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HomeMy WebLinkAboutDAQ-2025-0007311 DAQC-104-25 Site ID 101838 (B4) MEMORANDUM TO: STACK TEST FILE – OVINTIV USA, INC. – Boston SWD – Duchesne County THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: January 28, 2025 SUBJECT: Source: One (1) Doosan 8.8L engine; SN: 0012527; and Three (3) Caterpillar G3516H engines; SN’s: H6C00285, H6C00280, H6C00248 Location: Duchesne County, UT Contact: Ryan Zillner: 720-876-3144 Tester: Great Plains Analytical Services, Inc. Site ID #: 101838 Permit/AO #: Permit by Rule Subject: Review of Stack Test Report dated September 9, 2024 On September 9, 2024, DAQ received a test report for the above listed units at Boston SWD in Duchesne County, UT. Testing was performed on August 20-21, 2024, to demonstrate compliance with the emission limits found in Utah Administrative Code R307-510 and 40 CFR Part 60 Subpart JJJJ. The DAQ-calculated test results are: Source Test Date Test Method Pollutant Tester Results DAQ Results Limits Doosan 8.8L engine; SN: 0012527 Aug. 21, 2024 ASTM D6348-03 NOx 3.964 ppmvd@15%O2 0.034 g/hp-hr 3.964 ppmvd@15%O2 0.034 g/hp-hr 82 ppmvd@15%O2 1.0 g/hp-hr CO 18.409 ppmvd@15%O2 0.097 g/hp-hr 18.411 ppmvd@15%O2 0.097 g/hp-hr 270 ppmvd@15%O2 2.0 g/hp-hr VOC 0.792 ppmvd@15%O2 0.007 g/hp-hr 0.792 ppmvd@15%O2 0.007 g/hp-hr 60 ppmvd@15%O2 0.70 g/hp-hr Caterpillar G3516H engine; SN: H6C00285 Aug. 20, 2024 ASTM D6348-03 NOx 41.527 ppmvd@15%O2 0.449 g/hp-hr 41.499 ppmvd@15%O2 0.448 g/hp-hr 82 ppmvd@15%O2 1.0 g/hp-hr CO 5.442 ppmvd@15%O2 0.036 g/hp-hr 5.438 ppmvd@15%O2 0.036 g/hp-hr 270 ppmvd@15%O2 2.0 g/hp-hr VOC 6.671 ppmvd@15%O2 0.069 g/hp-hr 6.666 ppmvd@15%O2 0.069 g/hp-hr 60 ppmvd@15%O2 0.70 g/hp-hr Caterpillar G3516H engine; SN: H6C00280 Aug. 20, 2024 ASTM D6348-03 NOx 42.955 ppmvd@15%O2 0.415 g/hp-hr 42.928 ppmvd@15%O2 0.414 g/hp-hr 82 ppmvd@15%O2 1.0 g/hp-hr CO 4.241 ppmvd@15%O2 0.025 g/hp-hr 4.239 ppmvd@15%O2 0.025 g/hp-hr 270 ppmvd@15%O2 2.0 g/hp-hr VOC 6.737 ppmvd@15%O2 0.062 g/hp-hr 6.733 ppmvd@15%O2 0.062 g/hp-hr 60 ppmvd@15%O2 0.70 g/hp-hr 4 ' - ) - " 2 Source Test Date Test Method Pollutant Tester Results DAQ Results Limits Caterpillar G3516H engine; SN: H6C00248 Aug. 21, 2024 ASTM D6348-03 NOx 41.047 ppmvd@15%O2 0.374 g/hp-hr 41.033 ppmvd@15%O2 0.373 g/hp-hr 82 ppmvd@15%O2 1.0 g/hp-hr CO 6.328 ppmvd@15%O2 0.035 g/hp-hr 6.326 ppmvd@15%O2 0.035 g/hp-hr 270 ppmvd@15%O2 2.0 g/hp-hr VOC 7.189 ppmvd@15%O2 0.063 g/hp-hr 7.187 ppmvd@15%O2 0.063 g/hp-hr 60 ppmvd@15%O2 0.70 g/hp-hr DEVIATIONS: None. CONCLUSION: The Stack Test appears to be acceptable. RECOMMENDATION: It is recommended that the emissions from the one (1) Doosan 8.8L engine and three (3) Caterpillar G3516H engines are considered to be in compliance with their NOx, CO, and VOC emission limits of Utah Administrative Code R307-510 and 40 CFR Part 60 Subpart JJJJ, during the time of testing. HPV: Not Applicable. ATTACHMENTS: DAQ stack test review Excel Spreadsheets; Ovintiv stack test reports Emissions Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Doosan 8.8L engine; SN: 0012527 Test Date: 8/21/24 Run # 1 2 3 Average Start Time 13:27 14:36 15:48 Stop Time 14:27 15:36 16:48 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 146 146 146 146 DS Stack Diameter (inches) 3.5 3.5 3.5 3.5 PAVG Average (Delta P)½ (" H2O)½0.8598 0.8696 0.8724 0.8673 CP Pitot Tube Constant (unitless) 0.99 0.99 0.99 0.99 TS Stack Temperature (°F) 827 829 829 829 Pbar Barometric Pressure (mbar) 835 834 834 835 Pbar Barometric Pressure (" Hg) 24.67 24.64 24.63 24.64 Ps Stack Pressure ('' H2O)0.74 0.76 0.76 0.75 O2%vd O2 (%vd)0.3 0.3 0.3 0.3 CO2%vd CO2 (%vd)9.0 9.1 9.0 9.1 N2%vd N2 (%vd)90.7 90.7 90.7 90.7 dry NOX (ppmvd)23.1 9.2 9.3 13.9 dry CO (ppmvd) 87.8 51.7 53.7 64.4 wet NMNEOC (ppmvw as C3H8)1.4 2.3 3.0 2.2 Run # 1 2 3 Average Bws Measured Moisture Content (%/100) 0.191 0.189 0.190 0.190 Bws Saturated Moisture Content (%/100) 477.187 482.150 482.203 480.514 Bws Actual Moisture Content (%/100) 0.191 0.189 0.190 0.190 MD Molecular Weight Dry (lb/lb-mole) 29.46 29.46 29.46 29.46 MA Molecular Weight Wet (lb/lb-mole) 27.27 27.30 27.29 27.28 VS Gas Velocity (ft/sec)100.6 101.8 102.2 101.5 FACFM Gas Flow (acfm) 403 408 410 407 FDSCFM Gas Flow (dscfm) 110 112 112 111 FWSCFM Gas Flow (wscfm) 137 138 138 138 FKWSCFH Gas Flow (kwscfh) 8 8 8 8 FKWSCFM Gas Flow (kwscfm) 0 0 0 0 lb/hr Gas Flow (lb/hr) 580 586 588 585 Fo Fo (unitless)2.283 2.276 2.279 2.279 wet O2 (%vw)0.211 0.211 0.244 0.222 wet CO2 (%vw)7.310 7.358 7.324 7.331 wet NOX (ppmvw)18.672 7.458 7.532 11.221 15 NOX (ppmvd @ 15% O2)6.601 2.628 2.663 3.964 82.0 lb/hr NOX (lb/hr)0.018 0.007 0.007 0.011 g/bhp-hr NOX (g/bhp-hr)0.057 0.023 0.023 0.034 1.0 wet CO (ppmvw) 70.991 41.903 43.476 52.124 15 CO (ppmvd @ 15% O2)25.097 14.766 15.369 18.411 ,270 lb/hr CO (lb/hr) 0.042 0.025 0.026 0.031 g/bhp-hr CO (g/bhp-hr) 0.131 0.078 0.081 0.097 2.0 dry NMEOC (ppmvd as C3H8)1.773 2.875 3.657 2.768 15 NMEOC (ppmvd as C3H8 @ 15% O2)0.507 0.822 1.047 0.792 60 lb/hr NMEOC (lb/hr as C3H8)0.001 0.002 0.003 0.002 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.004 0.007 0.009 0.007 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Doosan 8.8L engine; SN: 0012527 Test Date: 8/21/24 O2 21.0 10.760 0.0 10.7 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 10.6 % 0.00 10.760 20.98 0.0 10.6 20.6 0.0 0.2 0.4 0.0 0.00% 0.57% 1.81% Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value 4 Difference 1 4 Response 1 2 Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias Page 2 of 5 Run 1 Ovintiv USA Inc. Run 1 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 13:27 Doosan 8.8L engine; SN: 0012527 Run Length 60 Test Date: 8/21/24 Stop Time 14:27 O2 21.0 10.76 0.0 10.7 0.0 10.8 0.0% 1.1% 0.0% 0.5% Corrected O2 % 0.261 Run Length (Minutes) Uncorrected O2 % 60 0.26 Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Page 3 of 5 Run 2 Ovintiv USA Inc. Run 2 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 14:36 Doosan 8.8L engine; SN: 0012527 Run Length 60 Test Date: 8/21/24 Stop Time 15:36 O2 21.0 10.76 0.0 10.7 0.0 10.8 0.0% 1.1% 0.0% 0.5% Corrected O2 % 0.261 Run Length (Minutes) Uncorrected O2 % 60 0.26 Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Page 4 of 5 Run 3 Ovintiv USA Inc. Run 3 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 15:48 Doosan 8.8L engine; SN: 0012527 Run Length 60 Test Date: 8/21/24 Stop Time 16:48 O2 21.0 10.76 0.0 10.7 0.0 10.8 0.0% 1.1% 0.0% 0.5% Corrected O2 % 0.301 Run Length (Minutes) Uncorrected O2 % 60 0.30 Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Page 5 of 5 Emissions Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Caterpillar G3516H engine; SN: H6C00285 Test Date: 8/20/24 Run # 1 2 3 Average Start Time 9:14 10:25 11:35 Stop Time 10:14 11:25 12:35 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 1934 1934 1934 1934 DS Stack Diameter (inches) 18.0 18.0 18.0 18.0 PAVG Average (Delta P)½ (" H2O)½0.8935 0.8932 0.9037 0.8968 CP Pitot Tube Constant (unitless) 0.99 0.99 0.99 0.99 TS Stack Temperature (°F) 786 787 787 787 Pbar Barometric Pressure (mbar) 841 840 840 840 Pbar Barometric Pressure (" Hg) 24.83 24.82 24.81 24.82 Ps Stack Pressure ('' H2O)0.80 0.80 0.82 0.81 O2%vd O2 (%vd)9.6 9.5 9.5 9.5 CO2%vd CO2 (%vd)5.4 5.5 5.5 5.5 N2%vd N2 (%vd)85.0 85.0 85.0 85.0 dry NOX (ppmvd)81.0 79.6 79.4 80.0 dry CO (ppmvd) 9.9 10.4 11.1 10.5 wet NMNEOC (ppmvw as C3H8)11.1 11.3 11.6 11.3 Run # 1 2 3 Average Bws Measured Moisture Content (%/100) 0.120 0.121 0.121 0.121 Bws Saturated Moisture Content (%/100) 387.294 389.305 389.453 388.684 Bws Actual Moisture Content (%/100) 0.120 0.121 0.121 0.121 MD Molecular Weight Dry (lb/lb-mole) 29.25 29.25 29.26 29.25 MA Molecular Weight Wet (lb/lb-mole) 27.90 27.89 27.90 27.90 VS Gas Velocity (ft/sec)101.3 101.4 102.6 101.7 FACFM Gas Flow (acfm) 10741 10747 10874 10787 FDSCFM Gas Flow (dscfm) 3328 3322 3361 3337 FWSCFM Gas Flow (wscfm) 3785 3782 3825 3798 FKWSCFH Gas Flow (kwscfh) 227 227 230 228 FKWSCFM Gas Flow (kwscfm) 4 4 4 4 lb/hr Gas Flow (lb/hr) 16447 16428 16619 16498 Fo Fo (unitless)2.080 2.088 2.083 2.084 wet O2 (%vw)8.432 8.347 8.359 8.379 wet CO2 (%vw)4.785 4.799 4.809 4.798 wet NOX (ppmvw)71.212 69.929 69.795 70.312 15 NOX (ppmvd @ 15% O2)42.220 41.167 41.110 41.499 82.0 lb/hr NOX (lb/hr)1.929 1.892 1.910 1.910 g/bhp-hr NOX (g/bhp-hr)0.452 0.444 0.448 0.448 1.0 wet CO (ppmvw) 8.723 9.174 9.749 9.215 15 CO (ppmvd @ 15% O2)5.172 5.401 5.742 5.438 ,270 lb/hr CO (lb/hr) 0.144 0.151 0.162 0.152 g/bhp-hr CO (g/bhp-hr) 0.034 0.035 0.038 0.036 2.0 dry NMEOC (ppmvd as C3H8)12.576 12.800 13.164 12.847 15 NMEOC (ppmvd as C3H8 @ 15% O2)6.559 6.623 6.817 6.666 60 lb/hr NMEOC (lb/hr as C3H8)0.287 0.292 0.303 0.294 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.067 0.068 0.071 0.069 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Caterpillar G3516H engine; SN: H6C00285 Test Date: 8/20/24 O2 21.0 10.760 0.0 10.7 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 10.8 % 0.00 10.760 20.98 0.0 10.8 20.8 0.0 0.0 0.2 0.0 0.00% 0.48% 1.10% Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias 4 Difference 1 4 Response 1 2 Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value Page 2 of 5 Run 1 Ovintiv USA Inc. Run 1 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 9:14 Caterpillar G3516H engine; SN: H6C00285 Run Length 60 Test Date: 8/20/24 Stop Time 10:14 O2 21.0 10.76 0.0 10.7 0.0 11.0 0.0% 1.0% 0.0% 1.3% Corrected O2 % 9.587 Run Length (Minutes) Uncorrected O2 % 60 9.64 Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Page 3 of 5 Run 2 Ovintiv USA Inc. Run 2 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 10:25 Caterpillar G3516H engine; SN: H6C00285 Run Length 60 Test Date: 8/20/24 Stop Time 11:25 O2 21.0 10.76 0.0 10.7 0.0 11.0 0.0% 1.0% 0.0% 1.3% Corrected O2 % 9.497 Run Length (Minutes) Uncorrected O2 % 60 9.55 Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Page 4 of 5 Run 3 Ovintiv USA Inc. Run 3 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 11:35 Caterpillar G3516H engine; SN: H6C00285 Run Length 60 Test Date: 8/20/24 Stop Time 12:35 O2 21.0 10.76 0.0 10.7 0.0 11.0 0.0% 1.0% 0.0% 1.3% Corrected O2 % 9.507 Run Length (Minutes) Uncorrected O2 % 60 9.56 Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Page 5 of 5 Emissions Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Caterpillar G3516H engine; SN: H6C00280 Test Date: 8/20/24 Run # 1 2 3 Average Start Time 13:14 14:23 15:33 Stop Time 14:14 15:23 16:33 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 1934 1934 1934 1934 DS Stack Diameter (inches) 18.0 18.0 18.0 18.0 PAVG Average (Delta P)½ (" H2O)½0.7865 0.7960 0.8014 0.7946 CP Pitot Tube Constant (unitless) 0.99 0.99 0.99 0.99 TS Stack Temperature (°F) 784 785 785 785 Pbar Barometric Pressure (mbar) 839 838 837 838 Pbar Barometric Pressure (" Hg) 24.77 24.73 24.71 24.74 Ps Stack Pressure ('' H2O)0.62 0.63 0.64 0.63 O2%vd O2 (%vd)9.4 9.4 9.5 9.4 CO2%vd CO2 (%vd)5.4 5.5 5.5 5.5 N2%vd N2 (%vd)85.2 85.1 85.1 85.1 dry NOX (ppmvd)85.1 82.2 83.1 83.5 dry CO (ppmvd) 8.2 8.1 8.4 8.2 wet NMNEOC (ppmvw as C3H8)11.5 11.4 11.6 11.5 Run # 1 2 3 Average Bws Measured Moisture Content (%/100) 0.120 0.121 0.121 0.121 Bws Saturated Moisture Content (%/100) 384.546 386.860 387.240 386.215 Bws Actual Moisture Content (%/100) 0.120 0.121 0.121 0.121 MD Molecular Weight Dry (lb/lb-mole) 29.25 29.25 29.25 29.25 MA Molecular Weight Wet (lb/lb-mole) 27.90 27.89 27.89 27.89 VS Gas Velocity (ft/sec) 89.2 90.4 91.1 90.3 FACFM Gas Flow (acfm) 9462 9588 9659 9570 FDSCFM Gas Flow (dscfm) 2929 2956 2975 2953 FWSCFM Gas Flow (wscfm) 3330 3367 3388 3362 FKWSCFH Gas Flow (kwscfh) 200 202 203 202 FKWSCFM Gas Flow (kwscfm) 3 3 3 3 lb/hr Gas Flow (lb/hr) 14467 14621 14715 14601 Fo Fo (unitless)2.115 2.099 2.088 2.101 wet O2 (%vw)8.270 8.274 8.327 8.290 wet CO2 (%vw)4.788 4.806 4.806 4.800 wet NOX (ppmvw)74.920 72.197 73.009 73.375 15 NOX (ppmvd @ 15% O2)43.660 42.213 42.911 42.928 82.0 lb/hr NOX (lb/hr)1.785 1.739 1.770 1.765 g/bhp-hr NOX (g/bhp-hr)0.419 0.408 0.415 0.414 1.0 wet CO (ppmvw) 7.233 7.092 7.408 7.244 15 CO (ppmvd @ 15% O2)4.215 4.147 4.354 4.239 ,270 lb/hr CO (lb/hr) 0.105 0.104 0.109 0.106 g/bhp-hr CO (g/bhp-hr) 0.025 0.024 0.026 0.025 2.0 dry NMEOC (ppmvd as C3H8)13.022 12.992 13.256 13.090 15 NMEOC (ppmvd as C3H8 @ 15% O2)6.679 6.675 6.846 6.733 60 lb/hr NMEOC (lb/hr as C3H8)0.262 0.263 0.271 0.265 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.061 0.062 0.063 0.062 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Caterpillar G3516H engine; SN: H6C00280 Test Date: 8/20/24 O2 21.0 10.760 0.0 10.7 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 10.8 % 0.00 10.760 20.98 0.0 10.8 20.8 0.0 0.0 0.2 0.0 0.00% 0.48% 1.10% Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value 4 Difference 1 4 Response 1 2 Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias Page 2 of 5 Run 1 Ovintiv USA Inc. Run 1 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 13:14 Caterpillar G3516H engine; SN: H6C00280 Run Length 60 Test Date: 8/20/24 Stop Time 14:14 O2 21.0 10.76 0.0 10.7 0.0 10.9 0.0% 0.9% 0.0% 1.2% Corrected O2 % 9.396 Run Length (Minutes) Uncorrected O2 % 60 9.44 Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Page 3 of 5 Run 2 Ovintiv USA Inc. Run 2 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 14:23 Caterpillar G3516H engine; SN: H6C00280 Run Length 60 Test Date: 8/20/24 Stop Time 15:23 O2 21.0 10.76 0.0 10.7 0.0 10.9 0.0% 0.9% 0.0% 1.2% Corrected O2 % 9.416 Run Length (Minutes) Uncorrected O2 % 60 9.46 Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Page 4 of 5 Run 3 Ovintiv USA Inc. Run 3 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 15:33 Caterpillar G3516H engine; SN: H6C00280 Run Length 60 Test Date: 8/20/24 Stop Time 16:33 O2 21.0 10.76 0.0 10.7 0.0 10.9 0.0% 0.9% 0.0% 1.2% Corrected O2 % 9.476 Run Length (Minutes) Uncorrected O2 % 60 9.52 Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Page 5 of 5 Emissions Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Caterpillar G3516H engine; SN: H6C00248 Test Date: 8/21/24 Run # 1 2 3 Average Start Time 8:15 9:24 10:36 Stop Time 9:15 10:24 11:36 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 1879 1879 1879 1879 DS Stack Diameter (inches) 18.0 18.0 18.0 18.0 PAVG Average (Delta P)½ (" H2O)½0.7092 0.7376 0.7470 0.7313 CP Pitot Tube Constant (unitless) 0.99 0.99 0.99 0.99 TS Stack Temperature (°F) 809 807 805 807 Pbar Barometric Pressure (mbar) 838 838 838 838 Pbar Barometric Pressure (" Hg) 24.75 24.75 24.73 24.74 Ps Stack Pressure ('' H2O)0.50 0.54 0.56 0.53 O2%vd O2 (%vd)9.3 9.3 9.4 9.3 CO2%vd CO2 (%vd)5.6 5.6 5.6 5.6 N2%vd N2 (%vd)85.1 85.1 85.1 85.1 dry NOX (ppmvd)79.8 81.2 80.2 80.4 dry CO (ppmvd) 12.3 12.5 12.5 12.4 wet NMNEOC (ppmvw as C3H8)12.3 12.3 12.4 12.3 Run # 1 2 3 Average Bws Measured Moisture Content (%/100) 0.123 0.123 0.124 0.123 Bws Saturated Moisture Content (%/100) 436.277 431.815 428.075 432.055 Bws Actual Moisture Content (%/100) 0.123 0.123 0.124 0.123 MD Molecular Weight Dry (lb/lb-mole) 29.26 29.27 29.27 29.26 MA Molecular Weight Wet (lb/lb-mole) 27.88 27.88 27.87 27.88 VS Gas Velocity (ft/sec) 81.4 84.5 85.6 83.8 FACFM Gas Flow (acfm) 8626 8965 9074 8888 FDSCFM Gas Flow (dscfm) 2605 2710 2745 2687 FWSCFM Gas Flow (wscfm) 2972 3094 3135 3067 FKWSCFH Gas Flow (kwscfh) 178 186 188 184 FKWSCFM Gas Flow (kwscfm) 3 3 3 3 lb/hr Gas Flow (lb/hr) 12903 13431 13607 13314 Fo Fo (unitless)2.082 2.077 2.069 2.076 wet O2 (%vw)8.176 8.164 8.214 8.185 wet CO2 (%vw)4.876 4.891 4.881 4.883 wet NOX (ppmvw)70.001 71.179 70.322 70.501 15 NOX (ppmvd @ 15% O2)40.678 41.346 41.075 41.033 82.0 lb/hr NOX (lb/hr)1.488 1.576 1.577 1.547 g/bhp-hr NOX (g/bhp-hr)0.359 0.380 0.381 0.373 1.0 wet CO (ppmvw) 10.749 10.928 10.929 10.868 15 CO (ppmvd @ 15% O2)6.246 6.348 6.384 6.326 ,270 lb/hr CO (lb/hr) 0.139 0.147 0.149 0.145 g/bhp-hr CO (g/bhp-hr) 0.034 0.036 0.036 0.035 2.0 dry NMEOC (ppmvd as C3H8)13.985 14.074 14.197 14.085 15 NMEOC (ppmvd as C3H8 @ 15% O2)7.127 7.166 7.267 7.187 60 lb/hr NMEOC (lb/hr as C3H8)0.250 0.262 0.267 0.260 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.060 0.063 0.065 0.063 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Ovintiv USA Inc. Boston SWD (Site ID: 101838) Duchesne County, Utah Caterpillar G3516H engine; SN: H6C00248 Test Date: 8/21/24 O2 21.0 10.760 0.0 10.7 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 10.6 % 0.00 10.760 20.98 0.0 10.6 20.6 0.0 0.2 0.4 0.0 0.00% 0.57% 1.81% Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value 4 Difference 1 4 Response 1 2 Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias Page 2 of 5 Run 1 Ovintiv USA Inc. Run 1 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 8:15 Caterpillar G3516H engine; SN: H6C00248 Run Length 60 Test Date: 8/21/24 Stop Time 9:15 O2 21.0 10.76 0.0 10.7 0.0 10.8 0.0% 1.2% 0.0% 0.6% Corrected O2 % 9.323 Run Length (Minutes) Uncorrected O2 % 60 9.31 Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Page 3 of 5 Run 2 Ovintiv USA Inc. Run 2 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 9:24 Caterpillar G3516H engine; SN: H6C00248 Run Length 60 Test Date: 8/21/24 Stop Time 10:24 O2 21.0 10.76 0.0 10.7 0.0 10.8 0.0% 1.2% 0.0% 0.6% Corrected O2 % 9.313 Run Length (Minutes) Uncorrected O2 % 60 9.30 Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Page 4 of 5 Run 3 Ovintiv USA Inc. Run 3 Boston SWD (Site ID: 101838) Duchesne County, Utah Start Time 10:36 Caterpillar G3516H engine; SN: H6C00248 Run Length 60 Test Date: 8/21/24 Stop Time 11:36 O2 21.0 10.76 0.0 10.7 0.0 10.8 0.0% 1.2% 0.0% 0.6% Corrected O2 % 9.373 Run Length (Minutes) Uncorrected O2 % 60 9.36 Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Page 5 of 5 09/09/2024 VIA Stack Test Report Submission: https://utahgov.co1.qualtrics.com/jfe/form/SV_3dSxf7JSzy4jwGh Rik Ombach Manager, Minor Source Compliance Utah Department of Environmental Quality Division of Air Quality 195 North 1950 West Salt Lake City, Utah 84116 RE: Performance Test Reports Ovintiv USA Inc. Boston SWD (CAERS ID: 101838) Pleasant Valley Compressor Station (DAQE-AN142100007-23) Duchesne County, UT Dear Mr. Ombach: Ovintiv USA Inc. is submitting the attached performance test reports for the spark ignition internal combustion engines that are subject to the following requirements: • 40 CFR Part 60 Subpart JJJJ, 40 CFR §60.8, 40 CFR §60.4243(b)(2)(ii), 40 CFR §60.4245(d) • Permit by Rule and Approval Order Facility Unit Description Manufacturer & Model Serial Number Date of Performance Testing Boston SWD 90075729 Doosan 8.8L 0012527 08/21/2024 SW700322 Caterpillar G3516H H6C00285 08/20/2024 SW700332 Caterpillar G3516H H6C00280 08/20/2024 SW700631 Caterpillar G3516H H6C00248 08/21/2024 Pleasant Valley Compressor Station Unit 1 Caterpillar G3516 TALE 4EK04758 08/06/2024 Unit 2 Caterpillar G3516 TALE WPW01912 08/27/2024 Unit 3 Caterpillar G3516 TALE WPW02348 08/07/2024 Unit 4 Caterpillar G3516 TALE WPW02396 08/07/2024 Unit 5 Caterpillar G3516 LE WPW01760 08/08/2024 Results from the performance tests indicate that the engines have demonstrated compliance with emission limit requirements. If you have any questions, please contact me at 720-876-3144 or ryan.zillner@ovintiv.com. Sincerely, Ryan Zillner Senior Air Quality Engineer Performance Test Report Test Type: Initial Test Date: 8/21/2024 Doosan 8.8L Rich Burn (4 Cycle) DOM: 10/29/18 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:01:27 PM 05:04 PM Source: Unit Number: 90075729 Serial Number: 0012527 Engine Hours:94.46 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Boston SWD 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 64.371 13.861 2.768 2.000 1.000 0.700 0.097 0.034 0.007 Pass Pass Pass Federal Federal Federal Results ppmvd Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 27 28 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 GAS ALT 141_FTIR EPA............................................................15.0 Tester Qualifications (resume)....................................................2716.0 D6348 Annexes..........................................................................1211.0 18 19 25 8.0 9.0 10.0 Raw Data....................................................................................2817.0 1.0 Key Personnel GAS, Inc. Ovintiv USA Inc. 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Brian Webb 3 Cooper Green Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit 90075729 with a serial number of 0012527 which is a Doosan 8.8L engine located at Boston SWD and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/21/2024 by Cooper Green with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Rich Burn (4 Cycle) engine rated at 261 brake horse power (BHP) at 1800 RPM. The engine was operating at 146 BHP and 1799 RPM which is 56.00% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. 4 4.0 Test Summary Engine/Compressor Specs Boston SWDLocation 90075729Unit ID Make Doosan Site Elevation ft.5501 Model 8.8L Atmospheric Pressure psi.12.12 Serial Number 0012527 Stack Diameter in.3.5 mfg. rated hp 261 Yes 1800 Date of Manufacture 10/29/2018 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 146 146 146 146 1800 1799 1799 1799 Percent Load % Intake Manifold Pressure (hg) 56.00%56.00%56.00%56.00% -24.68 -24.68 -24.68 -24.68 Intake Manifold Temperature (F)N/A N/A N/A N/A Ambient Conditions Ambient Temperature Dry (F)86.00 88.00 89.00 87.67 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 6630.26 6714.31 6728.72 6691.10 187.75 190.13 190.53 189.47 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.19 0.19 0.19 0.19 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %19.14%18.88%18.98%19.00% T e s t S u m m a r y mfg. rated rpm Test RPM 0.26%0.26%0.30%0.27% Permitted Standards Results 5 Catalyst 0.0810.078 Run 1 Run 2 Run 3 3 Run Average Pass Permits 01:27 PM 02:36 PM 03:48 PM 8/21/2024 CO (g/hp-hr)0.131 0.0972.000 Pass Federal CO (ppmvw)70.989 41.905 43.477 52.123 CO (ppmvd)87.795 51.656 53.661 64.371 CO (mol wt) 28.01 CO (ppmvd) @15% O2 25.097 14.763 15.369 18.409 Fail CO (ppbvd) @15% O2 25096.753 14763.139 15368.516 18409.469 Fail NOx (g/hp-hr)0.057 0.023 0.023 0.0341.000 Pass NOx (ppmvw)18.672 7.459 7.532 11.221 NOx (ppmvd)23.092 9.194 9.296 13.861 NOx (mol wt) 46.01 1.434 2.332 2.963 2.243NMNEHC (ppmvw) 1.773 2.875 3.657 2.768NMNEHC (ppmvd) NOx (ppbvd) @15% O2 6601.162 2627.662 2662.457 3963.760 Fail NOx (ppmvd) @15% O2 6.601 2.628 2.662 3.964 Fail NMNEHC (mol wt) 44.10 506.966 821.574 1047.379 791.973 FailNMNEHC (ppbvd) @15% O2 0.004 0.007 0.009 0.0070.700 PassNMNEHC (g/hp-hr) 0.507 0.822 1.047 0.792 FailNMNEHC (ppmvd) @15% O2 Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 1.02Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 70.99 0.49 17.49 0.00 1.18 0.49 18.67 0.83 1.43 0.13% 0.21% 0.00% 19.14% NMNEHC 73.28 24.67 1.34 26.01 1.45 0.25%19.24% 65.06 28.56 2.50 31.06 21.65 0.44%17.77% 68.70 10.31 1.02 11.34 1.42 0.16%19.05% 0.00 0.00 0.00 0.00 0.21 0.16%0.17% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.21 0.16%0.17% 46.44 7.03 0.53 7.56 1.90 0.18%18.93% 60.81 22.74 0.41 23.16 20.88 0.18%17.38% 37.37 7.15 0.21 7.36 2.77 0.22%18.83% 0.74 0.00 0.00 0.00 0.42 0.20%0.15% Avg. Wet 41.90 7.09 0.37 7.46 2.33 0.20%18.88% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 43.87 7.23 0.20 7.42 2.90 0.22%18.92% 69.71 27.56 0.47 28.03 23.23 0.25%17.55% 43.09 7.61 0.03 7.64 3.03 0.25%19.04% 0.39 0.00 0.00 0.00 0.38 0.19%0.14% 0.74 0.00 0.00 0.00 0.42 0.20%0.15% Avg. Wet 43.48 7.42 0.11 7.53 2.96 0.24%18.98% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 3.5 inches or:.29 feet. or:.07 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.77 Yes 3.50 3.00 2.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 19.14 29.46 0.74 Inches 1.75 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points Single Point Sampling Used @ 6 inches and Under 9.04 0.21 70.99 835.35 0.05 24.67 24.73 827.44 1287.11 441.91 27.26 100.56 6.72 8199.93 6630.26 Run 2 18.88 29.46 0.76 9.07 0.21 41.90 834.35 0.06 24.64 24.70 829.38 1289.05 442.99 27.30 101.77 6.80 8276.85 6714.31 Run 3 18.98 29.46 0.76 9.04 0.24 43.48 833.98 0.06 24.63 24.69 829.31 1288.98 442.95 27.28 102.15 6.83 8304.86 6728.72 19.00 29.46 0.75 9.05 0.22 52.12 834.56 0.06 24.65 24.70 828.71 1288.38 442.62 27.28 101.49 6.78 8260.75 6691.22 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.71 Exhaust Temp F 827.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.72 0.72 0.72 827.00 828.00 827.00 0.73 0.72 0.72 827.00 828.00 828.00 0.73 0.74 0.75 827.00 827.00 828.00 0.75 828.00 0.75 0.76 0.76 827.00 827.00 828.00 0.77 0.78 0.74 828.00 827.00 827.44 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.76 Exhaust Temp F 829.00 0.76 0.77 0.78 829.00 829.00 830.00 0.73 0.75 0.75 829.00 829.00 830.00 0.74 0.79 0.75 829.00 829.00 830.00 0.77 830.00 0.74 0.76 0.78 829.00 829.00 829.00 0.78 0.77 830.00 829.00 829.310.76 Run 2 Δpstd (in) H2O 0.77 Exhaust Temp F 829.00 0.74 0.74 0.77 829.00 829.00 830.00 0.78 0.76 0.75 829.00 829.00 830.00 0.78 0.75 0.76 830.00 829.00 829.00 0.74 829.00 0.73 0.73 0.75 830.00 829.00 830.00 0.77 0.78 830.00 829.00 0.76 829.38 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.09)+.32(.003)+.28(.9+.007) = 29.457 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.457(1 -.19143)+.18.0(.19143) = 27.264 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.74*√(1287.1075/(24.73*27.264)) = 100.56 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.191)100.557*.067((528*24.73)/ (1287.1075*29.92)) = 6630.26 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 6630.257/35.315 = 187.746 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 87.795*(20.9-15)/(20.9-.3%)) = 25.145 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (87.795*(1.164*10^-3)*187.746*(Run Time/60))/146.16 = .131 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .131*1/453.6*146.16 = .042 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .042*4.38 = .184 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 87.79 = 70.9885*(1/(1-.19))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.56% 20.60% 10.68% 10.79% 10.76% 10.76% 10.79%10.68% 10.56% 20.60% 10.76% 20.98% 10.76% 20.98% 10.76%20.98% 0.00% 10.76% 20.98% 0.20% 0.38% 0.94% 1.83% 10.76% Span Zero Offset 0.00% 20.98 0.00% 10.56%0.54%1.08%0.01% 0.26% 0.26% 0.30% 0.26% 0.26% 0.30% 9 Gas, Inc. 0.0 0.0 0.0 0.0 0.0 0.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Boston SWD 8/21/2024 5501 90075729 Doosan Model Serial Number 8.8L 0012527 Technician Cooper Green Run Start Times 01:27 PM 02:36 PM 03:48 PM 05:04 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1800.0 1799.0 1799.0 1799.3 Engine Hours 91.46 92.46 93.46 94.46 Intake Manifold Pressure (psi)N/A N/A N/A N/A Intake Manifold Temp °F N/A N/A N/A N/A Engine Load (BHP)146.2 146.2 146.2 146.2 Ambient Temp °F 86.0 88.0 89.0 87.7 Humidity %26.0 21.0 20.0 22.3 Dew Point °F 47.0 43.0 43.0 44.3 Murphy YesCatalyst (Yes or No) AFR Manufacturer/Type Murphy Murphy Murphy 10 Run 3 AverageRun 2 0.0 0.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.07 R e s u l t s Average:Nitrogen monoxide NO 0.07 Average:Nitrogen dioxide NO2 0.12 Average:NOx 0.18 Average:VOC 0.04 Average:Oxygen 0.17 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.36 Tolerance 2.00% Difference between measured and expected 0.64% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 1.16 Average:Nitrogen monoxide NO 0.73 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.73 Average:VOC 0.77 Average:Oxygen 0.14 Pre-test System Zero Time: Mechanical Response Time 5 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 95.16 Tolerance 5.00% Difference between measured and expected 4.84% Pre-test System CTS & Mechanical Response Time 45 secondsEquilibration Response Time Value:Spike Reported 254.37 Value:Spike Expected 258.20 System (Equilibration) Response Time Target (Spike) 81 secondsSystem Zero Response Time 81 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC511346 4/24/2027 98.96 10.76% CC706226 4/24/2032 100.00 CC185396 6/17/2032 20.98% Cylinder # CC102850 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 258.20 502.80 243.30 10.14 Analyzer System Response 254.37 501.99 238.15 10.00 Percent Difference 1.48%0.16%2.12%1.41% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.365 4.968 Spike Direct Propane 255.470 Mechanical Response Time SF6 10.018 CO 503.775 NO 239.567 Ethylene 95.156 5 seconds Analyzer Response Propane 254.373 SF6 9.997 CO 501.989 NO 238.152 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.288 CO 497.040 NO 235.961 31 seconds 81 seconds 7.71% 7.11% 7.79% 94.27% 95.58% 96.32% 9.970 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Central Sampling Point Location in Inches 50%1.750 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 3.5 3 2 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 6691.22 H2O%d @ Sampling Point:19 CO2%d @ Sampling Point:9.05 Pressure @ Sampling Point (Pg "H2O):0.75 Temperature @ Sampling Point (Deg F):828.71 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99.36 4.968 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.365 4.968 Spike Direct Propane 255.470 Mechanical Response Time SF6 10.018 CO 503.775 NO 239.567 Ethylene 95.156 5 seconds Analyzer Response Propane 254.373 SF6 9.997 CO 501.989 NO 238.152 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.288 CO 497.040 NO 235.961 31 seconds 81 seconds 7.71% 7.11% 7.79% 94.27% 95.58% 96.32% 9.970 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 258.200 10.140 502.800 243.300 255.470 10.018 503.775 239.567 1.06% 1.20% 0.19% 1.53% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 0.016 0.005 Spike Average 18.780 0.772 Dilution Factor 7.706% Expected 19.922 % Recovery 94.270% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.007 Spike Average 0.712 Dilution Factor 7.107% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.009 Spike Average 0.780 Dilution Factor 7.786% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 0.102 19.464 20.208 96.320% 0.001197 0.000585 0.000222 0.111 17.645 18.461 95.580% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass1.36% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:9.95939222 Pass Line Position Difference:Resolution Difference to Reference 1.36% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 103.82 3.68% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Boston SWD; 90075729; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/21/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/21/2024 Cooper Green Gas, Inc. Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. 21% O2 Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Cooper Green GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Boston SWD Unit Number:90075729 Make:Doosan Location:8.8LModel: 0012527Serial Number: RAW Result Data Stability 8/21/2024 05:19 0.0000.000-0.025 0.012 0.0000.000 0.000 0.000 0.0000.0000.000 0.126 0.0000.066 0.000 835.00.480.590 0.000 0.00 0.14 179.0 Pre Test Baseline Direct 8/21/2024 05:27 0.0000.203-0.002 0.000 0.1520.079 0.015 0.058 0.0000.1800.000 0.000 0.0000.000 0.000 835.00.040.054 0.000 0.20 0.23 181.0 8/21/2024 05:27 0.3460.000-0.002 0.000 0.0400.013 0.012 0.000 0.0000.0000.000 0.000 0.0000.000 0.000 835.00.040.055 0.004 0.35 0.15 181.0 8/21/2024 05:28 0.0000.000-0.003 0.000 0.0000.110 0.012 0.000 0.0000.0000.000 0.000 0.0000.123 0.000 835.00.040.057 0.000 0.00 0.14 181.0 CTS Direct 8/21/2024 05:32 0.0000.1980.017 0.001 0.0000.116 0.034 0.000 0.0000.0700.000 100.093 0.0000.000 0.011 835.066.760.008 0.006 0.20 0.20 181.0 8/21/2024 05:32 0.0000.0530.017 0.007 0.0000.067 0.032 0.144 0.0000.0000.000 99.902 0.0000.108 0.001 835.066.700.133 0.004 0.05 0.20 181.0 8/21/2024 05:33 0.1700.2440.015 0.003 0.0000.112 0.015 0.000 0.0360.0000.110 98.099 0.0100.000 0.011 835.065.440.011 0.005 0.41 0.19 181.0 High O2 Direct 8/21/2024 05:43 0.0000.049-0.004 0.000 0.0500.138 0.024 0.110 0.0000.0000.407 0.000 0.0000.258 0.000 835.00.120.180 0.000 0.05 20.56 180.0 8/21/2024 05:43 0.0000.127-0.005 0.000 0.0000.233 0.030 0.253 0.0000.0600.487 0.051 0.0000.000 0.000 835.00.210.271 0.003 0.13 20.56 180.0 8/21/2024 05:43 0.0000.000-0.005 0.000 0.0200.082 0.029 0.110 0.0000.0430.657 0.085 0.0000.093 0.000 835.00.190.207 0.005 0.00 20.67 180.0 NO2/Mid O2 Direct 8/21/2024 05:52 98.4080.281-0.003 0.000 0.1080.035 0.386 0.000 0.6180.0001.244 0.000 0.0000.203 0.000 835.00.000.000 0.000 98.69 10.57 180.0 8/21/2024 05:52 97.1290.627-0.001 0.000 1.0380.156 0.380 0.000 0.7990.0001.233 0.000 0.0000.159 0.000 835.00.000.000 0.000 97.76 10.55 180.0 8/21/2024 05:52 98.3270.860-0.004 0.000 0.4630.088 0.383 0.000 0.4920.0021.423 0.000 0.0000.192 0.000 835.00.000.000 0.000 99.19 10.57 180.0 Spike Direct 8/21/2024 05:57 0.000239.4600.001 4.677 2.605503.680 1.293 1.783 5.1400.0271.581 1.379 255.4490.271 0.000 835.0258.152.673 10.013 239.46 0.14 180.0 8/21/2024 05:57 0.000239.688-0.001 4.682 2.106503.394 1.269 1.983 5.1420.1432.250 1.366 255.5470.277 0.000 835.0258.452.983 10.025 239.69 0.14 180.0 8/21/2024 05:58 0.000239.5530.000 4.678 3.023504.250 1.340 2.014 5.2670.3380.543 1.382 255.4140.162 0.000 835.0258.363.038 10.016 239.55 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/21/2024 06:00 0.0000.5390.017 0.000 0.2661.339 0.068 1.599 0.0000.0000.538 0.000 0.4710.000 0.117 835.00.920.318 0.015 0.54 0.14 180.0 8/21/2024 06:01 0.0000.8390.017 0.000 0.0161.064 0.058 1.437 0.0000.0020.204 0.135 0.2730.000 0.099 835.00.640.109 0.008 0.84 0.14 180.0 8/21/2024 06:01 0.0000.8000.013 0.000 0.1231.063 0.049 1.178 0.0720.0000.801 0.024 0.2770.000 0.119 835.00.760.341 0.004 0.80 0.14 180.0 CTS System with Response Time 8/21/2024 06:06 0.0000.0000.019 0.000 0.0000.671 0.062 0.731 0.0880.0030.618 95.116 0.0290.039 0.105 835.063.810.233 0.012 0.00 0.18 180.0 8/21/2024 06:07 0.0000.0000.018 0.001 0.0000.663 0.043 1.073 0.0000.0000.000 95.188 0.0860.000 0.081 835.063.830.173 0.015 0.00 0.18 180.0 8/21/2024 06:07 0.0000.2080.017 0.000 0.0000.647 0.040 0.979 0.0840.0290.000 95.164 0.0060.000 0.104 835.063.810.224 0.013 0.21 0.18 180.0 NO2/Mid O2 System with Response Time 8/21/2024 06:10 94.6211.7220.009 0.000 0.6050.634 0.390 0.806 0.0000.0010.000 0.007 0.0000.101 0.144 835.00.410.173 0.012 96.34 10.63 180.0 8/21/2024 06:10 95.7031.4730.010 0.000 0.6730.692 0.376 0.753 0.0000.0050.000 0.041 0.0000.300 0.117 835.00.600.510 0.008 97.18 10.66 180.0 8/21/2024 06:11 97.0511.9090.012 0.000 0.1040.605 0.393 0.830 0.0000.0120.000 0.000 0.0000.274 0.129 835.00.540.416 0.001 98.96 10.74 180.0 Spike System with Response Time 8/21/2024 06:13 0.000238.0860.004 4.658 2.607502.404 1.305 2.480 5.0260.1730.819 1.526 254.4840.000 0.000 835.0257.372.803 9.997 238.09 0.13 180.0 8/21/2024 06:14 0.000238.0580.004 4.670 2.528500.182 1.290 2.264 5.6960.0800.801 1.517 254.1710.275 0.000 835.0257.253.106 10.000 238.06 0.14 180.0 8/21/2024 06:14 0.000238.3110.007 4.662 2.561503.381 1.329 2.431 4.8450.0340.707 1.519 254.4640.000 0.000 835.0257.493.022 9.994 238.31 0.14 180.0 Baseline System with Response Time 8/21/2024 06:18 0.0000.8120.005 0.000 0.2191.202 0.073 0.720 0.0000.0010.631 0.390 0.4080.000 0.020 835.00.940.346 0.012 0.81 0.13 180.0 8/21/2024 06:18 0.0000.5720.009 0.000 0.3130.936 0.076 0.515 0.0000.0000.621 0.000 0.5210.000 0.000 835.00.770.375 0.011 0.57 0.14 180.0 8/21/2024 06:18 0.0000.0800.007 0.000 0.1660.927 0.057 0.706 0.0000.0000.634 0.185 0.3900.000 0.006 835.00.790.395 0.009 0.08 0.14 180.0 Run 1 - A 30minute/60min 8/21/2024 13:28 1.58844.39919.232 8.980 32.31715.575 0.000 1.063 1.1650.0010.000 0.996 0.0000.746 0.178 836.01.520.747 0.002 45.99 0.13 180.0 8/21/2024 13:29 1.8416.14019.213 8.993 8.691151.014 0.000 5.358 0.2790.0200.000 1.069 0.0000.666 0.165 836.01.450.605 0.006 7.98 0.13 180.0 8/21/2024 13:30 1.36052.52319.281 9.032 34.16551.373 0.000 4.420 1.3500.0310.000 0.941 0.0000.591 0.180 836.01.590.900 0.004 53.88 0.13 180.0 8/21/2024 13:31 2.1847.56519.221 9.008 7.82671.957 0.000 3.564 0.4230.0610.000 0.983 0.0000.756 0.202 836.01.540.726 0.006 9.75 0.14 180.0 8/21/2024 13:32 1.37546.85519.287 9.017 31.36128.498 0.000 1.074 1.5280.0160.000 0.948 0.0000.762 0.184 836.01.440.665 0.004 48.23 0.38 180.0 8/21/2024 13:33 1.9038.86119.239 9.017 11.224108.380 0.000 3.564 0.4900.0340.000 0.979 0.0000.741 0.146 836.01.360.621 0.001 10.76 0.14 180.0 8/21/2024 13:34 0.0007.61219.289 9.017 11.89655.568 0.000 1.494 0.5320.0390.000 1.068 0.0000.716 0.167 836.01.520.709 0.008 7.61 0.27 180.0 8/21/2024 13:35 0.94616.31419.313 9.035 18.74925.709 0.000 0.918 0.7270.0000.000 1.040 0.0000.759 0.139 836.01.400.640 0.005 17.26 0.13 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 13:36 1.1094.49019.267 9.012 12.11194.475 0.000 1.484 0.4410.0440.000 1.012 0.0000.652 0.163 836.01.480.726 0.001 5.60 0.13 180.0 8/21/2024 13:37 1.14348.35019.246 9.030 31.59540.620 0.000 2.712 1.0530.0000.000 1.041 0.0000.729 0.181 836.01.520.695 0.004 49.49 0.13 180.0 8/21/2024 13:38 1.2405.17119.245 9.039 11.921103.884 0.000 4.184 0.7730.0210.000 0.998 0.0000.606 0.121 836.01.440.801 0.007 6.41 0.14 180.0 8/21/2024 13:39 1.16459.30919.214 9.005 34.76543.169 0.000 4.269 1.9080.0090.000 0.878 0.1130.567 0.146 836.01.470.717 0.007 60.47 0.13 180.0 8/21/2024 13:40 1.1096.76919.157 9.014 15.596141.145 0.000 10.077 0.6240.0210.000 1.172 0.0000.629 0.164 836.01.410.450 0.004 7.88 0.14 180.0 8/21/2024 13:41 1.04848.26819.224 9.017 36.46437.377 0.062 2.688 1.3060.0050.000 0.961 0.0000.688 0.160 836.01.460.744 0.006 49.32 0.13 180.0 8/21/2024 13:42 1.4108.71619.206 9.023 20.176108.273 0.000 5.550 0.9410.0020.000 0.992 0.0000.645 0.144 836.01.480.801 0.003 10.13 0.82 180.0 8/21/2024 13:43 1.58611.15819.277 9.019 16.37460.286 0.000 2.388 0.7850.0050.000 0.937 0.0000.574 0.121 836.01.360.740 0.007 12.74 0.13 180.0 8/21/2024 13:44 1.5607.71519.305 9.048 11.70531.389 0.000 1.542 0.4620.0000.000 1.185 0.0000.499 0.141 836.01.420.527 0.005 9.28 0.13 180.0 8/21/2024 13:45 1.88629.74719.241 9.027 23.08861.624 0.000 1.610 0.9610.0040.000 1.116 0.0000.571 0.122 836.01.450.698 0.004 31.63 0.37 180.0 8/21/2024 13:46 1.3837.80419.247 9.039 13.82997.347 0.000 5.735 0.5290.0020.000 1.017 0.0000.623 0.155 836.01.400.623 0.008 9.19 0.14 180.0 8/21/2024 13:47 1.39973.73919.238 9.018 38.11668.508 0.044 4.178 1.4590.0000.000 1.260 0.0000.662 0.153 836.01.510.548 0.004 75.14 0.38 180.0 8/21/2024 13:48 1.58226.57019.198 9.032 19.647123.954 0.000 8.545 0.7790.0000.000 1.146 0.0000.441 0.125 836.01.500.729 0.004 28.15 0.15 180.0 8/21/2024 13:49 1.4348.37819.221 9.035 18.82781.548 0.000 5.037 1.0760.0000.000 1.204 0.0870.591 0.142 835.01.530.527 0.005 9.81 0.80 180.0 8/21/2024 13:50 0.81224.01719.246 9.037 20.83245.923 0.000 3.423 0.7260.0000.000 1.032 0.0000.494 0.133 835.01.290.506 0.008 24.83 0.13 180.0 8/21/2024 13:51 1.8827.89719.183 9.019 19.24183.842 0.000 5.878 0.5630.0030.000 1.166 0.0000.571 0.139 835.01.480.633 0.007 9.78 0.25 180.0 8/21/2024 13:52 1.7357.34519.265 9.042 13.90843.544 0.000 1.845 0.5730.0270.000 1.059 0.0000.472 0.144 835.01.390.593 0.006 9.08 0.13 180.0 8/21/2024 13:53 1.42285.46919.229 9.034 41.24734.890 0.000 2.081 2.1410.0000.000 1.121 0.0710.715 0.097 835.01.370.539 0.005 86.89 0.13 180.0 8/21/2024 13:54 1.26411.75219.220 9.021 18.513158.374 0.000 14.112 1.0070.0010.000 1.034 0.0390.658 0.092 835.01.370.681 0.011 13.02 0.15 180.0 8/21/2024 13:55 0.96110.83219.222 9.040 19.91366.123 0.000 3.317 1.3030.0000.000 1.171 0.0600.488 0.088 835.01.500.724 0.005 11.79 1.40 180.0 8/21/2024 13:56 1.02650.13919.202 9.042 31.47071.256 0.000 9.913 1.8240.0000.000 0.935 0.1110.615 0.120 835.01.470.743 0.005 51.16 0.13 180.0 8/21/2024 13:57 0.9146.09719.174 9.049 18.23692.772 0.000 6.096 0.7820.0140.000 1.176 0.0000.633 0.126 835.01.360.488 0.003 7.01 0.14 180.0 1.34224.66719.237 9.025 21.46073.280 0.004 4.271 0.9500.0120.000 1.055 0.0160.629 0.145 835.701.4490.662 0.005 26.009 0.254 180.0Avg. Spike 1 8/21/2024 14:00 2.50128.55517.767 8.648 22.76565.064 0.000 2.195 1.6760.0000.000 3.038 18.7800.507 0.172 835.021.650.757 0.772 31.06 0.44 180.0 Run 1 - B 30minute/60min 8/21/2024 14:02 1.2538.78619.253 9.034 15.40529.085 0.000 2.138 0.6100.0000.000 1.061 0.0000.760 0.156 835.01.180.245 0.010 10.04 0.13 180.0 8/21/2024 14:03 1.4097.87719.269 9.034 20.92663.023 0.000 5.212 0.6880.0000.000 1.126 0.0000.567 0.128 835.01.250.359 0.006 9.29 0.38 180.0 8/21/2024 14:05 0.8566.42119.201 9.036 19.75186.423 0.000 3.803 0.7970.0000.000 1.149 0.0000.595 0.126 835.01.500.729 0.009 7.28 0.13 180.0 8/21/2024 14:06 1.44234.53219.234 9.024 30.41948.332 0.000 4.993 1.0230.0020.000 1.136 0.0000.644 0.149 835.01.450.599 0.007 35.97 0.13 180.0 8/21/2024 14:07 0.0008.28319.265 9.037 18.766108.295 0.000 4.216 0.7290.0000.000 0.888 0.0000.469 0.107 835.01.060.387 0.007 8.28 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 14:08 0.0008.07019.222 9.012 28.44877.339 0.000 5.896 1.2400.0000.000 0.932 0.0000.501 0.119 835.01.260.598 0.009 8.07 0.38 180.0 8/21/2024 14:09 1.7917.11719.236 9.031 21.12553.159 0.000 1.982 1.0610.0000.000 0.966 0.0840.543 0.121 835.01.330.533 0.010 8.91 0.14 180.0 8/21/2024 14:10 1.00326.98619.227 9.058 27.62324.250 0.000 2.381 1.2620.0000.000 1.221 0.0970.566 0.125 835.01.490.493 0.006 27.99 0.13 180.0 8/21/2024 14:11 0.7493.46619.200 9.035 28.526180.350 0.000 21.187 1.3440.0000.000 1.317 0.0510.569 0.105 835.01.550.617 0.006 4.21 0.14 180.0 8/21/2024 14:12 1.49911.58719.165 9.038 22.02926.540 0.000 5.964 0.8330.0000.000 1.084 0.0000.602 0.109 835.01.120.275 0.008 13.09 0.14 180.0 8/21/2024 14:13 1.8495.87219.065 9.051 33.151126.665 0.000 7.853 1.6930.0000.000 1.020 0.0800.648 0.129 835.01.210.284 0.009 7.72 0.13 180.0 8/21/2024 14:14 1.4946.69119.151 9.062 22.01124.778 0.000 3.903 1.6400.0000.000 1.138 0.0280.624 0.098 835.01.260.418 0.006 8.19 0.14 180.0 8/21/2024 14:15 1.6296.57918.983 9.041 28.17747.853 0.000 2.681 1.3790.0000.000 1.160 0.0020.691 0.112 835.01.390.578 0.006 8.21 0.36 180.0 8/21/2024 14:16 1.1857.17118.925 9.047 33.66550.188 0.000 2.069 1.5450.0000.000 1.110 0.0660.586 0.091 835.01.430.665 0.011 8.36 0.14 180.0 8/21/2024 14:17 1.6456.98618.925 9.037 36.48848.025 0.000 3.482 1.9920.0000.000 1.118 0.0900.642 0.101 835.01.420.579 0.007 8.63 0.14 180.0 8/21/2024 14:18 0.0008.93218.892 9.065 27.96336.389 0.000 3.111 1.2970.0000.000 1.268 0.0960.586 0.078 835.01.480.571 0.005 8.93 0.14 180.0 8/21/2024 14:19 0.5037.99218.869 9.065 42.32868.704 0.000 4.612 1.7340.0000.000 1.149 0.1370.523 0.114 835.01.460.492 0.005 8.49 0.27 180.0 8/21/2024 14:20 1.03422.58818.915 9.078 31.37399.258 0.000 11.186 1.4170.0000.000 1.102 0.0660.678 0.115 835.01.370.501 0.007 23.62 0.15 180.0 8/21/2024 14:21 0.9317.60218.915 9.072 38.36381.734 0.000 6.231 1.6340.0000.000 0.939 0.0340.783 0.136 835.01.380.668 0.009 8.53 0.15 180.0 8/21/2024 14:22 1.3937.26918.975 9.087 37.03734.037 0.000 2.294 1.6720.0000.000 1.063 0.0720.605 0.117 835.01.580.841 0.009 8.66 0.15 180.0 8/21/2024 14:23 1.07910.14218.953 9.080 31.35329.355 0.000 4.096 1.5680.0000.000 0.968 0.1020.578 0.126 835.01.590.880 0.005 11.22 0.14 180.0 8/21/2024 14:24 0.7456.15718.946 9.052 57.948134.019 0.000 19.543 2.6010.0000.000 1.091 0.1190.721 0.148 835.01.680.813 0.009 6.90 0.14 180.0 8/21/2024 14:25 0.7377.26219.016 9.067 37.06721.138 0.000 4.657 1.5660.0000.000 1.207 0.1080.569 0.130 835.01.570.592 0.008 8.00 0.15 180.0 8/21/2024 14:26 0.9815.62218.973 9.078 71.005108.367 0.000 14.488 3.2780.0000.000 1.278 0.0270.955 0.122 835.01.430.464 0.004 6.60 0.14 180.0 8/21/2024 14:27 0.65321.34919.016 9.096 41.64954.731 0.202 10.003 1.7620.0000.000 0.867 0.0980.629 0.147 835.01.320.521 0.007 22.00 0.05 180.0 8/21/2024 14:28 1.1555.80418.930 9.069 50.11199.551 0.000 9.999 2.0180.0000.000 1.215 0.1010.491 0.135 835.01.770.883 0.007 6.96 0.15 180.0 8/21/2024 14:29 0.74720.44418.907 9.060 42.11223.758 0.204 5.764 1.6600.0000.000 1.015 0.1550.772 0.152 835.01.550.629 0.008 21.19 0.15 180.0 8/21/2024 14:30 0.9377.24618.898 9.051 41.087167.027 0.000 15.776 2.0170.0000.000 1.004 0.0410.608 0.112 835.01.280.514 0.008 8.18 0.15 180.0 8/21/2024 14:31 0.9337.20118.946 9.048 48.56165.957 0.000 8.867 2.0720.0000.000 1.033 0.0000.626 0.115 835.01.550.950 0.006 8.13 0.15 180.0 8/21/2024 14:32 1.0087.39818.981 9.077 48.22542.575 0.000 6.777 2.4000.0000.000 1.036 0.1440.479 0.147 835.01.660.793 0.004 8.41 0.15 180.0 1.02110.31419.048 9.054 34.42368.697 0.014 6.839 1.5510.0000.000 1.089 0.0600.620 0.122 835.001.4190.582 0.007 11.335 0.166 180.0Avg. 1.18217.49119.143 9.039 27.94270.988 0.009 5.555 1.2510.0060.000 1.072 0.0380.625 0.133 835.351.4340.622 0.006 18.672 0.210 180.0Run 1 Avg: Baseline 1 8/21/2024 14:34 0.0000.0000.168 0.000 0.4860.000 0.156 0.577 0.2270.0560.000 0.178 0.0920.000 0.000 835.00.210.000 0.012 0.00 0.16 180.0 Run 2 - A 30minute/60min 8/21/2024 14:37 0.7895.25118.914 9.027 60.295113.099 0.000 12.385 2.5890.0060.000 0.935 0.0730.656 0.127 835.01.590.953 0.010 6.04 0.15 180.0 8/21/2024 14:38 0.9527.43818.959 9.055 58.35637.175 0.000 6.756 2.3420.0020.000 1.061 0.1050.769 0.168 835.01.750.899 0.004 8.39 0.16 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 14:39 0.5546.50418.960 9.077 58.59041.008 0.000 3.919 2.3030.0000.000 1.223 0.0790.681 0.135 835.01.720.830 0.005 7.06 0.16 180.0 8/21/2024 14:40 0.7339.40818.976 9.070 58.40027.122 0.092 4.327 2.5250.0020.000 1.014 0.0660.799 0.123 835.01.520.795 0.002 10.14 0.16 180.0 8/21/2024 14:41 0.6164.45618.953 9.076 60.18987.826 0.000 4.686 2.4120.0000.000 0.973 0.0680.761 0.116 835.01.530.877 0.004 5.07 0.16 180.0 8/21/2024 14:43 1.4258.22018.962 9.085 48.51629.193 0.017 5.058 2.0680.0030.000 1.093 0.1220.885 0.147 835.01.800.986 0.007 9.64 0.16 180.0 8/21/2024 14:44 0.5815.78818.965 9.096 67.897101.839 0.000 3.959 2.9290.0010.000 1.039 0.1040.881 0.154 835.01.710.916 0.002 6.37 0.15 180.0 8/21/2024 14:45 1.4587.65119.036 9.094 65.68731.170 0.000 3.839 2.6250.0000.000 0.990 0.1230.743 0.158 835.01.891.181 0.002 9.11 0.41 180.0 8/21/2024 14:46 0.9477.21618.990 9.103 41.46463.292 0.000 4.158 1.6610.0000.000 0.987 0.0670.655 0.126 835.01.550.852 0.006 8.16 0.16 180.0 8/21/2024 14:47 0.4646.13518.935 9.067 79.50273.604 0.000 6.051 3.1540.0000.000 1.079 0.1120.600 0.146 835.02.011.330 0.006 6.60 0.15 180.0 8/21/2024 14:48 0.2667.17618.925 9.065 82.77329.705 0.000 3.095 2.3970.0000.000 0.987 0.1540.476 0.204 835.01.911.044 0.007 7.44 0.17 180.0 8/21/2024 14:50 1.0479.32918.970 9.078 56.17833.988 0.188 5.341 2.6100.0130.000 1.138 0.1710.859 0.166 835.02.011.125 0.006 10.38 0.17 180.0 8/21/2024 14:51 0.7437.28318.899 9.065 76.31579.540 0.000 6.373 3.0160.0370.000 1.176 0.0740.667 0.158 835.01.881.059 0.004 8.03 0.15 180.0 8/21/2024 14:52 0.3067.47718.901 9.075 78.64028.488 0.000 3.537 3.6300.0030.000 1.214 0.1000.719 0.170 835.01.951.043 0.004 7.78 0.17 180.0 8/21/2024 14:53 0.0007.26218.891 9.060 100.64336.607 0.000 2.196 2.1260.0040.000 0.939 0.0000.664 0.216 835.01.821.137 0.009 7.26 0.16 180.0 8/21/2024 14:54 0.5537.53418.938 9.056 93.21928.920 0.000 3.232 2.7770.0130.000 1.031 0.2420.535 0.222 835.02.141.156 0.009 8.09 0.18 180.0 8/21/2024 14:55 0.0005.41518.915 9.056 116.72940.385 0.000 5.300 3.4590.0030.000 0.851 0.0000.586 0.208 835.01.701.073 0.011 5.41 0.18 180.0 8/21/2024 14:56 0.4307.34018.894 9.060 95.08832.968 0.000 2.310 3.1060.0000.000 0.870 0.1870.448 0.174 835.02.021.351 0.007 7.77 0.19 180.0 8/21/2024 14:57 0.0007.33818.910 9.079 119.27328.515 0.043 2.347 3.3720.0240.000 1.089 0.0000.605 0.204 835.01.901.153 0.007 7.34 0.18 180.0 8/21/2024 14:58 0.4538.21618.915 9.099 55.74862.452 0.000 4.558 1.6110.0230.000 1.145 0.0000.724 0.152 834.01.600.803 0.004 8.67 0.20 180.0 8/21/2024 14:59 0.0007.00718.856 9.049 103.36846.093 0.000 4.310 2.7350.0000.000 0.893 0.0000.562 0.183 835.01.671.070 0.008 7.01 0.20 180.0 8/21/2024 15:00 0.2095.26918.939 9.049 99.52340.657 0.000 2.743 3.2320.0000.000 0.942 0.1190.725 0.165 835.01.771.048 0.011 5.48 0.19 180.0 8/21/2024 15:01 0.0007.49618.964 9.064 114.01929.927 0.000 9.415 3.5580.0020.000 1.047 0.0000.726 0.239 834.01.901.081 0.010 7.50 0.29 180.0 8/21/2024 15:02 0.6707.18818.981 9.093 80.13253.877 0.000 6.827 3.3980.0020.000 1.049 0.1550.756 0.183 834.02.071.276 0.007 7.86 0.20 180.0 8/21/2024 15:03 0.2165.54718.982 9.078 122.51731.760 0.000 5.747 4.5260.0010.000 1.214 0.1840.749 0.202 834.02.321.387 0.008 5.76 0.16 180.0 8/21/2024 15:04 0.3896.99018.969 9.078 139.38237.624 0.000 9.552 5.4760.0030.000 1.020 0.2900.394 0.248 834.02.331.292 0.007 7.38 0.20 180.0 8/21/2024 15:05 0.6137.41618.911 9.079 87.05433.205 0.000 2.880 2.3770.0290.000 0.842 0.2420.765 0.204 834.02.161.429 0.009 8.03 0.21 180.0 8/21/2024 15:06 0.8917.33718.883 9.077 112.79627.247 0.000 2.427 3.4210.0080.000 1.077 0.1870.703 0.236 834.02.331.428 0.008 8.23 0.18 180.0 8/21/2024 15:07 0.6077.83518.860 9.068 107.18121.736 0.054 3.193 4.0890.0170.000 0.993 0.2930.702 0.215 834.02.371.480 0.008 8.44 0.19 180.0 8/21/2024 15:08 0.0006.31518.812 9.066 122.84264.051 0.000 5.541 3.3230.0040.000 1.118 0.0000.556 0.236 834.02.031.222 0.006 6.32 0.19 180.0 0.5307.02818.932 9.071 85.41146.436 0.013 4.869 2.9620.0070.000 1.034 0.1110.678 0.180 834.701.8981.109 0.007 7.559 0.186 180.0Avg. Spike 2 8/21/2024 15:11 0.41422.74217.381 8.680 85.18360.808 0.028 5.345 2.6590.0940.000 2.693 17.6450.652 0.242 834.020.881.438 0.712 23.16 0.18 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/21/2024 15:14 0.0677.72918.872 9.085 82.58724.632 0.000 3.678 2.4980.0080.000 0.842 0.2590.506 0.215 834.02.211.439 0.012 7.80 0.22 180.0 8/21/2024 15:15 0.3216.85318.853 9.102 138.56039.483 0.000 4.563 5.2320.0170.000 0.939 0.2860.633 0.267 834.02.461.523 0.010 7.17 0.16 180.0 8/21/2024 15:16 0.0007.13618.905 9.100 176.97830.578 0.000 9.413 2.9540.0340.697 1.057 0.0000.625 0.446 834.02.942.016 0.007 7.14 0.21 180.0 8/21/2024 15:17 0.2615.69818.881 9.100 143.08122.677 0.000 7.381 5.5050.0240.000 1.077 0.3080.415 0.248 834.02.581.590 0.007 5.96 0.23 180.0 8/21/2024 15:18 0.0007.48718.845 9.072 175.05235.256 0.000 10.763 3.1880.0160.345 0.781 0.0910.627 0.475 834.02.871.967 0.012 7.49 0.22 180.0 8/21/2024 15:20 0.0007.87318.856 9.062 172.94628.413 0.103 9.385 2.9290.0270.927 1.110 0.0000.556 0.465 834.02.931.882 0.006 7.87 0.23 180.0 8/21/2024 15:21 0.2477.13518.878 9.089 106.05846.036 0.000 4.620 3.5900.0690.000 1.030 0.2670.470 0.255 834.02.341.310 0.008 7.38 0.23 180.0 8/21/2024 15:22 0.0007.63518.889 9.076 178.19842.428 0.048 12.754 3.2230.0670.959 1.207 0.0000.647 0.449 834.03.031.983 0.008 7.63 0.19 180.0 8/21/2024 15:23 0.2858.13618.860 9.073 125.75223.821 0.000 4.657 5.0080.0430.000 0.965 0.2980.714 0.262 834.02.441.466 0.008 8.42 0.25 180.0 8/21/2024 15:24 0.7856.16118.858 9.076 149.56954.590 0.033 12.174 6.2030.0590.103 1.216 0.2040.718 0.236 834.02.511.531 0.008 6.95 0.23 180.0 8/21/2024 15:25 0.0007.56818.845 9.096 171.28527.743 0.000 4.252 2.2030.0530.694 0.984 0.0000.579 0.444 834.02.882.007 0.013 7.57 0.22 180.0 8/21/2024 15:26 1.1865.60818.833 9.078 140.87244.158 0.000 6.969 5.5970.0160.074 0.955 0.2400.858 0.235 834.02.321.463 0.008 6.79 0.22 180.0 8/21/2024 15:27 0.0007.40118.844 9.070 193.34045.501 0.000 23.793 4.5170.0551.001 1.069 0.0000.691 0.423 834.02.932.055 0.008 7.40 0.21 180.0 8/21/2024 15:28 0.0007.98118.829 9.077 139.33027.717 0.000 11.888 4.5440.0080.000 0.817 0.0000.826 0.266 834.01.921.266 0.010 7.98 0.25 180.0 8/21/2024 15:29 0.0007.42118.839 9.074 179.93831.410 0.000 9.618 3.0780.0310.991 1.146 0.0000.575 0.449 834.03.082.123 0.001 7.42 0.20 180.0 8/21/2024 15:30 0.0007.95318.845 9.050 176.37238.021 0.237 24.952 4.0500.0140.640 1.042 0.0000.636 0.453 834.02.901.954 0.011 7.95 0.26 180.0 8/21/2024 15:31 0.0007.26918.848 9.096 170.55835.315 0.000 7.672 2.5260.0420.814 0.988 0.0000.504 0.410 834.02.902.139 0.004 7.27 0.23 180.0 8/21/2024 15:32 0.0006.34818.866 9.096 200.54621.439 0.000 11.218 4.4130.0671.354 1.101 0.0000.653 0.455 834.03.002.035 0.003 6.35 0.11 180.0 8/21/2024 15:33 0.0007.42518.805 9.069 205.67461.626 0.259 40.990 6.4410.0010.655 0.946 0.2040.638 0.497 834.03.212.073 0.012 7.42 0.26 180.0 8/21/2024 15:34 1.1095.77418.793 9.073 152.65643.295 0.051 10.975 6.5010.0850.000 0.994 0.2090.738 0.292 834.02.491.548 0.008 6.88 0.29 180.0 8/21/2024 15:35 0.0007.18618.820 9.094 180.49236.221 0.000 7.538 3.2620.0080.917 1.034 0.0000.629 0.401 834.02.832.007 0.006 7.19 0.22 180.0 8/21/2024 15:36 0.0007.12218.832 9.076 215.78924.341 0.071 10.059 5.6530.0771.621 1.321 0.0000.656 0.474 834.03.202.061 0.006 7.12 0.23 180.0 8/21/2024 15:37 0.0006.73118.831 9.073 234.19643.132 0.018 26.728 7.6240.0591.230 1.129 0.0000.601 0.498 834.03.102.019 0.008 6.73 0.26 180.0 8/21/2024 15:38 0.0006.25218.742 9.036 232.67847.576 0.282 27.691 7.8590.0131.539 1.336 0.0000.591 0.525 834.03.221.925 0.009 6.25 0.28 180.0 8/21/2024 15:39 0.0008.25118.747 9.069 206.25434.715 0.281 18.040 5.4460.0590.880 1.236 0.0240.733 0.470 834.03.031.861 0.005 8.25 0.28 180.0 8/21/2024 15:40 0.7038.84918.738 9.073 127.06524.494 0.033 10.625 5.3530.0530.000 0.967 0.2310.682 0.223 834.02.361.564 0.009 9.55 0.27 180.0 8/21/2024 15:41 0.0006.87918.775 9.062 186.55367.675 0.000 20.980 3.3940.0970.562 1.051 0.0000.632 0.443 834.02.932.007 0.012 6.88 0.19 180.0 8/21/2024 15:42 1.1767.86118.733 9.065 155.83029.387 0.009 9.637 6.9600.0490.487 0.845 0.1520.702 0.262 834.02.381.706 0.012 9.04 0.24 180.0 8/21/2024 15:43 0.0007.47518.739 9.051 176.76047.907 0.000 23.419 3.5350.0040.434 0.861 0.0840.618 0.472 834.02.942.000 0.014 7.47 0.22 180.0 8/21/2024 15:44 0.0005.41418.755 9.054 203.60341.590 0.000 18.994 4.7870.0370.401 1.103 0.0000.684 0.466 834.03.052.076 0.009 5.41 0.23 180.0 0.2057.15418.825 9.076 169.95237.373 0.048 13.514 4.6020.0400.578 1.038 0.0950.638 0.383 834.002.7661.820 0.008 7.358 0.228 180.0Avg. 0.3687.09118.879 9.074 127.68141.904 0.030 9.191 3.7820.0230.289 1.036 0.1030.658 0.281 834.352.3321.465 0.008 7.458 0.207 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/21/2024 15:46 0.0000.0000.153 0.000 1.3030.736 0.239 0.760 0.1990.0460.498 0.366 0.0250.000 0.003 834.00.420.217 0.012 0.00 0.20 180.0 Run 3 - A 30minute/60min 8/21/2024 15:49 0.3377.32318.732 9.047 120.47364.387 0.000 13.591 4.3170.0590.000 1.035 0.1870.623 0.244 834.02.371.508 0.008 7.66 0.20 180.0 8/21/2024 15:50 1.0446.80718.748 9.037 131.48944.093 0.235 14.128 6.0020.0560.055 1.180 0.1980.753 0.285 834.02.671.679 0.010 7.85 0.19 180.0 8/21/2024 15:51 0.9066.68118.798 9.067 132.01350.196 0.000 6.809 4.4360.0170.000 1.050 0.2360.721 0.251 834.02.491.582 0.008 7.59 0.20 180.0 8/21/2024 15:52 0.0007.51218.813 9.063 145.25524.564 0.000 9.116 4.7100.0960.000 1.065 0.0000.710 0.266 834.02.091.280 0.006 7.51 0.21 180.0 8/21/2024 15:54 0.0006.43518.782 9.064 198.65555.736 0.121 29.511 5.1060.0150.787 1.107 0.0000.511 0.487 834.03.112.093 0.007 6.43 0.24 180.0 8/21/2024 15:55 0.0327.48618.820 9.083 123.63524.652 0.000 6.240 4.3830.0490.000 0.892 0.2450.538 0.245 834.02.411.623 0.009 7.52 0.13 180.0 8/21/2024 15:56 0.0007.44218.882 9.093 191.54530.498 0.000 11.065 3.9110.0390.449 1.102 0.0000.595 0.460 834.03.022.051 0.007 7.44 0.19 180.0 8/21/2024 15:57 0.0007.98718.887 9.083 199.86629.838 0.000 14.416 4.7500.0430.984 1.184 0.0000.537 0.489 834.03.322.335 0.005 7.99 0.24 180.0 8/21/2024 15:58 0.0007.54518.861 9.080 203.46624.788 0.000 13.369 4.9550.0821.418 1.160 0.0000.580 0.455 834.03.001.982 0.005 7.54 0.25 180.0 8/21/2024 15:59 0.0007.70918.823 9.023 237.27880.460 0.258 54.893 8.8590.0001.200 1.077 0.1560.504 0.477 833.03.352.276 0.011 7.71 0.25 180.0 8/21/2024 16:00 0.0007.73718.828 9.052 199.06150.211 0.200 29.207 4.8180.0790.485 1.205 0.0000.574 0.481 834.03.091.985 0.012 7.74 0.28 180.0 8/21/2024 16:01 0.0006.51818.746 9.064 183.25622.194 0.024 10.816 3.5500.0491.104 1.212 0.0000.554 0.481 834.03.122.026 0.003 6.52 0.27 180.0 8/21/2024 16:02 0.0005.39418.797 9.068 191.80549.932 0.000 22.646 4.3420.0760.792 1.154 0.0000.627 0.455 834.02.971.935 0.008 5.39 0.23 180.0 8/21/2024 16:03 0.0007.72518.793 9.088 188.93925.832 0.000 10.646 3.7740.0130.770 1.235 0.0000.483 0.477 834.03.282.251 0.004 7.73 0.24 180.0 8/21/2024 16:04 0.0007.38718.798 9.050 203.90445.552 0.065 24.808 5.1580.0561.174 1.247 0.0000.617 0.482 834.03.111.968 0.008 7.39 0.23 180.0 8/21/2024 16:05 0.0007.57018.768 9.050 212.61636.132 0.053 16.829 5.7360.0321.186 1.171 0.0700.600 0.488 834.02.991.738 0.009 7.57 0.26 180.0 8/21/2024 16:06 0.0007.48918.767 8.997 241.049102.826 0.411 66.915 9.4860.0010.432 1.291 0.1220.560 0.506 834.03.472.206 0.015 7.49 0.26 180.0 8/21/2024 16:07 0.0008.12118.955 9.041 197.26338.133 0.154 22.654 4.7260.0480.978 1.127 0.0000.505 0.469 834.03.192.254 0.010 8.12 0.27 180.0 8/21/2024 16:08 0.6166.06119.056 9.032 153.15741.996 0.000 15.347 7.0740.0700.000 0.989 0.2390.510 0.254 834.02.431.530 0.010 6.68 0.24 180.0 8/21/2024 16:09 1.0578.19719.054 9.034 143.10837.819 0.033 12.036 5.7910.0340.009 1.047 0.2380.525 0.264 834.02.501.558 0.008 9.25 0.10 180.0 8/21/2024 16:10 0.6525.27119.076 9.055 135.36438.865 0.000 8.004 5.2630.0450.127 1.181 0.2070.774 0.221 834.02.441.500 0.008 5.92 0.10 180.0 8/21/2024 16:11 0.6218.11019.040 9.027 135.03332.738 0.000 9.284 5.0930.0060.012 0.975 0.1790.728 0.215 834.02.391.691 0.012 8.73 0.20 180.0 8/21/2024 16:12 0.5727.09319.092 9.028 149.04727.471 0.000 9.063 6.0830.0680.000 0.937 0.2280.643 0.258 834.02.421.576 0.010 7.66 0.23 180.0 8/21/2024 16:13 0.0005.76019.020 9.013 211.56352.108 0.000 25.629 5.5470.0431.173 1.289 0.0000.556 0.447 834.03.112.033 0.009 5.76 0.22 180.0 8/21/2024 16:14 0.0005.48419.074 9.016 225.83558.786 0.030 32.603 7.1880.0161.036 1.246 0.0130.571 0.460 834.03.071.966 0.010 5.48 0.25 180.0 8/21/2024 16:15 0.0008.11119.060 9.039 199.96932.736 0.036 18.276 4.8280.0440.911 1.057 0.0000.567 0.467 834.02.931.940 0.011 8.11 0.27 180.0 8/21/2024 16:16 0.0007.84919.120 9.046 200.42332.480 0.044 17.034 5.2310.0521.035 0.945 0.2030.630 0.491 834.03.242.141 0.012 7.85 0.25 180.0 8/21/2024 16:17 0.0007.97019.087 9.020 225.84683.063 0.161 51.062 7.7730.0020.666 0.960 0.5290.423 0.351 834.03.312.157 0.013 7.97 0.25 180.0 8/21/2024 16:18 0.0008.28419.142 9.041 198.66236.389 0.085 21.653 4.8770.0120.961 1.148 0.0000.641 0.462 834.02.991.948 0.011 8.28 0.27 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 16:19 0.0007.74019.040 9.023 199.63741.524 0.043 23.336 4.7200.0191.002 1.105 0.0000.591 0.447 834.02.961.988 0.012 7.74 0.25 180.0 0.1957.22718.915 9.047 182.64043.867 0.065 20.700 5.4160.0410.625 1.112 0.1020.592 0.395 833.972.8951.893 0.009 7.421 0.226 180.0Avg. Spike 3 8/21/2024 16:22 0.46527.56317.549 8.677 153.89269.708 0.074 10.865 6.5070.0880.328 2.991 19.4640.717 0.274 834.023.231.840 0.780 28.03 0.25 180.0 Run 3 - B 30minute/60min 8/21/2024 16:24 0.0008.72719.015 9.024 175.45129.867 0.142 16.092 3.4220.0190.635 1.327 0.0270.565 0.470 834.03.041.784 0.013 8.73 0.25 180.0 8/21/2024 16:25 0.0007.28319.045 9.029 206.46439.513 0.000 19.649 4.9950.0290.968 1.061 0.0000.501 