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HomeMy WebLinkAboutDAQ-2025-000747 1 DAQC-125-25 Site ID 10123 (B5) MEMORANDUM TO: FILE – HF SINCLAIR WOODS CROSS REFINING LLC THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: February 4, 2025 SUBJECT: Holly Refining and Marketing (Holly Refinery), Major, SIP, Title V, MACT, Davis County FRS # UT00000049001100013 INSPECTION TYPE: State Electronic Data Report (SEDR) Review REVIEW DATE: February 4, 2025 SOURCE LOCATION: West Bountiful/Davis County SOURCE CONTACT: Matt Howes - 801-397-7412 APPLICABLE REGS: Title V operating permit 1100013001 dated May 3, 2024 Last Revised May 3, 2024 November 18, 2013 – DAQE-AN101230041-13 – Approval Order SOURCE INSPECTION EVALUATION: With the exception of sources that only monitor for opacity, quarterly report memoranda will only address the findings of the quarterly report. Approval Order and Title V permit conditions addressing continuous emission monitoring requirements will be addressed in Holly Refinery’s relative accuracy performance specification test review memorandum. SEDR Review Fourth Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation Amine Plant 2208 H2S 100% 12/12/24 04/30/24 Amine Plant H2S 0.00 160 ppm - 3- hour RA U4 FCCU 2208 CO 100% 12/12/24 05/01/24 Amine Plant H2S 0.00 60 ppm - 365- day RA U4 FCCU 2208 CO2 100% 12/12/24 05/01/24 Sulfur Recovery Unit SO2 0.00 100 ppm - 12- hour RA 1 8 2 2 Fourth Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation U4 FCCU 2208 NOx 100% 12/18/24 05/01/24 U4 FCCU CO 9.00 500 ppm - hourly U4 FCCU 2208 SO2 100% 12/18/24 05/01/24 U4 FCCU NOx 0.00 40 ppm - 7- day RA U4 FCCU 2208 O2 100% 12/12/24 05/01/24 U4 FCCU NOx 0.00 22.5 ppm - 365-day RA U4 FCCU 2208 Particulate 100% U4 FCCU SO2 0.00 50 ppm - 7- day RA U4 FCCU 2208 Particulate 100% U4 FCCU SO2 0.00 25 ppm - 365- day RA Sulfur Recovery Unit 2208 SO2 100% 12/18/24 05/01/24 U4 FCCU Particulate 0.00 9.2 in H2O - hourly Sulfur Recovery Unit 2208 O2 100% 12/12/24 05/01/24 U4 FCCU Particulate 0.00 66 psi - hourly Crude Unit 2208 O2 100% 12/17/24 08/14/24 Crude Unit O2 0.00 5 ppm - hourly North Flare 2208 H2S 96% 12/13/24 03/26/24 North Flare H2S 7.00 162 ppm - 3- hour RA North Flare 2208 TRS 99% 12/13/24 South Flare H2S 0.00 162 ppm - 3- hour RA South Flare 2208 H2S 98% 12/13/24 03/27/24 U25 FCCU CO 0.00 500 ppm - hourly South Flare 2208 TRS 100% 12/13/24 U25 FCCU NOx 0.00 80 ppm - 7- day RA U25 FCCU 1871 CO 100% 12/17/24 08/14/24 U25 FCCU NOx 0.00 40 ppm - 365- day RA U25 FCCU 1871 CO2 100% 12/17/24 08/14/24 U25 FCCU SO2 0.00 50 ppm - 7- day RA U25 FCCU 1871 NOx 100% 12/17/24 09/10/24 U25 FCCU SO2 0.00 25 ppm - 365- day RA U25 FCCU 1871 SO2 100% 12/17/24 08/14/24 U25 FCCU Particulate 0.00 15.2 in H2O - 3-hour RA U25 FCCU 1871 O2 100% 12/17/24 08/14/24 U25 FCCU Particulate 0.00 0.21 GPM/MSCFH - 3-hour RA U25 FCCU 1871 Particulate 100% U25 FCCU 1871 Particulate 100% 3 Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit Amine Plant H2S 0 0 0 0 0 160 ppm - 3-hour RA Amine Plant H2S 0 0 0 0 0 60 ppm - 365-day RA Sulfur Recovery Unit SO2 0 0 0 0 0 100 ppm - 12-hour RA U4 FCCU CO 6 0 9 0 0 500 ppm - hourly U4 FCCU NOx 0 0 0 0 0 40 ppm - 7-day RA U4 FCCU NOx 0 0 0 0 0 22.5 ppm - 365-day RA U4 FCCU SO2 0 0 0 0 0 50 ppm - 7-day RA U4 FCCU SO2 0 0 0 0 0 25 ppm - 365-day RA U4 FCCU Particulate 0 0 0 0 0 9.2 in H2O - hourly U4 FCCU Particulate 0 0 0 0 0 66 psi - hourly Crude Unit O2 0 0 0 0 0 5 ppm - hourly North Flare H2S 9 0 7 0 0 162 ppm - 3-hour RA South Flare H2S 16 0 0 0 0 162 ppm - 3-hour RA U25 FCCU CO 33 0 0 0 0 500 ppm - hourly U25 FCCU NOx 0 0 0 0 0 80 ppm - 7-day RA U25 FCCU NOx 0 0 0 0 0 40 ppm - 365-day RA U25 FCCU SO2 0 0 0 0 0 50 ppm - 7-day RA U25 FCCU SO2 0 0 0 0 0 25 ppm - 365-day RA U25 FCCU Particulate 63 0 0 0 0 15.2 in H2O - 3-hour RA U25 FCCU Particulate 37 0 0 0 0 0.21 GPM/MSCFH - 3- hour RA CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes Amine Plant H2S 0 0 0 0 0 U4 FCCU CO 0 0 0 0 0 U4 FCCU CO2 0 0 0 0 0 U4 FCCU NOx 0 0 0 0 0 U4 FCCU SO2 0 0 0 0 0 U4 FCCU O2 0 0 0 0 0 U4 FCCU Particulate 0 0 0 0 0 U4 FCCU Particulate 0 0 0 0 0 Sulfur Recovery Unit SO2 0 0 0 0 0 4 CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes Sulfur Recovery Unit O2 0 0 0 0 0 Crude Unit O2 0 0 0 0 0 North Flare H2S 0 59 4 23 0 North Flare TRS 1 0 14 0 0 South Flare H2S 0 14 0 26 0 South Flare TRS 6 0 1 0 0 U25 FCCU CO 7 0 2 0 0 U25 FCCU CO2 7 0 2 0 0 U25 FCCU NOx 7 0 2 0 0 U25 FCCU SO2 7 0 2 0 0 U25 FCCU O2 7 0 2 0 0 U25 FCCU Particulate 0 0 0 0 0 U25 FCCU Particulate 0 0 0 0 0 Pollutant Concentration Exceeded Span of CEM Monitor Outage During Point Source Operation Alternate Sampling CEM Modifications 0 Hours 192 Hours 0 Hours 0 Events SOURCE INSPECTION SUMMARY EVALUATION: HF Sinclair Woods Cross Refining LLC maintains its CEMS as required in R307-170 and 40 CFR 60.13. CURRENT RECOMMENDATIONS: All deviations appear to be a result of breakdown or process related problems that do not warrant issuing a violation. HF Sinclair Woods Cross Refining LLC was in compliance during this reporting period. No further enforcement action is recommended. HF Sinclair Woods Cross Refining LLC’s NSPS monitoring system meets the performance standards of 40 CFR 60, Appendix B Performance Specifications. HPV: No RECOMMENDATION FOR NEXT INSPECTION: Check DAS for daily zero and span drift. Check the QC program to ensure that monitor drift is being tracked and that the source can identify excessive drift. ATTACHMENTS: Excel spreadsheet review ,.dttf$nclor January 22,2025 Director Division of Air Quality Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Certified Mail: 7 0l 2 2920 0000 3 468 7 393 RE:Continuous Emission Monitor Repor! 4c Quarter 2024 Director: ln accordance with 40 CFR 60.7(c) and Utah Administrative Code R307-170-9, please find enclosed the 4ft euarter 2OZ4 CEMand Excess Emissions Report for HF Sinclair Woods Cross Refining LLC, fffSWCn. The electronic report file was sent to Mr. Rob Leishman on January 22,2025 via e-mail. This report contains emission information from the Amine HzS, Crude Oz, North Flare HzS, North Flare Total Reduced Sulfur, South Flare HzS, South Flare Total Reduced Sulfi.r and Sulfur Recovery Unit SO2 in accordance with 40 CFR 60 Subpart Ja, and U25 FCCU CO, U25 FCCU COz,U2S FCCU NOx, U25 FCCU SOz, U25 FCCU Or,lJ FCCU CO, U4 FCCU NOx, U4 FCCU SOz, U4 FCCU Or, md U4N25 FCCU particulate monitors that are required for 40 CFR 63 subpart UUU to determine compliance with the applicable inorganic MACT standard. I believe the information presented in the report is accurate and complete. The following apply to this report: 5 For any periods for which hydrogen sulfide, total reduced sulfur, oxygen content data, or sulfur dioxide imission data, arenot available, changes were not made in the operation of the respective emission control system. Thi required continuous monitoring system calibration, span, and drift checks and other periodic audits have been performed as specified, except as noted in the attached report' The data used to show compliance were obtained in accordance with approved methods and procedures and are representative ofplant performance. The minimum data requirements have been met for