ensure all national/local regulations are observed. Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment: Approved safety glasses. Gloves. If insufficient ventilation: wear respiratory protection. Protective clothing when appropriate as indicated by air monitoring or if engineering controls are insufficient . Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Wear protective gloves. Eye Protection: Approved safety glasses Skin and Body Protection: Not available Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits. Other Information: When using, do not eat, drink or smoke. SDS# 1020 Date: 07/20/2020 Page 5 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet Specific Gravity : 1.72 - 1.00 (Poured bulk density) Solubility : Soluble in water. Water: 192 g/100 ml @ 20 °C (68 °F); 118 g/100 ml @ 0 °C (32 °F) Partition coefficient: n-octanol/water : Not applicable. (inorganic) Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not sensitive to mechanical impact. May be sensitive to supersonic explosively driven projectile impacts. Explosion Data – Sensitivity to Static Discharge : Not sensitive to static discharge. SECTION 10 - STABILITY AND REACTIVITY Reactivity: May cause or intensify fire; oxidizer. May accelerate the burning of other combustible materials. Smothering, contact with organic material, or combustible material may cause an explosive situation. Chemical Stability: May intensify fire; oxidizer. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Extremely high temperatures. Overheating. Open flame. Combustible materials. Sources of ignition. Incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Halogens. Chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. Hazardous Decomposition Products: Nitrogen oxides. Toxic vapors. Ammonia. Nitric acid SECTION 11 - TOXICOLOGICAL INFORMATION Information on Toxicological Effects – Product Acute Toxicity: Not classified LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not available Carcinogenicity: Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: May cause skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: None known. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Ammonium nitrate (6484-52-2) LD50 Oral Rat 2217 mg/kg LC50 Inhalation Rat > 88.8 mg/l/4h ATE CLP (oral) 2217.000 mg/kg body weight SECTION 12: ECOLOGICAL INFORMATION SDS# 1020 Date: 07/20/2020 Page 6 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet Toxicity Not classified Persistence and Degradability Superprill Persistence and Degradability Not established. Bioaccumulative Potential Superprill Bioaccumulative Potential Not established. Ammonium nitrate (6484-52-2) BCF fish 1 (no bioaccumulation expected) Log Pow -3.1 (at 25 °C) Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13 – DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Collect spillage for possible reuse. Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. Additional Information: Clean up even minor leaks or spills if possible without unnecessary risk. SECTION 14 - TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name : AMMONIUM NITRATE BASED FERTILIZER Hazard Class : 5.1 Identification Number : UN2067 Label Codes : 5.1 Packing Group : III ERG Number : 140 14.2 In Accordance with IMDG Proper Shipping Name : AMMONIUM NITRATE BASED FERTILIZER Hazard Class : 5.1 Identification Number : UN2067 Packing Group : III Label Codes : 5.1 EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q 14.3 In Accordance with IATA Proper Shipping Name : AMMONIUM NITRATE BASED FERTILIZER Packing Group : III Identification Number : UN2067 Hazard Class : 5 Label Codes : 5.1 ERG Code (IATA) : 5L 14.4 In Accordance with TDG SDS# 1020 Date: 07/20/2020 Page 7 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet Proper Shipping Name : AMMONIUM NITRATE BASED FERTILIZER Packing Group : III Hazard Class : 5.1 Identification Number : UN1942 Label Codes : 5.1 SECTION 15 - REGULATORY INFORMATION US Federal Regulations Superprill SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Ammonium nitrate (6484-52-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory US State Regulations Ammonium nitrate (6484-52-2) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Canadian Regulations Superprill WHMIS Classification Class C - Oxidizing Material Class D Division 2 Subdivision B - Toxic material causing other toxic effects Ammonium nitrate (6484-52-2) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Class C - Oxidizing Material Class D Division 2 Subdivision B - Toxic material causing other toxic effects This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date : 07/20/2020 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Ox. Sol. 3 Oxidizing solids Category 3 H272 May intensify fire; oxidizer H319 Causes serious eye irritation SDS# 1020 Date: 07/20/2020 Page 8 of 8 Safety Data Sheet ssssSSherrSheetSSh eeSheet Disclaimer Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, the information contained herein, or the results to be obtained, whether express or implied, INCLUDING WITHOUT LIMITATION, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. The information contained herein is provided for reference purposes only and is intended only for persons having relevant technical skills. Because conditions and manner of use are outside of our control, the user is responsible for determining the conditions of safe use of the product. Buyers and users assume all risk, responsibility and liability whatsoever from any and all injuries (including death), losses, or damages to persons or property arising from the