Loading...
HomeMy WebLinkAboutDAQ-2025-0005321 DAQC-077-25 Site ID 10335 (B4) MEMORANDUM TO: STACK TEST FILE – TESORO REFINING AND MARKETING COMPANY – SALT LAKE CITY REFINERY THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Paul Morris, Environmental Scientist DATE: January 23, 2025 SUBJECT: Sources: FCCU WGS, East and West Cogen Contact: Morgan Sites - (385) 306-4615 Location: 474 West 900 North, Salt Lake City, Salt Lake County, UT Test Contractor: Alliance Source Testing Permit/AO#: AO DAQE-AN103350075-18, dated January 11, 2018 Action Code: TR Subject: Review of Stack Test Reports received January 16, 2025 On January 16, 2025, DAQ received a test report for the FCCU wet gas scrubber as well as the East and West Cogeneration Unit Turbines. Testing was performed on November 19-21, 2024, to demonstrate compliance with the emission limit in condition II.B.7.a and II.B.8.a. The test results are as follow: Source Test Date RM/Pollutant DAQ Result Test Result Limit East (CG1) 11/20/2024 7E/NOx 29.49 ppmv 29.49 ppmv 8.4 lb/hr 8.3 lb/hr 0.046 lb/MMBtu 0.046 lb/MMBtu West (CG2) 11/19/2024 7E/NOx 41.71 ppmv 41.71 ppmv 12.1 lb/hr 12.1 lb/hr 0.064 lb/MMBtu 0.064 lb/MMBtu FCCU WGS 11/21/2024 PM 10 9.8 ton/yr 9.8 ton/yr 69 ton/yr DEVIATIONS: None reported. CONCLUSION: The source appears to have been operating in compliance with the applicable emission limit at the time of testing. RECOMMENDATION: None HPV: No ATTACHMENTS: Stack test report received January 16, 2025 6 3 I Introduction I Summary of Results ' I I :: Alliance T E C f I ~.J I C P., L G R O lJ P Source Test Report Testing Methodology contained 200-300 grams of silica gel. The un-weighed 90 mm Teflon filter was placed between the second and third impingers. The probe liner heating system was maintained at a temperature of 248 ±25°F, and the impinger temperature was maintained at 68°F or less throughout testing. The temperature of the Teflon filter was maintained greater than 65°F but less than or equal to 85°F. Following the completion of each test run, the sampling train was leak checked at a vacuum pressure greater than or equal to the highest vacuum pressure observed during the run. Condensate was collected in the first dry impinger, therefore the front-half of the sample train (the nozzle, probe, and heated pre-weighed filter) was removed in order to purge the back-half of the sample train (coil condenser, first and second impingers and CPM filter). A glass bubbler was inserted into the first impinger. If needed, de-ionized ultra-filtered (DIUF) water was added to the first impinger to raise the water level above the bubbler, then the coil condenser was replaced. Zero nitrogen was connected to the condenser, and a 60-minute purge at 14 liters per minute was conducted. After the completion of the nitrogen purge the impinger contents were measured for moisture gain. The pre-weighed quartz filter was carefully removed and placed in container 1. The probe, nozzle and front half of the filter holder were rinsed three (3) times with acetone to remove any adhering particulate matter and these rinses were recovered in container 2. All containers were sealed, labeled and liquid levels marked for transport to the identified laboratory for filterable particulate matter analysis. The contents of impingers 1 and 2 were recovered in container CPM Cont. # 1. The back half of the filterable PM filter holder, the coil condenser, impingers 1 and 2 and all connecting glassware were rinsed with DIUF water and then rinsed with acetone, followed by hexane. The water rinses were added to container CPM Cont. #1 while the solvent rinses were recovered in container CPM Cont. #2. The Teflon filter was removed from the filter holder and placed in container CPM Cont. #3. The front half of the condensable PM filter holder was rinsed with DIUF water and then with acetone, followed by hexane. The water rinse was added to container CPM Cont. #1 while the solvent rinses were added to container CPM Cont. #2. All containers were sealed, labeled and liquid levels marked for transport to the identified laboratory for condensable particulate matter analysis. 3.5 Quality Assurance/Quality Control-U.S. EPA Reference Test Method 3/3A Cylinder calibration gases used met EPA Protocol I(+/-2%) standards. Copies of all calibration gas certificates can be found in the Quality Assurance/Quality Control Appendix. Low-Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High-Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5% absolute difference. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. AST-2024-4117 MPC -Salt Lake City, UT Page 3-2 Appendix A I .:- Al I ia nce I ' Location: MPC-Tesoro -Salt Lake City Refmery, UT Source: FCCU Wet Gas Scrubber Project No.: AST-2024-4117 Run No.: 1 ---------------------------Par am et er: PM Moisture Fraction (BWS), dimensionless (measured) BWS =------V~w_s~td ___ _ ( Vwstd + Vmstd) where, Vwstd ____ l0_.6 __ 7_7 __ = standard wet volume, scf Vmstd 42.922 = standard meter volume, dscf BWS 0.199 = dimensionless Moisture Fraction (BWS), dimensionless BWS = BWSmsd unless BWSsat < BWSmsd where, BWSsat __ ..;;.0.;.;;.2_1_1 __ = moisture fraction (theoretical at saturated conditions) BWSmsd 0.199 = moisture fraction (measured) BWS 0.199 ------ Excess Air {EA), % EA = __ ........ ('¾_o_O_,_-_,._[0_.5_x_'¾_oC_O_,]'""')_x_l_0_0 __ _ (0.264 X %N2 ) -%02 - ( 0.5 X %CO) where, C0, __ .... 1_1 ..... 5...._ __ = carbon dioxide concentration,% 02 6.5 = oxygen concentration, % CO 0.0 = carbon monoxide concentration,% (assumed zero) N2 82 = nitrogen concentration, % EA 42.9 =% Molecular Wei2ht (DRY) (Md), lb/lb-mole Md= (0.44 X %CO2)+ (0.32 X %02) + (0.28 X (100 -%CO2 -%02]) where, CO, __ .... l_la.;;.5;;._ __ = carbon dioxide concentration, % 0, 6.5 = oxygen concentration, % Md 30.10 = lb/lb mo! Molecular Wei2ht (WET) (Ms), lb/lb-mole Ms= ( Md x (1 -BWS]) + (18.015 x BWS) where, Md __ ..;;.3..;;.0;.-,;.l~0 __ = molecular weight (DRY), lb/lb mo! BWS 0.199 = moisture fraction, dimensionless Ms 27.69 = lb/lb mo! Avera2e Velocity (Vs), ft/sec 85.49 x Cp x (t:. P112 ) avg x ~ Vs= where, Cp ___ o_.8_4_0 __ = pitot tube coefficient /1 P112 0.893 = velocity head of stack gas, (in. H20)"2 Ts 597 .1 = absolute stack temperature, 0R Ps 25.88 = absolute stack gas pressure, in. Hg Ms 2 7 .69 = molecular weight of stack gas, lb/lb mo! Vs 58.6 = ft/sec Appendix A Example Calculations Appendix B ~ Alliance Run Number Date Start Time Stop Time Run Time, min Barometric Pressure, in. Hg Meter Correction Factor Orifice Calibration Value Meter Volume, ft3 Meter Temperature, °F Meter Temperature, 0R Meter Orifice Pressure, in. WC Volume H20 Collected, mL Nozzle Diameter, in Area of Nozzle, ft2 Filterable PM Mass, mg Condensable PM Mass, mg PM2.5 PSD Results,% of Total Filterable PM PMl0 PSD Results,% of Total Filterable PM Filterable PM2.5 Mass, mg Filterable PMl0 Mass, mg Standard Meter Volume, ft3 Standard Water Volume, ft3 Moisture Fraction Measured Moisture Fraction @ Saturation Moisture Fraction Meter Pressure, in Hg Volume at Nozzle, ft3 Isokinetic Sampling Rate,(%) DGM Calibration Check Value,(+/-5%) Filterable PM Concentration, grain/dscf Filterable PM Emission Rate, lb/hr Filterable PM Emission Rate, ton/yr Condensable PM Concentration, grain/dscf Condensable PM Emission Rate, lb/hr Condensable PM Emission Rate, ton/yr Total PM Concentration, grain/dscf Total PM Emission Rate, lb/hr Total PM Emission Rate, ton/yr Filterable PM2.5 Concentration, grain/dscf Filterable PM2.5 Emission Rate, lb/hr Filterable PM2.5 Emission Rate, ton/yr Filterable PMlO Concentration, grain/dscf Filterable PMlO Emission Rate, lb/hr Filterable PMl0 Emission Rate, ton/yr Total PM2.5 Concentration, grain/dscf Total PM2.5 Emission Rate, lb/hr Total PM2.5 Emission Rate, ton/yr Total PMlO Concentration, grain/dscf Total PMl0 Emission Rate, lb/hr Total PMl0 Emission Rate, ton/yr Emission Calculations Location MPC-Tesoro -Salt Lake City Refinery, UT Source FCCU Wet Gas Scrubber Project No. AST-2024-4117 Parameter PM --------------------------- Run l Run2 Run3 Average 11/21/24 11/21/24 11/21/24 -- 11:50 14:45 16:45 -- 13:15 16:12 18:57 -- (9) 60.0 60.0 60.0 60.0 INPUT DATA (Pb) 25.88 25.83 25.85 25.85 (Y) l.003 l.003 l.003 -- (AH@) l.687 l.687 l.687 -- (Vm) 48.650 51.174 50.215 50.013 (Tm) 62.0 60.7 52.7 58.5 (Tm) 521.6 520.4 512.4 518.l (AH) l.867 2.083 1.942 l.964 (Vlc) 226.4 234.3 206.2 222.3 (Dn) 0.249 0.249 0.249 0.249 (An) 0.0003 0.0003 0.0003 0.0003 (Mn) 8.0 5.8 3.8 5.9 (MCPM) 9.0 5.3 3.4 5.9 (PSDi,M2.s) 4.5 4.4 6.4 5.1 (PSDi,M10) 31.3 31.8 42.3 35.l (MPM2.s) 0.4 0.3 0.2 0.3 (MPMIO) 2.5 l.8 l.6 2.0 ISOKINETIC DATA (Vmstd) 42.922 45.198 45.061 44.394 (Vwstd) 10.677 ll.050 9.724 10.484 (BWSmsd) 0.199 0.196 0.178 0.191 (BWSsat) 0.211 0.219 0.214 0.215 (BWS) 0.199 0.196 0.178 0.191 (Pm) 26.02 25.98 25.99 26.00 (Vn) 70.085 73.850 71.776 71.90 (I) 98.3 98.3 98.8 98.5 (Yq.) -1.l -1.2 0.9 -0.5 EMISSION CALCULATIONS (C,) 2.88E-03 l.98E-03 l.30E-03 2.05E-03 (PMR) 2.7 l.9 1.3 2.0 (ERFPM) 11.7 8.5 5.5 8.6 (CepM) 3.24E-03 l.81E-03 l.l6E-03 2.07E-03 (ERcPM) 3.0 l.8 l.l 2.0 (ERcpM) 13.l 7.7 4.9 8.6 (Cn,M) 6.llE-03 3.79E-03 2.47E-03 4.12E-03 (ERTPM) 5.7 3.7 2.4 3.9 (ERTPM) 24.8 16.2 10.5 17.2 (CPM2.s) l.29E-04 8.71E-05 8.33E-05 l.00E-04 (ERPM2s) 0.12 0.085 0.081 0.095 (ERPM2s) 0.53 0.37 0.35 0.42 (CpM10) 9.00E-04 6.30E-04 5.51E-04 6.94E-04 (ERpM10) 0.83 0.61 0.53 0.66 (ERPMIO) 3.7 2.7 2.3 2.9 (CrrM2.s) 3.37E-03 l.90E-03 l.25E-03 2.17E-03 (ERTPM2.s) 3.1 l.9 1.2 2.1 (ERTPM2s) 13.7 8.1 5.3 9.0 (CTPMlO) 4.14E-03 2.44E-03 l.71E-03 2.76E-03 (ERTPMIO) 3.8 2.4 1.7 2.6 (ERTPMIO) 16.8 10.4 7.3 11.5 . _:- Al I la nee TE !JI( r(IJ Sample Point 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Average Cyclonic Flow Check Location MPC-Tesoro -Salt Lake City Refinery, UT Source FCCU Wet Gas Scrubber Project No. AST-2024-4117 Date 11/21/24 Angle (AP=O) 5 5 4 6 2 1 5 12 10 9 8 8 2 5 8 5 1 1 2 3 5 1 1 1 5 Appendix C Project Narrative Analytical Method(s): Filterable Condensable MDL Blank Correction Method 5B -Determination of Nonsulfuric Acid Particulate Emissions From Stationary Sources Method 202 -Dry lmpinger Method for Determining Condensable Particulate Matter Emissions From Stationary Sources The filter(s) were either oven dried and/or desiccated per the method until a final weight was obtained. The liquid fractions were extracted if required, evaporated and cooled until a final weight was obtained. These fractions were summed together to provide the total Particulate Matter collected. The filter(s) were extracted per the method. The organic extract was added to the organic rinse, and the inorganic extract was added to the inorganic rinse. The inorganic fraction was extracted with solvent per the method. Extracts were combined with the organic rinse. The organic and inorganic fractions were evaporated and desiccated until a final weight was obtained. The Minimum Detection Level (MDL) is 0.5 mg per fraction. If the measured result for a fraction is less than the MDL, the MDL was used in ensuing calculations. If blank correction is performed, only blank values returned higher than the MDL are used. If a blank returns a value less than the MDL, no correction is included. Method 202 Recovery Blank corrections are applied by fraction (inorganic subtracted from inorganic; organic subtracted from organic). Custody: The samples were received by Dmitry Usav on 12/2/24 at 14: 15 in Arvada, CO. The samples were received in good condition with proper Chain-of-Custody documentation. No apparent container problems were noted upon receipt. Prior to analysis, the samples were kept secure with access limited to authorized personnel of ATG. Number of Samples: 24 (3 on Hold) Labeling: Acceptable Analyst: Dmitry Usav -Laboratory Analyst II Cory Manshack -Assistant Laboratory Manager Ryan Gillett -Laboratory Analyst II Equipment: Mettler Toledo Balance ML-104, SN B217893065. This scale was used for analytical determinations of filters and rinse vessels. Lab Reagents: QC Notes: Reporting Notes: Denver Instruments Balance TB-6201, SN 17904189. This scale was used to measure the total mass of rinse collected for blank correction. Analysis was performed on the same balance as the associated tare. Quincy Lab Inc oven, 30CG, SN G3-0l 2673. Acetone Lot Number: 240397 Hexane Lot Number: 234045 The samples met the minimum criteria established by the relevant method. A blank correction was applied per the method. 3 of 25 ~ a ent Tesoro Refining and Marketing Company Alliance Cfty, State Salt Lake City, UT 841 03 Project No. AST-2024-4117 TECHNICAL GROUP Meltlod EPA Method 5B Front Hall FIiier Lab ID D50764 D50769 D50774 Field ID M5B/202-FCCU WGS ESP-Run 1 Cont. 1 M5B/202-FCCU WGS ESP-Run 2 Cont. 1 M5B/202-FCCU WGS ESP-Run 3 Cont. 1 FIiier ID 16216 -C I6220-C 17294 -C: FIiier Tare Weight, g 0.5190 0.5269 0.5127 Date• Oven 12/3/24 12/3/24 12/3/24 Time-Oven 6:38 6:38 6:38 Date -Desslcator 12/3/24 12/3/24 12/3/24 Time • Deulcator 13:04 13:04 13:04 Dale ol Weighing 12/4/24 12/5/24 12/4/24 12/5/24 12/4/24 12/5/24 Time ol Weighing 14:17 8:06 14:17 8:06 14:17 8:06 FIiier Weight, g 0.5219 0.5219 0.5295 0.5295 0.5151 0.5155 FIiier PM Mass, mg• 3.0 2.6 2.6 Front Hall Rinse Lab ID D50765 D50770 D50775 Fleld ID M5B/202-FCCU WGS ESP-Run 1 Cont. 2 M5B/202-FCCU WGS ESP-Run 2 Cont. 2 M5B/202-FCCU WGS ESP-Run 3 Cont. 2 leaker ID 33779 33786 33795 leaker tare, g 3.9646 3.9615 3.9632 leaker with Acetone, g 77.5 70.3 40.2 Acetone Mau, g 73.5 66.3 36.2 Dale• Oven 12/3/24 12/3/24 12/3/24 Time-Oven 6:38 6:38 6:38 Date • Deulcator 12/3/24 12/3/24 12/3/24 Time -Desslcator 13:05 13:05 13:05 Date ol Weighing 12/4/24 12/5/24 12/4/24 12/5/24, 12/4/24 12/5/24 nme ol Weighing 14:10 7:59 14:10 7:59 14:10 7:59 Weight, g 3.9697 3.9696 3.9649 3.9645 3.9645 3.9642 Rinse PM Mass, mg• 5.0 3.2 1.1 Blank Corrected No Total PM Mau, mg 8.0 5.8 3.8 'All fractions were analyzed and retumed values greater than the MDL of 0.5 mg. 4 of 25 Client Tesoro Refining and Marketing Company E Alliance City, State Solt Lake City, UT 841 03 TECHNICAL GROUP Project No. AST-2024-4117 Method EPA Method 5B Acetone Blank Lab ID D50779 Field ID M5B-Acetone Blank Beaker ID 33748 Beaker tare, g 3.9645 Beaker with Acetone, g 157.36 Acetone Mass, g 153.40 Date-Oven 12/3/24 nme-Oven 6:38 Date -Desslcator 12/3/24 Time -Desslcator 13:05 Date of Weighing 12/4/24 12/5/24 nme of Weighing 14:10 7:59 Weight, g 3.9648 3.9646 Blank Mass, mg• 0.0 5 of 25 ~ Clent Tesoro Refining and Marketing Company City, State Salt Lake City, UT 84103 Alliance TECH N I CA L GROUP ProJec:t No. AST-2024-4117 Method EPA Method 202 Teflon Fitter Lab ID D50766 D50771 D50776 FteldlD M5B/202-FCCU WGS ESP-Run 1 Cont. 3 M5B/202-FCCU WGS ESP-Run 2 Cont. 3 M5B/202-FCCU WGS ESP-Run 3 Cont. 3 Organic Frac:tlon Lab ID D50768 D50773 D50778 Fteld ID M5B/202-FCCU WGS ESP-Run 1 Cont. 5 M5B/202-FCCU WGS ESP-Run 2 Cont. 5 M5B/202-FCCU WGS ESP-Run 3 Cont. 5 Beaker ID 33765 33750 33794 Beaker tare, g 3.9758 3.9658 3.9821 leaker Solvent, g 124.8 111.4 77.6 Solvent Mau, g 120.8 107.4 73.6 Date -Deulcator 12/2/24 12/2/24 12/2/24 Time -Desslcator 18:08 18:08 18:08 Date ol Weighing 12/3/24 12/4/24 12/3/24 12/4/24 12/3/24 12/4/24 Time ol Weighing 18:15 8:36 18:15 8:36 18:15 8:36 Weight, g 3.9778 3.9780 3.9673 3.9674 3.9838 3.9839 Organic PM Mass, mg• 2.2 1.6 1.8 Inorganic Fraction Lab ID D50767 D50772 D50777 Reid ID M5B/202-FCCU WGS ESP-Run 1 Cont. 4 M5B/202-FCCU WGS ESP-Run 2 Cont. 4 M5B/202-FCCU WGS ESP-Run 3 Cont. 4 Beaker ID 32047 32048 32057 Beaker tore, g 75.6032 75.4888 84.6170 leaker Water, g 482.3 477.5 391.0 Water Mass, g 406.7 402.0 306.4 Date -Deulcator 12/2/24 12/2/24 12/2/24 Time -Desslcator 18:07 18:07 18:07 Date of Weighing 12/3/24 12/4/24 12/3/24 12/4/24 12/3/24 12/4/24 Time of Weighing 18:08 8:30 18:08 8:30 18:08 8:30 Weight, g 75.6120 75.6120 75.4944 75.4946 84.6205 84.6206 Inorganic Mau, mg• a.a 5.7 3.6 Blank Corrected Yes Total PM Mass, mg 9.0 5.3 3.4 "All fractions were analyzed and returned values greater than the MDL of 0.5 mg. 6 of 25 Client Tesoro Refining and Marketing Company ~ Alliance City, State Salt Lake City, UT 84103 Projed No. AST-2024-4117 TEC H NIC A L GROUP Method EPA Method 202 Tellon FIiter Blanks Fleld Train Blank Prod Blank Lob ID D50782 N/A Field ID M202-FT Recovery Blank Cont. 3 N/A Organic Fraction Blanks Fleld Train Blank Prod Blank Lob ID D50784 D50781 Field ID M202-FT Recovery Blank Cont. 5 M202-FT Proof Blank Cont. 5 Beaker ID 33757 33763 Beaker tore, g 3.9572 3.9432 Beaker Solvent, g 92.3 82.4 Solvent Mou, g 88.3 78.5 Dote -Deulcator 12/2/24 12/2/24 Time -Desslcator 18:08 12:58 Dote of Weighing 12/3/24 12/4/24 12/3/24 12/4/24 nme of Weighing 18:15 8:36 16:19 8:23 Weight, g 3.9587 3.9586 3.9432 3.9434 Organic Mass, mg• 1.5 0.5 Inorganic Frodlon Blanks Field Train Blank Prod Blank Lab ID D50783 D50780 Field ID M202-FT Recovery Blank Cont. 4 M202-FT Proof Blank Cont. 4 Beaker ID 32064 32058 Beaker tore, g 71.4782 65.6197 Beaker Water g 386.8 237.7 Water Moss, g 315.3 172.1 Dote • Desslcotor 12/2/24 12/2/24 Time • Desslcator 18:07 12:58 Dote of Weighing 12/3/24 12/4/24 12/3/24 12/4/24 Time of Weighing 18:08 8:30 16:19 8:23 Weight, g 71.4798 71.4800 65.6208 65.6209 Inorganic Moss, mg• 1.8 1.2 7 of 25 Alliance '., () ~ I I~ I ~ r 1 L • 1 I I N I J Client Name MARATHON City, State SALT LAKE CITY, UT Source FCCU WGS ESP Project No 2024--4117 Sample ID MS/202 -FCCU WGS ESP -RUN I MS/202 -FCCU WGS ESP -RUN 2 MS/202 -FCCU WGS ESP -RUN 3 M202 FT PROOF BLANk M.202 FT RECOVERY BLANK MS/ M202 ACETONE BLANk M.202 WATER BLANK M202 HEXANE BLANX /J -, -II Reirqullhed By ~ -;q1 Relirqulshed By ~JU le:,..; h"' Relinquished By Chain-Of-Custody VetSlon No. LT 2019-01_190 Alliance Soorce Testing. UC -Lab Services 5530 MarshaU St Arvada, CO 80002 Phone (720) 457-9504 Turn Around Time: QStard.lrd □Expedited __ Number cl Business Days BlankM.nif,tott Act JVo:r91 /Si "J.6 2--:t:HS'"" Blank ManufAot t 1,./.g)(J d 'l'c, 8'/ Z Melhod,/Media Method S8 Mett-.:xl 17 MSi Melhod 201A Method 202 5 "' I t! i C: t! f:'! ~ "' "' 'Iii ., :, :, "' :i! ~ 0 ::, .. u .g ~ 0 u 0 < < E ~ < C 0 15 ~ E E 9 ' ~ ., E ' E 9 ~ S! ... 