0.470 834.03.102.179 0.009 7.28 0.24 180.0 8/21/2024 16:26 0.0008.12019.044 9.035 182.03130.845 0.000 12.219 3.5550.0481.126 1.149 0.0000.591 0.462 834.03.021.990 0.009 8.12 0.25 180.0 8/21/2024 16:27 0.0007.40919.087 9.054 203.32132.763 0.000 16.198 4.8990.0370.956 1.024 0.0000.499 0.455 834.02.972.066 0.011 7.41 0.24 180.0 8/21/2024 16:29 0.0008.29119.049 9.045 221.65435.728 0.083 19.054 6.8020.0041.598 1.081 0.0000.568 0.485 834.02.991.953 0.008 8.29 0.25 180.0 8/21/2024 16:30 0.0007.21919.055 9.023 240.20877.875 0.196 49.465 8.9410.0000.619 1.213 0.1590.561 0.490 834.03.271.979 0.011 7.22 0.27 180.0 8/21/2024 16:31 0.0007.65319.078 9.035 205.27034.180 0.104 17.088 5.0670.0171.411 1.347 0.0000.499 0.410 834.03.082.050 0.007 7.65 0.28 180.0 8/21/2024 16:32 0.0007.10719.024 9.013 229.96856.379 0.002 26.707 7.3710.0191.205 1.306 0.1980.395 0.415 834.03.322.137 0.007 7.11 0.25 180.0 8/21/2024 16:33 0.0008.28819.012 9.019 184.42637.711 0.213 26.499 4.4600.0170.551 1.459 0.0000.509 0.423 834.02.961.705 0.008 8.29 0.28 180.0 8/21/2024 16:34 0.0007.26819.000 9.022 216.00262.574 0.000 26.011 5.6720.0171.257 1.131 0.0000.466 0.436 834.03.112.232 0.008 7.27 0.24 180.0 8/21/2024 16:35 0.0007.68119.004 9.026 190.92749.921 0.006 22.439 4.0500.0340.755 1.019 0.0000.520 0.420 834.02.862.005 0.008 7.68 0.26 180.0 8/21/2024 16:36 0.8377.97019.001 9.043 154.63727.681 0.000 9.062 6.5410.0260.357 1.135 0.1990.640 0.239 834.02.381.419 0.010 8.81 0.25 180.0 8/21/2024 16:37 0.0005.75619.001 9.030 221.00054.539 0.000 22.551 6.5060.0010.876 1.222 0.0480.424 0.419 834.03.072.051 0.009 5.76 0.21 180.0 8/21/2024 16:38 0.0007.90419.033 9.036 218.21830.880 0.013 15.407 6.3650.0621.727 1.286 0.0000.623 0.434 834.03.122.089 0.008 7.90 0.26 180.0 8/21/2024 16:39 0.0006.15219.066 9.038 209.27042.277 0.009 20.469 5.4990.0231.189 1.215 0.0000.491 0.444 834.03.021.986 0.007 6.15 0.27 180.0 8/21/2024 16:40 0.0008.34719.057 9.044 218.44921.860 0.000 10.285 5.9670.0661.561 1.289 0.0000.530 0.494 834.03.252.109 0.005 8.35 0.26 180.0 8/21/2024 16:41 0.0007.62719.069 9.013 241.22368.715 0.000 35.099 8.5410.0221.267 1.277 0.1240.504 0.438 834.03.282.141 0.010 7.63 0.27 180.0 8/21/2024 16:42 0.0007.85019.075 9.017 235.26752.364 0.052 28.413 7.8780.0211.529 1.346 0.0800.583 0.437 834.03.061.807 0.009 7.85 0.27 180.0 8/21/2024 16:43 0.0008.39619.089 9.030 215.85933.576 0.126 16.944 5.8440.0471.191 1.139 0.0000.472 0.430 834.02.952.004 0.006 8.40 0.27 180.0 8/21/2024 16:44 0.0007.62519.073 9.038 201.31332.682 0.000 12.972 4.6780.0141.100 1.166 0.0000.553 0.443 834.02.921.888 0.006 7.62 0.25 180.0 8/21/2024 16:45 0.0008.03919.044 9.022 211.45346.805 0.000 21.337 5.4250.0581.191 1.267 0.0000.582 0.456 834.03.001.861 0.010 8.04 0.24 180.0 8/21/2024 16:46 0.0007.73419.050 9.022 214.01432.014 0.000 16.167 5.7220.0261.395 1.040 0.0010.479 0.466 834.03.002.065 0.010 7.73 0.25 180.0 8/21/2024 16:47 0.0007.92519.058 9.016 213.58835.137 0.000 16.539 5.5880.0261.462 1.027 0.0000.547 0.475 834.02.881.870 0.011 7.93 0.25 180.0 8/21/2024 16:48 0.0007.36319.084 9.026 214.30437.508 0.000 17.794 5.4730.0421.793 1.171 0.0000.482 0.483 834.03.031.918 0.007 7.36 0.25 180.0 8/21/2024 16:49 0.0008.12719.043 9.050 226.88735.911 0.000 22.470 6.9010.0101.535 1.303 0.0000.491 0.421 834.03.072.034 0.007 8.13 0.25 180.0 8/21/2024 16:50 0.0007.81719.047 9.029 241.77769.499 0.186 39.028 8.9440.0001.421 1.130 0.0910.381 0.417 834.02.891.814 0.009 7.82 0.27 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 16:51 0.0008.14618.998 9.046 218.40130.402 0.106 15.831 6.1770.0041.698 1.361 0.0530.567 0.481 834.03.181.893 0.003 8.15 0.28 180.0 8/21/2024 16:52 0.0007.46219.010 9.029 232.28754.548 0.075 31.183 7.5160.0031.271 1.357 0.0000.478 0.486 834.03.141.898 0.008 7.46 0.27 180.0 8/21/2024 16:53 0.0007.02719.001 9.021 226.37760.451 0.319 35.532 7.4460.0151.132 1.186 0.0710.478 0.488 834.03.101.898 0.007 7.03 0.28 180.0 8/21/2024 16:54 0.0006.11519.055 9.042 186.93738.418 0.000 17.918 3.4470.0120.804 1.104 0.0000.549 0.440 834.02.881.892 0.009 6.12 0.27 180.0 0.0287.61419.042 9.031 211.89943.087 0.054 21.881 5.9900.0241.186 1.205 0.0350.518 0.444 834.003.0311.957 0.008 7.643 0.258 180.0Avg. 0.1117.42018.979 9.039 197.27043.477 0.060 21.290 5.7030.0320.905 1.159 0.0680.555 0.419 833.982.9631.925 0.009 7.532 0.242 180.0Run 3 Avg: Baseline 3 8/21/2024 16:56 0.0000.0000.135 0.000 1.2790.391 0.193 0.623 0.3410.0200.000 0.208 0.0050.000 0.000 834.00.380.362 0.012 0.00 0.19 180.0 Post CTS 8/21/2024 16:58 0.0000.0000.149 0.000 0.0000.144 0.085 0.935 0.0000.1770.000 102.228 0.0000.000 0.101 833.068.610.376 0.016 0.00 0.21 180.0 8/21/2024 16:58 0.0000.0000.154 0.000 0.0000.353 0.087 0.887 0.0340.0061.221 103.937 0.2540.000 0.028 833.069.930.481 0.022 0.00 0.21 180.0 8/21/2024 16:58 0.0000.0000.162 0.000 0.0000.383 0.096 0.535 0.0630.1360.224 105.298 0.0000.000 0.051 833.070.360.077 0.010 0.00 0.20 180.0 Post NO2/Mid O2 8/21/2024 17:02 96.1332.4470.092 0.000 0.8300.136 0.397 0.315 0.0000.0340.000 0.000 0.0000.000 0.097 833.00.420.341 0.011 98.58 10.78 180.0 8/21/2024 17:02 96.1312.7640.098 0.000 0.9760.115 0.406 0.363 0.2900.0000.000 0.133 0.0000.000 0.010 833.00.140.042 0.009 98.89 10.77 180.0 8/21/2024 17:02 96.5871.9690.092 0.000 0.8180.187 0.391 0.549 0.3150.0000.000 0.000 0.0000.504 0.000 833.00.000.000 0.019 98.56 10.83 180.0 8/21/2024 17:02 97.1382.2820.093 0.000 1.4280.051 0.382 0.815 0.0000.0220.000 0.290 0.0000.364 0.080 833.00.550.300 0.010 99.42 10.78 180.0 Post 5-Gas 8/21/2024 17:03 0.000234.6650.092 4.518 2.147494.414 1.249 2.174 5.2040.2541.761 1.694 251.2000.175 0.000 834.0254.433.157 9.886 234.67 0.14 180.0 8/21/2024 17:04 0.000234.8340.075 4.528 2.409494.591 1.293 1.712 5.4660.2812.701 1.673 252.5360.000 0.000 834.0255.502.774 9.918 234.83 0.14 180.0 8/21/2024 17:04 0.000235.9700.058 4.532 1.732498.139 1.251 1.939 5.1060.0530.951 1.585 253.6780.626 0.000 833.0257.013.417 9.959 235.97 0.14 180.0 8/21/2024 17:04 0.000236.9980.061 4.527 2.483495.781 1.199 1.886 6.3230.2122.433 1.510 253.5070.056 0.000 833.0256.983.697 9.977 237.00 0.13 180.0 8/21/2024 17:04 0.000236.9100.054 4.573 1.711498.850 1.184 1.914 5.6140.1830.000 1.413 253.3790.000 0.000 833.0256.513.279 10.035 236.91 0.14 180.0 8/21/2024 17:04 0.000236.3050.053 4.545 1.709498.695 1.221 2.218 5.3020.2720.000 1.612 254.0260.000 0.000 834.0257.503.592 9.981 236.30 0.13 180.0 8/21/2024 17:04 0.000235.5320.061 4.541 2.476496.993 1.251 1.594 5.4350.0011.222 1.425 254.0000.000 0.000 833.0257.073.183 9.992 235.53 0.13 180.0 8/21/2024 17:04 0.000236.4710.063 4.576 2.272498.860 1.344 1.681 5.1010.0700.145 1.458 253.9810.405 0.000 833.0256.842.824 10.014 236.47 0.14 180.0 End of Test Purge 8/21/2024 17:06 0.0002.3580.051 0.000 0.2212.097 0.138 0.088 0.0960.0370.000 0.000 0.9840.355 0.000 833.01.460.716 0.051 2.36 0.14 180.0 8/21/2024 17:06 0.0001.7180.056 0.000 0.5881.572 0.103 0.711 0.5880.0000.000 0.054 0.6940.018 0.000 833.00.900.263 0.039 1.72 0.14 180.0 8/21/2024 17:06 0.0000.2210.066 0.000 0.5351.170 0.060 0.304 0.0000.0020.000 0.000 0.7410.000 0.000 833.01.040.451 0.023 0.22 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 17:06 0.0001.2650.060 0.000 0.0000.973 0.131 0.549 0.0000.0580.000 0.000 0.6240.000 0.000 833.00.630.015 0.038 1.26 0.14 180.0 8/21/2024 17:06 0.0000.0000.057 0.000 0.3570.645 0.049 0.332 0.1420.0000.109 0.545 0.6840.048 0.000 833.01.390.514 0.022 0.00 0.13 180.0 8/21/2024 17:07 0.0000.8760.043 0.000 0.2830.688 0.035 0.132 0.6540.1470.000 0.000 0.3780.000 0.000 833.00.630.371 0.027 0.88 0.13 180.0 8/21/2024 17:07 0.0000.7320.064 0.000 0.0000.562 0.042 0.373 0.6120.0020.000 0.000 0.3580.000 0.000 833.00.600.357 0.023 0.73 0.14 180.0 8/21/2024 17:07 0.0000.5510.054 0.000 0.0000.501 0.068 0.149 0.0000.0120.288 0.816 0.4220.225 0.006 833.01.400.636 0.022 0.55 0.14 180.0 GAS, Inc. Performance Test Report Test Type: Initial Test Date: 8/20/2024 Caterpillar G3516H Lean Burn (4 Cycle) DOM: 2/9/23 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:09:14 AM 12:52 PM Source: Unit Number: SW700322 Serial Number: H6C00285 Engine Hours:4194.5 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Boston SWD 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 10.481 79.969 12.848 2.000 0.180 1.000 0.500 0.700 0.300 0.036 0.449 0.069 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results ppmvd Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Wheeler CAT 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Ethan Kinsey 3 Cooper Green Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit SW700322 with a serial number of H6C00285 which is a Caterpillar G3516H engine located at Boston SWD and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/20/2024 by Cooper Green with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 2763 brake horse power (BHP) at 1800 RPM. The engine was operating at 1934 BHP and 1799 RPM which is 70.00% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. 4 4.0 Test Summary Engine/Compressor Specs Boston SWDLocation SW700322Unit ID Make Caterpillar Site Elevation ft.5486 Model G3516H Atmospheric Pressure psi.12.06 Serial Number H6C00285 Stack Diameter in.18 mfg. rated hp 2763 Yes 1800 Date of Manufacture 2/9/2023 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1934 1934 1934 1934 1799 1800 1799 1799 Percent Load % Intake Manifold Pressure (hg) 70.00%70.00%70.00%70.00% 68.70 70.12 69.71 69.51 Intake Manifold Temperature (F)126.00 126.00 123.00 125.00 Ambient Conditions Ambient Temperature Dry (F)69.00 72.00 77.00 72.67 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 200108.82 199687.23 201983.68 200593.24 5666.40 5654.46 5719.49 5680.11 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.12 0.12 0.12 0.12 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %12.04%12.11%12.10%12.08% T e s t S u m m a r y mfg. rated rpm Test RPM 9.59%9.50%9.52%9.54% Permitted Standards Results 5 Catalyst 0.0380.036 Run 1 Run 2 Run 3 3 Run Average Pass Permits 09:14 AM 10:25 AM 11:35 AM 8/20/2024 CO (g/hp-hr)0.034 0.0362.000 0.180 Pass StateFederal CO (ppmvw)8.723 9.175 9.747 9.215 CO (ppmvd)9.917 10.438 11.088 10.481 CO (mol wt) 28.01 CO (ppmvd) @15% O2 5.175 5.403 5.748 5.442 Fail CO (ppbvd) @15% O2 5174.717 5403.227 5748.352 5442.099 Fail NOx (g/hp-hr)0.454 0.445 0.449 0.4491.000 0.500 Pass NOx (ppmvw)71.210 69.931 69.777 70.306 NOx (ppmvd)80.959 79.564 79.385 79.969 NOx (mol wt) 46.01 11.062 11.250 11.574 11.295NMNEHC (ppmvw) 12.576 12.800 13.168 12.848NMNEHC (ppmvd) NOx (ppbvd) @15% O2 42243.678 41185.136 41153.517 41527.444 Fail NOx (ppmvd) @15% O2 42.244 41.185 41.154 41.527 Fail NMNEHC (mol wt) 44.10 6561.978 6625.571 6826.186 6671.245 FailNMNEHC (ppbvd) @15% O2 0.068 0.069 0.071 0.0690.700 0.300 PassNMNEHC (g/hp-hr) 6.562 6.626 6.826 6.671 FailNMNEHC (ppmvd) @15% O2 Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.43Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 8.72 0.45 65.09 0.00 6.12 0.45 71.21 0.43 11.06 0.13% 8.47% 0.00% 12.04% NMNEHC 8.72 65.66 6.20 71.86 11.08 8.48%12.05% 47.42 74.55 8.78 83.33 32.00 8.33%11.19% 8.73 64.51 6.05 70.56 11.04 8.47%12.04% 0.00 0.00 0.00 0.00 0.41 0.43%0.12% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.41 0.43%0.12% 8.95 63.90 5.92 69.81 11.08 8.34%12.08% 48.67 77.81 5.41 83.22 31.75 8.33%11.21% 9.40 64.05 6.00 70.05 11.42 8.43%12.14% 0.18 0.00 0.00 0.00 0.46 0.40%0.10% Avg. Wet 9.17 63.97 5.96 69.93 11.25 8.39%12.11% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 9.50 63.56 5.86 69.41 11.39 8.35%12.14% 47.17 74.91 6.29 81.20 30.93 8.34%11.26% 10.00 64.13 6.02 70.14 11.76 8.45%12.07% 0.11 0.00 0.00 0.00 0.58 0.24%0.07% 0.18 0.00 0.00 0.00 0.46 0.40%0.10% Avg. Wet 9.75 63.85 5.94 69.78 11.57 8.40%12.10% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 18 inches or:1.5 feet. or:1.77 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.81 Yes 18.00 9.00 36.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 12.04 29.21 0.80 Inches 3.01 9 14.99 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.44 8.48 8.72 841.00 0.06 24.84 24.90 786.44 1246.11 419.13 27.86 101.42 179.22 227504.97 200108.82 Run 2 12.11 29.21 0.80 5.46 8.39 9.17 840.37 0.06 24.82 24.88 787.31 1246.98 419.62 27.85 101.43 179.24 227194.84 199687.23 Run 3 12.10 29.21 0.82 5.47 8.41 9.75 840.00 0.06 24.81 24.87 787.31 1246.98 419.62 27.85 102.63 181.36 229794.56 201983.68 12.08 29.21 0.80 5.45 8.43 9.21 840.46 0.06 24.82 24.88 787.02 1246.69 419.46 27.86 101.83 179.94 228168.28 200596.43 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.78 Exhaust Temp F 786.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.76 0.77 0.81 786.00 786.00 787.00 0.85 0.86 0.89 786.00 787.00 787.00 0.87 0.89 0.82 787.00 786.00 786.00 0.81 787.00 0.76 0.71 0.71 787.00 786.00 786.00 0.74 0.76 0.80 787.00 786.00 786.44 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.83 Exhaust Temp F 787.00 0.85 0.80 0.82 787.00 788.00 787.00 0.82 0.77 0.81 787.00 787.00 788.00 0.84 0.79 0.76 788.00 787.00 787.00 0.82 787.00 0.88 0.84 0.83 788.00 787.00 787.00 0.80 0.81 788.00 787.00 787.310.82 Run 2 Δpstd (in) H2O 0.81 Exhaust Temp F 787.00 0.78 0.81 0.76 787.00 787.00 788.00 0.77 0.79 0.76 787.00 787.00 787.00 0.79 0.83 0.85 788.00 788.00 787.00 0.82 787.00 0.83 0.78 0.76 788.00 787.00 787.00 0.79 0.84 788.00 787.00 0.80 787.31 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.054)+.32(.096)+.28(.849+.001) = 29.21 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.21(1 -.12042)+.18.0(.12042) = 27.86 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.8*√(1246.1075/(24.9*27.86)) = 101.42 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.12)101.42*1.767((528*24.9)/ (1246.1075*29.92)) = 200108.82 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 200108.824/35.315 = 5666.397 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 9.917*(20.9-15)/(20.9-9.6%)) = 5.178 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (9.917*(1.164*10^-3)*5666.397*(Run Time/60))/1934.1 = .034 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .034*1/453.6*1934.1 = .144 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .144*4.38 = .631 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 9.92 = 8.723*(1/(1-.12))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.76% 20.75% 10.66% 10.96% 10.76% 10.76% 10.96%10.66% 10.76% 20.75% 10.76% 20.98% 10.76% 20.98% 10.76%20.98% 0.00% 10.76% 20.98% 0.00% 0.23% 0.01% 1.08% 10.76% Span Zero Offset 0.00% 20.98 0.00% 10.76%0.49%0.95%0.02% 9.64% 9.55% 9.56% 9.59% 9.50% 9.52% 9 Gas, Inc. 0.0 0.0 0.0 0.0 0.0 0.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Boston SWD 8/20/2024 5486 SW700322 Caterpillar Model Serial Number G3516H H6C00285 Technician Cooper Green Run Start Times 09:14 AM 10:25 AM 11:35 AM 12:52 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1799.0 1800.0 1799.0 1799.3 Engine Hours 4191.5 4192.5 4193.5 4194.5 Intake Manifold Pressure (psi)45.8 46.5 46.3 46.2 Intake Manifold Temp °F 126.0 126.0 123.0 125.0 Engine Load (BHP)1934.1 1934.1 1934.1 1934.1 Ambient Temp °F 69.0 72.0 77.0 72.7 Humidity %49.0 46.0 40.0 45.0 Dew Point °F 50.0 50.0 51.0 50.3 Caterpillar Yes 1 1 1 1# of Catalyst Installed Catalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 0.0 0.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.03 R e s u l t s Average:Nitrogen monoxide NO 0.10 Average:Nitrogen dioxide NO2 0.11 Average:NOx 0.21 Average:VOC 0.16 Average:Oxygen 0.13 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.00 Tolerance 2.00% Difference between measured and expected 1.00% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.22 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.73 Average:Oxygen 0.13 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 97.40 Tolerance 5.00% Difference between measured and expected 2.60% Pre-test System CTS & Mechanical Response Time 45 secondsEquilibration Response Time Value:Spike Reported 259.36 Value:Spike Expected 258.20 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC511346 4/24/2027 98.96 10.76% CC706226 4/24/2032 100.00 CC185396 6/17/2032 20.98% Cylinder # CC102850 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 258.20 502.80 243.30 10.14 Analyzer System Response 259.36 502.80 250.57 10.00 Percent Difference 0.45%0.00%2.99%1.35% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 98.996 4.950 Spike Direct Propane 259.754 Mechanical Response Time SF6 10.044 CO 503.508 NO 245.633 Ethylene 97.397 18 seconds Analyzer Response Propane 259.358 SF6 10.003 CO 502.796 NO 250.565 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 257.927 CO 500.192 NO 253.949 12 seconds 26 seconds 7.61% 7.39% 7.12% 100.47% 101.31% 100.21% 9.970 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%3.006 50%9.000 83.3%14.994 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 18 9 36 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 200596.43 H2O%d @ Sampling Point:12.08 CO2%d @ Sampling Point:5.45 Pressure @ Sampling Point (Pg "H2O):0.8 Temperature @ Sampling Point (Deg F):787.02 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99 4.95 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 98.996 4.950 Spike Direct Propane 259.754 Mechanical Response Time SF6 10.044 CO 503.508 NO 245.633 Ethylene 97.397 18 seconds Analyzer Response Propane 259.358 SF6 10.003 CO 502.796 NO 250.565 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 257.927 CO 500.192 NO 253.949 12 seconds 26 seconds 7.61% 7.39% 7.12% 100.47% 101.31% 100.21% 9.970 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 258.200 10.140 502.800 243.300 259.754 10.044 503.508 245.633 0.60% 0.95% 0.14% 0.96% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 5.453 0.000 Spike Average 24.802 0.764 Dilution Factor 7.607% Expected 24.687 % Recovery 100.470% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.742 Dilution Factor 7.387% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.715 Dilution Factor 7.119% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 5.598 23.632 23.583 100.210% 0.001267 0.000957 0.000954 5.498 24.488 24.172 101.310% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass1.59% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:15.6075719 Pass Line Position Difference:Resolution Difference to Reference 1.59% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 101.14 1.13% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Boston SWD; SW700322; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/20/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/20/2024 Cooper Green Gas, Inc. Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. 21% O2 Tri Probe Certification Great Plains Analytical Services 303 W 3rd St Elk City, OK, 73644 (580)225-0403 Fax: (580)225-2612 CERTIFICATE OF ANALYSIS Grade of Product: CERTIFIED STANDARD-PROBE Part Number: 18L Reference Number: 3 Laboratory: GAS INC. Stack Diameter: 18” Analysis Date: Dec. 3, 2021 Target Flow Rate: 3L/min LOT Number: SN: A 3A 18L Number of Points: 3 Product performance verified by direct comparison to calibration standards traceable to N.I.S.T. *The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e, section 8.4 as shown in the accompanying data. Method 7e, section 8.4 states that the multipoint traverse requirement can be satisfied by sampling via “a multi-hole probe designed to sample at the prescribed points with a flow +/- 10 percent of mean flow rate”. ANALYTICAL RESULTS !"#$%$&'()*$+*',$ -./01 $ 23)4"536$+*',$ 7'5($8 $-./01$ -93*()$:;1$ 23)4"536$+*',$ 7'5($<$-./01$ -93*()$:=1$ 23)4"536$+*',$ 7'5($>$-./01 $ -93*()$:?1$ Mean Probe Port Sampled Flow (L/m)$ $ Run 1 2 LPM .660 (5.88D) .620 (-0.53D) .590 (-5.35D) .623 Run 2 4 LPM 1.29 (3.20D) 1.26 (0.80D) 1.20 (-4.00D) 1.250 *Calibration conducted in accordance with Emission Measurement Center Guideline Document – EMC GD-031 Notes: ___________________________________________________ _________________________ Approved for Release Date 12-3-21 Probe size: 18 L Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Cooper Green GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Boston SWD Unit Number:SW700322 Make:Caterpillar Location:G3516HModel: H6C00285Serial Number: RAW Result Data Stability 8/20/2024 05:27 1.9560.0001.472 5.544 18.9310.000 0.000 0.000 6.1110.0180.000 0.000 0.0000.072 2.758 837.05.520.000 0.000 1.96 18.13 179.0 Pre Test Baseline Direct 8/20/2024 05:36 0.0000.105-0.016 0.000 0.0000.054 0.000 0.145 0.0000.0000.000 0.028 0.0000.043 0.000 837.00.180.245 0.002 0.10 0.14 181.0 8/20/2024 05:36 0.3420.097-0.016 0.000 0.0000.035 0.000 0.025 0.0000.0000.000 0.000 0.0000.117 0.000 837.00.100.153 0.004 0.44 0.13 181.0 8/20/2024 05:37 0.0000.090-0.014 0.000 0.0000.000 0.008 0.158 0.0000.0000.000 0.215 0.0000.081 0.000 837.00.200.089 0.003 0.09 0.13 181.0 CTS Direct 8/20/2024 05:41 0.0000.287-0.002 0.000 0.0000.415 0.064 0.123 0.0000.0000.000 99.644 0.0000.163 0.000 837.066.480.070 0.000 0.29 0.17 181.0 8/20/2024 05:42 0.0000.022-0.002 0.000 0.0000.558 0.021 0.145 0.0000.0150.000 98.667 0.0000.000 0.000 837.065.870.138 0.007 0.02 0.16 181.0 8/20/2024 05:42 0.0000.181-0.004 0.000 0.0000.622 0.038 0.041 0.0000.0160.000 98.676 0.0000.129 0.000 837.065.870.120 0.009 0.18 0.57 180.0 High O2 Direct 8/20/2024 05:52 0.0000.000-0.019 0.000 0.0000.056 0.004 0.000 0.0000.0000.000 0.127 0.0000.173 0.000 837.00.250.255 0.006 0.00 20.71 180.0 8/20/2024 05:52 0.0000.000-0.023 0.000 0.0000.053 0.000 0.000 0.0000.0000.000 0.000 0.0000.203 0.000 837.00.090.138 0.008 0.00 20.73 180.0 8/20/2024 05:53 0.1750.000-0.018 0.000 0.0000.106 0.000 0.027 0.0000.0000.000 0.247 0.0000.287 0.000 837.00.270.161 0.001 0.18 20.82 180.0 NO2/Mid O2 Direct 8/20/2024 06:02 98.5560.342-0.020 0.000 0.6820.046 0.394 0.000 0.2780.0000.000 0.000 0.0000.155 0.000 837.00.000.000 0.006 98.90 10.77 180.0 8/20/2024 06:02 99.4130.422-0.023 0.000 0.5440.070 0.376 0.000 0.2930.0000.000 0.000 0.0000.208 0.000 837.00.050.068 0.001 99.83 10.77 180.0 8/20/2024 06:03 99.1900.628-0.022 0.000 0.0000.046 0.371 0.000 0.5650.0000.000 0.000 0.0000.091 0.000 837.00.000.000 0.006 99.82 10.75 180.0 Spike Direct 8/20/2024 06:07 3.192245.229-0.020 4.682 5.911503.141 1.345 2.217 7.8370.0701.308 1.467 259.5820.204 0.000 837.0262.212.470 10.029 248.42 0.14 180.0 8/20/2024 06:08 2.839245.408-0.015 4.668 5.106504.111 1.338 1.843 7.4650.2350.603 1.367 259.9410.000 0.000 837.0262.141.930 10.061 248.25 0.14 180.0 8/20/2024 06:08 2.608246.261-0.012 4.689 5.839503.272 1.311 1.702 8.0980.2370.000 1.446 259.7380.147 0.000 837.0262.462.640 10.042 248.87 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/20/2024 06:10 0.0000.0000.024 0.000 0.0000.244 0.003 1.819 0.0000.0090.102 0.465 0.1580.000 0.224 837.00.920.000 0.006 0.00 0.13 180.0 8/20/2024 06:10 0.0000.0000.013 0.000 0.0000.226 0.004 1.784 0.0000.0130.000 0.212 0.3010.362 0.152 837.00.750.000 0.002 0.00 0.13 180.0 8/20/2024 06:11 0.0000.0000.020 0.000 0.0000.180 0.006 1.571 0.0000.0080.000 0.231 0.0320.000 0.154 837.00.520.040 0.005 0.00 0.13 180.0 CTS System with Response Time 8/20/2024 06:13 0.0000.1130.027 0.000 0.0000.050 0.015 1.365 0.0000.0000.000 97.461 0.0000.020 0.136 837.065.290.057 0.006 0.11 0.18 180.0 8/20/2024 06:13 0.0000.1260.023 0.003 0.0000.116 0.000 1.217 0.0000.0030.000 97.323 0.0000.000 0.122 837.065.130.000 0.010 0.13 0.18 180.0 8/20/2024 06:13 0.0000.0000.021 0.000 0.0000.095 0.008 1.279 0.0000.0000.000 97.407 0.0000.000 0.128 837.065.200.000 0.006 0.00 0.18 180.0 NO2/Mid O2 System with Response Time 8/20/2024 06:15 95.7321.9000.009 0.000 0.0000.237 0.366 1.030 0.0000.0010.000 0.325 0.0000.408 0.098 838.00.490.111 0.003 97.63 10.57 180.0 8/20/2024 06:16 96.2291.6860.008 0.000 0.0000.143 0.371 0.815 0.0000.0000.000 0.000 0.0000.061 0.125 838.00.320.105 0.009 97.92 10.66 180.0 8/20/2024 06:16 96.1591.6530.010 0.000 0.2600.111 0.375 0.802 0.0000.0000.000 0.177 0.0000.339 0.114 839.00.350.000 0.007 97.81 10.75 180.0 Spike System with Response Time 8/20/2024 06:19 0.000250.2420.007 4.646 3.786502.655 1.305 2.303 6.7120.0551.156 1.462 259.4250.109 0.000 840.0262.102.547 9.999 250.24 0.14 180.0 8/20/2024 06:19 0.000250.6060.004 4.667 3.255503.226 1.248 2.314 5.8440.0062.273 1.492 259.2340.000 0.000 840.0261.922.541 10.002 250.61 0.14 180.0 8/20/2024 06:19 0.000250.8460.005 4.652 2.867502.507 1.268 2.654 5.8750.0771.240 1.419 259.4150.000 0.000 840.0262.182.727 10.008 250.85 0.14 180.0 Baseline System with Response Time 8/20/2024 06:23 0.0000.6460.004 0.000 0.0000.584 0.037 0.659 0.0000.0000.000 0.000 0.4180.000 0.000 840.00.420.000 0.017 0.65 0.13 180.0 8/20/2024 06:23 0.0000.3180.001 0.000 0.0000.348 0.021 0.848 0.0000.0000.000 0.171 0.3500.289 0.000 840.00.510.067 0.015 0.32 0.13 180.0 8/20/2024 06:23 0.0000.3940.002 0.000 0.0000.349 0.040 0.846 0.0000.0190.000 0.008 0.3310.295 0.000 840.00.350.014 0.014 0.39 0.14 180.0 Run 1 - A 30minute/60min 8/20/2024 09:15 6.81871.45112.034 5.435 623.5808.728 0.000 0.000 39.4190.00010.087 4.398 5.2450.000 0.941 841.011.021.443 0.000 78.27 8.66 180.0 8/20/2024 09:16 6.59971.44412.031 5.444 624.4068.740 0.000 0.000 39.7660.00010.020 4.411 5.3590.000 0.875 841.011.081.550 0.000 78.04 8.65 180.0 8/20/2024 09:17 6.09670.19412.032 5.445 626.6958.850 0.000 0.000 40.1640.0009.914 4.319 5.3930.000 0.902 841.011.061.481 0.000 76.29 8.59 180.0 8/20/2024 09:18 6.69668.98012.067 5.447 629.0768.813 0.000 0.000 40.7010.00010.242 4.474 5.3700.000 0.841 841.010.931.339 0.002 75.68 8.54 180.0 8/20/2024 09:19 6.71167.00212.038 5.440 627.8538.812 0.000 0.000 40.7450.00010.085 4.674 5.4520.000 0.910 841.011.381.487 0.000 73.71 8.55 180.0 8/20/2024 09:20 6.29067.84612.039 5.444 628.6228.614 0.000 0.000 40.7030.0009.804 4.412 5.4830.000 0.862 841.011.191.559 0.000 74.14 8.54 180.0 8/20/2024 09:21 6.33866.42412.043 5.445 634.0638.811 0.000 0.000 42.0150.00010.341 4.541 5.4300.000 0.851 841.011.231.610 0.000 72.76 8.48 180.0 8/20/2024 09:23 6.47064.87112.037 5.429 635.2968.942 0.000 0.000 42.4570.00010.258 4.551 5.5900.000 0.805 841.011.331.650 0.000 71.34 8.48 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 09:24 6.33064.37112.038 5.429 632.8888.695 0.000 0.000 42.0450.00010.390 4.609 5.5030.000 0.865 841.011.261.438 0.000 70.70 8.47 180.0 8/20/2024 09:25 6.10664.69712.048 5.427 633.5058.724 0.000 0.000 42.1170.0009.909 4.561 5.5040.000 0.856 841.011.191.398 0.000 70.80 8.48 180.0 8/20/2024 09:26 6.43865.25912.053 5.432 636.2598.635 0.000 0.000 42.4800.0009.816 4.521 5.4690.000 0.844 841.011.111.414 0.000 71.70 8.47 180.0 8/20/2024 09:27 6.37465.48012.058 5.429 634.9458.851 0.000 0.000 41.9010.00010.173 4.535 5.3960.000 0.878 841.010.991.221 0.000 71.85 8.39 180.0 8/20/2024 09:28 6.15165.43112.048 5.424 633.5568.710 0.000 0.000 42.1640.00010.051 4.553 5.4570.000 0.837 841.010.931.146 0.000 71.58 8.58 180.0 8/20/2024 09:29 6.14467.03312.033 5.443 629.5868.746 0.000 0.000 41.1390.00010.037 4.494 5.4260.000 0.870 841.011.081.384 0.000 73.18 8.54 180.0 8/20/2024 09:30 6.31965.66912.037 5.432 633.7209.004 0.000 0.000 41.5850.00010.468 4.492 5.3880.000 0.877 841.011.101.444 0.000 71.99 8.48 180.0 8/20/2024 09:31 6.59665.08712.052 5.445 632.7548.717 0.000 0.000 41.5790.00010.324 4.398 5.4800.000 0.812 841.010.981.414 0.000 71.68 8.49 180.0 8/20/2024 09:32 5.77365.21412.011 5.429 635.2518.533 0.000 0.000 42.1720.0009.875 4.644 5.4790.000 0.838 841.011.271.536 0.003 70.99 8.46 180.0 8/20/2024 09:33 6.16864.93212.042 5.437 634.3998.783 0.000 0.000 41.8540.0009.945 4.525 5.4430.000 0.817 841.011.031.409 0.000 71.10 8.38 180.0 8/20/2024 09:34 5.43164.89412.059 5.444 635.9508.399 0.000 0.000 42.3540.00010.071 4.468 5.3780.000 0.803 841.010.931.458 0.000 70.33 8.47 180.0 8/20/2024 09:35 6.05163.00912.047 5.429 638.1208.573 0.000 0.000 42.6290.00010.552 4.701 5.4590.000 0.809 841.011.071.287 0.000 69.06 8.34 180.0 8/20/2024 09:36 6.02362.55212.086 5.441 637.6128.736 0.000 0.000 42.7760.00010.300 4.650 5.4900.000 0.812 841.011.141.385 0.000 68.57 8.46 180.0 8/20/2024 09:37 6.07964.84812.067 5.444 634.9758.714 0.000 0.000 42.4770.00010.064 4.498 5.4850.000 0.790 841.011.041.471 0.000 70.93 8.57 180.0 8/20/2024 09:38 6.40365.03712.021 5.429 634.5168.877 0.000 0.000 42.2210.00010.190 4.556 5.4080.000 0.825 841.010.991.350 0.000 71.44 8.49 180.0 8/20/2024 09:39 5.60964.76912.015 5.441 635.2978.654 0.000 0.000 42.3230.0009.918 4.654 5.3990.000 0.828 841.011.021.295 0.000 70.38 8.44 180.0 8/20/2024 09:40 5.83163.11612.049 5.434 637.8968.698 0.000 0.000 42.9380.00010.035 4.421 5.5260.000 0.775 841.010.911.328 0.000 68.95 8.37 180.0 8/20/2024 09:42 5.86062.75612.074 5.426 637.3768.884 0.000 0.000 42.8100.0009.960 4.535 5.6190.000 0.773 841.011.151.443 0.000 68.62 8.37 180.0 8/20/2024 09:43 5.62864.28412.096 5.443 633.6728.472 0.000 0.000 41.7820.0009.670 4.627 5.4840.000 0.786 841.011.091.432 0.000 69.91 8.37 180.0 8/20/2024 09:44 6.29363.64012.054 5.452 637.1008.515 0.000 0.000 42.6560.0009.964 4.581 5.5440.000 0.760 841.011.011.332 0.000 69.93 8.48 180.0 8/20/2024 09:45 6.13464.25812.082 5.447 636.5168.688 0.000 0.000 42.9780.00010.475 4.397 5.4650.000 0.784 841.011.011.568 0.000 70.39 8.46 180.0 8/20/2024 09:46 6.14265.35912.062 5.451 634.5828.574 0.000 0.000 41.9780.0009.909 4.601 5.4530.000 0.791 841.010.931.245 0.000 71.50 8.47 180.0 6.19765.66412.048 5.438 633.3368.716 0.000 0.000 41.8310.00010.095 4.527 5.4530.000 0.834 841.0011.0821.417 0.000 71.860 8.484 180.0Avg. Spike 1 8/20/2024 09:49 8.78174.54611.193 5.325 604.46947.415 0.000 0.787 35.6530.0006.331 5.814 24.8020.000 1.109 841.032.001.661 0.764 83.33 8.33 180.0 Run 1 - B 30minute/60min 8/20/2024 09:51 6.12665.14912.041 5.449 632.3858.517 0.000 0.000 41.6610.00010.190 4.600 5.5680.000 0.755 841.011.151.514 0.000 71.27 8.46 180.0 8/20/2024 09:52 6.19565.15112.018 5.445 633.5448.700 0.000 0.000 41.7930.0009.964 4.422 5.5310.000 0.782 841.011.021.466 0.000 71.35 8.46 180.0 8/20/2024 09:53 5.56364.55512.069 5.449 635.0728.764 0.000 0.000 42.3710.0009.944 4.503 5.4270.000 0.809 841.010.861.220 0.000 70.12 8.46 180.0 8/20/2024 09:54 5.43464.06512.066 5.441 636.3378.510 0.000 0.000 42.6220.00010.015 4.614 5.4770.000 0.799 841.011.081.390 0.000 69.50 8.37 180.0 8/20/2024 09:55 6.01664.85812.055 5.441 633.6878.566 0.000 0.000 42.0790.00010.570 4.563 5.4720.000 0.802 841.011.071.421 0.000 70.87 8.46 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 09:56 5.56764.08012.074 5.444 635.6538.801 0.000 0.000 42.4560.00010.524 4.575 5.4510.000 0.795 841.011.101.510 0.000 69.65 8.48 180.0 8/20/2024 09:57 5.50563.80312.093 5.456 636.4118.761 0.000 0.000 42.8160.00010.161 4.636 5.5820.000 0.771 841.011.221.509 0.000 69.31 8.36 180.0 8/20/2024 09:58 6.20165.66412.066 5.468 633.1138.735 0.000 0.000 41.8340.00010.033 4.572 5.5440.000 0.800 841.011.121.397 0.000 71.87 8.38 180.0 8/20/2024 09:59 6.77064.42012.098 5.444 633.3468.724 0.000 0.000 42.0290.00010.007 4.486 5.5030.000 0.781 841.010.971.369 0.000 71.19 8.45 180.0 8/20/2024 10:00 5.82264.47612.066 5.457 633.8538.456 0.000 0.000 42.0990.0009.952 4.574 5.4400.000 0.788 841.011.181.672 0.000 70.30 8.55 180.0 8/20/2024 10:01 6.13466.47312.050 5.456 630.4058.714 0.000 0.000 40.8320.00010.125 4.576 5.4430.000 0.829 841.011.101.422 0.000 72.61 8.48 180.0 8/20/2024 10:02 6.40466.25312.020 5.441 631.5668.795 0.000 0.000 41.4740.00010.004 4.439 5.4790.000 0.767 841.010.991.526 0.000 72.66 8.55 180.0 8/20/2024 10:03 6.47664.94212.010 5.441 631.9438.587 0.000 0.000 41.5090.0009.826 4.574 5.5070.000 0.807 841.011.171.503 0.000 71.42 8.55 180.0 8/20/2024 10:04 5.70064.72411.998 5.446 632.6168.583 0.000 0.000 41.8690.0009.620 4.173 5.4850.000 0.807 841.010.901.530 0.000 70.42 8.54 180.0 8/20/2024 10:05 6.61964.89811.976 5.433 633.3238.800 0.000 0.000 41.9230.00010.186 4.548 5.4230.000 0.796 841.011.051.499 0.000 71.52 8.44 180.0 8/20/2024 10:06 6.19062.93112.021 5.437 637.6998.703 0.000 0.000 42.9810.0009.868 4.541 5.4020.000 0.787 841.011.011.508 0.000 69.12 8.46 180.0 8/20/2024 10:07 6.27764.21512.030 5.457 633.5588.832 0.000 0.000 42.0690.0009.861 4.436 5.4780.000 0.796 841.011.101.607 0.000 70.49 8.49 180.0 8/20/2024 10:08 6.01364.11512.032 5.440 632.0788.786 0.000 0.000 41.6800.00010.213 4.389 5.4730.000 0.791 841.010.901.384 0.000 70.13 8.45 180.0 8/20/2024 10:09 6.09363.16912.045 5.441 638.2999.008 0.000 0.000 42.7190.0009.952 4.560 5.5750.000 0.762 841.011.261.679 0.000 69.26 8.49 180.0 8/20/2024 10:10 5.53064.14911.995 5.431 632.3328.613 0.000 0.000 41.9320.0009.913 4.584 5.4180.000 0.797 841.010.971.349 0.000 69.68 8.49 180.0 8/20/2024 10:11 5.58264.30212.034 5.432 631.0518.785 0.000 0.000 41.6740.0009.822 4.246 5.4040.000 0.793 841.010.861.553 0.001 69.88 8.55 180.0 8/20/2024 10:12 5.58064.74512.003 5.447 632.8988.587 0.000 0.000 42.0190.0009.810 4.278 5.4150.000 0.789 841.010.891.568 0.000 70.33 8.38 180.0 8/20/2024 10:13 6.02063.59212.053 5.427 637.3978.899 0.000 0.000 43.0300.0009.762 4.397 5.5640.000 0.756 841.010.951.411 0.001 69.61 8.56 180.0 8/20/2024 10:14 6.41666.59411.945 5.444 629.5768.868 0.000 0.000 41.1880.0009.368 4.464 5.4880.000 0.791 841.011.041.493 0.000 73.01 8.55 180.0 8/20/2024 10:15 5.63463.81912.025 5.443 635.8628.704 0.000 0.000 42.7720.0009.799 4.501 5.5750.000 0.732 841.011.061.533 0.000 69.45 8.46 180.0 8/20/2024 10:16 6.07263.92212.027 5.448 637.1628.830 0.000 0.000 42.7520.0009.775 4.476 5.4950.000 0.763 841.011.051.563 0.000 69.99 8.47 180.0 8/20/2024 10:18 6.44463.60912.052 5.447 636.3219.032 0.000 0.000 42.4160.00010.052 4.706 5.5730.000 0.794 841.011.271.453 0.000 70.05 8.45 180.0 8/20/2024 10:19 6.32263.67612.044 5.446 634.3748.721 0.000 0.000 42.1480.0009.657 4.592 5.4930.000 0.813 841.011.101.373 0.000 70.00 8.46 180.0 8/20/2024 10:20 6.28863.61912.062 5.451 634.3598.781 0.000 0.000 42.3500.0009.790 4.486 5.4400.000 0.781 841.011.051.592 0.000 69.91 8.44 180.0 8/20/2024 10:21 6.53065.29012.022 5.449 632.3958.737 0.000 0.000 41.8380.00010.118 4.379 5.4670.000 0.777 841.010.751.208 0.001 71.82 8.48 180.0 6.05164.50912.036 5.445 633.9548.730 0.000 0.000 42.0980.0009.963 4.496 5.4860.000 0.787 841.0011.0411.474 0.000 70.560 8.472 180.0Avg. 6.12465.08612.042 5.441 633.6458.723 0.000 0.000 41.9640.00010.029 4.512 5.4690.000 0.810 841.0011.0621.446 0.000 71.210 8.478 180.0Run 1 Avg: Baseline 1 8/20/2024 10:24 0.0000.0000.121 0.000 3.9380.000 0.090 0.496 0.5170.0220.000 0.303 0.1680.000 0.000 841.00.410.063 0.015 0.00 0.43 180.0 Run 2 - A 30minute/60min 8/20/2024 10:26 4.53661.65511.181 5.049 596.3956.775 0.000 0.849 37.1300.0006.688 3.962 5.4540.000 1.044 841.011.141.431 0.000 66.19 7.81 180.0 8/20/2024 10:27 5.70562.72612.025 5.429 635.0578.727 0.000 0.010 42.4450.0008.777 4.245 5.5380.000 0.786 840.010.801.291 0.000 68.43 8.23 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 10:28 6.19164.79612.045 5.443 629.8428.797 0.000 0.000 41.3300.0009.956 4.386 5.5000.000 0.792 841.011.011.497 0.000 70.99 8.36 180.0 8/20/2024 10:29 6.50064.21212.021 5.447 633.6078.879 0.000 0.000 42.0040.00010.194 4.399 5.4860.000 0.774 841.010.971.508 0.000 70.71 8.24 180.0 8/20/2024 10:30 5.99563.37512.048 5.432 635.1868.866 0.000 0.000 42.4110.00010.016 4.536 5.5770.000 0.773 841.011.061.365 0.000 69.37 8.35 180.0 8/20/2024 10:31 5.76764.19812.057 5.445 634.5418.765 0.000 0.000 42.2880.00010.059 4.437 5.5080.000 0.741 841.011.001.581 0.000 69.96 8.35 180.0 8/20/2024 10:32 5.41863.82312.044 5.448 634.4888.860 0.000 0.000 42.1210.00010.479 4.541 5.5690.000 0.779 841.011.221.594 0.001 69.24 8.35 180.0 8/20/2024 10:33 6.42364.27812.075 5.452 632.8659.095 0.000 0.000 41.8930.0009.816 4.530 5.5000.000 0.795 841.011.131.526 0.000 70.70 8.44 180.0 8/20/2024 10:34 5.58164.88112.089 5.457 636.9249.196 0.000 0.000 42.4960.0009.960 4.473 5.3760.000 0.783 841.011.001.612 0.000 70.46 8.35 180.0 8/20/2024 10:35 6.19663.91012.110 5.468 637.3208.930 0.000 0.000 42.8210.0009.763 4.437 5.4130.000 0.769 841.010.981.600 0.000 70.11 8.38 180.0 8/20/2024 10:36 6.16863.31612.178 5.474 633.7169.096 0.000 0.000 41.8480.00010.283 4.387 5.3920.000 0.806 841.010.891.436 0.000 69.48 8.35 180.0 8/20/2024 10:37 6.03963.80112.128 5.437 634.5659.183 0.000 0.000 41.7970.0009.970 4.227 5.3870.000 0.823 841.010.691.261 0.002 69.84 8.35 180.0 8/20/2024 10:38 5.82063.29812.103 5.454 637.1278.997 0.000 0.000 42.6590.0009.973 4.471 5.4260.000 0.769 841.010.971.538 0.000 69.12 8.35 180.0 8/20/2024 10:39 5.70062.04912.191 5.452 643.4169.017 0.000 0.000 43.7650.00010.087 4.369 5.4250.000 0.784 841.010.971.590 0.000 67.75 8.34 180.0 8/20/2024 10:40 6.08964.00512.126 5.447 636.7729.194 0.000 0.000 42.4560.00010.192 4.356 5.4110.000 0.827 841.010.941.457 0.000 70.09 8.39 180.0 8/20/2024 10:41 5.53364.22312.116 5.449 633.2969.159 0.000 0.000 42.0370.0009.703 4.435 5.3790.000 0.812 841.010.901.415 0.002 69.76 8.38 180.0 8/20/2024 10:42 6.29463.70712.105 5.463 636.1248.742 0.000 0.000 42.2740.00010.108 4.247 5.4560.000 0.721 841.010.941.824 0.000 70.00 8.37 180.0 8/20/2024 10:43 6.10263.84112.090 5.443 632.8088.923 0.000 0.000 41.7660.00010.184 4.568 5.4630.000 0.783 841.011.021.420 0.000 69.94 8.37 180.0 8/20/2024 10:44 6.23964.09912.094 5.435 633.8998.947 0.000 0.000 42.1520.0009.886 4.236 5.4350.000 0.771 841.010.891.631 0.001 70.34 8.37 180.0 8/20/2024 10:45 5.80264.65912.106 5.447 631.6979.058 0.000 0.000 41.5870.0009.985 4.354 5.3860.000 0.816 841.010.971.575 0.000 70.46 8.38 180.0 8/20/2024 10:46 6.24164.22012.118 5.450 633.4679.150 0.000 0.000 41.8330.00010.104 4.514 5.3800.000 0.852 841.011.061.454 0.000 70.46 8.34 180.0 8/20/2024 10:47 6.17964.44012.132 5.450 632.8919.150 0.000 0.000 41.6590.0009.755 4.422 5.3830.000 0.816 841.010.981.524 0.000 70.62 8.36 180.0 8/20/2024 10:48 5.77465.14712.160 5.468 634.3099.162 0.000 0.000 41.9360.00010.060 4.268 5.5130.000 0.791 840.011.081.707 0.000 70.92 8.46 180.0 8/20/2024 10:49 6.22765.47912.120 5.471 630.0049.140 0.000 0.000 41.3670.0009.980 4.562 5.5150.000 0.837 840.011.461.846 0.000 71.71 8.37 180.0 8/20/2024 10:50 6.07864.09912.151 5.463 629.4278.969 0.000 0.000 41.7030.00010.254 4.495 5.6940.000 0.809 840.011.341.551 0.000 70.18 8.38 180.0 8/20/2024 10:51 5.50462.80412.162 5.462 632.8189.124 0.000 0.000 42.1710.0009.772 4.470 5.5730.000 0.865 840.011.231.419 0.000 68.31 8.43 180.0 8/20/2024 10:52 5.75464.32212.118 5.471 629.1829.119 0.000 0.000 41.3830.0009.644 4.512 5.6620.000 0.833 840.011.461.686 0.000 70.08 8.38 180.0 8/20/2024 10:53 6.23364.35812.161 5.469 631.4089.233 0.000 0.000 41.8960.00010.033 4.452 5.7720.000 0.834 840.011.481.601 0.000 70.59 8.38 180.0 8/20/2024 10:55 5.80364.20912.165 5.474 632.8369.045 0.000 0.000 42.1790.0009.871 4.501 5.6630.000 0.809 840.011.291.506 0.000 70.01 8.37 180.0 8/20/2024 10:56 5.55962.97212.187 5.480 635.2689.316 0.000 0.000 42.4910.0009.968 4.440 5.6920.000 0.829 840.011.431.681 0.000 68.53 8.45 180.0 5.91563.89712.080 5.441 632.7098.954 0.000 0.029 41.9300.0009.851 4.408 5.4980.000 0.807 840.7011.0771.538 0.000 69.812 8.348 180.0Avg. Spike 2 8/20/2024 11:00 5.41077.81211.213 5.380 596.08848.670 0.000 0.324 35.4960.0007.814 5.728 24.4880.000 1.115 840.031.751.820 0.742 83.22 8.33 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/20/2024 11:02 5.59763.82112.060 5.466 633.3209.640 0.000 0.000 42.4830.00010.155 4.462 5.9670.000 0.818 840.011.671.642 0.001 69.42 8.44 180.0 8/20/2024 11:03 5.89563.50212.069 5.470 633.9129.411 0.000 0.000 42.4960.00010.074 4.488 5.7490.000 0.813 840.011.541.766 0.000 69.40 8.47 180.0 8/20/2024 11:04 5.79764.05312.098 5.459 631.2089.113 0.000 0.000 41.9770.0009.524 4.233 5.7280.000 0.842 840.011.281.563 0.002 69.85 8.48 180.0 8/20/2024 11:05 6.13763.46012.122 5.461 629.9769.300 0.000 0.000 41.9900.0009.909 4.475 5.6500.000 0.842 841.011.361.569 0.000 69.60 8.38 180.0 8/20/2024 11:06 6.33164.87712.108 5.464 631.1829.205 0.000 0.000 42.0460.0009.460 4.395 5.7840.000 0.816 840.011.431.625 0.001 71.21 8.46 180.0 8/20/2024 11:07 6.38363.79612.095 5.474 633.6569.226 0.000 0.000 42.6360.0009.935 4.406 5.7950.000 0.839 840.011.651.865 0.000 70.18 8.36 180.0 8/20/2024 11:08 6.07362.91512.154 5.456 635.2969.376 0.000 0.000 42.7190.0009.926 4.643 5.7170.000 0.834 840.011.681.803 0.000 68.99 8.37 180.0 8/20/2024 11:09 5.96163.94512.144 5.480 634.3239.604 0.000 0.000 42.4110.00010.021 4.258 5.7560.000 0.808 840.011.441.838 0.000 69.91 8.37 180.0 8/20/2024 11:10 6.02864.61012.146 5.499 631.5499.243 0.000 0.000 41.9390.0009.832 4.566 5.5690.000 0.845 840.011.391.627 0.000 70.64 8.38 180.0 8/20/2024 11:11 6.00263.71512.164 5.483 633.8919.531 0.000 0.000 42.2680.0009.819 4.700 5.7070.000 0.821 840.011.601.669 0.000 69.72 8.45 180.0 8/20/2024 11:12 5.67863.38712.191 5.489 634.2479.618 0.000 0.000 42.4030.0009.975 4.440 5.7150.000 0.807 840.011.321.553 0.000 69.06 8.38 180.0 8/20/2024 11:13 6.10664.39012.161 5.464 632.3019.259 0.000 0.000 42.1190.0009.830 4.369 5.6720.000 0.850 840.011.431.719 0.001 70.50 8.46 180.0 8/20/2024 11:14 5.57763.75512.128 5.466 629.9309.179 0.000 0.000 41.5430.0009.739 4.325 5.6160.000 0.851 840.011.361.730 0.000 69.33 8.44 180.0 8/20/2024 11:15 5.76663.78112.119 5.461 632.1079.350 0.000 0.000 42.1730.0009.373 4.326 5.5930.000 0.825 840.011.221.646 0.000 69.55 8.43 180.0 8/20/2024 11:16 5.59864.80812.115 5.479 628.2519.400 0.000 0.000 41.3510.0009.903 4.313 5.5690.000 0.870 840.011.291.652 0.000 70.41 8.48 180.0 8/20/2024 11:17 5.96563.94012.119 5.470 630.3089.348 0.000 0.000 41.5720.0009.434 4.334 5.6550.000 0.841 840.011.281.581 0.000 69.90 8.55 180.0 8/20/2024 11:18 5.72664.53712.133 5.475 632.3799.387 0.000 0.000 41.8140.0009.765 4.217 5.5310.000 0.844 840.011.181.722 0.000 70.26 8.48 180.0 8/20/2024 11:19 6.27363.24812.156 5.471 634.7489.435 0.000 0.000 42.4530.0009.852 4.218 5.6430.000 0.829 840.011.361.863 0.000 69.52 8.38 180.0 8/20/2024 11:20 5.68263.78312.166 5.475 632.1499.603 0.000 0.000 42.1470.00010.106 4.246 5.5980.000 0.853 840.011.311.768 0.000 69.47 8.46 180.0 8/20/2024 11:21 6.17164.10212.152 5.477 630.0479.210 0.000 0.000 41.8480.0009.863 4.419 5.6710.000 0.879 840.011.461.632 0.000 70.27 8.37 180.0 8/20/2024 11:22 6.34864.08612.155 5.473 631.6029.475 0.000 0.000 41.8410.00010.046 4.294 5.7120.000 0.836 840.011.461.816 0.000 70.43 8.46 180.0 8/20/2024 11:23 5.79664.46512.123 5.473 629.2909.281 0.000 0.000 41.6080.0009.418 4.234 5.6260.000 0.856 840.011.341.765 0.000 70.26 8.45 180.0 8/20/2024 11:24 5.65662.44812.127 5.472 633.9509.557 0.000 0.000 42.7330.0009.618 4.175 5.5980.000 0.833 840.011.201.734 0.000 68.10 8.38 180.0 8/20/2024 11:25 6.53064.62912.145 5.471 629.3339.653 0.000 0.000 41.5650.0009.376 4.456 5.6300.000 0.838 840.011.581.949 0.000 71.16 8.43 180.0 8/20/2024 11:26 5.92464.93112.153 5.473 629.3259.405 0.000 0.000 41.5760.0009.693 4.559 5.6100.000 0.881 840.011.541.690 0.000 70.85 8.54 180.0 8/20/2024 11:27 6.29565.24412.120 5.464 628.1049.391 0.000 0.000 40.9660.0009.394 4.551 5.6990.000 0.855 840.011.541.639 0.000 71.54 8.47 180.0 8/20/2024 11:28 6.34564.30412.153 5.474 631.0219.293 0.000 0.000 41.7520.0009.694 4.372 5.6920.000 0.839 840.011.531.865 0.000 70.65 8.44 180.0 8/20/2024 11:29 6.62964.95012.126 5.478 630.8729.568 0.000 0.000 41.5390.0009.569 4.281 5.6200.000 0.871 840.011.501.928 0.000 71.58 8.45 180.0 8/20/2024 11:31 5.51863.85112.167 5.480 631.3989.498 0.000 0.000 42.1120.0009.445 4.407 5.6110.000 0.836 840.011.351.695 0.000 69.37 8.37 180.0 8/20/2024 11:32 6.29164.09012.174 5.502 630.3979.279 0.000 0.000 41.8040.0009.653 4.287 5.6060.000 0.836 840.011.391.875 0.000 70.38 8.47 180.0 6.00364.04712.135 5.473 631.6699.395 0.000 0.000 41.9960.0009.747 4.382 5.6700.000 0.840 840.0311.4231.726 0.000 70.050 8.435 180.0Avg. 5.95963.97212.107 5.457 632.1899.174 0.000 0.014 41.9630.0009.799 4.395 5.5840.000 0.824 840.3711.2501.632 0.000 69.931 8.391 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/20/2024 11:34 0.0000.0000.099 0.000 2.8700.183 0.114 0.480 0.1020.0280.000 0.148 0.2470.000 0.000 840.00.460.175 0.010 0.00 0.40 180.0 Run 3 - A 30minute/60min 8/20/2024 11:36 2.64060.15810.947 4.948 578.3907.179 0.000 0.940 35.1720.0006.258 3.874 5.5320.000 1.168 840.011.842.081 0.000 62.80 7.71 180.0 8/20/2024 11:37 4.81461.82112.106 5.436 632.1999.593 0.000 0.006 42.4220.0008.611 4.206 5.5950.000 0.846 840.011.241.728 0.000 66.63 8.22 180.0 8/20/2024 11:38 6.23363.46512.110 5.465 631.4929.381 0.000 0.000 42.0020.0009.620 4.244 5.6840.000 0.827 840.011.401.850 0.000 69.70 8.27 180.0 8/20/2024 11:39 5.81562.88912.159 5.470 634.9159.403 0.000 0.032 42.7110.0008.746 4.436 5.6880.000 0.821 840.011.401.669 0.000 68.70 8.26 180.0 8/20/2024 11:40 5.54462.20612.173 5.470 631.5289.508 0.000 0.000 42.1800.0009.547 4.308 5.6720.000 0.823 840.011.311.678 0.000 67.75 8.23 180.0 8/20/2024 11:41 6.08761.77512.233 5.465 633.3719.386 0.000 0.000 42.4090.0009.831 4.299 5.8190.000 0.795 840.011.561.921 0.000 67.86 8.33 180.0 8/20/2024 11:42 5.67464.28712.211 5.473 629.2079.373 0.000 0.000 41.4500.0009.587 4.319 5.6730.000 0.833 840.011.241.526 0.000 69.96 8.36 180.0 8/20/2024 11:43 5.21963.75812.257 5.486 628.8359.312 0.000 0.000 41.4600.00010.054 4.249 5.5960.000 0.863 840.011.061.362 0.000 68.98 8.38 180.0 8/20/2024 11:44 6.15663.20712.254 5.486 631.0839.382 0.000 0.000 41.9000.0009.794 4.444 5.6170.000 0.852 840.011.541.885 0.000 69.36 8.33 180.0 8/20/2024 11:45 5.72362.56812.285 5.499 633.9529.509 0.000 0.000 42.6550.0009.564 4.312 5.6090.000 0.790 840.011.311.868 0.000 68.29 8.24 180.0 8/20/2024 11:46 6.25163.48912.264 5.489 633.1819.580 0.000 0.000 42.0140.0009.753 4.273 5.5200.000 0.844 840.011.281.834 0.000 69.74 8.37 180.0 8/20/2024 11:47 6.19462.83312.259 5.482 632.3559.499 0.000 0.000 42.0180.0009.790 4.360 5.6120.000 0.815 840.011.271.687 0.001 69.03 8.37 180.0 8/20/2024 11:48 5.61364.14112.222 5.481 631.3909.514 0.000 0.000 41.9480.0009.496 4.267 5.5750.000 0.858 840.011.241.662 0.000 69.75 8.38 180.0 8/20/2024 11:49 6.08163.23312.216 5.475 633.8509.825 0.000 0.000 42.2160.0009.674 4.281 5.6150.000 0.827 840.011.371.873 0.000 69.31 8.34 180.0 8/20/2024 11:50 5.56563.66612.194 5.476 633.2369.624 0.000 0.000 42.0630.0009.810 4.561 5.6240.000 0.838 840.011.531.792 0.000 69.23 8.35 180.0 8/20/2024 11:51 5.79064.40912.209 5.484 630.6189.507 0.000 0.000 41.3920.0009.997 4.337 5.5680.000 0.842 840.011.411.895 0.000 70.20 8.44 180.0 8/20/2024 11:52 5.58165.17612.212 5.477 630.5599.180 0.000 0.000 41.4590.0009.579 4.369 5.5290.000 0.850 840.011.401.890 0.000 70.76 8.37 180.0 8/20/2024 11:53 6.26163.43912.222 5.474 632.0959.641 0.000 0.000 42.0900.0009.567 4.235 5.5160.000 0.820 840.011.251.903 0.000 69.70 8.37 180.0 8/20/2024 11:54 5.82863.70412.186 5.476 631.1349.399 0.000 0.000 41.4650.0009.585 4.339 5.4960.000 0.885 840.011.441.922 0.000 69.53 8.45 180.0 8/20/2024 11:55 6.59465.33812.158 5.489 627.7939.449 0.000 0.000 40.9110.0009.327 4.430 5.4910.000 0.881 840.011.471.895 0.000 71.93 8.45 180.0 8/20/2024 11:56 6.06464.66212.170 5.474 632.1019.567 0.000 0.000 42.0140.0009.833 4.293 5.5720.000 0.865 840.011.311.720 0.000 70.73 8.35 180.0 8/20/2024 11:57 6.70464.24812.144 5.476 630.4749.627 0.000 0.000 41.6370.0009.747 4.214 5.5720.000 0.876 840.011.401.906 0.000 70.95 8.44 180.0 8/20/2024 11:58 5.90863.31912.109 5.456 631.2159.760 0.000 0.000 41.7740.0009.727 4.398 5.4690.000 0.839 840.011.432.018 0.000 69.23 8.48 180.0 8/20/2024 11:59 5.00963.25512.146 5.473 628.2809.899 0.000 0.000 41.3620.0009.568 4.224 5.4690.000 0.886 840.011.321.894 0.000 68.26 8.43 180.0 8/20/2024 12:00 6.48064.40312.126 5.487 630.2719.880 0.000 0.000 41.3460.0009.372 4.358 5.5710.000 0.866 840.011.461.884 0.000 70.88 8.44 180.0 8/20/2024 12:01 6.65563.75712.107 5.472 629.2049.900 0.000 0.000 41.5780.0009.517 4.543 5.5550.000 0.879 840.011.631.939 0.000 70.41 8.45 180.0 8/20/2024 12:02 6.56364.60812.097 5.471 627.7739.919 0.000 0.000 41.2130.0009.610 4.124 5.6650.000 0.855 840.011.421.943 0.000 71.17 8.55 180.0 8/20/2024 12:03 6.19464.91812.104 5.477 629.3409.683 0.000 0.000 41.4780.0009.420 4.110 5.6240.000 0.857 840.011.121.558 0.000 71.11 8.47 180.0 8/20/2024 12:04 6.05264.31512.108 5.469 629.2849.685 0.000 0.000 41.5190.0009.492 4.196 5.5890.000 0.885 840.011.431.905 0.000 70.37 8.36 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 12:05 6.45363.63712.108 5.471 630.7829.777 0.000 0.000 41.8420.0009.644 4.474 5.8100.000 0.857 840.011.701.785 0.000 70.09 8.46 180.0 5.85863.55612.137 5.458 629.3309.498 0.000 0.033 41.5900.0009.471 4.303 5.5980.000 0.858 840.0011.3931.816 0.000 69.414 8.355 180.0Avg. Spike 3 8/20/2024 12:09 6.28974.90911.255 5.362 595.88447.170 0.000 0.368 35.3770.0007.763 5.564 23.6320.000 1.173 840.030.931.872 0.715 81.20 8.34 180.0 Run 3 - B 30minute/60min 8/20/2024 12:11 5.41870.52211.787 5.446 615.66619.971 0.000 0.076 38.8660.0007.776 4.752 10.9390.000 0.933 840.017.081.661 0.198 75.94 8.52 180.0 8/20/2024 12:12 6.23964.24412.039 5.488 629.47510.172 0.000 0.002 41.7020.0008.502 4.305 5.8400.000 0.883 840.011.771.946 0.001 70.48 8.37 180.0 8/20/2024 12:13 5.86761.38412.135 5.480 634.12810.072 0.000 0.000 42.7480.0009.146 4.431 5.8130.000 0.864 840.011.731.851 0.000 67.25 8.32 180.0 8/20/2024 12:14 5.39162.94112.157 5.492 631.5519.778 0.000 0.000 42.1090.0009.378 4.294 5.6600.000 0.886 840.011.241.425 0.000 68.33 8.44 180.0 8/20/2024 12:15 6.15463.09912.161 5.502 631.6159.907 0.000 0.000 41.9800.0009.431 4.279 5.7400.000 0.891 840.011.631.888 0.000 69.25 8.45 180.0 8/20/2024 12:16 5.56863.03512.080 5.474 628.45010.110 0.000 0.000 41.4420.0009.286 4.373 5.7030.000 0.885 840.011.571.778 0.000 68.60 8.38 180.0 8/20/2024 12:17 6.12862.90512.057 5.468 630.25210.090 0.000 0.000 41.9590.0009.540 4.215 5.8840.000 0.847 840.011.631.859 0.000 69.03 8.35 180.0 8/20/2024 12:18 5.95262.90912.103 5.488 630.74310.125 0.000 0.000 42.0930.0009.483 4.452 5.7040.000 0.860 840.011.581.774 0.001 68.86 8.45 180.0 8/20/2024 12:19 6.34063.93712.093 5.479 628.0839.511 0.000 0.000 41.3310.0009.171 4.518 5.7300.000 0.870 840.011.811.985 0.001 70.28 8.46 180.0 8/20/2024 12:20 5.33464.13312.081 5.476 629.4069.439 0.000 0.000 41.6080.0009.166 4.229 5.6220.000 0.887 840.011.221.505 0.000 69.47 8.46 180.0 8/20/2024 12:21 6.18463.25612.079 5.479 631.1259.359 0.000 0.000 42.0010.0009.688 4.286 5.6750.000 0.889 840.011.652.005 0.001 69.44 8.46 180.0 8/20/2024 12:22 5.90064.26412.083 5.476 628.2099.652 0.000 0.000 41.0720.0009.102 4.307 5.6060.000 0.894 840.011.481.816 0.000 70.16 8.47 180.0 8/20/2024 12:23 5.90262.58012.068 5.471 630.0909.492 0.000 0.000 41.9510.0009.417 4.467 5.6880.000 0.856 840.011.371.480 0.000 68.48 8.36 180.0 8/20/2024 12:24 6.15263.05812.072 5.473 632.0159.460 0.000 0.000 42.3050.0009.262 4.490 5.7620.000 0.823 840.011.742.000 0.000 69.21 8.45 180.0 8/20/2024 12:25 5.94563.18912.110 5.470 630.5479.480 0.000 0.000 41.6910.0009.626 4.323 5.6960.000 0.874 840.011.561.854 0.000 69.13 8.45 180.0 8/20/2024 12:26 6.28562.55312.103 5.469 633.8979.565 0.000 0.000 42.3700.0009.879 4.382 5.6780.000 0.855 840.011.692.079 0.000 68.84 8.44 180.0 8/20/2024 12:27 5.49464.14512.113 5.463 629.0159.384 0.000 0.000 41.6890.0009.766 4.468 5.6530.000 0.859 840.011.541.787 0.000 69.64 8.48 180.0 8/20/2024 12:28 6.16964.68012.108 5.466 626.3409.553 0.000 0.000 41.1860.0009.277 4.519 5.6420.000 0.869 840.011.601.807 0.000 70.85 8.47 180.0 8/20/2024 12:29 5.99662.75312.128 5.462 629.5639.546 0.000 0.000 41.7600.0009.681 4.195 5.7680.000 0.832 840.011.491.886 0.000 68.75 8.46 180.0 8/20/2024 12:30 5.76764.28812.128 5.478 628.7939.532 0.000 0.000 41.5360.0009.526 4.206 5.6120.000 0.862 840.011.141.504 0.000 70.05 8.44 180.0 8/20/2024 12:31 5.71864.30012.151 5.468 629.2219.777 0.000 0.000 41.6850.0009.598 4.386 5.7610.000 0.859 840.011.641.855 0.000 70.02 8.38 180.0 8/20/2024 12:32 5.59065.02912.112 5.479 627.0089.600 0.000 0.000 41.0310.0009.908 4.450 5.6110.000 0.886 840.011.541.782 0.000 70.62 8.46 180.0 8/20/2024 12:33 6.13264.47912.094 5.465 627.2459.621 0.000 0.000 41.0270.0009.579 4.475 5.6510.000 0.903 840.011.641.798 0.000 70.61 8.46 180.0 8/20/2024 12:34 5.71464.33612.094 5.475 627.5929.506 0.000 0.000 41.2720.0009.732 4.535 5.7410.000 0.883 840.011.761.851 0.000 70.05 8.46 180.0 8/20/2024 12:35 6.41565.50212.032 5.471 626.5439.737 0.000 0.000 40.8770.0009.584 4.412 5.6460.000 0.890 840.011.601.847 0.000 71.92 8.58 180.0 8/20/2024 12:36 6.27166.81811.951 5.479 622.5119.337 0.000 0.000 40.1780.0009.589 4.277 5.7490.000 0.846 840.011.531.858 0.000 73.09 8.58 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 12:37 7.41065.63111.962 5.480 626.1709.550 0.000 0.000 40.8670.0009.034 4.303 5.8350.000 0.819 840.011.601.889 0.000 73.04 8.65 180.0 8/20/2024 12:38 6.21766.27611.946 5.479 625.6489.324 0.000 0.000 40.5870.0009.717 4.347 5.6860.000 0.914 840.011.621.809 0.000 72.49 8.58 180.0 8/20/2024 12:39 6.65863.38212.008 5.455 627.8309.539 0.000 0.000 41.6610.0009.483 4.380 5.7270.000 0.849 840.011.651.965 0.000 70.04 8.37 180.0 8/20/2024 12:40 6.15664.13612.005 5.456 629.7219.675 0.000 0.000 42.1620.0009.534 4.439 5.7060.000 0.849 840.011.561.788 0.000 70.29 8.56 180.0 6.01664.12512.068 5.474 628.6159.995 0.000 0.003 41.4920.0009.395 4.383 5.8840.000 0.871 840.0011.7551.811 0.007 70.140 8.459 180.0Avg. 5.93763.84112.102 5.466 628.9739.747 0.000 0.018 41.5410.0009.433 4.343 5.7410.000 0.864 840.0011.5741.813 0.003 69.777 8.407 180.0Run 3 Avg: Baseline 3 8/20/2024 12:44 0.0000.0000.069 0.000 1.3860.112 0.066 0.469 0.0000.0120.000 0.236 0.2300.000 0.000 840.00.580.284 0.007 0.00 0.24 180.0 Post CTS 8/20/2024 12:45 0.0002.6810.061 0.000 0.1470.159 0.037 0.883 0.0000.0110.000 100.647 0.1550.000 0.000 839.067.470.321 0.002 2.68 0.23 180.0 8/20/2024 12:45 0.0003.4540.059 0.000 0.0000.132 0.055 0.788 0.0000.0260.000 101.473 0.0000.224 0.021 840.067.730.063 0.007 3.45 0.22 180.0 8/20/2024 12:45 0.0001.6970.061 0.000 0.0000.187 0.069 0.689 0.0370.0230.000 101.302 0.1740.000 0.000 840.067.860.228 0.025 1.70 0.22 180.0 Post NO2/Mid O2 8/20/2024 12:50 96.1870.0000.042 0.000 0.7680.268 0.359 0.516 0.0000.0040.000 0.061 0.0000.958 0.024 839.00.090.000 0.000 96.19 10.97 180.0 8/20/2024 12:50 96.2840.1880.042 0.000 1.3620.230 0.379 0.451 0.7130.0000.000 0.000 0.0000.582 0.021 839.00.410.557 0.009 96.47 10.96 180.0 8/20/2024 12:50 97.8020.3630.040 0.000 1.0020.210 0.368 0.363 0.5280.0400.000 0.000 0.0000.247 0.036 839.00.380.455 0.010 98.17 10.95 180.0 8/20/2024 12:50 97.9810.4060.044 0.000 0.9880.305 0.377 0.506 0.5960.0000.000 0.000 0.0000.000 0.013 839.00.370.513 0.013 98.39 10.97 180.0 Post 5-Gas 8/20/2024 12:51 0.000251.9440.050 4.546 3.891495.899 1.227 1.494 6.6020.0910.000 1.697 255.4150.000 0.000 839.0258.683.194 9.887 251.94 0.13 180.0 8/20/2024 12:51 0.000252.7510.060 4.595 2.644498.988 1.267 1.517 5.4070.0690.000 1.548 257.5960.000 0.000 839.0260.492.796 9.948 252.75 0.13 180.0 8/20/2024 12:52 0.000254.6190.047 4.524 1.992500.541 1.229 1.801 4.9900.0251.244 1.440 258.1980.369 0.000 839.0260.882.588 9.985 254.62 0.14 180.0 8/20/2024 12:52 0.000254.4750.045 4.545 2.957500.435 1.315 1.284 5.5350.0870.000 1.376 257.8970.000 0.000 839.0260.662.760 9.998 254.48 0.14 180.0 8/20/2024 12:52 0.000254.3520.036 4.558 1.575501.909 1.306 1.727 4.8190.1510.000 1.522 258.7290.328 0.000 839.0261.512.650 9.975 254.35 0.14 180.0 8/20/2024 12:52 0.000255.4190.051 4.536 1.939502.705 1.279 1.646 5.4110.0110.946 1.487 258.9130.156 0.000 839.0261.812.853 9.982 255.42 0.14 180.0 8/20/2024 12:52 0.000254.0850.038 4.594 2.643500.867 1.290 2.028 5.5800.0041.264 1.380 258.7400.000 0.000 839.0261.532.805 10.016 254.09 0.14 180.0 End of Test Purge 8/20/2024 12:54 0.0000.9020.042 0.000 0.1881.843 0.097 0.223 0.0000.0620.000 0.095 0.9450.280 0.000 839.01.550.814 0.048 0.90 0.14 180.0 8/20/2024 12:54 0.0000.0000.029 0.000 0.1121.750 0.098 0.417 0.0000.0340.000 0.522 0.7400.160 0.000 839.01.370.421 0.023 0.00 0.14 180.0 8/20/2024 12:54 0.0000.4360.035 0.000 0.3531.049 0.082 0.300 0.0000.0440.000 0.000 0.5900.000 0.000 839.00.710.183 0.028 0.44 0.14 180.0 8/20/2024 12:54 0.0000.2240.042 0.000 0.0001.174 0.063 0.318 0.0690.0080.000 0.178 0.5980.238 0.000 839.01.070.525 0.030 0.22 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 12:54 0.0000.0000.037 0.000 0.0000.982 0.029 0.561 0.0000.0000.000 0.018 0.4200.283 0.006 839.00.650.312 0.018 0.00 0.14 180.0 8/20/2024 12:55 0.0000.3950.039 0.000 0.6660.823 0.025 0.863 0.0000.0000.000 0.549 0.6720.548 0.000 839.01.650.914 0.028 0.40 0.15 180.0 8/20/2024 12:55 0.0000.0000.037 0.000 0.0000.898 0.048 0.572 0.0000.0000.000 0.273 0.5170.009 0.000 839.00.990.430 0.020 0.00 0.15 180.0 8/20/2024 12:55 0.0000.0000.032 0.000 0.0000.905 0.044 0.371 0.0000.1490.000 0.069 0.5280.000 0.000 839.00.910.497 0.020 0.00 0.14 180.0 8/20/2024 12:55 0.0000.0000.034 0.000 0.0000.709 0.058 0.483 0.0000.0010.000 0.109 0.1530.093 0.000 839.00.300.109 0.019 0.00 0.15 180.0 GAS, Inc. Performance Test Report Test Type: Initial Test Date: 8/20/2024 Caterpillar G3516H Lean Burn (4 Cycle) DOM: 1/21/23 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:01:14 PM 04:48 PM Source: Unit Number: SW700332 Serial Number: H6C00280 Engine Hours:3238.1 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Boston SWD 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 8.240 83.459 13.090 2.000 0.180 1.000 0.500 0.700 0.300 0.025 0.415 0.062 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results ppmvd Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Wheeler CAT 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Ethan Kinsey 3 Cooper Green Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit SW700332 with a serial number of H6C00280 which is a Caterpillar G3516H engine located at Boston SWD and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/20/2024 by Cooper Green with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 2763 brake horse power (BHP) at 1800 RPM. The engine was operating at 1934 BHP and 1799 RPM which is 70.00% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. 