errors that were unavoidable, except as noted in the attached rePort. Compliance with the standard has been achieved during the reporting period except as noted in the attached rePort. Except as noted above and in the attached report, exceedances were not concurrent with a startup, shutdown, or malfunction of an affected facility or control system. If you have any questions or need additional information, please contact Matt Howes at (801) 397- 7412. HF Sinclair Woods Cross Refining LLC 1070 W. 500 S, West Bountiful, UT 84087 801 -299-6600 | HFSinclair.com -rrr-iltr5EPARTMENT oF rr.rviion-UENrm oU UIv DIVISION OF AIR OUALITY l. 3. 4. I cErti& under penalties of law that, based upon inquiry of personnel involve4 the statcments and informition coot ined in this report are tnrthful and accurate, and are a complete record of all monitoring related events that occurred during the rcporting pcriod. Sincerely, JJr=}'.-,S^^"^."^a' Dustin Simmonds Vice President and Refinery Manager Attachmcot ec: Mr. Rob Irishman (DAQ) cc: E. Benson (r) File 2.2.1 I a ENVTRONMENfA!!uALtTY DIVISION OF AIR OUALITY HF Sinclair Refinery EER 4Q2024 Point Source Information Late Expired Cal. Gas Valid Cal. Gas Days Yes No 1 Type Code 100(Company Information)Type Code Company Manager Company Name AIRS # Phone Number Environmental Contact 1 100 Dustin Simmonds 01100013 (801) 397-7412 Matt Howes 1 100 0 0 0 0 1 Type Code 110 (Point Source Identification)Type Code Point Source Quarter 1 - 4 Year Point Source Operating Hrs. in Quarter 1 110 4 2024 2208 1 110 4 2024 2208 1 110 4 2024 2208 1 110 4 2024 2208 1 110 4 2024 2208 1 110 4 2024 1871 1 110 4 2024 2208 1 110 0 0 0 1 Type Code 200(Monitor Identification)Type Code Point Source Channel Manufacturer Model No. Monitor SN Low Span High Span Installation Date Monitor Location 1 200 H2S Siemens 3004945670 10 - 300 4/1/2021 Fuel Line 1 200 O2 Ametek Thermox WDG-IV 10208656 - 20 8/17/2015 Stack 1 200 H2S Extrel Max 300-RTG 62582 - 300 11/8/2018 Flare Line 1 200 TRS Thermo Scientific Sola II SL-09960914 2000 30 11/11/2015 Flare Line 1 200 H2S Extrel Max 300-RTG 62585 - 300 11/8/2018 Flare Line 1 200 TRS Thermo Scientific Sola II SL-09970914 2000 30 11/11/2015 Flare Line 1 200 O2 Ametek 9900RM 9900-S1616-1 - 20 2/7/2023 Stack 1 200 SO2 Teledyne Monitor Labs T100H 467 - 200 5/30/2021 Stack 1 200 CO SICK MCS100E 15062323 - 1000 6/1/2016 Stack 1 200 CO2 SICK MCS100E 15062323 - 20 6/1/2016 Stack 1 200 NOx SICK MCS100E 15062323 - 200 6/1/2016 Stack 1 200 O2 SICK MCS100E 15062323 - 20 6/1/2016 Stack 1 200 Particulate Rosemount 3051CG4A22A1AS1M5K5Q4Q83051CG4A22A1AS1M5K5Q4Q8- - 6/1/2016 Stack 1 200 Particulate Flexim/SICK Maihak US-7407/SIC 199 F704/15062323 - - 9/20/2017 Stack 1 200 SO2 SICK MCS100E 15062323 - 200 6/1/2016 Stack 1 200 CO Teledyne Monitor Labs T300 5404 - 1000 5/30/2021 Stack 1 200 CO2 Teledyne Monitor Labs T300 5404 - 0.2 5/30/2021 Stack 1 200 NOx Ametek 9900RM 9900-S1616-1 - 200 2/7/2023 Stack 1 200 O2 Ametek 9900RM 9900-S1616-1 - 20 2/7/2023 Stack 1 200 Particulate Rosemount 3051CG2A22A1AS1E5M5Q4Q82278010 - - 10/27/2012 Stack 1 200 Particulate Rosemount 3051TG3A2B21AS1E5M5Q4Q82278290 - - 10/27/2012 Stack 1 200 SO2 Teledyne Monitor Labs T100H 467 - 200 5/30/2021 Stack 1 200 0 0 0 0 0 0 1/0/1900 0 HF Sinclair Woods Cross Refining LLC 0 Amine Plant Crude Unit North Flare North Flare South Flare South Flare Sulfur Recovery Unit Sulfur Recovery Unit U25 FCCU U25 FCCU U25 FCCU U4 FCCU 0 U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU Amine Plant Crude Unit North Flare South Flare Sulfur Recovery Unit U25 FCCU U4 FCCU 0 U25 FCCU U25 