'Iii "" ~ ~ ., ~ E C < E .c u :;; ,.._ u C0 C ~ QC E u < QC < .0 "' e: tii E 0 "' ' .B "' .B ~ .B 51 C a, u e: 1l S! :, C vi QC ' ., E E C z E i:i: Vl :;; ~ C 0 i:i: ~ ~ ::::E QC " z :, ::, l2 N -= C z z ., z c.. vi u:: ~ c Number of Date Time Collector 9 :;; .8 11 ;;i .8 :;; " y ::::E 1 0 0 N ~ 0 i Vl i C: Containers Collected Recovered lnilia~ -= ~ .±= F; ,'l .St ::c -<> -cc-;, -~, 5 11/21/24 l>lf CJ::/4 ' " " " " 5 11/21/24 I 7'/c;' C.J(,14 " " " " " 5 11/21/24 ~oJv CK.// J " " " " 2 1V21/24 /J(J(, C~)4 " " 3 11/21/24 J-1~ all " " " '\'J. 1V2V24 /Toi> ~ 1, " / 1 11/21/24 ) ':Toti c/CII 1, 1 11/21/24 i-:J'6~ cle:J/1, / Date/&~ Received By 'io.itl U lrCl \tn Dall! II/ZS z, Notes Date 1({1fl{rl Received By JJ' 'V..bo.v-Date _Q~ 12.4 AVt-'7i5 SLC SLCreports@a/liancetg com Date Received By Date Filter1 to be sent to Partide Technology Labs for PSD analysis after MS analysis Sample Container Recieved T en'4)E!rature (•F) Page_/_ of_/_ - 8 of25 Cellbratlon Cer1lllcate ID NA 1548-07~32024-ACC-USL MffiLER TOLEDO Service Test Equipment All weights used for metrological testing are traceable to national or international standards. The weights were calibrated and certified by an accredited calibration laboratory. Weight Set 1: OIML E2 Weight Set No.: Certificate Number: Remarks N/A 2010 220741954-1 Date of Issue: 27-Dec-2023 Calibration Due Date: 31-Dec-2024 End of Accredited Section The information below and any attachments to this calibration certificate are not part of the accredited calibration. Sonwere Version: 1.23.2.283 Report Version: 2.19.3 Form Number. AF1702Lr1 .0 C, METTLER TOLEDO This is an original document and may not be partially reproduced without the written permission of the loaulng calibration laboratory. Page4 of 5 12 of 25 16162 -C 0.4827 HT-08260 511640 0.4825 8/24/22 14:34 CM 0.4829 8/26/22 16:25 CM Pass G3-012673 160C Thermco 2088 16163 -C 0.5084 HT-08260 511640 0.5083 8/24/22 14:22 CM 0.5085 8/26/22 16:21 CM Pass G3-012673 160C Thermco 2088 16164 -C 0.5213 HT-Q8260 511640 0.5211 8/24/22 14:37 CM 0.5214 8/26/22 15:58 CM Pass G3-012673 160C Thermco 2088 16165 -C 0.5224 HT-Q8260 511640 0.5222 8/24/22 14:56 CM 0.5225 8/26/22 16:12 CM Pass G3-012673 160C Thermco 2088 16166 -C 0.5168 HT-Q8260 511640 0.5166 8/24/22 14:51 CM 0.5169 8/26/22 16:10 CM Pass G3-012673 160C Thermco 2088 16167 -C 0.5146 HT-Q8260 511640 0.5145 8/24/22 14:53 CM 0.5146 8/26/22 16:17 CM Pass G3-012673 160C Thermco 2088 16168 -C 0.5266 HT-Q8260 511640 0.5265 8/24/22 14:42 CM 0.5267 8/26/22 16:17 CM Pass G3-012673 160C Thermco 2088 16169 -C 0.4785 HT·Q8260 511640 0.4783 8/24/22 14:49 CM 0.4787 8/26/22 16:13 CM Pass G3-012673 160C Thermco 2088 16170 -C 0.5192 HT-Q8260 S11640 0.5190 8/24/22 14:55 CM 0.5193 8/26/22 16:16 CM Pass Gl-012673 160C Thermco 2088 16171 -C 0.5107 HT-Q8260 511640 0.5105 8/24/22 14:50 CM 0.5108 8/26/22 16:09 CM Pass G3-012673 160C Thermco 2088 16172 -C 0.4790 HT-Q8260 S11640 0.4788 8/24/22 14:35 CM 0.4791 8/26/22 16:32 CM Pass G3-012673 160C Thermco 2088 16173 -C O.S170 HT-Q8260 511640 0.5168 8/24/22 14:40 CM 0.5171 8/26/22 16:24 CM Pass Gl-012673 160C Thermco 2088 16174 -C 0.5216 HT-Q8260 511640 0.5215 8/24/22 14:39 CM 0.5216 8/26/22 16:05 CM Pass Gl-012673 160C Thermco 2088 16175 -C 0.5197 HT-Q8260 511640 0.5196 8/24/22 14:40 CM 0.5198 8/26/22 16:20 CM Pass G3-012673 160C Thermco 2088 16176 -C 0.5308 HT-Q8260 511640 0.5307 8/24/22 14:54 CM 0.5309 8/26/22 16:14 CM Pass Gl-012673 160C Thermco 2088 16177 -C 0.5090 HT-Q8260 511640 0.5088 8/24/22 14:54 CM 0.5091 8/26/22 16:14 CM Pass G3-012673 160C Thermco 2088 16178 -c 0.5196 HT·Q8260 511640 0.5195 8/24/22 14:47 CM 0.5197 8/26/22 16:07 CM Pass G3-012673 160C Thermco 2088 16179 -C 0.4881 HT-Q8260 511640 0.4879 8/24/22 14:24 CM 0.4883 8/26/22 16:31 CM Pass G3-012673 160C Thermco 2088 16180 -C 0.5141 HT-Q8260 511640 0.5139 8/24/22 14:21 CM 0.5143 8/26/22 16:05 CM Pass G3-012673 160C Thermco 2088 16181 -C 0.5244 HT-Q8260 511640 0.5243 8/24/22 14:20 CM 0.5244 8/26/22 16:01 CM Pass G3-012673 160C Thermco 2088 16182 -C 0.5100 HT-Q8260 511640 0.5099 8/24/22 17:17 CM 0.5100 8/26/22 16:09 CM Pass G3-012673 160C Thermco 2088 16183 -c 0.5197 HT-Q8260 511640 0.5195 8/24/22 14:52 CM 0.5198 8/26/22 16:12 CM Pass G3-012673 160C Thermco 2088 16184 -C 0.5187 HT-Q8260 511640 0.5186 8/24/22 14:51 CM 0.5188 8/26/22 16:08 CM Pass Gl-012673 160C Thermco 2088 16185 -C 0.5140 HT-Q8260 511640 0.5139 8/24/22 14:30 CM 0.5140 8/26/22 15:57 CM Pass G3-012673 160C Thermco 2088 16186 -C 0.5225 HT-Q8260 511640 0.5224 8/24/22 14:47 CM 0.5226 8/26/22 16:06 CM Pas.s G3-012673 160C Thermco 2088 16187 -C 0.5132 HT-Q8260 511640 0.5130 8/24/22 14:48 CM 0,5133 8/26/22 16:10 CM Pass G3-012673 160C Thermco 2088 16188 -C 0.4833 HT-Q8260 511640 0.4831 8/24/22 14:38 CM 0.4835 8/26/22 16:01 CM Pas, Gl-012673 160C Thermco 2088 16189 -C 0.5204 HT-Q8260 511640 0.5203 8/24/22 14:29 CM 0.5204 8/26/22 16:24 CM Pass Gl-012673 160C Thermco 2088 16190 -C 0.5188 HT-Q8260 511640 0.5186 8/24/22 14:28 CM 0.5189 8/26/22 16:22 CM Pass G3-012673 160C Thermco 2088 16191 -C 0.4824 HT-Q8260 511640 0.4822 8/24/22 14:19 CM 0.4825 8/26/22 15:59 CM Pass G3-012673 160C Thermco 2088 16192 -C 0.4808 HT-Q8260 511640 0.4806 8/24/22 14:27 CM 0.4810 8/26/22 16:06 CM Pass G3-012673 160C Thermco 2088 16193 -C 0.5191 HT-Q8260 511640 0.5190 8/24/22 14:43 CM 0.5191 8/26/22 16:29 CM Pass Gl-012673 160C Thermco 2088 16194 -C 0.5114 HT-Q8260 511640 0.5113 8/24/22 14:41 CM 0.5115 8/26/22 16:28 CM Pass G3-012673 160C Thermco 2088 16195 -C 0.5082 HT-Q8260 511640 0.5082 8/24/22 14:26 CM 0.5082 8/26/22 16:02 CM Pass G3-012673 160C Thermco 2088 16196 -C 0.4775 HT-Q8260 511640 0.4773 8/24/22 14:33 CM 0.4776 8/26/22 16:20 CM Pass G3-012673 160C Thermco 2088 16197 -C 0.5198 HT-Q8260 511640 0.5197 8/24/22 14:36 CM 0.5198 8/26/22 16:27 CM Pass Gl-012673 160C Thermco 2088 16198 -C 0.5105 HT-Q8260 511640 0.5103 8/24/22 14:26 CM 0.5107 8/26/22 15:59 CM Pass Gl-012673 160C Thermco 2088 16199 -C 0.5220 HT-Q8260 511640 0.5219 8/24/22 14:33 CM 0.5220 8/26/22 16:22 CM Pass G3-012673 160C Thermco 2088 16200 -C 0.5149 HT-Q8260 511640 0.5148 8/24/22 14:30 CM 0.5149 8/26/22 16:26 CM Pass G3-012673 160C Thermco2088 16201 -C 0.5098 HT-Q8260 511640 0.5097 8/24/22 14:18 CM 0.5099 8/26/22 15:55 CM Pass G3-012673 160C Thermco 2088 16202 -C 0.4816 HT-Q8260 511640 0.4814 8/24/22 14:32 CM 0.4818 8/26/22 16:04 CM Pass G3-012673 160C Thermco 2088 16203 -C 0.5192 HT-Q8260 511640 0.5191 8/24/22 14:31 CM 0.5192 8/26/22 16:00 CM Pass G3-012673 160C Thermco 2088 16204 -C 0.5079 HT-Q8260 511640 0.5078 8/24/22 14:23 CM 0.5080 8/26/22 16:23 CM Pass G3-012673 160C Thermco 2088 16205 -C 0.5219 HT-Q8260 511640 0.5219 8/24/22 14:25 CM 0.5218 8/26/22 15:56 CM Pass Gl-012673 160C Thermco 2088 16206 -C 0.5119 HT-Q8260 511640 0.5117 8/24/22 14:24 CM 0.5120 8/26/22 16:19 CM Pass Gl-012673 160C Thermco 2088 16207 -C 0.5126 HT-Q8260 511640 0.5125 8/24/22 14:29 CM 0.5127 8/26/22 16:31 CM Pass Gl-012673 160C Thermco 2088 16208 -C 0.5212 HT-Q8260 511640 0.5212 8/24/22 17:16 CM 0.5211 8/26/22 13:20 CM Pass G3-012673 160C Thermco 2088 16209 -C 0.5205 HT-Q8260 511640 0.5205 8/24/22 17:12 CM 0.5205 8/26/22 13:28 CM Pass Gl-012673 160C Thermco 2088 16210 -C 0.5216 HT-Q8260 511640 0.5218 8/24/22 16:51 CM 0.5214 8/26/22 13:40 CM Pass G3-012673 160C Thermco 2088 16211 -C 0.5216 HT-Q8260 511640 0.5215 8/24/22 17:09 CM 0.5217 8/26/22 14:06 CM Pass Gl-012673 160C Thermco 2088 16212 -C 0.5217 HT-Q8260 511640 0.5217 8/24/22 17:09 CM 0.5217 8/26/22 14:07 CM Pass G3-012673 160C Thermco 2088 16213 -C 0.5161 HT-Q8260 511640 0.5160 8/24/22 17:07 CM 0.5162 8/26/22 14:09 CM Pass Gl-012673 160C Thermco 2088 16214 -C 0.5112 HT-Q8260 511640 0.5111 8/24/22 17:01 CM 0.5112 8/26/22 14:04 CM Pass G3-012673 160C Thermco 2088 16215 -C 0.5207 HT-Q8260 511640 0.5205 8/24/22 16:58 CM 0.5208 8/26/22 13:50 CM Pass G3-012673 160C Thermco 2088 16216 -C 0.5190 HT-Q8260 511640 0.5189 8/24/22 17:13 CM 0.5190 8/26/22 13:30 CM Pass G3-012673 160C Thermco 2088 16217 -C 0.5116 HT-Q8260 511640 0.5115 8/24/22 17:16 CM 0.5116 8/26/22 13:22 CM Pass Gl-012673 160C Thermco 2088 16218 -C 0.5158 HT-Q8260 511640 0.5157 8/24/22 16:57 CM 0.5159 8/26/22 13:56 CM Pass G3-012673 160C Thermco 2088 22 of 25 16219 -C 0.5079 HT-Q8260 511640 0.5079 8/24/22 16:55 CM 0.5079 8/26/22 13:42 CM Pass G3-012673 160C Thermco 2088 16220 -C 0.5269 HT-Q8260 511640 0.5269 8/24/22 17:19 CM 0.5269 8/26/22 13:27 CM Pass G3-012673 l60C Thermco 2088 16221 -C 0.5216 HT-Q8260 S11640 O.S21S 8/24/22 16:56 CM O.S216 8/26/22 13:54 CM Pass G3-0l2673 l60C Thermco 2088 16222 -C O.S277 HT-Q8260 511640 0.5277 8/24/22 16:52 CM 0.5277 8/26/22 13:47 CM Pass G3-012673 160C Thermco 2088 16223 -C O.S2S8 HT-Q8260 511640 0.5257 8/24/22 17:08 CM 0.52S9 8/26/22 14:02 CM Pass G3-012673 160C Thermco 2088 16224 -C 0.5092 HT-08260 511640 0.5092 8/24/22 17:06 CM 0.S092 8/26/22 14:11 CM Pass G3-012673 160C Thermco 2088 16225 -C O.S201 HT-08260 S11640 O.S200 8/24/22 17:02 CM 0.5201 8/26/22 14:00 CM Pass G3-012673 160C Thermco 2088 16226 -C 0.5123 HT-Q8260 S11640 0.S123 8/24/22 16:59 CM 0.5123 8/26/22 13:44 CM Pass G3-012673 l60C Thermco 2088 16227 -C 0.5201 HT•Q8260 511640 0.5200 8/24/22 17:01 CM 0,5201 8/26/22 13:58 CM Pass G3-012673 160C Thermco 2088 16228 -C 0.5216 HT-Q8260 511640 0.5216 8/24/22 17:03 CM 0.S216 8/26/22 14:03 CM Pass G3-012673 160C Thermco 2088 16229 -C 0.5151 HT-Q8260 511640 0.5151 8/24/22 16:59 CM 0.5150 8/26/22 13:48 CM Pass G3-012673 160C Thermco 2088 16230 -C 0.5267 HT-Q8260 511640 0.5266 8/24/22 16:58 CM 0.5268 8/26/22 13:52 CM Pass G3-012673 160C Thermco 2088 16231 -C 0.5084 HT-08260 511640 0.5084 8/24/22 16:53 CM 0,5083 8/26/22 13:38 CM Pass G3-012673 160C Thermco 2088 16232 -C 0.5092 HT-Q8260 511640 0.5091 8/24/22 17:13 CM 0.5092 8/26/22 13:31 CM Pass G3-012673 160C Thermco 2088 16233 -C 0.5260 HT-Q8260 511640 0.5260 8/24/22 16:56 CM 0.5259 8/26/22 13:55 CM Pass G3-012673 160C Thermco 2088 16234 -C 0.5105 HT-08260 511640 0.5104 8/24/22 16:52 CM 0.5105 8/26/22 13:41 CM Pass G3-012673 160C Thermco 2088 16235 -C 0.5043 HT-Q8260 511640 0.S042 8/24/22 17:06 CM 0,5044 8/26/22 14:10 CM Pass G3-012673 160C Thermco 2088 16236 -C 0.5276 HT-Q8260 511640 0.5275 8/24/22 17:10 CM 0.5276 8/26/22 14:05 CM Pass G3-012673 160C Thermco 2088 16237 -C 0.5127 HT-Q8260 511640 0.5127 8/24/22 17:05 CM 0,5127 8/26/22 13:53 CM Pass G3-012673 160C Thermco 2088 16238 -C 0.5047 HT·Q8260 511640 0.5047 8/24/22 16:54 CM 0.5047 8/26/22 13:36 CM Pass G3-012673 160C Thermco 2088 16239 -C 0.5186 HT-Q8260 511640 0.5186 8/24/22 16:57 CM 0.5186 8/26/22 13:49 CM Pass G3-012673 160C Thermco 2088 16240 -e 0.5165 HT-Q8260 511640 0.5164 8/24/22 16:54 CM 0.5165 8/26/22 13:33 CM Pass G3-012673 160C Thermco 2088 16241 -C 0.5151 HT-Q8260 511640 0.5151 8/24/22 17:18 CM 0.5150 8/26/22 13:24 CM Pass G3-012673 160C Thermco 2088 16242 -C 0.5238 HT-Q8260 511640 0.5238 8/24/22 17:14 CM 0.5237 8/26/22 13:3S CM Pass G3-012673 160C Thermco 2088 16243 -C 0.5189 HT-Q8260 511640 0.5188 8/24/22 17:18 CM 0.5189 8/26/22 13:23 CM Pass G3-012673 l60C Thermco 2088 16244 -C O.S252 HT-Q8260 511640 0.5251 8/24/22 17:19 CM 0.5252 8/26/22 13:26 CM Pass G3-012673 160C Thermco 2088 16245 -C 0.5222 HT-Q8260 511640 0.S221 8/24/22 17:15 CM 0.5222 8/26/22 13:37 CM Pass G3-012673 160C Thermco 2088 16246 -C 0.5233 HT-Q8260 511640 0.5232 8/24/22 17:14 CM 0.5233 8/26/22 13:32 CM Pass G3-012673 160C Thermco 2088 16247 -C 0.5081 HT-Q8260 511640 0.5080 8/24/22 17:04 CM 0.5082 8/26/22 13:51 CM Pass G3-012673 l60C Thermco 2088 16248 -c 0.5211 HT-Q8260 511640 0.5210 8/25/22 10:23 CM 0.5211 8/31/22 14:12 CM Pass G3-012673 160C Thermco 2088 16249 -C 0.5111 HT·Q8260 511640 0.5109 8/24/22 17:07 CM 0.5112 8/26/22 14:08 CM Pass G3-012673 160C Thermco 2088 16250 -C 0.5140 HT-Q8260 511640 0.5139 8/24/22 17:03 CM 0.S140 8/26/22 14:01 CM Pass G3-012673 160C Thermco 2088 16251 -C O.S217 HT-Q8260 S11640 0.5216 8/24/22 17:00 CM O.S217 8/26/22 13:57 CM Pass G3-012673 160C Thermco 2088 16252 -C O.S202 HT-Q8260 511640 0.5201 8/24/22 16:50 CM O.S202 8/26/22 13:45 CM Pass G3-012673 160C Thermco 2088 16253 -C 0.5261 HT-Q8260 511640 0.5260 8/2S/22 9:21 CM 0.5261 8/31/22 13:48 CM Pass G3-012673 160C Thermco 2088 16254 -C 0.5088 HT-Q8260 511640 0.5086 8/25/22 9:16 CM 0.5089 8/31/22 13:59 CM Pass G3-012673 160C Thermco 2088 16255 -C 0.5085 HT-Q8260 511640 0.5083 8/25/22 9:18 CM 0.5087 8/31/22 14:02 CM Pass G3-012673 160C Thermco 2088 16256 -C 0.5298 HT-Q8260 511640 0.5298 8/2S/22 9:14 CM 0.5298 8/31/22 13:52 CM Pass G3-012673 160C Thermco 2088 16257 -C 0.5195 HT-Q8260 511640 0.S194 8/25/22 9:17 CM 0.5196 8/31/22 14:01 CM Pass G3-012673 160C Thermco 2088 16258 -C 0.5279 HT-Q8260 511640 0.5279 8/25/22 9:15 CM 0.5279 8/31/22 13:53 CM Pass G3-012673 160C Thermco 2088 16259 -C 0.5160 HT-Q8260 511640 0.5160 8/25/22 9:12 CM 0.5160 8/31/22 13:51 CM Pass G3-012673 160C Thermco 2088 16260 ·C 0.5294 HT-Q8260 511640 0.5294 8/25/22 9:12 CM 0.5294 8/31/22 13:50 CM Pass G3-012673 160C Thermco 2088 16261 -C 0.5125 HT-Q8260 511640 0.5124 8/25/22 9:25 CM 0.5126 8/31/22 13:55 CM Pass G3-012673 160C Thermco 2088 16262 -c 0.5163 HT-Q8260 511640 0.5164 8/25/22 9:24 CM 0.5162 8/31/22 13:54 CM Pass Gl-012673 160C Thermco 2088 16263 -C 0.5116 HT-Q8260 511640 0.5115 8/25/22 10:19 CM 0.5117 8/31/22 14:27 CM Pass G3-012673 160C Thermco 2088 16264 -C 0.5180 HT-Q8260 511640 0.5179 8/25/22 10:12 CM 05181 8/31/22 14:15 CM Pass G3-012673 160C Thermco 2088 16265 -C 0.5083 HT-Q8260 511640 0.5082 8/25/22 10:06 CM 0,5083 8/31/22 14:29 CM Pass G3-012673 160C Thermco 2088 16266 -C 0.5263 HT-Q8260 511640 0.5264 8/25/22 10:10 CM 0.5262 8/31/22 14:28 CM Pass G3-012673 160C Thermco 2088 16267 -C 0.5190 HT-Q8260 511640 O.S190 8/25/22 10:18 CM 0.5190 8/31/22 14:25 CM Pass G3-012673 160C Thermco 2088 16268 -C 0.5076 HT-Q8260 511640 0.5074 8/25/22 10:18 CM 0.5077 8/31/22 14:22 CM Pass Gl-012673 160C Thermco 2088 16269 -C 0.5218 HT-Q8260 511640 0.5217 8/25/22 10:26 CM 0.S219 8/31/22 14:22 CM Pass G3-012673 160C Thermco 2088 16270 -C 0.5219 HT-Q8260 511640 0.5219 8/25/22 10:17 CM 0.5218 8/31/22 14:19 CM Pass Gl-012673 160C Thermco 2088 16271 -c 0.5191 HT-Q8260 511640 0.5190 8/25/22 10:06 CM 0.5192 8/31/22 14:30 CM Pass G3-012673 160C Thermco 2088 16272 -C 0.5195 HT-Q8260 511640 0.5194 8/25/22 10:16 CM 0.5195 8/31/22 14:19 CM Pass G3-012673 160C Thermco 2088 16273 -C 0.5170 HT-Q8260 511640 0.5170 8/25/22 9:55 CM 0.5169 8/31/22 14:24 CM Pass G3-0l2673 160C Thermco 2088 16274 -C 0.5213 HT-Q8260 S11640 0.5213 8/25/22 9:55 CM 0.5213 8/31/22 14:26 CM Pass G3-012673 160C Thermco 2088 16275 -C 0.5128 HT-Q8260 511640 0.5127 8/25/22 10:05 CM 05129 8/31/22 14:30 CM Pass G3-012673 160C Thermco 2088 23 of 25 17289 -C 0.5272 HT-Q8260 511897 0.5272 1/8/24 12:09 cw 0.5272 1/9/24 12:56 cw Pass 63-012673 160( Thermco 2088 17290 -C 0.5127 HT-Q8260 511897 0.5126 1/8/24 12:04 cw 0.5128 1/9/24 13:17 cw Pass 63-012673 160 ( Thermco 2088 17291 -C 0.5071 HT-Q8260 511897 0.5071 1/8/24 12:06 cw 0.5071 1/9/24 12:56 cw Pass 63-012673 160( Thermco 2088 17292 -C 0.5125 HT-Q8260 511897 0.5124 1/8/24 12:07 cw 0.5126 1/9/24 12:54 cw Pass 63-012673 160( Thermco 2088 17293 -c 0.5117 HT-Q8260 511897 0.5115 1/8/24 12:08 cw 0.5118 1/9/24 12:52 cw Pass 63-012673 160 ( Thermco 2088 17294 -C 0.5127 HT-Q8260 511897 0.5126 1/8/24 11:35 cw 0.5128 1/9/24 13:10 cw Pass 63-012673 160( Thermco 2088 17295 -c 0.5149 HT-Q8260 511897 0.5148 1/8/24 11:33 cw 0.5150 1/9/24 13:04 cw Pass 63-012673 160( Thermco 2088 17296 -c 0.5184 HT-Q8260 511897 0.5182 1/8/24 12:11 cw 0.5185 1/9/24 12:55 cw Pass 63-012673 160( Thermco 2088 17297 -C 0.5278 HT-Q8260 511897 0.5278 1/8/.24 12:10 cw 0.5278 1/9/24 13:01 cw Pass 63-012673 160( Thermco 2088 17298 -C 0.5153 HT-Q8260 511897 0.5152 1/8/24 11:39 cw 0.5153 1/9/24 13:19 cw Pass 63-012673 160( Thermco 2088 17299 -C 0.5106 HT-Q8260 511897 0.5106 1/8/24 11:37 cw 0.5106 1/9/24 13:18 cw Pass 63-012673 160( Thermco 2088 17300 -c 0.5118 HT-Q8260 511897 0.5116 1/8/24 11:38 cw 0.5120 1/9/24 13:05 cw Pass 63-012673 160( Thermco 2088 17301 -C 0.5158 HT-Q8260 511897 0.5156 1/8/24 11:38 cw 0.5159 1/9/24 13:03 cw Pass 63-012673 160( Thermco 2088 17302 -c 0.5153 HT-Q8260 511897 0.5151 1/8/24 11:42 cw 0.5154 1/9/24 13:01 cw Pass 63-012673 160( Thermco 2088 17303 -c 0.5193 HT-Q8260 511897 0.5192 1/8/24 10:57 cw 0.5194 1/9/24 13:25 cw Pass 63-012673 160( Thermco 2088 17304 -C 0.5097 HT-Q8260 511897 0.5095 1/8/24 11:00 cw 0.5099 1/9/24 13:24 cw Pass 63-012673 160( Thermco 2088 17305 -c 0.5198 HT-Q8260 511897 0.5198 1/8/24 11:01 cw 0.5198 1/9/24 13:21 cw Pass 63-012673 160( Thermco 2088 17306 -c 0.5187 HT-Q8260 511897 0.5185 1/8/24 11:03 cw 0.5189 1/9/24 13:12 cw Pass 63-012673 160( Thermco 2088 17307 -c 0.5171 HT-Q8260 511897 0.5169 1/8/24 11:05 cw 0.5172 1/9/24 13:09 cw Pass 63-012673 160( Thermco 2088 17308 -C 0.5212 HT-Q8260 511897 0.5210 1/8/24 11:07 cw 0.5213 1/9/24 13:08 cw Pass 63-012673 160( Thermco 