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HomeMy WebLinkAboutDRC-2006-001221 - 0901a068808550e9Co-ExecutiveBecretary Utah Water Quality Board I t t I Permit No. UGW370004 STATE OF UTAH DMISION OF WATER QUALITY DEPARTMENT OF ENVIRONMENTAL QUALITY UTAH WATER QUALITY BOARD SALT LAKE CMY, LITAH 84114-4870 GROUND WATER DISCHARGE PERMIT In corapliancc with the piovisions of the Utah Water Quality Act, Title 19, Chapter -5, Utah Code Annotated 1953, as amended, the Act, International Uranium OSA) Corporation Independence Plaza, Suite 950 1050 17th Street Denver, Colorado 80265 is granted a ground water discharge permit for the operation of a uranium milling and tailings disposal facility located approximately 6 miles south of Blanding, Utah. The facility is located on a tract of land in Sections 28,29,32, and 33, fownship 37 South, Range 22Bas,t, Salt I.ake Base and Meridian, San Juan County, Utah. The permit is based on representations made by the Permittee and other information contained in the administrative record. It is the responsibility of the Permittee to read and understand all provisions of this permit. The milling and tailings disposal facility shall be operated and revised in accordance with conditions set forth in the permit and the Utah Ground Water Quality Protection Regulations. I I I I II I i I I I I i t t This permit shall become ettect;ue 7t*nl I%IQL This permit shall expire MA&!._E-.2OlQ. I t I I I t I I I I I t I I T t I I I Table of Contents PART I. SPECIFIC PERMIT CONDITIONS ............ ........... 1A. GnouNnWArERCressrrcerroN............... .................. 1B. BacrcnoulroWnrsnQuelrrv... ............... 1C. Penrwr Lnnrs .........21. Ground Water Compliance Limits.... ......22. Tailings Cell Operations........... ..............23. Prohibited Discharges ...........2D. DscruncB Mn'uvuzeuoN Tecm{orocy SreNoARD........... .......... g 1. DMT Design Standards for Existing Tailings Cells 2, and 3......... ............... g2. Existing Tailings Cell Construction Authorized ..... 103. Existing Facility DMT Performance Standards................ ........ 104. Best Available Technology Requirements for New Construction................................ 115. Definition of 11e.(2) Wasre ..................126. Closed Cell Performance Requirements .................127. Facility Reclamation Requirements........... ..-..........128. Stormwater Management and Spill Control Requirements.......... ..............12E. Gnoulto Weren CotwrnNcE AND Tecrworocy PBnronuaNcn Mowrronnqc............. 131. Routine Groundwater Compliance Monitoring............... ......... 132. Groundwater Head Monitoring .............143. Groundwater Monitoring:Well Design and Construction Criteria................................ 144. Monitoring Procedures for Wells.. ........ 145. White Mesa Seep and Spring Monitoring ............... 156. DMT Performance Standard Monitoring ................ 157. On-site Chemicals Inventory.. ............... 168. Tailings Cell Wastewater Quality Monitoring ........ 16F. RpponrnrcRrqum.nunNTs........... ............ 161. Routine Groundwater Monitoring Reports ............. 162. Routine DMT Performance Standard Monitoring Reports..... .................... 173. DMT Performance Upset Reports..... ....174. Other Information .""............175. Groundwater Monitoring Well As-Built Reports ..................... 176. White Mesa Seep and Spring Monitoring Reporrs ................... lg7. Chemicals Inventory Report ................. 1g8. Tailings Cell Wastewater Quality Reports..... ......... lg9. Revised Hydrogeologic Report ............. 1gG. OurorCorwrreNcEsrATus.. .................. 1g1. Accelerated Monitoring Status........ ...... lg2. Violation of Permit Limits .................... 193. Failure to Maintain DMT Required by Permit.. ....". 194. Facility Out of Compliance Status ........205. Accelerated Monitoring Status for New Wells .......20H. CorprmNcE ScrGDUr-E Rrqummmlrrs. .............. .....2O1. Installation of New Groundwater Monitoring Wells ....."..........202. Revised Hydrogeologic Report .............213. Background Ground Water Quality Report: Existing We11s........ ."..."........214. Background Groundwater Quality Report: New Monitoring wells ..".......225. Tailings Cells Wastewater Quality Sampling P1an.......... "........236. Monitoring Well Remedial Construction and Repair Work Plan and Report ........."....23 7 . Monitoring Well MW-3 Verification, Retrofit, or Reconstruction Report....... ......".....24 i I I I t t t T I I I I t I I I T t t I 8. white Mesa Seeps and Springs Sampling work plan and Report....... .......249. On-site Chemicals Inventory Report...... .................2410. Infiltration and Contaminant Transport Modeling Work Plan and Report...... .........2511. Plan forEvaluation of Deep SupplyWell WW-2............... ....................2612. DMT Monitoring P1an......... .............2613. Tailings cell 4A contaminant Removar Schedule and Report ..............2614. Tailings Cell 4A Redesign and Reconstruction ....................2715. Contingency Plan ............2716. Stormwater Best Management Practices plan ......... .............2717. Roberts Pond As-Built Report ..........2g18. Tetrahydrofuran Demonstration Study work plan and Report....... ........2g PART tr. REPORTING REQUIREMENTS.... ....2gA. RgpREssNterrvE SAIvIpLtr{c ..-.2gB. ANaryucer h.ocrounBs. .............. .........2gC. PSNALTmS ponTalvppnwc............... ........2gD. RsponrhrcorMoxrronwcRBsu_rs .......2gE. CorwueNcs Scrmourns ............... ...........2gF. ApomoNar Moxrronnqc By rr{E psRr[rrEE ............29G. Rrconns Con'rnr.rrs. ...............2gH. Rrrexrrox orRrconos................ ............2gI. NoucrorNoNcorwrreNcpReponrtrrc............... .....30J. Ornen NoNcotwueNcr Rsponrnlc............... ........... 30K. INsprcrroNANDENTRy ...........30 PART m. COMPLIANCE RESPONSIBILITIES........... ...... 31A. Dury ro Corwry .................... 31B. PrNerrmsroRVrorerroNsorprnrwrCouprrroNs............... .....31C. NrroroHerroRRBoucpAcmrrryNoreDrrnNsE............. ..... 3lD. DuryroMrucers ..................31E. Pnoprn OprnenoN eNp MenrrENANCE....... .............. 3l PART ry. GENERAL REQUIRErVIENTS.......... ..................32A. PremNrpCueNcns .................32B. Avncperrp NoNcorwtreNcE................ ...................32C. PsRN[rAcnoNs.... ..................32D. DuryroRreppry............... ....32E. Dury ro PRovns IuronuauoN ............ ....................32F. Orrmn lNronuauoN............. ....................32G. SrcNerony Rlqum.nvmNTs ........... ...........32H. PeNerrres ron FersrrcATroN orReponrs............... ................... 33I. Av^q,nesLrry opRppoRrs................ ........ 33J. PRopnnryRrcHrs ...................33K. SrvnRannrry ........33L. TneNsrnns ............33M. Srerel.ews ..........34N. RsopnNEn Pnovrs1oNs................ ..............34 List of Tables Table 1. Ground Water Classification ........... ......... I Table 2. Groundwater Compliance Limits............... ................3 Table 3. DMT Engineering Design and Specifications ........... g Table 4. Feedstock Storage Area Coordinates ......... .............. 1l Table 5. Groundwater Monitoring Repoting Schedule... ...... 16 I t t t I t t t i t I I I Part I permit No. UGW370004 PAR.T I. SPECIFIC PERMIT CONDITIONS A. GnornnWarrn ClessmcerloN - the ground water classification of the shallow aquifer under the tailings facility has been determined on a well-by-well basis, as defined in Table l, below: l) Based on historic total dissolved solids (TDS) rlata provided by IUC forperiod between October, 1979 and May, 1999. Average concentrations calculated by Utah Division of Radiatim Control (DRC) saff in a November 29, 1999 memorandum. 2) Based on average ofDRC split sarnples collecEd from the IUC facility benrecn May, 1999 and Septcmber, 2002. 3) Number of IUC or DRC samples used in the evaluation of average TDS concentsations. 4) Classificatioa of IUC well MW-19 based on the conservatively lower IUC data. 5) Welts MW-20.and MW-22 are not poiot of compliance monitoring wells, but instead are groundwater head monito,ring wells as per part I.8.2.6) Well MW-26 was originally named TW4-15 and was insalled as a part of a recent chloroform contaminant investigation at the facility. Under this Permit, MW-26 is defined as a Point of Compliance (POC) well for the ailings cells (see Pan I.E.l) . 7) well Tw4-16'was installed as a part of a recent chlorofomr investigation at the facility, and has been included in the permit as groundwater headmonitoringwe[(PartLE.2). GroundwaterclassificationprovidedherebasedonaverageofboththelUCandDRCdaa(2samples). 8) Well MW-32 was originally named ?xN+17 and was installed as a part of a rccetrt chlorofonn contaminant investigation at rhe facitity. Underftis Permit it is included as a PIOC well for the railings cells in part I.E.l. B. Becrcno{rND WersR Quarrrv - background groundwater quality will be determined on a well-by-well basis, as defined by the mean plus second standard deviation concentration. AfterExecutive Secretary approval of the Background Groundwater Quality Reports required by Part I.H.3 and 4, this permit will be re-opened and Table 2 revised to define background concentrations and groundwater compliance limits for all required contaminants. t I I I Table l. Ground Water Classification Class II Groundwater Class III Groundwater Well ID Averase TDS (meA) Well ID Averaqe TDS (mpll) IUC Data DRC Data IUC Data DRC Data (" Avg. Conc.(l) No. of Data(3) Avg. Conc.@) No. of DataG) Avg. Conc.(l) No. of Data(o Avg. Conc.@) No. of Data(3) Historic IUC Monitoring Wells MW-l t-276 68 r.268 4 MW-2 3,031 67 3,103 4 MW-5 2,081 69 2,068 4 MW-3 5,2W 67 5.289 4 MW-lt t-834 50 2.039 4 MW-12 3,939 50 3,756 4 MW-I8 2,545 9 2.61t 4 MW-14 3.582 30 ].589 4 MW-19(",2,697 9 3,120 4 MW-15 3,855 30 3.847 4 MW-20(,,2,977 I nla 0 MW-17 4,539 l1 4,542 4 NfiN-22r')5,105 I nla 0 Beqq4.t IUC Monitoring Wells MW-26("3,120 I 3.206 I TW4-16r"2,930 I 3,430 I MW-32(o)3.190 I 3,650 I Foohotes: Part I Prnrvrrl;nrrs - the permittee shall compty with the forowing r"ir"ffi:$fo ucw370o04 l. Ground Water Compliance Limits - contaminant concentrations measured in each monitoring well shall not exceed the Ground Water Compliance Limits (GWCL) definedin Table 2, below. Ground water quality at the site must at all times meet all the applicable GWQS and ad hoc GWQS defined in R317-6 even though this permit does not require monitoring for each specific contaminant. 2- Tailings Cell Operations - only ll.e.(2) by-product material authorized by Utah Radioactive Materials License No. UT-2300478 (hereafter License) shalibe discharged toor disposed of in the tailings ponds. l. Prohibited Discharges - discharge of other compounds such as paints, used oil, antifreeze, pesticides, or any other contaminant not defined as ie.(2) material is prohibited. t1U Bo rn.E J Lr(l) GI BIJtr oo oi (l) ,oGtt- ll =o Jr rDIa r- F II * i I t t i t t iti I i t i I I t) Erl !)()trGI (l) cl >13 =olio do tro(-) c\o ..oRI F< o \)E G s 4 q) L = ll B IF()r; li,E t t t I t t t I t t t I I l I F]U Bo (A H ;I !)otrcl c) (tl B€ =ol-r() 'ci!)atr troU No -oCdFr ll =o TEor; l- E Ixe I t t t t I t t i; I t I l I \o 3U (n Erl c)(J 6l =o EoU an (! F oBo 6 lrr F F U o B Ssl EI$lLI EI trL Ct BSI EBI $l>t >J>tllI$lEl tr ,C4F or0F olcEle tr-olc FIE /I trL !aL ctrF E EL t SUiq VrlUI odslol\tBIo<l le I aoo N oAr olUI a., Islslsol q, I blGI sl {q) o IF AlaF &F trL iF v) F 6o .F d *5 L;(:lc,t alcEIE t trL mF odtF trL -cEF 4 AlaF EL I L olaF t ooF trL olaF I mL CtrL I,or0F tcL Et-trL trt-I tr U- EGo o!oF 'l) sT =E E B(, ooF o L CtrL lI trL tr2 CEF !I a oEF oe EL ,F mL olaF T trL CtrL tr? olaF ,olat-F F I trL ocaF T tr,a otoF I trL oElF a do = Iac B InN !i T Irtt IE i 3,c 3 8 - €E ut !l n \a{.i I I G !+ C! 6 ot) 2 G o z +o dJI Z oEo E o! E E J Ee E6s o oE E troE! o o oz E aoo 7D o U) Ed E EdtrG a N oEooq{ (,) E0NE0a vgl otroEdtT N GE ct oF o U E eooEO {,)tr6 o EooEoa oEo6EEEdz ad o 6 6 a oEo oF Gc oeo x - q EEoT d E oE o E dF oE otJ d E o d a,J) d E U)oF () cl B€tr o o troU 6l q)p GIF l=o tE la ,: .E l1 E t I t i I t t t rl I t I t t I i= rETE E EEI; fl EE !'=,ii?$I g,EE EE E iEEEEEEEI ESEE EIE Ei SEEE E?i E-I aE$sEggH sg !iggggiggEgE !gggEgEEtgEre igEEEEEEB$,EEE | .ErrrsEEgg5igI H::::::" aae 1) 2) 3) i I I I I I I I I I I I I I i I i I I Part I Permit No. UGW37OOO4 D. Dlscuenar lv{nmruATroN Tucrryorocy STANDARD - the tailings disposal facility must be built and operated according to the following Discharge Minimization Technology (DMT) standards: l. DMT Design Standards for Existing Tailings Cells 1, 2, and 3 - shall be based on existing construction as described by design and construction information provided by the Permittee, as summarized in Table 3 below for Tailings Cells 1,2, and3: l) D'Appolonia Cmsultiug Engrneers, Inc., June, 199, "Engineers Reprt Tailings Mamgemetrt System White Mesa Uranium hoject Blaoding, Utah Energy Fuels Nuclear, Inc. Denver, Colmado", unpubHshed consultants reporq approximately 50 pp., 2 figurcs, 16 sheets, 2 appendices. D'Appolmia Consulting Engineen, Inc., February, 1982, "Constuction Re,port Initial Phase - Tailings Mauageme.nt System White Mesa Uranium Project Blanding, Utah Euergy Fuels Nucleat Inc. Denver, Colorado", unpublished consultatrts rcport approxirnately 7 pp., 6 tables, 13 figures, 4 appendices. D'Appolonia Cousulting Eogineers, Inc., May, 1981, "Engineer's Report Second Phase Design - Cell 3 Tailings Management SysEm White Mesa Uraaium Project Blanding, Utah Energy Fuels Nuclear, hc. Denver, Colmado'', unpublished consultents reput, approximately 20 pp., I figure,5 shees, 3 appendices. Energy Fuels Nuclear, Inc., March, 1983, 'Consruction Report Second Phase Tailings Maqagement System White M€sa Uranium Project Energy Fuels Nuclear, Inc.", uupublished compauy repor! l8 pp., 3 tables,4 figures, 5 appendices. a) Tailings Cell I - consisting of the following major design elements: Cross-valley Dike and East Dike - constructed on the south side of the pond of native granular materials with a 3:1. slope, a 20-foot crest width, and a crest elevation of about 5,620 ft above mean sea level (amsl). A dike of similar design was constructed on the east margin of the pond, which forms a continuous earthen structure with the south dike. The remaining interior slopes arc cut-slopes at 3:l grade. Liner System - including a single 30 mil PVC flexible membrane liner (FI\[) constructed of solvent welded seams on a prepared sub-base. Top elevation of the FML liner was 5,618.5 ft amsl on both the south dike and the north cut-slope. A protective soil cover layer was constructed immediately over the FML with a thickness of l2-inches on the cell floor and 18-inches on the interior sideslope. Crushed Sandstone Underlay - immediately below the FML a nominal 6-inch thick layer of crushed sandstone was prepared and rolled smooth as a FML sub- base layer. Beneath this underlay, native sandstone and other foundation materials were graded to drain to a single low point near the upstream toe of the south cross-valley dike. Inside this layer, an east-west oriented pipe was installed Table 3. DMT neering Desisn and Specifications Tailings Cell Repon Tvoe Eneineerine Report Desisn Fisures Construction Soecifications Cell I Design June, 1979 D'Appolonia Consultins Ensineers. Inc (1) Appendix A, Sheets 2,4,8, 9,12-15 Appendix B Cell2 Design Iune, 1979 D'Appolonia Consultins Eneineers. Inc (l)Appendix A, Sheets 2,4,'7- 10, 12-15 Appendix B As-Built February, I 982 D'Appolonia Consultine Ensineers. Inc (2) Figures 1,2, and l1 N/A Cell3 Design May, 1981D'Appolonia Consultins Ensineers. Inc €) Sheets 2-5 Appendix B As-Built March, 1983 E:rergy Fuels Nuclear.Inc. (a) Figures l-4 N/A Footnotes: tl lll l Part I Permit No. UGW370004 to gather fluids at the upstream toe of the cross-valley dike. b) Tailings cell2 - which consists of the following major design elements: l) Cross-valley Dike - constructed at the south margin of Cell 2 of native granular materials with a 3:1 slope, a 20-foot crest width, and crest elevation of about 5,615 ft amsl. The east and west interior slopes consist of cut-slopes with a 3:l grade. The Cell 1 south dike forms the north margin of Cell 2, with a crest elevation of 5,620 ft amsl. 2) Linet System - includes a single 30 mil PVC FML liner constructed of solvent welded seams on a prcparcd sub-base, and overlain by a slimes drain collection system. Top elevation of the FML liner in Cell 2 is 5,615.0 ft and 5,613.5 ft amsl on the north and south dikes, respectively. Said Cell2EML liner is independent of all other disposal cell FML liners. Immediately above the FML, a nominal 12- inch (cell floor) to l8-inch (inside sideslope) soil protective blanket was constructed of native sands from on-site excavated soils. 3) Crushed Sandstone Underlay - immediately below the FML a nominal 6-inch thick layer of crushed sandstone was prepared and rolled smooth as a FML sub- base layer. Beneath this underlay, native sandstone and other foundation materials were graded to drain to a single low point near the upstream toe of the south cross-valley dike. Inside this layer, an east-west oriented pipe was installed to gather fluids at the upstream toe of the cross-valley dike. 4) Slimes Drain Collection System immediately above the FML a nominal l2-inch thick protective blanket layer was constructed of native silty-sandy soil. On top of this protective blanket, a network of 1.S-inch PVC perforated pipe laterals was installed on a grid spacing interval of about 50-feet. These pipelaterals gravity drain to a 3-inch diameter perforated PVC collector pipe which also drains toward the south dike and is accessed from the ground surface via a24-inch diameter, vertical non-perforated IpPE access pipe. Each run of lateral drainpipe and collector piping was covered with a 12 to l8-inch thick berm of native granular filter material. At cell closure, leachate head inside the pipe network ,ritt U" removed via a submersible pump installed inside the 24-inch diameter IIDpE access pipe. c) Tailings cell 3 - consisting of the following major design elements: l) Cross-valley Dike - constructed at the south margin of Cell 3 of native granular materials with a 3:l slope, a 20-foot crest width, and a crest elevation of 5,610 ft amsl. The east and west interior slopes consist of cut-slopes with a 3:1 grade. The Cell 2 south dike forms the north margin of Cell 3, with a crest elevation of 5,615 ft amsl. 2) Linet System - includes a single 30 mil PVC FML liner constructed of solvent welded seams on a prepared sub-base, and overlain by a slimes drain collection system. Top elevation of the FML liner in Cell 3 is 5,613.5 ft and 5,608.5 ft amsl on the north and south dikes, respectively. Said Cell 3 FML liner is independent of all other disposal cell FML liners. 3) Crushed Sandstone Underlay - immediately below the FML a nominal 6-inch 9 il I t i I I I t t i t t I i t 3. t t I t t I I t t t t tI t t t I t t t Part I Permit No. UGW370004 thick layer of crushed sandstone was preparcd and rolled smooth as a FML sub- base layer. Beneath this underlay, native sandstone and other foundation materials were graded to drain to a single low point near the upstream toe of the south cross-valley dike. krside this layer, an east-west oriented pipe was installed to gather fluids at the upstream toe of the cross-valley dike. 4) Slimes Drain Collection Layer and System - immediately above the FML, a nominal l2-inch (cell floor) to l8-inch (inside sideslope) soil protective blanket was constructed of native sands from on-site excavated soils (707o) and dewatered and cyclone separated tailings sands from the mill (307o). On top of this protective blanket, a network of 3-inch PVC perforated pipe laterals was installed on approximately 5O-foot centers. This pipe network gravity drains to a 3-inch perforated PVC collector pipe which also drains toward the south dike, where it is accessed from the ground surface by a l2-inch diameter, inclined IIDPE access pipe. Each run of the 3-inch lateral drainpipe And collector pipe was covered with a 12 to l8-inch thick berm of native granular filter media. At cell closure, leachate head inside the pipe network will be removed via a submersible pump installed inside the l2-inch diameter inclined access pipe. Existing Tailings Cell Construction Authorized - tailings disposal authorized by this permit is limited to those existing tailings cells defined in Table 3 and Part I.D.l, above. Authorized operation and maximum disposal capacity in each of the existing tailings cells shall not exceed the levels authorized by the License. Under no circumstances shall the freeboard be less than three (3) feet, as measured from the top of the FML. Any modification by the Permittee to any approved engineering design parameter at these existing tailings cells shall require prior Executive Secretary approval, modification of this Permit, and issuance of a construction permit. Existing Facility DMT Performance Standards - the Permittee shall operate and maintain certain mill site facilities and the existing tailings disposal cells to minimize the potential for wastewater release to groundwater and the environment, including, but not limited to the following'additional DMT compliance measures: a) DMT Monitoring Wells at Tailings Cell I -at all times the Permittee shall operate and maintain Tailings Cell I to prevent groundwater quality conditions in any nearby monitoring well from exceeding any Ground Water Compliance Umit established in Table 2 of this Permit. b) Tailings Cells 2 and 3 - including the following performance criteria: l) Slimes Drain Maximum Allowable Head - the Permittee shall at all times maintain the average wastewater head in the slimes drain access pipe to be as low as reasonably achievable in each tailings disposal cell, in accordance with a DMT Monitoring Plan approved by the Executive Secretary pursuant to Part I.H.13 of this Permit. For Cell 3, this requirement shall apply after initiation of de-watering operations. 2) Maximum Tailings Waste Solids Elevation - upon closure of any tailings cell, the Permittee shall ensure that the maximum elevation of the tailings waste solids does not exceed the top of the FML liner. l0 c) d) I t I I I I I I I t t ,l I l Part I Permit No. UGW37OO04 3) DMT Monitoring Wells - at all times the Permittee shall operate and maintain Tailings Cells 2 and 3 to prevent groundwater quality conditions in any nearby monitoring well from exceeding any Ground Water Compliance Limit established in Table 2 of this Permit. Roberts Pond -the Permittee shall operate this wastewater pond so as to provide a minimum 2-foot freeboard at all times. Under no circumstances shall the water level in the pond exceed an elevati on of 5,624 feet amsl. In the event that the wastewater elevation exceeds this maximum level, the Permittee shall remove the excess wastewater and place it into containment in Tailings Cell 1 within 72 hours of discovery. At ttle time of mill site closure, the Permittee shall reclaim and decommission the Roberts Pond in compliance the final Reclamation Plan approved under the License (hereafter Reclamation Plan). Feedstock Storage Area -open-air or bulk storage of all feedstock materials at the facility awaiting mill processing shali be limited to the eastern ponion of the mill site area described in Table 4, below. Storage of feedstock materials at the facility outside this area, shall be performed and maintained only in closed, water-tight containers. At the time of mill site closure, the Pernrittee shall reclaim and decommission the Feedstock Storage Area in compliance with an approved Reclamation Plan. Table ates (l) Fmhote: I ) lpprffi ginning from the €xtreme northeast comer atrd progressing 4. Feedstock Storage Area Coorcltn Corner Northins (ft)Eastine (ft) Northeast 323,595 2,580,925 Southeast 322.140 2.580.920 Southwest 322,140 2.580.420 West I 322.815 2.580-410 West 2 323,O40 2.580,085 West 3 323,120 2,580,085 West 4 323,315 2,580,285 West 5 323,415 2,579,990 Northwest 323,600 2.579.990 State Plane Coddinates beginning from the i I i I l clo"k*ire around the feedstock area (from 6/2?01 IUC Response, Attachment I( Site Topographic Map' Revised June, 2fi)1.) e) Mill Site Chemical Reagent Storage - for all chemical reagents stored at existing storage facilities and held for use in the milling process, the Permittee shall provide secondary containment to capture and contain all volumes of reagen(s) that might be released at any individual storage area. Response to spills, cleanup thereof, and required reporting shall comply with the provisions of an approved Emergency Response Plan as found in an approved Stormwater Best Management Practices Plan, stipulated by Parts I.D.8 and I.H.17 of this Permit. For any new construction of reagent storage facilities, said secondary containment and control shall prevent any contact of the spilled or otherwise released reagent or product with the ground surface. 4. Best Available Technology Requirements for New Construction - any construction, modification, or operation of new waste or wastewater disposal, treatment, or storage facilities shall require submittal of engineering design plans and specifications, and prior Executive Secretary review and approval. All engineering plans or specifications ll Il Il I Part I Permit No. UGW370004 submitted shall demonstrate compliance with all Best Available Technology requirements stipulated bythe Utah Ground Water Quality Protection Regulations (UAC R317-6). Upon Executive Secretary approval, a Construction Permit may be issued, and this Permit may be re-opened and modified to include any necessary requirements. Definition of 1le.(2) Waste - for purposes of this Permit , lle.(2) waste is defined as: "... tailings or wastes produced by the extraction or concentration of uranium or thorium from any ore processed primarily for its source material content", as defined in Section f 1e.(2) of the U.S. Atomic Energy Act of '1,954, as amended; which includes other process related wastes and waste streams described by a March 7,2003 NRC letter from Paul H. Lohaus to William J. Sinclair. Closed Cell Performance Requirements - before reclamation and closure of any tailings disposal cell, the Permittee shall ensure that the final design, construction, and operation of the cover system at each tailings cell will comply with all requiremerrts of an approved Reclamation Plan, and will for a period of not less than 200 years meet the following minimum performance requirements: Minimize infiltration of precipitation or other surface water into the tailings, including, but not limited to the radon barier, and Prevent the accumulation of leachate head within the tailings waste layer that could rise above or over-top the maximum FML liner elevation internal to any disposal cell, i.e. create a "bathtub" effect. Ensure that groundwater quality at the compliance monitoring wells does not exceed the Ground Water Quality Standards or Ground Water Compliance Limits specified in Part I.C.l and Table 2 of this Permit. Facility Reclamation Requirements - upon commencement of decommissioning, the Permittee shall reclaim the mill site and all related facilities, stabilize the tailings cells, and construct a cover system over the tailings cells in compliance with all engineering design and specifications in an approved Reclamation Plan. The Executive Secretary reseryes the right to require modifications of the Reclamation Plan for purposes of compliance with the Utah Ground Water Quality Protection Regulations, including but not limited to containment and control of contaminants, or discharges, or potential discharges to Waters of the State. Stormwater Management and Spill Control Requirements - the Permittee will manage all contact and non-contact stormwater and control contaminant spills at the facility in accordance with an approved Stormwater Best Management Practices Plan, purcuant to Part I.H.l7 of the Permit. Said plan shall include provisions to adequately: Protect groundwater quality or other waters of.the state by design, construction, and/or active operational measures that meet the requirements of the Ground Water Quality Protection Regulations found in UAC R3l7-6-6.3(G) and R317-6-6.4(C), Prevent, control and contain spills of stored reagents or other chemicals at the mill site, c) Cleanup spills of stored reagents or other chemicals at the mill site immediately upon discovery, t2 a) b) c) a) b) 5. 6. 7. 8. tij il I I il t t I i t I i d t t t II II I i I t t II Part I Permit No. UGW37m/O4 d) Report reagent spills or other releases at the mill site to the Executive Secretary in accordance with UAC 19-5-114. Reconstruction of stormwater management and/or chemical reagent storage facilities, existing at the time of original Permit issuance, may be required by the Executive Secretary after occurrence of a major spill or catastrophic failure, pursuant to Part tV.N.3 of this Permit. E. GnouNo.Wlrrn CotwrreNcE AND TEcnxorocy PERFoRMANCE Mor.rroRn\G - beginning with the effective date and lasting through the term of this permit or as stated in an approved closure plan, the Permittee shall sample groundwater monitoring wells, monitor groundwater levels, monitor water levels of process solutions, and monitor ura rc"p records of the operation of the facility, as follows: l. Routine Groundwater Cornpliance Monitoring - the Permittee shall monitor upgradient, lateral gradient, and downgradient ground water monitoring wells completed in the shallow aquifer in the vicinity of all potential discharge sources that could affect local groundwater conditions at the facility, as follows: a) Quarterly Monitoring - the Permittee shall monitor on a quarterly basis all monitoring wells listed in Table 2 of this Permit where local groundwater average linear velocity has been found by the Executive Secretary to be equal to or greater than l0 feeUyear. For purposes of this Permit, quarterly monitoring is required at the following wells: 1) Upgradient Wells: none 2) Lateral or Downgradient Wells: MW-I1, MW-14, MW-26 (formerly TW4-15), and MW-32 (formerly TW4-17). b) Semi-annual Monitoring - the Permittee shall monitgr on a semi-annual basis all monitoring wells listed in Table 2 of this Permit where local groundwater average linear velocity has been found by the Executive Secretary to 6e less than l0 feet/year. For purposes of this Permit, semi-annual monitoring is required at the following wells: l) Upgradient Wells: Nf\V-l, MW-18, and MW-19, 2) lateralor Downgradient Wells: MW-2, MW-3, MW-5, MW-12, MW-15, and MW_17, c) Compliance Monitoring Parameters - all groundwater samples collected shall be nalyzed for the following parameters: 1) Field Parameters -depth to groundwater, pH, temperature, and specific conductance. 2) LaboratoryParameters i. GWCL Parameters - all contaminants specified in Table2. General Inorganics -+hloride, sulfate, carbonate, bicarbonate, sodium, potassium, magnesium, calcium, and total anions and cations. d) Special Provisions for Groundwater Monitoring - the Permittee shall ensure that all t3 I i t t t t t t t t 2) 3) b) c) t I ! I t I T T I I I t I I t I I t t Part I Permit No. UGW370004 groundwater monitoring conducted and reported complies with the following requirements: 1) Depth to Groundwater Measurements - shall always be made to the nearest 0.01 foot. Minimum Detection Limits - all groundwater quality analyses reported shall have a minimum detection limit or reporting limit that is less than its respective Ground Water Compliance Limit concentration defined in Table 2. Gross Alpha Counting Variance - all gross alpha analysis reported shall have a counting variance that is equal to or less than 20vo of the reported activity concentration. 2. Groundwater Head Monitoring - on a quarterly basis and at the same frequency as groundwater monitoring required by Part I.E.1, the Permittee shall measure depth to groundwater in the following wells and/or piezometers: a) Pointof ComplianceWells-identifiedinTable 2and,PartI.E.1 of thispermit, b) Piezometers - P-1, P-2,P-3,P-4,P-5. c) Existing Monitoring Wells - MW-20 andNNV-22. d) Contaminant Investigation Wells: any well required by the Executive Secretary as a part of a contaminant investigation or groundwater corrective action, and e) Any other wells or piezometers required by the Executive Secretary. 3- Groundwater Monitoring Well Design and Construction Criteria - all new groundwater monitoring wells installed at the facility shall comply with the following design and construction criteria: a) Located as close as practical to the contamination source, tailings cell, or other potential origin of groundwater pollution, Screened and completed in the shallow aquifer, Designed and constructed in compliance with UAC R317-6-6.3(I)(6), including the EPA RCRA Ground Water Monitoring Technical Enforcement Guidance Document, 1986, OSWER-9950.1. d) Aquifer tested to determine local hydraulic properties, including but not limited to hydraulic conductivity. 