FCCU U25 FCCU U25 FCCU U4 FCCU HF Sinclair Refinery EER 4Q2024 1 Type Code310 (Excess Emissions) SUMMARY REPORT Type Code Channel Total Hours of Excess Emissions Excess Emissions - % of Total Operating Hours RC 701 Hours - start up/Shutdown RC 702 Hours- Control Equipment Problems RC 703 Hours - Process Problems RC 704, 706, 707 Hours -Other Known Causes RC 705 Hours - Unknown Causes Emission Limitation Emission Limitation Units Emission Limitation Averaging Period 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 160 ppm 3-hour RA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 60 ppm 365-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 100 ppm 12-hour RA 1 TRUE 310 CO 15 0.68% 6 0 9 0 0 500 ppm hourly 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 40 ppm 7-day RA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 22.5 ppm 365-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 50 ppm 7-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 25 ppm 365-day RA 1 TRUE 310 Particulate 0 0.00% 0 0 0 0 0 9.2 in H2O hourly 1 TRUE 310 Particulate 0 0.00% 0 0 0 0 0 66 psi hourly 1 TRUE 310 O2 0 0.00% 0 0 0 0 0 5 ppm hourly 1 TRUE 310 H2S 16 0.72% 9 0 7 0 0 162 ppm 3-hour RA 1 TRUE 310 H2S 16 0.72% 16 0 0 0 0 162 ppm 3-hour RA 1 TRUE 310 CO 33 1.76% 33 0 0 0 0 500 ppm hourly 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 80 ppm 7-day RA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 40 ppm 365-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 50 ppm 7-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 25 ppm 365-day RA 1 TRUE 310 Particulate 63 3.37% 63 0 0 0 0 15.2 in H2O 3-hour RA 1 TRUE 310 Particulate 37 1.98% 37 0 0 0 0 0.21 GPM/MSCFH3-hour RA 1 310 0 0 0 0 0 0 0 0 0 1 Type Code 300 (CMS Performance Summary) Type Code Channel Point Source Operating Hours Downtime - % of Total Operating Hours Total CMS Downtime RC 721 Hours - Monitor Malfunction RC 722 Hours - Non-monitor Malfunction RC 723 Hours - QA Calibrations RC 724 Hours - Other Known Causes RC 725 Hours - Unknown Causes 1 TRUE 300 H2S 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 CO 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 CO2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 NOx 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 SO2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 O2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 Particulate 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 Particulate 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 SO2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 O2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 O2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 H2S 2208 3.89% 85.93 0 58.93 4 23 0 1 TRUE 300 TRS 2208 0.68% 15 1 0 14 0 0 1 TRUE 300 H2S 2208 1.81% 39.97 0 13.97 0 26 0 1 TRUE 300 TRS 2208 0.32% 7 6 0 1 0 0 1 TRUE 300 CO 1871 0.48% 9 7 0 2 0 0 1 TRUE 300 CO2 1871 0.48% 9 7 0 2 0 0 1 TRUE 300 NOx 1871 0.48% 9 7 0 2 0 0 1 TRUE 300 SO2 1871 0.48% 9 7 0 2 0 0 1 TRUE 300 O2 1871 0.48% 9 7 0 2 0 0 1 TRUE 300 Particulate 1871 0.00% 0 0 0 0 0 0 1 TRUE 300 Particulate 1871 0.00% 0 0 0 0 0 0 1 300 0 0 0 0 0 0 1 Type Code 250 (Performance Specification RATA Results) Type Code Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units of Measurement CEM Value Reference Method Value Relative accuracy Pass/ Fail 1 361 Days 250 H2S 04/30/24 05/05/23 12 ppm 18.2 19.7 180.00% pass 1 363 Days 250 CO 05/01/24 05/04/23 12 ppm 95.89 95.34 200.00% pass 1 363 Days 250 CO2 05/01/24 05/04/23 12 ppm 14.9 15.23 240.00% pass 1 363 Days 250 NOx 05/01/24 05/04/23 12 ppm 13.72 19.44 