use of thi s product or information. Under no circumstances shall either Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or incidental damages or for anticipated loss of profits. Dyno Nobel SDS NFPA Health Hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA Fire Hazard : 0 - Materials that will not burn. NFPA Reactivity : 3 - Capable of detonation or explosive reaction, but requires a strong initiating source or must be heated under confinement before initiation, or reacts explosively with water. NFPA Specific Hazard : OX - This denotes an oxidizer, a chemical which can greatly increase the rate of combustion/fire. Party Responsible for the Preparation of This Document Dyno Nobel Inc. 6440 S. Millrock Drive, Suite 150 Salt Lake City, Utah 84121 Phone: 801-364-4800 Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Product Regulations (WHMIS 2015) Revision Date: September 2018 Version: 1.0 September 2018 EN (English US) 1/7 SECTION 1: IDENTIFICATION Product Identifier Product Name: Ammonium Nitrate Solution, 83% Synonyms: Liquid Ammonium Nitrate Intended Use of the Product Not available Name, Address, and Telephone of the Responsible Party Company Cherokee Nitrogen L.L.C. 1080 Industrial Drive Cherokee, AL 35616 T (256) 359-7000 – F (256) 359-4450 Emergency Telephone Number Emergency number : (256) 359-7000, (800) 424-9300 (CHEMTREC, 24 hours) SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US/WHMIS 2015) Ox. Liq. 3 H272 Eye Irrit. 2A H319 Label Elements GHS-US Labeling Hazard Pictograms (GHS-US/WHMIS 2015) : GHS03 GHS07 Signal Word (GHS-US) : Warning Hazard Statements (GHS-US/WHMIS 2015) : H272 - May intensify fire; oxidizer H319 - Causes serious eye irritation Precautionary Statements (GHS- US/WHMIS 2015) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P220 - Keep/Store away from combustible materials, clothing, incompatible materials. P221 - Take any precaution to avoid mixing with combustibles, organic material, clothing, incompatible materials. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling . P280 - Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use appropriate media for extinction. P501 - Dispose of contents/container to local, regional, national, territorial, provincial, and international regulations. Other Hazards Other Hazards Not Contributing to the Classification : Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. Unknown Acute Toxicity (GHS-US/WHMIS 2015) Not available Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Products Regulations (WHMIS 2015) September 2018 EN (English US) 2/7 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Substances Mixture Name Product identifier % (w/w) Classification (GHS-US) Ammonium nitrate (CAS No) 6484-52-2 80 - 88 Ox. Sol. 3, H272 Eye Irrit. 2A, H319 Water (CAS No) 7732-18-5 12 - 20 Not classified Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists. Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation develops or persists. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. Ingestion: Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately. Most Important Symptoms and Effects Both Acute and Delayed General: Eye irritation. Inhalation: May cause respiratory irritation. Skin Contact: May cause skin irritation. Eye Contact: Causes serious eye irritation. Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: Not available Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. Hot Ammonium Nitrate burns skin, allowing rapid absorption of Ammonium Nitrate through the skin and toxic effects can occur quite rapidly. Causes methemoglobenemia – emergency response should treat appropriately. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Special Hazards Arising From the Substance or Mixture Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Nitrogen oxides. Toxic fumes are released. Ammonia. Other information: Do not add water to molten material as this may cause spattering. Do not allow run-off from fire fighting to enter drains or water courses. Suitable Extinguishing Media: Water spray. Unsuitable Extinguishing Media: Dry chemical, carbon dioxide, or regular foam. Fire Hazard: May intensify fire; oxidizer. Will burn if exposed to heat, and in addi tion, will accelerate the burning of other combustibles, resulting in more rapid spread of fire. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Smothering, contact with organic material, or combustible material may cause an explosive situation. Reactivity: May cause or intensify fire; oxidizer. May accelerate the burning of other combustible materials. Smothering, contact with organic material, or combustible material may cause an explosive situation. Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Products Regulations (WHMIS 2015) September 2018 EN (English US) 3/7 Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing (vapors, mist, spray). Do not get in eyes, on skin, or on clothing. Keep away from combustible material. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Use appropriate personal protection equipment (PPE). Emergency Procedures: Ventilate area. Environmental Precautions Prevent entry to sewers and public waters. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb and/or contain spill with inert material, then place in suitable container. Contact competent authorities after a spill. Do not take up in combustible material such as: saw dust or cellulosic material. Reference to Other Sections See section 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: When heated to decomposition, emits toxic fumes. Smothering, contact with organic material, or combustible material may cause an explosive situation. . Do not puncture or incinerate container. Handling Temperature: Should be kept from 71.1°C-107.2°C (160-225°F) to be kept fluid and pumpable. Keep below 204.4°C (400°F), becomes unstable above this temperature. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place. Keep/Store away from combustible materials, extremely high or low temperatures, direct sunlight, ignition sources, incompatible materials. Storage should be designed for the safe release of pressure. Floor drains and recessed areas should be plugged or eliminated to prevent entrapment of solution. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Halogens (F, Cl, Br, I). Chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. Organic materials. Combustible materials. Storage Temperature: < 204.4 °C (400°F) (becomes unstable above this temperature) Specific End Use(s) Not available SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters No additional information available Exposure Controls Appropriate Engineering Controls: Ensure all national/local regulations are observed. Ensure adequate ventilation, especially in confined areas. Use explosion-proof equipment. Personal Protective Equipment: Protective goggles. Gloves. Insufficient ventilation: wear respiratory protection. Protective clothing. Materials for Protective Clothing: Chemically resistant materials and fabrics. Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Products Regulations (WHMIS 2015) September 2018 EN (English US) 4/7 Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical goggles or face shield. Skin and Body Protection: Neoprene, nitrile or PVC gloves and protective clothing recommended. Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits. Other Information: When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Clear Odor : Trace odor of ammonia Odor Threshold : Not available pH : 4.5 – 6.0 Relative Evaporation Rate (butylacetate=1) : Not available Melting Point : 70 - 80.6 °C (158°F - 177°F) Freezing Point : Not available Boiling Point : 132.8 - 137.8 °C (271°F - 280°F) Flash Point : Not available Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Specific Gravity : ~ 1.4 @212°F Solubility : Complete. Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not available Explosion Data – Sensitivity to Static Discharge : Not available SECTION 10: STABILITY AND REACTIVITY Reactivity: May cause or intensify fire; oxidizer. May accelerate the burning of other combustible materials. Smothering, contact with organic material, or combustible material may cause an explosive situation. Chemical Stability: May intensify fire; oxidizer. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Overheating. Open flame. Combustible materials. Sources of ignition. Incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Halogens. Chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. Combustible materials. Organic materials. Hazardous Decomposition Products: Nitrogen oxides. Toxic vapors. Ammonia. Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Products Regulations (WHMIS 2015) September 2018 EN (English US) 5/7 SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects - Product LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified pH: 4.5 – 6.0 Serious Eye Damage/Irritation: Causes serious eye irritation. pH: 4.5 – 6.0 Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not available Carcinogenicity: Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: May cause skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Water (7732-18-5) LD50 Oral Rat > 90000 mg/kg Ammonium nitrate (6484-52-2) LD50 Oral Rat 2217 mg/kg LC50 Inhalation Rat (mg/l) > 88.8 mg/l/4h SECTION 12: ECOLOGICAL INFORMATION Toxicity Not classified Persistence and Degradability Ammonium Nitrate Solution (Conc.) Persistence and Degradability Not established. Bioaccumulative Potential Ammonium Nitrate Solution (Conc.) Bioaccumulative Potential Not established. Ammonium nitrate (6484-52-2) BCF fish 1 (no bioaccumulation expected) Log Pow -3.1 (at 25 °C) Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. Additional Information: Clean up even minor leaks or spills if possible without unnecessary risk. Acute Toxicity: Not classified Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Products Regulations (WHMIS 2015) September 2018 EN (English US) 6/7 SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name : AMMONIUM NITRATE, LIQUID (hot concentrated solution) Hazard Class : 5.1 Identification Number : UN2426 Label Codes : 5.1 ERG Number : 140 14.2 In Accordance with IMDG Proper Shipping Name : AMMONIUM NITRATE, LIQUID (hot concentrated solution) Hazard Class : 5.1 Identification Number : UN2426 Label Codes : 5.1 EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q 14.3 In Accordance with IATA Proper Shipping Name : AMMONIUM NITRATE, LIQUID (hot concentrated solution) Identification Number : UN2426 Hazard Class : 5 Label Codes : 5.1 ERG Code (IATA) : 5L 14.4 In Accordance with TDG Proper Shipping Name : AMMONIUM NITRATE, LIQUID (hot concentrated solution) Hazard Class : 5.1 Identification Number : UN2426 Label Codes : 5.1 SECTION 15: REGULATORY INFORMATION US Federal Regulations Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Ammonium nitrate (6484-52-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory US State Regulations Ammonium nitrate (6484-52-2) U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 RTK - U.S. - Massachusetts - Right To Know List RTK - U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Special Health Hazards Substances List RTK - U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List RTK - U.S. - Pennsylvania - RTK (Right to Know) List Ammonium Nitrate Solution (Conc.) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Ammonium Nitrate Solution, 83% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and Canada Hazardous Products Regulations (WHMIS 2015) September 2018 EN (English US) 7/7 U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Canadian Regulations Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Uncontrolled product according to WHMIS classification criteria Ammonium nitrate (6484-52-2) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Class C - Oxidizing Material Class D Division 2 Subdivision B - Toxic material causing other toxic effects This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date : September 2018 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 and Canada Hazardous Products Regulations (WHMIS 2015) GHS Full Text Phrases: ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Ox. Liq. 3 Oxidizing liquids Category 3 ------ Ox. Sol. 3 Oxidizing solids Category 3 ------ H272 May intensify fire; oxidizer ------ H319 Causes serious eye irritation NFPA Health Hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA Fire Hazard : 0 - Materials that will not burn. NFPA Reactivity : 3 - Capable of detonation or explosive reaction, but requires a strong initiating source or must be heated under confinement before initiation, or reacts explosively with water. NFPA Specific Hazard : OX - This denotes an oxidizer, a chemical which can greatly increase the rate of combustion/fire. Party Responsible for the Preparation of This Document Cherokee Nitrogen L.L.C. 1080 Industrial Drive Cherokee, AL 35616 T (256) 359-7000 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. North America GHS US 2012 & WHMIS 2 Ammonium Nitrate Solution (Conc.) WHMIS Classification Class C - Oxidizing Material Class D Division 2 Subdivision B - Toxic material causing other toxic effects Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.1200) Product Identifier: No. 2 Diesel Fuel Other means of identification: #2DSL ULS (All Grades); #2DSL HS (All Grades); #2DSL LS (All Grades); CARB DSL (All Grades); DIST CARB-Diesel (All Grades); Distillate,Diesel (All Grades); Gas Oil (All Grades); Hydrodewaxer Diesel (All Grades); Diesel Fuel (All Grades); EPA Diesel Fuel (All Grades); No. 2 Diesel (All Grades); No. 2 Diesel Fuel Oil (All Grades); No. 2 Distillate; No. 2 Diesel with Renewable Diesel (All Grades); Super Diesel Fuel (All Grades); Distillate Blend Stock; Fuels, Diesel; Virgin Diesel Fuel; PCR - HOD – Heating Oil Distillate SDS Number: 311 MARPOL Annex I Category: Gas Oils, Including Ship's Bunkers Relevant identified uses: Fuel Uses Advised Against: All others 24 Hour Emergency Phone Number: INFOTRAC: 800-535-5053 Supplied for: RelaDyne, LLC 8280 Montgomery Road, Suite 101 Cincinnati, OH 45236 SDS Information: Phone: 888-830-3156 Email: sales@reladyne.com URL: www.reladyne.com Classified Hazards Other Hazards H226 -- Flammable liquids -- Category 3 H315 -- Skin corrosion/irritation -- Category 2 H304 -- Aspiration Hazard -- Category 1 H332 -- Acute toxicity, Inhalation -- Category 4 H373 -- Specific target organ toxicity (repeated exposure) -- Category 2 H351 -- Carcinogenicity -- Category 2 H411 -- Hazardous to the aquatic environment, chronic toxicity -- Category 2 Electrostatic charge may be generated during pumping and other operations _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 001847 - No. 2 Diesel Fuel Page 1/9 Date of Issue: 06-Apr-2015 SDS#: 311 Label Elements DANGER Flammable liquid and vapor Causes skin irritation May be fatal if swallowed and enters airways Harmful if inhaled May cause damage to organs through prolonged or repeated exposure Suspected of causing cancer Toxic to aquatic life with long lasting effects Obtain special instructions before use; Do not handle until all safety precautions have been read and understood; Keep away from heat/sparks/open flames/hot surfaces. - No smoking; Ground/bond container and receiving equipment; Use only non-sparking tools; Take precautionary measures against static discharge; Do not breathe dust/fume/gas/mist/vapours/spray; Wash skin thoroughly after handling; Use only outdoors or in a well-ventilated area; Avoid release to the environment; Wear protective gloves/protective clothing and eye/face protection; IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician; Do NOT induce vomiting; IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower; IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing; Call a POISON CENTER or doctor/physician if you feel unwell; Take off contaminated clothing and wash before reuse; In case of fire: Use CO2, dry chemical, or foam for extinction; Store in a well-ventilated place. Keep cool; Dispose of contents/ container to an approved waste disposal plant SECTION 2: Hazard identification SECTION 1: Identification 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 2/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Chemical Name CASRN Concentration¹ Fuels, diesel, no. 2 68476-34-6 95-100 Naphthalene 91-20-3 <1 ¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention. Skin Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician. (see Note to Physician) Inhalation (Breathing): If respiratory symptoms or other symptoms of exposure develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. If symptoms persist, seek immediate medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Ingestion (Swallowing): Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek medical attention. Most important symptoms and effects, both acute and delayed: While significant vapor concentrations are not likely, high concentrations can cause minor respiratory irritation, headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Ingestion can cause irritation of the digestive tract, nausea, diarrhea, and vomiting. Dry skin and possible irritation with repeated or prolonged exposure. Notes to Physician: When using high-pressure equipment, injection of product under the skin can occur. In this case, the casualty should be sent immediately to the hospital. Do not wait for symptoms to develop. High-pressure hydrocarbon injection injuries may produce substantial necrosis of underlying tissue despite an innocuous appearing external wound. These injuries often require extensive emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of injury. Early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. NFPA 704 Hazard Class Health: 1 Flammability: 2 Instability: 0 0 (Minimal) 1 (Slight) 2 (Moderate) 3 (Serious) 4 (Severe) Extinguishing Media: Dry chemical, carbon dioxide, or foam is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Water may be ineffective for extinguishment, unless used under favorable conditions by experienced fire fighters. Specific hazards arising from the chemical SECTION 5: Firefighting measures SECTION 4: First aid measures SECTION 3: Composition/information on ingredients 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 3/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Unusual Fire & Explosion Hazards: Flammable. This material can be ignited by heat, sparks, flames, or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, and electronic devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically safe). Vapors may travel considerable distances to a source of ignition where they can ignite, flash back, or explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. This product will float and can be reignited on surface water. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire. Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of nitrogen and sulfur may also be formed. Special protective actions for firefighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits Personal precautions, protective equipment and emergency procedures: Flammable. Spillages of liquid product will create a fire hazard and may form an explosive atmosphere. Keep all sources of ignition and hot metal surfaces away from spill/release if safe to do so. The use of explosion-proof electrical equipment is recommended. Stay upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). See Sections 2 and 7 for additional information on hazards and precautionary measures. Environmental Precautions: Stop and contain spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use foam on spills to minimize vapors Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center (phone number 800-424-8802). Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand or vermiculite, and place in suitable container for disposal. If spilled on water remove with appropriate methods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations. Recommended measures are based on the most likely spillage scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. SECTION 7: Handling and storage SECTION 6: Accidental release measures 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 4/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Precautions for safe handling: Keep away from ignition sources such as heat/sparks/open flame – No smoking. Take precautionary measures against static discharge. Nonsparking tools should be used. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe vapors or mists. Use only outdoors or in well-ventilated area. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment (see section 8). Flammable. May vaporize easily at ambient temperatures. The vapor is heavier than air and may create an explosive mixture of vapor and air. Beware of accumulation in confined spaces and low lying areas. Open container slowly to relieve any pressure. The use of explosion-proof electrical equipment is recommended and may be required (see appropriate fire codes). Refer to NFPA-70 and/or API RP 2003 for specific bonding/grounding requirements. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. Keep contaminated clothing away from sources of ignition such as sparks or open flames. High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious consequences even though no symptoms or injury may be apparent. This can happen accidentally when using high pressure equipment such as high pressure grease guns, fuel injection apparatus or from pinhole leaks in tubing of high pressure hydraulic oil equipment. For use as a motor fuel only. Do not use as a solvent due to its flammable and potentially toxic properties. Siphoning by mouth can result in lung aspiration which can be harmful or fatal. The use of hydrocarbon fuel in an area without adequate ventilation may result in hazardous levels of incomplete combustion products (e.g. carbon monoxide, oxides of sulfur and nitrogen, benzene and other hydrocarbons) and/or dangerously low oxygen levels. Diesel engine exhaust contains hazardous combustion products and has been identified as a cancer hazard. Exposure should be minimized to reduce potential risk. Static Accumulation Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding of tanks, transfer piping, and storage tank level floats are necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. Special care should be given to ensure that special slow load procedures for "switch loading" are followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil or diesel) is loaded into tanks previously containing low flash point products (such as gasoline or naphtha). For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. Conditions for safe storage: Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved containers. Post area "No Smoking or Open Flame." Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Outdoor or detached storage is preferred. Indoor storage should meet OSHA standards and appropriate fire codes. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Chemical Name ACGIH OSHA Other Fuels, diesel, no. 2 TWA: 100 mg/m3 --- 100 mg/m3 TWA8hr Skin 50 mg/m3 TWA12hr 13 ppm TWA8hr 6.5 ppm TWA12hr (Phillips 66 Guidelines) SECTION 8: Exposure controls/personal protection 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 5/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Naphthalene STEL: 15 ppm TWA: 10 ppm 10 ppm TWA; skin; A3 - confirmed animal carcinogen with unknown relevance to humans; TLV basis: upper respiratory tract irritation Skin TWA: 10 ppm : 50 mg/m3 --- Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary. Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits. Suggested protective materials: Nitrile Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with organic vapor cartridges/canisters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health (IDLH). Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. Appearance: Straw colored to dyed red Flash Point: 125 - 180 °F / 52 - 82 °C Physical Form: Liquid Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 Odor: Diesel fuel Initial Boiling Point/Range: 300 - 690 °F / 149 - 366 °C Odor Threshold: No data Vapor Pressure: 0.40 mm Hg pH: Not applicable Partition Coefficient (n-octanol/water) (Kow): No data Vapor Density (air=1): > 3 Melting/Freezing Point: No data Upper Explosive Limits (vol % in air): 10.0 Auto-ignition Temperature: 500 °F / 260 °C Lower Explosive Limits (vol % in air): 0.3 Decomposition Temperature: No data Evaporation Rate (nBuAc=1): <1 Specific Gravity (water=1): 0.81-0.88 @ 60ºF (15.6ºC) Particle Size: Not applicable Bulk Density: 7.08 lbs/gal Percent Volatile: Negligible @ ambient conditions Viscosity: N/D Flammability (solid, gas): Not applicable Solubility in Water: Negligible Reactivity: Not chemically reactive. Chemical stability: Stable under normal ambient and anticipated conditions of use. Possibility of hazardous reactions: Hazardous reactions not anticipated. Conditions to avoid: Avoid high temperatures and all sources of ignition. Prevent vapor accumulation. SECTION 10: Stability and reactivity SECTION 9: Physical and chemical properties 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 6/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Incompatible materials: Avoid contact with strong oxidizing agents and strong reducing agents. Hazardous decomposition products: Not anticipated under normal conditions of use. Information on Toxicological Effects Substance / Mixture Aspiration Hazard: May be fatal if swallowed and enters airways. Skin Corrosion/Irritation: Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Causes mild eye irritation. Skin Sensitization: Not expected to be a skin sensitizer. Respiratory Sensitization: Not expected to be a respiratory sensitizer. Specific Target Organ Toxicity (Single Exposure): Not expected to cause organ effects from single exposure. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Repeated dermal application of petroleum gas oils for 90 days resulted in decreased liver, thymus, and spleen weights, and altered bone marrow function. Microscopic alterations included liver hypertrophy and necrosis, decreased hematopoesis and lymphocyte depletion. Carcinogenicity: Suspected of causing cancer. Petroleum middle distillates have been shown to cause skin tumors in mice following repeated and prolonged skin contact. Follow-up studies have shown that these tumors are produced through a non-genotoxic mechanism associated with frequent cell damage and repair, and that they are not likely to cause tumors in the absence of prolonged skin irritation. Germ Cell Mutagenicity: Not expected to cause heritable genetic effects. Reproductive Toxicity: Not expected to cause reproductive toxicity. Other Comments: Diesel engine exhaust has been classified by the International Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a carcinogen. Information on Toxicological Effects of Components Naphthalene Carcinogenicity: Naphthalene has been evaluated in two year inhalation studies in both rats and mice. The US National Toxicology Program (NTP) concluded that there is clear evidence of carcinogenicity in male and female rats based on increased incidences of respiratory epithelial adenomas and olfactory epithelial neuroblastomas of the nose. NTP found some evidence of carcinogenicity in female mice (alveolar adenomas) and no evidence of carcinogenicity in male mice. Naphthalene has been identified as a carcinogen by IARC and NTP. GHS Classification: H411 -- Hazardous to the aquatic environment, chronic toxicity -- Category 2 Toxic to aquatic life with long lasting effects. SECTION 12: Ecological information SECTION 11: Toxicological information Acute Toxicity Hazard Additional Information LC50/LD50 Data Inhalation Harmful if inhaled 4.65 mg/L (mist) Dermal Unlikely to be harmful >2 g/kg Oral