4 4.0 Test Summary Engine/Compressor Specs Boston SWDLocation SW700332Unit ID Make Caterpillar Site Elevation ft.5483 Model G3516H Atmospheric Pressure psi.12.11 Serial Number H6C00280 Stack Diameter in.18 mfg. rated hp 2763 Yes 1800 Date of Manufacture 1/21/2023 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1934 1934 1934 1934 1799 1799 1800 1799 Percent Load % Intake Manifold Pressure (hg) 70.00%70.00%70.00%70.00% 74.09 75.11 74.70 74.63 Intake Manifold Temperature (F)136.00 138.00 138.00 137.33 Ambient Conditions Ambient Temperature Dry (F)82.00 84.00 86.00 84.00 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 176033.29 177697.74 178826.10 177519.05 4984.66 5031.79 5063.74 5026.73 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.12 0.12 0.12 0.12 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %11.99%12.13%12.13%12.09% T e s t S u m m a r y mfg. rated rpm Test RPM 9.40%9.43%9.48%9.44% Permitted Standards Results 5 Catalyst 0.0260.024 Run 1 Run 2 Run 3 3 Run Average Pass Permits 01:14 PM 02:23 PM 03:33 PM 8/20/2024 CO (g/hp-hr)0.025 0.0252.000 0.180 Pass StateFederal CO (ppmvw)7.233 7.092 7.408 7.244 CO (ppmvd)8.218 8.071 8.431 8.240 CO (mol wt) 28.01 CO (ppmvd) @15% O2 4.217 4.150 4.356 4.241 Fail CO (ppbvd) @15% O2 4217.175 4150.002 4356.189 4241.122 Fail NOx (g/hp-hr)0.419 0.409 0.416 0.4151.000 0.500 Pass NOx (ppmvw)74.921 72.194 73.006 73.374 NOx (ppmvd)85.127 82.163 83.088 83.459 NOx (mol wt) 46.01 11.461 11.416 11.648 11.508NMNEHC (ppmvw) 13.022 12.992 13.256 13.090NMNEHC (ppmvd) NOx (ppbvd) @15% O2 43685.439 42248.498 42930.333 42954.757 Fail NOx (ppmvd) @15% O2 43.685 42.248 42.930 42.955 Fail NMNEHC (mol wt) 44.10 6682.757 6680.441 6849.178 6737.458 FailNMNEHC (ppbvd) @15% O2 0.062 0.062 0.064 0.0620.700 0.300 PassNMNEHC (g/hp-hr) 6.683 6.680 6.849 6.737 FailNMNEHC (ppmvd) @15% O2 Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.43Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 7.23 0.45 67.47 0.00 7.45 0.45 74.92 0.43 11.46 0.13% 8.30% 0.00% 11.99% NMNEHC 7.03 69.68 8.39 78.07 11.43 8.32%11.88% 43.91 71.68 6.36 78.03 30.45 8.09%11.25% 7.43 65.26 6.52 71.77 11.49 8.29%12.10% 0.00 0.00 0.00 0.00 0.44 0.25%0.06% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.44 0.25%0.06% 7.01 65.47 6.43 71.90 11.36 8.27%12.09% 50.93 79.99 4.99 84.98 33.72 8.20%11.15% 7.17 65.65 6.84 72.49 11.47 8.34%12.18% 0.00 0.00 0.00 0.00 0.59 0.38%0.08% Avg. Wet 7.09 65.56 6.63 72.19 11.42 8.31%12.13% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 7.12 65.79 6.61 72.39 11.47 8.30%12.14% 51.18 78.45 6.38 84.84 34.17 8.29%11.09% 7.70 66.61 7.01 73.62 11.83 8.42%12.13% 0.00 0.00 0.00 0.00 0.66 0.40%0.08% 0.00 0.00 0.00 0.00 0.59 0.38%0.08% Avg. Wet 7.41 66.20 6.81 73.01 11.65 8.36%12.13% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 18 inches or:1.5 feet. or:1.77 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.66 Yes 18.00 9.00 36.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 11.99 29.20 0.62 Inches 3.01 9 14.99 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.44 8.31 7.23 838.85 0.05 24.78 24.82 784.44 1244.11 418.02 27.86 89.30 157.80 200012.83 176033.29 Run 2 12.13 29.21 0.63 5.47 8.31 7.09 837.52 0.05 24.74 24.78 785.31 1244.98 418.51 27.85 90.49 159.91 202236.05 177697.74 Run 3 12.13 29.21 0.64 5.47 8.36 7.41 836.67 0.05 24.71 24.76 785.31 1244.98 418.51 27.85 91.16 161.09 203522.55 178826.10 12.09 29.21 0.63 5.46 8.33 7.24 837.68 0.05 24.74 24.79 785.02 1244.69 418.35 27.85 90.32 159.60 201930.85 177526.16 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.65 Exhaust Temp F 784.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.61 0.59 0.60 784.00 785.00 785.00 0.62 0.63 0.64 784.00 784.00 785.00 0.63 0.61 0.62 784.00 784.00 785.00 0.60 785.00 0.61 0.60 0.61 784.00 784.00 784.00 0.63 0.65 0.62 785.00 785.00 784.44 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.62 Exhaust Temp F 785.00 0.66 0.64 0.68 785.00 786.00 785.00 0.65 0.63 0.66 785.00 785.00 786.00 0.67 0.61 0.63 786.00 785.00 785.00 0.61 785.00 0.60 0.65 0.63 786.00 786.00 785.00 0.68 0.66 785.00 785.00 785.310.64 Run 2 Δpstd (in) H2O 0.64 Exhaust Temp F 785.00 0.60 0.63 0.67 785.00 786.00 785.00 0.62 0.65 0.66 785.00 785.00 786.00 0.61 0.60 0.63 785.00 785.00 785.00 0.62 786.00 0.65 0.68 0.64 786.00 785.00 785.00 0.63 0.61 785.00 786.00 0.63 785.31 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.054)+.32(.094)+.28(.851+.001) = 29.202 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.202(1 -.11989)+.18.0(.11989) = 27.859 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.62*√(1244.1075/(24.82*27.859)) = 89.3 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.12)89.297*1.767((528*24.82)/ (1244.1075*29.92)) = 176033.29 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 176033.293/35.315 = 4984.661 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 8.218*(20.9-15)/(20.9-9.4%)) = 4.216 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (8.218*(1.164*10^-3)*4984.661*(Run Time/60))/1934.1 = .025 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .025*1/453.6*1934.1 = .105 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .105*4.38 = .46 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 8.22 = 7.2325*(1/(1-.12))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.76% 20.75% 10.66% 10.94% 10.76% 10.76% 10.94%10.66% 10.76% 20.75% 10.76% 20.98% 10.76% 20.98% 10.76%20.98% 0.00% 10.76% 20.98% 0.00% 0.23% 0.01% 1.08% 10.76% Span Zero Offset 0.00% 20.98 0.00% 10.76%0.49%0.84%0.01% 9.44% 9.46% 9.52% 9.40% 9.43% 9.48% 9 Gas, Inc. 0.0 0.0 0.0 0.0 0.0 0.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Boston SWD 8/20/2024 5483 SW700332 Caterpillar Model Serial Number G3516H H6C00280 Technician Cooper Green Run Start Times 01:14 PM 02:23 PM 03:33 PM 04:48 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1799.0 1799.0 1800.0 1799.3 Engine Hours 3235.1 3236.1 3237.1 3238.1 Intake Manifold Pressure (psi)48.5 49.0 48.8 48.8 Intake Manifold Temp °F 136.0 138.0 138.0 137.3 Engine Load (BHP)1934.1 1934.1 1934.1 1934.1 Ambient Temp °F 82.0 84.0 86.0 84.0 Humidity %33.0 30.0 28.0 30.3 Dew Point °F 50.0 49.0 50.0 49.7 Caterpillar Yes 1 1 1 1# of Catalyst Installed Catalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 0.0 0.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.03 R e s u l t s Average:Nitrogen monoxide NO 0.10 Average:Nitrogen dioxide NO2 0.11 Average:NOx 0.21 Average:VOC 0.16 Average:Oxygen 0.13 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.00 Tolerance 2.00% Difference between measured and expected 1.00% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.22 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.73 Average:Oxygen 0.13 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 97.40 Tolerance 5.00% Difference between measured and expected 2.60% Pre-test System CTS & Mechanical Response Time 45 secondsEquilibration Response Time Value:Spike Reported 259.36 Value:Spike Expected 258.20 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC511346 4/24/2027 98.96 10.76% CC706226 4/24/2032 100.00 CC185396 6/17/2032 20.98% Cylinder # CC102850 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 258.20 502.80 243.30 10.14 Analyzer System Response 259.36 502.80 250.57 10.00 Percent Difference 0.45%0.00%2.99%1.35% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 98.996 4.950 Spike Direct Propane 259.754 Mechanical Response Time SF6 10.044 CO 503.508 NO 245.633 Ethylene 97.397 18 seconds Analyzer Response Propane 259.358 SF6 10.003 CO 502.796 NO 250.565 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 258.333 CO 498.325 NO 253.648 12 seconds 26 seconds 7.02% 8.20% 8.43% 99.85% 99.69% 99.97% 9.979 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%3.006 50%9.000 83.3%14.994 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 18 9 36 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 177526.16 H2O%d @ Sampling Point:12.09 CO2%d @ Sampling Point:5.46 Pressure @ Sampling Point (Pg "H2O):0.63 Temperature @ Sampling Point (Deg F):785.02 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99 4.95 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 98.996 4.950 Spike Direct Propane 259.754 Mechanical Response Time SF6 10.044 CO 503.508 NO 245.633 Ethylene 97.397 18 seconds Analyzer Response Propane 259.358 SF6 10.003 CO 502.796 NO 250.565 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 258.333 CO 498.325 NO 253.648 12 seconds 26 seconds 7.02% 8.20% 8.43% 99.85% 99.69% 99.97% 9.979 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 258.200 10.140 502.800 243.300 259.754 10.044 503.508 245.633 0.60% 0.95% 0.14% 0.96% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 5.448 0.000 Spike Average 23.156 0.705 Dilution Factor 7.019% Expected 23.191 % Recovery 99.850% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.824 Dilution Factor 8.204% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.847 Dilution Factor 8.433% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 5.529 26.820 26.829 99.970% 0.001267 0.000957 0.000954 5.590 26.222 26.304 99.690% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass1.59% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:15.6075719 Pass Line Position Difference:Resolution Difference to Reference 1.59% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 101.33 1.31% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Boston SWD; SW700332; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/20/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/20/2024 Cooper Green Gas, Inc. Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. 21% O2 Tri Probe Certification Great Plains Analytical Services 303 W 3rd St Elk City, OK, 73644 (580)225-0403 Fax: (580)225-2612 CERTIFICATE OF ANALYSIS Grade of Product: CERTIFIED STANDARD-PROBE Part Number: 18L Reference Number: 3 Laboratory: GAS INC. Stack Diameter: 18” Analysis Date: Dec. 3, 2021 Target Flow Rate: 3L/min LOT Number: SN: A 3A 18L Number of Points: 3 Product performance verified by direct comparison to calibration standards traceable to N.I.S.T. *The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e, section 8.4 as shown in the accompanying data. Method 7e, section 8.4 states that the multipoint traverse requirement can be satisfied by sampling via “a multi-hole probe designed to sample at the prescribed points with a flow +/- 10 percent of mean flow rate”. ANALYTICAL RESULTS !"#$%$&'()*$+*',$ -./01 $ 23)4"536$+*',$ 7'5($8 $-./01$ -93*()$:;1$ 23)4"536$+*',$ 7'5($<$-./01$ -93*()$:=1$ 23)4"536$+*',$ 7'5($>$-./01 $ -93*()$:?1$ Mean Probe Port Sampled Flow (L/m)$ $ Run 1 2 LPM .660 (5.88D) .620 (-0.53D) .590 (-5.35D) .623 Run 2 4 LPM 1.29 (3.20D) 1.26 (0.80D) 1.20 (-4.00D) 1.250 *Calibration conducted in accordance with Emission Measurement Center Guideline Document – EMC GD-031 Notes: ___________________________________________________ _________________________ Approved for Release Date 12-3-21 Probe size: 18 L Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Cooper Green GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Boston SWD Unit Number:SW700332 Make:Caterpillar Location:G3516HModel: H6C00280Serial Number: RAW Result Data Stability 8/20/2024 05:27 1.9560.0001.472 5.544 18.9310.000 0.000 0.000 6.1110.0180.000 0.000 0.0000.072 2.758 837.05.520.000 0.000 1.96 18.13 179.0 Pre Test Baseline Direct 8/20/2024 05:36 0.0000.105-0.016 0.000 0.0000.054 0.000 0.145 0.0000.0000.000 0.028 0.0000.043 0.000 837.00.180.245 0.002 0.10 0.14 181.0 8/20/2024 05:36 0.3420.097-0.016 0.000 0.0000.035 0.000 0.025 0.0000.0000.000 0.000 0.0000.117 0.000 837.00.100.153 0.004 0.44 0.13 181.0 8/20/2024 05:37 0.0000.090-0.014 0.000 0.0000.000 0.008 0.158 0.0000.0000.000 0.215 0.0000.081 0.000 837.00.200.089 0.003 0.09 0.13 181.0 CTS Direct 8/20/2024 05:41 0.0000.287-0.002 0.000 0.0000.415 0.064 0.123 0.0000.0000.000 99.644 0.0000.163 0.000 837.066.480.070 0.000 0.29 0.17 181.0 8/20/2024 05:42 0.0000.022-0.002 0.000 0.0000.558 0.021 0.145 0.0000.0150.000 98.667 0.0000.000 0.000 837.065.870.138 0.007 0.02 0.16 181.0 8/20/2024 05:42 0.0000.181-0.004 0.000 0.0000.622 0.038 0.041 0.0000.0160.000 98.676 0.0000.129 0.000 837.065.870.120 0.009 0.18 0.57 180.0 High O2 Direct 8/20/2024 05:52 0.0000.000-0.019 0.000 0.0000.056 0.004 0.000 0.0000.0000.000 0.127 0.0000.173 0.000 837.00.250.255 0.006 0.00 20.71 180.0 8/20/2024 05:52 0.0000.000-0.023 0.000 0.0000.053 0.000 0.000 0.0000.0000.000 0.000 0.0000.203 0.000 837.00.090.138 0.008 0.00 20.73 180.0 8/20/2024 05:53 0.1750.000-0.018 0.000 0.0000.106 0.000 0.027 0.0000.0000.000 0.247 0.0000.287 0.000 837.00.270.161 0.001 0.18 20.82 180.0 NO2/Mid O2 Direct 8/20/2024 06:02 98.5560.342-0.020 0.000 0.6820.046 0.394 0.000 0.2780.0000.000 0.000 0.0000.155 0.000 837.00.000.000 0.006 98.90 10.77 180.0 8/20/2024 06:02 99.4130.422-0.023 0.000 0.5440.070 0.376 0.000 0.2930.0000.000 0.000 0.0000.208 0.000 837.00.050.068 0.001 99.83 10.77 180.0 8/20/2024 06:03 99.1900.628-0.022 0.000 0.0000.046 0.371 0.000 0.5650.0000.000 0.000 0.0000.091 0.000 837.00.000.000 0.006 99.82 10.75 180.0 Spike Direct 8/20/2024 06:07 3.192245.229-0.020 4.682 5.911503.141 1.345 2.217 7.8370.0701.308 1.467 259.5820.204 0.000 837.0262.212.470 10.029 248.42 0.14 180.0 8/20/2024 06:08 2.839245.408-0.015 4.668 5.106504.111 1.338 1.843 7.4650.2350.603 1.367 259.9410.000 0.000 837.0262.141.930 10.061 248.25 0.14 180.0 8/20/2024 06:08 2.608246.261-0.012 4.689 5.839503.272 1.311 1.702 8.0980.2370.000 1.446 259.7380.147 0.000 837.0262.462.640 10.042 248.87 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/20/2024 06:10 0.0000.0000.024 0.000 0.0000.244 0.003 1.819 0.0000.0090.102 0.465 0.1580.000 0.224 837.00.920.000 0.006 0.00 0.13 180.0 8/20/2024 06:10 0.0000.0000.013 0.000 0.0000.226 0.004 1.784 0.0000.0130.000 0.212 0.3010.362 0.152 837.00.750.000 0.002 0.00 0.13 180.0 8/20/2024 06:11 0.0000.0000.020 0.000 0.0000.180 0.006 1.571 0.0000.0080.000 0.231 0.0320.000 0.154 837.00.520.040 0.005 0.00 0.13 180.0 CTS System with Response Time 8/20/2024 06:13 0.0000.1130.027 0.000 0.0000.050 0.015 1.365 0.0000.0000.000 97.461 0.0000.020 0.136 837.065.290.057 0.006 0.11 0.18 180.0 8/20/2024 06:13 0.0000.1260.023 0.003 0.0000.116 0.000 1.217 0.0000.0030.000 97.323 0.0000.000 0.122 837.065.130.000 0.010 0.13 0.18 180.0 8/20/2024 06:13 0.0000.0000.021 0.000 0.0000.095 0.008 1.279 0.0000.0000.000 97.407 0.0000.000 0.128 837.065.200.000 0.006 0.00 0.18 180.0 NO2/Mid O2 System with Response Time 8/20/2024 06:15 95.7321.9000.009 0.000 0.0000.237 0.366 1.030 0.0000.0010.000 0.325 0.0000.408 0.098 838.00.490.111 0.003 97.63 10.57 180.0 8/20/2024 06:16 96.2291.6860.008 0.000 0.0000.143 0.371 0.815 0.0000.0000.000 0.000 0.0000.061 0.125 838.00.320.105 0.009 97.92 10.66 180.0 8/20/2024 06:16 96.1591.6530.010 0.000 0.2600.111 0.375 0.802 0.0000.0000.000 0.177 0.0000.339 0.114 839.00.350.000 0.007 97.81 10.75 180.0 Spike System with Response Time 8/20/2024 06:19 0.000250.2420.007 4.646 3.786502.655 1.305 2.303 6.7120.0551.156 1.462 259.4250.109 0.000 840.0262.102.547 9.999 250.24 0.14 180.0 8/20/2024 06:19 0.000250.6060.004 4.667 3.255503.226 1.248 2.314 5.8440.0062.273 1.492 259.2340.000 0.000 840.0261.922.541 10.002 250.61 0.14 180.0 8/20/2024 06:19 0.000250.8460.005 4.652 2.867502.507 1.268 2.654 5.8750.0771.240 1.419 259.4150.000 0.000 840.0262.182.727 10.008 250.85 0.14 180.0 Baseline System with Response Time 8/20/2024 06:23 0.0000.6460.004 0.000 0.0000.584 0.037 0.659 0.0000.0000.000 0.000 0.4180.000 0.000 840.00.420.000 0.017 0.65 0.13 180.0 8/20/2024 06:23 0.0000.3180.001 0.000 0.0000.348 0.021 0.848 0.0000.0000.000 0.171 0.3500.289 0.000 840.00.510.067 0.015 0.32 0.13 180.0 8/20/2024 06:23 0.0000.3940.002 0.000 0.0000.349 0.040 0.846 0.0000.0190.000 0.008 0.3310.295 0.000 840.00.350.014 0.014 0.39 0.14 180.0 Run 1 - A 30minute/60min 8/20/2024 13:14 18.20660.7388.941 4.205 372.8654.215 0.000 7.007 47.8220.1551.968 1.547 3.8730.222 0.543 839.06.200.310 0.000 78.94 7.71 180.0 8/20/2024 13:15 6.63167.67111.924 5.367 612.2997.016 0.000 0.515 37.8310.0007.306 3.281 5.7250.000 1.393 839.011.851.733 0.000 74.30 8.20 180.0 8/20/2024 13:16 7.67168.20411.938 5.402 617.5446.972 0.000 0.257 37.0180.0008.098 3.483 5.7250.000 1.398 839.012.192.015 0.000 75.87 8.17 180.0 8/20/2024 13:17 7.26665.45611.940 5.421 617.5297.127 0.000 0.228 37.7510.0008.173 3.495 5.6600.000 1.394 839.012.061.919 0.000 72.72 8.16 180.0 8/20/2024 13:18 8.36970.69511.988 5.441 613.0097.357 0.000 0.117 38.9600.0017.893 3.295 5.7600.000 1.126 839.011.341.691 0.000 79.06 8.25 180.0 8/20/2024 13:19 7.44769.53812.026 5.444 612.5977.133 0.000 0.000 37.6010.0008.991 3.448 5.4960.000 1.326 839.011.641.793 0.000 76.99 8.33 180.0 8/20/2024 13:20 8.63873.47912.028 5.463 616.2717.212 0.000 0.004 36.1550.0007.787 3.416 5.5480.000 1.381 839.011.821.852 0.000 82.12 8.33 180.0 8/20/2024 13:21 8.27669.33012.048 5.447 617.0267.076 0.000 0.097 37.6890.0007.846 3.432 5.6410.000 1.346 839.011.841.834 0.001 77.61 8.21 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 13:23 7.61569.08812.025 5.458 618.3527.057 0.000 0.051 37.9940.0007.862 3.644 5.5440.000 1.292 839.011.761.809 0.001 76.70 8.33 180.0 8/20/2024 13:24 9.34572.36212.051 5.446 616.4747.173 0.000 0.148 36.9620.0008.065 3.529 5.4680.000 1.319 839.011.711.872 0.000 81.71 8.34 180.0 8/20/2024 13:25 8.46470.97312.036 5.463 618.6607.313 0.000 0.070 37.9350.0007.987 3.530 5.3800.000 1.311 839.011.521.752 0.000 79.44 8.43 180.0 8/20/2024 13:26 8.96973.46812.014 5.461 618.6977.055 0.000 0.007 37.7100.0008.032 3.628 5.3770.000 1.344 839.011.631.718 0.000 82.44 8.44 180.0 8/20/2024 13:27 8.04870.46312.001 5.455 620.1847.156 0.000 0.000 38.7290.0009.110 3.341 5.6370.000 1.118 839.011.231.699 0.000 78.51 8.34 180.0 8/20/2024 13:28 8.46271.28011.997 5.449 617.4267.113 0.000 0.000 37.8160.0008.696 3.373 5.3430.000 1.337 839.011.471.809 0.000 79.74 8.25 180.0 8/20/2024 13:29 7.34169.33011.968 5.457 618.8247.249 0.000 0.000 38.5890.0008.963 3.606 5.6580.000 1.140 839.011.481.708 0.000 76.67 8.35 180.0 8/20/2024 13:30 8.14171.57511.972 5.458 615.6387.017 0.000 0.000 37.2060.0009.434 3.465 5.5110.000 1.275 839.011.541.749 0.000 79.72 8.45 180.0 8/20/2024 13:31 9.16373.34211.978 5.452 616.1217.136 0.000 0.000 37.3410.0008.796 3.415 5.3920.000 1.309 839.011.451.737 0.000 82.50 8.54 180.0 8/20/2024 13:32 8.82571.59311.936 5.463 618.3887.136 0.000 0.000 37.7850.0009.378 3.399 5.3720.000 1.310 839.011.461.806 0.000 80.42 8.44 180.0 8/20/2024 13:33 8.97771.19711.936 5.460 617.8617.208 0.000 0.000 37.8700.0008.897 3.614 5.4950.000 1.293 839.011.791.945 0.000 80.17 8.44 180.0 8/20/2024 13:34 9.26672.89811.917 5.472 617.8757.202 0.000 0.000 37.8400.0008.972 3.478 5.4360.000 1.301 839.011.611.887 0.000 82.16 8.45 180.0 8/20/2024 13:35 8.62871.24811.925 5.460 619.4917.127 0.000 0.000 37.9370.0009.277 3.528 5.4580.000 1.309 839.011.491.594 0.000 79.88 8.35 180.0 8/20/2024 13:36 8.13670.21111.937 5.472 619.3097.149 0.000 0.000 38.1140.0008.801 3.524 5.4650.000 1.318 839.011.671.831 0.000 78.35 8.45 180.0 8/20/2024 13:37 7.98469.53411.954 5.456 618.7627.145 0.000 0.000 37.9950.0009.293 3.741 5.4120.000 1.312 839.011.811.919 0.000 77.52 8.37 180.0 8/20/2024 13:38 8.24469.56011.952 5.455 618.7547.201 0.000 0.000 37.9000.0008.859 3.386 5.4120.000 1.307 839.011.431.721 0.000 77.80 8.36 180.0 8/20/2024 13:39 8.14770.16711.942 5.464 614.7687.039 0.000 0.000 36.8190.0009.094 3.534 5.5670.000 1.298 839.011.761.865 0.001 78.31 8.46 180.0 8/20/2024 13:40 7.89671.87511.991 5.471 616.3737.006 0.000 0.000 37.1920.0008.906 3.694 5.3430.000 1.309 839.011.541.671 0.000 79.77 8.34 180.0 8/20/2024 13:41 6.56865.38111.977 5.460 617.0257.268 0.000 0.000 38.5120.0009.177 3.638 5.5550.000 1.167 839.011.271.439 0.000 71.95 8.27 180.0 8/20/2024 13:42 7.58767.77311.987 5.467 616.4667.007 0.000 0.000 37.5830.0008.860 3.586 5.3490.000 1.314 839.011.621.883 0.000 75.36 8.33 180.0 8/20/2024 13:43 7.26767.12111.989 5.460 620.8357.020 0.000 0.000 38.1460.0008.851 3.465 5.3580.000 1.317 839.011.591.933 0.000 74.39 8.35 180.0 8/20/2024 13:44 6.05264.87012.087 5.429 624.3697.042 0.000 0.000 39.9070.0008.910 3.570 5.4700.000 1.141 839.011.171.561 0.001 70.92 8.26 180.0 8.38869.68111.880 5.409 609.3267.031 0.000 0.283 38.1570.0058.409 3.436 5.4480.007 1.268 839.0011.4311.735 0.000 78.068 8.323 180.0Avg. Spike 1 8/20/2024 13:46 6.35871.67511.245 5.304 587.47043.906 0.000 0.895 33.5410.0005.752 4.754 23.1560.000 1.374 839.030.452.072 0.705 78.03 8.09 180.0 Run 1 - B 30minute/60min 8/20/2024 13:48 6.64269.77911.853 5.431 611.00718.375 0.000 0.150 36.8970.0007.182 3.972 11.0470.000 1.333 839.017.391.539 0.222 76.42 8.21 180.0 8/20/2024 13:49 6.89364.21012.174 5.466 620.7747.186 0.000 0.000 39.1760.0008.947 3.575 5.7360.000 1.115 839.011.481.690 0.000 71.10 8.24 180.0 8/20/2024 13:51 7.37264.55312.108 5.461 616.8347.014 0.000 0.000 37.9750.0009.470 3.606 5.4440.000 1.306 839.011.761.953 0.000 71.92 8.26 180.0 8/20/2024 13:52 5.97764.22412.090 5.458 617.6776.985 0.000 0.000 38.7630.0008.966 3.884 5.6130.000 1.152 839.011.561.578 0.001 70.20 8.21 180.0 8/20/2024 13:53 6.30466.03112.127 5.477 618.0567.040 0.000 0.000 38.5950.0009.638 3.667 5.6640.000 1.115 839.011.491.727 0.001 72.33 8.33 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 13:54 6.31463.37312.108 5.472 620.2037.169 0.000 0.000 39.1810.0009.631 3.678 5.6640.000 1.070 839.011.521.891 0.000 69.69 8.14 180.0 8/20/2024 13:55 6.37466.57812.133 5.482 620.5357.189 0.000 0.000 37.9720.0009.384 3.488 5.3560.000 1.306 839.011.591.940 0.000 72.95 8.23 180.0 8/20/2024 13:56 6.50165.67812.085 5.454 620.8057.111 0.000 0.000 38.7760.0009.539 3.491 5.5500.000 1.105 839.011.041.428 0.000 72.18 8.24 180.0 8/20/2024 13:57 6.06065.40712.091 5.465 620.6946.898 0.000 0.000 39.0790.0009.133 3.636 5.5770.000 1.087 839.011.211.554 0.000 71.47 8.34 180.0 8/20/2024 13:58 6.47265.98012.110 5.453 620.3686.841 0.000 0.000 38.8060.0009.556 3.568 5.5800.000 1.080 839.011.211.637 0.000 72.45 8.36 180.0 8/20/2024 13:59 5.78563.98912.099 5.471 621.7646.925 0.000 0.000 39.2310.0009.173 3.746 5.6400.000 1.066 839.011.391.687 0.000 69.77 8.15 180.0 8/20/2024 14:00 5.79963.10912.064 5.452 622.6557.304 0.000 0.000 39.5650.0009.438 3.667 5.6350.000 1.088 839.010.900.961 0.000 68.91 8.34 180.0 8/20/2024 14:01 6.48565.96812.096 5.443 623.0547.009 0.000 0.000 39.3310.0009.481 3.637 5.6280.000 1.081 839.011.291.616 0.000 72.45 8.16 180.0 8/20/2024 14:02 5.92561.72212.134 5.453 626.0257.055 0.000 0.000 40.4010.0009.417 3.604 5.6850.000 1.055 839.011.311.663 0.000 67.65 8.16 180.0 8/20/2024 14:03 6.86665.43712.125 5.471 620.8947.095 0.000 0.000 38.8610.0009.627 3.606 5.7090.000 1.066 839.011.351.659 0.000 72.30 8.35 180.0 8/20/2024 14:04 6.26864.95812.094 5.458 622.2396.987 0.000 0.000 38.8530.0009.462 3.680 5.5890.000 1.070 839.011.321.705 0.001 71.23 8.25 180.0 8/20/2024 14:05 5.10263.21512.118 5.458 622.9976.929 0.000 0.000 39.2090.0009.459 3.720 5.5660.000 1.083 839.011.041.235 0.000 68.32 8.22 180.0 8/20/2024 14:06 5.97162.80612.104 5.460 621.8886.875 0.000 0.000 39.0560.0009.176 3.563 5.5950.000 1.101 839.010.901.088 0.000 68.78 8.33 180.0 8/20/2024 14:07 5.84664.57012.086 5.467 622.2626.863 0.000 0.000 38.9160.0009.409 3.636 5.6070.000 1.078 839.011.021.248 0.000 70.42 8.33 180.0 8/20/2024 14:08 7.74065.95612.122 5.465 621.5236.926 0.000 0.000 38.5090.0009.174 3.650 5.5860.000 1.099 839.011.291.615 0.000 73.70 8.36 180.0 8/20/2024 14:09 6.56465.06112.136 5.476 624.3197.243 0.000 0.000 39.3070.0009.289 3.464 5.5370.000 1.047 839.011.111.757 0.000 71.63 8.25 180.0 8/20/2024 14:10 6.26263.23812.133 5.464 626.0467.064 0.000 0.000 39.4050.0009.687 3.555 5.6650.000 1.045 838.011.181.577 0.000 69.50 8.25 180.0 8/20/2024 14:11 6.33963.87712.090 5.461 623.1997.129 0.000 0.001 39.1440.0007.906 3.547 5.6070.000 1.087 838.011.001.282 0.000 70.22 8.34 180.0 8/20/2024 14:12 6.05763.93412.111 5.460 622.3477.188 0.000 0.000 38.6020.0009.364 3.567 5.5170.000 1.090 838.011.131.576 0.000 69.99 8.29 180.0 8/20/2024 14:13 7.19965.63312.110 5.465 619.2417.123 0.000 0.000 37.3420.0009.276 3.588 5.3650.000 1.299 838.011.481.683 0.000 72.83 8.44 180.0 8/20/2024 14:14 7.79868.08012.081 5.471 622.3587.034 0.000 0.000 37.8310.0009.141 3.602 5.3800.000 1.306 838.011.431.547 0.000 75.88 8.44 180.0 8/20/2024 14:15 7.96369.72512.090 5.479 620.8957.010 0.000 0.000 37.8810.0009.293 3.665 5.3360.000 1.257 838.011.541.872 0.000 77.69 8.45 180.0 8/20/2024 14:16 7.17069.17612.097 5.479 620.3387.197 0.000 0.007 38.6630.0007.936 3.631 5.5820.000 1.107 838.011.211.493 0.000 76.35 8.33 180.0 8/20/2024 14:17 6.98566.41712.092 5.474 620.7977.146 0.000 0.000 39.2650.0009.174 3.630 5.5860.000 1.084 838.011.321.723 0.000 73.40 8.34 180.0 8/20/2024 14:18 6.53764.95412.071 5.474 620.0507.110 0.000 0.000 39.4750.0009.560 3.655 5.6070.000 1.097 838.011.281.565 0.000 71.49 8.36 180.0 6.51965.25512.098 5.464 621.0617.434 0.000 0.005 38.8020.0009.196 3.633 5.7550.000 1.129 838.7011.4911.583 0.008 71.774 8.290 180.0Avg. 7.45367.46811.989 5.437 615.1947.232 0.000 0.144 38.4800.0038.803 3.534 5.6010.004 1.199 838.8511.4611.659 0.004 74.921 8.307 180.0Run 1 Avg: Baseline 1 8/20/2024 14:21 0.0000.0000.064 0.000 1.3810.000 0.017 0.449 0.0860.0070.000 0.150 0.2300.000 0.000 838.00.440.159 0.006 0.00 0.25 180.0 Run 2 - A 30minute/60min 8/20/2024 14:23 4.10163.58111.365 5.117 589.3075.403 0.000 0.959 34.5040.0006.273 3.329 5.5870.000 1.326 838.011.521.599 0.000 67.68 7.62 180.0 8/20/2024 14:24 6.74065.15612.039 5.442 617.4977.115 0.000 0.191 38.1410.0008.019 3.614 5.4880.000 1.248 838.011.511.682 0.000 71.90 8.12 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 14:25 6.58865.69012.060 5.440 616.1107.119 0.000 0.000 37.6100.0009.402 3.435 5.5670.000 1.259 838.011.561.779 0.002 72.28 8.22 180.0 8/20/2024 14:27 6.51265.73712.088 5.451 618.4066.969 0.000 0.000 38.1920.0009.285 3.610 5.5750.000 1.188 838.011.201.269 0.000 72.25 8.25 180.0 8/20/2024 14:28 5.87964.15412.105 5.473 619.4226.996 0.000 0.008 39.1010.0008.099 3.576 5.8070.000 1.056 838.011.341.549 0.000 70.03 8.23 180.0 8/20/2024 14:29 5.67964.17912.099 5.477 617.2117.233 0.000 0.012 38.8210.0008.341 3.545 5.6530.000 1.073 838.011.251.628 0.000 69.86 8.25 180.0 8/20/2024 14:30 7.23465.10112.069 5.469 619.0597.202 0.000 0.000 38.1460.0009.258 3.497 5.5040.000 1.282 838.011.601.807 0.000 72.33 8.35 180.0 8/20/2024 14:31 6.23665.95912.093 5.485 616.0677.058 0.000 0.000 37.6920.0009.432 3.528 5.3140.000 1.279 838.011.241.517 0.000 72.20 8.27 180.0 8/20/2024 14:32 6.36665.39512.118 5.475 620.2647.274 0.000 0.000 39.1730.0009.180 3.585 5.7820.000 1.058 838.011.341.571 0.000 71.76 8.22 180.0 8/20/2024 14:33 5.79063.93212.149 5.479 618.5066.966 0.000 0.000 38.9810.0009.715 3.538 5.6710.000 1.075 838.011.301.679 0.000 69.72 8.27 180.0 8/20/2024 14:34 7.21466.05312.120 5.482 616.8127.023 0.000 0.000 37.6320.0009.680 3.636 5.5390.000 1.305 838.011.721.719 0.000 73.27 8.47 180.0 8/20/2024 14:35 7.77371.04812.126 5.482 617.8497.120 0.000 0.023 37.4350.0008.198 3.541 5.4170.000 1.283 838.011.521.767 0.001 78.82 8.35 180.0 8/20/2024 14:36 7.29069.71112.115 5.494 620.2337.234 0.000 0.000 38.6510.0009.590 3.481 5.7450.000 1.068 838.011.241.552 0.001 77.00 8.44 180.0 8/20/2024 14:37 6.03864.89712.107 5.489 620.2547.004 0.000 0.000 39.1580.0009.212 3.518 5.6070.000 1.076 838.011.201.639 0.000 70.94 8.27 180.0 8/20/2024 14:38 6.32365.36112.122 5.494 619.3787.161 0.000 0.000 39.0930.0009.350 3.493 5.6270.000 1.117 838.011.201.511 0.000 71.68 8.31 180.0 8/20/2024 14:39 6.78965.85112.094 5.482 618.0726.978 0.000 0.000 38.8120.0009.073 3.595 5.7110.000 1.126 838.011.401.561 0.000 72.64 8.37 180.0 8/20/2024 14:40 5.90365.36912.108 5.479 617.6497.003 0.000 0.002 38.8360.0007.935 3.587 5.6950.000 1.065 838.011.351.698 0.000 71.27 8.34 180.0 8/20/2024 14:41 6.26063.60512.123 5.470 620.1497.121 0.000 0.014 39.4780.0007.985 3.626 5.5870.000 1.109 838.011.371.723 0.000 69.86 8.24 180.0 8/20/2024 14:42 5.85763.37012.132 5.466 621.0347.032 0.000 0.000 39.5200.0009.415 3.749 5.7060.000 1.067 838.011.401.591 0.000 69.23 8.34 180.0 8/20/2024 14:43 6.32366.21412.136 5.468 618.5897.060 0.000 0.000 38.7990.0009.365 3.880 5.5910.000 1.112 838.011.531.693 0.000 72.54 8.34 180.0 8/20/2024 14:44 6.37766.02112.117 5.477 617.1887.220 0.000 0.000 38.6120.0009.504 3.558 5.6590.000 1.068 838.011.171.509 0.000 72.40 8.34 180.0 8/20/2024 14:45 7.02167.16312.146 5.476 619.5937.237 0.000 0.000 38.6350.0008.838 3.647 5.5620.000 1.111 838.011.181.451 0.000 74.18 8.27 180.0 8/20/2024 14:46 6.47165.21512.120 5.472 620.0417.288 0.000 0.000 39.1500.0009.153 3.635 5.5680.000 1.119 838.011.251.532 0.003 71.69 8.36 180.0 8/20/2024 14:47 6.48664.85312.134 5.477 620.5106.907 0.000 0.058 38.9690.0007.952 3.705 5.6200.000 1.073 838.011.301.599 0.000 71.34 8.24 180.0 8/20/2024 14:48 5.43962.87612.170 5.467 619.3116.916 0.000 0.000 39.1080.0009.523 3.494 5.6400.000 1.058 838.010.951.301 0.000 68.31 8.22 180.0 8/20/2024 14:49 5.35563.07612.150 5.474 620.3677.032 0.000 0.011 39.0900.0008.221 3.644 5.7130.000 1.078 838.011.241.415 0.000 68.43 8.37 180.0 8/20/2024 14:50 7.25867.26812.109 5.486 618.8586.785 0.000 0.000 37.6040.0009.092 3.522 5.4390.000 1.248 838.011.501.822 0.000 74.53 8.36 180.0 8/20/2024 14:51 7.16565.63612.117 5.489 617.1556.828 0.000 0.000 37.8510.0009.431 3.508 5.4160.000 1.261 838.011.481.802 0.000 72.80 8.26 180.0 8/20/2024 14:52 7.49065.65512.114 5.485 619.0687.079 0.000 0.000 38.0480.0009.491 3.680 5.5090.000 1.265 838.011.791.952 0.000 73.14 8.35 180.0 8/20/2024 14:53 6.97866.00612.141 5.470 619.0597.032 0.000 0.000 37.9040.0009.454 3.352 5.4130.000 1.257 838.011.191.544 0.000 72.98 8.33 180.0 6.43165.47112.090 5.463 617.7677.013 0.000 0.043 38.4250.0008.916 3.570 5.5900.000 1.157 838.0011.3611.615 0.000 71.902 8.279 180.0Avg. Spike 2 8/20/2024 14:57 4.99279.98811.146 5.374 576.85850.927 0.000 0.497 31.4370.0005.565 5.285 26.2220.000 1.387 838.033.721.799 0.824 84.98 8.20 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/20/2024 14:59 7.57068.64712.085 5.486 617.2647.408 0.000 0.055 37.7620.0008.244 3.788 5.7070.000 1.246 838.011.941.819 0.003 76.22 8.33 180.0 8/20/2024 15:00 6.45066.55412.118 5.485 619.2847.114 0.000 0.084 38.7500.0008.164 3.761 5.6280.000 1.076 837.011.471.774 0.000 73.00 8.35 180.0 8/20/2024 15:01 6.09764.91812.129 5.483 620.0747.416 0.000 0.018 38.9680.0008.046 3.621 5.6390.000 1.123 837.011.261.443 0.002 71.01 8.43 180.0 8/20/2024 15:02 7.78966.95412.139 5.463 621.0696.996 0.000 0.000 37.9890.0009.402 3.563 5.5680.000 1.246 837.011.541.655 0.001 74.74 8.43 180.0 8/20/2024 15:04 6.34566.29312.138 5.489 620.4237.137 0.000 0.000 38.7520.0009.334 3.493 5.6400.000 1.077 837.011.191.598 0.000 72.64 8.36 180.0 8/20/2024 15:05 6.16564.64512.154 5.492 620.9477.073 0.000 0.000 39.0420.0009.354 3.639 5.6170.000 1.053 837.011.321.751 0.000 70.81 8.34 180.0 8/20/2024 15:06 6.85665.18412.141 5.499 620.4277.030 0.000 0.068 38.2230.0007.855 3.593 5.4810.000 1.230 837.011.581.871 0.000 72.04 8.34 180.0 8/20/2024 15:07 7.39266.64212.128 5.489 619.3017.200 0.000 0.000 37.8200.0009.083 3.586 5.4490.000 1.321 837.011.611.695 0.000 74.03 8.37 180.0 8/20/2024 15:08 6.63665.96812.130 5.467 619.3797.139 0.000 0.000 38.8250.0008.893 3.554 5.5880.000 1.101 837.011.261.655 0.002 72.60 8.37 180.0 8/20/2024 15:09 6.63365.39212.151 5.476 617.8147.092 0.000 0.000 38.6820.0009.524 3.509 5.7000.000 1.093 837.011.411.772 0.000 72.02 8.43 180.0 8/20/2024 15:10 7.80765.04212.128 5.473 618.5367.090 0.000 0.000 38.0880.0009.249 3.826 5.6920.000 1.208 837.011.861.799 0.002 72.85 8.34 180.0 8/20/2024 15:11 7.07265.11712.117 5.473 619.4017.275 0.000 0.000 38.0310.0008.954 3.789 5.5350.000 1.260 837.011.891.962 0.000 72.19 8.43 180.0 8/20/2024 15:12 6.69964.61712.179 5.480 619.4676.996 0.000 0.000 38.1080.0009.470 3.574 5.5040.000 1.263 837.011.551.709 0.000 71.32 8.24 180.0 8/20/2024 15:13 5.47564.54812.189 5.487 618.2167.166 0.000 0.012 38.8410.0008.036 3.627 5.6670.000 1.078 837.011.151.359 0.000 70.02 8.26 180.0 8/20/2024 15:14 6.90364.80112.137 5.479 617.4796.886 0.000 0.000 38.1280.0009.325 3.808 5.5260.000 1.259 837.011.831.867 0.000 71.70 8.44 180.0 8/20/2024 15:15 7.59068.46512.156 5.497 614.5527.171 0.000 0.030 37.2710.0007.900 3.556 5.4460.000 1.289 837.011.561.752 0.000 76.05 8.35 180.0 8/20/2024 15:16 5.74465.56212.171 5.475 616.5897.289 0.000 0.000 38.7910.0009.456 3.676 5.5460.000 1.087 837.011.291.672 0.000 71.31 8.35 180.0 8/20/2024 15:17 6.85664.65012.155 5.464 618.5686.972 0.000 0.000 38.2570.0009.126 3.529 5.3910.000 1.290 837.011.501.761 0.002 71.51 8.34 180.0 8/20/2024 15:18 5.84063.80812.202 5.467 617.6277.070 0.000 0.000 38.8030.0009.843 3.714 5.6300.000 1.084 837.011.321.575 0.000 69.65 8.25 180.0 8/20/2024 15:19 7.21865.03612.251 5.487 620.5537.146 0.000 0.000 38.2320.0009.542 3.840 5.4270.000 1.274 837.011.691.733 0.000 72.25 8.25 180.0 8/20/2024 15:20 6.19863.38712.289 5.466 617.8987.409 0.000 0.000 38.8670.0009.084 3.682 5.7190.000 1.091 837.011.491.699 0.002 69.58 8.27 180.0 8/20/2024 15:21 7.52967.28812.273 5.499 619.6507.083 0.000 0.000 38.6740.0008.967 3.642 5.6910.000 1.081 837.011.341.591 0.001 74.82 8.47 180.0 8/20/2024 15:22 7.54567.02012.261 5.476 618.7086.987 0.000 0.000 37.8120.0008.993 3.615 5.4470.000 1.239 837.011.511.764 0.002 74.56 8.24 180.0 8/20/2024 15:23 6.95965.49012.229 5.493 618.8047.285 0.000 0.000 37.8940.0009.802 3.393 5.4140.000 1.284 837.011.411.751 0.000 72.45 8.44 180.0 8/20/2024 15:24 8.01667.16612.200 5.478 619.0897.214 0.000 0.000 37.8030.0009.048 3.612 5.4260.000 1.270 837.011.501.690 0.000 75.18 8.25 180.0 8/20/2024 15:25 6.40864.89112.198 5.448 617.7517.185 0.000 0.000 38.6650.0009.266 3.681 5.6990.000 1.015 837.011.321.706 0.002 71.30 8.36 180.0 8/20/2024 15:26 6.90666.74812.213 5.452 621.2667.226 0.000 0.000 39.0340.0009.105 3.455 5.5130.000 1.093 837.011.111.661 0.003 73.65 8.25 180.0 8/20/2024 15:27 5.96663.04612.192 5.462 617.9487.126 0.000 0.000 38.7550.0009.180 3.631 5.5200.000 1.078 837.011.241.708 0.001 69.01 8.35 180.0 8/20/2024 15:28 6.70965.10812.217 5.474 618.4747.451 0.000 0.000 38.6550.0008.629 3.610 5.6320.000 1.063 837.011.231.594 0.000 71.82 8.34 180.0 8/20/2024 15:29 7.67266.57012.225 5.473 619.4657.476 0.000 0.000 38.1360.0009.220 3.687 5.5490.000 1.240 837.011.741.887 0.000 74.24 8.43 180.0 6.83565.65212.177 5.478 618.8677.170 0.000 0.009 38.3890.0009.003 3.635 5.5660.000 1.170 837.0311.4701.709 0.001 72.486 8.347 180.0Avg. 6.63365.56112.133 5.470 618.3177.092 0.000 0.026 38.4070.0008.959 3.603 5.5780.000 1.164 837.5211.4161.662 0.001 72.194 8.313 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/20/2024 15:31 0.0000.0000.084 0.000 2.4590.000 0.063 0.487 0.0000.0030.000 0.316 0.2860.000 0.000 837.00.590.137 0.010 0.00 0.38 180.0 Run 3 - A 30minute/60min 8/20/2024 15:33 2.71161.62710.643 4.817 548.1214.894 0.000 0.870 30.6720.0005.586 3.038 5.3930.000 1.391 837.011.341.713 0.000 64.34 7.71 180.0 8/20/2024 15:34 7.15866.55012.147 5.447 616.3677.099 0.000 0.029 37.7740.0007.879 3.413 5.4180.000 1.247 837.011.451.889 0.001 73.71 8.20 180.0 8/20/2024 15:35 7.39368.91512.163 5.483 615.5217.313 0.000 0.000 37.4530.0009.254 3.620 5.3810.000 1.255 837.011.451.716 0.000 76.31 8.36 180.0 8/20/2024 15:36 6.81168.97512.198 5.476 618.3597.193 0.000 0.000 38.6970.0009.485 3.576 5.6770.000 1.055 837.011.301.694 0.000 75.79 8.34 180.0 8/20/2024 15:37 6.49868.18512.209 5.480 617.3057.352 0.000 0.000 38.7820.0009.170 3.566 5.5780.000 1.076 837.011.121.519 0.000 74.68 8.25 180.0 8/20/2024 15:38 5.99164.91612.252 5.474 619.9727.035 0.000 0.000 39.4920.0009.512 3.650 5.5990.000 1.049 837.011.211.619 0.000 70.91 8.24 180.0 8/20/2024 15:39 6.50664.74112.223 5.483 617.7077.267 0.000 0.000 39.0950.0009.521 3.758 5.6280.000 1.091 837.011.471.728 0.000 71.25 8.26 180.0 8/20/2024 15:41 6.54465.39612.190 5.485 617.8757.438 0.000 0.000 38.3370.0009.537 3.618 5.5220.000 1.212 837.011.501.706 0.000 71.94 8.33 180.0 8/20/2024 15:42 6.42665.54612.229 5.492 617.0317.234 0.000 0.000 38.8520.0009.187 3.631 5.6120.000 1.093 837.011.241.530 0.001 71.97 8.34 180.0 8/20/2024 15:43 5.43065.16512.251 5.490 616.7747.231 0.000 0.000 38.8310.0009.285 3.806 5.6660.000 1.049 837.011.251.417 0.001 70.60 8.34 180.0 8/20/2024 15:44 7.12566.52112.244 5.487 617.5787.140 0.000 0.000 38.1020.0009.714 3.569 5.3960.000 1.258 837.011.561.905 0.000 73.65 8.35 180.0 8/20/2024 15:45 7.14366.50412.186 5.477 617.6667.325 0.000 0.000 38.1360.0008.992 3.662 5.5330.000 1.231 837.011.681.860 0.002 73.65 8.43 180.0 8/20/2024 15:46 7.54768.75012.161 5.487 616.9287.147 0.000 0.000 37.8690.0009.277 3.794 5.5010.000 1.241 837.011.721.805 0.000 76.30 8.35 180.0 8/20/2024 15:47 6.65667.24712.176 5.482 619.6967.231 0.000 0.000 38.2430.0008.966 3.681 5.4220.000 1.263 837.011.511.668 0.000 73.90 8.34 180.0 8/20/2024 15:48 5.90665.76812.163 5.484 619.2476.834 0.000 0.000 39.1060.0009.290 3.747 5.7410.000 1.033 837.011.401.643 0.000 71.67 8.25 180.0 8/20/2024 15:49 5.82564.64412.168 5.481 617.7337.121 0.000 0.000 38.9100.0009.275 3.698 5.7260.000 1.019 837.011.491.893 0.000 70.47 8.33 180.0 8/20/2024 15:50 5.55064.71812.180 5.472 618.2997.154 0.000 0.000 38.8670.0009.013 3.735 5.6550.000 1.089 837.011.371.563 0.000 70.27 8.33 180.0 8/20/2024 15:51 7.41765.62112.167 5.471 617.5717.377 0.000 0.000 38.0790.0009.279 3.755 5.4630.000 1.248 837.011.611.719 0.000 73.04 8.32 180.0 8/20/2024 15:52 6.20564.37512.200 5.467 616.5467.151 0.000 0.000 38.6440.0009.083 3.681 5.8030.000 1.030 837.011.541.835 0.001 70.58 8.26 180.0 8/20/2024 15:53 5.98563.72012.171 5.483 617.9607.097 0.000 0.000 38.8870.0009.546 3.836 5.5870.000 1.055 837.011.391.709 0.000 69.71 8.33 180.0 8/20/2024 15:54 7.09364.26312.179 5.482 616.6617.398 0.000 0.000 37.7410.0009.234 3.701 5.5500.000 1.253 837.011.561.551 0.000 71.36 8.34 180.0 8/20/2024 15:55 6.87164.79712.199 5.489 617.6317.156 0.000 0.000 37.8320.0009.285 3.523 5.3580.000 1.262 837.011.371.710 0.000 71.67 8.33 180.0 8/20/2024 15:56 7.74265.84612.181 5.483 615.8187.099 0.000 0.000 37.5460.0008.797 3.516 5.4960.000 1.224 837.011.411.683 0.000 73.59 8.34 180.0 8/20/2024 15:57 7.60566.44512.138 5.481 616.4897.207 0.000 0.000 37.7990.0009.252 3.774 5.4240.000 1.231 837.011.742.004 0.000 74.05 8.34 180.0 8/20/2024 15:58 7.00766.66612.136 5.469 614.9187.072 0.000 0.000 37.1680.0009.301 3.746 5.4300.000 1.218 837.011.501.699 0.000 73.67 8.35 180.0 8/20/2024 15:59 6.96365.72812.166 5.470 618.6856.752 0.000 0.000 38.0440.0009.197 3.626 5.4610.000 1.211 837.011.521.824 0.000 72.69 8.33 180.0 8/20/2024 16:00 7.07065.75212.177 5.475 617.7687.388 0.000 0.000 38.1570.0009.435 3.569 5.4540.000 1.292 837.011.461.569 0.000 72.82 8.37 180.0 8/20/2024 16:01 6.93865.27912.170 5.488 615.8307.254 0.000 0.000 37.5360.0009.525 3.773 5.4780.000 1.241 837.011.641.745 0.000 72.22 8.35 180.0 8/20/2024 16:02 6.88265.61512.196 5.483 616.3777.325 0.000 0.000 37.7510.0009.382 3.860 5.3930.000 1.270 837.011.681.762 0.000 72.50 8.35 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 16:03 7.15265.31312.192 5.483 617.3427.240 0.000 0.000 37.7220.0009.223 3.730 5.5270.000 1.233 837.011.611.699 0.002 72.46 8.27 180.0 6.60565.78612.135 5.457 615.0597.117 0.000 0.030 38.0040.0009.116 3.655 5.5290.000 1.181 837.0011.4701.713 0.000 72.392 8.301 180.0Avg. Spike 3 8/20/2024 16:06 6.38178.45411.088 5.329 573.42951.181 0.000 0.484 30.6500.0005.630 5.176 26.8200.000 1.368 837.034.171.750 0.847 84.84 8.29 180.0 Run 3 - B 30minute/60min 8/20/2024 16:08 6.38372.96011.771 5.431 603.18621.874 0.000 0.140 35.6960.0007.176 4.377 12.8070.000 1.286 837.019.561.891 0.289 79.34 8.39 180.0 8/20/2024 16:09 7.32264.69612.156 5.467 617.0367.228 0.000 0.000 37.9470.0009.444 3.686 5.5220.000 1.241 837.011.621.741 0.000 72.02 8.32 180.0 8/20/2024 16:10 5.97064.58112.155 5.476 616.1317.263 0.000 0.000 38.6900.0009.605 3.738 5.6820.000 1.042 837.011.361.657 0.000 70.55 8.34 180.0 8/20/2024 16:11 7.03665.57712.144 5.476 617.9387.138 0.000 0.000 38.0500.0009.553 3.663 5.6010.000 1.237 837.011.771.877 0.002 72.61 8.36 180.0 8/20/2024 16:12 6.38265.62712.148 5.492 615.9357.359 0.000 0.000 37.7480.0009.405 3.819 5.5130.000 1.223 837.011.741.847 0.000 72.01 8.43 180.0 8/20/2024 16:13 6.60664.49312.156 5.467 616.2557.279 0.000 0.000 37.9530.0009.561 3.618 5.4820.000 1.256 837.011.591.777 0.002 71.10 8.36 180.0 8/20/2024 16:14 7.36565.41312.156 5.472 615.7447.192 0.000 0.000 37.6930.0009.180 3.737 5.4800.000 1.248 837.011.611.715 0.000 72.78 8.46 180.0 8/20/2024 16:15 7.18266.61612.149 5.476 617.1347.190 0.000 0.000 37.9750.0009.282 3.759 5.5300.000 1.220 837.011.832.031 0.000 73.80 8.45 180.0 8/20/2024 16:17 7.39665.98112.168 5.485 617.8257.371 0.000 0.000 37.9780.0009.549 3.634 5.4730.000 1.247 837.011.491.654 0.000 73.38 8.44 180.0 8/20/2024 16:18 6.94065.91112.172 5.470 613.4297.205 0.000 0.000 37.6390.0009.148 3.628 5.5380.000 1.200 837.011.421.595 0.001 72.85 8.37 180.0 8/20/2024 16:19 7.61166.47912.216 5.506 616.2307.365 0.000 0.000 37.8600.0009.313 3.660 5.3460.000 1.271 836.011.601.913 0.000 74.09 8.45 180.0 8/20/2024 16:20 6.62066.12912.212 5.487 617.4346.959 0.000 0.000 38.1900.0009.185 3.726 5.5600.000 1.235 836.011.701.784 0.001 72.75 8.34 180.0 8/20/2024 16:21 7.12765.16312.211 5.488 615.5116.986 0.000 0.024 38.0620.0008.198 3.777 5.5060.000 1.229 836.011.661.770 0.000 72.29 8.47 180.0 8/20/2024 16:22 7.02768.82012.214 5.477 617.7367.428 0.000 0.000 37.8340.0009.234 3.671 5.5410.000 1.216 836.011.561.711 0.000 75.85 8.46 180.0 8/20/2024 16:23 7.73166.34912.187 5.472 615.8607.259 0.000 0.000 37.6660.0009.494 3.879 5.4160.000 1.243 836.011.771.927 0.000 74.08 8.46 180.0 8/20/2024 16:24 7.52767.16312.154 5.497 617.8267.130 0.000 0.000 37.9310.0009.229 3.740 5.6040.000 1.250 836.011.781.768 0.000 74.69 8.36 180.0 8/20/2024 16:25 7.09168.42512.125 5.465 615.5537.226 0.000 0.000 37.8500.0008.763 3.806 5.4940.000 1.253 836.011.661.686 0.000 75.52 8.47 180.0 8/20/2024 16:26 6.48566.48612.134 5.479 617.3677.164 0.000 0.000 38.1220.0009.193 3.694 5.5200.000 1.230 836.011.721.915 0.000 72.97 8.36 180.0 8/20/2024 16:27 6.16364.33512.165 5.475 618.2997.424 0.000 0.000 38.9160.0009.252 3.608 5.6940.000 1.083 836.011.371.653 0.000 70.50 8.33 180.0 8/20/2024 16:28 6.64764.34612.178 5.480 617.8787.059 0.000 0.000 38.2160.0009.377 3.799 5.6080.000 1.249 836.011.821.770 0.000 70.99 8.36 180.0 8/20/2024 16:29 7.12066.08312.144 5.466 615.5147.238 0.000 0.000 37.8290.0009.383 3.657 5.5350.000 1.236 836.011.651.805 0.000 73.20 8.53 180.0 8/20/2024 16:30 8.09870.12712.128 5.472 618.6126.977 0.000 0.000 37.9550.0009.166 3.669 5.5800.000 1.230 836.011.711.836 0.002 78.23 8.47 180.0 8/20/2024 16:31 8.21269.48812.091 5.488 619.0527.324 0.000 0.000 37.9280.0009.216 3.805 5.6230.000 1.209 836.011.751.758 0.000 77.70 8.55 180.0 8/20/2024 16:32 7.18869.06412.085 5.483 619.8047.135 0.000 0.000 38.7420.0009.022 3.785 5.6930.000 1.041 836.011.271.456 0.000 76.25 8.45 180.0 8/20/2024 16:33 7.53166.67812.085 5.469 618.6637.277 0.000 0.000 38.8930.0009.151 3.659 5.6980.000 0.983 836.011.281.761 0.000 74.21 8.46 180.0 8/20/2024 16:34 6.60666.52312.104 5.485 619.6117.144 0.000 0.000 39.2020.0009.115 3.709 5.6690.000 1.018 836.011.201.524 0.000 73.13 8.45 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 16:35 7.23266.02412.120 5.491 621.8427.184 0.000 0.000 39.5070.0009.337 3.759 5.6100.000 1.048 836.011.251.548 0.001 73.26 8.37 180.0 8/20/2024 16:36 6.46565.37612.131 5.491 620.8597.130 0.000 0.000 39.5780.0009.506 3.774 5.6530.000 1.038 836.011.311.598 0.000 71.84 8.47 180.0 8/20/2024 16:37 6.74566.45412.073 5.473 617.8926.923 0.000 0.000 39.1140.0009.209 3.686 5.6830.000 1.024 836.011.361.762 0.003 73.20 8.47 180.0 8/20/2024 16:38 6.52566.88112.098 5.469 618.2737.536 0.000 0.000 39.1310.0008.916 3.596 5.8730.000 0.982 836.011.341.654 0.002 73.41 8.47 180.0 7.01166.60812.134 5.478 617.0147.699 0.000 0.005 38.1970.0009.172 3.737 5.8180.000 1.176 836.3311.8251.746 0.010 73.620 8.422 180.0Avg. 6.80866.19712.135 5.467 616.0377.408 0.000 0.018 38.1000.0009.144 3.696 5.6730.000 1.178 836.6711.6471.729 0.005 73.006 8.362 180.0Run 3 Avg: Baseline 3 8/20/2024 16:40 0.0000.0000.081 0.000 2.6840.000 0.065 0.362 0.1790.0050.000 0.477 0.2360.000 0.000 836.00.660.163 0.007 0.00 0.40 180.0 Post CTS 8/20/2024 16:42 0.0000.8570.056 0.000 0.0000.000 0.004 0.428 0.0000.0360.000 101.752 0.1160.000 0.000 836.068.000.063 0.017 0.86 0.22 180.0 8/20/2024 16:42 0.0002.8620.047 0.000 0.0000.000 0.000 0.747 0.0000.0000.000 101.603 0.0000.036 0.000 836.067.840.156 0.006 2.86 0.22 180.0 8/20/2024 16:42 0.0002.7600.053 0.000 0.0000.000 0.008 0.435 0.0290.0220.000 100.642 0.2300.000 0.000 836.067.410.124 0.026 2.76 0.19 180.0 Post NO2/Mid O2 8/20/2024 16:46 97.2190.0000.027 0.000 0.8030.000 0.333 0.180 0.3740.0590.000 0.000 0.0000.009 0.072 836.00.340.292 0.014 97.22 10.89 180.0 8/20/2024 16:46 97.7980.3840.026 0.000 0.7180.005 0.333 0.586 0.2710.0310.000 0.000 0.0000.000 0.067 836.00.130.000 0.011 98.18 10.96 180.0 8/20/2024 16:46 99.2060.3620.019 0.000 0.5540.000 0.326 0.270 0.5630.0000.000 0.071 0.0000.444 0.081 836.00.490.413 0.019 99.57 10.97 180.0 Post 5-Gas 8/20/2024 16:48 0.000252.8020.051 4.536 4.091495.865 1.202 1.507 5.8750.1930.000 1.582 256.7180.126 0.000 836.0260.083.461 9.939 252.80 0.13 180.0 8/20/2024 16:48 0.000253.0600.046 4.553 1.856496.041 1.169 1.669 5.2070.0110.000 1.544 258.0120.000 0.000 836.0261.193.218 9.947 253.06 0.14 180.0 8/20/2024 16:48 0.000253.9730.042 4.546 2.916499.443 1.256 1.506 5.0130.0310.969 1.525 258.0080.327 0.000 836.0261.103.115 9.975 253.97 0.14 180.0 8/20/2024 16:48 0.000253.0740.032 4.530 1.420499.450 1.124 1.625 4.8480.0770.000 1.482 258.8940.000 0.000 836.0262.113.339 10.006 253.07 0.13 180.0 8/20/2024 16:48 0.000254.2070.022 4.580 1.877498.534 1.251 1.971 5.1250.0020.758 1.535 258.7900.255 0.000 836.0261.652.762 9.990 254.21 0.14 180.0 8/20/2024 16:48 0.000254.6360.035 4.487 2.084499.994 1.264 1.539 5.6510.0271.623 1.421 258.6160.214 0.000 836.0261.392.742 10.002 254.64 0.14 180.0 8/20/2024 16:48 0.000253.7820.027 4.541 1.678498.951 1.284 1.679 4.4080.0570.471 1.436 259.2900.000 0.000 836.0261.762.270 9.996 253.78 0.14 180.0 End of Test Purge 8/20/2024 16:50 0.0001.9810.021 0.000 0.0002.554 0.156 0.520 0.0000.0000.000 0.068 1.2050.611 0.000 836.01.340.140 0.054 1.98 0.15 180.0 8/20/2024 16:50 0.0002.1220.024 0.000 0.0001.584 0.045 0.409 0.0000.0000.000 0.300 1.1140.000 0.000 836.01.580.395 0.030 2.12 0.15 180.0 8/20/2024 16:50 0.0000.7950.026 0.000 0.0001.179 0.073 0.347 0.0000.0000.000 0.635 0.8070.000 0.000 836.01.540.466 0.026 0.80 0.15 180.0 8/20/2024 16:50 0.0070.8610.025 0.000 0.0001.075 0.051 0.681 0.0000.0000.000 0.936 0.7180.000 0.000 836.01.340.000 0.027 0.87 0.15 180.0 8/20/2024 16:51 0.0000.0000.019 0.000 0.3550.832 0.029 0.533 0.0000.0000.000 0.411 0.7620.000 0.000 836.01.440.601 0.029 0.00 0.15 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/20/2024 16:51 0.0000.1500.018 0.000 0.0270.722 0.032 0.364 0.0590.0090.000 0.315 0.3720.554 0.000 836.00.670.138 0.028 0.15 0.15 180.0 8/20/2024 16:51 0.0000.0680.025 0.000 0.0000.447 0.006 0.494 0.0000.0150.000 0.525 0.5900.000 0.000 836.01.210.409 0.024 0.07 0.15 180.0 8/20/2024 16:51 0.0000.5300.020 0.000 0.2430.580 0.000 0.179 0.0000.0030.000 0.239 0.6090.000 0.000 836.01.060.432 0.008 0.53 0.15 180.0 GAS, Inc. Performance Test Report Test Type: Initial Test Date: 8/21/2024 Caterpillar G3516H Lean Burn (4 Cycle) DOM: 4/12/22 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:08:15 AM 11:52 AM Source: Unit Number: SW700631 Serial Number: H6C00248 Engine Hours:5043.3 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Boston SWD 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 12.398 80.422 14.085 2.000 0.180 1.000 0.500 0.700 0.300 0.035 0.374 0.063 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results ppmvd Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Wheeler CAT 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Ethan Kinsey 3 Cooper Green Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit SW700631 with a serial number of H6C00248 which is a Caterpillar G3516H engine located at Boston SWD and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/21/2024 by Cooper Green with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 2763 brake horse power (BHP) at 1800 RPM. The engine was operating at 1879 BHP and 1800 RPM which is 68.00% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. 4 4.0 Test Summary Engine/Compressor Specs Boston SWDLocation SW700631Unit ID Make Caterpillar Site Elevation ft.5533 Model G3516H Atmospheric Pressure psi.12.04 Serial Number H6C00248 Stack Diameter in.18 mfg. rated hp 2763 Yes 1800 Date of Manufacture 4/12/2022 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1879 1879 1879 1879 1800 1800 1799 1800 Percent Load % Intake Manifold Pressure (hg) 68.00%68.00%68.00%68.00% 71.79 71.99 70.77 71.52 Intake Manifold Temperature (F)136.00 136.00 135.00 135.67 Ambient Conditions Ambient Temperature Dry (F)67.00 71.00 78.00 72.00 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 156570.79 162928.24 165020.81 161506.61 4433.55 4613.57 4672.83 4573.32 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.12 0.12 0.12 0.12 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %12.30%12.34%12.37%12.34% T e s t S u m m a r y mfg. rated rpm Test RPM 9.33%9.32%9.37%9.34% Permitted Standards Results 5 Catalyst 0.0360.036 Run 1 Run 2 Run 3 3 Run Average Pass Permits 08:15 AM 09:24 AM 10:36 AM 8/21/2024 CO (g/hp-hr)0.034 0.0352.000 0.180 Pass StateFederal CO (ppmvw)10.749 10.928 10.930 10.869 CO (ppmvd)12.256 12.466 12.472 12.398 CO (mol wt) 28.01 CO (ppmvd) @15% O2 6.249 6.351 6.384 6.328 Fail CO (ppbvd) @15% O2 6249.313 6350.645 6384.211 6328.056 Fail NOx (g/hp-hr)0.360 0.381 0.382 0.3741.000 0.500 Pass NOx (ppmvw)70.003 71.176 70.326 70.501 NOx (ppmvd)79.819 81.199 80.249 80.422 NOx (mol wt) 46.01 12.265 12.337 12.441 12.348NMNEHC (ppmvw) 13.985 14.074 14.196 14.085NMNEHC (ppmvd) NOx (ppbvd) @15% O2 40698.438 41364.479 41077.110 41046.676 Fail NOx (ppmvd) @15% O2 40.698 41.364 41.077 41.047 Fail NMNEHC (mol wt) 44.10 7130.693 7169.793 7266.493 7188.993 FailNMNEHC (ppbvd) @15% O2 0.060 0.063 0.065 0.0630.700 0.300 PassNMNEHC (g/hp-hr) 7.131 7.170 7.266 7.189 FailNMNEHC (ppmvd) @15% O2 Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 1.02Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 10.75 0.49 64.65 0.00 5.35 0.49 70.00 0.83 12.27 0.13% 8.16% 0.00% 12.30% NMNEHC 10.78 64.17 4.65 68.82 12.29 8.13%12.33% 59.74 78.13 4.55 82.68 36.93 7.87%11.17% 10.72 65.13 6.06 71.19 12.24 8.20%12.27% 0.55 0.27 0.00 0.27 0.49 0.34%0.10% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.55 0.27 0.00 0.27 0.49 0.34%0.10% 10.83 64.84 6.12 70.96 12.32 8.11%12.30% 47.61 74.05 6.39 80.44 31.18 7.88%11.31% 11.02 65.06 6.33 71.39 12.36 8.19%12.39% 0.67 0.00 0.00 0.00 0.56 0.24%0.08% Avg. Wet 10.93 64.95 6.22 71.18 12.34 8.15%12.34% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 10.89 64.10 6.03 70.13 12.40 8.15%12.38% 55.02 78.47 4.19 82.66 34.24 7.99%11.34% 10.98 64.38 6.14 70.53 12.48 8.25%12.35% 0.67 0.00 0.00 0.00 0.55 0.39%0.10% 0.67 0.00 0.00 0.00 0.56 0.24%0.08% Avg. Wet 10.93 64.24 6.09 70.33 12.44 8.20%12.37% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 18 inches or:1.5 feet. or:1.77 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.55 Yes 18.00 9.00 36.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 12.30 29.22 0.50 Inches 3.01 9 14.99 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.56 8.17 10.75 838.00 0.04 24.75 24.79 809.38 1269.05 431.88 27.84 81.41 143.87 178525.90 156570.79 Run 2 12.34 29.22 0.54 5.58 8.16 10.93 838.00 0.04 24.75 24.79 807.31 1266.98 430.73 27.83 84.61 149.52 185872.32 162928.24 Run 3 12.37 29.22 0.56 5.57 8.20 10.93 837.52 0.04 24.74 24.78 805.44 1265.11 429.69 27.83 85.64 151.34 188305.75 165020.81 12.34 29.22 0.54 5.57 8.18 10.87 837.84 0.04 24.75 24.79 807.38 1267.05 430.77 27.83 83.91 148.28 184276.60 161544.54 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.53 Exhaust Temp F 809.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.47 0.51 0.50 809.00 810.00 810.00 0.50 0.49 0.52 809.00 809.00 809.00 0.52 0.51 0.48 810.00 810.00 809.00 0.48 809.00 0.49 0.52 0.52 809.00 810.00 809.00 0.50 0.51 0.50 809.00 810.00 809.38 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.56 Exhaust Temp F 805.00 0.54 0.57 0.53 805.00 806.00 805.00 0.55 0.55 0.58 805.00 807.00 805.00 0.59 0.54 0.56 805.00 806.00 805.00 0.53 805.00 0.55 0.56 0.60 806.00 805.00 805.00 0.57 0.55 806.00 806.00 805.440.56 Run 2 Δpstd (in) H2O 0.53 Exhaust Temp F 807.00 0.55 0.55 0.57 807.00 807.00 808.00 0.52 0.50 0.56 808.00 807.00 807.00 0.54 0.58 0.54 808.00 808.00 807.00 0.53 807.00 0.58 0.57 0.51 807.00 808.00 807.00 0.52 0.56 807.00 807.00 0.54 807.31 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.056)+.32(.093)+.28(.85+.001) = 29.217 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.217(1 -.12298)+.18.0(.12298) = 27.838 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.5*√(1269.045/(24.79*27.838)) = 81.41 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.123)81.412*1.767((528*24.79)/ (1269.045*29.92)) = 156570.79 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 156570.786/35.315 = 4433.549 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 12.256*(20.9-15)/(20.9-9.3%)) = 6.234 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (12.256*(1.164*10^-3)*4433.549*(Run Time/60))/1878.84 = .034 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .034*1/453.6*1878.84 = .139 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .139*4.38 = .609 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 12.26 = 10.749*(1/(1-.12))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.56% 20.60% 10.68% 10.81% 10.76% 10.76% 10.81%10.68% 10.56% 20.60% 10.76% 20.98% 10.76% 20.98% 10.76%20.98% 0.00% 10.76% 20.98% 0.20% 0.38% 0.94% 1.83% 10.76% Span Zero Offset 0.00% 20.98 0.00% 10.56%0.54%1.18%0.01% 9.31% 9.30% 9.36% 9.33% 9.32% 9.37% 9 Gas, Inc. 0.0 0.0 0.0 0.0 0.0 0.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Boston SWD 8/21/2024 5533 SW700631 Caterpillar Model Serial Number G3516H H6C00248 Technician Cooper Green Run Start Times 08:15 AM 09:24 AM 10:36 AM 11:52 AM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1800.0 1800.0 1799.0 1799.7 Engine Hours 5040.3 5041.3 5042.3 5043.3 Intake Manifold Pressure (psi)47.3 47.4 46.8 47.2 Intake Manifold Temp °F 136.0 136.0 135.0 135.7 Engine Load (BHP)1878.8 1878.8 1878.8 1878.8 Ambient Temp °F 67.0 71.0 78.0 72.0 Humidity %57.0 50.0 38.0 48.3 Dew Point °F 51.0 52.0 50.0 51.0 Caterpillar Yes 1 1 1 1# of Catalyst Installed Catalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 0.0 0.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.07 R e s u l t s Average:Nitrogen monoxide NO 0.07 Average:Nitrogen dioxide NO2 0.12 Average:NOx 0.18 Average:VOC 0.04 Average:Oxygen 0.17 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.36 Tolerance 2.00% Difference between measured and expected 0.64% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 1.16 Average:Nitrogen monoxide NO 0.73 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.73 Average:VOC 0.77 Average:Oxygen 0.14 Pre-test System Zero Time: Mechanical Response Time 5 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 95.16 Tolerance 5.00% Difference between measured and expected 4.84% Pre-test System CTS & Mechanical Response Time 45 secondsEquilibration Response Time Value:Spike Reported 254.37 Value:Spike Expected 258.20 System (Equilibration) Response Time Target (Spike) 81 secondsSystem Zero Response Time 81 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC511346 4/24/2027 98.96 10.76% CC706226 4/24/2032 100.00 CC185396 6/17/2032 20.98% Cylinder # CC102850 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 258.20 502.80 243.30 10.14 Analyzer System Response 254.37 501.99 238.15 10.00 Percent Difference 1.48%0.16%2.12%1.41% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.365 4.968 Spike Direct Propane 255.470 Mechanical Response Time SF6 10.018 CO 503.775 NO 239.567 Ethylene 95.156 5 seconds Analyzer Response Propane 254.373 SF6 9.997 CO 501.989 NO 238.152 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.563 CO 500.179 NO 236.128 31 seconds 81 seconds 9.25% 7.09% 8.14% 98.01% 97.81% 98.29% 9.960 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%3.006 50%9.000 83.3%14.994 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 18 9 36 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 161544.54 H2O%d @ Sampling Point:12.34 CO2%d @ Sampling Point:5.57 Pressure @ Sampling Point (Pg "H2O):0.54 Temperature @ Sampling Point (Deg F):807.38 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99.36 4.968 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.365 4.968 Spike Direct Propane 255.470 Mechanical Response Time SF6 10.018 CO 503.775 NO 239.567 Ethylene 95.156 5 seconds Analyzer Response Propane 254.373 SF6 9.997 CO 501.989 NO 238.152 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.563 CO 500.179 NO 236.128 31 seconds 81 seconds 9.25% 7.09% 8.14% 98.01% 97.81% 98.29% 9.960 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 258.200 10.140 502.800 243.300 255.470 10.018 503.775 239.567 1.06% 1.20% 0.19% 1.53% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 5.516 0.000 Spike Average 28.313 0.927 Dilution Factor 9.253% Expected 28.889 % Recovery 98.010% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.710 Dilution Factor 7.087% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.815 Dilution Factor 8.135% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 5.480 25.605 26.052 98.290% 0.001197 0.000585 0.000222 5.478 22.883 23.396 97.810% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass1.36% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:9.95939222 Pass Line Position Difference:Resolution Difference to Reference 1.36% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 100.39 0.39% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Boston SWD; SW700631; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/21/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/21/2024 Cooper Green Gas, Inc. Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. 21% O2 Tri Probe Certification Great Plains Analytical Services 303 W 3rd St Elk City, OK, 73644 (580)225-0403 Fax: (580)225-2612 CERTIFICATE OF ANALYSIS Grade of Product: CERTIFIED STANDARD-PROBE Part Number: 18L Reference Number: 3 Laboratory: GAS INC. Stack Diameter: 18” Analysis Date: Dec. 3, 2021 Target Flow Rate: 3L/min LOT Number: SN: A 3A 18L Number of Points: 3 Product performance verified by direct comparison to calibration standards traceable to N.I.S.T. *The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e, section 8.4 as shown in the accompanying data. Method 7e, section 8.4 states that the multipoint traverse requirement can be satisfied by sampling via “a multi-hole probe designed to sample at the prescribed points with a flow +/- 10 percent of mean flow rate”. ANALYTICAL RESULTS !"