2088 17309 -C 0.5153 HT-Q8260 511897 0.5153 1/8/24 11:57 cw 0.5153 1/9/24 12:59 cw Pass 63-012673 160( Thermco 2088 17310 -c 0.5149 HT-Q8260 511897 0.5148 l/8/24 11:59 cw 0.5150 1/9/24 12:53 cw Pass 63-012673 160( Thermco 2088 17311 -c 0.5124 HT-Q8260 511897 0.5124 1/8/24 11:59 cw 0.5124 1/9/24 12:59 cw Pass 63-012673 160( Thermco 2088 17312 -C 0.5114 HT-Q8260 511897 0.5113 1/8/24 12:00 cw 0.5115 1/9/24 12:57 cw Pass 63-012673 160( Thermco 2088 17313 -C 0.5182 HT-Q8260 511897 0.5179 1/8/24 10:58 cw 0.5184 1/9/24 13:14 cw Pass 63-012673 160( Thermco 2088 17314 -C 0.5042 HT-Q8260 511897 0.5042 1/8/24 12:01 cw 0.5042 1/9/24 12:54 cw Pass 63-012673 160( Thermco 2088 17315 -C 0.5104 HT-Q8260 511897 0.5104 1/8/24 12:03 cw 0.5104 1/9/24 13:07 cw Pass 63-012673 160( Thermco 2088 17316 -C 0.5176 HT-Q8260 511897 0.5175 1/8/24 11:14 cw o.s1n 1/9/24 13:13 cw Pass 63-012673 160( Thermco 2088 17317 -C 0.5129 HT-Q8260 511897 0.5129 1/8/24 11:15 cw 0.5128 1/9/24 13:04 cw Pass 63-012673 160( Thermco 2088 17318 -C 0.5177 HT-Q8260 511897 0.5176 l/8/24 11:16 cw 0.5177 1/9/24 13:17 cw Pass 63-012673 160( Thermco 2088 17319 -c 0.5109 HT-Q8260 511897 0.5107 1/8/24 11:17 cw 0.5111 1/9/24 13:12 cw Pass 63-012673 160( Thermco 2088 17320 -C 0.5161 HT-08260 511897 0.5160 1/8/24 11:19 cw 0.5161 1/9/24 13:02 cw Pass 63-012673 160( Thermco 2088 17321 -C 0.5152 HT-Q8260 511897 0.5149 1/8/24 11:20 cw 0.5154 1/9/24 13:07 cw Pass 63-012673 160( Thermco 2088 17322 -c 0.5124 HT-Q8260 511897 0.5122 1/8/24 11:49 cw 0.5125 1/9/24 13:16 cw Pass 63-012673 160( Thermco 2088 17323 -C 0.5234 HT-Q8260 511897 0.5234 1/8/24 11:53 cw 0.5234 1/9/24 13:00 cw Pass 63-012673 160( Thermco 2088 17324 -C 0.5259 HT-Q8260 511897 0.5258 1/8/24 11:54 cw 0.5260 1/9/24 12:58 cw Pass 63-012673 160( Thermco 2088 :17325 -C 0.5199 HT-Q8260 511897 0.5197 1/8/24 11:56 cw 0.5200 1/9/24 13:06 cw Pass 63-012673 160( Thermco 2088 17326 -C 0.5220 HT-Q8260 511897 0.5220 1/8/24 11:51 cw 0.5220 1/9/24 12:57 cw Pass 63-012673 160( Thermco 2088 17327 -c 0.5162 HT-Q8260 51189 7 0.5161 1/8/24 11:00 cw 0.5163 1/9/24 13:19 cw Pass 63-012673 160( Thermco 2088 17328 -c 0.5210 HT-Q8260 511897 0.5208 1/8/24 11:06 cw 0.5212 1/9/24 13:02 cw Pass 63-012673 160( Thermco 2088 :17329 -c 0.5149 HT-Q8260 511897 0.5148 1/8/24 11:11 cw 0.5149 1/9/24 13:20 cw Pass 63-012673 160( Thermco 2088 17330 -C 0.5171 HT-Q8260 511897 0.5171 1/8/24 11:12 cw 0.5171 1/9/24 13:10 cw Pass 63-012673 160( Thermco 2088 17331 -C 0.5165 HT-Q8260 511897 0.5163 1/8/24 11:13 cw 0.5166 1/9/24 13:21 cw Pass 63-012673 160( Thermco 2088 17332 -C 0.5166 HT-Q8260 511897 0.5166 1/8/24 11:47 cw 0.5166 1/9/24 13:15 cw Pass 63-012673 160( Thermco 2088 17333 -c 0.5116 HT-Q8260 511897 0.5115 1/8/24 11:47 cw 0.5116 1/9/24 13:11 cw Pass 63-012673 160( Thermco 2088 17334 -c 0.5190 HT-Q8260 511897 0.5190 1/8/24 14:50 cw 0.5190 1/9/24 9:12 cw Pass 63-012673 160( Thermco 2088 17335 -C 0.5092 HT-08260 511897 0.5090 1/8/24 14:49 cw 0.5094 1/9/24 8:53 cw Pass 63-012673 160( Thermco 2088 17336 -c 0.5231 HT-Q8260 511897 0.5231 l/8/24 14:44 cw 0.5230 1/9/24 9:21 cw Pass 63-012673 160( Thermco 2088 17337 -C 0.5154 HT-Q8260 511897 0.5152 1/8/24 15:01 cw 0.5155 1/9/24 9:06 cw Pass 63-012673 160( Thermco 2088 17338-<: 0.5232 HT-Q8260 511897 0.5230 1/8/24 15:03 cw 0.5234 1/9/24 9:07 cw Pass 63-012673 160( Thermco 2088 17339 -C 0.5134 HT-Q8260 511897 0.5135 1/18/24 11:10 cw 0.5133 1/19/24 11:00 cw Pass 63-012673 160( Thermco 2088 17340 -c 0.5198 HT-Q8260 511897 0.5198 1/18/24 11:09 cw 0.5197 1/19/24 11:03 cw Pass 63-012673 160( Thermco 2088 17341 -c 0.5170 HT-Qll260 511897 0.5168 1/8/24 15:09 cw 0.5172 1/9/24 8:32 cw Pass 63-012673 160( Thermco 2088 24 of25 PTL PROJECT 65155-13 PARTICLE SIZE SUMMARY INSTRUMENT ACCESSORY TECHNIQUE Accusizer A7000AD Gravity Drain Single Particle Optical Sensing (SPOS) REFERENCE(S) PTL Test Method: N/A Client Method: NIA PARTICLE SIZE DATA SUMMARY SAMPLE ID MS Quartz Filter -Run 1 16216-C MS Quartz FIiter -Run 2 16220-C MS Quartz FIiter -Run 3 17294-C SAMPLE ID MS Quartz FIiter -Run 1 16216-C MS Quartz FIiter -Run 2 16220-C MS Quartz FIiter -Run 3 17294-C SAMPLE ID MS Quartz FIiter -Run 1 16216-C MS Quartz FIiter -Run 2 16220-C MS Quartz Filter -Run 3 17294-C CUMULATIVE NUMBER % LESS THAN INDICATED SIZE(um) 10111 Percentlle I 50111 Percentile I 90111 Percentlle 0.54 I 0.70 I 1.15 0.54 I 0.71 I 1.20 0.54 I 0.70 I 1.16 CUMULATIVE VOLUME % LESS THAN INDICATED 10111 Percentlle I 5.01 I 4.93 I 3.81 I Page 2 of 3 PARTICLE TECHNOLOGY LABS SIZE (um) 50111 Percentile I 90th Percentile 14.73 I 29.43 14.47 I 46.46 11.57 I 30.24 CUMULATIVE VOLUME % LESS THAN DIAMETER 2.Spm I 10pm 4.5 I 31.3 4.4 I 31.8 6.4 I 42.3 NUMBER WEIGHTED MEAN (um) 0.92 0.94 0.91 VOLUME WEIGHTED MEAN (um) 16.49 20.34 14.57 PARTICLE SIZE SUMMARY (Continued) Attachment(•): • An explanation page titled Interpreting Your Single Particle Optical Sensing Analysis. • Original result page(s). Comment(s): The lower size limit of this analysis was set at 0.50 µm. Page 3 of 3 PARTICLE TECHNOLOGY LABS PTL PROJECT65155-13 A ptl Particle Technology Labs 555 Rogers Street, Downers Grove, IL 60515 630.969.2703 www.particletechlabs.com INTERPRETING YOUR SINGLE PARTICLE OPTICAL SENSING ANALYSIS Introduction Your samples have been analyzed on a Particle Sizing Systems AccuSizerno, 780, or A7000 System, a particle counter capable of determining both particle size and concentration of suspensions. The AccuSizer utilizes Single Particle Optical Sensing (SPOS) technology (also referred to as the photozone technique) to provide excellent resolution, wide dynamic range, and high accuracy. SPOS utilizes two physical principles of detection; light extinction (also known as light obscuration) for particles larger than approximately 1.5 µm and light scattering for particles smaller than 1.5 µm. During analysis, a dilute suspension of particles is passed through a region of uniform illumination produced by a laser diode. Particles greater than approximately 1.5 µm are detected by the amount of light they obscure to the extinction detector, while smaller particles are detected by the intensity of light scattered at a range of angles towards a separate detector. The particle size is then determined by comparing the pulse heights to a calibration curve generated with standard reference materials of known size. The data are presented on the basis of CIRCULAR EQUIVALENT DIAMETER. This analytical technique is summarized under ISO 21501-2:2007 Determination of particle size distribution --Single particle light interaction methods --Part 2: Light scattering liquid-borne particle counter and ISO 21501-3:2007 Determination of particle size distribution --Single particle light interaction methods --Part 3: Light extinction liquid-borne particle counter. All AccuSizer systems consist of a pulse height analyzer, fluidics module, and sensor. Pulse Height Analyzer Commonly referred to as the "counter box,· the pulse height analyzer converts pulses from the sensor into particle size. Fluldlcs Module Sensor AccuSizer pulse height analyzers are multichannel and can report results in up to 1024 size channels, providing excellent resolution. The fluidics module determines how sample is transported through the sensor. Multiple fluidics configurations are available at PTL: including auto-dilution, metered drain, and syringe injection. The most appropriate for your sample was selected depending on the particle concentration and other sample characteristics. Particles flowing through the sensor scatter and obscure laser light, creating pulses proportional to the particle size. Particles must pass the sensing zone one at a time to prevent what are known as coincidence errors. Hence, dilution in a clean, chemically compatible fluid is often required. While multiple sensor models are available for the AccuSizer, the most commonly used model at PTL is the LE400 sensor with a nominal range of 0.5 µm to 400 µm. Since SPOS analyzers are true particle COUNTERS, data can be reported in two formats -NUMBER (count or frequency) and VOLUME. For your reference, the data have been reported using both of these formats. The 1 0lh, 50lh, and 9Qlh percentiles on both the NUMBER and VOLUME basis are also summarized. These percentiles will indicate the particle size where the percentage of the distribution lies below. For example, a 901h percentile value of 1 O µm indicates that 90% of the distribution lies below 1 0 µm. Number (Count or Frequency) Data Your data will include a NUMBER WEIGHTED DIFFERENTIAL FREQUENCY histogram, which plots the percentage of particles detected versus the size of the particles detected, on a log scale. The particle size distribution (PSD) is constructed particle by particle meaning each particle has equal weighting. For instance, a 1 µm particle will have just as much impact on the distribution as a 100 µm particle. The number data are the primary output of the AccuSizer and are used to generate all other outputs. Since the instrument counts individual particles and a known volume of sample is analyzed, an accurate concentration value in units of particles/ml can be generated. Volume Data Your data will also include a DIFFERENTIAL VOLUME PERCENTAGE graph, which plots the volume-weighted percentage of particles detected versus the size of the particles detected, on a log scale. The volume data are generated by assuming each particle is spherical, converting the diameter into a spherical volume to give each particle a weighting relative to its volume. Since the volume of a particle increases proportionally to the diameter cubed (D3), the volume data are inherently weighted towards the larger particles and better represent where the bulk or mass of the system lies. For example, a spherical 1 µm particle will have a volume of 0.52 µm3 while a 100 µm spherical particle will have a volume of approximately 523,599 µm3. One would have to count roughly one million, 1 µm particles in order to contribute the same volume percentage as one, 100 µm particle. The volume distribution can be considered interchangeable with a mass distribution if all the particles can be assumed to have equivalent density. Channel Data Channel data are also provided, which present the data within each channel or bin in a tabular format. The diameter in micrometers, the number of particles detected of that size, the cumulative number of particles, number and volume percentages, and absolute volume values can be found in this section. For additional questions specific to your analysis results, please contact us directly. Ths report caifcmB to provisions cl 21 CrRpErt 11 1621&-C-post l1J'l report-01/02/202513:14:58-Page 2 <:J 4 Dlumlu Counts Cumulalhe Nlllllher Afta Volame Nunar Volume Ahl. Volwm Channel (pm) (#) (#:5DIL) (~ r~ (~ C-/4:5DIL) (o/e:5DIL) (,mr1) 87 1.643 1268 472189 0.3 0.4 0.1 94.9 3.3 2947.1 88 1.6% 1221 473410 01 0.4 0.1 951 3.4 3119.3 89 1.752 1163 474572 01 0.4 0.1 95.4 3.5 3271.7 90 1.810 1027 475599 0.2 OJ 0.1 95.6 3.5 3185.3 91 1.871 1040 476639 01 0.4 0.1 95.8 3.6 3565.6 92 1.935 1004 4n644 01 0.4 0.1 96.0 3.7 3813.4 93 2.004 843 478486 01 OJ 0.1 962 3.8 3552.7 94 2.on 846 479333 0.2 0.4 0.1 96.4 3.9 3969.3 95 2.153 n6 4&>109 01 0.4 0.1 96.5 4.0 4056.0 96 2.232 n8 4&>887 01 0.4 0.1 96.7 4.1 4528.8 97 2.314 764 481651 0.2 0.4 0.1 96.8 4.2 4960.5 98 2.400 695 482346 0.1 0.4 0.1 97.0 4.3 5026.7 99 2.489 667 483013 0.1 0.4 0.1 97.1 4.5 5387.8 100 2.582 640 483654 0.1 0.4 0.1 971 4.6 5767.5 101 2.678 659 484312 0.1 0.5 01 97.4 4.8 6625.3 102 2.n8 552 484864 0.1 0.4 0.1 97.5 4.9 6191.2 103 2.882 575 485440 0.1 0.5 01 97.6 5.1 7211.4 104 2.990 501 485940 0.1 0.5 01 97.7 5.3 7004.4 105 3.102 523 486463 0.1 0.5 01 97.8 5.5 8165.6 106 3118 431 486893 0.1 0.5 0.2 97.9 5.6 7512.5 107 3.338 492 487385 0.1 0.6 01 98.0 5.9 9578.1 108 3.462 460 487845 0.1 0.6 01 98.1 6.1 9983.9 109 3.590 405 488250 0.1 0.5 01 98.2 6.4 9818.1 110 3.723 453 488703 0.1 0.6 OJ 98.2 6.7 12236.3 Ill 3.860 409 489112 0.1 0.6 0.3 98.3 6.9 12303.4 112 4.001 470 489582 0.1 0.8 0.4 98.4 73 15759.2 113 4.146 390 489972 0.1 0.7 0.4 98.5 7.7 14552.9 114 4296 332 490304 0.1 0.6 0.3 98.6 8.0 13n9.3 115 4.449 335 490639 0.1 0.7 0.4 98.6 8.4 15465.1 116 4.606 361 491000 0.1 0.8 0.4 98.7 8.8 18470.6 117 4.767 318 491318 0.1 0.7 0.4 98.8 93 18059.9 118 4.931 332 491650 0.1 0.8 0.5 98.8 9.8 20847.4- 119 5.100 288 491938 0.1 0.8 0.5 98.9 10.3 19982.4 120 5.274 318 492256 0.1 0.9 0.6 99.0 10.9 24450.2 121 5.454 305 492561 0.1 0.9 0.6 99.0 11.5 25881.9 122 5.640 276 492837 0.1 0.9 0.6 99.l 12.1 25903.8 123 5.832 289 493126 0.1 1.0 0.7 99.1 128 30062.1 124 6.031 249 493375 0.0 0.9 0.7 991 13.5 28551.8 125 6.237 252 493627 0.1 1.0 0.8 99.2 14J 32004.4 126 6.449 240 493867 0.0 1.0 0.8 99.3 IS.I 33707.1 127 6.667 223 494090 0.0 1.0 0.8 99.3 16.0 34608.3 128 6.892 225 494315 0.0 I.I 0.9 99.4 16.9 38524.7 129 7.124 191 494505 0.0 1.0 0.9 99.4 17.8 36095.0 130 7.362 155 494660 0.0 0.9 0.8 99.4 18.5 32366.5 131 7.606 204 494865 0.0 1.2 I.I 99.5 19.7 47073.1 132 7.857 206 495071 0.0 1.3 l.3 99.5 20.9 52312.3 133 8.113 174 495244 0.0 11 11 99.6 22.1 48560.0 134 8.375 182 495426 0.0 IJ 1.4 99.6 23.5 56039.5 135 8.643 157 495583 0.0 1.2 1.3 99.6 24.8 52946.4 136 8.915 126 495709 0.0 1.0 I.I 99.7 25.9 46736.8 137 9.191 138 495847 0.0 1.2 1.4 99.7 27.2 56066.5 138 9.471 141 495988 0.0 1.3 1.5 99.7 28.8 62866.4 139 9.755 111 496099 0.0 I.I 1.3 99.7 30.1 53779.8 140 10.040 97 496196 0.0 1.0 1.2 99.8 31.3 51421.1 141 10.328 92 496288 0.0 1.0 1.3 99.8 32.6 53038.4- 142 10.623 68 496356 0.0 0.8 1.0 99.8 33.6 42740.6 143 10.923 72 496427 0.0 0.9 1.2 99.8 34.8 48788.5 144 11.229 70 496497 0.0 0.9 1.3 99.8 36.1 51741.6 145 11.540 65 496562 0.0 0.9 1.3 99.8 37.3 52064.6 146 11.859 49 496611 0.0 0.7 1.0 99.8 38.4 43112.7 147 12.184 66 496678 0.0 1.0 1.5 99.9 39.9 62875.0 Tns report confcrmi to proyisials ex 21 a=Rpart 11 16216-C-post IUl report-01/02/202513:14:58-Riga 3 ex 4 Channel Dlameler Counts Cumulalhe NIIIIUr Area Valame NwdJer Volune Abl.Valame (Jim) 00 (#~Dia.) (~ c-~ (o/ .. (%~Dia.) (o/e~DIL) <,mr1) 148 12S15 54 496732 0.0 0.9 1.4 99.9 41.2 559l26 149 12853 S8 496790 0.0 1.0 1.6 99.9 428 643S3.0 150 13.198 S3 496843 0.0 0.9 1.5 99.9 44J 63S29.9 ISi 13.S50 36 496879 0.0 0.7 I.I 99.9 45.S 46575.6 1S2 13.910 46 49692S 0.0 0.9 1.6 99.9 47.0 64781.5 153 14.278 34 496959 0.0 0.7 IJ 99.9 48.3 51892.5 154 14.654 34 4969()3 0.0 0.8 1.4 99.9 49.6 5(,()98.0 155 15,038 43 497035 0.0 1.0 1.8 99.9 51.5 75787.6 156 IS.432 34 497069 0.0 0.8 1.6 99.9 53.1 65515.4 157 15.834 31 497100 0.0 0.8 I.S 99.9 54.6 63703.8 158 16.247 22 497122 0.0 0.6 1.2 99.9 S5.8 49703.0 159 16.671 29 4971S1 0.0 0.8 1.7 99.9 S7.5 70217.8 J(i() 17.107 17 497168 0.0 o.s I.I 99.9 58.6 44625.5 161 17.554 17 497185 0.0 o.s 1.2 100.0 59.8 48220.7 162 18.015 27 497212 0.0 0.9 2.0 100.0 61.8 83391.0 163 18.490 27 497240 0.0 1.0 2.2 100.0 64.0 90164.0 164 18.981 12 497252 0.0 0.4 1.0 100.0 65.0 42670.6 165 19.488 19 497270 0.0 0.7 1.8 100.0 66.7 72577.S 166 20.014 12 497282 0.0 0.S 1.2 100.0 68.0 50022.2 167 20.555 19 497301 0.0 0.8 2.1 100.0 70.0 85163.6 168 21.112 9 4973()1} 0.0 0.4 1.0 100.0 71.0 41940.4 169 21.683 9 497318 0.0 0.4 I.I 100.0 72.1 45437.1 170 22269 7 497325 0.0 0.3 1.0 100.0 73.I 39377.1 171 22.870 5 497330 0.0 OJ 0.8 100.0 73.9 31990.7 172 23.488 7 497337 0.0 0.4 I.I 100.0 75.0 46202.7 173 24.121 9 497345 0.0 0.5 1.5 100.0 76.S 625S5.4 174 24.m 10 4973S5 0.0 0.6 2.0 100.0 78.S 81306.1 175 25.440 10 497366 0.0 0.7 2.1 100.0 80.6 88062.8 176 26.126 3 497369 0.0 0.2 0.8 100.0 81.4 31793.7 m 26.831 5 497374 0.0 0,4 1.3 100.0 82.6 51654.9 178 21.S55 5 497379 0.0 0.4 1.4 100.0 84.0 S5949.9 179 28.299 3 497383 0.0 OJ 1.0 100.0 84.9 40403.S 180 29.063 12 497395 0.0 1.0 3.7 100.0 88.7 l531!r7.2 181 29.849 9 497403 0.0 0.8 2.9 100.0 91.S 118540.7 182 30.658 0 497403 0.0 0.0 0.0 100.0 91.5 0.0 183 31.490 2 497405 0.0 0.2 0.7 100.0 92.2 27835.7 184 32.346 3 497408 0.0 0.4 1.5 100.0 93.7 (i()336J 185 33.227 3 497412 0.0 0.4 1.6 100.0 95.2 65404.9 186 34.136 2 497413 0.0 02 0.9 100.0 96.I 35457.9 187 35.072 0 497413 0.0 0.0 0.0 100.0 96.1 0.0 188 36.037 0 497413 0.0 0.0 0.0 100.0 96.1 0.0 189 37.033 2 497415 0.0 02 I.I 100.0 97.2 45274.1 190 38.062 0 497415 0.0 0.0 0.0 100.0 97.2 0.0 191 39.124 0 497415 0.0 0.0 0.0 100.0 97.2 0.0 192 40.223 3 497418 0.0 0.6 2.8 100.0 100.0 I l(i()25.0 193 41.361 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 194 42539 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 195 43.761 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 196 45.029 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 197 46.346 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 198 47.717 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 199 49.143 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 200 50.