860.00% pass 1 363 Days 250 SO2 05/01/24 05/04/23 12 ppm 0.044 0.017 20.00% pass 1 363 Days 250 O2 05/01/24 05/04/23 12 0 1.86 2.69 80.00% pass 1 363 Days 250 SO2 05/01/24 05/04/23 12 ppm 0.044 0.017 20.00% pass 1 363 Days 250 O2 05/01/24 05/04/23 12 0 1.86 2.69 80.00% pass 1 355 Days 250 O2 08/14/24 08/25/23 12 ppm 3.2 3.5 830.00% pass 1 379 Days 250 H2S 03/26/24 03/13/23 12 ppm 2.27 0 300.00% pass 1 369 Days 250 H2S 03/27/24 03/24/23 12 ppm 0.46 0 20.00% pass 1 356 Days 250 CO 08/14/24 08/24/23 12 ppm 128.1 141.3 410.00% pass 1 356 Days 250 CO2 08/14/24 08/24/23 12 0 13.3 15 1320.00% pass 1 383 Days 250 NOx 09/10/24 08/24/23 13 ppm 17.4 20.7 560.00% pass 1 356 Days 250 SO2 08/14/24 08/24/23 12 ppm 1.6 0 320.00% pass 1 356 Days 250 O2 08/14/24 08/24/23 12 0 2 2 570.00% pass 1 0 Days 250 0 01/00/00 01/00/00 0 0 0 0 0.00% 0 U4 FCCU U4 FCCU Amine Plant U25 FCCU U25 FCCU U25 FCCU U25 FCCU South Flare U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU 0 North Flare Sulfur Recovery Unit Sulfur Recovery Unit Crude Unit North Flare South Flare South Flare U25 FCCU U25 FCCU U25 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU Amine Plant Amine Plant U25 FCCU U25 FCCU Sulfur Recovery Unit Sulfur Recovery Unit Crude Unit North Flare South Flare Sulfur Recovery Unit U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU Crude Unit North Flare Amine Plant U4 FCCU U4 FCCU U25 FCCU U25 FCCU Point Source Point Source Point Source 0 U25 FCCU 0 U4 FCCU U4 FCCU U4 FCCU HF Sinclair Refinery EER 4Q2024 1 Type Code 260 (CGA Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 Valid Cal. Gas 260 H2S 12/12/24 1 CC358743 04/19/25 EPA Traceability Protocolppm 57 59.9 480.00% pass low 1 Valid Cal. Gas 260 H2S 12/12/24 2 CC18730 02/28/27 EPA Traceability Protocolppm 171.3 183.6 670.00% pass high 1 Valid Cal. Gas 260 O2 12/17/24 1 EB0095843 11/25/27 EPA Traceability Protocol% 3.9 4 410.00% pass low 1 Valid Cal. Gas 260 O2 12/17/24 2 CC484626 02/26/27 EPA Traceability Protocol% 9.6 10.1 440.00% pass high 1 Valid Cal. Gas 260 H2S 12/13/24 1 CC216113 11/29/25 EPA Traceability Protocolppm 61.3 59.5 310.00% pass low 1 Valid Cal. Gas 260 H2S 12/13/24 2 CC504017 04/20/25 EPA Traceability Protocolppm 186.2 177.7 480.00% pass high 1 Valid Cal. Gas 260 TRS 12/13/24 1 CC10516 12/28/25 EPA Traceability Protocolppm 430.7 406.1 610.00% pass low 1 Valid Cal. Gas 260 TRS 12/13/24 2 CC456684 08/02/25 EPA Traceability Protocolppm 1171.7 1192 170.00% pass high 1 Valid Cal. Gas 260 TRS 12/13/24 1 CC415059 11/16/26 Primary Standard ppm 61579.7 60040 260.00% pass low 1 Valid Cal. Gas 260 TRS 12/13/24 2 CC55059 05/17/26 Certified Standard-SPECppm 187514 180100 410.00% pass high 1 Valid Cal. Gas 260 H2S 12/13/24 1 CC216113 11/29/25 EPA Traceability Protocolppm 57.6 59.5 310.00% pass low 1 Valid Cal. Gas 260 H2S 12/13/24 2 CC504017 04/20/25 EPA Traceability Protocolppm 172.8 177.7 270.00% pass high 1 Valid Cal. Gas 260 TRS 12/13/24 1 CC10516 12/28/25 EPA Traceability Protocolppm 448.7 406.1 1050.00% pass low 1 Valid Cal. Gas 260 TRS 12/13/24 2 CC456684 08/02/25 EPA Traceability Protocolppm 1200.3 1192 70.00% pass high 1 Valid Cal. Gas 260 TRS 12/13/24 1 CC415059 11/16/26 Primary Standard ppm 62824.7 60040 460.00% pass low 1 Valid Cal. Gas 260 TRS 12/13/24 2 CC55059 5/17/26 Certified Standard-SPECppm 182,319 180,100 1 pass high 1 Valid Cal. Gas 260 O2 12/12/24 1 CC509042 1/4/25 EPA Traceability Protocol% 5 5 4 pass low 1 Valid Cal. Gas 260 O2 12/12/24 2 EB0108817 5/2/25 EPA Traceability Protocol% 11 11 1 pass high 1 Valid Cal. Gas 260 SO2 12/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 