DERR-2025-000887

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DRAFT FINAL
SITE ST071
CORRECTIVE ACTION PLAN ADDENDUM
FOR
HILL AIR FORCE BASE, UTAH
Contract No. W91238-20-C-0014
CLIN: 0031
Prepared for: 12
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Prepared by: 15
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HGL-APTIM Joint Venture Team 17
11107 Sunset Hills Road 18
Suite 400 19
Reston, Virginia 20190 20
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January 2025 25
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DRAFT FINAL
SITE ST071
CORRECTIVE ACTION PLAN ADDENDUM
FOR
HILL AIR FORCE BASE, UTAH
Contract No. W91238-20-C-0014
CLIN: 0031

January 2025 38
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Prepared by:
Gavin Kellough,
Primary Author/Geologist II
Date
Reviewed/
Approved by:
Mark L. Finney, P.G.
ST071 Project Manager Date
Reviewed/
Approved by:
Dave Reasons, PMP
Program Manager
Date
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TABLE OF CONTENTS
Section Page
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 i January 2025
1.0 INTRODUCTION ........................................................................................................... 1-1 44
1.1 PURPOSE OF THE CORRECTIVE ACTION PLAN ....................................... 1-1 45
1.2 CORRECTIVE ACTION PLAN ADDENDUM ORGANIZATION ................. 1-2 46
2.0 SITE DESCRIPTION AND HISTORY .......................................................................... 2-1 47
2.1 SITE LOCATION AND DESCRIPTION ........................................................... 2-1 48
2.2 BACKGROUND INFORMATION AND HISTORY ........................................ 2-1 49
2.3 SITE GEOLOGY AND HYDROLOGY ............................................................. 2-2 50
2.4 KNOWN OR SUSPECTED CONTAMINANTS OR CLASSES OF 51
CONTAMINANTS.............................................................................................. 2-3 52
2.5 NATURE AND EXTENT OF CONTAMINATION AT TIME OF 53
CLOSURE ........................................................................................................... 2-3 54
2.5.1 Soil Contamination .................................................................................. 2-3 55
2.5.2 Groundwater Contamination .................................................................... 2-3 56
2.6 EXPOSURE ASSESSMENT .............................................................................. 2-4 57
2.7 APRIL AND MAY 2022 SUPPLEMENTAL SITE INVESTIGATION............ 2-4 58
2.7.1 SOIL SAMPLING AND ANALYSIS ..................................................... 2-5 59
2.7.1.1 Soil Volatile Organic Compounds (EPA Method 8260B) ........... 2-6 60
2.7.1.2 Soil Total Petroleum Hydrocarbons – Diesel and Gasoline Range 61
Organics ....................................................................................... 2-6 62
2.7.2 Groundwater Sampling and Analysis ...................................................... 2-6 63
2.7.2.1 Groundwater Volatile Organic Compounds 64
(EPA Method 8260B) .................................................................. 2-7 65
2.7.2.2 Groundwater Total Petroleum Hydrocarbons – Diesel and Gasoline 66
Range Organics ............................................................................ 2-7 67
2.7.3 Investigation-Derived Waste Management.............................................. 2-7 68
2.8 2022 SUPPLEMENTAL SITE INVESTIGATION SUMMARY ...................... 2-8 69
2.9 2022 SUPPLEMENTAL SITE INVESTIGATION CONCLUSIONS ............... 2-8 70
3.0 2023 SOURCE AREA AND LNAPL INVESTIGATION ............................................. 3-1 71
3.1 HIGH RESOLUTION SITE CHARACTERIZATION....................................... 3-2 72
3.1.1 High Resolution Site Logging ................................................................. 3-2 73
3.1.2 Confirmation Soil Samples ...................................................................... 3-3 74
3.1.3 Volatile Organic Constituents (EPA Method 8260B) ............................. 3-3 75
3.1.4 Total Petroleum Hydrocarbons – Diesel and Gasoline Range 76
Organics ................................................................................................... 3-3 77
3.1.5 Confirmation Groundwater Samples ....................................................... 3-4 78
3.1.6 Volatile Organic Constituents (EPA Method 8260D) ............................. 3-4 79
3.1.7 Total Petroleum Hydrocarbons – Diesel and Gasoline Range 80
Organics ................................................................................................... 3-5 81
3.2 MONITORING WELL INSTALLATION .......................................................... 3-5 82
3.3 GROUNDWATER MONITORING ................................................................... 3-6 83
3.3.1 Monitoring Well Gauging ........................................................................ 3-6 84
3.3.2 Geochemical Parameters .......................................................................... 3-7 85
3.3.3 Volatile Organic Constituents (EPA Method 8260B) ............................. 3-7 86
TABLE OF CONTENTS (Continued)
Section Page
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 ii January 2025
3.3.4 Total Petroleum Hydrocarbons –Diesel and Gasoline Range87
Organics ................................................................................................... 3-7 88
3.4 CURRENT EXTENT OF CONTAMINATION ................................................. 3-7 89
3.4.1 Soil Contamination .................................................................................. 3-8 90
3.4.2 Dissolved-Phase Groundwater Plume...................................................... 3-8 91
3.4.3 Conclusions .............................................................................................. 3-9 92
4.0 CORRECTIVE ACTION ALTERNATIVES AND SELECTION ................................. 4-1 93
4.1 CORRECTIVE ACTION OBJECTIVES ............................................................ 4-1 94
4.2 VADOSE ZONE .................................................................................................. 4-1 95
4.2.1 Surfactant Enhanced Remediation ........................................................... 4-1 96
4.2.2 Active Bioventing .................................................................................... 4-2 97
4.3 GROUNDWATER .............................................................................................. 4-3 98
4.3.1 Baseline Groundwater Monitoring .......................................................... 4-3 99
4.3.2 In Situ Activated Carbon ......................................................................... 4-4 100
4.3.3 Monitored Natural Attenuation ................................................................ 4-4 101
4.3.4 Performance Groundwater Monitoring Program ..................................... 4-4 102
4.3.5 Land Use Controls ................................................................................... 4-5 103
5.0 CORRECTIVE ACTION IMPLEMENTATION ........................................................... 5-1 104
5.1 FIELD IMPLEMENTATION APPROACH ....................................................... 5-1 105
5.2 SITE PREPARATION......................................................................................... 5-1 106
5.2.1 Underground Utilities .............................................................................. 5-1 107
5.2.2 Permits ..................................................................................................... 5-1 108
5.3 GROUNDWATER MONITORING ................................................................... 5-1 109
5.4 INSTALLATION OF BIOVENT TREATMENT SYSTEM .............................. 5-2 110
5.4.1 Remediation Well Installation ................................................................. 5-2 111
5.4.1.1 Location and Spacing ................................................................... 5-3 112
5.4.1.2 Drilling and Installation Procedures ............................................ 5-3 113
5.4.1.3 Well Completion .......................................................................... 5-4 114
5.4.2 SVE Components ..................................................................................... 5-4 115
5.4.3 Biovent Components ................................................................................ 5-4 116
5.4.4 Control Panel ........................................................................................... 5-5 117
5.4.5 Enclosure.................................................................................................. 5-5 118
5.4.6 Piping/Trenching...................................................................................... 5-5 119
5.4.7 Electrical .................................................................................................. 5-6 120
5.5 VAPOR PERFORMANCE MONITORING ....................................................... 5-6 121
5.5.1 Respiration Tests ...................................................................................... 5-6 122
5.5.2 Air Permit Testing.................................................................................... 5-6 123
5.5.3 Startup and Performance Monitoring....................................................... 5-7 124
5.6 OPERATION AND MAINTENANCE ............................................................... 5-7 125
5.6.1 Startup Procedure ..................................................................................... 5-7 126
5.6.2 Operation and Maintenance Activities..................................................... 5-8 127
5.7 SITE CLOSURE CRITERIA .............................................................................. 5-9 128
5.8 SITE RESTORATION ........................................................................................ 5-9 129
TABLE OF CONTENTS (Continued)
Section Page
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 iii January 2025
5.9 SCHEDULE ....................................................................................................... 5-10 130
5.10 REPORTING ..................................................................................................... 5-10 131
6.0 PUBLIC NOTICE............................................................................................................ 6-1 132
7.0 REFERENCES ................................................................................................................ 7-1 133
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LIST OF TABLES
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 v January 2025
Table 2.1 Historical Soil Summary from UST Site 914 136
Table 2.2 Free Product Removal from Monitoring Wells at UST Site 914 – 2003-2008 137
Table 2.3 Free Product Levels from UST Site 914 – 2009 138
Table 2.4 UST Site 914 Groundwater Data Summary – 2000-2008 139
Table 2.5 Detected Compounds in Subsurface Soil – SSI April/May 2022 140
Table 2.6 Detected Compounds in Groundwater – SSI April 2022 141
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Table 3.1 Field Screening Data Summary – July 2023 143
Table 3.2 Soil Analytical Results – July 2023 144
Table 3.3 Discrete Groundwater Analytical Results – July 2023 145
Table 3.4 Monitoring Well Construction Summary 146
Table 3.5 Groundwater Field Parameters – November 2023 147
Table 3.6 Groundwater Geochemical Parameters – November 2023 148
Table 3.7 Groundwater Analytical Results – November 2023 149
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LIST OF FIGURES 153
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Figure 2.1 Hill Air Force Base Location Map 156
Figure 2.2 UST Site 914 Overview Map 157
Figure 2.3 Soil Boring and Cross Section Locations 158
Figure 2.4 Cross Section A-A’ 159
Figure 2.5 Cross Section B-B’ 160
Figure 2.6 Historical Free Product Plumes 161
Figure 2.7 2022 SSI Sample Locations 162
Figure 2.8 Soil COC Concentration Map, April/May 2022 163
Figure 2.9 Groundwater COC Concentration Map, April 2022 164
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Figure 3.1 Soil Analytical Results, July 2023 166
Figure 3.2 Discrete Groundwater Analytical Results, July 2023 167
Figure 3.3 Groundwater Elevations, November 2023 168
Figure 3.4 Groundwater COC Concentration Map, November 2023 169
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Figure 4.1 Cross Section Location Map 171
Figure 4.2 Cross Section A-A’ 172
Figure 4.3 Cross Section B-B’ 173
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Figure 5.1 Remediation System Layout 175
Figure 5.2 SVE Process Flow Diagram 176
Figure 5.3 Biovent Process Flow Diagram 177
Figure 5.4 Remediation Well Details (SVE and Biovent) 178
Figure 5.5 Pipe Trench Details 179
Figure 5.6 Biovent Treatment Zone180
LIST OF APPENDICES
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 v January 2025
Appendix A Historical Data 181
Appendix B Field Documentation 182
B.1 Calibration Forms 183
B.2 Groundwater Sample Collection Forms 184
B.3 Logbook 185
B.4 Boring Logs/Well Construction Diagrams 186
B.5 Surve 187
Appendix C OIP/HPT/EC Logs 188
Appendix D Laboratory Analytical Reports 189
Appendix E Laboratory Data Validation 190
E.1 Laboratory Data Validation Reports 191
E.2 Laboratory Quality Evaluation Reports 192
Appendix F Waste Disposal 193
Appendix G Responses to Regulators Comments 194
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LIST OF ACRONYMS AND ABBREVIATIONS
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 vi January 2025
% percent 196
hp horsepower 197
µg/kg micrograms per kilogram 198
µg/L micrograms per liter 199
mg/kg milligram per kilogram 200
scfm standard cubic feet per minute 201
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AFB Air Force Base 203
amsl above mean sea level 204
APTIM APTIM Federal Services, LLC 205
AST aboveground storage tank 206
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bgs below ground surface 208
BTEX benzene, toluene, ethylbenzene, and xylene 209
BTEXN benzene, toluene, ethylbenzene, xylene, and naphthalene 210
bTOC below top of casing 211
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CAP Corrective Action Plan 213
COC contaminant of concern 214
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DERR Division of Environmental Response and Remediation 216
DO dissolved oxygen 217
DoD ELAP Department of Defense Environmental Laboratory Accreditation Program 218
DPT direct push technology 219
DRO diesel range organic 220
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EC electrical conductivity 222
EPA U.S. Environmental Protection Agency 223
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GPS global positioning system 225
GRO gasoline range organic 226
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HAFB Hill Air Force Base 228
HGL HydroGeoLogic, Inc. 229
HGL-APTIM JV HydroGeoLogic, Inc.-APTIM Federal Services, LLC Joint Venture 230
HPT hydraulic profiling tool 231
HRSC high resolution site characterization 232
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ID identification 234
IDW investigation-derived waste 235
ISL initial screening levels 236
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JP-4 jet propulsion fuel, type 4 238
JV joint venture 239
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LNAPL light non-aqueous phase liquid 241
LIST OF ACRONYMS AND ABBREVIATIONS (Continued)
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 vii January 2025
LUC land use controls 242
LUST Leaking Underground Storage Tank Section 243
MNA monitored natural attenuation 244
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NEC National Electrical Code 246
NFA No Further Action 247
OIP optical image profiler 248
ORC Optimized Remediation Contract 249
ORP oxidation-reduction potential 250
OVM organic vapor meter 251
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PAH polynuclear aromatic hydrocarbons 253
PID photoionization detector 254
POL petroleum, oil, lubricant 255
psi pounds per square inch 256
PVC polyvinyl chloride 257
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QAPP Quality Assurance Project Plan 259
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RBCA Risk-Based Corrective Action 261
RPM remedial project manager 262
RSL Regional Screening Level 263
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SER surfactant enhanced remediation 265
SOP Standard Operating Procedure 266
SSI supplemental site investigation 267
SVE soil vapor extraction 268
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TPH total petroleum hydrocarbon 270
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UDEQ Utah Department of Environmental Quality 272
UE unrestricted exposure 273
UFP Uniform Federal Policy 274
UST underground storage tank 275
UU unlimited use 276
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VOC volatile organic compound 278
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 1-1 January 2025
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DRAFT FINAL
SITE ST071
CORRECTIVE ACTION PLAN ADDENDUM
FOR
HILL AIR FORCE BASE, UTAH 283
1.0 INTRODUCTION 284
This Corrective Action Plan (CAP) Addendum for Site ST071 at Hill Air Force Base (HAFB) has 285
been prepared by HydroGeoLogic, Inc. (HGL) and APTIM Federal Services, LLC (APTIM) Joint 286
Venture (HGL-APTIM JV) under the U.S. Army Corps of Engineers-Sacramento District 287
Optimized Remediation Contract (ORC) Contract Number W91238-20-C-0014. 288
Site ST071 is regulated by the Utah Department of Environmental Quality (UDEQ), Division of 289
Environmental Response and Remediation (DERR), Leaking Underground Storage Tank (LUST) 290
Section and is referred to as Underground Storage Tank (UST) Site 914 and identified as Facility 291
ID 3000212 with associated Release IDs EHVC and ELXI. In 2010, UDEQ-DERR authorized no 292
further action (NFA) with land use controls (LUCs) for UST Site 914, closing the site in the LUST 293
program. Under the ORC, it is the U.S. Air Force’s objective to reopen UST Site 914 and remove 294
the LUCs to achieve unlimited use/unrestricted exposure (UU/UE). The results of the 295
Supplemental Site Investigation (SSI) were used as the basis for reopening the site for further 296
remedial action with oversight from the UDEQ-DERR LUST program. Please note that throughout 297
this document Site ST071 will be referred to as “UST Site 914,” unless otherwise defined. 298
1.1 PURPOSE OF THE CORRECTIVE ACTION PLAN 299
Results of the limited SSI activities performed in April and May 2022 indicated that continued 300
dissolved-phase contamination of the upper aquifer and residual contamination in the smear zone 301
still exist. Total petroleum hydrocarbons (TPH)-diesel range organics (DRO) and TPH-gasoline 302
range organics (GRO) were detected at concentrations above the November 1, 2005, UDEQ-303
DERR initial screening levels (ISLs) in the soil. Implementation of a corrective action is required 304
to remove the residual contamination and maintain groundwater concentrations below ISLs to 305
remove LUCs. Additional site information related to the extent of light non-aqueous phase liquid 306
(LNAPL) and geochemical parameters were collected to evaluate and design a corrective action 307
as outlined in the 2023 CAP (HGL-APTIM JV, 2023). Previously implemented corrective actions 308
have consisted of bioventing, monitored natural attenuation (MNA) of the dissolved-phase 309
groundwater plume, and periodic free product collection. 310
This CAP Addendum summarizes data collected in 2023 and describes remedy selection, design, 311
and implementation activities to achieve final site closure, including removal of LUCs and 312
attainment of UU/UE at UST Site 914. Investigation activities conducted in 2023 complied with 313
all UDEQ regulations that apply to LUSTs. In accordance with state of Utah regulations, work was 314
performed under the guidance and direction of a Utah-certified underground storage tank (UST) 315
consultant provided by teaming partner Wasatch Environmental, Inc. The HGL-APTIM JV 316
complied with all substantive permit requirements for on-site work. The HGL-APTIM JV 317
coordinated with the U.S. Air Force prior to initiating field activities. 318
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 1-2 January 2025
1.2 CORRECTIVE ACTION PLAN ADDENDUM ORGANIZATION 319
This CAP Addendum is organized into the following sections: 320
• Section 1.0 – Introduction: Presents a description of the objectives and organization of 321
the CAP. 322
• Section 2.0 – Site Description and History: Presents a description of site physical features 323
and the current nature and extent of contamination, including the results of the SSI 324
conducted in January 2022. 325
• Section 3.0 – 2023 Source Area and LNAPL Investigation: Presents the results of the 326
source area and LNAPL investigation conducted in June, July, and November 2023. 327
• Section 4.0 – Corrective Action Alternatives and Selection: Presents a description and 328
evaluation of selected corrective action alternatives. 329
• Section 5.0 – Corrective Action Implementation: Presents a description of the corrective 330
action alternative implementation activities. 331
• Section 6.0 – Public Notice: This section describes the public notification plans for 332
changes to the corrective action at UST Site 914. 333
• Section 7.0 – References: Provides a list of references cited in this CAP Addendum.334
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 2-1 January 2025
2.0 SITE DESCRIPTION AND HISTORY 335
The following subsections provide a summary of the site history, geology and hydrology, 336
contaminants of concern (COCs) and a summary of the 2022 SSI. 337
2.1 SITE LOCATION AND DESCRIPTION 338
HAFB is located in northern Utah, approximately 25 miles north of Salt Lake City and about 339
5 miles south of Ogden. The installation occupies approximately 6,700 acres in Davis and Weber 340
counties. HAFB is bounded on the west by Interstate 15 and the Davis-Weber Canal, and on the 341
east by private property (Figure 2.1). UST Site 914 is located in the southwest portion of the Base 342
in one of the primary jet fuel storage and dispensing facilities at HAFB. The fuel storage system 343
consists of four 25,000-gallon-capacity jet fuel aboveground storage tanks (ASTs) designated 344
910AFT through 910DFT, and one 1,000-gallon UST that contains water filtered from the jet fuel. 345
The site is paved with asphalt and is located in a high-security controlled area. The layout of UST 346
Site 914 with September 2007 groundwater contours are shown in Figure 2.2. (Ogden Air Logistics 347
Center, 1994). 348
2.2 BACKGROUND INFORMATION AND HISTORY 349
The source of contamination at UST Site 914 included multiple historic fuel spills and leaks 350
associated with jet propulsion fuel, type 4 (JP-4) and possibly gasoline tanks and piping. A 27,000-351
gallon release of JP-4 was documented in 1985, and a number of smaller releases occurred between 352
1992 and 1996 (CH2M Hill, 2008b). A site investigation was conducted in 1993 following closure 353
and removal of UST 914.6, a 500-gallon UST that was removed on October 1, 1992. The 354
investigation revealed free product and dissolved-phase contamination in the former tank area. 355
Based on the investigation, a CAP for UST Site 914 was approved in 1994. The CAP 356
recommended bioventing for vadose zone contamination and free product recovery using a 357
skimmer pump (MW, 1994). 358
A soil vapor extraction (SVE) system was installed in 1998 for the purpose of remediating the 359
hydrocarbon contamination at the site. The SVE system was an alternative to bioventing based 360
on pilot testing performed in 1994 and 1995 and was operated until November 2001, when it was 361
shut down to conduct a soil investigation. The results of the investigation showed that benzene, 362
toluene, ethylbenzene, xylene, and naphthalene (BTEXN) and TPH concentrations in soil had 363
been reduced below the UDEQ-DERR Risk-Based Corrective Action (RBCA) Tier 1 screening 364
levels. Based on the investigation results, a new CAP was submitted and approved in 2002. The 365
CAP recommended free product monitoring, free product removal using absorbent pads, and 366
groundwater monitoring until a change in site conditions warranted additional remedial actions 367
or a recommendation for site closure (CH2M Hill, 2002). 368
After the 2002 CAP was implemented, gasoline was discovered and the free product removed from 369
two monitoring wells (T-914-PTW1 and T-914-203) during the 2004 summer sampling round 370
(CH2M Hill, 2005a). This discovery indicated a previously unidentified source, and a new Release 371
Site number, ELXI, was assigned to the site by UDEQ-DERR. Another soil investigation was 372
conducted in December 2004 and January 2005 to evaluate the source of the gasoline. A total of 373
13 samples were collected from 8 soil borings. An organic vapor meter (OVM) was used to screen 374
the core samples to provide preliminary qualitative data to aid in determining the extent of the 375
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 2-2 January 2025
contamination. The results of the soil borings and OVM readings indicated no evidence of a recent 376
release of gasoline or any other type of fuel (CH2M Hill, 2005b). Based on the results of the 377
investigation, CH2M Hill concluded that the source of the gasoline was a release that occurred 378
during the 1990s and recommended that management of the site continue under the CAP for site 379
EHVC. 380
Continued groundwater monitoring and free product removal occurred at UST Site 914 from 2005 381
to 2007. Free product levels continued to decline, and no detections of contaminants above Tier 1 382
screening levels have been observed in the perched water table or the deeper underlying aquifer 383
since 1999. A free product sheen was detected in three monitoring wells in 2007 (T -914-PTW1, 384
T-914-203, and T-914-006), but there was not enough free product to remove (CH2M Hill, 2008a).385
In 2008, a letter report was submitted to UDEQ-DERR requesting closure of the UST Site 914, 386
Release IDs EHVC and ELXI (CH2M Hill, 2008b). UDEQ-DERR authorized NFA for the site in 387
2010, conditional upon adherence to the LUC institutional controls detailed in the Hill Air Force 388
Base Land Use Control Dynamic Document referenced in the NFA letter dated 02 March 2010 389
(UDEQ, 2010). The LUCs consisted of limited access to the site, shallow groundwater rights 390
restrictions, and construction activity restrictions to prevent exposure to the residual contamination 391
remaining on the site. 392
2.3 SITE GEOLOGY AND HYDROLOGY 393
UST Site 914 soil from approximately 0 to 25 feet below ground surface (bgs) is composed 394
primarily of coarse-grained Provo formation deposits (sands) with areas of interbedded clay layers 395
(CH2M Hill, 2005b). Below 25 feet, the lithology becomes a complex heterogeneous sequence of 396
alternating clay layers and sand lenses of varying thicknesses. Between the north and south ends 397
of the site, a marked change in the thickness and distribution of sand-clay sequences occurs. On 398
the north side of the site, a homogeneous poorly graded sand approximately 4-feet thick is bounded 399
above and below by homogeneous clay layers ranging in thickness from 5 to 14 inches. Toward 400
the south end of the site, this interval changes from relatively discrete homogeneous sand and clay 401
units to a highly heterogeneous sequence of interbedded sand and clay units of varying thicknesses 402
(CH2M Hill, 2002). Geologic cross sections of the site from the 2005 Subsurface Investigation 403
Report (CH2M Hill, 2005b) are presented in Figures 2.3, 2.4, and 2.5 for reference. 404
A perched water table is present at approximately 26 feet bgs and is separated from a lower aquifer 405
by a clay-rich confining layer (CH2M Hill, 2002). The lower aquifer has been identified at a depth 406
of approximately 46 feet bgs. Groundwater is estimated to flow from the northeast to the southwest 407
based on groundwater elevation data collected from the site (Figure 2.2). Downward migration of 408
the groundwater appears to be restricted by the clay layers of the Alpine Formation (CH2M Hill, 409
2005b). During the last groundwater monitoring event in 2008, the depth to groundwater ranged 410
from 25.87 feet bgs (4,743.00 feet above mean sea level [amsl]) (T-914-MW1) in the perched 411
aquifer to the east to 53.05 feet bgs (4,659.00 feet amsl) (T-914-016) in the lower aquifer to the 412
west (T-914-016), north of Building 911 (CH2M Hill, 2010). 413
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 2-3 January 2025
2.4 KNOWN OR SUSPECTED CONTAMINANTS OR CLASSES OF 414
CONTAMINANTS 415
A series of releases have been reported from the UST/AST system at UST Site 914 since the mid-416
1980s. In 1985, a 27,000-gallon release of JP-4 occurred when an automatic overflow device 417
failed. The replacement of the 500-gallon UST in 1992 revealed elevated concentrations of TPH 418
and benzene, toluene, ethylbenzene, and xylene (BTEX) compounds in the soil due to tank 419
leakage. Several smaller releases occurred from 1992 to 1996. These releases are considered to be 420
the source of contamination at the site. The LNAPL may potentially act as a continuing source of 421
dissolved contamination to underlying groundwater. The primary COCs at UST Site 914consist of 422
TPH (GRO and DRO) and the volatile organic compounds (VOCs) BTEXN (MW, 1994). 423
2.5 NATURE AND EXTENT OF CONTAMINATION AT TIME OF CLOSURE 424
This section summarizes the nature and extent of petroleum contamination at UST Site 914. Unless 425
otherwise noted, information presented in this section was obtained from the 2008 Letter Report 426
for Closure of UST Site 914, Release IDs EHVC and ELXI (CH2M Hill, 2008b). Results of the 427
last quarterly free product monitoring and groundwater elevations for 2009, including data 428
summary tables, are provided in Appendix A. 429
2.5.1 Soil Contamination 430
In 1992, 74 cubic yards of soil were excavated at UST Site 914 following the removal of UST 431
914.6 owing to elevated concentrations of TPH and BTEX. An SVE system was operational from 432
1998 through 2001 for the purpose of remediating the hydrocarbon contamination in soil at the 433
site. 434
A number of soil borings have been drilled to investigate the extent of free product and vadose 435
zone contamination. The soil boring locations from pre-SVE and post-SVE soil sampling rounds 436
are presented in Figure 2.3. Table 2.1 provides a summary of the associated soil data derived from 437
the analysis of BTEXN, TPH-GRO, and TPH-DRO. As shown in Table 2.1, the only exceedances 438
of RBCA Tier 1 standards after operation of the SVE system were in the area of borings T -914-439
711 and T-914-712 at depths ranging from approximately 30 to 40 feet bgs, which is in the “smear 440
zone.” No other exceedances of BTEXN, TPH-GRO, and TPH-DRO were observed in the soil 441
samples collected following operation of the SVE system. In addition to the soil data, the OVM 442
data from the 2004 soil investigation did not indicate the presence of any type of organic vapor 443
above the smear zone at borings T-914-711 and T-914-712 (CH2M Hill, 2005b). 444
The soil data collected at UST Site 914 documents that the SVE system was successful in 445
remediating soil contamination to below Tier 1 screening levels in areas above the smear zone. 446
Some contamination in the smear zone may remain in perched areas. Based on the historical data, 447
residual contamination may be confined to an area approximately 30 feet southwest of the former 448
UST, near boring locations T-914-711 and T-914-712 (Figure 2.3). 449
2.5.2 Groundwater Contamination 450
Free product removal began at UST Site 914 in 1993. Since that time, a combination of remedial 451
activities, including bailing, mechanical free product removal using a skimmer pump, bioventing, 452
dual-phase vacuum extraction, and SVE, have been used to remove free product at the site. The 453
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 2-4 January 2025
volume of LNAPL recovered since 2003 is provided in Table 2.2. As shown in this table, free 454
product removal has steadily declined since 2004 to a point where it is no longer recoverable since 455
2007. 456
The historical extent of free product in 1994, 1999, and 2007 is shown in Figure 2.6. The 2007 457
estimate for the extent of free product is based on soil data from the 2005 investigation and 458
groundwater data from the 2007 sampling rounds. Only a free product sheen was noted in 459
monitoring wells during 2007. During the last LNAPL gauging events completed in 2009, the only 460
measurable free product was observed in well T-914-203 (Table 2.3). Neither LNAPL nor a sheen 461
were observed in any other monitoring wells in 2009 (CH2M Hill, 2010). 462
Groundwater samples were last collected at the site in 2008. Table 2.4 provides a summary of the 463
data derived from the analysis of BTEXN, TPH, and TPH-DRO. No detections of contaminants 464
above RBCA Tier 1 screening levels have been observed in the perched water table or the deeper 465
underlying aquifer since 1999. The data indicates that BTEXN and TPH contamination has been 466
limited to the upper perched aquifer and may still be located in the area immediately surrounding 467
the monitoring wells that last showed free product (T-914-203). The monitoring wells at UST Site 468
914 were abandoned in 2009. 469
2.6 EXPOSURE ASSESSMENT 470
Based on the historical soil and LNAPL gauging data collected at UST Site 914, it appears residual 471
BTEXN and TPH contamination in soil may be limited to the upper perched aquifer (at a depth of 472
approximately 30 feet bgs) in an area approximately 30 feet southwest of the former UST 914.6, 473
near 2004 boring locations T-914-711 and T-914-712 and abandoned monitoring well T-914-203. 474
Potential exposure to contaminated groundwater is highly unlikely, as the contamination is limited 475
in extent, and there are no drinking water wells within 500 feet of the site. There have been no 476
detections of hydrocarbons in downgradient monitoring wells, and detections in upgradient wells 477
have not exceeded RBCA Tier 1 screening levels since 2000 (see Table 2.4). The nearest lateral 478
municipal drinking water well is located approximately 2,000 feet southeast of UST Site 914. The 479
nearest downgradient municipal drinking water well is located over 3,000 feet southwest of UST 480
Site 914. The municipal wells draw water from a separate, lower aquifer. The only potential 481
exposure pathway identified at UST Site 914 is possible vapor intrusion through subsurface 482
utilities. The likelihood of exposure through this route is limited because the contaminated soil is 483
approximately 20 to 30 feet below these utilities (CH2M Hill, 2008b). 484
The last LNAPL gauging events completed in 2009 found measurable free product in one well, T-485
914-203, suggesting that residual LNAPL is trapped in the smear zone in the form of discontinuous486
ganglia outside of this area (CH2M Hill, 2010). Natural attenuation of the petroleum contamination487
may be ongoing at UST Site 914; therefore, the current concentrations of the contaminants in soil488
and groundwater are unknown. Because no monitoring wells remain at the site, additional soil and489
groundwater characterization must be conducted to evaluate the current extent and concentration490
of contaminants at the site.491
2.7 APRIL AND MAY 2022 SUPPLEMENTAL SITE INVESTIGATION 492
A limited SSI was conducted in April and May 2022 to evaluate the current site conditions and 493
support the evaluation and design of a CAP (HGL-APTIM JV, 2023). The limited SSI included 494
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the collection of discrete groundwater and soil samples in the vicinity of the historical LNAPL 495
footprint to assess the current extent of the dissolved-phase contamination and LNAPL. The last 496
groundwater monitoring event was conducted in 2008 and the last LNAPL gauging was completed 497
in 2009. The monitoring wells at UST Site 914 were abandoned in 2009. All limited SSI field 498
activities were conducted in accordance with the Site ST071 SSI Work Plan (HGL-APTIM JV, 499
2021b), the programmatic Accident Prevention Plan (HGL-APTIM JV, 2021a), and the HAFB 500
ORC Uniform Federal Policy (UFP) - Quality Assurance Project Plan (QAPP) (HGL-APTIM JV, 501
2022a). Investigation activities were limited to the collection of discrete groundwater and soil 502
samples using a direct push technology (DPT) rig within a grid overlain the historical LNAPL 503
footprint as depicted on Figure 2.7. Investigation activities are listed below. 504
• Collected a discrete groundwater sample (ST071GW-E2) from grid cell E2 using DPT 505
methods to assess the current extent of dissolved-phase contamination in the upper most 506
aquifer within the historical LNAPL footprint. 507
• Collected soil samples within the smear zone from grid cells A1 through F1 using DPT 508
methods to assess the current residual mass of contamination that could potentially leach 509
to groundwater and contribute to the dissolved-phase contamination in the upper most 510
aquifer within the historical LNAPL footprint. 511
• Note: The borings located in grid cells A2 through D2 and F2 were not collected due to 512
either their close location to buried utilities or proximity to the fueling station. The 513
technical sergeant prohibited drilling along the south grid locations based on active fueling 514
and truck traffic in and out of the area. 515
Results of the 2022 SSI field activities are described in greater detail in the following subsections. 516
2.7.1 SOIL SAMPLING AND ANALYSIS 517
Twelve boring locations were identified for the collection of soil and/or groundwater samples. Soil 518
borings were proposed adjacent to 2004 boring locations T-914-711 (cell F2) and T-914-712 (cell 519
D2) and abandoned monitoring well T-914-203 (cell F1) to evaluate residual LNAPL in the smear 520
zone (Figure 2.8). Access restriction prohibited sample collection at the proposed borings located 521
in cells A2 through D2 and F2, including abandoned borings T-914-711 (cell F2) and T-914-712 522
(cell D2). Cells A1 and E2 were designated for groundwater sample only; therefore, a soil sample 523
was not collected. Continuous soil cores were collected from cells B1 through F1 during sampling 524
using a DPT drill rig, logged by a geologist, and scanned with a photoionization detector (PID). 525
The borings were terminated at approximately 35 feet bgs. One soil sample was collected from 526
each boring location located in cells B1 (ST071SO-05), C1 (ST071SO-04), D1 (ST071SO-03), E1 527
(ST071SO-02), and F1 (ST071SO-01) from approximately 32 to 35 feet bgs, the interval with the 528
highest VOC concentration based on field screening measurements using a PID. A field GPS unit 529
was used to record and mark the soil boring locations during the investigation. The soil samples 530
were analyzed for BTEXN (Method 8260B) and TPH-GRO and TPH-DRO (Method 8015D). 531
Following collection, all sample containers were immediately placed on ice and shipped by 532
overnight delivery to the Arvada (Denver) facility of Eurofins Test America (a Department of 533
Defense Environmental Laboratory Accreditation Program [DoD ELAP]-certified laboratory) for 534
analysis in accordance with the UFP-QAPP. A copy of the Eurofins Test America DoD ELAP 535
laboratory scope of accreditation is included in Appendix D of the UFP-QAPP (HGL-APTIM JV, 536
2022a). 537
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Sampling equipment was decontaminated after each use and between sampling locations. The 538
investigation-derived waste (IDW), including soil cuttings, were containerized in 55-gallon drums 539
and managed in accordance with the HAFB IDW management plan. Soil VOC results are 540
presented in Figure 2.8. Analytical results are summarized on Table 2.5. 541
2.7.1.1 Soil Volatile Organic Compounds (EPA Method 8260B) 542
Ethylbenzene and total xylenes were the only VOCs detected in the soil samples at concentrations 543
that exceeded the ISLs of 5,000 and 142,000 micrograms per kilogram (µg/kg), respectively. 544
Ethylbenzene concentrations exceeded the ISL in four of the five soil samples collected ranging 545
from 1,700 J µg/kg (cell B1) to 47,000 µg/kg (cell D1). Total xylenes concentrations exceeded the 546
ISL in one of the five soil samples collected ranging from 16,000 µg/kg (cell B1) to 480,000 µg/kg 547
(cell D1). In addition, the chlorinated VOC 1,1,2-trichloroethane was detected at cell F1 (9,700 548
µg/kg) and cell C1 (10,000 µg/kg) at concentrations that exceeded the RSL for residential soil of 549
5,000 µg/kg. 550
Soil VOC results are presented in Figure 2.8. Analytical results are summarized in Table 2.5. 551
2.7.1.2 Soil Total Petroleum Hydrocarbons – Diesel and Gasoline Range Organics 552
TPH-GRO and TPH-DRO were detected in all five soil samples at concentrations that exceeded 553
the ISLs of 150 and 500 milligram per kilogram (mg/kg), respectively. TPH-GRO concentrations 554
exceeded the ISL in all five of the soil samples collected; concentrations ranged from 260 J mg/kg 555
(cell B1) to 9,600 J mg/kg (cell D1). TPH-DRO concentrations exceeded the ISL in all five of the 556
soil samples collected and ranged from 600 mg/kg (cell E1) to 2,300 J mg/kg (cell F1). 557
Soil TPH results are presented in Figure 2.8 Analytical results are summarized in Table 2.5. 558
2.7.2 Groundwater Sampling and Analysis 559
Twelve groundwater samples were proposed for collection within the historical LNAPL footprint 560
at UST Site 914 to assess the current extent of dissolved-phase contamination in the upper most 561
aquifer. However, sufficient quantities of groundwater to collect a sample were only observed at 562
one location, ST071GW-E2 (cell E2). The groundwater sample collected at cell E2 was submitted 563
for off-site laboratory analysis of the following: 564
• Select VOCs, including BTEXN, by EPA Method 8260B; and 565
• TPH-DRO and TPH-GRO by EPA Method 8015D. 566
An investigation was performed using a DPT rig to collect discrete groundwater samples to 567
evaluate the extent of current dissolved-phase contamination in the groundwater. A 10-foot by 568
10-foot grid was established over the investigation area for sample collection, as shown in 569
Figure 2.9. The investigation was focused in the area of the historical 2007 LNAPL footprint, 570
which includes abandoned monitoring well T-914-203. T-914-203 was the only well to have a free 571
product sheen in 2009 and is the most likely area where residual contamination (if present) would 572
be detected in groundwater. Sample locations were recorded and marked during the investigation 573
using a field GPS unit. 574
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An attempt was made to collect a groundwater sample within each grid with the exception of cells 575
A2 through D2, and F2 where access was prohibited by HAFB personnel. Borings were advanced 576
to a total depth of 35 feet bgs in cells B1 through F1 and to 45 feet bgs in cell A1. With the 577
exception of cell A1, the borings were anticipated to terminate in the upper perched aquifer 578
estimated to be between 30 to 36 feet bgs, which is also the approximate depth of the smear zone. 579
At sample grid A1, the boring was terminated at 45 feet bgs in an attempt to sample the underlying 580
aquifer. Insufficient groundwater was encountered to collect a groundwater sample at borings 581
located in cells A1 through F1; therefore, no groundwater samples were collected at these 582
locations. A groundwater sample was collected from the DPT boring in cell E2 (ST071GW-E2) at 583
a depth of 30 to 35 feet bgs. Sample ST071-GW-E2 was analyzed for BTEXN (Method 8260B) 584
and TPH-GRO and TPH-DRO (Method 8015D). 585
Sampling equipment was decontaminated after each use and between sampling locations. IDW 586
generated during DPT discrete groundwater sampling was managed in accordance with the HAFB 587
IDW Management Plan (HGL-APTIM JV, 2022b). 588
2.7.2.1 Groundwater Volatile Organic Compounds (EPA Method 8260B) 589
VOCs were detected in the groundwater sample collected from cell E2 (ST071GW-E2) at 590
concentrations exceeding their respective Regional Screening Levels (RSLs) for Residential Tap 591
Water or ISLs. Chloroform (4 J micrograms per liter [µg/L]) exceeded its RSL and ethylbenzene 592
(820 µg/L), total xylenes (11,000 J µg/L), and TPH-GRO (25,000 J µg/L) exceeded their ISLs. 593
RSLs were used for compounds without published ISLs. 594
Groundwater was either not encountered or of insufficient sample volume at the other probed 595
locations. Detected VOCs in the groundwater are presented in Figure 2.9. Analytical results for 596
detected compounds are summarized in Table 2.6. 597
2.7.2.2 Groundwater Total Petroleum Hydrocarbons – Diesel and Gasoline Range 598
Organics 599
TPH-GRO was detected in the groundwater sample collected from cell E2 (ST071GW-E2) at a 600
concentration of 25,000 J µg/L, which exceeds the ISL of 1,000 µg/L. TPH-DRO was not detected 601
in the groundwater sample collected from cell E2 (ST071GW-E2). Groundwater was either not 602
encountered or of insufficient sample volume at the other probed locations. 603
The groundwater TPH-GRO result is presented in Figure 2.9. Analytical results for detected 604
compounds in groundwater are summarized in Table 2.6. 605
2.7.3 Investigation-Derived Waste Management 606
The IDW, including soil cuttings, were containerized in 55-gallon drums and managed in 607
accordance with the HAFB IDW Management Plan (HGL-APTIM JV, 2022b). The IDW was 608
sampled and determined non-hazardous waste. The waste was shipped as non-hazardous waste by 609
Clean Harbors in accordance with the UFP-QAPP and disposed at the Grassy Mountain Landfill 610
Facility located in remote Tooele County, Utah (HGL-APTIM JV, 2022a). Grassy Mountain is a 611
Resource Conservation and Recovery Act- and Toxic Substances Control Act-permitted landfill, 612
with U.S. Environmental Protection Agency (EPA) ID UTD991301748. 613
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2.8 2022 SUPPLEMENTAL SITE INVESTIGATION SUMMARY 614
LNAPL was not observed at the groundwater sample location ST071GW-E2 in cell E2. 615
Groundwater was either not observed or of insufficient sample volume in the borings in cells A1 616
through F1. Groundwater levels have been dropping as a result of several years of below average 617
precipitation. It is likely that the depth to the top of groundwater was below the target depths 618
identified in the 2021 SSI Work Plan. 619
The VOCs ethylbenzene and total xylenes, and TPH-GRO and TPH-DRO were detected in the 620
soil samples at concentrations that exceeded their respective ISLs. The highest concentrations of 621
these COCs were generally detected in cell D1 located near the center of the 2007 LNAPL 622
footprint. 623
The VOCs ethylbenzene and total xylenes, and TPH-GRO were detected in the groundwater at 624
concentrations that exceeded their respective ISLs. Chloroform was detected in the groundwater 625
sample at a concentration that exceeded the RSL. These exceedances indicate that residual 626
contaminant concentrations have not decreased substantially over the last decade. 627
2.9 2022 SUPPLEMENTAL SITE INVESTIGATION CONCLUSIONS 628
In April and May 2022, soil and groundwater sampling was conducted to assess the extent of the 629
dissolved-phase hydrocarbons in the groundwater. Site conditions do not appear to have markedly 630
changed since 2008 with the exception of a drop in the groundwater elevation due to years of 631
below average precipitation. Residual concentrations of ethylbenzene, total xylenes, TPH-GRO, 632
and TPH-DRO remain in the soil within the 2007 LNAPL footprint at concentrations exceeding 633
their respective ISLs, which could potentially contribute dissolved-phase hydrocarbons in the 634
groundwater. This is supported by the elevated dissolved-phase COCs detected in ST071GW-E2. 635
The VOCs chloroform, ethylbenzene, total xylenes, and TPH-GRO were detected in the 636
groundwater at concentrations exceeding their respective RSL or ISLs. Residual contamination in 637
the soil and smear zone will continue to be a potential secondary source of groundwater 638
contamination until it has been remediated. Insufficient data was collected during the SSI to 639
evaluate if LNAPL and dissolved-phased hydrocarbons are stable or reducing. Supplemental data 640
was collected in 2023 in support of the evaluation and design of corrective action alternatives. 641
Greater sample depths were required to ensure groundwater was encountered. The 2023 source 642
area and LNAPL investigation is discussed in detail in Section 3.0. 643
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3.0 2023 SOURCE AREA AND LNAPL INVESTIGATION 644
A source area and LNAPL investigation was conducted in 2023 to support the evaluation and 645
design of a corrective action. COC concentrations exceeding their respective ISLs were detected 646
in the soil and groundwater during the April/May 2022 SSI, which indicated residual 647
contamination remains at UST Site 914. Implementation of a corrective action is required to 648
remove residual LNAPL in the soil and maintain groundwater concentrations below ISLs to 649
achieve final site closure, including removal of LUCs and attainment of UU/UE at UST Site 914. 650
Additional site information related to the extent of LNAPL, dissolved-phase plume, and 651
geochemical parameters was collected in 2023 to evaluate and design a corrective action. All field 652
activities were conducted in accordance with the UST Site 914 2023 CAP (HGL-APTIM JV, 653
2023), SSI Work Plan (HGL-APTIM JV, 2021b), the programmatic Accident Prevention Plan 654
(HGL-APTIM JV, 2021a), and the HAFB ORC UFP-QAPP (HGL-APTIM JV, 2022a). The 2023 655
CAP field activities were performed in June, July, and November 2023. Investigation activities are 656
listed below. 657
• High Resolution Site Characterization (HRSC) using optical imaging profiler (OIP), 658
hydraulic proofing tool (HPT), and electrical conductivity (EC) to better define the nature 659
and extent of LNAPL and site lithology. 660
• Confirmation soil sampling using a DPT rig following the HRSC screening to identify the 661
nature of the LNAPL. 662
• Confirmation groundwater sampling using a DPT rig following soil sampling to better 663
define the nature and extent of dissolved-phase COCs at concentrations exceeding their 664
respective ISLs. 665
• Installation of three new monitoring wells based on the results of the DPT groundwater 666
sampling and OIP investigation to collect definitive groundwater data to delineate the 667
dissolved-phase plume and measure LNAPL thickness if present. 668
• Gauge all new wells using an oil-water interface probe to measure depth to water and depth 669
to LNAPL (if present). Sample the three monitoring wells for BTEXN, TPH-GRO, and 670
TPH-DRO, field parameters (pH, temperature, conductivity, dissolved oxygen [DO], and 671
oxidation-reduction potential [ORP]) and geochemical parameters (nitrate, sulfate, iron, 672
and manganese) within and outside the dissolved-phase plume to determine biochemical 673
properties of the upper most aquifer and the impacted zones to evaluate site conditions for 674
MNA or active bioremediation. This information is necessary for the evaluation of the 675
application and design of the corrective action alternatives for Phase 2 implementation. 676
All sample containers were immediately placed on ice following collection and shipped by 677
overnight delivery to the Arvada (Denver) facility of Eurofins Test America (a DoD ELAP -678
certified laboratory) for analysis. Field logbooks and groundwater sample collection forms are 679
included in Appendix B. OIP/HPT/EC logs are provided in Appendix C. Analytical data was 680
validated in accordance with the HAFB ORC UFP-QAPP (HGL-APTIM JV, 2022a). Laboratory 681
reports are provided in Appendix D. Laboratory data validation reports are provided in Appendix 682
E. Waste profile for IDW disposal is provided in Appendix F. Analytical results are discussed 683
below by analyte group. 684
Results of the activities are described in the following sections. 685
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3.1 HIGH RESOLUTION SITE CHARACTERIZATION 686
HRSC was performed to delineate the nature and extent of LNAPL identified during the April/May 687
2022 SSI to support the evaluation and design of a corrective action. Before conducting field 688
activities, utilities were cleared through the HAFB dig permit process Red Stakes. Work was 689
coordinated in advance with representatives of the Petroleum, Oil, and Lubricant (POL) Yard. A 690
field GPS unit was used to record and temporarily mark the boring locations during the 691
investigation. 692
3.1.1 High Resolution Site Logging 693
HRSC was conducted at nine locations (ST071-OIP-01 through ST071-OIP-09) using an OIP 694
combined with HPT and EC logging to refine the extent of the LNAPL footprint from 6 June 2023 695
through 9 June 2023. The OIP is a direct push fluorescence detector tool used for the delineation 696
of non-aqueous phase liquid hydrocarbon fuels and oils, specifically fuel polynuclear aromatic 697
hydrocarbons (PAHs). Direct push HPT (used to assess permeability) and EC (used to assess 698
lithology) logging provided information about site hydrostratigraphy at a scale of relevance for 699
contaminant transport investigations. The OIP/HPT/EC probe was advanced with DPT drilling 700
methods to record OIP measurements simultaneously with permeability and lithologic 701
observations. The OIP/HPT/EC logs are provided in Appendix C. 702
OIP/HPT/EC data was collected in the area where LNAPL was historically observed to delineate 703
the vertical and areal extent of the LNAPL (see Figure 3.1). A total of nine OIP/HPT/EC borings 704
were installed using a DPT drill rig. All the OIP/HPT/EC borings were advanced a minimum of 705
10 feet below the estimated water table in the shallow aquifer to determine the vertical extent of 706
VOC contamination. OIP probes were advanced to 58 to 59 feet bgs at ST071-OIP-01 through 707
ST071-OIP-03 and ST071-OIP-07, 46 to 49 feet bgs at ST071-OIP-04 through ST071-OIP-06, 708
and ST071-OIP-09, and 61 feet bgs at ST071-OIP-08. A summary of the HRSC activities is 709
provided in Table 3.1. The depth to groundwater was typically 45 to 50 feet bgs. 710
Positive OIP responses, which is an indicator of LNAPL, were detected in the vadose zone at all 711
nine of the probe locations. A trace OIP response (0 to 9.9 percent [%]) was detected at the far 712
west probe location ST071-OIP-08, which is an indicator of low PAH concentrations. Low OIP 713
response (10.0 to 29.9%) was detected in the northeast portion of the site at ST071-OIP-02. 714
Moderate OIP responses (30.0 to 49.9%) were detected near the center of the site at ST071-OIP-715
04 and ST071-OIP-5. Moderate to high OIP responses (50.0 to 69.9%) were detected in the south 716
and east portion of the site at ST071-OIP-03, ST071-OIP-07, and ST071-OIP-09. High OIP 717
responses (70.0 to 100.0%) were detected in the north central and center portion of the site at 718
ST071-OIP-01 and ST071-OIP-06. OIP responses were used to select intervals for confirmation 719
samples. The locations of the OIP probes and relative responses are shown on Figure 3.1. 720
The depth to water ranged from 45.82 feet bgs at ST071-OIP-01 and -02 in the northeast portion 721
of the site to 50.51 feet bgs at ST071-OIP-07 located in the south center of the site. Residual 722
LNAPL was identified by OIP response in the vadose zone extending above the water table. 723
Moderate to high peak responses of greater than 50% were detected at ST071-OIP-07 (53%) from 724
25 to 40.2 feet bgs, ST071-OIP-09 (59%) from 25.6 to 31 feet bgs, ST071-OIP-03 (60%) from 25 725
to 32 feet bgs, ST071-OIP-06 (80%) from 26 to 43.5 feet bgs, ST071-OIP-01 (90%) from 26.5 to 726
38 feet bgs. OIP responses at all other probe locations ranged from 1.2 to 32%. 727
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3.1.2 Confirmation Soil Samples 728
Confirmation soil samples were collected from 14 July 2023 through 19 July 2023 following the 729
OIP/HPT/EC screening to identify the nature of the LNAPL. A 4-foot core sample was collected 730
at each OIP/HPT/EC location from the interval with the highest VOC detection at the adjacent 731
OIP/EC location as determined by the OIP response. The confirmation soil sample was collected 732
by advancing a 4-foot macro-core sampler to the identified sample interval and extracting the soil 733
core using a DPT rig. The soil sample once retrieved was screened using a PID. A soil sample was 734
collected from the interval with the highest PID response and packed in the appropriate sample 735
container in accordance with the SSI Work Plan (HGL-APTIM JV, 2021b). The confirmation soil 736
samples were submitted for BTEXN by EPA Method 8260D and TPH-GRO and TPH-DRO by 737
EPA Method 8015D. Sampling equipment was decontaminated after each use and between 738
sampling locations. Soil cuttings were placed in a roll-off dumpster pending waste characterization 739
and off-site disposal. Field screening of the soil samples using PID documented in the field 740
logbook provided in Appendix B.3. Soil analytical results are presented in Figure 3.1. The soil 741
sample intervals and maximum PID readings are summarized in Table 3.1. Soil analytical results 742
are summarized in Table 3.2. 743
3.1.3 Volatile Organic Compounds (EPA Method 8260D) 744
The VOCs toluene, ethylbenzene, xylenes, and naphthalene were detected in the soil at UST Site 745
914. Ethylbenzene and xylenes were detected in the soil at concentrations greater than the ISL of 746
5,000 µg/kg and 142,000 µg/kg, respectively. All other VOCs were detected in the soil samples at 747
concentrations below their respective ISLs. 748
Benzene was not detected in any of the soil samples collected at UST Site 914. 749
Toluene was detected in 1 of 9 soil samples at the concentration of 1,000 J µg/kg (ST071-OIP-05). 750
This detection did not exceed the ISL of 9,000 µg/kg. 751
Ethylbenzene was detected in 7 of 9 soil samples collected at UST Site 914 at concentrations 752
ranging from 81 J µg/kg (ST071-OIP-08) to 7,100 J µg/kg (ST071-OIP-04). Two of the detections 753
exceeded the ISL of 5,000 µg/kg: 5,800 J µg/kg detected at ST071-OIP-09 and 7,100 J µg/kg 754
detected at ST071-OIP-04. 755
Xylenes were detected in 6 of 9 soil samples at concentrations ranging from 5,700 µg/kg (ST071-756
OIP-07) to 1,000,000 J µg/kg (ST071-OIP-05). Only the detection at ST071-OIP-05 exceeded the 757
ISL of 142,000 µg/kg. 758
Naphthalene was detected in 4 of 9 soil samples at concentrations ranging from 1,100 J µg/kg 759
(ST071-OIP-03) to 15,000 J µg/kg (ST071-OIP-05). None of the detections exceeded the ISL of 760
51,000 µg/kg. 761
3.1.4 Total Petroleum Hydrocarbons – Diesel and Gasoline Range Organics 762
TPH-GRO was detected in all 9 of the soil samples collected at UST Site 914 at concentrations 763
ranging from 17 mg/kg (ST071-OIP-08) to 8,400 J mg/kg (ST071-OIP-09). Six of the detections 764
exceeded the ISL of 150 mg/kg: 290 mg/kg at ST071-OIP-02, 3,000 mg/kg at ST071-OIP-03, 765
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7,100 J mg/kg at ST071-OIP-04, 170 J mg/kg at ST071-OIP-06 (duplicate sample), 410 mg/kg at 766
ST071-OIP-07, and 8,400 J mg/kg at ST071-OIP-09. 767
TPH-DRO was detected in 8 of 9 soil samples collected at concentrations ranging from 43mg/kg 768
(ST071-OIP-01) to 3,900 mg/kg (ST071-OIP-05). Three of the detections exceeded the ISL of 500 769
mg/kg: 560 mg/kg at ST071-OIP-02, 1,700 J mg/kg at ST071-OIP-04, and 3,900 mg/kg at ST071-770
OIP-05. 771
3.1.5 Confirmation Groundwater Samples 772
Discrete groundwater samples were collected from 25 July 2023 through 26 July 2023 following 773
the confirmation soil sampling at 12 of the 13 locations using a DPT rig to evaluate COC 774
concentrations in the groundwater and identify residual LNAPL. The groundwater sample 775
locations were selected to target the area of the historic 2007 LNAPL footprint, which includes 776
abandoned monitoring well T-914-203. T-914-203 was the only well to have a free product sheen 777
in 2009 and is the most likely area where residual contamination (if present) would be detected in 778
groundwater. 779
A groundwater sample was collected from each DPT location using a discrete groundwater 780
sampler. A temporary well was installed and constructed of threaded 3/4-inch diameter casing with 781
a 10-foot screened interval due to slow water production. In total, 13 DPT borings (ST071-OIP-782
01 through ST071-OIP-09, ST071-GW-1A, ST071-GW-2A, ST071-GW-1C, and ST071-GW-2C) 783
were advanced to depths ranging from 45 feet bgs in the upper perched aquifer (east) to 65 feet 784
bgs in the lower aquifer (west). A groundwater sample was successfully collected from each boring 785
with the exception of ST071-GW-1C (groundwater was not encountered at this location). The 786
groundwater samples were submitted to Arvada (Denver) facility of Eurofins Test America (a DoD 787
ELAP-certified laboratory) and analyzed for BTEXN (Method 8260D) and TPH-GRO and TPH-788
DRO (Method 8015D). 789
Sampling equipment was decontaminated after each use and between sampling locations. IDW 790
generated during DPT discrete groundwater sampling was managed in accordance with the HAFB 791
IDW Management Plan (HGL-APTIM JV, 2022b). Groundwater analytical results are presented 792
in Figure 3.2. The groundwater sample intervals and maximum PID readings are summarized in 793
Table 3.1. Discrete groundwater analytical results are summarized in Table 3.3. 794
3.1.6 Volatile Organic Compounds (EPA Method 8260D) 795
The VOCs benzene, toluene, ethylbenzene, xylenes, and naphthalene were detected in 796
groundwater at UST Site 914. Benzene was detected in groundwater at concentrations higher than 797
the ISL of 5 µg/L and ethylbenzene was detected in groundwater at concentrations greater than the 798
ISL of 700 µg/L. All other VOCs analyzed were detected in groundwater samples at concentrations 799
below their respective ISLs. 800
Benzene was detected in 2 of 12 groundwater samples collected at UST Site 914 at concentrations 801
ranging from 19 J µg/L (ST071-GW-2A) to 47 J µg/L (ST071-GW-1A). Both detections exceeded 802
the ISL of 5 µg/L. 803
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 3-5 January 2025
Toluene was detected in 5 of 12 groundwater samples collected at UST Site 914 at concentrations 804
ranging from 0.32 J µg/L (ST071-OIP-03) to 10 J µg/L (ST071-OIP-07 and ST071-GW-2A). None 805
of the detections exceeded the ISL of 1,000 µg/L. 806
Ethylbenzene was detected in 9 of 12 groundwater samples collected at UST Site 914 at 807
concentrations ranging from 1.6 J µg/L (ST071-OIP-03) to 830 µg/L (ST071-GW-1A). One of the 808
detections exceeded the ISL of 700 µg/L: 830 µg/L at ST071-GW-1A. 809
Xylenes were detected in 9 of 12 groundwater samples collected at UST Site 914 at concentrations 810
ranging from 0.43 J µg/L (ST071-OIP-03) to 5,800 µg/L (ST071-GW-1A). None of the detections 811
exceeded the ISL of 10,000 µg/L. 812
Naphthalene was detected in 8 of 12 groundwater samples collected at UST Site 914 at 813
concentrations ranging from 2.8 µg/L (ST071-OIP-03) to 140 J µg/L (ST071-GW-1A). None of 814
the detections exceeded the ISL of 700 µg/L. 815
3.1.7 Total Petroleum Hydrocarbons – Diesel and Gasoline Range Organics 816
TPH-GRO was detected in 12 of 12 groundwater samples collected at UST Site 914 at 817
concentrations ranging from 0.012 J mg/L (ST071-OIP-08) to 49 mg/L (ST071-GW-1A). Eight of 818
the detections exceeded the ISL of 1 mg/L: 7.8 mg/L at ST071-OIP-01, 2.7 mg/L at ST071-OIP-819
03, 8 mg/L at ST071-OIP-04, 3.5 mg/L at ST071-OIP-05, 2.6 J mg/L at ST071-OIP-07, 49 mg/L 820
at ST071-GW-1A, 7.8 mg/L at ST071-GW-2A, and 11 mg/L at ST071-GW-2C. 821
TPH-DRO was detected in 12 of the 12 groundwater samples collected at concentrations ranging 822
from 0.041 J mg/L (ST071-OIP-08) to 8.9 mg/L (ST071-OIP-03). Five of the detections exceeded 823
the ISL of 1 mg/L: 2 mg/L at ST071-OIP-01, 8.9 mg/L at ST071-OIP-03, 1.9 mg/L at ST071-OIP-824
04, 1.7 mg/L at ST071-OIP-05, and 4.1 mg/L at ST071-GW-1A. 825
3.2 MONITORING WELL INSTALLATION 826
Three monitoring wells were installed based on the results of the OIP screening, soil confirmation 827
data, and discrete groundwater analytical data to collect representative groundwater data for the 828
delineation of the dissolved-phase plume and allow measurement of LNAPL thicknesses if present. 829
The boreholes were drilled using 6-inch diameter sonic drilling techniques to target depth based 830
on the DPT discrete groundwater sample results. The soil cores were continuously logged by an 831
HGL-APTIM JV geologist in accordance with Standard Operating Procedure (SOP) 7: Soil 832
Classification and field-screened for VOCs using a PID (HGL-APTIM JV, 2021b). The 833
monitoring wells were installed and developed in accordance with SOP 11: Monitoring Well 834
Installation, Completion and Development. Start Cards and well logs were submitted to the Utah 835
Division of Water Rights following the construction of the monitoring wells. The boring logs, well 836
construction diagrams, and well development forms are provided in Appendix B.4. 837
The monitoring wells were constructed using 2-inch diameter schedule 40 polyvinyl chloride 838
(PVC), screened with 2-inch diameter schedule 40 PVC 0.010-inch machine slotted well screen, 839
and 20/40 silica sand filter pack. The filter pack extended from the terminus of the borehole to 840
approximately 2 feet above the top of screen. An annular seal consisting of a minimum of 2 feet 841
of hydrated bentonite chips was placed on top of the filter pack. The remainder of the annular 842
space was filled with neat cement grout that extended from the top of the bentonite seal to 843
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 3-6 January 2025
approximately 1 foot from the ground surface. The monitoring wells were completed with flush 844
mount surface completions. A state licensed surveyor surveyed the ground surface and top of 845
casing elevations (Appendix B.5). Well development was conducted 24 hours after the well 846
completion. The locations of the three new monitoring wells are shown on Figure 3.3 along with 847
the November 2023 groundwater elevations. Monitoring well construction details are summarized 848
in Table 3.4. 849
3.3 GROUNDWATER MONITORING 850
The three new monitoring wells (T-914-017, T-914-018 and T-914-019) were sampled to assess 851
the presence of LNAPL, water levels, and groundwater quality during the November 2023 852
groundwater monitoring event. One round of groundwater samples was collected from the three 853
new monitoring wells to define the current extent of groundwater contamination and provide 854
geochemical parameter data to evaluate the biochemical properties of the aquifer. The locations of 855
the wells gauged and sampled are shown on Figure 3.4. 856
Low-flow purging procedures were followed during sample collection. The water level within the 857
well casing was monitored during purging to ensure that laminar flow to the pump inlet was 858
occurring. Well stabilization parameters, including temperature, pH, conductivity, DO, ORP, and 859
turbidity, were recorded every 5 minutes until stabilization occurred. Parameters were considered 860
stable when three successive readings meet the parameter-specific acceptance criteria as specified 861
in SOP 17: Groundwater Sampling for Chemical Analysis (HGL-APTIM JV, 2022a). 862
A bladder pump was used to sample the wells using low-flow sampling techniques. New, unused 863
tubing was used for each well, and after sampling, the downhole tubing was left in the well to 864
minimize contamination during storage. The discharge tubing was attached to a flow-through cell 865
with a multi-parameter meter capable of measuring temperature, pH, conductivity, DO, and ORP. 866
A separate turbidity meter was used to collect turbidity measurements. Groundwater samples 867
collected from each monitoring well were analyzed for BTEXN (Method 8260D), TPH-GRO and 868
TPH-DRO (Method 8015D), and the geochemical parameters nitrate (Method 353.3), total and 869
dissolved iron (Method 6010D), total and dissolved manganese (Method 6020B), sulfate (Method 870
300.0), and alkalinity (Method 2320B). All sample containers were immediately placed on ice 871
following collection and shipped by overnight delivery to the Arvada (Denver) facility of Eurofins 872
TestAmerica (a DoD ELAP-certified laboratory) for analysis. Sampling equipment was 873
decontaminated after each use and between sampling locations. IDW generated during the 874
groundwater sampling event was managed in accordance with the IDW Management Plan (HGL-875
APTIM JV, 2022b). Liquid wastes were transported to the HAFB water treatment facility for 876
disposal. 877
3.3.1 Monitoring Well Gauging 878
The depth to groundwater during the last sampling event in 2008 ranged from 25.87 feet bgs (T-879
914-MW1) in the perched aquifer to the east to 53.05 feet bgs (T-914-016) in the lower aquifer to 880
the west (T-914-016) north of Building 911. On 20 November 2023, each of the three new 881
monitoring wells (T-914-017, T-914-018 and T-914-019) was gauged using an oil-water interface 882
probe to measure depth to water and thickness of LNAPL (if present) prior to purging and 883
groundwater sampling. The depth to groundwater ranged from 44.84 feet below top of casing 884
(bTOC) (T-914-017) to 47.49 feet bTOC (T-914-019). Free product was not observed during the 885
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT
U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 3-7 January 2025
20 November 2023 groundwater monitoring event. The depth to groundwater and corresponding 886
groundwater elevations are summarized in Table 3.4 and shown on Figure 3.3. 887
3.3.2 Geochemical Parameters 888
Geochemical parameters were collected in addition to the COCs to evaluate the biochemical 889
properties of the upper most aquifer in the impacted zones to evaluate site conditions for MNA or 890
active bioremediation. Groundwater was slightly anaerobic (suboxic) across the site with little 891
variability in the geochemistry. DO ranged from 0.02 to 0.26 mg/L and ORP ranged from -28.7 to 892
155.7 millivolts, indicating generally oxidizing conditions. The groundwater had a neutral pH, 893
ranging from 7.02 to 7.07 and total alkalinity concentrations ranged from 230 to 290 mg/L. 894
Specific conductance ranged from 0.746 to 0.795 milliSiemens per centimeter. Nitrate 895
concentrations ranged from 3.7 to 4.2 mg/L. Dissolved iron concentrations ranged from 0.017 J to 896
0.16 mg/L. Dissolved manganese concentrations ranged from 0.016 to 0.19 mg/L. Sulfate 897
concentrations ranged from 15 to 20 mg/L. 898
The groundwater field parameters are presented in Table 3.5 and the geochemical data is presented 899
in Table 3.6. The groundwater sample locations are shown on Figure 3.4. 900
3.3.3 Volatile Organic Compounds (EPA Method 8260D) 901
The VOCs ethylbenzene and total xylenes were detected in a groundwater sample collected from 902
one of the three monitoring wells (T-914-018) sampled in the November 2023. Both ethylbenzene 903
and total xylenes detections were at concentrations below their respective ISLs. The VOCs 904
benzene, toluene, and naphthalene were not detected in any of the three groundwater samples 905
collected. Therefore, BTEXN was not detected in any groundwater samples at concentrations 906
above the respective ISLs. 907
Ethylbenzene was detected at the concentration of 0.82 J µg/L in monitoring well T-914-018. This 908
detection did not exceed the ISL of 700 µg/L. 909
Total xylenes were detected at the concentration of 13 J µg/L in T-914-018. This detection did not 910
exceed the ISL of 10,000 µg/L. 911
The groundwater COC analytical results are summarized in Table 3.7 and shown on Figure 3.4. 912
3.3.4 Total Petroleum Hydrocarbons – Diesel and Gasoline Range Organics 913
TPH-DRO was not detected in any of the groundwater samples collected at the three monitoring 914
wells during the 20 November 2023 sampling event. TPH-GRO (0.12 J mg/L) was only detected 915
in the groundwater sample collected from T-914-018 at a concentration below the ISL. 916
The groundwater analytical results are summarized in Table 3.7 and shown on Figure 3.4. 917
3.4 CURRENT EXTENT OF CONTAMINATION 918
There has been considerable change in the site conditions since it was last sampled in 2008. 919
Groundwater levels have decreased in response to several years of below average precipitation to 920
the extent that the previously observed perched aquifer was not observed which resulted in the 921
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U.S. Army Corps of Engineers—Sacramento District
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absence of the perched aquifer. Residual LNAPL was observed in the vadose zone from 25 feet 922
bgs to a maximum depth of 45 feet bgs. Residual LNAPL remains in the soil but no longer appears 923
to leach to the groundwater. LNAPL was not detected at the water table at any of the groundwater 924
sample locations. Ethylbenzene, total xylenes, TPH-GRO and TPH-DRO were detected in the soil 925
at concentrations that exceeded their respective ISLs. Ethylbenzene, total xylenes, and TPH-GRO 926
were the only COCs detected in the groundwater but at concentrations below their respective ISLs. 927
Concentrations of dissolved-phased hydrocarbons in the groundwater have decreased from the 928
2008 groundwater monitoring event indicating that MNA is likely occurring and controlling 929
further migration. Leaching is likely to occur in the event the water levels rise and come into 930
contact with residual LNAPL in the vadose zone. LNAPL will continue to be a potential source of 931
groundwater contamination until it has been remediated. 932
3.4.1 Soil Contamination 933
Soil contamination in the form of residual LNAPL was detected at seven of the nine OIP probe 934
locations (OIP-02, OIP-03, OIP-04, OIP-05, OIP-06, OIP-07, and OIP-09) as shown on Figure 935
3.1. OIP responses varied in depth from 25 to 28 feet bgs at OIP-02 to 28 to 44.5 feet bgs at OIP-936
05. The shallower responses were generally detected in the east portion of the former UST Site 937
914. COC concentrations exceeding their respective ISLs were detected in the soil at the OIP probe 938
locations OIP-02, OIP-03, OIP-04, OIP-05, OIP-06, OIP-07, and OIP-09. Ethylbenzene, total 939
xylenes, TPH-GRO, and TPH-DRO were the only COCs detected in the soil samples at 940
concentrations exceeding their respective ISLs, while TPH-GRO was the most widely distributed 941
COC. The extent of soil contamination exceeding the ISLs is illustrated on Figure 3.1. 942
The upper soil column consists of a permeable fine to coarse sand unit with a minor silt content, 943
extending to 25 feet bgs with a silty fine sand lense observed at 11 to 12 feet bgs. A low permeable 944
silty fine sand to silty clay layer with minor intermittent lenses of sand was observed underlying 945
the sand unit that extended to terminus of 45 to 60 feet bgs. The residual LNAPL was generally 946
observed in the lower portion or near the base of the low permeable silt layer as shown on the OIP 947
logs. The OIP response and confirmation soil analytical results are illustrated on Figure 3.1. 948
The depth to water was measured at the time of sample collection in July 2023. A summary of the 949
OIP response intervals and responses, soil sample interval, field screening using a PID, and depth 950
to water are included in Table 3.1. OIP/HPT/EC logs are provided in Appendix C. 951
3.4.2 Dissolved-Phase Groundwater Plume 952
The dissolved-phase COCs were detected at concentrations exceeding their respective ISLs at five 953
of the nine OIP probe locations (OIP-01, OIP-03, OIP-04, OIP-05, OIP-07) and all three of the 954
discreet groundwater sample locations (ST071-GW-1A, ST071-GW-2A, and ST071-GW-2C), as 955
shown on Figure 3.2. Five of the eight locations with ISL exceedances were located outside of the 956
limits of the 2007 LNAPL plume. COCs at concentrations exceeding their respective ISLs were 957
only detected in the discrete groundwater samples collected in July 2023. COC concentrations 958
were below their respective ISLs in the groundwater samples collected from the three new 959
monitoring wells sampled in November 2023. COC analytical results for the three new monitoring 960
wells are shown on Figure 3.4. 961
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 3-9 January 2025
The groundwater flow direction during the November 2023 monitoring event was to the west at a 962
minimum estimated hydraulic gradient of 0.0289. The depth to groundwater ranged from 44.84 ft 963
bTOC (4,711.99 ft amsl) at T-914-017 (east) to 47.49 ft bTOC (4,709.32 ft amsl) at T-914-019 964
(west). The depth to groundwater and well construction summaries are presented in Table 3.4. 965
3.4.3 Conclusions 966
Site conditions have changed since the last groundwater monitoring event conducted in 2008. 967
Groundwater elevations have decreased in response to several years of below average precipitation 968
resulting in the absence of the perched aquifer. The perched aquifer that had been sampled during 969
pre-2008 investigation was no longer present in 2022 and 2023. The depth to groundwater was 970
relatively consistent across the site, ranging from 44.84 ft bTOC (4,711.99 ft amsl) in the east (T-971
914-017) to 47.49 ft bTOC (4,709.32 ft amsl) in the west (T-914-019). Residual concentrations of 972
ethylbenzene, total xylenes, TPH-GRO, and TPH-DRO remain in the soil with five OIP locations 973
with ISL exceedances located outside of the 2007 LNAPL footprint. Residual LNAPL detected in 974
the vadose using OIP does not appear to be mobile. LNAPL was not observed on the water table 975
at the eight groundwater sample locations or three monitoring wells sampled in 2023. 976
Ethylbenzene, total xylenes, TPH-GRO, and TPH-DRO were detected in the discrete groundwater 977
samples at concentrations exceeding their respective ISLs, possibly transported downward from 978
the impacted interval in the vadose zone. This is supported by the fact that all COC concentrations 979
in the groundwater samples collected from the permanent monitoring wells were below ISLs. It is 980
likely that MNA is occurring and controlling COC concentrations in the groundwater and further 981
migration of the dissolved-phase COCs. 982
Sufficient soil and groundwater data were collected to determine that the residual LNAPL in the 983
soil no longer impacts the underlying groundwater at concentrations that exceed ISLs. The 984
continued presence of LNAPL and detections of TPH-DRO and TPH-GRO in the soil at 985
concentrations above ISLs will require ongoing implementation of LUCs to prevent exposure to 986
residual contamination until corrective action can be implemented. No additional data is required 987
to evaluate possible corrective actions to attain UU/UE. 988

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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 4-1 January 2025
4.0 CORRECTIVE ACTION ALTERNATIVES AND SELECTION 990
This CAP Addendum will address residual LNAPL removal, residual soil contamination in the 991
vadose zone, and dissolved-phase COC remediation. A description and evaluation of selected 992
corrective action alternatives are presented in the sections below. 993
4.1 CORRECTIVE ACTION OBJECTIVES 994
Corrective action is required to reduce residual petroleum contamination in the soil and 995
groundwater at UST Site 914 to attain UU/UE. Residual LNAPL and concentrations of 996
ethylbenzene, total xylenes, TPH-GRO, and TPH-DRO were detected in the soil at concentrations 997
exceeding their respective ISLs during investigations conducted in June and July 2023. BTEXN, 998
TPH-DRO, and TPH-GRO concentrations in the groundwater were below their respective ISLs 999
during groundwater monitoring conducted at three new monitoring wells in November 2023. 1000
The following corrective action objectives were developed to attain UU/UE: 1001
• Reduce residual LNAPL mass and soil contaminant concentrations to below their 1002
respective ISLs in the unsaturated soil; 1003
• Reduce residual LNAPL mass and soil contamination such that it does not leach into the 1004
underlying aquifer at concentrations resulting in dissolved-phase COCs exceeding their 1005
respective groundwater ISLs; and 1006
• Maintain dissolved-phase COCs in the groundwater at concentrations below their 1007
respective ISLs. 1008
4.2 VADOSE ZONE 1009
4.2.1 Surfactant Enhanced Remediation 1010
Surfactant enhanced remediation (SER), using Ivey-Sol 103® and/or 106®, was evaluated for use 1011
at UST Site 914 to remediate petroleum hydrocarbon LNAPL in the smear zone. Ivey-Sol 103® is 1012
formulated to target gasoline fuels (to include BTEX and methyl tertiary butyl ether). Ivey-Sol 1013
106® is designed to target diesel and PAHs and will be used to target jet fuels at ST071. SER 1014
effectively desorbs LNAPL trapped within the matrix to make it more soluble, increasing the 1015
“physical availability” for extraction, and more “biologically available” to microbes that degrade 1016
fuel hydrocarbons in HAFB groundwater. Ivey-Sol 106® was evaluated for application to wells 1017
within the LNAPL plume using a push-pull methodology where the reagent is injected into the 1018
subsurface and then extracted from the same well using dual-phase extraction via a vacuum truck. 1019
This method addresses potential regulatory concerns that the surfactant will mobilize fuel 1020
hydrocarbons and allow transport to uncontaminated portions of the aquifer. Three additional wells 1021
would be required west of the 2007 LNAPL plume and hydraulically downgradient of injection 1022
points to provide hydraulic control. SER more effectively remediates LNAPL compared to manual 1023
bailing or SVE, which do not address residual LNAPL trapped in pore spaces below the water 1024
table. HGL has effectively applied surfactants to remediate LNAPL at Little Rock Air Force Base 1025
(AFB) Site ST025 (USAF, 2020). 1026
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 4-2 January 2025
Surfactant technologies such as SER rely on direct contact of the surfactant with the LNAPL to 1027
selectively desorb and liberate sorbed LNAPL from the formation. The EC and HPT logs of the 1028
sediment in the impacted intervals are characteristic of low permeable silts, which would reduce 1029
the injection radius and rate. Residual LNAPL currently occurs above the water table observed in 1030
July 2023 as detected using the OIP probe and discrete confirmation soil samples. LNAPL was 1031
detected above the water table generally from 25 to 38 feet bgs with a maximum depth of 44.5 feet 1032
bgs where the depth to water was 46.17 feet bTOC (T-914-018). OIP responses of the residual 1033
LNAPL in relation to the lithology and depth to water are illustrated on Figures 4.2 and 4.3. The 1034
locations of the cross sections are shown on Figure 4.1. 1035
SER was not selected for application. The fine-grained sediments in the impacted intervals would 1036
limit the effective injection radius, rate of injection, and volume per location. In addition, residual 1037
LNAPL was observed in the vadose zone during the July 2023 HRSC investigation; therefore, the 1038
push-pull application of the SER using the existing monitoring wells would not come in contact 1039
with the residual LNAPL, with the possible exception of limited contact in the vicinity of the 1040
injection well due to temporary mounding during injection. COC concentrations in the surficial 1041
aquifer are low to non-detect during the November 2023 groundwater monitoring event. Surfactant 1042
flushing would mobilize the residual LNAPL in the vadose zone, subsequently contaminating the 1043
underlying surficial aquifer. The LNAPL plume is located beneath the primary trafficway for base 1044
fueling operations at the UST Site 914 POL Yard. Direct injection of the SER in the overlying 1045
vadose zone in a grid pattern over the footprint of the LNAPL plume is not feasible due to the 1046
interruption of the fueling delivery operations and would require multiple penetrations through the 1047
thick concrete trafficway. 1048
4.2.2 Active Bioventing 1049
Active bioventing was selected to remove residual hydrocarbon mass, including LNAPL, residing 1050
in the vadose zone at UST Site 914. The system will be designed to maximize aerobic 1051
biodegradation and minimize mass emissions. Atmospheric air will be injected to maximize 1052
oxygen availability to promote aerobic biodegradation of the petroleum hydrocarbons coupled 1053
with an SVE component to improve air circulation, capture effluent vapors, and to assist in 1054
monitoring mass removal rates and the system performance. While some hydrocarbon mass will 1055
be volatilized and removed by the SVE system, operation of the bioventing system will be 1056
optimized to maximize aerobic biodegradation and minimize physical mass removal. The 1057
bioventing system will focus on aerobic biodegradation as it is more effective than vapor extraction 1058
on the less volatile and more recalcitrant constituents of JP-4. Air injection will be maintained at 1059
a low pressure and low flow rate so soil gas is displaced, and the volatile hydrocarbons are 1060
biodegraded as the soil gas moves slowly through the soil. Under Utah Administrative Code R307-1061
401-15 for Air Strippers and Soil Venting Projects, a permit is not required if emissions of total 1062
VOCs are less than 5 tons per year (10,000 pounds) and the level of each hazardous air pollutant 1063
is below the emission threshold values derived for that contaminant as described in Utah 1064
Administrative Code R307-410-5(1)II(C). The proposed bioventing system is anticipated to 1065
remain below this limit. 1066
Residual hydrocarbons are present primarily within a lower permeability horizon within the low 1067
permeable sediments that are currently unsaturated. The majority of the residual petroleum 1068
hydrocarbons, based on OIP responses, were observed between 25 and 35 feet bgs and 1069
approximately 10 feet above the most recent groundwater levels. The exception was west of the 1070
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U.S. Army Corps of Engineers—Sacramento District
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former UST 914 where an OIP response indicating the presence of petroleum hydrocarbons was 1071
present between 40 and 45 feet bgs, immediately above the current groundwater levels. OIP 1072
responses of the residual LNAPL in relation to the lithology are illustrated in Figures 4.2 and 4.3. 1073
Bioventing was evaluated and selected for application. The system is designed to provide oxygen 1074
via a series of biovent wells and effluent vapor recovery via SVE wells, thus promoting aerobic 1075
degradation while minimizing volatilization of the petroleum hydrocarbons within the unsaturated 1076
zone. The system is designed to deliver approximately one pore volume exchange per day of 1077
ambient air at an oxygen concentration of 20.9%. The low exchange rate will provide sufficient 1078
oxygen to promote aerobic biodegradation of the hydrocarbons without drying out the formation. 1079
The SVE wells are located around the perimeter of the treatment system to minimize the potential 1080
for vapor migration from the injection well. The SVE wells will be used to conduct performance 1081
monitoring in addition to capturing vapors. The amount of VOCs, oxygen, and carbon dioxide in 1082
extracted vapors will be monitored during long-term operation to determine direct mass removal. 1083
A decrease in oxygen and an increase in carbon dioxide from atmospheric concentrations are 1084
anticipated to indicate the rate at which aerobic biodegradation activities are consuming oxygen 1085
and producing carbon dioxide. Changes over time will reflect the extent to which the remediation 1086
goals are being met. 1087
4.3 GROUNDWATER 1088
COC concentrations in the groundwater samples collected from the three new monitoring wells 1089
were below their respective ISLs, indicating that active groundwater remediation is not necessary 1090
at this time. Groundwater monitoring will be conducted throughout the corrective action to monitor 1091
COC concentrations. 1092
4.3.1 Baseline Groundwater Monitoring 1093
Baseline groundwater monitoring will be conducted prior to the startup of the biovent system to 1094
determine the COC concentrations in the shallow aquifer. One round of groundwater samples will 1095
be collected from the monitoring wells T-914-017, T-914-018, and T-914-019 to define the current 1096
extent of groundwater contamination and provide geochemical parameter data to evaluate the 1097
biochemical properties of the aquifer. 1098
All wells will be gauged prior to initiating well purging/sampling activities to evaluate the general 1099
groundwater flow direction at the site and to determine whether LNAPL is present in any of the 1100
wells. Baseline samples will be collected pre-startup and analyzed to provide quantitative baseline 1101
concentrations of COCs. All samples will be analyzed in the off-site laboratory for the following 1102
parameters: 1103
• BTEXN using SW846 8260D, 1104
• TPH-GRO and TPH-DRO using EPA 8015D, 1105
• Nitrate and sulfate using EPA 300.0, and 1106
• Dissolved iron and manganese using SW846 6010D. 1107
The field parameters pH, temperature, conductivity, DO, and ORP and geochemical parameters 1108
nitrate, sulfate, iron, and manganese will be analyzed to assess the biochemical properties of the 1109
upper most aquifer in the impacted zones to evaluate site conditions for MNA or active 1110
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bioremediation. The location of the wells identified for groundwater sampling and gauging are 1111
shown on Figure 3.4. 1112
4.3.2 In Situ Activated Carbon 1113
Liquid activated carbon will be evaluated to facilitate fuel hydrocarbon remediation of dissolved-1114
phase COCs in the groundwater in the event COC concentrations rebound above their respective 1115
ISLs, and MNA is determined to be inadequate. Treatment is anticipated across the residual plume 1116
with COC concentrations exceeding the ISLs. PetroFix™ or a similar amendment could be used 1117
to remediate dissolved-phase fuel hydrocarbons at UST Site 914 both in the source area and in 1118
areas of the downgradient plume where ISL exceedances occur. This product immobilizes 1119
dissolved-phase contaminants through sorption onto micron-scale activated carbon particles that 1120
adhere to the soil matrix. Fuel hydrocarbons are adsorbed onto the activated carbon and favorable 1121
geochemical conditions are created for microbial colonization and biodegradation degrading the 1122
contaminants in place. 1123
PetroFix™ contains activated carbon for sorption of target COCs and a sulfate and nitrate blend 1124
that serves as additional electron acceptors to promote fuel hydrocarbon biodegradation under 1125
anoxic and anaerobic conditions. The liquid activated carbon amendment quickly remediates 1126
dissolved-phase plumes. Both HGL and APTIM have successfully implemented in situ activated 1127
carbon remedies at other U.S. Air Force installations, such as MacDill AFB (HGL, 2020), Myrtle 1128
Beach AFB (APTIM, 2019), and the former George AFB (APTIM, 2022). 1129
4.3.3 Monitored Natural Attenuation 1130
Site conditions have changed since the last groundwater monitoring event conducted in 2008. The 1131
groundwater at UST Site 914 was hypoxic in November 2023, characterized by low nitrate, low 1132
dissolved iron, and low sulfate. The data suggest that oxygen is being consumed by natural aerobic 1133
biodegradation, but the presence of nitrate suggests that process is possibly limited by the low 1134
concentrations of COCs. In addition to natural attenuation processes reducing both residual and 1135
dissolved mass over time, the change in site conditions may also have contributed to a reduction 1136
in dissolved COCs. Groundwater elevations have decreased in response to several years of below 1137
average precipitation limiting the potential direct contact of groundwater with residual 1138
hydrocarbons in the vadose zone and reducing the leaching potential of contaminant mass in soil. 1139
While natural attenuation is likely occurring, the primary means of reducing the potential for 1140
dissolved COCs in the future is reducing the residual hydrocarbon mass in the unsaturated zone so 1141
that future site condition changes are unlikely to result in a rebound in dissolved COCs. Natural 1142
attenuation alone is an appropriate remedy for the underlying groundwater provided the corrective 1143
action implemented in the vadose zone reduces hydrocarbon mass in unsaturated soil. 1144
4.3.4 Performance Groundwater Monitoring Program 1145
Performance groundwater monitoring will be conducted following startup of the active bioventing 1146
to evaluate the effectiveness of the corrective action and biochemical properties of the aquifer. The 1147
goal of the corrective action is to remove residual LNAPL and COCs in the soil that exceed ISLs. 1148
All COC concentrations in the groundwater were below their respective ISLs during the November 1149
2023 groundwater monitoring event. Groundwater samples will be collected and analyzed for 1150
COCs annually from the three existing monitoring wells to evaluate the performance of the 1151
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U.S. Army Corps of Engineers—Sacramento District
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corrective action and ensure there is not vertical migration of COCs from the vadose zone to 1152
groundwater at concentrations that would result in ISL exceedance. Geochemical parameters will 1153
be analyzed on an annual basis if COCs are detected in the groundwater at concentrations that 1154
exceed ISLs. 1155
The depth to water and depth to product will be gauged prior to initiating well purging and 1156
groundwater sampling activities. This is to provide an accurate potentiometric surface map to 1157
determine the groundwater flow direction. Groundwater samples will not be collected from the 1158
wells containing measurable LNAPL, if observed, due to the potential for contaminating the 1159
groundwater sample. 1160
All samples will be analyzed in the off-site laboratory for the following parameters: 1161
• BTEXN using SW846 8260D, 1162
• TPH-GRO and TPH-DRO using EPA 8015D, 1163
• Nitrate and sulfate using EPA 300.0, and 1164
• Dissolved iron and manganese using SW846 6010C. 1165
The field parameters pH, temperature, conductivity, DO, and ORP and geochemical parameters 1166
nitrate, sulfate, iron, and manganese will be analyzed to assess the biogeochemical properties of 1167
the uppermost aquifer in the impacted zones to evaluate site conditions for MNA or active 1168
bioremediation. The dominant terminal electron-accepting process in petroleum hydrocarbon 1169
biodegradation is aerobic respiration (depletion of DO) and denitrification (depletion of nitrate), 1170
with iron reduction (increase in ferrous iron) and sulfate reduction (decrease in sulfate) 1171
occasionally occurring. The groundwater at UST Site 914 appears hypoxic, characterized by low 1172
nitrate, low dissolved iron, and low sulfate. The data suggests that oxygen is being consumed by 1173
natural aerobic biodegradation, but the presence of nitrate suggests that process is possibly limited 1174
by the low concentrations of COCs. 1175
4.3.5 Land Use Controls 1176
In 2010, UDEQ-DERR authorized an NFA with LUCs for UST Site 914, closing the site in the 1177
LUST program. The current LUCs at UST Site 914 consist of limited access to the site, shallow 1178
groundwater rights restrictions, and construction activity restrictions to prevent exposure to the 1179
residual contamination remaining at the site. The continued presence of residual LNAPL and 1180
detections of ethylbenzene, total xylenes, TPH-GRO, and TPH-DRO in the soil at concentrations 1181
above ISLs will require continued maintenance of LUCs to prevent exposure to residual 1182
contamination. A petition will be submitted to remove the LUCs for Site ST071 once COC 1183
concentrations in the soil and groundwater are below their respective ISLs. 1184
UST Site 914, Release IDs EHVC and ELXI, is regulated under the UDEQ-DERR LUST program. 1185
All future work will be coordinated with the UDEQ-DERR LUST program under the guidance 1186
provided by Utah-certified consultants and samplers, or site closure activities required to remove 1187
LUCs. 1188
Maintaining Compliance with Regulations: LUCs will be maintained during corrective action 1189
activities at the site until existing soil and groundwater contamination above ISLs have been 1190
eliminated. The results of LUC inspections will be included in the Annual HAFB LUC Report. 1191

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W91238-20-C-0014 5-1 January 2025
5.0 CORRECTIVE ACTION IMPLEMENTATION 1193
The selected corrective action includes active bioventing to address residual hydrocarbons, 1194
including LNAPL, in the vadose zone and MNA in the upper most aquifer. Corrective action 1195
implementation will support achievement of site closure in the future. Work will be performed 1196
under the guidance and direction of a Utah-certified UST consultant provided by teaming partner 1197
Wasatch Environmental, Inc. Soil samples will be collected in accordance with Utah 1198
Administrative Code R311-205 for UST Site Assessment Protocols. A detailed description of the 1199
selected corrective action is provided in the sections below. 1200
5.1 FIELD IMPLEMENTATION APPROACH 1201
The proposed sequence of field implementation is listed below. 1202
1. Site preparation 1203
2. Baseline groundwater monitoring 1204
3. Active bioventing 1205
4. System operation and performance monitoring 1206
5.2 SITE PREPARATION 1207
The following tasks will be completed prior to mobilization to the site. 1208
5.2.1 Underground Utilities 1209
An approved Red Stakes excavation permit will be obtained from the Base Civil Engineering Red 1210
Stakes office prior to any intrusive work activities. A third-party utility locator may be used to 1211
clear utilities in high-risk areas. 1212
5.2.2 Permits 1213
Prior to initiating work, appropriate permits and utility clearances will be obtained in accordance 1214
with SOP 00: Site Access, Clearance, and Permit Requirements found in the HAFB ORC UFP-1215
QAPP (HGL-APTIM JV, 2022a). A Base Civil Engineering Work Request (AF IMT 332 Form) 1216
will be submitted to the HAFB UST Site 914 remedial project manager (RPM) for submittal to 1217
HQ AFESC/DEMG 60 days prior to mobilization. A Non-Production Well Application for the 1218
installation of four bioventing and four SVE wells at HAFB UST Site 914 will be submitted to the 1219
Utah Division of Waters Rights to obtain a Start Card 14 days prior to mobilization. 1220
5.3 GROUNDWATER MONITORING 1221
The three existing monitoring wells have been identified for groundwater sample collection in 1222
support of the corrective action. All COC concentrations were below their respective ISLs during 1223
the November 2023 groundwater monitoring event. Groundwater monitoring will be conducted to 1224
monitor the possible groundwater contamination and evaluate the biogeochemical properties of 1225
the aquifer. Groundwater samples will be collected and analyzed for COCs annually from the three 1226
existing monitoring wells to evaluate the performance of the corrective action and ensure there is 1227
not vertical migration of COCs from the vadose zone to groundwater at concentrations that would 1228
result in ISL exceedance. The wells will be gauged for LNAPL using an oil-water interface probe 1229
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-2 January 2025
before purging and sampling. If a well contains free product, a groundwater sample will not be 1230
collected because the sampling equipment would become coated as it passes through LNAPL, 1231
thereby potentially cross contaminating the groundwater sample. As a result, the data from the 1232
well would not be representative of dissolved-phase concentrations in groundwater. 1233
Low-flow purging procedures will be followed during sample collection. The water level within 1234
the well casing will be monitored during purging to ensure that laminar flow to the pump inlet is 1235
occurring. Well stabilization parameters, including temperature, pH, conductivity, DO, ORP, and 1236
turbidity, will be recorded every 5 minutes until stabilization has occurred. Parameters will be 1237
considered stable when three successive readings meet the parameter-specific acceptance criteria 1238
(see SOP 17: Groundwater Sampling for Chemical Analysis in the HAFB ORC UFP-QAPP [HGL-1239
APTIM JV, 2022a]). 1240
A bladder pump will be used to sample the wells using low-flow sampling techniques. New, 1241
unused tubing will be used for each well, and after sampling, the downhole tubing will be left in 1242
the well to minimize contamination during storage. The discharge tubing will be attached to a 1243
flow-through cell with a multi-parameter meter capable of measuring temperature, pH, 1244
conductivity, DO, and ORP. A separate turbidity meter will be used to measure turbidity. 1245
Groundwater samples collected from each monitoring well will be analyzed for TPH -GRO and 1246
TPH-DRO (Method 8015D), and BTEXN (Method 8260D). The geochemical parameters nitrate 1247
(Method 353.3), total and dissolved iron and manganese (Method 6010C), sulfate (Method 9038), 1248
and alkalinity (Method 305.1) will be analyzed on an annual basis only if COCs are detected in 1249
the groundwater at concentrations that exceed ISLs. All sample containers will immediately be 1250
placed on ice following collection and shipped by overnight delivery to the Arvada (Denver) 1251
facility of Eurofins Test America (a DoD ELAP-certified laboratory) for analysis. Sampling 1252
equipment will be decontaminated after each use and between sampling locations. IDW generated 1253
during the groundwater sampling event will be managed in accordance with the HAFB IDW 1254
Management Plan (HGL-APTIM JV, 2022b). 1255
5.4 INSTALLATION OF BIOVENT TREATMENT SYSTEM 1256
The treatment system components will include separate biovent and SVE components incorporated 1257
into a single enclosed, skid-mounted treatment system. The interior of the enclosure will be 1258
constructed to conform to National Electrical Code (NEC) Class I Division II requirements. 1259
Electrical components mounted to the exterior of the enclosure may be suitable for operation in a 1260
non-classified area (no known fire or explosion hazards) unless otherwise required by HAFB. 1261
Preliminary number and locations for the proposed biovent and SVE wells are shown on 1262
Figure 5.1. The process and instrumentation drawing, which includes details on system 1263
components, is presented as Figure 5.2 for the SVE system and Figure 5.3 for the biovent system. 1264
Details of the SVE and biovent wells are illustrated on Figure 5.4 and the trench details is illustrate 1265
on Figure 5.5. 1266
5.4.1 Remediation Well Installation 1267
Four 2-inch diameter SVE wells and four 2-inch diameter biovent wells will be installed at UST 1268
Site 914 using sonic or hollow-stem auger drilling methods as part of the planned remediation 1269
system. The new biovent wells will be approximately 35 feet deep with 10 feet of screen across 1270
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-3 January 2025
the zone with highest residual hydrocarbons as determined based on recent soil sampling. The SVE 1271
wells will be completed to a depth of 40 feet, the bottom 15 feet of which will be screened as 1272
shown on Figure 5.4. The wells will be completed as flush-mounted wells. 1273
The following subsections provide additional details of the planned work activities. 1274
5.4.1.1 Location and Spacing 1275
To maximize the amount of in situ aerobic degradation of petroleum hydrocarbons relative to the 1276
mass removed as vapor, the biovent wells (and associated air injection) will be placed within the 1277
presumed source area where concentrations of residual hydrocarbons are highest. SVE wells will 1278
be placed at the margins of the treatment zone to capture injected vapors to minimize migration 1279
outside of the treatment area. 1280
The biovent wells will have an approximate radius of influence of 12.5 feet. This spacing was 1281
selected to achieve a minimum of one pore volume exchange per day of air, sufficient to maintain 1282
aerobic conditions within the treatment area. SVE wells will be placed at the margins of the 1283
treatment area where they will 1) capture injected vapors to minimize vapor migration, and 2) 1284
minimize the mass of hydrocarbons discharged to the atmosphere. 1285
The SVE wells will be installed around the margin of the treatment area with an estimated 25-foot 1286
radius capture zone, sufficient to capture the air injected from the biovent wells. The anticipated 1287
radius for the biovent and SVE wells are illustrated on Figure 5.6. 1288
Preliminary locations for the new remediation wells are shown on Figure 5.1. The locations are 1289
subject to change based on field conditions, location of existing utilities, and distribution of 1290
LNAPL encountered during the installation of the initial recovery wells. Field decisions will be 1291
made to relocate wells if they need to be moved less than 5 feet from the proposed locations. If the 1292
required location is more than 5 feet, the new proposed locations will be reviewed to evaluate the 1293
effect on system performance prior to installation. 1294
5.4.1.2 Drilling and Installation Procedures 1295
The bioventing and SVE wells will be constructed in accordance with the HAFB ORC UFP-QAPP 1296
(HGL-APTIM JV, 2022a), using Schedule 40 PVC flush-threaded pipe with 2-inch diameter, 1297
Schedule 40 PVC, 0.020-inch mill slot screen. The biovent wells will be constructed using 10 feet 1298
of screen with a total depth of 35 feet bgs. The SVE wells will be constructed using 15 feet of 1299
screen with a total depth of 40 feet bgs. A filter pack consisting of 10/20 grade silica sand will be 1300
placed around the screen and a minimum of 3 feet above it. A minimum thickness of 5 feet 1301
bentonite chip seal will be placed above the sand, hydrated in 6-inch lifts with potable water. The 1302
bentonite chip seal will be allowed to hydrate for a period of at least 2 hours before the high-solids 1303
bentonite grout is added. 1304
Sonic or hollow-stem auger drilling methods will be used for installation of the bioventing and 1305
SVE wells. Drilling will be conducted in accordance with site-specific SOPs as presented in the 1306
HAFB ORC UFP-QAPP (HGL-APTIM JV, 2022a). The on-site HGL-APTIM JV geologist will 1307
create a lithologic log for each boring. 1308
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-4 January 2025
5.4.1.3 Well Completion 1309
Temporary covers or barricades will be placed at the new wells immediately after well installation 1310
for protection until the final well completions are installed. A 2-inch by 2-inch by 2-inch tee will 1311
be installed below grade at all SVE and biovent wells to connect the remediation wells to the 1312
remediation lines. Backfill will be placed and compacted as necessary to bring the grade up for 1313
installation of the 12-inch diameter, H-20 traffic-rated well vault once the remediation lines are 1314
connected to the wellhead. A minimum 6-inch-thick concrete pad will be installed around each 1315
SVE and biovent well, extending a minimum of 12 inches beyond the well vault. Concrete used 1316
for the pads shall have a minimum 28-day compressive strength of 4,000 pounds per square inch 1317
(psi). 1318
5.4.2 SVE Components 1319
The SVE blower, knockout tank, and ancillary equipment will be housed within the treatment 1320
system enclosure. Piping will be installed from each of the four individual SVE wells to the 1321
treatment building and connected inside the building to a manifold header before flowing through 1322
a knockout tank and eventually discharged to the atmosphere by the blower. Flow meters will be 1323
installed on each individual well influent line and on the dilution air line. The SVE blower w ill 1324
discharge directly to the atmosphere, through a discharge vent stack. The system assumes a flow 1325
rate of 40 standard cubic feet per minute (scfm) per well for a total blower capacity of 160 scfm at 1326
80 inches of water vacuum. A 7.5 horsepower (hp) Rotron EN858 blower or equivalent meets the 1327
performance requirements after accounting for the elevation at HAFB. 1328
Air flow will be measured using rotameter type direct read flow meters with a range of 1329
approximately 7 to 70 scfm such as a Chemline FST40000 8.2-74 scfm or equivalent. 1330
While it is not anticipated that significant liquids will accumulate in the knockout tank, a 1 hp 1331
totally enclosed fan-cooled transfer pump will be installed. If after the system is placed in 1332
operation, it is determined that significant volumes of condensate are being produced, the pump 1333
will be used to transfer condensate to a small tank placed next to the system for temporary storage. 1334
Details on SVE system components are presented on Figure 5.2 1335
5.4.3 Biovent Components 1336
The biovent blower and ancillary equipment will be housed within the treatment system enclosure. 1337
Piping will be installed from the individual wells to the treatment building and connected inside 1338
the building. Atmospheric air will be discharged from the biovent blower, through the manifold 1339
header before flowing to the individual wells. Flow meters will be installed on each individual 1340
well influent line and on the dilution air line. A 1.0 hp Rotron EN404 blower or equivalent meets 1341
the performance requirements considering the elevation at HAFB. 1342
Air flow will be measured using rotometer type direct read flow meters with a range of 1343
approximately 1 to 10 scfm such as the Chemline FCT00402 or equivalent. Details on biovent 1344
system components are presented on Figure 5.3 1345
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-5 January 2025
5.4.4 Control Panel 1346
The SVE and biovent equipment will be controlled by a National Electrical Manufacturers 1347
Association Type 4 Control Panel placed in a non-classified area. All wiring which is not 1348
intrinsically safe shall have proper seal offs between the classified and non-classified areas. The 1349
control panel shall have a main disconnect, hour meters, alarm lights, a heater, timers on both the 1350
SVE and biovent blowers and the interlocks listed below. 1351
• If an SVE low vacuum condition occurs, the SVE and biovent systems will shut down. 1352
• If the high-high level control in the SVE knockout tank is reached, the SVE and biovent 1353
system will shut down. 1354
• If the SVE system is not operating, the biovent system will shut down. 1355
5.4.5 Enclosure 1356
The interior of the enclosure will be constructed in order to conform to NEC Class I Division II 1357
requirements. Electrical components mounted to the exterior of the enclosure may be suitable for 1358
operation in a non-classified area unless otherwise required by HAFB. 1359
The enclosure will be insulated with a minimum 1-inch foil backed insulation and will include a 1360
2000 watt hazardous location heater (minimum), hazardous location vent fan with intake guard, 1361
and wall shutters, two floor vents, and a vapor proof light. 1362
5.4.6 Piping/Trenching 1363
UST Site 914 is an active fueling area with existing buried utilities, including pressurized product 1364
lines. Trenching and piping will be carried out by a combination of hand digging, hydrovaccing, 1365
and backhoe as necessary to prevent damage to existing site infrastructure. 1366
The trenches will be a minimum of 2.5 feet below grade unless otherwise required when crossing 1367
existing utilities. The trenches shall be the narrowest width that will allow convenient placement 1368
of the pipe and preparation of the joints while still allowing for backfill around the pipe. No open 1369
trenches will be allowed overnight without security. 1370
Where suitable, excavated material may be used for backfill. Remaining spoils will be 1371
containerized, characterized and disposed of in accordance with the IDW Management Plan (HGL-1372
APTIM JV, 2022b). 1373
All buried and above ground piping will be 2-inch diameter Schedule 40 PVC. Individual lines 1374
will be placed between all wells and the treatment system. Where possible, pipe will be installed 1375
in 20-foot lengths and long sweeps will be used where elbows are required. During installation, 1376
the installation contractor will ensure that pipe, fittings, and joint interiors are free from dirt. Piping 1377
will be capped or plugged when left unattended. 1378
Upon completion of pipe installation, a pressure test will be conducted with air prior to placing the 1379
line in service. The piping will be sealed at both ends and brought up to a pressure of 10 psi ). If 1380
the pressure has dropped more than 2 psi at the end of 30 minutes, repairs to the piping will be 1381
made. Any visible or audible leak will be repaired regardless of the pressure loss . All pressure 1382
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U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-6 January 2025
testing should be conducted prior to backfilling. Details on trench components are presented on 1383
Figure 5.5. 1384
5.4.7 Electrical 1385
As noted above, all components located within the equipment enclosure will conform to NEC 1386
Class 1 Division II hazardous location requirements. All electrical components located outside of 1387
the enclosure will be installed in accordance with HAFB requirements. Once the final location for 1388
the enclosure has been established, the available electrical service will be verified with the UST 1389
Site 914 operators and provided to the original equipment manufacturer. 1390
5.5 VAPOR PERFORMANCE MONITORING 1391
5.5.1 Respiration Tests 1392
In situ respiration tests will be performed initially then annually during application of the remedy 1393
to determine the rate at which soil bacteria degrade petroleum hydrocarbons. A baseline test will 1394
be performed immediately prior to the beginning of treatment and annually thereafter to evaluate 1395
change in degradation rates over time. Respiration tests will be performed at every well where 1396
bacterial degradation of hydrocarbons is noted. These points are characterized by low oxygen 1397
levels and elevated carbon dioxide concentrations in the soil gas. 1398
The test will be initiated by turning off the bioventing system after air has been introduced into the 1399
vadose zone for at least 24 hours. Air will be injected at each point containing low levels of oxygen 1400
(below 5%, approximately) for a 12-hour period to oxygenate local contaminated soils. At the end 1401
of the 12-hour air injection period, the air supply will be cut off and oxygen and carbon dioxide 1402
levels will be monitored for the following 48 hours. The monitoring points will be purged for 20 1403
minutes and the biovent and SVE wells will be purged for 1 minute prior to sampling using a 1 1404
scfm vacuum pump and analyzed in the field using portable gas analyzers. 1405
Concentrations of oxygen, carbon dioxide, and petroleum hydrocarbons will be measured over 1 1406
to 2 days. Measurements will be taken hourly during the first 12 hours of monitoring but can be 1407
spaced at greater intervals for the remainder of the test. (Note: If the petroleum fuel source is easily 1408
biodegradable (fresh gasoline), then measurements must be taken at relatively short intervals, and 1409
the test duration will be less than if the source is difficult to degrade (weathered motor oil), 1410
requiring longer test duration and generally longer intervals between measurements.) The test will 1411
be concluded when the oxygen concentration drops to below 5% or after 5 days, whichever occurs 1412
first. The biodegradation rate will be calculated based on the oxygen or carbon dioxide utilization 1413
rate. 1414
5.5.2 Air Permit Testing 1415
Under Utah Administrative Code R307-401-15 for Air Strippers and Soil Venting Projects, an air 1416
emissions permit is not required if emissions of total VOCs are less than 5 tons per year (10,000 1417
pounds) and the level of each hazardous air pollutant is below the emission threshold values 1418
derived for that contaminant as described in Utah Administrative Code R307- 410-5(1)II(C). The 1419
bioventing system will be managed to promote in situ biodegradation of the petroleum 1420
hydrocarbons while minimizing the release of VOCs. Mass of TPH recovered monthly by the SVE 1421
system will be calculated from the TPH analytical results multiplied by the total air volume 1422
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U.S. Army Corps of Engineers—Sacramento District
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removed multiplied by a conversion factor to convert from parts per billion by volume to pounds 1423
per cubic meter. Mass removal from the SVE system and operation details will be provided in a 1424
tabular format. The mass of TPH and individual hazardous air pollutant will be evaluated to verify 1425
that concentrations are below the emission threshold values. 1426
5.5.3 Startup and Performance Monitoring 1427
Startup and Performance Monitoring Requirements are listed below. 1428
• Field monitoring: Field monitoring will occur daily at startup for the first week, then 1429
weekly for 2 months, then monthly during the duration of the system operation. Monitoring 1430
may occur more frequently if PID readings start and stay high enough to raise concerns 1431
regarding mass removal rates. 1432
• Effluent sample: An effluent vapor laboratory sample will be collected at the end of the 1433
first week to verify emissions discharged from the SVE system. The system will be down 1434
until the results are received and reviewed. The system operations will be adjusted, as 1435
necessary, based on the laboratory results before restarting. 1436
• Field testing: Gas concentration readings (VOCs, oxygen, and carbon dioxide) will be 1437
collected from each vapor recovery (SVE) well at the well head and of the combined 1438
discharge from the SVE header upgradient of dilution valves. Concentrations will be 1439
measured using a field gas analyzer. 1440
• Laboratory analysis: An air emission sample will be collected each month from the 1441
combined discharge for air permit compliance purposes. 1442
5.6 OPERATION AND MAINTENANCE 1443
Following completion of the system installation, the system will be started in a manner designed 1444
to evaluate the system coverage and to collect the data necessary to optimize performance, which 1445
means maximizing mass destruction via aerobic biodegradation while minimizing discharge of 1446
vapors to the atmosphere. 1447
5.6.1 Startup Procedure 1448
Startup of the SVE/biovent system will follow the general procedures listed below. 1449
1. Inspect all piping, piping connections, valve settings, and electrical connections. 1450
2. Start SVE blower with all valves fully opened to verify proper flow direction, then begin 1451
operation at design flows. 1452
3. Collect flow and pressure readings for each SVE well. 1453
4. Collect gas concentration readings (VOCs, oxygen, and carbon dioxide) from each vapor 1454
recovery well and from the blower discharge line. 1455
5. Check biovent wells and adjacent monitoring wells for vacuum influence. 1456
6. Simulate high knockout tank level to verify proper operation of the sensor. 1457
7. Monitor fluid level in the knockout tank. 1458
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-8 January 2025
8. Following startup of the SVE system, begin operation of the biovent blower. After 1 hour 1459
of operation, recheck gas concentration readings from each recovery well and check 1460
adjacent monitoring wells for vacuum influence. 1461
9. Leave the system operating overnight and recheck gas concentration readings on a regular 1462
basis until concentrations have stabilized. Adjust SVE and biovent flow rates as necessary 1463
to minimize mass removal via SVE while effectively distributing oxygen within the 1464
treatment zone. 1465
The performance goals to be achieved during startup activities are to: 1466
• Collect data to evaluate mass removal rates via biodegradation; 1467
• Minimize mass removal rates through vapor extraction and the potential for vapor 1468
migration while maximizing the biodegradation rate; and 1469
• Collect gas concentration readings to evaluate performance. 1470
In general, the goal will be to run the SVE system at the minimum rate necessary to demonstrate 1471
vacuum influence at the nearest biovent well. 1472
Mass removal via SVE is expected to decline quickly after startup. Changes in oxygen and carbon 1473
dioxide concentrations are likely to occur at a slower rate as aerobic activity is established. Startup 1474
will be considered complete when 1) SVE concentrations have stabilized and long-term flow rates 1475
have been established for the SVE system, and 2) concentrations of carbon dioxide have stabilized. 1476
Thus, the startup activities are likely to extend over a period of weeks where vapor concentrations 1477
are monitored on a daily basis (first week of operation) and then weekly, until concentrations 1478
stabilize. 1479
5.6.2 Operation and Maintenance Activities 1480
At a minimum, the site will be visited on a monthly basis during system operation. More frequent 1481
visits may be required to respond to system alarms and restart the systems. Operation and 1482
maintenance activities to be performed during each monthly visit generally consist of the 1483
following: 1484
• Visually inspect the blower, looking for unusual or excessive noise or vibration, leaking oil, 1485
overheating, reduced flow, or excessive inlet vacuum or discharge pressure; 1486
• Check and record fluid level in the knockout tank, pump out as needed; 1487
• Record flow rates and vacuum levels from SVE wells, and flow rates and pressure levels 1488
from biovent wells; 1489
• Collect gas concentration readings from each SVE recovery well and from the SVE blower 1490
discharge line. In addition to VOC readings, oxygen and carbon dioxide concentrations will 1491
be collected to evaluate the rate of aerobic biodegradation that is occurring within the 1492
treatment zone; 1493
• Check pressure loss at inline filters, replace as needed; 1494
• Visually inspect all SVE and biovent lines for damage or leaks, repair as needed; 1495
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-9 January 2025
• Adjust SVE and biovent well flow rates as needed to optimize system performance; 1496
• Gauge adjacent monitoring wells to determine depth to water; and 1497
• Perform any required maintenance in accordance with manufacturer’s recommendations. 1498
Once system startup has been completed and the mass discharge to the atmosphere has been 1499
minimized, few changes to system operation are anticipated. Long term monitoring will track the 1500
rate of mass removal and will calculate the mass of petroleum hydrocarbons destroyed via aerobic 1501
biodegradation. The mass destruction will be estimated using both the increase in carbon dioxide 1502
in the SVE discharge (above atmospheric concentrations) and the reduction in oxygen in the SVE 1503
discharge (below atmospheric conditions). 1504
After a maximum of 1 year of operation, rebound testing will be conducted to evaluate the change 1505
in mass removal rates when compared to startup. The rebound testing will consist of shutting the 1506
system down for a minimum of 1 week, then repeating the startup procedures. The rate of mass 1507
removal and change in the rate of aerobic biodegradation will be evaluated and included in the 1508
annual operations and maintenance report. 1509
5.7 SITE CLOSURE CRITERIA 1510
The bioventing system will be operated until the following criteria have been achieved: 1511
• COC concentrations in the groundwater remain below the ISLs; 1512
• Air oxygen concentrations in the UST Site 914 wells remain above 10% for 48 hours 1513
following turning the bioventing system off; 1514
• No significant rebound is observed in the SVE wells after the bioventing system is off for 1515
a minimum of 1 week, then repeating the startup procedures; and 1516
• Respiration tests indicate less than 0.01% oxygen loss per minute. 1517
Bioventing operations will be discontinued if significant difficulties or poor results are 1518
encountered with bioventing at this site. At which point, removal of the blower system and proper 1519
abandonment of the vent wells will be recommended. 1520
5.8 SITE RESTORATION 1521
All disturbed areas will be restored to their prior condition following completion of the corrective 1522
action. Unimproved areas disturbed by drilling or trenching activities shall remain unimproved. 1523
Penetrations through hard surfaces such as pavement will be patched with similar materials 1524
(concrete or asphalt patch). Field personnel shall make efforts not to disturb unnecessarily large 1525
areas during soil and groundwater sampling activities. The ground disturbance typically produced 1526
by these activities will not limit the natural regrowth of the existing vegetation. No reseeding or 1527
revegetation procedures will be performed at the site under typical conditions unless directed by 1528
the HAFB Site ST071 RPM. The site restoration activities will be performed per the procedures 1529
in SOP 5: Site Restoration found in the HAFB ORC UFP-QAPP (HGL-APTIM JV, 2022a). 1530
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 5-10 January 2025
5.9 SCHEDULE 1531
Field activities are scheduled to start in March 2025 and will include baseline groundwater 1532
monitoring (1 week), the installation of four SVE and four biovent wells (1 month), and 1533
performance monitoring from selected monitoring wells (1 week). The anticipated schedule for 1534
the field activities is listed below: 1535
• Baseline groundwater monitoring: March 2025 1536
• Site preparation: Within 30 days following completion of baseline groundwater monitoring 1537
• SVE/biovent well installation: April 2025 1538
• Active biovent system installation: Approximately 60 days following receipt of baseline 1539
groundwater monitoring data 1540
• Performance vapor monitoring: Monthly monitoring following system startup 1541
• Respiration testing: Annually following the initial respiration tests conducted as part of the 1542
system startup 1543
• Performance groundwater monitoring: Annual monitoring (starting 1 year following 1544
system startup) 1545
5.10 REPORTING 1546
A Corrective Action Implementation Report will be submitted following the completion of 1547
baseline groundwater sampling, SVE/biovent well installation, active biovent system installation, 1548
and 1 year of performance monitoring. 1549
Annual performance monitoring reports will be submitted for subsequent years and will include a 1550
cumulative summary of the data, measurement of corrective action performance against the 1551
corrective action objectives, and future recommendations. 1552
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, UT

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 6-1 January 2025
6.0 PUBLIC NOTICE 1553
Potentially affected communities will be notified prior to implementing the new CAP Addendum 1554
or any changes to the CAP. UST Site 914 is located within a security-controlled area of HAFB 1555
and those potentially impacted are primarily Air Force employees working in or near this industrial 1556
area. The site is approximately 2000 ft from on-Base housing and 3000 ft from the HAFB 1557
boundary. A notice will be printed in The Hilltop Times (HAFB newspaper) advising residents of 1558
a change to the CAP Addendum. The notice will be published 30 days prior to the implementation 1559
of the new CAP Addendum. Any public input will be taken under advisement prior to 1560
implementation of the modified CAP Addendum. 1561

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HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, Utah

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 7-1 January 2025
7.0 REFERENCES 1563
APTIM Federal Services LLC (APTIM), 2019. Corrective Measure Completion Report Building 1564
505 (SWMU 79/80) Myrtle Beach Air Force Base, South Carolina. April. 1565
APTIM, 2022. Final Report, PlumeStop™ Remediation Optimization Evaluation at Well EW-06 1566
Operable Unit 1, Site CG070 Former George Air Force Base, Victorville, California. July. 1567
CH2M Hill, 2002. Corrective Action Plan Underground Storage Tank Site 914 UDEQ-DERR 1568
LUST Site “EHVC.” Hill AFB, Utah. July. 1569
CH2M Hill, 2005a. Underground Storage Tank Program 2004 Summary Report for Site 914, 1570
UDEQ LUST Site EHVC. Hill AFB, Utah. May. 1571
CH2M Hill, 2005b. Subsurface Investigation Report for UST Site 914 (Release Site IDs “EHVC” 1572
& “ELXI”). Hill AFB, Utah. May. 1573
CH2M Hill, 2008a. Draft Underground Storage Tank Program 2007 Summary Report for Site 1574
914, UDEQ LUST Site EHVC and ELXI. Hill AFB, Utah. February. 1575
CH2M Hill, 2008b. Letter Report for Closure of Underground Storage Tank Site 914 UDEQ-1576
DERR LUST Sites EHVC and ELXI, Hill AFB, Utah. May. 1577
CH2M Hill, 2010. UST Site 914 2009 Groundwater Elevation and Free Product Monitoring. Hill 1578
AFB, Utah. April. 1579
HydroGeoLogic, Inc (HGL), 2020. Remedial Action Plan (RAP) Addendum, ST057, Flightline 1580
Fueling System, Former Fuel Hydrants/Pits 16-25, Revision 2, MacDill Air Force Base 1581
(MARB), Florida. October. 1582
HydroGeoLogic, Inc.-APTIM Federal Services, LLC Joint Venture (HGL-APTIM JV), 2021a. 1583
Final Accident Prevention Plan for Optimized Remediation Contract at Hill Air Force 1584
Base, Utah, March. 1585
HGL-APTIM JV, 2021b. Final Supplemental Site Investigation Work Plan for Site ST071, Hill 1586
Air Force Base Utah, Contract No. W91238-20-0014, September. 1587
HGL-APTIM JV, 2022a. Quality Program Plan, Final Uniform Federal Policy Quality Assurance 1588
Project Plan for Optimized Remediation Contract at Hill Air Force Base, Utah. April. 1589
HGL-APTIM JV, 2022b. Final Waste Management Plan for Optimized Remediation Contract at 1590
Hill Air Force Base Utah. April. 1591
HGL-APTIM JV, 2023. Final Site ST071 Corrective Action Plan for Hill Air Force Base Utah. 1592
April. 1593
Montgomery Watson (MW), 1994. Corrective Action Plan for UST Site 914 (5T71; EHVC). Hill 1594
AFB, Utah. January. 1595
HGL-APTIM JV—Corrective Action Plan Addendum, Site ST071—Hill Air Force Base ORC, Utah

U.S. Army Corps of Engineers—Sacramento District
W91238-20-C-0014 7-2 January 2025
USAF, 2020. Optimized Exit Strategy Effectiveness Report, Surfactant-Enhanced Removal of 1596
LNAPL, Site ST025, Little Rock AFB, Arkansas, June. 1597
Ogden Air Logistics Center, 1994. Decision Document for Site 5T71 Building 914 UST Fuel 1598
Release. Hill AFB, Utah. July. 1599
Utah Administrative Code Section R307-401-15 – Air Strippers and Soil Venting Projects. 1600
Utah Administrative Code Section R307-410-5 – Documentation of Ambient Air Impacts for 1601
Hazardous Air Pollutants. 1602
Utah Administrative Code Section R311-205 – Underground Storage Tanks: Site Assessment 1603
Protocol. 1604
Utah Department of Environmental Quality (UDEQ), 2010. No Further Action, Leaking 1605
Underground Storage Tank Release. Hill AFB, Utah. March. 1606

TABLES

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Table 2.1
Historical Soil Data Summary from UST Site 914
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
5,000 1,500 900 25,000 23,000 142,000 51,000
T-914-202 27.5-28 8/16/1993 150 NA 43,000 270,000 130,000 580,000 33,000
T-914-203 28.5-29 8/17/1993 8,900 NA 51,000 280,000 110,000 880,000 ND
T-914-006 30- 32.5 4/8/1995 11,200 NA 2,720 2,040 45,700 240,000 13,200
T-914-003 32.5-35 8/8/1995 1,850 NA ND 82 ND 16,600 1,100
T-914-008 37.5-40 3/31/1997 838 NA 2,640 20,000 25,000 149,000 8,110
T-914-950 24.5-26 7/27/1999 4T ND ND ND ND 1 T ND
T-914-950 26.5-28 7/27/1999 ND ND ND ND ND 2.8 T ND
T-914-950 28.5-31 7/27/1999 350 ND 90 70 320 2,350 100
T-914-951 27-28 7/27/1999 3T ND ND ND ND 0.8 T ND
T-914-951 29.5-31 7/27/1999 350 T ND ND 1,800 T 6,000 57,000 4,000
T-914-952 28-30 7/27/1999 700 ND ND 550T 710 T 8,200 1,100 T
T-914-953 25.5-27 7/28/1999 120 ND ND ND 290 2,350 100
T-914-954 30-32 7/28/1999 6T ND ND ND ND ND ND
T-914-954 34-36 7/28/1999 ND ND ND ND ND ND ND
T-914-954 40-42 7/28/1999 11 T ND ND 200T 360 T 3,790 140 T
T-914-955 30-32 7/28/1999 7T ND ND ND ND ND ND
T-914-956 32-34 7/29/1999 2T 11 ND ND ND ND ND
T-914-957 30-32 7/29/1999 46 5T ND ND 140 1,130 130
T-914-957 37-39 7/29/1999 440 ND ND 870T 1,500 T 16,000 730T
T-914-963 28.5-30 8/2/1999 65 ND ND ND 0.8 T 12 T ND
T-914-964 25.8-26.5 8/2/1999 65 ND ND ND 2,000 18,100 540T
T-914-707 30-32 12/5/2001 634 NA U 644.1 U 825.4 J 9,000 J 103,000 J 7,500
T-914-710 38-40 12/5/2001 134 NA U 69.2 U 88.7 U 96.6 J 1,190 J 560
T-914-706 32-36 12/6/2001 J 11.3 NA U 66.2 U 84.8 3,700 27,800 1,500
T-914-708 28-30 12/6/2001 14 NA U 0.6 U 0.8 J 1.4 17 U 1
T-914-709 28-30 12/6/2001 J 11 NA J 1.4 J 2.4 U 0.85 U 2.47 U 1.03
T-914-712 30-32 12/21/2004 881 3,886 4,490 111,500 50,090 449,400 8,176
T-914-712 34-36 12/21/2004 1,803 4,170 J 385.8 21,030 16,010 151,110 3,099
T-914-711 30-31 1/5/2005 468 1,103 ND ND 61,520 589,300 J 11,980
T-914-711 39-40 1/5/2005 933 4,799 ND ND 15,100 146,280 J 3,992
T-914-714 30-31 1/5/2005 138 J 106.8 ND J 638.7 J 3,369 33,965 J 1,476
T-914-722 30-31 1/5/2005 291 824 ND ND J 3,866 33,729 J 2,365
T-914-718 30-31 1/6/2005 ND ND ND ND ND ND ND
T-914-720 30-32 1/6/2005 ND ND ND ND ND ND ND
T-914-720 37-40 1/6/2005 ND ND ND ND ND ND ND
T-914-713 21-24 1/7/2005 J 3.58 ND ND ND ND ND ND
T-914-713 28-32 1/7/2005 248 474.1 ND ND 1,086 J 7,115.6 727.8
T-914-719 21-24 1/7/2005 ND ND ND ND ND ND ND
T-914-719 32-34 1/7/2005 J 4.17 ND ND ND ND ND ND
Notes:
*Current Utah UST Tier 1 Standards from November 1, 2005 NA = not applicable
Bold and shaded values indicate an exceedance of the Tier I screening levels.ND = not detected
µg/kg = micrograms per kilogram SVE = soil vapor extraction
mg/kg = milligrams per kilogram T = analyte detected between the method detection limit and the
bgs = below ground surface practical quantitation limit
ft = foot/feet TPH-DRO = total petroleum hydrocarbon-diesel range organics
ID = identification TPH-GRO = total petroleum hydrocarbon-gasoline range organics
UST = underground storage tank
Toluene
(µg/kg)
Ethylbenzene
(µg/kg)
Total
Xylenes
(µg/kg)
Napthalene
(µg/kg)
J = estimated value; The analyte was detected, but the reported value may
not be accurate or precise.
U = not detected; The analyte was analyzed, but was not detected
above the method detection limit.
TIER I SCREENING LEVELS*
PRE-SVE SYSTEM OPERATION
DURING SVE SYSTEM OPERATION
POST-SVE SYSTEM OPERATION
Location ID
Depth
Interval
(ft bgs)Date
TPH-DRO
(mg/kg)
TPH-GRO
(mg/kg)
Benzene
(µg/kg)
Page 1 of 1
Table 2.2
Free Product Removal from Monitoring Wells at UST Site 914 - 2003-2008
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
T-914-PTW1 T-914-PTW2 T-914-202 T-914-203 T-914-006
1/10/2003 0.55 0 0 0.71 NA
4/14/2003 0.4 0.08 0 0 NA
7/18/2003 0.26 0 0 0 NA
12/5/2003 0.61 0 0 0.13 NA
2003 ANNUAL TOTAL 1.82 0.08 0 0.84 0
2/27/2004 0.21 0 0 0.13 NA
4/12/2004 0.32 0 0 0.16 NA
7/26/2004 0.95 0 0 0.21 NA
10/8/2004 1.19 0 0 0.66 NA
10/17/2004 0 NA NA 0 NA
10/22/2004 0 NA NA 0 NA
10/29/2004 0 NA NA 0 NA
11/5/2004 0 NA NA 0 NA
12/3/2004 0 NA NA 0 NA
2004 ANNUAL TOTAL 2.67 0 0 1.16 0
1/11/2005 0.01 0 0 0.2 NA
2/11/2005 0.07 0 0 0.05 NA
3/18/2005 0 0 0 0 NA
4/22/2005 0 0 0 0 NA
5/20/2005 0 0 0 0 NA
8/26/2005 0 0 0 0 NA
10/31/2005 0 0 0 0 NA
12/2/2005 0 0 0 0 NA
2005 ANNUAL TOTAL 0.07 0 0 0.25 0
1/30/2006 0.03 0 0 0.01 NA
4/28/2006 0 0 0 0 NA
7/28/2006 0 0 0 0.02 NA
12/15/2006 0 0 0 0 NA
2006 ANNUAL TOTAL 0.03 0 0 0.03 0
3/20/2007 0 0 0 0 0
6/29/2007 0 0 0 0 0
9/28/2007 0 0 0 0 NA
2007 ANNUAL TOTAL 0 0 0 0 0
1/8/2008 0 0 0 0 NA
2008 ANNUAL TOTAL 0 0 0 0 0
GRAND TOTAL 4.59 0.08 0 2.28 0
Notes:
*Table data come from the Letter Report for Closure of UST Site 914 (CH2M Hill, 2008b)
gal = gallon
NA = not applicable
UST = underground storage tank
Free Product Removed (gal)Date
Page 1 of 1
Table 2.3
Free Product Levels from UST Site 914 - 2009
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Date
Monitoring
Point
Product Level
(ft bTOC)
Water Level
(ft bTOC)
Product
Thickness
(ft)
31-Mar-09 T-914-PTW1 30.08
T-914-PTW2 29.52
T-914-202 26.8
T-914-203 Sheen 28.78 Sheen
T-914-006 NM
30-Jun-09 T-914-PTW1 28.32
T-914-PTW2 26.9
T-914-202 25.7
T-914-203 27.13 27.16 0.03
T-914-006 45.13
22-Sep-09 T-914-PTW1 28.04
T-914-PTW2 26.42
T-914-202 25.16
T-914-203 26.7 26.71 0.01
T-914-006 45.06
31-Dec-09 T-914-PTW1 30.14
T-914-PTW2 28.18
T-914-202 26.45
T-914-203 Sheen 28.38 Sheen
T-914-006 NM
Notes:
ft = feet/foot
NM = not measured
bTOC = below top of casing
UST = underground storage tank
Page 1 of 1
Table 2.4
UST Site 914 Groundwater Data Summary - 2000-2008
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
GW Elevation Benzene Toluene Ethylbenzene Xylenes, Total Naphthalene TPH-Diesel TPH
(feet) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (mg/L) (mg/L)
5 1,000 700 10,000 700 1,000 1,000
300 3,000 4,000 10,000 700 10,000 10,000
3/16/2000 NM NM NM 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.3 TA NS
6/22/2000 28.87 4688.13 ND NA NA NA NA NA NA NA
3/23/2001 29.68 4687.32 ND 0.1 U 0.1 U 0.1 U 0.2 U 0.2 U 0.357 B NS
2/6/2002 29.42 4687.58 ND NA NA NA NA NA NA NA
2/8/2002 NM NM NM 0.1 U 0.1 U 0.1 U 0.3 U 0.2 U 0.514 J NS
3/16/2000 NM NM NM DRY DRY DRY DRY DRY DRY NS
6/22/2000 43.66 4672.34 ND NA NA NA NA NA NA NA
2/4/2002 43.72 4672.28 ND DRY DRY DRY DRY DRY DRY NS
1/28/2002 44.72 4668.28 ND NA NA NA NA NA NA NA
1/29/2002 NM NM NM J 44.9 J 2.1 97.4 2185 U 1.7 NA NS
3/16/2000 NM NM NM 2500 U 2500 U 370 6500 2500 U 220 A NS
6/22/2000 36.25 4679.75 ND NA NA NA NA NA NA NA
3/23/2001 39.62 4676.38 ND DRY DRY DRY DRY DRY DRY NS
2/4/2002 DRY DRY DRY DRY DRY DRY DRY DRY DRY NS
3/16/2000 NM NM NM 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.1 TA NS
6/22/2000 46.59 4666.41 ND NA NA NA NA NA NA NA
3/23/2001 47.06 4665.94 ND 0.1 U 0.1 U 0.1 U 0.2 U 0.2 U 0.17 B NS
1/28/2002 47.42 4665.58 ND NA NA NA NA NA NA NA
1/29/2002 NM NM NM 0.1 U 0.1 U 0.1 U 0.3 U 0.2 U 0.22 J NS
T-914-007 2/4/2002 DRY DRY DRY DRY DRY DRY DRY DRY DRY NS
T-914-008 2/4/2002 DRY DRY DRY DRY DRY DRY DRY DRY DRY NS
3/16/2000 NM NM NM 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.1 TA NS
6/22/2000 54.03 4651.97 ND NA NA NA NA NA NA NA
3/23/2001 54.32 4651.68 ND U 0.1 U 0.1 U 0.1 U 0.2 U 0.2 B 0.472 NS
2/4/2002 54.21 4651.79 ND U 0.1 J 0.2 U 0.2 U 0.3 U 0.2 UB 0.18 NS
3/16/2000 NM NM NM 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.1 TA NS
6/22/2000 48.15 4659.85 ND NA NA NA NA NA NA NA
3/23/2001 48.71 4659.29 ND 0.1 U 0.1 U 0.1 U 0.2 U 0.2 U B 0.08 NS
2/6/2002 49.59 4658.41 ND 0.1 U 0.2 J 0.2 J 0.3 U 0.2 U 0.51 UB NS
7/3/2003 49.71 4658.29 ND NA NA NA NA NA NA NA
7/28/2003 NM NM NM U 0.1 U 0.1 U 0.1 U 0.3 U 0.2 U 0.1 NS
6/28/2004 50.5 4657.5 ND U 0.1 U 0.2 U 0.2 U 0.3 U 0.2 U 0.1 NS
7/29/2005 49.7 4658.3 ND U 0.2 U 0.2 U 0.2 U 0.5 U 0.1 U 0.1 NS
6/19/2006 48.82 4659.18 ND U 0.1 UB 0.2 U 0.1 U 0.3 U 0.1 U 0.1 NS
7/13/2007 48.95 4659.05 ND U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 NS
10/9/2008 48.38 4660 ND U 0.1 U 0.1 U 0.1 U 0.2 U 0.05 J 0.02 NS
T-914-015
Initial Screening Levels*
T-914-002
T-914-003
T-914-006
T-914-005
T-914-004
Tier I Screening Levels*
Location Date
DTW
(feet)
FP
(feet)
T-914-009
Page 1 of 2
Table 2.4 (Continued)
UST Site 914 Groundwater Data Summary - 2000-2008
Corrective Action Plan Addendum for ST071
UST Site 914, Hill Air Force Base, Utah
GW Elevation Benzene Toluene Ethylbenzene Xylenes, Total Naphthalene TPH-Diesel TPH
(feet) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (mg/L) (mg/L)Location Date
DTW
(feet)
FP
(feet)
3/16/2000 NM NM NM 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.1 TA NS
6/22/2000 51.46 4660.54 ND NA NA NA NA NA NA NA
3/23/2001 NM NM NM NS NS NS NS NS NS NS
2/6/2002 51.95 4660.05 ND U 0.1 U 0.1 U 0.2 U 0.3 U 0.1 UB 0.14 NS
7/3/2003 53.26 4658.74 ND NA NA NA NA NA NA NA
7/25/2003 NM NM NM U 0.1 U 0.1 U 0.1 U 0.3 U 0.2 U 0.1 NS
6/29/2004 54.18 4657.82 ND U 0.1 U 0.2 U 0.2 U 0.3 UJ 0.2 U 0.1 NS
7/29/2005 53.18 4658.82 ND U 0.1 U 0.2 U 0.2 U 0.5 U 0.1 U 0.1 NS
6/19/2006 52.4 4659.6 ND U 0.1 U 0.1 U 0.1 U 0.3 U 0.1 U 0.1 NS
7/2/2007 52.6 4659.4 ND U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 NS
10/9/2008 53.05 4659 ND U 0.1 U 0.1 U 0.1 U 0.2 U 0.05 J 0.03 NS
3/16/2000 NM NM NM 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.07 TA NS
3/23/2001 NM NM NM NS NS NS NS NS NS NS
2/4/2002 NM NM NM U 0.1 J 0.2 U 0.2 U 0.3 J 0.2 UB 0.29 NS
7/3/2003 28.82 4740.24 ND NA NA NA NA NA NA NA
7/25/2003 NM NM NM U 0.1 U 0.3 U 0.1 U 0.6 U 0.2 U 0.1 NS
6/29/2004 26.3 4742.76 ND U 0.1 U 0.2 U 0.2 U 0.3 UJ 0.2 J 0.15 NS
7/29/2005 24.55 4744.51 ND U 0.2 U 0.2 U 0.2 U 0.5 U 0.1 J 0.17 NS
6/19/2006 NM NM NM U 0.1 UB 0.2 U 0.1 U 0.3 U 0.1 J 0.19 NS
6/20/2006 24.98 4744.08 ND NA NA NA NA NA NA NA
7/2/2007 27.8 4741.26 ND U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 NS
10/9/2008 25.87 4743 ND U 0.1 U 0.1 U 0.1 U 0.2 U 0.05 J 0.15 NS
Notes:
* Current Utah UST Tier 1 and Initial Screening Level Standards effective May 15, 2006. NA = not analyzed
Bold indicates analyte was detected above the Tier 1 screening level.ND = not detected
µg/L = micrograms per liter NM = not measured
mg/L = milligrams per liter NS = not sampled
A = unknown mixture in diesel/motor oil range T = analyte detected between the method detection limit and the practical quantitation limit.
Dry = water not present or insufficient water to sample TPH = total petroleum hydrocarbons
DTW = depth to water U = not detected above listed detection limit
FP = free product UB = analyte not detected at or above the indicated concentration due to blank contamination.
GW = groundwater UJ = estimated detection limit
J = estimated value UST = underground storage tank
T-914-016
T-914-MW1
Page 2 of 2
Table 2.5
Detected Compounds in Subsurface Soil - SSI April/May 2022
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Location
Cell Number
Sample Date
Media
Sample Depth (ft bgs) UDEQ DERR ISLs
Analyte (µg/kg)
1,1,2-Trichloroethane 5,000*9,700 2,000 U 1,600 U 10,000 U 10,000 J 1,500 U
Ethylbenzene 5,000 7,200 6,000 10,000 47,000 12,000 J 1,700 J
m-Xylene & p-Xylene --- 47,000 39,000 48,000 380,000 94,000 J 12,000
Naphthalene 51,000 2,400 J 3,100 U 2,100 J 16,000 U 16,000 U 2,300 U
o-Xyene --- 400 U 500 U 1,600 J 100,000 J 27,000 J 3,700
Xylenes, total 142,000 47,000 39,000 50,000 480,000 120,000 J 16,000
GRO (C6-C10) 150,000 1,000,000 J 460,000 J 1,400,000 J 9,600,000 J 3,600,000 J 260,000 J
DRO (C10-C28 500,000
2,300,000 J 1,200,000 J 600,000 1,300,000 1,800,000 J 1,700,000
Notes:
* Regional Screening Level, Residential Soil
Bold and shaded = value above ISL
µg/kg = micrograms per kilogram
bgs = below ground surface
DERR = Division of Environmental Response and Remediation
DRO = diesel range organics
FD = field duplicate
ft = feet/foot
GRO = gasoline range organics
ISL = initial screening level
J = value is estimated
SO = subsurface soil
SSI = Supplemental Site Investigation
U = analyte was analyzed for but not detected.
UDEQ = Utah Department of Environmental Quality
UST = underground storage tank
ST071SO-05
5/9/2022
SO
30-35
ST071SO-04
30-35
Results (µg/kg)
E1
Results (µg/kg)
B1
Results (µg/kg)
D1 C1
5/9/2022
SO
30-35
Results (µg/kg)
5/9/2022
SO
30-35
ST071SO-03
33-35 33-35
Results (µg/kg) Results (µg/kg)
ST071SO-01 ST071SO-01-FD
4/13/2022 4/13/2022
SO SO
F1 F1
ST071SO-02
5/9/2022
SO
Page 1 of 1
Table 2.6
Detected Compounds in Groundwater - SSI April 2022
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Location
Cell Number
Sample Date
Media
Sample Depth (ft bgs)
Analyte (µg/L)
1,3,5-Trimethylbenzene 5,900* 720
Acetone 18,000* 56 J
Carbon disulfide 810* 4 J
Chloroform 0.22*4 J
Ethylbenzene 5*820
Naphthalene 700 170
Toluene 700 8.4 J
m-Xylene & p-Xylene --- 10,000 J
o-Xylene --- 870 J
Xylenes, total 10,000 11,000 J
GRO (C6-C10)1,000 25,000 J
Notes:
* Regional Screening Level, Residential Tap Water
Bold and shaded = value above ISL
µg/L = micrograms per liter
bgs = below ground surface
DERR = Division of Environmental Response and Remediation
ft = feet/foot
GRO = gasoline range organics
GW = groundwater
ISL = initial screening level
J = value is estimated.
SSI = Supplemental Site Investigation
UDEQ = Utah Department of Environmental Quality
UST = underground storage tank
Results (µg/L)
E2
UDEQ DERR ISLs
ST071GW-E2
4/13/2022
GW
30-35
Page 1 of 1
Table 3.1
Field Screening Data Summary - July 2023
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Range of Sample Core Sample
Boring Response LNAPL Sample Interval Interval PID Depth PID Sample DTW TD Proposed
Location %ft bgs Date ft ft ppmv ft ppmv Sample ID Date ft ft Well ID Comments
ST071-OIP-01 90 26.5-38 7/14/2023 34.5-35.5 32-36 345.7 34.5 345.7 ST071-GW-OIP-01 7/26/2023 45.82 45.00 T-914-018
ST071-OIP-02 21.5 25-28 7/17/2023 27-28 24-28 ---------ST071-GW-OIP-02 7/26/2023 45.82 50.00
ST071-OIP-03 60 25-32 7/17/2023 24.5-25.5 24-28 ---------ST071-GW-OIP-03 7/26/2023 46.19 50.00 T-914-017
ST071-OIP-04 31.5 25-35 7/17/2023 32-33 28-32 ---------ST071-GW-OIP-04 7/26/2023 47.69 55.00
ST071-OIP-05 32 28-44.5 7/14/2023 30-31 28-32 1824 30.5 1824 ST071-GW-OIP-05 7/26/2023 47.35 55.00
ST071-OIP-06 80 26-43.5 7/18/2023 33-34 30-34 335.4 34 335.4 ST071-GW-OIP-06 7/25/2023 NM 55.00
ST071-OIP-07 53 25-40.2 7/18/2023 28.5-29.5 28-32 1373 29 1373 ST071-GW-OIP-07 7/25/2023 50.51 55.00
ST071-OIP-08 1.2 38 7/19/2023 37.5-38.5 36-40 596.1 38.5 596.1 ST071-GW-OIP-08 7/25/2023 48.31 65.00
ST071-OIP-09 59 25.6-31 7/14/2023 25.5-26.5 25-29 1760 26 1760 ST071-GW-OIP-09 7/26/2023 46.19 50.00
ST071-GW-1A ------------------------ST071-GW-1A 7/25/2023 48.15 60.00 T-914-019 Groundwater Only
ST071-GW-2A ------------------------ST071-GW-2A 7/25/2023 47.62 60.00 Groundwater Only
ST071-GW-1C ------------------------ST071-GW-1C 7/26/2023 DRY 55.00 Groundwater Only
ST071-GW-2C ------------------------ST071-GW-2C 7/26/2023 48.73 55.00 Groundwater Only
Notes:
Data Not Validated LNAPL=light non-aqueous phase liquid
---=data not available or not collected MN = not measured
%=percent OIP - optical image profiler
bgs = below ground surface PID=photoionization detector
DTW = depth to water ppmv=parts per million per volume
EC = electrical conductivity TD = total depth
ft=foot/feet UST = underground storage tank
ID=identification
Max PID
SoilOIP/EC Groundwater
Page 1 of 1
Table 3.2
Soil Analytical Results - July 2023
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Location ID ST071-OIP-01 ST071-OIP-02 ST071-OIP-03 ST071-OIP-04 ST071-OIP-05 ST071-OIP-07 ST071-OIP-08 ST071-OIP-09
Sample ID ST071-OIP-01-SO-
34.5-35.5
ST071-OIP-02-SO-
27-28
ST071-OIP-03-SO-
24.5-25.5
ST071-OIP-04-SO-
32-33
ST071-OIP-05-SO-
30-31
ST071-OIP-07-SO-
28.5-29.5
ST071-OIP-08-SO-
37.5-38.5
ST071-OIP-09-SO-
25.5-26.5
Sample Date 7/14/2023 7/17/2023 7/17/2023 7/17/2023 7/14/2023 7/18/2023 7/19/2023 7/14/2023
Sample Depth (ft)34.5-35.5 27-28 24.5-25.5 32-33 30-31 33-34 33-34 28.5-29.5 37.5-38.5 25.5-26.5
Sample Type Normal Normal Normal Normal Normal Normal Duplicate Normal Normal Normal
Analyte UDEQ DERR ISLs1 Units Results Results Results Results Results Results Results Results Results Results
Benzene 200 µg/kg 230 U 75 U 90 U 180 U 240 U 94 U 72 U 86 U 24 U 200 U
Toluene 9,000 µg/kg 460 U 150 U 180 U 350 U 1,000 J 190 U 140 U 170 U 48 U 400 U
Ethylbenzene 5,000 µg/kg 190 J 150 U 3,700 J 7,100 J 480 U 750 J 790 J 1,700 81 J 5,800 J
Xylenes 142,000 µg/kg 570 UJ 190 U 17,000 J 33,000 J 1,000,000 J 6,000 6,600 5,700 60 U 58,000 J
Naphthalene 51,000 µg/kg 2,900 U 930 U 1,100 J 3,900 J 15,000 J 1,200 U 910 U 1,100 U 300 U 2,800 J
TPH-GRO 150 mg/kg 120 J 290 3,000 7,100 J 120 J 120 J 170 J 410 17 8,400 J
TPH-DRO 500 mg/kg 43 560 100 1,700 J 3,900 500 J 86 J 65 8.8 U 260
Notes:
1Utah Division of Environmental Response and Remediation, Initial Screening Levels, November 1, 2005.
Bold text indicates analyte was detected.
Bold text with shading indicates analyte was detected above the ISL.
µg/kg=microgram per kilogram
mg/kg=milligram per kilogram
DERR = Division of Environmental Response and Remediation
DRO = diesel range organics
ft = feet
GRO = gasoline range organics
ID=identification
ISL = UDEQ DERR initial screening level
J = Analytical data are estimated between the detection limit and the limit of quantification or estimated due to quality control non-compliance.
TPH = total petroleum hydrocarbon
U = undetected at limit of detection
UDEQ = Utah Department of Environmental Quality
UST = underground storage tank
7/18/2023
ST071-OIP-06
ST071-OIP-06-SO-33-34
Page 1 of 1
Table 3.3
Discrete Groundwater Analytical Results - July 203
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
ST071-OIP-01 ST071-OIP-02 ST071-OIP-03 ST071-OIP-04 ST071-OIP-05 ST071-OIP-06 ST071-OIP-07
ST071-GW-OIP-01 ST071-GW-OIP-02 ST071-GW-OIP-03 ST071-GW-OIP-04 ST071-GW-OIP-05 ST071-GW-OIP-06 ST071-GW-OIP-07
7/26/2023 7/26/2023 7/26/2023 7/26/2023 7/26/2023 7/25/2023 7/25/2023
45 50 50 55 55 55 55
Normal Normal Normal Normal Normal Normal Normal
Analyte UDEQ
DERR ISLs1 Units Results Results Results Results Results Results Results
Benzene 5 µg/L 16 U 0.80 U 0.80 U 3.2 U 1.6 U 8.0 UJ 8.0 UJ
Toluene 1,000 µg/L 8.0 U 0.40 U 0.32 J 1.6 U 0.80 U 9.2 J 10 J
Ethylbenzene 700 µg/L 200 0.40 U 1.6 J 68 33 4.1 J 100 J
Xylenes 10,000 µg/L 810 0.80 U 0.43 J 400 110 22 J 300 J
Naphthalene 700 µg/L 30 J 0.80 U 2.8 J 14 3.6 J 8.0 UJ 17 J
TPH-GRO 1 mg/L 7.8 0.51 J 2.7 8.0 3.5 0.22 J 2.6 J
TPH-DRO 1 mg/L 2.0 0.25 J 8.9 1.9 1.7 0.086 J 0.45
Notes:
1Utah Division of Environmental Response and Remediation, Initial Screening Levels, November 1, 2005.
Bold text indicates analyte was detected.
Bold text with shading indicates analyte was detected above the ISL.
Temporary monitoring wells with 10 feet of well screen were installed to collect groundwater samples.
µg/L = micrograms per liter
mg/L = milligrams per liter
DERR = Division of Environmental Response and Remediation
DRO = diesel range organics
ft = feet
GRO = gasoline range organics
ID = identification
ISL = UDEQ DERR initial screening level
J = Analytical data are estimated between the detection limit and the limit of quantification or estimated due to quality control non-compliance.
TPH = total petroleum hydrocarbons
U = undetected at limit of detection
UDEQ = Utah Department of Environmental Quality
UST = underground storage tank
Total Depth (ft)
Sample Type
Location ID
Sample ID
Sample Date
Page 1 of 2
Table 3.3 (Continued)
Discrete Groundwater Analytical Results - July 203
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Analyte UDEQ
DERR ISLs1 Units
Benzene 5 µg/L
Toluene 1,000 µg/L
Ethylbenzene 700 µg/L
Xylenes 10,000 µg/L
Naphthalene 700 µg/L
TPH-GRO 1 mg/L
TPH-DRO 1 mg/L
Total Depth (ft)
Sample Type
Location ID
Sample ID
Sample Date
ST071-OIP-08 ST071-OIP-09 ST071-GW-1A ST071-GW-1C ST071-GW-2C
ST071-GW-OIP-08 ST071-GW-OIP-09 ST071-GW-1A ST071-GW-1C ST071-GW-2C
7/25/2023 7/26/2023 7/25/2023 7/26/2023 7/26/2023
65 50 60 60 60 55 55
Normal Normal Normal Normal Duplicate Normal Normal
Results Results Results Results Results Results Results
0.80 U 0.80 U 47 J 19 J 20 DRY 4.0 U
0.40 U 0.40 U 40 U 8.0 U 10 J DRY 3.4 J
0.40 U 0.40 U 830 160 180 DRY 150
0.80 U 0.80 U 5,800 1,700 1,800 DRY 1,000
0.80 U 0.80 U 140 J 20 J 23 J DRY 19
0.012 J 0.067 J 49 7.8 8.0 DRY 11
0.041 J 0.042 J 4.1 0.45 J 0.84 J DRY 0.86
Notes:
1Utah Division of Environmental Response and Remediation, Initial Screening Levels, November 1, 2005.
Bold text indicates analyte was detected.
Bold text with shading indicates analyte was detected above the ISL.
Temporary monitoring wells with 10 feet of well screen were installed to collect groundwater samples.
µg/L = micrograms per liter
mg/L = milligrams per liter
DERR = Division of Environmental Response and Remediation
DRO = diesel range organics
ft = feet
GRO = gasoline range organics
ID = identification
ISL = UDEQ DERR initial screening level
J = Analytical data are estimated between the detection limit and the limit of quantification or estimated due to quality control non-compliance.
TPH = total petroleum hydrocarbons
U = undetected at limit of detection
UDEQ = Utah Department of Environmental Quality
UST = underground storage tank
ST071-GW-2A
ST071-GW-2A
7/25/2023
Page 2 of 2
Northing (UTM
Z12 Meters)
Easting (UTM
Z12 Meters)
Top of Casing
Elevation
DTW
11-20-2023
Groundwater
Elevation
Screen
Slot Size
Filter
Pack
Top of
Screen
Bottom
of
Screen
Screen
Length
Total
Depth,
Well
Total Depth,
Borehole
(meters)(meters)(ft amsl)(ft bTOC)(ft amsl)(inch)(sieve)(ft bgs)(ft bgs)(ft)(ft bgs)(ft bgs)
T-914-017 10/31/2023 ST071 OIP-03 4,552,228.074 416,433.337 4,757.125 TOP CONCRETE NORTH SIDE Flush-mount PVC 0.010 20-40 40.0 54.6 14.6 54.6 55.5
ST071 OIP-03 4,552,227.961 416,433.319 4,756.828 TOP PIPE 44.84 4711.99
T-914-018 11/1/2023 ST071 OIP-01 4,552,229.126 416,424.017 4,757.305 TOP CONCRETE NORTH SIDE Flush-mount PVC 0.010 20-40 40.2 54.8 14.6 54.8 55.5
ST071 OIP-01 4,552,229.009 416,424.019 4,756.981 TOP PIPE 46.17 4710.81
T-914-019 11/1/2023 ST071 GW-1A 4,552,229.430 416,405.227 4,757.105 TOP CONCRETE NORTH SIDE Flush-mount PVC 0.010 20-40 45.9 60.5 14.6 60.5 61.0
ST071 GW-1A 4,552,229.333 416,405.231 4,756.812 TOP PIPE 47.49 4709.32
Notes:
amsl = above mean sea level
bgs = below ground surface
bTOC = below top of casing, NAVD88 Elev. (Based on BM-73-85)
DTW = depth to water
ft = foot/feet
NAVD88 = North American Vertical Datum of 1988
PVC = polyvinyl chloride
UST = underground storage tank
UTM = universal transverse mercator
Table 3.4
Monitoring Well Construction Summary
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Installation
DateWell Number
Reference
Location
Well
Completion
Well
MaterialDescription
Page 1 of 1
Table 3.5
Groundwater Field Parameters - November 2023
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Well Number
Monitoring
Point
Elevation
(ft amsl)
Sample
Date
Initial Depth
to Water
(ft bTOC)
Groundwater
Elevation
(ft amsl)
Depth to
Free Product
(ft bgs)
Free
Product
Thickness
(ft)
Final Depth
to Water
(ft bTOC)
Pump Inlet
Depth
(ft bTOC)
Purge
Volume (ml)
Temp
(°C)pH
Specific
Conductance(
mS/cm)
Turbidity
(NTU)
DO
(mg/L)
ORP
(mV)
T-914-017 4,756.83 11/20/2023 44.84 4,711.99 NE NE 45.27 51.06 5,000 14.9 7.07 0.746 7.21 0.05 -28.7
T-914-018 4,756.98 11/20/2023 46.17 4,710.81 NE NE 46.31 47.62 3,000 14.9 7.02 0.787 1.81 0.02 133.5
T-914-019 4,756.81 11/20/2023 47.49 4,709.32 NE NE 47.77 53.51 3,000 15.5 7.03 0.795 2.44 0.26 155.7
Notes:
amsl = above mean sea level
bgs = below ground surface
bTOC = below top of casing
DO = dissolved oxygen
ft = feet/foot
mg/L = milligrams per liter
ml = milliter
mS/cm = milliSiemens per centimeter
mV = millivolts
NE = not encountered
NTU = Nephelometric Turbidity Unit
ORP = oxidation-reduction potential
Page 1 of 1
T-914-017 T-914-018 T-914-018 T-914-019
11/20/2023 11/20/2023 11/20/2023 11/20/2023
Sample Type Normal Normal Duplicate Normal
Analyte Units Results Results Results Results
Arsenic ug/L 2 U 2 U NA 2 U
Nitrate mg/L 3.7 3.8 NA 4.2
Sulfate mg/L 20 15 NA 15
Iron, Dissolved mg/L 0.16 0.017 J NA 0.030 J
Manganese, Dissolved mg/L 0.19 0.016 NA 0.043
Alkalinity, Total mg/L 290 240 NA 230
Alkalinity, Bicarbonate mg/L 290 240 NA 230
Notes:
Utah Division of Environmental Response and Remediation, Initial Screening Levels, November 1, 2005.
Bold text indicates analyte was detected.
µg/L = micrograms per liter
mg/L = milligrams per liter
DERR = Division of Environmental Response and Remediation
ID=identification
ISL = UDEQ DERR initial screening level
NA = not analyzed
UDEQ = Utah Department of Environmental Quality
UST = underground storage tank
Location ID
Sample Date
y q q y
compliance.
Table 3.6
Groundwater Geochemical Parameters - November 2023
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
U = undetected at limit of detection
Page 1 of 1
T-914-017 T-914-019
11/20/2023 11/20/2023
Sample Type Normal Normal Duplicate Normal
Analyte UDEQ
DERR ISLs Units Results Results Results Results
Benzene 5 ug/L 0.8 U 0.8 U 0.8 U 0.8 U
Toluene 1,000 ug/L 0.4 U 0.4 U 0.4 U 0.4 U
Ethylbenzene 700 ug/L 0.4 U 0.82 J 0.4 U 0.4 U
Xylenes, Total 10,000 ug/L 0.8 U 13 J 3.4 J 0.8 U
Naphthalene 700 ug/L 0.8 U 0.8 U 0.8 U 0.8 U
TPH-GRO 1 mg/L 0.02 U 0.12 J 0.12 J 0.02 U
TPH-DRO 1 mg/L 0.12 U 0.13 U 0.12 U 0.13 U
Notes:
Utah Division of Environmental Response and Remediation, Initial Screening Levels, November 1, 2005.
Bold text indicates analyte was detected.
Bold text with shading indicates analyte was detected above the ISL.
µg/L = microgram per liter
mg/L = milligram per liter
Q = one or more quality control criteria failed
U = undetected at limit of detection
UST = underground storage tank
J = Analytical data are estimated between the detection limit and the limit of quantification or estimated due to quality control non-
compliance.
Location ID
Sample Date
Table 3.7
Groundwater Analytical Results - November 2023
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
T-914-018
11/20/2023
Page 1 of 1

FIGURES

This page was intentionally left blank.
!(
Hill Air Force Base
UST Site 914
Figure 2.1
Hill Air Force Base
Location Map
Legend
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
0 3,000 6,0001,500
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-01)Site_Location.mxd
10/2/2024 TA
Source: HGL, EA
ArcGIS Online World Street Map
^_
UTAH
Hill Air Force Base
General Location
Hill Air Force Base Boundary
Notes:
UST=underground storage tank
!A?!A?
!A?
!A?!A?
!A?
!A?
!A?
!A?!A?
!A?
!A?
!A?
!A?
!A?
!A?
T-914-MW1
T-914-203
T-914-202
T-914-016
4,659.15
T-914-015
4,654.38
T-914-009
T-914-008
T-914-007
T-914-006
4,667.19
T-914-005
T-914-004
T-914-003
4,672.49
T-914-002
4,688.48
T-914-001
T-914-PTW1
T-914-PTW2
923
922918
911
918D
918C
918B
918A
10917
922FT
922KFT
922JFT
922IFT
922HFT
922FFT
922EFT
922DFT
922CFT 922BFT
922AFT
910DFT
910CFT
910BFT
910AFT
4,660
4,662
4,
664
4
,
6
6
6
4
,
6
7
0
4
,
6
6
8
4
,
6
7
2
4
,
6
7
4
4
,
6
7
6
4
,
6
7
8
4
,
6
8
0
4
,
6
8
2
4
,
6
8
4
4
,
68
6
4,660
4,662
4,664
4,666
4,6704,668
4,672
4,674
4,676
4,678
4,680
4,682
4,684
4,686
Figure 2.2
UST Site 914
Overview Map
Legend
05010025
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-02)UST_Site_914_Overview.mxd
10/3/2024 TA
Source: HGL, EA
2021 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
ft amsl=feet above mean sea level
SVE=soil vapor extraction
UST=underground storage tank
Hill Air Force Base Boundary
Groundwater Flow Direction
Location Identification
Groundwater Elevation (ft amsl)
T-914-002
4,688.48
Building Identification922
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
Former UST 914.6
Monitoring Well (Abandoned)!A?
Groundwater Elevation Contour -
September 2007 (ft amsl)4,686
SVE Well (Abandoned)!A?
!A?
!(
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923
922918
911
918D
918C
918B
918A
10917
922FT
922KFT
922JFT
922IFT
922HFT
922FFT
922EFT
922DFT
922CFT 922BFT
922AFT
910DFT
910CFT
910BFT
910AFT
Former Location
of UST 914.6
T-914-PTW1
T-914-950
T-914-962
T-914-960
T-914-953
T-914-708
T-914-713
T-914-709
T-914-961
T-914-963
T-914-722
T-914-714
T-914-712
T-914-719
T-914-720
T-914-710
T-914-957
T-914-718
T-914-951T-914-956
T-914-707
T-914-952
T-914-959
T-914-706
T-914-955
T-914-964
T-914-711
T-914-958
A'
B'
B
A
Fuel Island
FUEL ISLAND
Fuel Island
Catch Basin
T-914-003
T-914-203
T-914-008
T-914-006
T-914-002
Figure 2.3
Soil Boring and
Cross Section Locations
Legend
05010025
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-03)Soil_Boring_and_Cross_Section_Loc.mxd
11/5/2024 TA
Source: HGL, EA, CH2M Hill, 2008b
2021 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
All wells on figure have been abandoned
SVE=soil vapor extraction
UST=underground storage tank
Hill Air Force Base Boundary
Building Identification922
Cross-Section LineA A'
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
Soil Boring Pre-SVE!(
Soil Boring During SVE!(
Monitoring Well (Abandoned)!A?
Former UST 914.6
Soil Boring Post-SVE!(
HGL-APTIM JV—ST071 Corrective Action Plan Addendum—Hill AFB, Utah
Figure 2.4
Cross Section A-A’
\\Srv-gst-01\HGLGIS\Hill_AFB_V1H001\ST071\CAP\
(2-04)Cross_Section_A.cdr
10/10/24 TA
Source:HGL, CH2MHILL, 2008b
Legend
Notes:
Cross Section Source: Letter Report for
Closure of Underground Storage
Tank Site 914 (CH2MHill, 2008).
BGS=below ground surfaceWell Screen
Sample Interval
Figure Not to Scale
HGL-APTIM JV—ST071 Corrective Action Plan Addendum—Hill AFB, Utah
Figure 2.5
Cross Section B-B’
\\Srv-gst-01\HGLGIS\Hill_AFB_V1H001\ST071\CAP\
(2-05)Cross_Section_B.cdr
10/10/24 TA
Source:HGL, CH2MHILL, 2008b
Legend
Notes:
Cross Section Source: Letter Report for
Closure of Underground Storage
Tank Site 914 (CH2MHill, 2008).
BGS=below ground surfaceWell Screen
Sample Interval
Figure Not to Scale
!A?
!A?!A?
!A?
!A?
!A?
!A?!A?
!A?
!A?
!A?
!A?!A?
!A?!A?!A?
!(
!(
T-914-MW1
T-914-203
T-914-202
T-914-016
T-914-015
T-914-009
T-914-008
T-914-007
T-914-006
T-914-005
T-914-004
T-914-003
T-914-002
T-914-001
T-914-PTW1
T-914-PTW2
Former Location
of UST 914.6
911
10917
923
922
918B
922FT
918A
918D
918C
922FFT
922EFT
922IFT
918
922JFT
922HFT
910AFT
910CFT
910BFT
910DFT
922KFT
922AFT
922CFT 922BFT
922DFT
T-914-712
T-914-711
Figure 2.6
Historical Free Product
Plumes
Legend
05010025
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-06)Historic_Free_Product_Plumes.mxd
10/3/2024 TA
Source: HGL, EA
2021 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
UST=underground storage tank
Hill Air Force Base Boundary
Wells With Free Product Sheen (2007)!A?
Building Identification922
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
Former UST
Monitoring Well (Abandoned)!A?
Approximate Free Product Extent (Year):
2007
1999
1994
Soil Boring!(
!(
!(
!A?
!A?
!A?!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
T-914-711
T-914-712
A
B
C
D
E
1
F
2
T-914-004
T-914-006
T-914-203
T-914-PTW1
Former
Location of
UST 914.6
Figure 2.7
2022 SSI Sample Locations
Legend
010205
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-07)2021_SSI_Sample_Loc.mxd
11/5/2024 TA
Source: HGL, EA
2021 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
Grid coordinates in State Plane Utah North (NAD83 Feet)
ft=feet
NAD83=North American Datum 1983
SSI=Supplemental Site Investigation
UST=underground storage tank
Hill Air Force Base Boundary
2007 Approximate Free Product Extent
Sampling Grid (10ft x 10ft)
Water
Storm Water
Underground Petroleum Line
Utilities:
Proposed Groundwater Sample Coordinates (Grid):
Grid Eastings Northings
A1 1503836.267 3566762.581
A2 1503835.438 3566749.362
B1 1503846.614 3566763.275
B2 1503848.142 3566753.762
C1 1503858.351 3566764.248
C2 1503859.392 3566755.012
D1 1503866.476 3566765.081
D2 1503868.906 3566755.706
E1 1503876.406 3566766.331
E2 1503877.864 3566757.998
F1 1503885.989 3566767.859
F2 1503886.962 3566762.303
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
2004 Soil Boring!(
Abandoned Monitoring Well!A?
Soil and/or Groundwater Sample!A?
Former UST 914.6
!(
!(!A?
!A?
!A?!A?
!A?!A?!A?!A?!A?
!A?
!A?
!A?!A?!A?
!A?
!A?
T-914-711
T-914-712
A
B
C
D
E
1
F
2
T-914-004
T-914-006
T-914-203
T-914-PTW1
Former
Location of
UST 914.6
05 04 03 02
01
NS
GW Only
NS
NS NS
NS NS
GW Only
NS
Figure 2.8
Soil COC Concentration Map
April/May 2022
Legend
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
010205
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-08)Soil_COC_Conc_AprMay2022.mxd
12/17/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Hill Air Force Base Boundary
Sampling Grid (10ft x 10ft)
Notes:
Only compounds detected at one or more locations.
Bold=Value above ISL.
*=Regional Screening Level, Residential Soil
µg/kg=microgram per kilogram
bgs=below ground surface
COC=contaminant of concern
DERR=Division of Environmental Response and Remediation
DRO (C10-C28)=Diesel Range Organics (C10-C28)
ft=feet
GRO (C6-C10)=Gas Range Organics (C6 to C10)
GW=groundwater
ISL=initial screening level
J=Value is estimated.
NS=not sampled due to access restrictions
SO=subsurface soil
SSI=Supplemental Site Investigation
U=Analyte was analyzed for but not detected.
UDEQ=Utah Department of Environmental Quality
UST=underground storage tank
Utilities:
Water
Underground Electric
Underground Petroleum Line
Abandoned Monitoring Well!A?
2004 Soil Boring!(
Former UST 914.6
Analyte Soil (µg/kg)
1,1,2-Trichloroethane 5,000*
Ethylbenzene 5,000
Naphthalene 51,000
Xylenes, total 142,000
GRO (C6-C10)150,000
DRO (C10-C28 500,000
UDEQ DERR ISLs
2022 SSI Boring Location!A?
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,1,2-Trichloroethane 1,600 U
Ethylbenzene 10,000
Naphthalene 2,100 J
Xylenes, total 50,000
GRO (C6-C10)1,400,000 J
DRO (C10-C28)600,000
ST071SO-02
5/9/2022
SO
30-35
Results (µg/kg)
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,1,2-Trichloroethane 10,000 U
Ethylbenzene 47,000
Naphthalene 16,000 U
Xylenes, total 480,000
GRO (C6-C10)9,600,000 J
DRO (C10-C28)1,300,000
Results (µg/kg)
30-35
ST071SO-03
5/9/2022
SO
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,1,2-Trichloroethane 10,000 J
Ethylbenzene 12,000 J
Naphthalene 16,000 U
Xylenes, total 120,000 J
GRO (C6-C10)3,600,000 J
DRO (C10-C28)1,800,000 J
ST071SO-04
5/9/2022
SO
30-35
Results (µg/kg)
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,1,2-Trichloroethane 1,500 U
Ethylbenzene 1,700 J
Naphthalene 2,300 U
Xylenes, total 16,000
GRO (C6-C10)260,000 J
DRO (C10-C28)1,700,000
ST071SO-05
5/9/2022
SO
30-35
Results (µg/kg)
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,1,2-Trichloroethane 9,700
Ethylbenzene 7,200
Naphthalene 2,400 J
Xylenes, total 47,000
GRO (C6-C10)1,000,000 J
DRO (C10-C28)2,300,000 J
ST071SO-01
4/13/2022
SO
33-35
Results (µg/kg)
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,1,2-Trichloroethane 2,000 U
Ethylbenzene 6,000
Naphthalene 3,100 U
Xylenes, total 39,000
GRO (C6-C10)460,000 J
DRO (C10-C28)1,200,000 J
ST071SO-01-FD
4/13/2022
SO
33-35
Results (µg/kg)
!(
!(!A?
!A?
!A?!A?
!A?!A?!A?!A?!A?
!A?
!A?
!A?!A?!A?
!A?
!A?
T-914-711
T-914-712
A
B
C
D
E
1
F
2
T-914-004
T-914-006
T-914-203T-914-PTW1
Former
Location of
UST 914.6
E2
DRY DRY
DRY
DRY
DRY
DRY
NS
NS NS
NS
NS
Figure 2.9
Groundwater COC Concentration Map
April 2022
Legend
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
010205
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(2-09)GW_COC_Conc_Apr2022.mxd
12/17/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
Only detected compounds shown.
Bold=Value above ISL.
*=Regional Screening Level, Residential Tap Water
µg/L=microgram per liter
bgs=below ground surface
COC=contaminant of concern
DERR=Division of Environmental Response and Remediation
ft=feet
GRO (C6-C10)=Gas Range Organics (C6 to C10)
GW=groundwater
ISL=initial screening level
J=Value is estimated.
NS=not sampled due to access restrictions
SSI=Supplemental Site Investigation
UDEQ=Utah Department of Environmental Quality
UST=underground storage tank
Hill Air Force Base Boundary
Sampling Grid (10ft x 10ft)
Underground Electric
Water
Underground Petroleum Line
Utilities:
2022 SSI Groundwater Sample!A?
Abandoned Monitoring Well!A?
2004 Soil Boring!(
Former UST 914.6
Location
Sample Date
Media
Sample Depth (ft bgs)
Analyte
1,3,5-Trimethylbenzene 720 D
Acetone 56 J D
Carbon disulfide 4J D
Chloroform 4 J D
Ethylbenzene 820 D
Naphthalene 170 D
Toluene 8.4 J D
Xylenes, total 11000 D H
GRO (C6-C10)25000 D Q
ST071GW-E2
4/13/2022
GW
30-35
Results (µg/L)
Analyte Tap Water (µg/L)
1,3,5-Trimethylbenzene 5900*
Acetone 18000*
Carbon disulfide 810*
Chloroform 0.22*
Ethylbenzene 700
Naphthalene 700
Toulene 1000
Xylenes, total 10000
GRO (C6-C10)1000
UDEQ DERR ISLs
@R!
@R!
@R!
@R!
@R!
@R!
@R!
@R!
@R!
!
!
!
!
!
!
!
!
!
!A?
!A?
!A?
!A?
A B
C D E
1
F
2
Former
Location of
UST 914.6
OIP-1 OIP-2OIP-3
OIP-4
OIP-5
OIP-6 OIP-7
OIP-8
OIP-9
ST071-GW-2A ST071-GW-2C
ST071-GW-1A
ST071-GW-1C
5000500150
Figure 3.1
Soil Analytical Results
July 2023
Legend
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(3-01)ST071_Soil_Analytical_Results_Jul2023.mxd
12/12/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Hill Air Force Base Boundary
2007 Approximate Free Product Extent
HGL-APTIM JV—ST071 Correction Action Plan Addendum
Hill AFB, Utah
2023 SSI Groundwater Sample!A?
012246
Feet
³
OIP/EC Probe Location and Response Percentage:
@R!0.0% - 9.9%
@R!10.0% - 29.9%
@R!30.0% - 49.9%
@R!50.0% - 69.9%
@R!70.0% - 100.0%
Utilities:
Water
Storm Water
Underground Petroleum Line
Sampling Grid (10 ft x 10 ft)
Analyte
Benzene 200 µg/kg
Toluene 9,000 µg/kg
Ethylbenzene 5,000 µg/kg
Xylenes 142,000 µg/kg
Naphthalene 51,000 µg/kg
TPH-GRO 150 mg/kg
TPH-DRO 500 mg/kg
Soil Screening Levels
UDEQ DERR ISLs
Analyte Concentrations (mg/kg):
TPH-GRO and Ethylbenzene5000
TPH-DRO500
TPH-GRO150
Location ID
Sample ID
Sample Date
Sample Depth 30-31 ft bgs
Sample Type
Analyte Results Units
Benzene 240 U µg/Kg
Toluene 1,000 µg/Kg
Ethylbenzene 480 U µg/Kg
Xylenes 1,000,000 µg/Kg
Naphthalene 15,000 µg/Kg
TPH-GRO 120 mg/Kg
TPH-DRO 3,900 mg/Kg
ST071-OIP-05-SO-30-31
7/14/2023
Normal
ST071-OIP-05
Former UST 914.6
Notes:
Utah Division of Environmental Response and Remediation, Initial
Screening Levels, November 1, 2005.
Bold text indicates analyte was detected.
Bold with highlight indicates analyte was detected above the ISL.
µg/kg=microgram per kilogram
bgs=below ground surface
ft=feet
ISL=initial screening level
J=value is estimated
mg/kg=milligram per kilogram
OIP/EC=Optical Image Profiler/Electrical Conductivity
SSI=Supplemental Site Investigation
TPH-DRO=Total Petroleum Hydrocarbons Diesel Range Organics
TPH-GRO=Total Petroleum Hydrocarbons Gasoline Range Organics
U=Analyte was analyzed for but not detected.
UDEQ DERR=Utah Department of Environmental Quality Division
of Environmental Response and Remediation
UST=underground storage tank
Location ID ST071-OIP-01
Sample ID ST071-OIP-01-SO-34.5-35.5
Sample Date 7/14/2023
Sample Depth (ft) 34.5-35.5
Sample Type Normal
Analyte Results, µg/Kg
Benzene 230 U
Toluene 460 U
Ethylbenzene 190 J
Xylenes 570 UJ
Naphthalene 2900 U
TPH-GRO 120 J
TPG-DRO 43
Location ID
Sample ID
Sample Date
Sample Depth (ft) 33-34 33-34
Sample Type Normal Duplicate
Analyte Results, µg/Kg Results, µg/Kg
Benzene 94 U 72 U
Toluene 190 U 140 U
Ethylbenzene 750 J 790 J
Xylenes 6,000 6,600
Naphthalene 1200 U 910 U
TPH-GRO 120 J 170 J
TPG-DRO 500 J 86 J
ST071-OIP-06
ST071-OIP-06-SO-33-34
7/18/2023
Location ID ST071-OIP-02
Sample ID ST071-OIP-02-SO-27-28
Sample Date 7/17/2023
Sample Depth (ft) 27-28
Sample Type Normal
Analyte Results, µg/Kg
Benzene 75 U
Toluene 150 U
Ethylbenzene 150 U
Xylenes 190 U
Naphthalene 930 U
TPH-GRO 290
TPG-DRO 560
Location ID ST071-OIP-03
Sample ID ST071-OIP-03-SO-24.5-25.5
Sample Date 7/17/2023
Sample Depth (ft) 24.5-25.5
Sample Type Normal
Analyte Results, µg/Kg
Benzene 90 U
Toluene 180 U
Ethylbenzene 3700 J
Xylenes 17000 J
Naphthalene 1100 J
TPH-GRO 3,000
TPG-DRO 100
Location ID ST071-OIP-04
Sample ID ST071-OIP-04-SO-32-33
Sample Date 7/17/2023
Sample Depth (ft) 32-33
Sample Type Normal
Analyte Results, µg/Kg
Benzene 180 U
Toluene 350 U
Ethylbenzene 7100 J
Xylenes 33000 J
Naphthalene 3900 J
TPH-GRO 7100 J
TPG-DRO 1700 J1
Location ID ST071-OIP-05
Sample ID ST071-OIP-05-SO-30-31
Sample Date 7/14/2023
Sample Depth (ft) 30-31
Sample Type Normal
Analyte Results, µg/Kg
Benzene 240 U
Toluene 1,000 J
Ethylbenzene 480 U
Xylenes 1,000,000 J
Naphthalene 15,000 J
TPH-GRO 120 J
TPG-DRO 3,900
Location ID ST071-OIP-07
Sample ID ST071-OIP-07-SO-28.5-29.5
Sample Date 7/18/2023
Sample Depth (ft) 28.5-29.5
Sample Type Normal
Analyte Results, µg/Kg
Benzene 86 U
Toluene 170 U
Ethylbenzene 1,700
Xylenes 5,700
Naphthalene 1100 U
TPH-GRO 410
TPG-DRO 65
Location ID ST071-OIP-08
Sample ID ST071-OIP-08-SO-37.5-38.5
Sample Date 7/19/2023
Sample Depth (ft) 37.5-38.5
Sample Type Normal
Analyte Results, µg/Kg
Benzene 24 U
Toluene 48 U
Ethylbenzene 81 J
Xylenes 60 U
Naphthalene 300 U
TPH-GRO 17
TPG-DRO 8.8 U
Location ID ST071-OIP-09
Sample ID ST071-OIP-09-SO-25.5-26.5
Sample Date 7/14/2023
Sample Depth (ft) 25.5-26.5
Sample Type Normal
Analyte Results, µg/Kg
Benzene 200 U
Toluene 400 U
Ethylbenzene 5800 J
Xylenes 58000 J
Naphthalene 2800 J
TPH-GRO 8400 J
TPG-DRO 260
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?
!A?
!A?
!A?
!A?
!A?
!A?
!A?
A B
C D E
1
F
2
Former
Location of
UST 914.6
OIP-1
OIP-2OIP-3
OIP-4
OIP-5
OIP-6 OIP-7
OIP-8
OIP-9
ST071
GW-1C
ST071-GW-2A
ST071-GW-2C
ST071
GW-1A
Figure 3.2
Discrete Groundwater
Analytical Results
November 2023
Legend
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(3-02)ST071_GW_Analytical_Results_Nov2023.mxd
12/12/2024 TA
Source: HGL, EA
2021 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Hill Air Force Base Boundary
2007 Approximate Free Product Extent
HGL-APTIM JV—ST071 Correction Action Plan Addendum
Hill AFB, Utah
Water
Storm Water
Underground Petroleum Line
Utilities:
2023 SSI Groundwater Sample!A?
012246
Feet
³
Sampling Grid (10 ft x 10 ft)
2023 OIP/EC Probe and Groundwater
Sample Location!A?!
Analyte
Benzene 5 µg/L
Toluene 1,000 µg/L
Ethylbenzene 700 µg/L
Xylenes 10,000 µg/L
Naphthalene 700 µg/L
TPH-GRO 1 mg/L
TPH-DRO 1 mg/L
Groundwater Screening Levels
UDEQ DERR ISLsNotes:
Utah Division of Environmental Response and Remediation, Initial
Screening Levels, November 1, 2005.
Preliminary data, not validated.
Bold text indicates analyte was detected.
Bold with highlight indicates analyte was detected above the ISL.
µg/L=microgram per liter
bgs=below ground surface
ft=feet
ISL=initial screening level
J=value is estimated
mg/L=milligram per liter
OIP/EC=Optical Image Profiler/Electrical Conductivity
SSI=Supplemental Site Investigation
TPH-DRO=Total Petroleum Hydrocarbons Diesel Range Organics
TPH-GRO=Total Petroleum Hydrocarbons Gasoline Range Organics
U=Analyte was analyzed for but not detected.
UDEQ DERR=Utah Department of Environmental Quality Division
of Environmental Response and Remediation
UST=underground storage tank
Former UST 914.6
Location ID ST071-OIP-01
Sample ID ST071-GW-OIP-01
Sample Date 7/26/2023
Total Depth (ft)45.00
Sample Type Normal
Analyte Results, µg/L
Benzene 16 U
Toluene 8.0 U
Ethylbenzene 200
Xylenes 810
Naphthalene 30 J
TPH-GRO 7.8
TPH-DRO 2
Location ID ST071-OIP-02
Sample ID ST071-GW-OIP-02
Sample Date 7/26/2023
Total Depth (ft)50.00
Sample Type Normal
Analyte Results, µg/L
Benzene 0.80 U
Toluene 0.40 U
Ethylbenzene 0.40 U
Xylenes 0.80 U
Naphthalene 0.80 U
TPH-GRO 0.51 J
TPH-DRO 0.25 J
Location ID ST071-OIP-03
Sample ID ST071-GW-OIP-03
Sample Date 7/26/2023
Total Depth (ft)50.00
Sample Type Normal
Analyte Results, µg/L
Benzene 0.80 U
Toluene 0.32 J
Ethylbenzene 1.6 J
Xylenes 0.43 J
Naphthalene 2.8 J
TPH-GRO 2.7
TPH-DRO 8.9
Location ID ST071-OIP-04
Sample ID ST071-GW-OIP-04
Sample Date 7/26/2023
Total Depth (ft)55.00
Sample Type Normal
Analyte Results, µg/L
Benzene 3.2 U
Toluene 1.6 U
Ethylbenzene 68
Xylenes 400
Naphthalene 14
TPH-GRO 8
TPH-DRO 1.9
Location ID ST071-OIP-05
Sample ID ST071-GW-OIP-05
Sample Date 7/26/2023
Total Depth (ft)55.00
Sample Type Normal
Analyte Results, µg/L
Benzene 1.6 U
Toluene 0.80 U
Ethylbenzene 33
Xylenes 110
Naphthalene 3.6 J
TPH-GRO 3.5
TPH-DRO 1.7
Location ID ST071-OIP-06
Sample ID ST071-GW-OIP-06
Sample Date 7/25/2023
Total Depth (ft)55
Sample Type Normal
Analyte Results, µg/L
Benzene 8.0 UJ
Toluene 9.2 J
Ethylbenzene 4.1 J
Xylenes 22 J
Naphthalene 8.0 UJ
TPH-GRO 0.22 J
TPH-DRO 0.086 J
Location ID ST071-OIP-07
Sample ID ST071-GW-OIP-07
Sample Date 7/25/2023
Total Depth (ft)55
Sample Type Normal
Analyte Results, µg/L
Benzene 8.0 UJ
Toluene 10 J
Ethylbenzene 100 J
Xylenes 300 J
Naphthalene 17 J
TPH-GRO 2.6 J
TPH-DRO 0.45
Location ID ST071-OIP-08
Sample ID ST071-GW-OIP-08
Sample Date 7/25/2023
Total Depth (ft)65.00
Sample Type Normal
Analyte Results, µg/L
Benzene 0.80 U
Toluene 0.40 U
Ethylbenzene 0.40 U
Xylenes 0.80 U
Naphthalene 0.80 U
TPH-GRO 0.012 J
TPH-DRO 0.041 J
Location ID ST071-OIP-09
Sample ID ST071-GW-OIP-09
Sample Date 7/26/2023
Total Depth (ft)50.00
Sample Type Normal
Analyte Results, µg/L
Benzene 0.80 U
Toluene 0.40 U
Ethylbenzene 0.40 U
Xylenes 0.80 U
Naphthalene 0.80 U
TPH-GRO 0.067 J
TPH-DRO 0.042 J
Location ID ST071-GW-1A
Sample ID ST071-GW-1A
Sample Date 7/25/2023
Total Depth (ft)60.00
Sample Type Normal
Analyte Results, µg/L
Benzene 47 J
Toluene 40 U
Ethylbenzene 830
Xylenes 5,800
Naphthalene 140 J
TPH-GRO 49
TPH-DRO 4.1
Location ID ST071-GW-1C
Sample ID ST071-GW-1C
Sample Date 7/26/2023
Total Depth (ft)55.00
Sample Type Normal
Analyte Results, µg/L
Benzene DRY
Toluene DRY
Ethylbenzene DRY
Xylenes DRY
Naphthalene DRY
TPH-GRO DRY
TPH-DRO DRY
Location ID ST071-GW-2C
Sample ID ST071-GW-2C
Sample Date 7/26/2023
Total Depth (ft)55.00
Sample Type Normal
Analyte Results, µg/L
Benzene 4.0 U
Toluene 3.4 J
Ethylbenzene 150
Xylenes 1,000
Naphthalene 19
TPH-GRO 11
TPH-DRO 0.86
Location ID ST071-GW-2A ST071-GW-2A
Sample ID ST071-GW-2A ST071-GW-2A
Sample Date 7/25/2023 7/25/2023
Total Depth (ft)60 60
Sample Type Normal Duplicate
Analyte Results, µg/L Results, µg/L
Benzene 19 J 20
Toluene 8.0 U 10 J
Ethylbenzene 160 180
Xylenes 1,700 1,800
Naphthalene 20 J 23 J
TPH-GRO 7.8 8.0
TPH-DRO 0.45 J 0.84 J
!A?
!A?!A?
Former
Location of
UST 914.6
T-914-017
4,711.99
T-914-018
4,710.81
T-914-019
4,709.32
Figure 3.3
Groundwater Elevations
November 2023
Legend
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(3-03)GW_Elev_Nov2023.mxd
12/9/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
ft amsl=feet above mean sea level
UST=underground storage tank
Hill Air Force Base Boundary
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
Water
Storm Water
Underground Petroleum Line
Utilities:
012246
Feet
³
Monitoring Well!A?
Former UST 914.6
Location Identification
Groundwater Elevation (ft amsl)
T-914-017
4,711.99
General Groundwater Flow
!A?
!A?!A?
T-914-017T-914-018T-914-019
Former
Location of
UST 914.6
Figure 3.4
Groundwater COC Concentration Map
November 2023
Legend
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
010205
Feet
³\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(3-04)GW_COC_Conc_Nov2023.mxd
12/12/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Notes:
Utah Division of Environmental Response and Remediation,
Initial Screening Levels, November 1, 2005.
Bold=Analyte was detected.
µg/L=microgram per liter
COC=contaminant of concern
DERR=Division of Environmental Response and Remediation
ISL=initial screening level
J=Analytical data are estimated between the detection limit and the limit
of quantification or estimated due to quality control non-compliance.
mg/L=milligram per liter
TPH-DRO=Total Petroleum Hydrocarbons Diesel Range Organics
TPH-GRO=Total Petroleum Hydrocarbons Gasoline Range Organics
U=undetected at limit of detection
UDEQ=Utah Department of Environmental Quality
UST=underground storage tank
Hill Air Force Base Boundary
Underground Electric
Water
Underground Petroleum Line
Utilities:
Analyte Concentration Units
Benzene 5 ug/L
Toluene 1,000 ug/L
Ethylbenzene 700 ug/L
Xylenes, Total 10,000 ug/L
Naphthalene 700 ug/L
TPH-GRO 1 mg/L
TPH-DRO 1 mg/L
UDEQ DERR ISLs
Monitoring Well!A?
Former UST 914.6
Location ID
Sample Date
Sample Type
Analyte Concentration Units Concentration Units
Benzene 0.8 U ug/L 0.8 U ug/L
Toluene 0.4 U ug/L 0.4 U ug/L
Ethylbenzene 0.82 J ug/L 0.4 U ug/L
Xylenes, Total 13 J ug/L 3.4 J ug/L
Naphthalene 0.8 U ug/L 0.8 U ug/L
TPH-GRO 0.12 J mg/L 0.12 J mg/L
TPH-DRO 0.13 U mg/L 0.12 U mg/L
DUP-T-914-018T-914-018
11/20/2023
Normal
11/20/2023
Duplicate
Location ID
Sample Date
Sample Type
Analyte Concentration Units
Benzene 0.8 U ug/L
Toluene 0.4 U ug/L
Ethylbenzene 0.4 U ug/L
Xylenes, Total 0.8 U ug/L
Naphthalene 0.8 U ug/L
TPH-GRO 0.02 U mg/L
TPH-DRO 0.12 U mg/L
T-914-017
11/20/2023
Normal
Location ID
Sample Date
Sample Type
Analyte Concentration Units
Benzene 0.8 U ug/L
Toluene 0.4 U ug/L
Ethylbenzene 0.4 U ug/L
Xylenes, Total 0.8 U ug/L
Naphthalene 0.8 U ug/L
TPH-GRO 0.02 U mg/L
TPH-DRO 0.13 U mg/L
Normal
T-914-019
11/20/2023
!A?
!A?!A?
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?!
!A?
!A?
!A?
!A?
Former
Location of
UST 914.6
OIP-1
OIP-2
OIP-3
OIP-4
OIP-5
OIP-6
OIP-7
OIP-8
OIP-9
ST071-GW-1C
ST071-GW-2A
ST071-GW-2C
ST071-GW-1A
T-914-017
T-914-018
T-914-019
A
B
B'
A'
Figure 4.1
Cross Section Location Map
Legend
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(4-01)EC_FLUOR_Cross_Section_Loc.mxd
12/9/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Hill Air Force Base Boundary
HGL-APTIM JV—ST071 Corrective Action Plan Addendum
Hill AFB, Utah
2023 SSI Groundwater Sample!A?
012246
Feet
³
Monitoring Well!A?
Utilities:
Underground Petroleum Line
Storm Water
Water
Notes:
OIP/EC=Optical Image Profiler/Electrical Conductivity
SSI=Supplemental Site Investigation
UST=underground storage tank
OIP/EC Probe and Soil/Groundwater
Sample Location!A?!
Cross Sections (dashed where transposed):
Former UST 914.6
See Figure 4.2A A'
See Figure 4.3B B'
HGL-APTIM JV—ST071 Corrective Action Plan Addendum—Hill AFB, Utah
Figure 4.2
Cross Section A-A’
\\Srv-gst-01\HGLGIS\Hill_AFB_V1H001\ST071\CAP_Addendum\
(4-02)EC_FLUOR_Cross_Section_A.cdr
10/10/24 TA
Source: HGL, Vista GeoScience
Notes:
Logs Source: Vista GeoScience Subsurface Imaging Systems,
Project ID 19294.08 (June 2023).
OIP Depth To Water, July 2024
Monitoring Well Depth To Water, November 2023
EC=Electrical Conductivity
FLUOR [275GP01] (%)=Percent Area Fluorescence (%AF)
response using 275GP01 image filters.
mS/m=milliSiemens per meter
OIP=Optical Image Profiler
PAH=polycyclic aromatic hydrocarbon
Cross Section A-A’
Screen Interval
Monitoring Well
Depth To Water (feet)
45.82
EC (mS/m)
(Silt/Clay Response)
FLOUR [275GP01] (%)
(PAH Response)
Legend
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
T-9
1
4
-
0
1
7
46.19
44.84
45.82
A’
(S outh)
OIP-09
15.90 ft15.90 ft
OIP-03
22.39 ft22.39 ft
OIP-02
A
(N orth)
Sandy Silt
Clayey Silt
Fine-Course Sand
Silty Sand
Fine-Course Sand
Sandy Silt
Clayey Silt
Fine-Course Sand
Silty Sand
Fine-Course Sand
HGL-APTIM JV—ST071 Corrective Action Plan Addendum—Hill AFB, Utah
Figure 4.3
Cross Section B-B’
\\Srv-gst-01\HGLGIS\Hill_AFB_V1H001\ST071\CAP_Addendum\
(4-03)EC_FLUOR_Cross_Section_B.cdr
12/9/24 TA
Source: HGL, Vista GeoScience
Notes:
Logs Source: Vista GeoScience Subsurface Imaging Systems,
Project ID 19294.08 (June 2023).
OIP Depth To Water, July 2024
Monitoring Well Depth To Water, November 2023
EC=Electrical Conductivity
FLUOR [275GP01] (%)=Percent Area Fluorescence (%AF)
response using 275GP01 image filters.
mS/m=milliSiemens per meter
OIP=Optical Image Profiler
PAH=polycyclic aromatic hydrocarbon
Cross Section B-B’
Screen Interval
Monitoring Well
Depth To Water (feet)
48.31
EC (mS/m)
(Silt/Clay Response)
FLOUR [275GP01] (%)
(PAH Response)
Legend
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
61
60
55
50
45
40
35
30
25
20
15
10
5
0
De
p
t
h

(
f
e
e
t
)
3002001000
EC (mS/m)
110100500
FLUOR [275GP01] (%)
T-9
1
4
-
0
1
7
T-9
1
4
-
0
1
8
T-9
1
4
-
0
1
9
48.31
47.35
44.84
47.49
45.82
47.69
B’
(East)
OIP-03
27.97 ft27.97 ft
(Transposed)
OIP-04OIP-0 1
14.82 ft14.82 ft
OIP-0 5
9.57 ft9.57 ft
(Transposed)
OIP-06
29.24 ft29.24 ft
OIP-08
B
(West)
Sandy Silt
Clayey Silt
Fine-Course Sand
Silty
Sand
Fine-Course Sand
Sandy Silt
Clayey Silt
Fine-Course Sand
Fine-Course Sand
Sandy Silt
Clayey Silt
Fine-Course Sand
Fine-Course Sand
Sandy Silt
Clayey Silt
Fine-Course Sand
Fine-Course Sand
Sandy Silt
Clayey Silt
Fine-Course Sand
Fine-Course Sand
Sandy Silt
Clayey Silt
Sand
Sand
Fine-Course Sand
Silty Sand
Fine-Course Sand
Silty
Sand
@R!@R!
@R!
@R!
@R!
@R!
@R!@R!
@R!
!
!
!
!
!
!
!!
!
!(
!(
!A?
!A?
!A?!A?!A?
!A?
!A?
!A?
!>!>
!>
!>!>
!>
!>
!>
Former
Location of
UST 914.6
OIP-1 OIP-2OIP-3
OIP-4
OIP-5
OIP-6 OIP-7
OIP-8
OIP-9
ST071-GW-2A
ST071-GW-2C
ST071-GW-1A
ST071-GW-1C
5000500150
T-914-203
T-914-711
T-914-712
BV-1
BV-2
BV-3
BV-4
SV-1
SV-2
SV-3
SV-4
T-914-017
T-914-018T-914-019
Figure 5.1
Remediation System Layout
Legend
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(5-01)Remediation_System_Layout.mxd
10/10/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Hill Air Force Base Boundary
2007 Approximate Free Product Extent
HGL-APTIM JV—ST071 Correction Action Plan Addendum
Hill AFB, Utah
012246
Feet
³
OIP/EC Probe Location and Response Percentage:
@R!0.0% - 9.9%
@R!10.0% - 29.9%
@R!30.0% - 49.9%
@R!50.0% - 69.9%
@R!70.0% - 100.0%
Utilities:
Water
Storm Water
Underground Petroleum Line
Analyte
Benzene 200 µg/kg
Toluene 9,000 µg/kg
Ethylbenzene 5,000 µg/kg
Xylenes 142,000 µg/kg
Naphthalene 51,000 µg/kg
TPH-GRO 150 mg/kg
TPH-DRO 500 mg/kg
Soil Screening Levels
UDEQ DERR ISLs
Analyte Concentrations (mg/kg):
TPH-GRO and Ethylbenzene5000
TPH-DRO500
TPH-GRO150
Tentative Location of Remediation Enclosure
Proposed Biovent Well!>
Proposed SVE Well!>
2023 SSI Groundwater Sample!A?
Abandoned Monitoring Well!A?
2004 Soil Boring!(
Monitoring Well!A?
Notes:
Utah Division of Environmental Response and Remediation, Initial
Screening Levels, November 1, 2005.
Preliminary data, not validated.
Bold text indicates analyte was detected.
Bold with highlight indicates analyte was detected above the ISL.
µg/kg=microgram per kilogram
bgs=below ground surface
ft=feet
ISL=initial screening level
J=value is estimated
mg/kg=milligram per kilogram
OIP/EC=Optical Image Profiler/Electrical Conductivity
SSI=Supplemental Site Investigation
SVE=soil vapor extraction
TPH-DRO=Total Petroleum Hydrocarbons Diesel Range Organics
TPH-GRO=Total Petroleum Hydrocarbons Gasoline Range Organics
U=Analyte was analyzed for but not detected.
UDEQ DERR=Utah Department of Environmental Quality Division
of Environmental Response and Remediation
UST=underground storage tank
Location ID
Sample ID
Sample Date
Sample Depth 34.5-35.5 ft bgs
Sample Type
Analyte Results Units
Benzene 230 U µg/Kg
Toluene 460 U µg/Kg
Ethylbenzene 190 µg/Kg
Xylenes 570 U µg/Kg
Naphthalene 2900 U µg/Kg
TPH-GRO 120 J mg/Kg
TPH-DRO 43 mg/Kg
ST071-OIP-01
ST071-OIP-01-SO-34.5-35.5
7/14/2023
Normal
Location ID
Sample ID
Sample Date
Sample Depth 27-28 ft bgs
Sample Type
Analyte Results Units
Benzene 75 U µg/Kg
Toluene 150 U µg/Kg
Ethylbenzene 150 U µg/Kg
Xylenes 190 U µg/Kg
Naphthalene 930 U µg/Kg
TPH-GRO 290 mg/Kg
TPH-DRO 560 mg/Kg
Normal
ST071-OIP-02
ST071-OIP-02-SO-27-28
7/17/2023
Location ID
Sample ID
Sample Date
Sample Depth 24.5-25.5 ft bgs
Sample Type
Analyte Results Units
Benzene 90 U µg/Kg
Toluene 180 U µg/Kg
Ethylbenzene 3700 J µg/Kg
Xylenes 17000 J µg/Kg
Naphthalene 1100 J µg/Kg
TPH-GRO 3,000 mg/Kg
TPH-DRO 100 mg/Kg
ST071-OIP-03
ST071-OIP-03-SO-24.5-25.5
7/17/2023
Normal
Location ID
Sample ID
Sample Date
Sample Depth 32-33 ft bgs
Sample Type
Analyte Results Units
Benzene 180 U µg/Kg
Toluene 350 U µg/Kg
Ethylbenzene 7100 J µg/Kg
Xylenes 33000 J µg/Kg
Naphthalene 3900 J µg/Kg
TPH-GRO 7,100 mg/Kg
TPH-DRO 1700 J mg/Kg
ST071-OIP-04
ST071-OIP-04-SO-32-33
7/17/2023
Normal
Location ID
Sample ID
Sample Date
Sample Depth 28.5-29.5 ft bgs
Sample Type Normal
Analyte Results Units
Benzene 86 U µg/Kg
Toluene 170 U µg/Kg
Ethylbenzene 1,700 µg/Kg
Xylenes 5,700 µg/Kg
Naphthalene 1100 U µg/Kg
TPH-GRO 410 mg/Kg
TPH-DRO 65 mg/Kg
ST071-OIP-07
ST071-OIP-07-SO-28.5-29.5
7/18/2023
Location ID
Sample ID
Sample Date
Sample Depth 37.5-38.5 ft bgs
Sample Type Normal
Analyte Results Units
Benzene 24 U µg/Kg
Toluene 48 U µg/Kg
Ethylbenzene 81 J µg/Kg
Xylenes 60 U µg/Kg
Naphthalene 300 U µg/Kg
TPH-GRO 17 mg/Kg
TPH-DRO 8.8 U mg/Kg
ST071-OIP-08-SO-37.5-38.5
7/19/2023
ST071-OIP-08
Location ID
Sample ID
Sample Date
Sample Depth 25.5-26.5 ft bgs
Sample Type
Analyte Results Units
Benzene 200 U µg/Kg
Toluene 400 U µg/Kg
Ethylbenzene 5800 J µg/Kg
Xylenes 58000 J µg/Kg
Naphthalene 2800 J µg/Kg
TPH-GRO 8400 J mg/Kg
TPH-DRO 260 mg/Kg
ST071-OIP-09
ST071-OIP-09-SO-25.5-26.5
7/14/2023
Normal
Location ID
Sample ID
Sample Date
Sample Depth 33-34 ft bgs 33-34 ft bgs
Sample Type
Analyte Results Units Results Units
Benzene 94 U µg/Kg 72 U µg/Kg
Toluene 190 U µg/Kg 140 U µg/Kg
Ethylbenzene 750 J µg/Kg 790 J µg/Kg
Xylenes 6,000 µg/Kg 6,600 µg/Kg
Naphthalene 1200 U µg/Kg 910 U µg/Kg
TPH-GRO 120 J mg/Kg 170 J mg/Kg
TPH-DRO 500 mg/Kg 86 mg/Kg
Duplicate
ST071-OIP-06
ST071-OIP-06-SO-33-34
7/18/2023
Normal
Former UST 914.6
Location ID
Sample ID
Sample Date
Sample Depth 30-31 ft bgs
Sample Type
Analyte Results Units
Benzene 240 U µg/Kg
Toluene 1,000 µg/Kg
Ethylbenzene 480 U µg/Kg
Xylenes 1,000,000 µg/Kg
Naphthalene 15,000 µg/Kg
TPH-GRO 120 mg/Kg
TPH-DRO 3,900 mg/Kg
ST071-OIP-05-SO-30-31
7/14/2023
Normal
ST071-OIP-05
Figure 5.2
SVE Process Flow Diagram
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum
(5-02)SVE_Process_Flow_Diagram.cdr
9/27/2024 TA
Source: HGL. SCS Aquaterra
Not to Scale
Notes:
=inch”
PVC=polyvinyl chloride
Sch=schedule
SVE=soil vapor extraction
WC=water column
HGL-APTIM JV—ST071 Correction Action Plan Addendum—Hill AFB, Utah
SV
-4
SV
-3
SV
-2
SV
-1
Fl
o
w
Fl
o
w
Fl
o
w
Fl
o
w
2” SVE Well
See Figure 5.4 for Additional Details
Well Vault
See Figure 5.5 for Additional Details
Knockout Tank
82 gallon
Control
Panel
3” PVC
3”

S
t
e
e
l

S
t
a
c
k
4” PVC4”

P
V
C
4”

S
c
h

4
0

P
V
C
Filter
Silencer
Regenerative
Blower
Knockout Tank
High High Level
Float Switch
4” to 2.5”
Reducer
Vacuum Relief Valve
Inline Filter Assembly
0-300” WC
Pressure Transducer
2” Ball Valve
4” Sch 40 PVC
Header with 2” Inlet
2” Sch 40
PVC Pipe
(Sloped to Well)
Enclosure Wall
Sample Port
Rotameter
Flow Meter
2” Ball Valve
Pete’s Plug
Figure 5.3
Biovent Process Flow Diagram
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum
(5-03)Biovent_Process_Flow_Diagram.cdr
9/27/2024 TA
Source: HGL. SCS Aquaterra
Not to Scale
Notes:
=inch”
PVC=polyvinyl chloride
Sch=schedule
SVE=soil vapor extraction
WC=water column
HGL-APTIM JV—ST071 Correction Action Plan Addendum—Hill AFB, Utah
BV
-4
BV
-3
BV
-2
BV
-1
Control
Panel
2” PVC2” PVC
2”

S
c
h

4
0

P
V
C
Well Vault
See Figure 5.5 for Additional Details
2” Biovent Well
See Figure 5.4 for Additional Details
Filter
Silencer
0-50” WC
Pressure
Transducer
Air Flow
Regenerative
Blower
Pressure Relief Valve
Inlet Filter/Silencer2” Ball Valve
2” Header
2” Sch 40
PVC Pipe
(Sloped to Well)
Fl
o
w
Fl
o
w
Fl
o
w
Fl
o
w
Enclosure Wall
Sample Port
Rotameter
Flow Meter
2” Ball Valve
Not to Scale
Notes:
=inch”
Drawings are preliminary, actual system will
be determined following systems testing.
=inch”
ft=feet/foot
Min.=minimum
PVC=polyvinyl chloride
SVE=soil vapor extraction
Figure 5.4
Remediation Well Details
(SVE and Biovent)
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum
(5-04)Remediation_Well_Details.cdr
9/27/2024 TA
Source: HGL. SCS Aquaterra
HGL-APTIM JV—ST071 Correction Action Plan Addendum—Hill AFB, Utah
SVE - 15 ft
Biovent - 10 ft
3 ft
19 ft
12” Min.
12”
24”
36”
2” Diameter
Schedule 40 PVC
0.020” Slots
Filter Pack
Depth
SVE Wells - 40 ft
Biovent Wells - 35 ft
Top of Filter Pack
Hydrated Bentonite Chip Seal
2” Schedule 40 PVC Casing
2” PVC Tee
2” PVC Pipe
for SVE
and Biovent
Limit of Trench
Excavation
1/8“ per ft Slope
Toward Well
if Possible
Limit of Trench Excavation
6” Minimum Concrete (Depth)
12” Minimum Concrete (Width)
Ground Surface
H-20 Rated Well Cover
Figure 5.5
Pipe Trench Details
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum
(5-05)Pipe_Trench_Details.cdr
10/10/2024 TA
Source: HGL. SCS Aquaterra
Not to Scale
Notes:
=inch”
ft=feet/foot
SVE=soil vapor extraction
HGL-APTIM JV—ST071 Correction Action Plan Addendum—Hill AFB, Utah
#4 Rebar at 2 ft Centers
Where Concrete is not Present,
Backfill Upper 12” of Trench
with Native Soil and Finish Surface
to Match Existing Surface
Existing Pavement
2” SVE Pipes
and Biovent Pipes
Sand Backfill
#4 Rebar at 1 ft Centers
(1 Bar per Each Foot of Trench Width)
Native Soil Backfill
New Concrete (Minimum 6” Thick or Equivalent
to Existing Pavement, Whichever is Greater)
2” Minimum Separation
4” Minimum
2 ft Wider
than Trench
4” Minimum
36
”

M
i
n
i
m
u
m
6” Minimum
@R!
@R!
@R!
@R!
@R!
@R!
@R!
@R!
@R!
!
!
!
!
!
!
!
!
!
!A?
!A?!A?
!>
!>!>
!>
!>
!>
!>
!>
Former
Location of
UST 914.6
OIP-1
OIP-2
OIP-3
OIP-4
OIP-5
OIP-6
OIP-7
OIP-8
OIP-9
5000500150
BV-1
BV-2
BV-3
BV-4
SV-1
SV-2 SV-3
SV-4
T-914-017
T-914-018T-914-019
Figure 5.6
Biovent Treatment Zone
Legend
\\SRV-GST-01\hglgis\Hill_AFB_V1H001\ST071\CAP_Addendum\
(5-06)Biovent_Treatment_Zone.mxd
10/3/2024 TA
Source: HGL, EA
2022 Google Earth Imagery
Hill
Air Force Base
Map Extent
Site Location
Hill Air Force Base Boundary
Former UST
HGL-APTIM JV—ST071 Correction Action Plan Addendum
Hill AFB, Utah
OIP/EC Probe Location and Response Percentage:
@R!0.0% - 9.9%
@R!10.0% - 29.9%
@R!30.0% - 49.9%
@R!50.0% - 69.9%
@R!70.0% - 100.0%
Utilities:
Water
Storm Water
Underground Petroleum Line
Analyte Concentrations (mg/kg):
TPH-GRO and Ethylbenzene5000
TPH-DRO500
TPH-GRO150
Proposed Biovent Well!>
Proposed SVE Well!>
Monitoring Well!A?
Notes:
ft=feet
mg/kg=milligram per kilogram
OIP/EC=Optical Image Profiler/Electrical Conductivity
SVE=soil vapor extraction
TPH-DRO=Total Petroleum Hydrocarbons Diesel Range Organics
TPH-GRO=Total Petroleum Hydrocarbons Gasoline Range Organics
UST=underground storage tank
Tentative Location of Remediation Enclosure
018369
Feet
³
Biovent Well 25 ft Buffer
SVE Well 50 ft Buffer

APPENDIX A

HISTORICAL DATA

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This page was intentionally left blank.

APPENDIX B

FIELD DOCUMENTATION

This page was intentionally left blank.

APPENDIX B.1

CALIBRATION FORMS

This page was intentionally left blank.
Project: HAEB
Personnel: Kopsun
Weather:
Instument Tag/D:
CALIBRATION:
Parameter Time
ORP
ot53
OS8
Calibration Method
Calibration Check:
Parameter Time
|Comments/Issues:
Temp.
FIELD EQUIPMENT CALIBRATION FORM
Conc.
Project Number:
Rain
2KI00Si8 Instrument Type:
32°
Calibration Standard
Single Point:
Lot/ID Expires
22k32_Ie/24 1.0o.o2 22k4S
(O.00.02 22L|T
34to41e
(.415nSlcm 3GHo562
24
23
Multi-point:
Calibration Check Standard
Conc./Range Lot/1D Expires
STDL
Date:
Snow
Pressure 30.5O-H
YSI Puo DSS
Reading
H.o|
02
(0.08
L27.5
-374
O.48
i2l.y9
5.42
Reading Pass/Fail
Comments

APPENDIX B.2

GROUNDWATER SAMPLE COLLECTION FORMS

This page was intentionally left blank.
Fi gure 17-1 Groundwater Sam pling Lo g
Operable Unit: _~_,,,,.._i _0_1_1 __ M onltorfn g
Hill AF B ORC LTM/L T O and Compliance M onito ring
Contract No. W91238-20·C-0014
"""""0 _1....;?_-.... 3~ __ Date ..... ·:,.('-2.0_(_2. '-{-'---_Sampler c.\. k S' ~-tt
Weather: S8 ° S:,,.. ... "' _________ ..;;;..,.__+---------------Visito rs: ,-J o ~
, I ,,
Boring Dia. __ .., ___ c asing Dia. ~1".. ~a' ____ DTW: '-/ 4>. oo TD: __ 'l-= __ Pump Intake Depth _____ Pump Top Depth: _______ _
Purge/Sampling Met h od:
Low Flow:
calculat ed Purge Volume
Tu bing Diameter factor5:
Standard Met ho d
calculated Purge Volume
Caslnn Volume Factors (gal/ft)
{"""" h·._ P v-':':f Vial p H: ,...J A Det ph to Water @ Sampling:
Tubil18 ~&th X TublnJik eter + Pump ~ume X2 Purge V ume (ml) = Roundeif Purge Volume (ml)
3/8 in = 13 ml/ft l/2 In = 20ml/ft (Rounded to nearest 100 ml)
l . . Casing Vol ume Above Screen \ I \ Screen Volume j \
\ -__l__=_.,,..__-_____ = __ x \ x 3= \ +____.,__x \ ·=--...--
-::-;r;-~ Wate ol.(ft) Scr.L .(ft) Casing k ng. ~ ca~ Vol Scr.leng.(ft) ~ Purge V~l (gal) '., '''\ \ \ \ 'i' \ '
2 ' = 0.17; 4' • 0.6 6; 5" c 0 .85 Screen Interval Vo um e Factors (Cas. Dla./Borehole Dla}(ln) 2/8= 2.15 gal/ft; 4/14 = 2.83 gal/ft; 4/U = 4.55 gal/ft; S/10 = 2.64 gal/fL
Water Quality Instrum ent: Disposition of Purge Water: 9 0% Recharge Level: ft Sampling Fl ow Rat e .Sl00 ml/min?
~ .. ~~, ....
Cond. Turbidity Nitrate
Purge Vol pH (mS/c m) (NTU) 00 (mg/I) Ammonia (YSI)
Specify m l Temp (0.0}± (0.0) (0.Q) (0.0 ) ORP(mV) Chlorid e (VSI) (YSI) (mg/I) (mg/I) GW Level Comments Other
Time or gal (0.0)±1"C 0.2 ±10% <S NTU ±0.2 (O.O) ±lO mV (mg/I) (0.00) (0.00) (0.00) (ft below M P) (color/odor) Paramet ers
f '/'{ 'l... r---NA /\JA-/\lA "-J,l. ~A NA ~ ~ -------------Su lflde 1mfl/l)
Sulfate (mg/I)
OO(mg/1)
Total Iron IFeJ
(mg/lJ
Ferrous Iron
{Fe+2)(mg/l)
Purge Flow Rate
ml(O)or
gal/min (0.0)
1i-1e10 1 a ram . ..urru:ier
Stable? y N Y N y N y N y N y N of
Sampl e ID Time Dat e Analysis Bottles
Normal ~,C~\ -C.w -C.:O,i>--;J r'i'-l-z.. ~/ u:, /v -/ E Tf;Y:1'l h ~o µI(.{) 0
Duplicate
M S/M SD
Trip Bl ank
Equip Blank
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APPENDIX B.3

LOGBOOK

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•
Dat e 7 I I 'f I Z 3 3 7
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ST O 7 / Ct,: I + w <.,~~ -...1{;/IA.A
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I
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e,,J v a(L 1~1l ,'~ +-l-.e -(,rJ~~ n , IJl'f\ ,1hJ.-
\,., ~h l Wt--ov lin.;t,, iA'lh 'J C ,;iJ 1'i I \/
t----r---;---'('_t,·+-~ ""'-1--"" C,.> re. J / I J l2_D' -~ (_ p , (lfd :~
t---1-----t--r -lol{.._-I-Jv . \ rt~\..\ ' I ~-
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t--t---+--1 -1-0 _t~rt_, \t ~\,,+'\ "\ (o V\(,.¼_ W'e_•• ; , ih~; ..
~~·1~e~c,:011, +.-!-{ .u f-f"J. o, -h,e:rf .... , 6.,.._,~K
-
38 ,, Lo cati on ________ _ Date __
Proiect /Cl ient ___________ _
O I Or : \eA
Location __________ _
ProJect /Client __________ _
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APPENDIX B.4

BORING LOGS/WELL CONSTRUCTION DIAGRAMS

This page was intentionally left blank.
HAFB
Walker Padgett
Yellow Jacket
ST071
T-914-017
11/03/2023
Surge & Pump 15
17
2
44.85
54.80
2 0.164
10 0.164 1.64
(49)(5.06)=434
7 2.25 1.8
10 1.8 5.4
5.4 1.6 7
7
0857
0859
0909
0922
Begin Pumping 44.85 NR NR NR NR NR NR No initial geochems due to
very high turbidity
2.25 Pumped below
top of pump
Very muddy
Brown
Very muddy
Brown
Muddy
BrownBegin Pumping
Pumped dry -
below top of pump10
NR
3075 14.9 8.06 1.236 0.53 22.4
1
14 21 28 35
----------
--------------
3
Mega Monsoon pump
Geotech water level meter. YSI Pro DSS
2
ST071
T-914-017
11/03/23
0934
0938
0944
0953
0958
1011
1030
11/17/23
1203
1210
1215
1220
45.40
49.48
45.50
45.53
50.30
44.70
45.20
45.95
46.03
32
33
NR
1428.03
NR
NR
1831
380.33
54.42
-
0.88
5.00
0.50
NR NR NR NR NR
NR NR NR NR NR
NR NR NR NR NR
15.2 6.99 1.127 0.78 99.6
15.4 6.92 1.137 0.91 99.2
15.6 7.07 1.123 0.94 124.7
------
15.2 7.26 0.847 0.98 182.9
15.9 7.06 1.134 0.85 90.1
Begin pumping
10 gallons
14 gallons
Record
Geochems Below top of
pump
Pumped below
pumpable level
16 gallons
pumping ceased
Begin pumping
16 gallons
20 gallons
Begin pumping
20 gallons
30 gallons
pumping ceased
Begin pumping
Record
geochem 31
gallons
Muddy
Brown
Muddy
Brown
Cloudy
Brown
Cloudy
Cloudy-
Muddy
Cloudy
Clear
Clear
Clear
Clear
15.3 7.16 0.768 1.00 141.2
130.10.970.7657.1015.4
3
3
ST071
T-914-017
11/03/2023
1225
1230
34
35
45.94
45.41
0.91
0.13
Clear
Clear
15.1
14.8
7.08
7.11
0.759
0.762
1.10
1.07
131.1
136.2
NA
NA
0
0
3
54.6
11/17/2023
21
52 ft 1
0.3 - 1.0
X
HAFB
Yellow Jacket
Walker Padgett
ST071
T-914-018
11/03/2023
1 3
Surge & Pump 15
17 45.89
2
1050
1057
1100
1110
7
12
12
45.89
50.25 1800.64 16.2 6.97 1.149 0.58 114.3
46.25
Begin pumping
Pumped below
top of pump
Very
muddy
Very muddy
- muddy
Muddy
Very
muddy
Surged prior to pumping
Surged prior to pumping
NR
NR
NR
V1H001.31.03.01
2 3
ST071
T-914-018
11/03/2023
1118
1129
1137
1144
1152
1153
1201
1205
1211
1220
1225
21
23
28
35
37
37
40
45
50
52.5
50.30
46.20
50.50
49.20
46.45
49.60
48.49
48.51
48.52
1875.05
NR
NR
559.36
723
NR
NR
359.81
57.94
4.62
0.34
Cloudy
Slightly
cloudy NR
NR NR
NR NR
NR NR
NR
NR
NR
Muddy
Cloudy
Muddy
Cloudy
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
15.6 7.00 1.149 1.74 120.2
16.0 7.09 1.159 1.89 119.5
16.0 7.01 1.155 1.46 124.7
15.8 6.99 1.151 2.09 130.3
15.7 6.98 1.153 2.05 133.1
15.7
15.7
6.98
6.98
1.151
1.152
1.98
1.82
135.3
136.6
Pumped down
Resume
pumping
Ceased pumping
pumped below pump
Muddy
Slightly
cloudy
Slightly
cloudy
Clear
Clear
Cloudy
Muddy
Cloudy
Pumped more rapidly to
dewater well
Surged prior to pumping
Increased pump rate to purge well
3 3
ST071
T-914-018
11/03/2023
Clear12295548.51 0.03 15.7 6.97 1.150 1.85 137.4
HAFB
Walker Padgett
Yellow Jacket
ST071
T-914-019
11/03/2023
Surge & Pump 1517
2
47.49
60.51
1256
1302
1311
1319
8
8
13
47.49
48.20
NR NR NR NR NR NR
Begin pumping
Pumped below
pumpable level
-------Surged prior to pumping
Very
muddy
Very
muddy
MuddyPumped below
recharge level
Record geochems from onset of pumping2029.1 16.3 6.95 1.159 0.61 131.6
1 3
2 3
ST071
T-914-019
11/03/2023
Surged prior to pumping
Recorded geochem parameters
Recorded geochem
Surged prior to pumping
Raised pump 1 foot off bottom
Pumped below
returnable level
Pumped below
returnable level
Begin
Pumping
1328
1330
1342
1347
1356
1402
1408
1418
1422
1428
1434
13
15
21
25
32
37
40
43
46
48.50
51.42
53.50
48.70
NG
48.60
51.15
51.75
51.50
1329.4
1038.08
NR NR NR NR NR NR NR
230.75 16.1 6.94 1.168 1.36 134.2
54.36
21.93
13.53
15.8
16.0
16.2
7.01
6.95
6.94
1.166
1.164
1.166
1.70
1.48
1.22
137.6
141.0
143.3
Muddycloudy
Cloudy
Clear
Clear
Clear
Resume
pumping
3 3
ST071
T-914-019
11/03/2023
1440
1446
1452
49
52
55
51.79
51.86
51.87
1.72
0.76
0.61
16.2
16.0
16.1
6.93
6.98
6.92
1.162
1.161
1.162
1.22
1.23
1.24
144.5
145.4
146.1
Clear
Clear
Clear

APPENDIX B.5

SURVEY

This page was intentionally left blank.
Table B.5.1
Monitoring Well Survey Data, November 2023
Site ST071 Corrective Action Plan Addendum
UST Site 914, Hill Air Force Base, Utah
Surveyed
Location Well LOC ID
Northing (UTM
Z12 Meters)
Easting (UTM
Z12 Meters)
Top of Casing Elevation (ft
amsl) NAVD88 Elev. (Based
on BM-73-85) Description
DTW (btoc)
11-20-2023
Groundwater
Elevation
(ft amsl)
ST071 OIP-01 T-914-018 4552229.126 416424.017 4757.305 TOP CONCRETE NORTH SIDE
ST071 OIP-01 T-914-018 4552229.009 416424.019 4756.981 TOP PIPE 46.17 4710.81
ST071 OIP-03 T-914-017 4552228.074 416433.337 4757.125 TOP CONCRETE NORTH SIDE
ST071 OIP-03 T-914-017 4552227.961 416433.319 4756.828 TOP PIPE 44.84 4711.99
ST071 GW-1A T-914-019 4552229.43 416405.227 4757.105 TOP CONCRETE NORTH SIDE
ST071 GW-1A T-914-019 4552229.333 416405.231 4756.812 TOP PIPE 47.49 4709.32
Note:
amsl = above mean sea level
BM = bench mark
btoc = below top of casing
DTW = deth to water
ft = feet/foot
ID = identification
LOC = location
NAVD88 = north american vertical datum of 1088
UTM = universal transverse mercator
Page 1 of 1

APPENDIX C

OIP/HPT/EC LOGS

This page was intentionally left blank.
File:
OIP-01.OIHP
Date:
6/7/2023
Location:
Hill AFB, UT
Company:
Vista GeoScience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-02.OIHP
Date:
6/7/2023
Location:
Hill AFB, UT
Company:
Vista GeoScience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-03.OIHP
Date:
6/7/2023
Location:
Hill AFB, UT
Company:
Vista GeoScience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-04.OIHP
Date:
6/8/2023
Location:
Hill AFB, UT
Company:
Vista Geoscience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-05.OIHP
Date:
6/8/2023
Location:
Hill AFB, UT
Company:
Vista Geoscience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-06.OIHP
Date:
6/8/2023
Location:
Hill AFB, UT
Company:
Vista Geoscience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-08.OIHP
Date:
6/8/2023
Location:
Hill AFB, UT
Company:
Vista Geoscience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-09.OIHP
Date:
6/9/2023
Location:
Hill AFB, UT
Company:
Vista Geoscience
Project ID:
19294.08
Operator:
DF
Client:
HGL
5
10
15
20
25
30
35
40
45
50
55
60
0
61
De
p
t
h

(
f
t
)
100 2000 300
EC (mS/m)
50 1000 110
FLUOR [275GP01] (%)
50 10010 120
Abs. Piezometric Pressure (psi)
50 10010 120
HPT Press. Max (psi)
100 20020 320
HPT Flow Avg (mL/min)
500 100
Corr. HPT Press. (psi)
5 101520022
Abs. Piezometric Pressure (psi)
20 40052
Est. K (ft/day)
5010
Est. GW Spec. Cond. (μS/cm)
DR
A
F
T
File:
OIP-07.OIHP
Date:
6/9/2023
Location:
Hill AFB, UT
Company:
Vista Geoscience
Project ID:
19294.08
Operator:
DF
Client:
HGL
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
0
49
De
p
t
h

(
f
t
)
50 1000110
EC (mS/m)
20 400 58
FLUOR [275GP01] (%)
50 10010 110
Abs. Piezometric Pressure (psi)
50 10010 110
HPT Press. Avg (psi)
Visible Still - 17.90 ft
Visible Still - 27.90 ft
UV - 30.05 ft
UV - 31.20 ft
UV - 34.35 ft
UV - 39.75 ft
250209 288
HPT Flow Avg (mL/min)
50 10
Corr. HPT Press. (psi)
50 10
Abs. Piezometric Pressure (psi)
50 10
Est. K (ft/day)
50 10
Est. GW Spec. Cond. (μS/cm)

APPENDIX D

LABORATORY ANALYTICAL REPORTS
(Will be submitted separately.)

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APPENDIX E

LABORATORY DATA VALIDATION

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APPENDIX E.1

LABORATORY DATA VALIDATION REPORTS

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September 7, 2023
Eurofins Test America 280-179102-1 (08/07/2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
• Basewide UFP-QAPP (HGL-APTIM, 2020),
• Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
• Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
• Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
• NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific

criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
• Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
• Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.

Table 1-1
Sample Field and Laboratory ID Numbers

Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validatio
n Level
ST071-OIP-01-SO-
[34.5-35.5] 280-179102-2 SO 07/14/23
12:16 N SW8260D
SW8015D/GRO S2BVM
ST071-OIP-09-SO-
[25.5-26.5] 280-179102-3 SO 07/14/23
13:50 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
EB-071423 280-179102-4 WQ 07/14/23
14:26 EB
SW8260D
SW8015D/GRO
SW8015D/DRO
None
TB-071423 280-179102-5 WQ 07/14/23
07:00 TB
SW8260D
SW8015D/GRO
SW8015D/DRO
None
ST071-OIP-05-SO-
[30-31] 280-179102-6 SO 07/14/23
15:00 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.

Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.

Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS

Reason
Code Name
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING

Reason
Code Name
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT

Reason
Code Name
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
mple

2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. The laboratory notes the following sample receipt anomalies.
• 1 x 4 oz soil jar was received with no client label on it. The container was
correctly identified and logged by process of elimination for sample ST071-
O1P-05-SO-[30-31] (280-179102-6).
• There is a trip blank with the same sample ID and collection time listed twice
on the COC. One TB requests GRO and the other requests BTEXN. The
ERPIMS EDD cannot have the same sample ID logged twice or else it will
get errors. The GRO data from TB sample 280-179102-1 will be re-
identified to sample 280-179102-5. The client was notified on 8/4/23.
• Reanalysis of the following sample was performed outside of the analytical
holding time due to compounds over calibration in the initial analysis:
ST071-OIP-05-SO-[30-31] (280-179102-6). The sample was re-run at a
high dilution.
o The VOC sample results (Xylenes) are qualified J/UJ-HHL
The validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s).
• Toluene-d8 (Surr) failed the surrogate recovery criteria high for ST071-
OIP-09-SO-[25.5-26.5] (280-179102-3). Toluene-d8 (Surr) failed the

surrogate recovery criteria high for ST071-OIP-05-SO-[30-31] (280-
179102-6). Evidence of matrix interference is present; therefore, re-
extraction and/or re-analysis was not performed.
o The sample detected analytes are qualified J-SGH.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
Sample ST071-OIP-01-SO-[34.5-35.5] (280-179102-2) was used for spiking. Due to
native concentrations of target analytes the MS/MSD recoveries are unusable for
accuracy and precision measurements.
Field Blanks
The submitted trip and equipment blanks reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.

• Samples ST071-OIP-01-SO-[34.5-35.5] (280-179102-2)[500X], ST071-
OIP-09-SO-[25.5-26.5] (280-179102-3)[500X], ST071-OIP-05-SO- [30-31]
(280-179102-6)[500X] and ST071-OIP-05-SO-[30-31] (280-179102-
6)[5000X] required dilution prior to analysis. The reporting limits have been
adjusted accordingly.
• The following samples were diluted due to the nature of the sample matrix:
ST071-OIP-01-SO-[34.5-35.5] (280-179102-2), ST071-OIP-01-SO-[34.5-
35.5] (280-179102-2[MS]) and ST071-OIP-01-SO-[34.5-35.5] (280-
179102-2[MSD]). Elevated reporting limits (RLs) are provided.
2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s).
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
OIP-01-SO-[34.5-35.5] (280-179102-2). a,a,a-Trifluorotoluene failed the
surrogate recovery criteria high for ST071-OIP-09-SO-[25.5-26.5] (280-
179102-3). a,a,a-Trifluorotoluene failed the surrogate recovery criteria high
for ST071-OIP-05-SO-[30-31] (280-179102-6). a,a,a-Trifluorotoluene failed
the surrogate recovery criteria high for ST071-OIP-01-SO-[34.5-35.5]MS
(280-179102-2MS). a,a,a-Trifluorotoluene failed the surrogate recovery
criteria high for ST071-OIP-01-SO-[34.5-35.5]MSD (280-179102-2MSD).
Refer to the QC report for details. Evidence of matrix interference is present;
therefore, re-extraction and/or re-analysis was not performed.
o The associated detected sample results are qualified J-SGH

Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip blank reports all target analytes not detected.

Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Sample T-870-OIP-04N-SO-26-27 (280-179077-5)[100X] required dilution
prior to analysis. The reporting limits have been adjusted accordingly.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.

Field Blanks
The submitted equipment blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Due to the matrix being wet, non-homogenous, and clay-like the initial
volumes of seven and a half grams was used instead of fifteen grams. This
was done in order to protect the microwave equipment and to prevent
venting in preparation batch 280-619877. This deviated from the standard
procedure. T-870-OIP-10N-SO-28.5-29.5 (280-179077-2), T-870-OIP-05S-
SO-30.5-31.5 (280-179077-3) and T-870-OIP-04S-SO-28.5-29.5 (280-
179077-4). The reporting limits (RLs) have been adjusted proportionately.
• Due to the matrix being wet, non-homogenous, and clay-like in combination
with a strong chemical odor, the initial volumes of seven and a half grams
was used instead of fifteen grams in order to prevent equipment damage
and venting in preparation batch 280-619877. This deviated from the
standard procedure. T-870-OIP-04N-SO-26-27 (280-179077-5). The
reporting limits (RLs) have been adjusted proportionately.

• Due to the matrix being wet, non-homogenous, and clay-like in combination
with a strong chemical odor, the initial volumes of seven and a half grams
was used instead of fifteen grams in order to prevent equipment damage
and venting in preparation batch 280-619877. This deviated from the
standard procedure. T-870-OIP-03N-SO-26-27 (280-179077-6). The
reporting limits (RLs) have been adjusted proportionately.
3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
Field duplicates were not submitted.
4.0 CONCLUSION
The following samples were qualified based on this validation.
Field Sample
ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resu
lt
Lab
Qualifi
er
Validatio
n
Qualifier
Validation
Reason
Codes
ST071-OIP-01-
SO-[34.5-35.5]
280-
17910
2-2
M801
5V
Petroleum
Hydrocarbons
C6-C10
120 Q J1 J SGH
ST071-OIP-09-
SO-[25.5-26.5]
280-
17910
2-3
SW82
60D
Xylene, m,p-
(Sum of Isomers)
4600
0 D Q J SGH
ST071-OIP-09-
SO-[25.5-26.5]
280-
17910
2-3
SW82
60D Xylene, o- 1200
0 D Q J SGH
ST071-OIP-09-
SO-[25.5-26.5]
280-
17910
2-3
SW82
60D Xylenes, Total 5800
0 D Q J SGH
ST071-OIP-09-
SO-[25.5-26.5]
280-
17910
2-3
SW82
60D Ethylbenzene 5800 D Q J SGH
ST071-OIP-05-
SO-[30-31]
280-
17910
2-6
SW82
60D Naphthalene 1500
0 D J SGH
ST071-OIP-05-
SO-[30-31]
280-
17910
2-6
SW82
60D Xylenes, Total 1000
000 H D J HHL, SGH
ST071-OIP-05-
SO-[30-31]
280-
17910
2-6
SW82
60D Xylene, o- 1900
00 H D J HHL, SGH

Field Sample
ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resu
lt
Lab
Qualifi
er
Validatio
n
Qualifier
Validation
Reason
Codes
ST071-OIP-05-
SO-[30-31]
280-
17910
2-6
SW82
60D
Xylene, m,p-
(Sum of Isomers)
8100
00 H D J HHL, SGH
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B

Holding Time: The validator correctly noted that re-analysis was performed on sample ST071-OIP-05-
SO-[30-31] past holding time, however, the wrong reason code was applied. HAHL is the correct reason
code for this exceedance.

Qualification Changes: The reason code applied for holding time exceedances in sample
ST071-OIP-05-SO-[30-31] is changed to HAHL.

Matrix Spike/Matrix Spike Duplicate (MS/MSD): The validator stated the following in Section 2.2.4 :
“Sample ST071-OIP-01-SO-[34.5-35.5] (280-179102-2) was used for spiking. Due to native
concentrations of target analytes the MS/MSD recoveries are unusable for accuracy and precision
measurements.” This is not accurate as all analytes were non-detect or detected well below the spike
amount in the parent sample. Recoveries in the MS and/or MSD were below QC limits for ethylbenzene,
total xylenes, o-xylene, and m&p-xylene. These results should be qualified J/UJ. Additionally, RPDs
exceeded QC limits for all target VOCs. Ethylbenzene was the only target analyte detected in the parent
sample and this result should be qualified J.

Qualification changes: In sample ST071-OIP-01-SO-[34.5-35.5], the total xylenes, o-xylene,
and m&p-xylene results are qualified UJ, reason code MSL. The ethylbenzene result is
qualified J, reason code MSL,MSD.

Surrogates: The validator noted a high surrogate recovery in sample ST071-OIP-05-SO-[30-31] and
qualified all detections in this sample. However, some target analytes were reported from a separate re-
analysis that yielded passing surrogates. The surrogate qualifiers for these should be removed.

Qualification Changes: In sample ST071-OIP-05-SO-[30-31], the J qualifiers assigned to
total xylenes, o-xylene, and m&p-xylene are retained due to a holding time exceedance,
but the SGH reason codes are removed.

Gasoline Range Organics – 8015D GRO

Matrix Spike/Matrix Spike Duplicate (MS/MSD): The validator stated in Section 2.3.2 that MS/MSD
samples were not submitted. MS/MSD analyses were performed on sample ST071-OIP-01-SO-[34.5-
Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179102-1
HGL Reviewer John Tracy
Review Date 9/20/23
35.5]. MS/MSD recoveries were above QC limits, but the detection in the parent sample was greater than
4X the spike amount and %R is not applicable.

Qualification Changes: None

Equipment Blank: The validator noted a trip blank, but failed to mention that an equipment blank was
also submitted with this SDG and was free from contamination.

Qualification Changes: None

Surrogates: The validator high surrogate recoveries in three samples but failed to qualify two samples as
a result. These results should be qualified J.

Qualification Changes: The GRO results in samples ST071-OIP-09-SO-[25.5-26.5] and
ST071-OIP-05-SO-[30-31] are qualified J, reason code SGH.

Diesel Range Organics – 8015D DRO

Matrix Spike/Matrix Spike Duplicate (MS/MSD): The validator stated in Section 2.1.4 that MS/MSD
samples were not submitted. MS/MSD analyses were performed on sample ST071-OIP-01-SO-[34.5-
35.5]. All %Rs and RPDs were within QC limits.

Qualification Changes: None

HGL Data Validation Review Report
This validation review report represents any additional findings or corrections to the validation performed
by ELAB. All recalculations performed by HGL to correct and/or supplement the recalculations performed
by ELAB are included at the end of this document.
General issues:
NA
100QC spreadsheet
NA
VOCs – 8260D
Matrix Spike/Matrix Spike Duplicate (MS/MSD): In Section 2.2.4, The validator noted that MS/MSD
analysis had been performed but listed a parent sample from a different SDG. No MS/MSD analysis was
performed.
Qualification Changes: None
Recalculations: Several discrepancies were found on review.
•Non-target VOCs were selected for recalculations of initial calibration (mean RRF calibration),
ICV, and CCV data. The HGL reviewer performed recalculations for these QC elements using
target VOCs using the raw instrument results.
•The validator did not include a recalculation of a target analyte calibrated to a linear relationship.
HGL validator recalculated the instrument VMS_X4 ICal for naphthalene, which was calibrated to
a linear response.
•The validator did not include a recalculation of an instrument tune. HGL validator recalculated a
BFB tuning.
•The validator incorrectly recalculated total xylenes in the LCS. The validator summed the peak
areas and summed the RRFs for m,p-xylenes and o-xylene and quantified using the summed
values. The laboratory reports total xylenes as the sum of the individually determined m,p-
xylenes and o-xylene concentrations. The HGL reviewer recalculated the total xylenes result
using the laboratory’s methodology. The HGL reviewer also recalculated the total xylenes
concentration in the corresponding LCSD and the LCS/LCSD RPD.
•The HGL reviewer recalculated a target analyte %R and RPD in an LCS/LCSD pair associated
with soil sample analyses.
•The validator switched the recalculations of the recoveries for surrogate compounds toluene-d8
and DBFM in sample 280-179151-1; the recalculations of the quantitation for each surrogate
(using the raw data) are correct and this appears to be an error in creating the %R summary
table. The HGL reviewer created a corrected surrogate %R calculation table for this sample.
•The recalculations of the %R for all surrogate compounds in sample 280-179151-3 are incorrectly
associated with the recalculated recoveries. This is caused by the reported back-calculated
Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B/4 – Volatile Organic Compounds, Gasoline Range Organics,
Diesel Range Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179151-1
HGL Reviewer (Stage 2B) John Tracy
Review Date (Stage 2B) 9/20/23
HGL Reviewer (Stage 4) Ken Rapuano
Review Date (Stage 4) 10.23.24 (Revised 1/9/2025)
surrogate concentrations in the %R recalculations not matching the values in the surrogate
concentration recalculation tables. The HGL reviewer verified that all the variables used in the
back-calculation of surrogate concentrations were correct and this appears to be a transcription
or boilerplate error in creating the %R table. The HGL reviewer created a corrected surrogate %R
calculation table for this sample.
• The naphthalene result in sample ST071-01P-03-SO-[24.5-25.5] (280-179151-3) was quantitated
using the average response instead of the linear relationship weighted for 1/conc as reported by
the laboratory on the ICal summary page. The HGL reviewer recalculated this result using the
correct calibration model and confirmed the laboratory-reported result.

Gasoline Range Organics – 8015D GRO

Equipment Blank: The validator noted a trip blank but failed to mention that an equipment blank was also
submitted with this SDG and was free from contamination.

Qualification Changes: None

Recalculations:
• The ICal recalculations were performed on the ICal performed on 4/13/23, which is only
associated with aqueous QC samples. The HGL reviewer recalculated the TPH-GRO calibration
from the ICal performed on 5/1/23, which is associated with all soil sample results reported in this
SDG.
• The validator recalculated ICV and CCV %Rs that are not associated with soil sample analyses
and without requantifying from the raw data. The HGL reviewer requantified the ICV and a CCV
associated with the soil data reported in this SDG using the raw data.
• The data report did not include an MS/MSD analysis and the HGL reviewer recalculated an
LCS/LCSD RPD associated with the soil sample results.

Diesel Range Organics – 8015D DRO

Qualification Changes: None

Recalculations:
• The validator recalculated ICV and CCV %Rs that are not associated with soil sample analyses
and without requantifying from the raw data. The HGL reviewer requantified the ICV and a CCV
associated with the soil data reported in this SDG using the raw data.
• Batch MS/MSD analyses were performed on a site sample and included in the data report;
however, the validator did not include recalculations. The HGL reviewer recalculated the
MS/MSD %Rs and RPD from the raw data.
• The recalculation of target results in samples in the validation report includes a term for
%moisture; this term is actually the fraction of solids. The HGL reviewer was able to confirm a
result recalculated by the validator from the information provided in the validation report.

VOCs ICal Calculations (1 of 2)
SDG 280-179151-1
Concentration units: ug/L
Instrument VMS_G2
Analyzed 6/29/23
Summary Data pp. 269-281
Raw Data pp. 282-413
Toluene RRF = (A[x] x C[is])/(C[x] x A[is])
IS = Fluorobenzene
File ID Analyte Conc Analyte Resp IS Conc IS Resp Calculated RRF Reported RRF
G2_04135.D 1 50267 50 2348232 1.0703 1.0703
G2_04136.D 2 91769 50 2352968 0.9750 0.9750
G2_04137.D 5 224710 50 2360369 0.9520 0.9520
G2_04138.D 10 400441 50 2164049 0.9252 0.9252
G2_04139.D 50 2273466 50 2289030 0.9932 0.9932
G2_04140.D 100 4373988 50 2293482 0.9536 0.9536
G2_04141.D 200 8370820 50 2273115 0.9206 0.9206
Calculated Reported
Mean RRF 0.9700 0.9700
%RSD 5.3 5.3
VOCs ICal Calculations (2 of 2)
SDG 280-177385-1
Concentration units: ug/L
Instrument VMS G2
Analyzed 6/29/23
Summary Data pp. 269-281
Raw Data pp. 282-413
Naphthalene
IS = 1,4-Dichlorobenzene-d4 RRF = (A[x] x C[is])/(C[x] x A[is])
Calibration mode:Linear Response term (RT) = (A[x] x C[is])/A[is]
Weighting:1/x Conc calc = (RT-b)/m
Lab Sample ID File ID Analyte Conc
[Cx]
Analyte Resp
A[x]
IS Conc
C[is]
IS Resp
A[is]Calculated RRF Reported RRF Response Term
(RT)Weighting (1/x)Conc (calc)Conc (rep)
STD01 280-617896/15 G2 04135.D 1.00 44387 50 760985 2.9164 2.9164 2.916417538 1.000000000 1.22 1.22
STD02 280-617896/16 G2 04136.D 2.00 63982 50 768272 2.0820 2.0820 4.164020035 0.500000000 1.82 1.82
STD05 280-617896/17 G2 04137.D 5.00 153056 50 782534 1.9559 1.9559 9.779511178 0.200000000 4.54 4.54
STD10 280-617896/18 G2 04138.D 10.0 267788 50 716987 1.8675 1.8675 18.674536637 0.1 8.84 8.84
ICIS 280-617896/19 G2 04139.D 50.0 1735857 50 785187 2.2108 2.2108 110.537808191 0.02 53.3 53.3
STD100 280-617896/20 G2 04140.D 100 3474123 50 804468 2.1593 2.1593 215.926736676 0.01 104.2 104.2
STD200 280-617896/21 G2 04141.D 200 6402186 50 796683 2.0090 2.0090 401.802599026 0.0050 194.1 194.1
Weighted Average 3.814713896 Reported but not used 8.283825602 n=7
p=2
m (calculated)m (reported)b (calculated)b (reported)r2 (calc)r2 (reported)RSE (calculated)RSE (reported)
2.0680 2.0680 0.3949 0.3949 0.998 0.998 13.0 13.0
VOCs Tuning Calculations
SDG 280-179151-1
Batch 621324
Instrument VMS_G2
Analyzed 07/31/2023
Lab File ID: G2_04680.D
Summary data p. 215
Raw Data pp. 617-620
m/e Resp Base resp %R calc %R rep (raw)%R rep (summary)Relative ion Rel ion resp Rel %R calc Rel %R rep (raw)Rel %R rep (summary)
50 87816 439616 20.0 20.0 20.0 95 439616 20.0 20.0 20.0
75 223680 439616 50.9 50.9 50.9 95 439616 50.9 50.9 50.9
95 439616 439616 100.0 100 100 95 439616 100 100 100 Base ion
96 29488 439616 6.7 6.7 6.7 95 439616 6.7 6.7 6.7
173 0 439616 0.0 0.0 0.0 174 279424 0.0 0.0 0.0 No peak
174 279424 439616 63.6 63.6 63.6 95 439616 63.6 63.6 63.6
175 22888 439616 5.2 5.2 5.2 174 279424 8.2 8.2 8.2
176 269824 439616 61.4 61.4 61.4 174 279424 96.6 96.6 96.6
177 17752 439616 4.0 4.0 4.0 176 269824 6.6 6.6 6.6
VOCs ICV and CCV Calculations
SDG 280-179151-1
Concentration units: ug/L
Calculation of CCRF Back-calculation of conc (mean RRF)
CCRF=(A[x] x C[is])/(C[x] x A[is])C[x]= (A[x] x C[is])/(ICal RRF x A[is])
Standard ID: ICV 280-617896/22
File ID: G2_04143.D
Instrument VMS_G2
Analyzed 6/29/23
Summary Data pp. 565-567
Raw Data pp. 568-574
Benzene
IS = Fluorobenzene
Analyte Conc Analyte Resp IS Conc IS Resp RRF50 Calc RRF50 Rep Analyte conc (calc)Analyte conc (rep)
50 1967710 50 2144799 0.9174 0.9174 51.3 51.3
ICal RRF %D Calc %D Rep
0.8934 2.7 2.7
Standard ID: CCV 280-621324/2
File ID: G2_04681.D
Instrument VMS_G2
Analyzed 07/31/2023
Summary Data pp. 575-577
Raw Data pp. 578-582
m,p-Xylene
IS = Chlorobenzene-d5
Analyte Conc Analyte Resp IS Conc IS Resp RRF50 Calc RRF50 Rep Analyte conc (calc)Analyte conc (rep)
50 863834 50 443142 1.949 1.949 52.0 52.1
ICal RRF %D Calc %D Rep
1.876 3.9 3.9
VOCs LCS Calculations (aqueous)
SDG 280-179151-1
Calculation of conc:
C[x]= (A[x] x C[is])/(ICal RRF x A[is])(on column)
C[x]= C[on column] x DF
LCS 280-621218/4 LCSD 280-621218/5
Summary Data pp. 208 and 649 Summary Data pp. 210 and 649
Raw Data pp. 650-654 Raw Data pp. 661-666
m,p-Xylene m,p-Xylene
IS = Chlorobenzene-d5 IS = Chlorobenzene-d5
Target Mean RRF 1.4425 Target Mean RRF 1.4425
Target Response 486589 Target Response 483832
IS conc (ug/L)50 IS conc (ug/L)50
IS Response 323473 IS Response 327807
Dilution factor 1 Dilution factor 1
LCS conc (ug/L)52.1 LCSD conc (ug/L)51.2
Reported conc (ug/L)See below Reported conc (ug/L)See below
o-Xylene o-Xylene
IS = Chlorobenzene-d5 IS = Chlorobenzene-d5
Target Mean RRF 1.3974 Target Mean RRF 1.3974
Target Response 475312 Target Response 487904
IS conc (ug/L)50 IS conc (ug/L)50
IS Response 323473 IS Response 327807
Dilution factor 1 Dilution factor 1
LCS conc (ug/L)52.6 LCSD conc (ug/L)53.3
Reported conc (ug/L)See below Reported conc (ug/L)See below
Calculated total xylenes (ug/L)105 Calculated total xylenes (ug/L)104
Reported total xylenes (ug/L)105 Reported total xylenes (ug/L)105 Potential iterative rounding
calculated reported calculated reported
Spike NA 100 Spike NA 100
%R 105 105 %R 104 105
RPD 0 0
VOCs LCS Calculations (solid)
SDG 280-179151-1
Calculation of conc:
C[x]= (A[x] x C[is])/(ICal RRF x A[is])(on columns)
C[x]= C[on column] x DF x V[purge] / M[sample]
LCS 280-621218/4 LCSD 280-621218/5
Summary Data pp. 208 and 655 Summary Data pp. 210 and 667
Raw Data pp. 636-660 Raw Data pp. 668-672
Benzene Benzene
IS = Fluorobenzene IS = Fluorobenzene
Target Mean RRF 0.8934 Target Mean RRF 0.8934
Target Response 1891540 Target Response 2066972
IS conc (ug/L)50 IS conc (ug/L)50
IS Response 2197144 IS Response 2259047
Dilution factor 50 Dilution factor 50
On-column conc calc (ug/L)48.2 On-column conc calc (ug/L)51.2
Reported conc (ug/L)48.2 Reported conc (ug/L)51.2
V[purge] (L)0.005 V[purge] (L)0.005
mass[sample] (kg)0.005 mass[sample] (kg)0.005
LCS conc calc (ug/kg)2409 LCSD conc calc (ug/kg)2560
LCS conc rep (ug/kg)2410 LCSD conc rep (ug/kg)2560
calculated reported calculated reported
Spike NA 2500 Spike NA 2500
%R 96 96 %R 102 102
RPD 6 6
VOCs Method Blank Calculations
SDG 280-179151-1
MB 280-621218/9
Summary Data p. 787
Raw Data pp. 788-794
Concentrations in ug/L
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
IS = Fluorobenzene IS = Fluorobenzene IS = Chlorobenzene-d5 IS = 1,4-Dichlorobenzene-d4
Target mean RRF 0.2906 Target mean RRF 0.3206 Target mean RRF 4.1357 Target mean RRF 0.9810
Target Response 324036 Target Response 399884 Target Response 1326059 Target Response 466674
IS conc 50 IS conc 50 IS conc 50 IS conc 50
IS Response 1338523 IS Response 1338523 IS Response 298845 IS Response 438252
On-column (calc)41.7 On-column (calc)46.6 On-column (calc)53.6 On-column (calc)54.3
On-column (rep)41.6 On-column (rep)46.6 On-column (rep)53.6 On-column (rep)54.3
Spike 50.0 Spike 50.0 Spike 50.0 Spike 50.0
%R calc (raw)83.31 %R calc (raw)93.18 %R calc (raw)107.29 %R calc (raw)108.55
%R rep (raw)83.30 %R rep (raw)93.18 %R rep (raw)107.29 %R rep (raw)108.55
%R rep (summary)83 %R rep (summary)93 %R rep (summary)107 %R rep (summary)109
VOCs Method Blank Calculations
SDG 280-179151-1
MB 280-621290/3-A
Summary Data p. 635
Raw Data pp. 788-794
Concentrations in ug/L
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
IS = Fluorobenzene IS = Fluorobenzene IS = Chlorobenzene-d5 IS = 1,4-Dichlorobenzene-d4
Target mean RRF 0.2222 Target mean RRF 0.2419 Target mean RRF 4.6151 Target mean RRF 0.9657
Target Response 479832 Target Response 530905 Target Response 2143986 Target Response 716262
IS conc 50 IS conc 50 IS conc 50 IS conc 50
IS Response 2257631 IS Response 2257631 IS Response 450838 IS Response 678661
On-column (calc)47.8 On-column (calc)48.6 On-column (calc)51.5 On-column (calc)54.6
On-column (rep)47.8 On-column (rep)48.6 On-column (rep)51.5 On-column (rep)54.6
Spike 50.0 Spike 50.0 Spike 50.0 Spike 50.0
%R calc (raw)96 %R calc (raw)97 %R calc (raw)103 %R calc (raw)109
%R rep (raw)4783.38 %R rep (raw)4860.52 %R rep (raw)5152.19 %R rep (raw)5464.54
%R rep (summary)96 %R rep (summary)97 %R rep (summary)103 %R rep (summary)109
The expected value in the quantitation reports is erroneously presented as 1 ug/L, although 50 ug/L is presented on p. 648. This appears to be due to the effective 50x dilution from methanol extraction is not applied in the quant report.
The corrrect spike amount was used to calculate the %Rs presented in the surrogate summary on p. 206; the laboratory has been alerted to this discrepancy.
Analyte amount amount injected DV recovery %Lab Source
1,2-Dichloroethane-d4 49.63154 50 99.26308 99%222
Analyte amount amount injected DV recovery %Lab Source
4-BFB 56.91277 50 113.82554 114%222
Analyte amount amount injected DV recovery %Lab Source
DBFM 47.02239 50 94.04478 94%222
Analyte amount amount injected DV recovery %Lab Source
Toluene-d8 51.95672 50 103.91344 104%222
Analyte amount amount injected DV recovery %Lab Source
1,2-Dichloroethane-d4 53.01634 50 106.032671 106%237
Analyte amount amount injected DV recovery %Lab Source
4-BFB 68.09542 50 136.190835 136%237
Analyte amount amount injected DV recovery %Lab Source
DBFM 47.00552 50 94.011034 94%237
Analyte amount amount injected DV recovery %Lab Source
Toluene-d8 62.21455 50 124.429106 124%237
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Sample ID: ST071-01P-02-SO-[27-28] (280-179151-1)
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Sample ID: ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
VOCs Target Calculations
SDG 280-179151-1
Sample ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Naphthalene
IS = 1,4-Dichlorobenzene-d4 Page
Target slope (m1)2.0680 274
Target intercept (b)0.3949 274
Target Response 145192 239
IS conc (ug/L)50 237
IS Response 713200 237
On-column (calc) (ug/L)4.73 calc
On-column rep (ug/L)4.73 239
Dilution factor 200 237
Purge volume (L)0.005 237
Sample mass (kg)0.005671 236
Fraction solids 0.785 236
Final conc (calc) (ug/kg)1063 calc
Reported conc (ug/kg)1100 236
GRO ICal Calculations
SDG 280-179151-1
Instrument VGC_S1
Analyzed 05/01/2023
Summary Data pp. 748-750
Raw Data pp. 798-823
Concentration units: ug/L
TPH-GRO
Calibration mode:Linear
Weighting:1/x^2
CF=Ax / Cx Conc calc = (A[x]-b)/m
Lab Sample ID File ID Analyte Conc
[Cx]
Analyte Resp
A[x]Calculated CF Reported CF Weighting (1/x^2)Conc (calc)Conc (rep)
IC 280-610832/3 S02344.D 3.97296 4071026 1024683.3595 1024683.3595 0.063353646 4.10 4.10
IC 280-610832/4 S02345.D 8.277 5166683 624221.6987 624221.6987 0.01459668 7.77 7.77
IC 280-610832/5 S02346.D 41.385 14940452 361011.2843 361011.2843 0.000583867 40.5 40.5
IC 280-610832/6 S02347.D 82.77 26288585 317610.0640 317610.0640 0.000145967 78.5 78.5
IC 280-610832/7 S02348.D 165.54 56748261 342806.9409 342806.9409 3.64917E-05 180.5 180.5
IC 280-610832/8 S02349.D 827.7 264624362 319710.4772 319710.4772 1.45967E-06 876.7 876.7
IC 280-610832/9 S02350.D 1655.4 493196846 297932.1288 297932.1288 3.64917E-07 1642.2 1642.2
IC 280-610832/10 S02351.D 3310.8 952942409 287828.4430 287828.4430 9.12293E-08 3181.9 3181.9
Weighted Average 5.296315468 4428628.295 Reported but not used n=8
p=2
m (calculated)m (reported)b (calculated)b (reported)r2 (calc)r2 (reported)RSE (calculated)RSE (reported)
298595.838 298595.838 2847170.54 2847170.54 0.999 0.9960 5.9 5.9
0.999 Unadjusted correlation coefficient
Spike concentrations are unrounded from the raw data instead of the rounded values on the summary forms.
TPH-GRO CCV Calculations
SDG 280-179151-1
Concentration units: ug/L
Calculation of CCRF Back-calculation of conc
CCRF=A[x] / C[x] (calc)C[x]= (A[x]-b)/m
Standard ID: ICV 280-610832/12
File ID: S02353.D
Instrument VGC_S1
Analyzed 05/01/2023
Summary Data pp. 856-857
Raw Data pp. 826-829
GRO C6-C10
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep
Analyte
conc (calc)
C[x]
Analyte on-
column
conc (rep)
Analyte summary
conc (rep)%D Calc %D Rep
447.5 132103463 295203 295174 432.9 432.9 21600 -3.3 -3.3
m b
298595.838 2847170.542 Note: Concentrations reported in the summary page include a 50x workup factor for medium-level analysis (prep log, p. 901)
Standard ID: CCV 280-620733/2
File ID: S04011.D
Instrument VGC_S1
Analyzed 07/25/2023
Summary Data p. 844-845
Raw Data pp. 826-829
GRO C6-C10
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep
Analyte
conc (calc)
C[x]
Analyte on-
column
conc (rep)
Analyte summary
conc (rep)%D Calc %D Rep
165.5 51095475 308734 308659 161.6 161.6 162 -2.4 -2.4
m b
298595.838 2847170.542 Note: Spike conc on summary page is rounded; actual spike conc reported from quant report
TPH-GRO LCS/LCSD RPD
SDG 280-179151-1
Back-calculation of conc (on-column) ug/L Back-calculation of soil conc mg/kg
C[x]= (A[x]-b)/m C[soil]= ((C[on column] x DF x V[purge]) / (M[sample]) * 0.001 mg/ug
Standard ID: LCS 280-620736/1-A
File ID: S04012.D
Instrument VGC_S1
Analyzed 11/14/2023 DF 50 Workup of 0.1 mL sample extract to 5 mL purge for medium-level analysis
Summary Data pp. 689 and 952 V[purge] (L)0.005
Raw Data pp. 953-956 M[sample] (kg)0.005
ug to mg 0.001
GRO C6-C10
Spike (mg/kg)Analyte Resp
A[x]
Analyte conc
(calc) ug/L
Analyte conc
(rep) ug/L
Analyte conc
(calc) mg/kg
Analyte conc
(rep) mg/kg %R Calc %R Rep
9.84 60298032 192.4 192.4 9.62 9.62 98 98
m b
298595.838 2847170.542
Standard ID: LCSD 280-620736/2-A
File ID: S04013.D
Instrument VGC_S1
Analyzed 11/14/2023 DF 50 Workup of 0.1 mL sample extract to 5 mL purge for medium-level analysis
Summary Data pp. 691 and 952 V[purge] (L)0.005
Raw Data pp. 953-956 M[sample] (kg)0.005
ug to mg 0.001
GRO C6-C10
Spike (mg/kg)Analyte Resp
A[x]
Analyte conc
(calc) ug/L
Analyte conc
(rep) ug/L
Analyte conc
(calc) mg/kg
Analyte conc
(rep) mg/kg %R Calc %R Rep RPD (calc)RPD (rep)
9.84 59633207 190.2 190.2 9.51 9.51 97 97 1 1
m b
298595.838 2847170.542
On-column Summary
On-column Summary
TPH-GRO Method Blank Calculations
SDG 280-179151-1
MB 280-619974/6
Summary Data pp. 687 and 864
Raw Data pp. 865-868
Concentrations in ug/L
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
a,a,a-TFT
Target ICal CF 358047.375
Target Response A[x]21515453
On-column conc (calc)60.1
On-column conc (rep)60.1
Spike conc 60.0
%R calc 100.15
%R rep (raw)100.15
%R rep (summary)100
TPH-GRO Method Blank Calculations
SDG 280-179151-1
MB 280-620736/3-A
Summary Data pp. 686 and 869
Raw Data pp. 865-868
Concentrations in ug/L
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
a,a,a-TFT
Target ICal CF 394701.079
Target Response A[x]21175811
On-column conc (calc)53.7
On-column conc (rep)53.7
Spike conc 60.0
%R calc 89.42
%R rep (raw)89.42
%R rep (summary)89
TPH-DRO ICV and CCV Calculations
SDG 280-179151-1
Concentration units: ug/mL
Calculation of CCRF Back-calculation of conc
CCRF=A[x] / C[x] (calc)C[x]= A[x] / CF ICal
Standard ID: ICV 280-621008/18
File ID: 0727018.D
Instrument SGC_U2a
Analyzed 07/27/2023
Summary Data pp. 980-981
Raw Data pp. 982-985
DRO C10-C28
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep Analyte conc (calc)
C[x]
Analyte on-
column conc
(rep)
Analyte
summary
conc (rep)
%D Calc %D Rep
2000 201132789 100566 100566 2201.5 2201.5 2200 10.1 10.1
CF ICal
91361.0022
Standard ID: CCV 280-634450/23
File ID: 0731013.D
Instrument SGC_U2a
Analyzed 07/31/2023
Summary Data pp. 992-993
Raw Data pp. 994-997
DRO C10-C28
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep Analyte conc (calc)
C[x]
Analyte on-
column conc
(rep)
Analyte
summary
conc (rep)
%D Calc %D Rep
5000 474086169 94817 94817 5189.2 5189.2 5190 3.8 3.8
CF ICal
91361.0022
DRO MS/MSD Calculations
SDG 280-179151-1
Back-calculation of conc (on-column) ug/mL Back-calculation of soil conc mg/kg
C[x]= A[x] / CF ICal C[soil]= ((C[on column] x DF x V[ext]) / (M[sample]*fsolids))*0.001 mg/ug
280-179151-4 280-179151-4 MS 280-179151-4 MSD
Summary Data pp. 912 and 931 Summary Data pp. 912 and 1067 Summary Data pp. 913 and 1073
Raw Data pp. 932-966 Raw Data pp. 1068-1072 Raw Data pp. 1074-1078
TPH-DRO TPH-DRO TPH-DRO
Target ICal CF 91361.0022 Target ICal CF 91361.0022 Target ICal CF 91361.0022
Target Response A[x]1008362182 Target Response A[x]846705602 Target Response A[x]746666464
On-column conc (calc)11037 On-column conc (calc)9267.7 On-column conc (calc)8172.7
On-column conc (rep) ug/mL 11037 On-column conc (rep)9267.7 On-column conc (rep)8172.7
Dilution Factor 1 Dilution Factor 1 Dilution Factor 1
Volume extract mL 1 Volume extract mL 1 Volume extract mL 1
Mass sample kg 0.00759 Mass sample kg 0.00751 Mass sample kg 0.00756
Fraction solids 0.833 Fraction solids 0.833 Fraction solids 0.833
Result (calc) mg/kg 1746 Result (calc) mg/kg 1481 Result (calc) mg/kg 1298
Result (rep) mg/kg 1700 Result (rep) mg/kg 1480 Result (rep) mg/kg 1300
calculated reported calculated reported
Parent conc 1745.7 1700 Parent conc 1745.7 1700
Spike NA 320 Spike NA 318
%R -83 -83 %R -141 -141
RPD 13 13
TPH-DRO Method Blank Calculations
SDG 280-179151-1
MB 280-620527/1-A
Summary Data pp. 908 and 1046
Raw Data pp. 1047-1051
Concentrations in ug/mL (=mg/L)
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
o-Terphenyl n-Octacosane
Target ICal CF 103424.627 Target ICal CF 98118.4781
Target Response A[x]3641177 Target Response A[x]2338633
On-column conc (calc)35.2 On-column conc (calc)23.8
On-column conc (rep)35.2 On-column conc (rep)23.8
Spike conc 35.0 Spike conc 35.0
%R calc 100.59 %R calc 68.10
%R rep (raw)100.59 %R rep (raw)68.10
%R rep (summary)101 %R rep (summary)68
TPH-DRO Method Blank Calculations
SDG 280-179151-1
MB 280-620310/1-A
Summary Data pp. 907 and 1040
Raw Data pp. 1041-1045
Concentrations in ug/mL (=mg/L)
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
o-Terphenyl n-Octacosane
Target ICal CF 103424.627 Target ICal CF 98118.4781
Target Response A[x]3078464 Target Response A[x]3286270
On-column conc (calc)29.8 On-column conc (calc)33.5
On-column conc (rep)29.8 On-column conc (rep)33.5
Spike conc 35.0 Spike conc 35.0
%R calc 85.04 %R calc 95.69
%R rep (raw)85.04 %R rep (raw)95.69
%R rep (summary)85 %R rep (summary)96
1
June 27, 2024
(September 12, 2023)
Eurofins Test America SDG: 280-179151-1 05/07/2023
Hill AFB VI Monitoring Program, UT – ST071
John Tracy
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190
Basewide Remedial Action-Operations Performance and Compliance Monitoring at Hill
Air Force Base, Utah.
Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP -
QAPP (HGL-APTIM JV, 2022) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense and Department of Energy Quality Systems
Manual for Environmental Laboratories Version 5.4 (Oct, 2021), Department of
Defense General Data Validation Guidelines November 2019 Revision 1 (DoD, 2019),
and Data Validation Guidelines Module 1 (2020) and Module 4 (2021).
Alexandrea Armfield Schulz Larry Duty
Data Validation Project Manager Data Validation Project Manager
E-Lab Consultants E-Lab Consultants
2
Table of Contents
1.0 INTRODUCTION ........................................................................................................... 4
2.0 Laboratory Data Package Review ................................................................................. 9
Case Narrative Review, Sample Documentation, Preservation, Handling, and Transport ..... 9
2.1 VOCs by SW846-8260D ............................................................................................ 9
2.1.1 Blanks ................................................................................................................... 9
2.1.2 Surrogate Recoveries .......................................................................................... 10
2.1.3 Laboratory Control Sample Recovery (Blank Spikes) .......................................... 10
2.1.4 Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 10
2.1.5 Field Blanks ......................................................................................................... 10
2.1.6 Instrument Initial Calibrations .............................................................................. 10
2.1.7 Initial Calibration Verifications .............................................................................. 10
2.1.8 Continuing Calibrations ....................................................................................... 10
2.1.9 Internal Standards ............................................................................................... 10
2.1.10 Target Compound Identification ....................................................................... 10
2.1.11 Compound Quantitation and Reporting Limits.................................................. 10
2.2 TPH-GRO SW846-8015D ....................................................................................... 11
2.2.1 Blanks ................................................................................................................. 11
2.2.2 Surrogate Recoveries .......................................................................................... 11
2.2.3 Laboratory Control Sample Recovery (Blank Spikes) .......................................... 11
2.2.4 Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 11
2.2.5 Field Blanks ......................................................................................................... 11
2.2.6 Instrument Initial Calibrations .............................................................................. 11
2.2.7 Initial Calibration Verifications .............................................................................. 11
2.2.8 Continuing Calibrations ....................................................................................... 11
2.2.9 Internal Standards ............................................................................................... 11
2.2.10 Target Compound Identification ....................................................................... 11
2.2.11 Compound Quantitation and Reporting Limits.................................................. 12
2.3 TPH-DRO SW846-8015D ........................................................................................ 12
2.3.1 Blanks ................................................................................................................. 12
2.3.2 Surrogate Recoveries .......................................................................................... 12
2.3.3 Laboratory Control Sample Recovery (Blank Spikes) .......................................... 12
2.3.4 Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 12
2.3.5 Field Blanks ......................................................................................................... 12
2.3.6 Instrument Initial Calibrations .............................................................................. 12
2.3.7 Initial Calibration Verifications .............................................................................. 12
2.3.8 Continuing Calibrations ....................................................................................... 12
3
2.3.9 Internal Standards ............................................................................................... 12
2.3.10 Target Compound Identification ....................................................................... 12
2.3.11 Compound Quantitation and Reporting Limits.................................................. 13
2.3.12 FIELD DUPLICATE RESULT AGREEMENT ................................................... 13
3.0 CONCLUSION ............................................................................................................ 13
4
1.0 INTRODUCTION
This Stage 2B/Stage 4 Data Validation Report, DVR, conducted for Hill AFB VI
Monitoring Program, contains the results of the validation of SDG 280-179151-1,
conducted for samples collected and analyzed by Eurofins, Denver as part of the
Optimized Remediation Contract for Hill AFB, UT – ST071. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party data
validation purposes. Table 1-1 identifies the field sampling and analytical information
applicable to this DVR, including field sample numbers and associated laboratory
sample identifications with field sample matrix, purpose, analytical methods requested,
and data validation levels.
These samples were analyzed in accordance with the approved Department of
Defense and Department of Energy Quality Systems Manual for Environmental
Laboratories Version 5.4(2021) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents; •Basewide UFP-QAPP (HGL-APTIM, 2022),
•Department of Defense and Department of Energy Quality Systems Manual for
Environmental Laboratories Version 5.4 (DoD, 2021),
•Department of Defense Data Validation Guidelines, Module 1 (2020) and Module 4 (2021),
•the method specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in the UFP-
QAPP and DoD QSM for the data quality parameters of sensitivity, accuracy,
precision, and completeness. Attached to this DVR is the laboratory data sheets that
have been annotated with qualifiers assigned during the validation process in
accordance with the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific
criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
5
•Organic Analysis; internal standards, continuing calibration verification,
internal standards, degradation summary, retention times, second column or
second detector confirmations, retention time windows,
•Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing
calibration verification, initial and continuing calibration blanks, interference
check sample, internal standards, serial dilution results, post digestion spike
recoveries, and interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if data
have been qualified.
6
Table 1-1
Sample Field and Laboratory ID Numbers
Lab ID Field ID Matrix Sample Date Purpose Analytical
Method
Validation
Level
280-179151-1 ST071-01P-02-SO-[27-28] Solid 07/17/23 11:45 N 8260D L2BVM
280-179151-2 TB-071723 Water 07/17/23 07:00 TB 8260D L2BVM
280-179151-3 ST071-01P-03-SO-[24.5-
25.5] Solid 07/17/23 12:30 N 8260D L4VM
280-179151-4 ST071-01P-04-SO-[32-33]Solid 07/17/23 13:59 N 8260D L2BVM
280-179151-5 EB-071723 Water 07/17/23 14:43 EB 8260D L2BVM
Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
L2BVM Level 2b Validation ManuaL
L4VM Level 4 Validation Manual
7
Following the specifications in the UFP QAPP related to the data validation process, the data were
annotated with data validation qualifiers and codes as presented in conclusion of this report. Table
1-2 provides definitions of the data qualifiers references, and Table 1-3 lists and defines the data
review qualifier codes.
Table 1 -2: Data Qualifier References
Qualifier Definition
No Qualifier
Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is
not affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and
meet QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and
meet QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.
Table 1 -3: Data Qualification Reason Codes
QC Element Reason Code Definition
Ambient Blank ABH Ambient blank result ≥LOQ
Ambient Blank ABHB Result is judged to be biased high based on associated ambient blank result
Ambient Blank ABL Ambient blank result <LOQ
Analyte Quantitation ACR Result above the upper end of the calibrated range
Analyte Quantitation EXC Result excluded; another data point for this analyte was selected for use
(use with X-qualified results)
Analyte Quantitation RTW Target analyte outside retention time window
Analyte Quantitation PSL Solid matrix sample with percent solids less than 50%
Analyte Quantitation PSLX Solid matrix sample with percent solids less than 10%
Analyte Quantitation TR Result between the DL and LOQ
Calibration Blank CBH Initial or continuing calibration blank result ≥LOQ
Calibration Blank CBHB Result is judged to be biased high based on associated continuing
calibration blank result
Calibration Blank CBL Initial or continuing calibration blank result <LOQ
Calibration Blank CBN Negative initial or continuing calibration blank result with absolute value
<LOQ
Calibration Blank CBNH Negative initial or continuing calibration blank result with absolute value
≥LOQ
Continuing
Calibration CCCC Calibration check compound did not meet %D criterion in continuing
calibration standard
Continuing
Calibration CCVD Continuing calibration standard did not meet %D criterion
Continuing
Calibration CRFL Continuing calibration RRF below acceptance criterion
8
QC Element Reason Code Definition
Continuing
Calibration CSPC System performance check compound did not meet minimum RRF criterion
in continuing calibration
Continuing
Calibration CVDX Continuing calibration standard did not meet %D criterion, extreme
discrepancy
Confirmation CF Confirmation precision exceeded acceptance criterion
Cyanide Method DSH High-level distillation standard did not meet %D criterion
Cyanide Method DSL Low-level distillation standard did not meet %D criterion
Equipment Blank EBH Equipment blank result ≥LOQ
Equipment Blank EBHB Result is judged to be biased high based on associated equipment blank
result
Equipment Blank EBL Equipment blank result <LOQ
Field Duplicate FDPA Field duplicate results did not meet absolute difference criterion
Field Duplicate FDPR Field duplicate results did not meet RPD criterion
Holding Time HTA Analytical holding time exceeded
Holding Time HTAX Analytical holding time exceeded, extreme discrepancy
Holding Time HTP Preparation holding time exceeded
Holding Time HTPX Preparation holding time exceeded, extreme discrepancy
Initial Calibration ICCC Calibration check compound did not meet %RSD criterion in initial
calibration
Initial Calibration ICLS Initial calibration low-level standard >LOQ
Initial Calibration ICR2 Initial calibration r2 below acceptance criterion
Initial Calibration ICRD Initial calibration %RSD above acceptance criterion
Laboratory Control
Sample LCLX LCS and/or LCSD %R below acceptance criterion, extreme discrepancy
Laboratory Control
Sample LCSH LCS and/or LCSD %R above acceptance criterion
Laboratory Control
Sample LCSL LCS and/or LCSD %R below acceptance criterion
Laboratory Control
Sample LCSP LCS/LCSD RPD above acceptance criterion
Laboratory Duplicate LDPA Laboratory duplicate results did not meet absolute difference criterion
Laboratory Duplicate LDPR Laboratory duplicate results did not meet RPD criterion
Low-Level
Calibration Check LLCH Low-level calibration check above the upper limit
Low-Level
Calibration Check LLCL Low-level calibration check below the lower limit
Low-Level
Calibration Check LLXL Low-level calibration check below the lower limit, extreme discrepancy
Method Blank MBH Method blank result ≥LOQ
Method Blank MBHB Result is judged to be biased high based on associated method blank result
Method Blank MBL Method blank result <LOQ
Matrix Spike MSH MS and/or MSD %R above acceptance criterion
Matrix Spike MSL MS and/or MSD %R below acceptance criterion
Matrix Spike MSLX MS and/or MSD %R below acceptance criterion, extreme discrepancy
Matrix Spike MSP MS/MSD RPD above acceptance criterion
9
QC Element Reason Code Definition
Post-Digestion
Spike PDH Post-digestion spike recovery high
Post-Digestion
Spike PDL Post-digestion spike recovery low
Post-Digestion
Spike PDLX Post-digestion spike recovery low, extreme discrepancy
Post-Digestion
Spike PDN Post-digestion spike not performed or not applicable and serial dilution result
not performed or not applicable
Sample Delivery and
Condition BUB Bubbles >5 mm in VOCs vial
Sample Delivery and
Condition DAM Sample container damaged
Sample Delivery and
Condition PRE Sample not properly preserved
Sample Delivery and
Condition TEMP Sample received at elevated temperature
Sample Delivery and
Condition TMPX Sample received at elevated temperature, extreme discrepancy
Serial Dilution SDIL Serial dilution did not meet %D criterion
Serial Dilution SDN Serial dilution not performed
Surrogate SSH Surrogate %R high
Surrogate SSL Surrogate %R low
Surrogate SSLX Surrogate %R low, extreme discrepancy
Surrogate SSN Surrogate compound not spiked into sample
Trip Blank TBH Trip blank result ≥LOQ
Trip Blank TBL Trip blank result <LOQ
Validator Judgment VJ Validator judgment (see validation narrative)
2.0 Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times. The
validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP. None of the data is qualified based on sample
documentation, preservation, handling, or transport.
2.1 VOCs by SW846-8260D
2.1.1 Blanks
Each analytical batch was represented with a method blank. The laboratory reports
10
none of the target compounds were detected in any of the method blanks.
2.1.2 Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s).
•4-Bromofluorobenzene (Surr) and Toluene-d8 (Surr) failed the surrogate recovery
criteria high for ST071-01P-03-SO-[24.5-25.5] (280-179151-3). Toluene-d8 (Surr)
failed the surrogate recovery criteria high for ST071-01P-04-SO-[32-33] (280-
179151-4). Evidence of matrix interference is present; therefore, re-extraction
and/or re-analysis was not performed.
o The associated detected analytes are qualified J-SGH.
2.1.3 Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
2.1.4 Matrix Spike/Matrix Spike Duplicate Recoveries
Sample ST071-OIP-01-SO-[34.5-35.5] (280-179102-2) was used for spiking. Due to
native concentrations of target analytes the MS/MSD recoveries are unusable for
accuracy and precision measurements.
2.1.5 Field Blanks
The submitted trip and equipment blanks reports all target analytes not detected.
2.1.6 Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
2.1.7 Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
2.1.8 Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12 -hour basis.
2.1.9 Internal Standards
Internal standards were reviewed for response and retention times.
2.1.10 Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
2.1.11 Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
11
•Samples ST071-01P-02-SO-[27-28] (280-179151-1)[200X], ST071-01P-03-SO-
[24.5-25.5] (280-179151-3)[200X] and ST071-01P-04-SO-[32-33] (280-179151-
4)[400X] required dilution prior to analysis due to the nature of the sample matrix.
The reporting limits have been adjusted accordingly.
2.2 TPH-GRO SW846-8015D
2.2.1 Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
2.2.2 Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s).
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071 -
01P-04-SO-[32-33] (280-179151-4). Evidence of matrix interference is
present; therefore, re-extraction and/or re-analysis was not performed.
o The associated detected sample results are qualified J-SGH
2.2.3 Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
2.2.4 Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
2.2.5 Field Blanks
The submitted trip blank reports all target analytes not detected.
2.2.6 Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
2.2.7 Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
2.2.8 Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12 -hour basis.
2.2.9 Internal Standards
Internal standards were reviewed for response and retention times.
2.2.10 Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
12
2.2.11 Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples ST071-01P-02-SO-[27-28] (280-179151-1)[20X], ST071-01P-03-
SO-[24.5-25.5] (280-179151-3)[100X] and ST071-01P-04-SO-[32-33] (280-
179151-4)[100X] required dilution prior to analysis. The reporting limits
have been adjusted accordingly.
2.3 TPH-DRO SW846-8015D
2.3.1 Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
2.3.2 Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
2.3.3 Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
2.3.4 Matrix Spike/Matrix Spike Duplicate Recoveries
Sample ST071-01P-04-SO-[32-33] (280-179151-4) was used for spiking. The native
concentrations were >4X the spike concentration. The MS/MSD results cannot be
used for accuracy and precision assessments.
2.3.5 Field Blanks
The submitted equipment blank reports all target analytes not detected.
2.3.6 Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
2.3.7 Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
2.3.8 Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12 -hour basis.
2.3.9 Internal Standards
Internal standards were reviewed for response and retention times .
2.3.10 Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
13
2.3.11 Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
•Due to the matrix having a very strong odor, the initial volumes used for the
following samples in preparation batch 280 -620310 deviated from the standard
procedure: ST071-01P-02-SO-[27-28] (280-179151-1), ST071-01P-03-SO-[24.5-
25.5] (280-179151-3), ST071-01P-04-SO-[32-33] (280-179151-4), (280-179151-
A-4 MS) and (280-179151-A-4 MSD). To prevent venting and to protect the
microwave equipment, the samples were ran at seven and a half grams instead
of the full fifteen grams. The reporting limits (RLs) have been adjusted
proportionately.
2.3.12 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared blow. Field duplicates were not
submitted.
3.0 CONCLUSION
The following samples were qualified based on this validation. Stage 4 independent calculated
results from the raw data are analogous to the reported results.
14
ICAL Analyte/IS: Vinyl chloride/FB
Amount Response ISTD Amt ISTD Resp Rel. Resp.
Lab Reported
Source Page 269
1.0 13328 50.0 2348232.0 0.28 0.2838 0.2838
2.0000 22329 50.0 2352968.0 0.47 0.2372 0.2372
5.0000 60781 50.0 2360369.0 1.29 0.2575 0.2575
10.0000 110491 50.0 2164049.0 2.55 0.2553 0.2553
50.0000 717908 50.0 2289030.0 15.68 0.3136 0.3136
100.0000 1287931 50.0 2293482.0 28.08 0.2808 0.2808
200.0000 2533400 50.0 2273115.0 55.73 0.2786 0.2786
AVG 0.2724 0.2724
COEF 0.9994574
%RSD 9.10 9.1
QC type Analyte spike recovery spike amount %D reported by lab Source
ICV 280-617896/22 Ethyl ether 52 50 4.0 4.1 565
CCV 280-621324/2 Iodomethane 44.7 50 -10.6 -10.6 575
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported Source Page
reported
LCS Source Page
Benzene/FB 50 46.50 93.00 93 18 46.5 649
Ethylbenzene/CBNZd5 50 52.07 104.14 104 18 52.1 649
Naphthalene/DCBd4 50 52.59 105.18 105 18 52.6 649
Toluene/FB 50 44.09 88.18 88 18 44.1 649
Xylenes, Total/CBNZd5 100 104.71 104.71 105 18 105 649
Sample ID: ST071-01P-02-SO-[27-28] (280-179151-1)
Analyte amount amount injected DV recovery %Lab reported Source
1,2-Dichloroethane-d4 49.63154 50 99.26307249 99%16
Analyte amount amount injected DV recovery %Lab reported Source
4-BFB 56.91277 50 113.8255388 114%16
Surrogate Recoveries
Surrogate Recoveries
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-179151-1 08/07/2023
Performed by E-Lab Consultants
Analy batch 617896 Inst VMS_G2 RRF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
ICV/CCV (form 7)
Surrogate Recoveries
LCS 280-621218/4
Analyte amount amount injected DV recovery %Lab reported Source
DBFM 51.95672 50 103.9134391 104%16
Analyte amount amount injected DV recovery %Lab reported Source
Toluene-d8 47.02239 50 94.04477606 94%16
Sample ID: ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Analyte amount amount injected DV recovery %Lab reported Source
1,2-Dichloroethane-d4 51.95672 50 103.9134391 104%237
Analyte amount amount injected DV recovery %Lab reported Source
4-BFB 47.02239 50 94.04477606 94%237
Analyte amount amount injected DV recovery %Lab reported Source
DBFM 53.01634 50 106.032671 106%237
Analyte amount amount injected DV recovery %Lab reported Source
Toluene-d8 68.09542 50 136.1908353 136%237
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Benzene/FB 1085752 1432545 50 0.815 1 46.49805217 46.5
Source page 651 650 650 590 649 649
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Ethylbenzene/CBNZd5 396479 323473 50 1.177 1 52.06858 52.1
Source page 651 650 650 591 649 649
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Naphthalene/DCBd4 717575 502026 50 1.359 1 52.58860 52.6
Source page 652 650 650 592 649 649
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Back Calculation of Data for Validation LCS
LCS 280-621218/4
Back Calculation of Data for Validation LCS
LCS 280-621218/4
Back Calculation of Data for Validation LCS
LCS 280-621218/4
Back Calculation of Data for Validation LCS
Surrogate Recoveries
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Toluene/FB 1143781 1432545 50 0.9055 1 44.08757 44.1
Source page 651 650 650 591 649 649
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Xylenes, Total/CBNZd5 961901 323473 100 2.84 1 104.70659 105
Source page 651 650 650 591 649 649
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
amount
injected
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
1,2-Dichloroethane-d4/FB 573717 2389319 50 0.2419 50 1 49.63153625 49.6
Source page 222 222 222 567 221 99%16
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
4-BFB/DCBd4 783085 712405 50 0.9657 50 1 56.91276941 56.9
Source page 222 222 222 567 221 114%16
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
Toluene-d8/CBNZ-d5 2327101 485257 50 4.615 50 1 51.95671956 52
Source page 222 222 222 567 221 104%16
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
DBFM/FB 499290 2389319 50 0.2222 50 1 47.02238803 47
Source page 222 222 222 566 221 94%16
calculation notation B C D E F G H I
Back Calculation of Data for Validation Surrogate
ST071-01P-02-SO-[27-28] (280-179151-1)
Back Calculation of Data for Validation Surrogate
ST071-01P-02-SO-[27-28] (280-179151-1)
ST071-01P-02-SO-[27-28] (280-179151-1)
LCS 280-621218/4
Back Calculation of Data for Validation LCS
LCS 280-621218/4
Back Calculation of Data for Validation Surrogate
ST071-01P-02-SO-[27-28] (280-179151-1)
Back Calculation of Data for Validation Surrogate
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
amount
injected
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
1,2-Dichloroethane-d4/FB 585175 2281446 50 0.2419 50 1 53.01633551 53
Source page 237 237 237 567 236 106%237
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
4-BFB/DCBd4 937997 713200 50 0.9657 50 1 68.09541764 68.1
Source page 237 237 222 567 236 136%237
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
Toluene-d8/CBNZ-d5 2734096 476124 50 4.615 50 1 62.21455297 62.2
Source page 237 237 237 567 236 124%237
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
DBFM/FB 476577 2281446 50 0.2222 50 1 47.00551714 47
Source page 237 237 237 566 236 94%237
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))

Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc
Lab reported
ug/kg
o-Xylene/CBNZ-d5 716111 476124 50 1.8132 5.671 0.786 5 200 9304.70 9300
Source page 239 237 237 272 236 236 648 236 236
calculation notation B C D E F G H I
calculation (C*E*J*I)/(D*F*(G*H))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc
Lab reported
ug/kg
Ethylbenzene/CBNZ-d5 234750 476124 50 1.5121 5.671 0.786 5 200 3657.57 3700
Back Calculation of Data for Validation Surrogate
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation Surrogate
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation Surrogate
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation Surrogate
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Source page 239 237 237 272 236 236 648 236 236
calculation notation B C D E F G H I
(C*E*J*I)/(D*F*(G*H))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc Lab reported
Naphthalene/DCBd4 145192 713200 50 2.068 5.671 0.786 5 200 1104.25 1100
Source page 239 237 237 272 236 236 648 236 236
calculation notation B C D E F G H I
((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc Lab reported
m-Xylene & p-Xylene /CBNZ-d5 575181 952248 100 1.8758 5.671 0.786 5 200 7224.13 7200
Source page 239 237 237 272 236 236 648 236 236
calculation notation B C D E F G H I
((B*D*I)/(C*E))
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
ICAL Analyte/IS: Diesel Range Organics [C10-C28]
Amount Response ISTD Amt
ISTD Resp pg.
180 Rel. Resp.
Lab Reported
Source Page 944
100 10176498 1 1 10176498 101765 101765
250 24069838 1 1 24069838 96279 96279
1000 78314792 1 1 78314792 78315 78315
5000 498369689 1 1 498369689 99674 99674
7500 646932963 1 1 646932963 86258 86258
15000 1249613769 1 1 1249613769 83308 83308
30000 2817859224 1 1 2817859224 93929 93929
AVG 91361 91361
COEF 0.998158807
%RSD 9.68 9.7
QC type Analyte spike recovery spike amount %D
reported by
lab Source page
ICV 280-621008/18 DRO[C10-C28]2200 2000 10.0 10.1 980
CCV 280-621262/13 DRO[C10-C28]5190 5000 3.8 3.8 992
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported
Source
Page
Lab reported
LCS Amount Source Page
DRO[C10-C28]133 107.23 80.62 80 21 107 1052
Sample ID: ST071-01P-02-SO-[27-28] (280-179151-1)
Analyte
amount
detected amount injected DV recovery %
Lab
reported Source Page
o-Terphenyl 26.54303 35 75.84 76%918
Sample ID: ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Analyte amount amount injected DV recovery %Lab Source Page
o-Terphenyl (Surr) 23.89984 35 68.28525611 68%926
Surrogate Recoveries
Surrogate Recoveries
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-179151-1 08/07/2023
Performed by E-Lab Consultants
Batch: 621008 SGC_U2a RRF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
ICV/CCV (form 7)
Surrogate Recoveries
LCS 280-620310/2-A
Analyte amount amount injected DV recovery %Lab Source Page
n-Octacosane 20.57911 35 58.79745849 59%926
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc
Lab Reported
mg/kg
DRO[C10-C28]146948807 1 1 91361.0022 15 0 1 1 107.2294184 107
Source page 1135 1135 1135 944 1052 1052
calculation notation B C D E F G H I
calculation ((C*E*I*J)/(D*F*(G*((100-H)/100))))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
o-Terphenyl 2745203 1 1 103424.627 7.54 80.3 1 1 26.54303022 26.5
Source page 1030 1030 1030 944 918 918 918 918 76%918
calculation notation B C D E F G H I
calculation ((C*E*J)/(D*F))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF Spl Mass (g)Spl % Ext Vol (mL)Dilution DV Analyte Lab Reported
o-Terphenyl (Surr) 2471832 1 1 103424.627 7.5 78.6 1 1 23.89983964 23.9
Source page 926 926 926 944 925 925 925 925 68%926
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF Spl Mass (g)Spl % Ext Vol (mL)Dilution DV Analyte Lab Reported
n-Octacosane 2019191 1 1 98118.4781 7.5 78.6 1 1 20.57911047 20.6
Source page 926 926 926 944 925 925 925 925 59%926
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Mass (g)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc Lab reported
DRO[C10-C28]55631559 1 1 91361.0022 7.5 0.786 1 1 103.29 100
Source page 926 926 926 944 925 925 925 925 925
calculation notation B C D E F G H I
Back Calculation of Data for Validation Surrogate
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation Surrogate
ST071-01P-02-SO-[27-28] (280-179151-1)
Back Calculation of Data for Validation Surrogate
Back Calculation of Data for Validation LCS
LCS 280-620310/2-A
calculation ((B*D*I)/(C*E))
ICAL Analyte/IS: Gasoline Range Organics (GRO)-C6-C10
Amount Response ISTD Amt ISTD Resp Rel. Resp.
Lab Reported
Source Page 720
3.3 3322995 1.0 1.0 3322995.00 1003926 1003683
8.3 4028624 1.0 1.0 4028624.00 486549 486725
16.6 5882033 1.0 1.0 5882033.00 354339 355324
82.8 21900572 1.0 1.0 21900572.00 264500 264596
166.0 41976907 1.0 1.0 41976907.00 252873 253576
331.0 81921031 1.0 1.0 81921031.00 247496 247436
828.0 189226291 1.0 1.0 189226291.00 228534 228617
1655.0 393947366 1.0 1.0 393947366.00 238035 219855
AVG 384531.3874 223955.6860
COEF 0.999736158 0.999
%RSD 68.89
QC type Analyte spike recovery spike amount %D
reported by
lab Source page
ICV 280-608643/14 GRO 402 426 -5.6 -5.5 812
CCV 280-619974/3 C4-C12 189 200 -5.5 -5.5 824
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported
Source
Page
Lab reported
LCS Amount Source Page
(GRO)-C6-C10 425.6 375.382 88.20 88 20 375 874
Sample ID: ST071-01P-02-SO-[27-28] (280-179151-1)
Analyte
amount
detected amount injected DV recovery %
Lab
reported Source Page
a,a,a-Trifluorotoluene 66.64132 60 111.0688654 111%694
Sample ID: ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Analyte amount amount injected DV recovery %Lab Source Page
Toluene-d8 74.03424 60 123.3904011 123%707
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-179151-1 08/07/2023
Surrogate Recoveries
Batch: 608643 CF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
ICV/CCV (form 7)
LCS Recoveries: LCS 280-619974/4
Surrogate Recoveries
Performed by E-Lab Consultants
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF slope intercept Dilution DV Analyte Lab Reported
(GRO)-C6-C10 86574192 1 1 223955.68 2505156.6 1 375.3824659 375
Source page 875 875 875 720 720 874 874
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
a,a,a-Trifluorotoluene 26303400 1 1 394701.07 1 66.64131921 66.6
Source page 695 695 695 797 694 107%695
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF Dilution DV Analyte Lab Reported
a,a,a-Trifluorotoluene 29221394 1 1 394701.07 1 74.03424065 74
Source page 705 705 705 797 704 123%707
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L) Prep Factor slope intercept Dry Factor
Dilution
Factor
DV Analyte
Conc Lab reported
(GRO)-C6-C10 130523344 1 1 54.80936483 298595.83 2847170.5 1.273088381 100 2983.592067 3000
Source page 695 695 695 720 720 704 704
calculation notation B C D E F G H I
calculation (((((C/D-H)*E/G)/1000)/1)*J*F*1*1*I)
Back Calculation of Data for Validation LCS
LCS 280-619974/4
Back Calculation of Data for Validation Surrogate
ST071-01P-02-SO-[27-28] (280-179151-1)
Back Calculation of Data for Validation Surrogate
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)
Back Calculation of Data for Validation
ST071-01P-03-SO-[24.5-25.5] (280-179151-3)

September 12, 2023
Eurofins Test America 280-179227-1 (08/07/2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
• Basewide UFP-QAPP (HGL-APTIM, 2020),
• Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
• Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
• Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
• NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific

criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
• Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
• Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.

Table 1-1
Sample Field and Laboratory ID Numbers

Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validatio
n Level
TB-071823 280-179227-1 WQ 07/18/23
07:00 TB SW8260D
SW8015D/GRO S2BVM
ST071-01P-06-SO-
[33-34] 280-179227-2 SO 07/18/23
09:10 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
DUP-ST071-06-
071823 280-179227-3 SO 07/18/23
09:10
FD of
ST071-
01P-06
SW8260D
SW8015D/GRO
SW8015D/DRO
None
ST071-01P-07-SO-
[28.5-29.5] 280-179227-4 SO 07/18/23
10:05 N
SW8260D
SW8015D/GRO
SW8015D/DRO
None
EB-071823 280-179227-5 WQ 07/18/23
13:40 EB
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.

Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.

Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS

Reason
Code Name
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING

Reason
Code Name
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT

Reason
Code Name
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
mple

2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times. The
validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP. None of the data is qualified based on sample
documentation, preservation, handling, or transport.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip and equipment blanks reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.

Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples ST071-01P-06-SO-[33-34] (280-179227-2)[200X], DUP-ST071-
06-071823 (280-179227-3)[200X] and ST071-01P-07-SO-[28.5-29.5] (280-
179227-4)[200X] required dilution prior to analysis due to the nature of the
sample matrix. The reporting limits have been adjusted accordingly.
2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s).
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
01P-06-SO-[33-34] (280-179227-2). a,a,a-Trifluorotoluene failed the
surrogate recovery criteria high for DUP-ST071-06-071823 (280-179227-
3). Evidence of matrix interference is present; therefore, re-extraction
and/or re-analysis was not performed.
o The associated detected sample results are qualified J-SGH
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.

Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Sample ST071-01P-07-SO-[28.5-29.5] (280-179227-4)[20X] required
dilution prior to analysis. The reporting limits have been adjusted
accordingly.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.

Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The EB reports detection of DRO 0.038 mg/L. The associated normal sample report
DRO detections>5X the blank concentration. None of the data is qualified.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Due to the matrix having a very strong odor, the initial volumes used for the
following samples in preparation batch 280-620310 deviated from the
standard procedure: ST071-01P-06-SO-[33-34] (280-179227-2), DUP-
ST071-06-071823 (280-179227-3) and ST071-01P-07-SO-[28.5-29.5]
(280-179227-4). To prevent venting and to protect the microwave
equipment, the samples were analyzed at seven and a half grams instead
of the full fifteen grams. The reporting limits (RLs) have been adjusted
proportionately.

3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.

Overall FD RPD= 28%
Field Sample ID Lab Sample
ID
Lab
Method Parameter Name Lab
Result
RP
D
ST071-01P-06-SO-
[33-34]
280-
179227-2 SW8260D Ethylbenzene 750
DUP-ST071-06-
071823
280-
179227-3 SW8260D Ethylbenzene 790 5.2
ST071-01P-06-SO-
[33-34]
280-
179227-2 D2216 Moisture, Percent 17.9
DUP-ST071-06-
071823
280-
179227-3 D2216 Moisture, Percent 16.9 5.7
ST071-01P-06-SO-
[33-34]
280-
179227-2 M8015D Petroleum Hydrocarbons
C10-C28 500
DUP-ST071-06-
071823
280-
179227-3 M8015D Petroleum Hydrocarbons
C10-C28 86 14
1
ST071-01P-06-SO-
[33-34]
280-
179227-2 M8015V Petroleum Hydrocarbons C6-
C10 120
DUP-ST071-06-
071823
280-
179227-3 M8015V Petroleum Hydrocarbons C6-
C10 170 34
ST071-01P-06-SO-
[33-34]
280-
179227-2 D2216 Solids, Percent 82.1
DUP-ST071-06-
071823
280-
179227-3 D2216 Solids, Percent 83.1 1.2
ST071-01P-06-SO-
[33-34]
280-
179227-2 SW8260D Xylene, m,p- (Sum of
Isomers) 5800
DUP-ST071-06-
071823
280-
179227-3 SW8260D Xylene, m,p- (Sum of
Isomers) 6400 9.8
ST071-01P-06-SO-
[33-34]
280-
179227-2 SW8260D Xylene, o- 230
DUP-ST071-06-
071823
280-
179227-3 SW8260D Xylene, o- 200 14
ST071-01P-06-SO-
[33-34]
280-
179227-2 SW8260D Xylenes, Total 6000
DUP-ST071-06-
071823
280-
179227-3 SW8260D Xylenes, Total 6600 9.5

4.0 CONCLUSION
The following samples were qualified based on this validation.

Field
Sample ID
Lab
Sampl
e ID
Lab
Meth
od
Parameter
Name
Lab
Resu
lt
Lab
Unit
s
Lab
Qualif
ier
Validatio
n
Qualifier
Validation
Reason
Codes
ST071-01P-
06-SO-[33-
34]
280-
17922
7-2
M801
5V
Petroleum
Hydrocarbons
C6-C10
120 MG
/KG Q J SGH
DUP-ST071-
06-071823
280-
17922
7-3
M801
5V
Petroleum
Hydrocarbons
C6-C10
170 MG
/KG Q J SGH
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:

Field Duplicates: The validator compared the parent/field duplicate pair of ST071-01P-06-SO-[33-
34]/DUP-ST071-06-071823 but failed to qualify RPD exceedances. The RPDs for DRO and GRO
exceeded QC limits. These results in samples ST071-01P-06-SO-[33-34] and DUP-ST071-06-071823
should be qualified J.

Qualification Changes: The GRO and DRO results in samples ST071-01P-06-SO-[33-34]
and DUP-ST071-06-071823 are qualified J, reason code FDD.

100QC spreadsheet
NA

VOCs – 8260B
Qualification Changes: None

Gasoline Range Organics – 8015D GRO

Equipment Blank: The validator noted a trip blank, but failed to mention that an equipment blank was
also submitted with this SDG and was free from contamination.

Qualification Changes: None

Diesel Range Organics – 8015D DRO

Qualification Changes: None

Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179227-1
HGL Reviewer John Tracy
Review Date 9/20/23

September 12, 2023
Eurofins Test America 280-179293-1 (08/07/2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
• Basewide UFP-QAPP (HGL-APTIM, 2020),
• Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
• Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
• Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
• NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific

criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
• Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
• Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.

Table 1-1
Sample Field and Laboratory ID Numbers

Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validatio
n Level
ST071-OIP-08-SO-
[37.5-38.5] 280-179293-1 SO 07/19/23
10:37 N SW8260D
SW8015D/GRO S2BVM
EB-071923 280-179293-2 WQ 07/19/23
15:10 EB
SW8260D
SW8015D/GRO
SW8015D/DRO
None
TB-071923 280-179293-3 WQ 07/19/23
07:00 TB
SW8260D
SW8015D/GRO
SW8015D/DRO
None
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.

Table 1-3
Data Qualification Reason Codes
Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.

Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS

Reason
Code Name
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT

Reason
Code Name
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD

Reason
Code Name
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
mple

2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times. The
validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP. None of the data is qualified based on sample
documentation, preservation, handling, or transport.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip and equipment blanks reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.

Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• The following sample was diluted due to the nature of the sample matrix:
ST071-OIP-08-SO-[37.5-38.5] (280-179293-1). Elevated reporting limits
(RLs) are provided.

2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.

Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The associated blanks report all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.

Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
No FD samples were submitted.
4.0 CONCLUSION
The following samples were qualified based on this validation.
No added DVQs

HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B
Qualification Changes: None

Gasoline Range Organics – 8015D GRO

Equipment Blank: The validator noted a trip blank, but failed to mention that an equipment blank was
also submitted with this SDG and was free from contamination.

Qualification Changes: None

Diesel Range Organics – 8015D DRO

Qualification Changes: None

Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179293-1
HGL Reviewer John Tracy
Review Date 9/21/23

September 12, 2023
Eurofins Test America 280-179551-1 (08/08 /2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
• Basewide UFP-QAPP (HGL-APTIM, 2020),
• Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
• Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
• Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
• NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific

criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
• Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
• Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.

Table 1-1
Sample Field and Laboratory ID Numbers

Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validation
Level
TB-072523 280-179551-1 WQ 07/25/23
07:00 TB SW8260D
SW8015D/GRO None
EB-072523 280-179551-2 WQ 07/25/23
15:04 EB
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-[OIP-06] 280-179551-3 WQ 07/25/23
13:09 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-[OIP-07] 280-179551-4 WQ 07/25/23
14:50 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.

Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.

Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS

Reason
Code Name
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING

Reason
Code Name
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT

Reason
Code Name
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times with the
following exception(s).
•The following samples were collected in a properly preserved vial; however,
the pH was outside the required criteria when verified by the laboratory with
a pH of (7): ST071-GW-[OIP-06] (280-179551-3) and ST071-GW-[OIP-07]
(280-179551-4). The samples were analyzed outside the 7-day holding time
specified for unpreserved samples but within the 14-day holding time
specified for preserved samples. (The field sampler noted on the COC that the following
samples had the HCl preservative removed: ST071-GW-[01P-06] (280-179551-3) and ST-071-GW-
[01P-07] (280-179551-4). Therefore, the samples were logged for the unpreserved prep for GRO
and VOCs (BTEXN).
o The associated sample results (VOC and TPH-GRO) are qualified J/UJ-
HHL, IMPR
The validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits or were diluted out due to native
compound concentration.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.

Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples T-870-OIP-06N-SO-17.5-18.5 (280-179365-1)[500X] and T-870-
OIP-07N-SO-18-19 (280-179365-3)[500X] required dilution prior to
analysis. The reporting limits have been adjusted accordingly.

2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.

Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s)
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
GW-[OIP-06] (280-179551-3). a,a,a-Trifluorotoluene failed the surrogate
recovery criteria high for ST071-GW-[OIP-07] (280-179551-4). Evidence of
matrix interference is present; therefore, re-extraction and/or re-analysis
was not performed. The sample was diluted and rendered the surrogate
recovery useless.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.

• Sample ST071-GW-[OIP-07] (280-179551-4)[5X] required dilution prior to
analysis. The reporting limits have been adjusted accordingly.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
DRO was detected in the MB. The associated sample ST071-GW-[OIP-06] is qualified
U-MBH.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.

Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Due to the matrix being non homogenous in combination with a strong
chemical smell, the initial volume(s) of seven and half grams was used
instead of fifteen for the following sample which deviated from the standard
procedure in order to prevent equipment damage: T-870-OIP-07N-SO-18-
19 (280-179365-3). The reporting limits (RLs) have been adjusted
proportionately.
• Due to the matrix fully venting in the microwave, the initial volumes used for
the following sample in preparation batch 280-620620 deviated from the
standard procedure: T-870-OIP-06N-SO-17.5-18.5 (280-179365-1). To
avoid further venting, the sample was ran at five grams instead of the full
fifteen grams. The reporting limits (RLs) have been adjusted
proportionately.

3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
No FD samples were submitted.
4.0 CONCLUSION
The following samples were qualified based on this validation.
Field
Sample ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resul
t
Lab
Qualifi
er
Validation
Qualifier
Validation
Reason
Codes
ST071-
GW-[OIP-
06]
280-
179551
-3
SW82
60D Xylenes, Total 22 D J HHL, IMPR
ST071-
GW-[OIP-
06]
280-
179551
-3
M801
5V
Petroleum
Hydrocarbons C6-
C10
0.22 Q J HHL, IMPR
ST071-
GW-[OIP-
06]
280-
179551
-3
M801
5D
Petroleum
Hydrocarbons
C10-C28
0.031 J U MBH

Field
Sample ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resul
t
Lab
Qualifi
er
Validation
Qualifier
Validation
Reason
Codes
ST071-
GW-[OIP-
06]
280-
179551
-3
SW82
60D Toluene 9.2 J D J HHL, IMPR
ST071-
GW-[OIP-
06]
280-
179551
-3
SW82
60D Naphthalene 8 U U HHL, IMPR
ST071-
GW-[OIP-
06]
280-
179551
-3
SW82
60D Ethylbenzene 4.1 J D J HHL, IMPR
ST071-
GW-[OIP-
06]
280-
179551
-3
SW82
60D Benzene 8 U U HHL, IMPR
ST071-
GW-[OIP-
07]
280-
179551
-4
SW82
60D Benzene 8 U U HHL, IMPR
ST071-
GW-[OIP-
07]
280-
179551
-4
SW82
60D Ethylbenzene 100 D J HHL, IMPR
ST071-
GW-[OIP-
07]
280-
179551
-4
SW82
60D Naphthalene 17 J D J HHL, IMPR
ST071-
GW-[OIP-
07]
280-
179551
-4
SW82
60D Toluene 10 D J HHL, IMPR
ST071-
GW-[OIP-
07]
280-
179551
-4
M801
5V
Petroleum
Hydrocarbons C6-
C10
2.6 D Q J HHL, IMPR
ST071-
GW-[OIP-
07]
280-
179551
-4
SW82
60D Xylenes, Total 300 D J HHL, IMPR
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B

Sample Preservation, Handling, and Transport: The validator noted in Section 2.1 that all results in
samples ST071-GW-[OIP-06] and ST071-GW-[OIP-07] should be qualified J/UJ, but three results were
qualified U.

Qualification Changes: The naphthalene result in sample ST071-GW-[OIP-06] and the
benzene results in samples ST071-GW-[OIP-06] and ST071-GW-[OIP-07] are qualified UJ.

Equipment Blank: The validator noted a trip blank, but failed to mention that an equipment blank was
also submitted with this SDG and was free from contamination.

Qualification Changes: None

Gasoline Range Organics – 8015D GRO

Surrogates: The validator mentioned surrogate failures that were noted in the case narrative form the
laboratory but failed to qualify any results. There were high surrogate recoveries in both samples in this
SDG. The results are already qualified J but should have a reason code added for the surrogate failures.

Qualification Changes: The GRO results in samples ST071-GW-[OIP-06] and ST071-GW-
[OIP-07] are qualified J, reason code, HHL,IMPR,SGH.

Field Blanks: The validator stated in Section 2.3.5 that field QC was not submitted. Trip blank TB-072523
and equipment blank EB-072523 were submitted with this SDG and were free from contamination.

Qualification Changes: None

Diesel Range Organics – 8015D DRO

Method Blank: The validator set the lab result for DRO in sample ST071-GW-[OIP-06] to report at the LOQ
as a non-detect due to a detection in the method blank. The detection was less than ½ the LOQ, and
according to the QAPP, requires no qualification.

Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179551-1
HGL Reviewer John Tracy
Review Date 9/21/23
Qualification Changes: The lab result for sample ST071-GW-[OIP-06] is returned to the value
reported by the laboratory with the qualifier J, reason code TR.

Field Blanks: The validator stated in Section 2.1.5 that field QC was not submitted. Equipment blank EB-
072523 was submitted with this SDG. There was a DRO detection at a level less than ½ the LOQ and no
qualification is required.

Qualification Changes: None

September 12, 2023
Eurofins Test America 280-179568-1 (08/08/2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
•Basewide UFP-QAPP (HGL-APTIM, 2020),
•Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
•Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
•Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
•NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific
criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
•Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
•Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.
Table 1-1
Sample Field and Laboratory ID Numbers
Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validation
Level
TB-072523 280-179568-1 WQ 07/25/23
07:00 TB SW8260D
SW8015D/GRO None
ST071-GW-(OIP-08) 280-179568-2 GW 07/25/23
08:00 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-(1A) 280-179568-3 GW 07/25/23
10:51 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-(2A) 280-179568-4 GW 07/25/23
12:35 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
DUP-ST071-GW-
(2A)-072523 280-179568-5 GW 07/25/23
12:35
FD of
ST071-
GW-(2A)
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.
Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.
Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
Reason
Code Name
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
Reason
Code Name
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
Reason
Code Name
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times with the
following exception(s).
•The field sampler noted on the COC that the following samples had the HCl
preservative removed: ST071-GW-(OIP-08) (280-179568-2), ST071-GW-
(1A) (280-179568-3), ST071-GW-(2A) (280-179568-4) and DUP-ST071-
GW-(2A)-072523 (280-179568-5). Therefore, the samples were logged for
the unpreserved prep for GRO and VOCs (BTEXN).
o The associated sample results (VOC and TPH-GRO) are qualified J/UJ-
IMPR
The validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits or were diluted out due to native
compound concentration.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.

Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples ST071-GW-(1A) (280-179568-3)[100X], ST071-GW-(2A) (280-
179568-4)[20X] and DUP-ST071-GW-(2A)-072523 (280-179568-5)[20X]
required dilution prior to analysis. The reporting limits have been adjusted
accordingly.
• The following sample was diluted to bring the concentration of target
analytes within the calibration range: ST071-GW-(1A) (280-179568-3).
Elevated reporting limits (RLs) are provided.
2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.

Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s)
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
GW-(1A) (280-179568-3). a,a,a-Trifluorotoluene failed the surrogate
recovery criteria high for ST071-GW-(2A) (280-179568-4). a,a,a-
Trifluorotoluene failed the surrogate recovery criteria high for DUP-ST071-
GW-(2A)-072523 (280-179568-5). Evidence of matrix interference is
present; therefore, re-extraction and/or re-analysis was not performed.
o The sample was diluted and rendered the surrogate recovery useless.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.

Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples ST071-GW-(1A) (280-179568-3)[100X], ST071-GW-(2A) (280-
179568-4)[20X] and DUP-ST071-GW-(2A)-072523 (280-179568-5)[20X]
required dilution prior to analysis. The reporting limits have been adjusted
accordingly.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
DRO was detected in the MB (0.0523 mg/L). The associated sample ST071-GW-[OIP-
06] is qualified U-MBH.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.

Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• In preparation batch 280-621295, a portion of the following samples were
used for analysis, rather than testing the entire sample amount in the
original container, due to a significant amount of sediment at the bottom of
the container: ST071-GW-(OIP-08) (280-179568-2), ST071-GW-(1A) (280-
179568-3), ST071-GW-(2A) (280-179568-4) and DUP-ST071-GW-(2A)-
072523 (280-179568-5). The samples were poured carefully so that only
the water was used for preparation. As such, the required solvent rinse of
the original container could not be performed.
3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
Field Sample ID Lab Sample
ID
Lab
Method Parameter Name Lab
Result
RP
D
ST071-GW-(2A) 280-
179568-4 SW8260D Benzene 19
DUP-ST071-GW-(2A)-
072523
280-
179568-5 SW8260D Benzene 20 5.1
ST071-GW-(2A) 280-
179568-4 SW8260D Ethylbenzene 160
DUP-ST071-GW-(2A)-
072523
280-
179568-5 SW8260D Ethylbenzene 180 12
ST071-GW-(2A) 280-
179568-4 SW8260D Naphthalene 20
DUP-ST071-GW-(2A)-
072523
280-
179568-5 SW8260D Naphthalene 23 14
ST071-GW-(2A) 280-
179568-4 M8015D Petroleum Hydrocarbons
C10-C28 0.45
DUP-ST071-GW-(2A)-
072523
280-
179568-5 M8015D Petroleum Hydrocarbons
C10-C28 0.84 60

4.0 CONCLUSION
The following samples were qualified based on this validation.
Field Sample ID Lab Sample
ID
Lab
Method Parameter Name Lab
Result
RP
D
ST071-GW-(2A) 280-
179568-4 M8015V Petroleum Hydrocarbons
C6-C10 7.8
DUP-ST071-GW-(2A)-
072523
280-
179568-5 M8015V Petroleum Hydrocarbons
C6-C10 8 2.5
ST071-GW-(2A) 280-
179568-4 SW8260D Toluene ND
DUP-ST071-GW-(2A)-
072523
280-
179568-5 SW8260D Toluene 10 NC
ST071-GW-(2A) 280-
179568-4 SW8260D Xylenes, Total 1700
DUP-ST071-GW-(2A)-
072523
280-
179568-5 SW8260D Xylenes, Total 1800 5.7 avg 17
Field Sample
ID
Lab
Sampl
e ID
Lab
Meth
od
Parameter Name
Lab
Resu
lt
Lab
Qualifi
er
Validatio
n
Qualifier
Validation
Reason
Codes
ST071-GW-
(OIP-08)
280-
17956
8-2
SW82
60D Xylenes, Total 0.8 U UJ IMPR
ST071-GW-
(OIP-08)
280-
17956
8-2
M801
5D
Petroleum
Hydrocarbons
C10-C28
0.25 J U MBH
ST071-GW-
(OIP-08)
280-
17956
8-2
M801
5V
Petroleum
Hydrocarbons
C6-C10
0.01
2 J J IMPR
ST071-GW-
(OIP-08)
280-
17956
8-2
SW82
60D Toluene 0.4 U UJ IMPR
ST071-GW-
(OIP-08)
280-
17956
8-2
SW82
60D Naphthalene 0.8 U M UJ IMPR
ST071-GW-
(OIP-08)
280-
17956
8-2
SW82
60D Ethylbenzene 0.4 U UJ IMPR
ST071-GW-
(OIP-08)
280-
17956
8-2
SW82
60D Benzene 0.8 U UJ IMPR

Field Sample
ID
Lab
Sampl
e ID
Lab
Meth
od
Parameter Name
Lab
Resu
lt
Lab
Qualifi
er
Validatio
n
Qualifier
Validation
Reason
Codes
ST071-GW-
(1A)
280-
17956
8-3
SW82
60D Xylenes, Total 5800 D J IMPR
ST071-GW-
(1A)
280-
17956
8-3
SW82
60D Naphthalene 140 J D J IMPR
ST071-GW-
(1A)
280-
17956
8-3
M801
5V
Petroleum
Hydrocarbons
C6-C10
49 D Q J IMPR
ST071-GW-
(1A)
280-
17956
8-3
SW82
60D Toluene 40 U UJ IMPR
ST071-GW-
(1A)
280-
17956
8-3
SW82
60D Ethylbenzene 830 D J IMPR
ST071-GW-
(1A)
280-
17956
8-3
SW82
60D Benzene 47 J D J IMPR
ST071-GW-
(2A)
280-
17956
8-4
SW82
60D Benzene 19 J D J IMPR
ST071-GW-
(2A)
280-
17956
8-4
SW82
60D Ethylbenzene 160 D J IMPR
ST071-GW-
(2A)
280-
17956
8-4
SW82
60D Toluene 8 U UJ IMPR
ST071-GW-
(2A)
280-
17956
8-4
M801
5V
Petroleum
Hydrocarbons
C6-C10
7.8 D Q J IMPR
ST071-GW-
(2A)
280-
17956
8-4
SW82
60D Naphthalene 20 J D J IMPR
ST071-GW-
(2A)
280-
17956
8-4
SW82
60D Xylenes, Total 1700 D J IMPR
DUP-ST071-
GW-(2A)-
072523
280-
17956
8-5
SW82
60D Benzene 20 D J IMPR
DUP-ST071-
GW-(2A)-
072523
280-
17956
8-5
SW82
60D Toluene 10 J D J IMPR

Field Sample
ID
Lab
Sampl
e ID
Lab
Meth
od
Parameter Name
Lab
Resu
lt
Lab
Qualifi
er
Validatio
n
Qualifier
Validation
Reason
Codes
DUP-ST071-
GW-(2A)-
072523
280-
17956
8-5
SW82
60D Ethylbenzene 180 D J IMPR
DUP-ST071-
GW-(2A)-
072523
280-
17956
8-5
SW82
60D Naphthalene 23 J D J IMPR
DUP-ST071-
GW-(2A)-
072523
280-
17956
8-5
SW82
60D Xylenes, Total 1800 D J IMPR
DUP-ST071-
GW-(2A)-
072523
280-
17956
8-5
M801
5V
Petroleum
Hydrocarbons
C6-C10
8 D Q J IMPR
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Field Duplicates: For parent // duplicate pair ST071-GW-(2A) // ST071-GW-(2A)-072523, corresponding
results less than 5x the associated LOQ should have been compared using the absolute difference criteria.
All low-level results were less than the LOQ and met control criteria listed in the QAPP. See table below.

Analyte
Concentration (ug/L) Absolute
Difference
Maximum
Absolute
Difference
(LOQ) ST071-GW-(2A)
ST071-GW-(2A)-
072523
Benzene 19 20 1.0 20
Naphthalene 20 23 3.0 40

Qualification Changes: None

Gasoline Range Organics – 8015D GRO

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179568-1
HGL Reviewer John Tracy
Review Date 9/21/23
Field Blanks: The validator stated in Section 2.3.5 that field QC was not submitted. Trip blank TB-072523
was submitted with this SDG and was free from contamination.

Qualification Changes: None

Diesel Range Organics – 8015D DRO

Method Blank: The validator set the lab result for DRO in sample S ST071-GW-(OIP-08) to report at the
LOQ as a non-detect due to a detection in the method blank. The detection was less than ½ the LOQ, and
according to the QAPP, requires no qualification.

Qualification Changes: The lab result for sample ST071-GW-(OIP-08) is returned to the value
reported by the laboratory with the qualifier J, reason code TR.

Field Duplicates: For parent // duplicate pair ST071-GW-(2A) // ST071-GW-(2A)-072523, corresponding
results less than 5x the associated LOQ should have been compared using the absolute difference criteria.
See table below.

Analyte
Concentration (mg/L) Absolute
Difference
Maximum
Absolute
Difference
(LOQ) ST071-GW-(2A)
ST071-GW-(2A)-
072523
Diesel Range Organics
[C10-C28] 0.45 0.84 0.39 0.28

Qualification Changes: The DRO results in samples ST071-GW-(2A) and ST071-GW-(2A)-
072523 are qualified J, reason code FDD.

September 12, 2023
Eurofins Test America 280-179621-1 (08/09/2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
• Basewide UFP-QAPP (HGL-APTIM, 2020),
• Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
• Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
• Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
• NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific

criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
• Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
• Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.
Table 1-1
Sample Field and Laboratory ID Numbers
Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validation
Level
ST071-GW-[2C] 280-179621-1 GW 07/25/23
07:00 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-[OIP-05] 280-179621-2 GW 07/25/23
08:00 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-[OIP-04] 280-179621-3 GW 07/25/23
10:51 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
TB-072623 280-179621-4 WQ 07/25/23
12:35 TB SW8260D
SW8015D/GRO None
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.
Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.
Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS

Reason
Code Name
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING
Reason
Code Name
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT

Reason
Code Name
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times with the
following exception(s).
•The client notified the PM on 7/27/23 that the following samples had the
HCl preservative removed: ST071-GW-[2C] (280-179621-1), ST071-GW-
[OIP-05] (280-179621-2) and ST071-GW-[OIP-04] (280-179621-3).
Therefore, the samples were logged for the unpreserved prep for GRO and
VOCs (BTEXN).
o The associated sample results (VOC and TPH-GRO) are qualified J/UJ-
IMPR
The validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks with the
following exception(s).
Naphthalene was detected in the MB (0.73 µg/L). All associated samples report
Naphthalene detected >5X the blank concentration. None of the data is qualified.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits or were diluted out due to native
compound concentration.

Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples ST071-GW-[2C] (280-179621-1)[5X], ST071-GW-[OIP-05] (280-
179621-2)[2X] and ST071-GW-[OIP-04] (280-179621-3)[4X] required
dilution prior to analysis. The reporting limits have been adjusted
accordingly.
• The following samples were diluted to bring the concentration of target
analytes within the calibration range: ST071-GW-[2C] (280-179621-1) and

ST071-GW-[OIP-04] (280-179621-3). Elevated reporting limits (RLs) are
provided.

2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s)
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
GW-[2C] (280-179621-1). a,a,a-Trifluorotoluene failed the surrogate
recovery criteria high for ST071-GW-[OIP-05] (280-179621-2). a,a,a-
Trifluorotoluene failed the surrogate recovery criteria high for ST071-GW-
[OIP-04] (280-179621-3). Evidence of matrix interference is present;
therefore, re-extraction and/or re-analysis was not performed.
o The samples were* diluted and rendered the surrogate recovery
useless.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.

Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Samples ST071-GW-[2C] (280-179621-1)[20X], ST071-GW-[OIP-05] (280-
179621-2)[10X] and ST071-GW-[OIP-04] (280-179621-3)[20X] required
dilution prior to analysis. The reporting limits have been adjusted
accordingly.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
DRO was detected in the MB (0.0523 mg/L). All associated samples report DRO
detection >5X the blank concentration. None of the data is qualified.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.

Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• In preparation batch 280-621295, a portion of the following samples were
used for analysis, rather than testing the entire sample amount in the
original container, due to a significant amount of sediment at the bottom of
the container: ST071-GW-[2C] (280-179621-1), ST071-GW-[OIP-05] (280-
179621-2) and ST071-GW-[OIP-04] (280-179621-3). The samples were
poured carefully so that only the water was used for preparation. As such,
the required solvent rinse of the original container could not be performed.

3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
FD samples were not submitted.
4.0 CONCLUSION
The following samples were qualified based on this validation.

Field Sample
ID
Lab
Sample
ID
Lab
Method Parameter Name Lab
Result
Lab
Qualifie
r
Validation
Qualifier
Validation
Reason Codes
ST071-GW-
[2C]
280-
179621-
1
SW826
0D Benzene 4 U UJ IMPR
ST071-GW-
[OIP-05]
280-
179621-
2
SW826
0D Benzene 1.6 U UJ IMPR
ST071-GW-
[OIP-04]
280-
179621-
3
SW826
0D Benzene 3.2 U UJ IMPR
ST071-GW-
[2C]
280-
179621-
1
SW826
0D Ethylbenzene 150 D J IMPR
ST071-GW-
[OIP-05]
280-
179621-
2
SW826
0D Ethylbenzene 33 D J IMPR
ST071-GW-
[OIP-04]
280-
179621-
3
SW826
0D Ethylbenzene 68 D J IMPR
ST071-GW-
[2C]
280-
179621-
1
SW826
0D Naphthalene 19 D J IMPR
ST071-GW-
[OIP-05]
280-
179621-
2
SW826
0D Naphthalene 3.6 J D J IMPR
ST071-GW-
[OIP-04]
280-
179621-
3
SW826
0D Naphthalene 14 D J IMPR
ST071-GW-
[2C]
280-
179621-
1
M8015
V
Petroleum
Hydrocarbons C6-C10 11 D Q J IMPR
ST071-GW-
[OIP-05]
280-
179621-
2
M8015
V
Petroleum
Hydrocarbons C6-C10 3.5 D Q J IMPR
ST071-GW-
[OIP-04]
280-
179621-
3
M8015
V
Petroleum
Hydrocarbons C6-C10 8 D Q J IMPR
ST071-GW-
[2C]
280-
179621-
1
SW826
0D Toluene 3.4 J D J IMPR
ST071-GW-
[OIP-05]
280-
179621-
2
SW826
0D Toluene 0.8 U UJ IMPR

Field Sample
ID
Lab
Sample
ID
Lab
Method Parameter Name Lab
Result
Lab
Qualifie
r
Validation
Qualifier
Validation
Reason Codes
ST071-GW-
[OIP-04]
280-
179621-
3
SW826
0D Toluene 1.6 U M UJ IMPR
ST071-GW-
[2C]
280-
179621-
1
SW826
0D Xylenes, Total 1000 D J IMPR
ST071-GW-
[OIP-05]
280-
179621-
2
SW826
0D Xylenes, Total 110 D J IMPR
ST071-GW-
[OIP-04]
280-
179621-
3
SW826
0D Xylenes, Total 400 D J IMPR
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Method Blank: In Section 2.2.1, the validator states that naphthalene was detected in an associated
method blank, but all three associated method blanks are non-detect for all target analytes.

Qualification Changes: None

Field Blank: In Section 2.2.5, the validator states that target analytes were not detected in the associated
trip blank. Naphthalene was detected in the trip blank at a level less than ½ the LOQ and no qualification
is required.

Qualification Changes: None

Gasoline Range Organics – 8015D GRO

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Field Blank: In Section 2.3.5, the validator states that field QC was not submitted. Trip blank TB-072623
was submitted with this SDG and was free from contamination.

Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179621-1
HGL Reviewer John Tracy
Review Date 9/21/23
Qualification Changes: None

Diesel Range Organics – 8015D DRO

Qualification Changes: None

September 14, 2023
Eurofins Test America 280-179622-1 (08/09/2023)
Hill AFB VI Monitoring Program

Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190

Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah

Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).

Larry Duty
Data Validation Project Manager

1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
• Basewide UFP-QAPP (HGL-APTIM, 2020),
• Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
• Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
• Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
• NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific

criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
• Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
• Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.

Table 1-1
Sample Field and Laboratory ID Numbers

Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validation
Level
ST071-GW-[OIP-09] 280-179622-1
GW 07/26/23
11:24 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
ST071-GW-[OIP-01] 280-179622-2
GW 07/26/23
11:35 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
TB-072623 280-179622-3 WQ 07/26/23
07:00 TB SW8260D
SW8015D/GRO None
ST071-GW-[OIP-02] 280-179622-4
GW 07/26/23
12:50 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.

Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.

Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS

Reason
Code Name
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING

Reason
Code Name
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT

Reason
Code Name
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times with the
following exception(s).
•The field sampler noted on the COC that the following samples had the HCl
preservative removed: ST071-GW-[OIP-09] (280-179622-1), ST071-GW-
[OIP-01] (280-179622-2) and ST071-GW-[OIP-02] (280-179622-4).
Therefore, the samples were logged for the unpreserved prep for GRO and
VOCs (BTEXN).
o The associated sample results (VOC and TPH-GRO) are qualified J/UJ-
IMPR
The validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits or were diluted out due to native
compound concentration.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.

Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Sample ST071-GW-[OIP-01] (280-179622-2)[20X] required dilution prior to
analysis to bring the concentration of target analytes within the calibration
range. The reporting limits have been adjusted accordingly.
2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s)
• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
GW-[OIP-09] (280-179622-1). a,a,a-Trifluorotoluene failed the surrogate

recovery criteria high for ST071-GW-[OIP-01] (280-179622-2). a,a,a-
Trifluorotoluene failed the surrogate recovery criteria high for ST071-GW-
[OIP-02] (280-179622-4). Evidence of matrix interference is present;
therefore, re-extraction and/or re-analysis was not performed.
o Samples ST071-GW-[OIP-09] and ST071-GW-[OIP-02] are qualified J-
SGH
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.

• Sample ST071-GW-[OIP-01] (280-179622-2)[20X] required dilution prior to
analysis. The reporting limits have been adjusted accordingly.
2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
DRO was detected in the MB (0.0523 mg/L).
Samples ST071-GW-[OIP-02] and ST071-GW-[OIP-09] detected results are
qualified U-LBM at the LOQ.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.

Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• In preparation batch 280-621295, a portion of the following samples were
used for analysis, rather than testing the entire sample amount in the
original container, due to a significant amount of sediment at the bottom of
the container: ST071-GW-[OIP-09] (280-179622-1), ST071-GW-[OIP-01]
(280-179622-2) and ST071-GW-[OIP-02] (280-179622-4). The samples
were poured carefully so that only the water was used for preparation. As
such, the required solvent rinse of the original container could not be
performed.

3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
FD samples were not submitted.
4.0 CONCLUSION
The following samples were qualified based on this validation.
Field
Sample ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resul
t
Lab
Qualifi
er
Validation
Qualifier
Validation
Reason
Codes
ST071-
GW-[OIP-
09]
280-
179622
-1
SW82
60D Benzene 0.8 U UJ IMPR
ST071-
GW-[OIP-
09]
280-
179622
-1
SW82
60D Ethylbenzene 0.4 U UJ IMPR
ST071-
GW-[OIP-
09]
280-
179622
-1
SW82
60D Naphthalene 0.8 U UJ IMPR

Field
Sample ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resul
t
Lab
Qualifi
er
Validation
Qualifier
Validation
Reason
Codes
ST071-
GW-[OIP-
09]
280-
179622
-1
SW82
60D Toluene 0.4 U UJ IMPR
ST071-
GW-[OIP-
09]
280-
179622
-1
M801
5D
Petroleum
Hydrocarbons
C10-C28
0.25 J U LBM
ST071-
GW-[OIP-
09]
280-
179622
-1
M801
5V
Petroleum
Hydrocarbons C6-
C10
0.067 Q J IMPR,SGH
ST071-
GW-[OIP-
09]
280-
179622
-1
SW82
60D Xylenes, Total 0.8 U UJ IMPR
ST071-
GW-[OIP-
01]
280-
179622
-2
SW82
60D Benzene 16 U UJ IMPR
ST071-
GW-[OIP-
01]
280-
179622
-2
SW82
60D Toluene 8 U UJ IMPR
ST071-
GW-[OIP-
01]
280-
179622
-2
SW82
60D Ethylbenzene 200 D J IMPR
ST071-
GW-[OIP-
01]
280-
179622
-2
SW82
60D Naphthalene 30 J D J IMPR
ST071-
GW-[OIP-
01]
280-
179622
-2
M801
5V
Petroleum
Hydrocarbons C6-
C10
7.8 D Q J IMPR
ST071-
GW-[OIP-
01]
280-
179622
-2
SW82
60D Xylenes, Total 810 D J IMPR
ST071-
GW-[OIP-
02]
280-
179622
-4
SW82
60D Xylenes, Total 0.8 U UJ IMPR
ST071-
GW-[OIP-
02]
280-
179622
-4
M801
5V
Petroleum
Hydrocarbons C6-
C10
0.51 Q J IMPR,SGH
ST071-
GW-[OIP-
02]
280-
179622
-4
M801
5D
Petroleum
Hydrocarbons
C10-C28
0.28 J U LBM
ST071-
GW-[OIP-
02]
280-
179622
-4
SW82
60D Toluene 0.4 U UJ IMPR

Field
Sample ID
Lab
Sample
ID
Lab
Meth
od
Parameter Name
Lab
Resul
t
Lab
Qualifi
er
Validation
Qualifier
Validation
Reason
Codes
ST071-
GW-[OIP-
02]
280-
179622
-4
SW82
60D Naphthalene 0.8 U UJ IMPR
ST071-
GW-[OIP-
02]
280-
179622
-4
SW82
60D Ethylbenzene 0.4 U UJ IMPR
ST071-
GW-[OIP-
02]
280-
179622
-4
SW82
60D Benzene 0.8 U UJ IMPR
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Gasoline Range Organics – 8015D GRO

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Trip Blank: In Section 2.3.5, the validator stated that field QC was not submitted. Trip blank TB-072623
was submitted with this SDG and was free from contamination.

Qualification Changes: None

Diesel Range Organics – 8015D DRO

Method Blank: The validator set the lab result for DRO in samples ST071-GW-[OIP-09] and ST071-GW-
[OIP-02] to report at the LOQ as a non-detect due to a detection in the method blank. The detection was
less than ½ the LOQ, and according to the QAPP, requires no qualification.

Qualification Changes: The lab results for samples ST071-GW-[OIP-09] and ST071-GW-
[OIP-02] are returned to the values reported by the laboratory with the qualifier J, reason
code TR.
Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179622-1
HGL Reviewer John Tracy
Review Date 9/22/23

September 14, 2023
Eurofins Test America 280-179623-1 (08/09/2023)
Hill AFB VI Monitoring Program
Jennifer Chandler
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190
Basewide Remedial Action-Operations Performance and Compliance Monitoring at
Hill Air Force Base, Utah
Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP-
QAPP (HGL-APTIM JV, 2020) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense Quality System Manual, Version 5.3 (DoD,
2019) and Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019).
Larry Duty
Data Validation Project Manager
1.0 INTRODUCTION
This DVR contains the results of the validation conducted for samples collected and
analyzed as part of the Optimized Remediation Contract. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party
data validation purposes. Table 1-1 identifies the field sampling and analytical
information applicable to this DVR, including field sample numbers and associated
laboratory sample identifications with field sample matrix, purpose, analytical methods
requested, and data validation levels.
These samples were analyzed in accordance with the approved United States
Department of Defense (DoD) Quality Systems Manual (QSM) for Environmental
Laboratories Version 5.3 (2019) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
•Basewide UFP-QAPP (HGL-APTIM, 2020),
•Department of Defense General Data Validation Guidelines November
2019 Revision 1 (DoD, 2019),
•Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use (EPA, 2009),
•Environmental Protection Agency (EPA) National Functional Guidelines
(NFG) for Organic (NFGO) Data Review (January 2017),
•NFG for Inorganic (NFGIO) Data Review (January 2017), and the method
specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in
the Uniform Federal Policy for Quality Assurance Project Plan (UFP-QAPP) and DoD
QSM for the data quality parameters of sensitivity, accuracy, precision, and
completeness. Attached to this DVR is the laboratory data sheets that have been
annotated with qualifiers assigned during the validation process in accordance with
the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific
criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
•Organic Analysis; internal standards, continuing calibration verification, internal
standards, degradation summary, retention times, second column or second
detector confirmations, retention time windows,
•Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing calibration
verification, initial and continuing calibration blanks, interference check sample,
internal standards, serial dilution results, post digestion spike recoveries, and
interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if
data have been qualified.
Table 1-1
Sample Field and Laboratory ID Numbers
Field ID Lab ID Matrix Sample
Date Purpose Analytical
Method
Validation
Level
TB-072623 280-179623-1 WQ 07/26/23
07:00 TB SW8260D
SW8015D/GRO None
EB-072623 280-179623-2 WQ 07/26/23
14:13 EB
SW8260D
SW8015D/GRO
SW8015D/DRO
None
ST071-GW-[OIP-03] 280-179623-3 GW 07/26/23
14:42 N
SW8260D
SW8015D/GRO
SW8015D/DRO
S2BVM
Following the specifications in the UFP QAPP related to the data validation process,
the data were annotated with data validation qualifiers and codes as presented in
conclusion of this report. Table 1-2 provides definitions of the data qualifiers
references, and Table 1-3 lists and defines the data review qualifier codes.
Table 1-2
Data Qualifier References
Qualifier Definition
No Qualifier Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is not
affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and meet
QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and meet
QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.
Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
NST-No sample time documented.
Table 1-3
Data Qualification Reason Codes
Reason
Code Name
ABG BLANK: AMBIENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
ABL BLANK: AMBIENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
CBH CALIBRATION: CONTINUING CALIBRATION BLANK CONCENTRATION GREATER THAN
THE REPORTING LIMIT
CBL BLANK: CONTINUING CALIBRATION BLANK CONCENTRATION LESS THAN THE
REPORTING LIMIT
CCA MISCELLANEOUS: COMPOUNDS WERE REPORTED COMBINED ON ONE COLUMN
CCL CALIBRATION: CONTINUING CALIBRATION RECOVERY LESS THAN THE LOWER
CONTROL LIMIT
CF CONFIRMATION: CONFIRMATION RESULT
CFD CONFIRMATION: CONFIRMATION PRECISION EXCEEDED
CFHD CONFIRMATION: CONFIRMATION RESULT RPD GREATER THAN THE UPPER CONTROL
LIMIT
CLS CALIBRATION: NO CALIBRATION ANALYZED IN THE ANALYTICAL BATCH
CRL CALIBRATION: RESULT BELOW THE CALIBRATION RANGE
CRR CALIBRATION: LAB R FLAG REMOVED - CALIBRATION RANGE EXCEEDED
CVES CALIBRATION: CALIBRATION VERIFICATION ENDING STANDARD EXCEEDED %D
CRITERIA
CVHL CALIBRATION: CONTINUING CALIBRATION RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
D DUPLICATES: DUPLICATE RUN
DL DILUTION: DILUTION
DS DILUTION: SERIAL DILUTION %D EXCEEDED CONTROL LIMIT
DUNC DETECTION LEVEL NOT MET UNCERTAINTY GREATER THAN MDL OR MDC
EBG BLANK: EQUIPMENT BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
EBL BLANK: EQUIPMENT BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
EISH EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
GREATER THAN THE UPPER CONTROL LIMIT
EISL EXTRACTED INTERNALSTANDARD: EXTRACTED INTERNAL STANDARD RESPONSE
LESS THAN THE LOWER CONTROL LIMIT
EMPC MATRIX: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
EXC MISCELLANEOUS: DATA NOT USED; ANOTHER VALUE IS APPROPRIATE OR DATA WAS
NOT REQUESTED
FBG BLANK: FIELD BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
FBL BLANK: FIELD BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
FDD DUPLICATES: FIELD DUPLICATE RPD CRITERIA EXCEEDED
FTD FIELD TRIPLICATE RSD CRITERIA EXCEEDED
HAHL HOLDINGTIME: EXTRACTION TO ANALYSIS HOLDING TIME EXCEEDED
HHL HOLDINGTIME: SAMPLING TO ANALYSIS HOLDING TIME EXCEEDED
HPHL HOLDINGTIME: SAMPLING TO EXTRACTION HOLDING TIME EXCEEDED
IAG ION ABUNDANCE RATIO OUTSIDE CALCULATED LIMITS
Reason
Code Name
IC2 CALIBRATION: EXCEEDS RSD CRITERIA AND INITIAL CALIBRATION EXCEEDED THE R2
FOR FIRST ORDER REGRESSION
ICA ABSOLUTE VALUE OF CONCENTRATION FOR ALL NON-SPIKED PROJECT ANALYTES
>DL FOR SAMPLES CONTAINING INTERFERING ELEMENTS
ICD CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED
ICE CALIBRATION: RESULT GREATER THAN LINEAR CALIBRATION RANGE
ICL CALIBRATION: INITIAL CALIBRATION LOW STD. GREATER THAN THE REPORTING
LIMIT
ICP CALIBRATION: INITIAL CALIBRATION RSD EXCEEDED FOR CONFIRMATION COLUMN
ICR2 CALIBRATION: INITIAL CALIBRATION EXCEEDED THE R2 FOR FIRST ORDER
REGRESSION
ICS CALIBRATION: INDUCTIVELY COUPLED PLASMA (ICP) AND/OR ICP MASS
SPECTROSCOPY (ICPMS) INTERFERENCE CHECK SAMPLE (ICS) SOLUTIONS A AND B
(ICS A/B) RECOVERIES ARE OUTSIDE CONTROL LIMITS.
IDG ISOTOPE DILUTION ANALYTE RECOVERY OUTSIDE ACCEPTANCE CRITERIA
IMPR IMPROPER SAMPLE PRESERVATION/HANDLING/COLLECTION
IRF CALIBRATION: INITIAL CALIBRATION RELATIVE RESPONSE FACTOR BELOW THE
LOWER CONTROL LIMIT
IRH TRANSITION ION RATIO GREATER THAN THE UPPER CONTROL LIMIT
IRL TRANSITION ION RATIO LESS THAN THE LOWER CONTROL LIMIT
ISH INTERNALSTANDARD: INTERNAL STANDARD RESPONSE GREATER THAN THE UPPER
CONTROL LIMIT
ISL INTERNALSTANDARD: INTERNAL STANDARD RESPONSE LESS THAN THE LOWER
CONTROL LIMIT
IVD CALIBRATION: EXCEEDS ICVS %D CRITERIA
IVS CALIBRATION: INITIAL CALIBRATION VERIFICATION STANDARD WAS NOT ANALYZED
LBG BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE REPORTING
LIMIT
LBL BLANK: LABORATORY BLANK CONTAMINATION LESS THAN THE REPORTING LIMIT
LBM BLANK: LABORATORY BLANK CONTAMINATION GREATER THAN THE METHOD
DETECTION LIMIT
LCD LABORATORYCONTROLSAMPLE: LCS RPD CRITERIA EXCEEDED
LCH LABORATORYCONTROLSAMPLE: LCS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT
LCL LABORATORYCONTROLSAMPLE: LCS RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
LCS LABORATORYCONTROLSAMPLE: NO LCS IN THE ANALYTICAL BATCH
LDD DUPLICATES: LAB DUPLICATE RPD CRITERIA EXCEEDED
LDH LABORATORYCONTROLSAMPLE: LCSD RPD CRITERIA EXCEEDED
LDS LABORATORYCONTROLSAMPLE: LCSD NOT REQUIRED - NO FLAGS APPLIED
LRL RL: RESULT LESS THAN THE REPORTING LIMIT
LTD LAB TRIPLICATE RSD CRITERIA EXCEEDED
MBG BLANK: MATERIAL BLANK CONCENTRATION EXCEEDS THE REPORTING LIMIT
MBL BLANK: MATERIAL BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
MIF MATRIX: MATRIX INAPPROPRIATELY FLAGGED
MS MATRIX: GLOBAL MATRIX SPIKE FLAGGING
Reason
Code Name
MSD MATRIX: MATRIX SPIKE RPD CRITERIA EXCEEDED
MSH MATRIX: MATRIX SPIKE RECOVERY GREATER THAN THE UPPER CONTROL LIMIT
MSL MATRIX: MATRIX SPIKE RECOVERY LESS THAN THE LOWER CONTROL LIMIT
PDSH POST DIGESTION SPIKE RECOVERY: PDS RECOVERY GREATER THAN THE UPPER
CONTROL LIMIT.
PDSL POST DIGESTION SPIKE RECOVERY: PDS RECOVERY LESS THAN THE LOWER
CONTROL LIMIT.
PJ PROFESSIONAL JUDGEMENT
RE RE-ANALYSIS: RE-EXTRACTION AND/OR REANALYSIS
RFJ MISCELLANEOUS: LAB F FLAG REPLACED WITH J - FLAGGING NOT VALID
RFL LABORATORYCONTROLSAMPLE: LAB R FLAG REMOVED - RECOVERY WITHIN LAB
CONTROL LIMITS
RHT HOLDINGTIME: LAB R FLAG REMOVED - HOLDING TIME EXCEEDED BY LESS THAN 24
HOURS
RIS INTERNALSTANDARD: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON IS
RLM RL: REPORTING LIMIT LESS THAN THE METHOD DETECTION LIMIT
RML MATRIX: LAB M FLAG REMOVED - RECOVERY WITHIN LAB CONTROL LIMITS
RMQ MATRIX: LAB M FLAG REMOVED - MATRIX SPIKE/DUPLICATE NOT REQUESTED IN THIS
ANALYTICAL BATCH
RPE HOLDINGTIME: LAB R FLAG REMOVED - PE SAMPLE
RRA BLANK: LAB B FLAG REMOVED - ANALYTE NOT DETECTED IN SAMPLE
RSG SURROGATERECOVERY: LAB R FLAG REMOVED - REANALYSIS CONFIRMED MATRIX
EFFECT ON SURROGATE
RSGQ SURROGATERECOVERY: LAB R FLAG REMOVED - SURROGATE NOT MONITORED IN
QAPP
RTO 7 CONFIRMATION: RESULT IS OUTSIDE THE METHOD SPECIFIED RETENTION TIME
WINDOW
RXL LABCONTROLLIMITS: LAB R FLAG REMOVED - RECOVERY WITHIN LAB CONTROL
LIMITS
SCN SCREENING: SCREENING METHOD
SDH MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA GREATER THAN THE
UPPER CONTROL LIMIT
SDL MATRIX: MATRIX SPIKE DUPLICATE RECOVERY CRITERIA LESS THAN THE LOWER
CONTROL LIMIT
SGH SURROGATERECOVERY: SURROGATE RECOVERY GREATER THAN THE UPPER
CONTROL LIMITSGH
SGL SURROGATERECOVERY: SURROGATE RECOVERY LESS THAN THE LOWER CONTROL
LIMIT
SNL SIGNAL-TO-NOISE RATIO LESS THAN 10:1 FOR IONS USED FOR QUANTITATION
SPRF CALIBRATION: SPCC EXCEEDS RF > 0.300 CRITERIA
SVHL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY GREATER THAN
THE UPPER CONTROL LIMIT
SVLL CALIBRATION: SECOND SOURCE VERIFICATION STD. RECOVERY LESS THAN THE
LOWER CONTROL LIMIT
TB BLANK: TRIP BLANK
TBG BLANK: TRIP BLANK CONCENTRATION GREATER THAN THE REPORTING LIMIT
TBL BLANK: TRIP BLANK CONCENTRATION LESS THAN THE REPORTING LIMIT
Reason
Code Name
TH THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF HIGH
BOILING PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TH8 BLANK: TEMPERATURE BLANK > 8 DEGREES C
TIC TENTATIVELYIDENTIFIEDCOMPOUND: TENTATIVELY IDENTIFIED COMPOUND
TL THE CHROMATOGRAM OF THIS SAMPLE INDICATES THE PRESENCE OF LOW BOILING
PETROLEUM HYDROCARBONS NOT CONSISTENT WITH THE QUALITATIVE
STANDARDS EMPLOYED FOR THIS METHOD
TR RL: RESULT BETWEEN THE METHOD DETECTION LIMIT AND REPORTING LIMIT
TVP PARTIAL RESULTS GREATER THAN TOTAL RESULTS, DIFFERENCE IS GREATER THAN
ACCURACY UCL (UPPER CONTROL LIMIT)
XJV DATA VALIDATION QUALIFIER REVISED FROM X TO J AFTER CONSULTATION WITH
PROJECT TEAM.
XRV DATA VALIDATION QUALIFIER REVISED FROM X TO R AFTER CONSULTATION WITH
PROJECT TEAM.
XUJV DATA VALIDATION QUALIFIER REVISED FROM X TO UJ AFTER CONSULTATION WITH
PROJECT TEAM.
2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
2.1 Case Narrative Review, Sample Documentation, Preservation,
Handling, and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements. A cross reference of the COC and analytical reports has concluded all
extractions and analysis were performed within the required holding times with the
following exception(s).
•The client notified the PM on 7/27/23 that the following sample had the HCl
preservative removed: ST071-GW-[OIP-03] (280-179623-3) Therefore, the
sample was logged for the unpreserved prep for GRO and VOCs (BTEXN).
o The associated sample results (VOC and TPH-GRO) are qualified J/UJ-
IMPR
The validation met all QC requirements listed in the method and data validation
requirements of the UFP-QAPP.
2.2 VOCs by SW846-8260D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits or were diluted out due to native
compound concentration with the following exception(s)..
•Toluene-d8 (Surr) failed the surrogate recovery criteria high for ST071-GW-
[OIP-03] (280-179623-3). Evidence of matrix interference due to non-target
analytes is present; therefore, re-extraction and/or re-analysis was not
performed.
o Detected compounds are qualified J-SGH.

Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
The submitted trip blank reports all target analytes not detected.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
2.3 TPH-GRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
none of the target compounds were detected in any of the method blanks.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits with the following exception(s)

• a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for ST071-
GW-[OIP-03] (280-179623-3). Evidence of matrix interference is present;
therefore, re-extraction and/or re-analysis was not performed.
o Sample dilution rendered the surrogate recovery data unusable.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.
Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• Sample ST071-GW-[OIP-03] (280-179623-3)[10X] required dilution prior to
analysis. The reporting limits have been adjusted accordingly.

2.1 TPH-DRO SW846-8015D
Blanks
Each analytical batch was represented with a method blank. The laboratory reports
DRO was detected in the MB (0.0523 mg/L).
The associated sample reports DRO detection >5X the blank. None of the data is
qualified.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS compounds were recovered within acceptance criteria.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD samples were not submitted for this analysis.
Field Blanks
Field QC was not submitted for this analysis.
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors
were within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that
contained all target compounds.
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12-hour basis.
Internal Standards
Internal standards were reviewed for response and retention times.
Target Compound Identification
None of the identified target compounds were qualified based compound
identification.

Compound Quantitation and Reporting Limits
Sample dilutions, cleanup concentrations, and moisture correction have been applied
to all reportable results.
• In preparation batch 280-621295, a portion of the following sample was
used for analysis, rather than testing the entire sample amount in the
original container, due to a significant amount of sediment at the bottom of
the container: ST071-GW-[OIP-03] (280-179623-3). The samples were
poured carefully so that only the water was used for preparation. As such,
the required solvent rinse of the original container could not be performed.
3.0 FIELD DUPLICATE RESULT AGREEMENT
The following detections of field duplicates are compared below.
FD samples were not submitted.
4.0 CONCLUSION
The following samples were qualified based on this validation.

Field Sample
ID
Lab
Sample
ID
Lab
Method Parameter Name Lab
Result
Lab
Qualifie
r
Validation
Qualifier
Validation
Reason Codes
ST071-GW-
[OIP-03]
280-
179623-
3
SW826
0D Xylenes, Total 0.43 J Q J IMPR, SGH
ST071-GW-
[OIP-03]
280-
179623-
3
SW826
0D Toluene 0.32 J Q J IMPR, SGH
ST071-GW-
[OIP-03]
280-
179623-
3
SW826
0D Naphthalene 2.8 J IMPR, SGH
ST071-GW-
[OIP-03]
280-
179623-
3
M8015
V
Petroleum
Hydrocarbons C6-C10 2.7 D Q J IMPR
ST071-GW-
[OIP-03]
280-
179623-
3
SW826
0D Ethylbenzene 1.6 Q J IMPR, SGH
ST071-GW-
[OIP-03]
280-
179623-
3
SW826
0D Benzene 0.8 U M UJ IMPR
HGL Data Validation Review Report

This validation review report represents any additional findings or corrections to the validation performed
by ELAB.

General issues:
NA

100QC spreadsheet
NA

VOCs – 8260B

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Equipment Blank: The validator noted a trip blank, but failed to mention that an equipment blank was
also submitted with this SDG and was free from contamination.

Qualification Changes: None

Gasoline Range Organics – 8015D GRO

Sample Preservation, Handling, and Transport: In the case narrative provided by the laboratory, it is
stated that the HCl preservative was removed by the field sampler. The samples were treated as
unpreserved by the laboratory. In Section 2.1, the validator states that the associated results should be
qualified J/UJ, but they were analyzed by the laboratory within the 7-day holding time for unpreserved
samples and no qualification is required.

Qualification Changes: All qualifiers relating to sample preservation are removed.

Field Blanks: In Section 2.3.5, the validator states that field QC was not submitted for this analysis. Trip
blank TB-072623 and equipment blank EB-072623 were submitted with this SDG. Both blanks were free
from contamination and no qualification is required.

Qualification Changes: None

Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B – Volatile Organic Compounds, Gasoline Range Organics, Diesel Range
Organics
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-179623-1
HGL Reviewer John Tracy
Review Date 9/22/23
Diesel Range Organics – 8015D DRO

Field Blanks: In Section 2.1.5, the validator states that field QC was not submitted for this analysis.
Equipment blank EB-072623 was submitted with this SDG. It was free from contamination and no
qualification is required.

Qualification Changes: None

1
June 28, 2024
(March 20, 2024)
Eurofins Test America SDG: 280-184903-1 12/14/2023
Hill AFB VI Monitoring Program, UT - ST071
John Tracy
HGL-APTIM JV, LLC
11107 Sunset Hills Road, Suite 400
Reston, VA 20190
Basewide Remedial Action-Operations Performance and Compliance Monitoring at Hill
Air Force Base, Utah.
Enclosed is the data validation reports for contract W91238-20-C-0014 from Basewide
UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
The specific sample identifications are listed in the Sample Identification Table(s). The
data packages were reviewed according to the Hill Air Force Base Basewide UFP -
QAPP (HGL-APTIM JV, 2022) and the following guidance documents, as applicable:
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009), Department of Defense and Department of Energy Quality Systems
Manual for Environmental Laboratories Version 5.4 (2021), Department of Defense
General Data Validation Guidelines November 2019 Revision 1 (DoD, 2019), and Data
Validation Module 1 (2020), Module 2 (2020), Module 4 (2021), and Module 5 (2022), .
Alexandrea Armfield Schulz Larry Duty
Data Validation Project Manager Data Validation Project Manager
E-Lab Consultants E-Lab Consultants
2
Table of Contents
1.0 INTRODUCTION ........................................................................................................... 6
2.0 DATA VALIDATION RESULTS ................................................................................... 11
Laboratory Data Package Review ........................................................................................ 11
Case Narrative Review, Sample Documentation, Preservation, Handling, and Transport .... 11
2.1 VOCs by SW846-8260D .......................................................................................... 12
Sample Requirements ......................................................................................... 12
Instrument Initial Calibrations .............................................................................. 12
Initial Calibration Verifications .............................................................................. 12
Continuing Calibrations ....................................................................................... 12
Blanks ................................................................................................................. 12
Surrogate Recoveries .......................................................................................... 12
Laboratory Control Sample Recovery (Blank Spikes) .......................................... 12
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 12
Laboratory Duplicate ........................................................................................... 13
Field Duplicate Result Agreement .................................................................... 13
Internal Standards ........................................................................................... 13
Target Compound Identification ....................................................................... 13
Compound Quantitation and Reporting Limits .................................................. 13
2.2 Gasoline Range Organics 8015D_GRO .................................................................. 13
Sample Requirements ......................................................................................... 13
Initial Calibrations ................................................................................................ 13
Initial Calibration Verifications and Resolution Checks ......................................... 13
Continuing Calibrations ........................................................................................ 14
Blanks ................................................................................................................. 14
Surrogate Recoveries .......................................................................................... 14
Laboratory Control Sample Recovery (Blank Spikes) ........................................... 14
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 14
Field Duplicate Agreement .................................................................................. 14
Laboratory Duplicate/Triplicate Agreement ...................................................... 14
Calibration Blanks ............................................................................................ 15
Internal Standards ........................................................................................... 15
Target Compound Identification ....................................................................... 15
Compound Quantitat ion and Reporting Limits .................................................. 15
2.3 Diesel Range Organics 8015D_DRO ...................................................................... 15
Initial Calibrations ................................................................................................ 15
Initial Calibration Verifications and Resolution Checks ......................................... 15
3
Continuing Calibrations ........................................................................................ 15
Blanks ................................................................................................................. 16
Laboratory Control Sample Recovery (Blank Spikes) ........................................... 16
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 16
Field Duplicate Agreement .................................................................................. 16
Laboratory Duplicate/Triplicate Agreement .......................................................... 16
Calibration Blanks................................................................................................ 16
Internal Standards ........................................................................................... 16
Target Compound Identification ....................................................................... 17
Compound Quantitat ion and Reporting Limits .................................................. 17
2.1 ICP Metals SW846-6010D ...................................................................................... 17
Instrument Performance Checks ......................................................................... 17
Initial Calibrations ................................................................................................ 17
Initial Calibration Verifications and Resolution Checks ........................................ 17
ICP Serial Dilutions .............................................................................................. 17
Continuing Calibrations ....................................................................................... 17
Blanks ................................................................................................................. 17
Laboratory Control Sample Recovery (Blank Spikes) ........................................... 17
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 18
Field Blank .......................................................................................................... 18
Field Duplicate Agreement ............................................................................... 18
Laboratory Duplicate Agreement ..................................................................... 18
Soil Sample Triplicate ...................................................................................... 18
Calibration Blanks ............................................................................................ 18
Internal Standards ........................................................................................... 18
Target Compound Identification ....................................................................... 18
Compound Quantitation and Reporting Limits.................................................. 18
2.2 Metals by SW846-6020B ......................................................................................... 18
Method Blanks ..................................................................................................... 18
Laboratory Control Sample Recovery (Blank Spikes) .......................................... 18
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 19
Post Digestion Spikes .......................................................................................... 19
Field Blank .......................................................................................................... 19
Field Duplicate Agreement .................................................................................. 19
ICP Serial Dilutions .............................................................................................. 19
Initial and Continuing Calibration Verifications ..................................................... 19
Calibration Blanks................................................................................................ 19
4
Internal Standards ........................................................................................... 19
Target Compound Identification ....................................................................... 19
Compound Quantitation and Reporting Limits.................................................. 19
2.3 Alkalinity SM20-2320B ............................................................................................ 20
Initial Calibrations ................................................................................................ 20
Initial Calibration Verifications and Resolution Checks ......................................... 20
Continuing Calibrations ........................................................................................ 20
Blanks ................................................................................................................. 20
Laboratory Control Sample Recovery (Blank Spikes) .......................................... 20
Surrogate Recoveries .......................................................................................... 20
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 20
Field Blank .......................................................................................................... 20
Field Duplicate Agreement .................................................................................. 20
Calibration Blanks ............................................................................................ 20
Internal Standards ........................................................................................... 21
Target Compound Identification ....................................................................... 21
Compound Quantitation and Reporting Limits.................................................. 21
2.4 Specific Ions: Sulfates E300.00 ............................................................................... 21
Initial Calibrations ................................................................................................ 21
Initial Calibration Verifications and Resolution Checks ........................................ 21
Continuing Calibrations ....................................................................................... 21
Blanks ................................................................................................................. 21
Laboratory Control Sample Recovery (Blank Spikes) .......................................... 21
Surrogate Recoveries .......................................................................................... 21
Laboratory Duplicate Agreement ......................................................................... 21
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 21
Laboratory Duplicate ........................................................................................... 22
Field Blank ....................................................................................................... 22
Field Duplicate Agreement ............................................................................... 22
Calibration Blanks ............................................................................................ 22
Internal Standards ........................................................................................... 22
Target Compound Identification ....................................................................... 22
Compound Quantitation and Reporting Limits.................................................. 22
2.5 Specific Ion: Nitrates E353.2 ................................................................................... 22
Initial Calibrations ................................................................................................ 22
Initial Calibration Verifications and Resolution Checks ........................................ 23
Continuing Calibrations ....................................................................................... 23
5
Blanks ................................................................................................................. 23
Laboratory Control Sample Recovery (Blank Spikes) .......................................... 23
Surrogate Recoveries .......................................................................................... 23
Matrix Spike/Matrix Spike Duplicate Recoveries .................................................. 23
Field Blank .......................................................................................................... 23
Field Duplicate Agreement .................................................................................. 23
Laboratory Duplicate Agreement ..................................................................... 23
Calibration Blanks ............................................................................................ 23
Internal Standards ........................................................................................... 23
Target Compound Identification ....................................................................... 23
Compound Quantitation and Reporting Limits.................................................. 24
CONCLUSION ........................................................................................................................ 24
6
1.0 INTRODUCTION
This Stage 2B/Stage 4 Data Validation Report, DVR, conducted for Hill AFB VI
Monitoring Program, contains the results of the validation of SDG 280-184903-1,
conducted for samples collected and analyzed by Eurofins, Denver as part of the
Optimized Remediation Contract for Hill AFB, UT - ST071. This DVR was
subcontracted to E-Lab Consultants from HGL-APTIM JV LLC to serve third party data
validation purposes. Table 1-1 identifies the field sampling and analytical information
applicable to this DVR, including field sample numbers and associated laboratory
sample identifications with field sample matrix, purpose, analytical methods requested,
and data validation levels.
These samples were analyzed in accordance with the approved Department of
Defense and Department of Energy Quality Systems Manual for Environmental
Laboratories Version 5.4 (2021) and the analytical methods specified for the analytes
requested on the Chain of Custody (COC) documentation. This DVR is conducted per
the analyses requested on the COC in accordance with the following guidance
documents;
•Basewide UFP-QAPP (HGL-APTIM, 2022),
•Department of Defense and Department of Energy Quality Systems Manual for
Environmental Laboratories Version 5.4 (DoD, 2021),
•Data Validation Module 1 (2020), Module 2 (2020), Module 4 (2021), and Module 5 (2022),
•the method specified for the analysis.
The data were evaluated against the quantitative acceptance limits given in the UFP -
QAPP and DoD QSM for the data quality parameters of sensitivity, accuracy,
precision, and completeness. Attached to this DVR is the laboratory data sheets that
have been annotated with qualifiers assigned during the validation process in
accordance with the Basewide UFP-QAPP.
In accordance with Basewide UFP-QAPP, a review of the data was conducted
independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative, and an evaluation of the sample-specific
criteria included in the laboratory data packages analyzed in accordance with the DOD
QSM.
The validation consists of an evaluation of the case narrative, chain of custody and
associated laboratory sample receipt forms, proper sample preservations, holding
times, initial calibration and continuing calibration procedures and results, laboratory
control sample (LCS) (and duplicate [LCSD] if reported) accuracy and precision and
matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method blanks,
field blanks, and field duplicate precision.
7
•Organic Analysis; internal standards, continuing calibration verification,
internal standards, degradation summary, retention times, second column or
second detector confirmations, retention time windows,
•Inorganic Analysis; laboratory duplicate precision, instrument tuning, initial
calibration, low-level calibration check standards, initial and continuing
calibration verification, initial and continuing calibration blanks, interference
check sample, internal standards, serial dilution results, post digestion spike
recoveries, and interelement correction factors
The results of the independent data review are presented in Section 2.0.
A qualification summary table is provided at the end of this report in Section 3.0 if data
have been qualified.
8
Table 1-1
Sample Field and Laboratory ID Numbers
Field ID Lab ID Matrix Sample Date Purpose Analytical
Method
Validation
Level
280-184903-1 T-914-017-11202023 Water 11/20/2023 10:40 N A,B,C,D,E,F,G,H L2BVM
280-184903-2 TB-11202023 Water 11/20/2023 9:00 TB A,B, L2BVM
280-184903-3 T-914-018-11202023 Water 11/20/2023 12:00 N A,B,C,D,E,F,G,H L4VM
280-184903-4 DUP-01-11202023 Water 11/20/2023 12:00 N A,B,C, L4VM
280-184903-5 T-914-019-11202023 Water 11/20/2023 14:30 N A,B,C,D,E,F,G,H L2BVM
280-184903-6 T-870-82B-11202023 Water 11/20/2023 15:10 N A,B,C,D,E,F,G,H L2BVM
Stage 2A Validation-Manual/Electronic
Stage 2B Validation-Manual/Electronic
L2BVM Level 2b Validation Manual
L4VM Level 4 Validation Manual
Method Key:
8260D……………A
8015D GRO……..B
8015D DRO……..C
6010D……………D
6020B……………E
SM2320B………..F
EPA300…………G
EPA353.2……….H

9

Following the specifications in the UFP QAPP related to the data validation process, the data were
annotated with data validation qualifiers and codes as presented in conclusion of this report. Table
1-2 provides definitions of the data qualifiers references, and Table 1-3 lists and defines the data
review qualifier codes.
Table 1 -2: Data Qualifier References
Qualifier Definition
No Qualifier
Confirmed identification. The analyte was positively identified at the reported concentration.
The reported concentration is within the calibrated range of the instrument and the result is
not affected by any deficiencies in the associated QC criteria.
J The analyte was detected at the reported concentration; the quantitation is an estimate.
X The result is associated with serious deficiencies in the ability to analyze the sample and
meet QC criteria.
R The result is rejected due to serious deficiencies in the ability to analyze the sample and
meet QC criteria.
U Not detected. The associated number indicates the analyte LOD.
UJ Not detected. The associated number indicates the analyte LOD, which may be inaccurate.
# Excluded. The data point is associated with reanalysis or diluted analysis and is excluded,
because another result has been selected as the definitive result for the analyte.

Table 1 -3: Data Qualification Reason Codes
QC Element Reason Code Definition
Ambient Blank ABH Ambient blank result ≥LOQ
Ambient Blank ABHB Result is judged to be biased high based on associated ambient blank result
Ambient Blank ABL Ambient blank result <LOQ
Analyte Quantitation ACR Result above the upper end of the calibrated range
Analyte Quantitation EXC Result excluded; another data point for this analyte was selected for use
(use with X-qualified results)
Analyte Quantitation RTW Target analyte outside retention time window
Analyte Quantitation PSL Solid matrix sample with percent solids less than 50%
Analyte Quantitation PSLX Solid matrix sample with percent solids less than 10%
Analyte Quantitation TR Result between the DL and LOQ
Calibration Blank CBH Initial or continuing calibration blank result ≥LOQ
Calibration Blank CBHB Result is judged to be biased high based on associated continuing
calibration blank result
Calibration Blank CBL Initial or continuing calibration blank result <LOQ
Calibration Blank CBN Negative initial or continuing calibration blank result with absolute value
<LOQ
Calibration Blank CBNH Negative initial or continuing calibration blank result with absolute value
≥LOQ
Continuing
Calibration CCCC Calibration check compound did not meet %D criterion in continuing
calibration standard
Continuing
Calibration CCVD Continuing calibration standard did not meet %D criterion
Continuing
Calibration CRFL Continuing calibration RRF below acceptance criterion

10

QC Element Reason Code Definition
Continuing
Calibration CSPC System performance check compound did not meet minimum RRF criterion
in continuing calibration
Continuing
Calibration CVDX Continuing calibration standard did not meet %D criterion, extreme
discrepancy
Confirmation CF Confirmation precision exceeded acceptance criterion
Cyanide Method DSH High-level distillation standard did not meet %D criterion
Cyanide Method DSL Low-level distillation standard did not meet %D criterion
Equipment Blank EBH Equipment blank result ≥LOQ
Equipment Blank EBHB Result is judged to be biased high based on associated equipment blank
result
Equipment Blank EBL Equipment blank result <LOQ
Field Duplicate FDPA Field duplicate results did not meet absolute difference criterion
Field Duplicate FDPR Field duplicate results did not meet RPD criterion
Holding Time HTA Analytical holding time exceeded
Holding Time HTAX Analytical holding time exceeded, extreme discrepancy
Holding Time HTP Preparation holding time exceeded
Holding Time HTPX Preparation holding time exceeded, extreme discrepancy
Initial Calibration ICCC Calibration check compound did not meet %RSD criterion in initial
calibration
Initial Calibration ICLS Initial calibration low-level standard >LOQ
Initial Calibration ICR2 Initial calibration r2 below acceptance criterion
Initial Calibration ICRD Initial calibration %RSD above acceptance criterion
Laboratory Control
Sample LCLX LCS and/or LCSD %R below acceptance criterion, extreme discrepancy
Laboratory Control
Sample LCSH LCS and/or LCSD %R above acceptance criterion
Laboratory Control
Sample LCSL LCS and/or LCSD %R below acceptance criterion
Laboratory Control
Sample LCSP LCS/LCSD RPD above acceptance criterion
Laboratory Duplicate LDPA Laboratory duplicate results did not meet absolute difference criterion
Laboratory Duplicate LDPR Laboratory duplicate results did not meet RPD criterion
Low-Level
Calibration Check LLCH Low-level calibration check above the upper limit
Low-Level
Calibration Check LLCL Low-level calibration check below the lower limit
Low-Level
Calibration Check LLXL Low-level calibration check below the lower limit, extreme discrepancy
Method Blank MBH Method blank result ≥LOQ
Method Blank MBHB Result is judged to be biased high based on associated method blank result
Method Blank MBL Method blank result <LOQ
Matrix Spike MSH MS and/or MSD %R above acceptance criterion
Matrix Spike MSL MS and/or MSD %R below acceptance criterion
Matrix Spike MSLX MS and/or MSD %R below acceptance criterion, extreme discrepancy
Matrix Spike MSP MS/MSD RPD above acceptance criterion

11

QC Element Reason Code Definition
Post-Digestion
Spike PDH Post-digestion spike recovery high
Post-Digestion
Spike PDL Post-digestion spike recovery low
Post-Digestion
Spike PDLX Post-digestion spike recovery low, extreme discrepancy
Post-Digestion
Spike PDN Post-digestion spike not performed or not applicable and serial dilution result
not performed or not applicable
Sample Delivery and
Condition BUB Bubbles >5 mm in VOCs vial
Sample Delivery and
Condition DAM Sample container damaged
Sample Delivery and
Condition PRE Sample not properly preserved
Sample Delivery and
Condition TEMP Sample received at elevated temperature
Sample Delivery and
Condition TMPX Sample received at elevated temperature, extreme discrepancy
Serial Dilution SDIL Serial dilution did not meet %D criterion
Serial Dilution SDN Serial dilution not performed
Surrogate SSH Surrogate %R high
Surrogate SSL Surrogate %R low
Surrogate SSLX Surrogate %R low, extreme discrepancy
Surrogate SSN Surrogate compound not spiked into sample
Trip Blank TBH Trip blank result ≥LOQ
Trip Blank TBL Trip blank result <LOQ
Validator Judgment VJ Validator judgment (see validation narrative)

2.0 DATA VALIDATION RESULTS
Laboratory Data Package Review
The samples reported, QC designations, and validation level is listed in Table 1-1.
The data packages were reviewed in accordance with the Basewide UFP-QAPP.
Case Narrative Review, Sample Documentation, Preservation, Handling,
and Transport
All samples arrived at the laboratory on time, intact and within preservation
requirements.
A cross reference of the COC and analytical reports has concluded all extractions and
analysis were performed within the required holding times. The validation met all QC
requirements listed in the method and data validation requirements of the UFP-QAPP.
None of the data is qualified based on sample documentation, preservation, handling,
or transport.

12

2.1 VOCs by SW846-8260D
Sample Requirements
The following sample(s) was collected in a properly preserved vial; however, the pH (6)
was outside the required criteria (<2) when verified by the laboratory. The sample was
analyzed outside the 7-day holding time specified for unpreserved samples but within the
14-day holding time specified for preserved samples: T-870-82B-11202023 (280-184903-
6).
Instrument Initial Calibrations
Relative Retention Factors (RRF) was verified against the quantitation reports, mass
spectra, and chromatograms. All initial calibration average relative response factors were
within the project DoD QSM requirements.
Initial Calibration Verifications
The initial calibration curve was verified with a second source standard mix that contained
all target compounds. All target compounds were recovered within QC limits with the
following exception(s).
Continuing Calibrations
Continuing calibration average relative response factors were within the DoD QSM
requirements (<20%). Continuing calibrations were performed on a 12 -hour basis.
Blanks
Each analytical batch was represented with a method blank. The laboratory reports none of
the target compounds were detected in method blank s, except for Naphthalene was
detected in method blank MB 280-635386/9 at a level that was below half the LOQ.
• Sample 280-184903-2 is qualified UJ,MBL.
2.1.5.1 Trip Blank
The trip blanks report all target compounds not detected, however, TB-11202023 was
qualified due to the method blank presence of Naphthalene.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits, specific to each analyte, except for
Dibromofluoromethane (Surr) failed the surrogate recovery criteria high for T -914-017-
11202023MS (280-184903-1MS).
• Corresponding sample, 280-184903-1, qualified UJ,SSH.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS/LCSD compounds were recovered within acceptance criteria, specific for each
analyte, for each LCS/LCSD sample.
Matrix Spike/Matrix Spike Duplicate Recoveries
Sample 280-184903-1 was used for Matrix Spike and Matrix Spike duplicate analysis. All
analytes’ RDP and %R values were within requirements of set control limits specific for
each analyte.

13

Laboratory Duplicate
Laboratory duplicates and triplicates were not prepped or analyzed for this method.
Field Duplicate Result Agreement
The following field duplicates were submitted for analysis.
• T-914-018-11202023
• DUP-01-11202023
Below are calculations performed analyzing the field duplicate.
Field Duplicate Result T-914-018-11202023 DUP-01-11202023
RPD Compound Parent Duplicate
Ethylbenzene 0.82 0.22 115.14
Xylenes, Total 13.00 3.40 117.07
• Samples qualified UJ/J, FDPR.
Internal Standards
Internal standards were reviewed for response and retention times. All were appropriate.
Target Compound Identification
None of the identified target compounds were qualified based compound identification,
compound quantitation and reporting limits. Sample dilutions, cleanup concentrations, and
moisture correction have been applied to all reportable results.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the Level of Detection (LOD). The LODs
have been verified to meet or exceed the project required performance standards.
Sample dilutions, cleanup concentrations, and moisture correction have been applied to
all reportable results.
2.2 Gasoline Range Organics 8015D_GRO
Sample Requirements
The following sample was collected in a properly preserved vial; however, the pH of 7 was
outside the required criteria (<2) when verified by the laboratory. The sample was analyzed
within the 7-day holding time specified for unpreserved samples: T-870-82B-11202023
(280-184903-6).
Initial Calibrations
Percent Relative Standard Deviations (%RSD) were verified to be ≤20% or the
coefficient of determination for the calibration curve (r2), is ≥0.990, for each compound.
Initial Calibration Verifications and Resolution Checks

14

The initial calibration curve was verified with a second source standard mix.
Resolutions and retentions times were verified to be within acceptance criteria. All target
analytes had a percent difference of less than 20%.
Continuing Calibrations
Continuing calibration recoveries were within the QC recovery compound specific limits for
all analytes. Continuing calibrations were performed with acceptable results on a 12-hour
basis.
Blanks
Each analytical batch was represented with a method blank. MB 280-635060/5 was free of
contamination.
2.2.5.1 Trip Blank
The trip blanks report all target compounds not detected.
Surrogate Recoveries
All surrogate recoveries are within acceptance limits, specific for each analyte, except for
a,a,a-Trifluorotoluene failed the surrogate recovery criteria high for T-914-018-11202023
(280-184903-3) and DUP-01-11202023 (280-184903-4).
• Evidence of matrix interference is present; therefore, re-extraction and/or re-
analysis was not performed.
• Corresponding samples are qualified J,SSH.
Laboratory Control Sample Recovery (Blank Spikes)
LCS/LCSD recoveries are within the laboratory established control limits, specific to each
compound.
Matrix Spike/Matrix Spike Duplicate Recoveries
Sample 280-184903-1 was used for Matrix Spike and Matrix Spike duplicate analysis. All
analytes’ RDP and %R values were within requirements of set control limits specific for
each analyte.
Field Duplicate Agreement
The following field duplicates were submitted for analysis.
• T-914-018-11202023
• DUP-01-11202023
Below are calculations performed analyzing the field duplicate.
Field Duplicate Result T-914-018-11202023 DUP-01-11202023
RPD Compound Parent Duplicate
(GRO)-C6-C10 0.12 0.12 0.0
Laboratory Duplicate/Triplicate Agreement
Duplicate or Triplicate samples were not collected or analyzed.

15

Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.
Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the LOD. The LODs have been verified to
meet or exceed the project required performance standards. Sample dilutions, cleanup
concentrations, and moisture correction have been applied to all reportable results. The
results are reported on a dry weight basis where applicable.
2.3 Diesel Range Organics 8015D_DRO
Initial Calibrations
Percent Relative Standard Deviations (%RSD) were verified to be ≤20% or the
coefficient of determination for the calibration curve (r2), is ≥0.990, for each compound.
Initial Calibration Verifications and Resolution Checks
The initial calibration curve was verified with a second source standard mix.
Resolutions and retentions times were verified to be within acceptance criteria. All target
analytes had a percent difference of less than 20%.
Continuing Calibrations
Continuing calibration recoveries were within the QC recovery compound specific limits for
all analytes, except for n-Octacosane (Surr), noted below. Continuing calibrations were
performed with acceptable results on a 12-hour basis.
• The continuing calibration verification (CCV) CCV 280-636127/26 associated with
batch 280-636127 recovered above the upper control limit for n-Octacosane
(Surr).
Analyte Calc. Conc.
(pg/g)
Spike Conc.
(pg/g) %D Limit
n-Octacosane
(Surr) 37.1 25.0 48.5 20%

16

• Sample surrogates are in control and all data have been reported.
• Corresponding samples are qualified UJ,CCVD.
Blanks
Each analytical batch was represented with a method blank. MB 280-635153/1-A was free
of contamination.
Laboratory Control Sample Recovery (Blank Spikes)
LCS/LCSD recoveries are within the laboratory established control limits, specific to each
compound.
Matrix Spike/Matrix Spike Duplicate Recoveries
Sample 280-184903-1 was used for Matrix Spike and Matrix Spike duplicate analysis. All
analytes’ RDP and %R values were within requirements of set control limits specific for
each analyte.
Field Duplicate Agreement
The following field duplicates were submitted for analysis.
• T-914-018-11202023
• DUP-01-11202023
Below are calculations performed analyzing the field duplicate.
Field Duplicate Result T-914-018-11202023 DUP-01-11202023
RPD Compound Parent Duplicate
Diesel Range Organics C10-C28 0.13 0.12 8
Laboratory Duplicate/Triplicate Agreement
Duplicate or Triplicate samples were not collected or analyzed.
Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.

17

Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the LOD. The LODs have been verified to
meet or exceed the project required performance standards. Sample dilutions, cleanup
concentrations, and moisture correction have been applied to all reportable results. The
results are reported on a dry weight basis where applicable. Ten percent of the reported
data was validated for quantification and qualifications. None of the data was
miscalculated.
2.1 ICP Metals SW846-6010D

Instrument Performance Checks
Data verification included verifying the mass spectral abundance and assignment were
correct and within the method requirements. All samples were analyzed with an acceptable
performance check solution and within the 12-hour window requirement. The mass
spectrometer was verified to have a resolution of ≥ 10000 AMUs. The retention time
windows were established with a window defining mix. The verification met all QC
requirements listed in the NFGO and EPA-1668.
Initial Calibrations
Percent Relative Standard Deviations (%RSD) were verified to be within 90 -110% for each
compound.
Initial Calibration Verifications and Resolution Checks
The initial calibration curve was verified with a second source standard mix. Resolutions
and retentions times were verified to be within acceptance criteria of 90 -110%.
ICP Serial Dilutions
The validation was performed using guidance defined in the project procedures manual. All
ICP serial dilutions percent differences were within control limits or reported detected <50
times the MDL.
Continuing Calibrations
Continuing calibration recoveries were within the QC recovery compound specific limits
(90%-110%). Continuing calibrations were performed with acceptable results on a 12-
hour basis.
Blanks
Each analytical batch was represented with a method blank. MB 280-635955/1-A was free
of contamination.
Laboratory Control Sample Recovery (Blank Spikes)
LCS/LCSD recoveries are within the laboratory established control limits, specific to each
compound.

18

Matrix Spike/Matrix Spike Duplicate Recoveries
Matrix Spike and Matrix Spike duplicate analysis was not conducted for this method.
Field Blank
Field blank samples were not submitted for this analysis.
Field Duplicate Agreement
FD samples were not submitted for this analysis.
Laboratory Duplicate Agreement
Laboratory duplicates were not submitted for this analysis.
Soil Sample Triplicate
Soil sample triplicates were not submitted for this analysis.
Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.
Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the LOD. The LODs have been verified to
meet or exceed the project required performance standards. Sample dilutions, cleanup
concentrations, and moisture correction have been applied to all reportable results . The
results are reported on a dry weight basis where applicable.
2.2 Metals by SW846-6020B
Method Blanks
The method blank, MB 280-635955/1-A, report all target analytes below their respective
LODs.
Laboratory Control Sample Recovery (Blank Spikes)
The percent recoveries for the LCS for the analysis were within the DOD QSM (or more

19

stringent laboratory) control limits.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD sample was not submitted for this analysis.
Post Digestion Spikes
PDS results are within established acceptance criteria.
Field Blank
Field blank samples were not submitted for this analysis.
Field Duplicate Agreement
FD samples were not submitted for this analysis.
ICP Serial Dilutions
The validation was performed using guidance defined in the project procedures manual. All
ICP serial dilutions percent differences were within control limits or reported detected <50
times the MDL.
Initial and Continuing Calibration Verifications
The initial calibration curve was verified with a second source standard mix that contained
all target compounds. Continuing calibration verifications (CCV) were performed per
method requirements. All sample results are bracketed by valid CCV results. None of the
data is qualified based on calibration verifications.
Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.
Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the Level of Detection (LOD). The LODs have
been verified to meet or exceed the project required performance standards. Sample
dilutions, cleanup concentrations, and moisture correction have been applied to all
reportable results.

20

2.3 Alkalinity SM20-2320B
Initial Calibrations
Percent Relative Standard Deviations (%RSD) were verified to be ≤20% or the
coefficient of determination for the calibration curve (r2), is ≥0.995, for each compound.
Initial Calibration Verifications and Resolution Checks
The initial calibration curve was verified with a second source standard mix.
Resolutions and retentions times were verified to be within acceptance criteria. All target
analytes had a percent difference of less than 20%.
Continuing Calibrations
Continuing calibration recoveries were within the QC recovery compound specific limits for
all analytes. Continuing calibrations were performed with acceptable results on a 12-hour
basis.
Blanks
Each analytical batch was represented with a method blank. Alkalinity as CaCO3 and
Bicarbonate Alkalinity as CaCO3 were detected in method blanks MB 280-635900/32 and
MB 280-635900/6, at levels that were below half the LOQ. The values should be
considered estimates.
.
• Corresponding samples are qualified J,MBL.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS/LCSD recoveries are within the laboratory established control limits.
Surrogate Recoveries
Surrogate analytes are analyzed with each sample and recoveries were within compound
specific established ranges.
Matrix Spike/Matrix Spike Duplicate Recoveries
MS/MSD sample was not submitted for this analysis.
Field Blank
Field blank samples were not submitted for this analysis.
Field Duplicate Agreement
FD samples were not submitted for this analysis.
Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
21
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.
Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the Level of Detection (LOD). The LODs have
been verified to meet or exceed the project required performance standards. Sample
dilutions, cleanup concentrations, and moisture correction have been applied to all
reportable results.
2.4 Specific Ions: Sulfates E300.00
Initial Calibrations
Percent Relative Standard Deviations (%RSD) were verified to be within 90 -110% for each
compound.
Initial Calibration Verifications and Resolution Checks
The initial calibration curve was verified with a second source standard mix. Resolutions
and retentions times were verified to be within acceptance criteria of 90 -110%.
Continuing Calibrations
Continuing calibration recoveries were within the QC recovery compound specific limits
(90%-110%). Continuing calibrations were performed with acceptable results on a 12-
hour basis.
Blanks
Each analytical batch was represented with a method blank. The laboratory reports none
of the target compounds were detected in the method blanks.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS/LCSD recoveries are within the laboratory established control limits.
Surrogate Recoveries
Surrogate analytes are analyzed with each sample and recoveries were within compound
specific established ranges.
Laboratory Duplicate Agreement
Laboratory duplicates were not submitted for this analysis.
Matrix Spike/Matrix Spike Duplicate Recoveries
Samples 280-184903-1 and 280-184903-6 were used for Matrix Spike and Matrix Spike
duplicate analysis. All analytes’ RDP and %R values were within the requirements of set
22
control limits specific for each analyte, except for Sulfate failed the recovery criteria high for
the MS and MSD of sample T-870-82B-11202023 (280-184903-6) in batch 280-636687.
Due to the high concentration of Sulfate, the matrix spike / matrix spike duplicate
(MS/MSD) for analytical
batch 280-636687 could not be evaluated for accuracy and precision. The associated
laboratory control sample (LCS/LCSD) met acceptance criteria.
•280-184903-6 is qualified J, MSH.
Laboratory Duplicate
Samples 280-184903-1 and 280-184903-6 were used in duplicate analysis. All RPD
values were within the RPD limit of 15%.
Field Blank
Field QC samples were not submitted for this analysis.
Field Duplicate Agreement
FD samples were not submitted for this analysis.
Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.
Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the Level of Detection (LOD). The LODs have
been verified to meet or exceed the project required performance standards. Sample
dilutions, cleanup concentrations, and moisture correction have been applied to all
reportable results.
2.5 Specific Ion: Nitrates E353.2
Initial Calibrations
Percent Relative Standard Deviations (%RSD) were verified to be within 90 -110% for each
compound.
23
Initial Calibration Verifications and Resolution Checks
The initial calibration curve was verified with a second source standard mix. Resolutions
and retentions times were verified to be within acceptance criteria of 90 -110%.
Continuing Calibrations
Continuing calibration recoveries were within the QC recovery compound specific limits
(90%-110%). Continuing calibrations were performed with acceptable results on a 12-
hour basis.
Blanks
Each analytical batch was represented with a method blank. The laboratory reports no
target compounds were detected in the method blank, MB 280-637162/20.
Laboratory Control Sample Recovery (Blank Spikes)
All LCS/LCSD recoveries are within the laboratory established control limits.
Surrogate Recoveries
Surrogate analytes are analyzed with each sample and recoveries were within compound
specific established ranges.
Matrix Spike/Matrix Spike Duplicate Recoveries
Matrix Spike and Matrix Spike duplicate analysis was not conducted for this method.
Field Blank
Field blank samples were not submitted for this analysis.
Field Duplicate Agreement
FD samples were not submitted for this analysis.
Laboratory Duplicate Agreement
Laboratory duplicates were not submitted for this analysis.
Calibration Blanks
All calibration blanks were reviewed in accordance with the project procedures manual.
Calibration blanks were analyzed at the beginning and ending of each QC batch of 20
samples or more often if necessary. Raw calibration blank (ICB and CCB) detections were
compared to the raw sample data detections to facilitate analogous units originating from
the analytical instrumentation. None of the data is qualified based on associated initial or
continuing calibration blank contaminations.
Internal Standards
Internal standards were reviewed for response and retention times. None of the internal
standards are reported outside the control limits. Therefore, data qualification was not
required.
Target Compound Identification
Target compounds were reviewed during the data validation process for their pattern
responses and retention times. None of the identified target compounds were qualified
24
based on compound identification.
Compound Quantitation and Reporting Limits
Reporting limits were verified to be equal to the Level of Detection (LOD). The LODs have
been verified to meet or exceed the project required performance standards. Sample
dilutions, cleanup concentrations, and moisture correction have been applied to all
reportable results.
CONCLUSION
The following samples were qualified based on this validation. Stage 4 independent
calculated results from the raw data are analogous to the reported results.
Field
Sample
ID
Lab
Sampl
e ID
Lab
Method
Lab
Parameter
Name
Lab
Resul
t
Lab
Qualifi
er
Detecte
d
Best
Valu
e
Validatio
n
Qualifier
Validatio
n Reason
Codes
DUP-01-
1120202
3
280-
18490
3-4
SW8260
D
Ethylbenzen
e 0.4 U N Y UJ FDPR
DUP-01-
1120202
3
280-
18490
3-4
M8015D
Petroleum
Hydrocarbo
ns C10-C28
0.12 U N Y UJ CCVD
DUP-01-
1120202
3
280-
18490
3-4
M8015V
Petroleum
Hydrocarbo
ns C6-C10
0.12 Q Y Y J SSH
DUP-01-
1120202
3
280-
18490
3-4
SW8260
D
Xylenes,
Total 3.4 Y Y J FDPR
T-870-
82B-
1120202
3
280-
18490
3-6
E300 Sulfate (as
SO4) 110 J1 Y Y J MSH
T-870-
82B-
1120202
3
280-
18490
3-6
M8015D
Petroleum
Hydrocarbo
ns C10-C28
0.12 U N Y UJ CCVD
T-870-
82B-
1120202
3
280-
18490
3-6
A2320B
Alkalinity,
Total (as
CACO3)
490 Y Y J MBL
T-870-
82B-
1120202
3
280-
18490
3-6
A2320B
Alkalinity,
Bicarbonate
(as CACO3)
490 Y Y J MBL
T-914-
017-
280-
18490
3-1
SW8260
D Benzene 0.8 U N Y UJ SSH

25

Field
Sample
ID
Lab
Sampl
e ID
Lab
Method
Lab
Parameter
Name
Lab
Resul
t
Lab
Qualifi
er
Detecte
d
Best
Valu
e
Validatio
n
Qualifier
Validatio
n Reason
Codes
1120202
3
T-914-
017-
1120202
3
280-
18490
3-1
A2320B
Alkalinity,
Bicarbonate
(as CACO3)
290 Y Y J MBL
T-914-
017-
1120202
3
280-
18490
3-1
A2320B
Alkalinity,
Total (as
CACO3)
290 Y Y J MBL
T-914-
017-
1120202
3
280-
18490
3-1
SW8260
D
Ethylbenzen
e 0.4 U N Y UJ SSH
T-914-
017-
1120202
3
280-
18490
3-1
SW8260
D Toluene 0.4 U N Y UJ SSH
T-914-
017-
1120202
3
280-
18490
3-1
SW8260
D
Naphthalen
e 0.8 U N Y UJ SSH
T-914-
017-
1120202
3
280-
18490
3-1
M8015D
Petroleum
Hydrocarbo
ns C10-C28
0.12 U N Y UJ CCVD
T-914-
017-
1120202
3
280-
18490
3-1
SW8260
D
Xylenes,
Total 0.8 U N Y UJ SSH
T-914-
018-
1120202
3
280-
18490
3-3
M8015V
Petroleum
Hydrocarbo
ns C6-C10
0.12 Q Y Y J SSH
T-914-
018-
1120202
3
280-
18490
3-3
SW8260
D
Xylenes,
Total 13 Y Y J FDPR
T-914-
018-
1120202
3
280-
18490
3-3
M8015D
Petroleum
Hydrocarbo
ns C10-C28
0.13 U N Y UJ CCVD
T-914-
018-
280-
18490
3-3
SW8260
D
Ethylbenzen
e 0.82 J Y Y J FDPR

26

Field
Sample
ID
Lab
Sampl
e ID
Lab
Method
Lab
Parameter
Name
Lab
Resul
t
Lab
Qualifi
er
Detecte
d
Best
Valu
e
Validatio
n
Qualifier
Validatio
n Reason
Codes
1120202
3
T-914-
018-
1120202
3
280-
18490
3-3
A2320B
Alkalinity,
Total (as
CACO3)
240 Y Y J MBL
T-914-
018-
1120202
3
280-
18490
3-3
A2320B
Alkalinity,
Bicarbonate
(as CACO3)
240 Y Y J MBL
T-914-
019-
1120202
3
280-
18490
3-5
A2320B
Alkalinity,
Total (as
CACO3)
230 Y Y J MBL
T-914-
019-
1120202
3
280-
18490
3-5
A2320B
Alkalinity,
Bicarbonate
(as CACO3)
230 Y Y J MBL
T-914-
019-
1120202
3
280-
18490
3-5
M8015D
Petroleum
Hydrocarbo
ns C10-C28
0.13 U N Y UJ CCVD
TB-
1120202
3
280-
18490
3-2
SW8260
D
Naphthalen
e 0.8 U N Y UJ MBL
ICAL Analyte/IS: Chloromethane /FB
Amount Response ISTD Amt ISTD Resp Rel. Resp.
Lab Reported
Source Page 407
0.5 50.0 1851509.0 0.00
1.0000 50.0 1865940.0 0.00
2.0000 37188 50.0 1526085.0 1.22 0.6092 0.6092
5.0000 82157 50.0 1567489.0 2.62 0.5241 0.5241
10.0000 138411 50.0 1651602.0 4.19 0.4190 0.4190
50.0000 747620 50.0 1602935.0 23.32 0.4664 0.4664
75.0000 1108795 50.0 1592069.0 34.82 0.4643 0.4643
100.0000 1380505 50.0 1639022.0 42.11 0.4211 0.4211
200.0000 2573045 50.0 1502189.0 85.64 0.4282 0.4282
AVG 0.4761 0.4761
COEF 0.999236
%RSD 14.56 14.6
QC type Analyte spike recovery spike amount %D reporte Source
ICV 280-635237/22 Ethyl ether 52.8 50 5.6 5.6 719
CCV 280-635587/2 Chloromethane 52 50 4.0 4 726
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported
Source
Page
Lab
reported
LCS Source Page
Benzene/FB 50 51.16 102.31 102 21 51.2 796
Ethylbenzene/CBNZd5 50 46.90 93.80 94 21 46.9 796
Naphthalene/DCBd4 50 48.11 96.23 96 21 48.1 796
Toluene/FB 50 49.47 98.94 99 21 49.5 796
Xylenes, Total/CBNZd5 100 95.45 95.45 96 21 95.5 796
Sample ID: T-914-017-11202023 (280-184903-1)
Analyte amount amount injected DV recovery %Lab Source
1,2-Dichloroethane-d4 52.00960 50 104.0191962 104%372
Analyte amount amount injected DV recovery %Lab Source
4-BFB 45.90402 50 91.80804488 92%372
Surrogate Recoveries
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-184903-1 12/14/2023
Performed by E-Lab Consultants
Analy batch 635237 Inst VMS_R1 RRF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
ICV/CCV (form 7)
Surrogate Recoveries
LCS 280-635386/4
Analyte amount amount injected DV recovery %Lab Source
Toluene-d8/CBNZ-d5 48.75058 50 97.50116688 98%372
Analyte amount amount injected DV recovery %Lab Source
DBFM/FB 51.52313 50 103.0462643 103%372
Sample ID: T-914-018-11202023 ( 280-184903-3)
Analyte amount amount injected DV recovery %Lab Source
1,2-Dichloroethane-d4/FB 49.41854 50 98.83707583 99%383
Analyte amount amount injected DV recovery %Lab Source
4-BFB/DCBd4 44.90621 50 89.81241931 90%383
Analyte amount amount injected DV recovery %Lab Source
Toluene-d8/CBNZ-d5 49.36374 50 98.72748377 99%383
Analyte amount amount injected DV recovery %Lab Source
DBFM/FB 51.28207 50 102.5641415 103%383
Sample ID: DUP-01-11202023 ( 280-184903-4)
Analyte amount amount injected DV recovery %Lab Source
1,2-Dichloroethane-d4/FB 50.42849 50 100.8569755 101%390
Analyte amount amount injected DV recovery %Lab Source
4-BFB/DCBd4 46.78820 50 93.57640214 94%390
Analyte amount amount injected DV recovery %Lab Source
Toluene-d8/CBNZ-d5 48.59145 50 97.1829023 97%390
Analyte amount amount injected DV recovery %Lab Source
DBFM/FB 51.85477 50 103.7095348 104%390
MS/MSD Sample:
MS %R MSD%R RPD MS %R MSD%R RPD
Benzene/FB 90.50554 89.21991 1.430656767 91 89 1
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Surrogate Recoveries
Back Calculation of Data for Validation LCS
LCS 280-635386/4
Surrogate Recoveries
Surrogate Recoveries
280-184903-1 MS
Calculated Lab reported page
Benzene/FB 2539231 2411848 50 1.029 1 51.16 51.2
Source page 797 797 797 740 796 796
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Ethylbenzene/CBNZd5 918392 622014 50 1.574 1 46.90220 46.9
Source page 798 797 797 741 796 796
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Naphthalene/DCBd4 1788168 1067364 50 1.741 1 48.11351 48.1
Source page 799 797 797 742 796 796
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Toluene/FB 2696404 2411848 50 1.13 1 49.46825 49.5
Source page 798 797 797 741 796 796
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab Reported
Xylenes, Total/CBNZd5 2256619 622014 100 3.801 1 95.44654 95.5
Source page 670 797 797 741 796 796
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
amount
injected
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
1,2-Dichloroethane-d4/FB 336191 1160506 50 0.2785 50 1 52.00959808 52
Back Calculation of Data for Validation LCS
LCS 280-635386/4
Back Calculation of Data for Validation LCS
LCS 280-635386/4
Back Calculation of Data for Validation LCS
LCS 280-635386/4
Back Calculation of Data for Validation Surrogate
T-914-017-11202023 (280-184903-1)
LCS 280-635386/4
Back Calculation of Data for Validation LCS
Source page 372 372 372 412 412 104%372
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
4-BFB/DCBd4 439606 541910 50 0.8836 50 1 45.90402244 45.9
Source page 372 372 372 412 412 92%372
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
Toluene-d8/CBNZ-d5 1272778 320642 50 4.0712 50 1 48.75058344 48.8
Source page 372 372 372 412 412 98%372
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
DBFM/FB 310086 1160506 50 0.2593 50 1 51.52313213 51.5
Source page 372 372 372 412 412 103%372
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
amount
injected
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
1,2-Dichloroethane-d4/FB 325143 1181216 50 0.2785 50 1 49.41853792 49.4
Source page 383 383 383 412 382 99%383
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
4-BFB/DCBd4 425934 536723 50 0.8836 50 1 44.90620965 44.9
Source page 383 383 383 412 382 90%383
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
Back Calculation of Data for Validation Surrogate
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation Surrogate
T-914-017-11202023 (280-184903-1)
Back Calculation of Data for Validation Surrogate
T-914-017-11202023 (280-184903-1)
Back Calculation of Data for Validation Surrogate
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation Surrogate
T-914-018-11202023 ( 280-184903-3)
T-914-017-11202023 (280-184903-1)
Back Calculation of Data for Validation Surrogate
Toluene-d8/CBNZ-d5 1272970 316707 50 4.0712 50 1 49.36374189 49.4
Source page 383 383 383 412 382 99%383
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
DBFM/FB 314143 1181216 50 0.2593 50 1 51.28207074 51.3
Source page 383 383 383 412 382 103%383
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
amount
injected
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
1,2-Dichloroethane-d4/FB 334754 1191776 50 0.2785 50 1 50.42848774 50.4
Source page 390 390 390 412 389 101%390
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
4-BFB/DCBd4 439471 531506 50 0.8836 50 1 46.78820107 46.8
Source page 390 390 390 412 389 94%390
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
Toluene-d8/CBNZ-d5 1310416 331205 50 4.0712 50 1 48.59145115 48.6
Source page 390 390 390 412 389 97%390
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
DBFM/FB 320491 1191776 50 0.2593 50 1 51.85476739 51.9
Source page 390 390 390 412 389 104%390
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Back Calculation of Data for Validation Surrogate
DUP-01-11202023 ( 280-184903-4)
DUP-01-11202023 ( 280-184903-4)
Back Calculation of Data for Validation Surrogate
DUP-01-11202023 ( 280-184903-4)
Back Calculation of Data for Validation Surrogate
DUP-01-11202023 ( 280-184903-4)
Back Calculation of Data for Validation Surrogate
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation Surrogate
Back Calculation of Data for Validation
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab reported
Ethylbenzene/FB 7655 316707 50 1.4671 1 0.823754537 0.82
Source page 384 383 367 410 382 382
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab reported
Xylenes, Total/CBNZ-d5 147961 316707 100 3.4917 1 13.37989 13
Source page 384 383 383 410 382 382
calculation notation B C D E F G H I
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab reported
Xylenes, Total/CBNZ-d5 38845 331205 100 3.4917 1 3.35893 3.4
Source page 391 390 390 410 389 389
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab reported
Benzene/FB 1192437 1246480 50 1.057 1 45.25277 45.3
Source page 822 821 821 727 827 820
calculation notation B C D E F G H I
((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc Lab reported
Benzene/FB 1248158 1323527 50 1.057 1 44.60995 44.6
Source page 829 828 828 727 827 827
calculation notation B C D E F G H I
Back Calculation of Data for Validation
DUP-01-11202023 ( 280-184903-4)
T-914-018-11202023 ( 280-184903-3)
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation
280-184903-1 MS
280-184903-1 MSD
ICAL Analyte/IS: Diesel Range Organics [C10-C28]
Amount Response ISTD Amt
ISTD Resp pg.
180 Rel. Resp.
Lab Reported
Source Page
1038
100 13804350 1 1 13804350 138044 138044
250 36316196 1 1 36316196 145265 145265
1000 154065217 1 1 154065217 154065 154065
5000 614229058 1 1 614229058 122846 122846
7500 971998725 1 1 971998725 129600 129600
15000 1866275393 1 1 1866275393 124418 124418
30000 3868641910 1 1 3868641910 128955 128955
AVG 134742 134742
COEF 0.999778283
%RSD 8.59 8.6
QC type Analyte spike recovery spike amount %D
reported by
lab Source page
ICV 280-628389/11 DRO[C10-C28]1710 2000 -14.5 -14.4 1073
CCV 280-636127/26 DRO[C10-C28]5090 5000 1.8 1.8 1085
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported
Source
Page
Lab reported
LCS Amount Source Page
DRO[C10-C28]2 1.69 84.65 85 24 1.69 1109
Sample ID: T-914-017-11202023 (280-184903-1)
Analyte
amount
detected amount injected DV recovery %
Lab
reported Source Page
o-Terphenyl 27.44151 35 78.40432683 78%1007
Sample ID: T-914-018-11202023 (280-184903-3)
Analyte amount amount injected DV recovery %Lab Source Page
o-Terphenyl (Surr)26.84453 35 76.69864331 77%1014
Surrogate Recoveries
Surrogate Recoveries
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-184903-1 12/14/2023
Performed by E-Lab Consultants
Batch: 628389 SGC_U2a RRF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
ICV/CCV (form 7)
Surrogate Recoveries
LCS 280-635153/2-A
Analyte amount amount injected DV recovery %Lab Source Page
n-Octacosane 45.39828 35 129.7093747 130%1014
Sample ID: DUP-01-11202023 (280-184903-4)
Analyte amount amount injected DV recovery %Lab Source Page
o-Terphenyl (Surr)33.96329 35 97.03797584 97%1020
Analyte amount amount injected DV recovery %Lab Source Page
n-Octacosane 49.79442 35 142.2697633 142%1020
3
MS/MSD Sample:
MS %R MSD%R RPD MS %R MSD%R RPD
DRO[C10-C28]88.52341 85.11861 9.436802682 89 87 9
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF slope intercept Dilution DV Analyte Lab Reported
DRO[C10-C28]228123756 1 1 134741.74 1 1.693044457 1.69
Source page 1135 1135 1135 1036 1109 1109
calculation notation B C D E F G H I
calculation ((C*E*J)/(D*F))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
o-Terphenyl 4830923 1 1 173818.88 61069.703 1 27.44151439 27.4
Source page 1008 1008 1008 1038 1038 1007 78%1007
calculation notation B C D E F G H I
calculation ((C*E*J)/(D*F))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD slope intercept Dilution DV Analyte Lab Reported
o-Terphenyl (Surr)4727155 1 1 173818.88 61069.703 1 26.84452516 26.8
Source page 1014 1014 1014 1038 1038 1013 77%1014
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF Dilution DV Analyte Lab Reported
n-Octacosane 4344510 1 1 95697.676 1 45.39828115 45.4
Source page 1014 1014 1014 1038 10 130%1014
Back Calculation of Data for Validation Surrogate
T-914-018-11202023 (280-184903-3)
T-914-018-11202023 (280-184903-3)
Back Calculation of Data for Validation Surrogate
T-914-017-11202023 (280-184903-1)
Back Calculation of Data for Validation Surrogate
Back Calculation of Data for Validation LCS
LCS 280-635153/2-A
Surrogate Recoveries
Calculated Lab reported page
Surrogate Recoveries
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD slope intercept Dilution DV Analyte Lab Reported
o-Terphenyl (Surr)5964531 1 1 173818.88 61069.703 1 33.96329154 34
Source page 1020 1020 1020 1038 1038 1019 97%1020
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF Dilution DV Analyte Lab Reported
n-Octacosane 4765210 1 1 95697.676 1 49.79441716 49.8
Source page 1020 1020 1020 1038 1019 142%1020
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Vol (mL)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc Lab reported
DRO[C10-C28]2887449 1 1 134741.74 951.5 0 1 1 0.02 0.13 LOD
Source page 1014 1013 1013 1036 1013 1013 1013 1013
calculation notation B C D E F G H I
calculation ((C*E*J)/(D*F))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) Spl Vol (mL)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc Lab reported
DRO[C10-C28]4519392 1 1 134741.74 974.7 0 1 1 0.03 0.12 LOD
Source page 1020 1020 1020 1036 1019 1019 1019 1019
calculation notation B C D E F G H I
calculation ((C*E*J)/(D*F))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Spl Vol
(mL)
Spl %
Moisture Ext Vol (mL)
Dilution
Factor
DV Analyte
Conc Lab reported
DRO[C10-C28]238845803 1 1 134742 991.3 0 1 1 1.78817 1.79
Source page 1120 1120 1120 1038 1119 1119 1119 1119 1119
calculation notation B C D E F G H I
((C*E*J)/(D*F))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF Spl Vol Spl % Ext Vol (mL)Dilution DV Analyte Lab reported
Back Calculation of Data for Validation Surrogate
DUP-01-11202023 (280-184903-4)
Back Calculation of Data for Validation
T-914-018-11202023 ( 280-184903-3)
DUP-01-11202023 (280-184903-4)
Back Calculation of Data for Validation
280-184903-1 MS
280-184903-1 MSD
Back Calculation of Data for Validation Surrogate
DUP-01-11202023 (280-184903-4)
DRO[C10-C28]233676480 1 1 134742 1065.9 0 1 1 1.62703 1.63
Source page 1126 1126 1126 1038 1125 1125 1125 1125 1125
calculation notation B C D E F G H I
((C*E*J)/(D*F))
*For samples that are ND, surrogate recalculations were provided.
ICAL Analyte/IS: Gasoline Range Organics (GRO)-C6-C10
Amount Response ISTD Amt
ISTD Resp pg.
180 Rel. Resp.
Lab Reported
Source Page 885
3.57 2170759 1.0 1.0 2170759.00 608056 607593
8.9 3203242 1.0 1.0 3203242.00 358706 358633
17.9 4886679 1.0 1.0 4886679.00 272999 273555
89.3 18574185 1.0 1.0 18574185.00 207998 207956
179.0 34537348 1.0 1.0 34537348.00 192946 193339
357.0 68323266 1.0 1.0 68323266.00 191382 191236
893.0 173181917 1.0 1.0 173181917.00 193933 193894
1786.0 346034323 1.0 1.0 346034323.00 193748 193709
AVG 277470.8234 189862.2000
COEF 1.00 1.0000
%RSD 52.63
QC type Analyte spike recovery spike amount %D
reported by
lab Source page
CCV 280-635060/2 GRO 178 181 -1.7 -1.5 929
CCV 280-635060/19 C4-C12 206 200 3.0 3.1 939
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported
Source
Page
Lab reported
LCS Amount Source Page
(GRO)-C6-C10 0.426 0.42 98.21 98 23 0.418 969
Sample ID: T-914-017-11202023 (280-184903-1)
Analyte
amount
detected amount injected DV recovery %
Lab
reported Source Page
a,a,a-Trifluorotoluene 62.27550 60 103.7924998 104%854
Sample ID: T-914-018-11202023 ( 280-184903-3)
Analyte amount amount injected DV recovery %Lab Source Page
a,a,a-Trifluorotoluene 70.79600 60 117.9933296 118%865
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-184903-1 12/14/2023
Surrogate Recoveries
Batch: 632163 Instrument ID: VGC_S1 RRF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
ICV/CCV (form 7)
Surrogate Recoveries
LCS 280-635060/3
Performed by E-Lab Consultants
Sample ID: DUP-01-11202023 (280-184903-4)
Analyte amount amount injected DV recovery %Lab Source Page
a,a,a-Trifluorotoluene 71.03339 60 118.3889817 118%870
MS/MSD Sample:
MS %R MSD%R RPD MS %R MSD%R RPD
(GRO)-C6-C10 95.94198 93.43508 2.647515561 96 94 3
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF slope intercept Dilution DV Analyte Lab Reported
(GRO)-C6-C10 80925604 1 1 189862.2 1494355 1 0.418362628 0.418
Source page 969 943 943 796 796 969 969
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL)
Dilution
Factor
DV Analyte
Conc
Lab Reported
OnCol Amt
(ug/mL)
a,a,a-Trifluorotoluene 23189427 1 1 372368.38 1 62.27549987 62.3
Source page 855 855 855 914 854 104%854
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
a,a,a-Trifluorotoluene 26362191 1 1 372368.38 50 1 70.79599777 70.8
Source page 865 865 865 914 864 118%865
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte Response Analyte Response Conc Assoc. ISTD Analyte RRF amount Dilution DV Analyte Lab Reported
a,a,a-Trifluorotoluene 26450588 1 1 372368.38 50 1 71.03338903 71
Source page 870 870 870 914 869 118%870
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Surrogate Recoveries
Calculated Lab reported page
Back Calculation of Data for Validation LCS
LCS 280-635060/3
Back Calculation of Data for Validation Surrogate
T-914-017-11202023 (280-184903-1)
Back Calculation of Data for Validation Surrogate
Back Calculation of Data for Validation Surrogate
DUP-01-11202023 (280-184903-4)
T-914-018-11202023 ( 280-184903-3)
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
DV Analyte
Conc ug/mL
Lab reported
mg/L
(GRO)-C6-C10 23412041 1 1 189862.2 1494355 1 0.115439966 0.12
Source page 865 865 865 796 796 864 864
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
DV Analyte
Conc Lab reported
(GRO)-C6-C10 24285980 1 1 189862.2 1494355 1 0.120042984 0.12
Source page 870 870 870 796 796 869 869
calculation notation B C D E F G H I
((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
DV Analyte
Conc Lab reported
(GRO)-C6-C10 79093469 1 1 189862.2 1494355 1 0.40871 0.409
Source page 979 979 979 796 796 979 979
calculation notation B C D E F G H I
((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc. ISTD
(ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
DV Analyte
Conc Lab reported
(GRO)-C6-C10 77065861 1 1 189862.2 1494355 1 0.39803 0.398
Source page 986 986 986 796 796 985 985
calculation notation B C D E F G H I
((B*D*I)/(C*E))
T-914-018-11202023 ( 280-184903-3)
DUP-01-11202023 (280-184903-4)
Back Calculation of Data for Validation
280-184903-1 MS
Back Calculation of Data for Validation
280-184903-1 MSD
Metals_6020B
QC type Analyte
spike recovery
(ug/L)
spike amount
(ug/L) %D
reported by
lab Source page
ICV 280-636339/5 Arsenic 42 40 105 105 1149
CCV 280-636339/74 Manganese 51.5 50 103 103 1149
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported Source Page
Lab reported
LCS Amount
Source
Page
Arsenic 40 39.27 98.16 98 1199 39 1164
Sample Name:
Analyte
Response
Analyte (Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL)
Raw
Concentrati
on (mg/L)
Final Volume
(L)
initial
volume
(L)
Dilution
Factor
DV Analyte
Conc
Lab
reported
Arsenic 1 39.265 0.5 0.5 1 39.265 39.3
Source page 1158 1201 1201 1330 1164
calculation notation B C D E B C D E
calculation ((F*G*I)/(H))
Sample Name:
Analyte
Response
Analyte (Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL)
Raw
Concentrati
on
Final Volume
(L)
initial
volume
(L)
Dilution
Factor
Ca DV Analyte
Conc
Lab
reported
Manganese 16.405 0.05 0.05 1 16.4 16
Source page 1568 1201 1201 1568 1142
calculation notation B C D E F G H I
calculation ((F*G*I)/(H))
ICV/CCV (form 7)
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-184903-1 12/14/2023
Performed by E-Lab Consultants
Back Calculation of Data for Validation LCS
LCS 280-635955/24-A
LCS 280-635955/24-A
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation
Page 1
Metals_6010D
QC type Analyte
spike recovery
(ug/L)
spike amount
(ug/L) %D
reported by
lab Source page
ICV 280-636238/7 Iron 1210 1250 97 97 1147
CCV 280-636238/20 Iron 2530 2500 101 101 1147
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported Source Page
Lab reported
LCS Amount
Source
Page
Iron 10000 10410.20 104.10 104 1163 10400 1163
Sample Name:
Analyte
Response
Analyte (Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL)
Raw
Concentrati
on (mg/L)
Final Volume
(L)
initial
volume
(L)
Dilution
Factor
DV Analyte
Conc
Lab
reported
Iron 1 10.410195 0.05 0.05 1 10410.195 10400
Source page 1331 1200 1200 1713 1163
calculation notation B C D E B C D E
calculation ((F*G*I)/(H))
Sample Name:
Analyte
Response
Analyte (Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL)
Raw
Concentrati
on
Final Volume
(L)
initial
volume
(L)
Dilution
Factor
Ca DV Analyte
Conc
Lab
reported
Iron 0.017172 0.5 0.5 1 17.2 17
Source page 1351 1200 1200 1351 1142
calculation notation B C D E F G H I
calculation ((F*G*I)/(H))
LCS 280-635955/2-A
ICV/CCV (form 7)
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-184903-1 12/14/2023
Performed by E-Lab Consultants
Back Calculation of Data for Validation LCS
LCS 280-635955/2-A
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation
Page 1
EPA 300
ICAL Analyte/IS: Sulfate
Amount Response ISTD Amt ISTD Resp Rel. Resp.
Lab
Reported
Source Page
1 2656542 1 1 2656542 2656542
3 5339330 1 1 5339330 2135732
5 10996507 1 1 10996507 2199301
60 126721303 1 1 126721303 2112022
120 262931201 1 1 262931201 2191093
200 495606287 1 1 495606287 2478031
AVG 2295454
COEF 0.997387954 0.999
%RSD 9.60
QC type Analyte
spike recovery
(ug/L)
spike amount
(ug/L) %D
reported by
lab Source page
ICV Nitrate as N 5.01 5 100 100 1619
CCV Nitrate as N 5.13 5 103 103 1619
LCS Recoveries:
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported Source Page
Lab reported
LCS Amount Source Page
Sulfate 100 97.65 97.65 98 1629 98 1629
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Data Validation calculations for
ICV/CCV (form 7)
Performed by E-Lab Consultants
RRF
(STDEV(G8:G16)/AVERAGE(G8:G16))*100
280-636687/4
Eurofins Test America 280-184903-1 12/14/2023
Batch: 0128284 WC_IonChrom15
Page 1
EPA 300
Sample Name:
Analyte
Response
Analyte (Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
DV Analyte
Conc
Lab
reported
Sulfate 227389505 1 1 1 2330000 -125000 1 97.6457103 97.7
Source page 1766 1632 1632 1724 1629
calculation notation B C D E B C D E
calculation ((F*G*I)/(H))
Sample Name:
Analyte
Response
Analyte (Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL) slope intercept
Dilution
Factor
Ca DV
Analyte Conc
Lab
reported
Sulfate 162224095 1 1 0.9975 10900000 779000 1 14.81148 15
Source page 1717 1632 1632 1717 2133
calculation notation B C D E F G H I
calculation ((F*G*I)/(H))
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation
Back Calculation of Data for Validation LCS
280-636687/4
Page 2
QC type Analyte
spike recovery
(mg/L)
spike amount
(mg/L) %D reported by lab Source page
CCV Alkalinity as CaCO3 209 200 105 105 1624
LCS 280-635900/4
Analyte spike added
LCS recovery
(cal below) %Recovery Lab reported Source Page
Lab reported
LCS Amount Source Page
Alkalinity as CaCO3 200.00 210.000 105.00 101.00 2150 210.000 1629
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL)
Raw
Concentration
(mg/L)
Final
Volume (L)
initial volume
(L)
Dilution
Factor
DV Analyte
Conc
Lab
Reported
Alkalinity as CaCO3 209.54 0.01 0.01 1 209.54 210
Source page 1812 1671 1671 1812 1629
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
Sample Name:
Analyte
Response Analyte
(Area)
Response
Assoc. ISTD
Conc Assoc.
ISTD (ug/L)
Analyte RRF
(from ICAL)
Raw
Concentration
(mg/L)
Final
Volume (L)
initial volume
(L)
Dilution
Factor
DV Analyte
Conc
Lab
reported
Alkalinity as CaCO3 237.58 0.01 0.01 1 237.58000 240
Source page 1812 1671 1671 1812 1616
calculation notation B C D E F G H I
calculation ((B*D*I)/(C*E))
LCS 280-635900/4
ICV/CCV (form 7)
Data Validation calculations for
W91238-20-C-0014 from Basewide UFP-QAPP, Hill Air Force Base, Optimized Remediation Contract.
Eurofins Test America 280-184903-1 12/14/2023
Performed by E-Lab Consultants
Back Calculation of Data for Validation
T-914-018-11202023 ( 280-184903-3)
Back Calculation of Data for Validation LCS
LCS 280-635900/4
HGL Data Validation Review Report
This validation review report represents any additional findings or corrections to the validation performed
by ELAB. All recalculations performed by HGL to correct and/or supplement the recalculations performed
by ELAB are included at the end of this document.
General issues:
NA
100QC spreadsheet
NA
VOCs – 8260D
2.1.1 – Sample Requirements: The validator correctly noted that sample T-870-82B-11202023 was not
preserved to pH of <2 and was analyzed past the 7-day holding time for unpreserved samples, but they
did not qualify the results accordingly. According to DoD Guidelines, all results in these samples should
be qualified J/UJ.
Qualification Changes: All results in sample T-870-82B-11202023 are qualified UJ, reason
code HTA.
2.1.5 - Blanks: The validator noted contamination in a method blank and qualified one result. According
to the UFP_QAPP, if the contamination is below ½ the LOQ, no action is required.
Qualification Changes: All qualifiers relating to method blank contamination are removed.
2.1.6 – Surrogate Recoveries: The validator noted a high surrogate recovery in the MS and qualified the
parent sample as a result. All surrogates passed within control limits in the parent sample and no
qualification is required due to the MS exceedance.
Qualification Changes: All qualifiers relating to high surrogate recoveries in sample T-
914-017-11202023 are removed.
2.1.10 – Field Duplicate Result Agreement: The validator incorrectly compared the field duplicate/parent
results. For results less than 5X the LOQ, results should be compared using the absolute difference
criteria.
Analyte
Concentration (ug/L)
Absolute
Difference
Maximum
Absolute
Difference
(LOQ)
RPD Maximum
RPD T-914-
018-
11202023
DUP-01-
112023
Project Name/Number Hill Air Force Base / V1H001.31.05
Data Validation Stage 2B/4 – Volatile Organic Compounds, GRO, DRO, Metals, Anions, and
Alkalinity
Validation Subcontractor ELAB
Laboratory Eurofins TestAmerica, Denver
SDG 280-184903-1
HGL Reviewer (Stage 2B) John Tracy
Review Date (Stage 2B) 03/21/2024
HGL Reviewer (Stage 4) Ken Rapuano
Review Date (Stage 4) 10.24.24 (Revised 01.08.25)
Ethylbenzene 0.82 0.4 U 0.42 1.0 N/A N/A
Xylenes, Total 13 3.4 9.6 1.0 N/A N/A

Qualification Changes: The qualifiers applied to ethylbenzene results in samples T-914-
018-11202023 and DUP-01-11202023 relating to field duplicate exceedances are removed.
The J qualifiers applied to the total xylenes results remain, but reason code is amended to
FDPA.

Recalculations: Due to errors found in previous DV reports, the HGL reviewer checked the surrogate %R
tables to the summaries in the laboratory report and to the validator’s back-calculated surrogate
concentrations. No discrepancies were found in the recalculated surrogate %Rs; however, several
discrepancies were found in other VOCs calculations on review.
• Non-target VOCs were selected for recalculations of initial calibration (mean RRF calibration),
ICV, and CCV data. The HGL reviewer performed recalculations for these QC elements using
target VOCs using the raw instrument results.
• The validator did not include a recalculation of an instrument tune. HGL validator recalculated a
BFB tuning.
• The validator incorrectly recalculated total xylenes in the LCS and samples selected by the
validator. The validator summed the peak areas and summed the RRFs for m,p-xylenes and o-
xylene and quantified using the summed values. The laboratory reports total xylenes as the sum
of the individually determined m,p-xylenes and o-xylene concentrations. The HGL reviewer
recalculated the total xylenes result using the laboratory’s methodology.

Gasoline Range Organics (GRO) – 8015D GRO

2.2.1. – Sample Requirements: The validator correctly noted that sample T-870-82B-11202023 was not
preserved to pH of <2 and was analyzed past the 7-day holding time for unpreserved samples, but they
did not qualify the results accordingly. According to DoD Guidelines, all results in these samples should
be qualified J/UJ.

Qualification Changes: All results in sample T-870-82B-11202023 are qualified UJ, reason
code HTA.

2.2.3. – ICV and Resolution Checks: The laboratory report did not include GRO ICVs and the data
validation report appears to include a template error. The HGL reviewer contacted the laboratory for a
revised report that included GRO ICV data. The ICV data were in control in the revised data report.

2.2.9 – Field Duplicate Agreement: The validator incorrectly compared the field duplicate/parent results.
For results less than 5X the LOQ, results should be compared using the absolute difference criteria.

Analyte
Concentration (mg/L)
Absolute
Difference
Maximum
Absolute
Difference
(LOQ)
RPD Maximum
RPD T-914-
018-
11202023
DUP-01-
112023
GRO (C6-C10) 0.12 0.12 0 0.025 N/A N/A

Qualification Changes: None

Recalculations:
• The ICal recalculations did not note that the selected ICal did was calibrated to a linear
relationship with 1/x2 weighting. The HGL reviewer recalculated this ICal and reproduced the
slope, intercept, back-calculated standard concentrations, r2, and RSE reported by the laboratory.
• The HGL reviewer recalculated an ICV %D from the raw data.
• The validator recalculated C4-C12 in the representative CCV; C4-C12 is not a target analyte and
the HGL reviewer recalculated the GRO (C6-C10) %D in this CCV using the raw data.
• The validator reported incorrect values for the surrogate %R and quantification recalculations for
sample T-914-017-11202023 (280-184903-1). The HGL reviewer recalculated both values and
replicated the reported values.

Diesel Range Organics (DRO) – 8015D DRO

2.3.3 - Continuing Calibrations: The validator noted a high surrogate recovery in a CCV associated with
this SDG and qualified all results. All target analytes recovered within control limits in the CCV, and no
qualification is required.

Qualification Changes: All qualifiers relating to CCV failures are removed.

2.3.7 – Field Duplicate Agreement: The validator compared the field duplicate/parent results in a table,
but DRO was not detected in either sample and no comparison is required.

Qualification Changes: None

Recalculations: The recalculation of target results in samples includes a term for %moisture which is
populated with “0” for aqueous samples; it appears that the validators use this term to generate a fraction
of solids, and the case of aqueous samples this term is used to represent fraction of mass that is sample,
which is 1 for aqueous samples without sediments. The HGL reviewer was able to confirm a result
recalculated by the validator from the information provided in the validation report.

Several discrepancies were found in other DRO calculations on review.
• The HGL reviewer recalculated an ICV and CCV %D from the raw data.
• The MSD %R recalculated by the validator is incorrect. The HGL reviewer recalculated the
concentration in the MSD and replicated the %R reported by the laboratory.
• The DRO result recalculated for sample DUP-01-11202023 (280-184903-4) uses the response
for C8-C12 instead of for C10-C28. The HGL reviewer recalculated the DRO result for this
sample and confirmed the result reported by the laboratory.

Metals – 6010D

Qualification Changes: None

Recalculations: The validator did not calculate a response factor from the calibration standards and did
not use measured signal intensities to confirm the reported raw concentrations. The HGL reviewer
performed supplemental calculations to address this discrepancy. The validator did not calculate a
response factor from the initial one-point daily calibration and did not use measured signal intensities to
confirm the reported raw concentrations. The HGL reviewer calculated the ICal response factor for iron
using the response for the non-zero spike (IC1) and subtracting the zero spike (ICIS) response.

Metals – 6020B

Qualification Changes: None

Recalculations: Several discrepancies were found on review. The HGL reviewer performed supplemental
calculations to address these discrepancies.
•The validator did not include recalculations for instrument tuning. The HGL reviewer performed
supplemental recalculations of mean count, count %RSD, and counts per second for a selected
mass in the instrument tuning.
•The validator did not calculate a response factor from the calibration standards and did not use
measured signal intensities to confirm the reported raw concentrations. The HGL reviewer
performed supplemental calculations of QC and sample results to address this discrepancy.
•The validation report did not include a recalculation of the LOQ check standard (CRI). The HGL
reviewer recalculated the result for this standard from the instrument response and used the
recalculated result to recalculate the %R.
•The validation report did not include a recalculation of internal standard %Rs; the HGL reviewer
recalculated the IS %R associated with all recalculated field and QC sample results using the
instrument response.
Anions – 300.0
Qualification Changes: None
Recalculations: The validator performed combined recalculations for sulfate and nitrate/nitrite. As these
are two different methods, the HGL reviewer recalculated ICV/CCV results for sulfate and added
recalculation of an MS/MSD. The validator recalculated an ICal for sulfate; however, the recalculation did
not include recalculation of slope or intercept using the weighting used by the laboratory. The HGL
reviewer recalculated a sulfate ICal slope and intercept using 1/x weighting.
Anions – 353.2
Qualification Changes: None
Recalculations: The validator performed combined recalculations for sulfate and nitrate/nitrite. As these
are two different methods, the HGL reviewer recalculated the ICal, ICV/CCV, LCS, and sample results for
nitrate/nitrite. The HGL recalculated results matched the laboratory reported values.
Alkalinity – SM 2320B
2.3.4 - Blanks: The validator noted contamination in two method blanks and qualified eight results.
According to the UFP_QAPP, if the contamination is below ½ the LOQ, no action is required.
Qualification Changes: All qualifiers relating to method blank contamination are removed.
VOCs ICal Calculations
SDG 280-184903-1
Concentration units: ug/L
Instrument VMS_R1
Analyzed 11/28/2023
Summary Data pp. 412-423
Raw Data pp. 424-581
Ethylbenzene
IS = Chlorobenzene-d5
File ID Lab Sample ID Analyte Conc Analyte Resp IS Conc IS Resp Calculated RRF Reported RRF
R_1361.D IC 280-635237/21 0.5 5453 50 369251 1.476773 1.476773
R_1360.D IC 280-635237/20 1 15733 50 419216 1.876479 1.876479
R_1359.D IC 280-635237/19 2 24144 50 402460 1.499776 1.499776
R_1358.D IC 280-635237/18 5 58270 50 422769 1.378294 1.378294
R_1357.D IC 280-635237/17 10 113750 50 445803 1.275788 1.275788
R_1356.D ICIS 280-635237/16 50 603786 50 437587 1.379808 1.379808
R_1355.D IC 280-635237/15 75 915580 50 439951 1.387397 1.387397
R_1354.D IC 280-635237/14 100 1276162 50 442255 1.442790 1.442790
R_1353.D IC 280-635237/13 200 2476046 50 416223 1.487211 1.487211
Calculated Reported
Mean RRF 1.4671 1.4671
%RSD 11.5 11.5
VOCs Tuning Calculations
SDG 280-184903-1
Batch 635587
Instrument VMS_R1
Analyzed 11/30/2023
Lab File ID: R_1456.D
Summary data p. 371
Raw Data pp. 774-777
m/e Resp Base resp %R calc %R rep (raw)%R rep (summary)Relative ion Rel ion resp Rel %R calc Rel %R rep (raw)Rel %R rep (summary)
50 47472 286720 16.6 16.6 16.6 95 286720 16.6 16.6 20.0
75 137920 286720 48.1 48.1 48.1 95 286720 48.1 48.1 50.9
95 286720 286720 100.0 100 100 95 286720 100 100 100 Base ion
96 17776 286720 6.2 6.2 6.2 95 286720 6.2 6.2 6.7
173 2193 286720 0.8 0.8 0.8 174 252160 0.9 0.9 0.9
174 252160 286720 87.9 87.9 87.9 95 286720 87.9 87.9 63.6
175 20048 286720 7.0 7.0 7.0 174 252160 8.0 8.0 8.0
176 245760 286720 85.7 85.7 85.7 174 252160 97.5 97.5 97.5
177 15093 286720 5.3 5.3 5.3 176 245760 6.1 6.1 6.1
VOCs ICV and CCV Calculations
SDG 280-184903-1
Concentration units: ug/L
Standard ID: ICV 280-635237/22
File ID: R_1362.D
Instrument VMS_R1
Analyzed 11/28/2023
Summary Data pp. 724-726
Raw Data pp. 727-730
Benzene
IS = Fluorobenzene
Analyte Conc Analyte Resp IS Conc IS Resp RRF50 Calc RRF50 Rep Analyte conc (calc)Analyte conc (rep)
50 715765 50 407753 1.7554 1.7550 51.4 51.5
ICal RRF %D Calc %D Rep
1.7060 2.9 2.9
Standard ID: CCV 280-635587/2
File ID: R_1458.D
Instrument VMS_R1
Analyzed 11/30/2023
Summary Data pp. 731-733
Raw Data pp. 734-737
o-Xylene
IS = Chlorobenzene-d5
Analyte Conc Analyte Resp IS Conc IS Resp RRF50 Calc RRF50 Rep Analyte conc (calc)Analyte conc (rep)
50 1151101 50 602808 1.910 1.910 49.9 50.0
ICal RRF %D Calc %D Rep
1.913 -0.2 -0.2
VOCs LCS Calculations
SDG 280-184903-1
LCS 280-635386/4
Summary Data pp. 361 and 801
Raw Data pp. 802-806
m,p-Xylene
IS = Chlorobenzene-d5
Target Mean RRF 1.8879
Target Response 1131161
IS conc (ug/L)50
IS Response 622014
Dilution factor 1
On-column conc (ug/L)48.2
Reported conc (ug/L)See below
o-Xylene
IS = Chlorobenzene-d5
Target Mean RRF 1.9133
Target Response 1125458
IS conc (ug/L)50
IS Response 622014
Dilution factor 1
On-column conc (ug/L)47.3
Reported conc (ug/L)See below
Calculated total xylenes (ug/L)95.4
Reported total xylenes (ug/L)95.5
VOCs Method Blank Calculations
SDG 280-184903-1
MB 280-635386/9
Summary Data p. 787
Raw Data pp. 788-794
Concentrations in ug/L
Naphthalene
IS = 1,4-Dichlorobenzene-d4
Target Mean RRF 1.7413
Target Response 28682
IS conc (ug/L)50
IS Response 1030810
Dilution factor 1
On-column conc (calc)0.7990
On-column conc (rep)0.7990
Summary report conc 0.799
VOCs Sample Calculations
SDG 280-184903-1
T-914-018-11202023 ( 280-184903-3)DUP-01-11202023 ( 280-184903-4)
Summary Data pp. 387 Summary Data pp. 394
Raw Data pp. 388-393 Raw Data pp. 395-399
m,p-Xylene m,p-Xylene
IS = Chlorobenzene-d5 IS = Chlorobenzene-d5
Target Mean RRF 1.7860 Target Mean RRF 1.7860
Target Response 121505 Target Response 33794
IS conc (ug/L)50 IS conc (ug/L)50
IS Response 316707 IS Response 331205
Dilution factor 1 Dilution factor 1
On-column conc (ug/L)10.7 On-column conc (ug/L)2.86
Reported conc (ug/L)See below Reported conc (ug/L)See below
o-Xylene o-Xylene
IS = Chlorobenzene-d5 IS = Chlorobenzene-d5
Target Mean RRF 1.7057 Target Mean RRF 1.7057
Target Response 26456 Target Response 5051
IS conc (ug/L)50 IS conc (ug/L)50
IS Response 316707 IS Response 331205
Dilution factor 1 Dilution factor 1
On-column conc (ug/L)2.4 On-column conc (ug/L)0.4470
Reported conc (ug/L)See below Reported conc (ug/L)See below
Calculated total xylenes (ug/L)13 Calculated total xylenes (ug/L)3.3
Reported total xylenes (ug/L)13 Reported total xylenes (ug/L)3.4 Possible effect of iterative rounding
GRO ICal Calculations
SDG 280-184903-1
Instrument VGC_S1
Analyzed 11/01/2023
Summary Data pp. 889-891
Raw Data pp. 892-917
TPH-GRO
Calibration:Linear
Weighting:1/x^2
File ID Analyte Conc Analyte Resp Calculated CF Reported CF Weighting (1/x^2)Conc (calc)Conc (rep)
S05805.D 3.57272 2170759 607592.8144 607592.8144 0.078343332 3.56 3.56
S05806.D 8.9318 3203242 358633.4222 358633.4222 0.012534933 9.00 9.00
S05807.D 17.8636 4886679 273555.1065 273555.1065 0.003133733 17.9 17.9
S05808.D 89.318 18574185 207955.6752 207955.6752 0.000125349 90.0 90.0
S05809.D 178.636 34537348 193339.2373 193339.2373 3.13373E-05 174.0 174.0
S05810.D 357.272 68323266 191235.9939 191235.9939 7.83433E-06 352.0 352.0
S05811.D 893.18 173181917 193893.6351 193893.6351 1.25349E-06 904.3 904.3
S05812.D 1786.36 346034323 193709.1756 193709.1756 3.13373E-07 1814.7 1814.7
Weighted Average 4.981098992 2440077.438 Reported but not used n=8
p=2
m (calculated)m (reported)b (calculated)b (reported)r2 (calc)r2 (reported)RSE (calculated)RSE (reported)
189862.204 189862.204 1494355.01 1494355.01 1.0000 1.0000 1.5 1.5
TPH-GRO CCV Calculations
SDG 280-184903-1
Concentration units: ug/L
Calculation of CCRF Back-calculation of conc
CCRF=A[x] / C[x] (calc)C[x]= (A[x]-b)/m
Standard ID: ICV 280-634565/8
File ID: S06171.D
Instrument VGC_S1
Analyzed 11/01/2023
Summary Data pp. 934-935
Raw Data pp. 936-939
GRO C6-C10
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep
Analyte on-column
conc (calc)
C[x]
Analyte on-
column conc
(rep)
Analyte summary
conc (rep)%D Calc %D Rep
425.6 90377104 212352 212329 468.1 468.1 468 10.0 10.0
m b
189862.204 1494355.006 Note: Concentrations reported in the summary page include a 50x workup factor for medium-level analysis (prep log, p. 901)
Standard ID: CCV 280-635060/19
File ID: S06873.D
Instrument VGC_S1
Analyzed 11/23/2023
Summary Data p. 939-940
Raw Data pp. 941-944
GRO C6-C10
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep Analyte conc (calc)
C[x]
Analyte on-
column conc
(rep)
Analyte summary
conc (rep)%D Calc %D Rep
180.7 36118732 199882 308659 182.4 182.4 182 0.9 0.9
m b
189862.204 1494355.006 Note: Spike conc on summary page is rounded; actual spike conc reported from quant report
Analyte amount amount injected %R (calc)%R (rep)Source
TPH-GRO 58.4 60 97 97%859
a,a,a-TFT Page
Target Response 21744783 860
CF 372368.389 919
On-column (calc) (mg/L)58.4 calc
On-column rep (mg/L)58.4 860
Sample ID: T-914-017-11202023 (280-184903-1)
Surrogate Recoveries
TPH-GRO Method Blank Calculations
SDG 280-184903-1
MB 280-635060/5
Summary Data pp. 853 and 974
Raw Data pp. 975-978
Concentrations in ug/L
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
a,a,a-TFT
Target ICal CF 372368.389
Target Response A[x]21568866
On-column conc (calc)57.9
On-column conc (rep)57.9
Spike conc 60.0
%R calc 96.54
%R rep (raw)96.54
%R rep (summary)97
TPH-DRO ICV and CCV Calculations
SDG 280-184903-1
Concentration units: ug/mL (=mg/L)
Calculation of CCRF Back-calculation of conc
CCRF=A[x] / C[x] (calc)C[x]= A[x] / CF ICal
Standard ID: ICV 280-628389/11
File ID: 10040011.D
Instrument SGC_U2a
Analyzed 10/04/2023
Summary Data p. 1088-1089
Raw Data pp. 1090-1093
DRO C10-C28
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep Analyte conc (calc)
C[x]
Analyte on-
column conc
(rep)
Analyte
summary
conc (rep)
%D Calc %D Rep
2000 230632246 115316 115316 1711.7 1711.7 1710 -14.4 -14.4
CF ICal
134741.747
Standard ID: CCV 280-636127/26
File ID: 1205026.D
Instrument SGC_U2a
Analyzed 12/06/2023
Summary Data pp. 1100-1101
Raw Data pp. 1102-1106
DRO C10-C28
Analyte Conc
C[x]
Analyte Resp
A[x]CCRF Calc CCRF Rep Analyte conc (calc)
C[x]
Analyte on-
column conc
(rep)
Analyte
summary
conc (rep)
%D Calc %D Rep
5000 685638018 137128 137128 5088.5 5088.5 5090 1.8 1.8
CF ICal
134741.747
DRO MS/MSD Calculations
SDG 280-184903-1
Back-calculation of conc (on-column) ug/mL Back-calculation of aqueous conc mg/L
C[x]= A[x] / CF ICal C[soil]= ((C[on column] x DF x V[ext]) / V[sample])*0.001 mg/ug
280-179151-4 MSD
Summary Data pp. 1018 and 1140
Raw Data pp. 1141-1145
TPH-DRO
Target ICal CF 134741.747
Target Response A[x]233676480
On-column conc (calc)1734.3
On-column conc (rep)1734.4
Dilution Factor 1
Volume extract mL 1
Volume sample L 1.0659
Result (calc) mg/L 1.63
Result (rep) mg/L 1.63
calculated reported
Parent conc NA 0
Spike NA 1.88
%R 87 87
TPH-DRO Method Blank Calculations
SDG 280-184903-1
MB 280-635153/1-A
Summary Data pp. 1014 and 1118
Raw Data pp. 975-978
Concentrations in ug/mL (=mg/L)
No target analytes detected in the method blank; surrogate recalculations provided as a check of response and calibration.
o-Terphenyl n-Octacosane
m 173818.883 Target ICal CF 95697.6767
b 61069.7031 Target Response A[x]4160004
Target Response A[x]4661383 On-column conc (calc)43.5
On-column conc (calc)26.5 On-column conc (rep)43.5
On-column conc (rep)26.5 Spike conc 35.0
Spike conc 35.0 %R calc 124.20
%R calc 75.62 %R rep (raw)124.20
%R rep (raw)75.62 %R rep (summary)124
%R rep (summary)76
DRO Sample Recalculation
SDG 280-184903-1
DUP-01-11202023 (280-184903-4)
DRO Page
Target Response 1884365 1035
CF 134741.747 1053
On-column (calc) (mg/L)14.0 calc
On-column rep (mg/L)14.0 1035
Dilution factor 1 1034
Extract volume (L)0.001 1034
Sample volume (L)0.9747 1034
Final conc (calc) (mg/L)0.014 calc
Reported conc (mg/L)<MDL (0.033)1034
ICP-AES Calculations
SDG 280-184903-1
1 ppm = 1000 ppb
Note: The raw data only reports the mean intensity from the three scans performed for each analysis
Initial Calibration - Iron page
Intensity - Blank (ICIS)32.944383 1217
Intensity Cal 16417.908215 1218
Target Standard Conc (ppm)5 1218
RF (calculated)3276.992766 Calc
CRI (LOQ Check) - Iron
Intensity - Blank (ICIS)32.944383 1217
Intensity - Target 352.703853 1227
RF 3276.992766 NA
Raw conc - calc (ppm)0.097577 NA
Raw conc - rep (ppm)0.097577 1227
Reported conc (ppb)97.6 1167
Spike (ppb)100 1167
%R (calc)98 NA
%R (rep)98 1167
MB - Iron
Intensity - Blank (ICIS)32.944383 1217
Intensity - Target 45.025099 1345
RF 3276.992766 NA
Raw conc - calc (ppm)0.003687 NA
Raw conc - rep (ppm)0.003687 1345
Reported conc (ppb)34 U 1172
LCS - Iron
Intensity - Blank (ICIS)32.944383 1217
Intensity - Target 34147.07818 1346
RF 3276.992766 NA
Raw conc - calc (ppm)10.410195 NA
Raw conc - rep (ppm)10.410195 1346
Reported conc (ppb)10400 1178
T-914-018-11202023 ( 280-184903-3) - Iron
Intensity - Blank (ICIS)32.944383 1217
Intensity - Target 89.218051 1366
RF 3276.992766 NA
Raw conc - calc (ppm)0.017172 NA
Raw conc - rep (ppm)0.017172 1366
Reported conc (ppb)17 1157
ICP-MS Calculations
SDG 280-184903-1
Initial Calibration - Arsenic IS = Ge-72, Tune 2 (ICal only associated with MB and LCS)
Standard page Conc Target Intensity Target Intensity IS Ratio
S0 - ICIS 1596 0 156 2778973 5.61358E-05
S1 - Cal Std 1598 100 58470 2706058 0.021607076
slope 0.000215509
intercept 5.61358E-05
MB - Arsenic page 1602
Intensity - As 107
Intensity - IS 2736826 Reference IS 2778973
Ratio 3.90964E-05 IS %R (calc)98.48
Raw conc - calc (ppb)-0.079 IS %R (raw rep)98.48
Raw conc - rep (ppb)-0.079 IS %R (summary)99 p. 1211
Reported conc (ppb)2.0 U p. 1164
LCS - Arsenic page 1603
Intensity - As 23383
Intensity - IS 2744857 Reference IS 2778973
Ratio 0.008518841 IS %R (calc)98.77
Raw conc - calc (ppb)39.268 IS %R (raw rep)98.77
Raw conc - rep (ppb)39.265 IS %R (summary)99 p. 1211
Reported conc (ppb)39.3 p. 1164
Initial Calibration - Manganese IS = Ge-72, Tune 2
Standard page Conc Target Intensity Target Intensity IS Ratio
S0 - ICIS 1496 0 333 2417138 0.000137766
S1 - Cal Std 1498 100 130119 2424403 0.053670532
slope 0.000535328
intercept 0.000137766
CRI (LOQ Check) - Manganese page 1501
Intensity - Mn 1670
Intensity - IS 2406871 Reference IS 2417138
Ratio 0.000693847 IS %R (calc)99.58
Raw conc - calc (ppb)1.039 IS %R (raw rep)99.58
Raw conc - rep (ppb)1.037 IS %R (summary)100 p. 1211
Reported conc (ppb)1.04 p. 1168
Spike (ppb)1.00 p. 1168
%R (calc)104 NA
%R (rep)104 p. 1168
T-914-018-11202023 ( 280-184903-3) - Manganese p. 1583
Intensity - Mn 24582
Intensity - IS 2756434 Reference IS 2417138
Ratio 0.008918044 IS %R (calc)114.04
Raw conc - calc (ppb)16.402 IS %R (raw rep)114.04
Raw conc - rep (ppb)16.405 IS %R (summary)114 p. 1211
Reported conc (ppb)16 p. 1142
Sulfate Calculations
SDG 280-184903-1
Concentrations in mg/L
Initial Calibration
Instrument WC_IonChrom14
Analyzed 12/06/2023
Summary p. 1650
Raw Data pp. 1693-1706
Sulfate
Calibration:Linear
Weighting:1/x
CF=Ax / Cx Conc calc = (A[x]-b)/m
Lab Sample ID Analyte Conc
[Cx]
Analyte Resp
A[x]Calculated CF Reported CF Weighting (1/x)Conc (calc)Conc (rep)
STD1 0.5 7323948 14647896.0000 NR 2.0000 0.6003 0.6003
STD2 1 9919518 9919518.0000 NR 1.0000 0.8384 0.8384
STD3 2.5 25993761 10397504.4000 NR 0.4000 2.31 2.31
STD4 5 55261662 11052332.4000 NR 0.2000 5.00 5.00
STD5 60 678260425 11304340.4167 NR 0.01667 62.1 62.1
STD6 120 1342008054 11183400.4500 NR 0.00833 123.0 123.0
STD7 200 2127701055 10638505.2750 NR 0.00500 195.1 195.1
Weighted Average 1.928374656 21802616.24 n=7
p=2
m (calculated)m (reported)b (calculated)b (reported)r (calc)r (reported)RSE (calculated)RSE (reported)
10902357 10900000 778787 779000 0.9996 0.9995 12.2 NR
ICV and CCV Response Conc (calc)Conc (rep)Spike %R (calc)%R (rep)Summary Page Raw Data Pages
ICV 280-636345/9 1114405417 102.1 102.1 100 102 102 1636 1706-1707
CCV 280-637042/1 1124911409 103.1 103.1 100 103 103 1638 1712-1713
MS/MSD Response Conc (calc)Conc (rep)Parent (calc)Parent (rep)Spike %R (calc)%R (Rep)RPD (calc)RPD (rep)Summary Page Raw Data Pages
Parent Sample T-914-017-11202023
280-184903-1 (parent)221113212 20.2 20.2 NA NA NA NA NA NA NA 1630 1724-1725
280-184903-1MS 820610643 75.2 75.2 20.2 20 50 110 110 NA NA 1641 1728-1729
280-184903-1MSD 802972635 73.6 73.6 20.2 20 50 107 107 2 2 1642 1730-1731
Method Blank Response Conc-raw (calc)Conc-raw (rep)Conc-summary (rep)Summary Page Raw Data Pages
MB 280-637042/6 696150 -0.007580 -0.007580 2.5 U 1640 1722-1723
Nitrate-Nitrite ICal Calculations
SDG 280-184903-1
Concentrations in mg/L
Initial Calibration
Instrument B918837629
Analyzed 12/12/2023
Summary p. 1691-1692
Run raw data pp. 1688-1691
Nitrate-Nitrite
Calibration:Quadratic
Weighting:None
File ID Analyte Resp Analyte Conc conc^2 Weighting (none)Resp (calc)Conc (calc)Conc (rep)
Cal 0.00 STD1 273.6 0 0 NA 1709.0290 -0.0114 -0.0114
Cal 0.05 STD2 6127 0.05 0.0025 NA 7994.2856 0.0351 0.0351
Cal 0.1 STD3 12122.3 0.1 0.01 NA 14278.6206 0.0828 0.0828
Cal 0.5 STD4 63890.5 0.5 0.25 NA 64520.1222 0.4950 0.4950
Cal 1.0 STD5 129813.3 1 1 NA 127239.0542 1.0205 1.0205
Cal 2.5 STD6 325647.5 2.5 6.25 NA 314842.8841 2.5866 2.5866
Cal 5.0 STD7 616884.7 5 25 NA 625672.7129 4.9291 4.9291
Cal 10.0 STD8 1241918.1 10 100 NA 1240420.2914 10.0123 10.0123
x = ay^2 + by + c
x = response, y = concentration n=7
p=3
c (calculated)c (reported)r2 (calc)r2 (reported)RSE (calculated)RSE (reported)
1.71E+03 1.71E+03 0.99984 0.99984 17.8 NR Does not include STD1, which causes a divide by 0 error
b (calculated)b (reported)
1.26E+05 1.26E+05
a (calculated)a (reported)
-1.84E+02 -1.84E+02
Standard Response Conc (calc)Conc (raw-rep)Conc (rep)Spike %R (calc)%R (rep)Summary Page Raw Data Pages
ICV 280-637162/13 626376.1 5.0057 5.0057 5.01 5.00 100 100 1634 1688
CCV 280-637162/33 641162.2 5.1251 5.1251 5.13 5.00 103 103 1634 1689
Method Blank Response Conc-raw (calc)Conc-raw (rep)Conc-summary (rep)Summary Page Raw Data Pages
MB 280-637042/6 0 -0.0136 ND 0.080 U 1640 1722-1723
LCS Response Conc (calc)Conc (raw-rep)Conc (rep)Spike %R (calc)%R (Rep)Summary Page Raw Data Pages
LCS 280-635572/60 636086.2 5.0841 5.0841 5.08 5.00 102 102 1644 1688
T-914-018-11202023 Response Dilution Conc (calc)Conc (raw-rep)Conc (rep)Summary Page Raw Data Pages
280-184903-3 481240.5 1 3.8360 3.8360 3.8 1631 1689

APPENDIX E.2

LABORATORY QUALITY EVALUATION REPORTS

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1.1 LABORATORY DATA QUALITY EVALUATION
This section describes the DQE process used to review and evaluate laboratory analytical data
collected between 1 January 2023 and 31 December 2023. The objective of this DQE is to provide
a professional evaluation of the analytical data packages submitted by the laboratory. The DQE
includes a review of laboratory and field quality control (QC) data, and an overall evaluation of
data labeled as usable, usable with qualification, and unusable.
1.1.1 Data Validation
The samples collected from sampling events between 1 January 2023 and 31 December 2023 were
analyzed and reported in 10 sample delivery groups (SDGs). Eurofins TestAmerica Laboratories
in Denver, Colorado analyzed all SDGs. All analytical results generated from samples collected
between 1 January 2023 and 31 December 2023 were validated by E-Lab Consultants and
secondarily reviewed by HGL Chemists to EPA Stage 2B requirements in accordance with the
Final Basewide Uniform Federal Policy (UFP)-Quality Assurance Project Plan (QAPP) (HGL-
APTIM JV, 2022). Stage 2B validation includes a verification of sample delivery and condition,
laboratory QC analyses, and instrumental QC analyses. These samples were analyzed in
accordance with the approved U.S. Department of Defense (DoD) Quality Systems Manual for
Environmental Laboratories Version 5.4 (DoD, 2021) or Version 6.0 (for SDGs validated after its
release) and the analytical methods specified for the analytes requested on the CoC documentation.
Note: Two SDGs were chosen for a Full 100% Level IV validation (This meets the 10%
requirement for Level IV validation for this set of SDGs listed below). SDGs 280-179151-1 and
280-184903-1 were chosen, completed, with no additional qualifiers added. This DQE is
conducted per the analyses requested on the CoC in accordance with the following guidance
documents:
• General Data Validation Guidelines, November 2019, Revision 1 (DoD, 2019);
• Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund
Use (EPA, 2009);
• Method specified for analysis.
Results determined to be usable or usable with qualification by a Stage 2B validation meet the
definition of definitive data and are not restricted in their use for decision making. All data
validation reports were reviewed by an HGL-APTIM JV project chemist who verified that the data
was validated in accordance with the Final Basewide UFP-QAPP (HGL-APTIM JV, 2022) and
confirmed the final qualification of all results. The Level IV validations completed on SDGs 280-
179151-1 and 280-184903-1 met the validation requirements per the QAPP with all results
reported as complete.
1.1.2 Data Quality Evaluation
During the DQE, the findings of the data validation process were reviewed to determine if the
dataset met performance criteria for precision, accuracy, representativeness, completeness,
comparability, and sensitivity (PARCCS) as described in the Final Basewide UFP-QAPP (HGL-
APTIM JV, 2022). The paragraphs below identify the number of results determined to be unusable,
those results that were usable with or without qualification, and any impacts affecting the PARCCS
associated with the dataset for that method. The validation consists of an evaluation of the case
narrative, CoC and associated laboratory sample receipt forms, proper sample preservations,
holding times, initial calibration and continuing calibration procedures and results, laboratory
control sample, and laboratory control sample duplicate (LCSD), if reported, accuracy and
precision and matrix spike (MS) and matrix spike duplicate (MSD) sample analyses, method
blanks, field blanks, and field duplicate precision.
In accordance with the Final Basewide UFP-QAPP (HGL-APTIM JV, 2022), a review of the data
was conducted independent of the laboratory. This review consisted of an evaluation of laboratory
performance criteria from the case narrative and an evaluation of the sample-specific criteria
included in the laboratory data packages analyzed in accordance with the DoD Quality Systems
Manual.
Data qualifiers may have been applied to analytical results associated with QC deficiencies. The
following are qualifiers that may have been applied:

• U: Not detected. The associated number indicates the analyte limit of detection (LOD).
• J: The analyte was detected at the reported concentration; the quantitation is an estimate.
• UJ: Not detected. The associated number indicates the analyte LOD, which may be
inaccurate.
• R: The result is rejected due to serious deficiencies in the ability to analyze the sample and
meet QC criteria.

Analytical or quality issues will be discussed in a per SDG manner; a more complete discussion
of the issues can be found in the associated validation reports.
No analytical issues requiring qualification were noted in the following SDGs: 280-179293-1, 280-
179621-1.

• SDG 280-179102-1 – Three results were qualified estimated due to re-analysis beyond
holding time. Nine results were qualified estimated due to surrogate recoveries above
control limits. Four results were qualified estimated due to MS and/or MSD recoveries
outside control limits.
• SDG 280-179151-1 – Eleven results were qualified estimated due to surrogate recoveries
above control limits.
• SDG 280-179227-1 – Two results were qualified estimated due to surrogate recoveries
above control limits. Four results were qualified estimated due to field duplicate precision
exceedances.
• SDG 280-179551-1 – Twelve results were qualified estimated due to analysis beyond
holding time. Twelve results were qualified estimated due to improper preservation. Two
results were qualified estimated due to surrogate recoveries above control limits.
• SDG 280-179568-1 – Two results were qualified estimated due to field duplicate precision
exceedances.
• SDG 280-179622-1 – Two results were qualified estimated due to surrogate recoveries
above control limits.
• SDG 280-179623-1 – Four results were qualified estimated due to surrogate recoveries
above control limits.
• SDG 280-184903-1 – Six results were qualified estimated due to analysis beyond holding
time. Two results were qualified estimated due to surrogate recoveries above control
limits. One result was qualified estimated due to MS and/or MSD recoveries outside
control limits. Two results were qualified estimated due to field duplicate precision
exceedances.
1.1.3 Overall Assessment of Data
All projected site samples were collected for all required analytical parameters. Field sampling
completeness is 100 percent. All data points were usable, and the analytical completeness and
overall project dataset completeness is 100 percent, which meets the project overall completeness
goal of 95 percent.

APPENDIX F

WASTE DISPOSAL

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Clean Harbors Profile No. CH2731753A
WASTE MATERIAL PROFILE SHEET
Hill Air Force
Base
A. GENERAL INFORMATION
GENERATOR EPA ID #/REGISTRATION #UT0571724350
GENERATOR CODE (Assigned by Clean Harbors)
7290 Weiner Street BLDG 383 75 CEG/CEIE
GENERATOR NAME:
CITY STATE/PROVINCE
Hill AFB
ZIP/POSTAL CODE 84056
PHONE:[phone]
UTHI22180
ADDRESS
ZIP/POSTAL CODE
CUSTOMER CODE (Assigned by Clean Harbors)
ADDRESS
CUSTOMER NAME:
CITY STATE/PROVINCEReston VA 20190
HGL-Aptim Joint Venture LLC
11107 Sunset Hills Road Suite 400A
HG1145
B. WASTE DESCRIPTION
WASTE DESCRIPTION:Soil from drilling operations at Hill AFB
PROCESS GENERATING WASTE:
IS THIS WASTE CONTAINED IN SMALL PACKAGING CONTAINED WITHIN A LARGER SHIPPING CONTAINER ?
From drilling operations at Hill AFB
No
C. PHYSICAL PROPERTIES (at 25C or 77F)
PHYSICAL STATE
SOLID WITHOUT FREE LIQUID
POWDER
MONOLITHIC SOLID
LIQUID WITH NO SOLIDS
LIQUID/SOLID MIXTURE
% FREE LIQUID
% SETTLED SOLID
% TOTAL SUSPENDED SOLID
SLUDGE
GAS/AEROSOL
% BY VOLUME (Approx.)
NUMBER OF PHASES/LAYERS
TOP
MIDDLE
BOTTOM
321 0.00
0.00
0.00
ODOR
NONE
MILD
STRONG
Describe:
BOILING POINT ºF (ºC)
<= 95 (<=35)
95 - 100 (35-38)
101 - 129 (38-54)
>= 130 (>54)
COLOR
Varies
VISCOSITY (If liquid present)
1 - 100 (e.g. Water)
101 - 500 (e.g. Motor Oil)
501 - 10,000 (e.g. Molasses)
> 10,000
TOTAL ORGANIC
CARBON
<= 1%
1-9%
>= 10%
< 140 (<60)
140-200 (60-93)
> 200 (>93)
MELTING POINT ºF (ºC)
FLASH POINT ºF (ºC)
< 73 (<23)
73 - 100 (23-38)
101 -140 (38-60)
141 -200 (60-93)
> 200 (>93)
SPECIFIC GRAVITY
< 0.8 (e.g. Gasoline)
0.8-1.0 (e.g. Ethanol)
1.0 (e.g. Water)
> 1.2 (e.g. Methylene Chloride)
1.0-1.2 (e.g. Antifreeze)
pH
2.1 - 6.9
<= 2
7 (Neutral)
7.1 - 12.4
>= 12.5
BTU/LB (MJ/kg)
< 2,000 (<4.6)
2,000-5,000 (4.6-11.6)
5,000-10,000 (11.6-23.2)
> 10,000 (>23.2)
Actual:
ASH
< 0.1
0.1 - 1.0
1.1 - 5.0
5.1 - 20.0
> 20
Unknown
D. COMPOSITION
DOES THIS WASTE CONTAIN ANY HEAVY GAUGE METAL DEBRIS OR OTHER LARGE OBJECTS (EX., METAL PLATE OR PIPING >1/4” THICK OR
>12” LONG, METAL REINFORCED HOSE >12” LONG, METAL WIRE >12” LONG, METAL VALVES, PIPE FITTINGS, CONCRETE REINFORCING BAR OR
PIECES OF CONCRETE >3”)?
YES NO
If yes, describe, including dimensions:
(List the complete composition of the waste, include any inert components and/or debris. Ranges for individual components are acceptable. If a trade name is used,
please supply an MSDS. Please do not use abbreviations.)
CHEMICAL MIN --MAX UOM
BARIUM (TCLP) 0.0000000 --1000.00000
00
PPB
CADMIUM (TCLP) 0.0000000 --5.0000000 PPB
SOIL 99.0000000 --100.0000000 %
DOES THIS WASTE CONTAIN ANY METALS IN POWDERED OR OTHER FINELY DIVIDED FORM?YES NO
DOES THIS WASTE CONTAIN OR HAS IT CONTACTED ANY OF THE FOLLOWING; ANIMAL WASTES, HUMAN BLOOD, BLOOD PRODUCTS, BODY
FLUIDS, MICROBIOLOGICAL WASTE, PATHOLOGICAL WASTE, HUMAN OR ANIMAL DERIVED SERUMS OR PROTEINS OR ANY OTHER
POTENTIALLY INFECTIOUS MATERIAL?
YES NO
I acknowledge that this waste material is neither infectious nor does it contain any organism known to be a threat to human health. This certification is
based on my knowledge of the material. Select the answer below that applies:
The waste was never exposed to potentially infectious material.YES NO
Chemical disinfection or some other form of sterilization has been applied to the waste.YES NO
I ACKNOWLEDGE THAT THIS PROFILE MEETS THE CLEAN HARBORS BATTERY PACKAGING REQUIREMENTS.YES NO
I ACKNOWLEDGE THAT MY FRIABLE ASBESTOS WASTE IS DOUBLE BAGGED AND WETTED.YES NO
SPECIFY THE SOURCE CODE ASSOCIATED WITH THE
WASTE.
SPECIFY THE FORM CODE ASSOCIATED WITH THE WASTE.G09 W301
Report Printed On : Tuesday, March 19, 2024 /WINWEB/Profile\Waste Profile.rdl Page 1 of 4
Clean Harbors Profile No. CH2731753A
If constituent concentrations are based on analytical testing, analysis must be provided. Please attach document(s) using the link on the Submit tab.
TestingKnowledgeAre these values based on testing or knowledge?
E. CONSTITUENTS
OTHER CONSTITUENTS MAX UOM NOT
APPLICABLE
BROMINE
CHLORINE
FLUORINE
IODINE
SULFUR
POTASSIUM
SODIUM
AMMONIA
CYANIDE AMENABLE
CYANIDE REACTIVE
CYANIDE TOTAL
SULFIDE REACTIVE
VOLATILE COMPOUNDS
D018 BENZENE 0.5
D019 CARBON TETRACHLORIDE 0.5
D021 CHLOROBENZENE 100.0
D022 CHLOROFORM 6.0
D028 1,2-DICHLOROETHANE 0.5
D029 1,1-DICHLOROETHYLENE 0.7
D035 METHYL ETHYL KETONE 200.0
D039 TETRACHLOROETHYLENE 0.7
D040 TRICHLOROETHYLENE 0.5
D043 VINYL CHLORIDE 0.2
SEMI-VOLATILE COMPOUNDS
D023 o-CRESOL 200.0
D024 m-CRESOL 200.0
D025 p-CRESOL 200.0
D026 CRESOL (TOTAL)200.0
D027 1,4-DICHLOROBENZENE 7.5
D030 2,4-DINITROTOLUENE 0.13
D032 HEXACHLOROBENZENE 0.13
D033 HEXACHLOROBUTADIENE 0.5
D034 HEXACHLOROETHANE 3.0
D036 NITROBENZENE 2.0
D037 PENTACHLOROPHENOL 100.0
D038 PYRIDINE 5.0
D041 2,4,5-TRICHLOROPHENOL 400.0
D042 2,4,6-TRICHLOROPHENOL 2.0
PESTICIDES AND HERBICIDES
D012 ENDRIN 0.02
D013 LINDANE 0.4
D014 METHOXYCHLOR 10.0
D015 TOXAPHENE 0.5
D016 2,4-D 10.0
D017 2,4,5-TP (SILVEX)1.0
D020 CHLORDANE 0.03
D031 HEPTACHLOR (AND ITS EPOXIDE)0.008
HOCs
NONE
< 1000 PPM
>= 1000 PPM
PCBs
NONE
< 50 PPM
>=50 PPM
IF PCBS ARE PRESENT, IS THE
WASTE REGULATED BY TSCA 40
CFR 761?
YES NO
Please indicate which constituents below apply. Concentrations must be entered when applicable to assist in accurate review and expedited
approval of your waste profile. Please note that the total regulated metals and other constituents sections require answers.
ADDITIONAL HAZARDS
DOES THIS WASTE HAVE ANY UNDISCLOSED HAZARDS OR PRIOR INCIDENTS ASSOCIATED WITH IT, WHICH COULD AFFECT THE WAY IT SHOULD BE HANDLED?
YES NO (If yes, explain)
DEA REGULATED SUBSTANCES EXPLOSIVE FUMING
NONE OF THE ABOVEPOLYMERIZABLERADIOACTIVEREACTIVE MATERIAL
RCRA REGULATED METALS REGULATORY
LEVEL (mg/l)
TCLP
mg/l
TOTAL UOM NOT APPLICABLE
D004 ARSENIC 5.0 0.0240 Trace
D005 BARIUM 100.0 1.0000 Trace
D006 CADMIUM 1.0 0.0067 Trace
D007 CHROMIUM 5.0
D008 LEAD 5.0
D009 MERCURY 0.2
D010 SELENIUM 1.0
D011 SILVER 5.0
CHOOSE ALL THAT APPLY
OSHA REGULATED CARCINOGENS
Report Printed On : Tuesday, March 19, 2024 /WINWEB/Profile\Waste Profile.rdl Page 2 of 4
Clean Harbors Profile No. CH2731753A
G. DOT/TDG INFORMATION
DOT/TDG PROPER SHIPPING NAME:
NON HAZARDOUS, NON D.O.T. REGULATED
F. REGULATORY STATUS
YES NO IF THIS IS A US EPA HAZARDOUS WASTE, DOES THIS WASTE STREAM CONTAIN BENZENE?
YES NO DO ANY CANADIAN PROVINCIAL WASTE CODES APPLY?
YES NO IS THE GENERATOR OF THE WASTE CLASSIFIED AS A VERY SMALL QUANTITY GENERATOR (VSQG) OR A STATE EQUIVALENT DESIGNATION?
YES NO IS THIS WASTE STREAM PROHIBITED FROM INCINERATION BASED ON THE INORGANIC METAL BEARING WASTE PROHIBITION FOUND AT 40 CFR
268.3(C)?
Pharmaceuticals production (subpart GGG)Hazardous Organic NESHAP (HON) rule (subpart G)
YES NO IS THE WASTE SUBJECT TO ONE OF THE FOLLOWING NESHAP RULES?
YES NO IS THIS MATERIAL GOING TO BE MANAGED AS A RCRA EXEMPT COMMERCIAL PRODUCT, WHICH IS FUEL (40 CFR 261.2 (C)(2)(II))?
Texas Waste Code
YES NO DO ANY STATE WASTE CODES APPLY?
YES NO USEPA HAZARDOUS WASTE?
NO IS THIS WASTE PROHIBITED FROM LAND DISPOSAL WITHOUT FURTHER TREATMENT PER 40 CFR PART 268?
LDR CATEGORY:
VARIANCE INFO:
YES NO IS THIS A UNIVERSAL WASTE?
YES NO DOES TREATMENT OF THIS WASTE GENERATE A F006 OR F019 SLUDGE?
YES NO
YES NO DOES THE WASTE CONTAIN GREATER THAN 20% OF ORGANIC CONSTITUENTS WITH A VAPOR PRESSURE >= .3KPA (.044 PSIA)?
YES NO DOES THIS WASTE CONTAIN AN ORGANIC CONSTITUENT WHICH IN ITS PURE FORM HAS A VAPOR PRESSURE > 76.6 KPA (11.1 PSIA)?
NO IS THIS CERCLA REGULATED (SUPERFUND ) WASTE ? YES
YES
DOES THIS WASTE CONTAIN VOC'S IN CONCENTRATIONS >=500 PPM?
Not subject to LDR
Megagram/year (1 Mg = 2,200 lbs)
Describe the knowledge :
Knowledge TestingThe basis for this determination is: Knowledge of the Waste Or Test Data
What is the TAB quantity for your facility?
YES NO Is the generating source of this waste stream a facility with Total Annual Benzene (TAB) >10 Mg/year?
YES NO Does the waste stream come from a facility with one of the SIC codes listed under benzene NESHAP or is this waste regulated under the benzene
NESHAP rules because the original source of the waste is from a chemical manufacturing, coke by-product recovery, or petroleum refinery process?
YES NO IS THIS WASTE STREAM "USED OIL" WHICH IS TO BE MANAGED UNDER 40 CFR PART 279 - STANDARDS FOR THE MANAGEMENT OF USED OIL?
H. TRANSPORTATION REQUIREMENTS
CONTAINER TYPE:
STORAGE CAPACITY:
CONTAINERS/SHIPMENT
CONTAINERIZED
0-0
DRUM
OTHER:
CUBIC YARD BOX
BOX|CARTON|CASEPORTABLE TOTE TANK
DRUM SIZE:
BULK LIQUID
GALLONS/SHIPMENT:GAL.0 Min -0 Max
ESTIMATED SHIPMENT FREQUENCY variesOTHERYEARLYQUARTERLYMONTHLYWEEKLYONE TIME
TONS/YARDS/SHIPMENT:
SHIPMENT UOM:TON YARD
BULK SOLID
12.00 Min - 16.00 Max
I. SPECIAL REQUEST
COMMENTS OR REQUESTS:
CBP-Grassy Mountain
GENERATOR'S CERTIFICATION
I certify that I am authorized to execute this document as an authorized agent. I hereby certify that all information submitted in this and attached documents is correct to the best of my knowledge.I also certify that any
samples submitted are representative of the actual waste.If Clean Harbors discovers a discrepancy during the approval process, Generator grants Clean Harbors the authority to amend the profile, as Clean Harbors
deems necessary, to reflect the discrepancy.
AUTHORIZED SIGNATURE NAME (PRINT)TITLE DATE
Report Printed On : Tuesday, March 19, 2024 /WINWEB/Profile\Waste Profile.rdl Page 3 of 4
Clean Harbors Profile No. CH2731753A
Addendum
D. COMPOSITION
F. REGULATORY STATUS
Report Printed On : Tuesday, March 19, 2024 /WINWEB/Profile\Waste Profile.rdl Page 4 of 4
ANALYTICAL REPORT
PREPARED FOR
Attn: Jennifer Chandler
HydroGeoLogic Inc
14142 Denver West Parkway
Suite 225
Lakewood CO 80401
Generated 12/4/2023 12:26 PM
JOB DESCRIPTION
Hill AFB, UT - ST071
JOB NUMBER
280-184424-1
See page two for job notes and contact information.
Arvada CO 80002
4955 Yarrow Street
Eurofins Denver
Page 1 of 1261
Eurofins Denver
Eurofins Denver is a laboratory within TestAmerica Laboratories, Inc., a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager.
Authorization
Generated
12/4/2023 12:26 PM
Authorized for release by
Shelby R McCabe, Project Manager I
[e-mail]
303 736-0165
Page 2 of 1261
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29
Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32
COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .88
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .363
GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .363
Method 8260D DOD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .363
Method 8260D DOD QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .364
Method 8260D DOD Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .370
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .374
Method 8260D DOD ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .374
Method 8260D DOD CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .516
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .537
Page 3 of 1261
Table of Contents
Method 8260D DOD Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .537
Method 8260D DOD Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .546
Method 8260D DOD LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .553
Method 8260D DOD Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .565
Method 8260D DOD Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .567
GC/MS Semi VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .577
8270E_DOD5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .577
8270E_DOD5 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .578
8270E_DOD5 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .584
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .594
8270E_DOD5 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .594
8270E_DOD5 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .725
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .749
8270E_DOD5 Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .749
8270E_DOD5 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .763
8270E_DOD5 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .764
8270E_DOD5 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .765
8270E_DOD5 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .767
Inorganic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .781
Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .781
Met Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .782
Met Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .783
Met QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .784
Met ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .784
Met CRQL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .788
Met Blanks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .790
Page 4 of 1261
Table of Contents
Met ICSA/ICSAB . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .795
Met MS/MSD/PDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .797
Met LCS/LCSD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .800
Met Serial Dilution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .802
Met MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .803
Met IECF . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .807
Met Linear Ranges . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .813
Met Preparation Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .814
Met Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .816
Met Internal Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .827
Met Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .829
Met Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .872
General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1168
Gen Chem Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1169
Gen Chem Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1171
Gen Chem QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1174
Gen Chem ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1174
Gen Chem Blanks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1177
Gen Chem MS/MSD/PDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1179
Gen Chem Duplicates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1181
Gen Chem LCS/LCSD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1182
Gen Chem MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1188
Gen Chem Preparation Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1198
Gen Chem Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1200
Gen Chem Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1205
Gen Chem Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1215
Page 5 of 1261
Table of Contents
Subcontracted Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1257
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . .1258
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1259
Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1260
Page 6 of 1261
Definitions/Glossary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Qualifiers
GC/MS VOA
Qualifier Description
U Undetected at the Limit of Detection.
Qualifier
GC/MS Semi VOA
Qualifier Description
M Manual integrated compound.
Qualifier
Q One or more quality control criteria failed.
U Undetected at the Limit of Detection.
Metals
Qualifier Description
J Estimated: The analyte was positively identified; the quantitation is an estimation
Qualifier
U Undetected at the Limit of Detection.
General Chemistry
Qualifier Description
HF Parameter with a holding time of 15 minutes. Test performed by laboratory at client's request. Sample was analyzed outside of hold time.
Qualifier
U Undetected at the Limit of Detection.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Denver
Page 7 of 1261
CASE NARRATIVE
Client: HydroGeoLogic Inc
Project: Hill AFB, UT - ST071
Report Number: 280-184424-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no
problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control
limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of
the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples,
the reporting limits are adjusted relative to the dilution required.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the
individual sections below.
RECEIPT
The sample was received on 11/10/2023 4:30 PM. Unless otherwise noted below, the sample arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.7º C.
TCLP VOLATILE ORGANIC COMPOUNDS (GC/MS)
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for TCLP volatile organic compounds (GC/MS) in accordance with
1311/8260D. The samples were leached on 11/14/2023 and analyzed on 11/18/2023.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TCLP METALS (ICP)
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for TCLP Metals (ICP) in accordance with SW 846 1311/6010D. The
samples were leached on 11/17/2023, prepared on 11/20/2023 and analyzed on 11/21/2023.
Barium was detected in method blank LB 280-634317/1-B at a level that was below half the LOQ. The value should be considered an
estimate, and has been flagged J.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TCLP MERCURY
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for TCLP mercury in accordance with SW-846 1311/7470. The samples
were leached on 11/17/2023, prepared on 11/27/2023 and analyzed on 11/28/2023.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TCLP SEMI VOLATILE ORGANIC COMPOUNDS
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for TCLP semi volatile organic compounds in accordance with SW-846
1311/8270E. The samples were leached on 11/17/2023, prepared on 11/22/2023 and analyzed on 11/28/2023.
Pyridine failed the recovery criteria low for LCS 280-634317/2-F. Refer to the QC report for details. Pyridine has been identified as a poor
performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
IGNITABILITY FOR SOLIDS
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for ignitability for solids in accordance with EPA SW-846 Method 1030.
The samples were analyzed on 11/14/2023.
The following sample did not ignite: ST071-SoilIDW-11092023 (280-184424-1); therefore, an ignitability value could not be obtained. The
result has been reported as "No Burn" (NB).
No samples ignited, therefore, there were no sample duplicates analyzed. An LCSD was analyzed which met acceptability criteria.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Page 8 of 1261
TOTAL CYANIDE
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for Total Cyanide in accordance with 9012B. The samples were
prepared on 11/14/2023 and analyzed on 11/15/2023.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TOTAL SULFIDE
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for total sulfide in accordance with EPA SW-846 Method 9034. The
samples were prepared and analyzed on 11/13/2023.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
CORROSIVITY (PH)
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for Corrosivity (pH) in accordance with EPA SW-846 Method 9045D.
The samples were leached on 12/02/2023 and analyzed on 12/03/2023.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
PERCENT SOLIDS
Sample ST071-SoilIDW-11092023 (280-184424-1) was analyzed for percent solids in accordance with ASTM D2216-90. The samples
were analyzed on 11/16/2023.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Page 9 of 1261
Detection Summary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Client Sample ID: ST071-SoilIDW-11092023 Lab Sample ID: 280-184424-1
DLLOQ
ug/L2275Arsenic
LOD
71
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
TCLP1J246010D
ug/L504.1Barium10 TCLP110006010D
ug/L250.65Cadmium2.3 TCLP16.7 J 6010D
mm/secIgnitability2.20 Total/NA1NB1030
SU0.1 0.1pH adj. to 25 deg C 0.1 Soluble19.2 HF 9045D
Degrees C1.0 1.0Temperature1.0 Soluble122.3 HF 9045D
Eurofins Denver
This Detection Summary does not include radiochemical test results.
Page 10 of 1261
Client Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: SW846 8260D - Volatile Organic Compounds (GC/MS) - TCLP
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
8.0 U 10 3.1 ug/L 111/18/23 00:578.0
Analyte Dil FacAnalyzedUnitDResultQualifier
Benzene
111/18/23 00:57ug/L60120150U1202-Butanone (MEK)
111/18/23 00:57ug/L5.78.010U8.0Carbon tetrachloride
111/18/23 00:57ug/L4.28.010U8.0Chlorobenzene
111/18/23 00:57ug/L3.68.010U8.0Chloroform
111/18/23 00:57ug/L5.48.010U8.01,2-Dichloroethane
111/18/23 00:57ug/L2.38.010U8.01,1-Dichloroethene
111/18/23 00:57ug/L4.08.010U8.0Tetrachloroethene
111/18/23 00:57ug/L3.04.010U4.0Trichloroethene
111/18/23 00:57ug/L5.11020U10Vinyl chloride
Toluene-d8 (Surr)101 78 -120 11/18/23 00:57 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
1,2-Dichloroethane-d4 (Surr)114 11/18/23 00:57 164-129
4-Bromofluorobenzene (Surr)98 11/18/23 00:57 178-121
Dibromofluoromethane (Surr)110 11/18/23 00:57 179-119
Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS) - TCLP
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
3.2 U 4.0 1.4 ug/L 111/28/23 11:103.2
Analyte Dil FacAnalyzedUnitDResultQualifier
1,4-Dichlorobenzene
111/28/23 11:10ug/L1.48.010U8.02,4-Dinitrotoluene
111/28/23 11:10ug/L0.868.010U8.0Hexachlorobenzene
111/28/23 11:10ug/L2.98.010U8.0Hexachlorobutadiene
111/28/23 11:10ug/L4.58.010U M8.0Hexachloroethane
111/28/23 11:10ug/L0.778.010U8.02-Methylphenol
111/28/23 11:10ug/L0.808.010U8.03 & 4 Methylphenol
111/28/23 11:10ug/L1.38.010U8.0Nitrobenzene
111/28/23 11:10ug/L204850U48Pentachlorophenol
111/28/23 11:10ug/L184850U Q48Pyridine
111/28/23 11:10ug/L0.908.010U8.02,4,5-Trichlorophenol
111/28/23 11:10ug/L0.718.010U8.02,4,6-Trichlorophenol
2-Fluorobiphenyl 76 44 -119 11/22/23 11:45 11/28/23 11:10 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
2-Fluorophenol (Surr)75 11/22/23 11:45 11/28/23 11:10 119-119
2,4,6-Tribromophenol (Surr)82 11/22/23 11:45 11/28/23 11:10 143-140
Nitrobenzene-d5 (Surr)85 11/22/23 11:45 11/28/23 11:10 144-120
Phenol-d5 (Surr)75 11/22/23 11:45 11/28/23 11:10 110-115
Terphenyl-d14 (Surr)111 11/22/23 11:45 11/28/23 11:10 150-134
Method: SW846 6010D - Metals (ICP) - TCLP
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
24 J 75 22 ug/L 111/21/23 07:0171
Analyte Dil FacAnalyzedUnitDResultQualifier
Arsenic
Eurofins Denver
Page 11 of 1261
Client Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: SW846 6010D - Metals (ICP) - TCLP (Continued)
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
1000 50 4.1 ug/L 111/21/23 07:0110
Analyte Dil FacAnalyzedUnitDResultQualifier
Barium
111/21/23 07:01ug/L0.652.325J6.7Cadmium
111/21/23 07:01ug/L3.31350U13Chromium
111/21/23 07:01ug/L143845U38Lead
111/21/23 07:01ug/L3295100U95Selenium
111/21/23 07:01ug/L9.83050U30Silver
Method: SW846 7470A - Mercury (CVAA) - TCLP
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
0.080 U 0.20 0.061 ug/L 111/28/23 00:260.080
Analyte Dil FacAnalyzedUnitDResultQualifier
Mercury
General Chemistry
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
NB mm/sec 111/14/23 14:202.20
Analyte Dil FacAnalyzedUnitDResultQualifier
Ignitability (SW846 1030)
111/16/23 13:49%0.10.10.116.4Percent Moisture (ASTM D 2216)
111/16/23 13:49%0.10.10.183.6Percent Solids (ASTM D 2216)
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Percent Solids: 83.6Date Received: 11/10/23 16:30
LOQ DLLOD
0.48 U 0.60 0.29 mg/Kg ☼111/15/23 17:440.48
Analyte Dil FacAnalyzedUnitDResultQualifier
Cyanide, Total (EPA 9012B)
111/13/23 15:18☼mg/Kg4.99.211U9.2Sulfide (SW846 9034)
General Chemistry - Soluble
Lab Sample ID: 280-184424-1Client Sample ID: ST071-SoilIDW-11092023
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
LOQ DLLOD
9.2 HF 0.1 0.1 SU 112/03/23 22:250.1
Analyte Dil FacAnalyzedUnitDResultQualifier
pH adj. to 25 deg C (SW846 9045D)
112/03/23 22:25Degrees C1.01.01.0HF22.3Temperature (SW846 9045D)
Eurofins Denver
Page 12 of 1261
Default Detection Limits
Client: HydroGeoLogic Inc Job ID: 280-184424-1
Project/Site: Hill AFB, UT - ST071
Method: 8260D - Volatile Organic Compounds (GC/MS) - TCLP
Leach: 1311
101,1-Dichloroethene ug/L
Analyte UnitsDLLOQ
2.3
101,2-Dichloroethane ug/L5.4
1502-Butanone (MEK)ug/L60
10Benzene ug/L3.1
10Carbon tetrachloride ug/L5.7
10Chlorobenzene ug/L4.2
10Chloroform ug/L3.6
10Tetrachloroethene ug/L4.0
10Trichloroethene ug/L3.0
20Vinyl chloride ug/L5.1
Method: 8270E - Semivolatile Organic Compounds (GC/MS) - TCLP
Prep: 3510C
Leach: 1311
4.01,4-Dichlorobenzene ug/L
Analyte UnitsDLLOQ
1.4
102,4,5-Trichlorophenol ug/L0.90
102,4,6-Trichlorophenol ug/L0.71
102,4-Dinitrotoluene ug/L1.4
102-Methylphenol ug/L0.77
103 & 4 Methylphenol ug/L0.80
10Hexachlorobenzene ug/L0.86
10Hexachlorobutadiene ug/L2.9
10Hexachloroethane ug/L4.5
10Nitrobenzene ug/L1.3
50Pentachlorophenol ug/L20
50Pyridine ug/L18
Method: 6010D - Metals (ICP) - TCLP
Prep: 3010A
Leach: 1311
75Arsenic ug/L
Analyte UnitsDLLOQ
22
50Barium ug/L4.1
25Cadmium ug/L0.65
50Chromium ug/L3.3
45Lead ug/L14
100Selenium ug/L32
50Silver ug/L9.8
Method: 7470A - Mercury (CVAA) - TCLP
Prep: 7470A
Leach: 1311
0.20Mercury ug/L
Analyte UnitsDLLOQ
0.061
General Chemistry
0.1Percent Moisture %
Analyte UnitsDLLOQ
0.1
0.1Percent Solids %0.1
Eurofins Denver
Page 13 of 1261
Default Detection Limits
Client: HydroGeoLogic Inc Job ID: 280-184424-1
Project/Site: Hill AFB, UT - ST071
General Chemistry
Prep: 9012B
0.50Cyanide, Total mg/Kg
Analyte UnitsDLLOQ
0.24
General Chemistry
Prep: 9030B
10Sulfide mg/Kg
Analyte UnitsDLLOQ
4.3
General Chemistry - Soluble
Leach: DI Leach
0.1pH adj. to 25 deg C SU
Analyte UnitsDLLOQ
0.1
1.0Temperature Degrees C1.0
Eurofins Denver
Page 14 of 1261
Surrogate Summary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 8260D - Volatile Organic Compounds (GC/MS)
Prep Type: TCLPMatrix: Solid
Lab Sample ID Client Sample ID (78-120)(64-129)(78-121)(79-119)
TOL DCA BFB DBFM
101 114 98 110280-184424-1
Percent Surrogate Recovery (Acceptance Limits)
ST071-SoilIDW-11092023
102 116 98 111LB 280-633952/1-A Method Blank
101 113 99 110LCS 280-633952/2-A Lab Control Sample
101 112 97 111LCSD 280-633952/3-A Lab Control Sample Dup
Surrogate Legend
TOL = Toluene-d8 (Surr)
DCA = 1,2-Dichloroethane-d4 (Surr)
BFB = 4-Bromofluorobenzene (Surr)
DBFM = Dibromofluoromethane (Surr)
Method: 8270E - Semivolatile Organic Compounds (GC/MS)
Prep Type: TCLPMatrix: Solid
Lab Sample ID Client Sample ID (44-119)(19-119)(43-140)(44-120)(10-115)(50-134)
FBP 2FP TBP NBZ PHL TPHL
76 75 82 85 75 111280-184424-1
Percent Surrogate Recovery (Acceptance Limits)
ST071-SoilIDW-11092023
84 70 79 6287 109LB 280-634317/1-F Method Blank
89 78 89 7890 96LCS 280-634317/2-F Lab Control Sample
Surrogate Legend
FBP = 2-Fluorobiphenyl
2FP = 2-Fluorophenol (Surr)
TBP = 2,4,6-Tribromophenol (Surr)
NBZ = Nitrobenzene-d5 (Surr)
PHL = Phenol-d5 (Surr)
TPHL = Terphenyl-d14 (Surr)
Eurofins Denver
Page 15 of 1261
QC Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 8260D - Volatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: LB 280-633952/1-A
Matrix: Solid Prep Type: TCLP
Analysis Batch: 634482
DLLOQ
LBLB
LOD
Benzene 8.0 U 10 3.1 ug/L 11/17/23 20:46 18.0
Analyte Dil FacAnalyzedDUnitResultQualifier
111/17/23 20:46ug/L60150U1202-Butanone (MEK)120
111/17/23 20:46ug/L5.710U8.0Carbon tetrachloride 8.0
111/17/23 20:46ug/L4.210U8.0Chlorobenzene 8.0
111/17/23 20:46ug/L3.610U8.0Chloroform 8.0
111/17/23 20:46ug/L5.410U8.01,2-Dichloroethane 8.0
111/17/23 20:46ug/L2.310U8.01,1-Dichloroethene 8.0
111/17/23 20:46ug/L4.010U8.0Tetrachloroethene 8.0
111/17/23 20:46ug/L3.010U4.0Trichloroethene 4.0
111/17/23 20:46ug/L5.120U10Vinyl chloride 10
Toluene-d8 (Surr)102 78 -120 11/17/23 20:46 1
LB LB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
116 11/17/23 20:46 11,2-Dichloroethane-d4 (Surr)64 -129
98 11/17/23 20:46 14-Bromofluorobenzene (Surr)78 -121
111 11/17/23 20:46 1Dibromofluoromethane (Surr)79 -119
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-633952/2-A
Matrix: Solid Prep Type: TCLP
Analysis Batch: 634482
Benzene 500 551 ug/L 110 74 -135
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
2-Butanone (MEK)2000 1930 ug/L 97 44 -150
Carbon tetrachloride 500 483 ug/L 97 67 -135
Chlorobenzene 500 486 ug/L 97 76 -135
Chloroform 500 548 ug/L 110 76 -120
1,2-Dichloroethane 500 556 ug/L 111 70 -135
1,1-Dichloroethene 500 539 ug/L 108 71 -136
Tetrachloroethene 500 505 ug/L 101 70 -135
Trichloroethene 500 482 ug/L 96 73 -135
Vinyl chloride 500 645 ug/L 129 40 -144
Toluene-d8 (Surr)78 -120
Surrogate
101
LCS LCS
Qualifier Limits%Recovery
1131,2-Dichloroethane-d4 (Surr)64 -129
994-Bromofluorobenzene (Surr)78 -121
110Dibromofluoromethane (Surr)79 -119
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-633952/3-A
Matrix: Solid Prep Type: TCLP
Analysis Batch: 634482
Benzene 500 554 ug/L 111 74 -135 0 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
2-Butanone (MEK)2000 1980 ug/L 99 44 -150 3 32
Carbon tetrachloride 500 495 ug/L 99 67 -135 2 21
Chlorobenzene 500 493 ug/L 99 76 -135 1 20
Eurofins Denver
Page 16 of 1261
QC Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 8260D - Volatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-633952/3-A
Matrix: Solid Prep Type: TCLP
Analysis Batch: 634482
Chloroform 500 549 ug/L 110 76 -120 0 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
1,2-Dichloroethane 500 563 ug/L 113 70 -135 1 20
1,1-Dichloroethene 500 545 ug/L 109 71 -136 1 20
Tetrachloroethene 500 515 ug/L 103 70 -135 2 20
Trichloroethene 500 483 ug/L 97 73 -135 0 20
Vinyl chloride 500 649 ug/L 130 40 -144 1 24
Toluene-d8 (Surr)78 -120
Surrogate
101
LCSD LCSD
Qualifier Limits%Recovery
1121,2-Dichloroethane-d4 (Surr)64 -129
974-Bromofluorobenzene (Surr)78 -121
111Dibromofluoromethane (Surr)79 -119
Method: 8270E - Semivolatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: LB 280-634317/1-F
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635266 Prep Batch: 634893
DLLOQ
LBLB
LOD
1,4-Dichlorobenzene 3.2 U 4.0 1.4 ug/L 11/28/23 10:02 13.2
Analyte Dil FacAnalyzedDUnitResultQualifier
111/28/23 10:02ug/L1.410U8.02,4-Dinitrotoluene 8.0
111/28/23 10:02ug/L0.8610U8.0Hexachlorobenzene 8.0
111/28/23 10:02ug/L2.910U8.0Hexachlorobutadiene 8.0
111/28/23 10:02ug/L4.510U8.0Hexachloroethane 8.0
111/28/23 10:02ug/L0.7710U8.02-Methylphenol 8.0
111/28/23 10:02ug/L0.8010U8.03 & 4 Methylphenol 8.0
111/28/23 10:02ug/L1.310U8.0Nitrobenzene 8.0
111/28/23 10:02ug/L2050U48Pentachlorophenol48
111/28/23 10:02ug/L1850U48Pyridine48
111/28/23 10:02ug/L0.9010U8.02,4,5-Trichlorophenol 8.0
111/28/23 10:02ug/L0.7110U8.02,4,6-Trichlorophenol 8.0
2-Fluorobiphenyl 84 44 -119 11/28/23 10:02 1
LB LB
Surrogate
11/22/23 11:45
Dil FacPreparedAnalyzedQualifierLimits%Recovery
70 11/22/23 11:45 11/28/23 10:02 12-Fluorophenol (Surr)19 -119
79 11/22/23 11:45 11/28/23 10:02 12,4,6-Tribromophenol (Surr)43 -140
87 11/22/23 11:45 11/28/23 10:02 1Nitrobenzene-d5 (Surr)44 -120
62 11/22/23 11:45 11/28/23 10:02 1Phenol-d5 (Surr)10 -115
109 11/22/23 11:45 11/28/23 10:02 1Terphenyl-d14 (Surr)50 -134
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-634317/2-F
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635266 Prep Batch: 634893
1,4-Dichlorobenzene 80.0 45.3 ug/L 57 29 -112
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
2,4-Dinitrotoluene 80.0 67.6 ug/L 85 57 -128
Eurofins Denver
Page 17 of 1261
QC Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 8270E - Semivolatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-634317/2-F
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635266 Prep Batch: 634893
Hexachlorobenzene 80.0 66.9 ug/L 84 53 -125
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Hexachlorobutadiene 80.0 47.4 ug/L 59 22 -124
Hexachloroethane 80.0 44.0 ug/L 55 21 -115
2-Methylphenol 80.0 67.5 ug/L 84 30 -117
3 & 4 Methylphenol 80.0 68.1 ug/L 85 29 -110
Nitrobenzene 80.0 68.7 ug/L 86 45 -121
Pentachlorophenol 160 148 ug/L 93 35 -138
Pyridine 160 48 U Q ug/L 5 10 -120
2,4,5-Trichlorophenol 80.0 67.9 ug/L 85 53 -123
2,4,6-Trichlorophenol 80.0 69.4 ug/L 87 50 -125
2-Fluorobiphenyl 44 -119
Surrogate
89
LCS LCS
Qualifier Limits%Recovery
782-Fluorophenol (Surr)19 -119
892,4,6-Tribromophenol (Surr)43 -140
90Nitrobenzene-d5 (Surr)44 -120
78Phenol-d5 (Surr)10 -115
96Terphenyl-d14 (Surr)50 -134
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: LB 280-634317/1-B
Matrix: Solid Prep Type: TCLP
Analysis Batch: 634762 Prep Batch: 634516
DLLOQ
LBLB
LOD
Arsenic 71 U 75 22 ug/L 11/21/23 05:08 171
Analyte Dil FacAnalyzedDUnitResultQualifier
111/21/23 05:08ug/L4.150J13.0Barium 10
111/21/23 05:08ug/L0.6525U2.3Cadmium 2.3
111/21/23 05:08ug/L3.350U13Chromium13
111/21/23 05:08ug/L1445U38Lead38
111/21/23 05:08ug/L32100U95Selenium95
111/21/23 05:08ug/L9.850U30Silver30
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-634317/2-B
Matrix: Solid Prep Type: TCLP
Analysis Batch: 634762 Prep Batch: 634516
Arsenic 8000 8340 ug/L 104 87 -113
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Barium 15000 15500 ug/L 103 88 -113
Cadmium 6000 5980 ug/L 100 88 -113
Chromium 10000 10300 ug/L 103 90 -113
Lead 10000 10700 ug/L 107 86 -113
Selenium 6000 6120 ug/L 102 83 -114
Silver 1250 1330 ug/L 106 84 -115
Eurofins Denver
Page 18 of 1261
QC Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: LB 280-634317/1-G
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635299 Prep Batch: 635179
DLLOQ
LBLB
LOD
Mercury 0.080 U 0.20 0.061 ug/L 11/28/23 00:03 10.080
Analyte Dil FacAnalyzedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-634317/2-G
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635299 Prep Batch: 635179
Mercury 5.00 5.10 ug/L 102 82 -119
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: ST071-SoilIDW-11092023Lab Sample ID: 280-184424-1 MS
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635299 Prep Batch: 635179
Mercury 0.080 U 5.00 4.98 ug/L 100 82 -119
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Client Sample ID: ST071-SoilIDW-11092023Lab Sample ID: 280-184424-1 MSD
Matrix: Solid Prep Type: TCLP
Analysis Batch: 635299 Prep Batch: 635179
Mercury 0.080 U 5.00 4.93 ug/L 99 82 -119 1 10
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Method: 1030 - Ignitability, Solids
Client Sample ID: Method BlankLab Sample ID: MB 680-808190/1
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 808190
DLLOQ
MBMB
LOD
Ignitability NB mm/sec 11/14/23 14:20 12.20
Analyte Dil FacAnalyzedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-808190/2
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 808190
Ignitability 2.68 2.681 mm/sec 100 75 -125
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-808190/14
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 808190
Ignitability 2.61 2.609 mm/sec 100 75 -125 3 10
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Eurofins Denver
Page 19 of 1261
QC Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 9012B - Cyanide, Total and/or Amenable
Client Sample ID: Method BlankLab Sample ID: MB 280-633831/4-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 634302 Prep Batch: 633831
DLLOQ
MBMB
LOD
Cyanide, Total 0.40 U 0.50 0.24 mg/Kg 11/15/23 17:42 10.40
Analyte Dil FacAnalyzedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: HLCS 280-633831/1-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 634302 Prep Batch: 633831
Cyanide, Total 17.5 17.0 mg/Kg 97 90 -110
Analyte
HLCS HLCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-633831/3-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 634302 Prep Batch: 633831
Cyanide, Total 5.00 4.27 mg/Kg 85 76 -120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Lab Control SampleLab Sample ID: LLCS 280-633831/2-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 634302 Prep Batch: 633831
Cyanide, Total 5.00 4.65 mg/Kg 93 51 -150
Analyte
LLCS LLCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: ST071-SoilIDW-11092023Lab Sample ID: 280-184424-1 MS
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 634302 Prep Batch: 633831
Cyanide, Total 0.48 U 5.96 5.33 mg/Kg 89 76 -120☼
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Client Sample ID: ST071-SoilIDW-11092023Lab Sample ID: 280-184424-1 MSD
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 634302 Prep Batch: 633831
Cyanide, Total 0.48 U 5.97 5.03 mg/Kg 84 76 -120 6 10☼
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Method: 9034 - Sulfide, Acid Soluble and Insoluble (Titrimetric)
Client Sample ID: Method BlankLab Sample ID: MB 280-633716/3-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 633717 Prep Batch: 633716
DLLOQ
MBMB
LOD
Sulfide 7.9 U 9.9 4.3 mg/Kg 11/13/23 15:18 17.9
Analyte Dil FacAnalyzedDUnitResultQualifier
Eurofins Denver
Page 20 of 1261
QC Sample Results
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method: 9034 - Sulfide, Acid Soluble and Insoluble (Titrimetric) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-633716/1-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 633717 Prep Batch: 633716
Sulfide 82.2 71.9 mg/Kg 87 35 -119
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-633716/2-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 633717 Prep Batch: 633716
Sulfide 81.6 67.3 mg/Kg 83 35 -119 7 35
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Method: 9045D - pH
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-635901/4
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 635901
pH adj. to 25 deg C 7.00 7.0 SU 100 99 -101
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: ST071-SoilIDW-11092023Lab Sample ID: 280-184424-1 DU
Matrix: Solid Prep Type: Soluble
Analysis Batch: 635901
pH adj. to 25 deg C 9.2 HF 9.3 SU 0.4 5
Analyte
DU DU
DUnitResultQualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Temperature 22.3 HF 22.3 Degrees C 0 5
Eurofins Denver
Page 21 of 1261
QC Association Summary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
GC/MS VOA
Leach Batch: 633952
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 1311280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 1311LB 280-633952/1-A Method Blank TCLP
Solid 1311LCS 280-633952/2-A Lab Control Sample TCLP
Solid 1311LCSD 280-633952/3-A Lab Control Sample Dup TCLP
Analysis Batch: 634482
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 8260D 633952280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 8260D 633952LB 280-633952/1-A Method Blank TCLP
Solid 8260D 633952LCS 280-633952/2-A Lab Control Sample TCLP
Solid 8260D 633952LCSD 280-633952/3-A Lab Control Sample Dup TCLP
GC/MS Semi VOA
Leach Batch: 634317
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 1311280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 1311LB 280-634317/1-F Method Blank TCLP
Solid 1311LCS 280-634317/2-F Lab Control Sample TCLP
Prep Batch: 634893
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 3510C 634317280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 3510C 634317LB 280-634317/1-F Method Blank TCLP
Solid 3510C 634317LCS 280-634317/2-F Lab Control Sample TCLP
Analysis Batch: 635266
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 8270E 634893280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 8270E 634893LB 280-634317/1-F Method Blank TCLP
Solid 8270E 634893LCS 280-634317/2-F Lab Control Sample TCLP
Metals
Leach Batch: 634317
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 1311280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 1311LB 280-634317/1-B Method Blank TCLP
Solid 1311LB 280-634317/1-G Method Blank TCLP
Solid 1311LCS 280-634317/2-B Lab Control Sample TCLP
Solid 1311LCS 280-634317/2-G Lab Control Sample TCLP
Solid 1311280-184424-1 MS ST071-SoilIDW-11092023 TCLP
Solid 1311280-184424-1 MSD ST071-SoilIDW-11092023 TCLP
Prep Batch: 634516
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 3010A 634317280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 3010A 634317LB 280-634317/1-B Method Blank TCLP
Solid 3010A 634317LCS 280-634317/2-B Lab Control Sample TCLP
Eurofins Denver
Page 22 of 1261
QC Association Summary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Metals
Analysis Batch: 634762
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 6010D 634516280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 6010D 634516LB 280-634317/1-B Method Blank TCLP
Solid 6010D 634516LCS 280-634317/2-B Lab Control Sample TCLP
Prep Batch: 635179
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 7470A 634317280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 7470A 634317LB 280-634317/1-G Method Blank TCLP
Solid 7470A 634317LCS 280-634317/2-G Lab Control Sample TCLP
Solid 7470A 634317280-184424-1 MS ST071-SoilIDW-11092023 TCLP
Solid 7470A 634317280-184424-1 MSD ST071-SoilIDW-11092023 TCLP
Analysis Batch: 635299
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 7470A 635179280-184424-1 ST071-SoilIDW-11092023 TCLP
Solid 7470A 635179LB 280-634317/1-G Method Blank TCLP
Solid 7470A 635179LCS 280-634317/2-G Lab Control Sample TCLP
Solid 7470A 635179280-184424-1 MS ST071-SoilIDW-11092023 TCLP
Solid 7470A 635179280-184424-1 MSD ST071-SoilIDW-11092023 TCLP
General Chemistry
Prep Batch: 633716
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 9030B280-184424-1 ST071-SoilIDW-11092023 Total/NA
Solid 9030BMB 280-633716/3-A Method Blank Total/NA
Solid 9030BLCS 280-633716/1-A Lab Control Sample Total/NA
Solid 9030BLCSD 280-633716/2-A Lab Control Sample Dup Total/NA
Analysis Batch: 633717
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 9034 633716280-184424-1 ST071-SoilIDW-11092023 Total/NA
Solid 9034 633716MB 280-633716/3-A Method Blank Total/NA
Solid 9034 633716LCS 280-633716/1-A Lab Control Sample Total/NA
Solid 9034 633716LCSD 280-633716/2-A Lab Control Sample Dup Total/NA
Prep Batch: 633831
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 9012B280-184424-1 ST071-SoilIDW-11092023 Total/NA
Solid 9012BMB 280-633831/4-A Method Blank Total/NA
Solid 9012BHLCS 280-633831/1-A Lab Control Sample Total/NA
Solid 9012BLCS 280-633831/3-A Lab Control Sample Total/NA
Solid 9012BLLCS 280-633831/2-A Lab Control Sample Total/NA
Solid 9012B280-184424-1 MS ST071-SoilIDW-11092023 Total/NA
Solid 9012B280-184424-1 MSD ST071-SoilIDW-11092023 Total/NA
Analysis Batch: 634249
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid D 2216280-184424-1 ST071-SoilIDW-11092023 Total/NA
Eurofins Denver
Page 23 of 1261
QC Association Summary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
General Chemistry
Analysis Batch: 634302
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 9012B 633831280-184424-1 ST071-SoilIDW-11092023 Total/NA
Solid 9012B 633831MB 280-633831/4-A Method Blank Total/NA
Solid 9012B 633831HLCS 280-633831/1-A Lab Control Sample Total/NA
Solid 9012B 633831LCS 280-633831/3-A Lab Control Sample Total/NA
Solid 9012B 633831LLCS 280-633831/2-A Lab Control Sample Total/NA
Solid 9012B 633831280-184424-1 MS ST071-SoilIDW-11092023 Total/NA
Solid 9012B 633831280-184424-1 MSD ST071-SoilIDW-11092023 Total/NA
Leach Batch: 635889
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid DI Leach280-184424-1 ST071-SoilIDW-11092023 Soluble
Solid DI Leach280-184424-1 DU ST071-SoilIDW-11092023 Soluble
Analysis Batch: 635901
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 9045D 635889280-184424-1 ST071-SoilIDW-11092023 Soluble
Solid 9045DLCS 280-635901/4 Lab Control Sample Total/NA
Solid 9045D 635889280-184424-1 DU ST071-SoilIDW-11092023 Soluble
Analysis Batch: 808190
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 1030280-184424-1 ST071-SoilIDW-11092023 Total/NA
Solid 1030MB 680-808190/1 Method Blank Total/NA
Solid 1030LCS 680-808190/2 Lab Control Sample Total/NA
Solid 1030LCSD 680-808190/14 Lab Control Sample Dup Total/NA
Eurofins Denver
Page 24 of 1261
Lab Chronicle
Client: HydroGeoLogic Inc Job ID: 280-184424-1
Project/Site: Hill AFB, UT - ST071
Client Sample ID: ST071-SoilIDW-11092023 Lab Sample ID: 280-184424-1
Matrix: SolidDate Collected: 11/09/23 16:00
Date Received: 11/10/23 16:30
Leach 1311 DFB111/14/23 23:33 EET DEN633952
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
TCLP 1.0 g 1.0 mL
Completed:11/15/23 19:55 ¹
Analysis 8260D 1 634482 11/18/23 00:57 CCF EET DENTCLP0.5 mL 5 mL
Leach 1311 634317 11/17/23 00:38 DFB1 EET DENTCLP1.0 g 1.0 mL
Prep 3510C 634893 11/22/23 11:45 NMC EET DENTCLP125 mL 1 mL
Analysis 8270E 1 635266 11/28/23 11:10 MAB EET DENTCLP1 mL 1 mL
Leach 1311 634317 11/17/23 00:38 DFB1 EET DENTCLP1.0 g 1.0 mL
Prep 3010A 634516 11/20/23 08:41 MSM EET DENTCLP10 mL 50 mL
Analysis 6010D 1 634762 11/21/23 07:01 ADL EET DENTCLP
Leach 1311 634317 11/17/23 00:38 DFB1 EET DENTCLP1.0 g 1.0 mL
Prep 7470A 635179 11/27/23 14:45 KMS EET DENTCLP30 mL 50 mL
Analysis 7470A 1 635299 11/28/23 00:26 KMS EET DENTCLP
Analysis 1030 1 808190 11/14/23 14:20 SM EET SAVTotal/NA
Leach DI Leach 635889 12/02/23 19:51 LL EET DENSoluble40.02 g 40 mL
Analysis 9045D 1 635901 12/03/23 22:25 LL EET DENSoluble
Analysis D 2216 1 634249 11/16/23 13:49 MMP EET DENTotal/NA
Client Sample ID: ST071-SoilIDW-11092023 Lab Sample ID: 280-184424-1
Matrix: SolidDate Collected: 11/09/23 16:00
Percent Solids: 83.6Date Received: 11/10/23 16:30
Prep 9012B BCR11/14/23 11:47 EET DEN633831
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1.0036 g 50 mL
Analysis 9012B 1 634302 11/15/23 17:44 MMP EET DENTotal/NA 50 mL 50 mL
Prep 9030B 633716 11/13/23 15:10 SAH EET DENTotal/NA 10.41 g 50 mL
Analysis 9034 1 633717 11/13/23 15:18 SAH EET DENTotal/NA
¹ This procedure uses a method stipulated length of time for the process. Both start and end times are displayed.
Laboratory References:
EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Denver
Page 25 of 1261
Accreditation/Certification Summary
Client: HydroGeoLogic Inc Job ID: 280-184424-1
Project/Site: Hill AFB, UT - ST071
Laboratory: Eurofins Denver
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
A2LA Dept. of Defense ELAP 2907.01 10-31-24
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
7470A 7470A Solid Mercury
9045D Solid Temperature
D 2216 Solid Percent Solids
Utah NELAP CO000262019-11 07-31-24
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
7470A 7470A Solid Mercury
9045D Solid Temperature
D 2216 Solid Percent Moisture
D 2216 Solid Percent Solids
Laboratory: Eurofins Savannah
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
ANAB Dept. of Defense ELAP L2463 09-22-24
Eurofins Denver
Page 26 of 1261
Method Summary
Job ID: 280-184424-1Client: HydroGeoLogic Inc
Project/Site: Hill AFB, UT - ST071
Method Method Description LaboratoryProtocol
SW8468260DVolatile Organic Compounds (GC/MS)EET DEN
SW8468270ESemivolatile Organic Compounds (GC/MS)EET DEN
SW8466010DMetals (ICP)EET DEN
SW8467470AMercury (CVAA)EET DEN
SW8461030Ignitability, Solids EET SAV
EPA9012BCyanide, Total and/or Amenable EET DEN
SW8469034Sulfide, Acid Soluble and Insoluble (Titrimetric)EET DEN
SW8469045DpH EET DEN
ASTMD 2216 Percent Moisture EET DEN
SW8461311TCLP Extraction EET DEN
SW8463010APreparation, Total Metals EET DEN
SW8463510CLiquid-Liquid Extraction (Separatory Funnel)EET DEN
SW8465030BPurge and Trap EET DEN
SW8467470APreparation, Mercury EET DEN
SW8469012BCyanide, Total and/or Amenable, Distillation EET DEN
SW8469030BSulfide, Distillation (Acid Soluble and Insoluble)EET DEN
ASTMDI Leach Deionized Water Leaching Procedure EET DEN
Protocol References:
ASTM = ASTM International
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Denver
Page 27 of 1261
Sample Summary
Client: HydroGeoLogic Inc Job ID: 280-184424-1
Project/Site: Hill AFB, UT - ST071
Lab Sample ID Client Sample ID Matrix Collected Received
280-184424-1 ST071-SoilIDW-11092023 Solid 11/09/23 16:00 11/10/23 16:30
Eurofins DenverPage 28 of 1261
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_X4 628924
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-628924/3
X508906.D10/08/23 18:03 GC Column:RXI-624SilMS ID:0.25(mm)
1,1,2,2-Tetrachloroethane Wrong peak BMJ3 10/09/23 10:158.92
8260D
Page 29 of 1261
Lab Name:Job No.:
GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:Analysis Batch Number:SMS_1 633956
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
STD20 280-633956/10 IC
SMS_1-111523003.D11/15/23 07:34 GC Column:Rxi-5Sil MS ID:0.25(mm)
Benzoic acid Incomplete Integration FP7E 11/15/23 08:265.01
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
STD12 280-633956/8 IC
SMS_1-111523005.D11/15/23 08:18 GC Column:Rxi-5Sil MS ID:0.25(mm)
Benzoic acid Incomplete Integration FP7E 11/15/23 08:404.98
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
STD01 280-633956/5 IC
SMS_1-111523008.D11/15/23 09:25 GC Column:Rxi-5Sil MS ID:0.25(mm)
Benzoic acid Assign Peak FP7E 11/15/23 10:324.93
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
STD004 280-633956/4 IC
SMS_1-111523009.D11/15/23 09:47 GC Column:Rxi-5Sil MS ID:0.25(mm)
2,4,6-Tribromophenol (Surr)Assign Peak FP7E 11/15/23 10:337.54
8270E
Page 30 of 1261
Lab Name:Job No.:
GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:Analysis Batch Number:SMS_1 635266
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-184424-1 ST071-SoilIDW-11092023
SMS_1-112823006.D11/28/23 11:10 GC Column:Rxi-5Sil MS ID:0.25(mm)
Hexachloroethane Invalid Compound ID FP7E 11/29/23 09:45
8270E
Page 31 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
571995_00171 1,1'-Biphenyl 80 ug/mL500 mL 5 mL11/13/24 11/13/238270_LCS_Main_00090 P&T Methanol, Lot
MethanolP&T_00345
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Page 32 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00172 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
Page 33 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Page 34 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00173 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
Page 35 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Page 36 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00174 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
Page 37 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Page 38 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00178 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Page 39 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00179 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
Page 40 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Page 41 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00180 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
Page 42 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Page 43 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
1,1'-Biphenyl 80 ug/mL571995_00181 5 mL
1,2,4,5-Tetrachlorobenzene 80 ug/mL
1,2,4-Trichlorobenzene 80 ug/mL
1,2-Dichlorobenzene 80 ug/mL
1,2-Diphenylhydrazine 80.878 ug/mL
1,3-Dichlorobenzene 80 ug/mL
1,3-Dinitrobenzene 80 ug/mL
1,4-Dichlorobenzene 80 ug/mL
1,4-Dioxane 80 ug/mL
1-Methylnaphthalene 80 ug/mL
2,2'-oxybis[1-chloropropane]80 ug/mL
2,3,4,6-Tetrachlorophenol 80 ug/mL
2,4,5-Trichlorophenol 80 ug/mL
2,4,6-Trichlorophenol 80 ug/mL
2,4-Dichlorophenol 80 ug/mL
2,4-Dimethylphenol 80 ug/mL
2,4-Dinitrophenol 160 ug/mL
2,4-Dinitrotoluene 80 ug/mL
2,6-Dichlorophenol 80 ug/mL
2,6-Dinitrotoluene 80 ug/mL
2-Chloronaphthalene 80 ug/mL
2-Chlorophenol 80 ug/mL
2-Methylnaphthalene 80 ug/mL
2-Methylphenol 80 ug/mL
2-Nitroaniline 80 ug/mL
2-Nitrophenol 80 ug/mL
3 & 4 Methylphenol 80 ug/mL
3-Methylphenol 80 ug/mL
3-Nitroaniline 80 ug/mL
Page 44 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4,6-Dinitro-2-methylphenol 160 ug/mL
4-Bromophenyl phenyl ether 80 ug/mL
4-Chloro-3-methylphenol 80 ug/mL
4-Chloroaniline 80 ug/mL
4-Chlorophenyl phenyl ether 80 ug/mL
4-Methylphenol 80 ug/mL
4-Nitroaniline 80 ug/mL
4-Nitrophenol 160 ug/mL
Acenaphthene 80 ug/mL
Acenaphthylene 80 ug/mL
Acetophenone 80 ug/mL
Aniline 80 ug/mL
Anthracene 80 ug/mL
Azobenzene 80 ug/mL
Benzo[a]anthracene 80 ug/mL
Benzo[a]pyrene 80 ug/mL
Benzo[b]fluoranthene 80 ug/mL
Benzo[g,h,i]perylene 80 ug/mL
Benzo[k]fluoranthene 80 ug/mL
Benzyl alcohol 80 ug/mL
Bis(2-chloroethoxy)methane 80 ug/mL
Bis(2-chloroethyl)ether 80 ug/mL
Bis(2-ethylhexyl) phthalate 80 ug/mL
Butyl benzyl phthalate 80 ug/mL
Carbazole 80 ug/mL
Chrysene 80 ug/mL
Di-n-butyl phthalate 80 ug/mL
Di-n-octyl phthalate 80 ug/mL
Dibenz(a,h)anthracene 80 ug/mL
Dibenzofuran 80 ug/mL
Diethyl phthalate 80 ug/mL
Dimethyl phthalate 80 ug/mL
Diphenylamine 68 ug/mL
Fluoranthene 80 ug/mL
Fluorene 80 ug/mL
Hexachlorobenzene 80 ug/mL
Hexachlorobutadiene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mL
Hexachloroethane 80 ug/mL
Hexadecane 80 ug/mL
Indeno[1,2,3-cd]pyrene 80 ug/mL
Isophorone 80 ug/mL
n-Decane 80 ug/mL
N-Nitrosodi-n-propylamine 80 ug/mL
N-Nitrosodimethylamine 80 ug/mL
N-Nitrosodiphenylamine 80 ug/mL
n-Octadecane 80 ug/mL
Page 45 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Naphthalene 80 ug/mL
Nitrobenzene 80 ug/mL
Pentachlorophenol 160 ug/mL
Phenanthrene 80 ug/mL
Phenol 80 ug/mL
Pyrene 80 ug/mL
Pyridine 160 ug/mL
Benzoic acid 80 ug/mLOP-569731_00099 5 mL
Indene 80 ug/mL
Benzoic acid 80 ug/mLOP-569731_00100 5 mL
Indene 80 ug/mL
Benzoic acid 80 ug/mLOP-569731_00101 5 mL
Indene 80 ug/mL
Benzoic acid 80 ug/mLOP-569731_00102 5 mL
Indene 80 ug/mL
Hexachlorocyclopentadiene 160.42 ug/mLOP-572556_00055 5 mL
OP-572556_00062 5 mL Hexachlorocyclopentadiene 160.42 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00171
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
Page 46 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Page 47 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00172
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Page 48 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00173
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
Page 49 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Page 50 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00174
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
Page 51 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Page 52 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00178
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
Page 53 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
Page 54 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00179
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Page 55 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00180
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
Page 56 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Page 57 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772.571995_00181
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1,4-Dioxane 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
Page 58 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
4-Methylphenol 1000 ug/mL
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Page 59 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Hexadecane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
n-Decane 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
n-Octadecane 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
01/31/25 (Purchased Reagent)Benzoic acid 2000 ug/mLRestek, Lot A0199925.OP-569731_00099
Indene 2000 ug/mL
01/31/25 (Purchased Reagent)Benzoic acid 2000 ug/mLRestek, Lot A0199925.OP-569731_00100
Indene 2000 ug/mL
01/31/25 (Purchased Reagent)Benzoic acid 2000 ug/mLRestek, Lot A0199925.OP-569731_00101
Indene 2000 ug/mL
01/31/25 (Purchased Reagent)Benzoic acid 2000 ug/mLRestek, Lot A0199925.OP-569731_00102
Indene 2000 ug/mL
06/30/26 (Purchased Reagent)Hexachlorocyclopentadiene 4021 ug/mLRestek, Lot A0186275.OP-572556_00055
06/30/26 (Purchased Reagent)Hexachlorocyclopentadiene 4021 ug/mLRestek, Lot A0186275.OP-572556_00062
8270SurStkHL_00434 2,4,6 - Tribromophenol 100 ug/mL1000 mL 5 mL09/06/24 09/06/238270Surrogate_00171 ACETONE, Lot
Acetone_00896
2,4,6-Tribromophenol (Surr)100 ug/mL
2-Fluorobiphenyl 100 ug/mL
2-Fluorophenol (Surr)100 ug/mL
Nitrobenzene-d5 (Surr)100 ug/mL
Phenol-d5 (Surr)100 ug/mL
Phenol-d6 100 ug/mL
Terphenyl-d14 (Surr)100 ug/mL
2,4,6 - Tribromophenol 100 ug/mL8270SurStkHL_00435 5 mL
2,4,6-Tribromophenol (Surr)100 ug/mL
2-Fluorobiphenyl 100 ug/mL
2-Fluorophenol (Surr)100 ug/mL
Nitrobenzene-d5 (Surr)100 ug/mL
Page 60 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Phenol-d5 (Surr)100 ug/mL
Phenol-d6 100 ug/mL
Terphenyl-d14 (Surr)100 ug/mL
2,4,6 - Tribromophenol 100 ug/mL8270SurStkHL_00441 5 mL
2,4,6-Tribromophenol (Surr)100 ug/mL
2-Fluorobiphenyl 100 ug/mL
2-Fluorophenol (Surr)100 ug/mL
Nitrobenzene-d5 (Surr)100 ug/mL
Phenol-d5 (Surr)100 ug/mL
Phenol-d6 100 ug/mL
Terphenyl-d14 (Surr)100 ug/mL
2,4,6 - Tribromophenol 100 ug/mL8270SurStkHL_00442 5 mL
2,4,6-Tribromophenol (Surr)100 ug/mL
2-Fluorobiphenyl 100 ug/mL
2-Fluorophenol (Surr)100 ug/mL
Nitrobenzene-d5 (Surr)100 ug/mL
Phenol-d5 (Surr)100 ug/mL
Phenol-d6 100 ug/mL
Terphenyl-d14 (Surr)100 ug/mL
04/30/27 (Purchased Reagent)2,4,6 - Tribromophenol 5000 ug/mLRestek, Lot A0184539.8270SurStkHL_00434
2,4,6-Tribromophenol (Surr)5000 ug/mL
2-Fluorobiphenyl 5000 ug/mL
2-Fluorophenol (Surr)5000 ug/mL
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Phenol-d6 5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
04/30/27 (Purchased Reagent)2,4,6 - Tribromophenol 5000 ug/mLRestek, Lot A0184539.8270SurStkHL_00435
2,4,6-Tribromophenol (Surr)5000 ug/mL
2-Fluorobiphenyl 5000 ug/mL
2-Fluorophenol (Surr)5000 ug/mL
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Phenol-d6 5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
04/30/27 (Purchased Reagent)2,4,6 - Tribromophenol 5000 ug/mLRestek, Lot A0184539.8270SurStkHL_00441
2,4,6-Tribromophenol (Surr)5000 ug/mL
2-Fluorobiphenyl 5000 ug/mL
2-Fluorophenol (Surr)5000 ug/mL
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Phenol-d6 5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
04/30/27 (Purchased Reagent)2,4,6 - Tribromophenol 5000 ug/mLRestek, Lot A0184539.8270SurStkHL_00442
2,4,6-Tribromophenol (Surr)5000 ug/mL
2-Fluorobiphenyl 5000 ug/mL
2-Fluorophenol (Surr)5000 ug/mL
Page 61 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Phenol-d6 5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
MV-Gas A_00167 Bromomethane 5 ug/mL100 uL 2 uL10/16/23 10/05/23Cal Dil Std_00249 P&T Methanol, Lot
ED137-US
Chloroethane 5 ug/mL
Chloromethane 5 ug/mL
Dichlorodifluoromethane 5 ug/mL
Dichlorofluoromethane 5 ug/mL
Trichlorofluoromethane 5 ug/mL
Vinyl chloride 5 ug/mL
2-Chloroethyl vinyl ether 5 ug/mL
Acrolein 49.375 ug/mLMV-MegaMainA_00096 5 uL
2-Butanone (MEK)20 ug/mL
2-Hexanone 20 ug/mL
4-Methyl-2-pentanone (MIBK)20 ug/mL
Acetone 20 ug/mL
Vinyl acetate 10 ug/mL
Cyclohexanone 150 ug/mL
1,1,1,2-Tetrachloroethane 5 ug/mL
1,1,1-Trichloroethane 5 ug/mL
1,1,2,2-Tetrachloroethane 5 ug/mL
1,1,2-Trichloro-1,2,2-trifluor
oethane
5 ug/mL
1,1,2-Trichloroethane 5 ug/mL
1,1-Dichloroethane 5 ug/mL
1,1-Dichloroethene 5 ug/mL
1,1-Dichloropropene 5 ug/mL
1,2,3-Trichlorobenzene 5 ug/mL
1,2,3-Trichloropropane 5 ug/mL
1,2,4-Trichlorobenzene 5 ug/mL
1,2,4-Trimethylbenzene 5 ug/mL
1,2-Dibromo-3-Chloropropane 5 ug/mL
1,2-Dichlorobenzene 5 ug/mL
1,2-Dichloroethane 5 ug/mL
1,2-Dichloropropane 5 ug/mL
1,3,5-Trimethylbenzene 5 ug/mL
1,3-Dichlorobenzene 5 ug/mL
1,3-Dichloropropane 5 ug/mL
1,4-Dichlorobenzene 5 ug/mL
1,4-Dioxane 100 ug/mL
2,2-Dichloropropane 5 ug/mL
2-Chlorotoluene 5 ug/mL
2-Methyl-2-propanol 50 ug/mL
3-Chloro-1-propene 5 ug/mL
4-Chlorotoluene 5 ug/mL
Page 62 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Isopropyltoluene 5 ug/mL
Acrylonitrile 50 ug/mL
Benzene 5 ug/mL
Bromobenzene 5 ug/mL
Bromoform 5 ug/mL
Carbon disulfide 5 ug/mL
Carbon tetrachloride 5 ug/mL
Chlorobenzene 5 ug/mL
Chlorobromomethane 5 ug/mL
Chlorodibromomethane 5 ug/mL
Chloroform 5 ug/mL
cis-1,2-Dichloroethene 5 ug/mL
cis-1,3-Dichloropropene 5 ug/mL
Cyclohexane 5 ug/mL
Dibromomethane 5 ug/mL
Dichlorobromomethane 5 ug/mL
Ethyl ether 5 ug/mL
Ethyl methacrylate 5 ug/mL
Ethylbenzene 5 ug/mL
Ethylene Dibromide 5 ug/mL
Hexachlorobutadiene 5 ug/mL
Hexane 5 ug/mL
Iodomethane 5 ug/mL
Isobutyl alcohol 125 ug/mL
Isopropylbenzene 5 ug/mL
m-Xylene & p-Xylene 5 ug/mL
Methyl acetate 10 ug/mL
Methyl tert-butyl ether 5 ug/mL
Methylcyclohexane 5 ug/mL
Methylene Chloride 5 ug/mL
n-Butylbenzene 5 ug/mL
n-Heptane 5 ug/mL
N-Propylbenzene 5 ug/mL
Naphthalene 5 ug/mL
o-Xylene 5 ug/mL
sec-Butylbenzene 5 ug/mL
Styrene 5 ug/mL
tert-Butylbenzene 5 ug/mL
Tetrachloroethene 5 ug/mL
Tetrahydrofuran 10 ug/mL
Toluene 5 ug/mL
trans-1,2-Dichloroethene 5 ug/mL
trans-1,3-Dichloropropene 5 ug/mL
trans-1,4-Dichloro-2-butene 5 ug/mL
Trichloroethene 5 ug/mL
1-Chlorohexane 4 ug/mL
2-Pentanone 16 ug/mL
Page 63 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
sec-Butyl Alcohol 120 ug/mL
MV-569722_00022 Bromomethane 250 ug/mL12.5 mL 1250 uL10/23/23 09/27/23.MV-Gas A_00167 P&T Methanol, Lot
198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00018 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
08/31/25 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0189184..MV-569722_00022
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
01/31/26 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0193735..MV-569723_00018
MV-568720_00046 Acrolein 987.5 ug/mL25 mL 1250 uL10/30/23 09/27/23.MV-MegaMainA_00096 P&T Methanol, Lot
181124
2-Butanone (MEK)400 ug/mLMV-569721_00015 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00035 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00024 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00015 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluor
oethane
100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
Page 64 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
Page 65 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739.s_00011 2000 uL
2-Pentanone 320 ug/mL
sec-Butyl Alcohol 2400 ug/mL
07/31/24 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0193730..MV-568720_00046
01/31/26 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0193494..MV-569721_00015
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
01/31/24 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0187365..MV-569724_00035
04/30/26 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0197009..MV-569727_00024
09/30/24 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0183568..MV-571992_00015
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluor
oethane
2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Page 66 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
05/31/24 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6676357.sec..MV-CUS17739.s_00011
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
CN CAL Std_00083 Cyanide, Amenable 10 mg/L100
mg/Kg
LAS
MW340
1 mL11/20/23 11/13/23CN 10ppm_00683 2% NaOH, Lot 11% NaOH
Cyanide, Free 10 mg/L
Cyanide, Non-amenable 10 mg/L
Cyanide, Total 10 mg/L
Page 67 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Cyanide, Weak Acid Dissociable 10 mg/L
Potassium Cyanide 0 mg/L
Potassium hydroxide 0 mg/L
06/08/24 (Purchased Reagent)Cyanide, Amenable 1000 mg/LERA, Lot 250623m.CN CAL Std_00083
Cyanide, Free 1000 mg/L
Cyanide, Non-amenable 1000 mg/L
Cyanide, Total 1000 mg/L
Cyanide, Weak Acid Dissociable 1000 mg/L
Potassium Cyanide 0 mg/L
Potassium hydroxide 0 mg/L
11/16/23 11/15/23 100 mL CN 10ppm_00683 10 mL Cyanide, Total 1 mg/LCN CAL 1 ppm_02258 1% NaOH, Lot N/A
11/20/23 11/13/23 100
mg/Kg
LAS
MW340
CN CAL Std_00083 1 mL Cyanide, Total 10 mg/L.CN 10ppm_00683 2% NaOH, Lot 11% NaOH
06/08/24 (Purchased Reagent)Cyanide, Total 1000 mg/LERA, Lot 250623m..CN CAL Std_00083
CN CAL Std_00083 Cyanide, Amenable 10 mg/L100 mL 1 mL11/20/23 11/13/23CN ICV Int_00861 1% NaOH, Lot NaOH
Cyanide, Free 10 mg/L
Cyanide, Non-amenable 10 mg/L
Cyanide, Total 10 mg/L
Cyanide, Weak Acid Dissociable 10 mg/L
Potassium Cyanide 0 mg/L
Potassium hydroxide 0 mg/L
06/08/24 (Purchased Reagent)Cyanide, Amenable 1000 mg/LERA, Lot 250623m.CN CAL Std_00083
Cyanide, Free 1000 mg/L
Cyanide, Non-amenable 1000 mg/L
Cyanide, Total 1000 mg/L
Cyanide, Weak Acid Dissociable 1000 mg/L
Potassium Cyanide 0 mg/L
Potassium hydroxide 0 mg/L
09/07/24 (Purchased Reagent)Arsenic 300 ug/mLCPI, Lot 1352389CPI TCLP Spk_00006
Barium 1000 ug/mL
Cadmium 100 ug/mL
Chromium 500 ug/mL
Cu 200 ug/mL
Lead 500 ug/mL
Selenium 100 ug/mL
Silver 100 ug/mL
12/12/23 11/28/23 100 mL Hg CPI Stock_00004 0.04 mL Mercury 400 ppbHg Biwk ICV_00405 1% HNO3, Lot 231516
03/08/25 (Purchased Reagent)Mercury 1000 ug/mLCPI International, Lot 1293435-1.Hg CPI Stock_00004
11/28/23 11/28/23 100 mL Hg Mnth Spike_00207 1 mL Mercury 100 ppbHg Daily Spk_03482 1% HNO3, Lot 231516
12/09/23 11/09/23 100 mL Hg EE 1000ppm_00007 1 mL Mercury 10 mg/L.Hg Mnth Spike_00207 1% HNO3, Lot K23022
02/28/25 (Purchased Reagent)Mercury 1000 ug/mLEnvironmental Express, Lot 2314224..Hg EE 1000ppm_00007
ICP ICAL1A_01013 Arsenic 0.5 mg/L500 mL 250 mL03/27/24 11/15/23ICP CCV_00709 5%/5% HCL/HNO3, Lot SEE
LOGBOOK
Barium 0.5 mg/L
Page 68 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Cadmium 0.5 mg/L
Chromium 0.5 mg/L
Lead 0.5 mg/L
Selenium 0.5 mg/L
Silver 0.5 mg/L
ICP CAL STD 1_00014 Arsenic 1 mg/L1000 mL 10 mL03/27/24 11/15/23.ICP ICAL1A_01013 5%/5% HCL/HNO3, Lot SEE
LOGBOOK
Barium 1 mg/L
Cadmium 1 mg/L
Chromium 1 mg/L
Lead 1 mg/L
Selenium 1 mg/L
ICP CAL STD 4_00012 10 mL Silver 1 mg/L
03/27/24 (Purchased Reagent)Arsenic 100 mg/LCPI, Lot 1208138-1..ICP CAL STD 1_00014
Barium 100 mg/L
Cadmium 100 mg/L
Chromium 100 mg/L
Lead 100 mg/L
Selenium 100 mg/L
04/30/24 (Purchased Reagent)Silver 100 mg/LCPI, Lot 220843..ICP CAL STD 4_00012
Icp stk ICSA_00040 Al 500 mg/L250 mL 25 mL05/03/24 11/03/23ICP ICSA_00261 5%/5% HCL/HNO3, Lot SEE
LOGBOOK
Ca 500 mg/L
Fe 200 mg/L
Mg 500 mg/L
06/30/24 (Purchased Reagent)Al 5000 mg/LIV, Lot t2-meb726136.Icp stk ICSA_00040
Ca 5000 mg/L
Fe 2000 mg/L
Mg 5000 mg/L
1000 Li_00044 Li 1 mg/L250 mL 0.25 mL12/31/23 11/07/23ICP ICSAB_00290 5%/5% HCL/HNO3, Lot SEE
LOGBOOK
Zr 1 mg/L1000 Zr_00025 0.25 mL
Sulfur 10 mg/L10000 S_00017 0.25 mL
Mo 1 mg/LICP ICSAB 1_00007 2.5 mL
Sb 1 mg/L
Sn 1 mg/L
Ti 1 mg/L
Arsenic 1 mg/LICP ICSAB 2_00007 2.5 mL
B 10 mg/L
Barium 1 mg/L
Be 0.5 mg/L
Cadmium 1 mg/L
Chromium 1 mg/L
Co 1 mg/L
Cu 1 mg/L
K 10 mg/L
Lead 1 mg/L
Page 69 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Mn 1 mg/L
Na 10 mg/L
Ni 1 mg/L
P 10 mg/L
Selenium 1 mg/L
Silver 1 mg/L
Tl 1 mg/L
V 1 mg/L
Zn 1 mg/L
Al 500 mg/LIcp stk ICSA_00039 25 mL
Ca 500 mg/L
Fe 200 mg/L
Mg 500 mg/L
06/23/24 (Purchased Reagent)Li 1000 mg/LCPI, Lot 1186016-37.1000 Li_00044
07/01/24 (Purchased Reagent)Zr 1000 mg/LCPI, Lot 1241783-14.1000 Zr_00025
11/02/24 (Purchased Reagent)Sulfur 10000 mg/LCPI, Lot 1205121-26.10000 S_00017
03/11/25 (Purchased Reagent)Mo 100 mg/LCPI, Lot 1399525.ICP ICSAB 1_00007
Sb 100 mg/L
Sn 100 mg/L
Ti 100 mg/L
03/14/25 (Purchased Reagent)Arsenic 100 mg/LCPI, Lot 1333445-1.ICP ICSAB 2_00007
B 1000 mg/L
Barium 100 mg/L
Be 50 mg/L
Cadmium 100 mg/L
Chromium 100 mg/L
Co 100 mg/L
Cu 100 mg/L
K 1000 mg/L
Lead 100 mg/L
Mn 100 mg/L
Na 1000 mg/L
Ni 100 mg/L
P 1000 mg/L
Selenium 100 mg/L
Silver 100 mg/L
Tl 100 mg/L
V 100 mg/L
Zn 100 mg/L
12/31/23 (Purchased Reagent)Al 5000 mg/Lhp, Lot 2203133-500.Icp stk ICSA_00039
Ca 5000 mg/L
Fe 2000 mg/L
Mg 5000 mg/L
ICP ICV STD 4_00003 Silver 0.25 ppm100 mL 0.25 mL07/31/24 11/20/23ICP ICV_01806 5%HNO3/5% HCl, Lot SEE
LOGBOOK
Arsenic 0.25 ppmICV MIX-1a_00004 0.25 mL
Barium 0.25 ppm
Page 70 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Cadmium 0.25 ppm
Chromium 0.25 ppm
Lead 0.25 ppm
Selenium 0.25 ppm
11/30/24 (Purchased Reagent)Silver 100 mg/LCPI, Lot 230336.ICP ICV STD 4_00003
07/31/24 (Purchased Reagent)Arsenic 100 mg/LIV, Lot u2-meb734729.ICV MIX-1a_00004
Barium 100 mg/L
Cadmium 100 mg/L
Chromium 100 mg/L
Lead 100 mg/L
Selenium 100 mg/L
ICP LLCCV_03783 Arsenic 15 ppb100 mL 1 mL11/21/23 11/20/23ICP LLCCV_03791 5%HNO3/5% HCl, Lot SEE
LOGBOOK
Barium 10 ppb
Cadmium 5 ppb
Chromium 10 ppb
Lead 9 ppb
Selenium 20 ppb
Silver 10 ppb
11/13/24 (Purchased Reagent)Arsenic 1.5 mg/LIV, Lot U2-MEB734692.ICP LLCCV_03783
Barium 1 mg/L
Cadmium 0.5 mg/L
Chromium 1 mg/L
Lead 0.9 mg/L
Selenium 2 mg/L
Silver 1 mg/L
Aramite, TotalMS-DFTPP_RVE_00001
Diallate
Isosafrole
Methyl Phenols,Total
Tentatively Identified
Compound
Total Cresols
TPAH
4,4'-DDD 0.025 ug/mLMS-31615_00016 0.5 mL
4,4'-DDE 0.025 ug/mL
4,4'-DDT 25 ug/mL
Benzidine_T 25 ug/mL
DFTPP 25 ug/mL
Pentachlorophenol_T 25 ug/mL
09/30/25 (Purchased Reagent)4,4'-DDD 1 ug/mLRestek, Lot A0189454.MS-31615_00016
4,4'-DDE 1 ug/mL
4,4'-DDT 1000 ug/mL
Benzidine_T 1000 ug/mL
DFTPP 1000 ug/mL
Pentachlorophenol_T 1000 ug/mL
Page 71 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
MS-567685_00063 2,4,6-Tribromophenol (Surr)200 ug/mL10 mL 0.4 mL12/31/23 08/16/23MS-HSL-WS_00005 Methylene Chloride, Lot
00604
2-Fluorobiphenyl 200 ug/mL
2-Fluorophenol (Surr)200 ug/mL
Nitrobenzene-d5 (Surr)200 ug/mL
Phenol-d5 (Surr)200 ug/mL
Terphenyl-d14 (Surr)200 ug/mL
1,4-Dichlorobenzene 200 ug/mLMS-571995_00084 2 mL
2,4,5-Trichlorophenol 200 ug/mL
2,4,6-Trichlorophenol 200 ug/mL
2,4-Dinitrotoluene 200 ug/mL
2-Methylphenol 200 ug/mL
3 & 4 Methylphenol 200 ug/mL
Hexachlorobenzene 200 ug/mL
Hexachlorobutadiene 200 ug/mL
Hexachloroethane 200 ug/mL
Nitrobenzene 200 ug/mL
Pentachlorophenol 400 ug/mL
Pyridine 400 ug/mL
04/30/27 (Purchased Reagent)2,4,6-Tribromophenol (Surr)5000 ug/mLRestek, Lot A0184539.MS-567685_00063
2-Fluorobiphenyl 5000 ug/mL
2-Fluorophenol (Surr)5000 ug/mL
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
12/31/23 (Purchased Reagent)1,4-Dichlorobenzene 1000 ug/mLRestek, Lot A0186002.MS-571995_00084
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2-Methylphenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Pyridine 2000 ug/mL
571995_00165 1,4-Dichlorobenzene 200 ug/mL10 mL 2 mL07/31/24 10/05/23MS-HSL-WS_00006 Methylene Chloride, Lot
00604
2,4,5-Trichlorophenol 200 ug/mL
2,4,6-Trichlorophenol 200 ug/mL
2,4-Dinitrotoluene 200 ug/mL
2-Methylphenol 200 ug/mL
3 & 4 Methylphenol 200 ug/mL
Hexachlorobenzene 200 ug/mL
Hexachlorobutadiene 200 ug/mL
Hexachloroethane 200 ug/mL
Page 72 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Nitrobenzene 200 ug/mL
Pentachlorophenol 400 ug/mL
Pyridine 400 ug/mL
2,4,6-Tribromophenol (Surr)200 ug/mL8270SurStkHL_00436 0.4 mL
2-Fluorobiphenyl 200 ug/mL
2-Fluorophenol (Surr)200 ug/mL
Nitrobenzene-d5 (Surr)200 ug/mL
Phenol-d5 (Surr)200 ug/mL
Terphenyl-d14 (Surr)200 ug/mL
09/30/24 (Purchased Reagent)1,4-Dichlorobenzene 1000 ug/mLRestek, Lot A0195772.571995_00165
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2-Methylphenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Pyridine 2000 ug/mL
04/30/27 (Purchased Reagent)2,4,6-Tribromophenol (Surr)5000 ug/mLRestek, Lot A0184539.8270SurStkHL_00436
2-Fluorobiphenyl 5000 ug/mL
2-Fluorophenol (Surr)5000 ug/mL
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
MS-IS_00035 1,4-Dichlorobenzene-d4 80 ug/mL50 mL 10 mL06/08/24 06/08/23MS-IS-RVE_00003 Methylene Chloride, Lot
MeCl2_Cycl_00602
Acenaphthene-d10 80 ug/mL
Chrysene-d12 80 ug/mL
Naphthalene-d8 80 ug/mL
Perylene-d12 80 ug/mL
Phenanthrene-d10 80 ug/mL
MS-567684_00040 1,4-Dichlorobenzene-d4 400 ug/mL50 mL 5 mL06/08/24 06/08/23.MS-IS_00035 Methylene Chloride, Lot
MeCl2_Cycl_00602
Acenaphthene-d10 400 ug/mL
Chrysene-d12 400 ug/mL
Naphthalene-d8 400 ug/mL
Perylene-d12 400 ug/mL
Phenanthrene-d10 400 ug/mL
1,4-Dichlorobenzene-d4 400 ug/mLMS-567684_00041 5 mL
Acenaphthene-d10 400 ug/mL
Chrysene-d12 400 ug/mL
Naphthalene-d8 400 ug/mL
Perylene-d12 400 ug/mL
Phenanthrene-d10 400 ug/mL
Page 73 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
07/30/27 (Purchased Reagent)1,4-Dichlorobenzene-d4 2000 ug/mLRestek, Lot A0187296..MS-567684_00040
Acenaphthene-d10 2000 ug/mL
Chrysene-d12 2000 ug/mL
Naphthalene-d8 2000 ug/mL
Perylene-d12 2000 ug/mL
Phenanthrene-d10 2000 ug/mL
07/30/27 (Purchased Reagent)1,4-Dichlorobenzene-d4 2000 ug/mLRestek, Lot A0187296..MS-567684_00041
Acenaphthene-d10 2000 ug/mL
Chrysene-d12 2000 ug/mL
Naphthalene-d8 2000 ug/mL
Perylene-d12 2000 ug/mL
Phenanthrene-d10 2000 ug/mL
MS-IS_00037 1,4-Dichlorobenzene-d4 80 ug/mL50 mL 10 mL08/14/24 10/26/23MS-IS-RVE_00005 Methylene Chloride, Lot
MeCl2_Cycl_00602
Acenaphthene-d10 80 ug/mL
Chrysene-d12 80 ug/mL
Naphthalene-d8 80 ug/mL
Perylene-d12 80 ug/mL
Phenanthrene-d10 80 ug/mL
MS-567684_00045 1,4-Dichlorobenzene-d4 400 ug/mL50 mL 10 mL10/09/24 10/09/23.MS-IS_00037 Methylene Chloride, Lot
MeCl2_Cycl_00563
Acenaphthene-d10 400 ug/mL
Chrysene-d12 400 ug/mL
Naphthalene-d8 400 ug/mL
Perylene-d12 400 ug/mL
Phenanthrene-d10 400 ug/mL
01/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2000 ug/mLRestek, Lot A0193798..MS-567684_00045
Acenaphthene-d10 2000 ug/mL
Chrysene-d12 2000 ug/mL
Naphthalene-d8 2000 ug/mL
Perylene-d12 2000 ug/mL
Phenanthrene-d10 2000 ug/mL
MS-HSL-WS_00006 1,1'-Biphenyl 20 ug/mL5 mL 500 uL07/31/24 11/15/23MS-RVHSL-WS_00003 Methylene Chloride, Lot
00562
1,2,4,5-Tetrachlorobenzene 20 ug/mL
1,2,4-Trichlorobenzene 20 ug/mL
1,2-Dichlorobenzene 20 ug/mL
1,2-Diphenylhydrazine 20.2195 ug/mL
1,3-Dichlorobenzene 20 ug/mL
1,3-Dinitrobenzene 20 ug/mL
1,4-Dichlorobenzene 20 ug/mL
1-Methylnaphthalene 20 ug/mL
2,2'-oxybis[1-chloropropane]20 ug/mL
2,3,4,6-Tetrachlorophenol 20 ug/mL
2,4,5-Trichlorophenol 20 ug/mL
2,4,6-Trichlorophenol 20 ug/mL
2,4-Dichlorophenol 20 ug/mL
Page 74 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2,4-Dimethylphenol 20 ug/mL
2,4-Dinitrophenol 40 ug/mL
2,4-Dinitrotoluene 20 ug/mL
2,6-Dichlorophenol 20 ug/mL
2,6-Dinitrotoluene 20 ug/mL
2-Chloronaphthalene 20 ug/mL
2-Chlorophenol 20 ug/mL
2-Methylnaphthalene 20 ug/mL
2-Methylphenol 20 ug/mL
2-Nitroaniline 20 ug/mL
2-Nitrophenol 20 ug/mL
3 & 4 Methylphenol 20 ug/mL
3-Nitroaniline 20 ug/mL
4,6-Dinitro-2-methylphenol 40 ug/mL
4-Bromophenyl phenyl ether 20 ug/mL
4-Chloro-3-methylphenol 20 ug/mL
4-Chloroaniline 20 ug/mL
4-Chlorophenyl phenyl ether 20 ug/mL
4-Nitroaniline 20 ug/mL
4-Nitrophenol 40 ug/mL
Acenaphthene 20 ug/mL
Acenaphthylene 20 ug/mL
Acetophenone 20 ug/mL
Aniline 20 ug/mL
Anthracene 20 ug/mL
Azobenzene 20 ug/mL
Benzo[a]anthracene 20 ug/mL
Benzo[a]pyrene 20 ug/mL
Benzo[b]fluoranthene 20 ug/mL
Benzo[g,h,i]perylene 20 ug/mL
Benzo[k]fluoranthene 20 ug/mL
Benzyl alcohol 20 ug/mL
Bis(2-chloroethoxy)methane 20 ug/mL
Bis(2-chloroethyl)ether 20 ug/mL
Bis(2-ethylhexyl) phthalate 20 ug/mL
Butyl benzyl phthalate 20 ug/mL
Carbazole 20 ug/mL
Chrysene 20 ug/mL
Di-n-butyl phthalate 20 ug/mL
Di-n-octyl phthalate 20 ug/mL
Dibenz(a,h)anthracene 20 ug/mL
Dibenzofuran 20 ug/mL
Diethyl phthalate 20 ug/mL
Dimethyl phthalate 20 ug/mL
Diphenylamine 17 ug/mL
Fluoranthene 20 ug/mL
Fluorene 20 ug/mL
Page 75 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Hexachlorobenzene 20 ug/mL
Hexachlorobutadiene 20 ug/mL
Hexachlorocyclopentadiene 20 ug/mL
Hexachloroethane 20 ug/mL
Indeno[1,2,3-cd]pyrene 20 ug/mL
Isophorone 20 ug/mL
N-Nitrosodi-n-propylamine 20 ug/mL
N-Nitrosodimethylamine 20 ug/mL
N-Nitrosodiphenylamine 20 ug/mL
Naphthalene 20 ug/mL
Nitrobenzene 20 ug/mL
Pentachlorophenol 40 ug/mL
Phenanthrene 20 ug/mL
Phenol 20 ug/mL
Pyrene 20 ug/mL
Pyridine 40 ug/mL
2,4,6-Tribromophenol (Surr)20 ug/mL
2-Fluorobiphenyl 20 ug/mL
2-Fluorophenol (Surr)20 ug/mL
Nitrobenzene-d5 (Surr)20 ug/mL
Phenol-d5 (Surr)20 ug/mL
Terphenyl-d14 (Surr)20 ug/mL
Alachlor 20 ug/mL
Benzoic acid 40 ug/mL
571995_00165 1,1'-Biphenyl 200 ug/mL10 mL 2 mL07/31/24 10/05/23.MS-HSL-WS_00006 Methylene Chloride, Lot
00604
1,2,4,5-Tetrachlorobenzene 200 ug/mL
1,2,4-Trichlorobenzene 200 ug/mL
1,2-Dichlorobenzene 200 ug/mL
1,2-Diphenylhydrazine 202.195 ug/mL
1,3-Dichlorobenzene 200 ug/mL
1,3-Dinitrobenzene 200 ug/mL
1,4-Dichlorobenzene 200 ug/mL
1-Methylnaphthalene 200 ug/mL
2,2'-oxybis[1-chloropropane]200 ug/mL
2,3,4,6-Tetrachlorophenol 200 ug/mL
2,4,5-Trichlorophenol 200 ug/mL
2,4,6-Trichlorophenol 200 ug/mL
2,4-Dichlorophenol 200 ug/mL
2,4-Dimethylphenol 200 ug/mL
2,4-Dinitrophenol 400 ug/mL
2,4-Dinitrotoluene 200 ug/mL
2,6-Dichlorophenol 200 ug/mL
2,6-Dinitrotoluene 200 ug/mL
2-Chloronaphthalene 200 ug/mL
2-Chlorophenol 200 ug/mL
2-Methylnaphthalene 200 ug/mL
2-Methylphenol 200 ug/mL
Page 76 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2-Nitroaniline 200 ug/mL
2-Nitrophenol 200 ug/mL
3 & 4 Methylphenol 200 ug/mL
3-Nitroaniline 200 ug/mL
4,6-Dinitro-2-methylphenol 400 ug/mL
4-Bromophenyl phenyl ether 200 ug/mL
4-Chloro-3-methylphenol 200 ug/mL
4-Chloroaniline 200 ug/mL
4-Chlorophenyl phenyl ether 200 ug/mL
4-Nitroaniline 200 ug/mL
4-Nitrophenol 400 ug/mL
Acenaphthene 200 ug/mL
Acenaphthylene 200 ug/mL
Acetophenone 200 ug/mL
Aniline 200 ug/mL
Anthracene 200 ug/mL
Azobenzene 200 ug/mL
Benzo[a]anthracene 200 ug/mL
Benzo[a]pyrene 200 ug/mL
Benzo[b]fluoranthene 200 ug/mL
Benzo[g,h,i]perylene 200 ug/mL
Benzo[k]fluoranthene 200 ug/mL
Benzyl alcohol 200 ug/mL
Bis(2-chloroethoxy)methane 200 ug/mL
Bis(2-chloroethyl)ether 200 ug/mL
Bis(2-ethylhexyl) phthalate 200 ug/mL
Butyl benzyl phthalate 200 ug/mL
Carbazole 200 ug/mL
Chrysene 200 ug/mL
Di-n-butyl phthalate 200 ug/mL
Di-n-octyl phthalate 200 ug/mL
Dibenz(a,h)anthracene 200 ug/mL
Dibenzofuran 200 ug/mL
Diethyl phthalate 200 ug/mL
Dimethyl phthalate 200 ug/mL
Diphenylamine 170 ug/mL
Fluoranthene 200 ug/mL
Fluorene 200 ug/mL
Hexachlorobenzene 200 ug/mL
Hexachlorobutadiene 200 ug/mL
Hexachlorocyclopentadiene 200 ug/mL
Hexachloroethane 200 ug/mL
Indeno[1,2,3-cd]pyrene 200 ug/mL
Isophorone 200 ug/mL
N-Nitrosodi-n-propylamine 200 ug/mL
N-Nitrosodimethylamine 200 ug/mL
N-Nitrosodiphenylamine 200 ug/mL
Page 77 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Naphthalene 200 ug/mL
Nitrobenzene 200 ug/mL
Pentachlorophenol 400 ug/mL
Phenanthrene 200 ug/mL
Phenol 200 ug/mL
Pyrene 200 ug/mL
Pyridine 400 ug/mL
2,4,6-Tribromophenol (Surr)200 ug/mL8270SurStkHL_00436 0.4 mL
2-Fluorobiphenyl 200 ug/mL
2-Fluorophenol (Surr)200 ug/mL
Nitrobenzene-d5 (Surr)200 ug/mL
Phenol-d5 (Surr)200 ug/mL
Terphenyl-d14 (Surr)200 ug/mL
Alachlor 200 ug/mLMS-568033.SEC_00002 0.5 mL
OP-569731_00078 2 mL Benzoic acid 400 ug/mL
09/30/24 (Purchased Reagent)1,1'-Biphenyl 1000 ug/mLRestek, Lot A0195772..571995_00165
1,2,4,5-Tetrachlorobenzene 1000 ug/mL
1,2,4-Trichlorobenzene 1000 ug/mL
1,2-Dichlorobenzene 1000 ug/mL
1,2-Diphenylhydrazine 1010.97 ug/mL
1,3-Dichlorobenzene 1000 ug/mL
1,3-Dinitrobenzene 1000 ug/mL
1,4-Dichlorobenzene 1000 ug/mL
1-Methylnaphthalene 1000 ug/mL
2,2'-oxybis[1-chloropropane]1000 ug/mL
2,3,4,6-Tetrachlorophenol 1000 ug/mL
2,4,5-Trichlorophenol 1000 ug/mL
2,4,6-Trichlorophenol 1000 ug/mL
2,4-Dichlorophenol 1000 ug/mL
2,4-Dimethylphenol 1000 ug/mL
2,4-Dinitrophenol 2000 ug/mL
2,4-Dinitrotoluene 1000 ug/mL
2,6-Dichlorophenol 1000 ug/mL
2,6-Dinitrotoluene 1000 ug/mL
2-Chloronaphthalene 1000 ug/mL
2-Chlorophenol 1000 ug/mL
2-Methylnaphthalene 1000 ug/mL
2-Methylphenol 1000 ug/mL
2-Nitroaniline 1000 ug/mL
2-Nitrophenol 1000 ug/mL
3 & 4 Methylphenol 1000 ug/mL
3-Nitroaniline 1000 ug/mL
4,6-Dinitro-2-methylphenol 2000 ug/mL
4-Bromophenyl phenyl ether 1000 ug/mL
4-Chloro-3-methylphenol 1000 ug/mL
4-Chloroaniline 1000 ug/mL
4-Chlorophenyl phenyl ether 1000 ug/mL
Page 78 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Nitroaniline 1000 ug/mL
4-Nitrophenol 2000 ug/mL
Acenaphthene 1000 ug/mL
Acenaphthylene 1000 ug/mL
Acetophenone 1000 ug/mL
Aniline 1000 ug/mL
Anthracene 1000 ug/mL
Azobenzene 1000 ug/mL
Benzo[a]anthracene 1000 ug/mL
Benzo[a]pyrene 1000 ug/mL
Benzo[b]fluoranthene 1000 ug/mL
Benzo[g,h,i]perylene 1000 ug/mL
Benzo[k]fluoranthene 1000 ug/mL
Benzyl alcohol 1000 ug/mL
Bis(2-chloroethoxy)methane 1000 ug/mL
Bis(2-chloroethyl)ether 1000 ug/mL
Bis(2-ethylhexyl) phthalate 1000 ug/mL
Butyl benzyl phthalate 1000 ug/mL
Carbazole 1000 ug/mL
Chrysene 1000 ug/mL
Di-n-butyl phthalate 1000 ug/mL
Di-n-octyl phthalate 1000 ug/mL
Dibenz(a,h)anthracene 1000 ug/mL
Dibenzofuran 1000 ug/mL
Diethyl phthalate 1000 ug/mL
Dimethyl phthalate 1000 ug/mL
Diphenylamine 850 ug/mL
Fluoranthene 1000 ug/mL
Fluorene 1000 ug/mL
Hexachlorobenzene 1000 ug/mL
Hexachlorobutadiene 1000 ug/mL
Hexachlorocyclopentadiene 1000 ug/mL
Hexachloroethane 1000 ug/mL
Indeno[1,2,3-cd]pyrene 1000 ug/mL
Isophorone 1000 ug/mL
N-Nitrosodi-n-propylamine 1000 ug/mL
N-Nitrosodimethylamine 1000 ug/mL
N-Nitrosodiphenylamine 1000 ug/mL
Naphthalene 1000 ug/mL
Nitrobenzene 1000 ug/mL
Pentachlorophenol 2000 ug/mL
Phenanthrene 1000 ug/mL
Phenol 1000 ug/mL
Pyrene 1000 ug/mL
Pyridine 2000 ug/mL
04/30/27 (Purchased Reagent)2,4,6-Tribromophenol (Surr)5000 ug/mLRestek, Lot A0184539..8270SurStkHL_00436
2-Fluorobiphenyl 5000 ug/mL
Page 79 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
2-Fluorophenol (Surr)5000 ug/mL
Nitrobenzene-d5 (Surr)5000 ug/mL
Phenol-d5 (Surr)5000 ug/mL
Terphenyl-d14 (Surr)5000 ug/mL
10/31/24 (Purchased Reagent)Alachlor 4000 ug/mLRestek, Lot A0196553..MS-568033.SEC_00002
07/31/24 (Purchased Reagent)Benzoic acid 2000 ug/mLRestek, Lot A0193718..OP-569731_00078
1,2-Dichloroethene, Totalmv-Cent BFB_00005
1,3-Dichloropropene, Total
Tentatively Identified
Compound
Total BTEX
Trihalomethanes, Total
Xylenes, Total
mv-IS/SS Tune_00001 10 mL BFB 50 ug/mL
11/30/23 (Purchased Reagent)BFB 250 ug/mLRestek, Lot A0143593.mv-IS/SS Tune_00001
1,2-Dichloroethene, Totalmv-Cent BFB_00006
1,3-Dichloropropene, Total
Tentatively Identified
Compound
Total BTEX
Trihalomethanes, Total
Xylenes, Total
mv-IS/SS Tune_00001 10 mL BFB 50 ug/mL
11/30/23 (Purchased Reagent)BFB 250 ug/mLRestek, Lot A0143593.mv-IS/SS Tune_00001
MV-569722_00022 Bromomethane 250 ug/mL12.5 mL 1250 uL11/06/23 10/05/23MV-Gas A_00168 P&T Methanol, Lot
198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00018 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
08/31/25 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0189184.MV-569722_00022
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
01/31/26 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0193735.MV-569723_00018
12/11/23 11/10/23 12.5 mL MV-569722_00023 1250 uL Vinyl chloride 250 ug/mLMV-Gas A_00172 P&T Methanol, Lot
198123
05/31/26 (Purchased Reagent)Vinyl chloride 2500 ug/mLRESTEK, Lot A0198219.MV-569722_00023
10/31/23 09/30/23 12.5 mL MV-569722.sec_00017 1250 uL Vinyl chloride 250 ug/mLMV-Gas B_00148 P&T Methanol, Lot
ea1899-us
Page 80 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
05/31/26 (Purchased Reagent)Vinyl chloride 2500 ug/mLRESTEK, Lot A0197640.MV-569722.sec_00017
mv-30241_00012 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL10/25/23 07/25/23mv-IS_SS_00066 P&T Methanol, Lot
198123
Chlorobenzene-d5 50 ug/mL
Fluorobenzene 50 ug/mL
1,2-Dichloroethane-d4 (Surr)50 ug/mLMV-567650_00030 1000 uL
4-Bromofluorobenzene (Surr)50 ug/mL
Dibromofluoromethane (Surr)50 ug/mL
Toluene-d8 (Surr)50 ug/mL
05/31/27 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0185733.mv-30241_00012
Chlorobenzene-d5 2500 ug/mL
Fluorobenzene 2500 ug/mL
05/31/26 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr)2500 ug/mLRestek, Lot A0172587.MV-567650_00030
4-Bromofluorobenzene (Surr)2500 ug/mL
Dibromofluoromethane (Surr)2500 ug/mL
Toluene-d8 (Surr)2500 ug/mL
mv-30241_00012 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL01/16/24 10/16/23mv-IS_SS_00071 P&T Methanol, Lot
198123
Chlorobenzene-d5 50 ug/mL
Fluorobenzene 50 ug/mL
05/31/27 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0185733.mv-30241_00012
Chlorobenzene-d5 2500 ug/mL
Fluorobenzene 2500 ug/mL
MV-567650_00030 1,2-Dichloroethane-d4 (Surr)50 ug/mL50 mL 1000 uL01/16/24 10/16/23mv-IS_SS_00071 P&T Methanol, Lot
198123
4-Bromofluorobenzene (Surr)50 ug/mL
Dibromofluoromethane (Surr)50 ug/mL
Toluene-d8 (Surr)50 ug/mL
05/31/26 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr)2500 ug/mLRestek, Lot A0172587.MV-567650_00030
4-Bromofluorobenzene (Surr)2500 ug/mL
Dibromofluoromethane (Surr)2500 ug/mL
Toluene-d8 (Surr)2500 ug/mL
MV-569721.sec_00011 2-Butanone (MEK)400 ug/mL25 mL 800 uL10/31/23 09/27/23MV-MegaMain B_00092 P&T Methanol, Lot
181124
1,1-Dichloroethene 100 ug/mLMV-571992.sec_00010 1000 uL
1,2-Dichloroethane 100 ug/mL
Benzene 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chloroform 100 ug/mL
Tetrachloroethene 100 ug/mL
Trichloroethene 100 ug/mL
02/28/26 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0194631.MV-569721.sec_00011
08/31/25 (Purchased Reagent)1,1-Dichloroethene 2500 ug/mLRESTEK, Lot A0195252.MV-571992.sec_00010
1,2-Dichloroethane 2500 ug/mL
Benzene 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Page 81 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chlorobenzene 2500 ug/mL
Chloroform 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Trichloroethene 2500 ug/mL
MV-568720_00046 Acrolein 987.5 ug/mL25 mL 1250 uL10/30/23 09/27/23MV-MegaMainA_00096 P&T Methanol, Lot
181124
2-Butanone (MEK)400 ug/mLMV-569721_00015 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00035 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00024 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00015 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluor
oethane
100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Page 82 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739.s_00011 2000 uL
2-Pentanone 320 ug/mL
sec-Butyl Alcohol 2400 ug/mL
07/31/24 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0193730.MV-568720_00046
01/31/26 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0193494.MV-569721_00015
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
01/31/24 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0187365.MV-569724_00035
04/30/26 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0197009.MV-569727_00024
Page 83 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
09/30/24 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0183568.MV-571992_00015
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluor
oethane
2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Page 84 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
05/31/24 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6676357.sec.MV-CUS17739.s_00011
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
MV-569721_00015 2-Butanone (MEK)400 ug/mL25 mL 800 uL12/11/23 11/10/23MV-MegaMainA_00099 P&T Methanol, Lot
181124
1,1-Dichloroethene 100 ug/mLMV-571992_00015 1000 uL
1,2-Dichloroethane 100 ug/mL
Benzene 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chloroform 100 ug/mL
Tetrachloroethene 100 ug/mL
Trichloroethene 100 ug/mL
01/31/26 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0193494.MV-569721_00015
09/30/24 (Purchased Reagent)1,1-Dichloroethene 2500 ug/mLRESTEK, Lot A0183568.MV-571992_00015
1,2-Dichloroethane 2500 ug/mL
Benzene 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chloroform 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Trichloroethene 2500 ug/mL
05/24/25 (Purchased Reagent)pH adj. to 25 deg C 7 SUOAKTON TRACEABLE, Lot CC778004pH 7.0 Buffer_00328
Page 85 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
11/30/24 (Purchased Reagent)pH adj. to 25 deg C 7 SUSPEX, Lot 9-128MFXpH 7.0 Buffer_00331
11/09/24 (Purchased Reagent)Mo 100 ug/mLInorganic Ventures, Lot U2-MEB734690Prep spike1IV_00014
Sb 100 ug/mL
Si 1000 ug/mL
SiO2 2140 ug/mL
Sn 100 ug/mL
Ti 100 ug/mL
Zr 100 ug/mL
11/09/24 (Purchased Reagent)Al 1000 ug/mLInorganic Ventures, Lot U2-MEB734691Prep spike2IV_00013
Arsenic 100 ug/mL
B 200 ug/mL
Barium 100 ug/mL
Be 100 ug/mL
Ca 5000 ug/mL
Cadmium 100 ug/mL
Chromium 100 ug/mL
Co 100 ug/mL
Cu 100 ug/mL
Fe 1000 ug/mL
K 5000 ug/mL
Lead 100 ug/mL
Li 100 ug/mL
Mg 5000 ug/mL
Mn 100 ug/mL
Na 5000 ug/mL
Ni 100 ug/mL
P 2000 ug/mL
Selenium 100 ug/mL
Silver 5 ug/mL
Sr 100 ug/mL
Sulfur 2000 ug/mL
Tl 100 ug/mL
V 100 ug/mL
Zn 100 ug/mL
50% NaOH_00023 Sodium Hydroxide 2000 mg/L500 mL 2 mL12/26/23 10/16/23SFD ICV INT_02379 ELGA Water, Lot N/A
SFD ICV STOCK_00001 3.08615
g
Sulfide 824.001 mg/L
01/31/24 (Purchased Reagent)Sodium Hydroxide 50 %RICCA, Lot 1102857.50% NaOH_00023
11/30/25 (Purchased Reagent)Sulfide 0.1335 g/gSupelco, Lot 206402.SFD ICV STOCK_00001
Page 86 of 1261
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-184424-1Eurofins Savannah
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
02/08/28 (Purchased Reagent)Ignitability 100 mm/secAWF, Lot -Wood Chips_00007
Page 87 of 1261
Reagent
1000 Li_00044
Page 88 of 1261
Page 89 of 1261
Page 90 of 1261
Reagent
1000 Zr_00025
Page 91 of 1261
Page 92 of 1261
Page 93 of 1261
Reagent
10000 S_00017
Page 94 of 1261
Page 95 of 1261
Page 96 of 1261
Reagent
50% NaOH_00023
Page 97 of 1261
Certificate of Analysis
448 West Fork Dr
Arlington, TX 76012
http://www.riccachemical.com
1-888-GO-RICCA
[e-mail]
Sodium Hydroxide, 50% (w/w) (760 g/L), Analytical Reagent Grade
Manufacture Date: FEB 05, 2021
Expiration Date: JAN 2024Lot Number: 1102857 Product Number: 7291
The specifications below are equivalent to the ACS Reagent Grade specifications for Sodium Hydroxide pellets, corrected for assay.
There is no ACS specification for 50% (w/w) Sodium Hydroxide solution.
Name CAS#Grade
Reagent7732-18-5Water
Reagent1310-73-2Sodium Hydroxide
Test ResultSpecification NIST SRM#
Appearance Passed Colorless liquid
Assay (vs. Sulfuric Acid/Phenolphthalein)50 % (w/w) 50-52 % (w/w)723
Chloride (Cl)< 0.002 % max 0.002 %
Heavy Metals (as Ag)< 0.001 % max 0.001 %
Iron (Fe)0.2 ppm max 5 ppm 3126
NH₄OH Precipitate 0.00009 % max 0.01 %
Nickel (Ni)< 1 ppm max 5 ppm 3136
Nitrogen Compounds (as N)< 5 ppm max 5 ppm
Phosphate (PO₄)< 5 ppm max 5 ppm
Potassium (K)0.002 % max 0.01 %3141
Sodium Carbonate (Na₂CO₃)0.02 % max 0.1 %
Sulfate (SO₄)< 0.001 % max 0.001 %
ReferenceSpecification
Sodium Hydroxide Solution, 50%ASTM (D 2187 E)
Sodium Hydroxide Solution, 50%ASTM (D 2187 F)
Sodium hydroxide stock solution, about 50%TAPPI (T 235 cm-85)
Sodium Hydroxide Solution ASTM (D 2187 G)
Sodium Hydroxide Solution, 50%ASTM (D 4548)
Sodium Hydroxide Solution (50% w/w)ASTM (D 2036 A)
Sodium Hydroxide Solution (50% w/w)ASTM (D 2036 B)
Sodium Hydroxide Solution (50% w/w)ASTM (D 2036 C)
Sodium Hydroxide Solution (50% w/w)ASTM (D 2036 D)
Volumetric glassware complies with Class A tolerance requirements of ASTM E 288 and NIST Circular 434; it is calibrated before first use and
recalibrated regularly in accordance with ASTM E 542 and NIST Procedure NBSIR 74-461. Balances are calibrated regularly with weights certified
traceable to the NIST national mass standard. Thermometers and temperature probes are calibrated before first use and recalibrated regularly with a
thermometer traceable to NIST standards. All products are prepared according to master documents that assure manufacture according to validated
methods. Batch records document raw material traceability and production and testing history for each lot manufactured.
Part Number Shelf Life (Unopened Container)Size / Package Type
7291-1 36 months4 L natural poly
7291-16 36 months500 mL natural poly
Version: 1.3 Product Number: 7291Lot Number: 1102857 Page 1 of 2
Page 98 of 1261
Recommended Storage: 15°C - 30°C (59°F - 86°F)
This Certificate of Analysis is designed to comply with ISO Guide 31 "Reference
Materials -- Contents of Certificates and Labels."
Quality Control Supervisor
Israel Alamudun (02/05/2021)
This test report shall not be reproduced, except in full, without the written approval of Ricca Chemical Company.
Version: 1.3 Product Number: 7291Lot Number: 1102857 Page 2 of 2
Page 99 of 1261
Reagent
571995_00165
Page 100 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :571995 Lot No.:A0190414
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
April 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 1,003.31,4-Dioxane
123-91-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8469
+/- 12.0005 µg/mL
+/- 19.0922 µg/mL
(Lot SHBN3770)
99%
2 µg/mL 1,006.7N-Nitrosodimethylamine
62-75-9CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8664
+/- 12.0403 µg/mL
+/- 19.1557 µg/mL
(Lot 220624JLM)
99%
3 µg/mL 2,011.7Pyridine
110-86-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6960
+/- 24.0476 µg/mL
+/- 38.2714 µg/mL
(Lot SHBN7324)
99%
4 µg/mL 1,006.3Phenol
108-95-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8644
+/- 12.0364 µg/mL
+/- 19.1493 µg/mL
(Lot MKCK1120)
99%
5 µg/mL 1,004.7Aniline
62-53-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8547
+/- 12.0164 µg/mL
+/- 19.1176 µg/mL
(Lot X22F726)
99%
6 µg/mL 1,004.0Bis(2-chloroethyl)ether
111-44-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8508
+/- 12.0084 µg/mL
+/- 19.1049 µg/mL
(Lot SHBL6942)
99%
7 µg/mL 1,007.2n-Decane (C10)
124-18-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8693
+/- 12.0463 µg/mL
+/- 19.1652 µg/mL
(Lot SHBN8619)
01-Aug-2020 rev.Page 1 of 8
Page 101 of 1261
99%
8 µg/mL 1,005.32-Chlorophenol
95-57-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8586
+/- 12.0244 µg/mL
+/- 19.1303 µg/mL
(Lot STBH7290)
99%
9 µg/mL 1,003.01,3-Dichlorobenzene
541-73-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8450
+/- 11.9965 µg/mL
+/- 19.0859 µg/mL
(Lot BCCD5315)
99%
10 µg/mL 1,005.31,4-Dichlorobenzene
106-46-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8586
+/- 12.0244 µg/mL
+/- 19.1303 µg/mL
(Lot MKBS4401V)
99%
11 µg/mL 1,003.3Benzyl alcohol
100-51-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8469
+/- 12.0005 µg/mL
+/- 19.0922 µg/mL
(Lot SHBK5943)
99%
12 µg/mL 1,005.31,2-Dichlorobenzene
95-50-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8586
+/- 12.0244 µg/mL
+/- 19.1303 µg/mL
(Lot SHBN3835)
99%
13 µg/mL 1,005.22-Methylphenol (o-cresol)
95-48-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8576
+/- 12.0224 µg/mL
+/- 19.1271 µg/mL
(Lot SHBN7598)
99%
14 µg/mL 1,006.72,2'-oxybis(1-chloropropane)
108-60-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8664
+/- 12.0403 µg/mL
+/- 19.1557 µg/mL
(Lot 12549200)
99%
15 µg/mL 1,005.0Acetophenone
98-86-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8567
+/- 12.0204 µg/mL
+/- 19.1240 µg/mL
(Lot STBH8205)
99%
16 µg/mL 503.73-Methylphenol (m-cresol)
108-39-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 2.9351
+/- 6.0242 µg/mL
+/- 9.5842 µg/mL
(Lot STBJ0710)
99%
17 µg/mL 503.04-Methylphenol (p-cresol)
106-44-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 2.9312
+/- 6.0162 µg/mL
+/- 9.5715 µg/mL
(Lot SHBN1151)
99%
18 µg/mL 1,002.7N-Nitroso-di-n-propylamine
621-64-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8431
+/- 11.9925 µg/mL
+/- 19.0796 µg/mL
(Lot 2D5VJ)
99%
19 µg/mL 1,003.3Hexachloroethane
67-72-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8469
+/- 12.0005 µg/mL
+/- 19.0922 µg/mL
(Lot QTORH)
99%
20 µg/mL 1,005.8Nitrobenzene
98-95-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8615
+/- 12.0304 µg/mL
+/- 19.1398 µg/mL
(Lot 10224044)
99%
21 µg/mL 1,004.3Isophorone
78-59-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8528
+/- 12.0124 µg/mL
+/- 19.1113 µg/mL
(Lot MKCC9506)
99%
22 µg/mL 1,003.22-Nitrophenol
88-75-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8460
+/- 11.9985 µg/mL
+/- 19.0891 µg/mL
(Lot BCCB2407)
99%
23 µg/mL 1,002.82,4-Dimethylphenol
105-67-9CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8440
+/- 11.9945 µg/mL
+/- 19.0827 µg/mL
(Lot XW5GK)
01-Aug-2020 rev.Page 2 of 8
Page 102 of 1261
99%
24 µg/mL 1,007.5Bis(2-chloroethoxy)methane
111-91-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8712
+/- 12.0503 µg/mL
+/- 19.1715 µg/mL
(Lot 13670200)
99%
25 µg/mL 1,002.22,4-Dichlorophenol
120-83-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8401
+/- 11.9865 µg/mL
+/- 19.0700 µg/mL
(Lot BCBZ6787)
99%
26 µg/mL 1,003.71,2,4-Trichlorobenzene
120-82-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8489
+/- 12.0045 µg/mL
+/- 19.0986 µg/mL
(Lot SHBM0526)
99%
27 µg/mL 1,003.3Naphthalene
91-20-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8469
+/- 12.0005 µg/mL
+/- 19.0922 µg/mL
(Lot MKCH0219)
99%
28 µg/mL 1,007.72,6-Dichlorophenol
87-65-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8722
+/- 12.0523 µg/mL
+/- 19.1747 µg/mL
(Lot MKCP7682)
99%
29 µg/mL 1,007.74-Chloroaniline
106-47-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8722
+/- 12.0523 µg/mL
+/- 19.1747 µg/mL
(Lot H24K)
99%
30 µg/mL 1,004.0Hexachlorobutadiene
87-68-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8508
+/- 12.0084 µg/mL
+/- 19.1049 µg/mL
(Lot X05J)
99%
31 µg/mL 1,002.34-Chloro-3-methylphenol
59-50-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8411
+/- 11.9885 µg/mL
+/- 19.0732 µg/mL
(Lot BCCD4461)
96%
32 µg/mL 1,009.12-Methylnaphthalene
91-57-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8807
+/- 12.0697 µg/mL
+/- 19.2024 µg/mL
(Lot STBK0259)
99%
33 µg/mL 1,004.21-Methylnaphthalene
90-12-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8518
+/- 12.0104 µg/mL
+/- 19.1081 µg/mL
(Lot 5234.00-3)
99%
34 µg/mL 1,007.31,2,4,5-Tetrachlorobenzene
95-94-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8703
+/- 12.0483 µg/mL
+/- 19.1684 µg/mL
(Lot 13278000)
99%
35 µg/mL 1,003.3Hexachlorocyclopentadiene
77-47-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8469
+/- 12.0005 µg/mL
+/- 19.0922 µg/mL
(Lot 0012019)
99%
36 µg/mL 1,004.72,4,6-Trichlorophenol
88-06-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8547
+/- 12.0164 µg/mL
+/- 19.1176 µg/mL
(Lot STBJ5914)
98%
37 µg/mL 1,006.82,4,5-Trichlorophenol
95-95-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8671
+/- 12.0418 µg/mL
+/- 19.1580 µg/mL
(Lot FHN01)
99%
38 µg/mL 1,007.02-Chloronaphthalene
91-58-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8683
+/- 12.0443 µg/mL
+/- 19.1620 µg/mL
(Lot RPN7O)
99%
39 µg/mL 1,003.7Biphenyl
92-52-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8489
+/- 12.0045 µg/mL
+/- 19.0986 µg/mL
(Lot MKCL6515)
01-Aug-2020 rev.Page 3 of 8
Page 103 of 1261
99%
40 µg/mL 1,003.72-Nitroaniline
88-74-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8489
+/- 12.0045 µg/mL
+/- 19.0986 µg/mL
(Lot MKCJ8895)
96%
41 µg/mL 1,004.2Acenaphthylene
208-96-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8518
+/- 12.0104 µg/mL
+/- 19.1080 µg/mL
(Lot Q24W)
99%
42 µg/mL 1,002.71,3-Dinitrobenzene
99-65-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8431
+/- 11.9925 µg/mL
+/- 19.0796 µg/mL
(Lot 1-DXX-24-1)
99%
43 µg/mL 1,008.0Dimethylphthalate
131-11-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8741
+/- 12.0563 µg/mL
+/- 19.1811 µg/mL
(Lot 10117699)
99%
44 µg/mL 1,005.32,6-Dinitrotoluene
606-20-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8586
+/- 12.0244 µg/mL
+/- 19.1303 µg/mL
(Lot BCCG1833)
99%
45 µg/mL 1,008.73-Nitroaniline
99-09-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8780
+/- 12.0643 µg/mL
+/- 19.1937 µg/mL
(Lot MKCH5457)
99%
46 µg/mL 1,000.0Acenaphthene
83-32-9CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8275
+/- 11.9606 µg/mL
+/- 19.0288 µg/mL
(Lot MKCQ4733)
99%
47 µg/mL 2,016.32,4-Dinitrophenol
51-28-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.7231
+/- 24.1034 µg/mL
+/- 38.3602 µg/mL
(Lot STBK5145-DR3)
99%
48 µg/mL 1,002.0Dibenzofuran
132-64-9CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8392
+/- 11.9845 µg/mL
+/- 19.0669 µg/mL
(Lot MKCN1772)
99%
49 µg/mL 2,007.54-Nitrophenol
100-02-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6718
+/- 23.9978 µg/mL
+/- 38.1921 µg/mL
(Lot MKCN1089)
99%
50 µg/mL 1,003.82,4-Dinitrotoluene
121-14-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8499
+/- 12.0065 µg/mL
+/- 19.1018 µg/mL
(Lot MKAA0690V)
99%
51 µg/mL 1,002.72,3,4,6-Tetrachlorophenol
58-90-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8431
+/- 11.9925 µg/mL
+/- 19.0796 µg/mL
(Lot PR-30126)
99%
52 µg/mL 1,006.8Fluorene
86-73-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8673
+/- 12.0423 µg/mL
+/- 19.1588 µg/mL
(Lot 094650L18G)
98%
53 µg/mL 1,004.8n-Hexadecane (C16)
544-76-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8556
+/- 12.0183 µg/mL
+/- 19.1207 µg/mL
(Lot SHBM4146)
99%
54 µg/mL 1,008.2Diethylphthalate
84-66-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8751
+/- 12.0583 µg/mL
+/- 19.1842 µg/mL
(Lot BCCD3396)
99%
55 µg/mL 1,005.24-Chlorophenyl phenyl ether
7005-72-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8576
+/- 12.0224 µg/mL
+/- 19.1271 µg/mL
(Lot MKCQ0984)
01-Aug-2020 rev.Page 4 of 8
Page 104 of 1261
99%
56 µg/mL 1,005.54-Nitroaniline
100-01-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8596
+/- 12.0264 µg/mL
+/- 19.1335 µg/mL
(Lot RP220906)
99%
57 µg/mL 2,012.04,6-Dinitro-2-methylphenol (Dinitro-o-cresol)
534-52-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6979
+/- 24.0516 µg/mL
+/- 38.2777 µg/mL
(Lot RP220915)
99%
58 µg/mL 853.5Diphenylamine
122-39-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 4.9738
+/- 10.2084 µg/mL
+/- 16.2411 µg/mL
(Lot MKCH1042)
99%
59 µg/mL 1,001.8Azobenzene
103-33-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8382
+/- 11.9825 µg/mL
+/- 19.0637 µg/mL
(Lot BCCC9136)
99%
60 µg/mL 1,007.24-Bromophenyl phenyl ether
101-55-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8693
+/- 12.0463 µg/mL
+/- 19.1652 µg/mL
(Lot STBH6361)
99%
61 µg/mL 1,006.0Hexachlorobenzene
118-74-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8625
+/- 12.0324 µg/mL
+/- 19.1430 µg/mL
(Lot 13562400)
99%
62 µg/mL 2,016.7Pentachlorophenol
87-86-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.7251
+/- 24.1074 µg/mL
+/- 38.3665 µg/mL
(Lot 211229RSR)
98%
63 µg/mL 1,007.4n-Octadecane (C18)
593-45-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8709
+/- 12.0496 µg/mL
+/- 19.1704 µg/mL
(Lot UE5NG)
99%
64 µg/mL 1,002.0Phenanthrene
85-01-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8392
+/- 11.9845 µg/mL
+/- 19.0669 µg/mL
(Lot MKCQ2033)
99%
65 µg/mL 1,004.2Anthracene
120-12-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8518
+/- 12.0104 µg/mL
+/- 19.1081 µg/mL
(Lot MKCP3968)
99%
66 µg/mL 1,002.8Carbazole
86-74-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8440
+/- 11.9945 µg/mL
+/- 19.0827 µg/mL
(Lot 13058900)
99%
67 µg/mL 1,001.2Di-n-butylphthalate
84-74-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8343
+/- 11.9746 µg/mL
+/- 19.0510 µg/mL
(Lot MKCN4337)
99%
68 µg/mL 1,005.8Fluoranthene
206-44-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8615
+/- 12.0304 µg/mL
+/- 19.1398 µg/mL
(Lot MKCQ4728)
99%
69 µg/mL 1,006.7Pyrene
129-00-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8664
+/- 12.0403 µg/mL
+/- 19.1557 µg/mL
(Lot BCCG7845)
99%
70 µg/mL 1,008.5Benzyl butyl phthalate
85-68-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8771
+/- 12.0623 µg/mL
+/- 19.1906 µg/mL
(Lot MKCN9008)
96%
71 µg/mL 1,001.9Benz(a)anthracene
56-55-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8387
+/- 11.9836 µg/mL
+/- 19.0654 µg/mL
(Lot RP220209)
01-Aug-2020 rev.Page 5 of 8
Page 105 of 1261
99%
72 µg/mL 1,007.0Chrysene
218-01-9CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8683
+/- 12.0443 µg/mL
+/- 19.1620 µg/mL
(Lot 468677L08C)
99%
73 µg/mL 1,004.7Bis(2-ethylhexyl)phthalate
117-81-7CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8547
+/- 12.0164 µg/mL
+/- 19.1176 µg/mL
(Lot MKCQ3468)
99%
74 µg/mL 1,006.5Di-n-octyl phthalate
117-84-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8654
+/- 12.0383 µg/mL
+/- 19.1525 µg/mL
(Lot 13651900)
99%
75 µg/mL 1,001.3Benzo(b)fluoranthene
205-99-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8353
+/- 11.9765 µg/mL
+/- 19.0542 µg/mL
(Lot 012022B)
99%
76 µg/mL 1,005.7Benzo(k)fluoranthene
207-08-9CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8605
+/- 12.0284 µg/mL
+/- 19.1367 µg/mL
(Lot 012022K)
99%
77 µg/mL 1,004.7Benzo(a)pyrene
50-32-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8547
+/- 12.0164 µg/mL
+/- 19.1176 µg/mL
(Lot Z8BKF)
99%
78 µg/mL 1,002.5Indeno(1,2,3-cd)pyrene
193-39-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8421
+/- 11.9905 µg/mL
+/- 19.0764 µg/mL
(Lot 8-URV-39-3)
99%
79 µg/mL 1,007.3Dibenz(a,h)anthracene
53-70-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8703
+/- 12.0483 µg/mL
+/- 19.1684 µg/mL
(Lot ER032211-01)
98%
80 µg/mL 1,003.4Benzo(g,h,i)perylene
191-24-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8471
+/- 12.0008 µg/mL
+/- 19.0927 µg/mL
(Lot PMEVE)
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Specific Reference Material Notes:
01-Aug-2020 rev.Page 6 of 8
Page 106 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance:
17-Oct-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Oct-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 7 of 8
Page 107 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 8 of 8
Page 108 of 1261
Reagent
571995_00171
Page 109 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 110 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 111 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 112 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 113 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 114 of 1261
Reagent
571995_00172
Page 115 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 116 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 117 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 118 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 119 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 120 of 1261
Reagent
571995_00173
Page 121 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 122 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 123 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 124 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 125 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 126 of 1261
Reagent
571995_00174
Page 127 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 128 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 129 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 130 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 131 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 132 of 1261
Reagent
571995_00178
Page 133 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 134 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 135 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 136 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 137 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 138 of 1261
Reagent
571995_00179
Page 139 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 140 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 141 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 142 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 143 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 144 of 1261
Reagent
571995_00180
Page 145 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 146 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 147 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 148 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 149 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 150 of 1261
Reagent
571995_00181
Page 151 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571995 Lot No.:A0195772
8270 List 1 / Std #1 MegaMix (2017)Description :
8270 List 1 / Std #1 MegaMix (2017) 500-2,000 µg/mL, Methylene
chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
10 mL > 5 mLPkg Amt:
Handling:Carcinogen/reproductive toxin.
Photosensitive. Sonicate.
September 30, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 1,005.41,4-Dioxane 123-91-1 +/- 18.5755SHBN3770
99% 2 µg/mL 1,005.2N-Nitrosodimethylamine 62-75-9 +/- 18.5718230209JLM
99% 3 µg/mL 2,010.1Pyridine110-86-1 +/- 37.1374SHBN7324
99% 4 µg/mL 1,005.1Phenol108-95-2 +/- 18.5706MKCK1120
99% 5 µg/mL 1,005.2Aniline62-53-3 +/- 18.5718X22F726
99% 6 µg/mL 1,005.0Bis(2-chloroethyl)ether 111-44-4 +/- 18.5681SHBL6942
99% 7 µg/mL 1,004.9n-Decane (C10)124-18-5 +/- 18.5669SHBN8619
99% 8 µg/mL 1,005.12-Chlorophenol 95-57-8 +/- 18.5706STBJ3909
99% 9 µg/mL 1,004.91,3-Dichlorobenzene 541-73-1 +/- 18.5669BCCD5315
99% 10 µg/mL 1,005.11,4-Dichlorobenzene 106-46-7 +/- 18.5706MKBS4401V
99% 11 µg/mL 1,004.9Benzyl alcohol 100-51-6 +/- 18.5669SHBK5943
99% 12 µg/mL 1,005.11,2-Dichlorobenzene 95-50-1 +/- 18.5706SHBN3835
99% 13 µg/mL 1,005.32-Methylphenol (o-cresol)95-48-7 +/- 18.5743SHBN7598
99% 14 µg/mL 1,005.32,2'-oxybis(1-chloropropane)108-60-1 +/- 18.57302-KMW-57-8
99% 15 µg/mL 1,005.4Acetophenone98-86-2 +/- 18.5755STBH8205
99% 16 µg/mL 502.33-Methylphenol (m-cresol)108-39-4 +/- 9.2831STBJ0710
01-Nov-2022 rev.Page 1 of 5
Page 152 of 1261
99% 17 µg/mL 502.74-Methylphenol (p-cresol)106-44-5 +/- 9.2893SHBN1151
99% 18 µg/mL 1,005.1N-Nitroso-di-n-propylamine 621-64-7 +/- 18.57062D5VJ
99% 19 µg/mL 1,004.9Hexachloroethane67-72-1 +/- 18.5656QTORH
99% 20 µg/mL 1,004.9Nitrobenzene98-95-3 +/- 18.565610224044
99% 21 µg/mL 1,005.1Isophorone78-59-1 +/- 18.5706MKCC9506
99% 22 µg/mL 1,004.92-Nitrophenol 88-75-5 +/- 18.5669BCCB2407
99% 23 µg/mL 1,005.22,4-Dimethylphenol 105-67-9 +/- 18.5718XW5GK
99% 24 µg/mL 1,004.9Bis(2-chloroethoxy)methane 111-91-1 +/- 18.566913670200
99% 25 µg/mL 1,005.42,4-Dichlorophenol 120-83-2 +/- 18.5755BCBZ6787
99% 26 µg/mL 1,005.21,2,4-Trichlorobenzene 120-82-1 +/- 18.5718SHBM0526
99% 27 µg/mL 1,004.7Naphthalene91-20-3 +/- 18.5619MKCH0219
99% 28 µg/mL 1,005.02,6-Dichlorophenol 87-65-0 +/- 18.5681MKCP7682
99% 29 µg/mL 1,004.94-Chloroaniline 106-47-8 +/- 18.5669H24K
99% 30 µg/mL 1,004.9Hexachlorobutadiene87-68-3 +/- 18.5669664800
99% 31 µg/mL 1,004.94-Chloro-3-methylphenol 59-50-7 +/- 18.5656BCCD4461
96% 32 µg/mL 1,005.02-Methylnaphthalene 91-57-6 +/- 18.5680STBK0259
99% 33 µg/mL 1,005.11-Methylnaphthalene 90-12-0 +/- 18.57065234.00-3
99% 34 µg/mL 1,005.21,2,4,5-Tetrachlorobenzene 95-94-3 +/- 18.5718MKCS1444
99% 35 µg/mL 1,005.2Hexachlorocyclopentadiene77-47-4 +/- 18.57180012019
99% 36 µg/mL 1,004.92,4,6-Trichlorophenol 88-06-2 +/- 18.5656STBJ5914
98% 37 µg/mL 1,005.12,4,5-Trichlorophenol 95-95-4 +/- 18.5697FHN01
99% 38 µg/mL 1,004.92-Chloronaphthalene 91-58-7 +/- 18.5669RPN7O
99% 39 µg/mL 1,005.3Biphenyl92-52-4 +/- 18.5743MKCJ6240
99% 40 µg/mL 1,005.02-Nitroaniline 88-74-4 +/- 18.5681MKCK7278
96% 41 µg/mL 1,005.0Acenaphthylene208-96-8 +/- 18.5680U25W
99% 42 µg/mL 1,005.31,3-Dinitrobenzene 99-65-0 +/- 18.57431-DXX-24-1
99% 43 µg/mL 1,005.1Dimethylphthalate131-11-3 +/- 18.570610117699
99% 44 µg/mL 1,005.02,6-Dinitrotoluene 606-20-2 +/- 18.5681BCCG1833
99% 45 µg/mL 1,005.13-Nitroaniline 99-09-2 +/- 18.5706MKCH5457
99% 46 µg/mL 1,004.7Acenaphthene83-32-9 +/- 18.5619MKCR7169
99% 47 µg/mL 2,010.02,4-Dinitrophenol 51-28-5 +/- 37.1362DR221221RSR
99% 48 µg/mL 1,005.3Dibenzofuran132-64-9 +/- 18.5743MKCN1772
99% 49 µg/mL 2,009.84-Nitrophenol 100-02-7 +/- 37.1325MKCN1089
99% 50 µg/mL 1,005.22,4-Dinitrotoluene 121-14-2 +/- 18.5718MKAA0690V
99% 51 µg/mL 1,004.82,3,4,6-Tetrachlorophenol 58-90-2 +/- 18.5644PR-30126
99% 52 µg/mL 1,005.3Fluorene86-73-7 +/- 18.574310217947
01-Nov-2022 rev.Page 2 of 5
Page 153 of 1261
99% 53 µg/mL 1,004.9n-Hexadecane (C16)544-76-3 +/- 18.5669SHBQ0897
99% 54 µg/mL 1,005.2Diethylphthalate84-66-2 +/- 18.5718BCCD3396
99% 55 µg/mL 1,005.14-Chlorophenyl phenyl ether 7005-72-3 +/- 18.5693MKCQ0984
99% 56 µg/mL 1,005.04-Nitroaniline 100-01-6 +/- 18.5681RP230111
99% 57 µg/mL 2,010.34,6-Dinitro-2-methylphenol (Dinitro-o-cresol)534-52-1 +/- 37.1411221221JIM
99% 58 µg/mL 854.3Diphenylamine122-39-4 +/- 15.7844MKCH1042
99% 59 µg/mL 1,004.9Azobenzene103-33-3 +/- 18.5656BCCC9136
99% 60 µg/mL 1,004.84-Bromophenyl phenyl ether 101-55-3 +/- 18.5644STBB9729V
99% 61 µg/mL 1,004.9Hexachlorobenzene118-74-1 +/- 18.566913994200
99% 62 µg/mL 2,010.1Pentachlorophenol87-86-5 +/- 37.1374RP221012
98% 63 µg/mL 1,005.0n-Octadecane (C18)593-45-3 +/- 18.5685UE5NG
99% 64 µg/mL 1,004.9Phenanthrene85-01-8 +/- 18.5669MKCQ2033
99% 65 µg/mL 1,005.4Anthracene120-12-7 +/- 18.5755MKCP3968
99% 66 µg/mL 1,005.1Carbazole86-74-8 +/- 18.569313058900
99% 67 µg/mL 1,005.3Di-n-butylphthalate 84-74-2 +/- 18.5730MKCN4337
99% 68 µg/mL 1,005.1Fluoranthene206-44-0 +/- 18.5693MKCQ4728
99% 69 µg/mL 1,005.1Pyrene129-00-0 +/- 18.5706BCCG7845
99% 70 µg/mL 1,005.1Benzyl butyl phthalate 85-68-7 +/- 18.5693MKCN9008
99% 71 µg/mL 1,005.1Benz(a)anthracene 56-55-3 +/- 18.57060012022BAA
99% 72 µg/mL 1,004.9Chrysene218-01-9 +/- 18.5669468677R25M
99% 73 µg/mL 1,005.0Bis(2-ethylhexyl)phthalate 117-81-7 +/- 18.5681MKCQ3468
99% 74 µg/mL 1,005.3Di-n-octyl phthalate 117-84-0 +/- 18.574313651900
99% 75 µg/mL 1,004.9Benzo(b)fluoranthene 205-99-2 +/- 18.5669012022B
99% 76 µg/mL 1,005.1Benzo(k)fluoranthene 207-08-9 +/- 18.5693012022K
99% 77 µg/mL 1,005.1Benzo(a)pyrene 50-32-8 +/- 18.5706J6IUE
99% 78 µg/mL 1,005.3Indeno(1,2,3-cd)pyrene 193-39-5 +/- 18.573012-JKL-118-9
99% 79 µg/mL 1,005.1Dibenz(a,h)anthracene 53-70-3 +/- 18.5706ER032211-01
98% 80 µg/mL 1,005.2Benzo(g,h,i)perylene 191-24-2 +/- 18.5721PMEVE
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
Page 154 of 1261
Specific Reference Material Notes:
N-nitrosodiphenylamine 1000 ug/mL equivalent when used for GC analysis . Actual formulation is diphenylamine 855 ug/mL.
N-Nitrosodiphenylamine is prone to breakdown in the injection port and will be converted to diphenylamine.
N-Nitrosodiphenylamine is also a reactive species that can initiate premature decomposition of other compounds in the mix. For
these reasons diphenylamine is used in the preparation of this mixture. When comparing the response of this compound to
mixtures manufactured using N-nitrosodiphenylamine, a difference in response will be observed .
This lot was approved even though the %D for 4,6-DN-2-MP was greater than 10%.
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant flow 1.8 mL/min.
80°C (hold 0.1 min.) to 330°C
@ 9.6°C/min. (hold 2.86 min.)
250°C
340°C
FID
B442140311Balance Serial #
05-Apr-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Mar-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
100 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
Page 155 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
Page 156 of 1261
Reagent
8270_LCS_Main_00090
Page 157 of 1261
Report Date: 14-Nov-2023 08:40:40 Chrom Revision: 2.3 11-Nov-2023 18:09:06
Preliminary Report
Eurofins Denver
LCS, Lab Control Sample Report
Sample Path:\\chromfs\Denver\ChromData\SMS_G6\20231113-127593.b\G6_111323040.D
Lims ID:LCS check Inj. Date:14-Nov-2023 04:28:30
Worklist ID:280-0127593-036 Instrument:SMS_G6
Method:SMSG6_8270C
Compound
Amount
Added
Amount
Recovered %Rec
Limits 1
3510C
16 1,4-Dioxane 80.0 61.5 76.9 0-0
17 N-Nitrosodimethylamine 80.0 64.8 81.0 21-120
18 Pyridine 160.0 131.4 82.1 10-120
29 Phenol 80.0 67.5 84.4 28-120
28 Aniline 80.0 64.5 80.7 13-120
32 Bis(2-chloroethyl)ether 80.0 64.9 81.1 43-118
33 2-Chlorophenol 80.0 64.3 80.3 38-117
34 n-Decane 80.0 62.2 77.7
35 1,3-Dichlorobenzene 80.0 65.4 81.7 28-110
37 1,4-Dichlorobenzene 80.0 65.3 81.7 29-112
39 Benzyl alcohol 80.0 69.6 87.1 31-112
40 1,2-Dichlorobenzene 80.0 66.4 83.0 32-111
41 Indene 80.0 65.8 82.2
42 2-Methylphenol 80.0 69.4 86.7 30-117
43 2,2'-oxybis[1-chloropro 80.0 65.4 81.7 32-120
45 Acetophenone 80.0 66.6 83.2 46-118
46 N-Nitrosodi-n-propylami 80.0 69.1 86.3 49-119
49 3 &4 Methylphenol 80.0 69.4 86.7 29-110
47 4-Methylphenol 80.0 69.4 86.7
48 3-Methylphenol 80.0 69.4 86.7
52 Hexachloroethane 80.0 62.4 78.0 21-115
53 Nitrobenzene 80.0 67.1 83.9 45-121
55 Isophorone 80.0 73.0 91.3 42-124
56 2-Nitrophenol 80.0 66.3 82.9 47-123
58 2,4-Dimethylphenol 80.0 69.5 86.9 31-124
60 Bis(2-chloroethoxy)meth 80.0 73.0 91.3 48-120
63 Benzoic acid 80.0 61.5 76.9 10-120
62 2,4-Dichlorophenol 80.0 75.1 93.9 47-121
66 1,2,4-Trichlorobenzene 80.0 69.4 86.7 29-116
67 Naphthalene 80.0 68.5 85.6 40-121
69 4-Chloroaniline 80.0 74.8 93.5 33-117
68 2,6-Dichlorophenol 80.0 75.1 93.8 50-118
71 Hexachlorobutadiene 80.0 70.5 88.2 22-124
77 4-Chloro-3-methylphenol 80.0 74.0 92.6 52-119
80 2-Methylnaphthalene 80.0 71.6 89.5 40-121
81 1-Methylnaphthalene 80.0 71.9 89.9 41-119
83 Hexachlorocyclopentadie 160.4 147.6 92.0 10-120
84 1,2,4,5-Tetrachlorobenz 80.0 77.5 96.9 35-121
87 2,4,6-Trichlorophenol 80.0 83.8 104.8 50-125
88 2,4,5-Trichlorophenol 80.0 81.5 101.9 53-123
90 1,1'-Biphenyl 80.0 71.4 89.2 49-115
Page 158 of 1261
Report Date: 14-Nov-2023 08:40:40 Chrom Revision: 2.3 11-Nov-2023 18:09:06
Preliminary Report
Sample Path:\\chromfs\Denver\ChromData\SMS_G6\20231113-127593.b\G6_111323040.D
Compound
Amount
Added
Amount
Recovered %Rec
Limits 1
3510C
91 2-Chloronaphthalene 80.0 74.1 92.6 40-116
93 2-Nitroaniline 80.0 75.6 94.5 55-127
96 Dimethyl phthalate 80.0 76.9 96.1 45-127
97 1,3-Dinitrobenzene 80.0 79.5 99.4 49-128
98 2,6-Dinitrotoluene 80.0 79.0 98.8 57-124
99 Acenaphthylene 80.0 75.3 94.1 41-130
100 3-Nitroaniline 80.0 75.4 94.2 41-128
101 Acenaphthene 80.0 72.3 90.4 47-122
102 2,4-Dinitrophenol 160.0 83.5 52.2 23-143
107 4-Nitrophenol 160.0 148.4 92.7 31-120
108 Dibenzofuran 80.0 75.6 94.5 53-118
109 2,4-Dinitrotoluene 80.0 77.3 96.7 57-128
114 2,3,4,6-Tetrachlorophen 80.0 81.5 101.9 50-128
116 Diethyl phthalate 80.0 77.2 96.4 56-125
117 Hexadecane 80.0 73.7 92.1
118 Fluorene 80.0 77.0 96.2 52-124
120 4-Chlorophenyl phenyl e 80.0 76.0 95.0 53-121
122 4-Nitroaniline 80.0 75.3 94.1 49-122
123 4,6-Dinitro-2-methylphe 160.0 120.4 75.3 44-137
126 N-Nitrosodiphenylamine 80.0 79.0 98.7 51-123
125 Diphenylamine 68.0 65.1 95.7 55-111
128 1,2-Diphenylhydrazine 80.9 75.8 93.7 49-122
129 Azobenzene 80.0 74.9 93.7 61-116
138 4-Bromophenyl phenyl et 80.0 81.4 101.8 55-124
140 Hexachlorobenzene 80.0 72.7 90.9 53-125
143 Pentachlorophenol 160.0 139.7 87.3 35-138
288 n-Octadecane 80.0 77.3 96.7
148 Phenanthrene 80.0 79.6 99.5 59-120
151 Anthracene 80.0 79.3 99.2 57-123
152 Carbazole 80.0 80.2 100.3 60-122
155 Di-n-butyl phthalate 80.0 78.9 98.6 59-127
160 Fluoranthene 80.0 79.4 99.2 57-128
162 Pyrene 80.0 76.3 95.4 57-126
169 Butyl benzyl phthalate 80.0 75.9 94.8 53-134
173 Benzo[a]anthracene 80.0 76.2 95.3 58-125
175 Chrysene 80.0 82.7 103.4 59-123
176 Bis(2-ethylhexyl)phtha 80.0 73.3 91.6 55-135
178 Di-n-octyl phthalate 80.0 70.8 88.5 51-140
179 Benzo[b]fluoranthene 80.0 76.7 95.9 53-131
181 Benzo[k]fluoranthene 80.0 86.9 108.7 57-129
183 Benzo[a]pyrene 80.0 82.2 102.7 54-128
187 Indeno[1,2,3-cd]pyrene 80.0 64.1 80.1 52-134
188 Dibenz(a,h)anthracene 80.0 83.7 104.7 51-134
189 Benzo[g,h,i]perylene 80.0 80.9 101.1 50-134
Page 159 of 1261
Report Date: 14-Nov-2023 08:40:40 Chrom Revision: 2.3 11-Nov-2023 18:09:06
Preliminary Report
Sample Path: \\chromfs\Denver\ChromData\SMS_G6\20231113-127593.b\G6_111323040.D
Samples for Limit Group: 1, Lims Prep Method: 3510C
280-183855-A-3-A 280-183855-A-4-A
Page 160 of 1261
Reagent
8270SurStkHL_00434
Page 161 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567685 Lot No.:A0184539
8270 Surrogate StandardDescription :
8270 Surrogate Standard 5,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonicate prior to use.
April 30, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 5,023.52-Fluorophenol
367-12-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.2073
+/- 146.6035 µg/mL
+/- 177.8977 µg/mL
(Lot STBJ3299)
99%
2 µg/mL 5,000.1Phenol-d5
4165-62-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0708
+/- 145.9187 µg/mL
+/- 177.0667 µg/mL
(Lot GH-100)
99%
3 µg/mL 5,012.6Nitrobenzene-d5
4165-60-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1437
+/- 146.2845 µg/mL
+/- 177.5106 µg/mL
(Lot PR-29940A)
99%
4 µg/mL 5,004.92-Fluorobiphenyl
321-60-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0991
+/- 146.0607 µg/mL
+/- 177.2391 µg/mL
(Lot 00021384)
99%
5 µg/mL 5,009.72,4,6-Tribromophenol
118-79-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1270
+/- 146.2008 µg/mL
+/- 177.4091 µg/mL
(Lot MKCJ7664)
99%
6 µg/mL 5,005.8p-Terphenyl-d14
1718-51-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1042
+/- 146.0860 µg/mL
+/- 177.2698 µg/mL
(Lot PR-30504)
01-Aug-2020 rev.Page 1 of 3
Page 162 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Due to the limited solubility of p-terphenyl-d14 in methanol, we do not recommend that this mixture be diluted in methanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
40°C (hold 2 min.) to 330°C
@ 10°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
29-Apr-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Apr-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 163 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 164 of 1261
Reagent
8270SurStkHL_00435
Page 165 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567685 Lot No.:A0184539
8270 Surrogate StandardDescription :
8270 Surrogate Standard 5,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonicate prior to use.
April 30, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 5,023.52-Fluorophenol
367-12-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.2073
+/- 146.6035 µg/mL
+/- 177.8977 µg/mL
(Lot STBJ3299)
99%
2 µg/mL 5,000.1Phenol-d5
4165-62-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0708
+/- 145.9187 µg/mL
+/- 177.0667 µg/mL
(Lot GH-100)
99%
3 µg/mL 5,012.6Nitrobenzene-d5
4165-60-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1437
+/- 146.2845 µg/mL
+/- 177.5106 µg/mL
(Lot PR-29940A)
99%
4 µg/mL 5,004.92-Fluorobiphenyl
321-60-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0991
+/- 146.0607 µg/mL
+/- 177.2391 µg/mL
(Lot 00021384)
99%
5 µg/mL 5,009.72,4,6-Tribromophenol
118-79-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1270
+/- 146.2008 µg/mL
+/- 177.4091 µg/mL
(Lot MKCJ7664)
99%
6 µg/mL 5,005.8p-Terphenyl-d14
1718-51-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1042
+/- 146.0860 µg/mL
+/- 177.2698 µg/mL
(Lot PR-30504)
01-Aug-2020 rev.Page 1 of 3
Page 166 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Due to the limited solubility of p-terphenyl-d14 in methanol, we do not recommend that this mixture be diluted in methanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
40°C (hold 2 min.) to 330°C
@ 10°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
29-Apr-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Apr-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 167 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 168 of 1261
Reagent
8270SurStkHL_00436
Page 169 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567685 Lot No.:A0184539
8270 Surrogate StandardDescription :
8270 Surrogate Standard 5,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonicate prior to use.
April 30, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 5,023.52-Fluorophenol
367-12-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.2073
+/- 146.6035 µg/mL
+/- 177.8977 µg/mL
(Lot STBJ3299)
99%
2 µg/mL 5,000.1Phenol-d5
4165-62-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0708
+/- 145.9187 µg/mL
+/- 177.0667 µg/mL
(Lot GH-100)
99%
3 µg/mL 5,012.6Nitrobenzene-d5
4165-60-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1437
+/- 146.2845 µg/mL
+/- 177.5106 µg/mL
(Lot PR-29940A)
99%
4 µg/mL 5,004.92-Fluorobiphenyl
321-60-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0991
+/- 146.0607 µg/mL
+/- 177.2391 µg/mL
(Lot 00021384)
99%
5 µg/mL 5,009.72,4,6-Tribromophenol
118-79-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1270
+/- 146.2008 µg/mL
+/- 177.4091 µg/mL
(Lot MKCJ7664)
99%
6 µg/mL 5,005.8p-Terphenyl-d14
1718-51-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1042
+/- 146.0860 µg/mL
+/- 177.2698 µg/mL
(Lot PR-30504)
01-Aug-2020 rev.Page 1 of 3
Page 170 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Due to the limited solubility of p-terphenyl-d14 in methanol, we do not recommend that this mixture be diluted in methanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
40°C (hold 2 min.) to 330°C
@ 10°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
29-Apr-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Apr-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 171 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 172 of 1261
Reagent
8270SurStkHL_00441
Page 173 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567685 Lot No.:A0184539
8270 Surrogate StandardDescription :
8270 Surrogate Standard 5,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonicate prior to use.
April 30, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 5,023.52-Fluorophenol
367-12-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.2073
+/- 146.6035 µg/mL
+/- 177.8977 µg/mL
(Lot STBJ3299)
99%
2 µg/mL 5,000.1Phenol-d5
4165-62-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0708
+/- 145.9187 µg/mL
+/- 177.0667 µg/mL
(Lot GH-100)
99%
3 µg/mL 5,012.6Nitrobenzene-d5
4165-60-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1437
+/- 146.2845 µg/mL
+/- 177.5106 µg/mL
(Lot PR-29940A)
99%
4 µg/mL 5,004.92-Fluorobiphenyl
321-60-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0991
+/- 146.0607 µg/mL
+/- 177.2391 µg/mL
(Lot 00021384)
99%
5 µg/mL 5,009.72,4,6-Tribromophenol
118-79-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1270
+/- 146.2008 µg/mL
+/- 177.4091 µg/mL
(Lot MKCJ7664)
99%
6 µg/mL 5,005.8p-Terphenyl-d14
1718-51-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1042
+/- 146.0860 µg/mL
+/- 177.2698 µg/mL
(Lot PR-30504)
01-Aug-2020 rev.Page 1 of 3
Page 174 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Due to the limited solubility of p-terphenyl-d14 in methanol, we do not recommend that this mixture be diluted in methanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
40°C (hold 2 min.) to 330°C
@ 10°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
29-Apr-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Apr-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 175 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 176 of 1261
Reagent
8270SurStkHL_00442
Page 177 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567685 Lot No.:A0184539
8270 Surrogate StandardDescription :
8270 Surrogate Standard 5,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonicate prior to use.
April 30, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 5,023.52-Fluorophenol
367-12-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.2073
+/- 146.6035 µg/mL
+/- 177.8977 µg/mL
(Lot STBJ3299)
99%
2 µg/mL 5,000.1Phenol-d5
4165-62-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0708
+/- 145.9187 µg/mL
+/- 177.0667 µg/mL
(Lot GH-100)
99%
3 µg/mL 5,012.6Nitrobenzene-d5
4165-60-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1437
+/- 146.2845 µg/mL
+/- 177.5106 µg/mL
(Lot PR-29940A)
99%
4 µg/mL 5,004.92-Fluorobiphenyl
321-60-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0991
+/- 146.0607 µg/mL
+/- 177.2391 µg/mL
(Lot 00021384)
99%
5 µg/mL 5,009.72,4,6-Tribromophenol
118-79-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1270
+/- 146.2008 µg/mL
+/- 177.4091 µg/mL
(Lot MKCJ7664)
99%
6 µg/mL 5,005.8p-Terphenyl-d14
1718-51-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1042
+/- 146.0860 µg/mL
+/- 177.2698 µg/mL
(Lot PR-30504)
01-Aug-2020 rev.Page 1 of 3
Page 178 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Due to the limited solubility of p-terphenyl-d14 in methanol, we do not recommend that this mixture be diluted in methanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
40°C (hold 2 min.) to 330°C
@ 10°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
29-Apr-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Apr-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 179 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 180 of 1261
Reagent
CN CAL Std_00083
Page 181 of 1261
Reagent
CPI TCLP Spk_00006
Page 182 of 1261
Page 183 of 1261
Page 184 of 1261
Reagent
Hg CPI Stock_00004
Page 185 of 1261
Page 186 of 1261
Page 187 of 1261
Reagent
Hg EE 1000ppm_00007
Page 188 of 1261
Page 189 of 1261
Page 190 of 1261
Reagent
ICP CAL STD 1_00014
Page 191 of 1261
Page 192 of 1261
Page 193 of 1261
Page 194 of 1261
Reagent
ICP CAL STD 4_00012
Page 195 of 1261
Page 196 of 1261
Page 197 of 1261
Reagent
ICP ICSAB 1_00007
Page 198 of 1261
Page 199 of 1261
Page 200 of 1261
Reagent
ICP ICSAB 2_00007
Page 201 of 1261
Page 202 of 1261
Page 203 of 1261
Page 204 of 1261
Reagent
ICP ICV STD 4_00003
Page 205 of 1261
Page 206 of 1261
Page 207 of 1261
Page 208 of 1261
Reagent
ICP LLCCV_03783
Page 209 of 1261
1.0 ACCREDITATION / REGISTRATION
INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for
the Competence of Reference Material Producers" and ISO/IEC 17025, "General
Requirements for the Competence of Testing and Calibration Laboratories".
Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate
Number QSR-1034).
Testing Laboratory
Certificate 883.01
Reference Material Producer
Certificate 883.02
2.0 PRODUCT DESCRIPTION
Product Code:Multi Analyte Custom Grade Solution
Catalog Number:IV-68440
Lot Number:U2-MEB734692
Matrix:5% (v/v) HNO3
tr. HF
Page 1 of 7
Page 210 of 1261
300 µg/mL ea:
Potassium,Phosphorus,
100 µg/mL ea:
Sodium,
50 µg/mL ea:
Silicon,
20 µg/mL ea:
Magnesium,Calcium,
10 µg/mL ea:
Aluminum,Boron,
Iron,Tin,
Sulfur,
6 µg/mL ea:
Uranium,
4 µg/mL ea:
Nickel,
2 µg/mL ea:
Antimony,Selenium,
Zinc,Molybdenum,
Lithium,
1.5 µg/mL ea:
Copper,Arsenic,
Thallium,
1 µg/mL ea:
Zirconium,Vanadium,
Strontium,Titanium,
Barium,Cobalt,
Chromium,Silver,
Manganese,
0.9 µg/mL ea:
Lead,
0.5 µg/mL ea:
Cadmium,
0.1 µg/mL ea:
Beryllium
Value / Analyte(s):
3.0 CERTIFIED VALUES AND UNCERTAINTIES
Page 2 of 7
Page 211 of 1261
ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
Aluminum, Al 9.99 ± 0.03 µg/mL Antimony, Sb 2.000 ± 0.015 µg/mL
Arsenic, As 1.500 ± 0.009 µg/mL Barium, Ba 1.000 ± 0.005 µg/mL
Beryllium, Be 0.1000 ± 0.0006 µg/mL Boron, B 10.00 ± 0.07 µg/mL
Cadmium, Cd 0.4999 ± 0.0030 µg/mL Calcium, Ca 20.00 ± 0.07 µg/mL
Chromium, Cr 1.000 ± 0.005 µg/mL Cobalt, Co 1.000 ± 0.004 µg/mL
Copper, Cu 1.500 ± 0.009 µg/mL Iron, Fe 10.00 ± 0.04 µg/mL
Lead, Pb 0.900 ± 0.004 µg/mL Lithium, Li 1.999 ± 0.009 µg/mL
Magnesium, Mg 20.00 ± 0.09 µg/mL Manganese, Mn 1.001 ± 0.005 µg/mL
Molybdenum, Mo 2.001 ± 0.016 µg/mL Nickel, Ni 3.999 ± 0.024 µg/mL
Phosphorus, P 300.0 ± 1.5 µg/mL Potassium, K 300.0 ± 1.3 µg/mL
Selenium, Se 2.000 ± 0.012 µg/mL Silicon, Si 50.00 ± 0.28 µg/mL
Silver, Ag 1.000 ± 0.007 µg/mL Sodium, Na 100.0 ± 0.4 µg/mL
Strontium, Sr 1.000 ± 0.004 µg/mL Sulfur, S 9.99 ± 0.04 µg/mL
Thallium, Tl 1.500 ± 0.009 µg/mL Tin, Sn 10.00 ± 0.04 µg/mL
Titanium, Ti 1.000 ± 0.006 µg/mL Uranium, U 6.000 ± 0.031 µg/mL
Vanadium, V 1.000 ± 0.005 µg/mL Zinc, Zn 2.001 ± 0.009 µg/mL
Zirconium, Zr 1.000 ± 0.007 µg/mL
Density:1.027 g/mL (measured at 20 ± 4 ºC)
Assay Information:
Page 3 of 7
Page 212 of 1261
METHOD NIST SRM#SRM LOT#ANALYTE
3151ICP Assay 160729Ag
999cVolhard 999cAg
Calculated See Sec. 4.2Ag
3101aICP Assay 140903Al
928EDTA 928Al
Calculated See Sec. 4.2Al
3103aICP Assay 100818As
Calculated See Sec. 4.2As
3107ICP Assay 190605B
Calculated See Sec. 4.2B
3104aICP Assay 140909Ba
Calculated See Sec. 4.2Ba
Gravimetric See Sec. 4.2Ba
Calculated See Sec. 4.2Be
3109aEDTA 130213Ca
3109aICP Assay 130213Ca
Calculated See Sec. 4.2Ca
3108ICP Assay 130116Cd
928EDTA 928Cd
Calculated See Sec. 4.2Cd
3113ICP Assay 190630Co
928EDTA 928Co
Calculated See Sec. 4.2Co
3112aICP Assay 170630Cr
Calculated See Sec. 4.2Cr
3114ICP Assay 120618Cu
928EDTA 928Cu
Calculated See Sec. 4.2Cu
3126aICP Assay 140812Fe
928EDTA 928Fe
Calculated See Sec. 4.2Fe
3141aICP Assay 140813K
Gravimetric See Sec. 4.2K
3129aICP Assay 100714Li
Calculated See Sec. 4.2Li
Gravimetric See Sec. 4.2Li
3131aICP Assay 140110Mg
928EDTA 928Mg
Calculated See Sec. 4.2Mg
3132ICP Assay 050429Mn
928EDTA 928Mn
Calculated See Sec. 4.2Mn
3134ICP Assay 130418Mo
3152aICP Assay 200413Na
Gravimetric See Sec. 4.2Na
3136ICP Assay 120619Ni
928EDTA 928Ni
Calculated See Sec. 4.2Ni
3139aICP Assay 060717P
Page 4 of 7
Page 213 of 1261
84LAcidimetric 84LP
3128ICP Assay 101026Pb
928EDTA 928Pb
Calculated See Sec. 4.2Pb
84LAcidimetric 84LS
traceable to 3154ICP Assay P2-S680745S
Calculated See Sec. 4.2S
3102aICP Assay 140911Sb
Calculated See Sec. 4.2Sb
3149ICP Assay 100901Se
Calculated See Sec. 4.2Se
3150ICP Assay 130912Si
Calculated See Sec. 4.2Si
3161aICP Assay 140917Sn
Calculated See Sec. 4.2Sn
928EDTA 928Sr
Traceable to 3153aICP Assay K2-SR650985Sr
Calculated See Sec. 4.2Sr
3162aICP Assay 130925Ti
3158ICP Assay 151215Tl
Calculated See Sec. 4.2Tl
traceable to 3164ICP Assay R2-U689597U
Calculated See Sec. 4.2U
3165ICP Assay 160906V
928EDTA 928V
Calculated See Sec. 4.2V
3168aICP Assay 120629Zn
928EDTA 928Zn
Calculated See Sec. 4.2Zn
3169ICP Assay 130920Zr
Calculated See Sec. 4.2Zr
The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent
expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.
Certified Abundance:
IV's Certified Abundance
Isotope Atom %
Uranium 238U
Uranium 235U
99.8 ± 0.1
0.19 ± 0.05
4.0 TRACEABILITY TO NIST
Page 5 of 7
Page 214 of 1261
- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified
value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and
volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is
specified.
4.1 Thermometer Calibration
- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights
used for testing are annually compared to master weights and are traceable to NIST.
4.2 Balance Calibration
- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration
laboratory.
4.3 Glassware Calibration
- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality
control of CRM/RMs.
TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0
N/A
INTENDED USE6.0
6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods
as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard
Methods 3120 B and USP <232> / ICH Q3D.
6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™)
see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale,
https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on
the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is
especially pertinent for laboratories accredited under ISO:17034.
INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0
7.1 Storage and Handling Recommendations
www.inorganicventures.com/TCT- For more information, visit
- Store between approximately 4° - 30° C while in sealed TCT bag.
- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT
bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is
the responsibility of the user to account for this effect. When the bottle is weighed both before and after being
placed in storage, the mass difference observed will be a measure of transpiration mass loss.
- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to
minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the
reported density. Do not pipette from the container. Do not return removed aliquots to container.
HF Note: This standard should not be prepared or stored in glass.
Low Silver Note: This solution contains “LOW” levels of Silver. Please store this entire bottle inside a sealed glass jar.
HAZARDOUS INFORMATION 8.0
- Please refer to the Safety Data Sheet for information regarding this CRM/RM.
HOMOGENEITY9.0
- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.
Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure
homogeneity.
Page 6 of 7
Page 215 of 1261
QUALITY STANDARD DOCUMENTATION10.0
10.1 ISO 9001 Quality Management System Registration
- QSR Certificate Number QSR-1034
- Chemical Testing - Accredited / A2LA Certificate Number 883.01
10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"
- Reference Material Producer - Accredited / A2LA Certificate Number 883.02
10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"
Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: [phone], Fax: [phone]; inorganicventures.com;
[e-mail]
CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0
11.1 Certification Issue Date
11.2 Lot Expiration Date
- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and
handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1
are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.
July 11, 2023
- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term
stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by
transpiration (loss of water from the solution) and infrequently by chemical stability.
- July 11, 2028
- The date after which this CRM/RM should not be used.
11.3 Period of Validity
- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the
date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is
contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.
- Sealed TCT Bag Open Date: __________________________
12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS
Certificate Approved By:
Paul Gaines
Chairman / Senior Technical Director
Certifying Officer:
Thomas Kozikowski
Stock VS Manager
Page 7 of 7
Page 216 of 1261
Reagent
Icp stk ICSA_00039
Page 217 of 1261
Page 218 of 1261
Page 219 of 1261
Reagent
Icp stk ICSA_00040
Page 220 of 1261
1.0 ACCREDITATION / REGISTRATION
INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for
the Competence of Reference Material Producers" and ISO/IEC 17025, "General
Requirements for the Competence of Testing and Calibration Laboratories".
Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate
Number QSR-1034).
Testing Laboratory
Certificate 883.01
Reference Material Producer
Certificate 883.02
2.0 PRODUCT DESCRIPTION
Product Code:Multi Analyte Custom Grade Solution
Catalog Number:CLPP-ICS-A
Lot Number:T2-MEB726136
Matrix:2% (v/v) HNO3
5 000 µg/mL ea:
Aluminum,Calcium,
Magnesium,
2 000 µg/mL ea:
Iron
Value / Analyte(s):
3.0 CERTIFIED VALUES AND UNCERTAINTIES
ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
Aluminum, Al 5 008 ± 17 µg/mL Calcium, Ca 5 008 ± 21 µg/mL
Iron, Fe 2 003 ± 9 µg/mL Magnesium, Mg 5 008 ± 21 µg/mL
Density:1.083 g/mL (measured at 20 ± 4 ºC)
Assay Information:
METHOD NIST SRM#SRM LOT#ANALYTE
3101aICP Assay 140903Al
928EDTA 928Al
3109aICP Assay 130213Ca
928EDTA 928Ca
3126aICP Assay 140812Fe
928EDTA 928Fe
3131aICP Assay 140110Mg
928EDTA 928Mg
The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent
expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.
Page 1 of 4
Page 221 of 1261
4.0 TRACEABILITY TO NIST
- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified
value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and
volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is
specified.
4.1 Thermometer Calibration
- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights
used for testing are annually compared to master weights and are traceable to NIST.
4.2 Balance Calibration
- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration
laboratory.
4.3 Glassware Calibration
- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality
control of CRM/RMs.
TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0
CRM/RMs are tested for trace metallic impurities by Axial ICP-OES and ICP-MS. The result from the most
sensitive method for each element, is reported below. Solutions tested by ICP-MS were analyzed in an
ULPA-Filtered Clean Room. An ULPA-Filter is 99.9985% efficient for the removal of particles down to
0.3 µm.
M Ag < 0.000330
s Al <
M As < 0.003900
M Au < 0.005100
O B < 0.022000
O Ba 0.009600
O Be < 0.000440
M Bi 0.001500
s Ca <
M Cd < 0.000420
M Ce < 0.000880
M Co 0.005200
O Cr 0.044000
M Cs 0.004100
M Cu < 0.001300
M Dy < 0.000110
M Er < 0.000110
M Eu < 0.000240
s Fe <
M Ga 0.080000
M Gd < 0.000110
M Ge < 0.002800
M Hf < 0.000400
M Hg < 0.000740
M Ho < 0.000110
M In < 0.000110
M Ir < 0.000110
O K 0.033000
M La 0.000640
O Li 0.006400
M Lu < 0.000110
s Mg <
O Mn 0.005200
M Mo 0.003400
O Na 0.180000
M Nb < 0.000110
M Nd < 0.000710
O Ni 0.015000
M Os < 0.000110
O P < 0.022000
M Pb 0.001300
M Pd < 0.000230
M Pr < 0.000110
M Pt < 0.000110
M Rb < 0.000250
M Re < 0.000110
M Rh < 0.000110
M Ru < 0.000110
O S < 0.220000
M Sb < 0.001900
M Sc < 0.000900
M Se < 0.001600
O Si 0.071000
M Sm < 0.000110
M Sn < 0.000480
O Sr 0.023000
M Ta < 0.000110
M Tb < 0.000110
M Te < 0.000350
M Th < 0.000110
M Ti < 0.002300
M Tl < 0.000110
M Tm < 0.000110
M U 0.000810
M V < 0.001800
M W < 0.001500
M Y < 0.000980
M Yb < 0.000110
M Zn 0.007200
M Zr 0.002700
M - Checked by ICP-MS O - Checked by ICP-OES i - Spectral Interference
n - Not Checked For s - Solution Standard Element
INTENDED USE6.0
- For the calibration of analytical instruments and validation of analytical methods as appropriate.
Page 2 of 4
Page 222 of 1261
INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0
7.1 Storage and Handling Recommendations
www.inorganicventures.com/TCT- For more information, visit
- Store between approximately 4° - 30° C while in sealed TCT bag.
- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT
bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is
the responsibility of the user to account for this effect. When the bottle is weighed both before and after being
placed in storage, the mass difference observed will be a measure of transpiration mass loss.
- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to
minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the
reported density. Do not pipette from the container. Do not return removed aliquots to container.
HAZARDOUS INFORMATION 8.0
- Please refer to the Safety Data Sheet for information regarding this CRM/RM.
HOMOGENEITY9.0
- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.
Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure
homogeneity.
QUALITY STANDARD DOCUMENTATION10.0
10.1 ISO 9001 Quality Management System Registration
- QSR Certificate Number QSR-1034
- Chemical Testing - Accredited / A2LA Certificate Number 883.01
10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"
- Reference Material Producer - Accredited / A2LA Certificate Number 883.02
10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"
Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: [phone], Fax: [phone]; inorganicventures.com; [e-mail]
CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0
11.1 Certification Issue Date
11.2 Lot Expiration Date
- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and
handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1
are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.
November 17, 2022
- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term
stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by
transpiration (loss of water from the solution) and infrequently by chemical stability.
- November 17, 2027
- The date after which this CRM/RM should not be used.
Page 3 of 4
Page 223 of 1261
11.3 Period of Validity
- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the
date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is
contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.
- Sealed TCT Bag Open Date: __________________________
12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS
Certificate Approved By:
Paul Gaines
Chairman / Senior Technical Director
Certifying Officer:
Thomas Kozikowski
Manager, Quality Control
Page 4 of 4
Page 224 of 1261
Reagent
ICV MIX-1a_00004
Page 225 of 1261
1.0 ACCREDITATION / REGISTRATION
INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for
the Competence of Reference Material Producers" and ISO/IEC 17025, "General
Requirements for the Competence of Testing and Calibration Laboratories".
Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate
Number QSR-1034).
Testing Laboratory
Certificate 883.01
Reference Material Producer
Certificate 883.02
2.0 PRODUCT DESCRIPTION
Product Code:Multi Analyte Custom Grade Solution
Catalog Number:IV-67795-A
Lot Number:U2-MEB734729
Matrix:5% (v/v) HNO3
100 µg/mL ea:
Arsenic,Barium,
Beryllium,Cadmium,
Cobalt,Chromium,
Copper,Lithium,
Manganese,Nickel,
Lead,Selenium,
Strontium,Thallium,
Vanadium
Value / Analyte(s):
3.0 CERTIFIED VALUES AND UNCERTAINTIES
ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
Arsenic, As 100.0 ± 0.7 µg/mL Barium, Ba 100.0 ± 0.4 µg/mL
Beryllium, Be 100.0 ± 0.6 µg/mL Cadmium, Cd 100.0 ± 0.4 µg/mL
Chromium, Cr 100.0 ± 0.6 µg/mL Cobalt, Co 100.0 ± 0.5 µg/mL
Copper, Cu 100.1 ± 0.4 µg/mL Lead, Pb 100.0 ± 0.5 µg/mL
Lithium, Li 100.1 ± 0.4 µg/mL Manganese, Mn 100.0 ± 0.4 µg/mL
Nickel, Ni 100.0 ± 0.4 µg/mL Selenium, Se 100.0 ± 0.6 µg/mL
Strontium, Sr 100.0 ± 0.4 µg/mL Thallium, Tl 100.0 ± 0.5 µg/mL
Vanadium, V 100.0 ± 0.4 µg/mL
Density:1.029 g/mL (measured at 20 ± 4 ºC)
Assay Information:
Page 1 of 4
Page 226 of 1261
METHOD NIST SRM#SRM LOT#ANALYTE
3103aICP Assay 100818As
Calculated See Sec. 4.2As
3104aICP Assay 140909Ba
Gravimetric See Sec. 4.2Ba
3105aICP Assay 090514Be
3108ICP Assay 130116Cd
928EDTA 928Cd
3113ICP Assay 190630Co
928EDTA 928Co
3112aICP Assay 170630Cr
3114ICP Assay 121207Cu
928EDTA 928Cu
3129aICP Assay 100714Li
Gravimetric See Sec. 4.2Li
3132ICP Assay 050429Mn
928EDTA 928Mn
3136ICP Assay 120619Ni
928EDTA 928Ni
3128ICP Assay 101026Pb
928EDTA 928Pb
3149ICP Assay 100901Se
928EDTA 928Sr
Traceable to 3153aICP Assay K2-SR650985Sr
Calculated See Sec. 4.2Sr
3158ICP Assay 151215Tl
3165ICP Assay 160906V
928EDTA 928V
The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent
expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.
4.0 TRACEABILITY TO NIST
- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified
value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and
volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is
specified.
Page 2 of 4
Page 227 of 1261
4.1 Thermometer Calibration
- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights
used for testing are annually compared to master weights and are traceable to NIST.
4.2 Balance Calibration
- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration
laboratory.
4.3 Glassware Calibration
- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality
control of CRM/RMs.
TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0
N/A
INTENDED USE6.0
6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods
as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard
Methods 3120 B and USP <232> / ICH Q3D.
6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™)
see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale,
https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on
the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is
especially pertinent for laboratories accredited under ISO:17034.
INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0
7.1 Storage and Handling Recommendations
www.inorganicventures.com/TCT- For more information, visit
- Store between approximately 4° - 30° C while in sealed TCT bag.
- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT
bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is
the responsibility of the user to account for this effect. When the bottle is weighed both before and after being
placed in storage, the mass difference observed will be a measure of transpiration mass loss.
- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to
minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the
reported density. Do not pipette from the container. Do not return removed aliquots to container.
HAZARDOUS INFORMATION 8.0
- Please refer to the Safety Data Sheet for information regarding this CRM/RM.
HOMOGENEITY9.0
- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.
Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure
homogeneity.
QUALITY STANDARD DOCUMENTATION10.0
10.1 ISO 9001 Quality Management System Registration
- QSR Certificate Number QSR-1034
Page 3 of 4
Page 228 of 1261
- Chemical Testing - Accredited / A2LA Certificate Number 883.01
10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"
- Reference Material Producer - Accredited / A2LA Certificate Number 883.02
10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"
Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: [phone], Fax: [phone]; inorganicventures.com;
[e-mail]
CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0
11.1 Certification Issue Date
11.2 Lot Expiration Date
- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and
handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1
are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.
July 12, 2023
- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term
stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by
transpiration (loss of water from the solution) and infrequently by chemical stability.
- July 12, 2028
- The date after which this CRM/RM should not be used.
11.3 Period of Validity
- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the
date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is
contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.
- Sealed TCT Bag Open Date: __________________________
12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS
Certificate Approved By:
Paul Gaines
Chairman / Senior Technical Director
Certifying Officer:
Thomas Kozikowski
Stock VS Manager
Page 4 of 4
Page 229 of 1261
Reagent
MS-31615_00016
Page 230 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :31615 Lot No.:A0189454
GC/MS Tuning MixtureDescription :
GC/MS Tuning Mixture 1,000µg/mL, Methylene Chloride, 1mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
2 mL > 1 mLPkg Amt:
Handling:Contains carcinogen/reproductive
toxin.
September 30, 2025
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 1,001.6Pentachlorophenol
87-86-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8779
+/- 45.6221 µg/mL
+/- 65.8721 µg/mL
(Lot 211229RSR)
95%
2 µg/mL 1,000.9DFTPP (Decafluorotriphenylphosphine)
5074-71-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8740
+/- 45.5911 µg/mL
+/- 65.8274 µg/mL
(Lot Q117-147)
99%
3 µg/mL 1,001.6Benzidine
92-87-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8779
+/- 45.6221 µg/mL
+/- 65.8721 µg/mL
(Lot 220511RSR)
98%
4 µg/mL 1,002.04,4'-DDT
50-29-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 5.8800
+/- 45.6381 µg/mL
+/- 65.8953 µg/mL
(Lot 220805JLM)
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
01-Aug-2020 rev.Page 1 of 3
Page 231 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128353505Balance:
15-Sep-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
11-Sep-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 232 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 233 of 1261
Reagent
MS-567684_00040
Page 234 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567684 Lot No.:A0187296
8270 Internal StandardDescription :
8270 Internal Standard 2,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonication required. Mix is
photosensitive.
July 31, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 2,004.41,4-Dichlorobenzene-d4
3855-82-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6535
+/- 90.2776 µg/mL
+/- 100.1741 µg/mL
(Lot PR-30447)
99%
2 µg/mL 2,005.4Naphthalene-d8
1146-65-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6593
+/- 90.3226 µg/mL
+/- 100.2241 µg/mL
(Lot M-2180)
99%
3 µg/mL 2,006.5Acenaphthene-d10
15067-26-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6657
+/- 90.3717 µg/mL
+/- 100.2786 µg/mL
(Lot PR-31822)
99%
4 µg/mL 2,004.3Phenanthrene-d10
1517-22-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6532
+/- 90.2753 µg/mL
+/- 100.1716 µg/mL
(Lot PR-32303)
99%
5 µg/mL 2,004.5Chrysene-d12
1719-03-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6542
+/- 90.2830 µg/mL
+/- 100.1801 µg/mL
(Lot PR-32210)
99%
6 µg/mL 2,006.0Perylene-d12
1520-96-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6628
+/- 90.3496 µg/mL
+/- 100.2541 µg/mL
(Lot PR-33205)
01-Aug-2020 rev.Page 1 of 3
Page 235 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
19-Jul-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
13-Jul-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 236 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 237 of 1261
Reagent
MS-567684_00041
Page 238 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567684 Lot No.:A0187296
8270 Internal StandardDescription :
8270 Internal Standard 2,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonication required. Mix is
photosensitive.
July 31, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 2,004.41,4-Dichlorobenzene-d4
3855-82-1CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6535
+/- 90.2776 µg/mL
+/- 100.1741 µg/mL
(Lot PR-30447)
99%
2 µg/mL 2,005.4Naphthalene-d8
1146-65-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6593
+/- 90.3226 µg/mL
+/- 100.2241 µg/mL
(Lot M-2180)
99%
3 µg/mL 2,006.5Acenaphthene-d10
15067-26-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6657
+/- 90.3717 µg/mL
+/- 100.2786 µg/mL
(Lot PR-31822)
99%
4 µg/mL 2,004.3Phenanthrene-d10
1517-22-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6532
+/- 90.2753 µg/mL
+/- 100.1716 µg/mL
(Lot PR-32303)
99%
5 µg/mL 2,004.5Chrysene-d12
1719-03-5CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6542
+/- 90.2830 µg/mL
+/- 100.1801 µg/mL
(Lot PR-32210)
99%
6 µg/mL 2,006.0Perylene-d12
1520-96-3CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 11.6628
+/- 90.3496 µg/mL
+/- 100.2541 µg/mL
(Lot PR-33205)
01-Aug-2020 rev.Page 1 of 3
Page 239 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
19-Jul-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
13-Jul-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 240 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 241 of 1261
Reagent
MS-567684_00045
Page 242 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :567684 Lot No.:A0193798
8270 Internal StandardDescription :
8270 Internal Standard 2,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonication required. Mix is
photosensitive.
January 31, 2028
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,018.21,4-Dichlorobenzene-d4 3855-82-1 +/- 90.9009PR-30447
99% 2 µg/mL 2,011.9Naphthalene-d8 1146-65-2 +/- 90.6172M-2180
99% 3 µg/mL 2,017.4Acenaphthene-d10 15067-26-2 +/- 90.8649PR-31822
99% 4 µg/mL 2,005.1Phenanthrene-d10 1517-22-2 +/- 90.3087PR-32303
99% 5 µg/mL 2,007.3Chrysene-d12 1719-03-5 +/- 90.4077PR-32210
99% 6 µg/mL 2,016.6Perylene-d12 1520-96-3 +/- 90.8289PR-33205
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
Page 243 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128353505Balance Serial #
24-Jan-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
20-Jan-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
10 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
Page 244 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
Page 245 of 1261
Reagent
MS-567685_00063
Page 246 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
Catalog No. :567685 Lot No.:A0184539
8270 Surrogate StandardDescription :
8270 Surrogate Standard 5,000µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:Sonicate prior to use.
April 30, 2027
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded Uncertainty
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
99%
1 µg/mL 5,023.52-Fluorophenol
367-12-4CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.2073
+/- 146.6035 µg/mL
+/- 177.8977 µg/mL
(Lot STBJ3299)
99%
2 µg/mL 5,000.1Phenol-d5
4165-62-2CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0708
+/- 145.9187 µg/mL
+/- 177.0667 µg/mL
(Lot GH-100)
99%
3 µg/mL 5,012.6Nitrobenzene-d5
4165-60-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1437
+/- 146.2845 µg/mL
+/- 177.5106 µg/mL
(Lot PR-29940A)
99%
4 µg/mL 5,004.92-Fluorobiphenyl
321-60-8CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.0991
+/- 146.0607 µg/mL
+/- 177.2391 µg/mL
(Lot 00021384)
99%
5 µg/mL 5,009.72,4,6-Tribromophenol
118-79-6CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1270
+/- 146.2008 µg/mL
+/- 177.4091 µg/mL
(Lot MKCJ7664)
99%
6 µg/mL 5,005.8p-Terphenyl-d14
1718-51-0CAS #
Purity Stressed
Unstressed
Gravimetric µg/mL+/- 29.1042
+/- 146.0860 µg/mL
+/- 177.2698 µg/mL
(Lot PR-30504)
01-Aug-2020 rev.Page 1 of 3
Page 247 of 1261
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
Due to the limited solubility of p-terphenyl-d14 in methanol, we do not recommend that this mixture be diluted in methanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
40°C (hold 2 min.) to 330°C
@ 10°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance:
29-Apr-2022Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Apr-2022Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
01-Aug-2020 rev.Page 2 of 3
Page 248 of 1261
Label Conditions Non-Standard Conditions
25°C Nominal (Room Temperature)
10°C or colder (Refrigerate)
0°C or colder (Freezer)
≥ 60°C up to 7 days
≥ 40°C up to 7 days
≥ 25°C up to 7 days
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
·Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Standard Conditions
< 60°C
< 40°C
< 25°C
·Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
-20°C or colder (Deep Freezer)
01-Aug-2020 rev.Page 3 of 3
Page 249 of 1261
Reagent
MS-568033.SEC_00002
Page 250 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
gravimetric
Certificate of Analysis
Catalog No. :568033.SEC Lot No.:A0196553
Denver 8270 StandardDescription :
Denver 8270 Standard 4,000µg/mL, Methylene chloride, 1mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
2 mL > 1 mLPkg Amt:
Handling:Sonicate prior to use. This product is
photosensitive.
October 31, 2024
Ship:Ambient
Componen
t #
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 4,016.02,3-Dichloroaniline 608-27-5.SEC +/- 96.5696A0147333
99% 2 µg/mL 4,024.03,5-Dimethylphenol 108-68-9.SEC +/- 96.7619NRWKD
99% 3 µg/mL 4,012.0Alachlor15972-60-8.SEC +/- 96.4734BCBW0992
99% 4 µg/mL 4,016.0alpha-Methylstyrene 98-83-9.SEC +/- 96.5696207VL
97% 5 µg/mL 4,019.7Benzo(e)pyrene 192-97-2.SEC +/- 96.6581033021
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
1128353505Balance:
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 8039703-Apr-2023Date Mixed:
01-Nov-2022 rev.Page 1 of 2
Page 251 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 2 of 2
Page 252 of 1261
Reagent
MS-571995_00084
Page 253 of 1261
Page 254 of 1261
Page 255 of 1261
Page 256 of 1261
Page 257 of 1261
Page 258 of 1261
Page 259 of 1261
Page 260 of 1261
Page 261 of 1261
Reagent
mv-30241_00012
Page 262 of 1261
Page 263 of 1261
Page 264 of 1261
Reagent
MV-567650_00030
Page 265 of 1261
Page 266 of 1261
Page 267 of 1261
Reagent
MV-568720_00046
Page 268 of 1261
Page 269 of 1261
Page 270 of 1261
Reagent
MV-569721.sec_00011
Page 271 of 1261
Page 272 of 1261
Page 273 of 1261
Reagent
MV-569721_00015
Page 274 of 1261
Page 275 of 1261
Page 276 of 1261
Reagent
MV-569722.sec_00017
Page 277 of 1261
Page 278 of 1261
Page 279 of 1261
Reagent
MV-569722_00022
Page 280 of 1261
Page 281 of 1261
Page 282 of 1261
Reagent
MV-569722_00023
Page 283 of 1261
Page 284 of 1261
Page 285 of 1261
Reagent
MV-569723_00018
Page 286 of 1261
Page 287 of 1261
Page 288 of 1261
Reagent
MV-569724_00035
Page 289 of 1261
Page 290 of 1261
Page 291 of 1261
Reagent
MV-569727_00024
Page 292 of 1261
Page 293 of 1261
Page 294 of 1261
Reagent
MV-571992.sec_00010
Page 295 of 1261
Page 296 of 1261
Page 297 of 1261
Page 298 of 1261
Page 299 of 1261
Reagent
MV-571992_00015
Page 300 of 1261
Page 301 of 1261
Page 302 of 1261
Page 303 of 1261
Page 304 of 1261
Page 305 of 1261
Page 306 of 1261
Reagent
MV-CUS17739.s_00011
Page 307 of 1261
Page 308 of 1261
Page 309 of 1261
Reagent
mv-IS/SS Tune_00001
Page 310 of 1261
Page 311 of 1261
Page 312 of 1261
Page 313 of 1261
Reagent
OP-569731_00078
Page 314 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569731 Lot No.:A0193718
8270 List 1 / Std #10Description :
8270 List 1 / Std #10 2,000 µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:This product is photosensitive.
July 31, 2024
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 2,007.2Indene95-13-6 +/- 112.7560RD221018
99% 2 µg/mL 2,009.9Benzoic acid 65-85-0 +/- 112.9084MKCL7479
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
Page 315 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance Serial #
23-Jan-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
18-Jan-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
10 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
Page 316 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
Page 317 of 1261
Reagent
OP-569731_00099
Page 318 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569731 Lot No.:A0199925
8270 List 1 / Std #10Description :
8270 List 1 / Std #10 2,000 µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:This product is photosensitive.
January 31, 2025
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 2,005.1Indene95-13-6 +/- 112.6381RD221018
99% 2 µg/mL 2,002.0Benzoic acid 65-85-0 +/- 112.4616MKCL7479
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
Page 319 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance Serial #
18-Jul-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
16-Jul-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
10 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
Page 320 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
Page 321 of 1261
Reagent
OP-569731_00100
Page 322 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569731 Lot No.:A0199925
8270 List 1 / Std #10Description :
8270 List 1 / Std #10 2,000 µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:This product is photosensitive.
January 31, 2025
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 2,005.1Indene95-13-6 +/- 112.6381RD221018
99% 2 µg/mL 2,002.0Benzoic acid 65-85-0 +/- 112.4616MKCL7479
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
Page 323 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance Serial #
18-Jul-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
16-Jul-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
10 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
Page 324 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
Page 325 of 1261
Reagent
OP-569731_00101
Page 326 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569731 Lot No.:A0199925
8270 List 1 / Std #10Description :
8270 List 1 / Std #10 2,000 µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:This product is photosensitive.
January 31, 2025
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 2,005.1Indene95-13-6 +/- 112.6381RD221018
99% 2 µg/mL 2,002.0Benzoic acid 65-85-0 +/- 112.4616MKCL7479
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
Page 327 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance Serial #
18-Jul-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
16-Jul-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
10 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
Page 328 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
Page 329 of 1261
Reagent
OP-569731_00102
Page 330 of 1261
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569731 Lot No.:A0199925
8270 List 1 / Std #10Description :
8270 List 1 / Std #10 2,000 µg/mL, Methylene chloride, 5mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
5 mL > 5 mLPkg Amt:
Handling:This product is photosensitive.
January 31, 2025
Ship:Ambient
Elution
Order
Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 2,005.1Indene95-13-6 +/- 112.6381RD221018
99% 2 µg/mL 2,002.0Benzoic acid 65-85-0 +/- 112.4616MKCL7479
Solvent:Methylene chloride
99%
75-09-2CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
Page 331 of 1261
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
30m x 0.25mm x 0.25µm
Rtx-5 (cat.#10223)
Column:
hydrogen-constant pressure 10 psi.
75°C (hold 1 min.) to 330°C
@ 20°C/min. (hold 10 min.)
250°C
330°C
FID
1128360905Balance Serial #
18-Jul-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
16-Jul-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
10 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
Page 332 of 1261
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred .
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights , and/or dilutions with Class A glassware .
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2 mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
Page 333 of 1261
Reagent
OP-572556_00055
Page 334 of 1261
Page 335 of 1261
Reagent
OP-572556_00062
Page 336 of 1261
Page 337 of 1261
Reagent
pH 7.0 Buffer_00328
Page 338 of 1261
Page 339 of 1261
Page 340 of 1261
Page 341 of 1261
Reagent
pH 7.0 Buffer_00331
Page 342 of 1261
Page 343 of 1261
Page 344 of 1261
Page 345 of 1261
Page 346 of 1261
Page 347 of 1261
Page 348 of 1261
Reagent
Prep spike1IV_00014
Page 349 of 1261
1.0 ACCREDITATION / REGISTRATION
INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for
the Competence of Reference Material Producers" and ISO/IEC 17025, "General
Requirements for the Competence of Testing and Calibration Laboratories".
Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate
Number QSR-1034).
Testing Laboratory
Certificate 883.01
Reference Material Producer
Certificate 883.02
2.0 PRODUCT DESCRIPTION
Product Code:Multi Analyte Custom Grade Solution
Catalog Number:IV-66967-A
Lot Number:U2-MEB734690
Matrix:5% (v/v) HNO3
0.4% (v/v) HF
1 000 µg/mL ea:
Silicon,
100 µg/mL ea:
Tin,Titanium,
Zirconium,Molybdenum,
Antimony
Value / Analyte(s):
3.0 CERTIFIED VALUES AND UNCERTAINTIES
ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
Antimony, Sb 100.1 ± 0.7 µg/mL Molybdenum, Mo 100.1 ± 0.6 µg/mL
Silicon, Si 1 001 ± 7 µg/mL Tin, Sn 100.1 ± 0.5 µg/mL
Titanium, Ti 100.1 ± 0.7 µg/mL Zirconium, Zr 100.1 ± 0.8 µg/mL
Density:1.030 g/mL (measured at 20 ± 4 ºC)
Assay Information:
METHOD NIST SRM#SRM LOT#ANALYTE
3134ICP Assay 130418Mo
3102aICP Assay 140911Sb
Traceable to 3150ICP Assay S2-SI702546Si
3161aICP Assay 140917Sn
3162aICP Assay 130925Ti
3169ICP Assay 130920Zr
The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent
expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.
Page 1 of 4
Page 350 of 1261
4.0 TRACEABILITY TO NIST
- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified
value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and
volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is
specified.
4.1 Thermometer Calibration
- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights
used for testing are annually compared to master weights and are traceable to NIST.
4.2 Balance Calibration
- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration
laboratory.
4.3 Glassware Calibration
- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality
control of CRM/RMs.
TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0
N/A
INTENDED USE6.0
6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods
as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard
Methods 3120 B and USP <232> / ICH Q3D.
6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™)
see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale,
https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on
the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is
especially pertinent for laboratories accredited under ISO:17034.
INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0
7.1 Storage and Handling Recommendations
Page 2 of 4
Page 351 of 1261
www.inorganicventures.com/TCT- For more information, visit
- Store between approximately 4° - 30° C while in sealed TCT bag.
- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT
bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is
the responsibility of the user to account for this effect. When the bottle is weighed both before and after being
placed in storage, the mass difference observed will be a measure of transpiration mass loss.
- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to
minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the
reported density. Do not pipette from the container. Do not return removed aliquots to container.
HF Note: This standard should not be prepared or stored in glass.
HAZARDOUS INFORMATION 8.0
- Please refer to the Safety Data Sheet for information regarding this CRM/RM.
HOMOGENEITY9.0
- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.
Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure
homogeneity.
QUALITY STANDARD DOCUMENTATION10.0
10.1 ISO 9001 Quality Management System Registration
- QSR Certificate Number QSR-1034
- Chemical Testing - Accredited / A2LA Certificate Number 883.01
10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"
- Reference Material Producer - Accredited / A2LA Certificate Number 883.02
10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"
Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: [phone], Fax: [phone]; inorganicventures.com;
[e-mail]
CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0
11.1 Certification Issue Date
11.2 Lot Expiration Date
- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and
handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1
are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.
July 12, 2023
- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term
stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by
transpiration (loss of water from the solution) and infrequently by chemical stability.
- July 12, 2028
- The date after which this CRM/RM should not be used.
Page 3 of 4
Page 352 of 1261
11.3 Period of Validity
- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the
date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is
contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.
- Sealed TCT Bag Open Date: __________________________
12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS
Certificate Approved By:
Paul Gaines
Chairman / Senior Technical Director
Certifying Officer:
Thomas Kozikowski
Stock VS Manager
Page 4 of 4
Page 353 of 1261
Reagent
Prep spike2IV_00013
Page 354 of 1261
1.0 ACCREDITATION / REGISTRATION
INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for
the Competence of Reference Material Producers" and ISO/IEC 17025, "General
Requirements for the Competence of Testing and Calibration Laboratories".
Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate
Number QSR-1034).
Testing Laboratory
Certificate 883.01
Reference Material Producer
Certificate 883.02
2.0 PRODUCT DESCRIPTION
Product Code:Multi Analyte Custom Grade Solution
Catalog Number:IV-66967-B
Lot Number:U2-MEB734691
Matrix:5% (v/v) HNO3
5 000 µg/mL ea:
Calcium,Potassium,
Magnesium,Sodium,
2 000 µg/mL ea:
Sulfur,Phosphorus,
1 000 µg/mL ea:
Iron,Aluminum,
200 µg/mL ea:
Boron,
100 µg/mL ea:
Barium,Beryllium,
Arsenic,Cadmium,
Cobalt,Chromium,
Copper,Lithium,
Nickel,Manganese,
Lead,Selenium,
Strontium,Thallium,
Vanadium,Zinc,
5 µg/mL ea:
Silver
Value / Analyte(s):
3.0 CERTIFIED VALUES AND UNCERTAINTIES
Page 1 of 6
Page 355 of 1261
ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
Aluminum, Al 1 000 ± 3 µg/mL Arsenic, As 100.0 ± 0.8 µg/mL
Barium, Ba 100.0 ± 0.4 µg/mL Beryllium, Be 100.0 ± 0.6 µg/mL
Boron, B 200.0 ± 1.4 µg/mL Cadmium, Cd 100.0 ± 0.4 µg/mL
Calcium, Ca 5 000 ± 16 µg/mL Chromium, Cr 100.0 ± 0.6 µg/mL
Cobalt, Co 100.0 ± 0.6 µg/mL Copper, Cu 100.0 ± 0.5 µg/mL
Iron, Fe 1 000 ± 4 µg/mL Lead, Pb 100.0 ± 0.5 µg/mL
Lithium, Li 100.0 ± 0.4 µg/mL Magnesium, Mg 5 000 ± 22 µg/mL
Manganese, Mn 100.0 ± 0.5 µg/mL Nickel, Ni 100.0 ± 0.5 µg/mL
Phosphorus, P 2 000 ± 10 µg/mL Potassium, K 5 000 ± 22 µg/mL
Selenium, Se 100.0 ± 0.6 µg/mL Silver, Ag 5.003 ± 0.022 µg/mL
Sodium, Na 5 000 ± 22 µg/mL Strontium, Sr 100.0 ± 0.4 µg/mL
Sulfur, S 2 000 ± 10 µg/mL Thallium, Tl 100.0 ± 0.5 µg/mL
Vanadium, V 100.0 ± 0.5 µg/mL Zinc, Zn 100.0 ± 0.5 µg/mL
Density:1.103 g/mL (measured at 20 ± 4 ºC)
Assay Information:
Page 2 of 6
Page 356 of 1261
METHOD NIST SRM#SRM LOT#ANALYTE
3151ICP Assay 160729Ag
999cVolhard 999cAg
3101aICP Assay 140903Al
928EDTA 928Al
3103aICP Assay 100818As
Calculated See Sec. 4.2As
3107ICP Assay 190605B
Calculated See Sec. 4.2B
3104aICP Assay 140909Ba
Gravimetric See Sec. 4.2Ba
3105aICP Assay 090514Be
3109aICP Assay 130213Ca
928EDTA 928Ca
3108ICP Assay 130116Cd
928EDTA 928Cd
3113ICP Assay 190630Co
928EDTA 928Co
3112aICP Assay 170630Cr
3114ICP Assay 121207Cu
928EDTA 928Cu
3126aICP Assay 140812Fe
928EDTA 928Fe
3141aICP Assay 140813K
Gravimetric See Sec. 4.2K
3129aICP Assay 100714Li
Gravimetric See Sec. 4.2Li
3131aICP Assay 140110Mg
928EDTA 928Mg
3132ICP Assay 050429Mn
928EDTA 928Mn
3152aICP Assay 200413Na
Gravimetric See Sec. 4.2Na
3136ICP Assay 120619Ni
928EDTA 928Ni
3139aICP Assay 060717P
84LAcidimetric 84LP
3128ICP Assay 101026Pb
928EDTA 928Pb
84LAcidimetric 84LS
traceable to 3154ICP Assay P2-S680745S
3149ICP Assay 100901Se
928EDTA 928Sr
Traceable to 3153aICP Assay K2-SR650985Sr
Calculated See Sec. 4.2Sr
3158ICP Assay 151215Tl
3165ICP Assay 160906V
928EDTA 928V
3168aICP Assay 120629Zn
928EDTA 928Zn
Page 3 of 6
Page 357 of 1261
The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent
expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.
4.0 TRACEABILITY TO NIST
- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified
value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and
volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is
specified.
4.1 Thermometer Calibration
- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights
used for testing are annually compared to master weights and are traceable to NIST.
4.2 Balance Calibration
- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration
laboratory.
4.3 Glassware Calibration
- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality
control of CRM/RMs.
TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0
N/A
INTENDED USE6.0
6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods
as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard
Methods 3120 B and USP <232> / ICH Q3D.
6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™)
see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale,
https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on
the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is
especially pertinent for laboratories accredited under ISO:17034.
INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0
7.1 Storage and Handling Recommendations
Page 4 of 6
Page 358 of 1261
www.inorganicventures.com/TCT- For more information, visit
- Store between approximately 4° - 30° C while in sealed TCT bag.
- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT
bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is
the responsibility of the user to account for this effect. When the bottle is weighed both before and after being
placed in storage, the mass difference observed will be a measure of transpiration mass loss.
- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to
minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the
reported density. Do not pipette from the container. Do not return removed aliquots to container.
Low Silver Note: This solution contains “LOW” levels of Silver. Please store this entire bottle inside a sealed glass jar.
HAZARDOUS INFORMATION 8.0
- Please refer to the Safety Data Sheet for information regarding this CRM/RM.
HOMOGENEITY9.0
- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.
Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure
homogeneity.
QUALITY STANDARD DOCUMENTATION10.0
10.1 ISO 9001 Quality Management System Registration
- QSR Certificate Number QSR-1034
- Chemical Testing - Accredited / A2LA Certificate Number 883.01
10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"
- Reference Material Producer - Accredited / A2LA Certificate Number 883.02
10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"
Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: [phone], Fax: [phone]; inorganicventures.com;
[e-mail]
CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0
11.1 Certification Issue Date
11.2 Lot Expiration Date
- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and
handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1
are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.
July 11, 2023
- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term
stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by
transpiration (loss of water from the solution) and infrequently by chemical stability.
- July 11, 2028
- The date after which this CRM/RM should not be used.
Page 5 of 6
Page 359 of 1261
11.3 Period of Validity
- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the
date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is
contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.
- Sealed TCT Bag Open Date: __________________________
12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS
Certificate Approved By:
Paul Gaines
Chairman / Senior Technical Director
Certifying Officer:
Thomas Kozikowski
Stock VS Manager
Page 6 of 6
Page 360 of 1261
Reagent
SFD ICV STOCK_00001
Page 361 of 1261
*(information only)
Page 362 of 1261
Method 8260D DOD
Volatile Organic Compounds by GC/MS
by Method 8260D DOD
Page 363 of 1261
FORM II
GC/MS VOA SURROGATE RECOVERY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Matrix:Solid (TCLP)Level:Low
GC Column (1):RXI-624SilMS ID:0.25(mm)
#Lab Sample IDClient Sample ID ###DBFM DCA TOL BFB
280-184424-1ST071-SoilIDW-1109
2023 110 114 101 98
LB
280-633952/1-A 111 116 102 98
LCS
280-633952/2-A 110 113 101 99
LCSD
280-633952/3-A 111 112 101 97
QC LIMITS
DBFM = Dibromofluoromethane (Surr)79-119
DCA = 1,2-Dichloroethane-d4 (Surr)64-129
TOL = Toluene-d8 (Surr)78-120
BFB = 4-Bromofluorobenzene (Surr)78-121
FORM II 8260D
# Column to be used to flag recovery values
Page 364 of 1261
GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-184424-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:X510785.DSolid (TCLP)
Lab ID:LCS 280-633952/2-A Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Benzene 500 551 74-135110
2-Butanone (MEK)2000 1930 44-15097
Carbon tetrachloride 500 483 67-13597
Chlorobenzene 500 486 76-13597
Chloroform 500 548 76-120110
1,2-Dichloroethane 500 556 70-135111
1,1-Dichloroethene 500 539 71-136108
Tetrachloroethene 500 505 70-135101
Trichloroethene 500 482 73-13596
Vinyl chloride 500 645 40-144129
FORM III 8260D
# Column to be used to flag recovery and RPD values
Page 365 of 1261
GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-184424-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:X510786.DSolid (TCLP)
Lab ID:LCSD 280-633952/3-A Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
500 554 20 74-135Benzene0111
2000 1980 32 44-1502-Butanone (MEK)399
500 495 21 67-135Carbon tetrachloride 299
500 493 20 76-135Chlorobenzene199
500 549 20 76-120Chloroform0110
500 563 20 70-1351,2-Dichloroethane 1113
500 545 20 71-1361,1-Dichloroethene 1109
500 515 20 70-135Tetrachloroethene2103
500 483 20 73-135Trichloroethene097
500 649 24 40-144Vinyl chloride 1130
FORM III 8260D
# Column to be used to flag recovery and RPD values
Page 366 of 1261
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-184424-1
Lab File ID:
Instrument ID:
X508904.D
VMS_X4
10/08/2023
17:17
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:628924
50 15.0 - 40.0 % of mass 95 19.2
75 30.0 - 60.0 % of mass 95 49.2
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.3
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 81.4
175 5.0 - 9.0 % of mass 174 6.8 (8.4)1
176 95.0 - 101.0 % of mass 174 80.7 (99.1)1
177 5.0 - 9.0 % of mass 176 5.0 (6.2)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
IC 280-628924/2 X508905.D 10/08/2023 17:38
IC 280-628924/3 X508906.D 10/08/2023 18:03
IC 280-628924/4 X508907.D 10/08/2023 18:24
IC 280-628924/5 X508908.D 10/08/2023 18:44
IC 280-628924/6 X508909.D 10/08/2023 19:04
ICIS 280-628924/7 X508910.D 10/08/2023 19:25
IC 280-628924/8 X508911.D 10/08/2023 19:45
IC 280-628924/9 X508912.D 10/08/2023 20:06
IC 280-628924/10 X508913.D 10/08/2023 20:26
ICV 280-628924/11 X508915.D 10/08/2023 21:07
ICV 280-628924/20 X508924.D 10/09/2023 0:11
FORM V 8260D Page 367 of 1261
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-184424-1
Lab File ID:
Instrument ID:
X510783.D
VMS_X4
11/17/2023
18:23
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:634482
50 15.0 - 40.0 % of mass 95 20.5
75 30.0 - 60.0 % of mass 95 50.4
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.8
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 80.2
175 5.0 - 9.0 % of mass 174 6.4 (8.0)1
176 95.0 - 101.0 % of mass 174 77.2 (96.2)1
177 5.0 - 9.0 % of mass 176 5.1 (6.6)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCV 280-634482/2 X510784.D 11/17/2023 18:43
LCS 280-633952/2-A X510785.D 11/17/2023 19:04
LCSD 280-633952/3-A X510786.D 11/17/2023 19:24
LB 280-633952/1-A X510790.D 11/17/2023 20:46
ST071-SoilIDW-11092023 280-184424-1 X510802.D 11/18/2023 0:57
CCVC 280-634482/24 X510804.D 11/18/2023 1:39
FORM V 8260D Page 368 of 1261
GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Denver 280-184424-1
SDG No.:
Sample No.:ICIS 280-628924/7 Date Analyzed:10/08/2023 19:25
Lab File ID (Standard):X508910.D
Instrument ID:VMS_X4 GC Column:RXI-624SilMS ID:0.25(mm)
Heated Purge: (Y/N)N
Calibration ID:85604
#RT #RT ##RT ##
FB CBNZd5 DCBd4
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
3004040
751010 180258
721030
313619
1254476
5.20 7.72 9.95INITIAL CALIBRATION MID-POINT
5.70
4.70
8.22
7.22
10.45
9.45
1502020 360515 627238
LAB SAMPLE ID CLIENT SAMPLE ID
ICV 280-628924/11 1453670 353562 602291 5.20 7.72 9.95
CCV 280-634482/2 2318220 624263 1067323 5.20 7.72 9.95
LCS 280-633952/2-A 2235343 602330 1036998 5.20 7.72 9.95
LCSD
280-633952/3-A
2215712 596480 1023110 5.20 7.72 9.95
LB 280-633952/1-A 2125951 576733 1006195 5.20 7.73 9.95
280-184424-1 ST071-SoilIDW-11092
023
2178068 594393 1006328 5.20 7.72 9.95
CCVC 280-634482/24 2234813 606183 1044845 5.20 7.72 9.95
FB = Fluorobenzene
CBNZd5 = Chlorobenzene-d5
DCBd4 = 1,4-Dichlorobenzene-d4
FORM VIII 8260D
# Column used to flag values outside QC limits
Area Limit = 50%-200% of internal standard area
RT Limit = ± 0.5 minutes of internal standard RT
Page 369 of 1261
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:ST071-SoilIDW-11092023 Lab Sample ID:280-184424-1
Matrix:X510802.DLab File ID:
Date Collected:8260DAnalysis Method:
Solid (TCLP)
11/09/2023 16:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
0.5(mL)
0.25(mm)
Date Analyzed:11/18/2023 00:57
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:634482 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
10U8.071-43-2 Benzene 8.0 3.1
150U12078-93-3 2-Butanone (MEK)120 60
10U8.056-23-5 Carbon tetrachloride 8.0 5.7
10U8.0108-90-7 Chlorobenzene 8.0 4.2
10U8.067-66-3 Chloroform 8.0 3.6
10U8.0107-06-2 1,2-Dichloroethane 8.0 5.4
10U8.075-35-4 1,1-Dichloroethene 8.0 2.3
10U8.0127-18-4 Tetrachloroethene 8.0 4.0
10U4.079-01-6 Trichloroethene 4.0 3.0
20U1075-01-4 Vinyl chloride 10 5.1
%RECCAS NO.LIMITSQSURROGATE
101 78-1202037-26-5 Toluene-d8 (Surr)
114 64-12917060-07-0 1,2-Dichloroethane-d4 (Surr)
98 78-121460-00-4 4-Bromofluorobenzene (Surr)
110 79-1191868-53-7 Dibromofluoromethane (Surr)
FORM I 8260D
Page 370 of 1261
Report Date: 20-Nov-2023 22:19:07 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510802.D
Lims ID:280-184424-C-1-B
Client ID:ST071-SoilIDW-11092023
Sample Type:Client
Inject. Date:18-Nov-2023 00:57:30 ALS Bottle#:19 Worklist Smp#:11
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-184424-c-1-b
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:20-Nov-2023 22:14:25
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 2178068 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 89 594393 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 1006328 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.699 4.691 0.008 93 596279 55.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 725211 56.8
$ 6 Toluene-d8 (Surr) 98 6.458 6.450 0.008 95 2568917 50.7
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 916646 49.0
11 Vinyl chloride 62 2.039 ND
21 1,1-Dichloroethene 96 3.047 ND
40 2-Butanone (MEK) 43 4.312 ND
49 Chloroform 83 4.577 ND
53 Carbon tetrachloride 117 4.842 ND
55 Benzene 78 4.992 ND
56 1,2-Dichloroethane 62 5.013 ND 7
60 Trichloroethene 95 5.471 ND
76 Tetrachloroethene 164 6.951 ND
82 Chlorobenzene 112 7.752 ND
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Reagents:
mv-IS_SS_00071 Amount Added: 5.00 Units: uL Run Reagent
Page 371 of 1261
Report Date: 20-Nov-2023 22:19:07 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510802.D
Injection Date:18-Nov-2023 00:57:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:280-184424-C-1-B Lab Sample ID:280-184424-1 Worklist Smp#:11
Client ID:ST071-SoilIDW-11092023
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:19
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
Y ( X
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0
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)
X510802[MS SCAN Chro]:Total
$ D
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Page 372 of 1261
Report Date: 20-Nov-2023 22:19:07 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510802.D
Lims ID:280-184424-C-1-B
Client ID:ST071-SoilIDW-11092023
Sample Type:Client
Inject. Date:18-Nov-2023 00:57:30 ALS Bottle#:19 Worklist Smp#:11
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-184424-c-1-b
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:20-Nov-2023 22:14:25
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 55.2 110.49
$5 1,2-Dichloroethane-d4 (Surr)50.0 56.8 113.69
$6 Toluene-d8 (Surr)50.0 50.7 101.33
$7 4-Bromofluorobenzene (Surr)50.0 49.0 98.01
Page 373 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
0.25(mm)RXI-624SilMSID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:
1Level IC 280-628924/2 X508905.D
2Level IC 280-628924/3 X508906.D
3Level IC 280-628924/4 X508907.D
4Level IC 280-628924/5 X508908.D
5Level IC 280-628924/6 X508909.D
6Level ICIS 280-628924/7 X508910.D
7Level IC 280-628924/8 X508911.D
8Level IC 280-628924/9 X508912.D
9Level IC 280-628924/10 X508913.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane ++++++++++0.1602 0.1528 0.2623 Lin1 0.9990
0.2650 0.2634 0.2571 0.2556
0.9900-0.24
7
0.260
8
Chloromethane +++++0.2401 0.2699 0.2347 0.3342 Lin2 0.9910
0.3085 0.3109 0.3061 0.3029
0.1000 0.9900-0.07
2
0.305
0
Vinyl chloride +++++0.2353 0.2490 0.2298 0.3251 Ave 12.9
0.3037 0.3033 0.2962 0.2978
30.00.280
0
Bromomethane +++++0.2242 0.1692 0.1653 0.1899 Ave 11.2
0.1668 0.1688 0.1699 0.1735
15.00.178
4
Chloroethane +++++0.1944 0.1747 0.1628 0.2239 Ave 9.7
0.1824 0.1885 0.1818 0.1793
15.00.186
0
Dichlorofluoromethane +++++0.6015 0.4924 0.4299 0.5070 Ave 10.2
0.4898 0.4727 0.4744 0.4625
15.00.491
3
Trichlorofluoromethane +++++0.3370 0.3439 0.2891 0.3819 Ave 7.9
0.3632 0.3651 0.3542 0.3545
15.00.348
6
Ethyl ether 0.2516 0.2445 0.2277 0.1972 0.2163 Ave 9.2
0.2026 0.2018 0.2060 0.2053
15.00.217
0
Acrolein 0.0366 0.0327 0.0312 0.0287 0.0319 Ave 7.7
0.0298 0.0294 0.0309 0.0293
15.00.031
2
1,1,2-Trichloro-1,2,2-trifluoroeth
ane
0.1310 0.1575 0.1641 0.1594 0.1799 Ave 8.7
0.1695 0.1733 0.1713 0.1715
15.00.164
2
1,1-Dichloroethene +++++0.2001 0.2118 0.2138 0.2389 Ave 6.0
0.2014 0.2022 0.2076 0.2071
30.00.210
3
Acetone +++++0.1606 0.1256 0.0864 0.0867 Lin2 0.9940
0.0726 0.0669 0.0734 0.0689
0.99000.373
1
0.071
1
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 374 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Iodomethane +++++0.2772 0.2673 0.2367 0.3215 Ave 10.8
0.3179 0.3258 0.3124 0.3083
15.00.295
9
Carbon disulfide 0.7274 0.7499 0.6872 0.6246 0.7871 Ave 6.4
0.6943 0.7017 0.6946 0.6906
15.00.706
4
Methyl acetate 0.2199 0.2609 0.1711 0.1574 0.1918 Lin1 0.9980
0.1796 0.1764 0.1909 0.1772
0.99000.053
7
0.180
2
3-Chloro-1-propene 0.5420 0.5263 0.5545 0.4422 0.5081 Qua 0.9990
0.4115 0.3876 0.3931 0.2828
0.99000.016
0
0.472
8
-0.000946
Methylene Chloride 0.2802 0.3068 0.2460 0.2537 0.2633 Ave 8.7
0.2424 0.2432 0.2421 0.2432
15.00.257
9
2-Methyl-2-propanol 0.0251 0.0227 0.0238 0.0224 0.0257 Ave 4.9
0.0243 0.0229 0.0250 0.0240
15.00.024
0
Acrylonitrile 0.1037 0.0870 0.0971 0.0914 0.1031 Ave 6.0
0.0936 0.0916 0.0961 0.0900
15.00.094
9
Methyl tert-butyl ether 0.7007 0.5773 0.6410 0.5953 0.7241 Ave 7.4
0.6826 0.6830 0.6943 0.6793
15.00.664
2
trans-1,2-Dichloroethene 0.2681 0.3328 0.2745 0.2249 0.2662 Ave 13.2
0.2315 0.2346 0.2382 0.2360
15.00.256
3
Hexane 1.9805 1.7836 1.3633 1.1510 1.4287 Lin1 0.9990
1.4507 1.4575 1.4724 1.4554
0.99000.119
9
1.453
5
Vinyl acetate 0.5831 0.6353 0.4735 0.4399 0.5535 Ave 11.6
0.4938 0.5020 0.5080 0.4867
15.00.519
5
1,1-Dichloroethane 0.4302 0.4910 0.4636 0.4328 0.5213 Ave 6.0
0.4614 0.4636 0.4635 0.4598
0.1000 15.00.465
2
2-Butanone (MEK)0.1214 0.1425 0.1125 0.1004 0.1174 Ave 9.9
0.1128 0.1092 0.1182 0.1129
15.00.116
4
cis-1,2-Dichloroethene +++++0.3408 0.2726 0.2740 0.2899 Ave 9.5
0.2622 0.2660 0.2629 0.2643
15.00.279
1
2,2-Dichloropropane +++++0.4667 0.4227 0.3743 0.4554 Ave 8.4
0.3890 0.3913 0.3900 0.3907
15.00.410
0
sec-Butyl Alcohol +++++0.0207 0.0206 0.0190 0.0229 Ave 5.8
0.0211 0.0196 0.0216 0.0203
15.00.020
7
Chlorobromomethane +++++0.1299 0.1201 0.1119 0.1361 Ave 7.1
0.1166 0.1150 0.1158 0.1141
15.00.119
9
Tetrahydrofuran +++++0.0836 0.0834 0.0731 0.0841 Ave 6.3
0.0750 0.0735 0.0771 0.0737
15.00.077
9
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 375 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Chloroform +++++0.4661 0.4426 0.4005 0.4794 Ave 6.0
0.4205 0.4256 0.4211 0.4235
30.00.434
9
1,1,1-Trichloroethane 0.4081 0.4004 0.3777 0.3251 0.3977 Ave 6.4
0.3712 0.3759 0.3779 0.3760
15.00.378
9
Cyclohexane 0.4068 0.4668 0.4986 0.4334 0.5069 Ave 6.5
0.4623 0.4678 0.4652 0.4623
15.00.463
3
1,1-Dichloropropene 0.3658 0.3196 0.3238 0.3268 0.3761 Ave 5.9
0.3518 0.3609 0.3627 0.3572
15.00.349
4
Carbon tetrachloride 0.4012 0.3581 0.3394 0.3140 0.3515 Ave 7.6
0.3217 0.3290 0.3328 0.3306
15.00.342
0
Isobutyl alcohol +++++0.0112 0.0098 0.0077 0.0091 Ave 12.7
0.0080 0.0082 0.0091 0.0086
15.00.009
0
Benzene 1.0374 1.0174 1.0319 0.9595 1.1482 Ave 4.9
1.0099 1.0281 1.0226 1.0051
15.01.028
9
1,2-Dichloroethane 0.3536 0.3395 0.3363 0.3069 0.3453 Ave 3.9
0.3284 0.3327 0.3312 0.3294
15.00.333
7
n-Heptane ++++++++++0.4414 0.3067 0.3290 Lin2 0.9940
0.3038 0.3095 0.3215 0.3097
0.99000.245
2
0.301
9
Trichloroethene +++++1.1018 1.0816 0.9863 1.1663 Ave 4.9
1.0482 1.0468 1.0521 1.0438
15.01.065
9
2-Pentanone 0.1869 0.1943 0.1898 0.1737 0.1902 Ave 4.3
0.1800 0.1739 0.1852 0.1745
15.00.183
2
Methylcyclohexane 0.3711 0.4392 0.3482 0.3170 0.3565 Ave 9.3
0.3413 0.3503 0.3535 0.3507
15.00.358
6
1,2-Dichloropropane 0.2537 0.3059 0.2772 0.2471 0.2964 Ave 6.6
0.2719 0.2780 0.2777 0.2795
30.00.276
4
1,4-Dioxane +++++0.0030 0.0027 0.0033 0.0034 Ave 6.6
0.0031 0.0031 0.0032 0.0031
15.00.003
1
Dibromomethane +++++0.1556 0.1487 0.1398 0.1547 Ave 4.3
0.1404 0.1415 0.1445 0.1423
15.00.145
9
Dichlorobromomethane +++++0.3936 0.3820 0.3208 0.3623 Ave 7.5
0.3290 0.3348 0.3409 0.3366
15.00.350
0
2-Chloroethyl vinyl ether +++++0.1568 0.1482 0.1465 0.1683 Ave 6.9
0.1733 0.1681 0.1755 0.1689
15.00.163
2
cis-1,3-Dichloropropene 1.8100 1.5643 1.6698 1.6408 1.8124 Ave 5.2
1.7875 1.7741 1.8164 1.7733
15.01.738
7
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 376 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
4-Methyl-2-pentanone (MIBK)0.2399 0.2663 0.2395 0.2428 0.2588 Ave 5.0
0.2399 0.2315 0.2426 0.2278
15.00.243
2
Toluene 1.1639 1.2403 1.1403 1.0587 1.2336 Ave 6.1
1.0778 1.0997 1.0879 1.0693
30.01.130
2
trans-1,3-Dichloropropene 0.3848 0.3958 0.3802 0.3688 0.4152 Ave 3.5
0.3945 0.3987 0.4047 0.3967
15.00.393
3
Ethyl methacrylate +++++1.5199 1.4197 1.2367 1.4420 Ave 7.1
1.3442 1.2826 1.3457 1.2715
15.01.357
8
1,1,2-Trichloroethane +++++0.2153 0.2566 0.2033 0.2276 Ave 7.9
0.2092 0.2089 0.2121 0.2086
15.00.217
7
Tetrachloroethene +++++0.7241 0.7394 0.7492 0.8655 Ave 6.9
0.8062 0.8401 0.8496 0.8274
15.00.800
2
1,3-Dichloropropane 1.6191 1.5630 1.3819 1.4179 1.6494 Ave 5.8
1.5821 1.5495 1.6075 1.5532
15.01.547
1
2-Hexanone 0.8318 0.7082 0.6695 0.6509 0.7578 Ave 8.6
0.6994 0.6594 0.6965 0.6424
15.00.701
8
Chlorodibromomethane 1.0197 1.2342 1.0734 0.9246 1.0962 Ave 8.0
1.0258 1.0124 1.0433 1.0129
15.01.049
2
Ethylene Dibromide +++++0.9408 0.9302 0.8084 0.9682 Ave 5.6
0.8899 0.8679 0.9053 0.8682
15.00.897
4
1-Chlorohexane +++++2.2757 1.8644 1.5266 1.5812 Lin2 0.9990
1.4400 1.4534 1.4701 1.4318
0.99000.666
5
1.437
9
Chlorobenzene 3.0469 2.9904 2.8435 2.4998 3.0093 Ave 6.3
2.7429 2.7492 2.7518 2.6802
0.3000 15.02.812
7
1,1,1,2-Tetrachloroethane 0.8851 1.0124 0.9131 0.8940 1.0404 Ave 5.6
0.9770 0.9830 0.9920 0.9826
15.00.964
4
Ethylbenzene 1.6664 1.6945 1.5537 1.3912 1.6880 Ave 6.1
1.5317 1.5434 1.5515 1.5489
30.01.574
4
m-Xylene & p-Xylene 1.8399 1.6767 1.9272 1.7585 2.0572 Ave 6.0
1.9209 1.9499 1.9460 1.9145
15.01.887
9
o-Xylene 2.0306 1.9146 1.8942 1.7560 2.0487 Ave 4.5
1.9196 1.8823 1.9049 1.8684
15.01.913
3
Styrene 3.3908 3.1173 3.3612 2.9783 3.4873 Ave 4.8
3.2194 3.2241 3.1991 3.1312
15.03.234
3
Bromoform 0.6864 0.6480 0.6675 0.6508 0.7887 Ave 6.3
0.7253 0.7060 0.7286 0.7011
0.1000 15.00.700
3
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 377 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Isopropylbenzene 2.5864 3.0227 2.8372 2.5432 3.0960 Ave 6.4
2.7615 2.8256 2.8358 2.7235
15.02.803
5
Cyclohexanone 0.0723 0.0532 0.0436 0.0487 0.0544 Lin1 0.9970
0.0485 0.0448 0.0484 0.0438
0.99000.366
5
0.045
6
1,1,2,2-Tetrachloroethane +++++0.6187 0.6256 0.6197 0.7481 Ave 6.6
0.6661 0.6489 0.6824 0.6417
0.3000 15.00.656
4
trans-1,4-Dichloro-2-butene 0.4676 0.3166 0.3003 0.2413 0.2734 Lin2 0.9920
0.2287 0.2204 0.2399 0.2171
0.99000.114
2
0.229
6
Bromobenzene 0.5306 0.6285 0.6474 0.6218 0.7300 Ave 8.7
0.6601 0.6866 0.6884 0.6792
15.00.652
5
1,2,3-Trichloropropane +++++0.2297 0.1839 0.1781 0.2270 Ave 9.4
0.1961 0.1939 0.1977 0.1908
15.00.199
7
N-Propylbenzene 0.7678 0.8371 0.7473 0.7246 0.8605 Ave 5.5
0.7611 0.7755 0.7877 0.7702
15.00.781
3
2-Chlorotoluene 0.6555 0.6715 0.6825 0.5689 0.6961 Ave 5.7
0.6266 0.6465 0.6506 0.6501
15.00.649
8
1,3,5-Trimethylbenzene 2.4753 2.3121 2.4743 2.1965 2.6597 Ave 5.4
2.3658 2.4027 2.4351 2.3223
15.02.404
9
4-Chlorotoluene 0.7433 0.6784 0.6412 0.6245 0.7482 Ave 6.1
0.6612 0.6823 0.6891 0.6726
15.00.682
3
tert-Butylbenzene 2.3510 2.1330 2.0722 1.8520 2.1554 Ave 6.8
1.9616 2.0317 2.0330 1.9815
15.02.063
5
1,2,4-Trimethylbenzene 2.6249 2.4285 2.5484 2.2447 2.7247 Ave 5.5
2.4344 2.5091 2.5263 2.4023
15.02.493
7
sec-Butylbenzene 0.4886 0.5847 0.5213 0.5112 0.6282 Ave 8.1
0.5676 0.5861 0.5968 0.5796
15.00.562
7
1,3-Dichlorobenzene 0.9789 1.2548 1.2243 1.1624 1.3786 Ave 9.2
1.2464 1.3078 1.3089 1.2799
15.01.238
0
4-Isopropyltoluene 2.7288 2.6660 2.5075 2.3406 2.7739 Ave 5.3
2.4808 2.5606 2.5837 2.4761
15.02.568
7
1,4-Dichlorobenzene 1.2380 1.2811 1.2799 1.1767 1.4345 Ave 5.4
1.2821 1.3177 1.3212 1.2881
15.01.291
0
n-Butylbenzene 2.2909 2.3295 2.3834 2.0377 2.4483 Ave 5.2
2.2141 2.2841 2.3130 2.2002
15.02.277
9
1,2-Dichlorobenzene 1.1776 1.1908 1.1435 1.0575 1.3269 Ave 6.0
1.1824 1.2066 1.2358 1.1882
15.01.189
9
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 378 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
1,2-Dibromo-3-Chloropropane +++++++++++++++0.1484 0.1839 Ave 9.8
0.1504 0.1451 0.1563 0.1429
15.00.154
5
1,2,4-Trichlorobenzene 0.7005 0.6477 0.6825 0.6551 0.7936 Ave 6.6
0.7002 0.7342 0.7582 0.7088
15.00.709
0
Hexachlorobutadiene +++++0.3217 0.3735 0.3192 0.3690 Ave 6.3
0.3245 0.3442 0.3603 0.3374
15.00.343
7
Naphthalene 1.8970 1.8841 1.6191 1.6330 1.8931 Ave 7.2
1.6770 1.6762 1.7926 1.5995
15.01.741
3
1,2,3-Trichlorobenzene 0.5413 0.6107 0.5899 0.5277 0.5979 Ave 5.2
0.5578 0.5656 0.6024 0.5485
15.00.571
3
Dibromofluoromethane (Surr)0.2436 0.2541 0.2487 0.2523 0.2503 Ave 1.5
0.2458 0.2443 0.2439 0.2468
15.00.247
8
1,2-Dichloroethane-d4 (Surr)0.2969 0.2929 0.2989 0.3043 0.2892 Ave 2.1
0.2863 0.2861 0.2901 0.2910
15.00.292
9
Toluene-d8 (Surr)4.2224 4.2296 4.2806 4.1846 4.2793 Ave 1.2
4.3592 4.2566 4.3162 4.2589
15.04.265
3
4-Bromofluorobenzene (Surr)0.9275 0.9380 0.9241 0.9231 0.9321 Ave 0.7
0.9262 0.9338 0.9380 0.9218
15.00.929
4
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 379 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
GC Column:RXI-624SilMSID:0.25(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 IC 280-628924/2 X508905.D
Level 2 IC 280-628924/3 X508906.D
Level 3 IC 280-628924/4 X508907.D
Level 4 IC 280-628924/5 X508908.D
Level 5 IC 280-628924/6 X508909.D
Level 6 ICIS 280-628924/7 X508910.D
Level 7 IC 280-628924/8 X508911.D
Level 8 IC 280-628924/9 X508912.D
Level 9 IC 280-628924/10 X508913.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane Lin1FB ++++++++++8970 22048 74469 ++++++++++2.00 5.00 10.0
398079 20010075.050.01594454776106608229
Chloromethane Lin2FB +++++6747 15118 33863 94870 +++++1.00 2.00 5.00 10.0
463435 20010075.050.01889370924009718140
Vinyl chloride AveFB +++++6612 13945 33161 92301 +++++1.00 2.00 5.00 10.0
456172 20010075.050.01857483893921700548
Bromomethane AveFB +++++6299 9476 23848 53918 +++++1.00 2.00 5.00 10.0
250463 20010075.050.01082108512908389782
Chloroethane AveFB +++++5464 9785 23490 63560 +++++1.00 2.00 5.00 10.0
274029 20010075.050.01118285548760435347
Dichlorofluoromethane AveFB +++++16902 27578 62042 143927 +++++1.00 2.00 5.00 10.0
735625 20010075.050.0288479114319211091645
Trichlorofluoromethane AveFB +++++9470 19263 41716 108401 +++++1.00 2.00 5.00 10.0
545491 20010075.050.022113351069119843141
Ethyl ether AveFB 3662 6870 12751 28452 61392 0.500 1.00 2.00 5.00 10.0
304348 20010075.050.01280417621848465957
Acrolein AveFB 5254 9063 17239 40933 89378 4.94 9.88 19.8 49.4 98.8
441942 19759887414941806565920279670407
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
AveFB 1907 4427 9189 22997 51056 0.500 1.00 2.00 5.00 10.0
254666 20010075.050.01069824516915400131
1,1-Dichloroethene AveFB +++++5622 11862 30846 67830 +++++1.00 2.00 5.00 10.0
302490 20010075.050.01291411626649466881
Acetone Lin2FB +++++18046 28136 49889 98457 +++++4.00 8.00 20.0 40.0
436015 8004003002001720188886169618145
Iodomethane AveFB +++++7790 14972 34156 91269 +++++1.00 2.00 5.00 10.0
477505 20010075.050.01922692942958752530
Carbon disulfide AveFB 10585 21073 38487 90139 223452 0.500 1.00 2.00 5.00 10.0
1042787 20010075.050.0430735920965891620608
FORM VI 8260D Page 380 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Methyl acetate Lin1FB 6399 14664 19163 45429 108898 1.00 2.00 4.00 10.0 20.0
539505 40020015010022110091152098814698
3-Chloro-1-propene QuaFB 7887 14788 31056 63813 144245 0.500 1.00 2.00 5.00 10.0
618018 20010075.050.017636371186490895173
Methylene Chloride AveFB 4077 8620 13779 36611 74757 0.500 1.00 2.00 5.00 10.0
364031 20010075.050.01516821730862561742
2-Methyl-2-propanol AveFB 3659 6375 13327 32270 73003 5.00 10.0 20.0 50.0 100
365034 200010007505001496095753849529565
Acrylonitrile AveFB 15095 24457 54368 131928 292624 5.00 10.0 20.0 50.0 100
1406464 20001000750500561637529000352114764
Methyl tert-butyl ether AveFB 10197 16223 35900 85899 205547 0.500 1.00 2.00 5.00 10.0
1025272 20010075.050.0423689720956461577468
trans-1,2-Dichloroethene AveFB 3901 9351 15374 32448 75568 0.500 1.00 2.00 5.00 10.0
347741 20010075.050.01472091719073541929
Hexane Lin1CBNZd
5
7239 12779 19134 42061 100743 0.500 1.00 2.00 5.00 10.0
522985 20010075.050.022356021079597821966
Vinyl acetate AveFB 16972 35704 53039 126969 314246 1.00 2.00 4.00 10.0 20.0
1483261 400200150100607081330667652318930
1,1-Dichloroethane AveFB 6261 13797 25963 62462 147981 0.500 1.00 2.00 5.00 10.0
692971 20010075.050.0286801713990061070605
2-Butanone (MEK)AveFB 7069 16015 25205 57977 133268 2.00 4.00 8.00 20.0 40.0
678002 800400300200281755214268651009078
cis-1,2-Dichloroethene AveFB +++++9576 15270 39539 82299 +++++1.00 2.00 5.00 10.0
393792 20010075.050.01648154793464614390
2,2-Dichloropropane AveFB +++++13113 23672 54009 129274 +++++1.00 2.00 5.00 10.0
584240 20010075.050.024367311176977903616
sec-Butyl Alcohol AveFB +++++13976 27684 65708 156067 +++++24.0 48.0 120 240
759145 4800240018001200304003815638691087196
Chlorobromomethane AveFB +++++3649 6726 16152 38626 +++++1.00 2.00 5.00 10.0
175142 20010075.050.0711787349629265679
Tetrahydrofuran AveFB +++++4698 9345 21107 47742 +++++2.00 4.00 10.0 20.0
225170 400200150100919668465397339612
Chloroform AveFB +++++13096 24788 57788 136084 +++++1.00 2.00 5.00 10.0
631528 20010075.050.026413891271065982830
1,1,1-Trichloroethane AveFB 5939 11250 21154 46910 112889 0.500 1.00 2.00 5.00 10.0
557595 20010075.050.023450291140489868188
Cyclohexane AveFB 5920 13118 27923 62539 143909 0.500 1.00 2.00 5.00 10.0
694448 20010075.050.0288359714039911080284
1,1-Dichloropropene AveFB 5323 8980 18136 47155 106780 0.500 1.00 2.00 5.00 10.0
528404 20010075.050.022278941094867833508
FORM VI 8260D Page 381 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Carbon tetrachloride AveFB 5838 10062 19009 45307 99795 0.500 1.00 2.00 5.00 10.0
483218 20010075.050.020620901004463759914
Isobutyl alcohol AveFB +++++7879 13672 27803 64738 +++++25.0 50.0 125 250
299463 50002500187512501339932685011472180
Benzene AveFB 15096 28588 57794 138461 325958 0.500 1.00 2.00 5.00 10.0
1516881 20010075.050.0626886130865512374523
1,2-Dichloroethane AveFB 5146 9540 18837 44281 98031 0.500 1.00 2.00 5.00 10.0
493315 20010075.050.02054517999765768282
n-Heptane Lin2FB ++++++++++24719 44253 93392 ++++++++++2.00 5.00 10.0
456301 20010075.050.01931736970428714896
Trichloroethene AveCBNZd
5
+++++7894 15181 36040 82241 +++++1.00 2.00 5.00 10.0
377900 20010075.050.01603326771441590373
2-Pentanone AveFB 8703 17472 34021 80204 172787 1.60 3.20 6.40 16.0 32.0
865305 640320240160348377317885591285337
Methylcyclohexane AveFB 5401 12341 19503 45745 101202 0.500 1.00 2.00 5.00 10.0
512571 20010075.050.021870991066998809132
1,2-Dichloropropane AveFB 3692 8597 15524 35662 84150 0.500 1.00 2.00 5.00 10.0
408366 20010075.050.01743360838306642074
1,4-Dioxane AveFB +++++1678 3069 9404 19423 +++++20.0 40.0 100 200
92379 4000200015001000381034195126142479
Dibromomethane AveFB +++++4372 8326 20175 43907 +++++1.00 2.00 5.00 10.0
210958 20010075.050.0887272436080326802
Dichlorobromomethane AveFB +++++11061 21395 46296 102843 +++++1.00 2.00 5.00 10.0
494092 20010075.050.020992511029064773302
2-Chloroethyl vinyl ether AveFB +++++4407 8301 21137 47787 +++++1.00 2.00 5.00 10.0
260306 20010075.050.01053443529631388338
cis-1,3-Dichloropropene AveCBNZd
5
6616 11208 23436 59958 127798 0.500 1.00 2.00 5.00 10.0
644431 20010075.050.0272386113318381000528
4-Methyl-2-pentanone (MIBK)AveFB 13965 29933 53645 140134 293844 2.00 4.00 8.00 20.0 40.0
1441546 800400300200568359729290142138435
Toluene AveFB 16937 34851 63863 152771 350189 0.500 1.00 2.00 5.00 10.0
1618912 20010075.050.0666935232834982539888
trans-1,3-Dichloropropene AveFB 5600 11121 21294 53223 117863 0.500 1.00 2.00 5.00 10.0
592518 20010075.050.024739651221611920830
Ethyl methacrylate AveCBNZd
5
+++++10890 19926 45193 101676 +++++1.00 2.00 5.00 10.0
484602 20010075.050.01953157986751723347
1,1,2-Trichloroethane AveFB +++++6051 14372 29332 64600 +++++1.00 2.00 5.00 10.0
314201 20010075.050.01301020640290482502
FORM VI 8260D Page 382 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Tetrachloroethene AveCBNZd
5
+++++5188 10378 27376 61027 +++++1.00 2.00 5.00 10.0
290651 20010075.050.01270979622945473804
1,3-Dichloropropane AveCBNZd
5
5918 11199 19395 51814 116301 0.500 1.00 2.00 5.00 10.0
570375 20010075.050.023857541178677873884
2-Hexanone AveCBNZd
5
12162 20297 37589 95146 213731 2.00 4.00 8.00 20.0 40.0
1008581 800400300200394718820427001487533
Chlorodibromomethane AveCBNZd
5
3727 8843 15066 33786 77299 0.500 1.00 2.00 5.00 10.0
369819 20010075.050.01555933765001570984
Ethylene Dibromide AveCBNZd
5
+++++6741 13055 29539 68270 +++++1.00 2.00 5.00 10.0
320814 20010075.050.01333646663819489465
1-Chlorohexane Lin2CBNZd
5
+++++13044 20934 44628 89196 +++++0.800 1.60 4.00 8.00
415301 16080.060.040.01759464862360655743
Chlorobenzene AveCBNZd
5
11137 21426 39909 91349 212195 0.500 1.00 2.00 5.00 10.0
988868 20010075.050.0411698820177341550437
1,1,1,2-Tetrachloroethane AveCBNZd
5
3235 7254 12816 32670 73365 0.500 1.00 2.00 5.00 10.0
352209 20010075.050.01509298727377554372
Ethylbenzene AveCBNZd
5
6091 12141 21806 50836 119027 0.500 1.00 2.00 5.00 10.0
552194 20010075.050.023792161137609870429
m-Xylene & p-Xylene AveCBNZd
5
6725 12013 27048 64259 145062 0.500 1.00 2.00 5.00 10.0
692516 20010075.050.0294081614268921099694
o-Xylene AveCBNZd
5
7422 13718 26585 64167 144463 0.500 1.00 2.00 5.00 10.0
692062 20010075.050.0287000013967241061567
Styrene AveCBNZd
5
12394 22335 47175 108832 245901 0.500 1.00 2.00 5.00 10.0
1160660 20010075.050.0480971223456641818307
Bromoform AveCBNZd
5
2509 4643 9369 23780 55610 0.500 1.00 2.00 5.00 10.0
261485 20010075.050.01076986534238398145
Isopropylbenzene AveDCBd4 16007 36202 67960 158638 368994 0.500 1.00 2.00 5.00 10.0
1732100 20010075.050.0718047635359812712108
Cyclohexanone Lin1CBNZd
5
7928 11438 18342 53419 115097 15.0 30.0 60.0 150 300
FORM VI 8260D Page 383 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
525064 600030002250150020179721065134757616
1,1,2,2-Tetrachloroethane AveDCBd4 +++++7410 14985 38653 89157 +++++1.00 2.00 5.00 10.0
417787 20010075.050.01691801850876622800
trans-1,4-Dichloro-2-butene Lin2DCBd4 2894 3792 7194 15049 32582 0.500 1.00 2.00 5.00 10.0
143467 20010075.050.0572452299158211545
Bromobenzene AveDCBd4 3284 7528 15507 38784 87001 0.500 1.00 2.00 5.00 10.0
414068 20010075.050.01790798858432659027
1,2,3-Trichloropropane AveDCBd4 +++++2751 4406 11111 27054 +++++1.00 2.00 5.00 10.0
123017 20010075.050.0502919246464186150
N-Propylbenzene AveDCBd4 4752 10026 17901 45196 102553 0.500 1.00 2.00 5.00 10.0
477375 20010075.050.02030536982157744378
2-Chlorotoluene AveDCBd4 4057 8042 16347 35486 82964 0.500 1.00 2.00 5.00 10.0
393028 20010075.050.01713968811176620568
1,3,5-Trimethylbenzene AveDCBd4 15319 27691 59267 137014 316997 0.500 1.00 2.00 5.00 10.0
1483899 20010075.050.0612276730363652306259
4-Chlorotoluene AveDCBd4 4600 8125 15359 38956 89175 0.500 1.00 2.00 5.00 10.0
414729 20010075.050.01773248859284654910
tert-Butylbenzene AveDCBd4 14550 25546 49636 115520 256893 0.500 1.00 2.00 5.00 10.0
1230403 20010075.050.0522414625349951950076
1,2,4-Trimethylbenzene AveDCBd4 16245 29086 61042 140020 324741 0.500 1.00 2.00 5.00 10.0
1526928 20010075.050.0633364431500352408360
sec-Butylbenzene AveDCBd4 3024 7003 12487 31890 74876 0.500 1.00 2.00 5.00 10.0
356000 20010075.050.01528084744173562585
1,3-Dichlorobenzene AveDCBd4 6058 15029 29325 72507 164309 0.500 1.00 2.00 5.00 10.0
781813 20010075.050.0337445116320351255280
4-Isopropyltoluene AveDCBd4 16888 31930 60064 146002 330604 0.500 1.00 2.00 5.00 10.0
1556031 20010075.050.0652818432216522457795
1,4-Dichlorobenzene AveDCBd4 7662 15343 30657 73400 170972 0.500 1.00 2.00 5.00 10.0
804154 20010075.050.0339616916473981264745
n-Butylbenzene AveDCBd4 14178 27900 57090 127109 291802 0.500 1.00 2.00 5.00 10.0
1388744 20010075.050.0580089828840422192336
1,2-Dichlorobenzene AveDCBd4 7288 14262 27391 65964 158147 0.500 1.00 2.00 5.00 10.0
741617 20010075.050.0313277615409711158131
1,2-Dibromo-3-Chloropropane AveDCBd4 +++++++++++++++9254 21923 +++++++++++++++5.00 10.0
94359 20010075.050.0376740194952139253
1,2,4-Trichlorobenzene AveDCBd4 4335 7757 16347 40864 94588 0.500 1.00 2.00 5.00 10.0
439187 20010075.050.01868862945366704738
Hexachlorobutadiene AveDCBd4 +++++3853 8946 19909 43983 +++++1.00 2.00 5.00 10.0
203543 20010075.050.0889637449216330387
Naphthalene AveDCBd4 11740 22565 38782 101863 225625 0.500 1.00 2.00 5.00 10.0
1051863 20010075.050.0421720422352291608855
FORM VI 8260D Page 384 of 1261
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:628924
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
85604Calibration Start Date:Calibration End Date:10/08/2023 17:38
N
10/08/2023 20:26
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
1,2,3-Trichlorobenzene AveDCBd4 3350 7314 14131 32915 71263 0.500 1.00 2.00 5.00 10.0
349903 20010075.050.01446093751174542899
Dibromofluoromethane (Surr)AveFB 354484 357025 348246 364068 355257 50.0 50.0 50.0 50.0 50.0
369268 50.050.050.050.0384808368114376197
1,2-Dichloroethane-d4 (Surr)AveFB 432018 411553 418567 439167 410433 50.0 50.0 50.0 50.0 50.0
430064 50.050.050.050.0453734437780440539
Toluene-d8 (Surr)AveCBNZd
5
1543355 1515235 1501993 1529125 1508711 50.0 50.0 50.0 50.0 50.0
1571566 50.050.050.050.0163549715823881600396
4-Bromofluorobenzene (Surr)AveDCBd4 574005 561696 553358 575779 555433 50.0 50.0 50.0 50.0 50.0
580978 50.050.050.050.0607600584827597540
Curve Type Legend:
Ave = Average ISTD
Lin1 = Linear 1/conc ISTD
Lin2 = Linear 1/conc^2 ISTD
Qua = Quadratic ISTD
FORM VI 8260D Page 385 of 1261
Report Date: 09-Oct-2023 13:08:46 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508905.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:08-Oct-2023 17:38:30 ALS Bottle#:100 Worklist Smp#:2
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:08:45 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1455245 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 365516 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 618886 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 354484 50.0 49.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 432018 50.0 50.7
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1543355 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 574005 50.0 49.9
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 98 16184 0.5000 3.08
10 Chloromethane 50 1.939 1.939 0.000 99 18204 0.5000 2.29
11 Vinyl chloride 62 2.039 2.039 0.000 97 15899 0.5000 1.95
12 Bromomethane 94 2.332 2.332 0.000 87 8292 0.5000 1.60
13 Chloroethane 64 2.425 2.425 0.000 94 11052 0.5000 2.04
14 Dichlorofluoromethane 67 2.596 2.596 0.000 95 27093 0.5000 1.89
16 Trichlorofluoromethane 101 2.632 2.632 0.000 97 20783 0.5000 2.05
18 Ethyl ether 59 2.847 2.847 0.000 80 3662 0.5000 0.5798
19 Acrolein 56 2.961 2.961 0.000 61 5254 4.94 5.79
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.047 3.040 0.007 76 1907 0.5000 0.3991
21 1,1-Dichloroethene 96 3.047 3.047 0.000 92 4572 0.5000 0.7468
22 Acetone 43 3.068 3.061 0.007 98 20608 2.00 4.71
24 Iodomethane 142 3.168 3.168 0.000 97 7658 0.5000 0.8892
25 Carbon disulfide 76 3.226 3.233 -0.007 99 10585 0.5000 0.5149
27 Methyl acetate 43 3.290 3.290 0.000 77 6399 1.00 0.9221
28 3-Chloro-1-propene 41 3.311 3.311 0.000 77 7887 0.5000 0.5398
29 Methylene Chloride 84 3.412 3.412 0.000 96 4077 0.5000 0.5432
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 7 3659 5.00 5.24
31 Acrylonitrile 53 3.576 3.576 0.000 99 15095 5.00 5.47
32 Methyl tert-butyl ether 73 3.590 3.597 -0.007 93 10197 0.5000 0.5275
33 trans-1,2-Dichloroethene 96 3.605 3.612 -0.007 35 3901 0.5000 0.5229
34 Hexane 57 3.805 3.805 0.000 80 7239 0.5000 0.5988
35 Vinyl acetate 43 3.905 3.905 0.000 97 16972 1.00 1.12
36 1,1-Dichloroethane 63 3.926 3.933 -0.007 91 6261 0.5000 0.4624
40 2-Butanone (MEK) 43 4.320 4.312 0.008 80 7069 2.00 2.09
Page 386 of 1261
Report Date: 09-Oct-2023 13:08:46 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508905.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 4802 0.5000 0.5912
43 2,2-Dichloropropane 77 4.355 4.355 0.000 68 7404 0.5000 0.6205
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 92 4877 12.0 8.09
47 Chlorobromomethane 128 4.513 4.520 -0.007 4 2221 0.5000 0.6362
48 Tetrahydrofuran 42 4.520 4.527 -0.007 27 1736 1.00 0.7653
49 Chloroform 83 4.570 4.577 -0.007 32 3100 0.5000 0.2449
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 93 5939 0.5000 0.5386
51 Cyclohexane 56 4.770 4.784 -0.014 59 5920 0.5000 0.4390
52 1,1-Dichloropropene 75 4.827 4.834 -0.007 84 5323 0.5000 0.5234
53 Carbon tetrachloride 117 4.842 4.842 0.000 86 5838 0.5000 0.5864
54 Isobutyl alcohol 41 4.842 4.842 0.000 76 2682 12.5 10.3
55 Benzene 78 4.992 4.992 0.000 92 15096 0.5000 0.5041
56 1,2-Dichloroethane 62 5.013 5.013 0.000 92 5146 0.5000 0.5298
58 n-Heptane 43 5.163 5.170 -0.007 83 5107 0.5000 -0.2310
60 Trichloroethene 95 5.471 5.471 0.000 88 7333 0.5000 0.9411
61 2-Pentanone 43 5.571 5.578 -0.007 94 8703 1.60 1.63
62 Methylcyclohexane 55 5.664 5.671 -0.007 82 5401 0.5000 0.5174
63 1,2-Dichloropropane 63 5.678 5.678 0.000 76 3692 0.5000 0.4590
65 1,4-Dioxane 88 5.721 ND ND
66 Dibromomethane 93 5.750 5.750 0.000 40 2732 0.5000 0.6433
67 Dichlorobromomethane 83 5.871 ND ND
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 83 8863 0.5000 1.87
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 91 6616 0.5000 0.5205
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 95 13965 2.00 1.97
72 Toluene 91 6.515 6.508 0.007 93 16937 0.5000 0.5149
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 92 5600 0.5000 0.4893
74 Ethyl methacrylate 69 6.708 6.701 0.007 48 6858 0.5000 0.6909
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 10 5169 0.5000 0.8158
76 Tetrachloroethene 164 6.958 6.958 0.000 75 1848 0.5000 0.3159
77 1,3-Dichloropropane 76 7.008 7.008 0.000 90 5918 0.5000 0.5233
78 2-Hexanone 43 7.022 7.022 0.000 85 12162 2.00 2.37
79 Chlorodibromomethane 129 7.201 7.201 0.000 1 3727 0.5000 0.4859
80 Ethylene Dibromide 107 7.316 7.323 -0.007 1 4218 0.5000 0.6430
81 1-Chlorohexane 91 7.716 7.709 0.007 29 5583 0.4000 0.0676
82 Chlorobenzene 112 7.752 7.752 0.000 88 11137 0.5000 0.5416
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 41 3235 0.5000 0.4589
84 Ethylbenzene 106 7.830 7.830 0.000 98 6091 0.5000 0.5292
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 6725 0.5000 0.4873
86 o-Xylene 106 8.302 8.302 0.000 91 7422 0.5000 0.5307
87 Styrene 104 8.317 8.324 -0.007 90 12394 0.5000 0.5242
88 Bromoform 173 8.495 8.502 -0.007 13 2509 0.5000 0.4901
89 Isopropylbenzene 105 8.646 8.645 0.001 93 16007 0.5000 0.4613
91 Cyclohexanone 55 8.738 8.746 -0.008 52 7928 15.0 15.7
92 1,1,2,2-Tetrachloroethane 83 8.924 8.931 -0.007 1 5972 0.5000 0.7351
93 Bromobenzene 156 8.967 8.967 0.000 94 3284 0.5000 0.4066
94 trans-1,4-Dichloro-2-butene 53 8.960 8.967 -0.007 48 2894 0.5000 0.5212
95 1,2,3-Trichloropropane 110 9.003 8.996 0.007 57 1020 0.5000 0.4127
96 N-Propylbenzene 120 9.039 9.046 -0.007 99 4752 0.5000 0.4914
97 2-Chlorotoluene 126 9.139 9.146 -0.007 93 4057 0.5000 0.5044
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 93 15319 0.5000 0.5146
99 4-Chlorotoluene 126 9.260 9.260 0.000 96 4600 0.5000 0.5447
100 tert-Butylbenzene 119 9.525 9.525 0.000 90 14550 0.5000 0.5697
Page 387 of 1261
Report Date: 09-Oct-2023 13:08:46 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508905.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 95 16245 0.5000 0.5263
103 sec-Butylbenzene 134 9.747 9.747 0.000 94 3024 0.5000 0.4342
104 1,3-Dichlorobenzene 146 9.883 9.875 0.008 84 6058 0.5000 0.3953
105 4-Isopropyltoluene 119 9.890 9.890 0.000 93 16888 0.5000 0.5312
106 1,4-Dichlorobenzene 146 9.975 9.968 0.007 83 7662 0.5000 0.4795
108 n-Butylbenzene 91 10.297 10.297 0.000 95 14178 0.5000 0.5029
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 93 7288 0.5000 0.4948
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 1 704 0.5000 0.3681
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 87 4335 0.5000 0.4940
113 Hexachlorobutadiene 225 12.070 ND ND
114 Naphthalene 128 12.206 12.199 0.007 95 11740 0.5000 0.5447
115 1,2,3-Trichlorobenzene 180 12.421 12.421 0.000 87 3350 0.5000 0.4737
S 122 1,2-Dichloroethene, Total (URS) 96 0 1.00 1.11
S 127 Trihalomethanes, Total 1 0 2.00 1.22
S 124 1,3-Dichloropropene, Total 1 0 1.00 1.01
S 129 1,2-Dichloroethene, Total 1 0 1.00 1.11
S 126 Total BTEX 1 0 2.57
S 125 Xylenes, Total 106 0 1.00 1.02
S 123 Xylenes, Total (URS) 1 0 1.00 1.02
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
Cal Dil Std_00249 Amount Added: 5.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 388 of 1261
Report Date: 09-Oct-2023 13:08:46 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508905.D
Injection Date:08-Oct-2023 17:38:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:2
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:100
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 389 of 1261
Report Date: 09-Oct-2023 13:08:51 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508906.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:08-Oct-2023 18:03:30 ALS Bottle#:1 Worklist Smp#:3
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:08:50 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
First Level Reviewer: BMJ3 Date:09-Oct-2023 10:16:16
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1404996 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 358244 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 598840 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.692 4.691 0.001 94 357025 50.0 51.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 411553 50.0 50.0
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1515235 50.0 49.6
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 561696 50.0 50.5
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 58 8679 1.00 2.13
10 Chloromethane 50 1.939 1.939 0.000 94 6747 1.00 1.02
11 Vinyl chloride 62 2.039 2.039 0.000 96 6612 1.00 0.8403
12 Bromomethane 94 2.332 2.332 0.000 84 6299 1.00 1.26
13 Chloroethane 64 2.432 2.425 0.007 92 5464 1.00 1.05
14 Dichlorofluoromethane 67 2.596 2.596 0.000 93 16902 1.00 1.22
16 Trichlorofluoromethane 101 2.632 2.632 0.000 97 9470 1.00 0.9667
18 Ethyl ether 59 2.847 2.847 0.000 85 6870 1.00 1.13
19 Acrolein 56 2.961 2.961 0.000 97 9063 9.88 10.4
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.047 3.040 0.007 71 4427 1.00 0.9597
21 1,1-Dichloroethene 96 3.040 3.047 -0.007 95 5622 1.00 0.9512
22 Acetone 43 3.061 3.061 0.000 98 18046 4.00 3.79
24 Iodomethane 142 3.169 3.168 0.000 98 7790 1.00 0.9369
25 Carbon disulfide 76 3.226 3.233 -0.007 95 21073 1.00 1.06
27 Methyl acetate 43 3.290 3.290 0.000 96 14664 2.00 2.60
28 3-Chloro-1-propene 41 3.312 3.311 0.001 86 14788 1.00 1.08
29 Methylene Chloride 84 3.404 3.412 -0.008 90 8620 1.00 1.19
30 2-Methyl-2-propanol 59 3.447 3.454 -0.007 90 6375 10.0 9.46
31 Acrylonitrile 53 3.576 3.576 0.000 98 24457 10.0 9.18
32 Methyl tert-butyl ether 73 3.590 3.597 -0.007 65 16223 1.00 0.8692
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 95 9351 1.00 1.30
34 Hexane 57 3.805 3.805 0.000 88 12779 1.00 1.14
35 Vinyl acetate 43 3.905 3.905 0.000 97 35704 2.00 2.45
36 1,1-Dichloroethane 63 3.934 3.933 0.001 93 13797 1.00 1.06
Page 390 of 1261
Report Date: 09-Oct-2023 13:08:51 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508906.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.320 4.312 0.008 99 16015 4.00 4.90
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 85 9576 1.00 1.22
43 2,2-Dichloropropane 77 4.355 4.355 0.000 64 13113 1.00 1.14
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 95 13976 24.0 24.0
47 Chlorobromomethane 128 4.520 4.520 0.000 95 3649 1.00 1.08
48 Tetrahydrofuran 42 4.534 4.527 0.007 54 4698 2.00 2.15
49 Chloroform 83 4.577 4.577 0.000 96 13096 1.00 1.07
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 91 11250 1.00 1.06
51 Cyclohexane 56 4.784 4.784 0.000 89 13118 1.00 1.01
52 1,1-Dichloropropene 75 4.827 4.834 -0.007 88 8980 1.00 0.9146
53 Carbon tetrachloride 117 4.835 4.842 -0.008 88 10062 1.00 1.05
54 Isobutyl alcohol 41 4.842 4.842 0.000 79 7879 25.0 31.3
55 Benzene 78 4.985 4.992 -0.007 96 28588 1.00 0.9888
56 1,2-Dichloroethane 62 5.013 5.013 0.000 93 9540 1.00 1.02
58 n-Heptane 43 5.170 ND ND
60 Trichloroethene 95 5.471 5.471 0.000 90 7894 1.00 1.03
61 2-Pentanone 43 5.578 5.578 0.000 96 17472 3.20 3.39
62 Methylcyclohexane 55 5.664 5.671 -0.007 87 12341 1.00 1.22
63 1,2-Dichloropropane 63 5.678 5.678 0.000 85 8597 1.00 1.11
65 1,4-Dioxane 88 5.721 5.721 0.000 11 1678 20.0 19.2
66 Dibromomethane 93 5.757 5.750 0.007 90 4372 1.00 1.07
67 Dichlorobromomethane 83 5.878 5.871 0.007 93 11061 1.00 1.12
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 78 4407 1.00 0.9609
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 92 11208 1.00 0.8997
71 4-Methyl-2-pentanone (MIBK) 43 6.329 6.322 0.007 95 29933 4.00 4.38
72 Toluene 91 6.508 6.508 0.000 98 34851 1.00 1.10
73 trans-1,3-Dichloropropene 75 6.679 6.686 -0.007 95 11121 1.00 1.01
74 Ethyl methacrylate 69 6.701 6.701 0.000 88 10890 1.00 1.12
75 1,1,2-Trichloroethane 97 6.865 6.858 0.007 86 6051 1.00 0.9891
76 Tetrachloroethene 164 6.951 6.958 -0.007 95 5188 1.00 0.9049
77 1,3-Dichloropropane 76 7.008 7.008 0.000 83 11199 1.00 1.01
78 2-Hexanone 43 7.022 7.022 0.000 98 20297 4.00 4.04
79 Chlorodibromomethane 129 7.201 7.201 0.000 84 8843 1.00 1.18
80 Ethylene Dibromide 107 7.316 7.323 -0.007 93 6741 1.00 1.05
81 1-Chlorohexane 91 7.709 7.709 0.000 33 13044 0.8000 0.8026
82 Chlorobenzene 112 7.752 7.752 0.000 96 21426 1.00 1.06
83 1,1,1,2-Tetrachloroethane 131 7.816 7.823 -0.007 40 7254 1.00 1.05
84 Ethylbenzene 106 7.830 7.830 0.000 98 12141 1.00 1.08
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 12013 1.00 0.8881
86 o-Xylene 106 8.310 8.302 0.008 90 13718 1.00 1.00
87 Styrene 104 8.317 8.324 -0.007 89 22335 1.00 0.9638
88 Bromoform 173 8.503 8.502 0.001 82 4643 1.00 0.9254
89 Isopropylbenzene 105 8.646 8.645 0.001 96 36202 1.00 1.08
91 Cyclohexanone 55 8.746 8.746 0.000 89 11438 30.0 26.9
92 1,1,2,2-Tetrachloroethane 83 8.924 8.931 -0.007 9 7410 1.00 0.9426 a
93 Bromobenzene 156 8.967 8.967 0.000 92 7528 1.00 0.9633
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 49 3792 1.00 0.8819
95 1,2,3-Trichloropropane 110 8.989 8.996 -0.007 81 2751 1.00 1.15
96 N-Propylbenzene 120 9.046 9.046 0.000 98 10026 1.00 1.07
97 2-Chlorotoluene 126 9.146 9.146 0.000 95 8042 1.00 1.03
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 92 27691 1.00 0.9614
99 4-Chlorotoluene 126 9.261 9.260 0.000 97 8125 1.00 0.99
Page 391 of 1261
Report Date: 09-Oct-2023 13:08:51 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508906.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.525 9.525 0.000 92 25546 1.00 1.03
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 97 29086 1.00 0.9739
103 sec-Butylbenzene 134 9.740 9.747 -0.007 93 7003 1.00 1.04
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 96 15029 1.00 1.01
105 4-Isopropyltoluene 119 9.890 9.890 0.000 96 31930 1.00 1.04
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 93 15343 1.00 0.99
108 n-Butylbenzene 91 10.297 10.297 0.000 97 27900 1.00 1.02
109 1,2-Dichlorobenzene 146 10.326 10.333 -0.007 96 14262 1.00 1.00
110 1,2-Dibromo-3-Chloropropane 157 11.098 11.105 -0.007 1 740 1.00 0.3999
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 89 7757 1.00 0.9135
113 Hexachlorobutadiene 225 12.078 12.070 0.008 88 3853 1.00 0.9359
114 Naphthalene 128 12.199 12.199 0.000 97 22565 1.00 1.08
115 1,2,3-Trichlorobenzene 180 12.428 12.421 0.007 93 7314 1.00 1.07
S 122 1,2-Dichloroethene, Total (URS) 96 0 2.00 2.52
S 127 Trihalomethanes, Total 1 0 4.00 4.30
S 124 1,3-Dichloropropene, Total 1 0 2.00 1.91
S 129 1,2-Dichloroethene, Total 1 0 2.00 2.52
S 126 Total BTEX 1 0 5.05
S 125 Xylenes, Total 106 0 2.00 1.89
S 123 Xylenes, Total (URS) 1 0 2.00 1.89
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
a - User Assigned ID
Reagents:
Cal Dil Std_00249 Amount Added: 10.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 392 of 1261
Report Date: 09-Oct-2023 13:08:51 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508906.D
Injection Date:08-Oct-2023 18:03:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:3
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:1
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 393 of 1261
Report Date: 09-Oct-2023 13:08:51 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508906.D
Injection Date:08-Oct-2023 18:03:30 Instrument ID:VMS_X4
Lims ID:IC
Client ID:
Operator ID:MEIERG ALS Bottle#:1 Worklist Smp#:3
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
92 1,1,2,2-Tetrachloroethane, CAS: 79-34-5
Signal: 1
Processing Integration Results
RT: 9.01
Area: 1529
Amount: 0.624818
Amount Units: ug/l
8.6 8.8 9.0 9.2
Min
8
12
16
20
24
28
32
36
40
44
48
52
56
60
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Y ( X
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m/z 83.0