#$%$&'()*$+*',$ -./01 $ 23)4"536$+*',$ 7'5($8 $-./01$ -93*()$:;1$ 23)4"536$+*',$ 7'5($<$-./01$ -93*()$:=1$ 23)4"536$+*',$ 7'5($>$-./01 $ -93*()$:?1$ Mean Probe Port Sampled Flow (L/m)$ $ Run 1 2 LPM .660 (5.88D) .620 (-0.53D) .590 (-5.35D) .623 Run 2 4 LPM 1.29 (3.20D) 1.26 (0.80D) 1.20 (-4.00D) 1.250 *Calibration conducted in accordance with Emission Measurement Center Guideline Document – EMC GD-031 Notes: ___________________________________________________ _________________________ Approved for Release Date 12-3-21 Probe size: 18 L Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Cooper Green GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Boston SWD Unit Number:SW700631 Make:Caterpillar Location:G3516HModel: H6C00248Serial Number: RAW Result Data Stability 8/21/2024 05:19 0.0000.000-0.025 0.012 0.0000.000 0.000 0.000 0.0000.0000.000 0.126 0.0000.066 0.000 835.00.480.590 0.000 0.00 0.14 179.0 Pre Test Baseline Direct 8/21/2024 05:27 0.0000.203-0.002 0.000 0.1520.079 0.015 0.058 0.0000.1800.000 0.000 0.0000.000 0.000 835.00.040.054 0.000 0.20 0.23 181.0 8/21/2024 05:27 0.3460.000-0.002 0.000 0.0400.013 0.012 0.000 0.0000.0000.000 0.000 0.0000.000 0.000 835.00.040.055 0.004 0.35 0.15 181.0 8/21/2024 05:28 0.0000.000-0.003 0.000 0.0000.110 0.012 0.000 0.0000.0000.000 0.000 0.0000.123 0.000 835.00.040.057 0.000 0.00 0.14 181.0 CTS Direct 8/21/2024 05:32 0.0000.1980.017 0.001 0.0000.116 0.034 0.000 0.0000.0700.000 100.093 0.0000.000 0.011 835.066.760.008 0.006 0.20 0.20 181.0 8/21/2024 05:32 0.0000.0530.017 0.007 0.0000.067 0.032 0.144 0.0000.0000.000 99.902 0.0000.108 0.001 835.066.700.133 0.004 0.05 0.20 181.0 8/21/2024 05:33 0.1700.2440.015 0.003 0.0000.112 0.015 0.000 0.0360.0000.110 98.099 0.0100.000 0.011 835.065.440.011 0.005 0.41 0.19 181.0 High O2 Direct 8/21/2024 05:43 0.0000.049-0.004 0.000 0.0500.138 0.024 0.110 0.0000.0000.407 0.000 0.0000.258 0.000 835.00.120.180 0.000 0.05 20.56 180.0 8/21/2024 05:43 0.0000.127-0.005 0.000 0.0000.233 0.030 0.253 0.0000.0600.487 0.051 0.0000.000 0.000 835.00.210.271 0.003 0.13 20.56 180.0 8/21/2024 05:43 0.0000.000-0.005 0.000 0.0200.082 0.029 0.110 0.0000.0430.657 0.085 0.0000.093 0.000 835.00.190.207 0.005 0.00 20.67 180.0 NO2/Mid O2 Direct 8/21/2024 05:52 98.4080.281-0.003 0.000 0.1080.035 0.386 0.000 0.6180.0001.244 0.000 0.0000.203 0.000 835.00.000.000 0.000 98.69 10.57 180.0 8/21/2024 05:52 97.1290.627-0.001 0.000 1.0380.156 0.380 0.000 0.7990.0001.233 0.000 0.0000.159 0.000 835.00.000.000 0.000 97.76 10.55 180.0 8/21/2024 05:52 98.3270.860-0.004 0.000 0.4630.088 0.383 0.000 0.4920.0021.423 0.000 0.0000.192 0.000 835.00.000.000 0.000 99.19 10.57 180.0 Spike Direct 8/21/2024 05:57 0.000239.4600.001 4.677 2.605503.680 1.293 1.783 5.1400.0271.581 1.379 255.4490.271 0.000 835.0258.152.673 10.013 239.46 0.14 180.0 8/21/2024 05:57 0.000239.688-0.001 4.682 2.106503.394 1.269 1.983 5.1420.1432.250 1.366 255.5470.277 0.000 835.0258.452.983 10.025 239.69 0.14 180.0 8/21/2024 05:58 0.000239.5530.000 4.678 3.023504.250 1.340 2.014 5.2670.3380.543 1.382 255.4140.162 0.000 835.0258.363.038 10.016 239.55 0.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/21/2024 06:00 0.0000.5390.017 0.000 0.2661.339 0.068 1.599 0.0000.0000.538 0.000 0.4710.000 0.117 835.00.920.318 0.015 0.54 0.14 180.0 8/21/2024 06:01 0.0000.8390.017 0.000 0.0161.064 0.058 1.437 0.0000.0020.204 0.135 0.2730.000 0.099 835.00.640.109 0.008 0.84 0.14 180.0 8/21/2024 06:01 0.0000.8000.013 0.000 0.1231.063 0.049 1.178 0.0720.0000.801 0.024 0.2770.000 0.119 835.00.760.341 0.004 0.80 0.14 180.0 CTS System with Response Time 8/21/2024 06:06 0.0000.0000.019 0.000 0.0000.671 0.062 0.731 0.0880.0030.618 95.116 0.0290.039 0.105 835.063.810.233 0.012 0.00 0.18 180.0 8/21/2024 06:07 0.0000.0000.018 0.001 0.0000.663 0.043 1.073 0.0000.0000.000 95.188 0.0860.000 0.081 835.063.830.173 0.015 0.00 0.18 180.0 8/21/2024 06:07 0.0000.2080.017 0.000 0.0000.647 0.040 0.979 0.0840.0290.000 95.164 0.0060.000 0.104 835.063.810.224 0.013 0.21 0.18 180.0 NO2/Mid O2 System with Response Time 8/21/2024 06:10 94.6211.7220.009 0.000 0.6050.634 0.390 0.806 0.0000.0010.000 0.007 0.0000.101 0.144 835.00.410.173 0.012 96.34 10.63 180.0 8/21/2024 06:10 95.7031.4730.010 0.000 0.6730.692 0.376 0.753 0.0000.0050.000 0.041 0.0000.300 0.117 835.00.600.510 0.008 97.18 10.66 180.0 8/21/2024 06:11 97.0511.9090.012 0.000 0.1040.605 0.393 0.830 0.0000.0120.000 0.000 0.0000.274 0.129 835.00.540.416 0.001 98.96 10.74 180.0 Spike System with Response Time 8/21/2024 06:13 0.000238.0860.004 4.658 2.607502.404 1.305 2.480 5.0260.1730.819 1.526 254.4840.000 0.000 835.0257.372.803 9.997 238.09 0.13 180.0 8/21/2024 06:14 0.000238.0580.004 4.670 2.528500.182 1.290 2.264 5.6960.0800.801 1.517 254.1710.275 0.000 835.0257.253.106 10.000 238.06 0.14 180.0 8/21/2024 06:14 0.000238.3110.007 4.662 2.561503.381 1.329 2.431 4.8450.0340.707 1.519 254.4640.000 0.000 835.0257.493.022 9.994 238.31 0.14 180.0 Baseline System with Response Time 8/21/2024 06:18 0.0000.8120.005 0.000 0.2191.202 0.073 0.720 0.0000.0010.631 0.390 0.4080.000 0.020 835.00.940.346 0.012 0.81 0.13 180.0 8/21/2024 06:18 0.0000.5720.009 0.000 0.3130.936 0.076 0.515 0.0000.0000.621 0.000 0.5210.000 0.000 835.00.770.375 0.011 0.57 0.14 180.0 8/21/2024 06:18 0.0000.0800.007 0.000 0.1660.927 0.057 0.706 0.0000.0000.634 0.185 0.3900.000 0.006 835.00.790.395 0.009 0.08 0.14 180.0 Run 1 - A 30minute/60min 8/21/2024 08:15 2.21264.53912.387 5.461 591.05610.801 0.000 1.434 34.7700.0009.262 3.911 5.3600.000 1.534 838.012.452.129 0.000 66.75 7.98 180.0 8/21/2024 08:16 2.52364.01112.379 5.504 591.78810.919 0.000 0.732 35.0980.0008.722 3.999 5.6170.000 1.394 838.012.522.169 0.000 66.53 8.19 180.0 8/21/2024 08:18 3.67566.67012.360 5.505 592.69710.756 0.000 0.485 34.8570.0008.263 4.076 5.4720.000 1.392 838.012.291.977 0.000 70.34 8.21 180.0 8/21/2024 08:19 3.88165.07612.345 5.529 593.75510.621 0.000 0.254 35.3040.0009.186 4.171 5.5640.000 1.352 838.012.321.911 0.000 68.96 8.12 180.0 8/21/2024 08:20 3.38662.49112.392 5.529 598.40810.609 0.000 0.074 36.1920.0009.090 4.051 5.5630.000 1.332 838.012.241.960 0.000 65.88 8.11 180.0 8/21/2024 08:21 3.43460.20012.407 5.535 597.53110.746 0.000 0.000 36.0960.0009.919 4.096 5.5810.000 1.315 838.012.312.048 0.000 63.63 8.02 180.0 8/21/2024 08:22 4.52563.71812.390 5.542 594.67810.722 0.000 0.000 35.3480.0009.855 4.396 5.5480.000 1.354 838.012.371.780 0.000 68.24 8.15 180.0 8/21/2024 08:23 4.87566.78612.357 5.567 596.16410.771 0.000 0.000 35.3990.00010.137 4.243 5.5670.000 1.286 838.012.281.969 0.000 71.66 8.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 08:24 4.75565.17912.355 5.572 597.99910.637 0.000 0.000 35.4230.0009.824 4.181 5.5390.000 1.295 838.012.081.745 0.000 69.93 8.12 180.0 8/21/2024 08:25 4.48062.63112.383 5.570 598.99110.869 0.000 0.000 36.2060.00010.061 4.185 5.5650.000 1.316 838.012.281.937 0.000 67.11 8.14 180.0 8/21/2024 08:26 4.70461.87712.388 5.558 600.17410.498 0.000 0.000 36.2770.0009.486 4.364 5.5970.000 1.271 838.012.301.882 0.000 66.58 8.21 180.0 8/21/2024 08:27 5.13663.49612.331 5.564 597.48710.617 0.000 0.000 35.7280.0009.716 4.264 5.6150.000 1.325 838.012.271.747 0.000 68.63 8.10 180.0 8/21/2024 08:28 4.85361.38112.307 5.562 596.99210.676 0.000 0.000 36.1260.00010.094 4.279 5.5730.000 1.341 838.012.391.917 0.000 66.23 8.10 180.0 8/21/2024 08:29 4.87664.51112.361 5.570 598.74410.641 0.000 0.000 35.8210.0009.667 4.374 5.5280.000 1.327 838.012.411.964 0.000 69.39 8.14 180.0 8/21/2024 08:30 4.36262.31212.321 5.552 597.42010.901 0.000 0.000 35.6300.0009.863 4.299 5.4930.000 1.323 838.012.251.863 0.000 66.67 8.03 180.0 8/21/2024 08:31 4.98363.19912.326 5.573 600.78010.902 0.000 0.000 36.0280.0009.474 4.293 5.4480.000 1.310 838.012.201.912 0.000 68.18 8.02 180.0 8/21/2024 08:32 5.03064.02812.311 5.553 597.91010.989 0.000 0.000 35.3180.0009.662 4.137 5.5720.000 1.301 838.012.071.715 0.000 69.06 8.11 180.0 8/21/2024 08:33 4.61362.61012.318 5.563 600.17610.981 0.000 0.000 36.0320.0009.824 4.170 5.6170.000 1.323 838.012.392.023 0.000 67.22 8.14 180.0 8/21/2024 08:34 4.23261.80412.323 5.557 599.80810.829 0.000 0.000 36.2220.0009.879 4.254 5.5870.000 1.288 838.012.332.000 0.000 66.04 8.10 180.0 8/21/2024 08:35 5.02662.99612.332 5.569 600.23010.780 0.000 0.000 36.0630.0009.608 4.447 5.4620.000 1.345 838.012.421.957 0.000 68.02 8.14 180.0 8/21/2024 08:36 4.98964.93912.328 5.576 597.38310.815 0.000 0.000 35.2220.0009.604 4.157 5.3940.000 1.352 838.012.051.777 0.000 69.93 8.23 180.0 8/21/2024 08:37 5.15365.47212.293 5.574 597.69210.710 0.000 0.000 35.3200.0009.564 4.193 5.4210.000 1.311 838.012.161.988 0.000 70.63 8.15 180.0 8/21/2024 08:38 5.09266.39612.244 5.568 596.19310.694 0.000 0.000 35.3100.0009.387 4.326 5.5200.000 1.314 838.012.291.891 0.000 71.49 8.21 180.0 8/21/2024 08:39 5.58366.93612.243 5.567 595.70810.929 0.000 0.000 35.1260.0009.418 4.265 5.5090.000 1.327 838.012.281.904 0.000 72.52 8.13 180.0 8/21/2024 08:40 5.17764.76312.284 5.565 595.87110.739 0.000 0.000 35.5750.0009.594 4.285 5.5340.000 1.329 838.012.311.895 0.000 69.94 8.09 180.0 8/21/2024 08:41 5.15864.05812.272 5.555 596.83010.718 0.000 0.000 35.8850.0009.720 4.450 5.4060.000 1.376 838.012.431.955 0.000 69.22 8.22 180.0 8/21/2024 08:42 5.09266.87112.283 5.581 595.24410.786 0.000 0.000 35.0520.0009.778 4.328 5.4000.000 1.366 838.012.321.947 0.001 71.96 8.22 180.0 8/21/2024 08:43 5.67563.94312.290 5.572 597.48510.972 0.000 0.000 35.5610.0009.331 4.330 5.5540.000 1.364 838.012.401.846 0.000 69.62 8.11 180.0 8/21/2024 08:44 5.46063.91012.303 5.570 596.79610.983 0.000 0.000 35.3520.0009.608 4.207 5.5220.000 1.348 838.012.241.833 0.000 69.37 8.24 180.0 8/21/2024 08:45 6.52568.26112.299 5.570 598.16310.721 0.000 0.000 35.0870.0009.304 4.190 5.3370.000 1.377 838.012.111.842 0.001 74.79 8.15 180.0 4.64964.16912.330 5.554 597.00510.778 0.000 0.099 35.5810.0009.563 4.231 5.5160.000 1.340 838.0012.2921.916 0.000 68.817 8.134 180.0Avg. Spike 1 8/21/2024 08:48 4.54878.12911.173 5.459 554.24959.740 0.000 0.439 28.1730.0007.847 5.802 28.3130.000 1.537 838.036.932.513 0.927 82.68 7.87 180.0 Run 1 - B 30minute/60min 8/21/2024 08:50 5.74663.68712.288 5.562 596.92610.858 0.000 0.000 35.3480.0009.921 4.316 5.5970.000 1.320 838.012.291.759 0.003 69.43 8.12 180.0 8/21/2024 08:51 6.05464.27812.269 5.562 597.62310.941 0.000 0.000 35.4870.0009.338 4.267 5.4400.000 1.374 838.012.111.608 0.000 70.33 8.13 180.0 8/21/2024 08:52 6.52565.34312.272 5.585 597.50810.693 0.000 0.000 35.4770.0009.434 4.077 5.5430.000 1.344 838.012.261.973 0.000 71.87 8.21 180.0 8/21/2024 08:54 6.13066.78612.278 5.567 595.72610.850 0.000 0.000 35.0250.0009.543 4.259 5.5880.000 1.316 838.012.321.895 0.000 72.92 8.20 180.0 8/21/2024 08:55 5.92264.92912.288 5.575 597.38210.714 0.000 0.000 35.3820.0009.136 4.240 5.5160.000 1.316 838.012.111.703 0.000 70.85 8.13 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 08:56 6.08265.18712.322 5.580 598.01610.763 0.000 0.000 35.5100.0009.774 4.393 5.6030.000 1.368 838.012.421.736 0.000 71.27 8.13 180.0 8/21/2024 08:57 5.79267.60412.260 5.565 595.99510.807 0.000 0.000 34.9980.0009.494 4.377 5.4950.000 1.356 838.012.171.567 0.000 73.40 8.31 180.0 8/21/2024 08:58 5.98567.18112.201 5.560 595.40010.868 0.000 0.000 35.0480.0009.608 4.337 5.3950.000 1.344 838.012.181.813 0.002 73.17 8.22 180.0 8/21/2024 08:59 6.47566.94212.201 5.566 596.14810.770 0.000 0.000 35.2380.0009.398 4.270 5.4510.000 1.346 838.012.111.685 0.000 73.42 8.21 180.0 8/21/2024 09:00 7.02665.08312.217 5.574 596.70710.782 0.000 0.000 35.5270.0009.660 4.353 5.4480.000 1.353 838.012.211.733 0.000 72.11 8.23 180.0 8/21/2024 09:01 5.92465.01812.206 5.576 596.82410.679 0.000 0.000 35.5240.0009.558 4.284 5.4670.000 1.361 838.012.231.783 0.000 70.94 8.22 180.0 8/21/2024 09:02 6.12665.03412.251 5.559 597.92510.884 0.000 0.000 35.7000.0009.554 4.444 5.5070.000 1.341 838.012.371.832 0.000 71.16 8.20 180.0 8/21/2024 09:03 6.15665.84212.257 5.575 598.44710.817 0.000 0.000 35.2620.0009.493 4.221 5.4850.000 1.354 838.012.211.804 0.000 72.00 8.24 180.0 8/21/2024 09:04 5.97765.31312.271 5.578 599.47010.444 0.000 0.000 35.8270.0009.378 4.302 5.5830.000 1.297 838.012.291.876 0.000 71.29 8.20 180.0 8/21/2024 09:05 6.24164.44712.311 5.580 600.21610.828 0.000 0.000 35.7990.0009.636 4.305 5.4650.000 1.370 838.012.291.814 0.000 70.69 8.14 180.0 8/21/2024 09:06 6.45664.79312.284 5.592 598.10310.623 0.000 0.000 35.4860.0009.420 4.220 5.4990.000 1.340 838.012.161.752 0.000 71.25 8.22 180.0 8/21/2024 09:07 6.25865.47812.280 5.586 597.20910.766 0.000 0.000 35.2100.0009.309 4.430 5.4590.000 1.340 838.012.321.847 0.003 71.74 8.23 180.0 8/21/2024 09:08 5.98464.69712.266 5.578 596.78710.532 0.000 0.000 35.4080.0009.415 4.175 5.5470.000 1.360 838.012.111.591 0.000 70.68 8.11 180.0 8/21/2024 09:09 6.12863.79212.267 5.566 596.27310.637 0.000 0.000 35.0820.0009.748 4.356 5.4820.000 1.373 838.012.311.769 0.000 69.92 8.13 180.0 8/21/2024 09:10 6.27364.14612.249 5.567 596.49710.586 0.000 0.000 35.3910.0009.376 4.284 5.5230.000 1.350 838.012.261.771 0.000 70.42 8.22 180.0 8/21/2024 09:11 5.80664.73112.230 5.563 597.00010.650 0.000 0.000 35.3830.0009.577 4.309 5.3930.000 1.356 838.012.231.874 0.000 70.54 8.23 180.0 8/21/2024 09:12 6.03864.04912.275 5.570 594.94710.791 0.000 0.000 35.0750.0019.252 4.453 5.4910.000 1.358 838.012.271.645 0.000 70.09 8.20 180.0 8/21/2024 09:13 5.45563.35712.283 5.583 596.54110.771 0.000 0.000 35.4470.0009.225 4.437 5.5590.000 1.341 838.012.401.807 0.000 68.81 8.22 180.0 8/21/2024 09:14 5.43863.95312.274 5.590 596.25110.408 0.000 0.000 35.3990.0009.306 4.269 5.3880.000 1.333 838.012.131.847 0.000 69.39 8.21 180.0 8/21/2024 09:15 5.81865.07812.299 5.597 595.14910.520 0.000 0.000 34.9280.0009.592 4.399 5.3010.000 1.374 838.012.211.844 0.000 70.90 8.23 180.0 8/21/2024 09:16 5.55964.37912.288 5.583 595.15910.864 0.000 0.000 35.2040.0009.175 4.466 5.4560.000 1.361 838.012.391.848 0.002 69.94 8.21 180.0 8/21/2024 09:17 6.73865.43812.302 5.577 593.11810.900 0.000 0.000 34.4960.0009.196 4.428 5.5440.000 1.364 838.012.311.632 0.000 72.18 8.30 180.0 8/21/2024 09:18 5.91365.32512.288 5.577 596.02410.383 0.000 0.000 34.9490.0009.464 4.256 5.4740.000 1.341 838.012.161.758 0.000 71.24 8.24 180.0 8/21/2024 09:19 5.68167.45112.249 5.585 593.64710.742 0.000 0.000 34.4570.0009.445 4.229 5.3330.000 1.401 838.012.121.744 0.000 73.13 8.22 180.0 8/21/2024 09:20 5.99164.56112.244 5.584 596.75110.732 0.000 0.000 35.3200.0009.237 4.280 5.5010.000 1.336 838.012.201.768 0.000 70.55 8.25 180.0 6.05765.13012.266 5.575 596.65910.720 0.000 0.000 35.2800.0009.455 4.315 5.4840.000 1.350 838.0012.2381.769 0.000 71.188 8.204 180.0Avg. 5.35364.64912.298 5.565 596.83210.749 0.000 0.050 35.4300.0009.509 4.273 5.5000.000 1.345 838.0012.2651.843 0.000 70.003 8.169 180.0Run 1 Avg: Baseline 1 8/21/2024 09:22 0.0000.2700.099 0.000 2.7680.554 0.145 0.405 0.3670.0130.000 0.158 0.0000.000 0.116 838.00.490.231 0.011 0.27 0.34 180.0 Run 2 - A 30minute/60min 8/21/2024 09:25 5.99066.52512.209 5.562 595.07610.774 0.000 0.000 35.0590.0009.797 4.473 5.5150.000 1.373 838.012.481.860 0.000 72.52 7.99 180.0 8/21/2024 09:26 5.55764.40512.248 5.573 595.70210.841 0.000 0.000 35.3600.0009.894 4.361 5.4730.000 1.356 838.012.381.929 0.000 69.96 8.10 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 09:27 5.69863.98312.245 5.566 597.30510.728 0.000 0.000 35.5300.0009.481 4.323 5.5700.000 1.351 838.012.261.659 0.000 69.68 8.03 180.0 8/21/2024 09:28 6.20665.53412.252 5.580 597.44610.922 0.000 0.000 35.2510.0009.658 4.409 5.6150.000 1.303 838.012.371.817 0.000 71.74 8.03 180.0 8/21/2024 09:30 5.72265.32112.260 5.572 596.68610.864 0.000 0.000 34.9440.0009.376 4.514 5.4900.000 1.336 838.012.371.803 0.000 71.04 8.02 180.0 8/21/2024 09:31 6.30064.20912.277 5.578 599.16710.843 0.000 0.000 35.6590.0009.687 4.285 5.5530.000 1.336 838.012.271.782 0.001 70.51 8.02 180.0 8/21/2024 09:32 6.03667.00212.301 5.586 596.26910.855 0.000 0.000 35.0860.0009.383 4.407 5.4340.000 1.325 838.012.161.709 0.000 73.04 8.13 180.0 8/21/2024 09:33 5.95764.85112.299 5.592 596.38810.877 0.000 0.000 35.1310.0009.396 4.355 5.5260.000 1.349 838.012.321.789 0.000 70.81 8.13 180.0 8/21/2024 09:34 5.83266.64712.322 5.592 599.12510.835 0.000 0.000 35.5370.0009.721 4.275 5.5250.000 1.338 838.012.201.725 0.000 72.48 8.04 180.0 8/21/2024 09:35 6.62464.73412.313 5.602 599.84910.877 0.000 0.000 35.7770.0009.615 4.363 5.4310.000 1.358 838.012.311.876 0.000 71.36 8.11 180.0 8/21/2024 09:36 5.68863.27912.342 5.595 602.10710.880 0.000 0.000 36.3220.0009.599 4.473 5.4360.000 1.361 838.012.351.812 0.000 68.97 8.01 180.0 8/21/2024 09:37 6.13964.21412.310 5.588 599.16610.648 0.000 0.000 35.7180.0029.467 4.405 5.5050.000 1.341 838.012.341.820 0.000 70.35 8.12 180.0 8/21/2024 09:38 6.39064.75312.295 5.588 599.72610.647 0.000 0.000 35.7990.0009.251 4.463 5.5230.000 1.336 838.012.491.982 0.000 71.14 8.13 180.0 8/21/2024 09:39 6.20164.99712.299 5.583 596.12710.814 0.000 0.000 35.2890.0009.223 4.411 5.4650.000 1.349 838.012.351.877 0.000 71.20 8.21 180.0 8/21/2024 09:40 5.60665.42012.280 5.579 597.18710.498 0.000 0.000 35.2360.0009.280 4.342 5.4920.000 1.376 838.012.321.767 0.000 71.03 8.12 180.0 8/21/2024 09:41 5.88364.03312.331 5.594 597.08410.920 0.000 0.000 35.2270.0009.523 4.470 5.5080.000 1.359 838.012.451.870 0.000 69.92 8.11 180.0 8/21/2024 09:42 6.21864.37112.289 5.561 598.79011.083 0.000 0.000 35.7980.0009.120 4.293 5.4230.000 1.330 838.012.302.035 0.000 70.59 8.09 180.0 8/21/2024 09:43 6.21665.01912.289 5.556 598.75810.826 0.000 0.000 35.3850.0008.804 4.430 5.3820.000 1.365 838.012.381.972 0.000 71.23 8.04 180.0 8/21/2024 09:44 6.16464.11612.322 5.576 597.42310.962 0.000 0.000 35.3470.0009.538 4.328 5.3740.000 1.383 838.012.251.839 0.000 70.28 8.21 180.0 8/21/2024 09:45 5.75164.89012.293 5.586 598.03110.757 0.000 0.000 35.3020.0009.805 4.551 5.3230.000 1.366 838.012.201.670 0.000 70.64 8.21 180.0 8/21/2024 09:46 6.48964.78112.289 5.583 598.33610.896 0.000 0.000 35.4530.0009.187 4.286 5.5280.000 1.367 838.012.331.811 0.000 71.27 8.10 180.0 8/21/2024 09:47 5.74463.56412.294 5.581 598.19010.770 0.000 0.000 35.6100.0009.173 4.320 5.5100.000 1.367 838.012.361.856 0.001 69.31 8.20 180.0 8/21/2024 09:48 7.34068.43612.339 5.604 597.75210.697 0.000 0.000 35.1890.0009.430 4.281 5.4350.000 1.368 838.012.201.762 0.000 75.78 8.21 180.0 8/21/2024 09:49 6.13363.96612.345 5.603 598.93510.878 0.000 0.000 35.4310.0009.427 4.264 5.3880.000 1.347 838.012.091.746 0.001 70.10 8.15 180.0 8/21/2024 09:50 6.40263.60312.340 5.589 600.00910.818 0.000 0.000 35.5410.0009.436 4.316 5.6130.000 1.339 838.012.341.755 0.000 70.00 8.14 180.0 8/21/2024 09:51 5.91063.55212.362 5.593 597.91810.997 0.000 0.000 35.3110.0009.235 4.403 5.4390.000 1.348 838.012.231.737 0.000 69.46 8.13 180.0 8/21/2024 09:52 6.12764.18612.317 5.581 597.21010.744 0.000 0.000 34.8990.0009.202 4.310 5.5340.000 1.363 838.012.361.838 0.000 70.31 8.10 180.0 8/21/2024 09:53 6.01065.49912.299 5.580 597.60910.848 0.000 0.000 35.3430.0009.274 4.424 5.4420.000 1.367 838.012.381.878 0.000 71.51 8.20 180.0 8/21/2024 09:54 6.33764.74512.334 5.589 598.25610.940 0.000 0.000 35.3800.0009.720 4.395 5.4190.000 1.360 838.012.281.812 0.000 71.08 8.12 180.0 8/21/2024 09:55 6.82564.61312.335 5.585 599.93910.930 0.000 0.000 35.9430.0009.326 4.464 5.4700.000 1.376 838.012.351.731 0.000 71.44 8.23 180.0 6.11764.84212.301 5.583 598.05210.832 0.000 0.000 35.4290.0009.434 4.380 5.4780.000 1.353 838.0012.3161.817 0.000 70.958 8.114 180.0Avg. Spike 2 8/21/2024 09:58 6.39374.05211.313 5.396 554.73747.613 0.000 0.199 28.2120.0067.695 5.528 22.8830.000 1.599 838.031.182.126 0.710 80.44 7.88 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/21/2024 10:01 6.07064.30112.343 5.570 597.59911.048 0.000 0.000 35.4480.0009.456 4.232 5.4980.000 1.376 838.012.361.936 0.005 70.37 8.09 180.0 8/21/2024 10:02 6.34464.92512.333 5.582 595.19011.064 0.000 0.000 35.0750.0009.405 4.336 5.4500.000 1.382 838.012.411.965 0.001 71.27 8.23 180.0 8/21/2024 10:03 6.70966.54512.327 5.585 595.48211.021 0.000 0.000 35.1280.0008.925 4.335 5.4500.000 1.405 838.012.371.828 0.000 73.25 8.22 180.0 8/21/2024 10:04 6.78664.99712.316 5.590 597.66711.022 0.000 0.000 35.1560.0009.428 4.226 5.5050.000 1.352 838.012.382.032 0.000 71.78 8.31 180.0 8/21/2024 10:06 6.07464.80312.343 5.595 597.43610.877 0.000 0.000 35.2670.0009.564 4.414 5.5340.000 1.353 838.012.461.918 0.002 70.88 8.12 180.0 8/21/2024 10:07 5.85062.12512.340 5.589 598.26310.853 0.000 0.000 35.5700.0009.527 4.232 5.4820.000 1.358 838.012.352.000 0.000 67.98 8.12 180.0 8/21/2024 10:08 6.09765.16312.354 5.579 596.34311.043 0.000 0.000 35.2070.0009.251 4.476 5.4630.000 1.395 838.012.531.932 0.000 71.26 8.11 180.0 8/21/2024 10:09 6.36365.64512.368 5.573 597.10710.899 0.000 0.000 35.4670.0009.636 4.358 5.4690.000 1.367 838.012.301.786 0.000 72.01 8.31 180.0 8/21/2024 10:10 5.81264.25512.352 5.598 598.64410.993 0.000 0.000 35.5610.0009.364 4.379 5.4160.000 1.399 838.012.411.916 0.000 70.07 8.22 180.0 8/21/2024 10:11 6.85668.34412.400 5.571 598.78311.106 0.000 0.000 35.3780.0009.257 4.313 5.3200.000 1.421 838.012.291.875 0.000 75.20 8.20 180.0 8/21/2024 10:12 5.82464.56312.411 5.611 598.17311.063 0.000 0.000 35.5840.0008.934 4.206 5.4010.000 1.385 838.012.201.842 0.000 70.39 8.10 180.0 8/21/2024 10:13 6.51464.71012.394 5.606 598.17211.050 0.000 0.000 35.2410.0009.272 4.487 5.5680.000 1.374 838.012.541.842 0.000 71.22 8.22 180.0 8/21/2024 10:14 5.88463.99912.387 5.603 599.12311.093 0.000 0.000 35.4270.0009.285 4.294 5.4140.000 1.386 838.012.291.855 0.002 69.88 8.12 180.0 8/21/2024 10:15 6.14763.50212.391 5.566 597.14111.016 0.000 0.000 35.2540.0009.525 4.366 5.5420.000 1.373 838.012.531.995 0.003 69.65 8.21 180.0 8/21/2024 10:16 6.67867.12212.366 5.571 594.43511.041 0.000 0.000 34.5680.0009.134 4.414 5.4930.000 1.385 838.012.461.885 0.001 73.80 8.24 180.0 8/21/2024 10:17 6.77566.73412.388 5.576 598.25110.860 0.000 0.000 35.1550.0009.309 4.276 5.4050.000 1.361 838.012.191.818 0.000 73.51 8.22 180.0 8/21/2024 10:18 6.75267.67412.409 5.607 598.10011.166 0.000 0.000 35.0820.0009.109 4.235 5.4140.000 1.394 838.012.161.706 0.000 74.43 8.30 180.0 8/21/2024 10:19 6.48562.91712.399 5.598 599.39710.996 0.000 0.000 35.4850.0009.244 4.332 5.5020.000 1.360 838.012.321.812 0.000 69.40 8.11 180.0 8/21/2024 10:20 6.07164.08312.422 5.608 600.33011.107 0.000 0.000 35.6500.0009.527 4.457 5.4890.000 1.387 838.012.511.909 0.002 70.15 8.24 180.0 8/21/2024 10:21 6.29764.48012.401 5.566 600.41311.083 0.000 0.000 35.6980.0009.621 4.198 5.4360.000 1.398 838.012.341.965 0.000 70.78 8.14 180.0 8/21/2024 10:22 6.22963.84712.402 5.564 600.19910.724 0.000 0.000 35.4550.0009.254 4.331 5.5310.000 1.370 838.012.431.912 0.000 70.08 8.23 180.0 8/21/2024 10:23 6.55266.25612.424 5.587 596.19711.076 0.000 0.000 35.0310.0009.080 4.343 5.3060.000 1.402 838.012.251.873 0.001 72.81 8.30 180.0 8/21/2024 10:24 6.02965.36412.393 5.571 599.03610.898 0.000 0.000 35.2340.0009.319 4.141 5.4490.000 1.353 838.012.191.909 0.001 71.39 8.23 180.0 8/21/2024 10:25 6.39863.58412.420 5.577 597.47811.182 0.000 0.000 35.3450.0009.237 4.389 5.5740.000 1.339 838.012.361.772 0.000 69.98 8.12 180.0 8/21/2024 10:26 5.83963.42612.417 5.569 596.77411.088 0.000 0.000 35.1840.0009.085 4.462 5.4680.000 1.366 838.012.481.953 0.000 69.26 8.24 180.0 8/21/2024 10:27 6.69468.88912.429 5.597 593.77611.090 0.000 0.000 34.2060.0009.218 4.174 5.3870.000 1.376 838.012.221.942 0.001 75.58 8.31 180.0 8/21/2024 10:28 6.36266.90112.394 5.601 596.19510.879 0.000 0.000 34.6940.0009.600 4.296 5.5420.000 1.381 838.012.391.835 0.000 73.26 8.20 180.0 8/21/2024 10:29 6.58164.83712.404 5.595 598.64911.143 0.000 0.000 34.9980.0009.034 4.174 5.3990.000 1.380 838.012.101.740 0.000 71.42 8.22 180.0 8/21/2024 10:30 6.51164.13512.412 5.564 598.86511.180 0.000 0.000 35.4170.0019.209 4.403 5.4830.000 1.379 838.012.471.945 0.001 70.65 8.12 180.0 8/21/2024 10:31 6.29963.77712.456 5.570 598.84211.032 0.000 0.000 35.2850.0009.011 4.334 5.4740.000 1.371 838.012.441.997 0.000 70.08 8.10 180.0 6.32965.06312.387 5.585 597.73511.023 0.000 0.000 35.2420.0009.294 4.320 5.4620.000 1.378 838.0012.3581.890 0.001 71.393 8.197 180.0Avg. 6.22364.95312.344 5.584 597.89410.928 0.000 0.000 35.3350.0009.364 4.350 5.4700.000 1.365 838.0012.3371.854 0.000 71.176 8.156 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/21/2024 10:34 0.0000.0000.083 0.000 1.5210.666 0.132 0.285 0.0000.0030.234 0.000 0.0000.000 0.142 838.00.560.412 0.010 0.00 0.24 180.0 Run 3 - A 30minute/60min 8/21/2024 10:37 5.90064.09912.371 5.540 598.57210.934 0.000 0.000 35.4110.0009.445 4.110 5.4670.000 1.387 838.012.271.927 0.000 70.00 7.91 180.0 8/21/2024 10:38 6.25363.39612.359 5.578 598.27011.010 0.000 0.000 35.3760.0009.691 4.213 5.4720.000 1.361 838.012.261.891 0.001 69.65 7.98 180.0 8/21/2024 10:39 6.26163.31412.381 5.590 600.95011.086 0.000 0.000 35.6960.0009.575 4.200 5.4730.000 1.381 838.012.241.809 0.001 69.57 8.10 180.0 8/21/2024 10:41 6.19764.08112.353 5.568 598.37710.768 0.000 0.000 35.2790.0009.014 4.228 5.5280.000 1.373 838.012.421.985 0.000 70.28 8.10 180.0 8/21/2024 10:42 6.50364.15012.346 5.566 599.59410.916 0.000 0.000 35.6240.0008.832 4.363 5.5150.000 1.378 838.012.351.752 0.001 70.65 8.09 180.0 8/21/2024 10:43 5.89261.67912.348 5.577 600.13410.709 0.000 0.000 35.9760.0009.575 4.021 5.6300.000 1.355 838.012.341.976 0.000 67.57 8.09 180.0 8/21/2024 10:44 5.84261.50412.352 5.582 600.50910.726 0.000 0.000 35.7160.0009.280 4.198 5.6030.000 1.356 838.012.311.795 0.000 67.35 8.09 180.0 8/21/2024 10:45 5.37362.66912.366 5.584 594.55810.906 0.000 0.000 34.7600.0009.372 4.204 5.5050.000 1.377 838.012.311.864 0.000 68.04 8.09 180.0 8/21/2024 10:46 6.23464.64412.377 5.566 597.33910.610 0.000 0.000 35.2010.0009.275 4.338 5.4520.000 1.410 838.012.441.913 0.000 70.88 8.22 180.0 8/21/2024 10:47 6.09663.28312.415 5.584 596.47910.827 0.000 0.000 35.4030.0008.958 4.474 5.5680.000 1.376 838.012.662.030 0.000 69.38 8.02 180.0 8/21/2024 10:48 5.10962.39312.412 5.592 595.83711.117 0.000 0.000 34.8710.0009.257 4.099 5.6400.000 1.386 838.012.532.075 0.000 67.50 8.09 180.0 8/21/2024 10:49 5.37763.34212.399 5.578 595.06310.936 0.000 0.000 34.5680.0008.877 4.416 5.4640.000 1.406 838.012.521.955 0.000 68.72 8.13 180.0 8/21/2024 10:50 5.86664.49312.408 5.560 593.44410.877 0.000 0.000 34.3370.0009.315 4.275 5.4210.000 1.441 838.012.341.777 0.002 70.36 8.20 180.0 8/21/2024 10:51 6.27665.88112.366 5.557 595.44710.942 0.000 0.000 34.2520.0009.275 4.230 5.4340.000 1.443 838.012.482.018 0.000 72.16 8.20 180.0 8/21/2024 10:52 6.39464.48412.360 5.555 596.03810.779 0.000 0.000 34.8360.0008.828 4.195 5.4770.000 1.411 838.012.432.004 0.000 70.88 8.21 180.0 8/21/2024 10:53 6.36466.35712.347 5.571 594.56910.617 0.000 0.000 34.3490.0008.926 4.275 5.4080.000 1.430 838.012.391.906 0.000 72.72 8.14 180.0 8/21/2024 10:54 6.03664.69112.373 5.569 596.35410.955 0.000 0.000 34.9330.0009.505 4.240 5.3670.000 1.406 838.012.291.919 0.000 70.73 8.13 180.0 8/21/2024 10:55 5.85063.65712.387 5.582 596.26210.822 0.000 0.000 34.7020.0009.017 4.111 5.4150.000 1.437 838.012.341.967 0.000 69.51 8.14 180.0 8/21/2024 10:56 5.76362.79912.391 5.553 596.61110.856 0.000 0.000 34.5210.0008.917 4.235 5.4290.000 1.411 838.012.391.980 0.000 68.56 8.22 180.0 8/21/2024 10:57 6.61167.58812.397 5.567 595.27210.848 0.000 0.000 34.4960.0009.198 4.294 5.5020.000 1.410 838.012.451.901 0.000 74.20 8.24 180.0 8/21/2024 10:58 6.57267.66412.412 5.573 596.87311.061 0.000 0.000 34.5400.0008.930 4.321 5.4230.000 1.421 838.012.381.843 0.000 74.24 8.22 180.0 8/21/2024 10:59 5.96462.59612.413 5.579 596.07511.172 0.000 0.000 35.0990.0008.863 4.146 5.4420.000 1.393 838.012.422.145 0.000 68.56 8.02 180.0 8/21/2024 11:00 5.97163.12212.424 5.576 598.16611.100 0.000 0.000 35.1700.0008.221 4.203 5.4240.000 1.391 838.012.372.045 0.003 69.09 8.21 180.0 8/21/2024 11:01 5.92466.06112.389 5.563 595.62910.831 0.000 0.000 34.5490.0008.837 4.209 5.4080.000 1.437 838.012.401.968 0.000 71.99 8.23 180.0 8/21/2024 11:02 5.96464.46312.366 5.563 594.32711.078 0.000 0.000 34.4050.0008.693 4.209 5.4390.000 1.411 838.012.271.802 0.000 70.43 8.21 180.0 8/21/2024 11:03 6.34464.27612.387 5.571 596.99110.781 0.000 0.000 34.7840.0008.455 4.276 5.5760.000 1.379 838.012.471.920 0.000 70.62 8.20 180.0 8/21/2024 11:04 5.53962.28712.380 5.556 599.71210.795 0.000 0.000 35.4920.0009.093 4.370 5.6560.000 1.392 838.012.671.975 0.001 67.83 8.12 180.0 8/21/2024 11:05 5.85262.58112.401 5.559 597.82310.841 0.000 0.000 35.3010.0008.933 4.307 5.5120.000 1.381 838.012.441.937 0.000 68.43 8.42 180.0 8/21/2024 11:06 6.46867.25512.375 5.568 593.22110.817 0.000 0.000 34.4510.0009.104 4.195 5.3980.000 1.431 838.012.311.886 0.000 73.72 8.32 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 11:07 5.97864.14212.350 5.561 594.57410.821 0.000 0.000 34.2880.0008.411 4.324 5.3560.000 1.419 838.012.492.124 0.000 70.12 8.20 180.0 6.02664.09812.380 5.570 596.76910.885 0.000 0.000 34.9460.0009.056 4.243 5.4800.000 1.400 838.0012.3991.936 0.000 70.125 8.151 180.0Avg. Spike 3 8/21/2024 11:10 4.18878.47411.337 5.434 554.07755.022 0.000 0.065 27.5870.0007.107 5.694 25.6050.000 1.557 838.034.242.579 0.815 82.66 7.99 180.0 Run 3 - B 30minute/60min 8/21/2024 11:12 6.70567.18512.370 5.555 595.50111.439 0.000 0.000 34.8600.0008.774 4.368 5.5240.000 1.400 837.012.551.969 0.006 73.89 8.28 180.0 8/21/2024 11:13 6.27164.62412.360 5.560 598.71210.925 0.000 0.000 35.3850.0008.944 4.206 5.5060.000 1.439 837.012.511.986 0.000 70.89 8.22 180.0 8/21/2024 11:14 5.50463.34812.334 5.546 595.54210.870 0.000 0.000 34.5710.0008.573 4.264 5.3570.000 1.440 838.012.432.020 0.001 68.85 8.22 180.0 8/21/2024 11:15 6.09263.10112.367 5.569 597.30811.105 0.000 0.000 35.1370.0008.556 4.208 5.4650.000 1.399 837.012.381.966 0.000 69.19 8.22 180.0 8/21/2024 11:16 6.37263.46712.372 5.559 597.02210.595 0.000 0.000 34.8630.0008.817 4.111 5.6500.000 1.375 837.012.482.007 0.000 69.84 8.20 180.0 8/21/2024 11:17 5.90163.19912.344 5.567 596.76211.035 0.000 0.000 34.6040.0009.004 4.248 5.4190.000 1.444 837.012.512.050 0.000 69.10 8.21 180.0 8/21/2024 11:19 5.90563.28012.348 5.560 596.22311.033 0.000 0.000 34.9960.0008.401 4.228 5.5170.000 1.430 837.012.411.823 0.000 69.19 8.21 180.0 8/21/2024 11:20 5.84062.43112.401 5.561 595.12211.026 0.000 0.000 34.6100.0008.553 4.384 5.5260.000 1.428 837.012.652.012 0.000 68.27 8.12 180.0 8/21/2024 11:21 5.89166.78512.394 5.567 594.79211.144 0.000 0.000 33.9580.0008.839 4.192 5.3560.000 1.464 837.012.361.930 0.000 72.68 8.31 180.0 8/21/2024 11:22 6.58266.94012.383 5.575 594.65211.025 0.000 0.000 33.9270.0008.778 4.238 5.3740.000 1.433 837.012.442.059 0.003 73.52 8.24 180.0 8/21/2024 11:23 5.79862.75812.371 5.567 599.26711.193 0.000 0.000 35.0520.0008.443 4.168 5.4110.000 1.424 837.012.442.098 0.000 68.56 8.11 180.0 8/21/2024 11:24 6.59264.34212.389 5.560 599.64111.143 0.000 0.000 34.9820.0008.744 4.359 5.4820.000 1.362 837.012.391.915 0.000 70.93 8.31 180.0 8/21/2024 11:25 6.50564.71412.369 5.557 598.41511.132 0.000 0.000 34.9420.0008.884 4.075 5.3980.000 1.429 837.012.261.925 0.000 71.22 8.22 180.0 8/21/2024 11:26 6.58364.37012.366 5.584 598.80511.043 0.000 0.000 35.4460.0009.152 4.464 5.4540.000 1.394 837.012.431.823 0.001 70.95 8.23 180.0 8/21/2024 11:27 6.34365.75012.361 5.552 597.25710.989 0.000 0.000 34.5330.0008.521 4.213 5.4240.000 1.412 837.012.391.997 0.000 72.09 8.30 180.0 8/21/2024 11:28 5.91163.57012.326 5.563 598.76411.062 0.000 0.000 35.1090.0008.674 4.223 5.4450.000 1.425 837.012.431.980 0.000 69.48 8.21 180.0 8/21/2024 11:29 5.50361.92212.296 5.552 598.17511.120 0.000 0.000 35.2600.0008.409 4.172 5.5280.000 1.419 837.012.492.012 0.000 67.42 8.20 180.0 8/21/2024 11:30 5.64461.38012.332 5.550 596.15611.023 0.000 0.000 35.0200.0008.406 4.372 5.5260.000 1.410 837.012.622.044 0.000 67.02 8.23 180.0 8/21/2024 11:31 5.58563.35512.336 5.552 595.51410.825 0.000 0.000 34.5130.0008.713 4.274 5.3740.000 1.440 837.012.431.996 0.001 68.94 8.23 180.0 8/21/2024 11:32 6.22466.88912.358 5.553 593.02610.891 0.000 0.000 34.0200.0008.863 4.308 5.4380.000 1.451 837.012.411.791 0.000 73.11 8.33 180.0 8/21/2024 11:33 6.40967.52812.323 5.562 597.34310.837 0.000 0.000 34.4500.0008.514 4.301 5.4470.000 1.429 837.012.401.840 0.002 73.94 8.33 180.0 8/21/2024 11:34 6.18863.91012.353 5.582 599.33910.798 0.000 0.000 35.3450.0008.800 4.376 5.4170.000 1.416 837.012.532.038 0.001 70.10 8.23 180.0 8/21/2024 11:35 6.02862.77612.324 5.549 596.77210.977 0.000 0.000 34.9780.0008.704 4.263 5.6470.000 1.382 837.012.602.028 0.000 68.80 8.31 180.0 8/21/2024 11:36 6.33666.36912.360 5.565 598.16311.020 0.000 0.000 35.0240.0008.564 4.246 5.4380.000 1.452 837.012.592.123 0.000 72.70 8.33 180.0 8/21/2024 11:37 6.82266.04012.345 5.578 596.03410.964 0.000 0.000 34.5860.0008.887 4.236 5.3440.000 1.489 837.012.451.962 0.000 72.86 8.31 180.0 8/21/2024 11:38 6.38464.59312.327 5.550 597.64310.973 0.000 0.000 34.7760.0008.609 4.334 5.4080.000 1.462 837.012.501.912 0.000 70.98 8.31 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 11:39 6.07663.54112.307 5.550 599.71710.914 0.000 0.000 35.3880.0008.705 4.430 5.4840.000 1.472 837.012.711.996 0.000 69.62 8.31 180.0 8/21/2024 11:40 6.26465.93412.336 5.543 596.80510.732 0.000 0.000 34.9520.0008.240 4.271 5.5110.000 1.433 837.012.491.901 0.001 72.20 8.32 180.0 8/21/2024 11:41 6.33364.06312.340 5.559 598.71510.801 0.000 0.000 35.5250.0008.885 4.429 5.5950.000 1.423 837.012.701.963 0.001 70.40 8.23 180.0 8/21/2024 11:42 5.74063.29412.324 5.555 599.96310.620 0.000 0.000 36.0600.0008.462 4.234 5.5460.000 1.379 837.012.482.030 0.000 69.03 8.30 180.0 6.14464.38212.351 5.560 597.23810.975 0.000 0.000 34.8960.0008.681 4.273 5.4670.000 1.425 837.0312.4821.973 0.001 70.526 8.253 180.0Avg. 6.08564.24012.365 5.565 597.00410.930 0.000 0.000 34.9210.0008.868 4.258 5.4740.000 1.412 837.5212.4411.955 0.000 70.325 8.202 180.0Run 3 Avg: Baseline 3 8/21/2024 11:44 0.0000.0000.104 0.000 3.3570.668 0.180 0.331 0.1640.0210.420 0.000 0.0000.000 0.145 837.00.550.385 0.014 0.00 0.39 180.0 Post CTS 8/21/2024 11:46 0.0000.0000.071 0.000 0.0280.368 0.104 0.461 0.1220.0000.000 100.086 0.0000.000 0.225 837.067.600.627 0.011 0.00 0.21 180.0 8/21/2024 11:46 0.0000.0000.066 0.000 0.0000.660 0.103 0.199 0.0000.0000.541 100.152 0.0000.000 0.266 837.067.360.088 0.011 0.00 0.20 180.0 8/21/2024 11:46 0.0000.0000.066 0.000 0.0000.491 0.069 0.660 0.0000.0000.000 100.926 0.0000.000 0.208 837.067.970.407 0.016 0.00 0.20 180.0 Post NO2/Mid O2 8/21/2024 11:50 97.0410.9320.048 0.000 1.1260.782 0.410 0.369 0.1090.0010.615 0.000 0.0000.545 0.153 837.00.660.523 0.006 97.97 10.84 180.0 8/21/2024 11:50 97.8590.8570.044 0.000 1.0100.397 0.400 0.277 0.0000.0030.000 0.000 0.0001.315 0.262 837.00.820.440 0.000 98.72 10.76 180.0 8/21/2024 11:50 98.0950.6160.046 0.000 1.4710.385 0.415 0.507 0.3850.0000.000 0.000 0.0000.633 0.209 837.00.720.452 0.003 98.71 10.83 180.0 Post 5-Gas 8/21/2024 11:52 0.000234.2570.062 4.554 3.784494.010 1.307 1.880 5.7100.1142.826 1.735 251.6670.767 0.000 837.0254.923.150 9.905 234.26 0.13 180.0 8/21/2024 11:52 0.000235.5180.059 4.566 3.170498.800 1.365 1.265 5.5680.1331.339 1.639 253.0580.151 0.000 837.0256.433.412 9.930 235.52 0.14 180.0 8/21/2024 11:52 0.000236.3050.058 4.535 2.963498.982 1.384 1.740 5.5610.2490.255 1.671 253.4760.000 0.000 837.0256.552.941 9.945 236.30 0.14 180.0 8/21/2024 11:52 0.000236.7240.042 4.561 3.098504.760 1.282 1.888 6.1940.2871.827 1.621 253.9880.000 0.000 837.0257.513.655 9.963 236.72 0.13 180.0 8/21/2024 11:52 0.000236.5320.056 4.583 1.968504.223 1.283 1.573 5.4070.2961.020 1.577 254.4220.000 0.000 837.0257.242.649 9.974 236.53 0.14 180.0 8/21/2024 11:52 0.000237.0130.043 4.611 4.201498.652 1.257 1.551 7.1840.4260.636 1.379 253.9030.258 0.000 837.0257.023.295 10.032 237.01 0.14 180.0 8/21/2024 11:52 0.000236.5460.051 4.561 2.644501.829 1.363 1.414 5.3050.2700.000 1.602 254.4290.000 0.000 837.0257.252.637 9.973 236.55 0.15 180.0 End of Test Purge 8/21/2024 11:54 0.0000.9440.039 0.008 0.0632.396 0.024 0.000 0.0540.0120.613 0.000 0.8470.000 0.107 837.01.430.548 0.040 0.94 0.16 180.0 8/21/2024 11:55 0.0001.6580.047 0.000 0.6712.185 0.146 0.250 0.1410.0490.000 0.485 0.4920.503 0.178 837.01.480.455 0.034 1.66 0.15 180.0 8/21/2024 11:55 0.8390.2110.043 0.000 0.6851.665 0.122 0.284 0.1700.0090.469 0.000 0.3910.110 0.101 837.00.590.000 0.030 1.05 0.15 180.0 8/21/2024 11:55 0.0001.2110.044 0.000 0.7521.655 0.106 0.503 0.0340.0071.067 0.000 0.3510.000 0.117 837.00.810.339 0.026 1.21 0.15 180.0 8/21/2024 11:55 0.0000.8860.044 0.000 0.1941.674 0.128 0.273 0.3630.0910.753 0.000 0.3750.000 0.115 837.00.930.494 0.020 0.89 0.15 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/21/2024 11:55 0.0001.0290.049 0.000 0.0051.393 0.096 0.034 0.0000.0480.422 0.308 0.2290.000 0.215 837.01.180.478 0.019 1.03 0.15 180.0 8/21/2024 11:55 0.0001.2320.046 0.000 1.1671.318 0.073 0.202 0.0000.0241.123 0.115 0.4930.000 0.075 837.01.230.760 0.013 1.23 0.15 180.0 8/21/2024 11:55 0.0000.0000.043 0.000 0.5320.959 0.079 0.000 0.0000.1580.000 0.000 0.3710.000 0.072 837.01.050.798 0.012 0.00 0.15 180.0 8/21/2024 11:55 0.0000.0000.042 0.000 0.5451.000 0.106 0.411 0.1320.0200.314 0.430 0.4270.000 0.048 837.01.150.506 0.017 0.00 0.15 180.0 GAS, Inc. Performance Test Report Test Type: Annual Test Date: 8/6/2024 Caterpillar G3516 TALE Lean Burn (4 Cycle) DOM: 1/23/19 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:09:03 AM 01:31 PM Source: Unit Number: 1 Serial Number: 4EK04758 Engine Hours:37505.3 Permit #: #DAQE-AN142100007-23 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Pleasant Valley Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 0.360 2.950 0.980 0.000 1.140 0.373 0.000 54.258 18.513 2.000 1.000 0.700 0.000 0.498 0.163 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Ovintiv USA Inc. 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 klye muir 3 Logan Miller Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit 1 with a serial number of 4EK04758 which is a Caterpillar G3516 TALE engine located at Pleasant Valley Compressor Station and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/6/2024 by Logan Miller with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1340 brake horse power (BHP) at 1400 RPM. The engine was operating at 1039 BHP and 1362 RPM which is 77.57% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit 1 is authorized to operate under permit #DAQE-AN142100007-23. 4 4.0 Test Summary Engine/Compressor Specs Pleasant Valley Compressor StationLocation 1Unit ID Make Caterpillar Site Elevation ft.5354 Model G3516 TALE Atmospheric Pressure psi.12.17 Serial Number 4EK04758 Stack Diameter in.14 mfg. rated hp 1340 Yes 1400 Date of Manufacture 1/23/2019 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1039 1039 1040 1039 1361 1361 1363 1362 Percent Load % Intake Manifold Pressure (hg) 77.53%77.53%77.64%77.57% 34.88 34.88 34.88 34.88 Intake Manifold Temperature (F)147.20 147.60 147.90 147.57 Ambient Conditions Ambient Temperature Dry (F)73.00 83.00 94.00 83.33 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 179022.41 171694.94 177438.83 176052.06 5069.30 4861.81 5024.46 4985.19 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.10 0.10 0.10 0.10 9380.96 9380.96 9379.11 9380.3433333333 333333Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %9.78%9.73%9.80%9.77% T e s t S u m m a r y mfg. rated rpm Test RPM 11.54%11.52%11.35%11.47% Permitted Standards Results 5 Catalyst 0.0000.000 Run 1 Run 2 Run 3 3 Run Average Pass Permits 09:03 AM 10:27 AM 12:10 PM 8/6/2024 CO (g/hp-hr)0.000 0.0002.000 Pass StateFederal CO (ppmvw)0.000 0.000 0.000 0.000 CO (ppmvd)0.000 0.000 0.000 0.000 CO (mol wt) 28.01 CO (ppmvd) @15% O2 0.000 0.000 0.000 0.000 Fail CO (ppbvd) @15% O2 0.000 0.000 0.000 0.000 Fail 0.0000.000CO (lbs/hr)0.000 0.0000.360 Pass NOx (g/hp-hr)0.475 0.456 0.562 0.4981.000 Pass NOx (ppmvw)45.965 46.051 54.858 48.958 NOx (ppmvd)50.945 51.012 60.816 54.258 NOx (mol wt) 46.01 16.503 16.811 16.802 16.705NMNEHC (ppmvw) 18.291 18.622 18.626 18.513NMNEHC (ppmvd) NOx (ppbvd) @15% O2 32107.311 32073.992 37570.490 33917.264 Fail NOx (ppmvd) @15% O2 32.107 32.074 37.570 33.917 Fail NMNEHC (mol wt) 44.10 11527.394 11708.795 11506.915 11581.035 FailNMNEHC (ppbvd) @15% O2 0.164 0.160 0.165 0.1630.700 PassNMNEHC (g/hp-hr) 0.375 0.366 0.378 0.3730.980 PassNMNEHC (lbs/hr) 11.527 11.709 11.507 11.581 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)1.089 1.045 1.288 1.1402.950 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.39Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 0.00 0.18 43.42 0.00 2.55 0.18 45.96 0.76 16.50 0.00% 10.16% 0.00% 9.78% NMNEHC 0.00 42.37 2.50 44.87 16.28 10.18%9.77% 42.02 60.08 0.00 60.08 36.83 9.52%8.89% 0.00 44.47 2.59 47.06 16.73 10.14%9.78% 0.23 0.12 0.00 0.12 0.74 0.00%0.05% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.23 0.12 0.00 0.12 0.74 0.00%0.05% 0.00 42.10 1.82 43.91 17.01 10.09%9.72% 34.95 51.17 1.99 53.16 35.64 9.48%8.88% 0.00 45.59 2.60 48.19 16.61 10.19%9.73% 0.00 0.00 0.00 0.00 0.24 0.00%0.00% Avg. Wet 0.00 43.84 2.21 46.05 16.81 10.14%9.73% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 49.62 2.15 51.77 16.85 9.95%9.77% 43.34 62.01 0.00 62.01 37.93 9.41%8.89% 0.00 55.18 2.76 57.95 16.75 10.03%9.82% 0.08 0.00 0.00 0.00 0.95 0.00%0.03% 0.00 0.00 0.00 0.00 0.24 0.00%0.00% Avg. Wet 0.00 52.40 2.46 54.86 16.80 9.99%9.80% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 14 inches or:1.17 feet. or:1.07 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 1.69 Yes 14.00 230.00 56.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 9.78 29.16 1.58 Inches 2.34 7 11.66 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 4.73 10.16 0.00 841.02 0.12 24.84 24.96 719.50 1179.17 381.94 28.07 138.05 147.57 198422.14 179022.41 Run 2 9.73 29.16 1.46 4.68 10.15 0.00 840.68 0.11 24.83 24.94 721.44 1181.11 383.02 28.07 132.64 141.79 190192.06 171694.94 Run 3 9.80 29.16 1.56 4.75 9.99 0.00 839.72 0.11 24.80 24.92 724.69 1184.36 384.83 28.07 137.68 147.18 196711.65 177438.83 9.77 29.16 1.53 4.72 10.10 0.00 840.47 0.11 24.82 24.94 721.88 1181.55 383.26 28.07 136.14 145.54 195140.21 176081.51 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 1.78 Exhaust Temp F 717.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 1.59 1.53 1.48 714.00 723.00 727.00 1.50 1.63 1.55 724.00 725.00 727.00 1.59 1.54 1.51 723.00 722.00 724.00 1.78 717.00 1.61 1.58 1.63 712.00 718.00 714.00 1.59 1.40 1.58 715.00 710.00 719.50 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 1.49 Exhaust Temp F 720.00 1.52 1.47 1.65 730.00 729.00 727.00 1.55 1.43 1.40 729.00 727.00 721.00 1.62 1.57 1.58 723.00 720.00 723.00 1.55 728.00 1.67 1.67 1.56 721.00 729.00 723.00 1.58 1.69 724.00 721.00 724.691.56 Run 2 Δpstd (in) H2O 1.58 Exhaust Temp F 719.00 1.47 1.34 1.53 713.00 719.00 723.00 1.33 1.39 1.43 724.00 721.00 729.00 1.41 1.40 1.23 723.00 727.00 713.00 1.54 712.00 1.55 1.48 1.59 729.00 726.00 721.00 1.52 1.50 723.00 721.00 1.46 721.44 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.047)+.32(.115)+.28(.838+0) = 29.163 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.163(1 -.09777)+.18.0(.09777) = 28.072 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√1.58*√(1179.17/(24.96*28.072)) = 138.05 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.098)138.046*1.069((528*24.96)/ (1179.17*29.92)) = 179022.41 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 179022.409/35.315 = 5069.302 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 0*(20.9-15)/(20.9-11.5%)) = 0 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (0*(1.164*10^-3)*5069.302*(Run Time/60))/1038.865 = 0 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = 0*1/453.6*1038.865 = 0 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = 0*4.38 = 0 TPYTPY = LB/HR. *4.38 Horsepower 1039= 1302.67 - ((69.7-60) / ((69.7-57.3) / 25%))) * 1302.67)BHP/HR = Available HP - ((MFP @100% - Actual MFP inHG) / ((MFP @100% - MFP @75%) / 25%))) * Available HP Wet to Dry PPM 0 = 0*(1/(1-.1))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.65% 20.93% 10.40% 10.31% 10.61% 10.61% 10.31%10.40% 10.65% 20.93% 10.61% 21.01% 10.61% 21.01% 10.61%21.01% 0.00% 10.61% 21.01% 0.04% 0.08% 0.20% 0.37% 10.61% Span Zero Offset 0.00% 21.01 0.00% 10.65%1.19%1.63%0.00% 11.26% 11.24% 11.08% 11.54% 11.52% 11.35% 9 Gas, Inc. 798.0 798.0 798.0 19.0 19.0 19.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Pleasant Valley Compressor Station 8/6/2024 5354 1 Caterpillar Model Serial Number G3516 TALE 4EK04758 Technician Logan Miller Run Start Times 09:03 AM 10:27 AM 12:10 PM 01:31 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1361.0 1361.0 1363.0 1361.7 Engine Hours 37502.3 37503.3 37504.3 37505.3 Intake Manifold Pressure (psi)29.3 29.3 29.3 29.3 Intake Manifold Temp °F 147.2 147.6 147.9 147.6 Engine Load (BHP)1038.9 1038.9 1040.4 1039.4 Ambient Temp °F 73.0 83.0 94.0 83.3 Humidity %42.0 31.0 22.0 31.7 Dew Point °F 49.0 49.0 49.0 49.0 Caterpillar YesCatalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 19.0 798.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.01 R e s u l t s Average:Nitrogen monoxide NO 0.19 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.18 Average:VOC 0.06 Average:Oxygen 0.00 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 102.73 Tolerance 2.00% Difference between measured and expected 0.26% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.34 Average:Nitrogen monoxide NO 0.20 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.20 Average:VOC 0.51 Average:Oxygen 0.00 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 101.75 Tolerance 5.00% Difference between measured and expected 1.22% Pre-test System CTS & Mechanical Response Time 57 secondsEquilibration Response Time Value:Spike Reported 251.68 Value:Spike Expected 254.10 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC517327 4/29/2027 99.84 10.61% CC190334 4/24/2032 103.00 ALM-062642 12/14/2031 21.01% Cylinder # CC403040& Expiration: 7-13-2031 Propane CO NO SF6 Bottle Value 254.10 507.00 253.30 10.10 Analyzer System Response 251.68 503.24 249.64 10.08 Percent Difference 0.95%0.74%1.45%0.17% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 102.729 4.987 Spike Direct Propane 253.268 Mechanical Response Time SF6 10.137 CO 506.597 NO 251.662 Ethylene 101.748 42 seconds Analyzer Response Propane 251.678 SF6 10.083 CO 503.237 NO 249.639 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 250.681 CO 500.920 NO 249.259 57 seconds 40 seconds 7.87% 7.20% 8.30% 96.56% 98.30% 96.76% 10.058 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.338 50%7.000 83.3%11.662 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 14 230 56 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 176081.51 H2O%d @ Sampling Point:9.77 CO2%d @ Sampling Point:4.72 Pressure @ Sampling Point (Pg "H2O):1.53 Temperature @ Sampling Point (Deg F):721.88 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 103 102.73 4.987 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 102.729 4.987 Spike Direct Propane 253.268 Mechanical Response Time SF6 10.137 CO 506.597 NO 251.662 Ethylene 101.748 42 seconds Analyzer Response Propane 251.678 SF6 10.083 CO 503.237 NO 249.639 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 250.681 CO 500.920 NO 249.259 57 seconds 40 seconds 7.87% 7.20% 8.30% 96.56% 98.30% 96.76% 10.058 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 254.100 10.100 507.000 253.300 253.268 10.137 506.597 251.662 0.33% 0.37% 0.08% 0.65% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 10.737 0.000 Spike Average 28.861 0.798 Dilution Factor 7.872% Expected 29.890 % Recovery 96.560% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.730 Dilution Factor 7.201% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.841 Dilution Factor 8.296% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 10.867 30.048 31.055 96.760% 0.000157 0.000078 0.000154 11.227 28.226 28.714 98.300% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass0.53% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:49.3073488 Pass Line Position Difference:Resolution Difference to Reference 0.53% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 103.00 104.43 1.37% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Pleasant Valley Compressor Station; 1; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/6/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/6/2024 Logan Miller Gas, Inc. Appendices Gas, Inc. Gas, Inc. CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number:E05NI94E15AC014 Reference Number:54-402783135-1 Cylinder Number:CC403040&Cylinder Volume:147.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:CO,CO2,NO,NOX,PPN,BALN Certification Date:Jul 13, 2023 Expiration Date:Jul 13, 2031 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates NOX 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 NITRIC OXIDE 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 PROPANE 250.0 PPM 254.1 PPM G1 +/- 0.9% NIST Traceable 07/11/2023 CARBON MONOXIDE 500.0 PPM 507.0 PPM G1 +/- 0.6% NIST Traceable 07/11/2023 CARBON DIOXIDE 5.000 %5.083 %G1 +/- 0.7% NIST Traceable 07/11/2023 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 200603-02 EB0112877 250.3 PPM NITRIC OXIDE/NITROGEN +/- 0.8%Oct 19, 2026 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR +/- 1.5%Feb 18, 2023 GMIS 1534012021105 ND73033 5.012 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.6%Jun 15, 2025 NTRM 200602-13 6162697Y 243.3 PPM PROPANE/AIR +/- 0.5%Mar 17, 2027 NTRM 150605-41 CC453947 491.9 PPM CARBON MONOXIDE/NITROGEN +/- 0.6%Mar 05, 2027 NTRM 13060423 CC413685 7.489 % CARBON DIOXIDE/NITROGEN +/- 0.6%May 14, 2025 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2010242 FTIR Jun 08, 2023 CO-1 SIEMENS ULTRAMAT 6E N1J5700 NDIR Jun 26, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2110277 FTIR Jul 07, 2023 Triad Data Available Upon Request PERMANENT NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc.      ,          '5781(+5 !+,+5+2)+81(+5    ;0/2*+52'0;<+*#%  ;0/2*+5$3081+   '(35'735;"#806''67/00" ;0/2*+5 5+6685+   " 2'0;6/6'7++(  $'09+870+7 3781(+5          Component Requested Certified Purity Concentration NITROGEN 99.999 %99.999 % OXYGEN <1 PPM 0.94 PPM WATER <1 PPM 0.058 PPM TOTAL HYDROCARBONS <0.1 PPM 0.1 PPM CARBON DIOXIDE <0.5 PPM 0.235 PPM CARBON MONOXIDE <0.5 PPM 0.235 PPM !##" #./6)+57/2)08*+69'08+6,5317.+,/006/*+'2*/62375+45+6+27'7/9+3,7.+86+6/*+485/7;327')7'2/5-'6 "'0+6!+45+6+27'7/9+,357./6/2,351'7/32 &!"#   &#%  #%   #% #%  #%  #% #%  #%    #%  #%   #%   #%  #%  #%  #%  #%  #%   #%   #%   1485/7/+69+5/,/+*'-'/267'2'0;7/)'067'2*'5*675')+'(0+73"#(;:+/-.7'2*35'2'0;6/6 #$! !%!"    Gas, Inc. 21% O2 Tri Probe Certification ” ‡ ƒ – Ž ƒ ‹ • • • ƒ Ž › – ‹ … ƒ Ž ‡ ” ˜ ‹ … ‡ • ͵Ͳ͵͵”†–Ž‹–›ǡǡ͹͵͸ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ ƒšǣȋͷͺͲȌʹʹͷǦʹ͸ͳʹ &(57,),&$7(2)$1$/<6,6 *UDGHRI3URGXFW&(57,),('67$1'$5'352%( 3DUW1XPEHU65HIHUHQFH 1XPEHU  /DERUDWRU\*$6,1&6WDFN'LDPHWHU $QDO\VLV'DWH7DUJHW)ORZ 5DWH /PLQ /271XPEHU 61 $ $6 1XPEHURI 3RLQWV  3URGXFWSHUIRUPDQFHYHULILHGE\GLUHFWFRPSDULVRQWRFDOLEUDWLRQVWDQGDUGVWUDFHDEOHWR1,67  7KHSUREHOLVWHGRQWKLVIRUPPHHWVWKHPXOWLSRLQWWUDYHUVHUHTXLUHPHQWRI(3$0HWKRGH VHFWLRQDVVKRZQLQWKHDFFRPSDQ\LQJGDWD0HWKRGHVHFWLRQVWDWHVWKDWWKHPXOWLSRLQW WUDYHUVHUHTXLUHPHQWFDQEHVDWLVILHGE\VDPSOLQJYLD³DPXOWLKROHSUREHGHVLJQHGWRVDPSOHDW WKHSUHVFULEHGSRLQWVZLWKDIORZSHUFHQWRIPHDQIORZUDWH´ $1$/<7,&$/5(68/76 ZƵŶηdŽƚĂů&ůŽǁ ;>ͬŵͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϭͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϮͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϯͿ 0HDQ3UREH 3RUW6DPSOHG )ORZ /P  5XQ/30  䧮    䧮    䧮   5XQ/30  䧮    䧮    䧮    &DOLEUDWLRQFRQGXFWHGLQDFFRUGDQFHZLWK(PLVVLRQ0HDVXUHPHQW&HQWHU*XLGHOLQH'RFXPHQW±(0&*' 1RWHV BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB $SSURYHGIRU5HOHDVH'DWH 3/23/2022 Probe size: 14S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Logan Miller GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Pleasant Valley Compressor Station Unit Number:1 Make:Caterpillar Location:G3516 TALEModel: 4EK04758Serial Number: RAW Result Data Stability 8/6/2024 06:26 0.00017.133-0.011 0.000 0.0260.000 0.000 0.000 0.0001.44218.850 50.379 0.0000.000 0.000 840.035.002.112 0.000 17.13 0.00 180.0 Pre Test Baseline Direct 8/6/2024 06:43 0.0000.385-0.001 0.000 0.1980.021 0.000 0.000 0.0000.0000.042 0.000 0.0420.000 0.000 841.00.040.001 0.000 0.38 0.00 180.0 8/6/2024 06:44 0.0000.168-0.003 0.000 0.1580.000 0.000 0.005 0.0450.4280.000 0.007 0.0430.079 0.000 841.00.090.061 0.000 0.17 0.00 180.0 8/6/2024 06:44 0.0000.0020.002 0.000 0.0880.022 0.000 0.011 0.0000.0000.072 0.065 0.0000.000 0.000 841.00.040.000 0.002 0.00 0.00 180.0 CTS Direct 8/6/2024 06:50 0.0000.0060.015 0.010 0.0000.099 0.000 0.152 0.2800.6630.000 103.162 0.0000.000 0.000 841.068.840.099 0.000 0.01 0.00 180.0 8/6/2024 06:50 0.2260.0450.019 0.002 0.0000.138 0.007 0.000 0.1130.2060.000 102.514 0.0790.129 0.039 841.068.500.000 0.000 0.27 0.00 180.0 8/6/2024 06:51 0.4630.1880.017 0.005 0.0000.179 0.016 0.000 0.1740.0000.000 102.510 0.0380.132 0.017 841.068.470.089 0.000 0.65 0.00 180.0 High O2 Direct 8/6/2024 06:56 0.0290.0630.002 0.000 0.1670.028 0.000 0.030 0.0370.2230.000 0.000 0.0290.076 0.006 841.00.060.034 0.000 0.09 20.52 180.0 8/6/2024 06:58 0.0000.0000.002 0.000 0.0000.000 0.000 0.028 0.0000.0600.000 0.000 0.0000.000 0.000 841.00.040.054 0.000 0.00 21.09 180.0 8/6/2024 06:58 0.0000.000-0.002 0.000 0.0040.044 0.002 0.000 0.0000.1070.000 0.000 0.0000.003 0.003 841.00.100.139 0.000 0.00 21.19 180.0 NO2/Mid O2 Direct 8/6/2024 07:07 96.8470.391-0.007 0.000 1.5790.000 0.764 0.000 1.7880.0050.059 0.000 0.0000.110 0.000 841.00.000.000 0.000 97.24 10.61 180.0 8/6/2024 07:08 99.1820.187-0.002 0.000 1.6910.000 0.767 0.000 1.5080.0050.265 0.000 0.0000.000 0.000 841.00.000.000 0.000 99.37 10.67 180.0 8/6/2024 07:09 100.3070.174-0.001 0.000 1.8070.000 0.776 0.000 1.7470.0000.248 0.000 0.0000.000 0.000 841.00.020.025 0.000 100.48 10.68 180.0 Spike Direct 8/6/2024 07:14 0.000251.466-0.001 4.828 2.732506.347 1.187 1.959 8.9740.3150.000 1.049 253.1830.355 0.000 841.0256.033.219 10.135 251.47 0.00 180.0 8/6/2024 07:14 0.000251.819-0.000 4.824 2.397506.685 1.162 1.990 8.9610.2950.000 1.031 253.3530.000 0.000 841.0256.203.238 10.141 251.82 0.00 180.0 8/6/2024 07:15 0.000251.7010.000 4.800 2.556506.759 1.160 2.018 8.9010.1160.000 1.052 253.2680.330 0.000 841.0256.083.161 10.136 251.70 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/6/2024 07:17 0.0000.1880.015 0.000 0.1380.702 0.026 1.130 0.0110.0000.000 0.003 0.3710.058 0.046 841.00.650.271 0.008 0.19 0.00 180.0 8/6/2024 07:17 0.0000.4240.006 0.000 0.1920.192 0.010 0.881 0.0000.1490.000 0.006 0.2360.000 0.000 841.00.460.328 0.002 0.42 0.00 180.0 8/6/2024 07:18 0.0000.0000.007 0.002 0.2850.121 0.005 0.822 0.0730.0040.000 0.000 0.2380.131 0.000 841.00.420.277 0.002 0.00 0.00 180.0 CTS System with Response Time 8/6/2024 07:19 0.0000.0000.023 0.004 0.0000.191 0.000 0.673 0.0300.0000.000 101.915 0.1110.000 0.023 841.068.250.218 0.000 0.00 0.00 180.0 8/6/2024 07:19 0.0000.0000.025 0.009 0.0000.112 0.000 0.570 0.0920.0020.000 101.765 0.0410.000 0.078 841.068.350.465 0.000 0.00 0.00 180.0 8/6/2024 07:20 0.0850.0000.022 0.000 0.0000.099 0.015 0.572 0.1500.0000.000 101.564 0.0000.000 0.029 841.067.950.274 0.000 0.08 0.00 180.0 NO2/Mid O2 System with Response Time 8/6/2024 07:23 100.3421.9050.001 0.000 2.4350.000 0.792 0.183 0.3800.0820.000 0.000 0.0000.077 0.033 841.00.450.580 0.000 102.25 10.24 180.0 8/6/2024 07:23 100.6100.5580.001 0.000 2.2160.000 0.794 0.107 0.6740.0000.000 0.000 0.0000.431 0.010 841.00.370.522 0.001 101.17 10.41 180.0 8/6/2024 07:23 101.5171.1830.001 0.000 2.1920.000 0.793 0.083 0.4510.0000.000 0.000 0.0000.469 0.035 841.00.370.447 0.000 102.70 10.56 180.0 Spike System with Response Time 8/6/2024 07:25 0.000249.4630.008 4.776 2.818502.864 1.223 2.339 9.1940.2220.213 1.182 251.5770.188 0.000 841.0254.573.308 10.071 249.46 0.00 180.0 8/6/2024 07:26 0.000249.5990.005 4.797 2.455503.394 1.257 2.275 9.0980.2790.420 1.119 251.7240.243 0.000 841.0254.613.207 10.093 249.60 0.00 180.0 8/6/2024 07:26 0.000249.8550.006 4.787 2.805503.452 1.304 2.331 9.1140.0260.297 1.153 251.7340.186 0.000 841.0254.673.247 10.085 249.85 0.00 180.0 Baseline System with Response Time 8/6/2024 07:28 0.0000.0910.003 0.000 0.5400.510 0.021 0.326 0.0720.0120.000 0.171 0.4040.201 0.000 841.00.900.579 0.008 0.09 0.00 180.0 8/6/2024 07:29 0.0000.4170.006 0.000 0.3490.372 0.011 0.239 0.0000.0270.000 0.035 0.3460.044 0.000 841.00.760.584 0.004 0.42 0.00 180.0 8/6/2024 07:29 0.0000.0320.005 0.000 0.2310.279 0.020 0.345 0.0740.0000.000 0.082 0.2710.136 0.000 841.00.620.450 0.001 0.03 0.00 180.0 Run 1 - A 30minute/60min 8/6/2024 09:04 2.16838.6899.769 4.690 699.3010.000 0.000 0.095 37.7140.0006.376 0.915 10.8390.065 1.353 841.016.413.379 0.000 40.86 10.23 180.0 8/6/2024 09:05 2.21738.3589.758 4.691 694.5930.000 0.000 0.072 37.3690.0006.362 0.896 10.9890.051 1.306 842.016.493.431 0.000 40.58 10.21 180.0 8/6/2024 09:06 1.77840.2499.785 4.714 694.5750.000 0.000 0.141 36.9760.0006.044 0.888 10.6750.181 1.289 841.016.083.349 0.000 42.03 10.21 180.0 8/6/2024 09:07 2.33241.2949.780 4.719 695.4450.000 0.000 0.037 36.9010.0006.277 0.844 10.6800.196 1.301 841.016.193.513 0.000 43.63 10.19 180.0 8/6/2024 09:08 2.40242.1619.782 4.718 688.1190.000 0.000 0.065 35.8220.0006.136 0.790 10.4590.093 1.312 841.015.943.494 0.000 44.56 10.16 180.0 8/6/2024 09:09 2.72843.2919.772 4.725 689.5430.000 0.000 0.108 35.8650.0006.021 0.881 10.5260.272 1.310 841.015.953.329 0.000 46.02 10.19 180.0 8/6/2024 09:10 3.16143.4789.774 4.731 699.3840.000 0.000 0.075 37.1320.0005.897 0.799 10.6030.098 1.339 841.016.003.287 0.000 46.64 10.12 180.0 8/6/2024 09:12 3.20544.2109.772 4.740 692.2070.000 0.000 0.147 36.3000.0006.331 0.902 10.5900.192 1.328 841.016.023.264 0.000 47.41 10.18 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/6/2024 09:13 2.72243.2339.747 4.718 693.5320.000 0.000 0.089 36.6440.0006.136 0.924 10.6280.239 1.298 841.016.093.367 0.000 45.96 10.17 180.0 8/6/2024 09:14 2.21541.5609.752 4.715 682.3300.000 0.000 0.093 35.3970.0006.252 0.812 10.5760.258 1.325 841.016.093.489 0.000 43.78 10.18 180.0 8/6/2024 09:15 1.96442.1189.749 4.710 679.0710.000 0.000 0.083 35.0460.0006.259 0.791 10.5420.096 1.384 841.016.103.399 0.000 44.08 10.17 180.0 8/6/2024 09:16 2.63343.8119.772 4.729 681.4440.000 0.000 0.035 34.7900.0006.138 0.891 10.6040.063 1.311 841.016.143.484 0.000 46.44 10.18 180.0 8/6/2024 09:17 3.11045.0209.778 4.739 682.9790.000 0.000 0.088 34.9760.0006.211 0.897 10.4400.200 1.322 841.015.973.432 0.000 48.13 10.20 180.0 8/6/2024 09:18 2.37845.2009.757 4.735 681.3300.000 0.000 0.073 34.6710.0005.765 0.904 10.4240.144 1.324 841.016.093.624 0.000 47.58 10.18 180.0 8/6/2024 09:19 2.70143.7789.747 4.733 692.0150.000 0.000 0.081 36.3520.0006.245 0.717 10.6400.266 1.286 841.016.073.573 0.000 46.48 10.16 180.0 8/6/2024 09:20 2.62443.5579.749 4.733 684.6550.000 0.000 0.042 35.1060.0005.807 0.742 10.5910.209 1.326 841.016.053.473 0.000 46.18 10.21 180.0 8/6/2024 09:21 2.35143.0329.750 4.727 698.9070.000 0.000 0.044 37.1650.0005.906 0.875 10.8750.226 1.255 841.016.373.600 0.000 45.38 10.23 180.0 8/6/2024 09:22 2.55742.9049.764 4.735 696.5810.000 0.000 0.018 36.9220.0006.047 0.799 10.6810.082 1.286 841.016.133.518 0.000 45.46 10.21 180.0 8/6/2024 09:23 3.24742.3189.778 4.738 695.1650.000 0.000 0.033 36.6480.0006.017 0.769 10.7800.161 1.313 841.016.333.618 0.000 45.57 10.15 180.0 8/6/2024 09:24 2.87043.0619.801 4.738 700.4110.000 0.000 0.153 37.5410.0005.970 0.804 10.8980.000 1.290 841.016.343.486 0.000 45.93 10.16 180.0 8/6/2024 09:25 3.34043.8699.814 4.752 695.5280.000 0.000 0.027 36.6820.0006.171 0.874 10.8790.137 1.300 841.016.543.713 0.000 47.21 10.14 180.0 8/6/2024 09:26 2.39644.1559.830 4.766 689.9260.000 0.000 0.032 35.9170.0006.145 0.925 10.5860.000 1.290 841.016.203.625 0.000 46.55 10.14 180.0 8/6/2024 09:27 3.04344.1559.812 4.749 701.0080.000 0.000 0.041 37.2400.0006.216 0.784 10.8700.240 1.309 841.016.413.598 0.000 47.20 10.16 180.0 8/6/2024 09:28 2.62041.9429.765 4.722 692.7340.000 0.000 0.042 36.5830.0006.403 0.796 10.9420.128 1.317 841.016.583.709 0.000 44.56 10.19 180.0 8/6/2024 09:29 2.54741.4839.766 4.716 692.9200.000 0.000 0.024 36.4630.0006.115 0.810 11.0140.068 1.314 841.016.723.802 0.000 44.03 10.23 180.0 8/6/2024 09:30 1.33238.9619.744 4.700 687.2070.000 0.000 0.011 36.4200.0006.035 0.762 10.9910.069 1.307 841.016.723.913 0.000 40.29 10.19 180.0 8/6/2024 09:31 1.48040.8529.765 4.701 685.7460.000 0.000 0.088 36.1020.0006.017 0.661 10.8410.075 1.297 841.016.453.860 0.000 42.33 10.18 180.0 8/6/2024 09:32 1.81640.4509.760 4.697 689.7000.000 0.000 0.014 36.6150.0005.968 0.805 11.1120.151 1.282 841.016.813.890 0.000 42.27 10.19 180.0 8/6/2024 09:33 2.33341.6589.764 4.707 687.8910.000 0.000 0.041 36.2910.0005.829 0.774 10.8410.100 1.296 841.016.483.795 0.000 43.99 10.15 180.0 8/6/2024 09:34 2.73342.2129.790 4.719 692.0840.000 0.000 0.019 36.7850.0006.062 0.817 11.0020.177 1.288 841.016.633.756 0.000 44.94 10.14 180.0 2.50042.3699.772 4.724 691.2110.000 0.000 0.064 36.3480.0006.105 0.828 10.7370.141 1.309 841.0316.2803.559 0.000 44.869 10.180 180.0Avg. Spike 1 8/6/2024 09:49 0.00060.0838.891 4.673 614.14942.021 0.000 1.116 28.5800.0005.843 2.880 28.8610.087 1.421 841.036.834.817 0.798 60.08 9.52 180.0 Run 1 - B 30minute/60min 8/6/2024 09:53 3.14048.1419.813 4.762 682.5690.000 0.000 0.080 34.6700.0005.434 0.686 10.7350.168 1.341 841.016.463.877 0.000 51.28 10.11 180.0 8/6/2024 09:54 3.23546.7859.837 4.762 683.0990.000 0.000 0.102 34.6820.0005.570 0.694 10.7010.117 1.334 841.016.413.860 0.000 50.02 10.05 180.0 8/6/2024 09:55 2.41144.7769.817 4.776 675.8370.000 0.000 0.027 34.5490.0005.465 0.765 10.7560.195 1.392 841.016.653.895 0.000 47.19 10.06 180.0 8/6/2024 09:56 2.40244.1289.800 4.764 680.3400.000 0.000 0.046 35.1210.0005.451 0.736 10.8320.116 1.369 841.016.663.901 0.000 46.53 10.10 180.0 8/6/2024 09:57 1.40544.3999.754 4.742 671.0000.000 0.000 0.000 34.2130.0005.435 0.656 10.8500.251 1.358 841.016.623.920 0.000 45.80 10.