54 50 6 pass low 1 Valid Cal. Gas 260 SO2 12/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 111 110 1 pass high 1 Valid Cal. Gas 260 CO 12/17/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 247 249 1 pass low 1 Valid Cal. Gas 260 CO 12/17/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 551 554 0 pass high 1 Valid Cal. Gas 260 CO2 12/17/24 1 CC509042 1/4/25 EPA Traceability Protocol% 6 6 5 pass low 1 Valid Cal. Gas 260 CO2 12/17/24 2 EB0108817 5/2/25 EPA Traceability Protocol% 11 12 9 pass high 1 Valid Cal. Gas 260 NOx 12/17/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 49 51 4 pass low 1 Valid Cal. Gas 260 NOx 12/17/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 111 111 1 pass high 1 Valid Cal. Gas 260 O2 12/17/24 1 CC509042 1/4/25 EPA Traceability Protocol% 5 5 3 pass low 1 Valid Cal. Gas 260 O2 12/17/24 2 EB0108817 5/2/25 EPA Traceability Protocol% 11 11 2 pass high 1 Valid Cal. Gas 260 SO2 12/17/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 50 50 0 pass low 1 Valid Cal. Gas 260 SO2 12/17/24 2 CC315186 5/28/27 EPA Traceability Protocolppm 116 118 2 pass high 1 Valid Cal. Gas 260 CO 12/12/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 235 249 6 pass low 1 Valid Cal. Gas 260 CO 12/12/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 526 554 5 pass high 1 Valid Cal. Gas 260 CO2 12/12/24 1 CC509042 1/4/25 EPA Traceability Protocol% 6 6 2 pass low 1 Valid Cal. Gas 260 CO2 12/12/24 2 EB0108817 5/2/25 EPA Traceability Protocol% 12 12 0 pass high 1 Valid Cal. Gas 260 NOx 12/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 51 51 1 pass low 1 Valid Cal. Gas 260 NOx 12/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 116 111 4 pass high 1 Valid Cal. Gas 260 O2 12/12/24 1 CC509042 1/4/25 EPA Traceability Protocol% 5 5 4 pass low 1 Valid Cal. Gas 260 O2 12/12/24 2 EB0108817 5/2/25 EPA Traceability Protocol% 11 11 1 pass high 1 Valid Cal. Gas 260 SO2 12/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 54 50 6 pass low 1 Valid Cal. Gas 260 SO2 12/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 111 110 1 pass high 1 260 0 1/0/00 0 0 1/0/00 0 0 0 0 0 0 0 1 Type Code 270 (Linearity Test Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 270 0 01/00/00 0 0 01/00/00 0 0 0 0 0.00% 0 0 1 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code Channel Start Date Start Time End Date End Time Hours 1 0 0 0 1/0/00 0:00 1/0/00 0:00 1 1 None Reported 1 0 TC 220 Hours 192.47 TC 220 Hours 0.00 TC 230 Hours 0.00 Events 0.00 Hours 0.00 Events 0.00 0.00 1 192.90 TC 300 Hours 0.43 FALSE 0 0 0 U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U4 FCCU U4 FCCU U4 FCCU Crude Unit Crude Unit U25 FCCU U25 FCCU South Flare North Flare North Flare North Flare North Flare North Flare Sulfur Recovery Unit U25 FCCU U25 FCCU South Flare Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code 220 (Monitor Outage During Point Source Operation) Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) Type Code 240 (CEM Modifications) Type Code 530 (Excess Emissions During Emergency Conditions) Type Code 550 (Changes in Operation in Control Equipment When CEM Data Not Available) Type Code 500 (Boiler Operating Days w/o 18 Hours of Data) Type Code 450 (Data Excluded) Point Source Point Source Point Source Yes North Flare South Flare South Flare South Flare South Flare Sulfur Recovery Unit Sulfur Recovery Unit Sulfur Recovery Unit Amine Plant Amine Plant None Reported None Reported None Reported None Reported None Reported None Reported HF Sinclair Refinery EER 4Q2024 Relative Accuracy Overview Point