9
.
0
1
0
Manual Integration Results
RT: 8.92
Area: 7410
Amount: 0.942595
Amount Units: ug/l
8.6 8.8 9.0 9.2
Min
RT
8
13
18
23
28
33
38
43
48
53
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m/z 83.0

8
.
9
2
4
Reviewer: BMJ3, 09-Oct-2023 10:15:54 -06:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Wrong peak
Page 394 of 1261
Report Date: 09-Oct-2023 13:08:55 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508907.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:08-Oct-2023 18:24:30 ALS Bottle#:2 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:08:55 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1400163 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 87 350880 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 598835 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 348246 50.0 50.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 418567 50.0 51.0
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1501993 50.0 50.2
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 553358 50.0 49.7
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 99 8970 2.00 2.17
10 Chloromethane 50 1.931 1.939 -0.008 98 15118 2.00 2.01
11 Vinyl chloride 62 2.039 2.039 0.000 95 13945 2.00 1.78
12 Bromomethane 94 2.339 2.332 0.007 90 9476 2.00 1.90
13 Chloroethane 64 2.425 2.425 0.000 97 9785 2.00 1.88
14 Dichlorofluoromethane 67 2.604 2.596 0.008 95 27578 2.00 2.00
16 Trichlorofluoromethane 101 2.632 2.632 0.000 98 19263 2.00 1.97
18 Ethyl ether 59 2.847 2.847 0.000 92 12751 2.00 2.10
19 Acrolein 56 2.961 2.961 0.000 98 17239 19.8 19.8
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.047 3.040 0.007 70 9189 2.00 2.00
21 1,1-Dichloroethene 96 3.047 3.047 0.000 95 11862 2.00 2.01
22 Acetone 43 3.068 3.061 0.007 100 28136 8.00 8.88
24 Iodomethane 142 3.168 3.168 0.000 97 14972 2.00 1.81
25 Carbon disulfide 76 3.226 3.233 -0.007 99 38487 2.00 1.95
27 Methyl acetate 43 3.290 3.290 0.000 99 19163 4.00 3.50
28 3-Chloro-1-propene 41 3.311 3.311 0.000 92 31056 2.00 2.32
29 Methylene Chloride 84 3.412 3.412 0.000 97 13779 2.00 1.91
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 91 13327 20.0 19.8
31 Acrylonitrile 53 3.576 3.576 0.000 99 54368 20.0 20.5
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 86 35900 2.00 1.93
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 15374 2.00 2.14
34 Hexane 57 3.805 3.805 0.000 90 19134 2.00 1.79
35 Vinyl acetate 43 3.905 3.905 0.000 97 53039 4.00 3.65
36 1,1-Dichloroethane 63 3.934 3.933 0.001 95 25963 2.00 1.99
40 2-Butanone (MEK) 43 4.320 4.312 0.008 98 25205 8.00 7.73
Page 395 of 1261
Report Date: 09-Oct-2023 13:08:55 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508907.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 85 15270 2.00 1.95
43 2,2-Dichloropropane 77 4.348 4.355 -0.007 74 23672 2.00 2.06
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 96 27684 48.0 47.7
47 Chlorobromomethane 128 4.520 4.520 0.000 91 6726 2.00 2.00
48 Tetrahydrofuran 42 4.527 4.527 0.000 52 9345 4.00 4.28
49 Chloroform 83 4.577 4.577 0.000 95 24788 2.00 2.04
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 96 21154 2.00 1.99
51 Cyclohexane 56 4.784 4.784 0.000 91 27923 2.00 2.15
52 1,1-Dichloropropene 75 4.834 4.834 0.000 90 18136 2.00 1.85
53 Carbon tetrachloride 117 4.842 4.842 0.000 93 19009 2.00 1.98
54 Isobutyl alcohol 41 4.849 4.842 0.007 94 13672 50.0 54.5
55 Benzene 78 4.985 4.992 -0.007 94 57794 2.00 2.01
56 1,2-Dichloroethane 62 5.013 5.013 0.000 95 18837 2.00 2.02
58 n-Heptane 43 5.170 5.170 0.000 93 24719 2.00 2.11
60 Trichloroethene 95 5.471 5.471 0.000 97 15181 2.00 2.03
61 2-Pentanone 43 5.578 5.578 0.000 99 34021 6.40 6.63
62 Methylcyclohexane 55 5.671 5.671 0.000 88 19503 2.00 1.94
63 1,2-Dichloropropane 63 5.678 5.678 0.000 81 15524 2.00 2.01
65 1,4-Dioxane 88 5.721 5.721 0.000 75 3069 40.0 35.3
66 Dibromomethane 93 5.750 5.750 0.000 96 8326 2.00 2.04
67 Dichlorobromomethane 83 5.871 5.871 0.000 96 21395 2.00 2.18
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 93 8301 2.00 1.82
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 90 23436 2.00 1.92
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 53645 8.00 7.88
72 Toluene 91 6.515 6.508 0.007 96 63863 2.00 2.02
73 trans-1,3-Dichloropropene 75 6.679 6.686 -0.007 93 21294 2.00 1.93
74 Ethyl methacrylate 69 6.701 6.701 0.000 89 19926 2.00 2.09
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 88 14372 2.00 2.36
76 Tetrachloroethene 164 6.958 6.958 0.000 92 10378 2.00 1.85
77 1,3-Dichloropropane 76 7.008 7.008 0.000 94 19395 2.00 1.79
78 2-Hexanone 43 7.022 7.022 0.000 97 37589 8.00 7.63
79 Chlorodibromomethane 129 7.194 7.201 -0.007 89 15066 2.00 2.05
80 Ethylene Dibromide 107 7.323 7.323 0.000 96 13055 2.00 2.07
81 1-Chlorohexane 91 7.709 7.709 0.000 67 20934 1.60 1.61
82 Chlorobenzene 112 7.752 7.752 0.000 93 39909 2.00 2.02
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 41 12816 2.00 1.89
84 Ethylbenzene 106 7.830 7.830 0.000 99 21806 2.00 1.97
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 27048 2.00 2.04
86 o-Xylene 106 8.302 8.302 0.000 96 26585 2.00 1.98
87 Styrene 104 8.317 8.324 -0.007 94 47175 2.00 2.08
88 Bromoform 173 8.503 8.502 0.000 91 9369 2.00 1.91
89 Isopropylbenzene 105 8.646 8.645 0.001 96 67960 2.00 2.02
91 Cyclohexanone 55 8.746 8.746 0.000 95 18342 60.0 49.2
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 92 14985 2.00 1.91
93 Bromobenzene 156 8.967 8.967 0.000 93 15507 2.00 1.98
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 53 7194 2.00 2.12
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 80 4406 2.00 1.84
96 N-Propylbenzene 120 9.046 9.046 0.000 99 17901 2.00 1.91
97 2-Chlorotoluene 126 9.139 9.146 -0.007 96 16347 2.00 2.10
98 1,3,5-Trimethylbenzene 105 9.210 9.218 -0.008 94 59267 2.00 2.06
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 15359 2.00 1.88
100 tert-Butylbenzene 119 9.525 9.525 0.000 93 49636 2.00 2.01
Page 396 of 1261
Report Date: 09-Oct-2023 13:08:55 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508907.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 97 61042 2.00 2.04
103 sec-Butylbenzene 134 9.754 9.747 0.007 94 12487 2.00 1.85
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 95 29325 2.00 1.98
105 4-Isopropyltoluene 119 9.890 9.890 0.000 96 60064 2.00 1.95
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 91 30657 2.00 1.98
108 n-Butylbenzene 91 10.290 10.297 -0.007 98 57090 2.00 2.09
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 96 27391 2.00 1.92
110 1,2-Dibromo-3-Chloropropane 157 11.112 11.105 0.007 75 2927 2.00 1.58
112 1,2,4-Trichlorobenzene 180 11.927 11.927 0.000 92 16347 2.00 1.93
113 Hexachlorobutadiene 225 12.070 12.070 0.000 91 8946 2.00 2.17
114 Naphthalene 128 12.199 12.199 0.000 98 38782 2.00 1.86
115 1,2,3-Trichlorobenzene 180 12.428 12.421 0.007 90 14131 2.00 2.07
S 122 1,2-Dichloroethene, Total (URS) 96 0 4.00 4.10
S 127 Trihalomethanes, Total 1 0 8.00 8.17
S 124 1,3-Dichloropropene, Total 1 0 4.00 3.85
S 129 1,2-Dichloroethene, Total 1 0 4.00 4.10
S 126 Total BTEX 1 0 10.0
S 125 Xylenes, Total 106 0 4.00 4.02
S 123 Xylenes, Total (URS) 1 0 4.00 4.02
Reagents:
Cal Dil Std_00249 Amount Added: 20.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 397 of 1261
Report Date: 09-Oct-2023 13:08:55 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508907.D
Injection Date:08-Oct-2023 18:24:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:4
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:2
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 398 of 1261
Report Date: 09-Oct-2023 13:09:01 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508908.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:08-Oct-2023 18:44:30 ALS Bottle#:3 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:09:00 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1443067 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 365421 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 95 623773 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 364068 50.0 50.9
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 439167 50.0 52.0
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1529125 50.0 49.1
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 575779 50.0 49.7
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 99 22048 5.00 3.87
10 Chloromethane 50 1.939 1.939 0.000 99 33863 5.00 4.08
11 Vinyl chloride 62 2.039 2.039 0.000 97 33161 5.00 4.10
12 Bromomethane 94 2.332 2.332 0.000 90 23848 5.00 4.63
13 Chloroethane 64 2.425 2.425 0.000 98 23490 5.00 4.38
14 Dichlorofluoromethane 67 2.596 2.596 0.000 96 62042 5.00 4.38
16 Trichlorofluoromethane 101 2.632 2.632 0.000 98 41716 5.00 4.15
18 Ethyl ether 59 2.847 2.847 0.000 93 28452 5.00 4.54
19 Acrolein 56 2.961 2.961 0.000 98 40933 49.4 45.5
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 68 22997 5.00 4.85
21 1,1-Dichloroethene 96 3.047 3.047 0.000 97 30846 5.00 5.08
22 Acetone 43 3.061 3.061 0.000 98 49889 20.0 19.1
24 Iodomethane 142 3.168 3.168 0.000 99 34156 5.00 4.00
25 Carbon disulfide 76 3.226 3.233 -0.007 99 90139 5.00 4.42
27 Methyl acetate 43 3.290 3.290 0.000 98 45429 10.0 8.44
28 3-Chloro-1-propene 41 3.311 3.311 0.000 90 63813 5.00 4.69
29 Methylene Chloride 84 3.412 3.412 0.000 97 36611 5.00 4.92
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 99 32270 50.0 46.6
31 Acrylonitrile 53 3.576 3.576 0.000 98 131928 50.0 48.2
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 96 85899 5.00 4.48
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 32448 5.00 4.39
34 Hexane 57 3.798 3.805 -0.007 94 42061 5.00 3.88
35 Vinyl acetate 43 3.905 3.905 0.000 97 126969 10.0 8.47
36 1,1-Dichloroethane 63 3.934 3.933 0.001 96 62462 5.00 4.65
40 2-Butanone (MEK) 43 4.320 4.312 0.008 99 57977 20.0 17.3
Page 399 of 1261
Report Date: 09-Oct-2023 13:09:01 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508908.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 85 39539 5.00 4.91
43 2,2-Dichloropropane 77 4.348 4.355 -0.007 89 54009 5.00 4.56
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 98 65708 120.0 109.9
47 Chlorobromomethane 128 4.520 4.520 0.000 95 16152 5.00 4.67
48 Tetrahydrofuran 42 4.534 4.527 0.007 87 21107 10.0 9.38
49 Chloroform 83 4.577 4.577 0.000 95 57788 5.00 4.60
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 95 46910 5.00 4.29
51 Cyclohexane 56 4.784 4.784 0.000 91 62539 5.00 4.68
52 1,1-Dichloropropene 75 4.834 4.834 0.000 90 47155 5.00 4.68
53 Carbon tetrachloride 117 4.842 4.842 0.000 93 45307 5.00 4.59
54 Isobutyl alcohol 41 4.842 4.842 0.000 84 27803 125.0 107.6
55 Benzene 78 4.985 4.992 -0.007 96 138461 5.00 4.66
56 1,2-Dichloroethane 62 5.013 5.013 0.000 96 44281 5.00 4.60
58 n-Heptane 43 5.171 5.170 0.001 95 44253 5.00 4.27
60 Trichloroethene 95 5.471 5.471 0.000 98 36040 5.00 4.63
61 2-Pentanone 43 5.578 5.578 0.000 98 80204 16.0 15.2
62 Methylcyclohexane 55 5.664 5.671 -0.007 93 45745 5.00 4.42
63 1,2-Dichloropropane 63 5.678 5.678 0.000 93 35662 5.00 4.47
65 1,4-Dioxane 88 5.721 5.721 0.000 85 9404 100.0 104.9
66 Dibromomethane 93 5.750 5.750 0.000 95 20175 5.00 4.79
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 46296 5.00 4.58
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 90 21137 5.00 4.49
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 93 59958 5.00 4.72
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 140134 20.0 20.0
72 Toluene 91 6.515 6.508 0.007 96 152771 5.00 4.68
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 95 53223 5.00 4.69
74 Ethyl methacrylate 69 6.701 6.701 0.000 89 45193 5.00 4.55
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 93 29332 5.00 4.67
76 Tetrachloroethene 164 6.951 6.958 -0.007 95 27376 5.00 4.68
77 1,3-Dichloropropane 76 7.008 7.008 0.000 94 51814 5.00 4.58
78 2-Hexanone 43 7.022 7.022 0.000 98 95146 20.0 18.6
79 Chlorodibromomethane 129 7.201 7.201 0.000 93 33786 5.00 4.41
80 Ethylene Dibromide 107 7.316 7.323 -0.007 94 29539 5.00 4.50
81 1-Chlorohexane 91 7.702 7.709 -0.007 95 44628 4.00 3.78
82 Chlorobenzene 112 7.752 7.752 0.000 93 91349 5.00 4.44
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 93 32670 5.00 4.64
84 Ethylbenzene 106 7.823 7.830 -0.007 99 50836 5.00 4.42
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 64259 5.00 4.66
86 o-Xylene 106 8.310 8.302 0.008 97 64167 5.00 4.59
87 Styrene 104 8.317 8.324 -0.007 95 108832 5.00 4.60
88 Bromoform 173 8.503 8.502 0.001 95 23780 5.00 4.65
89 Isopropylbenzene 105 8.646 8.645 0.001 96 158638 5.00 4.54
91 Cyclohexanone 55 8.746 8.746 0.000 93 53419 150.0 152.1
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 92 38653 5.00 4.72
93 Bromobenzene 156 8.967 8.967 0.000 97 38784 5.00 4.76
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 50 15049 5.00 4.76
95 1,2,3-Trichloropropane 110 8.989 8.996 -0.007 84 11111 5.00 4.46
96 N-Propylbenzene 120 9.046 9.046 0.000 99 45196 5.00 4.64
97 2-Chlorotoluene 126 9.146 9.146 0.000 95 35486 5.00 4.38
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 94 137014 5.00 4.57
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 38956 5.00 4.58
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 115520 5.00 4.49
Page 400 of 1261
Report Date: 09-Oct-2023 13:09:01 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508908.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 97 140020 5.00 4.50
103 sec-Butylbenzene 134 9.747 9.747 0.000 94 31890 5.00 4.54
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 99 72507 5.00 4.69
105 4-Isopropyltoluene 119 9.890 9.890 0.000 98 146002 5.00 4.56
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 94 73400 5.00 4.56
108 n-Butylbenzene 91 10.290 10.297 -0.007 98 127109 5.00 4.47
109 1,2-Dichlorobenzene 146 10.326 10.333 -0.007 94 65964 5.00 4.44
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 85 9254 5.00 4.80
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 93 40864 5.00 4.62
113 Hexachlorobutadiene 225 12.071 12.070 0.001 93 19909 5.00 4.64
114 Naphthalene 128 12.199 12.199 0.000 97 101863 5.00 4.69
115 1,2,3-Trichlorobenzene 180 12.428 12.421 0.007 94 32915 5.00 4.62
S 122 1,2-Dichloroethene, Total (URS) 96 0 10.0 9.30
S 127 Trihalomethanes, Total 1 0 20.0 18.2
S 124 1,3-Dichloropropene, Total 1 0 10.0 9.41
S 129 1,2-Dichloroethene, Total 1 0 10.0 9.30
S 126 Total BTEX 1 0 23.0
S 125 Xylenes, Total 106 0 10.0 9.25
S 123 Xylenes, Total (URS) 1 0 10.0 9.25
Reagents:
Cal Dil Std_00249 Amount Added: 50.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 401 of 1261
Report Date: 09-Oct-2023 13:09:01 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508908.D
Injection Date:08-Oct-2023 18:44:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:5
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 402 of 1261
Report Date: 09-Oct-2023 13:09:06 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508909.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:5
Inject. Date:08-Oct-2023 19:04:30 ALS Bottle#:4 Worklist Smp#:6
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:09:06 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1419389 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 352564 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 595926 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 355257 50.0 50.5
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 410433 50.0 49.4
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1508711 50.0 50.2
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 87 555433 50.0 50.1
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 74469 10.0 11.0
10 Chloromethane 50 1.939 1.939 0.000 99 94870 10.0 11.2
11 Vinyl chloride 62 2.039 2.039 0.000 98 92301 10.0 11.6
12 Bromomethane 94 2.339 2.339 0.000 92 53918 10.0 10.6
13 Chloroethane 64 2.432 2.432 0.000 99 63560 10.0 12.0
14 Dichlorofluoromethane 67 2.604 2.604 0.000 97 143927 10.0 10.3
16 Trichlorofluoromethane 101 2.639 2.639 0.000 98 108401 10.0 11.0
18 Ethyl ether 59 2.847 2.847 0.000 93 61392 10.0 9.97
19 Acrolein 56 2.961 2.961 0.000 99 89378 98.8 101.1
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 94 51056 10.0 11.0
21 1,1-Dichloroethene 96 3.047 3.047 0.000 98 67830 10.0 11.4
22 Acetone 43 3.061 3.061 0.000 99 98457 40.0 43.5
24 Iodomethane 142 3.168 3.168 0.000 99 91269 10.0 10.9
25 Carbon disulfide 76 3.233 3.233 0.000 100 223452 10.0 11.1
27 Methyl acetate 43 3.290 3.290 0.000 99 108898 20.0 21.0
28 3-Chloro-1-propene 41 3.319 3.319 0.000 92 144245 10.0 11.0
29 Methylene Chloride 84 3.412 3.412 0.000 96 74757 10.0 10.2
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 100 73003 100.0 107.2
31 Acrylonitrile 53 3.576 3.576 0.000 99 292624 100.0 108.7
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 99 205547 10.0 10.9
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 75568 10.0 10.4
34 Hexane 57 3.805 3.805 0.000 95 100743 10.0 9.75
35 Vinyl acetate 43 3.905 3.905 0.000 97 314246 20.0 21.3
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 147981 10.0 11.2
40 2-Butanone (MEK) 43 4.320 4.320 0.000 99 133268 40.0 40.3
Page 403 of 1261
Report Date: 09-Oct-2023 13:09:06 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508909.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 82299 10.0 10.4
43 2,2-Dichloropropane 77 4.355 4.355 0.000 88 129274 10.0 11.1
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 156067 240.0 265.3
47 Chlorobromomethane 128 4.520 4.520 0.000 97 38626 10.0 11.3
48 Tetrahydrofuran 42 4.534 4.534 0.000 91 47742 20.0 21.6
49 Chloroform 83 4.577 4.577 0.000 95 136084 10.0 11.0
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 98 112889 10.0 10.5
51 Cyclohexane 56 4.777 4.777 0.000 94 143909 10.0 10.9
52 1,1-Dichloropropene 75 4.834 4.834 0.000 93 106780 10.0 10.8
53 Carbon tetrachloride 117 4.842 4.842 0.000 94 99795 10.0 10.3
54 Isobutyl alcohol 41 4.842 4.842 0.000 93 64738 250.0 254.7
55 Benzene 78 4.985 4.985 0.000 97 325958 10.0 11.2
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 98031 10.0 10.3
58 n-Heptane 43 5.171 5.171 0.000 95 93392 10.0 10.1
60 Trichloroethene 95 5.478 5.478 0.000 98 82241 10.0 10.9
61 2-Pentanone 43 5.578 5.578 0.000 98 172787 32.0 33.2
62 Methylcyclohexane 55 5.671 5.671 0.000 93 101202 10.0 9.94
63 1,2-Dichloropropane 63 5.685 5.685 0.000 95 84150 10.0 10.7
65 1,4-Dioxane 88 5.728 5.728 0.000 91 19423 200.0 220.3
66 Dibromomethane 93 5.750 5.750 0.000 97 43907 10.0 10.6
67 Dichlorobromomethane 83 5.871 5.871 0.000 98 102843 10.0 10.4
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 90 47787 10.0 10.3
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 127798 10.0 10.4
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 98 293844 40.0 42.6
72 Toluene 91 6.515 6.515 0.000 97 350189 10.0 10.9
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 96 117863 10.0 10.6
74 Ethyl methacrylate 69 6.701 6.701 0.000 90 101676 10.0 10.6
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 91 64600 10.0 10.5
76 Tetrachloroethene 164 6.958 6.958 0.000 98 61027 10.0 10.8
77 1,3-Dichloropropane 76 7.008 7.008 0.000 97 116301 10.0 10.7
78 2-Hexanone 43 7.022 7.022 0.000 96 213731 40.0 43.2
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 77299 10.0 10.4
80 Ethylene Dibromide 107 7.323 7.323 0.000 98 68270 10.0 10.8
81 1-Chlorohexane 91 7.709 7.709 0.000 98 89196 8.00 8.33
82 Chlorobenzene 112 7.752 7.752 0.000 94 212195 10.0 10.7
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 96 73365 10.0 10.8
84 Ethylbenzene 106 7.830 7.830 0.000 99 119027 10.0 10.7
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 145062 10.0 10.9
86 o-Xylene 106 8.302 8.302 0.000 97 144463 10.0 10.7
87 Styrene 104 8.317 8.317 0.000 94 245901 10.0 10.8
88 Bromoform 173 8.503 8.503 0.000 96 55610 10.0 11.3
89 Isopropylbenzene 105 8.646 8.646 0.000 96 368994 10.0 11.0
91 Cyclohexanone 55 8.746 8.746 0.000 94 115097 300.0 349.6
92 1,1,2,2-Tetrachloroethane 83 8.932 8.932 0.000 94 89157 10.0 11.4
93 Bromobenzene 156 8.967 8.967 0.000 96 87001 10.0 11.2
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 59 32582 10.0 11.4
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 27054 10.0 11.4
96 N-Propylbenzene 120 9.046 9.046 0.000 99 102553 10.0 11.0
97 2-Chlorotoluene 126 9.139 9.139 0.000 95 82964 10.0 10.7
98 1,3,5-Trimethylbenzene 105 9.210 9.210 0.000 93 316997 10.0 11.1
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 89175 10.0 11.0
100 tert-Butylbenzene 119 9.525 9.525 0.000 93 256893 10.0 10.4
Page 404 of 1261
Report Date: 09-Oct-2023 13:09:06 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508909.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 324741 10.0 10.9
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 74876 10.0 11.2
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 164309 10.0 11.1
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 330604 10.0 10.8
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 96 170972 10.0 11.1
108 n-Butylbenzene 91 10.297 10.297 0.000 97 291802 10.0 10.7
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 98 158147 10.0 11.2
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 86 21923 10.0 11.9
112 1,2,4-Trichlorobenzene 180 11.927 11.927 0.000 93 94588 10.0 11.2
113 Hexachlorobutadiene 225 12.070 12.070 0.000 96 43983 10.0 10.7
114 Naphthalene 128 12.199 12.199 0.000 97 225625 10.0 10.9
115 1,2,3-Trichlorobenzene 180 12.428 12.428 0.000 94 71263 10.0 10.5
S 122 1,2-Dichloroethene, Total (URS) 96 0 20.0 20.8
S 127 Trihalomethanes, Total 1 0 40.0 43.1
S 124 1,3-Dichloropropene, Total 1 0 20.0 21.0
S 129 1,2-Dichloroethene, Total 1 0 20.0 20.8
S 126 Total BTEX 1 0 54.4
S 125 Xylenes, Total 106 0 20.0 21.6
S 123 Xylenes, Total (URS) 1 0 20.0 21.6
Reagents:
MV-MegaMainA_00096 Amount Added: 5.00 Units: uL
MV-Gas A_00168 Amount Added: 2.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 405 of 1261
Report Date: 09-Oct-2023 13:09:06 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508909.D
Injection Date:08-Oct-2023 19:04:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:6
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:4
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 406 of 1261
Report Date: 09-Oct-2023 13:09:12 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508910.D
Lims ID:ICIS
Client ID:
Sample Type:ICIS Calib Level:6
Inject. Date:08-Oct-2023 19:25:30 ALS Bottle#:5 Worklist Smp#:7
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ICIS
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:09:12 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
First Level Reviewer: BMJ3 Date:09-Oct-2023 09:52:29
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 99 1502020 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 360515 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 627238 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 369268 50.0 49.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 430064 50.0 48.9
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1571566 50.0 51.1
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 580978 50.0 49.8
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 398079 50.0 51.8
10 Chloromethane 50 1.939 1.939 0.000 99 463435 50.0 50.8
11 Vinyl chloride 62 2.039 2.039 0.000 99 456172 50.0 54.2
12 Bromomethane 94 2.332 2.332 0.000 92 250463 50.0 46.7
13 Chloroethane 64 2.425 2.425 0.000 100 274029 50.0 49.0
14 Dichlorofluoromethane 67 2.596 2.596 0.000 98 735625 50.0 49.8
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 545491 50.0 52.1
18 Ethyl ether 59 2.847 2.847 0.000 94 304348 50.0 46.7
19 Acrolein 56 2.961 2.961 0.000 100 441942 493.8 472.2
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 96 254666 50.0 51.6
21 1,1-Dichloroethene 96 3.047 3.047 0.000 98 302490 50.0 47.9
22 Acetone 43 3.061 3.061 0.000 99 436015 200.0 198.9
24 Iodomethane 142 3.168 3.168 0.000 99 477505 50.0 53.7
25 Carbon disulfide 76 3.233 3.233 0.000 99 1042787 50.0 49.1
27 Methyl acetate 43 3.290 3.290 0.000 99 539505 100.0 99.4
28 3-Chloro-1-propene 41 3.311 3.311 0.000 91 618018 50.0 48.1
29 Methylene Chloride 84 3.412 3.412 0.000 96 364031 50.0 47.0
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 99 365034 500.0 506.5
31 Acrylonitrile 53 3.576 3.576 0.000 99 1406464 500.0 493.6
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 96 1025272 50.0 51.4
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 347741 50.0 45.2
34 Hexane 57 3.805 3.805 0.000 94 522985 50.0 49.8
35 Vinyl acetate 43 3.905 3.905 0.000 97 1483261 100.0 95.0
36 1,1-Dichloroethane 63 3.933 3.933 0.000 97 692971 50.0 49.6
Page 407 of 1261
Report Date: 09-Oct-2023 13:09:12 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508910.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.312 4.312 0.000 100 678002 200.0 193.9
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 393792 50.0 47.0
43 2,2-Dichloropropane 77 4.355 4.355 0.000 88 584240 50.0 47.4
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 759145 1200.0 1219.6
47 Chlorobromomethane 128 4.520 4.520 0.000 97 175142 50.0 48.6
48 Tetrahydrofuran 42 4.527 4.527 0.000 90 225170 100.0 96.2
49 Chloroform 83 4.577 4.577 0.000 95 631528 50.0 48.3
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 557595 50.0 49.0
51 Cyclohexane 56 4.784 4.784 0.000 92 694448 50.0 49.9
52 1,1-Dichloropropene 75 4.834 4.834 0.000 96 528404 50.0 50.3
53 Carbon tetrachloride 117 4.842 4.842 0.000 96 483218 50.0 47.0
54 Isobutyl alcohol 41 4.842 4.842 0.000 94 299463 1250.0 1113.3
55 Benzene 78 4.992 4.992 0.000 97 1516881 50.0 49.1
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 493315 50.0 49.2
58 n-Heptane 43 5.170 5.170 0.000 95 456301 50.0 49.5
60 Trichloroethene 95 5.471 5.471 0.000 98 377900 50.0 49.2
61 2-Pentanone 43 5.578 5.578 0.000 99 865305 160.0 157.3
62 Methylcyclohexane 55 5.671 5.671 0.000 92 512571 50.0 47.6
63 1,2-Dichloropropane 63 5.678 5.678 0.000 95 408366 50.0 49.2
65 1,4-Dioxane 88 5.721 5.721 0.000 95 92379 1000.0 989.9
66 Dibromomethane 93 5.750 5.750 0.000 97 210958 50.0 48.1
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 494092 50.0 47.0
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 92 260306 50.0 53.1
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 644431 50.0 51.4
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 98 1441546 200.0 197.3
72 Toluene 91 6.508 6.508 0.000 98 1618912 50.0 47.7
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 97 592518 50.0 50.2
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 484602 50.0 49.5
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 92 314201 50.0 48.0
76 Tetrachloroethene 164 6.958 6.958 0.000 99 290651 50.0 50.4
77 1,3-Dichloropropane 76 7.008 7.008 0.000 98 570375 50.0 51.1
78 2-Hexanone 43 7.022 7.022 0.000 97 1008581 200.0 199.3
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 369819 50.0 48.9
80 Ethylene Dibromide 107 7.323 7.323 0.000 99 320814 50.0 49.6
81 1-Chlorohexane 91 7.709 7.709 0.000 97 415301 40.0 39.6
82 Chlorobenzene 112 7.752 7.752 0.000 93 988868 50.0 48.8
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 97 352209 50.0 50.7
84 Ethylbenzene 106 7.830 7.830 0.000 99 552194 50.0 48.6
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 692516 50.0 50.9
86 o-Xylene 106 8.302 8.302 0.000 97 692062 50.0 50.2
87 Styrene 104 8.324 8.324 0.000 95 1160660 50.0 49.8
88 Bromoform 173 8.502 8.502 0.000 96 261485 50.0 51.8
89 Isopropylbenzene 105 8.645 8.645 0.000 96 1732100 50.0 49.2
91 Cyclohexanone 55 8.746 8.746 0.000 94 525064 1500.0 1587.6
92 1,1,2,2-Tetrachloroethane 83 8.931 8.931 0.000 95 417787 50.0 50.7
93 Bromobenzene 156 8.967 8.967 0.000 97 414068 50.0 50.6
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 61 143467 50.0 49.3
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 86 123017 50.0 49.1
96 N-Propylbenzene 120 9.046 9.046 0.000 99 477375 50.0 48.7
97 2-Chlorotoluene 126 9.146 9.146 0.000 96 393028 50.0 48.2
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 94 1483899 50.0 49.2
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 414729 50.0 48.5
Page 408 of 1261
Report Date: 09-Oct-2023 13:09:12 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508910.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1230403 50.0 47.5
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 1526928 50.0 48.8
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 356000 50.0 50.4
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 781813 50.0 50.3
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 1556031 50.0 48.3
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 96 804154 50.0 49.7
108 n-Butylbenzene 91 10.297 10.297 0.000 98 1388744 50.0 48.6
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 98 741617 50.0 49.7
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 85 94359 50.0 48.7
112 1,2,4-Trichlorobenzene 180 11.927 11.927 0.000 94 439187 50.0 49.4
113 Hexachlorobutadiene 225 12.070 12.070 0.000 97 203543 50.0 47.2
114 Naphthalene 128 12.199 12.199 0.000 98 1051863 50.0 48.2
115 1,2,3-Trichlorobenzene 180 12.421 12.421 0.000 95 349903 50.0 48.8
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 92.1
S 127 Trihalomethanes, Total 1 0 200.0 196.0
S 124 1,3-Dichloropropene, Total 1 0 100.0 101.6
S 129 1,2-Dichloroethene, Total 1 0 100.0 92.1
S 125 Xylenes, Total 106 0 100.0 101.0
S 123 Xylenes, Total (URS) 1 0 100.0 101.0
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMainA_00096 Amount Added: 25.00 Units: uL
MV-Gas A_00168 Amount Added: 10.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 409 of 1261
Report Date: 09-Oct-2023 13:09:12 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508910.D
Injection Date:08-Oct-2023 19:25:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:ICIS Worklist Smp#:7
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 410 of 1261
Report Date: 09-Oct-2023 13:09:18 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508911.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:7
Inject. Date:08-Oct-2023 19:45:30 ALS Bottle#:6 Worklist Smp#:8
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:09:17 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1539686 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 375979 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 639895 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 95 376197 50.0 49.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 440539 50.0 48.8
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1600396 50.0 49.9
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 597540 50.0 50.2
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 608229 75.0 76.7
10 Chloromethane 50 1.939 1.939 0.000 99 718140 75.0 76.7
11 Vinyl chloride 62 2.039 2.039 0.000 99 700548 75.0 81.2
12 Bromomethane 94 2.332 2.332 0.000 91 389782 75.0 70.9
13 Chloroethane 64 2.425 2.425 0.000 100 435347 75.0 76.0
14 Dichlorofluoromethane 67 2.604 2.596 0.008 98 1091645 75.0 72.2
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 843141 75.0 78.5
18 Ethyl ether 59 2.847 2.847 0.000 94 465957 75.0 69.7
19 Acrolein 56 2.961 2.961 0.000 99 670407 740.6 698.8
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 95 400131 75.0 79.2
21 1,1-Dichloroethene 96 3.047 3.047 0.000 97 466881 75.0 72.1
22 Acetone 43 3.061 3.061 0.000 100 618145 300.0 277.1
24 Iodomethane 142 3.168 3.168 0.000 98 752530 75.0 82.6
25 Carbon disulfide 76 3.233 3.233 0.000 99 1620608 75.0 74.5
27 Methyl acetate 43 3.290 3.290 0.000 99 814698 150.0 146.5
28 3-Chloro-1-propene 41 3.311 3.311 0.000 91 895173 75.0 71.8
29 Methylene Chloride 84 3.412 3.412 0.000 96 561742 75.0 70.7
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 100 529565 750.0 716.9
31 Acrylonitrile 53 3.576 3.576 0.000 98 2114764 750.0 724.0
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 96 1577468 75.0 77.1
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 541929 75.0 68.7
34 Hexane 57 3.805 3.805 0.000 94 821966 75.0 75.1
35 Vinyl acetate 43 3.905 3.905 0.000 97 2318930 150.0 144.9
36 1,1-Dichloroethane 63 3.934 3.933 0.001 97 1070605 75.0 74.7
40 2-Butanone (MEK) 43 4.312 4.312 0.000 100 1009078 300.0 281.6
Page 411 of 1261
Report Date: 09-Oct-2023 13:09:18 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508911.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 614390 75.0 71.5
43 2,2-Dichloropropane 77 4.355 4.355 0.000 88 903616 75.0 71.6
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 1087196 1800.0 1703.8
47 Chlorobromomethane 128 4.520 4.520 0.000 97 265679 75.0 71.9
48 Tetrahydrofuran 42 4.527 4.527 0.000 90 339612 150.0 141.5
49 Chloroform 83 4.577 4.577 0.000 96 982830 75.0 73.4
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 868188 75.0 74.4
51 Cyclohexane 56 4.784 4.784 0.000 93 1080284 75.0 75.7
52 1,1-Dichloropropene 75 4.834 4.834 0.000 97 833508 75.0 77.5
53 Carbon tetrachloride 117 4.842 4.842 0.000 95 759914 75.0 72.1
54 Isobutyl alcohol 41 4.842 4.842 0.000 95 472180 1875.0 1712.5
55 Benzene 78 4.992 4.992 0.000 97 2374523 75.0 74.9
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 768282 75.0 74.8
58 n-Heptane 43 5.171 5.170 0.001 95 714896 75.0 76.1
60 Trichloroethene 95 5.471 5.471 0.000 99 590373 75.0 73.7
61 2-Pentanone 43 5.578 5.578 0.000 99 1285337 240.0 227.9
62 Methylcyclohexane 55 5.671 5.671 0.000 93 809132 75.0 73.3
63 1,2-Dichloropropane 63 5.678 5.678 0.000 96 642074 75.0 75.4
65 1,4-Dioxane 88 5.721 5.721 0.000 95 142479 1500.0 1489.4
66 Dibromomethane 93 5.750 5.750 0.000 97 326802 75.0 72.7
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 773302 75.0 71.7
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 92 388338 75.0 77.3
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 1000528 75.0 76.5
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 2138435 300.0 285.5
72 Toluene 91 6.515 6.508 0.007 97 2539888 75.0 73.0
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 97 920830 75.0 76.0
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 723347 75.0 70.8
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 92 482502 75.0 72.0
76 Tetrachloroethene 164 6.958 6.958 0.000 99 473804 75.0 78.7
77 1,3-Dichloropropane 76 7.008 7.008 0.000 98 873884 75.0 75.1
78 2-Hexanone 43 7.022 7.022 0.000 98 1487533 300.0 281.9
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 570984 75.0 72.4
80 Ethylene Dibromide 107 7.323 7.323 0.000 99 489465 75.0 72.5
81 1-Chlorohexane 91 7.709 7.709 0.000 98 655743 60.0 60.2
82 Chlorobenzene 112 7.752 7.752 0.000 92 1550437 75.0 73.3
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 97 554372 75.0 76.4
84 Ethylbenzene 106 7.830 7.830 0.000 99 870429 75.0 73.5
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 1099694 75.0 77.5
86 o-Xylene 106 8.302 8.302 0.000 97 1061567 75.0 73.8
87 Styrene 104 8.317 8.324 -0.007 95 1818307 75.0 74.8
88 Bromoform 173 8.503 8.502 0.001 97 398145 75.0 75.6
89 Isopropylbenzene 105 8.646 8.645 0.001 96 2712108 75.0 75.6
91 Cyclohexanone 55 8.746 8.746 0.000 94 757616 2250.0 2199.6
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 95 622800 75.0 74.1
93 Bromobenzene 156 8.967 8.967 0.000 97 659027 75.0 78.9
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 65 211545 75.0 71.5
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 186150 75.0 72.9
96 N-Propylbenzene 120 9.046 9.046 0.000 99 744378 75.0 74.4
97 2-Chlorotoluene 126 9.139 9.146 -0.007 96 620568 75.0 74.6
98 1,3,5-Trimethylbenzene 105 9.210 9.218 -0.008 95 2306259 75.0 74.9
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 654910 75.0 75.0
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1950076 75.0 73.8
Page 412 of 1261
Report Date: 09-Oct-2023 13:09:18 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508911.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 2408360 75.0 75.5
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 562585 75.0 78.1
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 1255280 75.0 79.2
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 2457795 75.0 74.8
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 94 1264745 75.0 76.5
108 n-Butylbenzene 91 10.297 10.297 0.000 98 2192336 75.0 75.2
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 1158131 75.0 76.1
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 85 139253 75.0 70.4
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 94 704738 75.0 77.7
113 Hexachlorobutadiene 225 12.071 12.070 0.000 96 330387 75.0 75.1
114 Naphthalene 128 12.199 12.199 0.000 98 1608855 75.0 72.2
115 1,2,3-Trichlorobenzene 180 12.421 12.421 0.000 96 542899 75.0 74.3
S 122 1,2-Dichloroethene, Total (URS) 96 0 150.0 140.2
S 127 Trihalomethanes, Total 1 0 300.0 293.1
S 124 1,3-Dichloropropene, Total 1 0 150.0 152.6
S 129 1,2-Dichloroethene, Total 1 0 150.0 140.2
S 126 Total BTEX 1 0 372.7
S 125 Xylenes, Total 106 0 150.0 151.3
S 123 Xylenes, Total (URS) 1 0 150.0 151.3
Reagents:
MV-MegaMainA_00096 Amount Added: 37.50 Units: uL
MV-Gas A_00168 Amount Added: 15.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 413 of 1261
Report Date: 09-Oct-2023 13:09:18 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508911.D
Injection Date:08-Oct-2023 19:45:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:8
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 414 of 1261
Report Date: 09-Oct-2023 13:09:23 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508912.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:08-Oct-2023 20:06:30 ALS Bottle#:7 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:09:23 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1509132 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 87 366618 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 623453 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.692 4.691 0.001 93 368114 50.0 49.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 437780 50.0 49.5
$ 6 Toluene-d8 (Surr) 98 6.451 6.450 0.001 94 1582388 50.0 50.6
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 584827 50.0 50.5
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 776106 100.0 99.5
10 Chloromethane 50 1.939 1.939 0.000 99 924009 100.0 100.6
11 Vinyl chloride 62 2.039 2.039 0.000 99 893921 100.0 105.8
12 Bromomethane 94 2.332 2.332 0.000 91 512908 100.0 95.2
13 Chloroethane 64 2.425 2.425 0.000 100 548760 100.0 97.8
14 Dichlorofluoromethane 67 2.597 2.596 0.001 98 1431921 100.0 96.6
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 1069119 100.0 101.6
18 Ethyl ether 59 2.847 2.847 0.000 94 621848 100.0 94.9
19 Acrolein 56 2.961 2.961 0.000 99 920279 987.5 978.7
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 96 516915 100.0 104.3
21 1,1-Dichloroethene 96 3.047 3.047 0.000 98 626649 100.0 98.7
22 Acetone 43 3.061 3.061 0.000 99 886169 400.0 407.8
24 Iodomethane 142 3.169 3.168 0.001 99 942958 100.0 105.6
25 Carbon disulfide 76 3.233 3.233 0.000 99 2096589 100.0 98.3
27 Methyl acetate 43 3.290 3.290 0.000 99 1152098 200.0 211.5
28 3-Chloro-1-propene 41 3.312 3.311 0.001 91 1186490 100.0 105.3
29 Methylene Chloride 84 3.412 3.412 0.000 96 730862 100.0 93.9
30 2-Methyl-2-propanol 59 3.455 3.454 0.001 100 753849 1000.0 1041.2
31 Acrylonitrile 53 3.576 3.576 0.000 98 2900035 1000.0 1013.0
32 Methyl tert-butyl ether 73 3.598 3.597 0.001 96 2095646 100.0 104.5
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 719073 100.0 92.9
34 Hexane 57 3.805 3.805 0.000 94 1079597 100.0 101.2
35 Vinyl acetate 43 3.905 3.905 0.000 97 3066765 200.0 195.6
36 1,1-Dichloroethane 63 3.934 3.933 0.001 97 1399006 100.0 99.6
40 2-Butanone (MEK) 43 4.313 4.312 0.001 100 1426865 400.0 406.2
Page 415 of 1261
Report Date: 09-Oct-2023 13:09:23 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508912.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 793464 100.0 94.2
43 2,2-Dichloropropane 77 4.356 4.355 0.001 88 1176977 100.0 95.1
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 1563869 2400.0 2500.5
47 Chlorobromomethane 128 4.520 4.520 0.000 97 349629 100.0 96.6
48 Tetrahydrofuran 42 4.527 4.527 0.000 89 465397 200.0 197.8
49 Chloroform 83 4.577 4.577 0.000 95 1271065 100.0 96.8
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 1140489 100.0 99.7
51 Cyclohexane 56 4.785 4.784 0.001 92 1403991 100.0 100.4
52 1,1-Dichloropropene 75 4.835 4.834 0.001 98 1094867 100.0 103.8
53 Carbon tetrachloride 117 4.842 4.842 0.000 95 1004463 100.0 97.3
54 Isobutyl alcohol 41 4.842 4.842 0.000 94 685011 2500.0 2534.6
55 Benzene 78 4.985 4.992 -0.007 97 3086551 100.0 99.4
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 999765 100.0 99.3
58 n-Heptane 43 5.171 5.170 0.001 94 970428 100.0 105.7
60 Trichloroethene 95 5.471 5.471 0.000 98 771441 100.0 98.7
61 2-Pentanone 43 5.578 5.578 0.000 99 1788559 320.0 323.5
62 Methylcyclohexane 55 5.671 5.671 0.000 92 1066998 100.0 98.6
63 1,2-Dichloropropane 63 5.678 5.678 0.000 96 838306 100.0 100.5
65 1,4-Dioxane 88 5.721 5.721 0.000 96 195126 2000.0 2081.1
66 Dibromomethane 93 5.750 5.750 0.000 98 436080 100.0 99.0
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 1029064 100.0 97.4
69 2-Chloroethyl vinyl ether 63 6.072 6.071 0.001 92 529631 100.0 107.5
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 1331838 100.0 104.5
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 98 2929014 400.0 399.0
72 Toluene 91 6.515 6.508 0.007 98 3283498 100.0 96.3
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 97 1221611 100.0 102.9
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 986751 100.0 99.1
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 92 640290 100.0 97.4
76 Tetrachloroethene 164 6.951 6.958 -0.007 98 622945 100.0 106.2
77 1,3-Dichloropropane 76 7.008 7.008 0.000 98 1178677 100.0 103.9
78 2-Hexanone 43 7.023 7.022 0.001 97 2042700 400.0 397.0
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 765001 100.0 99.4
80 Ethylene Dibromide 107 7.323 7.323 0.000 98 663819 100.0 100.9
81 1-Chlorohexane 91 7.709 7.709 0.000 98 862360 80.0 81.3
82 Chlorobenzene 112 7.752 7.752 0.000 93 2017734 100.0 97.8
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 97 727377 100.0 102.9
84 Ethylbenzene 106 7.831 7.830 0.001 99 1137609 100.0 98.5
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 1426892 100.0 103.1
86 o-Xylene 106 8.302 8.302 0.000 97 1396724 100.0 99.6
87 Styrene 104 8.324 8.324 0.000 95 2345664 100.0 98.9
88 Bromoform 173 8.503 8.502 0.001 97 534238 100.0 104.0
89 Isopropylbenzene 105 8.646 8.645 0.001 96 3535981 100.0 101.2
91 Cyclohexanone 55 8.746 8.746 0.000 94 1065134 3000.0 3174.9
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 95 850876 100.0 104.0
93 Bromobenzene 156 8.967 8.967 0.000 97 858432 100.0 105.5
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 79 299158 100.0 104.0
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 246464 100.0 99.0
96 N-Propylbenzene 120 9.046 9.046 0.000 99 982157 100.0 100.8
97 2-Chlorotoluene 126 9.146 9.146 0.000 96 811176 100.0 100.1
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 95 3036365 100.0 101.3
99 4-Chlorotoluene 126 9.261 9.260 0.001 98 859284 100.0 101.0
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 2534995 100.0 98.5
Page 416 of 1261
Report Date: 09-Oct-2023 13:09:23 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508912.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 3150035 100.0 101.3
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 744173 100.0 106.1
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 1632035 100.0 105.7
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 3221652 100.0 100.6
106 1,4-Dichlorobenzene 146 9.976 9.968 0.008 94 1647398 100.0 102.3
108 n-Butylbenzene 91 10.297 10.297 0.000 98 2884042 100.0 101.5
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 1540971 100.0 103.9
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 85 194952 100.0 101.2
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 94 945366 100.0 106.9
113 Hexachlorobutadiene 225 12.071 12.070 0.001 96 449216 100.0 104.8
114 Naphthalene 128 12.199 12.199 0.000 98 2235229 100.0 102.9
115 1,2,3-Trichlorobenzene 180 12.421 12.421 0.000 95 751174 100.0 105.4
S 122 1,2-Dichloroethene, Total (URS) 96 0 200.0 187.1
S 127 Trihalomethanes, Total 1 0 400.0 397.7
S 124 1,3-Dichloropropene, Total 1 0 200.0 207.4
S 129 1,2-Dichloroethene, Total 1 0 200.0 187.1
S 126 Total BTEX 1 0 496.8
S 125 Xylenes, Total 106 0 200.0 202.6
S 123 Xylenes, Total (URS) 1 0 200.0 202.6
Reagents:
MV-MegaMainA_00096 Amount Added: 50.00 Units: uL
MV-Gas A_00168 Amount Added: 20.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 417 of 1261
Report Date: 09-Oct-2023 13:09:23 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508912.D
Injection Date:08-Oct-2023 20:06:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:9
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 418 of 1261
Report Date: 09-Oct-2023 13:09:29 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508913.D
Lims ID:IC
Client ID:
Sample Type:IC Calib Level:9
Inject. Date:08-Oct-2023 20:26:30 ALS Bottle#:8 Worklist Smp#:10
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:09:29 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 1559275 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 384015 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 95 659131 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 95 384808 50.0 49.8
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 453734 50.0 49.7
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 1635497 50.0 49.9
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 607600 50.0 49.6
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 1594454 200.0 197.0
10 Chloromethane 50 1.939 1.939 0.000 99 1889370 200.0 198.9
11 Vinyl chloride 62 2.039 2.039 0.000 99 1857483 200.0 212.7
12 Bromomethane 94 2.325 2.332 -0.007 91 1082108 200.0 194.5
13 Chloroethane 64 2.425 2.425 0.000 100 1118285 200.0 192.8
14 Dichlorofluoromethane 67 2.596 2.596 0.000 98 2884791 200.0 188.3
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 2211335 200.0 203.4
18 Ethyl ether 59 2.847 2.847 0.000 94 1280417 200.0 189.2
19 Acrolein 56 2.961 2.961 0.000 99 1806565 1975.0 1859.4
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 95 1069824 200.0 209.0
21 1,1-Dichloroethene 96 3.047 3.047 0.000 98 1291411 200.0 196.9
22 Acetone 43 3.061 3.061 0.000 99 1720188 800.0 770.7
24 Iodomethane 142 3.168 3.168 0.000 99 1922692 200.0 208.4
25 Carbon disulfide 76 3.233 3.233 0.000 99 4307359 200.0 195.5
27 Methyl acetate 43 3.290 3.290 0.000 99 2211009 400.0 393.1
28 3-Chloro-1-propene 41 3.311 3.311 0.000 91 1763637 200.0 198.2
29 Methylene Chloride 84 3.412 3.412 0.000 96 1516821 200.0 188.6
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 100 1496095 2000.0 1999.8
31 Acrylonitrile 53 3.576 3.576 0.000 97 5616375 2000.0 1898.7
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 96 4236897 200.0 204.6
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 1472091 200.0 184.2
34 Hexane 57 3.805 3.805 0.000 95 2235602 200.0 200.2
35 Vinyl acetate 43 3.905 3.905 0.000 97 6070813 400.0 374.7
36 1,1-Dichloroethane 63 3.933 3.933 0.000 97 2868017 200.0 197.7
40 2-Butanone (MEK) 43 4.320 4.312 0.008 100 2817552 800.0 776.3
Page 419 of 1261
Report Date: 09-Oct-2023 13:09:29 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508913.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 1648154 200.0 189.4
43 2,2-Dichloropropane 77 4.355 4.355 0.000 90 2436731 200.0 190.6
45 sec-Butyl Alcohol 45 4.427 4.420 0.007 99 3040038 4800.0 4704.5
47 Chlorobromomethane 128 4.520 4.520 0.000 97 711787 200.0 190.3
48 Tetrahydrofuran 42 4.527 4.527 0.000 89 919668 400.0 378.4
49 Chloroform 83 4.577 4.577 0.000 95 2641389 200.0 194.8
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 2345029 200.0 198.5
51 Cyclohexane 56 4.784 4.784 0.000 92 2883597 200.0 199.6
52 1,1-Dichloropropene 75 4.834 4.834 0.000 97 2227894 200.0 204.5
53 Carbon tetrachloride 117 4.842 4.842 0.000 95 2062090 200.0 193.3
54 Isobutyl alcohol 41 4.842 4.842 0.000 94 1339932 5000.0 4798.5
55 Benzene 78 4.992 4.992 0.000 98 6268861 200.0 195.4
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 2054517 200.0 197.4
58 n-Heptane 43 5.170 5.170 0.000 95 1931736 200.0 204.3
60 Trichloroethene 95 5.471 5.471 0.000 98 1603326 200.0 195.9
61 2-Pentanone 43 5.578 5.578 0.000 99 3483773 640.0 609.9
62 Methylcyclohexane 55 5.671 5.671 0.000 92 2187099 200.0 195.5
63 1,2-Dichloropropane 63 5.678 5.678 0.000 96 1743360 200.0 202.3
65 1,4-Dioxane 88 5.721 5.721 0.000 98 381034 4000.0 3933.2
66 Dibromomethane 93 5.750 5.750 0.000 97 887272 200.0 195.0
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 2099251 200.0 192.3
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 92 1053443 200.0 207.0
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 2723861 200.0 204.0
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 5683597 800.0 749.3
72 Toluene 91 6.515 6.508 0.007 98 6669352 200.0 189.2
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 97 2473965 200.0 201.7
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 1953157 200.0 187.3
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 92 1301020 200.0 191.6
76 Tetrachloroethene 164 6.958 6.958 0.000 99 1270979 200.0 206.8
77 1,3-Dichloropropane 76 7.008 7.008 0.000 98 2385754 200.0 200.8
78 2-Hexanone 43 7.022 7.022 0.000 97 3947188 800.0 732.3
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 1555933 200.0 193.1
80 Ethylene Dibromide 107 7.323 7.323 0.000 98 1333646 200.0 193.5
81 1-Chlorohexane 91 7.709 7.709 0.000 97 1759464 160.0 158.9
82 Chlorobenzene 112 7.752 7.752 0.000 92 4116988 200.0 190.6
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 96 1509298 200.0 203.8
84 Ethylbenzene 106 7.830 7.830 0.000 99 2379216 200.0 196.8
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 2940816 200.0 202.8
86 o-Xylene 106 8.309 8.302 0.007 97 2870000 200.0 195.3
87 Styrene 104 8.324 8.324 0.000 94 4809712 200.0 193.6
88 Bromoform 173 8.502 8.502 0.000 97 1076986 200.0 200.2
89 Isopropylbenzene 105 8.645 8.645 0.000 97 7180476 200.0 194.3
91 Cyclohexanone 55 8.746 8.746 0.000 94 2017972 6000.0 5749.2
92 1,1,2,2-Tetrachloroethane 83 8.931 8.931 0.000 95 1691801 200.0 195.5
93 Bromobenzene 156 8.967 8.967 0.000 97 1790798 200.0 208.2
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 76 572452 200.0 188.7
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 502919 200.0 191.1
96 N-Propylbenzene 120 9.046 9.046 0.000 99 2030536 200.0 197.1
97 2-Chlorotoluene 126 9.146 9.146 0.000 96 1713968 200.0 200.1
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 95 6122767 200.0 193.1
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 1773248 200.0 197.1
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 5224146 200.0 192.1
Page 420 of 1261
Report Date: 09-Oct-2023 13:09:29 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508913.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 6333644 200.0 192.7
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 1528084 200.0 206.0
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 3374451 200.0 206.8
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 6528184 200.0 192.8
106 1,4-Dichlorobenzene 146 9.975 9.968 0.007 94 3396169 200.0 199.6
108 n-Butylbenzene 91 10.297 10.297 0.000 98 5800898 200.0 193.2
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 3132776 200.0 199.7
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 85 376740 200.0 185.0
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 94 1868862 200.0 200.0
113 Hexachlorobutadiene 225 12.070 12.070 0.000 96 889637 200.0 196.3
114 Naphthalene 128 12.199 12.199 0.000 98 4217204 200.0 183.7
115 1,2,3-Trichlorobenzene 180 12.428 12.421 0.007 96 1446093 200.0 192.0
S 122 1,2-Dichloroethene, Total (URS) 96 0 400.0 373.5
S 127 Trihalomethanes, Total 1 0 800.0 780.4
S 124 1,3-Dichloropropene, Total 1 0 400.0 405.7
S 129 1,2-Dichloroethene, Total 1 0 400.0 373.5
S 126 Total BTEX 1 0 979.5
S 125 Xylenes, Total 106 0 400.0 398.1
S 123 Xylenes, Total (URS) 1 0 400.0 398.1
Reagents:
MV-MegaMainA_00096 Amount Added: 100.00 Units: uL
MV-Gas A_00168 Amount Added: 40.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 421 of 1261
Report Date: 09-Oct-2023 13:09:29 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508913.D
Injection Date:08-Oct-2023 20:26:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:IC Worklist Smp#:10
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:8
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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1
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Page 422 of 1261
Calibration / Dichlorodifluoromethane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2467
Slope:0.2608
Error Coefficients
Standard Error:858000
Relative Standard Error:11.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.556058 50.0 1455245.0 1.112115 N
2 IC 280-628924/3 1.0 0.308862 50.0 1404996.0 0.308862 N
3 IC 280-628924/4 2.0 0.32032 50.0 1400163.0 0.16016 Y
4 IC 280-628924/5 5.0 0.763928 50.0 1443067.0 0.152786 Y
5 IC 280-628924/6 10.0 2.623277 50.0 1419389.0 0.262328 Y
6 ICIS 280-628924/7 50.0 13.251455 50.0 1502020.0 0.265029 Y
7 IC 280-628924/8 75.0 19.751722 50.0 1539686.0 0.263356 Y
8 IC 280-628924/9 100.0 25.713655 50.0 1509132.0 0.257137 Y
9 IC 280-628924/10 200.0 51.128056 50.0 1559275.0 0.25564 Y
RelResp = [-0.2467] + [0.2608]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Intercept = 0.946
Page 423 of 1261
Calibration / Chloromethane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.07188
Slope:0.305
Error Coefficients
Standard Error:928000
Relative Standard Error:9.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.625462 50.0 1455245.0 1.250923 N
2 IC 280-628924/3 1.0 0.240107 50.0 1404996.0 0.240107 Y
3 IC 280-628924/4 2.0 0.539866 50.0 1400163.0 0.269933 Y
4 IC 280-628924/5 5.0 1.1733 50.0 1443067.0 0.23466 Y
5 IC 280-628924/6 10.0 3.341931 50.0 1419389.0 0.334193 Y
6 ICIS 280-628924/7 50.0 15.427058 50.0 1502020.0 0.308541 Y
7 IC 280-628924/8 75.0 23.320989 50.0 1539686.0 0.310947 Y
8 IC 280-628924/9 100.0 30.613922 50.0 1509132.0 0.306139 Y
9 IC 280-628924/10 200.0 60.584887 50.0 1559275.0 0.302924 Y
RelResp = [-0.07188] + [0.305]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Intercept = 0.236
Page 424 of 1261
Calibration / Vinyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.28
Error Coefficients
Standard Error:842000
Relative Standard Error:12.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.981
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.546265 50.0 1455245.0 1.092531 N
2 IC 280-628924/3 1.0 0.235303 50.0 1404996.0 0.235303 Y
3 IC 280-628924/4 2.0 0.497978 50.0 1400163.0 0.248989 Y
4 IC 280-628924/5 5.0 1.148976 50.0 1443067.0 0.229795 Y
5 IC 280-628924/6 10.0 3.251434 50.0 1419389.0 0.325143 Y
6 ICIS 280-628924/7 50.0 15.185284 50.0 1502020.0 0.303706 Y
7 IC 280-628924/8 75.0 22.749704 50.0 1539686.0 0.303329 Y
8 IC 280-628924/9 100.0 29.617058 50.0 1509132.0 0.296171 Y
9 IC 280-628924/10 200.0 59.562393 50.0 1559275.0 0.297812 Y
RelResp = [0.28]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 425 of 1261
Calibration / Bromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1784
Error Coefficients
Standard Error:486000
Relative Standard Error:11.2
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.982
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.2849 50.0 1455245.0 0.569801 N
2 IC 280-628924/3 1.0 0.224164 50.0 1404996.0 0.224164 Y
3 IC 280-628924/4 2.0 0.338389 50.0 1400163.0 0.169195 Y
4 IC 280-628924/5 5.0 0.826296 50.0 1443067.0 0.165259 Y
5 IC 280-628924/6 10.0 1.899338 50.0 1419389.0 0.189934 Y
6 ICIS 280-628924/7 50.0 8.337539 50.0 1502020.0 0.166751 Y
7 IC 280-628924/8 75.0 12.657841 50.0 1539686.0 0.168771 Y
8 IC 280-628924/9 100.0 16.993477 50.0 1509132.0 0.169935 Y
9 IC 280-628924/10 200.0 34.699075 50.0 1559275.0 0.173495 Y
RelResp = [0.1784]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 426 of 1261
Calibration / Chloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.186
Error Coefficients
Standard Error:510000
Relative Standard Error:9.7
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.37973 50.0 1455245.0 0.75946 N
2 IC 280-628924/3 1.0 0.194449 50.0 1404996.0 0.194449 Y
3 IC 280-628924/4 2.0 0.349424 50.0 1400163.0 0.174712 Y
4 IC 280-628924/5 5.0 0.813892 50.0 1443067.0 0.162778 Y
5 IC 280-628924/6 10.0 2.238992 50.0 1419389.0 0.223899 Y
6 ICIS 280-628924/7 50.0 9.122016 50.0 1502020.0 0.18244 Y
7 IC 280-628924/8 75.0 14.137525 50.0 1539686.0 0.1885 Y
8 IC 280-628924/9 100.0 18.181312 50.0 1509132.0 0.181813 Y
9 IC 280-628924/10 200.0 35.859133 50.0 1559275.0 0.179296 Y
RelResp = [0.186]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 427 of 1261
Calibration / Dichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4913
Error Coefficients
Standard Error:1320000
Relative Standard Error:10.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.985
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.930874 50.0 1455245.0 1.861748 N
2 IC 280-628924/3 1.0 0.601496 50.0 1404996.0 0.601496 Y
3 IC 280-628924/4 2.0 0.984814 50.0 1400163.0 0.492407 Y
4 IC 280-628924/5 5.0 2.149658 50.0 1443067.0 0.429932 Y
5 IC 280-628924/6 10.0 5.070034 50.0 1419389.0 0.507003 Y
6 ICIS 280-628924/7 50.0 24.487856 50.0 1502020.0 0.489757 Y
7 IC 280-628924/8 75.0 35.450248 50.0 1539686.0 0.47267 Y
8 IC 280-628924/9 100.0 47.441874 50.0 1509132.0 0.474419 Y
9 IC 280-628924/10 200.0 92.504241 50.0 1559275.0 0.462521 Y
RelResp = [0.4913]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 428 of 1261
Calibration / Trichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3486
Error Coefficients
Standard Error:1000000
Relative Standard Error:7.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.714072 50.0 1455245.0 1.428144 N
2 IC 280-628924/3 1.0 0.337012 50.0 1404996.0 0.337012 Y
3 IC 280-628924/4 2.0 0.687884 50.0 1400163.0 0.343942 Y
4 IC 280-628924/5 5.0 1.445394 50.0 1443067.0 0.289079 Y
5 IC 280-628924/6 10.0 3.81858 50.0 1419389.0 0.381858 Y
6 ICIS 280-628924/7 50.0 18.15858 50.0 1502020.0 0.363172 Y
7 IC 280-628924/8 75.0 27.380291 50.0 1539686.0 0.365071 Y
8 IC 280-628924/9 100.0 35.421653 50.0 1509132.0 0.354217 Y
9 IC 280-628924/10 200.0 70.909076 50.0 1559275.0 0.354545 Y
RelResp = [0.3486]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 429 of 1261
Calibration / Ethyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.217
Error Coefficients
Standard Error:541000
Relative Standard Error:9.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.125821 50.0 1455245.0 0.251641 Y
2 IC 280-628924/3 1.0 0.244485 50.0 1404996.0 0.244485 Y
3 IC 280-628924/4 2.0 0.45534 50.0 1400163.0 0.22767 Y
4 IC 280-628924/5 5.0 0.985817 50.0 1443067.0 0.197163 Y
5 IC 280-628924/6 10.0 2.162621 50.0 1419389.0 0.216262 Y
6 ICIS 280-628924/7 50.0 10.13129 50.0 1502020.0 0.202626 Y
7 IC 280-628924/8 75.0 15.131559 50.0 1539686.0 0.201754 Y
8 IC 280-628924/9 100.0 20.602837 50.0 1509132.0 0.206028 Y
9 IC 280-628924/10 200.0 41.058088 50.0 1559275.0 0.20529 Y
RelResp = [0.217]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 430 of 1261
Calibration / Acrolein
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.03116
Error Coefficients
Standard Error:772000
Relative Standard Error:7.7
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 4.9375 0.180519 50.0 1455245.0 0.036561 Y
2 IC 280-628924/3 9.875 0.322528 50.0 1404996.0 0.032661 Y
3 IC 280-628924/4 19.75 0.615607 50.0 1400163.0 0.03117 Y
4 IC 280-628924/5 49.375 1.418264 50.0 1443067.0 0.028724 Y
5 IC 280-628924/6 98.75 3.148467 50.0 1419389.0 0.031883 Y
6 ICIS 280-628924/7 493.75 14.711588 50.0 1502020.0 0.029796 Y
7 IC 280-628924/8 740.625 21.7709 50.0 1539686.0 0.029395 Y
8 IC 280-628924/9 987.5 30.490341 50.0 1509132.0 0.030876 Y
9 IC 280-628924/10 1975.0 57.929647 50.0 1559275.0 0.029331 Y
RelResp = [0.03116]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 431 of 1261
Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1642
Error Coefficients
Standard Error:453000
Relative Standard Error:8.7
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.065522 50.0 1455245.0 0.131043 Y
2 IC 280-628924/3 1.0 0.157545 50.0 1404996.0 0.157545 Y
3 IC 280-628924/4 2.0 0.32814 50.0 1400163.0 0.16407 Y
4 IC 280-628924/5 5.0 0.79681 50.0 1443067.0 0.159362 Y
5 IC 280-628924/6 10.0 1.79852 50.0 1419389.0 0.179852 Y
6 ICIS 280-628924/7 50.0 8.47745 50.0 1502020.0 0.169549 Y
7 IC 280-628924/8 75.0 12.993916 50.0 1539686.0 0.173252 Y
8 IC 280-628924/9 100.0 17.126235 50.0 1509132.0 0.171262 Y
9 IC 280-628924/10 200.0 34.305174 50.0 1559275.0 0.171526 Y
RelResp = [0.1642]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6 ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 432 of 1261
Calibration / 1,1-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2103
Error Coefficients
Standard Error:583000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.157087 50.0 1455245.0 0.314174 N
2 IC 280-628924/3 1.0 0.200072 50.0 1404996.0 0.200072 Y
3 IC 280-628924/4 2.0 0.423594 50.0 1400163.0 0.211797 Y
4 IC 280-628924/5 5.0 1.068765 50.0 1443067.0 0.213753 Y
5 IC 280-628924/6 10.0 2.389408 50.0 1419389.0 0.238941 Y
6 ICIS 280-628924/7 50.0 10.06944 50.0 1502020.0 0.201389 Y
7 IC 280-628924/8 75.0 15.161565 50.0 1539686.0 0.202154 Y
8 IC 280-628924/9 100.0 20.761902 50.0 1509132.0 0.207619 Y
9 IC 280-628924/10 200.0 41.410624 50.0 1559275.0 0.207053 Y
RelResp = [0.2103]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 433 of 1261
Calibration / Acetone
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.3731
Slope:0.07109
Error Coefficients
Standard Error:849000
Relative Standard Error:7.4
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 2.0 0.708059 50.0 1455245.0 0.35403 N
2 IC 280-628924/3 4.0 0.642208 50.0 1404996.0 0.160552 Y
3 IC 280-628924/4 8.0 1.00474 50.0 1400163.0 0.125593 Y
4 IC 280-628924/5 20.0 1.728575 50.0 1443067.0 0.086429 Y
5 IC 280-628924/6 40.0 3.468288 50.0 1419389.0 0.086707 Y
6 ICIS 280-628924/7 200.0 14.514287 50.0 1502020.0 0.072571 Y
7 IC 280-628924/8 300.0 20.073736 50.0 1539686.0 0.066912 Y
8 IC 280-628924/9 400.0 29.360222 50.0 1509132.0 0.073401 Y
9 IC 280-628924/10 800.0 55.159866 50.0 1559275.0 0.06895 Y
RelResp = [0.3731] + [0.07109]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Intercept = -5.25
Page 434 of 1261
Calibration / Iodomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2959
Error Coefficients
Standard Error:877000
Relative Standard Error:10.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.986
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.263117 50.0 1455245.0 0.526234 N
2 IC 280-628924/3 1.0 0.277225 50.0 1404996.0 0.277225 Y
3 IC 280-628924/4 2.0 0.534652 50.0 1400163.0 0.267326 Y
4 IC 280-628924/5 5.0 1.183452 50.0 1443067.0 0.23669 Y
5 IC 280-628924/6 10.0 3.215081 50.0 1419389.0 0.321508 Y
6 ICIS 280-628924/7 50.0 15.895427 50.0 1502020.0 0.317909 Y
7 IC 280-628924/8 75.0 24.437775 50.0 1539686.0 0.325837 Y
8 IC 280-628924/9 100.0 31.241734 50.0 1509132.0 0.312417 Y
9 IC 280-628924/10 200.0 61.653397 50.0 1559275.0 0.308267 Y
RelResp = [0.2959]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 435 of 1261
Calibration / Carbon disulfide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7064
Error Coefficients
Standard Error:1830000
Relative Standard Error:6.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.363684 50.0 1455245.0 0.727369 Y
2 IC 280-628924/3 1.0 0.749931 50.0 1404996.0 0.749931 Y
3 IC 280-628924/4 2.0 1.374376 50.0 1400163.0 0.687188 Y
4 IC 280-628924/5 5.0 3.123174 50.0 1443067.0 0.624635 Y
5 IC 280-628924/6 10.0 7.871415 50.0 1419389.0 0.787142 Y
6 ICIS 280-628924/7 50.0 34.71282 50.0 1502020.0 0.694256 Y
7 IC 280-628924/8 75.0 52.627873 50.0 1539686.0 0.701705 Y
8 IC 280-628924/9 100.0 69.463407 50.0 1509132.0 0.694634 Y
9 IC 280-628924/10 200.0 138.120569 50.0 1559275.0 0.690603 Y
RelResp = [0.7064]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 436 of 1261
Calibration / Methyl acetate
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.0537
Slope:0.1802
Error Coefficients
Standard Error:1010000
Relative Standard Error:14.3
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 1.0 0.21986 50.0 1455245.0 0.21986 Y
2 IC 280-628924/3 2.0 0.521852 50.0 1404996.0 0.260926 Y
3 IC 280-628924/4 4.0 0.684313 50.0 1400163.0 0.171078 Y
4 IC 280-628924/5 10.0 1.574043 50.0 1443067.0 0.157404 Y
5 IC 280-628924/6 20.0 3.836087 50.0 1419389.0 0.191804 Y
6 ICIS 280-628924/7 100.0 17.959315 50.0 1502020.0 0.179593 Y
7 IC 280-628924/8 150.0 26.456628 50.0 1539686.0 0.176378 Y
8 IC 280-628924/9 200.0 38.170882 50.0 1509132.0 0.190854 Y
9 IC 280-628924/10 400.0 70.898623 50.0 1559275.0 0.177247 Y
RelResp = [0.0537] + [0.1802]x
Concentration
0 100 200 300 400
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Intercept = -0.298
Page 437 of 1261
Calibration / 3-Chloro-1-propene
Curve Type:Quadratic
Weighting:None
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.01604
Slope:0.4728
Second Order:-0.0009461
Error Coefficients
Standard Error:977000
Relative Standard Error:9.9
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.270985 50.0 1455245.0 0.541971 Y
2 IC 280-628924/3 1.0 0.526265 50.0 1404996.0 0.526265 Y
3 IC 280-628924/4 2.0 1.109014 50.0 1400163.0 0.554507 Y
4 IC 280-628924/5 5.0 2.21102 50.0 1443067.0 0.442204 Y
5 IC 280-628924/6 10.0 5.081236 50.0 1419389.0 0.508124 Y
6 ICIS 280-628924/7 50.0 20.572895 50.0 1502020.0 0.411458 Y
7 IC 280-628924/8 75.0 29.069986 50.0 1539686.0 0.3876 Y
8 IC 280-628924/9 100.0 39.310345 50.0 1509132.0 0.393103 Y
9 IC 280-628924/10 200.0 56.55311 50.0 1559275.0 0.282766 Y
RelResp = [0.01604] + [0.4728]x + [-0.0009461]x^2
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Intercept = -0.0339
Page 438 of 1261
Calibration / Methylene Chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2579
Error Coefficients
Standard Error:641000
Relative Standard Error:8.7
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.990
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.14008 50.0 1455245.0 0.280159 Y
2 IC 280-628924/3 1.0 0.306762 50.0 1404996.0 0.306762 Y
3 IC 280-628924/4 2.0 0.49205 50.0 1400163.0 0.246025 Y
4 IC 280-628924/5 5.0 1.268514 50.0 1443067.0 0.253703 Y
5 IC 280-628924/6 10.0 2.633422 50.0 1419389.0 0.263342 Y
6 ICIS 280-628924/7 50.0 12.118048 50.0 1502020.0 0.242361 Y
7 IC 280-628924/8 75.0 18.242096 50.0 1539686.0 0.243228 Y
8 IC 280-628924/9 100.0 24.214648 50.0 1509132.0 0.242146 Y
9 IC 280-628924/10 200.0 48.638662 50.0 1559275.0 0.243193 Y
RelResp = [0.2579]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 439 of 1261
Calibration / 2-Methyl-2-propanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.02399
Error Coefficients
Standard Error:635000
Relative Standard Error:4.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 5.0 0.125718 50.0 1455245.0 0.025144 Y
2 IC 280-628924/3 10.0 0.226869 50.0 1404996.0 0.022687 Y
3 IC 280-628924/4 20.0 0.475909 50.0 1400163.0 0.023795 Y
4 IC 280-628924/5 50.0 1.118105 50.0 1443067.0 0.022362 Y
5 IC 280-628924/6 100.0 2.571635 50.0 1419389.0 0.025716 Y
6 ICIS 280-628924/7 500.0 12.151436 50.0 1502020.0 0.024303 Y
7 IC 280-628924/8 750.0 17.197175 50.0 1539686.0 0.02293 Y
8 IC 280-628924/9 1000.0 24.976245 50.0 1509132.0 0.024976 Y
9 IC 280-628924/10 2000.0 47.974058 50.0 1559275.0 0.023987 Y
RelResp = [0.02399]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 440 of 1261
Calibration / Acrylonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.09485
Error Coefficients
Standard Error:2410000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 5.0 0.518641 50.0 1455245.0 0.103728 Y
2 IC 280-628924/3 10.0 0.870358 50.0 1404996.0 0.087036 Y
3 IC 280-628924/4 20.0 1.941488 50.0 1400163.0 0.097074 Y
4 IC 280-628924/5 50.0 4.571098 50.0 1443067.0 0.091422 Y
5 IC 280-628924/6 100.0 10.308097 50.0 1419389.0 0.103081 Y
6 ICIS 280-628924/7 500.0 46.819084 50.0 1502020.0 0.093638 Y
7 IC 280-628924/8 750.0 68.675171 50.0 1539686.0 0.091567 Y
8 IC 280-628924/9 1000.0 96.082881 50.0 1509132.0 0.096083 Y
9 IC 280-628924/10 2000.0 180.095718 50.0 1559275.0 0.090048 Y
RelResp = [0.09485]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 441 of 1261
Calibration / Methyl tert-butyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6642
Error Coefficients
Standard Error:1800000
Relative Standard Error:7.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.350353 50.0 1455245.0 0.700707 Y
2 IC 280-628924/3 1.0 0.577333 50.0 1404996.0 0.577333 Y
3 IC 280-628924/4 2.0 1.281994 50.0 1400163.0 0.640997 Y
4 IC 280-628924/5 5.0 2.976265 50.0 1443067.0 0.595253 Y
5 IC 280-628924/6 10.0 7.240686 50.0 1419389.0 0.724069 Y
6 ICIS 280-628924/7 50.0 34.129772 50.0 1502020.0 0.682595 Y
7 IC 280-628924/8 75.0 51.226938 50.0 1539686.0 0.683026 Y
8 IC 280-628924/9 100.0 69.432164 50.0 1509132.0 0.694322 Y
9 IC 280-628924/10 200.0 135.861121 50.0 1559275.0 0.679306 Y
RelResp = [0.6642]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 442 of 1261
Calibration / trans-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2563
Error Coefficients
Standard Error:623000
Relative Standard Error:13.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.976
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.134032 50.0 1455245.0 0.268065 Y
2 IC 280-628924/3 1.0 0.332777 50.0 1404996.0 0.332777 Y
3 IC 280-628924/4 2.0 0.549008 50.0 1400163.0 0.274504 Y
4 IC 280-628924/5 5.0 1.124272 50.0 1443067.0 0.224854 Y
5 IC 280-628924/6 10.0 2.66199 50.0 1419389.0 0.266199 Y
6 ICIS 280-628924/7 50.0 11.575778 50.0 1502020.0 0.231516 Y
7 IC 280-628924/8 75.0 17.598686 50.0 1539686.0 0.234649 Y
8 IC 280-628924/9 100.0 23.824059 50.0 1509132.0 0.238241 Y
9 IC 280-628924/10 200.0 47.204342 50.0 1559275.0 0.236022 Y
RelResp = [0.2563]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 443 of 1261
Calibration / Hexane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1199
Slope:1.453
Error Coefficients
Standard Error:1010000
Relative Standard Error:13.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.990244 50.0 365516.0 1.980488 Y
2 IC 280-628924/3 1.0 1.783561 50.0 358244.0 1.783561 Y
3 IC 280-628924/4 2.0 2.726573 50.0 350880.0 1.363287 Y
4 IC 280-628924/5 5.0 5.755143 50.0 365421.0 1.151029 Y
5 IC 280-628924/6 10.0 14.287193 50.0 352564.0 1.428719 Y
6 ICIS 280-628924/7 50.0 72.533043 50.0 360515.0 1.450661 Y
7 IC 280-628924/8 75.0 109.310094 50.0 375979.0 1.457468 Y
8 IC 280-628924/9 100.0 147.237315 50.0 366618.0 1.472373 Y
9 IC 280-628924/10 200.0 291.08264 50.0 384015.0 1.455413 Y
RelResp = [0.1199] + [1.453]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Intercept = -0.0825
Page 444 of 1261
Calibration / Vinyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5195
Error Coefficients
Standard Error:2600000
Relative Standard Error:11.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.981
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 1.0 0.583132 50.0 1455245.0 0.583132 Y
2 IC 280-628924/3 2.0 1.270609 50.0 1404996.0 0.635304 Y
3 IC 280-628924/4 4.0 1.894029 50.0 1400163.0 0.473507 Y
4 IC 280-628924/5 10.0 4.399276 50.0 1443067.0 0.439928 Y
5 IC 280-628924/6 20.0 11.069763 50.0 1419389.0 0.553488 Y
6 ICIS 280-628924/7 100.0 49.375541 50.0 1502020.0 0.493755 Y
7 IC 280-628924/8 150.0 75.30529 50.0 1539686.0 0.502035 Y
8 IC 280-628924/9 200.0 101.606917 50.0 1509132.0 0.508035 Y
9 IC 280-628924/10 400.0 194.66781 50.0 1559275.0 0.48667 Y
RelResp = [0.5195]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 445 of 1261
Calibration / 1,1-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4652
Error Coefficients
Standard Error:1220000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.215118 50.0 1455245.0 0.430237 Y
2 IC 280-628924/3 1.0 0.490998 50.0 1404996.0 0.490998 Y
3 IC 280-628924/4 2.0 0.927142 50.0 1400163.0 0.463571 Y
4 IC 280-628924/5 5.0 2.16421 50.0 1443067.0 0.432842 Y
5 IC 280-628924/6 10.0 5.212842 50.0 1419389.0 0.521284 Y
6 ICIS 280-628924/7 50.0 23.067968 50.0 1502020.0 0.461359 Y
7 IC 280-628924/8 75.0 34.766991 50.0 1539686.0 0.46356 Y
8 IC 280-628924/9 100.0 46.351346 50.0 1509132.0 0.463513 Y
9 IC 280-628924/10 200.0 91.966363 50.0 1559275.0 0.459832 Y
RelResp = [0.4652]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 446 of 1261
Calibration / 2-Butanone (MEK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1164
Error Coefficients
Standard Error:1200000
Relative Standard Error:9.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.987
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 2.0 0.24288 50.0 1455245.0 0.12144 Y
2 IC 280-628924/3 4.0 0.56993 50.0 1404996.0 0.142483 Y
3 IC 280-628924/4 8.0 0.900074 50.0 1400163.0 0.112509 Y
4 IC 280-628924/5 20.0 2.008812 50.0 1443067.0 0.100441 Y
5 IC 280-628924/6 40.0 4.694555 50.0 1419389.0 0.117364 Y
6 ICIS 280-628924/7 200.0 22.569673 50.0 1502020.0 0.112848 Y
7 IC 280-628924/8 300.0 32.768954 50.0 1539686.0 0.10923 Y
8 IC 280-628924/9 400.0 47.27436 50.0 1509132.0 0.118186 Y
9 IC 280-628924/10 800.0 90.348143 50.0 1559275.0 0.112935 Y
RelResp = [0.1164]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 447 of 1261
Calibration / cis-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2791
Error Coefficients
Standard Error:745000
Relative Standard Error:9.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.987
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.164989 50.0 1455245.0 0.329979 N
2 IC 280-628924/3 1.0 0.340784 50.0 1404996.0 0.340784 Y
3 IC 280-628924/4 2.0 0.545294 50.0 1400163.0 0.272647 Y
4 IC 280-628924/5 5.0 1.369964 50.0 1443067.0 0.273993 Y
5 IC 280-628924/6 10.0 2.8991 50.0 1419389.0 0.28991 Y
6 ICIS 280-628924/7 50.0 13.108747 50.0 1502020.0 0.262175 Y
7 IC 280-628924/8 75.0 19.951795 50.0 1539686.0 0.266024 Y
8 IC 280-628924/9 100.0 26.288754 50.0 1509132.0 0.262888 Y
9 IC 280-628924/10 200.0 52.85001 50.0 1559275.0 0.26425 Y
RelResp = [0.2791]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 448 of 1261
Calibration / 2,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.41
Error Coefficients
Standard Error:1100000
Relative Standard Error:8.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.990
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.25439 50.0 1455245.0 0.50878 N
2 IC 280-628924/3 1.0 0.466656 50.0 1404996.0 0.466656 Y
3 IC 280-628924/4 2.0 0.84533 50.0 1400163.0 0.422665 Y
4 IC 280-628924/5 5.0 1.871327 50.0 1443067.0 0.374265 Y
5 IC 280-628924/6 10.0 4.553861 50.0 1419389.0 0.455386 Y
6 ICIS 280-628924/7 50.0 19.448476 50.0 1502020.0 0.38897 Y
7 IC 280-628924/8 75.0 29.344165 50.0 1539686.0 0.391256 Y
8 IC 280-628924/9 100.0 38.995164 50.0 1509132.0 0.389952 Y
9 IC 280-628924/10 200.0 78.136666 50.0 1559275.0 0.390683 Y
RelResp = [0.41]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 449 of 1261
Calibration / sec-Butyl Alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.02072
Error Coefficients
Standard Error:1390000
Relative Standard Error:5.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 12.0 0.167566 50.0 1455245.0 0.013964 N
2 IC 280-628924/3 24.0 0.497368 50.0 1404996.0 0.020724 Y
3 IC 280-628924/4 48.0 0.988599 50.0 1400163.0 0.020596 Y
4 IC 280-628924/5 120.0 2.276679 50.0 1443067.0 0.018972 Y
5 IC 280-628924/6 240.0 5.497682 50.0 1419389.0 0.022907 Y
6 ICIS 280-628924/7 1200.0 25.270802 50.0 1502020.0 0.021059 Y
7 IC 280-628924/8 1800.0 35.30577 50.0 1539686.0 0.019614 Y
8 IC 280-628924/9 2400.0 51.813526 50.0 1509132.0 0.021589 Y
9 IC 280-628924/10 4800.0 97.48242 50.0 1559275.0 0.020309 Y
RelResp = [0.02072]x
Concentration
0 1000 2000 3000 4000 5000
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 450 of 1261
Calibration / Chlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1199
Error Coefficients
Standard Error:323000
Relative Standard Error:7.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.07631 50.0 1455245.0 0.15262 N
2 IC 280-628924/3 1.0 0.129858 50.0 1404996.0 0.129858 Y
3 IC 280-628924/4 2.0 0.240186 50.0 1400163.0 0.120093 Y
4 IC 280-628924/5 5.0 0.559641 50.0 1443067.0 0.111928 Y
5 IC 280-628924/6 10.0 1.360656 50.0 1419389.0 0.136066 Y
6 ICIS 280-628924/7 50.0 5.830215 50.0 1502020.0 0.116604 Y
7 IC 280-628924/8 75.0 8.627701 50.0 1539686.0 0.115036 Y
8 IC 280-628924/9 100.0 11.583778 50.0 1509132.0 0.115838 Y
9 IC 280-628924/10 200.0 22.824293 50.0 1559275.0 0.114121 Y
RelResp = [0.1199]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 451 of 1261
Calibration / Tetrahydrofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.07794
Error Coefficients
Standard Error:419000
Relative Standard Error:6.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 1.0 0.059646 50.0 1455245.0 0.059646 N
2 IC 280-628924/3 2.0 0.167189 50.0 1404996.0 0.083595 Y
3 IC 280-628924/4 4.0 0.333711 50.0 1400163.0 0.083428 Y
4 IC 280-628924/5 10.0 0.731324 50.0 1443067.0 0.073132 Y
5 IC 280-628924/6 20.0 1.68178 50.0 1419389.0 0.084089 Y
6 ICIS 280-628924/7 100.0 7.495573 50.0 1502020.0 0.074956 Y
7 IC 280-628924/8 150.0 11.028612 50.0 1539686.0 0.073524 Y
8 IC 280-628924/9 200.0 15.41936 50.0 1509132.0 0.077097 Y
9 IC 280-628924/10 400.0 29.490244 50.0 1559275.0 0.073726 Y
RelResp = [0.07794]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 452 of 1261
Calibration / Chloroform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4349
Error Coefficients
Standard Error:1190000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.106511 50.0 1455245.0 0.213023 N
2 IC 280-628924/3 1.0 0.466051 50.0 1404996.0 0.466051 Y
3 IC 280-628924/4 2.0 0.885183 50.0 1400163.0 0.442591 Y
4 IC 280-628924/5 5.0 2.002263 50.0 1443067.0 0.400453 Y
5 IC 280-628924/6 10.0 4.793753 50.0 1419389.0 0.479375 Y
6 ICIS 280-628924/7 50.0 21.022623 50.0 1502020.0 0.420452 Y
7 IC 280-628924/8 75.0 31.916573 50.0 1539686.0 0.425554 Y
8 IC 280-628924/9 100.0 42.112453 50.0 1509132.0 0.421125 Y
9 IC 280-628924/10 200.0 84.699267 50.0 1559275.0 0.423496 Y
RelResp = [0.4349]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 453 of 1261
Calibration / Dibromofluoromethane (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2478
Error Coefficients
Standard Error:386000
Relative Standard Error:1.5
Correlation Coefficient:NA
Coefficient of Determination (Adjusted):0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 50.0 12.17953 50.0 1455245.0 0.243591 Y
2 IC 280-628924/3 50.0 12.705552 50.0 1404996.0 0.254111 Y
3 IC 280-628924/4 50.0 12.435909 50.0 1400163.0 0.248718 Y
4 IC 280-628924/5 50.0 12.614383 50.0 1443067.0 0.252288 Y
5 IC 280-628924/6 50.0 12.514434 50.0 1419389.0 0.250289 Y
6 ICIS 280-628924/7 50.0 12.29238 50.0 1502020.0 0.245848 Y
7 IC 280-628924/8 50.0 12.216679 50.0 1539686.0 0.244334 Y
8 IC 280-628924/9 50.0 12.196216 50.0 1509132.0 0.243924 Y
9 IC 280-628924/10 50.0 12.339324 50.0 1559275.0 0.246786 Y
RelResp = [0.2478]x
Concentration
0 10 20 30 40 50
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/3IC 280-628924/4IC 280-628924/5IC 280-628924/6
Page 454 of 1261
Calibration / 1,1,1-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3789
Error Coefficients
Standard Error:992000
Relative Standard Error:6.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.204055 50.0 1455245.0 0.40811 Y
2 IC 280-628924/3 1.0 0.400357 50.0 1404996.0 0.400357 Y
3 IC 280-628924/4 2.0 0.755412 50.0 1400163.0 0.377706 Y
4 IC 280-628924/5 5.0 1.625358 50.0 1443067.0 0.325072 Y
5 IC 280-628924/6 10.0 3.976676 50.0 1419389.0 0.397668 Y
6 ICIS 280-628924/7 50.0 18.561504 50.0 1502020.0 0.37123 Y
7 IC 280-628924/8 75.0 28.193671 50.0 1539686.0 0.375916 Y
8 IC 280-628924/9 100.0 37.786257 50.0 1509132.0 0.377863 Y
9 IC 280-628924/10 200.0 75.196133 50.0 1559275.0 0.375981 Y
RelResp = [0.3789]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 455 of 1261
Calibration / Cyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4633
Error Coefficients
Standard Error:1220000
Relative Standard Error:6.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.203402 50.0 1455245.0 0.406804 Y
2 IC 280-628924/3 1.0 0.466834 50.0 1404996.0 0.466834 Y
3 IC 280-628924/4 2.0 0.997134 50.0 1400163.0 0.498567 Y
4 IC 280-628924/5 5.0 2.166878 50.0 1443067.0 0.433376 Y
5 IC 280-628924/6 10.0 5.0694 50.0 1419389.0 0.50694 Y
6 ICIS 280-628924/7 50.0 23.117136 50.0 1502020.0 0.462343 Y
7 IC 280-628924/8 75.0 35.081309 50.0 1539686.0 0.467751 Y
8 IC 280-628924/9 100.0 46.516508 50.0 1509132.0 0.465165 Y
9 IC 280-628924/10 200.0 92.465954 50.0 1559275.0 0.46233 Y
RelResp = [0.4633]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 456 of 1261
Calibration / 1,1-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3494
Error Coefficients
Standard Error:945000
Relative Standard Error:5.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.18289 50.0 1455245.0 0.36578 Y
2 IC 280-628924/3 1.0 0.319574 50.0 1404996.0 0.319574 Y
3 IC 280-628924/4 2.0 0.647639 50.0 1400163.0 0.323819 Y
4 IC 280-628924/5 5.0 1.633847 50.0 1443067.0 0.326769 Y
5 IC 280-628924/6 10.0 3.761478 50.0 1419389.0 0.376148 Y
6 ICIS 280-628924/7 50.0 17.589779 50.0 1502020.0 0.351796 Y
7 IC 280-628924/8 75.0 27.067467 50.0 1539686.0 0.3609 Y
8 IC 280-628924/9 100.0 36.274726 50.0 1509132.0 0.362747 Y
9 IC 280-628924/10 200.0 71.44006 50.0 1559275.0 0.3572 Y
RelResp = [0.3494]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 457 of 1261
Calibration / Carbon tetrachloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.342
Error Coefficients
Standard Error:872000
Relative Standard Error:7.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.200585 50.0 1455245.0 0.40117 Y
2 IC 280-628924/3 1.0 0.358079 50.0 1404996.0 0.358079 Y
3 IC 280-628924/4 2.0 0.678814 50.0 1400163.0 0.339407 Y
4 IC 280-628924/5 5.0 1.569816 50.0 1443067.0 0.313963 Y
5 IC 280-628924/6 10.0 3.515421 50.0 1419389.0 0.351542 Y
6 ICIS 280-628924/7 50.0 16.085605 50.0 1502020.0 0.321712 Y
7 IC 280-628924/8 75.0 24.677564 50.0 1539686.0 0.329034 Y
8 IC 280-628924/9 100.0 33.279494 50.0 1509132.0 0.332795 Y
9 IC 280-628924/10 200.0 66.123359 50.0 1559275.0 0.330617 Y
RelResp = [0.342]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 458 of 1261
Calibration / Isobutyl alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.008954
Error Coefficients
Standard Error:607000
Relative Standard Error:12.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.976
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 12.5 0.092149 50.0 1455245.0 0.007372 N
2 IC 280-628924/3 25.0 0.280392 50.0 1404996.0 0.011216 Y
3 IC 280-628924/4 50.0 0.488229 50.0 1400163.0 0.009765 Y
4 IC 280-628924/5 125.0 0.96333 50.0 1443067.0 0.007707 Y
5 IC 280-628924/6 250.0 2.280488 50.0 1419389.0 0.009122 Y
6 ICIS 280-628924/7 1250.0 9.968676 50.0 1502020.0 0.007975 Y
7 IC 280-628924/8 1875.0 15.333646 50.0 1539686.0 0.008178 Y
8 IC 280-628924/9 2500.0 22.69553 50.0 1509132.0 0.009078 Y
9 IC 280-628924/10 5000.0 42.966507 50.0 1559275.0 0.008593 Y
RelResp = [0.008954]x
Concentration
0 1000 2000 3000 4000 5000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 459 of 1261
Calibration / 1,2-Dichloroethane-d4 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2929
Error Coefficients
Standard Error:457000
Relative Standard Error:2.1
Correlation Coefficient:0.00000000000000000000
Coefficient of Determination (Adjusted):0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 50.0 14.84348 50.0 1455245.0 0.29687 Y
2 IC 280-628924/3 50.0 14.646056 50.0 1404996.0 0.292921 Y
3 IC 280-628924/4 50.0 14.947081 50.0 1400163.0 0.298942 Y
4 IC 280-628924/5 50.0 15.216445 50.0 1443067.0 0.304329 Y
5 IC 280-628924/6 50.0 14.458087 50.0 1419389.0 0.289162 Y
6 ICIS 280-628924/7 50.0 14.316188 50.0 1502020.0 0.286324 Y
7 IC 280-628924/8 50.0 14.306131 50.0 1539686.0 0.286123 Y
8 IC 280-628924/9 50.0 14.504364 50.0 1509132.0 0.290087 Y
9 IC 280-628924/10 50.0 14.549518 50.0 1559275.0 0.29099 Y
RelResp = [0.2929]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2IC 280-628924/3IC 280-628924/4IC 280-628924/5
Page 460 of 1261
Calibration / Benzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.029
Error Coefficients
Standard Error:2670000
Relative Standard Error:4.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.518676 50.0 1455245.0 1.037351 Y
2 IC 280-628924/3 1.0 1.017369 50.0 1404996.0 1.017369 Y
3 IC 280-628924/4 2.0 2.063831 50.0 1400163.0 1.031916 Y
4 IC 280-628924/5 5.0 4.797456 50.0 1443067.0 0.959491 Y
5 IC 280-628924/6 10.0 11.482335 50.0 1419389.0 1.148234 Y
6 ICIS 280-628924/7 50.0 50.4947 50.0 1502020.0 1.009894 Y
7 IC 280-628924/8 75.0 77.110625 50.0 1539686.0 1.028142 Y
8 IC 280-628924/9 100.0 102.262459 50.0 1509132.0 1.022625 Y
9 IC 280-628924/10 200.0 201.018454 50.0 1559275.0 1.005092 Y
RelResp = [1.029]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 461 of 1261
Calibration / 1,2-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3337
Error Coefficients
Standard Error:871000
Relative Standard Error:3.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.176809 50.0 1455245.0 0.353617 Y
2 IC 280-628924/3 1.0 0.339503 50.0 1404996.0 0.339503 Y
3 IC 280-628924/4 2.0 0.672672 50.0 1400163.0 0.336336 Y
4 IC 280-628924/5 5.0 1.534267 50.0 1443067.0 0.306853 Y
5 IC 280-628924/6 10.0 3.453282 50.0 1419389.0 0.345328 Y
6 ICIS 280-628924/7 50.0 16.421719 50.0 1502020.0 0.328434 Y
7 IC 280-628924/8 75.0 24.949308 50.0 1539686.0 0.332657 Y
8 IC 280-628924/9 100.0 33.123842 50.0 1509132.0 0.331238 Y
9 IC 280-628924/10 200.0 65.880521 50.0 1559275.0 0.329403 Y
RelResp = [0.3337]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 462 of 1261
Calibration / n-Heptane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.2452
Slope:0.3019
Error Coefficients
Standard Error:1040000
Relative Standard Error:7.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.175469 50.0 1455245.0 0.350937 N
2 IC 280-628924/3 1.0 0.0 50.0 1404996.0 0.0 N
3 IC 280-628924/4 2.0 0.882719 50.0 1400163.0 0.441359 Y
4 IC 280-628924/5 5.0 1.533297 50.0 1443067.0 0.306659 Y
5 IC 280-628924/6 10.0 3.289866 50.0 1419389.0 0.328987 Y
6 ICIS 280-628924/7 50.0 15.189578 50.0 1502020.0 0.303792 Y
7 IC 280-628924/8 75.0 23.215643 50.0 1539686.0 0.309542 Y
8 IC 280-628924/9 100.0 32.151859 50.0 1509132.0 0.321519 Y
9 IC 280-628924/10 200.0 61.943403 50.0 1559275.0 0.309717 Y
RelResp = [0.2452] + [0.3019]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Intercept = -0.812
Page 463 of 1261
Calibration / Trichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.066
Error Coefficients
Standard Error:724000
Relative Standard Error:4.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.003102 50.0 365516.0 2.006205 N
2 IC 280-628924/3 1.0 1.101763 50.0 358244.0 1.101763 Y
3 IC 280-628924/4 2.0 2.163275 50.0 350880.0 1.081638 Y
4 IC 280-628924/5 5.0 4.931298 50.0 365421.0 0.98626 Y
5 IC 280-628924/6 10.0 11.663272 50.0 352564.0 1.166327 Y
6 ICIS 280-628924/7 50.0 52.411134 50.0 360515.0 1.048223 Y
7 IC 280-628924/8 75.0 78.511433 50.0 375979.0 1.046819 Y
8 IC 280-628924/9 100.0 105.210464 50.0 366618.0 1.052105 Y
9 IC 280-628924/10 200.0 208.758252 50.0 384015.0 1.043791 Y
RelResp = [1.066]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 464 of 1261
Calibration / 2-Pentanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1832
Error Coefficients
Standard Error:1490000
Relative Standard Error:4.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 1.6 0.299022 50.0 1455245.0 0.186889 Y
2 IC 280-628924/3 3.2 0.621781 50.0 1404996.0 0.194307 Y
3 IC 280-628924/4 6.4 1.214894 50.0 1400163.0 0.189827 Y
4 IC 280-628924/5 16.0 2.778942 50.0 1443067.0 0.173684 Y
5 IC 280-628924/6 32.0 6.086668 50.0 1419389.0 0.190208 Y
6 ICIS 280-628924/7 160.0 28.80471 50.0 1502020.0 0.180029 Y
7 IC 280-628924/8 240.0 41.740231 50.0 1539686.0 0.173918 Y
8 IC 280-628924/9 320.0 59.257871 50.0 1509132.0 0.185181 Y
9 IC 280-628924/10 640.0 111.711308 50.0 1559275.0 0.174549 Y
RelResp = [0.1832]x
Concentration
0 100 200 300 400 500 600 700
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 465 of 1261
Calibration / Methylcyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3586
Error Coefficients
Standard Error:925000
Relative Standard Error:9.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.18557 50.0 1455245.0 0.37114 Y
2 IC 280-628924/3 1.0 0.439183 50.0 1404996.0 0.439183 Y
3 IC 280-628924/4 2.0 0.696455 50.0 1400163.0 0.348227 Y
4 IC 280-628924/5 5.0 1.584992 50.0 1443067.0 0.316998 Y
5 IC 280-628924/6 10.0 3.564985 50.0 1419389.0 0.356498 Y
6 ICIS 280-628924/7 50.0 17.062722 50.0 1502020.0 0.341254 Y
7 IC 280-628924/8 75.0 26.275877 50.0 1539686.0 0.350345 Y
8 IC 280-628924/9 100.0 35.351381 50.0 1509132.0 0.353514 Y
9 IC 280-628924/10 200.0 70.13192 50.0 1559275.0 0.35066 Y
RelResp = [0.3586]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 466 of 1261
Calibration / 1,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2764
Error Coefficients
Standard Error:736000
Relative Standard Error:6.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.126851 50.0 1455245.0 0.253703 Y
2 IC 280-628924/3 1.0 0.305944 50.0 1404996.0 0.305944 Y
3 IC 280-628924/4 2.0 0.554364 50.0 1400163.0 0.277182 Y
4 IC 280-628924/5 5.0 1.235632 50.0 1443067.0 0.247126 Y
5 IC 280-628924/6 10.0 2.964304 50.0 1419389.0 0.29643 Y
6 ICIS 280-628924/7 50.0 13.593894 50.0 1502020.0 0.271878 Y
7 IC 280-628924/8 75.0 20.85081 50.0 1539686.0 0.278011 Y
8 IC 280-628924/9 100.0 27.774443 50.0 1509132.0 0.277744 Y
9 IC 280-628924/10 200.0 55.902904 50.0 1559275.0 0.279515 Y
RelResp = [0.2764]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 467 of 1261
Calibration / 1,4-Dioxane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.003106
Error Coefficients
Standard Error:174000
Relative Standard Error:6.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 10.0 0.0 50.0 1455245.0 0.0 N
2 IC 280-628924/3 20.0 0.059715 50.0 1404996.0 0.002986 Y
3 IC 280-628924/4 40.0 0.109594 50.0 1400163.0 0.00274 Y
4 IC 280-628924/5 100.0 0.325834 50.0 1443067.0 0.003258 Y
5 IC 280-628924/6 200.0 0.684203 50.0 1419389.0 0.003421 Y
6 ICIS 280-628924/7 1000.0 3.075159 50.0 1502020.0 0.003075 Y
7 IC 280-628924/8 1500.0 4.626885 50.0 1539686.0 0.003085 Y
8 IC 280-628924/9 2000.0 6.464842 50.0 1509132.0 0.003232 Y
9 IC 280-628924/10 4000.0 12.218307 50.0 1559275.0 0.003055 Y
RelResp = [0.003106]x
Concentration
0 1000 2000 3000 4000
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 468 of 1261
Calibration / Dibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1459
Error Coefficients
Standard Error:402000
Relative Standard Error:4.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.093867 50.0 1455245.0 0.187735 N
2 IC 280-628924/3 1.0 0.155588 50.0 1404996.0 0.155588 Y
3 IC 280-628924/4 2.0 0.297323 50.0 1400163.0 0.148661 Y
4 IC 280-628924/5 5.0 0.699032 50.0 1443067.0 0.139806 Y
5 IC 280-628924/6 10.0 1.546687 50.0 1419389.0 0.154669 Y
6 ICIS 280-628924/7 50.0 7.022476 50.0 1502020.0 0.14045 Y
7 IC 280-628924/8 75.0 10.612618 50.0 1539686.0 0.141502 Y
8 IC 280-628924/9 100.0 14.44804 50.0 1509132.0 0.14448 Y
9 IC 280-628924/10 200.0 28.451428 50.0 1559275.0 0.142257 Y
RelResp = [0.1459]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 469 of 1261
Calibration / Dichlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.35
Error Coefficients
Standard Error:950000
Relative Standard Error:7.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.0 50.0 1455245.0 0.0 N
2 IC 280-628924/3 1.0 0.393631 50.0 1404996.0 0.393631 Y
3 IC 280-628924/4 2.0 0.764018 50.0 1400163.0 0.382009 Y
4 IC 280-628924/5 5.0 1.604084 50.0 1443067.0 0.320817 Y
5 IC 280-628924/6 10.0 3.622791 50.0 1419389.0 0.362279 Y
6 ICIS 280-628924/7 50.0 16.447584 50.0 1502020.0 0.328952 Y
7 IC 280-628924/8 75.0 25.112328 50.0 1539686.0 0.334831 Y
8 IC 280-628924/9 100.0 34.094566 50.0 1509132.0 0.340946 Y
9 IC 280-628924/10 200.0 67.31497 50.0 1559275.0 0.336575 Y
RelResp = [0.35]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 470 of 1261
Calibration / 2-Chloroethyl vinyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1632
Error Coefficients
Standard Error:480000
Relative Standard Error:6.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.304519 50.0 1455245.0 0.609038 N
2 IC 280-628924/3 1.0 0.156833 50.0 1404996.0 0.156833 Y
3 IC 280-628924/4 2.0 0.29643 50.0 1400163.0 0.148215 Y
4 IC 280-628924/5 5.0 0.732364 50.0 1443067.0 0.146473 Y
5 IC 280-628924/6 10.0 1.683365 50.0 1419389.0 0.168337 Y
6 ICIS 280-628924/7 50.0 8.665198 50.0 1502020.0 0.173304 Y
7 IC 280-628924/8 75.0 12.610948 50.0 1539686.0 0.168146 Y
8 IC 280-628924/9 100.0 17.547537 50.0 1509132.0 0.175475 Y
9 IC 280-628924/10 200.0 33.779898 50.0 1559275.0 0.168899 Y
RelResp = [0.1632]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 471 of 1261
Calibration / cis-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.739
Error Coefficients
Standard Error:1150000
Relative Standard Error:5.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.905022 50.0 365516.0 1.810044 Y
2 IC 280-628924/3 1.0 1.564297 50.0 358244.0 1.564297 Y
3 IC 280-628924/4 2.0 3.339603 50.0 350880.0 1.669802 Y
4 IC 280-628924/5 5.0 8.203962 50.0 365421.0 1.640792 Y
5 IC 280-628924/6 10.0 18.124085 50.0 352564.0 1.812409 Y
6 ICIS 280-628924/7 50.0 89.376448 50.0 360515.0 1.787529 Y
7 IC 280-628924/8 75.0 133.056368 50.0 375979.0 1.774085 Y
8 IC 280-628924/9 100.0 181.638381 50.0 366618.0 1.816384 Y
9 IC 280-628924/10 200.0 354.655547 50.0 384015.0 1.773278 Y
RelResp = [1.739]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 472 of 1261
Calibration / 4-Methyl-2-pentanone (MIBK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2432
Error Coefficients
Standard Error:2440000
Relative Standard Error:5.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 2.0 0.479816 50.0 1455245.0 0.239908 Y
2 IC 280-628924/3 4.0 1.065234 50.0 1404996.0 0.266309 Y
3 IC 280-628924/4 8.0 1.91567 50.0 1400163.0 0.239459 Y
4 IC 280-628924/5 20.0 4.855423 50.0 1443067.0 0.242771 Y
5 IC 280-628924/6 40.0 10.351074 50.0 1419389.0 0.258777 Y
6 ICIS 280-628924/7 200.0 47.986911 50.0 1502020.0 0.239935 Y
7 IC 280-628924/8 300.0 69.443867 50.0 1539686.0 0.23148 Y
8 IC 280-628924/9 400.0 97.043002 50.0 1509132.0 0.242608 Y
9 IC 280-628924/10 800.0 182.251271 50.0 1559275.0 0.227814 Y
RelResp = [0.2432]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 473 of 1261
Calibration / Toluene-d8 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:4.265
Error Coefficients
Standard Error:1650000
Relative Standard Error:1.2
Correlation Coefficient:NA
Coefficient of Determination (Adjusted):0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 50.0 211.120033 50.0 365516.0 4.222401 Y
2 IC 280-628924/3 50.0 211.480862 50.0 358244.0 4.229617 Y
3 IC 280-628924/4 50.0 214.03229 50.0 350880.0 4.280646 Y
4 IC 280-628924/5 50.0 209.22785 50.0 365421.0 4.184557 Y
5 IC 280-628924/6 50.0 213.962713 50.0 352564.0 4.279254 Y
6 ICIS 280-628924/7 50.0 217.96125 50.0 360515.0 4.359225 Y
7 IC 280-628924/8 50.0 212.830504 50.0 375979.0 4.25661 Y
8 IC 280-628924/9 50.0 215.808826 50.0 366618.0 4.316177 Y
9 IC 280-628924/10 50.0 212.94702 50.0 384015.0 4.25894 Y
RelResp = [4.265]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/4IC 280-628924/6ICIS 280-628924/7IC 280-628924/9
Page 474 of 1261
Calibration / Toluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.13
Error Coefficients
Standard Error:2840000
Relative Standard Error:6.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.58193 50.0 1455245.0 1.163859 Y
2 IC 280-628924/3 1.0 1.240253 50.0 1404996.0 1.240253 Y
3 IC 280-628924/4 2.0 2.280556 50.0 1400163.0 1.140278 Y
4 IC 280-628924/5 5.0 5.293275 50.0 1443067.0 1.058655 Y
5 IC 280-628924/6 10.0 12.335907 50.0 1419389.0 1.233591 Y
6 ICIS 280-628924/7 50.0 53.89116 50.0 1502020.0 1.077823 Y
7 IC 280-628924/8 75.0 82.480714 50.0 1539686.0 1.099743 Y
8 IC 280-628924/9 100.0 108.787634 50.0 1509132.0 1.087876 Y
9 IC 280-628924/10 200.0 213.860672 50.0 1559275.0 1.069303 Y
RelResp = [1.13]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 475 of 1261
Calibration / trans-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3933
Error Coefficients
Standard Error:1050000
Relative Standard Error:3.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.192407 50.0 1455245.0 0.384815 Y
2 IC 280-628924/3 1.0 0.395766 50.0 1404996.0 0.395766 Y
3 IC 280-628924/4 2.0 0.760411 50.0 1400163.0 0.380206 Y
4 IC 280-628924/5 5.0 1.844093 50.0 1443067.0 0.368819 Y
5 IC 280-628924/6 10.0 4.151892 50.0 1419389.0 0.415189 Y
6 ICIS 280-628924/7 50.0 19.724038 50.0 1502020.0 0.394481 Y
7 IC 280-628924/8 75.0 29.903175 50.0 1539686.0 0.398709 Y
8 IC 280-628924/9 100.0 40.473961 50.0 1509132.0 0.40474 Y
9 IC 280-628924/10 200.0 79.330618 50.0 1559275.0 0.396653 Y
RelResp = [0.3933]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 476 of 1261
Calibration / Ethyl methacrylate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.358
Error Coefficients
Standard Error:891000
Relative Standard Error:7.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.938126 50.0 365516.0 1.876252 N
2 IC 280-628924/3 1.0 1.519914 50.0 358244.0 1.519914 Y
3 IC 280-628924/4 2.0 2.839432 50.0 350880.0 1.419716 Y
4 IC 280-628924/5 5.0 6.183689 50.0 365421.0 1.236738 Y
5 IC 280-628924/6 10.0 14.41951 50.0 352564.0 1.441951 Y
6 ICIS 280-628924/7 50.0 67.209686 50.0 360515.0 1.344194 Y
7 IC 280-628924/8 75.0 96.195133 50.0 375979.0 1.282602 Y
8 IC 280-628924/9 100.0 134.574816 50.0 366618.0 1.345748 Y
9 IC 280-628924/10 200.0 254.307384 50.0 384015.0 1.271537 Y
RelResp = [1.358]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 477 of 1261
Calibration / 1,1,2-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2177
Error Coefficients
Standard Error:590000
Relative Standard Error:7.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.177599 50.0 1455245.0 0.355198 N
2 IC 280-628924/3 1.0 0.215339 50.0 1404996.0 0.215339 Y
3 IC 280-628924/4 2.0 0.513226 50.0 1400163.0 0.256613 Y
4 IC 280-628924/5 5.0 1.016308 50.0 1443067.0 0.203262 Y
5 IC 280-628924/6 10.0 2.275627 50.0 1419389.0 0.227563 Y
6 ICIS 280-628924/7 50.0 10.459282 50.0 1502020.0 0.209186 Y
7 IC 280-628924/8 75.0 15.668844 50.0 1539686.0 0.208918 Y
8 IC 280-628924/9 100.0 21.21385 50.0 1509132.0 0.212139 Y
9 IC 280-628924/10 200.0 41.718747 50.0 1559275.0 0.208594 Y
RelResp = [0.2177]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 478 of 1261
Calibration / Tetrachloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8002
Error Coefficients
Standard Error:575000
Relative Standard Error:6.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.252793 50.0 365516.0 0.505587 N
2 IC 280-628924/3 1.0 0.724087 50.0 358244.0 0.724087 Y
3 IC 280-628924/4 2.0 1.478853 50.0 350880.0 0.739427 Y
4 IC 280-628924/5 5.0 3.745816 50.0 365421.0 0.749163 Y
5 IC 280-628924/6 10.0 8.654741 50.0 352564.0 0.865474 Y
6 ICIS 280-628924/7 50.0 40.310528 50.0 360515.0 0.806211 Y
7 IC 280-628924/8 75.0 63.00937 50.0 375979.0 0.840125 Y
8 IC 280-628924/9 100.0 84.958322 50.0 366618.0 0.849583 Y
9 IC 280-628924/10 200.0 165.485593 50.0 384015.0 0.827428 Y
RelResp = [0.8002]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6 ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 479 of 1261
Calibration / 1,3-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.547
Error Coefficients
Standard Error:1010000
Relative Standard Error:5.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.80954 50.0 365516.0 1.619081 Y
2 IC 280-628924/3 1.0 1.563041 50.0 358244.0 1.563041 Y
3 IC 280-628924/4 2.0 2.763765 50.0 350880.0 1.381883 Y
4 IC 280-628924/5 5.0 7.089631 50.0 365421.0 1.417926 Y
5 IC 280-628924/6 10.0 16.493601 50.0 352564.0 1.64936 Y
6 ICIS 280-628924/7 50.0 79.105585 50.0 360515.0 1.582112 Y
7 IC 280-628924/8 75.0 116.214469 50.0 375979.0 1.549526 Y
8 IC 280-628924/9 100.0 160.750018 50.0 366618.0 1.6075 Y
9 IC 280-628924/10 200.0 310.632918 50.0 384015.0 1.553165 Y
RelResp = [1.547]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 480 of 1261
Calibration / 2-Hexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7018
Error Coefficients
Standard Error:1700000
Relative Standard Error:8.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.990
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 2.0 1.663675 50.0 365516.0 0.831838 Y
2 IC 280-628924/3 4.0 2.832846 50.0 358244.0 0.708211 Y
3 IC 280-628924/4 8.0 5.35639 50.0 350880.0 0.669549 Y
4 IC 280-628924/5 20.0 13.018683 50.0 365421.0 0.650934 Y
5 IC 280-628924/6 40.0 30.310951 50.0 352564.0 0.757774 Y
6 ICIS 280-628924/7 200.0 139.880587 50.0 360515.0 0.699403 Y
7 IC 280-628924/8 300.0 197.821288 50.0 375979.0 0.659404 Y
8 IC 280-628924/9 400.0 278.586976 50.0 366618.0 0.696467 Y
9 IC 280-628924/10 800.0 513.936695 50.0 384015.0 0.642421 Y
RelResp = [0.7018]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 481 of 1261
Calibration / Chlorodibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.049
Error Coefficients
Standard Error:659000
Relative Standard Error:8.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.509827 50.0 365516.0 1.019654 Y
2 IC 280-628924/3 1.0 1.234215 50.0 358244.0 1.234215 Y
3 IC 280-628924/4 2.0 2.146888 50.0 350880.0 1.073444 Y
4 IC 280-628924/5 5.0 4.622887 50.0 365421.0 0.924577 Y
5 IC 280-628924/6 10.0 10.962407 50.0 352564.0 1.096241 Y
6 ICIS 280-628924/7 50.0 51.290376 50.0 360515.0 1.025808 Y
7 IC 280-628924/8 75.0 75.932964 50.0 375979.0 1.01244 Y
8 IC 280-628924/9 100.0 104.332166 50.0 366618.0 1.043322 Y
9 IC 280-628924/10 200.0 202.587529 50.0 384015.0 1.012938 Y
RelResp = [1.049]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 482 of 1261
Calibration / Ethylene Dibromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8974
Error Coefficients
Standard Error:606000
Relative Standard Error:5.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.576993 50.0 365516.0 1.153985 N
2 IC 280-628924/3 1.0 0.940839 50.0 358244.0 0.940839 Y
3 IC 280-628924/4 2.0 1.860323 50.0 350880.0 0.930161 Y
4 IC 280-628924/5 5.0 4.041776 50.0 365421.0 0.808355 Y
5 IC 280-628924/6 10.0 9.68193 50.0 352564.0 0.968193 Y
6 ICIS 280-628924/7 50.0 44.493849 50.0 360515.0 0.889877 Y
7 IC 280-628924/8 75.0 65.092066 50.0 375979.0 0.867894 Y
8 IC 280-628924/9 100.0 90.532789 50.0 366618.0 0.905328 Y
9 IC 280-628924/10 200.0 173.64504 50.0 384015.0 0.868225 Y
RelResp = [0.8974]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 483 of 1261
Calibration / 1-Chlorohexane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.6665
Slope:1.438
Error Coefficients
Standard Error:861000
Relative Standard Error:2.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.4 0.763715 50.0 365516.0 1.909287 N
2 IC 280-628924/3 0.8 1.820547 50.0 358244.0 2.275684 Y
3 IC 280-628924/4 1.6 2.983071 50.0 350880.0 1.864419 Y
4 IC 280-628924/5 4.0 6.106381 50.0 365421.0 1.526595 Y
5 IC 280-628924/6 8.0 12.649618 50.0 352564.0 1.581202 Y
6 ICIS 280-628924/7 40.0 57.598297 50.0 360515.0 1.439957 Y
7 IC 280-628924/8 60.0 87.204737 50.0 375979.0 1.453412 Y
8 IC 280-628924/9 80.0 117.610156 50.0 366618.0 1.470127 Y
9 IC 280-628924/10 160.0 229.087926 50.0 384015.0 1.4318 Y
RelResp = [0.6665] + [1.438]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Intercept = -0.464
Page 484 of 1261
Calibration / Chlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.813
Error Coefficients
Standard Error:1750000
Relative Standard Error:6.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.523463 50.0 365516.0 3.046925 Y
2 IC 280-628924/3 1.0 2.99042 50.0 358244.0 2.99042 Y
3 IC 280-628924/4 2.0 5.686987 50.0 350880.0 2.843494 Y
4 IC 280-628924/5 5.0 12.499145 50.0 365421.0 2.499829 Y
5 IC 280-628924/6 10.0 30.093118 50.0 352564.0 3.009312 Y
6 ICIS 280-628924/7 50.0 137.146582 50.0 360515.0 2.742932 Y
7 IC 280-628924/8 75.0 206.186649 50.0 375979.0 2.749155 Y
8 IC 280-628924/9 100.0 275.18207 50.0 366618.0 2.751821 Y
9 IC 280-628924/10 200.0 536.045207 50.0 384015.0 2.680226 Y
RelResp = [2.813]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 485 of 1261
Calibration / 1,1,1,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9644
Error Coefficients
Standard Error:637000
Relative Standard Error:5.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.442525 50.0 365516.0 0.88505 Y
2 IC 280-628924/3 1.0 1.012438 50.0 358244.0 1.012438 Y
3 IC 280-628924/4 2.0 1.826265 50.0 350880.0 0.913133 Y
4 IC 280-628924/5 5.0 4.470186 50.0 365421.0 0.894037 Y
5 IC 280-628924/6 10.0 10.404494 50.0 352564.0 1.040449 Y
6 ICIS 280-628924/7 50.0 48.848037 50.0 360515.0 0.976961 Y
7 IC 280-628924/8 75.0 73.723798 50.0 375979.0 0.982984 Y
8 IC 280-628924/9 100.0 99.200939 50.0 366618.0 0.992009 Y
9 IC 280-628924/10 200.0 196.515501 50.0 384015.0 0.982578 Y
RelResp = [0.9644]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 486 of 1261
Calibration / Ethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.574
Error Coefficients
Standard Error:1000000
Relative Standard Error:6.1
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.833206 50.0 365516.0 1.666411 Y
2 IC 280-628924/3 1.0 1.694515 50.0 358244.0 1.694515 Y
3 IC 280-628924/4 2.0 3.10733 50.0 350880.0 1.553665 Y
4 IC 280-628924/5 5.0 6.955813 50.0 365421.0 1.391163 Y
5 IC 280-628924/6 10.0 16.880198 50.0 352564.0 1.68802 Y
6 ICIS 280-628924/7 50.0 76.584053 50.0 360515.0 1.531681 Y
7 IC 280-628924/8 75.0 115.755002 50.0 375979.0 1.5434 Y
8 IC 280-628924/9 100.0 155.149093 50.0 366618.0 1.551491 Y
9 IC 280-628924/10 200.0 309.781649 50.0 384015.0 1.548908 Y
RelResp = [1.574]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 487 of 1261
Calibration / m-Xylene & p-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.888
Error Coefficients
Standard Error:1240000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.919932 50.0 365516.0 1.839865 Y
2 IC 280-628924/3 1.0 1.676651 50.0 358244.0 1.676651 Y
3 IC 280-628924/4 2.0 3.854309 50.0 350880.0 1.927155 Y
4 IC 280-628924/5 5.0 8.792461 50.0 365421.0 1.758492 Y
5 IC 280-628924/6 10.0 20.572435 50.0 352564.0 2.057244 Y
6 ICIS 280-628924/7 50.0 96.04538 50.0 360515.0 1.920908 Y
7 IC 280-628924/8 75.0 146.244072 50.0 375979.0 1.949921 Y
8 IC 280-628924/9 100.0 194.602011 50.0 366618.0 1.94602 Y
9 IC 280-628924/10 200.0 382.903793 50.0 384015.0 1.914519 Y
RelResp = [1.888]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 488 of 1261
Calibration / o-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.913
Error Coefficients
Standard Error:1220000
Relative Standard Error:4.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.015277 50.0 365516.0 2.030554 Y
2 IC 280-628924/3 1.0 1.914617 50.0 358244.0 1.914617 Y
3 IC 280-628924/4 2.0 3.788332 50.0 350880.0 1.894166 Y
4 IC 280-628924/5 5.0 8.779873 50.0 365421.0 1.755975 Y
5 IC 280-628924/6 10.0 20.487486 50.0 352564.0 2.048749 Y
6 ICIS 280-628924/7 50.0 95.982414 50.0 360515.0 1.919648 Y
7 IC 280-628924/8 75.0 141.173709 50.0 375979.0 1.882316 Y
8 IC 280-628924/9 100.0 190.487647 50.0 366618.0 1.904876 Y
9 IC 280-628924/10 200.0 373.68332 50.0 384015.0 1.868417 Y
RelResp = [1.913]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 489 of 1261
Calibration / Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.234
Error Coefficients
Standard Error:2040000
Relative Standard Error:4.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.695411 50.0 365516.0 3.390823 Y
2 IC 280-628924/3 1.0 3.117289 50.0 358244.0 3.117289 Y
3 IC 280-628924/4 2.0 6.722384 50.0 350880.0 3.361192 Y
4 IC 280-628924/5 5.0 14.891317 50.0 365421.0 2.978263 Y
5 IC 280-628924/6 10.0 34.873243 50.0 352564.0 3.487324 Y
6 ICIS 280-628924/7 50.0 160.972498 50.0 360515.0 3.21945 Y
7 IC 280-628924/8 75.0 241.809649 50.0 375979.0 3.224129 Y
8 IC 280-628924/9 100.0 319.905733 50.0 366618.0 3.199057 Y
9 IC 280-628924/10 200.0 626.240121 50.0 384015.0 3.131201 Y
RelResp = [3.234]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 490 of 1261
Calibration / Bromoform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7003
Error Coefficients
Standard Error:458000
Relative Standard Error:6.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.343213 50.0 365516.0 0.686427 Y
2 IC 280-628924/3 1.0 0.648022 50.0 358244.0 0.648022 Y
3 IC 280-628924/4 2.0 1.335072 50.0 350880.0 0.667536 Y
4 IC 280-628924/5 5.0 3.253781 50.0 365421.0 0.650756 Y
5 IC 280-628924/6 10.0 7.886511 50.0 352564.0 0.788651 Y
6 ICIS 280-628924/7 50.0 36.265481 50.0 360515.0 0.72531 Y
7 IC 280-628924/8 75.0 52.947771 50.0 375979.0 0.70597 Y
8 IC 280-628924/9 100.0 72.860307 50.0 366618.0 0.728603 Y
9 IC 280-628924/10 200.0 140.227074 50.0 384015.0 0.701135 Y
RelResp = [0.7003]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6 ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 491 of 1261
Calibration / Isopropylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.804
Error Coefficients
Standard Error:3050000
Relative Standard Error:6.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.293211 50.0 618886.0 2.586421 Y
2 IC 280-628924/3 1.0 3.022677 50.0 598840.0 3.022677 Y
3 IC 280-628924/4 2.0 5.674351 50.0 598835.0 2.837176 Y
4 IC 280-628924/5 5.0 12.716004 50.0 623773.0 2.543201 Y
5 IC 280-628924/6 10.0 30.959716 50.0 595926.0 3.095972 Y
6 ICIS 280-628924/7 50.0 138.073586 50.0 627238.0 2.761472 Y
7 IC 280-628924/8 75.0 211.918205 50.0 639895.0 2.825576 Y
8 IC 280-628924/9 100.0 283.580398 50.0 623453.0 2.835804 Y
9 IC 280-628924/10 200.0 544.692633 50.0 659131.0 2.723463 Y
RelResp = [2.804]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 492 of 1261
Calibration / Cyclohexanone
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.3665
Slope:0.04564
Error Coefficients
Standard Error:931000
Relative Standard Error:10.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 15.0 1.084494 50.0 365516.0 0.0723 Y
2 IC 280-628924/3 30.0 1.596398 50.0 358244.0 0.053213 Y
3 IC 280-628924/4 60.0 2.613714 50.0 350880.0 0.043562 Y
4 IC 280-628924/5 150.0 7.309241 50.0 365421.0 0.048728 Y
5 IC 280-628924/6 300.0 16.322852 50.0 352564.0 0.05441 Y
6 ICIS 280-628924/7 1500.0 72.821381 50.0 360515.0 0.048548 Y
7 IC 280-628924/8 2250.0 100.752436 50.0 375979.0 0.044779 Y
8 IC 280-628924/9 3000.0 145.264826 50.0 366618.0 0.048422 Y
9 IC 280-628924/10 6000.0 262.746507 50.0 384015.0 0.043791 Y
RelResp = [0.3665] + [0.04564]x
Concentration
0 1000 2000 3000 4000 5000 6000
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Intercept = -8.03
Page 493 of 1261
Calibration / 4-Bromofluorobenzene (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9294
Error Coefficients
Standard Error:612000
Relative Standard Error:0.7
Correlation Coefficient:NA
Coefficient of Determination (Adjusted):0.000000000000000222
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 50.0 46.37405 50.0 618886.0 0.927481 Y
2 IC 280-628924/3 50.0 46.898671 50.0 598840.0 0.937973 Y
3 IC 280-628924/4 50.0 46.202877 50.0 598835.0 0.924058 Y
4 IC 280-628924/5 50.0 46.152927 50.0 623773.0 0.923059 Y
5 IC 280-628924/6 50.0 46.602514 50.0 595926.0 0.93205 Y
6 ICIS 280-628924/7 50.0 46.312405 50.0 627238.0 0.926248 Y
7 IC 280-628924/8 50.0 46.690473 50.0 639895.0 0.933809 Y
8 IC 280-628924/9 50.0 46.902252 50.0 623453.0 0.938045 Y
9 IC 280-628924/10 50.0 46.090989 50.0 659131.0 0.92182 Y
RelResp = [0.9294]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/3IC 280-628924/6IC 280-628924/8IC 280-628924/9
Page 494 of 1261
Calibration / 1,1,2,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6564
Error Coefficients
Standard Error:771000
Relative Standard Error:6.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.48248 50.0 618886.0 0.96496 N
2 IC 280-628924/3 1.0 0.618696 50.0 598840.0 0.618696 Y
3 IC 280-628924/4 2.0 1.251179 50.0 598835.0 0.62559 Y
4 IC 280-628924/5 5.0 3.098323 50.0 623773.0 0.619665 Y
5 IC 280-628924/6 10.0 7.480543 50.0 595926.0 0.748054 Y
6 ICIS 280-628924/7 50.0 33.303706 50.0 627238.0 0.666074 Y
7 IC 280-628924/8 75.0 48.664234 50.0 639895.0 0.648856 Y
8 IC 280-628924/9 100.0 68.238985 50.0 623453.0 0.68239 Y
9 IC 280-628924/10 200.0 128.335718 50.0 659131.0 0.641679 Y
RelResp = [0.6564]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 495 of 1261
Calibration / trans-1,4-Dichloro-2-butene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1142
Slope:0.2296
Error Coefficients
Standard Error:263000
Relative Standard Error:8.3
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.233807 50.0 618886.0 0.467614 Y
2 IC 280-628924/3 1.0 0.316612 50.0 598840.0 0.316612 Y
3 IC 280-628924/4 2.0 0.600666 50.0 598835.0 0.300333 Y
4 IC 280-628924/5 5.0 1.206288 50.0 623773.0 0.241258 Y
5 IC 280-628924/6 10.0 2.733729 50.0 595926.0 0.273373 Y
6 ICIS 280-628924/7 50.0 11.436409 50.0 627238.0 0.228728 Y
7 IC 280-628924/8 75.0 16.529665 50.0 639895.0 0.220396 Y
8 IC 280-628924/9 100.0 23.992025 50.0 623453.0 0.23992 Y
9 IC 280-628924/10 200.0 43.424752 50.0 659131.0 0.217124 Y
RelResp = [0.1142] + [0.2296]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Intercept = -0.497
Page 496 of 1261
Calibration / Bromobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6525
Error Coefficients
Standard Error:755000
Relative Standard Error:8.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.265315 50.0 618886.0 0.530631 Y
2 IC 280-628924/3 1.0 0.628549 50.0 598840.0 0.628549 Y
3 IC 280-628924/4 2.0 1.294764 50.0 598835.0 0.647382 Y
4 IC 280-628924/5 5.0 3.108823 50.0 623773.0 0.621765 Y
5 IC 280-628924/6 10.0 7.299648 50.0 595926.0 0.729965 Y
6 ICIS 280-628924/7 50.0 33.007248 50.0 627238.0 0.660145 Y
7 IC 280-628924/8 75.0 51.494933 50.0 639895.0 0.686599 Y
8 IC 280-628924/9 100.0 68.844965 50.0 623453.0 0.68845 Y
9 IC 280-628924/10 200.0 135.845378 50.0 659131.0 0.679227 Y
RelResp = [0.6525]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6 ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 497 of 1261
Calibration / 1,2,3-Trichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1997
Error Coefficients
Standard Error:228000
Relative Standard Error:9.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.082406 50.0 618886.0 0.164812 N
2 IC 280-628924/3 1.0 0.229694 50.0 598840.0 0.229694 Y
3 IC 280-628924/4 2.0 0.367881 50.0 598835.0 0.18394 Y
4 IC 280-628924/5 5.0 0.890628 50.0 623773.0 0.178126 Y
5 IC 280-628924/6 10.0 2.269913 50.0 595926.0 0.226991 Y
6 ICIS 280-628924/7 50.0 9.806246 50.0 627238.0 0.196125 Y
7 IC 280-628924/8 75.0 14.545355 50.0 639895.0 0.193938 Y
8 IC 280-628924/9 100.0 19.766045 50.0 623453.0 0.19766 Y
9 IC 280-628924/10 200.0 38.150155 50.0 659131.0 0.190751 Y
RelResp = [0.1997]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 498 of 1261
Calibration / N-Propylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7813
Error Coefficients
Standard Error:857000
Relative Standard Error:5.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.383916 50.0 618886.0 0.767831 Y
2 IC 280-628924/3 1.0 0.837118 50.0 598840.0 0.837118 Y
3 IC 280-628924/4 2.0 1.494652 50.0 598835.0 0.747326 Y
4 IC 280-628924/5 5.0 3.622792 50.0 623773.0 0.724558 Y
5 IC 280-628924/6 10.0 8.604508 50.0 595926.0 0.860451 Y
6 ICIS 280-628924/7 50.0 38.053737 50.0 627238.0 0.761075 Y
7 IC 280-628924/8 75.0 58.164074 50.0 639895.0 0.775521 Y
8 IC 280-628924/9 100.0 78.767525 50.0 623453.0 0.787675 Y
9 IC 280-628924/10 200.0 154.031293 50.0 659131.0 0.770156 Y
RelResp = [0.7813]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 499 of 1261
Calibration / 2-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6498
Error Coefficients
Standard Error:720000
Relative Standard Error:5.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.327766 50.0 618886.0 0.655533 Y
2 IC 280-628924/3 1.0 0.671465 50.0 598840.0 0.671465 Y
3 IC 280-628924/4 2.0 1.3649 50.0 598835.0 0.68245 Y
4 IC 280-628924/5 5.0 2.844464 50.0 623773.0 0.568893 Y
5 IC 280-628924/6 10.0 6.960931 50.0 595926.0 0.696093 Y
6 ICIS 280-628924/7 50.0 31.330053 50.0 627238.0 0.626601 Y
7 IC 280-628924/8 75.0 48.48983 50.0 639895.0 0.646531 Y
8 IC 280-628924/9 100.0 65.055104 50.0 623453.0 0.650551 Y
9 IC 280-628924/10 200.0 130.01725 50.0 659131.0 0.650086 Y
RelResp = [0.6498]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
IC 280-628924/10
Page 500 of 1261
Calibration / 1,3,5-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.405
Error Coefficients
Standard Error:2610000
Relative Standard Error:5.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.237627 50.0 618886.0 2.475254 Y
2 IC 280-628924/3 1.0 2.312053 50.0 598840.0 2.312053 Y
3 IC 280-628924/4 2.0 4.948525 50.0 598835.0 2.474263 Y
4 IC 280-628924/5 5.0 10.982681 50.0 623773.0 2.196536 Y
5 IC 280-628924/6 10.0 26.59701 50.0 595926.0 2.659701 Y
6 ICIS 280-628924/7 50.0 118.288353 50.0 627238.0 2.365767 Y
7 IC 280-628924/8 75.0 180.206049 50.0 639895.0 2.402747 Y
8 IC 280-628924/9 100.0 243.511941 50.0 623453.0 2.435119 Y
9 IC 280-628924/10 200.0 464.457521 50.0 659131.0 2.322288 Y
RelResp = [2.405]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 501 of 1261
Calibration / 4-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6823
Error Coefficients
Standard Error:749000
Relative Standard Error:6.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.371635 50.0 618886.0 0.743271 Y
2 IC 280-628924/3 1.0 0.678395 50.0 598840.0 0.678395 Y
3 IC 280-628924/4 2.0 1.282407 50.0 598835.0 0.641203 Y
4 IC 280-628924/5 5.0 3.12261 50.0 623773.0 0.624522 Y
5 IC 280-628924/6 10.0 7.482053 50.0 595926.0 0.748205 Y
6 ICIS 280-628924/7 50.0 33.059939 50.0 627238.0 0.661199 Y
7 IC 280-628924/8 75.0 51.173239 50.0 639895.0 0.68231 Y
8 IC 280-628924/9 100.0 68.913294 50.0 623453.0 0.689133 Y
9 IC 280-628924/10 200.0 134.51408 50.0 659131.0 0.67257 Y
RelResp = [0.6823]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 502 of 1261
Calibration / tert-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.063
Error Coefficients
Standard Error:2210000
Relative Standard Error:6.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.175499 50.0 618886.0 2.350998 Y
2 IC 280-628924/3 1.0 2.132957 50.0 598840.0 2.132957 Y
3 IC 280-628924/4 2.0 4.14438 50.0 598835.0 2.07219 Y
4 IC 280-628924/5 5.0 9.259779 50.0 623773.0 1.851956 Y
5 IC 280-628924/6 10.0 21.554102 50.0 595926.0 2.15541 Y
6 ICIS 280-628924/7 50.0 98.081031 50.0 627238.0 1.961621 Y
7 IC 280-628924/8 75.0 152.374686 50.0 639895.0 2.031662 Y
8 IC 280-628924/9 100.0 203.302815 50.0 623453.0 2.033028 Y
9 IC 280-628924/10 200.0 396.290419 50.0 659131.0 1.981452 Y
RelResp = [2.063]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 503 of 1261
Calibration / 1,2,4-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.494
Error Coefficients
Standard Error:2700000
Relative Standard Error:5.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.312439 50.0 618886.0 2.624878 Y
2 IC 280-628924/3 1.0 2.428528 50.0 598840.0 2.428528 Y
3 IC 280-628924/4 2.0 5.096729 50.0 598835.0 2.548365 Y
4 IC 280-628924/5 5.0 11.223634 50.0 623773.0 2.244727 Y
5 IC 280-628924/6 10.0 27.246755 50.0 595926.0 2.724676 Y
6 ICIS 280-628924/7 50.0 121.718391 50.0 627238.0 2.434368 Y
7 IC 280-628924/8 75.0 188.183999 50.0 639895.0 2.50912 Y
8 IC 280-628924/9 100.0 252.628105 50.0 623453.0 2.526281 Y
9 IC 280-628924/10 200.0 480.454113 50.0 659131.0 2.402271 Y
RelResp = [2.494]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 504 of 1261
Calibration / sec-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5627
Error Coefficients
Standard Error:646000
Relative Standard Error:8.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.24431 50.0 618886.0 0.48862 Y
2 IC 280-628924/3 1.0 0.584714 50.0 598840.0 0.584714 Y
3 IC 280-628924/4 2.0 1.042608 50.0 598835.0 0.521304 Y
4 IC 280-628924/5 5.0 2.556218 50.0 623773.0 0.511244 Y
5 IC 280-628924/6 10.0 6.282324 50.0 595926.0 0.628232 Y
6 ICIS 280-628924/7 50.0 28.378383 50.0 627238.0 0.567568 Y
7 IC 280-628924/8 75.0 43.959165 50.0 639895.0 0.586122 Y
8 IC 280-628924/9 100.0 59.681564 50.0 623453.0 0.596816 Y
9 IC 280-628924/10 200.0 115.916563 50.0 659131.0 0.579583 Y
RelResp = [0.5627]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 505 of 1261
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.238
Error Coefficients
Standard Error:1430000
Relative Standard Error:9.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.990
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.489428 50.0 618886.0 0.978856 Y
2 IC 280-628924/3 1.0 1.254843 50.0 598840.0 1.254843 Y
3 IC 280-628924/4 2.0 2.448504 50.0 598835.0 1.224252 Y
4 IC 280-628924/5 5.0 5.81197 50.0 623773.0 1.162394 Y
5 IC 280-628924/6 10.0 13.786024 50.0 595926.0 1.378602 Y
6 ICIS 280-628924/7 50.0 62.321878 50.0 627238.0 1.246438 Y
7 IC 280-628924/8 75.0 98.084842 50.0 639895.0 1.307798 Y
8 IC 280-628924/9 100.0 130.886771 50.0 623453.0 1.308868 Y
9 IC 280-628924/10 200.0 255.977264 50.0 659131.0 1.279886 Y
RelResp = [1.238]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/10
Page 506 of 1261
Calibration / 4-Isopropyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.569
Error Coefficients
Standard Error:2770000
Relative Standard Error:5.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.364387 50.0 618886.0 2.728774 Y
2 IC 280-628924/3 1.0 2.665988 50.0 598840.0 2.665988 Y
3 IC 280-628924/4 2.0 5.015071 50.0 598835.0 2.507535 Y
4 IC 280-628924/5 5.0 11.703136 50.0 623773.0 2.340627 Y
5 IC 280-628924/6 10.0 27.738679 50.0 595926.0 2.773868 Y
6 ICIS 280-628924/7 50.0 124.038324 50.0 627238.0 2.480766 Y
7 IC 280-628924/8 75.0 192.046742 50.0 639895.0 2.560623 Y
8 IC 280-628924/9 100.0 258.371682 50.0 623453.0 2.583717 Y
9 IC 280-628924/10 200.0 495.211422 50.0 659131.0 2.476057 Y
RelResp = [2.569]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 507 of 1261
Calibration / 1,4-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.291
Error Coefficients
Standard Error:1440000
Relative Standard Error:5.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.619015 50.0 618886.0 1.238031 Y
2 IC 280-628924/3 1.0 1.28106 50.0 598840.0 1.28106 Y
3 IC 280-628924/4 2.0 2.55972 50.0 598835.0 1.27986 Y
4 IC 280-628924/5 5.0 5.883551 50.0 623773.0 1.17671 Y
5 IC 280-628924/6 10.0 14.34507 50.0 595926.0 1.434507 Y
6 ICIS 280-628924/7 50.0 64.102781 50.0 627238.0 1.282056 Y
7 IC 280-628924/8 75.0 98.824417 50.0 639895.0 1.317659 Y
8 IC 280-628924/9 100.0 132.118861 50.0 623453.0 1.321189 Y
9 IC 280-628924/10 200.0 257.624736 50.0 659131.0 1.288124 Y
RelResp = [1.291]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 508 of 1261
Calibration / n-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.278
Error Coefficients
Standard Error:2470000
Relative Standard Error:5.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 1.145445 50.0 618886.0 2.29089 Y
2 IC 280-628924/3 1.0 2.329504 50.0 598840.0 2.329504 Y
3 IC 280-628924/4 2.0 4.766755 50.0 598835.0 2.383378 Y
4 IC 280-628924/5 5.0 10.188723 50.0 623773.0 2.037745 Y
5 IC 280-628924/6 10.0 24.483073 50.0 595926.0 2.448307 Y
6 ICIS 280-628924/7 50.0 110.703114 50.0 627238.0 2.214062 Y
7 IC 280-628924/8 75.0 171.304355 50.0 639895.0 2.284058 Y
8 IC 280-628924/9 100.0 231.295864 50.0 623453.0 2.312959 Y
9 IC 280-628924/10 200.0 440.041357 50.0 659131.0 2.200207 Y
RelResp = [2.278]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 509 of 1261
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.19
Error Coefficients
Standard Error:1330000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.5888 50.0 618886.0 1.1776 Y
2 IC 280-628924/3 1.0 1.190802 50.0 598840.0 1.190802 Y
3 IC 280-628924/4 2.0 2.287024 50.0 598835.0 1.143512 Y
4 IC 280-628924/5 5.0 5.2875 50.0 623773.0 1.0575 Y
5 IC 280-628924/6 10.0 13.269013 50.0 595926.0 1.326901 Y
6 ICIS 280-628924/7 50.0 59.117671 50.0 627238.0 1.182353 Y
7 IC 280-628924/8 75.0 90.493831 50.0 639895.0 1.206584 Y
8 IC 280-628924/9 100.0 123.583574 50.0 623453.0 1.235836 Y
9 IC 280-628924/10 200.0 237.644414 50.0 659131.0 1.188222 Y
RelResp = [1.19]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 510 of 1261
Calibration / 1,2-Dibromo-3-Chloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1545
Error Coefficients
Standard Error:204000
Relative Standard Error:9.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.986
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.056876 50.0 618886.0 0.113753 N
2 IC 280-628924/3 1.0 0.061786 50.0 598840.0 0.061786 N
3 IC 280-628924/4 2.0 0.244391 50.0 598835.0 0.122196 N
4 IC 280-628924/5 5.0 0.741776 50.0 623773.0 0.148355 Y
5 IC 280-628924/6 10.0 1.839406 50.0 595926.0 0.183941 Y
6 ICIS 280-628924/7 50.0 7.521786 50.0 627238.0 0.150436 Y
7 IC 280-628924/8 75.0 10.880926 50.0 639895.0 0.145079 Y
8 IC 280-628924/9 100.0 15.634859 50.0 623453.0 0.156349 Y
9 IC 280-628924/10 200.0 28.578537 50.0 659131.0 0.142893 Y
RelResp = [0.1545]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 511 of 1261
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.709
Error Coefficients
Standard Error:797000
Relative Standard Error:6.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.350226 50.0 618886.0 0.700452 Y
2 IC 280-628924/3 1.0 0.647669 50.0 598840.0 0.647669 Y
3 IC 280-628924/4 2.0 1.3649 50.0 598835.0 0.68245 Y
4 IC 280-628924/5 5.0 3.275551 50.0 623773.0 0.65511 Y
5 IC 280-628924/6 10.0 7.93622 50.0 595926.0 0.793622 Y
6 ICIS 280-628924/7 50.0 35.009598 50.0 627238.0 0.700192 Y
7 IC 280-628924/8 75.0 55.066691 50.0 639895.0 0.734223 Y
8 IC 280-628924/9 100.0 75.816942 50.0 623453.0 0.758169 Y
9 IC 280-628924/10 200.0 141.767115 50.0 659131.0 0.708836 Y
RelResp = [0.709]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 512 of 1261
Calibration / Hexachlorobutadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3437
Error Coefficients
Standard Error:405000
Relative Standard Error:6.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.0 50.0 618886.0 0.0 N
2 IC 280-628924/3 1.0 0.321705 50.0 598840.0 0.321705 Y
3 IC 280-628924/4 2.0 0.74695 50.0 598835.0 0.373475 Y
4 IC 280-628924/5 5.0 1.595853 50.0 623773.0 0.319171 Y
5 IC 280-628924/6 10.0 3.690307 50.0 595926.0 0.369031 Y
6 ICIS 280-628924/7 50.0 16.22534 50.0 627238.0 0.324507 Y
7 IC 280-628924/8 75.0 25.81572 50.0 639895.0 0.34421 Y
8 IC 280-628924/9 100.0 36.026453 50.0 623453.0 0.360265 Y
9 IC 280-628924/10 200.0 67.485598 50.0 659131.0 0.337428 Y
RelResp = [0.3437]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
Page 513 of 1261
Calibration / Naphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.741
Error Coefficients
Standard Error:1820000
Relative Standard Error:7.2
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.948478 50.0 618886.0 1.896957 Y
2 IC 280-628924/3 1.0 1.884059 50.0 598840.0 1.884059 Y
3 IC 280-628924/4 2.0 3.238121 50.0 598835.0 1.61906 Y
4 IC 280-628924/5 5.0 8.16507 50.0 623773.0 1.633014 Y
5 IC 280-628924/6 10.0 18.930622 50.0 595926.0 1.893062 Y
6 ICIS 280-628924/7 50.0 83.848794 50.0 627238.0 1.676976 Y
7 IC 280-628924/8 75.0 125.712422 50.0 639895.0 1.676166 Y
8 IC 280-628924/9 100.0 179.262029 50.0 623453.0 1.79262 Y
9 IC 280-628924/10 200.0 319.906362 50.0 659131.0 1.599532 Y
RelResp = [1.741]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 514 of 1261
Calibration / 1,2,3-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5713
Error Coefficients
Standard Error:620000
Relative Standard Error:5.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-628924/2 0.5 0.270648 50.0 618886.0 0.541295 Y
2 IC 280-628924/3 1.0 0.610681 50.0 598840.0 0.610681 Y
3 IC 280-628924/4 2.0 1.179874 50.0 598835.0 0.589937 Y
4 IC 280-628924/5 5.0 2.63838 50.0 623773.0 0.527676 Y
5 IC 280-628924/6 10.0 5.979182 50.0 595926.0 0.597918 Y
6 ICIS 280-628924/7 50.0 27.892363 50.0 627238.0 0.557847 Y
7 IC 280-628924/8 75.0 42.420944 50.0 639895.0 0.565613 Y
8 IC 280-628924/9 100.0 60.243034 50.0 623453.0 0.60243 Y
9 IC 280-628924/10 200.0 109.696934 50.0 659131.0 0.548485 Y
RelResp = [0.5713]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-628924/2
IC 280-628924/3
IC 280-628924/4
IC 280-628924/5
IC 280-628924/6
ICIS 280-628924/7
IC 280-628924/8
IC 280-628924/9
Page 515 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
10/08/2023 21:07
10/08/2023 17:38
10/08/2023 20:26
ICV 280-628924/11
RXI-624SilMS
Lab File ID:X508915.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.3011 0.1000 58.7 50.0 17.3 20.0Lin1
Chloromethane 0.3473 0.1000 57.2 50.0 14.3 20.0Lin2
Vinyl chloride 0.32700.2800 0.0100 58.4 50.0 16.8 20.0Ave
Bromomethane 0.18700.1784 0.0100 52.4 50.0 4.8 20.0Ave
Chloroethane 0.19950.1860 0.0100 53.6 50.0 7.3 20.0Ave
Dichlorofluoromethane 0.49700.4913 0.0100 50.6 50.0 1.2 20.0Ave
Trichlorofluoromethane 0.37990.3486 0.0100 54.5 50.0 9.0 20.0Ave
Ethyl ether 0.20980.2170 0.0100 48.3 50.0 -3.3 20.0Ave
Acrolein 0.02800.0312 0.0010 443 494 -10.2 20.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 0.17160.1642 0.0500 52.3 50.0 4.5 20.0Ave
1,1-Dichloroethene 0.21170.2103 0.0600 50.3 50.0 0.6 20.0Ave
Acetone 0.0721 0.0100 197 200 -1.3 20.0Lin2
Iodomethane 0.31430.2959 0.0100 53.1 50.0 6.2 20.0Ave
Carbon disulfide 0.72360.7064 0.1000 51.2 50.0 2.4 20.0Ave
Methyl acetate 0.1852 0.0100 103 100 2.5 20.0Lin1
3-Chloro-1-propene 0.4078 0.0100 47.6 50.0 -4.7 20.0Qua
Methylene Chloride 0.25660.2579 0.0100 49.8 50.0 -0.5 20.0Ave
2-Methyl-2-propanol 0.02420.0240 0.0010 505 500 0.9 20.0Ave
Acrylonitrile 0.09670.0949 0.0100 510 500 2.0 20.0Ave
Methyl tert-butyl ether 0.69960.6642 0.1000 52.7 50.0 5.3 20.0Ave
trans-1,2-Dichloroethene 0.24720.2563 0.1000 48.2 50.0 -3.6 20.0Ave
Hexane 1.410 0.0100 48.4 50.0 -3.2 20.0Lin1
Vinyl acetate 0.45230.5195 0.0100 87.1 100 -12.9 20.0Ave
1,1-Dichloroethane 0.48470.4652 0.1000 52.1 50.0 4.2 20.0Ave
2-Butanone (MEK)0.11600.1164 0.0100 199 200 -0.3 20.0Ave
cis-1,2-Dichloroethene 0.27550.2791 0.1000 49.4 50.0 -1.3 20.0Ave
2,2-Dichloropropane 0.39260.4100 0.0100 47.9 50.0 -4.2 20.0Ave
sec-Butyl Alcohol 0.02100.0207 0.0100 1220 1200 1.3 20.0Ave
Chlorobromomethane 0.11920.1199 0.0500 49.7 50.0 -0.6 20.0Ave
Tetrahydrofuran 0.07400.0779 0.0010 94.9 100 -5.1 20.0Ave
Chloroform 0.44380.4349 0.2000 51.0 50.0 2.1 20.0Ave
1,1,1-Trichloroethane 0.39130.3789 0.0500 51.6 50.0 3.3 20.0Ave
Cyclohexane 0.47230.4633 0.0100 51.0 50.0 1.9 20.0Ave
1,1-Dichloropropene 0.36450.3494 0.0100 52.2 50.0 4.3 20.0Ave
Carbon tetrachloride 0.33550.3420 0.1000 49.0 50.0 -1.9 20.0Ave
Isobutyl alcohol 0.00870.0090 0.0010 1220 1250 -2.8 20.0Ave
Benzene 1.0751.029 0.2000 52.2 50.0 4.5 20.0Ave
1,2-Dichloroethane 0.34120.3337 0.0700 51.1 50.0 2.2 20.0Ave
n-Heptane 0.3297 53.8 50.0 7.6Lin2
Trichloroethene 1.1051.066 0.2000 51.9 50.0 3.7 20.0Ave
FORM VII 8260D
Page 516 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
10/08/2023 21:07
10/08/2023 17:38
10/08/2023 20:26
ICV 280-628924/11
RXI-624SilMS
Lab File ID:X508915.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.18170.1832 0.0010 159 160 -0.8 20.0Ave
Methylcyclohexane 0.35890.3586 0.0500 50.0 50.0 0.0 20.0Ave
1,2-Dichloropropane 0.28660.2764 0.1000 51.9 50.0 3.7 20.0Ave
1,4-Dioxane 0.00310.0031 0.0010 983 1000 -1.7 20.0Ave
Dibromomethane 0.15320.1459 0.0100 52.5 50.0 5.0 20.0Ave
Dichlorobromomethane 0.34830.3500 0.2000 49.8 50.0 -0.5 20.0Ave
2-Chloroethyl vinyl ether 0.17670.1632 0.0100 54.1 50.0 8.2 20.0Ave
cis-1,3-Dichloropropene 1.7651.739 0.2000 50.7 50.0 1.5 20.0Ave
4-Methyl-2-pentanone (MIBK)0.24460.2432 0.0300 201 200 0.6 20.0Ave
Toluene 1.1151.130 0.3000 49.3 50.0 -1.4 20.0Ave
trans-1,3-Dichloropropene 0.41020.3933 0.2000 52.2 50.0 4.3 20.0Ave
Ethyl methacrylate 1.3811.358 0.0100 50.9 50.0 1.7 20.0Ave
1,1,2-Trichloroethane 0.21860.2177 0.1000 50.2 50.0 0.4 20.0Ave
Tetrachloroethene 0.86800.8002 0.1000 54.2 50.0 8.5 20.0Ave
1,3-Dichloropropane 1.6161.547 0.0100 52.2 50.0 4.5 20.0Ave
2-Hexanone 0.70870.7018 0.0100 202 200 1.0 20.0Ave
Chlorodibromomethane 1.0621.049 0.1000 50.6 50.0 1.2 20.0Ave
Ethylene Dibromide 0.91790.8974 0.1000 51.1 50.0 2.3 20.0Ave
1-Chlorohexane 1.479 0.0100 40.7 40.0 1.7 20.0Lin2
Chlorobenzene 2.8442.813 0.3000 50.6 50.0 1.1 20.0Ave
1,1,1,2-Tetrachloroethane 1.0240.9644 0.0100 53.1 50.0 6.2 20.0Ave
Ethylbenzene 1.6091.574 0.3000 51.1 50.0 2.2 20.0Ave
m-Xylene & p-Xylene 2.0111.888 0.1000 53.3 50.0 6.5 20.0Ave
o-Xylene 1.9671.913 0.2000 51.4 50.0 2.8 20.0Ave
Styrene 3.3723.234 0.2000 52.1 50.0 4.2 20.0Ave
Bromoform 0.73520.7003 0.1000 52.5 50.0 5.0 20.0Ave
Isopropylbenzene 2.9862.804 0.3000 53.3 50.0 6.5 20.0Ave
Cyclohexanone 0.0480 0.0010 1570 1500 4.7 20.0Lin1
1,1,2,2-Tetrachloroethane 0.68040.6564 0.3000 51.8 50.0 3.7 20.0Ave
Bromobenzene 0.71500.6525 0.0100 54.8 50.0 9.6 20.0Ave
trans-1,4-Dichloro-2-butene 0.2418 0.0100 52.2 50.0 4.3 20.0Lin2
1,2,3-Trichloropropane 0.20510.1997 0.0100 51.4 50.0 2.7 20.0Ave
N-Propylbenzene 0.80970.7813 0.0100 51.8 50.0 3.6 20.0Ave
2-Chlorotoluene 0.68250.6498 0.0100 52.5 50.0 5.0 20.0Ave
1,3,5-Trimethylbenzene 2.5122.405 0.0100 52.2 50.0 4.5 20.0Ave
4-Chlorotoluene 0.72000.6823 0.0100 52.8 50.0 5.5 20.0Ave
tert-Butylbenzene 2.0982.063 0.0100 50.8 50.0 1.7 20.0Ave
1,2,4-Trimethylbenzene 2.5732.494 0.3000 51.6 50.0 3.2 20.0Ave
sec-Butylbenzene 0.59810.5627 0.0100 53.1 50.0 6.3 20.0Ave
1,3-Dichlorobenzene 1.3491.238 0.5000 54.5 50.0 9.0 20.0Ave
4-Isopropyltoluene 2.6192.569 0.0100 51.0 50.0 1.9 20.0Ave
FORM VII 8260D
Page 517 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
10/08/2023 21:07
10/08/2023 17:38
10/08/2023 20:26
ICV 280-628924/11
RXI-624SilMS
Lab File ID:X508915.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.3951.291 0.5000 54.0 50.0 8.0 20.0Ave
n-Butylbenzene 2.3692.278 0.0100 52.0 50.0 4.0 20.0Ave
1,2-Dichlorobenzene 1.2621.190 0.5000 53.0 50.0 6.1 20.0Ave
1,2-Dibromo-3-Chloropropane 0.14550.1545 0.0100 47.1 50.0 -5.8 20.0Ave
1,2,4-Trichlorobenzene 0.78510.7090 0.2000 55.4 50.0 10.7 20.0Ave
Hexachlorobutadiene 0.37490.3437 0.0100 54.5 50.0 9.1 20.0Ave
Naphthalene 1.8051.741 0.0100 51.8 50.0 3.7 20.0Ave
1,2,3-Trichlorobenzene 0.61970.5713 0.3000 54.2 50.0 8.5 20.0Ave
Dibromofluoromethane (Surr)0.24740.2478 0.0100 49.9 50.0 -0.2 20.0Ave
1,2-Dichloroethane-d4 (Surr)0.28370.2929 0.0100 48.4 50.0 -3.1 20.0Ave
Toluene-d8 (Surr)4.3464.265 0.0100 50.9 50.0 1.9 20.0Ave
4-Bromofluorobenzene (Surr)0.91880.9294 0.0100 49.4 50.0 -1.1 20.0Ave
FORM VII 8260D
Page 518 of 1261
Report Date: 09-Oct-2023 13:10:58 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508915.D
Lims ID:ICV
Client ID:
Sample Type:ICV
Inject. Date:08-Oct-2023 21:07:30 ALS Bottle#:10 Worklist Smp#:11
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ICV
Operator ID:MEIERG Instrument ID:VMS_X4
Sublist:
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:10:57 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 99 1453670 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 90 353562 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 95 602291 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.692 4.691 0.001 95 359589 50.0 49.9
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 412470 50.0 48.4
$ 6 Toluene-d8 (Surr) 98 6.451 6.450 0.001 94 1536676 50.0 50.9
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 553409 50.0 49.4
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 437632 50.0 58.7
10 Chloromethane 50 1.939 1.939 0.000 100 504907 50.0 57.2
11 Vinyl chloride 62 2.039 2.039 0.000 99 475365 50.0 58.4
12 Bromomethane 94 2.332 2.332 0.000 92 271804 50.0 52.4
13 Chloroethane 64 2.425 2.425 0.000 100 290008 50.0 53.6
14 Dichlorofluoromethane 67 2.597 2.596 0.001 98 722429 50.0 50.6
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 552202 50.0 54.5
18 Ethyl ether 59 2.847 2.847 0.000 94 304934 50.0 48.3
19 Acrolein 56 2.961 2.961 0.000 99 401394 493.8 443.1
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 95 249401 50.0 52.3
21 1,1-Dichloroethene 96 3.047 3.047 0.000 97 307690 50.0 50.3
22 Acetone 43 3.061 3.061 0.000 99 418968 200.0 197.5
24 Iodomethane 142 3.169 3.168 0.001 99 456885 50.0 53.1
25 Carbon disulfide 76 3.233 3.233 0.000 99 1051824 50.0 51.2
27 Methyl acetate 43 3.290 3.290 0.000 99 538582 100.0 102.5
28 3-Chloro-1-propene 41 3.312 3.311 0.001 91 592826 50.0 47.6
29 Methylene Chloride 84 3.412 3.412 0.000 95 373045 50.0 49.8
30 2-Methyl-2-propanol 59 3.455 3.454 0.001 100 351905 500.0 504.6
31 Acrylonitrile 53 3.576 3.576 0.000 97 1406312 500.0 510.0
32 Methyl tert-butyl ether 73 3.598 3.597 0.001 96 1016940 50.0 52.7
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 359348 50.0 48.2
34 Hexane 57 3.805 3.805 0.000 94 498501 50.0 48.4
35 Vinyl acetate 43 3.905 3.905 0.000 97 1315085 100.0 87.1
36 1,1-Dichloroethane 63 3.934 3.933 0.001 97 704594 50.0 52.1
40 2-Butanone (MEK) 43 4.313 4.312 0.001 100 674494 200.0 199.3
Page 519 of 1261
Report Date: 09-Oct-2023 13:10:58 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508915.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 85 400489 50.0 49.4
43 2,2-Dichloropropane 77 4.356 4.355 0.001 88 570697 50.0 47.9
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 732228 1200.0 1215.4
47 Chlorobromomethane 128 4.520 4.520 0.000 97 173272 50.0 49.7
48 Tetrahydrofuran 42 4.527 4.527 0.000 88 215075 100.0 94.9
49 Chloroform 83 4.577 4.577 0.000 95 645194 50.0 51.0
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 568827 50.0 51.6
51 Cyclohexane 56 4.777 4.784 -0.007 94 686549 50.0 51.0
52 1,1-Dichloropropene 75 4.835 4.834 0.001 97 529891 50.0 52.2
53 Carbon tetrachloride 117 4.842 4.842 0.000 95 487734 50.0 49.0
54 Isobutyl alcohol 41 4.842 4.842 0.000 93 316384 1250.0 1215.3
55 Benzene 78 4.992 4.992 0.000 97 1562732 50.0 52.2
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 495993 50.0 51.1
58 n-Heptane 43 5.171 5.170 0.001 95 479333 50.0 53.8
60 Trichloroethene 95 5.471 5.471 0.000 98 390827 50.0 51.9
61 2-Pentanone 43 5.578 5.578 0.000 99 845078 160.0 158.7
62 Methylcyclohexane 55 5.671 5.671 0.000 92 521746 50.0 50.0
63 1,2-Dichloropropane 63 5.678 5.678 0.000 96 416673 50.0 51.9
65 1,4-Dioxane 88 5.721 5.721 0.000 97 88780 1000.0 983.0
66 Dibromomethane 93 5.750 5.750 0.000 97 222633 50.0 52.5
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 506316 50.0 49.8
69 2-Chloroethyl vinyl ether 63 6.072 6.071 0.001 92 256810 50.0 54.1
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 623863 50.0 50.7
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 98 1422387 200.0 201.1
72 Toluene 91 6.508 6.508 0.000 98 1620395 50.0 49.3
73 trans-1,3-Dichloropropene 75 6.687 6.686 0.001 97 596332 50.0 52.2
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 488427 50.0 50.9
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 92 317721 50.0 50.2
76 Tetrachloroethene 164 6.951 6.958 -0.007 98 306902 50.0 54.2
77 1,3-Dichloropropane 76 7.008 7.008 0.000 95 571435 50.0 52.2
78 2-Hexanone 43 7.023 7.022 0.001 98 1002338 200.0 202.0
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 375390 50.0 50.6
80 Ethylene Dibromide 107 7.323 7.323 0.000 99 324551 50.0 51.1
81 1-Chlorohexane 91 7.709 7.709 0.000 96 418469 40.0 40.7
82 Chlorobenzene 112 7.752 7.752 0.000 93 1005501 50.0 50.6
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 96 362131 50.0 53.1
84 Ethylbenzene 106 7.823 7.830 -0.007 99 568983 50.0 51.1
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 711131 50.0 53.3
86 o-Xylene 106 8.302 8.302 0.000 97 695451 50.0 51.4
87 Styrene 104 8.324 8.324 0.000 95 1192088 50.0 52.1
88 Bromoform 173 8.503 8.502 0.001 97 259941 50.0 52.5
89 Isopropylbenzene 105 8.646 8.645 0.001 96 1798385 50.0 53.3
91 Cyclohexanone 55 8.746 8.746 0.000 94 509239 1500.0 1569.9
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 95 409785 50.0 51.8
93 Bromobenzene 156 8.967 8.967 0.000 97 430611 50.0 54.8
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 62 145647 50.0 52.2
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 123545 50.0 51.4
96 N-Propylbenzene 120 9.046 9.046 0.000 99 487687 50.0 51.8
97 2-Chlorotoluene 126 9.146 9.146 0.000 96 411087 50.0 52.5
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 94 1513165 50.0 52.2
99 4-Chlorotoluene 126 9.261 9.260 0.001 98 433651 50.0 52.8
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1263805 50.0 50.8
Page 520 of 1261
Report Date: 09-Oct-2023 13:10:58 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508915.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 1549522 50.0 51.6
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 360233 50.0 53.1
104 1,3-Dichlorobenzene 146 9.876 9.875 0.001 98 812425 50.0 54.5
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 1577197 50.0 51.0
106 1,4-Dichlorobenzene 146 9.968 9.968 0.000 94 840124 50.0 54.0
108 n-Butylbenzene 91 10.297 10.297 0.000 98 1426528 50.0 52.0
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 760192 50.0 53.0
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.105 0.000 85 87650 50.0 47.1
112 1,2,4-Trichlorobenzene 180 11.935 11.927 0.008 94 472882 50.0 55.4
113 Hexachlorobutadiene 225 12.071 12.070 0.001 96 225817 50.0 54.5
114 Naphthalene 128 12.199 12.199 0.000 98 1087427 50.0 51.8
115 1,2,3-Trichlorobenzene 180 12.421 12.421 0.000 96 373227 50.0 54.2
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 97.6
S 127 Trihalomethanes, Total 1 0 200.0 203.9
S 124 1,3-Dichloropropene, Total 1 0 100.0 102.9
S 129 1,2-Dichloroethene, Total 1 0 100.0 97.6
S 125 Xylenes, Total 106 0 100.0 104.7
S 123 Xylenes, Total (URS) 1 0 100.0 104.7
Reagents:
MV-MegaMain B_00092 Amount Added: 25.00 Units: uL
MV-Gas B_00148 Amount Added: 10.00 Units: uL
mv-IS_SS_00066 Amount Added: 5.00 Units: uL Run Reagent
Page 521 of 1261
Report Date: 09-Oct-2023 13:10:58 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508915.D
Injection Date:08-Oct-2023 21:07:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:ICV Worklist Smp#:11
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:10
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 522 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/17/2023 18:43
10/08/2023 17:38
10/08/2023 20:26
CCV 280-634482/2
RXI-624SilMS
Lab File ID:X510784.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.2807 0.1000 54.8 50.0 9.5 20.0Lin1
Chloromethane 0.3273 0.1000 53.9 50.0 7.8 20.0Lin2
Vinyl chloride 0.31390.2800 0.0100 56.0 50.0 12.1 20.0Ave
Bromomethane 0.16610.1784 0.0100 46.5 50.0 -6.9 20.0Ave
Chloroethane 0.19470.1860 0.0100 52.3 50.0 4.7 20.0Ave
Dichlorofluoromethane 0.50590.4913 0.0100 51.5 50.0 3.0 20.0Ave
Trichlorofluoromethane 0.35890.3486 0.0100 51.5 50.0 3.0 20.0Ave
Ethyl ether 0.21380.2170 0.0100 49.3 50.0 -1.5 20.0Ave
Acrolein 0.03600.0312 0.0010 570 494 15.5 20.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 0.18340.1642 0.0500 55.8 50.0 11.7 20.0Ave
1,1-Dichloroethene 0.21920.2103 0.0600 52.1 50.0 4.2 20.0Ave
Acetone 0.0720 0.0100 197 200 -1.3 20.0Lin2
Iodomethane 0.27840.2959 0.0100 47.0 50.0 -5.9 20.0Ave
Carbon disulfide 0.74600.7064 0.1000 52.8 50.0 5.6 20.0Ave
Methyl acetate 0.1721 0.0100 95.2 100 -4.8 20.0Lin1
3-Chloro-1-propene 0.4385 0.0100 51.7 50.0 3.4 20.0Qua
Methylene Chloride 0.26540.2579 0.0100 51.5 50.0 2.9 20.0Ave
2-Methyl-2-propanol 0.02090.0240 0.0010 436 500 -12.7 35.0Ave
Acrylonitrile 0.09440.0949 0.0100 498 500 -0.5 20.0Ave
Methyl tert-butyl ether 0.71190.6642 0.1000 53.6 50.0 7.2 20.0Ave
trans-1,2-Dichloroethene 0.24640.2563 0.1000 48.1 50.0 -3.9 20.0Ave
Hexane 1.339 0.0100 46.0 50.0 -8.0 20.0Lin1
Vinyl acetate 0.53080.5195 0.0100 102 100 2.2 20.0Ave
1,1-Dichloroethane 0.49270.4652 0.1000 52.9 50.0 5.9 20.0Ave
2-Butanone (MEK)0.10970.1164 0.0100 188 200 -5.8 20.0Ave
cis-1,2-Dichloroethene 0.27750.2791 0.1000 49.7 50.0 -0.6 20.0Ave
2,2-Dichloropropane 0.40740.4100 0.0100 49.7 50.0 -0.6 20.0Ave
sec-Butyl Alcohol 0.01750.0207 0.0100 1010 1200 -15.7 20.0Ave
Chlorobromomethane 0.12460.1199 0.0500 51.9 50.0 3.9 20.0Ave
Tetrahydrofuran 0.07350.0779 0.0010 94.4 100 -5.6 20.0Ave
Chloroform 0.44700.4349 0.2000 51.4 50.0 2.8 20.0Ave
1,1,1-Trichloroethane 0.39010.3789 0.0500 51.5 50.0 3.0 20.0Ave
Cyclohexane 0.47830.4633 0.0100 51.6 50.0 3.2 20.0Ave
1,1-Dichloropropene 0.37560.3494 0.0100 53.7 50.0 7.5 20.0Ave
Carbon tetrachloride 0.32300.3420 0.1000 47.2 50.0 -5.6 20.0Ave
Isobutyl alcohol 0.00720.0090 0.0010 1000 1250 -19.7 20.0Ave
Benzene 1.0761.029 0.2000 52.3 50.0 4.5 20.0Ave
1,2-Dichloroethane 0.35620.3337 0.0700 53.4 50.0 6.7 20.0Ave
n-Heptane 0.3079 50.2 50.0 0.4Lin2
Trichloroethene 0.96571.066 0.2000 45.3 50.0 -9.4 20.0Ave
FORM VII 8260D
Page 523 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/17/2023 18:43
10/08/2023 17:38
10/08/2023 20:26
CCV 280-634482/2
RXI-624SilMS
Lab File ID:X510784.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.16950.1832 0.0010 148 160 -7.5 20.0Ave
Methylcyclohexane 0.34040.3586 0.0500 47.5 50.0 -5.1 20.0Ave
1,2-Dichloropropane 0.28050.2764 0.1000 50.7 50.0 1.5 20.0Ave
1,4-Dioxane 0.00310.0031 0.0010 985 1000 -1.5 20.0Ave
Dibromomethane 0.14730.1459 0.0100 50.5 50.0 0.9 20.0Ave
Dichlorobromomethane 0.33170.3500 0.2000 47.4 50.0 -5.2 20.0Ave
2-Chloroethyl vinyl ether 0.15710.1632 0.0100 48.1 50.0 -3.8 20.0Ave
cis-1,3-Dichloropropene 1.6121.739 0.2000 46.4 50.0 -7.3 20.0Ave
4-Methyl-2-pentanone (MIBK)0.22070.2432 0.0300 182 200 -9.2 20.0Ave
Toluene 1.1451.130 0.3000 50.7 50.0 1.3 20.0Ave
trans-1,3-Dichloropropene 0.38150.3933 0.2000 48.5 50.0 -3.0 20.0Ave
Ethyl methacrylate 1.1561.358 0.0100 42.6 50.0 -14.9 20.0Ave
1,1,2-Trichloroethane 0.21370.2177 0.1000 49.1 50.0 -1.8 20.0Ave
Tetrachloroethene 0.78470.8002 0.1000 49.0 50.0 -1.9 20.0Ave
1,3-Dichloropropane 1.4851.547 0.0100 48.0 50.0 -4.0 20.0Ave
2-Hexanone 0.57100.7018 0.0100 163 200 -18.6 20.0Ave
Chlorodibromomethane 0.85131.049 0.1000 40.6 50.0 -18.9 20.0Ave
Ethylene Dibromide 0.80630.8974 0.1000 44.9 50.0 -10.1 20.0Ave
1-Chlorohexane 1.252 0.0100 34.4 40.0 -14.1 20.0Lin2
Chlorobenzene 2.5732.813 0.3000 45.7 50.0 -8.5 20.0Ave
1,1,1,2-Tetrachloroethane 0.85000.9644 0.0100 44.1 50.0 -11.9 20.0Ave
Ethylbenzene 1.4491.574 0.3000 46.0 50.0 -8.0 20.0Ave
m-Xylene & p-Xylene 1.8081.888 0.1000 47.9 50.0 -4.2 20.0Ave
o-Xylene 1.7391.913 0.2000 45.5 50.0 -9.1 20.0Ave
Styrene 2.9653.234 0.2000 45.8 50.0 -8.3 20.0Ave
Bromoform 0.54310.7003 0.1000 38.8 50.0 -22.4 *20.0Ave
Isopropylbenzene 2.5612.804 0.3000 45.7 50.0 -8.6 20.0Ave
Cyclohexanone 0.0368 0.0010 1200 1500 -19.9 20.0Lin1
1,1,2,2-Tetrachloroethane 0.60360.6564 0.3000 46.0 50.0 -8.0 20.0Ave
Bromobenzene 0.62910.6525 0.0100 48.2 50.0 -3.6 20.0Ave
trans-1,4-Dichloro-2-butene 0.1857 0.0100 39.9 50.0 -20.1 *20.0Lin2
1,2,3-Trichloropropane 0.17930.1997 0.0100 44.9 50.0 -10.2 20.0Ave
N-Propylbenzene 0.70810.7813 0.0100 45.3 50.0 -9.4 20.0Ave
2-Chlorotoluene 0.59410.6498 0.0100 45.7 50.0 -8.6 20.0Ave
1,3,5-Trimethylbenzene 2.1542.405 0.0100 44.8 50.0 -10.4 20.0Ave
4-Chlorotoluene 0.62890.6823 0.0100 46.1 50.0 -7.8 20.0Ave
tert-Butylbenzene 1.7722.063 0.0100 42.9 50.0 -14.1 20.0Ave
1,2,4-Trimethylbenzene 2.2562.494 0.3000 45.2 50.0 -9.5 20.0Ave
sec-Butylbenzene 0.50930.5627 0.0100 45.3 50.0 -9.5 20.0Ave
1,3-Dichlorobenzene 1.1861.238 0.5000 47.9 50.0 -4.2 20.0Ave
4-Isopropyltoluene 2.2302.569 0.0100 43.4 50.0 -13.2 20.0Ave
FORM VII 8260D
Page 524 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/17/2023 18:43
10/08/2023 17:38
10/08/2023 20:26
CCV 280-634482/2
RXI-624SilMS
Lab File ID:X510784.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.2021.291 0.5000 46.6 50.0 -6.9 20.0Ave
n-Butylbenzene 1.9712.278 0.0100 43.3 50.0 -13.5 20.0Ave
1,2-Dichlorobenzene 1.1021.190 0.5000 46.3 50.0 -7.4 20.0Ave
1,2-Dibromo-3-Chloropropane 0.11580.1545 0.0100 37.5 50.0 -25.0 *20.0Ave
1,2,4-Trichlorobenzene 0.63360.7090 0.2000 44.7 50.0 -10.6 20.0Ave
Hexachlorobutadiene 0.29710.3437 0.0100 43.2 50.0 -13.6 20.0Ave
Naphthalene 1.4421.741 0.0100 41.4 50.0 -17.2 20.0Ave
1,2,3-Trichlorobenzene 0.47910.5713 0.3000 41.9 50.0 -16.1 20.0Ave
Dibromofluoromethane (Surr)0.26990.2478 0.0100 54.5 50.0 8.9 20.0Ave
1,2-Dichloroethane-d4 (Surr)0.32520.2929 0.0100 55.5 50.0 11.0 20.0Ave
Toluene-d8 (Surr)4.3174.265 0.0100 50.6 50.0 1.2 20.0Ave
4-Bromofluorobenzene (Surr)0.90950.9294 0.0100 48.9 50.0 -2.1 20.0Ave
FORM VII 8260D
Page 525 of 1261
Report Date: 20-Nov-2023 22:19:19 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510784.D
Lims ID:CCV
Client ID:
Sample Type:CCV
Inject. Date:17-Nov-2023 18:43:30 ALS Bottle#:1 Worklist Smp#:2
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:CCV
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:19:18 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:17-Nov-2023 19:22:58
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 99 2318220 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 88 624263 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 1067323 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 625662 50.0 54.5
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 753908 50.0 55.5
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 2695156 50.0 50.6
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 970771 50.0 48.9
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 650730 50.0 54.8
10 Chloromethane 50 1.939 1.939 0.000 100 758867 50.0 53.9
11 Vinyl chloride 62 2.039 2.039 0.000 99 727699 50.0 56.0
12 Bromomethane 94 2.332 2.332 0.000 91 385093 50.0 46.5
13 Chloroethane 64 2.425 2.425 0.000 100 451392 50.0 52.3
14 Dichlorofluoromethane 67 2.596 2.596 0.000 98 1172877 50.0 51.5
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 832044 50.0 51.5
18 Ethyl ether 59 2.847 2.847 0.000 92 495691 50.0 49.3
19 Acrolein 56 2.961 2.961 0.000 99 823554 493.8 570.1
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 96 425078 50.0 55.8
21 1,1-Dichloroethene 96 3.047 3.047 0.000 97 508059 50.0 52.1
22 Acetone 43 3.061 3.061 0.000 99 667870 200.0 197.4
24 Iodomethane 142 3.168 3.168 0.000 99 645406 50.0 47.0
25 Carbon disulfide 76 3.233 3.233 0.000 99 1729302 50.0 52.8
27 Methyl acetate 43 3.290 3.290 0.000 98 797714 100.0 95.2
28 3-Chloro-1-propene 41 3.311 3.311 0.000 91 1016510 50.0 51.7
29 Methylene Chloride 84 3.412 3.412 0.000 96 615260 50.0 51.5
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 100 485222 500.0 436.3
31 Acrylonitrile 53 3.576 3.576 0.000 98 2188678 500.0 497.7
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 95 1650313 50.0 53.6
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 571210 50.0 48.1
34 Hexane 57 3.805 3.805 0.000 94 835887 50.0 46.0
35 Vinyl acetate 43 3.905 3.905 0.000 97 2460925 100.0 102.2
36 1,1-Dichloroethane 63 3.933 3.933 0.000 97 1142103 50.0 52.9
Page 526 of 1261
Report Date: 20-Nov-2023 22:19:19 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510784.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.312 4.312 0.000 100 1016786 200.0 188.4
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 643308 50.0 49.7
43 2,2-Dichloropropane 77 4.355 4.355 0.000 89 944495 50.0 49.7
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 971881 1200.0 1011.6
47 Chlorobromomethane 128 4.520 4.520 0.000 98 288779 50.0 51.9
48 Tetrahydrofuran 42 4.527 4.527 0.000 89 340966 100.0 94.4
49 Chloroform 83 4.577 4.577 0.000 96 1036209 50.0 51.4
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 904236 50.0 51.5
51 Cyclohexane 56 4.777 4.777 0.000 93 1108858 50.0 51.6
52 1,1-Dichloropropene 75 4.834 4.834 0.000 96 870620 50.0 53.7
53 Carbon tetrachloride 117 4.842 4.842 0.000 96 748862 50.0 47.2
54 Isobutyl alcohol 41 4.842 4.842 0.000 95 416859 1250.0 1004.1
55 Benzene 78 4.992 4.992 0.000 97 2493539 50.0 52.3
56 1,2-Dichloroethane 62 5.013 5.013 0.000 98 825711 50.0 53.4
58 n-Heptane 43 5.170 5.170 0.000 95 713873 50.0 50.2
60 Trichloroethene 95 5.471 5.471 0.000 98 602822 50.0 45.3
61 2-Pentanone 43 5.578 5.578 0.000 99 1257474 160.0 148.1
62 Methylcyclohexane 55 5.671 5.671 0.000 93 789228 50.0 47.5
63 1,2-Dichloropropane 63 5.678 5.678 0.000 94 650194 50.0 50.7
65 1,4-Dioxane 88 5.721 5.721 0.000 97 141902 1000.0 985.2
66 Dibromomethane 93 5.750 5.750 0.000 96 341485 50.0 50.5
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 768954 50.0 47.4
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 92 364113 50.0 48.1
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 1006242 50.0 46.4
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 98 2046876 200.0 181.5
72 Toluene 91 6.515 6.515 0.000 98 2654136 50.0 50.7
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 97 884507 50.0 48.5
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 721634 50.0 42.6
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 93 495434 50.0 49.1
76 Tetrachloroethene 164 6.951 6.951 0.000 97 489839 50.0 49.0
77 1,3-Dichloropropane 76 7.008 7.008 0.000 95 926875 50.0 48.0
78 2-Hexanone 43 7.022 7.022 0.000 98 1425769 200.0 162.7
79 Chlorodibromomethane 129 7.201 7.201 0.000 90 531431 50.0 40.6
80 Ethylene Dibromide 107 7.323 7.323 0.000 98 503336 50.0 44.9
81 1-Chlorohexane 91 7.709 7.709 0.000 98 625489 40.0 34.4
82 Chlorobenzene 112 7.752 7.752 0.000 93 1605962 50.0 45.7
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 94 530644 50.0 44.1
84 Ethylbenzene 106 7.830 7.830 0.000 99 904643 50.0 46.0
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 1128472 50.0 47.9
86 o-Xylene 106 8.302 8.302 0.000 97 1085875 50.0 45.5
87 Styrene 104 8.324 8.324 0.000 94 1850685 50.0 45.8
88 Bromoform 173 8.502 8.502 0.000 97 339058 50.0 38.8
89 Isopropylbenzene 105 8.645 8.645 0.000 97 2733937 50.0 45.7
91 Cyclohexanone 55 8.746 8.746 0.000 93 689353 1500.0 1201.8
92 1,1,2,2-Tetrachloroethane 83 8.931 8.931 0.000 95 644211 50.0 46.0
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 61 198186 50.0 39.9
93 Bromobenzene 156 8.967 8.967 0.000 96 671501 50.0 48.2
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 191353 50.0 44.9
96 N-Propylbenzene 120 9.046 9.046 0.000 99 755739 50.0 45.3
97 2-Chlorotoluene 126 9.146 9.146 0.000 96 634115 50.0 45.7
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 95 2299150 50.0 44.8
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 671202 50.0 46.1
Page 527 of 1261
Report Date: 20-Nov-2023 22:19:19 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510784.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1891261 50.0 42.9
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 2408185 50.0 45.2
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 543638 50.0 45.3
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 1266154 50.0 47.9
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 2380489 50.0 43.4
106 1,4-Dichlorobenzene 146 9.975 9.975 0.000 94 1283402 50.0 46.6
108 n-Butylbenzene 91 10.297 10.297 0.000 98 2103357 50.0 43.3
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 1176168 50.0 46.3
110 1,2-Dibromo-3-Chloropropane 157 11.112 11.112 0.000 84 123603 50.0 37.5
112 1,2,4-Trichlorobenzene 180 11.935 11.935 0.000 94 676305 50.0 44.7
113 Hexachlorobutadiene 225 12.070 12.070 0.000 96 317136 50.0 43.2
114 Naphthalene 128 12.206 12.206 0.000 98 1538697 50.0 41.4
115 1,2,3-Trichlorobenzene 180 12.428 12.428 0.000 96 511320 50.0 41.9
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 97.8
S 127 Trihalomethanes, Total 1 0 200.0 178.1
S 124 1,3-Dichloropropene, Total 1 0 100.0 94.9
S 129 1,2-Dichloroethene, Total 1 0 100.0 97.8
S 125 Xylenes, Total 106 0 100.0 93.3
S 123 Xylenes, Total (URS) 1 0 100.0 93.3
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMainA_00099 Amount Added: 25.00 Units: uL
MV-Gas A_00172 Amount Added: 10.00 Units: uL
mv-IS_SS_00071 Amount Added: 5.00 Units: uL Run Reagent
Page 528 of 1261
Report Date: 20-Nov-2023 22:19:20 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510784.D
Injection Date:17-Nov-2023 18:43:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:CCV Worklist Smp#:2
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:1
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 529 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/18/2023 01:39
10/08/2023 17:38
10/08/2023 20:26
CCVC 280-634482/24
RXI-624SilMS
Lab File ID:X510804.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.2796 0.1000 54.6 50.0 9.1 50.0Lin1
Chloromethane 0.3350 0.1000 55.1 50.0 10.3 50.0Lin2
Vinyl chloride 0.31780.2800 0.0100 56.7 50.0 13.5 50.0Ave
Bromomethane 0.15360.1784 0.0100 43.1 50.0 -13.9 50.0Ave
Chloroethane 0.19270.1860 0.0100 51.8 50.0 3.6 50.0Ave
Dichlorofluoromethane 0.51360.4913 0.0100 52.3 50.0 4.5 50.0Ave
Trichlorofluoromethane 0.36040.3486 0.0100 51.7 50.0 3.4 50.0Ave
Ethyl ether 0.22190.2170 0.0100 51.1 50.0 2.3 50.0Ave
Acrolein 0.03540.0312 0.0010 561 494 13.6 50.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 0.18390.1642 0.0500 56.0 50.0 12.0 50.0Ave
1,1-Dichloroethene 0.22230.2103 0.0600 52.8 50.0 5.7 50.0Ave
Acetone 0.0849 0.0100 234 200 16.8 50.0Lin2
Iodomethane 0.26490.2959 0.0100 44.8 50.0 -10.5 50.0Ave
Carbon disulfide 0.74590.7064 0.1000 52.8 50.0 5.6 50.0Ave
Methyl acetate 0.1914 0.0100 106 100 5.9 50.0Lin1
3-Chloro-1-propene 0.4216 0.0100 49.4 50.0 -1.1 50.0Qua
Methylene Chloride 0.27140.2579 0.0100 52.6 50.0 5.2 50.0Ave
2-Methyl-2-propanol 0.02550.0240 0.0010 532 500 6.4 50.0Ave
Acrylonitrile 0.10430.0949 0.0100 550 500 10.0 50.0Ave
Methyl tert-butyl ether 0.74790.6642 0.1000 56.3 50.0 12.6 50.0Ave
trans-1,2-Dichloroethene 0.25320.2563 0.1000 49.4 50.0 -1.2 50.0Ave
Hexane 1.229 0.0100 42.2 50.0 -15.6 50.0Lin1
Vinyl acetate 0.33560.5195 0.0100 64.6 100 -35.4 50.0Ave
1,1-Dichloroethane 0.49400.4652 0.1000 53.1 50.0 6.2 50.0Ave
2-Butanone (MEK)0.12470.1164 0.0100 214 200 7.1 50.0Ave
cis-1,2-Dichloroethene 0.28270.2791 0.1000 50.7 50.0 1.3 50.0Ave
2,2-Dichloropropane 0.36630.4100 0.0100 44.7 50.0 -10.7 50.0Ave
sec-Butyl Alcohol 0.02100.0207 0.0100 1210 1200 1.2 50.0Ave
Chlorobromomethane 0.12550.1199 0.0500 52.3 50.0 4.6 50.0Ave
Tetrahydrofuran 0.08480.0779 0.0010 109 100 8.8 50.0Ave
Chloroform 0.45950.4349 0.2000 52.8 50.0 5.7 50.0Ave
1,1,1-Trichloroethane 0.39630.3789 0.0500 52.3 50.0 4.6 50.0Ave
Cyclohexane 0.48180.4633 0.0100 52.0 50.0 4.0 50.0Ave
1,1-Dichloropropene 0.37620.3494 0.0100 53.8 50.0 7.7 50.0Ave
Carbon tetrachloride 0.32550.3420 0.1000 47.6 50.0 -4.8 50.0Ave
Isobutyl alcohol 0.00920.0090 0.0010 1290 1250 2.9 50.0Ave
Benzene 1.0941.029 0.2000 53.2 50.0 6.3 50.0Ave
1,2-Dichloroethane 0.35950.3337 0.0700 53.9 50.0 7.7 50.0Ave
n-Heptane 0.2677 43.5 50.0 -13.0Lin2
Trichloroethene 1.0571.066 0.2000 49.6 50.0 -0.9 50.0Ave
FORM VII 8260D
Page 530 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/18/2023 01:39
10/08/2023 17:38
10/08/2023 20:26
CCVC 280-634482/24
RXI-624SilMS
Lab File ID:X510804.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.19350.1832 0.0010 169 160 5.7 50.0Ave
Methylcyclohexane 0.33770.3586 0.0500 47.1 50.0 -5.8 50.0Ave
1,2-Dichloropropane 0.28430.2764 0.1000 51.4 50.0 2.9 50.0Ave
1,4-Dioxane 0.00350.0031 0.0010 1120 1000 12.2 50.0Ave
Dibromomethane 0.15080.1459 0.0100 51.7 50.0 3.3 50.0Ave
Dichlorobromomethane 0.34130.3500 0.2000 48.7 50.0 -2.5 50.0Ave
2-Chloroethyl vinyl ether 0.16660.1632 0.0100 51.0 50.0 2.1 50.0Ave
cis-1,3-Dichloropropene 1.5871.739 0.2000 45.6 50.0 -8.7 50.0Ave
4-Methyl-2-pentanone (MIBK)0.25320.2432 0.0300 208 200 4.1 50.0Ave
Toluene 1.1601.130 0.3000 51.3 50.0 2.7 50.0Ave
trans-1,3-Dichloropropene 0.38590.3933 0.2000 49.1 50.0 -1.9 50.0Ave
Ethyl methacrylate 1.2271.358 0.0100 45.2 50.0 -9.6 50.0Ave
1,1,2-Trichloroethane 0.22280.2177 0.1000 51.2 50.0 2.4 50.0Ave
Tetrachloroethene 0.77660.8002 0.1000 48.5 50.0 -2.9 50.0Ave
1,3-Dichloropropane 1.5011.547 0.0100 48.5 50.0 -3.0 50.0Ave
2-Hexanone 0.64780.7018 0.0100 185 200 -7.7 50.0Ave
Chlorodibromomethane 0.87581.049 0.1000 41.7 50.0 -16.5 50.0Ave
Ethylene Dibromide 0.83270.8974 0.1000 46.4 50.0 -7.2 50.0Ave
1-Chlorohexane 1.258 0.0100 34.5 40.0 -13.7 50.0Lin2
Chlorobenzene 2.6142.813 0.3000 46.5 50.0 -7.1 50.0Ave
1,1,1,2-Tetrachloroethane 0.87420.9644 0.0100 45.3 50.0 -9.3 50.0Ave
Ethylbenzene 1.4601.574 0.3000 46.4 50.0 -7.3 50.0Ave
m-Xylene & p-Xylene 1.8181.888 0.1000 48.2 50.0 -3.7 50.0Ave
o-Xylene 1.7921.913 0.2000 46.8 50.0 -6.4 50.0Ave
Styrene 2.9863.234 0.2000 46.2 50.0 -7.7 50.0Ave
Bromoform 0.57240.7003 0.1000 40.9 50.0 -18.3 50.0Ave
Isopropylbenzene 2.5822.804 0.3000 46.0 50.0 -7.9 50.0Ave
Cyclohexanone 0.0419 0.0010 1370 1500 -8.7 50.0Lin1
1,1,2,2-Tetrachloroethane 0.57990.6564 0.3000 44.2 50.0 -11.6 50.0Ave
Bromobenzene 0.64020.6525 0.0100 49.1 50.0 -1.9 50.0Ave
trans-1,4-Dichloro-2-butene 0.1849 0.0100 39.8 50.0 -20.4 50.0Lin2
1,2,3-Trichloropropane 0.19210.1997 0.0100 48.1 50.0 -3.8 50.0Ave
N-Propylbenzene 0.70740.7813 0.0100 45.3 50.0 -9.5 50.0Ave
2-Chlorotoluene 0.59650.6498 0.0100 45.9 50.0 -8.2 50.0Ave
1,3,5-Trimethylbenzene 2.1702.405 0.0100 45.1 50.0 -9.8 50.0Ave
4-Chlorotoluene 0.62060.6823 0.0100 45.5 50.0 -9.0 50.0Ave
tert-Butylbenzene 1.7832.063 0.0100 43.2 50.0 -13.6 50.0Ave
1,2,4-Trimethylbenzene 2.2492.494 0.3000 45.1 50.0 -9.8 50.0Ave
sec-Butylbenzene 0.49850.5627 0.0100 44.3 50.0 -11.4 50.0Ave
1,3-Dichlorobenzene 1.1821.238 0.5000 47.7 50.0 -4.5 50.0Ave
4-Isopropyltoluene 2.1962.569 0.0100 42.7 50.0 -14.5 50.0Ave
FORM VII 8260D
Page 531 of 1261
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/18/2023 01:39
10/08/2023 17:38
10/08/2023 20:26
CCVC 280-634482/24
RXI-624SilMS
Lab File ID:X510804.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.2011.291 0.5000 46.5 50.0 -7.0 50.0Ave
n-Butylbenzene 1.9002.278 0.0100 41.7 50.0 -16.6 50.0Ave
1,2-Dichlorobenzene 1.1071.190 0.5000 46.5 50.0 -6.9 50.0Ave
1,2-Dibromo-3-Chloropropane 0.12380.1545 0.0100 40.1 50.0 -19.9 50.0Ave
1,2,4-Trichlorobenzene 0.64080.7090 0.2000 45.2 50.0 -9.6 50.0Ave
Hexachlorobutadiene 0.28100.3437 0.0100 40.9 50.0 -18.2 50.0Ave
Naphthalene 1.6031.741 0.0100 46.0 50.0 -7.9 50.0Ave
1,2,3-Trichlorobenzene 0.50950.5713 0.3000 44.6 50.0 -10.8 50.0Ave
Dibromofluoromethane (Surr)0.27190.2478 0.0100 54.9 50.0 9.7 50.0Ave
1,2-Dichloroethane-d4 (Surr)0.32490.2929 0.0100 55.5 50.0 10.9 50.0Ave
Toluene-d8 (Surr)4.3254.265 0.0100 50.7 50.0 1.4 50.0Ave
4-Bromofluorobenzene (Surr)0.90220.9294 0.0100 48.5 50.0 -2.9 50.0Ave
FORM VII 8260D
Page 532 of 1261
Report Date: 20-Nov-2023 22:17:42 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510804.D
Lims ID:ccvc
Client ID:
Sample Type:CCVC
Inject. Date:18-Nov-2023 01:39:30 ALS Bottle#:21 Worklist Smp#:24
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:CCVC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:17:41 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 99 2234813 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 89 606183 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 1044845 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.692 4.691 0.001 93 607629 50.0 54.9
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 726038 50.0 55.5
$ 6 Toluene-d8 (Surr) 98 6.458 6.450 0.008 94 2621887 50.0 50.7
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 942673 50.0 48.5
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 624903 50.0 54.6
10 Chloromethane 50 1.939 1.939 0.000 99 748644 50.0 55.1
11 Vinyl chloride 62 2.039 2.039 0.000 99 710270 50.0 56.7
12 Bromomethane 94 2.332 2.332 0.000 91 343354 50.0 43.1
13 Chloroethane 64 2.425 2.425 0.000 100 430638 50.0 51.8
14 Dichlorofluoromethane 67 2.597 2.596 0.001 99 1147842 50.0 52.3
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 805489 50.0 51.7
18 Ethyl ether 59 2.847 2.847 0.000 93 495863 50.0 51.1
19 Acrolein 56 2.961 2.961 0.000 99 780980 493.8 560.8
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 95 410970 50.0 56.0
21 1,1-Dichloroethene 96 3.047 3.047 0.000 97 496760 50.0 52.8
22 Acetone 43 3.069 3.061 0.008 100 758711 200.0 233.5
24 Iodomethane 142 3.169 3.168 0.001 99 592069 50.0 44.8
25 Carbon disulfide 76 3.233 3.233 0.000 99 1667022 50.0 52.8
27 Methyl acetate 43 3.290 3.290 0.000 98 855580 100.0 105.9
28 3-Chloro-1-propene 41 3.312 3.311 0.001 91 942186 50.0 49.4
29 Methylene Chloride 84 3.412 3.412 0.000 94 606435 50.0 52.6
30 2-Methyl-2-propanol 59 3.455 3.454 0.001 99 570545 500.0 532.1
31 Acrylonitrile 53 3.576 3.576 0.000 98 2331303 500.0 549.9
32 Methyl tert-butyl ether 73 3.598 3.597 0.001 96 1671415 50.0 56.3
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 565831 50.0 49.4
34 Hexane 57 3.805 3.805 0.000 94 744835 50.0 42.2
35 Vinyl acetate 43 3.905 3.905 0.000 97 1499939 100.0 64.6
36 1,1-Dichloroethane 63 3.934 3.933 0.001 97 1103929 50.0 53.1
40 2-Butanone (MEK) 43 4.320 4.312 0.008 100 1114657 200.0 214.3
Page 533 of 1261
Report Date: 20-Nov-2023 22:17:42 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510804.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 85 631822 50.0 50.7
43 2,2-Dichloropropane 77 4.356 4.355 0.001 88 818574 50.0 44.7
45 sec-Butyl Alcohol 45 4.427 4.420 0.007 99 1124307 1200.0 1213.9
47 Chlorobromomethane 128 4.520 4.520 0.000 97 280398 50.0 52.3
48 Tetrahydrofuran 42 4.527 4.527 0.000 89 378937 100.0 108.8
49 Chloroform 83 4.577 4.577 0.000 96 1026959 50.0 52.8
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 98 885761 50.0 52.3
51 Cyclohexane 56 4.785 4.777 0.008 91 1076830 50.0 52.0
52 1,1-Dichloropropene 75 4.835 4.834 0.001 98 840701 50.0 53.8
53 Carbon tetrachloride 117 4.842 4.842 0.000 95 727520 50.0 47.6
54 Isobutyl alcohol 41 4.842 4.842 0.000 93 514805 1250.0 1286.3
55 Benzene 78 4.992 4.992 0.000 97 2444697 50.0 53.2
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 803462 50.0 53.9
58 n-Heptane 43 5.171 5.170 0.001 95 598338 50.0 43.5
60 Trichloroethene 95 5.478 5.471 0.007 98 640595 50.0 49.6
61 2-Pentanone 43 5.578 5.578 0.000 99 1384097 160.0 169.1
62 Methylcyclohexane 55 5.671 5.671 0.000 92 754725 50.0 47.1
63 1,2-Dichloropropane 63 5.678 5.678 0.000 95 635469 50.0 51.4
65 1,4-Dioxane 88 5.721 5.721 0.000 96 155844 1000.0 1122.4
66 Dibromomethane 93 5.750 5.750 0.000 96 337027 50.0 51.7
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 762636 50.0 48.7
69 2-Chloroethyl vinyl ether 63 6.072 6.071 0.001 93 372326 50.0 51.0
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 95 962214 50.0 45.6
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 2263561 200.0 208.2
72 Toluene 91 6.515 6.515 0.000 98 2592623 50.0 51.3
73 trans-1,3-Dichloropropene 75 6.687 6.686 0.001 97 862378 50.0 49.1
74 Ethyl methacrylate 69 6.701 6.701 0.000 90 743916 50.0 45.2
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 93 497995 50.0 51.2
76 Tetrachloroethene 164 6.958 6.951 0.007 98 470789 50.0 48.5
77 1,3-Dichloropropane 76 7.008 7.008 0.000 98 910021 50.0 48.5
78 2-Hexanone 43 7.030 7.022 0.008 97 1570860 200.0 184.6
79 Chlorodibromomethane 129 7.201 7.201 0.000 91 530895 50.0 41.7
80 Ethylene Dibromide 107 7.323 7.323 0.000 99 504791 50.0 46.4
81 1-Chlorohexane 91 7.709 7.709 0.000 98 609941 40.0 34.5
82 Chlorobenzene 112 7.752 7.752 0.000 93 1584696 50.0 46.5
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 95 529954 50.0 45.3
84 Ethylbenzene 106 7.831 7.830 0.001 99 885033 50.0 46.4
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 1102236 50.0 48.2
86 o-Xylene 106 8.310 8.302 0.008 97 1086009 50.0 46.8
87 Styrene 104 8.324 8.324 0.000 95 1810175 50.0 46.2
88 Bromoform 173 8.503 8.502 0.001 96 346969 50.0 40.9
89 Isopropylbenzene 105 8.646 8.645 0.001 96 2697324 50.0 46.0
91 Cyclohexanone 55 8.746 8.746 0.000 94 762552 1500.0 1370.2
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 95 605928 50.0 44.2
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 80 193196 50.0 39.8
93 Bromobenzene 156 8.967 8.967 0.000 97 668865 50.0 49.1
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 84 200713 50.0 48.1
96 N-Propylbenzene 120 9.046 9.046 0.000 99 739152 50.0 45.3
97 2-Chlorotoluene 126 9.146 9.146 0.000 97 623289 50.0 45.9
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 95 2267580 50.0 45.1
99 4-Chlorotoluene 126 9.261 9.260 0.001 98 648452 50.0 45.5
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1862611 50.0 43.2
Page 534 of 1261
Report Date: 20-Nov-2023 22:17:42 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510804.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 2349349 50.0 45.1
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 520900 50.0 44.3
104 1,3-Dichlorobenzene 146 9.876 9.875 0.001 98 1234749 50.0 47.7
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 2294576 50.0 42.7
106 1,4-Dichlorobenzene 146 9.976 9.975 0.001 94 1254482 50.0 46.5
108 n-Butylbenzene 91 10.297 10.297 0.000 98 1984846 50.0 41.7
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 1157151 50.0 46.5
110 1,2-Dibromo-3-Chloropropane 157 11.113 11.112 0.001 85 129370 50.0 40.1
112 1,2,4-Trichlorobenzene 180 11.935 11.935 0.000 94 669585 50.0 45.2
113 Hexachlorobutadiene 225 12.071 12.070 0.001 96 293604 50.0 40.9
114 Naphthalene 128 12.207 12.206 0.001 97 1674933 50.0 46.0
115 1,2,3-Trichlorobenzene 180 12.428 12.428 0.000 95 532360 50.0 44.6
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 100.0
S 127 Trihalomethanes, Total 1 0 200.0 184.2
S 124 1,3-Dichloropropene, Total 1 0 100.0 94.7
S 129 1,2-Dichloroethene, Total 1 0 100.0 100.0
S 126 Total BTEX 1 0 245.8
S 125 Xylenes, Total 106 0 100.0 95.0
S 123 Xylenes, Total (URS) 1 0 100.0 95.0
Reagents:
MV-MegaMainA_00099 Amount Added: 25.00 Units: uL
MV-Gas A_00172 Amount Added: 10.00 Units: uL
mv-IS_SS_00071 Amount Added: 5.00 Units: uL Run Reagent
Page 535 of 1261
Report Date: 20-Nov-2023 22:17:43 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510804.D
Injection Date:18-Nov-2023 01:39:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ccvc Worklist Smp#:24
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:21
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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X510804[MS SCAN Chro]:Total

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Page 536 of 1261
Report Date: 09-Oct-2023 13:10:57 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508904.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:08-Oct-2023 17:17:30 ALS Bottle#:99 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:MEIERG Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:09-Oct-2023 13:10:57 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1667
First Level Reviewer: BMJ3 Date:09-Oct-2023 10:29:50
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 3.648 3.648 0.000 83 316666 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00005 Amount Added: 5.00 Units: uL
Page 537 of 1261
Report Date: 09-Oct-2023 13:10:57 Chrom Revision: 2.3 22-Sep-2023 11:33:50
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508904.D
Injection Date:08-Oct-2023 17:17:30 Instrument ID:VMS_X4
Lims ID:BFB
Client ID:
Operator ID:MEIERG ALS Bottle#:99 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350
m/z
0
2
4
6
8
10
12
14
16
18
Y ( X
1
0
0
0
0
)
Tune Spec :Average 429-431( 3.65-3.66 ) Bgrd 423( 3.60)
95
174 176
75
50 74
9468
96 177
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 19.2
75 30 to 60%of m/z 95 49.2
96 5 to 9%of m/z 95 6.3
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 81.4
175 5 to 9%of m/z 174 6.8 (8.4)
176 Greater than 95%but less than 101%of m/z 174 80.7 (99.1)
177 5 to 9%of m/z 176 5.0 (6.2)
Page 538 of 1261
Report Date: 09-Oct-2023 13:10:57 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508904.D\VMS_X4_8260.rslt\spectra.d
Injection Date:08-Oct-2023 17:17:30
Spectrum:Tune Spec :Average 429-431( 3.65-3.66 ) Bgrd 423( 3.60)
Base Peak:95.10
Minimum % Base Peak:0
Number of Points:167
m/z Y m/z Y m/z Y m/z Y
36.00 1826 82.00 917 136.00 177 194.00 107
37.00 9192 83.00 76 137.00 91 197.00 87
38.00 7932 84.00 257 138.00 21 200.00 98
39.00 2844 86.00 335 140.00 260 205.00 53
40.00 80 87.00 7714 141.00 1732 207.00 53
41.00 328 88.00 7759 142.00 436 210.00 37
42.00 173 89.00 5 143.00 1418 215.00 33
43.00 424 91.00 746 144.00 125 217.00 75
44.00 1543 92.00 4409 146.00 338 218.00 53
45.00 1596 93.00 6814 147.00 33 220.00 74
46.00 44 94.00 21136 148.00 556 220.00 45
47.00 2312 95.00 176960 149.00 106 222.00 34
48.00 1343 96.00 11175 150.00 72 223.00 35
49.00 6850 97.00 95 152.00 11 224.00 105
50.00 33912 98.00 275 153.00 7 228.00 42
51.00 10264 99.00 1 155.00 374 230.00 58
52.00 505 101.00 72 156.00 105 231.00 40
53.00 103 102.00 36 157.00 366 236.00 51
55.00 1060 103.00 254 158.00 79 237.00 62
56.00 2550 104.00 666 159.00 119 238.00 49
57.00 3721 106.00 583 160.00 37 239.00 36
58.00 17 107.00 338 162.00 72 241.00 45
60.00 1555 108.00 137 163.00 57 245.00 33
61.00 7875 110.00 29 164.00 58 246.00 46
62.00 8091 111.00 144 166.00 101 256.00 142
63.00 6192 113.00 81 168.00 135 259.00 50
64.00 406 115.00 18 169.00 262 263.00 36
66.00 12 116.00 308 170.00 209 270.00 34
67.00 955 117.00 1056 171.00 59 276.00 41
68.00 16824 118.00 445 172.00 346 277.00 41
69.00 17448 119.00 739 174.00 144064 284.00 175
70.00 1007 120.00 81 175.00 12086 289.00 37
72.00 1140 121.00 67 176.00 142720 296.00 107
Page 539 of 1261
Report Date: 09-Oct-2023 13:10:57 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508904.D\VMS_X4_8260.rslt\spectra.d
Injection Date:08-Oct-2023 17:17:30
Spectrum:Tune Spec :Average 429-431( 3.65-3.66 ) Bgrd 423( 3.60)
Base Peak:95.10
Minimum % Base Peak:0
Number of Points:167
m/z Y m/z Y m/z Y m/z Y
73.00 7774 124.00 78 177.00 8913 296.00 36
74.00 28960 125.00 19 178.00 58 302.00 37
75.00 87008 128.00 437 180.00 40 304.00 38
76.00 7501 129.00 249 182.00 37 311.00 37
77.00 1025 130.00 583 185.00 13 318.00 47
78.00 883 131.00 268 186.00 74 324.00 34
79.00 4143 132.00 52 187.00 38 338.00 37
80.00 1128 134.00 229 188.00 34 345.00 50
81.00 3885 135.00 180 191.00 37
Page 540 of 1261
Report Date: 09-Oct-2023 13:10:57 Chrom Revision: 2.3 22-Sep-2023 11:33:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508904.D
Injection Date:08-Oct-2023 17:17:30 Instrument ID:VMS_X4 Operator ID:MEIERG
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:99
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.5 0.7 0.9 1.1 1.3 1.5 1.7 1.9 2.1 2.3 2.5 2.7 2.9 3.1 3.3 3.5 3.7 3.9 4.1 4.3 4.5 4.7
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
0
0
)
X508904[MS SCAN Chro]:Total
$ B
F
B
(
3
.
6
5
5
)
Page 541 of 1261
Report Date: 20-Nov-2023 22:19:22 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510783.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:17-Nov-2023 18:23:30 ALS Bottle#:100 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:19:22 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 8.817 8.817 0.000 86 894684 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00006 Amount Added: 5.00 Units: uL
Page 542 of 1261
Report Date: 20-Nov-2023 22:19:22 Chrom Revision: 2.3 15-Nov-2023 20:54:34
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510783.D
Injection Date:17-Nov-2023 18:23:30 Instrument ID:VMS_X4
Lims ID:BFB
Client ID:
Operator ID:CF ALS Bottle#:100 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
0
0
)
Tune Spec :Average 1151-1153( 8.81-8.82 ) Bgrd 1143( 8.75)
95
174
176
75
50
74
9469
96 177
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 20.5
75 30 to 60%of m/z 95 50.4
96 5 to 9%of m/z 95 6.8
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 80.2
175 5 to 9%of m/z 174 6.4 (8.0)
176 Greater than 95%but less than 101%of m/z 174 77.2 (96.2)
177 5 to 9%of m/z 176 5.1 (6.6)
Page 543 of 1261
Report Date: 20-Nov-2023 22:19:22 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510783.D\VMS_X4_8260.rslt\spectra.d
Injection Date:17-Nov-2023 18:23:30
Spectrum:Tune Spec :Average 1151-1153( 8.81-8.82 ) Bgrd 1143( 8.75)
Base Peak:95.10
Minimum % Base Peak:0
Number of Points:94
m/z Y m/z Y m/z Y m/z Y
36.00 4796 67.00 452 97.00 1213 143.00 4195
37.00 25016 68.00 47912 103.00 415 144.00 241
38.00 21712 69.00 49480 104.00 1989 145.00 309
39.00 8627 70.00 3850 105.00 658 146.00 836
43.00 171 72.00 3282 106.00 2073 148.00 1160
44.00 2650 73.00 23504 107.00 422 150.00 318
45.00 4133 74.00 82256 113.00 169 153.00 170
46.00 182 75.00 241408 115.00 632 155.00 992
47.00 6071 76.00 21272 116.00 1723 157.00 858
48.00 3092 77.00 2713 117.00 2483 161.00 668
49.00 22608 78.00 2540 118.00 1308 172.00 598
50.00 98408 79.00 12553 119.00 2057 174.00 384384
51.00 29208 80.00 3855 125.00 277 175.00 30848
52.00 1572 81.00 11684 128.00 1813 176.00 369792
55.00 154 82.00 2783 129.00 628 177.00 24368
56.00 7721 86.00 514 130.00 1607 178.00 355
57.00 11973 87.00 21376 131.00 330 191.00 276
58.00 411 88.00 18224 133.00 465 193.00 336
59.00 166 91.00 1591 134.00 227 207.00 278
60.00 5159 92.00 12940 135.00 376 281.00 4556
61.00 23376 93.00 20216 137.00 879 282.00 1037
62.00 22200 94.00 54312 140.00 630 283.00 927
63.00 17520 95.00 479232 141.00 4388
64.00 1512 96.00 32672 142.00 859
Page 544 of 1261
Report Date: 20-Nov-2023 22:19:22 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510783.D
Injection Date:17-Nov-2023 18:23:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:100
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
Y ( X
1
0
0
0
0
0
)
X510783[MS SCAN Chro]:Total
$ B
F
B
(
8
.
8
1
7
)
Page 545 of 1261
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LB 280-633952/1-A
Matrix:X510790.DLab File ID:
Date Collected:8260DAnalysis Method:
Solid (TCLP)
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
0.5(mL)
0.25(mm)
Date Analyzed:11/17/2023 20:46
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:634482 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
10U8.071-43-2 Benzene 8.0 3.1
150U12078-93-3 2-Butanone (MEK)120 60
10U8.056-23-5 Carbon tetrachloride 8.0 5.7
10U8.0108-90-7 Chlorobenzene 8.0 4.2
10U8.067-66-3 Chloroform 8.0 3.6
10U8.0107-06-2 1,2-Dichloroethane 8.0 5.4
10U8.075-35-4 1,1-Dichloroethene 8.0 2.3
10U8.0127-18-4 Tetrachloroethene 8.0 4.0
10U4.079-01-6 Trichloroethene 4.0 3.0
20U1075-01-4 Vinyl chloride 10 5.1
%RECCAS NO.LIMITSQSURROGATE
102 78-1202037-26-5 Toluene-d8 (Surr)
116 64-12917060-07-0 1,2-Dichloroethane-d4 (Surr)
98 78-121460-00-4 4-Bromofluorobenzene (Surr)
111 79-1191868-53-7 Dibromofluoromethane (Surr)
FORM I 8260D
Page 546 of 1261
Report Date: 20-Nov-2023 22:19:13 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510790.D
Lims ID:LB 280-633952/1-A
Client ID:
Sample Type:LB
Inject. Date:17-Nov-2023 20:46:30 ALS Bottle#:7 Worklist Smp#:8
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lb 280-633952/1-a
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:20-Nov-2023 22:11:38
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 98 2125951 50.0 50.0
* 2 Chlorobenzene-d5 119 7.730 7.723 0.007 87 576733 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 1006195 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.692 4.691 0.001 93 585912 50.0 55.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 721516 50.0 57.9
$ 6 Toluene-d8 (Surr) 98 6.458 6.450 0.008 94 2517209 50.0 51.2
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 915380 50.0 48.9
$ 8 BFB 95 8.817 8.817 0.000 86 915380 NR
9 Dichlorodifluoromethane 85 1.760 ND
10 Chloromethane 50 1.939 ND
11 Vinyl chloride 62 2.039 ND
12 Bromomethane 94 2.346 2.332 0.014 1 1764 0.2325
13 Chloroethane 64 2.425 ND
15 Propene oxide 58 2.504 ND
14 Dichlorofluoromethane 67 2.596 ND
16 Trichlorofluoromethane 101 2.632 ND
17 Ethanol 45 2.754 ND
18 Ethyl ether 59 2.847 ND
19 Acrolein 56 2.968 2.961 0.007 42 1378 1.04
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 ND
21 1,1-Dichloroethene 96 3.047 ND
22 Acetone 43 3.069 3.061 0.008 98 46548 10.2
23 Isopropyl alcohol 45 3.147 ND 7
24 Iodomethane 142 3.169 3.168 0.001 54 2277 0.1810
25 Carbon disulfide 76 3.233 3.233 0.000 98 7107 0.2366
26 Acetonitrile 41 3.283 3.276 0.007 57 8382 4.92
27 Methyl acetate 43 3.290 3.290 0.000 98 28107 3.37
28 3-Chloro-1-propene 41 3.311 ND
29 Methylene Chloride 84 3.412 3.412 0.000 95 16760 1.53
30 2-Methyl-2-propanol 59 3.454 ND
31 Acrylonitrile 53 3.569 3.576 -0.007 98 2538 0.6293
32 Methyl tert-butyl ether 73 3.597 ND
Page 547 of 1261
Report Date: 20-Nov-2023 22:19:13 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510790.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
33 trans-1,2-Dichloroethene 96 3.612 ND
34 Hexane 57 3.805 ND
35 Vinyl acetate 43 3.905 ND 7
37 Isopropyl ether 87 3.926 ND
36 1,1-Dichloroethane 63 3.933 ND
38 2-Chloro-1,3-butadiene 53 3.984 ND
39 Tert-butyl ethyl ether 59 4.191 ND
40 2-Butanone (MEK) 43 4.312 ND
41 Ethyl acetate 43 4.313 4.327 -0.014 3 2033 0.2028
42 cis-1,2-Dichloroethene 96 4.341 ND
43 2,2-Dichloropropane 77 4.355 ND
44 Propionitrile 54 4.370 ND
45 sec-Butyl Alcohol 45 4.420 ND
46 Methacrylonitrile 41 4.484 ND
47 Chlorobromomethane 128 4.520 ND
48 Tetrahydrofuran 42 4.527 ND
49 Chloroform 83 4.577 ND
50 1,1,1-Trichloroethane 97 4.720 ND
51 Cyclohexane 56 4.777 ND
52 1,1-Dichloropropene 75 4.834 ND
53 Carbon tetrachloride 117 4.842 ND
54 Isobutyl alcohol 41 4.842 ND U
57 Tert-amyl methyl ether 73 4.942 ND
55 Benzene 78 4.992 ND
56 1,2-Dichloroethane 62 5.021 5.013 0.008 81 2732 0.1925
58 n-Heptane 43 5.170 ND
59 n-Butanol 56 5.335 ND
60 Trichloroethene 95 5.471 ND
61 2-Pentanone 43 5.578 ND
62 Methylcyclohexane 55 5.671 ND
63 1,2-Dichloropropane 63 5.678 ND
64 Methyl methacrylate 100 5.678 ND
65 1,4-Dioxane 88 5.721 ND
66 Dibromomethane 93 5.750 ND
67 Dichlorobromomethane 83 5.871 ND
68 2-Nitropropane 41 6.043 ND
69 2-Chloroethyl vinyl ether 63 6.071 ND
70 cis-1,3-Dichloropropene 75 6.222 ND
71 4-Methyl-2-pentanone (MIBK) 43 6.322 ND
72 Toluene 91 6.515 ND
73 trans-1,3-Dichloropropene 75 6.686 ND
74 Ethyl methacrylate 69 6.701 ND
75 1,1,2-Trichloroethane 97 6.858 ND
76 Tetrachloroethene 164 6.951 ND
77 1,3-Dichloropropane 76 7.008 ND
78 2-Hexanone 43 7.022 ND
79 Chlorodibromomethane 129 7.201 ND
80 Ethylene Dibromide 107 7.323 ND
81 1-Chlorohexane 91 7.709 ND 7
82 Chlorobenzene 112 7.752 ND
83 1,1,1,2-Tetrachloroethane 131 7.823 ND
84 Ethylbenzene 106 7.830 ND
Page 548 of 1261
Report Date: 20-Nov-2023 22:19:13 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510790.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
85 m-Xylene & p-Xylene 106 7.945 ND
86 o-Xylene 106 8.302 ND
87 Styrene 104 8.324 ND
88 Bromoform 173 8.502 ND
89 Isopropylbenzene 105 8.645 ND 7
90 cis-1,4-Dichloro-2-butene 53 8.696 ND
91 Cyclohexanone 55 8.746 ND 7
92 1,1,2,2-Tetrachloroethane 83 8.931 ND
94 trans-1,4-Dichloro-2-butene 53 8.967 ND
93 Bromobenzene 156 8.967 ND 7
95 1,2,3-Trichloropropane 110 8.996 ND
96 N-Propylbenzene 120 9.046 ND
97 2-Chlorotoluene 126 9.146 ND
98 1,3,5-Trimethylbenzene 105 9.218 ND 7
99 4-Chlorotoluene 126 9.260 ND
101 Pentachloroethane 167 9.411 ND
100 tert-Butylbenzene 119 9.525 ND
102 1,2,4-Trimethylbenzene 105 9.582 ND 7
103 sec-Butylbenzene 134 9.747 ND
104 1,3-Dichlorobenzene 146 9.876 9.875 0.001 91 5461 0.2192
105 4-Isopropyltoluene 119 9.890 ND
106 1,4-Dichlorobenzene 146 9.976 9.975 0.001 83 6190 0.2383
107 1,2,3-Trimethylbenzene 105 9.990 ND
108 n-Butylbenzene 91 10.297 ND 7
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 91 4708 0.1966
110 1,2-Dibromo-3-Chloropropane 157 11.113 11.112 0.001 1 731 0.2351
111 1,3,5-Trichlorobenzene 180 11.298 ND
112 1,2,4-Trichlorobenzene 180 11.935 11.935 0.000 89 9030 0.6329
113 Hexachlorobutadiene 225 12.071 12.070 0.001 83 3506 0.5069
114 Naphthalene 128 12.207 12.206 0.001 97 43984 1.26
115 1,2,3-Trichlorobenzene 180 12.428 12.428 0.000 94 15008 1.31
116 Ethylene oxide TIC 1 0.000 ND
117 t-Amyl alcohol 1 0.000 ND
118 Ethyl acrylate 55 0.000 ND
119 1-Chloro-1-fluoroethane TIC 1 0.000 ND
120 Tetrahydrothiophene TIC 1 0.000 ND
121 Propene oxide TIC 58 5.334 ND
S 122 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7
S 128 TAH 1 0 0
S 127 Trihalomethanes, Total 1 0.000 ND 7
S 124 1,3-Dichloropropene, Total 1 0.000 ND 7
S 129 1,2-Dichloroethene, Total 1 0.000 ND 7
S 126 Total BTEX 1 0.000 ND 7
S 125 Xylenes, Total 106 0.000 ND 7
S 123 Xylenes, Total (URS) 1 0.000 ND 7
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
7 - Failed Limit of Detection
Page 549 of 1261
Report Date: 20-Nov-2023 22:19:13 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Review Flags
U - Marked Undetected
Reagents:
mv-IS_SS_00071 Amount Added: 5.00 Units: uL Run Reagent
Page 550 of 1261
Report Date: 20-Nov-2023 22:19:13 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510790.D
Injection Date:17-Nov-2023 20:46:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:LB 280-633952/1-A Worklist Smp#:8
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
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X510790[MS SCAN Chro]:Total