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/6/2024 09:58 2.22046.0069.785 4.762 673.5310.000 0.000 0.022 34.4690.0005.360 0.691 11.0700.316 1.390 841.016.913.895 0.000 48.23 10.12 180.0 8/6/2024 09:59 2.47447.4409.802 4.770 667.7420.000 0.000 0.024 33.1390.0005.706 0.700 10.6720.169 1.353 841.016.393.823 0.000 49.91 10.10 180.0 8/6/2024 10:00 3.06347.8569.815 4.766 678.0320.000 0.000 0.034 34.1420.0005.706 0.792 10.7250.094 1.334 841.016.413.736 0.000 50.92 10.10 180.0 8/6/2024 10:01 2.77945.5819.806 4.758 677.5060.000 0.000 0.020 34.4130.0005.463 0.850 10.9000.106 1.371 841.016.743.792 0.000 48.36 10.12 180.0 8/6/2024 10:02 3.02145.2629.809 4.756 678.4470.000 0.000 0.000 34.4450.0005.477 0.756 10.8410.133 1.339 841.016.633.910 0.000 48.28 10.10 180.0 8/6/2024 10:03 2.76345.0249.803 4.753 678.8700.000 0.000 0.029 34.7090.0005.753 0.741 10.7540.124 1.346 841.016.463.779 0.000 47.79 10.13 180.0 8/6/2024 10:04 1.96343.6219.779 4.743 683.0540.000 0.000 0.024 35.4500.0005.630 0.768 10.9550.123 1.319 841.016.643.807 0.000 45.58 10.15 180.0 8/6/2024 10:05 2.88743.3839.780 4.736 682.6890.000 0.000 0.000 35.1480.0005.640 0.764 11.0480.114 1.332 841.016.743.785 0.000 46.27 10.13 180.0 8/6/2024 10:06 2.67344.8229.780 4.742 683.1290.000 0.000 0.000 35.3040.0005.681 0.799 10.9070.024 1.365 841.016.723.821 0.000 47.49 10.11 180.0 8/6/2024 10:07 2.43144.1619.781 4.746 683.2860.000 0.000 0.019 35.3720.0005.782 0.822 11.1450.003 1.318 841.016.873.805 0.000 46.59 10.19 180.0 8/6/2024 10:08 2.18843.2879.747 4.731 676.6910.000 0.000 0.021 34.7230.0005.743 0.833 10.9860.121 1.358 841.016.763.756 0.000 45.48 10.18 180.0 8/6/2024 10:09 1.87141.8959.756 4.731 683.8650.000 0.000 0.001 35.6600.0005.610 0.770 11.2200.089 1.367 841.016.983.776 0.000 43.77 10.18 180.0 8/6/2024 10:10 2.21041.8059.764 4.730 688.5250.000 0.000 0.059 36.3760.0006.108 0.739 11.3590.000 1.315 841.016.963.724 0.000 44.02 10.17 180.0 8/6/2024 10:11 2.39142.9209.768 4.727 686.4680.000 0.000 0.028 35.8950.0005.789 0.887 11.0420.085 1.344 841.016.773.671 0.000 45.31 10.19 180.0 8/6/2024 10:12 1.95142.1909.737 4.706 688.5780.000 0.000 0.065 36.3100.0005.648 0.814 11.1750.017 1.350 841.016.913.737 0.000 44.14 10.20 180.0 8/6/2024 10:13 2.93143.1559.778 4.719 689.7340.000 0.000 0.000 36.2510.0005.632 0.855 11.2390.190 1.346 841.017.093.883 0.000 46.09 10.19 180.0 8/6/2024 10:14 3.29844.3919.788 4.720 694.2930.000 0.000 0.000 36.7640.0005.895 0.759 11.1620.093 1.375 841.016.813.594 0.000 47.69 10.19 180.0 8/6/2024 10:15 2.96545.0739.766 4.712 686.7790.000 0.000 0.000 35.6810.0005.981 0.748 11.0330.000 1.327 841.016.663.716 0.000 48.04 10.15 180.0 8/6/2024 10:16 2.50144.7219.783 4.716 685.7390.000 0.000 0.000 35.3420.0006.005 0.788 10.9910.150 1.336 841.016.753.844 0.000 47.22 10.19 180.0 8/6/2024 10:17 3.30744.1969.761 4.713 692.3750.000 0.000 0.000 36.2340.0005.742 0.831 11.3050.000 1.338 841.016.933.599 0.000 47.50 10.17 180.0 8/6/2024 10:18 2.32343.3269.747 4.701 684.7370.000 0.000 0.000 35.6570.0005.790 0.714 11.0630.196 1.326 841.016.653.680 0.000 45.65 10.19 180.0 8/6/2024 10:19 3.10944.0229.774 4.714 693.2350.000 0.000 0.051 36.6560.0005.915 0.629 11.0900.165 1.325 841.016.733.853 0.000 47.13 10.15 180.0 8/6/2024 10:20 2.40143.2609.752 4.720 692.1010.000 0.000 0.024 36.4510.0005.921 0.827 11.0570.033 1.360 841.016.863.797 0.000 45.66 10.13 180.0 8/6/2024 10:21 2.93944.8339.781 4.730 687.8920.000 0.000 0.000 35.8690.0005.849 0.710 11.0170.121 1.315 841.016.603.719 0.000 47.77 10.14 180.0 8/6/2024 10:23 2.49243.6099.785 4.726 686.4900.000 0.000 0.001 35.8920.0005.851 0.711 11.2390.166 1.360 841.016.993.836 0.000 46.10 10.15 180.0 2.59144.4699.782 4.738 683.2210.000 0.000 0.023 35.3200.0005.701 0.761 10.9960.116 1.347 841.0016.7253.793 0.000 47.060 10.143 180.0Avg. 2.54643.4199.777 4.731 687.2160.000 0.000 0.043 35.8340.0005.903 0.795 10.8660.129 1.328 841.0216.5033.676 0.000 45.965 10.161 180.0Run 1 Avg: Baseline 1 8/6/2024 10:25 0.0000.1230.046 0.000 3.1300.230 0.077 0.006 0.5570.0020.000 0.000 0.1000.000 0.000 841.00.740.956 0.000 0.12 0.00 180.0 Run 2 - A 30minute/60min 8/6/2024 10:28 2.50842.0509.670 4.670 694.0640.000 0.000 0.306 37.1510.0005.709 0.748 11.3580.184 1.370 841.016.993.588 0.000 44.56 9.43 180.0 8/6/2024 10:29 2.66042.4799.645 4.656 685.9640.000 0.000 0.149 36.1610.0005.753 0.780 11.4090.186 1.322 841.017.093.779 0.000 45.14 9.65 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/6/2024 10:30 2.61344.9389.688 4.680 684.6760.000 0.000 0.081 35.8300.0005.884 0.678 11.1500.081 1.337 841.016.793.769 0.000 47.55 9.93 180.0 8/6/2024 10:31 2.55445.8509.695 4.689 676.8190.000 0.000 0.072 34.8230.0005.870 0.729 10.8420.155 1.359 841.016.563.770 0.000 48.40 9.97 180.0 8/6/2024 10:32 3.32645.2669.717 4.691 679.9420.000 0.000 0.075 34.5800.0005.934 0.738 11.1350.097 1.352 841.016.873.806 0.000 48.59 10.03 180.0 8/6/2024 10:33 2.80844.6509.724 4.683 687.8150.000 0.000 0.079 36.1290.0005.725 0.679 11.2500.000 1.332 841.016.863.748 0.000 47.46 10.06 180.0 8/6/2024 10:34 2.53445.3039.741 4.700 685.5010.000 0.000 0.046 35.7040.0005.869 0.743 11.1930.241 1.380 841.016.923.711 0.000 47.84 10.04 180.0 8/6/2024 10:35 2.77444.5749.775 4.706 682.9950.000 0.000 0.030 35.3030.0005.812 0.749 11.0410.125 1.400 841.016.813.702 0.000 47.35 10.05 180.0 8/6/2024 10:36 2.54542.0579.765 4.701 685.9120.000 0.000 0.076 35.8900.0005.589 0.740 11.2190.234 1.414 841.016.993.680 0.000 44.60 10.10 180.0 8/6/2024 10:37 1.62142.7929.716 4.684 679.8800.000 0.000 0.073 35.3230.0005.620 0.810 11.1930.114 1.360 841.016.893.654 0.000 44.41 10.12 180.0 8/6/2024 10:38 1.02740.4579.711 4.676 674.1380.000 0.000 0.045 34.9660.0006.059 0.794 11.3680.000 1.411 841.017.313.879 0.000 41.48 10.17 180.0 8/6/2024 10:39 1.80541.7079.691 4.686 675.4710.000 0.000 0.000 34.9120.0005.959 0.734 11.3080.137 1.388 841.017.103.789 0.000 43.51 10.15 180.0 8/6/2024 10:40 1.74742.9859.696 4.690 677.4340.000 0.000 0.000 34.8920.0005.943 0.764 11.3180.041 1.385 841.017.023.630 0.000 44.73 10.16 180.0 8/6/2024 10:41 1.97743.0649.696 4.699 674.9010.000 0.000 0.000 34.3920.0005.846 0.803 11.1710.255 1.413 841.017.063.788 0.000 45.04 10.16 180.0 8/6/2024 10:42 1.56843.1889.693 4.686 674.8880.000 0.000 0.000 34.4470.0005.990 0.785 11.1730.108 1.407 841.017.103.887 0.000 44.76 10.19 180.0 8/6/2024 10:43 1.57042.7759.704 4.685 670.5450.000 0.000 0.000 33.8490.0006.019 0.796 10.9840.014 1.411 841.016.873.806 0.000 44.34 10.23 180.0 8/6/2024 10:44 1.69740.4589.691 4.663 674.5150.000 0.000 0.000 34.6770.0005.951 0.817 11.1930.078 1.405 841.017.193.956 0.000 42.16 10.21 180.0 8/6/2024 10:45 1.44840.6519.666 4.650 671.4810.000 0.000 0.028 34.4610.0005.738 0.787 11.1760.163 1.391 841.017.154.004 0.000 42.10 10.21 180.0 8/6/2024 10:46 1.48941.9609.663 4.656 674.3490.000 0.000 0.000 34.8090.0005.746 0.835 11.1930.134 1.363 841.017.033.828 0.000 43.45 10.17 180.0 8/6/2024 10:47 1.20241.4769.667 4.661 675.0910.000 0.000 0.000 35.0520.0005.783 0.801 11.3440.195 1.410 841.017.173.708 0.000 42.68 10.16 180.0 8/6/2024 10:48 1.38540.6079.694 4.655 675.3440.000 0.000 0.000 35.1430.0005.858 0.828 11.4500.137 1.414 841.017.273.664 0.000 41.99 10.17 180.0 8/6/2024 10:49 1.19039.8719.735 4.639 667.3770.000 0.000 0.018 34.2730.0005.771 0.750 11.2800.137 1.417 841.017.133.772 0.000 41.06 10.23 180.0 8/6/2024 10:50 1.25340.9079.739 4.644 667.3290.000 0.000 0.000 33.7880.0005.750 0.834 11.1440.068 1.420 841.016.963.635 0.000 42.16 10.18 180.0 8/6/2024 10:51 1.48341.0619.774 4.668 665.8150.000 0.000 0.035 33.8300.0005.594 0.683 11.1050.222 1.456 841.016.953.720 0.000 42.54 10.18 180.0 8/6/2024 10:52 0.83940.4909.731 4.643 667.8520.000 0.000 0.000 34.0950.0005.819 0.762 11.2240.000 1.397 841.016.953.638 0.000 41.33 10.20 180.0 8/6/2024 10:53 1.73741.2679.734 4.639 673.5560.000 0.000 0.000 34.7470.0005.790 0.827 11.2510.157 1.408 841.016.963.510 0.000 43.00 10.16 180.0 8/6/2024 10:54 1.39339.5599.741 4.639 673.8160.000 0.000 0.003 35.0790.0005.953 0.839 11.5390.277 1.404 841.017.213.455 0.000 40.95 10.19 180.0 8/6/2024 10:55 0.84039.2729.773 4.657 669.6730.000 0.000 0.000 34.3050.0006.078 0.797 11.2460.039 1.444 841.017.093.643 0.000 40.11 10.18 180.0 8/6/2024 10:56 1.21639.8379.833 4.681 672.8620.000 0.000 0.015 34.9740.0005.860 0.829 11.3590.158 1.448 841.017.153.516 0.000 41.05 10.13 180.0 8/6/2024 10:58 1.64641.3079.822 4.662 673.2270.000 0.000 0.005 34.6720.0006.089 0.836 11.1860.105 1.453 841.016.983.499 0.000 42.95 10.16 180.0 1.81542.0959.720 4.671 676.4410.000 0.000 0.038 34.9420.0005.845 0.777 11.2270.128 1.396 841.0017.0143.718 0.000 43.910 10.099 180.0Avg. Spike 2 8/6/2024 11:26 1.98551.1728.877 4.581 625.63834.947 0.000 0.697 27.2610.0005.818 2.857 28.2260.150 1.668 841.035.643.258 0.730 53.16 9.48 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/6/2024 11:32 3.26248.0199.753 4.709 665.6870.000 0.000 0.078 32.6810.0006.099 0.755 11.0150.149 1.498 841.016.392.810 0.000 51.28 10.20 180.0 8/6/2024 11:33 3.38046.4199.780 4.683 671.8720.000 0.000 0.041 33.8960.0006.179 0.868 11.2060.111 1.495 841.016.682.854 0.000 49.80 10.19 180.0 8/6/2024 11:34 2.58344.6139.737 4.677 662.5310.000 0.000 0.119 32.9570.0005.974 0.810 11.1200.024 1.494 841.016.663.017 0.000 47.20 10.21 180.0 8/6/2024 11:35 3.73444.3919.721 4.678 676.5810.000 0.000 0.033 34.5380.0006.049 0.844 11.3610.052 1.503 841.016.892.936 0.000 48.13 10.19 180.0 8/6/2024 11:36 3.24245.5189.742 4.689 671.5670.000 0.000 0.034 33.8590.0006.365 0.751 11.1600.207 1.483 841.016.522.842 0.000 48.76 10.13 180.0 8/6/2024 11:37 2.40245.2529.761 4.689 670.6210.000 0.000 0.049 33.9850.0006.092 0.831 11.0830.088 1.478 841.016.472.812 0.000 47.65 10.14 180.0 8/6/2024 11:38 2.70945.9269.753 4.691 666.1430.000 0.000 0.023 33.1970.0006.226 0.792 11.1250.000 1.491 841.016.532.835 0.000 48.63 10.15 180.0 8/6/2024 11:39 3.48747.6079.796 4.712 673.8110.000 0.000 0.000 33.9100.0006.072 0.755 11.1710.138 1.493 841.016.442.664 0.000 51.09 10.15 180.0 8/6/2024 11:40 2.86646.2769.791 4.695 671.7970.000 0.000 0.052 33.7630.0006.293 0.757 11.1330.196 1.509 841.016.562.857 0.000 49.14 10.16 180.0 8/6/2024 11:41 3.71147.0969.779 4.687 673.6300.000 0.000 0.071 33.9090.0006.395 0.785 11.1690.151 1.483 841.016.442.667 0.000 50.81 10.18 180.0 8/6/2024 11:42 3.18646.4409.805 4.719 665.9520.000 0.000 0.014 33.1920.0006.322 0.711 11.1410.077 1.488 840.016.462.812 0.000 49.63 10.08 180.0 8/6/2024 11:43 3.46346.6109.803 4.716 668.7160.000 0.000 0.000 33.6660.0006.187 0.713 11.0640.187 1.498 840.016.382.774 0.000 50.07 10.16 180.0 8/6/2024 11:44 2.41245.1269.708 4.683 660.0230.000 0.000 0.000 32.9310.0005.966 0.848 11.0520.108 1.495 841.016.572.936 0.000 47.54 10.19 180.0 8/6/2024 11:45 3.52945.3919.721 4.691 668.4680.000 0.000 0.000 33.9280.0005.995 0.780 11.2730.145 1.488 840.016.632.795 0.000 48.92 10.18 180.0 8/6/2024 11:46 3.04445.4599.715 4.690 661.3450.000 0.000 0.015 32.9630.0006.212 0.777 11.1340.119 1.506 840.016.683.029 0.000 48.50 10.17 180.0 8/6/2024 11:47 1.81044.7389.767 4.694 657.9530.000 0.000 0.000 32.5730.0006.275 0.826 11.2440.072 1.506 840.016.792.977 0.000 46.55 10.21 180.0 8/6/2024 11:48 2.23245.3659.752 4.705 651.6620.000 0.000 0.014 31.6040.0006.087 0.773 11.0160.260 1.500 840.016.512.975 0.000 47.60 10.14 180.0 8/6/2024 11:49 2.05243.8249.756 4.694 657.8200.000 0.000 0.000 32.6370.0006.059 0.737 11.3970.000 1.500 840.016.862.959 0.000 45.88 10.19 180.0 8/6/2024 11:50 1.74644.0929.681 4.677 651.0220.000 0.000 0.000 31.5330.0006.012 0.724 11.2160.236 1.541 840.016.833.071 0.000 45.84 10.21 180.0 8/6/2024 11:51 1.43143.2909.652 4.659 650.0670.000 0.000 0.071 31.8180.0006.205 0.841 11.3030.142 1.525 840.016.902.986 0.000 44.72 10.26 180.0 8/6/2024 11:52 2.15143.9799.637 4.654 652.0620.000 0.000 0.070 31.7590.0006.321 0.815 11.1230.169 1.487 840.016.703.088 0.000 46.13 10.36 180.0 8/6/2024 11:53 1.95144.5789.637 4.652 652.8030.000 0.000 0.040 31.8180.0006.216 0.703 11.1210.433 1.508 840.016.582.956 0.000 46.53 10.34 180.0 8/6/2024 11:54 1.21543.9979.654 4.661 648.2380.000 0.000 0.026 31.6810.0006.241 0.854 11.1720.031 1.527 840.016.843.067 0.000 45.21 10.36 180.0 8/6/2024 11:55 1.93547.8329.716 4.710 654.6010.000 0.000 0.002 31.5420.0006.433 0.856 11.0100.150 1.480 840.016.482.911 0.000 49.77 10.18 180.0 8/6/2024 11:56 3.15647.8909.690 4.698 654.1390.000 0.000 0.010 31.5240.0006.179 0.805 11.0410.208 1.513 840.016.552.919 0.000 51.05 10.19 180.0 8/6/2024 11:57 2.20846.6459.726 4.714 653.3720.000 0.000 0.000 31.5110.0005.726 0.743 10.9810.331 1.510 840.016.482.982 0.000 48.85 10.17 180.0 8/6/2024 11:58 2.52246.0829.727 4.714 651.9910.000 0.000 0.027 31.1590.0006.116 0.772 11.0220.109 1.527 840.016.572.975 0.000 48.60 10.19 180.0 8/6/2024 11:59 1.77045.3519.711 4.709 652.2590.000 0.000 0.036 31.5830.0006.141 0.835 11.0640.176 1.489 840.016.582.972 0.000 47.12 10.20 180.0 8/6/2024 12:00 1.93444.1589.715 4.710 654.5820.000 0.000 0.004 32.1290.0005.871 0.753 11.1000.204 1.506 840.016.753.198 0.000 46.09 10.17 180.0 8/6/2024 12:01 2.85745.7869.739 4.718 661.8020.000 0.000 0.023 32.5110.0006.100 0.753 11.1370.058 1.448 840.016.512.959 0.000 48.64 10.25 180.0 2.59945.5929.731 4.693 661.1040.000 0.000 0.028 32.6920.0006.147 0.786 11.1380.144 1.499 840.3716.6082.921 0.000 48.191 10.197 180.0Avg. 2.20743.8439.725 4.682 668.7720.000 0.000 0.033 33.8170.0005.996 0.781 11.1830.136 1.447 840.6816.8113.319 0.000 46.050 10.148 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/6/2024 12:08 0.0000.0000.001 0.000 0.1100.000 0.000 0.168 0.0000.0010.000 0.000 0.0160.210 0.000 840.00.240.342 0.000 0.00 0.00 180.0 Run 3 - A 30minute/60min 8/6/2024 12:11 2.57748.3159.707 4.700 660.4220.000 0.000 0.227 32.2820.0005.799 0.705 11.0130.152 1.439 840.016.683.475 0.000 50.89 9.20 180.0 8/6/2024 12:12 2.46948.8669.719 4.715 653.1310.000 0.000 0.130 31.3910.0005.734 0.725 10.8480.175 1.467 840.016.653.575 0.000 51.33 9.54 180.0 8/6/2024 12:13 3.03551.8129.773 4.746 652.7760.000 0.000 0.077 31.1020.0005.971 0.714 10.6030.068 1.438 840.016.293.502 0.000 54.85 9.63 180.0 8/6/2024 12:14 3.09550.9719.773 4.739 656.0690.000 0.000 0.026 31.4760.0005.660 0.711 10.6040.300 1.469 840.016.453.646 0.000 54.07 9.72 180.0 8/6/2024 12:15 2.09550.1749.767 4.721 653.7680.000 0.000 0.060 31.1520.0005.546 0.703 10.8440.195 1.437 840.016.683.730 0.000 52.27 9.83 180.0 8/6/2024 12:16 2.16947.7579.784 4.726 649.8220.000 0.000 0.041 31.0030.0005.751 0.829 10.9080.257 1.479 840.016.923.745 0.000 49.93 9.93 180.0 8/6/2024 12:17 2.30048.6859.791 4.736 652.3430.000 0.000 0.042 31.2050.0005.473 0.663 10.7500.190 1.439 840.016.613.808 0.000 50.99 9.90 180.0 8/6/2024 12:18 2.04648.1469.811 4.749 653.5270.000 0.000 0.020 31.6570.0005.774 0.784 10.8250.138 1.405 840.016.743.877 0.000 50.19 9.95 180.0 8/6/2024 12:19 2.41547.2029.780 4.731 651.9400.000 0.000 0.000 31.5720.0005.576 0.761 10.9860.125 1.420 840.016.993.980 0.000 49.62 9.95 180.0 8/6/2024 12:20 1.63247.1549.777 4.738 653.5770.000 0.000 0.020 31.7860.0005.756 0.721 10.9990.193 1.428 840.017.034.040 0.000 48.79 9.95 180.0 8/6/2024 12:21 2.04247.9489.771 4.730 653.4130.000 0.000 0.000 31.6270.0005.516 0.756 11.0640.234 1.435 840.017.144.053 0.000 49.99 10.01 180.0 8/6/2024 12:22 1.80849.2989.763 4.722 648.6550.000 0.000 0.004 30.9940.0005.770 0.803 10.8440.121 1.456 840.016.953.986 0.000 51.11 9.99 180.0 8/6/2024 12:23 2.53750.2529.819 4.726 650.2110.000 0.000 0.000 30.9450.0005.579 0.607 10.8250.218 1.428 840.016.683.884 0.000 52.79 10.02 180.0 8/6/2024 12:24 1.81549.2189.765 4.719 650.7520.000 0.000 0.000 31.2030.0005.451 0.709 10.8690.161 1.442 840.016.823.886 0.000 51.03 10.04 180.0 8/6/2024 12:25 1.88448.8619.725 4.696 642.5580.000 0.000 0.000 30.2630.0005.481 0.699 10.9150.187 1.446 840.016.964.032 0.000 50.74 10.09 180.0 8/6/2024 12:26 1.79447.3959.722 4.702 654.1720.000 0.000 0.000 31.8580.0005.541 0.716 10.9750.185 1.413 840.017.074.192 0.000 49.19 10.05 180.0 8/6/2024 12:27 1.29846.9779.756 4.711 654.5130.000 0.000 0.000 32.0750.0005.335 0.695 11.0240.285 1.399 840.017.164.316 0.000 48.28 10.04 180.0 8/6/2024 12:28 1.29247.2339.786 4.723 653.0450.000 0.000 0.000 31.8650.0005.409 0.640 11.0200.043 1.403 840.017.064.217 0.000 48.53 10.02 180.0 8/6/2024 12:29 1.99750.5439.813 4.736 644.8590.000 0.000 0.000 30.6000.0005.370 0.649 10.7120.243 1.407 840.016.824.292 0.000 52.54 10.07 180.0 8/6/2024 12:30 1.95351.9209.803 4.747 646.8910.000 0.000 0.000 30.8060.0005.280 0.703 10.7300.130 1.440 840.016.864.174 0.000 53.87 10.01 180.0 8/6/2024 12:31 2.18449.8349.787 4.742 647.6750.000 0.000 0.000 30.8760.0005.330 0.653 10.8280.204 1.475 840.016.994.172 0.000 52.02 10.11 180.0 8/6/2024 12:32 2.29650.8359.822 4.752 643.4890.000 0.000 0.000 30.3060.0005.337 0.756 10.7750.085 1.423 840.016.904.170 0.000 53.13 10.01 180.0 8/6/2024 12:33 2.09551.0059.803 4.745 648.2540.000 0.000 0.000 30.8120.0005.217 0.699 10.8460.120 1.443 840.016.994.189 0.000 53.10 10.06 180.0 8/6/2024 12:34 2.07450.8039.798 4.732 656.7570.000 0.000 0.000 31.8130.0005.373 0.790 10.9300.115 1.394 840.016.974.092 0.000 52.88 10.06 180.0 8/6/2024 12:35 2.01450.6839.773 4.718 650.9310.000 0.000 0.000 30.9940.0005.185 0.644 10.8350.229 1.420 840.016.824.076 0.000 52.70 10.08 180.0 8/6/2024 12:36 2.69950.4499.802 4.727 655.1650.000 0.000 0.000 31.4800.0005.484 0.653 10.9270.235 1.425 840.016.904.027 0.000 53.15 10.02 180.0 8/6/2024 12:37 1.94248.9709.760 4.714 648.8840.000 0.000 0.000 31.1460.0005.325 0.667 11.0310.131 1.438 840.017.094.103 0.000 50.91 10.08 180.0 8/6/2024 12:38 2.11651.2759.733 4.707 646.4080.000 0.000 0.000 30.6590.0005.312 0.697 10.9250.168 1.401 840.016.934.108 0.000 53.39 10.09 180.0 8/6/2024 12:39 2.66253.7279.728 4.715 643.3420.000 0.000 0.000 29.6480.0005.355 0.596 10.6970.042 1.423 840.016.583.954 0.000 56.39 10.12 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/6/2024 12:40 2.27452.1599.715 4.703 641.8100.000 0.000 0.000 29.8890.0005.090 0.656 10.8450.114 1.444 840.016.894.081 0.000 54.43 10.11 180.0 2.15449.6169.771 4.726 650.6390.000 0.000 0.022 31.1500.0005.493 0.703 10.8670.168 1.433 840.0016.8543.979 0.000 51.770 9.956 180.0Avg. Spike 3 8/6/2024 12:44 0.00062.0108.889 4.701 591.84943.338 0.000 0.515 26.7480.0005.447 2.859 30.0480.276 1.432 840.037.934.669 0.841 62.01 9.41 180.0 Run 3 - B 30minute/60min 8/6/2024 12:48 2.74552.5099.795 4.739 644.4960.000 0.000 0.054 30.2530.0005.464 0.625 10.8790.309 1.502 840.017.094.183 0.000 55.25 10.03 180.0 8/6/2024 12:49 2.52354.4359.795 4.763 640.5810.000 0.000 0.000 29.5080.0005.172 0.614 10.5610.114 1.478 840.016.654.081 0.000 56.96 9.96 180.0 8/6/2024 12:50 2.67853.9969.821 4.776 638.1770.000 0.000 0.060 29.0170.0005.236 0.703 10.6810.260 1.476 840.016.844.100 0.000 56.67 10.02 180.0 8/6/2024 12:51 3.18654.0039.809 4.758 637.1230.000 0.000 0.000 28.9410.0004.904 0.767 10.7870.073 1.500 840.017.004.054 0.000 57.19 10.02 180.0 8/6/2024 12:52 4.04158.5579.831 4.777 640.1670.000 0.000 0.033 28.8470.0005.330 0.703 10.5320.323 1.468 840.016.493.834 0.000 62.60 10.03 180.0 8/6/2024 12:53 2.16452.8959.773 4.746 638.7340.000 0.000 0.000 29.6870.0005.010 0.629 10.9670.230 1.442 840.017.004.099 0.000 55.06 10.05 180.0 8/6/2024 12:54 4.04356.1759.788 4.744 649.5680.000 0.000 0.000 30.3780.0005.286 0.663 10.7510.104 1.432 840.016.784.089 0.000 60.22 10.03 180.0 8/6/2024 12:55 2.29652.8189.749 4.739 638.7500.000 0.000 0.000 29.5130.0004.958 0.741 10.9080.098 1.477 840.017.094.093 0.000 55.11 10.05 180.0 8/6/2024 12:56 2.59554.0369.751 4.723 640.6520.000 0.000 0.000 29.3320.0005.320 0.628 10.6720.182 1.467 840.016.704.017 0.000 56.63 10.07 180.0 8/6/2024 12:57 2.17553.0939.758 4.731 643.0500.000 0.000 0.000 29.9750.0005.187 0.595 11.0030.097 1.427 840.017.094.249 0.000 55.27 10.08 180.0 8/6/2024 12:58 2.41952.5289.776 4.745 647.5170.000 0.000 0.000 30.2060.0004.952 0.679 10.9320.125 1.453 840.017.034.108 0.000 54.95 10.06 180.0 8/6/2024 12:59 2.74152.3039.762 4.738 645.0370.000 0.000 0.000 29.9600.0005.178 0.657 10.9170.237 1.492 840.016.993.978 0.000 55.04 10.06 180.0 8/6/2024 13:00 1.79250.7659.785 4.735 644.0500.000 0.000 0.000 30.0230.0005.129 0.686 10.7740.071 1.523 839.016.994.066 0.000 52.56 10.04 180.0 8/6/2024 13:01 1.65051.9019.795 4.740 645.4160.000 0.000 0.000 30.0060.0005.034 0.602 10.7580.156 1.465 840.016.864.152 0.000 53.55 10.03 180.0 8/6/2024 13:02 1.63550.2219.771 4.734 644.7510.000 0.000 0.000 29.9160.0005.129 0.589 10.8470.092 1.475 839.016.944.134 0.000 51.86 10.07 180.0 8/6/2024 13:03 1.48950.4769.795 4.719 632.6420.000 0.000 0.000 28.7690.0005.173 0.673 10.8160.106 1.507 839.017.124.263 0.000 51.96 10.11 180.0 8/6/2024 13:04 3.26456.3189.815 4.750 637.0750.000 0.000 0.000 28.4300.0005.176 0.483 10.4250.138 1.482 839.016.524.215 0.000 59.58 10.07 180.0 8/6/2024 13:05 2.59454.9159.812 4.763 631.1190.000 0.000 0.000 28.2010.0004.956 0.711 10.5520.143 1.484 839.016.784.183 0.000 57.51 10.03 180.0 8/6/2024 13:06 3.17256.8259.842 4.783 637.4270.000 0.000 0.000 28.6450.0004.864 0.536 10.5020.104 1.459 839.016.554.158 0.000 60.00 10.05 180.0 8/6/2024 13:07 2.46456.2119.822 4.772 635.5510.000 0.000 0.000 28.7390.0004.786 0.599 10.5080.035 1.470 839.016.584.104 0.000 58.67 10.02 180.0 8/6/2024 13:08 3.54257.7219.884 4.863 636.2460.000 0.000 0.000 28.3000.0003.742 0.535 10.4580.243 1.636 839.016.743.973 0.000 61.26 10.03 180.0 8/6/2024 13:09 3.65159.9039.920 4.863 632.4220.000 0.000 0.000 27.7950.0004.184 0.451 10.3260.286 1.551 839.016.273.804 0.000 63.55 9.99 180.0 8/6/2024 13:10 3.49558.6059.900 4.825 627.6560.000 0.000 0.000 27.3570.0004.893 0.563 10.2400.228 1.494 839.016.284.021 0.000 62.10 9.99 180.0 8/6/2024 13:11 3.20757.9139.895 4.824 630.0700.000 0.000 0.015 27.5380.0004.607 0.651 10.4170.173 1.472 839.016.423.935 0.000 61.12 10.00 180.0 8/6/2024 13:12 2.76459.0619.896 4.829 630.7090.000 0.000 0.000 27.8340.0004.578 0.575 10.3830.002 1.518 839.016.514.062 0.000 61.82 9.96 180.0 8/6/2024 13:13 3.46560.2659.888 4.831 634.4020.000 0.000 0.000 28.1200.0004.801 0.509 10.3900.168 1.525 839.016.393.909 0.000 63.73 10.04 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/6/2024 13:15 3.63059.7989.868 4.816 635.6110.000 0.000 0.000 28.3090.0004.912 0.543 10.4920.167 1.495 839.016.594.124 0.000 63.43 10.02 180.0 8/6/2024 13:16 2.97057.1499.854 4.801 636.0000.000 0.000 0.000 28.9680.0005.179 0.602 10.6410.213 1.488 839.016.673.979 0.000 60.12 10.04 180.0 8/6/2024 13:17 2.98156.6929.881 4.809 638.7340.000 0.000 0.000 28.8800.0005.105 0.505 10.6720.173 1.466 839.016.644.052 0.000 59.67 10.00 180.0 8/6/2024 13:19 1.48153.4299.877 4.784 633.6360.000 0.000 0.000 28.9530.0004.749 0.461 10.6840.292 1.493 839.016.884.359 0.000 54.91 9.96 180.0 2.76255.1849.824 4.774 638.2460.000 0.000 0.005 29.0130.0004.966 0.609 10.6490.165 1.487 839.4316.7494.079 0.000 57.945 10.030 180.0Avg. 2.45852.4009.797 4.750 644.4420.000 0.000 0.013 30.0810.0005.230 0.656 10.7580.166 1.460 839.7216.8024.029 0.000 54.858 9.993 180.0Run 3 Avg: Baseline 3 8/6/2024 13:23 0.0000.0000.025 0.000 1.3730.084 0.024 0.000 0.5060.0160.000 0.000 0.0870.165 0.000 839.00.951.290 0.000 0.00 0.00 180.0 Post CTS 8/6/2024 13:25 0.0000.7370.013 0.000 0.0320.318 0.030 0.000 0.5350.0180.000 101.394 0.0160.000 0.029 839.068.421.113 0.000 0.74 1.68 180.0 8/6/2024 13:25 0.0000.5870.026 0.000 0.0150.051 0.008 0.000 0.2510.0000.000 105.476 0.0000.000 0.069 839.071.241.178 0.000 0.59 1.52 180.0 8/6/2024 13:25 0.0000.0000.024 0.000 0.1630.192 0.010 0.000 0.7260.0000.000 106.419 0.1630.513 0.000 839.072.191.610 0.000 0.00 1.51 180.0 Post NO2/Mid O2 8/6/2024 13:28 97.7120.5270.000 0.000 1.6750.000 0.762 0.000 1.0670.0500.000 0.000 0.0001.066 0.000 839.00.420.636 0.006 98.24 10.30 180.0 8/6/2024 13:28 98.7920.2970.005 0.000 1.2780.000 0.777 0.000 0.7550.0000.000 0.000 0.0001.094 0.000 839.00.500.748 0.010 99.09 10.25 180.0 8/6/2024 13:28 99.3700.2140.005 0.000 1.7140.002 0.795 0.000 0.5980.0560.000 0.000 0.0000.675 0.000 839.00.530.800 0.010 99.58 10.32 180.0 8/6/2024 13:28 101.0200.944-0.000 0.000 1.7920.184 0.760 0.000 1.1940.0000.000 0.000 0.0000.719 0.000 839.01.031.542 0.000 101.96 10.37 180.0 Post 5-Gas 8/6/2024 13:30 0.000247.247-0.000 4.716 2.063495.498 1.167 1.818 9.9090.1650.153 1.430 248.6640.069 0.000 839.0252.304.023 9.978 247.25 0.00 180.0 8/6/2024 13:30 0.000248.1760.006 4.695 3.495499.169 1.207 2.328 9.9010.8900.136 1.348 250.1800.000 0.000 839.0253.643.850 10.021 248.18 0.00 180.0 8/6/2024 13:30 0.000249.4240.007 4.692 1.591500.707 1.152 2.317 9.5200.0510.000 1.269 251.1380.114 0.000 839.0254.784.198 10.051 249.42 0.00 180.0 8/6/2024 13:30 0.000249.5580.002 4.718 2.912500.988 1.186 1.920 9.8920.5720.000 1.228 251.0920.649 0.000 839.0254.283.551 10.067 249.56 0.00 180.0 8/6/2024 13:30 0.000249.5150.012 4.727 2.743502.937 1.161 1.659 11.0080.0780.000 1.197 250.1970.087 0.000 839.0253.213.314 10.069 249.52 0.00 180.0 8/6/2024 13:30 0.000249.633-0.000 4.724 1.335501.735 1.145 1.879 10.1050.0610.000 1.233 251.4490.000 0.000 839.0255.024.119 10.065 249.63 0.00 180.0 8/6/2024 13:31 0.000250.2610.003 4.727 2.762500.836 1.148 2.099 9.9270.2920.000 1.142 251.6610.188 0.000 839.0255.184.142 10.101 250.26 0.00 180.0 8/6/2024 13:31 0.000249.634-0.000 4.741 2.203503.675 1.203 2.137 9.7470.3740.000 1.125 251.4300.307 0.000 839.0254.633.673 10.092 249.63 0.00 180.0 8/6/2024 13:31 0.000249.8820.013 4.742 2.442502.734 1.146 1.727 11.0690.1890.000 1.176 250.3220.000 0.000 839.0253.673.844 10.082 249.88 0.00 180.0 End of Test Purge 8/6/2024 13:33 0.0000.467-0.000 0.000 1.4820.846 0.002 0.000 0.0000.0000.000 0.000 0.5730.081 0.000 839.01.391.230 0.001 0.47 0.00 180.0 8/6/2024 13:34 0.0000.0000.001 0.000 0.8570.647 0.020 0.030 0.4890.2020.000 0.000 0.3960.000 0.000 839.01.301.349 0.005 0.00 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/6/2024 13:34 0.0000.1770.003 0.000 0.7880.631 0.021 0.012 0.0000.1920.000 0.000 0.5300.067 0.000 839.01.150.923 0.003 0.18 0.00 180.0 8/6/2024 13:34 0.0000.0590.008 0.000 0.5780.617 0.027 0.000 0.3620.0000.000 0.000 0.2510.000 0.000 839.01.091.255 0.000 0.06 0.00 180.0 8/6/2024 13:34 0.0000.000-0.000 0.000 0.9360.635 0.011 0.049 0.3590.0000.658 0.000 0.2200.665 0.000 839.00.941.085 0.000 0.00 0.00 180.0 8/6/2024 13:34 0.0000.0000.007 0.000 0.0000.528 0.008 0.055 0.1770.0000.000 0.000 0.2110.480 0.000 839.00.931.078 0.000 0.00 0.00 180.0 8/6/2024 13:34 0.0000.0000.006 0.000 0.1450.537 0.007 0.023 0.0080.0130.380 0.000 0.3500.000 0.000 839.00.900.824 0.000 0.00 0.00 180.0 8/6/2024 13:34 0.0000.0000.001 0.000 0.6530.024 0.003 0.063 0.5450.2810.000 0.000 0.1970.000 0.000 839.00.840.972 0.003 0.00 0.00 180.0 8/6/2024 13:34 0.0000.000-0.000 0.000 0.7560.356 0.000 0.115 0.2250.0000.041 0.000 0.3460.213 0.000 839.01.271.388 0.007 0.00 0.00 180.0 8/6/2024 13:35 0.6630.102-0.000 0.000 0.6430.134 0.015 0.065 0.0760.0000.098 0.000 0.2650.823 0.000 839.00.860.887 0.006 0.77 0.00 180.0 GAS, Inc. Source Test Report For Ovintiv USA Incorporated Pleasant Valley Compressor Station Duchesne County, Utah Test Date: August 27, 2024 Report Date: September 5, 2024 UDEQ Permit: #DAQE-AN0142100007-23 Engine: Caterpillar G3516LE SN: WPW01912 Unit ID: #2 Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 September 5, 2024 Mr. Ryan Zillner Ovintiv USA Incorporated 370 17th Street, Suite 1700 Denver CO 80202 Dear Mr. Zillner: Re: Engine Emission Testing For Ovintiv USA Incorporated, Pleasant Valley Compressor Station, Unit #2, Permit #DAQE-AN0142100007-23. An air emissions test program was conducted on a Caterpillar G3516LE engine, operated by Ovintiv USA Incorporated and designated as Unit #2, located at the Pleasant Valley Compressor Station in Duchesne County, Utah. The purpose of the testing was to demonstrate annual compliance with the emissions limits contained in UDEQ Permit #DAQE-AN0142100007-23 and EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on August 27, 2024. UDEQ Permit #DAQE-AN0142100007-23 Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC lbs/hr 1.76 2.95 0.01 0.36 0.22 0.98 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). EPA 40 CFR 60, Subpart JJJJ Emission Levels Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.90 1.0 0.00 2.0 0.11 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 916 N/A Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 1340 892.6 66.6 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 & EPA 40 CFR 63(A), Method 320, as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Crystal Leonard Manager of Technical Services Senior EHS Specialist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT UDEQ Permit #DAQE-AN0142100007-23 Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: Ovintiv USA Incorporated Owner/Operator Contact: Ryan Zillner 370 17th Street, Suite 1700 Denver CO 80202 Facility Name: Pleasant Valley Compressor Station 576,723 m Easting, 4,444,226 m Northing UTM Zone 12 Duchesne County, Utah Emission Source: Caterpillar G3516LE Unit #2 Date of Test: August 27, 2024 Date of Report: September 5, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 1.2 Deviation .............................................................................................................................. 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters ............................................................................................................... 7 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................. 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Caterpillar G3516LE engine, operated by Ovintiv USA Incorporated and designated as Unit #2, located at the Pleasant Valley Compressor Station in Duchesne County, Utah. The purpose of the testing was to demonstrate annual compliance with the emissions limits contained in UDEQ Permit #DAQE-AN0142100007-23 and EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non-methane, non- ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is located adjacent to the Ovintiv Myton Field Office 10530 South, County Road 33 Myton, UT 84052. 576,723 m Easting, 4,444,226 m Northing, UTM Zone 12 Three one hour test runs were performed on August 27, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 & EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol dated May 17, 2024. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine RPM, air intake temperature, intake manifold pressure and site elevation. The following key personnel were present during testing: TJ Schmidtberger, OEC Brian Webb, Ovintiv 1.2 Deviation EPA 40 CFR 60(A) Method 3 was used instead of Method 3A for the determination of CO2 and O2 as was submitted in the original test protocol. 2 2.1 Stack Sampling Location The facility is located adjacent to the Ovintiv Myton Field Office 10530 South, County Road 33 Myton, UT 84052. 576,723 m Easting, 4,444,226 m Northing, UTM Zone 12 Testing was conducted on the Caterpillar G3516LE engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 3.1 pipe diameters (36”) downstream from the nearest flow disturbance (Distance B) and 10.4 pipe diameters (120”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. Figure 1 - Sample Port Location 11.5" A B Oxidation Catalyst 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on August 27, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate annual compliance with the emissions limits contained in the WDEQ Permit #DAQE-AN0142100007-23 and EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Caterpillar G3516LE, NOx, CO and VOC The first test was performed from 9:48 to 10:48 for NOx, CO and VOC. Based on operating parameters recorded during testing, the average, maximum load was approximated at 892.6 bhp, and the average NOx and CO levels were found to be 1.82 lbs/hr and 0.01 lbs/hr respectively, below limitations. The VOC level tested at 0.21 lbs/hr, which tested in compliance. 3.1.2 Source Test 2: Caterpillar G3516LE, NOx, CO and VOC The second test was performed from 10:50 to 11:49 for NOx, CO and VOC. Based on operating parameters recorded during testing, the average, maximum load was approximated at 892.6 bhp, and the average NOx and CO levels were found to be 1.72 lbs/hr and 0.01 lbs/hr respectively, below limitations. The VOC level tested at 0.22 lbs/hr, which tested in compliance. 3.1.3 Source Test 3: Caterpillar G3516LE, NOx, CO and VOC The third test was performed from 11:51 to 12:50 for NOx, CO and VOC. Based on operating parameters recorded during testing, the average, maximum load was approximated at 892.6 bhp, and the average NOx and CO levels were found to be 1.75 lbs/hr and 0.01 lbs/hr respectively, below limitations. The VOC level tested at 0.22 lbs/hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp- hr) NOx (lbs/hr) CO (ppmvd) CO (g/bhp- hr) CO (lbs/hr) VOC (ppmvd) VOC (g/bhp- hr) VOC (lbs/hr) O2 (%) 1 162.83 0.92 1.82 0.92 0.00 0.01 19.45 0.11 0.21 7.9 Test Run NOx (ppmvd) NOx (g/bhp- hr) NOx (lbs/hr) CO (ppmvd) CO (g/bhp- hr) CO (lbs/hr) VOC (ppmvd) VOC (g/bhp- hr) VOC (lbs/hr) O2 (%) 2 152.03 0.87 1.72 0.83 0.00 0.01 20.20 0.11 0.22 8.1 Test Run NOx (ppmvd) NOx (g/bhp- hr) NOx (lbs/hr) CO ppmvd) CO (g/bhp- hr) CO (lbs/hr) VOC (ppmvd) VOC (g/bhp- hr) VOC (lbs/hr O2 (%) 3 153.58 0.89 1.75 0.78 0.00 0.01 20.23 0.11 0.22 8.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 & EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 3 September 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. ASTM International. “Standards & Publications.” All Environment Standards. Web. 3 September 2024. <https://www.astm.org/Standards/D6348.htm>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 & EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters The engine operating parameters were used in order to determine the load. Parameters include the engine RPM, air intake temperature, intake manifold pressure and site elevation. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 90.1%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 142.636773 29.429424 172.066197 1.0835 18.425976 10.811681 9:48:57 08/27/2024 2 142.764756 29.452315 172.217071 0.971965 18.934548 10.85103 9:49:57 08/27/2024 3 141.773958 29.139787 170.913745 1.055529 18.451518 11.372074 9:50:57 08/27/2024 4 144.098156 29.709193 173.807349 0.762289 18.210226 11.236532 9:51:57 08/27/2024 5 142.496505 29.390781 171.887286 0.968296 19.442431 11.834013 9:52:57 08/27/2024 6 142.503319 29.483224 171.986543 0.837764 18.800834 11.885625 9:53:58 08/27/2024 7 143.332793 29.625025 172.957818 0.949367 18.633622 12.246435 9:54:58 08/27/2024 8 142.628103 29.444463 172.072566 1.033867 19.805127 12.749635 9:55:57 08/27/2024 9 143.932484 29.746789 173.679273 0.895009 18.411224 12.533874 9:56:57 08/27/2024 10 143.177791 29.650247 172.828038 1.043085 17.987011 12.064008 9:57:58 08/27/2024 11 144.086857 29.668455 173.755312 1.024569 18.622802 11.785429 9:58:58 08/27/2024 12 143.835284 29.673424 173.508708 0.93962 18.834392 11.810747 9:59:58 08/27/2024 13 142.579755 29.741656 172.321411 0.91531 18.578243 11.536575 10:00:58 08/27/2024 14 142.935572 29.743574 172.679146 0.970302 18.272273 11.156705 10:01:58 08/27/2024 15 143.369089 29.185298 172.554387 1.103211 20.602794 16.35843 10:02:58 08/27/2024 16 142.093406 29.058191 171.151597 0.998802 19.779101 17.098709 10:03:58 08/27/2024 17 143.845844 29.672647 173.518491 0.941848 18.087438 13.098349 10:04:58 08/27/2024 18 144.575063 30.042869 174.617932 0.892876 18.467317 12.822463 10:05:59 08/27/2024 19 143.110331 29.532734 172.643065 1.064084 19.146116 13.299893 10:06:59 08/27/2024 20 141.945209 29.277032 171.222241 1.056828 18.401125 13.364219 10:07:59 08/27/2024 21 142.122852 29.245933 171.368785 0.934178 18.492547 13.499252 10:08:59 08/27/2024 22 142.8437 29.465843 172.309543 1.000769 17.917165 13.664041 10:09:59 08/27/2024 23 142.172259 29.274444 171.446703 0.880721 18.423368 13.149791 10:10:59 08/27/2024 24 143.071471 28.88861 171.960081 1.033534 18.337553 13.232159 10:11:59 08/27/2024 25 143.804814 29.430046 173.23486 0.742677 18.879504 12.912641 10:12:59 08/27/2024 26 142.181565 29.290288 171.471853 0.818446 19.249613 12.836411 10:13:59 08/27/2024 27 143.596268 29.72919 173.325458 0.998535 18.521744 12.256886 10:14:59 08/27/2024 28 142.78589 29.530497 172.316387 0.927218 18.981575 12.052251 10:15:59 08/27/2024 29 142.995764 29.567575 172.563339 0.928845 18.331200 12.220687 10:16:59 08/27/2024 30 143.428464 29.821753 173.250217 0.996056 18.437253 12.113049 10:17:59 08/27/2024 31 143.496818 29.870192 173.36701 0.85785 19.735264 11.852642 10:18:59 08/27/2024 32 143.545136 30.107401 173.652537 0.811257 19.009253 12.28004 10:20:00 08/27/2024 33 142.064274 29.765249 171.829523 0.994403 19.369340 12.13237 10:21:00 08/27/2024 34 136.878846 29.117684 165.99653 0.899235 19.574137 11.872699 10:22:00 08/27/2024 35 124.925154 26.398244 151.323398 0.917344 20.270946 11.510677 10:23:00 08/27/2024 36 125.364359 26.592264 151.956623 0.789985 19.894460 11.087238 10:24:00 08/27/2024 37 123.776621 26.147113 149.923734 0.891966 20.146489 11.554413 10:25:00 08/27/2024 38 125.396951 26.758839 152.15579 0.780635 20.521285 11.544019 10:26:00 08/27/2024 39 124.677257 26.320131 150.997388 0.813783 20.273798 11.9068 10:27:00 08/27/2024 40 125.493231 26.608455 152.101686 0.827756 20.808669 12.049857 10:28:00 08/27/2024 41 125.116621 26.545375 151.661996 0.816673 20.261113 11.908036 10:29:00 08/27/2024 42 121.315078 25.895922 147.211 0.923799 19.998380 11.948464 10:30:00 08/27/2024 43 125.141473 26.239473 151.380946 0.980199 21.774552 17.735141 10:31:00 08/27/2024 44 124.997204 26.434842 151.432046 1.177087 21.597078 17.801779 10:32:01 08/27/2024 45 123.958355 26.272342 150.230697 1.01928 21.294658 15.76619 10:33:01 08/27/2024 46 123.486118 26.111359 149.597477 0.815568 20.523994 14.21939 10:34:01 08/27/2024 47 123.938183 26.367665 150.305848 0.937867 19.787605 13.873444 10:35:01 08/27/2024 48 124.29336 26.10772 150.40108 0.932879 19.733620 13.664125 10:36:01 08/27/2024 49 126.060725 26.672641 152.733366 0.928437 19.232032 13.363625 10:37:01 08/27/2024 50 125.185718 26.418534 151.604252 0.871257 19.478129 12.712109 10:38:01 08/27/2024 51 123.718892 26.294915 150.013807 0.715655 20.625207 12.380358 10:39:01 08/27/2024 52 122.36658 26.001872 148.368452 0.851513 19.804322 12.603034 10:40:02 08/27/2024 53 124.605351 26.571144 151.176495 0.915721 19.925568 12.331325 10:41:01 08/27/2024 54 123.589119 26.187484 149.776603 0.96082 20.303317 12.345958 10:42:02 08/27/2024 55 123.89027 25.535151 149.425421 0.845274 20.099476 12.544566 10:43:02 08/27/2024 56 123.067385 25.449833 148.517218 0.847723 20.044224 12.361413 10:44:02 08/27/2024 57 122.704535 25.530587 148.235122 0.892725 20.630945 12.266156 10:45:02 08/27/2024 58 124.574197 25.801635 150.375832 0.884472 20.638601 12.299098 10:46:02 08/27/2024 59 124.290197 26.130638 150.420835 0.780506 20.073860 12.674575 10:47:02 08/27/2024 60 122.478912 25.672945 148.151857 0.864345 20.130217 12.333361 10:48:02 08/27/2024 AVG 134.75 28.08 162.83 0.92 19.45 12.71 ppm@15% O2 73.90 0.42 8.83 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.92 1.82 0.00 0.01 0.11 0.21 #2 FTIR Measurements Calculated Emission Levels Ovintiv USA Incorporated Pleasant Valley Compressor Station Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 11.5 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.58 1276 0.40 1.257 Average O2 7.9 (% dry)A 2 1.21 1.54 1.241 Average CO2 7.2 (% dry)A 3 2.23 1.56 1.249 Average N2 + CO 84.9 (% dry)A 4 3.71 1.52 1.233 Dry Molecular Weight 29.47 lb/lbmol A 5 7.79 1.48 1.217 Wet Molecular Weight 28.01 lb/lbmol A 6 9.27 1.44 1.200 EPA REFERENCE METHOD 320 A 7 10.29 1.48 1.217 Barometric Pressure 25.01 in Hg A 8 11.00 1.50 1.225 Moisture Content 12.71 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 162.83 ppm A 11 Calculated NOx Mass Output 1.82 lbs/hr A 12 Calculated NOx Output 0.92 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 0.92 ppm A 15 Calculated CO Mass Output 0.01 lbs/hr A 16 Calculated CO Output 0.00 g/bhp-hr B 1 0.50 1.57 1276 0.40 1.253 EPA REFERENCE METHOD 320 B 2 1.21 1.56 1.249 Average Analyzer NMNEHC Level 19.45 ppm B 3 2.23 1.49 1.221 Calculated NMNEHC Mass Output 0.21 lbs/hr B 4 3.71 1.52 1.233 Calculated NMNEHC Output 0.11 g/bhp-hr B 5 7.79 1.55 1.245 LOAD APPROXIMATION B 6 9.27 1.45 1.204 Estimated Engine Load 892.6 BHP B 7 10.29 1.48 1.217 B 8 11.00 1.51 1.229 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.5 1276 0.4 1.230 Average Stack Gas Velocity 119.19 ft/sec Average Dry Flowrate 1559.18 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 124.290235 26.062137 150.352372 0.763817 20.195240 12.172083 10:50:02 08/27/2024 2 124.36537 26.273314 150.638684 0.776903 20.489018 12.062998 10:51:02 08/27/2024 3 124.955272 26.169063 151.124335 0.903824 20.442950 11.912616 10:52:02 08/27/2024 4 124.657966 26.249851 150.907817 0.948554 19.660826 11.720977 10:53:02 08/27/2024 5 124.415975 26.238909 150.654884 0.806527 19.642912 11.583085 10:54:02 08/27/2024 6 124.449659 26.166204 150.615863 0.916163 20.097993 11.382271 10:55:03 08/27/2024 7 125.93722 26.435718 152.372938 0.838613 20.641469 11.289999 10:56:03 08/27/2024 8 125.573503 26.322956 151.896459 0.753685 20.030303 11.453055 10:57:03 08/27/2024 9 125.59361 26.374341 151.967951 0.906094 20.288508 11.525279 10:58:03 08/27/2024 10 124.198772 26.237364 150.436136 0.794628 19.995057 11.56751 10:59:03 08/27/2024 11 123.282429 26.095327 149.377756 1.016577 20.427709 11.53006 11:00:03 08/27/2024 12 126.04886 26.572453 152.621313 0.889412 19.761233 11.331773 11:01:03 08/27/2024 13 125.176175 26.547754 151.723929 0.824199 19.924126 11.121951 11:02:03 08/27/2024 14 124.323425 26.464977 150.788402 0.855251 19.690048 10.866293 11:03:03 08/27/2024 15 125.392849 26.860164 152.253013 0.752975 19.563733 10.366112 11:04:03 08/27/2024 16 125.485091 26.842473 152.327564 0.724586 19.802399 10.352869 11:05:04 08/27/2024 17 125.013076 26.74938 151.762456 0.765249 19.989599 10.768437 11:06:03 08/27/2024 18 124.682854 26.38608 151.068934 0.839762 21.442706 16.720156 11:07:04 08/27/2024 19 123.199092 26.040935 149.240027 0.937446 22.042570 15.60818 11:08:04 08/27/2024 20 124.651933 26.409678 151.061611 0.945193 20.520025 15.131985 11:09:04 08/27/2024 21 126.238257 26.901701 153.139958 0.860587 20.097559 12.829967 11:10:04 08/27/2024 22 124.710036 26.459821 151.169857 0.674771 20.520895 12.75749 11:11:04 08/27/2024 23 126.752475 26.900498 153.652973 0.914684 19.976008 12.241332 11:12:04 08/27/2024 24 125.647947 26.869304 152.517251 0.752536 19.776049 11.562893 11:13:04 08/27/2024 25 125.057218 26.609798 151.667016 0.83078 19.940025 11.366946 11:14:05 08/27/2024 26 126.294068 26.829692 153.12376 0.997699 19.989483 11.538868 11:15:04 08/27/2024 27 124.955355 26.457205 151.41256 0.803944 20.278449 11.899874 11:16:04 08/27/2024 28 126.0682 26.577582 152.645782 0.730968 20.249866 12.225494 11:17:04 08/27/2024 29 126.3706 26.734977 153.105577 0.870936 19.802019 12.376024 11:18:05 08/27/2024 30 127.169696 26.964121 154.133817 1.000491 20.133724 12.560442 11:19:05 08/27/2024 31 125.424931 26.467271 151.892202 0.814187 20.060211 12.747946 11:20:05 08/27/2024 32 127.070309 26.972109 154.042418 0.783901 20.437939 12.621903 11:21:05 08/27/2024 33 128.488794 27.110527 155.599321 0.844879 19.888917 12.644269 11:22:05 08/27/2024 34 126.59414 26.675934 153.270074 0.804566 20.766243 12.754566 11:23:05 08/27/2024 35 126.453843 26.726307 153.18015 0.760175 20.721954 12.489231 11:24:05 08/27/2024 36 125.787031 26.69513 152.482161 0.860214 20.418800 12.620117 11:25:05 08/27/2024 37 123.695073 26.32382 150.018893 0.746303 20.394350 12.434985 11:26:06 08/27/2024 38 124.228697 26.308484 150.537181 0.959768 20.370111 12.289713 11:27:06 08/27/2024 39 124.477912 26.664096 151.142008 0.901974 21.118000 12.046563 11:28:05 08/27/2024 40 124.482305 26.55125 151.033555 0.848452 20.643007 11.929847 11:29:05 08/27/2024 41 124.527119 26.578066 151.105185 0.856002 20.836082 11.855681 11:30:06 08/27/2024 42 124.618507 26.694092 151.312599 0.902178 20.216534 11.548774 11:31:06 08/27/2024 43 125.764357 26.80087 152.565227 0.858861 20.554628 11.485388 11:32:06 08/27/2024 44 126.710248 26.974091 153.684339 0.797283 20.487824 11.51934 11:33:06 08/27/2024 45 125.586601 26.954743 152.541344 0.842066 20.495314 11.380819 11:34:06 08/27/2024 46 124.697301 26.797965 151.495266 0.897838 20.519027 11.337578 11:35:06 08/27/2024 47 127.104133 27.052929 154.157062 0.70539 20.080495 11.346527 11:36:06 08/27/2024 48 126.106017 27.002231 153.108248 0.700363 20.305940 10.938039 11:37:06 08/27/2024 49 127.164754 27.262865 154.427619 0.769493 20.299665 10.682224 11:38:06 08/27/2024 50 125.602268 26.855972 152.45824 0.978716 20.217124 10.799812 11:39:06 08/27/2024 51 125.507594 27.016452 152.524046 0.676293 19.567749 10.932598 11:40:06 08/27/2024 52 127.586283 27.196554 154.782837 0.980204 19.957268 11.034702 11:41:07 08/27/2024 53 125.146153 26.789728 151.935881 0.851246 20.223174 10.913498 11:42:07 08/27/2024 54 125.55816 26.883328 152.441488 0.846336 19.691253 10.561194 11:43:07 08/27/2024 55 126.913115 27.322619 154.235734 0.778291 19.978391 9.836658 11:44:07 08/27/2024 56 127.832017 27.636982 155.468999 0.741786 20.303245 9.140066 11:45:07 08/27/2024 57 126.74383 27.403197 154.147027 0.71728 19.173238 8.628279 11:46:07 08/27/2024 58 123.002052 26.698089 149.700141 0.722349 19.797954 8.215008 11:47:07 08/27/2024 59 122.446414 26.598443 149.044857 0.724639 19.794357 8.112692 11:48:07 08/27/2024 60 121.196635 26.329298 147.525933 0.861562 19.520767 8.051682 11:49:08 08/27/2024 AVG 125.36 26.67 152.03 0.83 20.20 11.58 ppm@15% O2 70.07 0.38 9.31 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.87 1.72 0.00 0.01 0.11 0.22 Calculated Emission Levels Record Date Ovintiv USA Incorporated Pleasant Valley Compressor Station Run 2 #2 FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 11.5 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.59 1277 0.42 1.261 Average O2 8.1 (% dry)A 2 1.21 1.58 1.257 Average CO2 7.2 (% dry)A 3 2.23 1.51 1.229 Average N2 + CO 84.7 (% dry)A 4 3.71 1.55 1.245 Dry Molecular Weight 29.48 lb/lbmol A 5 7.79 1.49 1.221 Wet Molecular Weight 28.15 lb/lbmol A 6 9.27 1.58 1.257 EPA REFERENCE METHOD 320 A 7 10.29 1.46 1.208 Barometric Pressure 24.99 in Hg A 8 11.00 1.55 1.245 Moisture Content 11.58 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 152.03 ppm A 11 Calculated NOx Mass Output 1.72 lbs/hr A 12 Calculated NOx Output 0.87 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 0.83 ppm A 15 Calculated CO Mass Output 0.01 lbs/hr A 16 Calculated CO Output 0.00 g/bhp-hr B 1 0.50 1.55 1277 0.41 1.245 EPA REFERENCE METHOD 320 B 2 1.21 1.59 1.261 Average Analyzer NMNEHC Level 20.20 ppm B 3 2.23 1.52 1.233 Calculated NMNEHC Mass Output 0.22 lbs/hr B 4 3.71 1.56 1.249 Calculated NMNEHC Output 0.11 g/bhp-hr B 5 7.79 1.44 1.200 LOAD APPROXIMATION B 6 9.27 1.48 1.217 Estimated Engine Load 892.6 BHP B 7 10.29 1.45 1.204 B 8 11.00 1.49 1.221 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.5 1277 0.4 1.234 Average Stack Gas Velocity 119.37 ft/sec Average Dry Flowrate 1579.50 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 124.136036 26.867546 151.003582 0.653914 20.058659 8.129905 11:51:08 08/27/2024 2 123.678404 26.388462 150.066866 0.818557 21.121399 12.694117 11:52:07 08/27/2024 3 125.289222 26.754431 152.043653 0.750686 20.358692 11.932302 11:53:07 08/27/2024 4 126.292618 27.004034 153.296652 0.626265 20.360336 11.702684 11:54:08 08/27/2024 5 125.94608 26.873215 152.819295 0.643438 19.692974 11.161733 11:55:08 08/27/2024 6 125.334348 27.032566 152.366914 0.782482 19.872746 11.091769 11:56:08 08/27/2024 7 124.190958 26.765707 150.956665 0.564259 19.518210 10.505573 11:57:08 08/27/2024 8 126.010922 26.903662 152.914584 0.758467 20.004716 10.579953 11:58:08 08/27/2024 9 126.974513 27.31894 154.293453 0.782284 19.937144 11.087104 11:59:08 08/27/2024 10 128.113765 27.238639 155.352404 0.77505 20.389177 11.337493 12:00:08 08/27/2024 11 125.944097 27.16187 153.105967 0.778925 19.860449 11.59212 12:01:08 08/27/2024 12 124.683436 26.72855 151.411986 0.810351 20.973104 12.10794 12:02:09 08/27/2024 13 124.798374 26.583638 151.382012 0.791627 20.092389 12.082548 12:03:08 08/27/2024 14 125.576298 26.666619 152.242917 0.84779 19.561628 11.460721 12:04:09 08/27/2024 15 127.76408 27.20636 154.97044 0.788081 20.138180 10.790558 12:05:09 08/27/2024 16 127.489174 27.266286 154.75546 0.808239 19.138356 10.299068 12:06:09 08/27/2024 17 127.912614 27.481136 155.39375 0.502147 20.553362 10.128537 12:07:09 08/27/2024 18 128.573224 27.779092 156.352316 0.689369 20.370952 10.329269 12:08:09 08/27/2024 19 124.96406 27.020185 151.984245 0.684946 20.355574 10.344824 12:09:09 08/27/2024 20 122.241614 26.534622 148.776236 0.719672 20.250132 10.52075 12:10:09 08/27/2024 21 123.560191 26.6299 150.190091 0.855479 20.007726 10.759092 12:11:09 08/27/2024 22 124.127777 26.742573 150.87035 0.896913 20.443194 10.527883 12:12:09 08/27/2024 23 124.983858 26.714431 151.698289 0.784642 19.857263 10.681364 12:13:09 08/27/2024 24 128.680166 27.678287 156.358453 0.820111 19.837535 10.855135 12:14:09 08/27/2024 25 126.384071 27.200872 153.584943 0.707042 20.843282 11.290033 12:15:10 08/27/2024 26 126.997184 27.420984 154.418168 0.859772 20.784770 12.808822 12:16:10 08/27/2024 27 126.580414 27.196025 153.776439 0.816711 20.469664 11.57495 12:17:10 08/27/2024 28 127.154184 27.536333 154.690517 0.768681 20.232865 10.983253 12:18:10 08/27/2024 29 126.518792 27.651818 154.17061 0.709681 20.071043 10.60429 12:19:10 08/27/2024 30 126.338542 27.334017 153.672559 0.821817 19.818993 10.22442 12:20:10 08/27/2024 31 127.127962 27.642706 154.770668 0.837029 20.437502 10.005942 12:21:10 08/27/2024 32 128.408155 27.821834 156.229989 0.824302 20.338821 10.629982 12:22:10 08/27/2024 33 125.94752 27.120452 153.067972 0.980172 20.459270 12.257169 12:23:10 08/27/2024 34 124.529249 26.785783 151.315032 0.794567 19.955520 11.859911 12:24:10 08/27/2024 35 124.684762 26.748829 151.433591 0.823532 20.610323 12.713192 12:25:10 08/27/2024 36 126.10021 27.102396 153.202606 0.731911 20.578642 13.007934 12:26:10 08/27/2024 37 126.515318 27.422668 153.937986 0.729323 20.947560 11.093824 12:27:10 08/27/2024 38 127.974911 27.593298 155.568209 0.80413 19.760547 10.475515 12:28:10 08/27/2024 39 126.566039 27.364929 153.930968 0.708593 19.949376 10.402289 12:29:11 08/27/2024 40 124.960165 26.92907 151.889235 0.817166 19.746680 10.565625 12:30:11 08/27/2024 41 126.302056 27.282936 153.584992 0.799166 20.060075 10.777613 12:31:11 08/27/2024 42 127.666288 27.819125 155.485413 0.791418 19.725701 10.955234 12:32:11 08/27/2024 43 126.12242 27.253672 153.376092 0.994388 20.612518 12.096585 12:33:11 08/27/2024 44 126.716223 27.522068 154.238291 0.709019 20.835471 11.741159 12:34:11 08/27/2024 45 126.177291 27.042956 153.220247 0.762083 20.628462 11.912268 12:35:11 08/27/2024 46 125.408269 26.95235 152.360619 0.852945 19.992925 12.158374 12:36:11 08/27/2024 47 127.885848 27.658629 155.544477 0.69495 19.874706 10.655942 12:37:11 08/27/2024 48 127.216996 27.490744 154.70774 0.797364 20.159678 10.700745 12:38:11 08/27/2024 49 127.995866 27.651067 155.646933 1.003283 19.267549 10.935371 12:39:11 08/27/2024 50 128.245099 27.691857 155.936956 0.685944 19.658310 11.047648 12:40:11 08/27/2024 51 126.6063 27.391193 153.997493 0.800926 20.941272 11.838769 12:41:12 08/27/2024 52 128.383718 27.66644 156.050158 0.705808 20.443643 13.095044 12:42:12 08/27/2024 53 127.552881 27.29531 154.848191 0.805068 20.282578 13.427473 12:43:12 08/27/2024 54 127.122639 27.292674 154.415313 0.788938 20.082430 12.890589 12:44:12 08/27/2024 55 127.591638 27.568639 155.160277 0.774508 20.431401 11.563975 12:45:12 08/27/2024 56 127.309982 27.825066 155.135048 0.849327 20.532643 11.177814 12:46:12 08/27/2024 57 125.977702 27.258216 153.235918 0.797653 20.962299 11.279176 12:47:12 08/27/2024 58 126.333878 27.477868 153.811746 0.785387 20.295244 11.334058 12:48:12 08/27/2024 59 127.870344 27.80269 155.673034 0.779181 20.662406 11.513001 12:49:12 08/27/2024 60 126.78552 27.487556 154.273076 0.810225 20.562100 12.050774 12:50:12 08/27/2024 AVG 126.36 27.23 153.58 0.78 20.23 11.27 ppm@15% O2 70.24 0.36 9.25 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.89 1.75 0.00 0.01 0.11 0.22 FTIR Measurements #2 Calculated Emission Levels Ovintiv USA Incorporated Pleasant Valley Compressor Station Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 11.5 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.62 1275 0.41 1.273 Average O2 8.0 (% dry)A 2 1.21 1.55 1.245 Average CO2 7.2 (% dry)A 3 2.23 1.59 1.261 Average N2 + CO 84.8 (% dry)A 4 3.71 1.51 1.229 Dry Molecular Weight 29.47 lb/lbmol A 5 7.79 1.52 1.233 Wet Molecular Weight 28.18 lb/lbmol A 6 9.27 1.55 1.245 EPA REFERENCE METHOD 320 A 7 10.29 1.59 1.261 Barometric Pressure 24.98 in Hg A 8 11.00 1.58 1.257 Moisture Content 11.27 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 153.58 ppm A 11 Calculated NOx Mass Output 1.75 lbs/hr A 12 Calculated NOx Output 0.89 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 0.78 ppm A 15 Calculated CO Mass Output 0.01 lbs/hr A 16 Calculated CO Output 0.00 g/bhp-hr B 1 0.50 1.58 1275 0.41 1.257 EPA REFERENCE METHOD 320 B 2 1.21 1.57 1.253 Average Analyzer NMNEHC Level 20.23 ppm B 3 2.23 1.51 1.229 Calculated NMNEHC Mass Output 0.22 lbs/hr B 4 3.71 1.48 1.217 Calculated NMNEHC Output 0.11 g/bhp-hr B 5 7.79 1.49 1.221 LOAD APPROXIMATION B 6 9.27 1.44 1.200 Estimated Engine Load 892.6 BHP B 7 10.29 1.46 1.208 B 8 11.00 1.51 1.229 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.5 1275 0.4 1.239 Average Stack Gas Velocity 119.63 ft/sec Average Dry Flowrate 1590.18 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) spanCO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm)8/27/2024 9:14:15 -0.285891 -0.24286 0.002016 0.05401 -0.944002 0.853204 -0.141909 -0.185869 -0.185873 0.02461 -0.528751 -0.528762 0.340001 190.579636 1.0407518/27/2024 9:14:22 -0.099561 -0.271237 0.009042 0.105897 0.482949 -1.285679 -1.154895 -0.177467 -0.177483 -0.001183 -0.370798 -0.370832 0.08118 190.609924 1.0437768/27/2024 9:14:30 -0.142669 -0.308017 -0.005259 0.120467 -0.16025 -1.014591 -0.41338 -0.227481 -0.227469 0.020571 -0.450686 -0.450662 0.211483 190.580841 1.038635 8/27/2024 9:14:38 -0.0725 -0.295185 0.002009 0.098166 -0.671411 -0.125987 0.276967 -0.188874 -0.188878 -0.006652 -0.367685 -0.367692 0.085112 190.566315 1.037358/27/2024 9:15:16 0 0 0 0 0 0 0 0 0 0 0 0 0 190.580414 1.039258 8/27/2024 9:15:30 0.164901 0.068406 0.003253 0.065898 -1.283873 -0.234088 0.28551 0.286357 0.286367 0.022228 0.233308 0.233315 0.028936 190.638992 1.0366278/27/2024 9:15:37 -0.002509 0.00095 0.001977 -0.183749 -1.014672 -0.743721 -0.353376 0.220704 0.220708 0.003045 -0.001558 -0.001559 0.001407 190.682602 1.0395078/27/2024 9:15:45 0.502938 0.016584 0.002481 0.091703 -2.017885 0.798526 -0.309186 0.064177 0.064179 -0.000982 0.519522 0.519535 0.30364 190.682602 1.0346888/27/2024 9:15:52 -0.020351 -0.085137 -0.004936 -0.150775 -1.174313 -0.855078 -0.18552 -0.487519 -0.487495 0.011063 -0.105488 -0.105483 -0.006738 190.769806 1.0407018/27/2024 9:16:00 0.150743 -0.016814 -0.00204 0.129024 0.280171 -0.511456 -1.090711 0.344727 0.34472 0.020696 0.133929 0.133926 0.002961 190.880646 1.0350618/27/2024 9:16:07 0.197639 0.026135 0.00516 -0.185994 -0.983897 0.081654 0.287732 0.16509 0.165098 -0.00161 0.223773 0.223785 0.009327 190.910324 1.0396538/27/2024 9:16:15 -0.25219 0.111655 0.001919 0.059166 0.407683 0.057102 -0.283325 0.028466 0.028467 0.013705 -0.140536 -0.140538 -0.010713 190.906082 1.03257 8/27/2024 9:16:22 0.324504 -0.119432 0.003994 0.168568 -0.208225 -0.488361 0.575105 0.167938 0.167944 -0.022507 0.205072 0.20508 -0.00476 190.929703 1.0334028/27/2024 9:16:30 -0.071377 0.019827 -0.002007 0.18216 -0.118366 -0.240511 -0.201847 0.123427 0.123425 0.018606 -0.051551 -0.05155 -0.007334 190.958771 1.038222 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/27/2024 9:16:53 488.138712 462.651485 479.884091 190.884888 1.028648 8/27/2024 9:18:21 92.98631 190.605072 1.0426258/27/2024 9:17:00 507.4654 485.618104 500.594114 190.75528 1.026471 8/27/2024 9:18:28 96.074748 190.580841 1.04754 8/27/2024 9:17:07 507.869536 486.49016 500.824408 190.75528 1.029546 8/27/2024 9:18:35 95.707849 190.609924 1.0490098/27/2024 9:17:15 507.55661 484.754743 499.757408 190.842484 1.035192 8/27/2024 9:18:43 95.735649 190.595383 1.0528198/27/2024 9:17:22 507.454185 483.856377 500.428429 190.813416 1.031474 8/27/2024 9:18:51 96.207071 190.58812 1.0492398/27/2024 9:17:30 506.343581 484.702148 500.07512 190.726212 1.030924 8/27/2024 9:18:58 96.647173 190.58812 1.0451158/27/2024 9:17:37 503.107064 483.362041 495.02358 190.66806 1.033219 8/27/2024 9:19:06 96.83597 190.58812 1.0540588/27/2024 9:17:45 504.590602 482.68499 502.334869 190.651703 1.031124 8/27/2024 9:19:13 94.075251 190.566315 1.0534168/27/2024 9:17:52 507.485748 484.874984 502.949502 190.638992 1.028491 8/27/2024 9:19:21 95.948668 190.595383 1.052819 8/27/2024 9:18:00 505.985266 480.651845 498.303583 190.653519 1.033907 8/27/2024 9:19:28 95.751337 190.551773 1.052222 Date Time NO2 191C span Temp ( C )Pressure (atm)8/27/2024 9:19:49 107.991942 190.596588 1.0312188/27/2024 9:19:56 132.07175 190.580841 1.0349638/27/2024 9:20:03 134.745543 190.609924 1.034733 8/27/2024 9:20:11 135.573322 190.551773 1.038368/27/2024 9:20:18 135.692574 190.566315 1.0435018/27/2024 9:20:26 135.623817 190.624451 1.0608068/27/2024 9:20:34 135.960481 190.575394 1.0629758/27/2024 9:20:41 136.370366 190.566315 1.0635148/27/2024 9:20:48 136.940787 190.566315 1.0591538/27/2024 9:20:56 141.89546 190.580841 1.06815 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/27/2024 9:21:21 8.310684 136.148866 2.755826 190.571152 1.016893 8/27/2024 9:22:51 4.849385 190.571152 1.0117528/27/2024 9:21:28 12.375119 248.49486 12.28744 190.595383 1.015317 8/27/2024 9:22:58 4.283427 190.551773 1.0127468/27/2024 9:21:36 1.472919 283.603089 9.864585 190.566315 1.026333 8/27/2024 9:23:06 16.233227 190.551773 1.042958/27/2024 9:21:43 380.550496 422.340441 354.965063 190.580841 1.050845 8/27/2024 9:23:13 89.150089 190.580841 1.07499 8/27/2024 9:21:50 509.447795 486.104323 486.015249 190.551773 1.052589 8/27/2024 9:23:21 94.679708 190.551773 1.0741648/27/2024 9:21:58 512.689551 487.420811 498.374988 190.551773 1.056308 8/27/2024 9:23:28 94.460257 190.580841 1.075082 8/27/2024 9:22:05 512.186981 487.619963 498.467195 190.575394 1.05683 8/27/2024 9:23:36 96.487779 190.537247 1.0742218/27/2024 9:22:13 515.348943 489.508876 498.389791 190.537247 1.052773 8/27/2024 9:23:44 96.17986 190.537247 1.0771938/27/2024 9:22:21 511.369292 485.900012 496.434252 190.580841 1.056353 8/27/2024 9:23:51 94.940024 190.537247 1.0792598/27/2024 9:22:28 514.466673 489.85123 501.457218 190.580841 1.050753 8/27/2024 9:23:58 97.464275 190.549957 1.076269 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm)8/27/2024 9:24:21 0.003144 0.804129 0.120407 -0.063118 190.537247 1.0569968/27/2024 9:24:28 0.282755 0.763128 -0.749673 -0.312386 190.537247 1.0600728/27/2024 9:24:36 -0.136143 0.268277 -0.707172 -1.700322 190.566315 1.0589248/27/2024 9:24:44 -0.016015 0.317559 0.042945 -0.974507 190.551773 1.0592918/27/2024 9:24:51 0.644305 0.176076 0.726947 0.716534 190.551773 1.060622 8/27/2024 9:24:58 -0.076433 0.467283 -0.730243 -0.357365 190.537247 1.0601238/27/2024 9:25:06 0.119729 -0.260168 -0.280159 -1.239221 190.580841 1.058098 8/27/2024 9:25:14 -0.022802 0.32067 -0.014674 -0.823641 190.566315 1.058603 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm) 8/27/2024 9:42:48 6.265928 12.220715 190.121765 1.0036128/27/2024 9:42:55 6.258653 10.601593 190.115707 1.0031998/27/2024 9:43:03 6.292375 11.374588 190.115707 1.00158/27/2024 9:43:18 6.370888 11.093591 190.114166 1.0040358/27/2024 9:43:25 6.357106 11.691519 190.130234 1.0063438/27/2024 9:43:33 6.329941 10.250282 190.144775 1.0089828/27/2024 9:43:48 6.333017 11.488104 190.194504 1.00762 8/27/2024 9:43:55 6.340575 11.972623 190.33374 1.0080038/27/2024 9:44:03 6.355819 11.546094 190.33374 1.0089368/27/2024 9:44:10 4.342246 62.120602 190.522705 1.0079728/27/2024 9:44:18 0.263427 263.344121 190.537247 1.0096718/27/2024 9:44:25 0.092957 435.204455 190.638992 1.0056778/27/2024 9:44:33 0.089424 437.910757 190.677139 1.0061028/27/2024 9:44:41 4.397517 125.029788 190.697128 1.002097 8/27/2024 9:44:48 5.837096 50.092939 190.900635 1.0031998/27/2024 9:44:55 5.892575 48.803023 190.944244 1.007376 8/27/2024 9:45:03 5.908411 45.580374 190.973312 1.005548/27/2024 9:45:10 5.861898 50.435884 190.995117 1.0020858/27/2024 9:45:18 5.760141 55.109866 191.075058 1.0085698/27/2024 9:45:33 5.575633 69.723726 191.215576 1.0038628/27/2024 9:45:41 5.576381 70.811563 191.249496 1.0005068/27/2024 9:45:48 5.546862 71.30914 191.3367 1.0048058/27/2024 9:45:56 5.641697 64.394069 191.351242 1.005035 8/27/2024 9:46:03 5.783916 52.657267 191.351242 1.0100388/27/2024 9:46:11 6.277183 21.630164 191.363953 1.0057 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 8/27/2024 12:57:33 477.237142 450.495955 459.331414 190.620483 1.049969 8/27/2024 12:56:07 89.272114 190.995117 1.0634578/27/2024 12:57:41 505.264767 482.306813 488.921329 190.651703 1.052934 8/27/2024 12:56:14 94.971308 190.987854 1.069619 8/27/2024 12:57:48 505.039495 482.271239 492.726083 190.66806 1.051304 8/27/2024 12:56:22 95.693833 191.016922 1.0709968/27/2024 12:57:56 508.249779 486.263113 499.230558 190.769806 1.044924 8/27/2024 12:56:29 94.520412 190.958771 1.0696198/27/2024 12:58:03 509.545552 489.72232 492.527016 190.75528 1.048688 8/27/2024 12:56:37 95.108583 190.880646 1.0717718/27/2024 12:58:11 509.706113 488.343141 496.41243 190.857025 1.046806 8/27/2024 12:56:44 94.555513 190.740738 1.0733918/27/2024 12:58:18 510.115096 489.559356 497.57233 190.857025 1.045475 8/27/2024 12:56:52 98.008892 190.740738 1.0701648/27/2024 12:58:26 508.095087 488.159807 496.186723 190.906082 1.049279 8/27/2024 12:57:00 96.283407 190.697128 1.0713638/27/2024 12:58:33 505.165721 485.940054 492.717577 190.929703 1.051075 8/27/2024 12:57:07 96.597822 190.71167 1.071042 8/27/2024 12:58:41 509.742915 487.7349 500.737713 190.958771 1.050386 8/27/2024 12:57:14 95.005577 190.71167 1.071685 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/27/2024 12:56:22 0.108265 0.636952 -0.239544 191.016922 1.070996 8/27/2024 12:59:15 0.187964 191.147736 1.056721 8/27/2024 12:56:29 0.174414 0.145058 0.245917 190.958771 1.069619 8/27/2024 12:59:22 0.51282 191.04599 1.0612658/27/2024 12:56:37 -0.092801 0.229362 0.628081 190.880646 1.071771 8/27/2024 12:59:30 0.531714 191.04599 1.058281 8/27/2024 12:56:44 -0.256003 -0.161076 -0.147763 190.740738 1.073391 8/27/2024 12:59:37 -0.690436 191.04599 1.0571348/27/2024 12:56:52 0.277072 0.496272 0.999825 190.740738 1.070164 8/27/2024 12:59:45 -0.399933 191.104126 1.0552528/27/2024 12:57:00 0.240867 0.129762 0.160268 190.697128 1.071363 8/27/2024 12:59:53 -0.458632 191.060532 1.0567218/27/2024 12:57:07 0.202015 -0.109725 1.43443 190.71167 1.071042 8/27/2024 13:00:00 0.285538 191.058716 1.0587988/27/2024 12:57:14 -0.096554 0.44772 -1.238909 190.71167 1.071685 8/27/2024 13:00:08 -1.337378 191.04599 1.05454 POST SYSTEM ZERO SAMPLE SPIKE RECOVERY POST SYSTEM CAL PRE TEST 1 495.6 6.3 11.3 5.7 60.0 0.098 90.1% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 484.9 493.4 0.1 -1.73 0.03 CO 507.5 520.2 0.1 -2.44 0.02 Propane 502.9 495.6 -0.2 1.48 -0.05 Ethylene 96.8 100.1 -0.7 -3.26 -0.75 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 489.9 493.4 0.4 -0.72 0.07 CO 514.5 520.2 0.1 -1.10 0.02 Propane 501.5 495.6 -0.2 1.18 -0.05 Ethylene*97.5 100.1 -0.6 -2.63 -0.56 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 487.7 493.4 0.2 -1.15 0.04 0.43 0.03 CO 509.7 520.2 0.1 -2.01 0.02 0.91 0.00 Propane 500.7 495.6 0.4 1.04 0.09 0.15 0.13 Ethylene*96.6 100.1 0.0 -3.50 0.03 0.87 0.59 *CTS Scans are conducted with Ethylene through the sample line. Lf 5.11 Lr Cr Tr Pr Lr/Lf 5.00 96.8 190.6 1.1 0.98 Ls Cs Ts Ps Ls/Lf 4.86 97.5 190.5 1.1 0.95 % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration Pathlength Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL Ovintiv – Pleasant Valley CS 8-27-24 Ovintiv – Pleasant Valley CS 8-27-24 Ovintiv – Pleasant Valley CS 8-27-24 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report - Run 1 Sample Filename: C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000125.LAB Filename for noise: C:\OLT\2024 Data\Hilcorp\South Moxa E2 6-4-24\SOUTH MOXA E2 6-4-24_000011.LAB Interferences Filenames: C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000068.