(i()8 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 201 52.083 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 202 53.559 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 203 55.040 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 204 56.529 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 205 58.033 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 206 59.557 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 207 61.109 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 208 62698 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 l1is report cooform; to provisions rJ 21 CfRpart 11 16216-C-post rl.J"I report-01/02/20'25 13:14:58 -Page 4 rJ 4 Diameter Counll Cumuladw NumlJer Ma Volume Number Volu-Ala. Volume Channel (pm) (ii) (#SDIL) <·~ <·~ (~ (°leSDIL) (%SOIL) cJIIII"> 2()1) 64.333 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 210 66.029 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 211 67.798 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 212 69.659 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 213 71.629 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 214 73.731 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 215 75.992 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 216 78.440 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 217 81.1()1) 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 218 84.036 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 219 87.266 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 220 90.846 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 221 94.832 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 222 99.286 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 223 104.178 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 224 109.399 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 225 114.910 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 226 120.724 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 227 126.854 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 228 133.313 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 229 140.114 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 230 147.273 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 231 154.801 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 232 162.714 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 233 171.024 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 234 179.746 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 235 188.893 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 236 198.4TI 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 237 208.513 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 238 219.010 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 239 229.981 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 240 241.435 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 241 253.382 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 242 265.828 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 243 278.TI9 0 497418 00 0.0 0.0 100.0 100.0 0.0 244 292.239 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 245 306.208 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 246 320.685 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 247 335.664 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 248 351.136 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 249 367.088 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 250 383.501 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 251 400.352 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 252 417.(i()9 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 253 435.235 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 254 453.183 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 255 471.398 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 256 490.282 0 497418 0.0 0.0 0.0 100.0 100.0 0.0 1ns report confcrns to i;rovisions cl 21 CfRpErt 11 16220-C-pest n.n report-01/0'2/202513:23:28-Page 2 cl 4 c.baanel Diameter c-u Cmmdadw N11a1er Arn Val11111e Number Val-Am.Val- (Jim) (II) (#!SOIL) (~ (~ ("~ (%.:SOIL) ("/4.:S Dia.) uua3) F,7 1.643 1163 396700 OJ 0.4 0.1 94.4 3.2 2701.9 88 1.696 1129 397828 OJ 0.4 0.1 94.7 3J 2884.3 89 1.752 1159 398988 OJ 0.4 0.1 94.9 3.4 3262.2 90 1.810 993 399980 0.2 0.4 0.1 95.2 3.4 3079.6 91 1.P!7I 1027 401007 0.2 0.4 0.1 95.4 3.5 3518.9 92 1.935 841 401848 02 0.4 0.1 95.6 3.6 3192.9 93 2.004 851 402699 0.2 0.4 0.1 95.8 3.7 3588.6 94 2.077 724 403423 02 0.4 0.1 96.0 3.8 3394.3 95 2.153 798 404221 0.2 0.4 0.1 962 3.9 4171.6 96 2.232 753 404974 02 0.4 0.1 96.4 4.0 4380.1 97 2.314 667 405641 0.2 0.4 0.1 96.5 4.2 4330.8 98 2.400 727 406368 02 0.5 0.1 96.7 4.3 5260.8 99 2.489 674 407042 02 0.5 0.1 96.8 4.4 54428 100 2.582 (HJ 407712 0.2 0.5 0.2 97.0 4.6 6028.3 101 2.678 531 408243 0.1 0.5 0.1 97.1 4.8 5341.3 102 2.778 526 40P!769 0.1 0.5 0.2 97J 4.9 5904.6 103 2.882 560 409329 0.1 0.6 02 97.4 5.1 7019.3 104 2.990 446 409775 0.1 0.5 0.2 97.5 5.3 6242.0 l05 3.102 497 410272 0.1 0.6 0.2 97.6 5.5 7766.6 106 3218 S55 410827 0.1 0.7 OJ 97.7 5.8 9680.1 107 3.338 409 411236 0.1 0.5 0.2 97.8 6.0 7954.1 108 3.462 458 411694 0.1 0.7 OJ 98.0 6.2 9947.0 109 3.590 380 412073 0.1 0.6 0.2 98.0 6.5 9199.3 110 3.723 414 412ffi 0.1 0.7 0.3 98.1 6.8 11178.3 111 3.860 3S8 412845 0.1 0.6 OJ 98.2 7.1 10765.5 112 4.001 393 413238 0.1 0.8 0.4 98.3 7.4 13189.7 113 4.146 358 413595 0.1 0.7 0.4 98.4 7.8 13345.4 114 4296 332 413927 0.1 0.7 0.4 98.5 8.2 13779.3 115 4.449 271 414198 0.1 0.6 0.3 98.5 8.5 12482.0 116 4.606 347 414545 0.1 0.9 0.5 98.6 9.0 lm3.6 11 7 4.767 288 414833 0.1 0.8 0.4 98.7 9.4 16321.5 118 4.931 33S 415168 0.1 1.0 0.6 98.8 10.0 21061.2 119 5.100 286 415455 0.1 0.9 0.5 98.8 10.5 19864.1 120 5274 295 415749 0.1 1.0 0.6 98.9 11.2 22619.7 121 S.454 279 416028 0.1 1.0 0.6 99.0 11.8 23713.0 122 5.640 237 416265 0.1 0.9 0.6 99.0 12.4 22226.1 123 5.832 230 416495 0.1 0.9 0.6 99.1 Ill 23872.8 124 6.031 237 416731 0.1 1.0 0.7 992 13.8 27182.9 125 6.237 232 416963 0.1 I.I 0.8 99.2 14.6 29409.4 126 6.449 199 417162 0.0 1.0 0.8 99.3 15.3 27969.7 127 6.667 237 417399 0.1 1.3 1.0 99.3 16.3 36721.8 128 6.892 174 417572 0.0 1.0 0.8 99.4 17.2 29769.1 129 7.124 191 417763 0.0 1.2 1.0 99.4 18.1 360')5.0 130 7.362 172 417935 0.0 I.I 1.0 99.4 19.1 359232 131 7.606 194 418129 0.0 IJ 1.2 99.5 20.3 44719.4 132 7.857 157 418286 0.0 1.2 I.I 99.5 21.4 39774.7 133 8.113 152 418437 0.0 1.2 I.I 99.6 22.5 42371.0 134 8.375 133 418570 0.0 LI I.I 99.6 23.7 40851.2 135 8.643 107 418677 0.0 1.0 1.0 99.6 24.6 36256.8 136 8.915 129 418807 0.0 1.2 1.3 99.6 25.9 47999.9 137 9.191 129 418936 0.0 1.3 1.4 99.7 27.4 52605.6 138 9.471 109 419045 0.0 1.2 1.3 99.7 28.7 48475.3 139 9.755 126 419171 0.0 1.4 1.7 99.7 30.3 61226.3 140 10.040 100 419272 0.0 1.2 1.4 99.8 31.8 53225.4 141 10.328 66 419338 0.0 0.8 1.0 99.8 32.8 38305.5 142 10.623 89 419426 0.0 1.2 1.5 99.8 34.3 55562.8 143 10.923 89 419515 0.0 1.3 1.6 99.8 36.0 60404.8 144 11.229 58 419573 0.0 0.9 1.2 99.8 37.l 42907.6 145 11.540 63 419636 0.0 1.0 1.4 99.8 38.5 50694.5 146 11.859 58 419694 0.0 1.0 1.4 99.9 39.9 50545.9 147 12.184 72 419765 00 1.3 1.8 99.9 41.7 67711.5 Ttis repat confam; to provisions rl 21 Cffipa111 16220-C-post M repat-01/W202513:23:28 -AIQ8 3 rl 4 Oiannel Diameter C-Cs Cumulatlw Nadler Area Volume Number Volwm Alli. Volmne (Jim) (#) (#SDIL) (~ (~ r~ (o/eSDIL) (%SDIL) c,imJ) 148 12.515 51 419816 0.0 1.0 1.4 99.9 43.1 52418.0 149 12.853 41 419857 0.0 0.8 1.2 99.9 44.4 45425.6 150 13.198 36 419893 0.0 0.7 1.2 99.9 45.5 43036.4 151 13.550 48 419941 0.0 1.0 1.7 99.9 47.2 62100.8 152 13.910 32 419973 0.0 0.7 1.2 99.9 48.5 45586.9 153 14.278 17 419990 0.0 0.4 0.7 99.9 49.2 25946.2 154 14.654 37 420027 0.0 1.0 1.7 99.9 50.8 61707.8 155 15.038 27 420055 0.0 0.7 1.3 99.9 522 48504.1 156 15.432 17 420072 0.0 0.5 0.9 99.9 53.0 327S7.7 1S7 15.834 19 420090 0.0 0.6 I.I 100.0 54.1 38930.1 158 16.247 26 420116 0.0 0.8 1.6 100.0 S5.7 57349.7 159 16.671 22 420138 0.0 0.7 I.S 100.0 57.1 536%.0 ltiO 17.107 IS 4201S3 0.0 0.5 I.I 100.0 58.2 40163.0 161 17.S54 IS 420169 0.0 0.6 1.2 100.0 59.4 43398.7 162 18.015 14 420182 0.0 0.5 I.I 100.0 ro.5 41695.S 163 18.490 5 420187 0.0 0.2 0.5 100.0 61.0 16905.8 164 18.981 7 420194 0.0 0.3 0.7 100.0 61.6 24383.2 165 19.488 9 420203 0.0 0.4 0.9 100.0 625 32989.8 166 20.014 9 420211 0.0 0.4 1.0 100.0 61S 3S730.2 167 20.5S5 7 420218 0.0 0.3 0.8 100.0 64.3 30068.6 168 21.112 9 420227 0.0 o.s I.I 100.0 65.S 41940.4 169 21.683 5 420232 0.0 0.3 0.7 100.0 66.2 27262.3 170 22.269 5 420237 0.0 0.3 0.8 100.0 67.0 29532.8 171 22870 2 420239 0.0 0.1 0.3 100.0 67.3 10663.6 172 23.488 3 420242 0.0 0.2 0.6 100.0 67.9 23101.4 173 24.121 5 420247 0.0 0.4 1.0 100.0 68.9 37533.2 174 24.m 9 420256 0.0 0.6 1.8 100.0 70.8 67755.1 175 25.440 2 420257 0.0 0.1 0.4 100.0 71.2 14677.1 176 26.126 5 420262 0.0 0.4 1.3 100.0 12.S 47690.6 177 26.831 0 420262 0.0 0.0 0.0 100.0 12.S 0.0 178 27.555 0 420262 0.0 0.0 0.0 100.0 725 0.0 179 28.299 2 420264 0.0 0.2 0.S 100.0 73.0 20201.7 180 29.063 3 420267 0.0 0.3 1.2 100.0 74.2 43767.8 181 29.849 3 420271 0.0 0.4 1.3 100.0 75.5 47416.3 182 30.658 2 420273 0.0 0.2 0.7 100.0 76.2 25687.4 183 31.490 3 420276 0.0 0.4 1.5 100.0 77.7 55671.4 184 32.346 2 420278 0.0 0.2 0.8 100.0 78.5 30168.2 185 33.227 3 420281 0.0 0.4 1.8 100.0 80.3 65404.9 186 34.136 2 420283 0.0 0.2 1.0 100.0 81.3 35457.9 187 35.072 0 420283 0.0 0.0 0.0 100.0 81.3 0.0 188 36.037 2 420285 0.0 0.3 I.I 100.0 82.4 41718.6 189 37.033 0 420285 0.0 0.0 0.0 100.0 82.4 0.0 190 38.062 0 420285 0.0 0.0 0.0 100.0 82.4 0.0 191 39.124 2 420286 0.0 0.3 1.4 100.0 83.8 53386.0 192 40.223 0 420286 0.0 0.0 0.0 100.0 83.8 0.0 193 41.361 2 420288 0.0 0.3 1.7 100.0 85.5 63074.6 194 42.539 0 420288 0.0 0.0 0.0 100.0 85.S 0.0 195 43.761 2 420290 0.0 0.4 20 100.0 87.6 74703.4 196 45.029 2 420291 0.0 0.4 2.2 100.0 89.8 81387.8 197 46.346 0 420291 0.0 0.0 0.0 100.0 89.8 0.0 198 47.717 2 420293 0.0 0.5 2.6 100.0 92.4 96849.5 199 49.143 2 42029S 0.0 0.S 2.9 100.0 95.3 105798.3 200 50.608 0 420295 0.0 0.0 00 100.0 95.3 0.0 201 52.083 0 420295 0.0 0.0 0.0 100.0 95.3 0.0 202 53.559 0 420295 0.0 0.0 0.0 100.0 95.3 0.0 203 55.040 0 420295 0.0 0.0 0.0 100.0 95.3 0.0 204 56.529 0 420295 0.0 0.0 0.0 100.0 95.3 0.0 205 58.033 2 420296 00 0.7 4.7 100.0 100.0 174227.8 206 59.557 0 420296 00 0.0 0.0 100.0 100.0 0.0 207 61.109 0 420296 0.0 0.0 0.0 100.0 100.0 00 208 62.698 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 1ns report cataTTB to provisions r:i 21 CFRp:n 11 16220-C-post ru, report-01/02/202513:Z3:28-Riga 4 r:i 4 Diameter Ceunb Cumulathe Number Affa Volume Nunar Volume Abs. Volume Channel ()am) (#) (#:5,DIL) (9/~ (~ r1~ (8/4:SDIL) (8/e:5,DIL) CJun1) 2()1) 64.333 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 210 66.029 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 211 67.798 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 212 69.659 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 213 71.629 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 214 73.731 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 21S 7S.992 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 216 78.440 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 217 81.109 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 218 84.036 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 219 87.266 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 220 90.846 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 221 94.832 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 222 99.286 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 223 104.178 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 224 109.399 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 22S 114.910 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 226 120.724 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 227 126.854 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 228 133.313 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 229 140.114 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 230 147173 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 231 1S4.801 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 232 162.714 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 233 171.024 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 234 179.746 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 235 188.893 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 236 198.4n 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 237 208.S13 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 238 219.010 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 239 229.981 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 240 241.43S 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 241 253.382 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 242 265.828 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 243 278.779 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 244 292.239 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 24S 306108 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 246 320.685 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 247 33S.664 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 248 3S1.136 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 249 367.088 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 250 383.SOI 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 251 400.3S2 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 252 417.li09 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 253 43S13S 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 254 4S3.183 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 25S 471.398 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 256 490182 0 420296 0.0 0.0 0.0 100.0 100.0 0.0 Ths report coofoors to provisions ri 21 a=Rpa-t 11 17294-C-post n.l'l report-01/02/202513:38:53-Rige 2 a 4 Owmel Dlamelllr C-ts Cumuladw Nwnber Area Volume NIIIIDr Volume AIII.. Volume (pm) (#) (#SDIL) ("~ (~ (~ ("/4SDIL) ("/oSDIL) (Jlnr') 87 1.643 1144 398436 OJ 0.4 0.1 94.9 4.7 2658.3 88 1.696 1030 399466 0.2 0.4 0.1 95.2 4.8 26320 89 1.752 1079 400546 OJ 0.5 0.1 95.4 4.9 3037.0 90 1.810 965 401511 0.2 0.4 0.1 95.7 5.1 2995.1 91 1.871 884 402395 0.2 0.4 0.1 95.9 5.2 3028.7 92 1.935 m 403166 0.2 0.4 0.1 96.0 5.3 2927.9 93 2.004 788 403954 0.2 0.4 0.1 96.2 5.4 3323.1 94 2.077 710 404664 0.2 0.4 0.1 96.4 5.6 3330.4 95 2.153 739 405403 0.2 0.5 0.2 96.6 5.7 38(i().3 96 2.232 759 406162 0.2 0.5 0.2 96.8 5.9 4419.8 97 2.314 628 406790 0.1 0.5 0.2 96.9 6.1 4076.7 98 2.400 555 407345 0.1 0.5 0.2 97.0 6.2 4016.5 99 2.489 581 407926 0.1 0.5 0.2 97.2 6.4 4686.9 100 2.582 574 408500 0.1 0.5 0.2 97.3 6.6 5169.3 IOI 2.678 538 409038 0.1 0.5 0.2 97.4 6.9 540'J.8 102 2.778 521 409559 0.1 0.6 0.2 97.6 7.1 5847J 103 2.882 516 410075 0.1 0.6 OJ 97.7 7.4 6464.6 104 2.990 514 410589 0.1 0.6 0.3 97.8 7.7 7194.9 105 3.102 465 411054 0.1 0.6 0.3 97.9 8.0 7261.3 106 3.218 429 411483 0.1 0.6 0.3 98.0 8.3 7482.8 107 3.338 392 411874 0.1 0.6 0.3 98.1 8.6 7622.7 108 3.462 373 412247 0.1 0.6 0.3 98.2 8.9 8()C)8.I 109 3.590 390 412637 0.1 0.7 0.4 98.3 9.3 9446.8 110 3.723 369 413006 0.1 0.7 0.4 98.4 9.7 9982.2 111 3.S(i() 369 413376 0.1 0.8 0.5 98.5 10.2 11124.3 112 4.001 317 413692 0.1 0.7 0.4 98.6 10.6 10620.3 113 4.146 310 414002 0.1 0.8 0.5 98.6 II.I 11566.0 114 4.296 303 414305 0.1 0.8 0.5 98.7 11.6 12578.1 115 4.449 293 414598 0.1 0.8 0.6 98.8 12.1 13502.5 116 4.606 320 414918 0.1 1.0 0.7 98.8 12.8 16379.6 117 4.767 310 415228 0.1 1.0 0.7 98.9 13.5 17577.0 118 4.931 271 415499 0.1 0.9 0.7 99.0 14.2 16998.7 119 5.100 247 415746 0.1 0.9 0.7 99.0 14.9 17144.6 120 5.274 271 416016 0.1 I.I 0.9 99.I 15.8 20789.2 121 5.454 243 416260 0.1 1.0 0.8 99.2 16.6 20676.6 122 5.640 174 416433 0.0 0.8 0.7 99.2 17.3 16309.8 123 5.832 203 416636 0.0 1.0 0.9 99.3 18.2 21043.4 124 6.031 225 416861 0.1 1.2 I.I 99.3 19.2 25814.0 125 6.237 206 417067 0.0 I.I I.I 99.4 20.3 26165.8 126 6.449 203 417269 0.0 1.2 1.2 99.4 21.5 28447.8 127 6.667 150 417419 0.0 0.9 1.0 99.4 22.4 23248.3 128 6.892 184 417603 0.0 1.2 1.3 99.5 23.7 31520.2 129 7.124 165 4tn68 0.0 1.2 1.3 99.5 25.0 31260.9 130 7.362 131 417899 0.0 1.0 I.I 99.6 26.I 27387.0 131 7.606 157 418056 0.0 1.3 1.5 99.6 27.6 36089.4 132 7.857 155 418211 0.0 1.3 1.6 99.6 29.2 39342.3 133 8.113 148 418359 0.0 1.4 1.7 99.7 30.9 41418.8 134 8.375 121 418480 0.0 1.2 1.5 99.7 32.4 37185.1 135 8.643 106 418585 0.0 I.I 1.5 99.7 33.9 35681.3 136 8.915 99 418684 0.0 I.I 1.5 99.7 35.4 36631.5 137 9.191 95 418780 00 I.I 1.6 99.8 37.0 38762.0 138 9.471 Ill 418890 0.0 1.4 2.0 99.8 39.0 49232.7 139 9.755 90 418980 0.0 1.2 1.8 99.8 40.8 43851.2 140 10.040 68 419049 0.0 1.0 1.5 99.8 42.3 36085.0 141 10.328 77 419125 0.0 1.2 l.8 99.8 44.1 44198.7 142 10.623 75 419200 0.0 1.2 1.9 99.9 46.0 47014.7 143 10.923 51 419251 0.0 0.9 1.4 99.9 47.4 34848.9 144 11.229 46 419297 00 0.8 1.4 99.9 48.8 34073.7 145 11.540 32 419329 00 0.6 I.I 99.9 49.9 26032.3 146 11.859 31 419360 0.0 0.6 I.I 99.9 51.0 26759.6 147 12184 41 419401 0.0 0.9 1.6 99.9 52.6 38692.3 This report conforrrs to !X'OVisions r:J 21 CfRpart 11 17294-C-post run report-01/W2<Y.2513:38:53 -Riga 3 r:J 4 Chaanel Diameter Canis Clmmladw NIIIIDr Area Volume Number Volwne Alli. Volume (pm) (#) (#SOIL) <·~ (~ (~ C-1.SDIL) (o/eSDIL) <Jua3) 148 12515 31 419432 0.0 0.7 1.3 9'J.9 53.9 314.50.8 149 12853 41 419472 0.0 1.0 1.9 9'J.9 55.7 45425.6 I.SO 13.198 19 419491 0.0 0.5 0.9 9'J.9 56.6 22542.9 ISi 13.5.SO 36 419527 0.0 0.9 1.9 9'J.9 58.6 46575.6 152 13.910 22 419549 0.0 0.6 1.3 9'J.9 59.8 31191.1 153 14.278 24 419573 0.0 0.7 1.5 100.0 61.3 36324.7 154 14.654 15 419588 0.0 0.5 1.0 100.0 62.4 25244.1 155 15.038 20 419fffi 0.0 0.7 l.S 100.0 63.8 36378.1 156 15.432 10 419619 0.0 0.3 0.8 100.0 64.6 19654.6 157 15.834 15 419634 0.0 0.5 1.3 100.0 li6.0 31851.9 158 16.247 10 419644 0.0 0.4 0.9 100.0 li6.9 22939.9 159 16.671 5 419649 0.0 02 0.5 100.0 67.4 12391.4 I(,() 17.107 14 419663 0.0 0.6 1.5 100.0 68.9 35700.4 161 17.554 7 419670 0.0 0.3 0.8 100.0 (IJ.7 19288.3 162 18.015 7 4196n 0.0 0.3 0.9 100.0 70.5 20847.8 163 18.490 12 419689 0.0 0.6 1.6 100,0 72.1 