Unlikely to be harmful > 5 g/kg 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 7/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Toxicity: Experimental studies of gas oils show that acute aquatic toxicity values are typically in the range 2-20 mg/L. These values are consistent with the predicted aquatic toxicity of these substances based on their hydrocarbon compositions. They should be regarded as toxic to aquatic organisms, with the potential to cause long term adverse effects in the aquatic environment. Persistence and Degradability: Gas oils are complex combinations of individual hydrocarbon species. Based on the known or expected properties of individual constituents, category members are not predicted to be readily biodegradable. Some hydrocarbon constituents of gas oils are predicted to meet the criteria for persistence; on the other hand, some components can be easily degraded by microorganisms under aerobic conditions. Persistence per IOPC Fund definition: Non-Persistent Bioaccumulative Potential: Gas oil components have measured or calculated Log Kow values in the range of 3.9 to 6 which indicates a high potential to bioaccumulate. Lower molecular weight compounds are readily metabolized and the actual bioaccumulation potential of higher molecular weight compounds is limited by the low water solubility and large molecular size. Mobility in Soil: Releases to water will result in a hydrocarbon film floating and spreading on the surface. For the lighter components, volatilization is an important loss process and reduces the hazard to aquatic organisms. In air, the hydrocarbon vapors react readily with hydroxyl radicals with half-lives of less than one day. Photoxidation on the water surface is also a significant loss process particularly for polycyclic aromatic compounds. In water, the majority of components will be adsorbed on sediment. Adsorption is the most predominant physical process on release to soil. Adsorbed hydrocarbons will slowly degrade in both water and soil. Other adverse effects: None anticipated. The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste. However, it would likely be identified as a federally regulated RCRA hazardous waste for the following characteristic(s) shown below. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the SDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste.Container contents should be completely used and containers should be emptied prior to discard. Container residues and rinseates could be considered to be hazardous wastes. EPA Waste Number(s) • D001 - Ignitability characteristic UN Number: UN1202 UN proper shipping name: Diesel fuel Transport hazard class(es): 3 or Combustible liquid Packing Group: III Environmental Hazards: Marine pollutant - Environmentally Hazardous Special precautions for user: Combustible liquid classification is dependent on a flash point of >60° C (140° F) and <93° C (200° F). **NA1993 may be used instead of UN1202 for domestic land transportation. If transported in bulk by marine vessel in international waters, product is being carried under the scope of MARPOL Annex I. Container(s) greater than 5 liters (liquids) or 5 kilograms (solids), shipped by water mode and ALL bulk shipments may require the shipping description to contain the "Marine Pollutant" notation [49 CFR 172.203(l)] and the container(s) to display the [Marine Pollutant Mark] [49 CFR 172.322]. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds): This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/312 (Title III Hazard Categories) SECTION 15: Regulatory information SECTION 14: Transport information SECTION 13: Disposal considerations 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 8/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Acute Health Hazard: Yes Chronic Health Hazard: Yes Fire Hazard: Yes Pressure Hazard: No Reactive Hazard: No CERCLA/SARA - Section 313 and 40 CFR 372: This material contains the following chemicals subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR 372: Chemical Name Concentration¹ de minimis Naphthalene <1 0.1% EPA (CERCLA) Reportable Quantity (in pounds): EPA's Petroleum Exclusion applies to this material - (CERCLA 101(14)). California Proposition 65: Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the warning requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Chemical Name Type of Toxicity Naphthalene Cancer Diesel engine exhaust is on the Proposition 65 list of chemicals known to the State of California to cause cancer. International Hazard Classification Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the Regulations. WHMIS Hazard Class: B3 - Combustible liquid D1B - Toxic materials D2A - Very toxic materials D2B - Toxic materials International Inventories All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are either on the DSL, or are exempt from DSL listing requirements. U.S. Export Control Classification Number: EAR99 Date of Issue: Previous Issue Date: SDS Number: Status: 06-Apr-2015 01-Oct-2014 001847 FINAL Revised Sections or Basis for Revision: Technical Information (Section 1); Identified Hazards (Section 2); Environmental hazards (Section 12); Shipping information (Section 14) Guide to Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; GHS = Globally Harmonized System; IARC = International Agency for Research on Cancer; INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) SECTION 16: Other information 001847 - No. 2 Diesel Fuel Date of Issue: 06-Apr-2015 Page 9/9 SDS#: 311 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Disclaimer of Expressed