Source Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units Measured CEM Value Reference Method Value Relative Accuracy Pass/ Fail Amine Plant H2S 04/30/24 05/05/23 12 ppm 18.2 19.70 180.00% pass U4 FCCU CO 05/01/24 05/04/23 12 ppm 95.89 95.34 200.00% pass U4 FCCU CO2 05/01/24 05/04/23 12 ppm 14.9 15.23 240.00% pass U4 FCCU NOx 05/01/24 05/04/23 12 ppm 13.72 19.44 860.00% pass U4 FCCU SO2 05/01/24 05/04/23 12 ppm 0.044 0.02 20.00% pass U4 FCCU O2 05/01/24 05/04/23 12 1.86 2.69 80.00% pass Sulfur Recovery Unit SO2 05/01/24 05/04/23 12 ppm 0.044 0.02 20.00% pass Sulfur Recovery Unit O2 05/01/24 05/04/23 12 1.86 2.69 80.00% pass Crude Unit O2 08/14/24 08/25/23 12 ppm 3.2 3.50 830.00% pass North Flare H2S 03/26/24 03/13/23 12 ppm 2.27 0.00 300.00% pass South Flare H2S 03/27/24 03/24/23 12 ppm 0.46 0.00 20.00% pass U25 FCCU CO 08/14/24 08/24/23 12 ppm 128.1 141.30 410.00% pass U25 FCCU CO2 08/14/24 08/24/23 12 13.3 15.00 1320.00% pass U25 FCCU NOx 09/10/24 08/24/23 13 ppm 17.4 20.70 560.00% pass U25 FCCU SO2 08/14/24 08/24/23 12 ppm 1.6 0.00 320.00% pass U25 FCCU O2 08/14/24 08/24/23 12 2 2.00 570.00% pass * NSPS CGA Fourth 2024 Audit Gas Ranges Audit Gas Ranges AP1 Low AP2 Low AP1 High AP2 High Amine Plant H2S 12/12/24 300 59.9 60 to 90 Amine Plant H2S 12/12/24 300 183.6 150 to 180 Crude Unit O2 12/17/24 20 4 4 to 6 Crude Unit O2 12/17/24 20 10.1 8 to 12 North Flare H2S 12/13/24 300 59.5 60 to 90 North Flare H2S 12/13/24 300 177.7 150 to 180 North Flare TRS 12/13/24 2000 406.1 400 to 600 North Flare TRS 12/13/24 2000 1192 1000 to 1200 North Flare TRS 12/13/24 300000 60040 60000 to 90000 North Flare TRS 12/13/24 300000 180100 150000 to 180000 South Flare H2S 12/13/24 300 59.5 60 to 90 South Flare H2S 12/13/24 300 177.7 150 to 180 South Flare TRS 12/13/24 2000 406.1 400 to 600 South Flare TRS 12/13/24 2000 1192 1000 to 1200 South Flare TRS 12/13/24 300000 60040 60000 to 90000 South Flare TRS 12/13/24 300000 180100 150000 to 180000 Sulfur Recovery Unit O2 12/12/24 20 5 4 to 6 Sulfur Recovery Unit O2 12/12/24 20 11 8 to 12 Sulfur Recovery Unit SO2 12/18/24 200 50.4 40 to 60 Sulfur Recovery Unit SO2 12/18/24 200 110.3 100 to 120 U25 FCCU CO 12/17/24 1000 249 200 to 300 U25 FCCU CO 12/17/24 1000 553.5 500 to 600 U25 FCCU CO2 12/17/24 20 6 5 to 8 U25 FCCU CO2 12/17/24 20 11.7 10 to 14 U25 FCCU NOx 12/17/24 200 50.9 40 to 60 U25 FCCU NOx 12/17/24 200 111.2 100 to 120 U25 FCCU O2 12/17/24 20 5 4 to 6 U25 FCCU O2 12/17/24 20 11 8 to 12 U25 FCCU SO2 12/17/24 200 50.4 40 to 60 U25 FCCU SO2 12/17/24 200 118 100 to 120 U4 FCCU CO 12/12/24 1000 249 200 to 300 U4 FCCU CO 12/12/24 1000 553.5 500 to 600 U4 FCCU CO2 12/12/24 20 6 5 to 8 U4 FCCU CO2 12/12/24 20 11.7 10 to 14 U4 FCCU NOx 12/18/24 200 50.9 40 to 60 U4 FCCU NOx 12/18/24 200 111.2 100 to 120 U4 FCCU O2 12/12/24 20 5 4 to 6 U4 FCCU O2 12/12/24 20 11 8 to 12 U4 FCCU SO2 12/18/24 200 50.4 40 to 60 U4 FCCU SO2 12/18/24 200 110.3 100 to 120 Audit Gas Used High Span Audit Gas UsedPoint Source Channel Audit Date Low Span HF Sinclair Refinery EER 4Q2024 Monitoring Information TC 210, 230, & 240 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 240 (CEM Modifications) - 100 (All) * Count of Channel Column Labels Row Labels (blank) Grand Total (blank) (blank) Grand Total HF Sinclair Refinery EER 4Q2024 Type Code 220 (Monitor Outage During Point Source Operation) - 600 (All) * Sum of Hours Column Labels Row Labels 723 721 722 724 Grand Total U25 FCCU O2 QA Calibrations performed 1.97 1.97 Analyzer locked up, rebooted Analyzer 6.98 6.98 CO QA Calibrations performed 1.97 1.97 Analyzer locked up, rebooted Analyzer 6.98 6.98 CO2 QA Calibrations performed 