39446.8 164 18.981 7 419<65 0.0 0.3 1.0 100.0 73.I 243832 165 19.488 10 419706 0.0 0.5 1.6 100.0 74.7 39587.7 lli6 20.014 9 419714 0.0 0.5 1.5 100.0 762 35730.2 167 20.555 9 419723 0.0 0.5 1.6 100.0 n.s 38710.7 168 21.112 9 419731 0.0 0.5 1.7 100.0 79.5 41940.4 169 21.683 5 419736 0.0 0.3 I.I 100.0 80.6 m62.3 170 22269 2 419738 0.0 0.1 0.4 100.0 81.0 9844.3 171 22870 0 419738 0.0 0.0 0.0 100.0 81.0 0.0 172 23,488 0 419738 0.0 0,0 0.0 100.0 81.0 0.0 173 24.121 0 419738 0.0 0,0 0.0 100.0 81.0 0,0 174 24.m 2 419740 0.0 0.1 0.6 100.0 81.6 13551.0 175 25.440 7 419747 0.0 0.6 2.4 100.0 84.0 58708.6 176 26.126 7 419753 0.0 0.7 2.6 100.0 86.6 63587.5 m 26.831 3 419757 0.0 0.3 1.4 100.0 88.0 34436.6 178 27.555 0 419757 0.0 0.0 0.0 100.0 88.0 0.0 179 28.29') 0 419757 0,0 0.0 0.0 100.0 88.0 0.0 180 29.063 0 419757 0,0 0.0 0.0 100.0 88.0 0.0 181 29.849 2 419758 0,0 02 1.0 100.0 89.0 23708, I 182 30.658 3 419762 0.0 0.5 2.1 100.0 91.1 51374.9 183 31.490 2 419764 0.0 0.2 I.I 100.0 92.2 27835.7 184 32346 2 419765 0.0 0.3 1.2 100.0 93.5 30168.2 185 33.227 0 419765 0.0 0.0 0.0 100.0 93.5 0,0 186 34.136 0 419765 0.0 0.0 0.0 100.0 93.5 0,0 187 35.072 2 419767 0.0 0.3 1.6 100.0 95.0 38455.5 188 36.037 0 419767 0.0 0.0 0.0 100.0 95.0 0.0 189 37,033 0 419767 0.0 0.0 0,0 100.0 95.0 0.0 190 38.062 0 419767 0.0 00 0.0 100.0 95.0 0.0 191 39.124 0 419767 0.0 00 0,0 100.0 95.0 0.0 192 40.223 2 419769 0.0 0.4 2.4 100.0 97,4 58012.5 193 41.361 2 419no 0.0 0,4 26 100.0 100.0 63074.6 194 42539 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 195 43.761 0 419770 0.0 0.0 0.0 100.0 100.0 0.0 196 45.029 0 419770 0.0 0.0 0.0 100.0 100.0 0.0 197 46.346 0 419no 0,0 0.0 0.0 100.0 100.0 0.0 198 47.717 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 199 49.143 0 419770 0.0 0.0 0.0 100.0 100.0 0.0 200 50.f,()8 0 4l9n0 0.0 0.0 0.0 100.0 100.0 0.0 201 52.083 0 4l9nO 0.0 0.0 0.0 100.0 100.0 0.0 202 53.559 0 419n0 0.0 0.0 0.0 100,0 100.0 0,0 203 55.040 0 419n0 0.0 0.0 0.0 100,0 100.0 0.0 204 56.529 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 205 58.033 0 4l9n0 0.0 0.0 0.0 100.0 100.0 0.0 206 59.557 0 4l9n0 0.0 0.0 0.0 100.0 100.0 0.0 207 61.109 0 419no 0.0 0.0 0.0 100.0 100.0 0,0 208 62698 0 4l9n0 0,0 0.0 0.0 100.0 100.0 0,0 1ns report ca,foms to provisions of 21 a=Rpet 11 17294-C-post IUl report-01/02/202513:38:53 -Rlge 4 of 4 Cluumel Diameter Counts Cumulathe Nwmer Area Volume Number Volume AbL Vol- (pm) (#) (#SOIL) (1/ .. (o/ .. (~ (o/eSDIL) {9/eSDIL) ~ 2()1} 64.333 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 210 66.029 0 419no 0.0 0.0 0.0 100.0 100.0 0.0 211 67.798 0 419'n0 00 0.0 00 100.0 100.0 0.0 212 69.659 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 213 71.629 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 214 73.731 0 419no 0.0 0.0 0.0 100.0 100.0 0.0 215 75.992 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 216 78.440 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 217 81.109 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 218 84.036 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 219 87.266 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 220 90.846 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 221 94.832 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 222 99.286 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 223 104.178 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 224 109.399 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 225 114.910 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 226 120.724 0 419no 0.0 0.0 0.0 100.0 100.0 0.0 227 126.854 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 228 133.313 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 229 140.114 0 419no 0.0 0.0 0.0 100.0 100.0 0.0 230 147273 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 231 154.801 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 232 162.714 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 233 171.024 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 234 179.746 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 235 188.893 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 236 198.4n 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 237 208.513 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 238 219.010 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 239 229.981 0 419'n0 00 00 0.0 100.0 100.0 0.0 240 241.435 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 241 253.382 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 242 265.828 0 419'n0 0.0 0.0 0.0 100.0 100.0 00 243 278.779 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 244 292.239 0 419no 0.0 0.0 0.0 100.0 100.0 0.0 245 306.208 0 419nO 0.0 0.0 0.0 100.0 100.0 0.0 246 320.685 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 247 335.664 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 248 351.136 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 249 367.088 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 250 383.501 0 419'n0 00 0.0 0.0 100.0 100.0 0.0 251 400.352 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 252 417.609 0 419n0 0.0 0.0 0.0 100.0 100.0 0.0 253 435.235 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 254 453.183 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 255 471.398 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 256 490.282 0 419'n0 0.0 0.0 0.0 100.0 100.0 0.0 Appendix D ,=- Alllance DGM Calibration-Orifices . Issuing Department Tech Services Equipment Detail -Dry Gas Meter Console ID: M5-27 Meter 5/N: 20035543 Critical Orifice 5/N: VH 40-73 Calibration Detail Initial Barometric Pressure, in. Hg (Pb1) Final Barometric Pressure, in. Hg (PbF) Average Barometric Pressure, in. Hg (Pb) Critifcal Orifice ID (Y) VH-73 K' Factor, ft3·R112 /in.WC-min (K') 0.7915 Vacuum Pressure, in. Hg (Vp) 14.5 Initial DGM Volume, ft3 (Vm1) 939.800 Final DGM Volume, ft3 (VmF) 947.046 Total DGM Volume, ft3 (Vm) 7.246 Ambient Temperature, "F (Ta) 82 Initial DGM Temperature, °F (Tm1) 82 Final DGM Temperature, °F (TmF) 83 Averaqe DGM Temperature, "F (Tm) 83 Elapsed Time (0) 700 Meter Orifice Pressure, in. WC (LIH) 270 Standard Meter volume, ft3 (Vmstd) 6.0819 Standard Critical Orifice Volume, ft3 (Ver) 6.0942 Meter Correction Factor (Y) 1.002 Tolerance --0.001 Orifice Calibration Value (LIH @) 1.682 Tolerance -· 0.005 Orifice Cal Check -· 0.33 Meter Correction Factor (Y) Orifice Calibration Value (LIH @) Positive Pressure Leak Check Equipment Detail -Thermocouple Sensor Reference Calibrator Make: Practical Instrument Electronics Reference Calibrator Model: Piecal 520B Reference Calibrator 5/N: 121645 Calibration Detail Reference Temp. Display Temp. OF OR OF OR 0 460 0 460 68 528 66 526 100 560 98 558 223 683 223 683 248 708 248 708 273 733 273 733 300 760 300 760 400 860 398 858 500 960 497 957 600 1,060 599 1,059 700 1,160 700 1,160 800 1,260 800 1,260 900 1,360 900 1,360 1,000 1,460 1,000 1,460 1,100 1,560 1,100 1,560 1,200 1,660 1,200 1,660 Personnel VH-73 VH-63 0.7915 0.6091 14.5 16.0 947.700 956.600 954.950 962.934 7.250 6.334 83 83 83 83 83 83 83 83 7.00 8.00 2.70 1.60 6.0797 5.2949 6.0885 5.3548 1.001 1.011 0.001 0.009 1.683 1.679 0.004 0.008 Accuracy Absolute Difference % OF 0.0 0 0.4 2 0.4 2 0.0 0 0.0 0 0.0 0 0.0 0 0.2 2 0.3 3 0.1 1 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 25.60 25.60 25.60 0.36 1.003 1.687 Yes Calibration By: _X_a_nd_e_r_K_ra_h_n ______________ _ Calibration Date: 10/4/2024 --------------------Reviewed By: Charles Horton Document ID 620.004 Revision 24.0 Effective Date 1/31/24 Page 1 o/1 VH-63 VH-55 VH-55 0.609 0.4433 0.443 16.0 17.5 17.5 962.900 970.800 977.804 969.313 977.804 984.815 6.413 7.004 7.011 83 84 84 83 84 84 83 84 85 83 84 85 8.00 12.00 12-□0 1.60 0.86 0.86 5.3609 5.8318 5.8323 5.3548 5.8404 5.8404 0.999 1.001 1.001 0.004 0.001 0001 1.679 1.700 1.699 0.008 0.013 0.012 0.36 Appendix E FCU FRESH FEED TO RX FCU FRESH Start Time Finish Time FEED TO RX F100202.pv BPD Run#1 11/21/24 11 :50 AM 11/21/24 1:15 PM 28,978 Run#2 11/21/24 2:45 PM 11/21/24 4:12 PM 29,010 Run#3 11/21/24 5:45 PM 11/21/24 6:57 PM 28,956 AVERAGE: 28,981 Last Page of Report UT/1rl DFP/\ RTMFNT OF E'IVIROflMCN!~y ( DIVISION OF AIR QUALITY ___________ ___, ' Introduction Summary of Results I :: Alliar.ce TECHNICAL GROUP Source Test Report Testing Methodology If the pollutant concentration at each traverse point did not differ more than 5 percent or 0.5 ppmv/0.3% (whichever was less restrictive) of the average pollutant concentration, then single point sampling was conducted during the test runs. If the pollutant concentration did not meet these specifications but differed less than 10 percent or 1.0 ppmv/0.5% from the average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in diameter -16.7, 50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter -0.4, 1.0, and 2.0 meters from the stack wall). If the pollutant concentration differed by more than IO percent or 1.0 ppmv/0.5% from the average concentration, then sampling was conducted at a minimum of twelve (12) traverse points. Copies of stratification check data can be found in the Quality Assurance/Quality Control Appendix. An NO2 -NO converter check was performed on the analyzer prior to initiating testing. An approximately 50 ppm nitrogen dioxide cylinder gas was introduced directly to the NOx analyzer and the instrument response was recorded in an electronic data sheet. The instrument response was within+/-IO percent of the cylinder concentration. A Data Acquisition System with battery backup was used to record the instrument response in one (1) minute averages. The data was continuously stored as a * .CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. AST-2024-4117 MPC -Salt Lake City, UT Page 3-3 Appendix A Appendix B { ;- Al I ia nce Run 1 -RM Data C: I " i-' Location: MPC-Tesoro -Salt Lake City Refmery, UT Source: East Cogeneration Unit (CG!) Project No.: AST-202~ 117 Date: 11/20/24 Time 0,-0utlet CO,-Outlet NOx-Outlet Unit "lo dry %dry ppmvd Status Valid Valid Valid Uncorrected Run Average (C...) 7.61 7.75 29.08 Cal Gu Concentration (C...J 6.00 6.00 50.00 Pretell System Zero Retponae 0.23 --0.03 0.54 Polltett System Zero Retponse 0.23 --0.04 0.56 Average Zero Retponte (Co) 0.23 --0.04 0.55 Pretest System Cal Retponse 6.23 5.91 47.64 Po1ttest System Cal Re1pon1e 6.25 5.89 48.80 Average Cal Respon1e (C..) 6.24 5.90 48.22 Corrected Run Avera e Corr 7.36 7.87 29.92 10:45 7.83 7.55 28.68 10:46 7.85 7.54 28.82 10:47 7.85 7.55 28.33 10:48 7.85 7.56 28.51 10:49 7.84 7.56 28.28 10:50 7.76 7.61 28.36 10:51 7.72 7.65 28.S3 10:52 7.73 7.64 28.5S 10:53 7.78 7.63 28.62 10:54 7.74 7.64 29.06 10:55 7.75 7.68 28.9S 10:56 7.73 7.67 32.35 10:57 7.79 7.67 30.51 10:58 7.77 7.68 35.31 10:59 7.75 7.68 30.7S 11:00 7.72 7.71 29.S7 11:01 7.70 7.72 29.66 11:02 7.64 7.75 29.54 11:03 7.62 7.76 29.15 11:04 7.58 7.79 29.31 11:05 7.58 7.79 29.95 11:06 1.56 7.80 29.Sl 11:07 7.55 7.81 29.14 11:08 7.57 7.78 28.87 11:09 7.55 7.79 28.74 11:10 7.53 7.79 28.78 11:11 7.55 7.78 28.76 11:12 7.55 7.77 28.76 11:13 7.57 7.77 28.63 11:14 7.49 7.82 28.67 11:15 7.47 7.8S 29.03 11:16 7.45 7.8S 29.01 11:17 7.46 7.85 29.01 11:18 7.44 7.84 28.99 11:19 7.47 7.84 28.97 11 :20 7.45 7.84 28.97 11:21 7.52 7.81 28.86 11:22 7.58 7.77 28.67 11:23 7.56 7.77 28.55 11 :24 7.56 7.77 28.62 11 :25 7.52 7.78 28.71 11:26 7.49 7.82 28.92 11:27 7.47 7.84 28.88 11 :28 7.46 7.84 28.88 11 :29 7.47 7.84 28.88 11:30 7.45 7.8S 28.93 11:31 7.53 7.80 28.99 11:32 7.58 7.76 28.76 11:33 7.62 7.74 28.71 11:34 7.67 7.72 28.53 11:35 7.67 7.72 28.48 11:36 7.63 7.73 28.48 11:37 7.56 7.79 28.77 11:38 7.53 7.81 28.84 11:39 7.45 1.8S 29.07 11:40 7.46 7.84 29.05 11:41 7.55 7,78 28.88 11:42 7.60 7.74 28.66 11:43 7.60 7.73 28.59 11:44 7.61 7.73 28.48 f _:- Alliance T [ C 11 IC l, R ( l r Locadon: MPC-Tesoro -Salt Lake City Refinery, lIT Source: East Cogeneration Unit (CG!) Project No.: AST-2024-4117 Date: 11/20/24 Time Unit Stam Uncorrected Run Averqe (C...) Cal Gu Concentradon (CM.J Pretest System Zero Response Posttest System Zero Response Average Zero Response (Co) Pretest System Cal Response Posttett Sy,otem Cal Reoponse Averaee Cal Reoponae (CJIC! Corrected Ran Anra e Corr 12:12 12:13 12:14 12:15 12:16 12:17 12:18 12:19 12:20 12:21 12:22 12:23 12:24 12:25 12:26 12:27 12:28 12:29 12:30 12:31 12:32 12:33 12:34 12:35 12:36 12:37 12:38 12:39 12:40 12:41 12:42 12:43 12:44 12:45 12:46 12:47 12:48 12:49 12:50 12:51 12:52 12:53 12:54 12:55 12:56 12:57 12:58 12:59 13:00 13:01 13:02 13:03 13:04 13:0S 13:06 13:07 13:08 13:09 13:10 13:11 0,-0utlet "lo dry Valid 7.59 6.00 0.23 0.34 0.29 6.25 6.38 6.32 7.27 7.44 7.46 7.51 7.63 7.62 7.58 7.59 7.59 7.48 7.45 7.51 7.46 7.44 7.53 7.60 7.60 7.59 7.57 7.56 7.54 7.65 7.65 7.64 7.63 7.61 7.57 7.56 7.63 7.62 7.65 7.66 7.66 7.56 7.55 7.57 7.56 7.55 7.53 7.54 1.55 7.54 7.54 7.64 7.67 7.68 7.61 7.57 7.64 7.64 7.69 7.71 7.71 7.63 7.60 7.62 7.60 7.66 7.72 7.63 7.56 Run 2 -RM Data CO,-Outlet NO-.-Outlet %dry ppmvd Valid Valid 7.78 28.58 6.00 50.00 --0.04 0.56 0.00 0.15 --0.02 0.36 5.89 48.80 5.90 48.15 5.90 48.48 7.91 29.32 7.80 28.28 7.80 27.97 7.79 27.99 7.74 28.68 7.72 27.89 7.72 27.52 7.71 27.47 7.74 27.56 7.81 28.23 7.83 28.11 7.83 28.56 7.83 28.58 7.84 28.06 7.80 27.97 7.76 28.14 7.75 28.43 7.74 27.73 7.75 27.67 7.78 27.82 7.80 28.11 7.81 31.67 7.79 34.32 7.81 28.47 7.80 30.25 7.80 28.05 7.81 27.72 7.82 27.73 7.77 27.73 7.77 27.69 7.76 29.49 7.75 28.21 7.75 27.78 7.80 27.75 7.82 28.17 7.82 29.36 7.82 28.64 7.82 28.32 7.83 28.42 7.83 28.36 7.84 29.82 7.84 29.12 7.83 28,53 7.76 28.32 7.74 28.22 7.74 28.21 7.81 30.46 7.82 29.82 7.76 28.67 7.76 28.36 7.73 28.38 7.70 28.26 7.70 28.17 7.75 28.28 7.79 28.72 7.77 31.42 7.78 28.91 7.73 28.72 7.69 28.23 7.74 28.34 7.80 28.78 ~ ;' Alliance T E I r,J I \ L r l r Location: MPC-Tesoro -Salt Lake City Refinery, UT Project No.: AST-2024-4117 FUEL FACTOR CALCULATION BASED ON FUEL ANALYSIS Run 1 COMPONENT MW MOLEo/e MOLESC MOLESH MOLESO MOLESN MOLESS HYDROGEN 2.016 27.311 -54.622 ------ HELIUM 4.003 -----__ , -- METHANE 16.043 51.113 51.113 204.452 ------ WATER 18.015 ---------- CARBON MONOXIDE 28.010 0.000 ---------- NITROGEN 28.013 0.052 ------0.104 -- ETHYLENE 28.054 5.795 11.590 23.180 ------ ETHANE 30.070 10.738 21.476 64.428 ------ OXYGEN 31.999 0.000 ---------- HYDROGEN SULFIDE 34.076 ---------- ARGON 39.948 ---------- PROPYLENE 42.081 l.172 3.516 7.032 ------ CARBON DIOXIDE 44.010 0.000 ---------- PROPANE 44.097 2.755 8.265 22.040 ------ BUTYLENES 56.108 0.150 0.600 1.200 ------ ISO-BUTANE 58.124 ---------- N-BUTANE 58.124 ---------- PENTENES 70.135 ---------- ISO-PENTANE 72.151 0.910 4.550 10.920 ------ N-PENTANE 72.151 ---------- BENZENE 78.114 --------- HEXANE 86.178 ---------- TOLUENE 92.141 ---------- HEPTANE 100.205 ---------- ETHYLBENZENE 106.168 ---------- XYLENE 106.168 ---------- TOTAL 99.996 101.110 387.874 --0.104 -- WEIGHT (LBS) --1,214.432 390.938 --1.457 -- WEIGHT% --75.580 24.330 0.000 0.091 0.000 LHV (BTU/SCF): 927 = SUM [ (MOLE¾; • LHV;) + 100] HHV (BTU/SCF): --= SUM [ (MOLE¾; • HHV1) + 100] DENSITY (LB/SCF): 0.042 = SUM [ (MOLE %1 • DENSITY;) + 100] SPECIFIC GRAVITY: 0.555 = DENSITY (LB/SCF) + DENSITY AIR (0. 0763 LBISCF) GCV (BTU/LB): 24,204 =HIN+ DENSITY MW (LB/LBMOLE): 16.069 = SUM [ (MOLE¾; • MW,) + 100] Fd (DSCF/MMBTU): 8,437 = 106 • [ (3.64 •%H) + (1.53 •%C) + (0.14 •%NJ+ (0.57·%S) -(0.46 •%0)] + GCV F,. (WSCF/MMBTU): 10,377 = 106 • [ (5.57 •%HJ+ (1.53 •%C) + (0.14 •%NJ+ (0.57·%S) -(0.46 •%0)] + GCV F,(SCF/MMBTU): 1,002 = 106 • (0.321 •%C) + GCV Expected F0 : l.759 = 0.209 • F d + F c ~;, Alliance T [ '~ JI ; , 1 ' , ,,'. L_ ; ·, Fl :~) I I ;, Location: MPC-Tesoro -Salt Lake City Refmery, UT Project No.: AST-2024-4117 FUEL FACTOR CALCULATION BASED ON FUEL ANALYSIS COMPONENT MW MOLE% MOLESC MOLESH MOLESO HYDROGEN 2.016 26.852 --53.704 -- HELIUM 4.003 ------ METHANE 16.043 51.759 51.759 207.036 -- WATER 18.015 ------ CARBON MONOXIDE 28.010 0.000 ------ NITROGEN 28.013 0.051 ------ ETHYLENE 28.054 5.755 11.510 23.020 -- ETHANE 30.070 10.741 21.482 64.446 -- OXYGEN 31.999 0.000 ------ HYDROGEN SULFIDE 34.076 ------ ARGON 39.948 ------ PROPYLENE 42.081 1.013 3.039 6.078 -- CARBON DIOXIDE 44.010 0.000 ------ PROPANE 44.097 2.732 8.196 21 .856 -- BUTYLENES 56.108 0.139 0.556 1.112 -- ISO-BUTANE 58.124 ------ N-BUTANE 58.124 ------ PENTENES 70.135 ------ ISO-PENTANE 72. 151 0.928 4.640 11.136 -- N-PENTANE 72.151 ------ BENZENE 78.114 ------ HEXANE 86.178 ------ TOLUENE 92.141 ------ HEPTANE 100.205 ------ ETHYLBENZENE 106.168 ------ XYLENE 106.168 ------ TOTAL 99.970 101.182 388.388 -- WEIGHT (LBS) --1,215.297 391.456 -- WEIGHT% --75.570 24.342 0.000 LHV (BTU/SCF): 928 = SUM [ (MOLE¾; • LHV;J + 100} HHV (BTU/SCF): --= SUM [ (MOLE¾; • HHV;J + 100} DENSITY (LB/SCF): 0.042 = SUM [ (MOLE %1 • DENSITY;)+ 100} SPECIFIC GRAVITY: 0.555 = DENSITY (LB/SCF) + DENSITYA1R (0.0763 LBISCF) GCV (BTU/LB): 24,196 = HHV + DENSITY MW (LB/LBMOLE): 16.082 = SUM [ (MOLE¾; • MW;)+ 100] Run2 MOLESN MOLESS ---- ---- --- ---- ---- 0.102 -- ---- ---- ------- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---------------- ------------ 0.102 -- 1.429 -- 0.089 0.000 Fd (DSCF/MMBTU): 8,441 = 106 • [ (3.64 •%HJ+ (1.53 •¾CJ+ (0.14 •%NJ+ (0.57·%S) -(0.46 •¾OJ} + GCV F,. (WSCF/MMBTU): 10,382 = 106 • [ (5.57 •¾H) + (1.53 •¾CJ+ (0.14 •%NJ+ (0.57·%S) -(0.46 •%0)} + GCV F. (SCF/MMBTU): 1,003 = 106 • (0.321 •%CJ+ GCV Expected F0 : 1.760 = 0.209 • F d + F c '=:_.:' Alliance T E ( ' I ;· ~ ! '. ~ _:I p ·~ ~: [ _ :-, Location: MPC-Tesoro -Salt Lake City Refinery, UT Project No.: AST-2024-4117 FUEL FACTOR CALCULATION BASED ON FUEL ANALYSIS COMPONENT MW MOLE0/4 MOLESC MOLESH MOLESO HYDROGEN 2.016 26.833 -53.666 -- HELIUM 4.003 ------ METHANE 16.043 51.348 51.348 205.392 -- WATER 18.015 ----- CARBON MONOXIDE 28.010 0.000 ------ NITROGEN 28.013 0.052 ------ ETHYLENE 28.054 5.795 11.590 23.180 -- ETHANE 30.070 10.848 21.696 65.088 -- OXYGEN 31.999 0.000 ----- HYDROGEN SULFIDE 34.076 ------ ARGON 39.948 ----- PROPYLENE 42.081 1.125 3.375 6.750 -- CARBON DIOXIDE 44.010 0.000 ------ PROPANE 44.097 2.888 8.664 23. 