4. Monitoring Procedures for Wells - beginning with the date of Permit issuance, all monitoring shall be conducted by the Permittee in conformance with the following procedures: a) Sampling - grab samples shall be taken of the ground water, only after adequate removal or purging of standing water within the well casing has been performed. b) Sampling Plan - all sampling shall be conducted to ensure collection of representative samples, and reliability and validity of groundwater monitoring data. All groundwater sampling shall be conducted in accordance with the currently approved Groundwater Monitoring Quality Assurance plan. L4 c) d) e) a) b) c) d) 6. I I I I I T T I T T T I T t I t I t I Part I Permit No. UGW370004 Laboratory Approval - all analyses shall be performed by a laboratory certified by the State of Utah to perform the tests required. Damage to Monitoring Wells - if any monitor well is damaged or is otherwise rendered inadequate for its intended pu{pose, the Permittee shall notify the Executive Secretary in writing within five days of discovery. Field Monitoring Equipment Calibration and Records - immediately prior to each monitoring event, the Permittee shall calibrate all field monitoring equipment in accordance with the respective manufacturer's procedures and guidelines. The Permittee shall make and preserve on-site written records of such equipment calibration in accordance with Part tr.G and H of this Permit. Said records shall identify the manufacturer's and model number of each piece of field equipment used and calibration. 5. White Mesa Seep and Spring Monitoring - after approval of the report required by part I.H.9, this Permit may be modified to require annual monitoring of selected seeps or springs on White Mesa. DMT Performance Standard Monitoring - after approval of the DMT Monitoring plan required by Part I.H.13, thePermittee shall perform technology performance monitoring to determine if DMT is effective in minimizing and controlling the release of contaminants pursuant to the provisions of Parts I.D.1 and I.D.3 of this permit, but not limited to the following activities: including, weekly Tailings wastewater Pool Elevation Monitoring: cells 1 and 3 - the Permittee shall monitor and record weekly the elevation of wastewater in Tailings Cells 1 and 3 to ensure compliance with the maximum wastewater elevation criteria mandated by Condition 10.3 of the License.' Said measurements shall be made from a wastewater level gauge or elevation survey. Weekly Slimes Drain Water Level Monitoring: Cells 2 and,3 - the Permittee shall monitor and record weekly the depth to wastewater in the slimes drain access pipes at Tailings Cells 2 and 3 to determine maximum and minimum fluid head before and after a pumping cycle, respectively. The permittee shall designate, operate, and maintain one water level measuring point at the centerline of the slimes drain access pipe at each tailings cell. For Cell 3 this requirement shall apply upon initiation of tailings de-watering operations. Weekly Wastewater Irvel Monitoring: Roberts Pond - the Permittee shall monitor and record weekly wastewater levels at the Roberts Pond to determine compliance with the DMT operations standards in Part I.D.3. Said measurements shall be made from a wastewater level gauge or an elevation survey pursuant to I.H.13. Weekly Feedstock Storage Area Inspection - the Permittee shall develop a Standard Operating Procedure for the License and inspect the Feedstock Storage Areas to: Confirm the bulk feedstock materials are maintained within the approved Feedstock Storage Area defined by Table 4, and Verify that all alternate feedstock materials located outside the Feedstock Area defined in Table 4, are maintained within water-tight containers. 15 7. 8. I I I T I I I I t t T I I I I I I t I Part I Permit No. UGW370004 On-site Chemicals Inventory - the Permittee shall monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kilyr. Said inventory shall be maintained on-site, and shall include, but is not limited to: a) Identification of chemicals used in the milling process and the on-site laboratory, b) Determination of volume and mass of each raw chemical currently held in storage at the facility. Tailings Cell Wastewater Quality Monitoring - on an annual basis, the Permittee shall collect wastewater quality samples from each wastewater source at each tailings cell at the facility, including, but not limited to: surface impounded wastewaters, and slimes drain wastewaters. All such sampling shall be conducted in August of each calendar year in compliance with the approved Tailings Cell Wastewater Quality Sampling Plan required by Part I.H.5 of this Permit. The Permittee shall also provide at least a 30-day notice in advance of the annual sampling event, so as to allow the Executive Secretary to collect split samples of the various tailings cells wastewater sources. F. Rsponrhlc Rnqurnrwlrrs - The following reporting procedures for routine and compliance reports must be met. 1. Routine Groundwater Monitoring Reports - the Permittee shall furnish the Executive Secretary quarterly monitoring reports of field and laboratory analyses of all well monitoring and samples described in Parts I.E.1, I.8.2,I.8.4, and I.E.6 of this Permit. Reports shall be submitted according to the following schedule: Table 5. Groundwater Moni Scheduleton Quarter Period Due Date First January - March June I Second Anril - June September I Third Julv - September December I Founh October - December March I Failure to submit the reports by the due date shall be deemed as noncompliance with this permit. Said monitoring reports shall include, but are not limited to, the following minimum information: a) Field Data Sheets - or copies thereof that provide the following: well narne, date and time of well purging, date and time of well sampling, type and condition of well pump, depth to groundwater before purging and sampling, calculated well casing volume, volume of water purged before sampling, volume of water collected for analysis, types of sample containers and preservatives. b) Laboratory Results - or copies thereof that provide the following: date and time sampled, date received by laboratory, and for each parameter analyzed, the following information: laboratory result or concentration, units of measurement, minimum detection limit or reporting limit, analytical method, date of analysis, counting error for radiologic analyses, total cations and anions for inorganic analysis. c) Water Table Contour Map - which provides the location and identity of all wells sampled that quarter, the measured groundwater elevation at each well measured in 16 d) e) 3. 4. 5. I I I t I I I t I t I t t I t I T T I Part I Permit No. UGW3700O4 feet above mean sea level, and isocontour lines to delineate groundwater flow directions observed during the quarterly sampling event. Quality Assurance Evaluation and Data Validation - including a written description and findings of all quality assurance and data validation efforts conducted by the Permittee in compliance with the Groundwater Monitoring euality Assurante plan. Said report shall verify the accuracy and reliability of the groundwater quality compliance data, after evaluation of sample collection techniques and equipment, sample handling and preservation, analytical methods used, etc. Electronic Data Files and Format - in addition to written results required for every sampling report, the Permittee shall provide an electronic copy of all laboratory results for groundwater quality monitoring conducted. Said electronic files shall consist of Comma Separated Values (CSV) format, or as otherwise approved by theExecutive Secretary. 2. Routine DMT Performance Standard Monitoring Reports - the permittee shall provide quarterly monitoring reports of all DMT performance standard monitoring required byPat I.E.6 of this Permit. Said monitoring shall be conducted in compliance with an approved DMT Monitoring:Plan, pursuant to Part LH.13 of this permit. Said monitoring reports and results shall be submitted to the Executive Secretary on the schedule provide-d in Table 5, above, and shall at a minimum include the following information: a) Summary table of weekly wastewater pool elevation and the Roberts Pond. Units of reporting shall be in monitoring at Tailings Cells 1, 3, feet above mean sea level. b) Summary table of weekly slimes drain water level monitoring conducted at Tailings Cells 2 and 3. Said summary shall include, but is not limited to down-slope depth towater level inside the slimes drain access pipe, as measured from one watir level measuring point at the centerline of the pipe. DMT Performance Upset Reports - the Permittee shall report any non-compliance with the DMT performance criteria of Part I.D in accordance with the requiremeirts of part I.G.3 of this Permit. Other Information - when the Permittee becomes aware of a failure to submit any relevant facts in the permit application or submittal of incorrect information in a permit application or in any report to the Executive Secretary, the Permittee shall submit such facts or information within 10 days of discovery. Groundwater Monitoring Wetl As-Built Reports - as-built reports for new groundwater monitoring wells shall be submitted for Executive Secretary approval, and at a minimumwill include the following information: a) Geologic Logs - that detail all soil and rock lithologies and physical properties of all subsurface materials encountered during drilling. Said logs shall be prepared by a Professional Geologist licensed by the state of utah, or otherwise approved beforehand by the Executive Secretary. b) Well Completion Diagram - that detail all physical attributes of the well construction, including: 17 Part I Permit No. UGW370004 1) Total depth and diameters of boring, 2) Depth, type, diameter, and physical properties of well casing and screen, including well screen slot size, 3) Depth intervals, type and physical properties of annular filterpack and seal materials used, 4) Design, type, diameter, and construction of protective surface casing, 5) Survey coordinates prepared by a State of Utah licensed engineer or land surveyor, including horizontal coordinates and elevation of water level measuring point, as measured to the nearest 0.01 foot. c) Aquifer Permeability Data - including slug test, aquifer pump test or other hydraulic analysis to determine local aquifer hydraulic conductivity in each well. 6. White Mesa Seep and Spring Monitoring Reports - after approval of the work plan and report required by Pan I.H.9, this Permit may be modified to require annual monitoring and reporting of selected seeps or springs on White Mesa. 7 . Chemicals Inventory Report - at the time of Permit renewal the Permittee shall submit a report to update the facilities chemical inventory report required by Part I.H.10. Said report shall provide all inventory information gathered pursuant to Part I.8.7. 8. Tailings Cell Wastewater Quality Reports - all annual wastewater quality sampling and analysis required by Part I.E.8 shall be reported to the Executive Secretary with the 3'd Quarter groundwater quality report due on December 1 of each calendar year. Said report shall include all information required by Part I.F.1(a), (b), (d), and (e) of this Permit. g. Revised Hydrogeologic Report - pursuant to Part IV.D of this Permit, and at least 180 days prior to Permit expiration, the Permittee shall submit for Executive Secretary approval a revised hydrogeologic report for the facility and surrounding area. Said report shall provide a comprehensive update and evaluation of: a) Local hydrogeologic conditions in the shallow aquifer, including, but not limited to: local geologic conditions; time relationships and distribution of shallow aquifer head measurements from facility wells and piezometers; local groundwater flow directions; and distribution of aquifer permeability and average linear groundwater velocity across the site, and b) Well specific groundwater quality conditions measured at facility monitoring wells for all groundwater monitoring parameters required by this Permit, including, but not limited to: temporal contaminant concentrations and trends from each monitoring well; statistical tests for normality of each contaminant and well, including univariate or equivalent tests; calculation of the mean concentration and standard deviation for each well and contaminant. Our orCorwueNce STRTUS 1. Accelerated Monitoring Status - is required if the concentration of a pollutant in any compliance monitoring sample exceeds a GWCL in Table 2 of the Permit;the facility 18 a) b) b) a) b) c) I I I I I I I I I I I I I I I T I I I Part I Permit No. UGW370004 shall then: Notify the Executive Secretary in writing within 30 days of receipt of data; and Immediately initiate accelerated sampling of the pollutant as follows: 1) Quarterly Baseline Monitoring wells - for wells defined by Part I.E.1(a) the Permittee shall initiate monthly monitoring, 2) Semi-annual Baseline Monitoring Wells - for wells defined by Part I.E.l(b) the Permittee shall initi ate quarterly monitoring. Said accelerated monitoring shall continue at the frequencies defined above until the compliance status of the facility can be determined by the Executive Secretary. 2. Violation of Permit Umits - out-of-compliance status exists when: The concentration of a pollutant in two consecutive samples from a compliance monitoring point exceed: 1) A GWCL in Table 2 of this Permit, and; 2) The reported ground water concentration for that pollutant exceeds the mean by two standard deviations. For purposes of this Permit, the standard deviation and mean will be calculated using values for the ground water pollutant at each individual compliance monitoring point or well; or The concentration value of any pollutant in two or more consecutive samples is statistically significantly higher than the applicable permit limit. The statistical significance shall be determined using the statistical methods described in Statistical Methods for Evaluating Ground Water Monitoring Data from Hazardous Waste Facilities, Vol. 53, No. 196 of the Federal Register, Oct. 11, 1988. 3. Failure to Maintain DMT Required by Permit Permittee to Provide Information - in the event that the Permittee fails to maintain DMT or otherwise fails to meet DMT standards as required by the permit, the Permittee shall submit to the Executive Secretary a notification and description of the failure according to R317-6-6.16(C)(1). Notification shall be given orally within24 hours of the Permittee's discovery of the failure of DMT, and shall be followed up by written notification, including the information necessary to make a determination under R317-6-6.16(C)(2), within five days of the Permittee's discovery of the failure of best available technology. The Executive Secretary shall use the information provided under R317-6-6.16.C(1) and any additional information provided by the Permittee to determine whether to initiate a compliance action against the Permittee for violation of permit conditions. A compliance action shall not be initiated, if the Executive Secretary determines that the Permittee has met the standards for an affirmative defense, as specified in R317-6- 6.16(cX3). Affirmative Defense - in the event a compliance action is initiated against the Permittee for violation of permit conditions relating to best available technology or DMT, the Permittee may affirmatively defend against that action by demonstrating a) L9 c) d) I I I I I t I I t I I t I I I t I T I Part I Permit No. UGW370004 the following: 1) The Permittee submitted notification according to R317-6-6.13; 2) The failure was not intentional or caused by the Permittee's negligence, either in action or in failure to act 3) The Permittee has taken adequate measures to meet permit conditions in a timely manner or has submitted to the Executive Secretary, for the Executive Secretary's approval, an adequate plan and schedule for meeting permit conditions; and 4) The provisions of UCA 19-5-107 have not been violated. 4. Facility Out of Compliance Status - if the facility is out of compliance, the following is required: a) The Permittee shall notify the Executive Secretary of the out of compliance status within 24 hours after detection of that status, followed by a written notice within 5 days of the detection. b) The Permittee shall continue accelerated sampling pursuant to Part I.G.l, unless the Executive Secretary determines that other periodic sampling is appropriate, until the facility is brought into compliance. The Permittee shall prepare and submit within 30 days to the Executive Secretary a plan and a time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain ground water quality to insure that permit limits will not be exceeded at the compliance monitoring point and that DMT will be reestablished. The Executive Secretary may require immediate implementation of the contingency plan to be submitted pursuant to Part I.H.16, in order to regain and maintain compliance with the permit limit standards at the compliance monitoring point or to reestablish DMT as defined in the permit. e) Where it is infeasible to reestablish DMT as defined in the permit, the permittee may propose an alternative DMT for approval by the Executive secretary. 5. Accelerated Monitoring Status for New Wells - any new compliance monitoring well installed by the Permittee after issuance of this Permit, will be designated a compliance monitoring point, and subject to the requirements of Part I.G of this Permit, after submittal and Executive Secretary approval of the Background Groundwater euality Report required by Parr LH.4 of this Permit. H. ColvpI-IaNcE SCffiDULE RrqummmNTS. The Permittee will comply with the schedules as described and summarized below: l. Installation of New Groundwater Monitoring Wells - within 30 days of issuance of this Permit, the Permittee shall submit a plan for the installation of new monitoring wells for Executive Secretary approval. Said plan shall include the following information: a) Tailings Cell I DMT Wells -one (1) hydraulically upgradient well and two (2) hydraulically downgradient wells that comply with the provisions of Part I.E"3 of this 20 2. -J. I T I I I I I I I T I I T I I I I I I Part I Permit No. UGW370004 Permit, and the well location map submitted by the Permittee on April 16,2004. b) New Compliance Monitoring Wells for Tailings Cells 2 and 3 -an adequate number and location of monitoring wells to ensure: 1) Early detection of tailings cell contamination of shallow groundwater from Tailings Cells 2 and 3. The number and location of these wells shall conform to the provisions of Part I.E.3, and the well location map submitted by the Permittee on April 16,2004, and 2) Discrete monitoring of each individual disposal cell. For Cell}this shall mean installation of three (3) monitoring wells on the shared dike between Cells 2 and 3, as per the well location map submitted by the Permittee on April 16,2004. c) New well design and construction details that comply with Part I.E.3 of this Permit. On or before May 1, 2005, the Permittee shall complete installation of all new monitoring wells in accordance with said plan and any conditions of approval. The Permittee shall provide at least a7-day notice to allow the Executive Secretary to observe all drilling and well installation activities related to this plan. Revised Hydrogeologic Report - within 60 days of completion of the well installations required by Part I.H.1, the Permittee shall submit a revised hydrogeologic report for Executive Secretary approval that includes: a) Monitoring well as built report for each well that complies with the information requirements of Part I.F.5. b) Hydrogeologic data from each new well, including but not limited to: depth and elevation of groundwater level, and aquifer test results to determine local permeability. c) Comprehensive hydrogeologic evaluation of the facility that includes both new data collected during or as a result of the new monitoring well installation required by Part I.H.1, and all existing hydrogeologic information available for the site. d) Aquifer test results to determine local hydraulic conductivity and other aquifer properties at existing well MW-32 (formerly TW4-17). e) Average linear groundwater velocity calculated for each well, based on well specific hydraulic conductivity, hydraulic gradient, and effective aquifer porosity. If after review of this report, the Executive Secretary determines that additional monitoring wells are required to adequately monitor the facility, the Permit will be re- opened and modified to require all necessary improvements pursuant to Part tV.N.3. Background Ground Water Quality Report: Existing Wells - within 90 days of issuance of this Permit, the Permittee shall submit a Background Ground Water Quality Report for all existing monitoring wells at the facility for Executive Secretary approval. Said report shall include: a) All available groundwater quality data for all existing monitoring wells at the facility. b) A quality assurance evaluation and data validation of the existing and historic on-site groundwater quality data that on a well-by-well and contaminant specific basis: 2t Part I Permit No. UGW370004 Identifies,justifies, and/or culls any zero concentration values reported, Determines the adequacy of minimum detection limits used, particularly with respect to the corresponding GWQS for each contaminant, Adequately addresses any special statistical needs for management of data sets with a large proportion of non-detectable values, Determines the adequacy of laboratory and analytical methods used, Determines the consistency of laboratory units of reporting, Evaluates and justifies internal consistency between specific and composite types of groundwater quality analysis (e.g. major ions and TDS), Identifies and justifies any groundwater concentration outliers, Tests the selected groundwater quality data for each individual well and contaminant for normality, and justifies the use of parametric or non-parametric statistical methods for each. c) An examination and justification of any temporal and/or spatial groundwater quality concentration phenome[a, that shall include, but are not limited to: 1) Any long term or apparently increasing contaminant concentration trends found in any existing monitoring wells, 2) Any long term or apparently increasing contaminant concentration ratios observed in existing monitoring wells. 3) Any contaminant concentrations that appear to exceed their corresponding GWQS. d) Determination of descriptive statistics for each individual well and contaminant found in Table 2 of this Permit. Upon approval of this report, the Executive Secretary will re-open this Permit and modify the Ground Water Compliance Limits in Table 2, above to account for natural variations in groundwater quality, not caused by current or historic operations at the facility. 4. Background Groundwater Quality Report: New Monitoring Wells - within 30 days of installation of the new monitoring wells required by Part I.H.1 of this Permit, the Permittee shall implement a quarterly groundwater quality sampling program for all new monitoring wells. Said sampling shall comply with the following Permit requirements: a) Routine groundwater compliance monitoring requirements of Part I.E.l, b) Well monitoring procedure requirements of Part I.8.4, and c) Quarterly reporting requirements of Part I.F.1. After completion of eight (8) consecutive quarters of groundwater sampling and analysis of the new monitoring wells, the Permittee shall submit a Background Groundwater Quality Report for the new wells for Executive Secretary review and approval. The content of this report shall comply with the information requirements of Part I.H.3 of this Permit. Said report shall be submitted for Executive Secretary approval no later than June 1, 2007 . After approval of this report, the Executive Secretary will re-open this 22 1) 2) 3) 4) s) 6) 7) 8) 5. 6. I T I I I T I I t I I I t I I I I I I Part I Permit No. UGW370004 Permit and establish Groundwater Compliance Limits in Table 2 for the new monitoring wells. Tailings Cells Wastewater Quality Sampling Plan - within 150 days of issuance of this Permit, the Permittee shall submit a plan for tailings cell wastewater sampling and analysis for Executive Secretary approval. The purpose of this plan and associated report shall be to characterize the source term quality of all tailings cell wastewaters, including, but not limited to: impounded wastewaters or process waters in the tailings cells, and wastewater or leachates collected by internal slimes drains. Said plan shall include, but is not limited to: a) Collection of samples from each wastewater source at each tailings cell, including wastewater impoundments, slimes drains, etc. b) Complete analysis for both field and laboratory parameters required by Part I.E.l(d), and all detectable volatile organic contaminants by EpA Method 82608. c) Detailed description of all sampling methods and sample preservation techniques to be employed. d) Use of standardized analytical methods. e) Analysis by a State of Utah certified environmental laboratory. 0 30 day advance notice of each annual sampling event to allow the Executive Secretary to collect split samples of all tailings cell wastewater sources. After approval of the plan, the Permittee shall implement the plan pursuant to the requirements of Parts I.E.8 and I.F.8. After approval of this plan, the Executive Secretary may re-open and modify this Permit to incorporate the provisions of the approved plan. Monitoring Well Remedial Construction and Repair Work Plan and Report - within 30 days of issuance of this Permit, the Permittee shall submit a work plan and schedule for the following remedial construction activities for selected monitoring wells at the facility. Within 60 days of completion of these activities, the Permittee shall submit a report for Executive Secretary approval, including: a) Well Development - the Permittee shall develop existing wells at the facility so that they produce clear groundwater, including wells: Mw-5, Mw-l1, Mw-r8, Mw-19, MW-26, TW4-16, and MW-32. Said well development will ensure that groundwater clarity conforms to the EPA RCRA TEGD requirements found in Part I.E.3(c) of this Permit to the extent reasonably achievable. b) Protective Surface Casings: Wells and Piezometers - the Permittee shall install steel surface casings to protect the currently exposed PVC well and piezometer casings, including: Piezometers P-1, P-2,P-3, P-4, and P-5; and wells Mw-26 and MW-32. Each steel casing installed shall: 1) Allow ready water level measurement at each piezometer, 2) Not interfere or disturb the existing water level measuring point, and 3) Provide security and control access to the piezometer. 23 d) e) 7. 8. I I I I t I t I I I I I I I I I I T I Part I Permit No. UGW37OOO4 Monitoring Well MW-3 Verification, Retrofit, or Reconstruction Report - within 150 days of issuance of this Permit, the Permittee shall verify the depth to the upper contact of the Brushy Basin Member of the Morrison Formation in the immediate vicinity of well MW-3. The Permittee shall provide at least 14 days notice and allow the Executive Secretary to observe all field activities related to said verification. In the event that the Executive Secretary determines the well screen has been inadequately constructed, the Permittee shall retrofit, reconstruct, or replace monitoring well MW-3 in accordance with a plan and schedule approved by the Executive Secretary. White Mesa Seeps and Springs Sampling Work Plan and Report - within 180 days of issuance of this Permit, the Permittee shall submit a plan for Executive Secretary approval of groundwater sampling and analysis of all seeps and springs found downgradient or lateral gradient from the tailings cells on White Mesa. Said plan shall include, but is not limited to: a) Location of all seeps and springs to be sampled, including maps and surveyed coordinates (physical location, and elevation), b) Detailed description of sampling methods and equipment, c) Determination of field parameters or measurements that will be made, Description of sample preservation methods, Determination of the laboratory analyical methods and the environmental laboratory that will perform the analysis. 0 Sampling and analysis of all ground water compliance parameters found on Table 2 of this Permit, including analysis of volatile and semi-volatile organic compounds by EPA SW-846 methods 8260 and8270. Within 180 days of approval of the plan, the Permittee shall complete said sampling and analysis, and submit a final report for Executive Secretary approval. Said report shall: 1) document the sampling project, 2) transmit copies of all field measurements and laboratory results, 3) provide a water table contour map that includes water table elevations of all the wells at the facility and the elevations of the phreatic surfaces observed at each of the seeps and springs sampled, and 4) provide an evaluation and interpretation of the groundwater quality data collected. The Permittee shall also provide at least 15 days notice to allow the Executive Secretary to collect split groundwater quality samples of the seeps and springs. 9. On-site Chemicals Inventory Report - the Permittee shall complete a historical review, and conduct an inventory of all chemical compounds or reagents stored, used, or currently in use at the facility. Said report shall include: a) Identification of all chemicals used in the milling and milling related processes at White Mesa. b) Determination of the total volumes currently in use and historically used, as data is available. Said report shall be submitted for Executive Secretary approval within 90 days of issuance of this Permit. At the time of Permit renewal, the Permittee shall submit an 24 Part I Permit No. UGW370004 updated inventory report pursuant to Part I.F.7. l0.Infiltration and Contaminant Transport Modeling Work Plan and Report - the Permittee shall submit for Executive Secretary approval an infiltration and contaminant transport modeling report that demonstrates the long-term ability of the tailings cells cover system to adequately contain and control tailings contaminants and protect nearby groundwater quality of the uppermost aquifer. Said report shall demonstrate how the tailings cell engineering design and specifications will comply with the minimum performance requirements of Part I.D.6 of this Permit. Within 180 days of Permit issuance, the Permittee shall submit a work plan for Executive Secretary approval, that: a) Identifies all applicable and pertinent historic studies and modeling reports relevant to tailings cell cover design and tailings cell system performance. b) Determines all information necessary for infiltration and contaminant transport modeling, including but not limited to representative input values for vadose zone and aquifer soil-water partitioning (IQ) coefficients, tailings source term concentrations, tailings waste leach rates, vadose zone and aquifer groundwater velocities, vadose zone and aquifer dispersivity, contaminant half-life or other rates of decay, etc. In the event that any required information is not currently available, the Permittee may select conservative assumptions for use in the required infiltration and contaminant transport models. Otherwise, the Permittee shall identify how information will be collected that is representative of actual field conditions, and a timetable by which said information will be submitted forExecutive secretary approval. c) Identifies all computer models that will be used to simulate long-term performance of the tailings cells cover system. All predictive models used shall be publicly available computer codes that adequately represent field characteristics at the tailings disposal site. d) Determines the conceptual model to be used and justifies why it is representative or conservative of actual field conditions at the site. Said conceptual model will identify the physical domain(s) and geometries to be simulated including the tailings cell design and construction, all boundary and initial conditions to be assigned in the model(s), and the shallow aquifer locations where future potential contaminant concentrations will be predicted. e) Justifies how the infiltration and contaminant transport problem has been adequately conceptualized and planned to demonstrate compliance with the requirements of Part I.D.6 of this Permit. Within 180 days after approval of the modeling work plan, the Permittee shall complete all modeling in accordance with the approved work plan and submit a final report for Executive Secretary approval. In the final report, the Permittee may include supplemental information to justify modification of certain Permit requirements, including, but not limited to: the number and types of groundwater compliance monitoring parameters, tailings cell cover system engineering design and construction specifications, tailings cell operational requirements, etc. Upon Executive Secretary approval of the final infiltration and contaminant transport report, the Reclamation Plan may be modified to accommodate necessary changes to protect public health and the environment. 