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000069.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000070.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000071.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000072.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000073.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000074.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000075.LAB Recipe path: C:\OLT\RECIPES\NEW TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 127.62 3.85 -0.79 1.07 5.27 5.27 -2.55 --0-2795 1.05 Good NO2 191C 25.53 0.38 -0.08 0.09 0.41 0.41 -0.51 --0-488 1.04 Good N2O 191C -0.02 0.29 0.1 0.09 0.11 0.33 0.33 0.11 0.21 0.01 0.03 0-200 -Close to DL NH3 TE 191C 11.86 49.45 10.88 10.86 18.54 84.39 84.39 11.11 38.77 0.23 3.63 0-2995 -Close to DL H2O% (HIGH) 191C12.84 0.28 -0.04 0.07 0.45 0.45 -0.26 --0-40 -Good FORMALDEHYDE 191C2.36 0.79 2.07 0.62 0.7 0.9 0.9 2.32 2.33 0.25 0.69 0-69 -Close to DL FORMIC ACID 191C TE1.24 7.39 4.52 3.65 4.27 8.65 8.65 4.68 4.68 0.16 1.51 0-466 -Close to DL CH4 2900 CM-1 191C665.28 20.33 -3.9 5.67 39.19 39.19 -13.31 --0-3143 0.99 Good PROPANE 191C11.74 1.02 13.31 0.55 0.67 1.23 1.23 14.62 14.62 1.31 4.44 0-4976 0.97 Close to DL PROPYLENE 191C TE-1.07 7.74 5.85 3.86 4.57 9.16 9.16 6.26 6.26 0.41 1.95 0-194 -Close to DL ETHANE 191C 45.59 1.93 -1.26 1.96 3.01 3.01 -0.91 --0-1004 -Good ETHYLENE 191C TE7.74 19.41 10.07 5.17 6.38 23.95 23.95 10.56 14.16 0.49 3.36 0-900 -Close to DL CO PPM 191C (1OF2)0.74 1.09 0.87 0.47 1.01 2.35 2.35 1.03 1.03 0.16 0.29 0-5010 1.05 Close to DL CO2% 191C 6.28 0.14 -0.03 0.04 0.19 0.19 -0.13 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.81 2.17 1.75 1.67 2.15 2.78 2.78 1.89 1.89 0.15 0.58 0-186 1.04 Close to DL ACETYLENE 191C0.67 4.4 1.09 1.83 2.42 5.81 5.81 1.16 2.62 0.07 0.36 0-1016 -Close to DL SO2 191C 2.89 2.61 1.58 1.02 1.24 3.19 3.19 2.09 2.09 0.51 0.53 0-964 -Close to DL HEXANE 191C 0.27 0.7 0.33 0.32 0.43 0.95 0.95 0.33 0.38 0 0.11 0-1000 -Close to DL Analysis Validation Report - Run 2 Sample Filename: C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000182.LAB Filename for noise: C:\OLT\2024 Data\Hilcorp\South Moxa E2 6-4-24\SOUTH MOXA E2 6-4-24_000011.LAB Interferences Filenames: C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000068.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000069.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000070.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000071.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000072.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000073.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000074.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000075.LAB Recipe path: C:\OLT\RECIPES\NEW TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 111.71 3.8 -0.79 1.07 5.21 5.21 -2.23 --0-2795 1.05 Good NO2 191C 23.06 0.38 -0.08 0.09 0.4 0.4 -0.46 --0-488 1.04 Good N2O 191C -0.03 0.35 0.1 0.09 0.11 0.4 0.4 0.11 0.27 0.01 0.03 0-200 -Close to DL NH3 TE 191C 12.03 51.06 10.88 10.86 18.54 87.14 87.14 11.11 40.38 0.23 3.63 0-2995 -Close to DL H2O% (HIGH) 191C12.69 0.31 -0.04 0.07 0.5 0.5 -0.25 --0-40 -Good FORMALDEHYDE 191C2.46 0.81 2.07 0.62 0.7 0.91 0.91 2.32 2.33 0.25 0.69 0-69 -Close to DL FORMIC ACID 191C TE1.87 7.53 4.52 3.65 4.27 8.81 8.81 4.68 4.68 0.16 1.51 0-466 -Close to DL CH4 2900 CM-1 191C662.31 21.57 -3.9 5.67 41.57 41.57 -13.25 --0-3143 0.99 Good PROPANE 191C12.71 1.02 13.31 0.55 0.67 1.22 1.22 14.62 14.62 1.31 4.44 0-4976 0.97 Close to DL PROPYLENE 191C TE-0.64 8.26 5.85 3.86 4.57 9.78 9.78 6.26 6.26 0.41 1.95 0-194 -Close to DL ETHANE 191C 46.35 2.09 -1.26 1.96 3.25 3.25 -0.93 --0-1004 -Good ETHYLENE 191C TE8.55 19.76 10.07 5.17 6.38 24.38 24.38 10.56 14.49 0.49 3.36 0-900 -Close to DL CO PPM 191C (1OF2)0.65 1.1 0.87 0.47 1.01 2.37 2.37 1.03 1.03 0.16 0.29 0-5010 1.05 Close to DL CO2% 191C 6.21 0.14 -0.03 0.04 0.19 0.19 -0.12 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.96 2.25 1.75 1.67 2.15 2.88 2.88 1.89 1.89 0.15 0.58 0-186 1.04 Close to DL ACETYLENE 191C0.83 4.48 1.09 1.83 2.42 5.92 5.92 1.16 2.7 0.07 0.36 0-1016 -Close to DL SO2 191C 2.93 2.74 1.58 1.02 1.24 3.35 3.35 2.09 2.09 0.51 0.53 0-964 -Close to DL HEXANE 191C -0.11 0.71 0.33 0.32 0.43 0.96 0.96 0.33 0.4 0 0.11 0-1000 -Close to DL Analysis Validation Report - Run 3 Sample Filename: C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000245.LAB Filename for noise: C:\OLT\2024 Data\Hilcorp\South Moxa E2 6-4-24\SOUTH MOXA E2 6-4-24_000011.LAB Interferences Filenames: C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000068.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000069.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000070.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000071.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000072.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000073.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000074.LAB C:\OLT\2024 Data\Ovintiv\Pleasant Valley CS #2 8-27-24\PLEASANT VALLEY CS #2 8-27-24_000075.LAB Recipe path: C:\OLT\RECIPES\NEW TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 117.92 3.59 -0.79 1.07 4.92 4.92 -2.36 --0-2795 1.05 Good NO2 191C 24.67 0.35 -0.08 0.09 0.37 0.37 -0.49 --0-488 1.04 Good N2O 191C 0.03 0.32 0.1 0.09 0.11 0.37 0.37 0.11 0.25 0.01 0.03 0-200 -Close to DL NH3 TE 191C 9.75 45.38 10.88 10.86 18.54 77.45 77.45 11.11 34.76 0.23 3.63 0-2995 -Close to DL H2O% (HIGH) 191C10.86 0.26 -0.04 0.07 0.43 0.43 -0.22 --0-40 -Good FORMALDEHYDE 191C2.17 0.81 2.07 0.62 0.7 0.91 0.91 2.32 2.33 0.25 0.69 0-69 -Close to DL FORMIC ACID 191C TE0.96 7.49 4.52 3.65 4.27 8.77 8.77 4.68 4.68 0.16 1.51 0-466 -Close to DL CH4 2900 CM-1 191C666.2 21.06 -3.9 5.67 40.6 40.6 -13.32 --0-3143 0.99 Good PROPANE 191C13.32 1.02 13.31 0.55 0.67 1.22 1.22 14.62 14.62 1.31 4.44 0-4976 0.97 Close to DL PROPYLENE 191C TE-0.91 8.05 5.85 3.86 4.57 9.52 9.52 6.26 6.26 0.41 1.95 0-194 -Close to DL ETHANE 191C 46.99 2.07 -1.26 1.96 3.22 3.22 -0.94 --0-1004 -Good ETHYLENE 191C TE6.85 17.49 10.07 5.17 6.38 21.58 21.58 10.56 12.27 0.49 3.36 0-900 -Close to DL CO PPM 191C (1OF2)0.76 1.06 0.87 0.47 1.01 2.29 2.29 1.03 1.03 0.16 0.29 0-5010 1.05 Close to DL CO2% 191C 6.4 0.13 -0.03 0.04 0.18 0.18 -0.13 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.99 2.17 1.75 1.67 2.15 2.79 2.79 1.89 1.89 0.15 0.58 0-186 1.04 Close to DL ACETYLENE 191C0.74 3.8 1.09 1.83 2.42 5.02 5.02 1.16 2.02 0.07 0.36 0-1016 -Close to DL SO2 191C 2.43 2.39 1.58 1.02 1.24 2.91 2.91 2.09 2.09 0.51 0.53 0-964 -Close to DL HEXANE 191C 0.09 0.69 0.33 0.32 0.43 0.94 0.94 0.33 0.38 0 0.11 0-1000 -Close to DL APPENDIX C LOW NOX UPGRADE CONTINUOUS HPG IMPCO WITH AIR FUEL RATIO CONTROL Field Gas 40.0-45.0 62.1 1027 5816 72 1340 bhp@1400rpm RATING STRATEGY: RATING LEVEL: FUEL SYSTEM: SITE CONDITIONS: FUEL: FUEL PRESSURE RANGE(psig): (See note 1) FUEL METHANE NUMBER: FUEL LHV (Btu/scf): ALTITUDE(ft): INLET AIR TEMPERATURE(°F): STANDARD RATED POWER: ENGINE SPEED (rpm):1380 COMPRESSION RATIO:8 AFTERCOOLER TYPE:SCAC AFTERCOOLER - STAGE 2 INLET (°F):130 AFTERCOOLER - STAGE 1 INLET (°F):201 JACKET WATER OUTLET (°F):210 ASPIRATION:TA COOLING SYSTEM:JW+OC+1AC, 2AC CONTROL SYSTEM:ADEM3 EXHAUST MANIFOLD:ASWC COMBUSTION:LOW EMISSION NOx EMISSION LEVEL (g/bhp-hr NOx):1.0 SET POINT TIMING:27 RATING NOTES LOAD 100%100%75%51% ENGINE POWER (WITHOUT FAN)(2)bhp 1321 1321 990 670 INLET AIR TEMPERATURE °F 72 72 72 72 MAXIMUM RATING SITE RATING AT MAXIMUM INLET AIR TEMPERATURE ENGINE DATA FUEL CONSUMPTION (LHV)(3)Btu/bhp-hr 8157 8157 8528 9110 FUEL CONSUMPTION (HHV)(3)Btu/bhp-hr 9014 9014 9423 10066 AIR FLOW (@inlet air temp, 14.7 psia)(WET)(4)(5)ft3/min 3011 3011 2316 1704 AIR FLOW (WET)(4)(5)lb/hr 13478 13478 10365 7626 FUEL FLOW (60°F, 14.7 psia)scfm 175 175 137 99 INLET MANIFOLD PRESSURE (6)psi(abs)34.2 34.2 28.2 21.2 EXHAUST TEMPERATURE - ENGINE OUTLET (7)°F 993 993 1000 1002 EXHAUST GAS FLOW (@engine outlet temp, 14.5 psia)(WET)(5)(8)ft3/min 8880 8880 6873 5059 EXHAUST GAS MASS FLOW (WET)(5)(8)lb/hr 13997 13997 10771 7920 EMISSIONS DATA - ENGINE OUT NOx (as NO2)(9)(10)g/bhp-hr 1.00 1.00 1.00 1.00 CO (9)(10)g/bhp-hr 3.61 3.61 3.87 4.27 THC (mol. wt. of 15.84)(9)(10)g/bhp-hr 3.02 3.02 3.46 3.68 NMHC (mol. wt. of 15.84)(9)(10)g/bhp-hr 0.78 0.78 0.90 0.95 NMNEHC (VOCs) (mol. wt. of 15.84)(9)(10)(11)g/bhp-hr 0.53 0.53 0.60 0.64 HCHO (Formaldehyde)(9)(10)g/bhp-hr 0.41 0.41 0.27 0.35 CO2 (9)(10)g/bhp-hr 545 545 588 654 EXHAUST OXYGEN (9)(12)% DRY 8.0 8.0 7.8 7.6 HEAT REJECTION HEAT REJ. TO JACKET WATER (JW)(13)Btu/min 41256 41256 35394 27697 HEAT REJ. TO ATMOSPHERE (13)Btu/min 5237 5237 4365 3517 HEAT REJ. TO LUBE OIL (OC)(13)Btu/min 6153 6153 5279 4131 HEAT REJ. TO A/C - STAGE 1 (1AC)(13)(14)Btu/min 10073 10073 5682 2259 HEAT REJ. TO A/C - STAGE 2 (2AC)(13)(14)Btu/min 4137 4137 3400 2450 COOLING SYSTEM SIZING CRITERIA TOTAL JACKET WATER CIRCUIT (JW+OC+1AC)(14)(15)Btu/min 63342 TOTAL AFTERCOOLER CIRCUIT (2AC)(14)(15)Btu/min 4344 A cooling system safety factor of 0% has been added to the cooling system sizing criteria. CONDITIONS AND DEFINITIONS Engine rating obtained and presented in accordance with ISO 3046/1, adjusted for fuel, site altitude and site inlet air temperature. 100% rating at maximum inlet air temperature is the maximum engine capability for the specified fuel at site altitude and maximum site inlet air temperature. Maximum rating is the maximum capability at the specified aftercooler inlet temperature for the specified fuel at site altitude and reduced inlet air temperature. Refer to product O&M manual for details on additional lower load capability. No overload permitted at rating shown. For notes information consult page three. GAS COMPRESSION APPLICATION Page 1 of 4Data generated by GERP Web Version 2.11.0.24 Ref. Dta Set DM9401-06-001, Printed 03Sep2024 GAS ENGINE SITE SPECIFIC TECHNICAL DATAG3516Ovintiv - Pleasant Valley CS #2 APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 1559.18 892.6 7.9 162.83 0.92 1.82 0.92 0.00 0.01 19.45 0.11 0.21 12.71 2 1579.50 892.6 8.1 152.03 0.87 1.72 0.83 0.00 0.01 20.20 0.11 0.22 11.58 3 1590.18 892.6 8.0 153.58 0.89 1.75 0.78 0.00 0.01 20.23 0.11 0.22 11.27 892.6 8.0 156.15 0.90 1.76 0.84 0.00 0.01 19.96 0.11 0.22 11.85 Summary Average Levels Example Calculations: Ovintiv USA Incorporated, Pleasant Valley Compressor Station, #2 The following is a step-by-step calculation for the first test run conducted on the Pleasant Valley Compressor Station #2. Test Parameters  Stack Diameter = 11.5 inches  Traverse Points = 16  Ports = 2  Barometric Pressure = 25.01 in Hg  Average O2 = 7.9%  Average CO2 = 7.2%  Load Approximation = 892.6 bhp  Moisture Content = 12.71% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 7.2% %O2 – Oxygen Content Of The Gas = 7.9% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 7.9 – 7.2) = 84.9% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 7.2) + (0.32 * 7.9) + (0.28 * 84.9) = 29.47 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.47 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 12.71% = MD * (1-BWS) + (18) * BWS = 29.47 * (1 – (12.71/ 100)) + (18 * (12.71/ 100)) = 28.01 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 1.230 in H2O TS – Average stack temperature (R) = 1276 R PB – Barometric pressure (in Hg) = 25.01 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.4 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 28.01 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 1.230 * ( 1276 / (((0.4/ 13.6) + 25.01) * 28.01)) = 119.19 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 11.5 inches BWS – Moisture content of the gas (%) = 12.71% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1276 R PB – Barometric pressure (in Hg) = 25.01 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.4 in H2O VS– Average Stack gas velocity (ft/sec) = 119.19 ft/sec = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (12.71/ 100)) * 119.19 *  * (((11.5 / 2) / 12))2) * 528 / 1276 * (25.01 + (0.4 / 13.6)) / 29.92 = 1559.18 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 1559.18 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 1559.18 *60 * 2.83168*10 -2 = 2649.06 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 162.83 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 2649.06 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 892.6 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (162.83 * 1.912*10 -3 * 2649.06 * 1) / 892.6 = 0.92 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.92 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 892.6 Bhp = g/Bhp-hr / 454 * Bhp = 0.92 / 454 * 892.6 = 1.82 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 0.92 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 2649.06 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 892.6 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (0.92 * 1.164*10 -3 * 2649.06 * 1) / 892.6 = 0.00 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.00 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 892.6 Bhp = g/Bhp-hr / 454 * Bhp = 0.00 / 454 * 892.6 = 0.01 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 19.45 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 2649.06 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 892.6 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (19.45 * 1.833*10 -3 * 2649.06 * 1) / 892.6 = 0.11 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.11 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 892.6 Bhp = g/Bhp-hr / 454 * Bhp = 0.11 / 454 * 892.6 = 0.21 lbs/hr APPENDIX E FTIR Engine Test Sheet Company Name 01/1'"N'i/ Location / Unit 1.0. H&47 1>c,I,,} fA'; Ii'{;v c..S -I:f2­ 3x/h / jC/?V TJ Schmidtberoer DrrC.", We-bi:> -Oh \-..1"./ 8'-7..7-LLf Type of Test Completed Field Technician (5) Client Rep and/or State Rep Date Non-Resettable Run Time Hours .5"lS.31 J Engine Make Cc.-I Engine Model ~ "3S" /6 -rA 1-E Engine SIN Verified:~ LVrt1/o/'1' J2. Port Distance A /,;1;0 \~ -+ Port Distance B sh" Exhaust Diameter (inches) /I.g- Calibration Gas Cylinder # Concentration NO (ppm) CC453965 CO (ppm) CC453965 Propane (ppm) CC453965 N02 (ppm) CC168787 Ethylene (ppm) CC188939 Methane (ppm) Acetaldehyde (ppm) 01/24/2025 Stack Diagram <~""'~W""-'''' ,,'" ~"_'''."..-..,,>~..,.,­ C"""""'" :"""':"''!' T t A ;'.\:' (; 493.4­ 520.2 495.6 143 ,'"' T B .~100.1 ,T je-FW""'JCC453965 499.4 1CC321163 196.7 '-. : Test 1 Test 2 Test 3 Time of Reading V'/ .' <jg"A /It.-. / () : 'i '7A",1 /1;5"'0/1111 Atm Pressure (in Hg) zc, D 1 Z<t.9'1 Z'-/· 9/5 Atm Temp ('F) 65< ':'.2. ::;S Engine RPM -/~c;('c /3 =tc; rs e:", "'\ *Manifold Pres. Vae{") or BQost(psi}..6r Boost (psla) 26.0 zs.r z» , / Manifold Temp ('F) -­/2.2­IZ:!{;.-b /2v: 2 Psuction (psi) Staoe 1 2-1 Z/ 7/ Tsuction CF) Stage 1 5¥ !!:7 1-'1 Pdischarc e (psi) Stage 1 yc::;­<Zb X ,D Psuction (psi) Stage 2 """"" ~ \'" Tsuction 'F) Stage 2 /' /"'... ~ Pdischarge (psi) Stage 2 u7 Z,':f ( 272­ Psuction (psi) Stage 3 '\../ \,,.... V Tsuction 'F) Stage 3 /"­/, /' Pdischarc e (psi) Stage 3 2"1-/' ~n 'Klo Psuction (psi) Staoe 4 J Tsuction 'F) Stage 4 Pdischarqe (psi) Stage 4 Gas Throughput (mmefld) or ( ) Pre Cat Temp CF) 4/t:; If CJ!-6 Post Cat Temp CF) ~-b d5/-=t Y/6 Cat Differential Pres. (" of H2O) Humiditv% -~I-J ,.5'1 "SL 02% "7-,'1 "X , I &;:D C02 % Dry 7."2.. ~ ,7 ..(. Z. LOAD % (Panel) or (Estimated) Ce.//~e/ ...:z~ a:"t 6:6.'1 6-b,Lj Ignition Timing ('F) Z'tt .4. 2'1·6 z~,6 AFR Setting mV (Left Bank) zs, Nox /v o /"10 /1'0 AFR Setting mV (Right Bank) '­- Rev 8 • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-}. Eg: (+12") or (- 5") \ 9117/2019 Worksheet: O2 Stratification Client:Ovintiv Location:Pleasant Valley CS #2 Date:8/27/2024 PD:11.5 DD:36 YES Method 1 Criteria Met UD:120 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.91 7.90 A 2 5.75 7.90 A 3 9.58 7.90 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 7.90 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) COMPANY NAME:Ovintiv COMPANY LOCATION:Pleasant Valley CS #2 DATE:27-Aug STACK DIAMETER (inches):11.5 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:7.9 AVERAGE O2:8.1 AVERAGE O2:8 AVERAGE CO2:7.2 AVERAGE CO2:7.2 AVERAGE CO2:7.2 BARO PRESSURE:25.01 BARO PRESSURE:24.99 BARO PRESSURE:24.98 Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O) 1 0.5 1.58 816 0.4 1 0.5 1.59 817 0.42 1 0.5 1.62 815 0.41 2 1.2075 1.54 2 1.2075 1.58 2 1.2075 1.55 3 2.231 1.56 3 2.231 1.51 3 2.231 1.59 4 3.7145 1.52 4 3.7145 1.55 4 3.7145 1.51 5 7.7855 1.48 5 7.7855 1.49 5 7.7855 1.52 6 9.269 1.44 6 9.269 1.58 6 9.269 1.55 7 10.2925 1.48 7 10.2925 1.46 7 10.2925 1.59 8 11 1.5 8 11 1.55 8 11 1.58 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 1.57 816 0.4 1 0.5 1.55 817 0.41 1 0.5 1.58 815 0.41 2 1.2075 1.56 2 1.2075 1.59 2 1.2075 1.57 3 2.231 1.49 3 2.231 1.52 3 2.231 1.51 4 3.7145 1.52 4 3.7145 1.56 4 3.7145 1.48 5 7.7855 1.55 5 7.7855 1.44 5 7.7855 1.49 6 9.269 1.45 6 9.269 1.48 6 9.269 1.44 7 10.2925 1.48 7 10.2925 1.45 7 10.2925 1.46 8 11 1.51 8 11 1.49 8 11 1.51 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 Performance Test Report Test Type: Annual Test Date: 8/7/2024 Caterpillar G3516 TALE Lean Burn (4 Cycle) DOM: 5/18/19 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:09:25 AM 03:05 PM Source: Unit Number: 3 Serial Number: WPW02348 Engine Hours:38370.2 Permit #: #DAQE-AN142100007-23 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Pleasant Valley Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 0.360 2.950 0.980 0.000 1.861 0.484 0.000 102.632 27.842 2.000 1.000 0.700 0.000 0.877 0.228 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Ovintiv USA Inc. 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 klye muir 3 Logan Miller Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit 3 with a serial number of WPW02348 which is a Caterpillar G3516 TALE engine located at Pleasant Valley Compressor Station and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/7/2024 by Logan Miller with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1340 brake horse power (BHP) at 1400 RPM. The engine was operating at 962 BHP and 1374 RPM which is 71.81% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit 3 is authorized to operate under permit #DAQE-AN142100007-23. 4 4.0 Test Summary Engine/Compressor Specs Pleasant Valley Compressor StationLocation 3Unit ID Make Caterpillar Site Elevation ft.5379 Model G3516 TALE Atmospheric Pressure psi.12.18 Serial Number WPW02348 Stack Diameter in.14 mfg. rated hp 1340 Yes 1400 Date of Manufacture 5/18/2019 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 960 964 962 962 1371 1376 1374 1374 Percent Load % Intake Manifold Pressure (hg) 71.67%71.93%71.82%71.81% 31.60 31.60 31.60 31.60 Intake Manifold Temperature (F)140.00 140.00 149.20 143.07 Ambient Conditions Ambient Temperature Dry (F)78.00 91.00 95.00 88.00 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 151970.45 152211.01 151513.05 151898.17 4303.28 4310.10 4290.33 4301.24 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.12 0.12 0.12 0.12 9476.16 9471.91 9473.61 9473.8933333333 333333Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %12.17%12.17%11.74%12.03% T e s t S u m m a r y mfg. rated rpm Test RPM 8.45%8.38%8.57%8.46% Permitted Standards Results 5 Catalyst 0.0000.000 Run 1 Run 2 Run 3 3 Run Average Pass Permits 09:25 AM 10:40 AM 11:58 AM 8/7/2024 CO (g/hp-hr)0.000 0.0002.000 Pass StateFederal CO (ppmvw)0.000 0.000 0.000 0.000 CO (ppmvd)0.000 0.000 0.000 0.000 CO (mol wt) 28.01 CO (ppmvd) @15% O2 0.000 0.000 0.000 0.000 Fail CO (ppbvd) @15% O2 0.000 0.000 0.000 0.000 Fail 0.0000.000CO (lbs/hr)0.000 0.0000.360 Pass NOx (g/hp-hr)0.864 0.924 0.844 0.8771.000 Pass NOx (ppmvw)88.554 94.895 87.402 90.283 NOx (ppmvd)100.825 108.040 99.031 102.632 NOx (mol wt) 46.01 23.432 19.988 30.088 24.503NMNEHC (ppmvw) 26.679 22.757 34.091 27.842NMNEHC (ppmvd) NOx (ppbvd) @15% O2 47780.779 50895.328 47375.459 48683.855 Fail NOx (ppmvd) @15% O2 47.781 50.895 47.375 48.684 Fail NMNEHC (mol wt) 44.10 12642.926 10720.282 16308.927 13224.045 FailNMNEHC (ppbvd) @15% O2 0.219 0.187 0.279 0.2280.700 PassNMNEHC (g/hp-hr) 0.464 0.396 0.591 0.4840.980 PassNMNEHC (lbs/hr) 12.643 10.720 16.309 13.224 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)1.829 1.963 1.791 1.8612.950 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.35Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 0.00 0.29 82.95 0.02 5.60 0.30 88.55 0.53 23.43 0.00% 7.24% 0.00% 12.17% NMNEHC 0.00 82.93 4.47 87.39 23.92 7.23%12.20% 48.75 94.31 12.22 106.53 40.09 6.56%11.18% 0.00 82.98 6.73 89.71 22.94 7.25%12.15% 0.05 0.00 0.00 0.00 0.45 0.00%0.03% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.05 0.00 0.00 0.00 0.45 0.00%0.03% 0.00 83.10 9.16 92.26 21.69 7.14%12.17% 45.40 92.68 12.23 104.91 39.95 6.62%11.17% 0.00 81.30 16.23 97.53 18.29 7.21%12.17% 0.04 0.00 0.00 0.00 0.33 0.00%0.02% Avg. Wet 0.00 82.20 12.70 94.89 19.99 7.17%12.17% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 74.40 14.68 89.08 19.30 7.11%12.13% 45.62 86.47 10.51 96.98 41.27 6.63%11.03% 0.00 72.10 13.62 85.72 40.87 7.63%11.36% 0.12 0.04 0.55 0.58 0.21 0.00%0.02% 0.04 0.00 0.00 0.00 0.33 0.00%0.02% Avg. Wet 0.00 73.25 14.15 87.40 30.09 7.37%11.74% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 14 inches or:1.17 feet. or:1.07 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 1.03 Yes 14.00 230.00 56.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 12.17 29.24 1.18 Inches 2.34 7 11.66 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.93 7.24 0.00 838.62 0.09 24.77 24.86 704.06 1163.73 373.37 27.87 119.28 127.52 173030.91 151970.45 Run 2 12.17 29.24 1.19 5.93 7.18 0.00 837.88 0.09 24.75 24.84 706.94 1166.61 374.97 27.87 119.86 128.14 173296.91 152211.01 Run 3 11.74 29.22 1.18 5.79 7.38 0.00 836.45 0.09 24.71 24.79 714.38 1174.05 379.10 27.90 119.71 127.97 171672.55 151513.04 12.03 29.23 1.18 5.89 7.26 0.00 837.65 0.09 24.74 24.83 708.46 1168.13 375.81 27.88 119.62 127.87 172665.39 151898.34 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 1.47 Exhaust Temp F 700.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 1.10 1.21 1.02 710.00 709.00 703.00 0.96 1.05 1.02 700.00 707.00 709.00 1.09 1.06 1.14 699.00 703.00 708.00 1.13 710.00 1.35 1.26 1.35 698.00 700.00 707.00 1.47 1.24 1.18 702.00 700.00 704.06 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 1.19 Exhaust Temp F 712.00 1.09 1.11 1.34 722.00 712.00 713.00 1.43 1.18 1.21 718.00 716.00 718.00 1.11 1.23 1.09 719.00 712.00 716.00 1.21 714.00 1.09 1.11 1.23 710.00 709.00 713.00 1.21 1.03 714.00 712.00 714.381.18 Run 2 Δpstd (in) H2O 1.18 Exhaust Temp F 704.00 1.11 1.05 1.31 700.00 714.00 712.00 1.13 1.18 1.18 710.00 703.00 703.00 1.21 1.34 1.45 707.00 704.00 709.00 1.41 712.00 1.05 1.09 1.04 714.00 703.00 707.00 1.13 1.18 708.00 701.00 1.19 706.94 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.059)+.32(.085)+.28(.856+0) = 29.239 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.239(1 -.12172)+.18.0(.12172) = 27.871 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√1.18*√(1163.7325/(24.86*27.871)) = 119.28 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.122)119.284*1.069((528*24.86)/ (1163.7325*29.92)) = 151970.45 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 151970.448/35.315 = 4303.283 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 0*(20.9-15)/(20.9-8.5%)) = 0 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (0*(1.164*10^-3)*4303.283*(Run Time/60))/960.313 = 0 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = 0*1/453.6*960.313 = 0 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = 0*4.38 = 0 TPYTPY = LB/HR. *4.38 Horsepower 960= 1312.24 - ((69.7-56) / ((69.7-57.3) / 25%))) * 1312.24)BHP/HR = Available HP - ((MFP @100% - Actual MFP inHG) / ((MFP @100% - MFP @75%) / 25%))) * Available HP Wet to Dry PPM 0 = 0*(1/(1-.12))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.58% 21.10% 10.42% 10.28% 10.61% 10.61% 10.28%10.42% 10.58% 21.10% 10.61% 21.01% 10.61% 21.01% 10.61%21.01% 0.00% 10.61% 21.01% 0.03% 0.09% 0.14% 0.44% 10.61% Span Zero Offset 0.00% 21.01 0.00% 10.58%0.75%1.44%0.01% 8.24% 8.17% 8.36% 8.45% 8.38% 8.57% 9 Gas, Inc. 900.0 828.0 884.0 19.0 18.0 19.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Pleasant Valley Compressor Station 8/7/2024 5379 3 Caterpillar Model Serial Number G3516 TALE WPW02348 Technician Logan Miller Run Start Times 09:25 AM 10:40 AM 11:58 AM 03:05 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1371.0 1376.0 1374.0 1373.7 Engine Hours 38367.2 38368.2 38369.2 38370.2 Intake Manifold Pressure (psi)27.7 27.7 27.7 27.7 Intake Manifold Temp °F 140.0 140.0 149.2 143.1 Engine Load (BHP)960.3 963.8 962.4 962.2 Ambient Temp °F 78.0 91.0 95.0 88.0 Humidity %37.0 23.0 20.0 26.7 Dew Point °F 49.0 48.0 47.0 48.0 Caterpillar YesCatalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 20.0 924.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.05 R e s u l t s Average:Nitrogen monoxide NO 0.14 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.14 Average:VOC 0.03 Average:Oxygen 0.00 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 101.29 Tolerance 2.00% Difference between measured and expected 1.66% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.10 Average:Nitrogen monoxide NO 0.10 Average:Nitrogen dioxide NO2 0.19 Average:NOx 0.29 Average:VOC 0.34 Average:Oxygen 0.00 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 101.31 Tolerance 5.00% Difference between measured and expected 1.65% Pre-test System CTS & Mechanical Response Time 51 secondsEquilibration Response Time Value:Spike Reported 250.46 Value:Spike Expected 254.10 System (Equilibration) Response Time Target (Spike) 73 secondsSystem Zero Response Time 73 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC517327 4/29/2027 99.84 10.61% CC190334 4/24/2032 103.00 ALM-062642 12/14/2031 21.01% Cylinder # CC403040& Expiration: 7-13-2031 Propane CO NO SF6 Bottle Value 254.10 507.00 253.30 10.10 Analyzer System Response 250.46 501.26 248.24 10.07 Percent Difference 1.43%1.13%2.00%0.29% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 101.287 4.917 Spike Direct Propane 252.748 Mechanical Response Time SF6 10.139 CO 504.924 NO 251.283 Ethylene 101.305 40 seconds Analyzer Response Propane 250.461 SF6 10.071 CO 501.256 NO 248.244 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 248.234 CO 494.918 NO 246.866 51 seconds 73 seconds 9.09% 8.54% 8.50% 93.77% 97.53% 100.52% 9.963 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.338 50%7.000 83.3%11.662 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 14 230 56 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 151898.34 H2O%d @ Sampling Point:12.03 CO2%d @ Sampling Point:5.89 Pressure @ Sampling Point (Pg "H2O):1.18 Temperature @ Sampling Point (Deg F):708.46 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 103 101.29 4.917 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 101.287 4.917 Spike Direct Propane 252.748 Mechanical Response Time SF6 10.139 CO 504.924 NO 251.283 Ethylene 101.305 40 seconds Analyzer Response Propane 250.461 SF6 10.071 CO 501.256 NO 248.244 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 248.234 CO 494.918 NO 246.866 51 seconds 73 seconds 9.09% 8.54% 8.50% 93.77% 97.53% 100.52% 9.963 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 254.100 10.100 507.000 253.300 252.748 10.139 504.924 251.283 0.53% 0.39% 0.41% 0.80% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 14.253 0.000 Spike Average 33.810 0.922 Dilution Factor 9.094% Expected 36.055 % Recovery 93.770% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.866 Dilution Factor 8.541% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.862 Dilution Factor 8.502% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 14.144 34.718 34.540 100.520% 0.000323 0.000248 0.000191 13.722 33.405 34.250 97.530% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass0.34% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:42.1627746 Pass Line Position Difference:Resolution Difference to Reference 0.34% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 103.00 106.57 3.35% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Pleasant Valley Compressor Station; 3; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/7/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/7/2024 Logan Miller Gas, Inc. Appendices Gas, Inc. Gas, Inc. CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number:E05NI94E15AC014 Reference Number:54-402783135-1 Cylinder Number:CC403040&Cylinder Volume:147.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:CO,CO2,NO,NOX,PPN,BALN Certification Date:Jul 13, 2023 Expiration Date:Jul 13, 2031 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates NOX 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 NITRIC OXIDE 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 PROPANE 250.0 PPM 254.1 PPM G1 +/- 0.9% NIST Traceable 07/11/2023 CARBON MONOXIDE 500.0 PPM 507.0 PPM G1 +/- 0.6% NIST Traceable 07/11/2023 CARBON DIOXIDE 5.000 %5.083 %G1 +/- 0.7% NIST Traceable 07/11/2023 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 200603-02 EB0112877 250.3 PPM NITRIC OXIDE/NITROGEN +/- 0.8%Oct 19, 2026 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR +/- 1.5%Feb 18, 2023 GMIS 1534012021105 ND73033 5.012 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.6%Jun 15, 2025 NTRM 200602-13 6162697Y 243.3 PPM PROPANE/AIR +/- 0.5%Mar 17, 2027 NTRM 150605-41 CC453947 491.9 PPM CARBON MONOXIDE/NITROGEN +/- 0.6%Mar 05, 2027 NTRM 13060423 CC413685 7.489 % CARBON DIOXIDE/NITROGEN +/- 0.6%May 14, 2025 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2010242 FTIR Jun 08, 2023 CO-1 SIEMENS ULTRAMAT 6E N1J5700 NDIR Jun 26, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2110277 FTIR Jul 07, 2023 Triad Data Available Upon Request PERMANENT NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc.      ,          '5781(+5 !+,+5+2)+81(+5    ;0/2*+52'0;<+*#%  ;0/2*+5$3081+   '(35'735;"#806''67/00" ;0/2*+5 5+6685+   " 2'0;6/6'7++(  $'09+870+7 3781(+5          Component Requested Certified Purity Concentration NITROGEN 99.999 %99.999 % OXYGEN <1 PPM 0.94 PPM WATER <1 PPM 0.058 PPM TOTAL HYDROCARBONS <0.1 PPM 0.1 PPM CARBON DIOXIDE <0.5 PPM 0.235 PPM CARBON MONOXIDE <0.5 PPM 0.235 PPM !##" #./6)+57/2)08*+69'08+6,5317.+,/006/*+'2*/62375+45+6+27'7/9+3,7.+86+6/*+485/7;327')7'2/5-'6 "'0+6!+45+6+27'7/9+,357./6/2,351'7/32 &!"#   &#%  #%   #% #%  #%  #% #%  #%    #%  #%   #%   #%  #%  #%  #%  #%  #%   #%   #%   1485/7/+69+5/,/+*'-'/267'2'0;7/)'067'2*'5*675')+'(0+73"#(;:+/-.7'2*35'2'0;6/6 #$! !%!"    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The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Logan Miller GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Pleasant Valley Compressor Station Unit Number:3 Make:Caterpillar Location:G3516 TALEModel: WPW02348Serial Number: RAW Result Data Stability 8/7/2024 06:31 0.0000.4950.007 0.000 0.4170.025 0.000 0.000 0.5280.0280.119 0.000 0.0000.000 0.000 848.00.660.997 0.000 0.49 0.00 180.0 Pre Test Baseline Direct 8/7/2024 06:45 0.0000.0000.001 0.003 0.1270.044 0.007 0.000 0.0600.0010.104 0.000 0.0020.129 0.000 845.00.000.000 0.000 0.00 0.00 180.0 8/7/2024 06:45 0.0000.291-0.001 0.000 0.0000.076 0.021 0.084 0.0270.1390.070 0.000 0.0250.088 0.024 845.00.070.000 0.000 0.29 0.00 180.0 8/7/2024 06:46 0.0000.134-0.001 0.000 0.4610.042 0.006 0.039 0.0490.0410.143 0.000 0.0150.000 0.007 845.00.030.000 0.002 0.13 0.00 180.0 CTS Direct 8/7/2024 07:51 0.0000.9280.015 0.014 0.0000.188 0.032 0.000 0.0570.0000.000 101.334 0.0000.119 0.071 839.067.700.000 0.000 0.93 0.00 180.0 8/7/2024 07:52 0.2660.7110.011 0.010 0.0000.179 0.015 0.000 0.1940.0000.000 101.296 0.1300.000 0.050 839.067.760.000 0.000 0.98 0.00 180.0 8/7/2024 07:52 0.9130.4160.011 0.008 0.0000.134 0.020 0.000 0.2370.1220.000 101.230 0.0000.000 0.022 839.067.530.000 0.000 1.33 0.00 180.0 High O2 Direct 8/7/2024 08:00 0.0000.0000.002 0.001 0.1040.161 0.004 0.031 0.0400.0280.000 0.000 0.0010.000 0.017 839.00.040.000 0.000 0.00 21.29 180.0 8/7/2024 08:01 0.4680.000-0.002 0.001 0.0260.178 0.021 0.004 0.0080.0000.000 0.000 0.0000.000 0.000 839.00.000.000 0.000 0.47 20.97 180.0 8/7/2024 08:01 0.2250.000-0.007 0.002 0.3830.000 0.002 0.072 0.1410.1640.000 0.000 0.0000.027 0.025 839.00.050.000 0.000 0.22 21.05 180.0 NO2/Mid O2 Direct 8/7/2024 08:09 99.7210.000-0.006 0.000 2.0720.000 0.772 0.000 2.0380.0600.194 0.000 0.0000.000 0.000 839.00.000.000 0.000 99.72 10.63 180.0 8/7/2024 08:09 100.2800.113-0.005 0.000 2.4140.000 0.774 0.000 1.3310.0000.346 0.000 0.0000.003 0.000 839.00.000.000 0.000 100.39 10.53 180.0 8/7/2024 08:10 101.3860.000-0.009 0.000 2.1120.000 0.775 0.000 1.5900.0000.635 0.000 0.0000.000 0.000 839.00.040.062 0.000 101.39 10.58 180.0 Spike Direct 8/7/2024 08:14 0.000251.1820.002 4.842 2.861504.597 1.162 2.116 9.5050.1250.018 1.080 252.8200.000 0.000 839.0255.663.187 10.136 251.18 0.00 180.0 8/7/2024 08:15 0.000251.166-0.004 4.843 2.748505.307 1.167 2.107 9.8200.0390.000 1.051 252.6940.148 0.000 839.0255.603.310 10.143 251.17 0.00 180.0 8/7/2024 08:16 0.000251.501-0.000 4.836 1.793504.869 1.179 1.936 9.5070.3910.435 1.070 252.7290.096 0.000 839.0255.513.105 10.138 251.50 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/7/2024 08:19 0.4500.0990.016 0.006 0.1070.134 0.000 1.647 0.3250.0000.000 0.014 0.1430.000 0.000 839.00.570.622 0.000 0.55 0.00 180.0 8/7/2024 08:19 0.1150.2120.013 0.007 0.5580.108 0.000 1.457 0.4530.0000.000 0.105 0.0000.000 0.001 839.00.270.300 0.002 0.33 0.00 180.0 8/7/2024 08:19 0.0000.0000.007 0.003 0.1670.071 0.000 1.389 0.2660.0050.000 0.000 0.0860.117 0.000 839.00.190.163 0.000 0.00 0.00 180.0 CTS System with Response Time 8/7/2024 08:21 0.2050.0000.027 0.010 0.0000.156 0.000 1.219 0.5270.0000.000 101.341 0.0570.243 0.044 839.068.020.459 0.000 0.21 0.00 180.0 8/7/2024 08:21 0.2040.0000.030 0.014 0.0000.232 0.000 1.169 0.0660.0000.000 101.399 0.0030.000 0.062 839.067.990.397 0.000 0.20 0.00 180.0 8/7/2024 08:22 0.1530.0000.026 0.011 0.0000.165 0.000 1.157 0.0640.0000.000 101.175 0.0000.188 0.067 839.067.810.336 0.000 0.15 0.00 180.0 NO2/Mid O2 System with Response Time 8/7/2024 08:26 102.2950.9640.009 0.001 1.8130.156 0.800 0.469 0.7970.0030.000 0.000 0.0000.544 0.018 839.00.761.091 0.000 103.26 10.41 180.0 8/7/2024 08:26 101.1120.7050.007 0.000 2.4950.147 0.811 0.496 0.9160.0000.000 0.000 0.0000.465 0.000 839.00.520.786 0.000 101.82 10.41 180.0 8/7/2024 08:26 101.8881.077-0.000 0.000 2.1080.000 0.784 0.568 0.7340.0000.000 0.000 0.0000.584 0.000 839.00.340.507 0.000 102.96 10.45 180.0 Spike System with Response Time 8/7/2024 08:28 0.000248.0070.010 4.782 2.961500.962 1.175 2.606 11.0610.0590.786 1.243 249.6760.000 0.000 839.0252.432.894 10.061 248.01 0.00 180.0 8/7/2024 08:28 0.000248.3810.014 4.810 3.217501.313 1.176 2.721 11.2300.0200.467 1.197 250.1090.000 0.000 839.0253.013.148 10.073 248.38 0.00 180.0 8/7/2024 08:29 0.000248.3450.005 4.826 2.220501.492 1.148 2.637 9.5470.0340.857 1.216 251.5980.085 0.000 839.0254.683.409 10.078 248.34 0.00 180.0 Baseline System with Response Time 8/7/2024 08:31 0.0000.4190.001 0.010 0.2300.293 0.000 0.655 0.2010.0050.000 0.066 0.3300.236 0.000 839.00.620.376 0.008 0.42 0.00 180.0 8/7/2024 08:32 0.0540.4400.009 0.013 0.7000.418 0.000 0.645 0.2810.0000.000 0.000 0.1980.085 0.000 839.00.540.511 0.004 0.49 0.00 180.0 8/7/2024 08:32 0.0000.0000.005 0.003 0.2000.340 0.000 0.746 0.2060.0000.000 0.000 0.1650.430 0.000 839.00.430.397 0.005 0.00 0.00 180.0 Run 1 - A 30minute/60min 8/7/2024 09:26 5.41083.93412.183 5.940 833.7670.000 0.000 0.051 33.6350.00011.555 1.372 14.0750.000 2.762 839.023.674.732 0.000 89.34 7.22 180.0 8/7/2024 09:27 4.38882.62312.211 5.938 835.9210.000 0.000 0.056 34.4530.00011.427 1.449 14.0280.005 2.707 839.023.714.954 0.000 87.01 7.19 180.0 8/7/2024 09:28 4.87282.68312.215 5.943 832.3710.000 0.000 0.000 34.0280.00011.124 1.347 13.8960.114 2.819 839.023.694.879 0.000 87.56 7.18 180.0 8/7/2024 09:29 4.11182.81112.223 5.934 836.5380.000 0.000 0.121 34.3340.00011.527 1.554 14.1220.000 2.683 839.023.865.004 0.000 86.92 7.21 180.0 8/7/2024 09:30 5.12683.97712.207 5.944 835.8880.000 0.000 0.000 34.3650.00011.581 1.402 14.1370.000 2.757 839.023.804.823 0.000 89.10 7.24 180.0 8/7/2024 09:31 5.27483.84512.143 5.943 835.0970.000 0.000 0.007 33.8450.00011.700 1.257 14.2020.030 2.732 839.023.724.831 0.000 89.12 7.22 180.0 8/7/2024 09:32 4.81283.79712.104 5.930 835.6090.000 0.000 0.039 34.3060.00011.592 1.435 14.2350.000 2.752 839.023.934.850 0.000 88.61 7.23 180.0 8/7/2024 09:33 4.63282.79112.074 5.921 839.5290.000 0.000 0.029 34.5420.00011.593 1.478 14.2420.000 2.752 839.023.974.852 0.000 87.42 7.26 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 09:34 4.07681.70212.080 5.929 833.8360.000 0.000 0.000 34.4970.00011.151 1.323 14.2150.000 2.720 839.023.844.956 0.000 85.78 7.27 180.0 8/7/2024 09:35 4.79783.31012.085 5.920 838.8910.000 0.000 0.004 34.2270.00011.633 1.418 14.2080.000 2.782 839.023.934.814 0.000 88.11 7.27 180.0 8/7/2024 09:36 4.02281.01612.099 5.909 846.4390.000 0.000 0.000 36.0380.00011.247 1.502 14.5940.000 2.719 839.024.264.838 0.000 85.04 7.26 180.0 8/7/2024 09:37 4.26980.47412.159 5.920 844.2850.000 0.000 0.000 35.5700.00011.129 1.563 14.4100.000 2.743 839.024.184.856 0.000 84.74 7.26 180.0 8/7/2024 09:38 4.14082.50012.170 5.918 837.8890.000 0.000 0.023 34.3160.00011.801 1.444 14.2570.000 2.718 839.023.864.802 0.000 86.64 7.24 180.0 8/7/2024 09:39 4.19183.40712.200 5.932 833.9620.000 0.000 0.000 34.1200.00011.219 1.436 14.2950.000 2.760 839.023.974.793 0.000 87.60 7.23 180.0 8/7/2024 09:40 4.70782.90612.197 5.938 835.8990.000 0.000 0.002 34.6470.00011.543 1.452 14.3090.000 2.770 839.023.974.730 0.000 87.61 7.23 180.0 8/7/2024 09:41 5.02084.53812.189 5.928 838.3290.000 0.000 0.000 34.3160.00011.063 1.406 14.2310.000 2.778 839.023.904.762 0.000 89.56 7.26 180.0 8/7/2024 09:42 4.05883.47812.207 5.933 833.5620.000 0.000 0.000 33.7840.00011.129 1.489 14.1170.000 2.803 839.023.834.672 0.000 87.54 7.26 180.0 8/7/2024 09:43 4.10982.07512.180 5.931 834.5620.000 0.000 0.000 34.0180.00011.253 1.452 14.2280.000 2.785 839.023.934.740 0.000 86.18 7.24 180.0 8/7/2024 09:44 4.80283.48912.218 5.931 833.3280.000 0.000 0.000 34.0620.00011.133 1.502 14.0480.000 2.765 839.023.674.643 0.000 88.29 7.26 180.0 8/7/2024 09:45 4.65583.69612.210 5.936 831.0770.000 0.000 0.000 33.8340.00011.139 1.505 14.1920.000 2.799 839.023.864.601 0.000 88.35 7.24 180.0 8/7/2024 09:46 3.53781.91712.234 5.939 832.2030.000 0.000 0.000 34.2480.00011.267 1.513 14.3660.000 2.774 839.024.014.633 0.000 85.45 7.21 180.0 8/7/2024 09:47 5.13286.11112.259 5.948 832.9250.000 0.000 0.000 34.5140.00010.950 1.445 14.0410.000 2.776 839.023.724.743 0.000 91.24 7.24 180.0 8/7/2024 09:48 4.79183.73212.267 5.934 833.4170.000 0.000 0.013 34.5880.00011.515 1.460 14.3860.000 2.782 839.024.034.662 0.000 88.52 7.24 180.0 8/7/2024 09:49 5.04183.04412.256 5.938 834.3830.000 0.000 0.000 34.5710.00011.178 1.531 14.5040.003 2.758 839.024.194.725 0.000 88.08 7.21 180.0 8/7/2024 09:50 3.60583.41512.290 5.938 835.2820.000 0.000 0.000 34.9260.00011.195 1.446 14.3890.000 2.797 839.024.074.686 0.000 87.02 7.18 180.0 8/7/2024 09:51 4.04381.55812.294 5.934 830.7110.000 0.000 0.000 34.4840.00011.282 1.528 14.3920.000 2.760 839.023.984.571 0.000 85.60 7.20 180.0 8/7/2024 09:52 4.58282.70912.237 5.932 833.2670.000 0.000 0.000 34.6810.00011.136 1.450 14.3770.060 2.801 839.024.024.613 0.000 87.29 7.23 180.0 8/7/2024 09:54 3.90382.74012.212 5.935 832.3500.000 0.000 0.000 34.3980.00011.085 1.490 14.3940.054 2.743 839.024.044.755 0.000 86.64 7.22 180.0 8/7/2024 09:55 4.54982.96312.232 5.935 828.4480.000 0.000 0.000 33.9290.00011.135 1.431 14.3020.000 2.787 839.023.944.666 0.000 87.51 7.22 180.0 8/7/2024 09:56 3.44380.51612.255 5.928 830.6920.000 0.000 0.000 34.2460.00011.200 1.533 14.4080.000 2.774 839.024.054.608 0.000 83.96 7.19 180.0 4.47082.92512.196 5.933 835.0150.000 0.000 0.012 34.3840.00011.316 1.454 14.2530.009 2.762 839.0023.9204.760 0.000 87.394 7.230 180.0Avg. Spike 1 8/7/2024 10:00 12.21994.31411.177 5.837 750.75848.753 0.000 0.525 41.0220.0009.124 3.821 33.8100.038 1.083 839.040.092.355 0.922 106.53 6.56 180.0 Run 1 - B 30minute/60min 8/7/2024 10:03 4.58185.09812.250 5.927 832.6890.000 0.000 0.126 33.1610.00011.783 1.382 13.9330.000 2.787 839.023.494.597 0.001 89.68 7.21 180.0 8/7/2024 10:04 5.30985.15112.245 5.931 836.7960.000 0.000 0.000 34.2490.00011.112 1.315 14.3020.000 2.723 839.023.584.428 0.000 90.46 7.20 180.0 8/7/2024 10:05 4.89885.12512.235 5.932 828.1230.000 0.000 0.000 33.2340.00010.946 1.569 14.1750.000 2.847 839.023.994.604 0.000 90.02 7.21 180.0 8/7/2024 10:06 3.96085.25712.164 5.939 825.6290.000 0.000 0.000 33.1350.00011.058 1.504 14.2590.000 2.849 839.023.994.538 0.000 89.22 7.25 180.0 8/7/2024 10:07 4.13083.45712.153 5.930 830.7000.000 0.000 0.000 33.7910.00010.850 1.407 14.5500.000 2.866 839.024.374.718 0.000 87.59 7.20 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 10:08 4.51982.60312.151 5.928 827.5600.000 0.000 0.000 34.2800.00011.264 1.497 14.6460.000 2.846 839.024.414.610 0.000 87.12 7.27 180.0 8/7/2024 10:09 3.62782.41612.138 5.938 827.6790.000 0.000 0.000 33.8770.00011.161 1.460 14.6990.000 2.826 839.024.504.768 0.000 86.04 7.29 180.0 8/7/2024 10:10 4.38382.08612.094 5.925 828.6690.000 0.000 0.000 33.9120.00010.944 1.596 14.8320.000 2.862 838.024.654.544 0.000 86.47 7.26 180.0 8/7/2024 10:11 3.67882.74112.133 5.939 829.8460.000 0.000 0.000 33.9390.00010.951 1.452 14.7200.000 2.806 838.024.404.651 0.000 86.42 7.28 180.0 8/7/2024 10:12 17.28082.74412.102 5.946 808.6630.000 0.000 0.000 49.0010.0008.714 1.444 12.5850.000 0.979 838.017.422.873 0.000 100.02 7.26 180.0 8/7/2024 10:13 17.23083.71112.110 5.944 807.0310.000 0.000 0.000 48.8030.0008.781 1.458 12.5210.000 1.013 838.017.282.649 0.000 100.94 7.27 180.0 8/7/2024 10:14 17.24084.21912.111 5.945 809.6920.000 0.000 0.000 48.9720.0008.701 1.391 12.6000.000 0.985 838.017.432.894 0.000 101.46 7.29 180.0 8/7/2024 10:15 4.33482.09312.107 5.940 826.4580.000 0.000 0.000 33.9090.00010.780 1.453 14.8190.000 2.851 838.024.584.634 0.000 86.43 7.30 180.0 8/7/2024 10:16 3.83382.50812.099 5.945 830.2620.000 0.000 0.000 33.8680.00011.043 1.473 14.6340.000 2.866 838.024.464.666 0.000 86.34 7.28 180.0 8/7/2024 10:17 4.45982.79112.097 5.936 832.7670.000 0.000 0.000 34.4520.00011.043 1.491 14.7100.000 2.818 838.024.514.754 0.000 87.25 7.27 180.0 8/7/2024 10:18 3.97380.10712.126 5.927 838.5000.000 0.000 0.000 34.7970.00010.810 1.508 14.8770.000 2.810 838.024.664.737 0.000 84.08 7.29 180.0 8/7/2024 10:19 3.82481.61412.131 5.939 833.5270.000 0.000 0.000 34.0430.00010.907 1.534 14.5490.000 2.826 838.024.374.720 0.000 85.44 7.26 180.0 8/7/2024 10:20 3.32981.36512.160 5.946 833.6020.000 0.000 0.000 34.2110.00011.237 1.485 14.6290.000 2.814 838.024.454.802 0.000 84.69 7.24 180.0 8/7/2024 10:21 4.30782.68712.181 5.929 829.0440.000 0.000 0.000 33.9570.00011.082 1.490 14.5320.000 2.862 838.024.374.689 0.000 86.99 7.21 180.0 8/7/2024 10:22 4.25881.55112.232 5.943 829.6170.000 0.000 0.000 33.5170.00010.881 1.455 14.4670.000 2.865 838.024.374.800 0.000 85.81 7.18 180.0 8/7/2024 10:23 16.36883.14112.217 5.936 806.1590.000 0.000 0.000 48.2570.0008.776 1.343 12.3320.000 1.008 838.017.072.740 0.000 99.51 7.18 180.0 8/7/2024 10:24 17.46084.11012.185 5.934 808.1880.000 0.000 0.000 47.6830.0008.864 1.437 12.3340.000 1.014 838.017.252.892 0.000 101.57 7.23 180.0 8/7/2024 10:25 4.11483.25812.145 5.933 829.7970.000 0.000 0.000 33.2040.00010.960 1.439 14.6080.000 2.822 838.024.324.666 0.000 87.37 7.28 180.0 8/7/2024 10:26 3.90782.05512.144 5.928 829.5900.000 0.000 0.000 33.3620.00011.082 1.520 14.4190.000 2.849 838.024.254.674 0.000 85.96 7.24 180.0 8/7/2024 10:28 4.18682.90712.127 5.932 831.4900.000 0.000 0.000 33.5850.00011.128 1.546 14.5530.009 2.850 838.024.444.731 0.000 87.09 7.24 180.0 8/7/2024 10:29 5.00583.72612.163 5.940 830.4420.000 0.000 0.000 33.7240.00011.064 1.521 14.8090.000 2.792 838.024.584.758 0.000 88.73 7.29 180.0 8/7/2024 10:30 3.84982.97812.153 5.941 827.2210.000 0.000 0.000 33.3740.00010.820 1.459 14.6960.000 2.842 838.024.554.798 0.000 86.83 7.26 180.0 8/7/2024 10:31 4.15483.85512.086 5.934 825.9000.000 0.000 0.000 33.3760.00011.269 1.510 14.6110.000 2.869 838.024.574.825 0.000 88.01 7.24 180.0 8/7/2024 10:32 3.02781.47412.069 5.929 826.1300.000 0.000 0.000 32.9780.00010.944 1.518 14.7140.000 2.856 838.024.704.898 0.000 84.50 7.28 180.0 8/7/2024 10:33 16.66482.69812.104 5.933 808.1470.000 0.000 0.000 48.0210.0008.699 1.298 12.3750.000 1.029 838.017.292.989 0.002 99.36 7.25 180.0 6.73082.98412.147 5.936 825.6640.000 0.000 0.004 36.6890.00010.588 1.465 14.1500.000 2.468 838.2322.9434.322 0.000 89.713 7.250 180.0Avg. 5.60082.95512.172 5.934 830.3400.000 0.000 0.008 35.5370.00010.952 1.459 14.2020.005 2.615 838.6223.4324.541 0.000 88.554 7.240 180.0Run 1 Avg: Baseline 1 8/7/2024 10:38 0.0000.0000.032 0.002 1.5640.054 0.048 0.000 0.4500.0010.000 0.000 0.0710.205 0.015 838.00.450.529 0.000 0.00 0.00 180.0 Run 2 - A 30minute/60min 8/7/2024 10:41 16.65882.80512.141 5.916 807.7300.000 0.000 0.068 47.1470.0008.651 1.261 12.2040.000 1.046 838.017.102.952 0.000 99.46 6.57 180.0 8/7/2024 10:42 17.64982.99512.172 5.919 808.6680.000 0.000 0.000 47.4750.0008.814 1.396 12.1350.000 1.029 838.017.183.087 0.000 100.64 6.78 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 10:43 3.73882.56912.163 5.920 827.9470.000 0.000 0.000 32.3830.00011.303 1.475 14.2820.003 2.863 838.024.335.001 0.000 86.31 6.94 180.0 8/7/2024 10:44 4.04682.04912.177 5.923 828.1680.000 0.000 0.000 33.0310.00010.857 1.468 14.6100.000 2.818 838.024.554.986 0.000 86.09 7.06 180.0 8/7/2024 10:45 4.10483.57412.188 5.924 828.2680.000 0.000 0.000 32.5820.00011.021 1.378 14.5570.000 2.828 838.024.384.877 0.000 87.68 7.09 180.0 8/7/2024 10:46 4.04384.09812.181 5.925 828.3830.000 0.000 0.000 32.2200.00010.738 1.462 14.4740.083 2.848 838.024.424.908 0.000 88.14 7.14 180.0 8/7/2024 10:47 4.04883.66712.179 5.933 828.1150.000 0.000 0.000 32.4720.00010.772 1.498 14.5280.000 2.874 838.024.564.928 0.000 87.72 7.15 180.0 8/7/2024 10:48 4.14482.85112.187 5.934 826.3250.000 0.000 0.000 32.5420.00010.961 1.519 14.6410.000 2.824 838.024.514.818 0.000 87.00 7.18 180.0 8/7/2024 10:49 4.27883.77912.158 5.930 828.0580.000 0.000 0.000 33.1450.00010.831 1.384 14.5990.000 2.877 838.024.514.857 0.000 88.06 7.19 180.0 8/7/2024 10:50 4.34981.68112.168 5.929 828.9930.000 0.000 0.000 33.1770.00010.753 1.427 14.7200.000 2.851 838.024.715.005 0.000 86.03 7.18 180.0 8/7/2024 10:51 3.82982.27812.169 5.930 827.4340.000 0.000 0.000 33.3150.00010.818 1.443 14.6020.000 2.849 838.024.594.988 0.000 86.11 7.19 180.0 8/7/2024 10:52 16.99082.86812.180 5.930 807.8340.000 0.000 0.000 48.5140.0008.929 1.388 12.6380.000 0.974 838.017.492.968 0.000 99.86 7.21 180.0 8/7/2024 10:53 3.71882.53312.224 5.938 824.2120.000 0.000 0.000 33.3900.00010.997 1.485 14.8870.000 2.833 838.024.824.918 0.000 86.25 7.21 180.0 8/7/2024 10:54 16.83583.19212.206 5.941 808.2890.000 0.000 0.000 48.3650.0008.760 1.436 12.6690.000 1.060 838.017.742.993 0.000 100.03 7.23 180.0 8/7/2024 10:55 3.21382.69812.166 5.943 828.1230.000 0.000 0.000 33.1810.00011.179 1.408 14.7970.000 2.863 838.024.815.016 0.000 85.91 7.23 180.0 8/7/2024 10:56 4.05581.76312.151 5.921 828.0870.000 0.000 0.000 33.2480.00010.847 1.573 14.7820.000 2.872 838.024.834.876 0.000 85.82 7.21 180.0 8/7/2024 10:57 3.48981.61612.121 5.918 827.7890.000 0.000 0.000 33.1820.00010.718 1.385 14.6630.000 2.847 838.024.564.923 0.000 85.10 7.20 180.0 8/7/2024 10:58 2.94480.79712.125 5.913 830.2220.000 0.000 0.000 33.3370.00010.849 1.508 14.7430.000 2.784 838.024.644.992 0.000 83.74 7.19 180.0 8/7/2024 10:59 16.67782.32712.125 5.927 808.1510.000 0.000 0.000 47.7210.0008.678 1.271 12.4030.000 0.980 838.017.263.068 0.000 99.00 7.18 180.0 8/7/2024 11:00 3.49482.83412.158 5.935 827.3380.000 0.000 0.000 33.0990.00010.741 1.431 14.6050.000 2.798 838.024.464.953 0.000 86.33 7.17 180.0 8/7/2024 11:01 16.90582.37912.139 5.921 808.4520.000 0.000 0.000 47.7590.0008.752 1.389 12.4960.000 1.034 838.017.432.911 0.000 99.28 7.23 180.0 8/7/2024 11:03 17.57682.70812.162 5.934 810.2470.000 0.000 0.000 47.8350.0008.711 1.351 12.4140.000 1.009 838.017.443.157 0.001 100.28 7.21 180.0 8/7/2024 11:04 4.43883.27612.167 5.930 826.2300.000 0.000 0.000 32.4580.00011.143 1.487 14.5630.000 2.823 838.024.424.830 0.000 87.71 7.18 180.0 8/7/2024 11:05 16.38182.39012.163 5.930 808.5250.000 0.000 0.000 47.7240.0008.649 1.426 12.4220.000 1.010 838.017.392.999 0.000 98.77 7.21 180.0 8/7/2024 11:06 4.57683.76712.174 5.924 827.0430.000 0.000 0.000 32.6040.00011.035 1.487 14.6000.000 2.826 838.024.494.874 0.000 88.34 7.17 180.0 8/7/2024 11:07 16.70183.01112.205 5.933 807.1250.000 0.000 0.000 47.6140.0008.587 1.509 12.2880.000 1.035 838.017.322.928 0.000 99.71 7.19 180.0 8/7/2024 11:08 4.28083.61412.172 5.936 824.7110.000 0.000 0.000 32.8270.00011.076 1.350 14.4180.000 2.900 838.024.324.809 0.000 87.89 7.20 180.0 8/7/2024 11:09 16.36783.43412.204 5.936 804.6400.000 0.000 0.000 47.3930.0008.856 1.538 12.4400.000 1.034 838.017.603.102 0.000 99.80 7.21 180.0 8/7/2024 11:10 17.08686.14912.208 5.949 800.2770.000 0.000 0.000 46.2890.0008.745 1.449 12.2940.000 1.033 838.017.393.092 0.000 103.23 7.20 180.0 8/7/2024 11:11 18.16089.21712.176 5.942 804.1390.000 0.000 0.000 46.5550.0008.808 1.439 12.1860.000 1.085 838.017.393.107 0.000 107.38 7.20 180.0 9.15983.09712.170 5.929 819.3170.000 0.000 0.002 38.7530.00010.053 1.434 13.7220.003 2.117 838.0021.6884.164 0.000 92.256 7.143 180.0Avg. Spike 2 8/7/2024 11:20 12.22892.68111.173 5.849 741.93145.402 0.000 0.406 40.3070.0008.842 3.592 33.4050.000 1.195 838.039.952.642 0.866 104.91 6.62 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/7/2024 11:23 16.41482.96612.180 5.949 792.5030.000 0.000 0.000 47.0830.0008.509 1.271 13.0390.000 1.092 838.018.253.267 0.001 99.38 7.19 180.0 8/7/2024 11:24 17.24286.13412.156 5.946 790.2810.000 0.000 0.000 46.5900.0008.729 1.355 12.8880.000 1.121 838.017.992.942 0.000 103.38 7.20 180.0 8/7/2024 11:25 16.24485.21012.164 5.955 790.3080.000 0.000 0.000 46.4440.0008.719 1.328 13.0600.000 1.115 838.018.273.135 0.001 101.45 7.23 180.0 8/7/2024 11:26 16.81083.91112.169 5.950 790.6150.000 0.000 0.000 46.4170.0008.985 1.183 13.0870.000 1.140 838.018.183.031 0.003 100.72 7.21 180.0 8/7/2024 11:27 16.36583.17212.193 5.946 794.1560.000 0.000 0.000 46.9270.0008.629 1.441 13.1330.093 1.138 838.018.463.129 0.001 99.54 7.19 180.0 8/7/2024 11:28 16.09581.25712.193 5.943 794.3330.000 0.000 0.000 46.9210.0008.764 1.369 13.1960.000 1.114 838.018.363.039 0.001 97.35 7.20 180.0 8/7/2024 11:29 16.08682.25012.195 5.934 795.5730.000 0.000 0.000 46.6210.0008.865 1.492 12.9000.000 1.157 838.018.142.899 0.000 98.34 7.21 180.0 8/7/2024 11:30 17.04184.06512.173 5.945 793.4190.000 0.000 0.000 46.5290.0008.591 1.375 12.8310.000 1.110 838.017.932.950 0.000 101.11 7.21 180.0 8/7/2024 11:31 16.36084.78912.165 5.941 791.5890.000 0.000 0.000 46.4880.0008.953 1.337 13.0120.000 1.120 838.018.243.151 0.002 101.15 7.25 180.0 8/7/2024 11:32 16.68483.54512.145 5.949 792.4090.000 0.000 0.000 46.5430.0008.787 1.344 13.0450.000 1.124 838.018.263.104 0.002 100.23 7.22 180.0 8/7/2024 11:33 16.67383.98712.144 5.939 797.3420.000 0.000 0.000 46.9560.0008.668 1.368 12.9890.029 1.105 838.018.203.134 0.000 100.66 7.25 180.0 8/7/2024 11:34 16.58081.06212.133 5.931 797.6690.000 0.000 0.000 47.0390.0008.724 