104 -- BUTYLENES 56.108 0.149 0.596 1.192 -- ISO-BUTANE 58.124 ------ N-BUTANE 58.124 ----- PENTENES 70.135 ------ ISO-PENT ANE 72.151 0.986 4.930 11.832 -- N-PENTANE 72.151 ------ BENZENE 78.114 ------ HEXANE 86.178 ------ TOLUENE 92.141 ------ HEPTANE 100.205 ------ ETHYLBENZENE 106.168 ------ XYLENE 106.168 ------ TOTAL 100.024 102.199 390.204 - WEIGHT (LBS) --1,227.512 393.287 -- WEIGHT% --75.667 24.243 0.000 LHV (BTU/SCF): 935 = SUM [ (MOLE%; • LHV;) + 100] HHV (BTU/SCF): --= SUM [ (MOLE%; • HHV;) + 100] DENSITY (LB/SCF): 0.043 = SUM [ (MOLE %1 • DENSITY,) + 100] SPECIFIC GRAVITY: 0.560 = DENSITY (LB/SCF) + DENSITY AIR (0.0763 LBISCFJ GCV (BTU/LB): 24,162 = IIlN + DENSITY MW (LB/LBMOLE): 16.223 = SUM [ (MOLE%; • MW;) + 100] Run3 MOLESN MOLESS ---- ---- ---- ---- ---- 0.104 -- ---- ---- ---- ---- ---- ---- ---- ---- ---- --- --- ---- ---- --- ---- ---- ---- ----------- 0.104 -- 1.457 -- 0.090 0.000 Fd (DSCF/MMBTU): 8,444 = 106 • [ (3.64 •%HJ+ (1.53 •%CJ+ (0.14 •%NJ+ (0.57·%SJ -(0.46 •%OJ J + GCV F.,. (WSCF/MMBTU): 10,381 = 106 • [ (5.57 •%HJ+ (1.53 •%C) + (0.14 •%NJ+ (0.57·%SJ -(0.46 •%0) J + GCV Fe (SCF/MMBTU): 1,005 = 106 • (0.321 •¾C) + GCV Expected F0: l.756 = 0.209 • F d + F c ' :-:;;,--Alliance TE C ft CAL GAO Locadon: MPC-Tcsoro -Salt Lake City Refinery, UT Source: West Cogeneration Unit (CG2) Project No.: AST-2024--4117 Date: ll/ 19/24 Time Unit Stallls Uncorrocted Run Averaee (C..,) Cal Gu Concentradon (C...J Pretm System Zero Respon1e Po1tteat System Zero R.e■pon1e Average Zero Respon■e (Co) Pretat System Cal Respon1e Po11te■t Syatem Cal Re■pon1e Average Cal Response (C..) Corrected Run Avera e Corr 12:16 12:17 12:18 12:19 12:20 12:21 12:22 12:23 12:24 12:25 12:26 12:27 12:28 12:29 12:30 12:31 12:32 12:33 12:34 12:35 12:36 12:37 12:38 12:39 12:40 12:41 12:42 12:43 12:44 12:45 12:46 12:47 12:48 12:49 12:50 12:51 12:52 12:53 12:54 12:55 12:56 12:57 12:58 12:59 13:00 13:01 13:02 13:03 13:04 13:05 13:06 13:07 13:08 13:09 13:10 13:11 13:12 13:13 13:14 13:15 0.-0udet o/o dry Valid 7.45 10.87 0.21 0.20 0.21 10.98 10.98 10.98 7.31 7.50 7.49 7.49 7.52 7.55 7.56 7.56 7.55 7.52 7.52 7.51 7.53 7.58 7.60 7.63 7.63 7.64 7.66 7.64 7.65 7.67 7.65 7.65 7.64 7.62 7.56 7.57 7.57 7.57 7.54 7.50 7.50 7.53 7.49 7.47 7.47 7.45 7.44 7.44 7.43 7.44 7.51 7.49 7.44 7.37 7.37 7.37 7.35 7.32 7.31 7.28 7.27 7.24 7.23 7.23 7.23 7.22 7.22 7.22 5.61 Run 2 -RM Data CO,-Oudet NO:r-Oudet %dry ppmvd Valid Valid 7.59 42.24 10.92 50.00 0.03 -0.09 -0.01 0.15 0.01 0.03 10.82 50.21 10.79 50.21 10.80 50.21 7.67 42.06 7.54 40.69 7.56 40.67 7.57 40.60 7.55 40.61 7.54 40.48 7.54 40.37 7.54 40.38 7.55 40.44 7.57 40.57 7.57 40.50 7.58 40.66 7.57 40.63 7.53 40.51 7.52 40.46 7.50 40.24 7.50 40.19 7.48 40.20 7.47 39.96 7.48 39.93 7.49 39.90 7.51 47.63 7.50 42.60 7.50 39.94 7.50 41.65 7.51 40.20 7.55 40.16 7.55 40.34 7.55 41.74 7.55 40.44 7.57 42.14 7.59 40.40 7.60 41.20 7.58 40.80 7.61 40.63 7.61 41 .70 7.61 42.81 7.62 40.92 7.64 42.43 7.64 41.40 7.65 40.72 7.70 44.95 7.61 82.99 7.61 42.46 7.64 41 .16 7.67 41.05 7.68 41 .01 7.71 41.11 7.72 41 .18 7.73 41 .29 7.74 41 .35 7.77 41.48 7.77 41 .65 7.80 41.77 7.82 44.66 7.82 49.04 7.82 44.28 7.82 43.88 7.82 43.35 7.82 44.36 6.08 43.47 '=: Alliance TEC:1!, i'./\L GRntJP Location: MPC-Tesoro -Salt Lake Ci1y Refinery, lIT Sonrce: West Cogeneration Unit (CO2) Project No.: AST-2024-4117 Date: 11/19/24 Time Unit Stahl■ Uncorrected Ru Averace (C...) Cal Gu Coaeentratfoa (C...J Prete■t Sy,,tem Zero Re■poase Po1tte1t Sy,,tem Zero Re1ponse Average Zero Re9poa1e (Co) Prett1t Sy,,tem Cal Re1poa1e Po1tte1t Sy,,tem Cal Re■poase Average Cal Respoa■e (C..) Corrected Run Avera e Corr 13:28 13:29 13:30 13:31 13:32 13:33 13:34 13:35 13:36 13:37 13:38 13:39 13:40 13:41 13:42 13:43 13:44 13:45 13:46 13:47 13:48 13:49 13:50 13:51 13:52 13:53 13:54 13:55 13:56 13:57 13:58 13:59 14:00 14:01 14:02 14:03 14:04 14:05 14:06 14:07 14:08 14:09 14:10 14:11 14:12 14:13 14:14 14:15 14:16 14:17 14:18 14:19 14:20 14:21 14:22 14:23 14:24 14:25 14:26 14:27 0,-0udet o/o dry Valid 7.25 10.87 0.20 0.16 0.18 10.98 10.95 10.96 7.13 7.16 7.17 7.19 7.22 7.30 7.31 7.28 7.27 7.25 7.25 7.31 7.32 7.34 7.36 7.35 7.32 7.30 7.29 7.29 7.31 7.33 7.33 7.34 7.36 7.39 7.40 7.38 7.36 7.34 7.34 7.34 7.35 7.35 7.39 7.37 7.30 7.26 7.23 7.20 7.09 7.21 7.11 7.17 7.28 7.21 7.21 7.26 7.29 7.18 7.26 7.27 7.22 7.26 7.17 7.22 7.33 7.31 7.28 7.26 5.38 Run 3 -RM Data CO,-Oudet NOi:-Outlet %dry ppmvd Valid Valid 7.73 41.00 10.92 50.00 --0.01 0.15 0.01 0.02 0.00 0.09 10.79 50.21 10.83 49.96 10.81 50.08 7.81 40.92 7.82 42.09 7.81 42.11 7.80 41.43 7.79 41 .20 7.73 41 .09 7.73 40.74 7.75 40.96 7.75 41 .07 7.76 41 .00 7.77 41 .05 7.73 40.98 7.72 40.84 7.71 40.87 7.70 40.96 7.70 40.96 7.72 41 .17 7.73 41.12 7.75 41 .14 7.76 41 .30 7.78 41.70 7.74 49.10 7.73 41.40 7.73 41.16 7.71 40.61 7.69 40.35 7.69 40.24 7.69 40.26 7.71 40.37 7.72 40.42 7.72 40.53 7.72 40.56 7.72 40.58 7.72 40.46 7.69 40.44 7.71 40.31 7.75 40.37 7.77 40.52 7.79 40.70 7.81 40.87 7.91 40.91 7.81 41.17 7.90 40.87 7.84 41 .24 7.77 40.78 7.83 40.70 7.82 40.53 7.78 40.83 7.74 40.59 7.84 40.50 7.77 40.84 7.77 40.69 7.82 40.65 7.79 41.01 7.88 40.61 7.84 41.23 7.74 40.67 7.75 40.63 7.78 40.84 7.79 40.93 5.85 40.91 Locadon: MPC-Tesoro -Salt Lake City Refinery, UT Project No.: AST-2024-4117 FUEL FACTOR CALCULATION BASED ON FUEL ANALYSIS COMPONENT MW MOLE% MOLESC MOLESH MOLESO HYDROGEN 2.016 29.353 --58.706 -- HELIUM 4.003 ------ METHANE 16.043 50.872 50.872 203.488 -- WATER 18.015 ------ CARBON MONOXIDE 28.010 0.000 ------ NITROGEN 28.013 0.050 ------ ETHYLENE 28.054 5.460 10.920 21.840 -- ETHANE 30.070 9.439 18.878 56.634 -- OXYGEN 31.999 0.000 ------ HYDROGEN SULFIDE 34.076 ------ ARGON 39.948 ------ PROPYLENE 42.081 1.284 3.852 7.704 - CARBON DIOXIDE 44.010 0.000 ------ PROPANE 44.097 2.685 8.055 21.480 -- BUTYLENES 56.108 0.125 0.500 1.000 -- ISO-BUTANE 58.124 ------ N-BUTANE 58.124 ------ PENTENES 70.135 ----- ISO-PENTANE 72.151 ------ N-PENTANE 72.151 0.749 3.745 8.988 -- BENZENE 78.114 ------ HEXANE 86.178 ------ TOLUENE 92.141 ----- HEPTANE 100.205 ----- ETHYLBENZENE 106.168 ------ XYLENE 106.168 ------ TOTAL 100.017 96.822 379.840 -- WEIGHT <LBS) --1,162.929 382.841 - WEIGHT¾ --75.165 24.745 0.000 LHV (BTU/SCF): 899 = SUM [ (MOLE%1 • LHV1) + 100} HHV (BTU/SCF): --= SUM [ (MOLE%1 • HHV1) + 100} DENSITY (I.B/SCF): 0.041 = SUM [ (MOLE %1 • DENSITY 1) + 100} SPECIFIC GRAVITY: 0.534 = DENSITY (LB/SCF).,. DENSilY AIR (0.0763 LBISCF) GCV <BTU/LB): 24,390 = HHV.,. DENSITY MW (LB/LBMOLE): 15.472 = SUM [ (MOLE%1 • MW1) + 100} Run 1 MOLESN MOLESS ---- -------- ---- ---- 0.100 ------ ---- ---- -------- ---- ---- ---- -------- ---- --- ------------ ---- ---- -------- ---- 0.100 -- 1.401 -- 0.091 0.000 Fd (DSCF/MMBTU): 8,408 = 106 • [ (3.64 •¾H) + (1.53 •¾C) + (0.14 •¾NJ+ (0.57·%S) -(0.46 •%0)} + GCV F,. (WSCF/MMBTU): 10,366 = 106 • { (5.57 •¾H) + (1.53 •¾CJ+ (0.14 •¾NJ+ (0.57·%S) -(0.46 •%0)} + GCV F,(SCF/MMBTU): 989 = 106 • (0.321 •¾CJ+ GCV Expected F0: 1.776 = 0.209 • F d + F c LocaUon: MPC-Tesoro -Salt Lake City Refinery, UT Project No.: AST-2024-4117 FUEL FACTOR CALCULATION BASED ON FUEL ANALYSIS COMPONENT MW MOLE¾ MOLESC MOLESH MOLESO HYDROGEN 2.016 27.217 --54.434 -- HELn.JM 4.003 ------ METHANE 16.043 54.076 54.076 216.304 -- WATER 18.015 ------ CARBON MONOXIDE 28.010 0.000 ------ NITROGEN 28.013 0.050 ------ ETHYLENE 28.054 5.498 10.996 21.992 -- ETHANE 30.070 9.116 18.232 54.696 -- OXYGEN 31.999 0.000 ----.. HYDROGEN SULFIDE 34.076 ------ ARGON 39.948 ------ PROPYLENE 42.081 0.857 2.571 5.142 -- CARBON DIOXIDE 44.010 0.000 ------ PROPANE 44.097 2.300 6.900 18.400 -- BUTYLENES 56.108 0.123 0.492 0.984 -- ISO-BUTANE 58.124 .. ---- N-BUTANE 58.124 .. ---- PENTENES 70.135 ------ ISO-PENTANE 72.151 ----- N-PENTANE 72.151 0.794 3.970 9.528 .. BENZENE 78.114 .. .. .. HEXANE 86.178 .. ---- TOLUENE 92.1 41 .. ---- HEPTANE 100.205 ----.. ETHYLBENZENE 106.168 ------ XYLENE 106.168 --.. .. TOTAL 100.031 97.237 381.480 .. WEIGHT (LBS) .. 1,167.914 384.494 - WEIGHT% --75.165 24.745 0.000 LHV (BTU/SCF): 901 = SUM [ (MOLE%, • LHV,) + 100] HHV (BTU/SCF): .. = SUM [ (MOLE%, • HHV1) + 100] DENSITY (LB/SCF): 0.041 = SUM [ (MOLE %1 • DENSITY,)+ 100] SPECIFIC GRAVITY: 0.537 = DENSITY (LB/SCF) + DENSITY AIR (0. 0763 LBISCF) GCV (BTU/LB): 24,345 = HHV + DENSITY MW CLB/LBMOLE): 15.538 = SUM { (MOLE%, • MW1) + 100] Runl MOLESN MOLESS --- ---- ---- --_,_ ---- 0.100 - --- -- --- ---- --.. ---- --- -· - --.. ---- ·--- ---- ---- ---- ---- ---- ---- ---- --.. --.. 0.100 .. 1.401 -- 0.090 0.000 F d (DSCF/MMBTU): 8,424 = 1011 • [ (3.64 •%HJ+ (1.53 •¾C) + (0.14 •%NJ+ (0.57·%S) -(0.46 •%0)] + GCV F,. (WSCF/MMBTU): 10,386 = 1011 • {(5.57•%H) + {1.53•%C) + (0.14 •¾N) + (0.57·%S)-(0.46•%O)]+ GCV F,(SCF/MMBTU): 991 = 1011 • (0.321 •¾C) + GCV Expected F0: 1.777 = 0.209 • F d + F c Location: MPC-Tesoro -Salt Lake City Refinery, UT Project No.: AST-2024-4117 FUEL FACTOR CALCULATION BASED ON FUEL ANALYSIS COMPONENT MW MOLE¾ MOLESC MOLESH MOLESO HYDROGEN 2.016 26.033 --52.066 -- HEUUM 4.003 ----- METHANE 16.043 53.906 53.906 215.624 -- WATER 18.015 ----- CARBON MONOXIDE 28.010 0.000 ------ NITROGEN 28.013 0.049 ------ ETHYLENE 28.054 5.771 11.542 23.084 -- ETHANE 30.070 9.849 19.698 59.094 -- OXYGEN 31.999 0.000 ------ HYDROGEN SULFIDE 34.076 ----- ARGON 39.948 ----- PROPYLENE 42.081 0.861 2.583 5.166 -- CARBON DIOXIDE 44.010 0.000 ------ PROPANE 44.097 2.485 7.455 19.880 -- BUTYLENES 56.108 0.134 0.536 1.072 -- ISO-BUTANE 58.124 ------ N-BUTANE 58.124 ------ PENTENES 70.135 ------ ISO-PENTANE 72.151 ------ N-PENTANE 72.151 0.890 4.450 10.680 -- BENZENE 78.1 14 ----- HEXANE 86.178 ------ TOLUENE 92.141 ----- HEPTANE 100.205 ----- ETHYLBENZENE 106.168 ----- XYLENE 106.168 ----- TOTAL 99.978 100.170 386.666 - WEIGHT <LBS) --1,203.142 389.721 -- WEIGHT¾ --75.468 24.446 0.000 LHV (BTU/SCF): 920 = SUM [ (MOLE%; • LHV;) + 100] HHV (BTU/SCF): --= SUM [ (MOLE%; • HHV;) + 100] DENSITY (LB/SCF): 0.042 = SUM [(MOLE%; • DENSITY;)+ 100] SPECIFIC GRAVITY: 0.550 = DENSITY (LB/SCF) + DENSITY AIR (0. 0763 LBISCF) GCV (BTU/LB): 24,221 = HHV + DENSITY MW (LB/LBMOLE): 15.943 = SUM [ (MOLE%; • MW;)+ 100} Run3 MOLESN MOLESS ---- ---- --- --_,_ ---- 0.098 -- ---- ---- ---- --- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- ---- 0.098 -- 1.373 -- 0.086 0.000 Fd (DSCF/MMBTU): 8,442 = 106 • { (3.64 • %HJ + (1.53 • %CJ + (0.14 •%NJ+ (0.57·%S) -(0.46 • %0) J + GCV F,. (WSCF/MMBTU): 10,389 = 106 • { (5.57 • %HJ + (1.53 •%CJ+ (0.14 •%NJ+ (0.57·%S) -(0.46 • %0)] + GCV F.(SCF/MMBTU): 1,000 = 106 • (0.321 • %CJ + GCV Expected F0 : 1.764 = 0.209 • F d + F c Appendix C f .:- Al I la nee TCC,H ICI'-' ""0 r> Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: East Co generation Unit (CG 1) Project No.: AST-2024-4117 Date: 11/20/24 Parameter 01 -Outlet Expected A veraee Concentration 7.00 Span Between Low 7.00 High 35.00 Desired Span 10.87 Low Range Gas Low NA Hieb NA Mid Range Gas Low 4.35 High 6.52 High Range Gas Low NA Hieb NA Actual Concentration (% or ppm) Zero 0.00 Low NA Mid 6.00 Hieb 10.87 Response Time (seconds) 30.00 Upscale Calibration Gas (CMAl Mid Instrument Response (¾ or ppm) Zero 0.01 Low NA Mid 6.16 High 10.98 Performance(% of Span or Cal. Gas Cone.) Zero 0.09 Low NA Mid 1.47 High 1.01 Status Zero PASS Low NA Mid PASS High PASS Calibration Data CO2-Outlet NOx-Outlet 7.00 45.00 7.00 45.00 35.00 225.00 10.92 100.00 NA NA NA NA 4.37 40.00 6.55 60.00 NA NA NA NA 0.00 0.00 NA NA 6.00 50.00 10.92 100.00 30.00 56.67 Mid Mid -0.05 -0.10 NA NA 5.97 50.86 10.98 99.86 0.46 0.10 NA NA 0.27 0.86 0.55 0.14 PASS PASS NA NA PASS PASS PASS PASS ~ .:- Al I ia nce TCCII JICAL GROl Fl Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: East Co generation Unit (CG 1) Project No.: AST-2024-4117 Parameter 02-Outlet Runt Pretest System Zero Response 0.23 Posttest System Zero Response 0.23 Pretest System Upscale Response 6.23 Posttest System Upscale Response 6.25 Runl Pretest System Zero Response 0.23 Posttest System Zero Response 0.34 Pretest System Upscale Response 6.25 Posttest System Upscale Response 6.38 Run3 Pretest System Zero Response 0.34 Posttest System Zero Response 0.38 Pretest System Upscale Response 6.38 Posttest System Upscale Response 6.37 Bias/Drift Determinations CO2 -Outlet NOx-Outlet -0.03 0.54 -0.04 0.56 5.91 47.64 5.89 48.80 -0.04 0.56 0.00 0.15 5.89 48.80 5.90 48.15 0.00 0.15 -0.01 0.56 5.90 48.15 5.87 50.47 ' ;-Al I ia nce TECfl IC.,AL 11 Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: East Cogeneration Unit (CGl) Project No.: AST-2024-4117 Parameter 01-Outlet Run 1 Date 11/20/24 Span Value 10.87 Initial Instrument Zero Cal Response 0.01 Initial Instrument Upscale Cal Response 6.16 Pretest System Zero Response 0.23 Posttest System Zero Response 0.23 Pretest System Upscale Response 6.23 Posttest System Upscale Response 6.25 Bias(%) Pretest Zero 2.02 Posttest Zero 2.02 Pretest Span 0.64 Posttest Span 0.83 Drift(%) Zero 0.00 Mid 0.18 Run2 Date 11/20/24 Span Value 10.87 Instrument Zero Cal Response 0.01 Instrument Upscale Cal Response 6.16 Pretest System Zero Response 0.23 Posttest System Zero Response 0.34 Pretest System Upscale Response 6.25 Posttest System Upscale Response 6.38 Bias(%) Pretest Zero 2.02 Posttest Zero 3.04 Pretest Span 0.83 Posttest Span 2.02 Drift(%) Zero 1.01 Mid 1.20 Run3 Date 11/20/24 Span Value 10.87 Instrument Zero Cal Response 0.01 Instrument Upscale Cal Response 6.16 Pretest System Zero Response 0.34 Posttest System Zero Response 0.38 Pretest System Upscale Response 6.38 Posttest System Upscale Response 6.37 Bias(%) Pretest Zero 3.04 Posttest Zero 3.40 Pretest Span 2.02 Posttest Span 1.93 Drift(%) Zero 0.37 Mid -0.09 Bias/Drift Determinations COi-Outlet NOx-Outlet 10.92 100.00 -0.05 -0.10 5.97 50.86 -0.03 0.54 -0.04 0.56 5.91 47.64 5.89 48.80 0.18 0.64 0.09 0.66 -0.55 -3 .22 -0.73 -2.06 -0.09 0.02 -0.18 1.16 10.92 100.00 -0.05 -0.10 5.97 50.86 -0.04 0.56 0.00 0.15 5.89 48.80 5.90 48.15 0.09 0.66 0.46 0.25 -0.73 -2.06 -0.64 -2.71 0.37 -0.41 0.09 -0.65 10.92 100.00 -0.05 -0.10 5.97 50.86 0.00 0.15 -0.01 0.56 5.90 48.15 5.87 50.47 0.46 0.25 0.37 0.66 -0.64 -2.71 -0.92 -0.39 -0.09 0.41 -0.27 2.32 . _;' Alliance TE:.CH I,,. L ' " Location MPC-Tesoro -Salt Lake City Refinery, UT Source West Cogeneration Unit (CG2) Project No. AST-2024-4117 Parameter 02-Outlet Make Servomex Model 1400 SIN 1420C-2 Operatine Ranee 25 Cylinder ID Zero NA Low NA Mid RR03646 High CC727648 Cylinder Certifed Values Zero NA Low NA Mid 10.87 Hieb 24.06 Cylinder Expiration Date Zero NA Low NA Mid 2/24/32 High 9/19/31 CO2 -Outlet Servomex 1400 1415C-6 25 NA NA RR03646 CC727648 NA NA 10.92 23 .9 NA NA 2/24/32 9/19/31 Type of Sample Line Heated Sample Line QA Data NOx-Outlet Thermo 42i 1417161680 500 NA NA EB0099840 EB0099840 NA NA 489 489 NA NA 4/1/32 4/1/32 ~ ;' Alliance TECH,,lr,/\1 r,R , n Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: West Cogeneration Unit (CG2) Project No.: AST-2024-4117 Date: 11/19/24 Parameter 01-Outlet Expected Average Concentration 8.00 Span Between Low 8.00 High 40.00 Desired Span 24.06 Low Range Gas Low NA Hb?h NA Mid Range Gas Low 9.62 Hie:h 14.44 High Range Gas Low NA High NA Actual Concentration (% or ppm) Zero 0.00 Low NA Mid 10.87 Hie:h 24.06 Response Time (seconds) 47.50 Upscale Calibration Gas (CM.J Mid Instrument Response (o/• or ppm) Zero 0.00 Low NA Mid 10.92 Hie:h 24.08 Performance(% of Span or Cal. Gas Cone.) Zero 0.00 Low NA Mid 0.19 Hie:h 0.07 Status Zero PASS Low NA Mid PASS High PASS Calibration Data CO2-Outlet NOx-Outlet 8.00 45.00 8.00 45.00 40.00 225.00 23.90 100.00 NA NA NA NA 9.56 40.00 14.34 60.00 NA NA NA NA 0.00 0.00 NA NA 10.92 50.00 23.9 100.00 50.00 64.50 Mid Mid -0.05 -0.24 NA NA 10.95 50.34 23 .91 100.11 0.21 0.24 NA NA 0.11 0.34 0.05 0.11 PASS PASS NA NA PASS PASS PASS PASS ' .: Alliance TEr,11, IC.,AL GA LIP Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: West Cogeneration Unit (CG2) Project No.: AST-2024-4117 Parameter 02 -Outlet Run 1 Pretest System Zero Response 0.02 Posttest System Zero Response 0.21 Pretest System Upscale Response 10.93 Posttest System Upscale Response 10.98 Run2 Pretest System Zero Response 0.21 Posttest System Zero Response 0.20 Pretest System Upscale Response 10.98 Posttest System Upscale Response 10.98 Run3 Pretest System Zero Response 0.20 Posttest System Zero Response 0.16 Pretest System Upscale Response 10.98 Posttest System Upscale Response 10.95 Bias/Drift Determinations CO2-Outlet NOx-Outlet -0.04 0.16 0.03 -0.09 10.81 49.82 10.82 50.21 0.03 -0.09 -0.01 0.15 10.82 50.21 10.79 50.21 -0.01 0.15 0.01 0.02 10.79 50.21 10.83 49.96 EPA Method 205 Field Calibration of Dilution System Location: MPC-Tcsoro -Salt Lake City Refinery, lIT Source: East Co generation Unit (CG I) Project No.: AST-zoz.