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Page 551 of 1261
Report Date: 20-Nov-2023 22:19:13 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510790.D
Lims ID:LB 280-633952/1-A
Client ID:
Sample Type:LB
Inject. Date:17-Nov-2023 20:46:30 ALS Bottle#:7 Worklist Smp#:8
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lb 280-633952/1-a
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:20-Nov-2023 22:11:38
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 55.6 111.23
$5 1,2-Dichloroethane-d4 (Surr)50.0 57.9 115.89
$6 Toluene-d8 (Surr)50.0 51.2 102.33
$7 4-Bromofluorobenzene (Surr)50.0 48.9 97.89
Page 552 of 1261
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-633952/2-A
Matrix:X510785.DLab File ID:
Date Collected:8260DAnalysis Method:
Solid (TCLP)
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
0.5(mL)
0.25(mm)
Date Analyzed:11/17/2023 19:04
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:634482 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
1055171-43-2 Benzene 8.0 3.1
150193078-93-3 2-Butanone (MEK)120 60
1048356-23-5 Carbon tetrachloride 8.0 5.7
10486108-90-7 Chlorobenzene 8.0 4.2
1054867-66-3 Chloroform 8.0 3.6
10556107-06-2 1,2-Dichloroethane 8.0 5.4
1053975-35-4 1,1-Dichloroethene 8.0 2.3
10505127-18-4 Tetrachloroethene 8.0 4.0
1048279-01-6 Trichloroethene 4.0 3.0
2064575-01-4 Vinyl chloride 10 5.1
%RECCAS NO.LIMITSQSURROGATE
101 78-1202037-26-5 Toluene-d8 (Surr)
113 64-12917060-07-0 1,2-Dichloroethane-d4 (Surr)
99 78-121460-00-4 4-Bromofluorobenzene (Surr)
110 79-1191868-53-7 Dibromofluoromethane (Surr)
FORM I 8260D
Page 553 of 1261
Report Date: 20-Nov-2023 22:19:17 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510785.D
Lims ID:LCS 280-633952/2-A
Client ID:
Sample Type:LCS
Inject. Date:17-Nov-2023 19:04:30 ALS Bottle#:2 Worklist Smp#:6
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcs 280-633952/2-a
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:17-Nov-2023 19:23:57
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 99 2235343 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 89 602330 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 1036998 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 93 606888 50.0 54.8
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 742551 50.0 56.7
$ 6 Toluene-d8 (Surr) 98 6.450 6.450 0.000 94 2606838 50.0 50.7
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 88 951414 50.0 49.4
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 738979 50.0 64.3
10 Chloromethane 50 1.938 1.939 -0.001 100 840547 50.0 61.9
11 Vinyl chloride 62 2.039 2.039 0.000 99 807827 50.0 64.5
12 Bromomethane 94 2.332 2.332 0.000 91 433607 50.0 54.4
13 Chloroethane 64 2.425 2.425 0.000 100 485532 50.0 58.4
14 Dichlorofluoromethane 67 2.603 2.596 0.007 98 1266417 50.0 57.7
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 951764 50.0 61.1
18 Ethyl ether 59 2.847 2.847 0.000 93 495788 50.0 51.1
19 Acrolein 56 2.961 2.961 0.000 99 820132 493.8 588.8
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 94 411954 50.0 56.1
21 1,1-Dichloroethene 96 3.047 3.047 0.000 97 507245 50.0 53.9
22 Acetone 43 3.061 3.061 0.000 99 660330 200.0 202.5
24 Iodomethane 142 3.168 3.168 0.000 99 698379 50.0 52.8
25 Carbon disulfide 76 3.233 3.233 0.000 99 1739278 50.0 55.1
27 Methyl acetate 43 3.290 3.290 0.000 98 822483 100.0 101.8
28 3-Chloro-1-propene 41 3.311 3.311 0.000 91 1038209 50.0 55.2
29 Methylene Chloride 84 3.411 3.412 -0.001 95 622885 50.0 54.0
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 99 485679 500.0 452.9
31 Acrylonitrile 53 3.576 3.576 0.000 98 2179690 500.0 514.0
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 96 1628420 50.0 54.8
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 586423 50.0 51.2
34 Hexane 57 3.805 3.805 0.000 95 819869 50.0 46.7
35 Vinyl acetate 43 3.905 3.905 0.000 98 2497075 100.0 107.5
36 1,1-Dichloroethane 63 3.933 3.933 0.000 97 1139143 50.0 54.8
40 2-Butanone (MEK) 43 4.320 4.312 0.008 100 1004662 200.0 193.1
Page 554 of 1261
Report Date: 20-Nov-2023 22:19:17 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510785.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 651497 50.0 52.2
43 2,2-Dichloropropane 77 4.355 4.355 0.000 88 973588 50.0 53.1
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 984629 1200.0 1062.9
47 Chlorobromomethane 128 4.520 4.520 0.000 97 285533 50.0 53.2
48 Tetrahydrofuran 42 4.527 4.527 0.000 88 341193 100.0 97.9
49 Chloroform 83 4.577 4.577 0.000 95 1065893 50.0 54.8
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 98 904636 50.0 53.4
51 Cyclohexane 56 4.784 4.777 0.007 92 1089199 50.0 52.6
52 1,1-Dichloropropene 75 4.834 4.834 0.000 96 862913 50.0 55.2
53 Carbon tetrachloride 117 4.841 4.842 -0.001 96 738771 50.0 48.3
54 Isobutyl alcohol 41 4.841 4.842 -0.001 93 437363 1250.0 1092.6
55 Benzene 78 4.992 4.992 0.000 98 2536015 50.0 55.1
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 829239 50.0 55.6
58 n-Heptane 43 5.170 5.170 0.000 95 697299 50.0 50.8
60 Trichloroethene 95 5.471 5.471 0.000 99 618548 50.0 48.2
61 2-Pentanone 43 5.578 5.578 0.000 99 1251041 160.0 152.8
62 Methylcyclohexane 55 5.671 5.671 0.000 92 771666 50.0 48.1
63 1,2-Dichloropropane 63 5.678 5.678 0.000 96 675767 50.0 54.7
65 1,4-Dioxane 88 5.721 5.721 0.000 97 142640 1000.0 1027.1
66 Dibromomethane 93 5.750 5.750 0.000 96 348206 50.0 53.4
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 783421 50.0 50.1
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 92 383762 50.0 52.6
70 cis-1,3-Dichloropropene 75 6.221 6.222 -0.001 94 1021827 50.0 48.8
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 2038283 200.0 187.4
72 Toluene 91 6.515 6.515 0.000 98 2683750 50.0 53.1
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 98 911164 50.0 51.8
74 Ethyl methacrylate 69 6.701 6.701 0.000 90 733738 50.0 44.9
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 93 502354 50.0 51.6
76 Tetrachloroethene 164 6.958 6.951 0.007 98 487206 50.0 50.5
77 1,3-Dichloropropane 76 7.008 7.008 0.000 95 923271 50.0 49.5
78 2-Hexanone 43 7.022 7.022 0.000 97 1413856 200.0 167.2
79 Chlorodibromomethane 129 7.201 7.201 0.000 91 537108 50.0 42.5
80 Ethylene Dibromide 107 7.315 7.323 -0.008 99 503633 50.0 46.6
81 1-Chlorohexane 91 7.709 7.709 0.000 97 632125 40.0 36.0
82 Chlorobenzene 112 7.752 7.752 0.000 93 1648326 50.0 48.6
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 95 547245 50.0 47.1
84 Ethylbenzene 106 7.830 7.830 0.000 99 920466 50.0 48.5
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 1148286 50.0 50.5
86 o-Xylene 106 8.309 8.302 0.007 97 1122980 50.0 48.7
87 Styrene 104 8.324 8.324 0.000 95 1884054 50.0 48.4
88 Bromoform 173 8.502 8.502 0.000 96 348475 50.0 41.3
89 Isopropylbenzene 105 8.645 8.645 0.000 96 2791800 50.0 48.0
91 Cyclohexanone 55 8.746 8.746 0.000 93 556677 1500.0 1004.5
92 1,1,2,2-Tetrachloroethane 83 8.931 8.931 0.000 95 634928 50.0 46.6
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 62 196547 50.0 40.8
93 Bromobenzene 156 8.967 8.967 0.000 97 689004 50.0 50.9
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 87 189313 50.0 45.7
96 N-Propylbenzene 120 9.046 9.046 0.000 99 766073 50.0 47.3
97 2-Chlorotoluene 126 9.146 9.146 0.000 95 637905 50.0 47.3
98 1,3,5-Trimethylbenzene 105 9.217 9.218 -0.001 95 2341289 50.0 46.9
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 683347 50.0 48.3
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1931328 50.0 45.1
Page 555 of 1261
Report Date: 20-Nov-2023 22:19:17 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510785.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 2460029 50.0 47.6
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 542555 50.0 46.5
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 1300357 50.0 50.6
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 2404344 50.0 45.1
106 1,4-Dichlorobenzene 146 9.968 9.975 -0.007 93 1332037 50.0 49.7
108 n-Butylbenzene 91 10.297 10.297 0.000 98 2140639 50.0 45.3
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 1220156 50.0 49.4
110 1,2-Dibromo-3-Chloropropane 157 11.112 11.112 0.000 80 121919 50.0 38.0
112 1,2,4-Trichlorobenzene 180 11.935 11.935 0.000 93 697802 50.0 47.5
113 Hexachlorobutadiene 225 12.070 12.070 0.000 96 318317 50.0 44.7
114 Naphthalene 128 12.206 12.206 0.000 98 1655202 50.0 45.8
115 1,2,3-Trichlorobenzene 180 12.428 12.428 0.000 96 542473 50.0 45.8
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 103.4
S 127 Trihalomethanes, Total 1 0 200.0 188.7
S 124 1,3-Dichloropropene, Total 1 0 100.0 100.6
S 129 1,2-Dichloroethene, Total 1 0 100.0 103.4
S 125 Xylenes, Total 106 0 100.0 99.2
S 123 Xylenes, Total (URS) 1 0 100.0 99.2
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMainA_00099 Amount Added: 25.00 Units: uL
MV-Gas A_00172 Amount Added: 10.00 Units: uL
mv-IS_SS_00071 Amount Added: 5.00 Units: uL Run Reagent
Page 556 of 1261
Report Date: 20-Nov-2023 22:19:17 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510785.D
Injection Date:17-Nov-2023 19:04:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:LCS 280-633952/2-A Worklist Smp#:6
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:2
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 557 of 1261
Report Date: 20-Nov-2023 22:19:17 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510785.D
Lims ID:LCS 280-633952/2-A
Client ID:
Sample Type:LCS
Inject. Date:17-Nov-2023 19:04:30 ALS Bottle#:2 Worklist Smp#:6
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcs 280-633952/2-a
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
First Level Reviewer: AK2J Date:17-Nov-2023 19:23:57
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 54.8 109.58
$5 1,2-Dichloroethane-d4 (Surr)50.0 56.7 113.43
$6 Toluene-d8 (Surr)50.0 50.7 101.47
$7 4-Bromofluorobenzene (Surr)50.0 49.4 98.72
Page 558 of 1261
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-633952/3-A
Matrix:X510786.DLab File ID:
Date Collected:8260DAnalysis Method:
Solid (TCLP)
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
0.5(mL)
0.25(mm)
Date Analyzed:11/17/2023 19:24
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:634482 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
1055471-43-2 Benzene 8.0 3.1
150198078-93-3 2-Butanone (MEK)120 60
1049556-23-5 Carbon tetrachloride 8.0 5.7
10493108-90-7 Chlorobenzene 8.0 4.2
1054967-66-3 Chloroform 8.0 3.6
10563107-06-2 1,2-Dichloroethane 8.0 5.4
1054575-35-4 1,1-Dichloroethene 8.0 2.3
10515127-18-4 Tetrachloroethene 8.0 4.0
1048379-01-6 Trichloroethene 4.0 3.0
2064975-01-4 Vinyl chloride 10 5.1
%RECCAS NO.LIMITSQSURROGATE
101 78-1202037-26-5 Toluene-d8 (Surr)
112 64-12917060-07-0 1,2-Dichloroethane-d4 (Surr)
97 78-121460-00-4 4-Bromofluorobenzene (Surr)
111 79-1191868-53-7 Dibromofluoromethane (Surr)
FORM I 8260D
Page 559 of 1261
Report Date: 20-Nov-2023 22:19:16 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510786.D
Lims ID:LCSD 280-633952/3-A
Client ID:
Sample Type:LCSD
Inject. Date:17-Nov-2023 19:24:30 ALS Bottle#:3 Worklist Smp#:7
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcsd 280-633952/3-a
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.199 5.199 0.000 99 2215712 50.0 50.0
* 2 Chlorobenzene-d5 119 7.723 7.723 0.000 89 596480 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.947 9.947 0.000 96 1023110 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.691 4.691 0.000 92 611642 50.0 55.7
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.956 4.956 0.000 0 726714 50.0 56.0
$ 6 Toluene-d8 (Surr) 98 6.458 6.450 0.008 94 2558650 50.0 50.3
$ 7 4-Bromofluorobenzene (Surr) 95 8.817 8.817 0.000 89 926283 50.0 48.7
9 Dichlorodifluoromethane 85 1.760 1.760 0.000 100 731557 50.0 64.2
10 Chloromethane 50 1.939 1.939 0.000 100 831102 50.0 61.7
11 Vinyl chloride 62 2.039 2.039 0.000 99 805234 50.0 64.9
12 Bromomethane 94 2.332 2.332 0.000 91 432493 50.0 54.7
13 Chloroethane 64 2.425 2.425 0.000 100 490097 50.0 59.5
14 Dichlorofluoromethane 67 2.604 2.596 0.008 98 1254855 50.0 57.6
16 Trichlorofluoromethane 101 2.632 2.632 0.000 99 934451 50.0 60.5
18 Ethyl ether 59 2.847 2.847 0.000 94 495136 50.0 51.5
19 Acrolein 56 2.961 2.961 0.000 100 838340 493.8 607.2
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.040 3.040 0.000 96 426345 50.0 58.6
21 1,1-Dichloroethene 96 3.047 3.047 0.000 98 508111 50.0 54.5
22 Acetone 43 3.061 3.061 0.000 99 666710 200.0 206.4
24 Iodomethane 142 3.168 3.168 0.000 99 689256 50.0 52.6
25 Carbon disulfide 76 3.233 3.233 0.000 99 1733640 50.0 55.4
27 Methyl acetate 43 3.290 3.290 0.000 98 836408 100.0 104.4
28 3-Chloro-1-propene 41 3.319 3.311 0.008 91 1041362 50.0 55.9
29 Methylene Chloride 84 3.412 3.412 0.000 95 630811 50.0 55.2
30 2-Methyl-2-propanol 59 3.454 3.454 0.000 100 511412 500.0 481.1
31 Acrylonitrile 53 3.576 3.576 0.000 98 2206034 500.0 524.8
32 Methyl tert-butyl ether 73 3.597 3.597 0.000 96 1660807 50.0 56.4
33 trans-1,2-Dichloroethene 96 3.612 3.612 0.000 97 591286 50.0 52.1
34 Hexane 57 3.805 3.805 0.000 94 821235 50.0 47.3
35 Vinyl acetate 43 3.905 3.905 0.000 98 2530623 100.0 109.9
36 1,1-Dichloroethane 63 3.934 3.933 0.001 97 1142649 50.0 55.4
40 2-Butanone (MEK) 43 4.320 4.312 0.008 100 1023554 200.0 198.5
42 cis-1,2-Dichloroethene 96 4.341 4.341 0.000 86 650207 50.0 52.6
Page 560 of 1261
Report Date: 20-Nov-2023 22:19:16 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510786.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
43 2,2-Dichloropropane 77 4.355 4.355 0.000 88 954381 50.0 52.5
45 sec-Butyl Alcohol 45 4.420 4.420 0.000 99 995705 1200.0 1084.4
47 Chlorobromomethane 128 4.520 4.520 0.000 98 294776 50.0 55.5
48 Tetrahydrofuran 42 4.527 4.527 0.000 87 350241 100.0 101.4
49 Chloroform 83 4.577 4.577 0.000 95 1058453 50.0 54.9
50 1,1,1-Trichloroethane 97 4.720 4.720 0.000 99 911293 50.0 54.3
51 Cyclohexane 56 4.784 4.777 0.007 92 1091820 50.0 53.2
52 1,1-Dichloropropene 75 4.834 4.834 0.000 97 878734 50.0 56.8
53 Carbon tetrachloride 117 4.842 4.842 0.000 96 750203 50.0 49.5
54 Isobutyl alcohol 41 4.842 4.842 0.000 95 448187 1250.0 1129.5
55 Benzene 78 4.992 4.992 0.000 97 2525974 50.0 55.4
56 1,2-Dichloroethane 62 5.013 5.013 0.000 97 832466 50.0 56.3
58 n-Heptane 43 5.171 5.170 0.001 95 701101 50.0 51.6
60 Trichloroethene 95 5.478 5.471 0.007 98 614022 50.0 48.3
61 2-Pentanone 43 5.578 5.578 0.000 99 1272561 160.0 156.8
62 Methylcyclohexane 55 5.671 5.671 0.000 91 776886 50.0 48.9
63 1,2-Dichloropropane 63 5.678 5.678 0.000 95 659118 50.0 53.8
65 1,4-Dioxane 88 5.721 5.721 0.000 97 148473 1000.0 1078.5
66 Dibromomethane 93 5.750 5.750 0.000 97 345382 50.0 53.4
67 Dichlorobromomethane 83 5.871 5.871 0.000 99 791525 50.0 51.0
69 2-Chloroethyl vinyl ether 63 6.071 6.071 0.000 92 381622 50.0 52.8
70 cis-1,3-Dichloropropene 75 6.222 6.222 0.000 94 1013436 50.0 48.9
71 4-Methyl-2-pentanone (MIBK) 43 6.322 6.322 0.000 97 2070146 200.0 192.1
72 Toluene 91 6.515 6.515 0.000 98 2706896 50.0 54.0
73 trans-1,3-Dichloropropene 75 6.686 6.686 0.000 98 924957 50.0 53.1
74 Ethyl methacrylate 69 6.701 6.701 0.000 91 723181 50.0 44.6
75 1,1,2-Trichloroethane 97 6.858 6.858 0.000 92 501984 50.0 52.0
76 Tetrachloroethene 164 6.958 6.951 0.007 99 491903 50.0 51.5
77 1,3-Dichloropropane 76 7.008 7.008 0.000 98 921691 50.0 49.9
78 2-Hexanone 43 7.022 7.022 0.000 97 1434600 200.0 171.4
79 Chlorodibromomethane 129 7.201 7.201 0.000 91 549669 50.0 43.9
80 Ethylene Dibromide 107 7.323 7.323 0.000 98 517856 50.0 48.4
81 1-Chlorohexane 91 7.709 7.709 0.000 98 634688 40.0 36.5
82 Chlorobenzene 112 7.752 7.752 0.000 93 1653166 50.0 49.3
83 1,1,1,2-Tetrachloroethane 131 7.823 7.823 0.000 94 554882 50.0 48.2
84 Ethylbenzene 106 7.830 7.830 0.000 99 923250 50.0 49.2
85 m-Xylene & p-Xylene 106 7.945 7.945 0.000 0 1164544 50.0 51.7
86 o-Xylene 106 8.309 8.302 0.007 97 1132633 50.0 49.6
87 Styrene 104 8.324 8.324 0.000 94 1886015 50.0 48.9
88 Bromoform 173 8.503 8.502 0.001 96 348912 50.0 41.8
89 Isopropylbenzene 105 8.646 8.645 0.001 96 2828306 50.0 49.3
91 Cyclohexanone 55 8.746 8.746 0.000 95 577434 1500.0 1052.6
92 1,1,2,2-Tetrachloroethane 83 8.932 8.931 0.001 95 659046 50.0 49.1
94 trans-1,4-Dichloro-2-butene 53 8.967 8.967 0.000 59 194599 50.0 40.9
93 Bromobenzene 156 8.967 8.967 0.000 96 703611 50.0 52.7
95 1,2,3-Trichloropropane 110 8.996 8.996 0.000 86 197733 50.0 48.4
96 N-Propylbenzene 120 9.046 9.046 0.000 99 772761 50.0 48.3
97 2-Chlorotoluene 126 9.146 9.146 0.000 95 653481 50.0 49.1
98 1,3,5-Trimethylbenzene 105 9.218 9.218 0.000 95 2383748 50.0 48.4
99 4-Chlorotoluene 126 9.260 9.260 0.000 98 685527 50.0 49.1
100 tert-Butylbenzene 119 9.525 9.525 0.000 94 1943996 50.0 46.0
102 1,2,4-Trimethylbenzene 105 9.582 9.582 0.000 98 2484432 50.0 48.7
Page 561 of 1261
Report Date: 20-Nov-2023 22:19:16 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510786.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
103 sec-Butylbenzene 134 9.747 9.747 0.000 95 558458 50.0 48.5
104 1,3-Dichlorobenzene 146 9.875 9.875 0.000 98 1315095 50.0 51.9
105 4-Isopropyltoluene 119 9.890 9.890 0.000 97 2443068 50.0 46.5
106 1,4-Dichlorobenzene 146 9.975 9.975 0.000 94 1338790 50.0 50.7
108 n-Butylbenzene 91 10.297 10.297 0.000 98 2154935 50.0 46.2
109 1,2-Dichlorobenzene 146 10.333 10.333 0.000 97 1225957 50.0 50.4
110 1,2-Dibromo-3-Chloropropane 157 11.105 11.112 -0.007 84 132295 50.0 41.8
112 1,2,4-Trichlorobenzene 180 11.935 11.935 0.000 93 720212 50.0 49.6
113 Hexachlorobutadiene 225 12.070 12.070 0.000 96 329309 50.0 46.8
114 Naphthalene 128 12.206 12.206 0.000 97 1725738 50.0 48.4
115 1,2,3-Trichlorobenzene 180 12.428 12.428 0.000 96 558657 50.0 47.8
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 104.6
S 127 Trihalomethanes, Total 1 0 200.0 191.6
S 124 1,3-Dichloropropene, Total 1 0 100.0 101.9
S 129 1,2-Dichloroethene, Total 1 0 100.0 104.6
S 125 Xylenes, Total 106 0 100.0 101.3
S 123 Xylenes, Total (URS) 1 0 100.0 101.3
Reagents:
MV-MegaMainA_00099 Amount Added: 25.00 Units: uL
MV-Gas A_00172 Amount Added: 10.00 Units: uL
mv-IS_SS_00071 Amount Added: 5.00 Units: uL Run Reagent
Page 562 of 1261
Report Date: 20-Nov-2023 22:19:16 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510786.D
Injection Date:17-Nov-2023 19:24:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:LCSD 280-633952/3-A Worklist Smp#:7
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 563 of 1261
Report Date: 20-Nov-2023 22:19:16 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\X510786.D
Lims ID:LCSD 280-633952/3-A
Client ID:
Sample Type:LCSD
Inject. Date:17-Nov-2023 19:24:30 ALS Bottle#:3 Worklist Smp#:7
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcsd 280-633952/3-a
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20231117-127813.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:20-Nov-2023 22:18:33 Calib Date:08-Oct-2023 23:50:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20231008-126292.b\X508923.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1633
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 55.7 111.41
$5 1,2-Dichloroethane-d4 (Surr)50.0 56.0 111.99
$6 Toluene-d8 (Surr)50.0 50.3 100.57
$7 4-Bromofluorobenzene (Surr)50.0 48.7 97.41
Page 564 of 1261
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_X4
628924
Start Date:
End Date:10/09/2023 03:55
10/08/2023 17:17
BFB 280-628924/1 RXI-624SilMS 0.25(mm)110/08/2023 17:17 X508904.D
IC 280-628924/2 RXI-624SilMS 0.25(mm)110/08/2023 17:38 X508905.D
IC 280-628924/3 RXI-624SilMS 0.25(mm)110/08/2023 18:03 X508906.D
IC 280-628924/4 RXI-624SilMS 0.25(mm)110/08/2023 18:24 X508907.D
IC 280-628924/5 RXI-624SilMS 0.25(mm)110/08/2023 18:44 X508908.D
IC 280-628924/6 RXI-624SilMS 0.25(mm)110/08/2023 19:04 X508909.D
ICIS 280-628924/7 RXI-624SilMS 0.25(mm)110/08/2023 19:25 X508910.D
IC 280-628924/8 RXI-624SilMS 0.25(mm)110/08/2023 19:45 X508911.D
IC 280-628924/9 RXI-624SilMS 0.25(mm)110/08/2023 20:06 X508912.D
IC 280-628924/10 RXI-624SilMS 0.25(mm)110/08/2023 20:26 X508913.D
ICV 280-628924/11 RXI-624SilMS 0.25(mm)110/08/2023 21:07 X508915.D
IC 280-628924/12 RXI-624SilMS 0.25(mm)110/08/2023 21:27
IC 280-628924/13 RXI-624SilMS 0.25(mm)110/08/2023 21:48
IC 280-628924/14 RXI-624SilMS 0.25(mm)110/08/2023 22:08
IC 280-628924/15 RXI-624SilMS 0.25(mm)110/08/2023 22:29
IC 280-628924/16 RXI-624SilMS 0.25(mm)110/08/2023 22:49
IC 280-628924/17 RXI-624SilMS 0.25(mm)110/08/2023 23:09
IC 280-628924/18 RXI-624SilMS 0.25(mm)110/08/2023 23:30
IC 280-628924/19 RXI-624SilMS 0.25(mm)110/08/2023 23:50
ICV 280-628924/20 RXI-624SilMS 0.25(mm)110/09/2023 00:11 X508924.D
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 00:31
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 01:12
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 01:32
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 01:52
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 02:13
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 02:33
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 02:53
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 03:14
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 03:35
ZZZZZ RXI-624SilMS 0.25(mm)110/09/2023 03:55
8260D
Page 565 of 1261
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_X4
634482
Start Date:
End Date:11/18/2023 01:39
11/17/2023 18:23
BFB 280-634482/1 RXI-624SilMS 0.25(mm)111/17/2023 18:23 X510783.D
CCV 280-634482/2 RXI-624SilMS 0.25(mm)111/17/2023 18:43 X510784.D
LCS 280-633952/2-A RXI-624SilMS 0.25(mm)111/17/2023 19:04 X510785.D
LCSD 280-633952/3-A RXI-624SilMS 0.25(mm)111/17/2023 19:24 X510786.D
LB 280-633952/1-A RXI-624SilMS 0.25(mm)111/17/2023 20:46 X510790.D
ZZZZZ RXI-624SilMS 0.25(mm)111/18/2023 00:15
ZZZZZ RXI-624SilMS 0.25(mm)111/18/2023 00:36
280-184424-1 ST071-SoilIDW-1109202
3 RXI-624SilMS 0.25(mm)111/18/2023 00:57 X510802.D
ZZZZZ RXI-624SilMS 0.25(mm)111/18/2023 01:18
CCVC 280-634482/24 RXI-624SilMS 0.25(mm)111/18/2023 01:39 X510804.D
8260D
Page 566 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Meier, Greg P10/08/23 17:17628924
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount Cal Dil Std
00249
mv-Cent BFB
00005
mv-Cent IS
00008
MV-Gas A 00168
2 uL 2 uL 5 uL8260DBFB
280-628924/1
5 mL 5 mL 5 uL8260DIC 280-628924/2
5 mL 5 mL 10 uL8260DIC 280-628924/3
5 mL 5 mL 20 uL8260DIC 280-628924/4
5 mL 5 mL 50 uL8260DIC 280-628924/5
5 mL 5 mL 2 uL8260DIC 280-628924/6
5 mL 5 mL 10 uL8260DICIS
280-628924/7
5 mL 5 mL 15 uL8260DIC 280-628924/8
5 mL 5 mL 20 uL8260DIC 280-628924/9
5 mL 5 mL 40 uL8260DIC
280-628924/10
5 mL 5 mL8260DICV
280-628924/11
5 mL 5 mL 5 uL8260DICV
280-628924/20
Lab Sample ID Client Sample ID Method Chain Basis MV-Gas B 00148 mv-IS_SS 00066 MV-MegaMain B
00092
MV-MegaMainA
00096
MV-Supp B 00066
8260DBFB
280-628924/1
5 uL8260DIC 280-628924/2
5 uL8260DIC 280-628924/3
5 uL8260DIC 280-628924/4
5 uL8260DIC 280-628924/5
5 uL 5 uL8260DIC 280-628924/6
5 uL 25 uL8260DICIS
280-628924/7
5 uL 37.5 uL8260DIC 280-628924/8
5 uL 50 uL8260DIC 280-628924/9
5 uL 100 uL8260DIC
280-628924/10
10 uL 5 uL 25 uL8260DICV
280-628924/11
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28260D
Page 567 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Meier, Greg P10/08/23 17:17628924
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample ID Method Chain Basis MV-Gas B 00148 mv-IS_SS 00066 MV-MegaMain B
00092
MV-MegaMainA
00096
MV-Supp B 00066
25 uL8260DICV
280-628924/20
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28260D
Page 568 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/15/23 19:55
11/14/23 23:33633952
Batch Method:
Eurofins Denver
1311
Lab Sample ID Client Sample ID Method Chain Basis ExtractFluid
T11311, 8260DLB 280-633952/1
T11311, 8260DLCS
280-633952/2
T11311, 8260DLCSD
280-633952/3
ST071-SoilIDW-11
092023
T11311, 8260D P280-184424-C-1
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28260D
Page 569 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/15/23 19:55
11/14/23 23:33633952
Batch Method:
Eurofins Denver
1311
Batch Notes
Thermometer ID 311846
First Start time 11/14/2023 23:33
First End time 11/15/2023 16:20
Rotator ID ZHE#1 ZHE#3
Tumbler Rotations per Minute 29 29
Balance is Level? (Y/N)yes
TCLP Fluid pH 4.94 SU
TCLP Fluid 1 ID T1_00469
Uncorrected Minimum Temperature 24.1 Celsius
Minumum Temperature 24.3 Celsius
Uncorrected Maximum Temperature 22.5 Celsius
Maximum Temperature 22.7 Celsius
pH Buffer 1 ID 2271
pH Buffer 2 ID 223591
pH Buffer 3 ID 2133
pH Buffer 4 ID 221687
pH Meter Calibration Slope 97.7
Uncorrected Initial Room Temperature 24.1 Degrees C
Corrected Initial Room Temperature 24.3 Degrees C
Filtration Start Time 11/15/2023 19:11
Filtration End Time 11/15/2023 19:55
Analyst ID - Filtration DB
Filtration Date 11/15/2023
Batch Comment DV-IP-0011
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28260D
Page 570 of 1261
D002034661 Started 11-14-2023, Finished 11-15-2023.ltd
Recorder has been downloaded 11/15/2023 5:17:33 PM (UTC -07:00, daylight )me)
Alarm Status
Lower
Upper
OK
OK
Recorder Configura on
Start type :
Start delay :
Interval :
Alert indicator :
OK indicator :
Push bu on start
1 Minute
10 Minutes
Enabled lower & upper
Enabled
Temperature alarms
Lower :
Upper :
20.8 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
24.8 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
Recorder Info
Serial # :
User ID :
D002034661
Tumble Room (0.2)
Model :TRIX-8 Ba6ery :OK Trip # :34
Recorded Data
First reading :
Last reading :
Elapsed Time :
Total readings :
First evaluated :
Last evaluated :
Evaluated Time :
Evaluated Readings :
11/14/2023 11:32:59 PM
11/15/2023 4:12:59 PM
16 Hours, 40 Minutes
152
11/14/2023 11:32:59 PM
11/15/2023 4:12:59 PM
16 Hours, 40 Minutes
101
Temperature sta)s)cs
Lowest :
Highest :
Average reading :
Standard Devia)on (S) :
Mean Kine)c Temperature
22.5 °C
@ 11/15/2023 8:12:59 AM
24.1 °C
@ 11/14/2023 11:32:59 PM
23.1 °C
0.5 °C
23.13 °C
Lower Alarm
Triggered :
Time below :
Occurrences :
°C - Minutes below :
(none)
(none)
0
0.00
Upper Alarm
Triggered :
Time above :
Occurrences :
°C - Minutes above :
(none)
(none)
0
0.00
Readings (°C)Inspection Mark
24.5 24.5
24.0 24.0
23.5 23.5
23.0 23.0
22.5 22.5
22.0 22.0
11:32:59 PM
11/14/2023
4:12:59 PM
11/15/2023
2:02:59 AM
11/15/2023
4:32:59 AM
11/15/2023
7:02:59 AM
11/15/2023
9:32:59 AM
11/15/2023
12:02:59 PM
11/15/2023
Events Info
11/14/2023 11:42:59 PM Inspec on
Page 1 of 111/15/2023 4:18:53 PM
Page 571 of 1261
Analyst: DFB
Date: 11.14.23
184177 184420 184424 184443 LB
1 1 1 1
1 1 1 1
X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-14-2023 Z
Page 572 of 1261
Analyst: DFB
Login No.184177 184420 184424 184443 LB
Sample No. 1 1 1 1
1. Particle size reduction? (<1mm) Yes/No N
If yes, write NCM descibing how.
2. Balance ID 42605617
3. Sample weight, 5.0 +/- 0.1g 5.07
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 15:40
b. Stop Time for Mixing 15:45
c. pH reading after mixing
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"
a. HCL Lot# used
b. Pipette ID
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID
Termometer Correction Factor
b. Start Time
c. Start Temperature (Observed)
Start Temperature (Actual)0 0 0 0 0 0 0 0 0 0
d. Finish Time
e. Finish Temperature (Observed)
Finish Temperature (Actual)0 0 0 0 0 0 0 0 0 0
f. pH reading after heating (temperature corrected)
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-14-2023 Z
Page 573 of 1261
Analyst: DFB
Login No. 184177 184420 184424 184443 LB
Sample No.1 1 1 1
1. Particle size reduction? Yes/no
If yes, write NCM descibing how.
2. Balance ID
3. Weight of wet solids after filtration (g)
Fluid Type from Wksht 2 #VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE! #VALUE!
1. TCLP Fluid 1 Lot #
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid
6. Vol of Fluid = wet solids x 20 (mL)
Rotator Number:
1. Rotator speed between 28-32 RPM?
2. Leach start date and time
3. Leach stop date and time
4. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d.Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
5. pH of leachate
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-14-2023 ZPage 574 of 1261
Analyst: DFB
Login No.184177 184420 184424 184443 LB
Sample No.1 1 1 1
1. Balance ID 42605617 42605617 42605617 42605617
2. ZHE vessel number 1 4 Bunny Melissa Nicole
3. Weight of material added to ZHE (g) 25.06 25.00 25.05 25.01
"X" if there was headspace in container. X X
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g) 25 25 25 25
7. Weight of fluid to add (g) 501 500 501 500 0 0 0 0 0 0
a. TCLP Fluid 1 Lot # T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid 4.94 4.94 4.94 4.94 4.94
8. Percent Wet Solids (%) 100 100 100 100 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:ZHE#3 ZHE#3 ZHE#3 ZHE#1 ZHE#3
1. Leak Check
a. Reading #1 (psi) 50 50 50 50 50
b. Reading #2 (psi) 50 50 50 50 50
2. Rotator speed between 28 and 32 RPM?Y Y Y Y Y
3. Leach start date & time 11/14/23 23:33 11/14/23 23:33 11/14/23 23:33 11/14/23 23:33 11/14/23 23:33
4. Leach stop date & time 11/15/23 16:20 11/15/23 16:20 11/15/23 16:20 11/15/23 16:20 11/15/23 16:20
5. Room temperature
Thermometer Correction Factor 0.2 0.2 0.2 0.2 0.2
a.Temp Min (Observed) (oC)22.5 22.5 22.5 22.5 22.5
b.Temp Max (Observed) (oC)24.1 24.1 24.1 24.1 24.1
c.Temp Min (Actual) (oC)22.7 22.7 22.7 22.7 22.7 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)24.3 24.3 24.3 24.3 24.3 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching X X X X X
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) 0.0 0.0 0.0 0.0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-14-2023 Z
Page 575 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Fogg, Cameron C11/17/23 18:23634482
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount Initial pH Headspace mv-Cent BFB
00006
MV-Gas A 00172
2 uL 2 uL 5 uL8260DBFB
280-634482/1
5 mL 5 mL 10 uL8260DCCV
280-634482/2
0.5 mL 5 mL 10 uL8260DLCS
280-633952/2-A
0.5 mL 5 mL 10 uL8260DLCSD
280-633952/3-A
0.5 mL 5 mL8260DLB
280-633952/1-A
ST071-SoilIDW-11
092023
0.5 mL 5 mL n/a SU n/a8260DP280-184424-C-1-
B
5 mL 5 mL 10 uL8260DCCVC
280-634482/24
Lab Sample ID Client Sample ID Method Chain Basis mv-IS_SS 00071 MV-MegaMainA
00099
AnalysisComment
8260DBFB
280-634482/1
5 uL 25 uL8260DCCV
280-634482/2
5 uL 25 uL8260DLCS
280-633952/2-A
5 uL 25 uL8260DLCSD
280-633952/3-A
5 uL8260DLB
280-633952/1-A
ST071-SoilIDW-11
092023
5 uL TCLP8260DP280-184424-C-1-
B
5 uL 25 uL8260DCCVC
280-634482/24
Batch Notes
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 18260D
Page 576 of 1261
8270E_DOD5
Semivolatile Organic Compounds
(GC/MS)
Page 577 of 1261
FORM II
GC/MS SEMI VOA SURROGATE RECOVERY
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Matrix:Solid (TCLP)Level:Low
GC Column (1):Rxi-5Sil MS ID:0.25(mm)
#Lab Sample IDClient Sample ID #####2FP PHL NBZ FBP TBP TPHL
280-184424-1ST071-SoilIDW-1109
2023 75 75 85 76 82 111
LB
280-634317/1-F 70 62 87 84 79 109
LCS
280-634317/2-F 78 78 90 89 89 96
QC LIMITS
2FP = 2-Fluorophenol (Surr)19-119
PHL = Phenol-d5 (Surr)10-115
NBZ = Nitrobenzene-d5 (Surr)44-120
FBP = 2-Fluorobiphenyl 44-119
TBP = 2,4,6-Tribromophenol (Surr)43-140
TPHL = Terphenyl-d14 (Surr)50-134
FORM II 8270E
# Column to be used to flag recovery values
Page 578 of 1261
GC/MS SEMI VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-184424-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:SMS_1-112823004.DSolid (TCLP)
Lab ID:LCS 280-634317/2-F Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
1,4-Dichlorobenzene 80.0 45.3 29-11257
2,4-Dinitrotoluene 80.0 67.6 57-12885
Hexachlorobenzene 80.0 66.9 53-12584
Hexachlorobutadiene 80.0 47.4 22-12459
Hexachloroethane 80.0 44.0 21-11555
2-Methylphenol 80.0 67.5 30-11784
3 & 4 Methylphenol 80.0 68.1 29-11085
Nitrobenzene 80.0 68.7 45-12186
Pentachlorophenol 160 148 35-13893
Pyridine 160 48 10-1205U Q
2,4,5-Trichlorophenol 80.0 67.9 53-12385
2,4,6-Trichlorophenol 80.0 69.4 50-12587
FORM III 8270E
# Column to be used to flag recovery and RPD values
Page 579 of 1261
FORM V
DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)
Lab Name:Job No.:
GC/MS SEMI VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-184424-1
DFTPP Injection Date:11/15/2023Lab File ID:
Instrument ID:DFTPP Injection Time:07:01
SMS_1-111523001.D
SMS_1
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:633956
51 30.0 - 60.0 % of mass 198 57.6
68 Less than 2.0 % of mass 69 0.7 (1.6)1
69 Mass 69 relative abundance 47.1
70 Less than 2.0 % of mass 69 0.2 (0.5)1
127 40.0 - 60.0 % of mass 198 53.2
197 Less than 1.0 % of mass 198 0.3
198 Base Peak, 100 % relative abundance 100.0
199 5.0- 9.0 % of mass 198 6.9
275 10.0 - 30.0 % of mass 198 22.2
365 Greater than 1.0 % of mass 198 3.5
441 Present but less than mass 443 10.7 (81.6)3
442 Greater than 40.0 % of mass 198 69.8
443 17.0 - 23.0 % of mass 442 13.1 (18.7)2
1-Value is % mass 69 2-Value is % mass 442 3-Value is % mass 443
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
ICIS 280-633956/3 SMS_1-111523002.D11/15/2023 7:12
STD20 280-633956/10 SMS_1-111523003.D11/15/2023 7:34
STD16 280-633956/9 SMS_1-111523004.D11/15/2023 7:56
STD12 280-633956/8 SMS_1-111523005.D11/15/2023 8:18
STD05 280-633956/7 SMS_1-111523006.D11/15/2023 8:40
STD02 280-633956/6 SMS_1-111523007.D11/15/2023 9:03
STD01 280-633956/5 SMS_1-111523008.D11/15/2023 9:25
STD004 280-633956/4 SMS_1-111523009.D11/15/2023 9:47
FORM V 8270E Page 580 of 1261
FORM V
DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)
Lab Name:Job No.:
GC/MS SEMI VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-184424-1
DFTPP Injection Date:11/28/2023Lab File ID:
Instrument ID:DFTPP Injection Time:09:30
SMS_1-112823001.D
SMS_1
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:635266
51 30.0 - 60.0 % of mass 198 53.3
68 Less than 2.0 % of mass 69 0.7 (1.5)1
69 Mass 69 relative abundance 45.1
70 Less than 2.0 % of mass 69 0.2 (0.4)1
127 40.0 - 60.0 % of mass 198 52.1
197 Less than 1.0 % of mass 198 0.0
198 Base Peak, 100 % relative abundance 100.0
199 5.0- 9.0 % of mass 198 6.8
275 10.0 - 30.0 % of mass 198 22.0
365 Greater than 1.0 % of mass 198 3.4
441 Present but less than mass 443 10.8 (82.5)3
442 Greater than 40.0 % of mass 198 67.6
443 17.0 - 23.0 % of mass 442 13.1 (19.4)2
1-Value is % mass 69 2-Value is % mass 442 3-Value is % mass 443
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCVIS 280-635266/3 SMS_1-112823002.D11/28/2023 9:40
LB 280-634317/1-F SMS_1-112823003.D11/28/2023 10:02
LCS 280-634317/2-F SMS_1-112823004.D11/28/2023 10:25
ST071-SoilIDW-11092023 280-184424-1 SMS_1-112823006.D11/28/2023 11:10
CCVC 280-635266/17 SMS_1-112823013.D11/28/2023 13:48
FORM V 8270E Page 581 of 1261
GC/MS SEMI VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Denver 280-184424-1
SDG No.:
Sample No.:CCVIS 280-635266/3 Date Analyzed:11/28/2023 09:40
Lab File ID (Standard):SMS_1-112823002.D
Instrument ID:SMS_1 GC Column:Rxi-5Sil MS ID:0.25(mm)
Heated Purge: (Y/N)N
Calibration ID:87355
#RT #RT ##RT ##
DCBd4 NPT ANT
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
482868
120717 450671
1802684
230298
921190
3.90 5.07 6.7612/24 HOUR STD
4.07
3.74
5.24
4.91
6.93
6.59
241434 901342 460595
LAB SAMPLE ID CLIENT SAMPLE ID
LB 280-634317/1-F 284945 1044934 539803 3.90 5.07 6.76
LCS 280-634317/2-F 286067 1057766 555678 3.91 5.07 6.76
280-184424-1 ST071-SoilIDW-11092
023
310136 1143255 590166 3.91 5.07 6.76
CCVC 280-635266/17 253176 911231 472426 3.90 5.07 6.76
DCBd4 = 1,4-Dichlorobenzene-d4
NPT = Naphthalene-d8
ANT = Acenaphthene-d10
FORM VIII 8270E
# Column used to flag values outside QC limits
Area Limit = 50%-200% of internal standard area
RT Limit = ± 0.1666 minutes of internal standard RT
Page 582 of 1261
GC/MS SEMI VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Denver 280-184424-1
SDG No.:
Sample No.:CCVIS 280-635266/3 Date Analyzed:11/28/2023 09:40
Lab File ID (Standard):SMS_1-112823002.D
Instrument ID:SMS_1 GC Column:Rxi-5Sil MS ID:0.25(mm)
Heated Purge: (Y/N)N
Calibration ID:87355
#RT #RT ##RT ##
PHN CRY PRY
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
1578712
394678 284106
1136424
263348
1053392
8.21 10.95 13.1412/24 HOUR STD
8.38
8.04
11.11
10.78
13.31
12.97
789356 568212 526696
LAB SAMPLE ID CLIENT SAMPLE ID
LB 280-634317/1-F 921056 594621 515389 8.21 10.94 13.14
LCS 280-634317/2-F 941846 682053 589689 8.21 10.95 13.13
280-184424-1 ST071-SoilIDW-11092
023
1009229 633248 597097 8.21 10.94 13.14
CCVC 280-635266/17 803603 580998 568583 8.21 10.95 13.14
PHN = Phenanthrene-d10
CRY = Chrysene-d12
PRY = Perylene-d12
FORM VIII 8270E
# Column used to flag values outside QC limits
Area Limit = 50%-200% of internal standard area
RT Limit = ± 0.1666 minutes of internal standard RT
Page 583 of 1261
FORM I
GC/MS SEMI VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:ST071-SoilIDW-11092023 Lab Sample ID:280-184424-1
Matrix:SMS_1-112823006.DLab File ID:
Date Collected:8270EAnalysis Method:
Solid (TCLP)
11/09/2023 16:00
Level: (low/med)
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Analyzed:
Date Extracted:
Dilution Factor:
Extract. Method:11/22/2023 11:45
1
3510C
11/28/2023 11:10
Low
2(uL)
1(mL)
% Moisture:
Sample wt/vol:125(mL)
N% Solids:
GC Column:0.25(mm)ID:Rxi-5Sil MS
Cleanup Factor:
Analysis Batch No.:635266 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
4.0U3.2106-46-7 1,4-Dichlorobenzene 3.2 1.4
10U8.0121-14-2 2,4-Dinitrotoluene 8.0 1.4
10U8.0118-74-1 Hexachlorobenzene 8.0 0.86
10U8.087-68-3 Hexachlorobutadiene 8.0 2.9
10U M8.067-72-1 Hexachloroethane 8.0 4.5
10U8.095-48-7 2-Methylphenol 8.0 0.77
10U8.015831-10-4 3 & 4 Methylphenol 8.0 0.80
10U8.098-95-3 Nitrobenzene 8.0 1.3
50U4887-86-5 Pentachlorophenol 48 20
50U Q48110-86-1 Pyridine 48 18
10U8.095-95-4 2,4,5-Trichlorophenol 8.0 0.90
10U8.088-06-2 2,4,6-Trichlorophenol 8.0 0.71
%RECCAS NO.LIMITSQSURROGATE
76 44-119321-60-8 2-Fluorobiphenyl
75 19-119367-12-4 2-Fluorophenol (Surr)
82 43-140118-79-6 2,4,6-Tribromophenol (Surr)
85 44-1204165-60-0 Nitrobenzene-d5 (Surr)
75 10-1154165-62-2 Phenol-d5 (Surr)
111 50-1341718-51-0 Terphenyl-d14 (Surr)
FORM I 8270E
Page 584 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Lims ID:280-184424-B-1-C
Client ID:ST071-SoilIDW-11092023
Sample Type:Client
Inject. Date:28-Nov-2023 11:10:09 ALS Bottle#:0 Worklist Smp#:10
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:280-184424-B-1-C
Operator ID:MB Instrument ID:SMS_1
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:29-Nov-2023 10:11:15 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1689
First Level Reviewer: FP7E Date:29-Nov-2023 09:47:05
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.907 3.904 0.003 96 310136 8.00
* 2 Naphthalene-d8 136 5.072 5.072 0.000 99 1143255 8.00
* 3 Acenaphthene-d10 164 6.760 6.760 0.000 96 590166 8.00
* 4 Phenanthrene-d10 188 8.208 8.209 -0.001 97 1009229 8.00
* 5 Chrysene-d12 240 10.942 10.945 -0.003 98 633248 8.00
* 6 Perylene-d12 264 13.136 13.139 -0.003 97 597097 8.00
$ 7 2-Fluorophenol 112 2.856 2.850 0.006 94 503451 9.42
$ 8 Phenol-d5 99 3.651 3.648 0.003 96 645300 9.42
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 633033 10.6
$ 10 2-Fluorobiphenyl 172 6.128 6.129 -0.001 99 1003946 9.52
$ 11 2,4,6-Tribromophenol 330 7.540 7.540 0.000 89 156205 10.3
$ 12 Terphenyl-d14 244 9.808 9.808 0.000 97 1284984 13.9
$ 13 2,4,6-Trichlorophenol-d2 198 6.286 ND
15 1,4-Dioxane 88 1.549 ND U
14 Triethyl amine 86 1.574 1.608 -0.034 35 1153 NC
17 N-Nitrosodimethylamine 74 1.759 ND
16 2-Ethoxyethanol 59 1.759 ND
18 Pyridine 79 1.784 ND
19 Dimethylformamide 73 2.258 ND
20 2-Picoline 93 2.326 ND
22 N-Nitrosomethylethylamine 88 2.421 ND
23 Methyl methanesulfonate 80 2.665 ND
21 Acrylamide 71 2.763 ND U
25 N-Nitrosodiethylamine 102 2.985 ND
38 Pentachlorophenol_T 266 3.171 ND
27 Ethyl methanesulfonate 79 3.253 ND 7
28 Benzaldehyde 106 3.522 ND U
24 Phenylmercaptan TIC 110 3.583 ND
31 Aniline 93 3.623 ND 7
30 Pentachloroethane 117 3.654 ND 7
29 Phenol 94 3.660 ND 7
Page 585 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/ml Flags
33 Bis(2-chloroethyl)ether 93 3.688 ND 7
34 2-Chlorophenol 128 3.737 ND
35 n-Decane 43 3.790 3.790 0.000 96 7345 0.0771
36 1,3-Dichlorobenzene 146 3.851 ND
37 1,4-Dichlorobenzene 146 3.919 ND
43 1,2-Dichlorobenzene 146 4.052 ND
40 Benzyl alcohol 108 4.052 ND U
46 Indene 116 4.132 ND 7
47 2,2'-oxybis[1-chloropropane] 45 4.175 ND 7
45 2-Methylphenol 108 4.181 ND
48 N-Nitrosopyrrolidine 100 4.252 ND
52 Acetophenone 105 4.277 ND U
54 N-Nitrosodi-n-propylamine 70 4.289 ND U
53 N-Nitrosomorpholine 116 4.295 ND U
73 Benzidine_T 184 4.307 ND
55 2-Toluidine 106 4.307 ND 7
51 4-Methylphenol 108 4.329 ND
49 3-Methylphenol 108 4.329 ND
50 3 & 4 Methylphenol 108 4.329 ND
56 Hexachloroethane 117 4.354 ND U
58 Nitrobenzene 77 4.424 ND 7
59 N-Nitrosopiperidine 114 4.563 ND
60 Isophorone 82 4.656 ND 7
61 2-Nitrophenol 139 4.720 ND
62 2,4-Dimethylphenol 107 4.810 ND 7
42 2,4-Xylidine TIC 136 4.810 ND
44 o-Anisidine TIC 80 4.857 ND U
67 o,o',o''-Triethylphosphorothioat 198 4.859 ND
66 Bis(2-chloroethoxy)methane 63 4.877 ND 7
74 alpha,alpha-Dimethyl phenethylam 58 4.930 ND U
69 Benzoic acid 105 4.967 ND U
70 2,4-Dichlorophenol 162 4.976 ND 7
64 Benzyl dichloride 125 5.016 ND
72 1,2,4-Trichlorobenzene 180 5.025 ND
75 Naphthalene 128 5.090 5.090 0.000 96 33232 0.2058
77 4-Chloroaniline 127 5.164 ND 7
78 2,6-Dichlorophenol 162 5.173 ND 7
79 Hexachloropropene 213 5.179 ND
80 Hexachlorobutadiene 225 5.226 ND
81 Quinoline 129 5.410 ND U
84 Caprolactam 55 5.485 ND U
82 p-Phenylene diamine 108 5.506 ND
83 N-Nitrosodi-n-butylamine 84 5.506 ND 7
63 1,3-phenylenediamine TIC 108 5.568 ND
65 5-Methyl-o-Anisidine TIC 122 5.592 ND U
85 4-Chloro-3-methylphenol 107 5.679 ND
86 Safrole, Total 162 5.697 ND 7
88 2-Methylnaphthalene 141 5.759 5.759 0.000 91 48320 0.5492
89 1-Methylnaphthalene 142 5.851 5.851 0.000 91 33439 0.3473
92 Hexachlorocyclopentadiene 237 5.919 ND
90 1,2,4,5-Tetrachlorobenzene 216 5.919 ND
87 Carbofuran phenol 164 5.965 ND
Page 586 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/ml Flags
91 Isosafrole Peak 1 162 5.977 ND
94 2,3-Dichlorobenzenamine 161 6.039 ND
93 2,4,6-Trichlorophenol 196 6.055 ND
95 2,4,5-Trichlorophenol 196 6.107 ND
96 Isosafrole Peak 2 162 6.196 ND 7
97 1,1'-Biphenyl 154 6.221 6.218 0.003 97 9920 0.0815
98 2-Chloronaphthalene 162 6.224 ND 7
100 1-Chloronaphthalene 162 6.242 ND 7
101 2-Nitroaniline 65 6.344 ND U
102 1,4-Naphthoquinone 158 6.406 ND
103 1,4-Dinitrobenzene 168 6.483 ND U
104 Dimethyl phthalate 163 6.545 ND
105 1,3-Dinitrobenzene 168 6.554 ND
106 2,6-Dinitrotoluene 165 6.588 ND
107 Acenaphthylene 152 6.622 ND 7
108 3-Nitroaniline 138 6.748 ND
109 Acenaphthene 153 6.794 ND 7
111 2,4-Dinitrophenol 184 6.856 ND
115 Pentachlorobenzene 250 6.923 ND
114 Dibenzofuran 168 6.964 6.964 0.000 96 29178 0.2186
116 2,4-Dinitrotoluene 165 6.976 ND
113 4-Nitrophenol 109 7.001 ND
117 1-Naphthylamine 143 7.044 ND
120 2,3,4,6-Tetrachlorophenol 232 7.108 ND
119 2-Naphthylamine 143 7.124 ND
124 Diethyl phthalate 149 7.241 ND 7
122 Hexadecane 57 7.284 ND 7
127 Fluorene 166 7.300 ND 7
128 Thionazin 97 7.312 ND
126 4-Chlorophenyl phenyl ether 204 7.321 ND
129 N-Nitro-o-toluidine 152 7.330 ND
130 4-Nitroaniline 138 7.346 ND
131 4,6-Dinitro-2-methylphenol 198 7.373 ND
132 Diphenylamine 169 7.441 ND
133 N-Nitrosodiphenylamine 169 7.441 ND
135 Azobenzene 77 7.472 ND 7
136 1,2-Diphenylhydrazine 77 7.472 ND 7
140 Sulfotepp 97 7.635 ND U
110 1,3-Dimethyl-2,5-Dinitrobenzene 179 7.564 7.678 -0.114 0 135 NC
112 1,3-Dimethyl-2,4-Dinitrobenzene 77 7.719 ND
141 1,3,5-Trinitrobenzene 213 7.725 ND
137 Tributyl phosphate 99 7.728 ND
142 Diallate Peak 1 86 7.737 ND U
143 Phorate 121 7.743 ND
144 Phenacetin 108 7.774 ND
145 4-Bromophenyl phenyl ether 248 7.796 ND
147 Diallate Peak 2 86 7.820 ND U
148 Hexachlorobenzene 284 7.830 ND
149 Dimethoate 87 7.900 ND
150 Atrazine 200 7.993 ND
121 1,4-Dimethyl-2,6-Dinitrobenzene 179 8.019 ND
156 Pentachloronitrobenzene 237 8.045 ND
Page 587 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/ml Flags
153 Pentachlorophenol 266 8.048 ND
151 4-Aminobiphenyl 169 8.051 ND 7
123 1,4-Dimethyl-2,3-Dinitrobenzene 77 8.054 ND
125 1,2-Dimethyl-3,6-Dinitrobenzene 179 8.131 ND
155 Pronamide 173 8.144 ND
154 n-Octadecane 57 8.196 ND U
157 Phenanthrene 178 8.233 ND
159 Dinoseb 211 8.248 ND
158 Disulfoton 88 8.258 ND U
160 Anthracene 178 8.283 ND 7
134 1,5-Dimethyl-2,4-Dinitrobenzene 179 8.283 ND
138 1,5-Dimethyl-2,3-Dinitrobenzene 179 8.383 ND
161 Carbazole 167 8.461 ND
139 1,2-Dimethyl-3,5-Dinitrobenzene 179 8.495 ND
162 Methyl parathion 109 8.618 ND
163 Alachlor 188 8.625 ND
146 1,2-Dimethyl-3,4-Dinitrobenzene 179 8.648 ND
164 Di-n-butyl phthalate 149 8.856 8.859 -0.003 99 18323 0.2980
152 1,2-Dimethyl-4,5-Dinitrobenzene 91 8.889 ND
166 4-Nitroquinoline-1-oxide 190 9.003 ND
165 Ethyl Parathion 109 9.013 ND
167 Methapyrilene 97 9.114 ND
169 Isodrin 193 9.247 ND
170 Fluoranthene 202 9.398 ND
171 Benzidine 184 9.564 ND
172 Pyrene 202 9.614 ND 7
173 Aramite Peak 1 185 9.826 ND U
175 Aramite Peak 2 185 9.903 ND U
176 p-Dimethylamino azobenzene 120 9.949 ND
177 Chlorobenzilate 251 10.014 ND
178 Famphur 218 10.270 ND
179 3,3'-Dimethylbenzidine 212 10.304 ND
180 Butyl benzyl phthalate 149 10.353 ND
181 2-Acetylaminofluorene 181 10.590 ND
304 Kepone 272 10.643 ND
184 Benzo[a]anthracene 228 10.936 ND 7
183 3,3'-Dichlorobenzidine 252 10.942 ND
182 4,4'-Methylene bis(2-chloroanili 231 10.957 ND
185 Chrysene 228 10.979 ND 7
186 Bis(2-ethylhexyl) phthalate 149 11.117 11.111 -0.004 77 4294 0.5640 M
188 6-Methylchrysene 242 11.613 ND
168 Hexachlorophene 196 11.934 ND
189 Di-n-octyl phthalate 149 12.119 ND
190 Tris(2,3-dibromopropyl)phosphate 119 12.483 ND
192 7,12-Dimethylbenz(a)anthracene 256 12.513 ND
191 Benzo[b]fluoranthene 252 12.513 ND
193 Benzo[k]fluoranthene 252 12.560 ND
194 Benzo[a]pyrene 252 13.040 ND U
195 3-Methylcholanthrene 268 13.681 ND
196 Dibenz[a,h]acridine 279 14.643 ND
197 Dibenz[a,j]acridine 279 14.738 ND
198 Indeno[1,2,3-cd]pyrene 276 15.025 ND
Page 588 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/ml Flags
199 Dibenz(a,h)anthracene 278 15.099 ND
200 Benzo[g,h,i]perylene 276 15.478 ND
205 1,4-Dimethyl-2,5-Dinitrobenzene 1 0.000 ND
302 Toluene diamine (2,4- + 2,6- iso 1 0.000 ND
201 Phthalic anhydride 104 0.000 ND
303 Dibenzo[a,e]pyrene 1 0.000 ND
202 Dibenz[a,h]acridine TIC 1 0.000 ND
203 Dibenzo[a,e]pyrene TIC 1 0.000 ND
305 Alpha Methyl Styrene 1 0.000 ND
301 Alpha-Terpineol 59 0.000 ND
206 DFTPP
208 4,4'-DDD 235 4.685 ND
207 4,4'-DDE 246 4.704 ND
209 4,4'-DDT 235 4.904 ND
S 210 Phthalic acid TIC 1 5.729 ND 7
S 211 Total Cresols 108 15.496 ND 7
S 212 Methyl Phenols,Total 108 15.496 ND 7
S 214 Diallate 86 15.496 ND 7
S 213 Isosafrole 162 15.496 ND 7
S 215 Aramite, Total 185 15.496 ND 7
S 216 TPAH 1 0.000 ND 7
T 293 alpha,alpha-Dimethyl phenethylam 58 4.900 ND U
T 298 p-phenylenediamine TIC 108 5.500 ND U
T 217 Phthalic anhydride TIC 76 5.729 ND U
T 218 Kepone TIC 272 10.580 ND
T 297 Hexachlorophene TIC 196 13.000 ND U
T 291 Tributyl phosphate TIC 1 0.000 ND
T 300 2-Ethoxyethanol TIC 1 0.000 ND
T 222 2,6-Dimethylphenol TIC 1 0.000 ND
T 223 Hexachlorodibenzo-p-dioxin TIC 1 0.000 ND
T 224 Pentachlorodibenzo-p-dioxin TIC 1 0.000 ND
T 296 Triethyl amine TIC 1 0.000 ND
T 289 Tris(2,3-dibromopropyl)phosphate 1 0.000 ND
T 290 Alpha Methyl Styrene TIC 1 0.000 ND
T 299 Benzyl dichloride TIC 1 0.000 ND
T 220 Octadecane (TIC) 1 0.000 ND
T 219 Hexachlorodibenzofurans TIC 1 0.000 ND
T 288 Alpha-Terpineol TIC 1 0.000 ND
T 221 Pentachlorodibenzofurans TIC 1 0.000 ND
T 295 Toluene diamine (2,4- + 2,6- iso 1 0.000 ND
T 292 Dimethylformamide TIC 1 0.000 ND
T 294 Carbofuran phenol TIC 1 0.000 ND
QC Flag Legend
Processing Flags
NC - Not Calibrated
7 - Failed Limit of Detection
Page 589 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
MS-IS-RVE_00003 Amount Added: 25.00 Units: uL Run Reagent
Page 590 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Injection Date:28-Nov-2023 11:10:09 Instrument ID:SMS_1 Operator ID:MB
Lims ID:280-184424-B-1-C Lab Sample ID:280-184424-1 Worklist Smp#:10
Client ID:ST071-SoilIDW-11092023
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
Y ( X10
0
0
0
0
0
)
-112823006[MS Quad Chro]:Total
$ 2
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Page 591 of 1261
Report Date: 29-Nov-2023 10:11:25 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Lims ID:280-184424-B-1-C
Client ID:ST071-SoilIDW-11092023
Sample Type:Client
Inject. Date:28-Nov-2023 11:10:09 ALS Bottle#:0 Worklist Smp#:10
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:280-184424-B-1-C
Operator ID:MB Instrument ID:SMS_1
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:29-Nov-2023 10:11:15 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1689
First Level Reviewer: FP7E Date:29-Nov-2023 09:47:05
Compound
Amount
Added
Amount
Recovered %Rec.
$7 2-Fluorophenol 12.5 9.42 75.33
$8 Phenol-d5 12.5 9.42 75.36
$9 Nitrobenzene-d5 12.5 10.6 84.64
$10 2-Fluorobiphenyl 12.5 9.52 76.12
$11 2,4,6-Tribromophenol 12.5 10.3 82.44
$12 Terphenyl-d14 12.5 13.9 111.13
Page 592 of 1261
Report Date: 29-Nov-2023 10:11:26 Chrom Revision: 2.3 15-Nov-2023 20:54:34
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823006.D
Injection Date:28-Nov-2023 11:10:09 Instrument ID:SMS_1
Lims ID:280-184424-B-1-C Lab Sample ID:280-184424-1
Client ID:ST071-SoilIDW-11092023
Operator ID:MB ALS Bottle#:0 Worklist Smp#:10
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column:Rxi-5Sil MS ( 0.25 mm)Detector MS SCAN
56 Hexachloroethane, CAS: 67-72-1
Processing Results
40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 1061(4.36)
119
134
91
12051771176578
40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1061(4.36), Qvalue=46
119
13491
117775165
40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 56 Hexachloroethane (NIST98.L)
117 119
201
199
166
94 121
9682 168
84131
4937
4.2 4.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
-112823006[MS Quad Chro]:m/z 117

4
.
3
5
7
4.2 4.5
Min
RT
0
2
4
6
8
10
Y ( X10
0
)
-112823006[MS Quad Chro]:m/z 201
4.2 4.5
Min
RT
0
2
4
6
8
10
Y ( X10
0
)
-112823006[MS Quad Chro]:m/z 199
RT Mass Response Amount
4.36 117.00 2368 0.085029
4.35 201.00 0
4.35 199.00 0
Reviewer: FP7E, 29-Nov-2023 09:45:51 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
Page 593 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
0.25(mm)Rxi-5Sil MS ID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:
1Level STD004 280-633956/4 SMS_1-111523009.D
2Level STD01 280-633956/5 SMS_1-111523008.D
3Level STD02 280-633956/6 SMS_1-111523007.D
4Level STD05 280-633956/7 SMS_1-111523006.D
5Level ICIS 280-633956/3 SMS_1-111523002.D
6Level STD12 280-633956/8 SMS_1-111523005.D
7Level STD16 280-633956/9 SMS_1-111523004.D
8Level STD20 280-633956/10 SMS_1-111523003.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8
N-Nitrosodimethylamine 0.6949 0.8200 +++++0.9898 1.0293 Ave 14.0
0.9907 1.0110 1.0505
15.00.940
9
Pyridine 1.2543 1.3365 +++++1.5545 1.5905 Ave 8.8
1.4987 1.5092 1.5876
15.01.475
9
Aniline 1.4195 1.5871 +++++1.8286 1.8305 Ave 9.9
1.7958 1.8390 1.8912
15.01.741
7
Phenol 1.5235 1.7204 +++++2.1059 2.1270 Ave 12.3
2.0360 2.0774 2.1489
15.01.962
7
Bis(2-chloroethyl)ether 1.5762 1.6087 +++++1.6738 1.6788 Ave 2.5
1.5965 1.6112 1.6571
15.01.628
9
2-Chlorophenol 1.2262 1.3028 +++++1.5491 1.5431 Ave 9.3
1.5040 1.5275 1.5622
15.01.459
3
1,3-Dichlorobenzene 1.5992 1.6392 +++++1.7513 1.6400 Ave 2.9
1.6519 1.6409 1.6884
15.01.658
7
1,4-Dichlorobenzene 1.6913 1.6818 +++++1.7074 1.7028 Ave 1.5
1.6620 1.6558 1.7264
15.01.689
6
1,2-Dichlorobenzene 1.5706 1.6004 +++++1.6595 1.6273 Ave 1.9
1.5881 1.6162 1.6445
15.01.615
2
Benzyl alcohol 0.5625 0.8199 +++++0.9723 0.9736 Lin2 1.0000
0.9924 0.9969 1.0449
0.9900-0.18
3
1.013
9
2,2'-oxybis[1-chloropropane]3.2181 3.3757 +++++3.6368 4.0294 Ave 7.5
3.3921 3.4189 3.6162
15.03.526
7
2-Methylphenol 0.9803 1.1493 +++++1.3584 1.3693 Ave 11.9
1.3230 1.3534 1.3818
15.01.273
7
Acetophenone 1.6913 1.8525 +++++2.1035 2.0910 Ave 8.0
2.0490 2.0742 2.0878
15.01.992
8
FORM VI 8270E
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 594 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
0.25(mm)Rxi-5Sil MS ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8
N-Nitrosodi-n-propylamine 0.9272 1.0210 +++++1.1944 1.2363 Ave 10.3
1.1849 1.1912 1.2217
0.0500 15.01.139
5
3 & 4 Methylphenol 1.0583 1.1220 +++++1.4423 1.4571 Ave 13.2
1.4362 1.4406 1.4847
15.01.348
7
Hexachloroethane 0.6229 0.6881 +++++0.7522 0.7504 Ave 6.7
0.7264 0.7326 0.7561
15.00.718
4
Nitrobenzene 0.3591 0.4174 +++++0.4666 0.4610 Ave 8.7
0.4434 0.4489 0.4595
15.00.436
6
Isophorone 0.6006 0.6734 +++++0.7913 0.7892 Ave 10.4
0.7847 0.7859 0.7988
15.00.746
3
2-Nitrophenol 0.1255 0.1573 +++++0.2016 0.1981 Lin2 0.9980
0.2101 0.2103 0.2152
0.9900-0.03
6
0.208
9
2,4-Dimethylphenol 0.2017 0.2240 +++++0.2715 0.2765 Ave 12.1
0.2688 0.2720 0.2830
15.00.256
8
Bis(2-chloroethoxy)methane 0.3960 0.4315 +++++0.4652 0.4790 Ave 6.3
0.4478 0.4522 0.4701
15.00.448
8
Benzoic acid +++++0.0953 +++++0.2134 0.2283 Lin2 0.9960
0.2498 0.2669 0.2737
0.9900-0.34
8
0.265
3
2,4-Dichlorophenol 0.2592 0.2847 +++++0.3298 0.3216 Ave 9.0
0.3244 0.3244 0.3326
15.00.311
0
1,2,4-Trichlorobenzene 0.3670 0.3550 +++++0.3551 0.3496 Ave 1.8
0.3476 0.3522 0.3582
15.00.355
0
Naphthalene 1.1501 1.1625 +++++1.1614 1.1370 Ave 2.7
1.1003 1.0887 1.1100
15.01.130
0
4-Chloroaniline 0.3875 0.4169 +++++0.4611 0.4455 Ave 6.5
0.4497 0.4564 0.4677
15.00.440
7
2,6-Dichlorophenol 0.2748 0.2822 +++++0.3283 0.3211 Ave 7.7
0.3222 0.3267 0.3354
15.00.312
9
Hexachlorobutadiene 0.1836 0.1900 +++++0.1922 0.1826 Ave 2.5
0.1887 0.1914 0.1961
15.00.189
2
4-Chloro-3-methylphenol 0.2311 0.2505 +++++0.3272 0.3302 Ave 14.6
0.3265 0.3318 0.3385
15.00.305
1
2-Methylnaphthalene 0.5563 0.6065 +++++0.6358 0.6250 Ave 4.7
0.6207 0.6204 0.6448
15.00.615
6
1-Methylnaphthalene 0.6218 0.6630 +++++0.6965 0.6815 Ave 3.8
0.6748 0.6827 0.6956
15.00.673
7
FORM VI 8270E
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 595 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
0.25(mm)Rxi-5Sil MS ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8
Hexachlorocyclopentadiene +++++++++++++++0.1045 0.1404 Lin2 0.9970
0.1563 0.1714 0.1904
0.0500 0.9900-0.52
8
0.207
6
1,2,4,5-Tetrachlorobenzene 0.3512 0.3301 +++++0.3444 0.3273 Ave 3.0
0.3441 0.3500 0.3526
15.00.342
8
2,4,6-Trichlorophenol 0.2818 0.3254 +++++0.4109 0.4046 Ave 14.8
0.4108 0.4182 0.4321
15.00.383
4
2,4,5-Trichlorophenol 0.2765 0.3432 +++++0.4145 0.4279 Lin2 0.9980
0.4298 0.4461 0.4533
0.9900-0.06
9
0.438
5
1,1'-Biphenyl 1.5607 1.6347 +++++1.6946 1.6563 Ave 2.9
1.6288 1.6742 1.7025
15.01.650
2
2-Chloronaphthalene 1.2057 1.3078 +++++1.3563 1.3185 Ave 4.0
1.3120 1.3389 1.3649
15.01.314
9
2-Nitroaniline 0.2824 0.3494 +++++0.4889 0.5051 Lin2 0.9960
0.4999 0.5060 0.5234
0.9900-0.09
9
0.507
7
Dimethyl phthalate 1.2399 1.3130 +++++1.4708 1.4065 Ave 6.0
1.4255 1.4323 1.4504
15.01.391
2
1,3-Dinitrobenzene 0.1307 0.1479 +++++0.2196 0.2185 Lin2 0.9910
0.2332 0.2435 0.2502
0.9900-0.04
7
0.233
3
2,6-Dinitrotoluene 0.1634 0.2363 +++++0.3401 0.3237 Lin2 0.9980
0.3358 0.3398 0.3449
0.9900-0.07
5
0.341
0
Acenaphthylene 1.5739 1.7353 +++++2.0339 1.9938 Ave 9.0
1.9532 1.9545 2.0014
15.01.892
3
3-Nitroaniline 0.2235 0.2905 +++++0.3950 0.3844 Lin2 0.9980
0.3924 0.3975 0.3988
0.9900-0.07
4
0.397
2
Acenaphthene 1.2422 1.2865 +++++1.3458 1.3121 Ave 2.6
1.2916 1.3162 1.3293
15.01.303
4
2,4-Dinitrophenol +++++0.0081 +++++0.0976 0.1195 Qua 1.0000
0.1391 0.1584 0.1743
0.0500 0.9900-0.20
4
0.100
3
0.0019871
Dibenzofuran 1.7427 1.8088 +++++1.8865 1.8025 Ave 2.4
1.8155 1.7894 1.8215
15.01.809
6
2,4-Dinitrotoluene 0.2132 0.2804 +++++0.4437 0.4313 Lin2 0.9940
0.4577 0.4630 0.4659
0.9900-0.10
7
0.455
1
4-Nitrophenol 0.0441 0.0683 +++++0.1739 0.1848 Lin1 0.9980
0.1849 0.1940 0.1981
0.0500 0.9900-0.16
5
0.197
0
2,3,4,6-Tetrachlorophenol 0.1096 0.1841 +++++0.2975 0.3008 Lin2 0.9940
0.3076 0.3266 0.3343
0.9900-0.09
0
0.317
5
FORM VI 8270E
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 596 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
0.25(mm)Rxi-5Sil MS ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8
Diethyl phthalate 1.2228 1.3561 +++++1.5202 1.4653 Ave 7.1
1.4614 1.4781 1.4610
15.01.423
5
Fluorene 1.3611 1.4269 +++++1.5078 1.4260 Ave 3.1
1.4314 1.4624 1.4612
15.01.439
6
4-Chlorophenyl phenyl ether 0.6494 0.6753 +++++0.6899 0.6597 Ave 2.1
0.6708 0.6767 0.6850
15.00.672
4
4-Nitroaniline 0.2157 0.3046 +++++0.4052 0.3903 Lin2 0.9990
0.3859 0.3954 0.3892
0.9900-0.07
5
0.398
5
4,6-Dinitro-2-methylphenol +++++0.0562 +++++0.1183 0.1268 Lin2 0.9970
0.1364 0.1423 0.1488
0.9900-0.17
9
0.144
2
Diphenylamine 1.0286 1.1280 +++++1.2405 1.1936 Ave 6.6
1.2241 1.2386 1.2141
15.01.181
1
N-Nitrosodiphenylamine 0.4810 0.5151 +++++0.5678 0.5731 Ave 7.7
0.5781 0.5922 0.5966
15.00.557
7
1,2-Diphenylhydrazine 1.3293 1.5696 +++++1.8225 1.8069 Ave 10.3
1.7227 1.7255 1.7340
15.01.672
9
Azobenzene 1.3439 1.5868 +++++1.8425 1.8267 Ave 10.3
1.7416 1.7444 1.7530
15.01.691
3
4-Bromophenyl phenyl ether 0.1979 0.1974 +++++0.2141 0.2100 Ave 5.2
0.2166 0.2186 0.2277
15.00.211
8
Hexachlorobenzene 0.2589 0.2524 +++++0.2494 0.2478 Ave 2.8
0.2471 0.2521 0.2667
15.00.253
5
Pentachlorophenol ++++++++++0.0500 0.0993 0.1186 Lin2 0.9980
0.1205 0.1276 0.1406
0.9900-0.37
2
0.141
1
Phenanthrene 1.1602 1.1549 +++++1.1596 1.1462 Ave 1.2
1.1271 1.1408 1.1655
15.01.150
6
Anthracene 0.9501 1.0137 +++++1.1453 1.1334 Ave 7.3
1.1257 1.1418 1.1555
15.01.095
1
Carbazole 0.8906 0.9804 +++++1.1180 1.1000 Ave 7.8
1.0727 1.0746 1.0883
15.01.046
4
Alachlor +++++0.0962 +++++0.1361 0.1339 Ave 14.0
0.1397 0.1438 0.1475
15.00.132
9
Di-n-butyl phthalate 0.7603 0.9690 +++++1.3184 1.3565 Lin2 0.9980
1.3518 1.3483 1.3818
0.9900-0.26
1
1.362
0
Fluoranthene 0.9063 0.9811 +++++1.1325 1.1551 Ave 9.7
1.1178 1.1398 1.2001
15.01.090
4
FORM VI 8270E
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 597 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
0.25(mm)Rxi-5Sil MS ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8
Pyrene 1.3977 1.5200 +++++1.7168 1.6628 Ave 7.3
1.6812 1.6628 1.7118
15.01.621
9
Butyl benzyl phthalate 0.3409 0.4121 +++++0.6812 0.7238 Lin1 0.9980
0.7454 0.7484 0.7911
0.9900-0.23
9
0.771
7
Benzo[a]anthracene 1.0711 1.1598 +++++1.3410 1.3355 Ave 9.5
1.3577 1.3378 1.4059
15.01.287
0
Chrysene 1.4718 1.4521 +++++1.4909 1.4171 Ave 2.4
1.4366 1.3868 1.4392
15.01.442
1
Bis(2-ethylhexyl) phthalate +++++0.3643 +++++0.6284 0.7109 Lin2 0.9980
0.7000 0.7162 0.7615
0.9900-0.38
6
0.744
7
Di-n-octyl phthalate 0.5938 0.6414 +++++1.1859 1.5013 Lin1 0.9940
1.4499 1.4714 1.6021
0.9900-0.57
3
1.535
4
Benzo[b]fluoranthene 0.7474 0.9498 +++++1.1830 1.1995 Lin2 0.9980
1.2158 1.2481 1.3124
0.9900-0.21
2
1.244
1
Benzo[k]fluoranthene 0.8959 1.0823 +++++1.4107 1.4143 Lin2 0.9980
1.4328 1.4622 1.5083
0.9900-0.24
4
1.455
2
Benzo[a]pyrene 0.7292 0.9229 +++++1.1554 1.2007 Lin2 0.9960
1.2260 1.3155 1.3553
0.9900-0.23
2
1.262
5
Indeno[1,2,3-cd]pyrene 0.4842 0.6047 +++++0.7824 0.8636 Lin2 0.9960
0.8253 0.8456 0.8993
0.9900-0.16
0
0.849
7
Dibenz(a,h)anthracene 0.5863 0.7081 +++++0.8925 0.9773 Lin2 0.9930
1.0076 1.0429 1.1049
0.9900-0.19
0
1.011
8
Benzo[g,h,i]perylene 0.6712 0.7979 +++++1.0447 1.0831 Lin2 0.9960
1.0911 1.1311 1.1749
0.9900-0.19
5
1.111
2
2-Fluorophenol (Surr)0.7684 0.9599 +++++1.3649 1.4060 Lin2 0.9960
1.3656 1.4022 1.4643
0.9900-0.28
2
1.409
1
Phenol-d5 (Surr)1.3837 1.5871 +++++1.8567 1.9203 Ave 11.5
1.8392 1.8732 1.9097
15.01.767
1
Nitrobenzene-d5 (Surr)0.3607 0.3771 +++++0.4361 0.4392 Ave 8.3
0.4302 0.4402 0.4476
15.00.418
7
2-Fluorobiphenyl 1.4142 1.4196 +++++1.4663 1.4209 Ave 1.4
1.4124 1.4272 1.4508
15.01.430
2
2,4,6-Tribromophenol (Surr)0.0783 0.1479 +++++0.2010 0.1979 Lin2 0.9990
0.2068 0.2132 0.2117
0.9900-0.05
4
0.210
8
Terphenyl-d14 (Surr)1.0665 1.1247 +++++1.2325 1.1509 Ave 5.1
1.1921 1.1860 1.2277
15.01.168
6
FORM VI 8270E
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
Page 598 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
GC Column:Rxi-5Sil MSID:0.25(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 STD004 280-633956/4 SMS_1-111523009.D
Level 2 STD01 280-633956/5 SMS_1-111523008.D
Level 3 STD02 280-633956/6 SMS_1-111523007.D
Level 4 STD05 280-633956/7 SMS_1-111523006.D
Level 5 ICIS 280-633956/3 SMS_1-111523002.D
Level 6 STD12 280-633956/8 SMS_1-111523005.D
Level 7 STD16 280-633956/9 SMS_1-111523004.D
Level 8 STD20 280-633956/10 SMS_1-111523003.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/ML)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8
N-Nitrosodimethylamine AveDCBd4 9333 25555 +++++160426 282144 0.400 1.00 +++++5.00 8.00
415831 20.016.012.0752941572557
Pyridine AveDCBd4 33695 83296 +++++503890 871936 0.800 2.00 +++++10.0 16.0
1258142 40.032.024.022758091709398
Aniline AveDCBd4 19066 49459 +++++296368 501747 0.400 1.00 +++++5.00 8.00
753774 20.016.012.013554851041462
Phenol AveDCBd4 20463 53613 +++++341307 583032 0.400 1.00 +++++5.00 8.00
854606 20.016.012.015401891176471
Bis(2-chloroethyl)ether AveDCBd4 21171 50132 +++++271287 460174 0.400 1.00 +++++5.00 8.00
670092 20.016.012.01187697912493
2-Chlorophenol AveDCBd4 16470 40599 +++++251065 422978 0.400 1.00 +++++5.00 8.00
631298 20.016.012.01119683865054
1,3-Dichlorobenzene AveDCBd4 21480 51081 +++++283843 449527 0.400 1.00 +++++5.00 8.00
693382 20.016.012.01210172929292
1,4-Dichlorobenzene AveDCBd4 22717 52409 +++++276718 466763 0.400 1.00 +++++5.00 8.00
697624 20.016.012.01237363937705
1,2-Dichlorobenzene AveDCBd4 21095 49874 +++++268960 446050 0.400 1.00 +++++5.00 8.00
666592 20.016.012.01178658915309
Benzyl alcohol Lin2DCBd4 7555 25549 +++++157592 266872 0.400 1.00 +++++5.00 8.00
416553 20.016.012.0748936564578
2,2'-oxybis[1-chloropropane]AveDCBd4 43224 105198 +++++589425 1104488 0.400 1.00 +++++5.00 8.00
1423774 20.016.012.025919141936236
2-Methylphenol AveDCBd4 13167 35817 +++++220163 375339 0.400 1.00 +++++5.00 8.00
555294 20.016.012.0990421766494
Acetophenone AveDCBd4 22717 57731 +++++340919 573150 0.400 1.00 +++++5.00 8.00
860043 20.016.012.014964141174704
N-Nitrosodi-n-propylamine AveDCBd4 12453 31817 +++++193575 338892 0.400 1.00 +++++5.00 8.00
497348 20.016.012.0875681674606
3 & 4 Methylphenol AveDCBd4 14215 34965 +++++233765 399400 0.400 1.00 +++++5.00 8.00
602811 20.016.012.01064138815837
FORM VI 8270E Page 599 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
GC Column:Rxi-5Sil MSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/ML)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8
Hexachloroethane AveDCBd4 8366 21442 +++++121913 205683 0.400 1.00 +++++5.00 8.00
304885 20.016.012.0541965414905
Nitrobenzene AveNPT 17594 47980 +++++288437 487212 0.400 1.00 +++++5.00 8.00
710255 20.016.012.01248660968095
Isophorone AveNPT 29424 77405 +++++489190 834047 0.400 1.00 +++++5.00 8.00
1256897 20.016.012.021705701694968
2-Nitrophenol Lin2NPT 6146 18083 +++++124631 209315 0.400 1.00 +++++5.00 8.00
336620 20.016.012.0584661453440
2,4-Dimethylphenol AveNPT 9880 25745 +++++167826 292264 0.400 1.00 +++++5.00 8.00
430556 20.016.012.0768995586639
Bis(2-chloroethoxy)methane AveNPT 19402 49599 +++++287572 506242 0.400 1.00 +++++5.00 8.00
717299 20.016.012.01277443975155
Benzoic acid Lin2NPT +++++21901 +++++263900 482575 +++++2.00 +++++10.0 16.0
800283 40.032.024.014874751151207
2,4-Dichlorophenol AveNPT 12700 32731 +++++203863 339925 0.400 1.00 +++++5.00 8.00
519635 20.016.012.0903636699528
1,2,4-Trichlorobenzene AveNPT 17979 40806 +++++219534 369516 0.400 1.00 +++++5.00 8.00
556755 20.016.012.0973288759649
Naphthalene AveNPT 56343 133623 +++++717984 1201607 0.400 1.00 +++++5.00 8.00
1762396 20.016.012.030162202347978
4-Chloroaniline AveNPT 18985 47924 +++++285039 470863 0.400 1.00 +++++5.00 8.00
720309 20.016.012.01270802984393
2,6-Dichlorophenol AveNPT 13461 32436 +++++202969 339346 0.400 1.00 +++++5.00 8.00
516176 20.016.012.0911300704482
Hexachlorobutadiene AveNPT 8996 21844 +++++118809 192955 0.400 1.00 +++++5.00 8.00
302324 20.016.012.0532951412860
4-Chloro-3-methylphenol AveNPT 11320 28798 +++++202258 348914 0.400 1.00 +++++5.00 8.00
522915 20.016.012.0919914715526
2-Methylnaphthalene AveNPT 27254 69713 +++++393087 660537 0.400 1.00 +++++5.00 8.00
994271 20.016.012.017520761337912
1-Methylnaphthalene AveNPT 30464 76209 +++++430606 720213 0.400 1.00 +++++5.00 8.00
1080930 20.016.012.018901901472272
Hexachlorocyclopentadiene Lin2ANT +++++++++++++++35015 80139 +++++++++++++++5.00 8.00
136109 20.016.012.0276946199300
1,2,4,5-Tetrachlorobenzene AveNPT 17205 37945 +++++212892 345862 0.400 1.00 +++++5.00 8.00
551161 20.016.012.0958170754795
2,4,6-Trichlorophenol AveANT 7470 20108 +++++137731 230934 0.400 1.00 +++++5.00 8.00
357798 20.016.012.0628378486188
2,4,5-Trichlorophenol Lin2ANT 7328 21212 +++++138937 244227 0.400 1.00 +++++5.00 8.00
374350 20.016.012.0659330518624
1,1'-Biphenyl AveANT 41368 101022 +++++568002 945287 0.400 1.00 +++++5.00 8.00
FORM VI 8270E Page 600 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
GC Column:Rxi-5Sil MSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/ML)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8
1418694 20.016.012.024761711946452
2-Chloronaphthalene AveANT 31959 80820 +++++454627 752515 0.400 1.00 +++++5.00 8.00
1142817 20.016.012.019851511556707
2-Nitroaniline Lin2ANT 7485 21595 +++++163882 288255 0.400 1.00 +++++5.00 8.00
435463 20.016.012.0761274588314
Dimethyl phthalate AveANT 32863 81141 +++++492987 802746 0.400 1.00 +++++5.00 8.00
1241670 20.016.012.021094961665300
1,3-Dinitrobenzene Lin2ANT 3463 9138 +++++73604 124704 0.400 1.00 +++++5.00 8.00
203115 20.016.012.0363962283154
2,6-Dinitrotoluene Lin2ANT 4331 14601 +++++113994 184766 0.400 1.00 +++++5.00 8.00
292516 20.016.012.0501554395116
Acenaphthylene AveANT 41716 107237 +++++681761 1137918 0.400 1.00 +++++5.00 8.00
1701269 20.016.012.029108312272428
3-Nitroaniline Lin2ANT 5925 17955 +++++132385 219366 0.400 1.00 +++++5.00 8.00
341813 20.016.012.0580075462101
Acenaphthene AveANT 32926 79504 +++++451108 748834 0.400 1.00 +++++5.00 8.00
1125033 20.016.012.019332841530293
2,4-Dinitrophenol QuaANT +++++1007 +++++65442 136366 +++++2.00 +++++10.0 16.0
242255 40.032.024.0506902368389
Dibenzofuran AveANT 46192 111781 +++++632346 1028737 0.400 1.00 +++++5.00 8.00
1581303 20.016.012.026492402080402
2,4-Dinitrotoluene Lin2ANT 5650 17328 +++++148721 246163 0.400 1.00 +++++5.00 8.00
398696 20.016.012.0677661538277
4-Nitrophenol Lin1ANT 2338 8445 +++++116602 210909 0.800 2.00 +++++10.0 16.0
322021 40.032.024.0576307451217
2,3,4,6-Tetrachlorophenol Lin2ANT 2905 11378 +++++99705 171695 0.400 1.00 +++++5.00 8.00
267927 20.016.012.0486254379708
Diethyl phthalate AveANT 32411 83803 +++++509565 836275 0.400 1.00 +++++5.00 8.00
1272911 20.016.012.021248581718458
Fluorene AveANT 36078 88178 +++++505410 813885 0.400 1.00 +++++5.00 8.00
1246801 20.016.012.021252111700285
4-Chlorophenyl phenyl ether AveANT 17214 41730 +++++231257 376519 0.400 1.00 +++++5.00 8.00
584276 20.016.012.0996317786763
4-Nitroaniline Lin2ANT 5717 18823 +++++135804 222739 0.400 1.00 +++++5.00 8.00
336126 20.016.012.0566105459721
4,6-Dinitro-2-methylphenol Lin2PHN +++++12927 +++++146339 255827 +++++2.00 +++++10.0 16.0
426731 40.032.024.0748688588460
Diphenylamine AveANT 23173 59253 +++++353433 579064 0.340 0.850 +++++4.25 6.80
906293 17.013.610.215009131224070
N-Nitrosodiphenylamine AvePHN 23257 59253 +++++351230 578020 0.400 1.00 +++++5.00 8.00
904429 20.016.012.015009131224070
FORM VI 8270E Page 601 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
GC Column:Rxi-5Sil MSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/ML)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8
1,2-Diphenylhydrazine AveANT 35621 98062 +++++617581 1042574 0.404 1.01 +++++5.05 8.09
1517008 20.216.212.125496282028147
Azobenzene AveANT 35621 98062 +++++617581 1042574 0.400 1.00 +++++5.00 8.00
1517008 20.016.012.025496282028147
4-Bromophenyl phenyl ether AvePHN 9571 22704 +++++132421 211753 0.400 1.00 +++++5.00 8.00
338868 20.016.012.0572937451832
Hexachlorobenzene AvePHN 12517 29029 +++++154269 249907 0.400 1.00 +++++5.00 8.00
386532 20.016.012.0670825521105
Pentachlorophenol Lin2PHN ++++++++++24950 122823 239268 ++++++++++4.00 10.0 16.0
377152 40.032.024.0707444527518
Phenanthrene AvePHN 56097 132840 +++++717333 1156073 0.400 1.00 +++++5.00 8.00
1763403 20.016.012.029320982358217
Anthracene AvePHN 45942 116600 +++++708461 1143161 0.400 1.00 +++++5.00 8.00
1761150 20.016.012.029067892360227
Carbazole AvePHN 43061 112772 +++++691600 1109460 0.400 1.00 +++++5.00 8.00
1678231 20.016.012.027377472221331
Alachlor AvePHN +++++11069 +++++84184 135031 +++++1.00 +++++5.00 8.00
218583 20.016.012.0371173297183
Di-n-butyl phthalate Lin2PHN 36761 111463 +++++815575 1368119 0.400 1.00 +++++5.00 8.00
2114908 20.016.012.034762552787044
Fluoranthene AvePHN 43822 112844 +++++700563 1165007 0.400 1.00 +++++5.00 8.00
1748852 20.016.012.030190782356043
Pyrene AveCRY 46775 119971 +++++747634 1215620 0.400 1.00 +++++5.00 8.00
1850943 20.016.012.030723442451259
Butyl benzyl phthalate Lin1CRY 11408 32524 +++++296648 529191 0.400 1.00 +++++5.00 8.00
820730 20.016.012.014198651103297
Benzo[a]anthracene AveCRY 35845 91543 +++++584001 976348 0.400 1.00 +++++5.00 8.00
1494796 20.016.012.025233241972157
Chrysene AveCRY 49255 114614 +++++649263 1036035 0.400 1.00 +++++5.00 8.00
1581733 20.016.012.025831692044368
Bis(2-ethylhexyl) phthalate Lin2PHN +++++41898 +++++388741 717023 +++++1.00 +++++5.00 8.00
1095096 20.016.012.019155691480342
Di-n-octyl phthalate Lin1CRY 19871 50626 +++++516441 1097541 0.400 1.00 +++++5.00 8.00
1596360 20.016.012.028754522169070
Benzo[b]fluoranthene Lin2PRY 23144 71549 +++++486362 813452 0.400 1.00 +++++5.00 8.00
1229979 20.016.012.020890951618717
Benzo[k]fluoranthene Lin2PRY 27744 81525 +++++579943 959155 0.400 1.00 +++++5.00 8.00
1449509 20.016.012.024008941896457
Benzo[a]pyrene Lin2PRY 22581 69520 +++++475010 814306 0.400 1.00 +++++5.00 8.00
1240314 20.016.012.021572791706176
Indeno[1,2,3-cd]pyrene Lin2CRY 16204 47732 +++++340719 631383 0.400 1.00 +++++5.00 8.00
FORM VI 8270E Page 602 of 1261
FORM VI
Lab Name:Job No.:
GC/MS SEMI VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-184424-1 Analy Batch No.:633956
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)SMS_1
87156Calibration Start Date:Calibration End Date:11/15/2023 07:12
N
11/15/2023 09:47
GC Column:Rxi-5Sil MSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/ML)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 6 LVL 7 LVL 8
908696 20.016.012.016141101246539
Dibenz(a,h)anthracene Lin2PRY 18157 53336 +++++366940 662776 0.400 1.00 +++++5.00 8.00
1019382 20.016.012.017586981352560
Benzo[g,h,i]perylene Lin2PRY 20784 60104 +++++429486 734554 0.400 1.00 +++++5.00 8.00
1103876 20.016.012.018702221467055
2-Fluorophenol (Surr)Lin2DCBd4 10321 29912 +++++221207 385383 0.400 1.00 +++++5.00 8.00
573184 20.016.012.01049530794092
Phenol-d5 (Surr)AveDCBd4 18585 49460 +++++300918 526364 0.400 1.00 +++++5.00 8.00
771986 20.016.012.013688021060875
Nitrobenzene-d5 (Surr)AveNPT 17669 43347 +++++269624 464142 0.400 1.00 +++++5.00 8.00
689042 20.016.012.01216114949279
2-Fluorobiphenyl AveANT 37483 87726 +++++491480 810957 0.400 1.00 +++++5.00 8.00
1230245 20.016.012.021099991659306
2,4,6-Tribromophenol (Surr)Lin2ANT 2076 9137 +++++67367 112922 0.400 1.00 +++++5.00 8.00
180140 20.016.012.0307928247929
Terphenyl-d14 (Surr)AveCRY 35689 88768 +++++536736 841424 0.400 1.00 +++++5.00 8.00
1312447 20.016.012.022035641748352
Curve Type Legend:
Ave = Average ISTD
Lin1 = Linear 1/conc ISTD
Lin2 = Linear 1/conc^2 ISTD
Qua = Quadratic ISTD
FORM VI 8270E Page 603 of 1261
Report Date: 16-Nov-2023 10:00:50 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523002.D
Lims ID:ICIS
Client ID:
Sample Type:ICIS Calib Level:5
Inject. Date:15-Nov-2023 07:12:09 ALS Bottle#:0 Worklist Smp#:3
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:ICIS
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:00:49 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 08:26:08
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.903 3.903 0.000 95 274108 8.00 8.00
* 2 Naphthalene-d8 136 5.071 5.071 0.000 99 1056827 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 94 570732 8.00 8.00
* 4 Phenanthrene-d10 188 8.208 8.208 0.000 97 1008571 8.00 8.00
* 5 Chrysene-d12 240 10.944 10.944 0.000 98 731083 8.00 8.00
* 6 Perylene-d12 264 13.132 13.132 0.000 97 678185 8.00 8.00
$ 7 2-Fluorophenol 112 2.849 2.849 0.000 94 385383 8.00 8.18
$ 8 Phenol-d5 99 3.651 3.651 0.000 96 526364 8.00 8.69
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 464142 8.00 8.39
$ 10 2-Fluorobiphenyl 172 6.128 6.128 0.000 99 810957 8.00 7.95
$ 11 2,4,6-Tribromophenol 330 7.536 7.536 0.000 94 112922 8.00 7.77
$ 12 Terphenyl-d14 244 9.807 9.807 0.000 96 841424 8.00 7.88
15 1,4-Dioxane 88 1.540 1.540 0.000 86 178913 8.00 8.11
17 N-Nitrosodimethylamine 74 1.749 1.749 0.000 82 282144 8.00 8.75
18 Pyridine 79 1.777 1.777 0.000 75 871936 16.0 17.2
31 Aniline 93 3.623 3.623 0.000 93 501747 8.00 8.41
29 Phenol 94 3.663 3.663 0.000 93 583032 8.00 8.67
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 87 460174 8.00 8.25
34 2-Chlorophenol 128 3.737 3.737 0.000 91 422978 8.00 8.46
35 n-Decane 43 3.789 3.789 0.000 92 766077 8.00 9.10
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 94 449527 8.00 7.91
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 466763 8.00 8.06
40 Benzyl alcohol 108 4.051 4.051 0.000 88 266872 8.00 7.86
43 1,2-Dichlorobenzene 146 4.051 4.051 0.000 95 446050 8.00 8.06
46 Indene 116 4.131 4.131 0.000 90 1440600 16.0 16.5
47 2,2'-oxybis[1-chloropropane] 45 4.174 4.174 0.000 92 1104488 8.00 9.14
45 2-Methylphenol 108 4.184 4.184 0.000 95 375339 8.00 8.60
52 Acetophenone 105 4.276 4.276 0.000 90 573150 8.00 8.39
54 N-Nitrosodi-n-propylamine 70 4.288 4.288 0.000 93 338892 8.00 8.68
50 3 & 4 Methylphenol 108 4.332 4.332 0.000 0 399400 8.00 8.64
Page 604 of 1261
Report Date: 16-Nov-2023 10:00:50 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523002.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.332 0.000 86 399400 8.00 8.64
51 4-Methylphenol 108 4.332 4.332 0.000 93 399400 8.00 8.64
56 Hexachloroethane 117 4.356 4.356 0.000 95 205683 8.00 8.36
58 Nitrobenzene 77 4.424 4.424 0.000 98 487212 8.00 8.45
60 Isophorone 82 4.655 4.655 0.000 95 834047 8.00 8.46
61 2-Nitrophenol 139 4.720 4.720 0.000 86 209315 8.00 7.76
62 2,4-Dimethylphenol 107 4.809 4.809 0.000 95 292264 8.00 8.62
66 Bis(2-chloroethoxy)methane 63 4.877 4.877 0.000 90 506242 8.00 8.54
69 Benzoic acid 105 4.969 4.969 0.000 90 482575 16.0 15.1
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 95 339925 8.00 8.28
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 92 369516 8.00 7.88
75 Naphthalene 128 5.090 5.090 0.000 97 1201607 8.00 8.05
77 4-Chloroaniline 127 5.164 5.164 0.000 93 470863 8.00 8.09
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 93 339346 8.00 8.21
80 Hexachlorobutadiene 225 5.225 5.225 0.000 96 192955 8.00 7.72
85 4-Chloro-3-methylphenol 107 5.678 5.678 0.000 94 348914 8.00 8.66
88 2-Methylnaphthalene 141 5.758 5.758 0.000 93 660537 8.00 8.12
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 720213 8.00 8.09
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 97 80139 8.00 7.95
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 98 345862 8.00 7.64
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 399948 8.00 8.10
93 2,4,6-Trichlorophenol 196 6.054 6.054 0.000 94 230934 8.00 8.44
95 2,4,5-Trichlorophenol 196 6.103 6.103 0.000 92 244227 8.00 7.97
97 1,1'-Biphenyl 154 6.217 6.217 0.000 96 945287 8.00 8.03
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 752515 8.00 8.02
101 2-Nitroaniline 65 6.344 6.344 0.000 78 288255 8.00 8.15
104 Dimethyl phthalate 163 6.544 6.544 0.000 97 802746 8.00 8.09
105 1,3-Dinitrobenzene 168 6.553 6.553 0.000 83 124704 8.00 7.69
106 2,6-Dinitrotoluene 165 6.587 6.587 0.000 85 184766 8.00 7.82
107 Acenaphthylene 152 6.621 6.621 0.000 99 1137918 8.00 8.43
108 3-Nitroaniline 138 6.748 6.748 0.000 84 219366 8.00 7.93
109 Acenaphthene 153 6.794 6.794 0.000 96 748834 8.00 8.05
111 2,4-Dinitrophenol 184 6.852 6.852 0.000 77 136366 16.0 16.0
114 Dibenzofuran 168 6.966 6.966 0.000 96 1028737 8.00 7.97
116 2,4-Dinitrotoluene 165 6.976 6.976 0.000 88 246163 8.00 7.82
113 4-Nitrophenol 109 6.997 6.997 0.000 82 210909 16.0 15.8
120 2,3,4,6-Tetrachlorophenol 232 7.105 7.105 0.000 78 171695 8.00 7.86
124 Diethyl phthalate 149 7.244 7.244 0.000 97 836275 8.00 8.23
122 Hexadecane 57 7.284 7.284 0.000 87 923350 8.00 9.10
127 Fluorene 166 7.299 7.299 0.000 93 813885 8.00 7.92
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 94 376519 8.00 7.85
130 4-Nitroaniline 138 7.345 7.345 0.000 81 222739 8.00 8.02
131 4,6-Dinitro-2-methylphenol 198 7.370 7.370 0.000 78 255827 16.0 15.3
132 Diphenylamine 169 7.441 7.441 0.000 91 579064 6.80 6.87
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 67 578020 8.00 8.22
135 Azobenzene 77 7.472 7.472 0.000 96 1042574 8.00 8.64
136 1,2-Diphenylhydrazine 77 7.472 7.472 0.000 44 1042574 8.09 8.74
145 4-Bromophenyl phenyl ether 248 7.795 7.795 0.000 75 211753 8.00 7.93
148 Hexachlorobenzene 284 7.829 7.829 0.000 93 249907 8.00 7.82
153 Pentachlorophenol 266 8.048 8.048 0.000 90 239268 16.0 16.1
154 n-Octadecane 57 8.196 8.196 0.000 88 933307 8.00 8.67
157 Phenanthrene 178 8.233 8.233 0.000 99 1156073 8.00 7.97
Page 605 of 1261
Report Date: 16-Nov-2023 10:00:50 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523002.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.282 8.282 0.000 99 1143161 8.00 8.28
161 Carbazole 167 8.461 8.461 0.000 96 1109460 8.00 8.41
163 Alachlor 188 8.627 8.627 0.000 87 135031 8.00 8.06
164 Di-n-butyl phthalate 149 8.858 8.858 0.000 99 1368119 8.00 8.16
170 Fluoranthene 202 9.398 9.398 0.000 99 1165007 8.00 8.47
172 Pyrene 202 9.613 9.613 0.000 96 1215620 8.00 8.20
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 97 529191 8.00 7.81
184 Benzo[a]anthracene 228 10.932 10.932 0.000 100 976348 8.00 8.30
185 Chrysene 228 10.975 10.975 0.000 97 1036035 8.00 7.86
186 Bis(2-ethylhexyl) phthalate 149 11.120 11.120 0.000 94 717023 8.00 8.16
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 98 1097541 8.00 8.19
191 Benzo[b]fluoranthene 252 12.510 12.510 0.000 98 813452 8.00 7.88
193 Benzo[k]fluoranthene 252 12.556 12.556 0.000 98 959155 8.00 7.94
194 Benzo[a]pyrene 252 13.037 13.037 0.000 81 814306 8.00 7.79
198 Indeno[1,2,3-cd]pyrene 276 15.015 15.015 0.000 97 631383 8.00 8.32
199 Dibenz(a,h)anthracene 278 15.092 15.092 0.000 96 662776 8.00 7.91
200 Benzo[g,h,i]perylene 276 15.465 15.465 0.000 95 734554 8.00 7.97
305 Alpha Methyl Styrene 1 0.000 ND ND
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-RVHSL-WS_00003 Amount Added: 200.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 606 of 1261
Report Date: 16-Nov-2023 10:00:50 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523002.D
Injection Date:15-Nov-2023 07:12:09 Instrument ID:SMS_1 Operator ID:MB
Lims ID:ICIS Worklist Smp#:3
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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Y ( X10
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-111523002[MS Quad Chro]:Total
$ 2
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Page 607 of 1261
Report Date: 16-Nov-2023 10:00:53 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Lims ID:STD004 HSL
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:15-Nov-2023 09:47:48 ALS Bottle#:0 Worklist Smp#:4
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD004
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:00:53 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 10:34:02
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.903 0.001 96 268628 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.071 0.001 99 979829 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 94 530111 8.00 8.00
* 4 Phenanthrene-d10 188 8.208 8.208 0.000 97 967055 8.00 8.00
* 5 Chrysene-d12 240 10.942 10.944 -0.002 99 669301 8.00 8.00
* 6 Perylene-d12 264 13.133 13.132 0.001 97 619324 8.00 8.00
$ 7 2-Fluorophenol 112 2.871 2.849 0.022 93 10321 0.4000 0.4180
$ 8 Phenol-d5 99 3.666 3.651 0.015 97 18585 0.4000 0.3132
$ 9 Nitrobenzene-d5 82 4.409 4.406 0.003 96 17669 0.4000 0.3445
$ 10 2-Fluorobiphenyl 172 6.128 6.128 0.000 99 37483 0.4000 0.3955
$ 11 2,4,6-Tribromophenol 330 7.540 7.536 0.004 87 2076 0.4000 0.4065 a
$ 12 Terphenyl-d14 244 9.808 9.807 0.001 97 35689 0.4000 0.3650
15 1,4-Dioxane 88 1.540 1.540 0.000 85 7887 0.4000 0.3649
17 N-Nitrosodimethylamine 74 1.768 1.749 0.019 90 9333 0.4000 0.2954
18 Pyridine 79 1.793 1.777 0.016 77 33695 0.8000 0.6799
31 Aniline 93 3.626 3.623 0.003 91 19066 0.4000 0.3260
29 Phenol 94 3.679 3.663 0.016 91 20463 0.4000 0.3105
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 85 21171 0.4000 0.3871
34 2-Chlorophenol 128 3.746 3.737 0.009 92 16470 0.4000 0.3361
35 n-Decane 43 3.790 3.789 0.001 92 31114 0.4000 0.3770
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 95 21480 0.4000 0.3857
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 93 22717 0.4000 0.4004
40 Benzyl alcohol 108 4.061 4.051 0.010 87 7555 0.4000 0.4021
43 1,2-Dichlorobenzene 146 4.052 4.051 0.001 94 21095 0.4000 0.3889
46 Indene 116 4.132 4.131 0.001 91 63858 0.8000 0.7460
47 2,2'-oxybis[1-chloropropane] 45 4.172 4.174 -0.002 92 43224 0.4000 0.3650
45 2-Methylphenol 108 4.190 4.184 0.006 93 13167 0.4000 0.3079
52 Acetophenone 105 4.277 4.276 0.000 90 22717 0.4000 0.3395
54 N-Nitrosodi-n-propylamine 70 4.289 4.288 0.001 95 12453 0.4000 0.3255
50 3 & 4 Methylphenol 108 4.344 4.332 0.012 0 14215 0.4000 0.3139
Page 608 of 1261
Report Date: 16-Nov-2023 10:00:53 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.344 4.332 0.012 88 14215 0.4000 0.3139
51 4-Methylphenol 108 4.344 4.332 0.012 91 14215 0.4000 0.3139
56 Hexachloroethane 117 4.357 4.356 0.001 92 8366 0.4000 0.3468
58 Nitrobenzene 77 4.424 4.424 0.000 96 17594 0.4000 0.3290
60 Isophorone 82 4.656 4.655 0.001 95 29424 0.4000 0.3219
61 2-Nitrophenol 139 4.726 4.720 0.006 87 6146 0.4000 0.4119
62 2,4-Dimethylphenol 107 4.813 4.809 0.004 90 9880 0.4000 0.3141
66 Bis(2-chloroethoxy)methane 63 4.880 4.877 0.003 92 19402 0.4000 0.3529
69 Benzoic acid 105 4.982 4.969 0.013 33 1089 0.8000 1.34
70 2,4-Dichlorophenol 162 4.991 4.976 0.015 94 12700 0.4000 0.3335
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 92 17979 0.4000 0.4135
75 Naphthalene 128 5.090 5.090 0.000 97 56343 0.4000 0.4071
77 4-Chloroaniline 127 5.170 5.164 0.006 93 18985 0.4000 0.3517
78 2,6-Dichlorophenol 162 5.176 5.173 0.003 91 13461 0.4000 0.3512
80 Hexachlorobutadiene 225 5.226 5.225 0.001 96 8996 0.4000 0.3881
85 4-Chloro-3-methylphenol 107 5.691 5.678 0.013 93 11320 0.4000 0.3029
88 2-Methylnaphthalene 141 5.762 5.758 0.004 93 27254 0.4000 0.3614
89 1-Methylnaphthalene 142 5.851 5.851 0.000 92 30464 0.4000 0.3692
92 Hexachlorocyclopentadiene 237 5.919 ND ND
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 98 17205 0.4000 0.4098
94 2,3-Dichlorobenzenamine 161 6.042 6.039 0.003 95 16358 0.4000 0.3568
93 2,4,6-Trichlorophenol 196 6.058 6.054 0.004 95 7470 0.4000 0.2940
95 2,4,5-Trichlorophenol 196 6.122 6.103 0.019 86 7328 0.4000 0.4098
97 1,1'-Biphenyl 154 6.221 6.217 0.004 96 41368 0.4000 0.3783
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 31959 0.4000 0.3668
101 2-Nitroaniline 65 6.350 6.344 0.006 77 7485 0.4000 0.4177
104 Dimethyl phthalate 163 6.544 6.544 0.000 98 32863 0.4000 0.3565
105 1,3-Dinitrobenzene 168 6.557 6.553 0.004 77 3463 0.4000 0.4262
106 2,6-Dinitrotoluene 165 6.588 6.587 0.001 76 4331 0.4000 0.4126
107 Acenaphthylene 152 6.622 6.621 0.001 98 41716 0.4000 0.3327
108 3-Nitroaniline 138 6.757 6.748 0.009 33 5925 0.4000 0.4120
109 Acenaphthene 153 6.794 6.794 0.000 96 32926 0.4000 0.3812
111 2,4-Dinitrophenol 184 6.852 ND ND
114 Dibenzofuran 168 6.967 6.966 0.001 96 46192 0.4000 0.3852
116 2,4-Dinitrotoluene 165 6.979 6.976 0.003 91 5650 0.4000 0.4226
113 4-Nitrophenol 109 7.047 6.997 0.050 81 2338 0.8000 1.02
120 2,3,4,6-Tetrachlorophenol 232 7.115 7.105 0.010 73 2905 0.4000 0.4215
124 Diethyl phthalate 149 7.241 7.244 -0.003 97 32411 0.4000 0.3436
122 Hexadecane 57 7.284 7.284 0.000 87 28360 0.4000 0.3010
127 Fluorene 166 7.299 7.299 0.000 95 36078 0.4000 0.3782
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 93 17214 0.4000 0.3863
130 4-Nitroaniline 138 7.349 7.345 0.004 78 5717 0.4000 0.4059
131 4,6-Dinitro-2-methylphenol 198 7.380 7.370 0.010 71 2807 0.8000 1.41
132 Diphenylamine 169 7.441 7.441 0.000 92 23173 0.3400 0.2961
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 64 23257 0.4000 0.3450
135 Azobenzene 77 7.475 7.472 0.003 97 35621 0.4000 0.3178
136 1,2-Diphenylhydrazine 77 7.475 7.472 0.003 41 35621 0.4044 0.3213
145 4-Bromophenyl phenyl ether 248 7.796 7.795 0.001 73 9571 0.4000 0.3739
148 Hexachlorobenzene 284 7.829 7.829 0.000 93 12517 0.4000 0.4085
153 Pentachlorophenol 266 8.054 8.048 0.006 82 957 0.8000 2.69
154 n-Octadecane 57 8.196 8.196 0.000 91 23896 0.4000 0.4178
157 Phenanthrene 178 8.230 8.233 -0.003 97 56097 0.4000 0.4033
Page 609 of 1261
Report Date: 16-Nov-2023 10:00:53 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.282 8.282 0.000 98 45942 0.4000 0.3471
161 Carbazole 167 8.464 8.461 0.003 96 43061 0.4000 0.3404
163 Alachlor 188 8.624 8.627 -0.003 89 3882 0.4000 0.2417
164 Di-n-butyl phthalate 149 8.859 8.858 0.001 99 36761 0.4000 0.4146
170 Fluoranthene 202 9.398 9.398 0.000 98 43822 0.4000 0.3325
172 Pyrene 202 9.614 9.613 0.001 96 46775 0.4000 0.3447
180 Butyl benzyl phthalate 149 10.350 10.353 -0.003 96 11408 0.4000 0.4858
184 Benzo[a]anthracene 228 10.933 10.932 0.001 99 35845 0.4000 0.3329
185 Chrysene 228 10.976 10.975 0.001 97 49255 0.4000 0.4083
186 Bis(2-ethylhexyl) phthalate 149 11.117 11.120 -0.003 93 15475 0.4000 0.6902
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 98 19871 0.4000 0.5276
191 Benzo[b]fluoranthene 252 12.507 12.510 -0.003 97 23144 0.4000 0.4108
193 Benzo[k]fluoranthene 252 12.556 12.556 0.000 98 27744 0.4000 0.4138
194 Benzo[a]pyrene 252 13.037 13.037 0.000 78 22581 0.4000 0.4147
198 Indeno[1,2,3-cd]pyrene 276 15.015 15.015 0.000 98 16204 0.4000 0.4161
199 Dibenz(a,h)anthracene 278 15.089 15.092 -0.003 96 18157 0.4000 0.4194
200 Benzo[g,h,i]perylene 276 15.462 15.465 -0.003 96 20784 0.4000 0.4171
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 0.6217
S 212 Methyl Phenols,Total 108 0 0.6217
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
a - User Assigned ID
Reagents:
MS-RVHSL-WS_00003 Amount Added: 10.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 610 of 1261
Report Date: 16-Nov-2023 10:00:53 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Injection Date:15-Nov-2023 09:47:48 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD004 HSL Worklist Smp#:4
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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-111523009[MS Quad Chro]:Total
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Page 611 of 1261
Report Date: 16-Nov-2023 10:00:53 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Injection Date:15-Nov-2023 09:47:48 Instrument ID:SMS_1
Lims ID:STD004 HSL
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:4
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column:Rxi-5Sil MS ( 0.25 mm)Detector MS SCAN
$ 11 2,4,6-Tribromophenol, CAS: 118-79-6
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 7.54
7.2 7.4 7.6 7.8
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
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-111523009[MS Quad Chro]:m/z 330
Manual Integration Results
RT: 7.54
Area: 2076
Amount: 0.406459
Amount Units: ug/ml
7.2 7.4 7.6 7.8
Min
RT
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16
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-111523009[MS Quad Chro]:m/z 330

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Reviewer: FP7E, 15-Nov-2023 10:33:05 -07:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Assign Peak
Page 612 of 1261
Report Date: 16-Nov-2023 10:00:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523008.D
Lims ID:STD01 HSL
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:15-Nov-2023 09:25:26 ALS Bottle#:0 Worklist Smp#:5
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD01
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:00:56 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 10:32:54
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.907 3.903 0.004 95 249304 8.00 8.00
* 2 Naphthalene-d8 136 5.071 5.071 0.000 99 919593 8.00 8.00
* 3 Acenaphthene-d10 164 6.760 6.763 -0.003 95 494383 8.00 8.00
* 4 Phenanthrene-d10 188 8.208 8.208 0.000 97 920189 8.00 8.00
* 5 Chrysene-d12 240 10.942 10.944 -0.002 98 631435 8.00 8.00
* 6 Perylene-d12 264 13.133 13.132 0.001 97 602620 8.00 8.00
$ 7 2-Fluorophenol 112 2.862 2.849 0.013 93 29912 1.00 0.8811
$ 8 Phenol-d5 99 3.660 3.651 0.009 96 49460 1.00 0.8981
$ 9 Nitrobenzene-d5 82 4.409 4.406 0.003 96 43347 1.00 0.9006
$ 10 2-Fluorobiphenyl 172 6.128 6.128 0.000 100 87726 1.00 0.99
$ 11 2,4,6-Tribromophenol 330 7.540 7.536 0.004 90 9137 1.00 0.9594
$ 12 Terphenyl-d14 244 9.808 9.807 0.001 97 88768 1.00 0.9624
15 1,4-Dioxane 88 1.537 1.540 -0.003 91 20283 1.00 1.01
17 N-Nitrosodimethylamine 74 1.756 1.749 0.007 84 25555 1.00 0.8716
18 Pyridine 79 1.783 1.777 0.006 76 83296 2.00 1.81
31 Aniline 93 3.626 3.623 0.003 93 49459 1.00 0.9113
29 Phenol 94 3.672 3.663 0.009 91 53613 1.00 0.8765
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 91 50132 1.00 0.9876
34 2-Chlorophenol 128 3.743 3.737 0.006 92 40599 1.00 0.8928
35 n-Decane 43 3.790 3.789 0.001 91 72078 1.00 0.9412
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 95 51081 1.00 0.9882
37 1,4-Dichlorobenzene 146 3.922 3.919 0.003 92 52409 1.00 1.00
40 Benzyl alcohol 108 4.058 4.051 0.007 89 25549 1.00 0.9888
43 1,2-Dichlorobenzene 146 4.051 4.051 0.000 94 49874 1.00 0.99
46 Indene 116 4.132 4.131 0.001 89 154307 2.00 1.94
47 2,2'-oxybis[1-chloropropane] 45 4.172 4.174 -0.002 92 105198 1.00 0.9572
45 2-Methylphenol 108 4.187 4.184 0.003 94 35817 1.00 0.9024
52 Acetophenone 105 4.276 4.276 0.000 90 57731 1.00 0.9296
54 N-Nitrosodi-n-propylamine 70 4.289 4.288 0.001 92 31817 1.00 0.8960
50 3 & 4 Methylphenol 108 4.338 4.332 0.006 0 34965 1.00 0.8319
Page 613 of 1261
Report Date: 16-Nov-2023 10:00:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523008.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.338 4.332 0.006 88 34965 1.00 0.8319
51 4-Methylphenol 108 4.338 4.332 0.006 94 34965 1.00 0.8319
56 Hexachloroethane 117 4.357 4.356 0.001 93 21442 1.00 0.9578
58 Nitrobenzene 77 4.424 4.424 0.000 95 47980 1.00 0.9561
60 Isophorone 82 4.655 4.655 0.000 95 77405 1.00 0.9023
61 2-Nitrophenol 139 4.723 4.720 0.003 88 18083 1.00 0.9248
62 2,4-Dimethylphenol 107 4.813 4.809 0.004 95 25745 1.00 0.8722
66 Bis(2-chloroethoxy)methane 63 4.880 4.877 0.003 90 49599 1.00 0.9614
69 Benzoic acid 105 4.933 4.969 -0.036 89 21901 2.00 2.03 a
70 2,4-Dichlorophenol 162 4.985 4.976 0.009 96 32731 1.00 0.9157
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 40806 1.00 1.00
75 Naphthalene 128 5.093 5.090 0.003 97 133623 1.00 1.03
77 4-Chloroaniline 127 5.167 5.164 0.003 94 47924 1.00 0.9460
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 90 32436 1.00 0.9017
80 Hexachlorobutadiene 225 5.229 5.225 0.004 96 21844 1.00 1.00
85 4-Chloro-3-methylphenol 107 5.688 5.678 0.010 94 28798 1.00 0.8211
88 2-Methylnaphthalene 141 5.759 5.758 0.001 92 69713 1.00 0.9851
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 76209 1.00 0.9841
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 51 1125 1.00 2.63
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 98 37945 1.00 0.9630
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 40066 1.00 0.9371
93 2,4,6-Trichlorophenol 196 6.061 6.054 0.007 96 20108 1.00 0.8487
95 2,4,5-Trichlorophenol 196 6.116 6.103 0.013 94 21212 1.00 0.9405
97 1,1'-Biphenyl 154 6.218 6.217 0.001 95 101022 1.00 0.99
98 2-Chloronaphthalene 162 6.224 6.224 0.000 96 80820 1.00 0.99
101 2-Nitroaniline 65 6.347 6.344 0.003 77 21595 1.00 0.8836
104 Dimethyl phthalate 163 6.544 6.544 0.000 98 81141 1.00 0.9438
105 1,3-Dinitrobenzene 168 6.557 6.553 0.004 79 9138 1.00 0.8359
106 2,6-Dinitrotoluene 165 6.588 6.587 0.001 83 14601 1.00 0.9138
107 Acenaphthylene 152 6.621 6.621 0.000 99 107237 1.00 0.9170
108 3-Nitroaniline 138 6.751 6.748 0.003 83 17955 1.00 0.9183
109 Acenaphthene 153 6.791 6.794 -0.003 96 79504 1.00 0.9871
111 2,4-Dinitrophenol 184 6.871 6.852 0.019 68 1007 2.00 2.11
114 Dibenzofuran 168 6.967 6.966 0.001 96 111781 1.00 1.00
116 2,4-Dinitrotoluene 165 6.976 6.976 0.000 86 17328 1.00 0.8514
113 4-Nitrophenol 109 7.022 6.997 0.025 81 8445 2.00 1.53
120 2,3,4,6-Tetrachlorophenol 232 7.114 7.105 0.009 79 11378 1.00 0.8634
124 Diethyl phthalate 149 7.241 7.244 -0.003 97 83803 1.00 0.9526
122 Hexadecane 57 7.284 7.284 0.000 88 76650 1.00 0.8725
127 Fluorene 166 7.299 7.299 0.000 94 88178 1.00 0.99
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 95 41730 1.00 1.00
130 4-Nitroaniline 138 7.346 7.345 0.001 80 18823 1.00 0.9537
131 4,6-Dinitro-2-methylphenol 198 7.373 7.370 0.003 78 12927 2.00 2.02
132 Diphenylamine 169 7.441 7.441 0.000 91 59253 0.8500 0.8118
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 65 59253 1.00 0.9237
135 Azobenzene 77 7.472 7.472 0.000 97 98062 1.00 0.9382
136 1,2-Diphenylhydrazine 77 7.472 7.472 0.000 41 98062 1.01 0.9485
145 4-Bromophenyl phenyl ether 248 7.795 7.795 0.000 75 22704 1.00 0.9321
148 Hexachlorobenzene 284 7.832 7.829 0.003 93 29029 1.00 1.00
153 Pentachlorophenol 266 8.051 8.048 0.003 86 6840 2.00 3.06
154 n-Octadecane 57 8.196 8.196 0.000 89 69541 1.00 0.8836
157 Phenanthrene 178 8.230 8.233 -0.003 98 132840 1.00 1.00
Page 614 of 1261
Report Date: 16-Nov-2023 10:00:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523008.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.282 8.282 0.000 98 116600 1.00 0.9257
161 Carbazole 167 8.464 8.461 0.003 96 112772 1.00 0.9370
163 Alachlor 188 8.627 8.627 0.000 89 11069 1.00 0.7242
164 Di-n-butyl phthalate 149 8.859 8.858 0.001 99 111463 1.00 0.9028
170 Fluoranthene 202 9.398 9.398 0.000 99 112844 1.00 0.8997
172 Pyrene 202 9.614 9.613 0.001 97 119971 1.00 0.9372
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 98 32524 1.00 0.8431
184 Benzo[a]anthracene 228 10.932 10.932 0.000 99 91543 1.00 0.9012
185 Chrysene 228 10.976 10.975 0.001 98 114614 1.00 1.01
186 Bis(2-ethylhexyl) phthalate 149 11.117 11.120 -0.003 95 41898 1.00 1.01
189 Di-n-octyl phthalate 149 12.122 12.119 0.003 98 50626 1.00 0.7906
191 Benzo[b]fluoranthene 252 12.507 12.510 -0.003 98 71549 1.00 0.9340
193 Benzo[k]fluoranthene 252 12.553 12.556 -0.003 99 81525 1.00 0.9112
194 Benzo[a]pyrene 252 13.034 13.037 -0.003 78 69520 1.00 0.9147
198 Indeno[1,2,3-cd]pyrene 276 15.018 15.015 0.003 99 47732 1.00 0.8999
199 Dibenz(a,h)anthracene 278 15.086 15.092 -0.006 95 53336 1.00 0.8874
200 Benzo[g,h,i]perylene 276 15.468 15.465 0.003 96 60104 1.00 0.8936
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 1.73
S 212 Methyl Phenols,Total 108 0 1.73
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
a - User Assigned ID
Reagents:
MS-RVHSL-WS_00003 Amount Added: 25.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 615 of 1261
Report Date: 16-Nov-2023 10:00:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523008.D
Injection Date:15-Nov-2023 09:25:26 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD01 HSL Worklist Smp#:5
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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-111523008[MS Quad Chro]:Total
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Page 616 of 1261
Report Date: 16-Nov-2023 10:00:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523008.D
Injection Date:15-Nov-2023 09:25:26 Instrument ID:SMS_1
Lims ID:STD01 HSL
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:5
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column:Rxi-5Sil MS ( 0.25 mm)Detector MS SCAN
69 Benzoic acid, CAS: 65-85-0
Signal: 1
Processing Integration Results
RT: 5.00
Area: 1555
Amount: 1.320059
Amount Units: ug/ml
4.6 4.8 5.0 5.2
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-111523008[MS Quad Chro]:m/z 105

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Manual Integration Results
RT: 4.93
Area: 21901
Amount: 2.028455
Amount Units: ug/ml
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-111523008[MS Quad Chro]:m/z 105

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Reviewer: FP7E, 15-Nov-2023 10:32:36 -07:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Assign Peak
Page 617 of 1261
Report Date: 16-Nov-2023 10:01:00 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523007.D
Lims ID:STD02 HSL
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:15-Nov-2023 09:03:07 ALS Bottle#:0 Worklist Smp#:6
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD02
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:00:59 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 09:27:04
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.903 0.001 95 268538 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.071 0.001 99 999258 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 95 542716 8.00 8.00
* 4 Phenanthrene-d10 188 8.209 8.208 0.001 97 998953 8.00 8.00
* 5 Chrysene-d12 240 10.942 10.944 -0.002 98 695831 8.00 8.00
* 6 Perylene-d12 264 13.136 13.132 0.004 97 653947 8.00 8.00
$ 7 2-Fluorophenol 112 2.856 2.849 0.007 94 72741 2.00 1.74
$ 8 Phenol-d5 99 3.657 3.651 0.006 97 105402 2.00 1.78
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 93730 2.00 1.79
$ 10 2-Fluorobiphenyl 172 6.129 6.128 0.001 100 181836 2.00 1.87
$ 11 2,4,6-Tribromophenol 330 7.540 7.536 0.004 89 22201 2.00 1.81
$ 12 Terphenyl-d14 244 9.808 9.807 0.001 97 183793 2.00 1.81
15 1,4-Dioxane 88 1.537 1.540 -0.003 89 39679 2.00 1.84
17 N-Nitrosodimethylamine 74 1.753 1.749 0.004 85 56653 2.00 1.79
18 Pyridine 79 1.781 1.777 0.004 78 175318 4.00 3.54
31 Aniline 93 3.623 3.623 0.000 93 103036 2.00 1.76
29 Phenol 94 3.670 3.663 0.007 92 116552 2.00 1.77
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 90 100570 2.00 1.84
34 2-Chlorophenol 128 3.740 3.737 0.003 91 88922 2.00 1.82
35 n-Decane 43 3.790 3.789 0.001 92 148366 2.00 1.80
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 96 102662 2.00 1.84
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 93 104916 2.00 1.85
40 Benzyl alcohol 108 4.055 4.051 0.004 88 50551 2.00 1.67
43 1,2-Dichlorobenzene 146 4.052 4.051 0.001 96 99739 2.00 1.84
46 Indene 116 4.132 4.131 0.001 89 313677 4.00 3.67
47 2,2'-oxybis[1-chloropropane] 45 4.172 4.174 -0.002 92 212957 2.00 1.80
45 2-Methylphenol 108 4.187 4.184 0.003 94 79700 2.00 1.86
52 Acetophenone 105 4.277 4.276 0.001 91 121174 2.00 1.81
54 N-Nitrosodi-n-propylamine 70 4.289 4.288 0.001 92 66820 2.00 1.75
50 3 & 4 Methylphenol 108 4.335 4.332 0.003 0 80567 2.00 1.78
Page 618 of 1261
Report Date: 16-Nov-2023 10:01:00 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523007.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.335 4.332 0.003 86 80567 2.00 1.78
51 4-Methylphenol 108 4.335 4.332 0.003 93 80567 2.00 1.78
56 Hexachloroethane 117 4.357 4.356 0.001 95 44025 2.00 1.83
58 Nitrobenzene 77 4.425 4.424 0.001 97 99680 2.00 1.83
60 Isophorone 82 4.656 4.655 0.001 96 168060 2.00 1.80
61 2-Nitrophenol 139 4.723 4.720 0.003 87 41149 2.00 1.75
62 2,4-Dimethylphenol 107 4.810 4.809 0.001 86 57050 2.00 1.78
66 Bis(2-chloroethoxy)methane 63 4.881 4.877 0.004 92 101875 2.00 1.82
69 Benzoic acid 105 4.936 4.969 -0.033 85 62311 4.00 3.19
70 2,4-Dichlorophenol 162 4.982 4.976 0.006 96 70924 2.00 1.83
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 83395 2.00 1.88
75 Naphthalene 128 5.090 5.090 0.000 97 267972 2.00 1.90
77 4-Chloroaniline 127 5.164 5.164 0.000 94 97613 2.00 1.77
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 92 71088 2.00 1.82
80 Hexachlorobutadiene 225 5.226 5.225 0.001 97 43372 2.00 1.83
85 4-Chloro-3-methylphenol 107 5.685 5.678 0.007 95 68437 2.00 1.80
88 2-Methylnaphthalene 141 5.759 5.758 0.001 92 144696 2.00 1.88
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 156887 2.00 1.86
92 Hexachlorocyclopentadiene 237 5.922 5.919 0.003 75 7760 2.00 3.10
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 95 80264 2.00 1.87
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 83804 2.00 1.79
93 2,4,6-Trichlorophenol 196 6.055 6.054 0.001 95 45396 2.00 1.75
95 2,4,5-Trichlorophenol 196 6.113 6.103 0.010 93 47265 2.00 1.75
97 1,1'-Biphenyl 154 6.221 6.217 0.004 97 204121 2.00 1.82
98 2-Chloronaphthalene 162 6.224 6.224 0.000 96 162501 2.00 1.82
101 2-Nitroaniline 65 6.344 6.344 0.000 77 49736 2.00 1.64
104 Dimethyl phthalate 163 6.545 6.544 0.001 98 175262 2.00 1.86
105 1,3-Dinitrobenzene 168 6.554 6.553 0.001 84 22150 2.00 1.60
106 2,6-Dinitrotoluene 165 6.588 6.587 0.001 88 36768 2.00 1.81
107 Acenaphthylene 152 6.622 6.621 0.001 99 236272 2.00 1.84
108 3-Nitroaniline 138 6.751 6.748 0.003 85 42156 2.00 1.75
109 Acenaphthene 153 6.794 6.794 0.000 97 161941 2.00 1.83
111 2,4-Dinitrophenol 184 6.865 6.852 0.013 80 9126 4.00 3.18
114 Dibenzofuran 168 6.964 6.966 -0.002 96 230573 2.00 1.88
116 2,4-Dinitrotoluene 165 6.979 6.976 0.003 88 45136 2.00 1.70
113 4-Nitrophenol 109 7.013 6.997 0.016 84 28632 4.00 2.98
120 2,3,4,6-Tetrachlorophenol 232 7.109 7.105 0.004 77 29853 2.00 1.67
124 Diethyl phthalate 149 7.241 7.244 -0.003 97 177693 2.00 1.84
122 Hexadecane 57 7.284 7.284 0.000 87 172633 2.00 1.79
127 Fluorene 166 7.300 7.299 0.001 94 185442 2.00 1.90
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 94 87391 2.00 1.92
130 4-Nitroaniline 138 7.343 7.345 -0.002 83 43310 2.00 1.79
131 4,6-Dinitro-2-methylphenol 198 7.370 7.370 0.000 70 36188 4.00 3.25
132 Diphenylamine 169 7.441 7.441 0.000 92 127932 1.70 1.60
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 64 128986 2.00 1.85
135 Azobenzene 77 7.472 7.472 0.000 96 213464 2.00 1.86
136 1,2-Diphenylhydrazine 77 7.472 7.472 0.000 41 213464 2.02 1.88
145 4-Bromophenyl phenyl ether 248 7.796 7.795 0.001 74 46063 2.00 1.74
148 Hexachlorobenzene 284 7.830 7.829 0.001 92 55854 2.00 1.76
153 Pentachlorophenol 266 8.051 8.048 0.003 90 24950 4.00 4.05
154 n-Octadecane 57 8.196 8.196 0.000 88 161058 2.00 1.67
157 Phenanthrene 178 8.230 8.233 -0.003 98 272693 2.00 1.90
Page 619 of 1261
Report Date: 16-Nov-2023 10:01:00 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523007.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.282 0.001 96 242707 2.00 1.77
161 Carbazole 167 8.461 8.461 0.000 96 241455 2.00 1.85
163 Alachlor 188 8.628 8.627 0.001 88 24530 2.00 1.48
164 Di-n-butyl phthalate 149 8.859 8.858 0.001 99 257928 2.00 1.71
170 Fluoranthene 202 9.398 9.398 0.000 99 243899 2.00 1.79
172 Pyrene 202 9.614 9.613 0.001 97 257172 2.00 1.82
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 98 82180 2.00 1.53
184 Benzo[a]anthracene 228 10.933 10.932 0.001 100 191146 2.00 1.71
185 Chrysene 228 10.976 10.975 0.001 97 239409 2.00 1.91
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.120 0.001 95 102036 2.00 1.62
189 Di-n-octyl phthalate 149 12.116 12.119 -0.003 98 122215 2.00 1.29
191 Benzo[b]fluoranthene 252 12.510 12.510 0.000 96 155650 2.00 1.70
193 Benzo[k]fluoranthene 252 12.554 12.556 -0.002 98 194767 2.00 1.80
194 Benzo[a]pyrene 252 13.034 13.037 -0.003 79 149647 2.00 1.63
198 Indeno[1,2,3-cd]pyrene 276 15.019 15.015 0.004 98 98971 2.00 1.53
199 Dibenz(a,h)anthracene 278 15.093 15.092 0.001 95 113591 2.00 1.56
200 Benzo[g,h,i]perylene 276 15.469 15.465 0.004 97 133499 2.00 1.65
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 3.64
S 212 Methyl Phenols,Total 108 0 3.64
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-RVHSL-WS_00003 Amount Added: 50.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 620 of 1261
Report Date: 16-Nov-2023 10:01:00 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523007.D
Injection Date:15-Nov-2023 09:03:07 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD02 HSL Worklist Smp#:6
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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-111523007[MS Quad Chro]:Total
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Page 621 of 1261
Report Date: 16-Nov-2023 10:01:03 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523006.D
Lims ID:STD05 HSL
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:15-Nov-2023 08:40:46 ALS Bottle#:0 Worklist Smp#:7
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD05
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:01:03 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 09:17:17
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.903 0.001 95 259318 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.071 0.001 99 989147 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 95 536309 8.00 8.00
* 4 Phenanthrene-d10 188 8.209 8.208 0.001 97 989771 8.00 8.00
* 5 Chrysene-d12 240 10.942 10.944 -0.002 98 696790 8.00 8.00
* 6 Perylene-d12 264 13.133 13.132 0.001 97 657784 8.00 8.00
$ 7 2-Fluorophenol 112 2.850 2.849 0.001 94 221207 5.00 5.04
$ 8 Phenol-d5 99 3.651 3.651 0.000 96 300918 5.00 5.25
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 269624 5.00 5.21
$ 10 2-Fluorobiphenyl 172 6.129 6.128 0.001 99 491480 5.00 5.13
$ 11 2,4,6-Tribromophenol 330 7.540 7.536 0.004 89 67367 5.00 5.03
$ 12 Terphenyl-d14 244 9.808 9.807 0.001 97 536736 5.00 5.27
15 1,4-Dioxane 88 1.537 1.540 -0.003 90 105967 5.00 5.08
17 N-Nitrosodimethylamine 74 1.750 1.749 0.001 86 160426 5.00 5.26
18 Pyridine 79 1.778 1.777 0.001 77 503890 10.0 10.5
31 Aniline 93 3.623 3.623 0.000 93 296368 5.00 5.25
29 Phenol 94 3.663 3.663 0.000 83 341307 5.00 5.36
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 88 271287 5.00 5.14
34 2-Chlorophenol 128 3.737 3.737 0.000 92 251065 5.00 5.31
35 n-Decane 43 3.790 3.789 0.001 91 409161 5.00 5.14
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 96 283843 5.00 5.28
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 276718 5.00 5.05
40 Benzyl alcohol 108 4.052 4.051 0.001 89 157592 5.00 4.98
43 1,2-Dichlorobenzene 146 4.052 4.051 0.001 94 268960 5.00 5.14
46 Indene 116 4.132 4.131 0.001 90 865688 10.0 10.5
47 2,2'-oxybis[1-chloropropane] 45 4.172 4.174 -0.002 92 589425 5.00 5.16
45 2-Methylphenol 108 4.184 4.184 0.000 94 220163 5.00 5.33
52 Acetophenone 105 4.277 4.276 0.001 92 340919 5.00 5.28
54 N-Nitrosodi-n-propylamine 70 4.289 4.288 0.001 93 193575 5.00 5.24
50 3 & 4 Methylphenol 108 4.332 4.332 0.000 0 233765 5.00 5.35
Page 622 of 1261
Report Date: 16-Nov-2023 10:01:03 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523006.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.332 0.000 87 233765 5.00 5.35
51 4-Methylphenol 108 4.332 4.332 0.000 93 233765 5.00 5.35
56 Hexachloroethane 117 4.357 4.356 0.001 96 121913 5.00 5.24
58 Nitrobenzene 77 4.425 4.424 0.001 96 288437 5.00 5.34
60 Isophorone 82 4.656 4.655 0.001 96 489190 5.00 5.30
61 2-Nitrophenol 139 4.720 4.720 0.000 89 124631 5.00 5.00
62 2,4-Dimethylphenol 107 4.810 4.809 0.001 94 167826 5.00 5.29
66 Bis(2-chloroethoxy)methane 63 4.877 4.877 0.000 91 287572 5.00 5.18
69 Benzoic acid 105 4.955 4.969 -0.014 92 263900 10.0 9.36
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 96 203863 5.00 5.30
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 94 219534 5.00 5.00
75 Naphthalene 128 5.093 5.090 0.003 97 717984 5.00 5.14
77 4-Chloroaniline 127 5.167 5.164 0.003 94 285039 5.00 5.23
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 91 202969 5.00 5.25
80 Hexachlorobutadiene 225 5.229 5.225 0.004 97 118809 5.00 5.08
85 4-Chloro-3-methylphenol 107 5.682 5.678 0.004 94 202258 5.00 5.36
88 2-Methylnaphthalene 141 5.759 5.758 0.001 92 393087 5.00 5.16
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 430606 5.00 5.17
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 94 35015 5.00 5.06
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 98 212892 5.00 5.02
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 242631 5.00 5.23
93 2,4,6-Trichlorophenol 196 6.055 6.054 0.001 93 137731 5.00 5.36
95 2,4,5-Trichlorophenol 196 6.107 6.103 0.004 91 138937 5.00 4.88
97 1,1'-Biphenyl 154 6.221 6.217 0.004 96 568002 5.00 5.13
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 454627 5.00 5.16
101 2-Nitroaniline 65 6.344 6.344 0.000 80 163882 5.00 5.01
104 Dimethyl phthalate 163 6.545 6.544 0.001 98 492987 5.00 5.29
105 1,3-Dinitrobenzene 168 6.554 6.553 0.001 84 73604 5.00 4.91
106 2,6-Dinitrotoluene 165 6.588 6.587 0.001 86 113994 5.00 5.21
107 Acenaphthylene 152 6.622 6.621 0.001 99 681761 5.00 5.37
108 3-Nitroaniline 138 6.748 6.748 0.000 84 132385 5.00 5.16
109 Acenaphthene 153 6.794 6.794 0.000 96 451108 5.00 5.16
111 2,4-Dinitrophenol 184 6.856 6.852 0.004 77 65442 10.0 9.85
114 Dibenzofuran 168 6.964 6.966 -0.002 96 632346 5.00 5.21
116 2,4-Dinitrotoluene 165 6.976 6.976 0.000 89 148721 5.00 5.11
113 4-Nitrophenol 109 7.001 6.997 0.004 84 116602 10.0 9.66
120 2,3,4,6-Tetrachlorophenol 232 7.105 7.105 0.000 77 99705 5.00 4.97
124 Diethyl phthalate 149 7.241 7.244 -0.003 97 509565 5.00 5.34
122 Hexadecane 57 7.284 7.284 0.000 87 511194 5.00 5.36
127 Fluorene 166 7.300 7.299 0.001 94 505410 5.00 5.24
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 95 231257 5.00 5.13
130 4-Nitroaniline 138 7.343 7.345 -0.002 81 135804 5.00 5.27
131 4,6-Dinitro-2-methylphenol 198 7.370 7.370 0.000 73 146339 10.0 9.45
132 Diphenylamine 169 7.441 7.441 0.000 92 353433 4.25 4.46
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 65 351230 5.00 5.09
135 Azobenzene 77 7.472 7.472 0.000 97 617581 5.00 5.45
136 1,2-Diphenylhydrazine 77 7.472 7.472 0.000 41 617581 5.05 5.51
145 4-Bromophenyl phenyl ether 248 7.796 7.795 0.001 74 132421 5.00 5.05
148 Hexachlorobenzene 284 7.830 7.829 0.001 93 154269 5.00 4.92
153 Pentachlorophenol 266 8.048 8.048 0.000 86 122823 10.0 9.67
154 n-Octadecane 57 8.196 8.196 0.000 89 505341 5.00 4.87
157 Phenanthrene 178 8.230 8.233 -0.003 99 717333 5.00 5.04
Page 623 of 1261
Report Date: 16-Nov-2023 10:01:03 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523006.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.282 0.001 99 708461 5.00 5.23
161 Carbazole 167 8.461 8.461 0.000 96 691600 5.00 5.34
163 Alachlor 188 8.625 8.627 -0.002 88 84184 5.00 5.12
164 Di-n-butyl phthalate 149 8.859 8.858 0.001 99 815575 5.00 5.03
170 Fluoranthene 202 9.398 9.398 0.000 99 700563 5.00 5.19
172 Pyrene 202 9.614 9.613 0.001 96 747634 5.00 5.29
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 98 296648 5.00 4.72
184 Benzo[a]anthracene 228 10.933 10.932 0.001 100 584001 5.00 5.21
185 Chrysene 228 10.976 10.975 0.001 97 649263 5.00 5.17
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.120 0.001 95 388741 5.00 4.74
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 98 516441 5.00 4.23
191 Benzo[b]fluoranthene 252 12.510 12.510 0.000 98 486362 5.00 4.92
193 Benzo[k]fluoranthene 252 12.553 12.556 -0.003 99 579943 5.00 5.01
194 Benzo[a]pyrene 252 13.031 13.037 -0.006 79 475010 5.00 4.76
198 Indeno[1,2,3-cd]pyrene 276 15.016 15.015 0.001 96 340719 5.00 4.79
199 Dibenz(a,h)anthracene 278 15.086 15.092 -0.006 95 366940 5.00 4.60
200 Benzo[g,h,i]perylene 276 15.462 15.465 -0.003 96 429486 5.00 4.88
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 10.7
S 212 Methyl Phenols,Total 108 0 10.7
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-RVHSL-WS_00003 Amount Added: 125.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 624 of 1261
Report Date: 16-Nov-2023 10:01:04 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523006.D
Injection Date:15-Nov-2023 08:40:46 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD05 HSL Worklist Smp#:7
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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-111523006[MS Quad Chro]:Total
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Page 625 of 1261
Report Date: 16-Nov-2023 10:01:06 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523005.D
Lims ID:STD12 HSL
Client ID:
Sample Type:IC Calib Level:6
Inject. Date:15-Nov-2023 08:18:35 ALS Bottle#:0 Worklist Smp#:8
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD12
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:01:06 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 08:41:24
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.907 3.903 0.004 95 279825 8.00 8.00
* 2 Naphthalene-d8 136 5.075 5.071 0.004 99 1067876 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 94 580679 8.00 8.00
* 4 Phenanthrene-d10 188 8.208 8.208 0.000 97 1042988 8.00 8.00
* 5 Chrysene-d12 240 10.942 10.944 -0.002 98 733997 8.00 8.00
* 6 Perylene-d12 264 13.130 13.132 -0.002 97 674460 8.00 8.00
$ 7 2-Fluorophenol 112 2.847 2.849 -0.002 94 573184 12.0 11.8
$ 8 Phenol-d5 99 3.651 3.651 0.000 97 771986 12.0 12.5
$ 9 Nitrobenzene-d5 82 4.409 4.406 0.003 96 689042 12.0 12.3
$ 10 2-Fluorobiphenyl 172 6.132 6.128 0.004 99 1230245 12.0 11.9
$ 11 2,4,6-Tribromophenol 330 7.540 7.536 0.004 91 180140 12.0 12.0
$ 12 Terphenyl-d14 244 9.805 9.807 -0.002 97 1312447 12.0 12.2
15 1,4-Dioxane 88 1.537 1.540 -0.003 89 260152 12.0 11.6
17 N-Nitrosodimethylamine 74 1.750 1.749 0.001 85 415831 12.0 12.6
18 Pyridine 79 1.774 1.777 -0.003 78 1258142 24.0 24.4
31 Aniline 93 3.623 3.623 0.000 93 753774 12.0 12.4
29 Phenol 94 3.660 3.663 -0.003 92 854606 12.0 12.4
33 Bis(2-chloroethyl)ether 93 3.691 3.688 0.003 89 670092 12.0 11.8
34 2-Chlorophenol 128 3.737 3.737 0.000 92 631298 12.0 12.4
35 n-Decane 43 3.793 3.789 0.004 91 982403 12.0 11.4
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 96 693382 12.0 12.0
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 697624 12.0 11.8
40 Benzyl alcohol 108 4.055 4.051 0.004 91 416553 12.0 11.9
43 1,2-Dichlorobenzene 146 4.052 4.051 0.001 96 666592 12.0 11.8
46 Indene 116 4.135 4.131 0.004 90 2130140 24.0 23.9
47 2,2'-oxybis[1-chloropropane] 45 4.175 4.174 0.001 92 1423774 12.0 11.5
45 2-Methylphenol 108 4.184 4.184 0.000 95 555294 12.0 12.5
52 Acetophenone 105 4.276 4.276 0.000 91 860043 12.0 12.3
54 N-Nitrosodi-n-propylamine 70 4.292 4.288 0.004 91 497348 12.0 12.5
50 3 & 4 Methylphenol 108 4.332 4.332 0.000 0 602811 12.0 12.8
Page 626 of 1261
Report Date: 16-Nov-2023 10:01:06 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523005.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.332 0.000 87 602811 12.0 12.8
51 4-Methylphenol 108 4.332 4.332 0.000 93 602811 12.0 12.8
56 Hexachloroethane 117 4.357 4.356 0.001 97 304885 12.0 12.1
58 Nitrobenzene 77 4.427 4.424 0.003 95 710255 12.0 12.2
60 Isophorone 82 4.659 4.655 0.004 96 1256897 12.0 12.6
61 2-Nitrophenol 139 4.723 4.720 0.003 89 336620 12.0 12.2
62 2,4-Dimethylphenol 107 4.810 4.809 0.001 95 430556 12.0 12.6
66 Bis(2-chloroethoxy)methane 63 4.880 4.877 0.003 92 717299 12.0 12.0
69 Benzoic acid 105 4.982 4.969 0.013 90 800283 24.0 23.9 M
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 96 519635 12.0 12.5
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 556755 12.0 11.8
75 Naphthalene 128 5.093 5.090 0.003 97 1762396 12.0 11.7
77 4-Chloroaniline 127 5.167 5.164 0.003 94 720309 12.0 12.2
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 93 516176 12.0 12.4
80 Hexachlorobutadiene 225 5.229 5.225 0.004 97 302324 12.0 12.0
85 4-Chloro-3-methylphenol 107 5.679 5.678 0.001 94 522915 12.0 12.8
88 2-Methylnaphthalene 141 5.762 5.758 0.004 92 994271 12.0 12.1
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 1080930 12.0 12.0
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 97 136109 12.0 11.6
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 99 551161 12.0 12.0
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 620726 12.0 12.4
93 2,4,6-Trichlorophenol 196 6.055 6.054 0.000 95 357798 12.0 12.9
95 2,4,5-Trichlorophenol 196 6.104 6.103 0.001 92 374350 12.0 11.9
97 1,1'-Biphenyl 154 6.221 6.217 0.004 97 1418694 12.0 11.8
98 2-Chloronaphthalene 162 6.227 6.224 0.003 97 1142817 12.0 12.0
101 2-Nitroaniline 65 6.344 6.344 0.000 79 435463 12.0 12.0
104 Dimethyl phthalate 163 6.548 6.544 0.004 97 1241670 12.0 12.3
105 1,3-Dinitrobenzene 168 6.557 6.553 0.004 84 203115 12.0 12.2
106 2,6-Dinitrotoluene 165 6.591 6.587 0.004 89 292516 12.0 12.0
107 Acenaphthylene 152 6.621 6.621 0.000 99 1701269 12.0 12.4
108 3-Nitroaniline 138 6.751 6.748 0.003 91 341813 12.0 12.0
109 Acenaphthene 153 6.794 6.794 0.000 96 1125033 12.0 11.9
111 2,4-Dinitrophenol 184 6.856 6.852 0.004 80 242255 24.0 24.0
114 Dibenzofuran 168 6.967 6.966 0.001 96 1581303 12.0 12.0
116 2,4-Dinitrotoluene 165 6.979 6.976 0.003 91 398696 12.0 12.3
113 4-Nitrophenol 109 6.994 6.997 -0.003 84 322021 24.0 23.4
120 2,3,4,6-Tetrachlorophenol 232 7.108 7.105 0.003 77 267927 12.0 11.9
124 Diethyl phthalate 149 7.247 7.244 0.003 97 1272911 12.0 12.3
122 Hexadecane 57 7.284 7.284 0.000 87 1285820 12.0 12.5
127 Fluorene 166 7.299 7.299 0.000 93 1246801 12.0 11.9
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 95 584276 12.0 12.0
130 4-Nitroaniline 138 7.349 7.345 0.004 82 336126 12.0 11.8
131 4,6-Dinitro-2-methylphenol 198 7.373 7.370 0.003 73 426731 24.0 23.9
132 Diphenylamine 169 7.444 7.441 0.003 93 906293 10.2 10.6
133 N-Nitrosodiphenylamine 169 7.444 7.441 0.003 64 904429 12.0 12.4
135 Azobenzene 77 7.475 7.472 0.003 97 1517008 12.0 12.4
136 1,2-Diphenylhydrazine 77 7.475 7.472 0.003 41 1517008 12.1 12.5
145 4-Bromophenyl phenyl ether 248 7.796 7.795 0.001 72 338868 12.0 12.3
148 Hexachlorobenzene 284 7.833 7.829 0.004 93 386532 12.0 11.7
153 Pentachlorophenol 266 8.048 8.048 0.000 91 377152 24.0 23.1
154 n-Octadecane 57 8.196 8.196 0.000 89 1310362 12.0 11.7
157 Phenanthrene 178 8.233 8.233 0.000 99 1763403 12.0 11.8
Page 627 of 1261
Report Date: 16-Nov-2023 10:01:06 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523005.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.282 8.282 0.000 99 1761150 12.0 12.3
161 Carbazole 167 8.461 8.461 0.000 96 1678231 12.0 12.3
163 Alachlor 188 8.624 8.627 -0.003 89 218583 12.0 12.6
164 Di-n-butyl phthalate 149 8.859 8.858 0.001 99 2114908 12.0 12.1
170 Fluoranthene 202 9.398 9.398 0.000 99 1748852 12.0 12.3
172 Pyrene 202 9.614 9.613 0.001 96 1850943 12.0 12.4
180 Butyl benzyl phthalate 149 10.350 10.353 -0.003 98 820730 12.0 11.9
184 Benzo[a]anthracene 228 10.932 10.932 0.000 100 1494796 12.0 12.7
185 Chrysene 228 10.976 10.975 0.001 97 1581733 12.0 12.0
186 Bis(2-ethylhexyl) phthalate 149 11.117 11.120 -0.003 95 1095096 12.0 11.8
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 98 1596360 12.0 11.7
191 Benzo[b]fluoranthene 252 12.510 12.510 0.000 98 1229979 12.0 11.9
193 Benzo[k]fluoranthene 252 12.556 12.556 0.000 99 1449509 12.0 12.0
194 Benzo[a]pyrene 252 13.037 13.037 0.000 79 1240314 12.0 11.8
198 Indeno[1,2,3-cd]pyrene 276 15.012 15.015 -0.003 97 908696 12.0 11.8
199 Dibenz(a,h)anthracene 278 15.089 15.092 -0.003 95 1019382 12.0 12.1
200 Benzo[g,h,i]perylene 276 15.462 15.465 -0.003 96 1103876 12.0 12.0
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 25.2
S 212 Methyl Phenols,Total 108 0 25.2
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
MS-RVHSL-WS_00003 Amount Added: 300.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 628 of 1261
Report Date: 16-Nov-2023 10:01:06 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523005.D
Injection Date:15-Nov-2023 08:18:35 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD12 HSL Worklist Smp#:8
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
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-111523005[MS Quad Chro]:Total
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Page 629 of 1261
Report Date: 16-Nov-2023 10:01:06 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523005.D
Injection Date:15-Nov-2023 08:18:35 Instrument ID:SMS_1
Lims ID:STD12 HSL
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:8
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column:Rxi-5Sil MS ( 0.25 mm)Detector MS SCAN
69 Benzoic acid, CAS: 65-85-0
Signal: 1
Processing Integration Results
RT: 4.98
Area: 616101
Amount: 19.206732
Amount Units: ug/ml
4.6 4.8 5.0 5.2 5.4
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-111523005[MS Quad Chro]:m/z 105

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Manual Integration Results
RT: 4.98
Area: 800283
Amount: 23.909329
Amount Units: ug/ml
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-111523005[MS Quad Chro]:m/z 105

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Reviewer: FP7E, 15-Nov-2023 08:40:50 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
Page 630 of 1261
Report Date: 16-Nov-2023 10:01:11 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523004.D
Lims ID:STD16 HSL
Client ID:
Sample Type:IC Calib Level:7
Inject. Date:15-Nov-2023 07:56:24 ALS Bottle#:0 Worklist Smp#:9
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD16
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:01:10 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 08:27:33
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.907 3.903 0.004 95 283165 8.00 8.00
* 2 Naphthalene-d8 136 5.075 5.071 0.004 99 1078331 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 95 581319 8.00 8.00
* 4 Phenanthrene-d10 188 8.212 8.208 0.004 97 1033540 8.00 8.00
* 5 Chrysene-d12 240 10.945 10.944 0.001 98 737084 8.00 8.00
* 6 Perylene-d12 264 13.139 13.132 0.007 97 648480 8.00 8.00
$ 7 2-Fluorophenol 112 2.847 2.849 -0.002 94 794092 16.0 16.1
$ 8 Phenol-d5 99 3.651 3.651 0.000 97 1060875 16.0 17.0
$ 9 Nitrobenzene-d5 82 4.409 4.406 0.003 96 949279 16.0 16.8
$ 10 2-Fluorobiphenyl 172 6.132 6.128 0.004 99 1659306 16.0 16.0
$ 11 2,4,6-Tribromophenol 330 7.543 7.536 0.007 89 247929 16.0 16.4
$ 12 Terphenyl-d14 244 9.808 9.807 0.001 97 1748352 16.0 16.2
15 1,4-Dioxane 88 1.540 1.540 0.000 89 357127 16.0 15.7
17 N-Nitrosodimethylamine 74 1.753 1.749 0.004 85 572557 16.0 17.2
18 Pyridine 79 1.777 1.777 0.000 78 1709398 32.0 32.7
31 Aniline 93 3.623 3.623 0.000 93 1041462 16.0 16.9
29 Phenol 94 3.660 3.663 -0.003 92 1176471 16.0 16.9
33 Bis(2-chloroethyl)ether 93 3.691 3.688 0.003 89 912493 16.0 15.8
34 2-Chlorophenol 128 3.737 3.737 0.000 92 865054 16.0 16.7
35 n-Decane 43 3.793 3.789 0.004 92 1353541 16.0 15.6
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 95 929292 16.0 15.8
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 90 937705 16.0 15.7
40 Benzyl alcohol 108 4.055 4.051 0.004 90 564578 16.0 15.9
43 1,2-Dichlorobenzene 146 4.052 4.051 0.001 97 915309 16.0 16.0
46 Indene 116 4.135 4.131 0.004 90 2908510 32.0 32.2
47 2,2'-oxybis[1-chloropropane] 45 4.175 4.174 0.001 92 1936236 16.0 15.5
45 2-Methylphenol 108 4.184 4.184 0.000 95 766494 16.0 17.0
52 Acetophenone 105 4.280 4.276 0.004 92 1174704 16.0 16.7
54 N-Nitrosodi-n-propylamine 70 4.295 4.288 0.007 91 674606 16.0 16.7
50 3 & 4 Methylphenol 108 4.332 4.332 0.000 0 815837 16.0 17.1
Page 631 of 1261
Report Date: 16-Nov-2023 10:01:11 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523004.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.332 0.000 87 815837 16.0 17.1
51 4-Methylphenol 108 4.332 4.332 0.000 95 815837 16.0 17.1
56 Hexachloroethane 117 4.357 4.356 0.001 97 414905 16.0 16.3
58 Nitrobenzene 77 4.428 4.424 0.004 95 968095 16.0 16.5
60 Isophorone 82 4.662 4.655 0.007 96 1694968 16.0 16.9
61 2-Nitrophenol 139 4.723 4.720 0.003 89 453440 16.0 16.3
62 2,4-Dimethylphenol 107 4.810 4.809 0.001 95 586639 16.0 16.9
66 Bis(2-chloroethoxy)methane 63 4.881 4.877 0.004 92 975155 16.0 16.1
69 Benzoic acid 105 4.995 4.969 0.026 92 1151207 32.0 33.5
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 97 699528 16.0 16.7
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 759649 16.0 15.9
75 Naphthalene 128 5.093 5.090 0.003 97 2347978 16.0 15.4
77 4-Chloroaniline 127 5.167 5.164 0.003 94 984393 16.0 16.6
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 94 704482 16.0 16.7
80 Hexachlorobutadiene 225 5.229 5.225 0.004 98 412860 16.0 16.2
85 4-Chloro-3-methylphenol 107 5.679 5.678 0.001 94 715526 16.0 17.4
88 2-Methylnaphthalene 141 5.762 5.758 0.004 92 1337912 16.0 16.1
89 1-Methylnaphthalene 142 5.854 5.851 0.003 93 1472272 16.0 16.2
92 Hexachlorocyclopentadiene 237 5.922 5.919 0.003 98 199300 16.0 15.8
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 98 754795 16.0 16.3
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 822665 16.0 16.4
93 2,4,6-Trichlorophenol 196 6.055 6.054 0.001 93 486188 16.0 17.5
95 2,4,5-Trichlorophenol 196 6.104 6.103 0.001 94 518624 16.0 16.4
97 1,1'-Biphenyl 154 6.221 6.217 0.004 97 1946452 16.0 16.2
98 2-Chloronaphthalene 162 6.227 6.224 0.003 97 1556707 16.0 16.3
101 2-Nitroaniline 65 6.347 6.344 0.003 79 588314 16.0 16.1
104 Dimethyl phthalate 163 6.548 6.544 0.004 97 1665300 16.0 16.5
105 1,3-Dinitrobenzene 168 6.557 6.553 0.004 84 283154 16.0 16.9
106 2,6-Dinitrotoluene 165 6.594 6.587 0.007 88 395116 16.0 16.2
107 Acenaphthylene 152 6.625 6.621 0.004 99 2272428 16.0 16.5
108 3-Nitroaniline 138 6.754 6.748 0.006 87 462101 16.0 16.2
109 Acenaphthene 153 6.797 6.794 0.003 96 1530293 16.0 16.2
111 2,4-Dinitrophenol 184 6.856 6.852 0.004 79 368389 32.0 32.1
114 Dibenzofuran 168 6.967 6.966 0.001 96 2080402 16.0 15.8
116 2,4-Dinitrotoluene 165 6.979 6.976 0.003 92 538277 16.0 16.5
113 4-Nitrophenol 109 6.994 6.997 -0.003 83 451217 32.0 32.3
120 2,3,4,6-Tetrachlorophenol 232 7.108 7.105 0.003 77 379708 16.0 16.7
124 Diethyl phthalate 149 7.250 7.244 0.006 97 1718458 16.0 16.6
122 Hexadecane 57 7.287 7.284 0.003 87 1736010 16.0 16.8
127 Fluorene 166 7.303 7.299 0.004 94 1700285 16.0 16.3
126 4-Chlorophenyl phenyl ether 204 7.324 7.321 0.003 95 786763 16.0 16.1
130 4-Nitroaniline 138 7.355 7.345 0.010 81 459721 16.0 16.1
131 4,6-Dinitro-2-methylphenol 198 7.377 7.370 0.007 74 588460 32.0 32.8
132 Diphenylamine 169 7.444 7.441 0.003 93 1224070 13.6 14.3
133 N-Nitrosodiphenylamine 169 7.444 7.441 0.003 63 1224070 16.0 17.0
135 Azobenzene 77 7.478 7.472 0.006 97 2028147 16.0 16.5
136 1,2-Diphenylhydrazine 77 7.478 7.472 0.006 41 2028147 16.2 16.7
145 4-Bromophenyl phenyl ether 248 7.796 7.795 0.001 73 451832 16.0 16.5
148 Hexachlorobenzene 284 7.833 7.829 0.004 93 521105 16.0 15.9
153 Pentachlorophenol 266 8.048 8.048 0.000 91 527518 32.0 31.6
154 n-Octadecane 57 8.196 8.196 0.000 89 1784371 16.0 16.0
157 Phenanthrene 178 8.233 8.233 0.000 99 2358217 16.0 15.9
Page 632 of 1261
Report Date: 16-Nov-2023 10:01:11 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523004.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.282 0.000 99 2360227 16.0 16.7
161 Carbazole 167 8.464 8.461 0.003 96 2221331 16.0 16.4
163 Alachlor 188 8.628 8.627 0.001 90 297183 16.0 17.3
164 Di-n-butyl phthalate 149 8.859 8.858 0.001 99 2787044 16.0 16.0
170 Fluoranthene 202 9.398 9.398 0.000 99 2356043 16.0 16.7
172 Pyrene 202 9.614 9.613 0.001 95 2451259 16.0 16.4
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 98 1103297 16.0 15.8
184 Benzo[a]anthracene 228 10.936 10.932 0.004 100 1972157 16.0 16.6
185 Chrysene 228 10.979 10.975 0.004 97 2044368 16.0 15.4
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.120 0.001 95 1480342 16.0 15.9
189 Di-n-octyl phthalate 149 12.122 12.119 0.003 98 2169070 16.0 15.7
191 Benzo[b]fluoranthene 252 12.513 12.510 0.003 98 1618717 16.0 16.2
193 Benzo[k]fluoranthene 252 12.560 12.556 0.004 98 1896457 16.0 16.2
194 Benzo[a]pyrene 252 13.040 13.037 0.003 80 1706176 16.0 16.9
198 Indeno[1,2,3-cd]pyrene 276 15.022 15.015 0.007 97 1246539 16.0 16.1
199 Dibenz(a,h)anthracene 278 15.096 15.092 0.004 96 1352560 16.0 16.7
200 Benzo[g,h,i]perylene 276 15.475 15.465 0.010 95 1467055 16.0 16.5
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 34.1
S 212 Methyl Phenols,Total 108 0 34.1
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-RVHSL-WS_00003 Amount Added: 400.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 633 of 1261
Report Date: 16-Nov-2023 10:01:11 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523004.D
Injection Date:15-Nov-2023 07:56:24 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD16 HSL Worklist Smp#:9
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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-111523004[MS Quad Chro]:Total
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Page 634 of 1261
Report Date: 16-Nov-2023 10:01:14 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523003.D
Lims ID:STD20 HSL
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:15-Nov-2023 07:34:12 ALS Bottle#:0 Worklist Smp#:10
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:STD20
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:16-Nov-2023 10:01:13 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: FP7E Date:15-Nov-2023 08:26:58
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.907 3.903 0.004 94 286698 8.00 8.00
* 2 Naphthalene-d8 136 5.075 5.071 0.004 99 1086905 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.763 0.000 94 581763 8.00 8.00
* 4 Phenanthrene-d10 188 8.212 8.208 0.004 97 1006263 8.00 8.00
* 5 Chrysene-d12 240 10.948 10.944 0.004 98 717927 8.00 8.00
* 6 Perylene-d12 264 13.136 13.132 0.004 97 636717 8.00 8.00
$ 7 2-Fluorophenol 112 2.847 2.849 -0.002 94 1049530 20.0 21.0
$ 8 Phenol-d5 99 3.651 3.651 0.000 96 1368802 20.0 21.6
$ 9 Nitrobenzene-d5 82 4.412 4.406 0.006 96 1216114 20.0 21.4
$ 10 2-Fluorobiphenyl 172 6.132 6.128 0.004 99 2109999 20.0 20.3
$ 11 2,4,6-Tribromophenol 330 7.543 7.536 0.007 89 307928 20.0 20.3
$ 12 Terphenyl-d14 244 9.811 9.807 0.004 97 2203564 20.0 21.0
15 1,4-Dioxane 88 1.543 1.540 0.003 88 468765 20.0 20.3
17 N-Nitrosodimethylamine 74 1.756 1.749 0.007 85 752941 20.0 22.3
18 Pyridine 79 1.777 1.777 0.000 78 2275809 40.0 43.0
31 Aniline 93 3.623 3.623 0.000 93 1355485 20.0 21.7
29 Phenol 94 3.660 3.663 -0.003 93 1540189 20.0 21.9
33 Bis(2-chloroethyl)ether 93 3.691 3.688 0.003 88 1187697 20.0 20.3
34 2-Chlorophenol 128 3.737 3.737 0.000 92 1119683 20.0 21.4
35 n-Decane 43 3.793 3.789 0.004 92 1808615 20.0 20.5
36 1,3-Dichlorobenzene 146 3.854 3.851 0.003 95 1210172 20.0 20.4
37 1,4-Dichlorobenzene 146 3.922 3.919 0.003 91 1237363 20.0 20.4
40 Benzyl alcohol 108 4.058 4.051 0.007 89 748936 20.0 20.8
43 1,2-Dichlorobenzene 146 4.051 4.051 0.000 97 1178658 20.0 20.4
46 Indene 116 4.135 4.131 0.004 90 3710838 40.0 40.6
47 2,2'-oxybis[1-chloropropane] 45 4.175 4.174 0.001 92 2591914 20.0 20.5
45 2-Methylphenol 108 4.184 4.184 0.000 95 990421 20.0 21.7
52 Acetophenone 105 4.280 4.276 0.004 91 1496414 20.0 21.0
54 N-Nitrosodi-n-propylamine 70 4.295 4.288 0.007 94 875681 20.0 21.4
50 3 & 4 Methylphenol 108 4.332 4.332 0.000 0 1064138 20.0 22.0
Page 635 of 1261
Report Date: 16-Nov-2023 10:01:14 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523003.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.332 0.000 87 1064138 20.0 22.0
51 4-Methylphenol 108 4.332 4.332 0.000 92 1064138 20.0 22.0
56 Hexachloroethane 117 4.357 4.356 0.001 96 541965 20.0 21.1
58 Nitrobenzene 77 4.427 4.424 0.003 95 1248660 20.0 21.1
60 Isophorone 82 4.662 4.655 0.007 95 2170570 20.0 21.4
61 2-Nitrophenol 139 4.723 4.720 0.003 88 584661 20.0 20.8
62 2,4-Dimethylphenol 107 4.810 4.809 0.001 95 768995 20.0 22.0
66 Bis(2-chloroethoxy)methane 63 4.883 4.877 0.006 92 1277443 20.0 20.9
69 Benzoic acid 105 5.007 4.969 0.038 91 1487475 40.0 42.6 M
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 96 903636 20.0 21.4
72 1,2,4-Trichlorobenzene 180 5.028 5.025 0.003 93 973288 20.0 20.2
75 Naphthalene 128 5.093 5.090 0.003 97 3016220 20.0 19.6
77 4-Chloroaniline 127 5.170 5.164 0.006 94 1270802 20.0 21.2
78 2,6-Dichlorophenol 162 5.176 5.173 0.003 93 911300 20.0 21.4
80 Hexachlorobutadiene 225 5.229 5.225 0.004 97 532951 20.0 20.7
85 4-Chloro-3-methylphenol 107 5.679 5.678 0.001 94 919914 20.0 22.2
88 2-Methylnaphthalene 141 5.762 5.758 0.004 92 1752076 20.0 20.9
89 1-Methylnaphthalene 142 5.854 5.851 0.003 93 1890190 20.0 20.7
92 Hexachlorocyclopentadiene 237 5.922 5.919 0.003 97 276946 20.0 20.9
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.922 0.000 99 958170 20.0 20.6
94 2,3-Dichlorobenzenamine 161 6.042 6.039 0.003 95 1065504 20.0 21.2
93 2,4,6-Trichlorophenol 196 6.054 6.054 0.000 95 628378 20.0 22.5
95 2,4,5-Trichlorophenol 196 6.104 6.103 0.001 92 659330 20.0 20.8
97 1,1'-Biphenyl 154 6.224 6.217 0.007 98 2476171 20.0 20.6
98 2-Chloronaphthalene 162 6.227 6.224 0.003 97 1985151 20.0 20.8
101 2-Nitroaniline 65 6.347 6.344 0.003 79 761274 20.0 20.8
104 Dimethyl phthalate 163 6.551 6.544 0.007 97 2109496 20.0 20.9
105 1,3-Dinitrobenzene 168 6.560 6.553 0.007 84 363962 20.0 21.7
106 2,6-Dinitrotoluene 165 6.594 6.587 0.007 88 501554 20.0 20.4
107 Acenaphthylene 152 6.625 6.621 0.004 99 2910831 20.0 21.2
108 3-Nitroaniline 138 6.754 6.748 0.006 85 580075 20.0 20.3
109 Acenaphthene 153 6.797 6.794 0.003 97 1933284 20.0 20.4
111 2,4-Dinitrophenol 184 6.856 6.852 0.004 76 506902 40.0 39.9
114 Dibenzofuran 168 6.970 6.966 0.004 97 2649240 20.0 20.1
116 2,4-Dinitrotoluene 165 6.982 6.976 0.006 92 677661 20.0 20.7
113 4-Nitrophenol 109 6.994 6.997 -0.003 82 576307 40.0 41.1
120 2,3,4,6-Tetrachlorophenol 232 7.108 7.105 0.003 77 486254 20.0 21.3
124 Diethyl phthalate 149 7.250 7.244 0.006 97 2124858 20.0 20.5
122 Hexadecane 57 7.287 7.284 0.003 87 2223709 20.0 21.5
127 Fluorene 166 7.302 7.299 0.003 94 2125211 20.0 20.3
126 4-Chlorophenyl phenyl ether 204 7.324 7.321 0.003 95 996317 20.0 20.4
130 4-Nitroaniline 138 7.358 7.345 0.013 82 566105 20.0 19.7
131 4,6-Dinitro-2-methylphenol 198 7.380 7.370 0.010 75 748688 40.0 42.5
132 Diphenylamine 169 7.447 7.441 0.006 92 1500913 17.0 17.5
133 N-Nitrosodiphenylamine 169 7.447 7.441 0.006 64 1500913 20.0 21.4
135 Azobenzene 77 7.478 7.472 0.006 97 2549628 20.0 20.7
136 1,2-Diphenylhydrazine 77 7.478 7.472 0.006 41 2549628 20.2 21.0
145 4-Bromophenyl phenyl ether 248 7.799 7.795 0.004 73 572937 20.0 21.5
148 Hexachlorobenzene 284 7.832 7.829 0.003 94 670825 20.0 21.0
153 Pentachlorophenol 266 8.051 8.048 0.003 91 707444 40.0 42.5
154 n-Octadecane 57 8.199 8.196 0.003 89 2265594 20.0 20.8
157 Phenanthrene 178 8.236 8.233 0.003 99 2932098 20.0 20.3
Page 636 of 1261
Report Date: 16-Nov-2023 10:01:14 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523003.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.285 8.282 0.003 99 2906789 20.0 21.1
161 Carbazole 167 8.464 8.461 0.003 96 2737747 20.0 20.8
163 Alachlor 188 8.628 8.627 0.001 89 371173 20.0 22.2
164 Di-n-butyl phthalate 149 8.862 8.858 0.004 99 3476255 20.0 20.5
170 Fluoranthene 202 9.401 9.398 0.003 99 3019078 20.0 22.0
172 Pyrene 202 9.617 9.613 0.004 95 3072344 20.0 21.1
180 Butyl benzyl phthalate 149 10.356 10.353 0.003 98 1419865 20.0 20.8
184 Benzo[a]anthracene 228 10.939 10.932 0.007 100 2523324 20.0 21.8
185 Chrysene 228 10.982 10.975 0.007 99 2583169 20.0 20.0
186 Bis(2-ethylhexyl) phthalate 149 11.120 11.120 0.000 95 1915569 20.0 21.0
189 Di-n-octyl phthalate 149 12.125 12.119 0.006 99 2875452 20.0 21.2
191 Benzo[b]fluoranthene 252 12.516 12.510 0.006 98 2089095 20.0 21.3
193 Benzo[k]fluoranthene 252 12.563 12.556 0.007 98 2400894 20.0 20.9
194 Benzo[a]pyrene 252 13.043 13.037 0.006 80 2157279 20.0 21.7
198 Indeno[1,2,3-cd]pyrene 276 15.028 15.015 0.013 98 1614110 20.0 21.4
199 Dibenz(a,h)anthracene 278 15.099 15.092 0.007 95 1758698 20.0 22.0
200 Benzo[g,h,i]perylene 276 15.481 15.465 0.016 94 1870222 20.0 21.3
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 43.7
S 212 Methyl Phenols,Total 108 0 43.7
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
MS-RVHSL-WS_00003 Amount Added: 500.00 Units: uL
MS-IS-RVE_00005 Amount Added: 30.00 Units: uL Run Reagent
Page 637 of 1261
Report Date: 16-Nov-2023 10:01:14 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523003.D
Injection Date:15-Nov-2023 07:34:12 Instrument ID:SMS_1 Operator ID:MB
Lims ID:STD20 HSL Worklist Smp#:10
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
Min
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1
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4
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7
8
9
10
11
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-111523003[MS Quad Chro]:Total
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Page 638 of 1261
Report Date: 16-Nov-2023 10:01:14 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523003.D
Injection Date:15-Nov-2023 07:34:12 Instrument ID:SMS_1
Lims ID:STD20 HSL
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:10
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column:Rxi-5Sil MS ( 0.25 mm)Detector MS SCAN
69 Benzoic acid, CAS: 65-85-0
Signal: 1
Processing Integration Results
RT: 5.01
Area: 1179228
Amount: 38.982719
Amount Units: ug/ml
4.6 4.8 5.0 5.2 5.4
Min
0
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12
16
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-111523003[MS Quad Chro]:m/z 105

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Manual Integration Results
RT: 5.01
Area: 1487475
Amount: 42.579434
Amount Units: ug/ml
4.6 4.8 5.0 5.2 5.4
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RT
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Reviewer: FP7E, 15-Nov-2023 08:26:36 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
Page 639 of 1261
Calibration / N-Nitrosodimethylamine
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9409
Error Coefficients
Standard Error:442000
Relative Standard Error:14.0
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.979
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.277946 8.0 268628.0 0.694864 Y
2 STD01 280-633956/5 1.0 0.820043 8.0 249304.0 0.820043 Y
3 STD02 280-633956/6 2.0 1.687746 8.0 268538.0 0.843873 N
4 STD05 280-633956/7 5.0 4.949167 8.0 259318.0 0.989833 Y
5 ICIS 280-633956/3 8.0 8.234535 8.0 274108.0 1.029317 Y
6 STD12 280-633956/8 12.0 11.888316 8.0 279825.0 0.990693 Y
7 STD16 280-633956/9 16.0 16.175926 8.0 283165.0 1.010995 Y
8 STD20 280-633956/10 20.0 21.010011 8.0 286698.0 1.050501 Y
RelResp = [0.9409]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 640 of 1261
Calibration / Pyridine
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.476
Error Coefficients
Standard Error:1340000
Relative Standard Error:8.8
Correlation Coefficient:0.997
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.8 1.003469 8.0 268628.0 1.254337 Y
2 STD01 280-633956/5 2.0 2.672913 8.0 249304.0 1.336457 Y
3 STD02 280-633956/6 4.0 5.222888 8.0 268538.0 1.305722 N
4 STD05 280-633956/7 10.0 15.545084 8.0 259318.0 1.554508 Y
5 ICIS 280-633956/3 16.0 25.447955 8.0 274108.0 1.590497 Y
6 STD12 280-633956/8 24.0 35.969395 8.0 279825.0 1.498725 Y
7 STD16 280-633956/9 32.0 48.294048 8.0 283165.0 1.509189 Y
8 STD20 280-633956/10 40.0 63.504008 8.0 286698.0 1.5876 Y
RelResp = [1.476]x
Concentration
0 10 20 30 40
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 641 of 1261
Calibration / 2-Fluorophenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2817
Slope:1.409
Error Coefficients
Standard Error:672000
Relative Standard Error:6.2
Correlation Coefficient:0.997
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.307369 8.0 268628.0 0.768423 Y
2 STD01 280-633956/5 1.0 0.959856 8.0 249304.0 0.959856 Y
3 STD02 280-633956/6 2.0 2.167023 8.0 268538.0 1.083511 N
4 STD05 280-633956/7 5.0 6.82427 8.0 259318.0 1.364854 Y
5 ICIS 280-633956/3 8.0 11.247625 8.0 274108.0 1.405953 Y
6 STD12 280-633956/8 12.0 16.386928 8.0 279825.0 1.365577 Y
7 STD16 280-633956/9 16.0 22.43475 8.0 283165.0 1.402172 Y
8 STD20 280-633956/10 20.0 29.286008 8.0 286698.0 1.4643 Y
RelResp = [-0.2817] + [1.409]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 0.200
Page 642 of 1261
Calibration / Aniline
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.742
Error Coefficients
Standard Error:799000
Relative Standard Error:9.9
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.989
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.567804 8.0 268628.0 1.41951 Y
2 STD01 280-633956/5 1.0 1.587107 8.0 249304.0 1.587107 Y
3 STD02 280-633956/6 2.0 3.06954 8.0 268538.0 1.53477 N
4 STD05 280-633956/7 5.0 9.142998 8.0 259318.0 1.8286 Y
5 ICIS 280-633956/3 8.0 14.643775 8.0 274108.0 1.830472 Y
6 STD12 280-633956/8 12.0 21.549869 8.0 279825.0 1.795822 Y
7 STD16 280-633956/9 16.0 29.423467 8.0 283165.0 1.838967 Y
8 STD20 280-633956/10 20.0 37.823354 8.0 286698.0 1.891168 Y
RelResp = [1.742]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 643 of 1261
Calibration / Phenol-d5
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.767
Error Coefficients
Standard Error:813000
Relative Standard Error:11.5
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.986
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.553479 8.0 268628.0 1.383698 Y
2 STD01 280-633956/5 1.0 1.587139 8.0 249304.0 1.587139 Y
3 STD02 280-633956/6 2.0 3.140025 8.0 268538.0 1.570012 N
4 STD05 280-633956/7 5.0 9.283366 8.0 259318.0 1.856673 Y
5 ICIS 280-633956/3 8.0 15.362237 8.0 274108.0 1.92028 Y
6 STD12 280-633956/8 12.0 22.070537 8.0 279825.0 1.839211 Y
7 STD16 280-633956/9 16.0 29.971924 8.0 283165.0 1.873245 Y
8 STD20 280-633956/10 20.0 38.194951 8.0 286698.0 1.909748 Y
RelResp = [1.767]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 644 of 1261
Calibration / Phenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.963
Error Coefficients
Standard Error:908000
Relative Standard Error:12.3
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.983
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.609408 8.0 268628.0 1.52352 Y
2 STD01 280-633956/5 1.0 1.720406 8.0 249304.0 1.720406 Y
3 STD02 280-633956/6 2.0 3.472194 8.0 268538.0 1.736097 N
4 STD05 280-633956/7 5.0 10.529373 8.0 259318.0 2.105875 Y
5 ICIS 280-633956/3 8.0 17.016125 8.0 274108.0 2.127016 Y
6 STD12 280-633956/8 12.0 24.432585 8.0 279825.0 2.036049 Y
7 STD16 280-633956/9 16.0 33.237752 8.0 283165.0 2.077359 Y
8 STD20 280-633956/10 20.0 42.977321 8.0 286698.0 2.148866 Y
RelResp = [1.963]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 645 of 1261
Calibration / Bis(2-chloroethyl)ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.629
Error Coefficients
Standard Error:705000
Relative Standard Error:2.5
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.630493 8.0 268628.0 1.576232 Y
2 STD01 280-633956/5 1.0 1.608703 8.0 249304.0 1.608703 Y
3 STD02 280-633956/6 2.0 2.996075 8.0 268538.0 1.498038 N
4 STD05 280-633956/7 5.0 8.369245 8.0 259318.0 1.673849 Y
5 ICIS 280-633956/3 8.0 13.430443 8.0 274108.0 1.678805 Y
6 STD12 280-633956/8 12.0 19.157459 8.0 279825.0 1.596455 Y
7 STD16 280-633956/9 16.0 25.779824 8.0 283165.0 1.611239 Y
8 STD20 280-633956/10 20.0 33.14141 8.0 286698.0 1.657071 Y
RelResp = [1.629]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 646 of 1261
Calibration / 2-Chlorophenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.459
Error Coefficients
Standard Error:664000
Relative Standard Error:9.3
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.990
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.490492 8.0 268628.0 1.226231 Y
2 STD01 280-633956/5 1.0 1.302795 8.0 249304.0 1.302795 Y
3 STD02 280-633956/6 2.0 2.64907 8.0 268538.0 1.324535 N
4 STD05 280-633956/7 5.0 7.745394 8.0 259318.0 1.549079 Y
5 ICIS 280-633956/3 8.0 12.344857 8.0 274108.0 1.543107 Y
6 STD12 280-633956/8 12.0 18.048366 8.0 279825.0 1.50403 Y
7 STD16 280-633956/9 16.0 24.439574 8.0 283165.0 1.527473 Y
8 STD20 280-633956/10 20.0 31.243552 8.0 286698.0 1.562178 Y
RelResp = [1.459]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 647 of 1261
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.659
Error Coefficients
Standard Error:718000
Relative Standard Error:2.9
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.639695 8.0 268628.0 1.599238 Y
2 STD01 280-633956/5 1.0 1.639155 8.0 249304.0 1.639155 Y
3 STD02 280-633956/6 2.0 3.058398 8.0 268538.0 1.529199 N
4 STD05 280-633956/7 5.0 8.7566 8.0 259318.0 1.75132 Y
5 ICIS 280-633956/3 8.0 13.119705 8.0 274108.0 1.639963 Y
6 STD12 280-633956/8 12.0 19.823304 8.0 279825.0 1.651942 Y
7 STD16 280-633956/9 16.0 26.254431 8.0 283165.0 1.640902 Y
8 STD20 280-633956/10 20.0 33.768551 8.0 286698.0 1.688428 Y
RelResp = [1.659]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 648 of 1261
Calibration / 1,4-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.69
Error Coefficients
Standard Error:730000
Relative Standard Error:1.5
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.676534 8.0 268628.0 1.691335 Y
2 STD01 280-633956/5 1.0 1.68177 8.0 249304.0 1.68177 Y
3 STD02 280-633956/6 2.0 3.125546 8.0 268538.0 1.562773 N
4 STD05 280-633956/7 5.0 8.536793 8.0 259318.0 1.707359 Y
5 ICIS 280-633956/3 8.0 13.622747 8.0 274108.0 1.702843 Y
6 STD12 280-633956/8 12.0 19.94458 8.0 279825.0 1.662048 Y
7 STD16 280-633956/9 16.0 26.492116 8.0 283165.0 1.655757 Y
8 STD20 280-633956/10 20.0 34.527287 8.0 286698.0 1.726364 Y
RelResp = [1.69]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 649 of 1261
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.615
Error Coefficients
Standard Error:701000
Relative Standard Error:1.9
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.628229 8.0 268628.0 1.570573 Y
2 STD01 280-633956/5 1.0 1.600424 8.0 249304.0 1.600424 Y
3 STD02 280-633956/6 2.0 2.971319 8.0 268538.0 1.485659 N
4 STD05 280-633956/7 5.0 8.297457 8.0 259318.0 1.659491 Y
5 ICIS 280-633956/3 8.0 13.018226 8.0 274108.0 1.627278 Y
6 STD12 280-633956/8 12.0 19.057397 8.0 279825.0 1.588116 Y
7 STD16 280-633956/9 16.0 25.859382 8.0 283165.0 1.616211 Y
8 STD20 280-633956/10 20.0 32.889187 8.0 286698.0 1.644459 Y
RelResp = [1.615]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 650 of 1261
Calibration / Benzyl alcohol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1827
Slope:1.014
Error Coefficients
Standard Error:480000
Relative Standard Error:2.1
Correlation Coefficient:0.997
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.224995 8.0 268628.0 0.562488 Y
2 STD01 280-633956/5 1.0 0.81985 8.0 249304.0 0.81985 Y
3 STD02 280-633956/6 2.0 1.505962 8.0 268538.0 0.752981 N
4 STD05 280-633956/7 5.0 4.861737 8.0 259318.0 0.972347 Y
5 ICIS 280-633956/3 8.0 7.788813 8.0 274108.0 0.973602 Y
6 STD12 280-633956/8 12.0 11.908957 8.0 279825.0 0.992413 Y
7 STD16 280-633956/9 16.0 15.950502 8.0 283165.0 0.996906 Y
8 STD20 280-633956/10 20.0 20.898255 8.0 286698.0 1.044913 Y
RelResp = [-0.1827] + [1.014]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 0.180
Page 651 of 1261
Calibration / 2,2'-oxybis[1-chloropropane]
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.527
Error Coefficients
Standard Error:1530000
Relative Standard Error:7.5
Correlation Coefficient:0.994
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 1.287252 8.0 268628.0 3.218131 Y
2 STD01 280-633956/5 1.0 3.375734 8.0 249304.0 3.375734 Y
3 STD02 280-633956/6 2.0 6.34419 8.0 268538.0 3.172095 N
4 STD05 280-633956/7 5.0 18.183851 8.0 259318.0 3.63677 Y
5 ICIS 280-633956/3 8.0 32.235119 8.0 274108.0 4.02939 Y
6 STD12 280-633956/8 12.0 40.704698 8.0 279825.0 3.392058 Y
7 STD16 280-633956/9 16.0 54.702693 8.0 283165.0 3.418918 Y
8 STD20 280-633956/10 20.0 72.324578 8.0 286698.0 3.616229 Y
RelResp = [3.527]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 652 of 1261
Calibration / 2-Methylphenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.274
Error Coefficients
Standard Error:587000
Relative Standard Error:11.9
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.985
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.392126 8.0 268628.0 0.980315 Y
2 STD01 280-633956/5 1.0 1.149344 8.0 249304.0 1.149344 Y
3 STD02 280-633956/6 2.0 2.374338 8.0 268538.0 1.187169 N
4 STD05 280-633956/7 5.0 6.792062 8.0 259318.0 1.358412 Y
5 ICIS 280-633956/3 8.0 10.954485 8.0 274108.0 1.369311 Y
6 STD12 280-633956/8 12.0 15.875465 8.0 279825.0 1.322955 Y
7 STD16 280-633956/9 16.0 21.655049 8.0 283165.0 1.353441 Y
8 STD20 280-633956/10 20.0 27.636635 8.0 286698.0 1.381832 Y
RelResp = [1.274]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 653 of 1261
Calibration / Acetophenone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.993
Error Coefficients
Standard Error:895000
Relative Standard Error:8.0
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.676534 8.0 268628.0 1.691335 Y
2 STD01 280-633956/5 1.0 1.852549 8.0 249304.0 1.852549 Y
3 STD02 280-633956/6 2.0 3.609888 8.0 268538.0 1.804944 N
4 STD05 280-633956/7 5.0 10.517403 8.0 259318.0 2.103481 Y
5 ICIS 280-633956/3 8.0 16.727713 8.0 274108.0 2.090964 Y
6 STD12 280-633956/8 12.0 24.588025 8.0 279825.0 2.049002 Y
7 STD16 280-633956/9 16.0 33.18783 8.0 283165.0 2.074239 Y
8 STD20 280-633956/10 20.0 41.755827 8.0 286698.0 2.087791 Y
RelResp = [1.993]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 654 of 1261
Calibration / N-Nitrosodi-n-propylamine
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.14
Error Coefficients
Standard Error:520000
Relative Standard Error:10.3
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.370862 8.0 268628.0 0.927156 Y
2 STD01 280-633956/5 1.0 1.020986 8.0 249304.0 1.020986 Y
3 STD02 280-633956/6 2.0 1.990631 8.0 268538.0 0.995315 N
4 STD05 280-633956/7 5.0 5.971818 8.0 259318.0 1.194364 Y
5 ICIS 280-633956/3 8.0 9.890758 8.0 274108.0 1.236345 Y
6 STD12 280-633956/8 12.0 14.21883 8.0 279825.0 1.184902 Y
7 STD16 280-633956/9 16.0 19.059022 8.0 283165.0 1.191189 Y
8 STD20 280-633956/10 20.0 24.434939 8.0 286698.0 1.221747 Y
RelResp = [1.14]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 655 of 1261
Calibration / 3 & 4 Methylphenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.349
Error Coefficients
Standard Error:629000
Relative Standard Error:13.2
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.981
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.423336 8.0 268628.0 1.058341 Y
2 STD01 280-633956/5 1.0 1.122004 8.0 249304.0 1.122004 Y
3 STD02 280-633956/6 2.0 2.400167 8.0 268538.0 1.200083 N
4 STD05 280-633956/7 5.0 7.211686 8.0 259318.0 1.442337 Y
5 ICIS 280-633956/3 8.0 11.656719 8.0 274108.0 1.45709 Y
6 STD12 280-633956/8 12.0 17.233943 8.0 279825.0 1.436162 Y
7 STD16 280-633956/9 16.0 23.049092 8.0 283165.0 1.440568 Y
8 STD20 280-633956/10 20.0 29.693629 8.0 286698.0 1.484681 Y
RelResp = [1.349]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 656 of 1261
Calibration / Hexachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7184
Error Coefficients
Standard Error:321000
Relative Standard Error:6.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.249148 8.0 268628.0 0.622869 Y
2 STD01 280-633956/5 1.0 0.68806 8.0 249304.0 0.68806 Y
3 STD02 280-633956/6 2.0 1.311546 8.0 268538.0 0.655773 N
4 STD05 280-633956/7 5.0 3.761035 8.0 259318.0 0.752207 Y
5 ICIS 280-633956/3 8.0 6.002977 8.0 274108.0 0.750372 Y
6 STD12 280-633956/8 12.0 8.716448 8.0 279825.0 0.726371 Y
7 STD16 280-633956/9 16.0 11.721929 8.0 283165.0 0.732621 Y
8 STD20 280-633956/10 20.0 15.122952 8.0 286698.0 0.756148 Y
RelResp = [0.7184]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 657 of 1261
Calibration / Nitrobenzene-d5
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4187
Error Coefficients
Standard Error:724000
Relative Standard Error:8.3
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.144262 8.0 979829.0 0.360655 Y
2 STD01 280-633956/5 1.0 0.377097 8.0 919593.0 0.377097 Y
3 STD02 280-633956/6 2.0 0.750397 8.0 999258.0 0.375198 N
4 STD05 280-633956/7 5.0 2.180659 8.0 989147.0 0.436132 Y
5 ICIS 280-633956/3 8.0 3.513476 8.0 1056827.0 0.439184 Y
6 STD12 280-633956/8 12.0 5.161963 8.0 1067876.0 0.430164 Y
7 STD16 280-633956/9 16.0 7.04258 8.0 1078331.0 0.440161 Y
8 STD20 280-633956/10 20.0 8.951023 8.0 1086905.0 0.447551 Y
RelResp = [0.4187]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 658 of 1261
Calibration / Nitrobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4366
Error Coefficients
Standard Error:744000
Relative Standard Error:8.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.992
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.14365 8.0 979829.0 0.359124 Y
2 STD01 280-633956/5 1.0 0.417402 8.0 919593.0 0.417402 Y
3 STD02 280-633956/6 2.0 0.798032 8.0 999258.0 0.399016 N
4 STD05 280-633956/7 5.0 2.332814 8.0 989147.0 0.466563 Y
5 ICIS 280-633956/3 8.0 3.688112 8.0 1056827.0 0.461014 Y
6 STD12 280-633956/8 12.0 5.32088 8.0 1067876.0 0.443407 Y
7 STD16 280-633956/9 16.0 7.182173 8.0 1078331.0 0.448886 Y
8 STD20 280-633956/10 20.0 9.190573 8.0 1086905.0 0.459529 Y
RelResp = [0.4366]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 659 of 1261
Calibration / Isophorone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7463
Error Coefficients
Standard Error:1300000
Relative Standard Error:10.4
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.240238 8.0 979829.0 0.600595 Y
2 STD01 280-633956/5 1.0 0.673385 8.0 919593.0 0.673385 Y
3 STD02 280-633956/6 2.0 1.345478 8.0 999258.0 0.672739 N
4 STD05 280-633956/7 5.0 3.956459 8.0 989147.0 0.791292 Y
5 ICIS 280-633956/3 8.0 6.313593 8.0 1056827.0 0.789199 Y
6 STD12 280-633956/8 12.0 9.416052 8.0 1067876.0 0.784671 Y
7 STD16 280-633956/9 16.0 12.574751 8.0 1078331.0 0.785922 Y
8 STD20 280-633956/10 20.0 15.976152 8.0 1086905.0 0.798808 Y
RelResp = [0.7463]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 660 of 1261
Calibration / 2-Nitrophenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.03586
Slope:0.2089
Error Coefficients
Standard Error:380000
Relative Standard Error:4.4
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.05018 8.0 979829.0 0.12545 Y
2 STD01 280-633956/5 1.0 0.157313 8.0 919593.0 0.157313 Y
3 STD02 280-633956/6 2.0 0.329436 8.0 999258.0 0.164718 N
4 STD05 280-633956/7 5.0 1.007988 8.0 989147.0 0.201598 Y
5 ICIS 280-633956/3 8.0 1.584479 8.0 1056827.0 0.19806 Y
6 STD12 280-633956/8 12.0 2.521791 8.0 1067876.0 0.210149 Y
7 STD16 280-633956/9 16.0 3.364013 8.0 1078331.0 0.210251 Y
8 STD20 280-633956/10 20.0 4.303309 8.0 1086905.0 0.215165 Y
RelResp = [-0.03586] + [0.2089]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.172
Page 661 of 1261
Calibration / 2,4-Dimethylphenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2568
Error Coefficients
Standard Error:454000
Relative Standard Error:12.1
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.984
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.080667 8.0 979829.0 0.201668 Y
2 STD01 280-633956/5 1.0 0.223969 8.0 919593.0 0.223969 Y
3 STD02 280-633956/6 2.0 0.456739 8.0 999258.0 0.228369 N
4 STD05 280-633956/7 5.0 1.357339 8.0 989147.0 0.271468 Y
5 ICIS 280-633956/3 8.0 2.212389 8.0 1056827.0 0.276549 Y
6 STD12 280-633956/8 12.0 3.225513 8.0 1067876.0 0.268793 Y
7 STD16 280-633956/9 16.0 4.3522 8.0 1078331.0 0.272012 Y
8 STD20 280-633956/10 20.0 5.660071 8.0 1086905.0 0.283004 Y
RelResp = [0.2568]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 662 of 1261
Calibration / Bis(2-chloroethoxy)methane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4488
Error Coefficients
Standard Error:757000
Relative Standard Error:6.3
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.158411 8.0 979829.0 0.396028 Y
2 STD01 280-633956/5 1.0 0.431487 8.0 919593.0 0.431487 Y
3 STD02 280-633956/6 2.0 0.815605 8.0 999258.0 0.407803 N
4 STD05 280-633956/7 5.0 2.325818 8.0 989147.0 0.465164 Y
5 ICIS 280-633956/3 8.0 3.832166 8.0 1056827.0 0.479021 Y
6 STD12 280-633956/8 12.0 5.37365 8.0 1067876.0 0.447804 Y
7 STD16 280-633956/9 16.0 7.23455 8.0 1078331.0 0.452159 Y
8 STD20 280-633956/10 20.0 9.402426 8.0 1086905.0 0.470121 Y
RelResp = [0.4488]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 663 of 1261
Calibration / Benzoic acid
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.3476
Slope:0.2653
Error Coefficients
Standard Error:1060000
Relative Standard Error:5.9
Correlation Coefficient:0.996
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.8 0.008891 8.0 979829.0 0.011114 N
2 STD01 280-633956/5 2.0 0.190528 8.0 919593.0 0.095264 Y
3 STD02 280-633956/6 4.0 0.498858 8.0 999258.0 0.124715 N
4 STD05 280-633956/7 10.0 2.134364 8.0 989147.0 0.213436 Y
5 ICIS 280-633956/3 16.0 3.65301 8.0 1056827.0 0.228313 Y
6 STD12 280-633956/8 24.0 5.995325 8.0 1067876.0 0.249805 Y
7 STD16 280-633956/9 32.0 8.540658 8.0 1078331.0 0.266896 Y
8 STD20 280-633956/10 40.0 10.948335 8.0 1086905.0 0.273708 Y
RelResp = [-0.3476] + [0.2653]x
Concentration
0 10 20 30 40
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 1.31
Page 664 of 1261
Calibration / 2,4-Dichlorophenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.311
Error Coefficients
Standard Error:538000
Relative Standard Error:9.0
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.103692 8.0 979829.0 0.259229 Y
2 STD01 280-633956/5 1.0 0.284743 8.0 919593.0 0.284743 Y
3 STD02 280-633956/6 2.0 0.567813 8.0 999258.0 0.283907 N
4 STD05 280-633956/7 5.0 1.648798 8.0 989147.0 0.32976 Y
5 ICIS 280-633956/3 8.0 2.573174 8.0 1056827.0 0.321647 Y
6 STD12 280-633956/8 12.0 3.892849 8.0 1067876.0 0.324404 Y
7 STD16 280-633956/9 16.0 5.189709 8.0 1078331.0 0.324357 Y
8 STD20 280-633956/10 20.0 6.651076 8.0 1086905.0 0.332554 Y
RelResp = [0.311]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 665 of 1261
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.355
Error Coefficients
Standard Error:580000
Relative Standard Error:1.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.146793 8.0 979829.0 0.366982 Y
2 STD01 280-633956/5 1.0 0.354992 8.0 919593.0 0.354992 Y
3 STD02 280-633956/6 2.0 0.667655 8.0 999258.0 0.333828 N
4 STD05 280-633956/7 5.0 1.775542 8.0 989147.0 0.355108 Y
5 ICIS 280-633956/3 8.0 2.797173 8.0 1056827.0 0.349647 Y
6 STD12 280-633956/8 12.0 4.170934 8.0 1067876.0 0.347578 Y
7 STD16 280-633956/9 16.0 5.635739 8.0 1078331.0 0.352234 Y
8 STD20 280-633956/10 20.0 7.163739 8.0 1086905.0 0.358187 Y
RelResp = [0.355]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 666 of 1261
Calibration / Naphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.13
Error Coefficients
Standard Error:1810000
Relative Standard Error:2.7
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.460023 8.0 979829.0 1.150058 Y
2 STD01 280-633956/5 1.0 1.162453 8.0 919593.0 1.162453 Y
3 STD02 280-633956/6 2.0 2.145368 8.0 999258.0 1.072684 N
4 STD05 280-633956/7 5.0 5.806894 8.0 989147.0 1.161379 Y
5 ICIS 280-633956/3 8.0 9.09596 8.0 1056827.0 1.136995 Y
6 STD12 280-633956/8 12.0 13.203001 8.0 1067876.0 1.10025 Y
7 STD16 280-633956/9 16.0 17.419349 8.0 1078331.0 1.088709 Y
8 STD20 280-633956/10 20.0 22.200432 8.0 1086905.0 1.110022 Y
RelResp = [1.13]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
Page 667 of 1261
Calibration / 4-Chloroaniline
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4407
Error Coefficients
Standard Error:754000
Relative Standard Error:6.5
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.155007 8.0 979829.0 0.387517 Y
2 STD01 280-633956/5 1.0 0.416915 8.0 919593.0 0.416915 Y
3 STD02 280-633956/6 2.0 0.781484 8.0 999258.0 0.390742 N
4 STD05 280-633956/7 5.0 2.305332 8.0 989147.0 0.461066 Y
5 ICIS 280-633956/3 8.0 3.564353 8.0 1056827.0 0.445544 Y
6 STD12 280-633956/8 12.0 5.3962 8.0 1067876.0 0.449683 Y
7 STD16 280-633956/9 16.0 7.303086 8.0 1078331.0 0.456443 Y
8 STD20 280-633956/10 20.0 9.353546 8.0 1086905.0 0.467677 Y
RelResp = [0.4407]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 668 of 1261
Calibration / 2,6-Dichlorophenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3129
Error Coefficients
Standard Error:540000
Relative Standard Error:7.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.109905 8.0 979829.0 0.274762 Y
2 STD01 280-633956/5 1.0 0.282177 8.0 919593.0 0.282177 Y
3 STD02 280-633956/6 2.0 0.569126 8.0 999258.0 0.284563 N
4 STD05 280-633956/7 5.0 1.641568 8.0 989147.0 0.328314 Y
5 ICIS 280-633956/3 8.0 2.568791 8.0 1056827.0 0.321099 Y
6 STD12 280-633956/8 12.0 3.866936 8.0 1067876.0 0.322245 Y
7 STD16 280-633956/9 16.0 5.226462 8.0 1078331.0 0.326654 Y
8 STD20 280-633956/10 20.0 6.707486 8.0 1086905.0 0.335374 Y
RelResp = [0.3129]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 669 of 1261
Calibration / Hexachlorobutadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1892
Error Coefficients
Standard Error:316000
Relative Standard Error:2.5
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.07345 8.0 979829.0 0.183624 Y
2 STD01 280-633956/5 1.0 0.190032 8.0 919593.0 0.190032 Y
3 STD02 280-633956/6 2.0 0.347234 8.0 999258.0 0.173617 N
4 STD05 280-633956/7 5.0 0.960901 8.0 989147.0 0.19218 Y
5 ICIS 280-633956/3 8.0 1.460636 8.0 1056827.0 0.18258 Y
6 STD12 280-633956/8 12.0 2.264862 8.0 1067876.0 0.188739 Y
7 STD16 280-633956/9 16.0 3.062956 8.0 1078331.0 0.191435 Y
8 STD20 280-633956/10 20.0 3.922705 8.0 1086905.0 0.196135 Y
RelResp = [0.1892]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Page 670 of 1261
Calibration / 4-Chloro-3-methylphenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3051
Error Coefficients
Standard Error:547000
Relative Standard Error:14.6
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.977
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.092424 8.0 979829.0 0.231061 Y
2 STD01 280-633956/5 1.0 0.250528 8.0 919593.0 0.250528 Y
3 STD02 280-633956/6 2.0 0.547903 8.0 999258.0 0.273951 N
4 STD05 280-633956/7 5.0 1.635818 8.0 989147.0 0.327164 Y
5 ICIS 280-633956/3 8.0 2.641219 8.0 1056827.0 0.330152 Y
6 STD12 280-633956/8 12.0 3.917421 8.0 1067876.0 0.326452 Y
7 STD16 280-633956/9 16.0 5.308396 8.0 1078331.0 0.331775 Y
8 STD20 280-633956/10 20.0 6.770888 8.0 1086905.0 0.338544 Y
RelResp = [0.3051]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 671 of 1261
Calibration / 2-Methylnaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6156
Error Coefficients
Standard Error:1040000
Relative Standard Error:4.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.22252 8.0 979829.0 0.556301 Y
2 STD01 280-633956/5 1.0 0.606468 8.0 919593.0 0.606468 Y
3 STD02 280-633956/6 2.0 1.158428 8.0 999258.0 0.579214 N
4 STD05 280-633956/7 5.0 3.1792 8.0 989147.0 0.63584 Y
5 ICIS 280-633956/3 8.0 5.000152 8.0 1056827.0 0.625019 Y
6 STD12 280-633956/8 12.0 7.448588 8.0 1067876.0 0.620716 Y
7 STD16 280-633956/9 16.0 9.925798 8.0 1078331.0 0.620362 Y
8 STD20 280-633956/10 20.0 12.895891 8.0 1086905.0 0.644795 Y
RelResp = [0.6156]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 672 of 1261
Calibration / 1-Methylnaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6737
Error Coefficients
Standard Error:1130000
Relative Standard Error:3.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.248729 8.0 979829.0 0.621823 Y
2 STD01 280-633956/5 1.0 0.66298 8.0 919593.0 0.66298 Y
3 STD02 280-633956/6 2.0 1.256028 8.0 999258.0 0.628014 N
4 STD05 280-633956/7 5.0 3.482645 8.0 989147.0 0.696529 Y
5 ICIS 280-633956/3 8.0 5.451889 8.0 1056827.0 0.681486 Y
6 STD12 280-633956/8 12.0 8.097794 8.0 1067876.0 0.674816 Y
7 STD16 280-633956/9 16.0 10.922598 8.0 1078331.0 0.682662 Y
8 STD20 280-633956/10 20.0 13.912458 8.0 1086905.0 0.695623 Y
RelResp = [0.6737]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 673 of 1261
Calibration / Hexachlorocyclopentadiene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.5282
Slope:0.2076
Error Coefficients
Standard Error:218000
Relative Standard Error:3.5
Correlation Coefficient:0.996
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.0 8.0 530111.0 0.0 N
2 STD01 280-633956/5 1.0 0.018205 8.0 494383.0 0.018205 N
3 STD02 280-633956/6 2.0 0.114388 8.0 542716.0 0.057194 N
4 STD05 280-633956/7 5.0 0.522311 8.0 536309.0 0.104462 Y
5 ICIS 280-633956/3 8.0 1.123315 8.0 570732.0 0.140414 Y
6 STD12 280-633956/8 12.0 1.87517 8.0 580679.0 0.156264 Y
7 STD16 280-633956/9 16.0 2.742728 8.0 581319.0 0.171421 Y
8 STD20 280-633956/10 20.0 3.808369 8.0 581763.0 0.190418 Y
RelResp = [-0.5282] + [0.2076]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 2.54
Page 674 of 1261
Calibration / 1,2,4,5-Tetrachlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3428
Error Coefficients
Standard Error:571000
Relative Standard Error:3.0
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.140473 8.0 979829.0 0.351184 Y
2 STD01 280-633956/5 1.0 0.330103 8.0 919593.0 0.330103 Y
3 STD02 280-633956/6 2.0 0.642589 8.0 999258.0 0.321294 N
4 STD05 280-633956/7 5.0 1.721823 8.0 989147.0 0.344365 Y
5 ICIS 280-633956/3 8.0 2.618116 8.0 1056827.0 0.327265 Y
6 STD12 280-633956/8 12.0 4.129026 8.0 1067876.0 0.344086 Y
7 STD16 280-633956/9 16.0 5.599728 8.0 1078331.0 0.349983 Y
8 STD20 280-633956/10 20.0 7.052465 8.0 1086905.0 0.352623 Y
RelResp = [0.3428]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Page 675 of 1261
Calibration / 2,4,6-Trichlorophenol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3834
Error Coefficients
Standard Error:372000
Relative Standard Error:14.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.977
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.112731 8.0 530111.0 0.281828 Y
2 STD01 280-633956/5 1.0 0.325383 8.0 494383.0 0.325383 Y
3 STD02 280-633956/6 2.0 0.669168 8.0 542716.0 0.334584 N
4 STD05 280-633956/7 5.0 2.054502 8.0 536309.0 0.4109 Y
5 ICIS 280-633956/3 8.0 3.237022 8.0 570732.0 0.404628 Y
6 STD12 280-633956/8 12.0 4.929374 8.0 580679.0 0.410781 Y
7 STD16 280-633956/9 16.0 6.690826 8.0 581319.0 0.418177 Y
8 STD20 280-633956/10 20.0 8.641017 8.0 581763.0 0.432051 Y
RelResp = [0.3834]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 676 of 1261
Calibration / 2,4,5-Trichlorophenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.06911
Slope:0.4385
Error Coefficients
Standard Error:430000
Relative Standard Error:3.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.110588 8.0 530111.0 0.27647 Y
2 STD01 280-633956/5 1.0 0.343248 8.0 494383.0 0.343248 Y
3 STD02 280-633956/6 2.0 0.696718 8.0 542716.0 0.348359 N
4 STD05 280-633956/7 5.0 2.072492 8.0 536309.0 0.414498 Y
5 ICIS 280-633956/3 8.0 3.423351 8.0 570732.0 0.427919 Y
6 STD12 280-633956/8 12.0 5.157411 8.0 580679.0 0.429784 Y
7 STD16 280-633956/9 16.0 7.137203 8.0 581319.0 0.446075 Y
8 STD20 280-633956/10 20.0 9.066647 8.0 581763.0 0.453332 Y
RelResp = [-0.06911] + [0.4385]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.158
Page 677 of 1261
Calibration / 2-Fluorobiphenyl
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.43
Error Coefficients
Standard Error:1270000
Relative Standard Error:1.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.565663 8.0 530111.0 1.414157 Y
2 STD01 280-633956/5 1.0 1.419563 8.0 494383.0 1.419563 Y
3 STD02 280-633956/6 2.0 2.680385 8.0 542716.0 1.340193 N
4 STD05 280-633956/7 5.0 7.331296 8.0 536309.0 1.466259 Y
5 ICIS 280-633956/3 8.0 11.367255 8.0 570732.0 1.420907 Y
6 STD12 280-633956/8 12.0 16.949054 8.0 580679.0 1.412421 Y
7 STD16 280-633956/9 16.0 22.835049 8.0 581319.0 1.427191 Y
8 STD20 280-633956/10 20.0 29.015238 8.0 581763.0 1.450762 Y
RelResp = [1.43]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 678 of 1261
Calibration / 1,1'-Biphenyl
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.65
Error Coefficients
Standard Error:1480000
Relative Standard Error:2.9
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.624292 8.0 530111.0 1.56073 Y
2 STD01 280-633956/5 1.0 1.634716 8.0 494383.0 1.634716 Y
3 STD02 280-633956/6 2.0 3.008881 8.0 542716.0 1.504441 N
4 STD05 280-633956/7 5.0 8.472757 8.0 536309.0 1.694551 Y
5 ICIS 280-633956/3 8.0 13.25017 8.0 570732.0 1.656271 Y
6 STD12 280-633956/8 12.0 19.545312 8.0 580679.0 1.628776 Y
7 STD16 280-633956/9 16.0 26.786697 8.0 581319.0 1.674169 Y
8 STD20 280-633956/10 20.0 34.050581 8.0 581763.0 1.702529 Y
RelResp = [1.65]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 679 of 1261
Calibration / 2-Chloronaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.315
Error Coefficients
Standard Error:1190000
Relative Standard Error:4.0
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.482299 8.0 530111.0 1.205747 Y
2 STD01 280-633956/5 1.0 1.307812 8.0 494383.0 1.307812 Y
3 STD02 280-633956/6 2.0 2.395374 8.0 542716.0 1.197687 N
4 STD05 280-633956/7 5.0 6.781568 8.0 536309.0 1.356314 Y
5 ICIS 280-633956/3 8.0 10.548068 8.0 570732.0 1.318509 Y
6 STD12 280-633956/8 12.0 15.744561 8.0 580679.0 1.312047 Y
7 STD16 280-633956/9 16.0 21.423102 8.0 581319.0 1.338944 Y
8 STD20 280-633956/10 20.0 27.298415 8.0 581763.0 1.364921 Y
RelResp = [1.315]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 680 of 1261
Calibration / 2-Nitroaniline
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.09913
Slope:0.5077
Error Coefficients
Standard Error:495000
Relative Standard Error:5.9
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.112957 8.0 530111.0 0.282394 Y
2 STD01 280-633956/5 1.0 0.349446 8.0 494383.0 0.349446 Y
3 STD02 280-633956/6 2.0 0.733142 8.0 542716.0 0.366571 N
4 STD05 280-633956/7 5.0 2.444591 8.0 536309.0 0.488918 Y
5 ICIS 280-633956/3 8.0 4.040495 8.0 570732.0 0.505062 Y
6 STD12 280-633956/8 12.0 5.999363 8.0 580679.0 0.499947 Y
7 STD16 280-633956/9 16.0 8.096264 8.0 581319.0 0.506016 Y
8 STD20 280-633956/10 20.0 10.46851 8.0 581763.0 0.523426 Y
RelResp = [-0.09913] + [0.5077]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Intercept = 0.195
Page 681 of 1261
Calibration / Dimethyl phthalate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.391
Error Coefficients
Standard Error:1270000
Relative Standard Error:6.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.495941 8.0 530111.0 1.239854 Y
2 STD01 280-633956/5 1.0 1.313006 8.0 494383.0 1.313006 Y
3 STD02 280-633956/6 2.0 2.58348 8.0 542716.0 1.29174 N
4 STD05 280-633956/7 5.0 7.353776 8.0 536309.0 1.470755 Y
5 ICIS 280-633956/3 8.0 11.25216 8.0 570732.0 1.40652 Y
6 STD12 280-633956/8 12.0 17.106456 8.0 580679.0 1.425538 Y
7 STD16 280-633956/9 16.0 22.917538 8.0 581319.0 1.432346 Y
8 STD20 280-633956/10 20.0 29.008321 8.0 581763.0 1.450416 Y
RelResp = [1.391]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 682 of 1261
Calibration / 1,3-Dinitrobenzene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.04717
Slope:0.2333
Error Coefficients
Standard Error:235000
Relative Standard Error:9.3
Correlation Coefficient:0.997
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.052261 8.0 530111.0 0.130652 Y
2 STD01 280-633956/5 1.0 0.147869 8.0 494383.0 0.147869 Y
3 STD02 280-633956/6 2.0 0.326506 8.0 542716.0 0.163253 N
4 STD05 280-633956/7 5.0 1.097934 8.0 536309.0 0.219587 Y
5 ICIS 280-633956/3 8.0 1.747987 8.0 570732.0 0.218498 Y
6 STD12 280-633956/8 12.0 2.79831 8.0 580679.0 0.233193 Y
7 STD16 280-633956/9 16.0 3.896711 8.0 581319.0 0.243544 Y
8 STD20 280-633956/10 20.0 5.004952 8.0 581763.0 0.250248 Y
RelResp = [-0.04717] + [0.2333]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.202
Page 683 of 1261
Calibration / 2,6-Dinitrotoluene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.07533
Slope:0.341
Error Coefficients
Standard Error:329000
Relative Standard Error:4.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.06536 8.0 530111.0 0.1634 Y
2 STD01 280-633956/5 1.0 0.23627 8.0 494383.0 0.23627 Y
3 STD02 280-633956/6 2.0 0.541985 8.0 542716.0 0.270993 N
4 STD05 280-633956/7 5.0 1.700423 8.0 536309.0 0.340085 Y
5 ICIS 280-633956/3 8.0 2.589881 8.0 570732.0 0.323735 Y
6 STD12 280-633956/8 12.0 4.029986 8.0 580679.0 0.335832 Y
7 STD16 280-633956/9 16.0 5.43751 8.0 581319.0 0.339844 Y
8 STD20 280-633956/10 20.0 6.897022 8.0 581763.0 0.344851 Y
RelResp = [-0.07533] + [0.341]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.221
Page 684 of 1261
Calibration / Acenaphthylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.892
Error Coefficients
Standard Error:1750000
Relative Standard Error:9.0
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.991
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.629544 8.0 530111.0 1.573859 Y
2 STD01 280-633956/5 1.0 1.735286 8.0 494383.0 1.735286 Y
3 STD02 280-633956/6 2.0 3.482809 8.0 542716.0 1.741404 N
4 STD05 280-633956/7 5.0 10.169675 8.0 536309.0 2.033935 Y
5 ICIS 280-633956/3 8.0 15.950295 8.0 570732.0 1.993787 Y
6 STD12 280-633956/8 12.0 23.43834 8.0 580679.0 1.953195 Y
7 STD16 280-633956/9 16.0 31.272716 8.0 581319.0 1.954545 Y
8 STD20 280-633956/10 20.0 40.027723 8.0 581763.0 2.001386 Y
RelResp = [1.892]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 685 of 1261
Calibration / 3-Nitroaniline
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.07423
Slope:0.3972
Error Coefficients
Standard Error:383000
Relative Standard Error:4.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.089415 8.0 530111.0 0.223538 Y
2 STD01 280-633956/5 1.0 0.290544 8.0 494383.0 0.290544 Y
3 STD02 280-633956/6 2.0 0.621408 8.0 542716.0 0.310704 N
4 STD05 280-633956/7 5.0 1.974757 8.0 536309.0 0.394951 Y
5 ICIS 280-633956/3 8.0 3.074872 8.0 570732.0 0.384359 Y
6 STD12 280-633956/8 12.0 4.709149 8.0 580679.0 0.392429 Y
7 STD16 280-633956/9 16.0 6.359345 8.0 581319.0 0.397459 Y
8 STD20 280-633956/10 20.0 7.976788 8.0 581763.0 0.398839 Y
RelResp = [-0.07423] + [0.3972]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.187
Page 686 of 1261
Calibration / Acenaphthene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.303
Error Coefficients
Standard Error:1160000
Relative Standard Error:2.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.496892 8.0 530111.0 1.24223 Y
2 STD01 280-633956/5 1.0 1.286517 8.0 494383.0 1.286517 Y
3 STD02 280-633956/6 2.0 2.38712 8.0 542716.0 1.19356 N
4 STD05 280-633956/7 5.0 6.729076 8.0 536309.0 1.345815 Y
5 ICIS 280-633956/3 8.0 10.496471 8.0 570732.0 1.312059 Y
6 STD12 280-633956/8 12.0 15.499551 8.0 580679.0 1.291629 Y
7 STD16 280-633956/9 16.0 21.059597 8.0 581319.0 1.316225 Y
8 STD20 280-633956/10 20.0 26.585176 8.0 581763.0 1.329259 Y
RelResp = [1.303]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 687 of 1261
Calibration / 2,4-Dinitrophenol
Curve Type:Quadratic
Weighting:None
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2044
Slope:0.1003
Second Order:0.001987
Error Coefficients
Standard Error:398000
Relative Standard Error:3.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.8 0.0 8.0 530111.0 0.0 N
2 STD01 280-633956/5 2.0 0.016295 8.0 494383.0 0.008148 Y
3 STD02 280-633956/6 4.0 0.134523 8.0 542716.0 0.033631 N
4 STD05 280-633956/7 10.0 0.976184 8.0 536309.0 0.097618 Y
5 ICIS 280-633956/3 16.0 1.911454 8.0 570732.0 0.119466 Y
6 STD12 280-633956/8 24.0 3.337541 8.0 580679.0 0.139064 Y
7 STD16 280-633956/9 32.0 5.069698 8.0 581319.0 0.158428 Y
8 STD20 280-633956/10 40.0 6.970564 8.0 581763.0 0.174264 Y
RelResp = [-0.2044] + [0.1003]x + [0.001987]x^2
Concentration
0 10 20 30 40
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
Intercept = 1.96
Page 688 of 1261
Calibration / Dibenzofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.81
Error Coefficients
Standard Error:1600000
Relative Standard Error:2.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.697092 8.0 530111.0 1.742729 Y
2 STD01 280-633956/5 1.0 1.808816 8.0 494383.0 1.808816 Y
3 STD02 280-633956/6 2.0 3.398802 8.0 542716.0 1.699401 N
4 STD05 280-633956/7 5.0 9.432562 8.0 536309.0 1.886512 Y
5 ICIS 280-633956/3 8.0 14.419896 8.0 570732.0 1.802487 Y
6 STD12 280-633956/8 12.0 21.785572 8.0 580679.0 1.815464 Y
7 STD16 280-633956/9 16.0 28.630091 8.0 581319.0 1.789381 Y
8 STD20 280-633956/10 20.0 36.430505 8.0 581763.0 1.821525 Y
RelResp = [1.81]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 689 of 1261
Calibration / 2,4-Dinitrotoluene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1071
Slope:0.4551
Error Coefficients
Standard Error:445000
Relative Standard Error:7.6
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.085265 8.0 530111.0 0.213163 Y
2 STD01 280-633956/5 1.0 0.280398 8.0 494383.0 0.280398 Y
3 STD02 280-633956/6 2.0 0.665335 8.0 542716.0 0.332668 N
4 STD05 280-633956/7 5.0 2.218438 8.0 536309.0 0.443688 Y
5 ICIS 280-633956/3 8.0 3.450488 8.0 570732.0 0.431311 Y
6 STD12 280-633956/8 12.0 5.492825 8.0 580679.0 0.457735 Y
7 STD16 280-633956/9 16.0 7.407664 8.0 581319.0 0.462979 Y
8 STD20 280-633956/10 20.0 9.318723 8.0 581763.0 0.465936 Y
RelResp = [-0.1071] + [0.4551]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.235
Page 690 of 1261
Calibration / 4-Nitrophenol
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1647
Slope:0.197
Error Coefficients
Standard Error:374000
Relative Standard Error:16.1
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.8 0.035283 8.0 530111.0 0.044104 Y
2 STD01 280-633956/5 2.0 0.136655 8.0 494383.0 0.068328 Y
3 STD02 280-633956/6 4.0 0.422055 8.0 542716.0 0.105514 N
4 STD05 280-633956/7 10.0 1.739326 8.0 536309.0 0.173933 Y
5 ICIS 280-633956/3 16.0 2.95633 8.0 570732.0 0.184771 Y
6 STD12 280-633956/8 24.0 4.436475 8.0 580679.0 0.184853 Y
7 STD16 280-633956/9 32.0 6.209561 8.0 581319.0 0.194049 Y
8 STD20 280-633956/10 40.0 7.924973 8.0 581763.0 0.198124 Y
RelResp = [-0.1647] + [0.197]x
Concentration
0 10 20 30 40
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.836
Page 691 of 1261
Calibration / 2,3,4,6-Tetrachlorophenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.08998
Slope:0.3175
Error Coefficients
Standard Error:314000
Relative Standard Error:7.6
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.04384 8.0 530111.0 0.1096 Y
2 STD01 280-633956/5 1.0 0.184116 8.0 494383.0 0.184116 Y
3 STD02 280-633956/6 2.0 0.440053 8.0 542716.0 0.220027 N
4 STD05 280-633956/7 5.0 1.487277 8.0 536309.0 0.297455 Y
5 ICIS 280-633956/3 8.0 2.406664 8.0 570732.0 0.300833 Y
6 STD12 280-633956/8 12.0 3.691224 8.0 580679.0 0.307602 Y
7 STD16 280-633956/9 16.0 5.225468 8.0 581319.0 0.326592 Y
8 STD20 280-633956/10 20.0 6.686627 8.0 581763.0 0.334331 Y
RelResp = [-0.08998] + [0.3175]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.283
Page 692 of 1261
Calibration / Diethyl phthalate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.424
Error Coefficients
Standard Error:1290000
Relative Standard Error:7.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.48912 8.0 530111.0 1.222801 Y
2 STD01 280-633956/5 1.0 1.356082 8.0 494383.0 1.356082 Y
3 STD02 280-633956/6 2.0 2.619315 8.0 542716.0 1.309657 N
4 STD05 280-633956/7 5.0 7.601066 8.0 536309.0 1.520213 Y
5 ICIS 280-633956/3 8.0 11.722139 8.0 570732.0 1.465267 Y
6 STD12 280-633956/8 12.0 17.536863 8.0 580679.0 1.461405 Y
7 STD16 280-633956/9 16.0 23.649088 8.0 581319.0 1.478068 Y
8 STD20 280-633956/10 20.0 29.219569 8.0 581763.0 1.460978 Y
RelResp = [1.424]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 693 of 1261
Calibration / Fluorene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.44
Error Coefficients
Standard Error:1280000
Relative Standard Error:3.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.54446 8.0 530111.0 1.361149 Y
2 STD01 280-633956/5 1.0 1.426878 8.0 494383.0 1.426878 Y
3 STD02 280-633956/6 2.0 2.73354 8.0 542716.0 1.36677 N
4 STD05 280-633956/7 5.0 7.539087 8.0 536309.0 1.507817 Y
5 ICIS 280-633956/3 8.0 11.408297 8.0 570732.0 1.426037 Y
6 STD12 280-633956/8 12.0 17.177146 8.0 580679.0 1.431429 Y
7 STD16 280-633956/9 16.0 23.398994 8.0 581319.0 1.462437 Y
8 STD20 280-633956/10 20.0 29.224423 8.0 581763.0 1.461221 Y
RelResp = [1.44]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Page 694 of 1261
Calibration / 4-Chlorophenyl phenyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6724
Error Coefficients
Standard Error:599000
Relative Standard Error:2.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.25978 8.0 530111.0 0.649449 Y
2 STD01 280-633956/5 1.0 0.675266 8.0 494383.0 0.675266 Y
3 STD02 280-633956/6 2.0 1.288202 8.0 542716.0 0.644101 N
4 STD05 280-633956/7 5.0 3.449608 8.0 536309.0 0.689922 Y
5 ICIS 280-633956/3 8.0 5.2777 8.0 570732.0 0.659712 Y
6 STD12 280-633956/8 12.0 8.049556 8.0 580679.0 0.670796 Y
7 STD16 280-633956/9 16.0 10.827281 8.0 581319.0 0.676705 Y
8 STD20 280-633956/10 20.0 13.700658 8.0 581763.0 0.685033 Y
RelResp = [0.6724]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Page 695 of 1261
Calibration / 4-Nitroaniline
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.07549
Slope:0.3985
Error Coefficients
Standard Error:378000
Relative Standard Error:3.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.086276 8.0 530111.0 0.215691 Y
2 STD01 280-633956/5 1.0 0.30459 8.0 494383.0 0.30459 Y
3 STD02 280-633956/6 2.0 0.638419 8.0 542716.0 0.319209 N
4 STD05 280-633956/7 5.0 2.025758 8.0 536309.0 0.405152 Y
5 ICIS 280-633956/3 8.0 3.122152 8.0 570732.0 0.390269 Y
6 STD12 280-633956/8 12.0 4.630799 8.0 580679.0 0.3859 Y
7 STD16 280-633956/9 16.0 6.326592 8.0 581319.0 0.395412 Y
8 STD20 280-633956/10 20.0 7.784682 8.0 581763.0 0.389234 Y
RelResp = [-0.07549] + [0.3985]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
Intercept = 0.189
Page 696 of 1261
Calibration / 4,6-Dinitro-2-methylphenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1795
Slope:0.1442
Error Coefficients
Standard Error:542000
Relative Standard Error:4.9
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.8 0.023221 8.0 967055.0 0.029026 N
2 STD01 280-633956/5 2.0 0.112386 8.0 920189.0 0.056193 Y
3 STD02 280-633956/6 4.0 0.289807 8.0 998953.0 0.072452 N
4 STD05 280-633956/7 10.0 1.182811 8.0 989771.0 0.118281 Y
5 ICIS 280-633956/3 16.0 2.029224 8.0 1008571.0 0.126826 Y
6 STD12 280-633956/8 24.0 3.273142 8.0 1042988.0 0.136381 Y
7 STD16 280-633956/9 32.0 4.554908 8.0 1033540.0 0.142341 Y
8 STD20 280-633956/10 40.0 5.952225 8.0 1006263.0 0.148806 Y
RelResp = [-0.1795] + [0.1442]x
Concentration
0 10 20 30 40
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 1.24
Page 697 of 1261
Calibration / Diphenylamine
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.181
Error Coefficients
Standard Error:916000
Relative Standard Error:6.6
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.995
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.34 0.349708 8.0 530111.0 1.028553 Y
2 STD01 280-633956/5 0.85 0.958819 8.0 494383.0 1.128023 Y
3 STD02 280-633956/6 1.7 1.885804 8.0 542716.0 1.109296 N
4 STD05 280-633956/7 4.25 5.27208 8.0 536309.0 1.240489 Y
5 ICIS 280-633956/3 6.8 8.11679 8.0 570732.0 1.193646 Y
6 STD12 280-633956/8 10.2 12.485976 8.0 580679.0 1.224115 Y
7 STD16 280-633956/9 13.6 16.845415 8.0 581319.0 1.238633 Y
8 STD20 280-633956/10 17.0 20.639511 8.0 581763.0 1.214089 Y
RelResp = [1.181]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 698 of 1261
Calibration / N-Nitrosodiphenylamine
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5577
Error Coefficients
Standard Error:916000
Relative Standard Error:7.7
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.192394 8.0 967055.0 0.480986 Y
2 STD01 280-633956/5 1.0 0.515138 8.0 920189.0 0.515138 Y
3 STD02 280-633956/6 2.0 1.03297 8.0 998953.0 0.516485 N
4 STD05 280-633956/7 5.0 2.838879 8.0 989771.0 0.567776 Y
5 ICIS 280-633956/3 8.0 4.584863 8.0 1008571.0 0.573108 Y
6 STD12 280-633956/8 12.0 6.937215 8.0 1042988.0 0.578101 Y
7 STD16 280-633956/9 16.0 9.474776 8.0 1033540.0 0.592174 Y
8 STD20 280-633956/10 20.0 11.93257 8.0 1006263.0 0.596629 Y
RelResp = [0.5577]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 699 of 1261
Calibration / 1,2-Diphenylhydrazine
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.673
Error Coefficients
Standard Error:1550000
Relative Standard Error:10.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.40439 0.537563 8.0 530111.0 1.329319 Y
2 STD01 280-633956/5 1.010975 1.586818 8.0 494383.0 1.569593 Y
3 STD02 280-633956/6 2.021949 3.146603 8.0 542716.0 1.556223 N
4 STD05 280-633956/7 5.054873 9.212316 8.0 536309.0 1.822463 Y
5 ICIS 280-633956/3 8.087796 14.61385 8.0 570732.0 1.806901 Y
6 STD12 280-633956/8 12.131694 20.899781 8.0 580679.0 1.722742 Y
7 STD16 280-633956/9 16.175593 27.910968 8.0 581319.0 1.725499 Y
8 STD20 280-633956/10 20.219491 35.06071 8.0 581763.0 1.734006 Y
RelResp = [1.673]x
Concentration
0 10 20 30
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
Page 700 of 1261
Calibration / Azobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.691
Error Coefficients
Standard Error:1550000
Relative Standard Error:10.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.988
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.537563 8.0 530111.0 1.343907 Y
2 STD01 280-633956/5 1.0 1.586818 8.0 494383.0 1.586818 Y
3 STD02 280-633956/6 2.0 3.146603 8.0 542716.0 1.573302 N
4 STD05 280-633956/7 5.0 9.212316 8.0 536309.0 1.842463 Y
5 ICIS 280-633956/3 8.0 14.61385 8.0 570732.0 1.826731 Y
6 STD12 280-633956/8 12.0 20.899781 8.0 580679.0 1.741648 Y
7 STD16 280-633956/9 16.0 27.910968 8.0 581319.0 1.744435 Y
8 STD20 280-633956/10 20.0 35.06071 8.0 581763.0 1.753036 Y
RelResp = [1.691]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 701 of 1261
Calibration / 2,4,6-Tribromophenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.05433
Slope:0.2108
Error Coefficients
Standard Error:203000
Relative Standard Error:2.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.031329 8.0 530111.0 0.078323 Y
2 STD01 280-633956/5 1.0 0.147853 8.0 494383.0 0.147853 Y
3 STD02 280-633956/6 2.0 0.327258 8.0 542716.0 0.163629 N
4 STD05 280-633956/7 5.0 1.004898 8.0 536309.0 0.20098 Y
5 ICIS 280-633956/3 8.0 1.582837 8.0 570732.0 0.197855 Y
6 STD12 280-633956/8 12.0 2.481784 8.0 580679.0 0.206815 Y
7 STD16 280-633956/9 16.0 3.411951 8.0 581319.0 0.213247 Y
8 STD20 280-633956/10 20.0 4.234412 8.0 581763.0 0.211721 Y
RelResp = [-0.05433] + [0.2108]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.258
Page 702 of 1261
Calibration / 4-Bromophenyl phenyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2118
Error Coefficients
Standard Error:344000
Relative Standard Error:5.2
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.079176 8.0 967055.0 0.197941 Y
2 STD01 280-633956/5 1.0 0.197386 8.0 920189.0 0.197386 Y
3 STD02 280-633956/6 2.0 0.36889 8.0 998953.0 0.184445 N
4 STD05 280-633956/7 5.0 1.070316 8.0 989771.0 0.214063 Y
5 ICIS 280-633956/3 8.0 1.679628 8.0 1008571.0 0.209953 Y
6 STD12 280-633956/8 12.0 2.599209 8.0 1042988.0 0.216601 Y
7 STD16 280-633956/9 16.0 3.497355 8.0 1033540.0 0.218585 Y
8 STD20 280-633956/10 20.0 4.554968 8.0 1006263.0 0.227748 Y
RelResp = [0.2118]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Page 703 of 1261
Calibration / Hexachlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2535
Error Coefficients
Standard Error:400000
Relative Standard Error:2.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.103547 8.0 967055.0 0.258868 Y
2 STD01 280-633956/5 1.0 0.252374 8.0 920189.0 0.252374 Y
3 STD02 280-633956/6 2.0 0.4473 8.0 998953.0 0.22365 N
4 STD05 280-633956/7 5.0 1.246907 8.0 989771.0 0.249381 Y
5 ICIS 280-633956/3 8.0 1.982266 8.0 1008571.0 0.247783 Y
6 STD12 280-633956/8 12.0 2.964805 8.0 1042988.0 0.247067 Y
7 STD16 280-633956/9 16.0 4.033555 8.0 1033540.0 0.252097 Y
8 STD20 280-633956/10 20.0 5.333198 8.0 1006263.0 0.26666 Y
RelResp = [0.2535]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 704 of 1261
Calibration / Pentachlorophenol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.3717
Slope:0.1411
Error Coefficients
Standard Error:498000
Relative Standard Error:4.1
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.8 0.007917 8.0 967055.0 0.009896 N
2 STD01 280-633956/5 2.0 0.059466 8.0 920189.0 0.029733 N
3 STD02 280-633956/6 4.0 0.199809 8.0 998953.0 0.049952 Y
4 STD05 280-633956/7 10.0 0.992739 8.0 989771.0 0.099274 Y
5 ICIS 280-633956/3 16.0 1.897877 8.0 1008571.0 0.118617 Y
6 STD12 280-633956/8 24.0 2.892858 8.0 1042988.0 0.120536 Y
7 STD16 280-633956/9 32.0 4.083194 8.0 1033540.0 0.1276 Y
8 STD20 280-633956/10 40.0 5.624327 8.0 1006263.0 0.140608 Y
RelResp = [-0.3717] + [0.1411]x
Concentration
0 10 20 30 40
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 2.64
Page 705 of 1261
Calibration / Phenanthrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.151
Error Coefficients
Standard Error:1790000
Relative Standard Error:1.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):1.000
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.464065 8.0 967055.0 1.160162 Y
2 STD01 280-633956/5 1.0 1.154893 8.0 920189.0 1.154893 Y
3 STD02 280-633956/6 2.0 2.18383 8.0 998953.0 1.091915 N
4 STD05 280-633956/7 5.0 5.797971 8.0 989771.0 1.159594 Y
5 ICIS 280-633956/3 8.0 9.169988 8.0 1008571.0 1.146249 Y
6 STD12 280-633956/8 12.0 13.525778 8.0 1042988.0 1.127148 Y
7 STD16 280-633956/9 16.0 18.253513 8.0 1033540.0 1.140845 Y
8 STD20 280-633956/10 20.0 23.310789 8.0 1006263.0 1.165539 Y
RelResp = [1.151]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Page 706 of 1261
Calibration / Anthracene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.095
Error Coefficients
Standard Error:1780000
Relative Standard Error:7.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.380057 8.0 967055.0 0.950142 Y
2 STD01 280-633956/5 1.0 1.013705 8.0 920189.0 1.013705 Y
3 STD02 280-633956/6 2.0 1.943691 8.0 998953.0 0.971846 N
4 STD05 280-633956/7 5.0 5.726262 8.0 989771.0 1.145252 Y
5 ICIS 280-633956/3 8.0 9.06757 8.0 1008571.0 1.133446 Y
6 STD12 280-633956/8 12.0 13.508497 8.0 1042988.0 1.125708 Y
7 STD16 280-633956/9 16.0 18.269071 8.0 1033540.0 1.141817 Y
8 STD20 280-633956/10 20.0 23.109577 8.0 1006263.0 1.155479 Y
RelResp = [1.095]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 707 of 1261
Calibration / Carbazole
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.046
Error Coefficients
Standard Error:1680000
Relative Standard Error:7.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.356224 8.0 967055.0 0.890559 Y
2 STD01 280-633956/5 1.0 0.980425 8.0 920189.0 0.980425 Y
3 STD02 280-633956/6 2.0 1.933665 8.0 998953.0 0.966832 N
4 STD05 280-633956/7 5.0 5.58998 8.0 989771.0 1.117996 Y
5 ICIS 280-633956/3 8.0 8.800253 8.0 1008571.0 1.100032 Y
6 STD12 280-633956/8 12.0 12.872486 8.0 1042988.0 1.072707 Y
7 STD16 280-633956/9 16.0 17.193962 8.0 1033540.0 1.074623 Y
8 STD20 280-633956/10 20.0 21.765658 8.0 1006263.0 1.088283 Y
RelResp = [1.046]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 708 of 1261
Calibration / Alachlor
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1329
Error Coefficients
Standard Error:245000
Relative Standard Error:14.0
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.979
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.032114 8.0 967055.0 0.080285 N
2 STD01 280-633956/5 1.0 0.096232 8.0 920189.0 0.096232 Y
3 STD02 280-633956/6 2.0 0.196446 8.0 998953.0 0.098223 N
4 STD05 280-633956/7 5.0 0.680432 8.0 989771.0 0.136086 Y
5 ICIS 280-633956/3 8.0 1.071068 8.0 1008571.0 0.133883 Y
6 STD12 280-633956/8 12.0 1.676591 8.0 1042988.0 0.139716 Y
7 STD16 280-633956/9 16.0 2.300312 8.0 1033540.0 0.143769 Y
8 STD20 280-633956/10 20.0 2.950902 8.0 1006263.0 0.147545 Y
RelResp = [0.1329]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 709 of 1261
Calibration / Di-n-butyl phthalate
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2606
Slope:1.362
Error Coefficients
Standard Error:2320000
Relative Standard Error:4.9
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.304107 8.0 967055.0 0.760267 Y
2 STD01 280-633956/5 1.0 0.969044 8.0 920189.0 0.969044 Y
3 STD02 280-633956/6 2.0 2.065587 8.0 998953.0 1.032793 N
4 STD05 280-633956/7 5.0 6.59203 8.0 989771.0 1.318406 Y
5 ICIS 280-633956/3 8.0 10.85194 8.0 1008571.0 1.356493 Y
6 STD12 280-633956/8 12.0 16.221916 8.0 1042988.0 1.351826 Y
7 STD16 280-633956/9 16.0 21.5728 8.0 1033540.0 1.3483 Y
8 STD20 280-633956/10 20.0 27.63695 8.0 1006263.0 1.381847 Y
RelResp = [-0.2606] + [1.362]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Intercept = 0.191
Page 710 of 1261
Calibration / Fluoranthene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.09
Error Coefficients
Standard Error:1810000
Relative Standard Error:9.7
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.989
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.362519 8.0 967055.0 0.906298 Y
2 STD01 280-633956/5 1.0 0.981051 8.0 920189.0 0.981051 Y
3 STD02 280-633956/6 2.0 1.953237 8.0 998953.0 0.976619 N
4 STD05 280-633956/7 5.0 5.662425 8.0 989771.0 1.132485 Y
5 ICIS 280-633956/3 8.0 9.240853 8.0 1008571.0 1.155107 Y
6 STD12 280-633956/8 12.0 13.414168 8.0 1042988.0 1.117847 Y
7 STD16 280-633956/9 16.0 18.236686 8.0 1033540.0 1.139793 Y
8 STD20 280-633956/10 20.0 24.002298 8.0 1006263.0 1.200115 Y
RelResp = [1.09]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 711 of 1261
Calibration / Pyrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.622
Error Coefficients
Standard Error:1870000
Relative Standard Error:7.3
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.559091 8.0 669301.0 1.397727 Y
2 STD01 280-633956/5 1.0 1.519979 8.0 631435.0 1.519979 Y
3 STD02 280-633956/6 2.0 2.956718 8.0 695831.0 1.478359 N
4 STD05 280-633956/7 5.0 8.583751 8.0 696790.0 1.71675 Y
5 ICIS 280-633956/3 8.0 13.302128 8.0 731083.0 1.662766 Y
6 STD12 280-633956/8 12.0 20.173848 8.0 733997.0 1.681154 Y
7 STD16 280-633956/9 16.0 26.604935 8.0 737084.0 1.662808 Y
8 STD20 280-633956/10 20.0 34.235726 8.0 717927.0 1.711786 Y
RelResp = [1.622]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 712 of 1261
Calibration / Terphenyl-d14
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.169
Error Coefficients
Standard Error:1330000
Relative Standard Error:5.1
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.997
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.426582 8.0 669301.0 1.066456 Y
2 STD01 280-633956/5 1.0 1.124651 8.0 631435.0 1.124651 Y
3 STD02 280-633956/6 2.0 2.113076 8.0 695831.0 1.056538 N
4 STD05 280-633956/7 5.0 6.162385 8.0 696790.0 1.232477 Y
5 ICIS 280-633956/3 8.0 9.207425 8.0 731083.0 1.150928 Y
6 STD12 280-633956/8 12.0 14.304658 8.0 733997.0 1.192055 Y
7 STD16 280-633956/9 16.0 18.975878 8.0 737084.0 1.185992 Y
8 STD20 280-633956/10 20.0 24.554742 8.0 717927.0 1.227737 Y
RelResp = [1.169]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD16 280-633956/9
STD20 280-633956/10
Page 713 of 1261
Calibration / Butyl benzyl phthalate
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2386
Slope:0.7717
Error Coefficients
Standard Error:925000
Relative Standard Error:12.3
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.136357 8.0 669301.0 0.340893 Y
2 STD01 280-633956/5 1.0 0.412065 8.0 631435.0 0.412065 Y
3 STD02 280-633956/6 2.0 0.944827 8.0 695831.0 0.472414 N
4 STD05 280-633956/7 5.0 3.405881 8.0 696790.0 0.681176 Y
5 ICIS 280-633956/3 8.0 5.790762 8.0 731083.0 0.723845 Y
6 STD12 280-633956/8 12.0 8.945323 8.0 733997.0 0.745444 Y
7 STD16 280-633956/9 16.0 11.974722 8.0 737084.0 0.74842 Y
8 STD20 280-633956/10 20.0 15.821831 8.0 717927.0 0.791092 Y
RelResp = [-0.2386] + [0.7717]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 0.309
Page 714 of 1261
Calibration / Benzo[a]anthracene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.287
Error Coefficients
Standard Error:1520000
Relative Standard Error:9.5
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.990
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.428447 8.0 669301.0 1.071117 Y
2 STD01 280-633956/5 1.0 1.159809 8.0 631435.0 1.159809 Y
3 STD02 280-633956/6 2.0 2.197614 8.0 695831.0 1.098807 N
4 STD05 280-633956/7 5.0 6.705045 8.0 696790.0 1.341009 Y
5 ICIS 280-633956/3 8.0 10.683854 8.0 731083.0 1.335482 Y
6 STD12 280-633956/8 12.0 16.292121 8.0 733997.0 1.357677 Y
7 STD16 280-633956/9 16.0 21.404963 8.0 737084.0 1.33781 Y
8 STD20 280-633956/10 20.0 28.117889 8.0 717927.0 1.405894 Y
RelResp = [1.287]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD20 280-633956/10
Page 715 of 1261
Calibration / Chrysene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.442
Error Coefficients
Standard Error:1570000
Relative Standard Error:2.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.999
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.588734 8.0 669301.0 1.471834 Y
2 STD01 280-633956/5 1.0 1.452108 8.0 631435.0 1.452108 Y
3 STD02 280-633956/6 2.0 2.752496 8.0 695831.0 1.376248 N
4 STD05 280-633956/7 5.0 7.454332 8.0 696790.0 1.490866 Y
5 ICIS 280-633956/3 8.0 11.336989 8.0 731083.0 1.417124 Y
6 STD12 280-633956/8 12.0 17.239667 8.0 733997.0 1.436639 Y
7 STD16 280-633956/9 16.0 22.188711 8.0 737084.0 1.386794 Y
8 STD20 280-633956/10 20.0 28.784754 8.0 717927.0 1.439238 Y
RelResp = [1.442]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
Page 716 of 1261
Calibration / Bis(2-ethylhexyl) phthalate
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.386
Slope:0.7447
Error Coefficients
Standard Error:1390000
Relative Standard Error:3.8
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.128018 8.0 967055.0 0.320044 N
2 STD01 280-633956/5 1.0 0.364256 8.0 920189.0 0.364256 Y
3 STD02 280-633956/6 2.0 0.817144 8.0 998953.0 0.408572 N
4 STD05 280-633956/7 5.0 3.142068 8.0 989771.0 0.628414 Y
5 ICIS 280-633956/3 8.0 5.687437 8.0 1008571.0 0.71093 Y
6 STD12 280-633956/8 12.0 8.399682 8.0 1042988.0 0.699974 Y
7 STD16 280-633956/9 16.0 11.458421 8.0 1033540.0 0.716151 Y
8 STD20 280-633956/10 20.0 15.229172 8.0 1006263.0 0.761459 Y
RelResp = [-0.386] + [0.7447]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 0.518
Page 717 of 1261
Calibration / Di-n-octyl phthalate
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.5725
Slope:1.535
Error Coefficients
Standard Error:1840000
Relative Standard Error:18.7
Correlation Coefficient:0.996
Coefficient of Determination (Adjusted):0.994
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.237513 8.0 669301.0 0.593784 Y
2 STD01 280-633956/5 1.0 0.641409 8.0 631435.0 0.641409 Y
3 STD02 280-633956/6 2.0 1.405111 8.0 695831.0 0.702556 N
4 STD05 280-633956/7 5.0 5.929373 8.0 696790.0 1.185875 Y
5 ICIS 280-633956/3 8.0 12.010029 8.0 731083.0 1.501254 Y
6 STD12 280-633956/8 12.0 17.39909 8.0 733997.0 1.449924 Y
7 STD16 280-633956/9 16.0 23.542174 8.0 737084.0 1.471386 Y
8 STD20 280-633956/10 20.0 32.04172 8.0 717927.0 1.602086 Y
RelResp = [-0.5725] + [1.535]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 0.373
Page 718 of 1261
Calibration / Benzo[b]fluoranthene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2121
Slope:1.244
Error Coefficients
Standard Error:1370000
Relative Standard Error:4.4
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.298958 8.0 619324.0 0.747396 Y
2 STD01 280-633956/5 1.0 0.949839 8.0 602620.0 0.949839 Y
3 STD02 280-633956/6 2.0 1.90413 8.0 653947.0 0.952065 N
4 STD05 280-633956/7 5.0 5.915158 8.0 657784.0 1.183032 Y
5 ICIS 280-633956/3 8.0 9.595635 8.0 678185.0 1.199454 Y
6 STD12 280-633956/8 12.0 14.5892 8.0 674460.0 1.215767 Y
7 STD16 280-633956/9 16.0 19.969368 8.0 648480.0 1.248086 Y
8 STD20 280-633956/10 20.0 26.248333 8.0 636717.0 1.312417 Y
RelResp = [-0.2121] + [1.244]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.171
Page 719 of 1261
Calibration / Benzo[k]fluoranthene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2437
Slope:1.455
Error Coefficients
Standard Error:1600000
Relative Standard Error:4.8
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.998
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.358378 8.0 619324.0 0.895945 Y
2 STD01 280-633956/5 1.0 1.082274 8.0 602620.0 1.082274 Y
3 STD02 280-633956/6 2.0 2.382664 8.0 653947.0 1.191332 N
4 STD05 280-633956/7 5.0 7.053294 8.0 657784.0 1.410659 Y
5 ICIS 280-633956/3 8.0 11.314376 8.0 678185.0 1.414297 Y
6 STD12 280-633956/8 12.0 17.19312 8.0 674460.0 1.43276 Y
7 STD16 280-633956/9 16.0 23.395719 8.0 648480.0 1.462232 Y
8 STD20 280-633956/10 20.0 30.165917 8.0 636717.0 1.508296 Y
RelResp = [-0.2437] + [1.455]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.167
Page 720 of 1261
Calibration / Benzo[a]pyrene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2318
Slope:1.262
Error Coefficients
Standard Error:1410000
Relative Standard Error:6.6
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.291686 8.0 619324.0 0.729214 Y
2 STD01 280-633956/5 1.0 0.922903 8.0 602620.0 0.922903 Y
3 STD02 280-633956/6 2.0 1.830693 8.0 653947.0 0.915346 N
4 STD05 280-633956/7 5.0 5.777094 8.0 657784.0 1.155419 Y
5 ICIS 280-633956/3 8.0 9.605709 8.0 678185.0 1.200714 Y
6 STD12 280-633956/8 12.0 14.711787 8.0 674460.0 1.225982 Y
7 STD16 280-633956/9 16.0 21.04831 8.0 648480.0 1.315519 Y
8 STD20 280-633956/10 20.0 27.105028 8.0 636717.0 1.355251 Y
RelResp = [-0.2318] + [1.262]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.184
Page 721 of 1261
Calibration / Indeno[1,2,3-cd]pyrene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1599
Slope:0.8497
Error Coefficients
Standard Error:1050000
Relative Standard Error:6.3
Correlation Coefficient:0.998
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.193683 8.0 669301.0 0.484207 Y
2 STD01 280-633956/5 1.0 0.604743 8.0 631435.0 0.604743 Y
3 STD02 280-633956/6 2.0 1.137874 8.0 695831.0 0.568937 N
4 STD05 280-633956/7 5.0 3.91187 8.0 696790.0 0.782374 Y
5 ICIS 280-633956/3 8.0 6.909016 8.0 731083.0 0.863627 Y
6 STD12 280-633956/8 12.0 9.904084 8.0 733997.0 0.82534 Y
7 STD16 280-633956/9 16.0 13.52941 8.0 737084.0 0.845588 Y
8 STD20 280-633956/10 20.0 17.986341 8.0 717927.0 0.899317 Y
RelResp = [-0.1599] + [0.8497]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD20 280-633956/10
Intercept = 0.188
Page 722 of 1261
Calibration / Dibenz(a,h)anthracene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1898
Slope:1.012
Error Coefficients
Standard Error:1140000
Relative Standard Error:8.2
Correlation Coefficient:0.999
Coefficient of Determination (Adjusted):0.993
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.23454 8.0 619324.0 0.586349 Y
2 STD01 280-633956/5 1.0 0.708055 8.0 602620.0 0.708055 Y
3 STD02 280-633956/6 2.0 1.389605 8.0 653947.0 0.694802 N
4 STD05 280-633956/7 5.0 4.462742 8.0 657784.0 0.892548 Y
5 ICIS 280-633956/3 8.0 7.818232 8.0 678185.0 0.977279 Y
6 STD12 280-633956/8 12.0 12.091237 8.0 674460.0 1.007603 Y
7 STD16 280-633956/9 16.0 16.685912 8.0 648480.0 1.042869 Y
8 STD20 280-633956/10 20.0 22.097076 8.0 636717.0 1.104854 Y
RelResp = [-0.1898] + [1.012]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.188
Page 723 of 1261
Calibration / Benzo[g,h,i]perylene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.195
Slope:1.111
Error Coefficients
Standard Error:1230000
Relative Standard Error:6.2
Correlation Coefficient:1.000
Coefficient of Determination (Adjusted):0.996
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 STD004 280-633956/4 0.4 0.268473 8.0 619324.0 0.671183 Y
2 STD01 280-633956/5 1.0 0.797902 8.0 602620.0 0.797902 Y
3 STD02 280-633956/6 2.0 1.633148 8.0 653947.0 0.816574 N
4 STD05 280-633956/7 5.0 5.223429 8.0 657784.0 1.044686 Y
5 ICIS 280-633956/3 8.0 8.66494 8.0 678185.0 1.083117 Y
6 STD12 280-633956/8 12.0 13.09345 8.0 674460.0 1.091121 Y
7 STD16 280-633956/9 16.0 18.098384 8.0 648480.0 1.131149 Y
8 STD20 280-633956/10 20.0 23.498314 8.0 636717.0 1.174916 Y
RelResp = [-0.195] + [1.111]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
STD004 280-633956/4
STD01 280-633956/5
STD02 280-633956/6
STD05 280-633956/7
ICIS 280-633956/3
STD12 280-633956/8
STD16 280-633956/9
STD20 280-633956/10
Intercept = 0.175
Page 724 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 09:40
02/07/2023 11:04
02/07/2023 13:55
CCVIS 280-635266/3
Rxi-5Sil MS
Lab File ID:SMS_1-112823002.D Conc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Alpha Methyl Styrene 1.447 8000Ave
FORM VII 8270E
Page 725 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Lims ID:CCVIS HSL
Client ID:
Sample Type:CCVIS
Inject. Date:28-Nov-2023 09:40:41 ALS Bottle#:0 Worklist Smp#:3
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:CCVIS HSL
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:28-Nov-2023 11:18:58 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1646
First Level Reviewer: FP7E Date:28-Nov-2023 10:00:11
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.904 0.000 95 241434 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.072 0.000 99 901342 8.00 8.00
* 3 Acenaphthene-d10 164 6.760 6.760 0.000 95 460595 8.00 8.00
* 4 Phenanthrene-d10 188 8.209 8.209 0.000 97 789356 8.00 8.00
* 5 Chrysene-d12 240 10.945 10.945 0.000 99 568212 8.00 8.00
* 6 Perylene-d12 264 13.139 13.139 0.000 97 526696 8.00 8.00
$ 7 2-Fluorophenol 112 2.850 2.850 0.000 94 335016 8.00 8.08
$ 8 Phenol-d5 99 3.648 3.648 0.000 96 445061 8.00 8.35
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 393550 8.00 8.34
$ 10 2-Fluorobiphenyl 172 6.129 6.129 0.000 99 677779 8.00 8.23
$ 11 2,4,6-Tribromophenol 330 7.540 7.540 0.000 86 83811 8.00 7.17
$ 12 Terphenyl-d14 244 9.808 9.808 0.000 97 660228 8.00 7.95
15 1,4-Dioxane 88 1.549 1.549 0.000 87 159694 8.00 8.22
17 N-Nitrosodimethylamine 74 1.759 1.759 0.000 82 247879 8.00 8.73
18 Pyridine 79 1.784 1.784 0.000 75 770772 16.0 17.3
31 Aniline 93 3.623 3.623 0.000 93 432137 8.00 8.22
29 Phenol 94 3.660 3.660 0.000 92 507695 8.00 8.57
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 88 401770 8.00 8.17
34 2-Chlorophenol 128 3.737 3.737 0.000 91 366753 8.00 8.33
35 n-Decane 43 3.790 3.790 0.000 93 674120 8.00 9.09
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 94 406014 8.00 8.11
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 413235 8.00 8.10
43 1,2-Dichlorobenzene 146 4.052 4.052 0.000 94 391429 8.00 8.03
40 Benzyl alcohol 108 4.052 4.052 0.000 88 222936 8.00 7.47
46 Indene 116 4.132 4.132 0.000 90 1286661 16.0 16.7
47 2,2'-oxybis[1-chloropropane] 45 4.175 4.175 0.000 91 930445 8.00 8.74
45 2-Methylphenol 108 4.181 4.181 0.000 94 323079 8.00 8.41
52 Acetophenone 105 4.277 4.277 0.000 90 478870 8.00 7.96
54 N-Nitrosodi-n-propylamine 70 4.289 4.289 0.000 95 282688 8.00 8.22
51 4-Methylphenol 108 4.329 4.329 0.000 93 324542 8.00 7.97
Page 726 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.329 4.329 0.000 86 324542 8.00 7.97
50 3 & 4 Methylphenol 108 4.329 4.329 0.000 0 324542 8.00 7.97
56 Hexachloroethane 117 4.354 4.354 0.000 94 181046 8.00 8.35
58 Nitrobenzene 77 4.424 4.424 0.000 97 419843 8.00 8.54
60 Isophorone 82 4.656 4.656 0.000 95 674394 8.00 8.02
61 2-Nitrophenol 139 4.720 4.720 0.000 87 171262 8.00 7.45
62 2,4-Dimethylphenol 107 4.810 4.810 0.000 95 243848 8.00 8.43
66 Bis(2-chloroethoxy)methane 63 4.877 4.877 0.000 91 416907 8.00 8.24
69 Benzoic acid 105 4.967 4.967 0.000 88 368085 16.0 13.6
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 95 289222 8.00 8.26
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 311624 8.00 7.79
75 Naphthalene 128 5.090 5.090 0.000 97 1025479 8.00 8.05
77 4-Chloroaniline 127 5.164 5.164 0.000 94 398097 8.00 8.02
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 91 287973 8.00 8.17
80 Hexachlorobutadiene 225 5.226 5.226 0.000 96 166771 8.00 7.82
85 4-Chloro-3-methylphenol 107 5.679 5.679 0.000 93 280493 8.00 8.16
88 2-Methylnaphthalene 141 5.759 5.759 0.000 92 555026 8.00 8.00
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 608038 8.00 8.01
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 95 52089 8.00 6.90
90 1,2,4,5-Tetrachlorobenzene 216 5.919 5.919 0.000 98 298517 8.00 7.73
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 329527 8.00 8.27
93 2,4,6-Trichlorophenol 196 6.055 6.055 0.000 95 181410 8.00 8.22
95 2,4,5-Trichlorophenol 196 6.107 6.107 0.000 92 196516 8.00 7.94
97 1,1'-Biphenyl 154 6.218 6.218 0.000 97 785284 8.00 8.27
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 622510 8.00 8.22
101 2-Nitroaniline 65 6.344 6.344 0.000 78 213947 8.00 7.51
104 Dimethyl phthalate 163 6.545 6.545 0.000 97 637843 8.00 7.96
105 1,3-Dinitrobenzene 168 6.554 6.554 0.000 83 94078 8.00 7.21
106 2,6-Dinitrotoluene 165 6.588 6.588 0.000 85 144039 8.00 7.56
107 Acenaphthylene 152 6.622 6.622 0.000 99 923686 8.00 8.48
108 3-Nitroaniline 138 6.748 6.748 0.000 84 165926 8.00 7.44
109 Acenaphthene 153 6.794 6.794 0.000 96 610856 8.00 8.14
111 2,4-Dinitrophenol 184 6.856 6.856 0.000 74 110655 16.0 16.1
114 Dibenzofuran 168 6.964 6.964 0.000 96 835203 8.00 8.02
116 2,4-Dinitrotoluene 165 6.976 6.976 0.000 86 187689 8.00 7.40
113 4-Nitrophenol 109 7.001 7.001 0.000 83 151618 16.0 14.2
120 2,3,4,6-Tetrachlorophenol 232 7.108 7.108 0.000 78 131685 8.00 7.49
124 Diethyl phthalate 149 7.241 7.241 0.000 97 643472 8.00 7.85
122 Hexadecane 57 7.284 7.284 0.000 88 728242 8.00 8.90
127 Fluorene 166 7.300 7.300 0.000 94 657624 8.00 7.93
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 94 297217 8.00 7.68
130 4-Nitroaniline 138 7.346 7.346 0.000 80 159815 8.00 7.15
131 4,6-Dinitro-2-methylphenol 198 7.373 7.373 0.000 69 191387 16.0 14.7
132 Diphenylamine 169 7.441 7.441 0.000 91 455460 6.80 6.70
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 71 452586 8.00 8.22
135 Azobenzene 77 7.472 7.472 0.000 96 833097 8.00 8.56
136 1,2-Diphenylhydrazine 77 7.472 7.472 0.000 41 833097 8.09 8.65
145 4-Bromophenyl phenyl ether 248 7.796 7.796 0.000 76 165255 8.00 7.91
148 Hexachlorobenzene 284 7.830 7.830 0.000 92 190644 8.00 7.62
153 Pentachlorophenol 266 8.048 8.048 0.000 91 178834 16.0 15.5
154 n-Octadecane 57 8.196 8.196 0.000 89 704553 8.00 8.37
157 Phenanthrene 178 8.233 8.233 0.000 99 920179 8.00 8.10
Page 727 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.283 0.000 99 880737 8.00 8.15
161 Carbazole 167 8.461 8.461 0.000 96 866508 8.00 8.39
163 Alachlor 188 8.625 8.625 0.000 87 96718 8.00 7.38
164 Di-n-butyl phthalate 149 8.859 8.859 0.000 99 1001496 8.00 7.64
170 Fluoranthene 202 9.398 9.398 0.000 99 906235 8.00 8.42
172 Pyrene 202 9.614 9.614 0.000 96 940218 8.00 8.16
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 97 391849 8.00 7.46
184 Benzo[a]anthracene 228 10.936 10.936 0.000 100 756138 8.00 8.27
185 Chrysene 228 10.979 10.979 0.000 97 822342 8.00 8.03
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.121 0.000 95 512319 8.00 7.49
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 98 779448 8.00 7.52
191 Benzo[b]fluoranthene 252 12.513 12.513 0.000 98 666903 8.00 8.31
193 Benzo[k]fluoranthene 252 12.560 12.560 0.000 98 769401 8.00 8.20
194 Benzo[a]pyrene 252 13.040 13.040 0.000 82 639506 8.00 7.88
198 Indeno[1,2,3-cd]pyrene 276 15.025 15.025 0.000 98 481755 8.00 8.17
199 Dibenz(a,h)anthracene 278 15.099 15.099 0.000 95 512842 8.00 7.89
200 Benzo[g,h,i]perylene 276 15.478 15.478 0.000 95 593490 8.00 8.29
305 Alpha Methyl Styrene 1 0.000 ND ND
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-HSL-WS_00006 Amount Added: 20.00 Units: uL
MS-IS-RVE_00003 Amount Added: 25.00 Units: uL Run Reagent
Page 728 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Injection Date:28-Nov-2023 09:40:41 Instrument ID:SMS_1 Operator ID:MB
Lims ID:CCVIS HSL Worklist Smp#:3
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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Page 729 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 09:40
11/15/2023 07:12
11/15/2023 09:47
CCVIS 280-635266/3
Rxi-5Sil MS
Lab File ID:SMS_1-112823002.D Conc. Units:ug/mL
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
N-Nitrosodimethylamine 1.0270.9409 8.73 8.00 9.1 20.0Ave
Pyridine 1.5961.476 48.0 16.0 8.2 20.0Ave
Aniline 1.7901.742 8.22 8.00 2.8 20.0Ave
Phenol 2.1031.963 0.8000 8.57 8.00 7.1 20.0Ave
Bis(2-chloroethyl)ether 1.6641.629 0.7000 8.17 8.00 2.2 20.0Ave
2-Chlorophenol 1.5191.459 0.8000 8.33 8.00 4.1 20.0Ave
1,3-Dichlorobenzene 1.6821.659 8.11 8.00 1.4 20.0Ave
1,4-Dichlorobenzene 1.7121.690 8.10 8.00 1.3 20.0Ave
1,2-Dichlorobenzene 1.6211.615 8.03 8.00 0.4 20.0Ave
Benzyl alcohol 0.9234 7.47 8.00 -6.7 20.0Lin2
Indene 2.6652.549 16.7 16.0 4.5 20.0Ave
2,2'-oxybis[1-chloropropane]3.8543.527 0.0100 8.74 8.00 9.3 20.0Ave
2-Methylphenol 1.3381.274 0.7000 8.41 8.00 5.1 20.0Ave
Acetophenone 1.9831.993 0.0100 7.96 8.00 -0.5 20.0Ave
N-Nitrosodi-n-propylamine 1.1711.140 0.5000 8.22 8.00 2.8 20.0Ave
3 & 4 Methylphenol 1.3441.349 7.97 8.00 -0.3 20.0Ave
3-Methylphenol 1.3441.349 7.97 8.00 -0.3 20.0Ave
4-Methylphenol 1.3441.349 0.6000 7.97 8.00 -0.3 20.0Ave
Hexachloroethane 0.74990.7184 0.3000 8.35 8.00 4.4 20.0Ave
Nitrobenzene 0.46580.4366 0.2000 8.54 8.00 6.7 20.0Ave
Isophorone 0.74820.7463 0.4000 8.02 8.00 0.3 20.0Ave
2-Nitrophenol 0.1900 0.1000 7.45 8.00 -6.9 20.0Lin2
2,4-Dimethylphenol 0.27050.2568 0.2000 8.43 8.00 5.4 20.0Ave
Bis(2-chloroethoxy)methane 0.46250.4488 0.3000 8.24 8.00 3.1 20.0Ave
Benzoic acid 0.2042 48.0 16.0 -14.8 20.0Lin2
2,4-Dichlorophenol 0.32090.3110 0.2000 8.26 8.00 3.2 20.0Ave
1,2,4-Trichlorobenzene 0.34570.3550 7.79 8.00 -2.6 20.0Ave
Naphthalene 1.1381.130 0.7000 8.05 8.00 0.7 20.0Ave
4-Chloroaniline 0.44170.4407 0.0100 8.02 8.00 0.2 20.0Ave
2,6-Dichlorophenol 0.31950.3129 8.17 8.00 2.1 20.0Ave
Hexachlorobutadiene 0.18500.1892 0.0100 7.82 8.00 -2.2 20.0Ave
4-Chloro-3-methylphenol 0.31120.3051 0.2000 8.16 8.00 2.0 20.0Ave
2-Methylnaphthalene 0.61580.6156 0.4000 8.00 8.00 0.0 20.0Ave
1-Methylnaphthalene 0.67460.6737 8.01 8.00 0.1 20.0Ave
1,2,4,5-Tetrachlorobenzene 0.33120.3428 0.0100 7.73 8.00 -3.4 20.0Ave
Hexachlorocyclopentadiene 0.1131 0.0500 48.0 8.00 -13.7 20.0Lin2
2,4,6-Trichlorophenol 0.39390.3834 0.2000 8.22 8.00 2.7 20.0Ave
2,4,5-Trichlorophenol 0.4267 0.2000 7.94 8.00 -0.7 20.0Lin2
1,1'-Biphenyl 1.7051.650 0.0100 8.27 8.00 3.3 20.0Ave
2-Chloronaphthalene 1.3521.315 0.8000 8.22 8.00 2.8 20.0Ave
2-Nitroaniline 0.4645 0.0100 7.51 8.00 -6.1 20.0Lin2
FORM VII 8270E
Page 730 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 09:40
11/15/2023 07:12
11/15/2023 09:47
CCVIS 280-635266/3
Rxi-5Sil MS
Lab File ID:SMS_1-112823002.D Conc. Units:ug/mL
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dimethyl phthalate 1.3851.391 0.0100 7.96 8.00 -0.5 20.0Ave
1,3-Dinitrobenzene 0.2043 7.21 8.00 -9.9 20.0Lin2
2,6-Dinitrotoluene 0.3127 0.2000 7.56 8.00 -5.5 20.0Lin2
Acenaphthylene 2.0051.892 0.9000 8.48 8.00 6.0 20.0Ave
3-Nitroaniline 0.3602 0.0100 7.44 8.00 -7.0 20.0Lin2
Acenaphthene 1.3261.303 0.9000 8.14 8.00 1.8 20.0Ave
2,4-Dinitrophenol 0.1201 0.0100 16.1 16.0 0.5 20.0Qua
Dibenzofuran 1.8131.810 0.8000 8.02 8.00 0.2 20.0Ave
2,4-Dinitrotoluene 0.4075 0.2000 7.40 8.00 -7.5 20.0Lin2
4-Nitrophenol 0.1646 0.0100 14.2 16.0 -11.2 20.0Lin1
2,3,4,6-Tetrachlorophenol 0.2859 0.0100 7.49 8.00 -6.4 20.0Lin2
Diethyl phthalate 1.3971.424 0.0100 7.85 8.00 -1.9 20.0Ave
Hexadecane 1.5811.422 8.90 8.00 11.2 20.0Ave
Fluorene 1.4281.440 0.9000 7.93 8.00 -0.8 20.0Ave
4-Chlorophenyl phenyl ether 0.64530.6724 0.4000 7.68 8.00 -4.0 20.0Ave
4-Nitroaniline 0.3470 0.0100 7.15 8.00 -10.6 20.0Lin2
4,6-Dinitro-2-methylphenol 0.1212 0.0100 14.7 16.0 -8.2 20.0Lin2
Diphenylamine 1.1631.181 6.70 6.80 -1.5 20.0Ave
N-Nitrosodiphenylamine 0.57340.5577 0.0100 8.22 8.00 2.8 20.0Ave
1,2-Diphenylhydrazine 1.7891.673 8.65 8.09 6.9 20.0Ave
Azobenzene 1.8091.691 8.56 8.00 6.9 20.0Ave
4-Bromophenyl phenyl ether 0.20940.2118 0.1000 7.91 8.00 -1.1 20.0Ave
Hexachlorobenzene 0.24150.2535 0.1000 7.62 8.00 -4.7 20.0Ave
Pentachlorophenol 0.1133 0.0500 48.0 16.0 -3.2 20.0Lin2
Phenanthrene 1.1661.151 0.7000 8.10 8.00 1.3 20.0Ave
Anthracene 1.1161.095 0.7000 8.15 8.00 1.9 20.0Ave
Carbazole 1.0981.046 0.0100 8.39 8.00 4.9 20.0Ave
Di-n-butyl phthalate 1.269 0.0100 7.64 8.00 -4.5 20.0Lin2
Fluoranthene 1.1481.090 0.6000 8.42 8.00 5.3 20.0Ave
Pyrene 1.6551.622 0.6000 8.16 8.00 2.0 20.0Ave
Butyl benzyl phthalate 0.6896 0.0100 7.46 8.00 -6.8 20.0Lin1
Benzo[a]anthracene 1.3311.287 0.8000 8.27 8.00 3.4 20.0Ave
Chrysene 1.4471.442 0.7000 8.03 8.00 0.4 20.0Ave
Bis(2-ethylhexyl) phthalate 0.6490 0.0100 7.49 8.00 -6.4 20.0Lin2
Di-n-octyl phthalate 1.372 0.0100 7.52 8.00 -6.0 20.0Lin1
Benzo[b]fluoranthene 1.266 0.7000 8.31 8.00 3.9 20.0Lin2
Benzo[k]fluoranthene 1.461 0.7000 8.20 8.00 2.5 20.0Lin2
Benzo[a]pyrene 1.214 0.7000 7.88 8.00 -1.5 20.0Lin2
Indeno[1,2,3-cd]pyrene 0.8478 0.5000 8.17 8.00 2.1 20.0Lin2
Dibenz(a,h)anthracene 0.9737 0.4000 7.89 8.00 -1.4 20.0Lin2
Benzo[g,h,i]perylene 1.127 0.5000 8.29 8.00 3.6 20.0Lin2
FORM VII 8270E
Page 731 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 09:40
11/15/2023 07:12
11/15/2023 09:47
CCVIS 280-635266/3
Rxi-5Sil MS
Lab File ID:SMS_1-112823002.D Conc. Units:ug/mL
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Fluorophenol (Surr)1.388 8.08 8.00 1.0 20.0Lin2
Phenol-d5 (Surr)1.8431.767 8.35 8.00 4.3 20.0Ave
Nitrobenzene-d5 (Surr)0.43660.4187 8.34 8.00 4.3 20.0Ave
2-Fluorobiphenyl 1.4721.430 8.23 8.00 2.9 20.0Ave
2,4,6-Tribromophenol (Surr)0.1820 7.17 8.00 -10.4 20.0Lin2
Terphenyl-d14 (Surr)1.1621.169 7.95 8.00 -0.6 20.0Ave
FORM VII 8270E
Page 732 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Lims ID:CCVIS HSL
Client ID:
Sample Type:CCVIS
Inject. Date:28-Nov-2023 09:40:41 ALS Bottle#:0 Worklist Smp#:3
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:CCVIS HSL
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub40
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:28-Nov-2023 11:18:58 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1646
First Level Reviewer: FP7E Date:28-Nov-2023 10:00:11
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.904 0.000 95 241434 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.072 0.000 99 901342 8.00 8.00
* 3 Acenaphthene-d10 164 6.760 6.760 0.000 95 460595 8.00 8.00
* 4 Phenanthrene-d10 188 8.209 8.209 0.000 97 789356 8.00 8.00
* 5 Chrysene-d12 240 10.945 10.945 0.000 99 568212 8.00 8.00
* 6 Perylene-d12 264 13.139 13.139 0.000 97 526696 8.00 8.00
$ 7 2-Fluorophenol 112 2.850 2.850 0.000 94 335016 8.00 8.08
$ 8 Phenol-d5 99 3.648 3.648 0.000 96 445061 8.00 8.35
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 393550 8.00 8.34
$ 10 2-Fluorobiphenyl 172 6.129 6.129 0.000 99 677779 8.00 8.23
$ 11 2,4,6-Tribromophenol 330 7.540 7.540 0.000 86 83811 8.00 7.17
$ 12 Terphenyl-d14 244 9.808 9.808 0.000 97 660228 8.00 7.95
15 1,4-Dioxane 88 1.549 1.549 0.000 87 159694 8.00 8.22
17 N-Nitrosodimethylamine 74 1.759 1.759 0.000 82 247879 8.00 8.73
18 Pyridine 79 1.784 1.784 0.000 75 770772 16.0 17.3
31 Aniline 93 3.623 3.623 0.000 93 432137 8.00 8.22
29 Phenol 94 3.660 3.660 0.000 92 507695 8.00 8.57
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 88 401770 8.00 8.17
34 2-Chlorophenol 128 3.737 3.737 0.000 91 366753 8.00 8.33
35 n-Decane 43 3.790 3.790 0.000 93 674120 8.00 9.09
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 94 406014 8.00 8.11
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 413235 8.00 8.10
43 1,2-Dichlorobenzene 146 4.052 4.052 0.000 94 391429 8.00 8.03
40 Benzyl alcohol 108 4.052 4.052 0.000 88 222936 8.00 7.47
46 Indene 116 4.132 4.132 0.000 90 1286661 16.0 16.7
47 2,2'-oxybis[1-chloropropane] 45 4.175 4.175 0.000 91 930445 8.00 8.74
45 2-Methylphenol 108 4.181 4.181 0.000 94 323079 8.00 8.41
52 Acetophenone 105 4.277 4.277 0.000 90 478870 8.00 7.96
54 N-Nitrosodi-n-propylamine 70 4.289 4.289 0.000 95 282688 8.00 8.22
51 4-Methylphenol 108 4.329 4.329 0.000 93 324542 8.00 7.97
Page 733 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.329 4.329 0.000 86 324542 8.00 7.97
50 3 & 4 Methylphenol 108 4.329 4.329 0.000 0 324542 8.00 7.97
56 Hexachloroethane 117 4.354 4.354 0.000 94 181046 8.00 8.35
58 Nitrobenzene 77 4.424 4.424 0.000 97 419843 8.00 8.54
60 Isophorone 82 4.656 4.656 0.000 95 674394 8.00 8.02
61 2-Nitrophenol 139 4.720 4.720 0.000 87 171262 8.00 7.45
62 2,4-Dimethylphenol 107 4.810 4.810 0.000 95 243848 8.00 8.43
66 Bis(2-chloroethoxy)methane 63 4.877 4.877 0.000 91 416907 8.00 8.24
69 Benzoic acid 105 4.967 4.967 0.000 88 368085 16.0 13.6
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 95 289222 8.00 8.26
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 311624 8.00 7.79
75 Naphthalene 128 5.090 5.090 0.000 97 1025479 8.00 8.05
77 4-Chloroaniline 127 5.164 5.164 0.000 94 398097 8.00 8.02
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 91 287973 8.00 8.17
80 Hexachlorobutadiene 225 5.226 5.226 0.000 96 166771 8.00 7.82
85 4-Chloro-3-methylphenol 107 5.679 5.679 0.000 93 280493 8.00 8.16
88 2-Methylnaphthalene 141 5.759 5.759 0.000 92 555026 8.00 8.00
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 608038 8.00 8.01
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 95 52089 8.00 6.90
90 1,2,4,5-Tetrachlorobenzene 216 5.919 5.919 0.000 98 298517 8.00 7.73
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 329527 8.00 8.27
93 2,4,6-Trichlorophenol 196 6.055 6.055 0.000 95 181410 8.00 8.22
95 2,4,5-Trichlorophenol 196 6.107 6.107 0.000 92 196516 8.00 7.94
97 1,1'-Biphenyl 154 6.218 6.218 0.000 97 785284 8.00 8.27
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 622510 8.00 8.22
101 2-Nitroaniline 65 6.344 6.344 0.000 78 213947 8.00 7.51
104 Dimethyl phthalate 163 6.545 6.545 0.000 97 637843 8.00 7.96
105 1,3-Dinitrobenzene 168 6.554 6.554 0.000 83 94078 8.00 7.21
106 2,6-Dinitrotoluene 165 6.588 6.588 0.000 85 144039 8.00 7.56
107 Acenaphthylene 152 6.622 6.622 0.000 99 923686 8.00 8.48
108 3-Nitroaniline 138 6.748 6.748 0.000 84 165926 8.00 7.44
109 Acenaphthene 153 6.794 6.794 0.000 96 610856 8.00 8.14
111 2,4-Dinitrophenol 184 6.856 6.856 0.000 74 110655 16.0 16.1
114 Dibenzofuran 168 6.964 6.964 0.000 96 835203 8.00 8.02
116 2,4-Dinitrotoluene 165 6.976 6.976 0.000 86 187689 8.00 7.40
113 4-Nitrophenol 109 7.001 7.001 0.000 83 151618 16.0 14.2
120 2,3,4,6-Tetrachlorophenol 232 7.108 7.108 0.000 78 131685 8.00 7.49
124 Diethyl phthalate 149 7.241 7.241 0.000 97 643472 8.00 7.85
122 Hexadecane 57 7.284 7.284 0.000 88 728242 8.00 8.90
127 Fluorene 166 7.300 7.300 0.000 94 657624 8.00 7.93
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 94 297217 8.00 7.68
130 4-Nitroaniline 138 7.346 7.346 0.000 80 159815 8.00 7.15
131 4,6-Dinitro-2-methylphenol 198 7.373 7.373 0.000 69 191387 16.0 14.7
132 Diphenylamine 169 7.441 7.441 0.000 91 455460 6.80 6.70
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 71 452586 8.00 8.22
135 Azobenzene 77 7.472 7.472 0.000 96 833097 8.00 8.56
136 1,2-Diphenylhydrazine 77 7.472 7.472 0.000 41 833097 8.09 8.65
145 4-Bromophenyl phenyl ether 248 7.796 7.796 0.000 76 165255 8.00 7.91
148 Hexachlorobenzene 284 7.830 7.830 0.000 92 190644 8.00 7.62
153 Pentachlorophenol 266 8.048 8.048 0.000 91 178834 16.0 15.5
154 n-Octadecane 57 8.196 8.196 0.000 89 704553 8.00 8.37
157 Phenanthrene 178 8.233 8.233 0.000 99 920179 8.00 8.10
Page 734 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.283 0.000 99 880737 8.00 8.15
161 Carbazole 167 8.461 8.461 0.000 96 866508 8.00 8.39
163 Alachlor 188 8.625 8.625 0.000 87 96718 8.00 7.38
164 Di-n-butyl phthalate 149 8.859 8.859 0.000 99 1001496 8.00 7.64
170 Fluoranthene 202 9.398 9.398 0.000 99 906235 8.00 8.42
172 Pyrene 202 9.614 9.614 0.000 96 940218 8.00 8.16
180 Butyl benzyl phthalate 149 10.353 10.353 0.000 97 391849 8.00 7.46
184 Benzo[a]anthracene 228 10.936 10.936 0.000 100 756138 8.00 8.27
185 Chrysene 228 10.979 10.979 0.000 97 822342 8.00 8.03
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.121 0.000 95 512319 8.00 7.49
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 98 779448 8.00 7.52
191 Benzo[b]fluoranthene 252 12.513 12.513 0.000 98 666903 8.00 8.31
193 Benzo[k]fluoranthene 252 12.560 12.560 0.000 98 769401 8.00 8.20
194 Benzo[a]pyrene 252 13.040 13.040 0.000 82 639506 8.00 7.88
198 Indeno[1,2,3-cd]pyrene 276 15.025 15.025 0.000 98 481755 8.00 8.17
199 Dibenz(a,h)anthracene 278 15.099 15.099 0.000 95 512842 8.00 7.89
200 Benzo[g,h,i]perylene 276 15.478 15.478 0.000 95 593490 8.00 8.29
305 Alpha Methyl Styrene 1 0.000 ND ND
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-HSL-WS_00006 Amount Added: 20.00 Units: uL
MS-IS-RVE_00003 Amount Added: 25.00 Units: uL Run Reagent
Page 735 of 1261
Report Date: 28-Nov-2023 11:18:59 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823002.D
Injection Date:28-Nov-2023 09:40:41 Instrument ID:SMS_1 Operator ID:MB
Lims ID:CCVIS HSL Worklist Smp#:3
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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Page 736 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 13:48
02/07/2023 11:04
02/07/2023 13:55
CCVC 280-635266/17
Rxi-5Sil MS
Lab File ID:SMS_1-112823013.D Conc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Alpha Methyl Styrene 1.447 8000Ave
FORM VII 8270E
Page 737 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Lims ID:CCVC HSL
Client ID:
Sample Type:CCVC
Inject. Date:28-Nov-2023 13:48:10 ALS Bottle#:0 Worklist Smp#:17
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:CCVC HSL
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub29
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:29-Nov-2023 10:12:46 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1689
First Level Reviewer: FP7E Date:28-Nov-2023 16:25:51
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.904 0.000 95 253176 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.072 0.000 99 911231 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.760 0.003 95 472426 8.00 8.00
* 4 Phenanthrene-d10 188 8.209 8.209 0.000 97 803603 8.00 8.00
* 5 Chrysene-d12 240 10.945 10.945 0.000 98 580998 8.00 8.00
* 6 Perylene-d12 264 13.136 13.139 -0.003 97 568583 8.00 8.00
$ 7 2-Fluorophenol 112 2.850 2.850 0.000 93 343301 8.00 7.90
$ 8 Phenol-d5 99 3.648 3.648 0.000 96 451015 8.00 8.06
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 403647 8.00 8.46
$ 10 2-Fluorobiphenyl 172 6.129 6.129 0.000 100 683590 8.00 8.09
$ 11 2,4,6-Tribromophenol 330 7.540 7.540 0.000 89 88545 8.00 7.37
$ 12 Terphenyl-d14 244 9.808 9.808 0.000 97 659711 8.00 7.77
15 1,4-Dioxane 88 1.546 1.549 -0.003 90 158380 8.00 7.78
17 N-Nitrosodimethylamine 74 1.756 1.759 -0.003 86 241508 8.00 8.11
18 Pyridine 79 1.784 1.784 0.000 78 738445 16.0 15.8
31 Aniline 93 3.623 3.623 0.000 93 440615 8.00 7.99
29 Phenol 94 3.660 3.660 0.000 92 510188 8.00 8.21
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 90 400371 8.00 7.77
34 2-Chlorophenol 128 3.737 3.737 0.000 93 378878 8.00 8.20
35 n-Decane 43 3.790 3.790 0.000 92 600170 8.00 7.72
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 96 422166 8.00 8.04
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 420102 8.00 7.86
43 1,2-Dichlorobenzene 146 4.052 4.052 0.000 94 402100 8.00 7.87
40 Benzyl alcohol 108 4.052 4.052 0.000 89 236929 8.00 7.56
46 Indene 116 4.132 4.132 0.000 90 1297027 16.0 16.1
47 2,2'-oxybis[1-chloropropane] 45 4.172 4.175 -0.003 92 834593 8.00 7.48
45 2-Methylphenol 108 4.184 4.181 0.003 94 330739 8.00 8.21
52 Acetophenone 105 4.277 4.277 0.000 91 499617 8.00 7.92
54 N-Nitrosodi-n-propylamine 70 4.289 4.289 0.000 94 283209 8.00 7.85
51 4-Methylphenol 108 4.332 4.329 0.003 92 347754 8.00 8.15
Page 738 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.329 0.003 86 347754 8.00 8.15
50 3 & 4 Methylphenol 108 4.332 4.329 0.003 0 347754 8.00 8.15
56 Hexachloroethane 117 4.357 4.354 0.003 96 184052 8.00 8.10
58 Nitrobenzene 77 4.425 4.424 0.001 95 415629 8.00 8.36
60 Isophorone 82 4.656 4.656 0.000 96 705842 8.00 8.30
61 2-Nitrophenol 139 4.720 4.720 0.000 89 186268 8.00 8.00
62 2,4-Dimethylphenol 107 4.810 4.810 0.000 95 248858 8.00 8.51
66 Bis(2-chloroethoxy)methane 63 4.878 4.877 0.001 91 406031 8.00 7.94
69 Benzoic acid 105 4.964 4.933 -0.003 91 376957 16.0 13.8
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 96 288999 8.00 8.16
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 325028 8.00 8.04
75 Naphthalene 128 5.090 5.090 0.000 98 1041023 8.00 8.09
77 4-Chloroaniline 127 5.164 5.152 0.000 94 412119 8.00 8.21
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 92 295489 8.00 8.29
80 Hexachlorobutadiene 225 5.226 5.226 0.000 97 181314 8.00 8.41
85 4-Chloro-3-methylphenol 107 5.682 5.679 0.003 94 290312 8.00 8.35
88 2-Methylnaphthalene 141 5.759 5.759 0.000 92 565404 8.00 8.06
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 615132 8.00 8.02
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 96 53861 8.00 6.94
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.919 0.003 98 316283 8.00 8.10
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 340284 8.00 8.33
93 2,4,6-Trichlorophenol 196 6.055 6.055 0.000 93 190389 8.00 8.41
95 2,4,5-Trichlorophenol 196 6.107 6.107 0.000 93 202166 8.00 7.97
97 1,1'-Biphenyl 154 6.221 6.218 0.003 97 794715 8.00 8.15
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 634876 8.00 8.18
101 2-Nitroaniline 65 6.344 6.344 0.000 79 228738 8.00 7.82
104 Dimethyl phthalate 163 6.545 6.545 0.000 98 649707 8.00 7.91
105 1,3-Dinitrobenzene 168 6.554 6.554 0.000 84 104002 8.00 7.75
106 2,6-Dinitrotoluene 165 6.591 6.588 0.003 88 152800 8.00 7.81
107 Acenaphthylene 152 6.622 6.622 0.000 99 941958 8.00 8.43
108 3-Nitroaniline 138 6.751 6.748 0.003 85 179437 8.00 7.84
109 Acenaphthene 153 6.794 6.794 0.000 96 619768 8.00 8.05
111 2,4-Dinitrophenol 184 6.859 6.856 0.003 78 98433 16.0 14.5
114 Dibenzofuran 168 6.967 6.964 0.003 96 854509 8.00 8.00
116 2,4-Dinitrotoluene 165 6.979 6.976 0.003 89 199561 8.00 7.66
113 4-Nitrophenol 109 7.004 7.001 0.003 84 146419 16.0 13.4
120 2,3,4,6-Tetrachlorophenol 232 7.109 7.108 0.001 76 137010 8.00 7.59
124 Diethyl phthalate 149 7.244 7.241 0.003 97 671085 8.00 7.98
122 Hexadecane 57 7.284 7.284 0.000 87 671508 8.00 8.00
127 Fluorene 166 7.300 7.300 0.000 93 673421 8.00 7.92
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 95 309461 8.00 7.79
130 4-Nitroaniline 138 7.346 7.346 0.000 80 176439 8.00 7.69
131 4,6-Dinitro-2-methylphenol 198 7.374 7.373 0.001 72 196845 16.0 14.8
132 Diphenylamine 169 7.441 7.441 0.000 92 464353 6.80 6.66
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 64 464353 8.00 8.29
135 Azobenzene 77 7.475 7.472 0.003 97 809635 8.00 8.11
136 1,2-Diphenylhydrazine 77 7.475 7.472 0.003 41 809635 8.09 8.20
145 4-Bromophenyl phenyl ether 248 7.796 7.796 0.000 74 175440 8.00 8.25
148 Hexachlorobenzene 284 7.830 7.830 0.000 92 197864 8.00 7.77
153 Pentachlorophenol 266 8.052 8.048 0.004 90 184156 16.0 15.6
154 n-Octadecane 57 8.196 8.196 0.000 89 654728 8.00 7.65
157 Phenanthrene 178 8.233 8.233 0.000 98 922601 8.00 7.98
Page 739 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.283 0.001 98 926435 8.00 8.42
161 Carbazole 167 8.461 8.461 0.000 96 868492 8.00 8.26
163 Alachlor 188 8.625 8.625 0.000 89 107457 8.00 8.05
164 Di-n-butyl phthalate 149 8.859 8.859 0.000 99 1052055 8.00 7.88
170 Fluoranthene 202 9.398 9.398 0.000 99 926850 8.00 8.46
172 Pyrene 202 9.614 9.614 0.000 97 963707 8.00 8.18
180 Butyl benzyl phthalate 149 10.350 10.353 -0.003 98 418890 8.00 7.78
184 Benzo[a]anthracene 228 10.933 10.936 -0.003 100 800940 8.00 8.57
185 Chrysene 228 10.979 10.979 0.000 97 850061 8.00 8.12
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.111 0.000 96 559097 8.00 7.99
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 99 815831 8.00 7.69
191 Benzo[b]fluoranthene 252 12.513 12.510 0.000 98 686259 8.00 7.93
193 Benzo[k]fluoranthene 252 12.557 12.557 -0.003 99 798929 8.00 7.89
194 Benzo[a]pyrene 252 13.037 13.037 -0.003 79 714154 8.00 8.14
198 Indeno[1,2,3-cd]pyrene 276 15.025 15.025 0.000 97 505984 8.00 8.39
199 Dibenz(a,h)anthracene 278 15.093 15.095 -0.006 95 547644 8.00 7.80
200 Benzo[g,h,i]perylene 276 15.472 15.474 -0.006 96 614554 8.00 7.96
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 16.4
S 212 Methyl Phenols,Total 108 0 16.4
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-HSL-WS_00005 Amount Added: 20.00 Units: uL
MS-IS-RVE_00003 Amount Added: 25.00 Units: uL Run Reagent
Page 740 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Injection Date:28-Nov-2023 13:48:10 Instrument ID:SMS_1 Operator ID:MB
Lims ID:CCVC HSL Worklist Smp#:17
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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Page 741 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 13:48
11/15/2023 07:12
11/15/2023 09:47
CCVC 280-635266/17
Rxi-5Sil MS
Lab File ID:SMS_1-112823013.D Conc. Units:ug/mL
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
N-Nitrosodimethylamine 0.95390.9409 8.11 8.00 1.4 50.0Ave
Pyridine 1.4581.476 48.0 16.0 -1.2 50.0Ave
Aniline 1.7401.742 7.99 8.00 -0.0 50.0Ave
Phenol 2.0151.963 0.8000 8.21 8.00 2.7 50.0Ave
Bis(2-chloroethyl)ether 1.5811.629 0.7000 7.77 8.00 -2.9 50.0Ave
2-Chlorophenol 1.4971.459 0.8000 8.20 8.00 2.6 50.0Ave
1,3-Dichlorobenzene 1.6671.659 8.04 8.00 0.5 50.0Ave
1,4-Dichlorobenzene 1.6591.690 7.86 8.00 -1.8 50.0Ave
1,2-Dichlorobenzene 1.5881.615 7.87 8.00 -1.7 50.0Ave
Benzyl alcohol 0.9358 7.56 8.00 -5.4 50.0Lin2
Indene 2.5622.549 16.1 16.0 0.5 50.0Ave
2,2'-oxybis[1-chloropropane]3.2963.527 0.0100 7.48 8.00 -6.5 50.0Ave
2-Methylphenol 1.3061.274 0.7000 8.21 8.00 2.6 50.0Ave
Acetophenone 1.9731.993 0.0100 7.92 8.00 -1.0 50.0Ave
N-Nitrosodi-n-propylamine 1.1191.140 0.5000 7.85 8.00 -1.8 50.0Ave
3 & 4 Methylphenol 1.3741.349 8.15 8.00 1.8 50.0Ave
3-Methylphenol 1.3741.349 8.15 8.00 1.8 50.0Ave
4-Methylphenol 1.3741.349 0.6000 8.15 8.00 1.8 50.0Ave
Hexachloroethane 0.72700.7184 0.3000 8.10 8.00 1.2 50.0Ave
Nitrobenzene 0.45610.4366 0.2000 8.36 8.00 4.5 50.0Ave
Isophorone 0.77460.7463 0.4000 8.30 8.00 3.8 50.0Ave
2-Nitrophenol 0.2044 0.1000 8.00 8.00 0.0 50.0Lin2
2,4-Dimethylphenol 0.27310.2568 0.2000 8.51 8.00 6.4 50.0Ave
Bis(2-chloroethoxy)methane 0.44560.4488 0.3000 7.94 8.00 -0.7 50.0Ave
Benzoic acid 0.2068 48.0 16.0 -13.8 50.0Lin2
2,4-Dichlorophenol 0.31720.3110 0.2000 8.16 8.00 2.0 50.0Ave
1,2,4-Trichlorobenzene 0.35670.3550 8.04 8.00 0.5 50.0Ave
Naphthalene 1.1421.130 0.7000 8.09 8.00 1.1 50.0Ave
4-Chloroaniline 0.45230.4407 0.0100 8.21 8.00 2.6 50.0Ave
2,6-Dichlorophenol 0.32430.3129 8.29 8.00 3.6 50.0Ave
Hexachlorobutadiene 0.19900.1892 0.0100 8.41 8.00 5.1 50.0Ave
4-Chloro-3-methylphenol 0.31860.3051 0.2000 8.35 8.00 4.4 50.0Ave
2-Methylnaphthalene 0.62050.6156 0.4000 8.06 8.00 0.8 50.0Ave
1-Methylnaphthalene 0.67510.6737 8.02 8.00 0.2 50.0Ave
Hexachlorocyclopentadiene 0.1140 0.0500 48.0 8.00 -13.3 50.0Lin2
1,2,4,5-Tetrachlorobenzene 0.34710.3428 0.0100 8.10 8.00 1.3 50.0Ave
2,4,6-Trichlorophenol 0.40300.3834 0.2000 8.41 8.00 5.1 50.0Ave
2,4,5-Trichlorophenol 0.4279 0.2000 7.97 8.00 -0.4 50.0Lin2
1,1'-Biphenyl 1.6821.650 0.0100 8.15 8.00 1.9 50.0Ave
2-Chloronaphthalene 1.3441.315 0.8000 8.18 8.00 2.2 50.0Ave
2-Nitroaniline 0.4842 0.0100 7.82 8.00 -2.2 50.0Lin2
FORM VII 8270E
Page 742 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 13:48
11/15/2023 07:12
11/15/2023 09:47
CCVC 280-635266/17
Rxi-5Sil MS
Lab File ID:SMS_1-112823013.D Conc. Units:ug/mL
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dimethyl phthalate 1.3751.391 0.0100 7.91 8.00 -1.1 50.0Ave
1,3-Dinitrobenzene 0.2201 7.75 8.00 -3.1 50.0Lin2
2,6-Dinitrotoluene 0.3234 0.2000 7.81 8.00 -2.4 50.0Lin2
Acenaphthylene 1.9941.892 0.9000 8.43 8.00 5.4 50.0Ave
3-Nitroaniline 0.3798 0.0100 7.84 8.00 -2.0 50.0Lin2
Acenaphthene 1.3121.303 0.9000 8.05 8.00 0.7 50.0Ave
2,4-Dinitrophenol 0.1042 0.0100 14.5 16.0 -9.4 50.0Qua
Dibenzofuran 1.8091.810 0.8000 8.00 8.00 -0.0 50.0Ave
2,4-Dinitrotoluene 0.4224 0.2000 7.66 8.00 -4.2 50.0Lin2
4-Nitrophenol 0.1550 0.0100 13.4 16.0 -16.1 50.0Lin1
2,3,4,6-Tetrachlorophenol 0.2900 0.0100 7.59 8.00 -5.1 50.0Lin2
Diethyl phthalate 1.4211.424 0.0100 7.98 8.00 -0.2 50.0Ave
Hexadecane 1.4211.422 8.00 8.00 -0.0 50.0Ave
Fluorene 1.4251.440 0.9000 7.92 8.00 -1.0 50.0Ave
4-Chlorophenyl phenyl ether 0.65500.6724 0.4000 7.79 8.00 -2.6 50.0Ave
4-Nitroaniline 0.3735 0.0100 7.69 8.00 -3.9 50.0Lin2
4,6-Dinitro-2-methylphenol 0.1225 0.0100 14.8 16.0 -7.3 50.0Lin2
Diphenylamine 1.1561.181 6.66 6.80 -2.1 50.0Ave
N-Nitrosodiphenylamine 0.57780.5577 0.0100 8.29 8.00 3.6 50.0Ave
1,2-Diphenylhydrazine 1.6951.673 8.20 8.09 1.3 50.0Ave
Azobenzene 1.7141.691 8.11 8.00 1.3 50.0Ave
4-Bromophenyl phenyl ether 0.21830.2118 0.1000 8.25 8.00 3.1 50.0Ave
Hexachlorobenzene 0.24620.2535 0.1000 7.77 8.00 -2.9 50.0Ave
Pentachlorophenol 0.1146 0.0500 48.0 16.0 -2.3 50.0Lin2
Phenanthrene 1.1481.151 0.7000 7.98 8.00 -0.2 50.0Ave
Anthracene 1.1531.095 0.7000 8.42 8.00 5.3 50.0Ave
Carbazole 1.0811.046 0.0100 8.26 8.00 3.3 50.0Ave
Di-n-butyl phthalate 1.309 0.0100 7.88 8.00 -1.5 50.0Lin2
Fluoranthene 1.1531.090 0.6000 8.46 8.00 5.8 50.0Ave
Pyrene 1.6591.622 0.6000 8.18 8.00 2.3 50.0Ave
Butyl benzyl phthalate 0.7210 0.0100 7.78 8.00 -2.7 50.0Lin1
Benzo[a]anthracene 1.3791.287 0.8000 8.57 8.00 7.1 50.0Ave
Chrysene 1.4631.442 0.7000 8.12 8.00 1.5 50.0Ave
Bis(2-ethylhexyl) phthalate 0.6957 0.0100 7.99 8.00 -0.1 50.0Lin2
Di-n-octyl phthalate 1.404 0.0100 7.69 8.00 -3.9 50.0Lin1
Benzo[b]fluoranthene 1.207 0.7000 7.93 8.00 -0.9 50.0Lin2
Benzo[k]fluoranthene 1.405 0.7000 7.89 8.00 -1.3 50.0Lin2
Benzo[a]pyrene 1.256 0.7000 8.14 8.00 1.8 50.0Lin2
Indeno[1,2,3-cd]pyrene 0.8709 0.5000 8.39 8.00 4.8 50.0Lin2
Dibenz(a,h)anthracene 0.9632 0.4000 7.80 8.00 -2.5 50.0Lin2
Benzo[g,h,i]perylene 1.081 0.5000 7.96 8.00 -0.5 50.0Lin2
FORM VII 8270E
Page 743 of 1261
FORM VII
Lab Name:Job No.:
GC/MS SEMI VOA CONTINUING CALIBRATION DATA
280-184424-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
SMS_1
11/28/2023 13:48
11/15/2023 07:12
11/15/2023 09:47
CCVC 280-635266/17
Rxi-5Sil MS
Lab File ID:SMS_1-112823013.D Conc. Units:ug/mL
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Fluorophenol (Surr)1.356 7.90 8.00 -1.3 50.0Lin2
Phenol-d5 (Surr)1.7811.767 8.06 8.00 0.8 50.0Ave
Nitrobenzene-d5 (Surr)0.44300.4187 8.46 8.00 5.8 50.0Ave
2-Fluorobiphenyl 1.4471.430 8.09 8.00 1.2 50.0Ave
2,4,6-Tribromophenol (Surr)0.1874 7.37 8.00 -7.8 50.0Lin2
Terphenyl-d14 (Surr)1.1351.169 7.77 8.00 -2.8 50.0Ave
FORM VII 8270E
Page 744 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Lims ID:CCVC HSL
Client ID:
Sample Type:CCVC
Inject. Date:28-Nov-2023 13:48:10 ALS Bottle#:0 Worklist Smp#:17
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:CCVC HSL
Operator ID:MB Instrument ID:SMS_1
Sublist:chrom-SMS_1_8270*sub29
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:29-Nov-2023 10:12:46 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1689
First Level Reviewer: FP7E Date:28-Nov-2023 16:25:51
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
* 1 1,4-Dichlorobenzene-d4 152 3.904 3.904 0.000 95 253176 8.00 8.00
* 2 Naphthalene-d8 136 5.072 5.072 0.000 99 911231 8.00 8.00
* 3 Acenaphthene-d10 164 6.763 6.760 0.003 95 472426 8.00 8.00
* 4 Phenanthrene-d10 188 8.209 8.209 0.000 97 803603 8.00 8.00
* 5 Chrysene-d12 240 10.945 10.945 0.000 98 580998 8.00 8.00
* 6 Perylene-d12 264 13.136 13.139 -0.003 97 568583 8.00 8.00
$ 7 2-Fluorophenol 112 2.850 2.850 0.000 93 343301 8.00 7.90
$ 8 Phenol-d5 99 3.648 3.648 0.000 96 451015 8.00 8.06
$ 9 Nitrobenzene-d5 82 4.406 4.406 0.000 96 403647 8.00 8.46
$ 10 2-Fluorobiphenyl 172 6.129 6.129 0.000 100 683590 8.00 8.09
$ 11 2,4,6-Tribromophenol 330 7.540 7.540 0.000 89 88545 8.00 7.37
$ 12 Terphenyl-d14 244 9.808 9.808 0.000 97 659711 8.00 7.77
15 1,4-Dioxane 88 1.546 1.549 -0.003 90 158380 8.00 7.78
17 N-Nitrosodimethylamine 74 1.756 1.759 -0.003 86 241508 8.00 8.11
18 Pyridine 79 1.784 1.784 0.000 78 738445 16.0 15.8
31 Aniline 93 3.623 3.623 0.000 93 440615 8.00 7.99
29 Phenol 94 3.660 3.660 0.000 92 510188 8.00 8.21
33 Bis(2-chloroethyl)ether 93 3.688 3.688 0.000 90 400371 8.00 7.77
34 2-Chlorophenol 128 3.737 3.737 0.000 93 378878 8.00 8.20
35 n-Decane 43 3.790 3.790 0.000 92 600170 8.00 7.72
36 1,3-Dichlorobenzene 146 3.851 3.851 0.000 96 422166 8.00 8.04
37 1,4-Dichlorobenzene 146 3.919 3.919 0.000 91 420102 8.00 7.86
43 1,2-Dichlorobenzene 146 4.052 4.052 0.000 94 402100 8.00 7.87
40 Benzyl alcohol 108 4.052 4.052 0.000 89 236929 8.00 7.56
46 Indene 116 4.132 4.132 0.000 90 1297027 16.0 16.1
47 2,2'-oxybis[1-chloropropane] 45 4.172 4.175 -0.003 92 834593 8.00 7.48
45 2-Methylphenol 108 4.184 4.181 0.003 94 330739 8.00 8.21
52 Acetophenone 105 4.277 4.277 0.000 91 499617 8.00 7.92
54 N-Nitrosodi-n-propylamine 70 4.289 4.289 0.000 94 283209 8.00 7.85
51 4-Methylphenol 108 4.332 4.329 0.003 92 347754 8.00 8.15
Page 745 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
49 3-Methylphenol 108 4.332 4.329 0.003 86 347754 8.00 8.15
50 3 & 4 Methylphenol 108 4.332 4.329 0.003 0 347754 8.00 8.15
56 Hexachloroethane 117 4.357 4.354 0.003 96 184052 8.00 8.10
58 Nitrobenzene 77 4.425 4.424 0.001 95 415629 8.00 8.36
60 Isophorone 82 4.656 4.656 0.000 96 705842 8.00 8.30
61 2-Nitrophenol 139 4.720 4.720 0.000 89 186268 8.00 8.00
62 2,4-Dimethylphenol 107 4.810 4.810 0.000 95 248858 8.00 8.51
66 Bis(2-chloroethoxy)methane 63 4.878 4.877 0.001 91 406031 8.00 7.94
69 Benzoic acid 105 4.964 4.933 -0.003 91 376957 16.0 13.8
70 2,4-Dichlorophenol 162 4.976 4.976 0.000 96 288999 8.00 8.16
72 1,2,4-Trichlorobenzene 180 5.025 5.025 0.000 93 325028 8.00 8.04
75 Naphthalene 128 5.090 5.090 0.000 98 1041023 8.00 8.09
77 4-Chloroaniline 127 5.164 5.152 0.000 94 412119 8.00 8.21
78 2,6-Dichlorophenol 162 5.173 5.173 0.000 92 295489 8.00 8.29
80 Hexachlorobutadiene 225 5.226 5.226 0.000 97 181314 8.00 8.41
85 4-Chloro-3-methylphenol 107 5.682 5.679 0.003 94 290312 8.00 8.35
88 2-Methylnaphthalene 141 5.759 5.759 0.000 92 565404 8.00 8.06
89 1-Methylnaphthalene 142 5.851 5.851 0.000 93 615132 8.00 8.02
92 Hexachlorocyclopentadiene 237 5.919 5.919 0.000 96 53861 8.00 6.94
90 1,2,4,5-Tetrachlorobenzene 216 5.922 5.919 0.003 98 316283 8.00 8.10
94 2,3-Dichlorobenzenamine 161 6.039 6.039 0.000 95 340284 8.00 8.33
93 2,4,6-Trichlorophenol 196 6.055 6.055 0.000 93 190389 8.00 8.41
95 2,4,5-Trichlorophenol 196 6.107 6.107 0.000 93 202166 8.00 7.97
97 1,1'-Biphenyl 154 6.221 6.218 0.003 97 794715 8.00 8.15
98 2-Chloronaphthalene 162 6.224 6.224 0.000 97 634876 8.00 8.18
101 2-Nitroaniline 65 6.344 6.344 0.000 79 228738 8.00 7.82
104 Dimethyl phthalate 163 6.545 6.545 0.000 98 649707 8.00 7.91
105 1,3-Dinitrobenzene 168 6.554 6.554 0.000 84 104002 8.00 7.75
106 2,6-Dinitrotoluene 165 6.591 6.588 0.003 88 152800 8.00 7.81
107 Acenaphthylene 152 6.622 6.622 0.000 99 941958 8.00 8.43
108 3-Nitroaniline 138 6.751 6.748 0.003 85 179437 8.00 7.84
109 Acenaphthene 153 6.794 6.794 0.000 96 619768 8.00 8.05
111 2,4-Dinitrophenol 184 6.859 6.856 0.003 78 98433 16.0 14.5
114 Dibenzofuran 168 6.967 6.964 0.003 96 854509 8.00 8.00
116 2,4-Dinitrotoluene 165 6.979 6.976 0.003 89 199561 8.00 7.66
113 4-Nitrophenol 109 7.004 7.001 0.003 84 146419 16.0 13.4
120 2,3,4,6-Tetrachlorophenol 232 7.109 7.108 0.001 76 137010 8.00 7.59
124 Diethyl phthalate 149 7.244 7.241 0.003 97 671085 8.00 7.98
122 Hexadecane 57 7.284 7.284 0.000 87 671508 8.00 8.00
127 Fluorene 166 7.300 7.300 0.000 93 673421 8.00 7.92
126 4-Chlorophenyl phenyl ether 204 7.321 7.321 0.000 95 309461 8.00 7.79
130 4-Nitroaniline 138 7.346 7.346 0.000 80 176439 8.00 7.69
131 4,6-Dinitro-2-methylphenol 198 7.374 7.373 0.001 72 196845 16.0 14.8
132 Diphenylamine 169 7.441 7.441 0.000 92 464353 6.80 6.66
133 N-Nitrosodiphenylamine 169 7.441 7.441 0.000 64 464353 8.00 8.29
135 Azobenzene 77 7.475 7.472 0.003 97 809635 8.00 8.11
136 1,2-Diphenylhydrazine 77 7.475 7.472 0.003 41 809635 8.09 8.20
145 4-Bromophenyl phenyl ether 248 7.796 7.796 0.000 74 175440 8.00 8.25
148 Hexachlorobenzene 284 7.830 7.830 0.000 92 197864 8.00 7.77
153 Pentachlorophenol 266 8.052 8.048 0.004 90 184156 16.0 15.6
154 n-Octadecane 57 8.196 8.196 0.000 89 654728 8.00 7.65
157 Phenanthrene 178 8.233 8.233 0.000 98 922601 8.00 7.98
Page 746 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
160 Anthracene 178 8.283 8.283 0.001 98 926435 8.00 8.42
161 Carbazole 167 8.461 8.461 0.000 96 868492 8.00 8.26
163 Alachlor 188 8.625 8.625 0.000 89 107457 8.00 8.05
164 Di-n-butyl phthalate 149 8.859 8.859 0.000 99 1052055 8.00 7.88
170 Fluoranthene 202 9.398 9.398 0.000 99 926850 8.00 8.46
172 Pyrene 202 9.614 9.614 0.000 97 963707 8.00 8.18
180 Butyl benzyl phthalate 149 10.350 10.353 -0.003 98 418890 8.00 7.78
184 Benzo[a]anthracene 228 10.933 10.936 -0.003 100 800940 8.00 8.57
185 Chrysene 228 10.979 10.979 0.000 97 850061 8.00 8.12
186 Bis(2-ethylhexyl) phthalate 149 11.121 11.111 0.000 96 559097 8.00 7.99
189 Di-n-octyl phthalate 149 12.119 12.119 0.000 99 815831 8.00 7.69
191 Benzo[b]fluoranthene 252 12.513 12.510 0.000 98 686259 8.00 7.93
193 Benzo[k]fluoranthene 252 12.557 12.557 -0.003 99 798929 8.00 7.89
194 Benzo[a]pyrene 252 13.037 13.037 -0.003 79 714154 8.00 8.14
198 Indeno[1,2,3-cd]pyrene 276 15.025 15.025 0.000 97 505984 8.00 8.39
199 Dibenz(a,h)anthracene 278 15.093 15.095 -0.006 95 547644 8.00 7.80
200 Benzo[g,h,i]perylene 276 15.472 15.474 -0.006 96 614554 8.00 7.96
305 Alpha Methyl Styrene 1 0.000 ND ND
S 211 Total Cresols 108 0 16.4
S 212 Methyl Phenols,Total 108 0 16.4
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MS-HSL-WS_00005 Amount Added: 20.00 Units: uL
MS-IS-RVE_00003 Amount Added: 25.00 Units: uL Run Reagent
Page 747 of 1261
Report Date: 29-Nov-2023 10:12:48 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823013.D
Injection Date:28-Nov-2023 13:48:10 Instrument ID:SMS_1 Operator ID:MB
Lims ID:CCVC HSL Worklist Smp#:17
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0
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-112823013[MS Quad Chro]:Total
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Page 748 of 1261
Report Date: 15-Nov-2023 10:52:25 Chrom Revision: 2.3 13-Nov-2023 16:16:38
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D
Lims ID:DFTPP
Client ID:
Sample Type:DFTPP
Inject. Date:15-Nov-2023 07:01:36 ALS Bottle#:0 Worklist Smp#:2
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:DFTPP
Operator ID:MB Instrument ID:SMS_1
Method:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:15-Nov-2023 10:52:25 Calib Date:15-Nov-2023 09:47:48
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523009.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1680
First Level Reviewer: FP7E Date:15-Nov-2023 07:09:37
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
38 Pentachlorophenol_T 266 3.171 3.171 0.000 89 636088 NR NR
73 Benzidine_T 184 4.301 4.301 0.000 98 5253995 NR NR
206 DFTPP
207 4,4'-DDE 246 4.570 ND ND
208 4,4'-DDD 235 4.816 ND ND
209 4,4'-DDT 235 4.897 4.897 0.000 97 2339493 NR NR a
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
ND - Not Detected or Marked ND
Review Flags
a - User Assigned ID
Reagents:
MS-DFTPP_RVE_00001 Amount Added: 200.00 Units: uL
Page 749 of 1261
Report Date: 15-Nov-2023 10:52:26 Chrom Revision: 2.3 13-Nov-2023 16:16:38
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D
Injection Date:15-Nov-2023 07:01:36 Instrument ID:SMS_1
Lims ID:DFTPP
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:2
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Tune Method: DFTPP Method 8270
206 DFTPP
50 90 130 170 210 250 290 330 370 410 450
m/z
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
0
0
)
Tune Spec :Average 479-481( 3.54-3.54 ) Bgrd 472( 3.52)
198
442
127 25577
110
206 275129
107 224186 441
296167
m/z Ion Abundance Criteria %Relative
Abundance
198 Base peak,100%relative abundance 100.0
51 30-60%of mass 198 57.6
68 <2%of mass 69 0.7 (1.6)
69 Present 47.1
70 <2%of mass 69 0.2 (0.5)
127 40-60%of mass 198 53.2
197 <1%of mass 198 0.3
199 5-9%of mass 198 6.9
275 10-30%of mass 198 22.2
365 >1%of mass 198 3.5
441 Present but less than mass 443 10.7 (81.6)
442 >40%of mass 198 69.8
443 17-23%of mass 442 13.1 (18.7)
Page 750 of 1261
Report Date: 15-Nov-2023 10:52:26 Chrom Revision: 2.3 13-Nov-2023 16:16:38
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D\SMS_1_8270.rslt\spectra.d
Injection Date:15-Nov-2023 07:01:36
Spectrum:Tune Spec :Average 479-481( 3.54-3.54 ) Bgrd 472( 3.52)
Base Peak:198.00
Minimum % Base Peak:0
Number of Points:360
m/z Y m/z Y m/z Y m/z Y
50.00 174400 141.00 28824 234.00 5078 329.00 573
51.00 727040 142.00 9801 235.00 4933 330.00 127
52.00 37464 143.00 7900 236.00 3943 332.00 2013
53.00 1375 144.00 2202 237.00 5717 333.00 2561
54.00 138 145.00 1767 238.00 964 334.00 18432
55.00 2636 146.00 5324 239.00 3182 335.00 5135
56.00 19832 147.00 15979 240.00 1956 336.00 454
57.00 48208 148.00 38944 241.00 4506 338.00 51
58.00 2116 149.00 7615 242.00 9171 339.00 436
59.00 488 150.00 2205 243.00 10048 340.00 290
60.00 56 151.00 5107 244.00 135872 341.00 3077
61.00 6881 152.00 2665 245.00 18576 342.00 926
62.00 7869 153.00 9132 246.00 26728 343.00 163
63.00 23736 154.00 7583 247.00 6217 345.00 118
64.00 3407 155.00 17824 248.00 1763 346.00 6305
65.00 12278 156.00 26384 249.00 4429 347.00 945
66.00 1042 157.00 5245 250.00 1235 348.00 173
67.00 531 158.00 5536 251.00 988 350.00 266
68.00 9330 159.00 4768 252.00 1038 351.00 478
69.00 594432 160.00 9404 253.00 4094 352.00 8090
70.00 3077 161.00 14626 255.00 663104 353.00 5819
71.00 479 162.00 4351 256.00 94008 354.00 7407
72.00 101 163.00 1022 257.00 7403 355.00 1445
73.00 3295 164.00 1604 258.00 40896 356.00 261
74.00 54840 165.00 10919 259.00 6129 357.00 132
75.00 90312 166.00 8692 260.00 1080 358.00 158
76.00 32336 167.00 71088 261.00 1129 359.00 571
77.00 658176 168.00 34360 262.00 279 361.00 145
78.00 43608 169.00 5580 263.00 521 362.00 146
79.00 36208 170.00 2011 264.00 1127 363.00 119
80.00 29176 171.00 3000 265.00 15560 364.00 438
81.00 44136 172.00 5611 266.00 3251 365.00 43936
82.00 10760 173.00 6659 267.00 166 366.00 6061
Page 751 of 1261
Report Date: 15-Nov-2023 10:52:26 Chrom Revision: 2.3 13-Nov-2023 16:16:38
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D\SMS_1_8270.rslt\spectra.d
Injection Date:15-Nov-2023 07:01:36
Spectrum:Tune Spec :Average 479-481( 3.54-3.54 ) Bgrd 472( 3.52)
Base Peak:198.00
Minimum % Base Peak:0
Number of Points:360
m/z Y m/z Y m/z Y m/z Y
83.00 10621 174.00 13797 268.00 220 367.00 504
84.00 1408 175.00 25024 270.00 1276 370.00 637
85.00 7266 176.00 7074 271.00 1669 371.00 2106
86.00 12016 177.00 10920 272.00 2274 372.00 14873
87.00 5280 178.00 3806 273.00 21184 373.00 3337
88.00 2256 179.00 48528 274.00 52096 374.00 271
89.00 1151 180.00 31688 275.00 280064 377.00 72
90.00 236 181.00 15053 276.00 37960 377.00 466
91.00 8352 182.00 2614 277.00 26616 378.00 67
92.00 9226 183.00 1451 278.00 4405 383.00 4203
93.00 69128 184.00 3284 279.00 1003 384.00 1161
94.00 4863 185.00 22848 281.00 22 385.00 290
95.00 896 186.00 168512 282.00 851 386.00 50
96.00 2973 187.00 47600 283.00 3101 389.00 200
97.00 635 188.00 4941 284.00 2234 390.00 1843
98.00 49560 189.00 10617 285.00 4431 391.00 1401
99.00 40248 190.00 1625 286.00 756 392.00 993
100.00 3904 191.00 3975 287.00 147 393.00 249
101.00 23720 192.00 15973 288.00 436 396.00 56
102.00 1342 193.00 16135 289.00 1170 397.00 104
103.00 7697 194.00 3456 290.00 1181 401.00 916
104.00 13475 195.00 2598 291.00 658 402.00 5170
105.00 13891 196.00 37688 292.00 1467 403.00 7859
106.00 4174 197.00 3567 293.00 6128 404.00 3001
107.00 190784 198.00 1263104 294.00 1605 405.00 558
108.00 29352 199.00 86720 295.00 1228 406.00 50
109.00 4551 200.00 7070 296.00 91328 408.00 57
110.00 347456 202.00 6776 297.00 12943 410.00 151
111.00 52400 203.00 8569 298.00 1103 414.00 58
112.00 5900 204.00 45584 299.00 67 415.00 567
113.00 2226 205.00 76112 300.00 108 416.00 78
114.00 437 206.00 310784 301.00 1364 418.00 153
115.00 357 207.00 39168 302.00 1706 420.00 234
116.00 9092 208.00 10724 303.00 10230 421.00 7031
Page 752 of 1261
Report Date: 15-Nov-2023 10:52:26 Chrom Revision: 2.3 13-Nov-2023 16:16:38
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D\SMS_1_8270.rslt\spectra.d
Injection Date:15-Nov-2023 07:01:36
Spectrum:Tune Spec :Average 479-481( 3.54-3.54 ) Bgrd 472( 3.52)
Base Peak:198.00
Minimum % Base Peak:0
Number of Points:360
m/z Y m/z Y m/z Y m/z Y
117.00 157952 209.00 3722 304.00 2351 422.00 6546
118.00 11035 210.00 3462 305.00 164 423.00 46000
119.00 1362 211.00 12958 307.00 232 424.00 11266
120.00 2114 213.00 921 308.00 1680 425.00 1111
121.00 995 214.00 550 309.00 958 426.00 172
122.00 11644 215.00 3421 310.00 1141 428.00 80
123.00 17320 216.00 7370 311.00 211 429.00 81
124.00 7910 217.00 85920 312.00 278 430.00 268
125.00 7138 218.00 10859 313.00 931 432.00 217
127.00 671936 219.00 1393 314.00 4381 432.00 185
128.00 51360 221.00 63760 315.00 11080 433.00 462
129.00 250688 222.00 10923 316.00 5209 434.00 311
130.00 21864 223.00 20288 317.00 1086 435.00 520
131.00 4060 224.00 176000 319.00 175 436.00 499
132.00 1804 225.00 42088 320.00 506 437.00 857
133.00 1033 226.00 4525 321.00 2948 438.00 1200
134.00 7265 227.00 70656 322.00 1205 439.00 1494
135.00 18384 228.00 11157 323.00 26288 440.00 789
136.00 7890 229.00 14446 324.00 4821 441.00 134656
137.00 10303 230.00 2325 325.00 756 442.00 881984
138.00 2364 231.00 6652 326.00 680 443.00 164928
139.00 1196 232.00 946 327.00 5850 444.00 15161
140.00 2324 233.00 1608 328.00 2350 445.00 682
Page 753 of 1261
Report Date: 15-Nov-2023 10:52:26 Chrom Revision: 2.3 13-Nov-2023 16:16:38
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D
Injection Date:15-Nov-2023 07:01:36 Instrument ID:SMS_1 Operator ID:MB
Lims ID:DFTPP Worklist Smp#:2
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 6.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
0
)
-111523001[MS Quad Chro]:Total
Page 754 of 1261
Report Date: 15-Nov-2023 10:52:25 Chrom Revision: 2.3 13-Nov-2023 16:16:38
Breakdown Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231115-127671.b\SMS_1-111523001.D
Injection Date:15-Nov-2023 07:01:36 Instrument ID:SMS_1
Lims ID:DFTPP
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:2
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
209 4,4'-DDT, Detector: MS Quad
SW-846 Method
%Breakdown =
(Area Breakdown Cpnds/
Total Area Breakdown Cpnds) * 100
209 4,4'-DDT, Area = 2339493
208 4,4'-DDD, Area = 0
207 4,4'-DDE, Area = 0
%Breakdown: 0.00%, <= 20.00%
Passed
4.2 4.5 4.8 5.1
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
0
0
0
)
-111523001[MS Quad Chro]:m/z 235

B
e
n
zid
i
n
e
_
T
(
4.3
0
1
)

4,
4
'
-D
D
T
(
4.8
97)
2.0 3.2 4.4 5.6
Min
0
1
2
3
4
5
6
7
8
9
10
Y ( X10
0
0
)
-111523001[MS Quad Chro]:m/z 0

P
e
n
t
a
c
h
l
o
r
o
p
h
e
n
o
l
_
T
(
3
.
1
7
1
)

D
F
T
P
P
(
3
.
5
41)

B
e
n
zid
i
n
e
_
T
(
4.3
0
1
)

4,
4
'
-D
D
T
(
4.8
97)
Page 755 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D
Lims ID:DFTPP
Client ID:
Sample Type:DFTPP
Inject. Date:28-Nov-2023 09:30:00 ALS Bottle#:0 Worklist Smp#:2
Injection Vol:2.0 ul Dil. Factor:1.0000
Sample Info:DFTPP
Operator ID:MB Instrument ID:SMS_1
Method:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1_8270.m
Limit Group:MSSV - 8270C_625
Method Label:8270C / 625
Last Update:28-Nov-2023 11:18:57 Calib Date:20-Nov-2023 10:00:40
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\SMS_1\20231120-127850.b\SMS_1-112023008.D
Column 1 :Rxi-5Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1646
First Level Reviewer: FP7E Date:28-Nov-2023 09:36:55
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/ml
OnCol Amt
ug/ml Flags
38 Pentachlorophenol_T 266 3.171 3.171 0.000 93 639484 NR NR
73 Benzidine_T 184 4.307 4.307 0.000 98 5238471 NR NR
206 DFTPP
208 4,4'-DDD 235 4.685 ND ND
207 4,4'-DDE 246 4.704 ND ND
209 4,4'-DDT 235 4.904 4.904 0.000 97 2328741 NR NR a
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
ND - Not Detected or Marked ND
Review Flags
a - User Assigned ID
Reagents:
MS-DFTPP_RVE_00001 Amount Added: 200.00 Units: uL
Page 756 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D
Injection Date:28-Nov-2023 09:30:00 Instrument ID:SMS_1
Lims ID:DFTPP
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:2
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Tune Method: DFTPP Method 8270
206 DFTPP
50 90 130 170 210 250 290 330 370 410 450
m/z
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
0
0
)
Tune Spec :Average 480-482( 3.54-3.55 ) Bgrd 473( 3.52)
198
442
127 25577
110 206
275129
107 224186
441
296167
m/z Ion Abundance Criteria %Relative
Abundance
198 Base peak,100%relative abundance 100.0
51 30-60%of mass 198 53.3
68 <2%of mass 69 0.7 (1.5)
69 Present 45.1
70 <2%of mass 69 0.2 (0.4)
127 40-60%of mass 198 52.1
197 <1%of mass 198 0.0
199 5-9%of mass 198 6.8
275 10-30%of mass 198 22.0
365 >1%of mass 198 3.4
441 Present but less than mass 443 10.8 (82.5)
442 >40%of mass 198 67.6
443 17-23%of mass 442 13.1 (19.4)
Page 757 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D\SMS_1_8270.rslt\spectra.d
Injection Date:28-Nov-2023 09:30:00
Spectrum:Tune Spec :Average 480-482( 3.54-3.55 ) Bgrd 473( 3.52)
Base Peak:197.90
Minimum % Base Peak:0
Number of Points:363
m/z Y m/z Y m/z Y m/z Y
50.00 165696 142.00 9591 237.00 6788 332.00 2268
51.00 668096 143.00 7365 238.00 732 333.00 2660
52.00 34096 144.00 1870 239.00 2908 334.00 16928
53.00 1191 145.00 1504 240.00 2274 335.00 4424
54.00 188 146.00 5375 241.00 3984 336.00 690
55.00 1256 147.00 15717 242.00 9240 337.00 130
56.00 19160 148.00 37192 243.00 10015 338.00 67
57.00 45224 149.00 7275 244.00 135936 339.00 436
58.00 1988 150.00 2277 245.00 17088 340.00 413
59.00 415 151.00 4172 246.00 25384 341.00 3695
60.00 653 152.00 485 247.00 6173 342.00 928
61.00 6763 153.00 9042 248.00 1415 343.00 237
62.00 7726 154.00 6907 249.00 4708 344.00 59
63.00 22680 155.00 17312 250.00 1312 345.00 121
64.00 3315 156.00 26160 251.00 1685 346.00 5934
65.00 12138 157.00 5663 252.00 1694 347.00 1242
66.00 1029 158.00 5105 253.00 3230 348.00 52
67.00 817 159.00 3670 255.00 651648 349.00 54
68.00 8410 160.00 10028 256.00 95120 350.00 102
69.00 564416 161.00 14199 257.00 7781 351.00 570
70.00 2532 162.00 3902 258.00 41200 352.00 8096
71.00 398 163.00 1434 259.00 6822 353.00 6156
72.00 463 164.00 1630 260.00 1097 354.00 8019
73.00 3225 165.00 9975 261.00 1441 355.00 1679
74.00 51592 166.00 9329 262.00 154 356.00 71
75.00 86408 167.00 71048 264.00 1985 357.00 370
76.00 28920 168.00 35248 265.00 15770 358.00 216
77.00 628608 169.00 5864 266.00 2796 359.00 660
78.00 44208 170.00 2152 267.00 511 360.00 243
79.00 34200 171.00 2422 268.00 409 361.00 386
80.00 27656 172.00 5334 269.00 31 362.00 236
81.00 40672 173.00 7260 270.00 1183 363.00 62
82.00 10168 174.00 13061 271.00 1386 364.00 149
Page 758 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D\SMS_1_8270.rslt\spectra.d
Injection Date:28-Nov-2023 09:30:00
Spectrum:Tune Spec :Average 480-482( 3.54-3.55 ) Bgrd 473( 3.52)
Base Peak:197.90
Minimum % Base Peak:0
Number of Points:363
m/z Y m/z Y m/z Y m/z Y
83.00 9110 175.00 24776 272.00 2223 365.00 43128
84.00 1733 176.00 7481 273.00 21664 366.00 5618
85.00 9199 177.00 10364 274.00 52552 367.00 645
86.00 10078 178.00 3399 275.00 275264 370.00 895
87.00 5499 179.00 46416 276.00 37792 371.00 2316
88.00 2173 180.00 32136 277.00 25640 372.00 14491
89.00 710 181.00 15426 278.00 4082 373.00 2982
90.00 249 182.00 2390 279.00 1186 374.00 371
91.00 8053 183.00 1443 280.00 194 377.00 64
92.00 9863 184.00 4121 281.00 268 377.00 260
93.00 66400 185.00 22112 282.00 856 382.00 102
94.00 4601 186.00 173440 283.00 3142 383.00 3809
95.00 1125 187.00 49696 284.00 1966 384.00 1086
96.00 3155 188.00 5646 285.00 4749 385.00 361
97.00 957 189.00 9497 286.00 981 389.00 73
98.00 46864 190.00 1593 288.00 188 390.00 2238
99.00 39096 191.00 4570 289.00 1061 391.00 1437
100.00 3488 192.00 15492 290.00 860 392.00 1013
101.00 23432 193.00 16848 291.00 574 393.00 74
102.00 1137 194.00 3565 292.00 1191 395.00 56
103.00 6638 195.00 2973 293.00 5883 397.00 54
104.00 12995 196.00 37968 294.00 1768 399.00 64
105.00 12711 198.00 1252352 295.00 620 401.00 772
106.00 4146 199.00 84864 296.00 89144 402.00 6193
107.00 188992 200.00 6545 297.00 12275 403.00 8692
108.00 28712 202.00 6512 298.00 1133 404.00 3109
109.00 4910 203.00 9299 299.00 229 405.00 640
110.00 333888 204.00 45720 300.00 70 410.00 221
111.00 51592 205.00 78288 301.00 908 415.00 503
112.00 6292 206.00 317440 302.00 1782 416.00 68
113.00 2264 207.00 39816 303.00 10845 418.00 61
114.00 859 208.00 10385 304.00 2395 419.00 142
115.00 442 209.00 3923 305.00 461 420.00 242
116.00 8476 210.00 4569 307.00 102 421.00 7406
Page 759 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D\SMS_1_8270.rslt\spectra.d
Injection Date:28-Nov-2023 09:30:00
Spectrum:Tune Spec :Average 480-482( 3.54-3.55 ) Bgrd 473( 3.52)
Base Peak:197.90
Minimum % Base Peak:0
Number of Points:363
m/z Y m/z Y m/z Y m/z Y
117.00 152256 211.00 12334 308.00 1277 422.00 6418
118.00 11403 213.00 1124 309.00 1013 423.00 43984
119.00 1486 214.00 452 310.00 1485 424.00 11093
120.00 2346 215.00 3199 311.00 234 425.00 1648
121.00 821 216.00 6779 312.00 326 427.00 165
122.00 10587 217.00 87704 313.00 712 427.00 120
123.00 15559 218.00 11780 314.00 3835 428.00 161
124.00 7348 219.00 1318 315.00 10676 429.00 359
125.00 8478 220.00 1038 316.00 5601 430.00 127
127.00 652736 221.00 64536 317.00 1233 431.00 216
128.00 48240 223.00 19544 318.00 55 433.00 246
129.00 251520 224.00 173504 319.00 155 433.00 381
130.00 22312 225.00 42312 320.00 149 434.00 388
131.00 3888 226.00 5322 321.00 2594 435.00 618
132.00 2050 227.00 73280 322.00 1592 436.00 689
133.00 949 228.00 10694 323.00 26648 437.00 647
134.00 6436 229.00 14496 324.00 4871 438.00 1190
135.00 18072 230.00 2442 325.00 559 440.00 1521
136.00 6726 231.00 6190 326.00 558 441.00 135424
137.00 9675 232.00 1329 327.00 6142 442.00 846272
138.00 2453 233.00 1247 328.00 2775 443.00 164224
139.00 1080 234.00 4587 329.00 432 444.00 15333
140.00 2880 235.00 5903 330.00 137 445.00 659
141.00 30096 236.00 4275 331.00 251
Page 760 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D
Injection Date:28-Nov-2023 09:30:00 Instrument ID:SMS_1 Operator ID:MB
Lims ID:DFTPP Worklist Smp#:2
Client ID:
Injection Vol:2.0 ul Dil. Factor:1.0000 ALS Bottle#:0
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
Column: Rxi-5Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Peak: 1
2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 6.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Y ( X10
0
0
0
0
0
)
-112823001[MS Quad Chro]:Total
Page 761 of 1261
Report Date: 28-Nov-2023 11:18:57 Chrom Revision: 2.3 15-Nov-2023 20:54:34
Breakdown Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\SMS_1\20231128-128038.b\SMS_1-112823001.D
Injection Date:28-Nov-2023 09:30:00 Instrument ID:SMS_1
Lims ID:DFTPP
Client ID:
Operator ID:MB ALS Bottle#:0 Worklist Smp#:2
Injection Vol:2.0 ul Dil. Factor:1.0000
Method:SMS_1_8270 Limit Group:MSSV - 8270C_625
209 4,4'-DDT, Detector: MS Quad
SW-846 Method
%Breakdown =
(Area Breakdown Cpnds/
Total Area Breakdown Cpnds) * 100
209 4,4'-DDT, Area = 2328741
208 4,4'-DDD, Area = 0
207 4,4'-DDE, Area = 0
%Breakdown: 0.00%, <= 20.00%
Passed
4.3 4.6 4.9
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
0
0
0
)
-112823001[MS Quad Chro]:m/z 235

4
,4'-D
D
T
(
4
.
9
0
4
)
2.0 3.2 4.4 5.6
Min
0
1
2
3
4
5
6
7
8
9
10
Y ( X10
0
0
)
-112823001[MS Quad Chro]:m/z 0

P
e
n
t
a
c
h
l
o
r
o
p
h
e
n
o
l
_
T
(
3
.
1
7
1
)

D
F
T
P
P
(
3
.
5
4
4
)

B
e
n
zid
i
n
e
_
T
(
4
.
3
0
7
)

4
,4'-D
D
T
(
4
.
9
0
4
)
Page 762 of 1261
FORM I
GC/MS SEMI VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LB 280-634317/1-F
Matrix:SMS_1-112823003.DLab File ID:
Date Collected:8270EAnalysis Method:
Solid (TCLP)
Level: (low/med)
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Analyzed:
Date Extracted:
Dilution Factor:
Extract. Method:11/22/2023 11:45
1
3510C
11/28/2023 10:02
Low
2(uL)
1(mL)
% Moisture:
Sample wt/vol:125(mL)
N% Solids:
GC Column:0.25(mm)ID:Rxi-5Sil MS
Cleanup Factor:
Analysis Batch No.:635266 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
4.0U3.2106-46-7 1,4-Dichlorobenzene 3.2 1.4
10U8.0121-14-2 2,4-Dinitrotoluene 8.0 1.4
10U8.0118-74-1 Hexachlorobenzene 8.0 0.86
10U8.087-68-3 Hexachlorobutadiene 8.0 2.9
10U8.067-72-1 Hexachloroethane 8.0 4.5
10U8.095-48-7 2-Methylphenol 8.0 0.77
10U8.015831-10-4 3 & 4 Methylphenol 8.0 0.80
10U8.098-95-3 Nitrobenzene 8.0 1.3
50U4887-86-5 Pentachlorophenol 48 20
50U48110-86-1 Pyridine 48 18
10U8.095-95-4 2,4,5-Trichlorophenol 8.0 0.90
10U8.088-06-2 2,4,6-Trichlorophenol 8.0 0.71
%RECCAS NO.LIMITSQSURROGATE
84 44-119321-60-8 2-Fluorobiphenyl
70 19-119367-12-4 2-Fluorophenol (Surr)
79 43-140118-79-6 2,4,6-Tribromophenol (Surr)
87 44-1204165-60-0 Nitrobenzene-d5 (Surr)
62 10-1154165-62-2 Phenol-d5 (Surr)
109 50-1341718-51-0 Terphenyl-d14 (Surr)
FORM I 8270E
Page 763 of 1261
FORM I
GC/MS SEMI VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-634317/2-F
Matrix:SMS_1-112823004.DLab File ID:
Date Collected:8270EAnalysis Method:
Solid (TCLP)
Level: (low/med)
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Analyzed:
Date Extracted:
Dilution Factor:
Extract. Method:11/22/2023 11:45
1
3510C
11/28/2023 10:25
Low
2(uL)
1(mL)
% Moisture:
Sample wt/vol:125(mL)
N% Solids:
GC Column:0.25(mm)ID:Rxi-5Sil MS
Cleanup Factor:
Analysis Batch No.:635266 ug/LUnits:
CAS NO.LOQQRESULTCOMPOUND NAME LOD DL
4.045.3106-46-7 1,4-Dichlorobenzene 3.2 1.4
1067.6121-14-2 2,4-Dinitrotoluene 8.0 1.4
1066.9118-74-1 Hexachlorobenzene 8.0 0.86
1047.487-68-3 Hexachlorobutadiene 8.0 2.9
1044.067-72-1 Hexachloroethane 8.0 4.5
1067.595-48-7 2-Methylphenol 8.0 0.77
1068.115831-10-4 3 & 4 Methylphenol 8.0 0.80
1068.798-95-3 Nitrobenzene 8.0 1.3
5014887-86-5 Pentachlorophenol 48 20
50U Q48110-86-1 Pyridine 48 18
1067.995-95-4 2,4,5-Trichlorophenol 8.0 0.90
1069.488-06-2 2,4,6-Trichlorophenol 8.0 0.71
%RECCAS NO.LIMITSQSURROGATE
89 44-119321-60-8 2-Fluorobiphenyl
78 19-119367-12-4 2-Fluorophenol (Surr)
89 43-140118-79-6 2,4,6-Tribromophenol (Surr)
90 44-1204165-60-0 Nitrobenzene-d5 (Surr)
78 10-1154165-62-2 Phenol-d5 (Surr)
96 50-1341718-51-0 Terphenyl-d14 (Surr)
FORM I 8270E
Page 764 of 1261
Lab Name:Job No.:
GC/MS SEMI VOA ANALYSIS RUN LOG
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
SMS_1
633956
Start Date:
End Date:11/15/2023 18:18
11/15/2023 07:01
DFTPP 280-633956/2 Rxi-5Sil MS 0.25(mm)111/15/2023 07:01 SMS_1-111523001
.D
ICIS 280-633956/3 Rxi-5Sil MS 0.25(mm)111/15/2023 07:12 SMS_1-111523002
.D
STD20 280-633956/10
IC Rxi-5Sil MS 0.25(mm)111/15/2023 07:34 SMS_1-111523003
.D
STD16 280-633956/9
IC Rxi-5Sil MS 0.25(mm)111/15/2023 07:56 SMS_1-111523004
.D
STD12 280-633956/8
IC Rxi-5Sil MS 0.25(mm)111/15/2023 08:18 SMS_1-111523005
.D
STD05 280-633956/7
IC Rxi-5Sil MS 0.25(mm)111/15/2023 08:40 SMS_1-111523006
.D
STD02 280-633956/6
IC Rxi-5Sil MS 0.25(mm)111/15/2023 09:03 SMS_1-111523007
.D
STD01 280-633956/5
IC Rxi-5Sil MS 0.25(mm)111/15/2023 09:25 SMS_1-111523008
.D
STD004 280-633956/4
IC Rxi-5Sil MS 0.25(mm)111/15/2023 09:47 SMS_1-111523009
.D
ICV 280-633956/11 Rxi-5Sil MS 0.25(mm)111/15/2023 10:10
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 10:54
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 11:16
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 11:38
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 12:00
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 12:23
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 12:45
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 13:07
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 13:29
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 13:51
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 14:13
ZZZZZ Rxi-5Sil MS 0.25(mm)511/15/2023 14:36
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 14:58
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 15:20
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 15:42
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 16:04
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 16:27
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 16:49
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 17:11
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 17:33
ZZZZZ Rxi-5Sil MS 0.25(mm)111/15/2023 17:55
ZZZZZ Rxi-5Sil MS 0.25(mm)2511/15/2023 18:18
8270E
Page 765 of 1261
Lab Name:Job No.:
GC/MS SEMI VOA ANALYSIS RUN LOG
Eurofins Denver 280-184424-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
SMS_1
635266
Start Date:
End Date:11/28/2023 14:10
11/28/2023 09:30
DFTPP 280-635266/2 Rxi-5Sil MS 0.25(mm)111/28/2023 09:30 SMS_1-112823001
.D
CCVIS 280-635266/3 Rxi-5Sil MS 0.25(mm)111/28/2023 09:40 SMS_1-112823002
.D
LB 280-634317/1-F Rxi-5Sil MS 0.25(mm)111/28/2023 10:02 SMS_1-112823003
.D
LCS 280-634317/2-F Rxi-5Sil MS 0.25(mm)111/28/2023 10:25 SMS_1-112823004
.D
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 10:47
280-184424-1 ST071-SoilIDW-1109202
3 Rxi-5Sil MS 0.25(mm)111/28/2023 11:10 SMS_1-112823006
.D
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 11:32
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 11:55
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 12:17
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 12:40
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 13:02
ZZZZZ Rxi-5Sil MS 0.25(mm)111/28/2023 13:25
CCVC 280-635266/17 Rxi-5Sil MS 0.25(mm)111/28/2023 13:48 SMS_1-112823013
.D
CCVL 280-635266/20 Rxi-5Sil MS 0.25(mm)111/28/2023 14:10
8270E
Page 766 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS SEMI VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bekheit, Matthew A11/15/23 07:01633956
Batch Method:
Eurofins Denver
8270E
Lab Sample ID Client Sample ID Method Chain Basis FinalAmount CalcMsg MS-DFTPP_RVE
00001
MS-IS-RVE 00005 MS-RVHSL-WS
00003
1 mL Perform
Calculation
left blank
200 uL8270EDFTPP
280-633956/2
1 mL Perform
Calculation
left blank
30 uL 200 uL8270EICIS
280-633956/3
1 mL Perform
Calculation
left blank
30 uL 10 uL8270ESTD004
280-633956/4 IC
1 mL Perform
Calculation
left blank
30 uL 25 uL8270ESTD01
280-633956/5 IC
1 mL Perform
Calculation
left blank
30 uL 50 uL8270ESTD02
280-633956/6 IC
1 mL Perform
Calculation
left blank
30 uL 125 uL8270ESTD05
280-633956/7 IC
1 mL Perform
Calculation
left blank
30 uL 300 uL8270ESTD12
280-633956/8 IC
1 mL Perform
Calculation
left blank
30 uL 400 uL8270ESTD16
280-633956/9 IC
1 mL Perform
Calculation
left blank
30 uL 500 uL8270ESTD20
280-633956/10
IC
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 18270E
Page 767 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS SEMI VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/17/23 23:11
11/17/23 00:38634317
Batch Method:
Eurofins Denver
1311
Lab Sample ID Client Sample ID Method Chain Basis ExtractFluid
T11311, 3510C,
8270E
LB 280-634317/1
T11311, 3510C,
8270E
LCS
280-634317/2
ST071-SoilIDW-11
092023
T11311, 3510C,
8270E
P280-184424-B-1
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28270E
Page 768 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS SEMI VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/17/23 23:11
11/17/23 00:38634317
Batch Method:
Eurofins Denver
1311
Batch Notes
Thermometer ID 311846
First Start time 11/17/2023 00:38
First End time 11/17/2023 17:11
Rotator ID #1 1108 1102 Blue
Tumbler Rotations per Minute 29 29 29 31
Balance ID 42605617
Balance is Level? (Y/N)y
pH Meter Calibration Slope 99.9
Water Bath Thermometer ID 311846
TCLP Fluid 1 ID T1_00469
TCLP Fluid 1 pH 4.93 SU
TCLP Fluid 2 ID T2_00161
TCLP Fluid 2 pH 2.89 SU
pH Buffer 1 ID 2271
pH Buffer 2 ID 223591
pH Buffer 3 ID 2133
pH Buffer 4 ID 221687
Lot # of Nitric Acid NitricAcid_00009
1N HCl ID 1N HCL_00055
Uncorrected Maximum Temperature 24.3 Degrees C
Maximum Temperature 23.7 Degrees C
Uncorrected Minimum Temperature 22.5 Degrees C
Minimum Temperature 21.9 Degrees C
Analyst ID - Filtration DB
Filtration Date 11.17.23
Batch Comment DV-IP-0011
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28270E
Page 769 of 1261
Analyst: DFB
Date: 11.16.23
160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
1 2 3 1 2 1 1 1 2 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 770 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No. 1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.05 4.97 5.01 4.94 4.93 4.99 5.04 5.04 5.07 4.94
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00
b. Stop Time for Mixing 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05
c. pH reading after mixing 8.98 8.97 8.86 9.01 9.04 8.64 8.71 8.70 8.87 8.92
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.56 1.56 1.57 1.54 1.53 1.58 1.57 1.59 1.59 1.55
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 771 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.33 100.20 100.20 101.04 100.13 100.15 100.03 101.08 102.13 100.44
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2007 2004 2004 2021 2003 2003 2001 2022 2043 2009
Rotator Number:#1 #1 #1 #1 #1 #1 1102 1102 1102 1102
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.19 5.16 5.35 5.26 5.22 5.36 5.50 5.30 5.32 5.25
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
blank final pH --> 4.92
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1Page 772 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
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Analyst: DFB
Date: 11.16.23
184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
1 1 1 2 1 2 1 1 1 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 774 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No. 1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.1 4.99 5.00 5.07 5.06 4.98 4.96 5.09 5.05 5.02
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40
b. Stop Time for Mixing 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45
c. pH reading after mixing 7.92 9.95 12.10 9.29 7.66 8.07 8.23 7.92 8.21 10.66
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.73 1.89 10.62 4.54 1.58 1.55 1.54 1.76 1.63 2.25
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2 Fluid 2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 775 of 1261
Analyst: DFB
Login No. 184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.25 100.24 100.58 101.16 100.44 100.10 100.22 100.92 100.25
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2005 2005 2012 2023 2009 2002 2004 2018 2005
Rotator Number:Blue Blue 1108 1102 1102 Blue Blue Blue Blue
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 0.0 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 0.0 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.22 6.21 7.20 5.06 7.17 5.03 5.00 5.08 5.62
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2Page 776 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 777 of 1261
2000144860 Started 11-17-2023, Finished 11-17-2023.ltd
Recorder has been downloaded 11/17/2023 5:18:22 PM (UTC -07:00, standard 'me)
Alarm Status
Lower
Upper
OK
OK
Recorder Configura on
Start type :
Start delay :
Interval :
Alert indicator :
OK indicator :
Push bu on start
1 Minute
10 Minutes
Enabled lower & upper
Enabled
Temperature alarms
Lower :
Upper :
21.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
25.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
Recorder Info
Serial # :
User ID :
2000144860
TCLP 2 (-0.6)
Model :TRIX-8 Ba6ery :OK Trip # :265
Recorded Data
First reading :
Last reading :
Elapsed Time :
Total readings :
First evaluated :
Last evaluated :
Evaluated Time :
Evaluated Readings :
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
146
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
101
Temperature sta's'cs
Lowest :
Highest :
Average reading :
Standard Devia'on (S) :
Mean Kine'c Temperature
22.5 °C
@ 11/17/2023 12:26:53 PM
24.3 °C
@ 11/17/2023 12:46:53 AM
23.0 °C
0.4 °C
22.98 °C
Lower Alarm
Triggered :
Time below :
Occurrences :
°C - Minutes below :
(none)
(none)
0
0.00
Upper Alarm
Triggered :
Time above :
Occurrences :
°C - Minutes above :
(none)
(none)
0
0.00
Readings (°C)Inspection Mark
25.0 25.0
24.5 24.5
24.0 24.0
23.5 23.5
23.0 23.0
22.5 22.5
22.0 22.0
12:36:53 AM
11/17/2023
5:16:53 PM
11/17/2023
3:06:53 AM
11/17/2023
5:36:53 AM
11/17/2023
8:06:53 AM
11/17/2023
10:36:53 AM
11/17/2023
1:06:53 PM
11/17/2023
Events Info
11/17/2023 12:46:53 AM Inspec on
Page 1 of 111/17/2023 5:19:22 PM
Page 778 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS SEMI VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Cross, Nicole M
11/27/23 16:26
11/22/23 11:45634893
Batch Method:
Eurofins Denver
3510C
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount ReceivedpH FirstAdjustpH SecondAdjustpH 8270_LCS_Main
00090
125 mL 1 mL 5 SU 1-2 SU 14 SU3510C, 8270ELB
280-634317/1-A
125 mL 1 mL 5 SU 1-2 SU 14 SU 0.125 mL3510C, 8270ELCS
280-634317/2-A
ST071-SoilIDW-11
092023
125 mL 1 mL 5 SU 1-2 SU 14 SU3510C, 8270E P280-184424-B-1-
A
Lab Sample ID Client Sample ID Method Chain Basis 8270Surrogate
00171
0.125 mL3510C, 8270ELB
280-634317/1-A
0.125 mL3510C, 8270ELCS
280-634317/2-A
ST071-SoilIDW-11
092023
0.125 mL3510C, 8270E P280-184424-B-1-
A
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28270E
Page 779 of 1261
Lab Name:Job No.:
SDG No.:
GC/MS SEMI VOA BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Cross, Nicole M
11/27/23 16:26
11/22/23 11:45634893
Batch Method:
Eurofins Denver
3510C
Batch Notes
Method/Fraction 1311_T/3510C_LVI/8270E
Balance ID 834419820
Balance is Level? (Y/N)yes
pH Indicator ID HC318548
Pipette/Syringe/Dispenser ID RICHARD
Analyst ID - Extraction NC
Reagent Water ID N. ELGA
Analyst ID - Spike Analyst NC
Analyst ID - Spike Witness Analyst REVIEWER:EW
Sufficient Volume for Batch QC YES
Acid Used for pH Adjustment ID 1:1H2SO4_00117
Base Used to Adjust pH ID 10N_NaOH_00195
NaCl ID Baked_NaCl_00020
Prep Solvent ID Mecl2_Cycl_00620
Prep Solvent Volume Used 90 mL
Glass Wool ID Glass_Wool_OP_00003
Na2SO4 ID Na2SO4_00143
Analyst ID - Concentration CR (TRAINEE)
Equipment ID - Concentration 1 BUCHI 3, 4
Concentration 1 Uncorrected Temperature Base:55 Cover:50 Degrees C
Concentration 1 Corrected Temperature Base:55 Cover:50 Degrees C
Pipette Tip Lot ID B00442228S
Batch Comment DV-OP-0006/0007
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28270E
Page 780 of 1261
METALS
Page 781 of 1261
COVER PAGE
Lab Name: Job Number:
METALS
280-184424-1Eurofins Denver
SDG No.:
Client Sample ID Lab Sample ID
Project:Hill AFB, UT - ST071