25 I T I I I I I I I I T I t I I I I I I Part I Permit No. UGW370004 1 1. Plan for Evaluation of Deep Supply Well WW-2 - within 1 year from issuance of this Permit, the Permittee shall submit for Executive Secretary approval a plan for evaluation of the annular casing seal in water supply well W-W-2. The objective of this plan is to ensure adequate well casing and annular seals, in compliance with the regulations of the Utah State Engineer (UAC R655-4-9), with special emphasis on creating both a physical barrier and hydraulic isolation between the shallow unconfined and the deep confined aquifers. After approval of the plan, the Permittee shall completely execute all provisions of the plan on or before decommissioning of the White Mesa mill. 12. DMT Monitoring Plan - within 90 days of issuance of this Permit, the Permittee shall submit a Facility DMT Monitoring Plan for Executive Secretary approval. The purpose of said plan shall be to provide adequate design and construction of DMT monitoring equipment, adequate equipment operation and maintenance procedures to monitor DMT compliance with the requirements of Parts I.D.l and I.D.3; adequate DMT monitoring procedures in compliance with Parts I.E.6; and adequate DMT reporting procedures in compliance with Parts I.F.2 and I.F.3 of this Permit. Said plan shall include, but is not limited to: a) Design and constructionof a wastewater pool elevation gauge to be installed at each tailings cell, or procedures and equipment needed for completion of periodic wastewater elevation surveys. b) Designation of a water level measuring point on the slimes drain access pipe at both Tailings Cells 2 and 3. c) Based on historical consffuction information and actual measurements, determine the down-slope depth for the lowest point on the FML found at or near the base of the slimes drain access pipes for both Cells 2 and 3. d) Determination of an average allowable wastewater head in the slimes drain layers at both Cells 2 and 3 that is as low as reasonably achievable. e) Design and construction of a water level gauge, or procedures and equipment needed for completion of periodic elevation surveys at the Robens Pond to measure wastewater levels above the lowest point on the pond's FML. 0 Procedures for monitoring the Feedstock Storage Area to determine appropriate location of feedstock storage, and water-tight condition of containerized feedstocks. g) Weekly monitoring and record keeping to determine compliance with Parts I"D.3, and I.E.6. Within 30 days of approval of said plan, the Permittee shall complete installation and make operational all equipment required to comply with this Permit. After approval of said plan the Executive Secretary may re-open and modify this Permit to incorporate any additional equipment, operation, and maintenance procedures needed for DMT monitoring. 13. Tailings Cell4A Contaminant Removal Schedule and Report - within 90 days of issuance of this Permit, the Permittee shall submit for Executive Secretary approval a schedule for completion of removal of waste, wastewater, slimes drain material, existing FML liners, underlying leak detection system materials, and any contaminated subsoils 26 a) b) a) b) I T I I I T t I I I t I I I T t I I I Part I Permit No. UGW370004 under Tailings Cell 4A, including periodic progress reports. The purpose of this workshall be to recover, remove all contaminated materials and to disptse of these materials inTailings Cell 3. Within 60 days of completion of contaminant rernoval from TailingsCell 44, the Permittee shall submit a report for Executive Secretary approval. 14' Tailings Cell 44 Redesign and Reconstruction - after contaminant removal pursuant toPat I'H.14, and prior to any new construction including, but not limited to: ioundations,sub-base materials, liners, or leak detection systems at existing Tailings Cell 4A, thePermittee shall: Submit engineering design plans and specifications that demonstrate how the newconstruction will comply with the requirements of the Utah Water euality Act, allrules and regulations promulgated thereunder, and the Best Availabfu Technologyrequirements mandated by part I.D.4 of this permit. Secure prior Executive Secretary approval and issuance of a construction permit.Thereafter, this Permit may be re-opened and modified to reflect the new design andconstruction specifications, and any related operations, monitoring, or reportirigrequirements necessary. 15. Contingency Plan - within 180 days of issuance of this Permit, the permittee shall submita Contingency Plan for Executive Secretary approval that provides a detailed list ofactions the Permittee will take to regain compliance with permit limits and DMTrequirements defined in Parts I.C and I.D of this Permit. At a minimum, the ContingencyPlan will include, but is not limited to measures to resolve the following general categories of non-compliance : Groundwater Contamination - as shown by any contaminant concentrations incompliance monitoring wells that exceed their respective groundwater compliancelimit found in Part LC.l and Table 2 of this permii. Mill Discharge Violations - including unauthorized discharge or release of prohibited contaminants to the tailings cells, pursuant to partr.c.z andl.c.3; and c) DMT Violations - which include several types of non-compliance, including but notlimited to: 1) Excess tailings cell wastewater pool elevation above the maximum elevations mandated by Part I.D.3; 2) Excess head in the Tailings Cells 2 and,3 slimes drain system, pursuant to part I.D.3 and as defined by the DMT Monitoring plan in part I.H.13; and 3) Excess elevation for tailings solids as required by part I.D.3. After approval of the Contingency Plan, the Executive Secretary may re-open and modifythis Permit to include any new requirements therefrom. 16. Stormwater Best Management Practices Plan - within 180 days of permit issuance thePermittee shall submit a final Stormwater Best Management Practices plan for Executive Secretary approval. Said plan shall comply with the requirements of part I.D.g of thispermit. Upon Executive Secretary approval, the Permittee shall immediately implement 27 I t I I I I I I T t T I I I I t I t I Part I Permit No. UGW370004 all provisions of said plan. 17. Roberts Pond As-Built Report - within 90 days of issuance of this Permit, the Permittee shall submit for Executive Secretary review and approval a As-Built Report for the Roberts Pond. Said report shall document: a) All contaminant removal and re-construction activities completed by the Permittee in 2002, b) Engineering drawings and specifications to adequately describe and verify the recent reconstruction efforts. After review of this report, the Executive Secretary may require modification of the Reclamation Plan in order to provide adequate demolition and decontamination of the Roberts Pond at the time of facility closure, and to protect public health and the environment. 18. Tetrahydrofuran Demonstration Study Work Plan and Report - within 30 days of issuance of this Permit, the Permittee shall submit a work plan to examine and determine the root cause of continuing tetrahydrofuran (T[IF) contamination identified in several existing monitoring wells at the facility, including but not limited to wells: MW-l, MW- 2, MW-3, MW-5, and MW-12. Said plan shall be submitted for Executive Secretary approval, and shall include collection of direct evidence to verify the source and extent of TIIF contamination in the aquifer. Such work shall include field and laboratory studies to determine if the TIIF contamination is localized near each individual well casing and/or screen, or if it is more broadly distributed across the shallow aquifer. The Permittee shall complete said studies outlined by the approved plan and submit a final report for Executive Secretary approval within 90 days of issuance of this Permit. The Permittee shall provide at least a 30-day notice of any fieldwork related to this plan, to allow the Executive Secretary to observe all field activities and split any groundwater quality samples related to this demonstration. In the event that the Executive Secretary determines that the TIIF concentrations found in local groundwater are not the result of either historic or current facility operations, this Permit will be re-opened and Table 2 modified by removing TIf as a GWCL parameter. 28 I t I i t I I II t i i i B. C. D. Part tr Permit No. uGW370004 PART tr. REPORTING REQIJIREMENTS RspREsrNTerrvE Srumwc. Samples taken in compliance with the monitoring requirements established under Part I shall be representative of the monitored activity. ANeryncar Pnocsur-rnns. Water sample analysis must be conducted according to test procedures specified underUAC R317-6-6.3.12 unless othertestprocedures have been specified in this permit. kNarrres ron Tervprnxa. The Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate, any monitoring device or method required to be maintained under this permii shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than six months per violation, or by both' RsBonnrqc oF MoMToRrNc Rrsurrs" Monitoring results ohtainerl dunng reporting periods specified in the permit, shall be submitted to the Executive Secretary, Utah Division of Water {uality at the following address no later than the date specified following the completed reponing period: Attention: Compliance and Monitoring Program State of Utah Division of Water QualitY Department of Environmental Quality Salt Lake CitY, Utah 84114-4870 The quarterly due dates for reporting are: June l, September 1, December 1, and March 1. CotgnNcE SCIfiDr.I-ES. Reports of compliance or noncompliance with, or any progress reports on interim and final requirements contained in any Compliance Schedule of this permit shall be submitted no later than 14 days following each schedule date. Aopmouar Morqtonwc By rIrE Prnrvrrrrs. If the permittee monitors any pollutant more frequently than required by this permit, using approved test procedurel as specified in this permit, the results of tt ir monitoring shall be included in the calculation anil reporting of the data submitted. Such increased frequency shall also be indicated. G. RgCORDS CONIENTS. 1. Records of monitoring information shall include: The date, exact place, and time of sampling, observations' or measurements: The individual(s) who performed the sampling, observations, or measurements; The date(s) and time(s) analyses were performed; The name of the certified laboratory which performed the analyses; The analyical techniques or methods used; and, The results of such analyses. H. RrrsN-11oN oF Rrconos. The permittee shall retain records of all monitoring information, E. rl It I ;l I I I e) 0 a) b) c) d) 29 1. i, I II t 1t I t I 30 a) b) c) 3. J. K. t I t i t i i I i t I Part tr Permit No. UGW37W4 including all calibration and maintenance records and copies of all repo{s required. by this permit, and records of all data used to complete the application for this permit, for a period of at ieast five years from the date of the sample, measurement, report or application. This period may be extended by request of the Executive Secretary at any time. The permittee shall verbally report any noncompliance which may endanger public health or the environment as ,oon u, possible, Lut no later than 24 hours from the time the permittee first became aware of the circumstances. The report shall be made to the u.tatr Department of Environmental euality 24 hour number, (801) 538-6333, or to the Division of Water Quality, GroundWaterprotection Section at (801) 538-6146, duringnormal businesshours (8:00 am - 5:00 pm Mountain Time). A.written submission shall-also be provided to the Executive Secretary within five days of the time that the permittee becomes aware of the circumstances. The written submission shall contain: A description of the noncompliance and its cause; The period of noncompliance, including exact dates and times; The estimated time noncompliance is expected to continue if it has not been corrected; and, d) Steps taken or planned to reduce, eliminate, and prevent reoccurrence of the noncomPliance. 3. Reports shall be submitted to the addresses in Part tr.D, Reporting of Monitoring Results' Orrrn NoNcorwuaNcs RrponrNc. Instances of noncompiiance not required to be reported within 5 days, shall be reported at the time that monitoring reports for Part tr.D are submitted' IxspectoN eNo Exrny. The permittee shall allow the Executive Secretary, or an authorized +p***.,ive, upon the presentation of credentials and other documents as may be required by law, to: l. Enter upon the Permittee's premises where a regulated facility or activity is located or conducted, or where records must be kept under the conditions of the permit; 2. Have access to and copy, at reasonable times, any records that must be kept under the conditions of this Permit; Inspect at reasonable times any facilities, equipment (including monitoring and control "luiprn"n,), practices, or operations regulated or required under this permit; and, Sample or monitor at reasonable times, for the purpose of assuring pernrit compliance or as otherwise authorized by the Act, any substances or parameters at any location' A. B. D. E. I I t i I t t t i t t t t i i t t C. Part Itr Permit No. UGW370004 PART M. COMPLTANCE RESPONSIBILITIES Dury ro CoMpLy. The permittee must comply with all conditions of this permit. Any permit noncompliance constitutes a violation of the Act and is grounds for enforcement action; for permit termination, revocation and re-issuance, or modification; or for denial of a permit renewal application. The permittee shall give advance notice to the Executive Secretary of the Division of Water Quality of any planned changes in the permitted facility or activity which may result in noncompliance with permit requirements. PrNarrres FoR VIoLATToNS oF PERMIT CoNomoNs. The Act provides that any person who violates a permit condition implementing provisions of the Act is subject to a civil penalty not to exceed $10,000 per day of such violation. Any person who willfully or negligently violates permit conditions is subject to a fine not exceeding $25,000 per day of violation. Any person convicted under Section 19-5-115 of the Act a second time shall be punished by a fine not exceeding $50,000 per day. Nothing in this permit shall be construed to relieve the permittee of the civil or criminal penalties for noncompliance. Nrro ro Harr oR Rroucr Acmrrry Nor A DEFENSE. It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the conditions of this permit. Drrry To MmcAre. The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this permit which has a reasonable likelihood of adversely affecting human health or the environment. koprn Opnnauou Ar{D MAtr[Er\ANcE. The permittee shall at all times properly operate and maintain all facilities and systems of treatment andcontrol (andrelated appurtenances) which are installed or used by the permittee to achieve compliance with the conditions of this permit. Proper operation and maintenance also includes adequate laboratory controls and quality assurance procedures. This provision requires the operation of back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation is necessary to achieve compliance with the conditions of the permit. 3l I I t I t l I I I I It I It t I t t I Part IV Permit No. UGW370004 PART TV. GENERAL REQI.JIREMENTS A. praNr.nD CHANcES. The permittee shall give notice to the Executive secretary as soon as possible of any prurn"o physical alteration-s or additions to the permitted facility' Notice is ffirea when-the alteration or addition could significantly change the nature of the facility or increase the quantity of pollutants discharged' B. C. D. ANucrperroNoNcorwrr6Nce. The permittee shall give advancenotice of anyplannedchanges i;;;;tted facility or activity which may result in noncompliance with permit requirements. PBrurr ACTTONS. This permit may be modified, revoked and reissued, or terminated for cause' The filing of a requesiuy ttre permittee for apermit modification, revocation and re-issuance' or termination, or a notifirutio, brptanned changes or anticipated noncompliance, does not stay any permit condition. Drrry ro REAppLy. If the permittee wishes to continue an activity regulated by this permit after the expiration date of this permit, the permittee must apply for and obtain a new permit' The uppfi.r,ion should be subrnitted at leasl 180 days before the expiration date of this permit' DuryropnovIDEINFioRMATroN. The permittee shall furnish to the Executive Secretary, within a reasonable time, any information which the Executive Secretary may request to determine whether cause exists for modifying, revoking and reissuing, or terminating this permit' or to determine compriance with this p"r-ir, Thl permittee shall also furnish to the Executive Secretary, upon request, copies of records required to be kept by this permit' F. ourn INFpRMATIoN. when the permittee becomes aware that it failed to submit any relevant facts in a permit application, or rub-itt"d incorrect information in a permit application or any rcport to tire g*ouiir" Secretar/, it shall promptly submit s,ch facts or information' G. StcN^ronyRreunrrmrvrs. All applications, reports orinformation submittedtotheExecutive Secretary shall be signed and certified' 1. All permit applications shall be signed as follows: : a)Foracorporation:byaresponsiblecorporateofficer; b) For a partnership or sole proprietorship: by a general partner or the proprietor' respectively. c) For a municipality, State, Federal, or other public agency: by either a principal executive officer or ranking elected official' 2. All reports required by the permit and other information requested by the Executive Secretary shall be signed by a person described above or by a duly authorized representative ofthat person.epersonlsaautyauthorizedrepresentativeonlyit The authori zationis made in writing by a person described above and submitted to the Executive Secretary, and, The authorization specified either an individual or a position having responsibility for the overall operation oi,f,. regulated facility or activity, such as the position of plant 32 a) b) Part IV Permit No. UGW370004 manager, operator of a well or a well field, superintendent, position of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the cbmpany. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.) 3. Changes to Authorization. ff an authori zation under Part IV.G.2. is no longer accurate because a different individual or position has responsibility for the overall operation of the facility, a new authorization satisfying the requirements of Part w.G.2 must be submitted to the Executive Secretary prior to or together with any reports, information, orapplications to be signed by an authorized representative. 4. Certification. Any person signing a document under this section shall make the following certification: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. " H. krr.tALTEs FoR FelsmcenoN oF REPoRTs. The Act provides that any person who knowingly makes any false statement, representation, or certification in any record or other document submitted or required to be maintained under this permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction be punished by a fine of not more than $10,000perviolation, orbyimprisonment fornotmorethan six months perviolation, orbyboth. I. Avarenrrrv onRrponrs. Except for data determined to be confidential by the permittee, all reports prepared in accordance with the terms of this permit shall be available for public inspection at the offices of the Executive Secretary. As required by the Act, permit applications, permits, effluent data, and ground water quality data shall not be considered confidential. J. kopBnrv fucnrs. The issuance of this permit does not convey any property rights of any sort, or any exclusive privileges, nor does it authorize any injury to private property or any invasion of personal rights, nor any infringement of federal, state or local laws or regulations. K. SrvrnasIUTY. The provisions of this permit are severable, and if any provision of this permit, or the application of any provision of this permit to any circumstance, is held invalid, the application of such provision to other circumstances, and the remainder of this permit, shall not be affected thereby. L. TRaNsrrns. This permit may be automatically transferred to a new permittee if: l. The current permittee notifies the Executive Secretary at least 30 days in advance of the proposed transfer date; 2. The notice includes a written agreement between the existing and new permittee containing a 33 t' 1 t II I I I I I I I I I i t I i I I Part IV Permit No. UGW37W4 specific date for transfer of permit responsibility, coverage, and liability between them; and, 3. The Executive Secretary does not notify the existing permittee and the proposed new permittee of his or her intent to modify, or revoke and reissue the permit. If this notice is not received, the transfer is effective on the date specified in the agrcement mentioned in paragraph 2 above. M. Srarr Lews. Nothing in this permit shall be construed to preclude the institution of any legal action orrelieve the permittee from anyresponsibilities,liabilities, penalties establishedpursuant to any applicable state law or regulation under authority preserved by Section 19-5-1 15 of the Act. N. ReopnNrn h.ovrsroNs. This permit may be reopened and modified (following propr administrative procedures) to include the appropriate limitations and compliance schedule; if necessary, if one or more of the following events occuts: 1. If new ground water standards are adopted by the Board, the permit may be reopened and modified to extendthe terms of the permit orto include pollutants coveredbynew standards. The permittee may apply for a variance under the conditions outlined in R317-6-6.4(D). 2. Changes have been determined in background ground water quality. 3. The Executive Secretary determines permit modification is necessary to protect human health or the environment. LBM:lm F:/.../IUCgwPemit2h.doc 34 j J I I i i i t I i I I t i i t i t I DRAFT Utah Division of Radiation Control Ground Water Quality Discharge permit Statement of Basis For a Uranium Milling Facility At White Mesa, South of Blanding, Utah Owned and Operated by International Uranium (USA) Corporation Independen ce plaza, Suite 950 1050 17th Street Denver, Colorado 80265 December 1,2004 Purpose The purpose of this Statement of Basis (SOB) is to describe technical and regulatory basis to proposed permit requirements found in a Ground Water Quality Discharge Permit No. UGW370004, (hereafter Permit) for the International Uranium (USA) Corporation (hereafter IUC) uranium mill facility located about six miles south of Blanding, Utah on White Mesa in Sections 28,29,32, and 33, Township 37 South, Range 22Bast, Salt Lake Base and Meridian, San Juan County, Utah. Introduction and Historv The White Mesa uranium mill was constructed in 1979-1980 and licensed under federal regulations by the Nuclear Regulatory Commission (NRC), Source Material License SUA-1358 (hereafter NRC License). Initially, the facility consisted of the mill works and one tailings disposal cell, Cell 2, which was completed in May, 1980 (2182D'Appolonia Consulting Engineers Report, p. 3-l). In June, 1981 construction of a wastewater storage pond, Cell l, was completed (ibid., p. l-1). Conskuction of a second tailings cell, Cell 3, was completed in September,l9S2 (3/83 Energy Fuels Nuclear Report, p.l-2). Finally, tailings disposal Cell4A was completed in January, 1990 (5128199 IUC Groundwater Information Report, p. A-11). However, Cell 44 has not been used yet for tailings disposal, but instead foistorage of raffinate (personal communication, Mr. Harold Roberts). Groundwater at White Mesa is primarily found in two aquifers: a shallow unconfined or perched aquifer, and a deep underlying confined aquifer. The shallow aquifer is found almost entirely in the Cretaceous-age Burro Canyon Formation, where groundwater is perched on top of the underlying Jurassic-age Brushy Basin Member of the Morrison Formation. The Brushy Basin Member is about 200 - 400 feet thick and consists of low permeability shale and mudstone in the Blanding area (Hintze, p. 200). At White Mesa, IUC estimates that the Brushy Basin member is about 295 feet thick (7 194 Titan Environmental Report, Fig. 1 .2). From information provided by IUC, the geologic contact between these two formations is found at a depth of about 78 to I49 feet below ground surface (bgs, see 9/6102IUC map submittal). The waier table in the perched aquifer is found at shallower depths, and discharges to seeps and springs along the margin of White Mesa. Upgradient of the mill site, the perched aquifer is used for drinking water, stock I Statement of Basis DRAFT December 1,2004 watering, and irrigation. Downgradient of the mill site, the perched aquifer supports stock watering and some wildlife habitat. The deep confined aquifer under White Mesa is found in the Entrada and underlying Navajo Sandstones. IUC estimates the top of the Entrada Sandstone at the site is found at a depth of more than 1,150 feet bgs (Tlg4TiianEnvironmental Report, Fig. 2.3). This deep aquifer is hydraulically isolated from the shallow perched aqulfl by at least two (2) shale members of the Morrison Formation, including the Brushy Basin l-295 feet thickl and the Recapture [- 120 feet thickl Members (ibia., nig. l.i). Other formations are also found between the perched and deep confined aquiferi, that also include many layers of thin shale interbeds that contribute to hydraulic isolation of these two groundwater systems, including: the Morrison Formation festwater Canyon [- 60 feet thick], and Salt Wash [- 105 feet thick] Members, and the Summerville normation [- 100 feeittrictl (ibid.). Artesian groundwater conditions found in the deep Entrada/I.{avajo Sandstone aquifer also reinforce this concept of hydraulic isolation from the shallow perched system. Regionally, the deep confined aquifer is the primary drinking water supply, and must be piotected from pollution sources. A few miles south of the mill site the Ute Mountain Ute comrnunity depends on this deep confined aquifer for drinking water supply. Between 1979 and 1997 the initial groundwater monitoring program approved by NRC for the facility examined up to 13 wells and 20 different chemical and radiological contaminants; largely collected o, u qrru.t.rly basis. ln lggT , after examination of the historical data, the NRC reduced the monitoring program to six (6) point of compliance (POC) wells in the perched aquifer, all found a short distarice south of raitlngs Cells 3 and 4,{. These include IUC wells MW-5, MW- 11, MW-12, MW-14, MW-15, and MW-I7. Atthe same time the NRC reduced the number of analytical parameters to four (4) contaminants that the NRC considered dependable indicators of tailings ceil leakage: chloride, nickel, potassium, and uranium. This is the same quarterly moniioring program recently used by IUC to demonstrate compliance with its NRC License' Under the NRC approved progpm IUC uses an intra-well control chart method to determine compliance. This methodiompares recent groundwater quality results in each individual PoC weliwith a control limit for each analyte. In practice, control limits are calculated individually for each monitoring well and analyte, based on historical or background data that has not been altered or influenc.a uy the activiiy in question (EPA, February, 1989, pp.7-l andT-L2). Determination of non-compliance o"c.rir when a recent concentration exceeds its individual control limit on the controf chart (ibid. ,7-5). Information provided by IUC shows that control limits were established under the NRC License for four analytes: chloride, nickel, potassium, and uranium (glg4TitanEnvironmental Report, Appendix B). Since 1979,the Mill has not received any violation under its NRC approved groundwater monitoring program. To verify this apparent compliance, the Executive Secietary has required submittal of an historical Background dround Watei euality Report, pursuant to Part I.H.3 of the Permit. In May, lggg IUC and the utah Division of Radiation control (DRC) commenced an annual split sampling program for groundwater monitoring wells at the White Mesa facility. This program *u. .o*ir.hensivi in that it included all monitoring wells at the facility completed in it "-rtrutto* aquifer (not just pOC wells), and a large number of groundwater contaminants, including: heavy 111rtutr, nutrients, general chemistry analytes, radiologics, and volatile organic compounds (VOCs). t t t I I T I I I I I I t t I I I I I i I t i i i t t t i i i t t t t t t I Statement of Basis DRAFT December 1,2004 During the May, 1999 split sampling event excess chloroform concentrations were discovered in monitoring well MW-4, which is not a NRC POC well, found along the eastern margin of the site. Because these concentrations were above the State Ground Water Quality Standard (GWQS), the DRC initiated enforcement action against IUC on August 23,1999 thru issuance of a Groundwater Corrective Action Order, which required completion of: l) a contaminant investigation report to define and bound the contaminant plume, and 2) a groundwater corrective action plan to clean it up. Repeated groundwater sampling by both IUC and DRC have confirmed the presence of chloroform in concentrations that exceed the State GWQS along the eastern margin of the site in wells that appear to be upgradient or cross-gradient from the tailings cells. Other VOC contaminants have also been detected in these samples. After installation of 20 new monitoring wells at the site, groundwater studies appear to have defined the eastern and southern boundaries of the chlbroform plume. IUC believes the source of this contamination was caused by laboratory wastewater disposal activities that pre-dated mill operation. While the exact number and location of all the potential chloroform sources is still not yet resolved, an experimental long-term pump test was initiated in April, 2003 to investigate one possible cleanup methodology. While the contaminant investigation and groundwater remediation plan are not yet complete, the DRC believes that additional time is available to resolve these requirements based on the following factors: 1) hydraulic isolation found between the shallow and deep confined aquifers, 2) the large horizontal distance and the long groundwater travel times between the existing groundwater contamination on site and the seeps and springs where the shallow aquifer discharges at the edge of White Mesa, and 3) lack of human exposure for these shallow aquifer contaminants along this travel path. Upon completion of the contaminant investigation and before approval of the groundwater remediation plan, the DRC will provide a public comment period and hearing to inform the local community of the planned cleanup actions and receive comments thereon. With all this as a backdrop, the NRC delegated its uranium mill regulatory program to the State of Utah, effective August 16,2004. As a result, the DRC is the primary regulatory authority for the IUC White Mesa mill for both radioactive materials and groundwater protection. Shortly, the existing NRC Source Materials License will be converted to a State Radioactive Materials License (RML). tn this process, this proposed Permit will replace the groundwater protection provisions of the NRC Source Materials License. After review of the existing design, construction, and operation of the IUC facility; and after consideration of the requirements in both the Utah Water Quality Act (Utah Code Annotated l9- 5) and the Ground Water Quality Protection Regulations (Utah Administrative Code R317-6), the DRC has determined that a number of changes and enhancements are required in order to meet State requirements for groundwater protection. These changes are discussed in detail below. Maior Permit Requirements 1. Groundwater Classification (Part I.A and Table 1) - was assigned by the Executive Secretary on a well-by-well basis after review of groundwater quality characteristics for the shallow aquifer at the IUC White Mesa site. A well-by-well approach was selected by the Executive Secretary in order to acknowledge the spatial variability of groundwater aJ Statement of Basis DRAFT December 1,2004 ffil'#.?lii:jyf,r;'Ji?,,ffi1ffifi:ru1il"f,",1T*1il"ff-::;ll"-T,?ithe sharrow I classification at the IUC facility are discussed below: TDS Backeround Concentrations - the Executive Secretary has established a general policy that allows groundwater classification to be based on a statistical construct of the mean total dissolved solids (TDS) concentration plus the second standard deviation (X+2o). Using a well-by-well approach, this X+2o value would be derived from available data from each individual well. Inherent in this approach is the assumption that the TDS data used for this basis is composed solely of data representative of background or natural conditions at the site, and not groundwater quality altered by the facility in question. In determination of the background TDS concentrations, the Executive Secretary typically considers concentration trend or time series analysis. Spatial analysis of the data may also be considered to evaluate proximity of the reported concentrations to possible contamination sources. lncreasing contaminant trends in individual wells, spatial contaminant distribution pattems, and other statistical considerations may be used to identify the presence of man-caused groundwater pollution at the site. These types of evaluations are especially important at existing facilities that pre-dated the 1989 promulgation of the GWQP rules; such as the IUC White Mesa site. Evaluations of this kind will be submitted shortlyby IUC in the Background Groundwater Quality Report (Part I.H.3), and reviewed by the Executive Secretary. Pending this submittal, the Executive Secretary has decided to base the well-by-well groundwater classification on the average TDS concentration available, and omit any consideration