and implied Warranties: The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. EMRO 60 HT Safety Data Sheet 11/11/2015 EN (English US) Page 1 SECTION 1: Identification 1.1. Identification Product name : EMRO 60 HT Other means of identification : EMRO 60 DC, EMRO 60 TO 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Manufacturing 1.3. Details of the supplier of the safety data sheet Environmental Management of KC, Inc. 861 S. 66th Terrace Kansas City, KS 66111 T 913-287-1575 1.4. Emergency telephone number Emergency number : 1-800-229-5252 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Distillates, petroleum, hydrotreated light naphthenic (CAS No) 64742-53-6 100 Not classified Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. First-aid measures after skin contact : Wash thoroughly with soap and water. Remove contaminated clothing. First-aid measures after eye contact : Wash with water. If irritation or redness persists seek medical help. First-aid measures after ingestion : If swallowed, observe for signs of stomach discomfort or nausea. If symptoms persist, seek medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : None under normal use. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms/injuries after ingestion : May be harmful if swallowed. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available EMRO 60 HT Safety Data Sheet 11/11/2015 EN (English US) 2/4 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Halon, dry chemical, foam, carbon dioxide, and water mist or fog. Unsuitable extinguishing media : Do not use forced stream as this could cause fire to spread. 5.2. Special hazards arising from the substance or mixture Fire hazard : When heated to decomposition, emits toxic fumes, smoke and carbon monoxide. Explosion hazard : None known. 5.3. Advice for firefighters Protection during firefighting : Firefighters should wear full protective gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel No additional information available 6.1.2. For emergency responders No additional information available 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment : Stop the flow of material, if this is without risk. Methods for cleaning up : Eliminate sources of ignition. Use non-flammable absorbent material. Dispose of waste in accordance with local, state and federal regulations. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Never use a torch to cut or weld on or near container. Empty oil containers can contain explosive vapors. Wash thoroughly after handling. Wash hands with soap and water before eating, drinking, smoking or use of toilet facilities. Do not use gasoline, kerosene, solvents or harsh abrasive skin cleaners for washing exposed skin areas. Take a shower after work if general contact occurs. Remove oil-soaked clothing and launder before reuse. Discard contaminated shoes and leather gloves. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep away from flames, sparks or hot surfaces. NFPA Class IIIB storage. SECTION 8: Exposure controls/personal protection 8.1. Control parameters No additional information available 8.2. Exposure controls Appropriate engineering controls : Adequate ventilation is required where excessive heating or agitation may occur to maintain concentration below exposure limits. Hand protection : As needed to prevent repeated skin contact. Solvent resistant gloves should be used. Eye protection : Safety glasses or face shield where splashing is possible. Skin and body protection : Wear suitable working clothes. Respiratory protection : Not normally needed. Respirator should be used in areas where vapor concentrations are excessive due to high temperatures or where oil misting occurs. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Clear, bright straw Odor : Mild petroleum EMRO 60 HT Safety Data Sheet 11/11/2015 EN (English US) 3/4 Odor threshold : No data available pH : 7.29 Melting point : - 55 °C (-40°F) Freezing point : No data available Boiling point : 260 - 370 °C (500-700°F) Flash point : 145 °C (295°F) Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : No data available Explosion limits : 0.6 - 7 vol % Explosive properties : No data available Oxidizing properties : No data available Vapor pressure : < 0.2 PSIA Relative density : > 1 Relative vapor density at 20 °C : No data available Specific gravity / density : 0.88 Solubility : Negligible. Log Pow : No data available Auto-ignition temperature : 410 °C (770°F) Decomposition temperature : > 482 °C (>900°F) Viscosity : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions Will not occur. 10.4. Conditions to avoid Heat, flames, and other ignition sources. 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Combustion products include carbon dioxide and carbon monoxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation : Not classified pH: 7.29 Serious eye damage/irritation : Not classified pH: 7.29 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified EMRO 60 HT Safety Data Sheet 11/11/2015 EN (English US) 4/4 Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified SECTION 12: Ecological information 12.1. Toxicity Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) LC50 fish 1 > 5000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport SECTION 15: Regulatory information 15.1. US Federal regulations Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State regulations Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) U.S. - Massachusetts - Right To Know List SECTION 16: Other information NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product