280-184424-1 ST071-SoilIDW-11092023
Comments:
Page 782 of 1261
1A-IN
INORGANIC ANALYSIS DATA SHEET
Client Sample ID:
Lab Name:Job No.:
Lab Sample ID: 280-184424-1
280-184424-1
ST071-SoilIDW-11092023
METALS - TCLP
Eurofins Denver
SDG ID.:
Matrix:
Date Received:11/10/2023 16:30

Solid 11/09/2023 16:00Date Sampled:
Reporting Basis:WET
Analyte LOQ LOD Units C Q DIL MethodResultDL
ug/L J 1 6010D7524Arsenic7122
ug/L 1 6010D501000Barium104.1
ug/L J 1 6010D256.7Cadmium 2.3 0.65
ug/L U 1 6010D5013Chromium133.3
ug/L U 1 6010D4538Lead3814
ug/L U 1 6010D10095Selenium9532
ug/L U 1 6010D5030Silver309.8
ug/L U 1 7470A0.200.080Mercury 0.080 0.061
FORM IA-IN Page 783 of 1261
2A-IN
Lab Name:Job No.:
CALIBRATION VERIFICATIONS
METALS
Eurofins Denver 280-184424-1
SDG No.:
Concentration Units:ICV Source:
CCV Source:
mg/LICP ICV_01806
ICP CCV_00709
Analyte
ICV 280-634762/9
11/20/2023 10:56
Found C True %R
CCV 280-634762/204
11/21/2023 04:25
CCV 280-634762/211
11/21/2023 05:26
Found FoundC CTrue%R True %R
Arsenic 0.254 0.505 0.5010.250 0.500 0.500102101 100J
Barium 0.251 0.500 0.5040.250 0.500 0.500100100 101JJJ
Cadmium 0.253 0.510 0.5110.250 0.500 0.500101102 102
Chromium 0.252 0.512 0.5150.250 0.500 0.500101102 103J
Lead 0.259 0.537 0.5390.250 0.500 0.500103107 108J
Selenium 0.248 0.505 0.5070.250 0.500 0.50099101 101
Silver 0.251 0.506 0.5050.250 0.500 0.500100101 101J
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Italicized analytes were not requested for this sequence.
Page 784 of 1261
2A-IN
Lab Name:Job No.:
CALIBRATION VERIFICATIONS
METALS
Eurofins Denver 280-184424-1
SDG No.:
Concentration Units:ICV Source:
CCV Source:
mg/LICP ICV_01806
ICP CCV_00709
Analyte
CCV 280-634762/225
11/21/2023 06:27
Found C True %R
CCV 280-634762/239
11/21/2023 07:28
Found FoundC CTrue%R True %R
Arsenic 0.502 0.5030.500 0.500100 101
Barium 0.506 0.5010.500 0.500101 100JJ
Cadmium 0.511 0.5130.500 0.500102 103
Chromium 0.514 0.5150.500 0.500103 103
Lead 0.540 0.5390.500 0.500108 108
Selenium 0.501 0.5000.500 0.500100 100
Silver 0.507 0.5060.500 0.500101 101
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Italicized analytes were not requested for this sequence.
Page 785 of 1261
2A-IN
Lab Name:Job No.:
CALIBRATION VERIFICATIONS
METALS
Eurofins Denver 280-184424-1
SDG No.:
Concentration Units:ICV Source:
CCV Source:
mg/LHg Biwk ICV_00405
Hg Daily Spk_03482
Analyte
ICV 280-635180/9-A
11/27/2023 18:48
Found C True %R
CCV 280-635180/12-A
11/27/2023 23:58
CCV 280-635180/12-A
11/28/2023 00:29
Found FoundC CTrue%R True %R
Mercury 0.00410 0.00530 0.005290.00400 0.00500 0.00500102106 106
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Italicized analytes were not requested for this sequence.
Page 786 of 1261
2A-IN
Lab Name:Job No.:
CALIBRATION VERIFICATIONS
METALS
Eurofins Denver 280-184424-1
SDG No.:
Concentration Units:ICV Source:
CCV Source:
mg/LHg Biwk ICV_00405
Hg Daily Spk_03482
Analyte
CCV 280-635180/12-A
11/28/2023 00:44
Found C True %R Found FoundC CTrue%R True %R
Mercury 0.00532 0.00500 106
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Italicized analytes were not requested for this sequence.
Page 787 of 1261
2B-IN
Lab Name:Job No.:280-184424-1
CRQL CHECK STANDARD
METALS
Eurofins Denver
SDG No.:
Method:6010D Instrument ID:MT_052
Lab Sample ID:
Analyte True Found Qualifiers %R(1)Limits
CRI 280-634762/13
CRQL Check Standard
CRQL Check Standard Source:ICP LLCCV_03791
Concentration Units:mg/L
80-120Arsenic0.0150 0.075 U 113
80-120Barium0.0100 0.0101 J 101
80-120Cadmium0.00500 0.00524 J 105
80-120Chromium0.0100 0.00998 J 100
80-120Lead0.00900 0.045 U 110
80-120Selenium0.0200 0.095 U 99
80-120Silver0.0100 0.025 U 96
FORM IIB-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 788 of 1261
2B-IN
Lab Name:Job No.:280-184424-1
CRQL CHECK STANDARD
METALS
Eurofins Denver
SDG No.:
Method:7470A Instrument ID:MT_036
Lab Sample ID:
Analyte True Found Qualifiers %R(1)Limits
CRA 280-635180/11-A
CRQL Check Standard
CRQL Check Standard Source:Hg Daily Spk_03482
Concentration Units:mg/L
80-120Mercury0.000200 0.000180 J 90
FORM IIB-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 789 of 1261
Lab Name:Job No.:
INSTRUMENT BLANKS
METALS
Eurofins Denver 280-184424-1
3-IN
SDG No.:
Concentration Units:mg/L
CFoundCFoundCFoundCFoundRLAnalyte
ICB 280-634762/12 CCB 280-634762/205 CCB 280-634762/212 CCB 280-634762/226
11/20/2023 11:09 11/21/2023 04:30 11/21/2023 05:30 11/21/2023 06:32
Arsenic 0.075 0.075 0.075 0.0750.50 U U U U
Barium 0.013 0.013 0.013 0.0131.0 U U U U
Cadmium 0.0070 0.0070 0.0070 0.00700.10 U U U U
Chromium 0.013 0.013 0.013 0.0130.50 U U U U
Lead 0.045 0.045 0.045 0.0450.50 U U U U
Selenium 0.095 0.095 0.095 0.0950.10 U U U U
Silver 0.025 0.025 0.025 0.0250.50 U U U U
FORM III-IN
Italicized analytes were not requested for this sequence.
Page 790 of 1261
Lab Name:Job No.:
INSTRUMENT BLANKS
METALS
Eurofins Denver 280-184424-1
3-IN
SDG No.:
Concentration Units:mg/L
CFoundCFoundCFoundCFoundRLAnalyte
CCB 280-634762/240
11/21/2023 07:32
Arsenic 0.0750.50 U
Barium 0.0131.0 U
Cadmium 0.00700.10 U
Chromium 0.0130.50 U
Lead 0.0450.50 U
Selenium 0.0950.10 U
Silver 0.0250.50 U
FORM III-IN
Italicized analytes were not requested for this sequence.
Page 791 of 1261
Lab Name:Job No.:
INSTRUMENT BLANKS
METALS
Eurofins Denver 280-184424-1
3-IN
SDG No.:
Concentration Units:mg/L
CFoundCFoundCFoundCFoundRLAnalyte
ICB 280-635180/10-A CCB 280-635180/13-A CCB 280-635180/13-A CCB 280-635180/13-A
11/27/2023 18:51 11/28/2023 00:01 11/28/2023 00:31 11/28/2023 00:46
Mercury 0.000080 0.000080 0.000080 0.0000800.0020 U U U U
FORM III-IN
Italicized analytes were not requested for this sequence.
Page 792 of 1261
Lab Name:Job No.:
3-IN
280-184424-1
METHOD BLANK
METALS - TCLP
Eurofins Denver
SDG No.:
Lab Sample ID: LB 280-634317/1-BConcentration Units:ug/L
CAS No.Analyte Concentration C Q Method
Batch No.:

Instrument Code:MT_052 634762
7440-38-2 Arsenic 71 U 6010D_DOD5
7440-39-3 Barium 13.0 J 6010D_DOD5
7440-43-9 Cadmium 2.3 U 6010D_DOD5
7440-47-3 Chromium 13 U 6010D_DOD5
7439-92-1 Lead 38 U 6010D_DOD5
7782-49-2 Selenium 95 U 6010D_DOD5
7440-22-4 Silver 30 U 6010D_DOD5
FORM III-IN
Page 793 of 1261
Lab Name:Job No.:
3-IN
280-184424-1
METHOD BLANK
METALS - TCLP
Eurofins Denver
SDG No.:
Lab Sample ID: LB 280-634317/1-GConcentration Units:ug/L
CAS No.Analyte Concentration C Q Method
Batch No.:

Instrument Code:MT_036 635299
7439-97-6 Mercury 0.080 U 7470A_DOD5
FORM III-IN
Page 794 of 1261
4A-IN
Lab Name:Job No.:Eurofins Denver 280-184424-1
INTERFERENCE CHECK STANDARD
METALS
SDG No.:
Instrument ID:
ICS Source:
Concentration Units:
Analyte
True
Percent
Recovery
Found
Lab File ID:
Solution A Solution A
Lab Sample ID:ICSA 280-634762/14
52A112023A.csv
mg/L
ICP ICSA_00261
MT_052
0.0073Arsenic
-0.0005Barium
-0.0001Cadmium
0.0027Chromium
0.0024Lead
0.0014Selenium
0.0013Silver
515Aluminum500 103
-0.0022Antimony
0.0005Beryllium
-0.0040Bi
-0.0004Boron
510Calcium500 102
0.0021Cobalt
-0.0020Copper
192Iron200 96
0.0006Lithium
534Magnesium500 107
-0.0008Manganese
0.0004Molybdenum
-0.0051Nickel
0.0238Phosphorus
-0.0124Potassium
0.107Sodium
-0.0513Sulfur
-0.0004Thallium
-0.0026Tin
-0.0018Titanium
0.0033Vanadium
0.0024Zinc
0.0001Zirconium
FORM IVA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 795 of 1261
4A-IN
Lab Name:Job No.:Eurofins Denver 280-184424-1
INTERFERENCE CHECK STANDARD
METALS
SDG No.:
Instrument ID:
ICS Source:
Concentration Units:
Analyte
True
Percent
Recovery
Found
Lab File ID:
Solution AB Solution AB
Lab Sample ID:ICSAB 280-634762/15
52A112023A.csv
mg/L
ICP ICSAB_00290
MT_052
1.07Arsenic1.00 107
1.05Barium1.00 105
0.967Cadmium1.00 97
1.01Chromium1.00 101
0.993Lead1.00 99
1.04Selenium1.00 104
1.14Silver1.00 114
509Aluminum500 102
1.10Antimony1.00 110
0.509Beryllium0.500 102
0.0002Bi
10.8Boron10.0 108
504Calcium500 101
0.965Cobalt1.00 97
1.10Copper1.00 110
190Iron200 95
1.14Lithium1.00 114
528Magnesium500 106
0.992Manganese1.00 99
1.00Molybdenum1.00 100
0.941Nickel1.00 94
10.2Phosphorus10.0 102
11.3Potassium10.0 113
10.9Sodium10.0 109
10.4Sulfur10.0 104
0.967Thallium1.00 97
0.976Tin1.00 98
1.05Titanium1.00 105
1.03Vanadium1.00 103
0.971Zinc1.00 97
1.000Zirconium1.00 100
FORM IVA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 796 of 1261
MATRIX SPIKE SAMPLE RECOVERY
METALS - TCLP
5A-IN
ST071-SoilIDW-11092023 MSClient ID:Lab ID:280-184424-1 MS
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Matrix:Concentration Units:ug/LSolid
% Solids:
Control
Limit
%RAnalyteSSR
C
Sample
Result (SR)
C
Spike
Added (SA) %R Q Method
Mercury 82-1194.98 0.080 5.00 100 7470AU
SSR = Spiked Sample Result
FORM VA - IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 797 of 1261
MATRIX SPIKE DUPLICATE SAMPLE RECOVERY
METALS - TCLP
5A-IN
ST071-SoilIDW-11092023 MSDClient ID:Lab ID:280-184424-1 MSD
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Matrix:Concentration Units:ug/LSolid
% Solids:
Analyte (SDR)
C
Control
Limit
%R%R RPD
RPD
Limit Q Method
Spike
Added (SA)
Mercury 4.93 5.00 99 82-119 1 10 7470A
SDR = Sample Duplicate Result
FORM VD - IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 798 of 1261
POST DIGESTION SPIKE SAMPLE RECOVERY
METALS - TCLP
5B-IN
ST071-SoilIDW-11092023 PDSClient ID:Lab ID:280-184424-1 PDS
Lab Name:Job No.:280-184424-1Eurofins Denver
SDG No.:
Matrix:Concentration Units:ug/LSolid
Control
Limit
%RAnalyteSSR
C
Sample
Result (SR)
C
Spike
Added (SA) %R Q Method
Mercury 80-1205.15 0.080 5.00 103 7470AU
SSR = Spiked Sample Result
FORM VB - IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 799 of 1261
7A-IN
LAB CONTROL SAMPLE
METALS - TCLP
Lab ID:LCS 280-634317/2-B
Lab Name:Job No.:280-184424-1Eurofins Denver
Sample Matrix:LCS Source:Prep spike2IV_00013Solid
Analyte
Solid(ug/L)
True Found C %R Limits Q Method
Arsenic 8000 8340 104 6010D87113
Barium 15000 15500 103 6010D88113
Cadmium 6000 5980 100 6010D88113
Chromium 10000 10300 103 6010D90113
Lead 10000 10700 107 6010D86113
Selenium 6000 6120 102 6010D83114
Silver 1250 1330 106 6010D84115
Calculations are performed before rounding to avoid round-off errors in calculated results.
FORM VIIA - IN
Page 800 of 1261
7A-IN
LAB CONTROL SAMPLE
METALS - TCLP
Lab ID:LCS 280-634317/2-G
Lab Name:Job No.:280-184424-1Eurofins Denver
Sample Matrix:LCS Source:Hg Daily Spk_03482Solid
Analyte
Solid(ug/L)
True Found C %R Limits Q Method
Mercury 5.00 5.10 102 7470A82119
Calculations are performed before rounding to avoid round-off errors in calculated results.
FORM VIIA - IN
Page 801 of 1261
8-IN
Lab ID:280-184424-1
Lab Name:Job No:
SDG No:
280-184424-1
ICP-AES AND ICP-MS SERIAL DILUTIONS
METALS - TCLP
Eurofins Denver
Matrix:Concentration Units:ug/L
Analyte
Initial Sample
Result (I)C
Serial
Dilution
Result (S)C
%
Difference Q Method
Solid
Mercury 0.080 U 0.40 U NC 7470A
FORM VIII-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 802 of 1261
9-IN
280-184424-1Job Number:Lab Name:
METALS - TCLP
Eurofins Denver
CALIBRATION BLANK DETECTION LIMITS
SDG Number:
Instrument ID:MT_052SolidMatrix:
6010D XMDL Date:06/21/2019 00:00Method:
Analyte Wavelength/
Mass
XRL XMDL
(mg/L)(mg/L)
Arsenic 0.0220.5
Barium 0.0041
Cadmium 0.0020.1
Chromium 0.0030.5
Lead 0.0140.5
Selenium 0.0320.1
Silver 0.009780.5
FORM IX - IN
Page 803 of 1261
9-IN
280-184424-1Job Number:Lab Name:
METALS - TCLP
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:MT_052SolidMatrix:
05/10/2023 15:55Method:6010D DL Date:
3010APrep Method:
1311Leach Method:
Analyte Wavelength/
Mass
LOQ DL
(ug/L)(ug/L)
Arsenic 22.175
Barium 4.150
Cadmium 0.6525
Chromium 3.350
Lead 13.745
Selenium 31.5100
Silver 9.850
FORM IX - IN
Page 804 of 1261
9-IN
280-184424-1Job Number:Lab Name:
METALS - TCLP
Eurofins Denver
CALIBRATION BLANK DETECTION LIMITS
SDG Number:
Instrument ID:MT_036SolidMatrix:
7470A XMDL Date:04/11/2022 16:44Method:
Analyte Wavelength/
Mass
XRL XMDL
(mg/L)(mg/L)
Mercury 0.000060.002
FORM IX - IN
Page 805 of 1261
9-IN
280-184424-1Job Number:Lab Name:
METALS - TCLP
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:MT_036SolidMatrix:
05/10/2023 16:33Method:7470A DL Date:
7470APrep Method:
1311Leach Method:
Analyte Wavelength/
Mass
LOQ DL
(ug/L)(ug/L)
Mercury 253.7 0.0610.2
FORM IX - IN
Page 806 of 1261
10-IN
ICP-AES INTERELEMENT CORRECTION FACTORS
METALS
Lab Name: Job Number:Eurofins Denver 280-184424-1
SDG No.:
ICP-AES Instrument ID:Date:MT_052 03/15/2023
Analyte Ag Al As B Ba Be Bi Ca Cd Co Cr Cu Fe K
Wave
Length
394.401Aluminum
396.152Aluminum
206.834Antimony 0.00567 0.000058
188.980Arsenic -0.000011
493.408Barium 0.000019
234.861Beryllium 0.000079
223.061Bismuth
249.678Boron
214.439Cadmium 0.000014
315.887Calcium
205.560Chromium
228.615Cobalt
324.754Copper -0.000013 0.000027
238.204Iron 0.00316
259.940Iron
220.353 -0.000052Lead -0.000612
670.783Lithium
279.078Magnesium -0.000195
257.610Manganese
202.032Molybdenum
231.604Nickel
213.618Phosphorus -0.0443
766.491Potassium
196.026Selenium -0.000175
288.158Silicon
328.068Silver
589.592Sodium 0.968 -
589.593Sodium 0.993
421.552Strontium
0.006815181.972 0.0053Sulfur 0.000096 0.00019
X-IN
Page 807 of 1261
10-IN
ICP-AES INTERELEMENT CORRECTION FACTORS
METALS
Lab Name: Job Number:Eurofins Denver 280-184424-1
SDG No.:
ICP-AES Instrument ID:Date:MT_052 03/15/2023
Analyte Ag Al As B Ba Be Bi Ca Cd Co Cr Cu Fe K
Wave
Length
190.794Thallium 0.00178 -0.000017
288.505 0.00333Thorium -0.000347 -0.000016
189.925Tin
336.122Titanium 0.00002
409.013Uranium 0.000227
292.401Vanadium -0.00714
206.200Zinc
343.823Zirconium 0.000017
X-IN
Page 808 of 1261
10-IN
ICP-AES INTERELEMENT CORRECTION FACTORS
METALS
Lab Name: Job Number:Eurofins Denver 280-184424-1
SDG No.:
ICP-AES Instrument ID:Date:MT_052 03/15/2023
Analyte Li Mg Mn Mo Na Ni P Pb S Sb Se Si Sn Sr
Wave
Length
396.152Aluminum
394.401Aluminum
206.834Antimony -0.003886 -0.000291
188.980Arsenic
493.408Barium
234.861Beryllium
223.061Bismuth
249.678Boron
214.439Cadmium
315.887Calcium
205.560Chromium -0.00075 -0.00025
228.615Cobalt
324.754Copper
238.204Iron
259.940Iron
220.353Lead -0.000822
670.783Lithium
279.078Magnesium
257.610Manganese
202.032Molybdenum
231.604Nickel
213.618Phosphorus -0.02399
766.491Potassium
196.026 0.00108Selenium
288.158Silicon 0.0394
328.068Silver
589.593Sodium
589.592Sodium
421.552Strontium
181.972 0.0051Sulfur 0.0061
X-IN
Page 809 of 1261
10-IN
ICP-AES INTERELEMENT CORRECTION FACTORS
METALS
Lab Name: Job Number:Eurofins Denver 280-184424-1
SDG No.:
ICP-AES Instrument ID:Date:MT_052 03/15/2023
Analyte Li Mg Mn Mo Na Ni P Pb S Sb Se Si Sn Sr
Wave
Length
190.794Thallium -0.002337
288.505 0.00001 0.0108Thorium 0.00103
189.925Tin
336.122Titanium
409.013Uranium
292.401Vanadium -0.00109
206.200Zinc
343.823Zirconium
X-IN
Page 810 of 1261
10-IN
ICP-AES INTERELEMENT CORRECTION FACTORS
METALS
Lab Name: Job Number:Eurofins Denver 280-184424-1
SDG No.:
ICP-AES Instrument ID:Date:MT_052 03/15/2023
Analyte Th Ti Tl U V Zn Zr
Wave
Length
-0.0221394.401Aluminum 0.0086
396.152Aluminum
206.834 -0.0027Antimony
188.980Arsenic
493.408Barium
234.861Beryllium
223.061Bismuth
249.678Boron
214.439Cadmium
315.887Calcium
205.560Chromium
228.615 0.00211Cobalt
0.004517324.754 -0.000232Copper -0.001247
238.204Iron
259.940Iron
220.353 -0.000427Lead 0.000755
670.783Lithium
-0.00717279.078Magnesium -0.004857
257.610Manganese
202.032Molybdenum
231.604 0.000222Nickel
213.618Phosphorus
766.491Potassium
196.026Selenium
288.158 0.0274Silicon
0.00086328.068Silver -0.000575 -0.0148 0.0056
589.592Sodium
589.593Sodium
421.552Strontium
181.972Sulfur
X-IN
Page 811 of 1261
10-IN
ICP-AES INTERELEMENT CORRECTION FACTORS
METALS
Lab Name: Job Number:Eurofins Denver 280-184424-1
SDG No.:
ICP-AES Instrument ID:Date:MT_052 03/15/2023
Analyte Th Ti Tl U V Zn Zr
Wave
Length
190.794 -0.00154Thallium
288.505Thorium 0.00212 -0.024551
189.925Tin
336.122Titanium
0.0035409.013Uranium -0.0071
0.00205292.401 0.0005Vanadium -0.001315
206.200Zinc
343.823Zirconium
X-IN
Page 812 of 1261
11-IN
Lab Name: Eurofins Denver Job No:280-184424-1
LINEAR RANGES
METALS
SDG No.:
Instrument ID:Date:
Analyte
Integ.
Time
(Sec.)
Concentration
Method
MT_052
(mg/L)
07/03/2023 10:36
Arsenic 10 6010D
Barium 15 6010D
Cadmium 25 6010D
Chromium 10 6010D
Lead 50 6010D
Selenium 10 6010D
Silver 2 6010D
FORM XI - IN
Page 813 of 1261
12-IN
PREPARATION LOG
Lab Name:Job No.:280-184424-1
METALS
Eurofins Denver
SDG No.:
Prep Method:3010A
Lab
Sample
ID
Preparation
Date
Initial
Weight
Final
Volume
Prep
Batch
Initial
Volume
(mL)(mL)
11/20/2023 08:41 634516LB 280-634317/1-B 5010
11/20/2023 08:41 634516LCS 280-634317/2-B 5010
11/20/2023 08:41 634516280-184424-1 5010
FORM XII-IN
Page 814 of 1261
12-IN
PREPARATION LOG
Lab Name:Job No.:280-184424-1
METALS
Eurofins Denver
SDG No.:
Prep Method:7470A
Lab
Sample
ID
Preparation
Date
Initial
Weight
Final
Volume
Prep
Batch
Initial
Volume
(mL)(mL)
11/27/2023 14:45 635179LB 280-634317/1-G 5030
11/27/2023 14:45 635179LCS 280-634317/2-G 5030
11/27/2023 14:45 635179280-184424-1 5030
11/27/2023 14:45 635179280-184424-1 MS 5030
11/27/2023 14:45 635179280-184424-1 MSD 5030
FORM XII-IN
Page 815 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
X X X X X X X10:211ICIS 280-634762/1
X X X X X X X10:25IC 280-634762/2
X X X X X X X10:29IC 280-634762/3
10:39ZZZZZZ
10:43ZZZZZZ
10:47ZZZZZZ
X X X X X X X10:521ICVH 280-634762/8
X X X X X X X10:561ICV 280-634762/9
11:00CCVH 280-634762/10
11:05CCV 280-634762/11
X X X X X X X11:091ICB 280-634762/12
X X X X X X X11:131CRI 280-634762/13
X X X X X X X11:171ICSA 280-634762/14
X X X X X X X11:221ICSAB 280-634762/15
11:26LRA 280-634762/16
11:31CCVH 280-634762/17
11:36CCV 280-634762/18
11:40CCB 280-634762/19
11:44CCVL 280-634762/20
X X X X X X X12:02IC 280-634762/4
12:45CCVH 280-634762/21
12:49CCV 280-634762/22
12:54CCB 280-634762/23
12:58CCVL 280-634762/24
13:02ZZZZZZ
13:07ZZZZZZ
13:11ZZZZZZ
13:16ZZZZZZ
13:20ZZZZZZ
13:25ZZZZZZ
13:29ZZZZZZ
13:34ZZZZZZ
13:38ZZZZZZ
13:42ZZZZZZ
13:47CCVH 280-634762/35
13:52CCV 280-634762/36
13:56CCB 280-634762/37
14:01CCVL 280-634762/38
14:05ZZZZZZ
14:09ZZZZZZ
14:14ZZZZZZ
FORM XIII-IN
Page 816 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
14:18ZZZZZZ
14:23ZZZZZZ
14:27ZZZZZZ
14:33ZZZZZZ
14:37ZZZZZZ
14:41CCVH 280-634762/47
14:46CCV 280-634762/48
14:50CCB 280-634762/49
14:54CCVL 280-634762/50
14:59ZZZZZZ
15:03ZZZZZZ
15:07ZZZZZZ
15:11CCVH 280-634762/54
15:16CCV 280-634762/55
15:20CCB 280-634762/56
15:24CCVL 280-634762/57
15:28ZZZZZZ
15:33ZZZZZZ
15:37ZZZZZZ
15:41ZZZZZZ
15:46ZZZZZZ
15:50ZZZZZZ
15:54ZZZZZZ
15:59ZZZZZZ
16:03ZZZZZZ
16:07ZZZZZZ
16:12CCVH 280-634762/68
16:16CCV 280-634762/69
16:20CCB 280-634762/70
16:24CCVL 280-634762/71
16:29ZZZZZZ
16:37ZZZZZZ
16:41ZZZZZZ
16:45ZZZZZZ
16:50ZZZZZZ
16:54ZZZZZZ
16:58ZZZZZZ
17:02ZZZZZZ
17:07ZZZZZZ
17:11ZZZZZZ
17:15CCVH 280-634762/82
FORM XIII-IN
Page 817 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
17:20CCV 280-634762/83
17:25CCB 280-634762/84
17:29CCVL 280-634762/85
17:33ZZZZZZ
17:38ZZZZZZ
17:42ZZZZZZ
17:46ZZZZZZ
17:51ZZZZZZ
17:56ZZZZZZ
18:00ZZZZZZ
18:05ZZZZZZ
18:10ZZZZZZ
18:14CCVH 280-634762/95
18:19CCV 280-634762/96
18:23CCB 280-634762/97
18:27CCVL 280-634762/98
18:31ZZZZZZ
18:36ZZZZZZ
18:41ZZZZZZ
18:46ZZZZZZ
18:50ZZZZZZ
18:54ZZZZZZ
18:59ZZZZZZ
19:03ZZZZZZ
19:07ZZZZZZ
19:12ZZZZZZ
19:16CCVH 280-634762/109
19:21CCV 280-634762/110
19:25CCB 280-634762/111
19:29CCVL 280-634762/112
19:33ZZZZZZ
19:38ZZZZZZ
19:42ZZZZZZ
19:46ZZZZZZ
19:51ZZZZZZ
19:55ZZZZZZ
20:00ZZZZZZ
20:04ZZZZZZ
20:09ZZZZZZ
20:13ZZZZZZ
20:18CCVH 280-634762/123
FORM XIII-IN
Page 818 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
20:22CCV 280-634762/124
20:27CCB 280-634762/125
20:31CCVL 280-634762/126
20:35ZZZZZZ
20:39ZZZZZZ
20:44ZZZZZZ
20:48ZZZZZZ
20:53ZZZZZZ
20:57ZZZZZZ
21:01ZZZZZZ
21:06ZZZZZZ
21:10ZZZZZZ
21:14ZZZZZZ
21:19CCVH 280-634762/137
21:23CCV 280-634762/138
21:28CCB 280-634762/139
21:32CCVL 280-634762/140
21:36ZZZZZZ
21:40ZZZZZZ
21:45ZZZZZZ
21:49ZZZZZZ
21:53ZZZZZZ
21:57ZZZZZZ
22:02ZZZZZZ
22:06ZZZZZZ
22:10ZZZZZZ
22:15ZZZZZZ
22:19CCVH 280-634762/151
22:24CCV 280-634762/152
22:28CCB 280-634762/153
22:32CCVL 280-634762/154
22:37ZZZZZZ
22:41ZZZZZZ
22:45ZZZZZZ
22:50ZZZZZZ
22:54ZZZZZZ
22:58ZZZZZZ
23:03ZZZZZZ
23:07ZZZZZZ
23:12ZZZZZZ
23:16ZZZZZZ
FORM XIII-IN
Page 819 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
23:20CCVH 280-634762/165
23:25CCV 280-634762/166
23:29CCB 280-634762/167
23:33CCVL 280-634762/168
23:38ZZZZZZ
23:42ZZZZZZ
23:46ZZZZZZ
23:51ZZZZZZ
23:55ZZZZZZ
23:59ZZZZZZ
00:04ZZZZZZ
00:08ZZZZZZ
00:13ZZZZZZ
00:17ZZZZZZ
00:21CCVH 280-634762/179
00:26CCV 280-634762/180
00:30CCB 280-634762/181
00:34CCVL 280-634762/182
00:39ZZZZZZ
00:43ZZZZZZ
00:47ZZZZZZ
00:52ZZZZZZ
00:56ZZZZZZ
01:00ZZZZZZ
01:05ZZZZZZ
01:09ZZZZZZ
01:14ZZZZZZ
01:18ZZZZZZ
01:22CCVH 280-634762/193
01:27CCV 280-634762/194
01:31CCB 280-634762/195
01:35CCVL 280-634762/196
01:39ZZZZZZ
01:44ZZZZZZ
01:48ZZZZZZ
01:53ZZZZZZ
01:58ZZZZZZ
02:02ZZZZZZ
X X X X X X X04:211CCVH 280-634762/203
X X X X X X X04:251CCV 280-634762/204
X X X X X X X04:301CCB 280-634762/205
FORM XIII-IN
Page 820 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
04:34CCVL 280-634762/206
X X X X X X X05:081LB 280-634317/1-B P
X X X X X X X05:131LCS 280-634317/2-B P
05:17ZZZZZZ
X X X X X X X05:221CCVH 280-634762/210
X X X X X X X05:261CCV 280-634762/211
X X X X X X X05:301CCB 280-634762/212
05:34CCVL 280-634762/213
05:39ZZZZZZ
05:43ZZZZZZ
05:47ZZZZZZ
05:52ZZZZZZ
05:56ZZZZZZ
06:01ZZZZZZ
06:05ZZZZZZ
06:09ZZZZZZ
06:14ZZZZZZ
06:18ZZZZZZ
X X X X X X X06:231CCVH 280-634762/224
X X X X X X X06:271CCV 280-634762/225
X X X X X X X06:321CCB 280-634762/226
06:36CCVL 280-634762/227
06:40ZZZZZZ
06:44ZZZZZZ
06:49ZZZZZZ
06:53ZZZZZZ
06:57ZZZZZZ
X X X X X X X07:011280-184424-1 P
07:06ZZZZZZ
07:10ZZZZZZ
07:15ZZZZZZ
07:19ZZZZZZ
X X X X X X X07:241CCVH 280-634762/238
X X X X X X X07:281CCV 280-634762/239
X X X X X X X07:321CCB 280-634762/240
07:36CCVL 280-634762/241
07:41ZZZZZZ
07:45CCVH 280-634762/243
07:50CCV 280-634762/244
07:54CCB 280-634762/245
07:58CCVL 280-634762/246
FORM XIII-IN
Page 821 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/20/2023 10:21 11/21/2023 07:58
MT_052 6010D
Analytes
TimeD/FLab Sample Id
A
g
A
s
B
a
C
d
C
r
P
b
S
e
T
y
p
e
Prep Types:
TCLPP=
FORM XIII-IN
Page 822 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/27/2023 18:20 11/28/2023 00:46
MT_036 7470A
Analytes
TimeD/FLab Sample Id
H
g
T
y
p
e
X18:20STD0 280-635299/1 IC
X18:22STD1 280-635299/2 IC
X18:25STD2 280-635299/3 IC
X18:27STD3 280-635299/4 IC
X18:30STD4 280-635299/5 IC
X18:32STD5 280-635299/6 IC
X18:35STD6 280-635299/7 IC
X18:38STD7 280-635299/8 IC
18:44ICV 280-635180/9-A
X18:481ICV 280-635180/9-A
X18:511ICB 280-635180/10-A
X18:531CRA 280-635180/11-A
18:56CCV 280-635180/12-A
18:58CCB 280-635180/13-A
19:01ZZZZZZ
19:03ZZZZZZ
19:06ZZZZZZ
19:08ZZZZZZ
19:11ZZZZZZ
19:13ZZZZZZ
19:16ZZZZZZ
19:19ZZZZZZ
19:21ZZZZZZ
19:24ZZZZZZ
19:26CCV 280-635180/12-A
19:29CCB 280-635180/13-A
19:31ZZZZZZ
19:34ZZZZZZ
19:36ZZZZZZ
19:39ZZZZZZ
19:41ZZZZZZ
19:44ZZZZZZ
19:46ZZZZZZ
19:49ZZZZZZ
19:52ZZZZZZ
19:54ZZZZZZ
19:57CCV 280-635180/12-A
19:59CCB 280-635180/13-A
20:02ZZZZZZ
20:04ZZZZZZ
20:07ZZZZZZ
FORM XIII-IN
Page 823 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/27/2023 18:20 11/28/2023 00:46
MT_036 7470A
Analytes
TimeD/FLab Sample Id
H
g
T
y
p
e
20:09ZZZZZZ
20:12ZZZZZZ
20:14ZZZZZZ
20:17ZZZZZZ
20:19CCV 280-635180/12-A
20:22CCB 280-635180/13-A
20:25ZZZZZZ
20:27ZZZZZZ
20:30ZZZZZZ
20:32ZZZZZZ
20:35ZZZZZZ
20:37ZZZZZZ
20:40ZZZZZZ
20:42ZZZZZZ
20:45ZZZZZZ
20:47ZZZZZZ
20:50CCV 280-635180/12-A
20:52CCB 280-635180/13-A
20:55ZZZZZZ
20:58ZZZZZZ
21:00ZZZZZZ
21:03ZZZZZZ
21:05ZZZZZZ
21:08ZZZZZZ
21:10ZZZZZZ
21:13ZZZZZZ
21:15ZZZZZZ
21:18CCV 280-635180/12-A
21:20CCB 280-635180/13-A
21:23ZZZZZZ
21:25ZZZZZZ
21:28ZZZZZZ
21:30ZZZZZZ
21:33ZZZZZZ
21:36ZZZZZZ
21:38ZZZZZZ
21:41ZZZZZZ
21:43ZZZZZZ
21:46ZZZZZZ
21:48CCV 280-635180/12-A
21:51CCB 280-635180/13-A
FORM XIII-IN
Page 824 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/27/2023 18:20 11/28/2023 00:46
MT_036 7470A
Analytes
TimeD/FLab Sample Id
H
g
T
y
p
e
21:53ZZZZZZ
21:56ZZZZZZ
21:58ZZZZZZ
22:01ZZZZZZ
22:04ZZZZZZ
22:06ZZZZZZ
22:09ZZZZZZ
22:11ZZZZZZ
22:14ZZZZZZ
22:16ZZZZZZ
22:19CCV 280-635180/12-A
22:21CCB 280-635180/13-A
22:24ZZZZZZ
22:26ZZZZZZ
22:29CCV 280-635180/12-A
22:32CCB 280-635180/13-A
22:34ZZZZZZ
22:37ZZZZZZ
22:39ZZZZZZ
22:42ZZZZZZ
22:44ZZZZZZ
22:47ZZZZZZ
22:49ZZZZZZ
22:52ZZZZZZ
22:54ZZZZZZ
22:57ZZZZZZ
23:00CCV 280-635180/12-A
23:02CCB 280-635180/13-A
23:05ZZZZZZ
23:07ZZZZZZ
23:10ZZZZZZ
23:12ZZZZZZ
23:15ZZZZZZ
23:17CCV 280-635180/12-A
23:20CCB 280-635180/13-A
23:22ZZZZZZ
23:25ZZZZZZ
23:27ZZZZZZ
23:30ZZZZZZ
23:33ZZZZZZ
23:35ZZZZZZ
FORM XIII-IN
Page 825 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
METALS
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/27/2023 18:20 11/28/2023 00:46
MT_036 7470A
Analytes
TimeD/FLab Sample Id
H
g
T
y
p
e
23:38ZZZZZZ
23:40ZZZZZZ
23:43ZZZZZZ
23:45ZZZZZZ
23:48CCV 280-635180/12-A
23:50CCB 280-635180/13-A
23:53ZZZZZZ
23:55ZZZZZZ
X23:581CCV 280-635180/12-A
X00:011CCB 280-635180/13-A
X00:031LB 280-634317/1-G P
X00:061LCS 280-634317/2-G P
00:08ZZZZZZ
00:11ZZZZZZ
00:13ZZZZZZ
00:16ZZZZZZ
00:18ZZZZZZ
00:21ZZZZZZ
00:24ZZZZZZ
X00:261280-184424-1 P
X00:291CCV 280-635180/12-A
X00:311CCB 280-635180/13-A
X00:345280-184424-1 SD P
X00:361280-184424-1 MS P
X00:391280-184424-1 MSD P
X00:411280-184424-1 PDS P
X00:441CCV 280-635180/12-A
X00:461CCB 280-635180/13-A
Prep Types:
TCLPP=
FORM XIII-IN
Page 826 of 1261
15-IN
Lab Name:Job No.:
METALS
Eurofins Denver 280-184424-1
ICP INTERNAL STANDARDS RELATIVE INTENSITY SUMMARY
SDG No.: 634762Analysis Batch No.:
Lab Sample
ID
Time
Internal Standards %RI For:
Q
ElementElementElementElement
QQQQ
Element
Y Y Y
242.219 377.433 488.368
ICP Instrument ID:Start Date:End Date:MT_052 11/20/2023 11/21/2023
ICIS 280-634762/1 10:21
ICVH 280-634762/8 10:52 98 99 99
ICV 280-634762/9 10:56 100 101 99
ICB 280-634762/12 11:09 98 98 101
CRI 280-634762/13 11:13 101 102 101
ICSA 280-634762/14 11:17 89 90 96
ICSAB 280-634762/15 11:22 88 89 95
CCVH 280-634762/203 04:21 94 96 98
CCV 280-634762/204 04:25 97 99 100
CCB 280-634762/205 04:30 99 101 102
LB 280-634317/1-B 05:08 101 103 107
LCS 280-634317/2-B 05:13 99 101 104
CCVH 280-634762/210 05:22 101 103 106
CCV 280-634762/211 05:26 101 103 104
CCB 280-634762/212 05:30 102 103 104
CCVH 280-634762/224 06:23 99 101 106
CCV 280-634762/225 06:27 102 104 104
CCB 280-634762/226 06:32 102 104 105
280-184424-1 07:01 98 100 103
CCVH 280-634762/238 07:24 100 102 102
CCV 280-634762/239 07:28 99 100 100
CCB 280-634762/240 07:32 100 102 102
IS Name on Instrument
FORM XV - IN
Page 827 of 1261
15A-IN
Lab Name:Job No.:
METALS
ICP INTERNAL STANDARDS RELATIONS
280-184424-1Eurofins Denver
SDG No.:Analysis Batch No.: 634762
Internal Standard Used:
ElementElementElementElementElement
ICP Instrument ID:
Analyte Wavelength
Start Date:End Date:11/21/202311/20/2023
YYYYY
242.219 377.433 377.433 488.368 488.368
MT_052
188.980 XArsenic
493.408 XBarium
214.439 XCadmium
205.560 XChromium
220.353 XLead
196.026 XSelenium
328.068 XSilver
396.152 XAluminum
206.834 XAntimony
234.861 XBeryllium
223.061 XBi
249.678 XBoron
315.887 XCalcium
228.615 XCobalt
324.754 XCopper
259.940 XIron
670.783 XLithium
279.078 XMagnesium
257.610 XManganese
202.032 XMolybdenum
231.604 XNickel
213.618 XPhosphorus
766.491 XPotassium
589.592 XSodium
181.972 XSulfur
190.794 XThallium
189.925 XTin
336.122 XTitanium
292.401 XVanadium
206.200 XZinc
343.823 XZirconium
Internal Standard Name on Instrument Y
242.219
Y
377.433
Y_R
377.433
Y_R
488.368
Y_R2
488.368
FORM XV - IN
Page 828 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/17/23 23:11
11/17/23 00:38634317
Batch Method:
Eurofins Denver
1311
Lab Sample ID Client Sample ID Method Chain Basis ExtractFluid
T11311, 3010A,
6010D
LB 280-634317/1
T11311, 3010A,
6010D
LCS
280-634317/2
ST071-SoilIDW-11
092023
T11311, 3010A,
6010D
P280-184424-B-1
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 26010D
Page 829 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/17/23 23:11
11/17/23 00:38634317
Batch Method:
Eurofins Denver
1311
Batch Notes
Thermometer ID 311846
First Start time 11/17/2023 00:38
First End time 11/17/2023 17:11
Rotator ID #1 1108 1102 Blue
Tumbler Rotations per Minute 29 29 29 31
Balance ID 42605617
Balance is Level? (Y/N)y
pH Meter Calibration Slope 99.9
Water Bath Thermometer ID 311846
TCLP Fluid 1 ID T1_00469
TCLP Fluid 1 pH 4.93 SU
TCLP Fluid 2 ID T2_00161
TCLP Fluid 2 pH 2.89 SU
pH Buffer 1 ID 2271
pH Buffer 2 ID 223591
pH Buffer 3 ID 2133
pH Buffer 4 ID 221687
Lot # of Nitric Acid NitricAcid_00009
1N HCl ID 1N HCL_00055
Uncorrected Maximum Temperature 24.3 Degrees C
Maximum Temperature 23.7 Degrees C
Uncorrected Minimum Temperature 22.5 Degrees C
Minimum Temperature 21.9 Degrees C
Analyst ID - Filtration DB
Filtration Date 11.17.23
Batch Comment DV-IP-0011
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 26010D
Page 830 of 1261
Analyst: DFB
Date: 11.16.23
160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
1 2 3 1 2 1 1 1 2 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 831 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No. 1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.05 4.97 5.01 4.94 4.93 4.99 5.04 5.04 5.07 4.94
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00
b. Stop Time for Mixing 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05
c. pH reading after mixing 8.98 8.97 8.86 9.01 9.04 8.64 8.71 8.70 8.87 8.92
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.56 1.56 1.57 1.54 1.53 1.58 1.57 1.59 1.59 1.55
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 832 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.33 100.20 100.20 101.04 100.13 100.15 100.03 101.08 102.13 100.44
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2007 2004 2004 2021 2003 2003 2001 2022 2043 2009
Rotator Number:#1 #1 #1 #1 #1 #1 1102 1102 1102 1102
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.19 5.16 5.35 5.26 5.22 5.36 5.50 5.30 5.32 5.25
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
blank final pH --> 4.92
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1Page 833 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 834 of 1261
Analyst: DFB
Date: 11.16.23
184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
1 1 1 2 1 2 1 1 1 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 835 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No. 1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.1 4.99 5.00 5.07 5.06 4.98 4.96 5.09 5.05 5.02
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40
b. Stop Time for Mixing 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45
c. pH reading after mixing 7.92 9.95 12.10 9.29 7.66 8.07 8.23 7.92 8.21 10.66
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.73 1.89 10.62 4.54 1.58 1.55 1.54 1.76 1.63 2.25
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2 Fluid 2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 836 of 1261
Analyst: DFB
Login No. 184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.25 100.24 100.58 101.16 100.44 100.10 100.22 100.92 100.25
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2005 2005 2012 2023 2009 2002 2004 2018 2005
Rotator Number:Blue Blue 1108 1102 1102 Blue Blue Blue Blue
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 0.0 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 0.0 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.22 6.21 7.20 5.06 7.17 5.03 5.00 5.08 5.62
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2Page 837 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 838 of 1261
2000144860 Started 11-17-2023, Finished 11-17-2023.ltd
Recorder has been downloaded 11/17/2023 5:18:22 PM (UTC -07:00, standard 'me)
Alarm Status
Lower
Upper
OK
OK
Recorder Configura on
Start type :
Start delay :
Interval :
Alert indicator :
OK indicator :
Push bu on start
1 Minute
10 Minutes
Enabled lower & upper
Enabled
Temperature alarms
Lower :
Upper :
21.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
25.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
Recorder Info
Serial # :
User ID :
2000144860
TCLP 2 (-0.6)
Model :TRIX-8 Ba6ery :OK Trip # :265
Recorded Data
First reading :
Last reading :
Elapsed Time :
Total readings :
First evaluated :
Last evaluated :
Evaluated Time :
Evaluated Readings :
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
146
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
101
Temperature sta's'cs
Lowest :
Highest :
Average reading :
Standard Devia'on (S) :
Mean Kine'c Temperature
22.5 °C
@ 11/17/2023 12:26:53 PM
24.3 °C
@ 11/17/2023 12:46:53 AM
23.0 °C
0.4 °C
22.98 °C
Lower Alarm
Triggered :
Time below :
Occurrences :
°C - Minutes below :
(none)
(none)
0
0.00
Upper Alarm
Triggered :
Time above :
Occurrences :
°C - Minutes above :
(none)
(none)
0
0.00
Readings (°C)Inspection Mark
25.0 25.0
24.5 24.5
24.0 24.0
23.5 23.5
23.0 23.0
22.5 22.5
22.0 22.0
12:36:53 AM
11/17/2023
5:16:53 PM
11/17/2023
3:06:53 AM
11/17/2023
5:36:53 AM
11/17/2023
8:06:53 AM
11/17/2023
10:36:53 AM
11/17/2023
1:06:53 PM
11/17/2023
Events Info
11/17/2023 12:46:53 AM Inspec on
Page 1 of 111/17/2023 5:19:22 PM
Page 839 of 1261
Analyst: DFB
Date: 11.16.23
160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
1 2 3 1 2 1 1 1 2 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 840 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No. 1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.05 4.97 5.01 4.94 4.93 4.99 5.04 5.04 5.07 4.94
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00
b. Stop Time for Mixing 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05
c. pH reading after mixing 8.98 8.97 8.86 9.01 9.04 8.64 8.71 8.70 8.87 8.92
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.56 1.56 1.57 1.54 1.53 1.58 1.57 1.59 1.59 1.55
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 841 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.33 100.20 100.20 101.04 100.13 100.15 100.03 101.08 102.13 100.44
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2007 2004 2004 2021 2003 2003 2001 2022 2043 2009
Rotator Number:#1 #1 #1 #1 #1 #1 1102 1102 1102 1102
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.19 5.16 5.35 5.26 5.22 5.36 5.50 5.30 5.32 5.25
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
blank final pH --> 4.92
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1Page 842 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 843 of 1261
Analyst: DFB
Date: 11.16.23
184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
1 1 1 2 1 2 1 1 1 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 844 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No. 1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.1 4.99 5.00 5.07 5.06 4.98 4.96 5.09 5.05 5.02
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40
b. Stop Time for Mixing 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45
c. pH reading after mixing 7.92 9.95 12.10 9.29 7.66 8.07 8.23 7.92 8.21 10.66
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.73 1.89 10.62 4.54 1.58 1.55 1.54 1.76 1.63 2.25
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2 Fluid 2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 845 of 1261
Analyst: DFB
Login No. 184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.25 100.24 100.58 101.16 100.44 100.10 100.22 100.92 100.25
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2005 2005 2012 2023 2009 2002 2004 2018 2005
Rotator Number:Blue Blue 1108 1102 1102 Blue Blue Blue Blue
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 0.0 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 0.0 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.22 6.21 7.20 5.06 7.17 5.03 5.00 5.08 5.62
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2Page 846 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 847 of 1261
2000144860 Started 11-17-2023, Finished 11-17-2023.ltd
Recorder has been downloaded 11/17/2023 5:18:22 PM (UTC -07:00, standard 'me)
Alarm Status
Lower
Upper
OK
OK
Recorder Configura on
Start type :
Start delay :
Interval :
Alert indicator :
OK indicator :
Push bu on start
1 Minute
10 Minutes
Enabled lower & upper
Enabled
Temperature alarms
Lower :
Upper :
21.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
25.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
Recorder Info
Serial # :
User ID :
2000144860
TCLP 2 (-0.6)
Model :TRIX-8 Ba6ery :OK Trip # :265
Recorded Data
First reading :
Last reading :
Elapsed Time :
Total readings :
First evaluated :
Last evaluated :
Evaluated Time :
Evaluated Readings :
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
146
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
101
Temperature sta's'cs
Lowest :
Highest :
Average reading :
Standard Devia'on (S) :
Mean Kine'c Temperature
22.5 °C
@ 11/17/2023 12:26:53 PM
24.3 °C
@ 11/17/2023 12:46:53 AM
23.0 °C
0.4 °C
22.98 °C
Lower Alarm
Triggered :
Time below :
Occurrences :
°C - Minutes below :
(none)
(none)
0
0.00
Upper Alarm
Triggered :
Time above :
Occurrences :
°C - Minutes above :
(none)
(none)
0
0.00
Readings (°C)Inspection Mark
25.0 25.0
24.5 24.5
24.0 24.0
23.5 23.5
23.0 23.0
22.5 22.5
22.0 22.0
12:36:53 AM
11/17/2023
5:16:53 PM
11/17/2023
3:06:53 AM
11/17/2023
5:36:53 AM
11/17/2023
8:06:53 AM
11/17/2023
10:36:53 AM
11/17/2023
1:06:53 PM
11/17/2023
Events Info
11/17/2023 12:46:53 AM Inspec on
Page 1 of 111/17/2023 5:19:22 PM
Page 848 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
McConnell, Mitchel S
11/20/23 14:39
11/20/23 08:41634516
Batch Method:
Eurofins Denver
3010A
Lab Sample ID Client Sample ID Method Chain Basis Initial pH InitialAmount FinalAmount CPI TCLP Spk
00006
Prep spike1IV
00014
Prep spike2IV
00013
<2 SU 10 mL 50 mL3010A, 6010DLB
280-634317/1-A
<2 SU 10 mL 50 mL 0.1 mL 0.5 mL 0.5 mL3010A, 6010DLCS
280-634317/2-A
ST071-SoilIDW-11
092023
<2 SU 10 mL 50 mL3010A, 6010D P280-184424-B-1-
A
Batch Notes
Digestion Tube/Cup ID 2304355
Pipette/Syringe/Dispenser ID MET209+MET88
Analyst ID - Spike Analyst MM
Sufficient Volume for Batch QC YES
Hydrochloric Acid ID 231496
Nitric Acid ID 232616
Digestion Unit ID 09
Thermometer ID 940756
Thermometer Location ID D3
Temperature - Uncorrected - Start 94 Degrees C
Temperature - Corrected - Start 93 Degrees C
Digestion Start Time 11/20/2023 08:41
Digestion End Time 11/20/2023 14:39
Temperature - Uncorrected - End 94 Degrees C
Temperature - Corrected - End 93 Degrees C
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 16010D
Page 849 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/17/23 23:11
11/17/23 00:38634317
Batch Method:
Eurofins Denver
1311
Lab Sample ID Client Sample ID Method Chain Basis ExtractFluid
T11311, 7470A,
7470A
LB 280-634317/1
T11311, 7470A,
7470A
LCS
280-634317/2
ST071-SoilIDW-11
092023
T11311, 7470A,
7470A
P280-184424-B-1
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 27470A
Page 850 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bourgery, David F
11/17/23 23:11
11/17/23 00:38634317
Batch Method:
Eurofins Denver
1311
Batch Notes
Thermometer ID 311846
First Start time 11/17/2023 00:38
First End time 11/17/2023 17:11
Rotator ID #1 1108 1102 Blue
Tumbler Rotations per Minute 29 29 29 31
Balance ID 42605617
Balance is Level? (Y/N)y
pH Meter Calibration Slope 99.9
Water Bath Thermometer ID 311846
TCLP Fluid 1 ID T1_00469
TCLP Fluid 1 pH 4.93 SU
TCLP Fluid 2 ID T2_00161
TCLP Fluid 2 pH 2.89 SU
pH Buffer 1 ID 2271
pH Buffer 2 ID 223591
pH Buffer 3 ID 2133
pH Buffer 4 ID 221687
Lot # of Nitric Acid NitricAcid_00009
1N HCl ID 1N HCL_00055
Uncorrected Maximum Temperature 24.3 Degrees C
Maximum Temperature 23.7 Degrees C
Uncorrected Minimum Temperature 22.5 Degrees C
Minimum Temperature 21.9 Degrees C
Analyst ID - Filtration DB
Filtration Date 11.17.23
Batch Comment DV-IP-0011
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 27470A
Page 851 of 1261
Analyst: DFB
Date: 11.16.23
160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
1 2 3 1 2 1 1 1 2 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 852 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No. 1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.05 4.97 5.01 4.94 4.93 4.99 5.04 5.04 5.07 4.94
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00
b. Stop Time for Mixing 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05
c. pH reading after mixing 8.98 8.97 8.86 9.01 9.04 8.64 8.71 8.70 8.87 8.92
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.56 1.56 1.57 1.54 1.53 1.58 1.57 1.59 1.59 1.55
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 853 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.33 100.20 100.20 101.04 100.13 100.15 100.03 101.08 102.13 100.44
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2007 2004 2004 2021 2003 2003 2001 2022 2043 2009
Rotator Number:#1 #1 #1 #1 #1 #1 1102 1102 1102 1102
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.19 5.16 5.35 5.26 5.22 5.36 5.50 5.30 5.32 5.25
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
blank final pH --> 4.92
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1Page 854 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 855 of 1261
Analyst: DFB
Date: 11.16.23
184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
1 1 1 2 1 2 1 1 1 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 856 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No. 1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.1 4.99 5.00 5.07 5.06 4.98 4.96 5.09 5.05 5.02
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40
b. Stop Time for Mixing 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45
c. pH reading after mixing 7.92 9.95 12.10 9.29 7.66 8.07 8.23 7.92 8.21 10.66
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.73 1.89 10.62 4.54 1.58 1.55 1.54 1.76 1.63 2.25
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2 Fluid 2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 857 of 1261
Analyst: DFB
Login No. 184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.25 100.24 100.58 101.16 100.44 100.10 100.22 100.92 100.25
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2005 2005 2012 2023 2009 2002 2004 2018 2005
Rotator Number:Blue Blue 1108 1102 1102 Blue Blue Blue Blue
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 0.0 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 0.0 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.22 6.21 7.20 5.06 7.17 5.03 5.00 5.08 5.62
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2Page 858 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 859 of 1261
2000144860 Started 11-17-2023, Finished 11-17-2023.ltd
Recorder has been downloaded 11/17/2023 5:18:22 PM (UTC -07:00, standard 'me)
Alarm Status
Lower
Upper
OK
OK
Recorder Configura on
Start type :
Start delay :
Interval :
Alert indicator :
OK indicator :
Push bu on start
1 Minute
10 Minutes
Enabled lower & upper
Enabled
Temperature alarms
Lower :
Upper :
21.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
25.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
Recorder Info
Serial # :
User ID :
2000144860
TCLP 2 (-0.6)
Model :TRIX-8 Ba6ery :OK Trip # :265
Recorded Data
First reading :
Last reading :
Elapsed Time :
Total readings :
First evaluated :
Last evaluated :
Evaluated Time :
Evaluated Readings :
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
146
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
101
Temperature sta's'cs
Lowest :
Highest :
Average reading :
Standard Devia'on (S) :
Mean Kine'c Temperature
22.5 °C
@ 11/17/2023 12:26:53 PM
24.3 °C
@ 11/17/2023 12:46:53 AM
23.0 °C
0.4 °C
22.98 °C
Lower Alarm
Triggered :
Time below :
Occurrences :
°C - Minutes below :
(none)
(none)
0
0.00
Upper Alarm
Triggered :
Time above :
Occurrences :
°C - Minutes above :
(none)
(none)
0
0.00
Readings (°C)Inspection Mark
25.0 25.0
24.5 24.5
24.0 24.0
23.5 23.5
23.0 23.0
22.5 22.5
22.0 22.0
12:36:53 AM
11/17/2023
5:16:53 PM
11/17/2023
3:06:53 AM
11/17/2023
5:36:53 AM
11/17/2023
8:06:53 AM
11/17/2023
10:36:53 AM
11/17/2023
1:06:53 PM
11/17/2023
Events Info
11/17/2023 12:46:53 AM Inspec on
Page 1 of 111/17/2023 5:19:22 PM
Page 860 of 1261
Analyst: DFB
Date: 11.16.23
160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
1 2 3 1 2 1 1 1 2 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 861 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No. 1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.05 4.97 5.01 4.94 4.93 4.99 5.04 5.04 5.07 4.94
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00 19:00
b. Stop Time for Mixing 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05 19:05
c. pH reading after mixing 8.98 8.97 8.86 9.01 9.04 8.64 8.71 8.70 8.87 8.92
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11 20:11
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21 20:21
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.56 1.56 1.57 1.54 1.53 1.58 1.57 1.59 1.59 1.55
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 862 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.33 100.20 100.20 101.04 100.13 100.15 100.03 101.08 102.13 100.44
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2007 2004 2004 2021 2003 2003 2001 2022 2043 2009
Rotator Number:#1 #1 #1 #1 #1 #1 1102 1102 1102 1102
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.19 5.16 5.35 5.26 5.22 5.36 5.50 5.30 5.32 5.25
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
blank final pH --> 4.92
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1Page 863 of 1261
Analyst: DFB
Login No.160-51789 160-51789 160-51789 160-51790 160-51790 160-51875 160-51876 160-51885 160-51885 160-51886
Sample No.1 2 3 1 2 1 1 1 2 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 1
Page 864 of 1261
Analyst: DFB
Date: 11.16.23
184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
1 1 1 2 1 2 1 1 1 1
1 1 1 1 1 1 1 1 1 1
X X X X X X X X X X
B. Percent Solid Phase
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Thermometer Correction Factor
0 0 0 0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Comments:
(Total weight wet solids, B.4) = (Weight subsample, B.2.c) - (Weight filtrate, B.3.c) (Vol of initail filtrate, B.7) = (Weight of filtrate, B.3.c) / (Denisity of filtrate, B.3.d)
DV-IP-0012
TCLP/SPLP Worksheet No. 1
Sample Description
(Weight percent wet solids, B.5.) = 100 X (Total weight wet solids, B.4.) / (Weight of subsample, B.2.c.)
(Net Weight of Subsample, B.2.c) = (gross weight, B.2.a) - (tare weight, B.2.b)
(Net Weight of Filtrate, B.3.c) = (gross weight, B.3.a) - (tare weight, B.3.b)
8. Vol. of initial organic filtrate (mL)
6. Weight percent solids (dry)
d. Oven Temp (observed) (oC)
a. gross dry weight 1 (g)
a. gross weight (g)
b. tare weight (g)
c. net weight (g)
d. density of filtrate (g/mL)
4. Total weight wet solids (g)
7. Vol. of initial aqueous filtrate (mL)
Oven Temp Actual (oC)
Login No.
Sample No.
A. Sample Description
Number of phases
b. gross dry weight 2 (g)
c. percent dry solids (%)
b. tare weight (g)
c. net weight (g)
3. Weight of filtrate
5. Weight percent solids (wet) (%)
1. Weight of filter (g)
2. Weight of subsample
a. gross weight (g)
c. heavier than water
1. Solid
2. Liquid
a. lighter than water
b. water
Balance ID
 

 .B.2.c subsample ofWeight
B.1 filter, ofWeight blank is B.6.a if B.6.aor B.6.b 1,or 2 dry weight Gross 100 B.6.c solids,dry percent Weight 
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 865 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No. 1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? (<1mm) Yes/No N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Sample weight, 5.0 +/- 0.1g 5.1 4.99 5.00 5.07 5.06 4.98 4.96 5.09 5.05 5.02
4. Add 96.5 (+/- 2% or 94.57mL to 98.43mL)
a. Pipette ID or Grad Cylinder ID TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2 TCLP T2
5. Initial pH (after 5 min. mixing time)
a. Start Time for Mixing 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40 19:40
b. Stop Time for Mixing 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45 19:45
c. pH reading after mixing 7.92 9.95 12.10 9.29 7.66 8.07 8.23 7.92 8.21 10.66
6. If pH > 5.0, then add 3.5 mL 1N HCL & mark "X"X X X X X X X X X X
a. HCL Lot# used 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055 1 NHCl_00055
b. Pipette ID TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2 TCLP#2
7. Secondary pH (after 10min at 50C to 55C)
a. Thermometer ID 311846 311846 311846 311846 311846 311846 311846 311846 311846 311846
Termometer Correction Factor 1 1 1 1 1 1 1 1 1 1
b. Start Time 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00 21:00
c. Start Temperature (Observed)49 49 49 49 49 49 49 49 49 49
Start Temperature (Actual)50 50 50 50 50 50 50 50 50 50
d. Finish Time 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10 21:10
e. Finish Temperature (Observed)50 50 50 50 50 50 50 50 50 50
Finish Temperature (Actual)51 51 51 51 51 51 51 51 51 51
f. pH reading after heating (temperature corrected)1.73 1.89 10.62 4.54 1.58 1.55 1.54 1.76 1.63 2.25
1. If pH from C.5. or C.7.f. is <5.0 use Leach Fluid #1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1 Fluid 1
2. If pH from C.7.f is > 5.0, use Leach Fluid #2 Fluid 2
3. SPLP Fluid 1: Soils- East of the Mississippi River;
Wastewates; or Wastewaters
4. SPLP Fluid 2: Soils- West of Mississippi River
5. SPLP Fluid 3: If VOCs or Cyanide containing wastes.
6. X if filtrate and fluid are miscible
DV-IP-0012
C. Leach Fluid Determination- Does not apply to determination of volatile organic components or SPLP.
D. Selection of Leach Fluid
TCLP Worksheet No. 2
Selection of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 866 of 1261
Analyst: DFB
Login No. 184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Particle size reduction? Yes/no N N N N N N N N N N
If yes, write NCM descibing how.
2. Balance ID 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617 42605617
3. Weight of wet solids after filtration (g)100.25 100.24 100.58 101.16 100.44 100.10 100.22 100.92 100.25
Fluid Type from Wksht 2 TCLP 1 TCLP 1 TCLP 2 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1 TCLP 1
1. TCLP Fluid 1 Lot #T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469 T1_00469
2. TCLP Fluid 2 Lot #
3. SPLP 1 (East) Lot #
4. SPLP 2 (West) Lot #
5. pH of leach fluid 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93 4.93
6. Vol of Fluid = wet solids x 20 (mL)2005 2005 2012 2023 2009 2002 2004 2018 2005
Rotator Number:Blue Blue 1108 1102 1102 Blue Blue Blue Blue
1. Rotator speed between 28-32 RPM?Y Y Y Y Y Y Y Y Y
2. Leach start date and time 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38 11/17/23 0:38
3. Leach stop date and time 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11 11/17/23 17:11
4. Room temperature
Thermometer Correction Factor -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6 -0.6
a.Temp Min (Observed) (oC)24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3 24.3
b.Temp Max (Observed) (oC)22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5 22.5
c.Temp Min (Actual) (oC)23.7 23.7 0.0 23.7 23.7 23.7 23.7 23.7 23.7 23.7
d.Temp Max (Actual) (oC)21.9 21.9 0.0 21.9 21.9 21.9 21.9 21.9 21.9 21.9
5. pH of leachate 5.22 6.21 7.20 5.06 7.17 5.03 5.00 5.08 5.62
Was the sample multiphasic?#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6. Volume of leachate (mL)
a. Oil recovered from leachate (mL)
7. Volume of initial filtrate for
recombination (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
8. Combined initial filtrate + leachate (mL)#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
COMMENTS:
(Volume of Fluid, F.4) = (Weight of wet solids, E.3) X 20
(Vol. of Combined Filtrate and Leachate, G.8) = (Vol of Leachate, G.6) + (Vol of Filtrate, G.7)
G. Record of Leach - leach period is 16 to 20 hours
F. Determination of Amount of Leach Fluid
DV-IP-0012
TCLP/SPLP Worksheet No. 3
Bottle Leach Procedure for Metals and Semi-Volatile Organic Components
E. Determination of Sample Size
 

 