1.434 13.1370.000 1.137 838.018.413.060 0.000 97.64 7.22 180.0 8/7/2024 11:35 16.41481.57912.208 5.938 797.8150.000 0.000 0.000 46.8340.0008.739 1.460 13.0320.000 1.074 838.018.163.006 0.000 97.99 7.20 180.0 8/7/2024 11:37 17.45283.70312.172 5.935 795.4160.000 0.000 0.000 46.5280.0008.684 1.312 12.7890.000 1.110 838.017.973.124 0.002 101.15 7.20 180.0 8/7/2024 11:38 16.39881.77512.162 5.934 794.1290.000 0.000 0.000 46.6230.0008.625 1.263 12.8680.000 1.124 838.018.073.166 0.000 98.17 7.21 180.0 8/7/2024 11:39 16.95082.90312.158 5.944 795.9970.000 0.000 0.000 47.0350.0008.743 1.313 12.9360.000 1.116 838.018.123.120 0.001 99.85 7.22 180.0 8/7/2024 11:40 16.80984.58312.148 5.938 792.2300.000 0.000 0.000 46.6490.0009.014 1.375 12.9450.000 1.156 838.018.152.961 0.001 101.39 7.21 180.0 8/7/2024 11:41 16.32683.80112.180 5.946 795.8400.000 0.000 0.000 47.2240.0008.828 1.526 13.0580.000 1.067 838.018.253.055 0.000 100.13 7.23 180.0 8/7/2024 11:42 16.87782.74912.160 5.946 796.4400.000 0.000 0.000 46.9470.0008.848 1.350 13.1310.000 1.119 838.018.383.167 0.000 99.63 7.20 180.0 8/7/2024 11:43 15.44780.51312.163 5.935 794.6900.000 0.000 0.000 46.9980.0008.614 1.293 13.0830.000 1.157 838.018.323.086 0.001 95.96 7.23 180.0 8/7/2024 11:44 16.78682.46012.187 5.935 799.6940.000 0.000 0.000 46.9500.0008.749 1.222 13.0050.000 1.124 838.018.123.078 0.002 99.25 7.20 180.0 8/7/2024 11:45 16.31280.30912.203 5.935 799.3560.000 0.000 0.000 47.4870.0008.861 1.222 12.7890.000 1.145 838.017.943.073 0.002 96.62 7.19 180.0 8/7/2024 11:46 16.44482.58012.193 5.942 800.1780.000 0.000 0.000 47.7220.0008.524 1.480 12.7370.000 1.099 838.017.822.852 0.000 99.02 7.23 180.0 8/7/2024 11:47 15.72077.78612.196 5.938 805.1180.000 0.000 0.000 48.7820.0008.773 1.518 13.3490.000 1.092 837.018.573.032 0.000 93.51 7.24 180.0 8/7/2024 11:48 15.20276.17312.142 5.934 801.9300.000 0.000 0.000 48.2910.0008.770 1.367 13.5670.000 1.107 837.018.753.086 0.000 91.37 7.18 180.0 8/7/2024 11:49 15.19674.85012.137 5.922 804.6990.000 0.000 0.000 49.3590.0008.786 1.489 13.5890.000 1.091 837.018.722.941 0.000 90.05 7.18 180.0 8/7/2024 11:50 14.47973.33112.156 5.923 803.1620.000 0.000 0.000 49.0240.0008.997 1.313 13.5070.000 1.132 837.018.663.016 0.000 87.81 7.18 180.0 8/7/2024 11:51 15.81977.14912.145 5.943 799.9460.000 0.000 0.000 48.0490.0008.778 1.335 13.3670.000 1.128 837.018.563.075 0.001 92.97 7.22 180.0 8/7/2024 11:52 14.87175.85112.120 5.934 800.6450.000 0.000 0.000 48.7320.0008.767 1.380 13.5280.000 1.095 837.018.642.999 0.001 90.72 7.19 180.0 8/7/2024 11:53 14.83474.60912.116 5.920 800.9670.000 0.000 0.000 48.9130.0008.735 1.548 13.5470.000 1.114 837.018.742.895 0.000 89.44 7.21 180.0 16.23181.30212.165 5.939 796.6150.000 0.000 0.000 47.2900.0008.759 1.369 13.1050.004 1.117 837.7718.2883.052 0.001 97.533 7.210 180.0Avg. 12.69582.20012.168 5.934 807.9660.000 0.000 0.001 43.0210.0009.406 1.401 13.4130.003 1.617 837.8819.9883.608 0.000 94.894 7.177 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/7/2024 11:56 0.0000.0000.023 0.000 1.2580.038 0.044 0.079 0.4460.0000.000 0.000 0.0580.000 0.020 837.00.330.351 0.000 0.00 0.00 180.0 Run 3 - A 30minute/60min 8/7/2024 11:59 14.30275.56112.077 5.913 792.3820.000 0.000 0.103 48.1420.0008.853 1.532 13.7980.000 1.134 837.018.982.836 0.000 89.86 6.57 180.0 8/7/2024 12:00 14.46374.55412.119 5.931 793.6810.000 0.000 0.000 48.1450.0008.819 1.259 13.8750.000 1.189 837.019.113.025 0.000 89.02 6.83 180.0 8/7/2024 12:01 14.89275.62412.106 5.929 790.8600.000 0.000 0.003 47.9400.0008.648 1.348 13.9240.000 1.177 837.019.062.830 0.000 90.52 6.97 180.0 8/7/2024 12:02 14.40074.09512.094 5.921 791.0960.000 0.000 0.000 48.1880.0008.817 1.304 14.1730.000 1.165 837.019.232.781 0.001 88.49 7.06 180.0 8/7/2024 12:03 14.70476.53812.089 5.937 790.6370.000 0.000 0.000 48.0840.0008.805 1.477 14.1680.000 1.173 837.019.452.921 0.000 91.24 7.12 180.0 8/7/2024 12:04 14.23873.84112.093 5.929 793.9880.000 0.000 0.000 48.5710.0008.698 1.507 14.2900.000 1.183 837.019.622.946 0.000 88.08 7.12 180.0 8/7/2024 12:05 15.13074.57412.123 5.940 795.2190.000 0.000 0.000 48.5390.0008.881 1.518 14.2970.000 1.206 837.019.612.832 0.000 89.70 7.16 180.0 8/7/2024 12:06 14.61973.90212.122 5.938 796.5260.000 0.000 0.000 48.4590.0008.613 1.411 14.3360.000 1.190 837.019.512.782 0.001 88.52 7.14 180.0 8/7/2024 12:07 14.37072.69212.172 5.941 795.8190.000 0.000 0.000 48.4420.0009.088 1.346 14.0690.000 1.232 837.019.312.826 0.000 87.06 7.13 180.0 8/7/2024 12:08 14.07573.04312.197 5.942 794.6320.000 0.000 0.000 48.1480.0008.955 1.347 14.0450.000 1.192 837.019.222.834 0.001 87.12 7.16 180.0 8/7/2024 12:09 14.38973.27712.151 5.922 793.3820.000 0.000 0.000 48.2450.0008.795 1.301 14.1350.000 1.176 837.019.222.794 0.000 87.67 7.13 180.0 8/7/2024 12:10 14.82974.18212.138 5.934 790.4770.000 0.000 0.000 47.9070.0008.766 1.479 14.0630.000 1.208 837.019.392.881 0.000 89.01 7.14 180.0 8/7/2024 12:12 14.43175.00812.157 5.942 790.2750.000 0.000 0.000 47.7790.0008.830 1.310 14.0630.000 1.232 837.019.272.799 0.000 89.44 7.16 180.0 8/7/2024 12:13 15.05276.89512.140 5.945 793.4080.000 0.000 0.000 47.9440.0008.973 1.535 14.0590.000 1.221 837.019.352.743 0.000 91.95 7.19 180.0 8/7/2024 12:14 14.68974.41412.137 5.949 793.8020.000 0.000 0.000 48.0390.0009.032 1.360 14.1060.000 1.248 837.019.332.736 0.000 89.10 7.18 180.0 8/7/2024 12:15 15.03374.33812.154 5.945 790.1200.000 0.000 0.000 47.2350.0008.892 1.348 13.8970.000 1.287 837.019.132.649 0.000 89.37 7.14 180.0 8/7/2024 12:16 14.64273.62812.134 5.943 793.1420.000 0.000 0.000 48.0750.0008.924 1.444 14.0480.000 1.220 837.019.242.684 0.000 88.27 7.15 180.0 8/7/2024 12:17 14.27573.22312.143 5.940 792.4750.000 0.000 0.000 47.9090.0008.941 1.389 13.9640.000 1.217 837.019.042.580 0.001 87.50 7.19 180.0 8/7/2024 12:18 15.59474.26112.150 5.939 792.6500.000 0.000 0.000 47.9480.0009.114 1.347 14.1320.002 1.241 837.019.212.555 0.000 89.86 7.16 180.0 8/7/2024 12:19 14.45875.99712.125 5.947 794.0170.000 0.000 0.000 48.4560.0009.016 1.326 14.1840.000 1.205 837.019.172.530 0.000 90.46 7.19 180.0 8/7/2024 12:20 14.29271.98712.128 5.941 795.5560.000 0.000 0.000 48.8470.0008.858 1.391 14.3240.000 1.295 837.019.502.487 0.000 86.28 7.15 180.0 8/7/2024 12:21 15.01874.53012.150 5.944 794.1290.000 0.000 0.000 48.3250.0009.171 1.493 14.3030.000 1.241 837.019.482.547 0.000 89.55 7.15 180.0 8/7/2024 12:22 14.75274.31212.161 5.945 792.1390.000 0.000 0.000 48.2840.0009.045 1.341 14.2520.000 1.305 837.019.382.431 0.000 89.06 7.13 180.0 8/7/2024 12:23 14.60975.74012.128 5.938 788.9840.000 0.000 0.000 47.2500.0009.043 1.360 14.1720.000 1.241 837.019.222.487 0.000 90.35 7.18 180.0 8/7/2024 12:24 14.61374.87612.125 5.930 793.3190.000 0.000 0.000 47.9900.0009.143 1.432 14.1910.000 1.245 837.019.252.420 0.000 89.49 7.18 180.0 8/7/2024 12:25 14.92772.61212.129 5.924 794.3370.000 0.000 0.000 48.5790.0009.183 1.612 14.1740.000 1.278 837.019.422.427 0.000 87.54 7.19 180.0 8/7/2024 12:26 15.06774.57112.111 5.926 792.9480.000 0.000 0.000 48.3010.0009.087 1.441 14.2060.000 1.264 837.019.242.309 0.000 89.64 7.16 180.0 8/7/2024 12:27 14.99675.65512.108 5.939 791.8330.000 0.000 0.000 47.8730.0009.085 1.467 14.3540.000 1.245 837.019.432.408 0.000 90.65 7.18 180.0 8/7/2024 12:28 14.41574.47512.110 5.935 790.8680.000 0.000 0.000 47.8090.0009.450 1.363 14.3710.000 1.240 837.019.362.400 0.001 88.89 7.16 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 12:29 15.18273.57312.135 5.944 793.3530.000 0.000 0.000 48.2980.0009.386 1.403 14.3370.000 1.279 837.019.332.248 0.001 88.76 7.13 180.0 14.68274.39912.130 5.936 792.8680.000 0.000 0.004 48.1250.0008.964 1.406 14.1440.000 1.224 837.0019.3022.658 0.000 89.082 7.117 180.0Avg. Spike 3 8/7/2024 12:44 10.50986.46711.025 5.848 726.96145.624 0.000 0.305 39.9420.0009.146 3.624 34.7180.000 1.434 837.041.271.903 0.862 96.98 6.63 180.0 Run 3 - B 30minute/60min 8/7/2024 14:24 14.90371.21211.344 5.671 987.7750.000 0.000 0.000 67.3630.00011.922 1.417 32.3360.000 3.153 836.042.324.099 0.000 86.12 7.52 180.0 8/7/2024 14:25 13.87768.65211.354 5.664 981.5390.000 0.000 0.000 66.8700.00011.581 1.339 31.8760.000 3.179 836.041.924.184 0.003 82.53 7.59 180.0 8/7/2024 14:26 12.50071.36811.320 5.645 974.5160.000 0.000 0.000 65.0820.00011.713 1.371 30.9580.000 3.144 836.040.904.108 0.002 83.87 7.65 180.0 8/7/2024 14:27 11.24176.25211.308 5.654 967.6590.000 0.000 0.000 63.2800.00011.672 1.269 30.3200.000 3.201 836.040.314.119 0.000 87.49 7.68 180.0 8/7/2024 14:28 14.35274.80311.245 5.631 975.5620.000 0.000 0.000 64.7890.00011.458 1.449 30.9260.000 3.166 836.040.964.101 0.000 89.16 7.67 180.0 8/7/2024 14:29 13.86671.58711.279 5.632 977.3370.000 0.000 0.000 65.6160.00011.354 1.354 31.3100.000 3.150 836.041.214.052 0.002 85.45 7.69 180.0 8/7/2024 14:30 14.46171.36111.268 5.626 977.6620.000 0.000 0.000 65.7000.00011.387 1.408 31.6300.000 3.186 836.041.734.187 0.001 85.82 7.64 180.0 8/7/2024 14:31 14.11471.74711.222 5.614 978.0350.000 0.000 0.000 65.7310.00011.504 1.355 31.6010.000 3.211 836.041.654.089 0.002 85.86 7.68 180.0 8/7/2024 14:32 12.46069.67111.241 5.616 975.3550.000 0.000 0.000 65.2860.00011.396 1.283 31.6540.000 3.174 835.041.614.124 0.001 82.13 7.77 180.0 8/7/2024 14:33 12.87970.44411.219 5.611 970.9670.000 0.000 0.000 64.6050.00011.458 1.341 31.4780.000 3.233 835.041.594.132 0.000 83.32 7.73 180.0 8/7/2024 14:34 12.89970.80611.216 5.617 976.3230.000 0.000 0.000 65.7300.00011.542 1.298 31.8700.000 3.235 835.041.934.093 0.002 83.71 7.67 180.0 8/7/2024 14:35 14.08470.07011.332 5.662 983.7990.000 0.000 0.000 66.5220.00011.583 1.308 31.6300.000 3.150 836.041.554.127 0.001 84.15 7.50 180.0 8/7/2024 14:36 11.56270.48711.360 5.666 983.9770.000 0.000 0.000 66.2350.00011.595 1.176 31.5840.000 3.125 836.041.233.917 0.001 82.05 7.59 180.0 8/7/2024 14:37 13.98269.64611.345 5.632 983.4750.000 0.000 0.000 66.0490.00011.368 1.339 31.3510.000 3.112 836.041.103.953 0.002 83.63 7.59 180.0 8/7/2024 14:38 14.53673.47211.397 5.662 981.1470.000 0.000 0.000 65.4930.00011.752 1.355 31.2500.000 3.101 836.040.983.933 0.002 88.01 7.67 180.0 8/7/2024 14:39 11.48573.09911.327 5.644 977.5820.000 0.000 0.000 64.7140.00011.502 1.257 31.0970.000 3.164 836.040.903.952 0.001 84.58 7.61 180.0 8/7/2024 14:41 14.14773.39811.378 5.668 980.7580.000 0.000 0.000 64.8850.00011.689 1.307 30.9410.000 3.146 836.040.723.917 0.003 87.54 7.63 180.0 8/7/2024 14:42 14.19471.59611.408 5.661 982.4500.000 0.000 0.000 65.0660.00011.721 1.340 30.9320.000 3.130 836.040.653.844 0.001 85.79 7.59 180.0 8/7/2024 14:43 15.73771.32911.525 5.687 988.0930.000 0.000 0.000 65.8180.00011.693 1.315 31.0370.000 3.141 836.040.773.860 0.001 87.07 7.49 180.0 8/7/2024 14:44 13.58173.80811.401 5.646 979.4970.000 0.000 0.000 64.6610.00011.667 1.437 30.5460.000 3.134 836.040.333.831 0.001 87.39 7.70 180.0 8/7/2024 14:45 12.60974.60511.405 5.666 984.1930.000 0.000 0.000 64.9590.00011.726 1.540 30.4890.000 3.139 836.040.313.772 0.001 87.21 7.62 180.0 8/7/2024 14:46 12.52473.07911.443 5.673 986.8860.000 0.000 0.000 65.9730.00011.812 1.152 30.7930.000 3.095 836.040.243.739 0.002 85.60 7.62 180.0 8/7/2024 14:47 14.56671.90111.412 5.655 977.8870.000 0.000 0.000 64.8520.00011.718 1.357 30.7900.000 3.102 836.040.383.718 0.001 86.47 7.65 180.0 8/7/2024 14:48 14.23475.18411.456 5.674 976.7880.000 0.000 0.000 64.5670.00012.071 1.391 30.6120.000 3.135 836.040.303.729 0.001 89.42 7.63 180.0 8/7/2024 14:49 13.90374.18811.418 5.647 970.4440.000 0.000 0.000 63.6370.00011.913 1.309 30.5440.000 3.186 836.040.343.825 0.001 88.09 7.61 180.0 8/7/2024 14:50 14.66771.44711.435 5.651 976.8100.000 0.000 0.000 64.3820.00012.000 1.484 30.5800.000 3.134 836.040.223.575 0.002 86.11 7.57 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 14:51 14.24071.28311.480 5.664 982.5120.000 0.000 0.000 64.7510.00012.153 1.520 30.7380.000 3.116 836.040.393.615 0.000 85.52 7.64 180.0 8/7/2024 14:52 12.83371.75711.320 5.597 973.2110.000 0.000 0.000 63.4350.00011.571 1.490 30.1610.000 3.127 836.039.843.646 0.000 84.59 7.76 180.0 8/7/2024 14:53 13.77173.37211.350 5.609 977.3220.000 0.000 0.000 63.8300.00011.987 1.381 30.3600.000 3.113 836.040.053.810 0.001 87.14 7.66 180.0 8/7/2024 14:54 14.45971.37211.457 5.664 981.3790.000 0.000 0.000 64.1430.00011.897 1.304 30.2790.000 3.107 836.039.803.653 0.001 85.83 7.62 180.0 13.62272.10011.356 5.647 979.0310.000 0.000 0.000 65.1340.00011.680 1.355 31.0560.000 3.150 835.9040.8743.923 0.001 85.722 7.635 180.0Avg. 14.15273.25011.743 5.792 885.9500.000 0.000 0.002 56.6300.00010.322 1.381 22.6000.000 2.187 836.4530.0883.291 0.001 87.402 7.376 180.0Run 3 Avg: Baseline 3 8/7/2024 14:57 0.5470.0370.023 0.006 0.7590.120 0.017 0.110 0.0830.0000.000 0.000 0.0000.105 0.105 836.00.210.000 0.000 0.58 0.00 180.0 Post CTS 8/7/2024 14:59 0.0000.1990.036 0.009 0.1690.172 0.023 0.000 0.5790.0920.000 107.390 0.1970.454 0.039 837.071.870.000 0.000 0.20 1.22 180.0 8/7/2024 14:59 0.0000.6130.030 0.013 0.0000.251 0.033 0.067 0.2960.0240.000 108.251 0.0710.259 0.075 837.072.390.000 0.000 0.61 1.49 180.0 8/7/2024 14:59 0.0000.0000.026 0.034 0.0000.062 0.011 0.000 0.1430.0000.000 105.055 0.0620.000 0.105 837.070.310.000 0.002 0.00 0.00 180.0 8/7/2024 15:00 0.4490.0000.023 0.015 0.0000.125 0.035 0.121 0.0000.0000.000 105.566 0.0000.636 0.082 837.070.540.000 0.000 0.45 0.00 180.0 Post NO2/Mid O2 8/7/2024 15:03 102.1210.738-0.000 0.000 1.2660.000 0.822 0.000 0.0000.0130.000 0.000 0.0000.445 0.049 837.00.100.000 0.000 102.86 10.23 180.0 8/7/2024 15:03 103.0510.6860.009 0.009 1.5250.148 0.830 0.000 0.0610.0000.000 0.000 0.0000.905 0.059 837.00.120.000 0.000 103.74 10.23 180.0 8/7/2024 15:04 101.9520.658-0.000 0.000 1.4410.000 0.818 0.000 0.4450.0120.000 0.000 0.0000.982 0.031 837.00.060.000 0.000 102.61 10.26 180.0 8/7/2024 15:04 101.4430.562-0.000 0.000 1.2110.054 0.824 0.000 0.0610.0000.000 0.000 0.0000.269 0.063 837.00.130.000 0.000 102.00 10.39 180.0 Post 5-Gas 8/7/2024 15:05 0.000243.574-0.000 4.685 2.256486.623 1.143 1.843 8.8190.0000.202 1.855 244.4430.000 0.000 837.0247.172.241 9.788 243.57 0.00 180.0 8/7/2024 15:05 0.000246.8940.009 4.730 5.596495.051 1.198 2.132 9.7510.1830.164 1.458 247.5030.029 0.000 837.0249.561.630 9.951 246.89 0.00 180.0 8/7/2024 15:05 0.000248.320-0.000 4.764 2.618499.028 1.229 1.991 8.6950.0210.272 1.241 249.8880.000 0.000 837.0252.011.949 10.039 248.32 0.00 180.0 8/7/2024 15:05 0.000248.6760.004 4.804 3.343498.971 1.201 2.052 8.6920.0760.319 1.136 251.1000.505 0.000 837.0253.332.211 10.075 248.68 0.00 180.0 End of Test Purge 8/7/2024 15:08 0.4700.389-0.000 0.005 0.0000.635 0.023 0.000 0.0170.0000.000 0.033 0.1120.097 0.032 837.00.200.000 0.002 0.86 0.00 180.0 8/7/2024 15:08 0.2750.976-0.000 0.015 0.0000.483 0.002 0.000 0.0000.0520.000 0.253 0.2350.088 0.012 837.00.430.000 0.003 1.25 0.00 180.0 8/7/2024 15:08 0.0000.673-0.000 0.000 0.0000.307 0.060 0.106 0.0000.5490.000 0.096 0.0000.000 0.068 836.00.200.000 0.000 0.67 0.00 180.0 8/7/2024 15:08 0.2781.0450.001 0.000 0.0270.390 0.035 0.162 0.1310.0000.000 0.221 0.1240.000 0.076 836.00.420.000 0.001 1.32 0.00 180.0 8/7/2024 15:08 0.7740.0000.008 0.004 0.0000.310 0.028 0.000 0.0000.8370.163 0.258 0.1820.105 0.000 836.00.350.000 0.006 0.77 0.00 180.0 8/7/2024 15:08 0.2090.2750.010 0.000 0.0000.286 0.061 0.006 0.2560.0000.000 0.110 0.1270.201 0.084 836.00.370.000 0.000 0.48 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 15:09 1.1410.1150.003 0.000 0.6700.209 0.059 0.057 0.1650.0070.000 0.031 0.1450.303 0.001 836.00.170.000 0.000 1.26 0.00 180.0 8/7/2024 15:09 1.3350.1410.001 0.002 0.2450.416 0.060 0.112 0.0000.0340.000 0.000 0.1920.522 0.000 836.00.190.000 0.003 1.48 0.00 180.0 GAS, Inc. Performance Test Report Test Type: Annual Test Date: 8/7/2024 Caterpillar G3516 TALE Lean Burn (4 Cycle) DOM: 11/26/19 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:04:11 PM 08:11 PM Source: Unit Number: 4 Serial Number: WPW02396 Engine Hours:30378 Permit #: #DAQE-AN142100007-23 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Pleasant Valley Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 0.360 2.950 0.980 0.000 1.430 0.447 0.000 82.490 26.920 2.000 1.000 0.700 0.000 0.690 0.216 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Ovintiv USA Inc. 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 kyle muir 3 Logan Miller Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit 4 with a serial number of WPW02396 which is a Caterpillar G3516 TALE engine located at Pleasant Valley Compressor Station and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/7/2024 by Logan Miller with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1340 brake horse power (BHP) at 1400 RPM. The engine was operating at 940 BHP and 1400 RPM which is 70.16% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit 4 is authorized to operate under permit #DAQE-AN142100007-23. 4 4.0 Test Summary Engine/Compressor Specs Pleasant Valley Compressor StationLocation 4Unit ID Make Caterpillar Site Elevation ft.5419 Model G3516 TALE Atmospheric Pressure psi.12.19 Serial Number WPW02396 Stack Diameter in.14 mfg. rated hp 1340 Yes 1400 Date of Manufacture 11/26/2019 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 937 941 942 940 1400 1399 1400 1400 Percent Load % Intake Manifold Pressure (hg) 69.90%70.26%70.31%70.16% 29.95 30.15 30.15 30.09 Intake Manifold Temperature (F)140.00 143.00 143.00 142.00 Ambient Conditions Ambient Temperature Dry (F)95.00 96.00 96.00 95.67 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 143739.10 145271.72 146765.12 145258.64 4070.20 4113.60 4155.89 4113.23 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.10 0.10 0.10 0.10 9504.87 9499.02 9498.2 9500.6966666666 666667Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %10.29%10.28%10.23%10.27% T e s t S u m m a r y mfg. rated rpm Test RPM 10.70%10.56%10.60%10.62% Permitted Standards Results 5 Catalyst 0.0000.000 Run 1 Run 2 Run 3 3 Run Average Pass Permits 04:11 PM 05:24 PM 06:36 PM 8/7/2024 CO (g/hp-hr)0.000 0.0002.000 Pass StateFederal CO (ppmvw)0.000 0.000 0.000 0.000 CO (ppmvd)0.000 0.000 0.000 0.000 CO (mol wt) 28.01 CO (ppmvd) @15% O2 0.000 0.000 0.000 0.000 Fail CO (ppbvd) @15% O2 0.000 0.000 0.000 0.000 Fail 0.0000.000CO (lbs/hr)0.000 0.0000.360 Pass NOx (g/hp-hr)0.695 0.692 0.683 0.6901.000 Pass NOx (ppmvw)74.998 74.337 72.726 74.020 NOx (ppmvd)83.603 82.851 81.015 82.490 NOx (mol wt) 46.01 23.771 24.445 24.254 24.156NMNEHC (ppmvw) 26.498 27.244 27.019 26.920NMNEHC (ppmvd) NOx (ppbvd) @15% O2 48368.772 47270.744 46397.436 47345.651 Fail NOx (ppmvd) @15% O2 48.369 47.271 46.397 47.346 Fail NMNEHC (mol wt) 44.10 15330.510 15544.311 15473.574 15449.465 FailNMNEHC (ppbvd) @15% O2 0.211 0.218 0.218 0.2160.700 PassNMNEHC (g/hp-hr) 0.436 0.453 0.454 0.4470.980 PassNMNEHC (lbs/hr) 15.331 15.544 15.474 15.449 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)1.434 1.437 1.419 1.4302.950 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.35Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 0.00 0.29 61.26 0.02 13.74 0.30 75.00 0.53 23.77 0.00% 9.37% 0.00% 10.29% NMNEHC 0.00 63.35 13.85 77.20 23.66 9.35%10.28% 46.16 72.01 9.61 81.62 45.48 8.66%9.29% 0.00 59.16 13.63 72.80 23.88 9.40%10.31% 0.13 0.00 0.50 0.50 0.10 0.00%0.01% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.13 0.00 0.50 0.50 0.10 0.00%0.01% 0.00 59.90 14.24 74.14 24.24 9.19%10.37% 45.88 73.38 10.60 83.98 46.41 8.64%9.32% 0.00 59.86 14.68 74.53 24.65 9.31%10.19% 0.15 0.04 0.92 0.96 0.28 0.00%0.01% Avg. Wet 0.00 59.88 14.46 74.34 24.44 9.25%10.28% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 58.61 14.59 73.21 24.36 9.21%10.19% 47.13 73.07 10.08 83.15 46.37 8.70%9.27% 0.00 58.17 14.08 72.25 24.15 9.36%10.28% 0.26 0.00 0.96 0.96 0.36 0.00%0.02% 0.15 0.04 0.92 0.96 0.28 0.00%0.01% Avg. Wet 0.00 58.39 14.33 72.73 24.25 9.29%10.23% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 14 inches or:1.17 feet. or:1.07 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 1.08 Yes 14.00 230.00 53.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 10.29 29.17 1.04 Inches 2.34 7 11.66 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 4.96 9.38 0.00 835.00 0.08 24.66 24.74 724.81 1184.48 384.90 28.02 112.96 120.76 160232.64 143739.09 Run 2 10.28 29.17 1.07 4.97 9.25 0.00 835.00 0.08 24.66 24.74 726.94 1186.61 386.08 28.02 114.34 122.23 161910.45 145271.72 Run 3 10.23 29.16 1.08 4.94 9.29 0.00 834.97 0.08 24.66 24.74 714.88 1174.55 379.38 28.02 114.29 122.18 163494.71 146765.12 10.27 29.17 1.06 4.96 9.31 0.00 834.99 0.08 24.66 24.74 722.21 1181.88 383.45 28.02 113.87 121.73 161880.21 145259.16 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 1.10 Exhaust Temp F 721.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 1.09 1.04 1.07 720.00 731.00 728.00 1.02 1.10 1.03 729.00 721.00 727.00 1.06 1.00 0.99 725.00 729.00 730.00 1.03 726.00 1.05 0.98 1.05 721.00 719.00 726.00 1.04 1.03 1.04 721.00 723.00 724.81 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 1.04 Exhaust Temp F 712.00 1.02 1.04 1.04 722.00 721.00 718.00 1.19 1.14 1.09 712.00 718.00 712.00 1.10 1.03 1.02 718.00 712.00 714.00 1.03 710.00 1.05 1.11 1.14 712.00 714.00 717.00 1.10 1.08 715.00 711.00 714.881.08 Run 2 Δpstd (in) H2O 1.09 Exhaust Temp F 723.00 1.09 1.09 0.98 729.00 733.00 731.00 1.09 1.21 1.03 730.00 727.00 728.00 1.02 1.12 1.08 721.00 728.00 723.00 1.01 728.00 1.03 1.03 1.04 722.00 731.00 733.00 1.12 1.03 723.00 721.00 1.07 726.94 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.05)+.32(.107)+.28(.843+0) = 29.168 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.168(1 -.10294)+.18.0(.10294) = 28.019 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√1.04*√(1184.4825/(24.74*28.019)) = 112.96 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.103)112.963*1.069((528*24.74)/ (1184.4825*29.92)) = 143739.1 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 143739.095/35.315 = 4070.199 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 0*(20.9-15)/(20.9-10.7%)) = 0 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (0*(1.164*10^-3)*4070.199*(Run Time/60))/936.621 = 0 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = 0*1/453.6*936.621 = 0 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = 0*4.38 = 0 TPYTPY = LB/HR. *4.38 Horsepower 937= 1340 - ((69.7-55) / ((69.7-57.3) / 25%))) * 1340)BHP/HR = Available HP - ((MFP @100% - Actual MFP inHG) / ((MFP @100% - MFP @75%) / 25%))) * Available HP Wet to Dry PPM 0 = 0*(1/(1-.1))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.58% 21.10% 10.42% 10.30% 10.61% 10.61% 10.30%10.42% 10.58% 21.10% 10.61% 21.01% 10.61% 21.01% 10.61%21.01% 0.00% 10.61% 21.01% 0.03% 0.09% 0.14% 0.44% 10.61% Span Zero Offset 0.00% 21.01 0.00% 10.58%0.75%1.32%0.01% 10.45% 10.31% 10.35% 10.70% 10.56% 10.60% 9 Gas, Inc. 840.0 850.0 846.7 20.0 20.0 20.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Pleasant Valley Compressor Station 8/7/2024 5419 4 Caterpillar Model Serial Number G3516 TALE WPW02396 Technician Logan Miller Run Start Times 04:11 PM 05:24 PM 06:36 PM 08:11 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1400.0 1399.0 1400.0 1399.7 Engine Hours 30375 30376 30377 30378 Intake Manifold Pressure (psi)26.9 27.0 27.0 27.0 Intake Manifold Temp °F 140.0 143.0 143.0 142.0 Engine Load (BHP)936.6 941.4 942.1 940.1 Ambient Temp °F 95.0 96.0 96.0 95.7 Humidity %19.0 17.0 17.0 17.7 Dew Point °F 46.0 46.0 46.0 46.0 Caterpillar YesCatalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 20.0 850.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.05 R e s u l t s Average:Nitrogen monoxide NO 0.14 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.14 Average:VOC 0.03 Average:Oxygen 0.00 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 101.29 Tolerance 2.00% Difference between measured and expected 1.66% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.10 Average:Nitrogen monoxide NO 0.10 Average:Nitrogen dioxide NO2 0.19 Average:NOx 0.29 Average:VOC 0.34 Average:Oxygen 0.00 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 101.31 Tolerance 5.00% Difference between measured and expected 1.65% Pre-test System CTS & Mechanical Response Time 51 secondsEquilibration Response Time Value:Spike Reported 250.46 Value:Spike Expected 254.10 System (Equilibration) Response Time Target (Spike) 73 secondsSystem Zero Response Time 73 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC517327 4/29/2027 99.84 10.61% CC190334 4/24/2032 103.00 ALM-062642 12/14/2031 21.01% Cylinder # CC403040& Expiration: 7-13-2031 Propane CO NO SF6 Bottle Value 254.10 507.00 253.30 10.10 Analyzer System Response 250.46 501.26 248.24 10.07 Percent Difference 1.43%1.13%2.00%0.29% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 101.287 4.917 Spike Direct Propane 252.748 Mechanical Response Time SF6 10.139 CO 504.924 NO 251.283 Ethylene 101.305 40 seconds Analyzer Response Propane 250.461 SF6 10.071 CO 501.256 NO 248.244 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 252.142 CO 502.864 NO 250.370 51 seconds 73 seconds 8.87% 8.90% 8.98% 99.08% 99.81% 97.98% 10.089 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.338 50%7.000 83.3%11.662 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 14 230 53 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 145259.16 H2O%d @ Sampling Point:10.27 CO2%d @ Sampling Point:4.96 Pressure @ Sampling Point (Pg "H2O):1.06 Temperature @ Sampling Point (Deg F):722.21 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 103 101.29 4.917 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 101.287 4.917 Spike Direct Propane 252.748 Mechanical Response Time SF6 10.139 CO 504.924 NO 251.283 Ethylene 101.305 40 seconds Analyzer Response Propane 250.461 SF6 10.071 CO 501.256 NO 248.244 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 252.142 CO 502.864 NO 250.370 51 seconds 73 seconds 8.87% 8.90% 8.98% 99.08% 99.81% 97.98% 10.089 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 254.100 10.100 507.000 253.300 252.748 10.139 504.924 251.283 0.53% 0.39% 0.41% 0.80% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 18.534 0.000 Spike Average 39.068 0.899 Dilution Factor 8.867% Expected 39.429 % Recovery 99.080% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.902 Dilution Factor 8.896% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.910 Dilution Factor 8.975% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 19.594 39.830 40.653 97.980% 0.000323 0.000248 0.000191 19.411 40.220 40.298 99.810% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass0.34% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:42.1627746 Pass Line Position Difference:Resolution Difference to Reference 0.34% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 103.00 105.26 2.15% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Pleasant Valley Compressor Station; 4; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/7/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/7/2024 Logan Miller Gas, Inc. Appendices Gas, Inc. Gas, Inc. CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number:E05NI94E15AC014 Reference Number:54-402783135-1 Cylinder Number:CC403040&Cylinder Volume:147.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:CO,CO2,NO,NOX,PPN,BALN Certification Date:Jul 13, 2023 Expiration Date:Jul 13, 2031 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates NOX 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 NITRIC OXIDE 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 PROPANE 250.0 PPM 254.1 PPM G1 +/- 0.9% NIST Traceable 07/11/2023 CARBON MONOXIDE 500.0 PPM 507.0 PPM G1 +/- 0.6% NIST Traceable 07/11/2023 CARBON DIOXIDE 5.000 %5.083 %G1 +/- 0.7% NIST Traceable 07/11/2023 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 200603-02 EB0112877 250.3 PPM NITRIC OXIDE/NITROGEN +/- 0.8%Oct 19, 2026 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR +/- 1.5%Feb 18, 2023 GMIS 1534012021105 ND73033 5.012 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.6%Jun 15, 2025 NTRM 200602-13 6162697Y 243.3 PPM PROPANE/AIR +/- 0.5%Mar 17, 2027 NTRM 150605-41 CC453947 491.9 PPM CARBON MONOXIDE/NITROGEN +/- 0.6%Mar 05, 2027 NTRM 13060423 CC413685 7.489 % CARBON DIOXIDE/NITROGEN +/- 0.6%May 14, 2025 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2010242 FTIR Jun 08, 2023 CO-1 SIEMENS ULTRAMAT 6E N1J5700 NDIR Jun 26, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2110277 FTIR Jul 07, 2023 Triad Data Available Upon Request PERMANENT NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc.      ,          '5781(+5 !+,+5+2)+81(+5    ;0/2*+52'0;<+*#%  ;0/2*+5$3081+   '(35'735;"#806''67/00" ;0/2*+5 5+6685+   " 2'0;6/6'7++(  $'09+870+7 3781(+5          Component Requested Certified Purity Concentration NITROGEN 99.999 %99.999 % OXYGEN <1 PPM 0.94 PPM WATER <1 PPM 0.058 PPM TOTAL HYDROCARBONS <0.1 PPM 0.1 PPM CARBON DIOXIDE <0.5 PPM 0.235 PPM CARBON MONOXIDE <0.5 PPM 0.235 PPM !##" #./6)+57/2)08*+69'08+6,5317.+,/006/*+'2*/62375+45+6+27'7/9+3,7.+86+6/*+485/7;327')7'2/5-'6 "'0+6!+45+6+27'7/9+,357./6/2,351'7/32 &!"#   &#%  #%   #% #%  #%  #% #%  #%    #%  #%   #%   #%  #%  #%  #%  #%  #%   #%   #%   1485/7/+69+5/,/+*'-'/267'2'0;7/)'067'2*'5*675')+'(0+73"#(;:+/-.7'2*35'2'0;6/6 #$! !%!"    Gas, Inc. 21% O2 Tri Probe Certification ” ‡ ƒ – Ž ƒ ‹ • • • ƒ Ž › – ‹ … ƒ Ž ‡ ” ˜ ‹ … ‡ • ͵Ͳ͵͵”†–Ž‹–›ǡǡ͹͵͸ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ ƒšǣȋͷͺͲȌʹʹͷǦʹ͸ͳʹ &(57,),&$7(2)$1$/<6,6 *UDGHRI3URGXFW&(57,),('67$1'$5'352%( 3DUW1XPEHU65HIHUHQFH 1XPEHU  /DERUDWRU\*$6,1&6WDFN'LDPHWHU $QDO\VLV'DWH7DUJHW)ORZ 5DWH /PLQ /271XPEHU 61 $ $6 1XPEHURI 3RLQWV  3URGXFWSHUIRUPDQFHYHULILHGE\GLUHFWFRPSDULVRQWRFDOLEUDWLRQVWDQGDUGVWUDFHDEOHWR1,67  7KHSUREHOLVWHGRQWKLVIRUPPHHWVWKHPXOWLSRLQWWUDYHUVHUHTXLUHPHQWRI(3$0HWKRGH VHFWLRQDVVKRZQLQWKHDFFRPSDQ\LQJGDWD0HWKRGHVHFWLRQVWDWHVWKDWWKHPXOWLSRLQW WUDYHUVHUHTXLUHPHQWFDQEHVDWLVILHGE\VDPSOLQJYLD³DPXOWLKROHSUREHGHVLJQHGWRVDPSOHDW WKHSUHVFULEHGSRLQWVZLWKDIORZSHUFHQWRIPHDQIORZUDWH´ $1$/<7,&$/5(68/76 ZƵŶηdŽƚĂů&ůŽǁ ;>ͬŵͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϭͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϮͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϯͿ 0HDQ3UREH 3RUW6DPSOHG )ORZ /P  5XQ/30  䧮    䧮    䧮   5XQ/30  䧮    䧮    䧮    &DOLEUDWLRQFRQGXFWHGLQDFFRUGDQFHZLWK(PLVVLRQ0HDVXUHPHQW&HQWHU*XLGHOLQH'RFXPHQW±(0&*' 1RWHV BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB $SSURYHGIRU5HOHDVH'DWH 3/23/2022 Probe size: 14S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Logan Miller GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Pleasant Valley Compressor Station Unit Number:4 Make:Caterpillar Location:G3516 TALEModel: WPW02396Serial Number: RAW Result Data Stability 8/7/2024 06:31 0.0000.4950.007 0.000 0.4170.025 0.000 0.000 0.5280.0280.119 0.000 0.0000.000 0.000 848.00.660.997 0.000 0.49 0.00 180.0 Pre Test Baseline Direct 8/7/2024 06:45 0.0000.0000.001 0.003 0.1270.044 0.007 0.000 0.0600.0010.104 0.000 0.0020.129 0.000 845.00.000.000 0.000 0.00 0.00 180.0 8/7/2024 06:45 0.0000.291-0.001 0.000 0.0000.076 0.021 0.084 0.0270.1390.070 0.000 0.0250.088 0.024 845.00.070.000 0.000 0.29 0.00 180.0 8/7/2024 06:46 0.0000.134-0.001 0.000 0.4610.042 0.006 0.039 0.0490.0410.143 0.000 0.0150.000 0.007 845.00.030.000 0.002 0.13 0.00 180.0 CTS Direct 8/7/2024 07:51 0.0000.9280.015 0.014 0.0000.188 0.032 0.000 0.0570.0000.000 101.334 0.0000.119 0.071 839.067.700.000 0.000 0.93 0.00 180.0 8/7/2024 07:52 0.2660.7110.011 0.010 0.0000.179 0.015 0.000 0.1940.0000.000 101.296 0.1300.000 0.050 839.067.760.000 0.000 0.98 0.00 180.0 8/7/2024 07:52 0.9130.4160.011 0.008 0.0000.134 0.020 0.000 0.2370.1220.000 101.230 0.0000.000 0.022 839.067.530.000 0.000 1.33 0.00 180.0 High O2 Direct 8/7/2024 08:00 0.0000.0000.002 0.001 0.1040.161 0.004 0.031 0.0400.0280.000 0.000 0.0010.000 0.017 839.00.040.000 0.000 0.00 21.29 180.0 8/7/2024 08:01 0.4680.000-0.002 0.001 0.0260.178 0.021 0.004 0.0080.0000.000 0.000 0.0000.000 0.000 839.00.000.000 0.000 0.47 20.97 180.0 8/7/2024 08:01 0.2250.000-0.007 0.002 0.3830.000 0.002 0.072 0.1410.1640.000 0.000 0.0000.027 0.025 839.00.050.000 0.000 0.22 21.05 180.0 NO2/Mid O2 Direct 8/7/2024 08:09 99.7210.000-0.006 0.000 2.0720.000 0.772 0.000 2.0380.0600.194 0.000 0.0000.000 0.000 839.00.000.000 0.000 99.72 10.63 180.0 8/7/2024 08:09 100.2800.113-0.005 0.000 2.4140.000 0.774 0.000 1.3310.0000.346 0.000 0.0000.003 0.000 839.00.000.000 0.000 100.39 10.53 180.0 8/7/2024 08:10 101.3860.000-0.009 0.000 2.1120.000 0.775 0.000 1.5900.0000.635 0.000 0.0000.000 0.000 839.00.040.062 0.000 101.39 10.58 180.0 Spike Direct 8/7/2024 08:14 0.000251.1820.002 4.842 2.861504.597 1.162 2.116 9.5050.1250.018 1.080 252.8200.000 0.000 839.0255.663.187 10.136 251.18 0.00 180.0 8/7/2024 08:15 0.000251.166-0.004 4.843 2.748505.307 1.167 2.107 9.8200.0390.000 1.051 252.6940.148 0.000 839.0255.603.310 10.143 251.17 0.00 180.0 8/7/2024 08:16 0.000251.501-0.000 4.836 1.793504.869 1.179 1.936 9.5070.3910.435 1.070 252.7290.096 0.000 839.0255.513.105 10.138 251.50 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/7/2024 08:19 0.4500.0990.016 0.006 0.1070.134 0.000 1.647 0.3250.0000.000 0.014 0.1430.000 0.000 839.00.570.622 0.000 0.55 0.00 180.0 8/7/2024 08:19 0.1150.2120.013 0.007 0.5580.108 0.000 1.457 0.4530.0000.000 0.105 0.0000.000 0.001 839.00.270.300 0.002 0.33 0.00 180.0 8/7/2024 08:19 0.0000.0000.007 0.003 0.1670.071 0.000 1.389 0.2660.0050.000 0.000 0.0860.117 0.000 839.00.190.163 0.000 0.00 0.00 180.0 CTS System with Response Time 8/7/2024 08:21 0.2050.0000.027 0.010 0.0000.156 0.000 1.219 0.5270.0000.000 101.341 0.0570.243 0.044 839.068.020.459 0.000 0.21 0.00 180.0 8/7/2024 08:21 0.2040.0000.030 0.014 0.0000.232 0.000 1.169 0.0660.0000.000 101.399 0.0030.000 0.062 839.067.990.397 0.000 0.20 0.00 180.0 8/7/2024 08:22 0.1530.0000.026 0.011 0.0000.165 0.000 1.157 0.0640.0000.000 101.175 0.0000.188 0.067 839.067.810.336 0.000 0.15 0.00 180.0 NO2/Mid O2 System with Response Time 8/7/2024 08:26 102.2950.9640.009 0.001 1.8130.156 0.800 0.469 0.7970.0030.000 0.000 0.0000.544 0.018 839.00.761.091 0.000 103.26 10.41 180.0 8/7/2024 08:26 101.1120.7050.007 0.000 2.4950.147 0.811 0.496 0.9160.0000.000 0.000 0.0000.465 0.000 839.00.520.786 0.000 101.82 10.41 180.0 8/7/2024 08:26 101.8881.077-0.000 0.000 2.1080.000 0.784 0.568 0.7340.0000.000 0.000 0.0000.584 0.000 839.00.340.507 0.000 102.96 10.45 180.0 Spike System with Response Time 8/7/2024 08:28 0.000248.0070.010 4.782 2.961500.962 1.175 2.606 11.0610.0590.786 1.243 249.6760.000 0.000 839.0252.432.894 10.061 248.01 0.00 180.0 8/7/2024 08:28 0.000248.3810.014 4.810 3.217501.313 1.176 2.721 11.2300.0200.467 1.197 250.1090.000 0.000 839.0253.013.148 10.073 248.38 0.00 180.0 8/7/2024 08:29 0.000248.3450.005 4.826 2.220501.492 1.148 2.637 9.5470.0340.857 1.216 251.5980.085 0.000 839.0254.683.409 10.078 248.34 0.00 180.0 Baseline System with Response Time 8/7/2024 08:31 0.0000.4190.001 0.010 0.2300.293 0.000 0.655 0.2010.0050.000 0.066 0.3300.236 0.000 839.00.620.376 0.008 0.42 0.00 180.0 8/7/2024 08:32 0.0540.4400.009 0.013 0.7000.418 0.000 0.645 0.2810.0000.000 0.000 0.1980.085 0.000 839.00.540.511 0.004 0.49 0.00 180.0 8/7/2024 08:32 0.0000.0000.005 0.003 0.2000.340 0.000 0.746 0.2060.0000.000 0.000 0.1650.430 0.000 839.00.430.397 0.005 0.00 0.00 180.0 Run 1 - A 30minute/60min 8/7/2024 16:11 13.86169.00310.415 5.026 773.2320.000 0.000 0.456 50.1020.0008.317 0.627 18.0300.060 1.541 835.023.202.509 0.000 82.86 9.27 180.0 8/7/2024 16:12 14.73470.88010.393 5.035 773.4500.000 0.000 0.327 49.8670.0008.081 0.602 17.8770.000 1.499 835.022.932.475 0.000 85.61 9.26 180.0 8/7/2024 16:13 14.48869.16610.351 5.028 773.0070.000 0.000 0.326 49.9160.0008.035 0.696 18.0060.171 1.525 835.023.162.454 0.000 83.65 9.26 180.0 8/7/2024 16:14 14.74069.76610.337 5.037 773.2360.000 0.000 0.293 50.2900.0008.282 0.749 18.1450.046 1.485 835.023.212.398 0.000 84.51 9.30 180.0 8/7/2024 16:15 14.67769.10510.232 5.015 772.4890.000 0.000 0.309 50.2970.0007.926 0.675 18.2870.043 1.508 835.023.402.462 0.000 83.78 9.32 180.0 8/7/2024 16:16 14.34867.69510.251 5.011 774.2780.000 0.000 0.180 50.0830.0008.032 0.721 18.4320.047 1.495 835.023.632.585 0.000 82.04 9.37 180.0 8/7/2024 16:17 14.06368.68910.245 5.015 774.1270.000 0.000 0.227 49.8290.0007.926 0.679 18.0910.006 1.502 835.023.162.418 0.000 82.75 9.29 180.0 8/7/2024 16:19 15.34467.70610.299 5.017 774.2900.000 0.000 0.220 49.6290.0008.000 0.673 18.1670.059 1.530 835.023.292.419 0.000 83.05 9.36 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 16:20 14.68767.02610.290 5.010 776.0210.000 0.000 0.174 50.1080.0007.922 0.718 18.0610.018 1.504 835.023.142.389 0.000 81.71 9.29 180.0 8/7/2024 16:21 15.45468.26110.328 5.017 780.7670.000 0.000 0.137 50.5100.0007.927 0.765 18.0200.053 1.496 835.023.182.481 0.000 83.71 9.31 180.0 8/7/2024 16:22 15.00867.34410.350 5.018 778.4820.000 0.000 0.149 49.7500.0007.765 0.748 17.8970.014 1.542 835.023.122.454 0.000 82.35 9.32 180.0 8/7/2024 16:23 15.03367.03610.347 5.014 780.3690.000 0.000 0.100 50.4740.0008.063 0.703 18.0370.038 1.482 835.023.062.394 0.000 82.07 9.30 180.0 8/7/2024 16:24 14.72067.77110.360 4.999 778.5200.000 0.000 0.162 50.3650.0008.026 0.680 18.2450.000 1.462 835.023.222.397 0.000 82.49 9.29 180.0 8/7/2024 16:25 15.00666.93510.338 4.998 780.1100.000 0.000 0.182 50.8880.0007.810 0.764 18.4460.043 1.493 835.023.542.397 0.000 81.94 9.38 180.0 8/7/2024 16:26 13.07760.84610.302 4.983 779.8150.000 0.000 0.147 51.5470.0007.747 0.769 18.7290.010 1.533 835.023.922.424 0.000 73.92 9.34 180.0 8/7/2024 16:27 13.55860.33810.278 4.972 782.6470.000 0.000 0.135 52.4050.0007.875 0.741 18.9220.067 1.497 835.023.962.322 0.000 73.90 9.36 180.0 8/7/2024 16:28 13.56361.95210.333 4.992 785.0200.000 0.000 0.090 51.9890.0007.689 0.670 18.6900.000 1.485 835.023.652.312 0.000 75.51 9.32 180.0 8/7/2024 16:29 13.38660.48610.340 4.989 788.2380.000 0.000 0.072 52.7390.0007.865 0.700 18.7510.139 1.474 835.023.752.378 0.000 73.87 9.32 180.0 8/7/2024 16:30 12.87058.71610.311 4.977 788.0090.000 0.000 0.106 52.9620.0007.957 0.774 19.1540.000 1.602 835.024.432.327 0.000 71.59 9.32 180.0 8/7/2024 16:31 12.43558.34310.243 4.956 783.0750.000 0.000 0.124 51.8770.0007.999 0.663 19.5950.020 1.760 835.025.082.285 0.000 70.78 9.39 180.0 8/7/2024 16:32 12.59658.50210.205 4.938 782.8640.000 0.000 0.110 51.8360.0008.148 0.775 19.3520.074 1.684 835.024.822.374 0.000 71.10 9.43 180.0 8/7/2024 16:33 12.33557.96410.183 4.932 783.3760.000 0.000 0.098 51.7910.0007.877 0.763 18.8760.000 1.565 835.023.982.194 0.000 70.30 9.42 180.0 8/7/2024 16:34 13.00358.88310.172 4.927 786.8380.000 0.000 0.084 51.3740.0007.819 0.659 19.1710.077 1.656 835.024.512.380 0.000 71.89 9.40 180.0 8/7/2024 16:35 13.11257.49310.142 4.916 784.7970.000 0.000 0.090 51.6980.0007.954 0.662 19.1520.086 1.645 835.024.442.329 0.000 70.60 9.43 180.0 8/7/2024 16:36 12.76857.55010.159 4.915 784.2970.000 0.000 0.116 51.4260.0007.699 0.805 18.8580.023 1.464 835.023.932.417 0.000 70.32 9.45 180.0 8/7/2024 16:37 13.17658.89610.141 4.915 782.2750.000 0.000 0.074 50.9400.0007.656 0.733 18.8240.000 1.613 835.024.122.368 0.000 72.07 9.46 180.0 8/7/2024 16:38 13.11857.23010.177 4.928 786.4550.000 0.000 0.100 51.6260.0007.881 0.649 18.7290.080 1.463 835.023.592.251 0.000 70.35 9.45 180.0 8/7/2024 16:39 12.93157.56810.206 4.917 785.5330.000 0.000 0.111 51.7260.0007.828 0.736 18.6090.119 1.453 835.023.552.319 0.000 70.50 9.37 180.0 8/7/2024 16:40 14.10859.40010.277 4.948 784.0690.000 0.000 0.110 51.1400.0007.620 0.761 18.4700.000 1.502 835.023.472.226 0.000 73.51 9.36 180.0 8/7/2024 16:41 13.30359.90910.251 4.943 782.9120.000 0.000 0.046 50.7890.0007.897 0.807 18.4100.000 1.452 835.023.332.222 0.000 73.21 9.36 180.0 13.85063.34910.275 4.980 780.4200.000 0.000 0.162 50.9990.0007.921 0.716 18.5340.043 1.530 835.0023.6592.379 0.000 77.198 9.350 180.0Avg. Spike 1 8/7/2024 16:44 9.61472.0089.291 4.923 727.54446.161 0.000 0.688 42.8120.0007.947 3.036 39.0680.000 1.556 835.045.481.912 0.899 81.62 8.66 180.0 Run 1 - B 30minute/60min 8/7/2024 16:47 15.10562.36310.236 4.969 784.7620.000 0.000 0.162 51.5320.0007.819 0.775 18.7280.000 1.454 835.023.532.071 0.008 77.47 9.35 180.0 8/7/2024 16:48 14.72260.05410.225 4.956 787.9740.000 0.000 0.179 52.2270.0007.768 0.857 19.1150.060 1.495 835.024.162.220 0.000 74.78 9.36 180.0 8/7/2024 16:49 14.24059.11710.219 4.946 782.9660.000 0.000 0.085 52.1540.0008.005 0.719 19.1550.000 1.529 835.024.122.145 0.000 73.36 9.39 180.0 8/7/2024 16:50 13.79859.63710.192 4.942 776.1970.000 0.000 0.098 51.3730.0008.102 0.679 19.0120.017 1.521 835.023.872.044 0.000 73.44 9.42 180.0 8/7/2024 16:51 13.31658.97110.220 4.939 777.6600.000 0.000 0.087 51.4510.0008.207 0.770 19.0060.000 1.528 835.023.891.964 0.000 72.29 9.35 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 16:52 13.46459.74510.249 4.960 776.6180.000 0.000 0.011 51.1750.0007.981 0.702 18.9180.150 1.561 835.023.821.964 0.000 73.21 9.38 180.0 8/7/2024 16:54 14.10459.63810.268 4.952 780.5230.000 0.000 0.046 51.8440.0007.913 0.727 19.0230.000 1.498 835.023.831.983 0.000 73.74 9.40 180.0 8/7/2024 16:55 13.33758.75510.247 4.951 776.8380.000 0.000 0.078 51.5670.0008.041 0.700 19.0640.031 1.557 835.024.012.052 0.000 72.09 9.39 180.0 8/7/2024 16:56 14.24959.86410.288 4.963 778.4570.000 0.000 0.085 51.4420.0007.976 0.801 19.0230.000 1.518 835.023.861.895 0.000 74.11 9.38 180.0 8/7/2024 16:57 14.10360.51110.306 4.967 779.2710.000 0.000 0.056 51.8210.0007.998 0.628 18.9610.054 1.535 835.023.641.792 0.000 74.61 9.37 180.0 8/7/2024 16:58 13.78860.46410.314 4.975 777.7770.000 0.000 0.046 51.6290.0008.037 0.773 19.2750.042 1.525 835.024.081.861 0.000 74.25 9.35 180.0 8/7/2024 16:59 13.90660.07610.294 4.969 776.2020.000 0.000 0.070 51.6600.0008.019 0.807 19.1950.000 1.559 835.024.111.883 0.000 73.98 9.46 180.0 8/7/2024 17:00 14.05360.25610.269 4.970 777.1450.000 0.000 0.022 51.7960.0008.045 0.761 19.1970.085 1.524 835.023.981.841 0.000 74.31 9.44 180.0 8/7/2024 17:01 13.37558.39310.237 4.941 776.3810.000 0.000 0.099 51.7710.0007.913 0.787 19.2740.000 1.595 835.024.221.854 0.000 71.77 9.36 180.0 8/7/2024 17:02 13.78358.38010.210 4.936 775.6200.000 0.000 0.073 51.5640.0007.996 0.754 19.2930.000 1.557 835.024.121.821 0.000 72.16 9.44 180.0 8/7/2024 17:03 12.69658.10810.255 4.933 775.3270.000 0.000 0.047 51.7280.0008.237 0.771 19.1680.000 1.538 835.023.951.789 0.000 70.80 9.45 180.0 8/7/2024 17:04 13.43658.65710.237 4.911 771.9020.000 0.000 0.069 51.0670.0008.116 0.817 18.8870.000 1.570 835.023.741.750 0.000 72.09 9.43 180.0 8/7/2024 17:05 13.74258.27010.295 4.932 772.0780.000 0.000 0.000 51.0860.0008.369 0.794 19.1630.000 1.573 835.024.021.780 0.000 72.01 9.39 180.0 8/7/2024 17:06 13.09958.84410.267 4.905 768.8630.000 0.000 0.015 50.8240.0008.091 0.852 19.1140.000 1.561 835.023.951.714 0.000 71.94 9.53 180.0 8/7/2024 17:07 13.27957.83710.314 4.908 768.3640.000 0.000 0.017 50.8800.0008.147 0.702 19.1610.000 1.548 835.023.921.792 0.000 71.12 9.41 180.0 8/7/2024 17:08 13.26058.07010.364 4.909 768.5040.000 0.000 0.047 50.4500.0007.864 0.770 19.0910.000 1.569 835.023.951.811 0.000 71.33 9.38 180.0 8/7/2024 17:09 13.58758.59610.409 4.914 767.6170.000 0.000 0.056 50.2560.0007.980 0.794 18.9400.000 1.543 835.023.721.743 0.000 72.18 9.45 180.0 8/7/2024 17:10 13.33057.74810.416 4.917 768.8990.000 0.000 0.000 50.8170.0008.183 0.728 18.9920.038 1.581 835.023.831.787 0.000 71.08 9.39 180.0 8/7/2024 17:11 13.39558.53110.432 4.919 768.9430.000 0.000 0.015 50.6480.0008.159 0.801 18.8520.000 1.549 835.023.641.730 0.000 71.93 9.34 180.0 8/7/2024 17:12 12.94358.64010.395 4.900 765.7840.000 0.000 0.064 50.2460.0008.162 0.783 18.9440.022 1.567 835.023.801.802 0.000 71.58 9.42 180.0 8/7/2024 17:13 13.49559.29810.448 4.913 768.0360.000 0.000 0.018 50.1860.0008.190 0.819 18.8630.000 1.545 835.023.701.801 0.000 72.79 9.43 180.0 8/7/2024 17:14 12.84358.49710.411 4.892 762.6630.000 0.000 0.061 49.8780.0008.175 0.777 18.9090.054 1.563 835.023.791.849 0.000 71.34 9.45 180.0 8/7/2024 17:15 13.66059.39610.438 4.927 764.2200.000 0.000 0.031 49.6460.0008.114 0.721 18.9620.000 1.556 835.023.691.711 0.000 73.06 9.32 180.0 8/7/2024 17:16 13.22758.87810.459 4.922 766.6550.000 0.000 0.044 50.3740.0008.218 0.731 19.0890.000 1.545 835.023.811.711 0.000 72.10 9.49 180.0 8/7/2024 17:17 13.65259.33410.432 4.930 767.0360.000 0.000 0.071 50.5280.0008.179 0.851 18.9010.000 1.584 835.023.721.622 0.000 72.99 9.40 180.0 13.63359.16410.312 4.936 773.6430.000 0.000 0.058 51.1210.0008.067 0.765 19.0430.018 1.545 835.0023.8821.859 0.000 72.797 9.404 180.0Avg. 13.74161.25610.293 4.958 777.0310.000 0.000 0.110 51.0600.0007.994 0.740 18.7880.031 1.538 835.0023.7712.119 0.000 74.998 9.377 180.0Run 1 Avg: Baseline 1 8/7/2024 17:22 0.4950.0000.005 0.006 0.0000.134 0.028 0.058 0.0000.0000.000 0.000 0.0450.089 0.025 835.00.100.000 0.000 0.50 0.00 180.0 Run 2 - A 30minute/60min 8/7/2024 17:25 13.61859.24410.550 4.944 767.1870.000 0.000 0.163 50.9570.0008.347 0.771 19.1200.000 1.612 835.023.971.663 0.000 72.86 8.58 180.0 8/7/2024 17:26 14.67160.48110.564 4.970 768.7310.000 0.000 0.177 50.8160.0008.270 0.895 19.0370.065 1.567 835.023.911.708 0.000 75.15 8.77 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 17:27 14.06759.49010.511 4.952 770.9990.000 0.000 0.111 51.1190.0008.299 0.830 19.1310.000 1.570 835.023.931.667 0.000 73.56 8.95 180.0 8/7/2024 17:29 13.92658.27710.483 4.937 768.4530.000 0.000 0.100 50.9540.0007.892 0.797 19.2080.032 1.577 835.024.091.789 0.000 72.20 9.02 180.0 8/7/2024 17:30 14.13058.58210.476 4.945 769.0400.000 0.000 0.112 50.8980.0008.183 0.796 19.1350.037 1.587 835.023.951.667 0.000 72.71 9.06 180.0 8/7/2024 17:31 13.52159.53310.442 4.941 771.4210.000 0.000 0.134 51.3630.0008.357 0.788 19.2170.059 1.526 835.024.011.827 0.000 73.05 9.10 180.0 8/7/2024 17:32 13.18159.90510.435 4.948 770.8920.000 0.000 0.078 51.4620.0008.121 0.782 19.1590.000 1.552 835.024.001.820 0.000 73.09 9.16 180.0 8/7/2024 17:33 13.64459.79110.444 4.944 767.2830.000 0.000 0.102 51.0470.0008.111 0.831 19.2160.000 1.557 835.024.041.729 0.000 73.43 9.15 180.0 8/7/2024 17:34 13.91860.83710.515 4.984 769.9440.000 0.000 0.083 51.2470.0008.098 0.776 19.1370.000 1.571 835.024.011.814 0.000 74.76 9.14 180.0 8/7/2024 17:35 14.65061.02910.501 4.980 771.5370.000 0.000 0.065 51.4450.0008.195 0.772 19.1760.000 1.575 835.024.031.778 0.000 75.68 9.19 180.0 8/7/2024 17:36 13.39559.76210.399 4.948 770.6790.000 0.000 0.063 51.3510.0008.159 0.788 19.4480.000 1.532 835.024.261.827 0.000 73.16 9.20 180.0 8/7/2024 17:37 13.30958.39010.436 4.954 774.8150.000 0.000 0.076 52.2000.0008.140 0.806 19.5850.000 1.583 835.024.491.805 0.000 71.70 9.21 180.0 8/7/2024 17:38 13.89458.70610.449 4.953 772.9640.000 0.000 0.102 51.5210.0008.319 0.716 19.3410.080 1.545 835.024.111.798 0.000 72.60 9.24 180.0 8/7/2024 17:39 14.04758.79210.358 4.944 769.1840.000 0.000 0.047 51.3270.0008.026 0.818 19.3360.005 1.535 835.024.161.811 0.000 72.84 9.32 180.0 8/7/2024 17:40 14.03959.40210.326 4.936 767.7240.000 0.000 0.059 51.1170.0008.078 0.775 19.3110.000 1.564 835.024.161.808 0.000 73.44 9.32 180.0 8/7/2024 17:41 14.16860.50810.289 4.947 768.3380.000 0.000 0.016 50.8970.0008.113 0.754 19.3630.000 1.582 835.024.191.740 0.000 74.68 9.31 180.0 8/7/2024 17:42 14.23760.92010.300 4.943 770.6330.000 0.000 0.158 51.3690.0008.244 0.846 19.3280.000 1.575 835.024.271.840 0.000 75.16 9.31 180.0 8/7/2024 17:43 13.83959.71910.293 4.943 770.5510.000 0.000 0.091 51.2500.0008.126 0.778 19.4940.050 1.597 835.024.411.811 0.000 73.56 9.28 180.0 8/7/2024 17:44 14.18759.82410.300 4.965 769.6280.000 0.000 0.051 51.2940.0008.186 0.771 19.4300.124 1.557 835.024.121.600 0.000 74.01 9.23 180.0 8/7/2024 17:45 14.47060.14310.276 4.966 771.4460.000 0.000 0.028 51.0050.0008.308 0.845 19.4780.059 1.605 835.024.441.779 0.000 74.61 9.35 180.0 8/7/2024 17:46 14.14460.94110.239 4.970 773.2520.000 0.000 0.012 51.2520.0008.132 0.771 19.4630.000 1.542 835.024.241.768 0.000 75.09 9.29 180.0 8/7/2024 17:47 13.98459.73410.243 4.966 775.2830.000 0.000 0.061 51.9640.0007.984 0.779 19.5320.031 1.551 835.024.411.886 0.000 73.72 9.28 180.0 8/7/2024 17:48 14.83559.82310.281 4.990 777.9150.000 0.000 0.106 52.4660.0008.044 0.725 19.5920.096 1.528 835.024.311.764 0.000 74.66 9.28 180.0 8/7/2024 17:49 14.86861.43810.271 5.004 777.3310.000 0.000 0.076 52.2090.0008.003 0.763 19.5100.051 1.515 835.024.231.777 0.000 76.31 9.27 180.0 8/7/2024 17:50 14.40659.71510.234 5.008 778.2360.000 0.000 0.029 52.6970.0007.856 0.801 19.7090.000 1.556 835.024.571.824 0.000 74.12 9.31 180.0 8/7/2024 17:51 15.10160.77810.288 5.033 776.8240.000 0.000 0.024 52.5340.0008.229 0.744 19.6370.000 1.587 835.024.441.695 0.000 75.88 9.23 180.0 8/7/2024 17:52 15.23960.23510.310 5.026 780.4630.000 0.000 0.050 53.0220.0008.325 0.857 19.8780.000 1.574 835.024.761.746 0.000 75.47 9.24 180.0 8/7/2024 17:53 15.10760.34510.268 5.008 777.0270.000 0.000 0.052 52.1970.0008.113 0.831 19.7160.000 1.608 835.024.551.598 0.000 75.45 9.36 180.0 8/7/2024 17:54 14.92060.41910.253 5.022 781.2530.000 0.000 0.021 53.3770.0008.249 0.728 19.8180.000 1.561 835.024.561.698 0.000 75.34 9.29 180.0 8/7/2024 17:55 15.60660.26110.238 5.018 782.4330.000 0.000 0.047 53.2930.0008.325 0.861 19.8100.030 1.578 835.024.701.742 0.000 75.87 9.28 180.0 14.23759.90110.366 4.970 772.7160.000 0.000 0.076 51.6550.0008.161 0.793 19.4110.024 1.566 835.0024.2441.759 0.000 74.139 9.191 180.0Avg. Spike 2 8/7/2024 17:58 10.60273.3829.324 4.973 717.47545.883 0.000 0.565 43.6670.0008.494 3.063 40.2200.000 1.682 835.046.411.183 0.902 83.98 8.64 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/7/2024 18:00 15.98362.35310.289 5.035 775.3340.000 0.000 0.174 52.4180.0008.270 0.834 19.9150.000 1.585 835.024.751.662 0.003 78.34 9.20 180.0 8/7/2024 18:01 14.28459.61910.318 5.018 776.6120.000 0.000 0.175 53.1410.0008.565 0.908 20.1000.040 1.613 835.024.921.478 0.000 73.90 9.20 180.0 8/7/2024 18:03 14.42059.39910.277 5.002 773.7880.000 0.000 0.088 52.4370.0008.538 0.753 19.9870.000 1.625 835.024.871.689 0.000 73.82 9.22 180.0 8/7/2024 18:04 15.04460.24810.255 5.003 773.2520.000 0.000 0.053 52.2440.0008.192 0.806 19.7940.000 1.610 835.024.581.549 0.000 75.29 9.28 180.0 8/7/2024 18:05 14.59459.47210.201 4.966 770.5420.000 0.000 0.083 51.6670.0008.251 0.796 19.8050.000 1.637 835.024.721.669 0.000 74.07 9.35 180.0 8/7/2024 18:06 14.69260.70810.172 4.962 768.9420.000 0.000 0.137 51.4960.0008.168 0.692 19.5640.000 1.598 835.024.271.566 0.001 75.40 9.39 180.0 8/7/2024 18:07 14.34760.60410.142 4.951 765.4330.000 0.000 0.100 51.1750.0008.394 0.800 19.7780.000 1.618 835.024.541.486 0.000 74.95 9.34 180.0 8/7/2024 18:08 14.56760.60610.111 4.945 764.2520.000 0.000 0.085 50.8980.0008.159 0.857 19.8760.004 1.629 835.024.831.689 0.000 75.17 9.42 180.0 8/7/2024 18:09 14.71060.90010.087 4.934 764.8640.000 0.000 0.081 50.8200.0008.329 0.756 19.8860.000 1.633 835.024.701.562 0.000 75.61 9.39 180.0 8/7/2024 18:10 14.86060.46410.100 4.947 766.5210.000 0.000 0.085 51.2450.0008.123 0.783 19.7620.005 1.637 835.024.661.648 0.000 75.32 9.43 180.0 8/7/2024 18:11 14.12059.82410.051 4.922 765.5590.000 0.000 0.073 51.1090.0008.042 0.807 19.8560.000 1.627 835.024.691.560 0.000 73.94 9.39 180.0 8/7/2024 18:12 13.72857.53610.012 4.889 765.5470.000 0.000 0.120 51.1560.0008.286 0.824 19.9240.000 1.630 835.024.761.539 0.000 71.26 9.41 180.0 8/7/2024 18:13 14.19158.42710.044 4.924 766.8270.000 0.000 0.080 51.4010.0008.058 0.762 19.7360.069 1.631 835.024.621.665 0.000 72.62 9.41 180.0 8/7/2024 18:14 14.33959.31210.075 4.924 768.9960.000 0.000 0.058 51.5190.0008.233 0.743 19.6450.090 1.630 835.024.461.590 0.000 73.65 9.38 180.0 8/7/2024 18:15 13.94858.83610.087 4.931 771.0650.000 0.000 0.130 51.7660.0007.875 0.787 19.7690.090 1.621 835.024.621.628 0.000 72.78 9.41 180.0 8/7/2024 18:16 14.00159.80010.057 4.928 766.8810.000 0.000 0.118 51.3880.0008.154 0.740 19.6780.000 1.572 835.024.401.627 0.000 73.80 9.42 180.0 8/7/2024 18:17 14.47459.02210.071 4.933 767.0060.000 0.000 0.078 51.3460.0008.146 0.871 19.7950.000 1.592 835.024.681.673 0.000 73.50 9.36 180.0 8/7/2024 18:18 14.58161.10810.102 4.950 768.2750.000 0.000 0.077 51.0800.0008.385 0.823 19.5570.000 1.611 835.024.411.619 0.000 75.69 9.34 180.0 8/7/2024 18:19 15.32159.66410.219 4.981 778.2050.000 0.000 0.070 52.7430.0008.130 0.898 20.1650.097 1.597 835.025.021.592 0.000 74.99 9.26 180.0 8/7/2024 18:20 15.05058.69210.236 4.988 779.7810.000 0.000 0.071 52.9910.0008.247 0.841 20.2100.000 1.596 835.025.041.619 0.000 73.74 9.40 180.0 8/7/2024 18:21 14.89859.42810.253 4.998 776.1570.000 0.000 0.022 52.1730.0008.148 0.887 19.8500.000 1.612 835.024.811.711 0.000 74.33 9.28 180.0 8/7/2024 18:22 14.73859.18310.253 4.995 777.3940.000 0.000 0.111 52.5020.0008.282 0.834 19.8460.000 1.588 835.024.631.574 0.000 73.92 9.23 180.0 8/7/2024 18:23 14.84958.78710.244 4.976 778.9570.000 0.000 0.014 52.6750.0008.101 0.735 19.7590.000 1.597 835.024.521.620 0.000 73.64 9.24 180.0 8/7/2024 18:24 14.99659.67810.279 4.987 778.9220.000 0.000 0.102 52.8640.0008.444 0.808 19.8510.000 1.571 835.024.681.717 0.000 74.67 9.26 180.0 8/7/2024 18:25 15.59961.32210.309 5.024 778.2230.000 0.000 0.038 52.4920.0008.062 0.728 19.7820.000 1.585 835.024.551.676 0.000 76.92 9.22 180.0 8/7/2024 18:26 15.09160.63210.285 5.002 775.8560.000 0.000 0.064 52.1910.0008.101 0.882 19.7550.000 1.611 835.024.711.720 0.000 75.72 9.26 180.0 8/7/2024 18:27 14.55959.60810.271 4.989 774.8290.000 0.000 0.032 51.9090.0008.573 0.790 19.8270.017 1.607 835.024.651.618 0.000 74.17 9.25 180.0 8/7/2024 18:28 14.73760.42310.262 4.988 775.3470.000 0.000 0.050 51.6940.0008.258 0.743 19.6150.000 1.616 835.024.431.632 0.000 75.16 9.26 180.0 8/7/2024 18:29 14.90659.75810.282 5.004 777.4540.000 0.000 0.000 51.8720.0008.375 0.814 19.7330.020 1.595 835.024.571.651 0.000 74.66 9.20 180.0 8/7/2024 18:30 14.73160.25710.256 4.997 778.0910.000 0.000 0.019 51.8860.0008.397 0.835 19.4390.000 1.600 835.024.271.606 0.000 74.99 9.27 180.0 14.67959.85610.187 4.970 772.2970.000 0.000 0.080 51.8770.0008.243 0.805 19.8090.014 1.609 835.0024.6451.621 0.000 74.534 9.316 180.0Avg. 14.45859.87810.276 4.970 772.5060.000 0.000 0.078 51.7660.0008.202 0.799 19.6100.019 1.587 835.0024.4451.690 0.000 74.336 9.253 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/7/2024 18:33 0.9150.0430.014 0.016 0.4120.147 0.027 0.012 0.0770.0340.000 0.000 0.1580.178 0.061 835.00.280.000 0.000 0.96 0.00 180.0 Run 3 - A 30minute/60min 8/7/2024 18:36 14.47760.06610.233 4.978 777.2840.000 0.000 0.217 52.2070.0008.389 0.835 19.7510.000 1.627 835.024.641.616 0.000 74.54 8.33 180.0 8/7/2024 18:38 15.66860.04910.273 4.994 782.4670.000 0.000 0.181 53.1290.0008.302 0.877 19.8410.000 1.577 835.024.771.778 0.000 75.72 8.71 180.0 8/7/2024 18:39 14.86759.90010.244 4.995 779.9440.000 0.000 0.163 52.6350.0008.286 0.853 19.7090.149 1.577 835.024.571.711 0.000 74.77 8.98 180.0 8/7/2024 18:40 14.81659.76910.239 4.981 780.8030.000 0.000 0.139 52.7670.0008.291 0.770 19.7140.000 1.560 835.024.481.701 0.000 74.58 9.01 180.0 8/7/2024 18:41 15.26058.71510.247 4.972 781.3580.000 0.000 0.137 53.0350.0007.917 0.778 19.7030.005 1.561 835.024.431.635 0.000 73.97 9.07 180.0 8/7/2024 18:42 14.93259.79810.219 4.979 778.9370.000 0.000 0.109 52.3690.0008.014 0.764 19.6620.000 1.576 835.024.391.598 0.000 74.73 9.12 180.0 8/7/2024 18:43 15.15359.27710.168 4.962 776.2140.000 0.000 0.080 52.2210.0008.498 0.722 19.8320.000 1.599 835.024.531.528 0.000 74.43 9.20 180.0 8/7/2024 18:44 13.44358.18310.129 4.937 772.2340.000 0.000 0.106 51.7380.0008.246 0.845 19.8800.007 1.582 835.024.701.636 0.000 71.63 9.20 180.0 8/7/2024 18:45 14.69458.50310.151 4.949 770.3490.000 0.000 0.024 51.3150.0008.252 0.741 19.8040.199 1.609 835.024.621.661 0.000 73.20 9.21 180.0 8/7/2024 18:46 14.48758.69710.145 4.940 771.1130.000 0.000 0.140 51.3710.0008.281 0.943 19.6390.080 1.633 835.024.561.536 0.000 73.18 9.22 180.0 8/7/2024 18:47 14.63458.99310.163 4.947 771.6900.000 0.000 0.111 51.4370.0008.218 0.848 19.5570.000 1.611 835.024.411.596 0.000 73.63 9.25 180.0 8/7/2024 18:48 14.87159.20910.205 4.971 773.1250.000 0.000 0.093 51.4980.0008.297 0.903 19.4690.000 1.590 835.024.301.577 0.000 74.08 9.26 180.0 8/7/2024 18:49 15.20358.03510.198 4.963 774.4600.000 0.000 0.090 51.9530.0008.240 0.862 19.7360.000 1.587 835.024.441.430 0.000 73.24 9.22 180.0 8/7/2024 18:50 15.31460.64010.245 4.983 779.1300.000 0.000 0.031 52.3730.0008.235 0.851 19.5580.000 1.595 835.024.291.457 0.000 75.95 9.24 180.0 8/7/2024 18:51 15.05559.41010.253 4.992 776.9800.000 0.000 0.000 52.0450.0008.115 0.801 19.7550.000 1.584 835.024.411.436 0.000 74.46 9.22 180.0 8/7/2024 18:52 15.24859.62310.227 4.971 773.4300.000 0.000 0.072 51.5290.0008.452 0.759 19.6770.000 1.666 835.024.411.336 0.000 74.87 9.28 180.0 8/7/2024 18:53 14.73159.15210.223 4.975 775.3100.000 0.000 0.075 51.8070.0008.645 0.805 19.7470.000 1.617 835.024.441.378 0.000 73.88 9.30 180.0 8/7/2024 18:54 14.26358.09010.197 4.955 773.9460.000 0.000 0.036 51.5750.0008.264 0.745 19.6750.097 1.660 835.024.471.466 0.000 72.35 9.29 180.0 8/7/2024 18:55 14.01657.47110.218 4.956 775.6720.000 0.000 0.082 51.9570.0008.575 0.862 19.5600.000 1.646 835.024.281.288 0.000 71.49 9.30 180.0 8/7/2024 18:56 14.30757.45910.224 4.958 774.6430.000 0.000 0.042 51.7280.0008.335 0.814 19.5900.000 1.625 835.024.231.278 0.000 71.77 9.29 180.0 8/7/2024 18:57 14.52658.48010.200 4.952 775.0060.000 0.000 0.121 51.7530.0008.468 0.822 19.4790.059 1.594 835.024.091.317 0.000 73.01 9.31 180.0 8/7/2024 18:58 14.27958.15810.210 4.957 771.8190.000 0.000 0.000 51.3430.0008.495 0.835 19.4280.000 1.621 834.024.071.256 0.000 72.44 9.33 180.0 8/7/2024 18:59 14.35659.28710.193 4.952 773.6690.000 0.000 0.092 51.5790.0008.603 0.861 19.3350.000 1.633 835.024.041.290 0.000 73.64 9.33 180.0 8/7/2024 19:00 14.55158.08310.109 4.916 765.6550.000 0.000 0.028 50.3190.0008.693 0.878 19.4320.000 1.636 835.024.231.413 0.000 72.63 9.39 180.0 8/7/2024 19:01 14.54658.27210.119 4.929 764.8970.000 0.000 0.063 50.5630.0008.302 0.930 19.4010.113 1.624 835.024.171.346 0.000 72.82 9.37 180.0 8/7/2024 19:02 14.41457.44010.115 4.914 765.4070.000 0.000 0.071 50.7270.0008.466 0.863 19.4890.000 1.641 835.024.281.396 0.000 71.85 9.37 180.0 8/7/2024 19:03 14.62957.87210.135 4.923 763.8450.000 0.000 0.004 50.4650.0008.439 0.891 19.3680.050 1.648 835.024.181.390 0.000 72.50 9.36 180.0 8/7/2024 19:04 13.99057.11010.148 4.899 762.8790.000 0.000 0.097 50.2540.0008.727 0.924 19.3900.000 1.616 835.024.131.339 0.000 71.10 9.42 180.0 8/7/2024 19:05 13.53355.69010.140 4.881 761.9040.000 0.000 0.057 50.3360.0008.733 0.918 19.4140.000 1.623 835.024.201.397 0.000 69.22 9.43 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 19:06 13.46456.99410.123 4.880 762.2220.000 0.000 0.016 50.2360.0008.693 0.912 19.2300.062 1.601 835.024.021.462 0.000 70.46 9.45 180.0 14.59158.61410.190 4.952 772.8800.000 0.000 0.083 51.6090.0008.382 0.840 19.5940.027 1.611 834.9724.3591.475 0.000 73.205 9.215 180.0Avg. Spike 3 8/7/2024 19:09 10.07973.0679.270 4.882 704.90747.127 0.000 0.563 41.0680.0008.736 3.197 39.8300.029 1.757 835.046.371.335 0.910 83.15 8.70 180.0 Run 3 - B 30minute/60min 8/7/2024 19:13 14.21758.31510.175 4.917 764.0050.000 0.000 0.136 50.6110.0008.928 0.975 19.3860.000 1.637 835.024.301.485 0.001 72.53 9.40 180.0 8/7/2024 19:14 14.43857.87010.146 4.906 764.6980.000 0.000 0.107 50.5490.0008.842 0.947 19.5360.000 1.581 835.024.401.601 0.000 72.31 9.39 180.0 8/7/2024 19:15 13.52057.21010.119 4.903 763.3690.000 0.000 0.066 50.6400.0009.043 0.924 19.5060.000 1.600 835.024.311.481 0.000 70.73 9.35 180.0 8/7/2024 19:16 13.89657.81710.140 4.906 764.8820.000 0.000 0.046 50.9480.0008.740 0.819 19.6440.000 1.588 835.024.341.460 0.000 71.71 9.40 180.0 8/7/2024 19:17 13.77257.44710.175 4.911 763.8520.000 0.000 0.044 50.9640.0009.018 0.885 19.4740.000 1.571 835.024.301.638 0.001 71.22 9.42 180.0 8/7/2024 19:18 13.96157.97510.168 4.904 759.7550.000 0.000 0.046 50.0030.0008.947 0.829 19.3700.088 1.609 835.024.171.540 0.000 71.94 9.43 180.0 8/7/2024 19:19 14.28958.22410.203 4.910 764.2430.000 0.000 0.052 50.7200.0008.973 0.839 19.4540.000 1.604 835.024.231.515 0.000 72.51 9.43 180.0 8/7/2024 19:20 13.64257.13410.195 4.931 764.7400.000 0.000 0.029 50.6470.0009.115 0.945 19.4830.117 1.570 835.024.231.459 0.000 70.78 9.34 180.0 8/7/2024 19:21 13.76657.79010.212 4.914 764.6350.000 0.000 0.105 50.5970.0008.691 0.916 19.5020.000 1.604 835.024.321.497 0.000 71.56 9.40 180.0 8/7/2024 19:22 14.02457.69910.236 4.917 763.7290.000 0.000 0.080 50.5680.0009.083 0.802 19.2830.060 1.640 835.024.061.437 0.000 71.72 9.32 180.0 8/7/2024 19:23 14.24458.34710.260 4.931 765.3180.000 0.000 0.047 50.6090.0009.269 0.907 19.2340.123 1.578 835.024.021.539 0.000 72.59 9.40 180.0 8/7/2024 19:24 14.47058.57110.283 4.941 765.4530.000 0.000 0.037 50.8410.0009.036 0.950 19.2090.048 1.578 835.023.971.462 0.000 73.04 9.32 180.0 8/7/2024 19:25 14.12457.20610.278 4.925 766.3250.000 0.000 0.039 51.3410.0008.934 1.003 19.4340.000 1.590 835.024.301.533 0.000 71.33 9.38 180.0 8/7/2024 19:26 14.50457.78210.316 4.932 764.5770.000 0.000 0.022 50.8920.0009.198 0.963 19.3760.018 1.590 835.024.241.560 0.000 72.29 9.32 180.0 8/7/2024 19:27 13.83658.04210.322 4.925 762.4400.000 0.000 0.006 50.7940.0009.357 0.876 19.3350.000 1.594 835.024.101.495 0.000 71.88 9.35 180.0 8/7/2024 19:28 13.82257.66210.323 4.925 761.3470.000 0.000 0.041 50.6420.0009.074 0.858 19.2280.000 1.586 835.024.031.591 0.000 71.48 9.37 180.0 8/7/2024 19:29 13.50958.92310.318 4.923 761.1100.000 0.000 0.073 50.2570.0009.075 0.833 19.0640.067 1.559 835.023.761.538 0.000 72.43 9.39 180.0 8/7/2024 19:30 13.68557.95410.327 4.921 760.5270.000 0.000 0.070 50.2550.0009.045 0.970 19.2210.000 1.599 835.024.041.463 0.000 71.64 9.33 180.0 8/7/2024 19:31 14.22858.70610.317 4.930 765.0470.000 0.000 0.052 50.7400.0009.244 0.793 19.0780.063 1.582 834.023.841.603 0.000 72.93 9.29 180.0 8/7/2024 19:32 14.03859.05010.329 4.932 766.7470.000 0.000 0.035 50.7800.0008.882 0.998 19.2300.032 1.518 835.024.021.629 0.000 73.09 9.33 180.0 8/7/2024 19:33 13.95558.80010.320 4.934 763.2580.000 0.000 0.040 50.6020.0009.033 0.861 19.0350.000 1.576 835.023.781.527 0.000 72.75 9.39 180.0 8/7/2024 19:34 14.52759.58110.312 4.932 763.2830.000 0.000 0.000 50.6460.0009.026 0.843 19.0800.000 1.567 835.023.891.664 0.000 74.11 9.34 180.0 8/7/2024 19:35 14.09158.54210.321 4.946 764.1820.000 0.000 0.000 50.9040.0009.169 0.961 19.2660.110 1.581 835.024.181.666 0.000 72.63 9.38 180.0 8/7/2024 19:36 14.88359.34410.337 4.938 769.8540.000 0.000 0.105 51.8610.0009.002 0.749 19.4960.000 1.583 835.024.251.634 0.000 74.23 9.38 180.0 8/7/2024 19:37 13.95358.89010.325 4.944 765.4440.000 0.000 0.073 50.9650.0009.167 0.946 19.3150.026 1.571 835.024.221.692 0.000 72.84 9.37 180.0 8/7/2024 19:38 13.88458.06310.347 4.930 767.9060.000 0.000 0.012 51.4520.0008.983 0.873 19.3920.017 1.565 835.024.101.496 0.000 71.95 9.37 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/7/2024 19:39 13.78557.61010.332 4.934 765.3380.000 0.000 0.013 51.0390.0008.965 1.038 19.4490.020 1.573 835.024.391.651 0.000 71.40 9.41 180.0 8/7/2024 19:40 14.07557.74510.351 4.952 768.2830.000 0.000 0.049 51.5430.0009.170 0.993 19.3200.029 1.534 835.024.131.624 0.000 71.82 9.35 180.0 8/7/2024 19:41 14.25358.16010.388 4.946 770.1360.000 0.000 0.043 51.6930.0008.853 0.948 19.3210.000 1.519 835.024.171.773 0.000 72.41 9.35 180.0 8/7/2024 19:42 14.92558.61610.383 4.955 769.9150.000 0.000 0.025 51.6300.0009.175 0.959 19.4640.000 1.528 835.024.381.829 0.000 73.54 9.37 180.0 14.07758.16910.275 4.927 764.8130.000 0.000 0.050 50.8580.0009.035 0.907 19.3400.027 1.579 834.9724.1491.569 0.000 72.246 9.369 180.0Avg. 14.33458.39210.233 4.940 768.8470.000 0.000 0.066 51.2330.0008.708 0.874 19.4670.027 1.595 834.9724.2541.522 0.000 72.726 9.292 180.0Run 3 Avg: Baseline 3 8/7/2024 19:45 0.9570.0000.016 0.024 0.6360.261 0.030 0.032 0.1540.0150.000 0.056 0.1810.117 0.069 835.00.360.000 0.000 0.96 0.00 180.0 Post CTS 8/7/2024 20:05 0.0000.0000.059 0.029 0.0000.542 0.024 0.659 0.0000.1020.305 102.638 0.0000.124 0.159 835.068.750.000 0.000 0.00 0.00 180.0 8/7/2024 20:05 0.0000.0000.043 0.027 0.0000.403 0.018 0.488 0.0930.0000.527 106.059 0.0000.345 0.155 835.071.020.000 0.000 0.00 0.00 180.0 8/7/2024 20:05 0.8050.3610.038 0.009 0.0000.112 0.066 0.302 0.0000.0020.000 107.079 0.2810.660 0.032 835.071.740.000 0.000 1.17 0.00 180.0 Post NO2/Mid O2 8/7/2024 20:09 102.1350.765-0.000 0.028 1.1980.000 0.859 0.000 0.0000.0480.000 0.000 0.0000.099 0.088 836.00.180.000 0.000 102.90 10.29 180.0 8/7/2024 20:09 103.1380.9330.008 0.010 1.2760.158 0.884 0.119 0.2580.0210.000 0.000 0.0000.616 0.097 837.00.190.000 0.000 104.07 10.33 180.0 8/7/2024 20:09 104.8950.695-0.000 0.031 1.6620.024 0.878 0.024 0.3130.0000.952 0.000 0.2040.755 0.055 837.00.310.000 0.000 105.59 10.29 180.0 Post 5-Gas 8/7/2024 20:11 0.000249.3570.007 4.831 3.501501.956 1.284 2.060 8.1010.0131.085 0.999 252.0910.340 0.000 842.0253.551.182 10.097 249.36 0.00 180.0 8/7/2024 20:11 0.000251.318-0.000 4.837 2.477503.341 1.201 2.416 8.7940.3911.199 1.086 252.5570.000 0.000 842.0254.341.588 10.084 251.32 0.00 180.0 8/7/2024 20:11 0.000250.4110.002 4.851 1.728502.887 1.229 2.020 7.2140.2840.660 1.052 252.0560.000 0.000 842.0253.511.129 10.097 250.41 0.00 180.0 8/7/2024 20:11 0.000250.393-0.000 4.842 2.949503.270 1.238 2.389 8.0830.0601.565 1.131 251.8620.000 0.000 842.0253.641.530 10.077 250.39 0.00 180.0 End of Test Purge 8/7/2024 20:14 0.7290.141-0.000 0.040 0.0000.997 0.042 0.036 0.0000.0000.000 0.000 0.1020.249 0.127 843.00.360.000 0.000 0.87 0.00 180.0 8/7/2024 20:14 1.1070.0000.003 0.045 0.0000.861 0.015 0.157 0.3650.0900.000 0.286 0.2810.000 0.109 843.00.690.000 0.000 1.11 0.00 180.0 8/7/2024 20:14 0.5630.4870.004 0.024 0.0000.916 0.016 0.216 0.2930.0010.000 0.186 0.2200.000 0.008 843.00.360.000 0.002 1.05 0.00 180.0 8/7/2024 20:14 1.6110.502-0.000 0.041 0.0000.947 0.040 0.020 0.0000.0000.000 0.000 0.1960.000 0.000 842.00.200.000 0.000 2.11 0.00 180.0 8/7/2024 20:14 1.3850.0440.010 0.016 0.0170.653 0.037 0.101 0.0000.0000.000 0.301 0.2270.636 0.054 842.00.540.000 0.004 1.43 0.00 180.0 8/7/2024 20:14 1.7300.1320.006 0.035 0.0000.461 0.046 0.011 0.0000.0000.000 0.240 0.1620.000 0.007 842.00.340.000 0.003 1.86 0.00 180.0 8/7/2024 20:14 2.6270.000-0.000 0.045 0.0000.666 0.029 0.100 0.2190.0010.000 0.000 0.2640.023 0.000 841.00.260.000 0.000 2.63 0.00 180.0 8/7/2024 20:14 0.1310.000-0.000 0.055 0.6370.564 0.012 0.173 0.0000.0510.000 0.047 0.0000.000 0.108 840.00.250.000 0.000 0.13 0.00 180.0 GAS, Inc. Performance Test Report Test Type: Annual Test Date: 8/8/2024 Caterpillar G3516 LE Lean Burn (4 Cycle) DOM: 10/26/07 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:08:07 AM 12:23 PM Source: Unit Number: 5 Serial Number: WPW01760 Engine Hours:54154 Permit #: #DAQE-AN142100007-23 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Pleasant Valley Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 0.360 1.480 0.980 0.177 1.024 0.904 15.042 52.981 48.805 2.000 1.000 0.700 0.069 0.400 0.353 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Ovintiv USA Inc. 