of concentration variance. This approach is conservative, in that it will result in a generally lower concentration basis for the classification decision. At some fufure date, when such evaluations are available and found acceptable by the Executive Secretaty, the background TDS concentrations will be revised, and the Permit re-opened and modified, pursuant to Part fV.N.2 or 3 of the Permit. Impact of Historic Wildlife Pond Recharge (Local Groundwater Mounds) - IUC has demonstrated that four (4) existing wildlife ponds at the White Mesa facility discharge water to the shallow aquifer, that in turn has created two (2) local groundwater mounds; one (l) each at the Northern and Southern Wildlife Ponds (see l0/15/02 IUC submittal, water level map). The existence of these groundwater mounds has been confirmed by the Executive Secretary thru both independent water level measurements and preparation of a water table contour map for the White Mesa facility for the September,2002 split sampling event (see Attachment 1, below). The quality of water maintained in these wildlife ponds is likely high, in that it is derived from Recapture Reservoir. Water from this reservoir is conveyed to the IUC facility via a buried pipeline, where part of the supply is used in milling operations, and another part is diverted to the wildlife ponds to support aquatic life and habitat for migrating waterfowl (personal communication, Mr. Harold Roberts, IUC). No lining system was constructed under any of the wildlife ponds (ibid.). As a result, the wildlife ponds provide a nearly constant source of high quality recharge to the shallow aquifer at the site. Therefore, it is possible that I I T I T I I t I T I T I t T I I I A. B. 2. i J t i i t t i t t t i i i i t tj t Statement of Basis DRAFT December 1,2004 this recharge has significantly improved localized water quality conditions in the shallow aquifer; thereby encouraging a wide variability in quality conditions. This and other sources of water quality variation give rise to the need for well-by- well protection of groundwater quality at this site. C. TDS Basis for Classification - one key element in determination of groundwater class is the TDS content of the groundwater, as outlined in the GWQP Rules, see Utah Administrative Code (UAC), R317-6-3. Groundwater quality data collected by both IUC and the DRC show the shallow aquifer at White Mesa has a highly variable total dissolved solids (TDS) content, rangrng from about 600 to over 5,300 mg/l (see Attachment 2, below). Using all available TDS data, and after calculation of average TDS concentration for 33 wells including both POC and temporary wells, the Executive Secretary determined that 16 wells at the facility appear to exhibit Class II or drinking water quality groundwater. Seventeen (17) other wells appear to exhibit Class III or limited use groundwater at the site. For details, see Attachment2, below. Close review of the available data shows that the historical IUC data, the recent IUC split sampling data, andthe corresponding DRC split sample results are largely comparable, with a few exceptions. In the case of historical IUC well MW-19, the IUC historical TDS data (10179 thru 5/99) produced an average TDS that was significantly lower than the average TDS based on the recent DRC or IUC split sampling data (5199 thru9102). Because the older IUC data are conservatively lower, the Executive Secretary chose to rely on the older IUC TDS data to determine groundwater class for well MW-19. D. GWOS Basis for Classification - another key element in determination of groundwater class is the presence of naturally occurring contaminants in concentrations that exceed their respective GWQS. [n such cases, the Executive Secretary has cause to downgrade aquifer classification from Class II to Class III (see UAC R317-6-3.6). Historic IUC data and more recent split sampling data suggest that several groundwater contaminants may be found with concentrations above their respective GWQS in a number of wells at the site. These wells and parameters from recent split sampling are summarizedinAttachment 3, below. Some of these wells with excess contaminant concentrations are associated with the on-going chloroform investigation at the east margin of the site (see 8123199 Ground Water Corrective Action Order). With regard to historic excess concentrations found at the site, the NRC previously deemed these to be of natural origin. While some or all of these excess concentrations may be natural, the Executive Secretary has not yet fully evaluated the available data. For this and other reasons, the Executive Secretary has required IUC to evaluate groundwater quality data from the existing wells on site, and prepare and submit for approval a Background Groundwater Quality Report, in Part I.H.3 of the Permit. After review and approval of this report the Executive Secretary may determine the origin of these excess contaminant concentrations, and an appropriate groundwater classification(s) for the White Mesa facility. Backeround Ground Water Oualitv (Part I.B. I.H.3. and I.H.4) - a significant amount of historic groundwater quality data has been collected by IUC for many wells at the facility. In some cases, these data extend back about 25 years to September,1979. Statement of Basis DRAFT December 1,2004 However, the Executive Secretary has not yet completed an evaluation of the historic IUC data, particularly with regards to data quality, and quality assurance issues. Such an examination needs to include, but is not limited to: justification of any zero concentration values reported, adequacy of minimum detection limits provided (particularly with respect to the corresponding GWQS), adequacy of laboratory and analytical methods used, consistency of laboratory units of reporting, internal consistency between specific and composite types of analysis (e.g. major ions and TDS), identification and justification of concentration outliers, and implications of concentration trends (both temporal and spatial). During the review conducted to date, several groundwater quality issues came to the attention of the Executive Secretary that also need to be addressed and resolved by the Permittee in the Background Groundwater Quality Report. Some of these issues, include the following: A. Several Contaminants Recently Found to Exceed Respective GWQS - recent DRC split-sampling of groundwater at the IUC facility has found that several contaminants exceeded their respective GWQS during one or more of the four (4) split sampling events conducted by the DRC between May, 1999 and September, 2002. With regards to those wells considered for tailings cell monitoring, the contaminants with excess concentrations include the following (see Attachment 3, below): l) Manganese (MW-3, MW-14, MW-32 [formerly TW4-17]) 2) Nitrate (MW-4), 3) Selenium (MW-l, MW-4, MW-l5, MW-l7), and 4) Uranium (MW-3, MW-4, MW-14, MW-15, MW-17, and MW-18). The exceedances found in well MW-4 appear to be related to the chloroform contamination. While the remaining exceedances may be due to natural causes, the Executive Secretary has not fully evaluated the available data, and has therefore required IUC to perform this evaluation. B. Lone-Term Increasing Uranium Trend: Downsradient Wells - while recent groundwater quality data from the last l8-months suggests a stable or decreasing trend, the long-term uranium concentrations for the last l l to 15 years indicate an increasing trend exists in three (3) downgradient wells at the IUC facility, including: Mw-14, Mw-15, and MW-17 (Attachment 4, below). IUC believes that the cause for these increasing uranium trends is due to geochemical changes brought on by the effects of the groundwater mound created by the nearby wildlife ponds. While evidence to substantiate this has yet to be provided to and approved by the Executive Secretary, the exact cause for these long-term increasing trends is currently unknown, and may be due to a variety of factors that deserve further study and explanation. C. Downeradient Uranium Spatial Concentration Hieh - the same three (3) downgradient wells that exhibit a long term increasing uranium trend are also found near a spatial concentration high, located downgradient of Tailings Cell4A. A fourth well, MW-3 is also found inside this concentration high and exceeds the State GWQS (30 ug/l). For details, see the uranium isoconcentration map based on September,2002 DRC split sampling results in Attachment 5, below (DRC I I I I I I I I I I I I t I I I t t I j Statement of Basis DRAFT December 1,2004 art - the GWQP Rules provide for the 1"j::lyr111orctg.""d water Protectior LEek (GwPis) to be used as early-warningindicators of impending groundwater pollution. Under this approa"rr, ."-prirlr." i,determined after comparison of groundwater quality monitoring ,.ruit, wiitr ttre GWpLsin each well and for each parameter. said GWpLs are set in the permit afterdetermination that the particular contaminant is detectable in groundw atet atthe facility,its corresponding Gw_es, and its analytical Minimum Detect[n Limit (MDL). Asprovided in the GWQP Rules, these GWPLs are calculated as outlined in Table l, below. Because background groundwater quality at the IUC facility has not yet been approved,the Executive Secretary cannot determine if any contaminant is naturally occufrng andtherefore detectable or undetectable for purposes of selecting GWpLs in each well.Consequently, the Executive Secretary *itt-iritiatty assign the GWpLs as if they were map U238-9-02.srf). As shown there, well MW-14 represents the maximumuranium concentration during the September,2002split sampling event (56.7ugll). It is interesting to note that the average linear groundwater velocity(hereafter velocity) found in well MW-14 is one of the highest on site, 62feet/year (10/t9104 Hydro Geo Chem,Inc [HGC] Report, Table l). Furthermore,well MW-14 appears to be located on an uppur.rt prif.ora groundwater flowpath found between it and well MW-I1 which hasihe highei velocity at the site,135 feet/year (ibid., and Attachment L2,DRC groundwater velocity ctntour mapgwflowrate.srf, below). Two other uranium concentration high points exist at the White Mesa site whereuranium exceeds the State GWQS, including IUC wellsTw4-lg and TW4-l l (seeAttachment :,-Dlc mapU23g_9-02b.srf). However, these two wells appear to beassociated with the chloroform contamination plume. The cause for the uranium concentration highs found downgradient of Cell 44 and itscoincidence with an apparent preferred groundwater flow path is unknown at this time,and may be due to a variety of factors that deserve further study. These observations andothers indicate that great care must be taken by the Executive Secretary in determinationof background groundwater quality for the compliance monitoring weils at the site; inorder to ensure that any GWCL established by Fermit has not been affected by historicfacility operations. As a result, a detailed evaluation of these and other gro.rrri waterquality concems was added to the Permit ln Part I.H.3 (Background Gro'undwater eualityReport). After submittal of this report and resolution oithese and other groundwaterquality issues, an agreement can be reached regarding descriptive groundwater qualitystatistics and determination of background ground*ui", quality at the IUC facility. Atthat point, the Permit will be re-opened andhe background groundwater concentrationsand related compliance limits modified, see discussion below. Because Part I.H.1 of the Permit calls for installation of several new monitoring wellsgound the tailings cells, background groundwater quaiity will also need to be Jeterminedfor these monitoring points. To this end, Part I.H.4 was created to require IUC to collectat least eight (8) quarters of groundwater quality data, and submit a second report forExecutive Secretary approval to establish background groundwater quality for the.ewells' Upon approval of this report, the Executive Secietary will re-open the permit andestablish groundwater classifications, background ground water quality concentrations,and compliance limits, as appropriate and uutrro.irea by part IV.N.2 and 3. j i I I J I Jj j J I I I I I I Statement of Basis DRAFT December 1,2004 ..undetectable". After submittal and Executive Secretary approval of the existing well Background Ground Water Quality Report, pursuant to Part I.H.3, the Permit can be re- op.r.d and the GWPLs modified, see discussion below. Accordingly, the GWPLs set toaay in Table 2 of the Permit were calculated by use of the classification factors, being 0.25 and0.5 times the GWQS for Class II and III groundwater respectively. Table l. General Ground Water Protection Level Determinations 1) BG = background concentratron 2) MDL = minimum detection limit During a meeting of August 12,2003,IUC staff expressed a concern with this approach in that it does not recognize spatial variability of groundwater quality in the aquifer. Accordingly, IUC asked the Executive Secretary to downgrade the aquifer classifications for the Wttit" Mesa Facility, from Class II to Class III, in order to ensure that a large enough factor is used in determination of the GWPL, so that natural temporal variations in grJundwater quality at each well do not cause unnecessary non-compliance under the permit. At the treart of ttris concern is the need to avoid false positive violations of the GWpLs assigned under the Permit; unnecessary groundwater monitoring and analytical costs; unneeded enforcement efforts; and undue public concem. The Executive Secretary acknowledges these "on""*J, and in an effort to address them has arrived at an alternative approach to groundwater quality compliance that will recognize natural variations and still protect the groundwater resource. This approach incofoorates the use of Ground Water Compliance Limits (GWCL) on a well-by-well basis, instead of GWPLs. Under the GWQP Rules, groundwater quality compliance is determined in a step-wise fashion, as follows [see UAC R317-6-6.16(4) and (B)]: A. Accelerated Monitorine IUAC R3l7-6-6.16(A)l - if the concentration of a "ortr*irrart i, ury ra*ple exceeds the Permit limit, then the Permittee is required to initiate more frequent groundwater quality monitoring to determine the compliance status of the facility. Because this section generically refers to a "p"r-it limit" and not specifically to the GWPLs defined in UAC R317-6-4, the Executive Secretary has the latitude to use another basis to determine a maximum contaminant concentration for groundwater quality compliance purposes at a permitted facility. This maximum contaminant concentration is referred to in the IUC Permit as a Ground Water Compliance Limit (GWCL), and will be defined as the mean concentration plus the second standard deviation (X+2o). This GWCL will be defined on a well-by-well basis for each key indicator parameter required for groundwater quality monitoring at the IUC facility. On a statistical basis, and after collection of a sufficient number of samples, the Xt2o concentration corresponds to the 95Yorrypex confidence limit; which equates to a2.5o/o (0.025) probability of any parameter in any well falsely exceeding its GWCL during any given samPling event. I I t I I I I I I t I I I t I I Groundwater Class TDS Limit Groundwater Protection Levels Undetectable Contaminant (ereatest ofl Detectable Contaminant (ereatest of; tr 1.25 * BG u 0.25 * GWOS MDL (''1.25 * BG 0.25 * GWQS m 1.25 * BG 0.5 * GWQS MDL 1.5 * BG 0.5 * GWOS Footnotes: i t t I t t i i t I t i t t t t i i i Statement of Basis DRAFT December 1,2004 B. Non-Comoliance Status [UAC R3l7-6-6.16(8)] - the IUC facility will be considered to be out of compliance when two (2) consecutive groundwater quality samples exceed the respective GWCL (X+2o concentration) for each well and contaminant in question. On a statistical basis, and after collection of a sufficient number of samples, this equates to a 0.062% (0.0252) probability that any given well and parameter will twice, consecutively, falsely exceed its respective GWCLl. Pursuant to these considerations, Table 2 of the Permit has been structured to provide the mean concentration, the standard deviation, and the GWCL (X+2o) for each compliance monitoring well and monitoring parameter required at the facility. The Executive Secretary believes that this approach will protect the local groundwater resource, in thatit: 1) recognizes the heterogeneity in groundwater quality apparent at the White Mesa site by assigning GWCLs on a well-by-well and contaminant specific basis, and2) allows for natural temporal variation in the groundwater quality by use of the x+2o concentration limit. It is important to note that the X+2o concentration for each compliance monitoring well and contaminant must be based on the natural variance of groundwater quality atthat location, and not on concentrations that have been altered by man thru pollution. This issue is especially important for facilities that pre-existed the GWQP Rules, which were adopted in 1989. For this reason, the Permit requires IUC to prepare and submit for approval a Background Groundwater Quality Report for existing monitoring wells at the facility (see Part I.H.3). After review and approval of this report, the Executive Secretary will determine the mean concentration, standard deviation, and X+2o GWCL for each well and contaminant listed in the Permit. In the meantime, the Executive Secretary has set the GWCL concentrations in Table 2 of this Permit as the GWPL concentrations determined by the formulas outlined in Table l, above. Three (3) exceptions to this include chloride, sulfate, and TDS, which have no corresponding GWQS and therefore require pre-determination of background concentratiorts for each parameter and well. Consequently, the GWCL for these three (3) parameters will be determined later after approval of the Background Groundwater Quality Report required by Part I.H.3 of thePermit. The Executive Secretary recognizes that the fractions approach used to set the GWCLs in this Permit does not account for natural variations in groundwater quality. Hence, false positives in the groundwater monitoring data may occur until the Background Groundwater Quality Report, required by Part I.H.3 is submitted, approved by the Executive Secretary and the GWCLs re-established in the permit. Number and Twes of GWCL Parameters (Permit Table 2) - the process of selecting the groundwater quality monitoring parameters for the permit included examination of several technical factors. Each of these is discussed below. A. Feedstock Materials - one source of contaminants that may be discharged from the White Mesa facility is the number and type of contaminants that might occur in feedstock materials processed at the mill. During early operation of the White Mesa mill, it is anticipated that uranium ores were primarily derived from two (2) main sources: strata-bound deposits of the Colorado Plateau region, and solution breccia pipe deposits from the Arizona Strip. Natural contaminants known to I The Executive Secretary recognizes that this probability for a false positive result applies to a given parameter in agiven well, and that the probability for false positives is higher when considering a group of wel-ls thai are sampled for collection of parameters in the same monitoring event. 9 Statement of Basis DRAFT Ore Contaminants Near White Mesa (l) December 1,2004 B. occur in these uranium ore deposits have been determined by the U.S' Environmental Protection Agency (EPA), as summarized in Table 2, below (EPA, 1995, p. l1). From this research it appears that 12 metals are common to the uranium ores processed by the IUC White Mesa facility. Consequently, all of these metals have been listed in Table 2 of the Permit as groundwater compliance monitoring parameters. Table 2. Reported L ramum Ore Source Known Contaminants Colorado Plateau (strata-bound) Arsenic Lead Silver Chromium Molybdenum Vanadium Cobalt Nickel Zinc Copper Selenium Arizona Strip (solution breccia pipes) Coooer sulfides Lead sulfides Iron sulfides Zinc sulfides l) Data from EPA.995.p. ll Other contaminants may also have been added to the tailings waste via processing of alternate feedstocks authorized by the u.S. Nuclear Regulatory commission (NRC). However, any evaluation made to date by the Executive Secretary iegarding the number or types of contaminants that might be present in these alternate feed materials has not been considered here for inclusion as groundwater compliance monitoring parameters. process Reagents - another source of contaminants that could be discharged to groundwater from the facility include mill process reagents. Information f,rovided by EPA for acid leach processing at conventional uranium mills has Leen combined with process information from IUC in Table 3, below. Quantities of reagents actually used by IUC at the White Mesa mill are listed in Table 3 in bold face t1pe. Daily volumes of reagents actually used by IUC are summarized and ranked in Table 4, below. From this information it is clear that the tailings wastewater disposed at the IUC White Mesa mill should have an extremely low pH, and contain significant quantities of sodium, chloride, ammonia, and kerosene. Source Term Abundance - some limited historic wastewater quality sampling and ,"rb." h* b*" done at the IUC White Mesa tailings cells. Some of this work included pre-construction laboratory bench top testing by IUC to estimate the possible contaminants that might be discharged in the tailings wastewater. The i.tRC ulro published other estimates of expected tailings wastewater chemistry. Several historical samples of the tailings effluent have been collected and analyzedbyboth the NRC and IUC to determine the chemical properties of the tailings wastewater for a limited number of parameters (see Attachment 6, below). Little information is available regarding organic contaminants in the tailings effluent. All information available to the DRC is summarized in Table 5, below. C. 10 lt i t t t t i t t I t i i I t t t I t t \ Statement of Basis Table 3 S DRAFT December 1,2004 Footnotes: I ) For additional information on common acid leach circuit processes at conventional uranium mills, see EpA, 1995 , pp . 22-25 .2) Total daily pounds used of each reagent at the IUC white' Mesa uranium mill is listed in brackets il, as provide d in the 5l2g/99IUC report, p. A-8' Table A-1 and the 1/30/78 Dames and Moore Report, p. 3,-5 and Plates 3.2-1 (uranium milling iiocess), 3.2-2 (copper recovery), and,3.2-3(vanadiumrecovery). Bothofthesedocumentsdetailuseofmanganeseoxidelio,0oolb/dayliiihreep.o"".rrt"pr,including: l)uraniumoreoxidation, 2) uranium leaching and clarification, and 3) copp"r .eior"ry (eaching). Howevir, use ofmanganese oxide was listed in theseoriginal mill documents as an option in case the preferred oxidizer, sodium chloriie, was not available or was not economic. History ofthe millshows that concems about price or availability of sodium chlorate never materialized, hence manganese oxide was never used in any ofthesethree process (personal communication, Mr. Harold Roberts, llll5t}4).3) Also known as tlre uraniferous ion stabilization step (EpA, 1995,pp.22_25).4) Total "organic" used daily = 1,680 lb/day, ofwhich kerosene is reported to be 95% (ibid.). DRC staffthen assumed that remainder ofthe"organic" used in the solvent extraction circuit = amine type compounds used for anionic solvent extraction in the kerosene carrier (g4 lb/day).5) IUC reports only ammonia (NH3) used in the yellowcaketrecipitation step [5l28l99IUC report, p. A-g, Table A-l and l/30/7g Dames and MooreReport, p. 3-5 and Plate 3.2-l (uranium milling process)]. However, on." in un aqueous ro.m, *," ammonia likely occurs as ammonia hydroxidein solution. 6) Copper recovery was once envisioned for the White Mesa mill (l/30/78 Dames and Moore Report, pp. 3-6 and 7, and plate 3.2-2), however itwas never implemented (personal communication, Mr. Harold Roberts, 10/15/04).7) Vanadium recovery information for White Mesa mill from 1/30/78 Dames and I\.ioore Report, pp. 3-7 to 10, and plate 3.2-3. Table Rankin4. Ranklng of Reported White Mesa Mill Reagent Daily Consumption (lb/dav) Sulfuric acid (H,SO,)392,000 Chlorides (NaCl)15,000 Soda Ash (Na2COr)10,000 Sodium chlorate (NaClO.,)6,000 Ammonia 2,000 Kerosene 1,596 Flocculants 600 Amines (uranium extraction solvent)84 u White Mesa M ling Processes and Added. Process Step Actua and Potential Contaminants Added Uranium Milling Operations (l) Ore Oxidation Sodium chlorate (NaClOr) [6.0001b/davl (2) Uranium Leaching and Clarification (3) Sulturic acid (H2SOa) [392,000|b/day] (2) Flocculants [600 lb/day] (z) Solvent Extraction Secondary amines with aliphatic side chains [84 lb/davl (a) High molecular weight tri-alkyl amines Quaternary ammonium compounds Kerosene [1,596 lb/davl (o)Tributvl phosohate modifier Long chain alcohols Pregnant Liquor Strinpine Chlorides (NaCl) [15,000 tb/dayl e)Sulfates Yellowcake Precioitation Ammonia hydroxide (NH3OH) [2,000 lb/davl (s) Sodium hydroxide (NaOH) Copper Recoverv (6) Vanadium Recovery (7) Redox / pH Adiustment Sodium chlorate (NaClO3) [6,000 lb/davl (2) Solvent Extraction Kerosene [,596 lb/day] (a)Secondary amines with aliphatic side chains [84 lb/davl (a) Pregnant Liquor Stripping Soda Ash (Na2CO3) solution [10,000 cwes o) tb/davl @) Vanadium Precioitation Ammonia hydroxide (NIHIOH) [2,000 lb/davl (5) i From Table 3, above. September, 1980 - March, 2003 IUC / NRC Tailings Wastewater 1980 NRC Generic EIS Estimate(2) (me/L) 1979 rrJC Bench-top Estimate(l)Std. Dev. (me/L) 3,130.65 64,913.9 t48.18 I15.40 I i t' : ll li li lli ll I ll I t1 lr I I I T t I I December 1,2004 Wastewaterof Estimated and Measured IUC TailiTable 5. Statement of Basis DRAFT i Jj J t ij t i J J J It t II J i i J Statement of Basis DRAFT December 1,2004 State GWQS (me/L) 1979IUC Bench-top Estimate(l) (me/L) I98O NRC Generic EIS Estimate@) (me/L) September, 1980 - March, 2003 IUC / NRC Tailings Wastewater Samples(3) Reported Concentrations Avg/ GWQS Ratio Min. (mg/L) Max. (me/L) Average (ms/L) Std. Dev. (me/L) Sample CountContaminant Sodium N/a 4,900 200 1,40c 10,00c 5,808.7 3,072.10 19 Strontium 4 3.6 t4 7.0 4.74 4 1.8 Ihallium 0.002 0.7 45 16.0 20.54 8 7,988.1Iin22,000 <5 5 5 #DIV/O!3 Iitanium 150 6.5 33.3 19.1 ll.7c t2 0.13 Uranium 0.03 2.5 5.0 r54 93.C 41.20 t7 3,120.6 Vanadium 0.06 240 0.1 l3f 51(263.1 r I l.9l t7 4,385.3Zinc59t805(l30c 640.6 598.48 5 128.1 Zirconium 2.3 38.5 12.2 12.00 t4 Rldiolosics bCilL) Gross Alpha l5 2s0.00c 14,000 189,000 120,493 50,345.1 l5 8,032.9 Gross Beta 74 116,000 68,942 35,918.8 l5 #DIV/O! Lead-210 2.0 680 20,700 3,385 4,660.1 t7 1,692.6 Thorium-230 l8 3,650 76,640 21,748 15,394.8 l8 1.208.2 Thorium-232 l6 49 t2t 87 )1 A t2 5.4 Polonium-210 t.c 1,410 1,410 1,410 1,410 Radium-226 4C 1,69C 1,027 497.2 t5 Radium-228 1.9 1.9 1.9 #DIV/O! Iotal Radium 5 42 1,70c 942 553.2 t9 188.4 Selected VOCs fus/l) Acetone 700 28 514 192 278.4 J 0.3 Benzene 5 <5 <5 2 2-butanone (MEK)4,00[lt 1 5.13 r 3.38 2.13 J 0.003 Carbon Disulf,rde 70c I6 t6 l6 #DIV/O!I 0.02 Carbon tetrachloride 5 <5 <5 <5 2 hloroform 7Q (.16.84 10.28 5.77 J 0.15 I , l -Dichloroethane ola <5 <5 <5 2 1,2-Dichloroethane 5 <5 <5 5 2 Dichloromethane 5 l0 ll l0.s 0.71 2 2.1 Tetrahydrofuran 46 n-a n-a 1-a n-a n-a n-a Toluene 1,000 <5 6.25 s.62 2 Vinyl ctrloride 2 l0 l0 l0 2 Xylene (total)10,00c 5 <5 5 2 Sel et'tecl Semi-VOCs tus/l ) Benzo(a)pyrene 0.2 <10 <10 <10 2l Bis(2-ethylhexyl)phthalate 6,0 I I I J 0.2 3hrysene 48 <10 <10 10 2 Diethyl phthalate 5,000 <10 l8.l l8. t J 0.004 Dimethylphthalate Nia 2.7 2.7 2.7 J Di-n-butylphthalate 70c 1.08 1.08 l.0t J 0.002 Fluoranthene 28C <10 <10 t0 2 Z-Methylnaphthalene 4 l0 <10 <10 2 Naphthalene 100 2.44 2.44 2.44 J 0.024 Phenol 4,000 l0 38.4 38.4 J 0.01 Footnotes:1) From May, 1979 NRC Final Environmental Statement, p. 3-11, Table 3.1. Original concentrations reported in units of gm/liteq converted here to mg/liter.2) From September, 1980 NRC Final Generic EIS, p. M-5, Table M.3. Original concentrations reported in units of ugAiter; converted here to mg/I.3) Based on samples collected by IUC and the U.S. NRC between September, 1980 and March, 2003. For details see Attachment 6, below. l3 Statement of Basis I T I I I t I I I t I I I I I I I I I DRAFT December 1,2004 From this information it appears that the pre-construction laboratory testing under-estimated the actual concentration of several contaminants that would accumulate over time in the tailings wastewater, including: ammonia, chloride, fluoride, TDS, arsenic, cadmium, iron,lead, mercury, sodium, uranium, vanadium, and zinc. [n some cases these estimates under-predicted the average measured concentrations by 3-orders of magnitude, e.g., mercury, molybdenum, uranium, and vanadium. Other pre-construction estimates over-predicted the average measured concentrations, including: silica, barium, calcium, manganese, and gross alpha. These concentration differences are indicative of either variaUitity olthe feedstocks input to the White Mesa mill, the variability of the milling pio".s itself, and/or recycling of process fluids from Cell 1 back into the milling proc.s combined with the effects of seasonal evaporation. In order to better define the tailings wastewater source term concentrations and characteristics, the Executive Secretary has added a requirement to the Permit in Part I.8.8 to mandate periodic sampling and analysis of this wastewater. Review of the available data shows that many of the tailings wastewater contaminants have had an average concentration that was 50-times greater or more than the corresponding GWQS, including (see bold values in Table 5, above): ammonia (N), 16 heavy metals (arsenic, beryllium, cadmium, chromium, cobalq copper, iron,lead, manganese, mercury, molybdenum, nickel, thallium, uranium, vanadium, and zinc), fluoride, gross alpha, lead-2 1 0, thorium-2 3 0, polonium-210, and total radium. Of these, ammonia has been introduced as a ieagent in the milling process. Of the 16 heavy metals, 1l appear to be derived from ttre Colorado Plateau ore feedstocks, including: arsenic, chromium, cobalt, copper, iron,lead, molybdenum, nickel, uranium, vanadium, and zinc (see Table 2, above). Manganese is also a coflrmon contaminant in Colorado Plateau ores (rersonal communication, Mr. Harold Roberts, 10/18/04). The beryllium, Jadmium, fluoride, mercury, and thallium concentrations seen in the IUC tailings wastewater in excess of 5O-times the respective GWQS, appear to be derived from Arizona Strip ores and altemate feed materials (ibid.). Based on their elevated source term concentrations, all of these contaminants should be considered as potential groundwater monitoring parameters for the White Mesa facility. As for organic contaminants that might be found in the tailings wastewater, .., kerosenels probably the most significant in terms of IUC's reported daily mill consumption, about 1,600 lblday, see Tables 3 and 4, above. Kerosene is a mixture of many petroleum distillates, generally composed of hydrocarbons in the range of Ce to Cro (Risher and Rhodes, p. 105). Researchers who have studied "rrriro*.ntal releases of kerosene to gfoundwater have recommended use of several groundwater monitoring parameters, including: benzene, toluene, xylenes (ortho, meta, and para), ethylbenzene, naphthalene, etc (Thomas and Delfino, p, 96). These VOCs generally constitute the most soluble components of kerosene (Deutsch and Longmire, chp. 10, p. l9). of these compounds, all have been detected in groundwater at IUC in the area associated with the on-going chloroform investigation, with the exception of ethylbenzene, see discussion below. It is also important to note that these and other aromatic hydrocarbons commonly comprise about l0-20%of the total content of kerosene, (Risher and Rhodes, p. 105). On its own merits, naphthalene has been found to constitute t4 l) 2) D. i i i t t t i i t t t i t i i i t i i Statement of Basis DRAFT December 1,2004 about 3% of kerosene by volume (ibid., p. 107). Based on this information, the Executive Secretary has decided to add four (4) of these VoCs as groundwater monitoring and compliance parameters in Table 2 of the Permit: benzene, toluene, xylenes (total), and naphthalene. contaminant Mobility- during selection of the groundwater monitoring parameters to be required by the Permit, it is important to consider a contaminant's ability to travel in a groundwater environment. For most contaminants this is controlled by its soil-water partitioning (IQ) coefficient. Ideally these IQ values are determined independently for each Permitted facility, using laboratory or field-scale tests with site-specific groundwater and soils and/or aquifer materials. [n cases where site-specific IQ information is not available, the Executive Secretary has set a precedence of using the lowest Ie values available in the literature to represent the site in question. A summary of literature I(a values is found in Attachments 7 and 8, below. Anionic contaminants - anions generally exhibit very low I(6 values and need to be considered as groundwater monitoring parameters at the IUC facility. These anions include: chloride, fluoride, and sulfate. chloride is currently a groundwater monitoring parameter required under the NRC license, and has been included as a compliance monitoring parameter in Table 2 of the Permit. Fluoride, as mentioned above, has been found in the tailings wastewater with an average concentration that is more than 400-times its respective GWQS, and therefore is also included as a GWCL parameter. Sulfate is a blproduct of the large daily volumes of sulfuric acid used in the uranium leaching stage of milling (see Table 3, above, and EPA, 1995, p.22). As a parent contaminant, sulfuric acid is the most predominant reagent used in the mill where it is consumed at a rate of 392,000 lb/day (see Table 4, above). Accordingly, sulfate is extremely abundant in the IUC tailings wastewater with an average concentration of almost 65,000 mgll (see Attachment 6, below). At this average level, sulfate is more than l4-times more abundant in the tailings wastewater than chloride, which has been a historical groundwater monitoring parameter under the NRC license. Heavy Metals - of the heavy metals known to exist in uranium ores, all were found to have a lowest literature I(a value of less than2.0llkg, with the exception of lead @.5lkg) and vanadium (50l/kg), see Attachment 7, below. However, after consideration of the high acid conditions found in the tailings wastewater, with an average pH of 1.83, all these heavy metals could easily stay in solution and not partition on aquifer materials. To date, no information has been provided by IUC regarding site-specific Ka data for White Mesa soils and rock. Neither has any quantitative, site- specific information been submitted regarding the bulk or trace mineral composition of soils and bedrock at the site that could provide buffering capacity for any low-pH tailings solutions. Consequently, the Executive Secretary believes it is not appropriate to eliminate any of the uranium ore related heavy metals as groundwater compliance monitoring parameters. Therefore, 14 ore related metals were included in the Permit as GWCL Statement of Basis I I t I I t I I I I t I t I I t I I I 3) DRAFT December I,2004 parameters, including: arsenic, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, selenium, silver, uranium, vanadium, andzinc. Four (4) other heavy metals found in the IUC tailings wastewater appear to be derived from Aizona Strip ores and altemate feed materials, including: beryllium, cadmium, mercury, and thallium. All four (a) of these metals have average tailings wastewater concentrations in excess of 50-times the respective GWQS, ranging between 126-times (beryllium) to 7,988-times (thallium), see Attachment 6, below. Literature low IQ values for these four (4)metals also vary widely, ranging from 0.0 l/kg (thallium) to 3221/kg (mercury). Again, based on the high acid environment known to exist in the tailings wastewater and the unknown buffering potential expected in the subsurface formations, the Executive Secretary believes it prudent to include all of these four (4) metals as GWCL parameters in the Permit (Table 2). In the future, IUC may provide additional site specific information regarding contaminant K6 values, and soil and aquifer geochemical composition and buffering capacity information as a part of the contaminant transport modeling report required by Part I.H.1 1. After review and approval of this supporting information and the report, the Executive Secretary will re-evaluate the need to retain all heavy metals listed above as GWCL Parameters. Volatile Oreanics in Tailinss Wastewater - at least five (5) volatile organic contaminants (VOC) have been found in the tailings wastewater, including acetone, 2-butanone (methyl ethyl ketone or MEK), chloroform, naphthalene, and toluene (see Attachment 6, below). None of these contaminants exceeded their respective GWQS. However, relatively significant concentrations of acetone were detected. The possible source term for naphthalene and toluene may be the large daily volumes of kerosene used in the solvent extraction circuit, see Tables 3 and 4 above. Research by others has found that aromatic hydrocarbons, such as benzene and related compounds (toluene, xylenes, etc.), commonly constitute lO-20% of kerosene fuel oil (Risher and Rhodes, p. 105). By itself, naphthalene has also been found to constitute about 3%o of kerosene by volume (ibid., p. 107). Naphthalene and toluene have also been found to have low IQ values, 0.398 and 0.009 LlKg,respectively (see Attachment 8). These data support the use of naphthalene and toluene as groundwater compliance monitoring parameters under the Permit. As for the remaining tailings wastewater VOCs, the source term may be wastewater from the mill's on-site laboratory, which began operation in lg77,but did not begin to discharge to Tailings cell 1 until June, 1980 (9l3)l9g IUC Report, p. 6). These remaining VOC's also have very low literature Ka values of 0.001, 0.015, and0.024 L/Kg for acetone,2- butanone, and chloroform, respectively. 