 
 B.7trat,InitialFilF.6,FluidAdded
G.6covered,LeachateRe
B.4 Solids, Wet Tot.
E.3 Leachated, Solids G.7 ion,Recombinatfor Filtrate Inital of Vol.
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2Page 867 of 1261
Analyst: DFB
Login No.184420 184424 184443 184475 184529 184529 184531 184591 184612 184613
Sample No.1 1 1 2 1 2 1 1 1 1
1. Balance ID 42605617 42605617 42605617 42605617 42605617
2. ZHE vessel number
3. Weight of material added to ZHE (g)
"X" if there was headspace in container.
4. Weight of filtrate in syringe
a. gross weight (g)
b. tare weight (g)
c. net weight (g) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5. Volume of filtrate in syringe (mL)
6. Wet solids in ZHE (g)
7. Weight of fluid to add (g) 0 0 0 0 0 0 0 0 0 0
a. TCLP Fluid 1 Lot #
b. SPLP Fluid 3 Lot #
c. pH of Blank Fluid
8. Percent Wet Solids (%) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Rotator Number:
1. Leak Check
a. Reading #1 (psi)
b. Reading #2 (psi)
2. Rotator speed between 28 and 32 RPM?
3. Leach start date & time
4. Leach stop date & time
5. Room temperature
Thermometer Correction Factor
a.Temp Min (Observed) (oC)
b.Temp Max (Observed) (oC)
c.Temp Min (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d. Temp Max (Actual) (oC)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
6. X if still under positive pressure after leaching
7. Volume of leachate recovered (mL)
a. Volume of oil recovered after leaching
8. Vol. of initial aqueous filtrate for recombination
a. Calculated from Worksheet 1 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
b. Calculated from Worksheet 4 (mL) #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
(Net Weight of Filtrate, H.4.c) = (Gross weight, H.4.a.) - (Tare weight, H.4.b.)
(Wet Solids in ZHE, H.6) = (Weight of material added to ZHE, H.3.) - (net weight of filtrate, H.4.c.) (Vol of Filtrate for recombination, I.7.b) = (Vol of Leachate Recvd, I.6) X (Weight of Filtrate, H.4.c) / (Vol Fluid Added, H.7.)
(Weight of Fluid to add, H.7.) = (Wet Solids in ZHE, H.6) X 20 (Vol of Filtrate for recombination, I.7.a) = [ (Wet Solids in ZHE, H.6.) / (Tot Wet Solids, B.4) ] X [ (Vol Leachate Recvd, I.6.) / (Vol Fluid Add, H.7.) ] X (Vol Filtrate, B.7.)
COMMENTS:
I. Record of ZHE Leach - the Leach period is 16 to 20 hours.
(Percent Wet Solids, H.8.) = 100 X [ (Wet Solids in ZHE, H.6) / (Weight of material added to ZHE, H.3) ]
DV-IP-0012
TCLP/SPLP Worksheet No. 4
ZHE Leach
H.Determination of Amount of Leach Fluid
G:\OrgPrep\TCLP\TCLP Worksheets\Done 2023\November 2023\11-16-2023 2
Page 868 of 1261
2000144860 Started 11-17-2023, Finished 11-17-2023.ltd
Recorder has been downloaded 11/17/2023 5:18:22 PM (UTC -07:00, standard 'me)
Alarm Status
Lower
Upper
OK
OK
Recorder Configura on
Start type :
Start delay :
Interval :
Alert indicator :
OK indicator :
Push bu on start
1 Minute
10 Minutes
Enabled lower & upper
Enabled
Temperature alarms
Lower :
Upper :
21.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
25.6 °C a'er 3 Consecu ve
or a'er 3 Accumula ve
Recorder Info
Serial # :
User ID :
2000144860
TCLP 2 (-0.6)
Model :TRIX-8 Ba6ery :OK Trip # :265
Recorded Data
First reading :
Last reading :
Elapsed Time :
Total readings :
First evaluated :
Last evaluated :
Evaluated Time :
Evaluated Readings :
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
146
11/17/2023 12:36:53 AM
11/17/2023 5:16:53 PM
16 Hours, 40 Minutes
101
Temperature sta's'cs
Lowest :
Highest :
Average reading :
Standard Devia'on (S) :
Mean Kine'c Temperature
22.5 °C
@ 11/17/2023 12:26:53 PM
24.3 °C
@ 11/17/2023 12:46:53 AM
23.0 °C
0.4 °C
22.98 °C
Lower Alarm
Triggered :
Time below :
Occurrences :
°C - Minutes below :
(none)
(none)
0
0.00
Upper Alarm
Triggered :
Time above :
Occurrences :
°C - Minutes above :
(none)
(none)
0
0.00
Readings (°C)Inspection Mark
25.0 25.0
24.5 24.5
24.0 24.0
23.5 23.5
23.0 23.0
22.5 22.5
22.0 22.0
12:36:53 AM
11/17/2023
5:16:53 PM
11/17/2023
3:06:53 AM
11/17/2023
5:36:53 AM
11/17/2023
8:06:53 AM
11/17/2023
10:36:53 AM
11/17/2023
1:06:53 PM
11/17/2023
Events Info
11/17/2023 12:46:53 AM Inspec on
Page 1 of 111/17/2023 5:19:22 PM
Page 869 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Snowden, Kristen M
11/27/23 16:45
11/27/23 14:45635179
Batch Method:
Eurofins Denver
7470A
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount Hg Daily Spk
03482
30 mL 50 mL7470A, 7470ALB
280-634317/1-A
30 mL 50 mL 1.5 mL7470A, 7470ALCS
280-634317/2-A
ST071-SoilIDW-11
092023
30 mL 50 mL7470A, 7470A P280-184424-B-1-
A
ST071-SoilIDW-11
092023
30 mL 50 mL 1.5 mL7470A, 7470A P280-184424-B-1-
A MS
ST071-SoilIDW-11
092023
30 mL 50 mL 1.5 mL7470A, 7470A P280-184424-B-1-
A MSD
Batch Notes
Digestion Tube/Cup ID 2211204
Pipette/Syringe/Dispenser ID MET206/81/122
Analyst ID - Spike Analyst KS
Sufficient Volume for Batch QC YES
Nitric Acid ID 232617
Sulfuric Acid ID 225553
Potassium Permanganate ID 230512
Potassium Persulfate ID 214655
Digestion Unit ID 15
Thermometer ID 860401
Temperature - Uncorrected - Start 90 Degrees C
Temperature - Corrected - Start 91 Degrees C
Digestion Start Time 11/27/23 14:45
Digestion End Time 11/27/23 16:45
Temperature - Uncorrected - End 92 Degrees C
Temperature - Corrected - End 93 Degrees C
Hydroxylamine ID NACL222774/HA215679
Basis Basis Description
P TCLP
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 17470A
Page 870 of 1261
Lab Name:Job No.:
SDG No.:
METALS BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Snowden, Kristen M
11/27/23 16:45
11/27/23 14:45635180
Batch Method:
Eurofins Denver
245.1
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount Hg Biwk ICV
00405
Hg Daily Spk
03482
30 mL 50 mL 0.3 mL245.1, 7470AICV
280-635180/9
30 mL 50 mL245.1, 7470AICB
280-635180/10
30 mL 50 mL 0.06 mL245.1, 7470ACRA
280-635180/11
30 mL 50 mL 1.5 mL245.1, 7470ACCV
280-635180/12
30 mL 50 mL245.1, 7470ACCB
280-635180/13
Batch Notes
Digestion Tube/Cup ID 2211204
Pipette/Syringe/Dispenser ID MET206/81/122
Analyst ID - Spike Analyst KS
Sufficient Volume for Batch QC YES
Nitric Acid ID 232617
Sulfuric Acid Lot Number 225553
Potassium Permanganate ID 230512
Potassium Persulfate ID 214655
Digestion Unit ID 5A
Thermometer ID 761950
Temperature - Uncorrected - Start 90 Degrees C
Temperature - Corrected - Start 92 Degrees C
Digestion Start Time 11/27/2023 14:45
Digestion End Time 11/27/2023 16:45
Temperature - Uncorrected - End 92 Degrees C
Temperature - Corrected - End 94 Degrees C
Hydroxylamine ID NACL222774/HA215679
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 17470A
Page 871 of 1261
Solution Name: icis
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
icis 11/20/2023 10:21:18 AM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000000 ppm N/A N/A -594.855658 0.000000
Ag (328.068 nm)0.000000 ppm N/A N/A -29.272600 0.000000
Al (394.401 nm)0.000000 ppm N/A N/A 451.460000 0.000000
Al H (396.152 nm)0.000000 ppm N/A N/A 49.229900 0.000000
As (188.980 nm)0.000000 ppm N/A N/A -3.404450 0.000000
B (249.678 nm)0.000000 ppm N/A N/A 16.180800 0.000000
Ba (493.408 nm)0.000000 ppm N/A N/A -0.597230 0.000000
Be (234.861 nm)0.000000 ppm N/A N/A 39.860600 0.000000
Bi (223.061 nm)0.000000 ppm N/A N/A 4.085080 0.000000
Ca (315.887 nm)0.000000 ppm N/A N/A -24.012578 0.000000
Cd (214.439 nm)0.000000 ppm N/A N/A 0.077711 0.000000
Co (228.615 nm)0.000000 ppm N/A N/A 42.851000 0.000000
Cr (205.560 nm)0.000000 ppm N/A N/A 1.524180 0.000000
Cu (324.754 nm)0.000000 ppm N/A N/A 765.019000 0.000000
Fe (238.204 nm)0.000000 ppm N/A N/A 16.603805 0.000000
Fe H (259.940 nm)0.000000 ppm N/A N/A 12.162500 0.000000
K (766.491 nm)0.000000 ppm N/A N/A -447.413000 0.000000
Li (670.783 nm)0.000000 ppm N/A N/A -4280.600000 0.000000
Mg (279.078 nm)0.000000 ppm N/A N/A 9.030250 0.000000
Mn (257.610 nm)0.000000 ppm N/A N/A 4.482260 0.000000
Mo (202.032 nm)0.000000 ppm N/A N/A 3.478080 0.000000
Na (589.592 nm)0.000000 ppm N/A N/A 1036.930000 0.000000
Na H (589.593 nm)0.000000 ppm N/A N/A 2035.854647 0.000000
Ni (231.604 nm)0.000000 ppm N/A N/A -10.211100 0.000000
P (213.618 nm)0.000000 ppm N/A N/A 3.132180 0.000000
Pb (220.353 nm)0.000000 ppm N/A N/A -1.625940 0.000000
S (181.972 nm)0.000000 ppm N/A N/A 24.063425 0.000000
Sb (206.834 nm)0.000000 ppm N/A N/A 2.006790 0.000000
Se (196.026 nm)0.000000 ppm N/A N/A 5.015340 0.000000
Si (288.158 nm)0.000000 ppm N/A N/A 711.776000 0.000000
Sn (189.925 nm)0.000000 ppm N/A N/A 2.280900 0.000000
Sr (421.552 nm)0.000000 ppm N/A N/A 9.681729 0.000000
Th (288.505 nm)0.000000 ppm N/A N/A 260.518000 0.000000
Ti (336.122 nm)0.000000 ppm N/A N/A -118.090000 0.000000
Tl (190.794 nm)0.000000 ppm N/A N/A -2.488120 0.000000
U (409.013 nm)0.000000 ppm N/A N/A 23.416400 0.000000
V (292.401 nm)0.000000 ppm N/A N/A -39.490500 0.000000
Zn (206.200 nm)0.000000 ppm N/A N/A 4.162910 0.000000
Zr (343.823 nm)0.000000 ppm N/A N/A -7.652800 0.000000
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 1 of 287
Page 872 of 1261
Solution Name: ic1
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ic1 11/20/2023 10:25:20 AM 3:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.000000 ppm N/A N/A 2561248.116303 1.000000
Ag (328.068 nm)1.000000 ppm N/A N/A 53932.600000 1.000000
Al (394.401 nm)1.000000 ppm N/A N/A 12756.900000 1.000000
Al H (396.152 nm)1.000000 ppm N/A N/A 4544.770000 1.000000
As (188.980 nm)1.000000 ppm N/A N/A 827.473000 1.000000
B (249.678 nm)1.000000 ppm N/A N/A 8385.840000 1.000000
Ba (493.408 nm)1.000000 ppm N/A N/A 151453.000000 1.000000
Be (234.861 nm)1.000000 ppm N/A N/A 167114.000000 1.000000
Bi (223.061 nm)2.000000 ppm N/A N/A 2977.660000 2.000000
Ca (315.887 nm)10.000000 ppm N/A N/A 6720.178327 10.000000
Cd (214.439 nm)1.000000 ppm N/A N/A 14946.900000 1.000000
Co (228.615 nm)1.000000 ppm N/A N/A 19111.700000 1.000000
Cr (205.560 nm)1.000000 ppm N/A N/A 4115.830000 1.000000
Cu (324.754 nm)1.000000 ppm N/A N/A 47420.600000 1.000000
Fe (238.204 nm)5.000000 ppm N/A N/A 19698.646543 5.000000
Fe H (259.940 nm)5.000000 ppm N/A N/A 7960.020000 5.000000
K (766.491 nm)100.000000 ppm N/A N/A 179218.000000 100.000000
Li (670.783 nm)1.000000 ppm N/A N/A 32908.800000 1.000000
Mg (279.078 nm)40.000000 ppm N/A N/A 133797.000000 40.000000
Mn (257.610 nm)1.000000 ppm N/A N/A 266826.000000 1.000000
Mo (202.032 nm)1.000000 ppm N/A N/A 4965.560000 1.000000
Na (589.592 nm)ppm N/A N/A 614782.000000
Na H (589.593 nm)ppm N/A N/A 445972.144447
Ni (231.604 nm)1.000000 ppm N/A N/A 3394.890000 1.000000
P (213.618 nm)ppm N/A N/A -66.701700
Pb (220.353 nm)1.000000 ppm N/A N/A 2296.840000 1.000000
S (181.972 nm)ppm N/A N/A 28.558499
Sb (206.834 nm)1.000000 ppm N/A N/A 1220.840000 1.000000
Se (196.026 nm)1.000000 ppm N/A N/A 618.682000 1.000000
Si (288.158 nm)10.000000 ppm N/A N/A 73367.800000 10.000000
Sn (189.925 nm)1.000000 ppm N/A N/A 674.267000 1.000000
Sr (421.552 nm)1.000000 ppm N/A N/A 220809.146834 1.000000
Th (288.505 nm)ppm N/A N/A 331.405000
Ti (336.122 nm)1.000000 ppm N/A N/A 109001.000000 1.000000
Tl (190.794 nm)1.000000 ppm N/A N/A 1083.450000 1.000000
U (409.013 nm)ppm N/A N/A -38.186700
V (292.401 nm)1.000000 ppm N/A N/A 41925.500000 1.000000
Zn (206.200 nm)1.000000 ppm N/A N/A 2160.530000 1.000000
Zr (343.823 nm)1.000000 ppm N/A N/A 81511.700000 1.000000
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 2 of 287
Page 873 of 1261
Solution Name: ic3
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ic3 11/20/2023 10:29:46 AM 3:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)ppm N/A N/A -389.122786
Ag (328.068 nm)ppm N/A N/A -16.486400
Al (394.401 nm)ppm N/A N/A 459.901000
Al H (396.152 nm)ppm N/A N/A 54.612700
As (188.980 nm)ppm N/A N/A 0.242694
B (249.678 nm)ppm N/A N/A 32.500600
Ba (493.408 nm)ppm N/A N/A 12.706000
Be (234.861 nm)ppm N/A N/A 60.146600
Bi (223.061 nm)ppm N/A N/A 4.124910
Ca (315.887 nm)ppm N/A N/A -24.062556
Cd (214.439 nm)ppm N/A N/A -0.146630
Co (228.615 nm)ppm N/A N/A 42.999400
Cr (205.560 nm)ppm N/A N/A 2.819920
Cu (324.754 nm)ppm N/A N/A 764.979000
Fe (238.204 nm)ppm N/A N/A 31.360218
Fe H (259.940 nm)ppm N/A N/A 18.285700
K (766.491 nm)ppm N/A N/A -532.068000
Li (670.783 nm)ppm N/A N/A -4577.600000
Mg (279.078 nm)ppm N/A N/A 13.074300
Mn (257.610 nm)ppm N/A N/A 112.148000
Mo (202.032 nm)ppm N/A N/A 8.258880
Na (589.592 nm)50.000000 ppm N/A N/A 608795.000000 50.000000
Na H (589.593 nm)50.000000 ppm N/A N/A 529384.236573 50.000000
Ni (231.604 nm)ppm N/A N/A -6.535660
P (213.618 nm)ppm N/A N/A 8.026670
Pb (220.353 nm)ppm N/A N/A -2.917870
S (181.972 nm)ppm N/A N/A 15.206254
Sb (206.834 nm)ppm N/A N/A 4.075880
Se (196.026 nm)ppm N/A N/A 3.692170
Si (288.158 nm)ppm N/A N/A 688.279000
Sn (189.925 nm)ppm N/A N/A 2.296680
Sr (421.552 nm)ppm N/A N/A 29.344629
Th (288.505 nm)ppm N/A N/A 261.243000
Ti (336.122 nm)ppm N/A N/A -83.251000
Tl (190.794 nm)ppm N/A N/A -2.052360
U (409.013 nm)ppm N/A N/A 27.539600
V (292.401 nm)ppm N/A N/A -41.861100
Zn (206.200 nm)ppm N/A N/A 1.992240
Zr (343.823 nm)ppm N/A N/A 0.479007
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 3 of 287
Page 874 of 1261
Solution Name: ic2
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ic2 11/20/2023 12:02:03 PM 3:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)ppm N/A N/A 221.618545 !
Ag (328.068 nm)ppm N/A N/A 130.950000 !
Al (394.401 nm)100.000000 !ppm N/A N/A 1323760.000000 !100.000000 !
Al H (396.152 nm)100.000000 !ppm N/A N/A 449471.000000 !100.000000 !
As (188.980 nm)ppm N/A N/A -2.619180 !
B (249.678 nm)ppm N/A N/A -19.654300 !
Ba (493.408 nm)ppm N/A N/A 372.093000 !
Be (234.861 nm)ppm N/A N/A 1412.930000 !
Bi (223.061 nm)ppm N/A N/A 3.460370 !
Ca (315.887 nm)ppm N/A N/A -66.587078 !
Cd (214.439 nm)ppm N/A N/A 15.340300 !
Co (228.615 nm)ppm N/A N/A 52.110700 !
Cr (205.560 nm)ppm N/A N/A 8.235110 !
Cu (324.754 nm)ppm N/A N/A 2507.570000 !
Fe (238.204 nm)100.000000 !ppm N/A N/A 402627.286621 !100.000000 !
Fe H (259.940 nm)100.000000 !ppm N/A N/A 161838.000000 !100.000000 !
K (766.491 nm)ppm N/A N/A -382.477000 !
Li (670.783 nm)ppm N/A N/A -4430.400000 !
Mg (279.078 nm)ppm N/A N/A -416.729000 !
Mn (257.610 nm)ppm N/A N/A -499.691000 !
Mo (202.032 nm)ppm N/A N/A 1.370390 !
Na (589.592 nm)500.000000 !ppm N/A N/A 6073640.000000 !500.000000 !
Na H (589.593 nm)500.000000 !ppm N/A N/A 4468762.642525 !500.000000 !
Ni (231.604 nm)ppm N/A N/A -10.441300 !
P (213.618 nm)10.000000 !ppm N/A N/A 11809.100000 !10.000000 !
Pb (220.353 nm)ppm N/A N/A 1.221260 !
S (181.972 nm)10.000000 !ppm N/A N/A 2060.549351 !10.000000 !
Sb (206.834 nm)ppm N/A N/A 9.334350 !
Se (196.026 nm)ppm N/A N/A 0.553276 !
Si (288.158 nm)ppm N/A N/A 1020.470000 !
Sn (189.925 nm)ppm N/A N/A 2.259380 !
Sr (421.552 nm)ppm N/A N/A 220.270564 !
Th (288.505 nm)10.000000 !ppm N/A N/A 18931.200000 !10.000000 !
Ti (336.122 nm)ppm N/A N/A 50.778200 !
Tl (190.794 nm)ppm N/A N/A -15.338700 !
U (409.013 nm)5.000000 !ppm N/A N/A 22050.900000 !5.000000 !
V (292.401 nm)ppm N/A N/A 532.213000 !
Zn (206.200 nm)ppm N/A N/A 8.407250 !
Zr (343.823 nm)ppm N/A N/A -23.841500 !
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 4 of 287
Page 875 of 1261
Solution Name: S1-8068236
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
S1-8068236 11/20/2023 10:39:05 AM 3:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.019554 ppm 0.005215 0.51 2614733.790726 1.019554
Ag (328.068 nm)1.021170 ppm 0.003925 0.38 54568.300000 1.021170
Al (394.401 nm)1.025020 ppm 0.006019 0.59 13062.900000 1.025020
Al H (396.152 nm)1.012340 ppm 0.003410 0.34 4600.230000 1.012340
As (188.980 nm)1.025990 ppm 0.010530 1.03 849.018000 1.025990
B (249.678 nm)1.020680 ppm 0.002029 0.20 8558.890000 1.020680
Ba (493.408 nm)1.013800 ppm 0.000233 0.02 153558.000000 1.013800
Be (234.861 nm)0.990722 ppm 0.011749 1.19 165629.000000 0.990722
Bi (223.061 nm)2.035540 ppm 0.011164 0.55 3030.500000 2.035540
Ca (315.887 nm)10.117128 ppm 0.019876 0.20 6799.171914 10.117128
Cd (214.439 nm)1.024160 ppm 0.009068 0.89 15309.100000 1.024160
Co (228.615 nm)1.023860 ppm 0.003957 0.39 19607.800000 1.023860
Cr (205.560 nm)1.020060 ppm 0.006552 0.64 4194.160000 1.020060
Cu (324.754 nm)1.019430 ppm 0.003735 0.37 48317.500000 1.019430
Fe (238.204 nm)5.080196 ppm 0.018933 0.37 20027.074755 5.080196
Fe H (259.940 nm)5.051890 ppm 0.015749 0.31 8044.080000 5.051890
K (766.491 nm)102.680000 ppm 0.600003 0.58 184033.000000 102.680000
Li (670.783 nm)1.021810 ppm 0.006806 0.67 33720.100000 1.021810
Mg (279.078 nm)40.865400 ppm 0.326800 0.80 136688.000000 40.865400
Mn (257.610 nm)1.016120 ppm 0.005386 0.53 271126.000000 1.016120
Mo (202.032 nm)1.021300 ppm 0.005022 0.49 5071.230000 1.021300
Na (589.592 nm)50.768900 ppm 0.344947 0.68 630068.000000 50.768900
Na H (589.593 nm)40.483138 Qu ppm 0.063361 0.16 454883.683228 Q 40.483138 Qu
Ni (231.604 nm)1.021710 ppm 0.007042 0.69 3469.590000 1.021710
P (213.618 nm)0.011251 ppm 0.003877 34.46 -65.823500 0.011251
Pb (220.353 nm)1.026770 ppm 0.002891 0.28 2353.870000 1.026770
S (181.972 nm)-0.013127 u ppm 0.008137 61.98 26.445185 -0.013127 u
Sb (206.834 nm)1.023850 ppm 0.008133 0.79 1248.750000 1.023850
Se (196.026 nm)1.025650 ppm 0.011037 1.08 634.562000 1.025650
Si (288.158 nm)10.127200 ppm 0.016343 0.16 74787.500000 10.127200
Sn (189.925 nm)1.020540 ppm 0.012371 1.21 688.069000 1.020540
Sr (421.552 nm)1.015689 ppm 0.001545 0.15 224273.176070 1.015689
Th (288.505 nm)0.057668 ppm 0.002967 5.15 344.394000 0.057668
Ti (336.122 nm)1.020340 ppm 0.004538 0.44 111242.000000 1.020340
Tl (190.794 nm)1.025350 ppm 0.005268 0.51 1108.570000 1.025350
U (409.013 nm)-0.009335 u ppm 0.003407 36.49 -44.598300 -0.009335 u
V (292.401 nm)1.020800 ppm 0.004994 0.49 42468.200000 1.020800
Zn (206.200 nm)1.026120 ppm 0.008584 0.84 2216.850000 1.026120
Zr (343.823 nm)1.019910 ppm 0.004300 0.42 83142.000000 1.019910
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 5 of 287
Page 876 of 1261
Solution Name: S3-7995310
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
S3-7995310 11/20/2023 10:43:19 AM 3:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000095 ppm 0.000030 31.58 -313.832935 0.000095
Ag (328.068 nm)0.000147 u ppm 0.000285 > 100.00 -21.214100 0.000147 u
Al (394.401 nm)0.002293 ppm 0.001176 51.28 479.025000 0.002293
Al H (396.152 nm)-0.002229 u ppm 0.002005 89.96 40.545600 -0.002229 u
As (188.980 nm)0.006513 ppm 0.001688 25.91 2.006790 0.006513
B (249.678 nm)0.001537 ppm 0.000431 28.02 29.041100 0.001537
Ba (493.408 nm)0.000280 ppm 0.000187 66.76 41.809700 0.000280
Be (234.861 nm)0.000146 ppm 0.000042 28.65 64.297000 0.000146
Bi (223.061 nm)0.004280 ppm 0.003532 82.54 10.447800 0.004280
Ca (315.887 nm)-0.001460 u ppm 0.002608 > 100.00 -24.997127 -0.001460 u
Cd (214.439 nm)0.000094 ppm 0.000086 91.84 1.476340 0.000094
Co (228.615 nm)0.000053 ppm 0.000084 > 100.00 43.836700 0.000053
Cr (205.560 nm)-0.000161 u ppm 0.000098 60.96 0.859308 -0.000161 u
Cu (324.754 nm)0.000370 ppm 0.000437 > 100.00 782.730000 0.000370
Fe (238.204 nm)-0.001231 u ppm 0.000826 67.08 11.760276 -0.001231 u
Fe H (259.940 nm)0.093866 u ppm 0.001670 1.78 13.214900 0.093866 u
K (766.491 nm)0.031439 ppm 0.013555 43.11 -390.928000 0.031439
Li (670.783 nm)-0.002041 u ppm 0.002802 > 100.00 -4356.500000 -0.002041 u
Mg (279.078 nm)0.002744 ppm 0.003245 > 100.00 18.192100 0.002744
Mn (257.610 nm)0.000184 ppm 0.000049 26.76 53.632200 0.000184
Mo (202.032 nm)0.001014 ppm 0.000600 59.21 8.509370 0.001014
Na (589.592 nm)50.283300 ppm 0.243085 0.48 612241.000000 50.283300
Na H (589.593 nm)40.226029 u ppm 0.779914 1.94 443823.552078 40.226029 u
Ni (231.604 nm)0.000432 u ppm 0.001313 > 100.00 -8.735980 0.000432 u
P (213.618 nm)0.004062 ppm 0.001025 25.24 7.884680 0.004062
Pb (220.353 nm)0.000165 u ppm 0.001610 > 100.00 -1.251590 0.000165 u
S (181.972 nm)-0.047534 u ppm 0.016613 34.95 14.389678 -0.047534 u
Sb (206.834 nm)-0.000498 u ppm 0.001350 > 100.00 1.395810 -0.000498 u
Se (196.026 nm)-0.002382 u ppm 0.002941 > 100.00 3.553550 -0.002382 u
Si (288.158 nm)-0.001793 u ppm 0.001730 96.48 698.510000 -0.001793 u
Sn (189.925 nm)-0.000443 u ppm 0.001176 > 100.00 1.983300 -0.000443 u
Sr (421.552 nm)0.000072 ppm 0.000029 40.71 25.540494 0.000072
Th (288.505 nm)0.003441 ppm 0.002556 74.28 266.966000 0.003441
Ti (336.122 nm)0.000374 ppm 0.000165 44.18 -77.264300 0.000374
Tl (190.794 nm)0.003299 ppm 0.002127 64.48 1.092770 0.003299
U (409.013 nm)-0.002525 u ppm 0.003006 > 100.00 12.312100 -0.002525 u
V (292.401 nm)0.000161 u ppm 0.000257 > 100.00 -32.541400 0.000161 u
Zn (206.200 nm)-0.000701 u ppm 0.000445 63.55 2.652040 -0.000701 u
Zr (343.823 nm)0.000302 ppm 0.000078 25.78 16.987400 0.000302
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 6 of 287
Page 877 of 1261
Solution Name: s2- 8068255
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
s2- 8068255 11/20/2023 10:47:35 AM 3:6 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000909 u ppm 0.000011 1.22 170.442534 -0.000909 u
Ag (328.068 nm)-0.002625 u ppm 0.000219 8.34 123.560000 -0.002625 u
Al (394.401 nm)107.243000 o ppm 0.506634 0.47 1317940.000000 107.243000 o
Al H (396.152 nm)99.488400 ppm 0.191202 0.19 447172.000000 99.488400
As (188.980 nm)0.002880 u ppm 0.003609 > 100.00 -1.923290 0.002880 u
B (249.678 nm)-0.004308 u ppm 0.000573 13.29 -19.875200 -0.004308 u
Ba (493.408 nm)0.000711 ppm 0.000141 19.83 394.123000 0.000711
Be (234.861 nm)0.000181 ppm 0.000115 63.70 1386.790000 0.000181
Bi (223.061 nm)-0.000682 u ppm 0.000503 73.79 3.070940 -0.000682 u
Ca (315.887 nm)-0.062731 u ppm 0.005765 9.19 -66.319645 -0.062731 u
Cd (214.439 nm)-0.000335 u ppm 0.000089 26.60 15.949900 -0.000335 u
Co (228.615 nm)0.000742 ppm 0.000058 7.78 57.054500 0.000742
Cr (205.560 nm)0.001367 ppm 0.000187 13.65 7.144020 0.001367
Cu (324.754 nm)-0.004111 u ppm 0.000262 6.36 2501.150000 -0.004111 u
Fe (238.204 nm)102.002934 o ppm 0.106444 0.10 401541.866698 102.002934 o
Fe H (259.940 nm)99.617000 ppm 0.088221 0.09 161218.000000 99.617000
K (766.491 nm)0.041744 ppm 0.014435 34.58 -372.414000 0.041744
Li (670.783 nm)-0.002287 u ppm 0.001437 62.83 -4365.650000 -0.002287 u
Mg (279.078 nm)-0.010187 u ppm 0.001098 10.78 -408.416000 -0.010187 u
Mn (257.610 nm)-0.001962 u ppm 0.000023 1.18 -518.976000 -0.001962 u
Mo (202.032 nm)-0.000156 u ppm 0.000136 86.97 2.702210 -0.000156 u
Na (589.592 nm)503.584000 o ppm 1.747140 0.35 6122210.000000 503.584000 o
Na H (589.593 nm)514.848212 ppm 2.914511 0.57 4598763.541400 514.848212
Ni (231.604 nm)0.000022 u ppm 0.000313 > 100.00 -10.132300 0.000022 u
P (213.618 nm)9.906350 ppm 0.037641 0.38 11696.500000 9.906350
Pb (220.353 nm)0.002028 u ppm 0.002308 > 100.00 -0.278918 0.002028 u
S (181.972 nm)10.017047 ppm 0.064390 0.64 2067.897318 10.017047
Sb (206.834 nm)0.000243 u ppm 0.001400 > 100.00 9.358220 0.000243 u
Se (196.026 nm)0.011311 ppm 0.002222 19.65 1.244380 0.011311
Si (288.158 nm)0.034355 ppm 0.002003 5.83 961.619000 0.034355
Sn (189.925 nm)-0.000027 u ppm 0.001851 > 100.00 2.262960 -0.000027 u
Sr (421.552 nm)0.000898 ppm 0.000083 9.29 207.896909 0.000898
Th (288.505 nm)10.000100 ppm 0.026534 0.27 18947.200000 10.000100
Ti (336.122 nm)0.001701 ppm 0.000113 6.62 67.512200 0.001701
Tl (190.794 nm)-0.010370 u ppm 0.002701 26.05 -15.586900 -0.010370 u
U (409.013 nm)4.962990 Q ppm 0.020552 0.41 22140.600000 Q 4.962990 Q
V (292.401 nm)-0.000431 u ppm 0.000216 50.14 523.289000 -0.000431 u
Zn (206.200 nm)0.002103 ppm 0.000141 6.70 8.698450 0.002103
Zr (343.823 nm)-0.000608 u ppm 0.000054 8.95 81.023900 -0.000608 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 7 of 287
Page 878 of 1261
Solution Name: icvh-8079062
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
icvh-8079062 11/20/2023 10:52:09 AM 3:7 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000104 u ppm 0.000016 15.06 -407.207360 -0.000104 u
Ag (328.068 nm)-0.000303 u ppm 0.000128 42.37 -56.849000 -0.000303 u
Al (394.401 nm)39.467700 o ppm 0.108352 0.27 486157.000000 39.467700 o
Al H (396.152 nm)38.596100 ppm 0.087761 0.23 173509.000000 38.596100
As (188.980 nm)0.003790 ppm 0.001463 38.62 -0.974175 0.003790
B (249.678 nm)-0.002991 u ppm 0.000316 10.57 -8.851910 -0.002991 u
Ba (493.408 nm)-0.000715 u ppm 0.000060 8.46 117.351000 -0.000715 u
Be (234.861 nm)0.000220 ppm 0.000038 17.44 1114.080000 0.000220
Bi (223.061 nm)-0.001661 u ppm 0.002018 > 100.00 1.614940 -0.001661 u
Ca (315.887 nm)-0.004446 u ppm 0.006544 > 100.00 -27.010974 -0.004446 u
Cd (214.439 nm)-0.000030 u ppm 0.000208 > 100.00 16.076400 -0.000030 u
Co (228.615 nm)0.001149 ppm 0.000335 29.17 64.768000 0.001149
Cr (205.560 nm)-0.000094 u ppm 0.000577 > 100.00 1.134540 -0.000094 u
Cu (324.754 nm)-0.000861 u ppm 0.000083 9.59 801.971000 -0.000861 u
Fe (238.204 nm)80.377331 o ppm 0.189517 0.24 316414.645486 80.377331 o
Fe H (259.940 nm)78.415300 ppm 0.173329 0.22 126876.000000 78.415300
K (766.491 nm)-0.016743 u ppm 0.040552 > 100.00 -477.494000 -0.016743 u
Li (670.783 nm)-0.004176 u ppm 0.002115 50.65 -4435.880000 -0.004176 u
Mg (279.078 nm)-0.003098 u ppm 0.003139 > 100.00 -59.462100 -0.003098 u
Mn (257.610 nm)0.000352 ppm 0.000029 8.21 98.349500 0.000352
Mo (202.032 nm)0.000201 u ppm 0.000598 > 100.00 4.473980 0.000201 u
Na (589.592 nm)80.564900 o ppm 0.361718 0.45 980327.000000 80.564900 o
Na H (589.593 nm)72.661116 Q ppm 13.7229
64 18.89 727770.933403 Q 72.661116 Q
Ni (231.604 nm)0.000720 u ppm 0.001002 > 100.00 -7.759390 0.000720 u
P (213.618 nm)3.862090 ppm 0.016720 0.43 4562.820000 3.862090
Pb (220.353 nm)0.000897 u ppm 0.001135 > 100.00 -3.480490 0.000897 u
S (181.972 nm)3.775317 Q ppm 0.013540 0.36 795.949973 Q 3.775317 Q
Sb (206.834 nm)0.000579 u ppm 0.002750 > 100.00 8.268260 0.000579 u
Se (196.026 nm)0.009673 ppm 0.004564 47.18 2.510030 0.009673
Si (288.158 nm)0.018055 ppm 0.001359 7.53 843.000000 0.018055
Sn (189.925 nm)0.000788 u ppm 0.002135 > 100.00 2.810590 0.000788 u
Sr (421.552 nm)0.000100 ppm 0.000067 66.79 31.705228 0.000100
Th (288.505 nm)0.013787 Q ppm 0.002835 20.56 285.566000 Q 0.013787 Q
Ti (336.122 nm)0.000247 ppm 0.000099 40.09 -91.120900 0.000247
Tl (190.794 nm)-0.003283 u ppm 0.002320 70.65 -7.501610 -0.003283 u
U (409.013 nm)0.390623 ppm 0.002954 0.76 1823.100000 0.390623
V (292.401 nm)0.000162 u ppm 0.000159 97.69 -53.693500 0.000162 u
Zn (206.200 nm)0.000324 u ppm 0.001206 > 100.00 4.862060 0.000324 u
Zr (343.823 nm)-0.000258 u ppm 0.000060 23.26 80.284000 -0.000258 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 8 of 287
Page 879 of 1261
Solution Name: ICV-8079061
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ICV-8079061 11/20/2023 10:56:26 AM 3:8 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.213281 Q ppm 0.000695 0.33 546632.180561 Q 0.213281 Q
Ag (328.068 nm)0.251049 ppm 0.000774 0.31 13395.900000 0.251049
Al (394.401 nm)0.242794 ppm 0.000424 0.17 3436.980000 0.242794
Al H (396.152 nm)0.255986 u ppm 0.003285 1.28 1201.020000 0.255986 u
As (188.980 nm)0.254062 ppm 0.003984 1.57 207.678000 0.254062
B (249.678 nm)0.247928 ppm 0.000713 0.29 2091.250000 0.247928
Ba (493.408 nm)0.251045 ppm 0.000895 0.36 38024.800000 0.251045
Be (234.861 nm)0.249424 ppm 0.002552 1.02 41728.500000 0.249424
Bi (223.061 nm)0.504178 ppm 0.006605 1.31 753.690000 0.504178
Ca (315.887 nm)2.540462 ppm 0.001854 0.07 1689.323176 2.540462
Cd (214.439 nm)0.253006 ppm 0.000795 0.31 3781.990000 0.253006
Co (228.615 nm)0.253141 ppm 0.000520 0.21 4880.040000 0.253141
Cr (205.560 nm)0.252484 ppm 0.001756 0.70 1039.280000 0.252484
Cu (324.754 nm)0.248379 ppm 0.000910 0.37 12352.200000 0.248379
Fe (238.204 nm)1.271621 ppm 0.002388 0.19 5025.366006 1.271621
Fe H (259.940 nm)1.338470 u ppm 0.004750 0.35 2029.180000 1.338470 u
K (766.491 nm)24.960100 ppm 0.066523 0.27 44397.100000 24.960100
Li (670.783 nm)0.248874 ppm 0.001686 0.68 4974.870000 0.248874
Mg (279.078 nm)9.871790 ppm 0.032476 0.33 33026.300000 9.871790
Mn (257.610 nm)0.253021 ppm 0.000677 0.27 67515.800000 0.253021
Mo (202.032 nm)0.252954 ppm 0.000547 0.22 1258.660000 0.252954
Na (589.592 nm)12.635400 ppm 0.041471 0.33 157578.000000 12.635400
Na H (589.593 nm)2.767325 u ppm 0.310514 11.22 118085.014647 2.767325 u
Ni (231.604 nm)0.252051 ppm 0.000604 0.24 848.239000 0.252051
P (213.618 nm)0.001778 u ppm 0.002897 > 100.00 -14.919900 0.001778 u
Pb (220.353 nm)0.258666 ppm 0.001667 0.64 591.794000 0.258666
S (181.972 nm)-0.029744 u ppm 0.003595 12.09 19.250101 -0.029744 u
Sb (206.834 nm)0.257251 ppm 0.002100 0.82 315.268000 0.257251
Se (196.026 nm)0.248011 ppm 0.002463 0.99 157.245000 0.248011
Si (288.158 nm)2.380080 ppm 0.004314 0.18 18126.200000 2.380080
Sn (189.925 nm)0.251193 ppm 0.001392 0.55 171.079000 0.251193
Sr (421.552 nm)0.251057 ppm 0.000534 0.21 55442.929015 0.251057
Th (288.505 nm)0.016929 ppm 0.002291 13.53 286.337000 0.016929
Ti (336.122 nm)0.250760 ppm 0.000688 0.27 27250.100000 0.250760
Tl (190.794 nm)0.255620 ppm 0.000615 0.24 274.506000 0.255620
U (409.013 nm)-0.003147 u ppm 0.000262 8.33 2.885380 -0.003147 u
V (292.401 nm)0.250470 ppm 0.000857 0.34 10390.500000 0.250470
Zn (206.200 nm)0.253965 ppm 0.000586 0.23 551.804000 0.253965
Zr (343.823 nm)0.256617 ppm 0.000918 0.36 20913.300000 0.256617
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 9 of 287
Page 880 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 11:00:40 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000415 u ppm 0.000005 1.12 -82.949983 -0.000415 u
Ag (328.068 nm)-0.001101 u ppm 0.000031 2.82 57.805500 -0.001101 u
Al (394.401 nm)53.400900 o ppm 0.138506 0.26 656479.000000 53.400900 o
Al H (396.152 nm)50.598300 ppm 0.250452 0.49 227450.000000 50.598300
As (188.980 nm)0.001497 ppm 0.001098 73.33 -2.626400 0.001497
B (249.678 nm)-0.001843 u ppm 0.000203 11.02 0.752519 -0.001843 u
Ba (493.408 nm)0.000163 ppm 0.000142 87.26 170.711000 0.000163
Be (234.861 nm)0.000174 ppm 0.000017 9.71 741.247000 0.000174
Bi (223.061 nm)-0.000804 u ppm 0.000584 72.70 2.890040 -0.000804 u
Ca (315.887 nm)-0.026215 u ppm 0.004043 15.42 -41.692404 -0.026215 u
Cd (214.439 nm)-0.000026 u ppm 0.000092 > 100.00 10.348500 -0.000026 u
Co (228.615 nm)0.000357 ppm 0.000242 67.68 49.680100 0.000357
Cr (205.560 nm)0.000566 ppm 0.000231 40.80 3.852220 0.000566
Cu (324.754 nm)-0.002192 u ppm 0.000372 16.96 1633.510000 -0.002192 u
Fe (238.204 nm)52.093570 o ppm 0.320593 0.62 205078.200647 52.093570 o
Fe H (259.940 nm)50.955900 ppm 0.286799 0.56 82398.000000 50.955900
K (766.491 nm)0.018124 u ppm 0.026648 > 100.00 -414.850000 0.018124 u
Li (670.783 nm)-0.003275 u ppm 0.001863 56.89 -4402.380000 -0.003275 u
Mg (279.078 nm)-0.007267 u ppm 0.001682 23.14 -210.482000 -0.007267 u
Mn (257.610 nm)-0.000969 u ppm 0.000012 1.27 -253.979000 -0.000969 u
Mo (202.032 nm)0.000053 ppm 0.000020 38.08 3.740510 0.000053
Na (589.592 nm)257.694000 o ppm 1.828150 0.71 3133360.000000 257.694000 o
Na H (589.593 nm)252.114333 ppm 0.734107 0.29 2298734.015017 252.114333
Ni (231.604 nm)-0.000427 u ppm 0.000450 > 100.00 -11.663600 -0.000427 u
P (213.618 nm)5.026900 ppm 0.013696 0.27 5936.850000 5.026900
Pb (220.353 nm)0.000399 u ppm 0.001702 > 100.00 -2.303830 0.000399 u
S (181.972 nm)5.013818 ppm 0.012554 0.25 1047.104348 5.013818
Sb (206.834 nm)0.000753 ppm 0.000532 70.61 6.527750 0.000753
Se (196.026 nm)0.009319 ppm 0.001994 21.39 5.263330 0.009319
Si (288.158 nm)0.025257 ppm 0.001086 4.30 895.655000 0.025257
Sn (189.925 nm)0.000966 u ppm 0.001069 > 100.00 2.929760 0.000966 u
Sr (421.552 nm)0.000587 ppm 0.000037 6.25 139.196365 0.000587
Th (288.505 nm)5.131860 ppm 0.012724 0.25 9850.340000 5.131860
Ti (336.122 nm)0.000872 ppm 0.000053 6.07 -22.956700 0.000872
Tl (190.794 nm)-0.003512 u ppm 0.003783 > 100.00 -7.239910 -0.003512 u
U (409.013 nm)2.580020 Q ppm 0.005054 0.20 11518.000000 Q 2.580020 Q
V (292.401 nm)0.000132 u ppm 0.000322 > 100.00 255.627000 0.000132 u
Zn (206.200 nm)0.001151 ppm 0.000632 54.92 6.645730 0.001151
Zr (343.823 nm)-0.000884 u ppm 0.000033 3.71 -9.149920 -0.000884 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 10 of 287
Page 881 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 11:05:04 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.478701 ppm 0.001102 0.23 1227471.548962 0.478701
Ag (328.068 nm)0.511585 ppm 0.001936 0.38 27321.100000 0.511585
Al (394.401 nm)0.508124 ppm 0.002528 0.50 6699.970000 0.508124
Al H (396.152 nm)0.519603 u ppm 0.006918 1.33 2385.760000 0.519603 u
As (188.980 nm)0.514294 ppm 0.004504 0.88 423.888000 0.514294
B (249.678 nm)0.507513 ppm 0.000698 0.14 4263.890000 0.507513
Ba (493.408 nm)0.514722 ppm 0.002134 0.41 77963.400000 0.514722
Be (234.861 nm)0.505408 ppm 0.001650 0.33 84513.600000 0.505408
Bi (223.061 nm)1.030280 ppm 0.007554 0.73 1535.890000 1.030280
Ca (315.887 nm)5.162530 ppm 0.023841 0.46 3457.696103 5.162530
Cd (214.439 nm)0.518470 ppm 0.002869 0.55 7750.100000 0.518470
Co (228.615 nm)0.518025 ppm 0.000761 0.15 9941.630000 0.518025
Cr (205.560 nm)0.520367 ppm 0.003065 0.59 2140.350000 0.520367
Cu (324.754 nm)0.515796 ppm 0.001296 0.25 24827.400000 0.515796
Fe (238.204 nm)2.584785 ppm 0.011603 0.45 10197.817357 2.584785
Fe H (259.940 nm)2.626170 u ppm 0.015395 0.59 4114.970000 2.626170 u
K (766.491 nm)51.795600 ppm 0.387134 0.75 92611.300000 51.795600
Li (670.783 nm)0.514180 ppm 0.003054 0.59 14841.500000 0.514180
Mg (279.078 nm)20.431100 ppm 0.104244 0.51 68342.900000 20.431100
Mn (257.610 nm)0.513084 ppm 0.001321 0.26 136906.000000 0.513084
Mo (202.032 nm)0.515374 ppm 0.001391 0.27 2560.810000 0.515374
Na (589.592 nm)25.950100 ppm 0.172201 0.66 322519.000000 25.950100
Na H (589.593 nm)15.876864 u ppm 0.172377 1.09 235137.753612 15.876864 u
Ni (231.604 nm)0.517911 ppm 0.001271 0.25 1753.720000 0.517911
P (213.618 nm)0.004352 ppm 0.001914 43.99 -33.295700 0.004352
Pb (220.353 nm)0.523429 ppm 0.005381 1.03 1199.180000 0.523429
S (181.972 nm)-0.022968 u ppm 0.005440 23.69 21.925888 -0.022968 u
Sb (206.834 nm)0.511952 ppm 0.003143 0.61 625.442000 0.511952
Se (196.026 nm)0.516354 ppm 0.005911 1.14 321.953000 0.516354
Si (288.158 nm)5.050020 ppm 0.027597 0.55 37653.900000 5.050020
Sn (189.925 nm)0.518753 ppm 0.005037 0.97 350.876000 0.518753
Sr (421.552 nm)0.514233 ppm 0.002066 0.40 113551.984333 0.514233
Th (288.505 nm)0.034606 ppm 0.001142 3.30 313.044000 0.034606
Ti (336.122 nm)0.513207 ppm 0.001125 0.22 55893.800000 0.513207
Tl (190.794 nm)0.519797 ppm 0.002436 0.47 560.769000 0.519797
U (409.013 nm)-0.003728 u ppm 0.000487 13.07 -6.299770 -0.003728 u
V (292.401 nm)0.515297 ppm 0.001595 0.31 21418.000000 0.515297
Zn (206.200 nm)0.519034 ppm 0.002851 0.55 1123.390000 0.519034
Zr (343.823 nm)0.512236 ppm 0.001118 0.22 41753.000000 0.512236
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 11 of 287
Page 882 of 1261
Solution Name: ICB-8064644
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ICB-8064644 11/20/2023 11:09:24 AM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000052 ppm 0.000012 22.20 -457.129944 0.000052
Ag (328.068 nm)-0.000099 u ppm 0.000134 > 100.00 -34.806700 -0.000099 u
Al (394.401 nm)0.001192 ppm 0.000757 63.46 465.430000 0.001192
Al H (396.152 nm)-0.000368 u ppm 0.002878 > 100.00 48.912600 -0.000368 u
As (188.980 nm)0.001190 ppm 0.001720 > 100.00 -2.415930 0.001190
B (249.678 nm)0.000651 ppm 0.000248 38.03 21.633400 0.000651
Ba (493.408 nm)0.000119 ppm 0.000024 20.21 17.389700 0.000119
Be (234.861 nm)0.000009 u ppm 0.000017 > 100.00 41.437100 0.000009 u
Bi (223.061 nm)0.001230 u ppm 0.002801 > 100.00 5.913690 0.001230 u
Ca (315.887 nm)0.008641 ppm 0.003409 39.46 -18.184980 0.008641
Cd (214.439 nm)-0.000009 u ppm 0.000253 > 100.00 -0.057660 -0.000009 u
Co (228.615 nm)0.000213 ppm 0.000148 69.37 46.910100 0.000213
Cr (205.560 nm)0.000120 u ppm 0.000194 > 100.00 2.014530 0.000120 u
Cu (324.754 nm)0.000108 ppm 0.000043 39.21 770.779000 0.000108
Fe (238.204 nm)-0.000024 u ppm 0.000619 > 100.00 16.511852 -0.000024 u
Fe H (259.940 nm)0.095902 u ppm 0.002363 2.46 16.514300 0.095902 u
K (766.491 nm)-0.010528 u ppm 0.038991 > 100.00 -466.328000 -0.010528 u
Li (670.783 nm)-0.004435 Su ppm 0.000901 20.32 -4445.530000 S -0.004435 Su
Mg (279.078 nm)0.001299 ppm 0.001083 83.34 13.139100 0.001299
Mn (257.610 nm)-0.000018 u ppm 0.000013 72.34 -0.325375 -0.000018 u
Mo (202.032 nm)0.001084 ppm 0.000329 30.37 8.856580 0.001084
Na (589.592 nm)0.045873 ppm 0.004974 10.84 1595.710000 0.045873
Na H (589.593 nm)-10.188448 u ppm 0.013861 0.14 2484.951342 -10.188448 u
Ni (231.604 nm)-0.000729 u ppm 0.000486 66.63 -12.690900 -0.000729 u
P (213.618 nm)0.000616 u ppm 0.002355 > 100.00 3.812900 0.000616 u
Pb (220.353 nm)0.000980 u ppm 0.001473 > 100.00 0.635963 0.000980 u
S (181.972 nm)-0.027690 u ppm 0.009608 34.70 18.431438 -0.027690 u
Sb (206.834 nm)0.000835 u ppm 0.002017 > 100.00 3.020040 0.000835 u
Se (196.026 nm)0.001877 ppm 0.002012 > 100.00 6.167150 0.001877
Si (288.158 nm)0.000472 u ppm 0.000507 > 100.00 715.400000 0.000472 u
Sn (189.925 nm)0.000732 u ppm 0.000915 > 100.00 2.772790 0.000732 u
Sr (421.552 nm)0.000022 ppm 0.000012 55.59 14.618230 0.000022
Th (288.505 nm)0.006658 ppm 0.002475 37.18 272.983000 0.006658
Ti (336.122 nm)0.000104 u ppm 0.000125 > 100.00 -106.761000 0.000104 u
Tl (190.794 nm)0.003110 ppm 0.000936 30.08 0.886479 0.003110
U (409.013 nm)0.001229 u ppm 0.004600 > 100.00 28.906500 0.001229 u
V (292.401 nm)-0.000119 u ppm 0.000066 55.84 -44.489600 -0.000119 u
Zn (206.200 nm)-0.001018 u ppm 0.000360 35.36 1.968500 -0.001018 u
Zr (343.823 nm)0.000099 ppm 0.000116 > 100.00 0.401872 0.000099
Test Report
52A112023.esws
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Page 883 of 1261
Solution Name: CRI-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CRI-8079070 11/20/2023 11:13:26 AM 3:9 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014680 Q ppm 0.000024 0.16 37147.981030 Q 0.014680 Q
Ag (328.068 nm)0.009643 ppm 0.000152 1.58 484.118000 0.009643
Al (394.401 nm)0.092259 ppm 0.001235 1.34 1593.000000 0.092259
Al H (396.152 nm)0.095123 u ppm 0.004084 4.29 478.067000 0.095123 u
As (188.980 nm)0.017004 ppm 0.001831 10.77 10.722900 0.017004
B (249.678 nm)0.097311 ppm 0.001061 1.09 830.641000 0.097311
Ba (493.408 nm)0.010054 ppm 0.000110 1.09 1522.440000 0.010054
Be (234.861 nm)0.000998 ppm 0.000023 2.34 207.970000 0.000998
Bi (223.061 nm)-0.001787 Qu ppm 0.000868 48.59 1.427570 Q -0.001787 Qu
Ca (315.887 nm)0.209613 ppm 0.010808 5.16 117.354392 0.209613
Cd (214.439 nm)0.005241 ppm 0.000173 3.30 78.434100 0.005241
Co (228.615 nm)0.010407 ppm 0.000120 1.16 241.666000 0.010407
Cr (205.560 nm)0.009983 ppm 0.000313 3.13 42.489800 0.009983
Cu (324.754 nm)0.014569 ppm 0.000261 1.79 1441.290000 0.014569
Fe (238.204 nm)0.104001 ppm 0.002661 2.56 426.057701 0.104001
Fe H (259.940 nm)0.195001 u ppm 0.002503 1.28 177.031000 0.195001 u
K (766.491 nm)3.037930 ppm 0.016488 0.54 5010.690000 3.037930
Li (670.783 nm)0.016088 ppm 0.000186 1.16 -3682.300000 0.016088
Mg (279.078 nm)0.200940 ppm 0.002899 1.44 680.004000 0.200940
Mn (257.610 nm)0.010465 ppm 0.000023 0.22 2796.810000 0.010465
Mo (202.032 nm)0.020168 ppm 0.000554 2.75 103.552000 0.020168
Na (589.592 nm)1.072140 ppm 0.008608 0.80 14189.200000 1.072140
Na H (589.593 nm)-9.173665 u ppm 0.006059 0.07 11456.562578 -9.173665 u
Ni (231.604 nm)0.041504 ppm 0.000705 1.70 131.124000 0.041504
P (213.618 nm)2.821490 ppm 0.007856 0.28 3332.820000 2.821490
Pb (220.353 nm)0.009919 ppm 0.001460 14.72 21.206900 0.009919
S (181.972 nm)0.057424 Q ppm 0.004604 8.02 35.830509 Q 0.057424 Q
Sb (206.834 nm)0.022180 ppm 0.000747 3.37 28.951100 0.022180
Se (196.026 nm)0.019886 ppm 0.004553 22.90 17.214600 0.019886
Si (288.158 nm)0.467812 ppm 0.001629 0.35 4140.980000 0.467812
Sn (189.925 nm)0.099238 ppm 0.001908 1.92 68.967700 0.099238
Sr (421.552 nm)0.010055 ppm 0.000063 0.62 2229.918351 0.010055
Th (288.505 nm)0.001389 Qu ppm 0.001261 90.78 263.237000 Q 0.001389 Qu
Ti (336.122 nm)0.009946 ppm 0.000023 0.23 967.619000 0.009946
Tl (190.794 nm)0.016708 ppm 0.000851 5.09 15.608000 0.016708
U (409.013 nm)0.062026 ppm 0.001839 2.96 296.482000 0.062026
V (292.401 nm)0.009968 ppm 0.000076 0.77 371.954000 0.009968
Zn (206.200 nm)0.020822 ppm 0.000649 3.12 49.062200 0.020822
Zr (343.823 nm)0.010076 ppm 0.000132 1.31 813.845000 0.010076
Test Report
52A112023.esws
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Page 884 of 1261
Solution Name: ICSA-8047029
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ICSA-8047029 11/20/2023 11:17:38 AM 3:10 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000355 ppm 0.000010 2.79 6415.646345 0.000355
Ag (328.068 nm)0.001276 ppm 0.000095 7.46 38.463200 0.001276
Al (394.401 nm)541.765000 o ppm 1.423870 0.26 6667080.000000 541.765000 o
Al H (396.152 nm)515.438000 ppm 0.813490 0.16 2316530.000000 515.438000
As (188.980 nm)0.007337 ppm 0.003928 53.54 0.963225 0.007337
B (249.678 nm)-0.000390 u ppm 0.001242 > 100.00 12.917500 -0.000390 u
Ba (493.408 nm)-0.000548 u ppm 0.000149 27.18 460.662000 -0.000548 u
Be (234.861 nm)0.000462 ppm 0.000133 28.75 2613.610000 0.000462
Bi (223.061 nm)-0.003957 u ppm 0.003342 84.45 -1.797880 -0.003957 u
Ca (315.887 nm)510.439545 o ppm 0.782143 0.15 344226.160936 510.439545 o
Cd (214.439 nm)-0.000124 u ppm 0.000462 > 100.00 37.806200 -0.000124 u
Co (228.615 nm)0.002083 ppm 0.000381 18.29 82.548100 0.002083
Cr (205.560 nm)0.002712 K ppm 0.001084 39.97 12.671900 K 0.002712 K
Cu (324.754 nm)-0.002009 u ppm 0.000373 18.55 607.544000 -0.002009 u
Fe (238.204 nm)193.428700 o ppm 0.379434 0.20 761431.144950 193.428700 o
Fe H (259.940 nm)192.393000 ppm 0.356058 0.19 311494.000000 192.393000
K (766.491 nm)-0.012378 u ppm 0.050918 > 100.00 -469.652000 -0.012378 u
Li (670.783 nm)0.000599 Su ppm 0.002441 > 100.00 -4258.340000 S 0.000599 Su
Mg (279.078 nm)534.149000 o ppm 2.761850 0.52 1786450.000000 534.149000 o
Mn (257.610 nm)-0.000754 u ppm 0.000005 0.62 -196.622000 -0.000754 u
Mo (202.032 nm)0.000435 u ppm 0.000706 > 100.00 5.636430 0.000435 u
Na (589.592 nm)0.107353 ppm 0.010870 10.13 2376.880000 0.107353
Na H (589.593 nm)-9.825949 u ppm 0.015952 0.16 5683.362962 -9.825949 u
Ni (231.604 nm)-0.005094 Ku ppm 0.000802 15.74 -27.554400 K -0.005094 Ku
P (213.618 nm)0.023832 ppm 0.006344 26.62 31.542400 0.023832
Pb (220.353 nm)0.002387 u ppm 0.003619 > 100.00 -57.627200 0.002387 u
S (181.972 nm)-0.051334 Ku ppm 0.023976 46.71 30.938384 K -0.051334 Ku
Sb (206.834 nm)-0.002183 u ppm 0.003706 > 100.00 12.744900 -0.002183 u
Se (196.026 nm)0.001352 u ppm 0.006636 > 100.00 -14.466800 0.001352 u
Si (288.158 nm)0.028818 ppm 0.002158 7.49 920.243000 0.028818
Sn (189.925 nm)-0.002572 u ppm 0.001168 45.42 0.552708 -0.002572 u
Sr (421.552 nm)0.003656 K ppm 0.000097 2.65 816.861022 K 0.003656 K
Th (288.505 nm)0.133388 K ppm 0.003155 2.37 514.104000 K 0.133388 K
Ti (336.122 nm)-0.001826 u ppm 0.000051 2.78 799.481000 -0.001826 u
Tl (190.794 nm)-0.000432 u ppm 0.005532 > 100.00 -6.438000 -0.000432 u
U (409.013 nm)0.010126 ppm 0.004635 45.78 258.248000 0.010126
V (292.401 nm)0.003325 ppm 0.000059 1.78 101.158000 0.003325
Zn (206.200 nm)0.002438 ppm 0.001380 56.62 9.419280 0.002438
Zr (343.823 nm)0.000100 ppm 0.000029 29.40 262.604000 0.000100
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 14 of 287
Page 885 of 1261
Solution Name: ICSAB-8050400
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
ICSAB-8050400 11/20/2023 11:22:07 AM 3:11 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.272218 Go ppm 0.001593 0.13 3268091.874987
G 1.272218 Go
Ag (328.068 nm)1.143860 o ppm 0.001648 0.14 61183.000000 1.143860 o
Al (394.401 nm)534.861000 o ppm 0.416668 0.08 6582100.000000 534.861000 o
Al H (396.152 nm)508.553000 ppm 1.930360 0.38 2285590.000000 508.553000
As (188.980 nm)1.069700 ppm 0.003647 0.34 883.677000 1.069700
B (249.678 nm)10.781400 ppm 0.008983 0.08 90252.500000 10.781400
Ba (493.408 nm)1.048810 ppm 0.001785 0.17 159382.000000 1.048810
Be (234.861 nm)0.508821 ppm 0.002582 0.51 87512.900000 0.508821
Bi (223.061 nm)0.000230 Gu ppm 0.003354 > 100.00 4.427110 G 0.000230 Gu
Ca (315.887 nm)504.439470 o ppm 1.691682 0.34 340179.595903 504.439470 o
Cd (214.439 nm)0.967342 ppm 0.004450 0.46 14497.900000 0.967342
Co (228.615 nm)0.965026 ppm 0.001100 0.11 18486.600000 0.965026
Cr (205.560 nm)1.005830 ppm 0.003970 0.39 4135.750000 1.005830
Cu (324.754 nm)1.100510 o ppm 0.000756 0.07 52045.400000 1.100510 o
Fe (238.204 nm)190.786838 o ppm 0.956440 0.50 751043.704913 190.786838 o
Fe H (259.940 nm)189.579000 ppm 0.691221 0.36 306935.000000 189.579000
K (766.491 nm)11.327600 ppm 0.054454 0.48 19904.300000 11.327600
Li (670.783 nm)1.136830 So ppm 0.002647 0.23 37997.300000 S 1.136830 So
Mg (279.078 nm)527.628000 o ppm 1.825070 0.35 1764640.000000 527.628000 o
Mn (257.610 nm)0.991859 ppm 0.002746 0.28 264654.000000 0.991859
Mo (202.032 nm)1.001720 ppm 0.002934 0.29 4974.120000 1.001720
Na (589.592 nm)10.863800 ppm 0.032090 0.30 145461.000000 10.863800
Na H (589.593 nm)1.137564 Gu ppm 0.575437 50.59 110775.224577 G 1.137564 Gu
Ni (231.604 nm)0.941477 ppm 0.002165 0.23 3196.340000 0.941477
P (213.618 nm)10.240000 ppm 0.029433 0.29 12006.800000 10.240000
Pb (220.353 nm)0.993429 ppm 0.002384 0.24 2216.800000 0.993429
S (181.972 nm)10.368284 ppm 0.046748 0.45 2157.475803 10.368284
Sb (206.834 nm)1.103470 o ppm 0.008330 0.75 1358.540000 1.103470 o
Se (196.026 nm)1.044040 ppm 0.004979 0.48 626.328000 1.044040
Si (288.158 nm)10.607400 ppm 0.024152 0.23 78267.300000 10.607400
Sn (189.925 nm)0.975892 ppm 0.007722 0.79 658.067000 0.975892
Sr (421.552 nm)1.054814 ppm 0.001349 0.13 232912.085166 1.054814
Th (288.505 nm)0.159491 G ppm 0.006968 4.37 541.425000 G 0.159491 G
Ti (336.122 nm)1.049030 ppm 0.001015 0.10 115455.000000 1.049030
Tl (190.794 nm)0.967268 ppm 0.001828 0.19 1042.050000 0.967268
U (409.013 nm)0.003118 Gu ppm 0.003076 98.63 194.268000 G 0.003118 Gu
V (292.401 nm)1.025460 ppm 0.001532 0.15 42676.700000 1.025460
Zn (206.200 nm)0.970882 ppm 0.003810 0.39 2097.740000 0.970882
Zr (343.823 nm)0.999576 ppm 0.001329 0.13 81735.700000 0.999576
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 15 of 287
Page 886 of 1261
Solution Name: lra-8036900
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
lra-8036900 11/20/2023 11:26:25 AM 3:12 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.005644 u ppm 0.000026 0.45 445.269952 -0.005644 u
Ag (328.068 nm)0.036965 ppm 0.000300 0.81 -6322.090000 0.036965
Al (394.401 nm)0.056516 ppm 0.002473 4.38 1121.660000 0.056516
Al H (396.152 nm)0.192671 u ppm 0.003434 1.78 916.469000 0.192671 u
As (188.980 nm)10.268800 o ppm 0.023755 0.23 8524.220000 10.268800 o
B (249.678 nm)10.413000 ppm 0.015007 0.14 87169.100000 10.413000
Ba (493.408 nm)12.799700 ppm 0.019879 0.16 1939980.000000 12.799700
Be (234.861 nm)-0.000257 u ppm 0.000403 > 100.00 6446.830000 -0.000257 u
Bi (223.061 nm)-0.000777 u ppm 0.002131 > 100.00 2.930050 -0.000777 u
Ca (315.887 nm)0.052493 ppm 0.005473 10.43 11.389510 0.052493
Cd (214.439 nm)2.120710 o ppm 0.003561 0.17 31800.400000 2.120710 o
Co (228.615 nm)5.328270 o ppm 0.008189 0.15 102054.000000 5.328270 o
Cr (205.560 nm)10.405200 o ppm 0.015664 0.15 42785.600000 10.405200 o
Cu (324.754 nm)11.262700 Qo ppm 0.040354 0.36 526755.000000 Q 11.262700 Qo
Fe (238.204 nm)499.751346 o ppm 2.006468 0.40 1967268.651875 499.751346 o
Fe H (259.940 nm)490.942000 ppm 1.434440 0.29 795075.000000 490.942000
K (766.491 nm)-0.068309 u ppm 0.013669 20.01 -570.140000 -0.068309 u
Li (670.783 nm)-0.002140 u ppm 0.001087 50.81 -4360.180000 -0.002140 u
Mg (279.078 nm)-0.014933 u ppm 0.004448 29.78 -364.769000 -0.014933 u
Mn (257.610 nm)10.052600 o ppm 0.015136 0.15 2682240.000000 10.052600 o
Mo (202.032 nm)5.062270 o ppm 0.004581 0.09 25122.900000 5.062270 o
Na (589.592 nm)-5.990940 u ppm 0.021536 0.36 79003.800000 -5.990940 u
Na H (589.593 nm)-17.360109 u ppm 0.331277 1.91 51104.409854 -17.360109 u
Ni (231.604 nm)10.351400 o ppm 0.011369 0.11 35241.400000 10.351400 o
P (213.618 nm)25.716800 o ppm 0.082719 0.32 29633.400000 25.716800 o
Pb (220.353 nm)10.636500 ppm 0.018622 0.18 24419.300000 10.636500
S (181.972 nm)19.613714 o ppm 0.044744 0.23 4065.025490 19.613714 o
Sb (206.834 nm)-0.008417 u ppm 0.003988 47.38 41.016000 -0.008417 u
Se (196.026 nm)5.057730 o ppm 0.011721 0.23 3062.950000 5.057730 o
Si (288.158 nm)48.421400 o ppm 0.314097 0.65 354534.000000 48.421400 o
Sn (189.925 nm)-0.001132 u ppm 0.000922 81.46 1.520060 -0.001132 u
Sr (421.552 nm)10.405120 o ppm 0.013623 0.13 2297454.703676 10.405120 o
Th (288.505 nm)0.266190 ppm 0.004865 1.83 534.012000 0.266190
Ti (336.122 nm)10.100000 o ppm 0.012215 0.12 1101990.000000 10.100000 o
Tl (190.794 nm)5.177430 o ppm 0.015357 0.30 5591.440000 5.177430 o
U (409.013 nm)-0.057826 u ppm 0.004402 7.61 259.023000 -0.057826 u
V (292.401 nm)10.342000 o ppm 0.012320 0.12 430829.000000 10.342000 o
Zn (206.200 nm)10.490800 o ppm 0.015428 0.15 22626.100000 10.490800 o
Zr (343.823 nm)0.003111 ppm 0.000537 17.27 923.140000 0.003111
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 16 of 287
Page 887 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 11:31:23 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000409 u ppm 0.000010 2.55 -68.135489 -0.000409 u
Ag (328.068 nm)-0.000905 u ppm 0.000110 12.10 68.171100 -0.000905 u
Al (394.401 nm)53.546900 o ppm 0.124027 0.23 658276.000000 53.546900 o
Al H (396.152 nm)50.749800 ppm 0.079392 0.16 228131.000000 50.749800
As (188.980 nm)0.001379 ppm 0.000976 70.78 -2.724750 0.001379
B (249.678 nm)0.011500 ppm 0.001634 14.21 112.428000 0.011500
Ba (493.408 nm)0.000559 ppm 0.000104 18.59 230.751000 0.000559
Be (234.861 nm)0.000167 ppm 0.000065 38.72 740.676000 0.000167
Bi (223.061 nm)-0.001020 u ppm 0.001612 > 100.00 2.568380 -0.001020 u
Ca (315.887 nm)-0.029099 u ppm 0.003434 11.80 -43.637624 -0.029099 u
Cd (214.439 nm)0.000057 u ppm 0.000089 > 100.00 11.596600 0.000057 u
Co (228.615 nm)0.000468 ppm 0.000300 64.07 51.811100 0.000468
Cr (205.560 nm)0.001168 ppm 0.000755 64.66 6.325890 0.001168
Cu (324.754 nm)-0.001530 u ppm 0.000072 4.69 1664.320000 -0.001530 u
Fe (238.204 nm)52.133349 o ppm 0.101093 0.19 205234.790003 52.133349 o
Fe H (259.940 nm)50.953400 ppm 0.117482 0.23 82394.000000 50.953400
K (766.491 nm)-0.012745 u ppm 0.037384 > 100.00 -470.311000 -0.012745 u
Li (670.783 nm)-0.003344 u ppm 0.002281 68.22 -4404.960000 -0.003344 u
Mg (279.078 nm)-0.002072 u ppm 0.001473 71.09 -193.170000 -0.002072 u
Mn (257.610 nm)-0.000737 u ppm 0.000081 11.02 -192.083000 -0.000737 u
Mo (202.032 nm)0.000376 ppm 0.000409 > 100.00 5.345340 0.000376
Na (589.592 nm)256.162000 o ppm 1.422000 0.56 3114740.000000 256.162000 o
Na H (589.593 nm)247.879093 ppm 3.167991 1.28 2261662.794887 247.879093
Ni (231.604 nm)0.000613 ppm 0.000523 85.23 -8.119100 0.000613
P (213.618 nm)5.072670 ppm 0.024444 0.48 5990.860000 5.072670
Pb (220.353 nm)0.001022 ppm 0.000296 28.97 -0.887259 0.001022
S (181.972 nm)4.989619 ppm 0.050581 1.01 1042.176673 4.989619
Sb (206.834 nm)0.001350 u ppm 0.002071 > 100.00 7.256840 0.001350 u
Se (196.026 nm)0.006016 ppm 0.002396 39.82 3.232810 0.006016
Si (288.158 nm)0.050446 ppm 0.002100 4.16 1078.450000 0.050446
Sn (189.925 nm)-0.000041 u ppm 0.002710 > 100.00 2.253230 -0.000041 u
Sr (421.552 nm)0.000606 ppm 0.000041 6.73 143.493062 0.000606
Th (288.505 nm)5.108930 ppm 0.005191 0.10 9807.550000 5.108930
Ti (336.122 nm)0.001553 ppm 0.000070 4.51 51.341400 0.001553
Tl (190.794 nm)-0.002336 u ppm 0.001833 78.46 -5.964980 -0.002336 u
U (409.013 nm)2.574040 Q ppm 0.001675 0.07 11491.700000 Q 2.574040 Q
V (292.401 nm)0.000304 ppm 0.000084 27.57 262.621000 0.000304
Zn (206.200 nm)0.001368 ppm 0.000623 45.54 7.112590 0.001368
Zr (343.823 nm)-0.001080 u ppm 0.000108 10.03 -25.013700 -0.001080 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 17 of 287
Page 888 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 11:36:21 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.475421 ppm 0.001587 0.33 1219060.986108 0.475421
Ag (328.068 nm)0.508499 ppm 0.000686 0.13 27155.500000 0.508499
Al (394.401 nm)0.507555 ppm 0.003601 0.71 6693.360000 0.507555
Al H (396.152 nm)0.512970 u ppm 0.006846 1.33 2355.960000 0.512970 u
As (188.980 nm)0.512929 ppm 0.002378 0.46 422.754000 0.512929
B (249.678 nm)0.510713 ppm 0.001034 0.20 4290.680000 0.510713
Ba (493.408 nm)0.510711 ppm 0.001549 0.30 77355.900000 0.510711
Be (234.861 nm)0.499233 ppm 0.004233 0.85 83481.700000 0.499233
Bi (223.061 nm)1.018120 ppm 0.001329 0.13 1517.810000 1.018120
Ca (315.887 nm)5.124049 ppm 0.006191 0.12 3431.743746 5.124049
Cd (214.439 nm)0.516542 ppm 0.001775 0.34 7721.280000 0.516542
Co (228.615 nm)0.517560 ppm 0.001040 0.20 9932.680000 0.517560
Cr (205.560 nm)0.517848 ppm 0.001800 0.35 2129.990000 0.517848
Cu (324.754 nm)0.514035 ppm 0.000672 0.13 24744.900000 0.514035
Fe (238.204 nm)2.561053 ppm 0.005648 0.22 10104.374756 2.561053
Fe H (259.940 nm)2.599150 u ppm 0.006162 0.24 4071.200000 2.599150 u
K (766.491 nm)51.277500 ppm 0.302638 0.59 91680.400000 51.277500
Li (670.783 nm)0.510019 ppm 0.003041 0.60 14686.700000 0.510019
Mg (279.078 nm)20.330800 ppm 0.080587 0.40 68007.700000 20.330800
Mn (257.610 nm)0.508051 ppm 0.000969 0.19 135563.000000 0.508051
Mo (202.032 nm)0.514728 ppm 0.001188 0.23 2557.600000 0.514728
Na (589.592 nm)25.587800 ppm 0.163176 0.64 318066.000000 25.587800
Na H (589.593 nm)15.318454 u ppm 0.049832 0.33 230212.552400 15.318454 u
Ni (231.604 nm)0.517122 ppm 0.003908 0.76 1751.030000 0.517122
P (213.618 nm)0.007529 ppm 0.000837 11.12 -29.452000 0.007529
Pb (220.353 nm)0.524690 ppm 0.003466 0.66 1202.080000 0.524690
S (181.972 nm)-0.025023 u ppm 0.007174 28.67 21.499334 -0.025023 u
Sb (206.834 nm)0.509764 ppm 0.002027 0.40 622.768000 0.509764
Se (196.026 nm)0.515063 ppm 0.009215 1.79 321.159000 0.515063
Si (288.158 nm)5.061780 ppm 0.019908 0.39 37737.300000 5.061780
Sn (189.925 nm)0.512675 ppm 0.004278 0.83 346.791000 0.512675
Sr (421.552 nm)0.510777 ppm 0.001022 0.20 112789.051680 0.510777
Th (288.505 nm)0.032614 ppm 0.001793 5.50 309.353000 0.032614
Ti (336.122 nm)0.511361 ppm 0.001127 0.22 55692.300000 0.511361
Tl (190.794 nm)0.519383 ppm 0.000987 0.19 560.324000 0.519383
U (409.013 nm)-0.005359 u ppm 0.000913 17.03 -13.471700 -0.005359 u
V (292.401 nm)0.513522 ppm 0.001145 0.22 21344.200000 0.513522
Zn (206.200 nm)0.516566 ppm 0.001337 0.26 1118.070000 0.516566
Zr (343.823 nm)0.509901 ppm 0.001216 0.24 41562.600000 0.509901
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 18 of 287
Page 889 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 11:40:48 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000099 ppm 0.000016 16.36 -339.512763 0.000099
Ag (328.068 nm)-0.000006 u ppm 0.000106 > 100.00 -29.291000 -0.000006 u
Al (394.401 nm)0.001848 ppm 0.000498 26.93 473.425000 0.001848
Al H (396.152 nm)0.000268 u ppm 0.003273 > 100.00 51.771200 0.000268 u
As (188.980 nm)-0.001079 u ppm 0.000313 29.06 -4.300840 -0.001079 u
B (249.678 nm)0.003722 ppm 0.000270 7.26 47.334100 0.003722
Ba (493.408 nm)0.000181 ppm 0.000102 56.34 26.790900 0.000181
Be (234.861 nm)0.000003 ppm 0.000003 98.19 40.387000 0.000003
Bi (223.061 nm)-0.001348 u ppm 0.000799 59.29 2.080790 -0.001348 u
Ca (315.887 nm)-0.000462 u ppm 0.008735 > 100.00 -24.324389 -0.000462 u
Cd (214.439 nm)0.000081 u ppm 0.000178 > 100.00 1.288520 0.000081 u
Co (228.615 nm)0.000038 u ppm 0.000124 > 100.00 43.571900 0.000038 u
Cr (205.560 nm)-0.000116 u ppm 0.000243 > 100.00 1.047020 -0.000116 u
Cu (324.754 nm)-0.000054 u ppm 0.000205 > 100.00 763.182000 -0.000054 u
Fe (238.204 nm)0.000616 ppm 0.000556 90.26 19.031699 0.000616
Fe H (259.940 nm)0.094011 u ppm 0.001046 1.11 13.450400 0.094011 u
K (766.491 nm)-0.003648 u ppm 0.023018 > 100.00 -453.966000 -0.003648 u
Li (670.783 nm)-0.004152 Su ppm 0.001770 42.62 -4435.030000 S -0.004152 Su
Mg (279.078 nm)0.000163 u ppm 0.001305 > 100.00 9.416210 0.000163 u
Mn (257.610 nm)0.000001 u ppm 0.000030 > 100.00 4.743180 0.000001 u
Mo (202.032 nm)0.000488 ppm 0.000175 35.87 5.897560 0.000488
Na (589.592 nm)-0.001639 u ppm 0.004816 > 100.00 1019.140000 -0.001639 u
Na H (589.593 nm)-10.267770 u ppm 0.007581 0.07 1791.252043 -10.267770 u
Ni (231.604 nm)0.000049 u ppm 0.000713 > 100.00 -10.043400 0.000049 u
P (213.618 nm)0.002669 ppm 0.001961 73.48 6.247220 0.002669
Pb (220.353 nm)0.000564 u ppm 0.000770 > 100.00 -0.325784 0.000564 u
S (181.972 nm)-0.033840 u ppm 0.010162 30.03 17.177232 -0.033840 u
Sb (206.834 nm)0.001240 u ppm 0.002447 > 100.00 3.514200 0.001240 u
Se (196.026 nm)0.001692 ppm 0.001648 97.41 6.053360 0.001692
Si (288.158 nm)0.001422 ppm 0.000255 17.91 721.933000 0.001422
Sn (189.925 nm)-0.000715 u ppm 0.001533 > 100.00 1.800430 -0.000715 u
Sr (421.552 nm)0.000088 ppm 0.000015 16.80 29.065494 0.000088
Th (288.505 nm)0.004911 ppm 0.002667 54.30 269.731000 0.004911
Ti (336.122 nm)0.000130 ppm 0.000079 60.73 -103.925000 0.000130
Tl (190.794 nm)0.000959 ppm 0.000563 58.72 -1.447190 0.000959
U (409.013 nm)0.001718 u ppm 0.003135 > 100.00 31.048600 0.001718 u
V (292.401 nm)0.000035 u ppm 0.000193 > 100.00 -37.803400 0.000035 u
Zn (206.200 nm)-0.000925 u ppm 0.000530 57.26 2.168140 -0.000925 u
Zr (343.823 nm)0.000139 ppm 0.000048 34.88 3.677630 0.000139
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 19 of 287
Page 890 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 11:44:50 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014667 ppm 0.000005 0.03 37111.060241 0.014667
Ag (328.068 nm)0.009638 ppm 0.000214 2.22 483.317000 0.009638
Al (394.401 nm)0.091314 ppm 0.001123 1.23 1585.180000 0.091314
Al H (396.152 nm)0.096411 u ppm 0.003067 3.18 483.854000 0.096411 u
As (188.980 nm)0.014177 ppm 0.000395 2.78 8.373860 0.014177
B (249.678 nm)0.100050 ppm 0.000669 0.67 853.564000 0.100050
Ba (493.408 nm)0.010313 ppm 0.000094 0.91 1561.690000 0.010313
Be (234.861 nm)0.001017 ppm 0.000042 4.13 211.139000 0.001017
Bi (223.061 nm)-0.000647 Qu ppm 0.001863 > 100.00 3.123620 Q -0.000647 Qu
Ca (315.887 nm)0.208449 ppm 0.006809 3.27 116.569669 0.208449
Cd (214.439 nm)0.005264 ppm 0.000119 2.27 78.777000 0.005264
Co (228.615 nm)0.010149 ppm 0.000060 0.59 236.751000 0.010149
Cr (205.560 nm)0.009898 ppm 0.000271 2.74 42.138300 0.009898
Cu (324.754 nm)0.015029 ppm 0.000131 0.87 1459.770000 0.015029
Fe (238.204 nm)0.104205 ppm 0.002518 2.42 426.862334 0.104205
Fe H (259.940 nm)0.196558 u ppm 0.002241 1.14 179.553000 0.196558 u
K (766.491 nm)3.048050 ppm 0.022493 0.74 5028.870000 3.048050
Li (670.783 nm)0.019412 ppm 0.001614 8.32 -3558.690000 0.019412
Mg (279.078 nm)0.202416 ppm 0.001431 0.71 685.301000 0.202416
Mn (257.610 nm)0.010377 ppm 0.000044 0.42 2773.270000 0.010377
Mo (202.032 nm)0.020761 ppm 0.000477 2.30 106.493000 0.020761
Na (589.592 nm)1.024870 ppm 0.008262 0.81 13620.000000 1.024870
Na H (589.593 nm)-9.236269 u ppm 0.006992 0.08 10912.426331 -9.236269 u
Ni (231.604 nm)0.042194 ppm 0.000948 2.25 133.476000 0.042194
P (213.618 nm)2.841000 ppm 0.006166 0.22 3355.840000 2.841000
Pb (220.353 nm)0.009859 ppm 0.001432 14.52 21.065500 0.009859
S (181.972 nm)0.065247 Q ppm 0.010172 15.59 37.420296 Q 0.065247 Q
Sb (206.834 nm)0.022212 ppm 0.002242 10.09 28.985100 0.022212
Se (196.026 nm)0.015930 ppm 0.004165 26.14 14.786900 0.015930
Si (288.158 nm)0.471934 ppm 0.003352 0.71 4171.960000 0.471934
Sn (189.925 nm)0.102568 ppm 0.001755 1.71 71.205100 0.102568
Sr (421.552 nm)0.010195 ppm 0.000109 1.07 2260.709588 0.010195
Th (288.505 nm)0.003320 Q ppm 0.000464 13.97 266.849000 Q 0.003320 Q
Ti (336.122 nm)0.009994 ppm 0.000084 0.84 972.874000 0.009994
Tl (190.794 nm)0.017151 ppm 0.002011 11.72 16.087700 0.017151
U (409.013 nm)0.059385 ppm 0.002630 4.43 284.626000 0.059385
V (292.401 nm)0.009964 ppm 0.000157 1.58 370.576000 0.009964
Zn (206.200 nm)0.019228 ppm 0.001134 5.90 45.624700 0.019228
Zr (343.823 nm)0.009975 ppm 0.000038 0.38 805.664000 0.009975
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 20 of 287
Page 891 of 1261
Solution Name: 888-C-2 BC
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
888-C-2 BC 11/20/2023 12:32:25 PM 3:15 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.277091 b ppm 0.002269 0.82 725906.468015 0.277091 b
Ag (328.068 nm)0.005303 ppm 0.000147 2.77 154.661000 0.005303
Al (394.401 nm)0.345759 ppm 0.004243 1.23 4696.120000 0.345759
Al H (396.152 nm)0.283291 u ppm 0.003757 1.33 1323.730000 0.283291 u
As (188.980 nm)0.055927 ppm 0.001404 2.51 42.864800 0.055927
B (249.678 nm)7.051560 ppm 0.054689 0.78 59035.300000 7.051560
Ba (493.408 nm)0.064212 ppm 0.000681 1.06 9787.100000 0.064212
Be (234.861 nm)0.000132 ppm 0.000055 41.71 348.977000 0.000132
Bi (223.061 nm)-0.000401 u ppm 0.001565 > 100.00 3.488420 -0.000401 u
Ca (315.887 nm)29.546408 o ppm 0.152132 0.51 19902.648725 29.546408 o
Cd (214.439 nm)0.000435 ppm 0.000223 51.29 11.126000 0.000435
Co (228.615 nm)0.012055 ppm 0.000310 2.57 274.835000 0.012055
Cr (205.560 nm)0.089850 ppm 0.001503 1.67 370.947000 0.089850
Cu (324.754 nm)0.003126 ppm 0.000206 6.59 926.962000 0.003126
Fe (238.204 nm)22.248920 o ppm 0.138192 0.62 87597.476955 22.248920 o
Fe H (259.940 nm)22.097200 ppm 0.149281 0.68 35653.500000 22.097200
K (766.491 nm)233.133000 o ppm 43.6254
00 18.71 418412.000000 233.133000 o
Li (670.783 nm)0.176575 ppm 0.003431 1.94 2286.130000 0.176575
Mg (279.078 nm)94.227600 o ppm 0.731201 0.78 315157.000000 94.227600 o
Mn (257.610 nm)0.619875 ppm 0.005139 0.83 165400.000000 0.619875
Mo (202.032 nm)0.023792 ppm 0.001181 4.96 121.538000 0.023792
Na (589.592 nm)2684.000000
bo ppm 558.371
000 20.80 32626200.000000 2684.000000 bo
Na H (589.593 nm)1263.930452 b ppm 121.794
628 9.64 11156905.024995 1263.930452 b
Ni (231.604 nm)0.162609 ppm 0.001892 1.16 543.490000 0.162609
P (213.618 nm)3.374810 ppm 0.024608 0.73 3986.610000 3.374810
Pb (220.353 nm)0.002695 ppm 0.001575 58.46 4.401960 0.002695
S (181.972 nm)768.436922 bo ppm 4.278380 0.56 156517.295918 768.436922 bo
Sb (206.834 nm)0.005781 ppm 0.001217 21.06 10.917300 0.005781
Se (196.026 nm)0.008177 ppm 0.000912 11.15 8.107800 0.008177
Si (288.158 nm)4.419220 ppm 0.035989 0.81 32832.200000 4.419220
Sn (189.925 nm)0.005599 ppm 0.002563 45.76 6.043590 0.005599
Sr (421.552 nm)0.372977 ppm 0.003412 0.91 82362.714386 0.372977
Th (288.505 nm)0.080920 ppm 0.002417 2.99 419.341000 0.080920
Ti (336.122 nm)0.053937 ppm 0.000638 1.18 5831.970000 0.053937
Tl (190.794 nm)-0.000279 u ppm 0.003093 > 100.00 -3.314050 -0.000279 u
U (409.013 nm)-0.054580 u ppm 0.002410 4.42 -195.157000 -0.054580 u
V (292.401 nm)0.134050 ppm 0.001106 0.83 5562.630000 0.134050
Zn (206.200 nm)0.090358 ppm 0.002351 2.60 199.008000 0.090358
Zr (343.823 nm)0.012166 ppm 0.000183 1.51 1014.220000 0.012166
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 21 of 287
Page 892 of 1261
Solution Name: Rinse
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
Rinse 11/20/2023 12:37:21 PM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000057 ppm 0.000007 12.60 -439.369412 0.000057
Ag (328.068 nm)0.000020 u ppm 0.000092 > 100.00 -28.362300 0.000020 u
Al (394.401 nm)0.002499 ppm 0.000652 26.07 481.159000 0.002499
Al H (396.152 nm)0.001016 u ppm 0.000841 82.72 55.131900 0.001016 u
As (188.980 nm)-0.000002 u ppm 0.002835 > 100.00 -3.406210 -0.000002 u
B (249.678 nm)0.005300 ppm 0.000208 3.92 60.537300 0.005300
Ba (493.408 nm)-0.000093 u ppm 0.000048 51.11 -14.711400 -0.000093 u
Be (234.861 nm)-0.000001 u ppm 0.000009 > 100.00 39.646500 -0.000001 u
Bi (223.061 nm)-0.000334 u ppm 0.001541 > 100.00 3.589050 -0.000334 u
Ca (315.887 nm)0.004526 ppm 0.004004 88.47 -20.960178 0.004526
Cd (214.439 nm)-0.000006 u ppm 0.000199 > 100.00 -0.014561 -0.000006 u
Co (228.615 nm)-0.000059 u ppm 0.000344 > 100.00 41.732600 -0.000059 u
Cr (205.560 nm)0.000189 ppm 0.000137 72.26 2.301600 0.000189
Cu (324.754 nm)0.000482 ppm 0.000328 68.00 788.425000 0.000482
Fe (238.204 nm)0.000861 ppm 0.000879 > 100.00 19.995069 0.000861
Fe H (259.940 nm)0.093330 u ppm 0.003331 3.57 12.347300 0.093330 u
K (766.491 nm)0.136493 ppm 0.030609 22.43 -202.182000 0.136493
Li (670.783 nm)-0.003769 u ppm 0.000711 18.87 -4420.770000 -0.003769 u
Mg (279.078 nm)0.001966 u ppm 0.002475 > 100.00 15.400500 0.001966 u
Mn (257.610 nm)-0.000026 u ppm 0.000005 20.31 -2.564080 -0.000026 u
Mo (202.032 nm)0.000639 ppm 0.000285 44.64 6.646640 0.000639
Na (589.592 nm)0.884481 ppm 0.020205 2.28 11787.400000 0.884481
Na H (589.593 nm)-9.747317 u ppm 0.003145 0.03 6345.439127 -9.747317 u
Ni (231.604 nm)0.000150 u ppm 0.000497 > 100.00 -9.700610 0.000150 u
P (213.618 nm)-0.001703 u ppm 0.002565 > 100.00 1.068000 -0.001703 u
Pb (220.353 nm)-0.000800 u ppm 0.000836 > 100.00 -3.459270 -0.000800 u
S (181.972 nm)0.419851 ppm 0.066618 15.87 109.567690 0.419851
Sb (206.834 nm)0.001416 ppm 0.000693 48.95 3.731540 0.001416
Se (196.026 nm)0.000233 u ppm 0.002170 > 100.00 5.158270 0.000233 u
Si (288.158 nm)0.015724 ppm 0.002169 13.79 825.783000 0.015724
Sn (189.925 nm)-0.000274 u ppm 0.000940 > 100.00 2.096970 -0.000274 u
Sr (421.552 nm)0.000060 ppm 0.000038 63.29 22.918590 0.000060
Th (288.505 nm)0.005197 ppm 0.002048 39.41 270.246000 0.005197
Ti (336.122 nm)0.000015 u ppm 0.000139 > 100.00 -116.444000 0.000015 u
Tl (190.794 nm)0.000628 u ppm 0.003381 > 100.00 -1.807950 0.000628 u
U (409.013 nm)-0.000205 u ppm 0.001631 > 100.00 22.602100 -0.000205 u
V (292.401 nm)-0.000144 u ppm 0.000090 62.36 -45.394500 -0.000144 u
Zn (206.200 nm)-0.000963 u ppm 0.000398 41.33 2.087350 -0.000963 u
Zr (343.823 nm)-0.000037 u ppm 0.000046 > 100.00 -10.647200 -0.000037 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 22 of 287
Page 893 of 1261
Solution Name: Rinse
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
Rinse 11/20/2023 12:41:23 PM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000051 ppm 0.000004 7.88 -455.225540 0.000051
Ag (328.068 nm)-0.000359 u ppm 0.000159 44.39 -48.356000 -0.000359 u
Al (394.401 nm)0.001697 ppm 0.000641 37.75 469.499000 0.001697
Al H (396.152 nm)0.002581 u ppm 0.001879 72.79 62.163600 0.002581 u
As (188.980 nm)0.002914 u ppm 0.002926 > 100.00 -0.983565 0.002914 u
B (249.678 nm)0.001732 ppm 0.000410 23.69 30.677000 0.001732
Ba (493.408 nm)0.000056 u ppm 0.000165 > 100.00 7.908520 0.000056 u
Be (234.861 nm)0.000006 u ppm 0.000010 > 100.00 40.912900 0.000006 u
Bi (223.061 nm)-0.000100 u ppm 0.001329 > 100.00 3.937010 -0.000100 u
Ca (315.887 nm)-0.001546 u ppm 0.004620 > 100.00 -25.054989 -0.001546 u
Cd (214.439 nm)-0.000081 u ppm 0.000171 > 100.00 -1.138670 -0.000081 u
Co (228.615 nm)0.000028 u ppm 0.000047 > 100.00 43.377700 0.000028 u
Cr (205.560 nm)-0.000793 u ppm 0.000158 19.95 -1.739280 -0.000793 u
Cu (324.754 nm)-0.000028 u ppm 0.000055 > 100.00 765.996000 -0.000028 u
Fe (238.204 nm)0.000791 u ppm 0.000964 > 100.00 19.716494 0.000791 u
Fe H (259.940 nm)0.095562 u ppm 0.003089 3.23 15.963400 0.095562 u
K (766.491 nm)0.041403 u ppm 0.048310 > 100.00 -373.026000 0.041403 u
Li (670.783 nm)-0.004563 u ppm 0.000909 19.93 -4450.290000 -0.004563 u
Mg (279.078 nm)-0.000318 u ppm 0.001817 > 100.00 7.622490 -0.000318 u
Mn (257.610 nm)-0.000031 u ppm 0.000012 38.54 -3.920220 -0.000031 u
Mo (202.032 nm)0.000702 ppm 0.000188 26.78 6.962600 0.000702
Na (589.592 nm)0.576534 ppm 0.014224 2.47 8044.890000 0.576534
Na H (589.593 nm)-9.969545 u ppm 0.007214 0.07 4400.456815 -9.969545 u
Ni (231.604 nm)-0.000510 u ppm 0.000769 > 100.00 -11.945400 -0.000510 u
P (213.618 nm)0.000370 u ppm 0.000417 > 100.00 3.529460 0.000370 u
Pb (220.353 nm)-0.000528 u ppm 0.000827 > 100.00 -2.834250 -0.000528 u
S (181.972 nm)0.078801 ppm 0.009225 11.71 40.119896 0.078801
Sb (206.834 nm)0.000624 ppm 0.000535 85.76 2.759790 0.000624
Se (196.026 nm)0.001124 u ppm 0.002269 > 100.00 5.705160 0.001124 u
Si (288.158 nm)0.001508 ppm 0.000225 14.95 723.260000 0.001508
Sn (189.925 nm)0.001942 u ppm 0.003479 > 100.00 3.585700 0.001942 u
Sr (421.552 nm)0.000028 ppm 0.000022 78.38 15.823881 0.000028
Th (288.505 nm)0.008720 ppm 0.002303 26.41 276.831000 0.008720
Ti (336.122 nm)-0.000010 u ppm 0.000072 > 100.00 -119.138000 -0.000010 u
Tl (190.794 nm)0.002750 ppm 0.001387 50.45 0.496823 0.002750
U (409.013 nm)0.002093 u ppm 0.004714 > 100.00 32.824100 0.002093 u
V (292.401 nm)-0.000212 u ppm 0.000026 12.35 -47.412900 -0.000212 u
Zn (206.200 nm)-0.001208 u ppm 0.000179 14.80 1.558860 -0.001208 u
Zr (343.823 nm)-0.000003 u ppm 0.000139 > 100.00 -7.922260 -0.000003 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 23 of 287
Page 894 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 12:45:25 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000391 u ppm 0.000014 3.57 -29.412408 -0.000391 u
Ag (328.068 nm)-0.001034 u ppm 0.000051 4.93 61.242400 -0.001034 u
Al (394.401 nm)53.316300 o ppm 0.116106 0.22 655443.000000 53.316300 o
Al H (396.152 nm)50.472400 ppm 0.050239 0.10 226884.000000 50.472400
As (188.980 nm)0.001687 u ppm 0.004619 > 100.00 -2.465900 0.001687 u
B (249.678 nm)-0.001478 u ppm 0.000504 34.10 3.809810 -0.001478 u
Ba (493.408 nm)0.000267 ppm 0.000134 50.21 185.640000 0.000267
Be (234.861 nm)0.000168 ppm 0.000029 17.15 736.961000 0.000168
Bi (223.061 nm)-0.002026 u ppm 0.000796 39.27 1.072210 -0.002026 u
Ca (315.887 nm)-0.031923 u ppm 0.005586 17.50 -45.542394 -0.031923 u
Cd (214.439 nm)-0.000010 u ppm 0.000152 > 100.00 10.540500 -0.000010 u
Co (228.615 nm)0.000255 ppm 0.000131 51.34 47.724700 0.000255
Cr (205.560 nm)0.000557 ppm 0.000593 > 100.00 3.810440 0.000557
Cu (324.754 nm)-0.001772 u ppm 0.000140 7.90 1648.960000 -0.001772 u
Fe (238.204 nm)51.839092 o ppm 0.058418 0.11 204076.474387 51.839092 o
Fe H (259.940 nm)50.701900 ppm 0.037648 0.07 81986.500000 50.701900
K (766.491 nm)0.041596 u ppm 0.040771 98.02 -372.679000 0.041596 u
Li (670.783 nm)-0.003621 u ppm 0.001197 33.06 -4415.270000 -0.003621 u
Mg (279.078 nm)-0.004237 u ppm 0.000088 2.08 -199.655000 -0.004237 u
Mn (257.610 nm)-0.000938 u ppm 0.000034 3.64 -245.906000 -0.000938 u
Mo (202.032 nm)0.000400 u ppm 0.000604 > 100.00 5.461160 0.000400 u
Na (589.592 nm)258.901000 o ppm 0.712818 0.28 3148030.000000 258.901000 o
Na H (589.593 nm)250.365807 ppm 0.427144 0.17 2283427.236274 250.365807
Ni (231.604 nm)0.000225 u ppm 0.000333 > 100.00 -9.442340 0.000225 u
P (213.618 nm)5.013980 ppm 0.015479 0.31 5921.580000 5.013980
Pb (220.353 nm)0.000622 u ppm 0.003442 > 100.00 -1.784600 0.000622 u
S (181.972 nm)5.062558 ppm 0.023854 0.47 1057.017449 5.062558
Sb (206.834 nm)-0.000179 u ppm 0.001926 > 100.00 5.371840 -0.000179 u
Se (196.026 nm)0.003834 ppm 0.003291 85.83 1.924870 0.003834
Si (288.158 nm)0.026248 ppm 0.001784 6.80 902.906000 0.026248
Sn (189.925 nm)0.001188 ppm 0.001573 > 100.00 3.079420 0.001188
Sr (421.552 nm)0.000464 ppm 0.000043 9.33 112.052861 0.000464
Th (288.505 nm)5.093150 ppm 0.009856 0.19 9778.130000 5.093150
Ti (336.122 nm)0.000844 ppm 0.000077 9.11 -26.002000 0.000844
Tl (190.794 nm)-0.005060 u ppm 0.002919 57.68 -8.917700 -0.005060 u
U (409.013 nm)2.569510 Q ppm 0.008006 0.31 11471.100000 Q 2.569510 Q
V (292.401 nm)-0.000132 u ppm 0.000357 > 100.00 243.105000 -0.000132 u
Zn (206.200 nm)0.001082 ppm 0.000379 35.01 6.495210 0.001082
Zr (343.823 nm)-0.001119 u ppm 0.000119 10.66 -28.633800 -0.001119 u
Test Report
52A112023.esws
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Page 895 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 12:49:51 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.477607 ppm 0.000213 0.04 1224664.151024 0.477607
Ag (328.068 nm)0.511497 ppm 0.001198 0.23 27312.200000 0.511497
Al (394.401 nm)0.507584 ppm 0.000834 0.16 6700.370000 0.507584
Al H (396.152 nm)0.519795 u ppm 0.003769 0.73 2386.630000 0.519795 u
As (188.980 nm)0.516547 ppm 0.001108 0.21 425.760000 0.516547
B (249.678 nm)0.510036 ppm 0.001464 0.29 4285.010000 0.510036
Ba (493.408 nm)0.515231 ppm 0.001746 0.34 78040.500000 0.515231
Be (234.861 nm)0.507673 ppm 0.002611 0.51 84892.000000 0.507673
Bi (223.061 nm)1.034380 ppm 0.004958 0.48 1541.990000 1.034380
Ca (315.887 nm)5.154471 ppm 0.013693 0.27 3452.260749 5.154471
Cd (214.439 nm)0.518217 ppm 0.000777 0.15 7746.340000 0.518217
Co (228.615 nm)0.519360 ppm 0.001113 0.21 9967.120000 0.519360
Cr (205.560 nm)0.521195 ppm 0.001882 0.36 2143.750000 0.521195
Cu (324.754 nm)0.518086 ppm 0.000673 0.13 24928.700000 0.518086
Fe (238.204 nm)2.583378 ppm 0.006222 0.24 10192.276052 2.583378
Fe H (259.940 nm)2.619610 u ppm 0.005135 0.20 4104.340000 2.619610 u
K (766.491 nm)51.866000 ppm 0.247226 0.48 92737.800000 51.866000
Li (670.783 nm)0.513611 ppm 0.001876 0.37 14820.300000 0.513611
Mg (279.078 nm)20.434000 ppm 0.022403 0.11 68353.200000 20.434000
Mn (257.610 nm)0.513490 ppm 0.000446 0.09 137015.000000 0.513490
Mo (202.032 nm)0.515718 ppm 0.001848 0.36 2562.510000 0.515718
Na (589.592 nm)26.025600 ppm 0.100127 0.38 323441.000000 26.025600
Na H (589.593 nm)15.689220 u ppm 0.173501 1.11 233497.662821 15.689220 u
Ni (231.604 nm)0.519975 ppm 0.001271 0.24 1760.750000 0.519975
P (213.618 nm)0.006387 ppm 0.002366 37.04 -31.028200 0.006387
Pb (220.353 nm)0.525245 ppm 0.002173 0.41 1203.350000 0.525245
S (181.972 nm)0.037031 ppm 0.010243 27.66 34.147084 0.037031
Sb (206.834 nm)0.513640 ppm 0.000841 0.16 627.499000 0.513640
Se (196.026 nm)0.513209 ppm 0.006105 1.19 320.023000 0.513209
Si (288.158 nm)5.086040 ppm 0.021823 0.43 37914.700000 5.086040
Sn (189.925 nm)0.515107 ppm 0.001700 0.33 348.426000 0.515107
Sr (421.552 nm)0.514843 ppm 0.001810 0.35 113686.786637 0.514843
Th (288.505 nm)0.032330 ppm 0.004760 14.72 308.782000 0.032330
Ti (336.122 nm)0.513890 ppm 0.000604 0.12 55968.300000 0.513890
Tl (190.794 nm)0.520825 ppm 0.002131 0.41 561.886000 0.520825
U (409.013 nm)-0.003541 u ppm 0.003445 97.29 -5.630240 -0.003541 u
V (292.401 nm)0.516180 ppm 0.000206 0.04 21452.800000 0.516180
Zn (206.200 nm)0.518955 ppm 0.002810 0.54 1123.220000 0.518955
Zr (343.823 nm)0.504164 ppm 0.001028 0.20 41094.900000 0.504164
Test Report
52A112023.esws
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Page 896 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 12:54:14 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000079 ppm 0.000010 12.89 -390.678825 0.000079
Ag (328.068 nm)0.000039 u ppm 0.000177 > 100.00 -26.924300 0.000039 u
Al (394.401 nm)0.001001 u ppm 0.001475 > 100.00 463.177000 0.001001 u
Al H (396.152 nm)-0.000117 u ppm 0.002663 > 100.00 50.038500 -0.000117 u
As (188.980 nm)0.004525 ppm 0.001275 28.16 0.355674 0.004525
B (249.678 nm)0.001007 ppm 0.000085 8.45 24.610400 0.001007
Ba (493.408 nm)-0.000004 u ppm 0.000042 > 100.00 -1.236740 -0.000004 u
Be (234.861 nm)0.000033 ppm 0.000012 35.56 45.318300 0.000033
Bi (223.061 nm)-0.000807 u ppm 0.001946 > 100.00 2.885520 -0.000807 u
Ca (315.887 nm)-0.000882 u ppm 0.008179 > 100.00 -24.607643 -0.000882 u
Cd (214.439 nm)0.000062 ppm 0.000048 76.91 1.005660 0.000062
Co (228.615 nm)-0.000144 u ppm 0.000023 15.84 40.110100 -0.000144 u
Cr (205.560 nm)-0.000427 u ppm 0.000369 86.37 -0.235191 -0.000427 u
Cu (324.754 nm)-0.000011 u ppm 0.000339 > 100.00 765.078000 -0.000011 u
Fe (238.204 nm)0.000533 ppm 0.000503 94.46 18.703892 0.000533
Fe H (259.940 nm)0.096241 u ppm 0.001935 2.01 17.063000 0.096241 u
K (766.491 nm)0.012190 u ppm 0.054034 > 100.00 -425.512000 0.012190 u
Li (670.783 nm)-0.004509 Su ppm 0.000978 21.69 -4448.280000 S -0.004509 Su
Mg (279.078 nm)-0.000513 u ppm 0.001432 > 100.00 7.147310 -0.000513 u
Mn (257.610 nm)-0.000006 u ppm 0.000026 > 100.00 2.901890 -0.000006 u
Mo (202.032 nm)0.000509 ppm 0.000245 48.17 6.002000 0.000509
Na (589.592 nm)0.215685 ppm 0.003545 1.64 3657.440000 0.215685
Na H (589.593 nm)-10.117083 u ppm 0.007386 0.07 3107.952559 -10.117083 u
Ni (231.604 nm)-0.000140 u ppm 0.000283 > 100.00 -10.687000 -0.000140 u
P (213.618 nm)0.000818 u ppm 0.004580 > 100.00 4.076140 0.000818 u
Pb (220.353 nm)-0.000919 u ppm 0.001209 > 100.00 -3.730560 -0.000919 u
S (181.972 nm)0.011887 ppm 0.007275 61.20 26.489192 0.011887
Sb (206.834 nm)-0.000007 u ppm 0.002678 > 100.00 1.994940 -0.000007 u
Se (196.026 nm)-0.003539 u ppm 0.000364 10.30 2.843760 -0.003539 u
Si (288.158 nm)0.003921 ppm 0.002550 65.04 740.736000 0.003921
Sn (189.925 nm)0.001701 ppm 0.000900 52.91 3.424270 0.001701
Sr (421.552 nm)0.000033 ppm 0.000032 95.91 16.933962 0.000033
Th (288.505 nm)0.006183 ppm 0.001925 31.13 272.126000 0.006183
Ti (336.122 nm)0.000096 ppm 0.000067 69.66 -107.597000 0.000096
Tl (190.794 nm)0.001102 u ppm 0.003432 > 100.00 -1.292160 0.001102 u
U (409.013 nm)-0.002393 u ppm 0.001931 80.67 12.934400 -0.002393 u
V (292.401 nm)-0.000155 u ppm 0.000115 74.61 -45.902600 -0.000155 u
Zn (206.200 nm)-0.001196 u ppm 0.000632 52.82 1.583390 -0.001196 u
Zr (343.823 nm)0.000142 ppm 0.000063 44.63 3.919800 0.000142
Test Report
52A112023.esws
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Page 897 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 12:58:15 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014765 ppm 0.000013 0.09 37363.915251 0.014765
Ag (328.068 nm)0.009785 ppm 0.000081 0.82 491.127000 0.009785
Al (394.401 nm)0.093181 ppm 0.000870 0.93 1608.330000 0.093181
Al H (396.152 nm)0.097032 u ppm 0.002051 2.11 486.645000 0.097032 u
As (188.980 nm)0.016880 ppm 0.001422 8.42 10.619400 0.016880
B (249.678 nm)0.098837 ppm 0.000077 0.08 843.415000 0.098837
Ba (493.408 nm)0.010221 ppm 0.000064 0.63 1547.750000 0.010221
Be (234.861 nm)0.001014 ppm 0.000020 1.99 210.675000 0.001014
Bi (223.061 nm)-0.002411 Qu ppm 0.002193 90.96 0.499724 Q -0.002411 Qu
Ca (315.887 nm)0.205791 ppm 0.002136 1.04 114.777136 0.205791
Cd (214.439 nm)0.005120 ppm 0.000134 2.62 76.631400 0.005120
Co (228.615 nm)0.010578 ppm 0.000271 2.56 244.945000 0.010578
Cr (205.560 nm)0.009915 ppm 0.000506 5.10 42.208200 0.009915
Cu (324.754 nm)0.015039 ppm 0.000138 0.91 1460.130000 0.015039
Fe (238.204 nm)0.103155 ppm 0.000558 0.54 422.729253 0.103155
Fe H (259.940 nm)0.195203 u ppm 0.002494 1.28 177.359000 0.195203 u
K (766.491 nm)3.093940 ppm 0.026511 0.86 5111.320000 3.093940
Li (670.783 nm)0.015907 ppm 0.002189 13.76 -3689.050000 0.015907
Mg (279.078 nm)0.203223 ppm 0.001340 0.66 688.002000 0.203223
Mn (257.610 nm)0.010458 ppm 0.000011 0.10 2794.960000 0.010458
Mo (202.032 nm)0.020308 ppm 0.000586 2.88 104.246000 0.020308
Na (589.592 nm)1.224370 ppm 0.013089 1.07 16042.800000 1.224370
Na H (589.593 nm)-9.117154 u ppm 0.010112 0.11 11953.544390 -9.117154 u
Ni (231.604 nm)0.042063 ppm 0.000335 0.80 133.030000 0.042063
P (213.618 nm)2.850500 ppm 0.005298 0.19 3367.060000 2.850500
Pb (220.353 nm)0.009266 ppm 0.000722 7.79 19.703800 0.009266
S (181.972 nm)0.101250 ppm 0.004237 4.18 44.755114 0.101250
Sb (206.834 nm)0.020941 ppm 0.001620 7.74 27.440700 0.020941
Se (196.026 nm)0.018989 ppm 0.001841 9.70 16.664300 0.018989
Si (288.158 nm)0.474583 ppm 0.002776 0.58 4190.180000 0.474583
Sn (189.925 nm)0.099147 ppm 0.001049 1.06 68.906000 0.099147
Sr (421.552 nm)0.010110 ppm 0.000089 0.88 2242.014649 0.010110
Th (288.505 nm)0.001870 Q ppm 0.000834 44.59 264.134000 Q 0.001870 Q
Ti (336.122 nm)0.010089 ppm 0.000042 0.41 983.226000 0.010089
Tl (190.794 nm)0.017687 ppm 0.000996 5.63 16.670500 0.017687
U (409.013 nm)0.061590 ppm 0.002446 3.97 294.328000 0.061590
V (292.401 nm)0.010054 ppm 0.000104 1.03 374.229000 0.010054
Zn (206.200 nm)0.019727 ppm 0.001187 6.02 46.701000 0.019727
Zr (343.823 nm)0.010149 ppm 0.000032 0.32 819.808000 0.010149
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 27 of 287
Page 898 of 1261
Solution Name: LB 280-633855/1-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LB 280-633855/1-B 11/20/2023 1:02:34 PM 1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000063 u ppm 0.000005 8.45 525.097358 -0.000063 u
Ag (328.068 nm)0.000381 ppm 0.000231 60.57 -7.904100 0.000381
Al (394.401 nm)0.016652 ppm 0.001194 7.17 649.441000 0.016652
Al H (396.152 nm)0.010770 u ppm 0.002546 23.64 98.966500 0.010770 u
As (188.980 nm)0.007611 ppm 0.001018 13.37 2.918610 0.007611
B (249.678 nm)0.005491 ppm 0.000155 2.83 62.141700 0.005491
Ba (493.408 nm)0.003279 ppm 0.000137 4.18 496.198000 0.003279
Be (234.861 nm)0.000068 ppm 0.000030 43.97 52.233000 0.000068
Bi (223.061 nm)0.000505 u ppm 0.001882 > 100.00 4.835370 0.000505 u
Ca (315.887 nm)0.106059 ppm 0.004392 4.14 47.515396 0.106059
Cd (214.439 nm)0.000326 ppm 0.000230 70.70 4.966730 0.000326
Co (228.615 nm)0.000549 ppm 0.000178 32.39 53.329000 0.000549
Cr (205.560 nm)0.004736 ppm 0.000273 5.77 21.007900 0.004736
Cu (324.754 nm)0.003789 ppm 0.000226 5.96 946.862000 0.003789
Fe (238.204 nm)0.078775 ppm 0.001035 1.31 326.705891 0.078775
Fe H (259.940 nm)0.171947 u ppm 0.002293 1.33 139.689000 0.171947 u
K (766.491 nm)1.504730 ppm 0.040006 2.66 2256.060000 1.504730
Li (670.783 nm)-0.005596 u ppm 0.000511 9.13 -4488.700000 -0.005596 u
Mg (279.078 nm)0.015434 ppm 0.001007 6.52 60.335100 0.015434
Mn (257.610 nm)0.001038 ppm 0.000023 2.18 281.384000 0.001038
Mo (202.032 nm)-0.000280 u ppm 0.000359 > 100.00 2.089400 -0.000280 u
Na (589.592 nm)1676.740000 o ppm 3.910820 0.23 20382100.000000 1676.740000 o
Na H (589.593 nm)1841.899538 ppm 53.5140
06 2.91 16216014.328980 1841.899538
Ni (231.604 nm)0.000686 u ppm 0.001347 > 100.00 -7.872740 0.000686 u
P (213.618 nm)0.011757 ppm 0.000958 8.15 16.791500 0.011757
Pb (220.353 nm)0.004530 ppm 0.003222 71.13 8.760410 0.004530
S (181.972 nm)0.075634 ppm 0.008516 11.26 39.489068 0.075634
Sb (206.834 nm)-0.001683 u ppm 0.001463 86.95 -0.008556 -0.001683 u
Se (196.026 nm)0.004535 ppm 0.000495 10.91 7.790670 0.004535
Si (288.158 nm)0.028934 ppm 0.001434 4.96 921.836000 0.028934
Sn (189.925 nm)-0.000895 u ppm 0.001901 > 100.00 1.679450 -0.000895 u
Sr (421.552 nm)0.000908 ppm 0.000032 3.50 210.261524 0.000908
Th (288.505 nm)0.022889 ppm 0.000844 3.69 303.243000 0.022889
Ti (336.122 nm)0.000370 ppm 0.000041 11.20 -77.558800 0.000370
Tl (190.794 nm)-0.001992 u ppm 0.000143 7.16 -4.650150 -0.001992 u
U (409.013 nm)-0.045052 u ppm 0.005014 11.13 -174.681000 -0.045052 u
V (292.401 nm)0.000125 u ppm 0.000224 > 100.00 -33.024100 0.000125 u
Zn (206.200 nm)0.004373 ppm 0.000327 7.48 13.593600 0.004373
Zr (343.823 nm)0.000236 ppm 0.000193 81.59 11.707000 0.000236
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 28 of 287
Page 899 of 1261
Solution Name: LCS 280-633855/2-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-633855/2-B 11/20/2023 1:07:11 PM 1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.934507 ppm 0.002486 0.27 2397670.396255 0.934507
Ag (328.068 nm)0.243321 ppm 0.000559 0.23 12630.600000 0.243321
Al (394.401 nm)9.416510 o ppm 0.029601 0.31 116324.000000 9.416510 o
Al H (396.152 nm)9.110230 ppm 0.007759 0.09 40993.800000 9.110230
As (188.980 nm)1.557700 o ppm 0.004635 0.30 1290.770000 1.557700 o
B (249.678 nm)1.914320 ppm 0.002230 0.12 16038.400000 1.914320
Ba (493.408 nm)2.866600 ppm 0.001305 0.05 434185.000000 2.866600
Be (234.861 nm)0.920025 ppm 0.002491 0.27 153874.000000 0.920025
Bi (223.061 nm)0.003732 ppm 0.002971 79.61 9.633980 0.003732
Ca (315.887 nm)47.573317 o ppm 0.045274 0.10 32060.340361 47.573317 o
Cd (214.439 nm)1.128620 o ppm 0.004769 0.42 16871.300000 1.128620 o
Co (228.615 nm)0.938308 ppm 0.001657 0.18 17972.900000 0.938308
Cr (205.560 nm)1.898610 o ppm 0.006464 0.34 7809.150000 1.898610 o
Cu (324.754 nm)1.310090 o ppm 0.007693 0.59 61861.500000 1.310090 o
Fe (238.204 nm)9.485366 o ppm 0.012678 0.13 37368.923753 9.485366 o
Fe H (259.940 nm)9.402610 ppm 0.011291 0.12 15091.200000 9.402610
K (766.491 nm)47.736300 ppm 0.121188 0.25 85318.100000 47.736300
Li (670.783 nm)0.941944 ppm 0.003520 0.37 30749.800000 0.941944
Mg (279.078 nm)47.359900 o ppm 0.158412 0.33 158408.000000 47.359900 o
Mn (257.610 nm)0.936635 ppm 0.002223 0.24 249919.000000 0.936635
Mo (202.032 nm)0.947693 ppm 0.002531 0.27 4706.010000 0.947693
Na (589.592 nm)62.060000 o ppm 0.168257 0.27 789126.000000 62.060000 o
Na H (589.593 nm)52.515753 ppm 0.061575 0.12 576334.967698 52.515753
Ni (231.604 nm)0.912415 ppm 0.004878 0.53 3097.360000 0.912415
P (213.618 nm)19.097500 o ppm 0.050806 0.27 22454.200000 19.097500 o
Pb (220.353 nm)1.936110 ppm 0.002595 0.13 4443.330000 1.936110
S (181.972 nm)18.211398 o ppm 0.056325 0.31 3738.444734 18.211398 o
Sb (206.834 nm)0.988307 ppm 0.004926 0.50 1212.460000 0.988307
Se (196.026 nm)1.141360 o ppm 0.013778 1.21 705.052000 1.141360 o
Si (288.158 nm)9.056390 ppm 0.036485 0.40 66964.100000 9.056390
Sn (189.925 nm)0.928578 ppm 0.004597 0.50 626.272000 0.928578
Sr (421.552 nm)0.939656 ppm 0.000802 0.09 207485.230142 0.939656
Th (288.505 nm)0.058507 ppm 0.002603 4.45 351.660000 0.058507
Ti (336.122 nm)0.935121 ppm 0.002062 0.22 102026.000000 0.935121
Tl (190.794 nm)0.937811 ppm 0.006166 0.66 1013.590000 0.937811
U (409.013 nm)-0.001255 u ppm 0.004573 > 100.00 -2.064860 -0.001255 u
V (292.401 nm)0.946821 ppm 0.002358 0.25 39102.000000 0.946821
Zn (206.200 nm)0.931925 ppm 0.003606 0.39 2013.730000 0.931925
Zr (343.823 nm)0.935321 ppm 0.002008 0.21 76251.900000 0.935321
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 29 of 287
Page 900 of 1261
Solution Name: 160-51789-B-1-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-C 11/20/2023 1:11:34 PM 1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.008364 ppm 0.000015 0.18 23982.557066 0.008364
Ag (328.068 nm)0.002857 ppm 0.000026 0.89 -253.204000 0.002857
Al (394.401 nm)8.468580 o ppm 0.025073 0.30 104648.000000 8.468580 o
Al H (396.152 nm)7.600090 ppm 0.014059 0.18 34206.900000 7.600090
As (188.980 nm)0.023355 ppm 0.003772 16.15 15.728100 0.023355
B (249.678 nm)0.056843 ppm 0.000623 1.10 491.935000 0.056843
Ba (493.408 nm)1.408280 ppm 0.003377 0.24 213374.000000 1.408280
Be (234.861 nm)0.000906 ppm 0.000025 2.73 584.896000 0.000906
Bi (223.061 nm)-0.002566 u ppm 0.000746 29.08 0.270129 -0.002566 u
Ca (315.887 nm)118.587104 o ppm 0.209309 0.18 79953.394273 118.587104 o
Cd (214.439 nm)0.018818 ppm 0.000182 0.97 287.585000 0.018818
Co (228.615 nm)0.108321 ppm 0.000212 0.20 2122.640000 0.108321
Cr (205.560 nm)0.349394 ppm 0.003453 0.99 1438.460000 0.349394
Cu (324.754 nm)6.895690 o ppm 0.006587 0.10 322459.000000 6.895690 o
Fe (238.204 nm)30.509328 o ppm 0.066788 0.22 120114.028714 30.509328 o
Fe H (259.940 nm)29.938500 ppm 0.055376 0.18 48354.600000 29.938500
K (766.491 nm)3.461200 ppm 0.034613 1.00 5771.150000 3.461200
Li (670.783 nm)0.009170 ppm 0.001466 15.99 -3939.570000 0.009170
Mg (279.078 nm)20.523700 ppm 0.104315 0.51 68634.600000 20.523700
Mn (257.610 nm)4.313780 o ppm 0.021681 0.50 1151010.000000 4.313780 o
Mo (202.032 nm)0.009601 ppm 0.000163 1.69 51.120600 0.009601
Na (589.592 nm)1427.880000 o ppm 2.695990 0.19 17373700.000000 1427.880000 o
Na H (589.593 nm)1575.839484 ppm 20.6890
40 1.31 13899090.759190 1575.839484
Ni (231.604 nm)0.529694 ppm 0.004603 0.87 1793.450000 0.529694
P (213.618 nm)1.042740 ppm 0.015070 1.45 872.752000 1.042740
Pb (220.353 nm)3.678670 ppm 0.018771 0.51 8452.220000 3.678670
S (181.972 nm)4.410011 ppm 0.005142 0.12 930.145046 4.410011
Sb (206.834 nm)0.234116 ppm 0.001860 0.79 290.653000 0.234116
Se (196.026 nm)0.003599 ppm 0.002829 78.58 6.881150 0.003599
Si (288.158 nm)16.461000 o ppm 0.042688 0.26 120389.000000 16.461000 o
Sn (189.925 nm)0.027289 ppm 0.001084 3.97 20.619000 0.027289
Sr (421.552 nm)0.616057 ppm 0.001782 0.29 136034.732473 0.616057
Th (288.505 nm)0.099486 ppm 0.003283 3.30 510.972000 0.099486
Ti (336.122 nm)0.356554 ppm 0.001330 0.37 39048.100000 0.356554
Tl (190.794 nm)-0.001270 u ppm 0.000786 61.88 -4.820800 -0.001270 u
U (409.013 nm)-0.030434 u ppm 0.000851 2.79 -81.082500 -0.030434 u
V (292.401 nm)0.483909 ppm 0.002201 0.45 20174.600000 0.483909
Zn (206.200 nm)12.970900 o ppm 0.066358 0.51 27974.200000 12.970900 o
Zr (343.823 nm)0.027673 ppm 0.000130 0.47 2289.570000 0.027673
Test Report
52A112023.esws
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Page 901 of 1261
Solution Name: 183314-C-1 BC
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
183314-C-1 BC 11/20/2023 1:16:31 PM 3:90 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002420 ppm 0.000007 0.31 6722.220012 0.002420
Ag (328.068 nm)0.000460 ppm 0.000112 24.31 -5.318550 0.000460
Al (394.401 nm)0.013834 ppm 0.000473 3.42 622.280000 0.013834
Al H (396.152 nm)-0.006883 u ppm 0.001721 25.01 19.632600 -0.006883 u
As (188.980 nm)0.003924 ppm 0.001122 28.58 -0.144888 0.003924
B (249.678 nm)0.002843 ppm 0.000424 14.91 39.972800 0.002843
Ba (493.408 nm)0.049963 ppm 0.000378 0.76 7566.780000 0.049963
Be (234.861 nm)0.000197 ppm 0.000008 3.91 74.257900 0.000197
Bi (223.061 nm)0.001009 u ppm 0.003005 > 100.00 5.585680 0.001009 u
Ca (315.887 nm)44.171891 o ppm 0.322896 0.73 29766.353886 44.171891 o
Cd (214.439 nm)0.000451 ppm 0.000090 19.96 6.847980 0.000451
Co (228.615 nm)0.000300 u ppm 0.000313 > 100.00 48.538600 0.000300 u
Cr (205.560 nm)-0.000101 u ppm 0.000547 > 100.00 1.092750 -0.000101 u
Cu (324.754 nm)0.001035 ppm 0.000721 69.65 787.151000 0.001035
Fe (238.204 nm)0.118773 ppm 0.000778 0.65 484.158959 0.118773
Fe H (259.940 nm)0.208176 u ppm 0.002527 1.21 198.371000 0.208176 u
K (766.491 nm)0.830008 ppm 0.048189 5.81 1043.820000 0.830008
Li (670.783 nm)0.000642 u ppm 0.002532 > 100.00 -4256.730000 0.000642 u
Mg (279.078 nm)35.271200 ppm 0.263547 0.75 117980.000000 35.271200
Mn (257.610 nm)0.012819 ppm 0.000086 0.67 3424.820000 0.012819
Mo (202.032 nm)0.004496 ppm 0.000251 5.58 25.785600 0.004496
Na (589.592 nm)4.015760 ppm 0.043521 1.08 50438.500000 4.015760
Na H (589.593 nm)-6.106757 u ppm 0.011607 0.19 38651.286301 -6.106757 u
Ni (231.604 nm)-0.000462 u ppm 0.000562 > 100.00 -11.783000 -0.000462 u
P (213.618 nm)0.008915 ppm 0.000357 4.00 13.449200 0.008915
Pb (220.353 nm)0.000792 u ppm 0.001946 > 100.00 0.255858 0.000792 u
S (181.972 nm)39.740935 o ppm 0.231319 0.58 8118.139049 39.740935 o
Sb (206.834 nm)-0.002255 u ppm 0.001137 50.43 -0.751109 -0.002255 u
Se (196.026 nm)0.001756 u ppm 0.004977 > 100.00 6.088750 0.001756 u
Si (288.158 nm)3.125950 ppm 0.015280 0.49 23422.700000 3.125950
Sn (189.925 nm)-0.002744 u ppm 0.001473 53.67 0.436861 -0.002744 u
Sr (421.552 nm)0.318875 ppm 0.001616 0.51 70417.207567 0.318875
Th (288.505 nm)0.029230 ppm 0.002763 9.45 316.171000 0.029230
Ti (336.122 nm)-0.000095 u ppm 0.000039 41.45 -31.881700 -0.000095 u
Tl (190.794 nm)0.001839 ppm 0.000195 10.61 -0.502109 0.001839
U (409.013 nm)0.039252 ppm 0.002601 6.63 196.673000 0.039252
V (292.401 nm)0.000480 ppm 0.000161 33.47 -20.662500 0.000480
Zn (206.200 nm)0.219789 ppm 0.002062 0.94 478.107000 0.219789
Zr (343.823 nm)0.000096 ppm 0.000059 60.74 0.364053 0.000096
Test Report
52A112023.esws
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Page 902 of 1261
Solution Name: 160-51789-B-1- SD @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1- SD @5 11/20/2023 1:20:48 PM 1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001543 ppm 0.000016 1.06 4015.383948 0.001543
Ag (328.068 nm)0.000632 ppm 0.000079 12.47 -72.125400 0.000632
Al (394.401 nm)1.678200 ppm 0.001107 0.07 21100.700000 1.678200
Al H (396.152 nm)1.536700 ppm 0.001991 0.13 6956.800000 1.536700
As (188.980 nm)0.005728 ppm 0.000376 6.56 1.298350 0.005728
B (249.678 nm)0.010622 ppm 0.000411 3.87 105.083000 0.010622
Ba (493.408 nm)0.283826 ppm 0.000659 0.23 43003.800000 0.283826
Be (234.861 nm)0.000214 ppm 0.000041 19.03 157.430000 0.000214
Bi (223.061 nm)0.000127 u ppm 0.002040 > 100.00 4.273350 0.000127 u
Ca (315.887 nm)24.576047 o ppm 0.064031 0.26 16550.542805 24.576047 o
Cd (214.439 nm)0.004194 ppm 0.000037 0.88 64.063500 0.004194
Co (228.615 nm)0.022580 ppm 0.000337 1.49 476.316000 0.022580
Cr (205.560 nm)0.073129 ppm 0.000649 0.89 302.277000 0.073129
Cu (324.754 nm)1.373270 o ppm 0.003043 0.22 64828.900000 1.373270 o
Fe (238.204 nm)6.335973 o ppm 0.016881 0.27 24957.640482 6.335973 o
Fe H (259.940 nm)6.253010 ppm 0.024259 0.39 9989.610000 6.253010
K (766.491 nm)0.476725 ppm 0.102666 21.54 409.097000 0.476725
Li (670.783 nm)-0.046985 u ppm 0.038080 81.05 -6027.930000 -0.046985 u
Mg (279.078 nm)4.360630 ppm 0.004808 0.11 14590.000000 4.360630
Mn (257.610 nm)0.907323 ppm 0.000745 0.08 242098.000000 0.907323
Mo (202.032 nm)0.002555 ppm 0.000454 17.77 16.158500 0.002555
Na (589.592 nm)323.207000 o ppm 3.303580 1.02 3933010.000000 323.207000 o
Na H (589.593 nm)228.438934 ppm 51.5009
70 22.54 2093936.331756 228.438934
Ni (231.604 nm)0.110164 ppm 0.001540 1.40 364.907000 0.110164
P (213.618 nm)0.206922 ppm 0.000589 0.28 175.515000 0.206922
Pb (220.353 nm)0.778649 ppm 0.002295 0.29 1787.770000 0.778649
S (181.972 nm)0.894253 ppm 0.006782 0.76 207.845633 0.894253
Sb (206.834 nm)0.047639 ppm 0.000871 1.83 60.753300 0.047639
Se (196.026 nm)0.000012 u ppm 0.004048 > 100.00 4.959120 0.000012 u
Si (288.158 nm)3.299420 ppm 0.002569 0.08 24699.600000 3.299420
Sn (189.925 nm)0.004423 u ppm 0.004439 > 100.00 5.252910 0.004423 u
Sr (421.552 nm)0.125220 ppm 0.000360 0.29 27658.147065 0.125220
Th (288.505 nm)0.025718 ppm 0.003264 12.69 322.303000 0.025718
Ti (336.122 nm)0.072975 ppm 0.000084 0.12 7898.590000 0.072975
Tl (190.794 nm)-0.001352 u ppm 0.000612 45.26 -4.152420 -0.001352 u
U (409.013 nm)-0.001008 u ppm 0.002696 > 100.00 25.036800 -0.001008 u
V (292.401 nm)0.098613 ppm 0.000171 0.17 4079.390000 0.098613
Zn (206.200 nm)2.790980 o ppm 0.000340 0.01 6022.530000 2.790980 o
Zr (343.823 nm)0.005562 ppm 0.000089 1.61 454.347000 0.005562
Test Report
52A112023.esws
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Page 903 of 1261
Solution Name: 160-51789-B-1-D MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-D MS 11/20/2023 1:25:04 PM 1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.287619 o ppm 0.004074 0.32 3305986.851113 1.287619 o
Ag (328.068 nm)0.261986 ppm 0.001121 0.43 13205.200000 0.261986
Al (394.401 nm)20.114300 o ppm 0.052462 0.26 247950.000000 20.114300 o
Al H (396.152 nm)18.182500 ppm 0.066698 0.37 81766.600000 18.182500
As (188.980 nm)1.708860 o ppm 0.008556 0.50 1416.060000 1.708860 o
B (249.678 nm)2.117870 ppm 0.010689 0.50 17742.000000 2.117870
Ba (493.408 nm)4.499670 ppm 0.015454 0.34 681615.000000 4.499670
Be (234.861 nm)0.922802 ppm 0.007221 0.78 154781.000000 0.922802
Bi (223.061 nm)-0.001297 u ppm 0.001660 > 100.00 2.156270 -0.001297 u
Ca (315.887 nm)181.328860 o ppm 0.556518 0.31 122267.632365 181.328860 o
Cd (214.439 nm)1.126670 o ppm 0.005690 0.51 16849.300000 1.126670 o
Co (228.615 nm)1.076980 ppm 0.004097 0.38 20635.300000 1.076980
Cr (205.560 nm)2.306020 o ppm 0.008462 0.37 9484.680000 2.306020 o
Cu (324.754 nm)9.234220 o ppm 0.021256 0.23 431533.000000 9.234220 o
Fe (238.204 nm)43.788453 o ppm 0.117480 0.27 172399.875538 43.788453 o
Fe H (259.940 nm)42.956200 ppm 0.123303 0.29 69440.200000 42.956200
K (766.491 nm)57.661300 ppm 0.289478 0.50 103150.000000 57.661300
Li (670.783 nm)1.063420 ppm 0.004665 0.44 35267.300000 1.063420
Mg (279.078 nm)69.411300 o ppm 0.285815 0.41 232140.000000 69.411300 o
Mn (257.610 nm)5.670000 o ppm 0.023806 0.42 1512880.000000 5.670000 o
Mo (202.032 nm)0.978738 ppm 0.004100 0.42 4860.050000 0.978738
Na (589.592 nm)1620.360000 o ppm 8.526980 0.53 19749700.000000 1620.360000 o
Na H (589.593 nm)1800.568002 ppm 6.936574 0.39 15893294.828777 1800.568002
Ni (231.604 nm)1.451970 o ppm 0.008693 0.60 4934.540000 1.451970 o
P (213.618 nm)21.859200 o ppm 0.059739 0.27 25298.700000 21.859200 o
Pb (220.353 nm)6.014790 ppm 0.023225 0.39 13816.300000 6.014790
S (181.972 nm)24.111962 o ppm 0.084310 0.35 4949.275630 24.111962 o
Sb (206.834 nm)1.274500 o ppm 0.005354 0.42 1564.860000 1.274500 o
Se (196.026 nm)1.279880 o ppm 0.008280 0.65 789.594000 1.279880 o
Si (288.158 nm)27.668200 o ppm 0.084213 0.30 202286.000000 27.668200 o
Sn (189.925 nm)0.953136 ppm 0.011552 1.21 642.775000 0.953136
Sr (421.552 nm)1.672636 o ppm 0.005423 0.32 369326.859001 1.672636 o
Th (288.505 nm)0.143226 ppm 0.004558 3.18 580.182000 0.143226
Ti (336.122 nm)1.387220 o ppm 0.003822 0.28 151651.000000 1.387220 o
Tl (190.794 nm)0.875108 ppm 0.004846 0.55 944.325000 0.875108
U (409.013 nm)-0.052121 u ppm 0.003584 6.88 -193.792000 -0.052121 u
V (292.401 nm)1.511300 o ppm 0.004062 0.27 62679.800000 1.511300 o
Zn (206.200 nm)15.131700 o ppm 0.054670 0.36 32633.500000 15.131700 o
Zr (343.823 nm)0.997455 ppm 0.002640 0.26 81363.600000 0.997455
Test Report
52A112023.esws
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Page 904 of 1261
Solution Name: 160-51789-B-1-E MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-E MSD 11/20/2023 1:29:36 PM 1:6 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.127731 o ppm 0.002083 0.18 2895015.545800 1.127731 o
Ag (328.068 nm)0.235550 ppm 0.000328 0.14 11946.300000 0.235550
Al (394.401 nm)16.324000 o ppm 0.036479 0.22 201295.000000 16.324000 o
Al H (396.152 nm)14.767700 ppm 0.006557 0.04 66419.800000 14.767700
As (188.980 nm)1.516450 o ppm 0.003159 0.21 1256.280000 1.516450 o
B (249.678 nm)1.864250 ppm 0.001656 0.09 15619.300000 1.864250
Ba (493.408 nm)3.785850 ppm 0.019038 0.50 573476.000000 3.785850
Be (234.861 nm)0.816120 ppm 0.003393 0.42 136830.000000 0.816120
Bi (223.061 nm)-0.001159 u ppm 0.000496 42.82 2.361540 -0.001159 u
Ca (315.887 nm)141.851540 o ppm 0.132643 0.09 95643.374231 141.851540 o
Cd (214.439 nm)1.011410 ppm 0.002225 0.22 15124.400000 1.011410
Co (228.615 nm)0.942869 ppm 0.001886 0.20 18069.200000 0.942869
Cr (205.560 nm)2.011960 o ppm 0.003708 0.18 8275.380000 2.011960 o
Cu (324.754 nm)7.005600 o ppm 0.026452 0.38 327581.000000 7.005600 o
Fe (238.204 nm)33.940992 o ppm 0.041579 0.12 133634.811858 33.940992 o
Fe H (259.940 nm)33.267600 ppm 0.078631 0.24 53747.100000 33.267600
K (766.491 nm)49.919500 ppm 0.274135 0.55 89240.600000 49.919500
Li (670.783 nm)0.929353 ppm 0.004613 0.50 30281.500000 0.929353
Mg (279.078 nm)58.455100 o ppm 0.173075 0.30 195500.000000 58.455100 o
Mn (257.610 nm)4.336510 o ppm 0.012257 0.28 1157080.000000 4.336510 o
Mo (202.032 nm)0.874924 ppm 0.003076 0.35 4344.920000 0.874924
Na (589.592 nm)1265.630000 o ppm 2.392700 0.19 15429600.000000 1265.630000 o
Na H (589.593 nm)1379.759229 ppm 31.5499
23 2.29 12203243.396467 1379.759229
Ni (231.604 nm)1.212210 o ppm 0.004323 0.36 4118.090000 1.212210 o
P (213.618 nm)19.269000 o ppm 0.034312 0.18 22360.400000 19.269000 o
Pb (220.353 nm)4.837460 ppm 0.009055 0.19 11111.200000 4.837460
S (181.972 nm)20.854935 o ppm 0.121728 0.58 4283.014361 20.854935 o
Sb (206.834 nm)1.092530 ppm 0.004112 0.38 1341.600000 1.092530
Se (196.026 nm)1.120780 o ppm 0.008968 0.80 692.110000 1.120780 o
Si (288.158 nm)21.957700 o ppm 0.091023 0.41 160723.000000 21.957700 o
Sn (189.925 nm)0.847853 ppm 0.004937 0.58 572.026000 0.847853
Sr (421.552 nm)1.377625 o ppm 0.004796 0.35 304188.574562 1.377625 o
Th (288.505 nm)0.125842 ppm 0.002198 1.75 531.542000 0.125842
Ti (336.122 nm)1.169370 o ppm 0.002599 0.22 127792.000000 1.169370 o
Tl (190.794 nm)0.795002 ppm 0.003365 0.42 857.878000 0.795002
U (409.013 nm)-0.038230 u ppm 0.001837 4.81 -137.732000 -0.038230 u
V (292.401 nm)1.261120 o ppm 0.003251 0.26 52274.200000 1.261120 o
Zn (206.200 nm)11.571400 o ppm 0.031026 0.27 24956.300000 11.571400 o
Zr (343.823 nm)0.880949 ppm 0.002055 0.23 71852.800000 0.880949
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 34 of 287
Page 905 of 1261
Solution Name: 160-51789-B-1-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-C 11/20/2023 1:34:04 PM 1:7 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.132259 ppm 0.000150 0.11 342022.145111 0.132259
Ag (328.068 nm)0.052175 ppm 0.000282 0.54 2380.500000 0.052175
Al (394.401 nm)9.481530 o ppm 0.017055 0.18 117116.000000 9.481530 o
Al H (396.152 nm)8.582430 ppm 0.041512 0.48 38621.800000 8.582430
As (188.980 nm)0.228634 ppm 0.002352 1.03 186.282000 0.228634
B (249.678 nm)0.158452 ppm 0.000448 0.28 1342.370000 0.158452
Ba (493.408 nm)1.511760 ppm 0.008941 0.59 229049.000000 1.511760
Be (234.861 nm)0.045568 ppm 0.000543 1.19 8057.850000 0.045568
Bi (223.061 nm)-0.001642 u ppm 0.001001 60.97 1.643170 -0.001642 u
Ca (315.887 nm)137.961180 o ppm 0.546867 0.40 93019.641253 137.961180 o
Cd (214.439 nm)0.064312 ppm 0.000149 0.23 967.752000 0.064312
Co (228.615 nm)0.154904 ppm 0.000511 0.33 3012.810000 0.154904
Cr (205.560 nm)0.392981 ppm 0.000940 0.24 1617.620000 0.392981
Cu (324.754 nm)6.931770 o ppm 0.020083 0.29 324139.000000 6.931770 o
Fe (238.204 nm)31.373310 o ppm 0.133253 0.42 123515.599248 31.373310 o
Fe H (259.940 nm)30.747800 ppm 0.103268 0.34 49665.500000 30.747800
K (766.491 nm)24.229100 ppm 0.145349 0.60 43083.900000 24.229100
Li (670.783 nm)0.082604 ppm 0.023009 27.85 -1208.610000 0.082604
Mg (279.078 nm)38.186400 ppm 0.124627 0.33 127699.000000 38.186400
Mn (257.610 nm)4.264050 o ppm 0.013003 0.30 1137740.000000 4.264050 o
Mo (202.032 nm)0.056709 ppm 0.000830 1.46 284.870000 0.056709
Na (589.592 nm)1480.500000 o ppm 45.4989
00 3.07 18014500.000000 1480.500000 o
Na H (589.593 nm)1201.103635 ppm 576.197
204 47.97 10619486.261316 1201.103635
Ni (231.604 nm)0.557073 ppm 0.002235 0.40 1886.810000 0.557073
P (213.618 nm)3.072290 ppm 0.004994 0.16 3265.580000 3.072290
Pb (220.353 nm)3.809060 ppm 0.003882 0.10 8752.380000 3.809060
S (181.972 nm)4.377224 ppm 0.022763 0.52 924.369687 4.377224
Sb (206.834 nm)0.333883 ppm 0.002844 0.85 412.207000 0.333883
Se (196.026 nm)0.213462 ppm 0.005083 2.38 135.543000 0.213462
Si (288.158 nm)21.064600 o ppm 0.050822 0.24 153870.000000 21.064600 o
Sn (189.925 nm)0.108617 ppm 0.003361 3.09 75.269800 0.108617
Sr (421.552 nm)0.668099 ppm 0.004149 0.62 147525.558716 0.668099
Th (288.505 nm)0.294138 ppm 0.001520 0.52 874.662000 0.294138
Ti (336.122 nm)0.403895 ppm 0.000664 0.16 44256.300000 0.403895
Tl (190.794 nm)0.170191 ppm 0.001889 1.11 181.253000 0.170191
U (409.013 nm)0.443423 ppm 0.002186 0.49 2008.370000 0.443423
V (292.401 nm)0.528842 ppm 0.001314 0.25 22035.200000 0.528842
Zn (206.200 nm)13.037300 o ppm 0.038693 0.30 28117.300000 13.037300 o
Zr (343.823 nm)0.075074 ppm 0.000083 0.11 6154.830000 0.075074
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 35 of 287
Page 906 of 1261
Solution Name: 160-51789-B-2-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-2-C 11/20/2023 1:38:21 PM 1:8 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.009297 ppm 0.000043 0.46 26685.563040 0.009297
Ag (328.068 nm)0.003582 ppm 0.000135 3.76 -407.600000 0.003582
Al (394.401 nm)9.648360 o ppm 0.040536 0.42 119169.000000 9.648360 o
Al H (396.152 nm)8.701830 ppm 0.009833 0.11 39158.400000 8.701830
As (188.980 nm)0.019158 ppm 0.002143 11.19 12.204900 0.019158
B (249.678 nm)0.064590 ppm 0.000331 0.51 556.775000 0.064590
Ba (493.408 nm)1.422700 ppm 0.002635 0.19 215571.000000 1.422700
Be (234.861 nm)0.000875 ppm 0.000016 1.84 631.355000 0.000875
Bi (223.061 nm)-0.001187 u ppm 0.002052 > 100.00 2.319590 -0.001187 u
Ca (315.887 nm)130.449566 o ppm 0.085323 0.07 87953.665407 130.449566 o
Cd (214.439 nm)0.025085 ppm 0.000181 0.72 382.076000 0.025085
Co (228.615 nm)0.147583 ppm 0.000901 0.61 2875.830000 0.147583
Cr (205.560 nm)0.267636 ppm 0.001423 0.53 1101.990000 0.267636
Cu (324.754 nm)8.259370 o ppm 0.052441 0.63 386075.000000 8.259370 o
Fe (238.204 nm)34.512136 o ppm 0.042737 0.12 135870.802368 34.512136 o
Fe H (259.940 nm)33.752600 ppm 0.025569 0.08 54532.600000 33.752600
K (766.491 nm)3.304700 ppm 0.038959 1.18 5489.990000 3.304700
Li (670.783 nm)0.009789 ppm 0.000372 3.80 -3916.530000 0.009789
Mg (279.078 nm)24.006600 ppm 0.119681 0.50 80281.400000 24.006600
Mn (257.610 nm)5.684410 o ppm 0.027458 0.48 1516720.000000 5.684410 o
Mo (202.032 nm)0.012760 ppm 0.001174 9.20 66.792300 0.012760
Na (589.592 nm)1522.570000 o ppm 2.402390 0.16 18524900.000000 1522.570000 o
Na H (589.593 nm)1786.847287 ppm 47.5537
17 2.66 15746414.758629 1786.847287
Ni (231.604 nm)0.615554 ppm 0.002971 0.48 2085.810000 0.615554
P (213.618 nm)1.297590 ppm 0.008042 0.62 1102.110000 1.297590
Pb (220.353 nm)3.539460 ppm 0.014728 0.42 8131.950000 3.539460
S (181.972 nm)5.993116 ppm 0.063818 1.06 1254.350966 5.993116
Sb (206.834 nm)0.293401 ppm 0.001716 0.59 362.228000 0.293401
Se (196.026 nm)0.004669 u ppm 0.004350 93.18 8.026520 0.004669 u
Si (288.158 nm)17.912900 o ppm 0.114259 0.64 130962.000000 17.912900 o
Sn (189.925 nm)0.033535 ppm 0.003889 11.60 24.815900 0.033535
Sr (421.552 nm)0.637138 ppm 0.001374 0.22 140689.394834 0.637138
Th (288.505 nm)0.116412 ppm 0.002858 2.46 559.095000 0.116412
Ti (336.122 nm)0.468747 ppm 0.001655 0.35 51316.500000 0.468747
Tl (190.794 nm)0.000527 u ppm 0.002448 > 100.00 -3.059770 0.000527 u
U (409.013 nm)-0.037055 u ppm 0.003720 10.04 -106.774000 -0.037055 u
V (292.401 nm)0.725408 ppm 0.003611 0.50 30335.200000 0.725408
Zn (206.200 nm)12.146600 o ppm 0.062809 0.52 26196.600000 12.146600 o
Zr (343.823 nm)0.034133 ppm 0.000068 0.20 2821.600000 0.034133
Test Report
52A112023.esws
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Page 907 of 1261
Solution Name: 160-51789-B-3-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-3-C 11/20/2023 1:42:51 PM 1:9 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.009675 ppm 0.000027 0.28 27905.442839 0.009675
Ag (328.068 nm)0.002818 ppm 0.000163 5.78 -192.032000 0.002818
Al (394.401 nm)10.166500 o ppm 0.034299 0.34 125534.000000 10.166500 o
Al H (396.152 nm)9.162620 ppm 0.001407 0.02 41229.300000 9.162620
As (188.980 nm)0.020987 ppm 0.003264 15.55 13.648900 0.020987
B (249.678 nm)0.072359 ppm 0.001018 1.41 621.802000 0.072359
Ba (493.408 nm)1.402010 ppm 0.004124 0.29 212460.000000 1.402010
Be (234.861 nm)0.000928 ppm 0.000024 2.59 749.481000 0.000928
Bi (223.061 nm)-0.000460 u ppm 0.000709 > 100.00 3.400950 -0.000460 u
Ca (315.887 nm)171.328098 o ppm 0.213008 0.12 115522.927770 171.328098 o
Cd (214.439 nm)0.045310 ppm 0.000181 0.40 686.107000 0.045310
Co (228.615 nm)0.156187 ppm 0.000529 0.34 3036.790000 0.156187
Cr (205.560 nm)0.424667 ppm 0.001702 0.40 1747.850000 0.424667
Cu (324.754 nm)10.199300 o ppm 0.058099 0.57 476580.000000 10.199300 o
Fe (238.204 nm)42.981682 o ppm 0.073920 0.17 169210.661950 42.981682 o
Fe H (259.940 nm)41.999200 ppm 0.072421 0.17 67890.200000 41.999200
K (766.491 nm)4.066690 ppm 0.039848 0.98 6859.010000 4.066690
Li (670.783 nm)0.010347 ppm 0.000733 7.08 -3895.790000 0.010347
Mg (279.078 nm)26.442000 ppm 0.153402 0.58 88421.000000 26.442000
Mn (257.610 nm)6.284910 o ppm 0.028592 0.45 1676950.000000 6.284910 o
Mo (202.032 nm)0.009609 ppm 0.000772 8.04 51.156300 0.009609
Na (589.592 nm)1542.080000 o ppm 13.0123
00 0.84 18761800.000000 1542.080000 o
Na H (589.593 nm)1701.280266 ppm 17.9917
12 1.06 14997164.994032 1701.280266
Ni (231.604 nm)0.830451 ppm 0.003487 0.42 2817.560000 0.830451
P (213.618 nm)0.930868 ppm 0.005240 0.56 567.628000 0.930868
Pb (220.353 nm)2.613340 ppm 0.013633 0.52 6003.300000 2.613340
S (181.972 nm)5.032195 ppm 0.032022 0.64 1060.411170 5.032195
Sb (206.834 nm)0.283531 ppm 0.002115 0.75 352.135000 0.283531
Se (196.026 nm)0.010288 ppm 0.005916 57.50 10.983800 0.010288
Si (288.158 nm)19.496100 o ppm 0.119550 0.61 142450.000000 19.496100 o
Sn (189.925 nm)0.035184 ppm 0.002151 6.11 25.924000 0.035184
Sr (421.552 nm)0.858771 ppm 0.002790 0.32 189625.799808 0.858771
Th (288.505 nm)0.128512 ppm 0.006095 4.74 608.247000 0.128512
Ti (336.122 nm)0.391996 ppm 0.001654 0.42 43031.000000 0.391996
Tl (190.794 nm)-0.000710 u ppm 0.003622 > 100.00 -4.403190 -0.000710 u
U (409.013 nm)-0.038375 u ppm 0.003368 8.78 -103.615000 -0.038375 u
V (292.401 nm)0.408342 ppm 0.001747 0.43 16984.500000 0.408342
Zn (206.200 nm)14.001900 o ppm 0.090994 0.65 30197.300000 14.001900 o
Zr (343.823 nm)0.031532 ppm 0.000155 0.49 2621.070000 0.031532
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 37 of 287
Page 908 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 1:47:48 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000356 u ppm 0.000023 6.37 37.483224 -0.000356 u
Ag (328.068 nm)-0.000738 u ppm 0.000257 34.86 73.836700 -0.000738 u
Al (394.401 nm)52.586900 o ppm 0.143507 0.27 646488.000000 52.586900 o
Al H (396.152 nm)49.754800 ppm 0.235531 0.47 223659.000000 49.754800
As (188.980 nm)0.000703 u ppm 0.004312 > 100.00 -3.272720 0.000703 u
B (249.678 nm)-0.002970 u ppm 0.000446 15.02 -8.673800 -0.002970 u
Ba (493.408 nm)0.000158 ppm 0.000078 49.04 165.877000 0.000158
Be (234.861 nm)0.000046 u ppm 0.000049 > 100.00 701.288000 0.000046 u
Bi (223.061 nm)-0.000785 u ppm 0.000471 59.92 2.917640 -0.000785 u
Ca (315.887 nm)-0.020959 u ppm 0.005360 25.58 -38.147852 -0.020959 u
Cd (214.439 nm)-0.000166 u ppm 0.000074 44.38 7.963280 -0.000166 u
Co (228.615 nm)0.000418 ppm 0.000180 43.12 50.831600 0.000418
Cr (205.560 nm)0.001042 ppm 0.000456 43.76 5.813150 0.001042
Cu (324.754 nm)-0.001282 u ppm 0.000393 30.66 1653.180000 -0.001282 u
Fe (238.204 nm)50.666530 o ppm 0.283809 0.56 199460.773229 50.666530 o
Fe H (259.940 nm)49.247300 ppm 0.201802 0.41 79630.500000 49.247300
K (766.491 nm)0.041425 u ppm 0.055409 > 100.00 -372.987000 0.041425 u
Li (670.783 nm)-0.002176 u ppm 0.001656 76.12 -4361.510000 -0.002176 u
Mg (279.078 nm)-0.001568 u ppm 0.001784 > 100.00 -187.167000 -0.001568 u
Mn (257.610 nm)-0.000714 u ppm 0.000141 19.73 -186.029000 -0.000714 u
Mo (202.032 nm)-0.000377 u ppm 0.000052 13.93 1.609200 -0.000377 u
Na (589.592 nm)253.130000 o ppm 1.876990 0.74 3077880.000000 253.130000 o
Na H (589.593 nm)245.558879 ppm 2.242297 0.91 2241341.638996 245.558879
Ni (231.604 nm)-0.000429 u ppm 0.000690 > 100.00 -11.671300 -0.000429 u
P (213.618 nm)5.105030 ppm 0.015294 0.30 6029.090000 5.105030
Pb (220.353 nm)0.001475 ppm 0.000560 37.98 0.197198 0.001475
S (181.972 nm)4.910062 ppm 0.016597 0.34 1025.918072 4.910062
Sb (206.834 nm)-0.000334 u ppm 0.005231 > 100.00 5.106080 -0.000334 u
Se (196.026 nm)0.004902 ppm 0.003192 65.13 2.704230 0.004902
Si (288.158 nm)0.029276 ppm 0.002001 6.83 923.932000 0.029276
Sn (189.925 nm)-0.001918 u ppm 0.000099 5.18 0.991737 -0.001918 u
Sr (421.552 nm)0.000516 ppm 0.000068 13.10 123.587011 0.000516
Th (288.505 nm)4.973450 ppm 0.020355 0.41 9554.490000 4.973450
Ti (336.122 nm)0.000796 ppm 0.000044 5.59 -31.190800 0.000796
Tl (190.794 nm)-0.003761 u ppm 0.001787 47.52 -7.482450 -0.003761 u
U (409.013 nm)2.521860 Q ppm 0.011765 0.47 11258.600000 Q 2.521860 Q
V (292.401 nm)-0.000131 u ppm 0.000113 85.95 237.372000 -0.000131 u
Zn (206.200 nm)0.001463 ppm 0.000569 38.88 7.317900 0.001463
Zr (343.823 nm)-0.001069 u ppm 0.000111 10.42 -26.169100 -0.001069 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 38 of 287
Page 909 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 1:52:25 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.472778 ppm 0.000228 0.05 1212297.165827 0.472778
Ag (328.068 nm)0.511023 ppm 0.000972 0.19 27290.700000 0.511023
Al (394.401 nm)0.507139 ppm 0.000854 0.17 6689.580000 0.507139
Al H (396.152 nm)0.514826 u ppm 0.005282 1.03 2364.300000 0.514826 u
As (188.980 nm)0.524922 ppm 0.001515 0.29 432.718000 0.524922
B (249.678 nm)0.505869 ppm 0.000655 0.13 4250.130000 0.505869
Ba (493.408 nm)0.512931 ppm 0.001118 0.22 77692.100000 0.512931
Be (234.861 nm)0.499681 ppm 0.002470 0.49 83556.400000 0.499681
Bi (223.061 nm)1.017890 ppm 0.001828 0.18 1517.470000 1.017890
Ca (315.887 nm)5.151705 ppm 0.009673 0.19 3450.395471 5.151705
Cd (214.439 nm)0.515894 ppm 0.000622 0.12 7711.600000 0.515894
Co (228.615 nm)0.523935 ppm 0.000420 0.08 10054.300000 0.523935
Cr (205.560 nm)0.519153 ppm 0.001629 0.31 2135.370000 0.519153
Cu (324.754 nm)0.515868 ppm 0.000514 0.10 24829.400000 0.515868
Fe (238.204 nm)2.557543 ppm 0.002225 0.09 10090.555427 2.557543
Fe H (259.940 nm)2.584310 u ppm 0.011577 0.45 4047.150000 2.584310 u
K (766.491 nm)51.625400 ppm 0.176306 0.34 92305.500000 51.625400
Li (670.783 nm)0.506219 ppm 0.002094 0.41 14545.400000 0.506219
Mg (279.078 nm)20.172000 ppm 0.009298 0.05 67476.400000 20.172000
Mn (257.610 nm)0.497925 ppm 0.000239 0.05 132861.000000 0.497925
Mo (202.032 nm)0.515148 ppm 0.000559 0.11 2559.680000 0.515148
Na (589.592 nm)26.019300 ppm 0.093173 0.36 323336.000000 26.019300
Na H (589.593 nm)16.421626 u ppm 0.095175 0.58 239888.845506 16.421626 u
Ni (231.604 nm)0.511706 ppm 0.001680 0.33 1732.590000 0.511706
P (213.618 nm)0.004445 ppm 0.000941 21.16 -33.181500 0.004445
Pb (220.353 nm)0.532421 ppm 0.003308 0.62 1219.850000 0.532421
S (181.972 nm)-0.015227 u ppm 0.002475 16.25 23.506886 -0.015227 u
Sb (206.834 nm)0.509843 ppm 0.001944 0.38 622.858000 0.509843
Se (196.026 nm)0.522135 ppm 0.007845 1.50 325.493000 0.522135
Si (288.158 nm)5.059350 ppm 0.019811 0.39 37719.600000 5.059350
Sn (189.925 nm)0.512119 ppm 0.001639 0.32 346.418000 0.512119
Sr (421.552 nm)0.512997 ppm 0.000919 0.18 113279.120091 0.512997
Th (288.505 nm)0.035504 ppm 0.003311 9.33 314.663000 0.035504
Ti (336.122 nm)0.511420 ppm 0.000417 0.08 55698.800000 0.511420
Tl (190.794 nm)0.519200 ppm 0.000796 0.15 560.136000 0.519200
U (409.013 nm)-0.002374 u ppm 0.001820 76.66 -0.200199 -0.002374 u
V (292.401 nm)0.512019 ppm 0.000324 0.06 21280.800000 0.512019
Zn (206.200 nm)0.517597 ppm 0.001156 0.22 1120.290000 0.517597
Zr (343.823 nm)0.503401 ppm 0.000425 0.08 41032.700000 0.503401
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 39 of 287
Page 910 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 1:56:59 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000118 ppm 0.000011 9.39 -289.214117 0.000118
Ag (328.068 nm)-0.000063 u ppm 0.000071 > 100.00 -32.335500 -0.000063 u
Al (394.401 nm)0.000769 ppm 0.000848 > 100.00 460.455000 0.000769
Al H (396.152 nm)0.000758 u ppm 0.004076 > 100.00 53.971900 0.000758 u
As (188.980 nm)0.001135 u ppm 0.002382 > 100.00 -2.461650 0.001135 u
B (249.678 nm)0.000359 ppm 0.000264 73.72 19.183400 0.000359
Ba (493.408 nm)0.000092 u ppm 0.000085 92.46 13.264700 0.000092 u
Be (234.861 nm)0.000015 u ppm 0.000022 > 100.00 42.426900 0.000015 u
Bi (223.061 nm)0.002005 u ppm 0.002946 > 100.00 7.065850 0.002005 u
Ca (315.887 nm)-0.000838 u ppm 0.010311 > 100.00 -24.577414 -0.000838 u
Cd (214.439 nm)0.000012 u ppm 0.000160 > 100.00 0.254770 0.000012 u
Co (228.615 nm)0.000070 u ppm 0.000328 > 100.00 44.182300 0.000070 u
Cr (205.560 nm)-0.000081 u ppm 0.000684 > 100.00 1.192850 -0.000081 u
Cu (324.754 nm)0.000521 ppm 0.000245 46.98 789.692000 0.000521
Fe (238.204 nm)-0.000077 u ppm 0.000564 > 100.00 16.300135 -0.000077 u
Fe H (259.940 nm)0.093401 u ppm 0.000338 0.36 12.461700 0.093401 u
K (766.491 nm)0.002033 u ppm 0.013945 > 100.00 -443.761000 0.002033 u
Li (670.783 nm)-0.006216 Su ppm 0.002044 32.88 -4511.770000 S -0.006216 Su
Mg (279.078 nm)-0.000507 u ppm 0.001787 > 100.00 7.300280 -0.000507 u
Mn (257.610 nm)-0.000019 u ppm 0.000010 52.81 -0.687398 -0.000019 u
Mo (202.032 nm)0.000234 u ppm 0.000384 > 100.00 4.638020 0.000234 u
Na (589.592 nm)0.425291 Z ppm 0.011937 2.81 6207.190000 Z 0.425291 Z
Na H (589.593 nm)-9.619428 u ppm 0.008594 0.09 7465.943281 -9.619428 u
Ni (231.604 nm)-0.000406 u ppm 0.000811 > 100.00 -11.593000 -0.000406 u
P (213.618 nm)0.002019 u ppm 0.002903 > 100.00 5.470980 0.002019 u
Pb (220.353 nm)0.000422 u ppm 0.000690 > 100.00 -0.657989 0.000422 u
S (181.972 nm)-0.024150 u ppm 0.006418 26.58 19.150218 -0.024150 u
Sb (206.834 nm)-0.001717 u ppm 0.002669 > 100.00 -0.087292 -0.001717 u
Se (196.026 nm)0.003026 ppm 0.001993 65.87 6.872380 0.003026
Si (288.158 nm)-0.000200 u ppm 0.001333 > 100.00 709.938000 -0.000200 u
Sn (189.925 nm)-0.001547 u ppm 0.000339 21.93 1.241020 -0.001547 u
Sr (421.552 nm)-0.000008 u ppm 0.000033 > 100.00 7.982977 -0.000008 u
Th (288.505 nm)0.007232 ppm 0.000537 7.42 274.046000 0.007232
Ti (336.122 nm)0.000070 ppm 0.000054 77.07 -110.435000 0.000070
Tl (190.794 nm)0.001768 ppm 0.001984 > 100.00 -0.568201 0.001768
U (409.013 nm)-0.001055 u ppm 0.004246 > 100.00 18.786300 -0.001055 u
V (292.401 nm)-0.000051 u ppm 0.000149 > 100.00 -41.457600 -0.000051 u
Zn (206.200 nm)-0.001398 u ppm 0.000637 45.54 1.148060 -0.001398 u
Zr (343.823 nm)0.000124 u ppm 0.000145 > 100.00 2.463510 0.000124 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 40 of 287
Page 911 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 2:01:01 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014827 ppm 0.000006 0.04 37526.907225 0.014827
Ag (328.068 nm)0.009910 ppm 0.000095 0.96 499.373000 0.009910
Al (394.401 nm)0.093233 ppm 0.000566 0.61 1601.090000 0.093233
Al H (396.152 nm)0.099424 u ppm 0.002225 2.24 497.397000 0.099424 u
As (188.980 nm)0.015890 ppm 0.001422 8.95 9.797630 0.015890
B (249.678 nm)0.098978 ppm 0.000382 0.39 844.590000 0.098978
Ba (493.408 nm)0.010261 ppm 0.000192 1.87 1553.770000 0.010261
Be (234.861 nm)0.000993 ppm 0.000030 3.07 207.178000 0.000993
Bi (223.061 nm)-0.002604 Qu ppm 0.001159 44.49 0.213191 Q -0.002604 Qu
Ca (315.887 nm)0.213653 ppm 0.003334 1.56 120.079052 0.213653
Cd (214.439 nm)0.005385 ppm 0.000059 1.09 80.589000 0.005385
Co (228.615 nm)0.010471 ppm 0.000115 1.10 242.899000 0.010471
Cr (205.560 nm)0.009918 ppm 0.000383 3.86 42.222500 0.009918
Cu (324.754 nm)0.015439 ppm 0.000199 1.29 1484.800000 0.015439
Fe (238.204 nm)0.104182 ppm 0.000446 0.43 426.772326 0.104182
Fe H (259.940 nm)0.195358 u ppm 0.002027 1.04 177.609000 0.195358 u
K (766.491 nm)3.164630 ppm 0.030131 0.95 5238.320000 3.164630
Li (670.783 nm)0.017468 ppm 0.001406 8.05 -3630.990000 0.017468
Mg (279.078 nm)0.204247 ppm 0.000939 0.46 690.797000 0.204247
Mn (257.610 nm)0.010396 ppm 0.000035 0.34 2778.320000 0.010396
Mo (202.032 nm)0.020488 ppm 0.000511 2.49 105.141000 0.020488
Na (589.592 nm)1.455110 Q ppm 0.003764 0.26 18846.600000 Q 1.455110 Q
Na H (589.593 nm)-8.670732 u ppm 0.022145 0.26 15860.964582 -8.670732 u
Ni (231.604 nm)0.041824 ppm 0.000937 2.24 132.214000 0.041824
P (213.618 nm)2.912010 ppm 0.004374 0.15 3439.640000 2.912010
Pb (220.353 nm)0.009040 ppm 0.000969 10.71 19.180600 0.009040
S (181.972 nm)0.062130 Q ppm 0.003621 5.83 36.787085 Q 0.062130 Q
Sb (206.834 nm)0.021920 ppm 0.000487 2.22 28.632900 0.021920
Se (196.026 nm)0.017413 ppm 0.005972 34.29 15.697000 0.017413
Si (288.158 nm)0.476389 ppm 0.003567 0.75 4204.100000 0.476389
Sn (189.925 nm)0.101843 ppm 0.001817 1.78 70.718100 0.101843
Sr (421.552 nm)0.010128 ppm 0.000116 1.14 2245.847313 0.010128
Th (288.505 nm)0.004996 Q ppm 0.003004 60.13 269.969000 Q 0.004996 Q
Ti (336.122 nm)0.009993 ppm 0.000081 0.81 972.739000 0.009993
Tl (190.794 nm)0.016014 ppm 0.002113 13.20 14.853400 0.016014
U (409.013 nm)0.059249 ppm 0.001891 3.19 284.443000 0.059249
V (292.401 nm)0.009916 ppm 0.000207 2.09 370.957000 0.009916
Zn (206.200 nm)0.020642 ppm 0.000629 3.04 48.673600 0.020642
Zr (343.823 nm)0.010248 ppm 0.000107 1.05 827.925000 0.010248
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 41 of 287
Page 912 of 1261
Solution Name: 160-51790-B-1-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51790-B-1-C 11/20/2023 2:05:24 PM 1:10 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010405 ppm 0.000025 0.24 29170.325147 0.010405
Ag (328.068 nm)0.004800 ppm 0.000147 3.07 -618.912000 0.004800
Al (394.401 nm)12.228700 o ppm 0.028216 0.23 150911.000000 12.228700 o
Al H (396.152 nm)10.954400 ppm 0.039477 0.36 49281.800000 10.954400
As (188.980 nm)0.023859 ppm 0.002858 11.98 15.832000 0.023859
B (249.678 nm)0.058301 ppm 0.000349 0.60 504.136000 0.058301
Ba (493.408 nm)1.432430 ppm 0.001262 0.09 217132.000000 1.432430
Be (234.861 nm)0.001149 ppm 0.000016 1.37 1080.100000 0.001149
Bi (223.061 nm)-0.001120 u ppm 0.001277 > 100.00 2.419390 -0.001120 u
Ca (315.887 nm)145.702063 o ppm 0.389799 0.27 98240.240262 145.702063 o
Cd (214.439 nm)0.013814 ppm 0.000068 0.49 219.995000 0.013814
Co (228.615 nm)0.124324 ppm 0.000545 0.44 2437.440000 0.124324
Cr (205.560 nm)0.275604 ppm 0.002436 0.88 1134.750000 0.275604
Cu (324.754 nm)4.529390 o ppm 0.018128 0.40 212087.000000 4.529390 o
Fe (238.204 nm)65.745293 o ppm 0.211051 0.32 258817.146088 65.745293 o
Fe H (259.940 nm)64.211900 ppm 0.170002 0.26 103870.000000 64.211900
K (766.491 nm)3.083270 ppm 0.025109 0.81 5092.160000 3.083270
Li (670.783 nm)0.010677 ppm 0.001845 17.28 -3883.520000 0.010677
Mg (279.078 nm)23.075300 ppm 0.067730 0.29 77145.400000 23.075300
Mn (257.610 nm)4.668510 o ppm 0.013517 0.29 1245660.000000 4.668510 o
Mo (202.032 nm)0.011408 ppm 0.000363 3.18 60.084300 0.011408
Na (589.592 nm)1349.120000 o ppm 5.799280 0.43 16416700.000000 1349.120000 o
Na H (589.593 nm)1460.902984 ppm 18.7903
15 1.29 12893125.735544 1460.902984
Ni (231.604 nm)0.635832 ppm 0.002285 0.36 2154.860000 0.635832
P (213.618 nm)1.238530 ppm 0.009125 0.74 1227.950000 1.238530
Pb (220.353 nm)2.338620 ppm 0.006977 0.30 5371.500000 2.338620
S (181.972 nm)1.717475 ppm 0.017410 1.01 384.039765 1.717475
Sb (206.834 nm)0.315262 ppm 0.002097 0.67 390.664000 0.315262
Se (196.026 nm)0.000509 u ppm 0.003221 > 100.00 1.519670 0.000509 u
Si (288.158 nm)23.807500 o ppm 0.694313 2.92 173816.000000 23.807500 o
Sn (189.925 nm)0.034034 ppm 0.001807 5.31 25.151600 0.034034
Sr (421.552 nm)0.707817 ppm 0.000600 0.08 156295.322104 0.707817
Th (288.505 nm)0.123639 ppm 0.001276 1.03 535.207000 0.123639
Ti (336.122 nm)0.596410 ppm 0.001718 0.29 65280.400000 0.596410
Tl (190.794 nm)-0.001090 u ppm 0.002096 > 100.00 -5.633110 -0.001090 u
U (409.013 nm)-0.035018 u ppm 0.000860 2.46 -66.612100 -0.035018 u
V (292.401 nm)1.071510 ppm 0.002699 0.25 44863.100000 1.071510
Zn (206.200 nm)8.561520 o ppm 0.021528 0.25 18465.900000 8.561520 o
Zr (343.823 nm)0.033933 ppm 0.000102 0.30 2847.610000 0.033933
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 42 of 287
Page 913 of 1261
Solution Name: 160-51790-B-2-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51790-B-2-C 11/20/2023 2:09:45 PM 1:11 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.013951 ppm 0.000050 0.36 38911.340803 0.013951
Ag (328.068 nm)0.005812 ppm 0.000108 1.86 -799.010000 0.005812
Al (394.401 nm)14.870400 o ppm 0.035818 0.24 183424.000000 14.870400 o
Al H (396.152 nm)13.343000 ppm 0.060241 0.45 60016.900000 13.343000
As (188.980 nm)0.032236 ppm 0.003027 9.39 22.668600 0.032236
B (249.678 nm)0.083541 ppm 0.001030 1.23 715.394000 0.083541
Ba (493.408 nm)1.721850 ppm 0.007617 0.44 261005.000000 1.721850
Be (234.861 nm)0.001346 ppm 0.000067 5.01 1291.210000 0.001346
Bi (223.061 nm)-0.002110 u ppm 0.000839 39.77 0.948420 -0.002110 u
Ca (315.887 nm)171.953500 o ppm 0.851568 0.50 115944.710789 171.953500 o
Cd (214.439 nm)0.015457 ppm 0.000139 0.90 247.384000 0.015457
Co (228.615 nm)0.161867 ppm 0.000326 0.20 3159.640000 0.161867
Cr (205.560 nm)0.336156 ppm 0.000932 0.28 1383.770000 0.336156
Cu (324.754 nm)5.989020 o ppm 0.035066 0.59 280181.000000 5.989020 o
Fe (238.204 nm)79.573983 o ppm 0.392035 0.49 313252.549357 79.573983 o
Fe H (259.940 nm)77.624300 ppm 0.373984 0.48 125595.000000 77.624300
K (766.491 nm)3.734320 ppm 0.039023 1.04 6261.870000 3.734320
Li (670.783 nm)0.015575 ppm 0.002108 13.53 -3701.360000 0.015575
Mg (279.078 nm)24.787300 ppm 0.071406 0.29 82863.600000 24.787300
Mn (257.610 nm)5.484600 o ppm 0.014481 0.26 1463410.000000 5.484600 o
Mo (202.032 nm)0.018667 ppm 0.000444 2.38 96.107400 0.018667
Na (589.592 nm)1531.450000 o ppm 6.839210 0.45 18636300.000000 1531.450000 o
Na H (589.593 nm)1675.977848 ppm 18.4154
68 1.10 14778449.542113 1675.977848
Ni (231.604 nm)0.726094 ppm 0.001658 0.23 2462.210000 0.726094
P (213.618 nm)1.436770 ppm 0.004371 0.30 1385.310000 1.436770
Pb (220.353 nm)2.954500 ppm 0.001961 0.07 6786.570000 2.954500
S (181.972 nm)1.942886 ppm 0.018332 0.94 431.849670 1.942886
Sb (206.834 nm)0.413074 ppm 0.002124 0.51 510.690000 0.413074
Se (196.026 nm)0.007830 ppm 0.006193 79.09 5.104160 0.007830
Si (288.158 nm)34.983600 o ppm 0.179369 0.51 255060.000000 34.983600 o
Sn (189.925 nm)0.078307 ppm 0.001872 2.39 54.901900 0.078307
Sr (421.552 nm)0.827370 ppm 0.003221 0.39 182692.518881 0.827370
Th (288.505 nm)0.137474 ppm 0.002405 1.75 563.828000 0.137474
Ti (336.122 nm)0.753621 ppm 0.001591 0.21 82492.600000 0.753621
Tl (190.794 nm)-0.000254 u ppm 0.002927 > 100.00 -5.182030 -0.000254 u
U (409.013 nm)-0.046451 u ppm 0.002724 5.86 -104.061000 -0.046451 u
V (292.401 nm)1.363840 o ppm 0.003427 0.25 57113.500000 1.363840 o
Zn (206.200 nm)11.542400 o ppm 0.034582 0.30 24893.800000 11.542400 o
Zr (343.823 nm)0.039831 ppm 0.000027 0.07 3347.120000 0.039831
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 43 of 287
Page 914 of 1261
Solution Name: 160-51875-A-1-H
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51875-A-1-H 11/20/2023 2:14:17 PM 1:12 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.025175 ppm 0.000110 0.44 70782.064572 0.025175
Ag (328.068 nm)0.004497 ppm 0.000507 11.27 -477.505000 0.004497
Al (394.401 nm)18.982400 o ppm 0.073018 0.38 234025.000000 18.982400 o
Al H (396.152 nm)17.067000 ppm 0.007192 0.04 76753.200000 17.067000
As (188.980 nm)0.045553 ppm 0.004289 9.42 33.738700 0.045553
B (249.678 nm)0.234583 ppm 0.000103 0.04 1979.560000 0.234583
Ba (493.408 nm)1.109130 ppm 0.000873 0.08 168204.000000 1.109130
Be (234.861 nm)0.000542 ppm 0.000032 5.84 1149.700000 0.000542
Bi (223.061 nm)0.004360 ppm 0.001108 25.43 10.566900 0.004360
Ca (315.887 nm)160.978076 o ppm 0.149134 0.09 108542.675203 160.978076 o
Cd (214.439 nm)0.084570 ppm 0.000817 0.97 1280.300000 0.084570
Co (228.615 nm)0.128128 ppm 0.000393 0.31 2502.950000 0.128128
Cr (205.560 nm)0.971274 ppm 0.003823 0.39 3995.740000 0.971274
Cu (324.754 nm)43.345300 o ppm 0.245109 0.57 2023070.000000 43.345300 o
Fe (238.204 nm)78.993934 o ppm 0.082392 0.10 310970.108479 78.993934 o
Fe H (259.940 nm)77.064500 ppm 0.042006 0.05 124688.000000 77.064500
K (766.491 nm)5.357340 ppm 0.047380 0.88 9177.860000 5.357340
Li (670.783 nm)0.022078 ppm 0.000223 1.01 -3459.540000 0.022078
Mg (279.078 nm)30.533500 ppm 0.156074 0.51 102083.000000 30.533500
Mn (257.610 nm)5.581110 o ppm 0.031276 0.56 1489160.000000 5.581110 o
Mo (202.032 nm)0.027412 ppm 0.000830 3.03 139.498000 0.027412
Na (589.592 nm)1616.490000 o ppm 5.774170 0.36 19662800.000000 1616.490000 o
Na H (589.593 nm)1766.279902 ppm 2.202340 0.12 15563639.601744 1766.279902
Ni (231.604 nm)1.760610 o ppm 0.011187 0.64 5984.850000 1.760610 o
P (213.618 nm)2.520250 ppm 0.019903 0.79 706.341000 2.520250
Pb (220.353 nm)17.100300 ppm 0.042695 0.25 39300.200000 17.100300
S (181.972 nm)16.232800 o ppm 0.121562 0.75 3341.838483 16.232800 o
Sb (206.834 nm)1.886740 o ppm 0.010442 0.55 2312.200000 1.886740 o
Se (196.026 nm)0.005781 ppm 0.006111 > 100.00 3.968850 0.005781
Si (288.158 nm)29.543100 o ppm 0.195072 0.66 215492.000000 29.543100 o
Sn (189.925 nm)0.170132 ppm 0.003901 2.29 116.607000 0.170132
Sr (421.552 nm)0.759502 ppm 0.000469 0.06 167707.333995 0.759502
Th (288.505 nm)0.133273 ppm 0.001279 0.96 583.643000 0.133273
Ti (336.122 nm)0.422598 ppm 0.002139 0.51 46347.600000 0.422598
Tl (190.794 nm)-0.000469 u ppm 0.002014 > 100.00 -4.938910 -0.000469 u
U (409.013 nm)-0.029680 u ppm 0.006572 22.14 -30.512200 -0.029680 u
V (292.401 nm)0.874665 ppm 0.004270 0.49 36387.200000 0.874665
Zn (206.200 nm)45.781500 o ppm 0.264307 0.58 98725.800000 45.781500 o
Zr (343.823 nm)0.033282 ppm 0.000118 0.36 2812.470000 0.033282
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 44 of 287
Page 915 of 1261
Solution Name: 160-51876-C-1-I
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51876-C-1-I 11/20/2023 2:18:53 PM 1:13 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.024369 ppm 0.000050 0.20 68609.049216 0.024369
Ag (328.068 nm)0.006781 ppm 0.000065 0.96 -497.410000 0.006781
Al (394.401 nm)19.257200 o ppm 0.040997 0.21 237406.000000 19.257200 o
Al H (396.152 nm)17.262400 ppm 0.009669 0.06 77631.400000 17.262400
As (188.980 nm)0.058569 ppm 0.004131 7.05 44.066500 0.058569
B (249.678 nm)0.151882 ppm 0.000387 0.25 1287.390000 0.151882
Ba (493.408 nm)1.525770 ppm 0.002649 0.17 231459.000000 1.525770
Be (234.861 nm)0.000395 ppm 0.000034 8.73 1827.620000 0.000395
Bi (223.061 nm)0.002256 ppm 0.002946 > 100.00 7.438590 0.002256
Ca (315.887 nm)190.011750 o ppm 0.235167 0.12 128123.538829 190.011750 o
Cd (214.439 nm)0.078838 ppm 0.000404 0.51 1205.760000 0.078838
Co (228.615 nm)0.133216 ppm 0.000086 0.06 2602.840000 0.133216
Cr (205.560 nm)0.975425 ppm 0.002368 0.24 4012.860000 0.975425
Cu (324.754 nm)34.432000 o ppm 0.060983 0.18 1607260.000000 34.432000 o
Fe (238.204 nm)133.449897 o ppm 0.341824 0.26 525330.967904 133.449897 o
Fe H (259.940 nm)131.024000 ppm 0.147889 0.11 212090.000000 131.024000
K (766.491 nm)4.407680 ppm 0.045017 1.02 7471.650000 4.407680
Li (670.783 nm)0.023255 ppm 0.000359 1.54 -3415.750000 0.023255
Mg (279.078 nm)24.687900 ppm 0.067499 0.27 82496.000000 24.687900
Mn (257.610 nm)5.659740 o ppm 0.013968 0.25 1510140.000000 5.659740 o
Mo (202.032 nm)0.039892 ppm 0.000844 2.12 201.424000 0.039892
Na (589.592 nm)1526.110000 o ppm 3.878330 0.25 18569200.000000 1526.110000 o
Na H (589.593 nm)1649.038470 ppm 5.448067 0.33 14540918.800392 1649.038470
Ni (231.604 nm)1.686180 o ppm 0.005125 0.30 5731.420000 1.686180 o
P (213.618 nm)2.747440 ppm 0.006037 0.22 1441.650000 2.747440
Pb (220.353 nm)25.166600 ppm 0.047257 0.19 57840.100000 25.166600
S (181.972 nm)6.121838 ppm 0.033108 0.54 1285.469662 6.121838
Sb (206.834 nm)2.115550 o ppm 0.005301 0.25 2594.560000 2.115550 o
Se (196.026 nm)0.000648 u ppm 0.002004 > 100.00 -4.846700 0.000648 u
Si (288.158 nm)28.385200 o ppm 0.128915 0.45 207096.000000 28.385200 o
Sn (189.925 nm)0.178670 ppm 0.002590 1.45 122.345000 0.178670
Sr (421.552 nm)0.953448 ppm 0.002473 0.26 210530.434414 0.953448
Th (288.505 nm)0.135268 ppm 0.001886 1.39 579.435000 0.135268
Ti (336.122 nm)0.494604 ppm 0.000917 0.19 54268.300000 0.494604
Tl (190.794 nm)-0.000461 u ppm 0.001717 > 100.00 -6.053640 -0.000461 u
U (409.013 nm)-0.031801 u ppm 0.001348 4.24 13.327800 -0.031801 u
V (292.401 nm)1.055180 ppm 0.002024 0.19 43962.900000 1.055180
Zn (206.200 nm)43.886000 o ppm 0.173220 0.39 94638.300000 43.886000 o
Zr (343.823 nm)0.038339 ppm 0.000039 0.10 3298.480000 0.038339
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 45 of 287
Page 916 of 1261
Solution Name: 160-51885-A-1-H
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51885-A-1-H 11/20/2023 2:23:22 PM 1:14 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.012373 ppm 0.000020 0.16 34535.355595 0.012373
Ag (328.068 nm)0.002671 ppm 0.000183 6.85 -184.760000 0.002671
Al (394.401 nm)10.651000 o ppm 0.021610 0.20 131506.000000 10.651000 o
Al H (396.152 nm)9.585550 ppm 0.037295 0.39 43130.000000 9.585550
As (188.980 nm)0.027632 ppm 0.002832 10.25 19.178500 0.027632
B (249.678 nm)0.095330 ppm 0.001177 1.23 814.057000 0.095330
Ba (493.408 nm)1.207300 ppm 0.003300 0.27 182968.000000 1.207300
Be (234.861 nm)0.000990 ppm 0.000049 4.94 747.540000 0.000990
Bi (223.061 nm)-0.004323 u ppm 0.001823 42.17 -2.342270 -0.004323 u
Ca (315.887 nm)158.053194 o ppm 0.603521 0.38 106570.079098 158.053194 o
Cd (214.439 nm)0.020870 ppm 0.000287 1.38 320.611000 0.020870
Co (228.615 nm)0.131211 ppm 0.000867 0.66 2559.400000 0.131211
Cr (205.560 nm)0.328573 ppm 0.001375 0.42 1352.560000 0.328573
Cu (324.754 nm)6.007340 o ppm 0.026417 0.44 281000.000000 6.007340 o
Fe (238.204 nm)42.031550 o ppm 0.157726 0.38 165470.231596 42.031550 o
Fe H (259.940 nm)41.023200 ppm 0.151870 0.37 66309.200000 41.023200
K (766.491 nm)3.786250 ppm 0.055750 1.47 6355.160000 3.786250
Li (670.783 nm)0.011989 ppm 0.000906 7.56 -3834.750000 0.011989
Mg (279.078 nm)28.127600 ppm 0.064322 0.23 94059.900000 28.127600
Mn (257.610 nm)5.045090 o ppm 0.017111 0.34 1346140.000000 5.045090 o
Mo (202.032 nm)0.011252 ppm 0.000312 2.77 59.312500 0.011252
Na (589.592 nm)1496.710000 o ppm 5.990810 0.40 18207900.000000 1496.710000 o
Na H (589.593 nm)1674.182224 ppm 75.4124
64 4.50 14758249.927417 1674.182224
Ni (231.604 nm)0.753303 ppm 0.002897 0.38 2554.860000 0.753303
P (213.618 nm)1.137950 ppm 0.011933 1.05 1031.630000 1.137950
Pb (220.353 nm)4.941480 ppm 0.017172 0.35 11354.500000 4.941480
S (181.972 nm)7.323630 ppm 0.025041 0.34 1525.476192 7.323630
Sb (206.834 nm)0.333578 ppm 0.005106 1.53 412.479000 0.333578
Se (196.026 nm)0.004985 u ppm 0.005567 > 100.00 7.006750 0.004985 u
Si (288.158 nm)19.274900 o ppm 0.088651 0.46 140849.000000 19.274900 o
Sn (189.925 nm)0.074980 ppm 0.002201 2.94 52.666100 0.074980
Sr (421.552 nm)0.789646 ppm 0.001919 0.24 174363.096701 0.789646
Th (288.505 nm)0.119510 ppm 0.003881 3.25 567.628000 0.119510
Ti (336.122 nm)0.364037 ppm 0.000816 0.22 39951.100000 0.364037
Tl (190.794 nm)-0.001180 u ppm 0.003633 > 100.00 -4.901980 -0.001180 u
U (409.013 nm)-0.032345 u ppm 0.005624 17.39 -78.438700 -0.032345 u
V (292.401 nm)0.387451 ppm 0.000780 0.20 16132.600000 0.387451
Zn (206.200 nm)11.728900 o ppm 0.028425 0.24 25295.900000 11.728900 o
Zr (343.823 nm)0.030638 ppm 0.000120 0.39 2546.850000 0.030638
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 46 of 287
Page 917 of 1261
Solution Name: 160-51885-B-2-H
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51885-B-2-H 11/20/2023 2:27:54 PM 1:15 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.012008 ppm 0.000058 0.49 33601.216499 0.012008
Ag (328.068 nm)0.002506 ppm 0.000269 10.72 -181.986000 0.002506
Al (394.401 nm)10.917800 o ppm 0.055853 0.51 134786.000000 10.917800 o
Al H (396.152 nm)9.850760 ppm 0.024638 0.25 44321.900000 9.850760
As (188.980 nm)0.027617 ppm 0.002815 10.19 19.197500 0.027617
B (249.678 nm)0.092674 ppm 0.000468 0.51 791.829000 0.092674
Ba (493.408 nm)1.501870 ppm 0.000922 0.06 227572.000000 1.501870
Be (234.861 nm)0.001110 ppm 0.000017 1.49 722.726000 0.001110
Bi (223.061 nm)-0.001377 u ppm 0.001833 > 100.00 2.038200 -0.001377 u
Ca (315.887 nm)182.041586 o ppm 0.591478 0.32 122748.308126 182.041586 o
Cd (214.439 nm)0.018235 ppm 0.000509 2.79 280.516000 0.018235
Co (228.615 nm)0.123858 ppm 0.000489 0.39 2419.140000 0.123858
Cr (205.560 nm)0.289871 ppm 0.003582 1.24 1193.440000 0.289871
Cu (324.754 nm)5.494230 o ppm 0.020278 0.37 257044.000000 5.494230 o
Fe (238.204 nm)38.559909 o ppm 0.133256 0.35 151804.419610 38.559909 o
Fe H (259.940 nm)37.614400 ppm 0.123563 0.33 60787.900000 37.614400
K (766.491 nm)4.177020 ppm 0.039741 0.95 7057.240000 4.177020
Li (670.783 nm)0.013566 ppm 0.002247 16.56 -3776.090000 0.013566
Mg (279.078 nm)29.786000 ppm 0.192123 0.65 99609.100000 29.786000
Mn (257.610 nm)5.854880 o ppm 0.038806 0.66 1562210.000000 5.854880 o
Mo (202.032 nm)0.010195 ppm 0.000496 4.87 54.064400 0.010195
Na (589.592 nm)1581.310000 o ppm 3.274040 0.21 19239800.000000 1581.310000 o
Na H (589.593 nm)1721.165350 ppm 8.644559 0.50 15172109.620942 1721.165350
Ni (231.604 nm)0.649746 ppm 0.004658 0.72 2202.240000 0.649746
P (213.618 nm)1.147520 ppm 0.022147 1.93 1069.860000 1.147520
Pb (220.353 nm)2.421520 ppm 0.016086 0.66 5562.400000 2.421520
S (181.972 nm)6.874348 ppm 0.035254 0.51 1435.175198 6.874348
Sb (206.834 nm)0.259216 ppm 0.002829 1.09 321.365000 0.259216
Se (196.026 nm)0.013388 ppm 0.002307 17.23 13.065400 0.013388
Si (288.158 nm)20.120200 o ppm 0.068225 0.34 146975.000000 20.120200 o
Sn (189.925 nm)0.020932 ppm 0.002865 13.69 16.347000 0.020932
Sr (421.552 nm)0.975995 ppm 0.000606 0.06 215508.919774 0.975995
Th (288.505 nm)0.127482 ppm 0.002957 2.32 599.415000 0.127482
Ti (336.122 nm)0.363077 ppm 0.001787 0.49 39898.800000 0.363077
Tl (190.794 nm)-0.002013 u ppm 0.002507 > 100.00 -5.752450 -0.002013 u
U (409.013 nm)-0.038386 u ppm 0.001972 5.14 -108.400000 -0.038386 u
V (292.401 nm)0.374220 ppm 0.002178 0.58 15590.100000 0.374220
Zn (206.200 nm)8.600490 o ppm 0.063174 0.73 18549.900000 8.600490 o
Zr (343.823 nm)0.032522 ppm 0.000177 0.55 2695.730000 0.032522
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 47 of 287
Page 918 of 1261
Solution Name: 183314-C-1 DC
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
183314-C-1 DC 11/20/2023 2:33:04 PM 2:90 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002606 ppm 0.000009 0.33 7126.870773 0.002606
Ag (328.068 nm)0.000523 ppm 0.000195 37.21 -0.695869 0.000523
Al (394.401 nm)0.017599 ppm 0.000201 1.14 659.506000 0.017599
Al H (396.152 nm)-0.006168 u ppm 0.005437 88.16 22.846000 -0.006168 u
As (188.980 nm)0.004375 ppm 0.003041 69.53 0.229194 0.004375
B (249.678 nm)0.004282 ppm 0.000796 18.58 52.022400 0.004282
Ba (493.408 nm)0.048793 ppm 0.000195 0.40 7389.680000 0.048793
Be (234.861 nm)0.000110 ppm 0.000045 40.93 59.797400 0.000110
Bi (223.061 nm)0.002664 ppm 0.001109 41.62 8.045170 0.002664
Ca (315.887 nm)42.816358 o ppm 0.138453 0.32 28852.156473 42.816358 o
Cd (214.439 nm)0.000365 ppm 0.000199 54.60 5.560590 0.000365
Co (228.615 nm)-0.000061 u ppm 0.000070 > 100.00 41.681100 -0.000061 u
Cr (205.560 nm)0.000023 u ppm 0.000486 > 100.00 1.607870 0.000023 u
Cu (324.754 nm)0.000614 ppm 0.000224 36.43 775.330000 0.000614
Fe (238.204 nm)0.121487 ppm 0.000395 0.33 494.840695 0.121487
Fe H (259.940 nm)0.210969 u ppm 0.003399 1.61 202.896000 0.210969 u
K (766.491 nm)0.839327 ppm 0.006845 0.82 1060.570000 0.839327
Li (670.783 nm)0.002063 ppm 0.002250 > 100.00 -4203.890000 0.002063
Mg (279.078 nm)33.801300 ppm 0.158305 0.47 113063.000000 33.801300
Mn (257.610 nm)0.012135 ppm 0.000085 0.70 3242.380000 0.012135
Mo (202.032 nm)0.003834 ppm 0.000853 22.25 22.501700 0.003834
Na (589.592 nm)4.008440 ppm 0.037168 0.93 50334.500000 4.008440
Na H (589.593 nm)-5.385797 u ppm 0.068411 1.27 44951.651352 -5.385797 u
Ni (231.604 nm)-0.001787 u ppm 0.000874 48.94 -16.294200 -0.001787 u
P (213.618 nm)0.003456 ppm 0.002685 77.68 7.028340 0.003456
Pb (220.353 nm)-0.000064 u ppm 0.001852 > 100.00 -1.712970 -0.000064 u
S (181.972 nm)36.157256 o ppm 0.192128 0.53 7388.299777 36.157256 o
Sb (206.834 nm)-0.002757 u ppm 0.003613 > 100.00 -1.361650 -0.002757 u
Se (196.026 nm)0.000693 u ppm 0.001712 > 100.00 5.436050 0.000693 u
Si (288.158 nm)2.972020 ppm 0.013237 0.45 22305.400000 2.972020
Sn (189.925 nm)0.000478 ppm 0.000473 98.90 2.601960 0.000478
Sr (421.552 nm)0.310785 ppm 0.001138 0.37 68630.806131 0.310785
Th (288.505 nm)0.032150 ppm 0.000757 2.36 321.564000 0.032150
Ti (336.122 nm)-0.000222 u ppm 0.000058 26.06 -48.649700 -0.000222 u
Tl (190.794 nm)0.001107 u ppm 0.003331 > 100.00 -1.296990 0.001107 u
U (409.013 nm)0.036306 ppm 0.004413 12.15 184.192000 0.036306
V (292.401 nm)0.000611 ppm 0.000097 15.82 -12.253400 0.000611
Zn (206.200 nm)0.206985 ppm 0.001232 0.60 450.498000 0.206985
Zr (343.823 nm)0.000238 ppm 0.000061 25.66 11.949600 0.000238
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 48 of 287
Page 919 of 1261
Solution Name: 160-51886-B-1-H
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51886-B-1-H 11/20/2023 2:37:21 PM 1:16 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.005786 ppm 0.000020 0.34 16837.161575 0.005786
Ag (328.068 nm)0.001652 ppm 0.000371 22.46 -56.383100 0.001652
Al (394.401 nm)7.232440 o ppm 0.031329 0.43 89442.900000 7.232440 o
Al H (396.152 nm)6.504890 ppm 0.032047 0.49 29284.900000 6.504890
As (188.980 nm)0.021126 ppm 0.004417 20.91 13.919300 0.021126
B (249.678 nm)0.048396 ppm 0.000400 0.83 421.236000 0.048396
Ba (493.408 nm)1.190010 ppm 0.003682 0.31 180303.000000 1.190010
Be (234.861 nm)0.001018 ppm 0.000024 2.32 541.294000 0.001018
Bi (223.061 nm)-0.000389 u ppm 0.000565 > 100.00 3.507300 -0.000389 u
Ca (315.887 nm)115.206269 o ppm 0.618372 0.54 77673.294421 115.206269 o
Cd (214.439 nm)0.010281 ppm 0.000037 0.36 159.001000 0.010281
Co (228.615 nm)0.178871 ppm 0.001213 0.68 3465.120000 0.178871
Cr (205.560 nm)0.261446 ppm 0.001010 0.39 1076.320000 0.261446
Cu (324.754 nm)3.632940 o ppm 0.021153 0.58 170225.000000 3.632940 o
Fe (238.204 nm)25.684169 o ppm 0.116478 0.45 101120.138810 25.684169 o
Fe H (259.940 nm)25.087600 ppm 0.129494 0.52 40497.300000 25.087600
K (766.491 nm)3.045410 ppm 0.005172 0.17 5024.130000 3.045410
Li (670.783 nm)0.008756 ppm 0.001416 16.17 -3954.980000 0.008756
Mg (279.078 nm)24.492200 ppm 0.128081 0.52 81911.500000 24.492200
Mn (257.610 nm)4.458930 o ppm 0.022682 0.51 1189740.000000 4.458930 o
Mo (202.032 nm)0.009280 ppm 0.000375 4.04 49.526400 0.009280
Na (589.592 nm)1350.640000 o ppm 4.709810 0.35 16432300.000000 1350.640000 o
Na H (589.593 nm)1443.233412 ppm 14.0927
07 0.98 12736332.854253 1443.233412
Ni (231.604 nm)0.823802 ppm 0.003181 0.39 2794.910000 0.823802
P (213.618 nm)0.965048 ppm 0.003549 0.37 951.932000 0.965048
Pb (220.353 nm)2.076280 ppm 0.009362 0.45 4769.270000 2.076280
S (181.972 nm)3.229260 ppm 0.015525 0.48 689.590444 3.229260
Sb (206.834 nm)0.131348 ppm 0.007322 5.57 164.681000 0.131348
Se (196.026 nm)0.004324 ppm 0.000944 21.82 7.929930 0.004324
Si (288.158 nm)16.098800 o ppm 0.073359 0.46 117743.000000 16.098800 o
Sn (189.925 nm)0.026916 ppm 0.002062 7.66 20.368100 0.026916
Sr (421.552 nm)0.574743 ppm 0.001938 0.34 126912.586410 0.574743
Th (288.505 nm)0.099160 ppm 0.005153 5.20 528.542000 0.099160
Ti (336.122 nm)0.286228 ppm 0.000737 0.26 31366.900000 0.286228
Tl (190.794 nm)-0.002600 u ppm 0.002119 81.50 -5.923530 -0.002600 u
U (409.013 nm)-0.030605 u ppm 0.004708 15.38 -86.666900 -0.030605 u
V (292.401 nm)0.154078 ppm 0.000867 0.56 6356.590000 0.154078
Zn (206.200 nm)5.780090 o ppm 0.027876 0.48 12468.100000 5.780090 o
Zr (343.823 nm)0.019400 ppm 0.000122 0.63 1608.610000 0.019400
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 49 of 287
Page 920 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 2:41:50 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000328 u ppm 0.000006 1.86 97.195410 -0.000328 u
Ag (328.068 nm)-0.000932 u ppm 0.000133 14.27 62.164900 -0.000932 u
Al (394.401 nm)52.182700 o ppm 0.179456 0.34 641523.000000 52.182700 o
Al H (396.152 nm)49.307400 ppm 0.095437 0.19 221648.000000 49.307400
As (188.980 nm)0.000261 u ppm 0.003686 > 100.00 -3.636650 0.000261 u
B (249.678 nm)-0.003407 u ppm 0.000460 13.51 -12.332900 -0.003407 u
Ba (493.408 nm)0.000347 ppm 0.000244 70.44 193.268000 0.000347
Be (234.861 nm)0.000051 u ppm 0.000050 98.18 696.692000 0.000051 u
Bi (223.061 nm)-0.000576 u ppm 0.002188 > 100.00 3.229200 -0.000576 u
Ca (315.887 nm)-0.026030 u ppm 0.005078 19.51 -41.567624 -0.026030 u
Cd (214.439 nm)-0.000072 u ppm 0.000093 > 100.00 9.283620 -0.000072 u
Co (228.615 nm)0.000295 ppm 0.000103 34.73 48.490600 0.000295
Cr (205.560 nm)0.000243 ppm 0.000117 47.88 2.525320 0.000243
Cu (324.754 nm)-0.001385 u ppm 0.000238 17.21 1640.460000 -0.001385 u
Fe (238.204 nm)50.243989 o ppm 0.128343 0.26 197797.497725 50.243989 o
Fe H (259.940 nm)48.751800 ppm 0.109674 0.22 78827.800000 48.751800
K (766.491 nm)0.052698 u ppm 0.071118 > 100.00 -352.733000 0.052698 u
Li (670.783 nm)-0.003117 u ppm 0.000631 20.23 -4396.520000 -0.003117 u
Mg (279.078 nm)-0.002010 u ppm 0.000215 10.70 -186.941000 -0.002010 u
Mn (257.610 nm)-0.000812 u ppm 0.000032 4.00 -212.307000 -0.000812 u
Mo (202.032 nm)-0.000273 u ppm 0.000117 42.73 2.122600 -0.000273 u
Na (589.592 nm)251.413000 o ppm 0.911821 0.36 3057010.000000 251.413000 o
Na H (589.593 nm)240.890613 ppm 1.786965 0.74 2200480.179082 240.890613
Ni (231.604 nm)-0.000283 u ppm 0.000592 > 100.00 -11.173700 -0.000283 u
P (213.618 nm)5.048210 ppm 0.032115 0.64 5962.020000 5.048210
Pb (220.353 nm)0.000805 u ppm 0.000904 > 100.00 -1.335130 0.000805 u
S (181.972 nm)4.871721 ppm 0.038249 0.79 1018.094524 4.871721
Sb (206.834 nm)0.001901 u ppm 0.001789 94.13 7.798380 0.001901 u
Se (196.026 nm)0.006912 u ppm 0.007814 > 100.00 3.983130 0.006912 u
Si (288.158 nm)0.041650 ppm 0.005792 13.91 1014.840000 0.041650
Sn (189.925 nm)0.001602 ppm 0.001434 89.48 3.357650 0.001602
Sr (421.552 nm)0.000527 ppm 0.000024 4.51 125.962953 0.000527
Th (288.505 nm)4.906220 ppm 0.022821 0.47 9428.860000 4.906220
Ti (336.122 nm)0.000888 ppm 0.000024 2.72 -21.139800 0.000888
Tl (190.794 nm)-0.004543 u ppm 0.001545 34.01 -8.325040 -0.004543 u
U (409.013 nm)2.493280 Q ppm 0.008680 0.35 11131.600000 Q 2.493280 Q
V (292.401 nm)0.000018 u ppm 0.000351 > 100.00 241.399000 0.000018 u
Zn (206.200 nm)0.000454 u ppm 0.000943 > 100.00 5.142850 0.000454 u
Zr (343.823 nm)-0.000929 u ppm 0.000058 6.22 -15.346000 -0.000929 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 50 of 287
Page 921 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 2:46:16 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.469070 ppm 0.000972 0.21 1202783.937500 0.469070
Ag (328.068 nm)0.507518 ppm 0.000977 0.19 27102.600000 0.507518
Al (394.401 nm)0.504169 ppm 0.000423 0.08 6657.530000 0.504169
Al H (396.152 nm)0.516479 u ppm 0.002367 0.46 2371.730000 0.516479 u
As (188.980 nm)0.520557 ppm 0.003608 0.69 429.091000 0.520557
B (249.678 nm)0.502346 ppm 0.001426 0.28 4220.640000 0.502346
Ba (493.408 nm)0.509806 ppm 0.000518 0.10 77218.800000 0.509806
Be (234.861 nm)0.499405 ppm 0.001148 0.23 83510.200000 0.499405
Bi (223.061 nm)1.011210 ppm 0.004148 0.41 1507.540000 1.011210
Ca (315.887 nm)5.108566 ppm 0.008762 0.17 3421.301704 5.108566
Cd (214.439 nm)0.512971 ppm 0.000990 0.19 7667.910000 0.512971
Co (228.615 nm)0.519181 ppm 0.001628 0.31 9963.470000 0.519181
Cr (205.560 nm)0.514657 ppm 0.001447 0.28 2116.890000 0.514657
Cu (324.754 nm)0.511947 ppm 0.000948 0.19 24643.000000 0.511947
Fe (238.204 nm)2.547191 ppm 0.006182 0.24 10049.767086 2.547191
Fe H (259.940 nm)2.572180 u ppm 0.008122 0.32 4027.510000 2.572180 u
K (766.491 nm)51.374600 ppm 0.135252 0.26 91854.900000 51.374600
Li (670.783 nm)0.505695 ppm 0.000639 0.13 14525.900000 0.505695
Mg (279.078 nm)20.105500 ppm 0.023667 0.12 67254.600000 20.105500
Mn (257.610 nm)0.496469 ppm 0.000725 0.15 132473.000000 0.496469
Mo (202.032 nm)0.509928 ppm 0.001735 0.34 2533.780000 0.509928
Na (589.592 nm)25.900800 ppm 0.051832 0.20 321860.000000 25.900800
Na H (589.593 nm)16.220747 u ppm 0.143927 0.89 238103.285224 16.220747 u
Ni (231.604 nm)0.507983 ppm 0.001164 0.23 1719.910000 0.507983
P (213.618 nm)0.003374 ppm 0.002711 80.34 -34.083800 0.003374
Pb (220.353 nm)0.527408 ppm 0.001552 0.29 1208.340000 0.527408
S (181.972 nm)-0.032227 u ppm 0.006443 19.99 20.029151 -0.032227 u
Sb (206.834 nm)0.508484 ppm 0.001806 0.36 621.208000 0.508484
Se (196.026 nm)0.520448 ppm 0.006020 1.16 324.458000 0.520448
Si (288.158 nm)5.116700 ppm 0.048560 0.95 38135.300000 5.116700
Sn (189.925 nm)0.510849 ppm 0.005853 1.15 345.564000 0.510849
Sr (421.552 nm)0.510007 ppm 0.000604 0.12 112618.867054 0.510007
Th (288.505 nm)0.037398 ppm 0.000314 0.84 318.300000 0.037398
Ti (336.122 nm)0.508077 ppm 0.000806 0.16 55334.000000 0.508077
Tl (190.794 nm)0.513282 ppm 0.004384 0.85 553.719000 0.513282
U (409.013 nm)-0.005587 u ppm 0.000956 17.12 -14.547500 -0.005587 u
V (292.401 nm)0.508748 ppm 0.001181 0.23 21143.500000 0.508748
Zn (206.200 nm)0.513889 ppm 0.001185 0.23 1112.300000 0.513889
Zr (343.823 nm)0.500421 ppm 0.000692 0.14 40789.800000 0.500421
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 51 of 287
Page 922 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 2:50:38 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000144 ppm 0.000004 2.59 -221.936746 0.000144
Ag (328.068 nm)-0.000071 u ppm 0.000221 > 100.00 -32.880100 -0.000071 u
Al (394.401 nm)0.001800 ppm 0.000745 41.37 471.904000 0.001800
Al H (396.152 nm)0.001113 u ppm 0.002857 > 100.00 55.567400 0.001113 u
As (188.980 nm)0.001274 ppm 0.001051 82.46 -2.345880 0.001274
B (249.678 nm)0.000357 ppm 0.000125 34.94 19.171100 0.000357
Ba (493.408 nm)-0.000106 u ppm 0.000092 86.96 -16.636800 -0.000106 u
Be (234.861 nm)0.000010 u ppm 0.000024 > 100.00 41.512600 0.000010 u
Bi (223.061 nm)-0.000966 u ppm 0.000774 80.14 2.649480 -0.000966 u
Ca (315.887 nm)0.004708 u ppm 0.014001 > 100.00 -20.837712 0.004708 u
Cd (214.439 nm)0.000111 ppm 0.000050 44.54 1.744110 0.000111
Co (228.615 nm)0.000013 u ppm 0.000220 > 100.00 43.104000 0.000013 u
Cr (205.560 nm)-0.000024 u ppm 0.000226 > 100.00 1.421530 -0.000024 u
Cu (324.754 nm)0.000369 ppm 0.000094 25.40 783.452000 0.000369
Fe (238.204 nm)0.000844 u ppm 0.001414 > 100.00 19.927588 0.000844 u
Fe H (259.940 nm)0.094799 u ppm 0.002269 2.39 14.726900 0.094799 u
K (766.491 nm)0.035077 ppm 0.016728 47.69 -384.392000 0.035077
Li (670.783 nm)-0.004314 Su ppm 0.001262 29.26 -4441.030000 S -0.004314 Su
Mg (279.078 nm)0.001887 ppm 0.001478 78.32 15.321600 0.001887
Mn (257.610 nm)0.000002 u ppm 0.000004 > 100.00 5.053980 0.000002 u
Mo (202.032 nm)0.001003 ppm 0.000286 28.49 8.453320 0.001003
Na (589.592 nm)0.386560 Z ppm 0.019498 5.04 5731.840000 Z 0.386560 Z
Na H (589.593 nm)-9.505036 u ppm 0.026949 0.28 8463.985166 -9.505036 u
Ni (231.604 nm)0.000329 u ppm 0.001040 > 100.00 -9.088090 0.000329 u
P (213.618 nm)-0.000023 u ppm 0.003280 > 100.00 3.046450 -0.000023 u
Pb (220.353 nm)0.000291 u ppm 0.000914 > 100.00 -0.968070 0.000291 u
S (181.972 nm)-0.030911 u ppm 0.005949 19.25 17.777097 -0.030911 u
Sb (206.834 nm)-0.001917 u ppm 0.001743 90.93 -0.333776 -0.001917 u
Se (196.026 nm)0.003157 ppm 0.005167 > 100.00 6.952840 0.003157
Si (288.158 nm)0.011085 ppm 0.001109 10.00 792.311000 0.011085
Sn (189.925 nm)0.000020 u ppm 0.000972 > 100.00 2.294500 0.000020 u
Sr (421.552 nm)0.000096 ppm 0.000055 57.54 30.932934 0.000096
Th (288.505 nm)0.007044 ppm 0.000853 12.11 273.664000 0.007044
Ti (336.122 nm)0.000078 ppm 0.000046 59.22 -109.573000 0.000078
Tl (190.794 nm)0.001565 ppm 0.001318 84.23 -0.790873 0.001565
U (409.013 nm)0.000097 u ppm 0.001343 > 100.00 23.907700 0.000097 u
V (292.401 nm)-0.000220 u ppm 0.000225 > 100.00 -48.113100 -0.000220 u
Zn (206.200 nm)-0.001323 u ppm 0.001067 80.65 1.309550 -0.001323 u
Zr (343.823 nm)0.000130 ppm 0.000118 90.35 2.966400 0.000130
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 52 of 287
Page 923 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 2:54:40 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014611 ppm 0.000024 0.16 36974.247600 0.014611
Ag (328.068 nm)0.009844 ppm 0.000048 0.49 495.543000 0.009844
Al (394.401 nm)0.092736 ppm 0.000576 0.62 1596.160000 0.092736
Al H (396.152 nm)0.098966 u ppm 0.003227 3.26 495.340000 0.098966 u
As (188.980 nm)0.017675 ppm 0.001265 7.15 11.280600 0.017675
B (249.678 nm)0.097954 ppm 0.000200 0.20 836.019000 0.097954
Ba (493.408 nm)0.009966 ppm 0.000062 0.63 1509.030000 0.009966
Be (234.861 nm)0.001001 ppm 0.000036 3.55 208.495000 0.001001
Bi (223.061 nm)-0.000771 Qu ppm 0.001517 > 100.00 2.938340 Q -0.000771 Qu
Ca (315.887 nm)0.218770 ppm 0.002772 1.27 123.530083 0.218770
Cd (214.439 nm)0.005261 ppm 0.000184 3.50 78.734600 0.005261
Co (228.615 nm)0.010462 ppm 0.000372 3.56 242.715000 0.010462
Cr (205.560 nm)0.010273 ppm 0.000185 1.80 43.681300 0.010273
Cu (324.754 nm)0.015232 ppm 0.000090 0.59 1474.330000 0.015232
Fe (238.204 nm)0.103525 ppm 0.001315 1.27 424.184578 0.103525
Fe H (259.940 nm)0.194864 u ppm 0.001926 0.99 176.809000 0.194864 u
K (766.491 nm)3.087810 ppm 0.025022 0.81 5100.300000 3.087810
Li (670.783 nm)0.016838 ppm 0.001739 10.33 -3654.400000 0.016838
Mg (279.078 nm)0.203257 ppm 0.001995 0.98 687.506000 0.203257
Mn (257.610 nm)0.010255 ppm 0.000018 0.17 2740.610000 0.010255
Mo (202.032 nm)0.020738 ppm 0.000389 1.88 106.381000 0.020738
Na (589.592 nm)1.396650 Q ppm 0.008285 0.59 18131.100000 Q 1.396650 Q
Na H (589.593 nm)-8.577664 u ppm 0.016385 0.19 16672.020482 -8.577664 u
Ni (231.604 nm)0.042095 ppm 0.000367 0.87 133.138000 0.042095
P (213.618 nm)2.872780 ppm 0.006019 0.21 3393.340000 2.872780
Pb (220.353 nm)0.009667 ppm 0.001044 10.80 20.626100 0.009667
S (181.972 nm)0.060138 Q ppm 0.011130 18.51 36.382150 Q 0.060138 Q
Sb (206.834 nm)0.019522 ppm 0.004000 20.49 25.710000 0.019522
Se (196.026 nm)0.018815 ppm 0.004370 23.23 16.557100 0.018815
Si (288.158 nm)0.491355 ppm 0.008795 1.79 4312.030000 0.491355
Sn (189.925 nm)0.099176 ppm 0.000307 0.31 68.925600 0.099176
Sr (421.552 nm)0.009934 ppm 0.000033 0.33 2203.211802 0.009934
Th (288.505 nm)0.004179 Q ppm 0.002176 52.08 268.458000 Q 0.004179 Q
Ti (336.122 nm)0.009866 ppm 0.000055 0.55 958.889000 0.009866
Tl (190.794 nm)0.015633 ppm 0.001637 10.47 14.439400 0.015633
U (409.013 nm)0.061027 ppm 0.002808 4.60 292.230000 0.061027
V (292.401 nm)0.009849 ppm 0.000267 2.71 367.712000 0.009849
Zn (206.200 nm)0.020097 ppm 0.000381 1.90 47.498900 0.020097
Zr (343.823 nm)0.010144 ppm 0.000056 0.55 819.431000 0.010144
Test Report
52A112023.esws
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Page 924 of 1261
Solution Name: MB 280-634464/1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
MB 280-634464/1-A 11/20/2023 2:59:04 PM 2:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000133 ppm 0.000012 8.85 -248.395349 0.000133
Ag (328.068 nm)-0.000102 u ppm 0.000054 52.92 -34.755700 -0.000102 u
Al (394.401 nm)0.006843 ppm 0.000182 2.65 534.054000 0.006843
Al H (396.152 nm)0.002886 u ppm 0.001360 47.12 63.535600 0.002886 u
As (188.980 nm)-0.001022 u ppm 0.004270 > 100.00 -4.253300 -0.001022 u
B (249.678 nm)-0.000112 u ppm 0.000453 > 100.00 15.243000 -0.000112 u
Ba (493.408 nm)0.000265 ppm 0.000123 46.32 39.556100 0.000265
Be (234.861 nm)0.000012 u ppm 0.000011 92.25 42.012000 0.000012 u
Bi (223.061 nm)0.003178 ppm 0.003472 > 100.00 8.809650 0.003178
Ca (315.887 nm)0.017039 ppm 0.007436 43.64 -12.520881 0.017039
Cd (214.439 nm)0.000004 u ppm 0.000092 > 100.00 0.141140 0.000004 u
Co (228.615 nm)-0.000192 u ppm 0.000159 82.81 39.197200 -0.000192 u
Cr (205.560 nm)0.000331 ppm 0.000130 39.22 2.882080 0.000331
Cu (324.754 nm)0.000502 ppm 0.000101 20.05 789.769000 0.000502
Fe (238.204 nm)0.009746 ppm 0.000278 2.85 54.966552 0.009746
Fe H (259.940 nm)0.102136 u ppm 0.002261 2.21 26.611900 0.102136 u
K (766.491 nm)0.034368 ppm 0.019077 55.51 -385.664000 0.034368
Li (670.783 nm)-0.004712 u ppm 0.001579 33.51 -4455.820000 -0.004712 u
Mg (279.078 nm)0.002205 ppm 0.001737 78.76 16.193900 0.002205
Mn (257.610 nm)0.000372 ppm 0.000007 1.80 103.651000 0.000372
Mo (202.032 nm)0.001394 ppm 0.000372 26.66 10.394200 0.001394
Na (589.592 nm)0.367162 ppm 0.008518 2.32 5503.150000 0.367162
Na H (589.593 nm)-9.673515 u ppm 0.027833 0.29 6994.333423 -9.673515 u
Ni (231.604 nm)-0.000047 u ppm 0.000902 > 100.00 -10.370200 -0.000047 u
P (213.618 nm)0.001740 ppm 0.001785 > 100.00 5.100670 0.001740
Pb (220.353 nm)-0.000190 u ppm 0.000876 > 100.00 -2.062240 -0.000190 u
S (181.972 nm)-0.031261 u ppm 0.005819 18.61 17.703853 -0.031261 u
Sb (206.834 nm)0.000631 u ppm 0.001359 > 100.00 2.772040 0.000631 u
Se (196.026 nm)0.001307 u ppm 0.002288 > 100.00 5.816940 0.001307 u
Si (288.158 nm)0.010593 ppm 0.001877 17.72 788.725000 0.010593
Sn (189.925 nm)-0.000136 u ppm 0.001610 > 100.00 2.189470 -0.000136 u
Sr (421.552 nm)0.000045 u ppm 0.000061 > 100.00 19.638144 0.000045 u
Th (288.505 nm)0.008745 ppm 0.001101 12.58 276.873000 0.008745
Ti (336.122 nm)0.000172 ppm 0.000077 44.37 -99.229100 0.000172
Tl (190.794 nm)0.001446 u ppm 0.002406 > 100.00 -0.921927 0.001446 u
U (409.013 nm)-0.001527 u ppm 0.002081 > 100.00 16.804000 -0.001527 u
V (292.401 nm)-0.000113 u ppm 0.000133 > 100.00 -43.962000 -0.000113 u
Zn (206.200 nm)0.001957 ppm 0.000718 36.69 8.382920 0.001957
Zr (343.823 nm)0.000122 ppm 0.000004 3.29 2.289710 0.000122
Test Report
52A112023.esws
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Page 925 of 1261
Solution Name: LCS 280-634464/2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634464/2-A 11/20/2023 3:03:06 PM 2:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.987867 ppm 0.004531 0.46 2534054.455375 0.987867
Ag (328.068 nm)0.051660 ppm 0.000501 0.97 2254.870000 0.051660
Al (394.401 nm)10.036000 o ppm 0.038278 0.38 123947.000000 10.036000 o
Al H (396.152 nm)9.689510 ppm 0.016258 0.17 43597.200000 9.689510
As (188.980 nm)1.027760 ppm 0.002778 0.27 850.450000 1.027760
B (249.678 nm)2.035300 ppm 0.008327 0.41 17050.900000 2.035300
Ba (493.408 nm)0.997368 ppm 0.002507 0.25 151083.000000 0.997368
Be (234.861 nm)0.996422 ppm 0.002282 0.23 166646.000000 0.996422
Bi (223.061 nm)-0.001456 u ppm 0.000407 27.97 1.919640 -0.001456 u
Ca (315.887 nm)50.494403 o ppm 0.094680 0.19 34030.377065 50.494403 o
Cd (214.439 nm)1.000180 ppm 0.005374 0.54 14951.600000 1.000180
Co (228.615 nm)0.986782 ppm 0.004693 0.48 18899.800000 0.986782
Cr (205.560 nm)0.998383 ppm 0.004972 0.50 4105.060000 0.998383
Cu (324.754 nm)0.984321 ppm 0.004488 0.46 46661.400000 0.984321
Fe (238.204 nm)10.061109 o ppm 0.003486 0.03 39633.677794 10.061109 o
Fe H (259.940 nm)9.951240 ppm 0.005609 0.06 15979.900000 9.951240
K (766.491 nm)51.055900 ppm 0.291932 0.57 91282.400000 51.055900
Li (670.783 nm)0.999555 ppm 0.006464 0.65 32892.300000 0.999555
Mg (279.078 nm)50.936700 o ppm 0.244845 0.48 170370.000000 50.936700 o
Mn (257.610 nm)1.005420 ppm 0.003923 0.39 268272.000000 1.005420
Mo (202.032 nm)1.011370 ppm 0.003102 0.31 5021.990000 1.011370
Na (589.592 nm)50.060900 ppm 0.314443 0.63 621256.000000 50.060900
Na H (589.593 nm)40.583201 u ppm 0.469945 1.16 455606.875354 40.583201 u
Ni (231.604 nm)0.970581 ppm 0.002927 0.30 3295.470000 0.970581
P (213.618 nm)20.234000 o ppm 0.107364 0.53 23811.300000 20.234000 o
Pb (220.353 nm)1.027230 ppm 0.007352 0.72 2353.980000 1.027230
S (181.972 nm)19.183434 o ppm 0.109900 0.57 3935.567140 19.183434 o
Sb (206.834 nm)1.047680 ppm 0.007504 0.72 1278.100000 1.047680
Se (196.026 nm)0.997889 ppm 0.001999 0.20 616.996000 0.997889
Si (288.158 nm)9.724460 ppm 0.033319 0.34 71847.100000 9.724460
Sn (189.925 nm)0.984934 ppm 0.000879 0.09 664.143000 0.984934
Sr (421.552 nm)0.997670 ppm 0.002750 0.28 220294.739550 0.997670
Th (288.505 nm)0.064795 ppm 0.001683 2.60 358.110000 0.064795
Ti (336.122 nm)0.997680 ppm 0.003678 0.37 108858.000000 0.997680
Tl (190.794 nm)0.997107 ppm 0.005678 0.57 1077.800000 0.997107
U (409.013 nm)-0.001117 u ppm 0.004352 > 100.00 -2.859090 -0.001117 u
V (292.401 nm)1.009990 ppm 0.005004 0.50 42022.100000 1.009990
Zn (206.200 nm)1.000220 ppm 0.006778 0.68 2161.010000 1.000220
Zr (343.823 nm)0.996850 ppm 0.004046 0.41 81268.500000 0.996850
Test Report
52A112023.esws
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Page 926 of 1261
Solution Name: 280-184114-B-34-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-34-A 11/20/2023 3:07:29 PM 2:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010340 ppm 0.000017 0.16 26903.230865 0.010340
Ag (328.068 nm)0.001001 ppm 0.000040 3.96 20.401500 0.001001
Al (394.401 nm)0.027378 ppm 0.000814 2.97 784.495000 0.027378
Al H (396.152 nm)0.001601 u ppm 0.001873 > 100.00 57.761700 0.001601 u
As (188.980 nm)0.007628 ppm 0.002114 27.72 2.933430 0.007628
B (249.678 nm)0.130059 ppm 0.001159 0.89 1104.730000 0.130059
Ba (493.408 nm)0.581938 ppm 0.002699 0.46 88136.400000 0.581938
Be (234.861 nm)0.000147 ppm 0.000011 7.43 64.735600 0.000147
Bi (223.061 nm)0.000818 u ppm 0.002122 > 100.00 5.301940 0.000818 u
Ca (315.887 nm)52.636142 o ppm 0.243766 0.46 35474.806143 52.636142 o
Cd (214.439 nm)0.000312 ppm 0.000198 63.46 4.752220 0.000312
Co (228.615 nm)0.000053 u ppm 0.000196 > 100.00 43.864600 0.000053 u
Cr (205.560 nm)0.000632 u ppm 0.000835 > 100.00 4.113940 0.000632 u
Cu (324.754 nm)0.006331 ppm 0.000191 3.02 1031.680000 0.006331
Fe (238.204 nm)0.022795 ppm 0.001211 5.31 106.348298 0.022795
Fe H (259.940 nm)0.113362 u ppm 0.000315 0.28 44.794300 0.113362 u
K (766.491 nm)2.408830 ppm 0.049881 2.07 3880.410000 2.408830
Li (670.783 nm)0.008197 ppm 0.000994 12.13 -3975.740000 0.008197
Mg (279.078 nm)38.972800 ppm 0.157005 0.40 130361.000000 38.972800
Mn (257.610 nm)0.002656 ppm 0.000035 1.33 713.070000 0.002656
Mo (202.032 nm)0.003050 ppm 0.000501 16.41 18.610700 0.003050
Na (589.592 nm)61.137500 o ppm 0.066658 0.11 751012.000000 61.137500 o
Na H (589.593 nm)50.864678 ppm 0.679610 1.34 542006.185836 50.864678
Ni (231.604 nm)-0.000656 u ppm 0.001068 > 100.00 -12.444000 -0.000656 u
P (213.618 nm)0.039441 ppm 0.001450 3.68 49.242000 0.039441
Pb (220.353 nm)-0.000634 u ppm 0.000703 > 100.00 -3.074270 -0.000634 u
S (181.972 nm)23.895841 o ppm 0.153201 0.64 4891.466415 23.895841 o
Sb (206.834 nm)-0.000447 u ppm 0.002515 > 100.00 1.455220 -0.000447 u
Se (196.026 nm)0.003219 u ppm 0.003814 > 100.00 6.990110 0.003219 u
Si (288.158 nm)5.723170 ppm 0.026425 0.46 42294.000000 5.723170
Sn (189.925 nm)0.000463 u ppm 0.001743 > 100.00 2.592170 0.000463 u
Sr (421.552 nm)0.444058 ppm 0.002210 0.50 98057.554019 0.444058
Th (288.505 nm)0.037353 ppm 0.002146 5.75 330.836000 0.037353
Ti (336.122 nm)-0.000084 u ppm 0.000060 72.34 -12.103500 -0.000084 u
Tl (190.794 nm)0.001664 u ppm 0.003308 > 100.00 -0.688344 0.001664 u
U (409.013 nm)0.014490 ppm 0.003354 23.15 87.532400 0.014490
V (292.401 nm)0.005831 ppm 0.000140 2.40 205.779000 0.005831
Zn (206.200 nm)0.011107 ppm 0.000193 1.74 28.113500 0.011107
Zr (343.823 nm)0.000487 ppm 0.000021 4.22 32.097600 0.000487
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 56 of 287
Page 927 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 3:11:46 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000294 u ppm 0.000014 4.85 194.428740 -0.000294 u
Ag (328.068 nm)-0.000906 u ppm 0.000332 36.64 65.263000 -0.000906 u
Al (394.401 nm)52.385500 o ppm 0.168588 0.32 644008.000000 52.385500 o
Al H (396.152 nm)49.395100 ppm 0.258757 0.52 222042.000000 49.395100
As (188.980 nm)0.001112 u ppm 0.003779 > 100.00 -2.934010 0.001112 u
B (249.678 nm)-0.001534 u ppm 0.000764 49.82 3.341350 -0.001534 u
Ba (493.408 nm)0.000408 ppm 0.000138 33.67 203.979000 0.000408
Be (234.861 nm)0.000231 ppm 0.000040 17.44 733.023000 0.000231
Bi (223.061 nm)0.000166 u ppm 0.001259 > 100.00 4.331150 0.000166 u
Ca (315.887 nm)-0.020961 u ppm 0.015619 74.51 -38.149256 -0.020961 u
Cd (214.439 nm)-0.000059 u ppm 0.000246 > 100.00 9.571230 -0.000059 u
Co (228.615 nm)0.000254 u ppm 0.000272 > 100.00 47.713200 0.000254 u
Cr (205.560 nm)0.000819 ppm 0.000212 25.87 4.892880 0.000819
Cu (324.754 nm)-0.001678 u ppm 0.000259 15.42 1636.640000 -0.001678 u
Fe (238.204 nm)50.744061 o ppm 0.210584 0.41 199765.981226 50.744061 o
Fe H (259.940 nm)49.346000 ppm 0.203985 0.41 79790.300000 49.346000
K (766.491 nm)0.051318 ppm 0.022275 43.41 -355.212000 0.051318
Li (670.783 nm)-0.002424 u ppm 0.002367 97.62 -4370.760000 -0.002424 u
Mg (279.078 nm)-0.001907 u ppm 0.002103 > 100.00 -188.349000 -0.001907 u
Mn (257.610 nm)-0.000917 u ppm 0.000007 0.80 -240.190000 -0.000917 u
Mo (202.032 nm)-0.000002 u ppm 0.000424 > 100.00 3.470630 -0.000002 u
Na (589.592 nm)251.372000 o ppm 0.944250 0.38 3056510.000000 251.372000 o
Na H (589.593 nm)241.754656 ppm 1.853165 0.77 2208044.874206 241.754656
Ni (231.604 nm)-0.000301 u ppm 0.000233 77.23 -11.234900 -0.000301 u
P (213.618 nm)4.977220 ppm 0.027863 0.56 5878.210000 4.977220
Pb (220.353 nm)0.001566 ppm 0.000366 23.38 0.426404 0.001566
S (181.972 nm)4.886320 ppm 0.041930 0.86 1021.089437 4.886320
Sb (206.834 nm)0.001979 ppm 0.001370 69.23 7.926790 0.001979
Se (196.026 nm)0.008255 ppm 0.003081 37.33 4.755320 0.008255
Si (288.158 nm)0.035492 ppm 0.002190 6.17 970.369000 0.035492
Sn (189.925 nm)0.002227 ppm 0.002267 > 100.00 3.777690 0.002227
Sr (421.552 nm)0.000557 ppm 0.000042 7.58 132.571026 0.000557
Th (288.505 nm)4.920570 ppm 0.015493 0.31 9455.710000 4.920570
Ti (336.122 nm)0.000850 ppm 0.000089 10.49 -25.301700 0.000850
Tl (190.794 nm)-0.003831 u ppm 0.000375 9.79 -7.561220 -0.003831 u
U (409.013 nm)2.496670 Q ppm 0.009667 0.39 11147.800000 Q 2.496670 Q
V (292.401 nm)0.000104 ppm 0.000034 33.07 248.172000 0.000104
Zn (206.200 nm)0.001321 ppm 0.000337 25.49 7.010940 0.001321
Zr (343.823 nm)-0.000961 u ppm 0.000072 7.45 -17.266500 -0.000961 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 57 of 287
Page 928 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 3:16:13 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.466831 ppm 0.001038 0.22 1197044.737493 0.466831
Ag (328.068 nm)0.506952 ppm 0.003462 0.68 27074.500000 0.506952
Al (394.401 nm)0.502769 ppm 0.001223 0.24 6632.740000 0.502769
Al H (396.152 nm)0.505956 u ppm 0.002277 0.45 2324.440000 0.505956 u
As (188.980 nm)0.508167 ppm 0.004044 0.80 418.797000 0.508167
B (249.678 nm)0.504113 ppm 0.000113 0.02 4235.440000 0.504113
Ba (493.408 nm)0.505614 ppm 0.001938 0.38 76583.800000 0.505614
Be (234.861 nm)0.499773 ppm 0.001338 0.27 83571.500000 0.499773
Bi (223.061 nm)1.010820 ppm 0.001873 0.19 1506.960000 1.010820
Ca (315.887 nm)5.065515 ppm 0.006796 0.13 3392.267659 5.065515
Cd (214.439 nm)0.513358 ppm 0.001865 0.36 7673.700000 0.513358
Co (228.615 nm)0.513701 ppm 0.000999 0.19 9858.940000 0.513701
Cr (205.560 nm)0.514854 ppm 0.001921 0.37 2117.690000 0.514854
Cu (324.754 nm)0.509728 ppm 0.002084 0.41 24545.300000 0.509728
Fe (238.204 nm)2.533662 ppm 0.002127 0.08 9996.519156 2.533662
Fe H (259.940 nm)2.560550 u ppm 0.005421 0.21 4008.670000 2.560550 u
K (766.491 nm)50.982500 ppm 0.018999 0.04 91150.300000 50.982500
Li (670.783 nm)0.502929 ppm 0.001281 0.25 14423.000000 0.502929
Mg (279.078 nm)20.270800 ppm 0.090757 0.45 67806.800000 20.270800
Mn (257.610 nm)0.505738 ppm 0.001738 0.34 134946.000000 0.505738
Mo (202.032 nm)0.509572 ppm 0.000620 0.12 2532.020000 0.509572
Na (589.592 nm)25.474800 ppm 0.008439 0.03 316627.000000 25.474800
Na H (589.593 nm)15.611378 u ppm 0.171576 1.10 232728.773672 15.611378 u
Ni (231.604 nm)0.512848 ppm 0.003019 0.59 1736.470000 0.512848
P (213.618 nm)0.006302 ppm 0.003973 63.04 -30.536600 0.006302
Pb (220.353 nm)0.523730 ppm 0.001804 0.34 1199.900000 0.523730
S (181.972 nm)-0.024270 u ppm 0.010942 45.08 21.635079 -0.024270 u
Sb (206.834 nm)0.506215 ppm 0.002193 0.43 618.447000 0.506215
Se (196.026 nm)0.507065 ppm 0.003282 0.65 316.253000 0.507065
Si (288.158 nm)5.061890 ppm 0.010340 0.20 37737.000000 5.061890
Sn (189.925 nm)0.511534 ppm 0.005473 1.07 346.025000 0.511534
Sr (421.552 nm)0.506084 ppm 0.001801 0.36 111752.797802 0.506084
Th (288.505 nm)0.035361 ppm 0.000690 1.95 314.636000 0.035361
Ti (336.122 nm)0.506874 ppm 0.001475 0.29 55202.600000 0.506874
Tl (190.794 nm)0.512841 ppm 0.001107 0.22 553.234000 0.512841
U (409.013 nm)-0.005303 u ppm 0.001944 36.66 -12.957700 -0.005303 u
V (292.401 nm)0.508419 ppm 0.001301 0.26 21132.100000 0.508419
Zn (206.200 nm)0.514603 ppm 0.001064 0.21 1113.830000 0.514603
Zr (343.823 nm)0.502236 ppm 0.001660 0.33 40937.700000 0.502236
Test Report
52A112023.esws
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Page 929 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 3:20:34 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000176 ppm 0.000015 8.68 -135.657838 0.000176
Ag (328.068 nm)0.000036 u ppm 0.000096 > 100.00 -27.280600 0.000036 u
Al (394.401 nm)0.001354 ppm 0.000357 26.39 465.964000 0.001354
Al H (396.152 nm)-0.000749 u ppm 0.002438 > 100.00 47.200200 -0.000749 u
As (188.980 nm)0.001596 ppm 0.000136 8.55 -2.078750 0.001596
B (249.678 nm)0.000479 ppm 0.000219 45.76 20.185700 0.000479
Ba (493.408 nm)-0.000067 u ppm 0.000102 > 100.00 -10.717300 -0.000067 u
Be (234.861 nm)0.000040 ppm 0.000018 44.91 46.598100 0.000040
Bi (223.061 nm)-0.000326 u ppm 0.002096 > 100.00 3.599740 -0.000326 u
Ca (315.887 nm)0.007775 ppm 0.003732 48.01 -18.769159 0.007775
Cd (214.439 nm)0.000117 u ppm 0.000200 > 100.00 1.830490 0.000117 u
Co (228.615 nm)0.000019 u ppm 0.000143 > 100.00 43.206700 0.000019 u
Cr (205.560 nm)0.000182 u ppm 0.000559 > 100.00 2.270930 0.000182 u
Cu (324.754 nm)0.000519 ppm 0.000135 26.08 790.956000 0.000519
Fe (238.204 nm)0.001892 ppm 0.001309 69.20 24.052723 0.001892
Fe H (259.940 nm)0.092260 u ppm 0.002310 2.50 10.614100 0.092260 u
K (766.491 nm)0.022448 ppm 0.020441 91.06 -407.081000 0.022448
Li (670.783 nm)-0.002726 Su ppm 0.001210 44.38 -4381.960000 S -0.002726 Su
Mg (279.078 nm)0.001328 u ppm 0.001615 > 100.00 13.237900 0.001328 u
Mn (257.610 nm)-0.000027 u ppm 0.000028 > 100.00 -2.737120 -0.000027 u
Mo (202.032 nm)0.000815 ppm 0.000461 56.52 7.523610 0.000815
Na (589.592 nm)0.203965 ppm 0.012662 6.21 3516.180000 0.203965
Na H (589.593 nm)-9.837041 u ppm 0.013862 0.14 5560.370367 -9.837041 u
Ni (231.604 nm)0.000304 u ppm 0.000716 > 100.00 -9.173370 0.000304 u
P (213.618 nm)0.001071 u ppm 0.001077 > 100.00 4.331230 0.001071 u
Pb (220.353 nm)0.000519 u ppm 0.002290 > 100.00 -0.431069 0.000519 u
S (181.972 nm)-0.027450 u ppm 0.006530 23.79 18.486573 -0.027450 u
Sb (206.834 nm)-0.000050 u ppm 0.001878 > 100.00 1.943320 -0.000050 u
Se (196.026 nm)0.003746 ppm 0.001163 31.06 7.313960 0.003746
Si (288.158 nm)0.007921 ppm 0.001564 19.74 769.132000 0.007921
Sn (189.925 nm)-0.000383 u ppm 0.001349 > 100.00 2.023390 -0.000383 u
Sr (421.552 nm)0.000066 ppm 0.000030 45.13 24.302292 0.000066
Th (288.505 nm)0.011650 Z ppm 0.002056 17.65 282.286000 Z 0.011650 Z
Ti (336.122 nm)-0.000003 u ppm 0.000053 > 100.00 -118.350000 -0.000003 u
Tl (190.794 nm)0.001213 u ppm 0.002126 > 100.00 -1.172360 0.001213 u
U (409.013 nm)0.000267 u ppm 0.001700 > 100.00 24.722400 0.000267 u
V (292.401 nm)-0.000045 u ppm 0.000252 > 100.00 -40.839800 -0.000045 u
Zn (206.200 nm)-0.001013 u ppm 0.000481 47.49 1.979150 -0.001013 u
Zr (343.823 nm)0.000174 ppm 0.000024 13.50 6.545590 0.000174
Test Report
52A112023.esws
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Page 930 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 3:24:37 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014620 ppm 0.000044 0.30 36993.033207 0.014620
Ag (328.068 nm)0.009861 ppm 0.000025 0.26 495.557000 0.009861
Al (394.401 nm)0.092267 ppm 0.000930 1.01 1596.140000 0.092267
Al H (396.152 nm)0.095304 u ppm 0.002155 2.26 478.878000 0.095304 u
As (188.980 nm)0.015803 ppm 0.002097 13.27 9.724830 0.015803
B (249.678 nm)0.098292 ppm 0.000129 0.13 838.851000 0.098292
Ba (493.408 nm)0.010086 ppm 0.000341 3.38 1527.210000 0.010086
Be (234.861 nm)0.000969 ppm 0.000018 1.89 203.003000 0.000969
Bi (223.061 nm)0.001935 Qu ppm 0.002546 > 100.00 6.962650 Q 0.001935 Qu
Ca (315.887 nm)0.207873 ppm 0.000712 0.34 116.180753 0.207873
Cd (214.439 nm)0.005197 ppm 0.000031 0.59 77.779500 0.005197
Co (228.615 nm)0.010469 ppm 0.000084 0.80 242.844000 0.010469
Cr (205.560 nm)0.010051 ppm 0.000164 1.63 42.769400 0.010051
Cu (324.754 nm)0.015220 ppm 0.000187 1.23 1469.250000 0.015220
Fe (238.204 nm)0.103019 ppm 0.001120 1.09 422.194916 0.103019
Fe H (259.940 nm)0.193281 u ppm 0.002895 1.50 174.245000 0.193281 u
K (766.491 nm)3.000330 ppm 0.020070 0.67 4943.140000 3.000330
Li (670.783 nm)0.017004 ppm 0.001335 7.85 -3648.240000 0.017004
Mg (279.078 nm)0.202638 ppm 0.000706 0.35 686.001000 0.202638
Mn (257.610 nm)0.010384 ppm 0.000030 0.29 2775.080000 0.010384
Mo (202.032 nm)0.020686 ppm 0.000727 3.51 106.121000 0.020686
Na (589.592 nm)1.224220 ppm 0.001274 0.10 16038.800000 1.224220
Na H (589.593 nm)-8.856691 u ppm 0.011564 0.13 14232.112408 -8.856691 u
Ni (231.604 nm)0.042224 ppm 0.000116 0.28 133.578000 0.042224
P (213.618 nm)2.858700 ppm 0.002922 0.10 3376.710000 2.858700
Pb (220.353 nm)0.008553 ppm 0.000806 9.43 18.061900 0.008553
S (181.972 nm)0.067562 Q ppm 0.006356 9.41 37.895202 Q 0.067562 Q
Sb (206.834 nm)0.021959 ppm 0.003061 13.94 28.682000 0.021959
Se (196.026 nm)0.020356 ppm 0.004401 21.62 17.503100 0.020356
Si (288.158 nm)0.485586 ppm 0.006717 1.38 4269.610000 0.485586
Sn (189.925 nm)0.097287 ppm 0.002762 2.84 67.656500 0.097287
Sr (421.552 nm)0.009981 ppm 0.000098 0.98 2213.506725 0.009981
Th (288.505 nm)0.005592 Q ppm 0.001052 18.80 271.087000 Q 0.005592 Q
Ti (336.122 nm)0.009789 ppm 0.000025 0.26 950.435000 0.009789
Tl (190.794 nm)0.017936 ppm 0.000179 1.00 16.940900 0.017936
U (409.013 nm)0.058078 ppm 0.002477 4.26 278.902000 0.058078
V (292.401 nm)0.009828 ppm 0.000141 1.44 365.032000 0.009828
Zn (206.200 nm)0.020659 ppm 0.000460 2.23 48.711200 0.020659
Zr (343.823 nm)0.009988 ppm 0.000054 0.54 806.737000 0.009988
Test Report
52A112023.esws
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Page 931 of 1261
Solution Name: 280-184114-B-35-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-35-A 11/20/2023 3:28:57 PM 2:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010422 ppm 0.000049 0.47 27130.344812 0.010422
Ag (328.068 nm)0.000951 ppm 0.000300 31.54 19.079900 0.000951
Al (394.401 nm)0.033629 ppm 0.001540 4.58 851.314000 0.033629
Al H (396.152 nm)0.009280 u ppm 0.002241 24.15 92.269200 0.009280 u
As (188.980 nm)0.004948 ppm 0.000854 17.25 0.706608 0.004948
B (249.678 nm)0.128622 ppm 0.000490 0.38 1092.700000 0.128622
Ba (493.408 nm)0.583727 ppm 0.002982 0.51 88407.300000 0.583727
Be (234.861 nm)0.000132 ppm 0.000011 8.73 62.388300 0.000132
Bi (223.061 nm)0.002456 ppm 0.001227 49.94 7.737280 0.002456
Ca (315.887 nm)53.186742 o ppm 0.291616 0.55 35846.141771 53.186742 o
Cd (214.439 nm)0.000382 ppm 0.000120 31.35 5.791440 0.000382
Co (228.615 nm)0.000226 u ppm 0.000320 > 100.00 47.164800 0.000226 u
Cr (205.560 nm)0.000739 ppm 0.000581 78.63 4.551690 0.000739
Cu (324.754 nm)0.010149 ppm 0.000179 1.76 1217.330000 0.010149
Fe (238.204 nm)0.041805 ppm 0.002685 6.42 181.179607 0.041805
Fe H (259.940 nm)0.134992 u ppm 0.002900 2.15 79.830700 0.134992 u
K (766.491 nm)2.439580 ppm 0.045607 1.87 3935.660000 2.439580
Li (670.783 nm)0.006435 ppm 0.001042 16.19 -4041.290000 0.006435
Mg (279.078 nm)39.435800 ppm 0.184378 0.47 131909.000000 39.435800
Mn (257.610 nm)0.003090 ppm 0.000034 1.09 829.053000 0.003090
Mo (202.032 nm)0.002774 ppm 0.000273 9.83 17.244900 0.002774
Na (589.592 nm)61.861700 o ppm 0.174867 0.28 759832.000000 61.861700 o
Na H (589.593 nm)57.261452 ppm 2.290740 4.00 598017.765085 57.261452
Ni (231.604 nm)-0.000867 u ppm 0.000567 65.38 -13.162700 -0.000867 u
P (213.618 nm)0.039098 ppm 0.001280 3.27 48.643500 0.039098
Pb (220.353 nm)0.000504 u ppm 0.001259 > 100.00 -0.457581 0.000504 u
S (181.972 nm)24.130156 o ppm 0.163239 0.68 4939.195586 24.130156 o
Sb (206.834 nm)-0.000802 u ppm 0.002317 > 100.00 1.023290 -0.000802 u
Se (196.026 nm)0.002555 ppm 0.001819 71.17 6.581190 0.002555
Si (288.158 nm)5.783920 ppm 0.040726 0.70 42735.300000 5.783920
Sn (189.925 nm)-0.000457 u ppm 0.000432 94.56 1.973940 -0.000457 u
Sr (421.552 nm)0.445347 ppm 0.002271 0.51 98342.157288 0.445347
Th (288.505 nm)0.036480 ppm 0.002095 5.74 329.216000 0.036480
Ti (336.122 nm)-0.000048 u ppm 0.000051 > 100.00 -7.002830 -0.000048 u
Tl (190.794 nm)0.000913 u ppm 0.000940 > 100.00 -1.503450 0.000913 u
U (409.013 nm)0.016303 ppm 0.001700 10.43 96.120400 0.016303
V (292.401 nm)0.005808 ppm 0.000230 3.97 208.140000 0.005808
Zn (206.200 nm)0.013131 ppm 0.000634 4.83 32.478500 0.013131
Zr (343.823 nm)0.000256 ppm 0.000179 69.73 13.289400 0.000256
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 61 of 287
Page 932 of 1261
Solution Name: 280-184114-B-36-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-36-A 11/20/2023 3:33:15 PM 2:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010793 ppm 0.000056 0.52 27824.432527 0.010793
Ag (328.068 nm)0.000589 ppm 0.000144 24.36 -0.300709 0.000589
Al (394.401 nm)0.027682 ppm 0.000780 2.82 780.864000 0.027682
Al H (396.152 nm)-0.000381 u ppm 0.002111 > 100.00 48.852400 -0.000381 u
As (188.980 nm)0.004297 ppm 0.001444 33.61 0.166065 0.004297
B (249.678 nm)0.128776 ppm 0.000777 0.60 1093.990000 0.128776
Ba (493.408 nm)0.621836 ppm 0.000640 0.10 94179.000000 0.621836
Be (234.861 nm)0.000099 ppm 0.000023 23.57 56.680200 0.000099
Bi (223.061 nm)-0.000540 u ppm 0.001808 > 100.00 3.282110 -0.000540 u
Ca (315.887 nm)59.166018 o ppm 0.034403 0.06 39878.679169 59.166018 o
Cd (214.439 nm)0.000351 ppm 0.000074 20.94 5.328730 0.000351
Co (228.615 nm)-0.000089 u ppm 0.000134 > 100.00 41.156400 -0.000089 u
Cr (205.560 nm)0.000687 ppm 0.000477 69.43 4.337590 0.000687
Cu (324.754 nm)0.003100 ppm 0.000451 14.54 882.720000 0.003100
Fe (238.204 nm)0.019357 ppm 0.000745 3.85 92.814135 0.019357
Fe H (259.940 nm)0.113390 u ppm 0.001986 1.75 44.839700 0.113390 u
K (766.491 nm)2.330330 ppm 0.041979 1.80 3739.380000 2.330330
Li (670.783 nm)0.005850 ppm 0.001594 27.24 -4063.050000 0.005850
Mg (279.078 nm)40.126300 ppm 0.188443 0.47 134218.000000 40.126300
Mn (257.610 nm)0.000632 ppm 0.000010 1.52 173.114000 0.000632
Mo (202.032 nm)0.002995 ppm 0.000141 4.71 18.340100 0.002995
Na (589.592 nm)62.758600 o ppm 0.340562 0.54 771183.000000 62.758600 o
Na H (589.593 nm)54.555549 ppm 2.463624 4.52 574661.375557 54.555549
Ni (231.604 nm)-0.001762 u ppm 0.000462 26.21 -16.210100 -0.001762 u
P (213.618 nm)0.037461 ppm 0.002867 7.65 47.065700 0.037461
Pb (220.353 nm)0.000390 u ppm 0.001581 > 100.00 -0.713506 0.000390 u
S (181.972 nm)7.599099 ppm 0.057799 0.76 1572.782607 7.599099
Sb (206.834 nm)-0.002124 u ppm 0.001888 88.93 -0.588963 -0.002124 u
Se (196.026 nm)0.001707 u ppm 0.003033 > 100.00 6.061530 0.001707 u
Si (288.158 nm)5.896340 ppm 0.027608 0.47 43551.900000 5.896340
Sn (189.925 nm)-0.001092 u ppm 0.001416 > 100.00 1.547070 -0.001092 u
Sr (421.552 nm)0.465257 ppm 0.000448 0.10 102738.242100 0.465257
Th (288.505 nm)0.039459 ppm 0.003443 8.73 334.786000 0.039459
Ti (336.122 nm)-0.000069 u ppm 0.000064 92.16 3.798720 -0.000069 u
Tl (190.794 nm)0.001270 u ppm 0.002921 > 100.00 -1.116670 0.001270 u
U (409.013 nm)0.017635 ppm 0.003906 22.15 101.847000 0.017635
V (292.401 nm)0.005421 ppm 0.000138 2.55 190.895000 0.005421
Zn (206.200 nm)0.004002 ppm 0.000726 18.15 12.792800 0.004002
Zr (343.823 nm)0.000134 ppm 0.000034 25.14 3.284960 0.000134
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 62 of 287
Page 933 of 1261
Solution Name: 280-184114-B-37-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-37-A 11/20/2023 3:37:34 PM 2:6 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010529 ppm 0.000057 0.54 27126.569054 0.010529
Ag (328.068 nm)0.000811 ppm 0.000055 6.76 11.427200 0.000811
Al (394.401 nm)0.021188 ppm 0.000212 1.00 702.899000 0.021188
Al H (396.152 nm)-0.003165 u ppm 0.001145 36.17 36.341600 -0.003165 u
As (188.980 nm)0.004021 ppm 0.001343 33.39 -0.063337 0.004021
B (249.678 nm)0.125161 ppm 0.001353 1.08 1063.730000 0.125161
Ba (493.408 nm)0.602796 ppm 0.003048 0.51 91295.300000 0.602796
Be (234.861 nm)0.000094 ppm 0.000020 21.73 55.825600 0.000094
Bi (223.061 nm)0.000588 u ppm 0.002203 > 100.00 4.959600 0.000588 u
Ca (315.887 nm)57.296492 o ppm 0.347182 0.61 38617.835338 57.296492 o
Cd (214.439 nm)0.000160 ppm 0.000075 47.13 2.469710 0.000160
Co (228.615 nm)0.000109 ppm 0.000040 36.86 44.919600 0.000109
Cr (205.560 nm)0.000737 u ppm 0.000762 > 100.00 4.546200 0.000737 u
Cu (324.754 nm)0.008318 ppm 0.000090 1.08 1125.650000 0.008318
Fe (238.204 nm)0.018471 ppm 0.001186 6.42 89.320150 0.018471
Fe H (259.940 nm)0.108396 u ppm 0.003422 3.16 36.751300 0.108396 u
K (766.491 nm)2.223580 ppm 0.029234 1.31 3547.580000 2.223580
Li (670.783 nm)0.010076 ppm 0.001769 17.56 -3905.860000 0.010076
Mg (279.078 nm)39.087000 ppm 0.196860 0.50 130742.000000 39.087000
Mn (257.610 nm)0.000522 ppm 0.000013 2.48 143.851000 0.000522
Mo (202.032 nm)0.002122 ppm 0.000152 7.16 14.009900 0.002122
Na (589.592 nm)60.782700 o ppm 0.082142 0.14 746944.000000 60.782700 o
Na H (589.593 nm)51.188732 ppm 0.340217 0.66 545023.657621 51.188732
Ni (231.604 nm)-0.000693 u ppm 0.001011 > 100.00 -12.570600 -0.000693 u
P (213.618 nm)0.036547 ppm 0.001320 3.61 45.742400 0.036547
Pb (220.353 nm)0.001446 u ppm 0.001833 > 100.00 1.704110 0.001446 u
S (181.972 nm)7.371583 ppm 0.078862 1.07 1526.415014 7.371583
Sb (206.834 nm)-0.002423 u ppm 0.001046 43.17 -0.949972 -0.002423 u
Se (196.026 nm)0.003391 u ppm 0.003024 89.18 7.094860 0.003391 u
Si (288.158 nm)5.727900 ppm 0.036802 0.64 42328.300000 5.727900
Sn (189.925 nm)-0.000646 u ppm 0.002387 > 100.00 1.847120 -0.000646 u
Sr (421.552 nm)0.451005 ppm 0.002042 0.45 99591.313475 0.451005
Th (288.505 nm)0.036526 ppm 0.002540 6.95 329.264000 0.036526
Ti (336.122 nm)-0.000329 u ppm 0.000068 20.77 -28.669100 -0.000329 u
Tl (190.794 nm)0.000626 u ppm 0.001858 > 100.00 -1.812430 0.000626 u
U (409.013 nm)0.012294 ppm 0.005068 41.23 78.167600 0.012294
V (292.401 nm)0.005022 ppm 0.000072 1.43 173.769000 0.005022
Zn (206.200 nm)0.002906 ppm 0.000165 5.68 10.429600 0.002906
Zr (343.823 nm)0.000121 ppm 0.000096 79.31 2.230870 0.000121
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 63 of 287
Page 934 of 1261
Solution Name: 280-184114-B-38-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-38-A 11/20/2023 3:41:52 PM 2:7 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010247 ppm 0.000053 0.51 26379.710267 0.010247
Ag (328.068 nm)0.000605 ppm 0.000043 7.15 0.251930 0.000605
Al (394.401 nm)0.022159 ppm 0.001280 5.78 714.730000 0.022159
Al H (396.152 nm)-0.003308 u ppm 0.000466 14.08 35.696800 -0.003308 u
As (188.980 nm)0.005769 ppm 0.002671 46.29 1.388780 0.005769
B (249.678 nm)0.122230 ppm 0.000355 0.29 1039.210000 0.122230
Ba (493.408 nm)0.587341 ppm 0.004999 0.85 88954.500000 0.587341
Be (234.861 nm)0.000114 ppm 0.000029 25.37 59.159200 0.000114
Bi (223.061 nm)-0.000125 u ppm 0.001055 > 100.00 3.898690 -0.000125 u
Ca (315.887 nm)55.813755 o ppm 0.432312 0.77 37617.849058 55.813755 o
Cd (214.439 nm)0.000382 ppm 0.000159 41.56 5.795320 0.000382
Co (228.615 nm)0.000095 u ppm 0.000259 > 100.00 44.653900 0.000095 u
Cr (205.560 nm)0.000098 u ppm 0.000522 > 100.00 1.913740 0.000098 u
Cu (324.754 nm)0.012548 ppm 0.000162 1.29 1324.020000 0.012548
Fe (238.204 nm)0.013345 ppm 0.001485 11.13 69.140280 0.013345
Fe H (259.940 nm)0.105831 u ppm 0.000774 0.73 32.596600 0.105831 u
K (766.491 nm)2.198360 ppm 0.022823 1.04 3502.270000 2.198360
Li (670.783 nm)0.009140 ppm 0.001564 17.12 -3940.680000 0.009140
Mg (279.078 nm)38.035800 ppm 0.171533 0.45 127226.000000 38.035800
Mn (257.610 nm)0.000495 ppm 0.000045 9.07 136.509000 0.000495
Mo (202.032 nm)0.002397 ppm 0.000497 20.75 15.372500 0.002397
Na (589.592 nm)59.069900 o ppm 0.316604 0.54 725942.000000 59.069900 o
Na H (589.593 nm)49.469104 u ppm 0.651555 1.32 529834.245879 49.469104 u
Ni (231.604 nm)0.000097 u ppm 0.000474 > 100.00 -9.880420 0.000097 u
P (213.618 nm)0.034216 ppm 0.002330 6.81 42.770100 0.034216
Pb (220.353 nm)0.000707 ppm 0.000853 > 100.00 0.007529 0.000707
S (181.972 nm)7.208899 ppm 0.033270 0.46 1493.245954 7.208899
Sb (206.834 nm)-0.001599 u ppm 0.003157 > 100.00 0.051495 -0.001599 u
Se (196.026 nm)-0.000283 u ppm 0.001101 > 100.00 4.840640 -0.000283 u
Si (288.158 nm)5.581070 ppm 0.019691 0.35 41261.300000 5.581070
Sn (189.925 nm)-0.000683 u ppm 0.001225 > 100.00 1.821650 -0.000683 u
Sr (421.552 nm)0.439757 ppm 0.003540 0.81 97107.820080 0.439757
Th (288.505 nm)0.037824 ppm 0.004345 11.49 331.661000 0.037824
Ti (336.122 nm)-0.000357 u ppm 0.000072 20.10 -34.943800 -0.000357 u
Tl (190.794 nm)0.002534 ppm 0.000640 25.25 0.258133 0.002534
U (409.013 nm)0.013346 ppm 0.002674 20.03 82.809400 0.013346
V (292.401 nm)0.005257 ppm 0.000062 1.18 183.664000 0.005257
Zn (206.200 nm)0.002633 ppm 0.000547 20.77 9.840920 0.002633
Zr (343.823 nm)0.000154 ppm 0.000063 40.99 4.921070 0.000154
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 64 of 287
Page 935 of 1261
Solution Name: 280-184114-B-39-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-39-A 11/20/2023 3:46:15 PM 2:8 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010961 ppm 0.000035 0.32 28210.834742 0.010961
Ag (328.068 nm)0.000620 ppm 0.000192 30.97 0.583833 0.000620
Al (394.401 nm)0.025615 ppm 0.000964 3.76 761.931000 0.025615
Al H (396.152 nm)-0.000995 u ppm 0.002886 > 100.00 46.092700 -0.000995 u
As (188.980 nm)0.004406 ppm 0.004192 95.13 0.256617 0.004406
B (249.678 nm)0.123748 ppm 0.000695 0.56 1051.910000 0.123748
Ba (493.408 nm)0.576233 ppm 0.001115 0.19 87272.200000 0.576233
Be (234.861 nm)0.000100 ppm 0.000019 18.58 56.701100 0.000100
Bi (223.061 nm)-0.000338 u ppm 0.003309 > 100.00 3.582350 -0.000338 u
Ca (315.887 nm)56.496774 o ppm 0.096201 0.17 38078.490475 56.496774 o
Cd (214.439 nm)0.000329 ppm 0.000086 26.25 5.003350 0.000329
Co (228.615 nm)0.000007 u ppm 0.000262 > 100.00 42.985400 0.000007 u
Cr (205.560 nm)0.000549 ppm 0.000553 > 100.00 3.777510 0.000549
Cu (324.754 nm)0.002534 ppm 0.000317 12.50 852.818000 0.002534
Fe (238.204 nm)0.009659 ppm 0.000470 4.87 54.640400 0.009659
Fe H (259.940 nm)0.101335 u ppm 0.001567 1.55 25.313200 0.101335 u
K (766.491 nm)2.297390 ppm 0.037096 1.61 3680.200000 2.297390
Li (670.783 nm)0.009543 ppm 0.001120 11.74 -3925.700000 0.009543
Mg (279.078 nm)38.678700 ppm 0.191153 0.49 129377.000000 38.678700
Mn (257.610 nm)0.000392 ppm 0.000038 9.65 109.175000 0.000392
Mo (202.032 nm)0.002169 ppm 0.000630 29.04 14.238600 0.002169
Na (589.592 nm)108.436000 o ppm 0.582213 0.54 1325860.000000 108.436000 o
Na H (589.593 nm)98.498693 ppm 0.879853 0.89 958950.119832 98.498693
Ni (231.604 nm)-0.002188 u ppm 0.001228 56.11 -17.660300 -0.002188 u
P (213.618 nm)0.033564 ppm 0.001609 4.80 42.528300 0.033564
Pb (220.353 nm)0.000878 ppm 0.000649 73.92 0.402509 0.000878
S (181.972 nm)4.680287 ppm 0.017136 0.37 978.317553 4.680287
Sb (206.834 nm)-0.001895 u ppm 0.001483 78.24 -0.305296 -0.001895 u
Se (196.026 nm)0.001296 u ppm 0.004263 > 100.00 5.810220 0.001296 u
Si (288.158 nm)5.749860 ppm 0.037127 0.65 42487.600000 5.749860
Sn (189.925 nm)-0.000942 u ppm 0.001671 > 100.00 1.647960 -0.000942 u
Sr (421.552 nm)0.440741 ppm 0.000562 0.13 97325.029052 0.440741
Th (288.505 nm)0.038615 ppm 0.005911 15.31 333.171000 0.038615
Ti (336.122 nm)-0.000244 u ppm 0.000065 26.53 -21.172500 -0.000244 u
Tl (190.794 nm)0.001462 u ppm 0.002097 > 100.00 -0.904726 0.001462 u
U (409.013 nm)0.017856 ppm 0.002306 12.92 102.407000 0.017856
V (292.401 nm)0.005013 ppm 0.000011 0.22 171.774000 0.005013
Zn (206.200 nm)0.001030 ppm 0.000706 68.55 6.383340 0.001030
Zr (343.823 nm)0.000218 ppm 0.000095 43.41 10.119700 0.000218
Test Report
52A112023.esws
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Page 936 of 1261
Solution Name: 280-184114-B-40-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-40-A 11/20/2023 3:50:35 PM 2:9 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.011259 ppm 0.000041 0.36 28980.734570 0.011259
Ag (328.068 nm)0.000832 ppm 0.000047 5.62 12.836300 0.000832
Al (394.401 nm)0.024308 ppm 0.000862 3.55 740.139000 0.024308
Al H (396.152 nm)-0.002075 u ppm 0.002917 > 100.00 41.238300 -0.002075 u
As (188.980 nm)0.005373 ppm 0.001601 29.79 1.059370 0.005373
B (249.678 nm)0.126802 ppm 0.000586 0.46 1077.470000 0.126802
Ba (493.408 nm)0.534516 ppm 0.000817 0.15 80954.000000 0.534516
Be (234.861 nm)0.000107 ppm 0.000009 8.35 57.879200 0.000107
Bi (223.061 nm)-0.000305 u ppm 0.001743 > 100.00 3.631900 -0.000305 u
Ca (315.887 nm)53.138551 o ppm 0.082748 0.16 35813.640619 53.138551 o
Cd (214.439 nm)0.000388 ppm 0.000172 44.43 5.878490 0.000388
Co (228.615 nm)0.000126 u ppm 0.000373 > 100.00 45.248200 0.000126 u
Cr (205.560 nm)0.000521 ppm 0.000484 92.85 3.656310 0.000521
Cu (324.754 nm)0.010020 ppm 0.002860 28.54 1208.530000 0.010020
Fe (238.204 nm)0.010354 ppm 0.000931 8.99 57.377373 0.010354
Fe H (259.940 nm)0.097063 u ppm 0.001969 2.03 18.394900 0.097063 u
K (766.491 nm)2.368080 ppm 0.061658 2.60 3807.200000 2.368080
Li (670.783 nm)0.007985 ppm 0.001178 14.75 -3983.650000 0.007985
Mg (279.078 nm)39.622300 ppm 0.095994 0.24 132533.000000 39.622300
Mn (257.610 nm)0.000509 ppm 0.000176 34.70 140.164000 0.000509
Mo (202.032 nm)0.002130 ppm 0.000520 24.43 14.047000 0.002130
Na (589.592 nm)111.293000 o ppm 0.330861 0.30 1360100.000000 111.293000 o
Na H (589.593 nm)100.905272 ppm 0.243210 0.24 979655.692245 100.905272
Ni (231.604 nm)-0.001698 u ppm 0.000529 31.15 -15.991600 -0.001698 u
P (213.618 nm)0.032546 ppm 0.002043 6.28 40.931200 0.032546
Pb (220.353 nm)0.000006 u ppm 0.001064 > 100.00 -1.604050 0.000006 u
S (181.972 nm)4.760424 ppm 0.031294 0.66 994.565499 4.760424
Sb (206.834 nm)-0.000577 u ppm 0.002781 > 100.00 1.300240 -0.000577 u
Se (196.026 nm)-0.001226 u ppm 0.004854 > 100.00 4.262380 -0.001226 u
Si (288.158 nm)5.891590 ppm 0.013176 0.22 43517.500000 5.891590
Sn (189.925 nm)-0.001022 u ppm 0.001390 > 100.00 1.594410 -0.001022 u
Sr (421.552 nm)0.428861 ppm 0.000442 0.10 94702.047393 0.428861
Th (288.505 nm)0.038565 ppm 0.002466 6.39 333.091000 0.038565
Ti (336.122 nm)-0.000285 u ppm 0.000090 31.54 -33.006500 -0.000285 u
Tl (190.794 nm)0.001808 u ppm 0.002201 > 100.00 -0.529775 0.001808 u
U (409.013 nm)0.013208 ppm 0.001527 11.56 82.245600 0.013208
V (292.401 nm)0.004999 ppm 0.000232 4.63 173.066000 0.004999
Zn (206.200 nm)0.005134 ppm 0.003511 68.39 15.234000 0.005134
Zr (343.823 nm)0.000316 ppm 0.000089 28.16 18.132400 0.000316
Test Report
52A112023.esws
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Page 937 of 1261
Solution Name: 280-184114-B-41-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184114-B-41-A 11/20/2023 3:54:51 PM 2:10 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010956 ppm 0.000074 0.68 28171.974880 0.010956
Ag (328.068 nm)0.000539 ppm 0.000108 20.00 -2.016520 0.000539
Al (394.401 nm)0.022785 ppm 0.001214 5.33 718.049000 0.022785
Al H (396.152 nm)-0.000418 u ppm 0.001662 > 100.00 48.684500 -0.000418 u
As (188.980 nm)0.003259 ppm 0.000855 26.23 -0.696461 0.003259
B (249.678 nm)0.123176 ppm 0.000793 0.64 1047.120000 0.123176
Ba (493.408 nm)0.433115 ppm 0.001532 0.35 65596.400000 0.433115
Be (234.861 nm)0.000090 ppm 0.000019 21.48 55.069500 0.000090
Bi (223.061 nm)0.000034 u ppm 0.001686 > 100.00 4.136060 0.000034 u
Ca (315.887 nm)44.114038 o ppm 0.042799 0.10 29727.336651 44.114038 o
Cd (214.439 nm)0.000314 ppm 0.000081 25.71 4.767960 0.000314
Co (228.615 nm)-0.000007 u ppm 0.000142 > 100.00 42.713500 -0.000007 u
Cr (205.560 nm)0.000515 ppm 0.000419 81.42 3.631150 0.000515
Cu (324.754 nm)0.009063 ppm 0.000138 1.52 1171.900000 0.009063
Fe (238.204 nm)0.010983 ppm 0.001046 9.52 59.853174 0.010983
Fe H (259.940 nm)0.098624 u ppm 0.001488 1.51 20.922900 0.098624 u
K (766.491 nm)2.297140 ppm 0.017431 0.76 3679.750000 2.297140
Li (670.783 nm)0.006076 ppm 0.001701 28.00 -4054.640000 0.006076
Mg (279.078 nm)38.421900 ppm 0.293919 0.76 128517.000000 38.421900
Mn (257.610 nm)0.000386 ppm 0.000010 2.67 107.564000 0.000386
Mo (202.032 nm)0.002272 ppm 0.000536 23.59 14.752300 0.002272
Na (589.592 nm)108.381000 o ppm 0.428198 0.40 1323510.000000 108.381000 o
Na H (589.593 nm)97.896351 ppm 1.882110 1.92 952437.670066 97.896351
Ni (231.604 nm)-0.001504 u ppm 0.000234 15.58 -15.331600 -0.001504 u
P (213.618 nm)0.028662 ppm 0.004258 14.85 36.377000 0.028662
Pb (220.353 nm)0.000452 u ppm 0.001136 > 100.00 -0.583147 0.000452 u
S (181.972 nm)4.656703 ppm 0.039484 0.85 973.268384 4.656703
Sb (206.834 nm)-0.002055 u ppm 0.002013 97.96 -0.503080 -0.002055 u
Se (196.026 nm)0.000555 u ppm 0.003659 > 100.00 5.354930 0.000555 u
Si (288.158 nm)5.763410 ppm 0.038109 0.66 42585.700000 5.763410
Sn (189.925 nm)-0.002528 u ppm 0.000923 36.53 0.582350 -0.002528 u
Sr (421.552 nm)0.376277 ppm 0.001269 0.34 83091.428310 0.376277
Th (288.505 nm)0.036476 ppm 0.002829 7.76 329.154000 0.036476
Ti (336.122 nm)-0.000104 u ppm 0.000070 67.23 -32.962000 -0.000104 u
Tl (190.794 nm)0.000811 ppm 0.000610 75.26 -1.613070 0.000811
U (409.013 nm)0.012565 ppm 0.002251 17.91 79.593900 0.012565
V (292.401 nm)0.004883 ppm 0.000038 0.78 169.386000 0.004883
Zn (206.200 nm)0.001443 ppm 0.000091 6.29 7.274080 0.001443
Zr (343.823 nm)0.000180 ppm 0.000132 73.48 7.028160 0.000180
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 67 of 287
Page 938 of 1261
Solution Name: 280-184010-D-6-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-6-A 11/20/2023 3:59:09 PM 2:11 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000513 ppm 0.000009 1.74 780.252367 0.000513
Ag (328.068 nm)-0.000153 u ppm 0.000236 > 100.00 -37.982100 -0.000153 u
Al (394.401 nm)0.183994 ppm 0.002601 1.41 2714.410000 0.183994
Al H (396.152 nm)0.187281 u ppm 0.004379 2.34 892.242000 0.187281 u
As (188.980 nm)0.002006 ppm 0.003154 > 100.00 -1.765560 0.002006
B (249.678 nm)0.010225 ppm 0.000170 1.66 101.757000 0.010225
Ba (493.408 nm)0.014593 ppm 0.000169 1.16 2218.510000 0.014593
Be (234.861 nm)0.000049 ppm 0.000011 22.94 88.747200 0.000049
Bi (223.061 nm)-0.001741 u ppm 0.002254 > 100.00 1.496240 -0.001741 u
Ca (315.887 nm)1.004847 ppm 0.006522 0.65 653.675692 1.004847
Cd (214.439 nm)0.000180 ppm 0.000187 > 100.00 3.411660 0.000180
Co (228.615 nm)0.000400 ppm 0.000119 29.67 50.523400 0.000400
Cr (205.560 nm)0.000500 u ppm 0.000918 > 100.00 3.578770 0.000500 u
Cu (324.754 nm)0.002750 ppm 0.000144 5.25 897.502000 0.002750
Fe (238.204 nm)3.160515 ppm 0.018977 0.60 12457.683266 3.160515
Fe H (259.940 nm)3.156190 u ppm 0.026179 0.83 4973.470000 3.156190 u
K (766.491 nm)0.377653 ppm 0.063623 16.85 231.098000 0.377653
Li (670.783 nm)-0.002050 u ppm 0.002060 > 100.00 -4356.850000 -0.002050 u
Mg (279.078 nm)0.472378 ppm 0.002238 0.47 1586.830000 0.472378
Mn (257.610 nm)0.044479 ppm 0.000296 0.67 11872.400000 0.044479
Mo (202.032 nm)0.000451 ppm 0.000306 67.95 5.713770 0.000451
Na (589.592 nm)10.754000 ppm 0.075733 0.70 131928.000000 10.754000
Na H (589.593 nm)0.453213 u ppm 0.164019 36.19 95772.047252 0.453213 u
Ni (231.604 nm)0.001025 ppm 0.000864 84.36 -6.721900 0.001025
P (213.618 nm)0.011614 ppm 0.001059 9.12 16.681200 0.011614
Pb (220.353 nm)0.003539 ppm 0.001066 30.11 6.487840 0.003539
S (181.972 nm)1.029638 ppm 0.006962 0.68 233.932793 1.029638
Sb (206.834 nm)0.000848 u ppm 0.002103 > 100.00 3.257830 0.000848 u
Se (196.026 nm)0.000107 u ppm 0.003652 > 100.00 4.778540 0.000107 u
Si (288.158 nm)2.144690 ppm 0.016579 0.77 16294.000000 2.144690
Sn (189.925 nm)-0.001325 u ppm 0.001149 86.73 1.390320 -0.001325 u
Sr (421.552 nm)0.007306 ppm 0.000111 1.52 1622.919745 0.007306
Th (288.505 nm)0.007897 ppm 0.003721 47.12 276.050000 0.007897
Ti (336.122 nm)0.001116 ppm 0.000114 10.23 5.765430 0.001116
Tl (190.794 nm)0.000494 u ppm 0.001389 > 100.00 -2.009960 0.000494 u
U (409.013 nm)0.000309 u ppm 0.002210 > 100.00 27.922300 0.000309 u
V (292.401 nm)0.000752 ppm 0.000039 5.13 -7.771340 0.000752
Zn (206.200 nm)0.010934 ppm 0.000811 7.42 27.740300 0.010934
Zr (343.823 nm)0.000626 ppm 0.000016 2.51 47.671500 0.000626
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 68 of 287
Page 939 of 1261
Solution Name: 280-184010-D-7-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-7-A 11/20/2023 4:03:25 PM 2:12 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000346 ppm 0.000010 3.01 393.732818 0.000346
Ag (328.068 nm)-0.000008 u ppm 0.000123 > 100.00 -35.074900 -0.000008 u
Al (394.401 nm)0.718155 ppm 0.002986 0.42 9291.490000 0.718155
Al H (396.152 nm)0.747796 u ppm 0.002484 0.33 3411.310000 0.747796 u
As (188.980 nm)0.002278 ppm 0.000635 27.86 -1.591850 0.002278
B (249.678 nm)0.007657 ppm 0.000277 3.62 80.265700 0.007657
Ba (493.408 nm)0.007379 ppm 0.000249 3.38 1142.250000 0.007379
Be (234.861 nm)0.000039 ppm 0.000028 73.01 162.487000 0.000039
Bi (223.061 nm)-0.000278 u ppm 0.001555 > 100.00 3.671430 -0.000278 u
Ca (315.887 nm)0.446171 ppm 0.007169 1.61 276.893898 0.446171
Cd (214.439 nm)0.000083 u ppm 0.000208 > 100.00 3.160570 0.000083 u
Co (228.615 nm)0.000243 ppm 0.000199 81.76 47.709200 0.000243
Cr (205.560 nm)0.001888 ppm 0.000250 13.25 9.289340 0.001888
Cu (324.754 nm)0.440988 ppm 0.002279 0.52 21348.000000 0.440988
Fe (238.204 nm)9.008183 o ppm 0.029215 0.32 35476.496174 9.008183 o
Fe H (259.940 nm)8.824430 ppm 0.028220 0.32 14154.700000 8.824430
K (766.491 nm)0.490378 ppm 0.012291 2.51 433.627000 0.490378
Li (670.783 nm)-0.002909 u ppm 0.001623 55.77 -4388.790000 -0.002909 u
Mg (279.078 nm)0.251453 ppm 0.001061 0.42 844.567000 0.251453
Mn (257.610 nm)0.021006 ppm 0.000085 0.40 5609.420000 0.021006
Mo (202.032 nm)0.000445 ppm 0.000212 47.71 5.685150 0.000445
Na (589.592 nm)2.005480 ppm 0.015723 0.78 25504.200000 2.005480
Na H (589.593 nm)-8.082453 u ppm 0.015949 0.20 20987.071556 -8.082453 u
Ni (231.604 nm)0.001054 ppm 0.000291 27.59 -6.619760 0.001054
P (213.618 nm)0.039706 ppm 0.000586 1.48 26.958500 0.039706
Pb (220.353 nm)2.008010 ppm 0.007628 0.38 4613.630000 2.008010
S (181.972 nm)0.659654 ppm 0.010533 1.60 158.770587 0.659654
Sb (206.834 nm)0.007935 ppm 0.001588 20.01 12.292100 0.007935
Se (196.026 nm)-0.002150 u ppm 0.003294 > 100.00 2.764610 -0.002150 u
Si (288.158 nm)0.265867 ppm 0.000631 0.24 2644.640000 0.265867
Sn (189.925 nm)0.000229 u ppm 0.001972 > 100.00 2.434880 0.000229 u
Sr (421.552 nm)0.003288 ppm 0.000048 1.46 735.737129 0.003288
Th (288.505 nm)0.008936 ppm 0.001518 16.99 277.104000 0.008936
Ti (336.122 nm)0.005997 ppm 0.000138 2.29 537.228000 0.005997
Tl (190.794 nm)0.001603 ppm 0.000735 45.86 -0.918799 0.001603
U (409.013 nm)-0.003155 u ppm 0.003304 > 100.00 18.133600 -0.003155 u
V (292.401 nm)0.005929 ppm 0.000140 2.37 208.004000 0.005929
Zn (206.200 nm)0.036632 ppm 0.000602 1.64 83.154300 0.036632
Zr (343.823 nm)0.000752 ppm 0.000017 2.24 65.836400 0.000752
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 69 of 287
Page 940 of 1261
Solution Name: 280-184010-D-8-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-8-A 11/20/2023 4:07:48 PM 2:13 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000481 ppm 0.000003 0.72 667.585398 0.000481
Ag (328.068 nm)0.000037 u ppm 0.000157 > 100.00 -28.058600 0.000037 u
Al (394.401 nm)0.320412 ppm 0.001106 0.35 4394.170000 0.320412
Al H (396.152 nm)0.332715 u ppm 0.004091 1.23 1545.860000 0.332715 u
As (188.980 nm)0.001992 u ppm 0.002046 > 100.00 -1.760020 0.001992 u
B (249.678 nm)0.007028 ppm 0.000491 6.98 75.000100 0.007028
Ba (493.408 nm)0.007186 ppm 0.000052 0.72 1091.080000 0.007186
Be (234.861 nm)0.000026 ppm 0.000013 48.42 59.150600 0.000026
Bi (223.061 nm)-0.001030 u ppm 0.002633 > 100.00 2.554390 -0.001030 u
Ca (315.887 nm)0.280314 ppm 0.006228 2.22 165.036292 0.280314
Cd (214.439 nm)0.000048 u ppm 0.000140 > 100.00 1.038530 0.000048 u
Co (228.615 nm)0.000123 u ppm 0.000207 > 100.00 45.260100 0.000123 u
Cr (205.560 nm)0.000799 ppm 0.000209 26.11 4.807880 0.000799
Cu (324.754 nm)0.051266 ppm 0.000106 0.21 3158.310000 0.051266
Fe (238.204 nm)1.161436 ppm 0.010697 0.92 4588.490419 1.161436
Fe H (259.940 nm)1.225170 u ppm 0.009556 0.78 1845.660000 1.225170 u
K (766.491 nm)0.002546 u ppm 0.025066 > 100.00 -442.839000 0.002546 u
Li (670.783 nm)-0.002728 u ppm 0.000227 8.32 -4382.060000 -0.002728 u
Mg (279.078 nm)0.130393 ppm 0.000939 0.72 444.277000 0.130393
Mn (257.610 nm)0.011928 ppm 0.000045 0.37 3187.130000 0.011928
Mo (202.032 nm)0.000217 u ppm 0.000817 > 100.00 4.556310 0.000217 u
Na (589.592 nm)1.736950 ppm 0.011904 0.69 22236.800000 1.736950
Na H (589.593 nm)-8.381194 u ppm 0.007414 0.09 18369.369324 -8.381194 u
Ni (231.604 nm)0.001391 ppm 0.000574 41.30 -5.474420 0.001391
P (213.618 nm)0.007026 ppm 0.001641 23.36 8.734300 0.007026
Pb (220.353 nm)0.119239 ppm 0.001067 0.89 272.407000 0.119239
S (181.972 nm)0.220647 ppm 0.008066 3.66 69.067274 0.220647
Sb (206.834 nm)0.002050 ppm 0.001054 51.42 4.583490 0.002050
Se (196.026 nm)0.002866 u ppm 0.005964 > 100.00 6.660220 0.002866 u
Si (288.158 nm)1.274630 ppm 0.003571 0.28 9972.970000 1.274630
Sn (189.925 nm)-0.000452 u ppm 0.000828 > 100.00 1.977170 -0.000452 u
Sr (421.552 nm)0.002396 ppm 0.000102 4.25 538.761183 0.002396
Th (288.505 nm)0.003409 ppm 0.001190 34.92 267.089000 0.003409
Ti (336.122 nm)0.002255 ppm 0.000025 1.11 128.549000 0.002255
Tl (190.794 nm)0.001219 ppm 0.000990 81.21 -1.188690 0.001219
U (409.013 nm)-0.000169 u ppm 0.002816 > 100.00 23.832200 -0.000169 u
V (292.401 nm)0.001403 ppm 0.000185 13.20 19.116800 0.001403
Zn (206.200 nm)0.022278 ppm 0.000191 0.86 52.201800 0.022278
Zr (343.823 nm)0.000378 ppm 0.000098 26.02 24.729500 0.000378
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 70 of 287
Page 941 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 4:12:10 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000234 u ppm 0.000005 2.19 332.111859 -0.000234 u
Ag (328.068 nm)-0.000686 u ppm 0.000193 28.11 76.193900 -0.000686 u
Al (394.401 nm)51.881800 o ppm 0.131832 0.25 637817.000000 51.881800 o
Al H (396.152 nm)48.926600 ppm 0.175009 0.36 219937.000000 48.926600
As (188.980 nm)0.003460 ppm 0.002750 79.49 -0.978300 0.003460
B (249.678 nm)-0.003139 u ppm 0.000556 17.72 -10.087800 -0.003139 u
Ba (493.408 nm)0.000266 ppm 0.000161 60.47 180.969000 0.000266
Be (234.861 nm)0.000178 ppm 0.000026 14.47 717.552000 0.000178
Bi (223.061 nm)-0.000564 u ppm 0.001267 > 100.00 3.247060 -0.000564 u
Ca (315.887 nm)-0.030410 u ppm 0.001259 4.14 -44.521951 -0.030410 u
Cd (214.439 nm)-0.000014 u ppm 0.000111 > 100.00 10.146700 -0.000014 u
Co (228.615 nm)0.000352 ppm 0.000061 17.42 49.577100 0.000352
Cr (205.560 nm)0.000953 ppm 0.000609 63.86 5.443700 0.000953
Cu (324.754 nm)-0.001464 u ppm 0.000079 5.37 1639.640000 -0.001464 u
Fe (238.204 nm)50.258303 o ppm 0.150207 0.30 197853.840175 50.258303 o
Fe H (259.940 nm)48.898200 ppm 0.132251 0.27 79065.000000 48.898200
K (766.491 nm)0.050883 ppm 0.018389 36.14 -355.994000 0.050883
Li (670.783 nm)-0.001064 u ppm 0.000186 17.49 -4320.180000 -0.001064 u
Mg (279.078 nm)-0.001061 u ppm 0.001031 97.16 -183.966000 -0.001061 u
Mn (257.610 nm)-0.000922 u ppm 0.000018 1.91 -241.466000 -0.000922 u
Mo (202.032 nm)-0.000144 u ppm 0.000253 > 100.00 2.765040 -0.000144 u
Na (589.592 nm)250.349000 o ppm 0.923857 0.37 3044080.000000 250.349000 o
Na H (589.593 nm)241.314453 ppm 3.889030 1.61 2204191.001150 241.314453
Ni (231.604 nm)0.000365 u ppm 0.001085 > 100.00 -8.968660 0.000365 u
P (213.618 nm)4.943300 ppm 0.026833 0.54 5838.170000 4.943300
Pb (220.353 nm)0.000246 u ppm 0.001867 > 100.00 -2.594950 0.000246 u
S (181.972 nm)4.828509 ppm 0.025765 0.53 1009.292597 4.828509
Sb (206.834 nm)-0.000492 u ppm 0.001791 > 100.00 4.882060 -0.000492 u
Se (196.026 nm)0.004470 ppm 0.003955 88.47 2.486280 0.004470
Si (288.158 nm)0.026970 ppm 0.002640 9.79 908.012000 0.026970
Sn (189.925 nm)0.000823 u ppm 0.002437 > 100.00 2.833700 0.000823 u
Sr (421.552 nm)0.000557 ppm 0.000051 9.13 132.710325 0.000557
Th (288.505 nm)4.818430 ppm 0.018497 0.38 9264.930000 4.818430
Ti (336.122 nm)0.000736 ppm 0.000074 10.05 -37.819700 0.000736
Tl (190.794 nm)-0.003353 u ppm 0.001590 47.42 -7.032120 -0.003353 u
U (409.013 nm)2.456680 Q ppm 0.003285 0.13 10970.600000 Q 2.456680 Q
V (292.401 nm)0.000295 ppm 0.000112 38.02 254.274000 0.000295
Zn (206.200 nm)0.000697 ppm 0.000419 60.12 5.665770 0.000697
Zr (343.823 nm)-0.000846 u ppm 0.000046 5.39 -8.607590 -0.000846 u
Test Report
52A112023.esws
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Page 942 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 4:16:35 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.460825 ppm 0.001044 0.23 1181638.603419 0.460825
Ag (328.068 nm)0.502853 ppm 0.006288 1.25 26853.800000 0.502853
Al (394.401 nm)0.496094 ppm 0.001574 0.32 6559.160000 0.496094
Al H (396.152 nm)0.504680 u ppm 0.001772 0.35 2318.700000 0.504680 u
As (188.980 nm)0.503490 ppm 0.001465 0.29 414.911000 0.503490
B (249.678 nm)0.498802 ppm 0.000724 0.15 4190.990000 0.498802
Ba (493.408 nm)0.502300 ppm 0.002820 0.56 76081.800000 0.502300
Be (234.861 nm)0.502132 ppm 0.004900 0.98 83965.500000 0.502132
Bi (223.061 nm)1.000990 ppm 0.000849 0.08 1492.340000 1.000990
Ca (315.887 nm)5.025734 ppm 0.019161 0.38 3365.438270 5.025734
Cd (214.439 nm)0.510700 ppm 0.002935 0.57 7633.970000 0.510700
Co (228.615 nm)0.508836 ppm 0.002066 0.41 9766.010000 0.508836
Cr (205.560 nm)0.511545 ppm 0.001022 0.20 2104.090000 0.511545
Cu (324.754 nm)0.505266 ppm 0.001577 0.31 24330.600000 0.505266
Fe (238.204 nm)2.520420 ppm 0.010821 0.43 9944.361091 2.520420
Fe H (259.940 nm)2.548090 u ppm 0.003985 0.16 3988.490000 2.548090 u
K (766.491 nm)50.816100 ppm 0.143276 0.28 90851.400000 50.816100
Li (670.783 nm)0.495777 ppm 0.000579 0.12 14157.100000 0.495777
Mg (279.078 nm)20.196200 ppm 0.075491 0.37 67558.100000 20.196200
Mn (257.610 nm)0.502737 ppm 0.001641 0.33 134145.000000 0.502737
Mo (202.032 nm)0.505902 ppm 0.002221 0.44 2513.800000 0.505902
Na (589.592 nm)25.226900 ppm 0.075686 0.30 313573.000000 25.226900
Na H (589.593 nm)15.026357 u ppm 0.153016 1.02 227577.071877 15.026357 u
Ni (231.604 nm)0.513035 ppm 0.002179 0.42 1737.110000 0.513035
P (213.618 nm)0.003628 ppm 0.001810 49.90 -33.357600 0.003628
Pb (220.353 nm)0.522248 ppm 0.001834 0.35 1196.510000 0.522248
S (181.972 nm)-0.025031 u ppm 0.007745 30.94 21.456891 -0.025031 u
Sb (206.834 nm)0.500567 ppm 0.004008 0.80 611.567000 0.500567
Se (196.026 nm)0.502027 ppm 0.004187 0.83 313.161000 0.502027
Si (288.158 nm)4.998510 ppm 0.013523 0.27 37274.100000 4.998510
Sn (189.925 nm)0.505107 ppm 0.001919 0.38 341.706000 0.505107
Sr (421.552 nm)0.503009 ppm 0.002245 0.45 111073.716110 0.503009
Th (288.505 nm)0.037253 ppm 0.001551 4.16 318.238000 0.037253
Ti (336.122 nm)0.502727 ppm 0.001302 0.26 54750.000000 0.502727
Tl (190.794 nm)0.508377 ppm 0.004430 0.87 548.393000 0.508377
U (409.013 nm)-0.005232 u ppm 0.003475 66.41 -13.005800 -0.005232 u
V (292.401 nm)0.504348 ppm 0.001470 0.29 20959.900000 0.504348
Zn (206.200 nm)0.512843 ppm 0.001951 0.38 1110.040000 0.512843
Zr (343.823 nm)0.497229 ppm 0.001907 0.38 40529.600000 0.497229
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 72 of 287
Page 943 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 4:20:56 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000215 ppm 0.000006 2.79 -41.249753 0.000215
Ag (328.068 nm)0.000038 u ppm 0.000180 > 100.00 -27.205100 0.000038 u
Al (394.401 nm)0.001176 ppm 0.000646 54.95 464.632000 0.001176
Al H (396.152 nm)0.001420 u ppm 0.004999 > 100.00 56.947900 0.001420 u
As (188.980 nm)0.002881 ppm 0.002538 88.08 -1.010720 0.002881
B (249.678 nm)-0.000185 u ppm 0.000375 > 100.00 14.629900 -0.000185 u
Ba (493.408 nm)0.000194 ppm 0.000278 > 100.00 28.779100 0.000194
Be (234.861 nm)0.000015 u ppm 0.000041 > 100.00 42.413400 0.000015 u
Bi (223.061 nm)0.000456 u ppm 0.001824 > 100.00 4.762320 0.000456 u
Ca (315.887 nm)0.001928 u ppm 0.004917 > 100.00 -22.712411 0.001928 u
Cd (214.439 nm)0.000093 u ppm 0.000132 > 100.00 1.472890 0.000093 u
Co (228.615 nm)-0.000166 u ppm 0.000187 > 100.00 39.682900 -0.000166 u
Cr (205.560 nm)-0.000043 u ppm 0.000183 > 100.00 1.344520 -0.000043 u
Cu (324.754 nm)0.000264 ppm 0.000094 35.67 778.366000 0.000264
Fe (238.204 nm)0.000908 ppm 0.000973 > 100.00 20.179271 0.000908
Fe H (259.940 nm)0.093712 u ppm 0.001253 1.34 12.965500 0.093712 u
K (766.491 nm)0.000356 u ppm 0.018922 > 100.00 -446.773000 0.000356 u
Li (670.783 nm)-0.001433 Su ppm 0.000624 43.55 -4333.900000 S -0.001433 Su
Mg (279.078 nm)0.001151 u ppm 0.001475 > 100.00 12.738700 0.001151 u
Mn (257.610 nm)-0.000019 u ppm 0.000028 > 100.00 -0.545796 -0.000019 u
Mo (202.032 nm)0.001341 ppm 0.000236 17.62 10.132800 0.001341
Na (589.592 nm)0.113168 ppm 0.007255 6.41 2413.550000 0.113168
Na H (589.593 nm)-10.001507 u ppm 0.017986 0.18 4121.354594 -10.001507 u
Ni (231.604 nm)-0.000383 u ppm 0.000933 > 100.00 -11.514900 -0.000383 u
P (213.618 nm)-0.000252 u ppm 0.003235 > 100.00 2.763030 -0.000252 u
Pb (220.353 nm)-0.000367 u ppm 0.000899 > 100.00 -2.469420 -0.000367 u
S (181.972 nm)-0.039560 u ppm 0.001924 4.86 16.014374 -0.039560 u
Sb (206.834 nm)-0.000391 u ppm 0.001345 > 100.00 1.522960 -0.000391 u
Se (196.026 nm)-0.000488 u ppm 0.004915 > 100.00 4.715940 -0.000488 u
Si (288.158 nm)0.001966 ppm 0.000696 35.42 725.093000 0.001966
Sn (189.925 nm)-0.003218 u ppm 0.001606 49.89 0.118194 -0.003218 u
Sr (421.552 nm)0.000107 ppm 0.000029 27.07 33.225335 0.000107
Th (288.505 nm)0.006869 ppm 0.001680 24.45 273.362000 0.006869
Ti (336.122 nm)0.000009 u ppm 0.000038 > 100.00 -117.051000 0.000009 u
Tl (190.794 nm)0.001481 u ppm 0.002538 > 100.00 -0.883495 0.001481 u
U (409.013 nm)0.000230 u ppm 0.000788 > 100.00 24.507300 0.000230 u
V (292.401 nm)-0.000100 u ppm 0.000047 47.37 -43.273000 -0.000100 u
Zn (206.200 nm)-0.001650 u ppm 0.000284 17.22 0.605709 -0.001650 u
Zr (343.823 nm)0.000036 u ppm 0.000089 > 100.00 -4.751850 0.000036 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 73 of 287
Page 944 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 4:24:57 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014278 ppm 0.000015 0.11 36115.280437 0.014278
Ag (328.068 nm)0.009577 ppm 0.000103 1.08 480.444000 0.009577
Al (394.401 nm)0.089636 ppm 0.000719 0.80 1563.280000 0.089636
Al H (396.152 nm)0.092639 u ppm 0.001066 1.15 466.903000 0.092639 u
As (188.980 nm)0.017763 ppm 0.001735 9.77 11.353800 0.017763
B (249.678 nm)0.095032 ppm 0.000351 0.37 811.562000 0.095032
Ba (493.408 nm)0.009745 ppm 0.000308 3.16 1475.560000 0.009745
Be (234.861 nm)0.000977 ppm 0.000008 0.82 204.362000 0.000977
Bi (223.061 nm)-0.001588 Qu ppm 0.000383 24.09 1.724630 Q -0.001588 Qu
Ca (315.887 nm)0.207226 ppm 0.007806 3.77 115.744798 0.207226
Cd (214.439 nm)0.005078 ppm 0.000213 4.19 75.995000 0.005078
Co (228.615 nm)0.010122 ppm 0.000127 1.25 236.223000 0.010122
Cr (205.560 nm)0.009342 ppm 0.000204 2.19 39.855400 0.009342
Cu (324.754 nm)0.014532 ppm 0.000041 0.28 1437.530000 0.014532
Fe (238.204 nm)0.100706 ppm 0.000528 0.52 413.089704 0.100706
Fe H (259.940 nm)0.188930 u ppm 0.003157 1.67 167.198000 0.188930 u
K (766.491 nm)2.964240 ppm 0.054368 1.83 4878.290000 2.964240
Li (670.783 nm)0.017016 ppm 0.001036 6.09 -3647.770000 0.017016
Mg (279.078 nm)0.197580 ppm 0.000691 0.35 669.085000 0.197580
Mn (257.610 nm)0.010132 ppm 0.000008 0.08 2707.830000 0.010132
Mo (202.032 nm)0.019825 ppm 0.000383 1.93 101.850000 0.019825
Na (589.592 nm)1.125230 ppm 0.006434 0.57 14830.800000 1.125230
Na H (589.593 nm)-9.038301 u ppm 0.009266 0.10 12638.788359 -9.038301 u
Ni (231.604 nm)0.040038 ppm 0.001552 3.88 126.133000 0.040038
P (213.618 nm)2.791470 ppm 0.005228 0.19 3297.400000 2.791470
Pb (220.353 nm)0.008963 ppm 0.001152 12.86 19.003900 0.008963
S (181.972 nm)0.056182 Q ppm 0.008044 14.32 35.582388 Q 0.056182 Q
Sb (206.834 nm)0.018842 ppm 0.001157 6.14 24.883900 0.018842
Se (196.026 nm)0.023242 ppm 0.004472 19.24 19.274000 0.023242
Si (288.158 nm)0.467787 ppm 0.005160 1.10 4140.170000 0.467787
Sn (189.925 nm)0.096835 ppm 0.002720 2.81 67.352600 0.096835
Sr (421.552 nm)0.009578 ppm 0.000124 1.30 2124.577670 0.009578
Th (288.505 nm)0.007594 Q ppm 0.001669 21.98 274.818000 Q 0.007594 Q
Ti (336.122 nm)0.009716 ppm 0.000048 0.49 942.562000 0.009716
Tl (190.794 nm)0.015330 ppm 0.000738 4.81 14.112300 0.015330
U (409.013 nm)0.055389 ppm 0.000666 1.20 267.075000 0.055389
V (292.401 nm)0.009596 ppm 0.000212 2.21 355.660000 0.009596
Zn (206.200 nm)0.020246 ppm 0.000694 3.43 47.820700 0.020246
Zr (343.823 nm)0.009820 ppm 0.000038 0.38 792.996000 0.009820
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 74 of 287
Page 945 of 1261
Solution Name: 280-184010-D-9-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-9-A 11/20/2023 4:29:18 PM 2:14 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000478 ppm 0.000010 2.00 687.196703 0.000478
Ag (328.068 nm)0.000047 u ppm 0.000074 > 100.00 -26.861300 0.000047 u
Al (394.401 nm)0.111574 ppm 0.001015 0.91 1822.820000 0.111574
Al H (396.152 nm)0.113805 u ppm 0.003814 3.35 562.025000 0.113805 u
As (188.980 nm)0.002098 u ppm 0.002889 > 100.00 -1.723280 0.002098 u
B (249.678 nm)0.008768 ppm 0.000265 3.02 89.566700 0.008768
Ba (493.408 nm)0.014856 ppm 0.000343 2.31 2268.990000 0.014856
Be (234.861 nm)0.000033 ppm 0.000025 76.20 134.963000 0.000033
Bi (223.061 nm)-0.003165 u ppm 0.000174 5.49 -0.619892 -0.003165 u
Ca (315.887 nm)0.870736 ppm 0.005645 0.65 563.228424 0.870736
Cd (214.439 nm)0.000121 u ppm 0.000238 > 100.00 3.313570 0.000121 u
Co (228.615 nm)0.000059 u ppm 0.000180 > 100.00 44.018000 0.000059 u
Cr (205.560 nm)0.000713 ppm 0.000258 36.16 4.453680 0.000713
Cu (324.754 nm)0.011425 ppm 0.000103 0.90 1307.270000 0.011425
Fe (238.204 nm)6.946673 o ppm 0.028065 0.40 27361.548695 6.946673 o
Fe H (259.940 nm)6.827880 ppm 0.029017 0.42 10920.800000 6.827880
K (766.491 nm)0.389949 ppm 0.026575 6.81 253.190000 0.389949
Li (670.783 nm)0.000711 u ppm 0.001476 > 100.00 -4254.160000 0.000711 u
Mg (279.078 nm)0.403616 ppm 0.002851 0.71 1354.380000 0.403616
Mn (257.610 nm)0.030669 ppm 0.000209 0.68 8187.520000 0.030669
Mo (202.032 nm)0.000613 ppm 0.000217 35.33 6.518690 0.000613
Na (589.592 nm)5.500830 ppm 0.023154 0.42 68078.900000 5.500830
Na H (589.593 nm)-4.163997 u ppm 0.240742 5.78 55355.034569 -4.163997 u
Ni (231.604 nm)0.000304 u ppm 0.000602 > 100.00 -9.174690 0.000304 u
P (213.618 nm)0.013048 ppm 0.000563 4.32 17.930600 0.013048
Pb (220.353 nm)0.028782 ppm 0.000895 3.11 64.515200 0.028782
S (181.972 nm)0.635961 ppm 0.008914 1.40 153.890876 0.635961
Sb (206.834 nm)0.000780 u ppm 0.001088 > 100.00 3.435200 0.000780 u
Se (196.026 nm)0.000596 u ppm 0.004460 > 100.00 4.672660 0.000596 u
Si (288.158 nm)1.863090 ppm 0.008789 0.47 14247.900000 1.863090
Sn (189.925 nm)-0.001713 u ppm 0.000847 49.42 1.129650 -0.001713 u
Sr (421.552 nm)0.006387 ppm 0.000098 1.53 1419.828258 0.006387
Th (288.505 nm)0.006333 ppm 0.003949 62.35 272.770000 0.006333
Ti (336.122 nm)0.001189 ppm 0.000059 4.99 13.442600 0.001189
Tl (190.794 nm)0.000323 u ppm 0.000637 > 100.00 -2.265780 0.000323 u
U (409.013 nm)-0.001444 u ppm 0.003323 > 100.00 23.923700 -0.001444 u
V (292.401 nm)0.000815 ppm 0.000084 10.26 -4.977950 0.000815
Zn (206.200 nm)0.004905 ppm 0.000389 7.94 14.739300 0.004905
Zr (343.823 nm)0.000547 ppm 0.000067 12.27 46.316900 0.000547
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 75 of 287
Page 946 of 1261
Solution Name: 280-184010-D-10-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-10-A 11/20/2023 4:37:14 PM 2:15 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000476 ppm 0.000002 0.48 726.937544 0.000476
Ag (328.068 nm)0.000104 u ppm 0.000169 > 100.00 -26.394900 0.000104 u
Al (394.401 nm)0.530718 ppm 0.000474 0.09 6985.400000 0.530718
Al H (396.152 nm)0.548246 u ppm 0.002247 0.41 2514.500000 0.548246 u
As (188.980 nm)0.004886 ppm 0.003064 62.71 0.445455 0.004886
B (249.678 nm)0.007121 ppm 0.000096 1.35 75.785000 0.007121
Ba (493.408 nm)0.017947 ppm 0.000253 1.41 2783.440000 0.017947
Be (234.861 nm)0.000084 ppm 0.000077 92.32 356.273000 0.000084
Bi (223.061 nm)-0.001180 u ppm 0.001527 > 100.00 2.330170 -0.001180 u
Ca (315.887 nm)0.763462 ppm 0.012192 1.60 490.880738 0.763462
Cd (214.439 nm)0.000077 u ppm 0.000202 > 100.00 6.027130 0.000077 u
Co (228.615 nm)0.000381 ppm 0.000041 10.76 50.240300 0.000381
Cr (205.560 nm)0.001567 ppm 0.000541 34.53 7.967600 0.001567
Cu (324.754 nm)0.049622 ppm 0.000198 0.40 3105.770000 0.049622
Fe (238.204 nm)23.457906 o ppm 0.100779 0.43 92356.514756 23.457906 o
Fe H (259.940 nm)22.975700 ppm 0.088716 0.39 37076.500000 22.975700
K (766.491 nm)0.484650 ppm 0.012227 2.52 423.336000 0.484650
Li (670.783 nm)0.000946 ppm 0.000256 27.10 -4245.420000 0.000946
Mg (279.078 nm)0.367271 ppm 0.001668 0.45 1222.630000 0.367271
Mn (257.610 nm)0.030405 ppm 0.000077 0.25 8117.090000 0.030405
Mo (202.032 nm)0.000501 ppm 0.000381 76.14 5.962050 0.000501
Na (589.592 nm)3.392370 ppm 0.020615 0.61 42489.200000 3.392370
Na H (589.593 nm)-6.735909 u ppm 0.102080 1.52 32868.831963 -6.735909 u
Ni (231.604 nm)0.000857 ppm 0.000279 32.61 -7.293370 0.000857
P (213.618 nm)0.023307 ppm 0.002249 9.65 28.071600 0.023307
Pb (220.353 nm)0.193460 ppm 0.000597 0.31 442.974000 0.193460
S (181.972 nm)0.796826 ppm 0.005324 0.67 187.272817 0.796826
Sb (206.834 nm)0.001174 u ppm 0.006058 > 100.00 5.055060 0.001174 u
Se (196.026 nm)-0.001615 u ppm 0.001988 > 100.00 1.583590 -0.001615 u
Si (288.158 nm)2.205670 ppm 0.005586 0.25 16737.600000 2.205670
Sn (189.925 nm)-0.000972 u ppm 0.001172 > 100.00 1.628000 -0.000972 u
Sr (421.552 nm)0.006777 ppm 0.000066 0.98 1506.043753 0.006777
Th (288.505 nm)0.011385 ppm 0.002074 18.22 281.621000 0.011385
Ti (336.122 nm)0.003627 ppm 0.000093 2.55 279.275000 0.003627
Tl (190.794 nm)0.000716 u ppm 0.000862 > 100.00 -2.138910 0.000716 u
U (409.013 nm)0.000187 u ppm 0.002746 > 100.00 46.963700 0.000187 u
V (292.401 nm)0.002990 ppm 0.000046 1.54 84.489700 0.002990
Zn (206.200 nm)0.014151 ppm 0.000276 1.95 34.676700 0.014151
Zr (343.823 nm)0.001123 ppm 0.000101 8.95 115.678000 0.001123
Test Report
52A112023.esws
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Page 947 of 1261
Solution Name: 280-184010-D-11-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-11-A 11/20/2023 4:41:34 PM 2:16 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000517 ppm 0.000007 1.44 783.040934 0.000517
Ag (328.068 nm)-0.000145 u ppm 0.000292 > 100.00 -37.078100 -0.000145 u
Al (394.401 nm)0.162906 ppm 0.000579 0.36 2454.750000 0.162906
Al H (396.152 nm)0.169268 u ppm 0.002145 1.27 811.288000 0.169268 u
As (188.980 nm)0.000847 u ppm 0.001420 > 100.00 -2.706170 0.000847 u
B (249.678 nm)0.010202 ppm 0.000152 1.49 101.569000 0.010202
Ba (493.408 nm)0.025841 ppm 0.000120 0.46 3914.920000 0.025841
Be (234.861 nm)0.000036 ppm 0.000029 80.18 54.251500 0.000036
Bi (223.061 nm)-0.000549 u ppm 0.001970 > 100.00 3.268300 -0.000549 u
Ca (315.887 nm)1.072113 ppm 0.004706 0.44 699.040578 1.072113
Cd (214.439 nm)0.000195 ppm 0.000101 51.88 3.125390 0.000195
Co (228.615 nm)0.000363 ppm 0.000313 86.17 49.796100 0.000363
Cr (205.560 nm)0.001700 ppm 0.000426 25.06 8.514020 0.001700
Cu (324.754 nm)0.030543 ppm 0.000404 1.32 2191.330000 0.030543
Fe (238.204 nm)0.650412 ppm 0.001914 0.29 2576.895868 0.650412
Fe H (259.940 nm)0.721753 u ppm 0.001034 0.14 1030.250000 0.721753 u
K (766.491 nm)0.028947 u ppm 0.042870 > 100.00 -395.404000 0.028947 u
Li (670.783 nm)0.000669 u ppm 0.001685 > 100.00 -4255.730000 0.000669 u
Mg (279.078 nm)0.481435 ppm 0.002383 0.50 1618.620000 0.481435
Mn (257.610 nm)0.079163 ppm 0.000361 0.46 21126.700000 0.079163
Mo (202.032 nm)0.000505 ppm 0.000586 > 100.00 5.985690 0.000505
Na (589.592 nm)1.315460 ppm 0.007416 0.56 17332.600000 1.315460
Na H (589.593 nm)-8.865064 u ppm 0.009722 0.11 14295.342557 -8.865064 u
Ni (231.604 nm)0.001034 ppm 0.000545 52.66 -6.689830 0.001034
P (213.618 nm)0.021799 ppm 0.001256 5.76 27.236300 0.021799
Pb (220.353 nm)0.028436 ppm 0.002085 7.33 63.719500 0.028436
S (181.972 nm)1.720337 ppm 0.018995 1.10 374.542125 1.720337
Sb (206.834 nm)-0.000143 u ppm 0.002952 > 100.00 1.881570 -0.000143 u
Se (196.026 nm)0.003090 ppm 0.002198 71.13 6.895940 0.003090
Si (288.158 nm)0.122206 ppm 0.000450 0.37 1599.250000 0.122206
Sn (189.925 nm)-0.001615 u ppm 0.001471 91.04 1.195340 -0.001615 u
Sr (421.552 nm)0.007145 ppm 0.000042 0.59 1587.222308 0.007145
Th (288.505 nm)0.009205 ppm 0.000428 4.65 279.324000 0.009205
Ti (336.122 nm)0.000829 ppm 0.000020 2.36 -25.343800 0.000829
Tl (190.794 nm)0.000317 u ppm 0.000688 > 100.00 -2.157180 0.000317 u
U (409.013 nm)0.002128 u ppm 0.004165 > 100.00 33.528000 0.002128 u
V (292.401 nm)0.000597 ppm 0.000126 21.18 -14.471000 0.000597
Zn (206.200 nm)0.044065 ppm 0.001242 2.82 99.182600 0.044065
Zr (343.823 nm)0.000226 ppm 0.000115 50.73 11.633100 0.000226
Test Report
52A112023.esws
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Page 948 of 1261
Solution Name: 280-184010-D-12-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-12-A 11/20/2023 4:45:56 PM 2:17 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000561 ppm 0.000018 3.21 883.851014 0.000561
Ag (328.068 nm)-0.000040 u ppm 0.000069 > 100.00 -31.006900 -0.000040 u
Al (394.401 nm)0.140023 ppm 0.000376 0.27 2172.700000 0.140023
Al H (396.152 nm)0.145413 u ppm 0.005949 4.09 704.078000 0.145413 u
As (188.980 nm)0.002544 ppm 0.000696 27.35 -1.294650 0.002544
B (249.678 nm)0.007408 ppm 0.000607 8.19 78.184300 0.007408
Ba (493.408 nm)0.018552 ppm 0.000152 0.82 2810.380000 0.018552
Be (234.861 nm)0.000033 ppm 0.000005 15.29 50.845600 0.000033
Bi (223.061 nm)-0.001307 u ppm 0.000835 63.88 2.142140 -0.001307 u
Ca (315.887 nm)0.569915 ppm 0.005625 0.99 360.349179 0.569915
Cd (214.439 nm)0.000152 ppm 0.000153 > 100.00 2.438020 0.000152
Co (228.615 nm)0.000171 ppm 0.000128 75.00 46.115100 0.000171
Cr (205.560 nm)0.000420 ppm 0.000314 74.64 3.250750 0.000420
Cu (324.754 nm)0.007535 ppm 0.000435 5.77 1118.150000 0.007535
Fe (238.204 nm)0.427817 ppm 0.001485 0.35 1700.668517 0.427817
Fe H (259.940 nm)0.506548 u ppm 0.001384 0.27 681.666000 0.506548 u
K (766.491 nm)0.299075 ppm 0.032954 11.02 89.920900 0.299075
Li (670.783 nm)-0.003856 u ppm 0.001265 32.81 -4423.980000 -0.003856 u
Mg (279.078 nm)0.337443 ppm 0.001913 0.57 1137.250000 0.337443
Mn (257.610 nm)0.026959 ppm 0.000155 0.58 7197.740000 0.026959
Mo (202.032 nm)0.000660 ppm 0.000190 28.82 6.753870 0.000660
Na (589.592 nm)1.865910 ppm 0.027335 1.46 23937.300000 1.865910
Na H (589.593 nm)-8.324741 u ppm 0.018237 0.22 18961.791499 -8.324741 u
Ni (231.604 nm)0.001001 ppm 0.000777 77.65 -6.802630 0.001001
P (213.618 nm)0.001185 u ppm 0.001660 > 100.00 4.112170 0.001185 u
Pb (220.353 nm)0.002466 ppm 0.001240 50.28 4.023230 0.002466
S (181.972 nm)0.948771 ppm 0.009609 1.01 217.342776 0.948771
Sb (206.834 nm)-0.001146 u ppm 0.000261 22.79 0.639055 -0.001146 u
Se (196.026 nm)0.000969 u ppm 0.004070 > 100.00 5.583070 0.000969 u
Si (288.158 nm)1.308940 ppm 0.007042 0.54 10221.800000 1.308940
Sn (189.925 nm)-0.000629 u ppm 0.001114 > 100.00 1.858440 -0.000629 u
Sr (421.552 nm)0.006679 ppm 0.000099 1.48 1484.449219 0.006679
Th (288.505 nm)0.008742 ppm 0.002187 25.02 277.402000 0.008742
Ti (336.122 nm)0.000241 ppm 0.000110 45.60 -90.615400 0.000241
Tl (190.794 nm)0.002241 ppm 0.003308 > 100.00 -0.063126 0.002241
U (409.013 nm)-0.001649 u ppm 0.001510 91.53 16.667300 -0.001649 u
V (292.401 nm)0.000113 u ppm 0.000161 > 100.00 -34.317800 0.000113 u
Zn (206.200 nm)0.009018 ppm 0.000420 4.65 23.608700 0.009018
Zr (343.823 nm)0.000102 ppm 0.000084 81.90 1.252330 0.000102
Test Report
52A112023.esws
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Page 949 of 1261
Solution Name: 280-184010-D-13-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-13-A 11/20/2023 4:50:16 PM 2:18 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000378 ppm 0.000013 3.35 432.334526 0.000378
Ag (328.068 nm)-0.000057 u ppm 0.000243 > 100.00 -32.336800 -0.000057 u
Al (394.401 nm)0.164611 ppm 0.000315 0.19 2475.290000 0.164611
Al H (396.152 nm)0.170321 u ppm 0.000353 0.21 816.023000 0.170321 u
As (188.980 nm)0.001876 u ppm 0.003094 > 100.00 -1.846450 0.001876 u
B (249.678 nm)0.010784 ppm 0.000421 3.91 106.442000 0.010784
Ba (493.408 nm)0.040053 ppm 0.000216 0.54 6065.920000 0.040053
Be (234.861 nm)0.000048 ppm 0.000010 21.79 49.454700 0.000048
Bi (223.061 nm)0.001571 u ppm 0.002495 > 100.00 6.421180 0.001571 u
Ca (315.887 nm)1.232513 ppm 0.011026 0.89 807.217712 1.232513
Cd (214.439 nm)0.000286 ppm 0.000100 35.03 4.379870 0.000286
Co (228.615 nm)0.000981 ppm 0.000254 25.95 61.553000 0.000981
Cr (205.560 nm)0.000236 u ppm 0.000487 > 100.00 2.492650 0.000236 u
Cu (324.754 nm)0.012105 ppm 0.000144 1.19 1330.610000 0.012105
Fe (238.204 nm)0.120313 ppm 0.000430 0.36 490.208042 0.120313
Fe H (259.940 nm)0.209767 u ppm 0.002129 1.01 200.949000 0.209767 u
K (766.491 nm)0.235520 ppm 0.067991 28.87 -24.265200 0.235520
Li (670.783 nm)-0.003351 u ppm 0.001195 35.67 -4405.230000 -0.003351 u
Mg (279.078 nm)0.450818 ppm 0.000532 0.12 1516.630000 0.450818
Mn (257.610 nm)0.067350 ppm 0.000163 0.24 17974.800000 0.067350
Mo (202.032 nm)0.000607 ppm 0.000368 60.72 6.488170 0.000607
Na (589.592 nm)1.581320 ppm 0.011578 0.73 20729.900000 1.581320
Na H (589.593 nm)-8.467691 u ppm 0.054679 0.65 17896.449537 -8.467691 u
Ni (231.604 nm)0.001411 ppm 0.000839 59.42 -5.404880 0.001411
P (213.618 nm)0.005326 ppm 0.001368 25.69 8.760400 0.005326
Pb (220.353 nm)0.006507 ppm 0.000551 8.46 13.308600 0.006507
S (181.972 nm)2.113344 ppm 0.017784 0.84 454.548224 2.113344
Sb (206.834 nm)0.001465 ppm 0.000293 19.99 3.799240 0.001465
Se (196.026 nm)0.001249 u ppm 0.005561 > 100.00 5.813860 0.001249 u
Si (288.158 nm)0.072263 ppm 0.000746 1.03 1236.790000 0.072263
Sn (189.925 nm)0.000030 u ppm 0.001564 > 100.00 2.300980 0.000030 u
Sr (421.552 nm)0.011028 ppm 0.000087 0.79 2444.643936 0.011028
Th (288.505 nm)0.009506 ppm 0.002029 21.34 279.637000 0.009506
Ti (336.122 nm)0.000119 ppm 0.000056 46.85 -102.541000 0.000119
Tl (190.794 nm)-0.000167 u ppm 0.001689 > 100.00 -2.670880 -0.000167 u
U (409.013 nm)-0.001651 u ppm 0.002804 > 100.00 16.364900 -0.001651 u
V (292.401 nm)0.000070 u ppm 0.000182 > 100.00 -36.116600 0.000070 u
Zn (206.200 nm)0.033738 ppm 0.000887 2.63 76.914500 0.033738
Zr (343.823 nm)-0.000034 u ppm 0.000039 > 100.00 -10.271200 -0.000034 u
Test Report
52A112023.esws
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Page 950 of 1261
Solution Name: 280-184010-D-14-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-14-A 11/20/2023 4:54:24 PM 2:19 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000518 ppm 0.000006 1.24 789.804806 0.000518
Ag (328.068 nm)0.000009 u ppm 0.000116 > 100.00 -28.692000 0.000009 u
Al (394.401 nm)0.137236 ppm 0.001774 1.29 2140.800000 0.137236
Al H (396.152 nm)0.141327 u ppm 0.002735 1.94 685.715000 0.141327 u
As (188.980 nm)0.001772 ppm 0.000364 20.51 -1.933540 0.001772
B (249.678 nm)0.008842 ppm 0.000347 3.93 90.188700 0.008842
Ba (493.408 nm)0.042347 ppm 0.000369 0.87 6413.560000 0.042347
Be (234.861 nm)0.000049 ppm 0.000024 49.23 50.620500 0.000049
Bi (223.061 nm)-0.000645 u ppm 0.002262 > 100.00 3.126310 -0.000645 u
Ca (315.887 nm)0.964793 ppm 0.004162 0.43 626.662375 0.964793
Cd (214.439 nm)0.000191 ppm 0.000053 27.50 2.977800 0.000191
Co (228.615 nm)0.000098 ppm 0.000063 65.05 44.715000 0.000098
Cr (205.560 nm)0.000359 ppm 0.000192 53.46 2.998650 0.000359
Cu (324.754 nm)0.003864 ppm 0.000202 5.23 944.619000 0.003864
Fe (238.204 nm)0.196216 ppm 0.001178 0.60 788.992113 0.196216
Fe H (259.940 nm)0.284152 u ppm 0.003482 1.23 321.436000 0.284152 u
K (766.491 nm)0.338550 ppm 0.036308 10.72 160.845000 0.338550
Li (670.783 nm)-0.001885 u ppm 0.002433 > 100.00 -4350.690000 -0.001885 u
Mg (279.078 nm)0.396609 ppm 0.003156 0.80 1335.390000 0.396609
Mn (257.610 nm)0.046959 ppm 0.000190 0.40 12534.100000 0.046959
Mo (202.032 nm)0.000265 ppm 0.000131 49.29 4.793950 0.000265
Na (589.592 nm)1.878500 ppm 0.021713 1.16 24369.100000 1.878500
Na H (589.593 nm)-8.366730 u ppm 0.005008 0.06 18800.135136 -8.366730 u
Ni (231.604 nm)0.001824 ppm 0.000716 39.28 -3.999210 0.001824
P (213.618 nm)0.001274 u ppm 0.002206 > 100.00 4.424170 0.001274 u
Pb (220.353 nm)0.011162 ppm 0.001816 16.27 24.018800 0.011162
S (181.972 nm)1.377586 ppm 0.010533 0.76 304.686215 1.377586
Sb (206.834 nm)0.000234 u ppm 0.000974 > 100.00 2.305840 0.000234 u
Se (196.026 nm)0.000452 u ppm 0.002139 > 100.00 5.303270 0.000452 u
Si (288.158 nm)2.413060 ppm 0.009479 0.39 18244.300000 2.413060
Sn (189.925 nm)0.000807 u ppm 0.002592 > 100.00 2.823300 0.000807 u
Sr (421.552 nm)0.011471 ppm 0.000082 0.71 2542.411622 0.011471
Th (288.505 nm)0.005774 ppm 0.001951 33.80 272.295000 0.005774
Ti (336.122 nm)0.000180 ppm 0.000041 22.75 -96.427300 0.000180
Tl (190.794 nm)0.001267 ppm 0.001061 83.70 -1.115710 0.001267
U (409.013 nm)0.000550 u ppm 0.004565 > 100.00 26.014500 0.000550 u
V (292.401 nm)0.000109 u ppm 0.000222 > 100.00 -35.291700 0.000109 u
Zn (206.200 nm)0.007574 ppm 0.000487 6.43 20.495600 0.007574
Zr (343.823 nm)0.000235 ppm 0.000067 28.74 11.737600 0.000235
Test Report
52A112023.esws
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Page 951 of 1261
Solution Name: 280-184010-D-15-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-15-A 11/20/2023 4:58:38 PM 2:20 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000593 ppm 0.000006 1.01 975.247586 0.000593
Ag (328.068 nm)-0.000012 u ppm 0.000288 > 100.00 -29.550600 -0.000012 u
Al (394.401 nm)0.106302 ppm 0.001044 0.98 1758.600000 0.106302
Al H (396.152 nm)0.108427 u ppm 0.004120 3.80 537.857000 0.108427 u
As (188.980 nm)0.001333 ppm 0.000486 36.45 -2.298940 0.001333
B (249.678 nm)0.008024 ppm 0.000426 5.31 83.338300 0.008024
Ba (493.408 nm)0.040361 ppm 0.000301 0.75 6112.860000 0.040361
Be (234.861 nm)0.000008 u ppm 0.000011 > 100.00 43.941600 0.000008 u
Bi (223.061 nm)0.000903 ppm 0.000752 83.27 5.427510 0.000903
Ca (315.887 nm)1.155396 ppm 0.006049 0.52 755.208351 1.155396
Cd (214.439 nm)0.000139 ppm 0.000043 31.25 2.194520 0.000139
Co (228.615 nm)0.000151 u ppm 0.000254 > 100.00 45.733500 0.000151 u
Cr (205.560 nm)-0.000031 u ppm 0.000626 > 100.00 1.392160 -0.000031 u
Cu (324.754 nm)0.056981 ppm 0.000717 1.26 3423.860000 0.056981
Fe (238.204 nm)0.217916 ppm 0.001099 0.50 874.403794 0.217916
Fe H (259.940 nm)0.302569 u ppm 0.002358 0.78 351.266000 0.302569 u
K (766.491 nm)0.332722 ppm 0.019766 5.94 150.374000 0.332722
Li (670.783 nm)-0.000555 u ppm 0.000862 > 100.00 -4301.240000 -0.000555 u
Mg (279.078 nm)0.526701 ppm 0.003525 0.67 1770.410000 0.526701
Mn (257.610 nm)0.042016 ppm 0.000207 0.49 11215.300000 0.042016
Mo (202.032 nm)0.000554 ppm 0.000329 59.43 6.225850 0.000554
Na (589.592 nm)1.899410 ppm 0.010453 0.55 24599.400000 1.899410
Na H (589.593 nm)-8.340597 u ppm 0.012080 0.14 19011.276645 -8.340597 u
Ni (231.604 nm)0.001363 ppm 0.001167 85.57 -5.569020 0.001363
P (213.618 nm)0.003503 ppm 0.001235 35.26 4.256450 0.003503
Pb (220.353 nm)0.023250 ppm 0.000443 1.91 51.802600 0.023250
S (181.972 nm)1.570942 ppm 0.011483 0.73 344.063676 1.570942
Sb (206.834 nm)0.000901 ppm 0.000744 82.61 3.113870 0.000901
Se (196.026 nm)0.000496 u ppm 0.003487 > 100.00 5.324800 0.000496 u
Si (288.158 nm)0.524210 ppm 0.001718 0.33 4520.740000 0.524210
Sn (189.925 nm)0.000796 u ppm 0.002188 > 100.00 2.815960 0.000796 u
Sr (421.552 nm)0.012623 ppm 0.000021 0.16 2796.739118 0.012623
Th (288.505 nm)0.005806 ppm 0.005718 98.49 272.244000 0.005806
Ti (336.122 nm)0.000276 ppm 0.000028 10.18 -85.512100 0.000276
Tl (190.794 nm)0.001273 u ppm 0.001936 > 100.00 -1.110760 0.001273 u
U (409.013 nm)0.000996 u ppm 0.002631 > 100.00 28.075400 0.000996 u
V (292.401 nm)0.000144 ppm 0.000185 > 100.00 -33.133700 0.000144
Zn (206.200 nm)0.012349 ppm 0.000197 1.60 30.792100 0.012349
Zr (343.823 nm)0.000295 ppm 0.000079 26.85 16.695100 0.000295
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 81 of 287
Page 952 of 1261
Solution Name: 280-184010-D-16-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-16-A 11/20/2023 5:02:56 PM 2:21 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000572 ppm 0.000006 1.09 916.532584 0.000572
Ag (328.068 nm)0.000018 u ppm 0.000245 > 100.00 -28.046900 0.000018 u
Al (394.401 nm)0.106334 ppm 0.001065 1.00 1757.770000 0.106334
Al H (396.152 nm)0.109170 u ppm 0.002153 1.97 541.195000 0.109170 u
As (188.980 nm)0.003379 ppm 0.001139 33.71 -0.607490 0.003379
B (249.678 nm)0.007831 ppm 0.000053 0.68 81.727000 0.007831
Ba (493.408 nm)0.017369 ppm 0.000203 1.17 2633.200000 0.017369
Be (234.861 nm)0.000038 ppm 0.000021 53.61 61.198800 0.000038
Bi (223.061 nm)-0.001924 u ppm 0.000658 34.22 1.225190 -0.001924 u
Ca (315.887 nm)0.806524 ppm 0.010391 1.29 519.922564 0.806524
Cd (214.439 nm)0.000152 ppm 0.000117 76.93 2.579880 0.000152
Co (228.615 nm)0.000148 u ppm 0.000287 > 100.00 45.698300 0.000148 u
Cr (205.560 nm)0.000457 ppm 0.000065 14.16 3.401170 0.000457
Cu (324.754 nm)0.007512 ppm 0.000129 1.72 1118.110000 0.007512
Fe (238.204 nm)1.159398 ppm 0.004429 0.38 4580.463794 1.159398
Fe H (259.940 nm)1.227660 u ppm 0.006363 0.52 1849.690000 1.227660 u
K (766.491 nm)0.398335 ppm 0.076010 19.08 268.257000 0.398335
Li (670.783 nm)-0.002964 u ppm 0.000982 33.14 -4390.840000 -0.002964 u
Mg (279.078 nm)0.365551 ppm 0.001958 0.54 1230.750000 0.365551
Mn (257.610 nm)0.028750 ppm 0.000033 0.11 7675.490000 0.028750
Mo (202.032 nm)0.000443 ppm 0.000241 54.32 5.677580 0.000443
Na (589.592 nm)2.676150 ppm 0.023938 0.89 33773.900000 2.676150
Na H (589.593 nm)-7.521845 u ppm 0.011400 0.15 25981.596870 -7.521845 u
Ni (231.604 nm)0.002317 ppm 0.000366 15.82 -2.322730 0.002317
P (213.618 nm)0.006617 ppm 0.002342 35.40 10.531200 0.006617
Pb (220.353 nm)0.011286 ppm 0.000864 7.65 24.299300 0.011286
S (181.972 nm)0.911795 ppm 0.006249 0.69 209.842343 0.911795
Sb (206.834 nm)0.000051 u ppm 0.001935 > 100.00 2.147310 0.000051 u
Se (196.026 nm)-0.001004 u ppm 0.001895 > 100.00 4.296770 -0.001004 u
Si (288.158 nm)1.598690 ppm 0.003947 0.25 12327.700000 1.598690
Sn (189.925 nm)0.001574 ppm 0.001277 81.14 3.338440 0.001574
Sr (421.552 nm)0.007103 ppm 0.000091 1.28 1578.126857 0.007103
Th (288.505 nm)0.007955 ppm 0.005347 67.21 275.930000 0.007955
Ti (336.122 nm)0.000563 ppm 0.000053 9.44 -54.933200 0.000563
Tl (190.794 nm)0.000916 u ppm 0.001196 > 100.00 -1.515430 0.000916 u
U (409.013 nm)-0.001364 u ppm 0.001505 > 100.00 18.658500 -0.001364 u
V (292.401 nm)0.000308 ppm 0.000242 78.84 -26.006700 0.000308
Zn (206.200 nm)0.010870 ppm 0.000462 4.25 27.603000 0.010870
Zr (343.823 nm)0.000239 ppm 0.000058 24.38 13.438100 0.000239
Test Report
52A112023.esws
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Page 953 of 1261
Solution Name: 280-184010-D-16-A SD @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-16-A SD
@5
11/20/2023 5:07:15 PM 2:22 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000294 ppm 0.000007 2.55 166.843672 0.000294
Ag (328.068 nm)0.000115 u ppm 0.000149 > 100.00 -22.821700 0.000115 u
Al (394.401 nm)0.022833 ppm 0.000314 1.38 731.047000 0.022833
Al H (396.152 nm)0.026350 u ppm 0.004197 15.93 168.988000 0.026350 u
As (188.980 nm)0.002493 ppm 0.000975 39.10 -1.335550 0.002493
B (249.678 nm)0.000746 ppm 0.000327 43.86 22.425800 0.000746
Ba (493.408 nm)0.003597 ppm 0.000153 4.26 544.864000 0.003597
Be (234.861 nm)-0.000004 u ppm 0.000029 > 100.00 42.224800 -0.000004 u
Bi (223.061 nm)-0.000940 u ppm 0.001495 > 100.00 2.686860 -0.000940 u
Ca (315.887 nm)0.173427 ppm 0.007858 4.53 92.950124 0.173427
Cd (214.439 nm)0.000027 u ppm 0.000047 > 100.00 0.537491 0.000027 u
Co (228.615 nm)-0.000040 u ppm 0.000192 > 100.00 42.092900 -0.000040 u
Cr (205.560 nm)0.000596 ppm 0.000422 70.83 3.976670 0.000596
Cu (324.754 nm)0.001386 ppm 0.000209 15.10 831.032000 0.001386
Fe (238.204 nm)0.240099 ppm 0.001071 0.45 961.733930 0.240099
Fe H (259.940 nm)0.325636 u ppm 0.001659 0.51 388.629000 0.325636 u
K (766.491 nm)0.013927 u ppm 0.037456 > 100.00 -422.391000 0.013927 u
Li (670.783 nm)-0.020296 u ppm 0.023824 > 100.00 -5035.380000 -0.020296 u
Mg (279.078 nm)0.072871 ppm 0.000950 1.30 252.408000 0.072871
Mn (257.610 nm)0.005856 ppm 0.000068 1.15 1567.060000 0.005856
Mo (202.032 nm)0.000330 ppm 0.000264 79.99 5.116590 0.000330
Na (589.592 nm)0.668907 ppm 0.025515 3.81 9211.110000 0.668907
Na H (589.593 nm)-9.287797 u ppm 0.068579 0.74 10400.670593 -9.287797 u
Ni (231.604 nm)-0.000040 u ppm 0.000532 > 100.00 -10.347100 -0.000040 u
P (213.618 nm)0.002126 ppm 0.000696 32.72 5.548930 0.002126
Pb (220.353 nm)0.001878 ppm 0.000718 38.22 2.692030 0.001878
S (181.972 nm)0.156364 ppm 0.017787 11.38 55.925753 0.156364
Sb (206.834 nm)0.000937 u ppm 0.003323 > 100.00 3.168180 0.000937 u
Se (196.026 nm)-0.001633 u ppm 0.003707 > 100.00 3.991940 -0.001633 u
Si (288.158 nm)0.316049 ppm 0.000832 0.26 3007.730000 0.316049
Sn (189.925 nm)-0.001303 u ppm 0.001399 > 100.00 1.405180 -0.001303 u
Sr (421.552 nm)0.001483 ppm 0.000049 3.31 337.105850 0.001483
Th (288.505 nm)0.008837 ppm 0.002307 26.11 277.161000 0.008837
Ti (336.122 nm)0.000087 ppm 0.000046 52.75 -108.259000 0.000087
Tl (190.794 nm)0.001893 ppm 0.000620 32.75 -0.437717 0.001893
U (409.013 nm)-0.004158 u ppm 0.003797 91.32 5.431030 -0.004158 u
V (292.401 nm)0.000080 u ppm 0.000185 > 100.00 -35.935400 0.000080 u
Zn (206.200 nm)0.001957 ppm 0.000436 22.28 8.383700 0.001957
Zr (343.823 nm)0.000030 u ppm 0.000066 > 100.00 -4.922630 0.000030 u
Test Report
52A112023.esws
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Page 954 of 1261
Solution Name: 280-184010-D-16-B MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-16-B MS 11/20/2023 5:11:30 PM 2:23 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.898988 ppm 0.006943 0.77 2306107.911137 0.898988
Ag (328.068 nm)0.048163 ppm 0.000109 0.23 2102.040000 0.048163
Al (394.401 nm)9.336810 o ppm 0.064349 0.69 115343.000000 9.336810 o
Al H (396.152 nm)8.992960 ppm 0.033402 0.37 40466.700000 8.992960
As (188.980 nm)0.951624 ppm 0.005578 0.59 787.186000 0.951624
B (249.678 nm)1.900070 ppm 0.012309 0.65 15919.100000 1.900070
Ba (493.408 nm)0.932604 ppm 0.002870 0.31 141275.000000 0.932604
Be (234.861 nm)0.940133 ppm 0.009612 1.02 157244.000000 0.940133
Bi (223.061 nm)-0.000783 u ppm 0.001296 > 100.00 2.920840 -0.000783 u
Ca (315.887 nm)47.247632 o ppm 0.110135 0.23 31840.692435 47.247632 o
Cd (214.439 nm)0.931587 ppm 0.005780 0.62 13926.500000 0.931587
Co (228.615 nm)0.913933 ppm 0.005636 0.62 17507.100000 0.913933
Cr (205.560 nm)0.930278 ppm 0.005099 0.55 3825.200000 0.930278
Cu (324.754 nm)0.914423 ppm 0.004377 0.48 43403.200000 0.914423
Fe (238.204 nm)10.301874 o ppm 0.029418 0.29 40580.579592 10.301874 o
Fe H (259.940 nm)10.166500 ppm 0.046291 0.46 16328.600000 10.166500
K (766.491 nm)47.074600 ppm 0.370997 0.79 84129.200000 47.074600
Li (670.783 nm)0.911623 ppm 0.005578 0.61 29622.100000 0.911623
Mg (279.078 nm)47.687500 o ppm 0.290087 0.61 159503.000000 47.687500 o
Mn (257.610 nm)0.960396 ppm 0.005427 0.57 256259.000000 0.960396
Mo (202.032 nm)0.923237 ppm 0.006287 0.68 4584.660000 0.923237
Na (589.592 nm)47.888800 ppm 0.317083 0.66 594083.000000 47.888800
Na H (589.593 nm)38.152276 u ppm 0.582763 1.53 433757.134358 38.152276 u
Ni (231.604 nm)0.906986 ppm 0.004382 0.48 3078.870000 0.906986
P (213.618 nm)18.812500 o ppm 0.132176 0.70 22139.200000 18.812500 o
Pb (220.353 nm)0.974307 ppm 0.006709 0.69 2232.780000 0.974307
S (181.972 nm)18.615983 o ppm 0.165080 0.89 3819.728550 18.615983 o
Sb (206.834 nm)0.955391 ppm 0.007797 0.82 1165.870000 0.955391
Se (196.026 nm)0.923932 ppm 0.011714 1.27 571.557000 0.923932
Si (288.158 nm)10.422900 ppm 0.028895 0.28 76883.400000 10.422900
Sn (189.925 nm)0.911638 ppm 0.008312 0.91 614.889000 0.911638
Sr (421.552 nm)0.924746 ppm 0.002904 0.31 204193.212265 0.924746
Th (288.505 nm)0.066483 ppm 0.002339 3.52 363.571000 0.066483
Ti (336.122 nm)0.908930 ppm 0.005509 0.61 99166.900000 0.908930
Tl (190.794 nm)0.928447 ppm 0.005825 0.63 1003.470000 0.928447
U (409.013 nm)-0.006914 u ppm 0.000730 10.56 -25.466900 -0.006914 u
V (292.401 nm)0.932606 ppm 0.005307 0.57 38798.200000 0.932606
Zn (206.200 nm)0.938598 ppm 0.003850 0.41 2028.120000 0.938598
Zr (343.823 nm)0.907857 ppm 0.004899 0.54 74014.200000 0.907857
Test Report
52A112023.esws
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Page 955 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 5:15:59 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000196 u ppm 0.000019 9.87 431.265394 -0.000196 u
Ag (328.068 nm)-0.000374 u ppm 0.000116 31.00 92.523900 -0.000374 u
Al (394.401 nm)51.756300 o ppm 0.176662 0.34 636275.000000 51.756300 o
Al H (396.152 nm)48.870600 ppm 0.325539 0.67 219685.000000 48.870600
As (188.980 nm)0.002260 ppm 0.000354 15.66 -1.974330 0.002260
B (249.678 nm)0.000137 u ppm 0.000273 > 100.00 17.328900 0.000137 u
Ba (493.408 nm)0.000112 u ppm 0.000103 91.27 157.436000 0.000112 u
Be (234.861 nm)0.000243 ppm 0.000005 2.16 727.254000 0.000243
Bi (223.061 nm)-0.000127 u ppm 0.000687 > 100.00 3.896670 -0.000127 u
Ca (315.887 nm)-0.025426 u ppm 0.006168 24.26 -41.160455 -0.025426 u
Cd (214.439 nm)-0.000054 u ppm 0.000208 > 100.00 9.527580 -0.000054 u
Co (228.615 nm)0.000666 ppm 0.000259 38.84 55.568600 0.000666
Cr (205.560 nm)0.000831 ppm 0.000520 62.55 4.940400 0.000831
Cu (324.754 nm)-0.001063 u ppm 0.000552 51.88 1655.430000 -0.001063 u
Fe (238.204 nm)50.169804 o ppm 0.342230 0.68 197505.471817 50.169804 o
Fe H (259.940 nm)48.691500 ppm 0.319063 0.66 78730.200000 48.691500
K (766.491 nm)0.028145 ppm 0.008041 28.57 -396.845000 0.028145
Li (670.783 nm)-0.002674 u ppm 0.000575 21.49 -4380.050000 -0.002674 u
Mg (279.078 nm)0.000951 ppm 0.000697 73.30 -176.537000 0.000951
Mn (257.610 nm)-0.000882 u ppm 0.000026 2.95 -230.749000 -0.000882 u
Mo (202.032 nm)-0.000137 u ppm 0.000582 > 100.00 2.796280 -0.000137 u
Na (589.592 nm)248.145000 o ppm 0.403323 0.16 3017280.000000 248.145000 o
Na H (589.593 nm)236.515460 ppm 0.443580 0.19 2162177.695296 236.515460
Ni (231.604 nm)0.000566 ppm 0.000329 58.07 -8.282600 0.000566
P (213.618 nm)4.946170 ppm 0.013995 0.28 5841.550000 4.946170
Pb (220.353 nm)0.001631 ppm 0.000930 57.03 0.567234 0.001631
S (181.972 nm)4.806703 ppm 0.011370 0.24 1004.853216 4.806703
Sb (206.834 nm)0.001585 ppm 0.001493 94.17 7.406820 0.001585
Se (196.026 nm)0.008338 ppm 0.006115 73.33 4.869720 0.008338
Si (288.158 nm)0.031964 ppm 0.000228 0.71 944.226000 0.031964
Sn (189.925 nm)0.000592 u ppm 0.001702 > 100.00 2.678490 0.000592 u
Sr (421.552 nm)0.000547 ppm 0.000054 9.90 130.439002 0.000547
Th (288.505 nm)4.782220 ppm 0.021459 0.45 9197.270000 4.782220
Ti (336.122 nm)0.000921 ppm 0.000061 6.62 -17.554800 0.000921
Tl (190.794 nm)-0.002624 u ppm 0.001123 42.81 -6.238720 -0.002624 u
U (409.013 nm)2.436350 Q ppm 0.013760 0.56 10880.700000 Q 2.436350 Q
V (292.401 nm)0.000256 ppm 0.000059 23.03 251.979000 0.000256
Zn (206.200 nm)0.000718 u ppm 0.001360 > 100.00 5.711010 0.000718 u
Zr (343.823 nm)-0.000783 u ppm 0.000067 8.52 -3.543940 -0.000783 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 85 of 287
Page 956 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 5:20:56 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.454951 ppm 0.000125 0.03 1166580.716036 0.454951
Ag (328.068 nm)0.501447 ppm 0.002587 0.52 26781.900000 0.501447
Al (394.401 nm)0.492426 ppm 0.001561 0.32 6506.800000 0.492426
Al H (396.152 nm)0.499583 u ppm 0.003045 0.61 2295.790000 0.499583 u
As (188.980 nm)0.500256 ppm 0.002298 0.46 412.225000 0.500256
B (249.678 nm)0.493022 ppm 0.001167 0.24 4142.610000 0.493022
Ba (493.408 nm)0.494065 ppm 0.001380 0.28 74834.500000 0.494065
Be (234.861 nm)0.500012 ppm 0.003384 0.68 83610.700000 0.500012
Bi (223.061 nm)0.992023 ppm 0.006295 0.63 1479.010000 0.992023
Ca (315.887 nm)4.953468 ppm 0.012511 0.25 3316.700646 4.953468
Cd (214.439 nm)0.507329 ppm 0.001352 0.27 7583.570000 0.507329
Co (228.615 nm)0.504461 ppm 0.001198 0.24 9682.350000 0.504461
Cr (205.560 nm)0.510153 ppm 0.001285 0.25 2098.380000 0.510153
Cu (324.754 nm)0.499668 ppm 0.000911 0.18 24075.000000 0.499668
Fe (238.204 nm)2.485426 ppm 0.002206 0.09 9806.569527 2.485426
Fe H (259.940 nm)2.513570 u ppm 0.004235 0.17 3932.590000 2.513570 u
K (766.491 nm)50.170900 ppm 0.362834 0.72 89692.300000 50.170900
Li (670.783 nm)0.490390 ppm 0.001090 0.22 13956.700000 0.490390
Mg (279.078 nm)20.065500 ppm 0.040748 0.20 67120.400000 20.065500
Mn (257.610 nm)0.498216 ppm 0.000706 0.14 132939.000000 0.498216
Mo (202.032 nm)0.502246 ppm 0.001553 0.31 2495.660000 0.502246
Na (589.592 nm)24.841300 ppm 0.163116 0.66 308789.000000 24.841300
Na H (589.593 nm)14.409476 u ppm 0.262335 1.82 222104.914515 14.409476 u
Ni (231.604 nm)0.508446 ppm 0.001012 0.20 1721.480000 0.508446
P (213.618 nm)0.006629 ppm 0.001223 18.45 -29.414100 0.006629
Pb (220.353 nm)0.522204 ppm 0.002076 0.40 1196.420000 0.522204
S (181.972 nm)-0.023169 u ppm 0.013253 57.20 21.820714 -0.023169 u
Sb (206.834 nm)0.491727 ppm 0.003681 0.75 600.810000 0.491727
Se (196.026 nm)0.499395 ppm 0.004468 0.89 311.546000 0.499395
Si (288.158 nm)4.952990 ppm 0.032642 0.66 36941.200000 4.952990
Sn (189.925 nm)0.500455 ppm 0.001997 0.40 338.580000 0.500455
Sr (421.552 nm)0.495316 ppm 0.001472 0.30 109375.200342 0.495316
Th (288.505 nm)0.039940 ppm 0.003529 8.84 323.359000 0.039940
Ti (336.122 nm)0.497247 ppm 0.000917 0.18 54151.800000 0.497247
Tl (190.794 nm)0.504461 ppm 0.001205 0.24 544.152000 0.504461
U (409.013 nm)-0.006632 u ppm 0.001637 24.69 -18.678700 -0.006632 u
V (292.401 nm)0.499648 ppm 0.000807 0.16 20765.800000 0.499648
Zn (206.200 nm)0.508595 ppm 0.000717 0.14 1100.880000 0.508595
Zr (343.823 nm)0.492525 ppm 0.000699 0.14 40146.000000 0.492525
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 86 of 287
Page 957 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 5:25:15 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000236 ppm 0.000010 4.08 11.327483 0.000236
Ag (328.068 nm)0.000075 ppm 0.000075 > 100.00 -25.301900 0.000075
Al (394.401 nm)0.000338 u ppm 0.001499 > 100.00 454.806000 0.000338 u
Al H (396.152 nm)0.001258 u ppm 0.000909 72.21 56.219500 0.001258 u
As (188.980 nm)0.003135 ppm 0.000897 28.63 -0.799799 0.003135
B (249.678 nm)0.000656 ppm 0.000011 1.62 21.674000 0.000656
Ba (493.408 nm)0.000033 u ppm 0.000050 > 100.00 4.432100 0.000033 u
Be (234.861 nm)0.000005 u ppm 0.000040 > 100.00 40.700800 0.000005 u
Bi (223.061 nm)-0.001885 u ppm 0.001554 82.41 1.281840 -0.001885 u
Ca (315.887 nm)0.001916 u ppm 0.003136 > 100.00 -22.720214 0.001916 u
Cd (214.439 nm)0.000050 u ppm 0.000049 96.79 0.831581 0.000050 u
Co (228.615 nm)-0.000083 u ppm 0.000352 > 100.00 41.263100 -0.000083 u
Cr (205.560 nm)-0.000626 u ppm 0.000362 57.84 -1.050720 -0.000626 u
Cu (324.754 nm)0.000104 u ppm 0.000171 > 100.00 770.585000 0.000104 u
Fe (238.204 nm)0.001592 ppm 0.000377 23.67 22.872999 0.001592
Fe H (259.940 nm)0.092680 u ppm 0.000590 0.64 11.295400 0.092680 u
K (766.491 nm)0.020334 u ppm 0.033234 > 100.00 -410.880000 0.020334 u
Li (670.783 nm)0.000792 Su ppm 0.003124 > 100.00 -4251.140000 S 0.000792 Su
Mg (279.078 nm)-0.000201 u ppm 0.001201 > 100.00 8.175700 -0.000201 u
Mn (257.610 nm)-0.000036 u ppm 0.000004 10.90 -5.222990 -0.000036 u
Mo (202.032 nm)0.000755 ppm 0.000349 46.26 7.224470 0.000755
Na (589.592 nm)0.075307 ppm 0.012083 16.04 1951.820000 0.075307
Na H (589.593 nm)-10.102860 u ppm 0.004945 0.05 3232.979648 -10.102860 u
Ni (231.604 nm)-0.000374 u ppm 0.000777 > 100.00 -11.483000 -0.000374 u
P (213.618 nm)-0.002875 u ppm 0.001335 46.42 -0.293166 -0.002875 u
Pb (220.353 nm)-0.000385 u ppm 0.000521 > 100.00 -2.504730 -0.000385 u
S (181.972 nm)-0.026987 u ppm 0.003435 12.73 18.567795 -0.026987 u
Sb (206.834 nm)0.001554 ppm 0.000884 56.89 3.895660 0.001554
Se (196.026 nm)-0.004109 u ppm 0.003801 92.50 2.493700 -0.004109 u
Si (288.158 nm)0.000296 u ppm 0.001593 > 100.00 713.249000 0.000296 u
Sn (189.925 nm)-0.001809 u ppm 0.001835 > 100.00 1.065230 -0.001809 u
Sr (421.552 nm)0.000068 ppm 0.000031 46.22 24.587206 0.000068
Th (288.505 nm)0.007655 Z ppm 0.003780 49.38 274.843000 Z 0.007655 Z
Ti (336.122 nm)0.000026 u ppm 0.000056 > 100.00 -115.292000 0.000026 u
Tl (190.794 nm)0.000647 u ppm 0.001494 > 100.00 -1.787770 0.000647 u
U (409.013 nm)0.003323 ppm 0.001176 35.39 38.124100 0.003323
V (292.401 nm)-0.000124 u ppm 0.000078 62.61 -44.433800 -0.000124 u
Zn (206.200 nm)-0.001398 u ppm 0.000538 38.46 1.148980 -0.001398 u
Zr (343.823 nm)0.000162 ppm 0.000057 35.30 5.561990 0.000162
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 87 of 287
Page 958 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 5:29:16 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014369 ppm 0.000025 0.18 36345.838858 0.014369
Ag (328.068 nm)0.009674 ppm 0.000092 0.95 485.703000 0.009674
Al (394.401 nm)0.089842 ppm 0.001158 1.29 1565.540000 0.089842
Al H (396.152 nm)0.095268 u ppm 0.003779 3.97 478.720000 0.095268 u
As (188.980 nm)0.016900 ppm 0.001661 9.83 10.636300 0.016900
B (249.678 nm)0.096962 ppm 0.000598 0.62 827.723000 0.096962
Ba (493.408 nm)0.009829 ppm 0.000042 0.43 1488.390000 0.009829
Be (234.861 nm)0.001002 ppm 0.000036 3.61 208.581000 0.001002
Bi (223.061 nm)-0.001333 Qu ppm 0.001834 > 100.00 2.103850 Q -0.001333 Qu
Ca (315.887 nm)0.203729 ppm 0.002728 1.34 113.386463 0.203729
Cd (214.439 nm)0.005200 ppm 0.000116 2.23 77.823000 0.005200
Co (228.615 nm)0.010156 ppm 0.000217 2.13 236.881000 0.010156
Cr (205.560 nm)0.009477 ppm 0.000557 5.88 40.410700 0.009477
Cu (324.754 nm)0.014877 ppm 0.000173 1.16 1453.850000 0.014877
Fe (238.204 nm)0.101555 ppm 0.000177 0.17 416.429881 0.101555
Fe H (259.940 nm)0.192670 u ppm 0.002370 1.23 173.255000 0.192670 u
K (766.491 nm)3.018460 ppm 0.029202 0.97 4975.710000 3.018460
Li (670.783 nm)0.016584 ppm 0.000632 3.81 -3663.850000 0.016584
Mg (279.078 nm)0.201588 ppm 0.001100 0.55 682.445000 0.201588
Mn (257.610 nm)0.010218 ppm 0.000011 0.11 2730.830000 0.010218
Mo (202.032 nm)0.020253 ppm 0.000283 1.40 103.973000 0.020253
Na (589.592 nm)1.098270 ppm 0.007371 0.67 14505.300000 1.098270
Na H (589.593 nm)-9.110058 u ppm 0.014643 0.16 12012.205630 -9.110058 u
Ni (231.604 nm)0.040769 ppm 0.001444 3.54 128.623000 0.040769
P (213.618 nm)2.817570 ppm 0.003925 0.14 3328.200000 2.817570
Pb (220.353 nm)0.009312 ppm 0.001930 20.72 19.806100 0.009312
S (181.972 nm)0.055443 Q ppm 0.004928 8.89 35.424877 Q 0.055443 Q
Sb (206.834 nm)0.018897 ppm 0.003099 16.40 24.947800 0.018897
Se (196.026 nm)0.018251 ppm 0.006448 35.33 16.211600 0.018251
Si (288.158 nm)0.470697 ppm 0.004274 0.91 4162.320000 0.470697
Sn (189.925 nm)0.100115 ppm 0.000786 0.78 69.556500 0.100115
Sr (421.552 nm)0.009732 ppm 0.000103 1.06 2158.487895 0.009732
Th (288.505 nm)0.009830 Q ppm 0.002186 22.24 278.999000 Q 0.009830 Q
Ti (336.122 nm)0.009647 ppm 0.000088 0.91 934.950000 0.009647
Tl (190.794 nm)0.015850 ppm 0.002898 18.28 14.676500 0.015850
U (409.013 nm)0.060533 ppm 0.002815 4.65 289.755000 0.060533
V (292.401 nm)0.009807 ppm 0.000195 1.99 364.588000 0.009807
Zn (206.200 nm)0.020825 ppm 0.000907 4.36 49.069400 0.020825
Zr (343.823 nm)0.009887 ppm 0.000101 1.02 798.493000 0.009887
Test Report
52A112023.esws
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Page 959 of 1261
Solution Name: 280-184010-D-16-C MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-16-C MSD 11/20/2023 5:33:32 PM 2:24 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.954221 ppm 0.003798 0.40 2447802.203711 0.954221
Ag (328.068 nm)0.050449 ppm 0.000380 0.75 2205.950000 0.050449
Al (394.401 nm)9.836960 o ppm 0.052986 0.54 121501.000000 9.836960 o
Al H (396.152 nm)9.517470 ppm 0.040175 0.42 42824.000000 9.517470
As (188.980 nm)0.992317 ppm 0.005461 0.55 820.992000 0.992317
B (249.678 nm)1.994840 ppm 0.012054 0.60 16712.300000 1.994840
Ba (493.408 nm)0.986384 ppm 0.004263 0.43 149422.000000 0.986384
Be (234.861 nm)0.992967 ppm 0.004159 0.42 166079.000000 0.992967
Bi (223.061 nm)0.001595 ppm 0.001568 98.36 6.455940 0.001595
Ca (315.887 nm)50.045645 o ppm 0.248238 0.50 33727.726122 50.045645 o
Cd (214.439 nm)0.978816 ppm 0.005997 0.61 14632.500000 0.978816
Co (228.615 nm)0.960944 ppm 0.006721 0.70 18406.300000 0.960944
Cr (205.560 nm)0.978618 ppm 0.005489 0.56 4023.820000 0.978618
Cu (324.754 nm)0.968415 ppm 0.003163 0.33 45918.100000 0.968415
Fe (238.204 nm)10.892825 o ppm 0.043278 0.40 42907.394379 10.892825 o
Fe H (259.940 nm)10.738000 ppm 0.043934 0.41 17254.300000 10.738000
K (766.491 nm)50.141700 ppm 0.135301 0.27 89639.800000 50.141700
Li (670.783 nm)0.970474 ppm 0.002064 0.21 31810.800000 0.970474
Mg (279.078 nm)50.334300 o ppm 0.276771 0.55 168356.000000 50.334300 o
Mn (257.610 nm)1.011670 ppm 0.004752 0.47 269939.000000 1.011670
Mo (202.032 nm)0.990991 ppm 0.003347 0.34 4920.860000 0.990991
Na (589.592 nm)51.079200 ppm 0.105241 0.21 633492.000000 51.079200
Na H (589.593 nm)40.552020 u ppm 0.871032 2.15 455229.688338 40.552020 u
Ni (231.604 nm)0.953277 ppm 0.004730 0.50 3236.530000 0.953277
P (213.618 nm)19.775800 o ppm 0.160397 0.81 23271.600000 19.775800 o
Pb (220.353 nm)1.018570 ppm 0.010846 1.06 2334.190000 1.018570
S (181.972 nm)19.486820 o ppm 0.123269 0.63 3997.300020 19.486820 o
Sb (206.834 nm)1.026670 ppm 0.005282 0.51 1252.560000 1.026670
Se (196.026 nm)0.965250 ppm 0.007300 0.76 596.884000 0.965250
Si (288.158 nm)11.112700 o ppm 0.019739 0.18 81927.300000 11.112700 o
Sn (189.925 nm)0.977050 ppm 0.008270 0.85 658.845000 0.977050
Sr (421.552 nm)0.978871 ppm 0.004297 0.44 216143.815108 0.978871
Th (288.505 nm)0.067959 ppm 0.003216 4.73 365.200000 0.067959
Ti (336.122 nm)0.976650 ppm 0.004876 0.50 106563.000000 0.976650
Tl (190.794 nm)0.974391 ppm 0.006674 0.68 1053.160000 0.974391
U (409.013 nm)-0.002208 u ppm 0.002476 > 100.00 -6.458380 -0.002208 u
V (292.401 nm)0.981971 ppm 0.004418 0.45 40852.600000 0.981971
Zn (206.200 nm)0.987224 ppm 0.004440 0.45 2132.980000 0.987224
Zr (343.823 nm)0.975280 ppm 0.004719 0.48 79511.300000 0.975280
Test Report
52A112023.esws
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Page 960 of 1261
Solution Name: 280-184010-D-16-A PDS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-16-A PDS 11/20/2023 5:38:01 PM 2:25 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.088196 ppm 0.000141 0.16 226075.345255 0.088196
Ag (328.068 nm)0.049395 ppm 0.000240 0.49 2605.670000 0.049395
Al (394.401 nm)1.064670 ppm 0.004538 0.43 13551.500000 1.064670
Al H (396.152 nm)1.036780 ppm 0.002948 0.28 4710.080000 1.036780
As (188.980 nm)0.195998 ppm 0.002768 1.41 159.427000 0.195998
B (249.678 nm)0.113159 ppm 0.001252 1.11 963.285000 0.113159
Ba (493.408 nm)0.111888 ppm 0.000329 0.29 16951.200000 0.111888
Be (234.861 nm)0.048986 ppm 0.000515 1.05 8251.030000 0.048986
Bi (223.061 nm)0.001443 u ppm 0.002577 > 100.00 6.230120 0.001443 u
Ca (315.887 nm)20.398466 o ppm 0.052669 0.26 13733.102304 20.398466 o
Cd (214.439 nm)0.050098 ppm 0.000365 0.73 749.311000 0.050098
Co (228.615 nm)0.049364 ppm 0.000381 0.77 986.116000 0.049364
Cr (205.560 nm)0.049184 ppm 0.000273 0.56 203.669000 0.049184
Cu (324.754 nm)0.055919 ppm 0.000548 0.98 3376.210000 0.055919
Fe (238.204 nm)2.093195 ppm 0.004043 0.19 8256.908177 2.093195
Fe H (259.940 nm)2.124130 u ppm 0.008490 0.40 3301.770000 2.124130 u
K (766.491 nm)20.064400 ppm 0.068046 0.34 35601.400000 20.064400
Li (670.783 nm)0.094816 ppm 0.000308 0.32 -754.464000 0.094816
Mg (279.078 nm)20.100900 ppm 0.062381 0.31 67226.500000 20.100900
Mn (257.610 nm)0.077117 ppm 0.000273 0.35 20580.900000 0.077117
Mo (202.032 nm)0.051973 ppm 0.000294 0.57 261.372000 0.051973
Na (589.592 nm)22.113500 ppm 0.055116 0.25 271146.000000 22.113500
Na H (589.593 nm)15.595109 u ppm 1.653767 10.60 229170.402365 15.595109 u
Ni (231.604 nm)0.048605 ppm 0.000454 0.93 155.442000 0.048605
P (213.618 nm)1.962630 ppm 0.007060 0.36 2315.770000 1.962630
Pb (220.353 nm)0.112432 ppm 0.002281 2.03 257.306000 0.112432
S (181.972 nm)0.899300 ppm 0.007977 0.89 208.277273 0.899300
Sb (206.834 nm)0.106286 ppm 0.002081 1.96 131.562000 0.106286
Se (196.026 nm)0.197201 ppm 0.000588 0.30 125.862000 0.197201
Si (288.158 nm)6.405880 ppm 0.026155 0.41 47315.200000 6.405880
Sn (189.925 nm)0.177505 ppm 0.001622 0.91 121.562000 0.177505
Sr (421.552 nm)0.055497 ppm 0.000058 0.10 12263.425480 0.055497
Th (288.505 nm)0.212570 ppm 0.005512 2.59 660.050000 0.212570
Ti (336.122 nm)0.049836 ppm 0.000081 0.16 5364.490000 0.049836
Tl (190.794 nm)0.195553 ppm 0.001778 0.91 209.716000 0.195553
U (409.013 nm)0.485237 ppm 0.004838 1.00 2164.620000 0.485237
V (292.401 nm)0.049433 ppm 0.000074 0.15 2008.740000 0.049433
Zn (206.200 nm)0.208133 ppm 0.001378 0.66 452.973000 0.208133
Zr (343.823 nm)0.049903 ppm 0.000195 0.39 4063.210000 0.049903
Test Report
52A112023.esws
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Page 961 of 1261
Solution Name: 280-184010-D-17-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-D-17-A 11/20/2023 5:42:23 PM 2:26 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000541 ppm 0.000011 2.12 835.807059 0.000541
Ag (328.068 nm)0.000246 ppm 0.000083 33.76 -15.782200 0.000246
Al (394.401 nm)0.208867 ppm 0.001149 0.55 3020.730000 0.208867
Al H (396.152 nm)0.212789 u ppm 0.005799 2.73 1006.880000 0.212789 u
As (188.980 nm)0.001662 ppm 0.001014 61.03 -2.040110 0.001662
B (249.678 nm)0.008880 ppm 0.000374 4.21 90.499500 0.008880
Ba (493.408 nm)0.017221 ppm 0.000332 1.93 2612.850000 0.017221
Be (234.861 nm)0.000057 ppm 0.000010 17.03 73.434800 0.000057
Bi (223.061 nm)-0.000590 u ppm 0.002870 > 100.00 3.207670 -0.000590 u
Ca (315.887 nm)0.778450 ppm 0.006561 0.84 500.989158 0.778450
Cd (214.439 nm)0.000225 ppm 0.000111 49.47 3.817440 0.000225
Co (228.615 nm)0.000271 ppm 0.000156 57.71 48.407600 0.000271
Cr (205.560 nm)0.000716 ppm 0.000495 69.23 4.463820 0.000716
Cu (324.754 nm)0.019954 ppm 0.000253 1.27 1698.450000 0.019954
Fe (238.204 nm)1.864703 ppm 0.012758 0.68 7356.840597 1.864703
Fe H (259.940 nm)1.905780 u ppm 0.009113 0.48 2948.090000 1.905780 u
K (766.491 nm)0.459955 ppm 0.009450 2.05 378.966000 0.459955
Li (670.783 nm)-0.002402 u ppm 0.000656 27.30 -4369.930000 -0.002402 u
Mg (279.078 nm)0.336609 ppm 0.005074 1.51 1133.540000 0.336609
Mn (257.610 nm)0.026859 ppm 0.000133 0.50 7171.000000 0.026859
Mo (202.032 nm)0.001047 ppm 0.000582 55.64 8.672080 0.001047
Na (589.592 nm)2.409780 ppm 0.007148 0.30 30533.200000 2.409780
Na H (589.593 nm)-7.793385 u ppm 0.044905 0.58 23602.339585 -7.793385 u
Ni (231.604 nm)0.000696 u ppm 0.000902 > 100.00 -7.841070 0.000696 u
P (213.618 nm)0.016358 ppm 0.000845 5.16 21.363200 0.016358
Pb (220.353 nm)0.049537 ppm 0.001431 2.89 112.199000 0.049537
S (181.972 nm)0.793460 ppm 0.008227 1.04 185.769126 0.793460
Sb (206.834 nm)0.002934 u ppm 0.003551 > 100.00 5.678310 0.002934 u
Se (196.026 nm)0.001434 u ppm 0.006273 > 100.00 5.717460 0.001434 u
Si (288.158 nm)1.609570 ppm 0.007706 0.48 12408.200000 1.609570
Sn (189.925 nm)-0.000192 u ppm 0.000784 > 100.00 2.152160 -0.000192 u
Sr (421.552 nm)0.006744 ppm 0.000072 1.07 1498.856954 0.006744
Th (288.505 nm)0.007973 ppm 0.000892 11.19 275.935000 0.007973
Ti (336.122 nm)0.010298 ppm 0.000064 0.63 1007.200000 0.010298
Tl (190.794 nm)0.001030 u ppm 0.001012 98.32 -1.421420 0.001030 u
U (409.013 nm)-0.003383 u ppm 0.000640 18.91 10.381900 -0.003383 u
V (292.401 nm)0.000372 ppm 0.000172 46.31 -23.689300 0.000372
Zn (206.200 nm)0.013934 ppm 0.001698 12.19 34.208800 0.013934
Zr (343.823 nm)0.000655 ppm 0.000113 17.27 48.265600 0.000655
Test Report
52A112023.esws
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Page 962 of 1261
Solution Name: 280-184047-D-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184047-D-1-A 11/20/2023 5:46:43 PM 1:17 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.372456 b ppm 0.000522 0.14 970062.527720 0.372456 b
Ag (328.068 nm)0.002945 ppm 0.000139 4.70 125.458000 0.002945
Al (394.401 nm)0.052105 ppm 0.001184 2.27 1083.380000 0.052105
Al H (396.152 nm)-0.062521 u ppm 0.010579 16.92 -230.417000 -0.062521 u
As (188.980 nm)0.010102 ppm 0.002563 25.37 4.988900 0.010102
B (249.678 nm)0.431721 ppm 0.001258 0.29 3629.540000 0.431721
Ba (493.408 nm)0.020139 ppm 0.000187 0.93 3049.650000 0.020139
Be (234.861 nm)0.000235 ppm 0.000019 8.30 79.364900 0.000235
Bi (223.061 nm)0.002935 u ppm 0.005155 > 100.00 8.449400 0.002935 u
Ca (315.887 nm)611.525331 o ppm 1.077507 0.18 412400.345266 611.525331 o
Cd (214.439 nm)0.001309 ppm 0.000136 10.42 19.647100 0.001309
Co (228.615 nm)0.000607 ppm 0.000073 12.03 54.391600 0.000607
Cr (205.560 nm)0.000066 u ppm 0.000605 > 100.00 1.688050 0.000066 u
Cu (324.754 nm)0.033718 ppm 0.003165 9.39 1977.010000 0.033718
Fe (238.204 nm)0.021549 ppm 0.001406 6.52 101.466533 0.021549
Fe H (259.940 nm)0.113739 u ppm 0.002335 2.05 45.405000 0.113739 u
K (766.491 nm)20.788900 ppm 0.015543 0.07 36903.000000 20.788900
Li (670.783 nm)0.324114 ppm 0.002292 0.71 7773.030000 0.324114
Mg (279.078 nm)273.456000 o ppm 0.518199 0.19 914632.000000 273.456000 o
Mn (257.610 nm)0.334968 ppm 0.000574 0.17 89381.000000 0.334968
Mo (202.032 nm)0.021925 ppm 0.000718 3.27 112.270000 0.021925
Na (589.592 nm)233.072000 o ppm 0.730756 0.31 2834300.000000 233.072000 o
Na H (589.593 nm)221.932556 ppm 1.612292 0.73 2034687.435879 221.932556
Ni (231.604 nm)0.028615 ppm 0.001773 6.20 87.229200 0.028615
P (213.618 nm)0.045061 ppm 0.003688 8.19 53.876800 0.045061
Pb (220.353 nm)-0.002743 u ppm 0.001685 61.43 -7.711190 -0.002743 u
S (181.972 nm)735.375451 bo ppm 2.387988 0.32 149794.649746 735.375451 bo
Sb (206.834 nm)-0.003310 u ppm 0.003180 96.07 -2.122710 -0.003310 u
Se (196.026 nm)0.041138 ppm 0.002313 5.62 30.480200 0.041138
Si (288.158 nm)11.697600 o ppm 0.033670 0.29 85701.700000 11.697600 o
Sn (189.925 nm)-0.000901 u ppm 0.002634 > 100.00 1.675630 -0.000901 u
Sr (421.552 nm)5.030894 o ppm 0.064858 1.29 1110828.406015 5.030894 o
Th (288.505 nm)0.105562 ppm 0.001500 1.42 469.946000 0.105562
Ti (336.122 nm)-0.002338 u ppm 0.000104 4.44 965.451000 -0.002338 u
Tl (190.794 nm)0.000903 u ppm 0.004447 > 100.00 -1.558020 0.000903 u
U (409.013 nm)0.144985 ppm 0.004515 3.11 663.613000 0.144985
V (292.401 nm)0.004971 ppm 0.000225 4.54 167.494000 0.004971
Zn (206.200 nm)0.008772 ppm 0.000269 3.06 23.077800 0.008772
Zr (343.823 nm)0.000406 ppm 0.000054 13.41 25.493800 0.000406
Test Report
52A112023.esws
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Page 963 of 1261
Solution Name: 280-184047-D-2-A @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184047-D-2-A @5 11/20/2023 5:51:38 PM 1:18 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.117409 b ppm 0.000574 0.49 305560.862263 0.117409 b
Ag (328.068 nm)0.000983 ppm 0.000141 14.34 24.879300 0.000983
Al (394.401 nm)0.028142 ppm 0.000357 1.27 783.921000 0.028142
Al H (396.152 nm)-0.016893 u ppm 0.004719 27.93 -25.353800 -0.016893 u
As (188.980 nm)0.001662 ppm 0.001694 > 100.00 -2.025310 0.001662
B (249.678 nm)0.295986 ppm 0.000847 0.29 2493.490000 0.295986
Ba (493.408 nm)0.007036 ppm 0.000172 2.45 1065.690000 0.007036
Be (234.861 nm)0.000113 ppm 0.000024 21.10 61.786200 0.000113
Bi (223.061 nm)0.002439 u ppm 0.003561 > 100.00 7.711360 0.002439 u
Ca (315.887 nm)125.074315 o ppm 0.420614 0.34 84328.493462 125.074315 o
Cd (214.439 nm)0.000361 ppm 0.000065 17.91 5.526870 0.000361
Co (228.615 nm)0.000100 u ppm 0.000137 > 100.00 44.728900 0.000100 u
Cr (205.560 nm)0.000809 ppm 0.000203 25.03 4.848650 0.000809
Cu (324.754 nm)0.000732 ppm 0.000265 36.23 734.692000 0.000732
Fe (238.204 nm)0.236729 ppm 0.001847 0.78 948.486398 0.236729
Fe H (259.940 nm)0.319909 u ppm 0.001112 0.35 379.353000 0.319909 u
K (766.491 nm)5.297020 ppm 0.048557 0.92 9069.480000 5.297020
Li (670.783 nm)0.104935 ppm 0.005312 5.06 -378.124000 0.104935
Mg (279.078 nm)75.938300 o ppm 0.503496 0.66 253998.000000 75.938300 o
Mn (257.610 nm)0.040194 ppm 0.000226 0.56 10729.000000 0.040194
Mo (202.032 nm)0.000874 ppm 0.000172 19.66 7.814010 0.000874
Na (589.592 nm)164.606000 o ppm 1.093160 0.66 2001940.000000 164.606000 o
Na H (589.593 nm)172.823263 ppm 10.2728
67 5.94 1604663.356346 172.823263
Ni (231.604 nm)-0.000937 u ppm 0.000494 52.72 -13.399600 -0.000937 u
P (213.618 nm)0.003061 u ppm 0.004858 > 100.00 6.622150 0.003061 u
Pb (220.353 nm)0.000491 u ppm 0.001654 > 100.00 -0.456570 0.000491 u
S (181.972 nm)255.092569 bo ppm 1.806773 0.71 51975.817423 255.092569 bo
Sb (206.834 nm)-0.002195 u ppm 0.000912 41.53 -0.647129 -0.002195 u
Se (196.026 nm)0.001425 u ppm 0.003874 > 100.00 5.891830 0.001425 u
Si (288.158 nm)2.076580 ppm 0.009461 0.46 15798.600000 2.076580
Sn (189.925 nm)-0.001862 u ppm 0.000643 34.51 1.029330 -0.001862 u
Sr (421.552 nm)0.901177 ppm 0.006531 0.72 198989.159261 0.901177
Th (288.505 nm)0.057626 ppm 0.002256 3.92 370.391000 0.057626
Ti (336.122 nm)-0.000695 u ppm 0.000063 9.03 79.912100 -0.000695 u
Tl (190.794 nm)0.002904 ppm 0.002307 79.44 0.661207 0.002904
U (409.013 nm)0.030324 ppm 0.002738 9.03 158.174000 0.030324
V (292.401 nm)0.001129 ppm 0.000074 6.51 11.373800 0.001129
Zn (206.200 nm)0.003118 ppm 0.001226 39.33 10.886900 0.003118
Zr (343.823 nm)0.000156 ppm 0.000041 26.23 5.419050 0.000156
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 93 of 287
Page 964 of 1261
Solution Name: 280-184053-E-1-A @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184053-E-1-A @5 11/20/2023 5:56:01 PM 1:19 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.070616 b ppm 0.000252 0.36 185152.973898 0.070616 b
Ag (328.068 nm)0.000939 ppm 0.000132 14.10 21.120400 0.000939
Al (394.401 nm)0.031255 ppm 0.000686 2.20 829.322000 0.031255
Al H (396.152 nm)-0.020987 u ppm 0.001697 8.09 -43.755500 -0.020987 u
As (188.980 nm)0.003119 u ppm 0.003883 > 100.00 -0.858755 0.003119 u
B (249.678 nm)0.134351 ppm 0.000681 0.51 1140.650000 0.134351
Ba (493.408 nm)0.003699 ppm 0.000304 8.23 574.009000 0.003699
Be (234.861 nm)0.000157 ppm 0.000052 33.33 132.125000 0.000157
Bi (223.061 nm)0.000794 u ppm 0.001784 > 100.00 5.265860 0.000794 u
Ca (315.887 nm)153.273097 o ppm 0.563926 0.37 103346.290043 153.273097 o
Cd (214.439 nm)0.000453 ppm 0.000176 38.92 7.894320 0.000453
Co (228.615 nm)0.000099 u ppm 0.000209 > 100.00 44.711100 0.000099 u
Cr (205.560 nm)0.000731 ppm 0.000503 68.88 4.520750 0.000731
Cu (324.754 nm)-0.000170 u ppm 0.000165 97.38 675.513000 -0.000170 u
Fe (238.204 nm)5.126017 ppm 0.019969 0.39 20194.722748 5.126017
Fe H (259.940 nm)5.069240 ppm 0.025777 0.51 8072.180000 5.069240
K (766.491 nm)5.503220 ppm 0.037638 0.68 9439.970000 5.503220
Li (670.783 nm)0.053460 ppm 0.027919 52.22 -2292.460000 0.053460
Mg (279.078 nm)53.328300 o ppm 0.213712 0.40 178372.000000 53.328300 o
Mn (257.610 nm)0.724972 ppm 0.002443 0.34 193442.000000 0.724972
Mo (202.032 nm)0.001552 ppm 0.000335 21.61 11.178200 0.001552
Na (589.592 nm)111.099000 o ppm 0.491653 0.44 1351510.000000 111.099000 o
Na H (589.593 nm)91.782928 ppm 8.109303 8.84 895193.723980 91.782928
Ni (231.604 nm)-0.002928 u ppm 0.000737 25.17 -20.179000 -0.002928 u
P (213.618 nm)0.024970 ppm 0.001685 6.75 32.561900 0.024970
Pb (220.353 nm)-0.000084 u ppm 0.002057 > 100.00 -1.807000 -0.000084 u
S (181.972 nm)222.965937 bo ppm 0.994754 0.45 45434.726744 222.965937 bo
Sb (206.834 nm)-0.002632 u ppm 0.001385 52.63 -0.846146 -0.002632 u
Se (196.026 nm)0.004089 ppm 0.001286 31.44 7.467490 0.004089
Si (288.158 nm)1.797830 ppm 0.005758 0.32 13773.400000 1.797830
Sn (189.925 nm)-0.002042 u ppm 0.001829 89.58 0.908921 -0.002042 u
Sr (421.552 nm)2.166043 o ppm 0.030838 1.42 478270.751444 2.166043 o
Th (288.505 nm)0.054805 ppm 0.003294 6.01 378.294000 0.054805
Ti (336.122 nm)-0.000631 u ppm 0.000077 12.19 148.627000 -0.000631 u
Tl (190.794 nm)0.000154 u ppm 0.000614 > 100.00 -2.415660 0.000154 u
U (409.013 nm)0.012324 ppm 0.002621 21.27 83.147900 0.012324
V (292.401 nm)0.001261 ppm 0.000269 21.34 15.015900 0.001261
Zn (206.200 nm)0.000277 u ppm 0.000887 > 100.00 4.759720 0.000277 u
Zr (343.823 nm)0.000147 ppm 0.000034 23.21 11.249200 0.000147
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 94 of 287
Page 965 of 1261
Solution Name: 280-184047-D-2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184047-D-2-A 11/20/2023 6:00:24 PM 1:20 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.711032 b ppm 0.004838 0.68 1846667.053927 0.711032 b
Ag (328.068 nm)0.001811 ppm 0.000108 5.95 67.475200 0.001811
Al (394.401 nm)0.045478 ppm 0.000816 1.80 998.615000 0.045478
Al H (396.152 nm)-0.068134 u ppm 0.003149 4.62 -255.644000 -0.068134 u
As (188.980 nm)0.004174 ppm 0.001381 33.09 0.063577 0.004174
B (249.678 nm)1.561100 ppm 0.008462 0.54 13082.000000 1.561100
Ba (493.408 nm)0.006077 ppm 0.000150 2.48 919.819000 0.006077
Be (234.861 nm)0.000316 ppm 0.000013 4.11 92.786300 0.000316
Bi (223.061 nm)0.004421 ppm 0.000804 18.19 10.658400 0.004421
Ca (315.887 nm)614.127921 o ppm 1.997661 0.33 414155.581418 614.127921 o
Cd (214.439 nm)0.000843 ppm 0.000191 22.68 12.674400 0.000843
Co (228.615 nm)0.000887 ppm 0.000202 22.82 59.728700 0.000887
Cr (205.560 nm)0.000000 u ppm 0.001010 > 100.00 1.498720 0.000000 u
Cu (324.754 nm)0.002470 ppm 0.000394 15.93 518.175000 0.002470
Fe (238.204 nm)0.010023 ppm 0.000433 4.32 56.107509 0.010023
Fe H (259.940 nm)0.108079 u ppm 0.004025 3.72 36.237800 0.108079 u
K (766.491 nm)28.196600 ppm 0.169512 0.60 50212.100000 28.196600
Li (670.783 nm)0.507417 ppm 0.025253 4.98 14589.900000 0.507417
Mg (279.078 nm)384.201000 o ppm 2.825670 0.74 1285040.000000 384.201000 o
Mn (257.610 nm)0.190265 ppm 0.001118 0.59 50771.300000 0.190265
Mo (202.032 nm)0.001552 ppm 0.000741 47.73 11.180700 0.001552
Na (589.592 nm)837.723000 o ppm 19.1494
00 2.29 10183800.000000 837.723000 o
Na H (589.593 nm)919.341657 ppm 33.1660
49 3.61 8139805.310225 919.341657
Ni (231.604 nm)0.005845 ppm 0.000315 5.39 9.695470 0.005845
P (213.618 nm)0.011458 ppm 0.001871 16.33 16.413700 0.011458
Pb (220.353 nm)-0.000325 u ppm 0.001273 > 100.00 -2.252760 -0.000325 u
S (181.972 nm)1201.596154
bo ppm 8.181933 0.68 244739.680944 1201.596154 bo
Sb (206.834 nm)-0.005229 u ppm 0.003321 63.51 -4.363840 -0.005229 u
Se (196.026 nm)0.002655 u ppm 0.006249 > 100.00 6.769560 0.002655 u
Si (288.158 nm)10.748200 ppm 0.045328 0.42 78803.000000 10.748200
Sn (189.925 nm)-0.003972 u ppm 0.000803 20.22 -0.388368 -0.003972 u
Sr (421.552 nm)4.531761 o ppm 0.049589 1.09 1000620.178665 4.531761 o
Th (288.505 nm)0.120474 ppm 0.003931 3.26 496.705000 0.120474
Ti (336.122 nm)-0.002268 u ppm 0.000012 0.51 978.843000 -0.002268 u
Tl (190.794 nm)0.003216 ppm 0.000977 30.38 1.006600 0.003216
U (409.013 nm)0.062554 ppm 0.003759 6.01 300.172000 0.062554
V (292.401 nm)0.002993 ppm 0.000324 10.83 88.014500 0.002993
Zn (206.200 nm)0.004413 ppm 0.000739 16.75 13.678300 0.004413
Zr (343.823 nm)0.000088 u ppm 0.000169 > 100.00 -0.431087 0.000088 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 95 of 287
Page 966 of 1261
Solution Name: 280-184053-E-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184053-E-1-A 11/20/2023 6:05:20 PM 1:21 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.433855 b ppm 0.001987 0.46 1134856.395764 0.433855 b
Ag (328.068 nm)0.002115 ppm 0.000170 8.04 89.505600 0.002115
Al (394.401 nm)0.067413 ppm 0.000788 1.17 1238.780000 0.067413
Al H (396.152 nm)-0.064154 u ppm 0.001951 3.04 -237.757000 -0.064154 u
As (188.980 nm)0.004368 ppm 0.002485 56.90 -0.006049 0.004368
B (249.678 nm)0.713727 ppm 0.003539 0.50 5989.830000 0.713727
Ba (493.408 nm)0.018821 ppm 0.000166 0.88 2922.570000 0.018821
Be (234.861 nm)0.000253 ppm 0.000008 3.03 415.232000 0.000253
Bi (223.061 nm)0.004148 ppm 0.001739 41.94 10.251600 0.004148
Ca (315.887 nm)773.400807 o ppm 1.468533 0.19 521572.256191 773.400807 o
Cd (214.439 nm)0.000715 ppm 0.000155 21.62 16.044500 0.000715
Co (228.615 nm)0.000924 ppm 0.000230 24.89 60.444400 0.000924
Cr (205.560 nm)0.000200 u ppm 0.000317 > 100.00 2.340300 0.000200 u
Cu (324.754 nm)0.006466 ppm 0.000188 2.91 660.330000 0.006466
Fe (238.204 nm)25.834836 o ppm 0.026192 0.10 101713.136218 25.834836 o
Fe H (259.940 nm)25.552000 ppm 0.015794 0.06 41249.500000 25.552000
K (766.491 nm)30.971400 ppm 0.070098 0.23 55197.400000 30.971400
Li (670.783 nm)0.368286 ppm 0.003866 1.05 9415.750000 0.368286
Mg (279.078 nm)277.095000 o ppm 1.378500 0.50 926789.000000 277.095000 o
Mn (257.610 nm)3.614710 o ppm 0.013109 0.36 964487.000000 3.614710 o
Mo (202.032 nm)0.001528 ppm 0.000927 60.63 11.062100 0.001528
Na (589.592 nm)585.680000 o ppm 2.879170 0.49 7120300.000000 585.680000 o
Na H (589.593 nm)593.408543 ppm 7.357374 1.24 5286644.133714 593.408543
Ni (231.604 nm)-0.005515 u ppm 0.000754 13.67 -28.982600 -0.005515 u
P (213.618 nm)0.116107 ppm 0.003305 2.85 139.827000 0.116107
Pb (220.353 nm)0.001970 u ppm 0.001926 97.78 2.885990 0.001970 u
S (181.972 nm)1090.243030
bo ppm 6.860023 0.63 222070.430361 1090.243030 bo
Sb (206.834 nm)-0.003360 u ppm 0.001522 45.29 -0.302477 -0.003360 u
Se (196.026 nm)0.001206 ppm 0.000901 74.71 5.441830 0.001206
Si (288.158 nm)9.505750 ppm 0.041262 0.43 69775.600000 9.505750
Sn (189.925 nm)-0.003706 u ppm 0.001757 47.41 -0.209751 -0.003706 u
Sr (421.552 nm)11.000119 bo ppm 0.157585 1.43 2428830.066581 11.000119 bo
Th (288.505 nm)0.161953 ppm 0.001563 0.97 640.123000 0.161953
Ti (336.122 nm)-0.002007 u ppm 0.000030 1.47 1355.520000 -0.002007 u
Tl (190.794 nm)0.004002 ppm 0.002787 69.63 1.394920 0.004002
U (409.013 nm)-0.024370 u ppm 0.003695 15.16 -56.343100 -0.024370 u
V (292.401 nm)0.002991 ppm 0.000207 6.91 99.035100 0.002991
Zn (206.200 nm)0.001438 ppm 0.001330 92.46 7.263560 0.001438
Zr (343.823 nm)0.000315 ppm 0.000063 20.06 53.014200 0.000315
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 96 of 287
Page 967 of 1261
Solution Name: 280-184053-E-2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184053-E-2-A 11/20/2023 6:10:16 PM 1:22 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.426192 b ppm 0.000784 0.18 1104195.351186 0.426192 b
Ag (328.068 nm)0.003238 ppm 0.000108 3.32 144.252000 0.003238
Al (394.401 nm)0.237394 ppm 0.002418 1.02 3356.040000 0.237394
Al H (396.152 nm)0.159546 u ppm 0.005327 3.34 767.598000 0.159546 u
As (188.980 nm)0.005838 ppm 0.001419 24.30 1.443100 0.005838
B (249.678 nm)0.670284 ppm 0.001801 0.27 5626.230000 0.670284
Ba (493.408 nm)0.032802 ppm 0.000597 1.82 4968.330000 0.032802
Be (234.861 nm)0.000248 ppm 0.000010 4.07 85.419200 0.000248
Bi (223.061 nm)0.002907 u ppm 0.004405 > 100.00 8.406870 0.002907 u
Ca (315.887 nm)258.638323 o ppm 1.474787 0.57 174406.609840 258.638323 o
Cd (214.439 nm)0.000581 ppm 0.000078 13.46 8.832150 0.000581
Co (228.615 nm)0.000523 ppm 0.000051 9.77 52.958200 0.000523
Cr (205.560 nm)0.001041 ppm 0.000225 21.56 5.792160 0.001041
Cu (324.754 nm)0.005008 ppm 0.000156 3.11 857.793000 0.005008
Fe (238.204 nm)0.318928 ppm 0.003355 1.05 1272.070795 0.318928
Fe H (259.940 nm)0.401965 u ppm 0.003135 0.78 512.265000 0.401965 u
K (766.491 nm)4.865620 ppm 0.054705 1.12 8294.420000 4.865620
Li (670.783 nm)0.403485 ppm 0.002334 0.58 10724.800000 0.403485
Mg (279.078 nm)375.972000 o ppm 1.623820 0.43 1257520.000000 375.972000 o
Mn (257.610 nm)0.013322 ppm 0.000045 0.34 3559.070000 0.013322
Mo (202.032 nm)0.006310 ppm 0.000581 9.21 34.790500 0.006310
Na (589.592 nm)91.384200 o ppm 0.393121 0.43 1112210.000000 91.384200 o
Na H (589.593 nm)81.384230 ppm 0.167374 0.21 804411.623632 81.384230
Ni (231.604 nm)-0.003772 u ppm 0.002456 65.11 -23.055800 -0.003772 u
P (213.618 nm)0.021972 ppm 0.001282 5.83 28.561600 0.021972
Pb (220.353 nm)0.000200 u ppm 0.002190 > 100.00 -0.974796 0.000200 u
S (181.972 nm)515.426912 bo ppm 2.267311 0.44 104995.146689 515.426912 bo
Sb (206.834 nm)-0.005171 u ppm 0.001429 27.64 -4.304710 -0.005171 u
Se (196.026 nm)0.003976 ppm 0.002878 72.37 7.431010 0.003976
Si (288.158 nm)16.831900 o ppm 0.025474 0.15 123006.000000 16.831900 o
Sn (189.925 nm)-0.000464 u ppm 0.000874 > 100.00 1.969390 -0.000464 u
Sr (421.552 nm)2.216053 o ppm 0.029756 1.34 489312.939445 2.216053 o
Th (288.505 nm)0.094105 ppm 0.002632 2.80 443.954000 0.094105
Ti (336.122 nm)0.003593 ppm 0.000134 3.72 840.274000 0.003593
Tl (190.794 nm)0.000838 u ppm 0.002232 > 100.00 -1.601510 0.000838 u
U (409.013 nm)0.137445 ppm 0.003209 2.33 630.983000 0.137445
V (292.401 nm)0.002929 ppm 0.000219 7.47 85.119200 0.002929
Zn (206.200 nm)0.004412 ppm 0.000379 8.58 13.677300 0.004412
Zr (343.823 nm)0.000522 ppm 0.000068 13.08 35.367200 0.000522
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 97 of 287
Page 968 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 6:14:40 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000154 u ppm 0.000010 6.26 536.884311 -0.000154 u
Ag (328.068 nm)-0.000324 u ppm 0.000262 80.95 96.425000 -0.000324 u
Al (394.401 nm)52.127700 o ppm 0.281365 0.54 640841.000000 52.127700 o
Al H (396.152 nm)48.742300 ppm 0.250387 0.51 219109.000000 48.742300
As (188.980 nm)0.001505 u ppm 0.002004 > 100.00 -2.600550 0.001505 u
B (249.678 nm)-0.001685 u ppm 0.000552 32.76 2.074920 -0.001685 u
Ba (493.408 nm)0.000264 ppm 0.000233 88.40 179.872000 0.000264
Be (234.861 nm)0.000205 ppm 0.000044 21.26 718.632000 0.000205
Bi (223.061 nm)-0.000675 u ppm 0.001133 > 100.00 3.081740 -0.000675 u
Ca (315.887 nm)-0.018475 u ppm 0.007967 43.12 -36.472540 -0.018475 u
Cd (214.439 nm)0.000148 u ppm 0.000290 > 100.00 12.513800 0.000148 u
Co (228.615 nm)0.000471 ppm 0.000277 58.84 51.848900 0.000471
Cr (205.560 nm)0.000446 ppm 0.000150 33.73 3.354780 0.000446
Cu (324.754 nm)-0.000891 u ppm 0.000280 31.42 1667.530000 -0.000891 u
Fe (238.204 nm)50.010610 o ppm 0.264314 0.53 196878.805682 50.010610 o
Fe H (259.940 nm)48.572300 ppm 0.223765 0.46 78537.100000 48.572300
K (766.491 nm)0.023773 ppm 0.013503 56.80 -404.700000 0.023773
Li (670.783 nm)0.001294 u ppm 0.001231 95.14 -4232.470000 0.001294 u
Mg (279.078 nm)0.020058 ppm 0.010979 54.74 -113.405000 0.020058
Mn (257.610 nm)-0.000944 u ppm 0.000022 2.35 -247.327000 -0.000944 u
Mo (202.032 nm)-0.000164 u ppm 0.000353 > 100.00 2.665200 -0.000164 u
Na (589.592 nm)246.075000 o ppm 1.972490 0.80 2992130.000000 246.075000 o
Na H (589.593 nm)238.867079 ppm 1.733156 0.73 2182765.390891 238.867079
Ni (231.604 nm)0.000263 u ppm 0.000518 > 100.00 -9.313840 0.000263 u
P (213.618 nm)4.974650 ppm 0.020853 0.42 5875.140000 4.974650
Pb (220.353 nm)0.000427 u ppm 0.002656 > 100.00 -2.156950 0.000427 u
S (181.972 nm)4.890800 ppm 0.022665 0.46 1021.963577 4.890800
Sb (206.834 nm)-0.000557 u ppm 0.003209 > 100.00 4.780520 -0.000557 u
Se (196.026 nm)0.004538 ppm 0.001136 25.02 2.556880 0.004538
Si (288.158 nm)0.032034 ppm 0.002862 8.94 944.756000 0.032034
Sn (189.925 nm)0.001420 ppm 0.001679 > 100.00 3.235410 0.001420
Sr (421.552 nm)0.000547 ppm 0.000035 6.47 130.511781 0.000547
Th (288.505 nm)4.748200 ppm 0.024909 0.52 9133.880000 4.748200
Ti (336.122 nm)0.000711 ppm 0.000091 12.74 -40.519800 0.000711
Tl (190.794 nm)-0.003332 u ppm 0.001173 35.20 -7.005310 -0.003332 u
U (409.013 nm)2.442090 Q ppm 0.013223 0.54 10906.200000 Q 2.442090 Q
V (292.401 nm)0.000188 u ppm 0.000196 > 100.00 250.405000 0.000188 u
Zn (206.200 nm)0.000568 ppm 0.000559 98.38 5.388570 0.000568
Zr (343.823 nm)-0.000957 u ppm 0.000101 10.54 -18.036200 -0.000957 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 98 of 287
Page 969 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 6:19:08 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.454368 ppm 0.000763 0.17 1165086.607750 0.454368
Ag (328.068 nm)0.501283 ppm 0.002229 0.44 26774.300000 0.501283
Al (394.401 nm)0.492400 ppm 0.001411 0.29 6506.410000 0.492400
Al H (396.152 nm)0.498527 u ppm 0.002341 0.47 2291.050000 0.498527 u
As (188.980 nm)0.499502 ppm 0.002612 0.52 411.598000 0.499502
B (249.678 nm)0.494166 ppm 0.000581 0.12 4152.180000 0.494166
Ba (493.408 nm)0.493872 ppm 0.003271 0.66 74805.300000 0.493872
Be (234.861 nm)0.498103 ppm 0.005470 1.10 83291.700000 0.498103
Bi (223.061 nm)0.996451 ppm 0.005828 0.58 1485.600000 0.996451
Ca (315.887 nm)4.939433 ppm 0.002385 0.05 3307.235316 4.939433
Cd (214.439 nm)0.505099 ppm 0.001442 0.29 7550.230000 0.505099
Co (228.615 nm)0.503382 ppm 0.001215 0.24 9661.790000 0.503382
Cr (205.560 nm)0.509336 ppm 0.001563 0.31 2095.020000 0.509336
Cu (324.754 nm)0.498759 ppm 0.001360 0.27 24032.700000 0.498759
Fe (238.204 nm)2.476404 ppm 0.007856 0.32 9771.026483 2.476404
Fe H (259.940 nm)2.501450 u ppm 0.001143 0.05 3912.950000 2.501450 u
K (766.491 nm)50.167500 ppm 0.254193 0.51 89686.200000 50.167500
Li (670.783 nm)0.491495 ppm 0.004762 0.97 13997.800000 0.491495
Mg (279.078 nm)20.052000 ppm 0.054794 0.27 67075.100000 20.052000
Mn (257.610 nm)0.496213 ppm 0.000973 0.20 132405.000000 0.496213
Mo (202.032 nm)0.501921 ppm 0.001248 0.25 2494.050000 0.501921
Na (589.592 nm)24.781300 ppm 0.155686 0.63 308055.000000 24.781300
Na H (589.593 nm)14.652856 u ppm 0.228086 1.56 224232.313967 14.652856 u
Ni (231.604 nm)0.507319 ppm 0.001198 0.24 1717.640000 0.507319
P (213.618 nm)0.004591 ppm 0.002560 55.76 -31.766500 0.004591
Pb (220.353 nm)0.520977 ppm 0.002027 0.39 1193.610000 0.520977
S (181.972 nm)-0.011811 u ppm 0.006459 54.68 24.127179 -0.011811 u
Sb (206.834 nm)0.493798 ppm 0.001270 0.26 603.325000 0.493798
Se (196.026 nm)0.494941 ppm 0.008763 1.77 308.813000 0.494941
Si (288.158 nm)4.945380 ppm 0.032808 0.66 36885.200000 4.945380
Sn (189.925 nm)0.497663 ppm 0.001055 0.21 336.704000 0.497663
Sr (421.552 nm)0.495110 ppm 0.003292 0.66 109329.641055 0.495110
Th (288.505 nm)0.038497 ppm 0.002422 6.29 320.701000 0.038497
Ti (336.122 nm)0.497129 ppm 0.001040 0.21 54139.000000 0.497129
Tl (190.794 nm)0.502863 ppm 0.003110 0.62 542.415000 0.502863
U (409.013 nm)-0.008092 u ppm 0.002469 30.51 -25.141000 -0.008092 u
V (292.401 nm)0.498352 ppm 0.001226 0.25 20711.900000 0.498352
Zn (206.200 nm)0.505181 ppm 0.004139 0.82 1093.520000 0.505181
Zr (343.823 nm)0.492930 ppm 0.001497 0.30 40179.100000 0.492930
Test Report
52A112023.esws
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Page 970 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 6:23:31 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000305 ppm 0.000009 3.07 187.287349 0.000305
Ag (328.068 nm)0.000093 u ppm 0.000225 > 100.00 -24.242700 0.000093 u
Al (394.401 nm)0.000317 ppm 0.000256 80.76 454.190000 0.000317
Al H (396.152 nm)-0.002125 u ppm 0.001811 85.21 41.014200 -0.002125 u
As (188.980 nm)0.001909 ppm 0.000542 28.42 -1.818300 0.001909
B (249.678 nm)0.000586 ppm 0.000508 86.75 21.084000 0.000586
Ba (493.408 nm)0.000048 u ppm 0.000139 > 100.00 6.730680 0.000048 u
Be (234.861 nm)0.000004 u ppm 0.000014 > 100.00 40.452100 0.000004 u
Bi (223.061 nm)0.000803 u ppm 0.002509 > 100.00 5.278290 0.000803 u
Ca (315.887 nm)0.010583 ppm 0.006349 60.00 -16.875475 0.010583
Cd (214.439 nm)-0.000120 u ppm 0.000048 39.88 -1.712820 -0.000120 u
Co (228.615 nm)0.000017 u ppm 0.000085 > 100.00 43.172500 0.000017 u
Cr (205.560 nm)0.000295 u ppm 0.000697 > 100.00 2.738390 0.000295 u
Cu (324.754 nm)0.000423 ppm 0.000068 16.07 785.709000 0.000423
Fe (238.204 nm)0.000737 ppm 0.000469 63.65 19.506278 0.000737
Fe H (259.940 nm)0.092688 u ppm 0.000601 0.65 11.307300 0.092688 u
K (766.491 nm)0.059404 ppm 0.034626 58.29 -340.685000 0.059404
Li (670.783 nm)0.000282 Su ppm 0.001767 > 100.00 -4270.110000 S 0.000282 Su
Mg (279.078 nm)0.001819 ppm 0.001247 68.58 14.938400 0.001819
Mn (257.610 nm)-0.000011 u ppm 0.000033 > 100.00 1.631340 -0.000011 u
Mo (202.032 nm)0.000595 ppm 0.000214 35.94 6.432560 0.000595
Na (589.592 nm)0.110256 ppm 0.005981 5.42 2376.890000 0.110256
Na H (589.593 nm)-9.829184 u ppm 0.024664 0.25 5628.967525 -9.829184 u
Ni (231.604 nm)-0.000125 u ppm 0.000571 > 100.00 -10.637100 -0.000125 u
P (213.618 nm)0.000248 u ppm 0.001939 > 100.00 3.378690 0.000248 u
Pb (220.353 nm)0.000440 u ppm 0.000975 > 100.00 -0.611082 0.000440 u
S (181.972 nm)-0.016441 u ppm 0.005512 33.53 20.712858 -0.016441 u
Sb (206.834 nm)0.001566 ppm 0.000902 57.58 3.913730 0.001566
Se (196.026 nm)-0.004268 u ppm 0.003495 81.90 2.396160 -0.004268 u
Si (288.158 nm)0.001306 ppm 0.000869 66.56 721.485000 0.001306
Sn (189.925 nm)0.000891 ppm 0.000974 > 100.00 2.879960 0.000891
Sr (421.552 nm)0.000027 u ppm 0.000082 > 100.00 15.593819 0.000027 u
Th (288.505 nm)0.008877 Z ppm 0.001569 17.67 277.109000 Z 0.008877 Z
Ti (336.122 nm)-0.000005 u ppm 0.000072 > 100.00 -118.639000 -0.000005 u
Tl (190.794 nm)0.001825 ppm 0.001152 63.13 -0.507629 0.001825
U (409.013 nm)0.000622 u ppm 0.001094 > 100.00 26.238300 0.000622 u
V (292.401 nm)0.000041 u ppm 0.000142 > 100.00 -37.559800 0.000041 u
Zn (206.200 nm)-0.001507 u ppm 0.000742 49.25 0.912672 -0.001507 u
Zr (343.823 nm)0.000100 ppm 0.000069 68.80 0.523583 0.000100
Test Report
52A112023.esws
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Page 971 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 6:27:33 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014383 ppm 0.000046 0.32 36383.408310 0.014383
Ag (328.068 nm)0.009864 ppm 0.000181 1.84 495.984000 0.009864
Al (394.401 nm)0.089880 ppm 0.001233 1.37 1566.690000 0.089880
Al H (396.152 nm)0.092566 u ppm 0.003711 4.01 466.573000 0.092566 u
As (188.980 nm)0.015153 ppm 0.001223 8.07 9.184560 0.015153
B (249.678 nm)0.096622 ppm 0.000553 0.57 824.873000 0.096622
Ba (493.408 nm)0.009921 ppm 0.000369 3.72 1502.280000 0.009921
Be (234.861 nm)0.000965 ppm 0.000018 1.89 202.329000 0.000965
Bi (223.061 nm)0.001039 Qu ppm 0.002033 > 100.00 5.630100 Q 0.001039 Qu
Ca (315.887 nm)0.204201 ppm 0.000902 0.44 113.704701 0.204201
Cd (214.439 nm)0.005047 ppm 0.000032 0.64 75.532300 0.005047
Co (228.615 nm)0.010120 ppm 0.000318 3.14 236.198000 0.010120
Cr (205.560 nm)0.009715 ppm 0.000169 1.74 41.387800 0.009715
Cu (324.754 nm)0.015173 ppm 0.000196 1.29 1467.080000 0.015173
Fe (238.204 nm)0.100803 ppm 0.000171 0.17 413.468714 0.100803
Fe H (259.940 nm)0.191817 u ppm 0.000203 0.11 171.874000 0.191817 u
K (766.491 nm)2.998810 ppm 0.042551 1.42 4940.410000 2.998810
Li (670.783 nm)0.021999 ppm 0.003981 18.09 -3462.460000 0.021999
Mg (279.078 nm)0.201719 ppm 0.000830 0.41 682.962000 0.201719
Mn (257.610 nm)0.010216 ppm 0.000047 0.46 2730.340000 0.010216
Mo (202.032 nm)0.020361 ppm 0.000187 0.92 104.510000 0.020361
Na (589.592 nm)1.086850 ppm 0.017571 1.62 14366.300000 1.086850
Na H (589.593 nm)-8.892894 u ppm 0.019169 0.22 13913.183445 -8.892894 u
Ni (231.604 nm)0.041787 ppm 0.001077 2.58 132.089000 0.041787
P (213.618 nm)2.820670 ppm 0.011868 0.42 3331.820000 2.820670
Pb (220.353 nm)0.009614 ppm 0.001737 18.07 20.501500 0.009614
S (181.972 nm)0.074352 ppm 0.010106 13.59 39.275818 0.074352
Sb (206.834 nm)0.019429 ppm 0.001067 5.49 25.596200 0.019429
Se (196.026 nm)0.017979 ppm 0.003587 19.95 16.044400 0.017979
Si (288.158 nm)0.470142 ppm 0.004439 0.94 4157.930000 0.470142
Sn (189.925 nm)0.099101 ppm 0.001029 1.04 68.875400 0.099101
Sr (421.552 nm)0.009800 ppm 0.000173 1.77 2173.420088 0.009800
Th (288.505 nm)0.007857 Q ppm 0.001650 21.00 275.318000 Q 0.007857 Q
Ti (336.122 nm)0.009618 ppm 0.000084 0.87 931.799000 0.009618
Tl (190.794 nm)0.015771 ppm 0.001388 8.80 14.589900 0.015771
U (409.013 nm)0.054788 ppm 0.004742 8.66 264.403000 0.054788
V (292.401 nm)0.009534 ppm 0.000075 0.79 352.908000 0.009534
Zn (206.200 nm)0.020199 ppm 0.000494 2.45 47.718900 0.020199
Zr (343.823 nm)0.009835 ppm 0.000024 0.24 794.244000 0.009835
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 101 of 287
Page 972 of 1261
Solution Name: 280-183888-H-1-B @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183888-H-1-B @5 11/20/2023 6:31:56 PM 1:23 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.163755 b ppm 0.002179 1.33 431724.179374 0.163755 b
Ag (328.068 nm)0.003578 ppm 0.000087 2.43 101.136000 0.003578
Al (394.401 nm)0.430621 ppm 0.004813 1.12 5735.090000 0.430621
Al H (396.152 nm)0.361488 u ppm 0.002322 0.64 1675.170000 0.361488 u
As (188.980 nm)0.035510 ppm 0.005070 14.28 25.973600 0.035510
B (249.678 nm)4.166580 ppm 0.050613 1.21 34889.000000 4.166580
Ba (493.408 nm)0.050230 ppm 0.000599 1.19 7646.560000 0.050230
Be (234.861 nm)0.000117 ppm 0.000032 27.36 241.227000 0.000117
Bi (223.061 nm)0.000859 u ppm 0.002310 > 100.00 5.362810 0.000859 u
Ca (315.887 nm)20.230183 o ppm 0.078808 0.39 13619.608788 20.230183 o
Cd (214.439 nm)0.000580 ppm 0.000055 9.42 11.636900 0.000580
Co (228.615 nm)0.007641 ppm 0.000082 1.07 190.212000 0.007641
Cr (205.560 nm)0.059880 ppm 0.000582 0.97 247.731000 0.059880
Cu (324.754 nm)0.008817 ppm 0.000285 3.23 1192.470000 0.008817
Fe (238.204 nm)14.109492 o ppm 0.083681 0.59 55557.356877 14.109492 o
Fe H (259.940 nm)13.886000 ppm 0.077711 0.56 22353.300000 13.886000
K (766.491 nm)158.724000 o ppm 1.198690 0.76 284724.000000 158.724000 o
Li (670.783 nm)0.105251 ppm 0.038741 36.81 -366.391000 0.105251
Mg (279.078 nm)59.440900 o ppm 0.874620 1.47 198811.000000 59.440900 o
Mn (257.610 nm)0.372922 ppm 0.005394 1.45 99508.100000 0.372922
Mo (202.032 nm)0.015059 ppm 0.000320 2.12 78.200200 0.015059
Na (589.592 nm)1989.960000 o ppm 95.8517
00 4.82 24189900.000000 1989.960000 o
Na H (589.593 nm)2453.877475 ppm 61.6848
42 2.51 21573786.450274 2453.877475
Ni (231.604 nm)0.101998 ppm 0.002010 1.97 337.102000 0.101998
P (213.618 nm)2.326830 ppm 0.034535 1.48 2749.290000 2.326830
Pb (220.353 nm)0.001181 ppm 0.001308 > 100.00 0.948751 0.001181
S (181.972 nm)605.844875 bo ppm 9.412921 1.55 123404.881181 605.844875 bo
Sb (206.834 nm)-0.001140 u ppm 0.001604 > 100.00 1.787440 -0.001140 u
Se (196.026 nm)0.003441 ppm 0.003886 > 100.00 5.894330 0.003441
Si (288.158 nm)3.058600 ppm 0.049513 1.62 22943.400000 3.058600
Sn (189.925 nm)0.003636 ppm 0.001046 28.77 4.724030 0.003636
Sr (421.552 nm)0.243214 ppm 0.001766 0.73 53711.288135 0.243214
Th (288.505 nm)0.068538 ppm 0.001857 2.71 392.995000 0.068538
Ti (336.122 nm)0.042289 ppm 0.000486 1.15 4540.620000 0.042289
Tl (190.794 nm)-0.000159 u ppm 0.003218 > 100.00 -3.004850 -0.000159 u
U (409.013 nm)-0.046661 u ppm 0.005555 11.91 -167.813000 -0.046661 u
V (292.401 nm)0.084214 ppm 0.001039 1.23 3482.240000 0.084214
Zn (206.200 nm)0.057936 ppm 0.001127 1.95 129.094000 0.057936
Zr (343.823 nm)0.008160 ppm 0.000096 1.17 676.609000 0.008160
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 102 of 287
Page 973 of 1261
Solution Name: 280-183888-H-3-B @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183888-H-3-B @5 11/20/2023 6:36:51 PM 1:24 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.232974 b ppm 0.003028 1.30 611826.467098 0.232974 b
Ag (328.068 nm)0.008842 ppm 0.000336 3.80 358.043000 0.008842
Al (394.401 nm)0.607518 ppm 0.008012 1.32 7904.720000 0.607518
Al H (396.152 nm)0.514235 u ppm 0.002926 0.57 2361.640000 0.514235 u
As (188.980 nm)0.049687 ppm 0.002554 5.14 37.700500 0.049687
B (249.678 nm)6.117140 ppm 0.077590 1.27 51214.600000 6.117140
Ba (493.408 nm)0.063932 ppm 0.000624 0.98 9738.510000 0.063932
Be (234.861 nm)0.000184 ppm 0.000010 5.51 328.804000 0.000184
Bi (223.061 nm)-0.000732 u ppm 0.002114 > 100.00 2.996120 -0.000732 u
Ca (315.887 nm)23.116811 o ppm 0.146093 0.63 15566.405904 23.116811 o
Cd (214.439 nm)0.000667 ppm 0.000118 17.71 14.136700 0.000667
Co (228.615 nm)0.010204 ppm 0.000031 0.31 239.446000 0.010204
Cr (205.560 nm)0.087794 ppm 0.001189 1.35 362.516000 0.087794
Cu (324.754 nm)0.003881 ppm 0.000369 9.52 972.897000 0.003881
Fe (238.204 nm)20.039570 o ppm 0.130930 0.65 78900.573067 20.039570 o
Fe H (259.940 nm)19.711200 ppm 0.133500 0.68 31788.700000 19.711200
K (766.491 nm)209.690000 o ppm 0.593947 0.28 376293.000000 209.690000 o
Li (670.783 nm)0.169594 ppm 0.023341 13.76 2026.490000 0.169594
Mg (279.078 nm)75.699400 o ppm 0.905531 1.20 253186.000000 75.699400 o
Mn (257.610 nm)0.555983 ppm 0.007007 1.26 148353.000000 0.555983
Mo (202.032 nm)0.020797 ppm 0.000182 0.88 106.677000 0.020797
Na (589.592 nm)2430.560000 o ppm 89.8814
00 3.70 29545700.000000 2430.560000 o
Na H (589.593 nm)3248.933946 o ppm 169.756
716 5.23 28533968.931682 3248.933946 o
Ni (231.604 nm)0.145088 ppm 0.002284 1.57 483.829000 0.145088
P (213.618 nm)3.374770 ppm 0.044639 1.32 3986.580000 3.374770
Pb (220.353 nm)0.000588 u ppm 0.001170 > 100.00 -0.465154 0.000588 u
S (181.972 nm)721.843847 bo ppm 9.973835 1.38 147028.398249 721.843847 bo
Sb (206.834 nm)0.001831 ppm 0.001189 64.96 5.953710 0.001831
Se (196.026 nm)0.007419 ppm 0.006151 82.91 7.835020 0.007419
Si (288.158 nm)3.695680 ppm 0.044076 1.19 27574.000000 3.695680
Sn (189.925 nm)0.003051 ppm 0.001236 40.53 4.331180 0.003051
Sr (421.552 nm)0.302315 ppm 0.002347 0.78 66760.707786 0.302315
Th (288.505 nm)0.081983 ppm 0.003510 4.28 420.337000 0.081983
Ti (336.122 nm)0.051256 ppm 0.000774 1.51 5525.380000 0.051256
Tl (190.794 nm)0.000307 u ppm 0.001539 > 100.00 -2.629250 0.000307 u
U (409.013 nm)-0.059521 u ppm 0.002084 3.50 -218.311000 -0.059521 u
V (292.401 nm)0.119658 ppm 0.001539 1.29 4963.580000 0.119658
Zn (206.200 nm)0.084941 ppm 0.001847 2.17 187.328000 0.084941
Zr (343.823 nm)0.008214 ppm 0.000168 2.04 689.060000 0.008214
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 103 of 287
Page 974 of 1261
Solution Name: 320-105980-B-1-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
320-105980-B-1-B @10 11/20/2023 6:41:47 PM 1:25 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.005327 ppm 0.000023 0.42 14097.440779 0.005327
Ag (328.068 nm)0.000577 ppm 0.000306 53.06 3.544300 0.000577
Al (394.401 nm)0.035668 ppm 0.001319 3.70 877.984000 0.035668
Al H (396.152 nm)0.019537 u ppm 0.003005 15.38 138.367000 0.019537 u
As (188.980 nm)0.003265 ppm 0.001287 39.40 -0.691987 0.003265
B (249.678 nm)0.095857 ppm 0.000389 0.41 818.469000 0.095857
Ba (493.408 nm)0.002812 ppm 0.000069 2.44 425.530000 0.002812
Be (234.861 nm)0.000099 ppm 0.000038 38.81 57.381900 0.000099
Bi (223.061 nm)0.001565 u ppm 0.002450 > 100.00 6.411760 0.001565 u
Ca (315.887 nm)30.227939 o ppm 0.066043 0.22 20362.286464 30.227939 o
Cd (214.439 nm)0.000302 ppm 0.000125 41.43 4.604280 0.000302
Co (228.615 nm)0.000051 u ppm 0.000216 > 100.00 43.873000 0.000051 u
Cr (205.560 nm)0.000209 ppm 0.000200 95.88 2.379710 0.000209
Cu (324.754 nm)0.000719 ppm 0.000350 48.63 789.910000 0.000719
Fe (238.204 nm)0.079734 ppm 0.001206 1.51 330.482577 0.079734
Fe H (259.940 nm)0.167573 u ppm 0.001726 1.03 132.604000 0.167573 u
K (766.491 nm)8.485320 ppm 0.054983 0.65 14797.800000 8.485320
Li (670.783 nm)-0.001474 u ppm 0.014127 > 100.00 -4335.430000 -0.001474 u
Mg (279.078 nm)34.497600 ppm 0.054880 0.16 115392.000000 34.497600
Mn (257.610 nm)0.005722 ppm 0.000026 0.46 1531.230000 0.005722
Mo (202.032 nm)0.000925 ppm 0.000381 41.17 8.069200 0.000925
Na (589.592 nm)130.841000 o ppm 0.796414 0.61 1591470.000000 130.841000 o
Na H (589.593 nm)103.655603 ppm 2.310155 2.23 999119.873317 103.655603
Ni (231.604 nm)-0.002808 u ppm 0.000553 19.69 -19.769800 -0.002808 u
P (213.618 nm)0.021363 ppm 0.001604 7.51 28.247500 0.021363
Pb (220.353 nm)-0.000353 u ppm 0.001461 > 100.00 -2.444300 -0.000353 u
S (181.972 nm)31.078498 o ppm 0.124499 0.40 6353.756251 31.078498 o
Sb (206.834 nm)-0.003197 u ppm 0.003010 94.15 -1.888080 -0.003197 u
Se (196.026 nm)-0.000394 u ppm 0.005349 > 100.00 4.769120 -0.000394 u
Si (288.158 nm)0.978355 ppm 0.000918 0.09 7820.570000 0.978355
Sn (189.925 nm)0.000811 u ppm 0.001703 > 100.00 2.825600 0.000811 u
Sr (421.552 nm)0.313901 ppm 0.003184 1.01 69318.937812 0.313901
Th (288.505 nm)0.036526 ppm 0.003145 8.61 329.463000 0.036526
Ti (336.122 nm)0.001018 ppm 0.000074 7.30 59.121400 0.001018
Tl (190.794 nm)0.002428 ppm 0.001028 42.34 0.144156 0.002428
U (409.013 nm)0.005369 ppm 0.001106 20.60 47.851600 0.005369
V (292.401 nm)0.000557 ppm 0.000237 42.58 -12.381800 0.000557
Zn (206.200 nm)0.001048 ppm 0.000687 65.56 6.423020 0.001048
Zr (343.823 nm)0.000062 ppm 0.000050 80.07 -2.452510 0.000062
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 104 of 287
Page 975 of 1261
Solution Name: 320-105980-B-2-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
320-105980-B-2-B @10 11/20/2023 6:46:05 PM 1:26 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.004796 ppm 0.000010 0.20 12463.279844 0.004796
Ag (328.068 nm)0.000518 ppm 0.000221 42.69 -0.687532 0.000518
Al (394.401 nm)0.124971 ppm 0.000128 0.10 1981.520000 0.124971
Al H (396.152 nm)0.107150 u ppm 0.001964 1.83 532.118000 0.107150 u
As (188.980 nm)0.002701 ppm 0.000657 24.34 -1.163730 0.002701
B (249.678 nm)0.107818 ppm 0.000867 0.80 918.583000 0.107818
Ba (493.408 nm)0.002569 ppm 0.000063 2.46 389.670000 0.002569
Be (234.861 nm)0.000075 ppm 0.000020 27.04 57.649200 0.000075
Bi (223.061 nm)-0.000668 u ppm 0.002452 > 100.00 3.092380 -0.000668 u
Ca (315.887 nm)15.083511 o ppm 0.042045 0.28 10148.594874 15.083511 o
Cd (214.439 nm)0.000168 ppm 0.000091 54.09 2.665660 0.000168
Co (228.615 nm)0.000220 u ppm 0.000284 > 100.00 47.188700 0.000220 u
Cr (205.560 nm)0.001019 ppm 0.000436 42.76 5.714460 0.001019
Cu (324.754 nm)0.001030 ppm 0.000030 2.92 810.322000 0.001030
Fe (238.204 nm)0.402211 ppm 0.002019 0.50 1599.868850 0.402211
Fe H (259.940 nm)0.485126 u ppm 0.004073 0.84 646.966000 0.485126 u
K (766.491 nm)9.042820 ppm 0.120964 1.34 15799.400000 9.042820
Li (670.783 nm)-0.027772 u ppm 0.031876 > 100.00 -5313.420000 -0.027772 u
Mg (279.078 nm)18.545100 ppm 0.015373 0.08 62035.900000 18.545100
Mn (257.610 nm)0.052168 ppm 0.000052 0.10 13924.000000 0.052168
Mo (202.032 nm)0.000962 ppm 0.000290 30.11 8.252140 0.000962
Na (589.592 nm)159.263000 o ppm 3.763410 2.36 1936930.000000 159.263000 o
Na H (589.593 nm)124.318068 ppm 25.9474
21 20.87 1180001.367109 124.318068
Ni (231.604 nm)-0.000680 u ppm 0.000772 > 100.00 -12.527900 -0.000680 u
P (213.618 nm)0.068231 ppm 0.001989 2.91 83.577200 0.068231
Pb (220.353 nm)-0.000672 u ppm 0.000879 > 100.00 -3.192770 -0.000672 u
S (181.972 nm)24.011488 o ppm 0.063558 0.26 4914.338613 24.011488 o
Sb (206.834 nm)0.000428 u ppm 0.002251 > 100.00 2.549020 0.000428 u
Se (196.026 nm)0.000270 u ppm 0.002048 > 100.00 5.173420 0.000270 u
Si (288.158 nm)1.587230 ppm 0.002818 0.18 12244.200000 1.587230
Sn (189.925 nm)-0.001407 u ppm 0.001367 97.14 1.335510 -0.001407 u
Sr (421.552 nm)0.179004 ppm 0.001136 0.63 39533.697328 0.179004
Th (288.505 nm)0.027621 ppm 0.003333 12.07 313.456000 0.027621
Ti (336.122 nm)0.004167 ppm 0.000103 2.46 369.481000 0.004167
Tl (190.794 nm)-0.000448 u ppm 0.002199 > 100.00 -2.988780 -0.000448 u
U (409.013 nm)0.001503 u ppm 0.002496 > 100.00 30.854000 0.001503 u
V (292.401 nm)0.000660 ppm 0.000149 22.57 -9.613800 0.000660
Zn (206.200 nm)0.001828 ppm 0.000680 37.17 8.104660 0.001828
Zr (343.823 nm)0.000129 ppm 0.000077 59.92 3.414300 0.000129
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 105 of 287
Page 976 of 1261
Solution Name: 320-105980-B-5-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
320-105980-B-5-B @10 11/20/2023 6:50:21 PM 1:27 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.004137 ppm 0.000014 0.34 10775.715784 0.004137
Ag (328.068 nm)0.000572 ppm 0.000162 28.41 0.960617 0.000572
Al (394.401 nm)0.025012 ppm 0.000667 2.67 758.770000 0.025012
Al H (396.152 nm)0.008999 u ppm 0.002874 31.93 91.009100 0.008999 u
As (188.980 nm)0.002091 ppm 0.001297 62.06 -1.667860 0.002091
B (249.678 nm)0.060381 ppm 0.000385 0.64 521.547000 0.060381
Ba (493.408 nm)0.002898 ppm 0.000224 7.75 438.397000 0.002898
Be (234.861 nm)0.000055 ppm 0.000030 55.55 49.646500 0.000055
Bi (223.061 nm)-0.001224 u ppm 0.002815 > 100.00 2.264930 -0.001224 u
Ca (315.887 nm)27.028924 o ppm 0.097181 0.36 18204.809787 27.028924 o
Cd (214.439 nm)0.000013 u ppm 0.000110 > 100.00 0.276128 0.000013 u
Co (228.615 nm)-0.000208 u ppm 0.000213 > 100.00 38.914500 -0.000208 u
Cr (205.560 nm)0.001222 ppm 0.000208 17.01 6.548080 0.001222
Cu (324.754 nm)0.000477 ppm 0.000103 21.66 771.371000 0.000477
Fe (238.204 nm)0.051290 ppm 0.001526 2.98 218.508496 0.051290
Fe H (259.940 nm)0.139289 u ppm 0.001531 1.10 86.790400 0.139289 u
K (766.491 nm)5.276220 ppm 0.053811 1.02 9032.120000 5.276220
Li (670.783 nm)-0.035139 u ppm 0.056010 > 100.00 -5587.410000 -0.035139 u
Mg (279.078 nm)18.125000 ppm 0.118904 0.66 60631.400000 18.125000
Mn (257.610 nm)0.004502 ppm 0.000051 1.13 1205.820000 0.004502
Mo (202.032 nm)0.000636 ppm 0.000232 36.57 6.631940 0.000636
Na (589.592 nm)85.459900 o ppm 1.777770 2.08 1039850.000000 85.459900 o
Na H (589.593 nm)86.620292 ppm 10.1121
12 11.67 849991.537198 86.620292
Ni (231.604 nm)-0.001538 u ppm 0.000493 32.04 -15.446100 -0.001538 u
P (213.618 nm)0.017846 ppm 0.003605 20.20 24.144300 0.017846
Pb (220.353 nm)-0.000089 u ppm 0.000553 > 100.00 -1.826210 -0.000089 u
S (181.972 nm)27.448706 o ppm 0.304917 1.11 5614.496487 27.448706 o
Sb (206.834 nm)-0.000296 u ppm 0.001735 > 100.00 1.652070 -0.000296 u
Se (196.026 nm)0.002690 u ppm 0.003502 > 100.00 6.663600 0.002690 u
Si (288.158 nm)1.013640 ppm 0.007128 0.70 8076.980000 1.013640
Sn (189.925 nm)0.001357 ppm 0.000978 72.07 3.192540 0.001357
Sr (421.552 nm)0.241279 ppm 0.000716 0.30 53284.017550 0.241279
Th (288.505 nm)0.024039 ppm 0.003211 13.36 305.826000 0.024039
Ti (336.122 nm)0.000560 ppm 0.000038 6.74 2.152210 0.000560
Tl (190.794 nm)0.001132 u ppm 0.001482 > 100.00 -1.261530 0.001132 u
U (409.013 nm)0.008071 ppm 0.000683 8.46 59.078600 0.008071
V (292.401 nm)0.000770 ppm 0.000163 21.15 -7.465530 0.000770
Zn (206.200 nm)0.001565 ppm 0.000268 17.10 7.536640 0.001565
Zr (343.823 nm)0.000099 ppm 0.000038 38.65 0.515468 0.000099
Test Report
52A112023.esws
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Page 977 of 1261
Solution Name: 320-105980-B-6-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
320-105980-B-6-B @10 11/20/2023 6:54:41 PM 1:28 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.003678 ppm 0.000039 1.05 9456.686022 0.003678
Ag (328.068 nm)0.000072 u ppm 0.000154 > 100.00 -24.083100 0.000072 u
Al (394.401 nm)0.045796 ppm 0.000626 1.37 1004.710000 0.045796
Al H (396.152 nm)0.035801 u ppm 0.004130 11.54 211.459000 0.035801 u
As (188.980 nm)0.004139 ppm 0.002425 58.58 0.032253 0.004139
B (249.678 nm)0.115641 ppm 0.001034 0.89 984.057000 0.115641
Ba (493.408 nm)0.002528 ppm 0.000066 2.60 383.038000 0.002528
Be (234.861 nm)0.000063 ppm 0.000018 29.20 53.635600 0.000063
Bi (223.061 nm)-0.001844 u ppm 0.000996 54.02 1.342900 -0.001844 u
Ca (315.887 nm)7.580024 ppm 0.030024 0.40 5088.100572 7.580024
Cd (214.439 nm)0.000074 u ppm 0.000264 > 100.00 1.237040 0.000074 u
Co (228.615 nm)0.000104 ppm 0.000049 46.47 44.913700 0.000104
Cr (205.560 nm)0.000688 ppm 0.000092 13.45 4.350730 0.000688
Cu (324.754 nm)0.000807 ppm 0.000251 31.14 806.219000 0.000807
Fe (238.204 nm)0.248073 ppm 0.000356 0.14 993.125220 0.248073
Fe H (259.940 nm)0.332759 u ppm 0.002752 0.83 400.167000 0.332759 u
K (766.491 nm)7.954460 ppm 0.010001 0.13 13844.000000 7.954460
Li (670.783 nm)-0.020162 u ppm 0.039154 > 100.00 -5030.430000 -0.020162 u
Mg (279.078 nm)13.725900 ppm 0.087078 0.63 45917.000000 13.725900
Mn (257.610 nm)0.079055 ppm 0.000583 0.74 21098.100000 0.079055
Mo (202.032 nm)0.000760 ppm 0.000201 26.49 7.247770 0.000760
Na (589.592 nm)148.367000 o ppm 0.861731 0.58 1804490.000000 148.367000 o
Na H (589.593 nm)147.086142 ppm 13.8094
17 9.39 1379316.411616 147.086142
Ni (231.604 nm)-0.001206 u ppm 0.000601 49.87 -14.316700 -0.001206 u
P (213.618 nm)0.175813 ppm 0.002049 1.17 210.602000 0.175813
Pb (220.353 nm)0.000924 u ppm 0.002510 > 100.00 0.480783 0.000924 u
S (181.972 nm)19.183363 o ppm 0.183100 0.95 3930.980517 19.183363 o
Sb (206.834 nm)-0.000301 u ppm 0.002781 > 100.00 1.653980 -0.000301 u
Se (196.026 nm)0.003620 ppm 0.003074 84.92 7.263430 0.003620
Si (288.158 nm)1.680950 ppm 0.012298 0.73 12925.100000 1.680950
Sn (189.925 nm)-0.000410 u ppm 0.002132 > 100.00 2.005600 -0.000410 u
Sr (421.552 nm)0.102235 ppm 0.001284 1.26 22583.082069 0.102235
Th (288.505 nm)0.025192 ppm 0.000272 1.08 309.388000 0.025192
Ti (336.122 nm)0.002205 ppm 0.000062 2.80 139.030000 0.002205
Tl (190.794 nm)0.000717 u ppm 0.001542 > 100.00 -1.717720 0.000717 u
U (409.013 nm)-0.002178 u ppm 0.002439 > 100.00 14.611100 -0.002178 u
V (292.401 nm)0.000131 ppm 0.000057 43.40 -30.900900 0.000131
Zn (206.200 nm)0.003193 ppm 0.000702 22.00 11.048300 0.003193
Zr (343.823 nm)0.000088 u ppm 0.000109 > 100.00 -0.162987 0.000088 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 107 of 287
Page 978 of 1261
Solution Name: 280-184055-B-1-A @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184055-B-1-A @10 11/20/2023 6:59:03 PM 1:29 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.027279 b ppm 0.000476 1.74 72380.849777 0.027279 b
Ag (328.068 nm)0.000398 ppm 0.000266 66.72 -9.871800 0.000398
Al (394.401 nm)0.031544 ppm 0.000683 2.16 831.150000 0.031544
Al H (396.152 nm)0.012778 u ppm 0.003363 26.32 107.990000 0.012778 u
As (188.980 nm)0.003408 ppm 0.001426 41.84 -0.572760 0.003408
B (249.678 nm)0.391720 ppm 0.004246 1.08 3294.750000 0.391720
Ba (493.408 nm)0.006926 ppm 0.000080 1.16 1048.430000 0.006926
Be (234.861 nm)0.000048 ppm 0.000024 49.96 48.115500 0.000048
Bi (223.061 nm)-0.000545 u ppm 0.002664 > 100.00 3.275080 -0.000545 u
Ca (315.887 nm)36.731191 o ppm 0.050445 0.14 24748.204080 36.731191 o
Cd (214.439 nm)0.000329 ppm 0.000113 34.48 5.000060 0.000329
Co (228.615 nm)-0.000282 u ppm 0.000251 88.87 37.483100 -0.000282 u
Cr (205.560 nm)0.000644 u ppm 0.000570 88.46 3.825200 0.000644 u
Cu (324.754 nm)0.000739 ppm 0.000160 21.66 783.657000 0.000739
Fe (238.204 nm)0.021680 ppm 0.000484 2.23 101.957731 0.021680
Fe H (259.940 nm)0.110964 u ppm 0.001191 1.07 40.910100 0.110964 u
K (766.491 nm)32.730600 ppm 0.190317 0.58 58358.000000 32.730600
Li (670.783 nm)0.002899 u ppm 0.036494 > 100.00 -4172.800000 0.002899 u
Mg (279.078 nm)2.525990 ppm 0.039452 1.56 8457.010000 2.525990
Mn (257.610 nm)0.000955 ppm 0.000038 3.95 259.374000 0.000955
Mo (202.032 nm)0.113044 ppm 0.001748 1.55 564.411000 0.113044
Na (589.592 nm)204.857000 o ppm 1.962550 0.96 2491190.000000 204.857000 o
Na H (589.593 nm)212.445216 ppm 16.9419
41 7.97 1951519.719293 212.445216
Ni (231.604 nm)-0.000162 u ppm 0.000799 > 100.00 -10.761700 -0.000162 u
P (213.618 nm)0.005107 ppm 0.001317 25.78 5.912810 0.005107
Pb (220.353 nm)-0.001127 u ppm 0.000216 19.13 -4.437400 -0.001127 u
S (181.972 nm)153.176358 bo ppm 2.399469 1.57 31218.944733 153.176358 bo
Sb (206.834 nm)0.000483 u ppm 0.001646 > 100.00 2.064000 0.000483 u
Se (196.026 nm)0.003595 ppm 0.003543 98.55 7.219820 0.003595
Si (288.158 nm)0.713067 ppm 0.010016 1.40 5892.540000 0.713067
Sn (189.925 nm)-0.000650 u ppm 0.000672 > 100.00 1.844110 -0.000650 u
Sr (421.552 nm)1.687598 o ppm 0.011679 0.69 372630.416553 1.687598 o
Th (288.505 nm)0.016568 ppm 0.002217 13.38 291.318000 0.016568
Ti (336.122 nm)0.000379 ppm 0.000062 16.28 3.645490 0.000379
Tl (190.794 nm)0.002144 ppm 0.000505 23.56 -0.447812 0.002144
U (409.013 nm)-0.000487 u ppm 0.003866 > 100.00 21.747200 -0.000487 u
V (292.401 nm)0.005015 ppm 0.000118 2.34 168.451000 0.005015
Zn (206.200 nm)0.000579 ppm 0.000353 61.03 5.410690 0.000579
Zr (343.823 nm)0.000064 u ppm 0.000075 > 100.00 -2.388650 0.000064 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 108 of 287
Page 979 of 1261
Solution Name: MB 280-634101/1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
MB 280-634101/1-A 11/20/2023 7:03:21 PM 3:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000362 ppm 0.000009 2.51 343.148598 0.000362
Ag (328.068 nm)-0.000027 u ppm 0.000130 > 100.00 -30.773800 -0.000027 u
Al (394.401 nm)0.024926 ppm 0.000824 3.31 757.540000 0.024926
Al H (396.152 nm)0.025364 u ppm 0.004287 16.90 164.554000 0.025364 u
As (188.980 nm)0.001671 ppm 0.000830 49.65 -2.017060 0.001671
B (249.678 nm)0.029366 ppm 0.000780 2.66 261.967000 0.029366
Ba (493.408 nm)0.000799 ppm 0.000061 7.64 120.725000 0.000799
Be (234.861 nm)-0.000043 u ppm 0.000018 42.50 33.959700 -0.000043 u
Bi (223.061 nm)0.000527 u ppm 0.000819 > 100.00 4.869330 0.000527 u
Ca (315.887 nm)0.056969 ppm 0.006349 11.15 14.408171 0.056969
Cd (214.439 nm)0.000143 ppm 0.000055 38.33 2.229280 0.000143
Co (228.615 nm)0.000033 ppm 0.000057 > 100.00 43.508200 0.000033
Cr (205.560 nm)0.001824 ppm 0.000197 10.83 9.024420 0.001824
Cu (324.754 nm)0.004548 ppm 0.000266 5.84 977.846000 0.004548
Fe (238.204 nm)0.104599 ppm 0.001320 1.26 428.351055 0.104599
Fe H (259.940 nm)0.193114 u ppm 0.001978 1.02 173.975000 0.193114 u
K (766.491 nm)0.031801 ppm 0.032601 > 100.00 -390.278000 0.031801
Li (670.783 nm)0.005100 ppm 0.001025 20.09 -4090.930000 0.005100
Mg (279.078 nm)0.006276 ppm 0.000451 7.19 29.842400 0.006276
Mn (257.610 nm)0.000995 ppm 0.000004 0.42 269.884000 0.000995
Mo (202.032 nm)0.000929 ppm 0.000350 37.65 8.088350 0.000929
Na (589.592 nm)0.352993 ppm 0.011669 3.31 5337.510000 0.352993
Na H (589.593 nm)-9.552111 u ppm 0.010947 0.11 8061.989676 -9.552111 u
Ni (231.604 nm)0.000137 u ppm 0.000325 > 100.00 -9.741770 0.000137 u
P (213.618 nm)0.011783 ppm 0.000950 8.06 16.779800 0.011783
Pb (220.353 nm)0.001393 ppm 0.000859 61.65 1.573280 0.001393
S (181.972 nm)0.020034 ppm 0.005172 25.81 28.158208 0.020034
Sb (206.834 nm)-0.001525 u ppm 0.004740 > 100.00 0.154281 -0.001525 u
Se (196.026 nm)0.003417 u ppm 0.005206 > 100.00 7.101850 0.003417 u
Si (288.158 nm)0.148856 ppm 0.000897 0.60 1797.730000 0.148856
Sn (189.925 nm)0.015057 ppm 0.001667 11.07 12.399100 0.015057
Sr (421.552 nm)0.000264 ppm 0.000050 19.02 67.905214 0.000264
Th (288.505 nm)0.002285 u ppm 0.003993 > 100.00 264.822000 0.002285 u
Ti (336.122 nm)0.000351 ppm 0.000102 29.04 -79.714900 0.000351
Tl (190.794 nm)0.001408 u ppm 0.002746 > 100.00 -0.963668 0.001408 u
U (409.013 nm)-0.002767 u ppm 0.004880 > 100.00 11.371500 -0.002767 u
V (292.401 nm)0.000148 u ppm 0.000232 > 100.00 -33.655000 0.000148 u
Zn (206.200 nm)0.014980 ppm 0.001203 8.03 36.465100 0.014980
Zr (343.823 nm)0.000304 ppm 0.000138 45.34 17.304400 0.000304
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 109 of 287
Page 980 of 1261
Solution Name: LCS 280-634101/2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634101/2-A 11/20/2023 7:07:38 PM 3:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.953140 ppm 0.006906 0.72 2445042.717083 0.953140
Ag (328.068 nm)0.050166 ppm 0.000529 1.05 2184.150000 0.050166
Al (394.401 nm)9.997050 o ppm 0.064651 0.65 123461.000000 9.997050 o
Al H (396.152 nm)9.676420 ppm 0.043537 0.45 43538.400000 9.676420
As (188.980 nm)1.004920 ppm 0.004258 0.42 831.452000 1.004920
B (249.678 nm)2.029560 ppm 0.013331 0.66 17002.900000 2.029560
Ba (493.408 nm)1.010280 ppm 0.004462 0.44 153045.000000 1.010280
Be (234.861 nm)0.998054 ppm 0.006346 0.64 166945.000000 0.998054
Bi (223.061 nm)-0.000230 u ppm 0.002680 > 100.00 3.742930 -0.000230 u
Ca (315.887 nm)50.347760 o ppm 0.198520 0.39 33931.477957 50.347760 o
Cd (214.439 nm)0.988175 ppm 0.006311 0.64 14772.700000 0.988175
Co (228.615 nm)0.981631 ppm 0.006528 0.67 18801.900000 0.981631
Cr (205.560 nm)1.004590 ppm 0.005776 0.57 4130.610000 1.004590
Cu (324.754 nm)0.979337 ppm 0.011043 1.13 46435.900000 0.979337
Fe (238.204 nm)12.123217 o ppm 0.032048 0.26 47750.830907 12.123217 o
Fe H (259.940 nm)11.937200 ppm 0.024967 0.21 19196.700000 11.937200
K (766.491 nm)50.765800 ppm 0.134347 0.26 90761.100000 50.765800
Li (670.783 nm)0.989361 ppm 0.003708 0.37 32513.200000 0.989361
Mg (279.078 nm)50.728500 o ppm 0.284033 0.56 169672.000000 50.728500 o
Mn (257.610 nm)1.010830 ppm 0.005731 0.57 269715.000000 1.010830
Mo (202.032 nm)1.009350 ppm 0.005088 0.50 5011.930000 1.009350
Na (589.592 nm)49.310500 ppm 0.264686 0.54 612264.000000 49.310500
Na H (589.593 nm)39.884511 u ppm 1.182717 2.97 449586.188542 39.884511 u
Ni (231.604 nm)0.970331 ppm 0.005075 0.52 3294.600000 0.970331
P (213.618 nm)20.037000 o ppm 0.134257 0.67 23578.900000 20.037000 o
Pb (220.353 nm)1.072890 ppm 0.007651 0.71 2458.940000 1.072890
S (181.972 nm)18.483825 o ppm 0.133601 0.72 3793.105646 18.483825 o
Sb (206.834 nm)1.031920 ppm 0.011403 1.10 1259.010000 1.031920
Se (196.026 nm)0.962103 ppm 0.015522 1.61 594.824000 0.962103
Si (288.158 nm)7.003890 ppm 0.065226 0.93 52089.400000 7.003890
Sn (189.925 nm)1.007250 ppm 0.006047 0.60 679.139000 1.007250
Sr (421.552 nm)0.995073 ppm 0.004736 0.48 219721.333880 0.995073
Th (288.505 nm)0.065404 ppm 0.002742 4.19 359.544000 0.065404
Ti (336.122 nm)1.004570 ppm 0.006162 0.61 109610.000000 1.004570
Tl (190.794 nm)0.980444 ppm 0.004228 0.43 1059.650000 0.980444
U (409.013 nm)-0.008564 u ppm 0.002407 28.10 -33.529300 -0.008564 u
V (292.401 nm)1.001930 ppm 0.006406 0.64 41686.000000 1.001930
Zn (206.200 nm)1.218300 o ppm 0.004132 0.34 2631.270000 1.218300 o
Zr (343.823 nm)0.997641 ppm 0.006454 0.65 81335.800000 0.997641
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 110 of 287
Page 981 of 1261
Solution Name: LCSD 280-634101/3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCSD 280-634101/3-A 11/20/2023 7:12:07 PM 3:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.884224 ppm 0.004295 0.49 2268240.946481 0.884224
Ag (328.068 nm)0.047193 ppm 0.000217 0.46 2054.050000 0.047193
Al (394.401 nm)9.324300 o ppm 0.035618 0.38 115185.000000 9.324300 o
Al H (396.152 nm)9.096220 ppm 0.018398 0.20 40930.800000 9.096220
As (188.980 nm)0.948486 ppm 0.004994 0.53 784.586000 0.948486
B (249.678 nm)1.900960 ppm 0.009240 0.49 15926.600000 1.900960
Ba (493.408 nm)0.934363 ppm 0.000842 0.09 141539.000000 0.934363
Be (234.861 nm)0.937322 ppm 0.006582 0.70 156764.000000 0.937322
Bi (223.061 nm)0.000056 u ppm 0.001545 > 100.00 4.167720 0.000056 u
Ca (315.887 nm)47.348646 o ppm 0.122647 0.26 31908.818274 47.348646 o
Cd (214.439 nm)0.927937 ppm 0.006524 0.70 13871.800000 0.927937
Co (228.615 nm)0.920819 ppm 0.005171 0.56 17639.600000 0.920819
Cr (205.560 nm)0.939038 ppm 0.005608 0.60 3861.160000 0.939038
Cu (324.754 nm)0.919076 ppm 0.006210 0.68 43622.100000 0.919076
Fe (238.204 nm)9.493473 o ppm 0.036441 0.38 37398.332518 9.493473 o
Fe H (259.940 nm)9.331540 ppm 0.012726 0.14 14976.100000 9.331540
K (766.491 nm)47.897300 ppm 0.376789 0.79 85607.400000 47.897300
Li (670.783 nm)0.930232 ppm 0.003490 0.38 30314.200000 0.930232
Mg (279.078 nm)47.514000 o ppm 0.316685 0.67 158923.000000 47.514000 o
Mn (257.610 nm)0.939276 ppm 0.005254 0.56 250623.000000 0.939276
Mo (202.032 nm)0.947833 ppm 0.006047 0.64 4706.700000 0.947833
Na (589.592 nm)46.479600 ppm 0.370247 0.80 576962.000000 46.479600
Na H (589.593 nm)36.740053 u ppm 0.342019 0.93 421400.491216 36.740053 u
Ni (231.604 nm)0.908672 ppm 0.005795 0.64 3084.610000 0.908672
P (213.618 nm)18.828900 o ppm 0.133764 0.71 22157.500000 18.828900 o
Pb (220.353 nm)0.982963 ppm 0.005965 0.61 2252.580000 0.982963
S (181.972 nm)17.293336 o ppm 0.116330 0.67 3550.303936 17.293336 o
Sb (206.834 nm)0.969123 ppm 0.005508 0.57 1182.370000 0.969123
Se (196.026 nm)0.907506 ppm 0.004860 0.54 561.548000 0.907506
Si (288.158 nm)6.099650 ppm 0.020791 0.34 45488.500000 6.099650
Sn (189.925 nm)0.945177 ppm 0.011351 1.20 637.427000 0.945177
Sr (421.552 nm)0.936564 ppm 0.000764 0.08 206802.495061 0.936564
Th (288.505 nm)0.061801 ppm 0.001326 2.15 354.177000 0.061801
Ti (336.122 nm)0.938098 ppm 0.004809 0.51 102350.000000 0.938098
Tl (190.794 nm)0.925085 ppm 0.008907 0.96 999.735000 0.925085
U (409.013 nm)-0.006209 u ppm 0.001726 27.81 -23.871900 -0.006209 u
V (292.401 nm)0.939892 ppm 0.005003 0.53 39102.700000 0.939892
Zn (206.200 nm)0.932291 ppm 0.009081 0.97 2014.520000 0.932291
Zr (343.823 nm)0.935825 ppm 0.004772 0.51 76293.000000 0.935825
Test Report
52A112023.esws
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Page 982 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 7:16:36 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000054 u ppm 0.000016 30.28 796.591386 -0.000054 u
Ag (328.068 nm)-0.000245 u ppm 0.000355 > 100.00 100.655000 -0.000245 u
Al (394.401 nm)52.221700 o ppm 0.251084 0.48 641996.000000 52.221700 o
Al H (396.152 nm)48.927200 ppm 0.195841 0.40 219939.000000 48.927200
As (188.980 nm)0.000648 ppm 0.000422 65.11 -3.313740 0.000648
B (249.678 nm)0.000939 u ppm 0.001324 > 100.00 24.039700 0.000939 u
Ba (493.408 nm)0.000305 ppm 0.000196 64.21 186.519000 0.000305
Be (234.861 nm)0.000117 ppm 0.000002 1.68 705.553000 0.000117
Bi (223.061 nm)-0.000690 u ppm 0.000889 > 100.00 3.059890 -0.000690 u
Ca (315.887 nm)-0.015635 u ppm 0.008586 54.92 -34.556869 -0.015635 u
Cd (214.439 nm)-0.000011 u ppm 0.000144 > 100.00 10.155400 -0.000011 u
Co (228.615 nm)0.000435 ppm 0.000109 25.12 51.169200 0.000435
Cr (205.560 nm)0.001240 ppm 0.000586 47.25 6.624610 0.001240
Cu (324.754 nm)-0.000662 u ppm 0.000068 10.22 1679.210000 -0.000662 u
Fe (238.204 nm)50.147527 o ppm 0.130594 0.26 197417.782790 50.147527 o
Fe H (259.940 nm)48.639300 ppm 0.099852 0.21 78645.700000 48.639300
K (766.491 nm)0.055382 ppm 0.010019 18.09 -347.910000 0.055382
Li (670.783 nm)0.003279 ppm 0.002195 66.96 -4158.670000 0.003279
Mg (279.078 nm)0.002686 ppm 0.003053 > 100.00 -171.719000 0.002686
Mn (257.610 nm)-0.000894 u ppm 0.000021 2.35 -233.957000 -0.000894 u
Mo (202.032 nm)0.000765 ppm 0.000337 44.00 7.274990 0.000765
Na (589.592 nm)246.701000 o ppm 0.945711 0.38 2999740.000000 246.701000 o
Na H (589.593 nm)236.925700 ppm 3.949052 1.67 2165770.559823 236.925700
Ni (231.604 nm)-0.000393 u ppm 0.000856 > 100.00 -11.546600 -0.000393 u
P (213.618 nm)4.998050 ppm 0.034718 0.69 5902.740000 4.998050
Pb (220.353 nm)0.001384 ppm 0.000276 19.96 0.016035 0.001384
S (181.972 nm)4.813837 ppm 0.025964 0.54 1006.296146 4.813837
Sb (206.834 nm)0.000593 u ppm 0.001784 > 100.00 6.190410 0.000593 u
Se (196.026 nm)0.005412 ppm 0.003292 60.84 3.079750 0.005412
Si (288.158 nm)0.030040 ppm 0.002039 6.79 930.340000 0.030040
Sn (189.925 nm)0.000792 u ppm 0.000771 97.39 2.813160 0.000792 u
Sr (421.552 nm)0.000513 ppm 0.000035 6.80 122.908975 0.000513
Th (288.505 nm)4.686190 ppm 0.018368 0.39 9018.070000 4.686190
Ti (336.122 nm)0.000931 ppm 0.000029 3.07 -16.443400 0.000931
Tl (190.794 nm)-0.003975 u ppm 0.001270 31.94 -7.707500 -0.003975 u
U (409.013 nm)2.422850 Q ppm 0.010401 0.43 10821.600000 Q 2.422850 Q
V (292.401 nm)0.000461 ppm 0.000032 6.90 261.981000 0.000461
Zn (206.200 nm)0.000256 u ppm 0.000384 > 100.00 4.714810 0.000256 u
Zr (343.823 nm)-0.000518 u ppm 0.000044 8.47 17.923700 -0.000518 u
Test Report
52A112023.esws
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Page 983 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 7:21:01 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.451948 ppm 0.000543 0.12 1158889.224584 0.451948
Ag (328.068 nm)0.502858 ppm 0.001722 0.34 26859.600000 0.502858
Al (394.401 nm)0.493200 ppm 0.001660 0.34 6517.220000 0.493200
Al H (396.152 nm)0.501315 u ppm 0.000679 0.14 2303.580000 0.501315 u
As (188.980 nm)0.498832 ppm 0.002283 0.46 411.041000 0.498832
B (249.678 nm)0.495569 ppm 0.000661 0.13 4163.920000 0.495569
Ba (493.408 nm)0.495379 ppm 0.002109 0.43 75033.500000 0.495379
Be (234.861 nm)0.505606 ppm 0.002158 0.43 84545.300000 0.505606
Bi (223.061 nm)0.994198 ppm 0.000808 0.08 1482.250000 0.994198
Ca (315.887 nm)4.960914 ppm 0.020265 0.41 3321.722494 4.960914
Cd (214.439 nm)0.504514 ppm 0.001248 0.25 7541.490000 0.504514
Co (228.615 nm)0.503535 ppm 0.000222 0.04 9664.690000 0.503535
Cr (205.560 nm)0.509085 ppm 0.000895 0.18 2094.000000 0.509085
Cu (324.754 nm)0.499140 ppm 0.000804 0.16 24049.700000 0.499140
Fe (238.204 nm)2.484973 ppm 0.005490 0.22 9804.752840 2.484973
Fe H (259.940 nm)2.507030 u ppm 0.013506 0.54 3921.990000 2.507030 u
K (766.491 nm)50.108700 ppm 0.102161 0.20 89580.400000 50.108700
Li (670.783 nm)0.492390 ppm 0.002912 0.59 14031.100000 0.492390
Mg (279.078 nm)20.037000 ppm 0.021717 0.11 67025.200000 20.037000
Mn (257.610 nm)0.495040 ppm 0.000566 0.11 132092.000000 0.495040
Mo (202.032 nm)0.499615 ppm 0.001191 0.24 2482.610000 0.499615
Na (589.592 nm)24.717100 ppm 0.041700 0.17 307289.000000 24.717100
Na H (589.593 nm)14.419917 u ppm 0.252003 1.75 222203.829172 14.419917 u
Ni (231.604 nm)0.508179 ppm 0.000935 0.18 1720.560000 0.508179
P (213.618 nm)0.009900 ppm 0.003032 30.63 -25.472300 0.009900
Pb (220.353 nm)0.526603 ppm 0.003066 0.58 1206.540000 0.526603
S (181.972 nm)-0.016462 u ppm 0.002109 12.81 23.187859 -0.016462 u
Sb (206.834 nm)0.492608 ppm 0.001645 0.33 601.883000 0.492608
Se (196.026 nm)0.499107 ppm 0.005551 1.11 311.368000 0.499107
Si (288.158 nm)4.942900 ppm 0.020337 0.41 36868.700000 4.942900
Sn (189.925 nm)0.502826 ppm 0.001714 0.34 340.173000 0.502826
Sr (421.552 nm)0.496259 ppm 0.002795 0.56 109583.486720 0.496259
Th (288.505 nm)0.037519 ppm 0.001104 2.94 318.839000 0.037519
Ti (336.122 nm)0.497099 ppm 0.000921 0.19 54135.700000 0.497099
Tl (190.794 nm)0.499451 ppm 0.004848 0.97 538.716000 0.499451
U (409.013 nm)-0.007978 u ppm 0.002578 32.32 -24.677400 -0.007978 u
V (292.401 nm)0.497822 ppm 0.000667 0.13 20689.600000 0.497822
Zn (206.200 nm)0.504208 ppm 0.001746 0.35 1091.420000 0.504208
Zr (343.823 nm)0.491788 ppm 0.001171 0.24 40086.000000 0.491788
Test Report
52A112023.esws
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Page 984 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 7:25:22 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000378 ppm 0.000006 1.57 377.808464 0.000378
Ag (328.068 nm)0.000139 u ppm 0.000151 > 100.00 -21.667300 0.000139 u
Al (394.401 nm)0.000039 u ppm 0.000100 > 100.00 450.596000 0.000039 u
Al H (396.152 nm)0.000757 u ppm 0.002030 > 100.00 53.968300 0.000757 u
As (188.980 nm)0.000875 u ppm 0.001380 > 100.00 -2.677600 0.000875 u
B (249.678 nm)0.001412 ppm 0.000383 27.12 27.998400 0.001412
Ba (493.408 nm)0.000115 u ppm 0.000233 > 100.00 16.824400 0.000115 u
Be (234.861 nm)0.000032 ppm 0.000029 89.47 45.304000 0.000032
Bi (223.061 nm)-0.000538 u ppm 0.001164 > 100.00 3.285060 -0.000538 u
Ca (315.887 nm)0.007982 ppm 0.004754 59.57 -18.629483 0.007982
Cd (214.439 nm)0.000090 ppm 0.000080 88.98 1.420810 0.000090
Co (228.615 nm)0.000130 u ppm 0.000224 > 100.00 45.320200 0.000130 u
Cr (205.560 nm)-0.000267 u ppm 0.000116 43.51 0.423923 -0.000267 u
Cu (324.754 nm)0.000617 ppm 0.000181 29.40 794.925000 0.000617
Fe (238.204 nm)0.001716 ppm 0.000094 5.49 23.348719 0.001716
Fe H (259.940 nm)0.095055 u ppm 0.000552 0.58 15.140900 0.095055 u
K (766.491 nm)0.007664 u ppm 0.045851 > 100.00 -433.642000 0.007664 u
Li (670.783 nm)0.002788 S ppm 0.002288 82.06 -4176.920000 S 0.002788 S
Mg (279.078 nm)-0.000673 u ppm 0.000309 45.99 6.567600 -0.000673 u
Mn (257.610 nm)-0.000029 u ppm 0.000016 55.86 -3.307840 -0.000029 u
Mo (202.032 nm)0.001035 ppm 0.000635 61.31 8.614020 0.001035
Na (589.592 nm)0.136370 ppm 0.015632 11.46 2697.160000 0.136370
Na H (589.593 nm)-9.881943 u ppm 0.010040 0.10 5169.221389 -9.881943 u
Ni (231.604 nm)-0.000214 u ppm 0.000304 > 100.00 -10.938200 -0.000214 u
P (213.618 nm)-0.002960 u ppm 0.001814 61.29 -0.428792 -0.002960 u
Pb (220.353 nm)-0.000884 u ppm 0.000411 46.54 -3.653510 -0.000884 u
S (181.972 nm)-0.031251 u ppm 0.004841 15.49 17.703787 -0.031251 u
Sb (206.834 nm)0.000228 u ppm 0.001809 > 100.00 2.278170 0.000228 u
Se (196.026 nm)0.005157 ppm 0.002277 44.15 8.179890 0.005157
Si (288.158 nm)0.001114 ppm 0.000864 77.53 719.689000 0.001114
Sn (189.925 nm)-0.000521 u ppm 0.000829 > 100.00 1.930850 -0.000521 u
Sr (421.552 nm)0.000045 u ppm 0.000072 > 100.00 19.704678 0.000045 u
Th (288.505 nm)0.008595 Z ppm 0.003086 35.91 276.580000 Z 0.008595 Z
Ti (336.122 nm)0.000021 u ppm 0.000050 > 100.00 -115.755000 0.000021 u
Tl (190.794 nm)0.002487 ppm 0.001524 61.27 0.210222 0.002487
U (409.013 nm)0.000121 u ppm 0.004275 > 100.00 24.042700 0.000121 u
V (292.401 nm)0.000058 u ppm 0.000360 > 100.00 -36.677300 0.000058 u
Zn (206.200 nm)-0.000953 u ppm 0.000848 88.97 2.108690 -0.000953 u
Zr (343.823 nm)0.000116 ppm 0.000049 42.13 1.788820 0.000116
Test Report
52A112023.esws
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Page 985 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 7:29:24 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014307 ppm 0.000013 0.09 36187.740306 0.014307
Ag (328.068 nm)0.009875 ppm 0.000136 1.38 496.388000 0.009875
Al (394.401 nm)0.089820 ppm 0.000125 0.14 1566.240000 0.089820
Al H (396.152 nm)0.094564 u ppm 0.001626 1.72 475.553000 0.094564 u
As (188.980 nm)0.014485 ppm 0.003803 26.26 8.629550 0.014485
B (249.678 nm)0.096597 ppm 0.000662 0.69 824.665000 0.096597
Ba (493.408 nm)0.009871 ppm 0.000279 2.83 1494.610000 0.009871
Be (234.861 nm)0.000993 ppm 0.000050 5.08 207.010000 0.000993
Bi (223.061 nm)0.000264 Qu ppm 0.002212 > 100.00 4.477690 Q 0.000264 Qu
Ca (315.887 nm)0.206567 ppm 0.001466 0.71 115.300105 0.206567
Cd (214.439 nm)0.005142 ppm 0.000225 4.38 76.955600 0.005142
Co (228.615 nm)0.010087 ppm 0.000082 0.82 235.556000 0.010087
Cr (205.560 nm)0.009433 ppm 0.000978 10.37 40.228000 0.009433
Cu (324.754 nm)0.014962 ppm 0.000256 1.71 1457.060000 0.014962
Fe (238.204 nm)0.100120 ppm 0.000434 0.43 410.781172 0.100120
Fe H (259.940 nm)0.190674 u ppm 0.002666 1.40 170.022000 0.190674 u
K (766.491 nm)3.008260 ppm 0.032964 1.10 4957.390000 3.008260
Li (670.783 nm)0.024089 ppm 0.000350 1.45 -3384.730000 0.024089
Mg (279.078 nm)0.200081 ppm 0.000878 0.44 677.485000 0.200081
Mn (257.610 nm)0.010117 ppm 0.000027 0.27 2704.020000 0.010117
Mo (202.032 nm)0.020161 ppm 0.000358 1.78 103.520000 0.020161
Na (589.592 nm)1.125640 ppm 0.014822 1.32 14837.400000 1.125640
Na H (589.593 nm)-8.922558 u ppm 0.006903 0.08 13653.195717 -8.922558 u
Ni (231.604 nm)0.041315 ppm 0.000659 1.59 130.483000 0.041315
P (213.618 nm)2.824710 ppm 0.004700 0.17 3336.620000 2.824710
Pb (220.353 nm)0.009971 ppm 0.000417 4.18 21.323600 0.009971
S (181.972 nm)0.063214 Q ppm 0.003480 5.50 37.006111 Q 0.063214 Q
Sb (206.834 nm)0.021709 ppm 0.001221 5.62 28.376700 0.021709
Se (196.026 nm)0.020057 ppm 0.001451 7.24 17.319900 0.020057
Si (288.158 nm)0.467634 ppm 0.005356 1.15 4139.370000 0.467634
Sn (189.925 nm)0.097725 ppm 0.003422 3.50 67.950600 0.097725
Sr (421.552 nm)0.009832 ppm 0.000112 1.14 2180.613044 0.009832
Th (288.505 nm)0.005745 Q ppm 0.001076 18.72 271.361000 Q 0.005745 Q
Ti (336.122 nm)0.009582 ppm 0.000037 0.39 927.854000 0.009582
Tl (190.794 nm)0.016816 ppm 0.001596 9.49 15.725900 0.016816
U (409.013 nm)0.055690 ppm 0.002771 4.98 268.367000 0.055690
V (292.401 nm)0.009530 ppm 0.000142 1.49 352.652000 0.009530
Zn (206.200 nm)0.019572 ppm 0.000853 4.36 46.367800 0.019572
Zr (343.823 nm)0.009794 ppm 0.000020 0.20 790.893000 0.009794
Test Report
52A112023.esws
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Page 986 of 1261
Solution Name: 280-184252-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-1-A 11/20/2023 7:33:43 PM 3:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.026187 ppm 0.000110 0.42 68124.183067 0.026187
Ag (328.068 nm)0.000991 ppm 0.000270 27.30 -21.307300 0.000991
Al (394.401 nm)24.079000 o ppm 0.114343 0.47 296758.000000 24.079000 o
Al H (396.152 nm)23.556600 ppm 0.131911 0.56 105919.000000 23.556600
As (188.980 nm)0.020577 ppm 0.001739 8.45 13.000100 0.020577
B (249.678 nm)0.041415 ppm 0.000154 0.37 362.813000 0.041415
Ba (493.408 nm)0.258462 ppm 0.001134 0.44 39362.400000 0.258462
Be (234.861 nm)0.001074 ppm 0.000080 7.47 1219.020000 0.001074
Bi (223.061 nm)-0.001603 u ppm 0.001175 73.30 1.702340 -0.001603 u
Ca (315.887 nm)124.781747 o ppm 0.731062 0.59 84131.179500 124.781747 o
Cd (214.439 nm)0.002258 ppm 0.000341 15.11 49.678300 0.002258
Co (228.615 nm)0.019184 ppm 0.000316 1.65 444.811000 0.019184
Cr (205.560 nm)0.071095 ppm 0.000507 0.71 293.914000 0.071095
Cu (324.754 nm)0.285704 ppm 0.001339 0.47 14100.900000 0.285704
Fe (238.204 nm)77.605308 o ppm 0.452228 0.58 305502.870149 77.605308 o
Fe H (259.940 nm)75.269700 ppm 0.407780 0.54 121781.000000 75.269700
K (766.491 nm)6.928050 ppm 0.010839 0.16 11999.900000 6.928050
Li (670.783 nm)0.033809 ppm 0.000963 2.85 -3023.260000 0.033809
Mg (279.078 nm)19.038900 ppm 0.074967 0.39 63638.500000 19.038900
Mn (257.610 nm)1.043210 ppm 0.003843 0.37 278356.000000 1.043210
Mo (202.032 nm)0.013374 ppm 0.000311 2.32 69.840200 0.013374
Na (589.592 nm)0.651551 ppm 0.006205 0.95 12005.600000 0.651551
Na H (589.593 nm)-9.420262 u ppm 0.012384 0.13 11461.520134 -9.420262 u
Ni (231.604 nm)0.067769 ppm 0.000584 0.86 220.548000 0.067769
P (213.618 nm)12.294800 o ppm 0.044067 0.36 14503.100000 12.294800 o
Pb (220.353 nm)0.422972 ppm 0.002854 0.67 966.846000 0.422972
S (181.972 nm)31.749704 o ppm 0.199411 0.63 6496.326183 31.749704 o
Sb (206.834 nm)0.007873 ppm 0.002938 37.32 14.395200 0.007873
Se (196.026 nm)0.005526 ppm 0.001924 34.82 0.963728 0.005526
Si (288.158 nm)4.641450 ppm 0.021851 0.47 34623.300000 4.641450
Sn (189.925 nm)0.033899 ppm 0.004434 13.08 25.060400 0.033899
Sr (421.552 nm)0.296537 ppm 0.001593 0.54 65484.999713 0.296537
Th (288.505 nm)0.058828 ppm 0.001350 2.30 386.978000 0.058828
Ti (336.122 nm)0.898626 ppm 0.003844 0.43 98212.500000 0.898626
Tl (190.794 nm)0.001235 ppm 0.000782 63.32 -4.037960 0.001235
U (409.013 nm)0.007331 ppm 0.000194 2.64 131.077000 0.007331
V (292.401 nm)0.058844 ppm 0.000253 0.43 2425.820000 0.058844
Zn (206.200 nm)1.236830 o ppm 0.004807 0.39 2671.210000 1.236830 o
Zr (343.823 nm)0.009999 ppm 0.000058 0.58 912.389000 0.009999
Test Report
52A112023.esws
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Page 987 of 1261
Solution Name: 280-184252-A-2-B @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-2-B @25 11/20/2023 7:38:11 PM 3:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001956 ppm 0.000019 0.96 5380.414448 0.001956
Ag (328.068 nm)0.000166 ppm 0.000127 76.85 -23.398600 0.000166
Al (394.401 nm)1.876210 ppm 0.013616 0.73 23543.900000 1.876210
Al H (396.152 nm)1.921280 ppm 0.002137 0.11 8685.200000 1.921280
As (188.980 nm)0.007203 ppm 0.000890 12.35 1.882780 0.007203
B (249.678 nm)0.006400 ppm 0.000401 6.27 69.742700 0.006400
Ba (493.408 nm)1.205780 ppm 0.004576 0.38 182840.000000 1.205780
Be (234.861 nm)0.000111 ppm 0.000084 75.58 1065.740000 0.000111
Bi (223.061 nm)-0.002592 u ppm 0.001148 44.29 0.231723 -0.002592 u
Ca (315.887 nm)9.448544 ppm 0.018570 0.20 6348.266137 9.448544
Cd (214.439 nm)0.078772 ppm 0.000930 1.18 1193.450000 0.078772
Co (228.615 nm)0.017929 ppm 0.000255 1.42 392.956000 0.017929
Cr (205.560 nm)0.113312 ppm 0.001152 1.02 467.638000 0.113312
Cu (324.754 nm)0.115830 ppm 0.001184 1.02 6252.740000 0.115830
Fe (238.204 nm)78.194752 o ppm 0.204014 0.26 307824.099952 78.194752 o
Fe H (259.940 nm)75.730600 ppm 0.190703 0.25 122527.000000 75.730600
K (766.491 nm)0.307468 ppm 0.028124 9.15 105.001000 0.307468
Li (670.783 nm)-0.012069 u ppm 0.022131 > 100.00 -4729.420000 -0.012069 u
Mg (279.078 nm)1.336580 ppm 0.010437 0.78 4429.490000 1.336580
Mn (257.610 nm)0.415876 ppm 0.003802 0.91 110969.000000 0.415876
Mo (202.032 nm)0.012682 ppm 0.000266 2.10 66.408700 0.012682
Na (589.592 nm)-0.143122 u ppm 0.010870 7.60 13450.100000 -0.143122 u
Na H (589.593 nm)-10.085824 u ppm 0.128630 1.28 13838.630985 -10.085824 u
Ni (231.604 nm)0.039447 ppm 0.000822 2.08 124.113000 0.039447
P (213.618 nm)0.163568 ppm 0.001446 0.88 189.925000 0.163568
Pb (220.353 nm)2.883640 ppm 0.029597 1.03 6625.890000 2.883640
S (181.972 nm)1.665975 ppm 0.024878 1.49 366.908746 1.665975
Sb (206.834 nm)0.022385 ppm 0.002469 11.03 34.706800 0.022385
Se (196.026 nm)0.000806 u ppm 0.002123 > 100.00 -2.411710 0.000806 u
Si (288.158 nm)0.704760 ppm 0.008295 1.18 5875.290000 0.704760
Sn (189.925 nm)0.008030 ppm 0.001945 24.23 7.676790 0.008030
Sr (421.552 nm)0.045626 ppm 0.000192 0.42 10083.831235 0.045626
Th (288.505 nm)0.019501 ppm 0.002173 11.14 303.049000 0.019501
Ti (336.122 nm)0.204620 ppm 0.001556 0.76 22230.400000 0.204620
Tl (190.794 nm)0.002213 ppm 0.001067 48.23 -1.830540 0.002213
U (409.013 nm)-0.001659 u ppm 0.003459 > 100.00 92.153300 -0.001659 u
V (292.401 nm)0.005906 ppm 0.000153 2.59 177.173000 0.005906
Zn (206.200 nm)12.508800 o ppm 0.145915 1.17 26977.700000 12.508800 o
Zr (343.823 nm)0.003213 ppm 0.000057 1.79 360.004000 0.003213
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 117 of 287
Page 988 of 1261
Solution Name: 280-184252-A-2-B SD @125
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-2-B SD
@125
11/20/2023 7:42:33 PM 3:6 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000668 ppm 0.000015 2.28 1314.533443 0.000668
Ag (328.068 nm)0.000007 u ppm 0.000034 > 100.00 -29.706600 0.000007 u
Al (394.401 nm)0.375404 ppm 0.004601 1.23 5074.280000 0.375404
Al H (396.152 nm)0.388509 u ppm 0.002374 0.61 1796.600000 0.388509 u
As (188.980 nm)0.004300 ppm 0.001857 43.19 0.026599 0.004300
B (249.678 nm)0.000391 ppm 0.000259 66.20 19.455800 0.000391
Ba (493.408 nm)0.243312 ppm 0.001785 0.73 36894.800000 0.243312
Be (234.861 nm)0.000076 ppm 0.000009 11.88 257.710000 0.000076
Bi (223.061 nm)-0.002375 u ppm 0.000364 15.31 0.553826 -0.002375 u
Ca (315.887 nm)1.925453 ppm 0.013894 0.72 1274.549862 1.925453
Cd (214.439 nm)0.016024 ppm 0.000082 0.51 242.839000 0.016024
Co (228.615 nm)0.003856 ppm 0.000057 1.49 118.018000 0.003856
Cr (205.560 nm)0.023717 ppm 0.000362 1.53 99.082200 0.023717
Cu (324.754 nm)0.023699 ppm 0.000574 2.42 1885.770000 0.023699
Fe (238.204 nm)15.931459 o ppm 0.105821 0.66 62729.532930 15.931459 o
Fe H (259.940 nm)15.609300 ppm 0.103781 0.66 25144.600000 15.609300
K (766.491 nm)0.004759 u ppm 0.070484 > 100.00 -438.863000 0.004759 u
Li (670.783 nm)-0.028138 u ppm 0.044678 > 100.00 -5327.050000 -0.028138 u
Mg (279.078 nm)0.273294 ppm 0.001423 0.52 913.331000 0.273294
Mn (257.610 nm)0.085279 ppm 0.000580 0.68 22758.800000 0.085279
Mo (202.032 nm)0.002926 ppm 0.000498 17.03 17.999300 0.002926
Na (589.592 nm)0.037007 ppm 0.029657 80.14 4344.930000 0.037007
Na H (589.593 nm)-9.971206 u ppm 0.081640 0.82 6497.474876 -9.971206 u
Ni (231.604 nm)0.007826 ppm 0.000282 3.60 16.438500 0.007826
P (213.618 nm)0.032721 ppm 0.002441 7.46 40.462900 0.032721
Pb (220.353 nm)0.587410 ppm 0.004424 0.75 1348.410000 0.587410
S (181.972 nm)0.321490 ppm 0.010543 3.28 90.269421 0.321490
Sb (206.834 nm)0.005303 ppm 0.001822 34.35 9.577370 0.005303
Se (196.026 nm)0.003462 u ppm 0.003254 94.00 5.526550 0.003462 u
Si (288.158 nm)0.141042 ppm 0.001839 1.30 1744.540000 0.141042
Sn (189.925 nm)-0.000316 u ppm 0.000641 > 100.00 2.068690 -0.000316 u
Sr (421.552 nm)0.009207 ppm 0.000104 1.13 2042.615777 0.009207
Th (288.505 nm)0.007445 ppm 0.002045 27.46 275.676000 0.007445
Ti (336.122 nm)0.041207 ppm 0.000324 0.79 4382.540000 0.041207
Tl (190.794 nm)0.001057 u ppm 0.002753 > 100.00 -1.695140 0.001057 u
U (409.013 nm)-0.003352 u ppm 0.004155 > 100.00 23.964600 -0.003352 u
V (292.401 nm)0.001231 ppm 0.000129 10.49 5.119790 0.001231
Zn (206.200 nm)2.568550 o ppm 0.014823 0.58 5542.900000 2.568550 o
Zr (343.823 nm)0.000702 ppm 0.000042 5.97 71.160700 0.000702
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 118 of 287
Page 989 of 1261
Solution Name: 280-184252-A-2-C MS @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-2-C MS
@25
11/20/2023 7:46:56 PM 3:7 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.029698 ppm 0.000271 0.91 76321.658771 0.029698
Ag (328.068 nm)0.002148 ppm 0.000063 2.91 66.738100 0.002148
Al (394.401 nm)1.581980 ppm 0.013763 0.87 19915.800000 1.581980
Al H (396.152 nm)1.593550 ppm 0.009230 0.58 7212.290000 1.593550
As (188.980 nm)0.044638 ppm 0.001405 3.15 33.003200 0.044638
B (249.678 nm)0.077381 ppm 0.000873 1.13 663.834000 0.077381
Ba (493.408 nm)0.679957 ppm 0.004446 0.65 103196.000000 0.679957
Be (234.861 nm)0.037230 ppm 0.000477 1.28 7243.330000 0.037230
Bi (223.061 nm)-0.002107 u ppm 0.000017 0.80 0.952431 -0.002107 u
Ca (315.887 nm)8.254546 ppm 0.053056 0.64 5543.010817 8.254546
Cd (214.439 nm)0.081012 ppm 0.000645 0.80 1226.540000 0.081012
Co (228.615 nm)0.053577 ppm 0.000672 1.25 1073.410000 0.053577
Cr (205.560 nm)0.112046 ppm 0.000588 0.52 462.282000 0.112046
Cu (324.754 nm)0.151686 ppm 0.001594 1.05 7929.770000 0.151686
Fe (238.204 nm)76.323141 o ppm 0.385957 0.51 300456.702924 76.323141 o
Fe H (259.940 nm)73.943500 ppm 0.380959 0.52 119633.000000 73.943500
K (766.491 nm)2.113060 ppm 0.060596 2.87 3349.020000 2.113060
Li (670.783 nm)0.004985 u ppm 0.047725 > 100.00 -4095.200000 0.004985 u
Mg (279.078 nm)2.756710 ppm 0.022302 0.81 9179.930000 2.756710
Mn (257.610 nm)0.382884 ppm 0.002970 0.78 102166.000000 0.382884
Mo (202.032 nm)0.047260 ppm 0.001382 2.92 237.986000 0.047260
Na (589.592 nm)1.949500 ppm 0.039814 2.04 32723.100000 1.949500
Na H (589.593 nm)-8.426770 u ppm 0.554583 6.58 23808.892456 -8.426770 u
Ni (231.604 nm)0.081556 ppm 0.001515 1.86 267.521000 0.081556
P (213.618 nm)0.879369 ppm 0.011869 1.35 1032.140000 0.879369
Pb (220.353 nm)1.158160 ppm 0.008850 0.76 2659.830000 1.158160
S (181.972 nm)1.891081 ppm 0.021404 1.13 412.703657 1.891081
Sb (206.834 nm)0.085489 ppm 0.001593 1.86 111.249000 0.085489
Se (196.026 nm)0.036390 ppm 0.006161 16.93 19.599200 0.036390
Si (288.158 nm)0.413798 ppm 0.002826 0.68 3775.270000 0.413798
Sn (189.925 nm)0.044797 ppm 0.001823 4.07 32.383800 0.044797
Sr (421.552 nm)0.065465 ppm 0.000358 0.55 14464.333480 0.065465
Th (288.505 nm)0.019769 ppm 0.003261 16.50 301.419000 0.019769
Ti (336.122 nm)0.221573 ppm 0.001813 0.82 24077.800000 0.221573
Tl (190.794 nm)0.034770 ppm 0.003156 9.08 33.511100 0.034770
U (409.013 nm)-0.002620 u ppm 0.001800 68.69 85.388700 -0.002620 u
V (292.401 nm)0.040198 ppm 0.000180 0.45 1617.800000 0.040198
Zn (206.200 nm)8.585640 o ppm 0.061878 0.72 18517.900000 8.585640 o
Zr (343.823 nm)0.039367 ppm 0.000489 1.24 3304.740000 0.039367
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 119 of 287
Page 990 of 1261
Solution Name: 280-184252-A-2-D MSD @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-2-D MSD
@25
11/20/2023 7:51:16 PM 3:8 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.032335 ppm 0.000595 1.84 83373.785654 0.032335
Ag (328.068 nm)0.002790 ppm 0.000160 5.75 98.467700 0.002790
Al (394.401 nm)2.546180 ppm 0.044594 1.75 31780.500000 2.546180
Al H (396.152 nm)2.552680 ppm 0.015672 0.61 11522.800000 2.552680
As (188.980 nm)0.050265 ppm 0.002840 5.65 37.588900 0.050265
B (249.678 nm)0.083670 ppm 0.000923 1.10 716.468000 0.083670
Ba (493.408 nm)1.043060 ppm 0.005032 0.48 158217.000000 1.043060
Be (234.861 nm)0.039642 ppm 0.000285 0.72 7776.120000 0.039642
Bi (223.061 nm)-0.002612 u ppm 0.001086 41.57 0.202236 -0.002612 u
Ca (315.887 nm)11.043200 o ppm 0.060591 0.55 7423.732186 11.043200 o
Cd (214.439 nm)0.243959 ppm 0.004913 2.01 3664.150000 0.243959
Co (228.615 nm)0.059103 ppm 0.001066 1.80 1181.610000 0.059103
Cr (205.560 nm)0.167034 ppm 0.003156 1.89 688.490000 0.167034
Cu (324.754 nm)0.171956 ppm 0.003089 1.80 8885.290000 0.171956
Fe (238.204 nm)86.420774 o ppm 0.457372 0.53 340207.143934 86.420774 o
Fe H (259.940 nm)83.741300 ppm 0.360070 0.43 135503.000000 83.741300
K (766.491 nm)2.419910 ppm 0.046574 1.92 3900.320000 2.419910
Li (670.783 nm)0.021647 ppm 0.017497 80.83 -3475.580000 0.021647
Mg (279.078 nm)3.508790 ppm 0.062715 1.79 11689.000000 3.508790
Mn (257.610 nm)0.518798 ppm 0.009075 1.75 138431.000000 0.518798
Mo (202.032 nm)0.053858 ppm 0.000437 0.81 270.725000 0.053858
Na (589.592 nm)1.975750 ppm 0.027279 1.38 37300.300000 1.975750
Na H (589.593 nm)-8.015992 u ppm 0.497797 6.21 30550.782946 -8.015992 u
Ni (231.604 nm)0.090690 ppm 0.002182 2.41 298.625000 0.090690
P (213.618 nm)0.942840 ppm 0.019919 2.11 1105.830000 0.942840
Pb (220.353 nm)2.263470 ppm 0.036114 1.60 5200.150000 2.263470
S (181.972 nm)2.139419 ppm 0.043437 2.03 463.862573 2.139419
Sb (206.834 nm)0.079967 ppm 0.001299 1.62 105.324000 0.079967
Se (196.026 nm)0.039473 ppm 0.003336 8.45 20.524200 0.039473
Si (288.158 nm)0.255974 ppm 0.003759 1.47 2642.970000 0.255974
Sn (189.925 nm)0.046640 ppm 0.001732 3.71 33.622600 0.046640
Sr (421.552 nm)0.081537 ppm 0.000553 0.68 18012.980032 0.081537
Th (288.505 nm)0.025554 ppm 0.002882 11.28 314.454000 0.025554
Ti (336.122 nm)0.291492 ppm 0.005407 1.85 31713.400000 0.291492
Tl (190.794 nm)0.040605 ppm 0.000738 1.82 39.543500 0.040605
U (409.013 nm)-0.004977 u ppm 0.001210 24.31 84.735400 -0.004977 u
V (292.401 nm)0.045238 ppm 0.000901 1.99 1814.430000 0.045238
Zn (206.200 nm)12.892300 o ppm 0.226764 1.76 27804.500000 12.892300 o
Zr (343.823 nm)0.042589 ppm 0.000896 2.10 3581.020000 0.042589
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 120 of 287
Page 991 of 1261
Solution Name: 280-184252-A-2-B PDS @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-2-B PDS
@25
11/20/2023 7:55:41 PM 3:9 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.088756 ppm 0.000441 0.50 228428.463229 0.088756
Ag (328.068 nm)0.050712 ppm 0.000126 0.25 2672.480000 0.050712
Al (394.401 nm)2.919580 ppm 0.012120 0.42 36379.000000 2.919580
Al H (396.152 nm)2.877370 ppm 0.004311 0.15 12982.000000 2.877370
As (188.980 nm)0.208944 ppm 0.001572 0.75 169.487000 0.208944
B (249.678 nm)0.107037 ppm 0.000602 0.56 912.045000 0.107037
Ba (493.408 nm)1.309410 ppm 0.000823 0.06 198540.000000 1.309410
Be (234.861 nm)0.050165 ppm 0.000312 0.62 9454.390000 0.050165
Bi (223.061 nm)-0.001776 u ppm 0.001192 67.13 1.444280 -0.001776 u
Ca (315.887 nm)29.331185 o ppm 0.019539 0.07 19757.498810 29.331185 o
Cd (214.439 nm)0.127438 ppm 0.000772 0.61 1921.260000 0.127438
Co (228.615 nm)0.068020 ppm 0.000131 0.19 1350.210000 0.068020
Cr (205.560 nm)0.162912 ppm 0.000742 0.46 671.504000 0.162912
Cu (324.754 nm)0.165505 ppm 0.000996 0.60 8574.940000 0.165505
Fe (238.204 nm)80.205254 o ppm 0.070932 0.09 315738.863512 80.205254 o
Fe H (259.940 nm)77.715400 ppm 0.083913 0.11 125742.000000 77.715400
K (766.491 nm)20.419900 ppm 0.206607 1.01 36240.000000 20.419900
Li (670.783 nm)0.092507 ppm 0.015890 17.18 -840.336000 0.092507
Mg (279.078 nm)21.110200 ppm 0.106962 0.51 70552.300000 21.110200
Mn (257.610 nm)0.465239 ppm 0.002154 0.46 124140.000000 0.465239
Mo (202.032 nm)0.062266 ppm 0.000807 1.30 312.445000 0.062266
Na (589.592 nm)19.737300 ppm 0.190984 0.97 256320.000000 19.737300
Na H (589.593 nm)11.929545 u ppm 1.618205 13.56 207466.575320 11.929545 u
Ni (231.604 nm)0.087093 ppm 0.000424 0.49 286.496000 0.087093
P (213.618 nm)2.112620 ppm 0.010097 0.48 2486.940000 2.112620
Pb (220.353 nm)2.925360 ppm 0.013493 0.46 6722.310000 2.925360
S (181.972 nm)1.711179 ppm 0.023327 1.36 377.142168 1.711179
Sb (206.834 nm)0.125544 ppm 0.000760 0.61 160.493000 0.125544
Se (196.026 nm)0.196786 ppm 0.003667 1.86 117.676000 0.196786
Si (288.158 nm)5.608540 ppm 0.019183 0.34 41530.900000 5.608540
Sn (189.925 nm)0.065285 ppm 0.003990 6.11 46.151700 0.065285
Sr (421.552 nm)0.095092 ppm 0.000086 0.09 21005.995169 0.095092
Th (288.505 nm)0.218750 ppm 0.002670 1.22 677.067000 0.218750
Ti (336.122 nm)0.256725 ppm 0.001206 0.47 27959.600000 0.256725
Tl (190.794 nm)0.197552 ppm 0.001775 0.90 210.146000 0.197552
U (409.013 nm)0.478780 ppm 0.005681 1.19 2212.270000 0.478780
V (292.401 nm)0.055526 ppm 0.000224 0.40 2234.250000 0.055526
Zn (206.200 nm)12.610400 o ppm 0.054194 0.43 27196.700000 12.610400 o
Zr (343.823 nm)0.053602 ppm 0.000310 0.58 4470.430000 0.053602
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 121 of 287
Page 992 of 1261
Solution Name: 280-184252-A-3-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184252-A-3-A @25 11/20/2023 8:00:04 PM 3:10 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001192 ppm 0.000005 0.45 3332.906355 0.001192
Ag (328.068 nm)0.000211 u ppm 0.000193 91.51 -18.948400 0.000211 u
Al (394.401 nm)1.073030 ppm 0.006446 0.60 13654.400000 1.073030
Al H (396.152 nm)1.081280 ppm 0.001333 0.12 4910.050000 1.081280
As (188.980 nm)0.015785 ppm 0.001536 9.73 8.789860 0.015785
B (249.678 nm)0.005163 ppm 0.000743 14.38 59.390200 0.005163
Ba (493.408 nm)0.608506 ppm 0.002002 0.33 92450.100000 0.608506
Be (234.861 nm)0.000110 ppm 0.000056 50.83 1388.890000 0.000110
Bi (223.061 nm)-0.000933 u ppm 0.001740 > 100.00 2.697790 -0.000933 u
Ca (315.887 nm)8.157264 ppm 0.019872 0.24 5477.402037 8.157264
Cd (214.439 nm)0.034272 ppm 0.000388 1.13 533.430000 0.034272
Co (228.615 nm)0.015495 ppm 0.000081 0.52 355.926000 0.015495
Cr (205.560 nm)0.158088 ppm 0.000687 0.43 651.831000 0.158088
Cu (324.754 nm)0.131807 ppm 0.000900 0.68 7031.460000 0.131807
Fe (238.204 nm)103.290065 o ppm 0.304944 0.30 406608.958193 103.290065 o
Fe H (259.940 nm)100.016000 ppm 0.306042 0.31 161863.000000 100.016000
K (766.491 nm)0.203737 ppm 0.076478 37.54 -81.368100 0.203737
Li (670.783 nm)-0.019014 u ppm 0.025275 > 100.00 -4987.720000 -0.019014 u
Mg (279.078 nm)0.807348 ppm 0.010240 1.27 2642.820000 0.807348
Mn (257.610 nm)0.546618 ppm 0.004095 0.75 145854.000000 0.546618
Mo (202.032 nm)0.017034 ppm 0.000149 0.87 88.000100 0.017034
Na (589.592 nm)-0.005772 u ppm 0.010021 > 100.00 8126.750000 -0.005772 u
Na H (589.593 nm)-10.005131 u ppm 0.141185 1.41 9378.674154 -10.005131 u
Ni (231.604 nm)0.057613 ppm 0.001086 1.89 185.966000 0.057613
P (213.618 nm)0.136563 ppm 0.002368 1.73 157.087000 0.136563
Pb (220.353 nm)1.585970 ppm 0.014285 0.90 3643.100000 1.585970
S (181.972 nm)1.537967 ppm 0.021333 1.39 341.906468 1.537967
Sb (206.834 nm)0.036060 ppm 0.000751 2.08 52.622300 0.036060
Se (196.026 nm)0.003322 ppm 0.000581 17.49 -3.411910 0.003322
Si (288.158 nm)0.337650 ppm 0.003689 1.09 3254.980000 0.337650
Sn (189.925 nm)0.010010 ppm 0.002716 27.14 9.007380 0.010010
Sr (421.552 nm)0.031938 ppm 0.000170 0.53 7061.513452 0.031938
Th (288.505 nm)0.022183 ppm 0.002055 9.26 310.081000 0.022183
Ti (336.122 nm)0.437205 ppm 0.002830 0.65 47607.100000 0.437205
Tl (190.794 nm)-0.000576 u ppm 0.000776 > 100.00 -5.715690 -0.000576 u
U (409.013 nm)-0.004843 u ppm 0.003444 71.10 102.979000 -0.004843 u
V (292.401 nm)0.003657 ppm 0.000072 1.98 76.084100 0.003657
Zn (206.200 nm)10.206900 o ppm 0.076044 0.75 22014.000000 10.206900 o
Zr (343.823 nm)0.002428 ppm 0.000124 5.11 329.970000 0.002428
Test Report
52A112023.esws
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Page 993 of 1261
Solution Name: 280-184157-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184157-A-1-A 11/20/2023 8:04:27 PM 3:11 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.263429 ppm 0.000828 0.31 676566.051489 0.263429
Ag (328.068 nm)0.000807 ppm 0.000202 25.01 -341.395000 0.000807
Al (394.401 nm)360.417000 o ppm 1.432230 0.40 4435490.000000 360.417000 o
Al H (396.152 nm)341.330000 ppm 0.291045 0.09 1534060.000000 341.330000
As (188.980 nm)0.051519 ppm 0.003750 7.28 37.234800 0.051519
B (249.678 nm)0.149792 ppm 0.000648 0.43 1269.890000 0.149792
Ba (493.408 nm)0.457398 ppm 0.001183 0.26 69956.400000 0.457398
Be (234.861 nm)0.014799 ppm 0.000126 0.85 5641.560000 0.014799
Bi (223.061 nm)-0.000286 u ppm 0.001348 > 100.00 3.659220 -0.000286 u
Ca (315.887 nm)151.456861 o ppm 0.608844 0.40 102121.385662 151.456861 o
Cd (214.439 nm)0.001323 ppm 0.000103 7.78 69.466300 0.001323
Co (228.615 nm)0.091533 ppm 0.000291 0.32 1819.380000 0.091533
Cr (205.560 nm)0.352639 ppm 0.001835 0.52 1452.160000 0.352639
Cu (324.754 nm)0.146522 ppm 0.000446 0.30 7819.320000 0.146522
Fe (238.204 nm)242.891924 o ppm 0.464907 0.19 956138.595898 242.891924 o
Fe H (259.940 nm)238.474000 ppm 0.789126 0.33 386134.000000 238.474000
K (766.491 nm)49.791400 ppm 0.129167 0.26 89010.300000 49.791400
Li (670.783 nm)0.264542 ppm 0.002009 0.76 5557.570000 0.264542
Mg (279.078 nm)81.552200 o ppm 0.312397 0.38 272618.000000 81.552200 o
Mn (257.610 nm)1.981630 o ppm 0.007919 0.40 528747.000000 1.981630 o
Mo (202.032 nm)0.003329 ppm 0.001035 31.09 19.997300 0.003329
Na (589.592 nm)13.338500 ppm 0.029013 0.22 168577.000000 13.338500
Na H (589.593 nm)3.016949 u ppm 0.165985 5.50 122081.875386 3.016949 u
Ni (231.604 nm)0.206239 ppm 0.000141 0.07 692.056000 0.206239
P (213.618 nm)2.760200 ppm 0.015555 0.56 3254.280000 2.760200
Pb (220.353 nm)0.136508 ppm 0.001441 1.06 270.288000 0.136508
S (181.972 nm)1.490403 ppm 0.025602 1.72 341.832367 1.490403
Sb (206.834 nm)-0.001488 u ppm 0.004252 > 100.00 16.752800 -0.001488 u
Se (196.026 nm)-0.001374 u ppm 0.004974 > 100.00 -19.978300 -0.001374 u
Si (288.158 nm)4.201030 ppm 0.010027 0.24 31395.300000 4.201030
Sn (189.925 nm)0.023170 ppm 0.001322 5.70 17.850600 0.023170
Sr (421.552 nm)0.739451 ppm 0.001801 0.24 163280.023736 0.739451
Th (288.505 nm)0.215408 ppm 0.003655 1.70 674.538000 0.215408
Ti (336.122 nm)0.774926 ppm 0.002411 0.31 84773.100000 0.774926
Tl (190.794 nm)-0.000065 u ppm 0.000919 > 100.00 -8.052290 -0.000065 u
U (409.013 nm)-0.085886 u ppm 0.005301 6.17 -119.870000 -0.085886 u
V (292.401 nm)0.493784 ppm 0.001433 0.29 20604.700000 0.493784
Zn (206.200 nm)0.641740 ppm 0.005328 0.83 1387.990000 0.641740
Zr (343.823 nm)0.119428 ppm 0.000348 0.29 10056.600000 0.119428
Test Report
52A112023.esws
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Page 994 of 1261
Solution Name: 280-184157-A-2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184157-A-2-A 11/20/2023 8:09:07 PM 3:12 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.109706 ppm 0.000474 0.43 281999.171972 0.109706
Ag (328.068 nm)0.000686 ppm 0.000138 20.14 -120.826000 0.000686
Al (394.401 nm)93.898800 o ppm 0.411499 0.44 1155900.000000 93.898800 o
Al H (396.152 nm)91.018900 ppm 0.339862 0.37 409108.000000 91.018900
As (188.980 nm)0.037869 ppm 0.002097 5.54 27.224200 0.037869
B (249.678 nm)0.094299 ppm 0.000911 0.97 805.427000 0.094299
Ba (493.408 nm)0.614164 ppm 0.001517 0.25 93280.100000 0.614164
Be (234.861 nm)0.004496 ppm 0.000124 2.77 1997.950000 0.004496
Bi (223.061 nm)-0.003076 u ppm 0.001196 38.88 -0.487893 -0.003076 u
Ca (315.887 nm)319.690701 o ppm 0.954083 0.30 215581.499155 319.690701 o
Cd (214.439 nm)0.000873 ppm 0.000224 25.68 32.267600 0.000873
Co (228.615 nm)0.037804 ppm 0.000459 1.21 827.384000 0.037804
Cr (205.560 nm)0.115603 ppm 0.000266 0.23 477.045000 0.115603
Cu (324.754 nm)0.051674 ppm 0.000675 1.31 3090.290000 0.051674
Fe (238.204 nm)93.685704 o ppm 0.299159 0.32 368801.876349 93.685704 o
Fe H (259.940 nm)91.016500 ppm 0.303008 0.33 147287.000000 91.016500
K (766.491 nm)18.423600 ppm 0.140377 0.76 32653.400000 18.423600
Li (670.783 nm)0.117831 ppm 0.002458 2.09 101.470000 0.117831
Mg (279.078 nm)45.784800 o ppm 0.339784 0.74 153084.000000 45.784800 o
Mn (257.610 nm)2.243510 o ppm 0.013765 0.61 598622.000000 2.243510 o
Mo (202.032 nm)0.003181 ppm 0.000849 26.68 19.260100 0.003181
Na (589.592 nm)1.948770 ppm 0.024123 1.24 31940.500000 1.948770
Na H (589.593 nm)-8.224047 u ppm 0.023956 0.29 25011.954334 -8.224047 u
Ni (231.604 nm)0.083684 ppm 0.000462 0.55 274.743000 0.083684
P (213.618 nm)2.320940 ppm 0.016613 0.72 2740.600000 2.320940
Pb (220.353 nm)0.053671 ppm 0.003143 5.86 109.181000 0.053671
S (181.972 nm)1.281516 ppm 0.023562 1.84 297.220704 1.281516
Sb (206.834 nm)-0.001280 u ppm 0.003258 > 100.00 2.458840 -0.001280 u
Se (196.026 nm)0.003281 u ppm 0.002958 90.17 -1.305850 0.003281 u
Si (288.158 nm)7.620900 ppm 0.043916 0.58 56401.300000 7.620900
Sn (189.925 nm)0.014447 ppm 0.003788 26.22 11.988800 0.014447
Sr (421.552 nm)0.528238 ppm 0.000679 0.13 116644.303592 0.528238
Th (288.505 nm)0.147496 ppm 0.002676 1.81 570.347000 0.147496
Ti (336.122 nm)1.584310 o ppm 0.007742 0.49 173461.000000 1.584310 o
Tl (190.794 nm)0.002191 ppm 0.001423 64.97 -4.367670 0.002191
U (409.013 nm)-0.033456 u ppm 0.003522 10.53 -34.472300 -0.033456 u
V (292.401 nm)0.197224 ppm 0.001352 0.69 8241.460000 0.197224
Zn (206.200 nm)0.206132 ppm 0.002080 1.01 448.659000 0.206132
Zr (343.823 nm)0.089658 ppm 0.000503 0.56 7427.970000 0.089658
Test Report
52A112023.esws
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Page 995 of 1261
Solution Name: 280-184214-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184214-A-1-A 11/20/2023 8:13:39 PM 3:13 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000821 ppm 0.000020 2.45 1875.735361 0.000821
Ag (328.068 nm)0.000587 ppm 0.000317 54.00 1.571040 0.000587
Al (394.401 nm)0.743573 ppm 0.005829 0.78 9604.580000 0.743573
Al H (396.152 nm)0.772012 u ppm 0.001689 0.22 3520.140000 0.772012 u
As (188.980 nm)0.002695 ppm 0.002863 > 100.00 -1.200460 0.002695
B (249.678 nm)0.014413 ppm 0.000215 1.49 136.809000 0.014413
Ba (493.408 nm)0.039642 ppm 0.000715 1.80 6014.320000 0.039642
Be (234.861 nm)-0.000010 u ppm 0.000014 > 100.00 88.622800 -0.000010 u
Bi (223.061 nm)0.016138 ppm 0.001021 6.33 28.078400 0.016138
Ca (315.887 nm)7.168249 ppm 0.027295 0.38 4810.391300 7.168249
Cd (214.439 nm)0.000503 ppm 0.000042 8.43 8.395680 0.000503
Co (228.615 nm)0.001215 ppm 0.000071 5.85 66.727600 0.001215
Cr (205.560 nm)0.008341 ppm 0.000712 8.54 35.819600 0.008341
Cu (324.754 nm)0.112383 ppm 0.000597 0.53 6006.590000 0.112383
Fe (238.204 nm)3.914133 ppm 0.020192 0.52 15424.239899 3.914133
Fe H (259.940 nm)3.876100 u ppm 0.015623 0.40 6139.570000 3.876100 u
K (766.491 nm)4.180020 ppm 0.032764 0.78 7062.630000 4.180020
Li (670.783 nm)0.004913 ppm 0.001239 25.22 -4097.880000 0.004913
Mg (279.078 nm)1.158580 ppm 0.001540 0.13 3881.410000 1.158580
Mn (257.610 nm)0.044720 ppm 0.000118 0.26 11936.700000 0.044720
Mo (202.032 nm)0.004734 ppm 0.000365 7.70 26.970200 0.004734
Na (589.592 nm)1.225040 ppm 0.006883 0.56 16395.600000 1.225040
Na H (589.593 nm)-8.938743 u ppm 0.009824 0.11 13770.030623 -8.938743 u
Ni (231.604 nm)0.004300 ppm 0.000463 10.76 4.429960 0.004300
P (213.618 nm)8.543470 ppm 0.042501 0.50 10083.500000 8.543470
Pb (220.353 nm)0.005768 ppm 0.002399 41.59 11.545200 0.005768
S (181.972 nm)3.514791 ppm 0.019741 0.56 740.192876 3.514791
Sb (206.834 nm)-0.000379 u ppm 0.002654 > 100.00 1.779040 -0.000379 u
Se (196.026 nm)0.007482 ppm 0.004396 58.76 9.226330 0.007482
Si (288.158 nm)1.500520 ppm 0.001404 0.09 11624.800000 1.500520
Sn (189.925 nm)0.025311 ppm 0.000861 3.40 19.289200 0.025311
Sr (421.552 nm)0.078158 ppm 0.001120 1.43 17266.854159 0.078158
Th (288.505 nm)0.008406 ppm 0.003192 37.97 276.994000 0.008406
Ti (336.122 nm)0.017791 ppm 0.000036 0.20 1838.810000 0.017791
Tl (190.794 nm)0.001373 u ppm 0.002772 > 100.00 -1.105690 0.001373 u
U (409.013 nm)0.016417 ppm 0.001651 10.05 99.289300 0.016417
V (292.401 nm)0.002368 ppm 0.000067 2.85 56.302800 0.002368
Zn (206.200 nm)0.224137 ppm 0.001636 0.73 487.484000 0.224137
Zr (343.823 nm)0.006654 ppm 0.000093 1.40 540.085000 0.006654
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 125 of 287
Page 996 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 8:18:02 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000084 u ppm 0.000003 3.44 726.285960 -0.000084 u
Ag (328.068 nm)-0.000166 u ppm 0.000184 > 100.00 105.489000 -0.000166 u
Al (394.401 nm)52.213300 o ppm 0.208138 0.40 641891.000000 52.213300 o
Al H (396.152 nm)48.862800 ppm 0.193333 0.40 219650.000000 48.862800
As (188.980 nm)0.003559 ppm 0.002031 57.08 -0.894766 0.003559
B (249.678 nm)-0.003054 u ppm 0.000850 27.85 -9.377580 -0.003054 u
Ba (493.408 nm)0.000275 ppm 0.000154 56.14 181.746000 0.000275
Be (234.861 nm)0.000127 ppm 0.000074 58.29 706.588000 0.000127
Bi (223.061 nm)-0.001645 u ppm 0.001101 66.94 1.640010 -0.001645 u
Ca (315.887 nm)-0.010426 u ppm 0.012865 > 100.00 -31.044178 -0.010426 u
Cd (214.439 nm)0.000060 u ppm 0.000097 > 100.00 11.213800 0.000060 u
Co (228.615 nm)0.000658 ppm 0.000134 20.41 55.415500 0.000658
Cr (205.560 nm)0.000136 ppm 0.000018 13.58 2.081580 0.000136
Cu (324.754 nm)-0.000744 u ppm 0.000377 50.67 1676.860000 -0.000744 u
Fe (238.204 nm)50.118025 o ppm 0.172292 0.34 197301.650707 50.118025 o
Fe H (259.940 nm)48.535900 ppm 0.154276 0.32 78478.100000 48.535900
K (766.491 nm)0.039246 ppm 0.011069 28.20 -376.900000 0.039246
Li (670.783 nm)0.005717 ppm 0.000582 10.17 -4067.970000 0.005717
Mg (279.078 nm)0.003642 ppm 0.001822 50.03 -168.628000 0.003642
Mn (257.610 nm)-0.000932 u ppm 0.000012 1.25 -244.316000 -0.000932 u
Mo (202.032 nm)-0.000110 u ppm 0.000445 > 100.00 2.930060 -0.000110 u
Na (589.592 nm)247.405000 o ppm 1.558610 0.63 3008300.000000 247.405000 o
Na H (589.593 nm)236.689558 ppm 1.039017 0.44 2163703.629284 236.689558
Ni (231.604 nm)0.000063 u ppm 0.001057 > 100.00 -9.994310 0.000063 u
P (213.618 nm)5.029560 ppm 0.031461 0.63 5939.970000 5.029560
Pb (220.353 nm)0.000278 u ppm 0.002127 > 100.00 -2.523850 0.000278 u
S (181.972 nm)4.783750 ppm 0.030382 0.64 1000.171071 4.783750
Sb (206.834 nm)-0.001340 u ppm 0.001367 > 100.00 3.831950 -0.001340 u
Se (196.026 nm)0.006808 ppm 0.001711 25.14 3.940750 0.006808
Si (288.158 nm)0.029838 ppm 0.000913 3.06 929.137000 0.029838
Sn (189.925 nm)0.001772 ppm 0.000480 27.10 3.471700 0.001772
Sr (421.552 nm)0.000553 ppm 0.000090 16.21 131.685874 0.000553
Th (288.505 nm)4.675130 ppm 0.019670 0.42 8997.430000 4.675130
Ti (336.122 nm)0.000764 ppm 0.000146 19.04 -34.665400 0.000764
Tl (190.794 nm)-0.003696 u ppm 0.000048 1.30 -7.401620 -0.003696 u
U (409.013 nm)2.418160 Q ppm 0.012874 0.53 10801.000000 Q 2.418160 Q
V (292.401 nm)0.000297 ppm 0.000178 59.99 255.954000 0.000297
Zn (206.200 nm)0.000371 ppm 0.000230 61.90 4.962480 0.000371
Zr (343.823 nm)-0.000787 u ppm 0.000039 4.97 -4.033190 -0.000787 u
Test Report
52A112023.esws
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Page 997 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 8:22:42 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.455532 ppm 0.000904 0.20 1168087.898325 0.455532
Ag (328.068 nm)0.507386 ppm 0.003163 0.62 27101.900000 0.507386
Al (394.401 nm)0.497428 ppm 0.002803 0.56 6568.770000 0.497428
Al H (396.152 nm)0.499626 u ppm 0.004190 0.84 2295.990000 0.499626 u
As (188.980 nm)0.509934 ppm 0.002744 0.54 420.265000 0.509934
B (249.678 nm)0.498050 ppm 0.001203 0.24 4184.690000 0.498050
Ba (493.408 nm)0.500026 ppm 0.001592 0.32 75737.300000 0.500026
Be (234.861 nm)0.504964 ppm 0.003417 0.68 84438.400000 0.504964
Bi (223.061 nm)1.001760 ppm 0.004493 0.45 1493.490000 1.001760
Ca (315.887 nm)4.997964 ppm 0.018914 0.38 3346.710002 4.997964
Cd (214.439 nm)0.509303 ppm 0.001834 0.36 7613.070000 0.509303
Co (228.615 nm)0.510057 ppm 0.001343 0.26 9789.260000 0.510057
Cr (205.560 nm)0.513656 ppm 0.001374 0.27 2112.780000 0.513656
Cu (324.754 nm)0.503949 ppm 0.001238 0.25 24274.400000 0.503949
Fe (238.204 nm)2.506300 ppm 0.004960 0.20 9888.762090 2.506300
Fe H (259.940 nm)2.523090 u ppm 0.006117 0.24 3947.990000 2.523090 u
K (766.491 nm)51.072700 ppm 0.107856 0.21 91312.500000 51.072700
Li (670.783 nm)0.501408 ppm 0.001085 0.22 14366.500000 0.501408
Mg (279.078 nm)20.219700 ppm 0.085398 0.42 67636.300000 20.219700
Mn (257.610 nm)0.497432 ppm 0.001369 0.28 132730.000000 0.497432
Mo (202.032 nm)0.505285 ppm 0.000707 0.14 2510.740000 0.505285
Na (589.592 nm)25.099800 ppm 0.093967 0.37 311994.000000 25.099800
Na H (589.593 nm)14.811581 u ppm 0.377786 2.55 225671.765147 14.811581 u
Ni (231.604 nm)0.512588 ppm 0.002186 0.43 1735.580000 0.512588
P (213.618 nm)0.008716 ppm 0.003693 42.37 -27.278500 0.008716
Pb (220.353 nm)0.533230 ppm 0.000492 0.09 1221.750000 0.533230
S (181.972 nm)-0.016735 u ppm 0.006358 37.99 23.161675 -0.016735 u
Sb (206.834 nm)0.497683 ppm 0.002462 0.49 608.056000 0.497683
Se (196.026 nm)0.506444 ppm 0.005137 1.01 315.870000 0.506444
Si (288.158 nm)4.999630 ppm 0.007601 0.15 37281.600000 4.999630
Sn (189.925 nm)0.501424 ppm 0.003470 0.69 339.231000 0.501424
Sr (421.552 nm)0.501519 ppm 0.001468 0.29 110744.837544 0.501519
Th (288.505 nm)0.042591 ppm 0.004012 9.42 328.239000 0.042591
Ti (336.122 nm)0.501506 ppm 0.001159 0.23 54616.600000 0.501506
Tl (190.794 nm)0.504807 ppm 0.004599 0.91 544.523000 0.504807
U (409.013 nm)-0.009222 u ppm 0.002541 27.56 -30.230500 -0.009222 u
V (292.401 nm)0.501888 ppm 0.001175 0.23 20859.000000 0.501888
Zn (206.200 nm)0.510775 ppm 0.003965 0.78 1105.580000 0.510775
Zr (343.823 nm)0.495276 ppm 0.001416 0.29 40370.300000 0.495276
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 127 of 287
Page 998 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 8:27:05 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000387 ppm 0.000012 3.15 399.937191 0.000387
Ag (328.068 nm)0.000275 ppm 0.000134 48.95 -14.103700 0.000275
Al (394.401 nm)0.000113 u ppm 0.000229 > 100.00 452.214000 0.000113 u
Al H (396.152 nm)-0.000963 u ppm 0.001768 > 100.00 46.238600 -0.000963 u
As (188.980 nm)0.001948 ppm 0.002155 > 100.00 -1.785630 0.001948
B (249.678 nm)0.000290 u ppm 0.000351 > 100.00 18.605600 0.000290 u
Ba (493.408 nm)0.000259 ppm 0.000185 71.53 38.573200 0.000259
Be (234.861 nm)0.000011 ppm 0.000009 77.41 41.790400 0.000011
Bi (223.061 nm)-0.000459 u ppm 0.001270 > 100.00 3.403190 -0.000459 u
Ca (315.887 nm)0.010241 ppm 0.005675 55.42 -17.105831 0.010241
Cd (214.439 nm)0.000013 u ppm 0.000150 > 100.00 0.266821 0.000013 u
Co (228.615 nm)0.000090 u ppm 0.000326 > 100.00 44.560700 0.000090 u
Cr (205.560 nm)0.000190 u ppm 0.000582 > 100.00 2.302130 0.000190 u
Cu (324.754 nm)0.000287 ppm 0.000179 62.50 779.002000 0.000287
Fe (238.204 nm)0.001293 u ppm 0.002572 > 100.00 21.694711 0.001293 u
Fe H (259.940 nm)0.095496 u ppm 0.000405 0.42 15.856700 0.095496 u
K (766.491 nm)0.030804 u ppm 0.042120 > 100.00 -392.069000 0.030804 u
Li (670.783 nm)0.002819 S ppm 0.001763 62.55 -4175.760000 S 0.002819 S
Mg (279.078 nm)0.001395 ppm 0.000535 38.31 13.534600 0.001395
Mn (257.610 nm)-0.000006 u ppm 0.000032 > 100.00 2.828970 -0.000006 u
Mo (202.032 nm)0.000480 ppm 0.000415 86.37 5.861240 0.000480
Na (589.592 nm)0.030034 ppm 0.008032 26.74 1403.710000 0.030034
Na H (589.593 nm)-10.136205 u ppm 0.007399 0.07 2942.686919 -10.136205 u
Ni (231.604 nm)0.000918 ppm 0.000414 45.10 -7.085330 0.000918
P (213.618 nm)-0.004480 u ppm 0.001455 32.47 -2.207900 -0.004480 u
Pb (220.353 nm)0.001217 ppm 0.001128 92.70 1.178400 0.001217
S (181.972 nm)-0.033965 u ppm 0.001991 5.86 17.153764 -0.033965 u
Sb (206.834 nm)-0.000618 u ppm 0.002167 > 100.00 1.252270 -0.000618 u
Se (196.026 nm)0.000201 u ppm 0.002453 > 100.00 5.138750 0.000201 u
Si (288.158 nm)0.000528 ppm 0.000591 > 100.00 715.498000 0.000528
Sn (189.925 nm)-0.000207 u ppm 0.000621 > 100.00 2.141930 -0.000207 u
Sr (421.552 nm)0.000052 ppm 0.000022 42.09 21.266369 0.000052
Th (288.505 nm)0.005263 ppm 0.000982 18.66 270.403000 0.005263
Ti (336.122 nm)-0.000066 u ppm 0.000031 46.31 -125.328000 -0.000066 u
Tl (190.794 nm)0.000266 u ppm 0.001168 > 100.00 -2.199550 0.000266 u
U (409.013 nm)-0.001287 u ppm 0.002155 > 100.00 17.805200 -0.001287 u
V (292.401 nm)0.000031 u ppm 0.000167 > 100.00 -38.161000 0.000031 u
Zn (206.200 nm)-0.000878 u ppm 0.000791 89.99 2.268560 -0.000878 u
Zr (343.823 nm)0.000108 u ppm 0.000162 > 100.00 1.118450 0.000108 u
Test Report
52A112023.esws
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Page 999 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 8:31:07 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014213 ppm 0.000053 0.37 35943.368961 0.014213
Ag (328.068 nm)0.009743 ppm 0.000086 0.89 489.412000 0.009743
Al (394.401 nm)0.087480 ppm 0.001258 1.44 1537.060000 0.087480
Al H (396.152 nm)0.094186 u ppm 0.002465 2.62 473.858000 0.094186 u
As (188.980 nm)0.014484 ppm 0.000406 2.80 8.629330 0.014484
B (249.678 nm)0.095114 ppm 0.000684 0.72 812.252000 0.095114
Ba (493.408 nm)0.009800 ppm 0.000249 2.54 1483.900000 0.009800
Be (234.861 nm)0.000963 ppm 0.000033 3.47 202.098000 0.000963
Bi (223.061 nm)-0.001189 Qu ppm 0.001963 > 100.00 2.316680 Q -0.001189 Qu
Ca (315.887 nm)0.202730 ppm 0.008270 4.08 112.712351 0.202730
Cd (214.439 nm)0.005162 ppm 0.000112 2.18 77.252800 0.005162
Co (228.615 nm)0.009949 ppm 0.000285 2.87 232.936000 0.009949
Cr (205.560 nm)0.009771 ppm 0.000243 2.48 41.620500 0.009771
Cu (324.754 nm)0.015080 ppm 0.000175 1.16 1462.880000 0.015080
Fe (238.204 nm)0.101102 ppm 0.000673 0.67 414.647929 0.101102
Fe H (259.940 nm)0.191284 u ppm 0.002437 1.27 171.011000 0.191284 u
K (766.491 nm)2.979290 ppm 0.035555 1.19 4905.330000 2.979290
Li (670.783 nm)0.022949 ppm 0.001018 4.44 -3427.130000 0.022949
Mg (279.078 nm)0.198746 ppm 0.000886 0.45 672.967000 0.198746
Mn (257.610 nm)0.010051 ppm 0.000028 0.28 2686.420000 0.010051
Mo (202.032 nm)0.020053 ppm 0.000433 2.16 102.984000 0.020053
Na (589.592 nm)1.029990 ppm 0.010543 1.02 13673.800000 1.029990
Na H (589.593 nm)-9.154430 u ppm 0.008890 0.10 11622.611949 -9.154430 u
Ni (231.604 nm)0.041446 ppm 0.001166 2.81 130.928000 0.041446
P (213.618 nm)2.817750 ppm 0.015926 0.57 3328.410000 2.817750
Pb (220.353 nm)0.008871 ppm 0.002615 29.48 18.796000 0.008871
S (181.972 nm)0.060340 Q ppm 0.002464 4.08 36.416725 Q 0.060340 Q
Sb (206.834 nm)0.017991 ppm 0.003087 17.16 23.846600 0.017991
Se (196.026 nm)0.017226 ppm 0.000906 5.26 15.582500 0.017226
Si (288.158 nm)0.463824 ppm 0.002230 0.48 4111.610000 0.463824
Sn (189.925 nm)0.097606 ppm 0.001249 1.28 67.870400 0.097606
Sr (421.552 nm)0.009649 ppm 0.000131 1.36 2140.204304 0.009649
Th (288.505 nm)0.007634 Q ppm 0.000491 6.44 274.881000 Q 0.007634 Q
Ti (336.122 nm)0.009545 ppm 0.000075 0.78 923.795000 0.009545
Tl (190.794 nm)0.016560 ppm 0.002664 16.09 15.447000 0.016560
U (409.013 nm)0.054569 ppm 0.000702 1.29 263.455000 0.054569
V (292.401 nm)0.009611 ppm 0.000091 0.95 356.135000 0.009611
Zn (206.200 nm)0.019237 ppm 0.000935 4.86 45.644500 0.019237
Zr (343.823 nm)0.009743 ppm 0.000068 0.69 786.717000 0.009743
Test Report
52A112023.esws
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Page 1000 of 1261
Solution Name: 380-66876-A-1-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-1-B @10 11/20/2023 8:35:36 PM 3:14 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.012056 ppm 0.000249 2.07 30552.598227 0.012056
Ag (328.068 nm)0.000155 ppm 0.000038 24.34 -41.773700 0.000155
Al (394.401 nm)101.039000 o ppm 2.112510 2.09 1243780.000000 101.039000 o
Al H (396.152 nm)99.295800 ppm 0.348419 0.35 446306.000000 99.295800
As (188.980 nm)0.032601 ppm 0.002020 6.20 23.583800 0.032601
B (249.678 nm)0.007919 ppm 0.000094 1.19 82.460500 0.007919
Ba (493.408 nm)0.161797 ppm 0.000999 0.62 24535.500000 0.161797
Be (234.861 nm)0.000740 ppm 0.000030 4.11 307.105000 0.000740
Bi (223.061 nm)0.000620 u ppm 0.001072 > 100.00 5.006450 0.000620 u
Ca (315.887 nm)14.609180 o ppm 0.027822 0.19 9828.697297 14.609180 o
Cd (214.439 nm)0.000278 ppm 0.000086 30.79 6.513690 0.000278
Co (228.615 nm)0.004189 ppm 0.000266 6.35 129.242000 0.004189
Cr (205.560 nm)0.011758 ppm 0.000375 3.19 49.881100 0.011758
Cu (324.754 nm)0.164445 ppm 0.003210 1.95 8441.860000 0.164445
Fe (238.204 nm)11.146793 o ppm 0.034566 0.31 43894.956025 11.146793 o
Fe H (259.940 nm)10.914400 ppm 0.041163 0.38 17539.900000 10.914400
K (766.491 nm)2.066260 ppm 0.049164 2.38 3264.930000 2.066260
Li (670.783 nm)-0.011778 u ppm 0.045308 > 100.00 -4718.620000 -0.011778 u
Mg (279.078 nm)4.312850 ppm 0.099142 2.30 14426.200000 4.312850
Mn (257.610 nm)0.553833 ppm 0.012180 2.20 147779.000000 0.553833
Mo (202.032 nm)0.001366 ppm 0.000148 10.81 10.254900 0.001366
Na (589.592 nm)0.385738 ppm 0.019539 5.07 7625.630000 0.385738
Na H (589.593 nm)-9.712346 u ppm 0.092757 0.96 8055.675394 -9.712346 u
Ni (231.604 nm)0.012178 ppm 0.000834 6.85 31.257200 0.012178
P (213.618 nm)0.969056 ppm 0.020878 2.15 1138.590000 0.969056
Pb (220.353 nm)0.006609 ppm 0.000742 11.23 1.526740 0.006609
S (181.972 nm)1.900962 ppm 0.059938 3.15 412.508517 1.900962
Sb (206.834 nm)-0.000951 u ppm 0.000897 94.35 1.152830 -0.000951 u
Se (196.026 nm)0.001617 ppm 0.000956 59.09 5.206550 0.001617
Si (288.158 nm)0.363193 ppm 0.007147 1.97 3383.570000 0.363193
Sn (189.925 nm)0.002656 ppm 0.000435 16.37 4.065610 0.002656
Sr (421.552 nm)0.132852 ppm 0.000553 0.42 29343.369798 0.132852
Th (288.505 nm)0.024328 ppm 0.001132 4.65 315.835000 0.024328
Ti (336.122 nm)0.162384 ppm 0.003584 2.21 17633.000000 0.162384
Tl (190.794 nm)0.001745 ppm 0.001170 67.02 -1.058180 0.001745
U (409.013 nm)0.030348 ppm 0.004590 15.13 167.952000 0.030348
V (292.401 nm)0.029142 ppm 0.000496 1.70 1183.080000 0.029142
Zn (206.200 nm)0.034736 ppm 0.001095 3.15 79.067100 0.034736
Zr (343.823 nm)0.009576 ppm 0.000066 0.69 788.027000 0.009576
Test Report
52A112023.esws
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Page 1001 of 1261
Solution Name: 380-66876-A-2-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-2-B @10 11/20/2023 8:39:59 PM 3:15 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.012597 ppm 0.000272 2.16 31955.536217 0.012597
Ag (328.068 nm)0.000170 u ppm 0.000158 93.16 -44.705400 0.000170 u
Al (394.401 nm)109.429000 o ppm 2.444370 2.23 1347020.000000 109.429000 o
Al H (396.152 nm)107.422000 ppm 0.100807 0.09 482825.000000 107.422000
As (188.980 nm)0.035243 ppm 0.001832 5.20 25.764500 0.035243
B (249.678 nm)0.008401 ppm 0.000655 7.80 86.497900 0.008401
Ba (493.408 nm)0.165216 ppm 0.000375 0.23 25057.800000 0.165216
Be (234.861 nm)0.000802 ppm 0.000036 4.51 337.989000 0.000802
Bi (223.061 nm)-0.000934 u ppm 0.000087 9.27 2.695880 -0.000934 u
Ca (315.887 nm)12.259526 o ppm 0.010496 0.09 8244.045639 12.259526 o
Cd (214.439 nm)0.000172 ppm 0.000174 > 100.00 5.244440 0.000172
Co (228.615 nm)0.004565 ppm 0.000118 2.59 137.332000 0.004565
Cr (205.560 nm)0.011863 ppm 0.000670 5.64 50.308400 0.011863
Cu (324.754 nm)0.172762 ppm 0.003732 2.16 8827.940000 0.172762
Fe (238.204 nm)12.747780 o ppm 0.015134 0.12 50197.092141 12.747780 o
Fe H (259.940 nm)12.468100 ppm 0.006880 0.06 20056.600000 12.468100
K (766.491 nm)2.184230 ppm 0.113143 5.18 3476.880000 2.184230
Li (670.783 nm)-0.034170 u ppm 0.052250 > 100.00 -5551.340000 -0.034170 u
Mg (279.078 nm)4.441680 ppm 0.097802 2.20 14856.700000 4.441680
Mn (257.610 nm)0.544361 ppm 0.011306 2.08 145252.000000 0.544361
Mo (202.032 nm)0.001956 ppm 0.000508 25.95 13.185300 0.001956
Na (589.592 nm)0.445471 ppm 0.011543 2.59 8392.340000 0.445471
Na H (589.593 nm)-9.619909 u ppm 0.213354 2.22 8894.916329 -9.619909 u
Ni (231.604 nm)0.013462 ppm 0.000295 2.19 35.627600 0.013462
P (213.618 nm)1.115900 ppm 0.030623 2.74 1311.510000 1.115900
Pb (220.353 nm)0.010159 ppm 0.000716 7.05 8.679790 0.010159
S (181.972 nm)2.041637 ppm 0.047810 2.34 441.170036 2.041637
Sb (206.834 nm)-0.001751 u ppm 0.000633 36.17 0.212641 -0.001751 u
Se (196.026 nm)0.004378 ppm 0.002788 63.68 6.726640 0.004378
Si (288.158 nm)1.079220 ppm 0.021174 1.96 8591.000000 1.079220
Sn (189.925 nm)0.004266 ppm 0.001106 25.92 5.147270 0.004266
Sr (421.552 nm)0.126617 ppm 0.000395 0.31 27966.730154 0.126617
Th (288.505 nm)0.025507 ppm 0.000983 3.85 317.633000 0.025507
Ti (336.122 nm)0.185227 ppm 0.003696 2.00 20120.600000 0.185227
Tl (190.794 nm)0.001448 ppm 0.000938 64.80 -1.449000 0.001448
U (409.013 nm)0.026969 ppm 0.000816 3.03 154.205000 0.026969
V (292.401 nm)0.033000 ppm 0.000813 2.46 1343.300000 0.033000
Zn (206.200 nm)0.039037 ppm 0.000666 1.71 88.340200 0.039037
Zr (343.823 nm)0.011031 ppm 0.000215 1.95 908.858000 0.011031
Test Report
52A112023.esws
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Page 1002 of 1261
Solution Name: 380-66876-A-3-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-3-B @10 11/20/2023 8:44:20 PM 3:16 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.016056 ppm 0.000236 1.47 40873.889005 0.016056
Ag (328.068 nm)0.000293 ppm 0.000130 44.60 -40.834700 0.000293
Al (394.401 nm)143.191000 o ppm 2.076240 1.45 1762470.000000 143.191000 o
Al H (396.152 nm)138.237000 ppm 0.759287 0.55 621317.000000 138.237000
As (188.980 nm)0.042300 ppm 0.001645 3.89 31.613700 0.042300
B (249.678 nm)0.009812 ppm 0.000214 2.18 98.299700 0.009812
Ba (493.408 nm)0.208124 ppm 0.000953 0.46 31560.800000 0.208124
Be (234.861 nm)0.000930 ppm 0.000020 2.10 379.439000 0.000930
Bi (223.061 nm)-0.001781 u ppm 0.001282 71.98 1.437060 -0.001781 u
Ca (315.887 nm)14.921231 o ppm 0.092483 0.62 10039.150567 14.921231 o
Cd (214.439 nm)0.000325 ppm 0.000171 52.69 7.862300 0.000325
Co (228.615 nm)0.005324 ppm 0.000082 1.54 151.068000 0.005324
Cr (205.560 nm)0.013686 ppm 0.000662 4.84 57.807800 0.013686
Cu (324.754 nm)0.231489 ppm 0.003242 1.40 11572.700000 0.231489
Fe (238.204 nm)14.303897 o ppm 0.065601 0.46 56322.611170 14.303897 o
Fe H (259.940 nm)13.970200 ppm 0.069244 0.50 22489.700000 13.970200
K (766.491 nm)2.534530 ppm 0.062908 2.48 4106.250000 2.534530
Li (670.783 nm)-0.006380 u ppm 0.031241 > 100.00 -4517.850000 -0.006380 u
Mg (279.078 nm)5.052840 ppm 0.078433 1.55 16899.000000 5.052840
Mn (257.610 nm)0.700103 ppm 0.009926 1.42 186807.000000 0.700103
Mo (202.032 nm)0.001743 ppm 0.000558 32.01 12.129400 0.001743
Na (589.592 nm)0.369090 ppm 0.013686 3.71 7967.210000 0.369090
Na H (589.593 nm)-9.522937 u ppm 0.214856 2.26 10115.655462 -9.522937 u
Ni (231.604 nm)0.014840 ppm 0.000709 4.78 40.320100 0.014840
P (213.618 nm)1.389850 ppm 0.018076 1.30 1631.860000 1.389850
Pb (220.353 nm)0.008983 ppm 0.001285 14.30 2.311060 0.008983
S (181.972 nm)2.698877 ppm 0.058664 2.17 575.295354 2.698877
Sb (206.834 nm)0.000262 u ppm 0.002146 > 100.00 2.848970 0.000262 u
Se (196.026 nm)0.004534 u ppm 0.004837 > 100.00 6.762410 0.004534 u
Si (288.158 nm)0.337885 ppm 0.004485 1.33 3199.620000 0.337885
Sn (189.925 nm)0.000452 u ppm 0.001409 > 100.00 2.584340 0.000452 u
Sr (421.552 nm)0.164561 ppm 0.000806 0.49 36344.556676 0.164561
Th (288.505 nm)0.026645 ppm 0.001868 7.01 322.734000 0.026645
Ti (336.122 nm)0.166789 ppm 0.002343 1.40 18114.400000 0.166789
Tl (190.794 nm)0.001188 u ppm 0.001979 > 100.00 -1.726150 0.001188 u
U (409.013 nm)0.039267 ppm 0.003270 8.33 210.216000 0.039267
V (292.401 nm)0.038110 ppm 0.000444 1.16 1558.230000 0.038110
Zn (206.200 nm)0.043619 ppm 0.001377 3.16 98.220400 0.043619
Zr (343.823 nm)0.012838 ppm 0.000171 1.33 1058.230000 0.012838
Test Report
52A112023.esws
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Page 1003 of 1261
Solution Name: 380-66876-A-4-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-4-B @10 11/20/2023 8:48:42 PM 3:17 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.012416 ppm 0.000262 2.11 31469.630701 0.012416
Ag (328.068 nm)0.000227 u ppm 0.000273 > 100.00 -40.381500 0.000227 u
Al (394.401 nm)106.368000 o ppm 2.113970 1.99 1309350.000000 106.368000 o
Al H (396.152 nm)103.781000 ppm 0.341412 0.33 466462.000000 103.781000
As (188.980 nm)0.031424 ppm 0.002233 7.10 22.593700 0.031424
B (249.678 nm)0.008102 ppm 0.000653 8.06 83.995300 0.008102
Ba (493.408 nm)0.155843 ppm 0.000600 0.38 23637.300000 0.155843
Be (234.861 nm)0.000814 ppm 0.000041 5.04 336.009000 0.000814
Bi (223.061 nm)-0.001720 u ppm 0.000658 38.26 1.528530 -0.001720 u
Ca (315.887 nm)11.065995 o ppm 0.026367 0.24 7439.105706 11.065995 o
Cd (214.439 nm)0.000135 u ppm 0.000189 > 100.00 4.630550 0.000135 u
Co (228.615 nm)0.004483 ppm 0.000219 4.88 134.277000 0.004483
Cr (205.560 nm)0.011918 ppm 0.000480 4.02 50.538600 0.011918
Cu (324.754 nm)0.171881 ppm 0.003552 2.07 8792.080000 0.171881
Fe (238.204 nm)12.439440 o ppm 0.046468 0.37 48983.340687 12.439440 o
Fe H (259.940 nm)12.168600 ppm 0.030506 0.25 19571.500000 12.168600
K (766.491 nm)2.254990 ppm 0.017810 0.79 3604.020000 2.254990
Li (670.783 nm)-0.035023 u ppm 0.065403 > 100.00 -5583.090000 -0.035023 u
Mg (279.078 nm)4.054980 ppm 0.085781 2.12 13563.000000 4.054980
Mn (257.610 nm)0.483026 ppm 0.009389 1.94 128886.000000 0.483026
Mo (202.032 nm)0.001770 ppm 0.000054 3.06 12.261000 0.001770
Na (589.592 nm)0.418915 ppm 0.022054 5.26 7958.450000 0.418915
Na H (589.593 nm)-9.628961 u ppm 0.139234 1.45 8733.586856 -9.628961 u
Ni (231.604 nm)0.011661 ppm 0.000866 7.43 29.496700 0.011661
P (213.618 nm)1.072610 ppm 0.023162 2.16 1260.450000 1.072610
Pb (220.353 nm)0.007929 ppm 0.003064 38.64 4.024030 0.007929
S (181.972 nm)1.958540 ppm 0.032589 1.66 424.142527 1.958540
Sb (206.834 nm)-0.000156 u ppm 0.002942 > 100.00 2.256290 -0.000156 u
Se (196.026 nm)0.000524 u ppm 0.005404 > 100.00 4.352960 0.000524 u
Si (288.158 nm)0.289208 ppm 0.007568 2.62 2843.100000 0.289208
Sn (189.925 nm)0.002197 ppm 0.001626 74.01 3.757330 0.002197
Sr (421.552 nm)0.114529 ppm 0.000325 0.28 25297.621748 0.114529
Th (288.505 nm)0.024557 ppm 0.002653 10.80 314.630000 0.024557
Ti (336.122 nm)0.148229 ppm 0.002881 1.94 16080.700000 0.148229
Tl (190.794 nm)0.002317 ppm 0.001130 48.79 -0.437476 0.002317
U (409.013 nm)0.021686 ppm 0.001249 5.76 130.965000 0.021686
V (292.401 nm)0.032645 ppm 0.000846 2.59 1329.670000 0.032645
Zn (206.200 nm)0.041551 ppm 0.001166 2.81 93.762900 0.041551
Zr (343.823 nm)0.010382 ppm 0.000312 3.00 855.496000 0.010382
Test Report
52A112023.esws
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Page 1004 of 1261
Solution Name: 380-66876-A-5-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-5-B @10 11/20/2023 8:53:05 PM 3:18 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.021870 ppm 0.000084 0.38 55845.968785 0.021870
Ag (328.068 nm)0.000510 ppm 0.000200 39.12 -34.626600 0.000510
Al (394.401 nm)164.451000 o ppm 0.560615 0.34 2024090.000000 164.451000 o
Al H (396.152 nm)160.029000 ppm 0.803670 0.50 719252.000000 160.029000
As (188.980 nm)0.048488 ppm 0.000671 1.38 36.723400 0.048488
B (249.678 nm)0.010931 ppm 0.000747 6.84 107.668000 0.010931
Ba (493.408 nm)0.268003 ppm 0.000745 0.28 40639.900000 0.268003
Be (234.861 nm)0.001083 ppm 0.000029 2.70 451.592000 0.001083
Bi (223.061 nm)-0.000910 u ppm 0.000181 19.90 2.731820 -0.000910 u
Ca (315.887 nm)18.738611 o ppm 0.043665 0.23 12613.664170 18.738611 o
Cd (214.439 nm)0.000222 ppm 0.000210 94.65 7.051940 0.000222
Co (228.615 nm)0.006725 ppm 0.000180 2.68 179.634000 0.006725
Cr (205.560 nm)0.016380 ppm 0.000536 3.27 68.886200 0.016380
Cu (324.754 nm)0.253374 ppm 0.000863 0.34 12596.800000 0.253374
Fe (238.204 nm)17.923889 o ppm 0.047398 0.26 70572.382571 17.923889 o
Fe H (259.940 nm)17.523900 ppm 0.055426 0.32 28245.900000 17.523900
K (766.491 nm)2.897640 ppm 0.051509 1.78 4758.650000 2.897640
Li (670.783 nm)0.011710 u ppm 0.016266 > 100.00 -3845.130000 0.011710 u
Mg (279.078 nm)6.845460 ppm 0.030999 0.45 22892.400000 6.845460
Mn (257.610 nm)0.820559 ppm 0.002860 0.35 218947.000000 0.820559
Mo (202.032 nm)0.001533 ppm 0.000339 22.11 11.082600 0.001533
Na (589.592 nm)0.810695 ppm 0.003416 0.42 14036.600000 0.810695
Na H (589.593 nm)-9.125603 u ppm 0.290808 3.19 14112.296422 -9.125603 u
Ni (231.604 nm)0.019441 ppm 0.001043 5.36 55.989500 0.019441
P (213.618 nm)1.636390 ppm 0.003931 0.24 1921.800000 1.636390
Pb (220.353 nm)0.012453 ppm 0.001571 12.62 7.615240 0.012453
S (181.972 nm)3.276671 ppm 0.026200 0.80 693.307175 3.276671
Sb (206.834 nm)-0.002704 u ppm 0.002212 81.80 -0.651363 -0.002704 u
Se (196.026 nm)0.005057 ppm 0.002728 53.95 6.783560 0.005057
Si (288.158 nm)0.589431 ppm 0.001130 0.19 5037.300000 0.589431
Sn (189.925 nm)0.002398 u ppm 0.002871 > 100.00 3.892380 0.002398 u
Sr (421.552 nm)0.198809 ppm 0.000532 0.27 43906.531861 0.198809
Th (288.505 nm)0.036095 ppm 0.001127 3.12 342.370000 0.036095
Ti (336.122 nm)0.212841 ppm 0.000672 0.32 23148.000000 0.212841
Tl (190.794 nm)0.001135 u ppm 0.002022 > 100.00 -1.922430 0.001135 u
U (409.013 nm)0.035099 ppm 0.000909 2.59 195.391000 0.035099
V (292.401 nm)0.046619 ppm 0.000187 0.40 1916.270000 0.046619
Zn (206.200 nm)0.052735 ppm 0.000849 1.61 117.878000 0.052735
Zr (343.823 nm)0.015532 ppm 0.000110 0.71 1282.740000 0.015532
Test Report
52A112023.esws
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Page 1005 of 1261
Solution Name: 380-66876-A-6-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-6-B @10 11/20/2023 8:57:27 PM 3:19 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.018970 ppm 0.000240 1.27 48342.140866 0.018970
Ag (328.068 nm)0.000246 ppm 0.000214 87.05 -45.072600 0.000246
Al (394.401 nm)112.520000 o ppm 1.452360 1.29 1385050.000000 112.520000 o
Al H (396.152 nm)109.503000 ppm 0.390824 0.36 492181.000000 109.503000
As (188.980 nm)0.028720 ppm 0.001788 6.23 20.308100 0.028720
B (249.678 nm)0.009669 ppm 0.000762 7.88 97.109000 0.009669
Ba (493.408 nm)0.206007 ppm 0.000617 0.30 31247.200000 0.206007
Be (234.861 nm)0.001044 ppm 0.000042 4.06 430.590000 0.001044
Bi (223.061 nm)-0.003015 u ppm 0.000363 12.04 -0.397844 -0.003015 u
Ca (315.887 nm)20.244786 o ppm 0.077671 0.38 13629.457263 20.244786 o
Cd (214.439 nm)0.000329 u ppm 0.000381 > 100.00 8.423120 0.000329 u
Co (228.615 nm)0.006293 ppm 0.000038 0.60 171.600000 0.006293
Cr (205.560 nm)0.015023 ppm 0.000218 1.45 63.307500 0.015023
Cu (324.754 nm)0.164640 ppm 0.001985 1.21 8454.920000 0.164640
Fe (238.204 nm)16.801481 o ppm 0.080570 0.48 66154.121298 16.801481 o
Fe H (259.940 nm)16.388800 ppm 0.087358 0.53 26407.200000 16.388800
K (766.491 nm)3.147810 ppm 0.094063 2.99 5208.120000 3.147810
Li (670.783 nm)-0.018986 u ppm 0.043856 > 100.00 -4986.690000 -0.018986 u
Mg (279.078 nm)7.479830 ppm 0.102657 1.37 25015.200000 7.479830
Mn (257.610 nm)0.530634 ppm 0.006610 1.25 141589.000000 0.530634
Mo (202.032 nm)0.001500 ppm 0.000682 45.47 10.921100 0.001500
Na (589.592 nm)0.988764 ppm 0.029597 2.99 15474.600000 0.988764
Na H (589.593 nm)-9.205730 u ppm 0.273253 2.97 12874.199283 -9.205730 u
Ni (231.604 nm)0.016990 ppm 0.000842 4.95 47.643000 0.016990
P (213.618 nm)1.148750 ppm 0.016572 1.44 1350.730000 1.148750
Pb (220.353 nm)0.013567 ppm 0.000786 5.79 16.209000 0.013567
S (181.972 nm)2.365857 ppm 0.030419 1.29 507.486935 2.365857
Sb (206.834 nm)-0.002716 u ppm 0.002984 > 100.00 -0.767506 -0.002716 u
Se (196.026 nm)0.005835 ppm 0.002933 50.27 7.186580 0.005835
Si (288.158 nm)0.507823 ppm 0.006340 1.25 4445.040000 0.507823
Sn (189.925 nm)0.001389 u ppm 0.002938 > 100.00 3.214110 0.001389 u
Sr (421.552 nm)0.152172 ppm 0.000801 0.53 33609.181404 0.152172
Th (288.505 nm)0.031386 ppm 0.003924 12.50 327.830000 0.031386
Ti (336.122 nm)0.217661 ppm 0.002636 1.21 23677.200000 0.217661
Tl (190.794 nm)0.002278 u ppm 0.002901 > 100.00 -0.670470 0.002278 u
U (409.013 nm)0.021030 ppm 0.000789 3.75 132.365000 0.021030
V (292.401 nm)0.041538 ppm 0.000348 0.84 1704.270000 0.041538
Zn (206.200 nm)0.047861 ppm 0.000269 0.56 107.369000 0.047861
Zr (343.823 nm)0.012552 ppm 0.000180 1.43 1038.330000 0.012552
Test Report
52A112023.esws
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Page 1006 of 1261
Solution Name: 380-66876-A-7-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-7-B @10 11/20/2023 9:01:50 PM 3:20 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.017552 ppm 0.000280 1.59 44687.923320 0.017552
Ag (328.068 nm)0.000270 ppm 0.000236 87.50 -43.132000 0.000270
Al (394.401 nm)109.781000 o ppm 1.747290 1.59 1351350.000000 109.781000 o
Al H (396.152 nm)107.622000 ppm 0.590573 0.55 483727.000000 107.622000
As (188.980 nm)0.031173 ppm 0.001691 5.42 22.349800 0.031173
B (249.678 nm)0.009231 ppm 0.000216 2.34 93.441600 0.009231
Ba (493.408 nm)0.201892 ppm 0.000693 0.34 30623.000000 0.201892
Be (234.861 nm)0.001001 ppm 0.000046 4.60 419.384000 0.001001
Bi (223.061 nm)0.000479 u ppm 0.001976 > 100.00 4.796550 0.000479 u
Ca (315.887 nm)17.488805 o ppm 0.087511 0.50 11770.771535 17.488805 o
Cd (214.439 nm)0.000298 ppm 0.000033 10.96 7.902650 0.000298
Co (228.615 nm)0.005944 ppm 0.000143 2.41 163.774000 0.005944
Cr (205.560 nm)0.015345 ppm 0.000627 4.08 64.632500 0.015345
Cu (324.754 nm)0.164445 ppm 0.002528 1.54 8448.020000 0.164445
Fe (238.204 nm)16.476100 o ppm 0.086458 0.52 64873.286465 16.476100 o
Fe H (259.940 nm)16.095200 ppm 0.090530 0.56 25931.700000 16.095200
K (766.491 nm)3.083210 ppm 0.054054 1.75 5092.050000 3.083210
Li (670.783 nm)-0.006958 u ppm 0.029556 > 100.00 -4539.370000 -0.006958 u
Mg (279.078 nm)6.681140 ppm 0.103403 1.55 22344.000000 6.681140
Mn (257.610 nm)0.494815 ppm 0.007293 1.47 132032.000000 0.494815
Mo (202.032 nm)0.001315 ppm 0.000974 74.09 10.002700 0.001315
Na (589.592 nm)1.099610 ppm 0.022052 2.01 16775.400000 1.099610
Na H (589.593 nm)-8.829407 u ppm 0.483128 5.47 16134.174373 -8.829407 u
Ni (231.604 nm)0.015704 ppm 0.001210 7.70 43.265700 0.015704
P (213.618 nm)1.102590 ppm 0.018232 1.65 1296.260000 1.102590
Pb (220.353 nm)0.013147 ppm 0.000678 5.16 15.500200 0.013147
S (181.972 nm)2.318036 ppm 0.042257 1.82 497.638729 2.318036
Sb (206.834 nm)0.002014 ppm 0.002605 > 100.00 5.069400 0.002014
Se (196.026 nm)0.001153 ppm 0.001263 > 100.00 4.323890 0.001153
Si (288.158 nm)0.508524 ppm 0.007063 1.39 4444.350000 0.508524
Sn (189.925 nm)0.001092 ppm 0.000843 77.20 3.014980 0.001092
Sr (421.552 nm)0.137196 ppm 0.000870 0.63 30302.400246 0.137196
Th (288.505 nm)0.027904 ppm 0.000876 3.14 320.650000 0.027904
Ti (336.122 nm)0.188972 ppm 0.002621 1.39 20540.600000 0.188972
Tl (190.794 nm)0.002209 ppm 0.001861 84.24 -0.691813 0.002209
U (409.013 nm)0.017657 ppm 0.003508 19.87 117.243000 0.017657
V (292.401 nm)0.040365 ppm 0.000563 1.40 1654.730000 0.040365
Zn (206.200 nm)0.045374 ppm 0.001062 2.34 102.005000 0.045374
Zr (343.823 nm)0.012221 ppm 0.000152 1.24 1010.890000 0.012221
Test Report
52A112023.esws
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Page 1007 of 1261
Solution Name: 380-66876-A-8-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-8-B @10 11/20/2023 9:06:11 PM 3:21 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.017899 ppm 0.000034 0.19 45584.416208 0.017899
Ag (328.068 nm)0.000340 ppm 0.000082 24.08 -42.096500 0.000340
Al (394.401 nm)126.093000 o ppm 0.399067 0.32 1552090.000000 126.093000 o
Al H (396.152 nm)122.728000 ppm 0.865455 0.71 551614.000000 122.728000
As (188.980 nm)0.032560 ppm 0.004601 14.13 23.500200 0.032560
B (249.678 nm)0.009475 ppm 0.000365 3.86 95.484900 0.009475
Ba (493.408 nm)0.195667 ppm 0.001307 0.67 29680.700000 0.195667
Be (234.861 nm)0.001035 ppm 0.000028 2.72 427.003000 0.001035
Bi (223.061 nm)-0.001410 u ppm 0.001793 > 100.00 1.988230 -0.001410 u
Ca (315.887 nm)16.302256 o ppm 0.126695 0.78 10970.539952 16.302256 o
Cd (214.439 nm)0.000190 ppm 0.000161 85.06 6.309780 0.000190
Co (228.615 nm)0.006082 ppm 0.000166 2.73 165.516000 0.006082
Cr (205.560 nm)0.013722 ppm 0.000107 0.78 57.955700 0.013722
Cu (324.754 nm)0.184800 ppm 0.000307 0.17 9393.800000 0.184800
Fe (238.204 nm)16.632405 o ppm 0.094819 0.57 65488.566846 16.632405 o
Fe H (259.940 nm)16.230900 ppm 0.110189 0.68 26151.500000 16.230900
K (766.491 nm)3.146750 ppm 0.034047 1.08 5206.200000 3.146750
Li (670.783 nm)-0.044322 u ppm 0.048667 > 100.00 -5928.920000 -0.044322 u
Mg (279.078 nm)6.344020 ppm 0.021561 0.34 21216.900000 6.344020
Mn (257.610 nm)0.491996 ppm 0.001357 0.28 131279.000000 0.491996
Mo (202.032 nm)0.002115 ppm 0.000343 16.21 13.974100 0.002115
Na (589.592 nm)0.952208 ppm 0.025478 2.68 14908.000000 0.952208
Na H (589.593 nm)-9.278801 u ppm 0.350950 3.78 12144.214116 -9.278801 u
Ni (231.604 nm)0.015333 ppm 0.000397 2.59 42.000000 0.015333
P (213.618 nm)1.235370 ppm 0.007303 0.59 1451.930000 1.235370
Pb (220.353 nm)0.014416 ppm 0.001656 11.49 16.623800 0.014416
S (181.972 nm)2.728138 ppm 0.014717 0.54 581.140026 2.728138
Sb (206.834 nm)-0.001220 u ppm 0.002316 > 100.00 1.202110 -0.001220 u
Se (196.026 nm)0.002594 u ppm 0.004311 > 100.00 5.189980 0.002594 u
Si (288.158 nm)0.501953 ppm 0.001971 0.39 4391.970000 0.501953
Sn (189.925 nm)0.000754 u ppm 0.002230 > 100.00 2.787910 0.000754 u
Sr (421.552 nm)0.139392 ppm 0.000887 0.64 30787.319385 0.139392
Th (288.505 nm)0.029700 ppm 0.001303 4.39 323.845000 0.029700
Ti (336.122 nm)0.166657 ppm 0.000689 0.41 18103.000000 0.166657
Tl (190.794 nm)0.000955 ppm 0.000449 47.07 -2.020730 0.000955
U (409.013 nm)0.023248 ppm 0.001851 7.96 141.648000 0.023248
V (292.401 nm)0.042492 ppm 0.000210 0.50 1741.570000 0.042492
Zn (206.200 nm)0.047243 ppm 0.000423 0.90 106.037000 0.047243
Zr (343.823 nm)0.012663 ppm 0.000079 0.62 1047.140000 0.012663
Test Report
52A112023.esws
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Page 1008 of 1261
Solution Name: 380-66876-A-9-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-9-B @10 11/20/2023 9:10:35 PM 3:22 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014514 ppm 0.000117 0.80 36906.242716 0.014514
Ag (328.068 nm)0.000510 ppm 0.000237 46.43 -27.020600 0.000510
Al (394.401 nm)127.401000 o ppm 1.030170 0.81 1568170.000000 127.401000 o
Al H (396.152 nm)124.313000 ppm 0.332813 0.27 558739.000000 124.313000
As (188.980 nm)0.041967 ppm 0.005665 13.50 31.346100 0.041967
B (249.678 nm)0.009276 ppm 0.000656 7.07 93.815800 0.009276
Ba (493.408 nm)0.195009 ppm 0.000656 0.34 29571.800000 0.195009
Be (234.861 nm)0.000902 ppm 0.000030 3.38 362.575000 0.000902
Bi (223.061 nm)-0.000532 u ppm 0.001783 > 100.00 3.293900 -0.000532 u
Ca (315.887 nm)14.648669 o ppm 0.022908 0.16 9855.329266 14.648669 o
Cd (214.439 nm)0.000159 ppm 0.000133 84.07 5.177020 0.000159
Co (228.615 nm)0.004884 ppm 0.000027 0.55 143.438000 0.004884
Cr (205.560 nm)0.012702 ppm 0.000663 5.22 53.758100 0.012702
Cu (324.754 nm)0.217789 ppm 0.001989 0.91 10933.800000 0.217789
Fe (238.204 nm)13.352940 o ppm 0.016528 0.12 52579.254746 13.352940 o
Fe H (259.940 nm)13.037100 ppm 0.027931 0.21 20978.300000 13.037100
K (766.491 nm)2.510660 ppm 0.061082 2.43 4063.370000 2.510660
Li (670.783 nm)-0.003831 u ppm 0.024539 > 100.00 -4423.070000 -0.003831 u
Mg (279.078 nm)5.025100 ppm 0.039529 0.79 16806.800000 5.025100
Mn (257.610 nm)0.606730 ppm 0.004626 0.76 161893.000000 0.606730
Mo (202.032 nm)0.002158 ppm 0.000575 26.67 14.184300 0.002158
Na (589.592 nm)0.604685 ppm 0.011253 1.86 10676.900000 0.604685
Na H (589.593 nm)-9.527003 u ppm 0.181547 1.91 9966.287683 -9.527003 u
Ni (231.604 nm)0.014574 ppm 0.000284 1.95 39.415200 0.014574
P (213.618 nm)1.251160 ppm 0.013049 1.04 1468.830000 1.251160
Pb (220.353 nm)0.010313 ppm 0.002742 26.59 7.010390 0.010313
S (181.972 nm)2.372745 ppm 0.049086 2.07 508.737951 2.372745
Sb (206.834 nm)-0.001132 u ppm 0.003092 > 100.00 1.014740 -0.001132 u
Se (196.026 nm)0.002637 ppm 0.001003 38.02 5.636450 0.002637
Si (288.158 nm)1.421450 ppm 0.010227 0.72 11076.500000 1.421450
Sn (189.925 nm)0.000546 u ppm 0.001150 > 100.00 2.647750 0.000546 u
Sr (421.552 nm)0.156744 ppm 0.000684 0.44 34618.581381 0.156744
Th (288.505 nm)0.028021 ppm 0.003925 14.01 323.548000 0.028021
Ti (336.122 nm)0.185817 ppm 0.001436 0.77 20190.200000 0.185817
Tl (190.794 nm)-0.001242 u ppm 0.000930 74.94 -4.381220 -0.001242 u
U (409.013 nm)0.033770 ppm 0.001689 5.00 185.199000 0.033770
V (292.401 nm)0.035454 ppm 0.000350 0.99 1448.080000 0.035454
Zn (206.200 nm)0.043657 ppm 0.000268 0.61 98.303600 0.043657
Zr (343.823 nm)0.011455 ppm 0.000189 1.65 944.219000 0.011455
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 138 of 287
Page 1009 of 1261
Solution Name: 380-66876-A-10-B @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
380-66876-A-10-B @10 11/20/2023 9:14:57 PM 3:23 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.016568 ppm 0.000132 0.80 42187.424302 0.016568
Ag (328.068 nm)0.000274 ppm 0.000085 30.91 -43.129000 0.000274
Al (394.401 nm)139.005000 o ppm 1.090580 0.78 1710970.000000 139.005000 o
Al H (396.152 nm)135.607000 ppm 0.594787 0.44 609496.000000 135.607000
As (188.980 nm)0.040600 ppm 0.002660 6.55 30.184800 0.040600
B (249.678 nm)0.009659 ppm 0.000292 3.03 97.026800 0.009659
Ba (493.408 nm)0.196466 ppm 0.000718 0.37 29800.400000 0.196466
Be (234.861 nm)0.000964 ppm 0.000044 4.56 409.179000 0.000964
Bi (223.061 nm)-0.000443 u ppm 0.001620 > 100.00 3.426340 -0.000443 u
Ca (315.887 nm)14.548309 o ppm 0.061479 0.42 9787.644775 14.548309 o
Cd (214.439 nm)0.000191 u ppm 0.000212 > 100.00 6.235390 0.000191 u
Co (228.615 nm)0.005479 ppm 0.000099 1.81 154.394000 0.005479
Cr (205.560 nm)0.015469 ppm 0.000650 4.20 65.143600 0.015469
Cu (324.754 nm)0.221521 ppm 0.001663 0.75 11112.500000 0.221521
Fe (238.204 nm)16.167115 o ppm 0.057720 0.36 63656.999093 16.167115 o
Fe H (259.940 nm)15.795500 ppm 0.036778 0.23 25446.200000 15.795500
K (766.491 nm)2.790050 ppm 0.072883 2.61 4565.330000 2.790050
Li (670.783 nm)-0.035990 u ppm 0.051970 > 100.00 -5619.030000 -0.035990 u
Mg (279.078 nm)5.202130 ppm 0.039806 0.77 17397.200000 5.202130
Mn (257.610 nm)0.608278 ppm 0.004825 0.79 162306.000000 0.608278
Mo (202.032 nm)0.001795 ppm 0.000494 27.52 12.384500 0.001795
Na (589.592 nm)0.612427 ppm 0.018131 2.96 10788.300000 0.612427
Na H (589.593 nm)-9.669982 u ppm 0.256386 2.65 8727.431727 -9.669982 u
Ni (231.604 nm)0.014758 ppm 0.000307 2.08 40.040700 0.014758
P (213.618 nm)1.405630 ppm 0.015272 1.09 1651.020000 1.405630
Pb (220.353 nm)0.011160 ppm 0.001430 12.81 7.593990 0.011160
S (181.972 nm)2.634278 ppm 0.040073 1.52 562.108694 2.634278
Sb (206.834 nm)-0.000645 u ppm 0.002063 > 100.00 1.850860 -0.000645 u
Se (196.026 nm)0.007453 ppm 0.001572 21.09 8.297870 0.007453
Si (288.158 nm)0.784512 ppm 0.005792 0.74 6447.260000 0.784512
Sn (189.925 nm)0.001980 u ppm 0.002485 > 100.00 3.611570 0.001980 u
Sr (421.552 nm)0.146166 ppm 0.000351 0.24 32283.097422 0.146166
Th (288.505 nm)0.026364 ppm 0.002177 8.26 320.099000 0.026364
Ti (336.122 nm)0.175972 ppm 0.001353 0.77 19115.700000 0.175972
Tl (190.794 nm)0.001267 u ppm 0.003137 > 100.00 -1.688570 0.001267 u
U (409.013 nm)0.028359 ppm 0.001191 4.20 164.075000 0.028359
V (292.401 nm)0.041234 ppm 0.000376 0.91 1690.530000 0.041234
Zn (206.200 nm)0.048585 ppm 0.000654 1.35 108.929000 0.048585
Zr (343.823 nm)0.013795 ppm 0.000158 1.15 1138.780000 0.013795
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 139 of 287
Page 1010 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 9:19:21 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)-0.000053 u ppm 0.000001 2.59 806.530410 -0.000053 u
Ag (328.068 nm)0.000003 u ppm 0.000098 > 100.00 113.626000 0.000003 u
Al (394.401 nm)52.287500 o ppm 0.348507 0.67 642806.000000 52.287500 o
Al H (396.152 nm)48.887400 ppm 0.170429 0.35 219761.000000 48.887400
As (188.980 nm)0.001818 u ppm 0.002466 > 100.00 -2.340040 0.001818 u
B (249.678 nm)-0.002973 u ppm 0.000054 1.81 -8.699470 -0.002973 u
Ba (493.408 nm)0.000195 u ppm 0.000212 > 100.00 169.412000 0.000195 u
Be (234.861 nm)0.000106 ppm 0.000100 94.26 702.208000 0.000106
Bi (223.061 nm)-0.001517 u ppm 0.000717 47.25 1.829200 -0.001517 u
Ca (315.887 nm)-0.019098 u ppm 0.011242 58.87 -36.892587 -0.019098 u
Cd (214.439 nm)-0.000035 u ppm 0.000302 > 100.00 9.771460 -0.000035 u
Co (228.615 nm)0.000262 ppm 0.000158 60.46 47.844500 0.000262
Cr (205.560 nm)0.000703 ppm 0.000237 33.72 4.412390 0.000703
Cu (324.754 nm)-0.000630 u ppm 0.000198 31.45 1680.890000 -0.000630 u
Fe (238.204 nm)50.055529 o ppm 0.181404 0.36 197055.637209 50.055529 o
Fe H (259.940 nm)48.326400 ppm 0.181231 0.38 78138.900000 48.326400
K (766.491 nm)0.016598 u ppm 0.084963 > 100.00 -417.592000 0.016598 u
Li (670.783 nm)0.005004 ppm 0.002504 50.05 -4094.520000 0.005004
Mg (279.078 nm)0.002138 ppm 0.001396 65.28 -173.629000 0.002138
Mn (257.610 nm)-0.000900 u ppm 0.000039 4.29 -235.625000 -0.000900 u
Mo (202.032 nm)-0.000217 u ppm 0.000402 > 100.00 2.402930 -0.000217 u
Na (589.592 nm)247.412000 o ppm 1.543360 0.62 3008380.000000 247.412000 o
Na H (589.593 nm)239.201358 ppm 0.552073 0.23 2185690.575725 239.201358
Ni (231.604 nm)0.000347 u ppm 0.000465 > 100.00 -9.029440 0.000347 u
P (213.618 nm)5.075610 ppm 0.041015 0.81 5994.340000 5.075610
Pb (220.353 nm)0.000440 ppm 0.000310 70.43 -2.147600 0.000440
S (181.972 nm)4.764939 ppm 0.032404 0.68 996.336826 4.764939
Sb (206.834 nm)0.000081 u ppm 0.001270 > 100.00 5.565510 0.000081 u
Se (196.026 nm)0.004398 ppm 0.004497 > 100.00 2.469900 0.004398
Si (288.158 nm)0.026899 ppm 0.001679 6.24 906.830000 0.026899
Sn (189.925 nm)-0.000920 u ppm 0.001028 > 100.00 1.662600 -0.000920 u
Sr (421.552 nm)0.000552 ppm 0.000020 3.64 131.624420 0.000552
Th (288.505 nm)4.627070 ppm 0.024263 0.52 8907.700000 4.627070
Ti (336.122 nm)0.000674 ppm 0.000047 6.99 -44.575200 0.000674
Tl (190.794 nm)-0.004740 u ppm 0.002594 54.71 -8.533360 -0.004740 u
U (409.013 nm)2.409520 Q ppm 0.011614 0.48 10762.800000 Q 2.409520 Q
V (292.401 nm)0.000482 ppm 0.000188 38.99 262.852000 0.000482
Zn (206.200 nm)0.000594 ppm 0.000159 26.72 5.444640 0.000594
Zr (343.823 nm)-0.000861 u ppm 0.000092 10.69 -10.160800 -0.000861 u
Test Report
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Page 1011 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 9:23:50 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.449868 Q ppm 0.000581 0.13 1153561.148155
Q 0.449868 Q
Ag (328.068 nm)0.502866 ppm 0.002832 0.56 26860.200000 0.502866
Al (394.401 nm)0.493447 ppm 0.002660 0.54 6526.500000 0.493447
Al H (396.152 nm)0.497727 u ppm 0.001839 0.37 2287.450000 0.497727 u
As (188.980 nm)0.502304 ppm 0.001368 0.27 413.927000 0.502304
B (249.678 nm)0.492992 ppm 0.001343 0.27 4142.350000 0.492992
Ba (493.408 nm)0.494428 ppm 0.001967 0.40 74889.400000 0.494428
Be (234.861 nm)0.501260 ppm 0.003653 0.73 83819.200000 0.501260
Bi (223.061 nm)0.987579 ppm 0.006925 0.70 1472.400000 0.987579
Ca (315.887 nm)4.958477 ppm 0.021791 0.44 3320.078930 4.958477
Cd (214.439 nm)0.504321 ppm 0.000890 0.18 7538.600000 0.504321
Co (228.615 nm)0.507002 ppm 0.000848 0.17 9730.810000 0.507002
Cr (205.560 nm)0.510188 ppm 0.002398 0.47 2098.540000 0.510188
Cu (324.754 nm)0.498681 ppm 0.001166 0.23 24023.500000 0.498681
Fe (238.204 nm)2.476892 ppm 0.015480 0.62 9772.940669 2.476892
Fe H (259.940 nm)2.489840 u ppm 0.018441 0.74 3894.150000 2.489840 u
K (766.491 nm)49.894700 ppm 0.189228 0.38 89196.000000 49.894700
Li (670.783 nm)0.491185 ppm 0.001636 0.33 13986.300000 0.491185
Mg (279.078 nm)20.014700 ppm 0.046233 0.23 66951.000000 20.014700
Mn (257.610 nm)0.489586 ppm 0.001025 0.21 130636.000000 0.489586
Mo (202.032 nm)0.498524 ppm 0.000866 0.17 2477.190000 0.498524
Na (589.592 nm)24.479100 ppm 0.115403 0.47 304381.000000 24.479100
Na H (589.593 nm)14.161431 u ppm 0.024998 0.18 219929.426614 14.161431 u
Ni (231.604 nm)0.506000 ppm 0.001355 0.27 1713.150000 0.506000
P (213.618 nm)0.009792 ppm 0.001530 15.62 -25.549200 0.009792
Pb (220.353 nm)0.534072 ppm 0.001065 0.20 1223.710000 0.534072
S (181.972 nm)-0.023516 u ppm 0.009394 39.95 21.761431 -0.023516 u
Sb (206.834 nm)0.491051 ppm 0.003870 0.79 599.990000 0.491051
Se (196.026 nm)0.506253 ppm 0.004491 0.89 315.750000 0.506253
Si (288.158 nm)4.913030 ppm 0.017741 0.36 36650.700000 4.913030
Sn (189.925 nm)0.498917 ppm 0.003217 0.64 337.546000 0.498917
Sr (421.552 nm)0.495634 ppm 0.001740 0.35 109445.316302 0.495634
Th (288.505 nm)0.040242 ppm 0.007254 18.03 323.928000 0.040242
Ti (336.122 nm)0.496772 ppm 0.000809 0.16 54100.100000 0.496772
Tl (190.794 nm)0.500530 ppm 0.003227 0.64 539.899000 0.500530
U (409.013 nm)-0.005278 u ppm 0.001911 36.20 -13.140300 -0.005278 u
V (292.401 nm)0.496552 ppm 0.001433 0.29 20634.500000 0.496552
Zn (206.200 nm)0.505327 ppm 0.001798 0.36 1093.830000 0.505327
Zr (343.823 nm)0.490831 ppm 0.000618 0.13 40008.000000 0.490831
Test Report
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Page 1012 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 9:28:12 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000423 ppm 0.000004 0.87 489.638214 0.000423
Ag (328.068 nm)0.000024 u ppm 0.000109 > 100.00 -27.817700 0.000024 u
Al (394.401 nm)-0.000286 u ppm 0.001630 > 100.00 446.631000 -0.000286 u
Al H (396.152 nm)-0.001504 u ppm 0.004435 > 100.00 43.805300 -0.001504 u
As (188.980 nm)0.000914 u ppm 0.001436 > 100.00 -2.645350 0.000914 u
B (249.678 nm)0.000186 ppm 0.000048 25.87 17.736600 0.000186
Ba (493.408 nm)0.000174 ppm 0.000092 53.13 25.747100 0.000174
Be (234.861 nm)0.000000 u ppm 0.000033 > 100.00 39.937400 0.000000 u
Bi (223.061 nm)0.000732 u ppm 0.000876 > 100.00 5.173440 0.000732 u
Ca (315.887 nm)0.010432 ppm 0.003285 31.49 -16.977358 0.010432
Cd (214.439 nm)0.000118 ppm 0.000051 43.06 1.834090 0.000118
Co (228.615 nm)0.000027 u ppm 0.000163 > 100.00 43.362400 0.000027 u
Cr (205.560 nm)-0.000021 u ppm 0.000341 > 100.00 1.437670 -0.000021 u
Cu (324.754 nm)0.000488 ppm 0.000168 34.38 788.895000 0.000488
Fe (238.204 nm)0.000492 u ppm 0.002050 > 100.00 18.538705 0.000492 u
Fe H (259.940 nm)0.096067 u ppm 0.000486 0.51 16.780400 0.096067 u
K (766.491 nm)-0.013746 u ppm 0.050932 > 100.00 -472.109000 -0.013746 u
Li (670.783 nm)0.004735 S ppm 0.001545 32.64 -4104.510000 S 0.004735 S
Mg (279.078 nm)0.000923 ppm 0.000859 93.05 11.916900 0.000923
Mn (257.610 nm)-0.000035 u ppm 0.000006 16.71 -4.909330 -0.000035 u
Mo (202.032 nm)0.000910 ppm 0.000557 61.19 7.993360 0.000910
Na (589.592 nm)0.025899 ppm 0.003330 12.86 1351.770000 0.025899
Na H (589.593 nm)-10.169293 u ppm 0.009237 0.09 2651.789280 -10.169293 u
Ni (231.604 nm)-0.000319 u ppm 0.000410 > 100.00 -11.297100 -0.000319 u
P (213.618 nm)-0.001717 u ppm 0.002829 > 100.00 1.038420 -0.001717 u
Pb (220.353 nm)0.000298 u ppm 0.000593 > 100.00 -0.936443 0.000298 u
S (181.972 nm)-0.031757 u ppm 0.002188 6.89 17.599155 -0.031757 u
Sb (206.834 nm)0.001722 ppm 0.001311 76.16 4.100930 0.001722
Se (196.026 nm)-0.001845 u ppm 0.002526 > 100.00 3.883050 -0.001845 u
Si (288.158 nm)-0.000610 u ppm 0.001497 > 100.00 707.350000 -0.000610 u
Sn (189.925 nm)0.000060 u ppm 0.001698 > 100.00 2.321360 0.000060 u
Sr (421.552 nm)0.000045 u ppm 0.000073 > 100.00 19.696092 0.000045 u
Th (288.505 nm)0.008358 Z ppm 0.002050 24.52 276.159000 Z 0.008358 Z
Ti (336.122 nm)-0.000026 u ppm 0.000116 > 100.00 -120.913000 -0.000026 u
Tl (190.794 nm)0.001343 ppm 0.000496 36.91 -1.031350 0.001343
U (409.013 nm)-0.000179 u ppm 0.002731 > 100.00 22.718600 -0.000179 u
V (292.401 nm)0.000104 ppm 0.000043 41.32 -34.795900 0.000104
Zn (206.200 nm)-0.000205 u ppm 0.000240 > 100.00 3.720620 -0.000205 u
Zr (343.823 nm)0.000049 u ppm 0.000111 > 100.00 -3.659110 0.000049 u
Test Report
52A112023.esws
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Page 1013 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 9:32:14 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014236 ppm 0.000022 0.15 36007.276571 0.014236
Ag (328.068 nm)0.009783 ppm 0.000077 0.79 491.432000 0.009783
Al (394.401 nm)0.088417 ppm 0.000463 0.52 1548.410000 0.088417
Al H (396.152 nm)0.093872 u ppm 0.000904 0.96 472.443000 0.093872 u
As (188.980 nm)0.014791 ppm 0.002764 18.69 8.884170 0.014791
B (249.678 nm)0.094943 ppm 0.000654 0.69 810.820000 0.094943
Ba (493.408 nm)0.009686 ppm 0.000183 1.89 1466.620000 0.009686
Be (234.861 nm)0.000973 ppm 0.000009 0.88 203.658000 0.000973
Bi (223.061 nm)-0.000185 Qu ppm 0.001290 > 100.00 3.809620 Q -0.000185 Qu
Ca (315.887 nm)0.208217 ppm 0.007885 3.79 116.413065 0.208217
Cd (214.439 nm)0.005147 ppm 0.000071 1.39 77.022000 0.005147
Co (228.615 nm)0.010083 ppm 0.000109 1.08 235.476000 0.010083
Cr (205.560 nm)0.009331 ppm 0.000551 5.91 39.807700 0.009331
Cu (324.754 nm)0.014935 ppm 0.000161 1.08 1456.180000 0.014935
Fe (238.204 nm)0.099335 ppm 0.001653 1.66 407.690583 0.099335
Fe H (259.940 nm)0.189445 u ppm 0.002866 1.51 168.032000 0.189445 u
K (766.491 nm)3.018280 ppm 0.050259 1.67 4975.380000 3.018280
Li (670.783 nm)0.022760 ppm 0.000754 3.31 -3434.170000 0.022760
Mg (279.078 nm)0.199131 ppm 0.001339 0.67 674.296000 0.199131
Mn (257.610 nm)0.010038 ppm 0.000034 0.34 2682.930000 0.010038
Mo (202.032 nm)0.020047 ppm 0.000725 3.62 102.951000 0.020047
Na (589.592 nm)1.017600 ppm 0.017065 1.68 13521.500000 1.017600
Na H (589.593 nm)-9.189299 u ppm 0.003699 0.04 11316.090542 -9.189299 u
Ni (231.604 nm)0.040648 ppm 0.000867 2.13 128.212000 0.040648
P (213.618 nm)2.827530 ppm 0.010729 0.38 3339.950000 2.827530
Pb (220.353 nm)0.008804 ppm 0.001234 14.01 18.638200 0.008804
S (181.972 nm)0.051818 Q ppm 0.012700 24.51 34.690844 Q 0.051818 Q
Sb (206.834 nm)0.021069 ppm 0.005365 25.46 27.596100 0.021069
Se (196.026 nm)0.021632 ppm 0.006079 28.10 18.286200 0.021632
Si (288.158 nm)0.463127 ppm 0.004072 0.88 4106.620000 0.463127
Sn (189.925 nm)0.097655 ppm 0.000816 0.84 67.903700 0.097655
Sr (421.552 nm)0.009621 ppm 0.000071 0.74 2133.936879 0.009621
Th (288.505 nm)0.007184 Q ppm 0.002681 37.31 274.051000 Q 0.007184 Q
Ti (336.122 nm)0.009536 ppm 0.000056 0.59 922.838000 0.009536
Tl (190.794 nm)0.016364 ppm 0.000925 5.66 15.234700 0.016364
U (409.013 nm)0.053265 ppm 0.003581 6.72 257.704000 0.053265
V (292.401 nm)0.009840 ppm 0.000062 0.63 365.907000 0.009840
Zn (206.200 nm)0.019717 ppm 0.000826 4.19 46.680200 0.019717
Zr (343.823 nm)0.009727 ppm 0.000133 1.37 785.392000 0.009727
Test Report
52A112023.esws
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Page 1014 of 1261
Solution Name: MB 280-634363/1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
MB 280-634363/1-A 11/20/2023 9:36:35 PM 4:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000611 ppm 0.000005 0.88 981.947425 0.000611
Ag (328.068 nm)-0.000013 u ppm 0.000097 > 100.00 -29.854800 -0.000013 u
Al (394.401 nm)0.011659 ppm 0.001340 11.49 594.491000 0.011659
Al H (396.152 nm)0.013540 u ppm 0.001935 14.29 111.415000 0.013540 u
As (188.980 nm)0.001918 ppm 0.000868 45.27 -1.811210 0.001918
B (249.678 nm)-0.000075 u ppm 0.000876 > 100.00 15.552400 -0.000075 u
Ba (493.408 nm)0.000024 u ppm 0.000100 > 100.00 3.070300 0.000024 u
Be (234.861 nm)-0.000011 u ppm 0.000030 > 100.00 38.106200 -0.000011 u
Bi (223.061 nm)-0.000291 u ppm 0.000618 > 100.00 3.651980 -0.000291 u
Ca (315.887 nm)0.023305 ppm 0.004430 19.01 -8.295284 0.023305
Cd (214.439 nm)0.000096 u ppm 0.000192 > 100.00 1.509820 0.000096 u
Co (228.615 nm)-0.000187 u ppm 0.000172 92.08 39.285300 -0.000187 u
Cr (205.560 nm)-0.000127 u ppm 0.000562 > 100.00 0.999565 -0.000127 u
Cu (324.754 nm)0.000485 ppm 0.000448 92.49 788.015000 0.000485
Fe (238.204 nm)0.005623 ppm 0.000840 14.94 38.740002 0.005623
Fe H (259.940 nm)0.100113 u ppm 0.000790 0.79 23.335000 0.100113 u
K (766.491 nm)-0.028646 u ppm 0.020028 69.91 -498.880000 -0.028646 u
Li (670.783 nm)0.005254 ppm 0.002974 56.61 -4085.210000 0.005254
Mg (279.078 nm)0.157902 ppm 0.001458 0.92 537.084000 0.157902
Mn (257.610 nm)0.000987 ppm 0.000022 2.27 267.724000 0.000987
Mo (202.032 nm)0.000563 ppm 0.000170 30.14 6.272050 0.000563
Na (589.592 nm)0.411848 ppm 0.006242 1.52 6044.220000 0.411848
Na H (589.593 nm)-9.798041 u ppm 0.004636 0.05 5902.652349 -9.798041 u
Ni (231.604 nm)-0.000097 u ppm 0.000417 > 100.00 -10.542100 -0.000097 u
P (213.618 nm)-0.000088 u ppm 0.001461 > 100.00 2.982260 -0.000088 u
Pb (220.353 nm)-0.000001 u ppm 0.001258 > 100.00 -1.627910 -0.000001 u
S (181.972 nm)0.405732 ppm 0.002593 0.64 106.696625 0.405732
Sb (206.834 nm)0.000264 u ppm 0.003180 > 100.00 2.325030 0.000264 u
Se (196.026 nm)-0.000163 u ppm 0.006184 > 100.00 4.915490 -0.000163 u
Si (288.158 nm)0.001348 ppm 0.000794 58.91 721.463000 0.001348
Sn (189.925 nm)-0.000134 u ppm 0.000925 > 100.00 2.190640 -0.000134 u
Sr (421.552 nm)0.000295 ppm 0.000098 33.17 74.765259 0.000295
Th (288.505 nm)0.004999 ppm 0.002051 41.03 269.905000 0.004999
Ti (336.122 nm)-0.000058 u ppm 0.000079 > 100.00 -124.333000 -0.000058 u
Tl (190.794 nm)-0.001016 u ppm 0.001051 > 100.00 -3.591870 -0.001016 u
U (409.013 nm)0.000589 u ppm 0.003118 > 100.00 26.050300 0.000589 u
V (292.401 nm)0.000031 u ppm 0.000175 > 100.00 -38.050100 0.000031 u
Zn (206.200 nm)0.001023 ppm 0.000673 65.75 6.368550 0.001023
Zr (343.823 nm)0.000010 ppm 0.000009 83.85 -6.800580 0.000010
Test Report
52A112023.esws
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Page 1015 of 1261
Solution Name: LCS 280-634363/2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634363/2-A 11/20/2023 9:40:38 PM 4:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.949361 ppm 0.005396 0.57 2435358.917167 0.949361
Ag (328.068 nm)0.050978 ppm 0.000283 0.55 2235.410000 0.050978
Al (394.401 nm)9.838970 o ppm 0.049112 0.50 121517.000000 9.838970 o
Al H (396.152 nm)9.491150 ppm 0.028869 0.30 42705.700000 9.491150
As (188.980 nm)1.005720 ppm 0.007323 0.73 832.136000 1.005720
B (249.678 nm)2.000800 ppm 0.008463 0.42 16762.200000 2.000800
Ba (493.408 nm)0.976218 ppm 0.002025 0.21 147879.000000 0.976218
Be (234.861 nm)1.004350 ppm 0.005606 0.56 167968.000000 1.004350
Bi (223.061 nm)-0.000058 u ppm 0.003201 > 100.00 3.999310 -0.000058 u
Ca (315.887 nm)49.685272 o ppm 0.145397 0.29 33484.683481 49.685272 o
Cd (214.439 nm)0.984664 ppm 0.005543 0.56 14719.700000 0.984664
Co (228.615 nm)0.967574 ppm 0.004746 0.49 18532.800000 0.967574
Cr (205.560 nm)0.986999 ppm 0.006424 0.65 4058.300000 0.986999
Cu (324.754 nm)0.960829 ppm 0.004879 0.51 45569.600000 0.960829
Fe (238.204 nm)9.910537 o ppm 0.049482 0.50 39040.775311 9.910537 o
Fe H (259.940 nm)9.682330 ppm 0.015863 0.16 15544.300000 9.682330
K (766.491 nm)50.331100 ppm 0.347080 0.69 89980.100000 50.331100
Li (670.783 nm)0.980120 ppm 0.006078 0.62 32169.500000 0.980120
Mg (279.078 nm)50.522700 o ppm 0.241262 0.48 168985.000000 50.522700 o
Mn (257.610 nm)0.983349 ppm 0.004626 0.47 262383.000000 0.983349
Mo (202.032 nm)0.991622 ppm 0.004323 0.44 4923.990000 0.991622
Na (589.592 nm)48.340900 ppm 0.472343 0.98 600068.000000 48.340900
Na H (589.593 nm)38.672887 u ppm 0.333312 0.86 438676.215875 38.672887 u
Ni (231.604 nm)0.961156 ppm 0.004893 0.51 3263.360000 0.961156
P (213.618 nm)20.159700 o ppm 0.115977 0.58 23725.200000 20.159700 o
Pb (220.353 nm)1.042810 ppm 0.007088 0.68 2389.910000 1.042810
S (181.972 nm)18.276850 o ppm 0.078155 0.43 3750.870241 18.276850 o
Sb (206.834 nm)1.020440 ppm 0.006034 0.59 1244.920000 1.020440
Se (196.026 nm)0.986088 ppm 0.001587 0.16 609.757000 0.986088
Si (288.158 nm)9.496270 ppm 0.010602 0.11 70183.300000 9.496270
Sn (189.925 nm)0.971706 ppm 0.007302 0.75 655.254000 0.971706
Sr (421.552 nm)0.978492 ppm 0.001833 0.19 216060.161462 0.978492
Th (288.505 nm)0.066470 ppm 0.003361 5.06 361.778000 0.066470
Ti (336.122 nm)0.979386 ppm 0.004847 0.49 106860.000000 0.979386
Tl (190.794 nm)0.975506 ppm 0.004289 0.44 1054.390000 0.975506
U (409.013 nm)-0.007307 u ppm 0.003107 42.53 -29.614200 -0.007307 u
V (292.401 nm)0.985256 ppm 0.004789 0.49 40992.100000 0.985256
Zn (206.200 nm)0.983855 ppm 0.004748 0.48 2125.710000 0.983855
Zr (343.823 nm)0.976701 ppm 0.004307 0.44 79625.800000 0.976701
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 145 of 287
Page 1016 of 1261
Solution Name: LCSD 280-634363/3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCSD 280-634363/3-A 11/20/2023 9:45:06 PM 4:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.941042 ppm 0.003992 0.42 2414036.240250 0.941042
Ag (328.068 nm)0.050802 ppm 0.000347 0.68 2230.080000 0.050802
Al (394.401 nm)9.775280 o ppm 0.041534 0.42 120735.000000 9.775280 o
Al H (396.152 nm)9.392390 ppm 0.038715 0.41 42261.900000 9.392390
As (188.980 nm)1.006010 ppm 0.007655 0.76 832.376000 1.006010
B (249.678 nm)1.998230 ppm 0.007711 0.39 16740.700000 1.998230
Ba (493.408 nm)0.971840 ppm 0.004755 0.49 147216.000000 0.971840
Be (234.861 nm)0.991885 ppm 0.003003 0.30 165884.000000 0.991885
Bi (223.061 nm)-0.000246 u ppm 0.001797 > 100.00 3.719290 -0.000246 u
Ca (315.887 nm)49.201493 o ppm 0.273489 0.56 33158.413331 49.201493 o
Cd (214.439 nm)0.979601 ppm 0.007178 0.73 14644.100000 0.979601
Co (228.615 nm)0.964324 ppm 0.004960 0.51 18471.000000 0.964324
Cr (205.560 nm)0.983291 ppm 0.006954 0.71 4043.040000 0.983291
Cu (324.754 nm)0.956214 ppm 0.005625 0.59 45353.300000 0.956214
Fe (238.204 nm)9.787608 o ppm 0.047488 0.49 38556.817888 9.787608 o
Fe H (259.940 nm)9.610960 ppm 0.037339 0.39 15428.700000 9.610960
K (766.491 nm)50.047300 ppm 0.241180 0.48 89470.200000 50.047300
Li (670.783 nm)0.976470 ppm 0.003892 0.40 32033.800000 0.976470
Mg (279.078 nm)50.312400 o ppm 0.310582 0.62 168282.000000 50.312400 o
Mn (257.610 nm)0.979630 ppm 0.005662 0.58 261391.000000 0.979630
Mo (202.032 nm)0.994119 ppm 0.004783 0.48 4936.380000 0.994119
Na (589.592 nm)48.171500 ppm 0.312802 0.65 597958.000000 48.171500
Na H (589.593 nm)38.418745 u ppm 0.578752 1.51 436413.907721 38.418745 u
Ni (231.604 nm)0.958991 ppm 0.006325 0.66 3255.980000 0.958991
P (213.618 nm)20.097900 o ppm 0.122028 0.61 23652.400000 20.097900 o
Pb (220.353 nm)1.039430 ppm 0.008242 0.79 2382.140000 1.039430
S (181.972 nm)18.307012 o ppm 0.096605 0.53 3756.992468 18.307012 o
Sb (206.834 nm)1.025240 ppm 0.008637 0.84 1250.700000 1.025240
Se (196.026 nm)0.984620 ppm 0.008148 0.83 608.867000 0.984620
Si (288.158 nm)9.540070 ppm 0.032396 0.34 70504.400000 9.540070
Sn (189.925 nm)0.978841 ppm 0.005665 0.58 660.049000 0.978841
Sr (421.552 nm)0.974134 ppm 0.004036 0.41 215097.873462 0.974134
Th (288.505 nm)0.067860 ppm 0.001099 1.62 364.590000 0.067860
Ti (336.122 nm)0.982892 ppm 0.005144 0.52 107242.000000 0.982892
Tl (190.794 nm)0.968826 ppm 0.008883 0.92 1047.120000 0.968826
U (409.013 nm)-0.005467 u ppm 0.002977 54.44 -21.810900 -0.005467 u
V (292.401 nm)0.981589 ppm 0.006027 0.61 40839.000000 0.981589
Zn (206.200 nm)0.978057 ppm 0.009591 0.98 2113.210000 0.978057
Zr (343.823 nm)0.980101 ppm 0.005673 0.58 79902.800000 0.980101
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 146 of 287
Page 1017 of 1261
Solution Name: 280-182949-D-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-182949-D-1-A 11/20/2023 9:49:33 PM 4:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000634 ppm 0.000012 1.94 1075.579696 0.000634