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 kyle muir 3 Logan Miller Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit 5 with a serial number of WPW01760 which is a Caterpillar G3516 LE engine located at Pleasant Valley Compressor Station and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 8/8/2024 by Logan Miller with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1340 brake horse power (BHP) at 1400 RPM. The engine was operating at 1161 BHP and 1399 RPM which is 86.67% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit 5 is authorized to operate under permit #DAQE-AN142100007-23. 4 4.0 Test Summary Engine/Compressor Specs Pleasant Valley Compressor StationLocation 5Unit ID Make Caterpillar Site Elevation ft.5374 Model G3516 LE Atmospheric Pressure psi.12.12 Serial Number WPW01760 Stack Diameter in.14 mfg. rated hp 1340 Yes 1400 Date of Manufacture 10/26/2007 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1160 1162 1161 1161 1398 1400 1399 1399 Percent Load % Intake Manifold Pressure (hg) 86.60%86.73%86.67%86.67% 38.44 38.44 38.44 38.44 Intake Manifold Temperature (F)125.60 125.00 125.00 125.20 Ambient Conditions Ambient Temperature Dry (F)67.00 77.00 79.00 74.33 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 162932.21 161107.62 161618.92 161886.25 4613.68 4562.02 4576.50 4584.07 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.11 0.11 0.11 0.11 9233.56 9231.55 9232.56 9232.5566666666 666667Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %11.40%11.48%11.50%11.46% T e s t S u m m a r y mfg. rated rpm Test RPM 8.61%8.41%8.34%8.45% Permitted Standards Results 5 Catalyst 0.0700.071 Run 1 Run 2 Run 3 3 Run Average Pass Permits 08:07 AM 09:19 AM 10:29 AM 8/8/2024 CO (g/hp-hr)0.066 0.0692.000 Pass StateFederal CO (ppmvw)12.708 13.798 13.447 13.318 CO (ppmvd)14.344 15.587 15.194 15.042 CO (mol wt) 28.01 CO (ppmvd) @15% O2 6.887 7.364 7.137 7.129 Fail CO (ppbvd) @15% O2 6886.729 7363.634 7136.831 7129.065 Fail 0.1780.182CO (lbs/hr)0.170 0.1770.360 Pass NOx (g/hp-hr)0.410 0.397 0.393 0.4001.000 Pass NOx (ppmvw)47.790 46.780 46.158 46.909 NOx (ppmvd)53.942 52.847 52.153 52.981 NOx (mol wt) 46.01 41.674 43.375 44.585 43.211NMNEHC (ppmvw) 47.038 49.000 50.376 48.805NMNEHC (ppmvd) NOx (ppbvd) @15% O2 25898.393 24965.909 24497.530 25120.611 Fail NOx (ppmvd) @15% O2 25.898 24.966 24.498 25.121 Fail NMNEHC (mol wt) 44.10 22583.735 23148.683 23662.679 23131.699 FailNMNEHC (ppbvd) @15% O2 0.343 0.353 0.364 0.3530.700 PassNMNEHC (g/hp-hr) 0.877 0.903 0.932 0.9040.980 PassNMNEHC (lbs/hr) 22.584 23.149 23.663 23.132 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)1.049 1.016 1.006 1.0241.480 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.48Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 12.71 0.72 47.06 0.00 0.73 0.72 47.79 1.11 41.67 0.00% 7.42% 0.00% 11.40% NMNEHC 11.72 48.50 0.54 49.04 40.71 7.43%11.37% 63.12 63.50 0.00 63.49 64.92 6.71%10.33% 13.70 45.61 0.93 46.54 42.64 7.41%11.44% 0.18 0.96 0.00 0.96 1.38 0.00%0.03% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.18 0.96 0.00 0.96 1.38 0.00%0.03% 13.82 45.84 1.10 46.94 42.95 7.22%11.49% 62.93 62.87 0.00 62.87 65.32 6.63%10.46% 13.77 44.93 1.69 46.62 43.80 7.27%11.48% 0.34 1.50 0.00 1.50 1.04 0.00%0.05% Avg. Wet 13.80 45.38 1.40 46.78 43.37 7.25%11.48% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 13.35 45.13 1.24 46.36 44.14 7.14%11.50% 62.60 61.99 0.00 61.99 67.00 6.63%10.33% 13.55 44.92 1.03 45.95 45.03 7.22%11.49% 0.14 0.96 0.00 0.96 1.31 0.00%0.03% 0.34 1.50 0.00 1.50 1.04 0.00%0.05% Avg. Wet 13.45 45.03 1.13 46.16 44.58 7.18%11.50% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 14 inches or:1.17 feet. or:1.07 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 1.34 Yes 14.00 230.00 53.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 11.40 29.21 1.34 Inches 2.34 7 11.66 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.69 7.43 12.71 838.00 0.10 24.75 24.85 707.13 1166.80 375.07 27.93 127.15 135.92 183905.74 162932.21 Run 2 11.48 29.20 1.32 5.68 7.25 13.80 838.00 0.10 24.75 24.85 715.06 1174.73 379.48 27.91 126.70 135.44 182003.44 161107.62 Run 3 11.50 29.20 1.34 5.68 7.19 13.45 838.00 0.10 24.75 24.85 719.63 1179.30 382.01 27.91 127.61 136.41 182612.00 161618.92 11.46 29.20 1.33 5.68 7.29 13.32 838.00 0.10 24.75 24.85 713.94 1173.61 378.85 27.92 127.15 135.93 182839.49 161885.17 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 1.32 Exhaust Temp F 705.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 1.20 1.22 1.28 715.00 700.00 703.00 1.38 1.38 1.32 714.00 712.00 710.00 1.38 1.32 1.28 707.00 708.00 703.00 1.37 704.00 1.31 1.60 1.39 701.00 710.00 713.00 1.36 1.37 1.34 702.00 707.00 707.13 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 1.37 Exhaust Temp F 721.00 1.34 1.31 1.37 722.00 726.00 711.00 1.38 1.38 1.31 723.00 717.00 719.00 1.37 1.34 1.34 723.00 729.00 722.00 1.29 724.00 1.34 1.21 1.47 716.00 715.00 712.00 1.23 1.34 718.00 716.00 719.631.34 Run 2 Δpstd (in) H2O 1.34 Exhaust Temp F 714.00 1.34 1.21 1.33 724.00 712.00 712.00 1.55 1.23 1.22 711.00 722.00 714.00 1.32 1.37 1.36 716.00 711.00 710.00 1.34 716.00 1.31 1.30 1.34 712.00 719.00 720.00 1.28 1.33 713.00 715.00 1.32 715.06 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.057)+.32(.086)+.28(.856+.001) = 29.208 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.208(1 -.11405)+.18.0(.11405) = 27.93 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√1.34*√(1166.795/(24.85*27.93)) = 127.15 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.114)127.147*1.069((528*24.85)/ (1166.795*29.92)) = 162932.21 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 162932.211/35.315 = 4613.683 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 14.344*(20.9-15)/(20.9-8.6%)) = 6.88 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (14.344*(1.164*10^-3)*4613.683*(Run Time/60))/1160.483 = .066 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .066*1/453.6*1160.483 = .17 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .17*4.38 = .745 TPYTPY = LB/HR. *4.38 Horsepower 1160= 1338.09 - ((69.7-63) / ((69.7-57.3) / 25%))) * 1338.09)BHP/HR = Available HP - ((MFP @100% - Actual MFP inHG) / ((MFP @100% - MFP @75%) / 25%))) * Available HP Wet to Dry PPM 14.34 = 12.708*(1/(1-.11))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.70% 20.69% 10.52% 10.14% 10.61% 10.61% 10.14%10.52% 10.70% 20.69% 10.61% 21.01% 10.61% 21.01% 10.61%21.01% 0.00% 10.61% 21.01% 0.09% 0.32% 0.41% 1.54% 10.61% Span Zero Offset 0.00% 21.01 0.00% 10.70%0.83%2.65%0.02% 8.39% 8.19% 8.12% 8.61% 8.41% 8.34% 9 Gas, Inc. 803.0 801.0 802.3 23.0 23.0 23.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Pleasant Valley Compressor Station 8/8/2024 5374 5 Caterpillar Model Serial Number G3516 LE WPW01760 Technician Logan Miller Run Start Times 08:07 AM 09:19 AM 10:29 AM 12:23 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1398.0 1400.0 1399.0 1399.0 Engine Hours 54151 54152 54153 54154 Intake Manifold Pressure (psi)31.0 31.0 31.0 31.0 Intake Manifold Temp °F 125.6 125.0 125.0 125.2 Engine Load (BHP)1160.5 1162.1 1161.3 1161.3 Ambient Temp °F 67.0 77.0 79.0 74.3 Humidity %35.0 33.0 31.0 33.0 Dew Point °F 39.0 46.0 46.0 43.7 Caterpillar YesCatalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 23.0 803.0Discharge Pressure (psi) Suction Pressure (psi) Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.05 R e s u l t s Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.02 Average:NOx 0.03 Average:VOC 0.05 Average:Oxygen 0.00 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 101.57 Tolerance 2.00% Difference between measured and expected 1.39% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.29 Average:Nitrogen monoxide NO 0.30 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.30 Average:VOC 0.75 Average:Oxygen 0.00 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 103.00 Value:CTS Compound Concentration Avg 100.35 Tolerance 5.00% Difference between measured and expected 2.57% Pre-test System CTS & Mechanical Response Time 45 secondsEquilibration Response Time Value:Spike Reported 251.27 Value:Spike Expected 254.10 System (Equilibration) Response Time Target (Spike) 66 secondsSystem Zero Response Time 66 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas.  Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC517327 4/29/2027 99.84 10.61% CC190334 4/24/2032 103.00 ALM-062642 12/14/2031 21.01% Cylinder # CC403040& Expiration: 7-13-2031 Propane CO NO SF6 Bottle Value 254.10 507.00 253.30 10.10 Analyzer System Response 251.27 500.79 248.68 10.07 Percent Difference 1.11%1.22%1.83%0.30% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 101.573 4.931 Spike Direct Propane 252.700 Mechanical Response Time SF6 10.119 CO 504.656 NO 250.630 Ethylene 100.354 32 seconds Analyzer Response Propane 251.270 SF6 10.070 CO 500.790 NO 248.677 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 251.888 CO 505.487 NO 249.835 32 seconds 66 seconds 9.50% 9.23% 9.32% 101.73% 100.80% 101.30% 10.107 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.338 50%7.000 83.3%11.662 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 14 230 53 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 161885.17 H2O%d @ Sampling Point:11.46 CO2%d @ Sampling Point:5.68 Pressure @ Sampling Point (Pg "H2O):1.33 Temperature @ Sampling Point (Deg F):713.94 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 103 101.57 4.931 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 101.573 4.931 Spike Direct Propane 252.700 Mechanical Response Time SF6 10.119 CO 504.656 NO 250.630 Ethylene 100.354 32 seconds Analyzer Response Propane 251.270 SF6 10.070 CO 500.790 NO 248.677 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 251.888 CO 505.487 NO 249.835 32 seconds 66 seconds 9.50% 9.23% 9.32% 101.73% 100.80% 101.30% 10.107 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 254.100 10.100 507.000 253.300 252.700 10.119 504.656 250.630 0.55% 0.19% 0.46% 1.05% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 28.395 0.000 Spike Average 50.700 0.961 Dilution Factor 9.497% Expected 49.837 % Recovery 101.730% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.934 Dilution Factor 9.230% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.943 Dilution Factor 9.319% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 30.529 52.032 51.366 101.300% 0.000227 0.000231 0.000262 29.590 50.717 50.312 100.800% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass1.80% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:51.1591691 Pass Line Position Difference:Resolution Difference to Reference 1.80% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 103.00 104.33 1.27% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Pleasant Valley Compressor Station; 5; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 8/8/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 8/8/2024 Logan Miller Gas, Inc. Appendices Gas, Inc. Gas, Inc. CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number:E05NI94E15AC014 Reference Number:54-402783135-1 Cylinder Number:CC403040&Cylinder Volume:147.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:CO,CO2,NO,NOX,PPN,BALN Certification Date:Jul 13, 2023 Expiration Date:Jul 13, 2031 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates NOX 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 NITRIC OXIDE 250.0 PPM 253.3 PPM G1 +/- 0.9% NIST Traceable 07/11/2023, 07/13/2023 PROPANE 250.0 PPM 254.1 PPM G1 +/- 0.9% NIST Traceable 07/11/2023 CARBON MONOXIDE 500.0 PPM 507.0 PPM G1 +/- 0.6% NIST Traceable 07/11/2023 CARBON DIOXIDE 5.000 %5.083 %G1 +/- 0.7% NIST Traceable 07/11/2023 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 200603-02 EB0112877 250.3 PPM NITRIC OXIDE/NITROGEN +/- 0.8%Oct 19, 2026 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR +/- 1.5%Feb 18, 2023 GMIS 1534012021105 ND73033 5.012 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.6%Jun 15, 2025 NTRM 200602-13 6162697Y 243.3 PPM PROPANE/AIR +/- 0.5%Mar 17, 2027 NTRM 150605-41 CC453947 491.9 PPM CARBON MONOXIDE/NITROGEN +/- 0.6%Mar 05, 2027 NTRM 13060423 CC413685 7.489 % CARBON DIOXIDE/NITROGEN +/- 0.6%May 14, 2025 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2010242 FTIR Jun 08, 2023 CO-1 SIEMENS ULTRAMAT 6E N1J5700 NDIR Jun 26, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2010242 FTIR Jul 07, 2023 Nicolet iS50 AUP2110277 FTIR Jul 07, 2023 Triad Data Available Upon Request PERMANENT NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc.      ,          '5781(+5 !+,+5+2)+81(+5    ;0/2*+52'0;<+*#%  ;0/2*+5$3081+   '(35'735;"#806''67/00" ;0/2*+5 5+6685+   " 2'0;6/6'7++(  $'09+870+7 3781(+5          Component Requested Certified Purity Concentration NITROGEN 99.999 %99.999 % OXYGEN <1 PPM 0.94 PPM WATER <1 PPM 0.058 PPM TOTAL HYDROCARBONS <0.1 PPM 0.1 PPM CARBON DIOXIDE <0.5 PPM 0.235 PPM CARBON MONOXIDE <0.5 PPM 0.235 PPM !##" #./6)+57/2)08*+69'08+6,5317.+,/006/*+'2*/62375+45+6+27'7/9+3,7.+86+6/*+485/7;327')7'2/5-'6 "'0+6!+45+6+27'7/9+,357./6/2,351'7/32 &!"#   &#%  #%   #% #%  #%  #% #%  #%    #%  #%   #%   #%  #%  #%  #%  #%  #%   #%   #%   1485/7/+69+5/,/+*'-'/267'2'0;7/)'067'2*'5*675')+'(0+73"#(;:+/-.7'2*35'2'0;6/6 #$! !%!"    Gas, Inc. 21% O2 Tri Probe Certification ” ‡ ƒ – Ž ƒ ‹ • • • ƒ Ž › – ‹ … ƒ Ž ‡ ” ˜ ‹ … ‡ • ͵Ͳ͵͵”†–Ž‹–›ǡǡ͹͵͸ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ ƒšǣȋͷͺͲȌʹʹͷǦʹ͸ͳʹ &(57,),&$7(2)$1$/<6,6 *UDGHRI3URGXFW&(57,),('67$1'$5'352%( 3DUW1XPEHU65HIHUHQFH 1XPEHU  /DERUDWRU\*$6,1&6WDFN'LDPHWHU $QDO\VLV'DWH7DUJHW)ORZ 5DWH /PLQ /271XPEHU 61 $ $6 1XPEHURI 3RLQWV  3URGXFWSHUIRUPDQFHYHULILHGE\GLUHFWFRPSDULVRQWRFDOLEUDWLRQVWDQGDUGVWUDFHDEOHWR1,67  7KHSUREHOLVWHGRQWKLVIRUPPHHWVWKHPXOWLSRLQWWUDYHUVHUHTXLUHPHQWRI(3$0HWKRGH VHFWLRQDVVKRZQLQWKHDFFRPSDQ\LQJGDWD0HWKRGHVHFWLRQVWDWHVWKDWWKHPXOWLSRLQW WUDYHUVHUHTXLUHPHQWFDQEHVDWLVILHGE\VDPSOLQJYLD³DPXOWLKROHSUREHGHVLJQHGWRVDPSOHDW WKHSUHVFULEHGSRLQWVZLWKDIORZSHUFHQWRIPHDQIORZUDWH´ $1$/<7,&$/5(68/76 ZƵŶηdŽƚĂů&ůŽǁ ;>ͬŵͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϭͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϮͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϯͿ 0HDQ3UREH 3RUW6DPSOHG )ORZ /P  5XQ/30  䧮    䧮    䧮   5XQ/30  䧮    䧮    䧮    &DOLEUDWLRQFRQGXFWHGLQDFFRUGDQFHZLWK(PLVVLRQ0HDVXUHPHQW&HQWHU*XLGHOLQH'RFXPHQW±(0&*' 1RWHV BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB $SSURYHGIRU5HOHDVH'DWH 3/23/2022 Probe size: 14S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Logan Miller GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Pleasant Valley Compressor Station Unit Number:5 Make:Caterpillar Location:G3516 LEModel: WPW01760Serial Number: RAW Result Data Stability 8/8/2024 06:22 2.5210.000-0.002 0.031 0.0000.423 0.035 0.099 0.0000.2970.000 0.263 0.3570.000 0.102 837.00.740.000 0.000 2.52 0.00 181.0 Pre Test Baseline Direct 8/8/2024 06:33 0.0660.0120.001 0.000 0.0620.081 0.000 0.019 0.0000.0910.023 0.000 0.0100.038 0.016 837.00.040.000 0.000 0.08 0.00 180.0 8/8/2024 06:34 0.0000.000-0.002 0.004 0.2810.046 0.001 0.028 0.0000.0000.168 0.000 0.0000.116 0.000 837.00.070.103 0.002 0.00 0.00 180.0 8/8/2024 06:34 0.0000.000-0.003 0.000 0.0000.010 0.000 0.000 0.0000.0980.196 0.000 0.0000.044 0.000 837.00.050.080 0.000 0.00 0.00 180.0 CTS Direct 8/8/2024 06:39 0.1040.0000.019 0.000 0.0000.163 0.023 0.011 0.0000.0000.000 101.707 0.0120.000 0.016 837.067.900.076 0.000 0.10 0.92 180.0 8/8/2024 06:40 0.0000.0000.021 0.004 0.0000.179 0.014 0.013 0.0030.0000.000 101.833 0.0000.246 0.015 837.068.080.243 0.000 0.00 1.28 180.0 8/8/2024 06:40 0.4250.0000.023 0.004 0.0000.231 0.022 0.000 0.1250.0000.000 101.180 0.0000.048 0.022 837.067.660.242 0.000 0.43 0.00 180.0 High O2 Direct 8/8/2024 06:49 0.0000.0000.001 0.000 0.3030.140 0.001 0.067 0.0790.0000.363 0.000 0.0390.190 0.000 837.00.270.344 0.000 0.00 20.34 180.0 8/8/2024 06:50 0.0000.000-0.004 0.000 0.0310.000 0.000 0.000 0.0250.0830.270 0.000 0.0000.141 0.000 837.00.220.334 0.002 0.00 20.72 180.0 8/8/2024 06:50 0.0000.000-0.003 0.000 0.2210.000 0.000 0.000 0.0880.0000.480 0.000 0.0150.051 0.000 837.00.280.403 0.000 0.00 21.00 180.0 NO2/Mid O2 Direct 8/8/2024 06:55 98.7160.362-0.006 0.000 1.3620.000 0.763 0.000 1.3380.0620.440 0.000 0.0000.069 0.000 838.00.220.331 0.000 99.08 10.70 180.0 8/8/2024 06:55 97.6940.457-0.002 0.000 0.9600.000 0.745 0.000 1.1740.1720.182 0.000 0.0000.070 0.000 838.00.000.000 0.000 98.15 10.72 180.0 8/8/2024 06:57 98.9030.356-0.006 0.000 1.3810.000 0.771 0.000 1.1660.0330.561 0.000 0.0000.000 0.000 838.00.290.440 0.000 99.26 10.67 180.0 Spike Direct 8/8/2024 07:00 0.000250.253-0.001 4.792 3.316504.111 1.181 2.090 9.4090.2560.000 1.032 252.5270.229 0.000 838.0255.563.512 10.116 250.25 0.00 180.0 8/8/2024 07:01 0.000250.491-0.001 4.812 2.834505.003 1.167 2.110 9.3390.1520.000 1.037 252.7800.000 0.000 838.0255.923.670 10.119 250.49 0.00 180.0 8/8/2024 07:01 0.000251.147-0.000 4.823 2.699504.855 1.176 2.236 8.9060.1310.000 1.020 252.7920.215 0.000 838.0255.773.453 10.121 251.15 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 8/8/2024 07:04 0.0000.3020.005 0.000 0.6430.319 0.006 0.729 0.4960.0000.180 0.000 0.1680.000 0.000 838.00.630.689 0.003 0.30 0.00 180.0 8/8/2024 07:05 0.0000.3540.006 0.001 0.4060.274 0.000 0.595 0.4710.0140.455 0.031 0.0720.000 0.000 837.00.610.780 0.001 0.35 0.00 180.0 8/8/2024 07:05 0.0000.2510.004 0.000 0.8340.290 0.000 0.520 0.1680.0000.341 0.119 0.2540.044 0.000 837.01.021.036 0.004 0.25 0.00 180.0 CTS System with Response Time 8/8/2024 07:14 0.0000.1700.017 0.000 0.0000.279 0.008 0.260 0.3100.0000.000 100.002 0.0000.000 0.000 838.067.290.926 0.000 0.17 0.00 180.0 8/8/2024 07:14 0.0000.0000.017 0.000 0.0000.280 0.000 0.278 0.1420.0000.000 100.408 0.0000.000 0.003 837.067.390.665 0.000 0.00 0.00 180.0 8/8/2024 07:15 0.0000.0000.016 0.000 0.0000.233 0.000 0.313 0.1910.0090.000 100.652 0.0000.115 0.004 837.067.570.693 0.000 0.00 0.00 180.0 NO2/Mid O2 System with Response Time 8/8/2024 07:27 101.0310.882-0.000 0.000 1.3860.151 0.787 0.000 0.9250.0000.000 0.000 0.0000.516 0.000 838.00.711.071 0.001 101.91 10.61 180.0 8/8/2024 07:28 101.2790.886-0.000 0.000 1.2510.091 0.783 0.000 1.0700.0040.000 0.000 0.0000.346 0.000 838.00.771.155 0.000 102.17 10.48 180.0 8/8/2024 07:28 101.3700.728-0.000 0.000 1.2830.195 0.781 0.000 0.8660.0000.000 0.000 0.0000.370 0.000 837.00.711.063 0.001 102.10 10.48 180.0 Spike System with Response Time 8/8/2024 07:30 0.000248.0040.002 4.743 3.610499.464 1.177 2.173 9.5590.0910.000 1.167 250.8100.393 0.000 838.0254.143.830 10.060 248.00 0.00 180.0 8/8/2024 07:30 0.000248.9590.003 4.760 3.189501.591 1.155 2.315 9.3910.0000.467 1.182 251.4460.249 0.000 838.0254.873.960 10.069 248.96 0.00 180.0 8/8/2024 07:30 0.000249.0680.004 4.760 3.111501.314 1.170 2.441 9.4080.0050.291 1.153 251.5530.207 0.000 838.0255.044.072 10.082 249.07 0.00 180.0 Baseline System with Response Time 8/8/2024 07:33 0.0000.4870.002 0.000 0.5050.698 0.000 0.117 0.4690.0470.304 0.160 0.2500.062 0.000 838.01.121.149 0.004 0.49 0.00 180.0 8/8/2024 07:33 0.0000.997-0.000 0.000 0.9460.417 0.000 0.115 0.7410.0370.734 0.136 0.2710.190 0.000 837.01.231.296 0.004 1.00 0.00 180.0 8/8/2024 07:33 0.0000.6600.002 0.000 0.8930.338 0.000 0.189 0.6580.0000.728 0.000 0.1770.000 0.000 838.00.971.190 0.003 0.66 0.00 180.0 Run 1 - A 30minute/60min 8/8/2024 08:08 0.00050.45611.335 5.693 952.12511.096 0.000 0.058 64.2460.00013.805 4.776 27.8350.000 2.399 838.039.846.037 0.000 50.46 7.47 180.0 8/8/2024 08:09 0.00049.78211.345 5.685 954.87210.859 0.000 0.000 64.6780.00011.279 4.910 27.9880.000 2.435 838.040.135.999 0.000 49.78 7.45 180.0 8/8/2024 08:10 0.00049.55811.333 5.694 959.94710.977 0.000 0.000 65.3660.00011.351 4.978 28.3640.000 2.395 838.040.425.928 0.000 49.56 7.49 180.0 8/8/2024 08:11 0.00049.41111.331 5.695 965.24711.133 0.000 0.000 65.6210.00011.198 4.937 28.6010.000 2.391 838.040.675.988 0.000 49.41 7.48 180.0 8/8/2024 08:13 0.00048.77411.347 5.693 961.91411.200 0.000 0.000 65.1620.00011.164 5.013 28.2640.000 2.418 838.040.345.850 0.000 48.77 7.50 180.0 8/8/2024 08:14 0.00048.93611.341 5.697 963.43611.306 0.000 0.000 65.3830.00011.092 5.045 28.3370.000 2.417 838.040.445.851 0.000 48.94 7.46 180.0 8/8/2024 08:15 0.00049.37411.371 5.714 966.94811.157 0.000 0.000 65.6610.00013.444 5.069 28.2240.000 2.395 838.040.335.905 0.000 49.37 7.43 180.0 8/8/2024 08:16 0.00049.61811.402 5.720 966.05211.146 0.000 0.000 65.5130.00011.491 5.020 28.2160.000 2.413 838.040.185.692 0.000 49.62 7.45 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/8/2024 08:17 0.00049.27011.399 5.715 962.26911.059 0.000 0.000 65.1330.00011.357 5.072 28.0860.000 2.424 838.040.185.799 0.000 49.27 7.45 180.0 8/8/2024 08:18 0.00949.22311.389 5.712 974.63711.393 0.000 0.000 65.2260.00011.307 4.990 28.1100.000 2.418 838.040.105.740 0.000 49.23 7.46 180.0 8/8/2024 08:19 0.00048.94411.380 5.718 962.60511.266 0.000 0.000 65.0890.00013.650 5.101 28.0540.000 2.404 838.040.025.629 0.000 48.94 7.44 180.0 8/8/2024 08:20 0.00049.23711.372 5.713 961.24811.357 0.000 0.000 65.2070.00013.437 5.090 27.9920.000 2.405 838.039.955.635 0.000 49.24 7.45 180.0 8/8/2024 08:21 0.21049.67311.354 5.709 974.62511.468 0.000 0.000 65.4860.00013.412 4.989 28.2670.000 2.410 838.040.185.645 0.000 49.88 7.43 180.0 8/8/2024 08:22 1.31148.94611.362 5.709 982.15811.691 0.000 0.000 64.3110.00013.550 5.113 28.5910.000 2.683 838.041.085.568 0.000 50.26 7.44 180.0 8/8/2024 08:23 0.00047.79711.352 5.702 961.20411.467 0.000 0.000 65.5670.00013.554 5.127 28.4850.000 2.458 838.040.525.552 0.000 47.80 7.43 180.0 8/8/2024 08:24 0.00048.80611.359 5.707 958.94211.573 0.000 0.000 65.1860.00011.453 5.083 28.3390.000 2.446 838.040.255.447 0.000 48.81 7.44 180.0 8/8/2024 08:25 0.77448.39711.357 5.706 976.36411.429 0.000 0.000 63.0650.00010.985 5.068 28.4210.000 2.681 838.040.925.638 0.000 49.17 7.42 180.0 8/8/2024 08:26 1.13148.92611.403 5.714 977.14311.394 0.000 0.000 63.2940.00013.751 5.103 28.3310.000 2.665 838.040.855.679 0.000 50.06 7.39 180.0 8/8/2024 08:27 0.59548.28911.395 5.705 975.21711.712 0.000 0.000 63.1040.00013.429 5.204 28.1580.000 2.670 838.040.695.585 0.000 48.88 7.45 180.0 8/8/2024 08:28 0.18147.97811.408 5.702 976.90611.649 0.000 0.000 66.2100.00011.141 5.083 28.7230.000 2.485 838.040.815.597 0.000 48.16 7.43 180.0 8/8/2024 08:29 1.74747.60511.354 5.694 982.82311.984 0.000 0.000 63.9800.00013.464 5.260 28.5760.000 2.717 838.041.255.599 0.000 49.35 7.42 180.0 8/8/2024 08:30 0.71347.40411.362 5.699 979.17312.086 0.000 0.000 64.0610.00013.621 5.390 28.6490.000 2.659 838.041.335.645 0.000 48.12 7.42 180.0 8/8/2024 08:31 0.00048.55711.384 5.707 966.37112.190 0.000 0.000 66.1210.00010.992 5.219 28.5400.000 2.419 838.040.495.441 0.000 48.56 7.42 180.0 8/8/2024 08:32 1.11148.07311.396 5.705 978.68412.448 0.000 0.000 63.5330.00013.397 5.311 28.5850.000 2.714 838.041.325.656 0.000 49.18 7.42 180.0 8/8/2024 08:33 0.77747.48011.386 5.710 975.96212.495 0.000 0.000 63.3670.00010.889 5.336 28.7450.000 2.767 838.041.535.547 0.000 48.26 7.38 180.0 8/8/2024 08:34 1.89049.36411.427 5.716 979.44812.753 0.000 0.000 63.5460.00013.509 5.456 28.3920.000 2.697 838.041.215.673 0.000 51.25 7.43 180.0 8/8/2024 08:35 1.21847.70511.381 5.710 975.46412.834 0.000 0.000 63.2340.00013.185 5.453 28.2610.000 2.719 838.041.075.601 0.000 48.92 7.45 180.0 8/8/2024 08:36 1.60045.02311.346 5.693 986.43212.762 0.000 0.000 65.3440.00013.277 5.391 29.2510.000 2.681 838.041.945.603 0.000 46.62 7.40 180.0 8/8/2024 08:37 1.94845.93611.359 5.689 982.38412.777 0.000 0.000 64.6040.00013.199 5.445 28.7190.000 2.704 838.041.645.817 0.000 47.88 7.43 180.0 8/8/2024 08:38 0.99246.57811.394 5.698 980.61812.796 0.000 0.000 64.4300.00013.170 5.520 28.7450.000 2.688 838.041.555.629 0.000 47.57 7.45 180.0 0.54048.50411.371 5.704 970.70711.715 0.000 0.002 64.6910.00012.485 5.152 28.3950.000 2.539 838.0040.7085.699 0.000 49.044 7.439 180.0Avg. Spike 1 8/8/2024 08:41 0.00063.49510.327 5.608 888.00363.124 0.000 0.014 56.8800.00012.779 7.093 50.7000.000 2.658 838.064.926.261 0.961 63.49 6.71 180.0 Run 1 - B 30minute/60min 8/8/2024 08:44 0.68747.76211.406 5.704 975.61012.982 0.000 0.000 62.7300.00013.506 5.349 28.4530.000 2.710 838.041.295.780 0.000 48.45 7.46 180.0 8/8/2024 08:45 1.00549.65211.414 5.707 979.77213.143 0.000 0.000 63.2340.00013.424 5.521 28.4420.000 2.680 838.041.375.836 0.000 50.66 7.41 180.0 8/8/2024 08:47 0.06749.96211.376 5.697 973.00913.274 0.000 0.000 65.1210.00010.830 5.563 28.3310.000 2.427 838.040.815.874 0.001 50.03 7.46 180.0 8/8/2024 08:48 0.00049.47711.384 5.692 960.70413.439 0.000 0.000 65.5120.00010.953 5.520 28.3200.000 2.439 838.040.665.667 0.000 49.48 7.42 180.0 8/8/2024 08:49 1.15950.34711.398 5.697 972.49013.573 0.000 0.000 62.9210.00010.732 5.568 28.4550.000 2.696 838.041.576.009 0.000 51.51 7.46 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/8/2024 08:50 0.00049.73411.384 5.694 959.08513.632 0.000 0.000 65.7830.00013.520 5.564 29.0630.000 2.470 838.041.675.929 0.001 49.73 7.44 180.0 8/8/2024 08:51 0.18447.92211.388 5.682 974.94313.673 0.000 0.000 66.3910.00010.971 5.719 29.3100.000 2.502 838.042.166.049 0.000 48.11 7.47 180.0 8/8/2024 08:52 1.00146.36911.374 5.682 982.06813.484 0.000 0.000 64.9340.00010.861 5.678 29.5170.000 2.701 838.042.685.957 0.000 47.37 7.46 180.0 8/8/2024 08:53 1.00345.25711.394 5.679 982.29913.484 0.000 0.000 64.6290.00013.273 5.540 29.4970.000 2.719 838.042.696.088 0.000 46.26 7.45 180.0 8/8/2024 08:54 0.94444.80611.415 5.679 981.33713.598 0.000 0.000 64.5070.00013.125 5.764 29.5420.000 2.721 838.042.866.042 0.000 45.75 7.45 180.0 8/8/2024 08:55 0.79145.30311.433 5.677 981.94713.773 0.000 0.000 64.2090.00013.380 5.703 29.4240.000 2.724 838.042.746.092 0.000 46.09 7.43 180.0 8/8/2024 08:56 0.29944.48211.464 5.674 985.37713.860 0.000 0.000 67.1140.00013.200 5.822 29.7600.000 2.485 838.042.706.126 0.000 44.78 7.47 180.0 8/8/2024 08:57 0.83043.92811.480 5.668 986.83113.891 0.000 0.000 65.2680.00010.652 5.726 29.5980.000 2.669 838.042.836.112 0.000 44.76 7.45 180.0 8/8/2024 08:58 1.78345.03811.483 5.683 992.63113.717 0.000 0.000 66.2970.00013.126 5.761 29.7710.000 2.648 838.043.016.152 0.000 46.82 7.49 180.0 8/8/2024 08:59 1.40043.36311.414 5.660 993.71213.787 0.000 0.000 66.8090.00010.769 5.830 30.1380.000 2.650 838.043.466.204 0.002 44.76 7.45 180.0 8/8/2024 09:00 2.58342.41611.426 5.654 993.94013.820 0.000 0.000 66.7360.00013.012 5.790 30.1120.000 2.638 838.043.466.312 0.000 45.00 7.46 180.0 8/8/2024 09:01 1.36241.53411.435 5.655 992.33813.856 0.000 0.000 66.8490.00013.062 5.790 30.1460.000 2.703 838.043.656.360 0.000 42.90 7.44 180.0 8/8/2024 09:02 1.85043.01311.482 5.664 986.67613.765 0.000 0.000 65.7300.00013.017 5.740 29.8920.000 2.705 838.043.356.333 0.000 44.86 7.35 180.0 8/8/2024 09:03 1.41043.66011.495 5.672 990.05913.849 0.000 0.000 65.8460.00012.838 5.699 30.0000.000 2.753 838.043.476.246 0.000 45.07 7.37 180.0 8/8/2024 09:04 0.57943.41011.517 5.674 986.81513.828 0.000 0.000 65.1740.00013.172 5.846 29.7350.000 2.694 838.043.256.337 0.001 43.99 7.39 180.0 8/8/2024 09:05 0.87843.96111.526 5.675 984.44013.900 0.000 0.000 64.4960.00013.159 5.708 29.3540.000 2.725 838.042.856.364 0.000 44.84 7.37 180.0 8/8/2024 09:06 2.02244.76111.493 5.685 982.86613.923 0.000 0.000 64.0760.00010.389 5.716 29.1990.000 2.744 838.042.766.393 0.000 46.78 7.33 180.0 8/8/2024 09:07 1.15045.76811.468 5.683 980.42113.912 0.000 0.000 64.2550.00010.464 5.779 29.1940.000 2.729 838.042.706.295 0.000 46.92 7.36 180.0 8/8/2024 09:08 0.98846.02911.465 5.682 981.22713.872 0.000 0.000 64.3020.00012.832 5.703 29.2670.000 2.668 838.042.556.219 0.000 47.02 7.44 180.0 8/8/2024 09:09 1.27645.13611.445 5.685 985.37014.021 0.000 0.000 65.5790.00012.738 5.710 29.5680.000 2.676 838.042.906.265 0.000 46.41 7.37 180.0 8/8/2024 09:10 0.89345.73611.437 5.680 979.56713.735 0.000 0.000 64.7720.00012.784 5.731 29.1880.000 2.758 838.042.766.351 0.002 46.63 7.38 180.0 8/8/2024 09:11 0.36244.48211.426 5.669 985.58413.838 0.000 0.000 67.5670.00012.822 5.719 29.9760.000 2.527 838.043.226.566 0.000 44.84 7.39 180.0 8/8/2024 09:12 0.71444.91411.438 5.675 982.47213.840 0.000 0.000 65.2090.00010.411 5.802 29.5130.000 2.727 838.043.156.467 0.000 45.63 7.38 180.0 8/8/2024 09:13 0.43944.83311.436 5.676 981.09313.750 0.000 0.000 65.4150.00013.098 5.815 29.9230.000 2.743 838.043.616.480 0.000 45.27 7.38 180.0 8/8/2024 09:14 0.08445.27911.453 5.683 978.97813.807 0.000 0.000 67.4660.00013.136 5.812 29.8680.000 2.511 838.042.996.334 0.000 45.36 7.39 180.0 0.92545.61111.438 5.680 981.78913.701 0.000 0.000 65.2980.00012.309 5.700 29.4190.000 2.651 838.0042.6396.175 0.000 46.536 7.419 180.0Avg. 0.73347.05811.405 5.692 976.24812.708 0.000 0.001 64.9940.00012.397 5.426 28.9070.000 2.595 838.0041.6735.937 0.000 47.790 7.429 180.0Run 1 Avg: Baseline 1 8/8/2024 09:17 0.0000.9560.028 0.000 2.3860.181 0.019 0.000 0.9490.0000.439 0.000 0.0250.188 0.000 838.01.382.030 0.000 0.96 0.00 180.0 Run 2 - A 30minute/60min 8/8/2024 09:19 0.00045.22211.157 5.501 930.31913.070 0.000 0.000 62.7680.00010.279 5.425 28.7340.000 2.600 838.041.706.224 0.000 45.22 6.49 180.0 8/8/2024 09:20 0.00046.25711.497 5.679 958.18113.735 0.000 0.000 65.9530.00010.443 5.692 29.3400.000 2.508 838.042.276.181 0.000 46.26 6.89 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/8/2024 09:22 0.65446.30011.514 5.680 979.94413.648 0.000 0.000 64.9160.00010.775 5.560 29.6120.000 2.732 838.042.856.098 0.000 46.95 7.06 180.0 8/8/2024 09:23 0.65446.49111.523 5.690 972.33313.809 0.000 0.000 63.7480.00012.875 5.615 29.3950.000 2.805 838.042.936.264 0.000 47.14 7.19 180.0 8/8/2024 09:24 0.55545.92711.510 5.697 974.29013.742 0.000 0.000 63.5060.00013.023 5.709 29.2890.000 2.831 838.042.946.278 0.002 46.48 7.21 180.0 8/8/2024 09:25 0.80345.58511.488 5.692 982.64613.785 0.000 0.000 64.9390.00013.429 5.749 30.0050.000 2.804 838.043.516.092 0.000 46.39 7.26 180.0 8/8/2024 09:26 1.19346.09011.510 5.691 979.90313.793 0.000 0.000 64.5480.00013.165 5.796 29.7380.000 2.822 838.043.416.250 0.000 47.28 7.25 180.0 8/8/2024 09:27 1.21646.45811.540 5.705 975.14513.821 0.000 0.000 63.2680.00013.170 5.731 29.1250.000 2.851 838.042.716.097 0.000 47.67 7.25 180.0 8/8/2024 09:28 0.59745.81911.501 5.685 978.61913.881 0.000 0.000 63.8550.00013.126 5.715 29.2680.000 2.844 838.042.796.037 0.000 46.42 7.29 180.0 8/8/2024 09:29 1.79945.70411.495 5.691 983.14513.758 0.000 0.000 64.6370.00012.933 5.613 29.7710.000 2.812 838.043.156.013 0.000 47.50 7.26 180.0 8/8/2024 09:30 0.59647.02811.510 5.685 976.36313.717 0.000 0.000 63.6110.00010.520 5.636 29.3000.000 2.779 838.042.595.962 0.000 47.62 7.24 180.0 8/8/2024 09:31 0.63646.51011.505 5.696 975.43913.685 0.000 0.000 63.9280.00013.110 5.674 29.2770.000 2.797 838.042.746.126 0.000 47.15 7.27 180.0 8/8/2024 09:32 1.54846.05811.503 5.690 979.69313.660 0.000 0.000 64.4210.00013.040 5.699 29.7090.000 2.787 838.043.106.019 0.000 47.61 7.24 180.0 8/8/2024 09:33 0.65045.98411.492 5.685 970.69713.978 0.000 0.000 63.0100.00010.877 5.709 29.2850.000 2.915 838.042.855.889 0.000 46.63 7.32 180.0 8/8/2024 09:34 1.90346.17611.461 5.684 972.37114.066 0.000 0.000 62.9700.00010.859 5.796 29.3110.000 2.884 838.042.815.800 0.000 48.08 7.33 180.0 8/8/2024 09:35 1.12545.65511.464 5.685 977.05913.783 0.000 0.000 63.9240.00013.330 5.714 29.6340.000 2.838 838.043.015.838 0.000 46.78 7.27 180.0 8/8/2024 09:36 2.48645.24211.478 5.688 980.16813.816 0.000 0.000 64.5270.00013.419 5.741 30.1180.000 2.886 838.043.515.689 0.000 47.73 7.26 180.0 8/8/2024 09:37 1.88245.39011.495 5.685 982.34213.867 0.000 0.000 64.6490.00010.728 5.704 29.9280.000 2.825 838.043.205.735 0.000 47.27 7.27 180.0 8/8/2024 09:38 2.14144.90211.499 5.687 979.83713.837 0.000 0.000 64.2890.00011.015 5.942 29.8570.000 2.884 838.043.415.735 0.000 47.04 7.31 180.0 8/8/2024 09:39 0.36745.95711.527 5.706 974.49613.924 0.000 0.000 66.2200.00013.291 5.824 29.5880.000 2.619 838.042.545.749 0.000 46.32 7.27 180.0 8/8/2024 09:40 0.22345.69711.506 5.709 975.90513.919 0.000 0.000 66.3720.00013.365 5.737 29.7400.000 2.646 838.042.655.693 0.000 45.92 7.30 180.0 8/8/2024 09:41 0.85846.57711.535 5.706 976.09713.916 0.000 0.000 63.1390.00010.955 5.742 29.3420.000 2.863 838.042.725.729 0.000 47.43 7.30 180.0 8/8/2024 09:42 0.98146.15011.534 5.707 976.69513.945 0.000 0.000 63.9370.00013.719 5.794 29.6140.000 2.895 838.042.965.534 0.000 47.13 7.32 180.0 8/8/2024 09:43 0.93046.06911.509 5.696 971.96113.898 0.000 0.000 62.9380.00013.319 5.792 29.6640.000 2.963 838.043.275.725 0.000 47.00 7.28 180.0 8/8/2024 09:44 1.47744.89511.475 5.682 976.13114.078 0.000 0.000 63.9000.00013.273 5.737 30.1280.000 2.935 838.043.465.458 0.000 46.37 7.27 180.0 8/8/2024 09:45 1.57844.24211.473 5.683 978.47614.069 0.000 0.000 63.8660.00013.589 5.785 30.0930.000 2.945 838.043.515.501 0.000 45.82 7.29 180.0 8/8/2024 09:46 1.84044.67211.476 5.681 975.49013.900 0.000 0.000 63.2970.00010.858 5.778 29.8980.000 2.973 838.043.385.525 0.000 46.51 7.29 180.0 8/8/2024 09:47 2.41145.90811.489 5.687 975.66913.876 0.000 0.000 63.4500.00011.131 5.794 29.7100.000 2.896 838.043.095.586 0.000 48.32 7.29 180.0 8/8/2024 09:48 1.66846.56811.477 5.685 972.82613.803 0.000 0.000 62.9200.00011.154 5.781 29.5310.000 2.923 838.042.865.438 0.000 48.24 7.29 180.0 8/8/2024 09:49 0.29445.71211.479 5.684 969.94413.840 0.000 0.000 65.1940.00011.012 5.677 29.6980.000 2.700 838.042.665.659 0.000 46.01 7.26 180.0 1.10245.84211.487 5.684 974.40613.821 0.000 0.000 64.0900.00012.193 5.722 29.5900.000 2.819 838.0042.9535.864 0.000 46.943 7.227 180.0Avg. Spike 2 8/8/2024 09:53 0.00062.87310.457 5.601 879.04562.932 0.000 0.000 56.1860.0009.877 7.224 50.7170.000 2.937 838.065.325.863 0.934 62.87 6.63 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 8/8/2024 09:56 2.04245.58711.487 5.687 974.94113.995 0.000 0.000 63.3320.00010.959 5.912 29.9950.000 2.995 838.043.545.415 0.000 47.63 7.26 180.0 8/8/2024 09:57 0.64444.68611.486 5.673 977.83713.838 0.000 0.000 63.8340.00013.672 5.790 30.2740.000 2.974 838.043.735.466 0.000 45.33 7.29 180.0 8/8/2024 09:58 0.44444.49411.482 5.681 975.83213.710 0.000 0.000 63.5520.00013.518 5.744 29.8500.000 2.975 838.043.235.402 0.000 44.94 7.28 180.0 8/8/2024 09:59 1.64344.07511.475 5.684 977.76413.602 0.000 0.000 63.9140.00011.175 5.770 30.1320.000 2.980 838.043.545.408 0.000 45.72 7.27 180.0 8/8/2024 10:00 0.88445.14211.483 5.696 972.90113.745 0.000 0.000 63.4750.00013.660 5.802 29.9330.000 2.956 838.043.325.407 0.000 46.03 7.28 180.0 8/8/2024 10:01 2.17145.94911.480 5.696 972.92413.611 0.000 0.000 63.1120.00013.575 5.704 29.8410.000 2.976 838.043.295.539 0.000 48.12 7.28 180.0 8/8/2024 10:02 1.29145.16511.457 5.682 967.50613.798 0.000 0.000 62.8710.00010.932 5.737 30.0570.000 2.995 838.043.535.492 0.000 46.46 7.29 180.0 8/8/2024 10:03 1.57445.65211.457 5.686 972.75213.782 0.000 0.000 63.6620.00013.782 5.639 30.3970.000 2.982 838.043.885.634 0.000 47.23 7.29 180.0 8/8/2024 10:04 1.29245.28011.451 5.688 968.90613.762 0.000 0.000 62.6090.00011.110 5.681 29.9640.000 3.033 838.043.525.556 0.000 46.57 7.31 180.0 8/8/2024 10:05 1.65944.83611.461 5.681 974.29913.805 0.000 0.000 63.1760.00013.628 5.740 30.0620.000 2.997 838.043.615.584 0.000 46.50 7.29 180.0 8/8/2024 10:06 3.13844.67511.471 5.678 977.85413.713 0.000 0.000 64.1050.00011.019 5.760 30.3970.000 2.968 838.043.745.351 0.000 47.81 7.27 180.0 8/8/2024 10:07 2.39444.51811.456 5.678 976.93413.881 0.000 0.000 63.9790.00011.175 5.693 30.1980.000 2.973 838.043.605.489 0.000 46.91 7.27 180.0 8/8/2024 10:08 1.72145.07211.453 5.677 979.44813.841 0.000 0.000 64.5150.00011.077 5.817 30.3950.000 2.926 838.043.795.495 0.000 46.79 7.25 180.0 8/8/2024 10:09 1.95245.25011.475 5.682 977.03213.858 0.000 0.000 63.8080.00013.500 5.698 30.1200.000 2.971 838.043.515.477 0.000 47.20 7.31 180.0 8/8/2024 10:10 0.95545.23211.464 5.679 973.79113.735 0.000 0.000 63.6190.00010.966 5.787 30.3530.000 2.981 838.043.875.552 0.000 46.19 7.29 180.0 8/8/2024 10:11 1.64445.46411.445 5.683 973.67513.711 0.000 0.000 63.5800.00011.136 5.759 30.3600.000 3.022 838.043.985.608 0.000 47.11 7.27 180.0 8/8/2024 10:12 1.11945.01811.441 5.680 978.86113.900 0.000 0.000 63.9530.00011.075 5.826 30.6920.000 3.012 838.044.315.572 0.001 46.14 7.26 180.0 8/8/2024 10:13 2.30345.21511.441 5.680 978.73213.903 0.000 0.000 63.7630.00011.018 5.666 30.5520.000 2.986 838.043.935.449 0.000 47.52 7.27 180.0 8/8/2024 10:14 1.78344.83111.457 5.681 975.78713.858 0.000 0.000 63.4830.00010.959 5.811 30.3280.000 3.003 838.043.915.558 0.000 46.61 7.27 180.0 8/8/2024 10:15 2.30744.12111.456 5.679 984.64013.851 0.000 0.000 65.1710.00011.292 5.736 30.7620.000 2.958 838.044.165.491 0.000 46.43 7.29 180.0 8/8/2024 10:16 1.19044.25111.485 5.673 979.94613.721 0.000 0.000 64.3190.00011.316 5.773 30.4710.000 2.885 838.043.865.650 0.000 45.44 7.27 180.0 8/8/2024 10:17 1.22644.65111.471 5.673 974.80713.843 0.000 0.000 63.9900.00011.109 5.744 30.2270.000 2.946 838.043.745.688 0.000 45.88 7.30 180.0 8/8/2024 10:18 2.48344.71411.484 5.680 976.11013.899 0.000 0.000 64.1510.00010.990 5.821 30.5940.000 2.995 838.044.245.664 0.000 47.20 7.26 180.0 8/8/2024 10:19 2.32644.60111.512 5.677 976.41013.904 0.000 0.000 63.6990.00011.069 5.783 30.4060.000 3.006 838.044.005.588 0.000 46.93 7.24 180.0 8/8/2024 10:20 2.51345.17611.514 5.684 975.94713.827 0.000 0.000 63.7150.00011.040 5.693 30.3630.000 2.978 838.043.945.732 0.000 47.69 7.26 180.0 8/8/2024 10:21 1.55845.01511.499 5.682 974.72713.937 0.000 0.000 63.4100.00011.061 5.805 30.2640.000 2.964 838.043.865.691 0.000 46.57 7.25 180.0 8/8/2024 10:22 1.11444.98411.501 5.684 977.66913.755 0.000 0.000 63.7040.00010.973 5.846 30.5970.000 2.989 838.044.175.538 0.000 46.10 7.27 180.0 8/8/2024 10:23 1.55244.05911.490 5.685 977.13613.492 0.000 0.000 63.9190.00010.999 5.704 30.5000.000 2.990 838.044.085.688 0.000 45.61 7.25 180.0 8/8/2024 10:24 1.81945.08411.519 5.686 980.56013.459 0.000 0.000 64.3930.00011.004 5.750 30.4180.000 2.971 838.043.875.514 0.000 46.90 7.25 180.0 8/8/2024 10:25 1.99144.94011.504 5.683 980.31013.489 0.000 0.000 64.7360.00010.958 5.747 30.5600.000 2.954 838.044.135.746 0.000 46.93 7.24 180.0 1.69144.92511.475 5.682 976.20113.774 0.000 0.000 63.7850.00011.658 5.758 30.3020.000 2.978 838.0043.7965.548 0.000 46.616 7.273 180.0Avg. 1.39745.38311.481 5.683 975.30413.797 0.000 0.000 63.9370.00011.925 5.740 29.9460.000 2.898 838.0043.3745.706 0.000 46.780 7.250 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 8/8/2024 10:27 0.0001.5020.053 0.012 3.7970.338 0.000 0.000 0.7410.0000.361 0.000 0.1520.069 0.000 838.01.041.330 0.001 1.50 0.00 180.0 Run 3 - A 30minute/60min 8/8/2024 10:29 0.00042.69010.278 5.137 867.01311.031 0.000 0.000 56.3940.00011.149 4.957 28.2840.000 2.891 838.041.095.577 0.000 42.69 6.35 180.0 8/8/2024 10:31 0.94745.10611.474 5.669 973.10213.852 0.000 0.000 63.4620.00010.912 5.777 30.4460.000 2.968 838.044.005.649 0.000 46.05 6.81 180.0 8/8/2024 10:32 2.51244.37211.511 5.673 981.20713.719 0.000 0.000 64.6420.00011.054 5.695 30.6700.000 2.971 838.044.115.559 0.000 46.88 7.01 180.0 8/8/2024 10:33 2.27244.60711.536 5.681 979.88513.569 0.000 0.000 64.7700.00013.409 5.695 30.4770.000 2.960 838.043.955.642 0.000 46.88 7.10 180.0 8/8/2024 10:34 1.52144.49911.557 5.686 979.86713.177 0.000 0.000 65.1210.00011.030 5.673 30.6010.000 2.923 838.044.025.689 0.000 46.02 7.10 180.0 8/8/2024 10:35 1.96744.64811.564 5.702 973.98413.456 0.000 0.000 63.7350.00011.065 5.769 30.5350.000 2.994 838.044.325.934 0.000 46.61 7.19 180.0 8/8/2024 10:36 1.62944.95611.571 5.698 978.88213.598 0.000 0.000 64.3810.00013.441 5.668 30.8810.000 3.014 838.044.525.745 0.000 46.59 7.17 180.0 8/8/2024 10:37 1.37944.32211.606 5.695 977.62113.341 0.000 0.000 64.1640.00011.028 5.689 30.7560.000 2.956 838.044.275.713 0.000 45.70 7.15 180.0 8/8/2024 10:38 0.63244.25211.686 5.697 974.90913.524 0.000 0.000 63.5770.00011.132 5.670 30.4620.000 2.937 838.044.005.830 0.000 44.88 7.16 180.0 8/8/2024 10:39 0.64844.46111.681 5.704 974.95113.362 0.000 0.000 63.4560.00011.175 5.801 30.4490.000 2.969 838.044.225.951 0.000 45.11 7.17 180.0 8/8/2024 10:40 1.42545.68811.660 5.706 971.26613.486 0.000 0.000 63.1570.00011.120 5.712 30.4920.000 2.948 838.044.095.843 0.000 47.11 7.17 180.0 8/8/2024 10:41 0.00045.70111.654 5.705 959.21113.444 0.000 0.000 65.9840.00011.111 5.631 30.7500.000 2.695 838.043.695.693 0.000 45.70 7.17 180.0 8/8/2024 10:42 0.15144.94511.651 5.702 970.13113.382 0.000 0.000 66.1290.00011.163 5.691 30.6910.000 2.694 838.043.755.816 0.000 45.10 7.15 180.0 8/8/2024 10:43 1.25545.99711.660 5.705 967.34113.240 0.000 0.000 62.7700.00011.026 5.682 30.2290.000 3.007 838.043.915.823 0.001 47.25 7.17 180.0 8/8/2024 10:44 1.18145.59411.657 5.716 968.95813.373 0.000 0.000 62.7200.00011.186 5.708 30.5310.000 3.035 838.044.295.833 0.000 46.77 7.18 180.0 8/8/2024 10:45 1.92846.21411.613 5.705 968.69813.121 0.000 0.000 62.7690.00011.117 5.642 30.5370.000 3.026 838.044.275.884 0.000 48.14 7.21 180.0 8/8/2024 10:46 1.74646.15511.533 5.694 970.34013.302 0.000 0.000 62.9040.00010.823 5.744 30.6870.000 3.015 838.044.545.990 0.000 47.90 7.18 180.0 8/8/2024 10:47 0.97345.40411.523 5.690 975.52313.091 0.000 0.000 63.8780.00010.919 5.669 31.0050.000 3.028 838.044.735.842 0.000 46.38 7.22 180.0 8/8/2024 10:48 2.05345.30311.499 5.691 974.64513.177 0.000 0.000 63.3670.00013.386 5.655 30.6710.000 2.955 838.044.275.871 0.000 47.36 7.23 180.0 8/8/2024 10:49 0.95845.43111.435 5.684 971.24913.373 0.000 0.000 63.0320.00010.871 5.724 30.4690.000 2.988 838.044.185.870 0.000 46.39 7.24 180.0 8/8/2024 10:50 0.47545.39911.413 5.683 968.44013.565 0.000 0.000 63.4630.00010.811 5.650 30.4580.000 2.935 838.044.055.937 0.000 45.87 7.22 180.0 8/8/2024 10:51 1.63145.38811.454 5.694 971.14913.382 0.000 0.000 63.3620.00013.356 5.470 30.6210.000 2.982 838.044.225.979 0.000 47.02 7.25 180.0 8/8/2024 10:52 1.80145.72211.444 5.692 973.32213.372 0.000 0.000 64.0410.00010.896 5.631 30.8040.000 3.017 838.044.545.913 0.000 47.52 7.24 180.0 8/8/2024 10:53 1.03146.03311.463 5.707 969.28613.465 0.000 0.000 62.9390.00013.303 5.658 30.4400.000 3.037 838.044.265.957 0.000 47.06 7.25 180.0 8/8/2024 10:54 0.48344.79411.482 5.685 973.42013.562 0.000 0.000 63.9540.00013.641 5.710 30.8560.000 3.016 838.044.716.025 0.000 45.28 7.24 180.0 8/8/2024 10:55 1.84845.38311.494 5.684 970.31213.554 0.000 0.000 63.0310.00011.013 5.662 30.5360.000 3.027 838.044.406.053 0.000 47.23 7.21 180.0 8/8/2024 10:56 0.70344.72811.487 5.681 969.81913.342 0.000 0.000 63.1670.00013.554 5.759 30.4960.000 3.024 838.044.345.927 0.000 45.43 7.22 180.0 8/8/2024 10:57 1.95244.51411.482 5.684 979.87213.511 0.000 0.000 64.6400.00011.058 5.836 31.0430.000 2.941 838.044.815.986 0.000 46.47 7.20 180.0 8/8/2024 10:58 1.34245.81311.453 5.686 971.19513.597 0.000 0.000 63.5150.00010.888 5.733 30.4490.000 2.940 838.044.135.965 0.000 47.16 7.22 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/8/2024 10:59 0.66445.63411.442 5.683 966.76913.421 0.000 0.000 63.1340.00013.337 5.702 30.5360.000 3.030 838.044.456.083 0.000 46.30 7.26 180.0 1.23745.12511.499 5.674 969.07913.346 0.000 0.000 63.5220.00011.666 5.669 30.5290.000 2.964 838.0044.1385.853 0.000 46.362 7.148 180.0Avg. Spike 3 8/8/2024 11:02 0.00061.99010.332 5.590 878.54962.602 0.000 0.000 56.6830.0009.354 7.106 52.0320.000 2.948 838.067.006.503 0.943 61.99 6.63 180.0 Run 3 - B 30minute/60min 8/8/2024 11:04 0.58744.50311.403 5.678 974.00413.722 0.000 0.000 64.0060.00010.745 5.807 31.0040.000 2.951 838.044.906.183 0.003 45.09 7.25 180.0 8/8/2024 11:06 1.56344.55211.367 5.667 978.08113.837 0.000 0.000 64.8930.00013.414 5.779 31.0990.000 2.983 838.044.986.099 0.000 46.12 7.27 180.0 8/8/2024 11:07 1.48045.03811.382 5.672 976.44713.754 0.000 0.000 64.9510.00013.141 5.762 30.9910.000 2.942 838.044.806.130 0.000 46.52 7.25 180.0 8/8/2024 11:08 0.00044.50311.400 5.678 959.63813.685 0.000 0.000 66.4050.00013.234 5.822 31.3130.000 2.748 838.044.635.915 0.000 44.50 7.25 180.0 8/8/2024 11:09 1.40244.97311.406 5.679 977.42813.516 0.000 0.000 64.4190.00013.116 5.671 31.3800.000 3.017 838.045.115.880 0.000 46.38 7.22 180.0 8/8/2024 11:10 0.93844.25811.446 5.685 973.89813.676 0.000 0.000 63.9240.00010.682 5.644 31.0710.000 2.998 838.044.906.110 0.000 45.20 7.26 180.0 8/8/2024 11:11 1.99844.99411.441 5.682 979.80613.407 0.000 0.000 64.7710.00010.913 5.710 31.4570.000 2.996 838.045.376.173 0.000 46.99 7.28 180.0 8/8/2024 11:12 1.24344.41711.458 5.680 975.04013.535 0.000 0.000 64.2530.00010.343 5.698 31.0800.000 3.003 838.045.026.210 0.000 45.66 7.22 180.0 8/8/2024 11:13 1.26544.10011.472 5.671 975.08913.361 0.000 0.000 64.4750.00010.749 5.642 31.1150.000 3.007 838.044.996.143 0.001 45.37 7.22 180.0 8/8/2024 11:14 1.11345.23811.476 5.679 975.20813.401 0.000 0.000 64.1120.00010.790 5.653 30.9280.000 2.968 838.044.706.095 0.000 46.35 7.23 180.0 8/8/2024 11:15 0.21845.39911.474 5.681 972.00413.676 0.000 0.000 66.6160.00010.930 5.819 31.0400.000 2.740 838.044.536.189 0.000 45.62 7.21 180.0 8/8/2024 11:16 1.24144.69311.465 5.675 977.40513.838 0.000 0.000 64.6230.00010.707 5.755 31.4640.000 3.021 838.045.526.261 0.001 45.93 7.25 180.0 8/8/2024 11:17 2.33245.26011.487 5.677 970.09013.821 0.000 0.000 63.0920.00010.880 5.756 30.9550.000 3.091 838.045.046.097 0.000 47.59 7.25 180.0 8/8/2024 11:18 1.16745.00011.489 5.669 965.99713.502 0.000 0.000 63.2860.00010.640 5.789 30.8570.000 3.041 838.044.946.216 0.000 46.17 7.23 180.0 8/8/2024 11:19 1.09144.95511.502 5.677 965.48713.501 0.000 0.000 63.5280.00010.808 5.683 30.9360.000 3.096 838.045.046.184 0.000 46.05 7.20 180.0 8/8/2024 11:20 0.53845.55411.509 5.677 967.04113.367 0.000 0.000 63.3710.00011.186 5.710 30.7750.000 2.991 838.044.876.451 0.000 46.09 7.21 180.0 8/8/2024 11:21 1.80744.35811.486 5.664 980.72013.350 0.000 0.000 66.0520.00010.991 5.813 31.5750.000 2.975 838.045.546.212 0.000 46.16 7.21 180.0 8/8/2024 11:22 1.06043.88511.525 5.672 976.75213.467 0.000 0.000 64.9550.00010.867 5.691 30.9930.000 2.962 838.044.906.290 0.000 44.95 7.22 180.0 8/8/2024 11:23 0.89944.75111.535 5.676 975.90113.483 0.000 0.000 65.1190.00011.141 5.741 31.1980.000 2.973 838.045.166.289 0.000 45.65 7.24 180.0 8/8/2024 11:24 0.18344.91411.571 5.679 968.51113.438 0.000 0.000 66.4510.00010.925 5.694 31.0090.000 2.782 838.044.696.481 0.002 45.10 7.21 180.0 8/8/2024 11:25 0.26444.89611.585 5.690 975.96013.404 0.000 0.000 66.9210.00010.711 5.640 31.4620.000 2.766 838.045.016.379 0.000 45.16 7.18 180.0 8/8/2024 11:26 0.93044.86211.558 5.683 977.57713.439 0.000 0.000 65.1790.00010.741 5.757 31.1450.000 3.022 838.045.236.308 0.000 45.79 7.20 180.0 8/8/2024 11:27 0.62346.00511.549 5.687 971.66313.433 0.000 0.000 63.4870.00010.832 5.820 30.7200.000 3.070 838.045.036.436 0.000 46.63 7.25 180.0 8/8/2024 11:28 1.01344.63811.517 5.680 974.98013.500 0.000 0.000 64.0760.00010.843 5.728 31.1580.000 3.033 838.045.326.419 0.000 45.65 7.23 180.0 8/8/2024 11:29 0.77644.87511.525 5.687 977.94013.585 0.000 0.000 64.7510.00010.942 5.724 31.0400.000 2.966 838.045.046.372 0.000 45.65 7.24 180.0 8/8/2024 11:30 1.18644.47311.545 5.684 979.48213.495 0.000 0.000 65.1150.00013.540 5.784 30.9060.000 2.964 838.044.916.332 0.000 45.66 7.20 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/8/2024 11:31 0.56945.30611.564 5.688 976.90213.634 0.000 0.000 65.1410.00010.890 5.735 31.2050.000 2.950 838.045.296.542 0.000 45.88 7.21 180.0 8/8/2024 11:32 0.97145.82511.551 5.689 970.21313.704 0.000 0.000 63.6720.00013.481 5.860 30.9890.000 2.992 838.045.186.447 0.000 46.80 7.21 180.0 8/8/2024 11:33 0.89146.15211.568 5.679 969.63213.445 0.000 0.000 63.0580.00010.709 5.721 30.7390.000 3.017 838.044.896.455 0.002 47.04 7.17 180.0 8/8/2024 11:34 1.52945.31711.544 5.670 977.94313.462 0.000 0.000 64.5530.00010.793 5.758 31.2710.000 2.992 838.045.416.473 0.000 46.85 7.22 180.0 1.02944.92311.493 5.679 973.89513.548 0.000 0.000 64.6420.00011.323 5.739 31.0960.000 2.969 838.0045.0316.259 0.000 45.953 7.226 180.0Avg. 1.13345.02411.496 5.676 971.48713.447 0.000 0.000 64.0820.00011.494 5.704 30.8120.000 2.966 838.0044.5856.056 0.000 46.158 7.187 180.0Run 3 Avg: Baseline 3 8/8/2024 11:37 0.0000.9600.025 0.000 2.3500.136 0.011 0.000 0.8420.0000.325 0.000 0.0440.120 0.000 838.01.311.902 0.000 0.96 0.00 180.0 Post CTS 8/8/2024 12:17 0.0000.0000.082 0.000 3.9960.521 0.132 0.370 0.4850.0160.000 103.805 0.0300.295 0.176 838.070.491.353 0.000 0.00 0.00 180.0 8/8/2024 12:17 0.0000.0000.060 0.000 2.3720.286 0.056 0.291 0.7750.0000.000 104.286 0.0000.000 0.225 838.070.951.451 0.000 0.00 0.00 180.0 8/8/2024 12:17 0.0000.0000.053 0.013 0.8030.412 0.000 0.073 0.3280.0090.000 104.697 0.0000.598 0.106 838.070.530.776 0.000 0.00 0.07 180.0 8/8/2024 12:17 0.0000.0000.044 0.007 1.1090.282 0.000 0.000 0.2220.0000.000 104.522 0.1990.361 0.040 838.070.631.000 0.002 0.00 0.57 180.0 Post NO2/Mid O2 8/8/2024 12:20 101.1551.6970.005 0.000 1.5280.135 0.819 0.055 0.5730.0680.000 0.000 0.0000.650 0.000 839.00.530.793 0.000 102.85 10.12 180.0 8/8/2024 12:20 101.3662.453-0.000 0.000 1.5710.029 0.749 0.116 0.8890.0740.000 0.000 0.0000.621 0.000 840.00.751.121 0.001 103.82 10.11 180.0 8/8/2024 12:20 101.0670.932-0.000 0.000 1.7780.000 0.752 0.000 0.5910.0020.043 0.000 0.0000.613 0.000 840.00.210.314 0.002 102.00 10.19 180.0 Post 5-Gas 8/8/2024 12:23 0.000249.4410.008 4.764 3.378505.568 1.107 2.278 9.3390.0191.391 1.111 252.2210.000 0.000 845.0255.393.640 10.100 249.44 0.00 180.0 8/8/2024 12:23 0.000250.7970.001 4.767 3.290503.819 1.149 1.974 9.8900.2800.982 1.097 251.7480.208 0.000 845.0255.374.335 10.104 250.80 0.00 180.0 8/8/2024 12:23 0.000249.1930.012 4.792 2.879508.331 1.146 2.088 8.8870.0550.133 1.038 251.1550.637 0.000 845.0253.632.676 10.104 249.19 0.00 180.0 8/8/2024 12:23 0.000249.9080.002 4.753 4.734504.228 1.156 2.251 9.5160.0430.738 0.993 252.4260.000 0.000 845.0255.433.515 10.119 249.91 0.00 180.0 End of Test Purge 8/8/2024 12:26 0.0001.1940.002 0.001 0.7470.570 0.013 0.000 0.1210.0151.065 0.000 0.3290.145 0.000 846.01.031.058 0.006 1.19 0.00 180.0 8/8/2024 12:26 0.0001.495-0.000 0.000 0.8960.418 0.000 0.184 0.5430.0011.075 0.000 0.2110.280 0.000 846.00.710.745 0.011 1.49 0.00 180.0 8/8/2024 12:26 0.0000.7460.003 0.000 0.8770.719 0.002 0.178 0.3960.0000.926 0.014 0.0980.243 0.000 846.00.270.240 0.003 0.75 0.00 180.0 8/8/2024 12:26 0.0000.4750.007 0.000 0.9780.501 0.004 0.036 0.2350.2130.751 0.000 0.2180.000 0.000 846.00.840.935 0.001 0.47 0.00 180.0 8/8/2024 12:26 0.0000.692-0.000 0.000 0.6900.460 0.000 0.401 0.2450.0001.400 0.000 0.3100.116 0.000 846.00.840.799 0.005 0.69 0.00 180.0 8/8/2024 12:26 0.0001.1950.004 0.000 0.3260.548 0.003 0.218 0.2160.0241.159 0.000 0.2710.192 0.000 846.00.820.820 0.005 1.19 0.00 180.0 8/8/2024 12:27 0.0001.2010.011 0.000 0.4540.422 0.000 0.246 0.2910.0000.900 0.000 0.2710.519 0.000 846.00.810.810 0.000 1.20 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 8/8/2024 12:27 0.0000.2900.015 0.000 0.3310.466 0.000 0.144 0.1390.0830.000 0.000 0.1330.332 0.042 846.00.770.824 0.000 0.29 0.00 180.0 8/8/2024 12:27 0.0000.349-0.000 0.000 0.3170.064 0.002 0.180 0.0000.0000.236 0.000 0.2110.000 0.000 846.00.600.579 0.002 0.35 0.00 180.0 GAS, Inc.