16 i J J t J i J J J I I J t J i t J J i Statement of Basis DRAFT December 1,2004 unfortunately, the IUC voc data in question is not considered representative of actual field wastewater conditions in the tailings disposalcells, for several reasons, including 13 volatile compoundshave been found in detectabl" .orr"ert ution in IUC groundwater since a)siqgle Sample - the data available is derived from only I samplecollected from the slimes drain, and may not be representative ofconcentrations in all the tailings cells over the opeiating history ofthe facility (see Attachment 6, page 2), unknown sample Date - no sample date was provided for the IUCsample. consequently, it is difficult to know just when in thehistory of the facility the sample was collected, and Missine Sample Information - no information was availableregarding how the sample was collected, preserved, and analyzed. Based on this lack of source term characteization, the Executive Secretarytook a conservative approach and has required all five (5) of these voc,sas GWCL parameters in Table 2 of the permit. Furthermore, a compliance schedule item has been added to the permit to require IUC to bettercharacteize the tailings wastewater quality conditions, see parts I.E.g andI.H.s. b) c) May,1999, see Attachment 9, below. Of these, 12 w:ereorganic compounds including: six (6) chlorinated solvents, five (5jpetroleumdistillates, and one (l) non-chlorinated organic solvent ftetrarrvarofuran).of these 12 vocs, all appear to have v".y lo* Ie values, rurrgirg from0.009 (tetrahydrofuran) to 0.39g (naphthalene) L/I(g, andwould thereforebe very mobile in a groundwater environment, see Attachment g. consequently, if any of these contaminants have potential to be foundwastewaters generated at the IUC facility, they should be considered asGWCL parameters under the permit. a)chlorinated Solvents - the source term for the chlorinated solvents may have been pre-operational laboratory wastewaters dischargedto septic tank leachfields at the mill site. Since about June, lggl these wastewaters have been discharged to Tailings cett t. orthese six (6) chlorinated solvents, thrie (3) have b-een found withgroundwater concentrations that exceed their respective GWeS,including: chloroform, carbon tetrachlorid", urrd di.hloromethane (see Attachments 3 and 10, below). In order to ensure an adequatecharacteization is completed and to better coordinate groundwater monitoring for both the tailings cells and the chloroforir investigation, all three of these chlorinated voCs were included asgroundwater monitoring parameters in Table 2 of the permit. Peholeum Distillates - for the five (5) petroleum distillates detected in site groundwater, all are aromatic hydrocarbons, withfour (4) derivatives ofbenzene (benzene, toluene, xylene, and1,2,4-timethylbenzene), and one ( I ) polynuclear- artmatic(naphthalene). As discussed above, the source term for these b) Statement of Basis DRAFT December 1,2004 I I I I I I I t I I I I I I I I I I I c) compoundsmaybesmallquantitiesofkerosenefoundin laboiatory wastewater discharged historically to septic tank leachfields . Largequantities of kerosene are also used in the mill's solvent extraction circuit and are discharged to the tailings cells. ofthesefive(5),onlyone(l),benzene,hasbeenfoundinexcess of its 5 ug/l GWQS (sde Attachment 10, below). For reasons discussed'above, toluene, and naphthalene were added to the Permit as groundwater monitoring parameters' However' because benzene aid xylene are also related to kerosene, and have been detected in groundwater at the facility; these compounds have also been added as GWCL parameters in Table 2 of the Permit. For the time being 1,2,4-trimethylbenzene was omitted as a monitoring parameter. However, should it be necessary it can be added to the i'ermit later under provisions found in Part IV'N'3' Tetrahydrofuran - detectable concentrations of tetrahydrofuran (THF) h"r" b*" found in four (4) wells at the facility, including ,rp graAi.nt well MW-l, and downgradient wells MW-2, MW-3' ura-lrtW-t2 (see Attachment 10, below). Two (2) "f9::: wells have THF concentrations that exceed the State GWQS (46 ryll), including upgradient well MW-l and downgradient well MW-3 (ibid.). ifr. tt"o (2) other downgradient wells, MW-2 and MW-I2' "*rtiuit.a detectable THF concentrations that did not exceed the GWQS. As a part of the chloroform contaminant investigation, DRC staff asked IUC to evaluate possible sources of THF at the facility (ll22l02DRC Request for Additional tnformation, p' 3) In ,"rpon*", IUC claimed that this organic solvent may have been derived from PVC glues and solvents used during construction of the PVC well casings found in several monitoring wells at the facility (l2l2ol02IUC Letter ,p.2). This claim appears consistent with the occurrence of THF in both up and downgradient wells. However, further evaluation is required to determine why three (3) other IUC wells installed at the same time do not exhibit detectable THF concentrations, including lateral gradient well MW-4' and downgradient wells MW-5, and MW-l1' THF is a contaminant of concem, in that one of its major use is as aGrignardreagentinthesynthesisofmotorfuels(National Libraly of MeJicine [NLM] Hazardous Substances Data Bank). Therefore, it may be possible that THF is a trace contaminant in petroleum products such as kerosene, which is used in large quantities ut ttr" white Mesa mill (see Table 3, above). Further, tgF nur unique chemical properties in that it is soluble in both water and hydrocarbons. Be.a,r.e it has a high water solubility, THF may be a very mobile groundwater contaminant' DuringpreparationofthePermit,IUCofferedto:1)continue monit[.ing THF in all the monitoring wells at the facility, 2) include trtr as part of the routine tailings wastewater sampling 18 a) b) i I i II I T It i Ij t i t II J J J J i i Statement of Basis DRAFT December 1,2004 five (5) bis(2- and analysis, 3) submit a work plan for additional study and 4) complete the study and report the results thereof to resolve this issue. Accordingly, a condition has been added to the permit,s compliance schedule in Part I.H.l9. If after review and approval of this report, the Executive Secretary determines that THF is not a result of mill operations, then the permit will be re-opened andmodified to remove it as a groundwater compliance monitoring parameter (Table 2). - IUC has detectedsemi-voc contaminants in tailings cell wastewater, including: ethylhexyl)phalate; diethyl phthalate; dimethylphthalate; di-n- butylphthalate; and phenol (see Attachment 6, 6elow). Four (4) of thesecompounds may be mobile in groundwater environments, based on their estimated I(6 values, including: diethyl phthalate (0.07 LlKg); dimethylphthalate (0. 04 LlKg); di-n-butylphthalate (0. I 6 L/Kg); andphenol (0.016 L/Kg), see Attachment 8, below. However, none of thesesemi-voc contaminants were included as compliance monitoring parameters in the Permit, for the following reasons: Several VOC contaminants have already been proposed as compliance monitoring parameters that have lowei I(a values than the semi-voc parameters in question. Examples of these include, but are not limited to: acetone, chloromethane, dichloromethane, and toluene. consequently, these voc parameters should be detected at the compliance monitoring well before any arrival of the semi-VOC contaminants. Focusing on the voc contaminants will streamline groundwater monitoring efforts and reduce associated sampling and analysis costs for both IUC and the Executive Secretary, The Executive Secretary can add new compliance monitoring parameters at any time, if needed to protect human health and the environment, pursuant to Part fV.N.3 of the permit. semi-vocs Found in. Site Groundwater - only one (l) split sampling event included analysis of semi-voc parameters, May, iqqq. nuring tti. event which was conducted as apart of the chloroform investigation,-only one (1) semi-voc contaminant was detected in the IUC set ofgroundwater samples at the white Mesa facility, including: Bis(2- ethylhexyl)phthalate. Unfortunately, a problem with a laboratory blank forced the DRC to discount all its split sample results for this paiameter. Follow-up sampling for semi-vocs was not undertaken by DRC staff,primarily because the voc contaminants detected are known to generally be much more mobile in groundwater environments. The Executive Secretary will continue with this approach to semi-voC contaminants as compliance monitoring parameters under the permit. - the transformations or decay ofcontaminants that would alter the physical properties or reduce the concentrationof contaminants found in the tailings wastewater is another key consideration in Statement of Basis I I I I t I I I I I I t I I I I I t I r) 2) F. 5. DRAFT December 1,2004 selection of contaminants for gfoundwater monitoring. In cases where a contaminant is transformed to a reaction or decay product, it may be preferable to monitor groundwater quality for the degradation products instead of the parent contaminant. several tuilirrgr wastewater contaminants were examined with respect to their persistence in groundwater environments. Each of these parameters are discussed below: follows: NH3 (asN) GWQS : NH3 GWQS * Atomic Weieht of N Atomic Weight of NH3: 30 mg/l * 14.0067 I U4.0067 + 3 * 1.0079)l: 30 mg/l * 14.0067 I 17.0304 = 24.67 mg/I, round to 25 mgll. Nitrate and Nitrite - both of these compounds are oxidation or degradation p--6".t. "f ui"r"*ia, which is one of the top six (6) reagents added during the milling process (see Table 4, above). As anions, both nitrate and nitrite ut ,.udily mobile in groundwater environments. For these reasons, Nitrate + Nitrite (as N) was added to the list of groundwater compliance monitoring parameters in Table 2 of the Permit. Chloroform Dauehters - chloroform has been found both in the tailings @hment 6) and in shallow groundwater primarily in the area of the chloroform investigation (see Attachment 3) at the site' As a result, the Executive Secretary has added this volatile organic compound iVOCI io the list of required groundwater monitoring parameters in Table ) of the Permit. Undeianaerobic conditions, chloroform is degraded to dichloromethane (or methylene chloride) and then to chloromethane (see pankow and cherry, p. 80). Both of these daughter products have low soil I(a values of 0.10 and 0.06 LlKg,respectively (see Attachment 8). For th"r. ,"urons, all three (3) of these VOCs have been required for groundwater monitoring at the facility after addition to Table 2 of the Permit. Detectability - the ability of common environmental laboratory equipment and t""h""l"gy t" detect andquantiff contaminant concentrations in groundwater is another iiiportant issue to consider when selecting parameters for groundwater compliance monitoring. Executive Secretary review has found that standardized, EPA approved laboratory methods are available to provide minimum detection limits ihat are lower than the GWQS discussed below for each compliance monitoring parameter. 2) - the Executive Secretary has ffiffiffiFfor each of the grorrrrd*ut.r compliance monitoring parameters listed in Table 2 of the permit. The source or reference for each of these contaminant's GWQS is discussed below. Nutrients and Inorqanics A. Ammonia (as N) -the25 ug/lad-hoc GWQS found in Table 2 of the Permit was derived tomTO ug/l EPA final drinking water lifetime health advisory (LHA) for ammonia (NH3)lsee EPA, Summer, 2002,p. 8]. This value was then converted to an equivalent concentration for ammonia as nitrogen (NH3 as N), as 20 B. H. K. i i t J J i i J J II J J i It i J II II i Statement of Basis C. Metals D. DRAFT December 1,2004 Fluoride - the 4.0 mg/l value is a promulgated Gwes under the utah GwepRules found in UAC R3l7-6-2,Table l. - the l0 mg/l GWeS comes directly from the UtahGWQP Rules found in UAC R3I7-6-2,Table l. Arsentq- the 50 ugll Gwes comes from the utah GWep Rules found in uACR3r7-6-2, Table l. However, the EpA drinking water fiiral maximum concentration limit (MCL) has been recently changed to l0 ug/l (see EpA,Summer, 2002,p. 8). At some point in the future, the Executive becretary mayre-open,the Permit and revise this GWeS accordingly, pursuant to part IV.N.1. Thallium - all of these GWeS come rrom th" utah cw@Rules found in uAiR3l7-6-2, Table 1. cobalt and Iron - the ad-hoc GWeS for these two (2) metals, 730 and I 1,000ug/I, respectively, were derived from the tap water concentration limits found inthe EPA Region 3 Superfund Risk Based concenhation (RBC) Table. This EpAreference is available on the Internet at Mansanese - the 800-ug/l ad-hoc Gwes was derived from an ad-hoc drinkingwater LHA provided by EpA Region g (see ll4/00 EpA Region g letter, p. t)Ilnturn, this LHA was based on the most current reference dose (RfD) in the BpaIntegrated Risk Information System (IRIS) database. Molybdenum and Nickel - the ad-hoc GWeS of 40 and 100 ugll, respectively,were derived from EpA final LHA for these metals (see EpA, Eummlr,200i,'p.8). Uraniqrr-r - the 30 ug/l ad-hoc Gwes was derived from a final EpA drinkingwater MCL (see EPA, Surnmer, 2002,p. g). This MCL was re-affirmed bylhe G. united States court of Appeals on February 25,2003 (see District of columbiCircuit, Docket No. 01-1028, etc, p.49). vanadium - an ad-hoc GWeS of 60 ug/l was calculated by DRC staff with theassistance of Mr. Bob Benson, EPA Region 8 drinking *ui.. toxicologist using anEPA RfD for vanadium pentoxide (vzos) ot9 uglkgliay (see Tllglg6rJtahDepartment of Environmental euality tDEe] InformationNeeds Summary, Tablel, Footnote 5). Zinc - the 5,000 ug/1 ad-hoc Gwes comes directly from the Utah GWep Rulesfound in UAC R3l7-6-2, Table 1. However, the final EpA drinking waLr LHAis currently 2,000 ug/l (see EpA, summer,2002,p. 9). consequently, the Ex_e,cutive Secretary at some point may re-open the permit ana aa3usi the zincGWQS accordingly, pursuant to part tV.N.l. Radioloqics L' Gross Alpha - this 15 pCi/l GWQS is directly from the Utah GWep Rules foundin UAC R3t7-6-2, Table l. Statement of Basis VOC Contaminants DRAFT T December 1,2004 total) - the GWQS values M.Acetone - the 0.7 mg/l (700 ug/l) ad hoc GWQS was derived from lifetime health ,drtr"ry calculationiby UtahbWQ staff, with the assistance of Mr' Bob Benson' Bpe negion 8 Drinking wut., Program Toxicologist. For additional details, see the Augist 8,Igg|O1rliq Report (pp. 3-5 and Attachment l)' This 700 ug/l value was based on an orul e*pirure..f.t"n." dose (RfD) from the EPA Integrated Risk Information System (IRIS) database of 0.1 mgfi<flday. This same ad hoc GWQS has been used at another I le.(2) waste disposal facility in Utah' t I I t N. o. P. for all of these .orrtu.-i*ntt **e from the Utah GWQP Rules found in UAC Fi3l7-6-2,Table l. 2-Butanone (MEK). Chloromethane (Methvl Chloride).and Naphthalene - these EPA drinking water LHA for 2-butanone [4 -Jf * 4,00d udll; chloromethane [0.03 mg/l or 30 ug/l]; and naphthalene [0'l *In o. 1 00 ug/ll , see EPA, Summer, 2002 (yry ' 2, 5 , and 6) ' Chloroform -previously the Executive Secretary relied on an EPA drinking water MCL f", t"tuf t it utornlthanes, which includes chloroform and 3 other VOC contaminants, to establish an ad hoc GWQS for chloroform (0.8 mg/l)' However, recently DRi staff became aware of a new and discrete chloroform RfD established in the EPA IRIS database. with the help of EPA Region 8 toxicology staff, an ad hoc drinking water LHA of 0.7 ug/l was established for chlorofolm on the basis of the .o-porird's non-cancer risk (see 5129103 EPA memorandum)' Later this value *ur'upp.ored for use at the IUC White Mesa facility by the Utah DWQ $ee 6112103 DWQ Memorandum)' Dichloromethane (Methylene chloride) - this ad hoc GWQS was derived from a E*l EPA dtirki"g water MCL (see EPA, Summer, 2002,p'3)' Tetrahydrofuran - the 0.046 mgl @6 ug/l) ad hoc GWQS for tetrahydrofuran (THfibrs"d;n an ad hoc EFA Region 8 drinking water LHA (see 8124199 iee ifegion 8 memorandum). [n tum, the EPA ad hoc LHA was based on a frovisioial oral cancer slop factor of 7.68-3 mglkflday From calculations provided by EPA Region d, thr." values of cancer risk and corresponding THF concentrations were Ietermined, as summarized in Table 6, below' After review of these data, the Executive Secretary has determined that the mid-range value, 46 ug/l, is appropriate as an ad hoc THF GWQS for the IUC White Mesa site, based on the following findings:1) ffi;l['*:[:X"Tlffi:".'i'i,o,1,h*n"u.,* I qualitY), and Water - review of nearby groundwater I I t I a. R. I I 2)ko ur. t u. rtro*, that no existing gtoundwater supply wells or springs are currently found downgradient of the IUC facility on white Mesa that 22 exclusively use the shallow aquifer for drinking water' i II i II i i i t It J II i II I T J IIj II i Statement of Basis DRAFT December 1,2004 Table 6. Summary of Tetrahydrofuran Cancer Risk And GW Concentrations Cancer Risk THF Concentration (r) (me/l)(ue/l) l:10,000 0.46 ms,/l 460 l:100.000 0.046 46 1:1.000.000 0.0046 4.6 Frcm 8/24199 EPA Region 8 memorandum by Robert Benson. Future Monitorine Wells (Permit Table 2 and Part I.H.1) - recent water table contour maps of the shallow aquifer have identified a significant westerly component to groundwater flow at the White Mesa facility, see Attachment l, below. This change ingroundwater flow directions appears to be the result of wildlife pond seepage and groundwater mounding discussed above. As a consequence, new grounawater monitoring wells are necessary at the IUC facility, particularly along the western margin of the tailings cells. New wells are also needed for Discharge Minimization Technology(DMT) purposes that provide discrete monitoring of each tailings cell, as discussed below. During meetings in August, 2003 and February, 2}04,IUC proposed the installation of these new groundwater monitoring wells near the tailingi cells, as summarized in Table 7. Later,IUC submitted a map to confirm the locations of these new wells, see Attachment I l, below: able o IUC Moni Well Locations Well ID Approximate Location MW-23 Near southwest corner of Tailines Cell 3 MW-24 Near southwest corner of Tailinss Cell I MW-25 Near southeast corner of Tailines Cell 3 MW-26 Near northeast corner of Tailings Cell2 (existing chloroform investisation well TW4- I 5) MW-27 Near northeast corner of Tailines Cell 1 MW-28 Near mid-point of south dike at Tailinss Cell 1 MW-29, MW- 30. and MW-31 Spaced approximately equidistant on south dike of Tailings Cell2 MW-32 Near southeast corner of Tailings Cell2 (existing chloroform investigation well TW4- I 7) These general locations were found acceptable. If after review of the hydrogeologic report required by Part I.H.2 of the Permit, the Executive Secretary determines additional information is needed, IUC will be asked to provide more information. The short 60-day compliance schedule for IUC to install the new wells after Executive Secretary upp.ouuf of the plan was set in order to expedite both the collection of groundwater quality information from these new wells, and preparation and submittal of the new well Background Groundwater Quality Report (part I.H.4). 7. Statement of Basis DRAFT December 1,2004 Revised Hydroeeoloeic Report (Part I.H.2) - after installation of the new monitoring @i, it *ill be important to evaluate the new hydrogeologic information collected, and consider it in context with existing information collected to date at the facility. [n order to ensure evaluation is done and easily tracked by both IUC and DRC, the Executive Secretary added this requirement to Part I.H.2. At a minimum, the following types of hydrogeologic information will be included in the Revised Hydrogeologic RePort: Monitoring Well As-Built Information - including geologic logs, well completion diagrams, ind aquifer hydraulic analysis as required by Part I.F.5 of the Permit, Revised structural contour Map - of the geologic contact between the Brushy Basin Member of the Morrison Formation, and the overlying Burro Canyon Formation. Aquifer Saturated Thickness Map - including a contour map to illustrate the local distribution of the thickness of the perched aquifer. Water Table Contour Map - based on groundwater elevation measurements of all wells and piezometers at the site to illustrate local groundwater flow directions. Historic Aquifer Permeability Data - aquifer permeability data collected from the new monitoring wells needs to be evaluated in context with existing slug and./or aquifer pump test analysis to determine if any preferred groundwater flow pathways exist. Multi-well Aquifer Test Results - long-term any new multi-well aquifer testing done to determine local hydraulic properties, including permeability, needs to be included. One purpose of this testing would include determination if any preferred direciions of groundwater flow exist at the facility, i.e', aquifer permeability heterogeneity and anisotropy. - Aquifer permeability Distribution Map - based on all reliable and representative aquifer permeability available to date, IUC will provide a contour map to illustrate the distribution of permeability of the perched aquifer at the site. If after review of the Revised Hydrogeologic Report it is determined that additional information is needed, the Executive Secretary will ask IUC to provide it' added to the Permit to confirm that only 11e.(2) byproduct material, including various wastes listed by NRC, may be disposed of in the Mill's Mi Au Corr.t*.ti,on Gurtr t-p.t und Z) -information providedby IUC shows that Tailings Cells t,2., u"al *"r" .onrt*"t"d more than 20 years ago, as summarized in Table 8, below: I I I I I I t A. B. C. D. E. F. G. T I I 8. 9. I Il tailings cells. 24 i i t II i II t I i i t i I 1 I II i t II I Statement of Basis DRAFT December 1,2004 Tabl After review of the existing design and construction and consultation with the DWe, theExecutive Secretary has determined that the Discharge Minimization Technology 1Dfraf)required under the GWQP Rules [uAC R3r7-6-6.4(cX3)] for IUC disposal cJls l, 2, and 3 that pre-dated the 1989 GWQP Rules will be defined by the currint or existing disposal cell construction, with a few modifications. This approach is reasonable, practical, and acceptable for the following reasons: Existine conditions - Tailings Cells l, 2, and,3 have been in existence in their current state for more than 20 years. Over the course of this time, a significant amount of tailings have been disposed in Cells 2 and,3. Current Staee in Desiqn Life - Tailings Cell2 has nearly reached its maximum waste height and capacity, in that temporary soil cover has been advanced over 99.8% of the disposal cell. As a result, the remaining disposal capacity in Cell 2 is only about 5,000 dry tons out of 2,35 2,000 dry tons ofiotal design capacity (personal communication Harold Roberts, IUC) . At Tailings cell 3, about el% of the total design capacity has already been used (1,g25,000 o:ut of 2,7 25, 000 dry tons total), and temporary soil cover has been advanced over about 40%o of thecell (ibid.). Retrofit Construction Impractical - due to the ddvanced age of the disposal Cells 2 and 3 and their near-full capacity, little can be done to retrofit, re-construct, or modify the under liner systems. The improvements required under DMT for Tailings Cells 1,2 and3 will focus on changes in monitoring requirements, and on improvements to facility closure, if needed. The goal for these changes is to ensure that potential wastewater losses are minimized and local groundwater quality is protected. These changes include: D. Improved Groundwater Monitorins - improvements to the existing monitoring well network are needed to meet the following performance goals: Early Detection - the ability to detect a release as early as practicable is important, and is accomplished by locating wells immediately adjacent to and downgradient of each disposal cell. To satisfy this requirement the Executive Secretary has required three new DMT monitoring wells (MW- 24,}dw-27, and MW-28) be installed immediately adjacent to cell 1, see Part I.H.1. Discrete Monitorine - the ability to individually monitor each disposal cell at the facility is also important to allow the Executive Secretary to pin point the source of any groundwater contamination that might be detected. The DMT monitoring wells required for cell I in part I.H.l will help meet of A. B. C. l) 2) e 6. summary ot l'arlrngs Cell Completion Dates Tailings Cell Completion Date Reference I June 29, 1981 5/28/99AJC Groundwater Information Report, p. A-11 2 Mav 3. 1980 3 September 15,1982 3/83 Energy Fuels Nuclear Construction Report. p. l-2 4A November 30, 1989 VOqIfC Construction Report, p. 1 Statement of Basis DRAFT December 1,2004 this requirement. Also, IUC will be required to install three (3) additional monitoing wells between Cell 2 and3 to allow discrete monitoring of Cell2 (MW-29, MW-30, and MW-31). - changes to disposal efforts to minimize potential seepage losses, and thereby improve protection of local groundwater quality are also important' Related requiremints for monitoring are also added to confirm that these changes are in place and are actively being used by IUC. Examples of some of these changes include: - imposed in Part I.D.3 for Aitings cells and Roberts Pond to require that lUC continue to ensure that impounded wastes and wastewaters are held and maintained over a flexible membrane liner (FML)' E. I I I I I I T I t I I I I I I 1) 2) 3) Slimes Drain Maximum Allowable Head - required for Tailings cells 2 arld3 in purt fO:O) to ensure that IUC provides constant pumping efforts to minimize the accumulation of leachates over the FML, and thereby minimize potential FML leakage to the foundation and groundwater. This requirement ias immediately imposed in the Permit for Cell2, because IUC is already actively dewatering ihat cell. Imposition at Cell 3 was delayed by the Executive Secretary in response to IUC argUments that premature slimes drain pumping poses a rist< that ihe layer will plug with sulfate salts during tailings "e11 opeiation, and not be available for slimes de-watering when IUC is ready to advance a cover over the tailings cell. Such untimely loss of the slimes drain layer would gfeatly complicate and delay cover construction, and in tum increase the overall potential for leachates to be released from the final waste embankment. Detaiis as to an appropriate average wastewater head in the slimes drain layer at both cells 2 and 3 are to be proposed by IUC and approved by the Executive secretary in development of a DMT Monitoring Plan required by Part I.H. 1 3 of the Permit. Feedstock Storaee - in order to constrain and minimize potential generation of *"tu*i*ted stormwater or leachates the Permit requires IUC to continue it existing practice of [see Part I.D.3(d)]: 1) limiting open air storage of feedstoci materials to the historical storage area found along the eastem margin of the mill site (as defined by the survey coordinates found in Permit Tabl-e 5), and 2) maintaining water-tight containerized storage of feedstock material found anylvhere else at the IUC facility' 4) Mill Site Reaeent Storaee - is of potential concern for groundwater quality in the event that reagent storage tank leaks or spills could release contaminants to site soils or gro-undwater. In an effort to prevent this possible problem, and provide prope*pill prevention and control, Part I.D.3(e) requires IUC to iemonstrate thaiit has adequate provisions for spill response, cleanup, and reporting for reagent storage facilities, and to include these in the Stormwater Best Manag.-"rrt Practices Plan. Content of this plan is stipulated in Part I.D.8, and submittal and approval of the plan required under Part I.H.17. At new facilities, the performance goal for secondary containment should include prevention of spills from contacting the ground surface' During 26 i I I I i i I I I i i I i I i I I i I Statement of Basis DRAFT December 1,2004 discussion with IUC, the company responded that this was impractical in that the existing reagent storage facilities had been in existence for decades. Further, IUC contended that: 1) secondary containment had been designed and constructed at each of the existing reagent storage facilities, albeit it earthen lined, 2) any soils affected by spills could be easily excavated and disposed in the tailings cells should a spill occur, 3) after removal of the soils affected by major spills, new construction could be completed to replace and restore the secondary containment; which at that time could meet the new performance criteria for prevention of ground contact, and 4) any required improvements for chemical reagent storage should focus on changes to operational and/or spill response measures, and not on re-design or re- construction of these facilities. Because the IUC facility is a pre-existing operation under the Ground Water Quality Protection Regulations, DRC staff agreed with these arguments, and wrote the requirements of part I.D.3(e) accordingly. However, should any of the existing reagent storage facilities be re-built, provisions were added to the Permit to require the higher standard at re-construction, that being secondary containment that would prevent contact of any spill with the ground surface. Evaluation of Tailines cell cover System Desim -rover system design and construction needs to be evaluated in order to ensure that infiltration into the tailings waste is minimized and groundwater qualityprotected during the post- closure period. To this end, Part I.H.ll of the Permit requires IUC to submit an Infiltration and Contaminant Transport Modeling report for Executive Secretary review and approval. After review of this report, the Executive Secretary will determine if any changes are need in the proposed cover system. Minimum cover system performance criteria are stipulated in part I.D.6 of the permit. 