Ag (328.068 nm)0.000136 u ppm 0.000142 > 100.00 -22.494000 0.000136 u
Al (394.401 nm)0.008797 ppm 0.000953 10.83 558.627000 0.008797
Al H (396.152 nm)0.008596 u ppm 0.003405 39.60 89.198400 0.008596 u
As (188.980 nm)0.000559 u ppm 0.001264 > 100.00 -2.940180 0.000559 u
B (249.678 nm)0.012765 ppm 0.000976 7.64 123.019000 0.012765
Ba (493.408 nm)0.006626 ppm 0.000125 1.89 1003.040000 0.006626
Be (234.861 nm)0.000098 ppm 0.000027 27.55 56.327100 0.000098
Bi (223.061 nm)0.001236 u ppm 0.002539 > 100.00 5.922410 0.001236 u
Ca (315.887 nm)1.969519 ppm 0.014613 0.74 1304.268862 1.969519
Cd (214.439 nm)0.000068 ppm 0.000076 > 100.00 1.093760 0.000068
Co (228.615 nm)-0.000113 u ppm 0.000286 > 100.00 40.691500 -0.000113 u
Cr (205.560 nm)0.002113 ppm 0.000359 17.00 10.209800 0.002113
Cu (324.754 nm)0.003053 ppm 0.000225 7.36 907.237000 0.003053
Fe (238.204 nm)0.011837 ppm 0.001281 10.83 63.201656 0.011837
Fe H (259.940 nm)0.105242 u ppm 0.002069 1.97 31.642600 0.105242 u
K (766.491 nm)0.373453 ppm 0.008833 2.37 223.553000 0.373453
Li (670.783 nm)0.004266 ppm 0.001977 46.35 -4121.940000 0.004266
Mg (279.078 nm)0.760103 ppm 0.004138 0.54 2551.160000 0.760103
Mn (257.610 nm)0.001501 ppm 0.000050 3.31 405.073000 0.001501
Mo (202.032 nm)0.002056 ppm 0.000390 18.95 13.681400 0.002056
Na (589.592 nm)3.794230 ppm 0.012708 0.33 47235.700000 3.794230
Na H (589.593 nm)-6.458739 u ppm 0.061131 0.95 35193.226141 -6.458739 u
Ni (231.604 nm)0.000004 u ppm 0.000612 > 100.00 -10.195500 0.000004 u
P (213.618 nm)0.019131 ppm 0.001759 9.20 25.481800 0.019131
Pb (220.353 nm)0.001195 ppm 0.000898 75.11 1.122070 0.001195
S (181.972 nm)0.288595 ppm 0.012659 4.39 82.873669 0.288595
Sb (206.834 nm)-0.000129 u ppm 0.002714 > 100.00 1.854050 -0.000129 u
Se (196.026 nm)-0.002732 u ppm 0.000965 35.33 3.338650 -0.002732 u
Si (288.158 nm)3.652770 ppm 0.017902 0.49 27251.000000 3.652770
Sn (189.925 nm)-0.000424 u ppm 0.000735 > 100.00 1.996200 -0.000424 u
Sr (421.552 nm)0.007743 ppm 0.000088 1.13 1719.224341 0.007743
Th (288.505 nm)0.008453 ppm 0.002557 30.24 276.327000 0.008453
Ti (336.122 nm)0.000108 u ppm 0.000137 > 100.00 -102.124000 0.000108 u
Tl (190.794 nm)0.003022 ppm 0.001212 40.10 0.787933 0.003022
U (409.013 nm)-0.000877 u ppm 0.000258 29.40 19.640700 -0.000877 u
V (292.401 nm)0.001022 ppm 0.000082 8.01 3.010100 0.001022
Zn (206.200 nm)0.023337 ppm 0.001085 4.65 54.486200 0.023337
Zr (343.823 nm)0.000184 ppm 0.000114 62.09 7.337120 0.000184
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 147 of 287
Page 1018 of 1261
Solution Name: 280-182949-D-3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-182949-D-3-A 11/20/2023 9:53:37 PM 4:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000630 ppm 0.000006 0.89 1039.036543 0.000630
Ag (328.068 nm)0.000098 u ppm 0.000146 > 100.00 -24.082900 0.000098 u
Al (394.401 nm)0.121740 ppm 0.000862 0.71 1948.270000 0.121740
Al H (396.152 nm)0.128900 u ppm 0.004003 3.11 629.865000 0.128900 u
As (188.980 nm)0.003802 ppm 0.003206 84.32 -0.245333 0.003802
B (249.678 nm)0.006195 ppm 0.000375 6.05 68.033100 0.006195
Ba (493.408 nm)0.010414 ppm 0.000166 1.59 1576.600000 0.010414
Be (234.861 nm)0.000028 ppm 0.000014 51.51 44.657600 0.000028
Bi (223.061 nm)-0.000942 u ppm 0.002868 > 100.00 2.685270 -0.000942 u
Ca (315.887 nm)0.509175 ppm 0.008023 1.58 319.384649 0.509175
Cd (214.439 nm)0.000106 ppm 0.000092 87.19 1.657550 0.000106
Co (228.615 nm)0.000253 ppm 0.000174 68.82 47.683300 0.000253
Cr (205.560 nm)0.000538 u ppm 0.000647 > 100.00 3.732890 0.000538 u
Cu (324.754 nm)0.020305 ppm 0.000107 0.53 1713.060000 0.020305
Fe (238.204 nm)0.011304 ppm 0.000717 6.34 61.103263 0.011304
Fe H (259.940 nm)0.102757 u ppm 0.000756 0.74 27.617800 0.102757 u
K (766.491 nm)0.209809 ppm 0.050631 24.13 -70.458700 0.209809
Li (670.783 nm)0.005956 ppm 0.001994 33.48 -4059.100000 0.005956
Mg (279.078 nm)0.156620 ppm 0.001325 0.85 532.743000 0.156620
Mn (257.610 nm)0.004042 ppm 0.000030 0.74 1082.930000 0.004042
Mo (202.032 nm)0.000841 ppm 0.000368 43.72 7.649970 0.000841
Na (589.592 nm)0.805677 ppm 0.009307 1.16 10952.800000 0.805677
Na H (589.593 nm)-9.416041 u ppm 0.012182 0.13 9336.513980 -9.416041 u
Ni (231.604 nm)0.000737 ppm 0.000090 12.23 -7.700130 0.000737
P (213.618 nm)0.008830 ppm 0.001903 21.56 12.459800 0.008830
Pb (220.353 nm)0.000013 u ppm 0.000053 > 100.00 -1.612950 0.000013 u
S (181.972 nm)0.073726 ppm 0.005780 7.84 39.096937 0.073726
Sb (206.834 nm)0.000148 u ppm 0.001040 > 100.00 2.183830 0.000148 u
Se (196.026 nm)0.001335 u ppm 0.002839 > 100.00 5.836030 0.001335 u
Si (288.158 nm)1.678170 ppm 0.007290 0.43 12905.000000 1.678170
Sn (189.925 nm)0.001226 ppm 0.001065 86.88 3.104830 0.001226
Sr (421.552 nm)0.003639 ppm 0.000053 1.45 813.123076 0.003639
Th (288.505 nm)0.006946 ppm 0.002126 30.60 273.576000 0.006946
Ti (336.122 nm)0.000152 ppm 0.000068 45.14 -100.498000 0.000152
Tl (190.794 nm)0.000665 u ppm 0.001397 > 100.00 -1.768280 0.000665 u
U (409.013 nm)-0.000242 u ppm 0.001469 > 100.00 22.438100 -0.000242 u
V (292.401 nm)0.000070 ppm 0.000021 29.28 -36.242400 0.000070
Zn (206.200 nm)0.005794 ppm 0.001118 19.29 16.656600 0.005794
Zr (343.823 nm)-0.000062 u ppm 0.000114 > 100.00 -12.732200 -0.000062 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 148 of 287
Page 1019 of 1261
Solution Name: 280-182949-D-5-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-182949-D-5-A 11/20/2023 9:57:53 PM 4:6 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001082 ppm 0.000001 0.12 2243.186264 0.001082
Ag (328.068 nm)0.000103 u ppm 0.000105 > 100.00 -23.644100 0.000103 u
Al (394.401 nm)0.042776 ppm 0.000591 1.38 977.230000 0.042776
Al H (396.152 nm)0.043518 u ppm 0.002766 6.36 246.141000 0.043518 u
As (188.980 nm)0.002585 ppm 0.000787 30.43 -1.256790 0.002585
B (249.678 nm)0.011535 ppm 0.000138 1.20 112.728000 0.011535
Ba (493.408 nm)0.002776 ppm 0.000120 4.32 419.979000 0.002776
Be (234.861 nm)0.000035 ppm 0.000006 18.43 45.958600 0.000035
Bi (223.061 nm)-0.002143 u ppm 0.000658 30.68 0.898752 -0.002143 u
Ca (315.887 nm)1.376250 ppm 0.007282 0.53 904.156824 1.376250
Cd (214.439 nm)0.000444 ppm 0.000094 21.06 6.721390 0.000444
Co (228.615 nm)0.000364 ppm 0.000083 22.75 49.798400 0.000364
Cr (205.560 nm)0.000666 ppm 0.000322 48.33 4.256150 0.000666
Cu (324.754 nm)0.003184 ppm 0.000298 9.37 913.393000 0.003184
Fe (238.204 nm)0.024360 ppm 0.000612 2.51 112.500734 0.024360
Fe H (259.940 nm)0.114094 u ppm 0.002541 2.23 45.980100 0.114094 u
K (766.491 nm)0.754857 ppm 0.054510 7.22 908.803000 0.754857
Li (670.783 nm)0.007310 ppm 0.001431 19.58 -4008.740000 0.007310
Mg (279.078 nm)0.431496 ppm 0.000923 0.21 1452.050000 0.431496
Mn (257.610 nm)0.002681 ppm 0.000027 1.02 719.782000 0.002681
Mo (202.032 nm)0.001875 ppm 0.000523 27.89 12.779700 0.001875
Na (589.592 nm)4.159250 ppm 0.051720 1.24 51626.900000 4.159250
Na H (589.593 nm)-6.140908 u ppm 0.049462 0.81 37941.813325 -6.140908 u
Ni (231.604 nm)0.001106 ppm 0.000471 42.54 -6.443210 0.001106
P (213.618 nm)0.006152 ppm 0.001395 22.67 10.162900 0.006152
Pb (220.353 nm)0.000642 ppm 0.000165 25.72 -0.149713 0.000642
S (181.972 nm)1.672778 ppm 0.011900 0.71 364.757045 1.672778
Sb (206.834 nm)0.000669 ppm 0.000617 92.20 2.819460 0.000669
Se (196.026 nm)-0.000552 u ppm 0.002301 > 100.00 4.675970 -0.000552 u
Si (288.158 nm)3.141520 ppm 0.011040 0.35 23536.800000 3.141520
Sn (189.925 nm)0.000079 u ppm 0.001965 > 100.00 2.333940 0.000079 u
Sr (421.552 nm)0.007970 ppm 0.000112 1.41 1769.401340 0.007970
Th (288.505 nm)0.006664 ppm 0.001146 17.19 273.065000 0.006664
Ti (336.122 nm)0.000056 u ppm 0.000061 > 100.00 -109.016000 0.000056 u
Tl (190.794 nm)0.000992 u ppm 0.001067 > 100.00 -1.415240 0.000992 u
U (409.013 nm)0.002818 ppm 0.001623 57.60 35.917300 0.002818
V (292.401 nm)0.000541 ppm 0.000151 27.98 -16.939500 0.000541
Zn (206.200 nm)0.006932 ppm 0.000422 6.09 19.110500 0.006932
Zr (343.823 nm)0.000048 u ppm 0.000059 > 100.00 -3.690680 0.000048 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 149 of 287
Page 1020 of 1261
Solution Name: 280-184021-G-3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-G-3-A 11/20/2023 10:02:01 PM 4:7 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.122188 b ppm 0.000942 0.77 322981.565339 0.122188 b
Ag (328.068 nm)0.001649 ppm 0.000193 11.69 62.950000 0.001649
Al (394.401 nm)0.043324 ppm 0.001858 4.29 950.964000 0.043324
Al H (396.152 nm)-0.070600 u ppm 0.004988 7.06 -266.725000 -0.070600 u
As (188.980 nm)0.041088 ppm 0.003450 8.40 30.420500 0.041088
B (249.678 nm)0.384870 ppm 0.002092 0.54 3237.410000 0.384870
Ba (493.408 nm)0.027202 ppm 0.000424 1.56 4218.000000 0.027202
Be (234.861 nm)0.000228 ppm 0.000030 12.97 531.085000 0.000228
Bi (223.061 nm)0.003315 ppm 0.001377 41.53 9.013950 0.003315
Ca (315.887 nm)645.261486 o ppm 2.500029 0.39 435152.652110 645.261486 o
Cd (214.439 nm)0.000765 ppm 0.000120 15.64 18.694400 0.000765
Co (228.615 nm)0.000677 ppm 0.000265 39.17 55.734500 0.000677
Cr (205.560 nm)0.000253 u ppm 0.000473 > 100.00 2.537150 0.000253 u
Cu (324.754 nm)0.000754 ppm 0.000356 47.20 476.703000 0.000754
Fe (238.204 nm)35.199902 o ppm 0.126856 0.36 138577.851794 35.199902 o
Fe H (259.940 nm)34.277400 ppm 0.139151 0.41 55382.600000 34.277400
K (766.491 nm)11.496400 ppm 0.031722 0.28 20207.700000 11.496400
Li (670.783 nm)0.113158 ppm 0.000862 0.76 -72.328600 0.113158
Mg (279.078 nm)186.853000 o ppm 1.111900 0.60 624949.000000 186.853000 o
Mn (257.610 nm)4.488790 o ppm 0.020448 0.46 1197710.000000 4.488790 o
Mo (202.032 nm)0.008749 ppm 0.000363 4.15 46.893100 0.008749
Na (589.592 nm)77.045600 o ppm 0.288152 0.37 937867.000000 77.045600 o
Na H (589.593 nm)66.489589 ppm 1.224803 1.84 673979.181600 66.489589
Ni (231.604 nm)-0.005662 u ppm 0.000751 13.26 -29.486800 -0.005662 u
P (213.618 nm)0.410028 ppm 0.002314 0.56 486.928000 0.410028
Pb (220.353 nm)0.003448 ppm 0.001370 39.74 6.335570 0.003448
S (181.972 nm)424.325601 bo ppm 3.129044 0.74 86456.080674 424.325601 bo
Sb (206.834 nm)-0.003719 u ppm 0.003235 86.98 -0.132179 -0.003719 u
Se (196.026 nm)-0.001559 u ppm 0.004183 > 100.00 3.345790 -0.001559 u
Si (288.158 nm)28.436400 o ppm 0.269808 0.95 207319.000000 28.436400 o
Sn (189.925 nm)-0.001539 u ppm 0.001149 74.64 1.246570 -0.001539 u
Sr (421.552 nm)1.620810 o ppm 0.020915 1.29 357883.564359 1.620810 o
Th (288.505 nm)0.155363 ppm 0.005339 3.44 643.850000 0.155363
Ti (336.122 nm)-0.002399 u ppm 0.000090 3.75 1034.030000 -0.002399 u
Tl (190.794 nm)0.002028 u ppm 0.003978 > 100.00 -0.936663 0.002028 u
U (409.013 nm)0.006866 ppm 0.001092 15.90 90.078600 0.006866
V (292.401 nm)0.002392 ppm 0.000234 9.78 70.183500 0.002392
Zn (206.200 nm)0.001100 ppm 0.000870 79.06 6.535370 0.001100
Zr (343.823 nm)0.000091 u ppm 0.000189 > 100.00 47.317400 0.000091 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 150 of 287
Page 1021 of 1261
Solution Name: 280-184021-G-3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-G-3-A 11/20/2023 10:06:28 PM 4:8 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.019210 ppm 0.000105 0.55 50664.266582 0.019210
Ag (328.068 nm)0.001082 ppm 0.000418 38.68 30.328500 0.001082
Al (394.401 nm)0.025523 ppm 0.000339 1.33 751.009000 0.025523
Al H (396.152 nm)-0.022050 u ppm 0.005228 23.71 -48.533600 -0.022050 u
As (188.980 nm)0.009570 ppm 0.001140 11.91 4.484000 0.009570
B (249.678 nm)0.072232 ppm 0.001275 1.77 620.741000 0.072232
Ba (493.408 nm)0.005161 ppm 0.000170 3.28 800.894000 0.005161
Be (234.861 nm)0.000129 ppm 0.000021 16.64 152.080000 0.000129
Bi (223.061 nm)0.001915 ppm 0.001514 79.08 6.932430 0.001915
Ca (315.887 nm)128.113993 o ppm 0.774863 0.60 86378.510026 128.113993 o
Cd (214.439 nm)0.000628 ppm 0.000060 9.51 10.899100 0.000628
Co (228.615 nm)0.000109 u ppm 0.000214 > 100.00 44.911300 0.000109 u
Cr (205.560 nm)0.000764 ppm 0.000530 69.42 4.657570 0.000764
Cu (324.754 nm)-0.000209 u ppm 0.000230 > 100.00 697.594000 -0.000209 u
Fe (238.204 nm)7.047804 o ppm 0.044372 0.63 27759.661480 7.047804 o
Fe H (259.940 nm)6.902350 ppm 0.037766 0.55 11041.400000 6.902350
K (766.491 nm)2.128100 ppm 0.039627 1.86 3376.050000 2.128100
Li (670.783 nm)0.023839 ppm 0.001199 5.03 -3394.050000 0.023839
Mg (279.078 nm)35.878500 ppm 0.252003 0.70 120006.000000 35.878500
Mn (257.610 nm)0.898451 ppm 0.005496 0.61 239730.000000 0.898451
Mo (202.032 nm)0.002185 ppm 0.000307 14.03 14.321500 0.002185
Na (589.592 nm)14.618800 ppm 0.094022 0.64 178793.000000 14.618800
Na H (589.593 nm)4.991475 u ppm 0.524436 10.51 135418.033104 4.991475 u
Ni (231.604 nm)-0.003218 u ppm 0.000423 13.13 -21.166300 -0.003218 u
P (213.618 nm)0.075133 ppm 0.002987 3.98 91.787000 0.075133
Pb (220.353 nm)-0.001115 u ppm 0.001888 > 100.00 -4.154340 -0.001115 u
S (181.972 nm)81.502601 o ppm 0.671010 0.82 16625.686779 81.502601 o
Sb (206.834 nm)-0.002741 u ppm 0.003749 > 100.00 -0.850682 -0.002741 u
Se (196.026 nm)0.006000 ppm 0.003062 51.03 8.554430 0.006000
Si (288.158 nm)5.317510 ppm 0.038892 0.73 39346.800000 5.317510
Sn (189.925 nm)0.001026 u ppm 0.001236 > 100.00 2.970180 0.001026 u
Sr (421.552 nm)0.314823 ppm 0.002204 0.70 69522.525953 0.314823
Th (288.505 nm)0.056238 ppm 0.003397 6.04 384.193000 0.056238
Ti (336.122 nm)-0.000830 u ppm 0.000061 7.36 72.008400 -0.000830 u
Tl (190.794 nm)0.002521 ppm 0.002176 86.29 0.119894 0.002521
U (409.013 nm)0.018750 ppm 0.001563 8.34 113.846000 0.018750
V (292.401 nm)0.000951 ppm 0.000056 5.86 4.162390 0.000951
Zn (206.200 nm)0.000352 ppm 0.000075 21.40 4.922470 0.000352
Zr (343.823 nm)0.000096 u ppm 0.000154 > 100.00 9.700100 0.000096 u
Test Report
52A112023.esws
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Page 1022 of 1261
Solution Name: 280-184021-G-3-B MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-G-3-B MS 11/20/2023 10:10:54 PM 4:9 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.291271 bo ppm 0.007237 0.56 3322227.847324 1.291271 bo
Ag (328.068 nm)0.055466 ppm 0.000095 0.17 2476.070000 0.055466
Al (394.401 nm)10.664300 o ppm 0.055923 0.52 131649.000000 10.664300 o
Al H (396.152 nm)9.796870 ppm 0.001915 0.02 44079.700000 9.796870
As (188.980 nm)1.107290 o ppm 0.009152 0.83 916.210000 1.107290 o
B (249.678 nm)2.555830 ppm 0.009952 0.39 21407.600000 2.555830
Ba (493.408 nm)1.025940 ppm 0.000749 0.07 155511.000000 1.025940
Be (234.861 nm)1.034060 ppm 0.005030 0.49 173392.000000 1.034060
Bi (223.061 nm)0.001069 u ppm 0.002834 > 100.00 5.675190 0.001069 u
Ca (315.887 nm)710.144121 o ppm 1.270319 0.18 478910.739789 710.144121 o
Cd (214.439 nm)0.934526 ppm 0.004803 0.51 13977.600000 0.934526
Co (228.615 nm)0.941453 ppm 0.004357 0.46 18035.100000 0.941453
Cr (205.560 nm)0.986028 ppm 0.006040 0.61 4054.300000 0.986028
Cu (324.754 nm)1.010970 ppm 0.003417 0.34 47568.800000 1.010970
Fe (238.204 nm)45.716987 o ppm 0.100852 0.22 179989.022083 45.716987 o
Fe H (259.940 nm)44.547800 ppm 0.083023 0.19 72018.400000 44.547800
K (766.491 nm)65.434500 ppm 0.406812 0.62 117116.000000 65.434500
Li (670.783 nm)1.153990 o ppm 0.004131 0.36 38635.700000 1.153990 o
Mg (279.078 nm)243.084000 o ppm 1.166980 0.48 813020.000000 243.084000 o
Mn (257.610 nm)5.512510 o ppm 0.024459 0.44 1470860.000000 5.512510 o
Mo (202.032 nm)1.008940 ppm 0.005644 0.56 5009.910000 1.008940
Na (589.592 nm)130.305000 o ppm 0.857664 0.66 1596950.000000 130.305000 o
Na H (589.593 nm)121.327283 ppm 1.119438 0.92 1162681.287468 121.327283
Ni (231.604 nm)0.914419 ppm 0.005875 0.64 3104.160000 0.914419
P (213.618 nm)21.775700 o ppm 0.094860 0.44 25630.000000 21.775700 o
Pb (220.353 nm)1.022900 ppm 0.002367 0.23 2344.080000 1.022900
S (181.972 nm)455.567780 bo ppm 3.016044 0.66 92823.751430 455.567780 bo
Sb (206.834 nm)1.066090 ppm 0.003114 0.29 1302.890000 1.066090
Se (196.026 nm)1.036020 ppm 0.005067 0.49 639.650000 1.036020
Si (288.158 nm)38.731900 o ppm 0.173512 0.45 282598.000000 38.731900 o
Sn (189.925 nm)0.964505 ppm 0.008677 0.90 650.415000 0.964505
Sr (421.552 nm)2.664707 o ppm 0.003853 0.14 588375.504018 2.664707 o
Th (288.505 nm)0.189237 ppm 0.002854 1.51 684.804000 0.189237
Ti (336.122 nm)1.000380 ppm 0.004983 0.50 110598.000000 1.000380
Tl (190.794 nm)0.911257 ppm 0.006234 0.68 983.871000 0.911257
U (409.013 nm)-0.014110 u ppm 0.003572 25.31 -23.944500 -0.014110 u
V (292.401 nm)1.000740 ppm 0.004477 0.45 41649.500000 1.000740
Zn (206.200 nm)0.924516 ppm 0.006598 0.71 1997.760000 0.924516
Zr (343.823 nm)0.997475 ppm 0.005485 0.55 81367.700000 0.997475
Test Report
52A112023.esws
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Page 1023 of 1261
Solution Name: 280-184021-G-3-C MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-G-3-C MSD 11/20/2023 10:15:24 PM 4:10 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.272667 bo ppm 0.006553 0.51 3274518.466957 1.272667 bo
Ag (328.068 nm)0.054505 ppm 0.000253 0.46 2428.370000 0.054505
Al (394.401 nm)10.486800 o ppm 0.069927 0.67 129465.000000 10.486800 o
Al H (396.152 nm)9.666610 ppm 0.054099 0.56 43494.300000 9.666610
As (188.980 nm)1.096780 o ppm 0.004462 0.41 907.476000 1.096780 o
B (249.678 nm)2.520170 ppm 0.013340 0.53 21109.100000 2.520170
Ba (493.408 nm)1.010110 ppm 0.006562 0.65 153112.000000 1.010110
Be (234.861 nm)1.016870 ppm 0.008409 0.83 170518.000000 1.016870
Bi (223.061 nm)0.001194 u ppm 0.003337 > 100.00 5.860970 0.001194 u
Ca (315.887 nm)708.787917 o ppm 4.488169 0.63 477996.090052 708.787917 o
Cd (214.439 nm)0.926187 ppm 0.006942 0.75 13853.000000 0.926187
Co (228.615 nm)0.927986 ppm 0.004891 0.53 17777.700000 0.927986
Cr (205.560 nm)0.975447 ppm 0.008568 0.88 4010.810000 0.975447
Cu (324.754 nm)0.997977 ppm 0.005900 0.59 46963.600000 0.997977
Fe (238.204 nm)45.500277 o ppm 0.293096 0.64 179135.861443 45.500277 o
Fe H (259.940 nm)44.334500 ppm 0.274085 0.62 71672.900000 44.334500
K (766.491 nm)64.792300 ppm 0.620369 0.96 115962.000000 64.792300
Li (670.783 nm)1.134790 o ppm 0.010468 0.92 37921.600000 1.134790 o
Mg (279.078 nm)242.910000 o ppm 1.917230 0.79 812440.000000 242.910000 o
Mn (257.610 nm)5.507840 o ppm 0.040594 0.74 1469610.000000 5.507840 o
Mo (202.032 nm)0.996793 ppm 0.008065 0.81 4949.640000 0.996793
Na (589.592 nm)128.873000 o ppm 0.940539 0.73 1579350.000000 128.873000 o
Na H (589.593 nm)120.150590 ppm 0.631371 0.53 1152243.591000 120.150590
Ni (231.604 nm)0.905067 ppm 0.006901 0.76 3072.320000 0.905067
P (213.618 nm)21.455600 o ppm 0.114434 0.53 25253.000000 21.455600 o
Pb (220.353 nm)1.010300 ppm 0.005223 0.52 2315.210000 1.010300
S (181.972 nm)455.211789 bo ppm 3.734606 0.82 92751.191472 455.211789 bo
Sb (206.834 nm)1.048810 ppm 0.010893 1.04 1281.860000 1.048810
Se (196.026 nm)1.032270 ppm 0.011181 1.08 637.370000 1.032270
Si (288.158 nm)38.569300 o ppm 0.266426 0.69 281409.000000 38.569300 o
Sn (189.925 nm)0.949910 ppm 0.003793 0.40 640.607000 0.949910
Sr (421.552 nm)2.643515 o ppm 0.019784 0.75 583696.413117 2.643515 o
Th (288.505 nm)0.194399 ppm 0.000295 0.15 694.869000 0.194399
Ti (336.122 nm)0.983906 ppm 0.006493 0.66 108798.000000 0.983906
Tl (190.794 nm)0.906501 ppm 0.012513 1.38 978.742000 0.906501
U (409.013 nm)-0.008533 u ppm 0.005014 58.76 0.960669 -0.008533 u
V (292.401 nm)0.989397 ppm 0.007036 0.71 41177.000000 0.989397
Zn (206.200 nm)0.915418 ppm 0.006397 0.70 1978.140000 0.915418
Zr (343.823 nm)0.981027 ppm 0.005939 0.61 80026.600000 0.981027
Test Report
52A112023.esws
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Page 1024 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 10:19:55 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000004 u ppm 0.000016 > 100.00 932.119795 0.000004 u
Ag (328.068 nm)0.000116 u ppm 0.000177 > 100.00 118.276000 0.000116 u
Al (394.401 nm)51.529100 o ppm 0.109922 0.21 633485.000000 51.529100 o
Al H (396.152 nm)48.361100 ppm 0.220925 0.46 217395.000000 48.361100
As (188.980 nm)0.003048 ppm 0.003191 > 100.00 -1.314870 0.003048
B (249.678 nm)0.001936 ppm 0.000804 41.55 32.384900 0.001936
Ba (493.408 nm)0.000191 ppm 0.000022 11.46 167.868000 0.000191
Be (234.861 nm)0.000260 ppm 0.000065 24.89 723.428000 0.000260
Bi (223.061 nm)-0.000901 u ppm 0.001043 > 100.00 2.745180 -0.000901 u
Ca (315.887 nm)0.005937 ppm 0.006802 > 100.00 -20.008612 0.005937
Cd (214.439 nm)-0.000110 u ppm 0.000174 > 100.00 8.583850 -0.000110 u
Co (228.615 nm)0.000524 ppm 0.000066 12.62 52.873000 0.000524
Cr (205.560 nm)0.001108 ppm 0.000243 21.93 6.077200 0.001108
Cu (324.754 nm)-0.000227 u ppm 0.000154 67.59 1689.510000 -0.000227 u
Fe (238.204 nm)49.716482 o ppm 0.158500 0.32 195721.010632 49.716482 o
Fe H (259.940 nm)47.984900 ppm 0.201292 0.42 77585.700000 47.984900
K (766.491 nm)0.057957 ppm 0.023453 40.47 -343.285000 0.057957
Li (670.783 nm)0.000760 u ppm 0.001229 > 100.00 -4252.320000 0.000760 u
Mg (279.078 nm)0.008602 ppm 0.001633 18.99 -149.774000 0.008602
Mn (257.610 nm)-0.000802 u ppm 0.000036 4.54 -209.402000 -0.000802 u
Mo (202.032 nm)0.000506 u ppm 0.000560 > 100.00 5.987590 0.000506 u
Na (589.592 nm)245.031000 o ppm 0.436702 0.18 2979440.000000 245.031000 o
Na H (589.593 nm)233.968343 ppm 1.908755 0.82 2139880.477089 233.968343
Ni (231.604 nm)-0.000055 u ppm 0.001799 > 100.00 -10.397800 -0.000055 u
P (213.618 nm)4.965150 ppm 0.018377 0.37 5863.900000 4.965150
Pb (220.353 nm)0.001719 ppm 0.001526 88.74 0.782823 0.001719
S (181.972 nm)4.664601 ppm 0.020115 0.43 975.885081 4.664601
Sb (206.834 nm)-0.002304 u ppm 0.002991 > 100.00 2.625550 -0.002304 u
Se (196.026 nm)0.003777 ppm 0.002070 54.81 2.125770 0.003777
Si (288.158 nm)0.048878 ppm 0.001909 3.91 1066.850000 0.048878
Sn (189.925 nm)-0.000539 u ppm 0.002108 > 100.00 1.918640 -0.000539 u
Sr (421.552 nm)0.000650 ppm 0.000053 8.15 153.232570 0.000650
Th (288.505 nm)4.530600 ppm 0.012704 0.28 8727.430000 4.530600
Ti (336.122 nm)0.000814 ppm 0.000064 7.86 -29.225500 0.000814
Tl (190.794 nm)-0.003038 u ppm 0.001424 46.88 -6.680310 -0.003038 u
U (409.013 nm)2.358200 Q ppm 0.007670 0.33 10535.500000 Q 2.358200 Q
V (292.401 nm)0.000587 ppm 0.000191 32.57 264.660000 0.000587
Zn (206.200 nm)0.000877 ppm 0.000598 68.23 6.053800 0.000877
Zr (343.823 nm)-0.000717 u ppm 0.000063 8.81 1.070620 -0.000717 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 154 of 287
Page 1025 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 10:24:20 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.446880 Q ppm 0.000855 0.19 1145909.795349
Q 0.446880 Q
Ag (328.068 nm)0.504439 ppm 0.002534 0.50 26944.900000 0.504439
Al (394.401 nm)0.490747 ppm 0.001290 0.26 6493.870000 0.490747
Al H (396.152 nm)0.500246 u ppm 0.001584 0.32 2298.770000 0.500246 u
As (188.980 nm)0.499697 ppm 0.006421 1.28 411.760000 0.499697
B (249.678 nm)0.494026 ppm 0.000894 0.18 4151.010000 0.494026
Ba (493.408 nm)0.496061 ppm 0.000876 0.18 75136.900000 0.496061
Be (234.861 nm)0.514850 ppm 0.002662 0.52 86090.000000 0.514850
Bi (223.061 nm)0.987433 ppm 0.005613 0.57 1472.190000 0.987433
Ca (315.887 nm)4.984074 ppm 0.011992 0.24 3337.341938 4.984074
Cd (214.439 nm)0.506588 ppm 0.001308 0.26 7572.490000 0.506588
Co (228.615 nm)0.503525 ppm 0.001346 0.27 9664.470000 0.503525
Cr (205.560 nm)0.509466 ppm 0.001196 0.23 2095.570000 0.509466
Cu (324.754 nm)0.496829 ppm 0.001505 0.30 23936.600000 0.496829
Fe (238.204 nm)2.498263 ppm 0.004956 0.20 9857.097212 2.498263
Fe H (259.940 nm)2.503230 u ppm 0.005068 0.20 3915.840000 2.503230 u
K (766.491 nm)50.440100 ppm 0.434010 0.86 90175.900000 50.440100
Li (670.783 nm)0.492355 ppm 0.001795 0.36 14029.800000 0.492355
Mg (279.078 nm)20.176400 ppm 0.052632 0.26 67492.000000 20.176400
Mn (257.610 nm)0.494700 ppm 0.001128 0.23 132001.000000 0.494700
Mo (202.032 nm)0.499058 ppm 0.000440 0.09 2479.850000 0.499058
Na (589.592 nm)24.671800 ppm 0.204653 0.83 306740.000000 24.671800
Na H (589.593 nm)14.566858 u ppm 0.136094 0.93 223491.257977 14.566858 u
Ni (231.604 nm)0.510140 ppm 0.001844 0.36 1727.240000 0.510140
P (213.618 nm)0.010267 ppm 0.003188 31.05 -24.910600 0.010267
Pb (220.353 nm)0.530509 ppm 0.001502 0.28 1215.530000 0.530509
S (181.972 nm)-0.016742 u ppm 0.015587 93.10 23.142277 -0.016742 u
Sb (206.834 nm)0.490696 ppm 0.002522 0.51 599.552000 0.490696
Se (196.026 nm)0.501345 ppm 0.001389 0.28 312.740000 0.501345
Si (288.158 nm)4.994630 ppm 0.038198 0.76 37243.200000 4.994630
Sn (189.925 nm)0.497293 ppm 0.004618 0.93 336.455000 0.497293
Sr (421.552 nm)0.497003 ppm 0.000732 0.15 109747.682918 0.497003
Th (288.505 nm)0.040434 ppm 0.001167 2.89 324.275000 0.040434
Ti (336.122 nm)0.496104 ppm 0.001142 0.23 54027.200000 0.496104
Tl (190.794 nm)0.498859 ppm 0.000793 0.16 538.077000 0.498859
U (409.013 nm)-0.011315 u ppm 0.001802 15.93 -39.781200 -0.011315 u
V (292.401 nm)0.497126 ppm 0.000920 0.19 20658.600000 0.497126
Zn (206.200 nm)0.507336 ppm 0.002485 0.49 1098.160000 0.507336
Zr (343.823 nm)0.491650 ppm 0.001414 0.29 40074.700000 0.491650
Test Report
52A112023.esws
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Page 1026 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 10:28:43 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000447 ppm 0.000006 1.44 555.203559 0.000447
Ag (328.068 nm)0.000043 u ppm 0.000153 > 100.00 -26.624800 0.000043 u
Al (394.401 nm)0.000347 ppm 0.000103 29.72 453.606000 0.000347
Al H (396.152 nm)-0.000181 u ppm 0.004714 > 100.00 49.749200 -0.000181 u
As (188.980 nm)0.000089 u ppm 0.001043 > 100.00 -3.330460 0.000089 u
B (249.678 nm)0.001193 ppm 0.000355 29.76 26.166000 0.001193
Ba (493.408 nm)0.000170 ppm 0.000133 78.30 25.180500 0.000170
Be (234.861 nm)0.000028 u ppm 0.000032 > 100.00 44.525500 0.000028 u
Bi (223.061 nm)0.000832 ppm 0.000415 49.88 5.321810 0.000832
Ca (315.887 nm)0.010230 ppm 0.008393 82.04 -17.113396 0.010230
Cd (214.439 nm)0.000199 ppm 0.000110 55.21 3.056890 0.000199
Co (228.615 nm)-0.000083 u ppm 0.000188 > 100.00 41.255100 -0.000083 u
Cr (205.560 nm)0.000132 u ppm 0.000568 > 100.00 2.066690 0.000132 u
Cu (324.754 nm)0.000477 ppm 0.000452 94.81 788.952000 0.000477
Fe (238.204 nm)0.001129 u ppm 0.001066 94.43 21.048509 0.001129 u
Fe H (259.940 nm)0.094615 u ppm 0.002560 2.71 14.428600 0.094615 u
K (766.491 nm)0.005043 u ppm 0.024206 > 100.00 -438.353000 0.005043 u
Li (670.783 nm)0.004189 S ppm 0.001447 34.53 -4124.830000 S 0.004189 S
Mg (279.078 nm)0.001276 ppm 0.000669 52.40 13.081200 0.001276
Mn (257.610 nm)0.000004 u ppm 0.000032 > 100.00 5.474880 0.000004 u
Mo (202.032 nm)0.000438 u ppm 0.000781 > 100.00 5.653830 0.000438 u
Na (589.592 nm)0.046827 ppm 0.008273 17.67 1607.610000 0.046827
Na H (589.593 nm)-10.016705 u ppm 0.015000 0.15 3988.638261 -10.016705 u
Ni (231.604 nm)0.000295 ppm 0.000285 96.70 -9.206080 0.000295
P (213.618 nm)-0.002612 u ppm 0.003037 > 100.00 -0.000300 -0.002612 u
Pb (220.353 nm)0.001714 ppm 0.001752 > 100.00 2.313670 0.001714
S (181.972 nm)-0.030963 u ppm 0.007921 25.58 17.763303 -0.030963 u
Sb (206.834 nm)0.000760 u ppm 0.003619 > 100.00 2.931260 0.000760 u
Se (196.026 nm)-0.001349 u ppm 0.001571 > 100.00 4.187480 -0.001349 u
Si (288.158 nm)0.002981 ppm 0.001687 56.58 733.118000 0.002981
Sn (189.925 nm)-0.000997 u ppm 0.001145 > 100.00 1.610840 -0.000997 u
Sr (421.552 nm)0.000056 u ppm 0.000056 99.80 21.987916 0.000056 u
Th (288.505 nm)0.011232 Z ppm 0.000322 2.87 281.511000 Z 0.011232 Z
Ti (336.122 nm)-0.000040 u ppm 0.000056 > 100.00 -122.489000 -0.000040 u
Tl (190.794 nm)0.003030 ppm 0.001546 51.03 0.801364 0.003030
U (409.013 nm)0.002973 u ppm 0.003167 > 100.00 36.638200 0.002973 u
V (292.401 nm)-0.000057 u ppm 0.000124 > 100.00 -41.227200 -0.000057 u
Zn (206.200 nm)-0.001394 u ppm 0.000541 38.83 1.157770 -0.001394 u
Zr (343.823 nm)0.000129 ppm 0.000039 29.93 2.899450 0.000129
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 156 of 287
Page 1027 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 10:32:45 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014114 ppm 0.000052 0.37 35688.988862 0.014114
Ag (328.068 nm)0.009884 ppm 0.000278 2.82 497.089000 0.009884
Al (394.401 nm)0.087356 ppm 0.000861 0.99 1535.420000 0.087356
Al H (396.152 nm)0.090014 u ppm 0.002427 2.70 455.107000 0.090014 u
As (188.980 nm)0.017467 ppm 0.001454 8.33 11.107200 0.017467
B (249.678 nm)0.095796 ppm 0.000537 0.56 817.959000 0.095796
Ba (493.408 nm)0.009731 ppm 0.000215 2.21 1473.410000 0.009731
Be (234.861 nm)0.001025 ppm 0.000009 0.91 212.399000 0.001025
Bi (223.061 nm)-0.000083 Qu ppm 0.002861 > 100.00 3.960970 Q -0.000083 Qu
Ca (315.887 nm)0.197589 ppm 0.005799 2.93 109.245503 0.197589
Cd (214.439 nm)0.005163 ppm 0.000113 2.18 77.264500 0.005163
Co (228.615 nm)0.010259 ppm 0.000062 0.60 238.836000 0.010259
Cr (205.560 nm)0.009793 ppm 0.000242 2.48 41.712900 0.009793
Cu (324.754 nm)0.014761 ppm 0.000081 0.55 1447.940000 0.014761
Fe (238.204 nm)0.099180 ppm 0.000564 0.57 407.080617 0.099180
Fe H (259.940 nm)0.188533 u ppm 0.002988 1.58 166.555000 0.188533 u
K (766.491 nm)2.975280 ppm 0.032667 1.10 4898.130000 2.975280
Li (670.783 nm)0.023446 ppm 0.000781 3.33 -3408.670000 0.023446
Mg (279.078 nm)0.199512 ppm 0.001899 0.95 675.683000 0.199512
Mn (257.610 nm)0.010048 ppm 0.000040 0.40 2685.560000 0.010048
Mo (202.032 nm)0.019421 ppm 0.000079 0.40 99.847700 0.019421
Na (589.592 nm)1.012310 ppm 0.018203 1.80 13459.100000 1.012310
Na H (589.593 nm)-9.111160 u ppm 0.005219 0.06 12001.496059 -9.111160 u
Ni (231.604 nm)0.041162 ppm 0.000600 1.46 129.959000 0.041162
P (213.618 nm)2.796590 ppm 0.006161 0.22 3303.460000 2.796590
Pb (220.353 nm)0.009779 ppm 0.002158 22.07 20.872900 0.009779
S (181.972 nm)0.048502 Q ppm 0.003685 7.60 34.011220 Q 0.048502 Q
Sb (206.834 nm)0.019305 ppm 0.002264 11.73 25.452300 0.019305
Se (196.026 nm)0.017396 ppm 0.001970 11.33 15.686900 0.017396
Si (288.158 nm)0.461251 ppm 0.005972 1.29 4093.240000 0.461251
Sn (189.925 nm)0.098584 ppm 0.001733 1.76 68.527900 0.098584
Sr (421.552 nm)0.009630 ppm 0.000222 2.31 2135.967385 0.009630
Th (288.505 nm)0.006420 Q ppm 0.001156 18.01 272.626000 Q 0.006420 Q
Ti (336.122 nm)0.009413 ppm 0.000072 0.76 909.375000 0.009413
Tl (190.794 nm)0.016279 ppm 0.001294 7.95 15.145300 0.016279
U (409.013 nm)0.048936 ppm 0.004438 9.07 238.610000 0.048936
V (292.401 nm)0.009529 ppm 0.000139 1.45 352.840000 0.009529
Zn (206.200 nm)0.019863 ppm 0.000262 1.32 46.994100 0.019863
Zr (343.823 nm)0.009615 ppm 0.000155 1.61 776.285000 0.009615
Test Report
52A112023.esws
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Page 1028 of 1261
Solution Name: 280-184021-G-3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-G-3-A 11/20/2023 10:37:05 PM 4:11 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.229239 b ppm 0.000741 0.32 597549.750102 0.229239 b
Ag (328.068 nm)0.053293 ppm 0.000301 0.57 2819.030000 0.053293
Al (394.401 nm)1.072670 ppm 0.000577 0.05 13623.300000 1.072670
Al H (396.152 nm)0.909414 ppm 0.004994 0.55 4137.660000 0.909414
As (188.980 nm)0.242977 ppm 0.000365 0.15 198.164000 0.242977
B (249.678 nm)0.474427 ppm 0.000836 0.18 3986.970000 0.474427
Ba (493.408 nm)0.123047 ppm 0.000136 0.11 18734.600000 0.123047
Be (234.861 nm)0.051205 ppm 0.000320 0.62 9050.090000 0.051205
Bi (223.061 nm)0.006093 ppm 0.000873 14.33 13.144700 0.006093
Ca (315.887 nm)648.617709 o ppm 1.383111 0.21 437416.152552 648.617709 o
Cd (214.439 nm)0.046886 ppm 0.000291 0.62 708.093000 0.046886
Co (228.615 nm)0.046999 ppm 0.000204 0.43 940.844000 0.046999
Cr (205.560 nm)0.048998 ppm 0.000941 1.92 202.890000 0.048998
Cu (324.754 nm)0.050354 ppm 0.000127 0.25 2795.170000 0.050354
Fe (238.204 nm)35.355597 o ppm 0.082409 0.23 139191.305460 35.355597 o
Fe H (259.940 nm)34.453000 ppm 0.075294 0.22 55667.200000 34.453000
K (766.491 nm)32.179500 ppm 0.230043 0.71 57367.900000 32.179500
Li (670.783 nm)0.210780 ppm 0.001681 0.80 3558.190000 0.210780
Mg (279.078 nm)200.149000 o ppm 0.446400 0.22 669409.000000 200.149000 o
Mn (257.610 nm)4.368310 o ppm 0.010265 0.23 1165560.000000 4.368310 o
Mo (202.032 nm)0.055956 ppm 0.000809 1.45 281.136000 0.055956
Na (589.592 nm)94.663200 o ppm 0.581286 0.61 1153130.000000 94.663200 o
Na H (589.593 nm)85.163819 ppm 5.701458 6.69 838286.055295 85.163819
Ni (231.604 nm)0.039598 ppm 0.000615 1.55 124.760000 0.039598
P (213.618 nm)2.433970 ppm 0.002955 0.12 2872.390000 2.433970
Pb (220.353 nm)0.099613 ppm 0.002676 2.69 227.867000 0.099613
S (181.972 nm)408.548836 bo ppm 1.886961 0.46 83243.645500 408.548836 bo
Sb (206.834 nm)0.097788 ppm 0.001099 1.12 123.530000 0.097788
Se (196.026 nm)0.204606 ppm 0.004823 2.36 129.767000 0.204606
Si (288.158 nm)31.730500 o ppm 0.357997 1.13 231277.000000 31.730500 o
Sn (189.925 nm)0.052640 ppm 0.002649 5.03 37.654100 0.052640
Sr (421.552 nm)1.636135 o ppm 0.002602 0.16 361267.320194 1.636135 o
Th (288.505 nm)0.330308 ppm 0.003305 1.00 969.102000 0.330308
Ti (336.122 nm)0.046597 ppm 0.000104 0.22 6387.900000 0.046597
Tl (190.794 nm)0.177525 ppm 0.001762 0.99 189.537000 0.177525
U (409.013 nm)0.479875 ppm 0.000316 0.07 2175.020000 0.479875
V (292.401 nm)0.051057 ppm 0.000144 0.28 2085.090000 0.051057
Zn (206.200 nm)0.183604 ppm 0.000734 0.40 400.079000 0.183604
Zr (343.823 nm)0.049352 ppm 0.000181 0.37 4063.280000 0.049352
Test Report
52A112023.esws
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Page 1029 of 1261
Solution Name: 280-184021-F-4-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-F-4-A 11/20/2023 10:41:34 PM 4:12 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.137417 b ppm 0.000822 0.60 362661.607907 0.137417 b
Ag (328.068 nm)0.001501 ppm 0.000267 17.79 46.962000 0.001501
Al (394.401 nm)0.052577 ppm 0.001759 3.35 1097.910000 0.052577
Al H (396.152 nm)-0.071040 u ppm 0.001623 2.28 -268.703000 -0.071040 u
As (188.980 nm)0.010059 ppm 0.000689 6.85 4.927990 0.010059
B (249.678 nm)0.423887 ppm 0.003796 0.90 3563.970000 0.423887
Ba (493.408 nm)0.034362 ppm 0.000199 0.58 5211.670000 0.034362
Be (234.861 nm)0.000266 ppm 0.000054 20.26 120.740000 0.000266
Bi (223.061 nm)0.005256 ppm 0.002656 50.53 11.899900 0.005256
Ca (315.887 nm)852.133929 o ppm 2.449439 0.29 574671.376788 852.133929 o
Cd (214.439 nm)0.000812 ppm 0.000323 39.77 12.790100 0.000812
Co (228.615 nm)0.000954 ppm 0.000207 21.73 61.016500 0.000954
Cr (205.560 nm)0.000843 ppm 0.000381 45.25 3.891950 0.000843
Cu (324.754 nm)0.003482 ppm 0.000363 10.43 418.310000 0.003482
Fe (238.204 nm)2.828324 ppm 0.006440 0.23 11150.094111 2.828324
Fe H (259.940 nm)2.836150 u ppm 0.008140 0.29 4455.090000 2.836150 u
K (766.491 nm)9.332750 ppm 0.059065 0.63 16320.300000 9.332750
Li (670.783 nm)0.121469 ppm 0.001012 0.83 236.776000 0.121469
Mg (279.078 nm)187.763000 o ppm 1.043720 0.56 628012.000000 187.763000 o
Mn (257.610 nm)0.404967 ppm 0.002032 0.50 108058.000000 0.404967
Mo (202.032 nm)0.350713 ppm 0.001584 0.45 1743.750000 0.350713
Na (589.592 nm)191.862000 o ppm 0.969057 0.51 2333550.000000 191.862000 o
Na H (589.593 nm)183.368842 ppm 0.174416 0.10 1697216.586881 183.368842
Ni (231.604 nm)0.008143 ppm 0.001102 13.53 17.519200 0.008143
P (213.618 nm)0.051406 ppm 0.004148 8.07 53.678400 0.051406
Pb (220.353 nm)0.001704 u ppm 0.002169 > 100.00 2.042160 0.001704 u
S (181.972 nm)438.538645 bo ppm 2.831947 0.65 89349.114441 438.538645 bo
Sb (206.834 nm)-0.001901 u ppm 0.001944 > 100.00 -1.761640 -0.001901 u
Se (196.026 nm)0.002590 u ppm 0.009650 > 100.00 6.577010 0.002590 u
Si (288.158 nm)21.633700 o ppm 0.067114 0.31 157894.000000 21.633700 o
Sn (189.925 nm)0.000698 u ppm 0.003483 > 100.00 2.750040 0.000698 u
Sr (421.552 nm)5.644377 o ppm 0.036359 0.64 1246285.206382 5.644377 o
Th (288.505 nm)0.116686 ppm 0.002436 2.09 490.927000 0.116686
Ti (336.122 nm)-0.002975 u ppm 0.000139 4.69 1424.310000 -0.002975 u
Tl (190.794 nm)0.002624 ppm 0.002667 > 100.00 -0.571220 0.002624
U (409.013 nm)0.220360 ppm 0.003257 1.48 998.472000 0.220360
V (292.401 nm)0.003529 ppm 0.000200 5.67 87.012100 0.003529
Zn (206.200 nm)0.007032 ppm 0.000817 11.62 19.325900 0.007032
Zr (343.823 nm)-0.000050 u ppm 0.000125 > 100.00 -7.873230 -0.000050 u
Test Report
52A112023.esws
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Page 1030 of 1261
Solution Name: 280-184021-F-5-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-F-5-A 11/20/2023 10:45:58 PM 4:13 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.111039 ppm 0.000611 0.55 287626.079848 0.111039
Ag (328.068 nm)0.001160 ppm 0.000095 8.22 32.641900 0.001160
Al (394.401 nm)0.040969 ppm 0.001152 2.81 934.992000 0.040969
Al H (396.152 nm)-0.040001 u ppm 0.003890 9.72 -129.210000 -0.040001 u
As (188.980 nm)0.004750 ppm 0.001203 25.32 0.541495 0.004750
B (249.678 nm)0.510188 ppm 0.001246 0.24 4286.280000 0.510188
Ba (493.408 nm)0.127288 ppm 0.000741 0.58 19278.000000 0.127288
Be (234.861 nm)0.000173 ppm 0.000025 14.42 70.385400 0.000173
Bi (223.061 nm)0.003969 ppm 0.002049 51.63 9.985870 0.003969
Ca (315.887 nm)359.743142 o ppm 1.874129 0.52 242593.629856 359.743142 o
Cd (214.439 nm)0.000552 ppm 0.000088 16.01 8.353570 0.000552
Co (228.615 nm)0.000736 ppm 0.000374 50.80 56.849500 0.000736
Cr (205.560 nm)0.000592 ppm 0.000483 81.48 3.881870 0.000592
Cu (324.754 nm)0.000619 ppm 0.000233 37.63 590.977000 0.000619
Fe (238.204 nm)0.120937 ppm 0.000739 0.61 492.692481 0.120937
Fe H (259.940 nm)0.197311 u ppm 0.005194 2.63 180.773000 0.197311 u
K (766.491 nm)10.076700 ppm 0.062009 0.62 17656.900000 10.076700
Li (670.783 nm)0.103081 ppm 0.002445 2.37 -447.071000 0.103081
Mg (279.078 nm)105.745000 o ppm 0.536321 0.51 353691.000000 105.745000 o
Mn (257.610 nm)0.216987 ppm 0.001101 0.51 57901.200000 0.216987
Mo (202.032 nm)0.005648 ppm 0.000640 11.33 31.504500 0.005648
Na (589.592 nm)141.219000 o ppm 1.352820 0.96 1719070.000000 141.219000 o
Na H (589.593 nm)132.622740 ppm 0.409047 0.31 1253780.986293 132.622740
Ni (231.604 nm)0.051355 ppm 0.000468 0.91 164.659000 0.051355
P (213.618 nm)0.258990 ppm 0.001779 0.69 308.644000 0.258990
Pb (220.353 nm)0.000142 u ppm 0.002857 > 100.00 -1.312800 0.000142 u
S (181.972 nm)102.369837 o ppm 0.683798 0.67 20878.838469 102.369837 o
Sb (206.834 nm)-0.005086 u ppm 0.001024 20.13 -4.202430 -0.005086 u
Se (196.026 nm)0.000051 u ppm 0.001846 > 100.00 5.177910 0.000051 u
Si (288.158 nm)21.698200 o ppm 0.074585 0.34 158362.000000 21.698200 o
Sn (189.925 nm)-0.000805 u ppm 0.001395 > 100.00 1.739910 -0.000805 u
Sr (421.552 nm)2.580638 o ppm 0.012579 0.49 569813.209403 2.580638 o
Th (288.505 nm)0.078961 ppm 0.000267 0.34 414.109000 0.078961
Ti (336.122 nm)-0.001547 u ppm 0.000048 3.09 501.477000 -0.001547 u
Tl (190.794 nm)0.002479 u ppm 0.002986 > 100.00 0.192920 0.002479 u
U (409.013 nm)0.006659 ppm 0.005689 85.43 54.056600 0.006659
V (292.401 nm)0.004932 ppm 0.000240 4.86 173.434000 0.004932
Zn (206.200 nm)-0.000038 u ppm 0.000537 > 100.00 4.080420 -0.000038 u
Zr (343.823 nm)0.000103 ppm 0.000036 35.29 0.940924 0.000103
Test Report
52A112023.esws
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Page 1031 of 1261
Solution Name: 280-184021-F-6-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184021-F-6-A 11/20/2023 10:50:22 PM 4:14 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.124665 b ppm 0.000778 0.62 324201.537013 0.124665 b
Ag (328.068 nm)0.001432 ppm 0.000213 14.88 50.686200 0.001432
Al (394.401 nm)0.041770 ppm 0.001017 2.43 939.214000 0.041770
Al H (396.152 nm)-0.045423 u ppm 0.006881 15.15 -153.575000 -0.045423 u
As (188.980 nm)0.010156 ppm 0.006315 62.18 4.970050 0.010156
B (249.678 nm)4.035040 ppm 0.014818 0.37 33788.100000 4.035040
Ba (493.408 nm)0.057936 ppm 0.000921 1.59 8794.030000 0.057936
Be (234.861 nm)0.000174 ppm 0.000039 22.28 160.460000 0.000174
Bi (223.061 nm)0.002000 u ppm 0.002709 > 100.00 7.059220 0.002000 u
Ca (315.887 nm)413.473591 o ppm 0.792749 0.19 278830.470458 413.473591 o
Cd (214.439 nm)0.000600 ppm 0.000043 7.24 10.502500 0.000600
Co (228.615 nm)0.005193 ppm 0.000320 6.17 141.839000 0.005193
Cr (205.560 nm)0.001825 ppm 0.000519 28.44 8.514630 0.001825
Cu (324.754 nm)0.001016 ppm 0.000167 16.45 590.186000 0.001016
Fe (238.204 nm)7.116089 o ppm 0.008184 0.12 28028.474678 7.116089 o
Fe H (259.940 nm)6.973880 ppm 0.017642 0.25 11157.300000 6.973880
K (766.491 nm)8.561680 ppm 0.021572 0.25 14935.000000 8.561680
Li (670.783 nm)0.112283 ppm 0.000685 0.61 -104.856000 0.112283
Mg (279.078 nm)100.919000 o ppm 0.675701 0.67 337545.000000 100.919000 o
Mn (257.610 nm)1.967180 o ppm 0.010849 0.55 524890.000000 1.967180 o
Mo (202.032 nm)0.041172 ppm 0.000565 1.37 207.774000 0.041172
Na (589.592 nm)368.147000 o ppm 0.497653 0.14 4476600.000000 368.147000 o
Na H (589.593 nm)367.697553 ppm 3.456328 0.94 3311066.937544 367.697553
Ni (231.604 nm)0.379254 ppm 0.002436 0.64 1281.190000 0.379254
P (213.618 nm)0.429881 ppm 0.001734 0.40 509.401000 0.429881
Pb (220.353 nm)0.001102 ppm 0.000463 42.02 0.858816 0.001102
S (181.972 nm)183.806694 bo ppm 1.476081 0.80 37466.483692 183.806694 bo
Sb (206.834 nm)-0.003122 u ppm 0.002362 75.68 -1.485110 -0.003122 u
Se (196.026 nm)0.002920 ppm 0.002208 75.64 7.365760 0.002920
Si (288.158 nm)17.869700 o ppm 0.093129 0.52 130545.000000 17.869700 o
Sn (189.925 nm)-0.002205 u ppm 0.000556 25.21 0.799428 -0.002205 u
Sr (421.552 nm)1.765166 o ppm 0.022573 1.28 389757.302936 1.765166 o
Th (288.505 nm)0.104730 ppm 0.003085 2.95 497.496000 0.104730
Ti (336.122 nm)-0.001707 u ppm 0.000165 9.67 601.766000 -0.001707 u
Tl (190.794 nm)0.002670 ppm 0.002156 80.72 0.192857 0.002670
U (409.013 nm)0.020803 ppm 0.001425 6.85 123.646000 0.020803
V (292.401 nm)0.002140 ppm 0.000294 13.73 55.555300 0.002140
Zn (206.200 nm)0.001491 ppm 0.000860 57.70 7.378580 0.001491
Zr (343.823 nm)-0.000087 u ppm 0.000207 > 100.00 -5.130360 -0.000087 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 161 of 287
Page 1032 of 1261
Solution Name: MB 280-634435/1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
MB 280-634435/1-A 11/20/2023 10:54:49 PM 4:15 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000448 ppm 0.000008 1.83 561.804617 0.000448
Ag (328.068 nm)0.000188 ppm 0.000107 56.83 -18.921600 0.000188
Al (394.401 nm)0.003101 ppm 0.000749 24.15 487.498000 0.003101
Al H (396.152 nm)0.002816 u ppm 0.004103 > 100.00 63.218400 0.002816 u
As (188.980 nm)0.002426 ppm 0.001921 79.18 -1.388880 0.002426
B (249.678 nm)0.005632 ppm 0.001448 25.72 63.316400 0.005632
Ba (493.408 nm)0.000070 u ppm 0.000099 > 100.00 10.005200 0.000070 u
Be (234.861 nm)-0.000013 u ppm 0.000022 > 100.00 37.828700 -0.000013 u
Bi (223.061 nm)0.001283 u ppm 0.003045 > 100.00 5.992630 0.001283 u
Ca (315.887 nm)0.052221 ppm 0.010010 19.17 11.206160 0.052221
Cd (214.439 nm)0.000109 u ppm 0.000136 > 100.00 1.713180 0.000109 u
Co (228.615 nm)-0.000022 u ppm 0.000171 > 100.00 42.422800 -0.000022 u
Cr (205.560 nm)0.000155 ppm 0.000135 86.88 2.160590 0.000155
Cu (324.754 nm)0.000670 ppm 0.000158 23.63 797.986000 0.000670
Fe (238.204 nm)0.006064 ppm 0.000329 5.42 40.476603 0.006064
Fe H (259.940 nm)0.098806 u ppm 0.003503 3.55 21.217600 0.098806 u
K (766.491 nm)0.006418 u ppm 0.044791 > 100.00 -435.882000 0.006418 u
Li (670.783 nm)0.003186 ppm 0.000355 11.14 -4162.120000 0.003186
Mg (279.078 nm)0.006172 ppm 0.001701 27.56 29.378200 0.006172
Mn (257.610 nm)0.000260 ppm 0.000055 21.13 73.970600 0.000260
Mo (202.032 nm)0.000574 ppm 0.000480 83.61 6.327880 0.000574
Na (589.592 nm)0.136070 ppm 0.005276 3.88 2691.020000 0.136070
Na H (589.593 nm)-9.788365 u ppm 0.024875 0.25 5986.567609 -9.788365 u
Ni (231.604 nm)0.000200 u ppm 0.000848 > 100.00 -9.528610 0.000200 u
P (213.618 nm)0.000916 u ppm 0.003815 > 100.00 4.137150 0.000916 u
Pb (220.353 nm)0.000587 u ppm 0.001999 > 100.00 -0.271636 0.000587 u
S (181.972 nm)-0.010321 u ppm 0.007899 76.53 21.975439 -0.010321 u
Sb (206.834 nm)0.001916 ppm 0.001418 74.01 4.341920 0.001916
Se (196.026 nm)0.005978 ppm 0.002967 49.63 8.683440 0.005978
Si (288.158 nm)0.007105 ppm 0.000088 1.23 763.160000 0.007105
Sn (189.925 nm)-0.000723 u ppm 0.000735 > 100.00 1.795180 -0.000723 u
Sr (421.552 nm)0.000175 ppm 0.000112 64.21 48.281231 0.000175
Th (288.505 nm)0.012938 ppm 0.005228 40.41 284.711000 0.012938
Ti (336.122 nm)-0.000088 u ppm 0.000070 79.24 -127.610000 -0.000088 u
Tl (190.794 nm)0.001087 u ppm 0.001848 > 100.00 -1.308260 0.001087 u
U (409.013 nm)-0.002992 u ppm 0.002685 89.73 10.388300 -0.002992 u
V (292.401 nm)-0.000063 u ppm 0.000139 > 100.00 -41.656900 -0.000063 u
Zn (206.200 nm)-0.000742 u ppm 0.000656 88.43 2.563270 -0.000742 u
Zr (343.823 nm)-0.000132 u ppm 0.000020 14.99 -18.442400 -0.000132 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 162 of 287
Page 1033 of 1261
Solution Name: LCS 280-634435/2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634435/2-A 11/20/2023 10:58:51 PM 4:16 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.940545 ppm 0.003707 0.39 2412769.767998 0.940545
Ag (328.068 nm)0.050766 ppm 0.000157 0.31 2226.820000 0.050766
Al (394.401 nm)9.795040 o ppm 0.038088 0.39 120971.000000 9.795040 o
Al H (396.152 nm)9.457870 ppm 0.045001 0.48 42556.200000 9.457870
As (188.980 nm)0.996862 ppm 0.008198 0.82 824.777000 0.996862
B (249.678 nm)1.992870 ppm 0.005249 0.26 16695.900000 1.992870
Ba (493.408 nm)0.971435 ppm 0.003084 0.32 147155.000000 0.971435
Be (234.861 nm)1.022950 ppm 0.009375 0.92 171076.000000 1.022950
Bi (223.061 nm)0.002233 u ppm 0.005281 > 100.00 7.405570 0.002233 u
Ca (315.887 nm)49.390546 o ppm 0.200203 0.41 33285.914415 49.390546 o
Cd (214.439 nm)0.985884 ppm 0.004419 0.45 14738.000000 0.985884
Co (228.615 nm)0.962235 ppm 0.004271 0.44 18431.000000 0.962235
Cr (205.560 nm)0.986613 ppm 0.003649 0.37 4056.700000 0.986613
Cu (324.754 nm)0.955869 ppm 0.003417 0.36 45342.300000 0.955869
Fe (238.204 nm)9.857092 o ppm 0.064136 0.65 38830.412997 9.857092 o
Fe H (259.940 nm)9.631920 ppm 0.040348 0.42 15462.700000 9.631920
K (766.491 nm)49.870900 ppm 0.266058 0.53 89153.300000 49.870900
Li (670.783 nm)0.961972 ppm 0.002950 0.31 31494.600000 0.961972
Mg (279.078 nm)50.726300 o ppm 0.200333 0.39 169666.000000 50.726300 o
Mn (257.610 nm)0.984590 ppm 0.003644 0.37 262714.000000 0.984590
Mo (202.032 nm)0.993835 ppm 0.003900 0.39 4934.970000 0.993835
Na (589.592 nm)47.928700 ppm 0.235766 0.49 594999.000000 47.928700
Na H (589.593 nm)38.668029 u ppm 0.251229 0.65 438590.205574 38.668029 u
Ni (231.604 nm)0.964195 ppm 0.004551 0.47 3273.700000 0.964195
P (213.618 nm)20.098100 o ppm 0.081190 0.40 23652.600000 20.098100 o
Pb (220.353 nm)1.040800 ppm 0.005399 0.52 2385.290000 1.040800
S (181.972 nm)18.188742 o ppm 0.077927 0.43 3732.899260 18.188742 o
Sb (206.834 nm)1.023400 ppm 0.008266 0.81 1248.490000 1.023400
Se (196.026 nm)0.976984 ppm 0.008869 0.91 604.177000 0.976984
Si (288.158 nm)9.569950 ppm 0.043518 0.45 70721.500000 9.569950
Sn (189.925 nm)0.981276 ppm 0.007765 0.79 661.685000 0.981276
Sr (421.552 nm)0.973937 ppm 0.003043 0.31 215054.386409 0.973937
Th (288.505 nm)0.072442 ppm 0.002464 3.40 372.907000 0.072442
Ti (336.122 nm)0.979197 ppm 0.003343 0.34 106839.000000 0.979197
Tl (190.794 nm)0.970958 ppm 0.005725 0.59 1049.440000 0.970958
U (409.013 nm)-0.009548 u ppm 0.003747 39.25 -39.254400 -0.009548 u
V (292.401 nm)0.983409 ppm 0.003634 0.37 40916.500000 0.983409
Zn (206.200 nm)0.985474 ppm 0.003537 0.36 2129.200000 0.985474
Zr (343.823 nm)0.975989 ppm 0.003258 0.33 79567.700000 0.975989
Test Report
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Page 1034 of 1261
Solution Name: LCSD 280-634435/3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCSD 280-634435/3-A 11/20/2023 11:03:19 PM 4:17 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.934591 ppm 0.004688 0.50 2397499.486255 0.934591
Ag (328.068 nm)0.050717 ppm 0.000324 0.64 2224.230000 0.050717
Al (394.401 nm)9.736710 o ppm 0.048003 0.49 120265.000000 9.736710 o
Al H (396.152 nm)9.405040 ppm 0.023336 0.25 42318.700000 9.405040
As (188.980 nm)0.997285 ppm 0.001816 0.18 825.130000 0.997285
B (249.678 nm)1.985640 ppm 0.007347 0.37 16635.300000 1.985640
Ba (493.408 nm)0.965834 ppm 0.000867 0.09 146306.000000 0.965834
Be (234.861 nm)1.006670 ppm 0.001089 0.11 168355.000000 1.006670
Bi (223.061 nm)-0.000509 u ppm 0.000221 43.49 3.328550 -0.000509 u
Ca (315.887 nm)49.059933 o ppm 0.117680 0.24 33062.942516 49.059933 o
Cd (214.439 nm)0.979715 ppm 0.004131 0.42 14645.700000 0.979715
Co (228.615 nm)0.958330 ppm 0.004107 0.43 18356.200000 0.958330
Cr (205.560 nm)0.982752 ppm 0.005003 0.51 4040.850000 0.982752
Cu (324.754 nm)0.949826 ppm 0.005944 0.63 45052.100000 0.949826
Fe (238.204 nm)9.802671 o ppm 0.036880 0.38 38616.117736 9.802671 o
Fe H (259.940 nm)9.582330 ppm 0.041986 0.44 15382.300000 9.582330
K (766.491 nm)49.983500 ppm 0.091914 0.18 89355.600000 49.983500
Li (670.783 nm)0.964865 ppm 0.002860 0.30 31602.200000 0.964865
Mg (279.078 nm)50.447400 o ppm 0.207772 0.41 168734.000000 50.447400 o
Mn (257.610 nm)0.978786 ppm 0.003962 0.40 261165.000000 0.978786
Mo (202.032 nm)0.986068 ppm 0.005616 0.57 4896.430000 0.986068
Na (589.592 nm)49.628800 ppm 0.194790 0.39 615600.000000 49.628800
Na H (589.593 nm)40.359044 u ppm 0.199454 0.49 453346.568189 40.359044 u
Ni (231.604 nm)0.957566 ppm 0.001854 0.19 3251.130000 0.957566
P (213.618 nm)19.989900 o ppm 0.089585 0.45 23525.500000 19.989900 o
Pb (220.353 nm)1.038070 ppm 0.004280 0.41 2379.050000 1.038070
S (181.972 nm)18.467730 o ppm 0.101146 0.55 3789.700391 18.467730 o
Sb (206.834 nm)1.010720 ppm 0.007770 0.77 1233.070000 1.010720
Se (196.026 nm)0.976066 ppm 0.005745 0.59 603.615000 0.976066
Si (288.158 nm)9.453370 ppm 0.022232 0.24 69871.100000 9.453370
Sn (189.925 nm)0.973755 ppm 0.008221 0.84 656.631000 0.973755
Sr (421.552 nm)0.969245 ppm 0.000741 0.08 214018.559558 0.969245
Th (288.505 nm)0.073130 ppm 0.001441 1.97 374.379000 0.073130
Ti (336.122 nm)0.971620 ppm 0.004271 0.44 106012.000000 0.971620
Tl (190.794 nm)0.969098 ppm 0.003503 0.36 1047.450000 0.969098
U (409.013 nm)-0.008803 u ppm 0.001452 16.49 -36.426300 -0.008803 u
V (292.401 nm)0.978412 ppm 0.003910 0.40 40704.700000 0.978412
Zn (206.200 nm)0.977742 ppm 0.003209 0.33 2112.530000 0.977742
Zr (343.823 nm)0.968619 ppm 0.004286 0.44 78966.800000 0.968619
Test Report
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Page 1035 of 1261
Solution Name: 280-183889-A-18-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183889-A-18-A 11/20/2023 11:07:47 PM 4:18 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.058111 ppm 0.000189 0.33 149303.751119 0.058111
Ag (328.068 nm)0.001154 ppm 0.000124 10.72 33.131500 0.001154
Al (394.401 nm)0.086177 ppm 0.003960 4.59 1503.560000 0.086177
Al H (396.152 nm)0.065407 u ppm 0.001726 2.64 344.517000 0.065407 u
As (188.980 nm)0.001474 u ppm 0.003140 > 100.00 -2.192730 0.001474 u
B (249.678 nm)0.033053 ppm 0.000996 3.01 292.826000 0.033053
Ba (493.408 nm)0.046152 ppm 0.000632 1.37 6993.530000 0.046152
Be (234.861 nm)0.000161 ppm 0.000026 16.33 86.033100 0.000161
Bi (223.061 nm)0.000423 u ppm 0.000392 92.67 4.714680 0.000423 u
Ca (315.887 nm)32.094770 o ppm 0.049516 0.15 21621.313225 32.094770 o
Cd (214.439 nm)0.000823 ppm 0.000083 10.14 12.684200 0.000823
Co (228.615 nm)0.001776 ppm 0.000220 12.37 76.768400 0.001776
Cr (205.560 nm)0.226251 ppm 0.000733 0.32 932.319000 0.226251
Cu (324.754 nm)0.030357 ppm 0.010974 36.15 2170.250000 0.030357
Fe (238.204 nm)1.496189 ppm 0.001446 0.10 5906.232831 1.496189
Fe H (259.940 nm)1.540710 u ppm 0.002072 0.13 2356.760000 1.540710 u
K (766.491 nm)2.299520 ppm 0.011420 0.50 3684.020000 2.299520
Li (670.783 nm)0.062805 ppm 0.000909 1.45 -1944.930000 0.062805
Mg (279.078 nm)22.517000 ppm 0.052709 0.23 75319.800000 22.517000
Mn (257.610 nm)0.062306 ppm 0.000053 0.09 16628.900000 0.062306
Mo (202.032 nm)0.003967 ppm 0.000236 5.96 23.163600 0.003967
Na (589.592 nm)65.452000 o ppm 0.470857 0.72 797159.000000 65.452000 o
Na H (589.593 nm)55.040429 ppm 0.640113 1.16 573909.522959 55.040429
Ni (231.604 nm)0.053369 ppm 0.001551 2.91 171.520000 0.053369
P (213.618 nm)0.006714 ppm 0.001252 18.65 9.326390 0.006714
Pb (220.353 nm)0.000045 u ppm 0.001412 > 100.00 -1.532920 0.000045 u
S (181.972 nm)29.503500 o ppm 0.118445 0.40 6033.179195 29.503500 o
Sb (206.834 nm)-0.000651 u ppm 0.000547 83.90 2.834710 -0.000651 u
Se (196.026 nm)0.011394 ppm 0.002043 17.93 11.891800 0.011394
Si (288.158 nm)19.192100 o ppm 0.012686 0.07 140154.000000 19.192100 o
Sn (189.925 nm)0.000818 ppm 0.000861 > 100.00 2.830750 0.000818
Sr (421.552 nm)0.269408 ppm 0.002677 0.99 59494.797166 0.269408
Th (288.505 nm)0.031991 ppm 0.002817 8.80 321.854000 0.031991
Ti (336.122 nm)0.001163 ppm 0.000137 11.74 79.067100 0.001163
Tl (190.794 nm)0.004671 ppm 0.003025 64.76 2.550230 0.004671
U (409.013 nm)0.007230 ppm 0.003571 49.40 57.228200 0.007230
V (292.401 nm)0.001686 ppm 0.000139 8.22 -33.235400 0.001686
Zn (206.200 nm)0.006213 ppm 0.000096 1.54 17.560200 0.006213
Zr (343.823 nm)0.000319 ppm 0.000124 39.06 20.343200 0.000319
Test Report
52A112023.esws
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Page 1036 of 1261
Solution Name: 280-183889-A-18-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183889-A-18-A 11/20/2023 11:12:14 PM 4:19 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.010090 ppm 0.000063 0.63 25455.320229 0.010090
Ag (328.068 nm)0.000185 ppm 0.000019 10.09 -19.919900 0.000185
Al (394.401 nm)0.016862 ppm 0.000990 5.87 660.872000 0.016862
Al H (396.152 nm)0.014206 u ppm 0.002625 18.48 114.410000 0.014206 u
As (188.980 nm)-0.000530 u ppm 0.001547 > 100.00 -3.847200 -0.000530 u
B (249.678 nm)0.007249 ppm 0.000574 7.92 76.856400 0.007249
Ba (493.408 nm)0.009192 ppm 0.000193 2.10 1392.420000 0.009192
Be (234.861 nm)0.000056 ppm 0.000007 13.11 53.108100 0.000056
Bi (223.061 nm)0.000347 u ppm 0.001653 > 100.00 4.600340 0.000347 u
Ca (315.887 nm)6.388597 ppm 0.043742 0.68 4284.579497 6.388597
Cd (214.439 nm)0.000275 ppm 0.000167 60.72 4.252120 0.000275
Co (228.615 nm)0.000261 ppm 0.000061 23.25 47.826200 0.000261
Cr (205.560 nm)0.045275 ppm 0.000574 1.27 187.781000 0.045275
Cu (324.754 nm)0.001883 ppm 0.000130 6.88 847.959000 0.001883
Fe (238.204 nm)0.303318 ppm 0.000523 0.17 1210.592679 0.303318
Fe H (259.940 nm)0.386601 u ppm 0.008621 2.23 487.379000 0.386601 u
K (766.491 nm)0.427386 ppm 0.032736 7.66 320.451000 0.427386
Li (670.783 nm)0.015450 ppm 0.001285 8.32 -3706.030000 0.015450
Mg (279.078 nm)4.491850 ppm 0.027225 0.61 15032.800000 4.491850
Mn (257.610 nm)0.012578 ppm 0.000059 0.47 3360.500000 0.012578
Mo (202.032 nm)0.001057 ppm 0.000459 43.44 8.723180 0.001057
Na (589.592 nm)13.269200 ppm 0.057428 0.43 162435.000000 13.269200
Na H (589.593 nm)5.472022 u ppm 2.461512 44.98 139659.425468 5.472022 u
Ni (231.604 nm)0.011586 ppm 0.000760 6.56 29.242100 0.011586
P (213.618 nm)0.002066 u ppm 0.002496 > 100.00 5.434970 0.002066 u
Pb (220.353 nm)0.001393 ppm 0.000936 67.24 1.576070 0.001393
S (181.972 nm)5.772998 ppm 0.060145 1.04 1199.880888 5.772998
Sb (206.834 nm)-0.001548 u ppm 0.001469 94.90 0.440387 -0.001548 u
Se (196.026 nm)0.002567 ppm 0.002420 94.27 6.567330 0.002567
Si (288.158 nm)3.747290 ppm 0.032718 0.87 27937.900000 3.747290
Sn (189.925 nm)-0.000728 u ppm 0.001130 > 100.00 1.791600 -0.000728 u
Sr (421.552 nm)0.053779 ppm 0.000403 0.75 11884.041098 0.053779
Th (288.505 nm)0.012525 ppm 0.000578 4.61 284.241000 0.012525
Ti (336.122 nm)0.000209 ppm 0.000171 81.62 -81.370200 0.000209
Tl (190.794 nm)0.001543 u ppm 0.002483 > 100.00 -0.820449 0.001543 u
U (409.013 nm)0.001435 u ppm 0.002081 > 100.00 29.946100 0.001435 u
V (292.401 nm)0.000379 ppm 0.000142 37.54 -37.539400 0.000379
Zn (206.200 nm)0.000789 ppm 0.000316 40.02 5.864800 0.000789
Zr (343.823 nm)0.000024 u ppm 0.000163 > 100.00 -5.313780 0.000024 u
Test Report
52A112023.esws
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Page 1037 of 1261
Solution Name: 280-183889-A-18-B MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183889-A-18-B MS 11/20/2023 11:16:25 PM 4:20 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.094806 o ppm 0.008650 0.79 2809063.300517 1.094806 o
Ag (328.068 nm)0.052500 ppm 0.000155 0.30 2312.380000 0.052500
Al (394.401 nm)10.264900 o ppm 0.083631 0.81 126760.000000 10.264900 o
Al H (396.152 nm)9.705440 ppm 0.056086 0.58 43668.800000 9.705440
As (188.980 nm)1.028630 ppm 0.009280 0.90 851.157000 1.028630
B (249.678 nm)2.086110 ppm 0.014274 0.68 17476.200000 2.086110
Ba (493.408 nm)1.035270 ppm 0.003552 0.34 156828.000000 1.035270
Be (234.861 nm)1.027940 ppm 0.011341 1.10 171928.000000 1.027940
Bi (223.061 nm)-0.000309 u ppm 0.001720 > 100.00 3.626230 -0.000309 u
Ca (315.887 nm)81.550468 o ppm 0.421528 0.52 54975.179819 81.550468 o
Cd (214.439 nm)0.989079 ppm 0.007736 0.78 14786.000000 0.989079
Co (228.615 nm)0.974358 ppm 0.006082 0.62 18663.300000 0.974358
Cr (205.560 nm)1.226600 o ppm 0.011277 0.92 5043.970000 1.226600 o
Cu (324.754 nm)0.994139 ppm 0.009503 0.96 47103.900000 0.994139
Fe (238.204 nm)11.410716 o ppm 0.075868 0.66 44946.157701 11.410716 o
Fe H (259.940 nm)11.188900 ppm 0.065476 0.59 17984.600000 11.188900
K (766.491 nm)53.883800 ppm 0.091716 0.17 96363.000000 53.883800
Li (670.783 nm)1.056050 ppm 0.004274 0.40 34993.400000 1.056050
Mg (279.078 nm)74.492600 o ppm 0.636832 0.85 249157.000000 74.492600 o
Mn (257.610 nm)1.055790 ppm 0.008596 0.81 281712.000000 1.055790
Mo (202.032 nm)1.013640 ppm 0.007869 0.78 5033.250000 1.013640
Na (589.592 nm)116.313000 o ppm 0.193767 0.17 1426970.000000 116.313000 o
Na H (589.593 nm)106.040849 ppm 0.115934 0.11 1028934.779473 106.040849
Ni (231.604 nm)1.021860 ppm 0.011326 1.11 3470.050000 1.021860
P (213.618 nm)20.518200 o ppm 0.140458 0.68 24146.100000 20.518200 o
Pb (220.353 nm)1.049670 ppm 0.008100 0.77 2405.560000 1.049670
S (181.972 nm)48.785091 o ppm 0.466107 0.96 9964.636711 48.785091 o
Sb (206.834 nm)1.050480 ppm 0.010405 0.99 1283.050000 1.050480
Se (196.026 nm)1.003720 ppm 0.001905 0.19 620.468000 1.003720
Si (288.158 nm)29.071000 o ppm 0.277817 0.96 212422.000000 29.071000 o
Sn (189.925 nm)1.010100 ppm 0.001593 0.16 681.054000 1.010100
Sr (421.552 nm)1.267345 o ppm 0.004603 0.36 279838.795516 1.267345 o
Th (288.505 nm)0.078945 ppm 0.003125 3.96 386.263000 0.078945
Ti (336.122 nm)1.006390 ppm 0.007829 0.78 109877.000000 1.006390
Tl (190.794 nm)0.970489 ppm 0.008220 0.85 1048.830000 0.970489
U (409.013 nm)-0.007542 u ppm 0.004016 53.25 -30.137800 -0.007542 u
V (292.401 nm)1.002560 ppm 0.007787 0.78 41646.200000 1.002560
Zn (206.200 nm)0.993610 ppm 0.008989 0.90 2146.750000 0.993610
Zr (343.823 nm)1.000720 ppm 0.008069 0.81 81585.700000 1.000720
Test Report
52A112023.esws
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Page 1038 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/20/2023 11:20:53 PM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000050 ppm 0.000010 20.75 1048.470873 0.000050
Ag (328.068 nm)0.000263 ppm 0.000146 55.58 127.071000 0.000263
Al (394.401 nm)51.804100 o ppm 0.056096 0.11 636864.000000 51.804100 o
Al H (396.152 nm)48.618000 ppm 0.082195 0.17 218550.000000 48.618000
As (188.980 nm)0.004175 ppm 0.001729 41.41 -0.380465 0.004175
B (249.678 nm)0.000824 ppm 0.000477 57.96 23.073400 0.000824
Ba (493.408 nm)0.000031 ppm 0.000027 86.54 144.229000 0.000031
Be (234.861 nm)0.000082 ppm 0.000036 43.63 696.252000 0.000082
Bi (223.061 nm)-0.001219 u ppm 0.001070 87.76 2.272250 -0.001219 u
Ca (315.887 nm)-0.025359 u ppm 0.001559 6.15 -41.114891 -0.025359 u
Cd (214.439 nm)0.000045 u ppm 0.000333 > 100.00 10.944800 0.000045 u
Co (228.615 nm)0.000284 u ppm 0.000302 > 100.00 48.279300 0.000284 u
Cr (205.560 nm)0.000515 ppm 0.000551 > 100.00 3.637070 0.000515
Cu (324.754 nm)-0.000365 u ppm 0.000238 65.23 1686.660000 -0.000365 u
Fe (238.204 nm)49.928979 o ppm 0.082361 0.16 196557.488461 49.928979 o
Fe H (259.940 nm)48.205000 ppm 0.088185 0.18 77942.200000 48.205000
K (766.491 nm)0.068705 ppm 0.038623 56.22 -323.973000 0.068705
Li (670.783 nm)0.003357 ppm 0.001171 34.88 -4155.750000 0.003357
Mg (279.078 nm)0.005862 ppm 0.001424 24.29 -159.665000 0.005862
Mn (257.610 nm)-0.000899 u ppm 0.000002 0.25 -235.393000 -0.000899 u
Mo (202.032 nm)0.000607 ppm 0.000524 86.42 6.489320 0.000607
Na (589.592 nm)244.789000 o ppm 2.209200 0.90 2976490.000000 244.789000 o
Na H (589.593 nm)234.447327 ppm 1.573865 0.67 2144070.878905 234.447327
Ni (231.604 nm)-0.000402 u ppm 0.000156 38.92 -11.578000 -0.000402 u
P (213.618 nm)4.987950 ppm 0.019858 0.40 5890.800000 4.987950
Pb (220.353 nm)-0.000199 u ppm 0.001647 > 100.00 -3.643070 -0.000199 u
S (181.972 nm)4.688924 ppm 0.017833 0.38 980.844580 4.688924
Sb (206.834 nm)-0.000906 u ppm 0.000751 82.93 4.345660 -0.000906 u
Se (196.026 nm)0.003803 u ppm 0.004541 > 100.00 2.120090 0.003803 u
Si (288.158 nm)0.043432 ppm 0.003021 6.95 1027.390000 0.043432
Sn (189.925 nm)0.000353 u ppm 0.002074 > 100.00 2.517980 0.000353 u
Sr (421.552 nm)0.000515 ppm 0.000035 6.82 123.335834 0.000515
Th (288.505 nm)4.524840 ppm 0.004982 0.11 8716.730000 4.524840
Ti (336.122 nm)0.000696 ppm 0.000114 16.42 -42.167100 0.000696
Tl (190.794 nm)-0.003011 u ppm 0.002448 81.31 -6.655380 -0.003011 u
U (409.013 nm)2.361210 Q ppm 0.006986 0.30 10549.200000 Q 2.361210 Q
V (292.401 nm)0.000703 ppm 0.000073 10.38 270.490000 0.000703
Zn (206.200 nm)0.000928 u ppm 0.001235 > 100.00 6.163020 0.000928 u
Zr (343.823 nm)-0.000668 u ppm 0.000089 13.38 5.337840 -0.000668 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 168 of 287
Page 1039 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/20/2023 11:25:19 PM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.446341 Q ppm 0.001190 0.27 1144528.863618
Q 0.446341 Q
Ag (328.068 nm)0.502311 ppm 0.000824 0.16 26831.900000 0.502311
Al (394.401 nm)0.491118 ppm 0.002579 0.53 6492.240000 0.491118
Al H (396.152 nm)0.493390 u ppm 0.004769 0.97 2267.960000 0.493390 u
As (188.980 nm)0.498144 ppm 0.001255 0.25 410.470000 0.498144
B (249.678 nm)0.494190 ppm 0.001242 0.25 4152.380000 0.494190
Ba (493.408 nm)0.493947 ppm 0.001647 0.33 74816.600000 0.493947
Be (234.861 nm)0.511738 ppm 0.002365 0.46 85569.700000 0.511738
Bi (223.061 nm)0.985642 ppm 0.004544 0.46 1469.520000 0.985642
Ca (315.887 nm)4.944543 ppm 0.014910 0.30 3310.681676 4.944543
Cd (214.439 nm)0.505247 ppm 0.001413 0.28 7552.440000 0.505247
Co (228.615 nm)0.502768 ppm 0.000960 0.19 9650.010000 0.502768
Cr (205.560 nm)0.509660 ppm 0.003011 0.59 2096.370000 0.509660
Cu (324.754 nm)0.496731 ppm 0.001673 0.34 23936.800000 0.496731
Fe (238.204 nm)2.480436 ppm 0.007719 0.31 9786.904551 2.480436
Fe H (259.940 nm)2.492620 u ppm 0.004339 0.17 3898.650000 2.492620 u
K (766.491 nm)50.027400 ppm 0.208291 0.42 89434.400000 50.027400
Li (670.783 nm)0.490212 ppm 0.001479 0.30 13950.100000 0.490212
Mg (279.078 nm)20.144400 ppm 0.054060 0.27 67384.400000 20.144400
Mn (257.610 nm)0.493625 ppm 0.001040 0.21 131714.000000 0.493625
Mo (202.032 nm)0.497322 ppm 0.001286 0.26 2471.230000 0.497322
Na (589.592 nm)24.390000 ppm 0.079650 0.33 303290.000000 24.390000
Na H (589.593 nm)14.128817 u ppm 0.233178 1.65 219638.340465 14.128817 u
Ni (231.604 nm)0.508139 ppm 0.001697 0.33 1720.430000 0.508139
P (213.618 nm)0.012506 ppm 0.003839 30.70 -22.216400 0.012506
Pb (220.353 nm)0.533738 ppm 0.001309 0.25 1222.950000 0.533738
S (181.972 nm)-0.025361 u ppm 0.009089 35.84 21.382657 -0.025361 u
Sb (206.834 nm)0.490983 ppm 0.003212 0.65 599.909000 0.490983
Se (196.026 nm)0.502873 ppm 0.002631 0.52 313.679000 0.502873
Si (288.158 nm)4.948610 ppm 0.019934 0.40 36909.200000 4.948610
Sn (189.925 nm)0.498819 ppm 0.000361 0.07 337.480000 0.498819
Sr (421.552 nm)0.495282 ppm 0.001902 0.38 109367.766384 0.495282
Th (288.505 nm)0.041814 ppm 0.001492 3.57 326.900000 0.041814
Ti (336.122 nm)0.495484 ppm 0.000978 0.20 53959.500000 0.495484
Tl (190.794 nm)0.496569 ppm 0.003757 0.76 535.595000 0.496569
U (409.013 nm)-0.005466 u ppm 0.003638 66.56 -13.690300 -0.005466 u
V (292.401 nm)0.495739 ppm 0.001413 0.29 20602.500000 0.495739
Zn (206.200 nm)0.507506 ppm 0.003480 0.69 1098.530000 0.507506
Zr (343.823 nm)0.491157 ppm 0.001124 0.23 40034.500000 0.491157
Test Report
52A112023.esws
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Page 1040 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/20/2023 11:29:40 PM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000482 ppm 0.000012 2.40 643.373103 0.000482
Ag (328.068 nm)0.000242 ppm 0.000058 23.87 -15.825100 0.000242
Al (394.401 nm)-0.000339 u ppm 0.000360 > 100.00 445.310000 -0.000339 u
Al H (396.152 nm)-0.000536 u ppm 0.003850 > 100.00 48.155200 -0.000536 u
As (188.980 nm)0.000278 u ppm 0.000860 > 100.00 -3.173510 0.000278 u
B (249.678 nm)0.001242 ppm 0.000292 23.52 26.578800 0.001242
Ba (493.408 nm)0.000340 ppm 0.000072 21.02 50.915200 0.000340
Be (234.861 nm)0.000043 ppm 0.000016 36.73 46.991200 0.000043
Bi (223.061 nm)0.000742 u ppm 0.002112 > 100.00 5.188770 0.000742 u
Ca (315.887 nm)0.007950 ppm 0.004147 52.16 -18.650682 0.007950
Cd (214.439 nm)-0.000011 u ppm 0.000116 > 100.00 -0.083859 -0.000011 u
Co (228.615 nm)0.000182 ppm 0.000036 19.85 46.324800 0.000182
Cr (205.560 nm)0.000223 ppm 0.000040 18.09 2.440380 0.000223
Cu (324.754 nm)0.000556 ppm 0.000198 35.62 792.550000 0.000556
Fe (238.204 nm)0.000419 ppm 0.000321 76.52 18.252682 0.000419
Fe H (259.940 nm)0.094563 u ppm 0.000742 0.79 14.345200 0.094563 u
K (766.491 nm)0.038834 u ppm 0.041293 > 100.00 -377.641000 0.038834 u
Li (670.783 nm)0.005178 S ppm 0.000587 11.35 -4088.040000 S 0.005178 S
Mg (279.078 nm)0.001342 ppm 0.001032 76.88 13.269900 0.001342
Mn (257.610 nm)-0.000012 u ppm 0.000014 > 100.00 1.192070 -0.000012 u
Mo (202.032 nm)0.000700 u ppm 0.000683 97.60 6.950960 0.000700 u
Na (589.592 nm)0.052640 ppm 0.003681 6.99 1678.890000 0.052640
Na H (589.593 nm)-9.997798 u ppm 0.014741 0.15 4154.622342 -9.997798 u
Ni (231.604 nm)0.000354 u ppm 0.000666 > 100.00 -9.005180 0.000354 u
P (213.618 nm)-0.001537 u ppm 0.003414 > 100.00 1.258870 -0.001537 u
Pb (220.353 nm)0.000070 u ppm 0.002057 > 100.00 -1.461340 0.000070 u
S (181.972 nm)-0.037583 u ppm 0.003669 9.76 16.417223 -0.037583 u
Sb (206.834 nm)-0.000118 u ppm 0.002749 > 100.00 1.860620 -0.000118 u
Se (196.026 nm)0.003470 ppm 0.001941 55.95 7.144620 0.003470
Si (288.158 nm)0.001854 ppm 0.000206 11.09 725.247000 0.001854
Sn (189.925 nm)0.000115 u ppm 0.001711 > 100.00 2.358240 0.000115 u
Sr (421.552 nm)0.000067 ppm 0.000024 35.82 24.384543 0.000067
Th (288.505 nm)0.010910 Z ppm 0.003205 29.38 280.926000 Z 0.010910 Z
Ti (336.122 nm)0.000038 ppm 0.000044 > 100.00 -113.967000 0.000038
Tl (190.794 nm)0.003108 ppm 0.001654 53.22 0.885749 0.003108
U (409.013 nm)0.001259 u ppm 0.005727 > 100.00 29.090000 0.001259 u
V (292.401 nm)0.000220 ppm 0.000152 69.29 -29.758900 0.000220
Zn (206.200 nm)-0.000978 u ppm 0.000273 27.92 2.053770 -0.000978 u
Zr (343.823 nm)0.000070 u ppm 0.000097 > 100.00 -1.922980 0.000070 u
Test Report
52A112023.esws
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Page 1041 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/20/2023 11:33:42 PM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014152 ppm 0.000032 0.23 35794.301078 0.014152
Ag (328.068 nm)0.009666 ppm 0.000065 0.67 485.172000 0.009666
Al (394.401 nm)0.088225 ppm 0.000844 0.96 1546.460000 0.088225
Al H (396.152 nm)0.093625 u ppm 0.002153 2.30 471.334000 0.093625 u
As (188.980 nm)0.016565 ppm 0.000895 5.40 10.358000 0.016565
B (249.678 nm)0.096084 ppm 0.000589 0.61 820.373000 0.096084
Ba (493.408 nm)0.009548 ppm 0.000221 2.32 1445.790000 0.009548
Be (234.861 nm)0.000975 ppm 0.000013 1.38 204.141000 0.000975
Bi (223.061 nm)-0.000686 Qu ppm 0.000723 > 100.00 3.064560 Q -0.000686 Qu
Ca (315.887 nm)0.205852 ppm 0.007342 3.57 114.818155 0.205852
Cd (214.439 nm)0.005090 ppm 0.000184 3.61 76.174600 0.005090
Co (228.615 nm)0.010263 ppm 0.000301 2.94 238.908000 0.010263
Cr (205.560 nm)0.010109 ppm 0.000691 6.83 43.009700 0.010109
Cu (324.754 nm)0.014938 ppm 0.000110 0.74 1456.070000 0.014938
Fe (238.204 nm)0.101409 ppm 0.000756 0.75 415.852966 0.101409
Fe H (259.940 nm)0.190756 u ppm 0.003796 1.99 170.155000 0.190756 u
K (766.491 nm)2.985170 ppm 0.045272 1.52 4915.900000 2.985170
Li (670.783 nm)0.024346 ppm 0.001700 6.98 -3375.170000 0.024346
Mg (279.078 nm)0.200974 ppm 0.000564 0.28 680.446000 0.200974
Mn (257.610 nm)0.010056 ppm 0.000024 0.24 2687.590000 0.010056
Mo (202.032 nm)0.019815 ppm 0.000539 2.72 101.800000 0.019815
Na (589.592 nm)1.029820 ppm 0.021795 2.12 13669.800000 1.029820
Na H (589.593 nm)-9.060633 u ppm 0.011014 0.12 12442.345988 -9.060633 u
Ni (231.604 nm)0.041800 ppm 0.000568 1.36 132.133000 0.041800
P (213.618 nm)2.811000 ppm 0.000826 0.03 3320.450000 2.811000
Pb (220.353 nm)0.011084 ppm 0.001307 11.79 23.882700 0.011084
S (181.972 nm)0.052361 Q ppm 0.005839 11.15 34.805090 Q 0.052361 Q
Sb (206.834 nm)0.019680 ppm 0.000877 4.46 25.908700 0.019680
Se (196.026 nm)0.023574 ppm 0.004640 19.68 19.478200 0.023574
Si (288.158 nm)0.464024 ppm 0.007339 1.58 4113.020000 0.464024
Sn (189.925 nm)0.097367 ppm 0.000961 0.99 67.710300 0.097367
Sr (421.552 nm)0.009512 ppm 0.000026 0.27 2109.909439 0.009512
Th (288.505 nm)0.007299 Q ppm 0.002039 27.94 274.287000 Q 0.007299 Q
Ti (336.122 nm)0.009486 ppm 0.000113 1.19 917.358000 0.009486
Tl (190.794 nm)0.016330 ppm 0.000710 4.34 15.199200 0.016330
U (409.013 nm)0.052317 ppm 0.003096 5.92 253.525000 0.052317
V (292.401 nm)0.009584 ppm 0.000103 1.08 354.850000 0.009584
Zn (206.200 nm)0.019653 ppm 0.000803 4.08 46.542000 0.019653
Zr (343.823 nm)0.009525 ppm 0.000102 1.07 768.945000 0.009525
Test Report
52A112023.esws
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Page 1042 of 1261
Solution Name: 280-183889-A-18-C MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183889-A-18-C MSD 11/20/2023 11:38:01 PM 4:21 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.088716 ppm 0.004874 0.45 2793448.626511 1.088716
Ag (328.068 nm)0.052533 ppm 0.000256 0.49 2316.350000 0.052533
Al (394.401 nm)10.215700 o ppm 0.033899 0.33 126157.000000 10.215700 o
Al H (396.152 nm)9.666620 ppm 0.018014 0.19 43494.300000 9.666620
As (188.980 nm)1.029330 ppm 0.009080 0.88 851.737000 1.029330
B (249.678 nm)2.078120 ppm 0.007904 0.38 17409.300000 2.078120
Ba (493.408 nm)1.031370 ppm 0.003812 0.37 156237.000000 1.031370
Be (234.861 nm)1.017240 ppm 0.001823 0.18 170141.000000 1.017240
Bi (223.061 nm)0.001407 u ppm 0.002017 > 100.00 6.176970 0.001407 u
Ca (315.887 nm)81.186002 o ppm 0.189541 0.23 54729.377272 81.186002 o
Cd (214.439 nm)0.987036 ppm 0.004276 0.43 14755.500000 0.987036
Co (228.615 nm)0.972309 ppm 0.003557 0.37 18624.100000 0.972309
Cr (205.560 nm)1.223140 o ppm 0.001048 0.09 5029.730000 1.223140 o
Cu (324.754 nm)0.987695 ppm 0.003562 0.36 46802.800000 0.987695
Fe (238.204 nm)11.381108 o ppm 0.039926 0.35 44829.578652 11.381108 o
Fe H (259.940 nm)11.152600 ppm 0.025889 0.23 17925.900000 11.152600
K (766.491 nm)53.384300 ppm 0.199143 0.37 95465.700000 53.384300
Li (670.783 nm)1.048900 ppm 0.000353 0.03 34727.400000 1.048900
Mg (279.078 nm)74.270800 o ppm 0.328342 0.44 248415.000000 74.270800 o
Mn (257.610 nm)1.052190 ppm 0.003991 0.38 280750.000000 1.052190
Mo (202.032 nm)1.012030 ppm 0.003468 0.34 5025.250000 1.012030
Na (589.592 nm)114.445000 o ppm 0.741696 0.65 1404220.000000 114.445000 o
Na H (589.593 nm)104.402341 ppm 1.061866 1.02 1014557.901302 104.402341
Ni (231.604 nm)1.016890 ppm 0.002775 0.27 3453.140000 1.016890
P (213.618 nm)20.467300 o ppm 0.099944 0.49 24086.300000 20.467300 o
Pb (220.353 nm)1.045400 ppm 0.006545 0.63 2395.760000 1.045400
S (181.972 nm)48.844747 o ppm 0.291099 0.60 9976.772795 48.844747 o
Sb (206.834 nm)1.049670 ppm 0.009166 0.87 1282.050000 1.049670
Se (196.026 nm)1.004580 ppm 0.005080 0.51 620.996000 1.004580
Si (288.158 nm)28.822200 o ppm 0.078103 0.27 210613.000000 28.822200 o
Sn (189.925 nm)1.004410 ppm 0.010151 1.01 677.230000 1.004410
Sr (421.552 nm)1.260792 o ppm 0.004068 0.32 278391.932965 1.260792 o
Th (288.505 nm)0.082403 ppm 0.003646 4.42 392.890000 0.082403
Ti (336.122 nm)1.004220 ppm 0.003822 0.38 109640.000000 1.004220
Tl (190.794 nm)0.965597 ppm 0.003460 0.36 1043.520000 0.965597
U (409.013 nm)-0.005251 u ppm 0.004647 88.51 -20.062200 -0.005251 u
V (292.401 nm)0.998728 ppm 0.003983 0.40 41486.300000 0.998728
Zn (206.200 nm)0.992857 ppm 0.004007 0.40 2145.120000 0.992857
Zr (343.823 nm)0.999108 ppm 0.003872 0.39 81454.400000 0.999108
Test Report
52A112023.esws
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Page 1043 of 1261
Solution Name: 280-183889-A-18-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-183889-A-18-A 11/20/2023 11:42:32 PM 4:22 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.152727 ppm 0.000477 0.31 392340.410781 0.152727
Ag (328.068 nm)0.050604 ppm 0.000285 0.56 2671.440000 0.050604
Al (394.401 nm)1.066210 ppm 0.004082 0.38 13565.300000 1.066210
Al H (396.152 nm)1.007840 ppm 0.003177 0.32 4579.990000 1.007840
As (188.980 nm)0.201224 ppm 0.001325 0.66 163.766000 0.201224
B (249.678 nm)0.132412 ppm 0.001131 0.85 1124.420000 0.132412
Ba (493.408 nm)0.140151 ppm 0.000725 0.52 21232.600000 0.140151
Be (234.861 nm)0.050160 ppm 0.000556 1.11 8451.480000 0.050160
Bi (223.061 nm)0.000847 u ppm 0.001247 > 100.00 5.344590 0.000847 u
Ca (315.887 nm)50.664972 o ppm 0.202894 0.40 34145.411463 50.664972 o
Cd (214.439 nm)0.049890 ppm 0.000398 0.80 746.272000 0.049890
Co (228.615 nm)0.049625 ppm 0.000186 0.37 991.118000 0.049625
Cr (205.560 nm)0.268244 ppm 0.000650 0.24 1104.890000 0.268244
Cu (324.754 nm)0.055622 ppm 0.000400 0.72 3347.980000 0.055622
Fe (238.204 nm)2.420243 ppm 0.010226 0.42 9544.302320 2.420243
Fe H (259.940 nm)2.426420 u ppm 0.015372 0.63 3791.420000 2.426420 u
K (766.491 nm)22.279400 ppm 0.117509 0.53 39580.900000 22.279400
Li (670.783 nm)0.161010 ppm 0.001100 0.68 1707.250000 0.161010
Mg (279.078 nm)41.609900 ppm 0.176397 0.42 139167.000000 41.609900
Mn (257.610 nm)0.108464 ppm 0.000409 0.38 28944.900000 0.108464
Mo (202.032 nm)0.055223 ppm 0.000771 1.40 277.498000 0.055223
Na (589.592 nm)82.113100 o ppm 0.470894 0.57 1000780.000000 82.113100 o
Na H (589.593 nm)81.635351 ppm 4.978539 6.10 807540.096474 81.635351
Ni (231.604 nm)0.098124 ppm 0.001226 1.25 324.054000 0.098124
P (213.618 nm)1.992510 ppm 0.004501 0.23 2350.960000 1.992510
Pb (220.353 nm)0.105018 ppm 0.002595 2.47 240.242000 0.105018
S (181.972 nm)28.593339 o ppm 0.166917 0.58 5848.786833 28.593339 o
Sb (206.834 nm)0.102850 ppm 0.002102 2.04 128.865000 0.102850
Se (196.026 nm)0.204145 ppm 0.004855 2.38 130.111000 0.204145
Si (288.158 nm)23.292900 o ppm 0.123747 0.53 170017.000000 23.292900 o
Sn (189.925 nm)0.201565 ppm 0.002099 1.04 137.730000 0.201565
Sr (421.552 nm)0.310890 ppm 0.001792 0.58 68653.970058 0.310890
Th (288.505 nm)0.219981 ppm 0.003021 1.37 674.883000 0.219981
Ti (336.122 nm)0.050639 ppm 0.000295 0.58 5518.520000 0.050639
Tl (190.794 nm)0.191522 ppm 0.002823 1.47 205.325000 0.191522
U (409.013 nm)0.470408 ppm 0.004893 1.04 2099.840000 0.470408
V (292.401 nm)0.050736 ppm 0.000153 0.30 2000.350000 0.050736
Zn (206.200 nm)0.200473 ppm 0.001101 0.55 436.457000 0.200473
Zr (343.823 nm)0.049552 ppm 0.000176 0.36 4035.080000 0.049552
Test Report
52A112023.esws
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Page 1044 of 1261
Solution Name: 280-184444-A-2-A @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184444-A-2-A @5 11/20/2023 11:46:57 PM 4:23 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.009597 ppm 0.000047 0.49 24725.968440 0.009597
Ag (328.068 nm)0.000746 ppm 0.000138 18.48 11.092400 0.000746
Al (394.401 nm)0.020267 ppm 0.000880 4.34 690.432000 0.020267
Al H (396.152 nm)0.002987 u ppm 0.002522 84.42 63.989400 0.002987 u
As (188.980 nm)0.004570 ppm 0.002223 48.63 0.364426 0.004570
B (249.678 nm)0.757650 ppm 0.003299 0.44 6357.450000 0.757650
Ba (493.408 nm)0.251491 ppm 0.001309 0.52 38097.700000 0.251491
Be (234.861 nm)0.000111 ppm 0.000024 21.79 99.725700 0.000111
Bi (223.061 nm)-0.001175 u ppm 0.001060 90.18 2.337730 -0.001175 u
Ca (315.887 nm)27.758133 o ppm 0.147759 0.53 18696.602548 27.758133 o
Cd (214.439 nm)0.000233 ppm 0.000015 6.58 4.218870 0.000233
Co (228.615 nm)0.002627 ppm 0.000191 7.26 92.976800 0.002627
Cr (205.560 nm)0.002503 ppm 0.001037 41.42 11.798400 0.002503
Cu (324.754 nm)0.000562 ppm 0.000181 32.22 786.236000 0.000562
Fe (238.204 nm)3.203549 ppm 0.019501 0.61 12627.093722 3.203549
Fe H (259.940 nm)3.184620 u ppm 0.022331 0.70 5019.520000 3.184620 u
K (766.491 nm)13.563900 ppm 0.183431 1.35 23922.100000 13.563900
Li (670.783 nm)-0.012238 u ppm 0.022038 > 100.00 -4735.730000 -0.012238 u
Mg (279.078 nm)21.912000 ppm 0.072848 0.33 73295.000000 21.912000
Mn (257.610 nm)1.365310 o ppm 0.004096 0.30 364298.000000 1.365310 o
Mo (202.032 nm)0.001007 ppm 0.000391 38.79 8.474940 0.001007
Na (589.592 nm)180.487000 o ppm 3.095640 1.72 2197830.000000 180.487000 o
Na H (589.593 nm)127.679304 ppm 5.188395 4.06 1211579.742146 127.679304
Ni (231.604 nm)0.017252 ppm 0.000947 5.49 48.533500 0.017252
P (213.618 nm)0.091724 ppm 0.002082 2.27 111.349000 0.091724
Pb (220.353 nm)0.000800 u ppm 0.001521 > 100.00 0.201272 0.000800 u
S (181.972 nm)7.075833 ppm 0.061350 0.87 1467.141098 7.075833
Sb (206.834 nm)-0.002057 u ppm 0.000510 24.81 -0.269511 -0.002057 u
Se (196.026 nm)0.001042 u ppm 0.003658 > 100.00 6.223910 0.001042 u
Si (288.158 nm)3.528570 ppm 0.016993 0.48 26349.800000 3.528570
Sn (189.925 nm)0.002329 ppm 0.001209 51.89 3.846010 0.002329
Sr (421.552 nm)0.319917 ppm 0.001960 0.61 70647.279793 0.319917
Th (288.505 nm)0.047647 ppm 0.001502 3.15 377.242000 0.047647
Ti (336.122 nm)0.000815 ppm 0.000044 5.34 31.575400 0.000815
Tl (190.794 nm)0.001048 u ppm 0.003365 > 100.00 -1.404940 0.001048 u
U (409.013 nm)0.005112 ppm 0.002274 44.49 49.600100 0.005112
V (292.401 nm)0.002122 ppm 0.000119 5.59 52.093900 0.002122
Zn (206.200 nm)0.011311 ppm 0.000520 4.60 28.552900 0.011311
Zr (343.823 nm)0.001283 ppm 0.000062 4.80 101.296000 0.001283
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 174 of 287
Page 1045 of 1261
Solution Name: 280-184445-G-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184445-G-1-A 11/20/2023 11:51:19 PM 4:24 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.057028 ppm 0.000270 0.47 149272.230697 0.057028
Ag (328.068 nm)0.001895 ppm 0.000133 7.02 72.936700 0.001895
Al (394.401 nm)0.082147 ppm 0.010141 12.34 1421.570000 0.082147
Al H (396.152 nm)0.019028 u ppm 0.005265 27.67 136.079000 0.019028 u
As (188.980 nm)0.014466 ppm 0.001869 12.92 8.471100 0.014466
B (249.678 nm)4.001780 ppm 0.019552 0.49 33509.700000 4.001780
Ba (493.408 nm)1.284600 ppm 0.004073 0.32 194602.000000 1.284600
Be (234.861 nm)0.000234 ppm 0.000054 23.04 286.253000 0.000234
Bi (223.061 nm)0.000324 ppm 0.000272 84.05 4.566880 0.000324
Ca (315.887 nm)138.711124 o ppm 0.334184 0.24 93525.417584 138.711124 o
Cd (214.439 nm)0.000631 ppm 0.000186 29.51 12.796100 0.000631
Co (228.615 nm)0.013115 ppm 0.000349 2.66 293.085000 0.013115
Cr (205.560 nm)0.013140 ppm 0.000569 4.33 55.483100 0.013140
Cu (324.754 nm)0.152196 ppm 0.101490 66.68 7832.260000 0.152196
Fe (238.204 nm)16.107861 o ppm 0.032329 0.20 63423.761634 16.107861 o
Fe H (259.940 nm)15.736800 ppm 0.045969 0.29 25351.200000 15.736800
K (766.491 nm)71.860400 ppm 0.177056 0.25 128661.000000 71.860400
Li (670.783 nm)0.046395 ppm 0.001109 2.39 -2555.210000 0.046395
Mg (279.078 nm)114.268000 o ppm 0.548809 0.48 382187.000000 114.268000 o
Mn (257.610 nm)6.781160 o ppm 0.028650 0.42 1809360.000000 6.781160 o
Mo (202.032 nm)0.000866 ppm 0.000552 63.72 7.775400 0.000866
Na (589.592 nm)870.858000 o ppm 2.367180 0.27 10601500.000000 870.858000 o
Na H (589.593 nm)904.768803 ppm 5.711402 0.63 8023295.932394 904.768803
Ni (231.604 nm)0.088223 ppm 0.001799 2.04 290.205000 0.088223
P (213.618 nm)0.475831 ppm 0.007684 1.61 556.867000 0.475831
Pb (220.353 nm)0.001190 u ppm 0.001494 > 100.00 1.069700 0.001190 u
S (181.972 nm)37.614981 o ppm 0.323216 0.86 7694.704026 37.614981 o
Sb (206.834 nm)-0.001753 u ppm 0.001254 71.52 1.051840 -0.001753 u
Se (196.026 nm)0.000016 u ppm 0.003608 > 100.00 7.834220 0.000016 u
Si (288.158 nm)18.496600 o ppm 0.048902 0.26 135101.000000 18.496600 o
Sn (189.925 nm)-0.001455 u ppm 0.001923 > 100.00 1.303410 -0.001455 u
Sr (421.552 nm)1.635682 o ppm 0.005505 0.34 361167.296258 1.635682 o
Th (288.505 nm)0.169697 ppm 0.002332 1.37 715.366000 0.169697
Ti (336.122 nm)0.004466 ppm 0.000111 2.48 673.271000 0.004466
Tl (190.794 nm)0.001911 ppm 0.000749 39.18 -0.682569 0.001911
U (409.013 nm)-0.011431 u ppm 0.003136 27.44 -9.162580 -0.011431 u
V (292.401 nm)0.009808 ppm 0.000186 1.90 381.324000 0.009808
Zn (206.200 nm)0.015674 ppm 0.000544 3.47 37.961100 0.015674
Zr (343.823 nm)0.006554 ppm 0.000120 1.83 548.385000 0.006554
Test Report
52A112023.esws
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Page 1046 of 1261
Solution Name: MB 280-634280/1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
MB 280-634280/1-A 11/20/2023 11:55:54 PM 4:25 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000467 ppm 0.000007 1.57 608.416399 0.000467
Ag (328.068 nm)0.000174 ppm 0.000095 54.49 -19.679400 0.000174
Al (394.401 nm)0.002849 ppm 0.000048 1.70 485.252000 0.002849
Al H (396.152 nm)0.002913 u ppm 0.005891 > 100.00 63.654300 0.002913 u
As (188.980 nm)0.002242 ppm 0.000902 40.25 -1.541830 0.002242
B (249.678 nm)0.007332 ppm 0.001699 23.17 77.546300 0.007332
Ba (493.408 nm)0.000257 ppm 0.000137 53.26 38.359400 0.000257
Be (234.861 nm)0.000021 ppm 0.000017 79.41 43.510700 0.000021
Bi (223.061 nm)-0.001328 u ppm 0.000590 44.46 2.110640 -0.001328 u
Ca (315.887 nm)0.037153 ppm 0.005179 13.94 1.044262 0.037153
Cd (214.439 nm)-0.000009 u ppm 0.000235 > 100.00 -0.059134 -0.000009 u
Co (228.615 nm)-0.000047 u ppm 0.000233 > 100.00 41.944200 -0.000047 u
Cr (205.560 nm)-0.000211 u ppm 0.000169 79.82 0.652366 -0.000211 u
Cu (324.754 nm)0.000459 ppm 0.000180 39.16 787.549000 0.000459
Fe (238.204 nm)0.009405 ppm 0.001426 15.17 53.626003 0.009405
Fe H (259.940 nm)0.102484 u ppm 0.001329 1.30 27.174300 0.102484 u
K (766.491 nm)0.046550 u ppm 0.054808 > 100.00 -363.778000 0.046550 u
Li (670.783 nm)0.004744 ppm 0.003564 75.12 -4104.170000 0.004744
Mg (279.078 nm)0.007652 ppm 0.000977 12.77 34.359600 0.007652
Mn (257.610 nm)0.000436 ppm 0.000037 8.40 120.701000 0.000436
Mo (202.032 nm)0.000894 ppm 0.000741 82.87 7.913360 0.000894
Na (589.592 nm)0.234969 ppm 0.020336 8.65 3896.130000 0.234969
Na H (589.593 nm)-9.674442 u ppm 0.012968 0.13 6986.072446 -9.674442 u
Ni (231.604 nm)-0.000273 u ppm 0.000668 > 100.00 -11.138000 -0.000273 u
P (213.618 nm)-0.001538 u ppm 0.003226 > 100.00 1.254430 -0.001538 u
Pb (220.353 nm)-0.000087 u ppm 0.000676 > 100.00 -1.818890 -0.000087 u
S (181.972 nm)0.012850 ppm 0.003654 28.44 26.685859 0.012850
Sb (206.834 nm)-0.000369 u ppm 0.001339 > 100.00 1.551750 -0.000369 u
Se (196.026 nm)0.001541 u ppm 0.002883 > 100.00 5.960180 0.001541 u
Si (288.158 nm)0.078846 ppm 0.012998 16.49 1284.610000 0.078846
Sn (189.925 nm)0.000055 u ppm 0.001648 > 100.00 2.317610 0.000055 u
Sr (421.552 nm)0.000256 ppm 0.000018 6.83 66.294022 0.000256
Th (288.505 nm)0.009779 ppm 0.000724 7.40 278.831000 0.009779
Ti (336.122 nm)-0.000021 u ppm 0.000068 > 100.00 -120.360000 -0.000021 u
Tl (190.794 nm)0.001470 ppm 0.001234 83.93 -0.893400 0.001470
U (409.013 nm)0.002957 ppm 0.004977 > 100.00 36.568200 0.002957
V (292.401 nm)0.000012 u ppm 0.000253 > 100.00 -38.678800 0.000012 u
Zn (206.200 nm)-0.000949 u ppm 0.000603 63.55 2.115960 -0.000949 u
Zr (343.823 nm)-0.000142 u ppm 0.000181 > 100.00 -19.215100 -0.000142 u
Test Report
52A112023.esws
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Page 1047 of 1261
Solution Name: LCS 280-634280/2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634280/2-A 11/20/2023 11:59:57 PM 4:26 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.955954 ppm 0.003468 0.36 2452300.060068 0.955954
Ag (328.068 nm)0.052008 ppm 0.000540 1.04 2285.700000 0.052008
Al (394.401 nm)9.956030 o ppm 0.035971 0.36 122962.000000 9.956030 o
Al H (396.152 nm)9.576770 ppm 0.040471 0.42 43090.500000 9.576770
As (188.980 nm)1.021490 ppm 0.003806 0.37 845.236000 1.021490
B (249.678 nm)2.029490 ppm 0.006634 0.33 17002.300000 2.029490
Ba (493.408 nm)0.985967 ppm 0.003774 0.38 149356.000000 0.985967
Be (234.861 nm)1.028030 ppm 0.003291 0.32 171925.000000 1.028030
Bi (223.061 nm)0.001368 ppm 0.000987 72.17 6.118660 0.001368
Ca (315.887 nm)50.074840 o ppm 0.231417 0.46 33747.415700 50.074840 o
Cd (214.439 nm)0.998321 ppm 0.002866 0.29 14923.900000 0.998321
Co (228.615 nm)0.978933 ppm 0.003195 0.33 18750.000000 0.978933
Cr (205.560 nm)1.002240 ppm 0.004583 0.46 4120.960000 1.002240
Cu (324.754 nm)0.968113 ppm 0.005320 0.55 45905.400000 0.968113
Fe (238.204 nm)9.976496 o ppm 0.068156 0.68 39300.588130 9.976496 o
Fe H (259.940 nm)9.768060 ppm 0.052052 0.53 15683.200000 9.768060
K (766.491 nm)51.083700 ppm 0.324546 0.64 91332.200000 51.083700
Li (670.783 nm)0.985228 ppm 0.006910 0.70 32359.500000 0.985228
Mg (279.078 nm)51.385000 o ppm 0.166386 0.32 171870.000000 51.385000 o
Mn (257.610 nm)0.997869 ppm 0.002902 0.29 266257.000000 0.997869
Mo (202.032 nm)1.005400 ppm 0.004996 0.50 4992.340000 1.005400
Na (589.592 nm)49.122000 ppm 0.376637 0.77 609674.000000 49.122000
Na H (589.593 nm)39.252377 u ppm 0.759580 1.94 443831.487051 39.252377 u
Ni (231.604 nm)0.976658 ppm 0.002196 0.22 3316.150000 0.976658
P (213.618 nm)20.441300 o ppm 0.056764 0.28 24056.900000 20.441300 o
Pb (220.353 nm)1.059450 ppm 0.006149 0.58 2428.080000 1.059450
S (181.972 nm)18.527571 o ppm 0.074136 0.40 3801.986293 18.527571 o
Sb (206.834 nm)1.033130 ppm 0.006756 0.65 1260.360000 1.033130
Se (196.026 nm)0.994491 ppm 0.007962 0.80 614.917000 0.994491
Si (288.158 nm)9.765740 ppm 0.033056 0.34 72150.800000 9.765740
Sn (189.925 nm)0.993542 ppm 0.003387 0.34 669.927000 0.993542
Sr (421.552 nm)0.988361 ppm 0.004069 0.41 218239.163825 0.988361
Th (288.505 nm)0.073555 ppm 0.000896 1.22 374.747000 0.073555
Ti (336.122 nm)0.994405 ppm 0.002687 0.27 108500.000000 0.994405
Tl (190.794 nm)0.982536 ppm 0.005587 0.57 1061.990000 0.982536
U (409.013 nm)-0.005948 u ppm 0.005777 97.11 -24.342700 -0.005948 u
V (292.401 nm)0.997442 ppm 0.003374 0.34 41497.600000 0.997442
Zn (206.200 nm)0.996660 ppm 0.004741 0.48 2153.320000 0.996660
Zr (343.823 nm)0.991344 ppm 0.002925 0.30 80819.500000 0.991344
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 177 of 287
Page 1048 of 1261
Solution Name: 280-184226-A-1-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-A @25 11/21/2023 12:04:25 AM 4:27 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.019711 ppm 0.000070 0.36 51576.756860 0.019711
Ag (328.068 nm)0.000520 ppm 0.000113 21.75 -3.258970 0.000520
Al (394.401 nm)0.627169 ppm 0.002058 0.33 8169.140000 0.627169
Al H (396.152 nm)0.592531 u ppm 0.002829 0.48 2713.520000 0.592531 u
As (188.980 nm)0.004052 ppm 0.001616 39.89 -0.042815 0.004052
B (249.678 nm)0.102885 ppm 0.001210 1.18 877.293000 0.102885
Ba (493.408 nm)0.007632 ppm 0.000164 2.15 1156.880000 0.007632
Be (234.861 nm)0.000138 ppm 0.000018 12.84 70.424100 0.000138
Bi (223.061 nm)-0.000916 u ppm 0.002027 > 100.00 2.723400 -0.000916 u
Ca (315.887 nm)16.529924 o ppm 0.083587 0.51 11124.083868 16.529924 o
Cd (214.439 nm)0.000346 ppm 0.000300 86.45 5.376270 0.000346
Co (228.615 nm)0.000195 ppm 0.000207 > 100.00 46.776800 0.000195
Cr (205.560 nm)0.000990 ppm 0.000584 58.98 5.588730 0.000990
Cu (324.754 nm)0.001791 ppm 0.000044 2.47 839.099000 0.001791
Fe (238.204 nm)0.588049 ppm 0.003489 0.59 2331.411803 0.588049
Fe H (259.940 nm)0.656373 u ppm 0.003449 0.53 924.348000 0.656373 u
K (766.491 nm)0.607952 ppm 0.050733 8.34 644.866000 0.607952
Li (670.783 nm)0.014969 ppm 0.009492 63.41 -3723.920000 0.014969
Mg (279.078 nm)1.509390 ppm 0.007360 0.49 5057.170000 1.509390
Mn (257.610 nm)0.011147 ppm 0.000085 0.76 2978.810000 0.011147
Mo (202.032 nm)0.001763 ppm 0.000604 34.25 12.225700 0.001763
Na (589.592 nm)155.904000 o ppm 1.704460 1.09 1896160.000000 155.904000 o
Na H (589.593 nm)160.724307 ppm 6.349431 3.95 1498750.841771 160.724307
Ni (231.604 nm)0.000830 ppm 0.000461 55.51 -7.384030 0.000830
P (213.618 nm)0.045470 ppm 0.001793 3.94 56.665000 0.045470
Pb (220.353 nm)0.001293 ppm 0.000716 55.35 1.261830 0.001293
S (181.972 nm)86.539244 o ppm 0.310256 0.36 17648.023627 86.539244 o
Sb (206.834 nm)-0.002384 u ppm 0.001331 55.82 -0.876695 -0.002384 u
Se (196.026 nm)-0.001070 u ppm 0.002621 > 100.00 4.304330 -0.001070 u
Si (288.158 nm)1.199050 ppm 0.006809 0.57 9424.110000 1.199050
Sn (189.925 nm)-0.002158 u ppm 0.000914 42.38 0.831033 -0.002158 u
Sr (421.552 nm)0.321431 ppm 0.002611 0.81 70981.559448 0.321431
Th (288.505 nm)0.015319 ppm 0.001881 12.28 289.259000 0.015319
Ti (336.122 nm)0.006035 ppm 0.000164 2.72 576.539000 0.006035
Tl (190.794 nm)0.000804 u ppm 0.001720 > 100.00 -1.638230 0.000804 u
U (409.013 nm)0.003380 ppm 0.000855 25.30 38.845400 0.003380
V (292.401 nm)0.002491 ppm 0.000101 4.06 64.752200 0.002491
Zn (206.200 nm)0.003865 ppm 0.001165 30.15 12.496200 0.003865
Zr (343.823 nm)0.000476 ppm 0.000064 13.44 31.911000 0.000476
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 178 of 287
Page 1049 of 1261
Solution Name: 280-184226-A-1-A SD @125
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-A SD
@125
11/21/2023 12:08:50 AM 4:28 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.020302 ppm 0.000140 0.69 53141.749382 0.020302
Ag (328.068 nm)0.000429 ppm 0.000258 60.21 -7.303940 0.000429
Al (394.401 nm)0.766825 ppm 0.010369 1.35 9883.390000 0.766825
Al H (396.152 nm)0.733180 u ppm 0.003444 0.47 3345.620000 0.733180 u
As (188.980 nm)0.002913 ppm 0.002470 84.82 -0.990003 0.002913
B (249.678 nm)0.102909 ppm 0.000693 0.67 877.494000 0.102909
Ba (493.408 nm)0.008657 ppm 0.000301 3.47 1312.250000 0.008657
Be (234.861 nm)0.000116 ppm 0.000024 21.07 67.231000 0.000116
Bi (223.061 nm)-0.001345 u ppm 0.000958 71.21 2.085180 -0.001345 u
Ca (315.887 nm)17.007263 o ppm 0.072450 0.43 11446.010124 17.007263 o
Cd (214.439 nm)0.000184 ppm 0.000042 22.58 2.952440 0.000184
Co (228.615 nm)0.000459 ppm 0.000064 14.02 52.102600 0.000459
Cr (205.560 nm)0.001639 ppm 0.000992 60.55 8.262190 0.001639
Cu (324.754 nm)0.001577 ppm 0.000105 6.63 832.090000 0.001577
Fe (238.204 nm)0.625472 ppm 0.004613 0.74 2478.725050 0.625472
Fe H (259.940 nm)0.696662 u ppm 0.004242 0.61 989.606000 0.696662 u
K (766.491 nm)0.574940 ppm 0.092566 16.10 585.555000 0.574940
Li (670.783 nm)-0.012829 u ppm 0.051612 > 100.00 -4757.720000 -0.012829 u
Mg (279.078 nm)1.558710 ppm 0.009092 0.58 5221.730000 1.558710
Mn (257.610 nm)0.011387 ppm 0.000070 0.61 3042.800000 0.011387
Mo (202.032 nm)0.001237 ppm 0.000484 39.14 9.614740 0.001237
Na (589.592 nm)160.198000 o ppm 1.133150 0.71 1948370.000000 160.198000 o
Na H (589.593 nm)165.188455 ppm 16.8713
99 10.21 1537841.121903 165.188455
Ni (231.604 nm)0.000585 u ppm 0.000775 > 100.00 -8.217720 0.000585 u
P (213.618 nm)0.046947 ppm 0.002312 4.92 58.427000 0.046947
Pb (220.353 nm)0.001533 ppm 0.001038 67.70 1.791680 0.001533
S (181.972 nm)88.762459 o ppm 0.671879 0.76 18100.786930 88.762459 o
Sb (206.834 nm)-0.001925 u ppm 0.000900 46.76 -0.331565 -0.001925 u
Se (196.026 nm)0.000219 u ppm 0.002389 > 100.00 5.091720 0.000219 u
Si (288.158 nm)1.571850 ppm 0.018241 1.16 12134.200000 1.571850
Sn (189.925 nm)-0.001488 u ppm 0.002809 > 100.00 1.280960 -0.001488 u
Sr (421.552 nm)0.334632 ppm 0.002402 0.72 73896.160091 0.334632
Th (288.505 nm)0.017807 ppm 0.001859 10.44 293.900000 0.017807
Ti (336.122 nm)0.013362 ppm 0.000652 4.88 1377.110000 0.013362
Tl (190.794 nm)0.002268 ppm 0.001224 53.96 -0.059950 0.002268
U (409.013 nm)0.003833 ppm 0.000872 22.75 41.119100 0.003833
V (292.401 nm)0.002523 ppm 0.000187 7.42 67.458800 0.002523
Zn (206.200 nm)0.004327 ppm 0.000679 15.69 13.493200 0.004327
Zr (343.823 nm)0.000637 ppm 0.000069 10.85 45.121600 0.000637
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 179 of 287
Page 1050 of 1261
Solution Name: 280-184226-A-1-B MS @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-B MS
@25
11/21/2023 12:13:12 AM 4:29 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.061085 ppm 0.000206 0.34 157728.412610 0.061085
Ag (328.068 nm)0.002411 ppm 0.000034 1.39 78.737100 0.002411
Al (394.401 nm)1.762060 ppm 0.009808 0.56 22129.000000 1.762060
Al H (396.152 nm)1.683150 ppm 0.002197 0.13 7614.960000 1.683150
As (188.980 nm)0.042647 ppm 0.003842 9.01 32.020100 0.042647
B (249.678 nm)0.180219 ppm 0.000548 0.30 1524.560000 0.180219
Ba (493.408 nm)0.048998 ppm 0.000131 0.27 7423.400000 0.048998
Be (234.861 nm)0.040990 ppm 0.000109 0.26 6902.460000 0.040990
Bi (223.061 nm)0.000155 u ppm 0.001679 > 100.00 4.315680 0.000155 u
Ca (315.887 nm)18.502102 o ppm 0.046640 0.25 12454.158146 18.502102 o
Cd (214.439 nm)0.041203 ppm 0.000384 0.93 616.150000 0.041203
Co (228.615 nm)0.041255 ppm 0.000291 0.71 831.423000 0.041255
Cr (205.560 nm)0.041998 ppm 0.000862 2.05 174.144000 0.041998
Cu (324.754 nm)0.041988 ppm 0.000205 0.49 2717.540000 0.041988
Fe (238.204 nm)1.101042 ppm 0.004833 0.44 4351.270836 1.101042
Fe H (259.940 nm)1.161100 u ppm 0.000559 0.05 1741.890000 1.161100 u
K (766.491 nm)2.750850 ppm 0.133697 4.86 4494.910000 2.750850
Li (670.783 nm)0.000112 u ppm 0.053511 > 100.00 -4276.430000 0.000112 u
Mg (279.078 nm)3.603700 ppm 0.013505 0.37 12061.300000 3.603700
Mn (257.610 nm)0.051369 ppm 0.000162 0.32 13710.700000 0.051369
Mo (202.032 nm)0.040639 ppm 0.000587 1.44 205.133000 0.040639
Na (589.592 nm)159.145000 o ppm 3.426090 2.15 1936050.000000 159.145000 o
Na H (589.593 nm)131.298415 ppm 25.8286
38 19.67 1241509.529796 131.298415
Ni (231.604 nm)0.041929 ppm 0.000198 0.47 132.591000 0.041929
P (213.618 nm)0.867486 ppm 0.007048 0.81 1023.910000 0.867486
Pb (220.353 nm)0.042780 ppm 0.002565 6.00 96.307600 0.042780
S (181.972 nm)87.072966 o ppm 0.376174 0.43 17756.904902 87.072966 o
Sb (206.834 nm)0.039164 ppm 0.000906 2.31 49.737800 0.039164
Se (196.026 nm)0.041538 ppm 0.002214 5.33 30.424400 0.041538
Si (288.158 nm)2.016720 ppm 0.024946 1.24 15384.800000 2.016720
Sn (189.925 nm)0.038192 ppm 0.004132 10.82 27.945500 0.038192
Sr (421.552 nm)0.359328 ppm 0.000623 0.17 79349.090969 0.359328
Th (288.505 nm)0.020378 ppm 0.005472 26.85 297.659000 0.020378
Ti (336.122 nm)0.047619 ppm 0.000180 0.38 5118.540000 0.047619
Tl (190.794 nm)0.039968 ppm 0.001345 3.36 40.794300 0.039968
U (409.013 nm)0.001297 u ppm 0.001534 > 100.00 29.220900 0.001297 u
V (292.401 nm)0.043884 ppm 0.000164 0.37 1790.790000 0.043884
Zn (206.200 nm)0.046883 ppm 0.000486 1.04 105.261000 0.046883
Zr (343.823 nm)0.039450 ppm 0.000217 0.55 3209.760000 0.039450
Test Report
52A112023.esws
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Page 1051 of 1261
Solution Name: 280-184226-A-1-C MSD @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-C MSD
@25
11/21/2023 12:17:33 AM 4:30 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.062315 ppm 0.000441 0.71 160907.221577 0.062315
Ag (328.068 nm)0.002527 ppm 0.000105 4.16 82.865100 0.002527
Al (394.401 nm)1.932660 ppm 0.009888 0.51 24235.300000 1.932660
Al H (396.152 nm)1.841380 ppm 0.003926 0.21 8326.080000 1.841380
As (188.980 nm)0.044673 ppm 0.001220 2.73 33.702500 0.044673
B (249.678 nm)0.182598 ppm 0.000782 0.43 1544.470000 0.182598
Ba (493.408 nm)0.050402 ppm 0.000571 1.13 7636.250000 0.050402
Be (234.861 nm)0.041392 ppm 0.000250 0.60 6970.600000 0.041392
Bi (223.061 nm)-0.000282 u ppm 0.001870 > 100.00 3.666150 -0.000282 u
Ca (315.887 nm)18.777812 o ppm 0.090281 0.48 12640.102064 18.777812 o
Cd (214.439 nm)0.041537 ppm 0.000260 0.62 621.167000 0.041537
Co (228.615 nm)0.041800 ppm 0.000187 0.45 841.834000 0.041800
Cr (205.560 nm)0.042969 ppm 0.000492 1.15 178.144000 0.042969
Cu (324.754 nm)0.042949 ppm 0.000362 0.84 2756.970000 0.042949
Fe (238.204 nm)1.179784 ppm 0.004495 0.38 4661.238719 1.179784
Fe H (259.940 nm)1.235960 u ppm 0.004219 0.34 1863.140000 1.235960 u
K (766.491 nm)2.808020 ppm 0.048608 1.73 4597.620000 2.808020
Li (670.783 nm)0.029647 u ppm 0.034305 > 100.00 -3178.030000 0.029647 u
Mg (279.078 nm)3.699810 ppm 0.019187 0.52 12383.200000 3.699810
Mn (257.610 nm)0.052543 ppm 0.000373 0.71 14024.000000 0.052543
Mo (202.032 nm)0.039695 ppm 0.000253 0.64 200.446000 0.039695
Na (589.592 nm)160.045000 o ppm 3.955620 2.47 1947010.000000 160.045000 o
Na H (589.593 nm)158.573471 ppm 27.3152
25 17.23 1480292.657386 158.573471
Ni (231.604 nm)0.041882 ppm 0.000500 1.19 132.430000 0.041882
P (213.618 nm)0.880834 ppm 0.007484 0.85 1039.660000 0.880834
Pb (220.353 nm)0.044619 ppm 0.000865 1.94 100.521000 0.044619
S (181.972 nm)88.593834 o ppm 0.745482 0.84 18066.641832 88.593834 o
Sb (206.834 nm)0.036577 ppm 0.000695 1.90 46.598700 0.036577
Se (196.026 nm)0.040475 ppm 0.001885 4.66 29.764600 0.040475
Si (288.158 nm)2.129210 ppm 0.037465 1.76 16201.900000 2.129210
Sn (189.925 nm)0.036861 ppm 0.003943 10.70 27.050700 0.036861
Sr (421.552 nm)0.365739 ppm 0.003830 1.05 80764.707293 0.365739
Th (288.505 nm)0.020241 ppm 0.000635 3.14 297.413000 0.020241
Ti (336.122 nm)0.048267 ppm 0.000202 0.42 5189.750000 0.048267
Tl (190.794 nm)0.040807 ppm 0.000921 2.26 41.707100 0.040807
U (409.013 nm)0.002841 ppm 0.002612 91.95 35.736200 0.002841
V (292.401 nm)0.045026 ppm 0.000416 0.92 1836.300000 0.045026
Zn (206.200 nm)0.047987 ppm 0.000768 1.60 107.641000 0.047987
Zr (343.823 nm)0.038965 ppm 0.000229 0.59 3170.320000 0.038965
Test Report
52A112023.esws
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Page 1052 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 12:21:54 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000026 ppm 0.000006 21.57 999.665721 0.000026
Ag (328.068 nm)0.000352 ppm 0.000206 58.58 132.230000 0.000352
Al (394.401 nm)52.091300 o ppm 0.159007 0.31 640393.000000 52.091300 o
Al H (396.152 nm)48.746500 ppm 0.240220 0.49 219127.000000 48.746500
As (188.980 nm)0.003535 ppm 0.001774 50.20 -0.913471 0.003535
B (249.678 nm)-0.002023 u ppm 0.000136 6.72 -0.752901 -0.002023 u
Ba (493.408 nm)0.000277 ppm 0.000085 30.58 181.665000 0.000277
Be (234.861 nm)0.000093 ppm 0.000030 32.08 699.238000 0.000093
Bi (223.061 nm)-0.000681 u ppm 0.001469 > 100.00 3.072360 -0.000681 u
Ca (315.887 nm)-0.016599 u ppm 0.001975 11.90 -35.207103 -0.016599 u
Cd (214.439 nm)-0.000003 u ppm 0.000035 > 100.00 10.241700 -0.000003 u
Co (228.615 nm)0.000684 ppm 0.000245 35.81 55.909300 0.000684
Cr (205.560 nm)0.001133 ppm 0.000103 9.11 6.185770 0.001133
Cu (324.754 nm)-0.000349 u ppm 0.000138 39.71 1692.300000 -0.000349 u
Fe (238.204 nm)50.020476 o ppm 0.242050 0.48 196917.659600 50.020476 o
Fe H (259.940 nm)48.289000 ppm 0.220066 0.46 78078.300000 48.289000
K (766.491 nm)0.029182 u ppm 0.032295 > 100.00 -394.983000 0.029182 u
Li (670.783 nm)0.004909 ppm 0.001876 38.22 -4098.050000 0.004909
Mg (279.078 nm)0.003355 ppm 0.000945 28.17 -168.996000 0.003355
Mn (257.610 nm)-0.000906 u ppm 0.000028 3.04 -237.131000 -0.000906 u
Mo (202.032 nm)0.000004 u ppm 0.000491 > 100.00 3.499350 0.000004 u
Na (589.592 nm)244.417000 o ppm 0.310378 0.13 2971970.000000 244.417000 o
Na H (589.593 nm)237.150669 ppm 1.333858 0.56 2167740.424212 237.150669
Ni (231.604 nm)-0.000228 u ppm 0.000148 64.75 -10.986900 -0.000228 u
P (213.618 nm)5.008170 ppm 0.028632 0.57 5914.700000 5.008170
Pb (220.353 nm)0.001554 ppm 0.000602 38.75 0.397206 0.001554
S (181.972 nm)4.713473 ppm 0.007862 0.17 985.852897 4.713473
Sb (206.834 nm)0.000602 u ppm 0.003644 > 100.00 6.192790 0.000602 u
Se (196.026 nm)0.005251 ppm 0.002177 41.46 2.999160 0.005251
Si (288.158 nm)0.030185 ppm 0.002281 7.56 931.302000 0.030185
Sn (189.925 nm)0.000619 u ppm 0.003082 > 100.00 2.696870 0.000619 u
Sr (421.552 nm)0.000555 ppm 0.000059 10.57 132.139760 0.000555
Th (288.505 nm)4.544850 ppm 0.016353 0.36 8754.110000 4.544850
Ti (336.122 nm)0.000563 ppm 0.000033 5.87 -56.615800 0.000563
Tl (190.794 nm)-0.003379 u ppm 0.001722 50.95 -7.055260 -0.003379 u
U (409.013 nm)2.372670 Q ppm 0.008731 0.37 10600.200000 Q 2.372670 Q
V (292.401 nm)0.000689 ppm 0.000058 8.40 271.380000 0.000689
Zn (206.200 nm)0.002116 ppm 0.000152 7.16 8.725030 0.002116
Zr (343.823 nm)-0.000561 u ppm 0.000146 26.11 14.253200 -0.000561 u
Test Report
52A112023.esws
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Page 1053 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 12:26:22 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.448359 Q ppm 0.000265 0.06 1149698.753862
Q 0.448359 Q
Ag (328.068 nm)0.501792 ppm 0.007370 1.47 26801.100000 0.501792
Al (394.401 nm)0.492819 ppm 0.000480 0.10 6519.560000 0.492819
Al H (396.152 nm)0.500820 u ppm 0.003570 0.71 2301.350000 0.500820 u
As (188.980 nm)0.502915 ppm 0.003710 0.74 414.434000 0.502915
B (249.678 nm)0.494846 ppm 0.001029 0.21 4157.870000 0.494846
Ba (493.408 nm)0.497388 ppm 0.001996 0.40 75337.800000 0.497388
Be (234.861 nm)0.513871 ppm 0.003517 0.68 85926.400000 0.513871
Bi (223.061 nm)0.993187 ppm 0.002369 0.24 1480.740000 0.993187
Ca (315.887 nm)4.966599 ppm 0.026587 0.54 3325.556568 4.966599
Cd (214.439 nm)0.508780 ppm 0.000497 0.10 7605.250000 0.508780
Co (228.615 nm)0.505354 ppm 0.000982 0.19 9699.470000 0.505354
Cr (205.560 nm)0.511700 ppm 0.000292 0.06 2104.740000 0.511700
Cu (324.754 nm)0.500344 ppm 0.000681 0.14 24100.400000 0.500344
Fe (238.204 nm)2.493983 ppm 0.004970 0.20 9840.273867 2.493983
Fe H (259.940 nm)2.503470 u ppm 0.018347 0.73 3916.230000 2.503470 u
K (766.491 nm)50.471100 ppm 0.216330 0.43 90231.600000 50.471100
Li (670.783 nm)0.495745 ppm 0.001340 0.27 14155.900000 0.495745
Mg (279.078 nm)20.254100 ppm 0.022400 0.11 67751.900000 20.254100
Mn (257.610 nm)0.496846 ppm 0.000334 0.07 132573.000000 0.496846
Mo (202.032 nm)0.501933 ppm 0.001072 0.21 2494.110000 0.501933
Na (589.592 nm)24.681600 ppm 0.125583 0.51 306873.000000 24.681600
Na H (589.593 nm)14.441924 u ppm 0.188865 1.31 222408.214338 14.441924 u
Ni (231.604 nm)0.514041 ppm 0.000686 0.13 1740.530000 0.514041
P (213.618 nm)0.008356 ppm 0.003909 46.78 -27.426000 0.008356
Pb (220.353 nm)0.534414 ppm 0.000746 0.14 1224.490000 0.534414
S (181.972 nm)-0.025943 u ppm 0.005828 22.47 21.268162 -0.025943 u
Sb (206.834 nm)0.489579 ppm 0.005531 1.13 598.184000 0.489579
Se (196.026 nm)0.501479 ppm 0.008238 1.64 312.824000 0.501479
Si (288.158 nm)4.947510 ppm 0.019736 0.40 36902.400000 4.947510
Sn (189.925 nm)0.500790 ppm 0.002414 0.48 338.805000 0.500790
Sr (421.552 nm)0.498709 ppm 0.002417 0.48 110124.344261 0.498709
Th (288.505 nm)0.041503 ppm 0.002776 6.69 326.233000 0.041503
Ti (336.122 nm)0.498612 ppm 0.000342 0.07 54300.800000 0.498612
Tl (190.794 nm)0.501352 ppm 0.002893 0.58 540.777000 0.501352
U (409.013 nm)-0.008685 u ppm 0.002376 27.36 -28.311000 -0.008685 u
V (292.401 nm)0.499358 ppm 0.000728 0.15 20751.400000 0.499358
Zn (206.200 nm)0.508362 ppm 0.001078 0.21 1100.380000 0.508362
Zr (343.823 nm)0.494077 ppm 0.000457 0.09 40272.600000 0.494077
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 183 of 287
Page 1054 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 12:30:43 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000462 ppm 0.000003 0.62 592.335465 0.000462
Ag (328.068 nm)0.000062 u ppm 0.000287 > 100.00 -25.723400 0.000062 u
Al (394.401 nm)-0.000172 u ppm 0.000509 > 100.00 447.504000 -0.000172 u
Al H (396.152 nm)0.001490 u ppm 0.003744 > 100.00 57.259200 0.001490 u
As (188.980 nm)0.000773 u ppm 0.001275 > 100.00 -2.762180 0.000773 u
B (249.678 nm)0.000440 u ppm 0.000819 > 100.00 19.861800 0.000440 u
Ba (493.408 nm)0.000128 u ppm 0.000182 > 100.00 18.728800 0.000128 u
Be (234.861 nm)0.000022 u ppm 0.000025 > 100.00 43.480500 0.000022 u
Bi (223.061 nm)-0.001707 u ppm 0.000605 35.44 1.547000 -0.001707 u
Ca (315.887 nm)0.007805 ppm 0.004555 58.37 -18.748869 0.007805
Cd (214.439 nm)0.000117 ppm 0.000056 47.32 1.832160 0.000117
Co (228.615 nm)0.000026 ppm 0.000019 70.98 43.345200 0.000026
Cr (205.560 nm)-0.000226 u ppm 0.000226 99.90 0.590798 -0.000226 u
Cu (324.754 nm)0.000390 ppm 0.000237 60.79 784.693000 0.000390
Fe (238.204 nm)0.001195 ppm 0.000708 59.30 21.308561 0.001195
Fe H (259.940 nm)0.094790 u ppm 0.002090 2.21 14.712100 0.094790 u
K (766.491 nm)-0.024169 u ppm 0.005195 21.49 -490.835000 -0.024169 u
Li (670.783 nm)0.004910 S ppm 0.003859 78.59 -4097.990000 S 0.004910 S
Mg (279.078 nm)0.000171 u ppm 0.000693 > 100.00 9.376650 0.000171 u
Mn (257.610 nm)-0.000015 u ppm 0.000010 68.56 0.477407 -0.000015 u
Mo (202.032 nm)0.000672 ppm 0.000313 46.60 6.813530 0.000672
Na (589.592 nm)0.066709 ppm 0.010203 15.29 1848.290000 0.066709
Na H (589.593 nm)-9.997690 u ppm 0.023826 0.24 4154.369276 -9.997690 u
Ni (231.604 nm)-0.000049 u ppm 0.000835 > 100.00 -10.376700 -0.000049 u
P (213.618 nm)-0.000705 u ppm 0.002230 > 100.00 2.242280 -0.000705 u
Pb (220.353 nm)0.000453 u ppm 0.003247 > 100.00 -0.583273 0.000453 u
S (181.972 nm)-0.031388 u ppm 0.011247 35.83 17.675612 -0.031388 u
Sb (206.834 nm)-0.003171 u ppm 0.001560 49.19 -1.863390 -0.003171 u
Se (196.026 nm)-0.000484 u ppm 0.001606 > 100.00 4.718360 -0.000484 u
Si (288.158 nm)0.000858 u ppm 0.001219 > 100.00 718.253000 0.000858 u
Sn (189.925 nm)0.001032 ppm 0.000511 49.53 2.974540 0.001032
Sr (421.552 nm)0.000144 ppm 0.000043 29.65 41.477969 0.000144
Th (288.505 nm)0.012266 Z ppm 0.000495 4.04 283.432000 Z 0.012266 Z
Ti (336.122 nm)-0.000052 u ppm 0.000028 53.36 -123.721000 -0.000052 u
Tl (190.794 nm)0.002204 ppm 0.000605 27.43 -0.096037 0.002204
U (409.013 nm)0.000430 u ppm 0.003592 > 100.00 25.426600 0.000430 u
V (292.401 nm)-0.000032 u ppm 0.000057 > 100.00 -40.255800 -0.000032 u
Zn (206.200 nm)-0.001276 u ppm 0.000379 29.71 1.411420 -0.001276 u
Zr (343.823 nm)0.000074 u ppm 0.000102 > 100.00 -1.644100 0.000074 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 184 of 287
Page 1055 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 12:34:45 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014130 ppm 0.000028 0.20 35734.906392 0.014130
Ag (328.068 nm)0.009920 ppm 0.000032 0.33 499.103000 0.009920
Al (394.401 nm)0.087902 ppm 0.000775 0.88 1542.130000 0.087902
Al H (396.152 nm)0.090798 u ppm 0.002065 2.27 458.629000 0.090798 u
As (188.980 nm)0.013535 ppm 0.001670 12.34 7.840760 0.013535
B (249.678 nm)0.095301 ppm 0.000570 0.60 813.818000 0.095301
Ba (493.408 nm)0.009623 ppm 0.000150 1.56 1457.160000 0.009623
Be (234.861 nm)0.000985 ppm 0.000012 1.22 205.754000 0.000985
Bi (223.061 nm)-0.000434 Qu ppm 0.001212 > 100.00 3.439240 Q -0.000434 Qu
Ca (315.887 nm)0.204168 ppm 0.001914 0.94 113.681979 0.204168
Cd (214.439 nm)0.005250 ppm 0.000129 2.46 78.572000 0.005250
Co (228.615 nm)0.010044 ppm 0.000112 1.12 234.721000 0.010044
Cr (205.560 nm)0.009593 ppm 0.000244 2.55 40.885300 0.009593
Cu (324.754 nm)0.014813 ppm 0.000199 1.34 1450.460000 0.014813
Fe (238.204 nm)0.098564 ppm 0.000421 0.43 404.658804 0.098564
Fe H (259.940 nm)0.188541 u ppm 0.002909 1.54 166.567000 0.188541 u
K (766.491 nm)2.971500 ppm 0.005733 0.19 4891.330000 2.971500
Li (670.783 nm)0.027125 Q ppm 0.001346 4.96 -3271.820000 Q 0.027125 Q
Mg (279.078 nm)0.198245 ppm 0.001185 0.60 671.331000 0.198245
Mn (257.610 nm)0.010027 ppm 0.000032 0.32 2680.010000 0.010027
Mo (202.032 nm)0.020353 ppm 0.000516 2.54 104.470000 0.020353
Na (589.592 nm)1.041390 ppm 0.022319 2.14 13808.000000 1.041390
Na H (589.593 nm)-9.065538 u ppm 0.011381 0.13 12397.492910 -9.065538 u
Ni (231.604 nm)0.041389 ppm 0.001623 3.92 130.733000 0.041389
P (213.618 nm)2.804400 ppm 0.006587 0.23 3312.650000 2.804400
Pb (220.353 nm)0.009004 ppm 0.001019 11.32 19.099400 0.009004
S (181.972 nm)0.051828 Q ppm 0.006899 13.31 34.689998 Q 0.051828 Q
Sb (206.834 nm)0.018769 ppm 0.001969 10.49 24.794400 0.018769
Se (196.026 nm)0.020573 ppm 0.001444 7.02 17.636400 0.020573
Si (288.158 nm)0.460809 ppm 0.004224 0.92 4090.060000 0.460809
Sn (189.925 nm)0.098663 ppm 0.000923 0.94 68.581000 0.098663
Sr (421.552 nm)0.009559 ppm 0.000133 1.39 2120.234631 0.009559
Th (288.505 nm)0.008884 Q ppm 0.001850 20.82 277.229000 Q 0.008884 Q
Ti (336.122 nm)0.009403 ppm 0.000099 1.06 908.300000 0.009403
Tl (190.794 nm)0.016659 ppm 0.000417 2.50 15.554200 0.016659
U (409.013 nm)0.051990 ppm 0.001139 2.19 252.086000 0.051990
V (292.401 nm)0.009638 ppm 0.000123 1.28 357.260000 0.009638
Zn (206.200 nm)0.019457 ppm 0.000710 3.65 46.119200 0.019457
Zr (343.823 nm)0.009743 ppm 0.000027 0.28 786.752000 0.009743
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 185 of 287
Page 1056 of 1261
Solution Name: 280-184226-A-1-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-A @25 11/21/2023 12:39:04 AM 4:31 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.122773 ppm 0.000260 0.21 316311.820433 0.122773
Ag (328.068 nm)0.050619 ppm 0.000137 0.27 2670.320000 0.050619
Al (394.401 nm)1.643110 ppm 0.003552 0.22 20666.500000 1.643110
Al H (396.152 nm)1.533370 ppm 0.012673 0.83 6941.820000 1.533370
As (188.980 nm)0.204918 ppm 0.002771 1.35 166.844000 0.204918
B (249.678 nm)0.201774 ppm 0.000458 0.23 1704.960000 0.201774
Ba (493.408 nm)0.104069 ppm 0.000554 0.53 15765.500000 0.104069
Be (234.861 nm)0.051320 ppm 0.000693 1.35 8634.360000 0.051320
Bi (223.061 nm)-0.000343 u ppm 0.001838 > 100.00 3.574620 -0.000343 u
Ca (315.887 nm)36.482816 o ppm 0.197150 0.54 24580.694817 36.482816 o
Cd (214.439 nm)0.051019 ppm 0.000224 0.44 762.972000 0.051019
Co (228.615 nm)0.051190 ppm 0.000089 0.17 1021.190000 0.051190
Cr (205.560 nm)0.051083 ppm 0.000107 0.21 211.480000 0.051083
Cu (324.754 nm)0.051962 ppm 0.000319 0.61 3182.940000 0.051962
Fe (238.204 nm)1.582084 ppm 0.013838 0.87 6244.977130 1.582084
Fe H (259.940 nm)1.625720 u ppm 0.005628 0.35 2494.460000 1.625720 u
K (766.491 nm)20.954500 ppm 0.095351 0.46 37200.500000 20.954500
Li (670.783 nm)0.121322 ppm 0.002502 2.06 231.290000 0.121322
Mg (279.078 nm)21.672700 ppm 0.048123 0.22 72484.000000 21.672700
Mn (257.610 nm)0.061116 ppm 0.000128 0.21 16311.400000 0.061116
Mo (202.032 nm)0.051038 ppm 0.000404 0.79 256.732000 0.051038
Na (589.592 nm)173.755000 o ppm 0.528968 0.30 2114270.000000 173.755000 o
Na H (589.593 nm)191.357983 ppm 3.035347 1.59 1767759.465371 191.357983
Ni (231.604 nm)0.050077 ppm 0.000394 0.79 160.451000 0.050077
P (213.618 nm)2.093210 ppm 0.003335 0.16 2470.150000 2.093210
Pb (220.353 nm)0.105472 ppm 0.001956 1.85 241.216000 0.105472
S (181.972 nm)87.438943 o ppm 0.309309 0.35 17832.248607 87.438943 o
Sb (206.834 nm)0.101201 ppm 0.001643 1.62 125.362000 0.101201
Se (196.026 nm)0.196234 ppm 0.005411 2.76 125.312000 0.196234
Si (288.158 nm)6.065820 ppm 0.021826 0.36 44811.300000 6.065820
Sn (189.925 nm)0.058403 ppm 0.001388 2.38 41.527000 0.058403
Sr (421.552 nm)0.373560 ppm 0.002051 0.55 82491.637923 0.373560
Th (288.505 nm)0.211349 ppm 0.002640 1.25 657.336000 0.211349
Ti (336.122 nm)0.056143 ppm 0.000041 0.07 6088.080000 0.056143
Tl (190.794 nm)0.191419 ppm 0.000293 0.15 205.233000 0.191419
U (409.013 nm)0.472390 ppm 0.001585 0.34 2107.550000 0.472390
V (292.401 nm)0.052646 ppm 0.000193 0.37 2144.690000 0.052646
Zn (206.200 nm)0.210156 ppm 0.000486 0.23 457.336000 0.210156
Zr (343.823 nm)0.051102 ppm 0.000033 0.06 4160.280000 0.051102
Test Report
52A112023.esws
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Page 1057 of 1261
Solution Name: 280-184226-A-2-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-2-A @25 11/21/2023 12:43:28 AM 4:32 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.055424 b ppm 0.000700 1.26 144636.732943 0.055424 b
Ag (328.068 nm)0.000404 ppm 0.000133 32.89 -6.495130 0.000404
Al (394.401 nm)0.295399 ppm 0.003685 1.25 4080.610000 0.295399
Al H (396.152 nm)0.265812 u ppm 0.004762 1.79 1245.180000 0.265812 u
As (188.980 nm)0.004010 ppm 0.003147 78.48 -0.073407 0.004010
B (249.678 nm)0.092087 ppm 0.001835 1.99 786.916000 0.092087
Ba (493.408 nm)0.000501 ppm 0.000306 60.95 75.696300 0.000501
Be (234.861 nm)0.000123 ppm 0.000020 16.59 61.930200 0.000123
Bi (223.061 nm)0.001133 u ppm 0.003868 > 100.00 5.769990 0.001133 u
Ca (315.887 nm)13.599212 o ppm 0.037587 0.28 9147.555579 13.599212 o
Cd (214.439 nm)0.000442 ppm 0.000033 7.42 6.705820 0.000442
Co (228.615 nm)0.005173 ppm 0.000305 5.89 141.492000 0.005173
Cr (205.560 nm)0.000343 u ppm 0.000382 > 100.00 2.893510 0.000343 u
Cu (324.754 nm)0.002426 ppm 0.000037 1.54 874.472000 0.002426
Fe (238.204 nm)0.124256 ppm 0.001110 0.89 505.738541 0.124256
Fe H (259.940 nm)0.211914 u ppm 0.003312 1.56 204.427000 0.211914 u
K (766.491 nm)0.813055 ppm 0.160752 19.77 1013.360000 0.813055
Li (670.783 nm)0.014219 u ppm 0.049278 > 100.00 -3751.820000 0.014219 u
Mg (279.078 nm)27.340100 ppm 0.296057 1.08 91452.900000 27.340100
Mn (257.610 nm)0.151673 ppm 0.001664 1.10 40474.100000 0.151673
Mo (202.032 nm)0.000972 ppm 0.000254 26.14 8.298930 0.000972
Na (589.592 nm)261.667000 o ppm 7.932610 3.03 3181640.000000 261.667000 o
Na H (589.593 nm)255.958361 ppm 33.8081
34 13.21 2332384.341236 255.958361
Ni (231.604 nm)0.032117 ppm 0.000629 1.96 99.151600 0.032117
P (213.618 nm)0.007880 ppm 0.000813 10.32 12.263200 0.007880
Pb (220.353 nm)0.000229 u ppm 0.001040 > 100.00 -1.153930 0.000229 u
S (181.972 nm)159.726977 bo ppm 2.066565 1.29 32552.692067 159.726977 bo
Sb (206.834 nm)-0.002522 u ppm 0.001974 78.26 -1.060510 -0.002522 u
Se (196.026 nm)0.015580 ppm 0.005039 32.34 14.664100 0.015580
Si (288.158 nm)0.208805 ppm 0.001428 0.68 2228.490000 0.208805
Sn (189.925 nm)-0.000870 u ppm 0.000283 32.60 1.696550 -0.000870 u
Sr (421.552 nm)0.243471 ppm 0.003418 1.40 53768.000429 0.243471
Th (288.505 nm)0.037606 ppm 0.000210 0.56 334.283000 0.037606
Ti (336.122 nm)-0.000130 u ppm 0.000040 30.95 -102.598000 -0.000130 u
Tl (190.794 nm)0.001094 ppm 0.001059 96.77 -1.293270 0.001094
U (409.013 nm)-0.003032 u ppm 0.005350 > 100.00 10.456200 -0.003032 u
V (292.401 nm)0.000292 ppm 0.000038 13.05 -25.326700 0.000292
Zn (206.200 nm)0.030225 ppm 0.000845 2.80 69.338800 0.030225
Zr (343.823 nm)0.000558 ppm 0.000033 5.85 37.966300 0.000558
Test Report
52A112023.esws
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Page 1058 of 1261
Solution Name: 280-184226-A-3-A @10
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-3-A @10 11/21/2023 12:47:52 AM 4:33 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.398104 b ppm 0.004476 1.12 1029667.165623 0.398104 b
Ag (328.068 nm)0.000999 ppm 0.000375 37.49 27.061800 0.000999
Al (394.401 nm)6.208880 o ppm 0.070784 1.14 76834.000000 6.208880 o
Al H (396.152 nm)5.662970 ppm 0.013453 0.24 25501.100000 5.662970
As (188.980 nm)0.004072 ppm 0.001479 36.33 -0.022288 0.004072
B (249.678 nm)0.205364 ppm 0.001827 0.89 1735.010000 0.205364
Ba (493.408 nm)0.002095 ppm 0.000164 7.83 316.988000 0.002095
Be (234.861 nm)0.002177 ppm 0.000020 0.93 404.755000 0.002177
Bi (223.061 nm)0.001932 ppm 0.002088 > 100.00 6.957460 0.001932
Ca (315.887 nm)40.000895 o ppm 0.129590 0.32 26953.354780 40.000895 o
Cd (214.439 nm)0.003100 ppm 0.000102 3.28 46.433300 0.003100
Co (228.615 nm)0.029965 ppm 0.000333 1.11 614.256000 0.029965
Cr (205.560 nm)0.000848 ppm 0.000685 80.78 4.867010 0.000848
Cu (324.754 nm)0.001911 ppm 0.000209 10.93 845.475000 0.001911
Fe (238.204 nm)0.087408 ppm 0.001148 1.31 360.730159 0.087408
Fe H (259.940 nm)0.173138 u ppm 0.003315 1.91 141.619000 0.173138 u
K (766.491 nm)1.629390 ppm 0.019937 1.22 2480.030000 1.629390
Li (670.783 nm)0.328254 ppm 0.026161 7.97 7926.980000 0.328254
Mg (279.078 nm)155.188000 o ppm 0.990827 0.64 519064.000000 155.188000 o
Mn (257.610 nm)0.748506 ppm 0.007670 1.02 199722.000000 0.748506
Mo (202.032 nm)0.000626 ppm 0.000673 > 100.00 6.584320 0.000626
Na (589.592 nm)553.522000 o ppm 18.4686
00 3.34 6729220.000000 553.522000 o
Na H (589.593 nm)690.553185 ppm 58.3303
28 8.45 6136916.980566 690.553185
Ni (231.604 nm)0.137289 ppm 0.001818 1.32 457.274000 0.137289
P (213.618 nm)0.093675 ppm 0.003958 4.22 113.559000 0.093675
Pb (220.353 nm)0.004032 ppm 0.001247 30.94 6.897340 0.004032
S (181.972 nm)485.577752 bo ppm 5.693044 1.17 98912.880094 485.577752 bo
Sb (206.834 nm)-0.002083 u ppm 0.000833 40.02 -0.521121 -0.002083 u
Se (196.026 nm)0.012539 ppm 0.003521 28.08 13.196900 0.012539
Si (288.158 nm)1.099840 ppm 0.010448 0.95 8703.170000 1.099840
Sn (189.925 nm)0.000661 u ppm 0.001930 > 100.00 2.725140 0.000661 u
Sr (421.552 nm)0.415607 ppm 0.009760 2.35 91775.505660 0.415607
Th (288.505 nm)0.070361 ppm 0.002389 3.40 409.794000 0.070361
Ti (336.122 nm)0.000088 ppm 0.000064 72.35 -20.876800 0.000088
Tl (190.794 nm)0.001777 u ppm 0.001600 90.03 -0.501355 0.001777 u
U (409.013 nm)-0.006609 u ppm 0.005402 81.73 -4.552630 -0.006609 u
V (292.401 nm)0.000900 ppm 0.000337 37.44 4.501500 0.000900
Zn (206.200 nm)0.248909 ppm 0.004299 1.73 540.901000 0.248909
Zr (343.823 nm)0.001009 ppm 0.000116 11.47 74.693000 0.001009
Test Report
52A112023.esws
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Page 1059 of 1261
Solution Name: 280-184226-A-4-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-4-A @25 11/21/2023 12:52:15 AM 4:34 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.169679 b ppm 0.000963 0.57 437631.376308 0.169679 b
Ag (328.068 nm)0.000449 ppm 0.000111 24.76 -4.041380 0.000449
Al (394.401 nm)0.348515 ppm 0.001097 0.31 4728.400000 0.348515
Al H (396.152 nm)0.321184 u ppm 0.003566 1.11 1494.030000 0.321184 u
As (188.980 nm)0.000713 u ppm 0.002558 > 100.00 -2.814290 0.000713 u
B (249.678 nm)0.099344 ppm 0.000197 0.20 847.659000 0.099344
Ba (493.408 nm)0.003841 ppm 0.000284 7.39 581.801000 0.003841
Be (234.861 nm)0.000138 ppm 0.000035 24.94 65.782100 0.000138
Bi (223.061 nm)0.000475 u ppm 0.001468 > 100.00 4.791550 0.000475 u
Ca (315.887 nm)17.203732 o ppm 0.108319 0.63 11578.512669 17.203732 o
Cd (214.439 nm)0.000187 ppm 0.000067 35.94 2.912860 0.000187
Co (228.615 nm)0.000920 ppm 0.000129 14.00 60.531200 0.000920
Cr (205.560 nm)0.000498 ppm 0.000372 74.58 3.556830 0.000498
Cu (324.754 nm)0.001255 ppm 0.000044 3.48 822.334000 0.001255
Fe (238.204 nm)0.218202 ppm 0.000610 0.28 875.546306 0.218202
Fe H (259.940 nm)0.302499 u ppm 0.001487 0.49 351.154000 0.302499 u
K (766.491 nm)0.575894 ppm 0.068937 11.97 587.270000 0.575894
Li (670.783 nm)0.133267 ppm 0.039827 29.89 675.535000 0.133267
Mg (279.078 nm)42.024500 ppm 0.237889 0.57 140567.000000 42.024500
Mn (257.610 nm)0.060868 ppm 0.000336 0.55 16245.400000 0.060868
Mo (202.032 nm)0.000405 ppm 0.000275 67.95 5.485570 0.000405
Na (589.592 nm)184.623000 o ppm 3.557100 1.93 2245200.000000 184.623000 o
Na H (589.593 nm)187.720065 ppm 21.4799
52 11.44 1735043.698105 187.720065
Ni (231.604 nm)0.011912 ppm 0.000551 4.63 30.350500 0.011912
P (213.618 nm)0.010389 ppm 0.001749 16.84 15.292200 0.010389
Pb (220.353 nm)-0.000104 u ppm 0.000973 > 100.00 -1.915850 -0.000104 u
S (181.972 nm)171.664078 bo ppm 1.082369 0.63 34983.635291 171.664078 bo
Sb (206.834 nm)-0.000897 u ppm 0.001425 > 100.00 0.921848 -0.000897 u
Se (196.026 nm)0.009510 ppm 0.000709 7.45 10.868700 0.009510
Si (288.158 nm)0.708465 ppm 0.003311 0.47 5859.470000 0.708465
Sn (189.925 nm)-0.001406 u ppm 0.001086 77.27 1.336160 -0.001406 u
Sr (421.552 nm)0.265895 ppm 0.002636 0.99 58719.118227 0.265895
Th (288.505 nm)0.040334 ppm 0.003153 7.82 337.770000 0.040334
Ti (336.122 nm)0.003835 ppm 0.000094 2.46 337.994000 0.003835
Tl (190.794 nm)0.000462 u ppm 0.001958 > 100.00 -1.994670 0.000462 u
U (409.013 nm)0.000747 u ppm 0.005821 > 100.00 27.551500 0.000747 u
V (292.401 nm)0.000720 ppm 0.000142 19.68 -5.703380 0.000720
Zn (206.200 nm)0.007820 ppm 0.000897 11.47 21.025900 0.007820
Zr (343.823 nm)0.000491 ppm 0.000043 8.69 32.675000 0.000491
Test Report
52A112023.esws
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Page 1060 of 1261
Solution Name: 280-184226-A-5-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-5-A @25 11/21/2023 12:56:36 AM 4:35 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.205125 b ppm 0.001806 0.88 530356.634128 0.205125 b
Ag (328.068 nm)0.000544 ppm 0.000083 15.30 1.747500 0.000544
Al (394.401 nm)0.311899 ppm 0.002408 0.77 4273.790000 0.311899
Al H (396.152 nm)0.280060 u ppm 0.000961 0.34 1309.210000 0.280060 u
As (188.980 nm)0.001651 ppm 0.001466 88.78 -2.034890 0.001651
B (249.678 nm)0.086851 ppm 0.000853 0.98 743.092000 0.086851
Ba (493.408 nm)0.001568 ppm 0.000145 9.22 237.636000 0.001568
Be (234.861 nm)0.000172 ppm 0.000026 15.41 71.728800 0.000172
Bi (223.061 nm)-0.001672 u ppm 0.002115 > 100.00 1.598680 -0.001672 u
Ca (315.887 nm)15.204512 o ppm 0.077282 0.51 10230.200882 15.204512 o
Cd (214.439 nm)0.000400 ppm 0.000303 75.78 6.112050 0.000400
Co (228.615 nm)0.000339 ppm 0.000146 43.06 49.369600 0.000339
Cr (205.560 nm)0.000326 ppm 0.000277 85.21 2.850890 0.000326
Cu (324.754 nm)0.001595 ppm 0.000099 6.22 842.598000 0.001595
Fe (238.204 nm)0.248181 ppm 0.001160 0.47 993.562673 0.248181
Fe H (259.940 nm)0.331084 u ppm 0.001750 0.53 397.455000 0.331084 u
K (766.491 nm)0.747289 ppm 0.043192 5.78 895.206000 0.747289
Li (670.783 nm)0.168919 ppm 0.019132 11.33 2001.400000 0.168919
Mg (279.078 nm)73.103600 o ppm 0.547524 0.75 244517.000000 73.103600 o
Mn (257.610 nm)0.011069 ppm 0.000074 0.66 2957.780000 0.011069
Mo (202.032 nm)0.002293 ppm 0.000708 30.89 14.855400 0.002293
Na (589.592 nm)276.226000 o ppm 8.484190 3.07 3358630.000000 276.226000 o
Na H (589.593 nm)219.955731 ppm 35.3060
52 16.05 2017221.431669 219.955731
Ni (231.604 nm)0.001649 ppm 0.000694 42.07 -4.596160 0.001649
P (213.618 nm)0.023242 ppm 0.002925 12.58 30.377400 0.023242
Pb (220.353 nm)0.001756 ppm 0.001596 90.90 2.363390 0.001756
S (181.972 nm)262.430383 bo ppm 2.553935 0.97 53467.970927 262.430383 bo
Sb (206.834 nm)-0.004900 u ppm 0.004049 82.63 -3.962550 -0.004900 u
Se (196.026 nm)0.006857 ppm 0.004514 65.83 9.204530 0.006857
Si (288.158 nm)0.500976 ppm 0.001653 0.33 4351.960000 0.500976
Sn (189.925 nm)0.000452 u ppm 0.001515 > 100.00 2.584490 0.000452 u
Sr (421.552 nm)0.360397 ppm 0.001044 0.29 79585.106114 0.360397
Th (288.505 nm)0.053938 ppm 0.000823 1.53 362.758000 0.053938
Ti (336.122 nm)0.001501 ppm 0.000087 5.80 78.903200 0.001501
Tl (190.794 nm)0.000546 u ppm 0.002985 > 100.00 -1.906490 0.000546 u
U (409.013 nm)0.005034 ppm 0.004140 82.25 46.700000 0.005034
V (292.401 nm)0.000499 ppm 0.000160 32.05 -13.671300 0.000499
Zn (206.200 nm)0.005088 ppm 0.001391 27.33 15.134600 0.005088
Zr (343.823 nm)0.000395 ppm 0.000028 7.02 24.875600 0.000395
Test Report
52A112023.esws
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Page 1061 of 1261
Solution Name: 280-184226-A-6-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-6-A @25 11/21/2023 1:00:59 AM 4:36 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.118765 b ppm 0.000767 0.65 307276.958401 0.118765 b
Ag (328.068 nm)0.000321 ppm 0.000225 70.31 -11.251500 0.000321
Al (394.401 nm)0.081127 ppm 0.001263 1.56 1444.920000 0.081127
Al H (396.152 nm)0.070064 u ppm 0.003590 5.12 365.447000 0.070064 u
As (188.980 nm)0.001080 u ppm 0.001640 > 100.00 -2.508400 0.001080 u
B (249.678 nm)0.050746 ppm 0.000434 0.85 440.908000 0.050746
Ba (493.408 nm)0.002022 ppm 0.000132 6.53 305.909000 0.002022
Be (234.861 nm)0.000086 ppm 0.000022 25.63 55.692500 0.000086
Bi (223.061 nm)0.000621 u ppm 0.002686 > 100.00 5.008650 0.000621 u
Ca (315.887 nm)12.557022 o ppm 0.049113 0.39 8444.683004 12.557022 o
Cd (214.439 nm)0.000111 ppm 0.000090 80.79 1.762460 0.000111
Co (228.615 nm)0.000342 ppm 0.000133 39.00 49.418100 0.000342
Cr (205.560 nm)0.000536 ppm 0.000289 53.81 3.721970 0.000536
Cu (324.754 nm)0.001512 ppm 0.000073 4.85 831.940000 0.001512
Fe (238.204 nm)0.113610 ppm 0.002176 1.92 463.829216 0.113610
Fe H (259.940 nm)0.202601 u ppm 0.003948 1.95 189.341000 0.202601 u
K (766.491 nm)1.101880 ppm 0.074978 6.80 1532.290000 1.101880
Li (670.783 nm)0.079914 ppm 0.030282 37.89 -1308.660000 0.079914
Mg (279.078 nm)37.529500 ppm 0.203117 0.54 125533.000000 37.529500
Mn (257.610 nm)0.002623 ppm 0.000007 0.25 704.380000 0.002623
Mo (202.032 nm)0.001223 ppm 0.000239 19.52 9.544590 0.001223
Na (589.592 nm)220.771000 o ppm 4.398520 1.99 2684570.000000 220.771000 o
Na H (589.593 nm)194.638260 ppm 45.2977
43 23.27 1795590.370523 194.638260
Ni (231.604 nm)0.002253 ppm 0.000672 29.84 -2.539370 0.002253
P (213.618 nm)0.006123 ppm 0.004373 71.41 10.210200 0.006123
Pb (220.353 nm)0.001432 ppm 0.000216 15.09 1.661000 0.001432
S (181.972 nm)175.579694 bo ppm 1.126819 0.64 35780.894238 175.579694 bo
Sb (206.834 nm)-0.004120 u ppm 0.000879 21.33 -3.011510 -0.004120 u
Se (196.026 nm)0.013114 ppm 0.008012 61.10 13.052700 0.013114
Si (288.158 nm)0.259491 ppm 0.001808 0.70 2596.860000 0.259491
Sn (189.925 nm)-0.001596 u ppm 0.002479 > 100.00 1.208230 -0.001596 u
Sr (421.552 nm)0.586261 ppm 0.005296 0.90 129455.758841 0.586261
Th (288.505 nm)0.039145 ppm 0.002704 6.91 334.373000 0.039145
Ti (336.122 nm)0.001373 ppm 0.000055 3.99 59.124100 0.001373
Tl (190.794 nm)-0.001051 u ppm 0.000616 58.64 -3.634370 -0.001051 u
U (409.013 nm)0.010842 ppm 0.003449 31.81 71.583500 0.010842
V (292.401 nm)0.000444 ppm 0.000170 38.36 -19.682700 0.000444
Zn (206.200 nm)0.002608 ppm 0.000918 35.21 9.787360 0.002608
Zr (343.823 nm)0.000269 ppm 0.000045 16.61 14.418600 0.000269
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 191 of 287
Page 1062 of 1261
Solution Name: 280-184226-A-9-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-9-A @25 11/21/2023 1:05:19 AM 4:37 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.204532 b ppm 0.001400 0.68 533782.893435 0.204532 b
Ag (328.068 nm)0.000989 ppm 0.000044 4.40 24.127500 0.000989
Al (394.401 nm)0.784572 ppm 0.004819 0.61 10096.000000 0.784572
Al H (396.152 nm)0.703596 u ppm 0.003443 0.49 3212.670000 0.703596 u
As (188.980 nm)0.004541 ppm 0.002666 58.72 0.363158 0.004541
B (249.678 nm)0.081940 ppm 0.000357 0.44 701.990000 0.081940
Ba (493.408 nm)0.001852 ppm 0.000163 8.79 281.598000 0.001852
Be (234.861 nm)0.000491 ppm 0.000020 4.07 129.721000 0.000491
Bi (223.061 nm)-0.000638 u ppm 0.000264 41.36 3.136300 -0.000638 u
Ca (315.887 nm)19.077045 o ppm 0.076226 0.40 12841.911095 19.077045 o
Cd (214.439 nm)0.000520 ppm 0.000066 12.79 7.973020 0.000520
Co (228.615 nm)0.006316 ppm 0.000304 4.81 163.341000 0.006316
Cr (205.560 nm)0.001081 ppm 0.000588 54.36 5.953410 0.001081
Cu (324.754 nm)0.004213 ppm 0.000048 1.14 958.715000 0.004213
Fe (238.204 nm)0.606904 ppm 0.002360 0.39 2405.647534 0.606904
Fe H (259.940 nm)0.675641 u ppm 0.002202 0.33 955.557000 0.675641 u
K (766.491 nm)0.994584 ppm 0.016038 1.61 1339.510000 0.994584
Li (670.783 nm)0.142895 ppm 0.023908 16.73 1033.580000 0.142895
Mg (279.078 nm)173.322000 o ppm 0.878612 0.51 579716.000000 173.322000 o
Mn (257.610 nm)0.134745 ppm 0.000792 0.59 35957.400000 0.134745
Mo (202.032 nm)0.000798 ppm 0.000264 33.05 7.438230 0.000798
Na (589.592 nm)477.030000 o ppm 35.4471
00 7.43 5799440.000000 477.030000 o
Na H (589.593 nm)383.270478 ppm 67.9646
21 17.73 3446909.648764 383.270478
Ni (231.604 nm)0.008879 ppm 0.000671 7.55 20.025000 0.008879
P (213.618 nm)0.053858 ppm 0.002981 5.54 66.428000 0.053858
Pb (220.353 nm)0.001430 ppm 0.001017 71.09 1.584910 0.001430
S (181.972 nm)488.446260 bo ppm 3.453274 0.71 99496.007334 488.446260 bo
Sb (206.834 nm)-0.003457 u ppm 0.001488 43.06 -2.167450 -0.003457 u
Se (196.026 nm)0.004085 u ppm 0.005691 > 100.00 7.548160 0.004085 u
Si (288.158 nm)0.667282 ppm 0.004438 0.67 5560.530000 0.667282
Sn (189.925 nm)0.001036 ppm 0.000850 82.04 2.976750 0.001036
Sr (421.552 nm)0.417048 ppm 0.004787 1.15 92093.661737 0.417048
Th (288.505 nm)0.074572 ppm 0.000792 1.06 405.690000 0.074572
Ti (336.122 nm)0.001540 ppm 0.000065 4.19 91.659000 0.001540
Tl (190.794 nm)0.003530 ppm 0.001324 37.50 1.344550 0.003530
U (409.013 nm)0.015197 ppm 0.000834 5.49 91.573800 0.015197
V (292.401 nm)0.001258 ppm 0.000090 7.19 15.897100 0.001258
Zn (206.200 nm)0.043607 ppm 0.000317 0.73 98.194700 0.043607
Zr (343.823 nm)0.000873 ppm 0.000089 10.19 64.339000 0.000873
Test Report
52A112023.esws
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Page 1063 of 1261
Solution Name: 280-184226-A-10-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-10-A @25 11/21/2023 1:09:40 AM 4:38 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.035084 ppm 0.000218 0.62 91404.758414 0.035084
Ag (328.068 nm)0.000307 ppm 0.000211 68.78 -11.345600 0.000307
Al (394.401 nm)0.582495 ppm 0.003377 0.58 7609.200000 0.582495
Al H (396.152 nm)0.553987 u ppm 0.001666 0.30 2540.300000 0.553987 u
As (188.980 nm)0.001580 ppm 0.001162 73.55 -2.091650 0.001580
B (249.678 nm)0.060292 ppm 0.000518 0.86 520.802000 0.060292
Ba (493.408 nm)0.000472 ppm 0.000074 15.58 70.968600 0.000472
Be (234.861 nm)0.000292 ppm 0.000026 8.89 89.085600 0.000292
Bi (223.061 nm)0.001232 u ppm 0.004307 > 100.00 5.916320 0.001232 u
Ca (315.887 nm)15.790697 o ppm 0.042626 0.27 10625.535118 15.790697 o
Cd (214.439 nm)0.000327 ppm 0.000070 21.37 4.965220 0.000327
Co (228.615 nm)0.003716 ppm 0.000131 3.52 113.703000 0.003716
Cr (205.560 nm)0.000499 ppm 0.000438 87.75 3.560280 0.000499
Cu (324.754 nm)0.000678 ppm 0.000118 17.33 794.943000 0.000678
Fe (238.204 nm)0.028853 ppm 0.000537 1.86 130.193768 0.028853
Fe H (259.940 nm)0.120680 u ppm 0.002091 1.73 56.648700 0.120680 u
K (766.491 nm)0.294387 ppm 0.095473 32.43 81.497800 0.294387
Li (670.783 nm)-0.013880 u ppm 0.056976 > 100.00 -4796.770000 -0.013880 u
Mg (279.078 nm)26.283300 ppm 0.146995 0.56 87918.000000 26.283300
Mn (257.610 nm)0.086471 ppm 0.000490 0.57 23076.800000 0.086471
Mo (202.032 nm)0.000286 u ppm 0.000358 > 100.00 4.898090 0.000286 u
Na (589.592 nm)92.978200 o ppm 4.291810 4.62 1131210.000000 92.978200 o
Na H (589.593 nm)80.413689 ppm 17.7351
80 22.05 795635.143931 80.413689
Ni (231.604 nm)0.009678 ppm 0.000697 7.20 22.745100 0.009678
P (213.618 nm)0.004329 ppm 0.003504 80.95 8.170380 0.004329
Pb (220.353 nm)0.001567 u ppm 0.001710 > 100.00 1.901380 0.001567 u
S (181.972 nm)102.702008 o ppm 0.807950 0.79 20939.589574 102.702008 o
Sb (206.834 nm)-0.004570 u ppm 0.001812 39.66 -3.559080 -0.004570 u
Se (196.026 nm)0.003290 ppm 0.002205 67.01 7.088600 0.003290
Si (288.158 nm)0.622410 ppm 0.004051 0.65 5233.390000 0.622410
Sn (189.925 nm)-0.001181 u ppm 0.001704 > 100.00 1.487620 -0.001181 u
Sr (421.552 nm)0.112254 ppm 0.000496 0.44 24795.314127 0.112254
Th (288.505 nm)0.029668 ppm 0.000956 3.22 318.122000 0.029668
Ti (336.122 nm)-0.000143 u ppm 0.000091 63.88 -99.233900 -0.000143 u
Tl (190.794 nm)0.000354 u ppm 0.001523 > 100.00 -2.096330 0.000354 u
U (409.013 nm)0.002189 u ppm 0.002804 > 100.00 33.659300 0.002189 u
V (292.401 nm)0.000148 u ppm 0.000234 > 100.00 -30.200300 0.000148 u
Zn (206.200 nm)0.037711 ppm 0.000549 1.46 85.481500 0.037711
Zr (343.823 nm)0.000035 u ppm 0.000055 > 100.00 -4.743970 0.000035 u
Test Report
52A112023.esws
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Page 1064 of 1261
Solution Name: 280-184226-A-11-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-11-A @25 11/21/2023 1:14:01 AM 4:39 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.111835 b ppm 0.000520 0.46 289742.183161 0.111835 b
Ag (328.068 nm)0.000510 ppm 0.000058 11.33 -0.465311 0.000510
Al (394.401 nm)0.042912 ppm 0.000790 1.84 967.404000 0.042912
Al H (396.152 nm)0.030069 u ppm 0.004858 16.16 185.701000 0.030069 u
As (188.980 nm)0.002375 ppm 0.002286 96.25 -1.431830 0.002375
B (249.678 nm)0.050467 ppm 0.000861 1.71 438.571000 0.050467
Ba (493.408 nm)0.000756 ppm 0.000096 12.70 114.060000 0.000756
Be (234.861 nm)0.000111 ppm 0.000007 6.06 58.875200 0.000111
Bi (223.061 nm)0.000287 u ppm 0.002375 > 100.00 4.512260 0.000287 u
Ca (315.887 nm)16.270740 o ppm 0.021935 0.13 10949.285371 16.270740 o
Cd (214.439 nm)0.000083 u ppm 0.000178 > 100.00 1.328500 0.000083 u
Co (228.615 nm)0.000127 u ppm 0.000199 > 100.00 45.278700 0.000127 u
Cr (205.560 nm)0.000535 u ppm 0.000529 98.87 3.722050 0.000535 u
Cu (324.754 nm)0.001022 ppm 0.000117 11.49 812.224000 0.001022
Fe (238.204 nm)0.042912 ppm 0.000337 0.78 185.534207 0.042912
Fe H (259.940 nm)0.131558 u ppm 0.001231 0.94 74.268000 0.131558 u
K (766.491 nm)0.797795 ppm 0.085061 10.66 985.948000 0.797795
Li (670.783 nm)0.053123 ppm 0.054374 > 100.00 -2304.990000 0.053123
Mg (279.078 nm)49.339100 o ppm 0.213754 0.43 165032.000000 49.339100 o
Mn (257.610 nm)0.019641 ppm 0.000061 0.31 5245.060000 0.019641
Mo (202.032 nm)0.000603 ppm 0.000392 65.00 6.470480 0.000603
Na (589.592 nm)203.090000 o ppm 2.618140 1.29 2469640.000000 203.090000 o
Na H (589.593 nm)178.514302 ppm 26.5017
94 14.85 1654427.130250 178.514302
Ni (231.604 nm)-0.000251 u ppm 0.000154 61.56 -11.063100 -0.000251 u
P (213.618 nm)0.005409 ppm 0.003880 71.73 9.407630 0.005409
Pb (220.353 nm)-0.000607 u ppm 0.001095 > 100.00 -3.029220 -0.000607 u
S (181.972 nm)183.587311 bo ppm 0.781579 0.43 37411.715527 183.587311 bo
Sb (206.834 nm)-0.004177 u ppm 0.002108 50.45 -3.082930 -0.004177 u
Se (196.026 nm)0.007813 ppm 0.001602 20.51 9.818230 0.007813
Si (288.158 nm)0.227708 ppm 0.002144 0.94 2365.830000 0.227708
Sn (189.925 nm)-0.001587 u ppm 0.000742 46.74 1.214770 -0.001587 u
Sr (421.552 nm)0.453122 ppm 0.000819 0.18 100058.787683 0.453122
Th (288.505 nm)0.043766 ppm 0.001462 3.34 343.518000 0.043766
Ti (336.122 nm)0.000309 ppm 0.000072 23.12 -48.770800 0.000309
Tl (190.794 nm)0.001871 ppm 0.001370 73.19 -0.457705 0.001871
U (409.013 nm)0.004931 ppm 0.003090 62.66 45.861200 0.004931
V (292.401 nm)0.000252 ppm 0.000130 51.49 -25.186600 0.000252
Zn (206.200 nm)0.000985 ppm 0.000227 23.05 6.287510 0.000985
Zr (343.823 nm)0.000114 ppm 0.000022 19.34 1.714380 0.000114
Test Report
52A112023.esws
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Page 1065 of 1261
Solution Name: 280-184226-A-13-A @25
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-13-A @25 11/21/2023 1:18:21 AM 4:40 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.224412 b ppm 0.001278 0.57 580214.713173 0.224412 b
Ag (328.068 nm)0.000677 ppm 0.000077 11.36 8.166950 0.000677
Al (394.401 nm)0.229217 ppm 0.001910 0.83 3261.560000 0.229217
Al H (396.152 nm)0.200702 u ppm 0.002401 1.20 952.562000 0.200702 u
As (188.980 nm)0.002084 ppm 0.001755 84.23 -1.674440 0.002084
B (249.678 nm)0.092635 ppm 0.001113 1.20 791.502000 0.092635
Ba (493.408 nm)0.001025 ppm 0.000030 2.91 155.144000 0.001025
Be (234.861 nm)0.000173 ppm 0.000050 28.75 70.772500 0.000173
Bi (223.061 nm)0.002538 ppm 0.001673 65.91 7.858590 0.002538
Ca (315.887 nm)16.324874 o ppm 0.069063 0.42 10985.793841 16.324874 o
Cd (214.439 nm)0.000429 ppm 0.000027 6.38 6.521090 0.000429
Co (228.615 nm)0.000343 ppm 0.000220 63.98 49.417900 0.000343
Cr (205.560 nm)0.000937 ppm 0.000587 62.58 5.366720 0.000937
Cu (324.754 nm)0.001884 ppm 0.000181 9.58 851.387000 0.001884
Fe (238.204 nm)0.160585 ppm 0.001367 0.85 648.747832 0.160585
Fe H (259.940 nm)0.246958 u ppm 0.003591 1.45 261.189000 0.246958 u
K (766.491 nm)0.785200 ppm 0.056493 7.19 963.319000 0.785200
Li (670.783 nm)0.145555 ppm 0.043262 29.72 1132.490000 0.145555
Mg (279.078 nm)78.968100 o ppm 0.493870 0.63 264132.000000 78.968100 o
Mn (257.610 nm)0.010986 ppm 0.000075 0.68 2935.670000 0.010986
Mo (202.032 nm)0.001772 ppm 0.000780 44.02 12.268500 0.001772
Na (589.592 nm)298.210000 o ppm 10.9296
00 3.67 3625840.000000 298.210000 o
Na H (589.593 nm)234.546220 ppm 36.5733
88 15.59 2144942.991998 234.546220
Ni (231.604 nm)0.001768 ppm 0.000408 23.11 -4.192000 0.001768
P (213.618 nm)0.020601 ppm 0.002737 13.28 27.275900 0.020601
Pb (220.353 nm)0.001160 ppm 0.000662 57.11 1.012130 0.001160
S (181.972 nm)284.670998 bo ppm 1.925923 0.68 57997.265587 284.670998 bo
Sb (206.834 nm)-0.004489 u ppm 0.001782 39.70 -3.459350 -0.004489 u
Se (196.026 nm)0.008699 ppm 0.004691 53.93 10.344000 0.008699
Si (288.158 nm)0.336573 ppm 0.001485 0.44 3156.960000 0.336573
Sn (189.925 nm)-0.000922 u ppm 0.002050 > 100.00 1.661020 -0.000922 u
Sr (421.552 nm)0.380817 ppm 0.000182 0.05 84093.866400 0.380817
Th (288.505 nm)0.052988 ppm 0.003676 6.94 361.124000 0.052988
Ti (336.122 nm)0.000558 ppm 0.000059 10.63 -21.557500 0.000558
Tl (190.794 nm)-0.000074 u ppm 0.001190 > 100.00 -2.574950 -0.000074 u
U (409.013 nm)0.008318 ppm 0.005377 64.65 60.811900 0.008318
V (292.401 nm)0.000342 ppm 0.000049 14.21 -22.075400 0.000342
Zn (206.200 nm)0.004409 ppm 0.000586 13.29 13.671200 0.004409
Zr (343.823 nm)0.000302 ppm 0.000064 21.16 17.170200 0.000302
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 195 of 287
Page 1066 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 1:22:41 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000041 ppm 0.000019 47.37 1047.403621 0.000041
Ag (328.068 nm)0.000237 ppm 0.000079 33.28 126.799000 0.000237
Al (394.401 nm)52.196500 o ppm 0.282261 0.54 641685.000000 52.196500 o
Al H (396.152 nm)48.728200 ppm 0.252086 0.52 219045.000000 48.728200
As (188.980 nm)0.004431 ppm 0.002376 53.63 -0.168859 0.004431
B (249.678 nm)-0.003090 u ppm 0.000727 23.54 -9.685000 -0.003090 u
Ba (493.408 nm)0.000141 ppm 0.000133 94.41 161.121000 0.000141
Be (234.861 nm)0.000184 ppm 0.000003 1.63 714.394000 0.000184
Bi (223.061 nm)-0.001560 u ppm 0.000530 34.01 1.765820 -0.001560 u
Ca (315.887 nm)-0.015365 u ppm 0.007290 47.45 -34.375087 -0.015365 u
Cd (214.439 nm)-0.000010 u ppm 0.000140 > 100.00 10.137300 -0.000010 u
Co (228.615 nm)0.000400 ppm 0.000262 65.60 50.483600 0.000400
Cr (205.560 nm)0.001205 ppm 0.000563 46.71 6.480710 0.001205
Cu (324.754 nm)-0.000464 u ppm 0.000118 25.41 1689.410000 -0.000464 u
Fe (238.204 nm)50.014492 o ppm 0.253974 0.51 196894.090218 50.014492 o
Fe H (259.940 nm)48.281000 ppm 0.222990 0.46 78065.300000 48.281000
K (766.491 nm)-0.005233 u ppm 0.020972 > 100.00 -456.814000 -0.005233 u
Li (670.783 nm)0.006067 ppm 0.000105 1.74 -4054.970000 0.006067
Mg (279.078 nm)0.007220 ppm 0.001797 24.89 -156.622000 0.007220
Mn (257.610 nm)-0.000935 u ppm 0.000011 1.14 -244.984000 -0.000935 u
Mo (202.032 nm)-0.000218 u ppm 0.000352 > 100.00 2.393980 -0.000218 u
Na (589.592 nm)244.771000 o ppm 0.866113 0.35 2976270.000000 244.771000 o
Na H (589.593 nm)235.489690 ppm 3.214597 1.37 2153197.459965 235.489690
Ni (231.604 nm)0.000045 u ppm 0.000729 > 100.00 -10.057900 0.000045 u
P (213.618 nm)5.022050 ppm 0.032941 0.66 5931.100000 5.022050
Pb (220.353 nm)0.003189 ppm 0.001902 59.65 4.180030 0.003189
S (181.972 nm)4.740559 ppm 0.050677 1.07 991.375896 4.740559
Sb (206.834 nm)0.001110 u ppm 0.001359 > 100.00 6.815280 0.001110 u
Se (196.026 nm)0.005630 ppm 0.002363 41.97 3.231930 0.005630
Si (288.158 nm)0.024859 ppm 0.000706 2.84 892.194000 0.024859
Sn (189.925 nm)-0.000591 u ppm 0.001050 > 100.00 1.883970 -0.000591 u
Sr (421.552 nm)0.000476 ppm 0.000049 10.38 114.813818 0.000476
Th (288.505 nm)4.555300 ppm 0.021999 0.48 8773.730000 4.555300
Ti (336.122 nm)0.000670 ppm 0.000125 18.71 -44.931400 0.000670
Tl (190.794 nm)-0.003820 u ppm 0.001669 43.70 -7.533500 -0.003820 u
U (409.013 nm)2.378880 Q ppm 0.016728 0.70 10627.800000 Q 2.378880 Q
V (292.401 nm)0.000588 ppm 0.000074 12.60 267.721000 0.000588
Zn (206.200 nm)-0.000026 u ppm 0.000490 > 100.00 4.106770 -0.000026 u
Zr (343.823 nm)-0.000842 u ppm 0.000048 5.70 -8.675010 -0.000842 u
Test Report
52A112023.esws
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Page 1067 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 1:27:06 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.448921 Q ppm 0.000510 0.11 1151141.490654
Q 0.448921 Q
Ag (328.068 nm)0.504073 ppm 0.002408 0.48 26924.900000 0.504073
Al (394.401 nm)0.492938 ppm 0.000604 0.12 6520.650000 0.492938
Al H (396.152 nm)0.498660 u ppm 0.002859 0.57 2291.640000 0.498660 u
As (188.980 nm)0.502133 ppm 0.000373 0.07 413.784000 0.502133
B (249.678 nm)0.495994 ppm 0.000821 0.17 4167.480000 0.495994
Ba (493.408 nm)0.495526 ppm 0.000916 0.18 75055.800000 0.495526
Be (234.861 nm)0.506663 ppm 0.002877 0.57 84722.100000 0.506663
Bi (223.061 nm)0.994951 ppm 0.004315 0.43 1483.360000 0.994951
Ca (315.887 nm)4.955971 ppm 0.009085 0.18 3318.388597 4.955971
Cd (214.439 nm)0.506356 ppm 0.001317 0.26 7569.030000 0.506356
Co (228.615 nm)0.505861 ppm 0.001085 0.21 9709.140000 0.505861
Cr (205.560 nm)0.510257 ppm 0.000799 0.16 2098.820000 0.510257
Cu (324.754 nm)0.500972 ppm 0.001176 0.23 24130.000000 0.500972
Fe (238.204 nm)2.494244 ppm 0.008508 0.34 9841.272919 2.494244
Fe H (259.940 nm)2.506100 u ppm 0.002561 0.10 3920.480000 2.506100 u
K (766.491 nm)50.408600 ppm 0.244677 0.49 90119.300000 50.408600
Li (670.783 nm)0.498858 ppm 0.000740 0.15 14271.600000 0.498858
Mg (279.078 nm)20.183500 ppm 0.041498 0.21 67515.800000 20.183500
Mn (257.610 nm)0.496135 ppm 0.000987 0.20 132384.000000 0.496135
Mo (202.032 nm)0.500623 ppm 0.001289 0.26 2487.610000 0.500623
Na (589.592 nm)24.671700 ppm 0.136504 0.55 306730.000000 24.671700
Na H (589.593 nm)14.674390 u ppm 0.161570 1.10 224426.442753 14.674390 u
Ni (231.604 nm)0.510992 ppm 0.002140 0.42 1730.140000 0.510992
P (213.618 nm)0.010474 ppm 0.001030 9.83 -24.918700 0.010474
Pb (220.353 nm)0.534769 ppm 0.002442 0.46 1225.300000 0.534769
S (181.972 nm)-0.016784 u ppm 0.002442 14.55 23.140452 -0.016784 u
Sb (206.834 nm)0.491826 ppm 0.002821 0.57 600.919000 0.491826
Se (196.026 nm)0.505486 ppm 0.004797 0.95 315.283000 0.505486
Si (288.158 nm)4.932940 ppm 0.020551 0.42 36797.100000 4.932940
Sn (189.925 nm)0.502442 ppm 0.006064 1.21 339.915000 0.502442
Sr (421.552 nm)0.497179 ppm 0.000611 0.12 109786.578235 0.497179
Th (288.505 nm)0.038304 ppm 0.001276 3.33 320.312000 0.038304
Ti (336.122 nm)0.498769 ppm 0.000909 0.18 54317.900000 0.498769
Tl (190.794 nm)0.501716 ppm 0.002387 0.48 541.176000 0.501716
U (409.013 nm)-0.008692 u ppm 0.002114 24.33 -28.348800 -0.008692 u
V (292.401 nm)0.498896 ppm 0.001041 0.21 20732.700000 0.498896
Zn (206.200 nm)0.506498 ppm 0.003007 0.59 1096.360000 0.506498
Zr (343.823 nm)0.494788 ppm 0.001331 0.27 40330.500000 0.494788
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 197 of 287
Page 1068 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 1:31:27 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000494 ppm 0.000010 1.93 675.018161 0.000494
Ag (328.068 nm)0.000167 ppm 0.000185 > 100.00 -20.295100 0.000167
Al (394.401 nm)-0.000763 u ppm 0.000311 40.80 440.847000 -0.000763 u
Al H (396.152 nm)-0.001648 u ppm 0.002605 > 100.00 43.157700 -0.001648 u
As (188.980 nm)0.002829 ppm 0.002203 77.87 -1.053890 0.002829
B (249.678 nm)-0.000123 u ppm 0.000074 60.49 15.153500 -0.000123 u
Ba (493.408 nm)0.000119 u ppm 0.000215 > 100.00 17.455100 0.000119 u
Be (234.861 nm)0.000006 u ppm 0.000025 > 100.00 40.807500 0.000006 u
Bi (223.061 nm)-0.002611 u ppm 0.000865 33.14 0.202649 -0.002611 u
Ca (315.887 nm)0.008192 ppm 0.005011 61.16 -18.487620 0.008192
Cd (214.439 nm)0.000003 u ppm 0.000096 > 100.00 0.119496 0.000003 u
Co (228.615 nm)-0.000049 u ppm 0.000251 > 100.00 41.915700 -0.000049 u
Cr (205.560 nm)-0.000489 u ppm 0.000682 > 100.00 -0.488148 -0.000489 u
Cu (324.754 nm)0.000753 ppm 0.000247 32.79 801.131000 0.000753
Fe (238.204 nm)0.000571 u ppm 0.001818 > 100.00 18.853578 0.000571 u
Fe H (259.940 nm)0.093713 u ppm 0.002316 2.47 12.968600 0.093713 u
K (766.491 nm)0.025320 ppm 0.023888 94.34 -401.922000 0.025320
Li (670.783 nm)0.008845 S ppm 0.002836 32.06 -3951.650000 S 0.008845 S
Mg (279.078 nm)0.000709 ppm 0.000321 45.30 11.238600 0.000709
Mn (257.610 nm)-0.000025 u ppm 0.000017 68.52 -2.201040 -0.000025 u
Mo (202.032 nm)0.000405 ppm 0.000352 86.90 5.487250 0.000405
Na (589.592 nm)0.080651 ppm 0.005648 7.00 2018.830000 0.080651
Na H (589.593 nm)-9.945639 u ppm 0.013626 0.14 4610.829331 -9.945639 u
Ni (231.604 nm)0.000123 u ppm 0.000823 > 100.00 -9.792330 0.000123 u
P (213.618 nm)-0.001595 u ppm 0.000877 54.97 1.196960 -0.001595 u
Pb (220.353 nm)-0.000417 u ppm 0.000660 > 100.00 -2.581370 -0.000417 u
S (181.972 nm)-0.018968 u ppm 0.003057 16.12 20.210595 -0.018968 u
Sb (206.834 nm)-0.000995 u ppm 0.002394 > 100.00 0.789613 -0.000995 u
Se (196.026 nm)0.004558 ppm 0.001460 32.03 7.812510 0.004558
Si (288.158 nm)0.000490 ppm 0.000613 > 100.00 715.355000 0.000490
Sn (189.925 nm)0.000218 u ppm 0.001066 > 100.00 2.427250 0.000218 u
Sr (421.552 nm)0.000063 ppm 0.000028 44.52 23.492878 0.000063
Th (288.505 nm)0.007626 Z ppm 0.000964 12.64 274.772000 Z 0.007626 Z
Ti (336.122 nm)-0.000020 u ppm 0.000060 > 100.00 -120.293000 -0.000020 u
Tl (190.794 nm)0.000804 ppm 0.000772 96.07 -1.616320 0.000804
U (409.013 nm)0.000486 u ppm 0.001090 > 100.00 25.639300 0.000486 u
V (292.401 nm)0.000142 u ppm 0.000141 99.38 -33.113100 0.000142 u
Zn (206.200 nm)-0.001400 u ppm 0.000321 22.95 1.144410 -0.001400 u
Zr (343.823 nm)0.000030 u ppm 0.000161 > 100.00 -5.200660 0.000030 u
Test Report
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Page 1069 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 1:35:30 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014145 ppm 0.000069 0.49 35770.953101 0.014145
Ag (328.068 nm)0.009784 ppm 0.000124 1.26 491.465000 0.009784
Al (394.401 nm)0.086451 ppm 0.000327 0.38 1524.590000 0.086451
Al H (396.152 nm)0.091077 u ppm 0.002148 2.36 459.881000 0.091077 u
As (188.980 nm)0.014553 ppm 0.002153 14.79 8.686750 0.014553
B (249.678 nm)0.095586 ppm 0.000787 0.82 816.206000 0.095586
Ba (493.408 nm)0.009729 ppm 0.000211 2.17 1473.160000 0.009729
Be (234.861 nm)0.000986 ppm 0.000015 1.52 205.885000 0.000986
Bi (223.061 nm)-0.000911 Qu ppm 0.001796 > 100.00 2.729960 Q -0.000911 Qu
Ca (315.887 nm)0.203783 ppm 0.007865 3.86 113.422648 0.203783
Cd (214.439 nm)0.005024 ppm 0.000156 3.10 75.189000 0.005024
Co (228.615 nm)0.010103 ppm 0.000254 2.52 235.851000 0.010103
Cr (205.560 nm)0.009921 ppm 0.000388 3.91 42.239200 0.009921
Cu (324.754 nm)0.014782 ppm 0.000064 0.43 1448.810000 0.014782
Fe (238.204 nm)0.099510 ppm 0.000890 0.89 408.378293 0.099510
Fe H (259.940 nm)0.189794 u ppm 0.004158 2.19 168.597000 0.189794 u
K (766.491 nm)2.995920 ppm 0.017862 0.60 4935.210000 2.995920
Li (670.783 nm)0.027091 Q ppm 0.002300 8.49 -3273.100000 Q 0.027091 Q
Mg (279.078 nm)0.199525 ppm 0.000284 0.14 675.623000 0.199525
Mn (257.610 nm)0.010020 ppm 0.000051 0.51 2678.100000 0.010020
Mo (202.032 nm)0.019593 ppm 0.000558 2.85 100.702000 0.019593
Na (589.592 nm)1.049390 ppm 0.012742 1.21 13907.600000 1.049390
Na H (589.593 nm)-9.005262 u ppm 0.005248 0.06 12926.945739 -9.005262 u
Ni (231.604 nm)0.040883 ppm 0.000680 1.66 129.010000 0.040883
P (213.618 nm)2.809810 ppm 0.009607 0.34 3319.050000 2.809810
Pb (220.353 nm)0.009589 ppm 0.001166 12.16 20.444400 0.009589
S (181.972 nm)0.060567 Q ppm 0.012909 21.31 36.467589 Q 0.060567 Q
Sb (206.834 nm)0.018431 ppm 0.000312 1.69 24.385800 0.018431
Se (196.026 nm)0.019717 ppm 0.004004 20.31 17.111100 0.019717
Si (288.158 nm)0.458947 ppm 0.001816 0.40 4076.060000 0.458947
Sn (189.925 nm)0.096885 ppm 0.002187 2.26 67.386000 0.096885
Sr (421.552 nm)0.009594 ppm 0.000048 0.50 2128.056470 0.009594
Th (288.505 nm)0.007735 Q ppm 0.002710 35.03 275.066000 Q 0.007735 Q
Ti (336.122 nm)0.009485 ppm 0.000023 0.24 917.334000 0.009485
Tl (190.794 nm)0.015593 ppm 0.000808 5.18 14.399700 0.015593
U (409.013 nm)0.053982 ppm 0.002492 4.62 260.848000 0.053982
V (292.401 nm)0.009825 ppm 0.000134 1.37 365.073000 0.009825
Zn (206.200 nm)0.019460 ppm 0.000257 1.32 46.124800 0.019460
Zr (343.823 nm)0.009702 ppm 0.000139 1.43 783.408000 0.009702
Test Report
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Page 1070 of 1261
Solution Name: 280-184219-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184219-A-1-A 11/21/2023 1:39:47 AM 4:41 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.009091 b ppm 0.000021 0.23 25120.590203 0.009091 b
Ag (328.068 nm)0.000709 ppm 0.000088 12.42 9.963220 0.000709
Al (394.401 nm)0.096939 ppm 0.001012 1.04 1634.820000 0.096939
Al H (396.152 nm)0.076638 u ppm 0.002272 2.96 394.993000 0.076638 u
As (188.980 nm)0.003675 u ppm 0.003960 > 100.00 -0.351804 0.003675 u
B (249.678 nm)0.033279 ppm 0.000430 1.29 294.712000 0.033279
Ba (493.408 nm)0.877544 ppm 0.001519 0.17 132907.000000 0.877544
Be (234.861 nm)0.000023 u ppm 0.000024 > 100.00 45.279500 0.000023 u
Bi (223.061 nm)0.000794 u ppm 0.002170 > 100.00 5.265840 0.000794 u
Ca (315.887 nm)31.575904 o ppm 0.046996 0.15 21271.379559 31.575904 o
Cd (214.439 nm)0.000372 ppm 0.000097 26.13 5.661150 0.000372
Co (228.615 nm)0.005319 ppm 0.000246 4.63 144.294000 0.005319
Cr (205.560 nm)0.001578 ppm 0.000474 30.03 7.796380 0.001578
Cu (324.754 nm)0.256870 ppm 0.000326 0.13 12737.800000 0.256870
Fe (238.204 nm)0.127205 ppm 0.000840 0.66 517.345893 0.127205
Fe H (259.940 nm)0.213350 u ppm 0.002544 1.19 206.752000 0.213350 u
K (766.491 nm)56.205200 ppm 0.183483 0.33 100534.000000 56.205200
Li (670.783 nm)0.014422 ppm 0.001520 10.54 -3744.240000 0.014422
Mg (279.078 nm)7.052230 ppm 0.009700 0.14 23595.700000 7.052230
Mn (257.610 nm)0.184477 ppm 0.000191 0.10 49226.800000 0.184477
Mo (202.032 nm)0.005894 ppm 0.000114 1.93 32.724000 0.005894
Na (589.592 nm)179.353000 o ppm 0.744662 0.42 2191380.000000 179.353000 o
Na H (589.593 nm)167.583618 ppm 1.800322 1.07 1566325.629959 167.583618
Ni (231.604 nm)0.196320 ppm 0.000293 0.15 658.278000 0.196320
P (213.618 nm)1.535360 ppm 0.001997 0.13 1802.100000 1.535360
Pb (220.353 nm)0.006086 ppm 0.000623 10.24 12.334500 0.006086
S (181.972 nm)113.207369 bo ppm 0.055579 0.05 23079.402818 113.207369 bo
Sb (206.834 nm)0.000282 u ppm 0.000651 > 100.00 2.319050 0.000282 u
Se (196.026 nm)-0.003929 u ppm 0.003829 97.45 2.713270 -0.003929 u
Si (288.158 nm)1.745220 ppm 0.003947 0.23 13408.400000 1.745220
Sn (189.925 nm)0.057254 ppm 0.002015 3.52 40.755000 0.057254
Sr (421.552 nm)0.226114 ppm 0.000286 0.13 49935.500334 0.226114
Th (288.505 nm)0.022707 ppm 0.001056 4.65 306.750000 0.022707
Ti (336.122 nm)0.000202 ppm 0.000117 58.07 -26.971500 0.000202
Tl (190.794 nm)0.000843 u ppm 0.001513 > 100.00 -1.579350 0.000843 u
U (409.013 nm)0.005909 ppm 0.002764 46.77 50.112300 0.005909
V (292.401 nm)0.000680 ppm 0.000154 22.64 -8.594020 0.000680
Zn (206.200 nm)0.014121 ppm 0.000691 4.89 34.612200 0.014121
Zr (343.823 nm)0.000174 ppm 0.000095 54.58 6.734950 0.000174
Test Report
52A112023.esws
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Page 1071 of 1261
Solution Name: 280-184226-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-A 11/21/2023 1:44:13 AM 4:42 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.612187 b ppm 0.001700 0.28 1603626.731594 0.612187 b
Ag (328.068 nm)0.002001 ppm 0.000154 7.69 44.868500 0.002001
Al (394.401 nm)16.243400 o ppm 0.047448 0.29 200313.000000 16.243400 o
Al H (396.152 nm)14.834300 ppm 0.021209 0.14 66719.000000 14.834300
As (188.980 nm)0.010987 ppm 0.002093 19.05 5.601980 0.010987
B (249.678 nm)2.527930 ppm 0.009320 0.37 21174.100000 2.527930
Ba (493.408 nm)0.187403 ppm 0.000564 0.30 28420.900000 0.187403
Be (234.861 nm)0.001412 ppm 0.000013 0.94 452.727000 0.001412
Bi (223.061 nm)-0.000184 u ppm 0.001380 > 100.00 3.812040 -0.000184 u
Ca (315.887 nm)392.438634 o ppm 1.218892 0.31 264644.094122 392.438634 o
Cd (214.439 nm)0.001508 ppm 0.000076 5.05 25.422200 0.001508
Co (228.615 nm)0.006042 ppm 0.000216 3.57 163.790000 0.006042
Cr (205.560 nm)0.021955 ppm 0.000328 1.49 91.794400 0.021955
Cu (324.754 nm)0.028420 ppm 0.000214 0.75 1882.490000 0.028420
Fe (238.204 nm)13.741107 o ppm 0.052540 0.38 54107.271103 13.741107 o
Fe H (259.940 nm)13.491000 ppm 0.041509 0.31 21713.400000 13.491000
K (766.491 nm)17.254300 ppm 0.035391 0.21 30552.700000 17.254300
Li (670.783 nm)0.519175 ppm 0.002037 0.39 15027.200000 0.519175
Mg (279.078 nm)34.473900 ppm 0.208045 0.60 115304.000000 34.473900
Mn (257.610 nm)0.257129 ppm 0.001255 0.49 68611.900000 0.257129
Mo (202.032 nm)0.008882 ppm 0.001024 11.53 47.550700 0.008882
Na (589.592 nm)####ppm N/A N/A ########
Na H (589.593 nm)3551.950304
bo ppm 23.6340
17 0.67 31187691.429417 3551.950304 bo
Ni (231.604 nm)0.020490 ppm 0.000321 1.57 59.560400 0.020490
P (213.618 nm)1.165580 ppm 0.010213 0.88 1377.450000 1.165580
Pb (220.353 nm)0.029832 ppm 0.001618 5.43 64.957000 0.029832
S (181.972 nm)1819.890594
bo ppm 10.8603
27 0.60 370650.726368 1819.890594 bo
Sb (206.834 nm)-0.002991 u ppm 0.003068 > 100.00 -1.052760 -0.002991 u
Se (196.026 nm)0.001464 u ppm 0.005301 > 100.00 4.644630 0.001464 u
Si (288.158 nm)31.071700 o ppm 0.024665 0.08 226495.000000 31.071700 o
Sn (189.925 nm)-0.000882 u ppm 0.000980 > 100.00 1.688470 -0.000882 u
Sr (421.552 nm)8.017830 o ppm 0.028302 0.35 1770342.253675 8.017830 o
Th (288.505 nm)0.090393 ppm 0.001324 1.46 432.411000 0.090393
Ti (336.122 nm)0.146882 ppm 0.001014 0.69 16769.300000 0.146882
Tl (190.794 nm)-0.000549 u ppm 0.002366 > 100.00 -3.577660 -0.000549 u
U (409.013 nm)-0.063349 u ppm 0.002033 3.21 -241.538000 -0.063349 u
V (292.401 nm)0.050901 ppm 0.000302 0.59 2099.330000 0.050901
Zn (206.200 nm)0.104896 ppm 0.001174 1.12 230.356000 0.104896
Zr (343.823 nm)0.010660 ppm 0.000124 1.17 879.951000 0.010660
Test Report
52A112023.esws
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Page 1072 of 1261
Solution Name: 280-184226-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-A 11/21/2023 1:48:54 AM 4:43 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.112459 b ppm 0.000983 0.87 295614.381998 0.112459 b
Ag (328.068 nm)0.000898 ppm 0.000154 17.18 11.972900 0.000898
Al (394.401 nm)3.485740 o ppm 0.047009 1.35 43341.000000 3.485740 o
Al H (396.152 nm)3.225640 ppm 0.013777 0.43 14547.300000 3.225640
As (188.980 nm)0.003729 ppm 0.002503 67.13 -0.331302 0.003729
B (249.678 nm)0.485565 ppm 0.004983 1.03 4080.190000 0.485565
Ba (493.408 nm)0.038189 ppm 0.000389 1.02 5791.190000 0.038189
Be (234.861 nm)0.000357 ppm 0.000053 14.76 135.814000 0.000357
Bi (223.061 nm)-0.000952 u ppm 0.001906 > 100.00 2.669060 -0.000952 u
Ca (315.887 nm)78.514049 o ppm 0.414724 0.53 52927.360899 78.514049 o
Cd (214.439 nm)0.000720 ppm 0.000190 26.34 11.413300 0.000720
Co (228.615 nm)0.001245 ppm 0.000238 19.13 68.492200 0.001245
Cr (205.560 nm)0.005222 ppm 0.000464 8.89 22.995400 0.005222
Cu (324.754 nm)0.006457 ppm 0.000236 3.66 1024.190000 0.006457
Fe (238.204 nm)2.825828 ppm 0.016378 0.58 11140.237708 2.825828
Fe H (259.940 nm)2.820390 u ppm 0.017324 0.61 4429.560000 2.820390 u
K (766.491 nm)3.111010 ppm 0.053597 1.72 5141.990000 3.111010
Li (670.783 nm)0.071092 ppm 0.046452 65.34 -1636.740000 0.071092
Mg (279.078 nm)7.153500 ppm 0.063091 0.88 23933.400000 7.153500
Mn (257.610 nm)0.051897 ppm 0.000448 0.86 13851.800000 0.051897
Mo (202.032 nm)0.002271 ppm 0.000446 19.62 14.744500 0.002271
Na (589.592 nm)732.325000 o ppm 9.926720 1.36 8903010.000000 732.325000 o
Na H (589.593 nm)797.978522 ppm 68.9540
87 8.64 7077650.395066 797.978522
Ni (231.604 nm)0.002904 ppm 0.000230 7.92 -0.322544 0.002904
P (213.618 nm)0.220063 ppm 0.006757 3.07 262.529000 0.220063
Pb (220.353 nm)0.004918 ppm 0.000492 10.01 9.217640 0.004918
S (181.972 nm)417.853560 bo ppm 4.525827 1.08 85121.060440 417.853560 bo
Sb (206.834 nm)-0.002719 u ppm 0.001617 59.46 -1.244200 -0.002719 u
Se (196.026 nm)-0.001454 u ppm 0.001204 82.83 3.861700 -0.001454 u
Si (288.158 nm)6.866470 ppm 0.068663 1.00 50610.200000 6.866470
Sn (189.925 nm)-0.000043 u ppm 0.000787 > 100.00 2.251840 -0.000043 u
Sr (421.552 nm)1.565573 o ppm 0.006404 0.41 345687.265142 1.565573 o
Th (288.505 nm)0.034454 ppm 0.002074 6.02 325.432000 0.034454
Ti (336.122 nm)0.048973 ppm 0.001046 2.14 5397.760000 0.048973
Tl (190.794 nm)0.000364 u ppm 0.002097 > 100.00 -2.225420 0.000364 u
U (409.013 nm)-0.008199 u ppm 0.001669 20.35 -9.871040 -0.008199 u
V (292.401 nm)0.011320 ppm 0.000472 4.17 436.397000 0.011320
Zn (206.200 nm)0.021727 ppm 0.000584 2.69 51.015100 0.021727
Zr (343.823 nm)0.002522 ppm 0.000069 2.74 201.777000 0.002522
Test Report
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Page 1073 of 1261
Solution Name: 280-184226-A-1-B MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-B MS 11/21/2023 1:53:19 AM 4:44 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.909013 bo ppm 0.012010 0.63 4929656.677281 1.909013 bo
Ag (328.068 nm)0.058311 ppm 0.000631 1.08 2577.700000 0.058311
Al (394.401 nm)47.037000 o ppm 0.246311 0.52 579251.000000 47.037000 o
Al H (396.152 nm)43.091000 ppm 0.052330 0.12 193710.000000 43.091000
As (188.980 nm)1.084090 ppm 0.002041 0.19 897.112000 1.084090
B (249.678 nm)4.653820 ppm 0.014423 0.31 38967.100000 4.653820
Ba (493.408 nm)1.235580 ppm 0.001637 0.13 187206.000000 1.235580
Be (234.861 nm)0.998522 ppm 0.014101 1.41 167201.000000 0.998522
Bi (223.061 nm)0.000157 u ppm 0.002768 > 100.00 4.318990 0.000157 u
Ca (315.887 nm)439.844430 o ppm 0.673203 0.15 296615.467840 439.844430 o
Cd (214.439 nm)0.922362 ppm 0.005108 0.55 13791.800000 0.922362
Co (228.615 nm)0.945335 ppm 0.004041 0.43 18116.600000 0.945335
Cr (205.560 nm)0.985277 ppm 0.004870 0.49 4051.350000 0.985277
Cu (324.754 nm)1.080070 ppm 0.006295 0.58 50914.200000 1.080070
Fe (238.204 nm)25.967213 o ppm 0.024428 0.09 102245.689065 25.967213 o
Fe H (259.940 nm)25.430400 ppm 0.058708 0.23 41052.600000 25.430400
K (766.491 nm)77.240500 ppm 0.521823 0.68 138327.000000 77.240500
Li (670.783 nm)1.607230 o ppm 0.009433 0.59 55491.500000 1.607230 o
Mg (279.078 nm)83.950800 o ppm 0.538171 0.64 280782.000000 83.950800 o
Mn (257.610 nm)1.206400 o ppm 0.007253 0.60 321897.000000 1.206400 o
Mo (202.032 nm)0.951629 ppm 0.006258 0.66 4725.540000 0.951629
Na (589.592 nm)####ppm N/A N/A ########
Na H (589.593 nm)3606.636977
bo ppm 5.990557 0.17 31675499.116883 3606.636977 bo
Ni (231.604 nm)0.949712 ppm 0.006663 0.70 3224.280000 0.949712
P (213.618 nm)22.761300 o ppm 0.082773 0.36 26791.400000 22.761300 o
Pb (220.353 nm)1.017250 ppm 0.007926 0.78 2327.000000 1.017250
S (181.972 nm)1823.551428
bo ppm 12.6330
37 0.69 371401.193038 1823.551428 bo
Sb (206.834 nm)0.948609 ppm 0.005814 0.61 1158.030000 0.948609
Se (196.026 nm)1.075910 ppm 0.006184 0.57 663.342000 1.075910
Si (288.158 nm)54.413400 o ppm 0.680759 1.25 396553.000000 54.413400 o
Sn (189.925 nm)0.906029 ppm 0.009282 1.02 611.120000 0.906029
Sr (421.552 nm)9.052947 o ppm 0.016528 0.18 1998895.584022 9.052947 o
Th (288.505 nm)0.137615 ppm 0.001769 1.29 496.308000 0.137615
Ti (336.122 nm)1.184120 o ppm 0.006415 0.54 130056.000000 1.184120 o
Tl (190.794 nm)0.830658 ppm 0.005826 0.70 896.544000 0.830658
U (409.013 nm)-0.085291 u ppm 0.005013 5.88 -357.894000 -0.085291 u
V (292.401 nm)1.058660 ppm 0.005992 0.57 44079.800000 1.058660
Zn (206.200 nm)1.055290 ppm 0.003767 0.36 2279.760000 1.055290
Zr (343.823 nm)0.992351 ppm 0.004840 0.49 80923.300000 0.992351
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 203 of 287
Page 1074 of 1261
Solution Name: 280-184226-A-1-C MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-C MSD 11/21/2023 1:58:17 AM 4:45 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.916367 bo ppm 0.007514 0.39 4948560.531449 1.916367 bo
Ag (328.068 nm)0.058188 ppm 0.000266 0.46 2559.490000 0.058188
Al (394.401 nm)50.472500 o ppm 0.203836 0.40 621527.000000 50.472500 o
Al H (396.152 nm)46.443900 ppm 0.121883 0.26 208779.000000 46.443900
As (188.980 nm)1.080160 ppm 0.008031 0.74 893.830000 1.080160
B (249.678 nm)4.676150 ppm 0.026728 0.57 39154.000000 4.676150
Ba (493.408 nm)1.254260 ppm 0.003211 0.26 190040.000000 1.254260
Be (234.861 nm)1.007980 ppm 0.009386 0.93 168802.000000 1.007980
Bi (223.061 nm)0.000403 u ppm 0.001073 > 100.00 4.684160 0.000403 u
Ca (315.887 nm)441.829299 o ppm 1.270715 0.29 297954.101388 441.829299 o
Cd (214.439 nm)0.911844 ppm 0.004679 0.51 13634.900000 0.911844
Co (228.615 nm)0.941839 ppm 0.003633 0.39 18049.500000 0.941839
Cr (205.560 nm)0.980707 ppm 0.005222 0.53 4032.670000 0.980707
Cu (324.754 nm)1.077700 ppm 0.005684 0.53 50805.000000 1.077700
Fe (238.204 nm)27.571045 o ppm 0.087299 0.32 108558.892080 27.571045 o
Fe H (259.940 nm)26.979300 ppm 0.057587 0.21 43561.400000 26.979300
K (766.491 nm)77.341400 ppm 0.187338 0.24 138508.000000 77.341400
Li (670.783 nm)1.586690 o ppm 0.001402 0.09 54727.700000 1.586690 o
Mg (279.078 nm)83.859200 o ppm 0.395198 0.47 280475.000000 83.859200 o
Mn (257.610 nm)1.202470 o ppm 0.005099 0.42 320849.000000 1.202470 o
Mo (202.032 nm)0.914775 ppm 0.005174 0.57 4542.670000 0.914775
Na (589.592 nm)####ppm N/A N/A ########
Na H (589.593 nm)3613.558808
bo ppm 18.4595
08 0.51 31736254.959305 3613.558808 bo
Ni (231.604 nm)0.940570 ppm 0.002224 0.24 3193.140000 0.940570
P (213.618 nm)22.785300 o ppm 0.112458 0.49 26821.000000 22.785300 o
Pb (220.353 nm)1.014000 ppm 0.004855 0.48 2319.200000 1.014000
S (181.972 nm)1825.118914
bo ppm 11.8269
31 0.65 371720.521496 1825.118914 bo
Sb (206.834 nm)0.906857 ppm 0.005610 0.62 1107.440000 0.906857
Se (196.026 nm)1.091990 o ppm 0.012432 1.14 673.044000 1.091990 o
Si (288.158 nm)55.980700 o ppm 0.647790 1.16 407928.000000 55.980700 o
Sn (189.925 nm)0.869790 ppm 0.002729 0.31 586.768000 0.869790
Sr (421.552 nm)9.075904 o ppm 0.016734 0.18 2003964.325381 9.075904 o
Th (288.505 nm)0.134437 ppm 0.003219 2.39 490.013000 0.134437
Ti (336.122 nm)1.172550 o ppm 0.004361 0.37 128798.000000 1.172550 o
Tl (190.794 nm)0.824682 ppm 0.005919 0.72 890.131000 0.824682
U (409.013 nm)-0.086209 u ppm 0.003863 4.48 -359.239000 -0.086209 u
V (292.401 nm)1.059370 ppm 0.003712 0.35 44112.800000 1.059370
Zn (206.200 nm)1.044610 ppm 0.006799 0.65 2256.730000 1.044610
Zr (343.823 nm)0.955889 ppm 0.003559 0.37 77953.100000 0.955889
Test Report
52A112023.esws
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Page 1075 of 1261
Solution Name: 280-184226-A-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184226-A-1-A 11/21/2023 2:02:58 AM 4:46 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.735224 b ppm 0.001568 0.21 1918418.222169 0.735224 b
Ag (328.068 nm)0.055693 ppm 0.000063 0.11 2913.070000 0.055693
Al (394.401 nm)18.651100 o ppm 0.293128 1.57 229940.000000 18.651100 o
Al H (396.152 nm)16.840200 ppm 0.111991 0.67 75733.800000 16.840200
As (188.980 nm)0.224412 ppm 0.004982 2.22 182.925000 0.224412
B (249.678 nm)2.608860 ppm 0.008017 0.31 21851.400000 2.608860
Ba (493.408 nm)0.285591 ppm 0.000665 0.23 43293.900000 0.285591
Be (234.861 nm)0.048515 ppm 0.000400 0.82 8331.700000 0.048515
Bi (223.061 nm)0.002152 u ppm 0.005410 > 100.00 7.285250 0.002152 u
Ca (315.887 nm)399.383980 o ppm 0.476742 0.12 269328.167811 399.383980 o
Cd (214.439 nm)0.047564 ppm 0.000106 0.22 713.956000 0.047564
Co (228.615 nm)0.052809 ppm 0.000163 0.31 1060.080000 0.052809
Cr (205.560 nm)0.069850 ppm 0.000362 0.52 288.658000 0.069850
Cu (324.754 nm)0.080133 ppm 0.000432 0.54 4302.530000 0.080133
Fe (238.204 nm)14.467342 o ppm 0.036867 0.25 56966.599957 14.467342 o
Fe H (259.940 nm)14.243200 ppm 0.002332 0.02 22931.900000 14.243200
K (766.491 nm)39.705200 ppm 0.120383 0.30 70889.100000 39.705200
Li (670.783 nm)0.599769 ppm 0.037362 6.23 18024.500000 0.599769
Mg (279.078 nm)51.625700 o ppm 0.119841 0.23 172659.000000 51.625700 o
Mn (257.610 nm)0.293862 ppm 0.000549 0.19 78413.100000 0.293862
Mo (202.032 nm)0.055706 ppm 0.000601 1.08 279.898000 0.055706
Na (589.592 nm)####ppm N/A N/A ########
Na H (589.593 nm)4134.254986
bo ppm 426.411
875 10.31 36286136.289444 4134.254986 bo
Ni (231.604 nm)0.065439 ppm 0.001433 2.19 212.740000 0.065439
P (213.618 nm)3.286300 ppm 0.012785 0.39 3877.090000 3.286300
Pb (220.353 nm)0.127037 ppm 0.001278 1.01 288.670000 0.127037
S (181.972 nm)1762.871162
bo ppm 5.669503 0.32 359039.563205 1762.871162 bo
Sb (206.834 nm)0.099549 ppm 0.000428 0.43 123.696000 0.099549
Se (196.026 nm)0.216141 ppm 0.005321 2.46 136.333000 0.216141
Si (288.158 nm)40.689900 o ppm 0.806836 1.98 296413.000000 40.689900 o
Sn (189.925 nm)0.047477 ppm 0.000989 2.08 34.184700 0.047477
Sr (421.552 nm)7.913565 o ppm 0.006334 0.08 1747320.595929 7.913565 o
Th (288.505 nm)0.265874 ppm 0.004803 1.81 761.850000 0.265874
Ti (336.122 nm)0.259192 ppm 0.019595 7.56 29039.500000 0.259192
Tl (190.794 nm)0.165962 ppm 0.002955 1.78 177.017000 0.165962
U (409.013 nm)0.402641 ppm 0.001671 0.41 1813.240000 0.402641
V (292.401 nm)0.100647 ppm 0.000687 0.68 4163.460000 0.100647
Zn (206.200 nm)0.286779 ppm 0.000533 0.19 622.563000 0.286779
Zr (343.823 nm)0.063440 ppm 0.000554 0.87 5183.510000 0.063440
Test Report
52A112023.esws
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Page 1076 of 1261
Solution Name: Rinse
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
Rinse 11/21/2023 2:07:35 AM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000548 ppm 0.000009 1.59 813.918282 0.000548
Ag (328.068 nm)0.000159 ppm 0.000127 79.65 -20.777600 0.000159
Al (394.401 nm)-0.001277 u ppm 0.000883 69.15 435.873000 -0.001277 u
Al H (396.152 nm)-0.000506 u ppm 0.001675 > 100.00 48.288400 -0.000506 u
As (188.980 nm)0.002748 ppm 0.001194 43.45 -1.121260 0.002748
B (249.678 nm)0.004476 ppm 0.001013 22.64 53.642600 0.004476
Ba (493.408 nm)0.000074 u ppm 0.000197 > 100.00 10.680900 0.000074 u
Be (234.861 nm)-0.000042 u ppm 0.000005 12.66 32.880800 -0.000042 u
Bi (223.061 nm)-0.001107 u ppm 0.001268 > 100.00 2.439600 -0.001107 u
Ca (315.887 nm)0.024168 ppm 0.003348 13.86 -7.713492 0.024168
Cd (214.439 nm)0.000162 ppm 0.000106 65.54 2.503880 0.000162
Co (228.615 nm)-0.000044 u ppm 0.000153 > 100.00 41.997600 -0.000044 u
Cr (205.560 nm)-0.000249 u ppm 0.000225 90.50 0.501111 -0.000249 u
Cu (324.754 nm)0.000629 ppm 0.000126 20.03 794.230000 0.000629
Fe (238.204 nm)0.001284 u ppm 0.001435 > 100.00 21.649007 0.001284 u
Fe H (259.940 nm)0.093654 u ppm 0.000555 0.59 12.872300 0.093654 u
K (766.491 nm)0.071629 ppm 0.009259 12.93 -318.720000 0.071629
Li (670.783 nm)0.014655 ppm 0.000919 6.27 -3735.610000 0.014655
Mg (279.078 nm)0.000880 ppm 0.000642 73.01 11.997000 0.000880
Mn (257.610 nm)-0.000027 u ppm 0.000006 21.53 -2.803230 -0.000027 u
Mo (202.032 nm)0.000155 ppm 0.000140 90.53 4.247850 0.000155
Na (589.592 nm)0.717421 ppm 0.041439 5.78 9757.760000 0.717421
Na H (589.593 nm)-8.498145 u ppm 0.060340 0.71 17281.615399 -8.498145 u
Ni (231.604 nm)0.000261 u ppm 0.000434 > 100.00 -9.321120 0.000261 u
P (213.618 nm)-0.003619 u ppm 0.001476 40.79 -1.181140 -0.003619 u
Pb (220.353 nm)0.000591 ppm 0.000207 35.00 -0.268495 0.000591
S (181.972 nm)0.092976 ppm 0.014576 15.68 43.000295 0.092976
Sb (206.834 nm)-0.000666 u ppm 0.002395 > 100.00 1.193310 -0.000666 u
Se (196.026 nm)0.000927 u ppm 0.002677 > 100.00 5.583890 0.000927 u
Si (288.158 nm)0.027361 ppm 0.001669 6.10 910.150000 0.027361
Sn (189.925 nm)-0.001593 u ppm 0.000747 46.86 1.210260 -0.001593 u
Sr (421.552 nm)0.000221 ppm 0.000041 18.61 58.531715 0.000221
Th (288.505 nm)0.001364 u ppm 0.002445 > 100.00 263.073000 0.001364 u
Ti (336.122 nm)0.000032 ppm 0.000043 > 100.00 -114.544000 0.000032
Tl (190.794 nm)0.002642 ppm 0.001875 70.97 0.380257 0.002642
U (409.013 nm)-0.000133 u ppm 0.000877 > 100.00 22.822100 -0.000133 u
V (292.401 nm)0.000112 u ppm 0.000264 > 100.00 -34.734000 0.000112 u
Zn (206.200 nm)-0.001538 u ppm 0.000316 20.54 0.846824 -0.001538 u
Zr (343.823 nm)-0.000067 u ppm 0.000115 > 100.00 -13.111000 -0.000067 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 206 of 287
Page 1077 of 1261
Solution Name: Rinse
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
Rinse 11/21/2023 2:11:37 AM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000517 ppm 0.000010 1.86 732.950669 0.000517
Ag (328.068 nm)0.000195 ppm 0.000055 28.11 -18.888300 0.000195
Al (394.401 nm)-0.003186 u ppm 0.000133 4.18 412.491000 -0.003186 u
Al H (396.152 nm)-0.000041 u ppm 0.002091 > 100.00 50.379900 -0.000041 u
As (188.980 nm)0.001073 u ppm 0.002326 > 100.00 -2.512970 0.001073 u
B (249.678 nm)0.002085 ppm 0.000592 28.39 33.635100 0.002085
Ba (493.408 nm)0.000115 u ppm 0.000160 > 100.00 16.793200 0.000115 u
Be (234.861 nm)-0.000019 u ppm 0.000018 93.95 36.620500 -0.000019 u
Bi (223.061 nm)0.001324 u ppm 0.001876 > 100.00 6.053290 0.001324 u
Ca (315.887 nm)0.015706 ppm 0.006196 39.45 -13.420319 0.015706
Cd (214.439 nm)0.000053 ppm 0.000044 83.16 0.866533 0.000053
Co (228.615 nm)-0.000113 u ppm 0.000383 > 100.00 40.682800 -0.000113 u
Cr (205.560 nm)-0.000079 u ppm 0.001183 > 100.00 1.200070 -0.000079 u
Cu (324.754 nm)0.000397 ppm 0.000099 24.88 783.363000 0.000397
Fe (238.204 nm)0.000191 u ppm 0.001759 > 100.00 17.355671 0.000191 u
Fe H (259.940 nm)0.094545 u ppm 0.001457 1.54 14.316300 0.094545 u
K (766.491 nm)0.038568 ppm 0.014693 38.09 -378.119000 0.038568
Li (670.783 nm)0.013744 ppm 0.001366 9.94 -3769.480000 0.013744
Mg (279.078 nm)-0.000094 u ppm 0.001202 > 100.00 8.757620 -0.000094 u
Mn (257.610 nm)-0.000040 u ppm 0.000023 55.87 -6.296640 -0.000040 u
Mo (202.032 nm)0.000841 ppm 0.000316 37.59 7.652170 0.000841
Na (589.592 nm)0.522430 ppm 0.038074 7.29 7388.580000 0.522430
Na H (589.593 nm)-8.999850 u ppm 0.039062 0.43 12890.321428 -8.999850 u
Ni (231.604 nm)-0.000598 u ppm 0.000136 22.70 -12.245700 -0.000598 u
P (213.618 nm)-0.002922 u ppm 0.002582 88.34 -0.361742 -0.002922 u
Pb (220.353 nm)0.000483 u ppm 0.001975 > 100.00 -0.517797 0.000483 u
S (181.972 nm)0.034096 ppm 0.002024 5.94 31.011233 0.034096
Sb (206.834 nm)-0.000209 u ppm 0.002427 > 100.00 1.751760 -0.000209 u
Se (196.026 nm)0.000182 u ppm 0.003563 > 100.00 5.127190 0.000182 u
Si (288.158 nm)0.009979 ppm 0.002141 21.46 784.014000 0.009979
Sn (189.925 nm)-0.000728 u ppm 0.001082 > 100.00 1.791490 -0.000728 u
Sr (421.552 nm)0.000069 ppm 0.000106 > 100.00 24.938519 0.000069
Th (288.505 nm)0.002231 ppm 0.001006 45.11 264.682000 0.002231
Ti (336.122 nm)-0.000050 u ppm 0.000035 70.27 -123.528000 -0.000050 u
Tl (190.794 nm)0.001136 ppm 0.000930 81.85 -1.256700 0.001136
U (409.013 nm)-0.002681 u ppm 0.000969 36.15 11.586300 -0.002681 u
V (292.401 nm)0.000065 u ppm 0.000099 > 100.00 -36.947200 0.000065 u
Zn (206.200 nm)-0.001501 u ppm 0.000608 40.51 0.926642 -0.001501 u
Zr (343.823 nm)-0.000077 u ppm 0.000079 > 100.00 -13.967600 -0.000077 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 207 of 287
Page 1078 of 1261
Solution Name: Rinse
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
Rinse 11/21/2023 2:15:38 AM S1:5 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000512 ppm 0.000020 3.83 719.636053 0.000512
Ag (328.068 nm)0.000251 ppm 0.000129 51.27 -16.009000 0.000251
Al (394.401 nm)-0.002265 u ppm 0.000488 21.52 424.397000 -0.002265 u
Al H (396.152 nm)-0.001346 u ppm 0.002916 > 100.00 44.514500 -0.001346 u
As (188.980 nm)0.003339 ppm 0.002325 69.62 -0.629924 0.003339
B (249.678 nm)0.000819 ppm 0.000247 30.20 23.038300 0.000819
Ba (493.408 nm)0.000036 u ppm 0.000254 > 100.00 4.820550 0.000036 u
Be (234.861 nm)-0.000025 u ppm 0.000010 42.18 35.743900 -0.000025 u
Bi (223.061 nm)0.000633 u ppm 0.000935 > 100.00 5.026390 0.000633 u
Ca (315.887 nm)0.009882 ppm 0.000888 8.99 -17.348301 0.009882
Cd (214.439 nm)0.000147 ppm 0.000040 27.56 2.272530 0.000147
Co (228.615 nm)-0.000204 u ppm 0.000126 61.68 38.964300 -0.000204 u
Cr (205.560 nm)-0.000075 u ppm 0.000324 > 100.00 1.216590 -0.000075 u
Cu (324.754 nm)0.000581 ppm 0.000198 34.09 791.478000 0.000581
Fe (238.204 nm)0.000147 u ppm 0.000325 > 100.00 17.178172 0.000147 u
Fe H (259.940 nm)0.092676 u ppm 0.001363 1.47 11.288200 0.092676 u
K (766.491 nm)0.008750 u ppm 0.007690 87.88 -431.692000 0.008750 u
Li (670.783 nm)0.014444 ppm 0.002454 16.99 -3743.420000 0.014444
Mg (279.078 nm)-0.001095 u ppm 0.001289 > 100.00 5.459230 -0.001095 u
Mn (257.610 nm)-0.000048 u ppm 0.000011 22.80 -8.432580 -0.000048 u
Mo (202.032 nm)0.000014 u ppm 0.000282 > 100.00 3.548250 0.000014 u
Na (589.592 nm)0.435060 ppm 0.030799 7.08 6322.640000 0.435060
Na H (589.593 nm)-9.249620 u ppm 0.027107 0.29 10700.884571 -9.249620 u
Ni (231.604 nm)0.000215 u ppm 0.000517 > 100.00 -9.479670 0.000215 u
P (213.618 nm)-0.000810 u ppm 0.002319 > 100.00 2.143520 -0.000810 u
Pb (220.353 nm)-0.000717 u ppm 0.000696 97.14 -3.273720 -0.000717 u
S (181.972 nm)0.008257 u ppm 0.010813 > 100.00 25.750184 0.008257 u
Sb (206.834 nm)0.000107 u ppm 0.002551 > 100.00 2.136320 0.000107 u
Se (196.026 nm)-0.000851 u ppm 0.002090 > 100.00 4.493290 -0.000851 u
Si (288.158 nm)0.005226 ppm 0.001772 33.91 749.940000 0.005226
Sn (189.925 nm)0.000807 u ppm 0.001630 > 100.00 2.823070 0.000807 u
Sr (421.552 nm)0.000016 u ppm 0.000052 > 100.00 13.322126 0.000016 u
Th (288.505 nm)0.000493 u ppm 0.003292 > 100.00 261.448000 0.000493 u
Ti (336.122 nm)-0.000028 u ppm 0.000052 > 100.00 -121.103000 -0.000028 u
Tl (190.794 nm)0.000076 u ppm 0.000141 > 100.00 -2.406680 0.000076 u
U (409.013 nm)0.000223 u ppm 0.001818 > 100.00 24.350400 0.000223 u
V (292.401 nm)0.000097 u ppm 0.000134 > 100.00 -35.652000 0.000097 u
Zn (206.200 nm)-0.000720 u ppm 0.000710 98.65 2.610380 -0.000720 u
Zr (343.823 nm)-0.000065 u ppm 0.000062 95.20 -12.928000 -0.000065 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 208 of 287
Page 1079 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 2:19:41 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000087 ppm 0.000007 8.21 1143.562469 0.000087
Ag (328.068 nm)-0.000045 u ppm 0.000334 > 100.00 109.408000 -0.000045 u
Al (394.401 nm)51.768400 o ppm 0.065390 0.13 636433.000000 51.768400 o
Al H (396.152 nm)48.102000 ppm 0.217747 0.45 216231.000000 48.102000
As (188.980 nm)0.000782 u ppm 0.002515 > 100.00 -3.195270 0.000782 u
B (249.678 nm)-0.001785 u ppm 0.000409 22.91 1.240890 -0.001785 u
Ba (493.408 nm)0.000373 ppm 0.000248 66.41 194.631000 0.000373
Be (234.861 nm)-0.000022 u ppm 0.000037 > 100.00 672.238000 -0.000022 u
Bi (223.061 nm)-0.001715 u ppm 0.000633 36.95 1.535950 -0.001715 u
Ca (315.887 nm)-0.014471 u ppm 0.002785 19.24 -33.771866 -0.014471 u
Cd (214.439 nm)-0.000066 u ppm 0.000053 80.30 9.168010 -0.000066 u
Co (228.615 nm)0.000130 u ppm 0.000235 > 100.00 45.339700 0.000130 u
Cr (205.560 nm)0.000995 ppm 0.000646 64.90 5.617020 0.000995
Cu (324.754 nm)-0.000691 u ppm 0.000188 27.25 1665.230000 -0.000691 u
Fe (238.204 nm)49.408503 o ppm 0.221112 0.45 194508.669503 49.408503 o
Fe H (259.940 nm)47.738200 ppm 0.243276 0.51 77186.100000 47.738200
K (766.491 nm)0.042308 u ppm 0.050425 > 100.00 -371.400000 0.042308 u
Li (670.783 nm)0.017865 ppm 0.002042 11.43 -3616.200000 0.017865
Mg (279.078 nm)0.004379 ppm 0.001043 23.82 -163.624000 0.004379
Mn (257.610 nm)-0.000923 u ppm 0.000006 0.62 -241.728000 -0.000923 u
Mo (202.032 nm)0.000317 u ppm 0.000314 98.97 5.052650 0.000317 u
Na (589.592 nm)243.506000 o ppm 2.359870 0.97 2960890.000000 243.506000 o
Na H (589.593 nm)234.570621 ppm 3.819203 1.63 2145151.450068 234.570621
Ni (231.604 nm)-0.000655 u ppm 0.001334 > 100.00 -12.441700 -0.000655 u
P (213.618 nm)4.984140 ppm 0.015380 0.31 5886.360000 4.984140
Pb (220.353 nm)0.000372 u ppm 0.001343 > 100.00 -2.269820 0.000372 u
S (181.972 nm)4.763016 ppm 0.003640 0.08 995.919674 4.763016
Sb (206.834 nm)-0.000315 u ppm 0.001816 > 100.00 5.032280 -0.000315 u
Se (196.026 nm)0.006150 ppm 0.004717 76.69 3.614700 0.006150
Si (288.158 nm)0.032994 ppm 0.002441 7.40 951.388000 0.032994
Sn (189.925 nm)-0.000218 u ppm 0.001270 > 100.00 2.134740 -0.000218 u
Sr (421.552 nm)0.000491 ppm 0.000079 16.01 118.115122 0.000491
Th (288.505 nm)4.486010 Q ppm 0.003706 0.08 8644.250000 Q 4.486010 Q
Ti (336.122 nm)0.000744 ppm 0.000036 4.90 -36.868000 0.000744
Tl (190.794 nm)-0.002280 u ppm 0.001342 58.86 -5.852160 -0.002280 u
U (409.013 nm)2.359120 Q ppm 0.004274 0.18 10539.100000 Q 2.359120 Q
V (292.401 nm)0.000578 ppm 0.000046 8.02 263.020000 0.000578
Zn (206.200 nm)0.000262 u ppm 0.000368 > 100.00 4.728360 0.000262 u
Zr (343.823 nm)-0.000765 u ppm 0.000043 5.66 -3.265370 -0.000765 u
Test Report
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Page 1080 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 2:24:11 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.448066 Q ppm 0.000894 0.20 1148946.958923
Q 0.448066 Q
Ag (328.068 nm)0.506005 ppm 0.005155 1.02 27030.500000 0.506005
Al (394.401 nm)0.492126 ppm 0.001821 0.37 6513.050000 0.492126
Al H (396.152 nm)0.497072 u ppm 0.002634 0.53 2284.510000 0.497072 u
As (188.980 nm)0.504361 ppm 0.001034 0.21 415.635000 0.504361
B (249.678 nm)0.498216 ppm 0.000576 0.12 4186.080000 0.498216
Ba (493.408 nm)0.494964 ppm 0.000926 0.19 74970.500000 0.494964
Be (234.861 nm)0.501099 ppm 0.002532 0.51 83792.200000 0.501099
Bi (223.061 nm)0.991154 ppm 0.002875 0.29 1477.720000 0.991154
Ca (315.887 nm)4.920569 ppm 0.025648 0.52 3294.512980 4.920569
Cd (214.439 nm)0.499497 ppm 0.000870 0.17 7466.500000 0.499497
Co (228.615 nm)0.503808 ppm 0.001494 0.30 9669.920000 0.503808
Cr (205.560 nm)0.507136 ppm 0.000967 0.19 2085.990000 0.507136
Cu (324.754 nm)0.502107 ppm 0.001296 0.26 24181.200000 0.502107
Fe (238.204 nm)2.473163 ppm 0.014458 0.58 9758.198321 2.473163
Fe H (259.940 nm)2.481960 u ppm 0.005628 0.23 3881.370000 2.481960 u
K (766.491 nm)50.203700 ppm 0.306890 0.61 89751.100000 50.203700
Li (670.783 nm)0.504963 ppm 0.001183 0.23 14498.700000 0.504963
Mg (279.078 nm)19.950000 ppm 0.038923 0.20 66735.000000 19.950000
Mn (257.610 nm)0.491926 ppm 0.000792 0.16 131261.000000 0.491926
Mo (202.032 nm)0.496498 ppm 0.000632 0.13 2467.140000 0.496498
Na (589.592 nm)24.778600 ppm 0.122911 0.50 308024.000000 24.778600
Na H (589.593 nm)14.911804 u ppm 0.215052 1.44 226499.791072 14.911804 u
Ni (231.604 nm)0.505721 ppm 0.001472 0.29 1712.190000 0.505721
P (213.618 nm)0.008978 ppm 0.002144 23.88 -26.624400 0.008978
Pb (220.353 nm)0.533278 ppm 0.000820 0.15 1221.890000 0.533278
S (181.972 nm)0.017249 ppm 0.014940 86.62 30.070811 0.017249
Sb (206.834 nm)0.492079 ppm 0.002975 0.60 601.232000 0.492079
Se (196.026 nm)0.507141 ppm 0.004184 0.82 316.298000 0.507141
Si (288.158 nm)4.996030 ppm 0.022609 0.45 37252.700000 4.996030
Sn (189.925 nm)0.494016 ppm 0.004505 0.91 334.253000 0.494016
Sr (421.552 nm)0.496485 ppm 0.001419 0.29 109633.383109 0.496485
Th (288.505 nm)0.033400 ppm 0.003990 11.94 311.265000 0.033400
Ti (336.122 nm)0.497109 ppm 0.000654 0.13 54136.700000 0.497109
Tl (190.794 nm)0.494310 ppm 0.002884 0.58 533.142000 0.494310
U (409.013 nm)-0.008506 u ppm 0.001669 19.62 -27.596000 -0.008506 u
V (292.401 nm)0.495522 ppm 0.001085 0.22 20591.300000 0.495522
Zn (206.200 nm)0.499221 ppm 0.001251 0.25 1080.670000 0.499221
Zr (343.823 nm)0.492199 ppm 0.000681 0.14 40119.400000 0.492199
Test Report
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Page 1081 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 2:28:35 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000526 ppm 0.000007 1.32 757.566595 0.000526
Ag (328.068 nm)0.000210 ppm 0.000117 55.74 -18.198800 0.000210
Al (394.401 nm)-0.002112 u ppm 0.000271 12.85 425.547000 -0.002112 u
Al H (396.152 nm)-0.001544 u ppm 0.001291 83.57 43.623900 -0.001544 u
As (188.980 nm)0.001420 u ppm 0.002722 > 100.00 -2.224840 0.001420 u
B (249.678 nm)0.000741 ppm 0.000362 48.86 22.379600 0.000741
Ba (493.408 nm)0.000039 u ppm 0.000091 > 100.00 5.359670 0.000039 u
Be (234.861 nm)-0.000001 u ppm 0.000019 > 100.00 39.668300 -0.000001 u
Bi (223.061 nm)-0.000746 u ppm 0.000318 42.60 2.976070 -0.000746 u
Ca (315.887 nm)0.011394 ppm 0.005704 50.06 -16.328559 0.011394
Cd (214.439 nm)0.000055 ppm 0.000019 34.61 0.906010 0.000055
Co (228.615 nm)-0.000156 u ppm 0.000281 > 100.00 39.881200 -0.000156 u
Cr (205.560 nm)-0.000051 u ppm 0.000450 > 100.00 1.313870 -0.000051 u
Cu (324.754 nm)0.000750 ppm 0.000135 18.02 799.992000 0.000750
Fe (238.204 nm)0.000383 u ppm 0.001624 > 100.00 18.109834 0.000383 u
Fe H (259.940 nm)0.094013 u ppm 0.002705 2.88 13.453300 0.094013 u
K (766.491 nm)0.066187 ppm 0.016444 24.84 -328.497000 0.066187
Li (670.783 nm)0.011885 S ppm 0.001513 12.73 -3838.610000 S 0.011885 S
Mg (279.078 nm)0.000656 u ppm 0.001231 > 100.00 11.187200 0.000656 u
Mn (257.610 nm)-0.000023 u ppm 0.000010 44.95 -1.668420 -0.000023 u
Mo (202.032 nm)0.000671 ppm 0.000226 33.64 6.808080 0.000671
Na (589.592 nm)0.298953 ppm 0.016152 5.40 4671.520000 0.298953
Na H (589.593 nm)-9.545598 u ppm 0.022742 0.24 8112.263660 -9.545598 u
Ni (231.604 nm)-0.000189 u ppm 0.000929 > 100.00 -10.853300 -0.000189 u
P (213.618 nm)-0.001330 u ppm 0.000940 70.64 1.506970 -0.001330 u
Pb (220.353 nm)-0.000480 u ppm 0.000640 > 100.00 -2.726600 -0.000480 u
S (181.972 nm)-0.011028 u ppm 0.003451 31.29 21.823704 -0.011028 u
Sb (206.834 nm)-0.001242 u ppm 0.001977 > 100.00 0.488968 -0.001242 u
Se (196.026 nm)0.002243 u ppm 0.003935 > 100.00 6.391920 0.002243 u
Si (288.158 nm)0.005071 ppm 0.000878 17.32 748.031000 0.005071
Sn (189.925 nm)-0.001966 u ppm 0.000709 36.07 0.959583 -0.001966 u
Sr (421.552 nm)0.000150 ppm 0.000042 28.17 42.891992 0.000150
Th (288.505 nm)0.003135 ppm 0.002515 80.22 266.376000 0.003135
Ti (336.122 nm)0.000023 u ppm 0.000089 > 100.00 -115.611000 0.000023 u
Tl (190.794 nm)0.002345 ppm 0.000993 42.33 0.056634 0.002345
U (409.013 nm)-0.001379 u ppm 0.002176 > 100.00 17.341800 -0.001379 u
V (292.401 nm)0.000210 ppm 0.000312 > 100.00 -30.729800 0.000210
Zn (206.200 nm)-0.001108 u ppm 0.000407 36.71 1.773660 -0.001108 u
Zr (343.823 nm)0.000144 ppm 0.000031 21.22 4.114770 0.000144
Test Report
52A112023.esws
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Page 1082 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 2:32:38 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014122 ppm 0.000028 0.20 35716.418855 0.014122
Ag (328.068 nm)0.009734 ppm 0.000167 1.71 488.584000 0.009734
Al (394.401 nm)0.086677 ppm 0.000305 0.35 1528.320000 0.086677
Al H (396.152 nm)0.091664 u ppm 0.001319 1.44 462.521000 0.091664 u
As (188.980 nm)0.015225 ppm 0.002890 18.98 9.244700 0.015225
B (249.678 nm)0.096152 ppm 0.000991 1.03 820.939000 0.096152
Ba (493.408 nm)0.009893 ppm 0.000191 1.93 1498.040000 0.009893
Be (234.861 nm)0.000973 ppm 0.000018 1.85 203.624000 0.000973
Bi (223.061 nm)-0.001250 Qu ppm 0.001701 > 100.00 2.227150 Q -0.001250 Qu
Ca (315.887 nm)0.203993 ppm 0.005338 2.62 113.564042 0.203993
Cd (214.439 nm)0.004981 ppm 0.000076 1.53 74.541500 0.004981
Co (228.615 nm)0.010042 ppm 0.000199 1.98 234.702000 0.010042
Cr (205.560 nm)0.009494 ppm 0.000337 3.55 40.482200 0.009494
Cu (324.754 nm)0.015286 ppm 0.000226 1.48 1471.580000 0.015286
Fe (238.204 nm)0.099546 ppm 0.000534 0.54 408.519414 0.099546
Fe H (259.940 nm)0.188943 u ppm 0.000943 0.50 167.219000 0.188943 u
K (766.491 nm)3.007960 ppm 0.025010 0.83 4956.850000 3.007960
Li (670.783 nm)0.033042 Q ppm 0.001415 4.28 -3051.780000 Q 0.033042 Q
Mg (279.078 nm)0.197634 ppm 0.001037 0.52 669.388000 0.197634
Mn (257.610 nm)0.010054 ppm 0.000008 0.08 2686.960000 0.010054
Mo (202.032 nm)0.019704 ppm 0.000287 1.46 101.249000 0.019704
Na (589.592 nm)1.262240 ppm 0.007170 0.57 16496.700000 1.262240
Na H (589.593 nm)-8.644487 u ppm 0.005617 0.06 16086.646665 -8.644487 u
Ni (231.604 nm)0.041311 ppm 0.000824 1.99 130.469000 0.041311
P (213.618 nm)2.834280 ppm 0.015411 0.54 3347.920000 2.834280
Pb (220.353 nm)0.009825 ppm 0.001579 16.07 20.987100 0.009825
S (181.972 nm)0.086169 ppm 0.004678 5.43 41.683645 0.086169
Sb (206.834 nm)0.020209 ppm 0.001330 6.58 26.550700 0.020209
Se (196.026 nm)0.019150 ppm 0.001389 7.25 16.763100 0.019150
Si (288.158 nm)0.471415 ppm 0.004421 0.94 4166.730000 0.471415
Sn (189.925 nm)0.097244 ppm 0.002825 2.90 67.627700 0.097244
Sr (421.552 nm)0.009754 ppm 0.000057 0.58 2163.319427 0.009754
Th (288.505 nm)0.002333 Q ppm 0.001824 78.16 264.991000 Q 0.002333 Q
Ti (336.122 nm)0.009567 ppm 0.000081 0.85 926.229000 0.009567
Tl (190.794 nm)0.015768 ppm 0.003002 19.04 14.588800 0.015768
U (409.013 nm)0.054960 ppm 0.003212 5.84 265.106000 0.054960
V (292.401 nm)0.009797 ppm 0.000104 1.06 363.672000 0.009797
Zn (206.200 nm)0.019899 ppm 0.000405 2.03 47.071600 0.019899
Zr (343.823 nm)0.009692 ppm 0.000111 1.15 782.549000 0.009692
Test Report
52A112023.esws
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Page 1083 of 1261
Solution Name: MB 280-634511/1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
MB 280-634511/1-A 11/21/2023 2:36:58 AM 3:24 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000516 ppm 0.000010 1.89 730.516277 0.000516
Ag (328.068 nm)0.000058 u ppm 0.000172 > 100.00 -26.350000 0.000058 u
Al (394.401 nm)-0.000239 u ppm 0.000935 > 100.00 448.727000 -0.000239 u
Al H (396.152 nm)0.001028 u ppm 0.001482 > 100.00 55.185200 0.001028 u
As (188.980 nm)0.003138 ppm 0.000709 22.58 -0.797050 0.003138
B (249.678 nm)0.000193 u ppm 0.000359 > 100.00 17.793200 0.000193 u
Ba (493.408 nm)0.000454 ppm 0.000119 26.12 68.218800 0.000454
Be (234.861 nm)-0.000033 u ppm 0.000010 31.04 34.360000 -0.000033 u
Bi (223.061 nm)0.000173 u ppm 0.003946 > 100.00 4.342750 0.000173 u
Ca (315.887 nm)0.010458 ppm 0.008390 80.23 -16.959457 0.010458
Cd (214.439 nm)0.000057 u ppm 0.000100 > 100.00 0.934572 0.000057 u
Co (228.615 nm)-0.000131 u ppm 0.000086 65.29 40.338900 -0.000131 u
Cr (205.560 nm)-0.000358 u ppm 0.000290 80.98 0.048346 -0.000358 u
Cu (324.754 nm)0.000642 ppm 0.000222 34.61 794.888000 0.000642
Fe (238.204 nm)0.002801 ppm 0.000294 10.51 27.628850 0.002801
Fe H (259.940 nm)0.094690 u ppm 0.000412 0.44 14.550600 0.094690 u
K (766.491 nm)0.068869 ppm 0.044446 64.54 -323.678000 0.068869
Li (670.783 nm)0.013629 ppm 0.000759 5.57 -3773.740000 0.013629
Mg (279.078 nm)0.001141 u ppm 0.001790 > 100.00 12.791100 0.001141 u
Mn (257.610 nm)0.000026 ppm 0.000014 53.02 11.424700 0.000026
Mo (202.032 nm)0.000526 u ppm 0.000594 > 100.00 6.087910 0.000526 u
Na (589.592 nm)0.256780 ppm 0.009690 3.77 4161.350000 0.256780
Na H (589.593 nm)-9.681695 u ppm 0.021724 0.22 6922.653065 -9.681695 u
Ni (231.604 nm)0.000398 ppm 0.000151 38.00 -8.856300 0.000398
P (213.618 nm)0.000040 u ppm 0.003367 > 100.00 3.133730 0.000040 u
Pb (220.353 nm)0.001213 ppm 0.001625 > 100.00 1.165460 0.001213
S (181.972 nm)-0.006444 u ppm 0.006034 93.64 22.758350 -0.006444 u
Sb (206.834 nm)-0.002329 u ppm 0.001010 43.37 -0.834133 -0.002329 u
Se (196.026 nm)0.001703 ppm 0.001557 91.45 6.059870 0.001703
Si (288.158 nm)0.004707 ppm 0.002369 50.32 745.946000 0.004707
Sn (189.925 nm)-0.000105 u ppm 0.002261 > 100.00 2.210330 -0.000105 u
Sr (421.552 nm)0.000057 u ppm 0.000078 > 100.00 22.363900 0.000057 u
Th (288.505 nm)0.004575 ppm 0.002601 56.85 269.086000 0.004575
Ti (336.122 nm)0.000036 ppm 0.000020 55.99 -114.113000 0.000036
Tl (190.794 nm)0.001945 ppm 0.001214 62.43 -0.377251 0.001945
U (409.013 nm)0.000928 u ppm 0.003331 > 100.00 27.509100 0.000928 u
V (292.401 nm)0.000108 ppm 0.000036 33.61 -35.096600 0.000108
Zn (206.200 nm)-0.000921 u ppm 0.000266 28.90 2.176950 -0.000921 u
Zr (343.823 nm)-0.000015 u ppm 0.000078 > 100.00 -8.852520 -0.000015 u
Test Report
52A112023.esws
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Page 1084 of 1261
Solution Name: LCS 280-634511/2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634511/2-A 11/21/2023 2:41:02 AM 3:25 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.957395 ppm 0.006428 0.67 2455975.396855 0.957395
Ag (328.068 nm)0.051485 ppm 0.000020 0.04 2263.400000 0.051485
Al (394.401 nm)9.976570 o ppm 0.051238 0.51 123216.000000 9.976570 o
Al H (396.152 nm)9.513670 ppm 0.018152 0.19 42806.900000 9.513670
As (188.980 nm)1.014890 ppm 0.003792 0.37 839.755000 1.014890
B (249.678 nm)2.040370 ppm 0.008478 0.42 17093.400000 2.040370
Ba (493.408 nm)0.982833 ppm 0.003137 0.32 148881.000000 0.982833
Be (234.861 nm)1.004430 ppm 0.005531 0.55 167981.000000 1.004430
Bi (223.061 nm)-0.000512 u ppm 0.001099 > 100.00 3.323230 -0.000512 u
Ca (315.887 nm)49.368757 o ppm 0.099212 0.20 33271.219920 49.368757 o
Cd (214.439 nm)0.981570 ppm 0.005381 0.55 14673.500000 0.981570
Co (228.615 nm)0.974415 ppm 0.003970 0.41 18664.000000 0.974415
Cr (205.560 nm)0.991627 ppm 0.005370 0.54 4077.310000 0.991627
Cu (324.754 nm)0.972837 ppm 0.004705 0.48 46125.500000 0.972837
Fe (238.204 nm)9.879940 o ppm 0.020072 0.20 38920.294713 9.879940 o
Fe H (259.940 nm)9.700430 ppm 0.019525 0.20 15573.600000 9.700430
K (766.491 nm)50.372100 ppm 0.073080 0.15 90053.800000 50.372100
Li (670.783 nm)0.987647 ppm 0.003440 0.35 32449.400000 0.987647
Mg (279.078 nm)50.728600 o ppm 0.285971 0.56 169675.000000 50.728600 o
Mn (257.610 nm)0.989845 ppm 0.005326 0.54 264116.000000 0.989845
Mo (202.032 nm)1.001530 ppm 0.005912 0.59 4973.150000 1.001530
Na (589.592 nm)48.543300 ppm 0.145670 0.30 602602.000000 48.543300
Na H (589.593 nm)39.327822 u ppm 0.481566 1.22 444463.775142 39.327822 u
Ni (231.604 nm)0.966978 ppm 0.004907 0.51 3283.180000 0.966978
P (213.618 nm)20.438800 o ppm 0.104374 0.51 24053.800000 20.438800 o
Pb (220.353 nm)1.051570 ppm 0.005075 0.48 2409.980000 1.051570
S (181.972 nm)18.517537 o ppm 0.119620 0.65 3799.909918 18.517537 o
Sb (206.834 nm)1.033280 ppm 0.005326 0.52 1260.480000 1.033280
Se (196.026 nm)0.997465 ppm 0.007921 0.79 616.747000 0.997465
Si (288.158 nm)9.672310 ppm 0.005888 0.06 71469.800000 9.672310
Sn (189.925 nm)0.984964 ppm 0.009398 0.95 664.163000 0.984964
Sr (421.552 nm)0.986018 ppm 0.003092 0.31 217721.900429 0.986018
Th (288.505 nm)0.063282 ppm 0.003276 5.18 355.810000 0.063282
Ti (336.122 nm)0.996277 ppm 0.004781 0.48 108703.000000 0.996277
Tl (190.794 nm)0.969680 ppm 0.003600 0.37 1048.030000 0.969680
U (409.013 nm)-0.007604 u ppm 0.001323 17.40 -31.858800 -0.007604 u
V (292.401 nm)0.991024 ppm 0.005277 0.53 41231.100000 0.991024
Zn (206.200 nm)0.979093 ppm 0.005839 0.60 2115.440000 0.979093
Zr (343.823 nm)0.993757 ppm 0.005263 0.53 81016.200000 0.993757
Test Report
52A112023.esws
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Page 1085 of 1261
Solution Name: LCSD 280-634511/3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCSD 280-634511/3-A 11/21/2023 2:45:28 AM 3:26 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.966466 ppm 0.004038 0.42 2479259.328320 0.966466
Ag (328.068 nm)0.051872 ppm 0.000102 0.20 2278.220000 0.051872
Al (394.401 nm)10.076500 o ppm 0.037390 0.37 124442.000000 10.076500 o
Al H (396.152 nm)9.634860 ppm 0.036897 0.38 43351.600000 9.634860
As (188.980 nm)1.035980 ppm 0.006167 0.60 857.278000 1.035980
B (249.678 nm)2.062250 ppm 0.006567 0.32 17276.500000 2.062250
Ba (493.408 nm)0.998959 ppm 0.003627 0.36 151324.000000 0.998959
Be (234.861 nm)0.994174 ppm 0.005406 0.54 166270.000000 0.994174
Bi (223.061 nm)-0.001653 u ppm 0.000985 59.62 1.627540 -0.001653 u
Ca (315.887 nm)50.027232 o ppm 0.242067 0.48 33715.307786 50.027232 o
Cd (214.439 nm)0.990687 ppm 0.004786 0.48 14809.800000 0.990687
Co (228.615 nm)0.985566 ppm 0.004806 0.49 18876.800000 0.985566
Cr (205.560 nm)1.001410 ppm 0.005953 0.59 4117.540000 1.001410
Cu (324.754 nm)0.991509 ppm 0.006742 0.68 46999.100000 0.991509
Fe (238.204 nm)10.088358 o ppm 0.037108 0.37 39740.825443 10.088358 o
Fe H (259.940 nm)9.914480 ppm 0.036297 0.37 15920.300000 9.914480
K (766.491 nm)51.457200 ppm 0.148801 0.29 92003.300000 51.457200
Li (670.783 nm)1.013090 ppm 0.003974 0.39 33395.600000 1.013090
Mg (279.078 nm)51.189400 o ppm 0.244962 0.48 171215.000000 51.189400 o
Mn (257.610 nm)1.000350 ppm 0.004529 0.45 266920.000000 1.000350
Mo (202.032 nm)1.004720 ppm 0.004090 0.41 4988.980000 1.004720
Na (589.592 nm)49.525000 ppm 0.140212 0.28 614724.000000 49.525000
Na H (589.593 nm)39.553556 u ppm 0.538072 1.36 446579.807321 39.553556 u
Ni (231.604 nm)0.975616 ppm 0.003056 0.31 3312.600000 0.975616
P (213.618 nm)20.673700 o ppm 0.121583 0.59 24330.100000 20.673700 o
Pb (220.353 nm)1.067150 ppm 0.004021 0.38 2445.750000 1.067150
S (181.972 nm)18.770241 o ppm 0.085877 0.46 3851.446425 18.770241 o
Sb (206.834 nm)1.043240 ppm 0.002907 0.28 1272.660000 1.043240
Se (196.026 nm)1.011110 ppm 0.001293 0.13 625.108000 1.011110
Si (288.158 nm)9.694580 ppm 0.046468 0.48 71633.900000 9.694580
Sn (189.925 nm)0.988993 ppm 0.007776 0.79 666.871000 0.988993
Sr (421.552 nm)1.001847 ppm 0.003962 0.40 221216.858720 1.001847
Th (288.505 nm)0.066533 ppm 0.003390 5.10 361.841000 0.066533
Ti (336.122 nm)1.001810 ppm 0.004265 0.43 109308.000000 1.001810
Tl (190.794 nm)0.977925 ppm 0.005617 0.57 1056.980000 0.977925
U (409.013 nm)-0.007240 u ppm 0.002433 33.60 -30.017600 -0.007240 u
V (292.401 nm)1.001200 ppm 0.004194 0.42 41656.400000 1.001200
Zn (206.200 nm)0.992851 ppm 0.007450 0.75 2145.110000 0.992851
Zr (343.823 nm)0.998896 ppm 0.003749 0.38 81435.300000 0.998896
Test Report
52A112023.esws
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Page 1086 of 1261
Solution Name: 280-184010-E-18-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-18-A 11/21/2023 2:49:54 AM 3:27 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000756 ppm 0.000011 1.51 1401.426924 0.000756
Ag (328.068 nm)0.000141 ppm 0.000140 99.01 -21.713300 0.000141
Al (394.401 nm)0.068414 ppm 0.001142 1.67 1293.870000 0.068414
Al H (396.152 nm)0.074915 u ppm 0.002298 3.07 387.247000 0.074915 u
As (188.980 nm)0.001889 ppm 0.001050 55.60 -1.841750 0.001889
B (249.678 nm)0.012246 ppm 0.000856 6.99 118.678000 0.012246
Ba (493.408 nm)0.027860 ppm 0.000264 0.95 4221.000000 0.027860
Be (234.861 nm)0.000024 u ppm 0.000040 > 100.00 53.459900 0.000024 u
Bi (223.061 nm)-0.000869 u ppm 0.001438 > 100.00 2.792780 -0.000869 u
Ca (315.887 nm)1.110353 ppm 0.011192 1.01 724.830889 1.110353
Cd (214.439 nm)0.000246 ppm 0.000188 76.19 3.907580 0.000246
Co (228.615 nm)0.000069 u ppm 0.000163 > 100.00 44.178800 0.000069 u
Cr (205.560 nm)-0.000212 u ppm 0.000791 > 100.00 0.647498 -0.000212 u
Cu (324.754 nm)0.053061 ppm 0.000338 0.64 3240.490000 0.053061
Fe (238.204 nm)0.739582 ppm 0.004449 0.60 2927.900787 0.739582
Fe H (259.940 nm)0.809867 u ppm 0.005028 0.62 1172.970000 0.809867 u
K (766.491 nm)0.650969 ppm 0.009041 1.39 722.152000 0.650969
Li (670.783 nm)0.013055 ppm 0.000307 2.35 -3795.090000 0.013055
Mg (279.078 nm)0.571126 ppm 0.001862 0.33 1918.790000 0.571126
Mn (257.610 nm)0.031927 ppm 0.000081 0.25 8523.140000 0.031927
Mo (202.032 nm)0.000898 ppm 0.000332 36.93 7.934730 0.000898
Na (589.592 nm)1.385150 ppm 0.014502 1.05 18201.800000 1.385150
Na H (589.593 nm)-8.605110 u ppm 0.008072 0.09 16587.351507 -8.605110 u
Ni (231.604 nm)0.000764 u ppm 0.000692 90.55 -7.609240 0.000764 u
P (213.618 nm)0.003786 ppm 0.000269 7.11 4.795570 0.003786
Pb (220.353 nm)0.101193 ppm 0.001163 1.15 230.956000 0.101193
S (181.972 nm)0.898823 ppm 0.008615 0.96 207.196734 0.898823
Sb (206.834 nm)0.002265 ppm 0.000144 6.36 4.812460 0.002265
Se (196.026 nm)0.003004 ppm 0.001934 64.39 6.802540 0.003004
Si (288.158 nm)2.576320 ppm 0.006377 0.25 19429.900000 2.576320
Sn (189.925 nm)-0.001257 u ppm 0.001005 80.00 1.436550 -0.001257 u
Sr (421.552 nm)0.011581 ppm 0.000113 0.98 2566.703164 0.011581
Th (288.505 nm)0.002719 ppm 0.002216 81.52 266.245000 0.002719
Ti (336.122 nm)0.000502 ppm 0.000023 4.62 -60.983700 0.000502
Tl (190.794 nm)0.002038 u ppm 0.002771 > 100.00 -0.290731 0.002038 u
U (409.013 nm)0.002811 ppm 0.000857 30.50 36.484900 0.002811
V (292.401 nm)0.000253 ppm 0.000160 63.33 -29.055300 0.000253
Zn (206.200 nm)0.037838 ppm 0.000222 0.59 85.756000 0.037838
Zr (343.823 nm)0.000599 ppm 0.000087 14.58 42.171500 0.000599
Test Report
52A112023.esws
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Page 1087 of 1261
Solution Name: 280-184010-E-19-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-19-A 11/21/2023 2:54:15 AM 3:28 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000796 ppm 0.000016 1.99 1502.552541 0.000796
Ag (328.068 nm)0.000098 u ppm 0.000165 > 100.00 -23.801300 0.000098 u
Al (394.401 nm)0.140699 ppm 0.000860 0.61 2182.620000 0.140699
Al H (396.152 nm)0.149218 u ppm 0.000598 0.40 721.182000 0.149218 u
As (188.980 nm)0.003373 ppm 0.002583 76.57 -0.603789 0.003373
B (249.678 nm)0.010442 ppm 0.000456 4.37 103.573000 0.010442
Ba (493.408 nm)0.041643 ppm 0.000558 1.34 6306.890000 0.041643
Be (234.861 nm)0.000010 u ppm 0.000010 > 100.00 43.874600 0.000010 u
Bi (223.061 nm)-0.000485 u ppm 0.002732 > 100.00 3.363620 -0.000485 u
Ca (315.887 nm)0.957612 ppm 0.006636 0.69 621.818959 0.957612
Cd (214.439 nm)0.000158 ppm 0.000079 49.89 2.483720 0.000158
Co (228.615 nm)-0.000012 u ppm 0.000103 > 100.00 42.633600 -0.000012 u
Cr (205.560 nm)-0.000061 u ppm 0.000298 > 100.00 1.272100 -0.000061 u
Cu (324.754 nm)0.004421 ppm 0.000202 4.57 971.120000 0.004421
Fe (238.204 nm)0.182227 ppm 0.001588 0.87 733.922815 0.182227
Fe H (259.940 nm)0.270492 u ppm 0.002363 0.87 299.309000 0.270492 u
K (766.491 nm)0.416918 ppm 0.037051 8.89 301.643000 0.416918
Li (670.783 nm)0.014931 ppm 0.000575 3.85 -3725.320000 0.014931
Mg (279.078 nm)0.395512 ppm 0.001605 0.41 1331.760000 0.395512
Mn (257.610 nm)0.046167 ppm 0.000074 0.16 12322.700000 0.046167
Mo (202.032 nm)0.000344 u ppm 0.000629 > 100.00 5.182800 0.000344 u
Na (589.592 nm)1.985190 ppm 0.008869 0.45 25657.100000 1.985190
Na H (589.593 nm)-8.011054 u ppm 0.008391 0.10 21907.196918 -8.011054 u
Ni (231.604 nm)0.001415 ppm 0.000912 64.43 -5.391820 0.001415
P (213.618 nm)0.000952 u ppm 0.000836 87.81 4.025930 0.000952 u
Pb (220.353 nm)0.009709 ppm 0.000319 3.28 20.671800 0.009709
S (181.972 nm)1.377739 ppm 0.014844 1.08 304.715716 1.377739
Sb (206.834 nm)0.000899 u ppm 0.003120 > 100.00 3.111420 0.000899 u
Se (196.026 nm)0.001731 ppm 0.001206 69.66 6.088910 0.001731
Si (288.158 nm)2.390310 ppm 0.004548 0.19 18078.900000 2.390310
Sn (189.925 nm)0.000063 u ppm 0.001243 > 100.00 2.323330 0.000063 u
Sr (421.552 nm)0.011266 ppm 0.000103 0.91 2497.156406 0.011266
Th (288.505 nm)0.005286 ppm 0.001087 20.57 271.352000 0.005286
Ti (336.122 nm)0.000197 ppm 0.000029 14.54 -94.538500 0.000197
Tl (190.794 nm)0.002224 ppm 0.002105 94.67 -0.077758 0.002224
U (409.013 nm)-0.002568 u ppm 0.005803 > 100.00 12.290500 -0.002568 u
V (292.401 nm)0.000287 ppm 0.000103 35.79 -27.281700 0.000287
Zn (206.200 nm)0.010445 ppm 0.000708 6.78 26.686500 0.010445
Zr (343.823 nm)0.000025 u ppm 0.000037 > 100.00 -5.380360 0.000025 u
Test Report
52A112023.esws
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Page 1088 of 1261
Solution Name: 280-184010-E-20-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-20-A 11/21/2023 2:58:33 AM 3:29 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001222 ppm 0.000008 0.65 2846.256612 0.001222
Ag (328.068 nm)0.000292 ppm 0.000098 33.43 -14.565300 0.000292
Al (394.401 nm)0.293492 ppm 0.000335 0.11 4060.590000 0.293492
Al H (396.152 nm)0.267281 u ppm 0.004677 1.75 1251.780000 0.267281 u
As (188.980 nm)0.001348 ppm 0.000579 42.92 -2.499350 0.001348
B (249.678 nm)0.035073 ppm 0.000259 0.74 309.731000 0.035073
Ba (493.408 nm)0.151572 ppm 0.000791 0.52 23023.400000 0.151572
Be (234.861 nm)0.000060 ppm 0.000045 74.90 360.682000 0.000060
Bi (223.061 nm)-0.001272 u ppm 0.000416 32.72 2.193910 -0.001272 u
Ca (315.887 nm)14.215789 o ppm 0.066462 0.47 9563.387146 14.215789 o
Cd (214.439 nm)0.000204 ppm 0.000049 24.14 8.049540 0.000204
Co (228.615 nm)0.001708 ppm 0.000148 8.68 75.521200 0.001708
Cr (205.560 nm)0.001432 ppm 0.000298 20.77 7.411780 0.001432
Cu (324.754 nm)0.001117 ppm 0.000099 8.82 839.530000 0.001117
Fe (238.204 nm)24.141236 o ppm 0.097544 0.40 95046.384571 24.141236 o
Fe H (259.940 nm)23.421700 ppm 0.121244 0.52 37799.000000 23.421700
K (766.491 nm)1.614840 ppm 0.032179 1.99 2453.900000 1.614840
Li (670.783 nm)0.011859 ppm 0.001186 10.00 -3839.580000 0.011859
Mg (279.078 nm)6.413660 ppm 0.014983 0.23 21445.300000 6.413660
Mn (257.610 nm)0.130866 ppm 0.000327 0.25 34922.400000 0.130866
Mo (202.032 nm)0.000539 ppm 0.000271 50.23 6.152080 0.000539
Na (589.592 nm)112.017000 o ppm 1.118840 1.00 1364400.000000 112.017000 o
Na H (589.593 nm)102.207751 ppm 1.824655 1.79 987736.234944 102.207751
Ni (231.604 nm)0.001547 ppm 0.000766 49.48 -4.943250 0.001547
P (213.618 nm)0.059510 ppm 0.002073 3.48 73.348000 0.059510
Pb (220.353 nm)0.001100 u ppm 0.001684 > 100.00 0.860183 0.001100 u
S (181.972 nm)0.691517 ppm 0.005622 0.81 166.216844 0.691517
Sb (206.834 nm)-0.000237 u ppm 0.001170 > 100.00 3.379200 -0.000237 u
Se (196.026 nm)0.003210 ppm 0.002826 88.06 4.542850 0.003210
Si (288.158 nm)7.312750 ppm 0.046583 0.64 53844.300000 7.312750
Sn (189.925 nm)0.001727 ppm 0.000524 30.33 3.441510 0.001727
Sr (421.552 nm)0.073321 ppm 0.000420 0.57 16199.026686 0.073321
Th (288.505 nm)0.013932 ppm 0.001328 9.53 288.448000 0.013932
Ti (336.122 nm)0.002987 ppm 0.000090 3.02 238.832000 0.002987
Tl (190.794 nm)-0.000364 u ppm 0.001067 > 100.00 -3.319040 -0.000364 u
U (409.013 nm)-0.002666 u ppm 0.001961 73.57 35.251900 -0.002666 u
V (292.401 nm)0.002643 ppm 0.000257 9.70 71.935600 0.002643
Zn (206.200 nm)0.009664 ppm 0.000333 3.44 25.001400 0.009664
Zr (343.823 nm)0.002428 ppm 0.000163 6.69 222.927000 0.002428
Test Report
52A112023.esws
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Page 1089 of 1261
Solution Name: 280-184010-E-21-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-21-A 11/21/2023 3:03:02 AM 3:30 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001064 ppm 0.000003 0.26 2210.823062 0.001064
Ag (328.068 nm)0.000189 u ppm 0.000213 > 100.00 -19.207600 0.000189 u
Al (394.401 nm)0.054454 ppm 0.001276 2.34 1121.770000 0.054454
Al H (396.152 nm)0.059262 u ppm 0.000071 0.12 316.900000 0.059262 u
As (188.980 nm)0.001119 u ppm 0.001348 > 100.00 -2.476270 0.001119 u
B (249.678 nm)0.009889 ppm 0.000448 4.53 98.948900 0.009889
Ba (493.408 nm)0.043460 ppm 0.000301 0.69 6582.050000 0.043460
Be (234.861 nm)-0.000037 u ppm 0.000010 28.17 35.959500 -0.000037 u
Bi (223.061 nm)-0.000819 u ppm 0.001127 > 100.00 2.866740 -0.000819 u
Ca (315.887 nm)1.399571 ppm 0.008210 0.59 919.884677 1.399571
Cd (214.439 nm)0.000980 ppm 0.000044 4.54 14.757100 0.000980
Co (228.615 nm)0.000444 ppm 0.000103 23.23 51.326000 0.000444
Cr (205.560 nm)-0.000236 u ppm 0.000519 > 100.00 0.550157 -0.000236 u
Cu (324.754 nm)0.057720 ppm 0.000396 0.69 3457.250000 0.057720
Fe (238.204 nm)0.175357 ppm 0.003559 2.03 706.890423 0.175357
Fe H (259.940 nm)0.264417 u ppm 0.000863 0.33 289.469000 0.264417 u
K (766.491 nm)0.746055 ppm 0.035038 4.70 892.989000 0.746055
Li (670.783 nm)0.013132 ppm 0.001565 11.92 -3792.230000 0.013132
Mg (279.078 nm)0.536768 ppm 0.001359 0.25 1804.220000 0.536768
Mn (257.610 nm)0.033377 ppm 0.000175 0.52 8910.170000 0.033377
Mo (202.032 nm)0.000541 ppm 0.000348 64.31 6.162860 0.000541
Na (589.592 nm)2.620050 ppm 0.008963 0.34 33394.200000 2.620050
Na H (589.593 nm)-7.398777 u ppm 0.034926 0.47 27282.243801 -7.398777 u
Ni (231.604 nm)0.001971 ppm 0.000391 19.86 -3.498220 0.001971
P (213.618 nm)0.002738 ppm 0.001486 54.27 3.334950 0.002738
Pb (220.353 nm)0.070254 ppm 0.001268 1.80 159.845000 0.070254
S (181.972 nm)2.136665 ppm 0.018734 0.88 459.266963 2.136665
Sb (206.834 nm)-0.001311 u ppm 0.000906 69.13 0.416732 -0.001311 u
Se (196.026 nm)0.004113 ppm 0.004404 > 100.00 7.542980 0.004113
Si (288.158 nm)1.363130 ppm 0.004029 0.30 10615.800000 1.363130
Sn (189.925 nm)0.000500 ppm 0.000269 53.77 2.616770 0.000500
Sr (421.552 nm)0.021903 ppm 0.000134 0.61 4845.757937 0.021903
Th (288.505 nm)0.001723 u ppm 0.001940 > 100.00 264.427000 0.001723 u
Ti (336.122 nm)0.000180 ppm 0.000113 62.62 -95.433500 0.000180
Tl (190.794 nm)0.001916 ppm 0.001916 100.00 -0.410762 0.001916
U (409.013 nm)0.003176 ppm 0.002791 87.86 37.574000 0.003176
V (292.401 nm)0.000138 ppm 0.000104 75.69 -33.788000 0.000138
Zn (206.200 nm)0.213335 ppm 0.001766 0.83 464.192000 0.213335
Zr (343.823 nm)0.000159 ppm 0.000087 54.60 5.520970 0.000159
Test Report
52A112023.esws
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Page 1090 of 1261
Solution Name: 280-184010-E-22-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-22-A 11/21/2023 3:07:18 AM 3:31 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000771 ppm 0.000009 1.19 1412.189050 0.000771
Ag (328.068 nm)0.000001 u ppm 0.000151 > 100.00 -29.436400 0.000001 u
Al (394.401 nm)0.015869 ppm 0.000494 3.11 647.500000 0.015869
Al H (396.152 nm)0.018767 u ppm 0.001524 8.12 134.906000 0.018767 u
As (188.980 nm)0.003438 ppm 0.000799 23.23 -0.551076 0.003438
B (249.678 nm)0.011686 ppm 0.000253 2.16 113.990000 0.011686
Ba (493.408 nm)0.007493 ppm 0.000200 2.66 1135.320000 0.007493
Be (234.861 nm)0.000000 u ppm 0.000046 > 100.00 44.791600 0.000000 u
Bi (223.061 nm)-0.001953 u ppm 0.000804 41.19 1.181250 -0.001953 u
Ca (315.887 nm)0.878150 ppm 0.004268 0.49 568.228723 0.878150
Cd (214.439 nm)0.000177 ppm 0.000052 29.48 2.806760 0.000177
Co (228.615 nm)-0.000046 u ppm 0.000099 > 100.00 41.978600 -0.000046 u
Cr (205.560 nm)-0.000146 u ppm 0.000250 > 100.00 0.925543 -0.000146 u
Cu (324.754 nm)0.004269 ppm 0.000209 4.89 963.627000 0.004269
Fe (238.204 nm)0.388103 ppm 0.002568 0.66 1544.334668 0.388103
Fe H (259.940 nm)0.466634 u ppm 0.003965 0.85 617.013000 0.466634 u
K (766.491 nm)1.046670 ppm 0.008639 0.83 1433.100000 1.046670
Li (670.783 nm)0.011528 ppm 0.001093 9.48 -3851.880000 0.011528
Mg (279.078 nm)0.418929 ppm 0.001298 0.31 1409.980000 0.418929
Mn (257.610 nm)0.014960 ppm 0.000080 0.54 3996.050000 0.014960
Mo (202.032 nm)0.000557 ppm 0.000431 77.42 6.243340 0.000557
Na (589.592 nm)2.142350 ppm 0.011884 0.55 27166.500000 2.142350
Na H (589.593 nm)-7.861888 u ppm 0.096090 1.22 22916.959988 -7.861888 u
Ni (231.604 nm)0.000195 u ppm 0.000370 > 100.00 -9.545330 0.000195 u
P (213.618 nm)0.002892 ppm 0.000392 13.54 6.326140 0.002892
Pb (220.353 nm)-0.000387 u ppm 0.001021 > 100.00 -2.513610 -0.000387 u
S (181.972 nm)0.446202 ppm 0.006922 1.55 114.990942 0.446202
Sb (206.834 nm)0.002115 ppm 0.000878 41.51 4.608370 0.002115
Se (196.026 nm)0.002821 ppm 0.002066 73.23 6.715880 0.002821
Si (288.158 nm)1.061970 ppm 0.004818 0.45 8427.480000 1.061970
Sn (189.925 nm)-0.001324 u ppm 0.000532 40.18 1.391340 -0.001324 u
Sr (421.552 nm)0.008130 ppm 0.000007 0.09 1804.812499 0.008130
Th (288.505 nm)0.000812 u ppm 0.002636 > 100.00 262.381000 0.000812 u
Ti (336.122 nm)0.000080 ppm 0.000064 79.87 -107.525000 0.000080
Tl (190.794 nm)0.002082 ppm 0.000634 30.45 -0.235404 0.002082
U (409.013 nm)-0.000440 u ppm 0.004286 > 100.00 21.823900 -0.000440 u
V (292.401 nm)0.000134 ppm 0.000095 70.84 -34.174300 0.000134
Zn (206.200 nm)0.003936 ppm 0.000642 16.31 12.651400 0.003936
Zr (343.823 nm)0.000123 ppm 0.000077 62.79 2.861050 0.000123
Test Report
52A112023.esws
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Page 1091 of 1261
Solution Name: 280-184010-E-23-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-23-A 11/21/2023 3:11:45 AM 3:32 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000963 ppm 0.000006 0.59 1912.851359 0.000963
Ag (328.068 nm)0.000140 ppm 0.000031 22.31 -22.774900 0.000140
Al (394.401 nm)0.097293 ppm 0.000798 0.82 1652.330000 0.097293
Al H (396.152 nm)0.100852 u ppm 0.003329 3.30 503.814000 0.100852 u
As (188.980 nm)0.002108 ppm 0.000204 9.68 -1.677430 0.002108
B (249.678 nm)0.011922 ppm 0.000377 3.17 115.963000 0.011922
Ba (493.408 nm)0.006754 ppm 0.000252 3.73 1029.980000 0.006754
Be (234.861 nm)-0.000026 u ppm 0.000014 51.92 70.903800 -0.000026 u
Bi (223.061 nm)-0.001885 u ppm 0.000187 9.95 1.283040 -0.001885 u
Ca (315.887 nm)0.253795 ppm 0.000534 0.21 147.151901 0.253795
Cd (214.439 nm)0.000000 u ppm 0.000023 > 100.00 0.644176 0.000000 u
Co (228.615 nm)0.000008 u ppm 0.000154 > 100.00 43.027000 0.000008 u
Cr (205.560 nm)0.000342 u ppm 0.000656 > 100.00 2.928120 0.000342 u
Cu (324.754 nm)0.009408 ppm 0.000216 2.30 1204.350000 0.009408
Fe (238.204 nm)2.752537 ppm 0.006777 0.25 10851.713584 2.752537
Fe H (259.940 nm)2.753080 u ppm 0.009566 0.35 4320.520000 2.753080 u
K (766.491 nm)1.168160 ppm 0.022380 1.92 1651.370000 1.168160
Li (670.783 nm)0.012950 ppm 0.001578 12.18 -3798.990000 0.012950
Mg (279.078 nm)0.120156 ppm 0.000264 0.22 409.442000 0.120156
Mn (257.610 nm)0.003189 ppm 0.000005 0.16 855.304000 0.003189
Mo (202.032 nm)0.000403 ppm 0.000222 55.14 5.478130 0.000403
Na (589.592 nm)2.247420 ppm 0.011919 0.53 28434.700000 2.247420
Na H (589.593 nm)-7.836051 u ppm 0.024296 0.31 23136.484287 -7.836051 u
Ni (231.604 nm)0.000209 u ppm 0.000636 > 100.00 -9.497280 0.000209 u
P (213.618 nm)0.012638 ppm 0.001555 12.31 17.572400 0.012638
Pb (220.353 nm)0.004566 ppm 0.000367 8.04 8.859330 0.004566
S (181.972 nm)0.966341 ppm 0.010193 1.05 220.974470 0.966341
Sb (206.834 nm)0.000520 u ppm 0.001737 > 100.00 2.827800 0.000520 u
Se (196.026 nm)0.000991 u ppm 0.003299 > 100.00 5.337470 0.000991 u
Si (288.158 nm)1.491910 ppm 0.006522 0.44 11551.300000 1.491910
Sn (189.925 nm)-0.000792 u ppm 0.001983 > 100.00 1.748500 -0.000792 u
Sr (421.552 nm)0.003729 ppm 0.000005 0.13 833.124573 0.003729
Th (288.505 nm)0.004732 ppm 0.002075 43.84 269.339000 0.004732
Ti (336.122 nm)0.001095 ppm 0.000032 2.93 1.853510 0.001095
Tl (190.794 nm)0.001814 ppm 0.000621 34.27 -0.569768 0.001814
U (409.013 nm)-0.000558 u ppm 0.002251 > 100.00 23.437600 -0.000558 u
V (292.401 nm)0.000304 ppm 0.000165 54.19 -27.948100 0.000304
Zn (206.200 nm)0.009134 ppm 0.000543 5.95 23.858500 0.009134
Zr (343.823 nm)0.000284 ppm 0.000054 18.86 19.247100 0.000284
Test Report
52A112023.esws
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Page 1092 of 1261
Solution Name: 280-184010-E-24-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-24-A 11/21/2023 3:16:08 AM 3:33 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.004157 ppm 0.000017 0.42 10318.217047 0.004157
Ag (328.068 nm)0.000532 ppm 0.000094 17.68 -1.092710 0.000532
Al (394.401 nm)0.019638 ppm 0.000622 3.17 691.288000 0.019638
Al H (396.152 nm)0.006513 u ppm 0.003597 55.23 79.833100 0.006513 u
As (188.980 nm)0.001886 u ppm 0.003728 > 100.00 -1.840800 0.001886 u
B (249.678 nm)0.045001 ppm 0.000343 0.76 392.827000 0.045001
Ba (493.408 nm)0.055566 ppm 0.000505 0.91 8416.140000 0.055566
Be (234.861 nm)0.000059 ppm 0.000012 20.01 54.432900 0.000059
Bi (223.061 nm)-0.001519 u ppm 0.002062 > 100.00 1.826050 -0.001519 u
Ca (315.887 nm)28.700222 o ppm 0.120329 0.42 19331.965138 28.700222 o
Cd (214.439 nm)0.000318 ppm 0.000211 66.31 4.907500 0.000318
Co (228.615 nm)-0.000163 u ppm 0.000313 > 100.00 39.738200 -0.000163 u
Cr (205.560 nm)0.000114 u ppm 0.000242 > 100.00 1.987560 0.000114 u
Cu (324.754 nm)0.001389 ppm 0.000152 10.97 814.543000 0.001389
Fe (238.204 nm)0.371833 ppm 0.003562 0.96 1480.297804 0.371833
Fe H (259.940 nm)0.453447 u ppm 0.001917 0.42 595.654000 0.453447 u
K (766.491 nm)3.438980 ppm 0.028513 0.83 5731.240000 3.438980
Li (670.783 nm)0.016005 ppm 0.002138 13.36 -3685.370000 0.016005
Mg (279.078 nm)4.616590 ppm 0.017447 0.38 15449.400000 4.616590
Mn (257.610 nm)0.034255 ppm 0.000128 0.37 9144.520000 0.034255
Mo (202.032 nm)0.001742 ppm 0.000312 17.90 12.121700 0.001742
Na (589.592 nm)18.883000 ppm 0.014919 0.08 231215.000000 18.883000
Na H (589.593 nm)8.890962 u ppm 0.169177 1.90 169990.203179 8.890962 u
Ni (231.604 nm)-0.000391 u ppm 0.000954 > 100.00 -11.542400 -0.000391 u
P (213.618 nm)0.009817 ppm 0.001725 17.57 14.601400 0.009817
Pb (220.353 nm)-0.001399 u ppm 0.001411 > 100.00 -4.822600 -0.001399 u
S (181.972 nm)6.443298 ppm 0.053921 0.84 1336.855472 6.443298
Sb (206.834 nm)-0.000243 u ppm 0.001230 > 100.00 1.729220 -0.000243 u
Se (196.026 nm)0.002521 u ppm 0.002921 > 100.00 6.546430 0.002521 u
Si (288.158 nm)4.683030 ppm 0.014522 0.31 34736.800000 4.683030
Sn (189.925 nm)-0.000117 u ppm 0.001416 > 100.00 2.202350 -0.000117 u
Sr (421.552 nm)0.127095 ppm 0.000909 0.72 28072.098437 0.127095
Th (288.505 nm)0.012589 ppm 0.003959 31.45 284.840000 0.012589
Ti (336.122 nm)-0.000107 u ppm 0.000048 45.35 -66.912900 -0.000107 u
Tl (190.794 nm)0.001555 ppm 0.001259 80.95 -0.810713 0.001555
U (409.013 nm)0.009261 ppm 0.002815 30.39 64.758700 0.009261
V (292.401 nm)0.000851 ppm 0.000257 30.17 -3.616610 0.000851
Zn (206.200 nm)0.005125 ppm 0.000578 11.28 15.214900 0.005125
Zr (343.823 nm)0.000166 ppm 0.000012 7.01 6.404170 0.000166
Test Report
52A112023.esws
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Page 1093 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 3:20:30 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000079 ppm 0.000014 17.54 1124.192691 0.000079
Ag (328.068 nm)0.000134 u ppm 0.000242 > 100.00 119.421000 0.000134 u
Al (394.401 nm)51.920500 o ppm 0.172948 0.33 638300.000000 51.920500 o
Al H (396.152 nm)48.498500 ppm 0.085500 0.18 218013.000000 48.498500
As (188.980 nm)0.001313 ppm 0.001000 76.11 -2.756910 0.001313
B (249.678 nm)-0.002426 u ppm 0.000112 4.63 -4.124920 -0.002426 u
Ba (493.408 nm)0.000215 ppm 0.000076 35.46 171.580000 0.000215
Be (234.861 nm)-0.000025 u ppm 0.000027 > 100.00 676.315000 -0.000025 u
Bi (223.061 nm)-0.000958 u ppm 0.001468 > 100.00 2.660130 -0.000958 u
Ca (315.887 nm)-0.022472 u ppm 0.002078 9.25 -39.168428 -0.022472 u
Cd (214.439 nm)0.000028 u ppm 0.000133 > 100.00 10.653500 0.000028 u
Co (228.615 nm)0.000535 ppm 0.000200 37.44 53.052400 0.000535
Cr (205.560 nm)0.000911 ppm 0.000135 14.86 5.270720 0.000911
Cu (324.754 nm)-0.000440 u ppm 0.000221 50.14 1681.130000 -0.000440 u
Fe (238.204 nm)49.772473 o ppm 0.070895 0.14 195941.413880 49.772473 o
Fe H (259.940 nm)48.062900 ppm 0.059188 0.12 77712.000000 48.062900
K (766.491 nm)0.030542 ppm 0.028798 94.29 -392.540000 0.030542
Li (670.783 nm)0.013020 ppm 0.000574 4.41 -3796.380000 0.013020
Mg (279.078 nm)0.004624 ppm 0.001107 23.93 -163.668000 0.004624
Mn (257.610 nm)-0.000907 u ppm 0.000023 2.53 -237.524000 -0.000907 u
Mo (202.032 nm)0.000313 u ppm 0.000394 > 100.00 5.032830 0.000313 u
Na (589.592 nm)245.830000 o ppm 0.387768 0.16 2989140.000000 245.830000 o
Na H (589.593 nm)235.888375 ppm 2.314585 0.98 2156688.261597 235.888375
Ni (231.604 nm)-0.000415 u ppm 0.000263 63.50 -11.622500 -0.000415 u
P (213.618 nm)4.999760 ppm 0.028789 0.58 5904.780000 4.999760
Pb (220.353 nm)0.001515 ppm 0.000880 58.10 0.326044 0.001515
S (181.972 nm)4.724939 ppm 0.023952 0.51 988.175535 4.724939
Sb (206.834 nm)0.001044 u ppm 0.003819 > 100.00 6.711620 0.001044 u
Se (196.026 nm)0.003610 ppm 0.000854 23.65 2.017490 0.003610
Si (288.158 nm)0.028854 ppm 0.002842 9.85 921.527000 0.028854
Sn (189.925 nm)0.000367 u ppm 0.001088 > 100.00 2.527740 0.000367 u
Sr (421.552 nm)0.000491 ppm 0.000050 10.13 118.198644 0.000491
Th (288.505 nm)4.507190 ppm 0.011703 0.26 8683.790000 4.507190
Ti (336.122 nm)0.000697 ppm 0.000022 3.16 -42.069200 0.000697
Tl (190.794 nm)-0.004123 u ppm 0.002620 63.54 -7.858820 -0.004123 u
U (409.013 nm)2.365090 Q ppm 0.012712 0.54 10566.000000 Q 2.365090 Q
V (292.401 nm)0.000737 ppm 0.000090 12.27 270.989000 0.000737
Zn (206.200 nm)0.001196 ppm 0.001091 91.22 6.742590 0.001196
Zr (343.823 nm)-0.000769 u ppm 0.000038 4.92 -3.042670 -0.000769 u
Test Report
52A112023.esws
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Page 1094 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 3:25:00 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.446778 Q ppm 0.001063 0.24 1145646.816653
Q 0.446778 Q
Ag (328.068 nm)0.504709 ppm 0.002542 0.50 26961.400000 0.504709
Al (394.401 nm)0.490664 ppm 0.001461 0.30 6488.270000 0.490664
Al H (396.152 nm)0.495146 u ppm 0.002414 0.49 2275.850000 0.495146 u
As (188.980 nm)0.504703 ppm 0.002515 0.50 415.920000 0.504703
B (249.678 nm)0.496919 ppm 0.001293 0.26 4175.220000 0.496919
Ba (493.408 nm)0.492780 ppm 0.001819 0.37 74639.900000 0.492780
Be (234.861 nm)0.500561 ppm 0.002097 0.42 83702.300000 0.500561
Bi (223.061 nm)0.992780 ppm 0.008330 0.84 1480.140000 0.992780
Ca (315.887 nm)4.929504 ppm 0.028651 0.58 3300.538711 4.929504
Cd (214.439 nm)0.500857 ppm 0.002280 0.46 7486.830000 0.500857
Co (228.615 nm)0.503649 ppm 0.001786 0.35 9666.860000 0.503649
Cr (205.560 nm)0.506743 ppm 0.000653 0.13 2084.370000 0.506743
Cu (324.754 nm)0.501067 ppm 0.001533 0.31 24137.900000 0.501067
Fe (238.204 nm)2.471711 ppm 0.008876 0.36 9752.505101 2.471711
Fe H (259.940 nm)2.479010 u ppm 0.008360 0.34 3876.590000 2.479010 u
K (766.491 nm)50.063700 ppm 0.030247 0.06 89499.700000 50.063700
Li (670.783 nm)0.497617 ppm 0.001768 0.36 14225.500000 0.497617
Mg (279.078 nm)20.007000 ppm 0.042433 0.21 66924.800000 20.007000
Mn (257.610 nm)0.492808 ppm 0.001152 0.23 131496.000000 0.492808
Mo (202.032 nm)0.496462 ppm 0.001170 0.24 2466.960000 0.496462
Na (589.592 nm)24.548200 ppm 0.024010 0.10 305196.000000 24.548200
Na H (589.593 nm)14.412001 u ppm 0.182227 1.26 222104.984784 14.412001 u
Ni (231.604 nm)0.509263 ppm 0.002393 0.47 1724.250000 0.509263
P (213.618 nm)0.007511 ppm 0.004374 58.23 -28.301700 0.007511
Pb (220.353 nm)0.531580 ppm 0.001376 0.26 1217.990000 0.531580
S (181.972 nm)-0.006649 u ppm 0.007798 > 100.00 25.199964 -0.006649 u
Sb (206.834 nm)0.488360 ppm 0.001777 0.36 596.695000 0.488360
Se (196.026 nm)0.505393 ppm 0.001370 0.27 315.225000 0.505393
Si (288.158 nm)4.935420 ppm 0.021052 0.43 36811.800000 4.935420
Sn (189.925 nm)0.492767 ppm 0.003675 0.75 333.413000 0.492767
Sr (421.552 nm)0.494098 ppm 0.002076 0.42 109106.162709 0.494098
Th (288.505 nm)0.035993 ppm 0.001079 3.00 316.104000 0.035993
Ti (336.122 nm)0.496637 ppm 0.000981 0.20 54085.200000 0.496637
Tl (190.794 nm)0.495977 ppm 0.003312 0.67 534.953000 0.495977
U (409.013 nm)-0.009180 u ppm 0.003111 33.89 -30.176100 -0.009180 u
V (292.401 nm)0.495811 ppm 0.000881 0.18 20605.900000 0.495811
Zn (206.200 nm)0.500603 ppm 0.001149 0.23 1083.640000 0.500603
Zr (343.823 nm)0.491856 ppm 0.001399 0.28 40091.500000 0.491856
Test Report
52A112023.esws
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Page 1095 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 3:29:21 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000519 ppm 0.000013 2.55 737.927440 0.000519
Ag (328.068 nm)0.000209 ppm 0.000078 37.23 -17.687800 0.000209
Al (394.401 nm)-0.002488 u ppm 0.000443 17.83 421.012000 -0.002488 u
Al H (396.152 nm)-0.000799 u ppm 0.001625 > 100.00 46.974800 -0.000799 u
As (188.980 nm)0.002091 ppm 0.002147 > 100.00 -1.667100 0.002091
B (249.678 nm)-0.000181 u ppm 0.000350 > 100.00 14.664100 -0.000181 u
Ba (493.408 nm)0.000103 u ppm 0.000110 > 100.00 14.931000 0.000103 u
Be (234.861 nm)0.000015 u ppm 0.000017 > 100.00 42.315300 0.000015 u
Bi (223.061 nm)-0.000130 u ppm 0.001565 > 100.00 3.891420 -0.000130 u
Ca (315.887 nm)0.008458 ppm 0.007741 91.53 -18.308416 0.008458
Cd (214.439 nm)0.000119 ppm 0.000146 > 100.00 1.856340 0.000119
Co (228.615 nm)-0.000108 u ppm 0.000085 79.51 40.797400 -0.000108 u
Cr (205.560 nm)-0.000510 u ppm 0.000697 > 100.00 -0.576878 -0.000510 u
Cu (324.754 nm)0.000756 ppm 0.000140 18.49 800.226000 0.000756
Fe (238.204 nm)0.000853 ppm 0.000382 44.79 19.963378 0.000853
Fe H (259.940 nm)0.094762 u ppm 0.001639 1.73 14.666500 0.094762 u
K (766.491 nm)0.028095 u ppm 0.043677 > 100.00 -396.935000 0.028095 u
Li (670.783 nm)0.012260 S ppm 0.001022 8.33 -3824.640000 S 0.012260 S
Mg (279.078 nm)0.000358 u ppm 0.001885 > 100.00 10.193800 0.000358 u
Mn (257.610 nm)-0.000013 u ppm 0.000035 > 100.00 1.056430 -0.000013 u
Mo (202.032 nm)0.001194 ppm 0.000191 16.01 9.403480 0.001194
Na (589.592 nm)0.146363 ppm 0.010146 6.93 2815.990000 0.146363
Na H (589.593 nm)-9.933872 u ppm 0.013834 0.14 4712.663605 -9.933872 u
Ni (231.604 nm)0.000178 u ppm 0.000717 > 100.00 -9.604270 0.000178 u
P (213.618 nm)-0.000001 u ppm 0.001706 > 100.00 3.060230 -0.000001 u
Pb (220.353 nm)-0.000030 u ppm 0.000471 > 100.00 -1.692660 -0.000030 u
S (181.972 nm)-0.019277 u ppm 0.008338 43.25 20.146718 -0.019277 u
Sb (206.834 nm)0.002069 ppm 0.001494 72.22 4.521740 0.002069
Se (196.026 nm)0.002251 u ppm 0.002304 > 100.00 6.396340 0.002251 u
Si (288.158 nm)0.001235 ppm 0.000732 59.23 720.058000 0.001235
Sn (189.925 nm)-0.002115 u ppm 0.001180 55.78 0.859587 -0.002115 u
Sr (421.552 nm)0.000099 u ppm 0.000090 91.41 31.507550 0.000099 u
Th (288.505 nm)0.004364 ppm 0.000150 3.44 268.719000 0.004364
Ti (336.122 nm)0.000069 ppm 0.000090 > 100.00 -110.518000 0.000069
Tl (190.794 nm)0.001862 ppm 0.001152 61.86 -0.469543 0.001862
U (409.013 nm)-0.001317 u ppm 0.003292 > 100.00 17.612200 -0.001317 u
V (292.401 nm)0.000101 ppm 0.000062 60.96 -35.289800 0.000101
Zn (206.200 nm)-0.000961 u ppm 0.000340 35.35 2.091310 -0.000961 u
Zr (343.823 nm)0.000099 u ppm 0.000117 > 100.00 0.425969 0.000099 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 225 of 287
Page 1096 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 3:33:23 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014131 ppm 0.000033 0.23 35735.264682 0.014131
Ag (328.068 nm)0.009896 ppm 0.000171 1.73 497.636000 0.009896
Al (394.401 nm)0.087246 ppm 0.000930 1.07 1535.020000 0.087246
Al H (396.152 nm)0.094433 u ppm 0.003097 3.28 474.967000 0.094433 u
As (188.980 nm)0.015088 ppm 0.001702 11.28 9.130730 0.015088
B (249.678 nm)0.096988 ppm 0.000704 0.73 827.940000 0.096988
Ba (493.408 nm)0.009806 ppm 0.000111 1.14 1484.900000 0.009806
Be (234.861 nm)0.000937 ppm 0.000005 0.55 197.625000 0.000937
Bi (223.061 nm)0.000114 Qu ppm 0.001426 > 100.00 4.255290 Q 0.000114 Qu
Ca (315.887 nm)0.204399 ppm 0.010833 5.30 113.838210 0.204399
Cd (214.439 nm)0.005091 ppm 0.000038 0.75 76.192200 0.005091
Co (228.615 nm)0.010099 ppm 0.000082 0.81 235.794000 0.010099
Cr (205.560 nm)0.010056 ppm 0.000472 4.69 42.793500 0.010056
Cu (324.754 nm)0.015330 ppm 0.000114 0.74 1473.830000 0.015330
Fe (238.204 nm)0.100762 ppm 0.001768 1.75 413.307132 0.100762
Fe H (259.940 nm)0.188998 u ppm 0.003084 1.63 167.308000 0.188998 u
K (766.491 nm)3.029700 ppm 0.016404 0.54 4995.910000 3.029700
Li (670.783 nm)0.032868 Q ppm 0.003616 11.00 -3058.260000 Q 0.032868 Q
Mg (279.078 nm)0.199294 ppm 0.001751 0.88 674.950000 0.199294
Mn (257.610 nm)0.010085 ppm 0.000026 0.26 2695.240000 0.010085
Mo (202.032 nm)0.020033 ppm 0.000184 0.92 102.882000 0.020033
Na (589.592 nm)1.141460 ppm 0.017119 1.50 15027.900000 1.141460
Na H (589.593 nm)-8.983056 u ppm 0.015107 0.17 13122.307272 -8.983056 u
Ni (231.604 nm)0.041275 ppm 0.000644 1.56 130.345000 0.041275
P (213.618 nm)2.846510 ppm 0.007124 0.25 3362.360000 2.846510
Pb (220.353 nm)0.010909 ppm 0.000736 6.75 23.476500 0.010909
S (181.972 nm)0.073002 ppm 0.007660 10.49 39.000028 0.073002
Sb (206.834 nm)0.019616 ppm 0.002053 10.47 25.828200 0.019616
Se (196.026 nm)0.018061 ppm 0.000972 5.38 16.094600 0.018061
Si (288.158 nm)0.469236 ppm 0.003239 0.69 4150.500000 0.469236
Sn (189.925 nm)0.095925 ppm 0.001850 1.93 66.741000 0.095925
Sr (421.552 nm)0.009650 ppm 0.000093 0.97 2140.356731 0.009650
Th (288.505 nm)0.004454 Q ppm 0.001264 28.39 268.956000 Q 0.004454 Q
Ti (336.122 nm)0.009543 ppm 0.000040 0.41 923.631000 0.009543
Tl (190.794 nm)0.016601 ppm 0.000472 2.84 15.492300 0.016601
U (409.013 nm)0.055297 ppm 0.003259 5.89 266.599000 0.055297
V (292.401 nm)0.009587 ppm 0.000233 2.43 354.894000 0.009587
Zn (206.200 nm)0.019537 ppm 0.000826 4.23 46.292500 0.019537
Zr (343.823 nm)0.009766 ppm 0.000108 1.10 788.616000 0.009766
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 226 of 287
Page 1097 of 1261
Solution Name: 280-184010-E-25-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-25-A 11/21/2023 3:37:39 AM 3:34 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001165 ppm 0.000007 0.60 2471.087189 0.001165
Ag (328.068 nm)0.000163 u ppm 0.000151 92.42 -21.911500 0.000163 u
Al (394.401 nm)0.480463 ppm 0.003671 0.76 6366.750000 0.480463
Al H (396.152 nm)0.497727 u ppm 0.004327 0.87 2287.450000 0.497727 u
As (188.980 nm)0.003292 ppm 0.001339 40.68 -0.717698 0.003292
B (249.678 nm)0.011088 ppm 0.000353 3.19 108.982000 0.011088
Ba (493.408 nm)0.019304 ppm 0.000421 2.18 2938.480000 0.019304
Be (234.861 nm)-0.000004 u ppm 0.000022 > 100.00 109.828000 -0.000004 u
Bi (223.061 nm)0.000029 u ppm 0.001107 > 100.00 4.127800 0.000029 u
Ca (315.887 nm)1.897562 ppm 0.019141 1.01 1255.739719 1.897562
Cd (214.439 nm)0.000173 ppm 0.000029 16.95 3.785980 0.000173
Co (228.615 nm)0.000679 ppm 0.000056 8.26 56.085100 0.000679
Cr (205.560 nm)0.001247 ppm 0.000501 40.17 6.649170 0.001247
Cu (324.754 nm)0.002990 ppm 0.000157 5.25 907.625000 0.002990
Fe (238.204 nm)5.484796 o ppm 0.043669 0.80 21607.004763 5.484796 o
Fe H (259.940 nm)5.370690 ppm 0.032871 0.61 8560.450000 5.370690
K (766.491 nm)1.148810 ppm 0.029357 2.56 1616.600000 1.148810
Li (670.783 nm)0.010916 ppm 0.000557 5.10 -3874.620000 0.010916
Mg (279.078 nm)0.822356 ppm 0.001355 0.16 2756.360000 0.822356
Mn (257.610 nm)0.033190 ppm 0.000051 0.15 8860.390000 0.033190
Mo (202.032 nm)0.000682 ppm 0.000472 69.19 6.863410 0.000682
Na (589.592 nm)5.185380 ppm 0.023062 0.44 64294.000000 5.185380
Na H (589.593 nm)-4.922096 u ppm 0.110879 2.25 48755.067074 -4.922096 u
Ni (231.604 nm)0.001341 ppm 0.000228 17.00 -5.644230 0.001341
P (213.618 nm)0.063631 ppm 0.002285 3.59 78.098700 0.063631
Pb (220.353 nm)0.002556 ppm 0.000474 18.55 4.179200 0.002556
S (181.972 nm)1.538347 ppm 0.007374 0.48 337.625994 1.538347
Sb (206.834 nm)0.000543 u ppm 0.002799 > 100.00 3.027560 0.000543 u
Se (196.026 nm)0.000612 u ppm 0.003785 > 100.00 4.838110 0.000612 u
Si (288.158 nm)2.824400 ppm 0.007467 0.26 21234.500000 2.824400
Sn (189.925 nm)0.001237 ppm 0.000671 54.27 3.112370 0.001237
Sr (421.552 nm)0.012290 ppm 0.000112 0.91 2723.395962 0.012290
Th (288.505 nm)0.006692 ppm 0.000724 10.81 273.476000 0.006692
Ti (336.122 nm)0.007591 ppm 0.000212 2.79 714.244000 0.007591
Tl (190.794 nm)-0.000452 u ppm 0.001894 > 100.00 -3.090030 -0.000452 u
U (409.013 nm)0.004073 ppm 0.002007 49.28 46.483100 0.004073
V (292.401 nm)0.001805 ppm 0.000124 6.87 35.107200 0.001805
Zn (206.200 nm)0.016615 ppm 0.001056 6.36 39.991000 0.016615
Zr (343.823 nm)0.001395 ppm 0.000013 0.96 113.476000 0.001395
Test Report
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Page 1098 of 1261
Solution Name: 280-184010-E-25-A SD @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-25-A SD
@5
11/21/2023 3:42:05 AM 3:35 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000622 ppm 0.000011 1.84 1015.913825 0.000622
Ag (328.068 nm)0.000059 u ppm 0.000221 > 100.00 -26.545000 0.000059 u
Al (394.401 nm)0.094433 ppm 0.001220 1.29 1613.540000 0.094433
Al H (396.152 nm)0.102089 u ppm 0.001206 1.18 509.375000 0.102089 u
As (188.980 nm)0.002275 ppm 0.001450 63.73 -1.523750 0.002275
B (249.678 nm)0.001516 ppm 0.000094 6.23 28.867900 0.001516
Ba (493.408 nm)0.004161 ppm 0.000023 0.56 632.700000 0.004161
Be (234.861 nm)-0.000014 u ppm 0.000009 65.16 51.882600 -0.000014 u
Bi (223.061 nm)0.000589 u ppm 0.001814 > 100.00 4.960420 0.000589 u
Ca (315.887 nm)0.389710 ppm 0.011850 3.04 238.815203 0.389710
Cd (214.439 nm)0.000056 u ppm 0.000132 > 100.00 1.136250 0.000056 u
Co (228.615 nm)-0.000043 u ppm 0.000096 > 100.00 42.068700 -0.000043 u
Cr (205.560 nm)0.000637 ppm 0.000306 48.08 4.143590 0.000637
Cu (324.754 nm)0.001065 ppm 0.000282 26.50 815.849000 0.001065
Fe (238.204 nm)1.112780 ppm 0.003725 0.33 4396.961808 1.112780
Fe H (259.940 nm)1.175620 u ppm 0.004148 0.35 1765.410000 1.175620 u
K (766.491 nm)0.224141 ppm 0.065095 29.04 -44.708800 0.224141
Li (670.783 nm)-0.010803 u ppm 0.036429 > 100.00 -4682.350000 -0.010803 u
Mg (279.078 nm)0.171897 ppm 0.001242 0.72 583.219000 0.171897
Mn (257.610 nm)0.006867 ppm 0.000040 0.59 1836.760000 0.006867
Mo (202.032 nm)0.000609 ppm 0.000287 47.12 6.497790 0.000609
Na (589.592 nm)1.183030 ppm 0.040022 3.38 15466.300000 1.183030
Na H (589.593 nm)-8.512199 u ppm 0.400796 4.71 17194.807987 -8.512199 u
Ni (231.604 nm)0.000202 u ppm 0.000823 > 100.00 -9.522260 0.000202 u
P (213.618 nm)0.012518 ppm 0.002325 18.57 17.849000 0.012518
Pb (220.353 nm)-0.000025 u ppm 0.000476 > 100.00 -1.694920 -0.000025 u
S (181.972 nm)0.294148 ppm 0.004483 1.52 84.025289 0.294148
Sb (206.834 nm)0.001305 ppm 0.000962 73.77 3.668770 0.001305
Se (196.026 nm)0.000575 u ppm 0.002586 > 100.00 5.256380 0.000575 u
Si (288.158 nm)0.569357 ppm 0.003185 0.56 4848.860000 0.569357
Sn (189.925 nm)0.000353 u ppm 0.001833 > 100.00 2.517870 0.000353 u
Sr (421.552 nm)0.002568 ppm 0.000087 3.37 576.684111 0.002568
Th (288.505 nm)0.004820 ppm 0.001486 30.84 269.622000 0.004820
Ti (336.122 nm)0.001420 ppm 0.000102 7.21 37.661000 0.001420
Tl (190.794 nm)0.001571 ppm 0.000804 51.22 -0.805674 0.001571
U (409.013 nm)-0.000281 u ppm 0.002724 > 100.00 23.266200 -0.000281 u
V (292.401 nm)0.000353 ppm 0.000045 12.83 -24.805800 0.000353
Zn (206.200 nm)0.003554 ppm 0.001191 33.50 11.827200 0.003554
Zr (343.823 nm)0.000249 ppm 0.000126 50.47 14.179500 0.000249
Test Report
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Page 1099 of 1261
Solution Name: 280-184010-E-25-B MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-25-B MS 11/21/2023 3:46:25 AM 3:36 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.968634 ppm 0.004902 0.51 2484891.526163 0.968634
Ag (328.068 nm)0.052178 ppm 0.000037 0.07 2297.420000 0.052178
Al (394.401 nm)10.819100 o ppm 0.061836 0.57 133578.000000 10.819100 o
Al H (396.152 nm)10.296500 ppm 0.038907 0.38 46325.100000 10.296500
As (188.980 nm)1.029370 ppm 0.007576 0.74 851.734000 1.029370
B (249.678 nm)2.067090 ppm 0.013681 0.66 17317.000000 2.067090
Ba (493.408 nm)1.006520 ppm 0.002249 0.22 152485.000000 1.006520
Be (234.861 nm)1.007930 ppm 0.005923 0.59 168639.000000 1.007930
Bi (223.061 nm)-0.001672 u ppm 0.000204 12.22 1.599010 -0.001672 u
Ca (315.887 nm)51.415716 o ppm 0.136560 0.27 34651.727615 51.415716 o
Cd (214.439 nm)0.984541 ppm 0.005939 0.60 14719.000000 0.984541
Co (228.615 nm)0.991323 ppm 0.006524 0.66 18987.000000 0.991323
Cr (205.560 nm)1.005560 ppm 0.004862 0.48 4134.610000 1.005560
Cu (324.754 nm)0.993115 ppm 0.008726 0.88 47080.800000 0.993115
Fe (238.204 nm)15.512758 o ppm 0.057219 0.37 61093.414690 15.512758 o
Fe H (259.940 nm)15.187000 ppm 0.045370 0.30 24460.600000 15.187000
K (766.491 nm)52.287200 ppm 0.144912 0.28 93494.400000 52.287200
Li (670.783 nm)1.001790 ppm 0.003822 0.38 32975.400000 1.001790
Mg (279.078 nm)51.940300 o ppm 0.297852 0.57 173723.000000 51.940300 o
Mn (257.610 nm)1.031260 ppm 0.005258 0.51 275167.000000 1.031260
Mo (202.032 nm)1.004370 ppm 0.005471 0.54 4987.260000 1.004370
Na (589.592 nm)54.232000 ppm 0.136613 0.25 672031.000000 54.232000
Na H (589.593 nm)44.867835 u ppm 0.433885 0.97 493170.421330 44.867835 u
Ni (231.604 nm)0.980785 ppm 0.008457 0.86 3330.190000 0.980785
P (213.618 nm)20.619400 o ppm 0.136687 0.66 24265.900000 20.619400 o
Pb (220.353 nm)1.056670 ppm 0.005900 0.56 2421.560000 1.056670
S (181.972 nm)20.502547 o ppm 0.132417 0.65 4204.473782 20.502547 o
Sb (206.834 nm)1.047210 ppm 0.005167 0.49 1277.870000 1.047210
Se (196.026 nm)1.005590 ppm 0.008642 0.86 621.168000 1.005590
Si (288.158 nm)13.056900 o ppm 0.106301 0.81 96065.100000 13.056900 o
Sn (189.925 nm)0.990552 ppm 0.000473 0.05 667.918000 0.990552
Sr (421.552 nm)1.003199 ppm 0.002736 0.27 221515.566543 1.003199
Th (288.505 nm)0.067114 ppm 0.001768 2.63 363.420000 0.067114
Ti (336.122 nm)1.010730 ppm 0.005183 0.51 110285.000000 1.010730
Tl (190.794 nm)0.974091 ppm 0.002136 0.22 1052.720000 0.974091
U (409.013 nm)-0.011447 u ppm 0.000976 8.53 -43.182900 -0.011447 u
V (292.401 nm)0.998309 ppm 0.004927 0.49 41534.900000 0.998309
Zn (206.200 nm)1.000140 ppm 0.006422 0.64 2160.830000 1.000140
Zr (343.823 nm)0.999001 ppm 0.004759 0.48 81451.200000 0.999001
Test Report
52A112023.esws
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Page 1100 of 1261
Solution Name: 280-184010-E-25-C MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-25-C MSD 11/21/2023 3:50:53 AM 3:37 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.989347 ppm 0.003304 0.33 2538035.077521 0.989347
Ag (328.068 nm)0.052696 ppm 0.000119 0.23 2315.340000 0.052696
Al (394.401 nm)11.031800 o ppm 0.034110 0.31 136195.000000 11.031800 o
Al H (396.152 nm)10.551200 ppm 0.045055 0.43 47469.700000 10.551200
As (188.980 nm)1.046330 ppm 0.007485 0.72 865.823000 1.046330
B (249.678 nm)2.106400 ppm 0.006201 0.29 17646.000000 2.106400
Ba (493.408 nm)1.035200 ppm 0.006334 0.61 156829.000000 1.035200
Be (234.861 nm)1.021520 ppm 0.006830 0.67 170915.000000 1.021520
Bi (223.061 nm)-0.000280 u ppm 0.001101 > 100.00 3.668360 -0.000280 u
Ca (315.887 nm)52.783552 o ppm 0.185031 0.35 35574.222747 52.783552 o
Cd (214.439 nm)1.002970 ppm 0.005660 0.56 14994.500000 1.002970
Co (228.615 nm)1.010480 ppm 0.004345 0.43 19353.000000 1.010480
Cr (205.560 nm)1.021660 ppm 0.003063 0.30 4200.760000 1.021660
Cu (324.754 nm)1.016040 ppm 0.002723 0.27 48150.100000 1.016040
Fe (238.204 nm)15.909337 o ppm 0.046013 0.29 62654.731707 15.909337 o
Fe H (259.940 nm)15.576400 ppm 0.049328 0.32 25091.400000 15.576400
K (766.491 nm)53.272600 ppm 0.114360 0.21 95264.900000 53.272600
Li (670.783 nm)1.024420 ppm 0.004008 0.39 33817.000000 1.024420
Mg (279.078 nm)52.966500 o ppm 0.215584 0.41 177155.000000 52.966500 o
Mn (257.610 nm)1.050590 ppm 0.004311 0.41 280326.000000 1.050590
Mo (202.032 nm)1.024160 ppm 0.005886 0.57 5085.430000 1.024160
Na (589.592 nm)55.149200 o ppm 0.268175 0.49 683513.000000 55.149200 o
Na H (589.593 nm)45.958574 u ppm 0.689359 1.50 502965.978695 45.958574 u
Ni (231.604 nm)1.000870 ppm 0.002762 0.28 3398.600000 1.000870
P (213.618 nm)21.010400 o ppm 0.064074 0.30 24725.800000 21.010400 o
Pb (220.353 nm)1.077010 ppm 0.006337 0.59 2468.200000 1.077010
S (181.972 nm)20.791202 o ppm 0.111012 0.53 4263.369760 20.791202 o
Sb (206.834 nm)1.060110 ppm 0.003348 0.32 1293.570000 1.060110
Se (196.026 nm)1.031310 ppm 0.003154 0.31 636.926000 1.031310
Si (288.158 nm)13.246400 o ppm 0.021778 0.16 97450.900000 13.246400 o
Sn (189.925 nm)1.006560 ppm 0.004543 0.45 678.678000 1.006560
Sr (421.552 nm)1.030438 ppm 0.006179 0.60 227529.924255 1.030438
Th (288.505 nm)0.069508 ppm 0.002453 3.53 367.458000 0.069508
Ti (336.122 nm)1.029920 ppm 0.003338 0.32 112382.000000 1.029920
Tl (190.794 nm)0.992262 ppm 0.011017 1.11 1072.400000 0.992262
U (409.013 nm)-0.008691 u ppm 0.003133 36.05 -31.185700 -0.008691 u
V (292.401 nm)1.017550 ppm 0.003705 0.36 42336.800000 1.017550
Zn (206.200 nm)1.039780 ppm 0.005216 0.50 2246.320000 1.039780
Zr (343.823 nm)1.016910 ppm 0.003440 0.34 82911.500000 1.016910
Test Report
52A112023.esws
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Page 1101 of 1261
Solution Name: 280-184010-E-25-A PDS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-25-A PDS 11/21/2023 3:55:25 AM 3:38 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.085992 ppm 0.000278 0.32 220474.026919 0.085992
Ag (328.068 nm)0.050570 ppm 0.000325 0.64 2668.160000 0.050570
Al (394.401 nm)1.465010 ppm 0.008698 0.59 18479.200000 1.465010
Al H (396.152 nm)1.432210 ppm 0.004072 0.28 6487.230000 1.432210
As (188.980 nm)0.204923 ppm 0.002701 1.32 166.805000 0.204923
B (249.678 nm)0.118230 ppm 0.001851 1.57 1005.730000 0.118230
Ba (493.408 nm)0.114683 ppm 0.000040 0.04 17386.400000 0.114683
Be (234.861 nm)0.049954 ppm 0.000423 0.85 8467.530000 0.049954
Bi (223.061 nm)0.000033 u ppm 0.000920 > 100.00 4.134080 0.000033 u
Ca (315.887 nm)21.645142 o ppm 0.042174 0.19 14573.884130 21.645142 o
Cd (214.439 nm)0.050167 ppm 0.000319 0.64 751.218000 0.050167
Co (228.615 nm)0.050679 ppm 0.000262 0.52 1011.470000 0.050679
Cr (205.560 nm)0.051278 ppm 0.000885 1.73 212.288000 0.051278
Cu (324.754 nm)0.052804 ppm 0.000156 0.30 3234.020000 0.052804
Fe (238.204 nm)6.341355 o ppm 0.014913 0.24 24979.397490 6.341355 o
Fe H (259.940 nm)6.213470 ppm 0.017985 0.29 9925.560000 6.213470
K (766.491 nm)21.139400 ppm 0.105321 0.50 37532.800000 21.139400
Li (670.783 nm)0.108941 ppm 0.001618 1.49 -229.133000 0.108941
Mg (279.078 nm)20.762700 ppm 0.076784 0.37 69437.600000 20.762700
Mn (257.610 nm)0.081838 ppm 0.000333 0.41 21840.500000 0.081838
Mo (202.032 nm)0.050524 ppm 0.000533 1.05 254.182000 0.050524
Na (589.592 nm)24.632200 ppm 0.167769 0.68 301790.000000 24.632200
Na H (589.593 nm)15.810181 u ppm 2.541324 16.07 231074.417286 15.810181 u
Ni (231.604 nm)0.049083 ppm 0.000787 1.60 157.068000 0.049083
P (213.618 nm)2.072160 ppm 0.017011 0.82 2445.310000 2.072160
Pb (220.353 nm)0.106752 ppm 0.001213 1.14 244.195000 0.106752
S (181.972 nm)1.543832 ppm 0.005355 0.35 339.739326 1.543832
Sb (206.834 nm)0.099943 ppm 0.001264 1.26 124.159000 0.099943
Se (196.026 nm)0.197008 ppm 0.002019 1.02 125.303000 0.197008
Si (288.158 nm)7.675460 ppm 0.043726 0.57 56506.700000 7.675460
Sn (189.925 nm)0.058864 ppm 0.002036 3.46 41.836500 0.058864
Sr (421.552 nm)0.061082 ppm 0.000031 0.05 13496.522774 0.061082
Th (288.505 nm)0.201677 ppm 0.002592 1.29 639.666000 0.201677
Ti (336.122 nm)0.056747 ppm 0.000157 0.28 6121.370000 0.056747
Tl (190.794 nm)0.195527 ppm 0.000560 0.29 209.607000 0.195527
U (409.013 nm)0.471895 ppm 0.001696 0.36 2109.830000 0.471895
V (292.401 nm)0.051227 ppm 0.000096 0.19 2083.440000 0.051227
Zn (206.200 nm)0.213705 ppm 0.001724 0.81 464.989000 0.213705
Zr (343.823 nm)0.051573 ppm 0.000103 0.20 4205.080000 0.051573
Test Report
52A112023.esws
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Page 1102 of 1261
Solution Name: 280-184010-E-26-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-26-A 11/21/2023 3:59:45 AM 3:39 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.001171 ppm 0.000008 0.68 2491.003644 0.001171
Ag (328.068 nm)0.000233 ppm 0.000179 76.88 -18.141300 0.000233
Al (394.401 nm)0.491655 ppm 0.003235 0.66 6503.890000 0.491655
Al H (396.152 nm)0.509441 u ppm 0.001195 0.23 2340.090000 0.509441 u
As (188.980 nm)0.003710 ppm 0.001461 39.37 -0.372965 0.003710
B (249.678 nm)0.013631 ppm 0.000193 1.41 130.269000 0.013631
Ba (493.408 nm)0.019374 ppm 0.000296 1.53 2949.770000 0.019374
Be (234.861 nm)0.000059 ppm 0.000014 23.15 123.221000 0.000059
Bi (223.061 nm)-0.000116 u ppm 0.002234 > 100.00 3.912870 -0.000116 u
Ca (315.887 nm)1.902468 ppm 0.011405 0.60 1259.048346 1.902468
Cd (214.439 nm)0.000189 ppm 0.000035 18.63 4.071950 0.000189
Co (228.615 nm)0.000516 ppm 0.000141 27.29 52.957400 0.000516
Cr (205.560 nm)0.001727 ppm 0.000583 33.77 8.623790 0.001727
Cu (324.754 nm)0.003163 ppm 0.000197 6.23 916.323000 0.003163
Fe (238.204 nm)5.714687 o ppm 0.009966 0.17 22511.948535 5.714687 o
Fe H (259.940 nm)5.595890 ppm 0.010102 0.18 8925.220000 5.595890
K (766.491 nm)1.171060 ppm 0.027776 2.37 1656.570000 1.171060
Li (670.783 nm)0.009982 ppm 0.001365 13.67 -3909.370000 0.009982
Mg (279.078 nm)0.852543 ppm 0.004954 0.58 2857.220000 0.852543
Mn (257.610 nm)0.034303 ppm 0.000244 0.71 9157.240000 0.034303
Mo (202.032 nm)0.000661 ppm 0.000389 58.89 6.756130 0.000661
Na (589.592 nm)5.287970 ppm 0.061370 1.16 65542.100000 5.287970
Na H (589.593 nm)-3.684696 u ppm 0.262467 7.12 59588.275168 -3.684696 u
Ni (231.604 nm)0.001363 ppm 0.001200 88.05 -5.569280 0.001363
P (213.618 nm)0.062734 ppm 0.001985 3.16 77.027400 0.062734
Pb (220.353 nm)0.003172 ppm 0.001518 47.86 5.586290 0.003172
S (181.972 nm)1.558063 ppm 0.008659 0.56 341.657779 1.558063
Sb (206.834 nm)0.001691 u ppm 0.001635 96.69 4.446510 0.001691 u
Se (196.026 nm)0.001942 u ppm 0.003686 > 100.00 5.631400 0.001942 u
Si (288.158 nm)2.929610 ppm 0.018179 0.62 21998.300000 2.929610
Sn (189.925 nm)-0.000919 u ppm 0.001022 > 100.00 1.663190 -0.000919 u
Sr (421.552 nm)0.012417 ppm 0.000105 0.84 2751.372314 0.012417
Th (288.505 nm)0.008482 ppm 0.002069 24.39 276.825000 0.008482
Ti (336.122 nm)0.007413 ppm 0.000257 3.47 694.934000 0.007413
Tl (190.794 nm)0.000970 u ppm 0.001508 > 100.00 -1.548970 0.000970 u
U (409.013 nm)-0.000963 u ppm 0.001029 > 100.00 24.534800 -0.000963 u
V (292.401 nm)0.001837 ppm 0.000156 8.51 36.621800 0.001837
Zn (206.200 nm)0.016827 ppm 0.000148 0.88 40.448100 0.016827
Zr (343.823 nm)0.001553 ppm 0.000065 4.16 126.692000 0.001553
Test Report
52A112023.esws
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Page 1103 of 1261
Solution Name: 280-184010-E-27-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184010-E-27-A 11/21/2023 4:04:09 AM 3:40 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000917 ppm 0.000012 1.31 1810.960608 0.000917
Ag (328.068 nm)0.000121 ppm 0.000088 73.18 -22.302100 0.000121
Al (394.401 nm)0.165823 ppm 0.002176 1.31 2491.100000 0.165823
Al H (396.152 nm)0.173003 u ppm 0.000937 0.54 828.073000 0.173003 u
As (188.980 nm)0.003557 ppm 0.001060 29.80 -0.456195 0.003557
B (249.678 nm)0.010620 ppm 0.000228 2.14 105.068000 0.010620
Ba (493.408 nm)0.014087 ppm 0.000106 0.75 2135.320000 0.014087
Be (234.861 nm)0.000003 u ppm 0.000039 > 100.00 51.305500 0.000003 u
Bi (223.061 nm)0.000944 u ppm 0.001440 > 100.00 5.488300 0.000944 u
Ca (315.887 nm)1.041735 ppm 0.011277 1.08 678.553436 1.041735
Cd (214.439 nm)0.000151 ppm 0.000103 68.09 2.509400 0.000151
Co (228.615 nm)0.000232 u ppm 0.000326 > 100.00 47.288400 0.000232 u
Cr (205.560 nm)0.000639 ppm 0.000293 45.83 4.151570 0.000639
Cu (324.754 nm)0.003440 ppm 0.000191 5.56 926.679000 0.003440
Fe (238.204 nm)0.850383 ppm 0.002629 0.31 3364.058481 0.850383
Fe H (259.940 nm)0.912269 u ppm 0.003650 0.40 1338.840000 0.912269 u
K (766.491 nm)0.880571 ppm 0.069016 7.84 1134.670000 0.880571
Li (670.783 nm)0.010451 ppm 0.000244 2.33 -3891.920000 0.010451
Mg (279.078 nm)0.636535 ppm 0.003170 0.50 2137.370000 0.636535
Mn (257.610 nm)0.024449 ppm 0.000139 0.57 6527.970000 0.024449
Mo (202.032 nm)0.000466 ppm 0.000241 51.65 5.792130 0.000466
Na (589.592 nm)4.321590 ppm 0.015833 0.37 53732.500000 4.321590
Na H (589.593 nm)-5.866555 u ppm 0.084152 1.43 40441.239483 -5.866555 u
Ni (231.604 nm)0.001391 ppm 0.000910 65.44 -5.472790 0.001391
P (213.618 nm)-0.001332 u ppm 0.000394 29.61 1.368090 -0.001332 u
Pb (220.353 nm)0.000173 u ppm 0.000269 > 100.00 -1.247130 0.000173 u
S (181.972 nm)1.053919 ppm 0.012383 1.17 238.776510 1.053919
Sb (206.834 nm)-0.000122 u ppm 0.000762 > 100.00 1.919140 -0.000122 u
Se (196.026 nm)0.001306 ppm 0.001348 > 100.00 5.743960 0.001306
Si (288.158 nm)2.511980 ppm 0.014713 0.59 18962.600000 2.511980
Sn (189.925 nm)-0.000849 u ppm 0.001239 > 100.00 1.710470 -0.000849 u
Sr (421.552 nm)0.008324 ppm 0.000107 1.29 1847.553935 0.008324
Th (288.505 nm)0.006669 ppm 0.001203 18.04 273.490000 0.006669
Ti (336.122 nm)0.000368 ppm 0.000063 17.12 -75.723800 0.000368
Tl (190.794 nm)0.001405 u ppm 0.001596 > 100.00 -0.977549 0.001405 u
U (409.013 nm)-0.000300 u ppm 0.002840 > 100.00 22.963900 -0.000300 u
V (292.401 nm)0.000237 ppm 0.000142 59.84 -29.517800 0.000237
Zn (206.200 nm)0.014067 ppm 0.000648 4.61 34.495900 0.014067
Zr (343.823 nm)0.000672 ppm 0.000067 9.90 48.260700 0.000672
Test Report
52A112023.esws
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Page 1104 of 1261
Solution Name: 280-184097-E-7-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184097-E-7-A 11/21/2023 4:08:34 AM 3:41 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000512 ppm 0.000018 3.50 720.834969 0.000512
Ag (328.068 nm)0.000070 u ppm 0.000222 > 100.00 -25.202000 0.000070 u
Al (394.401 nm)0.032704 ppm 0.000282 0.86 852.419000 0.032704
Al H (396.152 nm)0.032072 u ppm 0.003214 10.02 194.703000 0.032072 u
As (188.980 nm)-0.002582 u ppm 0.000282 10.91 -5.549960 -0.002582 u
B (249.678 nm)0.000475 ppm 0.000330 69.40 20.155500 0.000475
Ba (493.408 nm)0.001228 ppm 0.000073 5.95 185.538000 0.001228
Be (234.861 nm)-0.000006 u ppm 0.000011 > 100.00 39.157900 -0.000006 u
Bi (223.061 nm)-0.001364 u ppm 0.000948 69.53 2.057340 -0.001364 u
Ca (315.887 nm)0.444025 ppm 0.002040 0.46 275.446073 0.444025
Cd (214.439 nm)0.000106 u ppm 0.000100 94.63 1.663350 0.000106 u
Co (228.615 nm)-0.000055 u ppm 0.000260 > 100.00 41.812100 -0.000055 u
Cr (205.560 nm)0.000532 ppm 0.000136 25.64 3.710820 0.000532
Cu (324.754 nm)0.001148 ppm 0.000093 8.09 819.510000 0.001148
Fe (238.204 nm)0.028378 ppm 0.000582 2.05 128.308816 0.028378
Fe H (259.940 nm)0.118270 u ppm 0.001560 1.32 52.745100 0.118270 u
K (766.491 nm)0.048172 u ppm 0.062077 > 100.00 -360.864000 0.048172 u
Li (670.783 nm)0.008882 ppm 0.000902 10.16 -3950.280000 0.008882
Mg (279.078 nm)0.024695 ppm 0.001082 4.38 91.469600 0.024695
Mn (257.610 nm)0.000966 ppm 0.000018 1.81 262.119000 0.000966
Mo (202.032 nm)0.000496 ppm 0.000270 54.54 5.938060 0.000496
Na (589.592 nm)0.576476 ppm 0.000527 0.09 8059.100000 0.576476
Na H (589.593 nm)-9.549941 u ppm 0.008324 0.09 8084.768435 -9.549941 u
Ni (231.604 nm)0.000408 ppm 0.000431 > 100.00 -8.818420 0.000408
P (213.618 nm)0.000333 u ppm 0.000375 > 100.00 3.452630 0.000333 u
Pb (220.353 nm)0.000017 u ppm 0.001496 > 100.00 -1.590810 0.000017 u
S (181.972 nm)-0.006769 u ppm 0.002265 33.47 22.695387 -0.006769 u
Sb (206.834 nm)0.001437 ppm 0.000015 1.03 3.759440 0.001437
Se (196.026 nm)-0.001427 u ppm 0.004608 > 100.00 4.137260 -0.001427 u
Si (288.158 nm)0.106872 ppm 0.001412 1.32 1488.470000 0.106872
Sn (189.925 nm)0.000545 u ppm 0.002779 > 100.00 2.647100 0.000545 u
Sr (421.552 nm)0.000729 ppm 0.000056 7.72 170.571115 0.000729
Th (288.505 nm)0.006042 ppm 0.001678 27.78 271.825000 0.006042
Ti (336.122 nm)0.000377 ppm 0.000049 12.96 -76.074500 0.000377
Tl (190.794 nm)0.002436 u ppm 0.002514 > 100.00 0.154676 0.002436 u
U (409.013 nm)-0.003496 u ppm 0.003062 87.57 8.123380 -0.003496 u
V (292.401 nm)0.000017 u ppm 0.000188 > 100.00 -38.469500 0.000017 u
Zn (206.200 nm)0.003306 ppm 0.000612 18.52 11.291100 0.003306
Zr (343.823 nm)0.000047 ppm 0.000064 > 100.00 -3.782460 0.000047
Test Report
52A112023.esws
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Page 1105 of 1261
Solution Name: 280-184144-C-2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184144-C-2-A 11/21/2023 4:12:36 AM 3:42 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.025482 b ppm 0.000157 0.62 77849.804974 0.025482 b
Ag (328.068 nm)0.001117 ppm 0.000199 17.78 32.491600 0.001117
Al (394.401 nm)0.050167 ppm 0.001641 3.27 1052.310000 0.050167
Al H (396.152 nm)-0.048239 u ppm 0.003185 6.60 -166.232000 -0.048239 u
As (188.980 nm)0.002792 u ppm 0.002455 87.95 -1.084890 0.002792 u
B (249.678 nm)0.042011 ppm 0.000340 0.81 367.795000 0.042011
Ba (493.408 nm)0.009584 ppm 0.000141 1.47 1451.020000 0.009584
Be (234.861 nm)0.000169 ppm 0.000006 3.62 68.306300 0.000169
Bi (223.061 nm)0.002939 u ppm 0.005867 > 100.00 8.454800 0.002939 u
Ca (315.887 nm)488.314904 o ppm 0.724097 0.15 329304.880749 488.314904 o
Cd (214.439 nm)0.000662 ppm 0.000179 27.07 9.979690 0.000662
Co (228.615 nm)0.000327 ppm 0.000029 8.93 49.044400 0.000327
Cr (205.560 nm)0.000283 u ppm 0.000727 > 100.00 2.681640 0.000283 u
Cu (324.754 nm)0.003144 ppm 0.000168 5.35 627.516000 0.003144
Fe (238.204 nm)0.011644 ppm 0.001288 11.06 62.473206 0.011644
Fe H (259.940 nm)0.099091 u ppm 0.001235 1.25 21.679500 0.099091 u
K (766.491 nm)12.428900 ppm 0.088403 0.71 21883.000000 12.428900
Li (670.783 nm)0.035242 ppm 0.001780 5.05 -2969.970000 0.035242
Mg (279.078 nm)43.246500 ppm 0.302560 0.70 144654.000000 43.246500
Mn (257.610 nm)0.003238 ppm 0.000053 1.63 868.480000 0.003238
Mo (202.032 nm)0.001726 ppm 0.000069 3.97 12.044300 0.001726
Na (589.592 nm)518.192000 o ppm 3.842090 0.74 6299860.000000 518.192000 o
Na H (589.593 nm)522.846491 ppm 0.863672 0.17 4668848.694528 522.846491
Ni (231.604 nm)-0.003579 u ppm 0.000967 27.01 -22.395000 -0.003579 u
P (213.618 nm)0.006599 ppm 0.002140 32.43 10.652900 0.006599
Pb (220.353 nm)0.001453 u ppm 0.001693 > 100.00 1.728330 0.001453 u
S (181.972 nm)599.570827 bo ppm 3.581919 0.60 122135.512806 599.570827 bo
Sb (206.834 nm)-0.002385 u ppm 0.003191 > 100.00 -0.900881 -0.002385 u
Se (196.026 nm)0.079882 ppm 0.005430 6.80 54.037100 0.079882
Si (288.158 nm)5.697970 ppm 0.022315 0.39 42110.500000 5.697970
Sn (189.925 nm)-0.001088 u ppm 0.001838 > 100.00 1.549770 -0.001088 u
Sr (421.552 nm)11.620828 bo ppm 0.075166 0.65 2565882.303115 11.620828 bo
Th (288.505 nm)0.069037 ppm 0.005115 7.41 390.309000 0.069037
Ti (336.122 nm)-0.001745 u ppm 0.000057 3.26 761.410000 -0.001745 u
Tl (190.794 nm)0.003954 ppm 0.001245 31.49 1.804990 0.003954
U (409.013 nm)0.002333 u ppm 0.003560 > 100.00 34.727900 0.002333 u
V (292.401 nm)0.002173 ppm 0.000304 13.99 56.337900 0.002173
Zn (206.200 nm)0.004009 ppm 0.000657 16.40 12.807000 0.004009
Zr (343.823 nm)-0.000224 u ppm 0.000028 12.54 -25.937300 -0.000224 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 235 of 287
Page 1106 of 1261
Solution Name: 280-184144-C-3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184144-C-3-A 11/21/2023 4:16:58 AM 3:43 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.040910 b ppm 0.000131 0.32 108813.769198 0.040910 b
Ag (328.068 nm)0.001032 ppm 0.000052 5.00 26.058700 0.001032
Al (394.401 nm)0.088169 ppm 0.000714 0.81 1526.240000 0.088169
Al H (396.152 nm)0.012510 u ppm 0.000401 3.20 106.788000 0.012510 u
As (188.980 nm)0.001934 ppm 0.000386 19.96 -1.798130 0.001934
B (249.678 nm)0.069461 ppm 0.000709 1.02 597.545000 0.069461
Ba (493.408 nm)0.035073 ppm 0.000180 0.51 5311.600000 0.035073
Be (234.861 nm)0.000108 ppm 0.000020 18.86 58.958600 0.000108
Bi (223.061 nm)0.003547 ppm 0.002146 60.51 9.358810 0.003547
Ca (315.887 nm)312.661297 o ppm 0.624431 0.20 210840.734774 312.661297 o
Cd (214.439 nm)0.000547 ppm 0.000027 4.95 8.263850 0.000547
Co (228.615 nm)0.000066 u ppm 0.000193 > 100.00 44.113500 0.000066 u
Cr (205.560 nm)0.002455 ppm 0.000083 3.39 11.596800 0.002455
Cu (324.754 nm)0.005479 ppm 0.000254 4.64 839.061000 0.005479
Fe (238.204 nm)0.077095 ppm 0.001718 2.23 320.106629 0.077095
Fe H (259.940 nm)0.160917 u ppm 0.000694 0.43 121.823000 0.160917 u
K (766.491 nm)2.284870 ppm 0.038079 1.67 3657.710000 2.284870
Li (670.783 nm)0.048935 ppm 0.000953 1.95 -2460.740000 0.048935
Mg (279.078 nm)42.350400 ppm 0.078695 0.19 141656.000000 42.350400
Mn (257.610 nm)0.001544 ppm 0.000018 1.19 416.546000 0.001544
Mo (202.032 nm)0.007065 ppm 0.000287 4.06 38.535500 0.007065
Na (589.592 nm)158.013000 o ppm 1.499430 0.95 1922120.000000 158.013000 o
Na H (589.593 nm)148.622458 ppm 2.439642 1.64 1393045.819191 148.622458
Ni (231.604 nm)-0.003398 u ppm 0.000958 28.19 -21.781200 -0.003398 u
P (213.618 nm)0.041849 ppm 0.001888 4.51 52.013900 0.041849
Pb (220.353 nm)-0.000062 u ppm 0.000983 > 100.00 -1.731470 -0.000062 u
S (181.972 nm)176.333906 bo ppm 0.807332 0.46 35940.365537 176.333906 bo
Sb (206.834 nm)-0.003803 u ppm 0.004115 > 100.00 -2.640080 -0.003803 u
Se (196.026 nm)0.002662 u ppm 0.003675 > 100.00 6.641650 0.002662 u
Si (288.158 nm)14.325100 o ppm 0.043683 0.30 104792.000000 14.325100 o
Sn (189.925 nm)-0.002402 u ppm 0.000466 19.41 0.667041 -0.002402 u
Sr (421.552 nm)5.006512 o ppm 0.008646 0.17 1105444.845473 5.006512 o
Th (288.505 nm)0.050972 ppm 0.001524 2.99 356.563000 0.050972
Ti (336.122 nm)0.000076 ppm 0.000040 52.78 575.292000 0.000076
Tl (190.794 nm)-0.000272 u ppm 0.001836 > 100.00 -2.801390 -0.000272 u
U (409.013 nm)0.033061 ppm 0.001310 3.96 169.926000 0.033061
V (292.401 nm)0.002686 ppm 0.000039 1.44 74.664200 0.002686
Zn (206.200 nm)0.001848 ppm 0.000299 16.16 8.147590 0.001848
Zr (343.823 nm)0.000057 u ppm 0.000144 > 100.00 -2.919820 0.000057 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 236 of 287
Page 1107 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 4:21:22 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000003 u ppm 0.000007 > 100.00 945.467742 0.000003 u
Ag (328.068 nm)0.000188 ppm 0.000101 54.00 123.585000 0.000188
Al (394.401 nm)52.584200 o ppm 0.340325 0.65 646458.000000 52.584200 o
Al H (396.152 nm)49.175700 ppm 0.109143 0.22 221056.000000 49.175700
As (188.980 nm)0.002422 ppm 0.003012 > 100.00 -1.840650 0.002422
B (249.678 nm)-0.002744 u ppm 0.000399 14.56 -6.783090 -0.002744 u
Ba (493.408 nm)0.000386 ppm 0.000079 20.48 199.101000 0.000386
Be (234.861 nm)0.000065 ppm 0.000012 18.55 698.554000 0.000065
Bi (223.061 nm)-0.000245 u ppm 0.001059 > 100.00 3.720440 -0.000245 u
Ca (315.887 nm)-0.012256 u ppm 0.002956 24.12 -32.278048 -0.012256 u
Cd (214.439 nm)0.000024 u ppm 0.000051 > 100.00 10.714500 0.000024 u
Co (228.615 nm)0.000354 ppm 0.000228 64.42 49.611400 0.000354
Cr (205.560 nm)0.000624 u ppm 0.000801 > 100.00 4.092070 0.000624 u
Cu (324.754 nm)0.000190 u ppm 0.000498 > 100.00 1718.810000 0.000190 u
Fe (238.204 nm)50.326600 o ppm 0.133308 0.26 198122.690556 50.326600 o
Fe H (259.940 nm)48.524200 ppm 0.127590 0.26 78459.100000 48.524200
K (766.491 nm)0.060413 ppm 0.015507 25.67 -338.871000 0.060413
Li (670.783 nm)0.002327 ppm 0.000868 37.31 -4194.070000 0.002327
Mg (279.078 nm)0.005807 ppm 0.001156 19.91 -161.308000 0.005807
Mn (257.610 nm)-0.000950 u ppm 0.000045 4.74 -248.903000 -0.000950 u
Mo (202.032 nm)-0.000464 u ppm 0.000152 32.79 1.175900 -0.000464 u
Na (589.592 nm)248.405000 o ppm 0.356943 0.14 3020440.000000 248.405000 o
Na H (589.593 nm)239.351742 ppm 1.368176 0.57 2187009.265487 239.351742
Ni (231.604 nm)-0.000818 u ppm 0.001237 > 100.00 -12.994300 -0.000818 u
P (213.618 nm)5.068960 ppm 0.032440 0.64 5986.440000 5.068960
Pb (220.353 nm)0.001776 ppm 0.001518 85.47 0.874156 0.001776
S (181.972 nm)4.798066 ppm 0.041609 0.87 1003.090521 4.798066
Sb (206.834 nm)-0.000054 u ppm 0.002443 > 100.00 5.417720 -0.000054 u
Se (196.026 nm)0.003239 ppm 0.002419 74.69 1.731680 0.003239
Si (288.158 nm)0.034975 ppm 0.002634 7.53 966.121000 0.034975
Sn (189.925 nm)0.000802 u ppm 0.002217 > 100.00 2.820050 0.000802 u
Sr (421.552 nm)0.000646 ppm 0.000123 19.09 152.251426 0.000646
Th (288.505 nm)4.573700 ppm 0.018240 0.40 8808.030000 4.573700
Ti (336.122 nm)0.000576 ppm 0.000065 11.26 -55.272700 0.000576
Tl (190.794 nm)-0.002812 u ppm 0.000716 25.47 -6.443450 -0.002812 u
U (409.013 nm)2.386060 Q ppm 0.009968 0.42 10659.600000 Q 2.386060 Q
V (292.401 nm)0.000478 ppm 0.000272 56.89 262.644000 0.000478
Zn (206.200 nm)-0.000521 u ppm 0.000965 > 100.00 3.039630 -0.000521 u
Zr (343.823 nm)-0.000869 u ppm 0.000081 9.32 -10.436600 -0.000869 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 237 of 287
Page 1108 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 4:25:48 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.450539 ppm 0.000275 0.06 1155291.894505 0.450539
Ag (328.068 nm)0.506469 ppm 0.003016 0.60 27051.600000 0.506469
Al (394.401 nm)0.495763 ppm 0.001822 0.37 6555.960000 0.495763
Al H (396.152 nm)0.501067 u ppm 0.002135 0.43 2302.460000 0.501067 u
As (188.980 nm)0.505099 ppm 0.004160 0.82 416.249000 0.505099
B (249.678 nm)0.495576 ppm 0.000474 0.10 4163.980000 0.495576
Ba (493.408 nm)0.499825 ppm 0.001104 0.22 75707.000000 0.499825
Be (234.861 nm)0.508548 ppm 0.000694 0.14 85037.100000 0.508548
Bi (223.061 nm)0.995711 ppm 0.006032 0.61 1484.500000 0.995711
Ca (315.887 nm)5.012731 ppm 0.011500 0.23 3356.668756 5.012731
Cd (214.439 nm)0.510095 ppm 0.000768 0.15 7624.910000 0.510095
Co (228.615 nm)0.509150 ppm 0.000690 0.14 9771.910000 0.509150
Cr (205.560 nm)0.512263 ppm 0.000811 0.16 2107.060000 0.512263
Cu (324.754 nm)0.500684 ppm 0.000935 0.19 24116.200000 0.500684
Fe (238.204 nm)2.508905 ppm 0.004916 0.20 9899.033270 2.508905
Fe H (259.940 nm)2.515470 u ppm 0.005646 0.22 3935.650000 2.515470 u
K (766.491 nm)50.840700 ppm 0.222560 0.44 90895.700000 50.840700
Li (670.783 nm)0.497825 ppm 0.003209 0.64 14233.200000 0.497825
Mg (279.078 nm)20.275400 ppm 0.024333 0.12 67823.100000 20.275400
Mn (257.610 nm)0.499317 ppm 0.000347 0.07 133233.000000 0.499317
Mo (202.032 nm)0.503802 ppm 0.001519 0.30 2503.390000 0.503802
Na (589.592 nm)24.889400 ppm 0.128479 0.52 309429.000000 24.889400
Na H (589.593 nm)14.762957 u ppm 0.317240 2.15 225240.484321 14.762957 u
Ni (231.604 nm)0.513179 ppm 0.001087 0.21 1737.590000 0.513179
P (213.618 nm)0.010453 ppm 0.001975 18.90 -25.039100 0.010453
Pb (220.353 nm)0.536764 ppm 0.001977 0.37 1229.880000 0.536764
S (181.972 nm)-0.016302 u ppm 0.003299 20.24 23.245047 -0.016302 u
Sb (206.834 nm)0.491902 ppm 0.000774 0.16 601.011000 0.491902
Se (196.026 nm)0.504895 ppm 0.006619 1.31 314.921000 0.504895
Si (288.158 nm)4.953270 ppm 0.013859 0.28 36945.100000 4.953270
Sn (189.925 nm)0.502342 ppm 0.002254 0.45 339.848000 0.502342
Sr (421.552 nm)0.500132 ppm 0.000981 0.20 110438.663567 0.500132
Th (288.505 nm)0.043126 ppm 0.003162 7.33 329.220000 0.043126
Ti (336.122 nm)0.500506 ppm 0.000720 0.14 54507.600000 0.500506
Tl (190.794 nm)0.502084 ppm 0.002405 0.48 541.570000 0.502084
U (409.013 nm)-0.008662 u ppm 0.002525 29.15 -28.267900 -0.008662 u
V (292.401 nm)0.502445 ppm 0.000365 0.07 20880.400000 0.502445
Zn (206.200 nm)0.510642 ppm 0.002448 0.48 1105.290000 0.510642
Zr (343.823 nm)0.496627 ppm 0.000832 0.17 40480.500000 0.496627
Test Report
52A112023.esws
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Page 1109 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 4:30:10 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000484 ppm 0.000011 2.36 646.751033 0.000484
Ag (328.068 nm)0.000207 ppm 0.000121 58.37 -17.664500 0.000207
Al (394.401 nm)-0.000706 u ppm 0.000697 98.70 441.094000 -0.000706 u
Al H (396.152 nm)-0.001662 u ppm 0.004948 > 100.00 43.096600 -0.001662 u
As (188.980 nm)0.000838 u ppm 0.003347 > 100.00 -2.708140 0.000838 u
B (249.678 nm)0.000049 u ppm 0.000432 > 100.00 16.593700 0.000049 u
Ba (493.408 nm)0.000125 ppm 0.000061 48.55 18.412200 0.000125
Be (234.861 nm)0.000040 ppm 0.000037 91.74 46.625400 0.000040
Bi (223.061 nm)0.000193 u ppm 0.001153 > 100.00 4.371660 0.000193 u
Ca (315.887 nm)0.004702 ppm 0.001800 38.28 -20.841484 0.004702
Cd (214.439 nm)-0.000052 u ppm 0.000066 > 100.00 -0.692861 -0.000052 u
Co (228.615 nm)-0.000174 u ppm 0.000156 89.46 39.523400 -0.000174 u
Cr (205.560 nm)-0.000148 u ppm 0.000340 > 100.00 0.911563 -0.000148 u
Cu (324.754 nm)0.000148 ppm 0.000129 87.34 773.250000 0.000148
Fe (238.204 nm)0.001084 ppm 0.000586 54.06 20.861337 0.001084
Fe H (259.940 nm)0.096001 u ppm 0.002304 2.40 16.674600 0.096001 u
K (766.491 nm)0.031424 ppm 0.027149 86.40 -390.955000 0.031424
Li (670.783 nm)0.005770 S ppm 0.001163 20.15 -4066.030000 S 0.005770 S
Mg (279.078 nm)0.001483 ppm 0.001043 70.31 13.823300 0.001483
Mn (257.610 nm)-0.000036 u ppm 0.000011 30.25 -5.232980 -0.000036 u
Mo (202.032 nm)0.001070 ppm 0.000483 45.15 8.788550 0.001070
Na (589.592 nm)0.113352 ppm 0.009638 8.50 2413.450000 0.113352
Na H (589.593 nm)-9.932545 u ppm 0.011483 0.12 4723.339675 -9.932545 u
Ni (231.604 nm)-0.000038 u ppm 0.000906 > 100.00 -10.340300 -0.000038 u
P (213.618 nm)-0.001471 u ppm 0.000852 57.97 1.336870 -0.001471 u
Pb (220.353 nm)0.000051 u ppm 0.000987 > 100.00 -1.509680 0.000051 u
S (181.972 nm)-0.029051 u ppm 0.003169 10.91 18.151118 -0.029051 u
Sb (206.834 nm)0.000167 u ppm 0.001980 > 100.00 2.204100 0.000167 u
Se (196.026 nm)-0.001113 u ppm 0.006232 > 100.00 4.331970 -0.001113 u
Si (288.158 nm)-0.000326 u ppm 0.000545 > 100.00 709.478000 -0.000326 u
Sn (189.925 nm)0.000381 u ppm 0.001476 > 100.00 2.536750 0.000381 u
Sr (421.552 nm)0.000111 ppm 0.000007 6.10 34.193009 0.000111
Th (288.505 nm)0.008819 Z ppm 0.001403 15.91 277.013000 Z 0.008819 Z
Ti (336.122 nm)-0.000091 u ppm 0.000084 91.91 -128.028000 -0.000091 u
Tl (190.794 nm)0.000764 ppm 0.000386 50.53 -1.661320 0.000764
U (409.013 nm)-0.000818 u ppm 0.002133 > 100.00 19.911500 -0.000818 u
V (292.401 nm)0.000092 u ppm 0.000162 > 100.00 -35.106900 0.000092 u
Zn (206.200 nm)-0.001122 u ppm 0.000298 26.56 1.742760 -0.001122 u
Zr (343.823 nm)0.000060 u ppm 0.000165 > 100.00 -2.737070 0.000060 u
Test Report
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Page 1110 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 4:34:12 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014281 ppm 0.000013 0.09 36122.262738 0.014281
Ag (328.068 nm)0.009750 ppm 0.000122 1.25 489.579000 0.009750
Al (394.401 nm)0.087642 ppm 0.001512 1.72 1539.770000 0.087642
Al H (396.152 nm)0.095641 u ppm 0.001480 1.55 480.395000 0.095641 u
As (188.980 nm)0.015744 ppm 0.000125 0.80 9.676230 0.015744
B (249.678 nm)0.095801 ppm 0.000535 0.56 818.003000 0.095801
Ba (493.408 nm)0.009950 ppm 0.000189 1.90 1506.630000 0.009950
Be (234.861 nm)0.000972 ppm 0.000007 0.75 203.502000 0.000972
Bi (223.061 nm)-0.001987 Qu ppm 0.000168 8.46 1.131030 Q -0.001987 Qu
Ca (315.887 nm)0.208781 ppm 0.006976 3.34 116.793405 0.208781
Cd (214.439 nm)0.005059 ppm 0.000181 3.57 75.712000 0.005059
Co (228.615 nm)0.010130 ppm 0.000163 1.61 236.374000 0.010130
Cr (205.560 nm)0.009843 ppm 0.000401 4.08 41.915900 0.009843
Cu (324.754 nm)0.014623 ppm 0.000182 1.24 1441.010000 0.014623
Fe (238.204 nm)0.100697 ppm 0.001526 1.52 413.050770 0.100697
Fe H (259.940 nm)0.189773 u ppm 0.002665 1.40 168.563000 0.189773 u
K (766.491 nm)3.019370 ppm 0.046393 1.54 4977.340000 3.019370
Li (670.783 nm)0.025705 ppm 0.000090 0.35 -3324.660000 0.025705
Mg (279.078 nm)0.200381 ppm 0.000793 0.40 678.508000 0.200381
Mn (257.610 nm)0.010086 ppm 0.000032 0.31 2695.630000 0.010086
Mo (202.032 nm)0.019803 ppm 0.000335 1.69 101.742000 0.019803
Na (589.592 nm)1.102200 ppm 0.013420 1.22 14551.900000 1.102200
Na H (589.593 nm)-8.987711 u ppm 0.008213 0.09 13082.408653 -8.987711 u
Ni (231.604 nm)0.041096 ppm 0.000463 1.13 129.737000 0.041096
P (213.618 nm)2.832860 ppm 0.004695 0.17 3346.260000 2.832860
Pb (220.353 nm)0.009531 ppm 0.001280 13.43 20.313100 0.009531
S (181.972 nm)0.052904 Q ppm 0.002287 4.32 34.910972 Q 0.052904 Q
Sb (206.834 nm)0.021451 ppm 0.000794 3.70 28.064000 0.021451
Se (196.026 nm)0.019146 ppm 0.003786 19.78 16.760500 0.019146
Si (288.158 nm)0.464222 ppm 0.004300 0.93 4115.040000 0.464222
Sn (189.925 nm)0.099400 ppm 0.004600 4.63 69.076400 0.099400
Sr (421.552 nm)0.009763 ppm 0.000090 0.93 2165.261699 0.009763
Th (288.505 nm)0.004450 Q ppm 0.002160 48.54 268.971000 Q 0.004450 Q
Ti (336.122 nm)0.009536 ppm 0.000084 0.88 922.862000 0.009536
Tl (190.794 nm)0.016246 ppm 0.001441 8.87 15.107800 0.016246
U (409.013 nm)0.057279 ppm 0.003451 6.02 275.351000 0.057279
V (292.401 nm)0.009891 ppm 0.000048 0.49 367.693000 0.009891
Zn (206.200 nm)0.020415 ppm 0.000606 2.97 48.185500 0.020415
Zr (343.823 nm)0.009758 ppm 0.000100 1.02 787.976000 0.009758
Test Report
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Solution Name: 280-184144-C-4-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184144-C-4-A 11/21/2023 4:38:30 AM 3:44 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.041603 b ppm 0.000179 0.43 110815.702636 0.041603 b
Ag (328.068 nm)0.000926 ppm 0.000063 6.77 20.624400 0.000926
Al (394.401 nm)0.109251 ppm 0.000586 0.54 1785.560000 0.109251
Al H (396.152 nm)0.020568 u ppm 0.002031 9.88 143.002000 0.020568 u
As (188.980 nm)0.004565 ppm 0.003335 73.07 0.387578 0.004565
B (249.678 nm)0.052821 ppm 0.000497 0.94 458.270000 0.052821
Ba (493.408 nm)0.054002 ppm 0.000782 1.45 8178.450000 0.054002
Be (234.861 nm)0.000132 ppm 0.000017 13.18 62.698600 0.000132
Bi (223.061 nm)0.000569 u ppm 0.000605 > 100.00 4.931040 0.000569 u
Ca (315.887 nm)397.486851 o ppm 0.371422 0.09 268048.708190 397.486851 o
Cd (214.439 nm)0.000595 ppm 0.000121 20.27 8.990890 0.000595
Co (228.615 nm)0.000306 ppm 0.000233 75.90 48.693200 0.000306
Cr (205.560 nm)-0.000111 u ppm 0.000432 > 100.00 1.062730 -0.000111 u
Cu (324.754 nm)0.001685 ppm 0.000431 25.60 610.537000 0.001685
Fe (238.204 nm)0.063881 ppm 0.001290 2.02 268.093918 0.063881
Fe H (259.940 nm)0.150981 u ppm 0.002792 1.85 105.728000 0.150981 u
K (766.491 nm)7.185840 ppm 0.029612 0.41 12463.000000 7.185840
Li (670.783 nm)0.050421 ppm 0.001568 3.11 -2405.490000 0.050421
Mg (279.078 nm)40.103000 ppm 0.181270 0.45 134140.000000 40.103000
Mn (257.610 nm)0.003256 ppm 0.000018 0.55 873.376000 0.003256
Mo (202.032 nm)0.001040 ppm 0.000293 28.14 8.639360 0.001040
Na (589.592 nm)190.639000 o ppm 0.671431 0.35 2318920.000000 190.639000 o
Na H (589.593 nm)184.022523 ppm 1.784037 0.97 1703107.918562 184.022523
Ni (231.604 nm)-0.003622 u ppm 0.001080 29.81 -22.543900 -0.003622 u
P (213.618 nm)0.038855 ppm 0.007095 18.26 48.836800 0.038855
Pb (220.353 nm)0.001985 ppm 0.002067 > 100.00 2.988510 0.001985
S (181.972 nm)188.865163 bo ppm 1.018898 0.54 38494.015171 188.865163 bo
Sb (206.834 nm)-0.003077 u ppm 0.001064 34.58 -1.741240 -0.003077 u
Se (196.026 nm)0.010756 ppm 0.001973 18.34 11.611400 0.010756
Si (288.158 nm)12.350700 o ppm 0.022757 0.18 90446.800000 12.350700 o
Sn (189.925 nm)-0.001851 u ppm 0.001068 57.71 1.037140 -0.001851 u
Sr (421.552 nm)4.519962 o ppm 0.034021 0.75 998014.938386 4.519962 o
Th (288.505 nm)0.054142 ppm 0.000501 0.92 362.506000 0.054142
Ti (336.122 nm)-0.000188 u ppm 0.000051 26.99 732.195000 -0.000188 u
Tl (190.794 nm)0.000632 u ppm 0.002330 > 100.00 -1.802900 0.000632 u
U (409.013 nm)0.036580 ppm 0.003084 8.43 185.429000 0.036580
V (292.401 nm)0.002392 ppm 0.000157 6.57 63.160100 0.002392
Zn (206.200 nm)0.003183 ppm 0.000718 22.56 11.027000 0.003183
Zr (343.823 nm)0.000184 ppm 0.000055 29.80 7.426900 0.000184
Test Report
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Page 1112 of 1261
Solution Name: 280-184152-C-1-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184152-C-1-A 11/21/2023 4:42:52 AM 3:45 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.024059 ppm 0.000102 0.42 61849.228269 0.024059
Ag (328.068 nm)0.000775 ppm 0.000027 3.49 12.752600 0.000775
Al (394.401 nm)0.023681 ppm 0.000884 3.73 736.147000 0.023681
Al H (396.152 nm)-0.005970 u ppm 0.001830 30.66 23.733700 -0.005970 u
As (188.980 nm)0.007286 ppm 0.001761 24.16 2.640930 0.007286
B (249.678 nm)0.534253 ppm 0.003120 0.58 4487.700000 0.534253
Ba (493.408 nm)0.289388 ppm 0.000725 0.25 43831.100000 0.289388
Be (234.861 nm)0.000067 ppm 0.000010 14.71 63.184200 0.000067
Bi (223.061 nm)-0.001038 u ppm 0.001135 > 100.00 2.541480 -0.001038 u
Ca (315.887 nm)71.474932 o ppm 0.032994 0.05 48180.045892 71.474932 o
Cd (214.439 nm)0.000338 ppm 0.000023 6.77 5.325900 0.000338
Co (228.615 nm)0.000226 ppm 0.000023 10.29 47.146100 0.000226
Cr (205.560 nm)0.000518 ppm 0.000327 63.09 3.645000 0.000518
Cu (324.754 nm)0.000097 u ppm 0.000171 > 100.00 732.506000 0.000097 u
Fe (238.204 nm)0.947671 ppm 0.001874 0.20 3747.037579 0.947671
Fe H (259.940 nm)1.008610 u ppm 0.001845 0.18 1494.890000 1.008610 u
K (766.491 nm)1.200520 ppm 0.030851 2.57 1709.510000 1.200520
Li (670.783 nm)0.033151 ppm 0.002647 7.99 -3047.720000 0.033151
Mg (279.078 nm)29.546200 ppm 0.181686 0.61 98830.900000 29.546200
Mn (257.610 nm)0.217973 ppm 0.001202 0.55 58164.400000 0.217973
Mo (202.032 nm)0.003642 ppm 0.000426 11.70 21.550900 0.003642
Na (589.592 nm)171.671000 o ppm 0.730320 0.43 2091120.000000 171.671000 o
Na H (589.593 nm)162.034199 ppm 1.153721 0.71 1512655.613318 162.034199
Ni (231.604 nm)-0.000923 u ppm 0.000416 45.11 -13.354000 -0.000923 u
P (213.618 nm)0.114538 ppm 0.001963 1.71 138.225000 0.114538
Pb (220.353 nm)-0.000971 u ppm 0.001432 > 100.00 -3.858710 -0.000971 u
S (181.972 nm)7.797564 ppm 0.063328 0.81 1613.698374 7.797564
Sb (206.834 nm)-0.001721 u ppm 0.003943 > 100.00 -0.037902 -0.001721 u
Se (196.026 nm)-0.000215 u ppm 0.003957 > 100.00 4.928400 -0.000215 u
Si (288.158 nm)10.932200 ppm 0.043139 0.39 80140.000000 10.932200
Sn (189.925 nm)-0.002296 u ppm 0.000967 42.12 0.737855 -0.002296 u
Sr (421.552 nm)0.513423 ppm 0.000815 0.16 113373.214987 0.513423
Th (288.505 nm)0.033196 ppm 0.001630 4.91 327.421000 0.033196
Ti (336.122 nm)-0.000299 u ppm 0.000043 14.48 5.849820 -0.000299 u
Tl (190.794 nm)-0.000972 u ppm 0.001392 > 100.00 -3.568630 -0.000972 u
U (409.013 nm)0.010132 ppm 0.003256 32.14 69.380100 0.010132
V (292.401 nm)0.000701 ppm 0.000104 14.87 -8.376540 0.000701
Zn (206.200 nm)0.001696 ppm 0.000776 45.76 7.820270 0.001696
Zr (343.823 nm)0.000087 ppm 0.000081 92.87 0.695309 0.000087
Test Report
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Page 1113 of 1261
Solution Name: 280-184152-C-2-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184152-C-2-A 11/21/2023 4:47:11 AM 3:46 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.024616 ppm 0.000082 0.33 63275.769345 0.024616
Ag (328.068 nm)0.000785 ppm 0.000219 27.86 10.683700 0.000785
Al (394.401 nm)0.605261 ppm 0.002980 0.49 7890.570000 0.605261
Al H (396.152 nm)0.547477 u ppm 0.005416 0.99 2511.040000 0.547477 u
As (188.980 nm)0.003535 ppm 0.002031 57.45 -0.471518 0.003535
B (249.678 nm)0.198321 ppm 0.000770 0.39 1676.060000 0.198321
Ba (493.408 nm)0.451651 ppm 0.001183 0.26 68405.100000 0.451651
Be (234.861 nm)0.000116 ppm 0.000023 19.68 65.017500 0.000116
Bi (223.061 nm)0.000126 u ppm 0.000431 > 100.00 4.272790 0.000126 u
Ca (315.887 nm)92.275016 o ppm 0.333509 0.36 62208.019773 92.275016 o
Cd (214.439 nm)0.000391 ppm 0.000072 18.40 6.014290 0.000391
Co (228.615 nm)0.000782 ppm 0.000205 26.21 58.088700 0.000782
Cr (205.560 nm)0.001167 ppm 0.000074 6.35 6.312890 0.001167
Cu (324.754 nm)0.001217 ppm 0.000164 13.48 773.166000 0.001217
Fe (238.204 nm)0.451966 ppm 0.001319 0.29 1795.745417 0.451966
Fe H (259.940 nm)0.524042 u ppm 0.005468 1.04 710.002000 0.524042 u
K (766.491 nm)1.454410 ppm 0.063837 4.39 2165.660000 1.454410
Li (670.783 nm)0.032966 ppm 0.000936 2.84 -3054.620000 0.032966
Mg (279.078 nm)32.914500 ppm 0.115155 0.35 110097.000000 32.914500
Mn (257.610 nm)0.323695 ppm 0.001014 0.31 86373.200000 0.323695
Mo (202.032 nm)0.003475 ppm 0.000404 11.62 20.722300 0.003475
Na (589.592 nm)124.110000 o ppm 0.757222 0.61 1514900.000000 124.110000 o
Na H (589.593 nm)113.690929 ppm 1.405079 1.24 1090854.653773 113.690929
Ni (231.604 nm)-0.002163 u ppm 0.000793 36.65 -17.574000 -0.002163 u
P (213.618 nm)0.043752 ppm 0.003003 6.86 54.595900 0.043752
Pb (220.353 nm)-0.001006 u ppm 0.001456 > 100.00 -4.010700 -0.001006 u
S (181.972 nm)4.992916 ppm 0.023593 0.47 1043.036800 4.992916
Sb (206.834 nm)-0.001383 u ppm 0.002091 > 100.00 0.317513 -0.001383 u
Se (196.026 nm)0.003114 ppm 0.003986 > 100.00 7.093550 0.003114
Si (288.158 nm)11.598500 o ppm 0.050458 0.44 84983.900000 11.598500 o
Sn (189.925 nm)0.000245 u ppm 0.001820 > 100.00 2.445750 0.000245 u
Sr (421.552 nm)0.607207 ppm 0.001915 0.32 134080.583522 0.607207
Th (288.505 nm)0.034814 ppm 0.002242 6.44 332.478000 0.034814
Ti (336.122 nm)0.009510 ppm 0.000060 0.63 1121.780000 0.009510
Tl (190.794 nm)0.005316 ppm 0.001311 24.66 3.256900 0.005316
U (409.013 nm)0.013934 ppm 0.006015 43.17 85.779700 0.013934
V (292.401 nm)0.004843 ppm 0.000253 5.21 166.007000 0.004843
Zn (206.200 nm)0.003604 ppm 0.000406 11.28 11.934700 0.003604
Zr (343.823 nm)0.000556 ppm 0.000099 17.88 38.284700 0.000556
Test Report
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Page 1114 of 1261
Solution Name: 280-184152-C-3-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184152-C-3-A 11/21/2023 4:51:31 AM 3:47 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.030241 ppm 0.000084 0.28 77580.265880 0.030241
Ag (328.068 nm)0.000906 ppm 0.000114 12.62 19.617400 0.000906
Al (394.401 nm)0.076822 ppm 0.001146 1.49 1388.800000 0.076822
Al H (396.152 nm)0.047484 u ppm 0.002263 4.77 263.965000 0.047484 u
As (188.980 nm)0.001361 ppm 0.001045 76.76 -2.274220 0.001361
B (249.678 nm)0.168286 ppm 0.000266 0.16 1424.670000 0.168286
Ba (493.408 nm)0.388497 ppm 0.001737 0.45 58838.900000 0.388497
Be (234.861 nm)0.000061 ppm 0.000019 31.09 50.543200 0.000061
Bi (223.061 nm)-0.000664 u ppm 0.001320 > 100.00 3.098200 -0.000664 u
Ca (315.887 nm)65.314502 o ppm 0.167193 0.26 44025.334674 65.314502 o
Cd (214.439 nm)0.000251 ppm 0.000197 78.48 3.844710 0.000251
Co (228.615 nm)0.000410 ppm 0.000211 51.49 50.669200 0.000410
Cr (205.560 nm)0.000104 u ppm 0.000545 > 100.00 1.937630 0.000104 u
Cu (324.754 nm)0.000779 ppm 0.000211 27.01 768.104000 0.000779
Fe (238.204 nm)0.041484 ppm 0.001373 3.31 179.913381 0.041484
Fe H (259.940 nm)0.132728 u ppm 0.000984 0.74 76.162600 0.132728 u
K (766.491 nm)1.465010 ppm 0.017274 1.18 2184.700000 1.465010
Li (670.783 nm)0.041568 ppm 0.002921 7.03 -2734.730000 0.041568
Mg (279.078 nm)30.817200 ppm 0.115815 0.38 103082.000000 30.817200
Mn (257.610 nm)0.253719 ppm 0.000819 0.32 67702.100000 0.253719
Mo (202.032 nm)0.004055 ppm 0.000413 10.18 23.597100 0.004055
Na (589.592 nm)114.827000 o ppm 0.345948 0.30 1401330.000000 114.827000 o
Na H (589.593 nm)111.061896 ppm 3.731725 3.36 1067292.660973 111.061896
Ni (231.604 nm)-0.003022 u ppm 0.000711 23.53 -20.500500 -0.003022 u
P (213.618 nm)0.021286 ppm 0.001183 5.56 28.082700 0.021286
Pb (220.353 nm)-0.000155 u ppm 0.001275 > 100.00 -1.982350 -0.000155 u
S (181.972 nm)2.619717 ppm 0.021799 0.83 559.117607 2.619717
Sb (206.834 nm)-0.003138 u ppm 0.001448 46.13 -1.830700 -0.003138 u
Se (196.026 nm)0.001459 u ppm 0.002469 > 100.00 6.074490 0.001459 u
Si (288.158 nm)12.301700 o ppm 0.069679 0.57 90090.500000 12.301700 o
Sn (189.925 nm)-0.001137 u ppm 0.001077 94.71 1.516740 -0.001137 u
Sr (421.552 nm)0.577934 ppm 0.001850 0.32 127617.285791 0.577934
Th (288.505 nm)0.034393 ppm 0.001790 5.20 330.408000 0.034393
Ti (336.122 nm)0.000224 ppm 0.000104 46.40 49.331300 0.000224
Tl (190.794 nm)0.000394 u ppm 0.000988 > 100.00 -2.069810 0.000394 u
U (409.013 nm)0.016263 ppm 0.002445 15.04 95.610700 0.016263
V (292.401 nm)0.001421 ppm 0.000159 11.19 22.101700 0.001421
Zn (206.200 nm)0.000317 u ppm 0.000587 > 100.00 4.845480 0.000317 u
Zr (343.823 nm)0.000034 ppm 0.000018 53.85 -4.797070 0.000034
Test Report
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Page 1115 of 1261
Solution Name: 280-184152-C-4-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184152-C-4-A 11/21/2023 4:55:53 AM 3:48 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.051628 ppm 0.000304 0.59 132948.016661 0.051628
Ag (328.068 nm)0.001151 ppm 0.000083 7.25 29.387600 0.001151
Al (394.401 nm)0.178296 ppm 0.000307 0.17 2638.140000 0.178296
Al H (396.152 nm)0.132169 u ppm 0.003059 2.31 644.558000 0.132169 u
As (188.980 nm)0.005441 ppm 0.002016 37.05 1.115430 0.005441
B (249.678 nm)0.212962 ppm 0.000848 0.40 1798.600000 0.212962
Ba (493.408 nm)0.161651 ppm 0.000767 0.47 24482.500000 0.161651
Be (234.861 nm)0.000146 ppm 0.000016 11.26 65.863400 0.000146
Bi (223.061 nm)-0.000301 u ppm 0.001074 > 100.00 3.637040 -0.000301 u
Ca (315.887 nm)114.619365 o ppm 0.397401 0.35 77277.475664 114.619365 o
Cd (214.439 nm)0.000326 ppm 0.000172 52.68 4.971700 0.000326
Co (228.615 nm)0.000374 ppm 0.000070 18.74 50.060000 0.000374
Cr (205.560 nm)0.000162 u ppm 0.000648 > 100.00 2.163840 0.000162 u
Cu (324.754 nm)0.001004 ppm 0.000050 5.03 748.097000 0.001004
Fe (238.204 nm)0.127419 ppm 0.001166 0.92 518.193012 0.127419
Fe H (259.940 nm)0.211601 u ppm 0.003804 1.80 203.919000 0.211601 u
K (766.491 nm)1.658340 ppm 0.033499 2.02 2532.050000 1.658340
Li (670.783 nm)0.058508 ppm 0.002332 3.99 -2104.740000 0.058508
Mg (279.078 nm)55.382800 o ppm 0.234920 0.42 185247.000000 55.382800 o
Mn (257.610 nm)0.310900 ppm 0.001240 0.40 82959.300000 0.310900
Mo (202.032 nm)0.007610 ppm 0.000364 4.79 41.238300 0.007610
Na (589.592 nm)289.983000 o ppm 2.007540 0.69 3527720.000000 289.983000 o
Na H (589.593 nm)283.639621 ppm 0.616454 0.22 2576104.518354 283.639621
Ni (231.604 nm)-0.002883 u ppm 0.000971 33.69 -20.025900 -0.002883 u
P (213.618 nm)0.022156 ppm 0.002880 13.00 28.989200 0.022156
Pb (220.353 nm)0.000548 ppm 0.000395 72.08 -0.387652 0.000548
S (181.972 nm)10.981197 o ppm 0.082192 0.75 2262.956265 10.981197 o
Sb (206.834 nm)-0.003749 u ppm 0.003320 88.56 -2.592530 -0.003749 u
Se (196.026 nm)0.003768 ppm 0.004020 > 100.00 7.520410 0.003768
Si (288.158 nm)10.595400 ppm 0.066315 0.63 77694.100000 10.595400
Sn (189.925 nm)-0.000987 u ppm 0.000437 44.27 1.617950 -0.000987 u
Sr (421.552 nm)0.911124 ppm 0.002665 0.29 201185.317344 0.911124
Th (288.505 nm)0.049640 ppm 0.001779 3.58 360.297000 0.049640
Ti (336.122 nm)0.002304 ppm 0.000023 1.00 384.363000 0.002304
Tl (190.794 nm)0.001589 ppm 0.000853 53.70 -0.785676 0.001589
U (409.013 nm)0.015330 ppm 0.006145 40.09 91.535900 0.015330
V (292.401 nm)0.005785 ppm 0.000206 3.55 204.965000 0.005785
Zn (206.200 nm)0.002530 ppm 0.001284 50.74 9.619050 0.002530
Zr (343.823 nm)0.000182 ppm 0.000074 40.41 7.389980 0.000182
Test Report
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Page 1116 of 1261
Solution Name: 280-184152-C-5-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184152-C-5-A 11/21/2023 5:00:15 AM 3:49 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.055630 ppm 0.000330 0.59 143072.322466 0.055630
Ag (328.068 nm)0.001163 ppm 0.000118 10.16 33.746200 0.001163
Al (394.401 nm)0.220784 ppm 0.001600 0.72 3156.400000 0.220784
Al H (396.152 nm)0.173324 u ppm 0.001587 0.92 829.520000 0.173324 u
As (188.980 nm)0.004237 ppm 0.001431 33.77 0.114132 0.004237
B (249.678 nm)0.176609 ppm 0.001571 0.89 1494.340000 0.176609
Ba (493.408 nm)0.304947 ppm 0.000235 0.08 46185.400000 0.304947
Be (234.861 nm)0.000110 ppm 0.000006 5.02 61.058000 0.000110
Bi (223.061 nm)0.004658 ppm 0.002475 53.15 11.010000 0.004658
Ca (315.887 nm)116.146024 o ppm 0.270947 0.23 78307.082993 116.146024 o
Cd (214.439 nm)0.000416 ppm 0.000160 38.49 6.342140 0.000416
Co (228.615 nm)0.000678 ppm 0.000320 47.26 55.948600 0.000678
Cr (205.560 nm)0.000780 ppm 0.000489 62.66 4.718270 0.000780
Cu (324.754 nm)0.001349 ppm 0.000326 24.18 766.975000 0.001349
Fe (238.204 nm)0.222155 ppm 0.002074 0.93 891.116357 0.222155
Fe H (259.940 nm)0.305947 u ppm 0.000899 0.29 356.737000 0.305947 u
K (766.491 nm)1.829980 ppm 0.026650 1.46 2840.430000 1.829980
Li (670.783 nm)0.064973 ppm 0.003649 5.62 -1864.300000 0.064973
Mg (279.078 nm)55.152900 o ppm 0.337801 0.61 184478.000000 55.152900 o
Mn (257.610 nm)0.362280 ppm 0.002210 0.61 96668.400000 0.362280
Mo (202.032 nm)0.004630 ppm 0.000213 4.59 26.453200 0.004630
Na (589.592 nm)188.275000 o ppm 1.413220 0.75 2293120.000000 188.275000 o
Na H (589.593 nm)178.407086 ppm 1.419030 0.80 1656121.188122 178.407086
Ni (231.604 nm)-0.003000 u ppm 0.000256 8.53 -20.424800 -0.003000 u
P (213.618 nm)0.034619 ppm 0.002155 6.23 43.749700 0.034619
Pb (220.353 nm)-0.000504 u ppm 0.002375 > 100.00 -2.803180 -0.000504 u
S (181.972 nm)5.686637 ppm 0.025243 0.44 1184.807091 5.686637
Sb (206.834 nm)-0.002797 u ppm 0.002341 83.67 -1.416000 -0.002797 u
Se (196.026 nm)-0.002420 u ppm 0.002729 > 100.00 3.747070 -0.002420 u
Si (288.158 nm)12.430500 o ppm 0.095938 0.77 91028.000000 12.430500 o
Sn (189.925 nm)0.000712 u ppm 0.001324 > 100.00 2.759680 0.000712 u
Sr (421.552 nm)1.007169 ppm 0.001531 0.15 222392.038597 1.007169
Th (288.505 nm)0.049601 ppm 0.001894 3.82 361.426000 0.049601
Ti (336.122 nm)0.005180 ppm 0.000042 0.81 701.580000 0.005180
Tl (190.794 nm)0.002878 ppm 0.001548 53.81 0.616721 0.002878
U (409.013 nm)0.016021 ppm 0.001890 11.80 94.948500 0.016021
V (292.401 nm)0.002090 ppm 0.000170 8.14 51.275800 0.002090
Zn (206.200 nm)0.001582 ppm 0.001358 85.87 7.573320 0.001582
Zr (343.823 nm)0.000221 ppm 0.000084 38.20 10.661300 0.000221
Test Report
52A112023.esws
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Page 1117 of 1261
Solution Name: 280-184152-C-6-A
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184152-C-6-A 11/21/2023 5:04:34 AM 3:50 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.071639 ppm 0.000470 0.66 184948.019429 0.071639
Ag (328.068 nm)0.000814 ppm 0.000044 5.41 14.955600 0.000814
Al (394.401 nm)0.049971 ppm 0.001170 2.34 1048.210000 0.049971
Al H (396.152 nm)0.006881 u ppm 0.000859 12.49 81.489500 0.006881 u
As (188.980 nm)0.003283 ppm 0.002199 66.99 -0.677287 0.003283
B (249.678 nm)0.295557 ppm 0.000631 0.21 2489.890000 0.295557
Ba (493.408 nm)0.107901 ppm 0.000392 0.36 16341.600000 0.107901
Be (234.861 nm)0.000157 ppm 0.000013 8.06 66.325700 0.000157
Bi (223.061 nm)0.001195 u ppm 0.003230 > 100.00 5.862370 0.001195 u
Ca (315.887 nm)151.576356 o ppm 0.385034 0.25 102201.975789 151.576356 o
Cd (214.439 nm)0.000607 ppm 0.000019 3.06 9.159200 0.000607
Co (228.615 nm)0.000538 ppm 0.000086 16.08 53.088800 0.000538
Cr (205.560 nm)0.000370 u ppm 0.000493 > 100.00 3.026960 0.000370 u
Cu (324.754 nm)0.001190 ppm 0.000145 12.15 742.572000 0.001190
Fe (238.204 nm)0.021860 ppm 0.000292 1.33 102.681739 0.021860
Fe H (259.940 nm)0.111407 u ppm 0.000979 0.88 41.628900 0.111407 u
K (766.491 nm)2.157910 ppm 0.030543 1.42 3429.600000 2.157910
Li (670.783 nm)0.075653 ppm 0.001642 2.17 -1467.100000 0.075653
Mg (279.078 nm)94.961900 o ppm 0.344653 0.36 317626.000000 94.961900 o
Mn (257.610 nm)0.404869 ppm 0.001255 0.31 108032.000000 0.404869
Mo (202.032 nm)0.004766 ppm 0.001169 24.54 27.125800 0.004766
Na (589.592 nm)359.083000 o ppm 1.244950 0.35 4367020.000000 359.083000 o
Na H (589.593 nm)355.653963 ppm 4.827389 1.36 3206066.157679 355.653963
Ni (231.604 nm)-0.003680 u ppm 0.001272 34.56 -22.741100 -0.003680 u
P (213.618 nm)0.020854 ppm 0.001820 8.73 27.502400 0.020854
Pb (220.353 nm)-0.000542 u ppm 0.001092 > 100.00 -2.874440 -0.000542 u
S (181.972 nm)21.256277 o ppm 0.136299 0.64 4356.275097 21.256277 o
Sb (206.834 nm)-0.004910 u ppm 0.004181 85.15 -3.992050 -0.004910 u
Se (196.026 nm)0.000216 u ppm 0.003734 > 100.00 5.414360 0.000216 u
Si (288.158 nm)10.768100 ppm 0.001310 0.01 78947.200000 10.768100
Sn (189.925 nm)-0.004045 u ppm 0.000911 22.51 -0.437207 -0.004045 u
Sr (421.552 nm)1.592397 o ppm 0.004457 0.28 351610.131053 1.592397 o
Th (288.505 nm)0.061504 ppm 0.001870 3.04 385.196000 0.061504
Ti (336.122 nm)-0.000420 u ppm 0.000056 13.34 168.086000 -0.000420 u
Tl (190.794 nm)0.002090 u ppm 0.002341 > 100.00 -0.228481 0.002090 u
U (409.013 nm)0.016948 ppm 0.001710 10.09 99.174000 0.016948
V (292.401 nm)0.002934 ppm 0.000254 8.65 88.783500 0.002934
Zn (206.200 nm)0.003989 ppm 0.000342 8.57 12.764800 0.003989
Zr (343.823 nm)-0.000008 u ppm 0.000137 > 100.00 -8.268660 -0.000008 u
Test Report
52A112023.esws
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Page 1118 of 1261
Solution Name: LB 280-634317/1-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LB 280-634317/1-B 11/21/2023 5:08:57 AM 3:51 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000516 ppm 0.000013 2.54 959.820068 0.000516
Ag (328.068 nm)0.000058 u ppm 0.000169 > 100.00 -25.395500 0.000058 u
Al (394.401 nm)0.002972 ppm 0.000364 12.24 486.071000 0.002972
Al H (396.152 nm)0.003203 u ppm 0.003545 > 100.00 64.961300 0.003203 u
As (188.980 nm)0.002940 ppm 0.001696 57.68 -0.961970 0.002940
B (249.678 nm)0.006897 ppm 0.000705 10.23 73.910000 0.006897
Ba (493.408 nm)0.002606 ppm 0.000148 5.68 394.120000 0.002606
Be (234.861 nm)-0.000007 u ppm 0.000016 > 100.00 38.904100 -0.000007 u
Bi (223.061 nm)-0.000646 u ppm 0.001648 > 100.00 3.125010 -0.000646 u
Ca (315.887 nm)0.149150 ppm 0.001263 0.85 76.576949 0.149150
Cd (214.439 nm)0.000087 u ppm 0.000092 > 100.00 1.376340 0.000087 u
Co (228.615 nm)-0.000216 u ppm 0.000115 53.29 38.717300 -0.000216 u
Cr (205.560 nm)0.000404 ppm 0.000388 96.09 3.185390 0.000404
Cu (324.754 nm)0.001535 ppm 0.000301 19.58 837.800000 0.001535
Fe (238.204 nm)0.012677 ppm 0.000254 2.00 66.505526 0.012677
Fe H (259.940 nm)0.107170 u ppm 0.000579 0.54 34.766000 0.107170 u
K (766.491 nm)0.147213 ppm 0.024998 16.98 -182.923000 0.147213
Li (670.783 nm)0.016358 ppm 0.001001 6.12 -3672.250000 0.016358
Mg (279.078 nm)0.021451 ppm 0.001788 8.33 80.916400 0.021451
Mn (257.610 nm)0.000536 ppm 0.000018 3.31 147.529000 0.000536
Mo (202.032 nm)0.000333 u ppm 0.000479 > 100.00 5.129860 0.000333 u
Na (589.592 nm)325.105000 o ppm 1.173340 0.36 3952780.000000 325.105000 o
Na H (589.593 nm)317.785625 ppm 2.594059 0.82 2873649.110294 317.785625
Ni (231.604 nm)0.000521 ppm 0.000339 65.05 -8.435780 0.000521
P (213.618 nm)0.001367 ppm 0.000890 65.13 4.648310 0.001367
Pb (220.353 nm)0.001138 ppm 0.001164 > 100.00 0.966199 0.001138
S (181.972 nm)-0.011044 u ppm 0.009236 83.63 21.819572 -0.011044 u
Sb (206.834 nm)-0.001042 u ppm 0.001818 > 100.00 0.738833 -0.001042 u
Se (196.026 nm)-0.001932 u ppm 0.000923 47.78 3.828670 -0.001932 u
Si (288.158 nm)0.014331 ppm 0.002476 17.28 815.372000 0.014331
Sn (189.925 nm)-0.001733 u ppm 0.000866 49.96 1.116070 -0.001733 u
Sr (421.552 nm)0.000582 ppm 0.000064 11.04 138.245591 0.000582
Th (288.505 nm)0.005451 ppm 0.001286 23.59 270.695000 0.005451
Ti (336.122 nm)0.000094 ppm 0.000050 52.52 -107.523000 0.000094
Tl (190.794 nm)0.002208 u ppm 0.002041 92.44 -0.091076 0.002208 u
U (409.013 nm)-0.010153 u ppm 0.001204 11.86 -21.262200 -0.010153 u
V (292.401 nm)0.000041 u ppm 0.000147 > 100.00 -36.945100 0.000041 u
Zn (206.200 nm)0.002809 ppm 0.000757 26.96 10.220300 0.002809
Zr (343.823 nm)-0.000203 u ppm 0.000075 37.00 -24.176700 -0.000203 u
Test Report
52A112023.esws
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Page 1119 of 1261
Solution Name: LCS 280-634317/2-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
LCS 280-634317/2-B 11/21/2023 5:13:23 AM 3:52 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.125097 o ppm 0.002643 0.23 2886449.468981 1.125097 o
Ag (328.068 nm)0.265902 ppm 0.000762 0.29 13829.600000 0.265902
Al (394.401 nm)10.360100 o ppm 0.017636 0.17 127935.000000 10.360100 o
Al H (396.152 nm)9.661400 ppm 0.038046 0.39 43470.900000 9.661400
As (188.980 nm)1.668400 o ppm 0.003573 0.21 1382.740000 1.668400 o
B (249.678 nm)2.031040 ppm 0.008386 0.41 17015.300000 2.031040
Ba (493.408 nm)3.096910 ppm 0.004407 0.14 469067.000000 3.096910
Be (234.861 nm)1.013680 ppm 0.002710 0.27 169528.000000 1.013680
Bi (223.061 nm)0.002114 ppm 0.001801 85.21 7.227590 0.002114
Ca (315.887 nm)50.436949 o ppm 0.055779 0.11 33991.628844 50.436949 o
Cd (214.439 nm)1.196920 o ppm 0.003623 0.30 17892.400000 1.196920 o
Co (228.615 nm)0.995115 ppm 0.001788 0.18 19059.200000 0.995115
Cr (205.560 nm)2.050840 o ppm 0.002736 0.13 8435.170000 2.050840 o
Cu (324.754 nm)1.433000 o ppm 0.001277 0.09 67594.000000 1.433000 o
Fe (238.204 nm)10.091371 o ppm 0.040199 0.40 39755.258882 10.091371 o
Fe H (259.940 nm)9.931190 ppm 0.031914 0.32 15947.400000 9.931190
K (766.491 nm)52.118600 ppm 0.231922 0.44 93191.600000 52.118600
Li (670.783 nm)1.010620 ppm 0.004840 0.48 33304.000000 1.010620
Mg (279.078 nm)50.578200 o ppm 0.104997 0.21 169171.000000 50.578200 o
Mn (257.610 nm)0.992648 ppm 0.002112 0.21 264864.000000 0.992648
Mo (202.032 nm)1.010700 ppm 0.003200 0.32 5018.640000 1.010700
Na (589.592 nm)348.724000 o ppm 1.527450 0.44 4276120.000000 348.724000 o
Na H (589.593 nm)345.334813 ppm 4.723169 1.37 3141610.032705 345.334813
Ni (231.604 nm)0.991608 ppm 0.002363 0.24 3367.030000 0.991608
P (213.618 nm)20.741000 o ppm 0.041649 0.20 24386.100000 20.741000 o
Pb (220.353 nm)2.146510 ppm 0.004478 0.21 4926.570000 2.146510
S (181.972 nm)18.996858 o ppm 0.074860 0.39 3898.806793 18.996858 o
Sb (206.834 nm)1.043980 ppm 0.004489 0.43 1280.690000 1.043980
Se (196.026 nm)1.224430 o ppm 0.011168 0.91 756.004000 1.224430 o
Si (288.158 nm)9.786550 ppm 0.029876 0.31 72306.500000 9.786550
Sn (189.925 nm)0.999869 ppm 0.003547 0.35 674.179000 0.999869
Sr (421.552 nm)1.000551 ppm 0.000969 0.10 220930.725946 1.000551
Th (288.505 nm)0.064367 ppm 0.004420 6.87 361.458000 0.064367
Ti (336.122 nm)1.008950 ppm 0.001933 0.19 110088.000000 1.008950
Tl (190.794 nm)0.951960 ppm 0.001807 0.19 1028.780000 0.951960
U (409.013 nm)-0.020329 u ppm 0.002182 10.73 -88.170600 -0.020329 u
V (292.401 nm)1.004750 ppm 0.002345 0.23 41493.100000 1.004750
Zn (206.200 nm)0.995336 ppm 0.004550 0.46 2150.470000 0.995336
Zr (343.823 nm)1.008560 ppm 0.001933 0.19 82222.800000 1.008560
Test Report
52A112023.esws
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Page 1120 of 1261
Solution Name: 160-51789-B-1-F
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-F 11/21/2023 5:17:44 AM 3:53 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002550 ppm 0.000033 1.30 6560.088222 0.002550
Ag (328.068 nm)0.000636 ppm 0.000180 28.27 5.016100 0.000636
Al (394.401 nm)0.062938 ppm 0.000894 1.42 1218.830000 0.062938
Al H (396.152 nm)0.035365 u ppm 0.003050 8.63 209.500000 0.035365 u
As (188.980 nm)0.005436 ppm 0.003228 59.39 1.111740 0.005436
B (249.678 nm)0.023806 ppm 0.000716 3.01 215.425000 0.023806
Ba (493.408 nm)0.174538 ppm 0.000641 0.37 26433.900000 0.174538
Be (234.861 nm)0.000131 ppm 0.000022 17.13 61.922100 0.000131
Bi (223.061 nm)-0.000872 u ppm 0.001664 > 100.00 2.788040 -0.000872 u
Ca (315.887 nm)54.656409 o ppm 0.220547 0.40 36837.313044 54.656409 o
Cd (214.439 nm)0.005251 ppm 0.000160 3.06 78.569800 0.005251
Co (228.615 nm)0.008921 ppm 0.000201 2.26 212.969000 0.008921
Cr (205.560 nm)0.007487 ppm 0.000595 7.94 32.264900 0.007487
Cu (324.754 nm)0.702866 ppm 0.006357 0.90 33529.900000 0.702866
Fe (238.204 nm)0.017678 ppm 0.000410 2.32 86.261715 0.017678
Fe H (259.940 nm)0.108716 u ppm 0.000504 0.46 37.270100 0.108716 u
K (766.491 nm)1.217730 ppm 0.006227 0.51 1740.420000 1.217730
Li (670.783 nm)0.018427 ppm 0.001194 6.48 -3595.330000 0.018427
Mg (279.078 nm)6.378830 ppm 0.030964 0.49 21343.700000 6.378830
Mn (257.610 nm)0.801332 ppm 0.004125 0.51 213817.000000 0.801332
Mo (202.032 nm)0.001064 ppm 0.000644 60.50 8.757190 0.001064
Na (589.592 nm)320.852000 o ppm 1.419260 0.44 3903090.000000 320.852000 o
Na H (589.593 nm)315.381656 ppm 5.265702 1.67 2854091.715511 315.381656
Ni (231.604 nm)0.053518 ppm 0.000771 1.44 172.025000 0.053518
P (213.618 nm)0.016328 ppm 0.000968 5.93 -14.583700 0.016328
Pb (220.353 nm)0.066354 ppm 0.000578 0.87 150.864000 0.066354
S (181.972 nm)2.216826 ppm 0.032379 1.46 477.430828 2.216826
Sb (206.834 nm)0.011765 ppm 0.003576 30.40 16.394100 0.011765
Se (196.026 nm)0.002394 u ppm 0.002393 99.99 7.013490 0.002394 u
Si (288.158 nm)1.745080 ppm 0.009853 0.56 13390.900000 1.745080
Sn (189.925 nm)-0.000094 u ppm 0.001323 > 100.00 2.217710 -0.000094 u
Sr (421.552 nm)0.245998 ppm 0.001071 0.44 54326.005188 0.245998
Th (288.505 nm)0.027777 ppm 0.003594 12.94 328.630000 0.027777
Ti (336.122 nm)0.000486 ppm 0.000020 4.16 54.569200 0.000486
Tl (190.794 nm)0.001348 ppm 0.000637 47.25 -1.009340 0.001348
U (409.013 nm)0.003913 u ppm 0.007291 > 100.00 41.058000 0.003913 u
V (292.401 nm)0.001754 ppm 0.000207 11.82 34.055200 0.001754
Zn (206.200 nm)2.221870 o ppm 0.013674 0.62 4795.330000 2.221870 o
Zr (343.823 nm)0.000176 u ppm 0.000167 94.84 6.728360 0.000176 u
Test Report
52A112023.esws
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Page 1121 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 5:22:05 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000042 ppm 0.000002 4.04 1040.784405 0.000042
Ag (328.068 nm)0.000134 u ppm 0.000123 91.92 119.747000 0.000134 u
Al (394.401 nm)51.889500 o ppm 0.244378 0.47 637911.000000 51.889500 o
Al H (396.152 nm)49.061700 ppm 0.262756 0.54 220544.000000 49.061700
As (188.980 nm)0.005346 ppm 0.001141 21.35 0.588185 0.005346
B (249.678 nm)-0.001983 u ppm 0.000478 24.10 -0.412465 -0.001983 u
Ba (493.408 nm)0.000270 ppm 0.000086 31.96 181.729000 0.000270
Be (234.861 nm)-0.000014 u ppm 0.000029 > 100.00 686.339000 -0.000014 u
Bi (223.061 nm)-0.001834 u ppm 0.000448 24.43 1.358040 -0.001834 u
Ca (315.887 nm)-0.021728 u ppm 0.003839 17.67 -38.666114 -0.021728 u
Cd (214.439 nm)-0.000020 u ppm 0.000289 > 100.00 10.064000 -0.000020 u
Co (228.615 nm)0.000160 ppm 0.000096 59.87 45.900700 0.000160
Cr (205.560 nm)0.000514 ppm 0.000474 92.07 3.638860 0.000514
Cu (324.754 nm)-0.001005 u ppm 0.000170 16.92 1661.480000 -0.001005 u
Fe (238.204 nm)50.415668 o ppm 0.272274 0.54 198473.293096 50.415668 o
Fe H (259.940 nm)48.780000 ppm 0.263002 0.54 78873.500000 48.780000
K (766.491 nm)0.062287 ppm 0.039754 63.82 -335.504000 0.062287
Li (670.783 nm)0.015005 ppm 0.002252 15.01 -3722.570000 0.015005
Mg (279.078 nm)0.004344 ppm 0.001284 29.56 -166.434000 0.004344
Mn (257.610 nm)-0.000913 u ppm 0.000007 0.80 -239.178000 -0.000913 u
Mo (202.032 nm)-0.000016 u ppm 0.000633 > 100.00 3.397530 -0.000016 u
Na (589.592 nm)244.473000 o ppm 1.886410 0.77 2972660.000000 244.473000 o
Na H (589.593 nm)233.966000 ppm 2.492715 1.07 2139860.579820 233.966000
Ni (231.604 nm)0.000451 u ppm 0.001427 > 100.00 -8.674840 0.000451 u
P (213.618 nm)4.997920 ppm 0.032334 0.65 5902.640000 4.997920
Pb (220.353 nm)0.001001 u ppm 0.001114 > 100.00 -0.870461 0.001001 u
S (181.972 nm)4.721765 ppm 0.040499 0.86 987.557180 4.721765
Sb (206.834 nm)-0.001339 u ppm 0.001950 > 100.00 3.850380 -0.001339 u
Se (196.026 nm)0.005564 ppm 0.000863 15.51 3.150020 0.005564
Si (288.158 nm)0.025334 ppm 0.001854 7.32 896.442000 0.025334
Sn (189.925 nm)0.002162 u ppm 0.003920 > 100.00 3.733730 0.002162 u
Sr (421.552 nm)0.000452 ppm 0.000010 2.21 109.510043 0.000452
Th (288.505 nm)4.529240 ppm 0.016825 0.37 8725.060000 4.529240
Ti (336.122 nm)0.000763 ppm 0.000025 3.23 -34.824100 0.000763
Tl (190.794 nm)-0.004265 u ppm 0.001374 32.21 -8.024860 -0.004265 u
U (409.013 nm)2.399230 Q ppm 0.016600 0.69 10717.700000 Q 2.399230 Q
V (292.401 nm)0.000922 ppm 0.000112 12.16 280.254000 0.000922
Zn (206.200 nm)0.000152 u ppm 0.000790 > 100.00 4.491150 0.000152 u
Zr (343.823 nm)-0.000734 u ppm 0.000017 2.36 0.640372 -0.000734 u
Test Report
52A112023.esws
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Page 1122 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 5:26:31 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.451449 ppm 0.000721 0.16 1157626.911465 0.451449
Ag (328.068 nm)0.504565 ppm 0.002475 0.49 26951.700000 0.504565
Al (394.401 nm)0.493512 ppm 0.001762 0.36 6521.360000 0.493512
Al H (396.152 nm)0.502891 u ppm 0.002860 0.57 2310.660000 0.502891 u
As (188.980 nm)0.501054 ppm 0.001925 0.38 412.888000 0.501054
B (249.678 nm)0.492905 ppm 0.000362 0.07 4141.630000 0.492905
Ba (493.408 nm)0.504493 ppm 0.002495 0.49 76413.900000 0.504493
Be (234.861 nm)0.511888 ppm 0.003518 0.69 85595.300000 0.511888
Bi (223.061 nm)1.002460 ppm 0.003014 0.30 1494.520000 1.002460
Ca (315.887 nm)5.032989 ppm 0.012862 0.26 3370.331045 5.032989
Cd (214.439 nm)0.511228 ppm 0.001227 0.24 7641.850000 0.511228
Co (228.615 nm)0.508874 ppm 0.000995 0.20 9766.720000 0.508874
Cr (205.560 nm)0.514888 ppm 0.001119 0.22 2117.850000 0.514888
Cu (324.754 nm)0.501269 ppm 0.000872 0.17 24148.800000 0.501269
Fe (238.204 nm)2.525664 ppm 0.015252 0.60 9965.011492 2.525664
Fe H (259.940 nm)2.535460 u ppm 0.013033 0.51 3968.040000 2.535460 u
K (766.491 nm)50.463100 ppm 0.189147 0.37 90217.100000 50.463100
Li (670.783 nm)0.504712 ppm 0.005166 1.02 14489.400000 0.504712
Mg (279.078 nm)20.183800 ppm 0.033344 0.17 67515.900000 20.183800
Mn (257.610 nm)0.496193 ppm 0.000700 0.14 132399.000000 0.496193
Mo (202.032 nm)0.504272 ppm 0.000474 0.09 2505.720000 0.504272
Na (589.592 nm)24.576200 ppm 0.129608 0.53 305675.000000 24.576200
Na H (589.593 nm)14.721773 u ppm 0.159749 1.09 224918.635110 14.721773 u
Ni (231.604 nm)0.516595 ppm 0.000613 0.12 1749.220000 0.516595
P (213.618 nm)0.011174 ppm 0.000538 4.82 -24.229000 0.011174
Pb (220.353 nm)0.539446 ppm 0.003153 0.58 1236.050000 0.539446
S (181.972 nm)-0.023692 u ppm 0.006468 27.30 21.733981 -0.023692 u
Sb (206.834 nm)0.494699 ppm 0.003709 0.75 604.423000 0.494699
Se (196.026 nm)0.506513 ppm 0.004590 0.91 315.909000 0.506513
Si (288.158 nm)4.915030 ppm 0.022546 0.46 36668.400000 4.915030
Sn (189.925 nm)0.505069 ppm 0.003143 0.62 341.680000 0.505069
Sr (421.552 nm)0.502555 ppm 0.002590 0.52 110973.643432 0.502555
Th (288.505 nm)0.033437 ppm 0.000916 2.74 311.076000 0.033437
Ti (336.122 nm)0.502171 ppm 0.000552 0.11 54689.300000 0.502171
Tl (190.794 nm)0.503221 ppm 0.004628 0.92 542.801000 0.503221
U (409.013 nm)-0.006073 u ppm 0.002404 39.59 -16.526000 -0.006073 u
V (292.401 nm)0.501660 ppm 0.000856 0.17 20849.200000 0.501660
Zn (206.200 nm)0.510630 ppm 0.000924 0.18 1105.270000 0.510630
Zr (343.823 nm)0.499205 ppm 0.000713 0.14 40690.600000 0.499205
Test Report
52A112023.esws
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Page 1123 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 5:30:51 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000490 ppm 0.000014 2.80 661.429586 0.000490
Ag (328.068 nm)0.000184 ppm 0.000086 47.03 -19.419400 0.000184
Al (394.401 nm)-0.001992 u ppm 0.000552 27.73 426.794000 -0.001992 u
Al H (396.152 nm)-0.000910 u ppm 0.002662 > 100.00 46.473400 -0.000910 u
As (188.980 nm)0.000940 ppm 0.000971 > 100.00 -2.623580 0.000940
B (249.678 nm)0.000515 ppm 0.000469 91.08 20.487600 0.000515
Ba (493.408 nm)0.000071 u ppm 0.000089 > 100.00 10.089900 0.000071 u
Be (234.861 nm)0.000036 ppm 0.000018 50.30 45.876800 0.000036
Bi (223.061 nm)-0.000401 u ppm 0.002782 > 100.00 3.489020 -0.000401 u
Ca (315.887 nm)0.014063 ppm 0.008411 59.81 -14.528301 0.014063
Cd (214.439 nm)0.000070 u ppm 0.000103 > 100.00 1.130200 0.000070 u
Co (228.615 nm)-0.000122 u ppm 0.000109 89.33 40.521900 -0.000122 u
Cr (205.560 nm)-0.000563 u ppm 0.000320 56.78 -0.794069 -0.000563 u
Cu (324.754 nm)0.000021 u ppm 0.000119 > 100.00 766.187000 0.000021 u
Fe (238.204 nm)0.000943 ppm 0.000367 38.87 20.318010 0.000943
Fe H (259.940 nm)0.093004 u ppm 0.001344 1.45 11.818800 0.093004 u
K (766.491 nm)-0.015231 u ppm 0.057252 > 100.00 -474.777000 -0.015231 u
Li (670.783 nm)0.013135 S ppm 0.000594 4.52 -3792.120000 S 0.013135 S
Mg (279.078 nm)-0.000026 u ppm 0.000328 > 100.00 8.871330 -0.000026 u
Mn (257.610 nm)-0.000023 u ppm 0.000018 79.76 -1.657250 -0.000023 u
Mo (202.032 nm)0.000730 ppm 0.000131 17.90 7.099400 0.000730
Na (589.592 nm)0.127664 ppm 0.023340 18.28 2587.650000 0.127664
Na H (589.593 nm)-9.853029 u ppm 0.028893 0.29 5419.611317 -9.853029 u
Ni (231.604 nm)0.000448 ppm 0.000225 50.14 -8.684090 0.000448
P (213.618 nm)0.000912 u ppm 0.002626 > 100.00 4.175830 0.000912 u
Pb (220.353 nm)0.000901 ppm 0.000740 82.13 0.448625 0.000901
S (181.972 nm)-0.039501 u ppm 0.006248 15.82 16.022404 -0.039501 u
Sb (206.834 nm)0.001591 ppm 0.000805 50.58 3.938940 0.001591
Se (196.026 nm)0.000999 u ppm 0.001134 > 100.00 5.628030 0.000999 u
Si (288.158 nm)-0.002566 u ppm 0.000998 38.90 693.365000 -0.002566 u
Sn (189.925 nm)0.000959 u ppm 0.003604 > 100.00 2.925200 0.000959 u
Sr (421.552 nm)0.000112 ppm 0.000055 49.34 34.503305 0.000112
Th (288.505 nm)0.003155 ppm 0.000755 23.93 266.426000 0.003155
Ti (336.122 nm)0.000006 u ppm 0.000043 > 100.00 -117.374000 0.000006 u
Tl (190.794 nm)0.001710 ppm 0.000975 57.03 -0.633436 0.001710
U (409.013 nm)-0.000303 u ppm 0.000825 > 100.00 22.101600 -0.000303 u
V (292.401 nm)0.000065 ppm 0.000056 85.59 -36.618500 0.000065
Zn (206.200 nm)-0.001593 u ppm 0.000050 3.16 0.727811 -0.001593 u
Zr (343.823 nm)0.000042 u ppm 0.000085 > 100.00 -4.214460 0.000042 u
Test Report
52A112023.esws
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Page 1124 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 5:34:54 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014276 ppm 0.000036 0.25 36109.669453 0.014276
Ag (328.068 nm)0.009840 ppm 0.000142 1.44 494.419000 0.009840
Al (394.401 nm)0.087267 ppm 0.000480 0.55 1535.630000 0.087267
Al H (396.152 nm)0.095273 u ppm 0.000125 0.13 478.739000 0.095273 u
As (188.980 nm)0.014912 ppm 0.002364 15.85 8.984800 0.014912
B (249.678 nm)0.094594 ppm 0.000396 0.42 807.898000 0.094594
Ba (493.408 nm)0.009910 ppm 0.000372 3.75 1500.600000 0.009910
Be (234.861 nm)0.001012 ppm 0.000012 1.18 210.160000 0.001012
Bi (223.061 nm)-0.000169 Qu ppm 0.001465 > 100.00 3.833130 Q -0.000169 Qu
Ca (315.887 nm)0.209926 ppm 0.002779 1.32 117.565797 0.209926
Cd (214.439 nm)0.005211 ppm 0.000202 3.88 77.986400 0.005211
Co (228.615 nm)0.010184 ppm 0.000093 0.91 237.394000 0.010184
Cr (205.560 nm)0.010027 ppm 0.000421 4.20 42.673100 0.010027
Cu (324.754 nm)0.014625 ppm 0.000246 1.68 1440.730000 0.014625
Fe (238.204 nm)0.100361 ppm 0.000265 0.26 411.729380 0.100361
Fe H (259.940 nm)0.191781 u ppm 0.003243 1.69 171.816000 0.191781 u
K (766.491 nm)3.009260 ppm 0.024116 0.80 4959.180000 3.009260
Li (670.783 nm)0.031443 Q ppm 0.002303 7.33 -3111.250000 Q 0.031443 Q
Mg (279.078 nm)0.199232 ppm 0.002638 1.32 674.710000 0.199232
Mn (257.610 nm)0.010099 ppm 0.000033 0.33 2699.130000 0.010099
Mo (202.032 nm)0.020147 ppm 0.000151 0.75 103.447000 0.020147
Na (589.592 nm)1.096910 ppm 0.014986 1.37 14487.500000 1.096910
Na H (589.593 nm)-8.937523 u ppm 0.024408 0.27 13521.619188 -8.937523 u
Ni (231.604 nm)0.041910 ppm 0.000585 1.40 132.508000 0.041910
P (213.618 nm)2.821770 ppm 0.010111 0.36 3333.170000 2.821770
Pb (220.353 nm)0.010725 ppm 0.000861 8.02 23.056700 0.010725
S (181.972 nm)0.056499 Q ppm 0.007594 13.44 35.644805 Q 0.056499 Q
Sb (206.834 nm)0.020796 ppm 0.002121 10.20 27.265700 0.020796
Se (196.026 nm)0.020063 ppm 0.005335 26.59 17.323300 0.020063
Si (288.158 nm)0.458547 ppm 0.004912 1.07 4074.010000 0.458547
Sn (189.925 nm)0.099912 ppm 0.002305 2.31 69.420200 0.099912
Sr (421.552 nm)0.009791 ppm 0.000051 0.52 2171.599900 0.009791
Th (288.505 nm)0.002683 Q ppm 0.000470 17.50 265.663000 Q 0.002683 Q
Ti (336.122 nm)0.009565 ppm 0.000042 0.44 925.975000 0.009565
Tl (190.794 nm)0.016261 ppm 0.002144 13.19 15.123800 0.016261
U (409.013 nm)0.056055 ppm 0.002895 5.16 269.931000 0.056055
V (292.401 nm)0.009776 ppm 0.000031 0.31 362.638000 0.009776
Zn (206.200 nm)0.019780 ppm 0.000126 0.64 46.815200 0.019780
Zr (343.823 nm)0.009724 ppm 0.000121 1.24 785.154000 0.009724
Test Report
52A112023.esws
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Page 1125 of 1261
Solution Name: 160-51789-B-1-F SD @5
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-F SD @5 11/21/2023 5:39:10 AM 3:54 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000821 ppm 0.000009 1.15 1635.357442 0.000821
Ag (328.068 nm)0.000231 ppm 0.000063 27.44 -17.122900 0.000231
Al (394.401 nm)0.013395 ppm 0.000996 7.43 615.115000 0.013395
Al H (396.152 nm)0.006979 u ppm 0.000897 12.85 81.930600 0.006979 u
As (188.980 nm)0.002098 ppm 0.000765 36.46 -1.661120 0.002098
B (249.678 nm)0.004112 ppm 0.000828 20.13 50.600000 0.004112
Ba (493.408 nm)0.035724 ppm 0.000700 1.96 5410.020000 0.035724
Be (234.861 nm)0.000034 ppm 0.000023 67.31 45.680600 0.000034
Bi (223.061 nm)-0.001141 u ppm 0.000676 59.25 2.388120 -0.001141 u
Ca (315.887 nm)11.231780 o ppm 0.073413 0.65 7550.914141 11.231780 o
Cd (214.439 nm)0.001141 ppm 0.000104 9.14 17.136300 0.001141
Co (228.615 nm)0.001524 ppm 0.000067 4.39 71.905200 0.001524
Cr (205.560 nm)0.001466 ppm 0.000581 39.61 7.540100 0.001466
Cu (324.754 nm)0.139933 ppm 0.000544 0.39 7287.800000 0.139933
Fe (238.204 nm)0.008423 ppm 0.000637 7.56 49.777349 0.008423
Fe H (259.940 nm)0.100761 u ppm 0.001655 1.64 24.383500 0.100761 u
K (766.491 nm)0.228807 ppm 0.014709 6.43 -36.326700 0.228807
Li (670.783 nm)0.005479 u ppm 0.013519 > 100.00 -4076.840000 0.005479 u
Mg (279.078 nm)1.306150 ppm 0.004549 0.35 4377.600000 1.306150
Mn (257.610 nm)0.164124 ppm 0.000463 0.28 43796.200000 0.164124
Mo (202.032 nm)0.000645 ppm 0.000379 58.81 6.679480 0.000645
Na (589.592 nm)65.711100 o ppm 0.686373 1.04 800184.000000 65.711100 o
Na H (589.593 nm)75.053266 ppm 11.5308
50 15.36 749014.232487 75.053266
Ni (231.604 nm)0.011410 ppm 0.000339 2.97 28.642300 0.011410
P (213.618 nm)0.001502 u ppm 0.002941 > 100.00 -2.475650 0.001502 u
Pb (220.353 nm)0.014988 ppm 0.000535 3.57 32.816600 0.014988
S (181.972 nm)0.411618 ppm 0.007766 1.89 108.283220 0.411618
Sb (206.834 nm)0.002887 ppm 0.000790 27.37 5.533450 0.002887
Se (196.026 nm)-0.001242 u ppm 0.002673 > 100.00 4.360930 -0.001242 u
Si (288.158 nm)0.337950 ppm 0.001524 0.45 3167.180000 0.337950
Sn (189.925 nm)0.000175 u ppm 0.002050 > 100.00 2.398430 0.000175 u
Sr (421.552 nm)0.049939 ppm 0.001017 2.04 11036.242732 0.049939
Th (288.505 nm)0.009041 ppm 0.004151 45.91 280.723000 0.009041
Ti (336.122 nm)0.000082 ppm 0.000042 51.68 -84.633100 0.000082
Tl (190.794 nm)0.001244 ppm 0.001056 84.91 -1.135510 0.001244
U (409.013 nm)0.002221 ppm 0.001170 52.69 33.270100 0.002221
V (292.401 nm)0.000559 ppm 0.000143 25.59 -16.130900 0.000559
Zn (206.200 nm)0.460769 ppm 0.001768 0.38 997.749000 0.460769
Zr (343.823 nm)0.000011 u ppm 0.000047 > 100.00 -6.735170 0.000011 u
Test Report
52A112023.esws
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Page 1126 of 1261
Solution Name: 160-51789-B-1-G MS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-G MS 11/21/2023 5:43:31 AM 3:55 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.160954 o ppm 0.004907 0.42 2978796.371825 1.160954 o
Ag (328.068 nm)0.274095 ppm 0.001197 0.44 14259.000000 0.274095
Al (394.401 nm)10.648600 o ppm 0.049639 0.47 131477.000000 10.648600 o
Al H (396.152 nm)9.906490 ppm 0.020401 0.21 44572.300000 9.906490
As (188.980 nm)1.714210 o ppm 0.007088 0.41 1420.800000 1.714210 o
B (249.678 nm)2.098150 ppm 0.008836 0.42 17577.000000 2.098150
Ba (493.408 nm)3.287910 ppm 0.003850 0.12 497995.000000 3.287910
Be (234.861 nm)1.032000 ppm 0.009225 0.89 172591.000000 1.032000
Bi (223.061 nm)0.003529 ppm 0.001628 46.12 9.332000 0.003529
Ca (315.887 nm)104.523449 o ppm 0.222361 0.21 70468.596786 104.523449 o
Cd (214.439 nm)1.226970 o ppm 0.005569 0.45 18341.600000 1.226970 o
Co (228.615 nm)1.016200 ppm 0.005458 0.54 19462.300000 1.016200
Cr (205.560 nm)2.110280 o ppm 0.006254 0.30 8679.580000 2.110280 o
Cu (324.754 nm)2.129080 o ppm 0.020137 0.95 100044.000000 2.129080 o
Fe (238.204 nm)10.224218 o ppm 0.028941 0.28 40278.573415 10.224218 o
Fe H (259.940 nm)10.068400 ppm 0.020551 0.20 16169.700000 10.068400
K (766.491 nm)54.412300 ppm 0.186488 0.34 97312.500000 54.412300
Li (670.783 nm)1.037340 ppm 0.002973 0.29 34297.500000 1.037340
Mg (279.078 nm)58.018700 o ppm 0.258770 0.45 194057.000000 58.018700 o
Mn (257.610 nm)1.795360 o ppm 0.008198 0.46 479044.000000 1.795360 o
Mo (202.032 nm)1.041480 ppm 0.004221 0.41 5171.370000 1.041480
Na (589.592 nm)364.629000 o ppm 0.564942 0.15 4471680.000000 364.629000 o
Na H (589.593 nm)357.626476 ppm 2.482190 0.69 3250861.129743 357.626476
Ni (231.604 nm)1.060560 ppm 0.006627 0.62 3601.850000 1.060560
P (213.618 nm)21.278700 o ppm 0.111784 0.53 24983.400000 21.278700 o
Pb (220.353 nm)2.253070 ppm 0.013960 0.62 5171.380000 2.253070
S (181.972 nm)21.650269 o ppm 0.119960 0.55 4441.161943 21.650269 o
Sb (206.834 nm)1.084080 ppm 0.001330 0.12 1329.740000 1.084080
Se (196.026 nm)1.247450 o ppm 0.013496 1.08 770.652000 1.247450 o
Si (288.158 nm)11.669100 o ppm 0.072149 0.62 85995.800000 11.669100 o
Sn (189.925 nm)1.022780 ppm 0.008280 0.81 689.574000 1.022780
Sr (421.552 nm)1.257024 o ppm 0.003123 0.25 277560.008782 1.257024 o
Th (288.505 nm)0.083231 ppm 0.001386 1.66 412.086000 0.083231
Ti (336.122 nm)1.032710 ppm 0.004705 0.46 112800.000000 1.032710
Tl (190.794 nm)0.971635 ppm 0.006043 0.62 1050.070000 0.971635
U (409.013 nm)-0.011681 u ppm 0.001757 15.04 -50.138100 -0.011681 u
V (292.401 nm)1.031030 ppm 0.004089 0.40 42580.600000 1.031030
Zn (206.200 nm)3.117800 o ppm 0.016324 0.52 6727.280000 3.117800 o
Zr (343.823 nm)1.030210 ppm 0.004337 0.42 83987.900000 1.030210
Test Report
52A112023.esws
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Page 1127 of 1261
Solution Name: 160-51789-B-1-H MSD
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-H MSD 11/21/2023 5:47:59 AM 3:56 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)1.138204 o ppm 0.001256 0.11 2920416.055696 1.138204 o
Ag (328.068 nm)0.269258 ppm 0.000676 0.25 14003.800000 0.269258
Al (394.401 nm)10.485600 o ppm 0.013807 0.13 129480.000000 10.485600 o
Al H (396.152 nm)9.784940 ppm 0.021512 0.22 44026.100000 9.784940
As (188.980 nm)1.693440 o ppm 0.003453 0.20 1403.540000 1.693440 o
B (249.678 nm)2.071860 ppm 0.002884 0.14 17356.900000 2.071860
Ba (493.408 nm)3.260740 ppm 0.013067 0.40 493879.000000 3.260740
Be (234.861 nm)1.009430 ppm 0.006531 0.65 168819.000000 1.009430
Bi (223.061 nm)0.000776 u ppm 0.002261 > 100.00 5.238850 0.000776 u
Ca (315.887 nm)101.584560 o ppm 0.180684 0.18 68486.553736 101.584560 o
Cd (214.439 nm)1.206500 o ppm 0.001869 0.15 18035.600000 1.206500 o
Co (228.615 nm)1.003600 ppm 0.000796 0.08 19221.100000 1.003600
Cr (205.560 nm)2.073730 o ppm 0.002008 0.10 8529.280000 2.073730 o
Cu (324.754 nm)2.076710 o ppm 0.000880 0.04 97595.300000 2.076710 o
Fe (238.204 nm)10.095731 o ppm 0.021654 0.21 39772.549034 10.095731 o
Fe H (259.940 nm)9.944570 ppm 0.022451 0.23 15969.100000 9.944570
K (766.491 nm)53.712600 ppm 0.213721 0.40 96055.500000 53.712600
Li (670.783 nm)1.024180 ppm 0.005846 0.57 33808.000000 1.024180
Mg (279.078 nm)56.857000 o ppm 0.068702 0.12 190172.000000 56.857000 o
Mn (257.610 nm)1.749330 o ppm 0.001971 0.11 466762.000000 1.749330 o
Mo (202.032 nm)1.021990 ppm 0.000911 0.09 5074.660000 1.021990
Na (589.592 nm)347.626000 o ppm 1.773270 0.51 4264700.000000 347.626000 o
Na H (589.593 nm)343.792611 ppm 2.000473 0.58 3129531.062037 343.792611
Ni (231.604 nm)1.039620 ppm 0.001918 0.18 3530.520000 1.039620
P (213.618 nm)21.036400 o ppm 0.045901 0.22 24700.700000 21.036400 o
Pb (220.353 nm)2.219830 ppm 0.001646 0.07 5095.060000 2.219830
S (181.972 nm)21.300554 o ppm 0.043948 0.21 4369.784425 21.300554 o
Sb (206.834 nm)1.065730 ppm 0.003202 0.30 1307.270000 1.065730
Se (196.026 nm)1.233970 o ppm 0.006915 0.56 762.365000 1.233970 o
Si (288.158 nm)11.444400 o ppm 0.021258 0.19 84355.500000 11.444400 o
Sn (189.925 nm)1.007430 ppm 0.001332 0.13 679.261000 1.007430
Sr (421.552 nm)1.236343 o ppm 0.000915 0.07 272993.580775 1.236343 o
Th (288.505 nm)0.079452 ppm 0.001464 1.84 404.748000 0.079452
Ti (336.122 nm)1.015690 ppm 0.000956 0.09 110935.000000 1.015690
Tl (190.794 nm)0.962094 ppm 0.001044 0.11 1039.760000 0.962094
U (409.013 nm)-0.011961 u ppm 0.004738 39.62 -51.470900 -0.011961 u
V (292.401 nm)1.015370 ppm 0.000955 0.09 41931.900000 1.015370
Zn (206.200 nm)2.995960 o ppm 0.004714 0.16 6464.540000 2.995960 o
Zr (343.823 nm)1.013690 ppm 0.000988 0.10 82641.500000 1.013690
Test Report
52A112023.esws
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Page 1128 of 1261
Solution Name: 160-51789-B-1-F PDS
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-1-F PDS 11/21/2023 5:52:28 AM 3:57 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.113888 ppm 0.000718 0.63 292467.677900 0.113888
Ag (328.068 nm)0.052644 ppm 0.000086 0.16 2779.810000 0.052644
Al (394.401 nm)1.102670 ppm 0.004760 0.43 14016.000000 1.102670
Al H (396.152 nm)0.998333 ppm 0.007021 0.70 4537.280000 0.998333
As (188.980 nm)0.206174 ppm 0.004091 1.98 167.892000 0.206174
B (249.678 nm)0.126839 ppm 0.001592 1.25 1077.780000 0.126839
Ba (493.408 nm)0.268596 ppm 0.001367 0.51 40682.100000 0.268596
Be (234.861 nm)0.050803 ppm 0.000665 1.31 8540.630000 0.050803
Bi (223.061 nm)0.000841 u ppm 0.002066 > 100.00 5.334910 0.000841 u
Ca (315.887 nm)73.508799 o ppm 0.348534 0.47 49551.724926 73.508799 o
Cd (214.439 nm)0.055164 ppm 0.000181 0.33 824.816000 0.055164
Co (228.615 nm)0.058614 ppm 0.000252 0.43 1162.530000 0.058614
Cr (205.560 nm)0.057836 ppm 0.000577 1.00 239.211000 0.057836
Cu (324.754 nm)0.734621 ppm 0.004781 0.65 35010.000000 0.734621
Fe (238.204 nm)1.003791 ppm 0.003059 0.30 3968.632367 1.003791
Fe H (259.940 nm)1.064530 u ppm 0.009541 0.90 1585.460000 1.064530 u
K (766.491 nm)22.053800 ppm 0.092471 0.42 39175.700000 22.053800
Li (670.783 nm)0.110604 ppm 0.004543 4.11 -167.317000 0.110604
Mg (279.078 nm)26.019500 ppm 0.115229 0.44 87023.100000 26.019500
Mn (257.610 nm)0.834417 ppm 0.004086 0.49 222645.000000 0.834417
Mo (202.032 nm)0.051713 ppm 0.000589 1.14 260.082000 0.051713
Na (589.592 nm)334.580000 o ppm 1.754570 0.52 4071060.000000 334.580000 o
Na H (589.593 nm)371.549534 ppm 14.7119
90 3.96 3346610.251219 371.549534
Ni (231.604 nm)0.101403 ppm 0.000584 0.58 335.220000 0.101403
P (213.618 nm)2.086340 ppm 0.004827 0.23 2426.080000 2.086340
Pb (220.353 nm)0.170618 ppm 0.001815 1.06 391.030000 0.170618
S (181.972 nm)2.196400 ppm 0.009223 0.42 474.242931 2.196400
Sb (206.834 nm)0.110765 ppm 0.000904 0.82 137.042000 0.110765
Se (196.026 nm)0.203112 ppm 0.003976 1.96 130.106000 0.203112
Si (288.158 nm)6.601380 ppm 0.032670 0.49 48701.000000 6.601380
Sn (189.925 nm)0.056565 ppm 0.003122 5.52 40.292000 0.056565
Sr (421.552 nm)0.291050 ppm 0.001533 0.53 64273.263710 0.291050
Th (288.505 nm)0.216654 ppm 0.001467 0.68 683.037000 0.216654
Ti (336.122 nm)0.051145 ppm 0.000269 0.53 5623.770000 0.051145
Tl (190.794 nm)0.190487 ppm 0.002356 1.24 204.253000 0.190487
U (409.013 nm)0.483206 ppm 0.005719 1.18 2154.730000 0.483206
V (292.401 nm)0.052344 ppm 0.000266 0.51 2129.620000 0.052344
Zn (206.200 nm)2.340720 o ppm 0.011674 0.50 5051.620000 2.340720 o
Zr (343.823 nm)0.050918 ppm 0.000178 0.35 4144.480000 0.050918
Test Report
52A112023.esws
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Page 1129 of 1261
Solution Name: 160-51789-B-2-D
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-2-D 11/21/2023 5:56:48 AM 3:58 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002172 ppm 0.000016 0.73 5540.215446 0.002172
Ag (328.068 nm)0.000578 ppm 0.000185 32.10 1.778370 0.000578
Al (394.401 nm)0.070529 ppm 0.001167 1.65 1312.220000 0.070529
Al H (396.152 nm)0.047437 u ppm 0.003873 8.17 263.757000 0.047437 u
As (188.980 nm)0.004757 ppm 0.001904 40.02 0.547602 0.004757
B (249.678 nm)0.022193 ppm 0.000090 0.41 201.927000 0.022193
Ba (493.408 nm)0.158493 ppm 0.000398 0.25 24004.000000 0.158493
Be (234.861 nm)0.000078 ppm 0.000014 18.55 53.320400 0.000078
Bi (223.061 nm)-0.000845 u ppm 0.002345 > 100.00 2.828840 -0.000845 u
Ca (315.887 nm)50.121471 o ppm 0.082830 0.17 33778.864027 50.121471 o
Cd (214.439 nm)0.004331 ppm 0.000115 2.65 64.825100 0.004331
Co (228.615 nm)0.010021 ppm 0.000216 2.15 233.979000 0.010021
Cr (205.560 nm)0.001877 ppm 0.000607 32.33 9.185270 0.001877
Cu (324.754 nm)0.487837 ppm 0.002686 0.55 23500.400000 0.487837
Fe (238.204 nm)0.037160 ppm 0.001561 4.20 162.938828 0.037160
Fe H (259.940 nm)0.127348 u ppm 0.000990 0.78 67.448200 0.127348 u
K (766.491 nm)0.876791 ppm 0.037682 4.30 1127.880000 0.876791
Li (670.783 nm)0.017588 ppm 0.002584 14.69 -3626.500000 0.017588
Mg (279.078 nm)6.485810 ppm 0.037790 0.58 21701.500000 6.485810
Mn (257.610 nm)0.837463 ppm 0.004279 0.51 223457.000000 0.837463
Mo (202.032 nm)0.000275 u ppm 0.000309 > 100.00 4.841850 0.000275 u
Na (589.592 nm)311.736000 o ppm 0.881628 0.28 3792100.000000 311.736000 o
Na H (589.593 nm)304.819666 ppm 3.485920 1.14 2761491.866603 304.819666
Ni (231.604 nm)0.057853 ppm 0.000630 1.09 186.786000 0.057853
P (213.618 nm)0.012969 ppm 0.002460 18.97 -7.231810 0.012969
Pb (220.353 nm)0.035942 ppm 0.000579 1.61 80.958300 0.035942
S (181.972 nm)2.167211 ppm 0.019924 0.92 467.270444 2.167211
Sb (206.834 nm)0.003931 ppm 0.002847 72.43 6.809140 0.003931
Se (196.026 nm)-0.001624 u ppm 0.003384 > 100.00 4.570280 -0.001624 u
Si (288.158 nm)1.486000 ppm 0.009244 0.62 11508.100000 1.486000
Sn (189.925 nm)-0.001746 u ppm 0.001673 95.79 1.107460 -0.001746 u
Sr (421.552 nm)0.198155 ppm 0.000303 0.15 43762.278088 0.198155
Th (288.505 nm)0.028448 ppm 0.001303 4.58 330.599000 0.028448
Ti (336.122 nm)0.001475 ppm 0.000053 3.63 152.570000 0.001475
Tl (190.794 nm)0.002484 u ppm 0.002772 > 100.00 0.227098 0.002484 u
U (409.013 nm)0.006235 ppm 0.003518 56.43 51.314200 0.006235
V (292.401 nm)0.001833 ppm 0.000124 6.78 39.162600 0.001833
Zn (206.200 nm)1.582610 o ppm 0.008092 0.51 3416.850000 1.582610 o
Zr (343.823 nm)-0.000005 u ppm 0.000127 > 100.00 -8.051110 -0.000005 u
Test Report
52A112023.esws
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Page 1130 of 1261
Solution Name: 160-51789-B-3-D
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51789-B-3-D 11/21/2023 6:01:08 AM 3:59 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002526 ppm 0.000004 0.16 6587.694118 0.002526
Ag (328.068 nm)0.000847 ppm 0.000045 5.31 17.164100 0.000847
Al (394.401 nm)0.048560 ppm 0.000788 1.62 1039.430000 0.048560
Al H (396.152 nm)0.012863 u ppm 0.001908 14.83 108.371000 0.012863 u
As (188.980 nm)0.002148 u ppm 0.003182 > 100.00 -1.619610 0.002148 u
B (249.678 nm)0.027946 ppm 0.000458 1.64 250.082000 0.027946
Ba (493.408 nm)0.196391 ppm 0.000380 0.19 29743.600000 0.196391
Be (234.861 nm)0.000038 ppm 0.000022 57.73 46.279800 0.000038
Bi (223.061 nm)-0.000707 u ppm 0.000842 > 100.00 3.033740 -0.000707 u
Ca (315.887 nm)86.273597 o ppm 0.179544 0.21 58160.547953 86.273597 o
Cd (214.439 nm)0.005965 ppm 0.000183 3.06 89.237000 0.005965
Co (228.615 nm)0.012681 ppm 0.000275 2.17 284.645000 0.012681
Cr (205.560 nm)0.003141 ppm 0.000139 4.43 14.383000 0.003141
Cu (324.754 nm)0.307227 ppm 0.002684 0.87 15053.700000 0.307227
Fe (238.204 nm)0.008171 ppm 0.000672 8.22 48.849578 0.008171
Fe H (259.940 nm)0.099618 u ppm 0.001142 1.15 22.531900 0.099618 u
K (766.491 nm)1.257180 ppm 0.005198 0.41 1811.290000 1.257180
Li (670.783 nm)0.019686 ppm 0.001725 8.76 -3548.480000 0.019686
Mg (279.078 nm)6.305870 ppm 0.019170 0.30 21099.500000 6.305870
Mn (257.610 nm)1.316120 o ppm 0.003938 0.30 351174.000000 1.316120 o
Mo (202.032 nm)0.001050 ppm 0.000205 19.47 8.689870 0.001050
Na (589.592 nm)327.588000 o ppm 0.572730 0.17 3985230.000000 327.588000 o
Na H (589.593 nm)322.426565 ppm 3.560694 1.10 2915953.617964 322.426565
Ni (231.604 nm)0.056514 ppm 0.000320 0.57 182.227000 0.056514
P (213.618 nm)0.008730 ppm 0.000645 7.38 -2.757420 0.008730
Pb (220.353 nm)0.039938 ppm 0.000338 0.85 90.139500 0.039938
S (181.972 nm)2.398790 ppm 0.013878 0.58 515.642072 2.398790
Sb (206.834 nm)0.003087 ppm 0.003331 > 100.00 5.787170 0.003087
Se (196.026 nm)-0.001284 u ppm 0.001183 92.10 5.098910 -0.001284 u
Si (288.158 nm)1.508380 ppm 0.002710 0.18 11670.800000 1.508380
Sn (189.925 nm)-0.001002 u ppm 0.001236 > 100.00 1.607300 -0.001002 u
Sr (421.552 nm)0.381218 ppm 0.001029 0.27 84182.310360 0.381218
Th (288.505 nm)0.033339 ppm 0.002773 8.32 349.389000 0.033339
Ti (336.122 nm)-0.000299 u ppm 0.000090 29.96 38.206600 -0.000299 u
Tl (190.794 nm)0.000984 ppm 0.000530 53.83 -1.395910 0.000984
U (409.013 nm)0.005219 ppm 0.004892 93.74 46.937200 0.005219
V (292.401 nm)0.001349 ppm 0.000077 5.68 19.279000 0.001349
Zn (206.200 nm)2.336460 o ppm 0.006125 0.26 5042.430000 2.336460 o
Zr (343.823 nm)-0.000055 u ppm 0.000047 85.11 -12.146100 -0.000055 u
Test Report
52A112023.esws
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Page 1131 of 1261
Solution Name: 160-51790-B-1-D
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51790-B-1-D 11/21/2023 6:05:34 AM 3:60 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002131 ppm 0.000005 0.22 5632.980839 0.002131
Ag (328.068 nm)0.000869 ppm 0.000154 17.76 15.407800 0.000869
Al (394.401 nm)0.084398 ppm 0.001391 1.65 1482.690000 0.084398
Al H (396.152 nm)0.056752 u ppm 0.001565 2.76 305.619000 0.056752 u
As (188.980 nm)0.002259 ppm 0.001899 84.06 -1.527990 0.002259
B (249.678 nm)0.022765 ppm 0.000572 2.51 206.716000 0.022765
Ba (493.408 nm)0.293223 ppm 0.000894 0.30 44409.200000 0.293223
Be (234.861 nm)0.000093 ppm 0.000019 20.18 55.747500 0.000093
Bi (223.061 nm)-0.002219 u ppm 0.000410 18.48 0.785576 -0.002219 u
Ca (315.887 nm)62.953378 o ppm 0.236073 0.37 42432.947448 62.953378 o
Cd (214.439 nm)0.005395 ppm 0.000206 3.83 80.721200 0.005395
Co (228.615 nm)0.013529 ppm 0.000223 1.65 300.827000 0.013529
Cr (205.560 nm)0.001866 ppm 0.000645 34.57 9.141080 0.001866
Cu (324.754 nm)0.942205 ppm 0.011316 1.20 44691.500000 0.942205
Fe (238.204 nm)0.028906 ppm 0.000317 1.10 130.465856 0.028906
Fe H (259.940 nm)0.118301 u ppm 0.001489 1.26 52.795300 0.118301 u
K (766.491 nm)1.116520 ppm 0.051647 4.63 1558.580000 1.116520
Li (670.783 nm)0.020647 ppm 0.002670 12.93 -3512.770000 0.020647
Mg (279.078 nm)5.911200 ppm 0.008234 0.14 19779.600000 5.911200
Mn (257.610 nm)1.026910 ppm 0.001759 0.17 274007.000000 1.026910
Mo (202.032 nm)0.000257 u ppm 0.000382 > 100.00 4.751800 0.000257 u
Na (589.592 nm)311.728000 o ppm 1.444230 0.46 3793580.000000 311.728000 o
Na H (589.593 nm)303.576615 ppm 4.862345 1.60 2751775.772528 303.576615
Ni (231.604 nm)0.054066 ppm 0.000178 0.33 173.891000 0.054066
P (213.618 nm)0.019655 ppm 0.000959 4.88 -23.255400 0.019655
Pb (220.353 nm)0.090949 ppm 0.001250 1.37 207.382000 0.090949
S (181.972 nm)0.742103 ppm 0.005109 0.69 177.498167 0.742103
Sb (206.834 nm)0.010381 ppm 0.003656 35.22 14.673400 0.010381
Se (196.026 nm)0.000936 u ppm 0.004419 > 100.00 6.267250 0.000936 u
Si (288.158 nm)1.460240 ppm 0.002276 0.16 11321.500000 1.460240
Sn (189.925 nm)0.000674 u ppm 0.001147 > 100.00 2.734100 0.000674 u
Sr (421.552 nm)0.302532 ppm 0.001003 0.33 66808.515743 0.302532
Th (288.505 nm)0.029777 ppm 0.001378 4.63 336.759000 0.029777
Ti (336.122 nm)0.000031 u ppm 0.000049 > 100.00 23.150300 0.000031 u
Tl (190.794 nm)0.000724 u ppm 0.001367 > 100.00 -1.675410 0.000724 u
U (409.013 nm)0.002900 u ppm 0.003202 > 100.00 36.609900 0.002900 u
V (292.401 nm)0.004389 ppm 0.000155 3.52 146.523000 0.004389
Zn (206.200 nm)5.735670 o ppm 0.005761 0.10 12372.400000 5.735670 o
Zr (343.823 nm)-0.000093 u ppm 0.000088 94.98 -15.191400 -0.000093 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 261 of 287
Page 1132 of 1261
Solution Name: 160-51790-B-2-D
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51790-B-2-D 11/21/2023 6:09:58 AM 3:61 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002160 ppm 0.000016 0.75 5538.544035 0.002160
Ag (328.068 nm)0.000971 ppm 0.000209 21.54 19.237100 0.000971
Al (394.401 nm)0.058423 ppm 0.000899 1.54 1165.250000 0.058423
Al H (396.152 nm)0.029324 u ppm 0.004505 15.36 182.354000 0.029324 u
As (188.980 nm)0.002897 ppm 0.001551 53.53 -0.997641 0.002897
B (249.678 nm)0.022397 ppm 0.000332 1.48 203.637000 0.022397
Ba (493.408 nm)0.317294 ppm 0.000946 0.30 48054.900000 0.317294
Be (234.861 nm)0.000089 ppm 0.000023 26.12 55.003700 0.000089
Bi (223.061 nm)-0.000773 u ppm 0.000497 64.38 2.936510 -0.000773 u
Ca (315.887 nm)63.519507 o ppm 0.288181 0.45 42814.755797 63.519507 o
Cd (214.439 nm)0.003918 ppm 0.000104 2.64 58.639200 0.003918
Co (228.615 nm)0.011216 ppm 0.000379 3.37 256.714000 0.011216
Cr (205.560 nm)0.002343 ppm 0.000291 12.43 11.101300 0.002343
Cu (324.754 nm)0.605515 ppm 0.002469 0.41 28981.000000 0.605515
Fe (238.204 nm)0.019177 ppm 0.001442 7.52 92.145056 0.019177
Fe H (259.940 nm)0.108775 u ppm 0.001953 1.80 37.365400 0.108775 u
K (766.491 nm)1.090870 ppm 0.026458 2.43 1512.500000 1.090870
Li (670.783 nm)0.014794 ppm 0.001100 7.44 -3730.430000 0.014794
Mg (279.078 nm)6.289700 ppm 0.008091 0.13 21045.700000 6.289700
Mn (257.610 nm)1.054460 ppm 0.002041 0.19 281356.000000 1.054460
Mo (202.032 nm)0.000804 ppm 0.000483 60.09 7.465880 0.000804
Na (589.592 nm)322.209000 o ppm 0.880195 0.27 3921250.000000 322.209000 o
Na H (589.593 nm)316.316401 ppm 2.748616 0.87 2863509.100053 316.316401
Ni (231.604 nm)0.053699 ppm 0.000455 0.85 172.640000 0.053699
P (213.618 nm)0.014656 ppm 0.000497 3.39 -11.425700 0.014656
Pb (220.353 nm)0.061986 ppm 0.000616 0.99 140.823000 0.061986
S (181.972 nm)0.665362 ppm 0.011535 1.73 161.909312 0.665362
Sb (206.834 nm)0.006198 ppm 0.001775 28.64 9.573980 0.006198
Se (196.026 nm)-0.001846 u ppm 0.000782 42.38 4.579460 -0.001846 u
Si (288.158 nm)1.362920 ppm 0.003425 0.25 10614.300000 1.362920
Sn (189.925 nm)0.000547 u ppm 0.001205 > 100.00 2.648330 0.000547 u
Sr (421.552 nm)0.319932 ppm 0.001101 0.34 70650.412637 0.319932
Th (288.505 nm)0.032312 ppm 0.002553 7.90 341.988000 0.032312
Ti (336.122 nm)-0.000046 u ppm 0.000116 > 100.00 15.967800 -0.000046 u
Tl (190.794 nm)0.000281 u ppm 0.001159 > 100.00 -2.162270 0.000281 u
U (409.013 nm)0.006759 ppm 0.008243 > 100.00 53.494100 0.006759
V (292.401 nm)0.005832 ppm 0.000136 2.34 206.204000 0.005832
Zn (206.200 nm)1.434250 o ppm 0.004435 0.31 3096.940000 1.434250 o
Zr (343.823 nm)0.000006 u ppm 0.000030 > 100.00 -7.109330 0.000006 u
Test Report
52A112023.esws
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Page 1133 of 1261
Solution Name: 160-51875-A-1-I
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51875-A-1-I 11/21/2023 6:14:25 AM 3:62 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.004959 ppm 0.000032 0.65 13272.034819 0.004959
Ag (328.068 nm)0.000837 ppm 0.000144 17.22 16.205900 0.000837
Al (394.401 nm)0.088195 ppm 0.002006 2.27 1528.930000 0.088195
Al H (396.152 nm)0.051575 u ppm 0.003869 7.50 282.352000 0.051575 u
As (188.980 nm)0.004267 ppm 0.001741 40.80 0.140191 0.004267
B (249.678 nm)0.062511 ppm 0.000727 1.16 539.374000 0.062511
Ba (493.408 nm)0.163938 ppm 0.000300 0.18 24828.700000 0.163938
Be (234.861 nm)0.000056 ppm 0.000017 30.64 50.211200 0.000056
Bi (223.061 nm)-0.002073 u ppm 0.000761 36.71 1.003140 -0.002073 u
Ca (315.887 nm)84.007370 o ppm 0.073572 0.09 56632.161756 84.007370 o
Cd (214.439 nm)0.025805 ppm 0.000117 0.45 385.791000 0.025805
Co (228.615 nm)0.013040 ppm 0.000266 2.04 291.480000 0.013040
Cr (205.560 nm)0.004042 ppm 0.000311 7.69 18.037400 0.004042
Cu (324.754 nm)5.781510 o ppm 0.022565 0.39 270460.000000 5.781510 o
Fe (238.204 nm)0.082590 ppm 0.000935 1.13 342.038382 0.082590
Fe H (259.940 nm)0.172754 u ppm 0.004015 2.32 140.997000 0.172754 u
K (766.491 nm)1.534830 ppm 0.020751 1.35 2310.150000 1.534830
Li (670.783 nm)0.019997 ppm 0.002307 11.54 -3536.940000 0.019997
Mg (279.078 nm)4.731540 ppm 0.012399 0.26 15833.900000 4.731540
Mn (257.610 nm)1.212920 o ppm 0.004479 0.37 323638.000000 1.212920 o
Mo (202.032 nm)0.000294 ppm 0.000334 > 100.00 4.936800 0.000294
Na (589.592 nm)332.703000 o ppm 2.599110 0.78 4047020.000000 332.703000 o
Na H (589.593 nm)324.412928 ppm 0.749071 0.23 2933061.909440 324.412928
Ni (231.604 nm)0.109468 ppm 0.000726 0.66 362.541000 0.109468
P (213.618 nm)0.083347 ppm 0.003987 4.78 -202.354000 0.083347
Pb (220.353 nm)3.126560 ppm 0.015485 0.50 7184.650000 3.126560
S (181.972 nm)6.765093 ppm 0.019198 0.28 1404.684451 6.765093
Sb (206.834 nm)0.020822 ppm 0.000605 2.90 27.420100 0.020822
Se (196.026 nm)0.000882 u ppm 0.002369 > 100.00 6.351680 0.000882 u
Si (288.158 nm)1.481600 ppm 0.005540 0.37 11475.900000 1.481600
Sn (189.925 nm)-0.001752 u ppm 0.000564 32.21 1.103430 -0.001752 u
Sr (421.552 nm)0.341766 ppm 0.000108 0.03 75471.360430 0.341766
Th (288.505 nm)0.030413 ppm 0.000423 1.39 341.845000 0.030413
Ti (336.122 nm)-0.000400 u ppm 0.000111 27.77 22.304300 -0.000400 u
Tl (190.794 nm)0.001352 u ppm 0.002416 > 100.00 -0.994238 0.001352 u
U (409.013 nm)0.004419 ppm 0.001988 45.00 43.393900 0.004419
V (292.401 nm)0.001099 ppm 0.000048 4.36 7.902910 0.001099
Zn (206.200 nm)7.373370 o ppm 0.015157 0.21 15903.800000 7.373370 o
Zr (343.823 nm)0.000006 u ppm 0.000111 > 100.00 -7.045710 0.000006 u
Test Report
52A112023.esws
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Page 1134 of 1261
Solution Name: 160-51876-C-1-J
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51876-C-1-J 11/21/2023 6:18:50 AM 3:63 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.005050 ppm 0.000033 0.66 13371.173015 0.005050
Ag (328.068 nm)0.000856 ppm 0.000173 20.25 17.698100 0.000856
Al (394.401 nm)0.076229 ppm 0.001000 1.31 1380.750000 0.076229
Al H (396.152 nm)0.035586 u ppm 0.001912 5.37 210.496000 0.035586 u
As (188.980 nm)0.002381 ppm 0.000847 35.59 -1.430070 0.002381
B (249.678 nm)0.041554 ppm 0.000232 0.56 363.974000 0.041554
Ba (493.408 nm)0.237103 ppm 0.000846 0.36 35910.900000 0.237103
Be (234.861 nm)0.000035 ppm 0.000015 41.06 51.597300 0.000035
Bi (223.061 nm)0.000195 u ppm 0.001807 > 100.00 4.375160 0.000195 u
Ca (315.887 nm)98.934067 o ppm 0.389735 0.39 66699.011005 98.934067 o
Cd (214.439 nm)0.025257 ppm 0.000182 0.72 377.679000 0.025257
Co (228.615 nm)0.014859 ppm 0.000305 2.05 326.166000 0.014859
Cr (205.560 nm)0.002098 ppm 0.000090 4.28 10.049800 0.002098
Cu (324.754 nm)3.319200 o ppm 0.013699 0.41 155571.000000 3.319200 o
Fe (238.204 nm)0.453581 ppm 0.000420 0.09 1802.407603 0.453581
Fe H (259.940 nm)0.530749 u ppm 0.005082 0.96 720.865000 0.530749 u
K (766.491 nm)1.832480 ppm 0.041435 2.26 2844.920000 1.832480
Li (670.783 nm)0.019306 ppm 0.001258 6.52 -3562.640000 0.019306
Mg (279.078 nm)4.421210 ppm 0.009487 0.21 14795.500000 4.421210
Mn (257.610 nm)1.465290 o ppm 0.001229 0.08 390975.000000 1.465290 o
Mo (202.032 nm)0.000670 ppm 0.000402 59.97 6.802980 0.000670
Na (589.592 nm)325.308000 o ppm 1.104390 0.34 3957990.000000 325.308000 o
Na H (589.593 nm)317.661747 ppm 3.602082 1.13 2874593.440305 317.661747
Ni (231.604 nm)0.099362 ppm 0.000824 0.83 328.130000 0.099362
P (213.618 nm)0.040568 ppm 0.004287 10.57 -123.476000 0.040568
Pb (220.353 nm)0.524256 ppm 0.001319 0.25 1203.340000 0.524256
S (181.972 nm)2.589496 ppm 0.027562 1.06 554.901532 2.589496
Sb (206.834 nm)0.017316 ppm 0.001165 6.73 23.157100 0.017316
Se (196.026 nm)0.002941 u ppm 0.004517 > 100.00 7.744270 0.002941 u
Si (288.158 nm)1.414090 ppm 0.001257 0.09 10985.300000 1.414090
Sn (189.925 nm)-0.001356 u ppm 0.001085 80.06 1.370000 -0.001356 u
Sr (421.552 nm)0.434539 ppm 0.001579 0.36 95955.594628 0.434539
Th (288.505 nm)0.038196 ppm 0.003550 9.29 361.483000 0.038196
Ti (336.122 nm)-0.000401 u ppm 0.000057 14.25 54.796800 -0.000401 u
Tl (190.794 nm)-0.000032 u ppm 0.001294 > 100.00 -2.501850 -0.000032 u
U (409.013 nm)0.008277 ppm 0.002352 28.42 60.837700 0.008277
V (292.401 nm)0.000987 ppm 0.000249 25.24 3.920560 0.000987
Zn (206.200 nm)7.579640 o ppm 0.003636 0.05 16348.600000 7.579640 o
Zr (343.823 nm)-0.000085 u ppm 0.000148 > 100.00 -13.972700 -0.000085 u
Test Report
52A112023.esws
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Page 1135 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 6:23:14 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000049 ppm 0.000005 10.60 1055.023426 0.000049
Ag (328.068 nm)0.000233 ppm 0.000192 82.22 125.224000 0.000233
Al (394.401 nm)51.776500 o ppm 0.112092 0.22 636523.000000 51.776500 o
Al H (396.152 nm)48.985500 ppm 0.069479 0.14 220202.000000 48.985500
As (188.980 nm)0.001703 ppm 0.000263 15.42 -2.438590 0.001703
B (249.678 nm)-0.003328 u ppm 0.000606 18.21 -11.672800 -0.003328 u
Ba (493.408 nm)0.000232 ppm 0.000108 46.68 176.068000 0.000232
Be (234.861 nm)-0.000069 u ppm 0.000056 80.95 677.263000 -0.000069 u
Bi (223.061 nm)-0.001346 u ppm 0.001244 92.39 2.083780 -0.001346 u
Ca (315.887 nm)-0.011050 u ppm 0.002846 25.75 -31.465107 -0.011050 u
Cd (214.439 nm)0.000149 u ppm 0.000230 > 100.00 12.597900 0.000149 u
Co (228.615 nm)0.000320 ppm 0.000125 39.20 48.968700 0.000320
Cr (205.560 nm)0.000363 ppm 0.000351 96.61 3.016360 0.000363
Cu (324.754 nm)-0.000438 u ppm 0.000193 44.10 1686.730000 -0.000438 u
Fe (238.204 nm)50.423815 o ppm 0.126413 0.25 198505.363368 50.423815 o
Fe H (259.940 nm)48.755300 ppm 0.097305 0.20 78833.500000 48.755300
K (766.491 nm)0.052941 ppm 0.037762 71.33 -352.296000 0.052941
Li (670.783 nm)0.015221 ppm 0.001013 6.66 -3714.540000 0.015221
Mg (279.078 nm)0.006461 ppm 0.001644 25.44 -159.047000 0.006461
Mn (257.610 nm)-0.000884 u ppm 0.000027 3.06 -231.258000 -0.000884 u
Mo (202.032 nm)0.000106 u ppm 0.000697 > 100.00 4.004230 0.000106 u
Na (589.592 nm)242.250000 o ppm 0.132244 0.05 2945630.000000 242.250000 o
Na H (589.593 nm)232.735546 ppm 2.718605 1.17 2129086.540220 232.735546
Ni (231.604 nm)0.000238 u ppm 0.000962 > 100.00 -9.399890 0.000238 u
P (213.618 nm)4.995680 ppm 0.020165 0.40 5899.970000 4.995680
Pb (220.353 nm)0.000449 ppm 0.000310 69.05 -2.146110 0.000449
S (181.972 nm)4.706774 ppm 0.023323 0.50 984.504904 4.706774
Sb (206.834 nm)-0.002074 u ppm 0.000857 41.34 2.955030 -0.002074 u
Se (196.026 nm)0.008011 ppm 0.004050 50.56 4.651430 0.008011
Si (288.158 nm)0.022621 ppm 0.002303 10.18 876.615000 0.022621
Sn (189.925 nm)0.001513 ppm 0.001385 91.59 3.297300 0.001513
Sr (421.552 nm)0.000536 ppm 0.000008 1.54 127.972009 0.000536
Th (288.505 nm)4.502390 ppm 0.005457 0.12 8674.920000 4.502390
Ti (336.122 nm)0.000699 ppm 0.000071 10.12 -41.806700 0.000699
Tl (190.794 nm)-0.003858 u ppm 0.002029 52.60 -7.582820 -0.003858 u
U (409.013 nm)2.384710 Q ppm 0.007845 0.33 10653.600000 Q 2.384710 Q
V (292.401 nm)0.000889 ppm 0.000357 40.13 278.547000 0.000889
Zn (206.200 nm)0.000358 u ppm 0.000731 > 100.00 4.934220 0.000358 u
Zr (343.823 nm)-0.000915 u ppm 0.000064 6.97 -14.098700 -0.000915 u
Test Report
52A112023.esws
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Page 1136 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 6:27:40 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.450984 ppm 0.000845 0.19 1156428.065730 0.450984
Ag (328.068 nm)0.507364 ppm 0.002091 0.41 27102.100000 0.507364
Al (394.401 nm)0.493296 ppm 0.002127 0.43 6527.150000 0.493296
Al H (396.152 nm)0.503979 u ppm 0.001984 0.39 2315.550000 0.503979 u
As (188.980 nm)0.501835 ppm 0.000459 0.09 413.536000 0.501835
B (249.678 nm)0.492904 ppm 0.001335 0.27 4141.620000 0.492904
Ba (493.408 nm)0.505700 ppm 0.000151 0.03 76596.700000 0.505700
Be (234.861 nm)0.515429 ppm 0.001363 0.26 86187.000000 0.515429
Bi (223.061 nm)1.001130 ppm 0.008713 0.87 1492.560000 1.001130
Ca (315.887 nm)5.038760 ppm 0.007968 0.16 3374.223403 5.038760
Cd (214.439 nm)0.511040 ppm 0.000928 0.18 7639.040000 0.511040
Co (228.615 nm)0.508605 ppm 0.001764 0.35 9761.590000 0.508605
Cr (205.560 nm)0.514220 ppm 0.000489 0.10 2115.110000 0.514220
Cu (324.754 nm)0.501527 ppm 0.002233 0.45 24154.200000 0.501527
Fe (238.204 nm)2.523108 ppm 0.005132 0.20 9954.949350 2.523108
Fe H (259.940 nm)2.541480 u ppm 0.000553 0.02 3977.780000 2.541480 u
K (766.491 nm)50.485900 ppm 0.248404 0.49 90258.100000 50.485900
Li (670.783 nm)0.506542 ppm 0.002627 0.52 14557.400000 0.506542
Mg (279.078 nm)20.147200 ppm 0.037978 0.19 67394.300000 20.147200
Mn (257.610 nm)0.495394 ppm 0.000865 0.17 132186.000000 0.495394
Mo (202.032 nm)0.503881 ppm 0.001483 0.29 2503.780000 0.503881
Na (589.592 nm)24.538400 ppm 0.099603 0.41 305229.000000 24.538400
Na H (589.593 nm)14.598292 u ppm 0.111750 0.77 223848.333315 14.598292 u
Ni (231.604 nm)0.517501 ppm 0.002623 0.51 1752.310000 0.517501
P (213.618 nm)0.009159 ppm 0.000909 9.92 -26.620100 0.009159
Pb (220.353 nm)0.539525 ppm 0.001898 0.35 1236.220000 0.539525
S (181.972 nm)-0.024550 u ppm 0.005380 21.92 21.557402 -0.024550 u
Sb (206.834 nm)0.492098 ppm 0.003644 0.74 601.249000 0.492098
Se (196.026 nm)0.501218 ppm 0.000762 0.15 312.660000 0.501218
Si (288.158 nm)4.916410 ppm 0.020771 0.42 36678.900000 4.916410
Sn (189.925 nm)0.506939 ppm 0.002512 0.50 342.937000 0.506939
Sr (421.552 nm)0.502726 ppm 0.000326 0.06 111011.323987 0.502726
Th (288.505 nm)0.035135 ppm 0.002379 6.77 314.245000 0.035135
Ti (336.122 nm)0.501963 ppm 0.001009 0.20 54666.600000 0.501963
Tl (190.794 nm)0.503531 ppm 0.002814 0.56 543.138000 0.503531
U (409.013 nm)-0.008974 u ppm 0.004517 50.33 -29.814000 -0.008974 u
V (292.401 nm)0.500766 ppm 0.001104 0.22 20809.300000 0.500766
Zn (206.200 nm)0.510978 ppm 0.003274 0.64 1106.020000 0.510978
Zr (343.823 nm)0.499027 ppm 0.001218 0.24 40676.100000 0.499027
Test Report
52A112023.esws
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Page 1137 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 6:32:02 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000509 ppm 0.000005 0.99 712.517482 0.000509
Ag (328.068 nm)0.000322 ppm 0.000106 32.80 -12.636000 0.000322
Al (394.401 nm)-0.002498 u ppm 0.000531 21.25 424.326000 -0.002498 u
Al H (396.152 nm)0.000209 u ppm 0.003924 > 100.00 51.504500 0.000209 u
As (188.980 nm)0.000774 ppm 0.000754 97.36 -2.761360 0.000774
B (249.678 nm)0.000109 u ppm 0.000122 > 100.00 17.090400 0.000109 u
Ba (493.408 nm)0.000061 u ppm 0.000265 > 100.00 8.585080 0.000061 u
Be (234.861 nm)-0.000002 u ppm 0.000023 > 100.00 39.600000 -0.000002 u
Bi (223.061 nm)-0.000567 u ppm 0.001136 > 100.00 3.241610 -0.000567 u
Ca (315.887 nm)0.009266 ppm 0.005647 60.94 -17.763359 0.009266
Cd (214.439 nm)0.000055 ppm 0.000077 > 100.00 0.899970 0.000055
Co (228.615 nm)-0.000185 u ppm 0.000071 38.15 39.316900 -0.000185 u
Cr (205.560 nm)-0.000009 u ppm 0.000363 > 100.00 1.487700 -0.000009 u
Cu (324.754 nm)-0.000039 u ppm 0.000269 > 100.00 760.360000 -0.000039 u
Fe (238.204 nm)0.001014 u ppm 0.001593 > 100.00 20.595672 0.001014 u
Fe H (259.940 nm)0.094753 u ppm 0.000315 0.33 14.652900 0.094753 u
K (766.491 nm)0.023379 u ppm 0.041164 > 100.00 -405.409000 0.023379 u
Li (670.783 nm)0.014209 S ppm 0.001509 10.62 -3752.170000 S 0.014209 S
Mg (279.078 nm)0.000529 u ppm 0.000816 > 100.00 11.154100 0.000529 u
Mn (257.610 nm)-0.000033 u ppm 0.000026 79.51 -4.238740 -0.000033 u
Mo (202.032 nm)0.000782 ppm 0.000734 93.81 7.360840 0.000782
Na (589.592 nm)0.173994 ppm 0.033619 19.32 3152.150000 0.173994
Na H (589.593 nm)-9.823464 u ppm 0.015296 0.16 5679.418643 -9.823464 u
Ni (231.604 nm)-0.000509 u ppm 0.000093 18.33 -11.942700 -0.000509 u
P (213.618 nm)-0.002039 u ppm 0.002879 > 100.00 0.694590 -0.002039 u
Pb (220.353 nm)0.000157 u ppm 0.000764 > 100.00 -1.269660 0.000157 u
S (181.972 nm)-0.034854 u ppm 0.004441 12.74 16.975486 -0.034854 u
Sb (206.834 nm)0.000148 u ppm 0.001547 > 100.00 2.183850 0.000148 u
Se (196.026 nm)0.002047 u ppm 0.002176 > 100.00 6.271320 0.002047 u
Si (288.158 nm)-0.002783 u ppm 0.000170 6.11 691.558000 -0.002783 u
Sn (189.925 nm)0.001343 ppm 0.000811 60.38 3.183560 0.001343
Sr (421.552 nm)0.000015 u ppm 0.000062 > 100.00 13.006370 0.000015 u
Th (288.505 nm)0.000444 ppm 0.000171 38.53 261.351000 0.000444
Ti (336.122 nm)0.000016 u ppm 0.000080 > 100.00 -116.393000 0.000016 u
Tl (190.794 nm)0.001298 ppm 0.001607 > 100.00 -1.081320 0.001298
U (409.013 nm)-0.003138 u ppm 0.000795 25.33 9.382190 -0.003138 u
V (292.401 nm)-0.000094 u ppm 0.000171 > 100.00 -44.580300 -0.000094 u
Zn (206.200 nm)-0.001072 u ppm 0.000461 43.00 1.851570 -0.001072 u
Zr (343.823 nm)-0.000017 u ppm 0.000064 > 100.00 -9.012060 -0.000017 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 267 of 287
Page 1138 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 6:36:05 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014150 ppm 0.000047 0.33 35783.474400 0.014150
Ag (328.068 nm)0.009852 ppm 0.000068 0.69 494.935000 0.009852
Al (394.401 nm)0.086754 ppm 0.000873 1.01 1529.870000 0.086754
Al H (396.152 nm)0.093313 u ppm 0.002601 2.79 469.931000 0.093313 u
As (188.980 nm)0.016766 ppm 0.001280 7.63 10.524900 0.016766
B (249.678 nm)0.094312 ppm 0.000738 0.78 805.536000 0.094312
Ba (493.408 nm)0.009861 ppm 0.000068 0.69 1493.160000 0.009861
Be (234.861 nm)0.000944 ppm 0.000006 0.63 198.820000 0.000944
Bi (223.061 nm)-0.002209 Qu ppm 0.001939 87.78 0.800227 Q -0.002209 Qu
Ca (315.887 nm)0.210477 ppm 0.002038 0.97 117.936921 0.210477
Cd (214.439 nm)0.005072 ppm 0.000131 2.57 75.909000 0.005072
Co (228.615 nm)0.010123 ppm 0.000139 1.38 236.237000 0.010123
Cr (205.560 nm)0.010040 ppm 0.000209 2.08 42.729000 0.010040
Cu (324.754 nm)0.014283 ppm 0.000368 2.57 1424.350000 0.014283
Fe (238.204 nm)0.099846 ppm 0.000277 0.28 409.700336 0.099846
Fe H (259.940 nm)0.190353 u ppm 0.002135 1.12 169.503000 0.190353 u
K (766.491 nm)3.019500 ppm 0.036271 1.20 4977.570000 3.019500
Li (670.783 nm)0.034455 Q ppm 0.001987 5.77 -2999.250000 Q 0.034455 Q
Mg (279.078 nm)0.198109 ppm 0.002351 1.19 670.962000 0.198109
Mn (257.610 nm)0.010022 ppm 0.000045 0.45 2678.680000 0.010022
Mo (202.032 nm)0.019755 ppm 0.000894 4.53 101.504000 0.019755
Na (589.592 nm)1.115660 ppm 0.008363 0.75 14714.100000 1.115660
Na H (589.593 nm)-8.913489 u ppm 0.009901 0.11 13731.104055 -8.913489 u
Ni (231.604 nm)0.041341 ppm 0.000597 1.44 130.572000 0.041341
P (213.618 nm)2.797750 ppm 0.004874 0.17 3304.850000 2.797750
Pb (220.353 nm)0.008663 ppm 0.001169 13.50 18.320200 0.008663
S (181.972 nm)0.054410 Q ppm 0.007884 14.49 35.213882 Q 0.054410 Q
Sb (206.834 nm)0.018342 ppm 0.001459 7.95 24.274600 0.018342
Se (196.026 nm)0.016363 ppm 0.004693 28.68 15.052900 0.016363
Si (288.158 nm)0.453904 ppm 0.005297 1.17 4039.410000 0.453904
Sn (189.925 nm)0.096751 ppm 0.001619 1.67 67.296000 0.096751
Sr (421.552 nm)0.009718 ppm 0.000107 1.10 2155.462779 0.009718
Th (288.505 nm)0.000305 Qu ppm 0.001539 > 100.00 261.223000 Q 0.000305 Qu
Ti (336.122 nm)0.009580 ppm 0.000084 0.87 927.606000 0.009580
Tl (190.794 nm)0.016138 ppm 0.002603 16.13 14.990100 0.016138
U (409.013 nm)0.054169 ppm 0.003712 6.85 261.604000 0.054169
V (292.401 nm)0.009631 ppm 0.000054 0.56 356.446000 0.009631
Zn (206.200 nm)0.020216 ppm 0.001020 5.05 47.755300 0.020216
Zr (343.823 nm)0.009608 ppm 0.000105 1.09 775.726000 0.009608
Test Report
52A112023.esws
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Page 1139 of 1261
Solution Name: 160-51885-A-1-I
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51885-A-1-I 11/21/2023 6:40:22 AM 3:64 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.003048 ppm 0.000014 0.47 7921.661489 0.003048
Ag (328.068 nm)0.000983 ppm 0.000101 10.29 25.048900 0.000983
Al (394.401 nm)0.059554 ppm 0.000304 0.51 1173.570000 0.059554
Al H (396.152 nm)0.031571 u ppm 0.003195 10.12 192.451000 0.031571 u
As (188.980 nm)0.001396 ppm 0.000887 63.52 -2.251060 0.001396
B (249.678 nm)0.031207 ppm 0.000381 1.22 277.376000 0.031207
Ba (493.408 nm)0.172388 ppm 0.001710 0.99 26110.300000 0.172388
Be (234.861 nm)0.000082 ppm 0.000014 16.46 63.013900 0.000082
Bi (223.061 nm)-0.000268 u ppm 0.000601 > 100.00 3.686340 -0.000268 u
Ca (315.887 nm)78.425983 o ppm 0.890699 1.14 52867.967288 78.425983 o
Cd (214.439 nm)0.006560 ppm 0.000129 1.97 98.284200 0.006560
Co (228.615 nm)0.024519 ppm 0.000414 1.69 510.401000 0.024519
Cr (205.560 nm)0.001784 ppm 0.000858 48.07 8.785910 0.001784
Cu (324.754 nm)0.372035 ppm 0.000271 0.07 18083.900000 0.372035
Fe (238.204 nm)0.728626 ppm 0.007696 1.06 2884.863050 0.728626
Fe H (259.940 nm)0.799135 u ppm 0.009969 1.25 1155.590000 0.799135 u
K (766.491 nm)1.266960 ppm 0.045279 3.57 1828.870000 1.266960
Li (670.783 nm)0.019767 ppm 0.002851 14.42 -3545.490000 0.019767
Mg (279.078 nm)7.217550 ppm 0.018813 0.26 24148.300000 7.217550
Mn (257.610 nm)1.563430 o ppm 0.002825 0.18 417162.000000 1.563430 o
Mo (202.032 nm)0.000969 ppm 0.000217 22.37 8.287370 0.000969
Na (589.592 nm)326.373000 o ppm 5.542560 1.70 3970180.000000 326.373000 o
Na H (589.593 nm)324.397240 ppm 6.503730 2.00 2932998.111607 324.397240
Ni (231.604 nm)0.070457 ppm 0.000968 1.37 229.703000 0.070457
P (213.618 nm)0.007797 ppm 0.003077 39.46 -7.262560 0.007797
Pb (220.353 nm)0.129864 ppm 0.001473 1.13 296.807000 0.129864
S (181.972 nm)3.265895 ppm 0.017629 0.54 692.355197 3.265895
Sb (206.834 nm)0.001923 ppm 0.001230 63.98 4.406530 0.001923
Se (196.026 nm)-0.000362 u ppm 0.002323 > 100.00 5.753350 -0.000362 u
Si (288.158 nm)1.571290 ppm 0.004044 0.26 12127.900000 1.571290
Sn (189.925 nm)-0.000546 u ppm 0.001675 > 100.00 1.914140 -0.000546 u
Sr (421.552 nm)0.319582 ppm 0.002961 0.93 70573.249212 0.319582
Th (288.505 nm)0.038702 ppm 0.003693 9.54 364.389000 0.038702
Ti (336.122 nm)-0.000011 u ppm 0.000042 > 100.00 52.438300 -0.000011 u
Tl (190.794 nm)0.000836 u ppm 0.002113 > 100.00 -1.546910 0.000836 u
U (409.013 nm)0.001836 u ppm 0.004259 > 100.00 32.782800 0.001836 u
V (292.401 nm)0.000894 ppm 0.000288 32.22 1.054860 0.000894
Zn (206.200 nm)1.348810 o ppm 0.006116 0.45 2912.700000 1.348810 o
Zr (343.823 nm)0.000009 u ppm 0.000124 > 100.00 -5.919900 0.000009 u
Test Report
52A112023.esws
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Page 1140 of 1261
Solution Name: 160-51885-B-2-I
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51885-B-2-I 11/21/2023 6:44:44 AM 3:65 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.003062 ppm 0.000014 0.46 7969.921667 0.003062
Ag (328.068 nm)0.000951 ppm 0.000315 33.15 22.465900 0.000951
Al (394.401 nm)0.048537 ppm 0.000777 1.60 1042.210000 0.048537
Al H (396.152 nm)0.017316 u ppm 0.003514 20.30 128.386000 0.017316 u
As (188.980 nm)0.002125 u ppm 0.002434 > 100.00 -1.639260 0.002125 u
B (249.678 nm)0.032211 ppm 0.000509 1.58 285.775000 0.032211
Ba (493.408 nm)0.180284 ppm 0.000251 0.14 27304.200000 0.180284
Be (234.861 nm)0.000082 ppm 0.000006 7.81 53.740000 0.000082
Bi (223.061 nm)0.000126 u ppm 0.001941 > 100.00 4.272990 0.000126 u
Ca (315.887 nm)83.621153 o ppm 0.163727 0.20 56371.689564 83.621153 o
Cd (214.439 nm)0.006232 ppm 0.000177 2.84 93.229100 0.006232
Co (228.615 nm)0.011908 ppm 0.000098 0.82 269.906000 0.011908
Cr (205.560 nm)0.002184 ppm 0.000127 5.83 10.447000 0.002184
Cu (324.754 nm)0.399479 ppm 0.001439 0.36 19357.100000 0.399479
Fe (238.204 nm)0.018665 ppm 0.002118 11.35 90.161312 0.018665
Fe H (259.940 nm)0.109578 u ppm 0.002653 2.42 38.665200 0.109578 u
K (766.491 nm)1.467620 ppm 0.081246 5.54 2189.390000 1.467620
Li (670.783 nm)0.018762 ppm 0.001915 10.21 -3582.840000 0.018762
Mg (279.078 nm)7.855410 ppm 0.029955 0.38 26282.500000 7.855410
Mn (257.610 nm)1.337250 o ppm 0.005449 0.41 356812.000000 1.337250 o
Mo (202.032 nm)0.000874 ppm 0.000253 28.99 7.813410 0.000874
Na (589.592 nm)344.028000 o ppm 1.931400 0.56 4184870.000000 344.028000 o
Na H (589.593 nm)338.352256 ppm 5.706115 1.69 3055230.948732 338.352256
Ni (231.604 nm)0.056219 ppm 0.000974 1.73 181.222000 0.056219
P (213.618 nm)0.010928 ppm 0.001527 13.98 -4.998110 0.010928
Pb (220.353 nm)0.138522 ppm 0.002314 1.67 316.736000 0.138522
S (181.972 nm)3.157815 ppm 0.021732 0.69 670.188084 3.157815
Sb (206.834 nm)0.006776 ppm 0.001559 23.00 10.278000 0.006776
Se (196.026 nm)0.001689 ppm 0.002660 > 100.00 6.936320 0.001689
Si (288.158 nm)1.510440 ppm 0.004193 0.28 11685.900000 1.510440
Sn (189.925 nm)-0.000283 u ppm 0.001906 > 100.00 2.090480 -0.000283 u
Sr (421.552 nm)0.393887 ppm 0.000811 0.21 86979.802407 0.393887
Th (288.505 nm)0.039277 ppm 0.001586 4.04 360.954000 0.039277
Ti (336.122 nm)-0.000034 u ppm 0.000101 > 100.00 61.298300 -0.000034 u
Tl (190.794 nm)0.001741 ppm 0.001329 76.33 -0.575078 0.001741
U (409.013 nm)0.005744 ppm 0.002608 45.40 49.093200 0.005744
V (292.401 nm)0.001363 ppm 0.000246 18.09 19.140200 0.001363
Zn (206.200 nm)1.475090 o ppm 0.003875 0.26 3184.980000 1.475090 o
Zr (343.823 nm)0.000013 u ppm 0.000050 > 100.00 -6.533740 0.000013 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 270 of 287
Page 1141 of 1261
Solution Name: 160-51886-B-1-I
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
160-51886-B-1-I 11/21/2023 6:49:06 AM 3:66 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000483 ppm 0.000007 1.45 642.733066 0.000483
Ag (328.068 nm)0.000066 u ppm 0.000129 > 100.00 -26.438800 0.000066 u
Al (394.401 nm)-0.001112 u ppm 0.000538 48.43 442.546000 -0.001112 u
Al H (396.152 nm)0.000552 u ppm 0.005876 > 100.00 53.045700 0.000552 u
As (188.980 nm)0.002248 ppm 0.000845 37.58 -1.536620 0.002248
B (249.678 nm)-0.000417 u ppm 0.000535 > 100.00 12.689000 -0.000417 u
Ba (493.408 nm)0.000129 ppm 0.000056 43.53 19.014900 0.000129
Be (234.861 nm)0.000023 ppm 0.000017 73.97 44.012400 0.000023
Bi (223.061 nm)0.000647 u ppm 0.000879 > 100.00 5.046590 0.000647 u
Ca (315.887 nm)0.021178 ppm 0.002629 12.41 -9.729590 0.021178
Cd (214.439 nm)0.000091 ppm 0.000062 67.55 1.444490 0.000091
Co (228.615 nm)-0.000011 u ppm 0.000212 > 100.00 42.638400 -0.000011 u
Cr (205.560 nm)0.000011 u ppm 0.000393 > 100.00 1.570020 0.000011 u
Cu (324.754 nm)0.000021 u ppm 0.000039 > 100.00 762.434000 0.000021 u
Fe (238.204 nm)0.025906 ppm 0.000609 2.35 118.581525 0.025906
Fe H (259.940 nm)0.117442 u ppm 0.001389 1.18 51.403300 0.117442 u
K (766.491 nm)0.057129 ppm 0.012710 22.25 -344.772000 0.057129
Li (670.783 nm)0.016033 ppm 0.000898 5.60 -3684.340000 0.016033
Mg (279.078 nm)0.000659 ppm 0.000498 75.55 11.512100 0.000659
Mn (257.610 nm)0.000306 ppm 0.000058 18.90 86.009600 0.000306
Mo (202.032 nm)0.000347 ppm 0.000418 > 100.00 5.198500 0.000347
Na (589.592 nm)0.181187 ppm 0.026628 14.70 3238.610000 0.181187
Na H (589.593 nm)-9.762193 u ppm 0.022216 0.23 6215.086846 -9.762193 u
Ni (231.604 nm)0.000381 u ppm 0.000796 > 100.00 -8.914070 0.000381 u
P (213.618 nm)-0.000730 u ppm 0.001489 > 100.00 2.274360 -0.000730 u
Pb (220.353 nm)0.000776 u ppm 0.001697 > 100.00 0.165940 0.000776 u
S (181.972 nm)-0.019975 u ppm 0.004064 20.35 19.999972 -0.019975 u
Sb (206.834 nm)0.001587 u ppm 0.001784 > 100.00 3.944290 0.001587 u
Se (196.026 nm)0.000213 u ppm 0.000782 > 100.00 5.143680 0.000213 u
Si (288.158 nm)-0.003715 u ppm 0.000572 15.38 683.524000 -0.003715 u
Sn (189.925 nm)-0.004219 u ppm 0.000213 5.04 -0.554262 -0.004219 u
Sr (421.552 nm)0.000083 ppm 0.000058 70.05 28.032297 0.000083
Th (288.505 nm)-0.000020 u ppm 0.002476 > 100.00 260.536000 -0.000020 u
Ti (336.122 nm)-0.000042 u ppm 0.000048 > 100.00 -122.641000 -0.000042 u
Tl (190.794 nm)0.001490 ppm 0.000133 8.90 -0.871232 0.001490
U (409.013 nm)0.002034 ppm 0.001006 49.44 32.166000 0.002034
V (292.401 nm)0.000101 ppm 0.000091 90.03 -36.895900 0.000101
Zn (206.200 nm)-0.000203 u ppm 0.000070 34.50 3.724610 -0.000203 u
Zr (343.823 nm)-0.000095 u ppm 0.000063 66.09 -15.358000 -0.000095 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 271 of 287
Page 1142 of 1261
Solution Name: 280-184475-A-2-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184475-A-2-B 11/21/2023 6:53:10 AM 3:67 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014395 ppm 0.000093 0.65 38271.938881 0.014395
Ag (328.068 nm)0.001835 ppm 0.000022 1.18 75.029300 0.001835
Al (394.401 nm)0.034524 ppm 0.000175 0.51 842.381000 0.034524
Al H (396.152 nm)-0.012563 u ppm 0.005297 42.16 -5.896780 -0.012563 u
As (188.980 nm)0.001809 ppm 0.001995 > 100.00 -1.901460 0.001809
B (249.678 nm)0.003273 ppm 0.000227 6.92 43.577100 0.003273
Ba (493.408 nm)0.006696 ppm 0.000085 1.27 1013.510000 0.006696
Be (234.861 nm)-0.000052 u ppm 0.000031 59.47 31.387300 -0.000052 u
Bi (223.061 nm)0.001052 u ppm 0.003576 > 100.00 5.648740 0.001052 u
Ca (315.887 nm)134.190207 o ppm 0.406944 0.30 90476.424978 134.190207 o
Cd (214.439 nm)0.009335 ppm 0.000122 1.30 139.615000 0.009335
Co (228.615 nm)0.011191 ppm 0.000143 1.27 256.225000 0.011191
Cr (205.560 nm)0.000812 ppm 0.000490 60.35 4.853310 0.000812
Cu (324.754 nm)0.030067 ppm 0.000316 1.05 2112.400000 0.030067
Fe (238.204 nm)0.013083 ppm 0.000586 4.48 68.232917 0.013083
Fe H (259.940 nm)0.102812 u ppm 0.003233 3.14 27.706700 0.102812 u
K (766.491 nm)0.184600 ppm 0.017864 9.68 -115.750000 0.184600
Li (670.783 nm)0.029210 ppm 0.001969 6.74 -3194.290000 0.029210
Mg (279.078 nm)24.826600 ppm 0.106908 0.43 83043.400000 24.826600
Mn (257.610 nm)10.294800 o ppm 0.033871 0.33 2746870.000000 10.294800 o
Mo (202.032 nm)0.000538 ppm 0.000488 90.72 6.148340 0.000538
Na (589.592 nm)315.668000 o ppm 2.526680 0.80 3838110.000000 315.668000 o
Na H (589.593 nm)310.137885 ppm 7.505288 2.42 2806734.551599 310.137885
Ni (231.604 nm)0.004567 ppm 0.000302 6.60 5.350370 0.004567
P (213.618 nm)0.001124 u ppm 0.003316 > 100.00 2.815430 0.001124 u
Pb (220.353 nm)-0.000151 u ppm 0.001114 > 100.00 -1.993780 -0.000151 u
S (181.972 nm)31.898932 o ppm 0.226828 0.71 6533.585095 31.898932 o
Sb (206.834 nm)-0.002375 u ppm 0.000173 7.27 -0.880041 -0.002375 u
Se (196.026 nm)-0.003383 u ppm 0.005169 > 100.00 9.764740 -0.003383 u
Si (288.158 nm)0.370392 ppm 0.003278 0.88 3403.120000 0.370392
Sn (189.925 nm)0.001273 ppm 0.000938 73.69 3.136230 0.001273
Sr (421.552 nm)0.127444 ppm 0.000491 0.38 28149.201317 0.127444
Th (288.505 nm)0.172035 ppm 0.004870 2.83 789.888000 0.172035
Ti (336.122 nm)-0.000713 u ppm 0.000023 3.20 98.091400 -0.000713 u
Tl (190.794 nm)0.001549 u ppm 0.001929 > 100.00 -0.783526 0.001549 u
U (409.013 nm)0.003567 ppm 0.004315 > 100.00 41.059500 0.003567
V (292.401 nm)0.000174 ppm 0.000104 59.75 -21.844700 0.000174
Zn (206.200 nm)0.053330 ppm 0.001440 2.70 119.161000 0.053330
Zr (343.823 nm)0.000046 ppm 0.000040 87.83 -3.917030 0.000046
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 272 of 287
Page 1143 of 1261
Solution Name: 280-184591-G-1-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184591-G-1-B 11/21/2023 6:57:32 AM 3:68 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.006510 ppm 0.000035 0.53 17083.804645 0.006510
Ag (328.068 nm)0.001329 ppm 0.000087 6.58 46.090300 0.001329
Al (394.401 nm)0.735488 ppm 0.003335 0.45 9480.270000 0.735488
Al H (396.152 nm)0.663464 u ppm 0.004431 0.67 3032.310000 0.663464 u
As (188.980 nm)0.000874 u ppm 0.002694 > 100.00 -2.678050 0.000874 u
B (249.678 nm)0.018571 ppm 0.000283 1.52 171.611000 0.018571
Ba (493.408 nm)0.244192 ppm 0.000775 0.32 36983.300000 0.244192
Be (234.861 nm)-0.000146 u ppm 0.000040 27.66 15.635700 -0.000146 u
Bi (223.061 nm)0.001202 u ppm 0.002194 > 100.00 5.871660 0.001202 u
Ca (315.887 nm)52.392126 o ppm 0.288415 0.55 35310.237617 52.392126 o
Cd (214.439 nm)0.000519 ppm 0.000097 18.73 7.835830 0.000519
Co (228.615 nm)0.000214 ppm 0.000059 27.37 46.919500 0.000214
Cr (205.560 nm)-0.000013 u ppm 0.000290 > 100.00 1.465570 -0.000013 u
Cu (324.754 nm)0.000487 ppm 0.000151 31.05 772.639000 0.000487
Fe (238.204 nm)0.011447 ppm 0.000734 6.42 61.675037 0.011447
Fe H (259.940 nm)0.101796 u ppm 0.000913 0.90 26.060000 0.101796 u
K (766.491 nm)0.722895 ppm 0.022689 3.14 851.378000 0.722895
Li (670.783 nm)0.021634 ppm 0.001022 4.72 -3476.040000 0.021634
Mg (279.078 nm)2.460450 ppm 0.014298 0.58 8236.630000 2.460450
Mn (257.610 nm)7.775900 o ppm 0.033084 0.43 2074780.000000 7.775900 o
Mo (202.032 nm)0.000770 ppm 0.000202 26.19 7.300550 0.000770
Na (589.592 nm)310.195000 o ppm 2.598600 0.84 3774370.000000 310.195000 o
Na H (589.593 nm)302.859392 ppm 2.002452 0.66 2745072.315796 302.859392
Ni (231.604 nm)0.000292 u ppm 0.000490 > 100.00 -9.209780 0.000292 u
P (213.618 nm)-0.001666 u ppm 0.003784 > 100.00 1.099460 -0.001666 u
Pb (220.353 nm)0.001366 ppm 0.001517 > 100.00 1.426810 0.001366
S (181.972 nm)0.710773 ppm 0.013138 1.85 177.929515 0.710773
Sb (206.834 nm)-0.003855 u ppm 0.000398 10.33 -2.693050 -0.003855 u
Se (196.026 nm)-0.003923 u ppm 0.001592 40.58 7.762590 -0.003923 u
Si (288.158 nm)0.533845 ppm 0.003956 0.74 4590.590000 0.533845
Sn (189.925 nm)0.000845 ppm 0.000281 33.23 2.848640 0.000845
Sr (421.552 nm)0.366385 ppm 0.001244 0.34 80907.300723 0.366385
Th (288.505 nm)0.115841 ppm 0.001034 0.89 633.712000 0.115841
Ti (336.122 nm)-0.000305 u ppm 0.000063 20.71 -36.729900 -0.000305 u
Tl (190.794 nm)0.001172 ppm 0.000417 35.57 -1.216270 0.001172
U (409.013 nm)-0.002953 u ppm 0.000797 27.00 11.634400 -0.002953 u
V (292.401 nm)0.000205 ppm 0.000085 41.31 -24.006700 0.000205
Zn (206.200 nm)0.012144 ppm 0.000937 7.72 30.350000 0.012144
Zr (343.823 nm)-0.000192 u ppm 0.000054 27.96 -23.307100 -0.000192 u
Test Report
52A112023.esws
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Page 1144 of 1261
Solution Name: 280-184424-B-1-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184424-B-1-B 11/21/2023 7:01:59 AM 3:69 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002320 ppm 0.000003 0.14 5928.786083 0.002320
Ag (328.068 nm)0.001059 ppm 0.000081 7.69 28.023100 0.001059
Al (394.401 nm)0.029276 ppm 0.001686 5.76 804.789000 0.029276
Al H (396.152 nm)-0.019433 u ppm 0.003928 20.21 -36.772500 -0.019433 u
As (188.980 nm)0.004793 ppm 0.001437 29.98 0.578011 0.004793
B (249.678 nm)0.026470 ppm 0.000998 3.77 237.723000 0.026470
Ba (493.408 nm)0.199569 ppm 0.000117 0.06 30224.900000 0.199569
Be (234.861 nm)0.000051 ppm 0.000018 35.34 48.592000 0.000051
Bi (223.061 nm)0.000087 u ppm 0.001336 > 100.00 4.213790 0.000087 u
Ca (315.887 nm)174.393722 o ppm 0.541565 0.31 117590.442655 174.393722 o
Cd (214.439 nm)0.001330 ppm 0.000086 6.43 19.965000 0.001330
Co (228.615 nm)0.007223 ppm 0.000135 1.87 180.558000 0.007223
Cr (205.560 nm)0.000441 u ppm 0.000816 > 100.00 3.322260 0.000441 u
Cu (324.754 nm)0.002664 ppm 0.001244 46.70 788.589000 0.002664
Fe (238.204 nm)0.020327 ppm 0.000042 0.20 96.641911 0.020327
Fe H (259.940 nm)0.107571 u ppm 0.001599 1.49 35.414400 0.107571 u
K (766.491 nm)0.842221 ppm 0.029321 3.48 1065.770000 0.842221
Li (670.783 nm)0.015352 ppm 0.000954 6.22 -3709.680000 0.015352
Mg (279.078 nm)2.427300 ppm 0.011492 0.47 8126.960000 2.427300
Mn (257.610 nm)1.014070 ppm 0.003840 0.38 270580.000000 1.014070
Mo (202.032 nm)0.001654 ppm 0.000536 32.38 11.684600 0.001654
Na (589.592 nm)345.465000 o ppm 0.119787 0.03 4202560.000000 345.465000 o
Na H (589.593 nm)339.052272 ppm 0.534134 0.16 3061525.659615 339.052272
Ni (231.604 nm)0.005140 ppm 0.000967 18.81 7.293370 0.005140
P (213.618 nm)0.004664 ppm 0.000616 13.20 8.436250 0.004664
Pb (220.353 nm)-0.000849 u ppm 0.001322 > 100.00 -3.587670 -0.000849 u
S (181.972 nm)0.767898 ppm 0.008421 1.10 184.924675 0.767898
Sb (206.834 nm)-0.000650 u ppm 0.001418 > 100.00 1.215840 -0.000650 u
Se (196.026 nm)-0.004126 u ppm 0.001811 43.91 3.153640 -0.004126 u
Si (288.158 nm)1.767850 ppm 0.005911 0.33 13556.100000 1.767850
Sn (189.925 nm)-0.000178 u ppm 0.001503 > 100.00 2.161180 -0.000178 u
Sr (421.552 nm)0.172034 ppm 0.000143 0.08 37994.767110 0.172034
Th (288.505 nm)0.035189 ppm 0.003942 11.20 346.703000 0.035189
Ti (336.122 nm)-0.000607 u ppm 0.000148 24.45 197.783000 -0.000607 u
Tl (190.794 nm)0.000738 u ppm 0.001078 > 100.00 -1.674960 0.000738 u
U (409.013 nm)0.009856 ppm 0.003445 34.96 67.263100 0.009856
V (292.401 nm)0.001695 ppm 0.000107 6.33 33.486200 0.001695
Zn (206.200 nm)0.010001 ppm 0.001053 10.53 25.729100 0.010001
Zr (343.823 nm)-0.000048 u ppm 0.000028 58.65 -11.565600 -0.000048 u
Test Report
52A112023.esws
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Page 1145 of 1261
Solution Name: 280-184529-G-1-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184529-G-1-C 11/21/2023 7:06:22 AM 3:70 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000554 ppm 0.000016 2.84 1967.973796 0.000554
Ag (328.068 nm)0.000602 ppm 0.000044 7.32 2.819580 0.000602
Al (394.401 nm)0.769214 ppm 0.001141 0.15 9914.360000 0.769214
Al H (396.152 nm)0.698462 u ppm 0.005594 0.80 3189.600000 0.698462 u
As (188.980 nm)0.003149 ppm 0.002678 85.03 -0.842899 0.003149
B (249.678 nm)0.012654 ppm 0.000287 2.27 122.093000 0.012654
Ba (493.408 nm)0.102737 ppm 0.000285 0.28 15576.600000 0.102737
Be (234.861 nm)0.000311 ppm 0.000014 4.59 171.483000 0.000311
Bi (223.061 nm)-0.001520 u ppm 0.001109 72.99 1.825300 -0.001520 u
Ca (315.887 nm)41.335813 o ppm 0.055023 0.13 27853.648929 41.335813 o
Cd (214.439 nm)0.003767 ppm 0.000065 1.72 57.647000 0.003767
Co (228.615 nm)0.006923 ppm 0.000206 2.97 174.879000 0.006923
Cr (205.560 nm)0.003069 ppm 0.000529 17.24 14.112400 0.003069
Cu (324.754 nm)0.002171 ppm 0.000159 7.31 851.167000 0.002171
Fe (238.204 nm)6.190797 o ppm 0.014626 0.24 24386.160417 6.190797 o
Fe H (259.940 nm)6.073740 ppm 0.020609 0.34 9699.240000 6.073740
K (766.491 nm)0.711593 ppm 0.031920 4.49 831.073000 0.711593
Li (670.783 nm)0.014395 ppm 0.001755 12.19 -3745.250000 0.014395
Mg (279.078 nm)2.566920 ppm 0.011280 0.44 8589.920000 2.566920
Mn (257.610 nm)0.389289 ppm 0.001687 0.43 103875.000000 0.389289
Mo (202.032 nm)0.000759 ppm 0.000282 37.19 7.244230 0.000759
Na (589.592 nm)341.344000 o ppm 1.210050 0.35 4151330.000000 341.344000 o
Na H (589.593 nm)338.350237 ppm 1.255493 0.37 3054542.892626 338.350237
Ni (231.604 nm)0.032879 ppm 0.000465 1.42 101.747000 0.032879
P (213.618 nm)0.001631 ppm 0.001090 66.83 4.938650 0.001631
Pb (220.353 nm)17.267900 ppm 0.102545 0.59 39688.100000 17.267900
S (181.972 nm)18.843123 o ppm 0.118474 0.63 3862.894904 18.843123 o
Sb (206.834 nm)0.017026 ppm 0.001710 10.05 23.202100 0.017026
Se (196.026 nm)0.003478 ppm 0.001722 49.52 6.759120 0.003478
Si (288.158 nm)0.763760 ppm 0.002471 0.32 6261.220000 0.763760
Sn (189.925 nm)-0.000495 u ppm 0.002468 > 100.00 1.948110 -0.000495 u
Sr (421.552 nm)0.063000 ppm 0.000180 0.29 13919.996471 0.063000
Th (288.505 nm)0.016869 ppm 0.001479 8.77 299.834000 0.016869
Ti (336.122 nm)0.000387 ppm 0.000064 16.43 14.633000 0.000387
Tl (190.794 nm)0.002407 ppm 0.000964 40.06 0.026387 0.002407
U (409.013 nm)0.025858 ppm 0.002225 8.60 143.638000 0.025858
V (292.401 nm)0.000765 ppm 0.000095 12.39 -7.932880 0.000765
Zn (206.200 nm)0.582523 ppm 0.002867 0.49 1260.300000 0.582523
Zr (343.823 nm)-0.000020 u ppm 0.000035 > 100.00 -0.912291 -0.000020 u
Test Report
52A112023.esws
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Page 1146 of 1261
Solution Name: 280-184529-F-2-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184529-F-2-C 11/21/2023 7:10:49 AM 3:71 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000544 ppm 0.000009 1.72 1943.760117 0.000544
Ag (328.068 nm)0.000526 ppm 0.000104 19.81 -2.393430 0.000526
Al (394.401 nm)0.740328 ppm 0.002744 0.37 9564.470000 0.740328
Al H (396.152 nm)0.670201 u ppm 0.001151 0.17 3062.580000 0.670201 u
As (188.980 nm)0.004300 ppm 0.003713 86.35 0.069633 0.004300
B (249.678 nm)0.011508 ppm 0.000337 2.93 112.499000 0.011508
Ba (493.408 nm)0.096917 ppm 0.000672 0.69 14708.800000 0.096917
Be (234.861 nm)0.000293 ppm 0.000053 18.17 230.929000 0.000293
Bi (223.061 nm)0.002500 u ppm 0.002506 > 100.00 7.802400 0.002500 u
Ca (315.887 nm)44.583878 o ppm 0.238728 0.54 30044.205569 44.583878 o
Cd (214.439 nm)0.004456 ppm 0.000146 3.27 68.939700 0.004456
Co (228.615 nm)0.006888 ppm 0.000041 0.59 174.195000 0.006888
Cr (205.560 nm)0.003457 ppm 0.000662 19.15 15.707800 0.003457
Cu (324.754 nm)0.003405 ppm 0.002383 69.98 908.479000 0.003405
Fe (238.204 nm)11.037216 o ppm 0.055597 0.50 43463.656626 11.037216 o
Fe H (259.940 nm)10.825100 ppm 0.059438 0.55 17395.300000 10.825100
K (766.491 nm)0.655285 ppm 0.030020 4.58 729.907000 0.655285
Li (670.783 nm)0.018371 ppm 0.000653 3.56 -3597.390000 0.018371
Mg (279.078 nm)2.845690 ppm 0.011521 0.40 9519.540000 2.845690
Mn (257.610 nm)0.319000 ppm 0.001358 0.43 85120.500000 0.319000
Mo (202.032 nm)0.000698 ppm 0.000241 34.54 6.940510 0.000698
Na (589.592 nm)328.017000 o ppm 0.926738 0.28 3989280.000000 328.017000 o
Na H (589.593 nm)325.314967 ppm 5.462877 1.68 2940380.371279 325.314967
Ni (231.604 nm)0.034319 ppm 0.000914 2.66 106.647000 0.034319
P (213.618 nm)0.001620 u ppm 0.003711 > 100.00 4.878710 0.001620 u
Pb (220.353 nm)15.408800 ppm 0.091896 0.60 35415.000000 15.408800
S (181.972 nm)21.416328 o ppm 0.102069 0.48 4387.094673 21.416328 o
Sb (206.834 nm)0.019913 ppm 0.001406 7.06 27.057300 0.019913
Se (196.026 nm)-0.000897 u ppm 0.002404 > 100.00 3.520380 -0.000897 u
Si (288.158 nm)0.791033 ppm 0.004072 0.51 6458.250000 0.791033
Sn (189.925 nm)-0.002883 u ppm 0.001546 53.62 0.343517 -0.002883 u
Sr (421.552 nm)0.064878 ppm 0.000372 0.57 14334.695993 0.064878
Th (288.505 nm)0.016835 ppm 0.001752 10.40 298.247000 0.016835
Ti (336.122 nm)0.000330 ppm 0.000110 33.25 15.566400 0.000330
Tl (190.794 nm)-0.001882 u ppm 0.002254 > 100.00 -4.718300 -0.001882 u
U (409.013 nm)0.031772 ppm 0.002794 8.79 174.137000 0.031772
V (292.401 nm)0.000698 ppm 0.000103 14.77 -12.737800 0.000698
Zn (206.200 nm)0.596125 ppm 0.002041 0.34 1289.620000 0.596125
Zr (343.823 nm)-0.000043 u ppm 0.000045 > 100.00 3.766730 -0.000043 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 276 of 287
Page 1147 of 1261
Solution Name: 280-184531-D-1-C
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184531-D-1-C 11/21/2023 7:15:18 AM 3:72 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000564 ppm 0.000007 1.20 1988.617284 0.000564
Ag (328.068 nm)0.000526 ppm 0.000171 32.44 -1.762110 0.000526
Al (394.401 nm)0.867449 ppm 0.003654 0.42 11126.000000 0.867449
Al H (396.152 nm)0.789073 u ppm 0.002665 0.34 3596.820000 0.789073 u
As (188.980 nm)0.004823 ppm 0.000729 15.12 0.552001 0.004823
B (249.678 nm)0.014678 ppm 0.000691 4.71 139.029000 0.014678
Ba (493.408 nm)0.118735 ppm 0.000182 0.15 17998.400000 0.118735
Be (234.861 nm)0.000301 ppm 0.000020 6.52 163.948000 0.000301
Bi (223.061 nm)-0.001128 u ppm 0.001044 92.52 2.407900 -0.001128 u
Ca (315.887 nm)35.470477 o ppm 0.078849 0.22 23897.954429 35.470477 o
Cd (214.439 nm)0.004690 ppm 0.000109 2.32 71.351900 0.004690
Co (228.615 nm)0.006731 ppm 0.000112 1.66 171.209000 0.006731
Cr (205.560 nm)0.003616 ppm 0.000222 6.13 16.366000 0.003616
Cu (324.754 nm)0.004469 ppm 0.000098 2.20 959.481000 0.004469
Fe (238.204 nm)5.735437 o ppm 0.018050 0.31 22593.688311 5.735437 o
Fe H (259.940 nm)5.641010 ppm 0.017434 0.31 8998.310000 5.641010
K (766.491 nm)0.743237 ppm 0.010213 1.37 887.925000 0.743237
Li (670.783 nm)0.019603 ppm 0.001858 9.48 -3551.580000 0.019603
Mg (279.078 nm)2.939030 ppm 0.010403 0.35 9834.750000 2.939030
Mn (257.610 nm)0.340190 ppm 0.001090 0.32 90774.500000 0.340190
Mo (202.032 nm)0.000893 ppm 0.000188 21.10 7.911090 0.000893
Na (589.592 nm)349.939000 o ppm 2.759100 0.79 4256000.000000 349.939000 o
Na H (589.593 nm)342.333662 ppm 8.126005 2.37 3089551.954499 342.333662
Ni (231.604 nm)0.028985 ppm 0.000665 2.29 88.489100 0.028985
P (213.618 nm)0.003667 ppm 0.001080 29.45 7.221520 0.003667
Pb (220.353 nm)19.834900 ppm 0.070964 0.36 45588.200000 19.834900
S (181.972 nm)14.932407 o ppm 0.124957 0.84 3066.299522 14.932407 o
Sb (206.834 nm)0.016509 ppm 0.000385 2.33 22.541900 0.016509
Se (196.026 nm)0.001834 ppm 0.001398 76.25 5.765500 0.001834
Si (288.158 nm)0.826538 ppm 0.001830 0.22 6717.380000 0.826538
Sn (189.925 nm)0.001094 u ppm 0.002204 > 100.00 3.016080 0.001094 u
Sr (421.552 nm)0.059903 ppm 0.000078 0.13 13236.212222 0.059903
Th (288.505 nm)0.015813 ppm 0.002383 15.07 296.947000 0.015813
Ti (336.122 nm)0.000184 ppm 0.000075 40.61 -20.351400 0.000184
Tl (190.794 nm)0.003181 ppm 0.001699 53.42 0.875496 0.003181
U (409.013 nm)0.036216 ppm 0.001218 3.36 188.738000 0.036216
V (292.401 nm)0.000516 ppm 0.000091 17.58 -19.645300 0.000516
Zn (206.200 nm)0.548359 ppm 0.001290 0.24 1186.620000 0.548359
Zr (343.823 nm)-0.000078 u ppm 0.000091 > 100.00 -6.262910 -0.000078 u
Test Report
52A112023.esws
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Page 1148 of 1261
Solution Name: 280-184612-C-1-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184612-C-1-B 11/21/2023 7:19:41 AM 3:73 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000603 ppm 0.000010 1.72 2306.729262 0.000603
Ag (328.068 nm)0.000763 ppm 0.000315 41.35 11.579800 0.000763
Al (394.401 nm)0.799377 ppm 0.001464 0.18 10283.600000 0.799377
Al H (396.152 nm)0.719796 u ppm 0.001995 0.28 3285.480000 0.719796 u
As (188.980 nm)0.004637 ppm 0.001264 27.25 0.331305 0.004637
B (249.678 nm)0.017049 ppm 0.000206 1.21 158.878000 0.017049
Ba (493.408 nm)0.171259 ppm 0.000756 0.44 25974.200000 0.171259
Be (234.861 nm)0.000371 ppm 0.000006 1.53 271.271000 0.000371
Bi (223.061 nm)0.001045 u ppm 0.001572 > 100.00 5.638800 0.001045 u
Ca (315.887 nm)53.873525 o ppm 0.077460 0.14 36309.321419 53.873525 o
Cd (214.439 nm)0.004876 ppm 0.000129 2.65 75.650800 0.004876
Co (228.615 nm)0.006986 ppm 0.000262 3.76 176.058000 0.006986
Cr (205.560 nm)0.003219 ppm 0.000824 25.61 14.717100 0.003219
Cu (324.754 nm)0.001172 ppm 0.000266 22.69 807.283000 0.001172
Fe (238.204 nm)13.165571 o ppm 0.032696 0.25 51841.738310 13.165571 o
Fe H (259.940 nm)12.905100 ppm 0.014466 0.11 20764.500000 12.905100
K (766.491 nm)0.982258 ppm 0.043996 4.48 1317.360000 0.982258
Li (670.783 nm)0.016594 ppm 0.002660 16.03 -3663.490000 0.016594
Mg (279.078 nm)2.860500 ppm 0.003096 0.11 9566.780000 2.860500
Mn (257.610 nm)0.347467 ppm 0.000798 0.23 92716.100000 0.347467
Mo (202.032 nm)0.000519 ppm 0.000398 76.72 6.053530 0.000519
Na (589.592 nm)339.385000 o ppm 0.661580 0.19 4128320.000000 339.385000 o
Na H (589.593 nm)330.946525 ppm 4.959964 1.50 2990323.966666 330.946525
Ni (231.604 nm)0.045592 ppm 0.000533 1.17 145.035000 0.045592
P (213.618 nm)0.000702 u ppm 0.001860 > 100.00 3.910520 0.000702 u
Pb (220.353 nm)22.483700 ppm 0.073116 0.33 51676.300000 22.483700
S (181.972 nm)21.503125 o ppm 0.093900 0.44 4405.065729 21.503125 o
Sb (206.834 nm)0.023532 ppm 0.001421 6.04 31.615000 0.023532
Se (196.026 nm)0.002393 u ppm 0.003889 > 100.00 5.335240 0.002393 u
Si (288.158 nm)0.822942 ppm 0.003208 0.39 6690.850000 0.822942
Sn (189.925 nm)-0.000154 u ppm 0.001397 > 100.00 2.177500 -0.000154 u
Sr (421.552 nm)0.092064 ppm 0.000519 0.56 20337.389188 0.092064
Th (288.505 nm)0.021432 ppm 0.002864 13.36 307.398000 0.021432
Ti (336.122 nm)-0.000163 u ppm 0.000025 15.20 -17.936800 -0.000163 u
Tl (190.794 nm)-0.000462 u ppm 0.002990 > 100.00 -3.213020 -0.000462 u
U (409.013 nm)0.043800 ppm 0.002846 6.50 229.701000 0.043800
V (292.401 nm)0.000697 ppm 0.000282 40.55 -10.594000 0.000697
Zn (206.200 nm)0.663979 ppm 0.000594 0.09 1435.940000 0.663979
Zr (343.823 nm)-0.000066 u ppm 0.000095 > 100.00 4.724500 -0.000066 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 278 of 287
Page 1149 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 7:24:08 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000051 ppm 0.000013 25.04 1062.022051 0.000051
Ag (328.068 nm)0.000251 ppm 0.000019 7.57 126.467000 0.000251
Al (394.401 nm)51.920300 o ppm 0.174354 0.34 638290.000000 51.920300 o
Al H (396.152 nm)49.101600 ppm 0.124557 0.25 220723.000000 49.101600
As (188.980 nm)0.003139 ppm 0.002534 80.71 -1.245800 0.003139
B (249.678 nm)-0.003043 u ppm 0.000655 21.54 -9.285310 -0.003043 u
Ba (493.408 nm)0.000251 ppm 0.000170 67.97 179.001000 0.000251
Be (234.861 nm)0.000103 ppm 0.000022 21.46 706.642000 0.000103
Bi (223.061 nm)-0.000974 u ppm 0.000649 66.67 2.637420 -0.000974 u
Ca (315.887 nm)-0.016615 u ppm 0.002649 15.94 -35.218026 -0.016615 u
Cd (214.439 nm)-0.000123 u ppm 0.000123 > 100.00 8.544260 -0.000123 u
Co (228.615 nm)0.000285 ppm 0.000079 27.80 48.300900 0.000285
Cr (205.560 nm)0.001130 ppm 0.000172 15.24 6.169840 0.001130
Cu (324.754 nm)-0.000633 u ppm 0.000111 17.47 1679.420000 -0.000633 u
Fe (238.204 nm)50.479377 o ppm 0.051444 0.10 198724.062074 50.479377 o
Fe H (259.940 nm)48.845500 ppm 0.043444 0.09 78979.700000 48.845500
K (766.491 nm)0.056278 ppm 0.044399 78.89 -346.300000 0.056278
Li (670.783 nm)0.012290 ppm 0.000997 8.12 -3823.540000 0.012290
Mg (279.078 nm)0.004982 ppm 0.000198 3.98 -164.245000 0.004982
Mn (257.610 nm)-0.000933 u ppm 0.000025 2.68 -244.443000 -0.000933 u
Mo (202.032 nm)0.000004 u ppm 0.000339 > 100.00 3.496300 0.000004 u
Na (589.592 nm)241.858000 o ppm 0.274462 0.11 2940860.000000 241.858000 o
Na H (589.593 nm)231.756975 ppm 2.542117 1.10 2120522.461848 231.756975
Ni (231.604 nm)-0.000317 u ppm 0.001233 > 100.00 -11.290300 -0.000317 u
P (213.618 nm)4.984710 ppm 0.028234 0.57 5887.020000 4.984710
Pb (220.353 nm)0.002278 ppm 0.001259 55.26 2.047050 0.002278
S (181.972 nm)4.704695 ppm 0.035294 0.75 984.077584 4.704695
Sb (206.834 nm)0.000325 u ppm 0.001213 > 100.00 5.885850 0.000325 u
Se (196.026 nm)0.004477 ppm 0.002381 53.19 2.477170 0.004477
Si (288.158 nm)0.022097 ppm 0.001361 6.16 872.182000 0.022097
Sn (189.925 nm)-0.000934 u ppm 0.001597 > 100.00 1.653460 -0.000934 u
Sr (421.552 nm)0.000499 ppm 0.000075 15.11 119.753951 0.000499
Th (288.505 nm)4.512380 ppm 0.024239 0.54 8693.570000 4.512380
Ti (336.122 nm)0.000762 ppm 0.000093 12.17 -34.919300 0.000762
Tl (190.794 nm)-0.003926 u ppm 0.001212 30.88 -7.657750 -0.003926 u
U (409.013 nm)2.389180 Q ppm 0.015502 0.65 10673.500000 Q 2.389180 Q
V (292.401 nm)0.000963 ppm 0.000182 18.93 282.250000 0.000963
Zn (206.200 nm)0.000324 u ppm 0.000664 > 100.00 4.862490 0.000324 u
Zr (343.823 nm)-0.001015 u ppm 0.000080 7.85 -22.212100 -0.001015 u
Test Report
52A112023.esws
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Page 1150 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 7:28:36 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.449395 Q ppm 0.001328 0.30 1152356.644654
Q 0.449395 Q
Ag (328.068 nm)0.505996 ppm 0.002816 0.56 27027.600000 0.505996
Al (394.401 nm)0.492658 ppm 0.003721 0.76 6518.440000 0.492658
Al H (396.152 nm)0.508010 u ppm 0.003862 0.76 2333.660000 0.508010 u
As (188.980 nm)0.503480 ppm 0.005993 1.19 414.903000 0.503480
B (249.678 nm)0.490777 ppm 0.003127 0.64 4123.820000 0.490777
Ba (493.408 nm)0.501213 ppm 0.001695 0.34 75917.200000 0.501213
Be (234.861 nm)0.519088 ppm 0.004172 0.80 86798.300000 0.519088
Bi (223.061 nm)0.998990 ppm 0.001924 0.19 1489.370000 0.998990
Ca (315.887 nm)5.009357 ppm 0.018850 0.38 3354.393498 5.009357
Cd (214.439 nm)0.512650 ppm 0.001093 0.21 7663.100000 0.512650
Co (228.615 nm)0.507274 ppm 0.001747 0.34 9736.150000 0.507274
Cr (205.560 nm)0.515250 ppm 0.002857 0.55 2119.340000 0.515250
Cu (324.754 nm)0.500451 ppm 0.002326 0.46 24104.800000 0.500451
Fe (238.204 nm)2.520453 ppm 0.002646 0.10 9944.519312 2.520453
Fe H (259.940 nm)2.530550 u ppm 0.003197 0.13 3960.080000 2.530550 u
K (766.491 nm)50.412600 ppm 0.242866 0.48 90126.500000 50.412600
Li (670.783 nm)0.498234 ppm 0.001588 0.32 14248.500000 0.498234
Mg (279.078 nm)20.184900 ppm 0.061129 0.30 67520.400000 20.184900
Mn (257.610 nm)0.495769 ppm 0.001140 0.23 132286.000000 0.495769
Mo (202.032 nm)0.504000 ppm 0.002494 0.49 2504.370000 0.504000
Na (589.592 nm)24.521800 ppm 0.105938 0.43 304976.000000 24.521800
Na H (589.593 nm)14.588802 u ppm 0.137357 0.94 223726.972132 14.588802 u
Ni (231.604 nm)0.518522 ppm 0.001845 0.36 1755.780000 0.518522
P (213.618 nm)0.010135 ppm 0.001812 17.88 -25.404000 0.010135
Pb (220.353 nm)0.539368 ppm 0.001978 0.37 1235.870000 0.539368
S (181.972 nm)-0.031640 u ppm 0.004938 15.61 20.113647 -0.031640 u
Sb (206.834 nm)0.494651 ppm 0.004708 0.95 604.371000 0.494651
Se (196.026 nm)0.499765 ppm 0.007012 1.40 311.769000 0.499765
Si (288.158 nm)4.903130 ppm 0.030503 0.62 36580.800000 4.903130
Sn (189.925 nm)0.501912 ppm 0.007171 1.43 339.559000 0.501912
Sr (421.552 nm)0.498361 ppm 0.001873 0.38 110047.413966 0.498361
Th (288.505 nm)0.039437 ppm 0.002120 5.37 322.258000 0.039437
Ti (336.122 nm)0.500587 ppm 0.001452 0.29 54516.400000 0.500587
Tl (190.794 nm)0.501984 ppm 0.003875 0.77 541.457000 0.501984
U (409.013 nm)-0.007816 u ppm 0.000810 10.36 -24.619600 -0.007816 u
V (292.401 nm)0.501160 ppm 0.001300 0.26 20825.800000 0.501160
Zn (206.200 nm)0.514394 ppm 0.001021 0.20 1113.380000 0.514394
Zr (343.823 nm)0.497910 ppm 0.001491 0.30 40585.000000 0.497910
Test Report
52A112023.esws
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Page 1151 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 7:32:57 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000486 ppm 0.000030 6.16 652.945673 0.000486
Ag (328.068 nm)0.000113 u ppm 0.000110 97.22 -23.115600 0.000113 u
Al (394.401 nm)-0.000460 u ppm 0.000984 > 100.00 444.540000 -0.000460 u
Al H (396.152 nm)-0.000304 u ppm 0.001871 > 100.00 49.200400 -0.000304 u
As (188.980 nm)0.002826 u ppm 0.004581 > 100.00 -1.056700 0.002826 u
B (249.678 nm)-0.000092 u ppm 0.000423 > 100.00 15.407500 -0.000092 u
Ba (493.408 nm)0.000088 u ppm 0.000207 > 100.00 12.754700 0.000088 u
Be (234.861 nm)0.000023 u ppm 0.000027 > 100.00 43.663900 0.000023 u
Bi (223.061 nm)-0.001540 u ppm 0.000384 24.93 1.795490 -0.001540 u
Ca (315.887 nm)0.013969 ppm 0.006242 44.68 -14.591301 0.013969
Cd (214.439 nm)0.000046 u ppm 0.000054 > 100.00 0.759802 0.000046 u
Co (228.615 nm)0.000012 u ppm 0.000129 > 100.00 43.071700 0.000012 u
Cr (205.560 nm)-0.000167 u ppm 0.000568 > 100.00 0.835026 -0.000167 u
Cu (324.754 nm)0.000088 u ppm 0.000206 > 100.00 770.100000 0.000088 u
Fe (238.204 nm)0.001014 ppm 0.000558 55.00 20.587928 0.001014
Fe H (259.940 nm)0.094471 u ppm 0.002565 2.71 14.195300 0.094471 u
K (766.491 nm)0.027695 ppm 0.019732 71.25 -397.655000 0.027695
Li (670.783 nm)0.010697 S ppm 0.000821 7.68 -3882.780000 S 0.010697 S
Mg (279.078 nm)0.001569 ppm 0.000604 38.51 14.172300 0.001569
Mn (257.610 nm)0.000003 u ppm 0.000029 > 100.00 5.234420 0.000003 u
Mo (202.032 nm)0.000823 ppm 0.000025 3.09 7.559890 0.000823
Na (589.592 nm)0.181170 ppm 0.011561 6.38 3239.990000 0.181170
Na H (589.593 nm)-9.801601 u ppm 0.008666 0.09 5871.263418 -9.801601 u
Ni (231.604 nm)0.000093 u ppm 0.000972 > 100.00 -9.893980 0.000093 u
P (213.618 nm)-0.001023 u ppm 0.002068 > 100.00 1.883680 -0.001023 u
Pb (220.353 nm)0.000148 u ppm 0.000920 > 100.00 -1.288090 0.000148 u
S (181.972 nm)-0.030018 u ppm 0.001562 5.20 17.955323 -0.030018 u
Sb (206.834 nm)0.001191 u ppm 0.001763 > 100.00 3.453980 0.001191 u
Se (196.026 nm)-0.001522 u ppm 0.001877 > 100.00 4.081430 -0.001522 u
Si (288.158 nm)-0.000808 u ppm 0.000914 > 100.00 705.731000 -0.000808 u
Sn (189.925 nm)-0.000600 u ppm 0.001648 > 100.00 1.877530 -0.000600 u
Sr (421.552 nm)0.000101 ppm 0.000062 61.78 31.937601 0.000101
Th (288.505 nm)0.005927 ppm 0.000991 16.72 271.607000 0.005927
Ti (336.122 nm)-0.000057 u ppm 0.000066 > 100.00 -124.260000 -0.000057 u
Tl (190.794 nm)0.002395 ppm 0.001555 64.95 0.110899 0.002395
U (409.013 nm)-0.001501 u ppm 0.001549 > 100.00 16.869100 -0.001501 u
V (292.401 nm)-0.000078 u ppm 0.000289 > 100.00 -42.374200 -0.000078 u
Zn (206.200 nm)-0.001344 u ppm 0.000112 8.35 1.265310 -0.001344 u
Zr (343.823 nm)0.000062 u ppm 0.000072 > 100.00 -2.582060 0.000062 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 281 of 287
Page 1152 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 7:36:59 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014291 ppm 0.000053 0.37 36145.683919 0.014291
Ag (328.068 nm)0.009987 ppm 0.000073 0.73 502.454000 0.009987
Al (394.401 nm)0.089276 ppm 0.000355 0.40 1558.830000 0.089276
Al H (396.152 nm)0.094499 u ppm 0.001882 1.99 475.264000 0.094499 u
As (188.980 nm)0.016000 ppm 0.001844 11.52 9.888480 0.016000
B (249.678 nm)0.094964 ppm 0.000253 0.27 810.999000 0.094964
Ba (493.408 nm)0.009976 ppm 0.000076 0.76 1510.650000 0.009976
Be (234.861 nm)0.000993 ppm 0.000017 1.73 207.026000 0.000993
Bi (223.061 nm)-0.000436 Qu ppm 0.001662 > 100.00 3.437230 Q -0.000436 Qu
Ca (315.887 nm)0.209288 ppm 0.001140 0.54 117.135243 0.209288
Cd (214.439 nm)0.005158 ppm 0.000131 2.53 77.195500 0.005158
Co (228.615 nm)0.010233 ppm 0.000063 0.61 238.346000 0.010233
Cr (205.560 nm)0.010260 ppm 0.000287 2.80 43.629600 0.010260
Cu (324.754 nm)0.014784 ppm 0.000201 1.36 1449.250000 0.014784
Fe (238.204 nm)0.101512 ppm 0.002710 2.67 416.259281 0.101512
Fe H (259.940 nm)0.191568 u ppm 0.003136 1.64 171.470000 0.191568 u
K (766.491 nm)3.033670 ppm 0.065969 2.17 5003.040000 3.033670
Li (670.783 nm)0.028936 Q ppm 0.002276 7.87 -3204.480000 Q 0.028936 Q
Mg (279.078 nm)0.201836 ppm 0.001297 0.64 683.337000 0.201836
Mn (257.610 nm)0.010109 ppm 0.000020 0.20 2701.750000 0.010109
Mo (202.032 nm)0.020301 ppm 0.000582 2.87 104.215000 0.020301
Na (589.592 nm)1.164970 ppm 0.017103 1.47 15316.000000 1.164970
Na H (589.593 nm)-8.869705 u ppm 0.016633 0.19 14116.224439 -8.869705 u
Ni (231.604 nm)0.042329 ppm 0.000891 2.10 133.936000 0.042329
P (213.618 nm)2.825950 ppm 0.020316 0.72 3338.090000 2.825950
Pb (220.353 nm)0.008925 ppm 0.000894 10.02 18.915400 0.008925
S (181.972 nm)0.064696 Q ppm 0.004038 6.24 37.309183 Q 0.064696 Q
Sb (206.834 nm)0.020198 ppm 0.001584 7.84 26.536700 0.020198
Se (196.026 nm)0.016770 ppm 0.004349 25.94 15.302500 0.016770
Si (288.158 nm)0.459364 ppm 0.003264 0.71 4079.010000 0.459364
Sn (189.925 nm)0.096509 ppm 0.001304 1.35 67.133900 0.096509
Sr (421.552 nm)0.009797 ppm 0.000226 2.31 2172.823663 0.009797
Th (288.505 nm)0.007053 Q ppm 0.000917 13.00 273.800000 Q 0.007053 Q
Ti (336.122 nm)0.009531 ppm 0.000017 0.18 922.301000 0.009531
Tl (190.794 nm)0.015781 ppm 0.000575 3.64 14.601600 0.015781
U (409.013 nm)0.053922 ppm 0.001775 3.29 260.612000 0.053922
V (292.401 nm)0.009772 ppm 0.000089 0.91 362.979000 0.009772
Zn (206.200 nm)0.020292 ppm 0.000457 2.25 47.918800 0.020292
Zr (343.823 nm)0.009736 ppm 0.000082 0.85 786.147000 0.009736
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 282 of 287
Page 1153 of 1261
Solution Name: 280-184613-C-1-B
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
280-184613-C-1-B 11/21/2023 7:41:17 AM 3:74 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.002176 ppm 0.000012 0.53 6004.872428 0.002176
Ag (328.068 nm)0.000824 ppm 0.000211 25.66 13.462100 0.000824
Al (394.401 nm)1.604760 ppm 0.010549 0.66 20198.500000 1.604760
Al H (396.152 nm)1.472920 ppm 0.008453 0.57 6670.180000 1.472920
As (188.980 nm)0.007190 ppm 0.003045 42.35 2.564490 0.007190
B (249.678 nm)0.027241 ppm 0.000499 1.83 244.176000 0.027241
Ba (493.408 nm)0.157014 ppm 0.001044 0.66 23781.400000 0.157014
Be (234.861 nm)0.000386 ppm 0.000003 0.86 111.636000 0.000386
Bi (223.061 nm)-0.000563 u ppm 0.001077 > 100.00 3.247600 -0.000563 u
Ca (315.887 nm)126.695352 o ppm 0.937518 0.74 85421.751166 126.695352 o
Cd (214.439 nm)0.005554 ppm 0.000156 2.81 83.216000 0.005554
Co (228.615 nm)0.011897 ppm 0.000365 3.06 269.691000 0.011897
Cr (205.560 nm)0.005793 ppm 0.000455 7.86 25.029300 0.005793
Cu (324.754 nm)0.004076 ppm 0.000313 7.68 880.992000 0.004076
Fe (238.204 nm)0.569385 ppm 0.005498 0.97 2258.014989 0.569385
Fe H (259.940 nm)0.642436 u ppm 0.003071 0.48 901.773000 0.642436 u
K (766.491 nm)3.858220 ppm 0.038206 0.99 6484.470000 3.858220
Li (670.783 nm)0.008520 ppm 0.000662 7.77 -3963.740000 0.008520
Mg (279.078 nm)9.051930 ppm 0.049491 0.55 30282.300000 9.051930
Mn (257.610 nm)0.389889 ppm 0.002516 0.65 104035.000000 0.389889
Mo (202.032 nm)0.001727 ppm 0.000288 16.65 12.046900 0.001727
Na (589.592 nm)340.964000 o ppm 1.660990 0.49 4147350.000000 340.964000 o
Na H (589.593 nm)331.531142 ppm 4.657969 1.40 2995315.126378 331.531142
Ni (231.604 nm)0.318009 ppm 0.002751 0.87 1072.640000 0.318009
P (213.618 nm)0.004347 ppm 0.004605 > 100.00 7.967540 0.004347
Pb (220.353 nm)1.021980 ppm 0.008704 0.85 2347.310000 1.021980
S (181.972 nm)22.957427 o ppm 0.121864 0.53 4702.237838 22.957427 o
Sb (206.834 nm)0.037988 ppm 0.002172 5.72 48.376300 0.037988
Se (196.026 nm)0.003750 u ppm 0.006372 > 100.00 7.515760 0.003750 u
Si (288.158 nm)4.400050 ppm 0.015390 0.35 32680.600000 4.400050
Sn (189.925 nm)-0.000262 u ppm 0.001545 > 100.00 2.105150 -0.000262 u
Sr (421.552 nm)0.132157 ppm 0.000868 0.66 29189.974741 0.132157
Th (288.505 nm)0.033845 ppm 0.000718 2.12 332.158000 0.033845
Ti (336.122 nm)-0.000433 u ppm 0.000068 15.60 112.224000 -0.000433 u
Tl (190.794 nm)0.001145 u ppm 0.003200 > 100.00 -1.233650 0.001145 u
U (409.013 nm)0.096100 ppm 0.005850 6.09 447.884000 0.096100
V (292.401 nm)0.001099 ppm 0.000152 13.81 3.100800 0.001099
Zn (206.200 nm)0.721922 ppm 0.003355 0.46 1560.890000 0.721922
Zr (343.823 nm)-0.000036 u ppm 0.000202 > 100.00 -9.787340 -0.000036 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 283 of 287
Page 1154 of 1261
Solution Name: CCVH-8068274
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVH-8068274 11/21/2023 7:45:39 AM S1:1 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000035 ppm 0.000008 22.99 1010.666917 0.000035
Ag (328.068 nm)0.000279 ppm 0.000156 55.94 126.896000 0.000279
Al (394.401 nm)51.442500 o ppm 0.157057 0.31 632420.000000 51.442500 o
Al H (396.152 nm)48.941200 ppm 0.257887 0.53 220002.000000 48.941200
As (188.980 nm)0.001234 u ppm 0.002636 > 100.00 -2.828010 0.001234 u
B (249.678 nm)-0.003281 u ppm 0.000679 20.71 -11.282000 -0.003281 u
Ba (493.408 nm)0.000138 u ppm 0.000193 > 100.00 161.526000 0.000138 u
Be (234.861 nm)0.000034 u ppm 0.000078 > 100.00 693.296000 0.000034 u
Bi (223.061 nm)-0.000558 u ppm 0.002127 > 100.00 3.255900 -0.000558 u
Ca (315.887 nm)-0.014356 u ppm 0.004882 34.01 -33.694540 -0.014356 u
Cd (214.439 nm)0.000056 u ppm 0.000150 > 100.00 11.183300 0.000056 u
Co (228.615 nm)0.000502 ppm 0.000053 10.64 52.420100 0.000502
Cr (205.560 nm)0.000148 u ppm 0.000197 > 100.00 2.130880 0.000148 u
Cu (324.754 nm)-0.000600 u ppm 0.000349 58.16 1672.840000 -0.000600 u
Fe (238.204 nm)50.321843 o ppm 0.300320 0.60 198103.959506 50.321843 o
Fe H (259.940 nm)48.688500 ppm 0.272491 0.56 78725.300000 48.688500
K (766.491 nm)-0.012282 u ppm 0.032353 > 100.00 -469.479000 -0.012282 u
Li (670.783 nm)0.009704 ppm 0.001107 11.41 -3919.710000 0.009704
Mg (279.078 nm)0.005765 ppm 0.000731 12.67 -160.008000 0.005765
Mn (257.610 nm)-0.000905 u ppm 0.000018 2.03 -236.990000 -0.000905 u
Mo (202.032 nm)-0.000323 u ppm 0.000220 68.08 1.875580 -0.000323 u
Na (589.592 nm)241.844000 o ppm 0.632663 0.26 2940690.000000 241.844000 o
Na H (589.593 nm)232.017020 ppm 1.472197 0.63 2122797.141649 232.017020
Ni (231.604 nm)-0.000047 u ppm 0.000522 > 100.00 -10.369900 -0.000047 u
P (213.618 nm)4.947090 ppm 0.008848 0.18 5842.630000 4.947090
Pb (220.353 nm)0.000142 u ppm 0.000733 > 100.00 -2.890420 0.000142 u
S (181.972 nm)4.680966 ppm 0.022946 0.49 979.243091 4.680966
Sb (206.834 nm)-0.001143 u ppm 0.000892 78.07 4.084020 -0.001143 u
Se (196.026 nm)0.006291 ppm 0.000852 13.55 3.605450 0.006291
Si (288.158 nm)0.023505 ppm 0.001671 7.11 882.332000 0.023505
Sn (189.925 nm)-0.000821 u ppm 0.001005 > 100.00 1.729270 -0.000821 u
Sr (421.552 nm)0.000515 ppm 0.000099 19.24 123.336399 0.000515
Th (288.505 nm)4.479210 Q ppm 0.007589 0.17 8631.530000 Q 4.479210 Q
Ti (336.122 nm)0.000648 ppm 0.000049 7.58 -47.393500 0.000648
Tl (190.794 nm)-0.004768 u ppm 0.001109 23.26 -8.567730 -0.004768 u
U (409.013 nm)2.362190 Q ppm 0.012882 0.55 10553.700000 Q 2.362190 Q
V (292.401 nm)0.000607 ppm 0.000101 16.58 265.171000 0.000607
Zn (206.200 nm)0.000769 u ppm 0.000987 > 100.00 5.821730 0.000769 u
Zr (343.823 nm)-0.000945 u ppm 0.000046 4.88 -16.681000 -0.000945 u
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 284 of 287
Page 1155 of 1261
Solution Name: CCV-8068273
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCV-8068273 11/21/2023 7:50:05 AM S1:2 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.448827 Q ppm 0.001149 0.26 1150896.445116
Q 0.448827 Q
Ag (328.068 nm)0.504876 ppm 0.001805 0.36 26968.100000 0.504876
Al (394.401 nm)0.492578 ppm 0.002283 0.46 6518.620000 0.492578
Al H (396.152 nm)0.503400 u ppm 0.001813 0.36 2312.950000 0.503400 u
As (188.980 nm)0.498046 ppm 0.001579 0.32 410.388000 0.498046
B (249.678 nm)0.489866 ppm 0.000516 0.11 4116.190000 0.489866
Ba (493.408 nm)0.500931 ppm 0.000635 0.13 75874.500000 0.500931
Be (234.861 nm)0.512133 ppm 0.001426 0.28 85636.200000 0.512133
Bi (223.061 nm)0.995572 ppm 0.001974 0.20 1484.290000 0.995572
Ca (315.887 nm)5.008579 ppm 0.007401 0.15 3353.868429 5.008579
Cd (214.439 nm)0.510390 ppm 0.000981 0.19 7629.320000 0.510390
Co (228.615 nm)0.505573 ppm 0.000659 0.13 9703.680000 0.505573
Cr (205.560 nm)0.514463 ppm 0.002886 0.56 2116.110000 0.514463
Cu (324.754 nm)0.498805 ppm 0.001053 0.21 24027.100000 0.498805
Fe (238.204 nm)2.515263 ppm 0.002781 0.11 9924.059889 2.515263
Fe H (259.940 nm)2.525150 u ppm 0.002027 0.08 3951.330000 2.525150 u
K (766.491 nm)50.152800 ppm 0.311767 0.62 89659.800000 50.152800
Li (670.783 nm)0.499917 ppm 0.000645 0.13 14311.000000 0.499917
Mg (279.078 nm)20.133900 ppm 0.047446 0.24 67349.800000 20.133900
Mn (257.610 nm)0.494905 ppm 0.001197 0.24 132056.000000 0.494905
Mo (202.032 nm)0.502629 ppm 0.001475 0.29 2497.570000 0.502629
Na (589.592 nm)24.397300 ppm 0.131317 0.54 303459.000000 24.397300
Na H (589.593 nm)14.574104 u ppm 0.101752 0.70 223595.521866 14.574104 u
Ni (231.604 nm)0.516554 ppm 0.002194 0.42 1749.080000 0.516554
P (213.618 nm)0.007043 ppm 0.001562 22.18 -28.947600 0.007043
Pb (220.353 nm)0.536015 ppm 0.000908 0.17 1228.170000 0.536015
S (181.972 nm)-0.030600 u ppm 0.004239 13.85 20.316149 -0.030600 u
Sb (206.834 nm)0.491301 ppm 0.001395 0.28 600.289000 0.491301
Se (196.026 nm)0.497880 ppm 0.000746 0.15 310.612000 0.497880
Si (288.158 nm)4.888990 ppm 0.018595 0.38 36479.500000 4.888990
Sn (189.925 nm)0.507625 ppm 0.004941 0.97 343.398000 0.507625
Sr (421.552 nm)0.497960 ppm 0.000245 0.05 109958.984926 0.497960
Th (288.505 nm)0.037454 ppm 0.004165 11.12 318.638000 0.037454
Ti (336.122 nm)0.499954 ppm 0.001349 0.27 54447.300000 0.499954
Tl (190.794 nm)0.501065 ppm 0.004204 0.84 540.461000 0.501065
U (409.013 nm)-0.003144 u ppm 0.001642 52.21 -4.073520 -0.003144 u
V (292.401 nm)0.499459 ppm 0.000917 0.18 20754.300000 0.499459
Zn (206.200 nm)0.511565 ppm 0.001496 0.29 1107.280000 0.511565
Zr (343.823 nm)0.497560 ppm 0.001582 0.32 40556.500000 0.497560
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 285 of 287
Page 1156 of 1261
Solution Name: CCB
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCB 11/21/2023 7:54:28 AM S1:4 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.000492 ppm 0.000002 0.43 667.617877 0.000492
Ag (328.068 nm)0.000194 ppm 0.000118 60.85 -19.053800 0.000194
Al (394.401 nm)-0.002651 u ppm 0.001174 44.29 419.046000 -0.002651 u
Al H (396.152 nm)-0.001694 u ppm 0.003649 > 100.00 42.950500 -0.001694 u
As (188.980 nm)0.001017 u ppm 0.001673 > 100.00 -2.559400 0.001017 u
B (249.678 nm)0.000133 u ppm 0.000421 > 100.00 17.291500 0.000133 u
Ba (493.408 nm)0.000196 u ppm 0.000281 > 100.00 29.059400 0.000196 u
Be (234.861 nm)-0.000021 u ppm 0.000014 69.19 36.456100 -0.000021 u
Bi (223.061 nm)-0.001335 u ppm 0.001255 94.01 2.100260 -0.001335 u
Ca (315.887 nm)0.015723 ppm 0.006149 39.11 -13.408469 0.015723
Cd (214.439 nm)0.000048 u ppm 0.000143 > 100.00 0.789259 0.000048 u
Co (228.615 nm)-0.000080 u ppm 0.000282 > 100.00 41.328100 -0.000080 u
Cr (205.560 nm)-0.000320 u ppm 0.000504 > 100.00 0.204851 -0.000320 u
Cu (324.754 nm)0.000084 u ppm 0.000189 > 100.00 768.845000 0.000084 u
Fe (238.204 nm)0.002234 ppm 0.002804 > 100.00 25.397727 0.002234
Fe H (259.940 nm)0.096570 u ppm 0.004141 4.29 17.596000 0.096570 u
K (766.491 nm)0.013517 u ppm 0.072750 > 100.00 -423.127000 0.013517 u
Li (670.783 nm)0.014219 S ppm 0.000125 0.88 -3751.790000 S 0.014219 S
Mg (279.078 nm)0.001312 u ppm 0.001865 > 100.00 13.346000 0.001312 u
Mn (257.610 nm)-0.000025 u ppm 0.000021 82.80 -2.287370 -0.000025 u
Mo (202.032 nm)0.000234 u ppm 0.000348 > 100.00 4.639070 0.000234 u
Na (589.592 nm)0.146558 ppm 0.003850 2.63 2818.930000 0.146558
Na H (589.593 nm)-9.865196 u ppm 0.017028 0.17 5314.292118 -9.865196 u
Ni (231.604 nm)0.000222 u ppm 0.000955 > 100.00 -9.453460 0.000222 u
P (213.618 nm)-0.000931 u ppm 0.002165 > 100.00 2.023270 -0.000931 u
Pb (220.353 nm)-0.000019 u ppm 0.000424 > 100.00 -1.664560 -0.000019 u
S (181.972 nm)-0.036070 u ppm 0.012562 34.83 16.723884 -0.036070 u
Sb (206.834 nm)-0.000701 u ppm 0.001385 > 100.00 1.150710 -0.000701 u
Se (196.026 nm)0.001144 u ppm 0.002644 > 100.00 5.716900 0.001144 u
Si (288.158 nm)-0.002803 u ppm 0.001442 51.47 691.553000 -0.002803 u
Sn (189.925 nm)0.000641 u ppm 0.001193 > 100.00 2.711540 0.000641 u
Sr (421.552 nm)0.000103 ppm 0.000035 34.30 32.415175 0.000103
Th (288.505 nm)0.004130 ppm 0.001040 25.18 268.251000 0.004130
Ti (336.122 nm)0.000020 u ppm 0.000057 > 100.00 -115.843000 0.000020 u
Tl (190.794 nm)0.002124 u ppm 0.002895 > 100.00 -0.182470 0.002124 u
U (409.013 nm)-0.000615 u ppm 0.001814 > 100.00 20.716700 -0.000615 u
V (292.401 nm)-0.000087 u ppm 0.000041 47.18 -43.251900 -0.000087 u
Zn (206.200 nm)-0.001395 u ppm 0.000563 40.34 1.155620 -0.001395 u
Zr (343.823 nm)0.000059 ppm 0.000038 63.70 -2.815770 0.000059
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 286 of 287
Page 1157 of 1261
Solution Name: CCVL-8079070
Solution Name Date Rack:Tube Weight (g)Volume (mL)Dilution
CCVL-8079070 11/21/2023 7:58:30 AM S1:3 1 1 1
Label Solution
Concentration
Unit Conc SD Conc %RSD Intensity (c/s)Adjusted Concentration
(Li-A) (670.783 nm)0.014153 ppm 0.000021 0.15 35790.308552 0.014153
Ag (328.068 nm)0.009693 ppm 0.000129 1.33 486.632000 0.009693
Al (394.401 nm)0.085834 ppm 0.000024 0.03 1517.870000 0.085834
Al H (396.152 nm)0.092829 u ppm 0.001288 1.39 467.756000 0.092829 u
As (188.980 nm)0.014695 ppm 0.001419 9.65 8.804390 0.014695
B (249.678 nm)0.093706 ppm 0.000375 0.40 800.464000 0.093706
Ba (493.408 nm)0.009986 ppm 0.000104 1.04 1512.050000 0.009986
Be (234.861 nm)0.000973 ppm 0.000005 0.55 203.770000 0.000973
Bi (223.061 nm)-0.000204 Qu ppm 0.002965 > 100.00 3.782440 Q -0.000204 Qu
Ca (315.887 nm)0.206290 ppm 0.007202 3.49 115.113270 0.206290
Cd (214.439 nm)0.005158 ppm 0.000112 2.17 77.191100 0.005158
Co (228.615 nm)0.010157 ppm 0.000309 3.04 236.885000 0.010157
Cr (205.560 nm)0.010322 ppm 0.000418 4.05 43.883100 0.010322
Cu (324.754 nm)0.014275 ppm 0.000084 0.59 1424.430000 0.014275
Fe (238.204 nm)0.100492 ppm 0.001944 1.93 412.246580 0.100492
Fe H (259.940 nm)0.190908 u ppm 0.003057 1.60 170.401000 0.190908 u
K (766.491 nm)2.986160 ppm 0.045202 1.51 4917.680000 2.986160
Li (670.783 nm)0.032331 Q ppm 0.000207 0.64 -3078.220000 Q 0.032331 Q
Mg (279.078 nm)0.198079 ppm 0.000974 0.49 670.899000 0.198079
Mn (257.610 nm)0.010023 ppm 0.000011 0.11 2678.810000 0.010023
Mo (202.032 nm)0.020390 ppm 0.000301 1.48 104.654000 0.020390
Na (589.592 nm)1.114290 ppm 0.005295 0.48 14699.000000 1.114290
Na H (589.593 nm)-8.951411 u ppm 0.010801 0.12 13400.263796 -8.951411 u
Ni (231.604 nm)0.042327 ppm 0.000715 1.69 133.928000 0.042327
P (213.618 nm)2.788090 ppm 0.002805 0.10 3293.410000 2.788090
Pb (220.353 nm)0.009757 ppm 0.001631 16.71 20.826500 0.009757
S (181.972 nm)0.049147 Q ppm 0.006194 12.60 34.140285 Q 0.049147 Q
Sb (206.834 nm)0.020966 ppm 0.001287 6.14 27.474500 0.020966
Se (196.026 nm)0.017581 ppm 0.004524 25.73 15.800200 0.017581
Si (288.158 nm)0.451618 ppm 0.004939 1.09 4023.090000 0.451618
Sn (189.925 nm)0.097942 ppm 0.001187 1.21 68.096800 0.097942
Sr (421.552 nm)0.009649 ppm 0.000158 1.64 2140.143785 0.009649
Th (288.505 nm)0.001104 Qu ppm 0.002566 > 100.00 262.692000 Q 0.001104 Qu
Ti (336.122 nm)0.009543 ppm 0.000022 0.23 923.642000 0.009543
Tl (190.794 nm)0.017502 ppm 0.001249 7.14 16.469500 0.017502
U (409.013 nm)0.055363 ppm 0.001861 3.36 266.875000 0.055363
V (292.401 nm)0.009640 ppm 0.000081 0.84 356.873000 0.009640
Zn (206.200 nm)0.019405 ppm 0.000373 1.92 46.007300 0.019405
Zr (343.823 nm)0.009730 ppm 0.000027 0.27 785.638000 0.009730
Test Report
52A112023.esws
[Rev. 2]Printed: 2023-11-21 08:22:08-07:00 Page 287 of 287
Page 1158 of 1261
Report Generated By Teledyne Leeman QuickTrace
Analyst:
Worksheet file:
Creation Date:
Comment:
denmet,X4NN/CJ9W
C:\Users\Public\Documents\Teledyne CETAC\QuickTrace\Worksheets\112723-36C.wszf
11/27/2023 4:55:32 PM
Results
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
STD0 11/27/23 06:20:13 pm 872 2.16 1.0000
Replicates 896.9 875.9 857.4 857.4
0.0000STD N/A
STD1 11/27/23 06:22:45 pm 2598 0.56 1.0000
Replicates 2617.8 2594.5 2599.0 2582.6
0.0600STD N/A10.01%
STD2 11/27/23 06:25:18 pm 3808 0.23 1.0000
Replicates 3814.1 3810.3 3794.6 3811.1
0.1200STD N/A-2.09%
STD3 11/27/23 06:27:50 pm 8794 0.26 1.0000
Replicates 8761.0 8795.8 8812.3 8806.1
0.3000STD N/A9.94%
STD4 11/27/23 06:30:23 pm 15094 0.91 1.0000
Replicates 14908.9 15076.6 15173.8 15217.5
0.6000STD N/A-0.31%
STD5 11/27/23 06:32:56 pm 29187 1.15 1.0000
Replicates 28748.9 29117.4 29358.4 29524.3
1.2000STD N/A-0.15%
STD6 11/27/23 06:35:29 pm 70502 1.17 1.0000
Replicates 69469.3 70267.3 70895.6 71373.8
3.0000STD N/A-1.41%
STD7 11/27/23 06:38:03 pm 142424 1.23 1.0000
Replicates 140202.0 141966.2 143244.8 144282.0
6.0000STD N/A0.34%
Concentration (ug/L)
6543210
µA
b
s
o
r
b
a
n
c
e
150,000
100,000
50,000
0
Equation:
R2:
SEE:
Flags:
Abs = 23483.275x + 1048.373
Calibration
0.99990
542.9025
RSE: 6.41%
ICV 280-635180/9-A 11/27/23 06:44:34 pm 61222 1.28 1.0000
Replicates 60243.2 61037.6 61581.6 62024.9
2.5624ICV 106.77
ICV 280-635180/9-A 11/27/23 06:48:39 pm 58760 1.30 1.0000
Replicates 57803.2 58559.3 59143.4 59533.4
2.4576ICV 102.40
ICB 280-635180/10-A 11/27/23 06:51:11 pm 487 3.75 1.0000
Replicates 481.5 516.6 483.4 466.8
-0.0239ICB N/A
CRA 280-635180/11-A 11/27/23 06:53:43 pm 3577 1.40 1.0000
Replicates 3558.1 3542.3 3586.2 3622.8
0.1077CRDL 89.74
CCV 280-635180/12-A 11/27/23 06:56:17 pm 70467 1.25 1.0000
Replicates 69391.2 70200.8 70882.6 71394.6
2.9561CCV 98.54
11/28/2023 11:26:29 AM Page 1112723-36C.wszf of 9
Page 1159 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
CCB 280-635180/13-A 11/27/23 06:58:48 pm 505 3.23 1.0000
Replicates 481.5 519.2 502.5 517.9
-0.0231CCB N/A
MB 280-635165/1-A 11/27/23 07:01:20 pm 558 2.38 1.0000
Replicates 569.9 543.9 553.4 564.9
-0.0209UNK N/A
LCS 280-635165/2-A 11/27/23 07:03:51 pm 73477 1.17 1.0000
Replicates 72398.9 73263.0 73881.8 74363.0
3.0843UNK N/A
LCSD 280-635165/3-A 11/27/23 07:06:23 pm 74236 1.14 1.0000
Replicates 73180.7 74017.3 74647.1 75097.3
3.1166UNK N/A
280-184299-A-1-B 11/27/23 07:08:55 pm 5314 2.01 1.0000
Replicates 5208.2 5279.5 5375.2 5391.2
0.1816UNK N/A
280-184299-A-1-B SD@5 11/27/23 07:11:27 pm 1451 4.92 1.0000
Replicates 1423.5 1449.0 1460.5 1469.0
0.0171UNK N/A
280-184299-A-1-C MS 11/27/23 07:13:59 pm 63813 1.56 1.0000
Replicates 62589.6 63547.2 64254.5 64860.7
2.6727UNK N/A
280-184299-A-1-D MSD 11/27/23 07:16:31 pm 62884 1.66 1.0000
Replicates 61623.3 62561.9 63351.7 63998.6
2.6332UNK N/A
280-184299-A-1-B PDS 11/27/23 07:19:03 pm 67907 1.47 1.0000
Replicates 66648.0 67678.6 68364.1 68937.6
2.8471UNK N/A
280-184299-A-2-B 11/27/23 07:21:36 pm 1456 5.40 1.0000
Replicates 1422.8 1469.1 1465.1 1465.5
0.0173UNK N/A
280-184299-A-3-B 11/27/23 07:24:08 pm 2894 2.56 1.0000
Replicates 2845.8 2862.2 2942.6 2926.1
0.0786UNK N/A
CCV 280-635180/12-A 11/27/23 07:26:42 pm 70056 1.12 1.0000
Replicates 69089.3 69853.3 70400.3 70881.9
2.9386CCV 97.95
CCB 280-635180/13-A 11/27/23 07:29:13 pm 535 1.83 1.0000
Replicates 545.7 523.1 537.5 532.5
-0.0219CCB N/A
280-184299-A-4-B 11/27/23 07:31:46 pm 791 7.02 1.0000
Replicates 800.5 811.2 770.3 783.8
-0.0109UNK N/A
280-184299-A-5-B 11/27/23 07:34:19 pm 16186 1.69 1.0000
Replicates 15870.4 16110.4 16300.8 16463.3
0.6446UNK N/A
280-184097-E-7-B 11/27/23 07:36:50 pm 562 4.88 1.0000
Replicates 544.4 576.7 540.0 588.0
-0.0207UNK N/A
280-184105-D-1-B 11/27/23 07:39:22 pm 579 4.04 1.0000
Replicates 561.4 581.2 605.0 569.8
-0.0200UNK N/A
280-184105-D-2-B 11/27/23 07:41:53 pm 519 1.85 1.0000
Replicates 524.2 513.8 529.3 507.6
-0.0226UNK N/A
280-184105-D-3-B 11/27/23 07:44:25 pm 614 2.37 1.0000
Replicates 607.9 612.0 607.5 629.3
-0.0185UNK N/A
11/28/2023 11:26:29 AM Page 2112723-36C.wszf of 9
Page 1160 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
280-184105-D-4-B 11/27/23 07:46:57 pm 645 2.78 1.0000
Replicates 653.1 645.2 629.7 653.9
-0.0172UNK N/A
280-184105-D-5-B 11/27/23 07:49:29 pm 606 3.47 1.0000
Replicates 610.0 584.2 607.7 620.7
-0.0189UNK N/A
280-184105-D-6-B 11/27/23 07:52:01 pm 574 5.00 1.0000
Replicates 570.9 542.2 589.4 594.7
-0.0202UNK N/A
280-184105-D-7-B 11/27/23 07:54:34 pm 684 1.56 1.0000
Replicates 691.3 678.6 684.4 680.1
-0.0155UNK N/A
CCV 280-635180/12-A 11/27/23 07:57:07 pm 69888 1.22 1.0000
Replicates 68831.1 69654.8 70300.8 70765.5
2.9314CCV 97.71
CCB 280-635180/13-A 11/27/23 07:59:39 pm 502 3.10 1.0000
Replicates 496.0 493.7 526.7 489.8
-0.0233CCB N/A
280-184105-D-8-B 11/27/23 08:02:11 pm 542 1.85 1.0000
Replicates 529.6 548.1 550.4 540.3
-0.0216UNK N/A
280-184105-D-9-B 11/27/23 08:04:44 pm 534 2.00 1.0000
Replicates 537.1 544.0 536.6 519.8
-0.0219UNK N/A
280-184390-B-1-A 11/27/23 08:07:17 pm 577 6.68 1.0000
Replicates 572.5 535.0 609.0 590.2
-0.0201UNK N/A
280-184157-E-3-B 11/27/23 08:09:50 pm 562 2.50 1.0000
Replicates 552.8 551.5 569.3 576.0
-0.0207UNK N/A
280-184158-D-1-A 11/27/23 08:12:21 pm 573 3.67 1.0000
Replicates 565.3 552.5 592.5 580.4
-0.0203UNK N/A
280-184158-B-2-C 11/27/23 08:14:52 pm 716 2.83 1.0000
Replicates 704.0 720.5 712.5 725.5
-0.0142UNK N/A
280-183860-E-2-B 11/27/23 08:17:24 pm 577 1.66 1.0000
Replicates 580.7 577.5 565.5 583.2
-0.0201UNK N/A
CCV 280-635180/12-A 11/27/23 08:19:58 pm 69809 1.24 1.0000
Replicates 68751.5 69548.4 70204.9 70729.4
2.9280CCV 97.60
CCB 280-635180/13-A 11/27/23 08:22:29 pm 527 2.02 1.0000
Replicates 517.2 535.9 518.6 536.2
-0.0222CCB N/A
MB 280-635167/1-A 11/27/23 08:25:01 pm 539 2.72 1.0000
Replicates 533.5 530.4 560.0 533.7
-0.0217UNK N/A
LCS 280-635167/2-A 11/27/23 08:27:33 pm 72762 1.22 1.0000
Replicates 71635.6 72570.5 73174.0 73667.8
3.0538UNK N/A
LCSD 280-635167/3-A 11/27/23 08:30:04 pm 74004 1.31 1.0000
Replicates 72799.9 73748.8 74467.1 74999.8
3.1067UNK N/A
280-184095-H-3-B 11/27/23 08:32:36 pm 329 3.10 1.0000
Replicates 330.3 316.8 309.8 360.2
-0.0306UNK N/A
11/28/2023 11:26:29 AM Page 3112723-36C.wszf of 9
Page 1161 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
280-184095-H-4-E 11/27/23 08:35:08 pm 449 2.28 1.0000
Replicates 440.1 438.5 468.2 449.2
-0.0255UNK N/A
280-184095-H-4-F MS 11/27/23 08:37:40 pm 67914 1.41 1.0000
Replicates 66729.4 67657.6 68336.4 68930.6
2.8474UNK N/A
280-184095-H-4-G MSD 11/27/23 08:40:12 pm 67539 1.49 1.0000
Replicates 66311.5 67238.6 68014.4 68591.2
2.8314UNK N/A
280-184095-H-5-B 11/27/23 08:42:45 pm 237 0.98 1.0000
Replicates 242.8 229.3 245.6 232.1
-0.0345UNK N/A
280-184123-C-3-B 11/27/23 08:45:17 pm 419 2.04 1.0000
Replicates 404.7 415.4 435.6 420.8
-0.0268UNK N/A
280-184123-C-4-B 11/27/23 08:47:50 pm 547 1.78 1.0000
Replicates 557.9 551.0 540.5 539.0
-0.0213UNK N/A
CCV 280-635180/12-A 11/27/23 08:50:23 pm 70024 1.17 1.0000
Replicates 68988.3 69841.1 70418.5 70846.8
2.9372CCV 97.91
CCB 280-635180/13-A 11/27/23 08:52:55 pm 521 3.20 1.0000
Replicates 507.8 512.4 545.4 518.3
-0.0225CCB N/A
280-184123-C-5-A 11/27/23 08:55:27 pm 544 4.56 1.0000
Replicates 511.7 558.8 562.0 541.6
-0.0215UNK N/A
280-184123-C-6-B 11/27/23 08:58:00 pm 506 2.58 1.0000
Replicates 489.0 515.6 499.1 518.6
-0.0231UNK N/A
280-184123-C-7-B 11/27/23 09:00:33 pm 549 3.26 1.0000
Replicates 534.1 571.3 549.8 540.5
-0.0213UNK N/A
280-184123-C-8-B 11/27/23 09:03:04 pm 451 3.25 1.0000
Replicates 429.2 443.4 456.0 475.0
-0.0254UNK N/A
280-184208-C-3-A 11/27/23 09:05:36 pm 461 2.04 1.0000
Replicates 469.3 443.3 467.1 464.1
-0.0250UNK N/A
280-184208-C-4-B 11/27/23 09:08:08 pm 468 2.87 1.0000
Replicates 475.4 457.0 451.4 487.5
-0.0247UNK N/A
280-184208-C-5-B 11/27/23 09:10:40 pm 447 1.99 1.0000
Replicates 433.6 441.4 453.4 460.3
-0.0256UNK N/A
280-184208-C-6-A 11/27/23 09:13:13 pm 400 3.46 1.0000
Replicates 369.2 411.4 400.1 420.7
-0.0276UNK N/A
280-184208-C-7-A 11/27/23 09:15:45 pm 466 2.42 1.0000
Replicates 456.3 479.6 451.6 476.6
-0.0248UNK N/A
CCV 280-635180/12-A 11/27/23 09:18:18 pm 73789 1.29 1.0000
Replicates 72598.4 73561.5 74214.8 74780.8
3.0975CCV 103.25
CCB 280-635180/13-A 11/27/23 09:20:50 pm 504 4.04 1.0000
Replicates 478.1 531.7 506.7 500.8
-0.0232CCB N/A
11/28/2023 11:26:29 AM Page 4112723-36C.wszf of 9
Page 1162 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
MB 280-635173/1-A 11/27/23 09:23:22 pm 512 3.02 1.0000
Replicates 505.6 518.5 493.2 530.7
-0.0228UNK N/A
LCS 280-635173/2-A 11/27/23 09:25:54 pm 74291 1.32 1.0000
Replicates 73050.6 74066.6 74769.5 75278.8
3.1189UNK N/A
280-184206-A-2-G 11/27/23 09:28:27 pm 516 3.65 1.0000
Replicates 542.0 519.4 506.6 497.1
-0.0227UNK N/A
280-184206-A-2-G SD@5 11/27/23 09:30:59 pm 540 1.74 1.0000
Replicates 530.2 544.9 535.7 549.7
-0.0216UNK N/A
280-184206-A-2-H MS 11/27/23 09:33:31 pm 72657 1.29 1.0000
Replicates 71475.7 72438.7 73095.0 73618.3
3.0493UNK N/A
280-184206-A-2-I MSD 11/27/23 09:36:03 pm 74287 1.19 1.0000
Replicates 73181.2 74067.7 74701.3 75198.3
3.1188UNK N/A
280-184206-A-4-B 11/27/23 09:38:36 pm 526 3.09 1.0000
Replicates 509.6 531.9 515.6 545.3
-0.0223UNK N/A
280-184488-B-5-B 11/27/23 09:41:09 pm 425 1.33 1.0000
Replicates 413.6 424.0 428.8 432.8
-0.0266UNK N/A
280-184488-A-6-B 11/27/23 09:43:41 pm 1079 60.31 1.0000
Replicates 1068.0 1059.5 1099.4 1090.7
0.0013UNK N/A
280-184213-D-1-E 11/27/23 09:46:14 pm 417 1.89 1.0000
Replicates 414.0 419.3 403.0 431.6
-0.0269UNK N/A
CCV 280-635180/12-A 11/27/23 09:48:48 pm 75524 1.22 1.0000
Replicates 74382.4 75271.0 75939.3 76502.1
3.1714CCV 105.71
CCB 280-635180/13-A 11/27/23 09:51:20 pm 508 2.94 1.0000
Replicates 496.8 513.8 527.5 493.3
-0.0230CCB N/A
280-184213-D-3-B 11/27/23 09:53:53 pm 370 2.54 1.0000
Replicates 368.4 394.2 361.9 354.5
-0.0289UNK N/A
280-184213-D-5-B 11/27/23 09:56:26 pm 383 2.60 1.0000
Replicates 368.7 387.3 405.8 370.7
-0.0283UNK N/A
280-184213-D-7-B 11/27/23 09:58:58 pm 475 1.77 1.0000
Replicates 471.4 477.1 488.3 464.3
-0.0244UNK N/A
280-184213-D-9-B 11/27/23 10:01:31 pm 373 3.12 1.0000
Replicates 365.1 364.1 403.7 357.2
-0.0288UNK N/A
280-184213-D-11-B 11/27/23 10:04:03 pm 386 1.85 1.0000
Replicates 369.3 390.9 384.1 397.9
-0.0282UNK N/A
280-184213-D-13-B 11/27/23 10:06:36 pm 449 0.77 1.0000
Replicates 453.6 447.0 443.4 451.7
-0.0255UNK N/A
280-184213-D-15-B 11/27/23 10:09:08 pm 335 0.57 1.0000
Replicates 331.8 337.9 338.1 330.3
-0.0304UNK N/A
11/28/2023 11:26:29 AM Page 5112723-36C.wszf of 9
Page 1163 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
280-184213-D-17-B 11/27/23 10:11:41 pm 422 1.87 1.0000
Replicates 421.8 417.2 437.5 409.9
-0.0267UNK N/A
280-184213-D-19-B 11/27/23 10:14:13 pm 570 3.47 1.0000
Replicates 576.4 567.5 548.5 587.8
-0.0204UNK N/A
280-184213-D-21-B 11/27/23 10:16:46 pm 396 2.29 1.0000
Replicates 415.6 380.1 397.8 390.6
-0.0278UNK N/A
CCV 280-635180/12-A 11/27/23 10:19:19 pm 75338 1.28 1.0000
Replicates 74134.7 75089.0 75790.4 76336.0
3.1635CCV 105.45
CCB 280-635180/13-A 11/27/23 10:21:51 pm 526 0.46 1.0000
Replicates 523.3 529.0 524.7 525.5
-0.0223CCB N/A
280-184213-D-24-B 11/27/23 10:24:23 pm 459 1.01 1.0000
Replicates 456.0 453.2 461.5 466.5
-0.0251UNK N/A
280-184213-D-26-B 11/27/23 10:26:56 pm 480 2.25 1.0000
Replicates 462.8 480.9 484.4 493.2
-0.0242UNK N/A
CCV 280-635180/12-A 11/27/23 10:29:29 pm 75492 1.30 1.0000
Replicates 74275.6 75236.7 75943.2 76513.9
3.1701CCV 105.67
CCB 280-635180/13-A 11/27/23 10:32:01 pm 532 3.48 1.0000
Replicates 512.1 522.6 549.6 545.3
-0.0220CCB N/A
MB 280-635177/1-A 11/27/23 10:34:34 pm 502 2.12 1.0000
Replicates 512.3 485.4 506.8 501.9
-0.0233UNK N/A
LCS 280-635177/2-A 11/27/23 10:37:06 pm 74084 1.31 1.0000
Replicates 72889.0 73813.5 74524.9 75109.2
3.1101UNK N/A
280-184230-D-1-B 11/27/23 10:39:39 pm 399 1.79 1.0000
Replicates 395.7 394.5 415.3 388.6
-0.0277UNK N/A
280-184230-D-1-B SD@5 11/27/23 10:42:11 pm 524 5.14 1.0000
Replicates 492.0 513.2 539.5 552.3
-0.0223UNK N/A
280-184230-D-1-C MS 11/27/23 10:44:44 pm 73829 1.23 1.0000
Replicates 72692.5 73605.4 74241.9 74778.0
3.0993UNK N/A
280-184230-D-1-D MSD 11/27/23 10:47:16 pm 72834 1.24 1.0000
Replicates 71700.3 72602.4 73267.4 73765.9
3.0569UNK N/A
280-184230-D-1-B PDS 11/27/23 10:49:49 pm 73247 1.31 1.0000
Replicates 72058.9 72990.5 73699.1 74240.8
3.0745UNK N/A
280-184230-D-2-B 11/27/23 10:52:21 pm 491 3.17 1.0000
Replicates 466.0 491.3 502.3 504.5
-0.0237UNK N/A
280-184230-D-3-B 11/27/23 10:54:54 pm 461 1.23 1.0000
Replicates 462.4 467.8 451.0 464.0
-0.0250UNK N/A
280-184230-D-4-B 11/27/23 10:57:27 pm 500 1.85 1.0000
Replicates 491.1 502.1 492.6 513.1
-0.0234UNK N/A
11/28/2023 11:26:29 AM Page 6112723-36C.wszf of 9
Page 1164 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
CCV 280-635180/12-A 11/27/23 11:00:00 pm 75704 1.25 1.0000
Replicates 74529.4 75444.4 76142.4 76697.9
3.1791CCV 105.97
CCB 280-635180/13-A 11/27/23 11:02:31 pm 548 2.94 1.0000
Replicates 569.0 536.4 547.4 539.4
-0.0213CCB N/A
280-184471-A-2-B 11/27/23 11:05:04 pm 497 3.92 1.0000
Replicates 491.9 496.9 525.6 473.4
-0.0235UNK N/A
280-184488-B-1-B 11/27/23 11:07:37 pm 519 3.17 1.0000
Replicates 519.3 518.2 498.0 539.2
-0.0226UNK N/A
280-184488-A-2-A 11/27/23 11:10:10 pm 588 4.28 1.0000
Replicates 564.9 602.2 577.5 606.0
-0.0196UNK N/A
280-184488-A-3-B 11/27/23 11:12:42 pm 503 1.71 1.0000
Replicates 493.7 497.1 514.6 505.0
-0.0232UNK N/A
280-184488-B-4-B 11/27/23 11:15:15 pm 509 3.53 1.0000
Replicates 486.0 500.8 521.0 527.7
-0.0230UNK N/A
CCV 280-635180/12-A 11/27/23 11:17:48 pm 75608 1.23 1.0000
Replicates 74450.3 75370.4 76045.5 76566.5
3.1750CCV 105.83
CCB 280-635180/13-A 11/27/23 11:20:20 pm 548 3.50 1.0000
Replicates 521.7 554.8 558.6 556.3
-0.0213CCB N/A
MB 280-634907/1-B 11/27/23 11:22:53 pm 512 3.12 1.0000
Replicates 509.9 490.3 519.8 529.5
-0.0228UNK N/A
LCS 280-634907/2-B 11/27/23 11:25:25 pm 72488 1.31 1.0000
Replicates 71295.7 72263.2 72932.4 73461.0
3.0422UNK N/A
280-184280-C-4-D 11/27/23 11:27:58 pm 452 2.42 1.0000
Replicates 432.2 450.4 465.9 457.9
-0.0254UNK N/A
280-184280-C-4-E MS 11/27/23 11:30:31 pm 72218 1.18 1.0000
Replicates 71127.4 72040.4 72627.4 73075.9
3.0306UNK N/A
280-184280-C-4-F MSD 11/27/23 11:33:04 pm 72934 1.26 1.0000
Replicates 71776.6 72725.7 73338.5 73896.8
3.0612UNK N/A
280-184280-C-7-E 11/27/23 11:35:37 pm 25556 1.55 1.0000
Replicates 25089.9 25436.1 25727.2 25971.6
1.0436UNK N/A
280-184280-C-10-E 11/27/23 11:38:09 pm 517 3.61 1.0000
Replicates 495.7 523.0 540.8 510.3
-0.0226UNK N/A
280-184280-C-11-E 11/27/23 11:40:42 pm 27578 1.44 1.0000
Replicates 27096.3 27484.6 27744.2 27987.9
1.1297UNK N/A
280-184280-C-12-E 11/27/23 11:43:15 pm 25859 1.38 1.0000
Replicates 25425.4 25761.9 26039.2 26211.2
1.0565UNK N/A
280-184280-C-13-E 11/27/23 11:45:48 pm 587 5.52 1.0000
Replicates 553.0 599.8 581.6 611.6
-0.0197UNK N/A
11/28/2023 11:26:29 AM Page 7112723-36C.wszf of 9
Page 1165 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
CCV 280-635180/12-A 11/27/23 11:48:21 pm 75545 1.31 1.0000
Replicates 74326.4 75269.4 75983.7 76601.9
3.1723CCV 105.74
CCB 280-635180/13-A 11/27/23 11:50:53 pm 561 0.99 1.0000
Replicates 564.5 563.6 553.8 560.6
-0.0208CCB N/A
280-184280-C-15-E 11/27/23 11:53:26 pm 492 3.85 1.0000
Replicates 462.8 490.4 513.7 499.2
-0.0237UNK N/A
280-184280-C-16-E 11/27/23 11:55:59 pm 491 2.06 1.0000
Replicates 483.9 505.9 480.6 494.9
-0.0237UNK N/A
CCV 280-635180/12-A 11/27/23 11:58:32 pm 75747 1.24 1.0000
Replicates 74580.9 75480.3 76217.0 76709.0
3.1809CCV 106.03
CCB 280-635180/13-A 11/28/23 12:01:04 am 558 0.82 1.0000
Replicates 561.0 552.8 557.3 561.5
-0.0209CCB N/A
LB 280-634317/1-G 11/28/23 12:03:37 am 533 3.12 1.0000
Replicates 536.6 551.7 513.0 529.4
-0.0220UNK N/A
LCS 280-634317/2-G 11/28/23 12:06:10 am 72914 1.40 1.0000
Replicates 71651.1 72637.3 73383.0 73983.3
3.0603UNK N/A
280-184475-A-2-C 11/28/23 12:08:43 am 428 0.94 1.0000
Replicates 431.7 426.8 433.1 420.1
-0.0264UNK N/A
280-184529-G-1-D 11/28/23 12:11:16 am 1067 148.59 1.0000
Replicates 1039.7 1049.2 1100.3 1079.2
0.0008UNK N/A
280-184529-F-2-D 11/28/23 12:13:49 am 928 11.34 1.0000
Replicates 921.3 912.9 937.2 942.1
-0.0051UNK N/A
280-184531-D-1-J 11/28/23 12:16:22 am 600 4.29 1.0000
Replicates 590.9 583.0 627.2 600.5
-0.0191UNK N/A
280-184591-G-1-D 11/28/23 12:18:55 am 452 3.15 1.0000
Replicates 452.3 453.6 427.4 473.3
-0.0254UNK N/A
280-184612-C-1-E 11/28/23 12:21:28 am 876 11.38 1.0000
Replicates 855.3 864.0 887.0 897.5
-0.0073UNK N/A
280-184613-C-1-G 11/28/23 12:24:01 am 1804 4.95 1.0000
Replicates 1762.0 1782.5 1829.2 1840.5
0.0322UNK N/A
280-184424-B-1-D 11/28/23 12:26:34 am 478 2.58 1.0000
Replicates 463.7 476.3 472.7 498.3
-0.0243UNK N/A
CCV 280-635180/12-A 11/28/23 12:29:08 am 75630 1.22 1.0000
Replicates 74465.1 75422.9 76042.6 76591.1
3.1760CCV 105.87
CCB 280-635180/13-A 11/28/23 12:31:40 am 579 3.53 1.0000
Replicates 558.8 595.3 589.6 573.1
-0.0200CCB N/A
280-184424-B-1-D SD@5 11/28/23 12:34:13 am 527 3.38 1.0000
Replicates 514.4 524.4 517.5 553.0
-0.0222UNK N/A
11/28/2023 11:26:29 AM Page 8112723-36C.wszf of 9
Page 1166 of 1261
Sample Name Type Date/Time Conc (ug/L) µAbs %RSD Flags DFResidual % Recovery
280-184424-B-1-E MS 11/28/23 12:36:46 am 71153 1.37 1.0000
Replicates 69926.6 70918.9 71604.4 72163.4
2.9853UNK N/A
280-184424-B-1-F MSD 11/28/23 12:39:19 am 70494 1.29 1.0000
Replicates 69358.9 70279.3 70897.8 71439.6
2.9572UNK N/A
280-184424-B-1-D PDS 11/28/23 12:41:52 am 73675 1.38 1.0000
Replicates 72404.1 73432.7 74133.7 74730.0
3.0927UNK N/A
CCV 280-635180/12-A 11/28/23 12:44:26 am 76028 1.36 1.0000
Replicates 74732.5 75770.3 76524.1 77084.3
3.1929CCV 106.43
CCB 280-635180/13-A 11/28/23 12:46:57 am 587 0.77 1.0000
Replicates 586.6 583.5 591.8 585.5
-0.0197CCB N/A
11/28/2023 11:26:29 AM Page 9112723-36C.wszf of 9
Page 1167 of 1261
GENERAL CHEMISTRY
Page 1168 of 1261
COVER PAGE
Lab Name: Job Number:
GENERAL CHEMISTRY
280-184424-1Eurofins Denver
SDG No.:
Client Sample ID Lab Sample ID
Project:Hill AFB, UT - ST071