µ117 Date 11 /20/24 Method Criteria EPA Parameter 0 2 Make Servomex Model 1440 SIN 1420C-2 Span 23.9 CVllnder Number m Zero NA Mid RR03646 Hi2h CC731666 CyUnder Cntlfled Valu,s Zero 0.0 Mid 10.87 Hl2h 23.88 Instrument ResPOnle (•/4 Or ppm Zero -0.1 Mid 10.9 Ri2b 23.9 Calibration Gas Selection C°I• of Span) Mid 4S.S Ri2h 100.0 Calibration Error Performance % of Span) Zero -0.2 Mid 0.3 Hl2b -0.1 Linearity ("lo of Ran2e) 0.4 Analyzer Make: Analyzer Model: Analyzer SN: Envirooics ID: CompooeoliBalaoce Gas: Cylinder Gas ID (Dilution): Cylinder Gas Concentration (Dilution), ¾: Cylinder Gas ID (Mid-Level): Cylinder Gas Concentration (Mid-Level), %: Injection I Target TareetFlow Target Aetna! Analyzer Tareet Ma11 Flow Dilution Rate Concentration Concentntlon Concentntlon Contollen (%) 1pm (%) (%) (%) I0USL 80.0 s.o 19.1 19.1 19.1 I0USL 50.0 s.o 11.9 11.9 11.8 i0UlL 20,0 4,0 4.8 4,8 4,9 i0UlL 10.0 4.0 2.4 2.4 2.4 Servomcx 1440 1420C-2 8412 O2/N2 CC731666 23.88 RR03646 10.87 Injection 2 Injection J Average Analyzer Analyzer Analyzer Concentntlon Concentration Concentration Difference (%) (%) (%) (%) 19.1 18,9 19.01 -0,09 11.8 11.7 11.78 -0.12 4.9 4.8 4,88 0.08 2.4 2.4 2.40 0.00 .. *Not aU AST Envu-owcs Uwts have 2-1 0L Mass Flow ControUers. For these UDJts the 90% @ 11pm and 80% @ 11pm 1QJect10ns will not be conducted. Averaee Analyzer Injection l Injection 2 lnjectlonl Concentntlon Error Error Error (%) (±1'/o) (±2%) (±2 o/o) 19.01 0.2% 0.5% -0.7% 11.78 -0.1% 0.5% -0.4% 4.88 0.8% 0.8% -1.6% 2.40 -0.1% 1.1% -1.0% Mid-Level Sup1 ly Gas Calibration Direct to Aoalvur CaUbratlon Injection I Injection 2 Injection J Average Gu Analyzer Analyzer Analyzer Analyzer Average Concentration Concentration Concentration Concentntlon Concentntlon Difference Error ("It) ("I.) (¾) (%) (%) (%) (±2%) 10.87 10.6 10.9 10.7 10.71 -0.16 -1.4% Averaee Error (±1%) -0.S% -1.0% 1.7% 0.1% Allin:e SQcACc TESll~G Issuing Department Dilution System Make: Dilution System Model: Dilution System S/N: Calibration Equipment Make: Calibration Equipment Model: Calibration Equipment S/N: Flow Cell S/N: Flow Cell S/N: Calibration Gas: Barometric Pressure, mmHg: Ambient Temperature, °F: Mass Flow Controller ID Size, ccm: Make: Model: S/N: 5% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Mass Flow Controller Calibration Tech Services Environics 4040 8412-02-21-2024 Alicat Scientific M-10SLPD/SMM-D/SM, M-1SLPM-D/SM 272121 272121 272120 Nitrogen 25.641 64.4 #1 10,000 Environics FFC 202 626687006 Set Flow True Flow Difference cc/min cc/min 500 493 1.4% 1,000 1,008 0.8% 2,000 2,039 20% 3,000 3,061 2.0% 4,000 4,079 2.0% 5,000 5,093 1.9% 6,000 6,110 1.8% 7,000 7,134 1.9% 8,000 8,154 1.9% 9,000 9,183 2.0% 10.000 10,202 20% Set Flow cc/min 500 1,000 2,000 3,000 4,000 5,000 6,000 7,000 8,000 9,000 10,000 Document ID 620.009 Revision 22 0 Effective Date 12/16/22 Paqe 1 of1 #2 #3 10,000 1,000 Environics Environics FFC 202 FFC 202 626687003 626683003 True Flow Difference Set Flow True Flow Difference cc/min cc/min cc/min 491 1.8% so 49 2.2% 1,013 1.3% 100 99 0.9% 2,041 2.1% 200 200 0.0% 3,074 2.5% 300 301 0.3% 4,105 2.6% 400 402 0.6% 5,127 2.5% 500 503 0.6% 6,143 2.4% 600 605 0.8% 7,168 2.4% 700 707 1.0% 8,175 2.2% 800 809 1.2% 9,190 2.1% 900 914 1.5% 10,202 2.0% 1,000 1,019 1.9% Note: The mass fiow controller's calibration values are used by the dilution system's operating software to improve accuracy. These calibrations are not necessarily indicative of the systems overall performance. Performance is verified by conducting a Method 205 prior to each field use. Calibration Performed By: JFT -------------------Date: 2/21/2024 Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: East Cogeneration Unit (CGl) Project No.: AST-2024-4117 Date: 11/20/2024 Traverse Point Time 02 CO2 (%) (%) A-1 10:45 7.75 7.65 2 11:05 7.52 7.80 3 11:25 7.55 7.79 Average 7.6 7.7 Criteria Met Single Point Single Point Stratification Check NOx (nnm) 29.54 28.92 28.77 29.1 Single Point Location: MPC-Tesoro -Salt Lake City Refinery, UT Source: West Cogeneration Unit (CG2) Project No.: AST-2024-4117 Date: 11/19/2024 Traverse Point Time 01 CO2 (%) (%) A-1 11 :05 7.36 7.75 2 11:25 7.46 7.64 3 11:45 7.50 7.61 Average 7.4 7.7 Criteria Met Single Point Single Point Stratification Check NOx (oom) 42.77 42.82 40.96 42.2 Single Point Appendix D Cogen West Fuel Gas Analyzer Data Run 1 Run2 Run3 Start 11/19/2411:05 11/19/2412:16 11/19/2413:28 Stop 11/19/2412:05 11/19/2413:16 11/19/24 14:28 RERNERYFUELGASH2S PPMV ai20711a.pv 7.561 8.054 8.197 REFINERY FUEL GAS NITROGEN MOL% ai20711c.pv 0.050 0.050 0.049 REFINERY FUEL GAS OXYGEN/ARGON MOL% ai20711d.pv 0.000 0.000 0.000 REFINERY FUEL GAS CARBON DIOXIDE MOL% ai20711e.pv 0.000 0.000 0.000 REFINERY FUEL GAS CARBON MONOXIDE MOL% ai20711f.pv 0.000 0.000 0.000 REFINERY FUEL GAS HYDROGEN MOL% ai20711g.pv 29.353 27.217 26.033 REFINERY FUEL GAS METHANE MOL% ai20711h.pv 50.872 54.076 53.906 REFINERY FUEL GAS ETHANE MOL% ai20711j.pv 9.439 9.116 9.849 REFINERY FUEL GAS ETHYLENE MOL% ai20711k.pv 5.460 5.498 5.771 REFINERY FUEL GAS PROPANE MOL% ai20711l.pv 2.685 2.300 2.485 REFINERY FUEL GAS PROPYLENE MOL% ai20711m.pv 1.284 0.857 0.861 REFINERY FUEL GAS ISOBUTANE MOL% ai20711n.pv 0.000 0.000 0.000 REFINERY FUEL GAS NORMAL BUTANE MOL% ai20711p.pv 0.000 0.000 0.000 REFINERY FUEL GAS C4 OLEFINS MOL% ai20711q.pv 0.125 0.123 0.134 REFINERY FUEL GAS C5S MOL% ai20711r.pv 0.749 0.794 0.890 REFINERY FUEL GAS CS+ MOL% ai20711s.pv 0.000 0.000 0.000 100.016 100.031 99.978 Cogen West Fuel Rate Run 1 Run2 Run3 210MSCFH 206MSCFH 208.3MSCFH Cogen East Fuel Gas Analyzer Data Run 1 Run2 Run3 Start 11/20/2410:45 11/20/24 12: 12 11/20/24 13:25 Stop 11/20/2411:45 11/20/2413:12 11/20/2414:25 REFINERY FUEL GAS H2S PPMV ai20711a.pv 8.779 9.236 10.449 REFINERY FUEL GAS NITROGEN MOL% ai20711c.pv 0.052 0.051 0.052 REFINERY FUEL GAS OXYGEN/ARGON MOL% ai20711d.pv 0.000 0.000 0.000 REFINERY FUEL GAS CARBON DIOXIDE MOL% ai20711e.pv 0.000 0.000 0.000 REFINERY FUEL GAS CARBON MONOXIDE MOL% ai20711f.pv 0.000 0.000 0.000 REFINERY FUEL GAS HYDROGEN MOL% ai20711g.pv 27.311 26.852 26.833 REFINERY FUEL GAS METHANE MOL% ai20711h.pv 51.113 51.759 51.348 REFINERY FUEL GAS ETHANE MOL% ai20711j.pv 10.738 10.741 10.848 REFINERY FUEL GAS ETHYLENE MOL% ai20711k.pv 5.795 5.755 5.795 REFINERY FUEL GAS PROPANE MOL% ai20711l.pv 2.755 2.732 2.888 REFINERY FUEL GAS PROPYLENE MOL% ai20711m.pv 1.172 1.013 1.125 REFINERY FUEL GAS ISOBUTANE MOL% ai20711n.pv 0.000 0.000 0.000 REFINERY FUEL GAS NORMAL BUTANE MOL% ai20711p.pv 0.000 0.000 0.000 REFINERY FUEL GAS C4 OLEFINS MOL% al20711q.pv 0.150 0.139 0.149 REFINERY FUEL GAS C5S MOL% ai20711r.pv 0.910 0.928 0.986 REFINERY FUEL GAS C6+ MOL% ai20711s.pv 0.000 0.000 0.000 99.995 99.970 100.024 Cogen East Fuel Rate Run 1 Run2 Run3 197.6KSCFH 197.6KSCFH 193.5KSCFH Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Tesouro - FCCU WGS Company Contact:Morgan Sites Contact Phone No.385-306-4615 Source Designation:FCCU WGS Test & Review Dates Test Date: 1/21/2025 Review Date: 11/21/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf - - - Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.6606 0.0007 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 96.00 50.27 1.0030 1.687 0.84 25.9 0.06 0.249 Contractor Information Contracting Company: Alliance Technical Group, LLC Contact: Shamit Nakra Phone No.: 385-252-7553 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Tesouro - FCCU WGS Testing Results Lab Data - grams collected Test Date 1/21/2025 1/21/2025 1/21/2025 1/21/2025 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.001565 0.000939 0.009 As ft^2 50.27 50.27 50.27 Run 2 0.0010176 0.0008268 0.0053 Pbar 25.90 25.90 25.90 Run 3 0.0004653 0.0010998 0.0034 Pq (static)0.06 0.06 0.06 Run 4 Ps 25.90 25.90 25.90 Avg. Ts F 137.75 138.75 137.92 Front Half Emissions Summary CO2 - FCO2 13.80 13.80 13.80 Run 1 Run 2 Run 3 Run 4 Avg. O2 4.60 4.60 4.60 gr./dscf 0.0009 0.0006 0.0005 0.0007 N2+C 81.60 81.60 81.60 lbs/hr 0.8371 0.6195 0.5253 0.6606 Md 30.39 30.39 30.39 ton/yr 3.6667 2.7133 2.3006 2.8935 Ms 27.91 27.94 28.17 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 48.65 51.17 50.22 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 226.40 234.30 206.20 gr./dscf 0.0042 0.0025 0.0017 0.0028 AVG. Tm F 66.29 67.21 61.54 lbs/hr 3.8460 2.3996 1.6663 2.6373 Vm std 42.58 44.74 44.36 ton/yr 16.8456 10.5101 7.2985 11.5514 Vw std 10.66 11.03 9.71 Bws 0.20 0.20 0.18 S Bws 0.21 0.22 0.22 Avg. Sqrt Dlp 0.89 0.94 0.92 Vs 58.33 61.49 59.48 F factor used scfm wet 134539.79 141586.74 137159.85 acfm 175923.25 185447.52 179399.23 Qsd dscfh 6456632.08 6815332.77 6752335.28 # Sample Points 24.00 24.00 24.00 Dn 0.249 0.249 0.249 An 3.38E-04 3.38E-04 3.38E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00Total Test time 60.00 60.00 60.00 Time @ point 2.50 2.50 2.50 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Tesouro - FCCU WGS Flow & Moisture Test Date 1/21/2025 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 50.27 25.90 0.06 25.90 138 13.80 4.60 81.60 30.39 27.91 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.2146 1.0030 0.84 48.650 226.40 66.29 42.584 10.657 0.2002 0.2146 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.893 58.33 134,540 175,923 6.46E+06 24 0.249 60 2.50 1.866667 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 584.654 0.77 1.80 133 53 57 Wt. (Final) Wt. (Initial) lc 2 586.770 0.79 1.90 134 51 65 902.30 763.00 139.3 3 588.610 0.78 1.80 138 51 75 717.80 663.70 54.1 4 590.660 0.76 1.70 136 58 77 645.80 634.70 11.1 5 592.590 0.77 1.80 139 53 82 955.60 933.70 21.9 6 594.550 0.91 2.10 144 55 85 0.0 7 596.600 1.00 2.00 135 57 87 8 598.870 1.00 2.00 135 66 86 Isokinetics 98.1 9 600.930 1.00 2.10 135 72 81 Test Date 1/21/2025 10 603.200 1.00 2.40 138 68 76 Start Time enter 11 605.550 1.10 2.60 139 67 68 End Time 12 607.980 1.10 2.60 136 66 64 Run 1 13 610.386 0.52 1.30 137 58 60 14 612.340 0.57 1.30 137 59 60 15 614.070 0.58 1.40 137 58 60 16 615.770 0.64 1.50 139 64 66 17 617.540 0.62 1.60 139 60 66 18 619.450 0.71 1.60 140 60 66 19 621.260 0.62 1.60 140 61 67 20 623.160 0.76 1.80 139 62 67 21 625.090 0.78 1.80 139 64 71 22 627.050 0.79 1.90 139 66 76 23 629.150 0.85 2.00 139 68 77 24 631.240 0.94 2.20 139 68 78 25 633.304 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Tesouro - FCCU WGS Flow & Moisture Test Date 1/21/2025 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 50.27 25.90 0.06 25.90 139 13.80 4.60 81.60 30.39 27.94 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.2202 1.0030 0.84 51.174 234.30 67 44.743 11.029 0.1977 0.2202 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.941 61.49 141,587 185,448 6.82E+06 24 0.249 60 2.50 2.08 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 634.900 0.84 2.00 138.0 55.0 66.0 Wt. (Final) Wt. (Initial) lc 2 637.050 0.79 1.90 139.0 53.0 65.0 924.90 750.30 174.6 3 639.140 0.83 1.90 139.0 53.0 71.0 685.60 647.80 37.8 4 641.190 0.78 1.80 139.0 53.0 82.0 665.80 659.80 6.0 5 643.240 0.70 1.60 139.0 55.0 84.0 967.90 952.00 15.9 6 645.200 0.67 1.60 139.0 58.0 83.0 0.0 7 647.250 1.10 2.60 139.0 63.0 84.0 8 649.150 1.20 2.80 139.0 66.0 76.0 Isokinetics 97.6 9 650.490 1.20 2.80 138.0 68.0 73.0 Test Date 1/21/2025 10 653.720 1.10 2.50 138.0 68.0 69.0 Start Time 11 656.090 1.10 2.60 138.0 68.0 68.0 End Time 12 658.480 1.10 2.60 138.0 65.0 70.0 Run 2 13 660.875 0.70 1.70 135.0 58.0 65.0 14 663.290 0.70 1.60 139.0 59.0 65.0 15 665.130 0.90 2.10 139.0 59.0 67.0 16 667.130 0.90 2.20 139.0 58.0 68.0 17 669.270 1.00 2.30 139.0 59.0 68.0 18 671.520 1.10 2.20 139.0 61.0 71.0 19 673.780 0.60 1.40 140.0 61.0 74.0 20 675.770 0.90 2.10 140.0 63.0 73.0 21 677.780 1.00 2.30 138.0 64.0 76.0 22 679.940 0.95 2.20 140.0 66.0 79.0 23 682.160 0.63 1.50 139.0 67.0 81.0 24 684.140 0.71 1.70 140.0 67.0 81.0 25 686.074 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Tesouro - FCCU WGS Flow & Moisture Test Date 1/21/2025 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 50.27 25.90 0.06 25.90 138 13.80 4.60 81.60 30.39 28.17 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.2155 1.0030 0.84 50.215 206.20 62 44.364 9.706 0.1795 0.2155 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.915 59.48 137,160 179,399 6.75E+06 24 0.249 60 2.50 1.94 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 687.925 0.66 1.50 138.0 46.0 47.0 Wt. (Final) Wt. (Initial) lc 2 689.890 0.96 2.20 138.0 47.0 47.0 905.0 763.2 141.8 3 691.950 0.75 1.70 138.0 49.0 52.0 704.4 665.5 38.9 4 693.930 0.77 1.80 138.0 50.0 58.0 654.9 645.8 9.1 5 695.890 0.65 1.50 138.0 51.0 62.0 972.0 955.6 16.4 6 697.760 0.69 1.60 138.0 52.0 63.0 0.0 7 699.620 0.92 2.10 139.0 53.0 64.0 8 701.660 0.83 1.90 139.0 55.0 67.0 Isokinetics 97.7 9 703.740 0.82 1.90 139.0 57.0 70.0 Test Date 1/21/2025 10 705.790 0.85 2.00 138.0 60.0 72.0 Start Time 11 707.880 0.90 2.10 138.0 62.0 74.0 End Time 12 710.020 0.84 1.90 138.0 65.0 76.0 Run 3 13 712.121 0.79 1.80 137.0 54.0 59.0 14 714.260 0.84 2.00 137.0 59.0 58.0 15 716.340 0.94 2.20 137.0 61.0 60.0 16 718.490 0.79 1.80 137.0 62.0 68.0 17 721.390 0.81 1.90 138.0 63.0 71.0 18 722.750 0.85 2.00 137.0 63.0 71.0 19 724.730 0.88 2.00 137.0 64.0 71.0 20 726.840 0.90 2.10 138.0 64.0 72.0 21 729.010 0.94 2.20 139.0 63.0 71.0 22 731.450 1.00 2.30 138.0 64.0 71.0 23 733.780 0.79 1.80 138.0 64.0 70.0 24 735.920 0.99 2.30 138.0 64.0 68.0 25 738.140 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 FCCU Cogen East 2024 Reference Methods 2, 3A, 6C, 7E, 10, & 19 Source Information Company Name Tesoro Company Contact:Sergio Ibarra Contact Phone No.801-366-2086 Stack Designation:Cogen East Test & Review Dates Test Date:11/20/2024 & Review Date: 1/22/2025 Observer: Reviewer:Paul Morris Emission Limits Emission Rates SO2 NOX CO SO2 NOX CO lbs./MMBtu lbs./hr. ppm 20.0 197.0 29.487 Percent %O2 Correction as a whole #0.00 15.00 Test Information Heat Input Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) fuel flow rate (Btu/hr.) Heat Input (Btu/hr.) 72.00 28.274 Contractor Information Contact: Charles Horton Contracting Company: Alliance Technical Group, LLC Address: 3683 W 2270 S, Suite E West Valley City, UT 84120 Phone No.: (464) 352-7568 Project No.: 8441 Round Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthrocite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 CO2 Interference w/CO Yes Yes Yes FCCU Cogen East 2024 Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Tesoro Cogen East Average Emission Dry SO2 NOX CO lbs./MMbtu 0.046 Average % concentration lbs./hr.8.36 CO2 O2 ppm or % 29.49 7.87 7.31 Run 1 Enter O2 or CO2 Dry SO2 NOX CO CO2 O2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)4.66E-02 E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 3.574E-06 lbs./hr.8.55 7.87 7.37 ppm or %29.92 7.75 7.61 Run 2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)4.53E-02 E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 3.503E-06 lbs./hr.8.33 7.91 7.27 ppm or %29.33 7.75 7.59 Raw Value Run 3 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)4.52E-02 E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 3.489E-06 lbs./hr.8.20 7.83 7.29 ppm or %29.21 7.70 7.68 Raw Value Run 4 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value Run 5 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value C For Cal Drift Raw Value C For Cal Drift C For Cal Drift C For Cal Drift C For Cal Drift O2 CO2 Clear lbs./MMBTU FCCU Cogen East 2024 Calibration Error Test Test Date November 20, 2024 O2 CS - Cal. Span 10.87 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.01 0.01 0.09% Passed Cal. RR03646 02/24/32 Mid-level 6.00 6.16 0.16 1.47% Passed Cal. High-level 10.87 10.98 0.11 1.01% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of CS - Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 55.20% 100% of Cal. Span High-level 100.00% Test Date November 20, 2024 CO2 CS - Cal. Span 10.92 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 -0.05 0.05 0.458% Passed Cal. RR03646 02/24/32 Mid-level 6.00 5.97 0.03 0.275% Passed Cal. High-level 10.92 10.98 0.06 0.549% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 54.95% 100% of Cal. Span High-level 100.00% Test Date SO2 CS - Cal. Span Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level Mid-level High-level % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 40 to 60% of Cal. Span Mid-level 100% of Cal. Span High-level Test Date November 20, 2024 NOx CS - Cal. Span 100.