10. Existing Tailines Cell Desisn / Construction Findines -during review of the existing tailings cell design and construction the Executive Secretary found that construction documentation for Tailings Cell 1 is limited to one (l) as-built report dated February, 1982 by D'Appolonia Consulting Engineers (p. 3-1). In this report the as-built information is limited to only a topographic map of the Cell 1 floor prior to FML installation (ibid., Fig. l2). Authors of the report state that they were involved in construction of Cell 2, and that Tailings Cell I construction was done by the previous White Mesa owner, Energy Fuels Nuclear (EFN). No other Cell I as-built information is available, nor is there any documentation of any Cell I construction quality assurance / quality control. DRC field inspections have confirmed the existence of an earthen dike at the south margin of Cell 1 and a FML liner inside this cell. Without any other information, the Executive Secretary has assumed that the Cell 1 construction largely followed the cell's original design found in a June, 1979 D'Appolonia Engineers Report. From IUC plan maps the Executive Secretary estimated the Cell 1 footprint area to be about 57 acres. As for Tailings Cells 2 and 3, as-built reports were found and reviewed by DRC staff; findings from which are found in a June 27,2000 DRC Memorandum. These reviews resulted in a summary description of the liner technology for these two (2) disposal cells, as outlined in Part I.D.l(b) and (c) of the Permit. From IUC plan maps the Executive Secretary estimated the footprint area to be about 68 and 55 acres for Cells 2 and3, respectively. Statement of Basis DRAFT December 1,2004 From this review it appears that the design and construction of all three (3) existing tailings cells consists of a single PVC FML liner and a limited leak detection system undeithe primary liner comprised of a single pipe at the toe of the southern dike within a permeable sand layer that extends across the cell floor. While outdated, this construction upp"urr to have been common technology for the time (1980-1982). Since then, FML tec-hnology has greatly advanced both in materials used, designs produced, construction methodslracticed, and quality assurance / quality control measures applied. Modern designs include multiplaFMls (e.g., primary, secondary, tertiary, etc), and a leachate removal system over and multiple leak detection layers under the primary FML' Such advanced designs provide effective leachate head control at the primary FML, thereby minimizing lpakage rates and providing sensitive leak detection; and efficient leakage collection and removal systems. [n cases where facilities have deployed modem waste containment and leak deiection / control technology, the Executive Secretary has allowed the leak detection system to be the primary means of compliance determination for the facility. However, this is not case for the existing tailings cells at IUC. Therefore, for purposes of defining the DMT standard for IUC, the Executive Secretary is left with only one option, that of improving detection of potential tailings cell leakage by installation of discrete monitoring wells-. To this end,IUC has agreed to install eight (8) new monitoring wells immediately adjacent to the tailings cells, as follows (see Attachment 11, below): A. Tailings Cell I - wells MW-24, NNV'27, and MW-28, B. Tailings Cell 2 -wells MW-29, MW-30, and MW-31, and C. Tailings Cell 3 - wells MW-23 and MW-25. @rTailingsCell4AisfoundintwoUmetcoMineralsCorporation @Jreafter [metco; reports dated August, 1988 and April 10, 1989. Cell 4,{ construction was completed on or about November 30, 1989, see Table 8, above. Later, IUC completed an as-built report and submitted it for Executive Secretary review (see 8/00 IUC Tailings Cell44 Construction Report). Review of the engineering design and as- built reporti , shows that an improvement was made to the leak detection system in Cell 44, coirpared to the older cells, in that a secondary FML was installed immediately underneath the leak detection piping system. Unfortunately, this secondary FML was very limited in horizontal extent, in that it was only 2-feet wider than the graded trench for each leak detection pipe (8/88 Umetco Report, Sheet C4-3). As a result, very large areas exist between the leak detection pipes where the primary FML has no underlying membrane to divert leakage to the detection pipe. Consequently, 98% of the Cell 4A floor area does not have a-secondary FML present to divert leakage to the leak detection collection pipes (6127 100 DRC memorandum, p. I 0). As a result, the existing design and construction of this disposal cell could allow a significant volume of leakage to escape undetected and possibly contaminate underlying groundwater re sources. However, unlike Cells l, 2, and 3, Cell 4A has a 12-inch clay liner under the primary FML. Therefore, leakage from the primary FML would necessarily have to penetrate and escape this clay layer before it could infiltrate the cell foundation and possibly contaminate underlying groundwater. While this clay liner represents a significant improvement in facility tuitirrg. cell design, DRC review of the as-built report, referenced I li ll ti lr Ii Ii 11. .14 ll li ll I i28 li Ir lrlt t i I I I I i I I I I Jll ;l Statement of Basis DRAFT December 1,2004 above, found very little clay liner conskuction quality assurance I quality control information to substantiate any in-place or field permeability for this clay layer. As a result, the DRC is unable to quantift the rate of any possible leakage from this clay layer, or confirm the degree of control this layer may have had on said leichate. Despite this lack of information, Cell 4,A' has never been used for tailings disposal, but instead was used only for storage and evaporation of vanadium process solutions (5l2gl1l IUC Cell4A Leak Detection Report, p. 1). ruC has advised DRC staff that no taiiings waste or wastewater have been deposited in Cell4,A' since the early 1990's. This lack of waste disposal, and exposure of the FML to the elements has caused Cell4A to fall into disrepair over the years. DRC staff site visits between 1995 and 2003 have observed failure of several FML panels on the interior sideslope; thereby exposing large areas of the sideslope subsoils. IUC acknowledges this damage and the general airrepuir of Cell 4/^. In addition, the existing NRC License requires IUC to submit verbal and written reports when flow rates from the leak detection system exceed I gallon per minute (gpm) iNnC 9123102 License, Condition 11.3(D)1. tn a May 29,2001letter, IUC notified the NRC that LDS flows at Tailings Cell4A had exceeded the 1.0 gpm rate atCell4A. Based on these findings, it appears that the FML has failed to control the process fluids maintained across the floor of Cell 4A, thereby causing reliance on the clay sub-liner to prevent contact with the underlying sub-soils. Since that time IUC has begun the process of removing the materials once stored there, in preparation of re-lining the cell prior to re- use. The raffinates and salts once stored in Cell 4Amay have similar chemical characteristics as the uranium raffinate in the Mill, in that the vanadium raffinate is derived from the outfall of the uranium extraction circuit in the IUC milling process (5/25/gg IUC Groundwater Information Report, p.A-7 and Figure B-2). Consequently, these fluids may contain significant concentrations of many contaminants of concem, including: low pH fluids, heavy metals, uranium, high sulfates and TDS levels, and organic contaminants. Considering the FML damage acknowledged by IUC, the general state of disrepair discussed above, and the lack of tailings solids disposed to date; major improvements in the design and construction of Cell 4A are warranted prior to re-use of thocell. For this reason, the existing Cell 44 design and construction were not approved in Part I.D of the Permit. IUC has also agreed and Part I.H.14 of the Permit has been crafted to require submiffal of a Cell4A contaminant removal schedule for Executive Secretary approval, which would include periodic progress reports of said contaminant removal. Requirements are also provided for IUC to complete removal of all fluids and salts stored there, the FML liner and LDS layer, and any contaminated underlying clay or sub-soils, pursuant to Part I.H.14. Furthermore, if IUC desires to reconstruct and re-line Cell44, the Permit also requires IUC to submit new engineering design and specifications for Cell 44 that meet BAT design and construction requirements, and secure prior approval, pursuant to Part I.H.l5. Part - this pond was originally installed as a part of the initial Mill constru"tion approrr"d by the NRi, and is located in the western portion of the mill site a short distance east of Cell 1. This pond was designed as an emergency catchment basin for major tank failure or process upset from the mill. In May,2002IUC made the decision to clean out the exisiing pond and Statement of Basis DRAFT December 1,2004 replace the former Hypalon liner with a new High Density Polyethylene (HDPE) rnembrane. To date, no IUC engineering design or as-built drawings have been provided for re-construction of the Roberts Pond, but IUC has committed to provide this information in the near future. A brief description of the FML retrofit construction was provided in a February LI,}OO4IUC email, details of which are outlined below: A. B. C. The Roberts Pond is relatively small, less than 0.4 acres in srze. After 25 years of gervice the Hypalon liner in the Roberts Pond was removed and replaced with a single membrane, 60 mil HDPE liner' After removal of the former Hypalon FML, IUC conducted radiological surveys with.both field instruments and uranium soil sampling and analysis to determine soil areas with concentrations that were above "background". Contaminated soils were excavated and moved to the ore storage pad for re- processing in the mill. Foundation preparation included gleaning the sub-grade to remove oversize rock, rolling the sub-grade with a smooth drum roller, raking pond sideslopes to remove or.rrir" rock oi other material, installation of a geotextile material over the entire footprint as a protective layer under the FML' Construction quality assurance / quality control (QA/QC) measures performed included three (3) destructive tests on FML seams (l per 500 linear feet), followed by air pressure tests and vacuum box tests where needed. lr ll li ll li li Il I lr I I T I I l) 2) 3) D. E. F. 13. Without having reviewed the IUC As-Built report, the Executive Secretary cannot approve either the design or the construction of the re-built pond. However, the Executive Secretary hai decided to accept the pond as it is, regulate it under the Permit, including imposition of DMT monitoring requirements, based on the following findings: The Roberts Pond is small in size, about 0.4 acres, compared to the tailings cells, and The Roberts Pond is used to store intermittent wastewater flows, and therefore may not be a constant head source At the time mill site decommissioning, detailed radiologic surveys will be conducted of the entire atea, andcontaminated soils removed and placed for disposal in the tailings cells. All of these activities are regulated by the Executive Secretary under the Radioactive Materials License Therefore, part I.H.l8 has been added to the Permit's compliance schedule to require submittal of an As-Built report to document the recent design and re-construction. After review of this report, the Executive Secretary will determine if additional measures are necessary to protect public health and the environment. Such changes, if needed, would be implernented as a-part of the Reclamation Plan required by the License' Existine Facilitv DMT Operations Standards (Part I.D.3) - in lieu of major engineering i,severa1newoperationalrequirementswereimposedby the iermit to minimize the fotential for release of contaminants to the groundwater from the tailings cells and facilities at the mill site, including: A. Slimes Drain Maximum Head: Cells 2 and 3 - this performance criteria was added .o ur io require IUC to install, operate, and maintain automated pump 30 It Ir Ir Irrl i I i J I J I J J Ij i 1ij Statement of Basis DRAFT December 1,2004 control systems inside the slimes drain access pipe for both Tailings Cells 2 and 3. The intent of this requirement is to ensure that the average wastewater head in this layer is maintained as low as reasonably achievable, and thereby minimize leakage from the primary FML. Determination of the wastewater level that meets this criteria will be made by IUC and approved by the Executive Secretary later asapart of the DMT Monitoring Plan; pursuant to Part I.H.13. Similar head control requirements have been stipulated by the Executive Secretary for other facilities. - this requirementIE applies to all tailings cells at the IUC facility. The utah water eualityRegulations require a minimum 3-foot freeboard for wastewater impoundments that treat 50,000 gallons or more per day [uAC R3l3-10.3(c;1. ru^c has reported that the tailings disposal system is expected to average 335 gavmin, which equates to a daily rate of 482,400 gal/day (5l28l99IUC Groundwater Information Report, p. A-9). Assuming that this rate is evenly dishibuted between all Cells l, 2, and 3, this flow would equate to a daily rate of 160,g00 gallday/cell, which iswell above the 50,000 gal/day limit established by state rule. As a result, the 3-foot minimum freeboard limit applies to the IUC tailings cells, and such a requirement was stipulated in Partl.D.2 of the Permit. The Executive Secretary recognizes that the NRC License already requires IUC to make an annual determination of the minimum freeboard required at the tailings cells to control the Potential Maximum Precipitation (PMP). This annual evaluation includes calculations to determine the necessary freeboard required in the tailings cells to control any upslope run-off that could impinge on the tailings ur"a, andwould have to be maintained behind the tailings dikes. Consequently, the State,s 3-foot freeboard requirement imposed in Part I.D.2 is designed to compliment and not replace the existing License freeboard requirement. C. IUC design and as-built reports it was clerwas clear that Tailings Cells I and2 share a 3 - during review of the common dike, and Cells 2 and 3 share a dike in common. The construction originally approved by the NRC and the IUC design and as-built reports provided show different elevations for the top of the FML liner at both the north and south sides of each of these intervening dikes. consequently, it appears possible for waste to be disposed at an elevation where the FML does noi exist. The originalNRC approval stipulated that tailings material was to be deposited only to tf,e topof the FML (personal communication, Mr. Harold Roberts, l0/15/04). To continue this restriction and prevent unacceptable tailings placement above theFML, an additional performance criteria was added to the bermit to require that the final tailings waste elevation, before cover system emplacement, always be below the maximum FML liner elevation in each disposai cell. Although Cell I is cutrently used for process wastewater storage and not for tailings solids disposal, this requirement would still apply at Cell I at some future time when undeithe current NRC approved reclamation plan requires Cell I be used for disposal of demolition debris from the mill and decommissioning wastes from the mill site. I.D - as discussed above, the Executive Secretary has determined it necessary and IUC has agreed to insiall discrete groundwater monitoring wells around each tailings cell as a means toyti{ythe DMT requirements of the cwep Rures [uAC R317-6-6.4(cX3)]. DMT performance standards stipulated in Part I.D.3(a)(2) of the p..-it i"q-ui..t Statement of Basis DRAFT December 1,2004 IUC to operate and maintain the tailings cells in such a manner as to prevent gfoundwater conditions in any nearby wells from exceeding the Groundwater -ompliance Limits established in Table 2 of the Permit Roberts pond lPart I.D.3(_c)l - as described above, little documentation has been pr""rd"d by ruc;garding the design and construction of this mill site wastewatei catchment pot a. This pond, is about 0-40 acres in size, and found approximately 180 feei west of the mill building and about 200 feet east of the ntrtneast corner of Tailings Cell 1 (see 6122101 ruC Response, Attachment K, Site Topographic Map, Revised 6/01). This wastewater pond apparently receives periodic nioi ataittage and other wastewaters from the mill, is frequently empty, ind was re-lined with a new FML in May, 2002' In order to minimize any seepage release from this wastewater pond, the Executive Secretary has determined that an appropriate DMT operations standard would be two-fold: A stipulation that IUC maintain a minimal wastewater head in this pond basei on a 2-foot freeboard and a l-foot additional operating limit. Since the top of FML in this pond is about 5,626 feet above mean sea level (ft amsl), the maximum operating solution limit in the Roberts Pond was set in the Permit at 5,624 ft amsl. Because the lowest point on the FML is found at 5,618 ft amsl, this would allow the pond to be operated with a 5- foot maximum head, and At the time of mill site closure IUC will excavate and remove the liner, berms, and all contaminated subsoils in compliance with an approved final Reclamation Plan under the Radioactive Materials License (hereinafter Reclamation Plan). Since the Executive Secretary now has Agreement State status for uranium mills, the DRC will closely examine decommissioning of this pond at the appropriate time' I li li li lr li ll i l T It I i i 1) 2) E. F. I I i Feedstock storase Area [Part I.D.3(d) and Table 5l - for new facilities, the @ apotential discharging facilitymeet BAT requirements. At otier permitted facilities, BAT for waste storage areas has been defined as storage or". u hardened concrete or asphalt surface. For existing facilities that preda:ted the GWQP Rules, less stringent design requirements, called DMT 'standards, are imposed [see UAC R3l7-6-6.4(C)]. For the IUC facility, the Executive Secretary has decided to define DMT for the feedstock storage area by restricting the locaiions where this activity can be done, and by requiring that certain feidstock materials be maintained in watertight containers, as described below. 1) Restricted Area for Open Air Feedstock Storaee -historically feedstock' materiuls fo. th. mill have been stored under open-air conditions in an area found along the eastem margin of the mill site. In order to minimize the potential foigroundwater and surface water pollution at the facility, the Executive Secretary has decided to restrict feedstock storage to the existing area, thereby constraining the size and location of these activities in the future. The Executive Secretary determined that this approach to DMT is appropriate, not only because the practice has a historical precedencg but also because IUC has a commitment under the 32 2) ij t I J i I J i J I I J J J Jj J I Statement of Basis DRAFT December I,2004 Radioactive Materials License to decommission and decontaminate this area at the time of closure, in accordance with a July 7,2000ILJC Reclamation Plan. During preparation of the permit, IUC staff explained that this reclamation plan includes radiologic soil surveys of uranium to determine the depth to which excavation would be conducted, and contaminated soils removed and disposed of in the tailings cells. Although DRC staff has yet to review and evaluate the content the IUC Reclamation Plan, we anticipate this would be done as a part of the next License renewal, scheduled for sometime on or near March 3r,2007 . State plane coordinates for the Feedstock Storage Area are defined in Table 5 of the Permit, as a means to constrain where open-air storage can be done. These coordinates were initially estimated by DRC staff from a June, 2001 IUC topographic map (ibid.), and later refined by IUC in a February 19,2004 email. Designation of only one (1) open-air feedstock storage area will also facilitate IUC and DRC compliance inspections by allowing ready identification of feedstocks stored at the mill site. containerized Storaee for Feedstock - during permit preparation it was agreed that if IUC chose to store feedstock materials anywhere else at the facility, other than the feedstock storage area defined in permit Table 5, that this storage would be conducted only in closed, watertight containers. This more stringent requirement is appropriate in order to protect these other areas from contamination by contact stormwater runoff or feedstock leachates that might be generated by open-air storage. Alternate Feedstock Storaee - IUC will be required to obtain an amendment to its Radioactive Materials License before it will be authorized to receive and process any new alternate feed materials. This allows the Executive Secretary prior opportunity to review each license amendment application and determine if any special storage precautions are needed to protect groundwater quality, public health and the environment. significant quantities of chemical reagents are stored on the mill site for use in the uranium milling process. In order to minimize the potential for discharge to native soils and groundwater, a DMT performance standard was added to this section of the Permit to require IUC to continue to maintain secondary containment around exiting storage areas and to require that any new or replacement storage facilities meet current BAT standards. Resolution of this requirement should be provided by IUC after submittal of the DMT Monitoring Plan required by Part I.H.13. leT .4) - this section has been added to the Permit to ensure that all new construction, modification, or operation of waste or wastewater disposal, treatment, or storage facilities requires submittal of engineering plans and specifications and prior Executive Secretary review and approval. In these plans and specifications the Permittee is required to demonstrate how the Best Available Technology (BAT) requirements of the GWQP Rules have been 15. Statement of Basis DRAFT December 1,2004 met. After Executive Secretary approval a Construction Permit may be issued, and the Ground Water Discharge Permit modified. Definition of I le.(2) Waste (Part I.D.5) - this definition was added to the Permit for p"rpor"r of .turity, as it regards prohibited discharges defined in Part I.C.l(c). The -Executive Secretary has determined that constraining the types of contaminants authorized for disposal is consistent with discharge minimization and groundwater quality protection. Regulatory definition of l1e.(2) waste is found in Section I le.(2) of tfre U.S. Atomic Energy'Act, 1954, as amended, and includes "the tailings or wastes produced by the extraction or concentration of uranium or thoriumfrom any ore 'processed primarily for its source material contenf'. In addition to mill tailings solids and wastewaters, the NRC considers other process related wastes to also be 11e.(2) by- product material, including (see 317103 NRC letter): A. Solid waste from facility office buildings, C. Spent chemicals used in ongoing process operations, including laboratory chemicals used for ore assay, Virgin chemicals intended for use at the facility, but not consumed in process operations, including laboratory chemicals intended for use in ore assay, Non-uranium bearing structural or other debris found in altemate feedstock materials accepted for on-site processing. Contaminated groundwater from the on-going chloroform groundwater corrective action project at the facility. This wastewater has been deemed as 1le.(2) waste in thatlt originated from on-site disposal of spent laboratory chemicals used for ore assay. post-Closure Performance Requirements (Part I.D.6) - currently a Reclamation Plan has b*" ,ppr"*d by th" NRC under the existing License. Soon the NRC License will be converted to a State License as a part of the Agreement State transfer process. At the time of the next License renewal, scheduled for sometime around March, 2007, DRC staff will re-examine the Reclamation Plan for content and adequacy. New requirements were added to the Permit at this time to ensure that the final reclamation design provided adequate performance criteria to protect local groundwater quality. This is appropriate, as discussed above, in that the cover system design and construction is the only means available to the Executive Secretary to improve the existing facility and protect underlying groundwater resources, if determined necessary. These new performance criteria *itt utro guide the infiltration and contaminant transport modeling to be done shortly by IUC in response to requirements found in Part I.H.l1. To this end, three (3) requirements were added to ensure that the cover system for each tailings cell will be designed and constructed to: Minimize the infiltration of water into radon barrier and underlying tailings waste, prevent the accumulation of leachates within the tailings that might create a bathtub effect and thereby spill over the maximum elevation of the FML inside any disposal cell; thereby causing a release of contaminants to the environment, and protect groundwater quality at the compliance monitoring wells by ensuring that contaminant concentrations there do not exceed their respective GWQS or GWCL defined in Part I.C.l and Table2. B. ll li D. E. 16. lr ll I lr i I iI I A. B. 34 C. the A. t i I t t t i t i t t t i t t I I i I Statement of Basis DRAFT December 1,2004 To provide consistency with the performance criteria stipulated by the Executive Secretary at other 11e.(2) disposal operations, a200-year minimum performance period was required for all three (3) of these criteria. - Part I.D.7 has been added to Permit to provide the Executive Secretary an opportunity to ensure that: Ihe post-closure performance requirements for the tailings cell cover system in Part I.D.6 is fully and adequately integrated into the Reclamation Plan. Because DRC evaluation of this Reclamation Plan will be done at the time of the next License renewal, scheduled on or around March, 2007 part I.H.l I has been added to the Permit to require that IUC complete an infiltration and contaminant tranSport model of the final tailings cell cover system to demonstrate the long- term ability of the cover to protect nearby groundwater quality. As a part ofthis cover system performance modeling required by part I.H.l l, the Executive secretary will determine if changes to cover system are needed to ensure compliance with the Part I.D.6 performance criteria. All other facility demolition and decommissioning activities outlined in the Reclamation Plan will be done in a manner adequate to protect local groundwater quality. Issues or concerns to be considered and resolved include, but are not limited to: 1) Identification, isolation, and authorized disposal of any un-used chemical reagents held in storage at the mill site at the time of closure. 2) Demolition, excavation, removal, and authorized disposal of a[ contaminated man-made structures, including, but not limited to: buildings, pipes, power lines, tanks, access roads, drain fields, leach fields, fly-ash disposal ponds, feedstock storage areas, mill site wastewater storage ponds, solid waste disposal landfills, and all related appurtenances. 3) Excavation, removal, and authorized disposal of all contaminated soils found anywhere outside of the tailings cells at the facility. Through this process the Executive Secretary aims to ensure that DMT has been adequately established for both the final tailings cell cover system and reclamation of the facility. and and I.H.lil - one aspect ofDMT is preventing and controlling contaminated stormwater and chemical spills frommill site activities. [n July, 2001 ruC provided the DRC a draft copy of a July 17, 2001 Spill Management Plan. Said plan included a section on stormwater management. During a meeting in February,2004IUC explained that they had submitted this plan for NRC approval. IUC also submitted a copy of the plan to DRC on July 17, 2001 and laterprovided a second coPy, which contained additional minor revisions on April 26,2004. Subsequent DRC research found that the July 17,2001 draft plan had not yet been approved by the NRC. Currently, DRC staff are in review of this plan and will provide comments to IUC shortly. With respect to this issue, IUC and DRC reached the following agreements: A. IUC is an existing facility under the GWQP Rules. Therefore, the existing stormwater management system and chemical I rcagent storage facilities would be accepted "as is" under the permit. Statement of Basis DRAFT December 1,2004 In the future, any construction of new reagent storage facilities or major re- construction of existing facilities will meet current BAT design and operation standards" Re-construction of reagent storage facilities may be required by the DRC after a major spill or catastrophic failure of existing storage facilities, pursuant to the Permit re-opener provisions in Part IV.N.3. D. IUC will revise both plans submitted to take into account and resolve any Executive Secretary comments, and re-submit a final Stormwater Management and Spill Control Plan for approval. The final plan will establish acceptable operational, maintenance, monitoring, and reporting requirements for stormwater management and spill prevention and control. The final plan will also provide speciic actions to prevent, respond to, control, and remediate spills of chemical reagents at the mill site. To this end part I.D.8 was added to the Permit to require IUC to conduct its activities in compliance with an approved Stormwater Management and Spill Control Plan. Part t.ff.iZ was added to require IUC to submit a final version of this plan for Executive Secretary approval. I.E.1) - this section prescribes the -""rt"""g r"q"""*ents for groundwater monitoring wells at the facility, including upgradienq downgradient, and lateral gradient wells. Some of the specific requirements are described below: -1'l- routine groundwater q""ttty *""rt"""g is commonly done on a quarterly basis (4-times/year). Iio*"r"., the Executive Secretary may allow a reduced frequency of routine groundwater sampling if site specific groundwater conditions warrant [see UAC F.f tZ-O-0.t6(AXt)1. For certain sites where groundwater velocities have been found as low as one to two feet per year, the Executive Secretary has approved a semi-arurual sampling frequency (2-times/year) in order to avoid statistical problems such as auto-correlation, and allow a better measure of natural groundwater quality variations. During preparation of the Permit, IUC submitted a March 25,2004 Hydro Geo CnemlffC-C) letter and a January 30, 2003 HGC groundwater velocity report wherein IUC suggested that local groundwater velocity at White Mesa was about l.l to 2.8 feetlyeir. Detailed DRC review found the January 30, 2003 HGC analysis to be based on an area between the tailings cells and Ruin Spring, and not focused on each individual monitoring well at the facility (see9l2ll04 DRC Memorandum). on october 15,2004 a conference call was held between DRC staff and representatives of IUC and HGC. During this call, DRC staff asked that ad-ditional work be done to determine local groundwater velocity at each monitoring well at the site, where velocity would be calculated on well specific hydraulic ionductivity and hydraulic gradient data. On this same date, IUC staff pioposed that there be two (2) different frequencies of routine groundwater monitoring at White Mesa, as follows: I I I I I I I I T I I T I t I I I I I B. C. A. 19. 