280-184424-1 ST071-SoilIDW-11092023
Comments:
Page 1169 of 1261
COVER PAGE
Lab Name: Job Number:
GENERAL CHEMISTRY
280-184424-1Eurofins Savannah
SDG No.:
Client Sample ID Lab Sample ID
Project:Hill AFB, UT - ST071

280-184424-1 ST071-SoilIDW-11092023
Comments:
Page 1170 of 1261
1B-IN
INORGANIC ANALYSIS DATA SHEET
Client Sample ID:
Lab Name:Job No.:
Lab Sample ID: 280-184424-1
280-184424-1
ST071-SoilIDW-11092023
GENERAL CHEMISTRY
Eurofins Denver
SDG ID.:
Matrix:
Date Received:11/10/2023 16:30

Solid 11/09/2023 16:00Date Sampled:
Reporting Basis:DRY
% Solids:83.6
Analyte LOQ LOD Units C Q DIL MethodResultDL
mg/Kg U 1 9012B0.600.48Cyanide, Total 0.48 0.29
mg/Kg U 1 9034119.2Sulfide 9.2 4.9
FORM IB-IN Page 1171 of 1261
1B-IN
INORGANIC ANALYSIS DATA SHEET
Client Sample ID:
Lab Name:Job No.:
Lab Sample ID: 280-184424-1
280-184424-1
ST071-SoilIDW-11092023
GENERAL CHEMISTRY - SOLUBLE
Eurofins Denver
SDG ID.:
Matrix:
Date Received:11/10/2023 16:30

Solid 11/09/2023 16:00Date Sampled:
Reporting Basis:WET
Analyte LOQ LOD Units C Q DIL MethodResultDL
SU HF 1 9045D0.19.2pH adj. to 25 deg C 0.1 0.1
Degrees
C
HF 1 9045D1.022.3Temperature 1.0 1.0
FORM IB-IN Page 1172 of 1261
1B-IN
INORGANIC ANALYSIS DATA SHEET
Client Sample ID:
Lab Name:Job No.:
Lab Sample ID: 280-184424-1
280-184424-1
ST071-SoilIDW-11092023
GENERAL CHEMISTRY
Eurofins Savannah
SDG ID.:
Matrix:
Date Received:11/10/2023 16:30

Solid 11/09/2023 16:00Date Sampled:
Reporting Basis:WET
Analyte LOQ LOD Units C Q DIL MethodResultDL
mm/sec 1 1030NBIgnitability2.20
FORM IB-IN Page 1173 of 1261
2-IN
Lab Name:Job No.:280-184424-1
CALIBRATION QUALITY CONTROL
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Analyst:MMP Batch Start Date:11/15/2023
Reporting Units:mg/L Analytical Batch No.:634302
Sample
Number
QC
Type Time Analyte Result Spike
Amount
(%)
Recovery Limits Qual Reagent
ICV 17:24 Cyanide, Total 0.100 0.100 100 90-110 CN ICV Int_00861 9
ICB 17:26 Cyanide, Total 0.010 U 10
CCV 18:00 Cyanide, Total 0.201 0.200 101 90-110 CN CAL 1 ppm_02258 22
CCB 18:02 Cyanide, Total 0.010 U 23
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1174 of 1261
2-IN
Lab Name:Job No.:280-184424-1
CALIBRATION QUALITY CONTROL
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Analyst:LL Batch Start Date:12/03/2023
Reporting Units:Degrees C Analytical Batch No.:635901
Sample
Number
QC
Type Time Analyte Result Spike
Amount
(%)
Recovery Limits Qual Reagent
ICV 22:25 Temperature 21.9 1
CCV 22:25 Temperature 22.1 15
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1175 of 1261
2-IN
Lab Name:Job No.:280-184424-1
CALIBRATION QUALITY CONTROL
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Analyst:LL Batch Start Date:12/03/2023
Reporting Units:SU Analytical Batch No.:635901
Sample
Number
QC
Type Time Analyte Result Spike
Amount
(%)
Recovery Limits Qual Reagent
ICV 22:25 pH adj. to 25 deg C 7.0 7.00 100 97-102 pH 7.0
Buffer_00331
1
CCV 22:25 pH adj. to 25 deg C 7.0 7.00 100 97-102 pH 7.0
Buffer_00328
15
FORM II-IN
Note! Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1176 of 1261
Lab Name:Job No.:
3-IN
280-184424-1Eurofins Denver
METHOD BLANK
GENERAL CHEMISTRY
SDG No.:
Method Analyte Result Qual Dil

Lab Sample ID Units LOQ
Batch ID: 634302 Date:11/15/2023 17:42 633831 Date:11/14/2023 11:47Prep Batch:
0.40MB 280-633831/4-A U 10.50mg/KgCyanide, Total9012B
Batch ID: 633717 Date:11/13/2023 15:18 633716 Date:11/13/2023 15:10Prep Batch:
7.9MB 280-633716/3-A U 19.9mg/KgSulfide9034
FORM III-IN
Page 1177 of 1261
Lab Name:Job No.:
3-IN
280-184424-1Eurofins Savannah
METHOD BLANK
GENERAL CHEMISTRY
SDG No.:
Method Analyte Result Qual Dil

Lab Sample ID Units LOQ
Batch ID: 808190 Date:11/14/2023 14:20
NBMB 680-808190/1 1mm/secIgnitability1030
FORM III-IN
Page 1178 of 1261
Lab Name:Job No.:280-184424-1
5-IN
MATRIX SPIKE SAMPLE RECOVERY
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Matrix:
Analyte

Method Lab Sample ID Result Unit Spike
Amount
Pct.
Rec.LimitsC RPD RPD
Limit Q
Solid
Batch ID: 634302 Date:11/15/2023 17:46 Prep Batch: 633831 Date:11/14/2023 11:47
Cyanide, Total9012B mg/Kg0.48280-184424-1 U
9012B 280-184424-1
MS
Cyanide, Total 5.33 mg/Kg 5.96 76-12089
FORM V-IN
Note - Results and Reporting Limits have been adjusted for dry weight.
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1179 of 1261
Lab Name:Job No.:280-184424-1
5-IN
MATRIX SPIKE DUPLICATE SAMPLE RECOVERY
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Matrix:
Analyte

Method Lab Sample ID Result Unit Spike
Amount
Pct.
Rec.LimitsC RPD RPD
Limit Q
Solid
Batch ID: 634302 Date:11/15/2023 17:48 Prep Batch: 633831 Date:11/14/2023 11:47
9012B 280-184424-1
MSD
Cyanide, Total 5.03 mg/Kg 5.97 84 76-120 6 10
FORM V-IN
Note - Results and Reporting Limits have been adjusted for dry weight.
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1180 of 1261
6-IN
Lab Name:Job No.:280-184424-1Eurofins Denver
DUPLICATE
GENERAL CHEMISTRY
SDG No.:
Matrix:
Analyte RPD QualMethod

Client
Sample ID
Lab
Sample ID Result Unit RPD
Limit
Solid
Batch ID: 635901 Date:12/03/2023 22:25
9045D ST071-SoilIDW-1109
2023
pH adj. to 25 deg C SU9.2280-184424-1
pH adj. to 25 deg C 9.3 0.49045DST071-SoilIDW-1109
2023
280-184424-1 DU SU 5
9045D ST071-SoilIDW-1109
2023
Temperature Degree
s C
22.3280-184424-1
Temperature 22.3 09045DST071-SoilIDW-1109
2023
280-184424-1 DU Degree
s C
5
Calculations are performed before rounding to avoid round-off errors in calculated results.
FORM VI-IN
Page 1181 of 1261
7A-IN
Job No.:280-184424-1
LAB CONTROL SAMPLE
GENERAL CHEMISTRY
Lab Name:Eurofins Denver
SDG No.:
QRPD
LimitRPDLimitsPct.
Rec.
Spike
AmountUnitCResultAnalyteLab Sample IDMethod
Matrix:Solid
Batch ID: 634302 Date:11/15/2023 17:40 633831 Date:11/14/2023 11:47Prep Batch:
LCS Source:CN ICV Int_00861
5.00 859012BLCS
280-633831/3-
A
Cyanide, Total 4.27 mg/Kg 76-120
Batch ID: 633717 Date:11/13/2023 15:18 633716 Date:11/13/2023 15:10Prep Batch:
LCS Source:SFD ICV INT_02379
82.2 87 359034LCS
280-633716/1-
A
Sulfide 71.9 mg/Kg 35-119 7
Batch ID: 635901 Date:12/03/2023 22:25
LCS Source:pH 7.0 Buffer_00328
7.00 1009045DLCS
280-635901/4
pH adj. to 25 deg C 7.0 SU 99-101
FORM VIIA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1182 of 1261
7A-IN
Job No.:280-184424-1
LAB CONTROL SAMPLE DUPLICATE
GENERAL CHEMISTRY
Lab Name:Eurofins Denver
SDG No.:
QRPD
LimitRPDLimitsPct.
Rec.
Spike
AmountUnitCResultAnalyteLab Sample IDMethod
Matrix:Solid
Batch ID: 633717 Date:11/13/2023 15:18 633716 Date:11/13/2023 15:10Prep Batch:
LCSD Source:SFD ICV INT_02379
81.6 83 359034LCSD
280-633716/2-
A
Sulfide 67.3 mg/Kg 35-119 7
FORM VIIA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1183 of 1261
7A-IN
Job No.:280-184424-1
LOW LEVEL CONTROL SAMPLE
GENERAL CHEMISTRY
Lab Name:Eurofins Denver
SDG No.:
QRPD
LimitRPDLimitsPct.
Rec.
Spike
AmountUnitCResultAnalyteLab Sample IDMethod
Matrix:Solid
Batch ID: 634302 Date:11/15/2023 17:38 633831 Date:11/14/2023 11:47Prep Batch:
LCS Source:CN 10ppm_00683
5.00 939012BLLCS
280-633831/2-
A
Cyanide, Total 4.65 mg/Kg 51-150
FORM VIIA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1184 of 1261
7A-IN
Job No.:280-184424-1
HIGH LEVEL CONTROL SAMPLE
GENERAL CHEMISTRY
Lab Name:Eurofins Denver
SDG No.:
QRPD
LimitRPDLimitsPct.
Rec.
Spike
AmountUnitCResultAnalyteLab Sample IDMethod
Matrix:Solid
Batch ID: 634302 Date:11/15/2023 17:36 633831 Date:11/14/2023 11:47Prep Batch:
LCS Source:CN 10ppm_00683
17.5 979012BHLCS
280-633831/1-
A
Cyanide, Total 17.0 mg/Kg 90-110
FORM VIIA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1185 of 1261
7A-IN
Job No.:280-184424-1
LAB CONTROL SAMPLE
GENERAL CHEMISTRY
Lab Name:Eurofins Savannah
SDG No.:
QRPD
LimitRPDLimitsPct.
Rec.
Spike
AmountUnitCResultAnalyteLab Sample IDMethod
Matrix:Solid
Batch ID: 808190 Date:11/14/2023 14:20
LCS Source:Wood Chips_00007
2.68 100 101030LCS
680-808190/2
Ignitability 2.681 mm/sec 75-125 3
FORM VIIA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1186 of 1261
7A-IN
Job No.:280-184424-1
LAB CONTROL SAMPLE DUPLICATE
GENERAL CHEMISTRY
Lab Name:Eurofins Savannah
SDG No.:
QRPD
LimitRPDLimitsPct.
Rec.
Spike
AmountUnitCResultAnalyteLab Sample IDMethod
Matrix:Solid
Batch ID: 808190 Date:11/14/2023 14:20
LCSD Source:Wood Chips_00007
2.61 100 101030LCSD
680-808190/14
Ignitability 2.609 mm/sec 75-125 3
FORM VIIA-IN
Calculations are performed before rounding to avoid round-off errors in calculated results.
Page 1187 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:WC_OI 3700SolidMatrix:
02/03/2019 00:00Method:9012B DL Date:
9012BPrep Method:
Analyte Wavelength/
Mass
LOQ DL
(mg/Kg)(mg/Kg)
Cyanide, Total 0.2440.5
FORM IX - IN
Page 1188 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY
Eurofins Denver
CALIBRATION BLANK DETECTION LIMITS
SDG Number:
Instrument ID:WC_OI 3700SolidMatrix:
9012B XMDL Date:02/03/2019 00:00Method:
Analyte Wavelength/
Mass
XRL XMDL
(mg/L)(mg/L)
Cyanide, Total 0.0050.01
FORM IX - IN
Page 1189 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
04/15/2022 13:19Method:9034 DL Date:
9030BPrep Method:
Analyte Wavelength/
Mass
LOQ DL
(mg/Kg)(mg/Kg)
Sulfide 4.310
FORM IX - IN
Page 1190 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY
Eurofins Denver
CALIBRATION BLANK DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
9034 XMDL Date:11/28/2016 11:01Method:
Analyte Wavelength/
Mass
XRL XMDL
(mg/L)(mg/L)
Sulfide 0.794
FORM IX - IN
Page 1191 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY - SOLUBLE
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
9045D LOQ Date:11/01/2009 00:00Method:
DI LeachLeach Method:
Analyte Wavelength/
Mass
LOQ
(Degrees C)
Temperature 1
FORM IX - IN
Page 1192 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY - SOLUBLE
Eurofins Denver
CALIBRATION BLANK DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
9045D XRL Date:12/07/2009 19:08Method:
Analyte Wavelength/
Mass
XRL
(Degrees C)
Temperature 1
FORM IX - IN
Page 1193 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY - SOLUBLE
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
9045D LOQ Date:11/01/2009 00:00Method:
DI LeachLeach Method:
Analyte Wavelength/
Mass
LOQ
(SU)
pH adj. to 25 deg C 0.1
FORM IX - IN
Page 1194 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY - SOLUBLE
Eurofins Denver
CALIBRATION BLANK DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
9045D XRL Date:12/07/2009 19:08Method:
Analyte Wavelength/
Mass
XRL
(SU)
pH adj. to 25 deg C 0.1
FORM IX - IN
Page 1195 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY
Eurofins Denver
DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
D 2216 LOQ Date:11/01/2009 00:00Method:
Analyte Wavelength/
Mass
LOQ
(%)
Percent Moisture 0.1
Percent Solids 0.1
FORM IX - IN
Page 1196 of 1261
9-IN
280-184424-1Job Number:Lab Name:
GENERAL CHEMISTRY
Eurofins Savannah
DETECTION LIMITS
SDG Number:
Instrument ID:NOEQUIPSolidMatrix:
01/01/2016 15:07Method:1030 DL Date:
Analyte Wavelength/
Mass
LOQ DL
(mm/sec)(mm/sec)
Ignitability 2.22.2
FORM IX - IN
Page 1197 of 1261
12-IN
PREPARATION LOG
Lab Name:Job No.:280-184424-1
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Prep Method:9012B
Lab
Sample
ID
Preparation
Date
Initial
Weight
Final
Volume
Prep
Batch
Initial
Volume
(g)(mL)
11/14/2023 11:47 633831HLCS 280-633831/1-A 501
11/14/2023 11:47 633831LLCS 280-633831/2-A 501
11/14/2023 11:47 633831LCS 280-633831/3-A 501
11/14/2023 11:47 633831MB 280-633831/4-A 501
11/14/2023 11:47 633831280-184424-1 501.0036
11/14/2023 11:47 633831280-184424-1 MS 501.0028
11/14/2023 11:47 633831280-184424-1 MSD 501.0021
FORM XII-IN
Page 1198 of 1261
12-IN
PREPARATION LOG
Lab Name:Job No.:280-184424-1
GENERAL CHEMISTRY
Eurofins Denver
SDG No.:
Prep Method:9030B
Lab
Sample
ID
Preparation
Date
Initial
Weight
Final
Volume
Prep
Batch
Initial
Volume
(g)(mL)
11/13/2023 15:10 633716LCS 280-633716/1-A 5010.02
11/13/2023 15:10 633716LCSD 280-633716/2-A 5010.10
11/13/2023 15:10 633716MB 280-633716/3-A 5010.07
11/13/2023 15:10 633716280-184424-1 5010.41
FORM XII-IN
Page 1199 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
GENERAL CHEMISTRY
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/15/2023 17:00 11/15/2023 18:18
WC_OI 3700 9012B
Analytes
TimeD/FLab Sample Id
C
N
T
y
p
e
17:00ZZZZZZ
17:06ZZZZZZ
17:08ZZZZZZ
17:10ZZZZZZ
17:12ZZZZZZ
17:14ZZZZZZ
17:16ZZZZZZ
17:18ZZZZZZ
X17:241ICV 280-634302/9
X17:261ICB 280-634302/10
17:28ZZZZZZ
X17:361HLCS 280-633831/1-A T
X17:381LLCS 280-633831/2-A T
X17:401LCS 280-633831/3-A T
X17:421MB 280-633831/4-A T
X17:441280-184424-1 T
X17:461280-184424-1 MS T
X17:481280-184424-1 MSD T
17:50ZZZZZZ
17:52ZZZZZZ
17:54ZZZZZZ
X18:001CCV 280-634302/22
X18:021CCB 280-634302/23
18:08ZZZZZZ
18:10ZZZZZZ
18:16CCV 280-634302/26
18:18CCB 280-634302/27
Prep Types:
Total/NAT=
FORM XIII-IN
Page 1200 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
GENERAL CHEMISTRY
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/13/2023 15:18 11/13/2023 15:18
NOEQUIP 9034
Analytes
TimeD/FLab Sample Id
S
2
T
y
p
e
X15:181LCS 280-633716/1-A T
X15:181LCSD 280-633716/2-A T
X15:181MB 280-633716/3-A T
15:18ZZZZZZ
15:18ZZZZZZ
15:18ZZZZZZ
15:18ZZZZZZ
15:18ZZZZZZ
X15:181280-184424-1 T
15:18ZZZZZZ
15:18ZZZZZZ
15:18ZZZZZZ
15:18ZZZZZZ
15:18ZZZZZZ
Prep Types:
Total/NAT=
FORM XIII-IN
Page 1201 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
GENERAL CHEMISTRY
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:12/03/2023 22:25 12/03/2023 22:25
NOEQUIP 9045D
Analytes
TimeD/FLab Sample Id
p
H
T
e
m
p
T
y
p
e
X X22:251ICV 280-635901/1
22:25ZZZZZZ
22:25ZZZZZZ
X X22:251LCS 280-635901/4 T
X X22:251280-184424-1 S
X X22:251280-184424-1 DU S
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
X X22:251CCV 280-635901/15
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25ZZZZZZ
22:25CCV 280-635901/25
22:25ZZZZZZ
Prep Types:
SolubleS=
Total/NAT=
FORM XIII-IN
Page 1202 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
GENERAL CHEMISTRY
Job No.:280-184424-1Eurofins Denver
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/16/2023 13:37 11/16/2023 13:49
NOEQUIP D 2216
Analytes
TimeD/FLab Sample Id
%
S
o
l
M
o
i
s
t
T
y
p
e
13:37ZZZZZZ
13:37ZZZZZZ
13:49ZZZZZZ
X X13:491280-184424-1 T
13:49ZZZZZZ
13:49ZZZZZZ
13:49ZZZZZZ
Prep Types:
Total/NAT=
FORM XIII-IN
Page 1203 of 1261
Lab Name:
13-IN
ANALYSIS RUN LOG
GENERAL CHEMISTRY
Job No.:280-184424-1Eurofins Savannah
SDG No.:
Instrument ID:Analysis Method:
Start Date:End Date:11/14/2023 14:20 11/14/2023 14:20
NOEQUIP 1030
Analytes
TimeD/FLab Sample Id
I
g
n
T
y
p
e
X14:201MB 680-808190/1 T
X14:201LCS 680-808190/2 T
14:20ZZZZZZ
14:20ZZZZZZ
14:20ZZZZZZ
14:20ZZZZZZ
14:20ZZZZZZ
14:20ZZZZZZ
14:20ZZZZZZ
X14:201280-184424-1 T
14:20ZZZZZZ
14:20ZZZZZZ
14:20ZZZZZZ
X14:201LCSD 680-808190/14 T
Prep Types:
Total/NAT=
FORM XIII-IN
Page 1204 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Rittenhouse, Ben C11/14/23 11:47633831
Batch Method:
Eurofins Denver
9012B
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount NO3Screen NO3TreatVol DigestBlockID DigestBlockPos
1 g 50 mL MgCl 2 mL 41260 19012B, 9012BHLCS
280-633831/1
1 g 50 mL MgCl 2 mL 41260 29012B, 9012BLLCS
280-633831/2
1 g 50 mL MgCl 2 mL 41260 39012B, 9012BLCS
280-633831/3
1 g 50 mL MgCl 2 mL 41260 49012B, 9012BMB 280-633831/4
ST071-SoilIDW-11
092023
1.0036 g 50 mL MgCl 2 mL 41260 59012B, 9012B T280-184424-D-1
ST071-SoilIDW-11
092023
1.0028 g 50 mL MgCl 2 mL 41260 69012B, 9012B T280-184424-D-1
MS
ST071-SoilIDW-11
092023
1.0021 g 50 mL MgCl 2 mL 41260 19012B, 9012B T280-184424-D-1
MSD
Lab Sample ID Client Sample ID Method Chain Basis RefluxStartTime RefluxEndTime RefluxTime CN 10ppm 00683 CN ICV Int
00861
11/14/2023
13:23
11/14/2023
14:53
90 min 1.75 mL9012B, 9012BHLCS
280-633831/1
11/14/2023
13:23
11/14/2023
14:53
90 min 0.5 mL9012B, 9012BLLCS
280-633831/2
11/14/2023
13:23
11/14/2023
14:53
90 min 0.5 mL9012B, 9012BLCS
280-633831/3
11/14/2023
13:23
11/14/2023
14:53
90 min9012B, 9012BMB 280-633831/4
ST071-SoilIDW-11
092023
11/14/2023
13:23
11/14/2023
14:53
90 min9012B, 9012B T280-184424-D-1
ST071-SoilIDW-11
092023
11/14/2023
13:23
11/14/2023
14:53
90 min 0.5 mL9012B, 9012B T280-184424-D-1
MS
ST071-SoilIDW-11
092023
11/14/2023
15:17
11/14/2023
16:17
60 min 0.5 mL9012B, 9012B T280-184424-D-1
MSD
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 29012B
Page 1205 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Rittenhouse, Ben C11/14/23 11:47633831
Batch Method:
Eurofins Denver
9012B
Batch Notes
Balance ID M19170
Balance is Level? (Y/N)yes
Pipette/Syringe/Dispenser ID 5000 IX, 1000 HEX, 200 BWH
Sodium Hydroxide ID 2% NaOH_00441
Magnesium Chloride Reagent ID Number CN Mag Chl_00126
Sulfamic Acid ID CN SULFAMIC_00146
Sulfuric Acid Reagent ID Number SulfuricAcid_00294
Distillation Start Time 11/14/2023 13:23
Distillation End Time 11/14/2023 16:17
pH Paper ID HC210330
Batch Comment BCR
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 29012B
Page 1206 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Peterson, McKenzy M11/15/23 17:00634302
Batch Method:
Eurofins Denver
9012B
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount CN CAL 1 ppm
02258
CN ICV Int
00861
100 mL 100 mL 1 mL9012BICV
280-634302/9
50 mL 50 mL9012BICB
280-634302/10
50 mL 50 mL9012BHLCS
280-633831/1-A
50 mL 50 mL9012BLLCS
280-633831/2-A
50 mL 50 mL9012BLCS
280-633831/3-A
50 mL 50 mL9012BMB
280-633831/4-A
ST071-SoilIDW-11
092023
50 mL 50 mL9012BT280-184424-D-1-
B
ST071-SoilIDW-11
092023
50 mL 50 mL9012BT280-184424-D-1-
C MS
ST071-SoilIDW-11
092023
50 mL 50 mL9012BT280-184424-D-1-
D MSD
50 mL 50 mL 10 mL9012BCCV
280-634302/22
50 mL 50 mL9012BCCB
280-634302/23
Batch Notes
Pipette/Syringe/Dispenser ID MMP 5000, 1000 HEX, BWH 200
Sodium Hydroxide ID NaOH 1%_00582
Buffer Reagent ID CN Buffer_00225
Chloramine-T ID CN CHLOR-T_01575
Pyridine-Barbituric Acid ID CN PYR/BARB_00246
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 19012B
Page 1207 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Hohulin, Sierra A11/13/23 15:10633716
Batch Method:
Eurofins Denver
9030B
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount DistillUnitPort Initial pH Final pH AcidVolAdded
10.02 g 50 mL 1 7 SU <2 SU 5 mL9030B, 9034LCS
280-633716/1
10.10 g 50 mL 2 7 SU <2 SU 5 mL9030B, 9034LCSD
280-633716/2
10.07 g 50 mL 3 7 SU <2 SU 5 mL9030B, 9034MB 280-633716/3
ST071-SoilIDW-11
092023
10.41 g 50 mL 9 >12 SU <2 SU 5 mL9030B, 9034 T280-184424-D-1
Lab Sample ID Client Sample ID Method Chain Basis SFD ICV INT
02379
1 mL9030B, 9034LCS
280-633716/1
1 mL9030B, 9034LCSD
280-633716/2
9030B, 9034MB 280-633716/3
ST071-SoilIDW-11
092023
9030B, 9034 T280-184424-D-1
Batch Notes
Formaldehyde ID Form_00125
Zinc Acetate Buffer ID znac_00131
Pipette/Syringe/Dispenser ID CAI 5000
Sulfuric Acid Reagent ID Number SulfuricAcid_00288
Balance ID M19170
Balance is Level? (Y/N)yes
pH Indicator ID HC312502
Oven, Bath or Block Temperature 1 80 Degrees C
Distillation Start Time 11/13/2023 12:15
Uncorrected Temperature 2 80 Degrees C
Oven, Bath or Block Temperature 2 80 Degrees C
Distillation End Time 11/13/2023 13:45
Batch Comment SAH
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 29034
Page 1208 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Hohulin, Sierra A11/13/23 15:10633716
Batch Method:
Eurofins Denver
9030B
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 29034
Page 1209 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Hohulin, Sierra A
11/13/23 16:50
11/13/23 15:20633717
Batch Method:
Eurofins Denver
9034
Lab Sample ID Client Sample ID Method Chain Basis BuretStart1 BuretStop1 IodineAmount TitrantVolume1 FinalAmount
0 mL 3.2 mL 1.25 mL 3.2 mL 50 mL9034LCS
280-633716/1-A
3.2 mL 6.5 mL 1.25 mL 3.3 mL 50 mL9034LCSD
280-633716/2-A
6.5 mL 7.5 mL 0.25 mL 1 mL 50 mL9034MB
280-633716/3-A
ST071-SoilIDW-11
092023
16.8 mL 17.8 mL 0.25 mL 1 mL 50 mL9034T280-184424-D-1-
A
Batch Notes
Normality of First Titrant 0.025 N
Normality of Iodine Solution 0.1 N
Zinc Acetate Buffer ID znac_00131
Iodine ID Iod_00279
Hydrochloric Acid ID HCL Sol_00209
Sodium Thiosulfate ID Na Thio_00185
Starch Reagent ID Starch Ind_00072
Pipette/Syringe/Dispenser ID CAI 5000
Batch Comment SAH
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 19034
Page 1210 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Luce, Luke12/02/23 19:50635889
Batch Method:
Eurofins Denver
DI Leach
Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount
ST071-SoilIDW-11
092023
40.02 g 40 mLDI Leach,
9045D
S280-184424-D-1
ST071-SoilIDW-11
092023
40.02 g 40 mLDI Leach,
9045D
S280-184424-D-1
DU
Batch Notes
Balance ID 24750836
Balance is Level? (Y/N)yes
Tumble Start Time 12/03/2023 21:00
Tumble End Time 12/03/2023 21:10
Batch Comment LL
Basis Basis Description
S Soluble
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 19045D
Page 1211 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Luce, Luke12/03/23 22:25635901
Batch Method:
Eurofins Denver
9045D
Lab Sample ID Client Sample ID Method Chain Basis pH 7.0 Buffer
00328
pH 7.0 Buffer
00331
30 mL9045DICV
280-635901/1
30 mL9045DLCS
280-635901/4
30 mL9045DCCV
280-635901/15
Batch Notes
pH Meter ID pH Meter 1
Probe ID SV1-16261
Thermometer ID pH probe 1
pH Buffer 1 ID pH 2.0 buffer_00102
pH Buffer 2 ID pH 4.0 buffer_00213
pH Buffer 3 ID pH 7.0 buffer_00328
pH Buffer 4 ID pH 10 buffer_00164
pH Buffer 5 ID pH 12 buffer_00184
pH Buffer 6 ID pH 7.0 buffer_00331
pH Meter Calibration Slope See attached
Calibration Date and Time 12/03/2023 22:27
Balance is Level? (Y/N)Y
Sufficient volume for sample dup Yes
Blank Matrix ID lot 2BD0138
Batch Comment LL
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 19045D
Page 1212 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Peterson, McKenzy M11/16/23 13:36634249
Batch Method:
Eurofins Denver
D 2216
Lab Sample ID Client Sample ID Method Chain Basis DISH#DishWeight SampleMassWet SampleMassDry %_Moisture %_Solid
ST071-SoilIDW-11
092023
4 0.97 g 14.50 g 12.28 g 16.407982261640
8 %
83.592017738359
2 %
D 2216 T280-184424-C-1
Batch Notes
Balance ID 24750836
Balance is Level? (Y/N)yes
Oven ID e
Thermometer ID 1354
Date samples were placed in the oven 11/16/2023
Time samples were place in the oven 13:42
Temperature - Start - Uncorrected 103 Degrees C
Oven Temp In 103 Degrees C
Date samples were removed from oven 11/17/2023
Time Samples were removed from oven 09:06
Analyst ID - Weighing wet: BCR dry:MMP
Temperature - End - Uncorrected 103 Degrees C
Oven Temp Out 103 Degrees C
Date and Time Samples in Desiccator 11/17/2023 09:06
Date and Time Samples out of Desiccator 11/17/2023 12:20
Batch Comment CN SOIL % M
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 1D 2216
Page 1213 of 1261
Lab Name:Job No.:
SDG No.:
GENERAL CHEMISTRY BATCH WORKSHEET
280-184424-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Mike-Thomas, Sarah
11/14/23 14:50
11/14/23 14:20808190
Batch Method:
Eurofins Savannah
1030
Lab Sample ID Client Sample ID Method Chain Basis FinalAmount UnCorSampTemp SampleTemp potting mix
00010
Wood Chips
00007
100 mL 14.7 Degrees C 14.7 Degrees C 100 mm1030MB 680-808190/1
100 mL 14.6 Degrees C 14.6 Degrees C 2.681 mm1030LCS
680-808190/2
ST071-SoilIDW-11
092023
100 mL 13.6 Degrees C 13.6 Degrees C1030T280-184424-E-1
100 mL 14.6 Degrees C 14.6 Degrees C 2.609 mm1030LCSD
680-808190/14
Batch Notes
Thermometer ID geir2
Hood ID GE HOOD 3
Fume Hood Air Velocity 0.97 m/s m/s
Air Flow Meter ID Anemometer 8
Flame Temp >1000C 1003 DEGREES C
Thermocouple ID thermocouple 6
Timer ID GE timer30
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 11030
Page 1214 of 1261
TestAmerica Calibration Spreadsheet, Work Instruction No. CA-Q-WI-13; dated 8/10/2011
335.4 11152023
Cyanide mmp
------------------------------Input Calibration Data--------------------------------------- --------------------------------------------- Relative Errors in X --------------------------------------------------------
Amount Response ISTD Amt ISTD Resp Response Average Linear (1/x2)Linear (1/X)Linear Forced Linear Quadratic
0.000 0.000 0.00000
10.000 1596.800 1596.80000 #DIV/0! #DIV/0!#DIV/0!6.73% 0.80% 2.28%
20.000 3089.200 3089.20000 #DIV/0! #DIV/0!#DIV/0!3.24% 0.50% 0.58%
50.000 7608.200 7608.20000 #DIV/0! #DIV/0!#DIV/0!1.70% 0.89% 0.31%
100.000 15031.000 15031.00000 #DIV/0! #DIV/0!#DIV/0!0.46% 0.28% -0.20%
200.000 29842.000 29842.00000 #DIV/0! #DIV/0!#DIV/0!-0.27% -0.13% 0.02%
400.000 59602.800 59602.80000 #DIV/0! #DIV/0!#DIV/0!-0.41% -0.11% 1.63%
0.00000
0.00000
0.00000
RSE in X:#DIV/0!#DIV/0!#DIV/0!3.4%0.7%1.7%
--------------------------------------------------Curve Fit Statistics--------------------------------------------------------------------- --------------------------------------------Sample Results-------------------------------------------------------------
1ST Degree 2ND Degree Sample 1 Sample 2 Sample 3 Sample 4 Sample 5
Constant Coefficient Coefficient X-Intercept r² r Instrum.Responses: 1,596.800 7,608.200
Weighted (1/Amt^2)IS Response:
Average #DIV/0!0 #DIV/0!#DIV/0!Avg RF Result:#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Linear #DIV/0!#DIV/0!#DIV/0!#DIV/0!#DIV/0!Linear(1/x2) Result:#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Weighted (1/Amt)
Linear #DIV/0!#DIV/0!#DIV/0!#DIV/0!#DIV/0!Linear(1/x) Result:#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Unweighted
Forced Zero 1.4962E+02 0 0.99998 0.99999 Linear Forced:10.673 50.851 0.000 0.000 0.000
Linear 9.5565E+01 1.4893E+02 -0.64 0.99999 1.00000 Linear Result:10.080 50.444 -0.642 -0.642 -0.642
Quadratic 5.0721E+01 1.5128E+02 -1.1761E-02 -0.34 0.99965 0.99983 Quad Result (no IS):10.228 50.153 -0.335 -0.335 -0.335
c b a Quad Result (with IS):
11/20/2023 3:47 PM
Page 1215 of 1261
FlowView - Result
InstrumentID: B918837629
Operator ID: BCR
Methodology: USEPA 335.4
File Version: 111
Created On: 11/15/2023 4:59:55 PM
Last Modified On: 11/15/2023 6:28:14 PM
Exported on 11/16/2023 12:23:23 PM
Date/Time Cup # Peak # Sample Name M-Dil Calc (ppb) Type Peak Response Avg Response Avg Calc (ppb)
11/15/2023 5:00:09 PM 910 1 Sync 1 390.3808 SYNC 60085.6 60085.6 390.3808
11/15/2023 5:02:09 PM 900 2 Baseline 1 -1.0236 RB 21.8
11/15/2023 5:04:09 PM 900 3 Baseline 1 -0.3953 RB 116.8 69.3 -0.7095
11/15/2023 5:06:09 PM 904 4 Cal Std 0 mg/L 1 0.0000 STD1 0.0 0.0 0.0000
11/15/2023 5:08:09 PM 905 5 Cal Std 0.01 mg/L 1 10.0000 STD2 1596.8 1596.8 10.0000
11/15/2023 5:10:09 PM 906 6 Cal Std 0.02 mg/L 1 20.0000 STD3 3089.2 3089.2 20.0000
11/15/2023 5:12:09 PM 907 7 Cal Std 0.05 mg/L 1 50.0000 STD4 7608.2 7608.2 50.0000
11/15/2023 5:14:09 PM 908 8 Cal Std 0.1 mg/L 1 100.0000 STD5 15031.0 15031.0 100.0000
11/15/2023 5:16:09 PM 909 9 Cal Std 0.2 mg/L 1 200.0000 STD6 29842.0 29842.0 200.0000
11/15/2023 5:18:09 PM 910 10 Cal Std 0.4 mg/L 1 400.0000 STD7 59602.8 59602.8 400.0000
11/15/2023 5:20:09 PM 900 11 Baseline 1 1.3149 RB 280.6
11/15/2023 5:22:09 PM 900 12 Baseline 1 1.4422 RB 299.6 290.1
11/15/2023 5:24:09 PM 903 13 ICV 1 100.2057 ICV 15034.2 15034.2 100.2057
11/15/2023 5:26:09 PM 904 14 ICB 1 0.2957 ICB 128.4 128.4 0.2957
11/15/2023 5:28:09 PM 900 15 Blank 1 -0.2802 SPL 42.4 42.4 -0.2802
11/15/2023 5:30:09 PM 900 16 Baseline 1 -0.1851 RB 56.6 56.6 -0.1851
11/15/2023 5:32:09 PM 900 17 Baseline 1 1.4783 RB 305.0
11/15/2023 5:34:09 PM 900 18 Baseline 1 1.3082 RB 279.6 292.3
11/15/2023 5:36:09 PM 101 19 HLCS 280-633831/1-A 1 340.4564 LCS 50762.6 50762.6 340.4564
11/15/2023 5:38:09 PM 102 20 LLCS 280-633831/2-A 1 92.9671 LCS 13955.2 13955.2 92.9671
11/15/2023 5:40:09 PM 103 21 LCS 280-633831/3-A 1 85.4236 LCS 12830.6 12830.6 85.4236
11/15/2023 5:42:09 PM 104 22 MB 280-633831/4-A 1 -0.2762 MB 43.0 43.0 -0.2762
11/15/2023 5:44:09 PM 105 23 280-184424-D-1-B 1 0.4444 SPL 150.6 150.6 0.4444
11/15/2023 5:46:09 PM 106 24 280-184424-D-1-C MS 1 89.3394 SPL 13414.4 13414.4 89.3394
C:\ProgramData\OI Analytical\FlowView\Database\Instrument_B918837629\Results\CN 11152023.RST
Printed on 2023/11/16 Page 1 of 3
Page 1216 of 1261
FlowView - Result
Date/Time Cup # Peak # Sample Name M-Dil Calc (ppb) Type Peak Response Avg Response Avg Calc (ppb)
11/15/2023 5:48:10 PM 107 25 280-184424-D-1-D MSD 1 84.3438 SPL 12669.6 12669.6 84.3438
11/15/2023 5:50:10 PM 108 26 280-183925-E-1-G 1 90.9721 SPL 13657.8 13657.8 90.9721
11/15/2023 5:52:10 PM 109 27 280-183925-C-2-F 1 106.4200 SPL 15960.4 15960.4 106.4200
11/15/2023 5:54:10 PM 110 28 280-183926-D-1-B 1 72.8732 SPL 10959.2 10959.2 72.8732
11/15/2023 5:56:10 PM 900 29 Baseline 1 1.1502 RB 256.0 256.0
11/15/2023 5:58:10 PM 900 30 Baseline 1 1.1221 RB 251.8 251.8
11/15/2023 6:00:10 PM 909 31 CCV 1 201.4461 CCV1 30109.8 30109.8 201.4461
11/15/2023 6:02:10 PM 904 32 CCB 1 -0.0619 CCB 75.0 75.0 -0.0619
11/15/2023 6:04:10 PM 900 33 Baseline 1 -0.5641 RB 0.0 0.0 -0.5641
11/15/2023 6:06:10 PM 900 34 Baseline 1 0.3520 RB 136.8 136.8 0.3520
11/15/2023 6:08:10 PM 111 35 280-184177-D-1-C 1 1.3431 SPL 284.8 284.8
11/15/2023 6:10:10 PM 112 36 280-184214-D-1-A 1 2.4118 SPL 444.4 444.4 2.4118
11/15/2023 6:12:10 PM 900 37 Baseline 1 0.1270 RB 103.2 103.2 0.1270
11/15/2023 6:14:10 PM 900 38 Baseline 1 -0.1904 RB 55.8 55.8 -0.1904
11/15/2023 6:16:10 PM 909 39 CCV 1 198.8744 CCV1 29727.2 29727.2 198.8744
11/15/2023 6:18:10 PM 904 40 CCB 1 -0.5320 CCB 4.8 4.8 -0.5320
11/15/2023 6:20:10 PM 900 41 Baseline 1 0.0895 RB 97.6 97.6 0.0895
11/15/2023 6:22:10 PM 900 42 Baseline 1 -0.0351 RB 79.0 79.0 -0.0351
Calibration Results - Channel2
Calibration Summary
Curve Fit: = Second Order
R²: = 0.99999457 a: = -1.408991E-003
RF: = n/a b: = 1.493339E+002
Offset: n/a c: 8.423900E+001
HLCAVG: 0.00000000 LHCAVG: 0.00000000
Calibration Details
Name Type Std Conc(ppb) Avg Height Calc Avg Conc(ppb) %RSD Flags Date/Time
Cal Std 0 mg/L STD1 0.0000 0.0 -0.5641 0.0 11/15/2023 5:06:09 PM
C:\ProgramData\OI Analytical\FlowView\Database\Instrument_B918837629\Results\CN 11152023.RST
Printed on 2023/11/16 Page 2 of 3
Page 1217 of 1261
FlowView - Result
Name Type Std Conc(ppb) Avg Height Calc Avg Conc(ppb) %RSD Flags Date/Time
Cal Std 0.01 mg/L STD2 10.0000 1596.8 10.1297 0.0 11/15/2023 5:08:09 PM
Cal Std 0.02 mg/L STD3 20.0000 3089.2 20.1263 0.0 11/15/2023 5:10:09 PM
Cal Std 0.05 mg/L STD4 50.0000 7608.2 50.4075 0.0 11/15/2023 5:12:09 PM
Cal Std 0.1 mg/L STD5 100.0000 15031.0 100.1842 0.0 11/15/2023 5:14:09 PM
Cal Std 0.2 mg/L STD6 200.0000 29842.0 199.6460 0.0 11/15/2023 5:16:09 PM
Cal Std 0.4 mg/L STD7 400.0000 59602.8 400.0704 0.0 11/15/2023 5:18:09 PM
C:\ProgramData\OI Analytical\FlowView\Database\Instrument_B918837629\Results\CN 11152023.RST
Printed on 2023/11/16 Page 3 of 3
Page 1218 of 1261
General Chemistry Raw Data Report
Job ID: 280-184424-1
Batch: 633717 Analyst Initials: SaH
Instrument: No Equipment Used for this TestMethod: 9034
Lab Sample ID: LCS 280-633716/1-A Analysis Date: Nov 13, 2023 15:18
Sulfide
Analyte Raw Result UnitDetector
14.4None mg/L
Dilution
1
Initial Final
Amount Amount
10.02 g 50 mL
Lab Sample ID: LCSD 280-633716/2-A Analysis Date: Nov 13, 2023 15:18
Sulfide
Analyte Raw Result UnitDetector
13.6None mg/L
Dilution
1
Initial Final
Amount Amount
10.10 g 50 mL
Lab Sample ID: MB 280-633716/3-A Analysis Date: Nov 13, 2023 15:18
Sulfide
Analyte Raw Result UnitDetector
0None mg/L
Dilution
1
Initial Final
Amount Amount
10.07 g 50 mL
Lab Sample ID: 280-184424-D-1-A Analysis Date: Nov 13, 2023 15:18
Sulfide
Analyte Raw Result UnitDetector
0None mg/L
Dilution
1
Initial Final
Amount Amount
10.41 g 50 mL
Eurofins Denver
Page 1219 of 1261
Analyst:
Date:Number:
INT_02477 Buret Buret mL Final Conc
9/26/2023 Start End Iodine mL mg/L
SLR CAL 5 0.00 9.90 5 9.90 808.000
804 CAL 5 9.90 19.90 5 10.00 800.000
12/26/2023
INT_02362 Buret Buret mL Final Conc
10/16/2023 Start End Iodine mL mg/L
SLR ICV 5 0.00 9.70 5 9.70 824.000
824 ICV 5 9.70 19.40 5 9.70 824.000
12/26/2023
Iodine
Titration Solutions
Solution 1:
slr
Source/Ver-Lot#:
Normality:
Iod_00279
TALS ID Na Thio_00185
Solution 2:
CAL
Volume
Calibration Information
Prep Date:
Made By:
Expiration Date:
Concentration:
Sulfide by Titration
0.025
Starch IND_00072TALS ID
Starch Indicator
Normality:
11/13/2023
SOP Information:
91
TALS ID
0.1
sodium thiosulfate
ICV Information
Source/Ver-Lot#:
Prep Date:
CAL
Volume
Made By:
Concentration:
Expiration Date:
DV-F-0061-3-22-2017-Rev 6 Sheet 1 of 1
G:\Wetchem\Wet Chemistry Methods\Sulfide\Standardization PDFs\9030 Excel spreadsheet Standardization\
9030&9034 standardizationPage 1220 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-150147-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
Page 1221 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-150571-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
7 410-150571-C-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L mg/Kg
Sulfide as H2S 0 mg/L mg/Kg
Page 1222 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-150572-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
8 410-150572-C-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L mg/Kg
Sulfide as H2S 0 mg/L mg/Kg
Page 1223 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184097-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 4.6 U mg/Kg
Sulfide 0 mg/L 4.3 U mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L 5.7 U mg/Kg
Sulfide 0.8 mg/L 5.3 U mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
10 280-184097-B-5-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L 5.4 U mg/Kg
Sulfide as H2S 0 mg/L 5.8 U mg/Kg
11 280-184097-A-6-B 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0.8 mg/L 5.7 U mg/Kg
Sulfide as H2S 0.85 mg/L 6.1 U mg/Kg
Page 1224 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184157-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 4.6 U mg/Kg
Sulfide 0 mg/L 4.3 U mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L 5.7 U mg/Kg
Sulfide 0.8 mg/L 5.3 U mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
12 280-184157-C-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L 5.6 U mg/Kg
Sulfide as H2S 0 mg/L 6.0 U mg/Kg
13 280-184157-E-2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L 5.6 U mg/Kg
Sulfide as H2S 0 mg/L 6.0 U mg/Kg
Page 1225 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184177-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
14 280-184177-D-1-B 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L mg/Kg
Sulfide as H2S 0 mg/L mg/Kg
Page 1226 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184424-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 8.4 U mg/Kg
Sulfide 0 mg/L 7.9 U mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L 10 U mg/Kg
Sulfide 0.8 mg/L 9.9 U mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 15.2 mg/L mg/Kg 92 35 119
Sulfide as H2S 16.15 mg/L mg/Kg
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Sulfide as H2S 14.45 mg/L mg/Kg
9 280-184424-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide 0 mg/L 9.2 U mg/Kg
Sulfide as H2S 0 mg/L 9.8 U mg/Kg
Page 1227 of 1261
TALS Raw Data Report
Page 1228 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-150147-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Page 1229 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-150571-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
7 410-150571-C-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
Page 1230 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-150572-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
8 410-150572-C-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
Page 1231 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184097-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 4.6 U mg/Kg
Sulfide 0 mg/L 4.3 U mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L 5.7 U mg/Kg
Sulfide 0.8 mg/L 5.3 U mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Page 1232 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184157-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 4.6 U mg/Kg
Sulfide 0 mg/L 4.3 U mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L 5.7 U mg/Kg
Sulfide 0.8 mg/L 5.3 U mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
Page 1233 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184177-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L mg/Kg
Sulfide 0.8 mg/L mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
14 280-184177-D-1-B 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L mg/Kg
Sulfide 0 mg/L mg/Kg
Page 1234 of 1261
TALS Raw Data Report
Eurofins Denver
633717
280-184424-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 LCS 280-633716/1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 15.3 mg/L mg/Kg
Sulfide 14.4 mg/L mg/Kg 87 35 119
2 LCSD 280-633716/2-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 7 35
3 MB 280-633716/3-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 8.4 U mg/Kg
Sulfide 0 mg/L 7.9 U mg/Kg
4 410-150147-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0.85 mg/L 10 U mg/Kg
Sulfide 0.8 mg/L 9.9 U mg/Kg
5 410-150147-D-1-B MS 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 16.15 mg/L mg/Kg
Sulfide 15.2 mg/L mg/Kg 92 35 119
6 410-150147-D-1-C MSD 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 14.45 mg/L mg/Kg
Sulfide 13.6 mg/L mg/Kg 83 35 119 14 35
9 280-184424-D-1-A 1.011/13/2023 3:18:43PM 9034Lab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Sulfide as H2S 0 mg/L 9.8 U mg/Kg
Sulfide 0 mg/L 9.2 U mg/Kg
Page 1235 of 1261
TALS Raw Data Report
Page 1236 of 1261
General Chemistry Raw Data Report
Job ID: 280-184424-1
Batch: 635901 Analyst Initials: LL
Instrument: No Equipment Used for this TestMethod: 9045D
Lab Sample ID: ICV 280-635901/1 Analysis Date: Dec 03, 2023 22:25
pH adj. to 25 deg C
Analyte Raw Result UnitDetector
7.00None SU
Dilution
1
Temperature None 21.9 Degrees C1
Lab Sample ID: LCS 280-635901/4 Analysis Date: Dec 03, 2023 22:25
pH adj. to 25 deg C
Analyte Raw Result UnitDetector
7.01None SU
Dilution
1
Temperature None 22.0 Degrees C1
Lab Sample ID: 280-184424-D-1-H Analysis Date: Dec 03, 2023 22:25
pH adj. to 25 deg C
Analyte Raw Result UnitDetector
9.24None SU
Dilution
1
Temperature None 22.3 Degrees C1
Lab Sample ID: 280-184424-D-1-I DU Analysis Date: Dec 03, 2023 22:25
pH adj. to 25 deg C
Analyte Raw Result UnitDetector
9.28None SU
Dilution
1
Temperature None 22.3 Degrees C1
Lab Sample ID: CCV 280-635901/15 Analysis Date: Dec 03, 2023 22:25
pH adj. to 25 deg C
Analyte Raw Result UnitDetector
7.03None SU
Dilution
1
Temperature None 22.1 Degrees C1
Eurofins Denver
Page 1237 of 1261
Page 1238 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184424-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C Degrees C
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C 0 5
pH 9.28 SU SU 0.4 5
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
Page 1239 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184531-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C Degrees C
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C 0 5
pH 9.28 SU SU 0.4 5
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
24 280-184531-C-1-B 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.4 Degrees C Degrees C
pH 7.06 SU SU
25 CCV 280-635901/25 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.01 SU SU 100 97 102
Page 1240 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184612-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C Degrees C
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C 0 5
pH 9.28 SU SU 0.4 5
7 280-184612-B-1-B 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.4 Degrees C Degrees C
pH 7.28 SU SU
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
Page 1241 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184613-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C Degrees C
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C 0 5
pH 9.28 SU SU 0.4 5
8 280-184613-B-1-B 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.2 Degrees C Degrees C
pH 9.90 SU SU
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
Page 1242 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184800-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C SU
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU NaN 5
pH 9.28 SU SU 0.4 5
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
19 280-184800-A-1-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C SU
pH 8.59 SU SU
20 280-184800-A-2-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C SU
pH 8.62 SU SU
21 280-184800-A-3-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C SU
pH 8.74 SU SU
22 280-184800-A-4-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU
pH 8.61 SU SU
23 280-184800-A-5-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.4 Degrees C SU
pH 8.73 SU SU
Page 1243 of 1261
TALS Raw Data Report
25 CCV 280-635901/25 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.01 SU SU 100 97 102
Page 1244 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184801-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C SU
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU NaN 5
pH 9.28 SU SU 0.4 5
13 280-184801-A-1-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.2 Degrees C SU
pH 9.05 SU SU
14 280-184801-A-2-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.5 Degrees C SU
pH 9.05 SU SU
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
16 280-184801-A-3-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C SU
pH 8.84 SU SU
17 280-184801-A-4-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C SU
pH 8.87 SU SU
18 280-184801-A-5-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.2 Degrees C SU
pH 8.86 SU SU
Page 1245 of 1261
TALS Raw Data Report
25 CCV 280-635901/25 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.01 SU SU 100 97 102
Page 1246 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184816-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C Degrees C
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C Degrees C 0 5
pH 9.28 SU SU 0.4 5
9 280-184816-D-2-C 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.2 Degrees C Degrees C
pH 9.22 SU SU
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045DLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
Page 1247 of 1261
TALS Raw Data Report
Eurofins Denver
635901
280-184824-1Job Number:
LIMS Batch:
Laboratory:
NOEQUIPEquipment:
1 ICV 280-635901/1 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 21.9 Degrees C Degrees C
pH 7.00 SU SU 100 97 102
4 LCS 280-635901/4 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.0 Degrees C SU
pH 7.01 SU SU 100 99 101
5 280-184424-D-1-H 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU
pH 9.24 SU SU
6 280-184424-D-1-I DU 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.3 Degrees C SU NaN 5
pH 9.28 SU SU 0.4 5
10 280-184824-A-1-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.4 Degrees C SU
pH 8.86 SU SU
11 280-184824-A-2-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.5 Degrees C SU
pH 8.69 SU SU
12 280-184824-A-3-A 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.4 Degrees C SU
pH 8.66 SU SU
15 CCV 280-635901/15 1.012/3/2023 10:25:52PM 9045CLab ID:Dil:Meth:Inj Date:
Analyte Rspnse Raw Res/Units Final Res/Qual/Units % Rec Rec Lmt % RPD RPD Lmt
RS#
Temperature 22.1 Degrees C Degrees C
pH 7.03 SU SU 100 97 102
Page 1248 of 1261
TALS Raw Data Report
Page 1249 of 1261
General Chemistry Raw Data Report
Job ID: 280-184424-1
Batch: 634249 Analyst Initials: MMP
Instrument: No Equipment Used for this TestMethod: D 2216
Lab Sample ID: 280-184424-C-1 Analysis Date: Nov 16, 2023 13:49
Percent Moisture
Analyte Raw Result UnitDetector
16.4079822616408None %
Dilution
1
Percent Solids None 83.5920177383592 %1
Eurofins Denver
Page 1250 of 1261
General Chemistry Raw Data Report
Job ID: 280-184424-1
Batch: 808190 Analyst Initials: SM
Instrument: No Equipment Assigned to The
Batch
Method: 1030
Lab Sample ID: MB 680-808190/1 Analysis Date: Nov 14, 2023 14:20
Ignitability
Analyte Raw Result UnitDetector
NBNone mm/sec
Dilution
1
Final
Amount
100 mL
Lab Sample ID: LCS 680-808190/2 Analysis Date: Nov 14, 2023 14:20
Ignitability
Analyte Raw Result UnitDetector
2.681None mm/sec
Dilution
1
Final
Amount
100 mL
Lab Sample ID: 280-184424-E-1 Analysis Date: Nov 14, 2023 14:20
Ignitability
Analyte Raw Result UnitDetector
NBNone mm/sec
Dilution
1
Final
Amount
100 mL
Lab Sample ID: LCSD 680-808190/14 Analysis Date: Nov 14, 2023 14:20
Ignitability
Analyte Raw Result UnitDetector
2.609None mm/sec
Dilution
1
Final
Amount
100 mL
Eurofins Savannah
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Subcontract Data
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Shipping and
Receiving
Documents
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Login Sample Receipt Checklist
Client: HydroGeoLogic Inc Job Number: 280-184424-1
Login Number: 184424
Question Answer Comment
Creator: Held, Wesley
List Source: Eurofins Denver
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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Login Sample Receipt Checklist
Client: HydroGeoLogic Inc Job Number: 280-184424-1
Login Number: 184424
Question Answer Comment
Creator: Harley, Tynisha
List Source: Eurofins Savannah
List Creation: 11/14/23 12:47 PMList Number: 2
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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APPENDIX G

RESPONSES TO REGULATORS COMMENTS

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