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 -0.10 0.10 0.100% Passed Cal. EB0099840 04/01/32 Mid-level 50.00 50.86 0.86 0.860% Passed Cal. High-level 100.00 99.86 0.14 0.140% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date CO CS - Cal. Span Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level Mid-level High-level % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 40 to 60% of Cal. Span Mid-level 100% of Cal. Span High-level Valid Cal Gas Valid Cal Gas Valid Cal Gas FCCU Cogen East 2024 Division of Air Quality Stack Test Review ofTesoro SO2 NOX CO CO2 O2 Cogen East CS Calibration Span 100.00 10.92 10.87 Units ppm ppm ppm % % Unprotected CV - Cylinder Value: SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00 Mid-Level 50.00 6.00 6.00 High-Level 100.00 10.92 10.87 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 54.9% 55.2% 100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CDir CMA 50.00 6.00 6.00 Calibration Error Test Cs - Measured Concentration SO2 NOX CO CO2 O2 Low-Level -0.10 -0.05 0.01 Mid-Level 50.86 5.97 6.16High-Level 99.86 10.98 10.98 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.86 5.97 6.16 Low-Level 0.10% 0.46% 0.09% ppmdv Difference 0.1 0.05 0.01 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.86% 0.27% 1.47% ppmdv Difference 0.86 0.03 0.16 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.14% 0.55% 1.01% ppmdv Difference 0.14 0.06 0.11 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.54 -0.03 0.23 System Bias. SBi - Zero Bias TRUE 0.64% TRUE 0.18% 2.02%± 5% of Span Difference TRUE 0.64 TRUE 0.02 0.22 Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 47.64 5.91 6.23 SBi - Up-Scale Bias TRUE 3.22% TRUE 0.55% 0.64% Difference TRUE 3.22 TRUE 0.06 0.07 Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:11/20/2024 SO2 SO2 NOX CO CO2 O2 NOX29.1 7.8 7.6 CO 0.0% 29.1% 0.0% 71.0% 70.0% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.56 -0.04 0.23 System Bias. SBi - Zero Bias TRUE 0.66% TRUE 0.09% 2.02%± 5% of Span Difference TRUE 0.7 TRUE 0.0 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 48.80 5.89 6.25 SBi - Up-Scale Bias TRUE 2.06% TRUE 0.73% 0.83% Difference TRUE 2.1 TRUE 0.1 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.02% TRUE 0.09% 0.00% Drift Difference TRUE 0.0 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 1.16% TRUE 0.18% 0.18% Difference TRUE 1.2 TRUE 0.0 0.0 Pass or Re-Calibrate Pass Pass Pass Cogen East Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 28.274 0.00 0.00 0.00 7.87 7.37 84.77 29.55 29.55 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws #NUM! 0.0000 #DIV/0! 0.999 Load - Megawatts Avg. √∆P's Vs (ft/sec.)Qsw scfh wet Qa acfm Qsd dscfh Heat InputBtu/hr Low Mid High 183.546 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 12 3 4 5 6 7 89 10 11 12 13 14 15 1617 18 1920 21 22 23 24 Failed Bias Dialog Failed Drift Dialog Failed Cal Error Dialog CO Calibration Gas Failed Bias Dialog FCCU Cogen East 2024 Division of Air Quality Stack Test Review ofTesoro SO2 NOX CO CO2 O2 Cogen East CS Calibration Span 100.00 10.92 10.87 Units ppm ppm ppm % % CV - Cylinder Value:SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00Mid-Level 50.00 6.00 6.00 High-Level 100.00 10.92 10.87 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 54.9% 55.2%100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CMA 50.00 6.00 6.00 Calibration Error Test Measured Concentration SO2 NOX CO CO2 O2Low-Level -0.10 -0.05 0.01 Mid-Level 50.86 5.97 6.16 High-Level 99.86 10.98 10.98 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.86 5.97 6.16 Low-Level 0.10% 0.46% 0.09% ppmdv Difference 0.1 0.05 0.01 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.86% 0.27% 1.47% ppmdv Difference 0.86 0.03 0.16 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.14% 0.55% 1.01% ppmdv Difference 0.14 0.06 0.11 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.56 -0.04 0.23 System Bias. SBi - Zero Bias TRUE 0.66% TRUE 0.09% 2.02%± 5% of Span Difference TRUE 0.66 TRUE 0.01 0.22 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 48.80 5.89 6.25 SBi - Up-Scale Bias TRUE 2.06% TRUE 0.73% 0.83% Difference TRUE 2.06 TRUE 0.08 0.09 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:11/20/2024 SO2 SO2 NOX CO CO2 O2 NOX 28.6 7.8 7.6 CO 0.0% 28.6% 0.0% 71.2% 69.8% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.15 0.00 0.34 System Bias. SBi - Zero Bias TRUE 0.25% TRUE 0.46% 3.04%± 5% of Span Difference TRUE 0.3 TRUE 0.1 0.3 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 48.15 5.90 6.38 SBi - Up-Scale Bias TRUE 2.71% TRUE 0.64% 2.02% Difference TRUE 2.7 TRUE 0.1 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.41% TRUE 0.37% 1.01% Response Spec. Difference TRUE 0.4 TRUE 0.0 0.1 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 0.65% TRUE 0.09% 1.20% Difference TRUE 0.6 TRUE 0.0 0.1 Pass or Re-Calibrate Pass Pass Pass Cogen East Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 28.27 0.00 0.00 0.00 7.91 7.27 84.82 29.56 29.56 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 0.0000 #DIV/0! 0.999 Load - Megawatts Avg. √∆P's Vs Qsw scfh wet Qa acfm Qsd dscfh Heat Input Btu/hr Low Mid High 183.744 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 2 34 5 6 78 9 10 11 12 13 14 1516 17 1819 20 21 22 23 24 Failed Bias Dialog Failed Drift Dialog Failed Cal Error Dialog Failed Bias Dialog FCCU Cogen East 2024 Division of Air Quality Stack Test Review ofTesoro SO2 NOX CO CO2 O2 Cogen East CS Calibration Span 100.00 10.92 10.87 Units ppm ppm ppm % % CV - Cylinder Value:SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00Mid-Level 50.00 6.00 6.00 High-Level 100.00 10.92 10.87 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 54.9% 55.2%100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CMA 50.00 6.00 6.00 Calibration Error Test Measured Concentration SO2 NOX CO CO2 O2Low-Level -0.10 -0.05 0.01 Mid-Level 50.86 5.97 6.16 High-Level 99.86 10.98 10.98 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.86 5.97 6.16 Low-Level 0.10% 0.46% 0.09% ppmv Difference 0.1 0.05 0.01 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.86% 0.27% 1.47% ppmv Difference 0.86 0.03 0.16 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.14% 0.55% 1.01% ppmv Difference 0.14 0.06 0.11 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.15 0.00 0.34 System Bias. SBi - Zero Bias TRUE 0.25% TRUE 0.46% 3.04%± 5% of Span Difference TRUE 0.25 TRUE 0.05 0.33 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 48.15 5.90 6.38 SBi - Up-Scale Bias TRUE 2.71% TRUE 0.64% 2.02% Difference TRUE 2.71 TRUE 0.07 0.22 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:11/20/2024 SO2 SO2 NOX CO CO2 O2 NOX 29.0 7.7 7.7 CO 0.0% 29.0% 0.0% 70.5% 70.7% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.56 -0.01 0.38 System Bias. SBi - Zero Bias TRUE 0.66% TRUE 0.37% 3.40%± 5% of Span Difference TRUE 0.7 TRUE 0.0 0.4 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 50.47 5.90 6.38 SBi - Up-Scale Bias TRUE 0.39% TRUE 0.64% 2.02% Difference TRUE 0.4 TRUE 0.1 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.41% TRUE 0.09% 0.37% Response Spec. Difference TRUE 0.4 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 2.32% TRUE 0.00% 0.00% Difference TRUE 2.3 TRUE 0.0 0.0 Pass or Re-Calibrate Pass Pass Pass Cogen East Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 28.27 0.00 0.00 0.00 7.83 7.29 84.88 29.54 29.54 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 0.0000 #DIV/0! 0.999 Load - Megawatts Avg. √∆P's Vs Qsw scfh wet Qa acfm Qsd dscfh Heat Input Btu/hr Low Mid High 181.39 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 2 34 5 6 FT``` 78 9 10 11 12 13 14 1516 17 1819 20 21 22 23 24 Failed Bias Dialog Failed Cal Error Dialog Failed Drift Dialog Failed Bias Dialog FCCU Cogen West 2024 Reference Methods 2, 3A, 6C, 7E, 10, & 19 Source Information Company Name Tesoro Company Contact:Sergio Ibarra Contact Phone No.801-366-2086 Stack Designation:Cogen West Test & Review Dates Test Date:11/19/2024 & Review Date: 1/22/2025 Observer: Reviewer:Paul Morris Emission Limits Emission Rates SO2 NOX CO SO2 NOX CO lbs./MMBtu lbs./hr. ppm 20.0 197.0 41.713 Percent %O2 Correction as a whole #0.00 15.00 Test Information Heat Input Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) fuel flow rate (Btu/hr.) Heat Input (Btu/hr.) 72.00 28.274 Contractor Information Contact: Charles Horton Contracting Company: Alliance Technical Group, LLC Address: 3683 W 2270 S, Suite E West Valley City, UT 84120 Phone No.: (464) 352-7568 Project No.: 8425 Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Round Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthrocite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 CO2 Interference w/CO Yes Yes Yes FCCU Cogen West 2024 Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Tesoro Cogen West Average Emission Dry SO2 NOX CO lbs./MMbtu 0.064 Average % concentration lbs./hr.12.13 CO2 O2 ppm or % 41.71 7.74 7.26 Run 1 Enter O2 or CO2 Dry SO2 NOX CO CO2 O2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)6.54E-02 E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 5.036E-06 lbs./hr.12.35 7.75 7.35 ppm or %42.16 7.67 7.44 Run 2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)6.51E-02 E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 5.024E-06 lbs./hr.12.08 7.67 7.31 ppm or %42.06 7.67 7.45 Raw Value Run 3 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)6.25E-02 E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 4.887E-06 lbs./hr.11.96 7.81 7.13 ppm or %40.92 7.73 7.25 Raw Value Run 4 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value Run 5 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value C For Cal Drift Raw Value C For Cal Drift C For Cal Drift C For Cal Drift C For Cal Drift O2 CO2 Clear lbs./MMBTU FCCU Cogen West 2024 Calibration Error Test Test Date November 19, 2024 O2 CS - Cal. Span 24.06 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.00% Passed Cal. RR03646 02/24/32 Mid-level 10.87 10.92 0.05 0.21% Passed Cal. CC727648 09/19/31 High-level 24.06 24.08 0.02 0.08% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of CS - Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 45.18% 100% of Cal. Span High-level 100.00% Test Date November 19, 2024 CO2 CS - Cal. Span 23.90 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 -0.05 0.05 0.209% Passed Cal. RR03646 02/24/32 Mid-level 10.92 10.95 0.03 0.126% Passed Cal. CC727648 09/19/31 High-level 23.90 23.91 0.01 0.042% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 45.69% 100% of Cal. Span High-level 100.00% Test Date SO2 CS - Cal. Span Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level Mid-level High-level % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 40 to 60% of Cal. Span Mid-level 100% of Cal. Span High-level Test Date November 19, 2024 NOx CS - Cal. Span 100.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 -0.24 0.24 0.240% Passed Cal. EB0099840 04/01/32 Mid-level 50.00 50.34 0.34 0.340% Passed Cal. High-level 100.00 100.11 0.11 0.110% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date CO CS - Cal. Span Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level Mid-level High-level % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 40 to 60% of Cal. Span Mid-level 100% of Cal. Span High-level Valid Cal Gas Valid Cal Gas Valid Cal Gas Valid Cal Gas Valid Cal Gas FCCU Cogen West 2024 Division of Air Quality Stack Test Review ofTesoro SO2 NOX CO CO2 O2 Cogen West CS Calibration Span 100.00 23.90 24.06 Units ppm ppm ppm % % Unprotected CV - Cylinder Value: SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00 Mid-Level 50.00 10.92 10.87 High-Level 100.00 23.90 24.06 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 45.7% 45.2% 100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CDir CMA 50.00 10.92 10.87 Calibration Error Test Cs - Measured Concentration SO2 NOX CO CO2 O2 Low-Level -0.24 -0.05 0.00 Mid-Level 50.34 10.95 10.92High-Level 100.11 23.91 24.08 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.34 10.95 10.92 Low-Level 0.24% 0.21% 0.00% ppmdv Difference 0.24 0.05 0 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.34% 0.13% 0.21% ppmdv Difference 0.34 0.03 0.05 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.11% 0.04% 0.08% ppmdv Difference 0.11 0.01 0.02 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.16 -0.04 0.02 System Bias. SBi - Zero Bias TRUE 0.40% TRUE 0.04% 0.08%± 5% of Span Difference TRUE 0.4 TRUE 0.01 0.02 Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.82 10.81 10.93 SBi - Up-Scale Bias TRUE 0.52% TRUE 0.59% 0.04% Difference TRUE 0.52 TRUE 0.14 0.01 Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:11/19/2024 SO2 SO2 NOX CO CO2 O2 NOX42.2 7.7 7.4 CO 0.0% 42.2% 0.0% 32.1% 30.9% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level -0.09 0.03 0.21 System Bias. SBi - Zero Bias TRUE 0.15% TRUE 0.33% 0.87%± 5% of Span Difference TRUE 0.2 TRUE 0.1 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 50.21 10.82 10.98 SBi - Up-Scale Bias TRUE 0.13% TRUE 0.54% 0.25% Difference TRUE 0.1 TRUE 0.1 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.25% TRUE 0.29% 0.79% Drift Difference TRUE 0.3 TRUE 0.1 0.2 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 0.39% TRUE 0.04% 0.21% Difference TRUE 0.4 TRUE 0.0 0.1 Pass or Re-Calibrate Pass Pass Pass Cogen West Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 28.274 0.00 0.00 0.00 7.75 7.35 84.91 29.53 29.53 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws #NUM! 0.0000 #DIV/0! 0.999 Load - Megawatts Avg. √∆P's Vs (ft/sec.)Qsw scfh wet Qa acfm Qsd dscfh Heat InputBtu/hr Low Mid High 188.79 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 12 3 4 5 6 7 89 10 11 12 13 14 15 1617 18 1920 21 22 23 24 Failed Bias Dialog Failed Drift Dialog Failed Cal Error Dialog CO Calibration Gas Failed Bias Dialog FCCU Cogen West 2024 Division of Air Quality Stack Test Review ofTesoro SO2 NOX CO CO2 O2 Cogen West CS Calibration Span 100.00 23.90 24.06 Units ppm ppm ppm % % CV - Cylinder Value:SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00Mid-Level 50.00 10.92 10.87 High-Level 100.00 23.90 24.06 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 45.7% 45.2%100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CMA 50.00 10.92 10.87 Calibration Error Test Measured Concentration SO2 NOX CO CO2 O2Low-Level -0.24 -0.05 0.00 Mid-Level 50.34 10.95 10.92 High-Level 100.11 23.91 24.08 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.34 10.95 10.92 Low-Level 0.24% 0.21% 0.00% ppmdv Difference 0.24 0.05 0 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.34% 0.13% 0.21% ppmdv Difference 0.34 0.03 0.05 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.11% 0.04% 0.08% ppmdv Difference 0.11 0.01 0.02 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level -0.09 0.03 0.21 System Bias. SBi - Zero Bias TRUE 0.15% TRUE 0.33% 0.87%± 5% of Span Difference TRUE 0.15 TRUE 0.08 0.21 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 50.21 10.82 10.98 SBi - Up-Scale Bias TRUE 0.13% TRUE 0.54% 0.25% Difference TRUE 0.13 TRUE 0.13 0.06 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:11/19/2024 SO2 SO2 NOX CO CO2 O2 NOX 42.2 7.6 7.5 CO 0.0% 42.2% 0.0% 31.8% 31.0% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.15 -0.01 0.20 System Bias. SBi - Zero Bias TRUE 0.39% TRUE 0.17% 0.83%± 5% of Span Difference TRUE 0.4 TRUE 0.0 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 50.21 10.79 10.98 SBi - Up-Scale Bias TRUE 0.13% TRUE 0.67% 0.25% Difference TRUE 0.1 TRUE 0.2 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.24% TRUE 0.17% 0.04% Response Spec. Difference TRUE 0.2 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 0.00% TRUE 0.13% 0.00% Difference TRUE 0.0 TRUE 0.0 0.0 Pass or Re-Calibrate Pass Pass Pass Cogen West Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 28.27 0.00 0.00 0.00 7.67 7.31 85.02 29.52 29.52 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 0.0000 #DIV/0! 0.999 Load - Megawatts Avg. √∆P's Vs Qsw scfh wet Qa acfm Qsd dscfh Heat Input Btu/hr Low Mid High 185.606 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 2 34 5 6 78 9 10 11 12 13 14 1516 17 1819 20 21 22 23 24 Failed Bias Dialog Failed Drift Dialog Failed Cal Error Dialog Failed Bias Dialog FCCU Cogen West 2024 Division of Air Quality Stack Test Review ofTesoro SO2 NOX CO CO2 O2 Cogen West CS Calibration Span 100.00 23.90 24.06 Units ppm ppm ppm % % CV - Cylinder Value:SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00Mid-Level 50.00 10.92 10.87 High-Level 100.00 23.90 24.06 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 45.7% 45.2%100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CMA 50.00 10.92 10.87 Calibration Error Test Measured Concentration SO2 NOX CO CO2 O2Low-Level -0.24 -0.05 0.00 Mid-Level 50.34 10.95 10.92 High-Level 100.11 23.91 24.08 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.34 10.95 10.92 Low-Level 0.24% 0.21% 0.00% ppmv Difference 0.24 0.05 0 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.34% 0.13% 0.21% ppmv Difference 0.34 0.03 0.05 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.11% 0.04% 0.08% ppmv Difference 0.11 0.01 0.02 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.15 -0.01 0.20 System Bias. SBi - Zero Bias TRUE 0.39% TRUE 0.17% 0.83%± 5% of Span Difference TRUE 0.39 TRUE 0.04 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 50.21 10.79 10.98 SBi - Up-Scale Bias TRUE 0.13% TRUE 0.67% 0.25% Difference TRUE 0.13 TRUE 0.16 0.06 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:11/19/2024 SO2 SO2 NOX CO CO2 O2 NOX 41.0 7.7 7.3 CO 0.0% 41.0% 0.0% 32.3% 30.1% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.02 0.01 0.16 System Bias. SBi - Zero Bias TRUE 0.26% TRUE 0.25% 0.67%± 5% of Span Difference TRUE 0.3 TRUE 0.1 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.96 10.83 10.95 SBi - Up-Scale Bias TRUE 0.38% TRUE 0.50% 0.12% Difference TRUE 0.4 TRUE 0.1 0.0 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.13% TRUE 0.08% 0.17% Response Spec. Difference TRUE 0.1 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 0.25% TRUE 0.17% 0.12% Difference TRUE 0.3 TRUE 0.0 0.0 Pass or Re-Calibrate Pass Pass Pass Cogen West Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 28.27 0.00 0.00 0.00 7.81 7.13 85.07 29.53 29.53 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 0.0000 #DIV/0! 0.999 Load - Megawatts Avg. √∆P's Vs Qsw scfh wet Qa acfm Qsd dscfh Heat Input Btu/hr Low Mid High 191.36 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 2 34 5 6 FT``` 78 9 10 11 12 13 14 1516 17 1819 20 21 22 23 24 Failed Bias Dialog Failed Cal Error Dialog Failed Drift Dialog Failed Bias Dialog