36 l) ll Ir Ir li It t t t t t t t J t J t i i t Statement of Basis DRAFT December 1,2004 o Semi-annual (2 times/year) where groundwater velocity is less than l0 feet/year, and o Quarterly (4 times/year) where groundwater velocity is equal to or greater than 10 feet/year. Later IUC provided an October 19,2OO4 HGC letter report that revised previous HGC groundwater velocity calculations by providing well specific values. Afterreview of this HGC report, DRC staff found four (4) tailings wells at the White \desa facility exhibit local groundwater flow velociiy .quuI to or greater than 10 feetlyea4 including (see I ll23l04 DRC Memorandum, iables I ind2): o cross-eradient wells: MW-26 (14 feet/year) and Mw-32 (19 feet /year). Previously these wells were named Tw4-15 and rw4-17, respectivlly, and o Downeradient wells: MW-l I (135 feet/year)and MW-l 4 (62 feet/year) All other existing IUC tailings cell monitoring wells were found with local groundwater velocities of less than l0 feetlyear (ibid.). Based on this information, the Executive Secretary has agreed to accept IUC,s proposal for two(2) different routine groundwater monitoring scheduler ut th" aci1ty, based on the following findings: Areas of high groundwater velocity deserve more frequent sampling in order to rapidly detect contamination and remediate ilearlier while the problem is smaller and closer to the source. To do otherwise is not protective of groundwater quality resources, and serves only to make theproblem more expensive before it is discovered and corrected. At IUC wells where groundwater velocity is equal to or above l0 feetlyear, groundwater will travel more than 2.5 feetbetween quarterly sampling events. At the highest velocity tailings well, MW_t f 1t:Sfeetlyear), groundwater at this downgradient location will havel about 34 feet between quarterly sampling events. The Executive Secretary believes that this provides sufficient reaction time to confirm any contaminant exceedance and regain control thereof. At IUC wells where groundwater velocity is less than 10 feetlyear, groundwater will travel less than 5 feet between each semi-annual sampling event. At the tailings well with the lowest velocity, Mw-l(0.026 feetlyear) groundwater at this upgradient location wiil travel a very short distance between each semi-annual sampling event (0.01 feet), and auto-correlation will likely occur. Despite this statistical drawback, the Executive Secretary believes that semi-annual sampling at this and other low velocity locations is protective of the environment. Above and beyond these baseline frequencies, the permit contains provisions for accelerated groundwater monitoring to confirm the presence of groundwater contamination, see part I.G.l . Under these requirements, IUC is mandated to accelerate its monitoring frequency when any pollutant in any well exceeds its respective GWCL in Table 2 of the Permit. For those wells with a semi-annual baseline frequency, quarterly accelerated monitoring is required. For wells with a quarterly baseline schedule, monthly accelerated sampling is required. In summ ary, a single Statement of Basis DRAFT December 1,2004 exceedance in a single well will result in a much higher sampling frequency in order to confirm the apparent problem, and pursuant to Part I.G:I, this accelerated monitoring will continue until the Executive secretary can determine the compliance status of the facility. If groundwater contamination is detected and confirmed in the future, tec'hnology is available to control the contamination, and even reverse its flow and thereby contain it near its source. IUC owns and controls a large area of land downgradient of the tailings cells where it can control public access to groundwater. Further, the seeps and springs found at the edge of White Mesa where the public could be exposed tlo contaminated groundwater are even more removed from the taiiings cells. These long distances appeal to provide ample reaction time to deiect and confirm the presence of contamination, and design and implement corrective actions to regain control of said releases, should they occur. Momtonng raramglgrs Lrart r.D.rt.u,ll - t uLu IIvIU ouu rsuvr@rvrJ ; compliance' The need for laboratory analysis for I.both field and laboratory parameters are the Table 2 compliance parameters is self-evident. Certain other groundwater quality parameteis were added to assist in interpretation of general geochemical condiiions present in the aquifer, including the major anions and cations. Due to the limited informatiott uruilubl" and uncertainty in the characterization of the tailings cells contaminant source terms, a broad suite of VOCs are also required under the Permit (EPA Method 8260). In general, many VOC parameters may be key indicators of groundwater pollution, in that they are man-made and are *ouit" in groundwater environments, see discussion above. C. Special provisions [Part I.E.l(d)l - during review of the data from several split *-pting "r"rrt, ,ir." M ay, 1999, certain quality assurance issues have been identified by the Executive Secretary. In order to ensure that these issues are resolved in the future, special provisions have been added to the Permit to draw attention to them. I.E.2) - certain wells and piezometers exist at the Well Part I.- in order to Provide an 5) 6) B. 20. Ii li T I I 21. I1JC fr4tty th"t ur" **pt.t.a it the shallow aquifer, but are not listed in Table 2 as compliance monitoring wells for the tailings cells. These include five (5) piezometers associated with the *it-olif" ponds (p-l thru p-5), two (2) existing wells outside the IUC restricted area (MW-20 and MW -22), atdseveral wells related to the chloroform investigation. currently these chloroform investigation wells include Mw-4A, TW4-1 thru T,i/4-14, TW4-16, fW+-tS, and TW4-19, but may change as the investigation and corrective action project progresses' Depth to groundwater or head monitoring is required of these *"i1, in ora.r to maximize our understanding of local groundwater flow directions at the facility. To this end, a requirement was added to do this extra head monitoring at these existing wells and piezometers at the same frequency as the ermit requires that a number of new monitoring wells be installed, see Part I.H.l. To ensure that these new wells are properly located and compliance monitoring wells. 38 constructed, certain performance criteria have been added to the Permit in this section' i I t I I i t t i t i i t t t I i i I 22. Statement of Basis DRAFT December 1,2004 - this section has been added to the permit to provide general performance criteria for groundwater sampling. Most important of these is the requirement that all groundwater monitoring comply rritt a quality assurance(QA) plan, such as will be submitted by IUC for Executive Sicretary upprolrui, pursuant to Part I.H.6. In order to comply with requirements found in the GWep Rules iUeCR317-6-6.3(I) and (L)1, ruC will need to submit its existing QA plan to ensure ihut it it consistent with EPA guidance found in the RCRA Ground Water Monitoring Technical Enforcement Guidance (TEGD) document (EpA, 19g6). and I.H.9) - as described below, monitoring of the contact seeps and springs ut tt " rag" of Wrte Mesa is important because these locations are where the shaliow aquifer discharges, and henceform points of exposure for wildlife and the public for any groundwater contamination that may be released from the facility. This monitoring wili not replace the compliancewell monitoring required by Part I.E.l, which will provide a much earlier warning of arelease. Instead, the seep and spring monitoring is designed to compliment the IUCmonitoring well data, and confirm that activities at the IUC facility have not adversely impacted local surface water quality. Under the requirements of tLese two (2) sections of the Permit this sampling and reporting will be completed on an annual basis. Determination of those seeps or springs selected for sampling will be completed afterExecutive Secretary approval of the White Mesa Seep and Spring Sampling Report required by Part I.H.9. Commencement of this annual surface *iter monitoring will thenbegin after modification of the permit accordingly. DMT 6 and - Part I.E.6 stipulates the24. monitoring requirements standards set forth in Part needed to demonstrate compliance with the DMT performance LD.2 and 3 of the Permit, as summarized below: A.Tailines Cell 1 - including weekly wastewater pool level monitoring to determine compliance with the minimum freeboard requirement in Part 1.D.2. Again, if the maximum wastewater pool elevation is exceeded, IUC is required to immediatelynotify the Executive Secretary under the provisions of parts I.F.3 and I.G.3. Quarterly depth to groundwater and groundwater quality sampling and analysis is also required from three (3) discrete monitoring wells immediately adjacenito Cell l. DMT compliance is maintained at Cell 1 when the groundwater quality in these three (3) monitoring wells does not exceed their respeitive GWeS in fa'Ute 2 of the Permit. In the event that any groundwater contaminant in these wells exceeds a GWQS, IUC will be required to report the non-compliance pursuant to Parts I.G. I and2. A compliance schedule requirement has been added to part I.H.l to ensure the DMT monitoring wells are installed properly at cell 1. Tailines Cells 2 and 3 - including weekly wastewater pool elevation and slimes drain water level monitoring. DMT compliance is maintained when the water levels in the wastewater pools and in the slimes drain layers are below their respective maximums specified in Part l.D-2. In the event that either of these wastewater levels exceeds the requirements, IUC is required to report them immediately to the Executive Secretary in accordance *ith Part I.F.3 and I.G.3. Roberts Pond - including weekly monitoring of wastewater levels in the Roberts Pond at the mill site to verify that the wastewater head is maintained so as to provide the minimum 2-foot freeboard required by part I.D.3(c). B. C. Statement of Basis DRAFT December 1,2004 Feedstock Storase Area - including weekly monitoring to ensure that: Bulk feedstocks are located and stored only inside the approved Feedstock Storage Area, and that Containerized feedstocks located outside the approved Feedstock Storage Area are maintained in closed, water-tight containers. In order to ensure that IUC provides appropriate monitoring equipment, and adequate operation and maintenance procedures for DMT monitoring, a compliance schedule requirements has been added to Part I.H.l3 to require submittal and approval of a DMT Monitoring Plan. and I.F.7 - much of the D. I I I t I I I 1) 2) On25. di.""*'ir" above regarding determination of groundwater monitoring parameters rs intimately related to ttre type of ore or feedstock material being processed, and the types and conclntrations of chemicals used on-site in the milling process, on-site laboratory, etc. For this reason, the Executive Secretary has determined it critical to maintain an inventory of chemicals in storage and used at the facility in order to determine at some future date the appropriate parameters that should be considered both for characterization of the tailings cells wastewaters, and for groundwater monitoring parameters. To this end, monitoring requirements were added to Part I.E.7 to require IUC to maintain a current chemical inv-ntory on site. The Executive Secretary recognizes that some chemicals may be used at such a small rate that they do not constitute a potential risk to groundwater quality. In order to address this issue, an annual consumption rate of 100 fg/y, *ut tp""in"d. Using this provision, IUC need not inventory those compounds whose annual consumption is less than this amount. Reporting requirements for this inventory were also added to Part I.F.7, where IUC will ue requirld to submit a report at the time of Permit renewal, i.e., 180 days before expiration of the current Permit. The Executive Secretary has determined it important to establish a baseline inventory of historical and current chemicals used at the facility. To this end, a new Permit requirement was added to the Permit's compliance schedule in Part I'H'10' I.E. I 26. li I I li40 LFS*"d tHfl - uft"r r*i"* of the historic tailings cell wastewater quality samples *tt""t"a to Auie by IUC, it appears that IUC's tailings wastewater sampling and analysis has been focused on process control and not environmental considerations (see Attachment 6, below). Historically, IUC has not been required to conduct any comprehensive analysis of this tailings wastewater for environmental purposes. Consequently, the available data are limited both in the number of samples and pururn"i..r. iltU" information is also available regarding quality assurance issues for said sampling and analysis. In light of this situation a new requirement has been added to the permit to require a comprehensive and routine examination of tailings wastewater quality for environmental purposes. To facilitate this, a compliance schedule item was added to part I.H.5 to requireluc to submit a plan for Executive Secretary approval for routine tailings cell wastiwater monitoring. The purpose of this sampling plan is to identify the d]stinct sources of tailings wastewater that will be sampled (wastewater pool, slimes drain, etc), standardize all sampling and analytical procedures, and provide an r) 3) 4) ri i i t i i t t Jj i i J J t t t i I Statement of Basis DRAFT December 1,2004 outline for compliance with all related monitoring and reporting requirements in parts I.E.8 and I.F.8 of the Permit. This approach of annual sampling assumes that over several years a sufficient number of samples will be available to adequately describe the average chemical conditions of these wastewaters. Further, the approach in Part I.E.8 also specifies that the samples be collected in August, at the peak of the evaporation season in order to measure the highest contaminant concentrations in the sybtem. Other approaches to sampling frequency could have been used, such as: 1) a minimum number of days of mill operation, 2) sampling after a change in feedstocksprocessed, or 3) multiple samples for each season of the year, etc. However, all of these Lave drawbacks, in that they: l) ignore the dynamics of local weather conditions which change from year to year, 2) ignore processing schedule dynamics which are also variable, 3) require more samples to be collected, 4) mandate tedious monitoring andreporting to document and justifu the frequency used, and 5) result in increased sampling costs with little apparent benefit. In the end, the Executive Secretary chose a simple approach of one (l) annual sample from each tailings wastewater source to be collected when contaminant concentrations should be highest. The information generated by this routine monitoring will also be helpful in the on-goingchloroform contaminant investigation. In an April 11, 2002 Technical Information Request, DRC staff asked IUC to fully characteize the contaminants in this wastewater, and allow the State to collect split samples in this process (ibid., pp. l5-16). The need for this characterization was discussed with IUC in meetings of eprii-tZ and,i4,2OO2. In the latter meeting, IUC agreed to sample and, analyze the tailings wastewater for a comprehensive suite of contaminants, including, but not limited to: metals, VOCs, Semi-vocs, etc. It was also agreed that a sampling plan would be submitted for DRC approval before sampling began. Later,IUC provided a May 3l,2}02work plan for thissampling. DRC staff reviewed the sampling plan and requested additional information in a July 3 , 2002 email. Because discussions about the content of this sampling plan are on-going, Part I.H.5 has been added to the Permit to require IUC to submit a tai'iings cellwastewater sampling plan for Executive Secretary approval. Pending completion of this sampling plan, on August 12,2003IUC voluntarily submiued results of several grab samples collected from the tailings cells in March, 211i,which aresummarized in Attachment 6, below. Preliminary DRC review shows the following: IUC samples were collected from impounded wastewaters in Tailings Cells I and 3 and analyzed for a partial list of the analytes previously agreed to in the plan, including: major ions, nutrients, metals, and radiologics, No sampling was conducted of impounded wastewater at either Tailings Cells 2 or 44 because no exposed solution was available at the time of sampling (March, 2003), No samples were collected from the slimes drain layers or leak detection systems in Cells 2,3, or 4A, No analysis was made for any voC or Semi-voC contaminants in any sample. This March,2003IUC data may be used at sometime in the future by the Executive Secretary in his review of routine monitoring data to be collected under the permit. In Statement of Basis DRAFT December 1,2004 the meantime, the Permit will require routine monitoring in order that a defensible and representative characteizationof tailings wastewater quality be completed. part I.E.8 of the Permit also requires IUC to provide 30-day prior notice, so as to allow the Executive Secretary an opportunity to collect split samples of these tailings cell wastewaters. DRC staff intena to periodically conduct such split sampling as a means of verification of IUC',s tailings wastewater chatacteization. Reporting requirements in Part I.F.S mandate that IUC report the annual tailings *urt.*ut-., quality results with the 3'd quarter groundwater monitoring report, due each year on Decembei 1. This section also requires that the content of these reports be ,i*itu, !o the quarterly groundwater monitoring reports, by providing the field data sheets, copies oftn" laboratory reports, a quality assurance evaluation and data validaiion, and reporting in etectronic format, pursuant to Part I'F'l(a), O), (d), and (e)' - this section was added to reporting and to detail the types of routine quarterly groundwater monitorin g datarequired. The schedule provided in Table 6 of the Permit I I I I 27. illo*. IUC 45 days after the end of each quarter to submit the required information. Most of the data requirements are self-explanatory, but are specificallylistgd in the permit to assist tUi in providing complete submittals. The list of required information will also provide a guidi for the types of information that must be considered in preparatiin of the Groundwater Monitoring Quality Assurance Plan, required by Part DMT performance Upset Reports (Part I.F.3) - this requirement was added to the Permit f"r "lrrifr*tion prrp*"r to distinguish this reporting from the routine DMT performance reporting to be submitted quarterly under Part I.F.2. Examples of DMT failures that need lr li r.H.6. In addition, the Executive Secretary has required the submittal of quarterly water table contour maps to emphasis the need to understand groundwater flow directions at the facility. pursuant to Part IV.N.3, these contour maps will allow the Executive Secretary to require new compliance monitoring wells should it be discovered that groundwater flow directions have changed. A section has also been added to require IUC to provide the groundwater quality results in an electronic format, which will allow the Executive Secretary ready access to the information and will speed review of the data' ul purt ff : fras been uaa.O to ttr. permit to require quarterly reporting for all monitoring related to the DMT standards specified in Part I.8.6, including wastewater pool elevations in all three (3) tailings cells, slimes drain head for Tailings Cells 2 and 3, and a sunmary table of weekly wastewater levels measured by IUC at the Roberts Pond in the mill site area. In the event that IUC discovers an upset condition, where the DMT performance standard has been violated, they are required to notify the Executive Secretary within 24-hours of discovery (verbal) uri 5 duytlwri6en; of the problem. Examples of these types of problems, include, but are not limited to: Excess wastewater head at any of the tailings cells or the Roberts Pond, Excess leachate head in the slimes drain layer at Tailings Cells 2 or 3; rtI28. ll 29. 42 lr ll Ir 11 a a t t i t I t i i i J i i J J t J i i i Statement of Basis DRAFT December 1,2004 to be reported under this section include, but are not limited to: excess wastewater pool elevations in Tailings Cellsl, 2,3, andthe Roberts Pond; excess slimes drain leachate heads at Tailings Cells 2 and 3; bulk feedstock materials stored outside the approved storage area; and leaking containers of altemate feedstock materials, etc. Other lnformation (Part I.F.4) - in the event that the Permittee omits information, or discovers incorrect information was reported, this section provides a timeline by which IUC must correct or complete the respective repoft. I.F.5) -this section has been addedto the Permit to provide specific guidelines on what kinds of information are required formonitoring well as built reports. The Executive Secretary deems it necessary to provide these details, in light of the need for additional monitoring wells at the faciliiy, as mandated by Part I.H.l of the Permit. Part of the requirements mandated here require the geologic log for each monitoring well be prepared by a Professional Geologist licensed by the State. This requirement was added in order to comply with the recent Professional Geologist Licensing Act, enacted by the Utah State Legislature in2002, and the attending Professional Geologisi Licensing Rules (UAC Rl56-76). The requirement that the survey coordinates for each monitoringwell be prepared by a Utah licensed land surveyor or engineer was added to the permit in order to ensure accuracy for the survey coordinates reported. - this section of the permit is taken almost verbatim from the GWQP Rules in UAC R317-6-6.16(A). It requires the permittee to accelerate the frequency of monitoring in the event that any pollutant in any well exceeds its corresponding GWCL, as defined in Table 2 of the Permit, and to continue that accelerated monitoring frequency until such time as the Executive Secretary ca1_ determine the compliance status of the facility. Because semi-annual and quarterly groundwater monitoring have been defined as the routine frequencies in part I.E.l, this accelerated monitoring status would require quarterly and monthly groundwater quality sampling, respectively. Violation of Permit Limits (Part I.G.2) - this section is taken almost verbatim from theGWQP Rules, found in UAC R317-6-6.16(8). 34. Failu Rules found in 30. Gro31. 33. 35. 32. Permit - this section of the Permit is taken almost verbatim from the Gwep UAC R317-6-6.16(C) I.H.l6) - general requirements to addressfacility out-of-compliance status are found in Part I.G.4 of the permit, which is taken almost verbatim from the GWQP Rules (UAC R317-6-6.17). This section of the permit references the ability of the Executive Secretary to require immediate implementation of the Contingency Plan to regain and maintain compliance with the permit, should the Permittee fail to act [see Part I.G.4 (d)]. Such Executive Secretary action is authorized by the GWQP Rules IUAC R3 I 7-6-6. I 7(A)(4)]. This plan is also required as a part of a Permit application in the GWQP Rules IUAC R317-6-6.3(N)]. To date, IU0hasn,t submitted a Contingency Plan for Executive Secretary approval. The overall goal for thisplan is to provide the necessary actions for IUC to re-gain compliance in seveial areas regulated by the Permit, including: groundwater quality, limitations or prohibitions on contaminants discharged to the tailings cells, and/or Discharge Minimization Technology performance standards (e.g. tailings cell solids and wastewater elevations, slimes drain 36. 37. I I I I I I I I I t I T I I A. B. 38. Statement of Basis DRAFT December 1,2004 operation, etc). For this reason a compliance schedule item in Part I.H.16 has been added to ttre permit to require IUC to provide a final plan for Executive Secretary approval. Accelerated Monitorine Status for New Wells (Part I.G.5) - this section was added to the P"@liancemonitoringofthenewtailingsce1lmonitoringwells required by Part I.H.1 does not beginuntil after Executive Secretary approval of the nack$ound Groundwater Quality Report required by Part I.H.4. As a result, IUC will not be required to accelerate their monitoring frequency, as per Parts I.G.1 (Probable Out- of-Compliance), or I.G.2 (Out-of-Compliance), until after approval of this report. - the GWQP Rules require th"t th" Pr""it application include several information items regarding quality assurance and quality.otrtrol for groundwater monitoring [UAC R3l7-6-6.3(I) and (L)]. Part of this riquirlment mandates that groundwater sampling conform to the EPA RCRA Ground Water Monitoring Technical Enforcement Guidance (TEGD) document (EPA, 1986). prior to the May,leel sptit sampling event, IUC provided a Groundwater Quality Assurance Project Planto the DRC (3/90 ruC Groundwater QA Project Plan, Rev. 2). However, thisilan was written for purposes of the NRC radioactive materials license, and did not specifically rely on the EPA RCRA TEGD (ibid., p. 3). In order to provide IUC the opportrnity to modiff their existing plan to conform to the State requirements, a ,"* .o-piiur"" scledule item was added to Part I.H.6 of the Permit, which mandates a revised pian be submitted for Executive Secretary approval. After review and approval of this modified plan, the permit will be re-opened and modified to require that all future groundwater sampling comply with the new plan. I.H.7) - during several rit"r rrrit. ,"d four (4) split groundwater quality sampling events since May, 1999, DRC staff have noted the need for remedial construction, maintenance, or repair at several monitoring wells at the IUC facility, including: Well Development - 16 of the existing monitoring wells at the IUC facility fail to pr"d".. "1*t groundwater in confornance with the EPA RCRA TEGD. The observed groundwater turbidity appears to be the product of incomplete well developmint, and poses a potential for bias of the groundwater quality analytical results, particularly for metals and nutrients' Consequently, the Executive Secretary has determined it necessary to require IUC to develop these wells in order to ensure they meet the EPA RCRA TEGD turbidity criteria of 5 nephelometric turbidity units (NTU), to the extent reasonably practicable' Protective Surface Casinss: Piezometers - in response to a DRC request for "ddtt."rt hydr"geologic information, IUC installed five (5) piezometers at the White Mesafaciiity in December, 2001 (518102 Hydro Geo Chem Report, p.1)' While no protectivl steel surface casings were called for in the original approved installation plan, it is important to protect these piezometers because they are used for groundwater head monitoring under PartI.E.2. The lack of protective casing porJr a problem because the l-inch diameter PVC piezometer casings could be easily bioken by surface activities. Also, PVC is prone to degradation by ultraviolet light, and could be easily degraded. In order to ensure that the monitoring wells are properly repaired and developed in a timely manner these requirements have been added to Part I.H.7. l1 44 Statement of Basis DRAFT December 1,2004 A. B. C. D. 39. t i t t i t i i Jj t i t i t J i t i -3 Veri Part I. during recent information, including: Missine Geolosic Loe - review of the MW-3 well as-built diagram shows that no geologic log was provided at the time of well installation(7194 Titan Environmental Report, Appendix A, as-built diagram). consequently, it is impossible to ascertain if the screened interval was adequately located across the base of the shallow aquifer, i.e., at or below the upper contact of the Brushy Basin Member of the Morrison Formation. Lack of Filter Media - well MW-3 was constructed without any filter media or sand pack across the screened interval. Excessivelv Lone Casine Sump - a 9 or lO-foot long non-perforated section of well casing was constructed at the bottom of this well. Poor Positionine of Well Screen Apparent - about 2 week after installation of well MW-3, mill staff found the well to be dry (ibid., Appendix A,9ll4l7g). However, in late September, 1979 mill staff measured the static water level at a depth of 83.4 ft (ibid., Appendix 8,9125179). Recent DRC water level measurements show that the water table surface is found at a similar depth, 83.6 feet below the water level measuring point (ft bmp, 919/02). After consideration of the well's measuring point stickup , r.95 feet, the September,2oo2 water level was only about 5.3 feet above the base of the well screen. This well construction and water table depth poses a problem in that at the IUC purge rate of 2 gallons per minute (gpm), the well is rapidlypurged dry and IUC is unable to complete both purging and sample collection in one continuous process. Arguments have been made by IUC that the well screen in MW-3 was properly set based on the local geology found there. However, no geologic or geophysical logs exist to support this assertion. Consequently, the Executive Secretary has determined it necessary to verify, retrofit or reconstruct this well. Key to this mandate is the requirement to determine the total saturated thickness of the aquifer at well MW-3, which will require determination of the depth of the upper contact of the Brushy Basin Member of the Morrison Formation at this location. This can be done either by geophysical logging and/or drilling of a confirmation boring in the immediate vicinity of the well. After determination of the complete saturated thickness of the aquifer at well MW-3, the Permittee is required to retrofit or re-construct the well to ensure the well screen fully penetrates the saturation. Thereafter, a new well as-built report must be submitted. After approval of the replacement well, if needed, the Executive Secretary may require plugging and abandonment of the former well. The Permittee is also required to provide at least a7-day notice of all field activities, so as to allow the Executive Secretary to observe these activities and participate in decisions regarding the fate of well MW-3. white Mesa Seeps and Sprinss Samplins Report (part I.H.9) - in a February 7,2000 request for information, IUC was asked to provide a hydrogeologic study of the contact seeps and springs found at the edge of White Mesa (see 217100 DRC Request for Information, p. 13). The purpose of this study was to establish background groundwater flow and water quality conditions at these discharge points, and included a request for: split sampling events and after review of available well MW-3 as-built DRC staff have found several problems with the construction of this well, 40. Statement of Basis DRAFT December 1,2004 Land Survey - of the seePs/sPrings, Water Table Contour Map - of both the IUC monitoring wells and the contact seeps/springs, and Groundwater ouality Sampline - and analysis of said seeps/springs. IUC responded to portions of this request in a September 8, 2000 submittal. Later the DRC renewed its request for survey coordinates for these seeps and springs in a March 20,ZO1t letter to IUC (3120101 DRC Request for Information, p. 6). Subsequently, IUC provided survey coordinates for three (3) contact seeps at the edge of White Mesa, including elevation data (9l7l0l ruC letter, attached spreadsheets). Subsequently, other parties expressed interest and concern in the groundwater hydrology and walter quality oflhese seeps and springs at the edge of White Mesa, including the Moab office of the Bureau of Land Management (BLM), and White Mesa band of the Ute Mountain Ute Tribe (Ute Tribe). ln June, 2002the DRC proposed a collaboration between the BLM, Ute Tribe, IUC and DRC to study the hydrogeology of the White Mesa contact seeps and springs. In subsequent discussions it was agreed that: 1) the Ute Tribe, with BLM assistance, would complete a detailed reconnaissance of all the seeps and springs found downgradient of the IUC tailings cells at the edge of White Mesa, 2) IUC would provide a land survey to accurately locate and determine the elevation of all the seeps and springs identified by the Ute Tribe, and 3) DRC would provide analytical services for the groundwater quality samples collected. Later,on September 20,2002 DRC and Ute Tribe staff conducted a preliminary field survey of seeps and springs in the area, and located six (6) different discharge points at the edge of White Mesa, all of which appear to be hydraulically downgradient of the IUC facitity. These seeps and springs are summarizedinTable 10, below. 2002 Footnotes: ffin.