1.97 1.97 Analyzer locked up, rebooted Analyzer 6.98 6.98 NOx QA Calibrations performed 1.97 1.97 Analyzer locked up, rebooted Analyzer 6.98 6.98 SO2 QA Calibrations performed 1.97 1.97 Analyzer locked up, rebooted Analyzer 6.98 6.98 North Flare H2S QA Calibrations performed 3.97 3.97 Sample System Contaminated. System Cleaned Out 15.97 15.97 Analyzer Software Malfunction, Reset software 27.98 27.98 Annual Preventative Maintenance 22.98 22.98 Issues with sample conditioning 14.98 14.98 TRS QA Calibrations performed 11.95 11.95 Analyzer locked up, rebooted Analyzer 0.98 0.98 Cylinder Gas Audit 1.98 1.98 South Flare H2S Sample System Contaminated. System Cleaned Out 13.97 13.97 Annual Preventative Maintenance 25.98 25.98 TRS Analyzer locked up, rebooted Analyzer 5.98 5.98 #N/A 0.98 0.98 Grand Total 28.72 41.88 72.90 48.97 192.47 HF Sinclair Refinery EER 4Q2024 SO2 * SO2 Type Code 410 (SO2) - 6000 (All) SO2 * SO2 Count of Magnitude of Emissions Column Labels SO2 Row Labels (blank)Grand Total SO2 U4 FCCU 1 1 SO2 Sulfur Recovery Unit 1 1 SO2 U25 FCCU 1 1 SO2 SO2 (blank) SO2 Grand Total 3 3 NOx * NOx Type Code 420 (NOx) - 6000 (All) NOx *NOx Count of Magnitude of Emissions Column Labels NOx Row Labels (blank)Grand Total NOx U4 FCCU NOx 0 1 1 NOx U25 FCCU NOx 0 1 1 NOx Grand Total 2 2 H2S/TRS * H2S/TRS Type Code 430 (H2S) - 6000 (All) H2S/TRS * H2S/TRS Count of Magnitude of Emissions Column Labels H2S/TRS Row Labels (blank)701 703 Grand Total H2S/TRS Amine Plant H2S/TRS 0 1 1 H2S/TRS North Flare H2S/TRS Compressor Interlock, Compressor brought back online 3 3 H2S/TRS Process Interlock of the FCCU, Attempted restart of unit 4 4 H2S/TRS External power outage.9 9 H2S/TRS South Flare H2S/TRS Startup/Shutdown of FCCU 16 16 H2S/TRS Grand Total 1 25 7 33 CO * CO Type Code 440 (CO) - 6000 (All) CO * CO Count of Magnitude of Emissions Column Labels CO Row Labels (blank)701 703 Grand Total CO U4 FCCU CO Process Interlock of the FCCU, Attempted restart of unit 4 4 CO Lost charger to unit. Brought unit back online 5 5 CO #N/A 3 3 CO External power outage.3 3 CO U25 FCCU CO External power outage.25 25 CO Start up/Shut down 8 8 CO Grand Total 39 9 48 VOC/THC *VOC/THC Type Code 460 (VOC/THC) - 6000 (All) VOC/THC * VOC/THC Count of Magnitude of Emissions Column Labels VOC/THC Row Labels Grand Total VOC/THC Grand Total O2 * O2 Type Code 470 (TRS as O2) - 6000 (All) O2 * O2 Count of Magnitude of Emissions Column Labels O2 Row Labels (blank)Grand Total O2 Crude Unit O2 0 1 1 O2 Grand Total 1 1 P.M.* P.M.Type Code 490 Particulate (PM) - 6000 (All) P.M.* P.M.Count of Magnitude of Emissions Column Labels P.M.Row Labels 701 Grand Total P.M.External power outage.25 25 P.M.U25 FCCU 25 25 P.M.Start up/Shut down 75 75 P.M.U25 FCCU 75 75 P.M.Grand Total 100 100 HF Sinclair Refinery EER 4Q2024 Type Code 500 Before February 28, 2005 (Boiler Operating Days w/o 18 Hours of Data) After February 28, 2005 (90% Operating Hours For each 30 BOD) - 500 (All) * Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 510 (F-factor, Equations & Conversion Factors) - 500 (All) Count of F-factor Column Labels Row Labels Grand Total Grand Total * Type Code 520 (Minimum Data Not Obtained <22/30 BODs) - 500 (All) Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 530 (Excess Emissions During Emergency Conditions) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * Type Code 540 (Fuel Pre-treatment Credit SO2) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * TypeCode 550 (Changes in Operation in Control Equipment When CEM Data Not Available) - 500 (All) Column Labels Row Labels Grand Total Grand Total