-tir.a.ompass direction and approximated distance from estimated center of IUC Tailings Cell 1. During a May 21,2003 conference call between BLM, Ute Tribe, IUC and DRC staff several otheraspects of this hydrogeologic study were discussed, including: goals and objectives ofthe study, need for an upgradient reference seep, field and laboratory parameters to sample and analyze, field sampling equipment and methods, data quality assurance rrr"ur*r"i needed, and capability for split sampling. At the conclusion of this 46 I I t I t I I I I I I t T I I I I A. B. C. Table 10. Known White Mesa Perimeter Seeps and Springs as of Septembff Seep or Spring Name USGS 7.5 Minute Ouadranqle Approximate Location Relative to IUC Tailines Cells (r) Approximate MaP LocationDirectionDistance (ft) Entrance Seeo BlackMesa Butte East 4,700 -300 ft E.,0 ft S., NW Corner, Sec. 34. T. 37 S., R.22F,. Westwater Seep Black Mesa Butte West 5,200 -1,000 ft E., 200 ft S., NW Corner, Sec. 32.T.37 S., R.22E. Cottonwood Seep Black Mesa Butte Southwest 9,400 -1,500 ftN,2,200 ftW., SE Corner, Sec. 31. T.37 S., R.22F,. Ruin Spring Black Mesa Butte Southwest 13,000 -2,200 ft E., 1,200 ft S., NW Corner, Sec. 8. T. 38 S.. R.228. Corral Seep Big Bench South 16,200 -300 ft E., 1,200 ft N., SW Corner, Sec. 10. T. 38 S.. R.22 E. Tank Seep Big Bench Southeast 21,400 -2,300 ft N., 400 ft W., SE Corner, Sec. 15, T. 38 S., R.22 E. i t i t t J i tj i t t t i t J II Jj Statement of Basis DRAFT December 1,2004 meeting, the parties agreed to convene again after the Ute Tribe completed its detailed field survey of White Mesa seep and spring locations. On July l,20}3,the Ute Tribe reported that the field survey was about half done (7lll03 Ute Tribe email). To date, it is unknown if the Ute Tribe field survey has been completed. After all of these considerations, the Executive Secretary has determined it appropriate for IUC to bear the responsibility forthis study, by adding a Permit requirement for a White Mesa Seeps and Springs Sampling Report in Part I.H.9. This is done not only to ensure IUC participation, but to accelerate completion of the study, and provide timely resolution of concerns held by local citizens and tribal members regarding the potential for pollution from the tailings cells to adversely affect nearby surface *uG. quality. A provision has also been added to Part I.H.9 to allow the Executive Secretary to re-open and modify the Permit after approval of said sampling report, in particular parts I.8.5 andI.F.6. The purpose of this action is to allow the collection of background groundwater head, flow, and water quality data during the operating life of the facility. This is important in that these seeps and springs form points of exposure for wildlife and the public where offsite groundwater contamination could be discharged. By way of clarification, it is not the Executive Secretary's intent to use this siep and spring sampling in lieu of compliance monitoring well sampling at the facility. Instead, it is to be used to complement that data collected from wells at the IUC faciliiy, with the intent of establishing background water quality conditions at these surface water locations. Recently IUC initiated its own sampling of Ruin Spring and sampled Cottonwood Spring on one occasion when water was available. At the time these samples were collected, these were the only seeps and springs IUC considered to have sufficient flow to allow sampling. Results of this sampling have yet to be reviewed by the DRC. and Plan 2\ - after review of available well completion information, IUC was informed that the construction of a deep supply well, WW-2,locatedhydraulically upgradient of the mill site, was inadequate, in that it failed to provide an annular seal that would isolate the deep confined aquifer from the shallow unconfined aquifer (see 217100 DRC Request for Additional information, pp. 7-9). This same DRC request also asked that this problem be investigated for all other deep supply wells at the IUC facility (ibid., p. 9). In response IUC agreed to consider several alternatives for well WW-2 at the time of mill decommissioning (9/3/00 ruC Response, p.20). To this end, a new condition was added to the Permii in part I.H.12 to require submittal of a work plan within I year of Permit issuance that would apply to all the deep supply wells at the facility. This mandate also provides: l) a performance objective to ensure that both physical and hydraulic barriers are constructed in the deep supply wells at the time ofplugging and abandonment to prevent hydraulic communication between the shallow unconfined and the deep confined aquifers, and2) a requirement that the provisions of the approved plugging and abandorr*ent plan on or before decommissioning of the uranium mill. - as described above, the Executive Secretary in issuance of this Permit has reviewed the existing engineering design and construction, determined the DMT design and performance standards (Parts I.D.1 and I.D.3), established DMT monitoring criteria (Part I.E.6), and established DMT reporting requirements (Part I.F.2). However, the Executive Secretary has not yet had the opportunity to review and approve the specific activities, procedures, and equipment that IUC will use to monitor and verify DMT compliance. In order to provide for this 42. 43. Statement of Basis DRAFT December 1,2004 opportunity, part I.H.l3 has been added to the Permit. Facilities that need to be examinea in this plan include, but are not limited to: various wastewater level criteria for Tailings Cells l, ),3 andthe Roberts Pond; the Feedstock Storage Area restrictions, and secondary containment for mill site reagent storage' Relatively short timeframes have been provided in order to accelerate IUC's implementation of DMT. Provisions have also been included in Part I.H.13 to allow the Executive Secretary to re-open and modify the Permit, so as to include all necessary monitoring procedures and equipment. .H.14) - as discussed above Part although somewhatTailinqs cell 44 Redesign ancl l(econstrucUon ( raIT r.Ia.l I , - aluruuB[ suurtrw ."d*dr"t *ith th" prwisions of Part I.D.4, this requirement has been added to emphasize the need for Executive Secretary approval before any re-construction of tailings Cell44, including: soil foundation or sub-base preparation, liner construction, or leak detection system construction. This section also allows the Executive Secretary to re-open and modify the Permit to add any necessary design, construction, operation, .orrltotirg or reporting requirements for the revised cells' the GWQPExecutive Secretary -htndtngs Kegarotng rxtsung rasrlty nequueurguls - Lrre \r Yv vr n rt"r -uraate that G Executive Secretary may issue a Permit for a facility that was constructed before adoption of the GWQP Rules in 1989, i.e., an "existing" facility, that certain provisions are met by the applicant, including [UAC R3 l7-6-6'a(Q]: ,,...1. the applicant demonstrates that the applicable class TDS limits, ground water quality standards and protection levels will be met; 2. the monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; the Executive Secretary has determined it necessary to require IUC to continue to compiete its removal of th" contaminated materials and liner system in existing tailings Cell44. Over the past two (2) years IUC has been removing the raffinates and salts that have been stored inthe cell, and disposing of them in tailings Cell 3. To ensure that this process is completed in a timely manner, a requirement has been added to Part I.H.14 to iequire IUC to submit a contaminant removal schedule for completion of this work for Executive Secretary approval. This new requirement also mandates periodic progress reports, and a frnal-completion report that isto be submitted after contaminant removal is finished, for Executive Secretary approval. It is anticipated that adequate contaminant removal will include removal of all fluids, any residual salts or solids, the FML liner system, any underlying LDS, and all contaminated clay sub-liner and any contaminated sub-soils. b*ing permit preparation, it was agreed that IUC will perform a radiologic survey and/or uranium laboratory analysis ofthe clay subJiner and ifnecessary any unaertying soils found under tailings Cell 4A to determine the total extent of any clay sub-liner or subsoil contamination. This approach is justified, in that under oxidizing or acidic conditions uranium is expected to by highly mobile in soils. Consequently, the Executive Secretary believes that uranium soil concentrations can be used as a tracer to estimate the vertical penetration of contaminants in the raffinates and salts once stored in Cell4A. No approvut of tn. final contamination removal report will be issued until the Executive Secretary is satisfied that any contaminants potentially released to the clay sub- liner or sub-grade soils via the FML leakage discussed above, have been adequately recovered and placed back into appropriate engineering control. 44. 45. l t1 48 I t It I I I I I i i I I t t i I t t t t t t Statement of Basis DRAFT December 1,2004 3. the applicant utilizes treatment and discharge minimization technologt commensurate with plant process design capability and similar or equivalent to that utilized byfocilities that produce similar products or' services with similar production process technologlt; and, 4. there is no current or anticipated impairment of present andfuture beneficial uses of the ground water." After consideration of the above discussion, the Executive Secretarybelieves the GWep Rule requirements have been or will be met by the provisions of the draft permit, as described below: A. Applicable TDS Limits. GWOS. and GWPLs - the draft Permit establishes both GWQS and GWCLs for all related contaminants known to exist in the tailings wastewater effluent. On an interim basis, the GWCLs assigned herein were based on the factoring approach allowed in the GWQP Rules. Later,after completion and approval of the existing well Background broundwater Quality Report (part I.H.3), the Executive Secretary will establish a GWCL based on descriptive statistics (X+2o) for all compliance parameters in Table 2 ineachmonitoringwell' Future compliance monitoring at the facility will verify if IUC continues to meet these GWCLs at each well. If at sometime, one of more wells exceed its GV/CL for TDS or any other Table 2 contaminant, enforcement action will be taken to ensure local groundwater quality is restored. B. Monitoring Plan. Sampling and Reportins Requirements - groundwater monitoring at the facility is adequate in that all related contaminants known to exist in the tailings effluent at elevated concentrations have been selected for compliance sampling, and respective GWQS and GWCL have been established. DMT monitoring requirements have also been determined for each potential contaminant source at the facility. Although a certain number of monitoring wells need to be installed, and groundwater compliance and DMT monitoring plans need to be finalized and approved, the Executive Secretary has required th.s" activities to be completed and the missing plans submitted for approval. Upon approval of these activities, completion by IUC, and submittal and approval of the required monitoring plans, the Executive Secretary will re-open and modify the permit to incorporate all necessary requirements. At that point, the approved monitoring plans will become enforceable appendices to the Permit, ana th" Permit will be complete in terms of providing adequate monitoring and reporting. C. Satisfactory DMT - the review conducted herein has identified those aspects of existing facility design and construction that do not meet current standards. In fum, the Permit specifies new monitoring and operational improvements to minimize the potential for discharge of contaminants to native soils and groundwater from several potential sources at the facility, including the tailings cells, wastewater ponds, feedstock storage areas, etc. D. Impairment of Beneficial Uses of Groundwater -This determination will be made by the Executive Secretary after IUC completes two major efforts: 1) Improvements to the existing monitoring well network, including addition of new wells to provide more discrete and more rapid detection of potential seepage release from the tailings cells, and establishment of an approved groundwater monitoring quality assurance plan to enhance reliability of reported monitoring DRAFTStatement of Basis Attachments (11) F:/.../IUCgwpSOB2f.doc File: IUC Ground Water Permit LBM:lm December 1,2004 results, and2) Submittal of a Background Groundwater Quality Report to provide a compreheniive evaluation of local groundwater quality conditions' After review of this report, the Executive secretary will re-open the Permit and modiff the GWCLs to reflect natural groundwater conditions, or may take enforcement actions as necessary to protect local groundwater quality and all related current or future beneficial uses oigrdundwater. In either case, a public review and comment period will be frovided, either for a modified Permit, or at the time of approval of *y groundwater corrective action plan that may be required' with regards to possible future groundwater quality impairment, infiltration, groundiater flow, and contaminant transport modeling will be providedby IUC io predict future compliance by the facility. The Permit requires that these types of models be used tolvaluate the existing NRC approved Reclamation Plan for the facility, and stipulates minimum performance criteria for the same. If the modelingindicates that these minimum performance criteria will not be met, then: l. Changes to the tailings cell cover design will be implemented by the Executive Secretary in the Reclamation Plan under the State License, and 2. The input values to these models will become the design basis for the final engineiring design, specifications, and construction parameters for the cover system at the reclaimed facility. 50 t t i t i i i t I J i i J i t t tj t Statement of Basis DRAFT December 1,2004 References D'Appolonia Consulting Engineers, Inc., February, 1982, "Construction Report Initial Phase - Tailings Management System White Mesa Uranium Project Blanding, Utah Energy Fuels Nuclear Inc. Denver, Colorado", unpublished consultants report, approximately 7 pp., 6 tables, l3 figures,4 appendices. Dames & Moore, January 30,1978, "Environmental Report White Mesa Uranium Project San Juan County, Utah for Energy Fuels Nuclear, [nc., unpublished consultants report, approximately 549 pp., 9 appendices. Deutsch, W. and P. Longmire, February, 1997,"Practical Applications of Groundwater Geochemistry", National Ground Water Association seminarproceedings, Denver, CO, approximately 988 pp. Energy Fuels Nuclear, Inc., March, 1983, "Construction Report Second Phase Tailings Management System White Mesa Uranium Project Energy Fuels Nuclear, Inc.", unpublished company report, l8 pp., 3 tables, 4 figures, 5 appendices. Hem, J.D., 1985, Study and Interpretation of the Chemical Characteristics of Natural Water", 3'd Edition, USGS Water Supply Paper 2254,264pp. Hintze, L.F., 1988, Geoloeic History of Utah, Brigham Young University Geology Studies Special Publication 7, 202 pp. Hydro Geo Chem, Inc., May 8, 2002,letter report of as-built details for monitoring wells and piezometers at the IUC White Mesa uranium mill, unpublished consultants report from Stewart J. Smith to Michelle Rehmann, includes May 9,2002 hansmittal letter by David C. Frydenlund of International Uranium Corporation to William J. Sinclair,2 pp. Hydro Geo Chem, Inc., January 30, 2003,"Site Hydrogeology and Estimation of Groundwater Travel Times in the Perched Zone White Mesa Uranium Mill Site Near Blanding, (Jtah", unpublished consultants report, l8 pp., 2 tables, 7 figures. Hydro Geo Chem, IDC., March 25,2004, untitled letter from Stewart Smith to Harold Roberts, 4 pp. Hydro Geo Chem, Inc., October 19,2004,letter report from Stewart Smith to Harold Roberts on well specific groundwater average linear velocity, 3 pp., I table, 2 figures; includes an October 20,2004International Uranium (USA) Corporation transmittal letter from David C. Frydenlund to Loren Morton, 1 p. International Uranium Corporation, March, 1990, "White Mesa Mill's Ground Water QA Project Plan, Rev. 2", unpublished companyplan, 17 pp, includes February 24,1999 transmittal letter from Michelle R. Rehmann to William J. Sinclair,2 pp. International Uranium Corporation, May 28,1999, "Groundwater Information Report White Mesa Uranium Mill Blanding, Utah", unpublished company report, I l3 pp., l2 tables, 15 figures, 8 attachments. Statement of Basis DRAFT December 1,2004 Intemational Uranium Corporation, September 30, 1999, "Chloroform Source Assessment Report", unpublished company report by Michelle Rehmann, 13 pp., 2 figures, and2 appendices. International Uranium Corporation, August, 2000, "Construction Report Tailings Cell 4A White Mesa Uranium Mill - Tailings Management System", unpublished company report, 13 pp., 2 fi gures, 12 attaclwrents, 1 4 photographs' International Uranium Corporation, September 8, 2000, "Groundwater Information Report Revision Package", unpublished company report, 31 pp., l1 attachments, includes September 8, 2000 transmittal letter from David C. Frydenlund to William J. Sinclain, 2 pp. International Uranium Corporation, June 22,2001, "March 20,2001 UDEQ Letter and Request for Additional Site Hydrogeology Information in Response to IUSA September 8, 2000 Revised Groundwater lnformation Report; Groundwater Discharge Permit for White Mesa Mill; Followup to May l l, 2001 Letter from David C. Frydenlund to William J. Sinclair", unpublished company response, 20 pp.,14 attachments' International Uranium Corporation, July 17,2OOl, "Draft Spill Management Plan, Groundwater Discharge Permit Application for White Mesa Mill", includes three plans: l) July 17, 2001 Stormwater Best Management Practices Plan, 7 pp.,4 figures, I table, and2 Appendices (Appendix 1: July 17,2001 :Spill Prevention, Control, and Countenneasures for Chemicals and Petroleum Products", l4pp.,6 tables, 2 figures; and Appendix2: April 29, 1998 "Emergency Response Plan", l5 pp.,4 exhibits, 2 appendices, I figure, I table). Intemational Uranium Corporation, September 7,200l, "Updated Topographic Map, Groundwater Discharge Permit Application for White Mesa Mill", unpublished company letter from Harold R. Roberts to William J. Sinclair, 1 p., includes map and 4 spreadsheets. Intemational Uranium Corporation, May 3l,2002, "Pond Solution Sampling Workplan White Mesa Uranium Mill Site Near Blanding, IJtah", unpublished company work plan, 4pp., includes May 31, 2002 transmittal letter from Michelle Rehmann to William J. Sinclair, 2 pp. International Uranium Corporation, September 6,2O\2,"Transmittal of Brushy Basin Contour Map, White Mesa Mill Site Utah DEQ Notice of Violation and Groundwater Corrective Action Order UDEQ Docket No. UGQ-20-01 of August 23, 1999", transmittal letter (2 pp.) and unpublished company contour map. Intemational Uranium Corporation, October 15,2\O2,"W.ater Level Map and Resolution of Increasing Water Levels Observed in MW-4, Utah DEQ Notice of Violation and Groundwater Corrective Action Order, UDEQ Docket No. UGQ-20-01 of August 23, lggg",unpublished company submittal, 2pp.,l map, 50 pages of water level data. I I I t I t I I I t I I I I I I I I I52 i i i I'l I i i t Jj I J t J J t i i i Statement of Basis DRAFT December 1,2004 Intemational Uranium Corporation, December 20,2002, "November,2002 Letter from Utah Department of Environmental Quality to International Uranium Corporation Regarding November,200l Split Sampling Results for the White Mesa Uranium Mill", unpublished company response, 4 pp.,2 attachments. International Uranium Corporation, August 3l,z}}4,"International Uranium (USA) Corporation Source Material License No. SUA-1358 White Mesa Mill, Blanding, Utah Semi-Annual Effluent Monitoring Report for Period January I,2OO4 through June 30, 2004,,, unpublished company monitoring report, 3 pp., 7 attachments, includes transmittal letter from Ron Berg to Mr. Dane Finerfrock, 2 pp. International Uranium Corporation, October 17,2}}3,"September 16,2003 Letter from the Utah Departrnent of Environmental Quality, Division of Water Quality to International Uranium (USA) Corporation", unpublished company response, 3 pp., 2 attachments. uranium corporation, February 19,2004, "Supporting Information for GwDp,,, correspondence from Harold Roberts to Loren Morton, I p. 3 attachments. National Library of Medicine,Hazardous Substances Data Bank, part of the Toxnet System, found on the intemet at: http://toxnet.nlm.nih.gov/. Pankow, J.F. and J.A. Cherry,1996, Dense Chlorinated Solvents and Other DNApLs in Groundwater, Waterloo Press, portland, Oregon, 522pp. Risher, J.F. and S.W. Rhodes, June, 1995, "Toxicological Profile for Fuel Oils", U.S. Department of Health and Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry, 231pp.,2 appendices, found on internet at: www.atsdr.cdc. eov/toxprofi les/tp75-c3.pdf. Thomas, D. and J.J. Delfino, Fall, 1991, "A Gas Chromatographic / Chemical Indicator Approach to Assessing Groundwater Contamination by Peholeum products", Ground Water Monitorine Review, National Ground Water Association, pp. 90-100. Titan Environmental Corporation, July, 1994, "Hydrogeologic Evaluation of White Mesa uranium Mill", unpublished consultants report, approximately 5l pp., 5 tables, 19 figures, 7 appendices. Titan Environmental Corporation, September,1994,"Points of Compliance White Mesa Uranium Mill", unpublished consultants report, 13 pp., I table, 4 figures, 3 appendices. Umetco Minerals Corporation, April 10, 1989, "Cell4 Design", unpublished company report, includes: l) April 10, 1989 letter from Curtis O. Sealy to Edward F. Hawkin., t pp., *itf, 60 pp. of technical response materials, and2) August, 1988 Umetco Minerals Corporation "Cell 4 Design Tailings Management System", unpublished company report, 17 pp.,2 attachments, and 2 appendices. Umetco Minerals Corporation and Peel Environmental Services, January, 1993, "Groundwater Study White Mesa Facility Blanding, IJtah",unpublished company and consultants report, approximately 54 pp., 5 appendices. Statement of Basis DRAFT December 1,2004 umetco Minerals corporation, June, lgg4,"Gtoundwater Study 1994 Update White Mesa Facility Blanding, IJtah", unpublished company report, 51 pp', 6 appendices. United States Code of Federal Regulations, Title 10, Chapter 1 - Energy, "Domestic Licensing of Source Material", Part 40 (10 CFR 40), Appendix A "Criteria Relating to the Operation of Uranium Mills and the Disposition of Tailings or Wastes Produced by the Extraction or Concentration of Source Material From Ores Processed Primarily for Their Source Material Content", available on the internet at: http://www.nrc.gov/reading- rm/doc-collections/cfr/. United States Court of Appeals, District of Columbia Circuit, February 25,2003, Docket Nos' 0l-102g, 0l-103i, 0l-1034, and 01-1037,City of Waukesha; Village of Sussex Water Commission; Radiation, Science & Health; Nuclear Energy Institute, Inc.; and the National Mining Association versus Environmental Protection AgencY,49 PP., available on the lnternet at:2603 and at united states Environmental Protection Agency, september, 1986, RCRA Ground-water Monitoring Technical Enforcement Guidance Document, Office of Solid Waste and Emergency Response, OSWER-9950.1, 208 pp', 3 appendices' United States Environmental Protection Agency, February, 1989, "statistical Analysis of Ground-Water Monitoring Data at RCRA Facilities, Interim Final Guidance", Office of Solid Waste, aPProximatelY 146 PP' United States Environmental Protection Agency, Jarntary,1995, "Technical Resource Document Extraction and Beneficiation of Ores and Minerals Volume 5 Uranium", EPA 530-R-94- 032,74 PP., 3 aPPendices. United States Environmental Protection Agency, Region 8, August 24,1999, "Toxicity of Tetrahydrofirran", unpublished agency memo from Robert Benson, Ph.D- to Loren Morton, Utah DEQ, I P., 2 attachments. United States Environmental Protection Agency, January 4,2}O},technical correspondence letter from Mr. Robert Benson, EpA Region 8 drinking water program toxicologist to Loren Morton, Utah Division of Radiation Control,2 pp' United States Environmental Protection Agency, Summer,2002 "Drinking Water Standards and Health Advisories", EPA 822-R-02-038,12 pp., available on the Intemet at United States Environmental Protection Agency, Regron 8, May 29,2003, "Lifetime Health Advisory and Cancer Risk for Chloroform", unpublished agency memorandum from Robert Benson, Ph.D. to Loren Morton, Utah DEQ ,2 pp' United States Nuclear Regulatory Commission, May, 1979, "Final Environmental Statement Related to Operat[n of White Mesa Uranium Project Energy Fuels Nuclear, fnc., Docket 54 I I t T t I t T I I I I I I I I I l1 t1 i t I I i i i I t t t t t t t J t i i Statement of Basis DRAFT December 1,2004 No. 40-8681", NUREG-0556, Office of Nuclear Material Safety and Safeguards, approximately 290 pp. United States Nuclear Regulatory Commission, September, 1980, "Final Generic Environmental Impact Statement on Uranium Milling Project M-25, Appendices G-V", NUREG-0706, Vol. III, Office of Nuclear Material Safety and Safeguards, approximately 238 pp. United States Nuclear Regulatory Commission, September 23,2002, "Source Material License No. SUA-I358, Docket No. 040-8681, Amendment No. 22", agency license to International Uranium Corporation for Uranium Mill at White Mesa, Utah, 1I pp. United States Nuclear Regulatory Commission, March 7,2003, "Response to Questions in January 14,2003 Letter from William Sinclair", agency response letter from Paul H. Lohaus to William J. Sinclair, 3 pp. Utah Department of Environmental Quality, July 18, 1996, "lnformation Needs Summary for Atlas Corporation Moab Uranium Mill Ground Water Contaminant Investigation Report and Ground Water Corrective Action Plan, as found in the Utah Ground Water Quality Protection Regulations (UAC R317-6-6.1 5),24 pp., found as an attachment to a September 12,1996 Utah Division of Radiation Control letter from William J. Sinclair and Don A. Ostler to Richard E. Blubaugh, 6 pp. Utah Division of Radiation Control, February 7, 2000, "Muy, 1999 ruC Groundwater Information Report: DRC Request for Additional tnformation Related to Site Hydrogeology'', unpublished agency request, 2 pp. transmittal leffer, includes Utah Division of Radiation Control technical information request of February 7, 2000 "Request for Additional lnformation Related to Site Hydrogeolo1t'', 18 pp., 2 attachments. Utah Division of Radiation Control, J:urire 27,2000, "International Uranium Corporation White Mesa Uranium Tailings Facility: Engineering Design and As-Built Reports; Staff Findings, Conclusions, and Recommendations", unpublished agency technical memorandum, 29 pp., 5 attachments. Utah Division of Radiation Control, March 20,200l, "September 8, 2000 IUC Revised Groundwater Information Report: Ground Water Discharge Permit Application for White Mesa Mill: Request for Additional Site Hydrogeology Information", unpublished agency request for information, 10 pp., 3 attachments. Utah Division of Radiation Control, June 7, 200I, "October 4,2000IUC and HGC Investigation of Elevated Chloroform Concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah: August 23,1999 Utah Division of Water Quality Notice of Violation and Groundwater Corrective Action Order; Docket No. UGW20-01: Request for Additional Information.", unpublished agency information request, 12 pp., 8 attachments. Utah Division of Radiation Control, october 26, 200l, "September 21, 2001NRC Draft Environmental Assessment Regarding Maywood New Jersey FUSRAP Site: IUC White 55 Statement of Basis DRAFT December 1,2004 Mesa Uranium Mill Near Blanding, LJtah", unpublished agency comment letter from William J. Sinclair to Melvyn Leach, U.S. NRC, 5 pp. Utah Division of Radiation Control, November 15, 2001, o'Recent Meetings and Conference Call with tnternational Uranium Corporation Regarding Hydrogeologic Conditions at White MesaMill, October4, 18, and24,2001-,unpublishedagencytechnicalmemorandum, 16 pp., 3 attachments. Utah Division of Radiation Control, April I l,2002,"November 9,2001IUC Update Report on Ongoing Chloroform Investigation at White Mesa Uranium Mill; AugustZ3,1999 Division of Water Quality Notice of Violation and Groundwater Corrective Action Order, Docket No. UGW20-01: Request for Additional Information", unpublished agency information request, 18 pp., 5 attachments. Utah Division of Radiation Control, July 3, 2002, "IUC: 5/31102 Tailings Pond Wastewater Sampling Workplan - DRC Comments", unpublished agency comments, email transmittal from Loren Morton to Harold Roberts, 2 pp. Utah Division of Radiation Control, November 22,2002, 'November, 2001 Groundwater Split Sampling Event at IUC White Mesa Uranium Mill Near Blanding, Utah: Utah DEQ Request for Additional Information", unpublished agency information request, 4 pp.,7 attachments. Utah Division of Radiation Control, April 30,2003, "November,2}0l Split Sampling Event at IUC White Mesa Uranium Mill: DRC Staff Review and Conclusions", unpublished agency memorandum report, 44 pp.,7 tables, 29 attachments. Utah Division of Radiation Control, September 16,2003, "December 20,2002IUC Response Regarding Recent Detection of Tetrahydrofuran Concentrations in Groundwater at the White Mesa Uranium Mill: Request for Work Plan", unpublished agency information request, 3 pp., 2 attachments. Utah Division of Radiation Control, November 12,2003, "October 17 ,2003 IUC Response to September 16,2003 DRC Request for Work Plan; THF Contamination of Several Monitoring Wells at White Mesa Uranium Mill: Request for Work Plan", 5 pp, 5 attachments. Utah Division of Radiation Control, November 26,2003, "IUC: Groundwater Protection Level Statistics and Accelerated Monitoring Frequency'', email correspondence from Loren Morton to David Frydenlund,2PP. Utah Division of Radiation Control, September 2l,2004, "Review of IUC Report - 'Site Hydrogeology and Estimation of Groundwater Travel Times in the Perched Zone White Mesa Uranium Mill Site Near Blanding, Utah', January 30, 2003 by Hydro Geo Chem, Inc.", unpublished agency technical memorandum, 6 PP., 4 figures, 7 tables. Utah Division of Radiation Control, November 23,2004, "Review of Hydro Geo Chem Inc Report - Report on Perched Zone Water Movement, White Mesa Uranium Mill Site Near 56 T I I T I I I T I li Il ll I i i I I i I I t I t I II t II II I i t i Statement of Basis DRAFT December 1,2004 Blanding, Utah, October 20,2004", unpublished agency technical memorandum , 4 pp.,2 tables, 5 figures. Utah Division of Water Quality, August 8,1994, "Basis for Revised Ground Water Protection Levels: New Parameters and Revised Shallow Ground Water Quality Statistics", unpublished staff report, 39 pp., 23 attachments. Utah Division of Water Quality, August 23,1999, 'Notice of Violation and Groundwater Corrective Action Order; Docket No. UGW20-01: Request for Additional Information.", unpublished agency order and information request,12 pp., 8 attachments. Utah Division of Water Quality, June 12, 2003, "Chloroform Standard for White Mesa Mill Corrective Action", unpublished agency memorandum from Don Ostler to Bill Sinclair, I p. Utah Division of Water Quality, September 16,2003, "December 20,2002IUC Response Regarding Recent Detection of Tetrahydrofuran Concentrations in Groundwater at the White Mesa Uranium Mill: Request for Work Plan", unpublished agency information request from William J. Sinclair to Harold Roberts, 3 pp., 2 attachments. Ute Mountain Ute Tribe, July l, 2003, "White Mesa Seep Sampling", unpublished tribal email from Scott Clow to Loren Morton, 2 pp. DRAFT ATTACHMENT 1 Utah Division of Radiation Control Water Table Contour MaPs For the September,2002 Split Sampling Event At the IUC White Mesa Uranium Mill Near Blanding Utah. DRC Surfer Maps: 9-02h.srf,9-02h-b.sd and 9-02h-c.srf, and DRC spreadsheet GWHEAD.XLS, tabsheet 9-02 DRAFT ATTACHMENT 2 Utah Division of Radiation Control Summary of Shallow Aquifer TDS Concentrations At the IUC White Mesa Uranium Mill Near Blanding Utah. DRC Spreadsheet GWclass.xls, tabsheets Sum, HistSum, and HistSumELI DRAFT ATTACHMENT 3 Utah Division of Radiation Control Summary of IUC Wells and Parameters That Exceed their Respective GWQS At the IUC White Mesa Uranium Mill Near Blanding Utah. (based on DRC/IUC split sampling results) DRC spreadsheet GWclass.xls, tabsheet Exceed DRAFTi I i I i t t t I i t a t t I I t t t ATTACHMENT 4 Utah Division of Radiation Control Time Series Concentration Graphs of Natural Uranium Contamination in IUC White Mesa Mill Groundwater Monitoring Wells MW-14, MW-I5, andMW-17 From August 31,2004IUC Semi-Annual Effluent Monitoring Report, Groundwater Statistical Analysis by Shewhart-Cusum Method June 30, 2004 Section DRAFT ATTACHMENT 5 Utah Division of Radiation Conhol Shallow Aquifer Uranium 238 Isoconcentration Map For the September,2002 Groundwater Split Sampling Event at the IUC White Mesa Uranium Mill Facility Near Blanding, Utah DRC Surfer Contour Maps: U238-9-02.srf and U238-9-02b.srf DRC Excel spreadsheet U-238.x1s, tabsheet 9-02 II II I i i It i II t t t II * Ii t i i i DRAFT ATTACHMENT 6 Utah Division of Radiation Control Summary of IUC Tailings Cells Historic Wastewater Quality Data From the White Mesa Uranium Mill Near Blanding Utah. DRC spreadsheet TailsWQ.xls, tabsheet NewSum DRAFT ATTACHMENT 7 Utah Division of Radiation Control Summary of Literature Values for Soil-Water Partitioning (K6) Coefficients for Metals DRC spreadsheet I lE2KdSum.xls Tabsheet: Metals i a t i i J I t I J i I * I I II i i i DRAFT ATTACHMENT 8 Utah Division of Radiation Control Summary of Literature Values for Organic Carbon Partitioning Coefficients (K*) Soil-Water Partitioning (Ka) Coefficients for Organics DRC spreadsheet 1 lE2KdSum.xls Tabsheet: Org-Koc DRAFT ATTACHMENT 9 Utah Division of Radiation Control Summary of Detectable Organic Contaminants Found in Utah DRC Split Groundwater Samples Colleted from the IUC White Mesa Uranium Mill Site From MaY, 1999 thru SePtember,200? DRC spreadsheet Splitsum.xls Tabsheet: Organics I I I I I I I I I I I I t I I !r tl DRAFT ATTACHMENT 10 Utah Division of Radiation Control Summary of Groundwater Quality Split Sampling Results For Selected Volatile Organic Contaminants From the IUC White Mesa Uranium Mill, May, 1999 thru Septemb er, 2002 DRC spreadsheets: Benzene.xls, CTC.xls, and THF.xls Tabsheets: HistSum DRAFT I t I I I I I I I t T t I I I I I I I ATTACHMENT 11 April 16,2004 Proposed Groundwater Monitoring Well Location Map Received by the Utah Division of Radiation Control On April 20,2004 I T I 1 i I i i it I'l I I I I I ! 1 I t rlI i Iti DRAFT ATTACHMENT 12 Utah Division of Radiation Control Groundwater Velocity Contour Map (based on IUC velocity data) From November 23,2004 Utah Division of Radiation Control Memorandum, Figure 2